Science.gov

Sample records for methane series part

  1. Methane flux time series for tundra environments

    SciTech Connect

    Whalen, S.C.; Reeburgh, W.E. )

    1988-12-01

    Seasonal measurements of net methane flux were made at permanent sites representing important components of arctic tundra. The sites include Eriophorum tussocks, intertussock depressions, moss-covered areas, and Carex stands. Methane fluxes showed high diel, seasonal, intra site, and between site variability. Eriophorum tussocks and Carex dominated methane release to the atmosphere, with mean annual net methane fluxes of 8.05 + or{minus}2.50 g CH{sub 4}/sq m and 4.88 + or{minus}0.73 g CH{sub 4}/sq m, respectively. Methane fluxes form the moss sites and intertussock depressions were much lower. Over 90% of the mean annual methane flux from the Eriophorum, intertussock depressions, and Carex sites occurred between thaw and freeze-up. Some 40% of the mean annual methane flux from the moss sites occurred during winter. Composite methane fluxes for tussock tundra and Carex-dominated wet meadow tundra environments were produced by weighting measured component fluxes according to areal coverage. Tussock and wet meadow tundra account for an estimated global methane emission of 19-33 Tg/yr. 39 refs., 7 figs., 2 tabs.

  2. Measuring in situ dissolved methane concentrations in gas hydrate-rich systems, Part 1: Investigating the correlation between tectonics and methane release from sediments

    NASA Astrophysics Data System (ADS)

    Lapham, L.; Wilson, R. M.; Paull, C. K.; Chanton, J.; Riedel, M.

    2010-12-01

    In 2009, an area of extended methane venting at 1200 meters water depth was found with high resolution AUV bathymetry scans on the Northern Cascadia Margin that was previously unknown. When visited by ROV, we found seafloor cracks with active bubble streams and thin bacterial mats suggesting shallow gas and possible pore-fluid saturation. Upon coring into the cracks, a hard-substrate (carbonate or gas hydrate) was punctured and gas flows began. With these observations, we asked the question “is this shallow gas released from the seafloor from regional tectonic activity, and, if so, what is the temporal variability of such release events?” To answer this, we deployed a long term pore-water collection device at one of these gas crack sites, informally named “bubbly gulch”, for 9 months. The device is made up of 4 OsmoSamplers that were each plumbed to a port along a 1-meter probe tip using small diameter tubing. By osmosis, the samplers collected water samples slowly through the ports and maintained them within a 300 meter-long copper tubing coil. Because of the high methane concentrations anticipated, in situ pressures were maintained within the coil by the addition of a high pressure valve. Water samples were collected from the overlying water, at the sediment-water interface, and 6 and 10 cm into the sediments. Bottom water temperatures were also measured over the time series to determine pumping rates of the samplers but also to look for any temporal variability. In May 2010, the samplers were retrieved by ROV during efforts to install seafloor instruments for Neptune Canada. In a land-based lab, the coils were sub-sampled by cutting every 4 meters of tubing. With a pumping rate of 0.5 mL/day, this allowed a temporal resolution of 6 days. To date, one sampler coil has been sub-sampled and measured for methane concentrations and stable carbon isotopes. Preliminary results from this coil show pore-fluids nearly saturated with respect to methane, ~45 m

  3. Ritter reaction in monoterpenes of the p-methane series

    SciTech Connect

    Kozlov, N.G.; Popova, L.A.; Novikova, M.G.

    1986-03-01

    The Ritter reaction was studied for some individual monoterpenes of the p-menthane series (p-menth-1-ene, p-menth-2-ene, p-menth-3-ene, cis- and trans-p-menth-8-ene, dipentene, cis- and trans-p-menthan-8-ol, and ..cap alpha..-terpineol) with acetonitrile in the presence of concentrated sulfuric acid at 20/sup 0/C. The stereochemical structure of the reaction products (substituted amides) was established. Possible paths were proposed for their formation through carbocations in accordance with the previously described transformations of stable carbocations generated from the analogous monoterpenes in superacidic media.

  4. 40 CFR Table W - 7 of Subpart W of Part 98-Default Methane Emission Factors for Natural Gas Distribution

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Methane Emission Factors for Natural Gas Distribution W Table W Protection of Environment ENVIRONMENTAL... Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-7 Table W-7 of Subpart W of Part 98—Default Methane Emission Factors for Natural Gas Distribution Natural gas distribution Emission factor...

  5. 40 CFR Table W - 7 of Subpart W of Part 98-Default Methane Emission Factors for Natural Gas Distribution

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Methane Emission Factors for Natural Gas Distribution W Table W Protection of Environment ENVIRONMENTAL... Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-7 Table W-7 of Subpart W of Part 98—Default Methane Emission Factors for Natural Gas Distribution Natural gas distribution Emission factor...

  6. Lower Rydberg series of methane: a combined coupled cluster linear response and molecular quantum defect orbital calculation.

    PubMed

    Velasco, A M; Pitarch-Ruiz, J; Sánchez de Merás, Alfredo M J; Sánchez-Marín, J; Martin, I

    2006-03-28

    Vertical excitation energies as well as related absolute photoabsorption oscillator strength data are very scarce in the literature for methane. In this study, we have characterized the three existing series of low-lying Rydberg states of CH4 by computing coupled cluster linear response (CCLR) vertical excitation energies together with oscillator strengths in the molecular-adapted quantum defect orbital formalism from a distorted Cs geometry selected on the basis of outer valence green function calculations. The present work provides a wide range of data of excitation energies and absolute oscillator strengths which correspond to the Rydberg series converging to the three lower ionization potential values of the distorted methane molecule, in energy regions for which experimentally measured data appear to be unavailable.

  7. Trends and Patterns in a New Time Series of Natural and Anthropogenic Methane Emissions, 1980-2000

    NASA Astrophysics Data System (ADS)

    Matthews, E.; Bruhwiler, L.; Themelis, N. J.

    2007-12-01

    We report on a new time series of methane (CH4) emissions from anthropogenic and natural sources developed for a multi-decadal methane modeling study (see following presentation by Bruhwiler et al.). The emission series extends from 1980 through the early 2000s with annual emissions for all countries has several features distinct from the source histories based on IPCC methods typically employed in modeling the global methane cycle. Fossil fuel emissions rely on 7 fuel-process emission combinations and minimize reliance on highly-uncertain emission factors. Emissions from ruminant animals employ regional profiles of bovine populations that account for the influence of variable age- and size-demographics on emissions and are ~15% lower than other estimates. Waste-related emissions are developed using an approach that avoids using of data-poor emission factors and accounts for impacts of recycling and thermal treatment of waste on diverting material from landfills and CH4 capture at landfill facilities. Emissions from irrigated rice use rice-harvest areas under 3 water-management systems and a new historical data set that analyzes multiple sources for trends in water management since 1980. A time series of emissions from natural wetlands was developed by applying a multiple-regression model derived from full process-based model of Walter with analyzed meteorology from the ERA-40 reanalysis.

  8. Time-series measurements of bubble plume variability and water column methane distribution above Southern Hydrate Ridge, Oregon

    NASA Astrophysics Data System (ADS)

    Philip, Brendan T.; Denny, Alden R.; Solomon, Evan A.; Kelley, Deborah S.

    2016-03-01

    An estimated 500-2500 gigatons of methane carbon is sequestered in gas hydrate at continental margins and some of these deposits are associated with overlying methane seeps. To constrain the impact that seeps have on methane concentrations in overlying ocean waters and to characterize the bubble plumes that transport methane vertically into the ocean, water samples and time-series acoustic images were collected above Southern Hydrate Ridge (SHR), a well-studied hydrate-bearing seep site ˜90 km west of Newport, Oregon. These data were coregistered with robotic vehicle observations to determine the origin of the seeps, the plume rise heights above the seafloor, and the temporal variability in bubble emissions. Results show that the locations of seep activity and bubble release remained unchanged over the 3 year time-series investigation, however, the magnitude of gas release was highly variable on hourly time scales. Bubble plumes were detected to depths of 320-620 m below sea level (mbsl), in several cases exceeding the upper limit of hydrate stability by ˜190 m. For the first time, sustained gas release was imaged at the Pinnacle site and in-between the Pinnacle and the Summit area of venting, indicating that the subseafloor transport of fluid and gas is not restricted to the Summit at SHR, requiring a revision of fluid-flow models. Dissolved methane concentrations above background levels from 100 to 300 mbsl are consistent with long-term seep gas transport into the upper water column, which may lead to the build-up of seep-derived carbon in regional subsurface waters and to increases in associated biological activity.

  9. Atmospheric methane time series from Finland and Siberia: source areas and surface flux estimates

    NASA Astrophysics Data System (ADS)

    Kilkki, Juho; Aalto, Tuula; Kouznetsov, Rostislav; Hatakka, Juha; Makelä, Timo; Leskinen, Ari; Laurila, Tuomas

    2016-04-01

    We present atmospheric methane concentrations from a diverse set of Finnish stations and Tiksi, northeastern Siberia, and associate them with source areas and surface fluxes. In Finland, synoptic time scale concentrations are consistent with observations from the WMO/GAW site Pallas, with little difference in mean concentration in well-mixed cases. However, source areas determined with a backward dispersion model show that there is a gradient in sensitivity to both anthropogenic and wetland emissions among the stations. We estimate these flux components in the northern parts of Europe using the available observations. In Tiksi, the concentrations are consistent with nearby micrometeorological measurements and a remote-sensed wetness distribution in the region. Wintertime concentrations are usually close to background concentrations in a global transport model, and overall there are few events attributable to the ocean. In a Bayesian atmospheric inversion with weather-independent emissions, the oceanic source is about a third of wetland emissions in our study area that covers most of northern Yakutia and the East-Siberian Arctic Shelf.

  10. Isoreticular Series of (3,24)-Connected Metal-Organic Frameworks: Facile Synthesis and High Methane Uptake Properties

    SciTech Connect

    Barin, G; Krungleviciute, V; Gomez-Gualdron, DA; Sarjeant, AA; Snurr, RQ; Hupp, JT; Yildirim, T; Farha, OK

    2014-03-11

    We have successfully used a highly efficient copper-catalyzed "click" reaction for the synthesis of a new series of hexacarboxylic acid linkers with varying sizes for the construction of isoreticular (3,24)-connected metal-organic frameworks (MOFs)-namely, NU-138, NU-139, and NU-140. One of these MOFs, NU-140, exhibits a gravimetric methane uptake of 0.34 g/g at 65 bar and 298 K, corresponding to almost 70% of the DOE target (0.5 g/g), and has a working capacity (deliverable amount between 65 and 5 bar) of 0.29 g/g, which translates into a volumetric working capacity of 170 cc(STP)/cc. These values demonstrate that NU-140 performs well for methane storage purposes, from both a gravimetric and a volumetric point of view. Adsorption of CO2 and H-2 along with simulated isotherms are also reported.

  11. What's the Deal with Methane at LUST Spill Sites? Part 1

    EPA Science Inventory

    This article is specifically intended to discuss methane produced from releases of ethanol and gasoline-ethanol mixtures. There may be other sources of methane at a site, including leaks of natural gas or methane produced from the natural decay of buried plant tissues or from th...

  12. What's the Deal with Methane at LUST Spill Sites? Part 2: Vapor Intrusion

    EPA Science Inventory

    This article is specifically intended to discuss methane produced from releases of ethanol and gasoline-ethanol mixtures. There may be other sources of methane at a site, including leaks of natural gas or methane produced from the natural decay of buried plant tissues or from the...

  13. Writing for professional publication. Part 12: summary of the series.

    PubMed

    Fowler, John

    The previous articles in this series have explored the practical issues of writing for professional publication. In this final article, John Fowler, an experienced nursing lecturer and author, summarises the series and presents an overview of the practicalities of writing for publication.

  14. Bio-conversion of water hyacinths into methane gas, part 1

    NASA Technical Reports Server (NTRS)

    Wolverton, B. C.; Mcdonald, R. C.; Gordon, J.

    1974-01-01

    Bio-gas and methane production from the microbial anaerobic decomposition of water hyacinths (Eichhornia crassipes) (Mart) Solms was investigated. These experiments demonstrated the ability of water hyacinths to produce an average of 13.9 ml of methane gas per gram of wet plant weight. This study revealed that sample preparation had no significant effect on bio-gas and/or methane production. Pollution of water hyacinths by two toxic heavy materials, nickel and cadmium, increased the rate of methane production from 51.8 ml/day for non-contaminated plants incubated at 36 C to 81.0 ml/day for Ni-Cd contaminated plants incubated at the same temperature. The methane content of bio-gas evolved from the anaerobic decomposition of Ni-Cd contaminated plants was 91.1 percent as compared to 69.2 percent methane content of bio-gas collected from the fermentation of non-contaminated plants.

  15. A lean methane premixed laminar flame doped with components of diesel fuel part III: Indane and comparison between n-butylbenzene, n-propylcyclohexane and indane

    SciTech Connect

    Pousse, E.; Tian, Z.Y.; Glaude, P.A.; Fournet, R.; Battin-Leclerc, F.

    2010-07-15

    To better understand the chemistry of the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with indane has been investigated. The inlet gases contained 7.1% (molar) of methane, 36.8% of oxygen and 0.9% of indane corresponding to an equivalence ratio of 0.67 and a ratio C{sub 10}H{sub 14}/CH{sub 4} of 12.8%. The flame has been stabilized on a burner at a pressure of 6.7 kPa (50 Torr) using argon as diluent, with a gas velocity at the burner of 49.1 cm s{sup -1} at 333 K. Quantified species included the usual methane C{sub 0}-C{sub 2} combustion products, but also 16 C{sub 3}-C{sub 5} non-aromatic hydrocarbons, 6 C{sub 1}-C{sub 3} non-aromatic oxygenated compounds, as well as 22 aromatic products, namely benzene, toluene, xylenes, phenylacetylene, ethylbenzene, styrene, propenylbenzene, allylbenzene, n-propylbenzene, methylstyrenes, ethyltoluenes, trimethylbenzenes, n-butylbenzene, dimethylethylbenzene, indene, methylindenes, methylindane, benzocyclobutene, naphthalene, phenol, benzaldehyde, and benzofuran. A new mechanism for the oxidation of indane was proposed whose predictions were in satisfactory agreement with measured species profiles in both flames and jet-stirred reactor experiments. The main reaction pathways of consumption of indane have been derived from flow rate analyses in the two types of reactors. A comparison of the effect of the addition of three components of diesel fuel, namely indane, n-butylbenzene and n-propylcyclohexane (parts I and II of this series of paper), on the structure of a laminar lean premixed methane flame is also presented. (author)

  16. Accounting Issues: An Essay Series Part VII--Liabilities

    ERIC Educational Resources Information Center

    Laux, Judy

    2008-01-01

    This article, the seventh in the series, presents accounting for liabilities along with some related conceptual and measurement issues. Additional coverage is devoted to potential ethical dilemmas and both theoretical and empirical literature related to this set of accounting elements.

  17. Accounting Issues: An Essay Series Part VIII--Stockholders' Equity

    ERIC Educational Resources Information Center

    Laux, Judy

    2008-01-01

    This eighth installment in the series on accounting theory pertains to stockholders' equity and its related conceptual, measurement and ethical issues. Coverage includes the associated theoretical, empirical, and popular literature. (Contains 5 footnotes.)

  18. Campus Ecology, Part 2 of a Series: Pond Water

    ERIC Educational Resources Information Center

    Bryan, R. C.

    1974-01-01

    Presents a series of activities which focus on the study of the physical characteristics of water, including temperatures, opacity, pH-values, oxygen concentrations, reagents, and free CO2 concentrations. Indicates that ponds can provide the students with opportunities to learn chemistry, geology, biology, botany, and the effects of weather. (CC)

  19. Accounting Issues: An Essay Series. Part II--Accounts Receivable

    ERIC Educational Resources Information Center

    Laux, Judith A.

    2007-01-01

    This is the second in a series of articles designed to help academics refocus the introductory accounting course on the theoretical underpinnings of accounting. Intended as a supplement for the principles course, this article connects the asset Accounts Receivable to the essential theoretical constructs, discusses the inherent tradeoffs and…

  20. Accounting Issues: An Essay Series Part III--Inventory

    ERIC Educational Resources Information Center

    Laux, Judy

    2007-01-01

    The third in a series of theoretical essays intended to supplement the introductory financial accounting course, this article is dedicated to the treatment of inventory and its related conceptual connections. In addition, this paper addresses inventory measurement dilemmas, describes scandalous accounting episodes that have made the headlines, and…

  1. Accounting Issues: An Essay Series Part V--Intangible Assets

    ERIC Educational Resources Information Center

    Laux, Judy

    2008-01-01

    This article represents the fifth in a series of theoretical essays intended to supplement the introductory financial accounting course and investigates the accounting treatment and related conceptual connections for intangibles. In addition, intangibles present unique accounting issues, conceptual challenges, and measurement dilemmas not found…

  2. ISKME Special Series Part 2: Data Use and School Reform

    ERIC Educational Resources Information Center

    Petrides, Lisa A.

    2006-01-01

    This is the second part of a four-part report on data-driven decision-making. Widespread attention to school accountability, driven by state and federal mandates, has increased the stakes for all schools. These mandates have made more data available to educators at all levels, but they have not been as effective in encouraging teachers to use…

  3. Lecture Series. Boundary Layer Theory. Part 1. Laminar Flows

    DTIC Science & Technology

    1949-04-01

    conditions =: p ’ =0 The solution found by series development can be found in the thesis of Hiemenz (reference 10), compare table 1*. The velocity...Boundary Layer on the Cylinder (symmetrical case) The integration method of Blasius given in the previous section was used by Hiemenz (thesis G6ttingen...the differential equations (9.33) are best obtained by numerical integration. The functions f, and f3 were already calculated by Hiemenz (reference

  4. 40 CFR Table W - 5 of Subpart W of Part 98-Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Methane Emission Factors for Liquefied Natural Gas (LNG) Storage W Table W Protection of Environment... Petroleum and Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-5 Table W-5 of Subpart W of Part 98—Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage LNG storage Emission factor...

  5. 40 CFR Table W - 5 of Subpart W of Part 98-Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Methane Emission Factors for Liquefied Natural Gas (LNG) Storage W Table W Protection of Environment... Petroleum and Natural Gas Systems Definitions. Pt. 98, Subpt. W, Table W-5 Table W-5 of Subpart W of Part 98—Default Methane Emission Factors for Liquefied Natural Gas (LNG) Storage LNG storage Emission factor...

  6. Jackson's Mill Industrial Arts Curriculum Theory: A Base for Curriculum Conceptualization. Part 2 of a Two-Part Series.

    ERIC Educational Resources Information Center

    Hales, James A.; Snyder, James F.

    1982-01-01

    Presents narratives, charts, and diagrams showing the unique aspects of the four subsystems of human technical endeavor. These subsystems are communication, construction, manufacturing, and transportation. (For part 1 of this series, see CE 511 770.) (CT)

  7. BEGINNING CHINESE READER, PART I. YALE LINGUISTIC SERIES.

    ERIC Educational Resources Information Center

    DE FRANCIS, JOHN; AND OTHERS

    THIS READER, ALONG WITH "BEGINNING CHINESE READER, PART II," IS CLOSELY INTEGRATED WITH THE SETON HALL UNIVERSITY TEXTS FOR SPOKEN AND WRITTEN CHINESE, "BEGINNING CHINESE" AND "CHARACTER TEXT FOR BEGINNING CHINESE." OF THE 400 CHARACTERS IN THESE TWO READERS, ALL BUT 33 HAVE BEEN PRESENTED TO THE STUDENT IN "BEGINNING CHINESE" AND "CHARACTER…

  8. Effects of Hofmeister salt series on gluten network formation: Part I. Cation series.

    PubMed

    Tuhumury, H C D; Small, D M; Day, L

    2016-12-01

    Different cationic salts were used to investigate the effects of the Hofmeister salt series on gluten network formation. The effects of cationic salts on wheat flour dough mixing properties, the rheological and the chemical properties of the gluten extracted from the dough with different respective salts, were investigated. The specific influence of different cationic salts on the gluten structure formation during dough mixing, compared to the sodium ion, were determined. The effects of different cations on dough and gluten of different flours mostly followed the Hofmeister series (NH4(+), K(+), Na(+), Mg(2+) and Ca(2+)). The impacts of cations on gluten structure and dough rheology at levels tested were relatively small. Therefore, the replacement of sodium from a technological standpoint is possible, particularly by monovalent cations such as NH4(+), or K(+). However the levels of replacement need to take into account sensory attributes of the cationic salts.

  9. Effects of Hofmeister salt series on gluten network formation: Part II. Anion series.

    PubMed

    Tuhumury, H C D; Small, D M; Day, L

    2016-12-01

    Different anion salts from the Hofmeister series were used to investigate their effects on gluten network formation. The effects of these anion salts on the mixing properties of the dough and the rheological and chemical properties of gluten samples extracted from the dough with these respective salts were compared. The aim of this work was to determine how different anion salts influence the formation of the gluten structure during dough mixing. It was found that the Hofmeister anion salts affected the gluten network formation by interacting directly with specific amino acid residues that resulted in changes in gluten protein composition, specifically the percentage of the unextractable polymeric protein fractions (%UPP). These changes consequently led to remarkable differences in the mixing profiles and microstructural features of the dough, small deformation rheological properties of the gluten and a strain hardening behaviour of both dough and gluten samples.

  10. Methane to syngas conversion. Part I. Equilibrium conditions and stability requirements of membrane materials

    NASA Astrophysics Data System (ADS)

    Frade, J. R.; Kharton, V. V.; Yaremchenko, A.; Naumovich, E.

    Thermodynamic data have been used to predict the dependence of methane conversion on temperature and oxygen partial pressure in mixed conducting membrane reactors, and the corresponding fractions of water vapor, H 2, CO and CO 2. The relations between methane conversion, gas composition and oxygen partial pressure were also used to formulate the oxygen balance in mixed conducting membrane reactors, with tubular reactor and continuous stirred tank reactor (CSTR) configurations. A single dimensionless parameter accounts for the combined effects of geometric parameters of the membrane reactor, the permeability of the membrane material, and flow rate at the entry of the reactor. Selected examples were calculated to illustrate the effects of steam to methane and inert to methane ratios in the gas entering the reactor. The values of oxygen partial pressure required to attain the highest yield of CO and H 2 were also used to estimate the stability requirements to be met by mixed conducting membrane materials. Suitable membrane designs might be needed to bridge the difference between the conditions inside the reactors and the stability limits of known mixed conductors.

  11. Methane oxidation in a biofilter (Part 1): Development of a mathematical model for designing and optimization.

    PubMed

    Amodeo, Corrado; Masi, Salvatore; Van Hulle, Stijn W H; Zirpoli, Pierfrancesco; Mancini, Ignazio M; Caniani, Donatella

    2015-01-01

    The aim of this work is the evaluation of the efficiency of such a biofilter, through the application of a mathematical model which describes the biological oxidation process. This mathematical model is able to predict the efficiency of the system under varying operating conditions. Literature data have been used in order to build the model. The factors that mostly affect the process and which actually regulate the entire process have been highlighted in this work. Specifically, it was found that temperature, flow and methane concentration are the most important parameters that influence the system. The results obtained from the mathematical model showed also that the biofilter system is simple to implement and manage and allows the achievement of high efficiency of methane oxidation. In the optimal conditions for temperature (between 20-30°C), residence time (between 0.7-0.8 h) and methane molar fraction (between 20-25%) the efficiency of methane oxidation could be around 50%.

  12. HyFlux - Part I: Regional Modeling of Methane Flux From Near-Seafloor Gas Hydrate Deposits on Continental Margins

    NASA Astrophysics Data System (ADS)

    MacDonald, I. R.; Asper, V.; Garcia, O. P.; Kastner, M.; Leifer, I.; Naehr, T.; Solomon, E.; Yvon-Lewis, S.; Zimmer, B.

    2008-12-01

    HyFlux - Part I: Regional modeling of methane flux from near-seafloor gas hydrate deposits on continental margins MacDonald, I.R., Asper, V., Garcia, O., Kastner, M., Leifer, I., Naehr, T.H., Solomon, E., Yvon-Lewis, S., and Zimmer, B. The Dept. of Energy National Energy Technology Laboratory (DOE/NETL) has recently awarded a project entitled HyFlux: "Remote sensing and sea-truth measurements of methane flux to the atmosphere." The project will address this problem with a combined effort of satellite remote sensing and data collection at proven sites in the Gulf of Mexico where gas hydrate releases gas to the water column. Submarine gas hydrate is a large pool of greenhouse gas that may interact with the atmosphere over geologic time to affect climate cycles. In the near term, the magnitude of methane reaching the atmosphere from gas hydrate on continental margins is poorly known because 1) gas hydrate is exposed to metastable oceanic conditions in shallow, dispersed deposits that are poorly imaged by standard geophysical techniques and 2) the consumption of methane in marine sediments and in the water column is subject to uncertainty. The northern GOM is a prolific hydrocarbon province where rapid migration of oil, gases, and brines from deep subsurface petroleum reservoirs occurs through faults generated by salt tectonics. Focused expulsion of hydrocarbons is manifested at the seafloor by gas vents, gas hydrates, oil seeps, chemosynthetic biological communities, and mud volcanoes. Where hydrocarbon seeps occur in depths below the hydrate stability zone (~500m), rapid flux of gas will feed shallow deposits of gas hydrate that potentially interact with water column temperature changes; oil released from seeps forms sea-surface features that can be detected in remote-sensing images. The regional phase of the project will quantify verifiable sources of methane (and oil) the Gulf of Mexico continental margin and selected margins (e.g. Pakistan Margin, South China Sea

  13. Simulations of Methane Hydrate Phenomena Over Geologic Timescales. Part I: Effect of Sediment Compaction Rates on Methans Hydrate and Free Gas Accumulation

    SciTech Connect

    Gering, Kevin Leslie

    2003-01-01

    The focus of this work is a model that describes migration and biogenic formation of methane under conditions representative of dynamic marine basins, and the conversion of soluble methane into either solid hydrate or exsolved gas. Incorporated into the overall model are an accurate phase equilibria model for seawater-methane, a methane source term based on biogenesis data, and a sediment compaction model based on porosity as a function of position, time, and the local volume fractions of hydrate solids and free gas. Simulations have shown that under some compaction scenarios, liquid overpressures reach the lithostatic limit due to permeability constraints, which can diminish the advective transfer of soluble methane within the porous sediment. As such, the formation of methane hydrate can be somewhat of a self-moderating process. The occurrence and magnitude of hydrate formation is directly tied to fundamental parameters such as the compaction/sedimentation rates, liquid advection rates, seafloor depth, geothermal gradient, etc. Results are shown for simulations covering 20 million years, wherein growth profiles for methane hydrate and free gas (neither exceeding 10 vol% at any location) are tracked within a vertical sediment column spanning over 3000 m. A case study is also presented for the Blake Ridge region (Ocean Drilling Program Leg 164, Sites 994, 995, and 997) based on simulations covering 6 Ma, wherein it is concluded that methane migration from compaction-driven advection may account for 15-30% of the total hydrate mass present in this region.

  14. Calculations of automatic chamber flux measurements of methane and carbon dioxide using short time series of concentrations

    NASA Astrophysics Data System (ADS)

    Pirk, Norbert; Mastepanov, Mikhail; Parmentier, Frans-Jan W.; Lund, Magnus; Crill, Patrick; Christensen, Torben R.

    2016-02-01

    The closed chamber technique is widely used to measure the exchange of methane (CH4) and carbon dioxide (CO2) from terrestrial ecosystems. There is, however, large uncertainty about which model should be used to calculate the gas flux from the measured gas concentrations. Due to experimental uncertainties the simple linear regression model (first-order polynomial) is often applied, even though theoretical considerations of the technique suggest the application of other, curvilinear models. High-resolution automatic chamber systems which sample gas concentrations several hundred times per flux measurement make it possible to resolve the curvilinear behavior and study the information imposed by the natural variability of the temporal concentration changes. We used more than 50 000 such flux measurements of CH4 and CO2 from five field sites located in peat-forming wetlands ranging from 56 to 78° N to quantify the typical differences between flux estimates of different models. In addition, we aimed to assess the curvilinearity of the concentration time series and test the general applicability of curvilinear models. Despite significant episodic differences between the calculated flux estimates, the overall differences are generally found to be smaller than the local flux variability on the plot scale. The curvilinear behavior of the gas concentrations within the chamber is strongly influenced by wind-driven chamber leakage, and less so by changing gas concentration gradients in the soil during chamber closure. Such physical processes affect both gas species equally, which makes it possible to isolate biochemical processes affecting the gases differently, such as photosynthesis limitation by chamber headspace CO2 concentrations under high levels of incoming solar radiation. We assess the possibility to exploit this effect for a partitioning of the net CO2 flux into photosynthesis and ecosystem respiration as an example of how high-resolution automatic chamber

  15. MONGOLS OF THE TWENTIETH CENTURY, PART II. URALIC AND ALTAIC SERIES, VOLUME 37, PART 2.

    ERIC Educational Resources Information Center

    RUPEN, ROBERT A.

    THIS BIBLIOGRAPHY DIRECTLY SUPPLEMENTS AND IS INTENDED AS AN INTEGRAL PART OF "MONGOLS OF THE TWENTIETH CENTURY, PART I." THE RANGE OF SUBJECT MATTER, HOWEVER, GOES FAR BEYOND THE SPECIFIC CONCERNS OF THE FIRST VOLUME, COVERING GENERAL AND SPECIFIC BIBLIOGRAPHIES, UNSIGNED REPORTS AND DOCUMENTS, ENCYCLOPEDIAS, OFFICIAL HISTORIES,…

  16. Part 2 of a 4-part series Hair Products: Trends and Alternatives

    PubMed Central

    Jacob, Sharon; Katta, Rajani; Nedorost, Susan; Warshaw, Erin; Zirwas, Matt; Bhinder, Manpreet

    2011-01-01

    Objective: To provide updated data on usage of ingredients that are common potential contact allergens in several categories of hair products. To identify useful alternative products with few or no common contact allergens. Design: In November 2009, the full ingredient lists of 5,416 skin, hair, and cosmetic products marketed by the CVS pharmacy chain was copied from CVS.com into Microsoft Word format for analysis. Computer searches were made in Microsoft Word using search/replace and sorting functions to accurately identify the presence of specific allergens in each website product. Measurements: Percentages of American Contact Dermatitis Society core series allergens (and other common preservatives and sunblocks) were calculated. Results: The usage of American Contact Dermatitis Society core series allergens (and other preservatives and sunblocks) in hair products is reported. Conclusion: Data on allergens and alternatives for hair products is not widely published. This article reviews some of the common potential allergens in hair products, including shampoos, conditioners, and styling products. Suitable available alternative products for patients with contact allergy are listed. PMID:21779419

  17. Part 3 of a 4-part series Lip and Common Dental Care Products: Trends and Alternatives

    PubMed Central

    Jacob, Sharon; Katta, Rajani; Nedorost, Susan; Warshaw, Erin; Zirwas, Matt; Kruk, Ann

    2011-01-01

    Objective: To provide updated data on the use of ingredients that are common potential contact allergens in several categories of lip and oral products. To identify useful alternative products with few or no common contact allergens. Design: In November 2009, the full ingredient lists of 5,416 skin, hair, and cosmetic products marketed by the CVS pharmacy chain was copied from CVS.com into Microsoft Word format for analysis. Computer searches were made in Microsoft Word using search/replace and sorting functions to accurately identify the presence of specific allergens in each website product. Measurements: Percentages of American Contact Dermatitis Society core series allergens (and other common preservatives) were calculated. Results: The use of American Contact Dermatitis Society core series allergens (and other preservatives) in various categories of lip and oral products are reported. Conclusion: Data on allergens and alternatives for lip and oral products is not widely published. This article reviews some of the common potential allergens in lip liners, lipsticks, lip moisturizers, mouthwashes, and toothpastes. Suitable available alternative products for patients with contact allergy are listed. PMID:21938270

  18. Part 1 of a 4-part series Facial Cosmetics: Trends and Alternatives

    PubMed Central

    Jacob, Sharon; Katta, Rajani; Nedorost, Susan; Warshaw, Erin; Zirwas, Matt; Cha, Christina

    2011-01-01

    Objective: To provide updated data on usage of ingredients that are common potential contact allergens in several categories of facial cosmetics. To identify useful alternative products with few or no common contact allergens. Design: In November 2009, the full ingredient lists of 5,416 skin, hair, and cosmetic products marketed by the CVS pharmacy chain were copied from CVS.com into Microsoft Word format for analysis. Computer searches were made in Microsoft Word using search/replace and sorting functions to accurately identify the presence of specific allergens in each website product. Measurements: Percentages of American Contact Alternatives Group core series allergens were calculated. Results: The usage of American Contact Alternatives Group core series allergens in facial cosmetics is reported along with suitable alternative products for individuals with contact allergy. Conclusion: Data on allergen usage and alternatives for facial cosmetics is not widely published. This article reviews some of the common potential allergens in facial cosmetics, including blushers and bronzers, concealers, eyeliners, eyeshadows, foundations, loose and pressed powders, and mascaras. Suitable available alternative products for patients with contact allergy are listed. PMID:21779413

  19. Lecture Series "Boundary Layer Theory". Part I - Laminar Flows. Part 1; Laminar Flows

    NASA Technical Reports Server (NTRS)

    Schlichting, H.

    1949-01-01

    In the lecture series starting today author want to give a survey of a field of aerodynamics which has for a number of years been attracting an ever growing interest. The subject is the theory of flows with friction, and, within that field, particularly the theory of friction layers, or boundary layers. A great many considerations of aerodynamics are based on the ideal fluid, that is the frictionless incompressibility and fluid. By neglect of compressibility and friction the extensive mathematical theory of the ideal fluid, (potential theory) has been made possible. Actual liquids and gases satisfy the condition of incomressibility rather well if the velocities are not extremely high or, more accurately, if they are small in comparison with sonic velocity. For air, for instance, the change in volume due to compressibility amounts to about 1 percent for a velocity of 60 meters per second. The hypothesis of absence of friction is not satisfied by any actual fluid; however, it is true that most technically important fluids, for instance air and water, have a very small friction coefficient and therefore behave in many cases almost like the ideal frictionless fluid. Many flow phenomena, in particular most cases of lift, can be treated satisfactorily, - that is, the calculations are in good agreement with the test results, -under the assumption of frictionless fluid. However, the calculations with frictionless flow show a very serious deficiency; namely, the fact, known as d'Alembert's paradox, that in frictionless flow each body has zero drag whereas in actual flow each body experiences a drag of greater or smaller magnitude. For a long time the theory has been unable to bridge this gap between the theory of frictionless flow and the experimental findings about actual flow. The cause of this fundamental discrepancy is the viscosity which is neglected in the theory of ideal fluid; however, in spite of its extraordinary smallness it is decisive for the course of the flow

  20. Getting "Ready" for an Emergency: Emergency Preparedness Series--Part 3

    ERIC Educational Resources Information Center

    Apel, Laura

    2009-01-01

    This article presents part 3 of a series of articles giving timely information about potential emergency situations and offering suggestions and new technology that exceptional families can use to prepare for emergencies--everything from localized to large scale emergencies, everything from natural disasters to terrorist attacks. In 2003 the…

  1. Up with methane

    SciTech Connect

    Barlaz, M.A.; Milke, M.W.; Ham, R.K.

    1986-12-01

    Methane production from municipal refuse represents a rapidly developing source of energy which remains underutilized. Part of the problem is the small amount of methane which is typically collected relative to the refuse's methane generation potential. This study was undertaken to define the parameters which affect the onset of methane production and methane yields in sanitary landfills. Ultimately, we need to develop refuse disposal methods which enhance its methane production potential. Included in the study were tests of how introduction of old refuse, use of sterile cover soil, addition of acetate to refuse, and use of leachate, recycling and neutralization affect methane generation. A more thorough understanding of how the microbes present in refuse react to different variables is the first step in the development of techniques for stimulating methane production in sanitary landfills.

  2. Transcontinental methane measurements: Part 1. A mobile surface platform for source investigations

    NASA Astrophysics Data System (ADS)

    Farrell, Paige; Culling, Daniel; Leifer, Ira

    2013-08-01

    The potent greenhouse gas, methane, CH4, originates from a wide range of anthropogenic and natural sources. A ground-based, satellite-scale, transcontinental (Florida to California) survey was conducted to understand better emissions from key sources including wetlands, forest fire, and geologic sources, as well as to acquire desert background values and lower atmosphere vertical profiling in the San Bernardino Mountains. A total of 6600 measurements along 7020 km of roadways were made by flame ion detection, gas chromatography (GC) onboard a recreational vehicle in 2010, and during a second survey with a cavity ring-down spectrometer system in Southern California in 2012. Significant vibration reduction efforts allowed near continuous mobile GC measurements. Nocturnal CH4 measurements tended to be higher compared to daytime values, sometime significantly, for similar sources and were concluded due to day/night meteorological differences. The lowest GC observations were 1.80 ppm, observed in the California desert, ˜60 ppb less than minimum desert CH4 observed in 2012. Thanks to smoke visualization of a brush fire plume, the flux from the fire was estimated at 0.15 kiloton day-1. Geologic CH4 emissions from the La Brea tar pit and surrounding areas were surprisingly strong, with peak concentrations of nearly 50 ppm and highly elevated CH4 concentrations extending over at least ˜100 km2, and accounting potentially for a significant fraction of the LA basin CH4 emissions. Geologic CO2 emissions also were observed.

  3. Measuring In situ Dissolved Methane Concentrations in Gas Hydrate-Rich Systems. Part 2: Investigating Mechanisms Controlling Hydrate Dissolution

    NASA Astrophysics Data System (ADS)

    Wilson, R. M.; Lapham, L.; Riedel, M.; Chanton, J.

    2010-12-01

    Methane is a potent greenhouse gas, twenty times more infrared-active than CO2, and an important energy source. For these reasons, methane hydrate, one of the largest potential reservoirs of methane on earth, is of considerable interest to scientists and industry alike. In particular, questions relating to the stability of methane hydrate are becoming more important as concern about the release of methane into overlying ocean (and eventually the atmosphere) and interest in the recovery of methane from this resource increase. Three primary factors control hydrate stability: pressure (P), temperature (T), and the gas concentration in the surrounding environment. Pressure and temperature govern the stability of the hydrate structure. When hydrate is exposed to P/T regimes outside of the stability zone (HSZ), the hydrate decomposes by dissociation, a relatively fast process resulting in the release of gaseous phase methane (CH4(g)). However, if the P/T regime is within the HSZ, but the concentration of the guest gas (typically CH4) in the surroundings is below saturation, the hydrate will decompose by dissolution resulting in a phase change between hydrate and the dissolved gas phase (CH4(aq)). OsmoSamplers were deployed at a methane hydrate outcrop in Barkley Canyon, Northern Cascadia Margin, collecting porewater samples in a gradient at 1cm increments away from the hydrate surface. Methane, ethane, and propane concentrations in the porewater samples were measured at 6-day resolution over a period of 9 months. At three centimeters from the hydrate face, methane concentrations were significantly lower than predicted saturation for conditions at this site. Curiously, in situ observations of natural hydrate dissolution are up to two orders of magnitude lower than predicted diffusion-controlled dissolution based on surrounding methane concentrations. Since diffusion of methane away from the hydrate surface has been implicated as the dominant control of hydrate dissolution

  4. Characterizing Methane Emissions at Local Scales with a 20 Year Total Hydrocarbon Time Series, Imaging Spectrometry, and Web Facilitated Analysis

    NASA Astrophysics Data System (ADS)

    Bradley, Eliza Swan

    Methane is an important greenhouse gas for which uncertainty in local emission strengths necessitates improved source characterizations. Although CH4 plume mapping did not motivate the NASA Airborne Visible InfraRed Imaging Spectrometer (AVIRIS) design and municipal air quality monitoring stations were not intended for studying marine geological seepage, these assets have capabilities that can make them viable for studying concentrated (high flux, highly heterogeneous) CH4 sources, such as the Coal Oil Point (COP) seep field (˜0.015 Tg CH4 yr-1) offshore Santa Barbara, California. Hourly total hydrocarbon (THC) data, spanning 1990 to 2008 from an air pollution station located near COP, were analyzed and showed geologic CH4 emissions as the dominant local source. A band ratio approach was developed and applied to high glint AVIRIS data over COP, resulting in local-scale mapping of natural atmospheric CH4 plumes. A Cluster-Tuned Matched Filter (CTMF) technique was applied to Gulf of Mexico AVIRIS data to detect CH4 venting from offshore platforms. Review of 744 platform-centered CTMF subsets was facilitated through a flexible PHP-based web portal. This dissertation demonstrates the value of investigating municipal air quality data and imaging spectrometry for gathering insight into concentrated methane source emissions and highlights how flexible web-based solutions can help facilitate remote sensing research.

  5. Wavelet Analysis of the Periodicity and Correlation of the 420-ka Temperature, Carbon Dioxide, and Methane Time Series from the Vostok Ice Core

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Huang, S.

    2010-12-01

    A good understanding of the history of Earth’s surface temperature and the excursion of atmospheric greenhouse gas composition is of crucial importance in reasoning the course and causes of climate change. However, identifying the variation and correspondence of different climate variables has been a challenging task due to the noisy, complex, and non-linear nature of paleoclimate records. Here we use wavelet technique to revisit the 420-ka temperature, carbon dioxide, and methane records from the ice core of Vostok station in East Antarctica [Petit et al., 1999, Nature, 399, 429] for the periodicity of and the correlation among these three variables. As with many other paleoclimate records, the sampling intervals of the Vostok records are different from variable to variable and from time to time. To allow for the application of continuous Morlet wavelet transform, cross-wavelet transform, and cross-wavelet coherence techniques, all three records were interpolated into 500-year equal interval time series with a cubic polynomial interpolation scheme. All three time series demonstrate the orbital eccentricity oscillation of about 100-ka as the most significant period with a lengthening trend towards the present day. Another periodicity common to all three records is the orbital tilt period of about 41 ka. However, the about 21 ka precession period can only be identified in the methane time series in the Morlet wavelet power spectrum. Our analysis further shows that temperature, CO2, and CH4 are well correlated, whereas the linkage of temperature with CO2 is stranger than that of temperature with CH4 and CO2 with CH4. In pairwise cross-wavelet transform and cross-wavelet coherence diagrams, almost all significant sections show in-phase correlations. Generally, the fluctuations of CO2 and CH4 appear to be either in sync with or slightly led by temperature variation, although there are isolated slots of millennium scales when the temperature - greenhouse gas

  6. IUPAC-NIST Solubility Data Series. 95. Alkaline Earth Carbonates in Aqueous Systems. Part 2. Ca

    SciTech Connect

    De Visscher, Alex; Vanderdeelen, Jan

    2012-06-15

    The alkaline earth carbonates are an important class of minerals. This article is part of a volume in the IUPAC-NIST Solubility Data Series that compiles and critically evaluates solubility data of the alkaline earth carbonates in water and in simple aqueous electrolyte solutions. Part 1 outlined the procedure adopted in this volume, and presented the beryllium and magnesium carbonates. Part 2, the current paper, compiles and critically evaluates the solubility data of calcium carbonate. The chemical forms included are the anhydrous CaCO{sub 3} types calcite, aragonite, and vaterite, the monohydrate monohydrocalcite (CaCO{sub 3}{center_dot} H{sub 2}O), the hexahydrate ikaite (CaCO{sub 3}{center_dot}6H{sub 2}O), and an amorphous form. The data were analyzed with two model variants, and thermodynamic data of each form consistent with each of the models and with the CODATA key values for thermodynamics are presented.

  7. Water Under Fire: A Seven Part Video Series on Canada's Water

    NASA Astrophysics Data System (ADS)

    Mrazek, R.; Byrne, J.; Rabe, N.; Gallant, G.

    2003-12-01

    Canada's water is under escalating pressure from a host of threats. Increasingly, our water is being tainted, misused and over allocated. Experts have identified a multitude of threats to water quantity and quality. Among them, climate change impacts on water supply, and the effects of pesticides, pathogens, industrial waste, urban runoff, and rising demands. These and other threats are the roots to a serious shortage of high quality, safe water sources. In the 1990s, waterborne diseases have re-emerged as one of the primary health issues on a national and global scale. This seven-part video series brings science voices together and provides a nationwide context. The first six programs in the series explore regional concerns: Rocky Mountains, Prairie Waters, Northern Waters, Great Lakes Basin, St. Lawrence and Atlantic Canada. The final program covers the national and international perspectives.

  8. Selective desorption of carbon dioxide from sewage sludge for in situ methane enrichment--Part II: Modelling and evaluation of experiments.

    PubMed

    Lindberg, Anna; Rasmuson, Ake C

    2007-08-01

    In situ methane enrichment in anaerobic digestion of sewage sludge has been investigated by experiments and by modelling. Sludge from a full scale digester was fed to a pilot scale bubble column having 0.3 m diameter for preferential desorption of carbon dioxide. In this second part, a model describing the steady-state performance of the bubble column for desorption of carbon dioxide and methane has been developed. The column is assumed to operate in the homogeneous flow regime, and with respect to carbon dioxide and methane both phases are described by the axial dispersion model. The model treats the chemical reaction equilibrium between carbon dioxide and bicarbonate as being slow and the bicarbonate concentration as being constant. The model is correlated to previously reported experimental results to determine the liquid side mass transfer coefficient in each experiment. A simple power law model is used to correlate the mass transfer coefficient to the gas flow rate. In general, the model allows for a reasonable qualitative description of the behaviour of the bubble column performance but the quantitative agreement with experimental results is not satisfactory. It is believed, though that the main problem is actually not in the model but is related to experimental uncertainties concerning inlet concentrations of liquid phase methane and bicarbonate.

  9. Calculations of automatic chamber flux measurements of methane and carbon dioxide using short time series of concentrations

    NASA Astrophysics Data System (ADS)

    Pirk, N.; Mastepanov, M.; Parmentier, F.-J. W.; Lund, M.; Crill, P.; Christensen, T. R.

    2015-09-01

    The closed chamber technique is widely used to measure the exchange of methane (CH4) and carbon dioxide (CO2) from terrestrial ecosystems. There is, however, large uncertainty about which model should be used to calculate the gas flux from the measured gas concentrations. Due to experimental uncertainties the robust linear regression model (first order polynomial) is often applied, even though theoretical considerations of the technique suggest the application of other, curvilinear models. High-resolution automatic chamber systems which sample gas concentrations several hundred times per flux measurement make it possible to resolve the curvilinear behavior and study the information imposed by the natural variability of the temporal concentration changes. We used more than 50 000 such flux measurements of CH4 and CO2 from five field sites located in peat forming wetlands to calculate fluxes with different models. The flux differences from independent linear estimates are generally found to be smaller than the local flux variability on the plot scale. The curvilinear behavior of the gas concentrations within the chamber is strongly influenced by wind driven chamber leakage, and less so by changing gas concentration gradients in the soil during chamber closure. Such physical processes affect both gas species equally, which makes it possible to isolate biochemical processes affecting the gases differently, such as photosynthesis limitation by chamber headspace CO2 concentrations under high levels of incoming solar radiation. We assess the possibility to exploit this effect for a partitioning of the net CO2 flux into photosynthesis and ecosystem respiration and argue that high-resolution automatic chamber measurements could be used for purposes beyond the estimation of the net gas flux.

  10. ZnO Functionalization of Multi-walled Carbon Nanotubes for Methane Sensing at Single Parts Per Million Concentration Levels

    EPA Science Inventory

    This paper presents a novel atomic layer deposition (ALD) based ZnO functionalization of surface pre-treated multi-walled carbon nanotubes (MWCNTs) for highly sensitive methane chemoresistive sensors. The temperature optimization of the ALD process leads to enhanced ZnO nanopart...

  11. (Atmospheric methane research program for a study in China)

    SciTech Connect

    Not Available

    1991-01-01

    The most significant results of recent research are the findings (1) that methane emissions from rice paddies are strongly dependent on the soil temperature, and (2) that the fluxes of methane from the Chinese rice paddies are up to 10 times greater on average compared with fluxes from rice paddies in other parts of the world. In addition to the main findings there are a number of other significant results. These are: (1) the extension of a time series of concentrations of methane (and also of other gases) at Minqin. The data now span sufficiently long times to estimate trends and seasonal variations and to include Minqin in our global flask sampling network. (2) We have completed further work on bio-gas pits. (3) We have also measured methane in Beijing and found relatively low concentrations for an urban area. 8 figs.

  12. The SPASIBA force field of aldehydes. Part I: Structure and vibrational wavenumbers of methanal, ethanal and propanal

    NASA Astrophysics Data System (ADS)

    Zanoun, A.; Durier, V.; Belaidi, A.; Vergoten, G.

    1999-02-01

    The SPASIBA vibrational spectroscopic force field has been developed for the aldehyde function. The tested molecules are methanal, ethanal, propanal and some of their deuterated analogues. The parameters have been obtained by fitting calculated and observed vibrational wavenumbers. A set of 34 independant force constants has been found to correctly describe the structure and vibrational spectra. The average error between predicted and observed vibrational wavenumber is 16 cm -1.

  13. The 1992-1993 advanced design program. Part 1: The Mars methane engine project. Part 2: The Mars oxygen processor new furnace

    NASA Technical Reports Server (NTRS)

    Lauer, Stephen; Hoover, Scott; Lawrence, Lori; Paparistodemou, Christos; Taylor, Doug

    1993-01-01

    Three constituents of the Martian atmosphere, methane, carbon dioxide, and oxygen, can be used for internal combustion in engines utilized for future space exploration on Mars. These three gases, considered as the test case in this research, will be examined to determine required flow rates needed for combustion and optimization of engine performance. Results of the test case are examined in relation to a base case of methane and air for comparative purposes. Testing of exhaust temperatures, cylinder pressure, and exhaust gas analysis were performed for the base case and test case. Also described is a study utilizing a zirconia cell to convert carbon dioxide into usable oxygen to help support future Mars missions.

  14. The 1992-1993 advanced design program. Part 1: The Mars methane engine project. Part 2: The Mars oxygen processor new furnace

    NASA Astrophysics Data System (ADS)

    Lauer, Stephen; Hoover, Scott; Lawrence, Lori; Paparistodemou, Christos; Taylor, Doug

    1993-04-01

    Three constituents of the Martian atmosphere, methane, carbon dioxide, and oxygen, can be used for internal combustion in engines utilized for future space exploration on Mars. These three gases, considered as the test case in this research, will be examined to determine required flow rates needed for combustion and optimization of engine performance. Results of the test case are examined in relation to a base case of methane and air for comparative purposes. Testing of exhaust temperatures, cylinder pressure, and exhaust gas analysis were performed for the base case and test case. Also described is a study utilizing a zirconia cell to convert carbon dioxide into usable oxygen to help support future Mars missions.

  15. Methane formation and methane oxidation by methanogenic bacteria.

    PubMed Central

    Zehnder, A J; Brock, T D

    1979-01-01

    Methanogenic bacteria were found to form and oxidize methane at the same time. As compared to the quantity of methane formed, the amount of methane simultaneously oxidized varied between 0.3 and 0.001%, depending on the strain used. All the nine tested strains of methane producers (Methanobacterium ruminantium, Methanobacterium strain M.o.H., M. formicicum, M. thermoautotrophicum, M. arbophilicum, Methanobacterium strain AZ, Methanosarcina barkeri, Methanospirillum hungatii, and the "acetate organism") reoxidized methane to carbon dioxide. In addition, they assimilated a small part of the methane supplied into cell material. Methanol and acetate also occurred as oxidation products in M. barkeri cultures. Acetate was also formed by the "acetate organism," a methane bacterium unable to use methanogenic substrates other than acetate. Methane was the precursor of the methyl group of the acetate synthesized in the course of methane oxidation. Methane formation and its oxidation were inhibited equally by 2-bromoethanesulfonic acid. Short-term labeling experiments with M. thermoautotrophicum and M. hungatii clearly suggest that the pathway of methane oxidation is not identical with a simple back reaction of the methane formation process. Images PMID:762019

  16. Time-series analysis for the episodic production and transport of methane from the Glacial Lake Agassiz peatlands, northern Minnesota. Final report

    SciTech Connect

    Siegel, D.I.

    1998-01-01

    The large peat basins of North America are an important reservoir in the global carbon cycle and a significant source of atmospheric methane. The authors investigated carbon cycling in the Glacial Lake Agassiz peatlands (GLAP) of Minnesota. Initially in 1990, they identified a dramatic change in the concentration of methane in the pore-waters of the raised bogs in the GLAP during an extreme drought. This methane dissipated when the drought broke in 1991 and the occurrence of deep methane is related to changes in the direction of groundwater flow in the peat column. The production of methane and its diffusive loss to the atmosphere was modeled and was about 10 times less than that measured directly in chambers at the land surface. It is clear from the reversals in hydraulic heat, changes in pore-water chemical composition over time, and paleostratigraphic markers, that regional ground water flow systems that are controlled by climate change are unexpectedly a major control over methanogenesis and carbon cycling in GLAP. Seismic profiles made showed that buried bedrock ridges particularly deflect regional groundwater flow upwards towards the land surface and towards raised bog landforms. In addition, high-resolution GPS measurements from data stations funded by this DOE project have shown this year that the peakland land surface elevation changes daily on a scale of cms, and seasonally on a scale of 10s of cm. This most recent observation is exciting because it may reflect episodic degassing of free phase methane from the peat column to the atmosphere, a source for methane previously unaccounted for by methane researchers.

  17. Accounting Issues: An Essay Series Part I--Introduction to Accounting Theory and Cash

    ERIC Educational Resources Information Center

    Laux, Judy

    2007-01-01

    Recent accounting scandals challenge academics to refocus the educational process on the theoretical underpinnings of accounting. This is the first in a series of articles designed to facilitate this realignment. Intended as a supplement for the introductory accounting course, the essay series connects each of the primary accounting elements to…

  18. Methane Emission by Camelids

    PubMed Central

    Dittmann, Marie T.; Runge, Ullrich; Lang, Richard A.; Moser, Dario; Galeffi, Cordula; Kreuzer, Michael; Clauss, Marcus

    2014-01-01

    Methane emissions from ruminant livestock have been intensively studied in order to reduce contribution to the greenhouse effect. Ruminants were found to produce more enteric methane than other mammalian herbivores. As camelids share some features of their digestive anatomy and physiology with ruminants, it has been proposed that they produce similar amounts of methane per unit of body mass. This is of special relevance for countrywide greenhouse gas budgets of countries that harbor large populations of camelids like Australia. However, hardly any quantitative methane emission measurements have been performed in camelids. In order to fill this gap, we carried out respiration chamber measurements with three camelid species (Vicugna pacos, Lama glama, Camelus bactrianus; n = 16 in total), all kept on a diet consisting of food produced from alfalfa only. The camelids produced less methane expressed on the basis of body mass (0.32±0.11 L kg−1 d−1) when compared to literature data on domestic ruminants fed on roughage diets (0.58±0.16 L kg−1 d−1). However, there was no significant difference between the two suborders when methane emission was expressed on the basis of digestible neutral detergent fiber intake (92.7±33.9 L kg−1 in camelids vs. 86.2±12.1 L kg−1 in ruminants). This implies that the pathways of methanogenesis forming part of the microbial digestion of fiber in the foregut are similar between the groups, and that the lower methane emission of camelids can be explained by their generally lower relative food intake. Our results suggest that the methane emission of Australia's feral camels corresponds only to 1 to 2% of the methane amount produced by the countries' domestic ruminants and that calculations of greenhouse gas budgets of countries with large camelid populations based on equations developed for ruminants are generally overestimating the actual levels. PMID:24718604

  19. Methane emission by camelids.

    PubMed

    Dittmann, Marie T; Runge, Ullrich; Lang, Richard A; Moser, Dario; Galeffi, Cordula; Kreuzer, Michael; Clauss, Marcus

    2014-01-01

    Methane emissions from ruminant livestock have been intensively studied in order to reduce contribution to the greenhouse effect. Ruminants were found to produce more enteric methane than other mammalian herbivores. As camelids share some features of their digestive anatomy and physiology with ruminants, it has been proposed that they produce similar amounts of methane per unit of body mass. This is of special relevance for countrywide greenhouse gas budgets of countries that harbor large populations of camelids like Australia. However, hardly any quantitative methane emission measurements have been performed in camelids. In order to fill this gap, we carried out respiration chamber measurements with three camelid species (Vicugna pacos, Lama glama, Camelus bactrianus; n = 16 in total), all kept on a diet consisting of food produced from alfalfa only. The camelids produced less methane expressed on the basis of body mass (0.32±0.11 L kg⁻¹ d⁻¹) when compared to literature data on domestic ruminants fed on roughage diets (0.58±0.16 L kg⁻¹ d⁻¹). However, there was no significant difference between the two suborders when methane emission was expressed on the basis of digestible neutral detergent fiber intake (92.7±33.9 L kg⁻¹ in camelids vs. 86.2±12.1 L kg⁻¹ in ruminants). This implies that the pathways of methanogenesis forming part of the microbial digestion of fiber in the foregut are similar between the groups, and that the lower methane emission of camelids can be explained by their generally lower relative food intake. Our results suggest that the methane emission of Australia's feral camels corresponds only to 1 to 2% of the methane amount produced by the countries' domestic ruminants and that calculations of greenhouse gas budgets of countries with large camelid populations based on equations developed for ruminants are generally overestimating the actual levels.

  20. Legal Issues Relating to Part-Time Faculty Employment. Occasional Paper Series No. 6.

    ERIC Educational Resources Information Center

    Head, Ronald B.

    Summarized from a national study of part-time college faculty employment are the legal developments that affect the rights of part-time faculty. The part-timer has long been a marginal employee in academe, but recent developments in the law clarify the degree to which he holds some measure of job security, rights to equal pay, and the protections…

  1. Edited Excerpts from a Smithsonian Seminar Series--Part 3: The Humanities and Social Sciences.

    ERIC Educational Resources Information Center

    Borden, Carla M., Ed.; And Others

    1992-01-01

    The third article in a series of excerpts from seminars sponsored by the Smithsonian Institution on knowledge collaboration focuses on the humanities and social sciences. Reasons for the relatively greater frequency of collaborative research in the natural sciences are examined, and examples of collaborative projects in the humanities and social…

  2. Mounting Pressures on Planet Earth. A Four-Part Bicentennial Symposium Series.

    ERIC Educational Resources Information Center

    Anderton, David A., Ed.

    Detailed are the proceedings of the 1976 Bicentennial Symposium Series held under the general title of Mounting Pressures on Planet Earth. This event, co-sponsored by the Maryland State Department of Education and the NASA Goddard Space Flight Center, brought together researchers and educators to discuss solutions to the Earth's problems. The…

  3. Accounting Issues: An Essay Series Part IV--Property, Plant, & Equipment

    ERIC Educational Resources Information Center

    Laux, Judy

    2007-01-01

    This fourth article in a series of theoretical essays intended to supplement the introductory financial accounting course is dedicated to the topic of property, plant, and equipment (PP&E), including both the accounting treatment and its related conceptual connections. The paper also addresses the measurement dilemmas, scandalous accounting…

  4. Accounting Issues: An Essay Series Part IX--Statement of Cash Flows

    ERIC Educational Resources Information Center

    Laux, Judy

    2009-01-01

    This essay series, beginning with Laux [2007a], defends the proposition that eliminating the theoretical chapter from the principles level accounting course has weakened the introduction for students new to this subject, perhaps resulting in some adverse selection for the accounting profession. As a remedy, it offers concise theoretical articles…

  5. Accounting Issues: An Essay Series Part VI--Investments in Securities

    ERIC Educational Resources Information Center

    Laux, Judy

    2008-01-01

    The sixth in a series of theory-based essays, this article presents accounting for investments in debt and equity securities along with some related conceptual and measurement issues. Additional coverage is devoted to potential ethical dilemmas and both theoretical and empirical literature related to this asset. (Contains 1 footnote.)

  6. NASPE Developed Informational Products and Applications. Article #4 in a 4-Part Series

    ERIC Educational Resources Information Center

    Fisette, Jennifer L.; Placek, Judith H.; Avery, Marybell; Dyson, Ben; Fox, Connie; Franck, Marian; Graber, Kim; Rink, Judith; Zhu, Weimo

    2009-01-01

    This is the fourth and final article in the "PE Metrics" series that focuses on assessing the National Standards for Physical Education (NASPE) for Standard 1. The first article focused on assessment of student learning. The second described formative and summative assessments and provided considerations on how to implement assessment within…

  7. Instructional Considerations for Implementing Student Assessments. Article #2 in a 4-part series

    ERIC Educational Resources Information Center

    Fisette, Jennifer L.; Placek, Judith H.; Avery, Marybell; Dyson, Ben; Fox, Connie; Franck, Marian; Graber, Kim; Rink, Judith; Zhu, Weimo

    2009-01-01

    The first article of the PE Metrics series, "Developing Quality Physical Education through Student Assessments" (January/February 2009 "Strategies" issue) focused on the importance of assessing student learning in relation to NASPE's content standards (NASPE, 2004). The article emphasized that unless students are appropriately assessed, it is…

  8. Cooperation in Japan. Grades Kindergarten-Third. Elementary Literature Series, Part 1.

    ERIC Educational Resources Information Center

    Mukai, Gary

    The Stanford Program on International and Cross-Cultural Education (SPICE) represents a long-term effort by Stanford University to improve international and cross-cultural education in elementary and secondary schools. This volume of the elementary literature series focuses on the primary grades; utilizes primary source literature from Japan;…

  9. Culture Shock: A Teacher's Guide To Accompany the Four-Part PBS Series Premiering January 2000.

    ERIC Educational Resources Information Center

    Jaffee, Cyrisse, Ed.; Sharma, Amina, Ed.

    This teacher's guide accompanies the four videos ("Born to Trouble: Adventures of Huckleberry Finn"; "The Shock of the Nude: Manet's Olympia"; "Hollywood Censored: Movies, Morality and the Production Code"; and "The Devil's Music: 1920s Jazz") of the PBS "Culture Shock" series. The guide suggests that the videos could be used in the…

  10. Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water

    SciTech Connect

    Kirchman, David L.

    2012-03-29

    The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (Methane in the Arctic Shelf or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (metagenomes ). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in

  11. Part-Time Occupational Faculty: A Contribution to Excellence. Information Series No. 300.

    ERIC Educational Resources Information Center

    Parsons, Michael H.

    Part-time faculty are essential to the accomplishment of the mission of postsecondary occupational education institutions. A commitment to excellence requires a comprehensive, systematic design for part-time faculty recruitment, development, assessment, and integration into the institution's delivery system. Careful attention to recruitment…

  12. Plagioclase in the Skaergaard intrusion. Part 1: Core and rim compositions in the layered series

    NASA Astrophysics Data System (ADS)

    Toplis, Michael J.; Brown, William L.; Pupier, Elsa

    2008-03-01

    The anorthite content of plagioclase grains (XAn) in 12 rocks from the layered series of the Skaergaard intrusion has been studied by electron microprobe (typically ˜30 core and ˜70 rim analyses per thin section). Mean core compositions vary continuously from An66 at the base of the layered series (LZa) to An32-30 at the top. On the other hand, crystal rims are of approximately constant composition (An50 ± 1) from the LZa to the lower Middle Zone (MZ). Above the MZ, core and rim compositions generally overlap. Profiles across individual plagioclase grains from the lower zone show that most crystals have an external zone buffered at XAn ˜50 ± 1. The simplest explanation for these features is that during postcumulus crystallization in the lower zone, interstitial liquids passed through a density maximum. This interpretation is consistent with proposed liquid lines of descent that predict silica enrichment of the liquid associated with the appearance of cumulus magnetite.

  13. Developing receptor-oriented methods for non-methane hydrocarbon characterisation in urban air. Part II: source apportionment

    NASA Astrophysics Data System (ADS)

    Borbon, Agnès; Fontaine, Hervé; Locoge, Nadine; Veillerot, Marc; Galloo, J. C.

    The methods and the results of non-methane hydrocarbon (NMHC) source apportionment are described at urban scale on a spatial and temporal basis. Here, hourly ambient concentrations of nearly 40 C 2-C 9 NMHC are used. Methods are based on the knowledge of the wintertime NMHC vehicle-exhaust emission ratio generally determined by simple regression analysis taking acetylene, ethylene, propene and 1,3-butadiene as auto-exhaust tracers. The RSD of the estimated source contributions is lower than 20%; the developed receptor-oriented methods are flexible and easily transposable to other areas. In winter, vehicle-exhaust emissions explain 100% of the NMHC majority levels and even isoprene. From May to November, our models revealed the temperature-dependent contribution of additional sources (0.71< r<0.90). On the one hand, the evaporation of fuel and solvent affects the whole C 4-C 9 NMHC fraction, and fluctuates between 20% and 50%, even for a northern France urban area. On the other hand, both vehicle-exhaust and biogenic emissions control the highly photoreactive isoprene distribution whatever the site; the traffic is responsible for a third of its levels in summer. Finally, the particular behaviour of the C 2-C 4 compounds pointed out dominant contributions, generally other than traffic. Suspected sources are numerous: natural gas leakage for ethane and propane, wintertime fuel evaporation for butanes and butenes, non-automotive combustion for ethylene and acetylene. Ethane and propane also showed that long-range advective transport, responsible for background concentrations, could significantly contribute to the hydrocarbon levels with a high atmospheric residence time (from 20% to 50%).

  14. Synchronizable Series Expressions. Part 1. User’s Manual for the OSS Macro Package.

    DTIC Science & Technology

    1987-11-01

    programmers can obtain the advantages of expressing computations as series without incurring any * run-time overhead. %o X ,w A2.. "a 1. All You Need...To Know to Get Started "T [his first section describes everything you need to know to start using the oss macro package. It then presents a detailed...2 -2 3)) 3)) (Rsum (TmapF #’(lambda ( x ) (expt (abs x ) 3)) * (Evector #(2 -2 3)) 43 * Creating OSS variables. V he oSS Iiacro pa~ kage provides two

  15. Options in Education: Program No. 88. Sex and Sexism in Education, Part II. Transcripts of a Weekly Series Broadcast by Member Stations of National Public Radio.

    ERIC Educational Resources Information Center

    National Public Radio, Washington, DC.

    This booklet is a transcription of a program from the radio series, "Options in Education." It is part 2 of a two-part series dealing with sexism in education. It deals with sex discrimination in various aspects of public education, including textbooks, teacher promotion, sports programs and children's literature. There is also a…

  16. An Alternative Approach to Atopic Dermatitis: Part I—Case-Series Presentation

    PubMed Central

    2004-01-01

    Atopic dermatitis (AD) is a complex disease of obscure pathogenesis. A substantial portion of AD patients treated with conventional therapy become intractable after several cycles of recurrence. Over the last 20 years we have developed an alternative approach to treat many of these patients by diet and Kampo herbal medicine. However, as our approach is highly individualized and the Kampo formulae sometimes complicated, it is not easy to provide evidence to establish usefulness of this approach. In this Review, to demonstrate the effectiveness of the method of individualized Kampo therapy, results are presented for a series of patients who had failed with conventional therapy but were treated afterwards in our institution. Based on these data, we contend that there exist a definite subgroup of AD patients in whom conventional therapy fails, but the ‘Diet and Kampo’ approach succeeds, to heal. Therefore, this approach should be considered seriously as a second-line treatment for AD patients. In the Discussion, we review the evidential status of the current conventional strategies for AD treatment in general, and then specifically discuss the possibility of integrating Kampo regimens into it, taking our case-series presented here as evidential basis. We emphasize that Kampo therapy for AD is more ‘art’ than technology, for which expertise is an essential pre-requisite. PMID:15257326

  17. The skaergaard layered series. Part IV. reaction-transport simulations of foundered blocks.

    SciTech Connect

    Sonnenthal, Eric L.; McBirney, Alexander R.

    1996-01-02

    During the middle stages of crystallization of the Skaergaard Layered Series large numbers of blocks became detached from the Upper Border Series and settled into the mush of crystals on the floor. It has been recognized for some time that these blocks now have compositions and textures that differ markedly from those of the units from which they came. They tend to be more plagioclase rich and seem to have lost mafic components to the surrounding gabbro. Numerical simulations coupling crystallization, melting, and heat and mass transfer for a multicomponent system show how the blocks reacted with the mush in which they were emplaced. Enhanced cooling and crystallization of a compositionally stratified mush adjacent to the blocks resulted in patterns of melt compositions similar to those of layering around the blocks. Volume changes during crystallization and melting induced convection of the interstitial melt leading to changes in the bulk compositions of the blocks and the surrounding mush. Inhomogeneities such as inclusions are likely to facilitate the onset of compositional convection in a chemically stratified solidification zone.

  18. Progress report on LLTR Series II Test A-2 (Part 1). [LMFBR

    SciTech Connect

    Freede, W.J.; Neely, H.H.

    1980-01-01

    This document contains a complete set of valid and final digital and analog data plots for LLTR Series II, Test A-2. Included is an Accuracy Statement regarding this data as required by Revision 0 of the GE Test Request, Specification No. 23A2062. The Series II, Sodium-Water Reaction Test A-2 was performed in the Large Leak Test Rig (LLTR) at the Energy Technology Engineering Center (ETEC). This was the third of three planned double-edged guillotine (DEG) rupture tests of a single tube which will be followed by a number of small leak tests. The test article is the LLTI which is a full-size diameter internals, shortened in length and prototypic of the CRBR steam generator. It is installed in the Large Leak Test Vessel (LLTV). The overall test program was formulated by General Electric (GE) as Test Requester to establish steam generator design and to verify analytical models/codes to estimate the effect of large leak accidents in an LMFBR demonstration plant steam generator and system.

  19. Engineering Certification Program Self-Study Course, Construction Inspection - Part II. Engineering Management [Series].

    ERIC Educational Resources Information Center

    Owsley, Fran, Ed.

    This book is a part of a self-study sequence in an engineering certification program. This volume concerns inspection and quality control of concrete structures. Sections titles are Inspection and Quality Control of Concrete; General Guides for Concrete Work; Concrete Floor and Slab Construction; Concrete Formwork; Correct and Incorrect Methods of…

  20. Photophysical Study of a Series of Cyanines Part III. The Direct Photooxidation Reaction

    NASA Astrophysics Data System (ADS)

    Lepaja, Shukri; Strub, Henry; Lougnot, Daniel-Joseph

    1983-01-01

    The main degradative pathway of tricarbocyanine dyes in aerated solutions is demonstrated to be a photooxidation; using sensitization techniques and specific quenchers, this reaction is established to proceed via singlet oxygen for a part, and the site at which this species attacks the polymethinic skeleton is unambiguously determined. The major photoproduct is identified as being 1,3,3-trimethyl-2-indolinone.

  1. 40 CFR Table W - 6 of Subpart W of Part 98-Default Methane Emission Factors for LNG Import and Export Equipment

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Methane Emission Factors for LNG Import and Export Equipment W Table W Protection of Environment...—Default Methane Emission Factors for LNG Import and Export Equipment LNG import and export equipment Emission factor (scf/hour/component) Leaker Emission Factors—LNG Terminals Components, LNG Service Valve...

  2. 40 CFR Table W - 6 of Subpart W of Part 98-Default Methane Emission Factors for LNG Import and Export Equipment

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Methane Emission Factors for LNG Import and Export Equipment W Table W Protection of Environment...—Default Methane Emission Factors for LNG Import and Export Equipment LNG import and export equipment Emission factor (scf/hour/component) Leaker Emission Factors—LNG Terminals Components, LNG Service Valve...

  3. Global Methane Biogeochemistry

    NASA Astrophysics Data System (ADS)

    Reeburgh, W. S.

    2003-12-01

    Methane (CH4) has been studied as an atmospheric constituent for over 200 years. A 1776 letter from Alessandro Volta to Father Campi described the first experiments on flammable "air" released by shallow sediments in Lake Maggiore (Wolfe, 1996; King, 1992). The first quantitative measurements of CH4, both involving combustion and gravimetric determination of trapped oxidation products, were reported in French by Boussingault and Boussingault, 1864 and Gautier (1901), who reported CH4 concentrations of 10 ppmv and 0.28 ppmv (seashore) and 95 ppmv (Paris), respectively. The first modern measurements of atmospheric CH4 were the infrared absorption measurements of Migeotte (1948), who estimated an atmospheric concentration of 2.0 ppmv. Development of gas chromatography and the flame ionization detector in the 1950s led to observations of vertical CH4 distributions in the troposphere and stratosphere, and to establishment of time-series sampling programs in the late 1970s. Results from these sampling programs led to suggestions that the concentration of CH4, as that of CO2, was increasing in the atmosphere. The possible role of CH4 as a greenhouse gas stimulated further research on CH4 sources and sinks. Methane has also been of interest to microbiologists, but findings from microbiology have entered the larger context of the global CH4 budget only recently.Methane is the most abundant hydrocarbon in the atmosphere. It plays important roles in atmospheric chemistry and the radiative balance of the Earth. Stratospheric oxidation of CH4 provides a means of introducing water vapor above the tropopause. Methane reacts with atomic chlorine in the stratosphere, forming HCl, a reservoir species for chlorine. Some 90% of the CH4 entering the atmosphere is oxidized through reactions initiated by the OH radical. These reactions are discussed in more detail by Wofsy (1976) and Cicerone and Oremland (1988), and are important in controlling the oxidation state of the atmosphere

  4. Breaking methane

    PubMed Central

    Rosenzweig, Amy C.

    2015-01-01

    The most powerful oxidant found in nature is compound Q, an enzymatic intermediate that oxidizes methane. New spectroscopic data have resolved the long-running controversy about Q’s chemical structure. PMID:25607367

  5. Harnessing methane

    NASA Astrophysics Data System (ADS)

    Showstack, Randy

    The total methane resource in hydrates—ice-like substances found in deep ocean sediments and Arctic permafrost—exceeds the energy content of all other fossil fuel resources,such as coal, oil, and conventional gas, according to the U.S. Geological Survey (USGS).The Methane Hydrate Research and Development Act, signed into law by U.S. President Bill Clinton on May 3, establishes a new federal commitment to developing methane hydrates, which has been touted as a potentially clean energy source that could make the U.S. less dependent on foreign sources of energy. The bill authorizes $47.5 million over five years for the Department of Energy to establish a federal methane hydrate research and development program.

  6. SeaWiFS technical report series. Volume 28: SeaWiFS algorithms, part 1

    NASA Technical Reports Server (NTRS)

    Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Acker, James G. (Editor); Mcclain, Charles R.; Arrigo, Kevin; Esaias, Wayne E.; Darzi, Michael; Patt, Frederick S.; Evans, Robert H.; Brown, James W.

    1995-01-01

    This document provides five brief reports that address several algorithm investigations sponsored by the Calibration and Validation Team (CVT) within the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project. This volume, therefore, has been designated as the first in a series of algorithm volumes. Chapter 1 describes the initial suite of masks, used to prevent further processing of contaminated radiometric data, and flags, which are employed to mark data whose quality (due to a variety of factors) may be suspect. In addition to providing the mask and flag algorithms, this chapter also describes the initial strategy for their implementation. Chapter 2 evaluates various strategies for the detection of clouds and ice in high latitude (polar and sub-polar regions) using Coastal Zone Color Scanner (CZCS) data. Chapter 3 presents an algorithm designed for detecting and masking coccolithosphore blooms in the open ocean. Chapter 4 outlines a proposed scheme for correcting the out-of-band response when SeaWiFS is in orbit. Chapter 5 gives a detailed description of the algorithm designed to apply sensor calibration data during the processing of level-1b data.

  7. Diseases associated with hidranitis suppurativa: part 2 of a series on hidradenitis.

    PubMed

    Scheinfeld, Noah

    2013-06-15

    Hidradenitis suppurativa (HS), a pathologic follicular disease, impacts patients' lives profoundly and usually occurs in isolation. The diseases with the strongest association are obesity, depression, and pain. HS is associated with many diseases including acne conglobata (AC), dissecting cellulitis, pilonidal cysts, and obesity. Pyoderma fistulans sinifica (fox den disease) appears to be the same entity as Hurley Stage 2 of 3 HS. The rate of acne vulgaris in HS patients mirrors unaffected controls. The most common, albeit still uncommon, association is with seronegative, haplotype unlinked arthritis (most importantly B27), in particular spondolyarthritis. Crohn disease and HS occur together at a rate that varies from 0.6% to 38% in retrospective cases series. Ulcerative colitis occurred with HS in 14% of patients in one series. The next most common association is with pyoderma gangrenosum, but this association is likely under-reported. Synovitis-Acne-Pustulosis Hyperostosis-Osteitis (SAPHO) syndrome, which is rare, has more than 10 reports linking it to HS. Nine case reports have linked Dowling-Degos disease (DDD) to HS and two reports related HS to Fox-Fordyce disease (FF), but because both occur in the axilla this might be a mere coincidence. HS is rarely associated with ophthalmic pathology. Specifically, more than 5 reports link it to Keratitis-Ichthyosis-Deafness syndrome (KID); greater than10 cases link it to interstitial keratitis and 2 cases are linked to Behçet's disease. The presence of proteinuria and acute nephritis link HS to the kidney, especially since and reports have documented resolution of HS after renal transplant. Florid steatocystoma multiplex, Sjogren Syndrome, and HS have been linked and their reports likely underestimate their coincidence because all these entities involve occlusion (albeit by different mechanisms). Three reports link HS and amyloid, but both share some common genetic underpinnings and thus the coincidence of these

  8. Modeling and Measurements of Atmospheric Methane at Four Corners, NM

    NASA Astrophysics Data System (ADS)

    Costigan, K. R.; Lindenmaier, R.; Dubey, M. K.

    2014-12-01

    Methane (CH4) fugitive emissions from fossil energy mining remain highly uncertain and scrutinized with the rapid expansion in domestic production by hydraulic fracturing. Top down observational studies of reported bottom up inventories are limited, but the latter may be biased low. We focus on the Four Corners region of the Southwestern United States, a region with extensive coal bed methane production, to verify its current emissions. At our site we measured methane over a range of scales using ground-based, in-situ instruments and a Fourier Transform Spectrometer (FTS), which is part of the Total Carbon Column Observing Network (TCCON). Measurements of CH4 produced much higher concentrations of methane in this rural area than previously expected. The diurnal variation and wind direction dependence in the CH4 concentrations suggest a source location tied to topographically induced winds and consistent with oil and gas production. This paper presents the results of WRF-Chem simulations that are performed to simulate methane concentrations in this region. Emissions from the Emissions Database for Global Atmospheric Research (EDGAR) indicate large CH4 emissions, associated with the gas production and distribution sector, in one 0.1 x 0.1 degree grid cell within the region and these emissions are employed in the simulations. A series of six simulations are run at two-month intervals during 2012. Each simulates a six-day time series to demonstrate the diurnal and seasonal characteristics of the methane concentrations that would be expected at the FTS location, from the sources reported in the EDGAR data set. The results of these simulations will be presented, along with the implications for interpretation of the FTS measurements. We will also interpret our FTS measurements of ethane (C2H6), which is emitted only from fossil fuel mining, to attribute leaks.

  9. 32 CFR Appendix F to Part 197 - Procedures for Copying of Documents for the Foreign Relations of the United States Series

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Foreign Relations of the United States Series F Appendix F to Part 197 National Defense Department of...—Procedures for Copying of Documents for the Foreign Relations of the United States Series 1. The records will.../declassification and historical research branch staff member must be present at all times. 4. OSD will supply...

  10. Charters, Constitutions and By-Laws of the Indian Tribes of North America. Part XI: The Basin-Plateau Tribes. Occasional Publications in Anthropology, Ethnology Series, No. 12.

    ERIC Educational Resources Information Center

    Fay, George E., Comp.

    The Museum of Anthropology, University of Northern Colorado at Greeley, has assembled various American Indian tribal charters, constitutions, and by-laws to comprise a series of publications. The present volume, Part XI of the series, deals with the Indian tribes of Nevada: The Moapa Band of Paiute Indians, the Pyramid Lake Paiute Tribe, the…

  11. 32 CFR Appendix F to Part 197 - Procedures for Copying of Documents for the Foreign Relations of the United States Series

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 2 2012-07-01 2012-07-01 false Procedures for Copying of Documents for the Foreign Relations of the United States Series F Appendix F to Part 197 National Defense Department of...—Procedures for Copying of Documents for the Foreign Relations of the United States Series 1. The records...

  12. 32 CFR Appendix F to Part 197 - Procedures for Copying of Documents for the Foreign Relations of the United States Series

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 2 2014-07-01 2014-07-01 false Procedures for Copying of Documents for the Foreign Relations of the United States Series F Appendix F to Part 197 National Defense Department of...—Procedures for Copying of Documents for the Foreign Relations of the United States Series 1. The records...

  13. 32 CFR Appendix F to Part 197 - Procedures for Copying of Documents for the Foreign Relations of the United States Series

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 2 2013-07-01 2013-07-01 false Procedures for Copying of Documents for the Foreign Relations of the United States Series F Appendix F to Part 197 National Defense Department of...—Procedures for Copying of Documents for the Foreign Relations of the United States Series 1. The records...

  14. Constraining Methane Flux Estimates Using Atmospheric Observations of Methane and 1^3C in Methane

    NASA Astrophysics Data System (ADS)

    Mikaloff Fletcher, S. E.; Tans, P. P.; Miller, J. B.; Bruhwiler, L. M.

    2002-12-01

    Understanding the budget of methane is crucial to predicting climate change and managing earth's carbon reservoirs. Methane is responsible for approximately 15% of the anthropogenic greenhouse forcing and has a large impact on the oxidative capacity of Earth's atmosphere due to its reaction with hydroxyl radical. At present, many of the sources and sinks of methane are poorly understood due in part to the large spatial and temporal variability of the methane flux. Model simulations of methane mixing ratios using most process-based source estimates typically over-predict the latitudinal gradient of atmospheric methane relative to the observations; however, the specific source processes responsible for this discrepancy have not been identified definitively. The aim of this work is to use the isotopic signatures of the sources to attribute these discrepancies to a source process or group of source processes and create global and regional budget estimates that are in agreement with both the atmospheric observations of methane and 1^3C in methane. To this end, observations of isotopic ratios of 1^3C in methane and isotopic signatures of methane source processes are used in conjunction with an inverse model of the methane budget. Inverse modeling is a top-down approach which uses observations of trace gases in the atmosphere, an estimate of the spatial pattern of trace gas fluxes, and a model of atmospheric transport to estimate the sources and sinks. The atmospheric transport was represented by the TM3 three-dimensional transport model. The GLOBALVIEW 2001 methane observations were used along with flask measurements of 1^3C in methane at six of the CMDL-NOAA stations by INSTAAR. Initial results imply interesting differences from previous methane budget estimates. For example, the 1^3C isotope observations in methane call for an increase in southern hemisphere sources with a bacterial isotopic signature such as wetlands, rice paddies, termites, and ruminant animals. The

  15. Methanation of CO and CO/sub 2/ for heat production

    SciTech Connect

    Arcilla, N.T.; Plumlee, D.E.

    1981-01-01

    This study explores workable CO and CO/sub 2/ methanation systems for process heat as part of a Thermo-Chemical Heat Pipe (TCHP) based on methane reforming. Tested methanator designs and methanation catalyst materials were reviewed to identify those suitable in high temperature, high pressure methanation. 7 refs.

  16. What we mean when we talk about MRD in myeloma. A review of current methods. Part 1 of a two-part series.

    PubMed

    Ely, Scott; Biran, Noa; Chari, Ajai

    2014-12-01

    Assessment of minimal residual disease (MRD) is becoming standard of care for potentially curable cancers, like some leukemias. For diseases not currently curable, like multiple myeloma (MM), the optimal methodology to assess MRD is much less clear, let alone the clinical significance. In this two-part series, we review each of these aspects of MRD in MM. In part 1, we review different methodologies available for MRD assessment, with an emphasis on multiparameter flow cytometry (MFC) and duplex immunohistochemistry. There is currently a strong push in the MM community for the use of MFC, based on studies demonstrating MRD negativity by MFC being associated with delayed time to relapse. After participating in a recent international meeting of leaders in the field, convened to discuss this topic, we review and assess the voiced opinions and published data. While great strides have been made toward the standardization of MFC for MRD, we review not only intrinsic biologic differences between MM and leukemia but also the technical challenges that follow from these differences, including the need for live cells, a difficult to characterize immunophenotype, and significant interlaboratory variability in MFC testing and interpretation.

  17. FACT SHEET: EPAS STRATEGY FOR REDUCING METHANE AND OZONE-FORMING POLLUTION FROM THE OIL AND NATURAL GAS INDUSTRY

    EPA Pesticide Factsheets

    January 14, 2015 -- As part of the Obama Administration's commitment to addressing climate change, the U.S. Environmental Protection Agency (EPA) has outlined a series of steps it plans to take to address methane and smog-forming VOC emissions from the oil

  18. The WAIS Divide deep ice core WD2014 chronology - Part 1: Methane synchronization (68-31 ka BP) and the gas age-ice age difference

    NASA Astrophysics Data System (ADS)

    Buizert, C.; Cuffey, K. M.; Severinghaus, J. P.; Baggenstos, D.; Fudge, T. J.; Steig, E. J.; Markle, B. R.; Winstrup, M.; Rhodes, R. H.; Brook, E. J.; Sowers, T. A.; Clow, G. D.; Cheng, H.; Edwards, R. L.; Sigl, M.; McConnell, J. R.; Taylor, K. C.

    2015-02-01

    The West Antarctic Ice Sheet Divide (WAIS Divide, WD) ice core is a newly drilled, high-accumulation deep ice core that provides Antarctic climate records of the past ∼68 ka at unprecedented temporal resolution. The upper 2850 m (back to 31.2 ka BP) have been dated using annual-layer counting. Here we present a chronology for the deep part of the core (67.8-31.2 ka BP), which is based on stratigraphic matching to annual-layer-counted Greenland ice cores using globally well-mixed atmospheric methane. We calculate the WD gas age-ice age difference (Δage) using a combination of firn densification modeling, ice-flow modeling, and a data set of δ15N-N2, a proxy for past firn column thickness. The largest Δage at WD occurs during the Last Glacial Maximum, and is 525 ± 120 years. Internally consistent solutions can be found only when assuming little to no influence of impurity content on densification rates, contrary to a recently proposed hypothesis. We synchronize the WD chronology to a linearly scaled version of the layer-counted Greenland Ice Core Chronology (GICC05), which brings the age of Dansgaard-Oeschger (DO) events into agreement with the U/Th absolutely dated Hulu Cave speleothem record. The small Δage at WD provides valuable opportunities to investigate the timing of atmospheric greenhouse gas variations relative to Antarctic climate, as well as the interhemispheric phasing of the "bipolar seesaw".

  19. Landfill Methane

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Landfill methane (CH4) accounts for approximately 1.3% (0.6 Gt) of global anthropogenic greenhouse gas emissions relative to total emissions from all sectors of about 49 Gt CO2-eq yr-1. For countries with a history of controlled landfilling, landfills can be one of the larger national sources of ant...

  20. A twenty year record of the 13C isotopic composition of methane from Cape Meares, Oregon (1978-1998)

    NASA Astrophysics Data System (ADS)

    Teama, D.; Rice, A. L.

    2009-12-01

    Methane is an important greenhouse gas, second only to carbon dioxide in its radiative forcing since the industrial revolution. Over this time, the concentration of methane has increased by ~150% , primarily as a result of anthropogenic practices such as fossil fuel production, rice cultivation, biomass burning and waste management. In 1980s and through the 1990s, direct measurements of atmospheric methane from several global monitoring networks showed that the growth rate slowed from its previous ~1% per year climb. The year 2000 was the first year to record a negative annual growth. However, interannual variations are large and there remains considerable uncertainty regarding future trends in the global burden of methane due, in part, to poorly quantified trends of sources and sinks. One tool to better understand trends in sources and sinks of methane is through the use of stable isotopes. By comparing trends in the13C/12C and D/H content of atmospheric methane in time series to the isotopic signatures of sources, we can potentially disentangle trends in methane sources and sinks. Here we report preliminary measurements of 13C/12C ratios in atmospheric methane from a rare historic archive of whole air collected at Cape Meares, Oregon (45.5 °N, 124 °W) during the period 1978-1998 as part of the global monitoring program at the Oregon Graduate Institute. This unique dataset is the only direct time series of methane isotopic composition in the northern hemisphere prior to the late 1980s and early 1990s. The measurements reveal an increasing trend in the δ13C of methane consistent with more recent time series and firn air results (0.2-0.4‰ year-1). The increase in δ 13C over this time reflects an increase in fossil (~ -40‰) and pyrogenic (~ -25‰) sources of methane, which are enriched relative to biogenic sources (~ -60‰), and the relaxation of δ13C associated with isotopic disequilibrium. We discuss the long term trend in δ13C, its shorter term

  1. Characterization of ozone precursors in a regional background site of the Pearl River Delta by time series observation of non-methane hydrocarbons

    NASA Astrophysics Data System (ADS)

    Chang, C.; Wang, J.; Liu, S. C.; Lai, C.; Shao, M.; Zeng, L.; Zhang, Y.

    2009-12-01

    Continuous hourly measurements of C3-C12 non-methane hydrocarbons (NMHCs) were carried out in the period July 3 - 30, 2006 at a downwind site of Peal River Delta during the PRIDE-PRD2006 campaign. The measurements were intended to characterize the “residual composition” of ozone precursors through photochemical processing and to evaluate the photochemical relationship between oxidant (O3+NO2) and its precursors. An observation based method (OBM) of consumption concept is used to generate an ozone isopleth diagram that resembles the EKMA diagram, to examine the relationship of oxidant versus ozone precursors. A critical step in the method is to use observed concentrations of ethylbenzene and m,p-xylenes to estimate the degree of photochemical processing and amounts of photochemically consumed NOx and NMHCs by OH. The 3D OBM ozone isopleth diagram indicates that the observed oxidant level was sensitive to both of the consumed amounts of NMHCs and NOx. In addition, based on the 577 samples analyzed, toluene, benzene, isoprene, xylene and C3-C5 alkanes were found to be the most elevated species accounting for around 55% of the total measured NMHC abundance. After considering both the photochemical reactivities and mixing ratios of all the measured species, CO, isoprene, propene, xylene and toluene were calculated to have the highest ozone formation potentials (OFPs) accounting for 76.5% of total reactivity. Good correlation between NMHCs and 3-methylpentane, a proven good vehicular indicator, suggests vehicular emissions should be the major source for anthropogenic NMHCs. No correlation was found between isoprene and anthropogenic NMHCs, clearly supporting the existence of isoprene’s non-anthropogenic sources. Moreover, its diurnal pattern showed maximum mixing ratios around midday hours and minima at night, reflecting its biogenic properties which are both solar radiation and temperature dependent. Keywords: Age indicator; photochemical aging; NOx-control regime

  2. 32 CFR Appendix F to Part 197 - Procedures for Copying of Documents for the Foreign Relations of the United States Series

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 2 2011-07-01 2011-07-01 false Procedures for Copying of Documents for the Foreign Relations of the United States Series F Appendix F to Part 197 National Defense Department of... THE FILES OF THE OFFICE OF THE SECRETARY OF DEFENSE (OSD) Pt. 197, App. F Appendix F to Part...

  3. Holocene Concentrations of Methane in the Atmosphere are in Part Proportional to Concentrations of Sulfur Dioxide and Inversely Proportional to the Oxidizing Capacity of the Atmosphere

    NASA Astrophysics Data System (ADS)

    Ward, P. L.

    2008-12-01

    The atmosphere cleans itself by oxidizing pollutants. The primary oxidant is the hydroxyl radical (OH) formed by photodissociation of ozone in the near ultra-violet. Ozone and OH are in limited supply. Sulfur dioxide (SO2) absorbs near ultraviolet light limiting production of OH and reacts immediately with any available OH, forming sulfuric acid. Methane reacts more slowly with OH and will typically not be oxidized until there is little SO2. Thus a high concentration of methane indicates low oxidizing capacity. The rate at which SO2 is injected into the atmosphere controls oxidizing capacity and climate change in four ways: 1. Moderate rate: Large volcanic eruptions (VEI >=6) lower global temperatures for a few years when they are separated by years to decades so the oxidizing capacity of the atmosphere can fully recover. In 1991, Pinatubo volcano in the Philippines erupted 20 Mt SO2 and 491 Mt H2O, the largest volcanic eruption since 1912. The SO2 was oxidized primarily by OH to form a 99% pure aerosol of sulfuric acid and water at an elevation of 20-23 km. This aerosol reflected sunlight, lowering the world's temperature on average 0.4°C for three years. Ozone levels were reduced by 10%. Methane increased by 15 ppb for a year. The e-folding time for SO2 was 35 days. 2. High rate: When large eruptions occur once to several times per year, there is insufficient oxidizing capacity leading to increases in methane and other greenhouse gases and global warming. There were 15 times in the Holocene when large volcanoes erupted on average at least every year for 7 to 21 years. Man is now putting as much SO2 from burning fossil fuels into the atmosphere every year as one large volcano, causing current global warming. The two previous times were from 818-838 AD, the onset of the Medieval Warming Period, and from 180-143 BC, the onset of the Roman Warm Period. 3. Low rate: When there are no large eruptions for decades, the oxidizing capacity can catch up, cleaning the

  4. Traditional vs modern: role of breed type in determining enteric methane emissions from cattle grazing as part of contrasting grassland-based systems.

    PubMed

    Fraser, Mariecia D; Fleming, Hannah R; Moorby, Jon M

    2014-01-01

    Ruminant livestock turn forages and poor-quality feeds into human edible products, but enteric methane (CH4) emissions from ruminants are a significant contributor to greenhouse gases (GHGs) and hence to climate change. Despite the predominance of pasture-based beef production systems in many parts of Europe there are little data available regarding enteric CH4 emissions from free-ranging grazing cattle. It is possible that differences in physiology or behaviour could influence comparative emissions intensities for traditional and modern breed types depending on the nutritional characteristics of the herbage grazed. This study investigated the role of breed type in influencing CH4 emissions from growing beef steers managed on contrasting grasslands typical of intensive (lowland) and extensive (upland) production systems. Using the SF6 dilution technique CH4 emissions were estimated for a modern, fast-growing crossbred (Limousin cross) and a smaller and hardier native breed (Welsh Black) when grazing lowland perennial ryegrass (high nutritional density, low sward heterogeneity) and semi-improved upland pasture (low/medium nutritional density, high sward heterogeneity). Live-weight gain was substantially lower for steers on the upland system compared to the lowland system (0.31 vs. 1.04 kg d-1; s.e.d. = 0.085 kg d-1; P<0.001), leading to significant differences in estimated dry matter intakes (8.0 vs. 11.1 kg DM d-1 for upland and lowland respectively; s.e.d. = 0.68 kg DM d-1; P<0.001). While emissions per unit feed intake were similar for the lowland and upland systems, CH4 emissions per unit of live-weight gain (LWG) were substantially higher when the steers grazed the poorer quality hill pasture (760 vs 214 g kg-1 LWG; s.e.d. = 133.5 g kg-1 LWG; P<0.001). Overall any effects of breed type were relatively small relative to the combined influence of pasture type and location.

  5. Traditional vs Modern: Role of Breed Type in Determining Enteric Methane Emissions from Cattle Grazing as Part of Contrasting Grassland-Based Systems

    PubMed Central

    Fraser, Mariecia D.; Fleming, Hannah R.; Moorby, Jon M.

    2014-01-01

    Ruminant livestock turn forages and poor-quality feeds into human edible products, but enteric methane (CH4) emissions from ruminants are a significant contributor to greenhouse gases (GHGs) and hence to climate change. Despite the predominance of pasture-based beef production systems in many parts of Europe there are little data available regarding enteric CH4 emissions from free-ranging grazing cattle. It is possible that differences in physiology or behaviour could influence comparative emissions intensities for traditional and modern breed types depending on the nutritional characteristics of the herbage grazed. This study investigated the role of breed type in influencing CH4 emissions from growing beef steers managed on contrasting grasslands typical of intensive (lowland) and extensive (upland) production systems. Using the SF6 dilution technique CH4 emissions were estimated for a modern, fast-growing crossbred (Limousin cross) and a smaller and hardier native breed (Welsh Black) when grazing lowland perennial ryegrass (high nutritional density, low sward heterogeneity) and semi-improved upland pasture (low/medium nutritional density, high sward heterogeneity). Live-weight gain was substantially lower for steers on the upland system compared to the lowland system (0.31 vs. 1.04 kg d−1; s.e.d. = 0.085 kg d−1; P<0.001), leading to significant differences in estimated dry matter intakes (8.0 vs. 11.1 kg DM d−1 for upland and lowland respectively; s.e.d. = 0.68 kg DM d−1; P<0.001). While emissions per unit feed intake were similar for the lowland and upland systems, CH4 emissions per unit of live-weight gain (LWG) were substantially higher when the steers grazed the poorer quality hill pasture (760 vs 214 g kg−1 LWG; s.e.d. = 133.5 g kg−1 LWG; P<0.001). Overall any effects of breed type were relatively small relative to the combined influence of pasture type and location. PMID:25259617

  6. Coalbed Methane Outreach Program

    EPA Pesticide Factsheets

    Coalbed Methane Outreach Program, voluntary program seeking to reduce methane emissions from coal mining activities. CMOP promotes profitable recovery/use of coal mine methane (CMM), addressing barriers to using CMM instead of emitting it to atmosphere.

  7. METHANE: INDUSTRIAL SOURCES

    EPA Science Inventory

    The chapter provides qualitative information on the magnitude of industrial sources of methane and, where possible, provides information to allow the reader to quantify methane emissions. One difficulty in quantifying methane emissions from industry is the inconsistent treatment ...

  8. Optical constants of solid methane

    NASA Technical Reports Server (NTRS)

    Khare, Bishun N.; Thompson, W. R.; Sagan, C.; Arakawa, E. T.; Bruel, C.; Judish, J. P.; Khanna, R. K.; Pollack, J. B.

    1989-01-01

    Methane is the most abundant simple organic molecule in the outer solar system bodies. In addition to being a gaseous constituent of the atmospheres of the Jovian planets and Titan, it is present in the solid form as a constituent of icy surfaces such as those of Triton and Pluto, and as cloud condensate in the atmospheres of Titan, Uranus, and Neptune. It is expected in the liquid form as a constituent of the ocean of Titan. Cometary ices also contain solid methane. The optical constants for both solid and liquid phases of CH4 for a wide temperature range are needed for radiative transfer calculations, for studies of reflection from surfaces, and for modeling of emission in the far infrared and microwave regions. The astronomically important visual to near infrared measurements of solid methane optical constants are conspicuously absent from the literature. Preliminary results are presented of the optical constants of solid methane for the 0.4 to 2.6 micron region. K is reported for both the amorphous and the crystalline (annealed) states. Using the previously measured values of the real part of the refractive index, n, of liquid methane at 110 K n is computed for solid methane using the Lorentz-Lorentz relationship. Work is in progress to extend the measurements of optical constants n and k for liquid and solid to both shorter and longer wavelengths, eventually providing a complete optical constants database for condensed CH4.

  9. Mechanism and Kinetics of Methane Combustion, Part I: Thermal Rate Constants for Hydrogen-Abstraction Reaction of CH4 + O((3)P).

    PubMed

    Peng, Ya; Jiang, Zhong'an; Chen, Jushi

    2017-03-23

    The mechanism and kinetics of gas-phase hydrogen-abstraction by the O((3)P) from methane are investigated using ab initio calculations and dynamical methods. Not only are the electronic structure properties including the optimized geometries, relative energies, and vibrational frequencies of all the stationary points obtained from state-averaged complete active space self-consistent field calculations, but also the single-point energies for all points on the intrinsic reaction coordinate are evaluated using the internally contracted multireference configuration interaction approach with modified optimized cc-pCVDZ basis sets. Our calculations give a fairly accurate description of the regions around the (3)A″ transition state in the O((3)P) attacking a near-collinear H-CH3 direction with a barrier height of 12.53 kcal/mol, which is lower than those reported before. Subsequently, thermal rate constants for this hydrogen-abstraction are calculated using the canonical unified statistical theory method with the temperature ranging from 298 K to 1000 K. These calculated rate constants are in agreement with experiments. The present work reveals the reaction mechanism of hydrogen-abstraction by the O((3)P) from methane, and it is helpful for the understanding of methane combustion.

  10. Analysis of methane emissions from digested sludge.

    PubMed

    Schaum, C; Fundneider, T; Cornel, P

    2016-01-01

    The energetic use of sewage sludge is an important step in the generation of electricity and heat within a wastewater treatment plant (WWTP). For a holistic approach, methane emissions derived from anaerobic treatment have to be considered. Measurements show that methane dissolved in digested sludge can be analyzed via the vacuum salting out degassing method. At different WWTPs, dissolved methane was measured, showing a concentration range of approximately 7-37 mg CH4/L. The average concentration of dissolved methane in mesophilic digested sludge was approximately 29 mg CH4/L, which corresponds to an estimated yearly specific load of approximately 14-21 g CH4 per population equivalent. Comparisons between continuous and discontinuous digester feeding show that a temporary rise in the volume load causes increased concentrations of dissolved methane. Investigations using an industrial-scale digestion plant, consisting of three digestion tank operated in series, show comparable results.

  11. Methane: Fuel for the future

    SciTech Connect

    McGeer, P.; Durbin, E.

    1982-01-01

    In September of 1981, a world conference on alternative fuels entitled ''Methane - Fuel for the Future'' was held at Delta's River Inn in Vancouver, British Columbia. Approximately 500 registrants from over a dozen countries attended the two day meeting. The Western world has been adequately warned about the dangers of dependence on oil as an energy source and particularly as a transportation fuel. Over the past decade, the long-range prospect of a real depletion of the oil supply has been eclipsed by a series of artificial shortages precipitated by the Organization of Petroleum Exporting Countries (OPEC). Yet the remedies that have been employed to reduce this dependence - specifically energysaving measures and development of major new oil fields - provide only a temporary remission. This book points the way toward an effective solution to the oil problem, proposing methane as the most attractive choice for an alternative fuel. The book outlines the reasons for the superiority of methane to oil and synthetic fuels, citing availability, price, ease of distribution, and cleanliness and compatibility with current engines. In twenty-three articles the authors discuss the state-of-the-technology of using methane as a fuel for motor vehicles, the commercial aspects of methane as an alternative fuel, and the political problems associated with alternative fuel programs in seven countries.

  12. Coal Bed Methane Primer

    SciTech Connect

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of

  13. Charters, Constitutions and By-Laws of the Indian Tribes of North America. Part IIa: The Northern Plains. Occasional Publications in Anthropology, Ethnology Series, No. 3.

    ERIC Educational Resources Information Center

    Fay, George E., Comp.

    Part IIa of a series of publications consisting of American Indian tribal governmental documents, this volume contains charters, constitutions, and by-laws of Indian tribes in the Northern Plains (Montana and North Dakota). Documents are presented relative to the Assiniboine and Sioux Tribes of the Fort Peck Reservation, the Blackfeet Tribe of the…

  14. Charters, Constitutions and By-Laws of the Indian Tribes of North America; Part IV: The Southwest (Navajo--Zuni). Occasional Publications in Anthropology Ethnology Series No. 5.

    ERIC Educational Resources Information Center

    Fay, George E., Comp.

    Part IV of a series of publications consisting of American Indian tribal governmental documents, this volume includes charters, constitutions, articles of association, and by-laws of Indian tribes of New Mexico and Arizona. Documents are included relative to the Navajo Tribe of Arizona and New Mexico; the Eastern Navajo Council--New Mexico; the…

  15. Dedos de Luna. Children's Literature in Spanish: Bilingual Edition. Guia para maestros en espanol e ingles. Elementary Literature Series, Part II.

    ERIC Educational Resources Information Center

    Walker, Dana; Huerta, Mario

    This curriculum unit is designed to give primary school students foreign language experiences and also to support the cultural literacy strand of the California State History-Social Science Framework. The unit is part of an elementary literature series which utilizes quality primary source literature from various world regions and countries and…

  16. Methane activation on supported transition metal catalysts

    NASA Astrophysics Data System (ADS)

    Carstens, Jason Ned

    At present, there is considerable interest in utilizing methane more efficiently as both a fuel source and as a starting material for the production of other, more valuable products. However, methane is a very stable molecule with strong C-H bonds that are difficult to break. This makes methane combustion or the formation of carbon-carbon bonds quite difficult. The present work focuses on the use of supported transition metal catalysts as a means of activating methane (i.e. breaking C-H bonds) at low temperatures to produce valuable products or energy. The conversion of methane into higher hydrocarbons. A low temperature (<750 K), direct process to effectively convert methane into higher hydrocarbons would be quite desirable. Such a process is thermodynamically feasible if the reaction is broken up into two separate steps. The first step is the adsorption of methane onto a transition metal catalyst at temperatures above about 600 K to produce a surface carbon species. The second step is a low temperature (<373 K) hydrogenation to convert the carbon species into higher hydrocarbons. T. Koerts et al. have pursued this approach by dissociatively absorbing methane onto silica supported transition metal catalysts at temperatures ranging between 573 K and 773 K. The result was a surface carbonaceous species and hydrogen. In the second step, the carbonaceous intermediates produced small alkanes upon hydrogenation around 373 K. A maximum yield to higher hydrocarbons of 13% was obtained on a ruthenium catalyst. The present study was conducted to further investigate the nature of the carbonaceous species reported by Koerts. Methane combustion. This investigation was conducted in an effort to better understand the mechanism of methane combustion on Pd catalysts. In the first part of this study, temperature programmed reduction (TPR) was used to investigate the oxidation and reduction dynamics of a 10 wt% Pd/ZrOsb2 catalyst used for methane combustion. TPR experiments indicate

  17. [Sources of Methane in the Boreal Region

    NASA Technical Reports Server (NTRS)

    1998-01-01

    In determining the global methane budget the sources of methane must be balanced with the sinks and atmospheric inventory. The approximate contribution of the different methane sources to the budget has been establish showing the major terrestrial inputs as rice, wetlands, bogs, fens, and tundra. Measurements and modeling of production in these sources suggest that temperature, water table height and saturation along with substratum composition are important in controlling methane production and emission. The isotopic budget of 13 C and D/H in methane can be used as a tool to clarify the global budget. This approach has achieved success at constraining the inputs. Studies using the isotopic approach place constraints on global methane production from different sources. Also, the relation between the two biogenic production pathways, acetate fermentation and CO2 reduction, and the effect of substratum composition can be made using isotope measurements shows the relation between the different biogenic, thermogenic and anthropogenic sources of methane as a function of the carbon and hydrogen isotope values for each source and the atmosphere, tropospheric composition. Methane emissions from ponds and fens are a significant source in the methane budget of the boreal region. An initial study in 1993 and 1994 on the isotopic composition of this methane source and the isotopic composition in relation to oxidation of methane at the sediment surface of the ponds or fen was conducted as part of our BOREAS project. The isotopic composition of methane emitted by saturated anoxic sediment is dependent on the sediment composition and geochemistry, but will be influenced by in situ oxidation, in part, a function of rooted plant activity. The influence of oxidation mediated by rooted plant activities on the isotopic composition of methane is not well known and will depend on the plant type, sediment temperature, and numerous other variables. Information on this isotopic composition

  18. Coalbed methane resource potential and current prospects in Pennsylvania

    USGS Publications Warehouse

    Markowski, A.K.

    1998-01-01

    Coalbed methane gas content analyses from exploratory coal cores and existing data indicate that gas content generally increases with increasing depth and rank. The coal beds studied are from the Main Bituminous field of Pennsylvania (which currently contains 24 coalbed methane pools) and the Northern and Southern Anthracite coal fields. They range from the Middle Pennsylvanian Allegheny Group to the Late Pennsylvanian-Early Permian Dunkard Group. Previous US Bureau of Mines studies revealed gas contents from 0.4 to 13.8 cm3/g at depths of 99 to 432 m for the bituminous coal beds of the Allegheny Group. More recent core data from the Allegheny Group yielded gas contents from 2.2 to 8.9 cm3/g at depths from 167 to 387 m. In the Anthracite region of eastern Pennsylvania, the little data that are available show that gas content is anomalously high or low. Gas yields from test holes in eastern Pennsylvania are low with or without artificial stimulation mainly due to the lack of a good cleat system. Overall estimates of coalbed methane resources indicate there may be 1.7 Tm3 (61 Tcf) of gas-in-place contained in the Northern Appalachian coal basin. The amount of technically recoverable coalbed methane resources is projected by the US Geological Survey National Oil and Gas Resource Assessment Team [US Geological Survey National Oil and Gas Resource Assessment Team, 1996. 1995 National assessment of United States oil and gas resources-results, methodology, and supporting data, US Geological Survey Digital Data Series DDS-30, CD-ROM, Denver, CO, 80 pp.] and Lyons [Lyons, P.C., 1997. Central-northern Appalachian coalbed methane flow grows. Oil and Gas Journal 95 (27) 76-79] at 0.3 Tm3 (11.48 Tcf). This includes portions of Pennsylvania, Ohio, West Virginia, and a small part of Maryland. Consequently, a mapping investigation was conducted to evaluate the regional geology of the bituminous coal-bearing intervals in southwestern Pennsylvania and its influence on coalbed

  19. Zero methane-emitting peatlands: biogeochemical features and forecasting response to environmental change

    NASA Astrophysics Data System (ADS)

    Sirin, Andrey; Suvorov, Gennady; Glagolev, Mikhail; Kravchenko, Irina; Chistotin, Maxim; Bazhin, Nikolai

    2014-05-01

    Peatlands are one of the main sources of atmospheric CH4, a greenhouse gas responsible for a large part of current climate forcing. Existing estimates of methane flux from peatlands on a country, continental and global scale do not cover all variety of extremely diverse natural peatland ecosystems, their spatial uncertainties, and related to human impacts modifications. During last 2-3 decades numerous CH4flux measurements were conducted in northern peatlands, but many peatland types were not elaborated being suggested as unessential or even 'zero' source of methane to the atmosphere. Among them are widespread forested dwarf-shrub sphagnum peatbogs, frozen flat palsa mires, etc., as well as considered 'dry' peatlands drained and utilized for peat extraction, agriculture and forestry. Methane fluxes were measured at key peatland taiga test-plots of Central part of European Russia and taiga and tundra-forest zones of West Siberia purposely to examine periods of different level of humidity. The water level (WL) position switching from methane emission to uptake was elucidated for pine-dwarf-shrub-sphagnum ecotopes: at 50 cm WL near-zero or negative methane fluxes were registered at 86% of measurements, at 40 cm WL - emission at 89%. Observations in Central European Russia cover different natural and drained peatland types. Drainage and management usually decreased CH4 emissions relative to pristine peatlands through drying of surface peats and simultaneous decrease the size of anoxic horizons, but the rise of WL switches to CH4 fluxes. Relation between methane flux and peat wetness was additionally tested by series of lab mesocosm experiments. Processes resulting in similar final zero methane emissions under conditions of drained and intact peatland could be different. Microbial communities, involved in methane cycle, have been significantly changed in drained peatlands. Methanogens in natural peatlands were almost exclusively composed of hydrogenotrophs, whereas both

  20. Methane biofiltration using autoclaved aerated concrete as the carrier material.

    PubMed

    Ganendra, Giovanni; Mercado-Garcia, Daniel; Hernandez-Sanabria, Emma; Boeckx, Pascal; Ho, Adrian; Boon, Nico

    2015-09-01

    The methane removal capacity of mixed methane-oxidizing bacteria (MOB) culture in a biofilter setup using autoclaved aerated concrete (AAC) as a highly porous carrier material was tested. Batch experiment was performed to optimize MOB immobilization on AAC specimens where optimum methane removal was obtained when calcium chloride was not added during bacterial inoculation step and 10-mm-thick AAC specimens were used. The immobilized MOB could remove methane at low concentration (~1000 ppmv) in a biofilter setup for 127 days at average removal efficiency (RE) of 28.7 %. Unlike a plug flow reactor, increasing the total volume of the filter by adding a biofilter in series did not result in higher total RE. MOB also exhibited a higher abundance at the bottom of the filter, in proximity with the methane gas inlet where a high methane concentration was found. Overall, an efficient methane biofilter performance could be obtained using AAC as the carrier material.

  1. Methane mapping and its seasonal cycle in the atmosphere of Western Siberia as observed by IASI

    NASA Astrophysics Data System (ADS)

    Khamatnurova, Marina; Gribanov, Konstantin; Zadvornykh, Ilya; Rokotyan, Nikita; Zakharov, Vyacheslav

    2014-05-01

    Western Siberia is wide area covered with pristine peatlands which play important role in global carbon balance. Large areas of arctic and subarctic wetlands are vulnerable to climate change and industrial activity on oil, natural gas mining together with their transportation. These areas can have important feedback mechanisms in global warming, due to their large carbon stocks and the presence of permafrost. This study presents iterative regularization methods, software tool and some results on CH4 content retrieval from Infrared Atmospheric Sounding Interferometer (IASI/MetOp series) spectra measured over Western Siberia. Dense coverage of IASI measurements can be used to map sink and source regions on the territory of target region. Because of pure statistics of direct vertical profile measurements and low signal to noise ratio for northern part of target region, only most stable methods of methane content retrieval are required. We used iteratively regularized Gauss-Newton and Levenberg-Marquardt methods without using a priory covariance matrices for methane vertical profiles. Some examples of interatively calculated averaging kernels for both methods are represented. Spatial distribution methane columnar value maps, seasonal variations for whole target region are represented. Comparison of ground-based FTIR measurements of methane in atmosphere with obtained IASI-CH4 over Kourovka site is presented. Comparison of GOSAT standard products for methane and our retrieval results are presented and discussed.

  2. Economic Stress and Suicide: Multilevel Analyses. Part 1: Aggregate Time-Series Analyses of Economic Stress and Suicide.

    ERIC Educational Resources Information Center

    Dooley, David; And Others

    1989-01-01

    Conducted two studies on economic stress and suicide on same population. First study replicated aggregate time-series work using monthly data for 1975-82 for Los Angeles, California. Results do not support contention that economic contraction has strong, widespread effect on suicide in general population. Findings suggest effect that regional…

  3. Study on synchronous detection method of methane and ethane with laser absorption spectroscopy technology

    NASA Astrophysics Data System (ADS)

    He, Ying; Zhang, Yu-jun; You, Kun; Gao, Yan-wei; Chen, Chen; Liu, Jian-guo; Liu, Wen-qing

    2016-10-01

    The main ingredient of mash gas is alkenes, and methane is the most parts of mash gas and ethane is a small portion of it. Fast, accurate, real-time measurement of methane and ethane concentration is an important task for preventing coal mining disaster. In this research, a monitoring system with tunable diode laser absorption spectroscopy (TDLAS) technology has been set up for simultaneous measurement of methane and ethane, and a DFB laser at wavelength of 1.653μm was used as the laser source. The absorption spectroscopy information of methane and ethane, especially the characteristic of the spectrum peak positions and relative intensity were determined by available spectral structures from previous study and available database. Then, the concentration inversion algorithm method based on the spectral resolution and feature extraction was designed for methane and ethane synchronous detection. At last, the continuously experimental results obtained by different concentration of methane and ethane sample gases with the multiple reflection cell and the standard distribution system. In this experiment, the standard distribution system made with the standard gas and two high precision mass flow meters of D07 Sevenstar series whose flow velocity is 1l/min and 5l/min respectively. When the multiple reflection cell work stably, the biggest detection error of methane concentration inversion was 3.7%, and the biggest detection error of ethane was 4.8%. So it is verified that this concentration inversion algorithm works stably and reliably. Thus, this technology could realize the real-time, fast and continuous measurement requirement of mash gas and it will provide the effective technical support to coal mining production in safety for our country.

  4. Part 1. A time-series study of ambient air pollution and daily mortality in Shanghai, China.

    PubMed

    Kan, Haidong; Chen, Bingheng; Zhao, Naiqing; London, Stephanie J; Song, Guixiang; Chen, Guohai; Zhang, Yunhui; Jiang, Lili

    2010-11-01

    Although the relation between outdoor air pollution and daily mortality has been examined in several Chinese cities, there are still a number of key scientific issues to be addressed concerning the health effects of air pollution in China. Given the changes over the past decade in concentrations and sources of air pollution (e.g., the change from one predominant source [coal combustion], which was typical of the twentieth century, to a mix of sources [coal combustion and motor-vehicle emissions]) and transition in China, it is worthwhile to investigate the acute effects of outdoor air pollution on mortality outcomes in the country. We conducted a time-series study to investigate the relation between outdoor air pollution and daily mortality in Shanghai using four years of daily data (2001-2004). This study is a part of the Public Health and Air Pollution in Asia (PAPA) program supported by the Health Effects Institute (HEI). We collected data on daily mortality, air pollution, and weather from the Shanghai Municipal Center of Disease Control and Prevention (SMCDCP), Shanghai Environmental Monitoring Center, and Shanghai Meteorologic Bureau. An independent auditing team assigned by HEI validated all the data. Our statistical analysis followed the Common Protocol of the PAPA program (found at the end of this volume). Briefly, a natural-spline model was used to analyze the mortality, air pollution, and covariate data. We first constructed the basic models for various mortality outcomes excluding variables for air pollution, and used the partial autocorrelation function of the residuals to guide the selection of degrees of freedom for time trend and lag days for the autoregression terms. Thereafter, we introduced the pollutant variables and analyzed their effects on mortality outcomes, including both mortality due to all natural (nonaccidental) causes and cause-specific mortality. We fitted single- and multipollutant models to assess the stability of the effects of the

  5. Flexible Pedagogies: Part-Time Learners and Learning in Higher Education. Flexible Pedagogies: Preparing for the Future Series

    ERIC Educational Resources Information Center

    McLinden, Michael

    2013-01-01

    This publication focuses on national and international policy initiatives to develop a better understanding of part-time learners and the types of flexibility that may enhance their study especially pedagogically. As part of our five-strand research project "Flexible Pedagogies: preparing for the future" it: (1) highlights the challenges…

  6. Contribution of oil and natural gas production to renewed increase in atmospheric methane (2007-2014): top-down estimate from ethane and methane column observations

    NASA Astrophysics Data System (ADS)

    Hausmann, Petra; Sussmann, Ralf; Smale, Dan

    2016-03-01

    Harmonized time series of column-averaged mole fractions of atmospheric methane and ethane over the period 1999-2014 are derived from solar Fourier transform infrared (FTIR) measurements at the Zugspitze summit (47° N, 11° E; 2964 m a.s.l.) and at Lauder (45° S, 170° E; 370 m a.s.l.). Long-term trend analysis reveals a consistent renewed methane increase since 2007 of 6.2 [5.6, 6.9] ppb yr-1 (parts-per-billion per year) at the Zugspitze and 6.0 [5.3, 6.7] ppb yr-1 at Lauder (95 % confidence intervals). Several recent studies provide pieces of evidence that the renewed methane increase is most likely driven by two main factors: (i) increased methane emissions from tropical wetlands, followed by (ii) increased thermogenic methane emissions due to growing oil and natural gas production. Here, we quantify the magnitude of the second class of sources, using long-term measurements of atmospheric ethane as a tracer for thermogenic methane emissions. In 2007, after years of weak decline, the Zugspitze ethane time series shows the sudden onset of a significant positive trend (2.3 [1.8, 2.8] × 10-2 ppb yr-1 for 2007-2014), while a negative trend persists at Lauder after 2007 (-0.4 [-0.6, -0.1] × 10-2 ppb yr-1). Zugspitze methane and ethane time series are significantly correlated for the period 2007-2014 and can be assigned to thermogenic methane emissions with an ethane-to-methane ratio (EMR) of 12-19 %. We present optimized emission scenarios for 2007-2014 derived from an atmospheric two-box model. From our trend observations we infer a total ethane emission increase over the period 2007-2014 from oil and natural gas sources of 1-11 Tg yr-1 along with an overall methane emission increase of 24-45 Tg yr-1. Based on these results, the oil and natural gas emission contribution (C) to the renewed methane increase is deduced using three different emission scenarios with dedicated EMR ranges. Reference scenario 1 assumes an oil and gas emission combination with EMR = 7

  7. Part 4 of a 4-part series Miscellaneous Products: Trends and Alternatives in Deodorants, Antiperspirants, Sunblocks, Shaving Products, Powders, and Wipes

    PubMed Central

    Jacob, Sharon; Katta, Rajani; Nedorost, Susan; Warshaw, Erin; Zirwas, Matt; Selbo, Nicole

    2011-01-01

    Objective: To provide updated data on the usage of ingredients that are common potential contact allergens in several categories of topical products. To identify useful alternative products with few or no common contact allergens. Design: In November 2009, the full ingredient lists of 5,416 skin, hair, and cosmetic products marketed by the CVS pharmacy chain were copied from CVS.com into Microsoft Word format for analysis. Computer searches were made in Microsoft Word using search/replace and sorting functions to accurately identify the presence of specific allergens in each website product. Measurements: Percentages of American Contact Dermatitis Society core series allergens (and other common preservatives and sunblocks) were calculated. Results: The usage of American Contact Dermatitis Society core series allergens (and other preservatives and sunblocks) in various miscellaneous categories of topical products is reported. Conclusion: Data on allergens and alternatives for ancillary skin care products are not widely published. This article reviews some of the common potential allergens in antiperspirants, deodorants, shaving products, sunblocks, powders, and wipes. Suitable available alternative products for patients with contact allergy are listed. PMID:22010054

  8. Methane Plumes on Mars

    NASA Video Gallery

    Spectrometer instruments attached to several telescopes detect plumes of methane emitted from Mars during its summer and spring seasons. High levels of methane are indicated by warmer colors. The m...

  9. Optical constants of solid methane

    NASA Technical Reports Server (NTRS)

    Khare, Bishun N.; Thompson, W. R.; Sagan, C.; Arakawa, E. T.; Bruel, C.; Judish, J. P.; Khanna, R. K.; Pollack, J. B.

    1990-01-01

    Methane is the most abundant simple organic molecule in the outer solar system bodies. In addition to being a gaseous constituent of the atmospheres of the Jovian planets and Titan, it is present in the solid form as a constituent of icy surfaces such as those of Triton and Pluto, and as cloud condensate in the atmospheres of Titan, Uranus, and Neptune. It is expected in the liquid form as a constituent of the ocean of Titan. Cometary ices also contain solid methane. The optical constants for both solid and liquid phases of CH4 for a wide temperature range are needed for radiative transfer calculations, for studies of reflection from surfaces, and for modeling of emission in the far infrared and microwave regions. The astronomically important visual to near infrared measurements of solid methane optical constants are conspicuously absent from the literature. Preliminary results are presented on the optical constants of solid methane for the 0.4 to 2.6 micrometer region. Deposition onto a substrate at 10 K produces glassy (semi-amorphous) material. Annealing this material at approximately 33 K for approximately 1 hour results in a crystalline material as seen by sharper, more structured bands and negligible background extinction due to scattering. The constant k is reported for both the amorphous and the crystalline (annealed) states. Typical values (at absorption maxima) are in the .001 to .0001 range. Below lambda = 1.1 micrometers the bands are too weak to be detected by transmission through the films less than or equal to 215 micrometers in thickness, employed in the studies to date. Using previously measured values of the real part of the refractive index, n, of liquid methane at 110 K, n is computed for solid methane using the Lorentz-Lorenz relationship. Work is in progress to extend the measurements of optical constants n and k for liquid and solid to both shorter and longer wavelengths, eventually providing a complete optical constants database for

  10. Potential methane reservoirs beneath Antarctica.

    PubMed

    Wadham, J L; Arndt, S; Tulaczyk, S; Stibal, M; Tranter, M; Telling, J; Lis, G P; Lawson, E; Ridgwell, A; Dubnick, A; Sharp, M J; Anesio, A M; Butler, C E H

    2012-08-30

    Once thought to be devoid of life, the ice-covered parts of Antarctica are now known to be a reservoir of metabolically active microbial cells and organic carbon. The potential for methanogenic archaea to support the degradation of organic carbon to methane beneath the ice, however, has not yet been evaluated. Large sedimentary basins containing marine sequences up to 14 kilometres thick and an estimated 21,000 petagrams (1 Pg equals 10(15) g) of organic carbon are buried beneath the Antarctic Ice Sheet. No data exist for rates of methanogenesis in sub-Antarctic marine sediments. Here we present experimental data from other subglacial environments that demonstrate the potential for overridden organic matter beneath glacial systems to produce methane. We also numerically simulate the accumulation of methane in Antarctic sedimentary basins using an established one-dimensional hydrate model and show that pressure/temperature conditions favour methane hydrate formation down to sediment depths of about 300 metres in West Antarctica and 700 metres in East Antarctica. Our results demonstrate the potential for methane hydrate accumulation in Antarctic sedimentary basins, where the total inventory depends on rates of organic carbon degradation and conditions at the ice-sheet bed. We calculate that the sub-Antarctic hydrate inventory could be of the same order of magnitude as that of recent estimates made for Arctic permafrost. Our findings suggest that the Antarctic Ice Sheet may be a neglected but important component of the global methane budget, with the potential to act as a positive feedback on climate warming during ice-sheet wastage.

  11. Oxygen-Methane Thruster

    NASA Technical Reports Server (NTRS)

    Pickens, Tim

    2012-01-01

    An oxygen-methane thruster was conceived with integrated igniter/injector capable of nominal operation on either gaseous or liquid propellants. The thruster was designed to develop 100 lbf (approximately 445 N) thrust at vacuum conditions and use oxygen and methane as propellants. This continued development included refining the design of the thruster to minimize part count and manufacturing difficulties/cost, refining the modeling tools and capabilities that support system design and analysis, demonstrating the performance of the igniter and full thruster assembly with both gaseous and liquid propellants, and acquiring data from this testing in order to verify the design and operational parameters of the thruster. Thruster testing was conducted with gaseous propellants used for the igniter and thruster. The thruster was demonstrated to work with all types of propellant conditions, and provided the desired performance. Both the thruster and igniter were tested, as well as gaseous propellants, and found to provide the desired performance using the various propellant conditions. The engine also served as an injector testbed for MSFC-designed refractory combustion chambers made of rhenium.

  12. Heat pipe methanator

    DOEpatents

    Ranken, William A.; Kemme, Joseph E.

    1976-07-27

    A heat pipe methanator for converting coal gas to methane. Gravity return heat pipes are employed to remove the heat of reaction from the methanation promoting catalyst, transmitting a portion of this heat to an incoming gas pre-heat section and delivering the remainder to a steam generating heat exchanger.

  13. Structural and thermodiffractometric analysis of coordination polymers. Part I: tin derivatives of the Bim ligand [Bim = Bis(1-imidazolyl)methane]).

    PubMed

    Masciocchi, Norberto; Pettinari, Claudio; Alberti, Enrica; Pettinari, Riccardo; Nicola, Corrado Di; Albisetti, Alessandro Figini; Sironi, Angelo

    2007-12-10

    New polynuclear coordination species containing the ditopic bis(1-imidazolyl)methane (Bim) ligand have been prepared as microcrystalline powders and structurally characterized by ab initio X-ray powder diffraction methods. [Bim(Me2SnCl2)]n (1), [Bim(nBu2SnCl2)]n (3), [Bim(Ph2SnCl2)]n (4), [Bim(MeSnCl3)]n (5), and [Bim(PhSnCl3)]n (6) all contain 1D chains with octahedral tin atoms with trans N-Sn-N linkages (but 4, which displays a cis N-Sn-N linkage). Their thermodiffractometric analysis allowed the estimation of the linear thermal expansion coefficients and strain tensors derived there from. The potential-energy surface of the free Bim ligand (as defined by two torsional degrees of freedom about the two N-CH2 bonds), eventually controlling the length of the repeating unit (polymer elongation), has been estimated using molecular mechanics and correlated with experimental observations.

  14. Structural and thermodiffractometric analysis of coordination polymers. Part II: zinc and cadmium derivatives of the Bim ligand [Bim = bis(1-imidazolyl)methane].

    PubMed

    Masciocchi, Norberto; Pettinari, Claudio; Alberti, Enrica; Pettinari, Riccardo; Nicola, Corrado Di; Albisetti, Alessandro Figini; Sironi, Angelo

    2007-12-10

    New polynuclear coordination species containing the ditopic bis(1-imidazolyl)methane (Bim) ligand have been prepared as microcrystalline powders and structurally characterized by ab initio X-ray powder diffraction methods. [Zn(CH3COO)2(Bim)]n contains 1D chains with tetrahedral metal atoms bridged by Bim ligands; [CdBr2(Bim)]n shows a dense packing with hexacoordinated Cd(II) ions and mu-Br and mu-Bim bridges; at variance, the isomorphous [ZnCl2(Bim)]n and [ZnBr2(Bim)]n species contain cyclic dimers based on tetrahedral Zn(II) ions. Thermodiffractometric analysis allowed estimation of the linear thermal expansion coefficients and strain tensors derived there from. Bim-rich phases, with 2:1 ligand-to-metal ratio, were also isolated: ZnBr2(Bim)2(H2O)3 and [Cd(CH3COO)2(Bim)2]n containing cis and trans MN4O2 chromophores, respectively, show 1D polymers built upon M2Bim2 cycles, hinged on the metal ions. In all species the conformation of the Bim ligands is Cs (or nearly so), while in the few sparse reports of similar coordination polymers the alternative C2 one was preferentially observed.

  15. Regolith production and transport in the Susquehanna Shale Hills Critical Zone Observatory, Part 1: Insights from U-series isotopes

    NASA Astrophysics Data System (ADS)

    Ma, Lin; Chabaux, Francois; West, Nikki; Kirby, Eric; Jin, Lixin; Brantley, Susan

    2013-06-01

    investigate the timescales of regolith formation on hillslopes with contrasting topographic aspect, we measured U-series isotopes in regolith profiles from two hillslopes (north facing versus south facing) within the east-west trending Shale Hills catchment in Pennsylvania. This catchment is developed entirely on the Fe-rich, Silurian Rose Hill gray shale. Hillslopes exhibit a topographic asymmetry: The north-facing hillslope has an average slope gradient of ~20°, slightly steeper than the south-facing hillslope (~15°). The regolith samples display significant U-series disequilibrium resulting from shale weathering. Based on the U-series data, the rates of regolith production on the two ridgetops are indistinguishable (40 ± 22 versus 45 ± 12 m/Ma). However, when downslope positions are compared, the regolith profiles on the south-facing hillslope are characterized by faster regolith production rates (50 ± 15 to 52 ± 15 m/Ma) and shorter durations of chemical weathering (12 ± 3 to 16 ± 5 ka) than those on the north-facing hillslope (17 ± 14 to 18 ± 13 m/Ma and 39 ± 20 to 43 ± 20 ka). The south-facing hillslope is also characterized by faster chemical weathering rates inferred from major element chemistry, despite lower extents of chemical depletion. These results are consistent with the influence of aspect on regolith formation at Shale Hills; we hypothesize that aspect affects such variables as temperature, moisture content, and evapotranspiration in the regolith zone, causing faster chemical weathering and regolith formation rates on the south-facing side of the catchment. The difference in microclimate between these two hillslopes is inferred to have been especially significant during the periglacial period that occurred at Shale Hills at least ~15 ka before present. At that time, the erosion rates may also have been different from those observed today, perhaps denuding the south-facing hillslope of regolith but not quite stripping the north

  16. Homicide by methane gas.

    PubMed

    De-Giorgio, Fabio; Grassi, Vincenzo M; Vetrugno, Giuseppe; Rossi, Riccardo; Fucci, Nadia; d'Aloja, Ernesto; Pascali, Vincenzo L

    2012-09-10

    Methane is a suffocating gas, and "methane deaths" are largely the result of suffocation by gas-air displacement after accidental or deliberate exposure. Neither methane gas nor other suffocating gases are a common means of homicide, with the potential exception of the use of gas in chemical weapons or gas chambers. Here, we report the case of a 53-year-old woman who was killed by her husband with methane gas. The man had given his wife a dose of Lorazepam before setting up a hose that conveyed methane from the kitchen into the apartment's bedroom. The man subsequently faked his own suicide, which was later discovered.

  17. IUPAC-NIST Solubility Data Series. 101. Alcohols + Hydrocarbons + Water Part 3. C1-C3 Alcohols + Aromatic Hydrocarbons

    NASA Astrophysics Data System (ADS)

    Oracz, Paweł; Góral, Marian; Wiśniewska-Gocłowska, Barbara; Shaw, David G.; Mączyński, Andrzej

    2016-09-01

    The mutual solubilities and related liquid-liquid equilibria for 11 ternary systems of C1-C3 alcohols with aromatic hydrocarbons and water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2012 are compiled. For nine systems, sufficient data are available (two or more independent determinations) to allow critical evaluation. All new data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, an additional criterion was used for each of the evaluated systems. These systems include one binary miscibility gap in the hydrocarbon + water subsystem. The binary tie lines were compared with the recommended values published previously.

  18. IUPAC-NIST Solubility Data Series. 101. Alcohols + Hydrocarbons + Water. Part 2. C1-C3 Alcohols + Aliphatic Hydrocarbons

    NASA Astrophysics Data System (ADS)

    Oracz, Paweł; Góral, Marian; Wiśniewska-Gocłowska, Barbara; Shaw, David G.; Mączyński, Andrzej

    2016-09-01

    The mutual solubilities and related liquid-liquid equilibria for 37 ternary systems of C1-C3 alcohols with aliphatic hydrocarbons and water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2012 are compiled. For 14 systems, sufficient data are available (two or more independent determinations) to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, an additional criterion was used for each of the evaluated systems. These systems include one binary miscibility gap in the hydrocarbon + water subsystem and another one can be in the methanol + hydrocarbon subsystem. The binary tie lines were compared with the recommended values published previously.

  19. Methane Hydrates: Chapter 8

    USGS Publications Warehouse

    Boswell, Ray; Yamamoto, Koji; Lee, Sung-Rock; Collett, Timothy S.; Kumar, Pushpendra; Dallimore, Scott

    2008-01-01

    Gas hydrate is a solid, naturally occurring substance consisting predominantly of methane gas and water. Recent scientific drilling programs in Japan, Canada, the United States, Korea and India have demonstrated that gas hydrate occurs broadly and in a variety of forms in shallow sediments of the outer continental shelves and in Arctic regions. Field, laboratory and numerical modelling studies conducted to date indicate that gas can be extracted from gas hydrates with existing production technologies, particularly for those deposits in which the gas hydrate exists as pore-filling grains at high saturation in sand-rich reservoirs. A series of regional resource assessments indicate that substantial volumes of gas hydrate likely exist in sand-rich deposits. Recent field programs in Japan, Canada and in the United States have demonstrated the technical viability of methane extraction from gas-hydrate-bearing sand reservoirs and have investigated a range of potential production scenarios. At present, basic reservoir depressurisation shows the greatest promise and can be conducted using primarily standard industry equipment and procedures. Depressurisation is expected to be the foundation of future production systems; additional processes, such as thermal stimulation, mechanical stimulation and chemical injection, will likely also be integrated as dictated by local geological and other conditions. An innovative carbon dioxide and methane swapping technology is also being studied as a method to produce gas from select gas hydrate deposits. In addition, substantial additional volumes of gas hydrate have been found in dense arrays of grain-displacing veins and nodules in fine-grained, clay-dominated sediments; however, to date, no field tests, and very limited numerical modelling, have been conducted with regard to the production potential of such accumulations. Work remains to further refine: (1) the marine resource volumes within potential accumulations that can be

  20. An Interview Series with Members of the ASHP Expert Panel on Formulary Management: Part 3: Sabrina W. Cole, PharmD.

    PubMed

    Ventola, C Lee

    2010-01-01

    This article presents the third in a series of three interviews that P&T conducted with several members of the American Society of Health-System Pharmacists (ASHP) Expert Panel on Formulary Management.In 2008, ASHP convened this panel of experts to develop revised guidelines for P&T committee and formulary management to replace the previous guidance issued in 1991.1 These revised guidelines include recommendations concerning the review and evaluation of drugs for formulary inclusion, pharmacoeconomic assessments, therapeutic interchange, medication-use evaluations (MUEs), management of drug shortages, and many other important topics.In this series, ASHP experts discuss P&T committee and formulary management guidelines in their respective institutions as well as other observations and insights. In Part 3, the author interviews Sabrina Cole, PharmD, Clinical Specialist, Drug Information, at the Grady Health System in Atlanta, Georgia.

  1. Methane photochemistry and methane production on Neptune

    NASA Technical Reports Server (NTRS)

    Romani, P. N.; Atreya, S. K.

    1988-01-01

    The Neptune stratosphere's methane photochemistry is presently studied by means of a numerical model in which the observed mixing ratio of methane prompts photolysis near the CH4 homopause. Haze generation by methane photochemistry has its basis in the formation of hydrocarbon ices and polyacetylenes; the hazes can furnish the requisite aerosol haze at the appropriate pressure levels required by observations of Neptune in the visible and near-IR. Comparisons of model predictions with Uranus data indicate a lower ratio of polyacetylene production to hydrocarbon ice, as well as a lower likelihood of UV postprocessing of the acetylene ice to polymers on Neptune, compared to Uranus.

  2. Methane photochemistry and methane production on Neptune

    SciTech Connect

    Romani, P.N.; Atreya, S.K.

    1988-06-01

    The Neptune stratosphere's methane photochemistry is presently studied by means of a numerical model in which the observed mixing ratio of methane prompts photolysis near the CH4 homopause. Haze generation by methane photochemistry has its basis in the formation of hydrocarbon ices and polyacetylenes; the hazes can furnish the requisite aerosol haze at the appropriate pressure levels required by observations of Neptune in the visible and near-IR. Comparisons of model predictions with Uranus data indicate a lower ratio of polyacetylene production to hydrocarbon ice, as well as a lower likelihood of UV postprocessing of the acetylene ice to polymers on Neptune, compared to Uranus. 65 references.

  3. Methane photochemistry and methane production on Neptune

    NASA Astrophysics Data System (ADS)

    Romani, P. N.; Atreya, S. K.

    1988-06-01

    The Neptune stratosphere's methane photochemistry is presently studied by means of a numerical model in which the observed mixing ratio of methane prompts photolysis near the CH4 homopause. Haze generation by methane photochemistry has its basis in the formation of hydrocarbon ices and polyacetylenes; the hazes can furnish the requisite aerosol haze at the appropriate pressure levels required by observations of Neptune in the visible and near-IR. Comparisons of model predictions with Uranus data indicate a lower ratio of polyacetylene production to hydrocarbon ice, as well as a lower likelihood of UV postprocessing of the acetylene ice to polymers on Neptune, compared to Uranus.

  4. Clumped Methane Isotopologue Temperatures of Microbial Methane

    NASA Astrophysics Data System (ADS)

    Ono, S.; Wang, D. T.; Gruen, D.; Delwiche, K.; Hemond, H.; Pohlman, J.

    2014-12-01

    We will report the abundance of 13CH3D, a clumped isotopologue of methane, in microbial methane sampled from natural environments. They yield some expected and some unexpected results reflecting both equilibrium and kinetic isotope effects controlling the abundance of 13CH3D in low temperature environments. The four isotopologues of methane (12CH4, 13CH4, 12CH3D and 13CH3D) were measured by a tunable infrared spectroscopy method at a precision of 0.2‰ and accuracy of 0.5‰ (Ono et al., 2014). Similar to carbonate clumped isotope thermometry, clumped isotopologues of methane become more stable at lower temperatures. The equilibrium constant for the isotope exchange reaction 13CH4 + 12CH3D ⇌ 13CH3D + 12CH4 deviates from unity by +6.3 to +3.5 ‰ for methane equilibrated between 4 and 121 °C, a range expected for microbial methanogenesis. This would be measurably-distinct from a thermogenic methane signal, which typically have apparent 13CH3D-based temperatures ranging from 150 to 220 °C (+3.0 to +2.2 ‰ clumped isotope effect; Ono et al., 2014; Stolper et al. 2014). Marine samples, such as methane clathrates and porewater methane from the Cascadia margin, have 13CH3D-based temperatures that appear to be consistent with isotopic equilibration at in situ temperatures that are reasonable for deep sedimentary environments. In contrast, methane from freshwater environments, such as a lake and a swamp, yield apparent temperatures that are much higher than the known or inferred environmental temperature. Mixing of two or more distinct sources of methane could potentially generate this high temperature bias. We suggest, however, that this high-temperature bias likely reflects a kinetic isotope fractionation intrinsic to methanogenesis in fresh water environments. In contrast, the low-temperature signals from marine methane could be related to the slow metabolic rates and reversibility of microbial methanogenesis and methanotrophy in marine sedimentary environments

  5. Methane on Mars: Measurements and Possible Origins

    NASA Technical Reports Server (NTRS)

    Mumma, Michael J.; Villanueva, Geronimo L.; Novak, Robert E.; Radeva, Yana L.; Kaufl, H. Ulrich; Tokunaga, Alan; Encrenaz, Therese; Hartogh, Paul

    2011-01-01

    The presence of abundant methane in Earth's atmosphere (1.6 parts per million) requires sources other than atmospheric chemistry. Living systems produce more than 90% of Earth's atmospheric methane; the balance is of geochemical origin. On Mars, methane has been sought for nearly 40 years because of its potential biological significance, but it was detected only recently [1-5]. Its distribution on the planet is found to be patchy and to vary with time [1,2,4,5], suggesting that methane is released recently from the subsurface in localized areas, and is then rapidly destroyed [1,6]. Before 2000, searchers obtained sensitive upper limits for methane by averaging over much of Mars' dayside hemisphere, using data acquired by Marsorbiting spacecraft (Mariner 9) and Earth-based observatories (Kitt Peak National Observatory, Canada- France-Hawaii Telescope, Infrared Space Observatory). These negative findings suggested that methane should be searched at higher spatial resolution since the local abundance could be significantly larger at active sites. Since 2001, searches for methane have emphasized spatial mapping from terrestrial observatories and from Mars orbit (Mars Express).

  6. Efficient Algorithm for Locating and Sizing Series Compensation Devices in Large Transmission Grids: Solutions and Applications (PART II)

    SciTech Connect

    Frolov, Vladimir; Backhaus, Scott N.; Chertkov, Michael

    2014-01-14

    In a companion manuscript, we developed a novel optimization method for placement, sizing, and operation of Flexible Alternating Current Transmission System (FACTS) devices to relieve transmission network congestion. Specifically, we addressed FACTS that provide Series Compensation (SC) via modification of line inductance. In this manuscript, this heuristic algorithm and its solutions are explored on a number of test cases: a 30-bus test network and a realistically-sized model of the Polish grid (~2700 nodes and ~3300 lines). The results on the 30-bus network are used to study the general properties of the solutions including non-locality and sparsity. The Polish grid is used as a demonstration of the computational efficiency of the heuristics that leverages sequential linearization of power flow constraints and cutting plane methods that take advantage of the sparse nature of the SC placement solutions. Using these approaches, the algorithm is able to solve an instance of Polish grid in tens of seconds. We explore the utility of the algorithm by analyzing transmission networks congested by (a) uniform load growth, (b) multiple overloaded configurations, and (c) sequential generator retirements

  7. Efficient Algorithm for Locating and Sizing Series Compensation Devices in Large Transmission Grids: Model Implementation (PART 1)

    SciTech Connect

    Frolov, Vladimir; Backhaus, Scott N.; Chertkov, Michael

    2014-01-14

    We explore optimization methods for planning the placement, sizing and operations of Flexible Alternating Current Transmission System (FACTS) devices installed to relieve transmission grid congestion. We limit our selection of FACTS devices to Series Compensation (SC) devices that can be represented by modification of the inductance of transmission lines. Our master optimization problem minimizes the l1 norm of the inductance modification subject to the usual line thermal-limit constraints. We develop heuristics that reduce this non-convex optimization to a succession of Linear Programs (LP) which are accelerated further using cutting plane methods. The algorithm solves an instance of the MatPower Polish Grid model (3299 lines and 2746 nodes) in 40 seconds per iteration on a standard laptop—a speed up that allows the sizing and placement of a family of SC devices to correct a large set of anticipated congestions. We observe that our algorithm finds feasible solutions that are always sparse, i.e., SC devices are placed on only a few lines. In a companion manuscript, we demonstrate our approach on realistically-sized networks that suffer congestion from a range of causes including generator retirement. In this manuscript, we focus on the development of our approach, investigate its structure on a small test system subject to congestion from uniform load growth, and demonstrate computational efficiency on a realistically-sized network.

  8. Process for separating nitrogen from methane using microchannel process technology

    DOEpatents

    Tonkovich, Anna Lee; Qiu, Dongming; Dritz, Terence Andrew; Neagle, Paul; Litt, Robert Dwayne; Arora, Ravi; Lamont, Michael Jay; Pagnotto, Kristina M.

    2007-07-31

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  9. High-resolution passive sampling of dissolved methane in the water column of lakes in Greenland

    NASA Astrophysics Data System (ADS)

    Goldman, A. E.; Cadieux, S. B.; White, J. R.; Pratt, L. M.

    2013-12-01

    Arctic lakes are important participants in the global carbon cycle, releasing methane in a warming climate and contributing to a positive feedback to climate change. In order to yield detailed methane budgets and understand the implications of warming on methane dynamics, high-resolution profiles revealing methane behavior within the water column need to be obtained. Single day sampling using disruptive techniques has the potential to result in biases. In order to obtain high-resolution, undisturbed profiles of methane concentration and isotopic composition, this study evaluates a passive sampling method over a multi-day equilibration period. Selected for this study were two small lakes (<1km2) within a narrow valley stretching between Russells Glacier and Søndre Strømfjord in southwestern Greenland, which are part of an ongoing study of a series of seven lakes. Commercially available, 150 mL, polyethylene Passive Diffusion Bags (PDB's) were deployed in July 2013 for five days at 0.5-meter depth intervals. PDB samples were compared to samples collected with a submersible, electric pump taken immediately before PBD deployment. Preliminary CH4 concentrations and carbon isotopes for one lake were obtained in the field using a Los Gatos Research Methane Carbon Isotope Analyzer. PDB sampling and pump sampling resulted in statistically similar concentrations (R2=0.89), ranging from 0.85 to 135 uM from PDB and 0.74 to 143 uM from pump sampling. In anoxic waters of the lake, where concentrations were high enough to yield robust isotopic results on the LGR MCIA, δ13C were also similar between the two methods, yielding -73‰ from PDB and -74‰ from pump sampling. Further investigation will produce results for a second lake and methane carbon and hydrogen isotopic composition for both lakes. Preliminary results for this passive sampling method are promising. We envision the use of this technique in future studies of dissolved methane and expect that it will provide a

  10. Methane emission from sewers.

    PubMed

    Liu, Yiwen; Ni, Bing-Jie; Sharma, Keshab R; Yuan, Zhiguo

    2015-08-15

    Recent studies have shown that sewer systems produce and emit a significant amount of methane. Methanogens produce methane under anaerobic conditions in sewer biofilms and sediments, and the stratification of methanogens and sulfate-reducing bacteria may explain the simultaneous production of methane and sulfide in sewers. No significant methane sinks or methanotrophic activities have been identified in sewers to date. Therefore, most of the methane would be emitted at the interface between sewage and atmosphere in gravity sewers, pumping stations, and inlets of wastewater treatment plants, although oxidation of methane in the aeration basin of a wastewater treatment plant has been reported recently. Online measurements have also revealed highly dynamic temporal and spatial variations in methane production caused by factors such as hydraulic retention time, area-to-volume ratio, temperature, and concentration of organic matter in sewage. Both mechanistic and empirical models have been proposed to predict methane production in sewers. Due to the sensitivity of methanogens to environmental conditions, most of the chemicals effective in controlling sulfide in sewers also suppress or diminish methane production. In this paper, we review the recent studies on methane emission from sewers, including the production mechanisms, quantification, modeling, and mitigation.

  11. Detection of methane in the atmosphere of Mars.

    PubMed

    Formisano, Vittorio; Atreya, Sushil; Encrenaz, Thérèse; Ignatiev, Nikolai; Giuranna, Marco

    2004-12-03

    We report a detection of methane in the martian atmosphere by the Planetary Fourier Spectrometer onboard the Mars Express spacecraft. The global average methane mixing ratio is found to be 10 +/- 5 parts per billion by volume (ppbv). However, the mixing ratio varies between 0 and 30 ppbv over the planet. The source of methane could be either biogenic or nonbiogenic, including past or present subsurface microorganisms, hydrothermal activity, or cometary impacts.

  12. Methane-Powered Vehicles

    NASA Technical Reports Server (NTRS)

    1982-01-01

    Liquid methane is beginning to become an energy alternative to expensive oil as a power source for automotive vehicles. Methane is the principal component of natural gas, costs less than half as much as gasoline, and its emissions are a lot cleaner than from gasoline or diesel engines. Beech Aircraft Corporation's Boulder Division has designed and is producing a system for converting cars and trucks to liquid methane operation. Liquid methane (LM) is a cryogenic fuel which must be stored at a temperature of 260 degrees below zero Fahrenheit. The LM system includes an 18 gallon fuel tank in the trunk and simple "under the hood" carburetor conversion equipment. Optional twin-fuel system allows operator to use either LM or gasoline fuel. Boulder Division has started deliveries for 25 vehicle conversions and is furnishing a liquid methane refueling station. Beech is providing instruction for Northwest Natural Gas, for conversion of methane to liquid state.

  13. Mars methane engine

    NASA Technical Reports Server (NTRS)

    Bui, Hung; Coletta, Chris; Debois, Alain

    1994-01-01

    The feasibility of an internal combustion engine operating on a mixture of methane, carbon dioxide, and oxygen has been verified by previous design groups for the Mars Methane Engine Project. Preliminary stoichiometric calculations examined the theoretical fuel-air ratios needed for the combustion of methane. Installation of a computer data acquisition system along with various ancillary components will enable the performance of the engine, running on the described methane mixture, to be optimized with respect to minimizing excess fuel. Theoretical calculations for stoichiometric combustion of methane-oxygen-carbon dioxide mixtures yielded a ratio of 1:2:4.79 for a methane-oxygen-carbon dioxide mixture. Empirical data shows the values to be closer to 1:2.33:3.69 for optimum operation.

  14. Detecting Methane Leaks

    NASA Technical Reports Server (NTRS)

    Grant, W. B.; Hinkley, E. D.

    1984-01-01

    Remote sensor uses laser radiation backscattered from natural targets. He/Ne Laser System for remote scanning of Methane leaks employs topographic target to scatter light to receiver near laser transmitter. Apparatus powered by 1.5kW generator transported to field sites and pointed at suspected methane leaks. Used for remote detection of natural-gas leaks and locating methane emissions in landfill sites.

  15. Solar Energy Education. Reader, Part IV. Sun schooling

    SciTech Connect

    Not Available

    1981-05-01

    A collection of magazine articles which focus on solar energy is presented. This is the final book of the four part series of the Solar Energy Reader. The articles include brief discussions on energy topics such as the sun, ocean energy, methane gas from cow manure, and solar homes. Instructions for constructing a sundial and a solar stove are also included. A glossary of energy related terms is provided. (BCS)

  16. Applications of a simulation model to description of anaerobic conversion of complex organic matter into methane

    SciTech Connect

    Vavilin, V.A.; Rytow, S.V.; Lokshina, L.Ya.

    1996-12-31

    Three years passed since the generalized model <METHANE> of anaerobic degradation of complex organic matter has been developed. Now the new modifications were created. Anaerobic degradation was described as a multistep process of series and parallel reactions in which several groups of bacteria take part. Hydrolysis, acidogenesis, acetogenesis and methanogenesis were considered in the model with the various kinetic functions. A two-phase equation describing a particulate substrate degradation as a heterogeneous reaction has been developed. Acetic, butyric, and propionic groups of acidogenic bacteria producing the particular products were considered. The additional group of homoacetogenic bacteria producing acetate from hydrogen and carbon dioxide was involved into new version of the <METHANE> model. Ammonia and hydrogen sulfide inhibition were described previously. In that paper, it was shown by simulation of several case-studies that unionized volatile fatty acids (VFA) are the inhibitors of key stages of anaerobic conversion of complex organic matter: hydrolysis, acetogenesis and methanogenesis.

  17. A conduit dilation model of methane venting from lake sediments

    USGS Publications Warehouse

    Scandella, B.P.; Varadharajan, C.; Hemond, Harold F.; Ruppel, C.; Juanes, R.

    2011-01-01

    Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the methane generated in organic-rich sediments underlying surface water bodies, including lakes, wetlands, and the ocean. The fraction of the methane that reaches the atmosphere depends critically on the mode and spatiotemporal characteristics of free-gas venting from the underlying sediments. Here we propose that methane transport in lake sediments is controlled by dynamic conduits, which dilate and release gas as the falling hydrostatic pressure reduces the effective stress below the tensile strength of the sediments. We test our model against a four-month record of hydrostatic load and methane flux in Upper Mystic Lake, Mass., USA, and show that it captures the complex episodicity of methane ebullition. Our quantitative conceptualization opens the door to integrated modeling of methane transport to constrain global methane release from lakes and other shallow-water, organic-rich sediment systems, and to assess its climate feedbacks.

  18. A conduit dilation model of methane venting from lake sediments

    NASA Astrophysics Data System (ADS)

    Scandella, Benjamin P.; Varadharajan, Charuleka; Hemond, Harold F.; Ruppel, Carolyn; Juanes, Ruben

    2011-03-01

    Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the methane generated in organic-rich sediments underlying surface water bodies, including lakes, wetlands, and the ocean. The fraction of the methane that reaches the atmosphere depends critically on the mode and spatiotemporal characteristics of free-gas venting from the underlying sediments. Here we propose that methane transport in lake sediments is controlled by dynamic conduits, which dilate and release gas as the falling hydrostatic pressure reduces the effective stress below the tensile strength of the sediments. We test our model against a four-month record of hydrostatic load and methane flux in Upper Mystic Lake, Mass., USA, and show that it captures the complex episodicity of methane ebullition. Our quantitative conceptualization opens the door to integrated modeling of methane transport to constrain global methane release from lakes and other shallow-water, organic-rich sediment systems, and to assess its climate feedbacks.

  19. The future of methane

    SciTech Connect

    Howell, D.G.

    1995-12-31

    Natural gas, mainly methane, produces lower CO{sub 2}, CO, NO{sub x}, SO{sub 2} and particulate emissions than either oil or coal; thus further substitutions of methane for these fuels could help mitigate air pollution. Methane is, however, a potent greenhouse gas and the domestication of ruminants, cultivation of rice, mining of coal, drilling for oil, and transportation of natural gas have all contributed to a doubling of the amount of atmospheric methane since 1800. Today nearly 300,000 wells yearly produce ca. 21 trillion cubic feet of methane. Known reserves suggest about a 10 year supply at the above rates of recovery; and the potential for undiscovered resources is obscured by uncertainty involving price, new technologies, and environmental restrictions steming from the need to drill an enormous number of wells, many in ecologically sensitive areas. Until all these aspects of methane are better understood, its future role in the world`s energy mix will remain uncertain. The atomic simplicity of methane, composed of one carbon and four hydrogen atoms, may mask the complexity and importance of this, the most basic of organic molecules. Within the Earth, methane is produced through thermochemical alteration of organic materials, and by biochemical reactions mediated by metabolic processes of archaebacteria; some methane may even be primordial, a residue of planetary accretion. Methane also occurs in smaller volumes in landfills, rice paddies, termite complexes, ruminants, and even many humans. As an energy source, its full energy potential is controversial. Methane is touted by some as a viable bridge to future energy systems, fueled by the sun and uranium and carried by electricity and hydrogen.

  20. Methanation assembly using multiple reactors

    DOEpatents

    Jahnke, Fred C.; Parab, Sanjay C.

    2007-07-24

    A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

  1. Effects of Environmental Conditions on an Urban Wetland's Methane Fluxes

    NASA Astrophysics Data System (ADS)

    Naor Azrieli, L.; Morin, T. H.; Bohrer, G.; Schafer, K. V.; Brooker, M.; Mitsch, W. J.

    2013-12-01

    Methane emissions from wetlands are the largest natural source of uncertainty in the global methane (CH4) budget. Wetlands are highly productive ecosystems with a large carbon sequestration potential. While wetlands are a net sink for carbon dioxide, they also release methane, a potent greenhouse gas. To effectively develop wetland management techniques, it is important to properly calculate the carbon budget of wetlands by understand the driving factors of methane fluxes. We constructed an eddy flux covariance system in the Olentangy River Wetland Research Park, a series of created and restored wetland in Columbus Ohio. Through the use of high frequency open path infrared gas analyzer (IRGA) sensors, we have continuously monitored the methane fluxes associated with the wetland since May 2011. To account for the heterogeneous landscape surrounding the tower, a footprint analysis was used to isolate data originating from within the wetland. Continuous measurements of the meteorological and environmental conditions at the wetlands coinciding with the flux measurements allow the interactions between methane fluxes and the climate and ecological forcing to be studied. The wintertime daily cycle of methane peaks around midday indicating a typical diurnal pattern in cold months. In the summer, the peak shifts to earlier in the day and also includes a daily peak occurring at approximately 10 AM. We believe this peak is associated with the onset of photosynthesis in Typha latifolia flushing methane from the plant's air filled tissue. Correlations with methane fluxes include latent heat flux, soil temperature, and incoming radiation. The connection to radiation may be further evidence of plant activity as a driver of methane fluxes. Higher methane fluxes corresponding with higher soil temperature indicates that warmer days stimulate the methanogenic consortium. Further analysis will focus on separating the methane fluxes into emissions from different terrain types within

  2. Methane emission from flooded soils - from microorganisms to the atmosphere

    NASA Astrophysics Data System (ADS)

    Conrad, Ralf

    2016-04-01

    Methane is an important greenhouse gas that is affected by anthropogenic activity. The annual budget of atmospheric methane, which is about 600 million tons, is by more than 75% produced by methanogenic archaea. These archaea are the end-members of a microbial community that degrades organic matter under anaerobic conditions. Flooded rice fields constitute a major source (about 10%) of atmospheric methane. After flooding of soil, anaerobic processes are initiated, finally resulting in the disproportionation of organic matter to carbon dioxide and methane. This process occurs in the bulk soil, on decaying organic debris and in the rhizosphere. The produced methane is mostly ventilated through the plant vascular system into the atmosphere. This system also allows the diffusion of oxygen into the rizosphere, where part of the produced methane is oxidized by aerobic methanotrophic bacteria. More than 50% of the methane production is derived from plant photosynthetic products and is formed on the root surface. Methanocellales are an important group of methanogenic archaea colonizing rice roots. Soils lacking this group seem to result in reduced root colonization and methane production. In rice soil methane is produced by two major paths of methanogenesis, the hydrogenotrophic one reducing carbon dioxide to methane, and the aceticlastic one disproportionating acetate to methane and carbon dioxide. Theoretically, at least two third of the methane should be produced by aceticlastic and the rest by hydrogenotrophic methanogenesis. In nature, however, the exact contribution of the two paths can vary from zero to 100%. Several environmental factors, such as temperature and quality of organic matter affect the path of methane production. The impact of these factors on the composition and activity of the environmental methanogenic microbial community will be discussed.

  3. Geoengineering treatment of methane

    NASA Astrophysics Data System (ADS)

    Lockley, Andrew; Gardian, Alan

    2010-05-01

    Methane is a significant GHG, and substantial reservoirs are vulnerable to instability due to AGW. Excursions, from permafrost and clathrates especially, act a positive feedback to AGW. Existing concentrations of well-mixed atmospheric methane substantially exceed pre-industrial levels. Various geoengineering methods are herein proposed for containment of methane, and/or accelerated oxidation to CO2 (a gas with a lower GWP over all timescales). A basic qualitative analysis of each technique is undertaken, to direct further study. Consideration is also given to the potential capacity of each technique to treat the total likely excursions of methane expected as a result of AGW. Proposed techniques: Section 0 SRM (comparison option) Section 1 Pre-emptive treatment of methane reservoirs Soil heating (polytunnels, heat pumps); Soil aeration; Mining of clathrates; Burning of clathrates Section 2 Remediation of aquatic methane excursions Lake sealing; Mixing of aquatic strata; Bubble capture; Lake aeration; Biological oxidation in aquatic environments Section 3 Remediation of concentrated atmospheric methane Regenerative thermal oxidation; Electrical ignition; Thermal ignition; Using incendiary munitions Section 4 Remediation of diffuse atmospheric methane Thermal oxidation by concentrated solar power; Compression ignition; Chemical degradation Assessment criteria: Infrastructure/implementation cost; Energy cost; Expected efficacy; Complexity/development path; Environmental impacts; Potential for CCS

  4. Part 1. Short-term effects of air pollution on mortality: results from a time-series analysis in Chennai, India.

    PubMed

    Balakrishnan, Kalpana; Ganguli, Bhaswati; Ghosh, Santu; Sankar, S; Thanasekaraan, Vijaylakshmi; Rayudu, V N; Caussy, Harry

    2011-03-01

    This report describes the results of a time-series analysis of the effect of short-term exposure to particulate matter with an aerodynamic diameter < or = 10 pm (PM10) on mortality in metropolitan Chennai, India (formerly Madras). This was one of three sites in India chosen by HEI as part of its Public Health and Air Pollution in Asia (PAPA) initiative. The study involved integration and analysis of retrospective data for the years 2002 through 2004. The data were obtained from relevant government agencies in charge of routine data collection. Data on meteorologic confounders (including temperature, relative humidity, and dew point) were available on all days of the study period. Data on mortality were also available on all days, but information on cause-of-death (including accidental deaths) could not be reliably ascertained. Hence, only all-cause daily mortality was used as the major outcome for the time-series analyses. Data on PM10, nitrogen dioxide (NO2), and sulfur dioxide (SO2) were limited to a much smaller number of days, but spanned the full study period. Data limitations resulting from low sensitivity of gaseous pollutant measurements led to using only PM10 in the main analysis. Of the eight operational ambient air quality monitor (AQM) stations in the city, seven met the selection criteria set forth in the common protocol developed for the three PAPA studies in India. In addition, all raw data used in the analysis were subjected to additional quality assurance (QA) and quality control (QC) criteria to ensure the validity of the measurements. Two salient features of the PM10 data set in Chennai were a high percentage of missing readings and a low correlation among daily data recorded by the AQMs. The latter resulted partly because each AQM had a small footprint (approximate area over which the air pollutant measurements recorded in the AQM are considered valid), and partly because of differences in source profiles among the 10 zones within the city. The

  5. 40 CFR Table Hh-4 to Subpart Hh of... - Landfill Methane Oxidation Fractions

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Landfill Methane Oxidation Fractions.... 98, Subpt. HH, Table HH-4 Table HH-4 to Subpart HH of Part 98—Landfill Methane Oxidation Fractions... soil prior to any oxidation and is calculated as follows: ER29NO13.024 Where: MF = Methane flux...

  6. 30 CFR 75.150 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Tests for methane and for oxygen deficiency... Certified Persons § 75.150 Tests for methane and for oxygen deficiency; qualified person. (a) The provisions of Subpart D—Ventilation of this part and § 75.1106 require that tests for methane and for...

  7. 30 CFR 75.150 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Tests for methane and for oxygen deficiency... Certified Persons § 75.150 Tests for methane and for oxygen deficiency; qualified person. (a) The provisions of Subpart D—Ventilation of this part and § 75.1106 require that tests for methane and for...

  8. 30 CFR 75.150 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Tests for methane and for oxygen deficiency... Certified Persons § 75.150 Tests for methane and for oxygen deficiency; qualified person. (a) The provisions of Subpart D—Ventilation of this part and § 75.1106 require that tests for methane and for...

  9. 30 CFR 75.150 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Tests for methane and for oxygen deficiency... Certified Persons § 75.150 Tests for methane and for oxygen deficiency; qualified person. (a) The provisions of Subpart D—Ventilation of this part and § 75.1106 require that tests for methane and for...

  10. 30 CFR 75.150 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Tests for methane and for oxygen deficiency... Certified Persons § 75.150 Tests for methane and for oxygen deficiency; qualified person. (a) The provisions of Subpart D—Ventilation of this part and § 75.1106 require that tests for methane and for...

  11. Genomic heritabilities and genomic estimated breeding values for methane traits in Angus cattle.

    PubMed

    Hayes, B J; Donoghue, K A; Reich, C M; Mason, B A; Bird-Gardiner, T; Herd, R M; Arthur, P F

    2016-03-01

    Enteric methane emissions from beef cattle are a significant component of total greenhouse gas emissions from agriculture. The variation between beef cattle in methane emissions is partly genetic, whether measured as methane production, methane yield (methane production/DMI), or residual methane production (observed methane production - expected methane production), with heritabilities ranging from 0.19 to 0.29. This suggests methane emissions could be reduced by selection. Given the high cost of measuring methane production from individual beef cattle, genomic selection is the most feasible approach to achieve this reduction in emissions. We derived genomic EBV (GEBV) for methane traits from a reference set of 747 Angus animals phenotyped for methane traits and genotyped for 630,000 SNP. The accuracy of GEBV was tested in a validation set of 273 Angus animals phenotyped for the same traits. Accuracies of GEBV ranged from 0.29 ± 0.06 for methane yield and 0.35 ± 0.06 for residual methane production. Selection on GEBV using the genomic prediction equations derived here could reduce emissions for Angus cattle by roughly 5% over 10 yr.

  12. Biostratigraphy and sedimentology of the Fluviatile Untere Serie (Early and Middle Miocene) in the central part of the North Alpine Foreland Basin: implications for palaeoenvironment and climate

    NASA Astrophysics Data System (ADS)

    Prieto, J.; Böhme, M.; Maurer, H.; Heissig, K.; Abdul Aziz, H.

    2009-10-01

    The Early to Middle Miocene Fluviatile Untere Serie lithostratigraphic unit of the Upper Freshwater Molasse (UFM) in the North Alpine Foreland Basin (NAFB) crops out in a 40 m long section at Untereichen-Altenstadt (central part of the NAFB). This section yields a unique superposition of two vertebrate assemblages belonging to different biostratigraphic units: early part OSM C + D (Karpatian) and OSM E (Early Badenian). Detailed taxonomic analyses reveal different diversity patterns in the two assemblages. Nine small mammal and six ectothermic vertebrate taxa occur in the older level UA 540 m, while 20 small mammal and 23 ectothermic vertebrate taxa are recorded for the younger level UA 565 m. From the latter locality comes a small-sized representative of the biostratigraphically significant Megacricetodon lappi lineage. This evolutionary level has not been documented previously for the eastern part of the NAFB. Bioclimatic analysis combined with lithofacies and architectural element analysis indicates that significant changes in the fluvial sedimentation style, surface-water runoff and tectonics occurred between the Early Karpatian and Early Badenian. A meandering fluvial system (marly unit) is erosively overlain by sandy braided river deposits (sandy unit). Overbank deposits of the marly unit revealed that the older vertebrate fossil assemblage (UA 540 m) is deposited in an animal burrow that was presumably produced by owls. Both reptilian and mammalian taxa are indicative of a relatively open environment and dry, probably semi-arid climate. Conversely, vertebrates from the sandy unit (UA 565 m), which are accumulated in channel fill deposits, suggest closed as well as open habitats with a subtropical humid climate and mean annual rainfall of about 1,000 mm. According to the sequence stratigraphic analysis the marly unit is interpreted as a highstand-system-tract of the TB 2.2 global 3rd order sequence. The new results add support to the hypothesis that the

  13. The Search for Methane on Mars

    NASA Astrophysics Data System (ADS)

    Webster, C. R.; Mahaffy, P. R.; Atreya, S. K.; Flesch, G.; Farley, K. A.; Owen, T. C.; Leshin, L. A.; Stern, J. C.; Franz, H.; Eigenbrode, J. L.

    2013-12-01

    Abstract: Over the last several years, Earth-based telescopic and Mars orbit remote sensing instruments have reported significant abundances of methane on Mars ranging to tens of parts-per-billion by volume (ppbv). These observations have reported 'plumes' or localized patches of methane with variations on timescales much faster than model predictions, leading to speculation of sources from sub-surface methanogen bacteria, geological water-rock reactions, degassing of infalling comets, or UV degradation of micro-meteorites or interplanetary dust. More recently, these same groups report that the methane is no longer localized, and appears to have gone away, down to their detection limits of 7-8 ppbv. We will report in situ measurements made by the Tunable Laser Spectrometer (TLS) in the Sample Analysis at Mars (SAM) instrument suite on Curiosity at much higher sensitivity, and over the first year of operation. Additionally, we will report methane abundances and 13CH4 measurements from methane detected in our evolved gas experiments using martian rock drill samples and compare the measurement methods to those used for determining H, C and O isotope ratios in carbon dioxide and water. The research described here was carried out in part at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (NASA).

  14. The evolution and distribution of methane in Lake Champlain sediments

    SciTech Connect

    Thibodeau, P.M. . Dept. of Geology)

    1993-03-01

    Regions of Lake Champlain sediments are acoustically impenetrable to the energy emitted from high resolution, low energy sub-bottom seismic profiling apparatus. This anomolous behavior is caused by the presence of interstitial methane gas which absorbs the wave energy and thus prevents the formation of well-defined seismic boundaries. Through gas chromatographic and carbon isotope analyses, the methane gas contained in the recent sediments of Lake Champlain has been demonstrated to be biogenic in origin. The production of biogenic methane occurs as a result of a series of coupled oxidation-reduction reactions occurring within the upper two meters beneath the sediment-water interface.

  15. Modeling the Terrestrial Contribution to the Global Methane Balance

    NASA Astrophysics Data System (ADS)

    Smith, Amy Tetlow

    Most of the methane emitted into the atmosphere is produced microbiologically. Methanogenic bacteria in soils and sediments of natural wetlands are one of the largest sources of methane. The activity of these organisms is closely linked to environmental conditions. A climate -driven model of methane flux across the terrestrial surface is developed for analysis of atmosphere-biosphere interactions. The methane-flux model is based on temperature response of bacterial populations, and the requirement of anaerobic conditions for growth of methanogenic bacteria or the requirement of aerobic conditions for growth of methane-oxidizing bacteria. A biological inertia factor is also used to reflect dependence on previous bacterial conditions. Model parameters are fit for characteristic ecosystems based on the availability of appropriate time -series data. Using air temperature and precipitation climatologies as both direct and indirect model input, monthly methane fluxes are calculated for muskeg tundra, wet-meadow tundra, temperate and tropical wetlands, cool woods, and tropical savanna. Ecosystem models performed well in diverse environments. Annual -flux totals based on these models are consistent with published methane-budget estimates. To evaluate the global distribution of methane flux, emission estimates from rice cultivation, grazing animals, termites, biomass burning, and fossil fuel extraction and transportation are combined with the ecosystem-model estimates. The resulting global distribution of methane flux shows that the mid-latitudes of the northern hemisphere are the strongest methane source zone. Summer and fall are the most important emission seasons for in any latitudinal zone. My estimated atmospheric residence time of methane, calculated using this global-flux distribution, also agrees well with other published values.

  16. Microbial methane consumption in the oligotrophic surface waters of the East Siberian Arctic Shelf

    NASA Astrophysics Data System (ADS)

    Joye, S. B.

    2011-12-01

    The East Siberian Arctic Shelf (ESAS) accounts for ten percent of the world ocean shelf area and is the shallowest shelf (average depth < 50m). This area is home to a tremendous stock of hydrocarbons, mostly as methane associated with shallow, permafrost-associated hydrates. Thus, the ESAS represents an enormous potential atmospheric methane source that could result from global warming-triggered permafrost destabilization; such a massive methane infusion to the atmosphere from the Arctic could exacerbate and/or accelerate global warming. Increased methane fluxes could occur as numerous weak seeps or strong bubble plumes over large areas. Due to the shallow, well-mixed nature of the ESAS and its oligotrophic waters, the majority of methane entering ESAS water may avoids microbial oxidation and escape to the atmosphere. As part of an international research effort that aims to describe the patterns and controls methane dynamics within the ESAS, we documented methane concentrations and methane oxidation rates and examined environmental and microbiological factors that could regulate methane oxidation activity. Methane concentrations varied spatially and temporally and surface water concentrations were substantially super-saturated at most sites. The highest methane concentrations observed were hundreds of nanomolar. Despite the relatively methane concentrations, methane oxidation rates, determined with tritium-labeled methane tracer, were low, ranging from 10's of picomoles per liter per day to 3 nanomoles per liter per day. By and large, the turnover time for the methane pool was hundreds to thousands of days, which means that methane would be vented to the atmosphere before it was microbially oxidized. The exception to this pattern was in fresh water near the mouth of a river, where methane oxidation rates were high such that the pool turnover time was roughly 4 days. Available data suggest that nutrient availability limits accumulation of methanotroph biomass and

  17. A CLINICAL GUIDE TO THE ASSESSMENT AND TREATMENT OF BREATHING PATTERN DISORDERS IN THE PHYSICALLY ACTIVE: PART 2, A CASE SERIES

    PubMed Central

    Chapman, Erin B.; Nasypany, Alan; Baker, Russell T.; May, Jim

    2016-01-01

    Introduction Breathing pattern disorders (BPDs) are characterized by persistent, suboptimal breathing strategies that may result in additional musculoskeletal pain and/or dysfunction. The purpose of this case series was to examine the effects of Primal Reflex Release Technique (PRRT) and breathing exercise interventions in physically active individuals that presented with a primary complaint of musculoskeletal pain, a BPD, and startle reflexes. Subjects The assessment techniques described in Part 1 of this series were used to identify three student athletes (aged 16-22) who presented with musculoskeletal pain of the low back, mid back, and knee, BPDs, and startle reflexes. The subjects were unable to identify an apparent source of their pain. Intervention The clinician's classification of the subject's breathing patterns guided intervention(s). Each subject was treated once with PRRT and/or a breathing reflex triggering exercise. Results Each of the three subjects demonstrated clinically important improvements on the numerical pain rating scale specific to their tender areas and/or with their primary musculoskeletal complaint. Discussion These findings suggest that it may be useful to assess for a BPD and startle reflexes along with a standard orthopedic evaluation in the physically active athlete. Treatment of BPD's may positively impact musculoskeletal pain and/or dysfunction. Further research is needed to understand the effects of treatment of BPD's and how these effects relate to musculoskeletal dysfunction. Summary The prevalence of BPD with startle reflexes is unknown and implications regarding the assessment for and treatment of BPD has limited research; however, positive results were demonstrated for the three subjects after normalizing breathing patterns. Level of Evidence 4 PMID:27904799

  18. Enzymatic Oxidation of Methane

    SciTech Connect

    Sirajuddin, S; Rosenzweig, AC

    2015-04-14

    Methane monooxygenases (MMOs) are enzymes that catalyze the oxidation of methane to methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane bioconversion processes, MMOs have attracted intense attention in recent years. There are two distinct types of MMO, a soluble, cytoplasmic MMO (sMMO) and a membrane-bound, particulate MMO (pMMO). Both oxidize methane at metal centers within a complex, multisubunit scaffold, but the structures, active sites, and chemical mechanisms are completely different. This Current Topic review article focuses on the overall architectures, active site structures, substrate reactivities, proteinprotein interactions, and chemical mechanisms of both MMOs, with an emphasis on fundamental aspects. In addition, recent advances, including new details of interactions between the sMMO components, characterization of sMMO intermediates, and progress toward understanding the pMMO metal centers are highlighted. The work summarized here provides a guide for those interested in exploiting MMOs for biotechnological applications.

  19. Methane heat transfer investigation

    NASA Technical Reports Server (NTRS)

    1984-01-01

    Future high chamber pressure LOX/hydrocarbon booster engines require copper base alloy main combustion chamber coolant channels similar to the SSME to provide adequate cooling and reusable engine life. Therefore, it is of vital importance to evaluate the heat transfer characteristics and coking thresholds for LNG (94% methane) cooling, with a copper base alloy material adjacent to he fuel coolant. High pressure methane cooling and coking characteristics recently evaluated at Rocketdyne using stainless steel heated tubes at methane bulk temperatures and coolant wall temperatures typical of advanced engine operation except at lower heat fluxes as limited by the tube material. As expected, there was no coking observed. However, coking evaluations need be conducted with a copper base surface exposed to the methane coolant at higher heat fluxes approaching those of future high chamber pressure engines.

  20. Methane heat transfer investigation

    NASA Technical Reports Server (NTRS)

    Cook, R. T.

    1984-01-01

    Future high chamber pressure LOX/hydrocarbon booster engines require copper-base alloy main combustion chamber coolant channels similar to the SSME to provide adequate cooling and resuable engine life. Therefore, it is of vital importance to evaluate the heat transfer characteristics and coking thresholds for LNG (94% methane) cooling, with a copper-base alloy material adjacent to the fuel coolant. High-pressure methane cooling and coking characteristics were recently evaluated using stainless-steel heated tubes at methane bulk temperatures and coolant wall temperatures typical of advanced engine operation except at lower heat fluxes as limited by the tube material. As expected, there was no coking observed. However, coking evaluations need be conducted with a copper-base surface exposed to the methane coolant at higher heat fluxes approaching those of future high chamber pressure engines.

  1. Multiparametric methane sensor for environmental monitoring

    NASA Astrophysics Data System (ADS)

    Borecki, M.; Duk, M.; Kociubiński, A.; Korwin-Pawlowski, M. L.

    2016-12-01

    Today, methane sensors find applications mostly in safety alarm installations, gas parameters detection and air pollution classification. Such sensors and sensors elements exists for industry and home use. Under development area of methane sensors application is dedicated to ground gases monitoring. Proper monitoring of soil gases requires reliable and maintenance-free semi-constant and longtime examination at relatively low cost of equipment. The sensors for soil monitoring have to work on soil probe. Therefore, sensor is exposed to environment conditions, as a wide range of temperatures and a full scale of humidity changes, as well as rain, snow and wind, that are not specified for classical methane sensors. Development of such sensor is presented in this paper. The presented sensor construction consists of five commercial non dispersive infra-red (NDIR) methane sensing units, a set of temperature and humidity sensing units, a gas chamber equipped with a micro-fan, automated gas valves and also a microcontroller that controls the measuring procedure. The electronics part of sensor was installed into customized 3D printed housing equipped with self-developed gas valves. The main development of proposed sensor is on the side of experimental evaluation of construction reliability and results of data processing included safety procedures and function for hardware error correction. Redundant methane sensor units are used providing measurement error correction as well as improved measurement accuracy. The humidity and temperature sensors are used for internal compensation of methane measurements as well as for cutting-off the sensor from the environment when the conditions exceed allowable parameters. Results obtained during environment sensing prove that the gas concentration readings are not sensitive to gas chamber vertical or horizontal position. It is important as vertical sensor installation on soil probe is simpler that horizontal one. Data acquired during six

  2. Methane drainage with horizontal boreholes in advance of longwall mining: an analysis. Final report

    SciTech Connect

    Gabello, D.P.; Felts, L.L.; Hayoz, F.P.

    1981-05-01

    The US Department of Energy (DOE) Morgantown Energy Technology Center has implemented a comprehensive program to demonstrate the technical and economic viability of coalbed methane as an energy resource. The program is directed toward solution of technical and institutional problems impeding the recovery and use of large quantities of methane contained in the nation's minable and unminable coalbeds. Conducted in direct support of the DOE Methane Recovery from Coalbeds Project, this study analyzes the economic aspects of a horizontal borehole methane recovery system integrated as part of a longwall mine operation. It establishes relationships between methane selling price and annual mine production, methane production rate, and the methane drainage system capital investment. Results are encouraging, indicating that an annual coal production increase of approximately eight percent would offset all associated drainage costs over the range of methane production rates and capital investments considered.

  3. Laser beam methane detector

    NASA Technical Reports Server (NTRS)

    Hinkley, E. D., Jr.

    1981-01-01

    Instrument uses infrared absorption to determine methane concentration in liquid natural gas vapor. Two sensors measure intensity of 3.39 mm laser beam after it passes through gas; absorption is proportional to concentration of methane. Instrument is used in modeling spread of LNG clouds and as leak detector on LNG carriers and installations. Unit includes wheels for mobility and is both vertically and horizontally operable.

  4. Electrochemical methane sensor

    DOEpatents

    Zaromb, S.; Otagawa, T.; Stetter, J.R.

    1984-08-27

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  5. Reactor models for a series of continuous stirred tank reactors with a gas-liquid-solid leaching system: Part I. Surface reaction control

    NASA Astrophysics Data System (ADS)

    Papangelakis, V. G.; Demopoulos, G. P.

    1992-12-01

    In this three-part series of articles, comprehensive three-phase steady-state hydrometallurgical reactor models of the continuous stirred tank reactor (CSTR) type are developed and applied to a commercial (pressure oxidation) process. The key features of the developed models are the coupling of both mass and heat balance equations, the description of the nonisothermal performance (autothermal) of a multistage continuous reactor, and the treatment of multimineral feed materials. The model considers only the oxidation reactions, because they mainly affect the thermal balance of the reactor. The stoichiometries and intrinsic kinetics of the heterogeneous leaching reactions, which are established via independent experiments, are the foundation of the developed model. A three-phase (g-l-s) reaction process might be controlled by either surface reaction control, i.e., the rate(s) of the heterogeneous leaching reaction(s), or by gas transfer control, i.e., the rate of transfer of the gaseous reactant into the liquid phase. In the present article (Part I), the case of surface reaction control is treated. The article addresses, in particular, the following topics: (1) it outlines the basic mass and heat balance equations which describe the performance of a multistage leaching reactor; (2) it presents a continuous function to describe the particle size distribution of the feed; and (3) it develops, on the basis of probability theory, number- and mass-particle size density functions which give the size distribution of particle populations reacting according to the surface reaction control-shrinking core model.

  6. Methane Emissions from Upland Forests

    NASA Astrophysics Data System (ADS)

    Megonigal, Patrick; Pitz, Scott; Wang, Zhi-Ping

    2016-04-01

    Global budgets ascribe 4-10% of atmospheric methane sinks to upland soils and assume that soils are the sole surface for methane exchange between upland forests and the atmosphere. The dogma that upland forests are uniformly atmospheric methane sinks was challenged a decade ago by the discovery of abiotic methane production from plant tissue. Subsequently a variety of relatively cryptic microbial and non-microbial methane sources have been proposed that have the potential to emit methane in upland forests. Despite the accumulating evidence of potential methane sources, there are few data demonstrating actual emissions of methane from a plant surface in an upland forest. We report direct observations of methane emissions from upland tree stems in two temperate forests. Stem methane emissions were observed from several tree species that dominate a forest located on the mid-Atlantic coast of North America (Maryland, USA). Stem emissions occurred throughout the growing season while soils adjacent to the trees simultaneously consumed methane. Scaling fluxes by stem surface area suggested the forest was a net methane source during a wet period in June, and that stem emissions offset 5% of the soil methane sink on an annual basis. High frequency measurements revealed diurnal cycles in stem methane emission rates, pointing to soils as the methane source and transpiration as the most likely pathway for gas transport. Similar observations were made in an upland forest in Beijing, China. However, in this case the evidence suggested the methane was not produced in soils, but in the heartwood by microbial or non-microbial processes. These data challenge the concept that forests are uniform sinks of methane, and suggest that upland forests are smaller methane sinks than previously estimated due to stem emissions. Tree emissions may be particularly important in upland tropical forests characterized by high rainfall and transpiration.

  7. The Impact of Methane Clathrate Emissions on the Earth System

    NASA Astrophysics Data System (ADS)

    Cameron-Smith, P. J.; Bhattacharyya, S.; Bergmann, D. J.; Reagan, M. T.; Elliott, S.; Moridis, G. J.

    2013-12-01

    Methane is locked in ice-like deposits called clathrates in ocean sediments and underneath permafrost regions. Clathrates are stable under high pressures and low temperatures, so in a warming climate, increases in ocean temperatures could lead to dissociation of the clathrates and release methane into the ocean and subsequently the atmosphere, where methane is both an important greenhouse gas and a key species in atmospheric chemistry. Clathrates in the shallower parts of the Arctic Ocean (around 300m depth) are predicted to be particularly important since clathrates at that depth are expected to start outgassing abruptly in the next few decades. We will present the atmospheric impact of such methane emissions using multi-century steady-state simulations with a version of the Community Earth System Model (CESM) that includes atmospheric chemistry. Our simulations include a plausible release from clathrates in the Arctic that increases global methane emissions above present-day conditions by 22%, as well as a scenario with 10 times those clathrate emissions. The CESM model includes a fully interactive physical ocean, to which we added a fast atmospheric chemistry mechanism that represents methane as a fully interactive tracer (with emissions rather than concentration boundary conditions). The results indicate that such Arctic clathrate emissions (1) increase global methane concentrations by an average of 38%, non-uniformly; (2) increase surface ozone concentrations by around 10% globally, and even more in polluted regions; (3) increase methane lifetime by 13%; (4) increase the interannual variability in surface methane, surface ozone, and methane lifetime, and (5) show modest differences in surface temperature and methane lifetime compared to simulations in which the clathrate emissions are distributed uniformly. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

  8. Sea-floor methane blow-out and global firestorm at the K-T boundary

    USGS Publications Warehouse

    Max, M.D.; Dillon, William P.; Nishimura, C.; Hurdle, B.G.

    1999-01-01

    A previously unsuspected source of fuel for the global firestorm recorded by soot in the Cretaceous-Tertiary impact layer may have resided in methane gas associated with gas hydrate in the end-Cretaceous seafloor. End-Cretaceous impact-generated shock and megawaves would have had the potential to initiate worldwide oceanic methane gas blow-outs from these deposits. The methane would likely have ignited and incompletely combusted. This large burst of methane would have been followed by longer-term methane release as a part of a positive thermal feedback in the disturbed ocean-atmosphere system.

  9. Eddy covariance based methane flux in Sundarbans mangroves, India

    NASA Astrophysics Data System (ADS)

    Jha, Chandra Shekhar; Rodda, Suraj Reddy; Thumaty, Kiran Chand; Raha, A. K.; Dadhwal, V. K.

    2014-06-01

    We report the initial results of the methane flux measured using eddy covariance method during summer months from the world's largest mangrove ecosystem, Sundarbans of India. Mangrove ecosystems are known sources for methane (CH4) having very high global warming potential. In order to quantify the methane flux in mangroves, an eddy covariance flux tower was recently erected in the largest unpolluted and undisturbed mangrove ecosystem in Sundarbans (India). The tower is equipped with eddy covariance flux tower instruments to continuously measure methane fluxes besides the mass and energy fluxes. This paper presents the preliminary results of methane flux variations during summer months (i.e., April and May 2012) in Sundarbans mangrove ecosystem. The mean concentrations of CH4 emission over the study period was 1682 ± 956 ppb. The measured CH4 fluxes computed from eddy covariance technique showed that the study area acts as a net source for CH4 with daily mean flux of 150.22 ± 248.87 mg m-2 day-1. The methane emission as well as its flux showed very high variability diurnally. Though the environmental conditions controlling methane emission is not yet fully understood, an attempt has been made in the present study to analyse the relationships of methane efflux with tidal activity. This present study is part of Indian Space Research Organisation-Geosphere Biosphere Program (ISRO-GBP) initiative under `National Carbon Project'.

  10. Methane Emissions From Boreal and Tropical Forest Ecosystems

    NASA Astrophysics Data System (ADS)

    Williams, J.; Sinha, V.; Crutzen, P.; Lelieveld, J.

    2006-12-01

    Methane is a climatologically important greenhouse gas and plays a key role in regulating water vapour in the stratosphere and hydroxyl radicals in the troposphere. Recent findings that vegetation emits methane have stimulated efforts to ascertain the impact of this source on the global budget of this trace gas. In this work, we present the results of high frequency (1 minute) methane measurements conducted in the boreal forests of Finland and the tropical forests of Suriname, in April-May, 2005 and October 2005 respectively. The measurements were performed using a gas chromatograph - flame ionization detector (GC-FID). The average of the median mixing ratios during a typical diel cycle were 1.83 μmol mol-1 and 1.74 μmol mol-1 for the boreal forest ecosystem and tropical forest ecosystem respectively, with remarkable similarity in the time series of both the boreal and tropical diel profiles. Night time methane emission flux of the boreal forest ecosystem, calculated from the increase of methane during the night and measured nocturnal boundary layer heights yields a flux of 3.62 x 1011 molecules cm-2 s-1.These results highlight the importance of the boreal and tropical forest ecosystems for the global budget of methane. We also discuss our results in the context of recent work reporting high methane mixing ratios over tropical forests using space borne near infra red spectroscopy measurements.

  11. Combustion of Methane Hydrate

    NASA Astrophysics Data System (ADS)

    Roshandell, Melika

    A significant methane storehouse is in the form of methane hydrates on the sea floor and in the arctic permafrost. Methane hydrates are ice-like structures composed of water cages housing a guest methane molecule. This caged methane represents a resource of energy and a potential source of strong greenhouse gas. Most research related to methane hydrates has been focused on their formation and dissociation because they can form solid plugs that complicate transport of oil and gas in pipelines. This dissertation explores the direct burning of these methane hydrates where heat from the combustion process dissociates the hydrate into water and methane, and the released methane fuels the methane/air diffusion flame heat source. In contrast to the pipeline applications, very little research has been done on the combustion and burning characteristics of methane hydrates. This is the first dissertation on this subject. In this study, energy release and combustion characteristics of methane hydrates were investigated both theoretically and experimentally. The experimental study involved collaboration with another research group, particularly in the creation of methane hydrate samples. The experiments were difficult because hydrates form at high pressure within a narrow temperature range. The process can be slow and the resulting hydrate can have somewhat variable properties (e.g., extent of clathration, shape, compactness). The experimental study examined broad characteristics of hydrate combustion, including flame appearance, burning time, conditions leading to flame extinguishment, the amount of hydrate water melted versus evaporated, and flame temperature. These properties were observed for samples of different physical size. Hydrate formation is a very slow process with pure water and methane. The addition of small amounts of surfactant increased substantially the hydrate formation rate. The effects of surfactant on burning characteristics were also studied. One finding

  12. Environmental control on aerobic methane oxidation in coastal waters

    NASA Astrophysics Data System (ADS)

    Steinle, Lea; Maltby, Johanna; Engbersen, Nadine; Zopfi, Jakob; Bange, Hermann; Elvert, Marcus; Hinrichs, Kai-Uwe; Kock, Annette; Lehmann, Moritz; Treude, Tina; Niemann, Helge

    2016-04-01

    Large quantities of methane are produced in anoxic sediments of continental margins and may be liberated to the overlying water column, where some of it is consumed by aerobic methane oxidizing bacteria (MOB). Aerobic methane oxidation (MOx) in the water column is consequently the final sink for methane before its release to the atmosphere, where it acts as a potent greenhouse gas. In the context of the ocean's contribution to atmospheric methane, coastal seas are particularly important accounting >75% of global methane emission from marine systems. Coastal oceans are highly dynamic, in particular with regard to the variability of methane and oxygen concentrations as well as temperature and salinity, all of which are potential key environmental factors controlling MOx. To determine important environmental controls on the activity of MOBs in coastal seas, we conducted a two-year time-series study with measurements of physicochemical water column parameters, MOx activity and the composition of the MOB community in a coastal inlet in the Baltic Sea (Boknis Eck Time Series Station, Eckernförde Bay - E-Bay). In addition, we investigated the influence of temperature and oxygen on MOx during controlled laboratory experiments. In E-Bay, hypoxia developed in bottom waters towards the end of the stratification period. Constant methane liberation from sediments resulted in bottom water methane accumulations and supersaturation (with respect to the atmospheric equilibrium) in surface waters. Here, we will discuss the factors impacting MOx the most, which were (i) perturbations of the water column (ii) temperature and (iii) oxygen concentration. (i) Perturbations of the water column caused by storm events or seasonal mixing led to a decrease in MOx, probably caused by replacement of stagnant water with a high standing stock of MOB by 'new' waters with a lower abundance of methanotrophs. b) An increase in temperature generally led to higher MOx rates. c) Even though methane was

  13. Leaking methane reservoirs offshore Svalbard

    NASA Astrophysics Data System (ADS)

    Minshull, T. A.; Westbrook, G. K.; Weitemeyer, K. A.; Sinha, M. C.; Goswami, B. K.; Marsset, B.

    2012-10-01

    Methane hydrate—a solid substance in which methane is trapped within ice-like crystals—is stable at low temperatures and high pressures and may be destabilized by ocean warming on both geological and human time scales. Methane is a powerful greenhouse gas, and methane released from hydrate provides a potential positive feedback mechanism in global climate change [e.g., Archer and Buffett, 2005]—in theory, the more methane is released by the hydrates, the warmer the climate gets, causing the ocean to warm and release more methane. However, methane escaping from the seabed is oxidized and dissolved in the ocean, and insufficient methane may reach the atmosphere to affect the climate significantly. Its importance for climate change therefore depends on whether the flux from the seabed is great enough to overcome solution in the ocean and perturb atmospheric concentrations over sufficiently long time scales.

  14. The basics of coalbed methane

    SciTech Connect

    2006-12-15

    The report is an overview of coalbed methane (CBM), also known as coal seam gas. It provides an overview of what coalbed methane is and the current status of global coalbed methane exploration and production. Topics covered in the report include: An analysis of the natural gas industry, including current and future production, consumption, and reserves; A detailed description of coalbed methane, its characteristics, and future potential; An analysis of the key business factors that are driving the increased interest in coalbed methane; An analysis of the barriers that are hindering the development of coalbed methane; An overview of the technologies used for coalbed methane production and water treatment; and Profiles of key coalbed methane producing countries. 25 figs., 5 tabs., 1 app.

  15. Transformations in methane hydrates

    USGS Publications Warehouse

    Chou, I.-Ming; Sharma, A.; Burruss, R.C.; Shu, J.; Mao, Ho-kwang; Hemley, R.J.; Goncharov, A.F.; Stern, L.A.; Kirby, S.H.

    2000-01-01

    Detailed study of pure methane hydrate in a diamond cell with in situ optical, Raman, and x-ray microprobe techniques reveals two previously unknown structures, structure II and structure H, at high pressures. The structure II methane hydrate at 250 MPa has a cubic unit cell of a = 17.158(2) A?? and volume V = 5051.3(13) A??3; structure H at 600 MPa has a hexagonal unit cell of a = 11.980(2) A??, c = 9.992(3) A??, and V = 1241.9(5) A??3. The compositions of these two investigated phases are still not known. With the effects of pressure and the presence of other gases in the structure, the structure II phase is likely to dominate over the known structure I methane hydrate within deep hydrate-bearing sediments underlying continental margins.

  16. Charters, Constitutions and By-Laws of the Indian Tribes of North America. Part II: The Indian Tribes of Wisconsin (Great Lakes Agency). Occasional Publications in Anthropology, Ethnology Series, No. 2.

    ERIC Educational Resources Information Center

    Fay, George E., Comp.

    Part II of a series of publications consisting of American Indian tribal governmental documents, this volume includes charters, constitutions, and by-laws of Indian tribes of Wisconsin (Great Lakes Agency). Documents are included relative to the Bad River, Lac Courte Oreilles, Lac du Flambeau, and the Red Cliff bands of Lake Superior Chippewa…

  17. Clumped isotope effects during OH and Cl oxidation of methane

    NASA Astrophysics Data System (ADS)

    Whitehill, Andrew R.; Joelsson, Lars Magnus T.; Schmidt, Johan A.; Wang, David T.; Johnson, Matthew S.; Ono, Shuhei

    2017-01-01

    A series of experiments were carried out to determine the clumped (13CH3D) methane kinetic isotope effects during oxidation of methane by OH and Cl radicals, the major sink reactions for atmospheric methane. Experiments were performed in a 100 L quartz photochemical reactor, in which OH was produced from the reaction of O(1D) (from O3 photolysis) with H2O, and Cl was from photolysis of Cl2. Samples were taken from the reaction cell and analyzed for methane (12CH4, 12CH3D, 13CH4, 13CH3D) isotopologue ratios using tunable infrared laser direct absorption spectroscopy. Measured kinetic isotope effects for singly substituted species were consistent with previous experimental studies. For doubly substituted methane, 13CH3D, the observed kinetic isotope effects closely follow the product of the kinetic isotope effects for the 13C and deuterium substituted species (i.e., 13,2KIE = 13KIE × 2KIE). The deviation from this relationship is 0.3‰ ± 1.2‰ and 3.5‰ ± 0.7‰ for OH and Cl oxidation, respectively. This is consistent with model calculations performed using quantum chemistry and transition state theory. The OH and Cl reactions enrich the residual methane in the clumped isotopologue in open system reactions. In a closed system, however, this effect is overtaken by the large D/H isotope effect, which causes the residual methane to become anti-clumped relative to the initial methane. Based on these results, we demonstrate that oxidation of methane by OH, the predominant oxidant for tropospheric methane, will only have a minor (∼0.3‰) impact on the clumped isotope signature (Δ13CH3D, measured as a deviation from a stochastic distribution of isotopes) of tropospheric methane. This paper shows that Δ13CH3D will provide constraints on methane source strengths, and predicts that Δ12CH2D2 can provide information on methane sink strengths.

  18. Perspectives On The Global Budget of Methane

    NASA Astrophysics Data System (ADS)

    Khalil, M. K.; Butenhoff, C. L.; Shearer, M. J.

    2008-12-01

    Early budgets of methane focused on the emissions from individual sources but the estimates had large uncertainties. These uncertainties have been reduced considerably in recent years, but we need an understanding of the trends in the sources as well as their spatial distributions if we are to use methane to control global warming. A nearly 30 year long time series of global atmospheric methane concentrations has accumulated that can provide some of the answers. One of the most dramatic findings is that the increase of methane has nearly stopped in the last decade. But the record also shows that the trend was falling ever since systematic measurements were taken, and perhaps even before that. This finding has led to some puzzles. There is a belief that the anthropogenic sources of methane are increasing but to explain the falling trend we need decreasing sources (or increasing sinks). In fact, the atmospheric measurements show only that the most probable explanation for the decreasing trend and the present near constancy of concentrations is that the global source of methane has been more or less constant over the last 30 years with many short-term ups and downs. Moreover, there is good evidence that some of the major man-made sources of methane, such as cattle, biomass burning and possibly others, have stopped increasing some time back and other sources such as rice agriculture may have decreased over the last 30 years. This allows some smaller energy based sources to have increased, consistent with expectations, and balance out the decreasing sources to keep the total more or less constant. A credible quantitative case can be made for a stable global source based on available information on the trends of the various sources and sinks of methane, but uncertainties remain. We will argue that the stability of sources and sinks is the most likely explanation of the methane concentration trends. We will use this result to re-evaluate the future of man- made methane

  19. Methane in Crystalline Bedrock: the Outokumpu Deep Drill Hole, Finland

    NASA Astrophysics Data System (ADS)

    Kietäväinen, R.; Ahonen, L.; Niinikoski, P.; Itävaara, M.; Kukkonen, I. T.

    2014-12-01

    Carbon is a key element for life. One of the most interesting forms of carbon is methane, as it is both consumed and produced by microorganisms. Methane has also several possible ways of abiotic origin, some of which could provide understanding of the origin of life itself. The study of methane is thus important in order to understand deep subsurface ecosystems such as those found in the 2516 m deep Outokumpu Deep Drill Hole within the Precambrian Fennoscandian Shield in eastern Finland. There rock types differ from graphite-bearing mica schist and black schist to serpentinite and pegmatitic granodiorite and saline, gas-rich water, with up to 32 mmol l-1 of methane, and residence times of tens of millions of years occupies the fracture zones which host diverse microbial life, including methanogenic archaea. In order to understand methane systematics in crystalline bedrock, we analysed several forms of carbon, including dissolved inorganic carbon (DIC), methane and ethane from the Outokumpu Deep Drill Hole for their isotopic composition. In addition, isotopic compositions of water and hydrogen were determined. The results show that hydrogen is in isotopic equilibrium in the system H2O-H2-CH4 at ambient temperatures, which could either indicate equilibration due to long residence time or relatively recent production of methane in situ. Therefore hydrogen is not a very useful indicator for the origin of methane in this case. Carbon isotope analysis shows that both methane and DIC becomes generally more enriched in 13C with depth, which could indicate higher amounts of microbial methane in the upper part of the bedrock. Based on carbon isotope composition, two types of ethane can be discerned. Taken all the evidence together, this leads us to suggest that at least two mechanisms are responsible for the methane production in Outokumpu: 1) Biotic which comprise most of methane and 2) abiotic which dominates in the deeper parts of the bedrock. The former type may include

  20. Series Bosch System Development

    NASA Technical Reports Server (NTRS)

    Abney, Morgan B.; Evans, Christopher; Mansell, Matt; Swickrath, Michael

    2012-01-01

    State-of-the-art (SOA) carbon dioxide (CO2) reduction technology for the International Space Station produces methane as a byproduct. This methane is subsequently vented overboard. The associated loss of hydrogen ultimately reduces the mass of oxygen that can be recovered from CO2 in a closed-loop life support system. As an alternative to SOA CO2 reduction technology, NASA is exploring a Series-Bosch system capable of reducing CO2 with hydrogen to form water and solid carbon. This results in 100% theoretical recovery of oxygen from metabolic CO2. In the past, Bosch-based technology did not trade favorably against SOA technology due to a high power demand, low reaction efficiencies, concerns with carbon containment, and large resupply requirements necessary to replace expended catalyst cartridges. An alternative approach to Bosch technology, labeled "Series-Bosch," employs a new system design with optimized multi-stage reactors and a membrane-based separation and recycle capability. Multi-physics modeling of the first stage reactor, along with chemical process modeling of the integrated system, has resulted in a design with potential to trade significantly better than previous Bosch technology. The modeling process and resulting system architecture selection are discussed.

  1. 32 CFR Appendix C to Part 197 - Procedures for the Department of State (DoS) Foreign Relations of the United States (FRUS) Series

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the DoS for the FRUS series under Public Law No. 102-138. b. Request authorization from the CIA, NSC.... Submit to the respective Agency a list of CIA and NSC documents copied and released to the...

  2. 32 CFR Appendix C to Part 197 - Procedures for the Department of State (DoS) Foreign Relations of the United States (FRUS) Series

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... the DoS for the FRUS series under Public Law No. 102-138. b. Request authorization from the CIA, NSC.... Submit to the respective Agency a list of CIA and NSC documents copied and released to the...

  3. 32 CFR Appendix C to Part 197 - Procedures for the Department of State (DoS) Foreign Relations of the United States (FRUS) Series

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the DoS for the FRUS series under Public Law No. 102-138. b. Request authorization from the CIA, NSC.... Submit to the respective Agency a list of CIA and NSC documents copied and released to the...

  4. 32 CFR Appendix C to Part 197 - Procedures for the Department of State (DoS) Foreign Relations of the United States (FRUS) Series

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... the DoS for the FRUS series under Public Law No. 102-138. b. Request authorization from the CIA, NSC.... Submit to the respective Agency a list of CIA and NSC documents copied and released to the...

  5. 32 CFR Appendix C to Part 197 - Procedures for the Department of State (DoS) Foreign Relations of the United States (FRUS) Series

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... the DoS for the FRUS series under Public Law No. 102-138. b. Request authorization from the CIA, NSC.... Submit to the respective Agency a list of CIA and NSC documents copied and released to the...

  6. Methane emissions from natural wetlands

    SciTech Connect

    Meyer, J.L.; Burke, R.A. Jr.

    1993-09-01

    Analyses of air trapped in polar ice cores in conjunction with recent atmospheric measurements, indicate that the atmospheric methane concentration increased by about 250% during the past two or three hundred years (Rasmussen and Khalil, 1984). Because methane is a potent ``greenhouse`` gas, the increasing concentrations are expected to contribute to global warning (Dickinson and Cicerone, 1986). The timing of the methane increase suggests that it is related to the rapid growth of the human population and associated industrialization and agricultural development. The specific causes of the atmospheric methane concentration increase are not well known, but may relate to either increases in methane sources, decreases in the strengths of the sinks, or both.

  7. Liquid Methane/Oxygen Injector Study for Mars Ascent Engines

    NASA Technical Reports Server (NTRS)

    Trinh, Huu Phuoc

    1999-01-01

    As a part of the advancing technology of the cryogenic propulsion system for the Mars exploration mission, this effort aims at evaluating propellant injection concepts for liquid methane/liquid oxygen (LOX) rocket engines. Split-triplet and unlike impinging injectors were selected for this study. A total of four injector configurations were tested under combustion conditions in a modular combustor test article (MCTA), equipped with optically accessible windows, at MSFC. A series of forty hot-fire tests, which covered a wide range of engine operating conditions with the chamber pressure ranging from 320 to 510 and the mixture ratio from 1.5 to 3.5, were conducted. The test matrix also included a variation in the combustion chamber length for the purpose of investigating its effects on the combustion performance and stability. Initial assessments of the test results showed that the injectors provided stable combustion and there were no injector face overheating problems under all operating conditions. The Raman scattering signal measurement method was successfully demonstrated for the hydrocarbon/oxygen reactive flow field. The near-injector face flow field was visually observed through the use of an infrared camera. Chamber wall temperature, high frequency chamber pressure, and average throat section heat flux were also recorded throughout the test series. Assessments of the injector performance are underway.

  8. Methane Clathrate Hydrate Prospecting

    NASA Technical Reports Server (NTRS)

    Duxbury, N.; Romanovsky, V.

    2003-01-01

    A method of prospecting for methane has been devised. The impetus for this method lies in the abundance of CH4 and the growing shortages of other fuels. The method is intended especially to enable identification of subpermafrost locations where significant amounts of methane are trapped in the form of methane gas hydrate (CH4(raised dot)6H2O). It has been estimated by the U.S. Geological Survey that the total CH4 resource in CH4(raised dot) 6H2O exceeds the energy content of all other fossil fuels (oil, coal, and natural gas from non-hydrate sources). Also, CH4(raised dot)6H2O is among the cleanest-burning fuels, and CH4 is the most efficient fuel because the carbon in CH4 is in its most reduced state. The method involves looking for a proxy for methane gas hydrate, by means of the combination of a thermal-analysis submethod and a field submethod that does not involve drilling. The absence of drilling makes this method easier and less expensive, in comparison with prior methods of prospecting for oil and natural gas. The proposed method would include thermoprospecting in combination with one more of the other non-drilling measurement techniques, which could include magneto-telluric sounding and/or a subsurface-electrical-resistivity technique. The method would exploit the fact that the electrical conductivity in the underlying thawed region is greater than that in the overlying permafrost.

  9. Development of Sand Production Evaluation Apparatus for Methane Hydrate Development

    NASA Astrophysics Data System (ADS)

    Kakumoto, M.; Yoneda, J.; Tenma, N.; Katagiri, J.; Noda, S.

    2015-12-01

    As a part of a Japanese National hydrate research program (MH21, funded by METI), we performed a study on sand production mechanism during methane gas production. In 2013, the first methane hydrate offshore production test was conducted in Japan, and it was recognized in the production of about 20000m3/day of methane gas from methane hydrate bearing sand sediment in deep marine sediment. In methane hydrate development, depressurization method has been proposed for gas extraction. This method is a method to reduce the bottom hole pressure by submersible pump lowering water level in the production well, and gas and water is recovered by methane hydrate dissociation at the in situ. At that time, a phenomenon that sand flows into the wells is feared. In actually, sand production phenomenon occurred after 6 days from production start in offshore production test. A mechanism of sand production has not yet been resolved in case of methane hydrate development. Therefore, we developed large scale laboratory test apparatus for the purpose of elucidation of the mechanism of sand production phenomenon. In this presentation, we introduce basic performance of this apparatus, and usefulness is made mention by representative test results.

  10. Lead optimization of the VU0486321 series of mGlu(1) PAMs. Part 2: SAR of alternative 3-methyl heterocycles and progress towards an in vivo tool.

    PubMed

    Garcia-Barrantes, Pedro M; Cho, Hyekyung P; Metts, Adam M; Blobaum, Anna L; Niswender, Colleen M; Conn, P Jeffrey; Lindsley, Craig W

    2016-02-01

    This Letter describes the further lead optimization of the VU0486321 series of mGlu1 positive allosteric modulators (PAMs), driven by recent genetic data linking loss of function GRM1 to schizophrenia. Steep and caveat-laden SAR plagues the series, but ultimately potent mGlu1 PAMs (EC50s ∼5 nM) have resulted with good DMPK properties (low intrinsic clearance, clean CYP profile, modest Fu) and CNS penetration (Kps 0.25-0.97), along with up to >450-fold selectivity versus mGlu4 and mGlu5.

  11. Methane cycling. Nonequilibrium clumped isotope signals in microbial methane.

    PubMed

    Wang, David T; Gruen, Danielle S; Lollar, Barbara Sherwood; Hinrichs, Kai-Uwe; Stewart, Lucy C; Holden, James F; Hristov, Alexander N; Pohlman, John W; Morrill, Penny L; Könneke, Martin; Delwiche, Kyle B; Reeves, Eoghan P; Sutcliffe, Chelsea N; Ritter, Daniel J; Seewald, Jeffrey S; McIntosh, Jennifer C; Hemond, Harold F; Kubo, Michael D; Cardace, Dawn; Hoehler, Tori M; Ono, Shuhei

    2015-04-24

    Methane is a key component in the global carbon cycle, with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its multiply substituted "clumped" isotopologues (for example, (13)CH3D) has recently emerged as a proxy for determining methane-formation temperatures. However, the effect of biological processes on methane's clumped isotopologue signature is poorly constrained. We show that methanogenesis proceeding at relatively high rates in cattle, surface environments, and laboratory cultures exerts kinetic control on (13)CH3D abundances and results in anomalously elevated formation-temperature estimates. We demonstrate quantitatively that H2 availability accounts for this effect. Clumped methane thermometry can therefore provide constraints on the generation of methane in diverse settings, including continental serpentinization sites and ancient, deep groundwaters.

  12. Project identification for methane reduction options

    SciTech Connect

    Kerr, T.

    1996-12-31

    This paper discusses efforts directed at reduction in emission of methane to the atmosphere. Methane is a potent greenhouse gas, which on a 20 year timeframe may present a similar problem to carbon dioxide. In addition, methane causes additional problems in the form of smog and its longer atmospheric lifetime. The author discusses strategies for reducing methane emission from several major sources. This includes landfill methane recovery, coalbed methane recovery, livestock methane reduction - in the form of ruminant methane reduction and manure methane recovery. The author presents examples of projects which have implemented these ideas, the economics of the projects, and additional gains which come from the projects.

  13. Charters, Constitutions and By-Laws of the Indian Tribes of North America; Part III: The Southwest (Apache--Mohave). Occasional Publications in Anthropology Ethnology Series No. 4.

    ERIC Educational Resources Information Center

    Fay, George E., Comp.

    The Museum of Anthropology of the University of Northern Colorado (formerly known as Colorado State College) has assembled a large number of Indian tribal charters, constitutions, and by-laws to be reproduced as a series of publications. Included in this volume are the amended charter and constitution of the Jicarilla Apache Tribe, Dulce, New…

  14. Testing & Research, Part I. Options in Education: Program Transcripts of a Weekly Series Broadcast by Member Stations of National Public Radio. Program No. 78.

    ERIC Educational Resources Information Center

    George Washington Univ., Washington, DC. Inst. for Educational Leadership.

    Several program transcripts on educational testing from the National Public Radio series, Options in Education, are included in this pamphlet. In "The I.Q. Controversy," Ned Block discusses culturally biased standardized tests. Dr. Harold Hodgkinson, former Director of the National Institute of Education, and Noel Epstein, Education Editor of the…

  15. Charters, Constitutions and By-Laws of Indian Tribes of North America. Part I: The Sioux Tribes of South Dakota. Occasional Publications in Anthropology, Ethnology Series, No. 1.

    ERIC Educational Resources Information Center

    Fay, George E., Comp.

    To facilitate the study and understanding of present-day Indian tribal organization and governmental procedures, the Museum of Anthropology of the University of Northern Colorado (formerly known as Colorado State College) has assembled a large number of Indian tribal charters, constitutions, and by-laws to be reproduced as a series of…

  16. Diffusion of methane (1); water (2); calcium chloride (3)

    NASA Astrophysics Data System (ADS)

    Winkelmann, J.

    This document is part of Subvolume A `Gases in Gases, Liquids and their Mixtures' of Volume 15 `Diffusion in Gases, Liquids and Electrolytes' of Landolt-Börnstein Group IV `Physical Chemistry'. It is part of the chapter of the chapter `Diffusion in Pure Gases' and contains data on diffusion of (1) methane; (2) water; (3) calcium chloride

  17. Field and experimental evidence for low-O2 affinity of aerobic methane oxidizers in coastal waters

    NASA Astrophysics Data System (ADS)

    Steinle, Lea; Maltby, Johanna; Bange, Hermann; Kock, Annette; Lehmann, Moritz F.; Treude, Tina; Niemann, Helge

    2015-04-01

    The coastal ocean accounts for more than 75 % of the global oceanic methane emissions. An important process in mitigating methane emissions from the seawater to the atmosphere is aerobic methane oxidation (MOx). Coastal oceans are highly dynamic systems, in particular with regard to the variability of temperature, salinity, and oxygen concentrations, all of which are potential key environmental factors controlling MOx. We conducted a two-year time-series study of MOx measurements in the water column of a coastal inlet in the southwestern Baltic Sea (Eckernförde Bay, Boknis Eck Time Series Station, 54°31.823 N, 10°02.764 E, 28 m water depth; www.bokniseck.de). Physicochemical parameters at this station have been monitored since 1957. Seasonal stratification during summer/autumn leads to intermittent oxygen depletion (hypoxic to anoxic) in bottom waters in the later part of the stratification period. The duration of these low-oxygen events increased since the 1970s (Lennartz et al., 2014). Furthermore, the organic-rich seafloor continuously produces methane, which leads to gas ebullition followed by accumulation of dissolved methane in bottom waters (up to 470 nM) and supersaturation (with respect to the atmospheric equilibrium) in surface waters (up to 27 nM). MOx communities were most active in bottom waters (1-5 nM/day), which usually contain the lowest oxygen concentrations (sometimes below the in situ detection limit of ~1 µM). In order to better understand the effect of low oxygen concentrations, and thus of hypoxic and suboxic events, on MOx in coastal systems, we conducted lab-based experiments, during which we adjusted oxygen concentrations to values between 0.2 - 220 µM in methane-rich (~100 nM) Eckernförde Bay waters. These samples were then incubated with trace amounts of tritium-labeled methane to assess first order rate constants of methane oxidation. Highest MOx rates were detected at oxygen concentrations of ~0.5 µM (considerably higher than at

  18. Low upper limit to methane abundance on Mars.

    PubMed

    Webster, Christopher R; Mahaffy, Paul R; Atreya, Sushil K; Flesch, Gregory J; Farley, Kenneth A

    2013-10-18

    By analogy with Earth, methane in the Martian atmosphere is a potential signature of ongoing or past biological activity. During the past decade, Earth-based telescopic observations reported "plumes" of methane of tens of parts per billion by volume (ppbv), and those from Mars orbit showed localized patches, prompting speculation of sources from subsurface bacteria or nonbiological sources. From in situ measurements made with the Tunable Laser Spectrometer (TLS) on Curiosity using a distinctive spectral pattern specific to methane, we report no detection of atmospheric methane with a measured value of 0.18 ± 0.67 ppbv corresponding to an upper limit of only 1.3 ppbv (95% confidence level), which reduces the probability of current methanogenic microbial activity on Mars and limits the recent contribution from extraplanetary and geologic sources.

  19. World-wide increase in tropospheric methane, 1978-1983

    NASA Technical Reports Server (NTRS)

    Blake, D. R.; Rowland, F. S.

    1986-01-01

    Techniques used to assess methane concentration in the troposphere are described, and data obtained during the period from 1978 to 1983 are presented in detail. Tropospheric methane concentrations in remote locations averaged a yearly world-wide increase of 0.018 + or - 0.002 parts per million by volume (ppmv). Average world-wide tropospheric concentration of methane in dry air was 1.625 ppmv at the end of 1983 measured against an NBS standard certified as 0.97 ppmv. Contributing to this steady increase in methane concentration are increases in the source strengths from cattle and rice fields, which in turn result from CO, CH4 and HO coupling. Among the physical and chemical effects is an increase in greenhouse warming of about 0.04 C per decade.

  20. Mars atmosphere. Mars methane detection and variability at Gale crater.

    PubMed

    Webster, Christopher R; Mahaffy, Paul R; Atreya, Sushil K; Flesch, Gregory J; Mischna, Michael A; Meslin, Pierre-Yves; Farley, Kenneth A; Conrad, Pamela G; Christensen, Lance E; Pavlov, Alexander A; Martín-Torres, Javier; Zorzano, María-Paz; McConnochie, Timothy H; Owen, Tobias; Eigenbrode, Jennifer L; Glavin, Daniel P; Steele, Andrew; Malespin, Charles A; Archer, P Douglas; Sutter, Brad; Coll, Patrice; Freissinet, Caroline; McKay, Christopher P; Moores, John E; Schwenzer, Susanne P; Bridges, John C; Navarro-Gonzalez, Rafael; Gellert, Ralf; Lemmon, Mark T

    2015-01-23

    Reports of plumes or patches of methane in the martian atmosphere that vary over monthly time scales have defied explanation to date. From in situ measurements made over a 20-month period by the tunable laser spectrometer of the Sample Analysis at Mars instrument suite on Curiosity at Gale crater, we report detection of background levels of atmospheric methane of mean value 0.69 ± 0.25 parts per billion by volume (ppbv) at the 95% confidence interval (CI). This abundance is lower than model estimates of ultraviolet degradation of accreted interplanetary dust particles or carbonaceous chondrite material. Additionally, in four sequential measurements spanning a 60-sol period (where 1 sol is a martian day), we observed elevated levels of methane of 7.2 ± 2.1 ppbv (95% CI), implying that Mars is episodically producing methane from an additional unknown source.

  1. Mars methane detection and variability at Gale crater

    NASA Astrophysics Data System (ADS)

    Webster, Christopher R.; Mahaffy, Paul R.; Atreya, Sushil K.; Flesch, Gregory J.; Mischna, Michael A.; Meslin, Pierre-Yves; Farley, Kenneth A.; Conrad, Pamela G.; Christensen, Lance E.; Pavlov, Alexander A.; Martín-Torres, Javier; Zorzano, María-Paz; McConnochie, Timothy H.; Owen, Tobias; Eigenbrode, Jennifer L.; Glavin, Daniel P.; Steele, Andrew; Malespin, Charles A.; Archer, P. Douglas; Sutter, Brad; Coll, Patrice; Freissinet, Caroline; McKay, Christopher P.; Moores, John E.; Schwenzer, Susanne P.; Bridges, John C.; Navarro-Gonzalez, Rafael; Gellert, Ralf; Lemmon, Mark T.; MSL Science Team; Abbey, William; Achilles, Cherie; Agard, Christophe; Alexandre Alves Verdasca, José; Anderson, Dana; Anderson, Robert C.; Anderson, Ryan B.; Appel, Jan Kristoffer; Archer, Paul Douglas; Arevalo, Ricardo; Armiens-Aparicio, Carlos; Arvidson, Raymond; Atlaskin, Evgeny; Atreya, Andrew Sushil; Azeez, Aubrey Sherif; Baker, Burt; Baker, Michael; Balic-Zunic, Tonci; Baratoux, David; Baroukh, Julien; Barraclough, Bruce; Battalio, Michael; Beach, Michael; Bean, Keri; Beck, Pierre; Becker, Richard; Beegle, Luther; Behar, Alberto; Belgacem, Inès; Bell, James F., III; Bender, Steven; Benna, Mehdi; Bentz, Jennifer; Berger, Jeffrey; Berger, Thomas; Berlanga, Genesis; Berman, Daniel; Bish, David; Blacksberg, Jordana; Blake, David F.; José Blanco, Juan; Blaney, Ávalos Diana; Blank, Jennifer; Blau, Hannah; Bleacher, Lora; Boehm, Eckart; Bonnet, Jean-Yves; Botta, Oliver; Böttcher, Stephan; Boucher, Thomas; Bower, Hannah; Boyd, Nick; Boynton, William; Braswell, Shaneen; Breves, Elly; Bridges, John C.; Bridges, Nathan; Brinckerhoff, William; Brinza, David; Bristow, Thomas; Brunet, Claude; Brunner, Anna; Brunner, Will; Buch, Arnaud; Bullock, Mark; Burmeister, Sönke; Burton, John; Buz, Jennifer; Cabane, Michel; Calef, Fred; Cameron, James; Campbell, John L.; Cantor, Bruce; Caplinger, Michael; Clifton, Carey, Jr.; Caride Rodríguez, Javier; Carmosino, Marco; Carrasco Blázquez, Isaías; Cavanagh, Patrick; Charpentier, Antoine; Chipera, Steve; Choi, David; Christensen, Lance; Clark, Benton; Clegg, Sam; Cleghorn, Timothy; Cloutis, Ed; Cody, George; Coll, Patrice; Coman, Ecaterina I.; Conrad, Pamela; Coscia, David; Cousin, Agnès; Cremers, David; Crisp, Joy A.; Cropper, Kevin; Cros, Alain; Cucinotta, Francis; d'Uston, Claude; Davis, Scott; Day, Mackenzie; Daydou, Yves; DeFlores, Lauren; Dehouck, Erwin; Delapp, Dorothea; DeMarines, Julia; Dequaire, Tristan; Des Marais, David; Desrousseaux, Roch; Dietrich, William; Dingler, Robert; Domagal-Goldman, Shawn; Donny, Christophe; Downs, Robert; Drake, Darrell; Dromart, Gilles; Dupont, Audrey; Duston, Brian; Dworkin, Jason P.; Dyar, M. Darby; Edgar, Lauren; Edgett, Kenneth; Edwards, Christopher S.; Edwards, Laurence; Edwards, Peter; Ehlmann, Bethany; Ehresmann, Bent; Eigenbrode, Jennifer; Elliott, Beverley; Elliott, Harvey; Ewing, Ryan; Fabre, Cécile; Fairén, Alberto; Fairén, Alberto; Farley, Kenneth; Farmer, Jack; Fassett, Caleb; Favot, Laurent; Fay, Donald; Fedosov, Fedor; Feldman, Jason; Fendrich, Kim; Fischer, Erik; Fisk, Martin; Fitzgibbon, Mike; Flesch, Gregory; Floyd, Melissa; Flückiger, Lorenzo; Forni, Olivier; Fox, Valerie; Fraeman, Abigail; Francis, Raymond; François, Pascaline; Franz, Heather; Freissinet, Caroline; French, Katherine Louise; Frydenvang, Jens; Garvin, James; Gasnault, Olivier; Geffroy, Claude; Gellert, Ralf; Genzer, Maria; Getty, Stephanie; Glavin, Daniel; Godber, Austin; Goesmann, Fred; Goetz, Walter; Golovin, Dmitry; Gómez Gómez, Felipe; Gómez-Elvira, Javier; Gondet, Brigitte; Gordon, Suzanne; Gorevan, Stephen; Graham, Heather; Grant, John; Grinspoon, David; Grotzinger, John; Guillemot, Philippe; Guo, Jingnan; Gupta, Sanjeev; Guzewich, Scott; Haberle, Robert; Halleaux, Douglas; Hallet, Bernard; Hamilton, Victoria; Hand, Kevin; Hardgrove, Craig; Hardy, Keian; Harker, David; Harpold, Daniel; Harri, Ari-Matti; Harshman, Karl; Hassler, Donald; Haukka, Harri; Hayes, Alexander; Herkenhoff, Kenneth; Herrera, Paul; Hettrich, Sebastian; Heydari, Ezat; Hipkin, Victoria; Hoehler, Tori; Hollingsworth, Jeff; Hudgins, Judy; Huntress, Wesley; Hurowitz, Joel; Hviid, Stubbe; Iagnemma, Karl; Indyk, Stephen; Israël, Guy; Jackson, Ryan Steele; Jacob, Samantha; Jakosky, Bruce; Jean-Rigaud, Laurent; Jensen, Elsa; Kløvgaard Jensen, Jaqueline; Johnson, Jeffrey R.; Johnson, Micah; Johnstone, Stephen; Jones, Andrea; Jones, John H.; Joseph, Jonathan; Joulin, Mélissa; Jun, Insoo; Kah, Linda C.; Kahanpää, Henrik; Kahre, Melinda; Kaplan, Hannah; Karpushkina, Natalya; Kashyap, Srishti; Kauhanen, Janne; Keely, Leslie; Kelley, Simon; Kempe, Fabian; Kemppinen, Osku; Kennedy, Megan R.; Keymeulen, Didier; Kharytonov, Alexander; Kim, Myung-Hee; Kinch, Kjartan; King, Penelope; Kirk, Randolph; Kirkland, Laurel; Kloos, Jacob; Kocurek, Gary; Koefoed, Asmus; Köhler, Jan; Kortmann, Onno; Kotrc, Benjamin; Kozyrev, Alexander; Krau, Johannes; Krezoski, ß. Gillian; Kronyak, Rachel; Krysak, Daniel; Kuzmin, Ruslan; Lacour, Jean-Luc; Lafaille, Vivian; Langevin, Yves; Lanza, Nina; Lapôtre, Mathieu; Larif, Marie-France; Lasue, Jérémie; Le Deit, Laetitia; Le Mouélic, Stéphane; Lee, Ella Mae; Lee, Qiu-Mei; Lee, Rebekka; Lees, David; Lefavor, Matthew; Lemmon, Mark; Lepinette, Alain; Lepore, Malvitte Kate; Leshin, Laurie; Léveillé, Richard; Lewin, Éric; Lewis, Kevin; Li, Shuai; Lichtenberg, Kimberly; Lipkaman, Leslie; Lisov, Denis; Little, Cynthia; Litvak, Maxim; Liu, Lu; Lohf, Henning; Lorigny, Eric; Lugmair, Günter; Lundberg, Angela; Lyness, Eric; Madsen, Morten Bo; Magee, Angela; Mahaffy, Paul; Maki, Justin; Mäkinen, Teemu; Malakhov, Alexey; Malespin, Charles; Malin, Michael; Mangold, Nicolas; Manhes, Gerard; Manning, Heidi; Marchand, Geneviève; Marín Jiménez, Mercedes; Martín García, César; Martin, David K.; Martin, Mildred; Martin, Peter; Martínez Martínez, Germán; Martínez-Frías, Jesús; Martín-Sauceda, Jaime; Martín-Soler, Martín Javier; Martín-Torres, F. Javier; Mason, Emily; Matthews, Tristan; Matthiä, Daniel; Mauchien, Patrick; Maurice, Sylvestre; McAdam, Amy; McBride, Marie; McCartney, Elaina; McConnochie, Timothy; McCullough, Emily; McEwan, Ian; McKay, Christopher; McLain, Hannah; McLennan, Scott; McNair, Sean; Melikechi, Noureddine; Mendaza de Cal, Teresa; Merikallio, Sini; Merritt, Sean; Meslin, Pierre-Yves; Meyer, Michael; Mezzacappa, Alissa; Milkovich, Sarah; Millan, Maëva; Miller, Hayden; Miller, Kristen; Milliken, Ralph; Ming, Douglas; Minitti, Michelle; Mischna, Michael; Mitchell, Julie; Mitrofanov, Igor; Moersch, Jeffrey; Mokrousov, Maxim; Molina, Antonio; Moore, Jurado Casey; Moores, John E.; Mora-Sotomayor, Luis; Moreno, Gines; Morookian, John Michael; Morris, Richard V.; Morrison, Shaunna; Mousset, Valérie; Mrigakshi, Alankrita; Mueller-Mellin, Reinhold; Muller, Jan-Peter; Muñoz Caro, Guillermo; Nachon, Marion; Nastan, Abbey; Navarro López, Sara; Navarro González, Rafael; Nealson, Kenneth; Nefian, Ara; Nelson, Tony; Newcombe, Megan; Newman, Claire; Newsom, Horton; Nikiforov, Sergey; Nikitczuk, Matthew; Niles, Paul; Nixon, Brian; Noblet, Audrey; Noe, Eldar; Nolan, Dobrea Thomas; Oehler, Dorothy; Ollila, Ann; Olson, Timothy; Orthen, Tobias; Owen, Tobias; Ozanne, Marie; de Pablo Hernández, Miguel Ángel; Pagel, Hannah; Paillet, Alexis; Pallier, Etienne; Palucis, Marisa; Parker, Timothy; Parot, Yann; Parra, Alex; Patel, Kiran; Paton, Mark; Paulsen, Gale; Pavlov, Alexander; Pavri, Betina; Peinado-González, Verónica; Pepin, Robert; Peret, Laurent; Pérez, René; Perrett, Glynis; Peterson, Joseph; Pilorget, Cedric; Pinet, Patrick; Pinnick, Veronica; Pla-García, Jorge; Plante, Ianik; Poitrasson, Franck; Polkko, Jouni; Popa, Radu; Posiolova, Liliya; Posner, Arik; Pradler, Irina; Prats, Benito; Prokhorov, Vasily; Raaen, Eric; Radziemski, Leon; Rafkin, Scot; Ramos, Miguel; Rampe, Elizabeth; Rapin, William; Raulin, François; Ravine, Michael; Reitz, Günther; Ren, Jun; Rennó, Nilton; Rice, Melissa; Richardson, Mark; Ritter, Birgit; Rivera-Hernández, Frances; Robert, François; Robertson, Kevin; Rodriguez Manfredi, José Antonio; José Romeral-Planelló, Julio; Rowland, Scott; Rubin, David; Saccoccio, Muriel; Said, David; Salamon, Andrew; Sanin, Anton; Sans Fuentes, Sara Alejandra; Saper, Lee; Sarrazin, Philippe; Sautter, Violaine; Savijärvi, Hannu; Schieber, Juergen; Schmidt, Mariek; Schmidt, Walter; Scholes, Daniel; Schoppers, Marcel; Schröder, Susanne; Schwenzer, Susanne P.; Sciascia Borlina, Cauê; Scodary, Anthony; Sebastián Martínez, Eduardo; Sengstacken, Aaron; Shechet, Jennifer Griffes; Shterts, Ruslan; Siebach, Kirsten; Siili, Tero; Simmonds, John J.; Sirven, Jean-Baptiste; Slavney, Susan; Sletten, Ronald; Smith, Michael D.; Sobron Sanchez, Pablo; Spanovich, Nicole; Spray, John; Spring, Justin; Squyres, Steven; Stack, Katie; Stalport, Fabien; Starr, Richard; Stein, Andrew Steele Thomas; Stern, Jennifer; Stewart, Noel; Stewart, Wayne; Stipp, Svane Susan Louise; Stoiber, Kevin; Stolper, Edward; Sucharski, Robert; Sullivan, Robert; Summons, Roger; Sumner, Dawn Y.; Sun, Vivian; Supulver, Kimberley; Sutter, Brad; Szopa, Cyril; Tan, Florence; Tate, Christopher; Teinturier, Samuel; ten Kate, Inge Loes; Thomas, Alicia; Thomas, Peter; Thompson, Lucy; Thuillier, Franck; Thulliez, Emmanual; Tokar, Robert; Toplis, Michael; de la Torre Juárez, Manuel; Torres Redondo, Josefina; Trainer, Melissa; Treiman, Allan; Tretyakov, Vladislav; Ullán-Nieto, Aurora; Urqui-O'Callaghan, Roser; Valentín-Serrano, Patricia; Van Beek, Jason; Van Beek, Tessa; VanBommel, Scott; Vaniman, David; Varenikov, Alexey; Vasavada, Ashwin R.; Vasconcelos, Paulo; de Vicente-Retortillo Rubalcaba, Álvaro; Vicenzi, Edward; Vostrukhin, Andrey; Voytek, Mary; Wadhwa, Meenakshi; Ward, Jennifer; Watkins, Jessica; Webster, Christopher R.; Weigle, Gerald; Wellington, Danika; Westall, Frances; Wiens, Roger; Wilhelm, Mary Beth; Williams, Amy; Williams, Joshua; Williams, Rebecca; Williams, Richard B.; Williford, Kenneth; Wilson, Michael A.; Wilson, Sharon A.; Wimmer-Schweingruber, Robert; Wolff, Michael; Wong, Michael; Wray, James; Yana, Charles; Yen, Albert; Yingst, Aileen; Zeitlin, Cary; Zimdar, Robert; Zorzano Mier, María-Paz

    2015-01-01

    Reports of plumes or patches of methane in the martian atmosphere that vary over monthly time scales have defied explanation to date. From in situ measurements made over a 20-month period by the tunable laser spectrometer of the Sample Analysis at Mars instrument suite on Curiosity at Gale crater, we report detection of background levels of atmospheric methane of mean value 0.69 ± 0.25 parts per billion by volume (ppbv) at the 95% confidence interval (CI). This abundance is lower than model estimates of ultraviolet degradation of accreted interplanetary dust particles or carbonaceous chondrite material. Additionally, in four sequential measurements spanning a 60-sol period (where 1 sol is a martian day), we observed elevated levels of methane of 7.2 ± 2.1 ppbv (95% CI), implying that Mars is episodically producing methane from an additional unknown source.

  2. Methane generation in tropical landfills: simplified methods and field results.

    PubMed

    Machado, Sandro L; Carvalho, Miriam F; Gourc, Jean-Pierre; Vilar, Orencio M; do Nascimento, Julio C F

    2009-01-01

    This paper deals with the use of simplified methods to predict methane generation in tropical landfills. Methane recovery data obtained on site as part of a research program being carried out at the Metropolitan Landfill, Salvador, Brazil, is analyzed and used to obtain field methane generation over time. Laboratory data from MSW samples of different ages are presented and discussed; and simplified procedures to estimate the methane generation potential, Lo, and the constant related to the biodegradation rate, k are applied. The first order decay method is used to fit field and laboratory results. It is demonstrated that despite the assumptions and the simplicity of the adopted laboratory procedures, the values Lo and k obtained are very close to those measured in the field, thus making this kind of analysis very attractive for first approach purposes.

  3. Determination of Methane Sourcex Globally by Sciamachy

    NASA Astrophysics Data System (ADS)

    Park, J. G.; Park, S. Y.

    2016-06-01

    Since the beginning of the industrial revolution, the atmospheric concentration of carbon dioxide (CO2) has increased by nearly 30%, and the Methane (CH4) concentration has more than doubled. CH4 is the second most important greenhouse gas, after CO2. Emissions, extrapolated from measurements of actual gas flux from wetlands, vary from place to place, even within the same wetland. This high variability makes large-scale estimates difficult and means that average emissions levels include a large degree of estimated uncertainty. The SCIAMACHY instrument on the European Space Agency satellite ENVISAT measured greenhouse gases in the troposphere and stratosphere. In this study, the CH4 source area is extracted by estimating the concentrations of methane emissions from time-series satellite data. Contamination of the data by cloud is interpolated both spatially and temporally. It is assumed that methane emission is negligible over ocean and that the concentration in the ocean area is due to advection from land. Background CH4 concentration on land was defined as the ocean CH4 concentration at the same latitude. Land CH4 emission concentrations show that areas of concentrated high CH4 emission are not in paddy fields only but also in broadleaf evergreen areas in South America and Central Africa.

  4. The NIST Atmospheric Methane Gas Standard Scale

    NASA Astrophysics Data System (ADS)

    Rhoderick, G.; Carney, J.; Dlugokencky, E. J.; Kitzis, D.

    2010-12-01

    The National Institute of Standards and Technology (NIST) has entered into a collaboration with the National Oceanic and Atmospheric Administration (NOAA) in Boulder, Colorado on dveloping SI-traceable standards for greenhouse gas monitoring. The Earth System Research Laboratory (ESRL) of NOAA has been designated by the World Meteorological Organization to provide SI-traceable gases to laboratories participating in the WMO climate science community Global Atmosphere Watch program. NOAA has agreed to demonstrate comparability to other National Metrology Institutes under international an existing international agreement (BIPM MRA). NIST and NOAA have begun a series of bilateral comparisons to demonstrate comparability. The Gas Metrology Group at NIST has developed a new suite of atmospheric methane Primary Standard Gas Mixtures (PSMs) that range in amount-of-substance fraction (dry-air mole fraction) from 1700 to 2050 nmol/mol (ppb) with ± 0.03% (0.6 nmol/mol) relative uncertainties (68 % confidence interval). Six levels of standards were made to support NIST programs plus the atmospheric level of 1700-2050 nmol/mol with 30 cylinders total. Each intermediate level was compared to existing NIST PSMs at completion for consistency. The 6th level was also compared to an existing suite of PSMs prepared in 1998. A ratio of the methane in each PSM to a control mixture was calculated by dividing the methane peak area response measured by gas chromatography of a PSM by that of the control. The ratio data and gravimetric mole fractions were plotted to a general least squares program called GenLine (1). The results of this regression are shown in Table 1. The average residual difference between the predicted values and the gravimetric values of the old and new PSMs was 0.08 nmol/mol. NOAA/ESRL has analyzed one of the new PSMs from the NIST atmospheric level suite and has shown good agreement. NOAA has filled 30 cylinders with real air from their Niwot Ridge, Colorado, site and

  5. PACE. A Program for Acquiring Competence in Entrepreneurship. Part II: Becoming an Entrepreneur. Unit G: Resources for Managerial Assistance. Research and Development Series No. 194 B-7.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. National Center for Research in Vocational Education.

    This three-part curriculum for entrepreneurship education is primarily for postsecondary level, including four-year colleges and adult education, but it can be adapted for special groups or vocational teacher education. The emphasis of the seven instructional units in Part II is establishing business. Unit G focuses on obtaining managerial…

  6. PACE. A Program for Acquiring Competence in Entrepreneurship. Part II: Becoming an Entrepreneur. Unit B: Where to Locate the Business. Research and Development Series No. 194 B-2.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. National Center for Research in Vocational Education.

    This three-part curriculum for entrepreneurship education is primarily for postsecondary level, including four-year colleges and adult education, but it can be adapted for special groups or vocational teacher education. The emphasis of the seven instructional units in Part II is on establishing a business. Unit B focuses on choosing a business…

  7. PACE. A Program for Acquiring Competence in Entrepreneurship. Part III: Being an Entrepreneur. Unit D: Marketing Management. Research and Development Series No. 194 C-4.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. National Center for Research in Vocational Education.

    This three-part curriculum for entrepreneurship education is primarily for postsecondary level, including four-year colleges and adult education, but it can be adapted for special groups or vocational teacher education. The emphasis of the eight instructional units in Part III is operating a business. Unit D focuses on market management. It…

  8. PACE. A Program for Acquiring Competence in Entrepreneurship. Part II: Becoming an Entrepreneur. Unit E: Choosing the Type of Ownership. Research and Development Series No. 194 B-5.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. National Center for Research in Vocational Education.

    This three-part curriculum for entrepreneurship education is primarily for postsecondary level, including four-year colleges and adult education, but it can be adapted for special groups or vocational teacher education. The emphasis of the seven instructional units in Part II is establishing a business. Unit E focuses on the three major types of…

  9. Lead optimization of the VU0486321 series of mGlu1 PAMs. Part 1: SAR of modifications to the central aryl core.

    PubMed

    Garcia-Barrantes, Pedro M; Cho, Hyekyung P; Blobaum, Anna L; Niswender, Colleen M; Conn, P Jeffrey; Lindsley, Craig W

    2015-11-15

    This Letter describes the lead optimization of the VU0486321 series of mGlu1 positive allosteric modulators (PAMs). While first generation PAMs from Roche were reported in the late 1990s, little effort has focused on the development of mGlu1 PAMs since. New genetic data linking loss-of-function mutant mGlu1 receptors to schizophrenia, bipolar disorder and other neuropsychiatric disorders has rekindled interest in the target, but the ideal in vivo probe, for example, with good PK, brain penetration and low plasma protein binding, for robust target validation has been lacking. Here we describe the first modifications to the central aryl core of the VU0486321 series, where robust SAR was noted. Moreover, structural variants were identified that imparted selectivity (up to >793-fold) versus mGlu4.

  10. Lead optimization of the VU0486321 series of mGlu1 PAMs. Part 3. Engineering plasma stability by discovery and optimization of isoindolinone analogs.

    PubMed

    Garcia-Barrantes, Pedro M; Cho, Hyekyung P; Blobaum, Anna L; Niswender, Colleen M; Conn, P Jeffrey; Lindsley, Craig W

    2016-04-15

    This Letter describes the further lead optimization of the VU0486321 series of mGlu1 positive allosteric modulators (PAMs), focused on addressing the recurrent issue of plasma instability of the phthalimide moiety. Here, we evaluated a number of phthalimide bioisosteres, and ultimately identified isoindolinones as the ideal replacement that effectively address plasma instability, while maintaining acceptable mGlu1 PAM potency, DMPK profile, CNS penetration and mGluR selectivity.

  11. Biological and biochemical methane reactions

    NASA Astrophysics Data System (ADS)

    Dalton, H.; Pienkos, P. T.; Stirling, D. I.

    1989-04-01

    The purpose of the project was to characterize the nature of the active site involved in methane activation by enzymes from well characterized and newly isolated methane-oxidizing bacteria. Kinetic and structural studies provided an initial picture of how the soluble methane monooxygenase (MMO) enzyme is structured and operates to selectively oxidize methane to methanol under ambient conditions. Cloning and sequencing of gene coding for some of the sMMO proteins were completed, and 72 strains of methanotrophs were isolated from extreme environments.

  12. Methane/nitrogen separation process

    DOEpatents

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Pinnau, Ingo; Segelke, Scott

    1997-01-01

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  13. Methane/nitrogen separation process

    DOEpatents

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  14. On methane pyrolysis special applications

    NASA Astrophysics Data System (ADS)

    Toncu, D. C.; Toncu, G.; Soleimani, S.

    2015-11-01

    Methane pyrolysis represents one of the most important processes in industrial use, with applications rising from the chemical and petrochemical industry, combustion, materials and protective coatings. Despite the intense research, experimental data lack kinetic aspects, and the thermodynamics involved often leads to inaccurate results when applied to various systems. Carrying out a comparative analysis of several available data on methane pyrolysis, the paper aims to study the phenomenon of methane pyrolysis under different environments (combustion and plasma), concluding on the most possible reaction pathways involved in many of its applications. Computer simulation using different database underlines the conclusion, helping to the understanding of methane pyrolysis importance in future technologies.

  15. Redefining the isotopic boundaries of biogenic methane: Methane from endoevaporites

    NASA Astrophysics Data System (ADS)

    Tazaz, Amanda M.; Bebout, Brad M.; Kelley, Cheryl A.; Poole, Jennifer; Chanton, Jeffrey P.

    2013-06-01

    The recent reports of methane in the atmosphere of Mars, as well as the findings of hypersaline paleoenvironments on that planet, have underscored the need to evaluate the importance of biological (as opposed to geological) trace gas production and consumption, particularly in hypersaline environments. Methane in the atmosphere of Mars may be an indication of extant life, but it may also be a consequence of geologic activity and/or the thermal alteration of ancient organic matter. On Earth these methane sources can be distinguished using stable isotopic analyses and the ratio of methane (C1) to C2 and C3 alkanes present in the gas source (C1/(C2 + C3)). We report here that methane produced in hypersaline environments on Earth has an isotopic composition and alkane content outside the values presently considered to indicate a biogenic origin. Methane-rich bubbles released from sub-aqueous substrates contained δ13CCH4 and δ2HCH4 values ranging from -65‰ to -35‰ and -350‰ to -140‰ respectively. Higher salinity endoevaporites yielded what would be considered non-biogenic methane based upon stable isotopic and alkane content, however incubation of crustal and algal mat samples resulted in methane production with similar isotopic values. Radiocarbon analysis indicated that the production of the methane was from recently fixed carbon. An extension of the isotopic boundaries of biogenic methane is necessary in order to avoid the possibility of false negatives returned from measurements of methane on Mars and other planetary bodies.

  16. Methane in groundwater used for Japanese agriculture: Its relationship to other physico-chemical properties and possible tropospheric source stength

    SciTech Connect

    Watanabe, A.; Kimura, M. ); Kasuya, M.; Kotake, M.; Katoh, T. )

    1994-01-01

    This paper presents results of measurements of dissolved methane found in ground water samples from Aichi Prefecture, Japan, taken from wells which were used for agricultural irrigation. It is a part of the overall program to account of methane sources and sinks in the environment. Detectable methane concentrations were found in more than half of the 131 samples taken. Based on the detected methane concentrations, and the estimated ground water usage, this source represents only 1.4% of the methane production from paddy fields in this geographic region.

  17. Consumption of atmospheric methane by tundra soils

    NASA Technical Reports Server (NTRS)

    Whalen, S. C.; Reeburgh, W. S.

    1990-01-01

    The results of field and laboratory experiments on methane consumption by tundra soils are reported. For methane concentrations ranging from below to well above ambient, moist soils are found to consume methane rapidly; in nonwaterlogged soils, equilibration with atmospheric methane is fast relative to microbial oxidation. It is concluded that lowering of the water table in tundra as a resulting from a warmer, drier climate will decrease methane fluxes and could cause these areas to provide negative feedback for atmospheric methane.

  18. What Controls Methane in Potable Ground Water in the Appalachian Basin?

    NASA Astrophysics Data System (ADS)

    Siegel, D. I.; Smith, B.; Perry, A. E.; Bothun, R.

    2014-12-01

    We present the results of baseline (pre-drilling) sampling for methane in 13,040 potable ground water samples in Northeastern Pennsylvania and 8,004 samples from a "Western Area" (southwest Pennsylvania, eastern Ohio, and north-central West Virginia) that were collected on behalf of Chesapeake Energy Corporation as part of its monitoring program prior to drilling unconventional oil and gas wells in the Marcellus and Utica Formations, as well as the results of a year-long study on temporal variability of methane in ground water at 12 locations in NE Pennsylvania We found dissolved methane common in potable ground water in the Appalachian Basin. In NE Pennsylvania, measureable dissolved methane occurred in 24% of our samples with 3.4% naturally exceeding the PADEP methane notification level of 7 mg/L. In the western area, dissolved methane occurred naturally in 36% of groundwater sampled and in Ohio, 4.1% of samples exceeded the Ohio dissolved methane action level of 10 mg/L. More methane is associated with hydrogeochemical facies trending towards Na-Cl and Na-HCO3 type waters in valleys and along hill flanks. We found no relationship occurs between the concentration of methane and proximity to pre-existing gas wells. Concentrations of methane in domestic wells can naturally vary by factors, depending on pumping regime and time of year.

  19. Methane production, emission and possible control measures in the rice agriculture

    NASA Astrophysics Data System (ADS)

    Wang, Mingxing; Shangguan, Xingjian; Shen, Renxing; Reiner, Wassmann; Wolfgang, Seiler

    1993-09-01

    In the rice field methane is produced in the soil layer with depths of 2 25 cm. The vertical profile of methane production rate in the paddy soil during the water covering period differs from that in the paddy soil in dry phase. Only a small part, about 30%, of the produced methane is emitted to the atmosphere through rice plant, air bubbles, and molecular diffusion. Therefore, the methane emission rate from the rice field depends not only on the methane production rate in the soil, but also on the transport efficiency of the rice plant, air bubble formation that in turn depends on the production rate, and molecular diffusion. Field measurements show that methane emission rates from a particular rice field have very large diurnal, seasonal and interannual variations, which are related to soil characteristics, water regime, farming procedure, local climate, and rice growing activities. The relationship between the methane emission rate and the above mentioned factors is very complicated. The emission rates from different rice fields differ greatly not only in the absolute value, but also in the temporal variation patterns. Methane emission rate from the rice field may be significantly reduced by scientific management of fertilizer and irrigation. While the use of SO{4/2-} containing fertilizer and fermented organic fertilizer may reduce the methane emission significantly, the most promising measure for reducing methane emission from rice field is the frequent drainage irrigation procedure.

  20. 30 CFR 77.101 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Tests for methane and for oxygen deficiency... oxygen deficiency; qualified person. (a) The provisions of Subparts C, P, R, and T of this Part 77 require that tests for methane and for oxygen deficiency be made by a qualified person. A person is...

  1. 30 CFR 77.101 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Tests for methane and for oxygen deficiency... oxygen deficiency; qualified person. (a) The provisions of Subparts C, P, R, and T of this Part 77 require that tests for methane and for oxygen deficiency be made by a qualified person. A person is...

  2. 30 CFR 77.101 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Tests for methane and for oxygen deficiency... oxygen deficiency; qualified person. (a) The provisions of Subparts C, P, R, and T of this Part 77 require that tests for methane and for oxygen deficiency be made by a qualified person. A person is...

  3. 30 CFR 77.101 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Tests for methane and for oxygen deficiency... oxygen deficiency; qualified person. (a) The provisions of Subparts C, P, R, and T of this Part 77 require that tests for methane and for oxygen deficiency be made by a qualified person. A person is...

  4. 30 CFR 77.101 - Tests for methane and for oxygen deficiency; qualified person.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Tests for methane and for oxygen deficiency... oxygen deficiency; qualified person. (a) The provisions of Subparts C, P, R, and T of this Part 77 require that tests for methane and for oxygen deficiency be made by a qualified person. A person is...

  5. Erbeta Ligands. Part 5: Synthesis and Structure-Activity Relationships of a Series of 4'-hydroxyphenyl-aryl-carbaldehyde Oxime Derivatives

    SciTech Connect

    Mewshaw,R.; Bowen, S.; Harris, H.; Xu, Z.; Manas, E.; Cohn, S.

    2007-01-01

    A series of 4'-hydroxyphenyl-aryl-carbaldehyde oximes (5b) was prepared and found to have high affinity (4 nM) and modest selectivity (39-fold) for estrogen receptor-{beta} (ER{beta}). Substitution of one of the core rings of the scaffold based around these novel ligands further expanded our knowledge in the quest toward achieving high affinity and selectivity for ER{beta}. An X-ray co-crystal of structure 11 revealed that the oxime moiety was mimicking the C-ring of genistein, as previously predicted by SAR and docking studies.

  6. Stimulation of commercial coal seam methane production aimed at improving mining technology

    NASA Astrophysics Data System (ADS)

    Shubina, E. A.; Lukyanov, V. G.

    2016-09-01

    The relevance of the current research is due to the urgent need to revise the existing normative bases and procedures involved in intensive development of coal-methane deposits and commercial production of coal seam methane. The article presents the analysis of data on coal production volume and amount of methane emitted into the atmosphere in Kuzbass. There is a need to develop the exploration techniques that would allow implementing pre-mining gas drainage of coal seams and provide the companies with the guidance on coal seam methane drainage in very gassy coal mines. Commercial production of methane should become an integral part of economy and energy balance of the Russian Federation, which, in its turn, would enhance environmental protection due to reducing methane emissions, the largest source of greenhouse effect.

  7. Effects of Monovalent Anions of the Hofmeister Series on DPPC Lipid Bilayers Part I: Swelling and In-Plane Equations of State

    PubMed Central

    Aroti, A.; Leontidis, E.; Dubois, M.; Zemb, T.

    2007-01-01

    Aiming to improve understanding of the mechanisms behind specific anion effects in biological systems we have studied the effects of sodium salts of simple monovalent anions belonging to the Hofmeister series on the bilayers of the zwitterionic lipid 1,2-dipalmitoyl-sn-glycero-3-phosphocholine using small-angle x-ray scattering and the osmotic stress technique. NaCl, NaBr, NaNO3, NaI, and NaSCN were used in this investigation. The electrolytes were found to swell the bilayers and to increase the area per lipid headgroup at each value of the osmotic pressure, suggesting the association of anions with the bilayer-lipid interfaces. The effects follow the Hofmeister series with SCN− inducing the most pronounced changes. “Ion competition” experiments with mixed NaI/NaCl solutions at total salinity 0.1 and 0.5 M revealed that the effect of ions on the lipid equation-of-state is roughly linear at low concentrations, but strongly nonlinear at high concentrations. The experimental results are fitted in a companion article to provide “binding” or “partitioning” constants of anions in the lipid bilayers. PMID:17496051

  8. Forecasting peak daily ozone levels: part 2--A regression with time series errors model having a principal component trigger to forecast 1999 and 2002 ozone levels.

    PubMed

    Liu, Pao-Wen Grace; Johnson, Richard

    2003-12-01

    A modified time series approach, a Box-Jenkins regression with time series errors (RTSE) model plus a principal component (PC) trigger, has been developed to forecast peak daily 1-hr ozone (O3) in real time at the University of Wisconsin-Milwaukee North (UWM-N) during 1999 and 2002. The PC trigger acts as a predictor variable in the RTSE model. It tries to answer the question: will the next day be a possible high O3 day? To answer this question, three PC trigger rules were developed: (1) Hi-Low Checklist, (2) Discriminant Function Approach I, and (3) Discriminant Function Approach II. Also, a pure RTSE model without including the PC trigger and a persistence approach were tested for comparison. The RTSE model with DFA I successfully forecast the only two 1-hr federal exceedances (124 ppb), one in 1999 and one in 2002. In terms of the O3 100-ppb exceedances, 60-80% of the incorrect forecasts occurred with incorrect PC decisions. A few others may have been caused by unexpected O3-weather relations. When the three approaches used UWM-N data to forecast a 100-ppb exceedance somewhere in the Milwaukee, WI, metropolitan area, their performance was dramatically improved: the false alarm rate was reduced from 0.89 to 0.44, and the probability of detection was increased from 0.71 to 0.88.

  9. Diverse origins of Arctic and Subarctic methane point source emissions identified with multiply-substituted isotopologues

    NASA Astrophysics Data System (ADS)

    Douglas, P. M. J.; Stolper, D. A.; Smith, D. A.; Walter Anthony, K. M.; Paull, C. K.; Dallimore, S.; Wik, M.; Crill, P. M.; Winterdahl, M.; Eiler, J. M.; Sessions, A. L.

    2016-09-01

    Methane is a potent greenhouse gas, and there are concerns that its natural emissions from the Arctic could act as a substantial positive feedback to anthropogenic global warming. Determining the sources of methane emissions and the biogeochemical processes controlling them is important for understanding present and future Arctic contributions to atmospheric methane budgets. Here we apply measurements of multiply-substituted isotopologues, or clumped isotopes, of methane as a new tool to identify the origins of ebullitive fluxes in Alaska, Sweden and the Arctic Ocean. When methane forms in isotopic equilibrium, clumped isotope measurements indicate the formation temperature. In some microbial methane, however, non-equilibrium isotope effects, probably related to the kinetics of methanogenesis, lead to low clumped isotope values. We identify four categories of emissions in the studied samples: thermogenic methane, deep subsurface or marine microbial methane formed in isotopic equilibrium, freshwater microbial methane with non-equilibrium clumped isotope values, and mixtures of deep and shallow methane (i.e., combinations of the first three end members). Mixing between deep and shallow methane sources produces a non-linear variation in clumped isotope values with mixing proportion that provides new constraints for the formation environment of the mixing end-members. Analyses of microbial methane emitted from lakes, as well as a methanol-consuming methanogen pure culture, support the hypothesis that non-equilibrium clumped isotope values are controlled, in part, by kinetic isotope effects induced during enzymatic reactions involved in methanogenesis. Our results indicate that these kinetic isotope effects vary widely in microbial methane produced in Arctic lake sediments, with non-equilibrium Δ18 values spanning a range of more than 5‰.

  10. Seasonal and inter-annual variation in ecosystem scale methane emission from a boreal fen

    NASA Astrophysics Data System (ADS)

    Rinne, Janne; Li, Xuefei; Raivonen, Maarit; Peltola, Olli; Sallantaus, Tapani; Haapanala, Sami; Smolander, Sampo; Alekseychik, Pavel; Aurela, Mika; Korrensalo, Aino; Mammarella, Ivan; Tuittila, Eeva-Stiina; Vesala, Timo

    2016-04-01

    Northern wetlands are one of the major sources of atmospheric methane. We have measured ecosystem scale methane emissions from a boreal fen continuously since 2005. The site is an oligotrophic fen in boreal vegetation zone situated in Siikaneva wetland complex in Southern Finland. The mean annual temperature in the area is 3.3°C and total annual precipitation 710 mm. We have conducted the methane emission measurements by the eddy covariance method. Additionally we have measured fluxes of carbon dioxide, water vapor, and sensible heat together with a suite of other environmental parameters. We have analyzed this data alongside with a model run with University of Helsinki methane model. The measured fluxes show generally highest methane emission in late summers coinciding with the highest temperatures in saturated peat zone. During winters the fluxes show small but detectable emission despite the snow and ice cover on the fen. More than 90% of the annual methane emission occurs in snow-free period. The methane emission and peat temperature are connected in exponential manner in seasonal scales, but methane emission does not show the expected behavior with water table. The lack of water table position dependence also contrasts with the spatial variation across microtopography. There is no systematic variation in sub-diurnal time scale. The general seasonal cycle in methane emission is captured well with the methane model. We will show how well the model reproduces the temperature and water table position dependencies observed. The annual methane emission is typically around 10 gC m-2. This is a significant part of the total carbon exchange between the fen and the atmosphere and about twice the estimated carbon loss by leaching from the fen area. The inter-annual variability in the methane emission is modest. The June-September methane emissions from different years, comprising most of the annual emission, correlates positively with peat temperature, but not with

  11. Methane in the Baltic and North Seas and a reassessment of the marine emissions of methane

    SciTech Connect

    Bange, H.W.; Bartell, U.H.; Rapsomanikis, S.

    1994-12-01

    During three measurement campaigns on the Baltic and North Seas, atmospheric and dissolved methane was determined with an automated gas chromatographic system. Area-weighted mean saturation values in the sea surface waters were 113{+-}5% and 395{+-}82% and 126{+-}8%. On the bases of our data and a compilation of literature data the global oceanic emissions of methane were reassessed by introducing a concept of regional gas transfer coefficients. Our estimates computed with two different air-sea exchange models lie in the range of 11-18 Tg CH{sub 4} yr{sup -1}. Despite the fact that shelf areas and estuaries only represent a small part of the world`s ocean they contribute about 75% to the global oceanic emissions. We applied a simple, coupled, three-layer model to evaluate the time dependent variation of the oceanic flux to the atmosphere. The model calculations indicate that even with increasing tropospheric methane concentration, the ocean will remain a source of atmospheric methane. 72 refs., 7 figs., 7 tabs.

  12. A Methane Balloon Inflation Chamber

    ERIC Educational Resources Information Center

    Czerwinski, Curtis J.; Cordes, Tanya J.; Franek, Joe

    2005-01-01

    The various equipments, procedure and hazards in constructing the device for inflating a methane balloon using a standard methane outlet in a laboratory are described. This device is fast, safe, inexpensive, and easy to use as compared to a hydrogen gas cylinder for inflating balloons.

  13. Methane dynamics regulated by microbial community response to permafrost thaw.

    PubMed

    McCalley, Carmody K; Woodcroft, Ben J; Hodgkins, Suzanne B; Wehr, Richard A; Kim, Eun-Hae; Mondav, Rhiannon; Crill, Patrick M; Chanton, Jeffrey P; Rich, Virginia I; Tyson, Gene W; Saleska, Scott R

    2014-10-23

    Permafrost contains about 50% of the global soil carbon. It is thought that the thawing of permafrost can lead to a loss of soil carbon in the form of methane and carbon dioxide emissions. The magnitude of the resulting positive climate feedback of such greenhouse gas emissions is still unknown and may to a large extent depend on the poorly understood role of microbial community composition in regulating the metabolic processes that drive such ecosystem-scale greenhouse gas fluxes. Here we show that changes in vegetation and increasing methane emissions with permafrost thaw are associated with a switch from hydrogenotrophic to partly acetoclastic methanogenesis, resulting in a large shift in the δ(13)C signature (10-15‰) of emitted methane. We used a natural landscape gradient of permafrost thaw in northern Sweden as a model to investigate the role of microbial communities in regulating methane cycling, and to test whether a knowledge of community dynamics could improve predictions of carbon emissions under loss of permafrost. Abundance of the methanogen Candidatus 'Methanoflorens stordalenmirensis' is a key predictor of the shifts in methane isotopes, which in turn predicts the proportions of carbon emitted as methane and as carbon dioxide, an important factor for simulating the climate feedback associated with permafrost thaw in global models. By showing that the abundance of key microbial lineages can be used to predict atmospherically relevant patterns in methane isotopes and the proportion of carbon metabolized to methane during permafrost thaw, we establish a basis for scaling changing microbial communities to ecosystem isotope dynamics. Our findings indicate that microbial ecology may be important in ecosystem-scale responses to global change.

  14. Renewed methane increase (2007-2014): contribution of oil and natural gas emissions determined from methane and ethane column observations

    NASA Astrophysics Data System (ADS)

    Hausmann, Petra; Sussmann, Ralf; Smale, Dan

    2016-04-01

    Harmonized time series of column-averaged mole fractions of atmospheric methane and ethane over the period 1999-2014 are derived from solar Fourier transform infrared (FTIR) measurements at the Zugspitze summit (47° N, 2964 m a.s.l.) and at Lauder (45° S, 370 m a.s.l.). Long-term trend analysis reveals a consistent renewed methane increase since 2007 of 6.2 [5.6, 6.9] ppb yr-1 at the Zugspitze and 6.0 [5.3, 6.7] ppb yr-1 at Lauder (95 % confidence intervals). Several recent studies provide pieces of evidence that the renewed methane increase is most likely driven by two main factors: (i) increased methane emissions from tropical wetlands, followed by (ii) increased thermogenic methane emissions due to growing oil and natural gas production. Here, we quantify the magnitude of the second class of sources, using long-term measurements of atmospheric ethane as tracer for thermogenic methane emissions. In 2007, after years of weak decline, the Zugspitze ethane time series shows the sudden onset of a significant positive trend (2.3 [1.8, 2.8] × 10-2 ppb yr-1 for 2007-2014), while a negative trend persists at Lauder after 2007 (-0.4 [-0.6, -0.1] × 10-2 ppb yr-1). Zugspitze methane and ethane time series are significantly correlated for the period 2007-2014 and can be assigned to thermogenic methane emissions with an ethane-to-methane ratio of 10-21 %. We present optimized emission scenarios for 2007-2014 derived from an atmospheric two-box model. From our trend observations we infer a total ethane emission increase over the period 2007-2014 from oil and natural gas sources of 1-11 Tg yr-1 along with an overall methane emission increase of 24-45 Tg yr-1. Based on these results, the oil and natural gas emission contribution C to the renewed methane increase is deduced using three different emission scenarios with dedicated ranges of methane-to-ethane ratios (MER). Reference scenario 1 assumes an oil and gas emission combination with MER = 3.3-7.6, which results in a

  15. Impact of changes in barometric pressure on landfill methane emission

    NASA Astrophysics Data System (ADS)

    Xu, Liukang; Lin, Xiaomao; Amen, Jim; Welding, Karla; McDermitt, Dayle

    2014-07-01

    Landfill methane emissions were measured continuously using the eddy covariance method from June to December 2010. The study site was located at the Bluff Road Landfill in Lincoln, Nebraska, USA. Our results show that landfill methane emissions strongly depended on changes in barometric pressure; rising barometric pressure suppressed the emission, while falling barometric pressure enhanced the emission, a phenomenon called barometric pumping. There was up to a 35-fold variation in day-to-day methane emissions due to changes in barometric pressure. Wavelet coherence analysis revealed a strong spectral coherency between variations of barometric pressure and methane emission at periodicities ranging from 1 day to 8 days. Power spectrum and ogive analysis showed that at least 10 days of continuous measurements was needed in order to capture 90% of the total variance in the methane emission time series at our landfill site. From our results, it is clear that point-in-time measurements taken at monthly or longer time intervals using techniques such as the trace plume method, the mass balance method, or the closed-chamber method will be subject to large variations in measured emission rates because of the barometric pumping phenomenon. Estimates of long-term integrated methane emissions from landfills based on such measurements could yield uncertainties, ranging from 28.8% underestimation to 32.3% overestimation. Our results demonstrate a need for continuous measurements to quantify annual total landfill emissions. This conclusion may apply to the study of methane emissions from wetlands, peatlands, lakes, and other environmental contexts where emissions are from porous media or ebullition. Other implications from the present study for hazard gas monitoring programs are also discussed.

  16. Attributes and National Behavior, Part 2: Modern International Relations Monograph Series. Patterns of Conflict: Relative Status-Field Theory, TT Actors.

    ERIC Educational Resources Information Center

    Vincent, Jack E.

    This monograph presents the computer printout of an analysis of data on international conflict over a three-year period. Part of a large scale research project to test various theories with regard to their power in analyzing international relations, this monograph presents data on the application of discriminant function analysis to 'topdog'…

  17. Attributes and National Behavior, Part 2: Modern International Relations Monograph Series. Patterns of Cooperation: Relative Status-Field Theory, TU Actors.

    ERIC Educational Resources Information Center

    Vincent, Jack E.

    This monograph presents the computer printout of an analysis of data on international cooperation over a three-year period. Part of a large scale research project to test various theories with regard to their power in analyzing international relations, this monograph presents data on the application of discriminant function analysis to combined…

  18. Attributes and National Behavior, Part 2: Modern International Relations Monograph Series. Patterns of Conflict: Relative Status-Field Theory, TU Actors.

    ERIC Educational Resources Information Center

    Vincent, Jack E.

    This monograph presents the computer printout of an analysis of data on international conflict over a three-year period. Part of a large scale research project to test various theories with regard to their power in analyzing international relations, this monograph presents data on the application of discriminant function analysis to combined…

  19. Environmental Controls on Aerobic Methane Oxidation in Coastal Waters

    NASA Astrophysics Data System (ADS)

    Steinle, L.; Maltby, J.; Engbersen, N.; Zopfi, J.; Bange, H. W.; Elvert, M.; Hinrichs, K. U.; Kock, A.; Lehmann, M. F.; Treude, T.; Niemann, H.

    2015-12-01

    Large quantities of the greenhouse gas CH4 are produced in anoxic sediments of continental margins and may be liberated to the overlying water column, and later into the atmosphere. Indeed, coastal seas account for more than 75% of global oceanic CH4 emissions. Yet, aerobic CH4 oxidizing bacteria (MOB) consume an important part of CH4 in the water column, thus mitigating CH4 release to the atmosphere. Coastal oceans are highly dynamic systems, in particular with regard to the variability of temperature, salinity and oxygen concentrations, all of which are potential key environmental factors controlling MOx. To determine the most important controlling factors, we conducted a two-year time-series study with measurements of CH4, MOx, the composition of the MOB community, and physicochemical water column parameters in a coastal inlet in the Baltic Sea (Eckernförde(E-) Bay, Boknis Eck Time Series Station). In addition, we investigated the influence of temperature and oxygen on MOx during controlled laboratory experiments. In E-Bay, seasonal stratification leads to hypoxia in bottom waters towards the end of the stratification period. Methane is produced year-round in the sediments, resulting in accumulation of methane in bottom waters, and supersaturation (with respect to the atmospheric equilibrium) in surface waters. Here, we will discuss the factors impacting MOx the most, which were a) perturbations of the water column caused by storm events, currents or seasonal mixing, b) temperature and c) oxygen concentration. a) Perturbations of the water column led to a sharp decrease in MOx within hours, probably caused by replacement of 'old' water with a high standing stock of MOB by 'new' waters with a lower abundance of MOB. b) An increase in temperature generally led to higher MOx rates. c) Even though CH4 was abundant at all depths, MOx was highest in bottom waters (1-5 nM/d), which usually contain the lowest O2 concentrations. Lab-based experiments with adjusted O2

  20. Methane Emissions from Upland Trees

    NASA Astrophysics Data System (ADS)

    Pitz, S.; Megonigal, P.; Schile, L. M.; Szlavecz, K. A.; King, K.

    2013-12-01

    Most work on methane (CH4) emissions from natural ecosystems has focused on wetlands and wetland soils because they are predictable emitters and relatively simple to quantify. Less attention has been directed toward upland ecosystems that cover far larger areas, but are assumed to be too dry to emit CH4. There is abundant evidence that upland ecosystems emit small amounts of CH4 during hot moments that collectively constitute a significant source in the global budget of this potent greenhouse gas. We have established two transects across natural moisture gradients in two forests near Annapolis, Maryland. Both tree and soil methane fluxes were measured using chamber methods. Each tree chamber was custom fit to the stem near the base. In addition, porewater methane concentrations were collected at multiple depths near trees. Abiotic parameters such as soil temperature, soil moisture, water potential, and depth to groundwater were monitored using a wireless sensor network. Upland emissions from tree stems were as high as 14.6 umoles CH4 m-2 hr-1 while the soil uptake was -1.5 umoles CH4 m-2 hr-1. These results demonstrate that tree methane emissions and soil methane uptake can occur simultaneously in a mesic forest. Factors controlling methane emissions were soil temperature, soil moisture, and depth to groundwater. Based on our preliminary data, tree mediated methane emissions may be offsetting the soil methane sink of upland forests by 20 to 30%. Future methane budgets and climate models will need to include tree fluxes and the parameters that control methane emissions for accurate accounting and predictions.

  1. Carbon fibre composite for ventilation air methane (VAM) capture.

    PubMed

    Thiruvenkatachari, Ramesh; Su, Shi; Yu, Xin Xiang

    2009-12-30

    Coal mine methane (CMM) is not only a hazardous greenhouse gas but is also a wasted energy resource, if not utilised. This paper evaluates a novel adsorbent material developed for capturing methane from ventilation air methane (VAM) gas in underground coal mines. The adsorbent material is a honeycomb monolithic carbon fibre composite (HMCFC) consisting of multiple parallel flow-through channels and the material exhibits unique features including low pressure drop, good mechanical properties, ability to handle dust-containing gas streams, good thermal and electrical conductivity and selective adsorption of gases. During this study, a series of HMCFC adsorbents (using different types of carbon fibres) were successfully fabricated. Experimental data demonstrated the proof-of-concept of using the HMCFC adsorbent to capture methane from VAM gas. The adsorption capacity of the HMCFC adsorbent was twice that of commercial activated carbon. Methane concentration of 0.56% in the inlet VAM gas stream is reduced to about 0.011% after it passes through the novel carbon fibre composite adsorbent material at ambient temperature and atmospheric pressure. This amounts to a maximum capture efficiency of 98%. These encouraging laboratory scale studies have prompted further large scale trials and economic assessment.

  2. Wind-Tunnel Tests on a Series of Wing Models Through a Large Angle of Attack Range. Part I : Force Tests

    NASA Technical Reports Server (NTRS)

    Knight, Montgomery; Wenzinger, Carl J

    1930-01-01

    This investigation covers force tests through a large range of angle of attack on a series of monoplane and biplane wing models. The tests were conducted in the atmospheric wind tunnel of the National Advisory Committee for Aeronautics. The models were arranged in such a manner as to make possible a determination of the effects of variations in tip shape, aspect ratio, flap setting, stagger, gap, decalage, sweep back, and airfoil profile. The arrangements represented most of the types of wing systems in use on modern airplanes. The effect of each variable is illustrated by means of groups of curves. In addition, there are included approximate autorotational characteristics in the form of calculated ranges of "rotary instability." a correction for blocking in this tunnel which applies to monoplanes at large angles of attack has been developed, and is given in an appendix. (author)

  3. Urban - Wetland contrast in turbulent exchange of methane

    NASA Astrophysics Data System (ADS)

    Pawlak, Włodzimierz; Fortuniak, Krzysztof; Siedlecki, Mariusz; Zieliński, Mariusz

    2016-11-01

    Continuous eddy-covariance measurements of turbulent methane exchange between the ground and the atmosphere were carried out during the period from July 2013 to September 2015. The measurement sites were located in areas characterized by different types of use: the city (Łódź, central Poland) and the wetlands of Biebrza National Park (northeastern Poland). Regardless of the type of surface, such long-term, continuous measurements of the turbulent fluxes of methane are rare. Our aim was to investigate the temporal variability of the turbulent methane exchange in the surface-atmosphere system, while considering the impact of land use. Because cities are a huge source of atmospheric carbon dioxide, we compared the intensity of methane emissions from the city as compared to the wetland, which is considered to be the most intense natural source atmospheric methane. In both cases, the results show a clear prevalence of positive as compared with negative fluxes. This shows that both areas are net sources of methane to the troposphere. The measurements also demonstrated the existence of a clear annual cycle of turbulent methane flux in the centre of the city (average values in winter ranged from ∼40 to 60 nmol m-2·s-1 and were significantly greater than values measured in summer) as well as in the wetlands, where maximum values were observed during the warm part of the year (approximately 80 nmol m-2·s-1 or more). The different times of maximum CH4 flux (FCH4) occurrence resulted from the differentiation of processes that determine methane emissions: in the city these are anthropogenic emissions (strongest in winter); in the wetland, natural processes dominate. The diurnal variability of FCH4 was faintly detectable, except for the cold half of the year in the city and the warm half of the year in the wetland. The studied area of the centre of Łódź, in turn, is also characterized by a weekly cycle of methane exchange: the values measured on working days were

  4. Making methane visible

    NASA Astrophysics Data System (ADS)

    Gålfalk, Magnus; Olofsson, Göran; Crill, Patrick; Bastviken, David

    2016-04-01

    Methane (CH4) is one of the most important greenhouse gases, and an important energy carrier in biogas and natural gas. Its large scale emission patterns have been unpredictable and the source and sink distributions are poorly constrained. Remote assessment of CH4 with high sensitivity at m2 spatial resolution would allow detailed mapping of near ground distribution and anthropogenic sources and sinks in landscapes but has hitherto not been possible. Here we show that CH4 gradients can be imaged on methane imaging will include a lake, barn, sewage sludge deposit, waste incineration plant, and controlled gas releases. We will also present successful simultaneous imaging of another important greenhouse gas, nitrous oxide, with the same instrument.

  5. Hydroxylation of methane through component interactions in soluble methane monooxygenases.

    PubMed

    Lee, Seung Jae

    2016-04-01

    Methane hydroxylation through methane monooxygenases (MMOs) is a key aspect due to their control of the carbon cycle in the ecology system and recent applications of methane gas in the field of bioenergy and bioremediation. Methanotropic bacteria perform a specific microbial conversion from methane, one of the most stable carbon compounds, to methanol through elaborate mechanisms. MMOs express particulate methane monooxygenase (pMMO) in most strains and soluble methane monooxygenase (sMMO) under copper-limited conditions. The mechanisms of MMO have been widely studied from sMMO belonging to the bacterial multicomponent monooxygenase (BMM) superfamily. This enzyme has diiron active sites where different types of hydrocarbons are oxidized through orchestrated hydroxylase, regulatory and reductase components for precise control of hydrocarbons, oxygen, protons, and electrons. Recent advances in biophysical studies, including structural and enzymatic achievements for sMMO, have explained component interactions, substrate pathways, and intermediates of sMMO. In this account, oxidation of methane in sMMO is discussed with recent progress that is critical for understanding the microbial applications of C-H activation in one-carbon substrates.

  6. [Biogeochemical cycle of methane in the northwestern shelf of the Black Sea].

    PubMed

    Rusanov, I I; Levi, A Iu; Pimenov, N V; Iusupov, S K; Ivanov, M V

    2002-01-01

    Seasonal investigations of methane distribution and rates of its oxidation and generation in the water column and sediments of the Black Sea northwestern shelf were carried out within the framework of the interdisciplinary projects "European River-Ocean Systems" (EROS-2000, EROS-21) and "Biogenic Gases Exchange in the Black Sea" (BigBlack) in August 1995, May 1997, and December 1999. Experiments that involved the addition of 14CH3COONa and 14CO2 to sediment samples showed the main part of methane to be formed from CO2. Maximum values of methane production (up to 559 mumol/(m2 day)) were found in coastal sediments in summer time. In winter and spring, methane production in the same sediments did not exceed 3.6-4.2 mumol/(m2 day). The delta 13C values of methane ranged from -70.7 to -81.8@1000, demonstrating its microbial origin and contradicting the concept of the migration of methane from cold seeps or from the oil fields located at the Black Sea shelf. Experiments that involved the addition of 14CH4 to water and sediment samples showed that a considerable part of methane is oxidized in the upper horizons of bottom sediments and in the water column. Nevertheless, it was found that, in summer, part of methane (from 6.8 to 320 mumol/(m2 day)) arrives in the atmosphere.

  7. IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 2. Light Lanthanides (Ce–Eu)

    SciTech Connect

    Mioduski, Tomasz; Gumiński, Cezary; Zeng, Dewen

    2015-03-15

    This is the second part of the volume devoted to the evaluation of experimental solubility data for rare earth metal (REM) fluorides in water as well as in aqueous ternary and multicomponent systems. Fluorides of Ce, Pr, Nd, Pm, Sm, and Eu (so-called light lanthanides), as the main solutes, are covered in the present part, which has thorough coverage of the experimental literature through the end of 2012. The experimentally unknown solubility value for PmF{sub 3} in water was predicted by an interpolation of the solubility values for NdF{sub 3} and SmF{sub 3} at 298 K. General features of the systems, such as the nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, pH, mixed solvent medium on the solubility, quality of the solubility results, and solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.

  8. Exponential model describing methane production kinetics in batch anaerobic digestion: a tool for evaluation of biochemical methane potential assays.

    PubMed

    Brulé, Mathieu; Oechsner, Hans; Jungbluth, Thomas

    2014-09-01

    Biochemical methane potential assays, usually run in batch mode, are performed by numerous laboratories to characterize the anaerobic degradability of biogas substrates such as energy crops, agricultural residues, and organic wastes. Unfortunately, the data obtained from these assays lacks common, universal bases for comparison, because standard protocols did not diffuse to the entire scientific community. Results are usually provided as final values of the methane yields of substrates. However, methane production curves generated in these assays also provide useful information about substrate degradation kinetics, which is rarely exploited. A basic understanding of the kinetics of the biogas process may be a first step towards a convergence of the assay methodologies on an international level. Following this assumption, a modeling toolbox containing an exponential model adjusted with a simple data-fitting method has been developed. This model should allow (a) quality control of the assays according to the goodness of fit of the model onto data series generated from the digestion of standard substrates, (b) interpretation of substrate degradation kinetics, and (c) estimate of the ultimate methane yield at infinite time. The exponential model is based on two assumptions: (a) the biogas process is a two-step reaction yielding VFA as intermediate products, and methane as the final product, and (b) the digestible substrate can be divided into a rapidly degradable and a slowly degradable fraction.

  9. Using Methane 14C to Determine the Origin of the Rapid Methane Rise at the End of the Younger Dryas 11,600 Years Ago: Increased Wetland Production or Methane Hydrates? A Progress Report.

    NASA Astrophysics Data System (ADS)

    Petrenko, V. V.; Severinghaus, J.; Brook, E.; Reeh, N.

    2002-12-01

    The atmospheric methane concentration rose from about 500 parts per billion (ppb) to about 750 ppb over a period of just 150 years at the termination of the Younger Dryas cold period 11,600 years ago, as indicated by Greenland ice core records. The start of this rapid methane increase was synchronous with an even more rapid climate warming -- Greenland ice core nitrogen and argon isotope records indicate that temperatures rose 5 - 10 ?C over just a few decades. There has been considerable debate about the source of this methane rise. Currently, the two main hypotheses attribute the methane rise either to increased bacterial methane production in wetlands, or to the dissociation of large quantities of methane hydrates on the ocean floor. Here we describe the progress of a project whose aim is to determine the origin of this methane rise. Our approach involves using 14C of ancient methane (derived from air bubbles in glacial ice) to determine its source. Methane hydrates are hundreds of thousands to millions of years old, and should contain virtually no 14C, whereas wetland-derived methane will have 14C content identical to that of atmospheric CO2 at the time of production. Obtaining enough ancient methane for a 14C measurement requires very large samples -- about 2 cubic meters. We have been able to locate a site on the western margin of the Greenland ice sheet where large amounts of uncontaminated ancient ice are available at the surface. Furthermore, our measurements of oxygen isotopes in the ice, as well as measurements of methane and oxygen and nitrogen isotopes in the air trapped in this ice have allowed us to date the ice and precisely locate the ice that contains the end-of-Younger-Dryas methane increase signal. Our data also demonstrate that the methane record in this ice is uncontaminated and suitable for methane 14C analysis. During the past year, we also constructed and are testing a device for melting and extracting air from large volumes of glacial ice.

  10. Archaebacterial Fuel Production: Methane from Biomass.

    ERIC Educational Resources Information Center

    Lennox, John E.; And Others

    1983-01-01

    Discusses microbial production of methane from biomass. Topics include methogens (bacteria producing methane), ecology of methanogenesis, methanogenesis in ruminant/nonruminant and other environments, role of methanogenesis in nature, and methane production in sewage treatment plants. Also discusses construction of methane digesters (and related…

  11. Oceanic Methane Concentrations in Three Mexican Regions

    EPA Science Inventory

    The atmospheric concentration of methane has increased significantly over the last several decades. Methane is an important greenhouse gas, and it is important to better quantify methane sources and sinks. Dissolved methane in the ocean is produced by biological and hydrothermal ...

  12. 75 FR 9886 - Methane Hydrate Advisory Committee

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-04

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. Federal... Methane Hydrate Advisory Committee is to provide advice on potential applications of methane hydrate...

  13. A fully coupled model for water-gas-heat reactive transport with methane oxidation in landfill covers.

    PubMed

    Ng, C W W; Feng, S; Liu, H W

    2015-03-01

    Methane oxidation in landfill covers is a complex process involving water, gas and heat transfer as well as microbial oxidation. The coupled phenomena of microbial oxidation, water, gas, and heat transfer are not fully understood. In this study, a new model is developed that incorporates water-gas-heat coupled reactive transport in unsaturated soil with methane oxidation. Effects of microbial oxidation-generated water and heat are included. The model is calibrated using published data from a laboratory soil column test. Moreover, a series of parametric studies are carried out to investigate the influence of microbial oxidation-generated water and heat, initial water content on methane oxidation efficiency. Computed and measured results of gas concentration and methane oxidation rate are consistent. It is found that the coupling effects between water-gas-heat transfer and methane oxidation are significant. Ignoring microbial oxidation-generated water and heat can result in a significant difference in methane oxidation efficiency by 100%.

  14. SeaWiFS technical report series. Volume 27: Case studies for SeaWiFS calibration and validation, part 3

    NASA Technical Reports Server (NTRS)

    Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Acker, James G. (Editor); Mueller, J. L.; Fraser, R. S.; Biggar, S. F.; Thome, K. J.; Slater, P. N.; Holmes, A. W.; Barnes, R. A.

    1995-01-01

    This document provides brief reports, or case studies, on a number of investigations sponsored by the Calibration and Validation Team (CVT) within the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project. Chapter I describes a comparison of the irradiance immersion coefficients determined for several different marine environmental radiometers (MERs). Chapter 2 presents an analysis of how light absorption by atmospheric oxygen will influence the radiance measurements in band 7 of the SeaWiFS instrument. Chapter 3 gives the results of the second ground-based solar calibration of the instrument, which was undertaken after the sensor was modified to reduce the effects of internal stray light. (The first ground-based solar calibration of SeaWiFS is described in Volume 19 in the SeaWiFS Technical Report Series.) Chapter 4 evaluates the effects of ship shadow on subsurface irradiance and radiance measurements deployed from the deck of the R/V Weatherbird 11 in the Atlantic Ocean near Bermuda. Chapter 5 illustrates the various ways in which a single data day of SeaWiFS observations can be defined, and why the spatial definition is superior to the temporal definition for operational usage.

  15. Series: The research agenda for general practice/family medicine and primary health care in Europe. Part 5: Needs and implications for future research and policy.

    PubMed

    van Royen, Paul; Beyer, Martin; Chevallier, Patrick; Eilat-Tsanani, Sophia; Lionis, Christos; Peremans, Lieve; Petek, Davorina; Rurik, Imre; Soler, Jean Karl; Stoffers, Henri E J H; Topsever, Pinar; Ungan, Mehmet; Hummers-Pradier, Eva

    2010-12-01

    The recently published 'Research Agenda for General Practice/Family Medicine and Primary Health Care in Europe' summarizes the evidence relating to the core competencies and characteristics of the Wonca Europe definition of GP/FM, and highlights related needs and implications for future research and policy. The European Journal of General Practice publishes a series of articles based on this document. In a first article, background, objectives, and methodology were discussed. In three subsequent, articles the results for the six core competencies of the European Definition of GP/FM were presented. This article formulates the common aims for further research and appropriate research methodologies, based on the missing evidence and research gaps identified form the comprehensive literature review. In addition, implications of this research agenda for general practitioners/family doctors, researchers, research organizations, patients and policy makers are presented. The concept of six core competencies should be abandoned in favour of a model with four dimensions, including clinical, person related, community oriented and management aspects. Future research and policy should consider more the involvement and rights of patients; more attention should be given to how new treatments or technologies are effectively translated into routine patient care, in particular primary care. There is a need for a European ethics board. The promotion of GP/FM research demands a good infrastructure in each country, including access to literature and databases, appropriate funding and training possibilities.

  16. SeaWiFS technical report series. Volume 13: Case studies for SeaWiFS calibration and validation, part 1

    NASA Technical Reports Server (NTRS)

    Hooker, Stanford B. (Editor); Firestone, Elaine R. (Editor); Mcclain, Charles R.; Comiso, Josefino C.; Fraser, Robert S.; Firestone, James K.; Schieber, Brian D.; Yeh, Eueng-Nan; Arrigo, Kevin R.; Sullivan, Cornelius W.

    1994-01-01

    Although the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Calibration and Validation Program relies on the scientific community for the collection of bio-optical and atmospheric correction data as well as for algorithm development, it does have the responsibility for evaluating and comparing the algorithms and for ensuring that the algorithms are properly implemented within the SeaWiFS Data Processing System. This report consists of a series of sensitivity and algorithm (bio-optical, atmospheric correction, and quality control) studies based on Coastal Zone Color Scanner (CZCS) and historical ancillary data undertaken to assist in the development of SeaWiFS specific applications needed for the proper execution of that responsibility. The topics presented are as follows: (1) CZCS bio-optical algorithm comparison, (2) SeaWiFS ozone data analysis study, (3) SeaWiFS pressure and oxygen absorption study, (4) pixel-by-pixel pressure and ozone correction study for ocean color imagery, (5) CZCS overlapping scenes study, (6) a comparison of CZCS and in situ pigment concentrations in the Southern Ocean, (7) the generation of ancillary data climatologies, (8) CZCS sensor ringing mask comparison, and (9) sun glint flag sensitivity study.

  17. SeaWiFS technical report series. Volume 20: The SeaWiFS bio-optical archive and storage system (SeaBASS), part 1

    NASA Technical Reports Server (NTRS)

    Hooker, Stanford B. (Editor); Mcclain, Charles R.; Firestone, James K.; Westphal, Todd L.; Yeh, Eueng-Nan; Ge, Yuntao; Firestone, Elaine R.

    1994-01-01

    This document provides an overview of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Bio-Optical Archive and Storage System (SeaBASS), which will serve as a repository for numerous data sets of interest to the SeaWiFS Science Team and other approved investigators in the oceanographic community. The data collected will be those data sets suitable for the development and evaluation of bio-optical algorithms which include results from SeaWiFS Intercalibration Round-Robin Experiments (SIRREXs), prelaunch characterization of the SeaWiFS instrument by its manufacturer -- Hughes/Santa Barbara Research Center (SBRC), Marine Optical Characterization Experiment (MOCE) cruises, Marine Optical Buoy (MOBY) deployments and refurbishments, and field studies of other scientists outside of NASA. The primary goal of the data system is to provide a simple mechanism for querying the available archive and requesting specific items, while assuring that the data is made available only to authorized users. The design, construction, and maintenance of SeaBASS is the responsibility of the SeaWiFS Calibration and Validation Team (CVT). This report is concerned with documenting the execution of this task by the CVT and consists of a series of chapters detailing the various data sets involved. The topics presented are as follows: 1) overview of the SeaBASS file architecture, 2) the bio-optical data system, 3) the historical pigment database, 4) the SIRREX database, and 5) the SBRC database.

  18. Quantification of methane fluxes from industrial sites using a combination of a tracer release method and a Gaussian model

    NASA Astrophysics Data System (ADS)

    Ars, S.; Broquet, G.; Yver-Kwok, C.; Wu, L.; Bousquet, P.; Roustan, Y.

    2015-12-01

    Greenhouse gas (GHG) concentrations keep on increasing in the atmosphere since industrial revolution. Methane (CH4) is the second most important anthropogenic GHG after carbon dioxide (CO2). Its sources and sinks are nowadays well identified however their relative contributions remain uncertain. The industries and the waste treatment emit an important part of the anthropogenic methane that is difficult to quantify because the sources are fugitive and discontinuous. A better estimation of methane emissions could help industries to adapt their mitigation's politic and encourage them to install methane recovery systems in order to reduce their emissions while saving money. Different methods exist to quantify methane emissions. Among them is the tracer release method consisting in releasing a tracer gas near the methane source at a well-known rate and measuring both their concentrations in the emission plume. The methane rate is calculated using the ratio of methane and tracer concentrations and the emission rate of the tracer. A good estimation of the methane emissions requires a good differentiation between the methane actually emitted by the site and the methane from the background concentration level, but also a good knowledge of the sources distribution over the site. For this purpose, a Gaussian plume model is used in addition to the tracer release method to assess the emission rates calculated. In a first step, the data obtained for the tracer during a field campaign are used to tune the model. Different model's parameterizations have been tested to find the best representation of the atmospheric dispersion conditions. Once these parameters are set, methane emissions are estimated thanks to the methane concentrations measured and a Bayesian inversion. This enables to adjust the position and the emission rate of the different methane sources of the site and remove the methane background concentration.

  19. Attention turns to naturally occurring methane seepage

    NASA Astrophysics Data System (ADS)

    Kvenvolden, Keith A.; Lorenson, Thomas D.; Reeburgh, William S.

    Methane is the most abundant organic compound in the Earth's atmosphere. As a powerful greenhouse gas, it has implications for global climate change. Sources of methane to the atmosphere are varied. Depending on the source, methane can contain either modern or ancient carbon. Methane exiting from swamps and wetlands contains modern carbon, whereas methane leaking from petroleum reservoirs contains ancient carbon. The total annual source of methane to the atmosphere has been constrained to about 540 teragrams (Tg) per year “Cicerone and Oremland, 1988”. Notably absent from any identified sources is the contribution of geologically sourced methane from naturally occurring seepage.

  20. Gas hydrate formation rates from dissolved-phase methane in porous laboratory specimens

    USGS Publications Warehouse

    Waite, William F.; Spangenberg, E.K.

    2013-01-01

    Marine sands highly saturated with gas hydrates are potential energy resources, likely forming from methane dissolved in pore water. Laboratory fabrication of gas hydrate-bearing sands formed from dissolved-phase methane usually requires 1–2 months to attain the high hydrate saturations characteristic of naturally occurring energy resource targets. A series of gas hydrate formation tests, in which methane-supersaturated water circulates through 100, 240, and 200,000 cm3 vessels containing glass beads or unconsolidated sand, show that the rate-limiting step is dissolving gaseous-phase methane into the circulating water to form methane-supersaturated fluid. This implies that laboratory and natural hydrate formation rates are primarily limited by methane availability. Developing effective techniques for dissolving gaseous methane into water will increase formation rates above our observed (1 ± 0.5) × 10−7 mol of methane consumed for hydrate formation per minute per cubic centimeter of pore space, which corresponds to a hydrate saturation increase of 2 ± 1% per day, regardless of specimen size.

  1. Water Column Methanotrophy Fueled by Methane from the Hudson Canyon Seep Field, US Atlantic Margin

    NASA Astrophysics Data System (ADS)

    Redmond, M. C.; Chan, E. W.; Kellermann, M. Y.; Arrington, E.; Valentine, D. L.; Kessler, J. D.

    2014-12-01

    Several areas of methane seepage have recently been discovered along the US Atlantic margin, including parts of Hudson Canyon, offshore New York and New Jersey. However, little is known about the magnitude of seepage, the fate of this methane once it enters the water column, or the bacteria that may consume it. In July 2014, water column methane concentrations were measured throughout Hudson Canyon and methane oxidation tracked using a 13C-methane tracer. Samples for microbial community composition analysis were collected throughout the water column in areas with and without active seepage. 16S rRNA gene sequencing will be used to compare microbial communities from different depths, locations, and in samples with low and high methane concentrations and oxidation rates. DNA stable isotope probing experiments with 13C-labeled methane were also conducted and will be used to detect active water column methanotrophs from seep and non-seep sites. In addition, mesocosm experiments were used for high resolution measurements of methane oxidation, with samples for microbial community composition taken at several time points. 16S rRNA gene sequencing will be used to track changes in methanotrophic bacteria and the overall microbial community as methane was consumed.

  2. Methane emissions from oceans, coasts, and freshwater habitats: New perspectives and feedbacks on climate

    USGS Publications Warehouse

    Hamdan, Leila J.; Wickland, Kimberly P.

    2016-01-01

    Methane is a powerful greenhouse gas, and atmospheric concentrations have risen 2.5 times since the beginning of the Industrial age. While much of this increase is attributed to anthropogenic sources, natural sources, which contribute between 35% and 50% of global methane emissions, are thought to have a role in the atmospheric methane increase, in part due to human influences. Methane emissions from many natural sources are sensitive to climate, and positive feedbacks from climate change and cultural eutrophication may promote increased emissions to the atmosphere. These natural sources include aquatic environments such as wetlands, freshwater lakes, streams and rivers, and estuarine, coastal, and marine systems. Furthermore, there are significant marine sediment stores of methane in the form of clathrates that are vulnerable to mobilization and release to the atmosphere from climate feedbacks, and subsurface thermogenic gas which in exceptional cases may be released following accidents and disasters (North Sea blowout and Deepwater Horizon Spill respectively). Understanding of natural sources, key processes, and controls on emission is continually evolving as new measurement and modeling capabilities develop, and different sources and processes are revealed. This special issue of Limnology and Oceanography gathers together diverse studies on methane production, consumption, and emissions from freshwater, estuarine, and marine systems, and provides a broad view of the current science on methane dynamics of aquatic ecosystems. Here, we provide a general overview of aquatic methane sources, their contribution to the global methane budget, and key uncertainties. We then briefly summarize the contributions to and highlights of this special issue.

  3. Geologic methane seeps along boundaries of Arctic permafrost thaw and melting glaciers

    NASA Astrophysics Data System (ADS)

    Walter Anthony, Katey M.; Anthony, Peter; Grosse, Guido; Chanton, Jeffrey

    2012-06-01

    Methane, a potent greenhouse gas, accumulates in subsurface hydrocarbon reservoirs, such as coal beds and natural gas deposits. In the Arctic, permafrost and glaciers form a `cryosphere cap' that traps gas leaking from these reservoirs, restricting flow to the atmosphere. With a carbon store of over 1,200Pg, the Arctic geologic methane reservoir is large when compared with the global atmospheric methane pool of around 5Pg. As such, the Earth's climate is sensitive to the escape of even a small fraction of this methane. Here, we document the release of 14C-depleted methane to the atmosphere from abundant gas seeps concentrated along boundaries of permafrost thaw and receding glaciers in Alaska and Greenland, using aerial and ground surface survey data and in situ measurements of methane isotopes and flux. We mapped over 150,000 seeps, which we identified as bubble-induced open holes in lake ice. These seeps were characterized by anomalously high methane fluxes, and in Alaska by ancient radiocarbon ages and stable isotope values that matched those of coal bed and thermogenic methane accumulations. Younger seeps in Greenland were associated with zones of ice-sheet retreat since the Little Ice Age. Our findings imply that in a warming climate, disintegration of permafrost, glaciers and parts of the polar ice sheets could facilitate the transient expulsion of 14C-depleted methane trapped by the cryosphere cap.

  4. IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (Gd–Lu)

    SciTech Connect

    Mioduski, Tomasz; Gumiński, Cezary; Zeng, Dewen

    2015-06-15

    This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF{sub 4} and YbF{sub 2} (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.

  5. Phase behavior of methane haze.

    PubMed

    Signorell, R; Jetzki, M

    2007-01-05

    Methane aerosols play a fundamental role in the atmospheres of Neptune, Uranus, and Saturn's moon Titan as borne out by the recent Cassini-Huygens mission. Here we present the first study of the phase behavior of free methane aerosol particles combining collisional cooling with rapid-scan infrared spectroscopy in situ. We find fast (within minutes) phase transitions to crystalline states directly after particle formation and characteristic surface effects for nanometer-sized particles. From our results, we conclude that in atmospheric clouds solid methane particles are crystalline.

  6. Improving dust and methane control

    SciTech Connect

    Cecala, A.B.; Organiscak, A.; Jankowski, R.A.

    1987-01-01

    This paper evaluates a number of techniques for controlling dust and methane during the headgate cutout of retreating longwall sections that use antitropal ventilation (headgate to tailgate). Some of these techniques are effective for both methane and dust control, while others are effective for only one or the other. The techniques include the gob curtain, the walkway curtain, stageloader-crusher control, and the wing curtain. Each improves the health and safety of workers and is economically feasible in hardware cost, setup cost, and maintenance. By combining various of these techniques, mine operators can substantially reduce the dust and methane concentrations at the shearer and ensure the health and safety of longwall workers.

  7. Methane hydroxylation: a biomimetic approach

    NASA Astrophysics Data System (ADS)

    Shilov, Aleksandr E.; Shteinman, Al'bert A.

    2012-04-01

    The review addresses direct methane oxidation — an important fundamental problem, which has attracted much attention of researchers in recent years. Analysis of the available results on biomimetic and bio-inspired methane oxygenation has demonstrated that assimilating of the experience of Nature on oxidation of methane and other alkanes significantly enriches the arsenal of chemistry and can radically change the character of the entire chemical production, as well as enables the solution of many material, energetic and environmental problems. The bibliography includes 310 references.

  8. Methane gas from cannery wastes

    SciTech Connect

    Not Available

    1981-12-01

    It is estimated that California produces 500,000 tons of tomato waste and 105,000 tons of peach waste from canneries every year. Results from a two-year investigation, including laboratory studies and pilot-plant operations indicate that it is possible to create methane gas through the anaerobic digestion of these cannery wastes. This article describes studies to determine the methane - generating potential of tomato and peach cannery wastes and of honeydew-melon culls separated in the field. A mobile pilot-scale methane plant situated at the T.H. Richards food processing plant in Sacramento is described.

  9. (Methane digester). Final report

    SciTech Connect

    Waybright, R.C.

    1981-01-01

    The purpose of the grant was to construct and operate a methane digester for dairy manure involving the latest state-of-the-art technics. The first step taken was to empty out the existing digester to evaluate its performance and to gain ideas of how to build the next digester so it would operate more efficiently. Next, the design criteria was set up in order to eliminate some problems involved with the first digester and also new ideas as to how to build the next one without a protective building and testing simplified construction technics. After this the digester construction was started with the completion date in late January. The digester was then filled and operated at different temperatures attempting to achieve the optimum operating range.

  10. Quantifying methane flux from lake sediments using multibeam sonar

    NASA Astrophysics Data System (ADS)

    Scandella, B.; Urban, P.; Delwiche, K.; Greinert, J.; Hemond, H.; Ruppel, C. D.; Juanes, R.

    2013-12-01

    methane fluxes from shallow-water bodies. Time series showing how the uncalibrated, sonar-detected flux estimate (black) varies inversely with the hydrostatic pressure (meters of water, blue) at 5-minute resolution during April 2012. Overlain is the time series of scaled gas flux from a mechanistic numerical model forced by the same hydrostatic pressure signal (orange).

  11. Effects of monovalent anions of the hofmeister series on DPPC lipid bilayers Part II: modeling the perpendicular and lateral equation-of-state.

    PubMed

    Leontidis, E; Aroti, A; Belloni, L; Dubois, M; Zemb, T

    2007-09-01

    The effects of Hofmeister anions on the perpendicular and lateral equation-of-state (EOS) of the dipalmitoylphosphatidylcholine lamellar phase discussed in the companion article are here examined using appropriate free energy models for the intra- and interbilayer interactions. Minimizing the free energy with respect to the two basic geometrical parameters of the lamellar phase, which are the interbilayer water thickness, d(w), and the lipid headgroup area, a(L), provides the perpendicular (osmotic pressure balance) and lateral EOS. Standard models were used for the hydration, undulation, and Van der Waals attractive force between the bilayers in the presence of electrolytes whereas two alternative treatments of electrostatic interactions were used to obtain "binding" or "partitioning" constants of anions to the lipid bilayers both in the absence and in the presence of sodium binding. The computed binding constants depend on anion type and follow the Hofmeister series, but were found to increase with electrolyte concentration, implying that the local binding approximation cannot fit bilayer repulsion data. The partitioning model was also found inadequate at high electrolyte concentrations. The fitting attempts revealed two additional features worthy of future investigation. First, at maximum swelling in the presence of electrolytes the osmotic pressure of the bilayer system cannot be set equal to zero. Second, at high salt concentrations an additional repulsion appears to come into effect in the presence of strongly adsorbing anions such as I(-) or SCN(-). Both these phenomena may reflect an inconsistent treatment of the ion-surface interactions, which have an impact on the osmotic pressure. Alternatively, they may arise from bulk solution nonidealities that cannot be handled by the classical Poisson-Boltzmann formalism. The inability of current models to explain the "lateral" EOS by fitting the area per lipid headgroup as a function of salt type and concentration

  12. Effects of Monovalent Anions of the Hofmeister Series on DPPC Lipid Bilayers Part II: Modeling the Perpendicular and Lateral Equation-of-State

    PubMed Central

    Leontidis, E.; Aroti, A.; Belloni, L.; Dubois, M.; Zemb, T.

    2007-01-01

    The effects of Hofmeister anions on the perpendicular and lateral equation-of-state (EOS) of the dipalmitoylphosphatidylcholine lamellar phase discussed in the companion article are here examined using appropriate free energy models for the intra- and interbilayer interactions. Minimizing the free energy with respect to the two basic geometrical parameters of the lamellar phase, which are the interbilayer water thickness, dw, and the lipid headgroup area, aL, provides the perpendicular (osmotic pressure balance) and lateral EOS. Standard models were used for the hydration, undulation, and Van der Waals attractive force between the bilayers in the presence of electrolytes whereas two alternative treatments of electrostatic interactions were used to obtain “binding” or “partitioning” constants of anions to the lipid bilayers both in the absence and in the presence of sodium binding. The computed binding constants depend on anion type and follow the Hofmeister series, but were found to increase with electrolyte concentration, implying that the local binding approximation cannot fit bilayer repulsion data. The partitioning model was also found inadequate at high electrolyte concentrations. The fitting attempts revealed two additional features worthy of future investigation. First, at maximum swelling in the presence of electrolytes the osmotic pressure of the bilayer system cannot be set equal to zero. Second, at high salt concentrations an additional repulsion appears to come into effect in the presence of strongly adsorbing anions such as I− or SCN−. Both these phenomena may reflect an inconsistent treatment of the ion-surface interactions, which have an impact on the osmotic pressure. Alternatively, they may arise from bulk solution nonidealities that cannot be handled by the classical Poisson-Boltzmann formalism. The inability of current models to explain the “lateral” EOS by fitting the area per lipid headgroup as a function of salt type and

  13. Identifying sources of methane sampled in the Arctic using δ13C in CH4 and Lagrangian particle dispersion modelling.

    NASA Astrophysics Data System (ADS)

    Cain, Michelle; France, James; Pyle, John; Warwick, Nicola; Fisher, Rebecca; Lowry, Dave; Allen, Grant; O'Shea, Sebastian; Illingworth, Samuel; Jones, Ben; Gallagher, Martin; Welpott, Axel; Muller, Jennifer; Bauguitte, Stephane; George, Charles; Hayman, Garry; Manning, Alistair; Myhre, Catherine Lund; Lanoisellé, Mathias; Nisbet, Euan

    2016-04-01

    An airmass of enhanced methane was sampled during a research flight at ~600 m to ~2000 m altitude between the North coast of Norway and Svalbard on 21 July 2012. The largest source of methane in the summertime Arctic is wetland emissions. Did this enhancement in methane come from wetland emissions? The airmass was identified through continuous methane measurements using a Los Gatos fast greenhouse gas analyser on board the UK's BAe-146 Atmospheric Research Aircraft (ARA) as part of the MAMM (Methane in the Arctic: Measurements and Modelling) campaign. A Lagrangian particle dispersion model (the UK Met Office's NAME model) was run backwards to identify potential methane source regions. This was combined with a methane emission inventory to create "pseudo observations" to compare with the aircraft observations. This modelling was used to constrain the δ13C CH4 wetland source signature (where δ13C CH4 is the ratio of 13C to 12C in methane), resulting in a most likely signature of -73‰ (±4‰7‰). The NAME back trajectories suggest a methane source region of north-western Russian wetlands, and -73‰ is consistent with in situ measurements of wetland methane at similar latitudes in Scandinavia. This analysis has allowed us to study emissions from remote regions for which we do not have in situ observations, giving us an extra tool in the determination of the isotopic source variation of global methane emissions.

  14. Mars Methane Analogue Mission (M3): Near Subsurface Electromagnetic Techniques and Analysis

    NASA Astrophysics Data System (ADS)

    Boivin, A.; Samson, C.; Holladay, J. S.; Cloutis, E. A.; Ernst, R. E.

    2012-03-01

    As part of the Canadian Space Agency's Mars Methane Analogue Mission, a micro-rover mission, an Electromagnetic Induction Sounder (EMIS) was used with the goal of demonstrating its value as a potential science instrument onboard future rovers.

  15. An overview of herb and dietary supplement efficacy, safety and government regulations in the United States with suggested improvements. Part 1 of 5 series.

    PubMed

    Brown, Amy Christine

    2016-11-03

    series to forewarn consumers, clinicians, corporations, and governments of possible serious adverse events. They may also quicken the response rate during Phase IV post-marketing surveillance, in which governments could then exercise their regulatory powers.

  16. Methane-related microbial processes and metabolic stratification in a terrestrial mud volcano, southwestern Taiwan

    NASA Astrophysics Data System (ADS)

    Cheng, T.; Lin, L.; Wang, P.; Chu, P.; Wu, J.

    2009-12-01

    Mud volcanoes are distinct geological features with fluid, sediment and hydrocarbon-enriched gas mixtures emitted from deep sedimentary environments. Without microbial attenuation in the water column, methane emission to atmosphere from terrestrial mud volcanoes constitutes a significant proportion to the global methane inventory. Microorganisms mediating methane transformation would be particularly enriched in such environments. Their activity, distribution, and diversity involved remain not well-constrained. At Shin-Yan-Ny-Hu Mud Volcanoes (SYNHMV) of southwestern Taiwan, we performed series of measurements and analyses on the pore water and eruptive water samples using geochemical and molecular approaches, in order to determine microbial processes and community assemblages responsible for methane transformation. Geochemical measurements indicated that sulfate depletion was companied with methane increase as the depth increased. Dissolved inorganic carbon (DIC) more depleted in 13C was observed at the depth of sulfate-methane transition zone (SMT, at ~12cm depth) than at other depth intervals. These characteristics of methane, sulfate, and DIC isotope profiles and the presence of ANME-1 sequences showed a high similarity with those of marine sediments, indicating the existence of active anaerobic oxidation of methane (AOM). From bottom to top, the increasing δ13C values of methane with the greatest value occurring in the eruptive surface water suggests methanogenesis and/or methane oxidation over the entire depth range. The contribution of microbial methane could be supported by molecular data of which methanogen-related archaea distributed throughout the entire depths, and the community structures were characterized by Methanosarcinales dominating at shallow depths and Methanomicrobiales dominating in deep sediments. The affinities and activities to substrate addition for methanogenesis appeared to be depth-dependent. Bacterial sequences affiliated with methane

  17. Methane production in terrestrial arthropods.

    PubMed Central

    Hackstein, J H; Stumm, C K

    1994-01-01

    We have screened more than 110 representatives of the different taxa of terrestrial arthropods for methane production in order to obtain additional information about the origins of biogenic methane. Methanogenic bacteria occur in the hindguts of nearly all tropical representatives of millipedes (Diplopoda), cockroaches (Blattaria), termites (Isoptera), and scarab beetles (Scarabaeidae), while such methanogens are absent from 66 other arthropod species investigated. Three types of symbiosis were found: in the first type, the arthropod's hindgut is colonized by free methanogenic bacteria; in the second type, methanogens are closely associated with chitinous structures formed by the host's hindgut; the third type is mediated by intestinal anaerobic protists with intracellular methanogens. Such symbiotic associations are likely to be a characteristic property of the particular taxon. Since these taxa represent many families with thousands of species, the world populations of methane-producing arthropods constitute an enormous biomass. We show that arthropod symbionts can contribute substantially to atmospheric methane. Images PMID:8202505

  18. Methane production in terrestrial arthropods

    SciTech Connect

    Hackstein, J.H.P.; Stumm, C.K. )

    1994-06-07

    The authors have screened more than 110 representatives of the different taxa of terrestrial arthropods for methane production in order to obtain additional information about the origins of biogenic methane. Methanogenic bacteria occur in the hindguts of nearly all tropical representatives of millipedes (Diplopoda), cockroaches (Blattaria), termites (Isoptera), and scarab beetles (Scarabaeidae), while such methanogens are absent from 66 other arthropod species investigated. Three types of symbiosis were found: in the first type, the arthropod's hindgut is colonized by free methanogenic bacteria; in the second type, methanogens are closely associated with chitinous structures formed by the host's hindgut; the third type is mediated by intestinal anaerobic protists with intracellular methanogens. Such symbiotic associations are likely to be a characteristic property of the particular taxon. Since these taxa represent many families with thousands of species, the world populations of methane-producing arthropods constitute an enormous biomass. The authors show that arthropod symbionts can contribute substantially to atmospheric methane.

  19. Titan ocean: Ethane, methane, nitrogen

    NASA Astrophysics Data System (ADS)

    Bell, Peter M.

    Detection of the atmosphere of Saturn's satellite Titan by the Voyager I spacecraft indicated an abundance of only 3 mol % methane (CH4). Recently J.I. Lunine, D.J. Stevenson, and Y.L. Yung calculated that 3 mol % methane is sufficiently low to preclude the stable coexistence of liquid methane on Titan's surface, which has a temperature of 94 K (Science, 222, 1229, 1983). Instead, Lunine et al. suggest that Titan's atmospheric methane may have broken down by a catalyzed photochemical reaction to ethane (C2H6). The resulting ocean would consist of a mixture of C2H6 and CH4 in the proportion of 3 to 1.

  20. Atmospheric Impact of Large Methane Emission in the Arctic Region

    NASA Astrophysics Data System (ADS)

    Bhattacharyya, S.; Cameron-Smith, P. J.; Bergmann, D.; Reagan, M. T.; Collins, W.; Elliott, S. M.; Maltrud, M. E.

    2011-12-01

    A highly potent greenhouse gas, methane, is locked in the solid phase as ice-like deposits containing a mixture of water and gas (mostly methane) called clathrates, in ocean sediments and underneath permafrost regions. Clathrates are stable under high pressure and low temperatures. Recent estimates suggest that about 1600 - 2000GtC of clathrates are present in oceans and 400GtC in Arctic permafrost (Archer et al.2009) which is about 4000 times that of current annual emissions. In a warming climate, increase in ocean temperatures could alter the geothermal gradient, which in turn could lead to dissociation of the clathrates and release of methane into the ocean and subsequently into the atmosphere as well. This could be of particular importance in the shallow part of the Arctic Ocean where the clathrates are found in depths of only 300m. In this presentation, we shall show results from our ongoing simulation of a scenario of large scale methane outgassing from clathrate dissociation due to warming ocean temperatures in the Arctic based on ocean sediment modeling. To that end we use the CESM (Community Earth System Model) version 1 with fully active coupled atmosphere-ocean-land model together with fast atmospheric chemistry module to simulate the response to increasing methane emissions in the Barents Sea, Canadian Archipelago and the Sea of Okhotsk. The simulation shows the effect these methane emissions could have on global surface methane, surface ozone, surface air temperature and other related indices. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-491764

  1. Methane in well water from Lake Charles, Louisiana

    SciTech Connect

    Murray, H.E.; Beck, J.N. )

    1992-05-01

    The Chicot aquifer underlies all or parts of 13 parishes in Southwestern Louisiana. The uses of the aquifer include agricultural, industrial and provides nearly 100% of the potable water for the area. Southwestern Louisiana has a large natural gas industry and its associated distribution facilities. Agriculture is unique in this region in that there is extensive rice production and crawfish farming which results in large areas being seasonally flooded. Much of this coastal region consists of fresh and brackish marsh. Methane gas has been found in varying concentrations throughout the environment. Concentrations of 1.6 ppm in atmospheric samples were reported by Stauffer et al. (1985). Relatively high concentrations of dissolved methane have been reported to occur in natural ecosystems as a result of leakage of hydrocarbon deposits, and also from biogenic sources. In deep subsurface environments, such as groundwater, methanogenesis has also been reported. Often the presence of methane in these deep subsurface systems is due to waste leachate contamination. Methane can degas from groundwater and accumulate in wells or buildings thereby posing a potential explosion hazard. In addition, groundwater containing dissolved methane can serve as a primary energy source for the development of microbial communities. Gunsalus et al. (1962) reported substantial microbial growth at the air-water interface of a methane-supersaturated well system in which microbial oxidation of methane provided the necessary energy for microbial growth. Microbial growth within a well system could create taste and odor problems among other things that would directly affect water quality. 8 refs., 1 fig., 1 tab.

  2. Methane emissions from MBT landfills

    SciTech Connect

    Heyer, K.-U. Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: • Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. • Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. • Methane oxidation in the waste itself and in soil covers. • Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (“Umweltbundesamt”), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 18–24 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD

  3. Optimizing immunosuppressive drug dosing in pediatric renal transplantation. Part of a special series on Paediatric Pharmacology, guest edited by Gianvincenzo Zuccotti, Emilio Clementi, and Massimo Molteni.

    PubMed

    Cattaneo, Dario; Vinks, Alexander A

    2012-02-01

    Kidney transplantation in pediatric patients has become a successful and routine procedure, with overall 1-year patient and graft survival rates exceeding 95%. These success rates, however, are not maintained in the long-term, as reported 10-year graft survival rates are in the 50-60% range. Further improvement of long-term allograft survival in pediatric transplantation requires specific focus on long term complications such as increased cardiovascular risk and over-immunosuppression, two linked conditions. One approach to avoid inadequate immunosuppression is to more aggressively tailor immunosuppressive treatment based on individual patient needs. This strategy is currently pursued in the pediatric transplant setting by implementation of individualized therapeutic management of drug concentrations and total exposure. In addition, there is increasing evidence that pharmacogenetic testing may equally benefit individualized immunosuppressive therapy through the identification of SNPs and haplotypes predictive of encoding of proteins involved in drug transport, metabolism and response (efficacy/toxicity). The next challenge will be to provide real time web-based access to all patient information including pharmacokinetic, pharmacodynamic and genotyping data as part of a dosing algorithm or decision support tool with the ultimate goal to adaptively predict and control immunosuppressant exposure and response in individual patients to improve long-term outcomes after kidney transplantation.

  4. Modelling an experimental methane fuel processor

    NASA Astrophysics Data System (ADS)

    Lin, Shi-Tin; Chen, Yih-Hang; Yu, Cheng-Ching; Liu, Yen-Chun; Lee, Chiou-Hwang

    Steady-state models are developed to describe an experimental methane fuel processor that is intended to provide hydrogen for a fuel cell system for power generation (2-3 kW). First-principle reactor models are constructed to describe a series of reactions, i.e., steam and autothermal reforming (SR/ATR), high- and low-temperature water-gas shift (HTS/LTS) reactions and preferential oxidation (PROX) reactions, at different sectors of the reactor system for methane reforming as well as gas cleaning. The pre-exponential factors of the rate constants are adjusted to fit the experimental data and the resultant reactor model provides a reasonably good description of steady-state behaviour. Next, sensitivity analyses are performed to locate the optimum operating point of the fuel processor. The objective function of the optimization is fuel processor efficiency. The dominating optimization variables include: the ratios of water and oxygen to the hydrocarbon feed to the autothermal reforming reactor and the inlet temperature of the reactor. The results indicate that further improvement in fuel processor efficiency can be made with a reliable process model.

  5. Experimental determination of methane dissolution from simulated subsurface oil leakages

    NASA Astrophysics Data System (ADS)

    Sauthoff, W.; Peltzer, E. T.; Walz, P. M.; Brewer, P. G.

    2013-12-01

    Subsurface oil leakages and increased offshore drilling efforts have raised concern over the fate of hydrocarbon mixtures of oil and gas in ocean environments. Recent wellhead and pipeline failures in the Gulf of Mexico are extreme examples of this problem. Understanding the mechanism and rate of vertical transport of hydrocarbon chemical species is necessary to predict the environmental impact of subsurface leakages. In a series of controlled experiments, we carried out a deep-sea field experiment in Monterey Canyon to investigate the behavior of a gas-saturated liquid hydrocarbon mass rising from the seafloor. Aboard the R/V Rachel Carson, we used the ROV Ventana to transport a laboratory prepared volume of decane (C10H22) saturated with methane gas (CH4) to mimic a subsurface seafloor discharge. We released the oil and gas mixture into a vertically oriented open bottom glass tube followed by methane loss rate measurements both at discrete depths, and during rapid, continuous vehicle ascent from 800 to 100 m water depth to monitor changes in dissolution and bubble nucleation. Using laser Raman techniques and HD video we quantified the chemical state of the hydrocarbon fluid, including rate of methane gas dissolution. The primary methane Raman peak was readily observable within the decane C-H stretching complex. Variation in the amount of gas dissolved in the oil greatly influences oil plume density and in turn oil plume vertical rise rate. Our results show that the rise rate of the hydrocarbon mass significantly exceeds the rate at which the excess methane was lost by dissolution. This result implies that vertical transport of methane in the saturated hydrocarbon liquid phase can greatly exceed a gas bubble plume ascending the water column from a seafloor source. These results and observations may be applicable to improved understanding of the composition, distribution, and environmental fate of leaked hydrocarbon mixtures and inform remediation efforts.

  6. Methane production in Minnesota peatlands

    SciTech Connect

    Williams, R.T.; Crawford, R.L.

    1984-06-01

    Rates of methane production in Minnesota peats were studied. Surface (10- to 25-cm) peats produced an average of 228 nmol of CH/sub 4/ per g (dry weight) per h at 25/sup 0/C and ambient pH. Methanogenesis rates generally decreased with depth in ombrotrophic peats, but on occasion were observed to rise within deeper layers of certain fen peats. Methane production was temperature dependent, increasing with increasing temperature (4 to 30/sup 0/C), except in peats from deeper layers. Maximal methanogenesis from these deeper regions occurred at 12/sup 0/C. Methane production rates were also pH dependent. Two peats with pHs of 3.8 and 4.3 had an optimum rate of methane production at pH 6.0. The addition to peat of glucose and H/sub 2/-CO/sub 2/ stimulated methanogenesis, whereas the addition of acetate inhibited methanogenesis. Cysteine-sulfide, nitrogen-phosphorus-trace metals, and vitamins-yeast extract affected methane production very little. Various gases were found to be trapped or dissolved (or both) within peatland waters. Dissolved methane increased linearly to a depth of 210 cm. The accumulation of metabolic end products produced within peat bogs appears to be an important mechanism limiting turnover in peatland environments.

  7. Geoscience in Support of a Mars Methane Analogue Mission

    NASA Astrophysics Data System (ADS)

    Boivin, Alexandre

    The Mars Methane Analogue Mission, funded by the Canadian Space Agency through its Analogue Missions program, simulates a Mars rover mission whose purpose is to detect, analyse, and determine the source of methane emissions on the planet's surface. As part of this project, both an electromagnetic induction sounder (EMIS) and a high-resolution triangulation-based 3D laser scanner were tested in the field to demonstrate the benefit of including these instruments on future rover missions. EMIS data was inverted in order to derive information on the conductivity and magnetic susceptibility of the near subsurface. 3D laser scanner data was processed with fracture detection as a goal in order to simplify the search for areas of potential methane seepage. Both instruments were found to be very valuable for future rover missions of this type.

  8. Manganese- and iron-dependent marine methane oxidation.

    PubMed

    Beal, Emily J; House, Christopher H; Orphan, Victoria J

    2009-07-10

    Anaerobic methanotrophs help regulate Earth's climate and may have been an important part of the microbial ecosystem on the early Earth. The anaerobic oxidation of methane (AOM) is often thought of as a sulfate-dependent process, despite the fact that other electron acceptors are more energetically favorable. Here, we show that microorganisms from marine methane-seep sediment in the Eel River Basin in California are capable of using manganese (birnessite) and iron (ferrihydrite) to oxidize methane, revealing that marine AOM is coupled, either directly or indirectly, to a larger variety of oxidants than previously thought. Large amounts of manganese and iron are provided to oceans from rivers, indicating that manganese- and iron-dependent AOM have the potential to be globally important.

  9. The permeation of methane molecules through silicalite-1 surfaces.

    PubMed

    Thompho, Somphob; Chanajaree, Rungroj; Remsungnen, Tawun; Hannongbua, Supot; Bopp, Philippe A; Fritzsche, Siegfried

    2009-03-12

    The permeation of methane molecules through the silicalite-1 surfaces with and without silanol groups has been studied by nonequilibrium molecular dynamics computer simulations. A newly fitted intermolecular potential between the methane molecules and the silanol is used. A control volume provides a nearly stationary gas phase close to the membrane. The nonequilibrium process of filling the (initially empty) membrane with methane molecules until saturation is considered, and the surface permeability has been evaluated. It turns out to be strongly influenced by the presence of silanol groups. Additionally it was found that for a large part of the loading process the particle stream into the zeolite membrane was nearly independent upon the deviation from equilibrium. This means that far from equilibrium the decay of this deviation does not follow an exponential law.

  10. Russian boreal peatlands dominate the natural European methane budget

    NASA Astrophysics Data System (ADS)

    Schneider, Julia; Jungkunst, Hermann F.; Wolf, Ulrike; Schreiber, Peter; Gažovič, Michal; Miglovets, Mikhail; Mikhaylov, Oleg; Grunwald, Dennis; Erasmi, Stefan; Wilmking, Martin; Kutzbach, Lars

    2016-01-01

    About 60% of the European wetlands are located in the European part of Russia. Nevertheless, data on methane emissions from wetlands of that area are absent. Here we present results of methane emission measurements for two climatically different years from a boreal peatland complex in European Russia. Winter fluxes were well within the range of what has been reported for the peatlands of other boreal regions before, but summer fluxes greatly exceeded the average range of 5-80 mg CH4 m-2 d-1 for the circumpolar boreal zone. Half of the measured fluxes ranged between 150 and 450 mg CH4 m-2 d-1. Extrapolation of our data to the whole boreal zone of European Russia shows that theses emissions could amount to up to 2.7 ± 1.1 Tg CH4 a-1, corresponding to 69% of the annual emissions from European wetlands or 33% of the total annual natural European methane emission. In 2008, climatic conditions corresponded to the long term mean, whereas the summer of 2011 was warmer and noticeably drier. Counterintuitively, these conditions led to even higher CH4 emissions, with peaks up to two times higher than the values measured in 2008. As Russian peatlands dominate the areal extend of wetlands in Europe and are characterized by very high methane fluxes to the atmosphere, it is evident, that sound European methane budgeting will only be achieved with more insight into Russian peatlands.

  11. Investigation of the Methane Hydrate Formation by Cavitation Jet

    NASA Astrophysics Data System (ADS)

    Morita, H.; Nagao, J.

    2015-12-01

    Methane hydrate (hereafter called "MH") is crystalline solid compound consisting of hydrogen-bonded water molecules forming cages and methane gas molecules enclosed in the cage. When using MH as an energy resource, MH is dissociated to methane gas and water and collect only the methane gas. The optimum MH production method was the "depressurization method". Here, the production of MH means dissociating MH in the geologic layers and collecting the resultant methane gas by production systems. In the production of MH by depressurization method, MH regeneration was consider to important problem for the flow assurance of MH production system. Therefore, it is necessary to clarify the effect of flow phenomena in the pipeline on hydrate regeneration. Cavitation is one of the flow phenomena which was considered a cause of MH regeneration. Large quantity of microbubbles are produced by cavitation in a moment, therefore, it is considered to promote MH formation. In order to verify the possible of MH regeneration by cavitation, it is necessary to detailed understanding the condition of MH formation by cavitation. As a part of a Japanese National hydrate research program (MH21, funded by METI), we performed a study on MH formation using by cavitation. The primary objective of this study is to demonstrate the formation MH by using cavitation in the various temperature and pressure condition, and to clarify the condition of MH formation by using observation results.

  12. 49 new T dwarfs identified using methane imaging

    NASA Astrophysics Data System (ADS)

    Cardoso, C. V.; Burningham, B.; Smart, R. L.; van Spaandonk, L.; Baker, D.; Smith, L. C.; Zhang, Z. H.; Andrei, A. H.; Bucciarelli, B.; Dhital, S.; Jones, H. R. A.; Lattanzi, M. G.; Magazzú, A.; Pinfield, D. J.; Tinney, C. G.

    2015-07-01

    We present the discovery of 49 new photometrically classified T dwarfs from the combination of large infrared and optical surveys combined with follow-up Telescopio Nazionale Galileo photometry. We used multiband infrared and optical photometry from the United Kingdom Infrared Telescope and Sloan Digital Sky Surveys to identify possible brown dwarf candidates, which were then confirmed using methane filter photometry. We have defined a new photometric conversion between CH4s - CH4l colour and spectral type for T4-T8 brown dwarfs based on a part of the sample that has been followed up using methane photometry and spectroscopy. Using methane differential photometry as a proxy for spectral type for T dwarfs has proved to be a very efficient technique. Of a subset of 45 methane selected brown dwarfs that were observed spectroscopically, 100 per cent were confirmed as T dwarfs. Future deep imaging surveys will produce large samples of faint brown dwarf candidates, for which spectroscopy will not be feasible. When broad wavelength coverage is unavailable, methane imaging offers a means to efficiently classify candidates from such surveys using just a pair of near-infrared images.

  13. Diamond Anniversary Lecture Series.

    ERIC Educational Resources Information Center

    Adams, Dewey A.; And Others

    This document contains the texts of four lectures that were presented as part of a series commemorating the 75th anniversary of Ohio State University's Department of Agricultural Education. The first lecture, "The Conceptualization Process and Vocational Education Management," (Dewey A. Adams) discusses a five-step management behavior approach for…

  14. Themes. Informal Education Series.

    ERIC Educational Resources Information Center

    Kessens, Rosanne

    Part of the larger Informal Education Series, this publication brings together many of the materials prepared by Rosanne Kessens for teachers and parents involved in Follow Through settings. Contents first explore theme development as an integrated approach to learning and then describe strategies for planning themes. Subsequent materials offer…

  15. Is methane a new therapeutic gas?

    PubMed Central

    2012-01-01

    Background Methane is an attractive fuel. Biologically, methanogens in the colon can use carbon dioxide and hydrogen to produce methane as a by-product. It was previously considered that methane is not utilized by humans. However, in a recent study, results demonstrated that methane could exert anti-inflammatory effects in a dog small intestinal ischemia-reperfusion model. Point of view Actually, the bioactivity of methane has been investigated in gastrointestinal diseases, but the exact mechanism underlying the anti-inflammatory effects is required to be further elucidated. Methane can cross the membrane and is easy to collect due to its abundance in natural gas. Although methane is flammable, saline rich in methane can be prepared for clinical use. These seem to be good news in application of methane as a therapeutic gas. Conclusion Several problems should be resolved before its wide application in clinical practice. PMID:23009320

  16. Methane and radioactive isotopes in submarine hydrothermal systems

    SciTech Connect

    Kim, K.R.

    1983-01-01

    This thesis consists of two parts: 1) methane and 2) radioactive isotopes, especially radon, in submarine hydrothermal systems. Both parts deal with the use of these gases as tracers for mapping hydrothermal vents at sea, and with their relationships to other sensitive tracers such as helium, manganese, and temperature. Hydrothermal methane was used as a real-time tracer for locating new submarine hydrothermal systems along spreading axes, discovering new hydrothermal systems at two locations in Pacific Ocean: 1) 20/sup 0/S on East Pacific Rise, and 2) Mariana Trough Back-arc Basin. Methane shows good correlations with helium-3 and temperature with similar ratios in various hydrothermal systems, 3 to 42 x 10/sup 6/ for the methane to helium-3 ratio, and 3 to 19 ..mu.. cc/kg/sup 0/C for the methane to temperature anomaly. These similar ratios from different areas provide evidence for chemical homogeneity of submarine hydrothermal waters. A good correlation between methane and manganese appears to be associated only with high-temperature hydrothermal systems. Radioisotopes in the vent waters of 21/sup 0/N high-temperature hydrothermal system have end-member concentrations of 7.5 to 40 dpm/kg for Ra-226, 360 dpm/kg for Rn 222, 62 dpm/kg for Pb-210, and 19 dpm/kg for Po-210. The radon activity for this system is one order of magnitude lower, and the Pb-210 activity is one order or magnitude higher, than those a the low temperature Galapagos system. All these observations suggest that the high radon, and low Pb-210 activity observed in Galapagos system may originate from the extensive subsurface mixing and water-rock interaction in this system (direct injection of radon and scavenging of Pb-210).

  17. The significance of methane ebullition

    NASA Astrophysics Data System (ADS)

    Walter, K.; Draluk, D. A.; Zimov, S. A.; Chapin, T.

    2003-12-01

    Ebullition is often the dominant pathway of methane release from aquatic ecosystems, yet it has seldom been carefully measured, due to heterogeneity in the spatial distribution and episodic release of gas bubbles. This likely results in an underestimation of total methane emission. We took advantage of ice formation over lake surfaces in NE Siberia to map patterns of ebullition. As ice forms in autumn, bubbles released from lake sediments are continually trapped under the ice at the water surface resulting in stacks of bubbles separated by thin films of ice called `koshkas'. Mapping the distribution of koshkas enabled us to identify `background' patterns of ebullition. In addition, we located `hot-spot' ebullition sites that remain permanently open throughout winter due to exceptionally high rates of methane bubbling. We used random and selective placement of underwater/ under-ice chambers to measure `background' and `hot-spot' fluxes annually. The combination of mapping and chamber measurements among different types of lakes and along lake margins varying in intensity of thermokarst erosion or aquatic plant growth enabled us to 1) improve estimates of total methane emissions from NE Siberian lakes, and to 2) identify landscape processes (thermokarst erosion vs. wetland mat formation) that enhance methane production and emission. Ignoring the contribution from hotspots, background ebullition comprised more than 75% of total methane emissions from lakes. From hotspot sites we measured up to 10-L m-2 of methane per day in early summer. Although hotspots comprised roughly 0.05% of the area along thermokarst margins, where they were most common, ebullition from hotspots contributed approximately 69% of the total ebullition flux. Including the flux from hotspots could increase estimates of CH4 ebullition from thermokarst margins 300%! Thermokarst lakes in Russia comprise a large proportion of the world's high latitude lakes; yet they are understudied. North Siberian

  18. Methane gas concentration in soils and ground water, Carbon and Emery Counties, Utah, 1995-2003

    USGS Publications Warehouse

    Stolp, B.J.; Burr, A.L.; Johnson, K.K.

    2006-01-01

    The release of methane gas from coal beds creates the potential for it to move into near-surface environments through natural and human-made pathways. To help ensure the safety of communities and determine the potential effects of development of coal-bed resources, methane gas concentrations in soils and ground water in Carbon and Emery Counties, Utah, were monitored from 1995 to 2003. A total of 420 samples were collected, which contained an average methane concentration of 2,740 parts per million by volume (ppmv) and a median concentration of less than 10 ppmv. On the basis of spatial and temporal methane concentration data collected during the monitoring period, there does not appear to be an obvious, widespread, or consistent migration of methane gas to the near-surface environment.

  19. Monitoring for methane gas in Carbon and Emery Counties, Utah, 1995-2003

    USGS Publications Warehouse

    Burr, Andrew L.; Stolp, Bernard J.; Johnson, Kevin K.; Hunt, Gilbert L.

    2006-01-01

    The release of methane gas from coal beds creates the potential for it to move into near-surface environments through natural and human-made pathways. To help ensure the safety of communities and determine the potential effects of development of coal-bed resources, methane gas concentrations in soils and ground water in Carbon and Emery Counties, Utah, were monitored from 1995 to 2003. A total of 420 samples were collected, which contained an average methane concentration of 2,740 parts per million by volume (ppmv) and a median concentration of less than 10 ppmv. On the basis of spatial and temporal methane concentration data collected during the monitoring period, there does not appear to be an obvious, widespread, or consistent migration of methane gas to the near-surface environment.

  20. Making methane visible

    NASA Astrophysics Data System (ADS)

    Gålfalk, Magnus; Olofsson, Göran; Crill, Patrick; Bastviken, David

    2016-04-01

    Methane (CH4) is one of the most important greenhouse gases, and an important energy carrier in biogas and natural gas. Its large-scale emission patterns have been unpredictable and the source and sink distributions are poorly constrained. Remote assessment of CH4 with high sensitivity at a m2 spatial resolution would allow detailed mapping of the near-ground distribution and anthropogenic sources in landscapes but has hitherto not been possible. Here we show that CH4 gradients can be imaged on the

  1. Modeling Modern Methane Emissions from Natural Wetlands. 2; Interannual Variations 1982-1993

    NASA Technical Reports Server (NTRS)

    Walter, Bernadette P.; Heimann, Martin; Mattews, Elaine; Hansen, James E. (Technical Monitor)

    2001-01-01

    A global run of a process-based methane model [Walter et al., this issue] is performed using high-frequency atmospheric forcing fields from ECMWF reanalyses of the period from 1982 to 1993. We calculate global annual methane emissions to be 260 Tg/ yr. 25% of methane emissions originate from wetlands north of 30 deg. N. Only 60% of the produced methane is emitted, while the rest is re-oxidized. A comparison of zonal integrals of simulated global wetland emissions and results obtained by an inverse modeling approach shows good agreement. In a test with data from two wetlands, the seasonality of simulated and observed methane emissions agrees well. The effects of sub-grid scale variations in model parameters and input data are examined. Modeled methane emissions show high regional, seasonal and interannual variability. Seasonal cycles of methane emissions are dominated by temperature in high latitude wetlands, and by changes in the water table in tropical wetlands. Sensitivity tests show that +/- 1 C changes in temperature lead to +/- 20 % changes in methane emissions from wetlands. Uniform changes of +/- 20% in precipitation alter methane emissions by about +/- 18%. Limitations in the model are analyzed. Simulated interannual variations in methane emissions from wetlands are compared to observed atmospheric growth rate anomalies. Our model simulation results suggest that contributions from other sources than wetlands and/or the sinks are more important in the tropics than north-of 30 deg. N. In higher northern latitudes, it seems that a large part, of the observed interannual variations can be explained by variations in wetland emissions. Our results also suggest that reduced wetland emissions played an important role in the observed negative methane growth rate anomaly in 1992.

  2. Methane Emission from Tropical Rivers

    NASA Astrophysics Data System (ADS)

    Sawakuchi, H. O.; Rasera, M. F. F. L.; Krusche, A. V.; Ballester, M. V. R.

    2012-04-01

    Inland water is already known as an important source of methane to atmosphere. Methane is produced in anaerobic environments usually find in lakes and floodplain bottom sediment. It is the main reason that almost all information regarding methane flux come from this environments. However, while floodplain dries during low water season reducing methanogenesis, rivers keep the capacity to emit methane throughout the year. Here we present preliminary results of CH4 flux measurements done in 6 large tropical rivers within the Amazon basin. We measured 17 areas using floating chamber during dry (low water) season, between September and November of 2011, in Amazon river mainstem, Araguaia, Xingu, Tapajós, Madeira, and Negro Rivers. Measured fluxes of all rivers ranged from 59.3 to 2974.4 mmol m-2 yr-1. Geomorphologic structure of channels is one important factor that contributes to this high heterogeneity due to development of low flow velocity depositional settings allowing formation of anoxic zones in rivers. Hydraulic and sediment barriers in the confluence of river channels promote the generation of natural dams which function as a trap for the suspension load favoring the deposition of organic rich muds. This kind of environment is very different from common river channels and has a stronger potential of methane emission. Average values of our flux measurements for this two river environments show that depositional areas can have much higher fluxes than the main channel, 1089.6 and 163.1 mmol m-2 yr-1, respectively. Hence, CH4 flux from these depositional zones is similar to some tropical floodplain lakes and reservoirs. Although the low flux from channel, the area covered by water is very large resulting in a significant contribution to the regional methane emission to the atmosphere. Moreover, mapping the area of these depositional river zones will give us a better idea of the magnitude of methane flux from tropical rivers.

  3. Unusually high stable carbon isotopic values of methane from low organic carbon Mars analog hypersaline environments

    NASA Astrophysics Data System (ADS)

    Kelley, C. A.; Poole, J. A.; Tazaz, A.; Chanton, J.; Bebout, B.

    2010-12-01

    Motivated by the Mars rovers’ findings of past hypersaline environments and the discovery of methane in the atmosphere of Mars, we examined methanogenesis in hypersaline ponds in Baja California Sur and in the Don Edwards National Wildlife Refuge in northern California. Methane-rich bubbles were observed to be released from below gypsum/halite crusts in these environments. The stable carbon isotopic composition of these bubbles ranged from about -30 to -40 ‰. Methane with these relatively high isotopic values would typically be considered non-biogenic, however incubations of crust and sediments samples over time resulted in the production of methane. We therefore undertook a series of measurements aimed at understanding the isotopic composition of methane in these environments. The concentrations and isotopic composition of the particulate organic carbon (POC) in these environments were measured. POC content was low (relative to most methane-producing sedimentary environments), generally less than 1%, and always less than 2% of the total mass. The isotopic composition of the POC ranged from -13 to -22 ‰. To determine the substrates used by the methanogens, 13C-labeled trimethylamine (TMA), monomethylamine, methanol, acetate and bicarbonate were added to incubation vials and the methane produced was monitored for 13C content. The main substrates used by the methanogens in these hypersaline environments were the non-competitive substrates, the methylamines and methanol. When unlabeled, but isotopically known, TMA was added to incubation vials in varying concentrations, the isotopic composition of the methane produced also varied. Little, if any, difference in the isotopic composition between the TMA and methane occurred at the lowest TMA concentration (10 µM final concentration). The lowest methane δ13C values (and so greatest fractionation between methane and TMA) occurred when the most TMA was added (1000 µM final concentration). This change in the

  4. Transport of Methane in Trees

    NASA Astrophysics Data System (ADS)

    Kutschera, E.; Khalil, A. K.; Shearer, M. J.; Rosenstiel, T.; Rice, A. L.

    2011-12-01

    Although overall methane (CH4) emissions for croplands, wetlands, and forests have been measured, the exact dynamics of CH4 transport through trees is not well understood. What roles transport mechanisms play in emission rates has been thoroughly investigated for rice, but is fairly unknown for trees. Better defined plant transport mechanisms yield more accurate determination of greenhouse gas flux and its variations, contributing to a comprehensive theory quantifying greenhouse gas emissions globally. CH4 emissions from the common wetland tree species black cottonwood (Populus trichocarpa) native to the Pacific Northwest have been measured under hydroponic conditions in order to separate plant transport processes from the influence of soil processes. Canopy emissions of CH4 have been measured via canopy enclosure. Measurements of CH4 flux from each of 16 trees have indicated that emissions are normally constant over the half-hour sampling period. Samples for stable carbon isotope composition have been taken during these experiments and measured on a mass spectrometer. Compared to the isotopic composition of root water CH4, canopy CH4 is depleted in 13C; this indicates that CH4 moving through the tree is not following a bulk flow pathway (where no depletion would occur), but instead moves either diffusively or through other cell or tissue barriers. No correlation was found to exist between leaf area and CH4 emission; this is vital to upscaling tree-level emissions to the global scale since leaf area index (LAI) cannot be treated as an appropriate parameter to upscale flux. Correctly informing global-scale CH4 fluxes from plants requires an association between the role plant physiology plays in the production and transport of CH4 and magnitudes of flux. This research was supported by the Office of Science (BER), U. S. Department of Energy, Grant No. DE-FG02-08ER64515. Supported in part through NASA / Oregon Space Grant Consortium, grant NNG05GJ85H.

  5. Assiniboine Series.

    ERIC Educational Resources Information Center

    Allen, Minerva

    This series of illustrated booklets presents 13 Indian stories in a bilingual format of English and Assiniboine, an Indian tribal language. Written on the first grade level, the stories have the following titles: (1) "Orange Tree in Lodgepole"; (2) "Pretty Flower"; (3) Inktomi and the Rock"; (4) "Inktomi and the…

  6. High Time Resolution Measurements of Methane Fluxes From Enteric Fermentation in Cattle Rumen

    NASA Astrophysics Data System (ADS)

    Floerchinger, C. R.; Herndon, S.; Fortner, E.; Roscioli, J. R.; Kolb, C. E.; Knighton, W. B.; Molina, L. T.; Zavala, M.; Castelán, O.; Ku Vera, J.; Castillo, E.

    2013-12-01

    Methane accounts for roughly 20% of the global radiative climate forcing in the last two and a half centuries. Methane emissions arise from a number of anthropogenic and biogenic sources. In some areas enteric fermentation in livestock produces over 90% of agricultural methane. In the spring of 2013, as a part of the Short Lived Climate Forcer-Mexico field campaign, the Aerodyne Mobile Laboratory in partnership with the Molina Center for the Environment studied methane production associated with enteric fermentation in the rumen of cattle. A variety of different breeds and stocks being raised in two agricultural and veterinary research facilities located in different areas of Mexico were examined. Methane fluxes were quantified using two methods: 1) an atmospherically stable gaseous tracer release was collocated with small herds in a pasture, allowing tracer ratio flux measurements; 2) respiratory CO2 was measured in tandem with methane in the breath of individual animals allowing methane production to be related to metabolism. The use of an extensive suite of very high time response instruments allows for differentiation of individual methane producing rumination events and respiratory CO2 from possible background interferences. The results of these studies will be presented and compared to data from traditional chamber experiments.

  7. Methane adsorption on the surface of a model of shale: A density functional theory study

    NASA Astrophysics Data System (ADS)

    Zhu, Yuan-qiang; Su, Hong; Jing, Ya; Guo, Jianchun; Tang, Junlei

    2016-11-01

    As a model of shale, one part of polycyclic aromatic ring was used to represent the kerogen surface with the structural heterogeneity. The adsorption mechanisms of methane on the surface of the kerogen were investigated by M06-2× functional with D3 dispersion correction. Nine stable adsorption sites and the orientations of methane (CH4) on the surface of the kerogen were systematically considered. Information from different methods lead to the same conclusion that methane prefers to be adsorbed on the sites directly above the carbon atoms of the kerogen rather than above the center of the six-membered rings. The interactions between methane and the surface of the kerogen are the van der Waals interactions. The interaction energies with the basis set superposition error (BSSE) corrections are around 14 kJ mol-1 at the M06-2×-D3/Jun-cc-pVDZ level. The RDG scatter graphs and the RDG gradient isosurface further illustrate that the interactions between methane and the surface of the kerogen belong to the van der Waals interactions. The weak interactions indicate that the adsorption of methane on the surface of the kerogen is physical adsorption and it slightly depends upon the adsorption sites on kerogen as well as the orientations of methane. These results are helpful for the understanding of the microcosmic mechanism of methane-shale interactions and for the exploitation of shale gas.

  8. Isotopic constraints on sources of methane in Los Angeles, California, USA (Invited)

    NASA Astrophysics Data System (ADS)

    Townsend-Small, A.; Tyler, S. C.; Christensen, L.; Xu, X.; Pataki, D. E.

    2009-12-01

    Methane is a powerful greenhouse gas and an important contributor to global warming. Recent studies have suggested that methane emissions in large cities are underestimated with several models even indicating that substantial emissions attributed to cities are in part from regional and/or encroaching agricultural sources rather than from urban fossil fuel sources. We have found that stable isotopes (13-C and D) and radiocarbon (C-14) are excellent tracers of various sources of methane in Los Angeles, California. Measurements of the d13C and dD of methane from discrete sources show excellent separation between urban sources, such as vehicle emissions, power plants, oil refineries, landfills, and sewage treatment plants and agricultural sources like cows, biogas, and cattle feedlots. In addition, radiocarbon is an excellent tracer of modern versus fossil fuel contributions to methane emissions in the region. Preliminary measurements of background air in Los Angeles indicate that the major source of excess methane is vehicle emissions with most additional CH4 likely contributed from among other fossil fuel sources such as oil refining or power plants. We are currently confirming these results with broader field campaigns and additional measurements, including continuous measurements of atmospheric methane concentration using tunable laser spectroscopy. The combination of high-resolution tunable laser concentration measurements and precise isotope measurements using mass spectrometry is a very promising and powerful tool for methane source monitoring.

  9. Iron-mediated anaerobic oxidation of methane in brackish coastal sediments.

    PubMed

    Egger, Matthias; Rasigraf, Olivia; Sapart, Célia J; Jilbert, Tom; Jetten, Mike S M; Röckmann, Thomas; van der Veen, Carina; Bândă, Narcisa; Kartal, Boran; Ettwig, Katharina F; Slomp, Caroline P

    2015-01-06

    Methane is a powerful greenhouse gas and its biological conversion in marine sediments, largely controlled by anaerobic oxidation of methane (AOM), is a crucial part of the global carbon cycle. However, little is known about the role of iron oxides as an oxidant for AOM. Here we provide the first field evidence for iron-dependent AOM in brackish coastal surface sediments and show that methane produced in Bothnian Sea sediments is oxidized in distinct zones of iron- and sulfate-dependent AOM. At our study site, anthropogenic eutrophication over recent decades has led to an upward migration of the sulfate/methane transition zone in the sediment. Abundant iron oxides and high dissolved ferrous iron indicate iron reduction in the methanogenic sediments below the newly established sulfate/methane transition. Laboratory incubation studies of these sediments strongly suggest that the in situ microbial community is capable of linking methane oxidation to iron oxide reduction. Eutrophication of coastal environments may therefore create geochemical conditions favorable for iron-mediated AOM and thus increase the relevance of iron-dependent methane oxidation in the future. Besides its role in mitigating methane emissions, iron-dependent AOM strongly impacts sedimentary iron cycling and related biogeochemical processes through the reduction of large quantities of iron oxides.

  10. Aerobic and anaerobic methane oxidation in terrestrial mud volcanoes in the Northern Apennines

    NASA Astrophysics Data System (ADS)

    Wrede, C.; Brady, S.; Rockstroh, S.; Dreier, A.; Kokoschka, S.; Heinzelmann, S. M.; Heller, C.; Reitner, J.; Taviani, M.; Daniel, R.; Hoppert, M.

    2012-07-01

    Methane oxidizing prokaryotes are ubiquitous in oxic and anoxic habitats wherever C1-compounds are present. Thus, methane saturated mud volcano fluids should be a preferred habitat of methane consuming prokaryotes, using the readily available electron donors. In order to understand the relevance of methane as a carbon and energy source in mud volcano communities, we investigate the diversity of prokaryotic organisms involved in oxidation of methane in fluid samples from the Salse di Nirano mud volcano field situated in the Northern Apennines. Cell counts were at approximately 0.7 × 106 microbial cells/ml. A fraction of the microbial biomass was identified as ANME (anaerobic methanotroph) archaea by fluorescence in situ hybridization (FISH) analysis. They are associated in densely colonized flakes, of some tens of μm in diameter, embedded in a hyaline matrix. Diversity analysis based on the 16S rDNA genes, retrieved from amplified and cloned environmental DNA, revealed a high proportion of archaea, involved in anaerobic oxidation of methane (AOM). Aerobic methane-oxidizing proteobacteria could be highly enriched from mud volcano fluids, indicating the presence of aerobic methanotrophic bacteria, which may contribute to methane oxidation, whenever oxygen is readily available. The results imply that biofilms, dominated by ANME archaea, colonize parts of the mud volcano venting system.

  11. Internal methane transport through Juncus effusus: experimental manipulation of morphological barriers to test above- and below-ground diffusion limitation.

    PubMed

    Henneberg, Anders; Sorrell, Brian K; Brix, Hans

    2012-11-01

    Aerenchymatous plants can transport methane (CH(4) ) from the root zone to the atmosphere, bypassing the surface-oxidizing layers of the soil, yet morphological and anatomical factors that govern the transport of methane have rarely been critically tested in manipulative experiments. Here, we investigated the methane transport capacity of hydroponically grown Juncus effusus, in experiments with roots submerged in nutrient solutions sparged with methane (1.16 mmol CH(4) l(-1)). Through a range of manipulations of the above- and below-ground plant parts, we tested the contradictory claims in the literature regarding which sites provide the greatest resistance to gas transport. Root manipulations had the greatest effect on methane transport. Removing root material reduced methane transport significantly, and especially the lateral roots and the root tips were important. Cutting of the shoots, with or without subsequent sealing, did not alter methane transport significantly. We confirm modelling predictions that the limiting factor for methane transport in the tussock forming wetland graminoid, J. effusus, is the amount of permeable root surface, estimated using the proxy measurement of root length. The aerial tissues do not provide any significant resistance to methane transport, and the methane is emitted from the lower 50 mm of the shoots.

  12. Measurements of the methane relaxation times for application to the infrared emission models of the upper atmospheres of outer planets and Titan

    NASA Technical Reports Server (NTRS)

    Halthore, Rangasayi N.; Caldwell, John J.; Allen, John E., Jr.; Burt, Jim A.; Yang, Kuanghua; Delaney, Paul

    1990-01-01

    The 7.8 micrometer emission from the nu(sub 4) band of methane (CH4) is a regularly observed feature in the stratosphere of all the giant planets and Titan. On Jupiter, enhancements in this emission are associated with the infrared hot spots in the auroral zone. Attempts to model this phenomenon in particular, and to understand the role of methane in general, have been hampered in part by a lack of adequate laboratory measurements of the collisional relaxation times for the nu(sub 3) and nu(sub 4) levels over the appropriate temperature range. To provide this needed data, a series of laboratory experiments were initiated. In the experimental arrangement the nu(sub3) band of methane is pumped at 3.3 micrometers using a pulsed infrared source (Nd:YAG/dye laser system equipped with a wave-length extender). The radiative lifetime of the nu(sub 3) level (approximately 37 ms) is much shorter than the nu(sub 4) lifetime (approximately 390 ms); however, a rapid V-V energy transfer rate ensures that the nu(sub 4) level is substantially populated. The photoacoustic technique is used to acquire relaxation rate information. The experiments are performed using a low-temperature, low-pressure cell. Experimental apparatus and technique are described. In addition some of the experimental difficulties associated with making these measurements are discussed and some preliminary results are presented.

  13. River methane hot-spots: Continuous methane ebullition measurements over an annual cycle linked to river sediment production

    NASA Astrophysics Data System (ADS)

    Wilkinson, Jeremy; Maeck, Andreas; Ashboul, Zeyad; Lorke, Andreas

    2015-04-01

    Hot spot methane ebullition from impounded river reaches matches high rates observed around the globe. Ebullition dominates total methane flux in the Saar River (Germany) and is largely determined by sediment deposition rate. Using automated bubble traps developed in-house, and deployed over a year at four sites, we collected high resolution data showing that hydrodynamic disturbances from shipping, lock operations and hydrograph events trigger ebullition episodes. Reverse smoothing was used to integrate the observed ebullition back in time, and helped in visualizing the data, and provides a time-series closer to methane accumulation in the sediments, whereas ebullition shows the triggering and release of the accumulated gas. One major hydrological disturbance of shallow-water sediment released around 13% of the total annual ebullition at that site, and ebullition generally followed the seasonal sediment temperature variations. The same event damped ebullition from deeper water sites. Total annual ebullition values ranged from 200 to 500 gCH4 m-2 yr-1. Ebullition from shallow water sediments in winter ceased for extended periods, but continued un-broken from deeper sites. With on-going measurements we believe these findings will help to improve estimates and the modelling of methane emissions from impounded river systems.

  14. A large increase in U.S. methane emissions over the past decade inferred from satellite data and surface observations

    NASA Astrophysics Data System (ADS)

    Turner, A. J.; Jacob, D. J.; Benmergui, J.; Wofsy, S. C.; Maasakkers, J. D.; Butz, A.; Hasekamp, O.; Biraud, S. C.

    2016-03-01

    The global burden of atmospheric methane has been increasing over the past decade, but the causes are not well understood. National inventory estimates from the U.S. Environmental Protection Agency indicate no significant trend in U.S. anthropogenic methane emissions from 2002 to present. Here we use satellite retrievals and surface observations of atmospheric methane to suggest that U.S. methane emissions have increased by more than 30% over the 2002-2014 period. The trend is largest in the central part of the country, but we cannot readily attribute it to any specific source type. This large increase in U.S. methane emissions could account for 30-60% of the global growth of atmospheric methane seen in the past decade.

  15. Real-Time Measurements of Ethane for Source Attribution of Methane Plumes from Oil and Gas Facilities

    NASA Astrophysics Data System (ADS)

    Yacovitch, T. I.; Floerchinger, C.; Roscioli, J. R.; Herndon, S.; Fortner, E.; Knighton, W. B.; Petron, G.; Sweeney, C.; Karion, A.; Kofler, J.; Iglesias, G.; Zavala, M. A.; Molina, L. T.

    2013-12-01

    The Aerodyne Mobile Lab has conducted several recent studies of the methane emissions from Oil and Gas facilities at varying stages of production: well-heads; processing facilities; and compressor stations. Accurate quantification of methane emission rates are can be complicated by other local sources, notably livestock and microbial production. Methane emissions from oil and gas facilities are always accompanied by small amounts of ethane, while biogenic plumes contain no ethane. A prototype ethane spectrometer based on the Aerodyne-Mini chassis, has been deployed to oil and gas facilities in the Veracruz region of Mexico, as part of the 2013 Short-Lived Climate-Forcing project, and during ground-based measurements in the Barnett Shale in Texas as part of the Barnett Oil and Gas Observation Study. These results suggest a source-dependence in the ethane-to-methane ratio in oil and gas emissions. The results will be contrasted with 13CH4 methane isotope ratios determined using Aerodyne's Methane-Dual instrument. The limits and advantages of ethane-methane ratios and methane isotopes will be discussed. In the current instrumentation, the precision of determined ethane-to-methane ratios in a single plume encounter exceeds the analogous carbon isotope quantification.

  16. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.703 Methane (LNG). Unless a cargo tank carrying methane (LNG)...

  17. Hello, Water -- Good-bye, Methane

    NASA Video Gallery

    An animation shows carbon, hydrogen and oxygen atoms. Two hydrogen atoms join each oxygen atom to make water, or H2O. Four hydrogen atoms join a carbon atom to make methane, or CH4. The methane the...

  18. Past methane seepage and linked deep-water anoxia are logged in methane-derived carbonates

    NASA Astrophysics Data System (ADS)

    Stadnitskaia, A.; Liebetrau, V.; Eisenhauer, A.; Sinninghe Damsté, J. S.

    2012-04-01

    The precipitation of carbonate in methane saturated environments is a common phenomenon that is caused by the increase of alkalinity due to the microbial process of anaerobic oxidation of methane (AOM) accomplished by a consortium of sulfate reducing bacteria and methanotrophic archaea (Boetius et al., 2000). Since the formation of such carbonates is irrespective to climate changes and to the depth of the carbonate compensation, they represent unique archives of the time and duration of methane seepage, adjacent sedimentary/water column environments and associated bionetwork. The Nile Deep Sea Fan basin is known for the widespread occurrence of seabed methane/fluid seepage linked to mud volcanoes and pock marks. Massive accumulations of methane-derived carbonate pavements and up to one meter buildups were often encountered in the vicinity or even within mud volcano structures. Here we analyzed at high resolution the differences in stable carbon and oxygen isotope compositions and lipid biomarker composition, accompanied with U/Th dating of the topmost part of a ~1 m-high carbonate edifice sited at the margin of the Amon mud volcano. The uppermost part of the edifice has been dated at ~7.8 - 9.1 kyr B.P. This is synchronous with the increase of fresh-water fluxes in the Eastern Mediterranean resulting in density stratification of the water column (~ 10.5 - 5.0 14C kyr B.P.), with the formation of S1 sapropel (~9.7 - 5.7 14C kyr B.P.; De Lange et al., 2008), and with the Holocene warm climatic optimum (Rohling and Hilgen, 1991). Significant changes of ^13CCaCO3 values, from -32 to -9‰ (VPDB), indicate swings in methane flux, which affected rates of AOM and the consequent production of 13C-depleted HCO3-. Lipid biomarkers revealed the presence of methanotrophic archaea of the ANME-2 group due to the dominance of sn-2-hydroxyarchaeol over archaeol and the low abundance of tetraether lipids (Blumenberg et al., 2004). Ecologically these archaea are associated with

  19. [Advances in biomolecular machine: methane monooxygenases].

    PubMed

    Lu, Jixue; Wang, Shizhen; Fang, Baishan

    2015-07-01

    Methane monooxygenases (MMO), regarded as "an amazing biomolecular machine", catalyze the oxidation of methane to methanol under aerobic conditions. MMO catalyze the oxidation of methane elaborately, which is a novel way to catalyze methane to methanol. Furthermore, MMO can inspire the biomolecular machine design. In this review, we introduced MMO including structure, gene and catalytic mechanism. The history and the taxonomy of MMO were also introduced.

  20. Method for the photocatalytic conversion of methane

    DOEpatents

    Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

    1998-02-24

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

  1. Method for the photocatalytic conversion of methane

    DOEpatents

    Noceti, Richard P.; Taylor, Charles E.; D'Este, Joseph R.

    1998-01-01

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

  2. Fisk's Follies... Part III of a Series

    ERIC Educational Resources Information Center

    Fisk, William J.

    1975-01-01

    Suggests using a bicycle road rally in the teaching of kinematics and presents a list of suggestions for running the rally. Suggests a ski trip and instruction in the physics of skiing to create student awareness of physics relevance. (GS)

  3. Improving dust and methane control

    SciTech Connect

    Cecala, A.; Organiscak, J.; Jankowski, R.

    1987-10-01

    The Bureau of Mines has evaluated a number of techniques for controlling dust and methane during the headgate cutout of retreating longwall sections that use antitropal ventilation (headgate to tailgate). Some of these techniques are effective for both methane and dust control, while others are effective for only one or the other. The techniques include the gob curtain, the walkway curtain, stageloader-crusher control and the wing curtain. Each improves the health and safety of workers and is economically feasible in hardware cost, setup cost and maintenance.

  4. Improving dust and methane control

    SciTech Connect

    Cecala, A.; Organiseak, J.; Jankowski, R.

    1987-01-01

    This paper presents a number of techniques for controlling dust and methane during the headgate cutout of retreating longwall sections that use antitropal ventilation (headgate to tailgate). Some of these techniques are effective for both methane and dust control, while others are effective for only one or the other. The techniques include the gob curtain, the walkway curtain, stage-loader-crusher control, and the wing curtain. Each improves the health and safety of workers and is economically feasible in hardware cost, setup cost, and maintenance.

  5. Coalbed methane production case histories

    SciTech Connect

    Not Available

    1981-02-01

    The production of methane gas from coal and coal-bearing rocks is one of the prime objectives of the Department of Energy's Methane Recovery from Coalbeds Project. This report contains brief description of wells that are presently producing gas from coal or coal-bearing rocks. Data from three gob gas production areas in Illinois, an in-mine horizontal borehole degasification, and eleven vertical boreholes are presented. Production charts and electric logs of the producing zones are included for some of the wells. Additional information on dry gas production from the San Juan Basin, Colorado/New Mexico and the Greater Green River Coal Region, Colorado/Wyoming is also included.

  6. Methane emissions from MBT landfills.

    PubMed

    Heyer, K-U; Hupe, K; Stegmann, R

    2013-09-01

    Within the scope of an investigation for the German Federal Environment Agency ("Umweltbundesamt"), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 18-24 m(3)CH(4)/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH(4)/(m(2)h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD) model of the IPCC Guidelines for National Greenhouse Gas Inventories, 2006, was used to estimate the methane emissions from MBT landfills. Due to the calculation made by the authors emissions in the range of 60,000-135,000 t CO(2-eq.)/a for all German MBT landfills can be expected. This wide range shows the uncertainties when the here used procedure and the limited available data are applied

  7. Is there methane on Mars?

    NASA Astrophysics Data System (ADS)

    Zahnle, Kevin; Freedman, Richard S.; Catling, David C.

    2011-04-01

    There have been several reports of methane on Mars at the 10-60 ppbv level. Most suggest that methane is both seasonally and latitudinally variable. Here we review why variable methane on Mars is physically and chemically implausible, and then we critically review the published reports. There is no known mechanism for destroying methane chemically on Mars. But if there is one, methane oxidation would deplete the O 2 in Mars's atmosphere in less than 10,000 years unless balanced by an equally large unknown source of oxidizing power. Physical sequestration does not raise these questions, but adsorption in the regolith or condensation in clathrates ignore competition for adsorption sites or are inconsistent with clathrate stability, respectively. Furthermore, any mechanism that relies on methane's van der Waals' attraction is inconsistent with the continued presence of Xe in the atmosphere at the 60 ppbv level. We then use the HITRAN database and transmission calculations to identify and characterize the absorption lines that would be present on Earth or Mars at the wavelengths of the published observations. These reveal strong competing telluric absorption that is most problematic at just those wavelengths where methane's signature seems most clearly seen from Earth. The competing telluric lines must be removed with models. The best case for martian methane was made for the 12CH 4ν3 R0 and R1 lines seen in blueshift when Mars was approaching Earth in early 2003 (Mumma, M.J., Villanueva, G.L., Novak, R.E., Hewagama, T., Bonev, B.P., DiSanti, M.A., Mandell, A.M., Smith, M.D. [2009]. Science 323, 1041-1045). For these the Doppler shift moves the two martian lines into near coincidence with telluric 13CH 4ν3 R1 and R2 lines that are 10-50× stronger than the inferred martian lines. By contrast, the 12CH 4ν3 R0 and R1 lines when observed in redshift do not contend with telluric 13CH 4. For these lines, Mumma et al.'s observations and analyses are consistent with an

  8. APPROACH FOR ESTIMATING GLOBAL LANDFILL METHANE EMISSIONS

    EPA Science Inventory

    The report is an overview of available country-specific data and modeling approaches for estimating global landfill methane. Current estimates of global landfill methane indicate that landfills account for between 4 and 15% of the global methane budget. The report describes an ap...

  9. Terminating marine methane bubbles by superhydrophobic sponges.

    PubMed

    Chen, Xiao; Wu, Yuchen; Su, Bin; Wang, Jingming; Song, Yanlin; Jiang, Lei

    2012-11-14

    Marine methane bubbles are absorbed, steadily stored, and continuously transported based on the employment of superhydrophobic sponges. Antiwetting sponges are water-repellent in the atmosphere and absorb gas bubbles under water. Their capacity to store methane bubbles increases with enhanced submerged depth. Significantly, trapped methane bubbles can be continuously transported driven by differential pressure.

  10. 40 CFR 721.4820 - Methane, bromodifluoro-.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Methane, bromodifluoro-. 721.4820... Substances § 721.4820 Methane, bromodifluoro-. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as methane, bromodifluoro- is subject to reporting...

  11. 30 CFR 75.342 - Methane monitors.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Methane monitors. 75.342 Section 75.342 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.342 Methane monitors. (a)(1) MSHA approved methane monitors shall be installed on all face cutting machines, continuous miners, longwall...

  12. Methane Emissions from Rice Fields - Final Report

    SciTech Connect

    Khalil, M. Aslam; Rasmussen,Reinhold A.

    2002-12-03

    Methane (Ch4) is a greenhouse gas regarded second only to carbon dioxide in its ability to cause global warming. Methane is important because of its relatively fast increase, and also because it is, per molecule, some 60 times more effective than carbon dioxide in causing global warming. The largest present anthropogenic sources of methane are rice fields, cattle and biomass burning.

  13. 30 CFR 75.342 - Methane monitors.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Methane monitors. 75.342 Section 75.342 Mineral... SAFETY STANDARDS-UNDERGROUND COAL MINES Ventilation § 75.342 Methane monitors. (a)(1) MSHA approved methane monitors shall be installed on all face cutting machines, continuous miners, longwall...

  14. 78 FR 26337 - Methane Hydrate Advisory Committee

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-06

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... Meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. The Federal... of the Methane Hydrate Advisory Committee is to provide advice on potential applications of...

  15. 78 FR 37536 - Methane Hydrate Advisory Committee

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-21

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. The Federal... of the Methane Hydrate Advisory Committee is to provide advice on potential applications of...

  16. Are methane production and cattle performance related?

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Methane is a product of fermentation of feed in ruminant animals. Approximately 2 -12% of the gross energy consumed by cattle is released through enteric methane production. There are three primary components that contribute to the enteric methane footprint of an animal. Those components are dry ...

  17. 76 FR 59667 - Methane Hydrate Advisory Committee

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-27

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Methane... Meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. Federal... of the Committee: The purpose of the Methane Hydrate Advisory Committee is to provide advice...

  18. 77 FR 40032 - Methane Hydrate Advisory Committee

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-06

    ... Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee.... SUPPLEMENTARY INFORMATION: Purpose of the Committee: The purpose of the Methane Hydrate Advisory Committee is...

  19. 40 CFR 721.4820 - Methane, bromodifluoro-.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Methane, bromodifluoro-. 721.4820... Substances § 721.4820 Methane, bromodifluoro-. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as methane, bromodifluoro- is subject to reporting...

  20. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR... and Temperature Control § 154.703 Methane (LNG). Unless a cargo tank carrying methane (LNG)...

  1. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR... and Temperature Control § 154.703 Methane (LNG). Unless a cargo tank carrying methane (LNG)...

  2. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR... and Temperature Control § 154.703 Methane (LNG). Unless a cargo tank carrying methane (LNG)...

  3. 46 CFR 154.703 - Methane (LNG).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Methane (LNG). 154.703 Section 154.703 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR... and Temperature Control § 154.703 Methane (LNG). Unless a cargo tank carrying methane (LNG)...

  4. Evaluating Bay Area Methane Emission Inventory

    SciTech Connect

    Fischer, Marc; Jeong, Seongeun

    2016-03-01

    As a regulatory agency, evaluating and improving estimates of methane (CH4) emissions from the San Francisco Bay Area is an area of interest to the Bay Area Air Quality Management District (BAAQMD). Currently, regional, state, and federal agencies generally estimate methane emissions using bottom-up inventory methods that rely on a combination of activity data, emission factors, biogeochemical models and other information. Recent atmospheric top-down measurement estimates of methane emissions for the US as a whole (e.g., Miller et al., 2013) and in California (e.g., Jeong et al., 2013; Peischl et al., 2013) have shown inventories underestimate total methane emissions by ~ 50% in many areas of California, including the SF Bay Area (Fairley and Fischer, 2015). The goal of this research is to provide information to help improve methane emission estimates for the San Francisco Bay Area. The research effort builds upon our previous work that produced methane emission maps for each of the major source sectors as part of the California Greenhouse Gas Emissions Measurement (CALGEM) project (http://calgem.lbl.gov/prior_emission.html; Jeong et al., 2012; Jeong et al., 2013; Jeong et al., 2014). Working with BAAQMD, we evaluate the existing inventory in light of recently published literature and revise the CALGEM CH4 emission maps to provide better specificity for BAAQMD. We also suggest further research that will improve emission estimates. To accomplish the goals, we reviewed the current BAAQMD inventory, and compared its method with those from the state inventory from the California Air Resources Board (CARB), the CALGEM inventory, and recent published literature. We also updated activity data (e.g., livestock statistics) to reflect recent changes and to better represent spatial information. Then, we produced spatially explicit CH4 emission estimates on the 1-km modeling grid used by BAAQMD. We present the detailed activity data, methods and derived emission maps by sector

  5. Use of the HadGEM2 climate-chemistry model to investigate interannual variability in methane sources

    NASA Astrophysics Data System (ADS)

    Hayman, Garry; O'Connor, Fiona; Clark, Douglas; Huntingford, Chris; Gedney, Nicola

    2013-04-01

    emission totals for the different years and source sectors using sector and species-specific scaling factors based on the annual trends given in various EDGAR time series: (a) version 4.2 for all species (except NMVOCs) and version 4.1 for NMVOCs; (b) v3.2. This approach was also applied to the emissions from aviation (only for oxides of nitrogen) and international shipping. Biomass burning: Month-specific emission inventories are available from the Global Fire Emissions Database (GFED, v3.1) for the years 1997 to 2009 [7]. The emissions were rescaled to give the same decadal mean as used in the Hadley Centre's earlier HadGEM2 runs (25 Tg CH4 per annum). Other: Sources such as termites and hydrates for methane were taken from the GEIA website and the dataset of Fung et al. [8]. The datasets contain a single annual cycle, which was assumed to apply for all years. For CH4, there are also emissions from wetlands. These were either based on the dataset of Fung et al. [8] or derived from the JULES (Joint UK Land Earth Simulator) land surface model [9, 10]. The standard version of JULES uses a simple methane wetland emission parameterization, developed and tested by [11] for use at large spatial scales. The surface concentrations from the different model runs have been compared to surface atmospheric CH4 measurements. In addition, growth rates have been derived. These comparisons will be reported and used to assess the contribution of different methane sources to the interannual variations in the methane growth rate. References [1] Dlugokencky, E.J., et al.: Global atmospheric methane: budget, changes and dangers. Philosophical Transactions of the Royal Society A, 369, 2058-2072; doi: 10.1098/rsta.2010.0341, 2011. [2] Forster, P., et al.: Changes in Atmospheric Constituents and in Radiative Forcing. In: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change [Solomon, S., D

  6. Landscape-level terrestrial methane flux observed from a very tall tower

    USGS Publications Warehouse

    Desai, Ankur R.; Xu, Ke; Tian, Hanqin; Weishampel, Peter; Thom, Jonthan; Baumann, Daniel D.; Andrews, Arlyn E.; Cook, Bruce D.; King, Jennifer Y.; Kolka, Randall

    2015-01-01

    -term (sub-weekly) variability. Temperature was found to be a stronger driver of regional CH4flux than moisture availability or net ecosystem production at the daily to monthly scale. Taken together, these results emphasize the multi-timescale dependence of drivers of regional methane flux and the importance of long, continuous time series for their characterization.

  7. Methane fluxes above the Hainich forest by True Eddy Accumulation and Eddy Covariance

    NASA Astrophysics Data System (ADS)

    Siebicke, Lukas; Gentsch, Lydia; Knohl, Alexander

    2016-04-01

    , based on preliminary evidence, that the Hainich forest acted as a moderate net sink for methane during the investigation. This supports earlier findings from chamber measurements at the Hainich forest site and is similar to findings from other forest sites. Our observations will be continued through 2016 and beyond to provide longer-term methane flux time series spanning entire seasons. However, the current data set already provides a basis for further consolidating methods of measurements and analysis of turbulent methane fluxes using eddy covariance and true eddy accumulation.

  8. Methane oxidation and methane fluxes in the ocean surface layer and deep anoxic waters

    NASA Technical Reports Server (NTRS)

    Ward, B. B.; Kilpatrick, K. A.; Novelli, P. C.; Scranton, M. I.

    1987-01-01

    Measured biological oxidation rates of methane in near-surface waters of the Cariaco Basin are compared with the diffusional fluxes computed from concentration gradients of methane in the surface layer. Methane fluxes and oxidation rates were investigated in surface waters, at the oxic/anoxic interface, and in deep anoxic waters. It is shown that the surface-waters oxidation of methane is a mechanism which modulates the flux of methane from marine waters to the atmosphere.

  9. Effect of Propellant Flowrate and Purity on Carbon Deposition in LO2/Methane Gas Generators

    NASA Technical Reports Server (NTRS)

    Bossard, J. A.; Burkhardt, W. M.; Niiya, K. Y.; Braam, F.

    1989-01-01

    The generation and deposition of carbon was studied in the Carbon Deposition Program using subscale hardware with LO2/Liquid Natural Gas (LNG) and LO2/Methane propellants at low mixture ratios. The purpose of the testing was to evaluate the effect of methane purity and full scale injection density on carbon deposition. The LO2/LNG gas generator/preburner testing was performed at mixture ratios between 0.24 and 0.58 and chamber pressures from 5.8 to 9.4 MPa (840 to 1370 psia). A total of seven 200 second duration tests were performed. The LNG testing occurred at low injection densities, similar to the previous LO2/RP-1, LO2/propane, and LO2/methane testing performed on the carbon deposition program. The current LO2/methane test series occurred at an injection density factor of approximately 10 times higher than the previous testing. The high injection density LO2/methane testing was performed at mixture ratios between from 0.23 to 0.81 and chamber pressures from 6.4 to 15.2 MPa (925 to 2210 psia). A total of nine high injection density tests were performed. The testing performed demonstrated that low purity methane (LNG) did not produce any detectable change in carbon deposition when compared to pure methane. In addition, the C* performance and the combustion gas temperatures measured were similar to those obtained for pure methane. Similar results were obtained testing pure methane at higher propellant injection densities with coarse injector elements.

  10. Catalyst for the methanation of carbon monoxide in sour gas

    DOEpatents

    Kustes, William A.; Hausberger, Arthur L.

    1985-01-01

    The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

  11. Global health benefits of mitigating ozone pollution with methane emission controls.

    PubMed

    West, J Jason; Fiore, Arlene M; Horowitz, Larry W; Mauzerall, Denise L

    2006-03-14

    Methane (CH(4)) contributes to the growing global background concentration of tropospheric ozone (O(3)), an air pollutant associated with premature mortality. Methane and ozone are also important greenhouse gases. Reducing methane emissions therefore decreases surface ozone everywhere while slowing climate warming, but although methane mitigation has been considered to address climate change, it has not for air quality. Here we show that global decreases in surface ozone concentrations, due to methane mitigation, result in substantial and widespread decreases in premature human mortality. Reducing global anthropogenic methane emissions by 20% beginning in 2010 would decrease the average daily maximum 8-h surface ozone by approximately 1 part per billion by volume globally. By using epidemiologic ozone-mortality relationships, this ozone reduction is estimated to prevent approximately 30,000 premature all-cause mortalities globally in 2030, and approximately 370,000 between 2010 and 2030. If only cardiovascular and respiratory mortalities are considered, approximately 17,000 global mortalities can be avoided in 2030. The marginal cost-effectiveness of this 20% methane reduction is estimated to be approximately 420,000 US dollars per avoided mortality. If avoided mortalities are valued at 1 US dollars million each, the benefit is approximately 240 US dollars per tone of CH(4) ( approximately 12 US dollars per tone of CO(2) equivalent), which exceeds the marginal cost of the methane reduction. These estimated air pollution ancillary benefits of climate-motivated methane emission reductions are comparable with those estimated previously for CO(2). Methane mitigation offers a unique opportunity to improve air quality globally and can be a cost-effective component of international ozone management, bringing multiple benefits for air quality, public health, agriculture, climate, and energy.

  12. Global health benefits of mitigating ozone pollution with methane emission controls

    NASA Astrophysics Data System (ADS)

    West, J. Jason; Fiore, Arlene M.; Horowitz, Larry W.; Mauzerall, Denise L.

    2006-03-01

    Methane (CH4) contributes to the growing global background concentration of tropospheric ozone (O3), an air pollutant associated with premature mortality. Methane and ozone are also important greenhouse gases. Reducing methane emissions therefore decreases surface ozone everywhere while slowing climate warming, but although methane mitigation has been considered to address climate change, it has not for air quality. Here we show that global decreases in surface ozone concentrations, due to methane mitigation, result in substantial and widespread decreases in premature human mortality. Reducing global anthropogenic methane emissions by 20% beginning in 2010 would decrease the average daily maximum 8-h surface ozone by 1 part per billion by volume globally. By using epidemiologic ozone-mortality relationships, this ozone reduction is estimated to prevent 30,000 premature all-cause mortalities globally in 2030, and 370,000 between 2010 and 2030. If only cardiovascular and respiratory mortalities are considered, 17,000 global mortalities can be avoided in 2030. The marginal cost-effectiveness of this 20% methane reduction is estimated to be 420,000 per avoided mortality. If avoided mortalities are valued at 1 million each, the benefit is 240 per tonne of CH4 (12 per tonne of CO2 equivalent), which exceeds the marginal cost of the methane reduction. These estimated air pollution ancillary benefits of climate-motivated methane emission reductions are comparable with those estimated previously for CO2. Methane mitigation offers a unique opportunity to improve air quality globally and can be a cost-effective component of international ozone management, bringing multiple benefits for air quality, public health, agriculture, climate, and energy. human health | mortality | tropospheric ozone | air quality


  13. Impact of hydrology on methane flux patterns in a permafrost-affected floodplain in Northeast Siberia

    NASA Astrophysics Data System (ADS)

    Kwon, Min Jung; Beulig, Felix; Kuesel, Kirsten; Wildner, Marcus; Heimann, Martin; Zimov, Nikita; Zimov, Sergei; Goeckede, Mathias

    2015-04-01

    A large fraction of organic carbon stored in Arctic permafrost soil is at risk to be decomposed and released to the atmosphere under climate change. Thawing of ice-rich permafrost will re-structure the surface topography, with potentially significant effects on hydrology: water table depth (WTD) of depressed areas will increase, while that of the surrounding area will decrease. Changes in hydrology will trigger modifications in soil and vegetation, e.g. soil temperature, vegetation and microbial community structure. All of these secondary effects will alter carbon cycle processes, with the magnitude and even sign of the net effect yet unknown. The objective of this study is to investigate effects of drainage on methane fluxes in a floodplain of the Kolyma River near Cherskii, Northeast Siberia. The study site is separated into two areas, one that has been drained since 2004, and a nearby reference site. Methane flux was measured for ~16 weeks during summer and early winter of 2013, and summer of 2014. In addition, to separate different methane emission pathways, plant-mediated methane transport (through aerenchyma) as well as the proportion of ebullition were measured in 2014. Vegetation and microbial community structures were investigated and compared. After a decade of drainage history that lowered WTD by about 20cm in the drained area, Eriophorum (cotton grass) that previously dominated have to a large part been replaced by Carex (tussock-forming sedge) and shrub species. While WTD primarily influenced the methane flux rate, this vegetation change indirectly altered the flux as well in a way that sites with Eriophorum emitted more methane. Concerning the microbial community structure, the relative abundance of methanogen and ratio of methanotrophs to methanogens were well correlated with methane flux rates, implying that the methane flux is highly influenced by microorganisms. As a consequence of these changes, in the drained area less amount of methane was

  14. Some seasonal characteristics in atmospheric methane concentration in the beginning of the XXI century

    NASA Astrophysics Data System (ADS)

    Vinogradova, Anna; Ginzburg, Alexander; Fedorova, Evgeniya

    2010-05-01

    Global average value of atmospheric methane concentrations have been increasing during the XX century, but this growth nearly stopped with the beginning of the 2000th. Such "stable" situation is the proper time for studying the seasonal cycle and extreme changes of air methane concentration. One of the most interesting periods for such investigations is autumn and winter 2006/07 [1] when a number of weather abnormalities (warm air temperature up to above 0°C, almost permanent cloudiness and absence of snow cover, and so on) in Moscow region created very specific conditions for air methane existence. Temporal variations in air methane concentration within the Moscow city have been studied using the data of observations at 12 stations of Moscow municipal environmental monitoring agency "Mosecomonitoring" in 2004-2008 [2]. It was found that near-surface air concentration of methane was much higher this time than few years before and after. The values of cold season methane concentrations in Moscow region have been compared with similar data measured in the North of Kola Peninsula (at WMO GAW station "Teriberka"), in the Sankt Petersburg region (the two stations of Roshydromet), in Finland and Hungary (the stations of NOAA GMD Carbon Cycle Sampling Network). Winter maxima (more or less) of methane concentrations were revealed almost each year at all these stations, but not everywhere they were simultaneous and as high as those had been found in Moscow. The reasons of winter 2006/07 high methane concentrations in Moscow and other regions of Northern Eurasia may be special weather conditions which could cause both decrease of air methane sinks and increase of methane emissions from natural and anthropogenic sources. Perhaps, the late growth of global atmospheric methane concentration after 2007 [3] was partly produced by those seasonal anomalies in the Northern Hemisphere. References: 1. E. Fedorova, A. Ginzburg, A. Vinogradova. Seasonal variations of atmospheric

  15. The effect of elevated methane pressure on methane hydrate dissociation

    USGS Publications Warehouse

    Circone, S.; Stern, L.A.; Kirby, S.H.

    2004-01-01

    Methane hydrate, equilibrated at P, T conditions within the hydrate stability field, was rapidly depressurized to 1.0 or 2.0 MPa and maintained at isobaric conditions outside its stability field, while the extent and rate of hydrate dissociation was measured at fixed, externally maintained temperatures between 250 and 288 K. The dissociation rate decreases with increasing pressure at a given temperature. Dissociation rates at 1.0 MPa parallel the complex, reproducible T-dependence previously observed between 250 and 272 K at 0.1 MPa. The lowest rates were observed near 268 K, such that >50% of the sample can persist for more than two weeks at 0.1 MPa to more than a month at 1 and 2 MPa. Varying the pressure stepwise in a single experiment increased or decreased the dissociation rate in proportion to the rates observed in the isobaric experiments, similar to the rate reversibility previously observed with stepwise changes in temperature at 0.1 MPa. At fixed P, T conditions, the rate of methane hydrate dissociation decreases monotonically with time, never achieving a steady rate. The relationship between time (t) and the extent of hydrate dissociation is empirically described by: Evolved gas (%) = A??tB where the pre-exponential term A ranges from 0 to 16% s-B and the exponent B is generally <1. Based on fits of the dissociation results to Equation 1 for the full range of temperatures (204 to 289 K) and pressures (0.1 to 2.0 MPa) investigated, the derived parameters can be used to predict the methane evolution curves for pure, porous methane hydrate to within ??5%. The effects of sample porosity and the presence of quartz sand and seawater on methane hydrate dissociation are also described using Equation 1.

  16. Cryptic Methane Emissions from Upland Forest Ecosystems

    SciTech Connect

    Megonigal, Patrick; Pitz, Scott

    2016-04-19

    This exploratory research on Cryptic Methane Emissions from Upland Forest Ecosystems was motivated by evidence that upland ecosystems emit 36% as much methane to the atmosphere as global wetlands, yet we knew almost nothing about this source. The long-term objective was to refine Earth system models by quantifying methane emissions from upland forests, and elucidate the biogeochemical processes that govern upland methane emissions. The immediate objectives of the grant were to: (i) test the emerging paradigm that upland trees unexpectedly transpire methane, (ii) test the basic biogeochemical assumptions of an existing global model of upland methane emissions, and (iii) develop the suite of biogeochemical approaches that will be needed to advance research on upland methane emissions. We instrumented a temperate forest system in order to explore the processes that govern upland methane emissions. We demonstrated that methane is emitted from the stems of dominant tree species in temperate upland forests. Tree emissions occurred throughout the growing season, while soils adjacent to the trees consumed methane simultaneously, challenging the concept that forests are uniform sinks of methane. High frequency measurements revealed diurnal cycling in the rate of methane emissions, pointing to soils as the methane source and transpiration as the most likely pathway for methane transport. We propose the forests are smaller methane sinks than previously estimated due to stem emissions. Stem emissions may be particularly important in upland tropical forests characterized by high rainfall and transpiration, resolving differences between models and measurements. The methods we used can be effectively implemented in order to determine if the phenomenon is widespread.

  17. Mars Express confirms methane in the Martian atmosphere

    NASA Astrophysics Data System (ADS)

    2004-03-01

    From the time of its arrival at Mars, the Mars Express spacecraft started producing stunning results. One of the aims of the mission is analysing in detail the chemical composition of the Martian atmosphere, known to consist of 95% percent carbon dioxide plus 5% of minor constituents. It is also from these minor constituents, which scientists expect to be oxygen, water, carbon monoxide, formaldehyde and methane, that we may get important information on the evolution of the planet and possible implications for the presence of past or present life. The presence of methane has been confirmed thanks to the observations of the Planetary Fourier Spectrometer (PFS) on board Mars Express during the past few weeks. This instrument is able to detect the presence of particular molecules by analysing their 'spectral fingerprints' - the specific way each molecule absorbs the sunlight it receives. The measurements confirm so far that the amount of methane is very small - about 10 parts in a thousand million, so its production process is probably small. However, the exciting question remains: "Where does this methane come from?" Methane, unless it is continuously produced by a source, only survives in the Martian atmosphere for a few hundreds of years because it quickly oxidises to form water and carbon dioxide, both present in the Martian atmosphere. So, there must be a mechanism that refills the atmosphere with methane. “The first thing to understand is how exactly the methane is distributed in the Martian atmosphere,” says Vittorio Formisano, Principal Investigator for the PFS instrument. “Since the methane presence is so small, we need to take more measurements. Only then will we have enough data to make a statistical analysis and understand whether there are regions of the atmosphere where methane is more concentrated.” Once this is done, scientists will try to establish a link between the planet-wide distribution of methane and possible atmospheric or surface

  18. Lidar Measurements of Methane and Applications for Aircraft and Spacecraft

    NASA Technical Reports Server (NTRS)

    Riris, Haris; Numata, Kenji; Abshire, James; Li, Steve; Wu, Stewart; Krainak, Michael; Sun, Xiaoli

    2010-01-01

    Atmospheric methane levels have remained relatively constant over the last decade around 1.78 parts per million (ppm) but observations since 2007 show that levels may be increasing. This trend may be caused by increased fossil fuel production, rice farming, livestock and landfills, but the underlying causes are quite uncertain. One hypothesis is that reservoirs of carbon trapped in the permafrost regions of northern Canada, Europe, and Siberia thaw as global temperatures rise and are releasing increasing amounts of methane. Another hypothesis points to increased production of methane by microbes as the permafrost warms. Currently most observations of greenhouse gases are limited to in-situ (surface and tower sites) and limited airborne in-situ measurements. Space column density measurements are starting to become available from the GOSAT mission. Although methane survives for a shorter time in the atmosphere than CO2, its impact on climate change per molecule is about 23 times than that of CO2. Accurate global observations of several greenhouse gases, including methane, are urgently needed in order to better understand climate change processes and to reduce the uncertainty in the carbon budget. Differential absorption lidar is a well-established technique to measure atmospheric gases, and methane has optical absorption bands near 1.65,2.2,3.4 and 7.8 micron. The near infrared overtones lines of CH4 near 1650 nm are relatively free of interference from other species. There are absorption lines near 1651 nm which are both temperature insensitive and have line strengths well suited for lidar measurements. We have developed a laser and demonstrated lidar measurements of CH4 using lines in this band. Our laser uses a narrow linewidth 1064 nm laser pulse passing through a nonlinear crystal. We generate the tunable laser signals near 1651 nm by using the optical parametric amplification (OPA) process. Inside the crystal the 1064 nm beam overlaps with an injection seed

  19. Tropical small streams are a consistent source of methane

    NASA Astrophysics Data System (ADS)

    Vihermaa, Leena; Waldron, Susan

    2013-04-01

    To date only a few studies have quantified diffusive methane emissions from headwater streams therefore the magnitude and seasonal variation of these emissions remain poorly understood. Here we present results from two Western Amazonian small streams (first and second order) in Tambopata National Reserve, Peru. Towards the end of wet season, April-May 2012, the streams were sampled using a static floating chamber to accumulate methane. Samples were drawn from the headspace twice daily over period of four days on three separate occasions. The methane concentrations were analysed using a gas chromatograph and the linear part of concentration increase used to calculate the flux rates. The streams were consistently outgassing methane. The seasonally active first order stream outgassed 6 ±2.4 nmol CH4-C m-2 s-1 and the second order stream 20 ±4.0 nmol CH4-C m-2 s-1. The latter flux rate is comparable to fluxes measured from seasonally flooded Amazonian forest in previous studies. The range measured in our streams is comparable to previous results in temperate streams and the lower end of fluxes observed in some peatland streams. The only other study on Amazonian small streams detected methane fluxes that were 100 times greater than those measured here. Depending on the density of small streams in Amazonian basin and the prevalent flux rate, the fluvial methane fluxes may constitute a significant global warming potential. Upscaling to the Amazon basin, assuming small stream density of 0.2 %, as was found at our field site, and the flux rates detected, yields an annual global warming potential equal to approximately 1.5 Mt of CO2 which is of minor importance compared to aquatic CO2-C flux of 500 Mt yr-1 from the basin. However, if the higher fluxes detected in the previous study were prevalent, the basin wide methane flux could become significant. Further studies are needed to establish the stream density in the Amazon basin and typical methane flux rates.

  20. Insights into Methane Formation Temperatures, Biogenic Methanogenesis, and Natural Methane Emissions from Clumped Isotopes

    NASA Astrophysics Data System (ADS)

    Douglas, P. M.; Stolper, D. A.; Walter Anthony, K. M.; Dallimore, S.; Paull, C. K.; Wik, M.; Crill, P. M.; Winterdahl, M.; Smith, D. A.; Luhmann, A. J.; Ding, K.; Seyfried, W. E., Jr.; Eiler, J. M.; Ponton, C.; Sessions, A. L.

    2015-12-01

    Multiply substituted isotopologues of methane are a valuable new tool for characterizing and understanding the source of methane in different Earth environments. Here we present methane clumped isotope results from natural gas wells, hydrothermal vents, marine and lacustrine methane seeps, and culture experiments. We observe a wide range of formation temperatures for thermogenic methane. Methane samples from low-maturity reservoirs indicate formation temperatures between 102-144° C, high-maturity conventional and shale gasses indicate temperatures between 158-246 °C, and thermogenic coal gases indicate temperatures between 174-267 °C. Methane formation temperatures generally correlate positively with δ13C, and negatively with gas wetness indices. Methane samples from a set of marine hydrothermal vents indicate a formation temperature of 290-350 °C. Methane sampled from subsurface and marine biogenic sources typically indicate temperatures consistent with the formation environment (0-64° C). In contrast, freshwater biogenic methane samples, and cultures of hydrogenotrophic and methylotrophic methanogens, express low levels of isotopic clumping inconsistent with their formation temperature. These data and complementary models suggest that kinetic isotope effects, likely modulated by rates and pathways of methanogenesis, affect biogenic methane in cultures and freshwater environments. Alternatively, non-equilibrium signatures may result from mixing of methane with widely differing δD and δ13C values. Analyses of biogenic methane emissions from lakes indicate a correlation between methane flux and non-equilibrium clumped isotope fractionations in a given lake. Results from large methane seeps in Alaskan lakes confirm that some seeps emit thermogenic methane, but also indicate that other seeps emit subsurface biogenic methane or variable mixtures of biogenic and thermogenic methane. These results point to diverse sources for large Arctic methane seeps.

  1. Quantification of methane emissions from natural gas extraction from the Haynesville, Fayetteville, and northeastern Marcellus shale regions

    NASA Astrophysics Data System (ADS)

    Peischl, J.; Ryerson, T. B.; Trainer, M.; De Gouw, J. A.; Warneke, C.; Parrish, D. D.

    2013-12-01

    We present airborne measurements of methane over three regions of natural gas extraction taken aboard a NOAA WP-3D research aircraft in June and July, 2013, as part of the Southeast Nexus (SENEX) field project. The three regions are (1) the Haynesville and (2) Fayetteville shale plays, located in eastern Texas/western Louisiana and western Arkansas, respectively, and (3) a part of the Marcellus shale play located in northeastern Pennsylvania. From these measurements, we derive methane emission rate estimates by calculating the methane advection flux in the planetary boundary layer downwind of the region, minus the methane flux upwind of the region. By attributing the methane emissions to natural gas extraction, we place an upper limit on the natural gas emissions from the region. We then compare this emission to the total volume of natural gas extracted from the region to derive an upper limit on the natural gas leak rate from extraction operations.

  2. Methane generation from waste materials

    DOEpatents

    Samani, Zohrab A.; Hanson, Adrian T.; Macias-Corral, Maritza

    2010-03-23

    An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

  3. Methane Dynamics in Flooded Lands

    EPA Science Inventory

    Methane (CH4) is the second most important anthropogenic greenhouse gas with a heat trapping capacity 34 times greater than that of carbon dioxide on a100 year time scale. Known anthropogenic CH4 sources include livestock production, rice agriculture, landfills, and natural gas m...

  4. Methane production by attached film

    DOEpatents

    Jewell, William J.

    1981-01-01

    A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

  5. Bis(2-chloroethoxy)methane

    Integrated Risk Information System (IRIS)

    Bis ( 2 - chloroethoxy ) methane ; CASRN 111 - 91 - 1 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for

  6. Methane flux from Minnesota peatlands

    SciTech Connect

    Crill, P.M.; Bartlett, K.B.; Harriss, R.C.; Gorham, E.; Verry, E.S. )

    1988-12-01

    Northern (> 40 deg N) wetlands have been suggested as the largest natural source of methane (CH{sub 4}) to the troposphere. To refine the authors estimates of source strengths from this region and to investigate climatic controls on the process, fluxes were measured from a variety of Minnesota peatlands during May, June, and August 1986. Late spring and summer fluxes ranged from 11 to 866 mg CH{sub 4}/sq/m/day, averaging 207 mg CH{sub 4} sq/m/day overall. At Marcell Forest, forested bogs and fen sites had lower fluxes than open bogs. In the Red Lake peatland, circumneutral fens, with standing water above the peat surface, produced more methane than acid bog sites in which the water table was beneath the moss surface. Peat temperature was an important control. Methane flux increased in response to increasing soil temperature. It is estimated that the methane flux from all peatlands north of 40 deg may be on the order of 70 to 90 Tg/yr though estimates of this sort are plagued by uncertainties in the areal extent of peatlands, length of the CH{sub 4} producing season, and the spatial and temporal variability of the flux. 60 refs., 7 figs., 5 tabs.

  7. Ductile flow of methane hydrate

    USGS Publications Warehouse

    Durham, W.B.; Stern, L.A.; Kirby, S.H.

    2003-01-01

    Compressional creep tests (i.e., constant applied stress) conducted on pure, polycrystalline methane hydrate over the temperature range 260-287 K and confining pressures of 50-100 MPa show this material to be extraordinarily strong compared to other icy compounds. The contrast with hexagonal water ice, sometimes used as a proxy for gas hydrate properties, is impressive: over the thermal range where both are solid, methane hydrate is as much as 40 times stronger than ice at a given strain rate. The specific mechanical response of naturally occurring methane hydrate in sediments to environmental changes is expected to be dependent on the distribution of the hydrate phase within the formation - whether arranged structurally between and (or) cementing sediments grains versus passively in pore space within a sediment framework. If hydrate is in the former mode, the very high strength of methane hydrate implies a significantly greater strain-energy release upon decomposition and subsequent failure of hydrate-cemented formations than previously expected.

  8. Methane on the greenhouse agenda

    NASA Technical Reports Server (NTRS)

    Hogan, Kathleen B.; Hoffman, John S.; Thompson, Anne M.

    1991-01-01

    Options for reducing methane emissions, which could have a significant effect on global warming, are addressed. Emissions from landfills, coal mining, oil and natural gas systems, ruminants, animal wastes and wastewater, rice cultivation, and biomass burning are considered. Methods for implementing these emission reductions are discussed.

  9. Understanding the Recent Methane Budget

    NASA Astrophysics Data System (ADS)

    Bruhwiler, L.; Dlugokencky, E. J.; Masarie, K.

    2010-12-01

    Anthropogenic sources are thought to account for roughly 2/3 of the global atmospheric methane budget, with natural sources making up the other 1/3. Emissions from wetlands are the largest contribution from natural sources while agriculture (rice and ruminants) and waste dominate anthropogenic emissions. Fugitive emissions from fossil fuel extraction are thought to make up about 20% of the global atmospheric methane budget. It is generally recognized that observed inter-annual variability in global network observations can be attributed to natural sources such as wetlands and biomass burning, while longer-term trends likely indicate changes in anthropogenic sources. Exceptions include an abrupt decrease in fossil fuel emissions in the early 1990s associated with political changes in the Former Soviet Union, and long-term trends in emissions from the Arctic due to a warming climate. The growth rate of global average atmospheric methane since the 1980s shows a steady decline until recent years when it started to increase again. Superimposed on these trends are episodes of higher growth rates. The cause of the recent increase is not currently well-understood, although climate-driven increases in wetland emissions likely played an important role, especially in the tropics. Recent increases in anthropogenic emissions, especially from rapidly expanding Asian economies cannot be ruled out. In addition, trends in the photochemical lifetime of methane must also be considered. In this paper we use both traditional data analysis of observations of methane and related species, and a state-of-the-art ensemble data assimilation system (CarbonTracker-CH4) to attribute methane variability and trends to anthropogenic and natural source processes. We pay particular attention to the Arctic, where some recent years have been the warmest on record, and to the tropics and the potential role of ENSO in driving variability of wetland emissions. Finally, we explore whether a signal in

  10. The regulation of methane oxidation in soil

    NASA Technical Reports Server (NTRS)

    Mancinelli, R. L.

    1995-01-01

    The atmospheric concentration of methane, a greenhouse gas, has more than doubled during the past 200 years. Consequently, identifying the factors influencing the flux of methane into the atmosphere is becoming increasingly important. Methanotrophs, microaerophilic organisms widespread in aerobic soils and sediments, oxidize methane to derive energy and carbon for biomass. In so doing, they play an important role in mitigating the flux of methane into the atmosphere. Several physico-chemical factors influence rates of methane oxidation in soil, including soil diffusivity; water potential; and levels of oxygen, methane, ammonium, nitrate, nitrite, and copper. Most of these factors exert their influence through interactions with methane monooxygenase (MMO), the enzyme that catalyzes the reaction converting methane to methanol, the first step in methane oxidation. Although biological factors such as competition and predation undoubtedly play a role in regulating the methanotroph population in soils, and thereby limit the amount of methane consumed by methanotrophs, the significance of these factors is unknown. Obtaining a better understanding of the ecology of methanotrophs will help elucidate the mechanisms that regulate soil methane oxidation.

  11. Methane hydrates and contemporary climate change

    USGS Publications Warehouse

    Ruppel, Carolyn D.

    2011-01-01

    As the evidence for warming climate became better established in the latter part of the 20th century (IPCC 2001), some scientists raised the alarm that large quantities of methane (CH4) might be liberated by widespread destabilization of climate-sensitive gas hydrate deposits trapped in marine and permafrost-associated sediments (Bohannon 2008, Krey et al. 2009, Mascarelli 2009). Even if only a fraction of the liberated CH4 were to reach the atmosphere, the potency of CH4 as a greenhouse gas (GHG) and the persistence of its oxidative product (CO2) heightened concerns that gas hydrate dissociation could represent a slow tipping point (Archer et al. 2009) for Earth's contemporary period of climate change.

  12. The isotopic composition of methane in polar ice cores

    NASA Technical Reports Server (NTRS)

    Craig, H.; Chou, C. C.; Welhan, J. A.; Stevens, C. M.; Engelkemeir, A.

    1988-01-01

    Air bubbles in polar ice cores indicate that about 300 years ago the atmospheric mixing ratio of methane began to increase rapidly. Today the mixing ratio is about 1.7 parts per million by volume, and, having doubled once in the past several hundred years, it will double again in the next 60 years if current rates continue. Carbon isotope ratios in methane up to 350 years in age have been measured with as little as 25 kilograms of polar ice recovered in 4-meter-long ice-core segments. The data show that: (1) in situ microbiology or chemistry has not altered the ice-core methane concentrations, and (2) that the carbon-13 to carbon-12 ratio of atmospheric CH4 in ice from 100 years and 300 years ago was about 2 per mil lower than at present. Atmospheric methane has a rich spectrum of isotopic sources: the ice-core data indicate that anthropogenic burning of the earth's biomass is the principal cause of the recent C-13H4 enrichment, although other factors may also contribute.

  13. Methane emissions to the atmosphere through aquatic plants

    NASA Technical Reports Server (NTRS)

    Sebacher, D. I.; Harriss, R. C.; Bartlett, K. B.

    1985-01-01

    The movement of methane (CH4) from anaerobic sediments through the leaves, stems, and flowers of aquatic plants and into the atmosphere was found to provide a significant pathway for the emission of CH4 from the aquatic substrates of flooded wetlands. Methane concentrations well above the surrounding ambient air levels were found in the mesophyll of 16 varies of aquatic plants and are attributed to transpiration, diffusion, and pressure-induced flow of gaseous CH4 from the roots when they are embedded in CH4-saturated anaerobic sediments. Methane emissions from the emergent parts of aquatic plants were measured using floating chamber techniques and by enclosing the plants in polyethylene bags of known volume. Concentration changes were monitored in the trapped air using syringes and gas chromatographic techniques. Vertical profiles of dissolved CH4 in sediment pore water surrounding the aquatic plants' rhizomes were obtained using an interstitial sampling technique. Methane emissions from the aquatic plants studied varied from 14.8 mg CH4/d to levels too low to be detectable. Rooted and unrooted freshwater aquatic plants were studied as well as saltwater and brackish water plants. Included in the experiment is detailed set of measurements on CH4 emissions from the common cattail (Typha latifolia). This paper illustrates that aquatic plants play an important gas exchange role in the C cycle between wetlands and the atmosphere.

  14. Geologic seepage of methane and light alkanes in Los Angeles

    NASA Astrophysics Data System (ADS)

    Doezema, L. A.; Chang, K.; Baril, R.; Nwachuku, I.; Contreras, P.; Marquez, A.; Howard, D.

    2013-12-01

    Natural geologic seepage of methane from underground oil and natural gas reservoirs has been suggested to be an underreported part of the global methane budget. Other light alkanes are also given off in combination with the methane seepage, making it possible that geologic seepage is also a potentially significant global source of these light alkanes. This study reports C1-C5 findings from geologic seepage made in the Los Angeles region. Microseepage, invisible escape of gases, was measured primarily at Kenneth Hahn Regional Park, while macroseepage, the visible release of gases, was measured at the La Brea Tar Pits. Samples were collected using stainless steel canisters and flux chambers and were analyzed using gas chromatography with flame ionization detectors (GC-FID). Average microseepage flux rates of 0.95 μg m-2 h-1 for ethane and 0.51 μg m-2 h-1 were found for propane, while average macroseepage rates for methane, ethane, and propane were 664, 19.8, and 18.1 mg m-2 h-1 respectively. Relationships between microseepage flux rate and location of underground oil and natural deposit and earthquake fault lines are presented. Additionally, the relative importance of findings in context with global budgets and local air quality is discussed.

  15. Estimation of methane emission flux at landfill surface using laser methane detector: Influence of gauge pressure.

    PubMed

    Park, Jin-Kyu; Kang, Jong-Yun; Lee, Nam-Hoon

    2016-08-01

    The aim of this study was to investigate the possibility of measuring methane emission fluxes, using surface methane concentration and gauge pressure, by analyzing the influence of gauge pressure on the methane emission flux and the surface methane concentration, as well as the correlation between the methane emission flux and surface methane concentrations. The surface methane concentration was measured using a laser methane detector. Our results show a positive linear relationship between the surface methane concentration and the methane emission flux. Furthermore, the methane emission flux showed a positive linear relationship with the gauge pressure; this implies that when the surface methane concentration and the surface gauge pressure are measured simultaneously, the methane emission flux can be calculated using Darcy's law. A decrease in the vertical permeability was observed when the gauge pressure was increased, because reducing the vertical permeability may lead to a reduced landfill gas emission to the atmosphere, and landfill gas would be accumulated inside the landfill. Finally, this method is simple and can allow for a greater number of measurements during a relatively shorter period. Thus, it provides a better representation of the significant space and time variations in methane emission fluxes.

  16. Methane clathrates in the solar system.

    PubMed

    Mousis, Olivier; Chassefière, Eric; Holm, Nils G; Bouquet, Alexis; Waite, Jack Hunter; Geppert, Wolf Dietrich; Picaud, Sylvain; Aikawa, Yuri; Ali-Dib, Mohamad; Charlou, Jean-Luc; Rousselot, Philippe

    2015-04-01

    We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form into the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from hydrothermal reactions with olivine-rich material. If they do exist, martian methane clathrates would be stable only at depth in the cryosphere and sporadically release some methane into the atmosphere via mechanisms that remain to be determined. In the case of Titan, most of its methane probably originates from the protosolar nebula, where it would have been trapped in the clathrates agglomerated by the satellite's building blocks. Methane clathrates are still believed to play an important role in the present state of Titan. Their presence is invoked in the satellite's subsurface as a means of replenishing its atmosphere with methane via outgassing episodes. The internal oceans of Enceladus and Europa also provide appropriate thermodynamic conditions that allow formation of methane clathrates. In turn, these clathrates might influence the composition of these liquid reservoirs. Finally, comets and Kuiper Belt Objects might have formed from the agglomeration of clathrates and pure ices in the nebula. The methane observed in comets would then result from the destabilization of clathrate layers in the nuclei concurrent with their approach to perihelion. Thermodynamic equilibrium calculations show that methane-rich clathrate

  17. Dissolved Methane in the Sills Region of the Gulf of California

    EPA Science Inventory

    An unusual combination of features make the midriff islands region of the northern Gulf of California (NGC) a strong source of methane to the atmosphere. Oceanographic isolation from the rest of the NGC by a series of sills and islands along with enhanced upward transport of nutr...

  18. Mitigation of methane and nitrous oxide emissions from animal operations: A review of manure management options

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This review analyzes published data on manure management practices used to mitigate methane (CH4) and nitrous oxide (N2O) emissions from animal operations. This is the second in a series of reports commissioned by the Food and Agriculture Organization of the United Nations to evaluate mitigation pra...

  19. Performance of catalysts for CO removal by methanation

    SciTech Connect

    Oshiro, Hitoshi; Nagaya, Kiichi; Mitani, Koichi

    1996-12-31

    This report forms part of a joint study on a PEFC propulsion system for surface ships, summarized in a presentation to this Seminar, entitled {open_quotes}Study on a Polymer Electrolyte Fuel Cell (PEFC) Propulsion System for Surface Ships{close_quotes}, and which envisages application to a 1,500 DWT cargo vessel. The aspect treated here concerns an experiment in reducing by methanation to a level below 10 ppm the CO that is contained to around 1% in reformate gas.

  20. Hydrogen stable isotopic constraints on methane emissions from oil and gas extraction in the Colorado Front Range, USA

    NASA Astrophysics Data System (ADS)

    Townsend-Small, A.; Botner, E. C.; Jimenez, K.; Blake, N. J.; Schroeder, J.; Meinardi, S.; Barletta, B.; Simpson, I. J.; Blake, D. R.; Flocke, F. M.; Pfister, G.; Bon, D.; Crawford, J. H.

    2015-12-01

    The climatic implications of a shift from oil and coal to natural gas depend on the magnitude of fugitive emissions of methane from the natural gas supply chain. Attempts to constrain methane emissions from natural gas production regions can be confounded by other sources of methane. Here we demonstrate the utility of stable isotopes, particularly hydrogen isotopes, for source apportionment of methane emissions. The Denver, Colorado area is home to a large oil and gas field with both conventional oil and gas wells and newer hydraulic fracturing wells. The region also has a large metropolitan area with several landfills and a sizable cattle population. As part of the DISCOVER-AQ and FRAPPE field campaigns in summer 2014, we collected three types of canister samples for analysis of stable isotopic composition of methane: 1), samples from methane sources; 2), samples from two stationary ground sites, one in the Denver foothills, and one in an oil and gas field; and 3), from the NCAR C-130 aircraft in samples upwind and downwind of the region. Our results indicate that hydrogen isotope ratios are excellent tracers of sources of methane in the region, as we have shown previously in California and Texas. Use of carbon isotope ratios is complicated by the similarity of natural gas isotope ratios to that of background methane. Our results indicate that, despite the large amount of natural gas production in the region, biological sources such as cattle feedlots and landfills account for at least 50% of total methane emissions in the Front Range. Future work includes comparison of isotopes and alkane ratios as tracers of methane sources, and calculation of total methane fluxes in the region using continuous measurements of methane concentrations during aircraft flights.

  1. Geological emission of methane from the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China.

    PubMed

    Tang, Junhong; Bao, Zhengyu; Xiang, Wu; Gou, Qinghong

    2008-01-01

    A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and pervasion, and that a part of the migrated methane that remained unoxidized could emit into the atmosphere. Methane emission rates varied less in the oil/gas field because the whole region was homogeneous in geology and geography, with a standard deviation of less than 0.02 mg/(m2 x h). These were the differences in methane emission flux in the day and at night in the oil/gas field. The maximum methane emission flux reached 0.15 mg/(m2 x h) at 5:00-6:00 early in the morning, and then decreased gradually. The minimum was shown 0.10 mg/(m2 x h) at 17:00-18:00 in the afternoon, and then increased gradually. The daily methane released flux of the study area was 2.89 mg/(m2 x d), with a standard deviation of 0.43 mg/(m2 x d), using the average methane flux of every hour in a day for all chambers. delta13C of methane increased with the increase of methane concentration in the flux chambers, further indicating that the pyrogenetic origin of methane was come from deep oil/gas reservoirs.

  2. The effects of alternative pretreatment strategies on anaerobic digestion and methane production from different algal strains.

    PubMed

    Bohutskyi, Pavlo; Betenbaugh, Michael J; Bouwer, Edward J

    2014-03-01

    The effect of various pretreatment strategies on methane yields following anaerobic digestion (AD) of five different microalgal strains was investigated. Pavlova_cf sp., Tetraselmis sp. and Thalassiosira weissflogii exhibited substantial methane yields of 0.4-0.5L/g volatile solids (VS) without pretreatment, providing up to 75-80% of theoretical values. In contrast, methane yields from Chlorella sp. and Nannochloropsis sp. were around 0.35L/g VS, or 55-60% of the theoretical values, respectively. Alkali treatment was not effective and thermal pretreatment only enhanced Nannochloropsis methane yields. Thermochemical pretreatment had the strongest impact on biomass solubilization with methane yields increasing by 30% and 40% for Chlorella and Nannochloropsis, respectively. The lipid content had a strong beneficial impact on the theoretical and observed methane yields as compared to protein and carbohydrate content. Other features such as cell-wall composition are also likely to be important factors dictating algal biodegradability and methane yields addressed in part by thermochemical pretreatment.

  3. A modeling approach to direct interspecies electron transfer process in anaerobic transformation of ethanol to methane.

    PubMed

    Liu, Yiwen; Zhang, Yaobin; Zhao, Zhiqiang; Ngo, Huu Hao; Guo, Wenshan; Zhou, Junliang; Peng, Lai; Ni, Bing-Jie

    2017-01-01

    Recent studies have shown that direct interspecies electron transfer (DIET) plays an important part in contributing to methane production from anaerobic digestion. However, so far anaerobic digestion models that have been proposed only consider two pathways for methane production, namely, acetoclastic methanogenesis and hydrogenotrophic methanogenesis, via indirect interspecies hydrogen transfer, which lacks an effective way for incorporating DIET into this paradigm. In this work, a new mathematical model is specifically developed to describe DIET process in anaerobic digestion through introducing extracellular electron transfer as a new pathway for methane production, taking anaerobic transformation of ethanol to methane as an example. The developed model was able to successfully predict experimental data on methane dynamics under different experimental conditions, supporting the validity of the developed model. Modeling predictions clearly demonstrated that DIET plays an important role in contributing to overall methane production (up to 33 %) and conductive material (i.e., carbon cloth) addition would significantly promote DIET through increasing ethanol conversion rate and methane production rate. The model developed in this work will potentially enhance our current understanding on syntrophic metabolism via DIET.

  4. Atmospheric constraints on the methane emissions from the East Siberian Shelf

    NASA Astrophysics Data System (ADS)

    Berchet, Antoine; Bousquet, Philippe; Pison, Isabelle; Locatelli, Robin; Chevallier, Frédéric; Paris, Jean-Daniel; Dlugokencky, Ed J.; Laurila, Tuomas; Hatakka, Juha; Viisanen, Yrjo; Worthy, Doug E. J.; Nisbet, Euan; Fisher, Rebecca; France, James; Lowry, David; Ivakhov, Viktor; Hermansen, Ove

    2016-03-01

    Subsea permafrost and hydrates in the East Siberian Arctic Shelf (ESAS) constitute a substantial carbon pool, and a potentially large source of methane to the atmosphere. Previous studies based on interpolated oceanographic campaigns estimated atmospheric emissions from this area at 8-17 TgCH4 yr-1. Here, we propose insights based on atmospheric observations to evaluate these estimates. The comparison of high-resolution simulations of atmospheric methane mole fractions to continuous methane observations during the whole year 2012 confirms the high variability and heterogeneity of the methane releases from ESAS. A reference scenario with ESAS emissions of 8 TgCH4 yr-1, in the lower part of previously estimated emissions, is found to largely overestimate atmospheric observations in winter, likely related to overestimated methane leakage through sea ice. In contrast, in summer, simulations are more consistent with observations. Based on a comprehensive statistical analysis of the observations and of the simulations, annual methane emissions from ESAS are estimated to range from 0.0 to 4.5 TgCH4 yr-1. Isotopic observations suggest a biogenic origin (either terrestrial or marine) of the methane in air masses originating from ESAS during late summer 2008 and 2009.

  5. FACT SHEET: Administration Takes Steps Forward on Climate Action Plan by Announcing Actions to Cut Methane Emissions

    EPA Pesticide Factsheets

    The Obama Administration is committed to taking responsible steps to address climate change and help ensure a cleaner, more stable environment for future generations. As part of that effort, today, the Administration is announcing a new goal to cut methane

  6. Turbulent burning rates of methane and methane-hydrogen mixtures

    SciTech Connect

    Fairweather, M.; Ormsby, M.P.; Sheppard, C.G.W.; Woolley, R.

    2009-04-15

    Methane and methane-hydrogen (10%, 20% and 50% hydrogen by volume) mixtures have been ignited in a fan stirred bomb in turbulence and filmed using high speed cine schlieren imaging. Measurements were performed at 0.1 MPa (absolute) and 360 K. A turbulent burning velocity was determined for a range of turbulence velocities and equivalence ratios. Experimental laminar burning velocities and Markstein numbers were also derived. For all fuels the turbulent burning velocity increased with turbulence velocity. The addition of hydrogen generally resulted in increased turbulent and laminar burning velocity and decreased Markstein number. Those flames that were less sensitive to stretch (lower Markstein number) burned faster under turbulent conditions, especially as the turbulence levels were increased, compared to stretch-sensitive (high Markstein number) flames. (author)

  7. Contribution of oil and natural gas production to renewed increase of atmospheric methane (2007-2014): top-down estimate from ethane and methane column observations

    NASA Astrophysics Data System (ADS)

    Hausmann, P.; Sussmann, R.; Smale, D.

    2015-12-01

    Harmonized time series of column-averaged mole fractions of atmospheric methane and ethane over the period 1999-2014 are derived from solar Fourier transform infrared (FTIR) measurements at the Zugspitze summit (47° N, 2964 m a.s.l.) and at Lauder (45° S, 370 m a.s.l.). Long-term trend analysis reveals a consistent renewed methane increase since 2007 of 6.2 [5.6, 6.9] ppb yr-1 at the Zugspitze and 6.0 [5.3, 6.7] ppb yr-1 at Lauder (95 % confidence intervals). Several recent studies provide pieces of evidence that the renewed methane increase is most likely driven by two main factors: (i) increased methane emissions from tropical wetlands, followed by (ii) increased thermogenic methane emissions due to growing oil and natural gas production. Here, we quantify the magnitude of the second class of sources, using long-term measurements of atmospheric ethane as tracer for thermogenic methane emissions. In 2007, after years of weak decline, the Zugspitze ethane time series shows the sudden onset of a significant positive trend (2.3 [1.8, 2.8] × 10-2 ppb yr-1 for 2007-2014), while a negative trend persists at Lauder after 2007 (-0.4 [-0.6, -0.1] × 10-2 ppb yr-1). Zugspitze methane and ethane time series are significantly correlated for the period 2007-2014 and can be assigned to thermogenic methane emissions with an ethane-to-methane ratio of 10-21 %. We present optimized emission scenarios for 2007-2014 derived from an atmospheric two-box model. From our trend observations we infer a total ethane emission increase over the period 2007-2014 from oil and natural gas sources of 1-11 Tg yr-1 along with an overall methane emission increase of 24-45 Tg yr-1. Based on these results, the oil and natural gas emission contribution C to the renewed methane increase is deduced using three different emission scenarios with dedicated ranges of methane-to-ethane ratios (MER). Reference scenario 1 assumes an oil and gas emission combination with MER = 3.3-7.6, which results in a

  8. Estimation of methane concentrations and loads in groundwater discharge to Sugar Run, Lycoming County, Pennsylvania

    USGS Publications Warehouse

    Heilweil, Victor M.; Risser, Dennis W.; Conger, Randall W.; Grieve, Paul L.; Hynek, Scott A.

    2014-01-01

    A stream-sampling study was conducted to estimate methane concentrations and loads in groundwater discharge to a small stream in an active shale-gas development area of northeastern Pennsylvania. Grab samples collected from 15 streams in Bradford, Lycoming, Susquehanna, and Tioga Counties, Pa., during a reconnaissance survey in May and June 2013 contained dissolved methane concentrations ranging from less than the minimum reporting limit (1.0) to 68.5 micrograms per liter (µg/L). The stream-reach mass-balance method of estimating concentrations and loads of methane in groundwater discharge was applied to a 4-kilometer (km) reach of Sugar Run in Lycoming County, one of the four streams with methane concentrations greater than or equal to 5 µg/L. Three synoptic surveys of stream discharge and methane concentrations were conducted during base-flow periods in May, June, and November 2013. Stream discharge at the lower end of the reach was about 0.10, 0.04, and 0.02 cubic meters per second, respectively, and peak stream methane concentrations were about 20, 67, and 29 µg/L. In order to refine estimated amounts of groundwater discharge and locations where groundwater with methane discharges to the stream, the lower part of the study reach was targeted more precisely during the successive studies, with approximate spacing between stream sampling sites of 800 meters (m), 400 m, and 200 m, in May, June, and November, respectively. Samples collected from shallow piezometers and a seep near the location of the peak methane concentration measured in streamwater had groundwater methane concentrations of 2,300 to 4,600 µg/L. These field data, combined with one-dimensional stream-methane transport modeling, indicate groundwater methane loads of 1.8 ±0.8, 0.7 ±0.3, and 0.7 ±0.2 kilograms per day, respectively, discharging to Sugar Run. Estimated groundwater methane concentrations, based on the transport modeling, ranged from 100 to 3,200 µg/L. Although total methane load

  9. Microbial methane production in deep aquifer associated with the accretionary prism in Japan.

    PubMed

    Kimura, Hiroyuki; Nashimoto, Hiroaki; Shimizu, Mikio; Hattori, Shohei; Yamada, Keita; Koba, Keisuke; Yoshida, Naohiro; Kato, Kenji

    2010-04-01

    To identify the methanogenic pathways present in a deep aquifer associated with an accretionary prism in Southwest Japan, a series of geochemical and microbiological studies of natural gas and groundwater derived from a deep aquifer were performed. Stable carbon isotopic analysis of methane in the natural gas and dissolved inorganic carbon (mainly bicarbonate) in groundwater suggested that the methane was derived from both thermogenic and biogenic processes. Archaeal 16S rRNA gene analysis revealed the dominance of H(2)-using methanogens in the groundwater. Furthermore, the high potential of methane production by H(2)-using methanogens was shown in enrichments using groundwater amended with H(2) and CO(2). Bacterial 16S rRNA gene analysis showed that fermentative bacteria inhabited the deep aquifer. Anaerobic incubations using groundwater amended with organic substrates and bromoethanesulfonate (a methanogen inhibitor) suggested a high potential of H(2) and CO(2) generation by fermentative bacteria. To confirm whether or not methane is produced by a syntrophic consortium of H(2)-producing fermentative bacteria and H(2)-using methanogens, anaerobic incubations using the groundwater amended with organic substrates were performed. Consequently, H(2) accumulation and rapid methane production were observed in these enrichments incubated at 55 and 65 degrees C. Thus, our results suggested that past and ongoing syntrophic biodegradation of organic compounds by H(2)-producing fermentative bacteria and H(2)-using methanogens, as well as a thermogenic reaction, contributes to the significant methane reserves in the deep aquifer associated with the accretionary prism in Southwest Japan.

  10. Effect of silane concentration on the supersonic combustion of a silane/methane mixture

    SciTech Connect

    Northam, G.B.; Mc Lain, A.G.; Pellett, G.L.; Diskin, G.S.

    1986-01-01

    A series of direct connect combustor tests was conducted to determine the effect of silane concentration on the supersonic combustion characteristics of silane/methane mixtures. Shock tube ignition delay data indicated more than an order of magnitude reduction in ignition delay times for both 10 and 20 percent silane/methane mixtures as compared to methane. The ignition delay time of the 10 percent mixture was only a factor of 2.3 greater than that of the 20 percent mixture. Supersonic combustion tests were conducted with the fuel injected into a model scramjet combustor. The combustor was mounted at the exit of a Mach 2 nozzle and a hydrogen fired heater was used to provide a variation in test gas total temperature. Tests using the 20 percent silane/methane mixture indicated considerable combustion enhancement when compared to methane alone. This mixture had an autoignition total temperature of 1650 R. The addition of 20 percent silane to methane resulted in a pyrophoric fuel with good supersonic combustion performance. Reducing the silane concentration below this level, however, yielded a less pyrophoric fuel that exhibited poor supersonic combustion performance.

  11. Attributing Atmospheric Methane to Anthropogenic Emission Sources.

    PubMed

    Allen, David

    2016-07-19

    Methane is a greenhouse gas, and increases in atmospheric methane concentration over the past 250 years have driven increased radiative forcing of the atmosphere. Increases in atmospheric methane concentration since 1750 account for approximately 17% of increases in radiative forcing of the atmosphere, and that percentage increases by approximately a factor of 2 if the effects of the greenhouse gases produced by the atmospheric reactions of methane are included in the assessment. Because of the role of methane emissions in radiative forcing of the atmosphere, the identification and quantification of sources of methane emissions is receiving increased scientific attention. Methane emission sources include biogenic, geogenic, and anthropogenic sources; the largest anthropogenic sources are natural gas and petroleum systems, enteric fermentation (livestock), landfills, coal mining, and manure management. While these source categories are well-known, there is significant uncertainty in the relative magnitudes of methane emissions from the various source categories. Further, the overall magnitude of methane emissions from all anthropogenic sources is actively debated, with estimates based on source sampling extrapolated to regional or national scale ("bottom-up analyses") differing from estimates that infer emissions based on ambient data ("top-down analyses") by 50% or more. To address the important problem of attribution of methane to specific sources, a variety of new analytical methods are being employed, including high time resolution and highly sensitive measurements of methane, methane isotopes, and other chemical species frequently associated with methane emissions, such as ethane. This Account describes the use of some of these emerging measurements, in both top-down and bottom-up methane emission studies. In addition, this Account describes how data from these new analytical methods can be used in conjunction with chemical mass balance (CMB) methods for source

  12. Methane in water columns and sediments of the north western Sea of Japan

    NASA Astrophysics Data System (ADS)

    Vereshchagina, Olga F.; Korovitskaya, Elena V.; Mishukova, Galina I.

    2013-02-01

    This paper presents the results of methane measurements in water and sediments, first performed along the north western continental slope and abyssal plain of the Sea of Japan. Methane concentrations in the study area were very low. However, some features of its distribution are revealed. The highest dissolved methane concentrations (10-14 nmol kg-1) are characteristic of the pycnocline layer at a depth of 30-50 m in the northern shallow stations. With increasing depth, the methane is reduced to minimum values (0.5-1.0 nmol kg-1). The greatest variability in methane concentrations was observed in the layers at 0-500 m, which can be explained by the hydrodynamic conditions of the environment on the slope. Methane plumes (1.7 and 1.3 nmol kg-1) on the northern section were recorded at the depth of 1250 and 1495 m, respectively. Plumes (1.2 nmol kg-1) are also observed on near bottom layers at the deepest (more than 3000 m) stations. CH4 concentration in bottom sediments is also low (from 1 nmol kg-1 at 7 cm level to 752 nmol kg-1 at the 53 cm level of the core sediment in the northern part). Reduced sediments in the southern part of the study region have maximal methane concentration for sediment (2549 nmol kg-1) at the horizon 44 cm bsf (below sea floor) with a smell of H2S. These results assume a close relation of CH4 with sediment properties. A few stations with maximum methane (86-101 nmol kg-1) in the surface sediment layer are at the foot of a steep slope. Herewith, the highest abundance of some pericarid species was observed at the points with the highest values of methane concentrations in the surface sediment layer. Weak methane seepage can cause anoxic marine waters. Methane emission from water to the atmosphere is low because its concentration is close to equilibrium in surface water. An improved formula for calculating the methane flux of water into the atmosphere, taking into account high wind speeds, is presented in the paper.

  13. [Copper in methane oxidation: a review].

    PubMed

    Su, Yao; Kong, Jiao-Yan; Zhang, Xuan; Xia, Fang-Fang; He, Ruo

    2014-04-01

    Methane bio-oxidation plays an important role in the global methane balance and warming mitigation, while copper has a crucial function in methane bio-oxidation. On one side, copper is known to be a key factor in regulating the expression of the genes encoding the two forms of methane monooxygenases (MMOs) and is the essential metal element of the particulate methane monooxygenase (pMMO). On the other side, the content and fractionation of copper in the environment have great effects on the distribution of methanotrophs and their metabolic capability of methane and non-methane organic compounds, as well as on the copper-specific uptake systems in methanotrophs. Thus, it is meaningful to know the role of copper in methane bio-oxidation for comprehensive understanding of this process and is valuable for guiding the application of methanotrophs in greenhouse gas removal and pollution remediation. In this paper, the roles of copper in methane oxidation were reviewed, including the effect of copper on methanotrophic community structure and activity, the expression and activity of MMOs as well as the copper uptake systems in methanotrophs. The future studies of copper and methane oxidation were also discussed.

  14. Photocatalytic conversion of methane to methanol

    SciTech Connect

    Taylor, C.E.; Noceti, R.P.; D`Este, J.R.

    1995-12-31

    A long-term goal of our research group is the exploration of novel pathways for the direct oxidation of methane to liquid fuels, chemicals, and intermediates. The use of three relatively abundant and inexpensive reactants, light, water, and methane, to produce methanol is attractive. The products of reaction, methanol and hydrogen, are both commercially desirable, methanol being used as is or converted to a variety of other chemicals, and the hydrogen could be utilized in petroleum and/or chemical manufacturing. Methane is produced as a by-product of coal gasification. Depending upon reactor design and operating conditions, up to 18% of total gasifier product may be methane. In addition, there are vast proven reserves of geologic methane in the world. Unfortunately, a large fraction of these reserves are in regions where there is little local demand for methane and it is not economically feasible to transport it to a market. There is a global research effort under way in academia, industry, and government to find methods to convert methane to useful, more readily transportable and storable materials. Methanol, the initial product of methane oxidation, is a desirable product of conversion because it retains much of the original energy of the methane while satisfying transportation and storage requirements. Investigation of direct conversion of methane to transportation fuels has been an ongoing effort at PETC for over 10 years. One of the current areas of research is the conversion of methane to methanol, under mild conditions, using light, water, and a semiconductor photocatalyst. The use of three relatively abundant and inexpensive reactants, light, water, and methane, to produce methanol, is attractive. Research in the laboratory is directed toward applying the techniques developed for the photocatalytic splitting of the water and the photochemical conversion of methane.

  15. Methane Uptake in Forest Soils is Driven by Diffusivity and Methane Oxidizer Community Size

    NASA Astrophysics Data System (ADS)

    Sullivan, B. W.; Hart, S. C.; Kolb, T. E.

    2008-12-01

    Upland forest soils are the only known terrestrial biological sink of methane, but the mechanisms controlling methane uptake are poorly understood. Methane uptake is the result of bacterial and archaeal 'methane oxidizer' activity. Temperature, water content, and substrate availability have all been described as potential mechanisms governing methane uptake in soils. We measured methane uptake in soil across two ecological different gradients in an attempt to determine controls on methane uptake in semi-arid soils. We measured the uptake of atmospheric methane in situ across a gradient of northern Arizona, USA ponderosa pine forest disturbance. This gradient included an unthinned, unburned forest, a mechanically thinned forest, and a former forest site that completely burned 10 years prior to measurements. In laboratory incubations, we measured potential methane uptake across a soil chronosequence of basalt-cinder derived soils from 0.001 to 3 million years old by exposing soils to 10x ambient levels of methane. This chronosequence has a gradient of soil texture, which will influence the air filled pore space, and consequently methane diffusion. Both gradients experience distinct dry and wet seasons during the growing season. Our field measurements suggest that methane uptake is greatest when the forest floor is thinnest and the soil is most dry. Our laboratory incubations suggest that, during the dry season, potential methane uptake is driven by diffusion, but that during the wet season potential methane uptake is a function of methane oxidizer community size. Methane uptake patterns across both gradients demonstrates the importance of diffusion and methane oxidizer community size as codominant controlling factors.

  16. Estimation of methane emission rate changes using age-defined waste in a landfill site.

    PubMed

    Ishii, Kazuei; Furuichi, Toru

    2013-09-01

    Long term methane emissions from landfill sites are often predicted by first-order decay (FOD) models, in which the default coefficients of the methane generation potential and the methane generation rate given by the Intergovernmental Panel on Climate Change (IPCC) are usually used. However, previous studies have demonstrated the large uncertainty in these coefficients because they are derived from a calibration procedure under ideal steady-state conditions, not actual landfill site conditions. In this study, the coefficients in the FOD model were estimated by a new approach to predict more precise long term methane generation by considering region-specific conditions. In the new approach, age-defined waste samples, which had been under the actual landfill site conditions, were collected in Hokkaido, Japan (in cold region), and the time series data on the age-defined waste sample's methane generation potential was used to estimate the coefficients in the FOD model. The degradation coefficients were 0.0501/y and 0.0621/y for paper and food waste, and the methane generation potentials were 214.4 mL/g-wet waste and 126.7 mL/g-wet waste for paper and food waste, respectively. These coefficients were compared with the default coefficients given by the IPCC. Although the degradation coefficient for food waste was smaller than the default value, the other coefficients were within the range of the default coefficients. With these new coefficients to calculate methane generation, the long term methane emissions from the landfill site was estimated at 1.35×10(4)m(3)-CH(4), which corresponds to approximately 2.53% of the total carbon dioxide emissions in the city (5.34×10(5)t-CO(2)/y).

  17. Methane emissions from boreal and tropical forest ecosystems derived from in-situ measurements

    NASA Astrophysics Data System (ADS)

    Sinha, V.; Williams, J.; Crutzen, P. J.; Lelieveld, J.

    2007-09-01

    Methane is a climatologically important greenhouse gas, which plays a key role in regulating water vapour in the stratosphere and hydroxyl radicals in the troposphere. Recent findings that vegetation emits methane have stimulated efforts to ascertain the impact of this source on the global budget. In this work, we present the results of high frequency (ca. 1 min-1) methane measurements conducted in the boreal forests of Finland and the tropical forests of Suriname, in April-May, 2005 and October 2005 respectively. The measurements were performed using a gas chromatograph - flame ionization detector (GC-FID). The average of the median mixing ratios during a typical diel cycle were 1.83 μmol mol-1 and 1.74 μmol mol-1 for the boreal forest ecosystem and tropical forest ecosystem respectively, with remarkable similarity in the time series of both the boreal and tropical diel profiles. Night time methane emission flux of the boreal forest ecosystem, calculated from the increase of methane during the night and measured nocturnal boundary layer heights yields a flux of (3.62±0.87)×1011 molecules cm-2 s-1(or 45.5±11 Tg CH4 yr-1 for global boreal forest area). This is a source contribution of circa 8% of the global methane budget. These results highlight the importance of the boreal and tropical forest ecosystems for the global budget of methane. The results are also discussed in the context of recent work reporting high methane mixing ratios over tropical forests using space borne near infra-red spectroscopy measurements.

  18. Dairy methane generator. Final report

    SciTech Connect

    Williams, T.B.

    1981-09-30

    Details of the work completed under this contract are presented. During the winter of 1979-80 three students enrolled, in the Mechanical Design Engineering Technology program at the Pennsylvania State University's Capitol Campus (Middletown, PA), undertook a feasibility study for the utilization of the manure generated by the dairy cows located on Mr. Thomas B. Williams farm for the generation and use of methane gas. The results of their effort was the design of an Anaerobic Digester/Electric Generation System. This preliminary designed system was later changed and improved by another group of P.S.U. MDET students in the spring of 1980. The final design included working drawings and an economic analysis of the estimated investment necessary to complete the Methane Generator/Electric Power Generation System.

  19. Widespread methane leakage from the sea floor on the northern US Atlantic margin

    NASA Astrophysics Data System (ADS)

    Skarke, A.; Ruppel, C.; Kodis, M.; Brothers, D.; Lobecker, E.

    2014-09-01

    Methane emissions from the sea floor affect methane inputs into the atmosphere, ocean acidification and de-oxygenation, the distribution of chemosynthetic communities and energy resources. Global methane flux from seabed cold seeps has only been estimated for continental shelves, at 8 to 65 Tg CH4 yr-1, yet other parts of marine continental margins are also emitting methane. The US Atlantic margin has not been considered an area of widespread seepage, with only three methane seeps recognized seaward of the shelf break. However, massive upper-slope seepage related to gas hydrate degradation has been predicted for the southern part of this margin, even though this process has previously only been recognized in the Arctic. Here we use multibeam water-column backscatter data that cover 94,000 km2 of sea floor to identify about 570 gas plumes at water depths between 50 and 1,700 m between Cape Hatteras and Georges Bank on the northern US Atlantic passive margin. About 440 seeps originate at water depths that bracket the updip limit for methane hydrate stability. Contemporary upper-slope seepage there may be triggered by ongoing warming of intermediate waters, but authigenic carbonates observed imply that emissions have continued for more than 1,000 years at some seeps. Extrapolating the upper-slope seep density on this margin to the global passive margin system, we suggest that tens of thousands of seeps could be discoverable.

  20. Widespread methane leakage from the sea floor on the northern US Atlantic margin

    USGS Publications Warehouse

    Skarke, Adam; Ruppel, Carolyn; Kodis, Mali'o; Brothers, Daniel S.; Lobecker, Elizabeth A.

    2014-01-01

    Methane emissions from the sea floor affect methane inputs into the atmosphere, ocean acidification and de-oxygenation, the distribution of chemosynthetic communities and energy resources. Global methane flux from seabed cold seeps has only been estimated for continental shelves, at 8 to 65 Tg CH4 yr−1, yet other parts of marine continental margins are also emitting methane. The US Atlantic margin has not been considered an area of widespread seepage, with only three methane seeps recognized seaward of the shelf break. However, massive upper-slope seepage related to gas hydrate degradation has been predicted for the southern part of this margin, even though this process has previously only been recognized in the Arctic. Here we use multibeam water-column backscatter data that cover 94,000 km2 of sea floor to identify about 570 gas plumes at water depths between 50 and 1,700 m between Cape Hatteras and Georges Bank on the northern US Atlantic passive margin. About 440 seeps originate at water depths that bracket the updip limit for methane hydrate stability. Contemporary upper-slope seepage there may be triggered by ongoing warming of intermediate waters, but authigenic carbonates observed imply that emissions have continued for more than 1,000 years at some seeps. Extrapolating the upper-slope seep density on this margin to the global passive margin system, we suggest that tens of thousands of seeps could be discoverable.

  1. Opaque closed chambers underestimate methane fluxes of Phragmites australis (Cav.) Trin. ex Steud.

    PubMed

    Günther, Anke; Jurasinski, Gerald; Huth, Vytas; Glatzel, Stephan

    2014-04-01

    Closed chamber measurements for methane emission estimation are often carried out with opaque chambers to avoid heating of the headspace. However, mainly in wetlands, some plants possess an internal convective gas transport which quickly responds to changes in irradiation. These plants have also been found to often channel a large part of the released methane in temperate fens. We compare methane fluxes derived from transparent versus opaque chambers on Carex-, Phragmites-, and Typha-dominated stands of a temperate fen. Transparent chamber fluxes almost doubled opaque chamber fluxes in the convective transporting Phragmites stand. In Typha, a trend of higher fluxes determined with the transparent chambers was detectable, whereas in Carex, transparent and opaque chamber fluxes did not differ significantly. Thus, opaque chambers bias the outcome of methane measurements, depending on dominant vegetation. We recommend the use of transparent chambers when determining emissions of convective plants or extrapolating fluxes to larger scales.

  2. ‘Baseline-offset’ scheme for a methane remote sensor based on wavelength modulation spectroscopy

    NASA Astrophysics Data System (ADS)

    Ding, Wuwen; Sun, Liqun; Yi, Luying; Zhang, Enyao

    2016-08-01

    A new scheme for methane remote sensing is presented. Unlike a standard published remote sensor based on wavelength modulation spectroscopy (WMS), a reference cell is inserted into the measuring optical path. This scheme inherits the merits of WMS and can achieve high signal-to-noise ratio especially in a low concentration environment. Experimental results show that the presented remote sensor can detect ambient methane with a detection limit of 5 ppm m (parts per million · meter) at a distance of 10 m and 16 ppm m for 20 m. A methane leak test shows the sensor can detect a methane leak of 15 ml min-1 within a range up to 37 m.

  3. Methane production from mixed tropical savanna and forest vegetation in Venezuela

    NASA Astrophysics Data System (ADS)

    Crutzen, P. J.; Sanhueza, E.; Brenninkmeijer, C. A. M.

    2006-04-01

    Measurements of methane concentrations in the boundary layer in the northern part of the Guayana shield, Venezuela, during the wet season (October 1988), showed the presence of substantial methane surface emissions. The measuring site is within the savanna climate region, but is affected by emissions from savanna and forest vegetation. From day versus night concentration measurements, with higher concentrations during night, a methane source strength near the site of 3-7×1011 molecules/cm2/s can be estimated, which includes emissions from small tracts of flooded soils, termites and especially tropical vegetation. Extrapolated to the entire savanna, this may imply a methane source of ~30-60 Tg yr-1 similar to the one calculated for tropical vegetation on the basis of recently published in vitro plant emission experiments by Keppler et al. (2006), which indicate emissions of ~30 Tg yr-1 for tropical savannas and grasslands and ~78 Tg yr-1 for tropical forests.

  4. Remote detection of methane with a 1.66-microm diode laser.

    PubMed

    Uehara, K; Tai, H

    1992-02-20

    High-sensitivity real-time remote detection of methane in air with a 1.66-microm distributed-feedback diode laser operating at room temperature is demonstrated by laboratory simulations. The laser current was modulated at a high frequency of ~5 MHz, and the laser-center frequency was locked onto a methane-absorption line. The laser light directed toward the probed region was received after one-way transmission or further reflection from a topographic target. The methane absorption was detected by the second-harmonic component in the optical-power variation. The minimum-detectable concentration-path-length product in the transmission scheme was 0.3 part in 10(6) m for a signal averaging time of 1.3 s. In the reflection scheme, the amount of methane could be measured from the ratio of the fundamental and second-harmonic signal intensities independently of the received power.

  5. Overestimating climate warming-induced methane gas escape from the seafloor by neglecting multiphase flow dynamics

    NASA Astrophysics Data System (ADS)

    Stranne, C.; O'Regan, M.; Jakobsson, M.

    2016-08-01

    Continental margins host large quantities of methane stored partly as hydrates in sediments. Release of methane through hydrate dissociation is implicated as a possible feedback mechanism to climate change. Large-scale estimates of future warming-induced methane release are commonly based on a hydrate stability approach that omits dynamic processes. Here we use the multiphase flow model TOUGH + hydrate (T + H) to quantitatively investigate how dynamic processes affect dissociation rates and methane release. The simulations involve shallow, 20-100 m thick hydrate deposits, forced by a bottom water temperature increase of 0.03°C yr-1 over 100 years. We show that on a centennial time scale, the hydrate stability approach can overestimate gas escape quantities by orders of magnitude. Our results indicate a time lag of > 40 years between the onset of warming and gas escape, meaning that recent climate warming may soon be manifested as widespread gas seepages along the world's continental margins.

  6. Dissolved methane in New York groundwater, 1999-2011

    USGS Publications Warehouse

    Kappel, William M.; Nystrom, Elizabeth A.

    2012-01-01

    New York State is underlain by numerous bedrock formations of Cambrian to Devonian age that produce natural gas and to a lesser extent oil. The first commercial gas well in the United States was dug in the early 1820s in Fredonia, south of Buffalo, New York, and produced methane from Devonian-age black shale. Methane naturally discharges to the land surface at some locations in New York. At Chestnut Ridge County Park in Erie County, just south of Buffalo, N.Y., several surface seeps of natural gas occur from Devonian black shale, including one behind a waterfall. Methane occurs locally in the groundwater of New York; as a result, it may be present in drinking-water wells, in the water produced from those wells, and in the associated water-supply systems (Eltschlager and others, 2001). The natural gas in low-permeability bedrock formations has not been accessible by traditional extraction techniques, which have been used to tap more permeable sandstone and carbonate bedrock reservoirs. However, newly developed techniques involving horizontal drilling and high-volume hydraulic fracturing have made it possible to extract previously inaccessible natural gas from low-permeability bedrock such as the Marcellus and Utica Shales. The use of hydraulic fracturing to release natural gas from these shale formations has raised concerns with water-well owners and water-resource managers across the Marcellus and Utica Shale region (West Virginia, Pennsylvania, New York and parts of several other adjoining States). Molofsky and others (2011) documented the widespread natural occurrence of methane in drinking-water wells in Susquehanna County, Pennsylvania. In the same county, Osborn and others (2011) identified elevated methane concentrations in selected drinking-water wells in the vicinity of Marcellus gas-development activities, although pre-development samples were not available for comparison. In order to manage water resources in areas of gas-well drilling and hydraulic

  7. Titan's Methane Cycle is Closed

    NASA Astrophysics Data System (ADS)

    Hofgartner, J. D.; Lunine, J. I.

    2013-12-01

    Doppler tracking of the Cassini spacecraft determined a polar moment of inertia for Titan of 0.34 (Iess et al., 2010, Science, 327, 1367). Assuming hydrostatic equilibrium, one interpretation is that Titan's silicate core is partially hydrated (Castillo-Rogez and Lunine, 2010, Geophys. Res. Lett., 37, L20205). These authors point out that for the core to have avoided complete thermal dehydration to the present day, at least 30% of the potassium content of Titan must have leached into an overlying water ocean by the end of the core overturn. We calculate that for probable ammonia compositions of Titan's ocean (compositions with greater than 1% ammonia by weight), that this amount of potassium leaching is achievable via the substitution of ammonium for potassium during the hydration epoch. Formation of a hydrous core early in Titan's history by serpentinization results in the loss of one hydrogen molecule for every hydrating water molecule. We calculate that complete serpentinization of Titan's core corresponds to the release of more than enough hydrogen to reconstitute all of the methane atoms photolyzed throughout Titan's history. Insertion of molecular hydrogen by double occupancy into crustal clathrates provides a storage medium and an opportunity for ethane to be converted back to methane slowly over time--potentially completing a cycle that extends the lifetime of methane in Titan's surface atmosphere system by factors of several to an order of magnitude over the photochemically-calculated lifetime.

  8. Short-term variations of methane concentrations and methanotrophic activity in a coastal inlet (Eckernförde Bay, Germany)

    NASA Astrophysics Data System (ADS)

    Richner, Dominik; Niemann, Helge; Steinle, Lea; Schneider von Deimling, Jens; Urban, Peter; Hoffmann, Jasper; Schmidt, Mark; Treude, Tina; Lehmann, Moritz

    2016-04-01

    Large quantities of methane are produced in anoxic sediments of continental margins and may be liberated into the overlying water column and, potentially, into the atmosphere. However, a sequence of microbially mediated methane oxidation pathways in sediments and the water column mitigate the contribution of oceans to the atmospheric methane budget. Of particular importance are methanotrophic bacteria in the water column that mediate the aerobic oxidation of methane (MOx), and represent the final sink for methane before its release to the atmosphere where it acts as a potent greenhouse gas. However methane cycling in (aerobic) marine waters is not well constrained. Particularly little is known about spatiotemporal aspects of MOx activity and the underlying key physical, chemical and biological factors. Here we show results from our investigations on methane dynamics on very short time scales of hours to days in the Eckernförde Bay (E-Bay), a costal inlet of the Baltic Sea in northern Germany featuring seasonal bottom water hypoxia/anoxia. In autumn 2014, we observed highly spatiotemporal variations in water column methane contents and MOx activity: Anoxic bottom waters in a trough in the northern part of the bay contained extremely high methane concentrations of up to 800 nM, which sharply declined at the midwater redox interface (methane remained supersaturated with respect to the atmospheric equilibrium throughout the water column at all times). The methane decrease at the redox interface was related to highly active MOx communities consuming methane under microoxic conditions at rates of up 40 nM/d. About 12 hours later, the methane content and the extend of bottom water anoxia was much lower and MOx activity was highly reduced in the northern part but strongly elevated in the southern part of the bay. A few days later, bottom water anoxia, methane loading and MOx activity was partially re-established. In this contribution, we will discuss potential forcing

  9. Methane Recovery from Hydrate-bearing Sediments

    SciTech Connect

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with

  10. Simulations of Carbon Dioxide Storage and Methane Production from Guest Molecule Exchange of Hydrates Using Reactive Transport Modeling and Gibbs Energy Minimization

    NASA Astrophysics Data System (ADS)

    Darnell, K.; Flemings, P. B.

    2015-12-01

    We investigate guest molecule exchange of hydrates as a method for simultaneous carbon dioxide storage and methane production. We simulate N2/CO2 binary gas mixture injection into marine and terrestrial methane hydrate bearing sediments. Different compositions of the injected gas can lead to four possible outcomes: 1) Injected gas flows downstream past methane hydrate and does not alter the methane hydrate, 2) Injected gas causes complete dissociation of methane hydrate, which creates a gas mixture of methane and injected gas that flows downstream, 3) Injected gas causes complete dissociation of methane hydrate with flow of methane gas downstream and all injected gas replaces methane in the hydrate cage, 4) Injected gas causes partial dissociation of methane hydrate with some replacement of methane in the hydrate cage and downstream flow of a methane and injected gas mixture. We focus on how composition of injected gas affects the outcome of the injection process, and then determine the optimal injection mixture of N2/CO2 for carbon dioxide storage and methane production. Our simulations combine dynamic flash calculations using the Gibbs energy minimization of Ballard and Sloan (2004) with 1-d reactive transport modeling. This work provides insight into the efficiency of the guest molecule exchange process in methane hydrate systems. Our results can be directly incorporated into simulations of more complex geometries and field settings such as the Ignik Sikumi Gas Hydrate Field Trial. ReferencesBallard, A. L., and Sloan, E. D. (2004). The next generation of hydrate prediction: Part III. Gibbs energy minimization formalism. Fluid phase equilibria, 218(1), 15-31.

  11. Evidence for methane in Martian meteorites

    PubMed Central

    Blamey, Nigel J. F.; Parnell, John; McMahon, Sean; Mark, Darren F.; Tomkinson, Tim; Lee, Martin; Shivak, Jared; Izawa, Matthew R. M.; Banerjee, Neil R.; Flemming, Roberta L.

    2015-01-01

    The putative occurrence of methane in the Martian atmosphere has had a major influence on the exploration of Mars, especially by the implication of active biology. The occurrence has not been borne out by measurements of atmosphere by the MSL rover Curiosity but, as on Earth, methane on Mars is most likely in the subsurface of the crust. Serpentinization of olivine-bearing rocks, to yield hydrogen that may further react with carbon-bearing species, has been widely invoked as a source of methane on Mars, but this possibility has not hitherto been tested. Here we show that some Martian meteorites, representing basic igneous rocks, liberate a methane-rich volatile component on crushing. The occurrence of methane in Martian rock samples adds strong weight to models whereby any life on Mars is/was likely to be resident in a subsurface habitat, where methane could be a source of energy and carbon for microbial activity. PMID:26079798

  12. Evidence for methane in Martian meteorites

    NASA Astrophysics Data System (ADS)

    Blamey, Nigel J. F.; Parnell, John; McMahon, Sean; Mark, Darren F.; Tomkinson, Tim; Lee, Martin; Shivak, Jared; Izawa, Matthew R. M.; Banerjee, Neil R.; Flemming, Roberta L.

    2015-06-01

    The putative occurrence of methane in the Martian atmosphere has had a major influence on the exploration of Mars, especially by the implication of active biology. The occurrence has not been borne out by measurements of atmosphere by the MSL rover Curiosity but, as on Earth, methane on Mars is most likely in the subsurface of the crust. Serpentinization of olivine-bearing rocks, to yield hydrogen that may further react with carbon-bearing species, has been widely invoked as a source of methane on Mars, but this possibility has not hitherto been tested. Here we show that some Martian meteorites, representing basic igneous rocks, liberate a methane-rich volatile component on crushing. The occurrence of methane in Martian rock samples adds strong weight to models whereby any life on Mars is/was likely to be resident in a subsurface habitat, where methane could be a source of energy and carbon for microbial activity.

  13. Emerging topics in marine methane biogeochemistry.

    PubMed

    Valentine, David L

    2011-01-01

    Our knowledge of physical, chemical, geological and biological processes affecting methane in the ocean and in underlying sediments is expanding at a rapid pace. On first inspection, marine methane biogeochemistry appears simple: Methane distribution in sediment is set by the deposition pattern of organic material, and the balance of sources and sinks keeps its concentration low in most waters. However, recent research reveals that methane is affected by complex biogeochemical processes whose interactions are understood only at a superficial level. Such processes span the deep-subsurface, near subsurface, and ocean waters, and relate primarily to the production, consumption, and transport of methane. The purpose of this synthesis is to examine select processes within the framework of methane biogeochemistry, to formulate hypotheses on how they might operate and interact with one another, and to consider their controls.

  14. Evidence for methane in Martian meteorites.

    PubMed

    Blamey, Nigel J F; Parnell, John; McMahon, Sean; Mark, Darren F; Tomkinson, Tim; Lee, Martin; Shivak, Jared; Izawa, Matthew R M; Banerjee, Neil R; Flemming, Roberta L

    2015-06-16

    The putative occurrence of methane in the Martian atmosphere has had a major influence on the exploration of Mars, especially by the implication of active biology. The occurrence has not been borne out by measurements of atmosphere by the MSL rover Curiosity but, as on Earth, methane on Mars is most likely in the subsurface of the crust. Serpentinization of olivine-bearing rocks, to yield hydrogen that may further react with carbon-bearing species, has been widely invoked as a source of methane on Mars, but this possibility has not hitherto been tested. Here we show that some Martian meteorites, representing basic igneous rocks, liberate a methane-rich volatile component on crushing. The occurrence of methane in Martian rock samples adds strong weight to models whereby any life on Mars is/was likely to be resident in a subsurface habitat, where methane could be a source of energy and carbon for microbial activity.

  15. Winter Video Series Coming in January | Poster

    Cancer.gov

    The Scientific Library’s annual Summer Video Series was so successful that it will be offering a new Winter Video Series beginning in January. For this inaugural event, the staff is showing the eight-part series from National Geographic titled “American Genius.” 

  16. Methane Line Intensities: Near and Far IR

    NASA Astrophysics Data System (ADS)

    Brown, Linda R.; Devi, V. Malathy; Wishnow, Edward H.; Sung, Keeyoon; Crawford, Timothy J.; Mantz, Arlan W.; Smith, Mary Ann H.; Predoi-Cross, Adriana; Benner, D. Chris

    2014-11-01

    Accurate knowledge of line intensities is crucial input for radiance calculations to interpret atmospheric observations of planets and moons. We have therefore undertaken extensive laboratory studies to measure the methane spectrum line-by-line in order to improve theoretical quantum mechanical modeling for molecular spectroscopy databases (e. g. HITRAN and GEISA) used by planetary astronomers. Preliminary results will be presented for selected ro-vibrational transitions in both the near-IR (1.66 and 2.2 - 2.4 microns) and the far-IR (80 - 120 microns) regions. For this, we have recorded high-resolution spectra (instrumental resolving power: 1,300,000 (NIR) and 10,000 (FIR)) with the Bruker 125HR Fourier transform spectrometer at JPL using isotopically-enriched 12CH4 and 13CH4, as well as normal methane samples. For the NIR wavelengths, three different absorption cells have been employed to achieve sample temperatures ranging from 78 K to 299 K: 1) a White cell set to a path length of 13.09 m for room temperature data, 2) a single-pass 0.2038 m cold cell and 3) a new coolable Herriott cell with a fixed 20.941 m optical path and configured for the first time to a FT-IR spectrometer. For the Far-IR, another coolable absorption chamber set to a 52 m optical path has been used. These new experiments and intensity measurements will be presented and discussed.Part of the research described in this paper was performed at the Jet Propulsion Laboratory, California Institute of Technology, the University of California, Berkeley, Connecticut College, and NASA Langley under contracts and grants with the National Aeronautics and Space Administration. A. Predoi-Cross and her research group have been supported by the National Science and Engineering Research Council of Canada.

  17. Investigating physical controls on methane and carbon ...

    EPA Pesticide Factsheets

    Reservoirs are a globally important source of carbon to the atmosphere. Several recent studies have found that both carbon dioxide (CO2) and methane (CH4) emissions from reservoirs are currently being underestimated by up to 50%. This underestimation is due to inadequate characterization of both spatial variability (e.g. ebullition and CO2 surface water concentration hot spots) and temporal variability (e.g. diurnal patterns, seasonal differences, and pulses driven by weather events or other disturbances). Use of the eddy covariance technique to measure CO2 and CH4 fluxes over reservoirs can help address the issues of spatial and temporal coverage. Here we present results from two eddy covariance measurement campaigns monitoring CO2 and CH4 fluxes over reservoirs in southwestern Ohio, US. The first campaign was part of a study looking at the effects of water level drawdown on reservoir methane ebullition. The eddy covariance results showed a clear response of CH4 emissions to the change in water level, increasing from a baseline of 3440 mg CH4 m-2 d-1 to a maximum of 6740 mg CH4 m-2 d-1 during the drawdown. These results agreed well with the emission rates measured via bubble samplers deployed in the same area as the tower. Conversely, the CO2 fluxes did not show a strong response to the drawdown. In the second campaign the eddy covariance system was deployed longer term at a mid-sized (2.4 km2) lake. Analyses of diurnal patterns in CO2 and CH4 emissions as well

  18. The methane cycle in ferruginous Lake Matano.

    PubMed

    Crowe, S A; Katsev, S; Leslie, K; Sturm, A; Magen, C; Nomosatryo, S; Pack, M A; Kessler, J D; Reeburgh, W S; Roberts, J A; González, L; Douglas Haffner, G; Mucci, A; Sundby, B; Fowle, D A

    2011-01-01

    In Lake Matano, Indonesia, the world's largest known ferruginous basin, more than 50% of authigenic organic matter is degraded through methanogenesis, despite high abundances of Fe (hydr)oxides in the lake sediments. Biogenic CH₄ accumulates to high concentrations (up to 1.4 mmol L⁻¹) in the anoxic bottom waters, which contain a total of 7.4 × 10⁵ tons of CH₄. Profiles of dissolved inorganic carbon (ΣCO₂) and carbon isotopes (δ¹³C) show that CH₄ is oxidized in the vicinity of the persistent pycnocline and that some of this CH₄ is likely oxidized anaerobically. The dearth of NO₃⁻ and SO₄²⁻ in Lake Matano waters suggests that anaerobic methane oxidation may be coupled to the reduction of Fe (and/or Mn) (hydr)oxides. Thermodynamic considerations reveal that CH₄ oxidation coupled to Fe(III) or Mn(III/IV) reduction would yield sufficient free energy to support microbial growth at the substrate levels present in Lake Matano. Flux calculations imply that Fe and Mn must be recycled several times directly within the water column to balance the upward flux of CH₄. 16S gene cloning identified methanogens in the anoxic water column, and these methanogens belong to groups capable of both acetoclastic and hydrogenotrophic methanogenesis. We find that methane is important in C cycling, even in this very Fe-rich environment. Such Fe-rich environments are rare on Earth today, but they are analogous to conditions in the ferruginous oceans thought to prevail during much of the Archean Eon. By analogy, methanogens and methanotrophs could have formed an important part of the Archean Ocean ecosystem.

  19. Carbon isotope fractionation during microbial methane oxidation

    NASA Astrophysics Data System (ADS)

    Barker, James F.; Fritz, Peter

    1981-09-01

    Methane, a common trace constituent of groundwaters, occasionally makes up more than 20% of the total carbon in groundwaters1,2. In aerobic environments CH4-rich waters can enable microbial food chain supporting a mixed culture of bacteria with methane oxidation as the primary energy source to develop3. Such processes may influence the isotopic composition of the residual methane and because 13C/12C analyses have been used to characterize the genesis of methanes found in different environments, an understanding of the magnitude of such effects is necessary. In addition, carbon dioxide produced by the methane-utilizing bacteria can be added to the inorganic carbon pool of affected groundwaters. We found carbon dioxide experimentally produced by methane-utilizing bacteria to be enriched in 12C by 5.0-29.6‰, relative to the residual methane. Where methane-bearing groundwaters discharged into aerobic environments microbial methane oxidation occurred, with the residual methane becoming progressively enriched in 13C. Various models have been proposed to explain the 13C/12C and 14C content of the dissolved inorganic carbon (DIC) of groundwaters in terms of additions or losses during flow in the subsurface4,5. The knowledge of both stable carbon isotope ratios in various pools and the magnitude of carbon isotope fractionation during various processes allows geochemists to use the 13C/12C ratio of the DIC along with water chemistry to estimate corrected 14C groundwater ages4,5. We show here that a knowledge of the carbon isotope fractionation between CH4 and CO2 during microbial methane-utilization could modify such models for application to groundwaters affected by microbial methane oxidation.

  20. Methane Pyrolysis and Disposing Off Resulting Carbon

    NASA Technical Reports Server (NTRS)

    Sharma, P. K.; Rapp, D.; Rahotgi, N. K.

    1999-01-01

    Sabatier/Electrolysis (S/E) is a leading process for producing methane and oxygen for application to Mars ISPP. One significant problem with this process is that it produces an excess of methane for combustion with the amount of oxygen that is produced. Therefore, one must discard roughly half of the methane to obtain the proper stoichiometric methane/oxygen mixture for ascent from Mars. This is wasteful of hydrogen, which must be brought from Earth and is difficult to transport to Mars and store on Mars. To reduced the problem of transporting hydrogen to Mars, the S/E process can be augmented by another process which reduces overall hydrogen requirement. Three conceptual approaches for doing this are (1) recover hydrogen from the excess methane produced by the S/E process, (2) convert the methane to a higher hydrocarbon or other organic with a lower H/C ratio than methane, and (3) use a separate process (such as zirconia or reverse water gas shift reaction) to produce additional oxygen, thus utilizing all the methane produced by the Sabatier process. We report our results here on recovering hydrogen from the excess methane using pyrolysis of methane. Pyrolysis has the advantage that it produces almost pure hydrogen, and any unreacted methane can pass through the S/E process reactor. It has the disadvantage that disposing of the carbon produced by pyrolysis presents difficulties. Hydrogen may be obtained from methane by pyrolysis in the temperature range 10000-12000C. The main reaction products are hydrogen and carbon, though very small amounts of higher hydrocarbons, including aromatic hydrocarbons are formed. The conversion efficiency is about 95% at 12000C. One needs to distinguish between thermodynamic equilibrium conversion and conversion limited by kinetics in a finite reactor.

  1. Methane storage in dry water gas hydrates.

    PubMed

    Wang, Weixing; Bray, Christopher L; Adams, Dave J; Cooper, Andrew I

    2008-09-03

    Dry water stores 175 v(STP)/v methane at 2.7 MPa and 273.2 K in a hydrate form which is close to the Department of Energy volumetric target for methane storage. Dry water is a silica-stabilized free-flowing powder (95% wt water), and fast methane uptakes were observed (90% saturation uptake in 160 min with no mixing) as a result of the relatively large surface-to-volume ratio of this material.

  2. Ebullitive methane emissions from oxygenated wetland streams.

    PubMed

    Crawford, John T; Stanley, Emily H; Spawn, Seth A; Finlay, Jacques C; Loken, Luke C; Striegl, Robert G

    2014-11-01

    Stream and river carbon dioxide emissions are an important component of the global carbon cycle. Methane emissions from streams could also contribute to regional or global greenhouse gas cycling, but there are relatively few data regarding stream and river methane emissions. Furthermore, the available data do not typically include the ebullitive (bubble-mediated) pathway, instead focusing on emission of dissolved methane by diffusion or convection. Here, we show the importance of ebullitive methane emissions from small streams in the regional greenhouse gas balance of a lake and wetland-dominated landscape in temperate North America and identify the origin of the methane emitted from these well-oxygenated streams. Stream methane flux densities from this landscape tended to exceed those of nearby wetland diffusive fluxes as well as average global wetland ebullitive fluxes. Total stream ebullitive methane flux at the regional scale (103 Mg C yr(-1) ; over 6400 km(2) ) was of the same magnitude as diffusive methane flux previously documented at the same scale. Organic-rich stream sediments had the highest rates of bubble release and higher enrichment of methane in bubbles, but glacial sand sediments also exhibited high bubble emissions relative to other studied environments. Our results from a database of groundwater chemistry support the hypothesis that methane in bubbles is produced in anoxic near-stream sediment porewaters, and not in deeper, oxygenated groundwaters. Methane interacts with other key elemental cycles such as nitrogen, oxygen, and sulfur, which has implications for ecosystem changes such as drought and increased nutrient loading. Our results support the contention that streams, particularly those draining wetland landscapes of the northern hemisphere, are an important component of the global methane cycle.

  3. Thermal properties of methane gas hydrates

    USGS Publications Warehouse

    Waite, William F.

    2007-01-01

    Gas hydrates are crystalline solids in which molecules of a “guest” species occupy and stabilize cages formed by water molecules. Similar to ice in appearance (fig. 1), gas hydrates are stable at high pressures and temperatures above freezing (0°C). Methane is the most common naturally occurring hydrate guest species. Methane hydrates, also called simply “gas hydrates,” are extremely concentrated stores of methane and are found in shallow permafrost and continental margin sediments worldwide. Brought to sea-level conditions, methane hydrate breaks down and releases up to 160 times its own volume in methane gas. The methane stored in gas hydrates is of interest and concern to policy makers as a potential alternative energy resource and as a potent greenhouse gas that could be released from sediments to the atmosphere and ocean during global warming. In continental margin settings, methane release from gas hydrates also is a potential geohazard and could cause submarine landslides that endanger offshore infrastructure. Gas hydrate stability is sensitive to temperature changes. To understand methane release from gas hydrate, the U.S. Geological Survey (USGS) conducted a laboratory investigation of pure methane hydrate thermal properties at conditions relevant to accumulations of naturally occurring methane hydrate. Prior to this work, thermal properties for gas hydrates generally were measured on analog systems such as ice and non-methane hydrates or at temperatures below freezing; these conditions limit direct comparisons to methane hydrates in marine and permafrost sediment. Three thermal properties, defined succinctly by Briaud and Chaouch (1997), are estimated from the experiments described here: - Thermal conductivity, λ: if λ is high, heat travels easily through the material. - Thermal diffusivity, κ: if κ is high, it takes little time for the temperature to rise in the material. - Specific heat, cp: if cp is high, it takes a great deal of heat to

  4. Ebullitive methane emissions from oxygenated wetland streams

    USGS Publications Warehouse

    Crawford, John T.; Stanley, Emily H.; Spawn, Seth A.; Finlay, Jacques C.; Striegl, Robert G.

    2014-01-01

    Stream and river carbon dioxide emissions are an important component of the global carbon cycle. Methane emissions from streams could also contribute to regional or global greenhouse gas cycling, but there are relatively few data regarding stream and river methane emissions. Furthermore, the available data do not typically include the ebullitive (bubble-mediated) pathway, instead focusing on emission of dissolved methane by diffusion or convection. Here, we show the importance of ebullitive methane emissions from small streams in the regional greenhouse gas balance of a lake and wetland-dominated landscape in temperate North America and identify the origin of the methane emitted from these well-oxygenated streams. Stream methane flux densities from this landscape tended to exceed those of nearby wetland diffusive fluxes as well as average global wetland ebullitive fluxes. Total stream ebullitive methane flux at the regional scale (103 Mg C yr−1; over 6400 km2) was of the same magnitude as diffusive methane flux previously documented at the same scale. Organic-rich stream sediments had the highest rates of bubble release and higher enrichment of methane in bubbles, but glacial sand sediments also exhibited high bubble emissions relative to other studied environments. Our results from a database of groundwater chemistry support the hypothesis that methane in bubbles is produced in anoxic near-stream sediment porewaters, and not in deeper, oxygenated groundwaters. Methane interacts with other key elemental cycles such as nitrogen, oxygen, and sulfur, which has implications for ecosystem changes such as drought and increased nutrient loading. Our results support the contention that streams, particularly those draining wetland landscapes of the northern hemisphere, are an important component of the global methane cycle.

  5. Liquid Methane/Liquid Oxygen Injectors for Potential Future Mars Ascent Engines

    NASA Technical Reports Server (NTRS)

    Trinh, Huu Phuoc

    1999-01-01

    Preliminary mission studies for human exploration of Mars have been performed at Marshall Space Flight Center (MSFC). These studies indicate that for chemical rockets only a cryogenic propulsion system would provide high enough performance to be considered for a Mars ascent vehicle. Although the mission is possible with Earth-supplied propellants for this vehicle, utilization of in-situ propellants is highly attractive. This option would significantly reduce the overall mass of launch vehicles. Consequently, the cost of the mission would be greatly reduced because the number and size of the Earth launch vehicle(s) needed for the mission would decrease. NASA/Johnson Space Center has initiated several concept studies of in-situ propellant production plants. Liquid oxygen (LOX) is the primary candidate for an in-situ oxidizer. In-situ fuel candidates include methane (CH4), ethylene (C2H4), and methanol (CH3OH). MSFC initiated a technology development program for a cryogenic propulsion system for the Mars human exploration mission in 1998. One part of this technology program is the effort described here: an evaluation of propellant injection concepts for a LOX/liquid methane Mars Ascent Engine (MAE) with an emphasis on light-weight, high efficiency, reliability, and thermal compatibility. In addition to the main objective, hot-fire tests of the subject injectors will be used to test other key technologies including light-weight combustion chamber materials and advanced ignition concepts. This paper will address the results of the liquid methane/LOX injector study conducted at MSFC. A total of four impinging injector configurations were tested under combustion conditions in a modular combustor test article (MCTA), equipped with optically accessible windows. A series of forty hot-fire tests, which covered a wide range of engine operating conditions with the chamber pressure varied from 320 to 510 and the mixture ratio from 1.5 to 3.5, were performed. The test matrix also

  6. Reconstructing Methane Emission Events in the Arctic Ocean: Observations from the Past to Present

    NASA Astrophysics Data System (ADS)

    Panieri, G.; Mienert, J.; Fornari, D. J.; Torres, M. E.; Lepland, A.

    2015-12-01

    methane discharge was measured, we deployed the CAGE 888 marker as our first step in conducting time series studies to establish temporal variability going forward. This research is partially supported by the Research Council of Norway through its Centres of Excellence funding scheme, project number 223259.

  7. Kansas coal distribution, resources, and potential for coalbed methane

    USGS Publications Warehouse

    Brady, L.L.

    2000-01-01

    Kansas has large amounts of bituminous coal both at the surface and in the subsurface of eastern Kansas. Preliminary studies indicate at least 53 billion tons (48 billion MT) of deep coal [>100 ft (>30 m)] determined from 32 different coal beds. Strippable coal resources at a depth < 100 ft (<30 m) total 2.8 billion tons (2.6 billion MT), and this total is determined from 17 coals. Coal beds present in the Cherokee Group (Middle Pennsylvanian) represent most of these coal resource totals. Deep coal beds with the largest resource totals include the Bevier, Mineral, "Aw" (unnamed coal bed), Riverton, and Weir-Pittsburg coals, all within the Cherokee Group. Based on chemical analyses, coals in the southeastern part of the state are generally high volatile A bituminous, whereas coals in the east-central and northeastern part of the state are high-volatile B bituminous coals. The primary concern of coal beds in Kansas for deep mining or development of coalbed methane is the thin nature [<2 ft (0.6 m)] of most coal beds. Present production of coalbed methane is centered mainly in the southern Wilson/northern Montgomery County area of southeastern Kansas where methane is produced from the Mulky, Weir-Pittsburg, and Riverton coals.

  8. GRI methane chemistry program review meeting

    SciTech Connect

    Dignon, J.; Grant, K.; Grossman, A.; Wuebles, D.; Brasseur, G.; Madronich, S.; Huang, T.; Chang, J.; Lott, B.

    1997-02-01

    Methane is an important greenhouse gas which affects the atmosphere directly by the absorption and re-emission of infrared radiation as well as indirectly, through chemical interactions. Emissions of several important greenhouse gases (GHGS) including methane are increasing, mainly due to human activity. Higher concentrations of these gases in the atmosphere are projected to cause a decrease in the amount of infrared radiation escaping to space, and a subsequent warming of global climate. It is therefore vital to understand not only the causes of increased production of methane and other GHGS, but the effect of higher GHG concentrations on climate, and the possibilities for reductions of these emissions. In GRI-UIUC methane project, the role of methane in climate change and greenhouse gas abatement strategies is being studied using several distinct approaches. First, a detailed treatment of the mechanisms controlling each important methane source and sink, and hence the atmospheric concentration of methane, is being developed for use with the UIUC Integrated Science Assessment Model. The focus of this study is to resolve the factors which determine methane emissions and removal, including human population, land use, energy demand, global temperature, and regional concentrations of the hydroxyl radical, carbon monoxide, nitrous oxides, non-methane hydrocarbons, water vapor, tropospheric and stratospheric ozone.

  9. Methane emission during municipal wastewater treatment.

    PubMed

    Daelman, Matthijs R J; van Voorthuizen, Ellen M; van Dongen, Udo G J M; Volcke, Eveline I P; van Loosdrecht, Mark C M

    2012-07-01

    Municipal wastewater treatment plants emit methane. Since methane is a potent greenhouse gas that contributes to climate change, the abatement of the emission is necessary to achieve a more sustainable urban water management. This requires thorough knowledge of the amount of methane that is emitted from a plant, but also of the possible sources and sinks of methane on the plant. In this study, the methane emission from a full-scale municipal wastewater facility with sludge digestion was evaluated during one year. At this plant the contribution of methane emissions to the greenhouse gas footprint were slightly higher than the CO₂ emissions related to direct and indirect fossil fuel consumption for energy requirements. By setting up mass balances over the different unit processes, it could be established that three quarters of the total methane emission originated from the anaerobic digestion of primary and secondary sludge. This amount exceeded the carbon dioxide emission that was avoided by utilizing the biogas. About 80% of the methane entering the activated sludge reactor was biologically oxidized. This knowledge led to the identification of possible measures for the abatement of the methane emission.

  10. Measurements of methane emissions from landfills using mobile plume method with trace gas and cavity ring-down spectroscopy

    NASA Astrophysics Data System (ADS)

    Mønster, J.; Kjeldsen, P.; Scheutz, C.

    2012-04-01

    Methane is emitted to the atmosphere from both anthropogenic and natural sources. One of the major anthropogenic sources is methane produced by bacteria in anaerobic environments such as rice pads and landfills. Land filling has for many years been the preferred waste disposal method, resulting in a large methane production with a large contribution to the global increase in atmospheric green house gas concentration. Several steps have been taken to reduce the emission of methane from landfills. In order to validate the effect of these steps, a measurement method is needed to quantify methane emissions with a large spatial variation. One method is to use a highly sensitive and fast analytical method, capable of measuring the atmospheric concentration methane downwind from emission areas. Combined with down-wind measurements of a trace gas, emitted at a controlled mass flow rate, the methane emission can be calculated. This method is called the mobile plume method, as the whole plume is measured by doing several transects. In the current study a methane/acetylene analyzer with cavity ring-down spectroscopy detection (Picarro, G2203) was used to estimate methane from a number of Danish landfills. We measured at both active and closed landfills and investigated the difference in methane emission. At landfills where the emissions could have more than one origin, the source strength of the different emission areas was determined by accurate trace gas positioning and choosing appropriate wind speed and measurement distance. To choose these factors, we addressed the uncertainties and limitations of the method with respect to the configuration of the trace gas bottles and the distance between the emission area and the measurement points. Composting of organic material in large piles was done at several of the investigated landfills and where possible, the methane emission from this partly anaerobic digestion was measured as a separate emission.

  11. Steam methane reforming in molten carbonate salt. Final report

    SciTech Connect

    Erickson, D.C.

    1996-05-01

    This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

  12. Pasture-scale measurement of methane emissions of grazing cattle

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Quantifying methane emission of cattle grazing on southern Great Plains pastures using micrometeorology presents several challenges. Cattle are elevated, mobile point sources of methane, so that knowing their location in relation to atmospheric methane concentration measurements becomes critical. St...

  13. Microbial methane turnover at mud volcanoes of the Gulf of Cadiz

    NASA Astrophysics Data System (ADS)

    Niemann, H.; Duarte, J.; Hensen, C.; Omoregie, E.; Magalhães, V. H.; Elvert, M.; Pinheiro, L. M.; Kopf, A.; Boetius, A.

    2006-11-01

    The Gulf of Cadiz is a tectonically active area of the European continental margin and characterised by a high abundance of mud volcanoes, diapirs, pockmarks and carbonate chimneys. During the R/V SONNE expedition "GAP-Gibraltar Arc Processes (SO-175)" in December 2003, several mud volcanoes were surveyed for gas seepage and associated microbial methane turnover. Pore water analyses and methane oxidation measurements on sediment cores recovered from the centres of the mud volcanoes Captain Arutyunov, Bonjardim, Ginsburg, Gemini and a newly discovered, mud volcano-like structure called "No Name" show that thermogenic methane and associated higher hydrocarbons rising from deeper sediment strata are completely consumed within the seabed. The presence of a distinct sulphate-methane transition zone (SMT) overlapping with high sulphide concentrations suggests that methane oxidation is mediated under anaerobic conditions with sulphate as the electron acceptor. Anaerobic oxidation of methane (AOM) and sulphate reduction (SR) rates show maxima at the SMT, which was found between 20 and 200 cm below seafloor at the different mud volcanoes. In comparison to other methane seeps, AOM activity (<383 mmol m -2 year -1) and diffusive methane fluxes (<321 mmol m -2 year -1) in mud volcano sediments of the Gulf of Cadiz are low to mid range. Corresponding lipid biomarker and 16S rDNA clone library analysis give evidence that AOM is mediated by a mixed community of anaerobic methanotrophic archaea and associated sulphate reducing bacteria (SRB) in the studied mud volcanoes. Little is known about the variability of methane fluxes in this environment. Carbonate crusts littering the seafloor of mud volcanoes in the northern part of the Gulf of Cadiz had strongly 13C-depleted lipid signatures indicative of higher seepage activities in the past. However, actual seafloor video observations showed only scarce traces of methane seepage and associated biological processes at the seafloor. No

  14. Variations in methane concentration and isotopic composition in a broad survey of lakes in Arctic Alaska

    NASA Astrophysics Data System (ADS)

    Townsend-Small, A.; Hinkel, K. M.; Arp, C. D.; Beck, R. A.; Frey, K. E.; Grosse, G.; Jones, B. M.; Kim, C.; Lenters, J. D.; Liu, H.

    2013-12-01

    Increasing methane emissions from thawing permafrost may represent a positive feedback to climate warming. Lakes are hotspots for permafrost thaw in summer due to low albedo, and warm, saturated sediments may mobilize a larger portion of thawed organic carbon as methane versus carbon dioxide than terrestrial soils. Thawing permafrost may also accelerate methane emissions via the release of previously trapped natural gas. As part of the Circumarctic Lakes Observation Network (CALON), we have measured dissolved methane and carbon dioxide concentrations and stable isotope composition of methane (carbon-13 and deuterium) in approximately 65 lakes across a latitudinal and longitudinal gradient in Arctic Alaska, with sampling conducted twice a year (April and August) for the past two years. We have two north-to-south sampling transects, one western transect starting in Barrow, AK and heading south to about 70 degrees N, and the other eastern transect heading south from Teshekpuk Lake to the Toolik Lake area. Methane concentrations were an average of ~500 times higher under ice than in open-water conditions, with average under-ice concentrations of about 25 micromoles per liter versus 50 nanomoles per liter in open water. It was also expected that southern lakes would have higher concentrations of methane in summer, consistent with the observed latitudinal temperature gradient. However, the highest methane concentrations were found in lakes in the western portion of the study domain, with no latitudinal trend. Total dissolved methane concentrations observed in summer 2012 ranged from 10 nanomoles per liter to 121 micromoles per liter in the western transect, and 7 nanomoles per liter to 1 micromole per liter in the eastern transect. Stable isotopic analyses indicated that many of the western transect lakes have thermogenic methane, such as that derived from fossil fuel formations. Longer-term sampling will help to indicate whether climate warming causes an increase in

  15. Methane seeps along boundaries of receding glaciers in Alaska and Greenland

    NASA Astrophysics Data System (ADS)

    Walter Anthony, K. M.; Anthony, P. M.; Grosse, G.; Chanton, J.

    2012-12-01

    . 1650-1850 C.E.). Across Alaska, we found a relationship between methane stable isotopes, radiocarbon age, and distance to faults. Faults appear to allow the escape of deeper, more 14C-depleted methane to the atmosphere, whereas seeps away from faults entrained 14C-enriched methane formed in shallower sediments from microbial decomposition of younger organic matter. Additionally, we observed younger subcap methane seeps in lakes of Greenland's Sondrestrom Fjord that were associated with ice-sheet retreat since the LIA. These correlations suggest that in a warming climate, continued disintegration of glaciers, permafrost, and parts of the polar ice sheets will weaken subsurface seals and further open conduits, allowing a transient expulsion of methane currently trapped by the cryosphere cap.

  16. Rainfall, Plant Communities and Methane Fluxes in the Ka`au Crater Wetland, Oahu, Hawaii

    NASA Astrophysics Data System (ADS)

    Grand, M.; Gaidos, E.

    2003-12-01

    reflects a difference in the relative activity of microorganisms in the oxic and anoxic parts of the soil column. We will use environmental molecular technique to compare the microbial community component responsible for the production of methane in the different wetland soils.

  17. Monazite U-Th-Pb EPMA and zircon U-Pb SIMS chronological constraints on the tectonic, metamorphic, and thermal events in the inner part of the Variscan orogen, example from the Sioule series, French Massif Central

    NASA Astrophysics Data System (ADS)

    Do Couto, Damien; Faure, Michel; Augier, Romain; Cocherie, Alain; Rossi, Philippe; Li, Xian-Hua; Lin, Wei

    2016-03-01

    In the northern Variscan French Massif Central, the Sioule metamorphic series exposes from top to bottom the tectonic superposition of the Upper Gneiss Unit (UGU), Lower Gneiss Unit (LGU), and Para-autochthonous Unit (PAU). The nappe stacking developed throughout two prograde syn-metamorphic events: D1 is a top-to-the-SW shearing coeval with a probable Devonian migmatization and D2 is a top-to-the-NW shearing event. Both events were completed before the unconformable deposition of the undeformed and unmetamorphosed "Tufs anthracifères" formation, dated at ca 330 Ma (Late Visean). Furthermore, the UGU experienced a high-pressure metamorphism ascribed to a D0 event during which eclogite or granulite crystallized in several parts of the UGU. Monazite U-Th-Pb and zircon U-Pb SIMS datings were carried out in order to constrain the ages of these D0, D1, and D2 tectono-metamorphic events. These new geochronological results are placed in a P-T-t diagram constructed for the UGU, LGU, and PAU. Monazite sampled in UGU, LGU, and PAU rocks yields similar 365-350 Ma ages consistent with the D2 event dated in other places of the French Massif Central. A zoned monazite grain from a granulitic paragneiss yields 416 ± 15 and 362 ± 14 Ma ages interpreted as those of the D0 and D2 events, respectively. Zircon from the same granulitic paragneiss yields SIMS ages at 343 ± 2 and 328 ± 2 Ma that are interpreted as recrystallization processes associated with post-thickening thermal events, possibly recording the onset of orogenic collapse of the Northern Massif Central. It is worth to note that neither monazite nor zircon recorded the D1 event.

  18. 31 CFR 353.30 - Series EE bonds.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Series EE bonds. 353.30 Section 353... BONDS, SERIES EE AND HH Interest § 353.30 Series EE bonds. Series EE bonds are issued at a discount. The... Department of the Treasury Circular, Public Debt Series No. 1-80 (31 CFR part 351)....

  19. 31 CFR 353.30 - Series EE bonds.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false Series EE bonds. 353.30 Section 353.30... BONDS, SERIES EE AND HH Interest § 353.30 Series EE bonds. Series EE bonds are issued at a discount. The... Department of the Treasury Circular, Public Debt Series No. 1-80 (31 CFR part 351)....

  20. 31 CFR 353.30 - Series EE bonds.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false Series EE bonds. 353.30 Section 353... SAVINGS BONDS, SERIES EE AND HH Interest § 353.30 Series EE bonds. Definitive Series EE bonds were issued... values is found in Department of the Treasury Circular, Fiscal Service Series No. 1-80 (31 CFR part 351)....

  1. Anthracite: A promising new target for coalbed methane exploration

    SciTech Connect

    Murray, D.K.

    1996-06-01

    Until recently, anthracite was not considered to constitute a viable reservoir for coalbed methane production. However, in 1994 commercial rates of methane were recovered from Permo-Carboniferous anthracites in the southern part of the North China Basin complex, in Henan and Shanxi Provinces, People`s Republic of China. During production tests of limited duration, shallow (approximately 1,200 to 1,600 ft) vertical wells flowed at rates exceeding 250 Mcf plus 200 bbls water per day. The coal in these two areas ranges from semi-anthracite to meta-anthracite, with vitrinite reflectances (R{sub o}) varying from 2.4 to 6.6 percent. In-situ gas contents of cored coals are as high as 1,000 s.c.f./short ton. The produced gas consists of approximately 95 percent methane, with traces of CO{sub 2} and other gases. Aggregate coal thickness in both areas is from 35 to 60 ft; some individual beds range from 10 to 20 ft in thickness. Cores of these anthracites are described as fractured and friable, exhibiting fair to good cleat development. These deposits occur in geologically complex areas within a zone of intersecting major tectonic elements that is characterized by high geothermal gradients. An untested but highly prospective anthracite deposit occurs in the South Wales Coal Basin, United Kingdom. Detailed, innovative research underway at the University of Wales, Cardiff, in this deformed Variscan foreland basin is focused on such topics as thrust-related permeability of anthracite and its potential control over coalbed methane production. The highest rank coal and the highest measured gas contents of cores (more than 850 s.c.f./short ton) in the U.K. are found in the northwestern part of the South Wales coal field.

  2. Methane release from pingo-like features across the South Kara Sea shelf, an area of thawing offshore permafrost

    NASA Astrophysics Data System (ADS)

    Serov, Pavel; Portnov, Alexey; Mienert, Jurgen; Semenov, Peter; Ilatovskaya, Polina

    2015-08-01

    The Holocene marine transgression starting at ~19 ka flooded the Arctic shelves driving extensive thawing of terrestrial permafrost. It thereby promoted methanogenesis within sediments, the dissociation of gas hydrates, and the release of formerly trapped gas, with the accumulation in pressure of released methane eventually triggering blowouts through weakened zones in the overlying and thinned permafrost. Here we present a range of geophysical and chemical scenarios for the formation of pingo-like formations (PLFs) leading to potential blowouts. Specifically, we report on methane anomalies from the South Kara Sea shelf focusing on two PLFs imaged from high-resolution seismic records. A variety of geochemical methods are applied to study concentrations and types of gas, its character, and genesis. PLF 1 demonstrates ubiquitously low-methane concentrations (14.2-55.3 ppm) that are likely due to partly unfrozen sediments with an ice-saturated internal core reaching close to the seafloor. In contrast, PLF 2 reveals anomalously high-methane concentrations of >120,000 ppm where frozen sediments are completely absent. The methane in all recovered samples is of microbial and not of thermogenic origin from deep hydrocarbon sources. However, the relatively low organic matter content (0.52-1.69%) of seafloor sediments restricts extensive in situ methane production. As a consequence, we hypothesize that the high-methane concentrations at PLF 2 are due to microbial methane production and migration from a deeper source.

  3. Potential methane production and methane oxidation rates in peatland ecosystems of the Appalachian Mountains, United States

    SciTech Connect

    Yavitt, J.B.; Lang, G.E.; Downey, D.M. )

    1988-09-01

    Potential rates of methane production and carbon dioxide production were measured on 11 dates in 1986 in peat from six plant communities typical of moss-dominated peatlands in the Appalachian Mountains. Annual methane production ranged from 2.7 to 17.5 mol/sq m, and annual carbon dioxide production ranged from 30.6 to 79.0 mol/sq m. The wide range in methane production values among the communities found within a single peatland indicates that obtaining one production value for a peatland may not be appropriate. Low temperature constrained the potential for methane production in winter, while the chemical quality of the peat substrate appears to control methane production in the summer. Methane oxidation was measured throughout the peat profile to a depth of 30 cm. Values for methane oxidation ranged from 0.08 to 18.7 microM/hr among the six plant communities. Aerobic methane-oxidizing bacteria probably mediated most of the activity. On a daily basis during the summer, between 11 and 100% of the methane produced is susceptible to oxidation within the peat column. Pools of dissolved methane and dissolved carbon dioxide in pore waters were less than 0.2 and less than 1.0 mol/sq m, respectively, indicating that methane does not accumulate in the pore waters. Peatlands have been considered as an important source of biologically produced methane. Despite the high rates of methane production, the high rates of methane oxidation dampen the potential emission of methane to the atmosphere. 41 refs., 7 figs., 4 tabs.

  4. Quantitative analysis of anaerobic oxidation of methane (AOM) in marine sediments: A modeling perspective

    NASA Astrophysics Data System (ADS)

    Regnier, P.; Dale, A. W.; Arndt, S.; LaRowe, D. E.; Mogollón, J.; Van Cappellen, P.

    2011-05-01

    Recent developments in the quantitative modeling of methane dynamics and anaerobic oxidation of methane (AOM) in marine sediments are critically reviewed. The first part of the review begins with a comparison of alternative kinetic models for AOM. The roles of bioenergetic limitations, intermediate compounds and biomass growth are highlighted. Next, the key transport mechanisms in multi-phase sedimentary environments affecting AOM and methane fluxes are briefly treated, while attention is also given to additional controls on methane and sulfate turnover, including organic matter mineralization, sulfur cycling and methane phase transitions. In the second part of the review, the structure, forcing functions and parameterization of published models of AOM in sediments are analyzed. The six-orders-of-magnitude range in rate constants reported for the widely used bimolecular rate law for AOM emphasizes the limited transferability of this simple kinetic model and, hence, the need for more comprehensive descriptions of the AOM reaction system. The derivation and implementation of more complete reaction models, however, are limited by the availability of observational data. In this context, we attempt to rank the relative benefits of potential experimental measurements that should help to better constrain AOM models. The last part of the review presents a compilation of reported depth-integrated AOM rates (ΣAOM). These rates reveal the extreme variability of ΣAOM in marine sediments. The model results are further used to derive quantitative relationships between ΣAOM and the magnitude of externally impressed fluid flow, as well as between ΣAOM and the depth of the sulfate-methane transition zone (SMTZ). This review contributes to an improved understanding of the global significance of the AOM process, and helps identify outstanding questions and future directions in the modeling of methane cycling and AOM in marine sediments.

  5. Anaerobic Methane Oxidation in Soils - revealed using 13C-labelled methane tracers

    NASA Astrophysics Data System (ADS)

    Riekie, G. J.; Baggs, E. M.; Killham, K. S.; Smith, J. U.

    2008-12-01

    In marine sediments, anaerobic methane oxidation is a significant biogeochemical process limiting methane flux from ocean to atmosphere. To date, evidence for anaerobic methane oxidation in terrestrial environments has proved elusive, and its significance is uncertain. In this study, an isotope dilution method specifically designed to detect the process of anaerobic methane oxidation in methanogenic wetland soils is applied. Methane emissions of soils from three contrasting permanently waterlogged sites in Scotland are investigated in strictly anoxic microcosms to which 13C- labelled methane is added, and changes in the concentration and 12C/13C isotope ratios of methane and carbon dioxide are subsequently measured and used to calculate separate the separate components of the methane flux. The method used takes into account the 13C-methane associated with methanogenesis, and the amount of methane dissolved in the soil. The calculations make no prior assumptions about the kinetics of methane production or oxidation. The results indicate that methane oxidation can take place in anoxic soil environments. The clearest evidence for anaerobic methane oxidation is provided by soils from a minerotrophic fen site (pH 6.0) in Bin Forest underlain by ultra-basic and serpentine till. In the fresh soil anoxic microcosms, net consumption methane was observed, and the amount of headspace 13C-CO2 increased at a greater rate than the 12+13C-CO2, further proof of methane oxidation. A net increase in methane was measured in microcosms of soil from Murder Moss, an alkaline site, pH 6.5, with a strong calcareous influence. However, the 13C-CH4 data provided evidence of methane oxidation, both in the disappearance of C- CH4 and appearance of smaller quantities of 13C-CO2. The least alkaline (pH 5.5) microcosms, of Gateside Farm soil - a granitic till - exhibited net methanogenesis and the changes in 13C-CH4 and 13C-CO2 here followed the pattern expected if no methane is consumed

  6. Eddy correlation measurements of methane fluxes using a tunable diode laser at the Kinosheo Lake tower site during the Northern Wetlands Study (NOWES)

    NASA Technical Reports Server (NTRS)

    Edwards, G. C.; Neumann, H. H.; Den Hartog, G.; Thurtell, G. W.; Kidd, G.

    1994-01-01

    As part of the Canadian Northern Wetlands Study (NOWES) measurements of methane flux were made at the Kinosheo Lake tower site for a 1-month period during the 1990 summer intensive. The measurements were made with a diode-laser-based methane sensor using the eddy correlation technique. Measurements of the methane fluxes were made at two levels, 5 or 18 m. Approximately 900 half-hour average methane flux measurements were obtained. Weak temporal and diurnal trends were observed in the data. Fluxes averaged over the study period showed an overall methane emission of 16 mg CH4 m(exp -2)/d with a daytime average of 20 mg CH4 m(exp -2)/d and a nighttime average of 9 mg CH4 m(exp -2)/d. The effect of emission footprint was evident in the data. A strong relationship between the daily average methane flux and wet bog temperature at 20-cm depth was observed.

  7. A Quantification of Methane Emissions from Oil and Natural Gas Extraction Regions in the Central/Western U.S. and a Comparison to Previous Studies

    NASA Astrophysics Data System (ADS)

    Peischl, J.; Aikin, K. C.; Eilerman, S. J.; Gilman, J.; De Gouw, J. A.; Herndon, S. C.; Lerner, B. M.; Neuman, J. A.; Tokarek, T. W.; Trainer, M.; Warneke, C.; Ryerson, T. B.

    2015-12-01

    We present airborne measurements of methane and ethane taken aboard a NOAA WP-3D research aircraft over five regions of oil and natural gas extraction in March and April, 2015, as part of the Shale Oil and Natural Gas Nexus (SONGNEX) field study. The five regions are the (1) Haynesville, (2) Barnett, and (3) Eagle Ford regions in Texas, (4) the Denver-Julesburg region of Colorado, and (5) the Bakken region of North Dakota. From these measurements, we derive methane emission rates from these regions using the mass balance method. Next, we attribute the methane emissions to oil and natural gas extraction, livestock operations, and other source sectors based on correlations of methane with ethane and ammonia. We then compare these emissions to those reported from previous studies, where applicable. Finally, we compare reported methane emissions from multiple regional-scale studies with inventory estimates of methane emissions from U.S. oil and natural gas production.

  8. Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide.

    PubMed

    Fuentes, M Ángeles; Olmos, Andrea; Muñoz, Bianca K; Jacob, Kane; González-Núñez, M Elena; Mello, Rossella; Asensio, Gregorio; Caballero, Ana; Etienne, Michel; Pérez, Pedro J

    2014-08-25

    The development of catalytic methods for the effective functionalization of methane yet remains a challenge. The best system known to date is the so-called Catalytica Process based on the use of platinum catalysts to convert methane into methyl bisulfate with a TOF rate of 10(-3) s. In this contribution, we report a series of silver complexes containing perfluorinated tris(indazolyl)borate ligands that catalyze the functionalization of methane into ethyl propionate upon reaction with ethyl diazoacetate (EDA) by using supercritical carbon dioxide (scCO2) as the reaction medium. The employment of this reaction medium has also allowed the functionalization of ethane, propane, butane, and isobutane.

  9. Plasma catalytic reforming of methane

    SciTech Connect

    Bromberg, L.; Cohn, D.R.; Rabinovich, A.; Alexeev, N.

    1998-08-01

    Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This paper describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius) and high degree of dissociation and substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (50% H{sub 2}, 17% CO and 33% N{sub 2}, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2--3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H{sub 2} with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content ({approximately} 1.5%) with power densities of {approximately} 30 kW (H{sub 2} HHV)/liter of reactor, or {approximately} 10 m{sup 3}/hr H{sub 2} per liter of reactor. Power density should further increase with increased power and improved design.

  10. Methane oxidation associated to submerged brown-mosses buffers methane emissions from Siberian polygonal peatlands

    NASA Astrophysics Data System (ADS)

    Liebner, Susanne; Zeyer, Josef; Knoblauch, Christian

    2010-05-01

    Circumpolar peatlands store roughly 18 % of the globally stored carbon in soils [based on 1, 2]. Also, northern wetlands and tundra are a net source of methane (CH4), an effective greenhouse gas (GHG), with an estimated annual CH4 release of 7.2% [3] or 8.1% [4] of the global total CH4 emission. Although it is definite that Arctic tundra significantly contributes to the global methane emissions in general, regional variations in GHG fluxes are enormous. CH4 fluxes of polygonal tundra within the Siberian Lena Delta, for example, were reported to be low [5, 6], particularly at open water polygonal ponds and small lakes [7] which make up around 10 % of the delta's surface. Low methane emissions from polygonal ponds oppose that Arctic permafrost thaw ponds are generally known to emit large amounts of CH4 [8]. Combining tools of biogeochemistry and molecular microbiology, we identified sinks of CH4 in polygonal ponds from the Lena Delta that were not considered so far in GHG studies from Arctic wetlands. Pore water CH4 profiling in polygonal ponds on Samoylov, a small island in the central part of the Lena Delta, revealed a pronounced zone of CH4 oxidation near the vegetation surface in submerged layers of brown-mosses. Here, potential CH4 oxidation was an order of magnitude higher than in non-submerged mosses and in adjacent bulk soil. We could additionally show that this moss associated methane oxidation (MAMO) is hampered when exposure of light is prevented. Shading of plots with submerged Scorpidium scorpioides inhibited MAMO leading to higher CH4 concentrations and an increase in CH4 fluxes by a factor of ~13. Compared to non-submerged mosses, the submerged mosses also showed significantly lower δ13C values indicating that they use carbon dioxide derived from methane oxidation for photosynthesis. Applying stable isotope probing of DNA, type II methanotrophs were identified to be responsible for the oxidation of CH4 in the submerged Scorpidium scorpioides. Our

  11. Light-Dependent Aerobic Methane Oxidation Reduces Methane Emissions from Seasonally Stratified Lakes

    PubMed Central

    Oswald, Kirsten; Milucka, Jana; Brand, Andreas; Littmann, Sten; Wehrli, Bernhard; Kuypers, Marcel M. M.; Schubert, Carsten J.

    2015-01-01

    Lakes are a natural source of methane to the atmosphere and contribute significantly to total emissions compared to the oceans. Controls on methane emissions from lake surfaces, particularly biotic processes within anoxic hypolimnia, are only partially understood. Here we investigated biological methane oxidation in the water column of the seasonally stratified Lake Rotsee. A zone of methane oxidation extending from the oxic/anoxic interface into anoxic waters was identified by chemical profiling of oxygen, methane and δ13C of methane. Incubation experiments with 13C-methane yielded highest oxidation rates within the oxycline, and comparable rates were measured in anoxic waters. Despite predominantly anoxic conditions within the zone of methane oxidation, known groups of anaerobic methanotrophic archaea were conspicuously absent. Instead, aerobic gammaproteobacterial methanotrophs were identified as the active methane oxidizers. In addition, continuous oxidation and maximum rates always occurred under light conditions. These findings, along with the detection of chlorophyll a, suggest that aerobic methane oxidation is tightly coupled to light-dependent photosynthetic oxygen production both at the oxycline and in the anoxic bottom layer. It is likely that this interaction between oxygenic phototrophs and aerobic methanotrophs represents a widespread mechanism by which methane is oxidized in lake water, thus diminishing its release into the atmosphere. PMID:26193458

  12. Hypersonic Methane Probed by CRDS

    NASA Astrophysics Data System (ADS)

    Louviot, M.; Boudon, V.; Suas-David, N.; Georges, R.; Kassi, S.; Rey, M.

    2014-06-01

    A new cavity ring-down spectroscopy device, designed to study hypersonic gas jets, started to yield encouraging results at the Institut de Physique de Rennes (IPR). In this experiment, two mixtures have been used: first, a mixture of argon and carbon monoxide and second, a mixture of argon and methane. Mixtures were contained at high pressure in a reservoir (˜ 1000 Torr) and heated at very high temperature (˜ 2000 K), thanks to the high enthalpy source developed at IPR1. A hypersonic gas expansion was produced in a low-pressure chamber (˜ 0.09 Torr) connected to the reservoir. High-resolution spectra of methane have thus been investigated in the [59206030] cm-1 spectral range, which corresponds to the Tetradecad region of methane. The CRD spectrometer, developed by the LAME group from the LIPhy laboratory in Grenoble, has been placed perpendicularly to the axis of the jet to record these spectra. The precise analysis of the CO lines helped to determine the different parameters of the jet: translational, rotational and vibrational temperatures, concentrations of the hot and cold gas. One of the most noteworthy results is the evidence of a strong thermodynamic disequilibrium of CO, with a rotational temperature of 7 K and a vibrational temperature of 2000 K. This confirms the weak vibrational relaxation of the molecules in the jet. Then, the parameters determined for CO gave a starting point for the simulation of the spectrum of methane. Thereupon, they were fitted in order to make the simulation match the experimental results for CH4. The simulation for CH4 was obtained from the HITRAN 2012 linelist2, for the cold bands (Tetradecad-GS), and from a variational calculation from the GSMA laboratory in Reims3, for the hot bands (Icosad-Dyad). The vibrational temperature is finally about 750 K and the rotational temperature, about 13 K. This rotational simplification is particularly useful for the identification of hot band lines, that is very more difficult in a

  13. Methane Combustion: An Exergy Analysis

    NASA Astrophysics Data System (ADS)

    Silva, Valter; Rouboa, Abel

    2011-09-01

    A VBA (Visual Basic for Applications) code was developed to determine the exergy associated to the methane combustion. It was considered as the main sub-processes for each stage of reaction: the combined reactant mixing, the fuel oxidation, the internal thermal energy exchange (heat transfer), and the product mixing process. The exergetic efficiency and the temperature of the products were computed as a function of the percentage of the excess air. It was verified that the internal thermal energy exchange is the sub-process where the larger exergy destruction occurs.

  14. Inhibition of methane oxidation by Methylococcus capsulatus with hydrochlorofluorocarbons and fluorinated methanes

    USGS Publications Warehouse

    Matheson, L.J.; Jahnke, L.L.; Oremland, R.S.

    1997-01-01

    The inhibition of methane oxidation by cell suspensions of Methylococcus capsulatus (Bath) exposed to hydrochlorofluorocarbon 21 (HCFC-21; difluorochloromethane [CHF2Cl]), HCFC-22 (fluorodichloromethane [CHFCl2]), and various fluorinated methanes was investigated. HCFC-21 inhibited methane oxidation to a greater extent than HCFC-22, for both the particulate and soluble methane monooxygenases. Among the fluorinated methanes, both methyl fluoride (CH3F) and difluoromethane (CH2F2) were inhibitory while fluoroform (CHF3) and carbon tetrafluoride (CF4) were not. The inhibition of methane oxidation by HCFC-21 and HCFC-22 was irreversible, while that by methyl fluoride was reversible. The HCFCs also proved inhibitory to methanol dehydrogenase, which suggests that they disrupt other aspects of C1 catabolism in addition to methane monooxygenase activity.

  15. High rates of anaerobic methane oxidation in freshwater wetlands reduce potential atmospheric methane emissions.

    PubMed

    Segarra, K E A; Schubotz, F; Samarkin, V; Yoshinaga, M Y; Hinrichs, K-U; Joye, S B

    2015-06-30

    The role of anaerobic oxidation of methane (AOM) in wetlands, the largest natural source of atmospheric methane, is poorly constrained. Here we report rates of microbially mediated AOM (average rate=20 nmol cm(-3) per day) in three freshwater wetlands that span multiple biogeographical provinces. The observed AOM rates rival those in marine environments. Most AOM activity may have been coupled to sulphate reduction, but other electron acceptors remain feasible. Lipid biomarkers typically associated with anaerobic methane-oxidizing archaea were more enriched in (13)C than those characteristic of marine systems, potentially due to distinct microbial metabolic pathways or dilution with heterotrophic isotope signals. On the basis of this extensive data set, AOM in freshwater wetlands may consume 200 Tg methane per year, reducing their potential methane emissions by over 50%. These findings challenge precepts surrounding wetland carbon cycling and demonstrate the environmental relevance of an anaerobic methane sink in ecosystems traditionally considered strong methane sources.

  16. Integrated modeling of methane source, sinks, and emissions control costs. Final report

    SciTech Connect

    Jain, Atul K.

    2002-06-01

    The overall objective of this three-year collaborative project between the University of Illinois at Urbana-Champaign (UIUC) and Battelle Pacific Northwest National Laboratory (PNNL) was to develop a framework which would incorporate computationally efficient representations of the latest knowledge concerning science, scenarios, and technical change, to allow for the effective and efficient analysis of possible future strategies to control methane. As part of this research project, we developed a model that takes into account more explicit treatment of the mechanisms controlling each important methane regional source and sink to study non-linear effects involved in methane chemistry in the atmosphere. On the policy front, we developed the relationship between economics and climatic impacts of methane emission reductions. On the application front, we applied the newly developed advanced methane modeling capabilities to study the effects of a wide range of possible scenarios of future methane emissions on climate and to examined the costs associated with achieving specific greenhouse gas reduction targets for a range of emission pathways. The significant findings from the DOE supported study are outlined.

  17. Methane Emissions from Leak and Loss Audits of Natural Gas Compressor Stations and Storage Facilities.

    PubMed

    Johnson, Derek R; Covington, April N; Clark, Nigel N

    2015-07-07

    As part of the Environmental Defense Fund's Barnett Coordinated Campaign, researchers completed leak and loss audits for methane emissions at three natural gas compressor stations and two natural gas storage facilities. Researchers employed microdilution high-volume sampling systems in conjunction with in situ methane analyzers, bag samples, and Fourier transform infrared analyzers for emissions rate quantification. All sites had a combined total methane emissions rate of 94.2 kg/h, yet only 12% of the emissions total resulted from leaks. Methane slip from exhausts represented 44% of the total emissions. Remaining methane emissions were attributed to losses from pneumatic actuators and controls, engine crankcases, compressor packing vents, wet seal vents, and slop tanks. Measured values were compared with those reported in literature. Exhaust methane emissions were lower than emissions factor estimates for engine exhausts, but when combined with crankcase emissions, measured values were 11.4% lower than predicted by AP-42 as applicable to emissions factors for four-stroke, lean-burn engines. Average measured wet seal emissions were 3.5 times higher than GRI values but 14 times lower than those reported by Allen et al. Reciprocating compressor packing vent emissions were 39 times higher than values reported by GRI, but about half of values reported by Allen et al. Though the data set was small, researchers have suggested a method to estimate site-wide emissions factors for those powered by four-stroke, lean-burn engines based on fuel consumption and site throughput.

  18. Methane seeps along boundaries of arctic permafrost thaw and melting glaciers

    NASA Astrophysics Data System (ADS)

    Anthony, P.; Walter Anthony, K. M.; Grosse, G.; Chanton, J.

    2014-12-01

    Methane, a potent greenhouse gas, accumulates in subsurface hydrocarbon reservoirs. In the Arctic, impermeable icy permafrost and glacial overburden form a 'cryosphere cap' that traps gas leaking from these reservoirs, restricting flow to the atmosphere. We document the release of geologic methane to the atmosphere from abundant gas seeps concentrated along boundaries of permafrost thaw and receding glaciers in Alaska. Through aerial and ground surveys we mapped >150,000 seeps identified as bubbling-induced open holes in lake ice. Subcap methane seeps had anomalously high fluxes, 14C-depletion, and stable isotope values matching known coalbed and thermogenic methane accumulations in Alaska. Additionally, we observed younger subcap methane seeps in Greenland that were associated with ice-sheet retreat since the Little Ice Age. These correlations suggest that in a warming climate, continued disintegration of permafrost, glaciers, and parts of the polar ice sheets will relax pressure on subsurface seals and further open conduits, allowing a transient expulsion of geologic methane currently trapped by the cryosphere cap.

  19. Carbon and hydrogen isotope composition and C-14 concentration in methane from sources and from the atmosphere: Implications for a global methane budget

    NASA Technical Reports Server (NTRS)

    Wahlen, Martin

    1994-01-01

    The topics covered include the following: biogenic methane studies; forest soil methane uptake; rice field methane sources; atmospheric measurements; stratospheric samples; Antarctica; California; and Germany.

  20. Small Molecule Catalysts for Harvesting Methane Gas

    SciTech Connect

    Baker, S. E.; Ceron-Hernandez, M.; Oakdale, J.; Lau, E. Y.

    2016-12-06

    As the average temperature of the earth increases the impact of these changes are becoming apparent. One of the most dramatic changes to the environment is the melting of arctic permafrost. The disappearance of the permafrost has resulted in release of streams of methane that was trapped in remote areas as gas hydrates in ice. Additionally, the use of fracking has also increased emission of methane. Currently, the methane is either lost to the atmosphere or flared. If these streams of methane could be brought to market, this would be an abundant source of revenue. A cheap conversion of gaseous methane to a more convenient form for transport would be necessary to economical. Conversion of methane is a difficult reaction since the C-H bond is very stable (104 kcal/mole). At the industrial scale, the Fischer-Tropsch reaction can be used to convert gaseous methane to liquid methanol but is this method is impractical for these streams that have low pressures and are located in remote areas. Additionally, the Fischer-Tropsch reaction results in over oxidation of the methane leading to many products that would need to be separated.

  1. Arctic permafrost: Microbial lid on subsea methane

    NASA Astrophysics Data System (ADS)

    Thornton, Brett F.; Crill, Patrick

    2015-08-01

    Submarine permafrost thaw in the Arctic has been suggested as a trigger for the release of large quantities of methane to the water column, and subsequently the atmosphere -- with important implications for global warming. Now research shows that microbial oxidation of methane at the thaw front can effectively prevent its release.

  2. Determination of soil-entrapped methane

    SciTech Connect

    Alberto, M.C.R.; Neue, H.U.; Lantin, R.S.; Aduna, J.B.

    1996-12-31

    A sampling method was developed and modified to sample soil from paddy fields for entrapped methane determination. A 25-cm long plexiglass tube (4.4-cm i.d.) fitted with gas bag was used to sample soil and entrapped gases to a depth of 15-cm. The sampling tube was shaken vigorously to release entrapped gases. Headspace gas in sampling tube and gas bag was analyzed for methane. The procedure was verified by doing field sampling weekly at an irrigated ricefield in the IRRI Research Farm on a Maahas clay soil. The modified sampling method gave higher methane concentration because it eliminated gas losses during sampling. The method gave 98% {+-} 5 recovery of soil-entrapped methane. Results of field sampling showed that the early growth stage of the rice plant, entrapped methane increased irrespective of treatment. This suggests that entrapped methane increased irrespective of treatment. This suggests that entrapped methane was primarily derived from fermentation of soil organic matter at the early growth stage. At the latter stage, the rice plant seems to be the major carbon source for methane production. 7 refs., 4 figs., 4 tabs.

  3. Towards Understanding Methane Emissions from Abandoned Wells

    EPA Science Inventory

    Reconciliation of large-scale top-down methane measurements and bottom-up inventories requires complete accounting of source types. Methane emissions from abandoned oil and gas wells is an area of uncertainty. This presentation reviews progress to characterize the potential inv...

  4. Dairy livestock methane remediation and global warming.

    PubMed

    Nusbaum, Neil J

    2010-10-01

    One of the major greenhouse gases is the methane released from ruminants. Greenhouse gas emissions in the agricultural portion of the economy may benefit from biologically based remediation strategies, including potential use of probiotics in animal husbandry. A broad range of disciplines (including climatologists, microbiologists, biochemists, physical chemists, agricultural economists) can assist in biological strategies to reduce agricultural methane emissions.

  5. Abiotic production of methane in terrestrial planets.

    PubMed

    Guzmán-Marmolejo, Andrés; Segura, Antígona; Escobar-Briones, Elva

    2013-06-01

    On Earth, methane is produced mainly by life, and it has been proposed that, under certain conditions, methane detected in an exoplanetary spectrum may be considered a biosignature. Here, we estimate how much methane may be produced in hydrothermal vent systems by serpentinization, its main geological source, using the kinetic properties of the main reactions involved in methane production by serpentinization. Hydrogen production by serpentinization was calculated as a function of the available FeO in the crust, given the current spreading rates. Carbon dioxide is the limiting reactant for methane formation because it is highly depleted in aqueous form in hydrothermal vent systems. We estimated maximum CH4 surface fluxes of 6.8×10(8) and 1.3×10(9) molecules cm(-2) s(-1) for rocky planets with 1 and 5 M⊕, respectively. Using a 1-D photochemical model, we simulated atmospheres with volume mixing ratios of 0.03 and 0.1 CO2 to calculate atmospheric methane concentrations for the maximum production of this compound by serpentinization. The resulting abundances were 2.5 and 2.1 ppmv for 1 M⊕ planets and 4.1 and 3.7 ppmv for 5 M⊕ planets. Therefore, low atmospheric concentrations of methane may be produced by serpentinization. For habitable planets around Sun-like stars with N2-CO2 atmospheres, methane concentrations larger than 10 ppmv may indicate the presence of life.

  6. Tracking Dissolved Methane Concentrations near Active Seeps and Gas Hydrates: Sea of Japan.

    NASA Astrophysics Data System (ADS)

    Snyder, G. T.; Aoki, S.; Matsumoto, R.; Tomaru, H.; Owari, S.; Nakajima, R.; Doolittle, D. F.; Brant, B.

    2015-12-01

    A number of regions in the Sea of Japan are known for active gas venting and for gas hydrate exposures on the sea floor. In this investigation we employed several gas sensors mounted on a ROV in order to determine the concentrations of dissolved methane in the water near these sites. Methane concentrations were determined during two-second intervals throughout each ROV deployment during the cruise. The methane sensor deployments were coupled with seawater sampling using Niskin bottles. Dissolved gas concentrations were later measured using gas chromatography in order to compare with the sensor results taken at the same time. The observed maximum dissolved methane concentrations were much lower than saturation values, even when the ROV manipulators were in contact with gas hydrate. Nonetheless, dissolved concentrations did reach several thousands of nmol/L near gas hydrate exposures and gas bubbles, more than two orders of magnitude over the instrumental detection limits. Most of the sensors tested were able to detect dissolved methane concentrations as low as 10 nmol/L which permitted detection when the ROV approached methane plume sites, even from several tens of meters above the sea floor. Despite the low detection limits, the methane sensors showed variable response times when returning to low-background seawater (~5nM). For some of the sensors, the response time necessary to return to background values occurred in a matter of minutes, while for others it took several hours. Response time, as well as detection limit, should be an important consideration when selecting methane sensors for ROV or AUV investigations. This research was made possible, in part, through funding provided by the Japanese Ministry of Economy, Trade and Industry (METI).

  7. Explicit Microbial Processes to Simulate Methane Production and Oxidation in Wetlands in the GFDL Land Model

    NASA Astrophysics Data System (ADS)

    Smolander, S.; Sulman, B. N.; Shevliakova, E.

    2015-12-01

    Recent observational studies highlighted the need to include explicit treatment of the soil microbial processes into the next generation of Earth System Models (ESMs). These processes shape most soil biogeochemical cycles and control releases of the most potent greenhouses gases carbon dioxide and methane. Currently global ecosystem models usually parameterize methane production as a fraction of soil heterotrophic respiration. This lumps the pathways of several different functional groups of microbes into one production rate, possibly modified by a number of environmental factor multipliers. Methane oxidation is usually more explicitly modeled by Michaelis-Menten kinetics, but if the maximum rate, before environmental multipliers, is a constant parameter, this essentially implies a constant methanotrophic microbe population size. We present an explicit model for wetland soil microbial processes in an ESM context. We introduce a growth and decomposition model for four functional groups of microbes involved in methane production and oxidation, so microbial populations can grow when conditions are favorable and substrate is available. When soil conditions are anoxic, fermenting microbes transform available soil carbon into intermediate substrates, and two different kinds of methanogenic microbes live on their preferred substrates producing methane. Methane is transported through aerobic layers of the soil column, where methanotrophic microbes oxidize part of the methane, and the rest escapes to the atmosphere. We present initial simulations using the new model in the context of existing measurements of methane emissions and microbial populations at the site level, and discuss the implications of including these processes in an ESM. This explicit process model establishes a foundation for improving dynamic ecosystem-climate feedbacks in ESM simulations, and facilitates more detailed experimental verification of wetland biogeochemical processes.

  8. Methane-derived carbonates as archives of past seepage activity along the Norwegian margin

    NASA Astrophysics Data System (ADS)

    Crémière, Antoine; Lepland, Aivo; Sahy, Diana; Noble, Stephen R.; Condon, Daniel J.; Chand, Shyam; Stoddart, Daniel; Halvard Pedersen, Jon; Sauer, Simone; Brunstad, Harald; Birger Pedersen, Rolf; Thornes, Terje

    2014-05-01

    Assessment of timing and flux rates of past methane discharges is in part hindered by the lack of robust age constraints. Authigenic carbonate crusts forming in shallow sediments due to the oxidation of methane are recorders of seepage that can be dated by using U-daughter decay affording the unique opportunity to constrain the absolute timing of methane release events. Methane-derived carbonate crusts exhibiting characteristic 13C-depleted isotopic signatures were collected from several seepage sites on the Norwegian continental shelf, including sites in the North Sea, the Norwegian Sea and the Barents Sea. The U-Th dating results constrain the main episode of carbonate crust formation in the Barents and Norwegian seas during the time interval between 14 and 7 ka. Such ages suggest that the methane seepage along the northern Norwegian margin was most active after the collapse of the Scandinavian ice sheet and deglaciation of the area that took place at about 15 ka. The methane flux for the carbonate crust formation was likely provided by the dissociation of methane hydrates that extensively formed in underlying sediments during the last glacial period, but became unstable due to depressuring effects of retreating ice sheet. The precipitation of studied North Sea carbonate crusts occurred more recently, from 6 to 1 ka, suggesting that their formation is unrelated to the glacial history of the area and gas hydrate stability. Carbonate crust formation in the North Sea is likely related to the methane seepage from the hydrocarbon reservoir and the dating results allow an assessment of the seepage history within individual conduits.

  9. Observing the Arctic Carbon Feedback: Regional scale methane flux measurements over the Alaskan North Slope using airplane flux observations and in situ measurements of δ13CH4.

    NASA Astrophysics Data System (ADS)

    Healy, C. E.; Sayres, D. S.; Dobosy, R.; Dumas, E. J.; Munster, J. B.; Kochendorfer, J.; Wilkerson, J.; Baker, B.; Dubey, M. K.; Anderson, J. G.

    2015-12-01

    One of the most powerful positive feedback mechanisms to anthropogenic climate change postulated is the increase in carbon emissions from polar-regions. Warmer temperatures at the poles is predicted to increase the rate of methanogensesis in thawing permafrost soils as well as destabilize the network of arctic marine and terrestrial methane hydrates. Recent estimates put the quantity of organic carbon stored in soils in the northern permafrost zone around 1,700 Pg of C, which is well in excess of the maximum carbon emissions necessary to limit global average temperature increase to only 2 C° (260-410 Pg of C between 2011 and 2100 as CO2). However, many climate models used to forecast changes in average global temperature and inform policy decisions do not take into account arctic carbon feedback. This is largely due in part to the daunting observational challenge presented by observing methane fluxes in the Arctic. An ideal measurement system must be able to distinguish between biological and anthropogenic methane sources, have the ability to cover large spatial ranges, and have the sensitivity to distinguish changes from season to season, and year to year. The FOCAL platform has been engineered to address these challenges and help bridge the gap in spatial coverage between ground based and inverse modelling studies. It consists of a small aircraft equipped with the best atmospheric turbulence (BAT) probe, and gas sensors for in situ measurements of CH4, CO2, δ13CH4, δ13CO2 to make regional scale surface eddy-covariance flux measurements of methane and carbon dioxide as well as their stable isotopologues. We will present data from the initial FOCAL flight series in August 2013 based out of Deadhorse, AK, including CH4 concentration and running flux data, as well as in situ δ13CH4 observations to gain mechanistic insight. With the FOCAL platform we were able to dramatically extend regional coverage of methane flux observations beyond what can normally be observe

  10. Liquid Oxygen/Liquid Methane Test Results of the RS-18 Lunar Ascent Engine at Simulated Altitude Conditions at NASA White Sands Test Facility

    NASA Technical Reports Server (NTRS)

    Melcher, John C., IV; Allred, Jennifer K.

    2009-01-01

    Tests were conducted with the RS-18 rocket engine using liquid oxygen (LO2) and liquid methane (LCH4) propellants under simulated altitude conditions at NASA Johnson Space Center White Sands Test Facility (WSTF). This project is part of NASA's Propulsion and Cryogenics Advanced Development (PCAD) project. "Green" propellants, such as LO2/LCH4, offer savings in both performance and safety over equivalently sized hypergolic propulsion systems in spacecraft applications such as ascent engines or service module engines. Altitude simulation was achieved using the WSTF Large Altitude Simulation System, which provided altitude conditions equivalent up to 122,000 ft (37 km). For specific impulse calculations, engine thrust and propellant mass flow rates were measured. LO2 flow ranged from 5.9 - 9.5 lbm/sec (2.7 - 4.3 kg/sec), and LCH4 flow varied from 3.0 - 4.4 lbm/sec (1.4 - 2.0 kg/sec) during the RS-18 hot-fire test series. Propellant flow rate was measured using a coriolis mass-flow meter and compared with a serial turbine-style flow meter. Results showed a significant performance measurement difference during ignition startup due to two-phase flow effects. Subsequent cold-flow testing demonstrated that the propellant manifolds must be adequately flushed in order for the coriolis flow meters to give accurate data. The coriolis flow meters were later shown to provide accurate steady-state data, but the turbine flow meter data should be used in transient phases of operation. Thrust was measured using three load cells in parallel, which also provides the capability to calculate thrust vector alignment. Ignition was demonstrated using a gaseous oxygen/methane spark torch igniter. Test objectives for the RS-18 project are 1) conduct a shakedown of the test stand for LO2/methane lunar ascent engines, 2) obtain vacuum ignition data for the torch and pyrotechnic igniters, and 3) obtain nozzle kinetics data to anchor two-dimensional kinetics codes. All of these objectives were

  11. Geogenic methane emissions in central and eastern Romania

    NASA Astrophysics Data System (ADS)

    Baciu, Calin; Ionescu, Artur; Pop, Cristian; Etiope, Giuseppe

    2015-04-01

    Keywords: methane, greenhouse gases, geogenic emissions, Romania Relatively often, the hydrocarbon reservoirs are not completely sealed, thus permitting the channeling to the surface of various amounts of gas, mainly consisting of methane and homologues. When important volumes of gas are released, features as mud volcanoes and everlasting fires may occur. When the gas amount is low, the degassing can be revealed by instrumental means only. The gas seeps may be useful as indicators in the hydrocarbon exploration, but may be also hazardous when gas is accumulating in closed spaces. Additionally, the geogenic methane degassing represents an important contribution to the atmospheric budget of greenhouse gases. Romania is one of the European important hydrocarbon producers, with oil and gas deposits in different geologic and tectonic contexts. As well, the frequency of gas emitting features and seepage areas is high. Some relevant hydrocarbon-prone areas from Romania, namely the Neogene Transylvanian Basin, the Carpathian Foredeep, and the Moldavian Platform, are comparatively analysed within the current work from the point of view of methane emissions. The Carpathian Foredeep hosts the most impressive mud volcanoes and everlasting fires in Romania, classified among the biggest in Europe. The degassing area also extends in the Carpathian Flysch zone. The Transylvanian Basin hosts numerous gas-bearing structures, mainly of biogenic origin. With some exceptions, the methane-emitting features are small, releasing relatively low amounts of gas. A relatively high number of seeps have been described on the Moldavian Platform, although no commercial hydrocarbon reservoirs have been identified. The seeps are small, and they are releasing low amounts of methane. However, it is important to notice that the investigated zone partly corresponds to an area of interest for shale gas, related to the deep-seated Silurian shales. For all mentioned areas, the main geochemical

  12. Seasonal methane emissions by diffusion and ebullition from oligohaline marsh environments in coastal Louisiana

    USGS Publications Warehouse

    Leventhal, Joel S.; Guntenspergen, Glenn R.

    2004-01-01

    Methane is an important atmospheric greenhouse gas that is emitted from many natural and anthropogenic sources. In order to evaluate the global methane budget, precise data are needed from the diverse sources including coastal wetlands. Over 100 time-series determinations of methane emissions from an oligohaline wetland (brackish marsh) in coastal Louisiana show large variability during five seasonal sampling periods. Emission by both diffusion and ebullition (bubbles) was measured, however, neither of these emission modes were strongly dependent on either water depth or temperature (except in winter). Methane emission to static collectors placed over plants (Scirpus olneyi andSpartina patens) was not significantly different from shallow open water or mud. However, considerable heterogeneity in methane emissions and processes occurs even at a single site. Thus, establishing a reasonable estimate of the overall methane emission for a particular marsh environment and season requires multiple measurements at several sites. The average emissions for April, May, July, and September ranged from 31 to 54 mg/m2/h (744–1296 mg/m2/day). This can be separated into emissions from diffusion ranging from 8.3 to 20 mg/m2/h (18–50% of total) and emissions due to ebullition of 20–44 mg/m /h (50–82%). January emissions were much lower, amounting to 0.2 mg/m2/h (6 mg/m2/day), mainly by diffusion with only one episode of ebullition. Extrapolating these data to annual emissions gives total annual methane emissions of 203 g/m2/yr (61 g/m2/yr by diffusion and 142 g/m2/yr by ebullition).

  13. Direct Continuous Measurements of Methane Emissions from a Landfill: Method, Station and Latest Results

    NASA Astrophysics Data System (ADS)

    Burba, G. G.; Xu, L.; Lin, X.; Amen, J.; Welding, K.; McDermitt, D. K.

    2014-12-01

    Solar-powered automated flux station was deployed continuously inside the Bluff Road Landfill (Lincoln, NE) for the period of over4 years starting June 2010. Landfill methane emissions were measured using the eddy covariance method, reporting hourly emission rates. The data shown in this presentation are from the period of June to December 2010 when no gas recovery was in operation. The continuous measurements of hourly emission rates allowed a number of important analyses of the key factors affecting landfill methane emissions at different time scales. In particular, the results show that landfill methane emissions strongly depended on changes in barometric pressure. Rising barometric pressure suppressed the emission, while falling barometric pressure enhanced the emission, resulting in up to a 35-fold variation in day-to-day methane emissions. Wavelet coherence analysis revealed a strong spectral coherency between variations of barometric pressure and methane emission at periodicities ranging from 1 day to 8 days. Power spectrum and ogive analysis showed that at least 10 days of continuous measurements was needed in order to capture 90% of the total variance in the methane emission time series at the site.From these results, it is apparent that point-in-time measurements taken at monthly or longer time intervals using techniques such as the trace plume method, the mass balance method, or the closed-chamber method will be subject to large variations in measured emission rates because of the barometric pumping phenomenon. Estimates of long-term integrated methane emissions based on such measurements could yield uncertainties, ranging from 28% underestimation to 32% overestimation.The results demonstrate a need for continuous measurements to quantify annual total landfill emissions. This conclusion may also apply to the wetlands, peatlands, lakes, and other environments where emissions are from porous media or ebullition.

  14. Rock Physics Characterization of Porous Media Containing Hydrates Formed Out of Solution: Tetrathydrofuran VS. Dissolved Methane

    NASA Astrophysics Data System (ADS)

    Schicks, J. M.; Rydzy, M. B.; Spangenberg, E.; Batzle, M. L.

    2012-12-01

    Methane hydrate formation in sediments from the dissolved gas phase is a tedious and time-consuming task, due to the relatively low solubility of methane in water. A number of studies on physical properties of hydrated sediments have been conducted on sediments containing tetrahydrofuran (THF) hydrates instead. The use of THF as a hydrate former is convenient as it forms hydrate at atmospheric pressure and relatively high temperatures of about 277 K. It is completely miscible in water, thus forms hydrate out solution and promises homogeneous synthesis of THF hydrate in sediment. The applicability of THF as a proxy for methane hydrate formed out of solution, however, has often been questioned. To better understand whether THF hydrates represent a legitimate proxy for methane hydrates formed out of solution, ultrasonic velocity and resistivity measurements were performed on hydrated Ottawa Sand F110 sand and glass bead samples in conjunction with imaging techniques, such as micro X-ray computed tomography (MXCT), and scanning electron microscopy (SEM). Thereby the tests were conducted on samples containing hydrates formed both, from methane dissolved in water and with the use of THF. The results show, that in terms of ultrasonic velocities, THF and methane hydrates exhibit the same trend. As the hydrate crystallized in the pore space, no increase in velocity was observed until a critical hydrate saturation of 35-50 percent was exceeded. On the other hand, the bulk electrical resistivity increased with increasing gas hydrate saturation. Comparison with current rock physics models suggested that the gas hydrate formed out of solution in both cases exhibits pore-filling/ load-bearing behavior, i.e. it suggests that the hydrate is formed away from the grains. This was supported through the imaging. This series of measurements provided the first direct comparison of THF and methane hydrates formed out of solution in terms of how their distribution and location in the pore

  15. Nonequilibrium clumped isotope signals in microbial methane

    USGS Publications Warehouse

    Wang, David T.; Gruen, Danielle S.; Lollar, Barbara Sherwood; Hinrichs, Kai-Uwe; Stewart, Lucy C.; Holden, James F.; Hristov, Alexander N.; Pohlman, John W.; Morrill, Penny L.; Könneke, Martin; Delwiche, Kyle B.; Reeves, Eoghan P.; Sutcliffe, Chelsea N.; Ritter, Daniel J.; Seewald, Jeffrey S.; McIntosh, Jennifer C.; Hemond, Harold F.; Kubo, Michael D.; Cardace, Dawn; Hoehler, Tori M.; Ono, Shuhei

    2015-01-01

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its multiply-substituted “clumped” isotopologues, e.g., 13CH3D, has recently emerged as a proxy for determining methane-formation temperatures; however, the impact of biological processes on methane’s clumped isotopologue signature is poorly constrained. We show that methanogenesis proceeding at relatively high rates in cattle, surface environments, and laboratory cultures exerts kinetic control on 13CH3D abundances and results in anomalously elevated formation temperature estimates. We demonstrate quantitatively that H2 availability accounts for this effect. Clumped methane thermometry can therefore provide constraints on the generation of methane in diverse settings, including continental serpentinization sites and ancient, deep groundwaters.

  16. Optical constants of liquid and solid methane

    NASA Technical Reports Server (NTRS)

    Martonchik, John V.; Orton, Glenn S.

    1994-01-01

    The optical constants n(sub r) + in(sub i) of liquid methane and phase 1 solid methane were determined over the entire spectral range by the use of various data sources published in the literature. Kramers-Kronig analyses were performed on the absorption spectra of liquid methane at the boiling point (111 K) and the melting point (90 K) and on the absorption spectra of phase 1 solid methane at the melting point and at 30 K. Measurements of the static dielectric constant at these temperatures and refractive indices determined over limited spectral ranges were used as constraints in the analyses. Applications of methane optical properties to studies of outer solar system bodies are described.

  17. Methane flux from coastal salt marshes

    NASA Technical Reports Server (NTRS)

    Bartlett, K. B.; Harriss, R. C.; Sebacher, D. I.

    1985-01-01

    It is thought that biological methanogenesis in natural and agricultural wetlands and enteric fermentation in animals are the dominant sources of global tropospheric methane. It is pointed out that the anaerobic soils and sediments, where methanogenesis occurs, predominate in coastal marine wetlands. Coastal marine wetlands are generally believed to be approximately equal in area to freshwater wetlands. For this reason, coastal marine wetlands may be a globally significant source of atmospheric methane. The present investigation is concerned with the results of a study of direct measurements of methane fluxes to the atmosphere from salt marsh soils and of indirect determinations of fluxes from tidal creek waters. In addition, measurements of methane distributions in coastal marine wetland sediments and water are presented. The results of the investigation suggest that marine wetlands provide only a minor contribution to atmospheric methane on a global scale.

  18. Methane flux from coastal salt marshes

    NASA Astrophysics Data System (ADS)

    Bartlett, K. B.; Harriss, R. C.; Sebacher, D. I.

    1985-06-01

    It is thought that biological methanogenesis in natural and agricultural wetlands and enteric fermentation in animals are the dominant sources of global tropospheric methane. It is pointed out that the anaerobic soils and sediments, where methanogenesis occurs, predominate in coastal marine wetlands. Coastal marine wetlands are generally believed to be approximately equal in area to freshwater wetlands. For this reason, coastal marine wetlands may be a globally significant source of atmospheric methane. The present investigation is concerned with the results of a study of direct measurements of methane fluxes to the atmosphere from salt marsh soils and of indirect determinations of fluxes from tidal creek waters. In addition, measurements of methane distributions in coastal marine wetland sediments and water are presented. The results of the investigation suggest that marine wetlands provide only a minor contribution to atmospheric methane on a global scale.

  19. Nonequilibrium clumped isotope signals in microbial methane

    NASA Astrophysics Data System (ADS)

    Wang, David T.; Gruen, Danielle S.; Lollar, Barbara Sherwood; Hinrichs, Kai-Uwe; Stewart, Lucy C.; Holden, James F.; Hristov, Alexander N.; Pohlman, John W.; Morrill, Penny L.; Könneke, Martin; Delwiche, Kyle B.; Reeves, Eoghan P.; Sutcliffe, Chelsea N.; Ritter, Daniel J.; Seewald, Jeffrey S.; McIntosh, Jennifer C.; Hemond, Harold F.; Kubo, Michael D.; Cardace, Dawn; Hoehler, Tori M.; Ono, Shuhei

    2015-04-01

    Methane is a key component in the global carbon cycle, with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its multiply substituted “clumped” isotopologues (for example, 13CH3D) has recently emerged as a proxy for determining methane-formation temperatures. However, the effect of biological processes on methane’s clumped isotopologue signature is poorly constrained. We show that methanogenesis proceeding at relatively high rates in cattle, surface environments, and laboratory cultures exerts kinetic control on 13CH3D abundances and results in anomalously elevated formation-temperature estimates. We demonstrate quantitatively that H2 availability accounts for this effect. Clumped methane thermometry can therefore provide constraints on the generation of methane in diverse settings, including continental serpentinization sites and ancient, deep groundwaters.

  20. Methane storage in advanced porous materials.

    PubMed

    Makal, Trevor A; Li, Jian-Rong; Lu, Weigang; Zhou, Hong-Cai

    2012-12-07

    The need for alternative fuels is greater now than ever before. With considerable sources available and low pollution factor, methane is a natural choice as petroleum replacement in cars and other mobile applications. However, efficient storage methods are still lacking to implement the application of methane in the automotive industry. Advanced porous materials, metal-organic frameworks and porous organic polymers, have received considerable attention in sorptive storage applications owing to their exceptionally high surface areas and chemically-tunable structures. In this critical review we provide an overview of the current status of the application of these two types of advanced porous materials in the storage of methane. Examples of materials exhibiting high methane storage capacities are analyzed and methods for increasing the applicability of these advanced porous materials in methane storage technologies described.