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Sample records for microcolumn high pressure

  1. Combining lectin microcolumns with high-resolution separation techniques for enrichment of glycoproteins and glycopeptides.

    PubMed

    Madera, Milan; Mechref, Yehia; Novotny, Milos V

    2005-07-01

    Silica-based lectin microcolumns are described in this study together with the chemical procedures necessary for their preparation. The analytical merits of Canavalia ensiformis and Sambucus nigra lectins, [immobilized on activated macroporous silica], such as binding capacity, trapping reproducibility, and substrate selectivity, have been evaluated using model glycoproteins. The described microcolumns are applicable to high-pressure analytical schemes utilizing microvalving procedures, washing steps, and quantitative desorption for LC/MS analysis. The described analytical systems are amenable to the applications aiming at fractionation of complex glycopeptide mixtures and determination of the sites of glycosylation.

  2. Highly Multiplexed RNA Aptamer Selection using a Microplate-based Microcolumn Device

    PubMed Central

    Reinholt, Sarah J.; Ozer, Abdullah; Lis, John T.; Craighead, Harold G.

    2016-01-01

    We describe a multiplexed RNA aptamer selection to 19 different targets simultaneously using a microcolumn-based device, MEDUSA (Microplate-based Enrichment Device Used for the Selection of Aptamers), as well as a modified selection process, that significantly reduce the time and reagents needed for selections. We exploited MEDUSA’s reconfigurable design between parallel and serially-connected microcolumns to enable the use of just 2 aliquots of starting library, and its 96-well microplate compatibility to enable the continued use of high-throughput techniques in downstream processes. Our modified selection protocol allowed us to perform the equivalent of a 10-cycle selection in the time it takes for 4 traditional selection cycles. Several aptamers were discovered with nanomolar dissociation constants. Furthermore, aptamers were identified that not only bound with high affinity, but also acted as inhibitors to significantly reduce the activity of their target protein, mouse decapping exoribonuclease (DXO). The aptamers resisted DXO’s exoribonuclease activity, and in studies monitoring DXO’s degradation of a 30-nucleotide substrate, less than 1 μM of aptamer demonstrated significant inhibition of DXO activity. This aptamer selection method using MEDUSA helps to overcome some of the major challenges with traditional aptamer selections, and provides a platform for high-throughput selections that lends itself to process automation. PMID:27432610

  3. High-temperature separations on a polymer-coated fibrous stationary phase in microcolumn liquid chromatography.

    PubMed

    Nakane, Kenichi; Shirai, Shingoro; Saito, Yoshihiro; Moriwake, Yusuke; Ueta, Ikuo; Inoue, Mitsuru; Jinno, Kiyokatsu

    2011-01-01

    Novel polymer-coated fiber-packed microcolumns in liquid chromatography (LC) have been developed. Typical polymeric materials, such as polydimethylsiloxane and polyethyleneglycol, which are conventional stationary phases of capillary columns in gas chromatography (GC), have been employed as coating materials onto the surface of fine filaments. Packed longitudinally with a bundle of polymer-coated filaments into a stainless-steel capillary of 0.8 mm i.d., 150 mm length, several types of polymer-coated fiber-packed columns were prepared, and the retention behavior of aromatic compounds on these columns has been studied. A good linear relationship was obtained for van't Hoff plots over the temperature range between 0 and 200 °C, clearly indicating an excellent heat-resistant property of these polymer-coated fibrous stationary phases. Taking advantage of the heat-resistant feature of the fibrous stationary phases, the separation of several test mixtures with temperature-programmed elution was studied, where a solvent gradient program was additionally introduced if needed. Separation was also carried out with pure water as the mobile phase using an appropriate temperature program. 2011 © The Japan Society for Analytical Chemistry

  4. Micro-column Scanning Electron Microscope and X-ray Spectrometer (MSEMS) for Planetary Exploration

    NASA Astrophysics Data System (ADS)

    Ribaya, B.; Niemann, D.; Makarewicz, J.; Clevenson, H.; McKenzie, C.; Nguyen, C.; Blake, D. F.

    2009-12-01

    Scanning Electron Microscopy combined with electron-induced X-ray Fluorescence Spectroscopy (SEM-EDX) is one of the most powerful techniques for characterizing sub-µm surface morphology and composition. In terrestrial laboratories, SEM-EDX is used to elucidate natural processes such as low-temperature diagenesis, thermal or pressure induced metamorphism, volcanism/magmatism, atmosphere/crust interaction and biological activity. Such information would be highly useful for investigating the natural history of the terrestrial planets, satellites and primitive bodies, providing morphological and elemental information that is 2 orders of magnitude higher in resolution than optical techniques. Below we describe the development of a Micro-column Scanning Electron Microscope and X-ray Spectrometer (MSEMS) for flight. The enabling technology of the MSEMS is a carbon nanotube field emission (CNTFE) electron source that is integrated with micro-electro-mechanical-systems (MEMS) - based electron gun and electron optical structures. A hallmark of CNTFE electron sources is their low chromatic aberration, which reduces the need for high accelerating voltages to obtain small spot size. The CNTFE also offers exceptional brightness and nanometer source size, eliminating the need for condenser lenses, making simple electrostatic focusing optics possible. Moreover, the CNT field emission gun (CFEG) at low operating voltage dissipates 103 less power than thermally-assisted Schottky emitters. A key feature of the MSEMS design is the lack of scanning coils. Rather, a piezoelectric sample stage capable of sub-nanometer resolution scans the sample past the fixed crossover of the MSEMS electron beam. We will describe a MEMS-based templating technique for fabricating mechanically and electrically stable miniature CFEGs. Using existing silicon (Si) technology, we fabricated highly controlled and precise MEMS structures for both the CNT cathode and focusing optics for the micro-column. The

  5. Highly efficient proteome analysis with combination of protein pre-fractionation by preparative microscale solution isoelectric focusing and identification by μRPLC-MS/MS with serially coupled long microcolumn.

    PubMed

    Tao, Dingyin; Sun, Liangliang; Zhu, Guijie; Liang, Yu; Liang, Zhen; Zhang, Lihua; Zhang, Yukui

    2011-01-01

    To improve the efficiency of proteome analysis, a strategy with the combination of protein pre-fractionation by preparative microscale solution isoelectric focusing, peptide separation by μRPLC with serially coupled long microcolumn and protein identification by ESI-MS/MS was proposed. By preparative microscale solution isoelectric focusing technique, proteins extracted from whole cell lysates of Escherichia coli were fractionated into five chambers divided by isoelectric membranes, respectively with pH range from 3.0 to 4.6, 4.6 to 5.4, 5.4 to 6.2, 6.2 to 7.0 and 7.0 to 10.0. Compared to the traditional on-gel IFF, the protein recovery could be obviously improved to over 95%. Subsequently, the enriched and fractionated proteins in each chamber were digested, and further separated by a 30-cm long serially coupled RP microcolumn. Through the detection by ESI-MS/MS, about 200 proteins were identified in each fraction, and in total 835 proteins were identified even with one-dimensional μRPLC-MS/MS system. All these results demonstrate that by such a combination strategy, highly efficient proteome analysis could be achieved, not only due to the in-solution protein enrichment and pre-fractionation with improved protein recovery but also owing to the increased separation capacity of serially coupled long μRPLC columns.

  6. Photocatalytic and photoelectrochemical performance of Ta3N5 microcolumn films fabricated using facile reactive sputtering

    NASA Astrophysics Data System (ADS)

    Lin, Der-Hwa; Chang, Kao-Shuo

    2016-08-01

    This paper presents the photocatalytic and photoelectrochemical (PEC) properties of Ta3N5 microcolumn films. The highlights include (1) overcoming the fundamental barrier of standard reactive sputtering for fabricating microcolumns; (2) preventing unnecessary complexity from complicating facile sputtering; (3) an alternative but effective approach for fabricating Ta3N5 without using caustic NH3 gases; (4) investigating morphology tuning for favorable photocatalysis and PEC reactions; and (5) elucidating the relationships of the structures, morphologies, and properties of Ta3N5 microcolumns. High-resolution transmission electron microscopy and selective-area electron diffraction verified the polycrystallinity of Ta3N5 microcolumns, of which the elemental compositions and stoichiometry were measured using electron-probe energy dispersive spectroscopy, Auger electron spectroscopy, and X-ray photoelectron spectroscopy. The corresponding band gap was determined to be approximately 2.1 eV. The sample exhibited a superior photodegradation capability; the photodegradation rate constant k was determined to be approximately 1.4 times higher than that of P25 under UV irradiation. A photocatalytic and PEC cycling test indicated the photodegradation reusability and photostability of the Ta3N5 microcolumns. The incident photon-to-current efficiency performance reached 6%, suggesting that these microcolumns hold potential for application in PEC devices.

  7. Photocatalytic and photoelectrochemical performance of Ta{sub 3}N{sub 5} microcolumn films fabricated using facile reactive sputtering

    SciTech Connect

    Lin, Der-Hwa; Chang, Kao-Shuo

    2016-08-21

    This paper presents the photocatalytic and photoelectrochemical (PEC) properties of Ta{sub 3}N{sub 5} microcolumn films. The highlights include (1) overcoming the fundamental barrier of standard reactive sputtering for fabricating microcolumns; (2) preventing unnecessary complexity from complicating facile sputtering; (3) an alternative but effective approach for fabricating Ta{sub 3}N{sub 5} without using caustic NH{sub 3} gases; (4) investigating morphology tuning for favorable photocatalysis and PEC reactions; and (5) elucidating the relationships of the structures, morphologies, and properties of Ta{sub 3}N{sub 5} microcolumns. High-resolution transmission electron microscopy and selective-area electron diffraction verified the polycrystallinity of Ta{sub 3}N{sub 5} microcolumns, of which the elemental compositions and stoichiometry were measured using electron-probe energy dispersive spectroscopy, Auger electron spectroscopy, and X-ray photoelectron spectroscopy. The corresponding band gap was determined to be approximately 2.1 eV. The sample exhibited a superior photodegradation capability; the photodegradation rate constant k was determined to be approximately 1.4 times higher than that of P25 under UV irradiation. A photocatalytic and PEC cycling test indicated the photodegradation reusability and photostability of the Ta{sub 3}N{sub 5} microcolumns. The incident photon-to-current efficiency performance reached 6%, suggesting that these microcolumns hold potential for application in PEC devices.

  8. High Blood Pressure

    MedlinePlus

    ... normal blood pressure 140/90 or higher is high blood pressure Between 120 and 139 for the top number, ... prehypertension. Prehypertension means you may end up with high blood pressure, unless you take steps to prevent it. High ...

  9. High Blood Pressure (Hypertension)

    MedlinePlus

    ... Print Page Text Size: A A A Listen High Blood Pressure (Hypertension) Nearly 1 in 3 American adults has ... weight. How Will I Know if I Have High Blood Pressure? High blood pressure is a silent problem — you ...

  10. High Blood Pressure

    MedlinePlus

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  11. High blood pressure

    MedlinePlus

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  12. Hypertension (High Blood Pressure)

    MedlinePlus

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  13. Development of arrayed microcolumns and field emitters

    NASA Astrophysics Data System (ADS)

    Kim, Ho Seob; Bok Lee, Young; Choi, Sung Woong; Kim, Hyung Woo; Kim, Dae-Wook; Ahn, Seung Joon; Oh, Tae Sik; Song, Yoon-Ho; Chon Park, Byong; Jong Lim, Sun

    2017-06-01

    Electron beam devices have been widely used for inspection or lithography processes. The multibeam technology based on arrayed microcolumns has been developed to overcome the low throughput issue. However, the multicolumn system has some drawbacks such as complexity, electron optics, and electron source. The first drawback is the difficulty in multicolumn assembly. In particular, the alignment process of a source lens and a tip requires sophisticated techniques. The second drawback is that the e-beam characteristics of microcolumns constituting the multicolumn differ from column to column. To solve the first drawback, a sub-5-nm-resolution probe beam optic design with a simple structure and a two-dimensional carbon nanotube (2D-CNT) electron emitter instead of the widely used tungsten field emitter tip have been studied.

  14. Nanophotonic ion production from silicon microcolumn arrays.

    PubMed

    Walker, Bennett N; Razunguzwa, Trust; Powell, Matthew; Knochenmuss, Richard; Vertes, Akos

    2009-01-01

    Nanoantennas for ions: Silicon microcolumn arrays harvest light from a laser pulse to produce ions. The system behaves like a quasi-periodic antenna array with ion yields that show profound dependence on the plane of polarization and the angle of incidence of the laser beam. Photonic ion sources promise to enable enhanced control of ion production on a micro- and nanometer scale and direct integration with miniaturized analytical devices.

  15. High blood pressure medicines

    MedlinePlus

    Hypertension - medicines ... blood vessel diseases. You may need to take medicines to lower your blood pressure if lifestyle changes ... blood pressure to the target level. WHEN ARE MEDICINES FOR HIGH BLOOD PRESSURE USED Most of the ...

  16. High blood pressure - infants

    MedlinePlus

    ... this page: //medlineplus.gov/ency/article/007329.htm High blood pressure - infants To use the sharing features on this page, please enable JavaScript. High blood pressure (hypertension) is an increase in the force of ...

  17. High Blood Pressure Prevention

    MedlinePlus

    ... version of this page please turn Javascript on. High Blood Pressure Prevention Steps You Can Take You can take steps to prevent high blood pressure by adopting these healthy lifestyle habits. Follow a ...

  18. Hypertension (High Blood Pressure)

    MedlinePlus

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  19. High Blood Pressure (Hypertension)

    MedlinePlus

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  20. High Blood Pressure in Pregnancy

    MedlinePlus

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  1. Analysis of biomolecular interactions using affinity microcolumns: A review

    PubMed Central

    Zheng, Xiwei; Li, Zhao; Beeram, Sandya; Podariu, Maria; Matsuda, Ryan; Pfaunmiller, Erika L.; White, Christopher J.; Carter, NaTasha; Hage, David S.

    2014-01-01

    Affinity chromatography has become an important tool for characterizing biomolecular interactions. The use of affinity microcolumns, which contain immobilized binding agents and have volumes in the mid-to-low microliter range, has received particular attention in recent years. Potential advantages of affinity microcolumns include the many analysis and detection formats that can be used with these columns, as well as the need for only small amounts of supports and immobilized binding agents. This review examines how affinity microcolumns have been used to examine biomolecular interactions. Both capillary-based microcolumns and short microcolumns are considered. The use of affinity microcolumns with zonal elution and frontal analysis methods are discussed. The techniques of peak decay analysis, ultrafast affinity extraction, split-peak analysis, and band-broadening studies are also explored. The principles of these methods are examined and various applications are provided to illustrate the use of these methods with affinity microcolumns. It is shown how these techniques can be utilized to provide information on the binding strength and kinetics of an interaction, as well as on the number and types of binding sites. It is further demonstrated how information on competition or displacement effects can be obtained by these methods. PMID:24572459

  2. High temperature pressure gauge

    DOEpatents

    Echtler, J. Paul; Scandrol, Roy O.

    1981-01-01

    A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

  3. Micro-column plasma emission liquid chromatograph

    DOEpatents

    Gay, Don D.

    1984-01-01

    In a direct current plasma emission spectrometer for use in combination with a micro-column liquid chromatograph, an improved plasma source unit. The plasma source unit includes a quartz capillary tube having an inlet means, outlet off gas means and a pair of spaced electrodes defining a plasma region in the tube. The inlet means is connected to and adapted to receive eluant of the liquid chromatograph along with a stream of plasma-forming gas. There is an opening through the wall of the capillary tube penetrating into the plasma region. A soft glass capillary light pipe is disposed at the opening, is connected to the spectrometer, and is adapted to transmit light passing from the plasma region to the spectrometer. There is also a source of electromotive force connected to the electrodes sufficient to initiate and sustain a plasma in the plasma region of the tube.

  4. Aspirated High Pressure Compressor

    DTIC Science & Technology

    2006-08-01

    Std. Z39.18 A proved for Public Release Distribution Unlimited ABSTRACT (continued from Blockl4) within 0.5 percentage points . High response static...attention was given to the design of the instrumentation to obtain efficiency measurements within 0.5 percentage points . High response static pressure...prior empirical knowledge [3]. 0.5 percentage points . High response static pressure The new proposition addressed here is that aspiration offers

  5. High-pressure microfluidics

    NASA Astrophysics Data System (ADS)

    Hjort, K.

    2015-03-01

    When using appropriate materials and microfabrication techniques, with the small dimensions the mechanical stability of microstructured devices allows for processes at high pressures without loss in safety. The largest area of applications has been demonstrated in green chemistry and bioprocesses, where extraction, synthesis and analyses often excel at high densities and high temperatures. This is accessible through high pressures. Capillary chemistry has been used since long but, just like in low-pressure applications, there are several potential advantages in using microfluidic platforms, e.g., planar isothermal set-ups, large local variations in geometries, dense form factors, small dead volumes and precisely positioned microstructures for control of reactions, catalysis, mixing and separation. Other potential applications are in, e.g., microhydraulics, exploration, gas driven vehicles, and high-pressure science. From a review of the state-of-art and frontiers of high pressure microfluidics, the focus will be on different solutions demonstrated for microfluidic handling at high pressures and challenges that remain.

  6. Prevention of High Blood Pressure

    MedlinePlus

    ... page from the NHLBI on Twitter. Prevention of High Blood Pressure Healthy lifestyle habits, proper use of medicines, and ... prevent high blood pressure or its complications. Preventing High Blood Pressure Onset Healthy lifestyle habits can help prevent high ...

  7. Determination of azithromycin residue in pork using a molecularly imprinted monolithic microcolumn coupled to liquid chromatography with tandem mass spectrometry.

    PubMed

    Zhou, Tong; Yang, Haicui; Jin, Zhen; Liu, Qingying; Song, Xuqin; He, Limin; Fang, Binghu; Meng, Chenying

    2016-04-01

    Using spiramycin as a dummy template, a molecularly imprinted polymer monolithic micro-column with high selection to azithromycin was prepared in a micropipette tip. The imprinting factor of the monolithic micro-column prepared was approximately 2.67 and the morphological structure of the polymers was characterized by scanning electron microscopy. A simple, sensitive, and reproducible method based on the imprinted monolithic micro-column coupled to liquid chromatography with tandem mass spectrometry was developed for determining the residues of azithromycin in pork. Pork samples were extracted with acetonitrile, cleaned up under the optimal monolithic micro-column conditions, and analyzed using liquid chromatography with tandem mass spectrometry in the multiple reaction monitoring mode. The assay exhibited a linear dynamic range of 0.50-50 μg/L with the correlation coefficient (r(2) ) above 0.99. In the three spiking levels of 0.50, 1.0, and 10 μg/kg, the average recoveries of azithromycin from pork samples were between 85.8 and 96.5% with a relative standard deviation below 10%. The limit of detection and limit of quantitation were 0.03 and 0.1 μg/kg, respectively.

  8. High Pressure Biomass Gasification

    SciTech Connect

    Agrawal, Pradeep K

    2016-07-29

    According to the Billion Ton Report, the U.S. has a large supply of biomass available that can supplement fossil fuels for producing chemicals and transportation fuels. Agricultural waste, forest residue, and energy crops offer potential benefits: renewable feedstock, zero to low CO2 emissions depending on the specific source, and domestic supply availability. Biomass can be converted into chemicals and fuels using one of several approaches: (i) biological platform converts corn into ethanol by using depolymerization of cellulose to form sugars followed by fermentation, (ii) low-temperature pyrolysis to obtain bio-oils which must be treated to reduce oxygen content via HDO hydrodeoxygenation), and (iii) high temperature pyrolysis to produce syngas (CO + H2). This last approach consists of producing syngas using the thermal platform which can be used to produce a variety of chemicals and fuels. The goal of this project was to develop an improved understanding of the gasification of biomass at high pressure conditions and how various gasification parameters might affect the gasification behavior. Since most downstream applications of synags conversion (e.g., alcohol synthesis, Fischer-Tropsch synthesis etc) involve utilizing high pressure catalytic processes, there is an interest in carrying out the biomass gasification at high pressure which can potentially reduce the gasifier size and subsequent downstream cleaning processes. It is traditionally accepted that high pressure should increase the gasification rates (kinetic effect). There is also precedence from coal gasification literature from the 1970s that high pressure gasification would be a beneficial route to consider. Traditional approach of using thermogravimetric analyzer (TGA) or high-pressure themogravimetric analyzer (PTGA) worked well in understanding the gasification kinetics of coal gasification which was useful in designing high pressure coal gasification processes. However

  9. The Optical Assembly of Lens System in Microcolumn

    NASA Astrophysics Data System (ADS)

    Jang, Won; Kim, Ho

    2005-04-01

    The resolution and performance of micro-column is determined by factors of optical aberration, which are dependent of the size, the roundness of lens aperture, and the precise alignment. The micro-column is composed of deflector, source lenses and Einzel lenses with the whole length less than 10mm. The optical aberrations of micro-column are reduced owing to the considerable reduction of its dimension compared with that of conventional electron column. A precise circular aperture was pierced on a 3μm thin silicon membrane by laser machining. The range of the aperture diameter of electron lenses usually ranges from 10 to 200μm, and the spacing between electrodes is from 100μm to several hundreds of μm. Laser diffraction pattern observed through the assembled lens system, and the distortion of the diffraction pattern can be easily recognized. An Airy circular diffraction was observed and monitored for the clear pattern..

  10. High pressure furnace

    DOEpatents

    Morris, Donald E.

    1993-01-01

    A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  11. High pressure oxygen furnace

    DOEpatents

    Morris, Donald E.

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  12. High pressure oxygen furnace

    DOEpatents

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  13. High pressure furnace

    DOEpatents

    Morris, D.E.

    1993-09-14

    A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

  14. Q Sepharose micro-column chromatography: A simple screening method for identifying beta thalassemia traits and hemoglobin E carriers.

    PubMed

    Wong, Peerapon; Sritippayawan, Suchila; Suwannakhon, Narutchala; Tapprom, Akamon; Deoisares, Rawisut; Sanguansermsri, Torpong

    2016-11-01

    For beta thalassemia control program in pregnancy, mass screening of the carrier state by determination of the hemoglobin (Hb) A2 and Hb E proportions and mutation analysis is a preferred method for making prenatal diagnoses. Q Sepharose micro-column chromatography, developed for the determination of Hb A2 and Hb E for screening purposes, was compared with high performance liquid chromatography (HPLC) to ascertain its relative accuracy and reliability. Results using Q Sepharose micro-column chromatography in 350 blood specimens, including 50 samples genetically proven to be beta thalassemia heterozygotes, were compared to HPLC for validation. An additional study was conducted to test a clinical application on a large-scale survey for beta thalassemia in 1581 pregnant women and their spouses. The mean (±SD) Hb A2 proportions in the normal and genetically proven beta thalassemia heterozygotes were 2.70±0.40% and 6.30±1.23%, respectively, as determined by Q-Sepharose micro-column chromatography, and 2.65±0.31% and 5.37±0.96%, respectively, as determined by HPLC. The mean Hb E proportions in the Hb E heterozygotes were 23.25±4.13% and 24.72±3.5% as determined by Q Sepharose micro-column chromatography and HPLC, respectively. In the large-scale survey for beta thalassemia, 23 at risk couples were detected. Seven affected fetuses were identified by prenatal diagnosis. Q Sepharose micro-column chromatography was found to be reliable, reproducible and well-suited for large-scale surveys. Additionally, by being reusable and convenient, this simple and economical chromatography method may be an alternative means to screen for beta thalassemia and Hb E carriers in the mass population. Copyright © 2016 The Canadian Society of Clinical Chemists. Published by Elsevier Inc. All rights reserved.

  15. HIGH PRESSURE GAS REGULATOR

    DOEpatents

    Ramage, R.W.

    1962-05-01

    A gas regulator operating on the piston and feedback principle is described. The device is particularly suitable for the delicate regulation of high pressure, i.e., 10,000 psi and above, gas sources, as well as being perfectly adaptable for use on gas supplies as low as 50 psi. The piston is adjustably connected to a needle valve and the movement of the piston regulates the flow of gas from the needle valve. The gas output is obtained from the needle valve. Output pressure is sampled by a piston feedback means which, in turn, regulates the movement of the main piston. When the output is other than the desired value, the feedback system initiates movement of the main piston to allow the output pressure to be corrected or to remain constant. (AEC)

  16. New method for sintering silica frits for capillary microcolumns.

    PubMed

    Keunchkarian, Sonia; Lebed, Pablo J; Sliz, Brenda B; Castells, Cecilia B; Gagliardi, Leonardo G

    2014-04-11

    One of the main steps in the manufacture of robust and efficient packed capillary microcolumns for electro- and capillary chromatography is the generation of porous devices to retain the packed beds. Frits based on sintered silica particles have been found to give the best results in terms of mechanical resistance and efficiency. The conventional procedure to produce these kinds of frits consists in a radial heating of the packed material with either a flame or an electrical resistance, but the frits thus obtained have many drawbacks as a result of the procedure rather than the silica per se as the base material. In the present work we investigated a new approach to produce silica-based retaining devices involving the frontal exposure of a short silica-particle bed packed at the end of a capillary tube. The capillary is radially insulated and frontally exposed to the heat of a muffle oven, generating a transfer of heat that is not radial but rather throughout the capillary axis. This procedure resulted in substantial advantages: an improved radial homogeneity, a protection of the external polyimide, and a generation of extremely short (400-600 μm) frits that were highly permeable and avoided bubble formation. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Living with High Blood Pressure

    MedlinePlus

    ... page from the NHLBI on Twitter. Living With High Blood Pressure If you have high blood pressure, the best thing to do is to talk ... help you track your blood pressure. Pregnancy Planning High blood pressure can cause problems for mother and baby. High ...

  18. Cryogenic High Pressure Sensor Module

    NASA Technical Reports Server (NTRS)

    Chapman, John J. (Inventor); Shams, Qamar A. (Inventor); Powers, William T. (Inventor)

    1999-01-01

    A pressure sensor is provided for cryogenic, high pressure applications. A highly doped silicon piezoresistive pressure sensor is bonded to a silicon substrate in an absolute pressure sensing configuration. The absolute pressure sensor is bonded to an aluminum nitride substrate. Aluminum nitride has appropriate coefficient of thermal expansion for use with highly doped silicon at cryogenic temperatures. A group of sensors, either two sensors on two substrates or four sensors on a single substrate are packaged in a pressure vessel.

  19. Cryogenic, Absolute, High Pressure Sensor

    NASA Technical Reports Server (NTRS)

    Chapman, John J. (Inventor); Shams. Qamar A. (Inventor); Powers, William T. (Inventor)

    2001-01-01

    A pressure sensor is provided for cryogenic, high pressure applications. A highly doped silicon piezoresistive pressure sensor is bonded to a silicon substrate in an absolute pressure sensing configuration. The absolute pressure sensor is bonded to an aluminum nitride substrate. Aluminum nitride has appropriate coefficient of thermal expansion for use with highly doped silicon at cryogenic temperatures. A group of sensors, either two sensors on two substrates or four sensors on a single substrate are packaged in a pressure vessel.

  20. Pressure Dome for High-Pressure Electrolyzer

    NASA Technical Reports Server (NTRS)

    Norman, Timothy; Schmitt, Edwin

    2012-01-01

    A high-strength, low-weight pressure vessel dome was designed specifically to house a high-pressure [2,000 psi (approx. = 13.8 MPa)] electrolyzer. In operation, the dome is filled with an inert gas pressurized to roughly 100 psi (approx. = 690 kPa) above the high, balanced pressure product oxygen and hydrogen gas streams. The inert gas acts to reduce the clamping load on electrolyzer stack tie bolts since the dome pressure acting axially inward helps offset the outward axial forces from the stack gas pressure. Likewise, radial and circumferential stresses on electrolyzer frames are minimized. Because the dome is operated at a higher pressure than the electrolyzer product gas, any external electrolyzer leak prevents oxygen or hydrogen from leaking into the dome. Instead the affected stack gas stream pressure rises detectably, thereby enabling a system shutdown. All electrical and fluid connections to the stack are made inside the pressure dome and require special plumbing and electrical dome interfaces for this to be accomplished. Further benefits of the dome are that it can act as a containment shield in the unlikely event of a catastrophic failure. Studies indicate that, for a given active area (and hence, cell ID), frame outside diameter must become ever larger to support stresses at higher operating pressures. This can lead to a large footprint and increased costs associated with thicker and/or larger diameter end-plates, tie-rods, and the frames themselves. One solution is to employ rings that fit snugly around the frame. This complicates stack assembly and is sometimes difficult to achieve in practice, as its success is strongly dependent on frame and ring tolerances, gas pressure, and operating temperature. A pressure dome permits an otherwise low-pressure stack to operate at higher pressures without growing the electrolyzer hardware. The pressure dome consists of two machined segments. An O-ring is placed in an O-ring groove in the flange of the bottom

  1. HIGH PRESSURE DIES

    DOEpatents

    Wilson, W.B.

    1960-05-31

    A press was invented for subjecting specimens of bismuth, urania, yttria, or thoria to high pressures and temperatures. The press comprises die parts enclosing a space in which is placed an electric heater thermally insulated from the die parts so as not to damage them by heat. The die parts comprise two opposed inner frustoconical parts and an outer part having a double frustoconical recess receiving the inner parts. The die space decreases in size as the inner die parts move toward one another against the outer part and the inner parts, though very hard, do not fracture because of the mode of support provided by the outer part.

  2. Chromium at High Pressure

    NASA Astrophysics Data System (ADS)

    Jaramillo, Rafael

    2012-02-01

    Chromium has long served as the archetype of spin density wave magnetism. Recently, Jaramillo and collaborators have shown that Cr also serves as an archetype of magnetic quantum criticality. Using a combination of x-ray diffraction and electrical transport measurements at high pressures and cryogenic temperatures in a diamond anvil cell, they have demonstrated that the N'eel transition (TN) can be continuously suppressed to zero, with no sign of a concurrent structural transition. The order parameter undergoes a broad regime of exponential suppression, consistent with the weak coupling paradigm, before deviating from a BCS-like ground state within a narrow but accessible quantum critical regime. The quantum criticality is characterized by mean field scaling of TN and non mean field scaling of the transport coefficients, which points to a fluctuation-induced reconstruction of the critical Fermi surface. A comparison between pressure and chemical doping as means to suppress TN sheds light on different routes to the quantum critical point and the relevance of Fermi surface nesting and disorder at this quantum phase transition. The work by Jaramillo et al. is broadly relevant to the study of magnetic quantum criticality in a physically pure and theoretically tractable system that balances elements of weak and strong coupling. [4pt] [1] R. Jaramillo, Y. Feng, J. Wang & T. F. Rosenbaum. Signatures of quantum criticality in pure Cr at high pressure. Proc. Natl. Acad. Sci. USA 107, 13631 (2010). [0pt] [2] R. Jaramillo, Y. Feng, J. C. Lang, Z. Islam, G. Srajer, P. B. Littlewood, D. B. McWhan & T. F. Rosenbaum. Breakdown of the Bardeen-Cooper-Schrieffer ground state at a quantum phase transition. Nature 459, 405 (2009).

  3. Laser desorption ionization and peptide sequencing on laser induced silicon microcolumn arrays

    DOEpatents

    Vertes, Akos [Reston, VA; Chen, Yong [San Diego, CA

    2011-12-27

    The present invention provides a method of producing a laser-patterned silicon surface, especially silicon wafers for use in laser desorption ionization (LDI-MS) (including MALDI-MS and SELDI-MS), devices containing the same, and methods of testing samples employing the same. The surface is prepared by subjecting a silicon substrate to multiple laser shots from a high-power picosecond or femtosecond laser while in a processing environment, e.g., underwater, and generates a remarkable homogenous microcolumn array capable of providing an improved substrate for LDI-MS.

  4. High pressure capillary connector

    DOEpatents

    Renzi, Ronald F.

    2005-08-09

    A high pressure connector capable of operating at pressures of 40,000 psi or higher is provided. This connector can be employed to position a first fluid-bearing conduit that has a proximal end and a distal end to a second fluid-bearing conduit thereby providing fluid communication between the first and second fluid-bearing conduits. The connector includes (a) an internal fitting assembly having a body cavity with (i) a lower segment that defines a lower segment aperture and (ii) an interiorly threaded upper segment, (b) a first member having a first member aperture that traverses its length wherein the first member aperture is configured to accommodate the first fluid-bearing conduit and wherein the first member is positioned in the lower segment of the internal fitting assembly, and (c) a second member having a second member aperture that traverses its length wherein the second member is positioned in the upper segment of the fitting assembly and wherein a lower surface of the second member is in contact with an upper surface of the first member to assert a compressive force onto the first member and wherein the first member aperture and the second member aperture are coaxial.

  5. What Causes High Blood Pressure?

    MedlinePlus

    ... can cause high blood pressure. Renin-Angiotensin-Aldosterone System The renin-angiotensin-aldosterone system makes angiotensin and ... blood volumes and high blood pressure. Sympathetic Nervous System Activity The sympathetic nervous system has important functions ...

  6. High Blood Pressure Fact Sheet

    MedlinePlus

    ... this? Submit What's this? Submit Button Related CDC Web Sites Heart Disease Stroke High Blood Pressure Salt ... Prevent and Control Chronic Diseases Million Hearts® WISEWOMAN Web Sites with More Information About High Blood Pressure ...

  7. High blood pressure and diet

    MedlinePlus

    ... this page: //medlineplus.gov/ency/article/007483.htm High blood pressure and diet To use the sharing features on ... diet is a proven way to help control high blood pressure . These changes can also help you lose weight ...

  8. High pressure mechanical seal

    NASA Technical Reports Server (NTRS)

    Babel, Henry W. (Inventor); Anderson, Raymond H. (Inventor)

    1996-01-01

    A relatively impervious mechanical seal is formed between the outer surface of a tube and the inside surface of a mechanical fitting of a high pressure fluid or hydraulic system by applying a very thin soft metal layer onto the outer surface of the hard metal tube and/or inner surface of the hard metal fitting. The thickness of such thin metal layer is independent of the size of the tube and/or fittings. Many metals and alloys of those metals exhibit the requisite softness, including silver, gold, tin, platinum, indium, rhodium and cadmium. Suitably, the coating is about 0.0025 millimeters (0.10 mils) in thickness. After compression, the tube and fitting combination exhibits very low leak rates on the order or 10.sup.-8 cubic centimeters per second or less as measured using the Helium leak test.

  9. High pressure mechanical seal

    NASA Technical Reports Server (NTRS)

    Babel, Henry W. (Inventor); Fuson, Phillip L. (Inventor); Chickles, Colin D. (Inventor); Jones, Cherie A. (Inventor); Anderson, Raymond H. (Inventor)

    1995-01-01

    A relatively impervious mechanical seal is formed between the outer surface of a tube and the inside surface of a mechanical fitting of a high pressure fluid or hydraulic system by applying a very thin soft metal layer onto the outer surface of the hard metal tube and/or inner surface of the hard metal fitting, prior to swaging the fitting onto the tube. The thickness of such thin metal layer is independent of the size of the tube and/or fittings. Many metals and alloys of those metals exhibit the requisite softness, including silver, gold, nickel, tin, platinum, indium, rhodium and cadmium. Suitably, the coating is about 0.0025 millimeters (0.10 mils) in thickness. After swaging, the tube and fitting combination exhibits very low leak rates on the order or 10.sup.-8 cubic centimeters per second or less as meaured using the Helium leak test.

  10. High Blood Pressure - Multiple Languages

    MedlinePlus

    ... Well-Being 8 - High Blood Pressure - العربية (Arabic) MP3 Siloam Family Health Center High Blood Pressure - العربية ( ... Being 8 - High Blood Pressure - myanma bhasa (Burmese) MP3 Siloam Family Health Center Chinese, Simplified (Mandarin dialect) ( ...

  11. Controlling your high blood pressure

    MedlinePlus

    ... medlineplus.gov/ency/patientinstructions/000101.htm Controlling your high blood pressure To use the sharing features on this page, ... JavaScript. Hypertension is another term used to describe high blood pressure. High blood pressure can lead to: Stroke Heart ...

  12. [High Pressure Gas Tanks

    NASA Technical Reports Server (NTRS)

    Quintana, Rolando

    2002-01-01

    Four high-pressure gas tanks, the basis of this study, were especially made by a private contractor and tested before being delivered to NASA Kennedy Space Center. In order to insure 100% reliability of each individual tank the staff at KSC decided to again submit the four tanks under more rigorous tests. These tests were conducted during a period from April 10 through May 8 at KSC. This application further validates the predictive safety model for accident prevention and system failure in the testing of four high-pressure gas tanks at Kennedy Space Center, called Continuous Hazard Tracking and Failure Prediction Methodology (CHTFPM). It is apparent from the variety of barriers available for a hazard control that some barriers will be more successful than others in providing protection. In order to complete the Barrier Analysis of the system, a Task Analysis and a Biomechanical Study were performed to establish the relationship between the degree of biomechanical non-conformities and the anomalies found within the system on particular joints of the body. This relationship was possible to obtain by conducting a Regression Analysis to the previously generated data. From the information derived the body segment with the lowest percentage of non-conformities was the neck flexion with 46.7%. Intense analysis of the system was conducted including Preliminary Hazard Analysis (PHA), Failure Mode and Effect Analysis (FMEA), and Barrier Analysis. These analyses resulted in the identification of occurrences of conditions, which may be becoming hazardous in the given system. These conditions, known as dendritics, may become hazards and could result in an accident, system malfunction, or unacceptable risk conditions. A total of 56 possible dendritics were identified. Work sampling was performed to observe the occurrence each dendritic. The out of control points generated from a Weighted c control chart along with a Pareto analysis indicate that the dendritics "Personnel not

  13. High pressure gas metering project

    SciTech Connect

    Tripp, L.R.

    1980-07-07

    The initial research and development of a system that uses high pressure helium gas to pressurize vessels over a wide range of pressurization rates, vessel volumes, and maximum test pressures are described. A method of controlling the mass flow rate in a test vessel was developed by using the pressure difference across a capillary tube. The mass flow rate is related to the pressurization rate through a real gas equation of state. The resulting mass flow equation is then used in a control algorithm. Plots of two typical pressurization tests run on a manually operated system are included.

  14. Adsorption of basic dyes onto activated carbon using microcolumns

    SciTech Connect

    El Qada, E.N.; Allen, S.J.; Walker, G.M.

    2006-08-16

    Column studies for the adsorption of basic dyes (methylene blue, basic red, and basic yellow) onto PAC2 (activated carbon produced from bituminous coal using steam activation) and F400 were undertaken in fixed-bed microcolumns. Experimental data were correlated using the bed depth service time (BDST) model. The effect of bisolute interactions on the performance of microcolumn fixed beds was studied. The BDST model was successful in describing the breakthrough curves for the adsorption of MB onto PAC2 and predicts the experimental data with a good degree of accuracy. The results emphasized that the interactions and competition for the available binding sites have considerable influence on the efficiency of adsorbents to remove dyes from the solution.

  15. High-pressure neutron diffraction

    SciTech Connect

    Xu, Hongwu

    2011-01-10

    This lecture will cover progress and prospect of applications of high-pressure neutron diffraction techniques to Earth and materials sciences. I will first introduce general high-pressure research topics and available in-situ high-pressure techniques. Then I'll talk about high-pressure neutron diffraction techniques using two types of pressure cells: fluid-driven and anvil-type cells. Lastly, I will give several case studies using these techniques, particularly, those on hydrogen-bearing materials and magnetic transitions.

  16. High Blood Pressure in Pregnancy

    MedlinePlus

    ... of the baby. Controlling your blood pressure during pregnancy and getting regular prenatal care are important for ... your baby. Treatments for high blood pressure in pregnancy may include close monitoring of the baby, lifestyle ...

  17. Rapid N-glycan release from glycoproteins using immobilized PNGase F microcolumns.

    PubMed

    Szigeti, Marton; Bondar, Judit; Gjerde, Douglas; Keresztessy, Zsolt; Szekrenyes, Akos; Guttman, Andras

    2016-10-01

    N-glycosylation profiling of glycoprotein biotherapeutics is an essential step in each phase of product development in the biopharmaceutical industry. For example, during clone selection, hundreds of clones should be analyzed quickly from limited amounts of samples. On the other hand, identification of disease related glycosylation alterations can serve as early indicators (glycobiomarkers) for various pathological conditions in the biomedical field. Therefore, there is a growing demand for rapid and easy to automate sample preparation methods for N-glycosylation analysis. In this paper, we report on the design and implementation of immobilized recombinant glutathione-S-transferase (GST) tagged PNGase F enzyme microcolumns for rapid and efficient removal of N-linked carbohydrates from glycoproteins. Digestion speed and efficiency were compared to conventional in-solution based protocols. The use of PNGase F functionalized microcolumns resulted in efficient N-glycan removal in 10min from all major N-linked glycoprotein types of: (i) neutral (IgG), (ii) highly sialylated (fetuin), and (iii) high mannose (ribonuclease B) carbohydrate containing glycoprotein standards. The approach can be readily applied to automated sample preparation systems, such as liquid handling robots.

  18. Micro-Columnated Loop Heat Pipe: The Future of Electronic Substrates

    NASA Astrophysics Data System (ADS)

    Dhillon, Navdeep Singh

    The modern world is run by semiconductor-based electronic systems. Due to continuous improvements in semiconductor device fabrication, there is a clear trend in the market towards the development of electronic devices and components that not only deliver enhanced computing power, but are also more compact. Thermal management has emerged as the primary challenge in this scenario where heat flux dissipation of electronic chips is increasing exponentially, but conventional cooling solutions such as conduction and convection are no longer feasible. To keep device junction temperatures within the safe operating limit, there is an urgent requirement for ultra-high-conductivity thermal substrates that not only absorb and transport large heat fluxes, but can also provide localized cooling to thermal hotspots. This dissertation describes the design, modeling, and fabrication of a phase change-based, planar, ultra-thin, passive thermal transport system that is inspired by the concept of loop heat pipes and capillary pumped loops. Fabricated on silicon and Pyrex wafers using microfabrication techniques, the micro-columnated loop heat pipe (muCLHP) can be integrated directly with densely packed or multiply-stacked electronic substrates, to provide localized high-heat-flux thermal management. The muCLHP employs a dual-scale coherent porous silicon(CPS)-based micro-columnated wicking structure, where the primary CPS wick provides large capillary forces for fluid transport, while a secondary surface-wick maximizes the rate of thin-film evaporation. To overcome the wick thickness limitation encountered in conventional loop heat pipes, strategies based on MEMS surface micromachining techniques were developed to reduce parasitic heat flow from the evaporator to the compensation chamber of the device. Finite element analysis was used to confirm this reduction in a planar evaporator design, thus enabling the generation of a large motive temperature head for continuous device operation

  19. High Blood Pressure

    MedlinePlus

    ... is at rest between beats Health care workers write blood pressure numbers with the systolic number above ... available to discuss recent findings and ongoing research projects about health conditions and social determinants that disproportionately ...

  20. High Blood Pressure (Hypertension)

    MedlinePlus

    ... Practice healthy coping techniques, such as muscle relaxation, deep breathing or meditation. Getting regular physical activity and ... blood pressure at home. Practice relaxation or slow, deep breathing. Practice taking deep, slow breaths to help ...

  1. High Blood Pressure (Hypertension)

    MedlinePlus

    ... can improve your health in other ways. Mastering stress management techniques can lead to other behavior changes — including those that reduce your blood pressure. When looking for ways to manage stress, remember that you have many options. For example: ...

  2. The High Pressure Nervous Syndrome and Other High Pressure Effects.

    DTIC Science & Technology

    Many of the problems of exposing man to a high pressure environment depend overtly on the properties of gases in the gaseous phase--such as the...or to changes in pressure. These are the subject of this chapter. The distinction is an arbitrary one, since both hyperbaric arthralgia and the high

  3. High pressure storage vessel

    SciTech Connect

    Liu, Qiang

    2013-08-27

    Disclosed herein is a composite pressure vessel with a liner having a polar boss and a blind boss a shell is formed around the liner via one or more filament wrappings continuously disposed around at least a substantial portion of the liner assembly combined the liner and filament wrapping have a support profile. To reduce susceptible to rupture a locally disposed filament fiber is added.

  4. Stroke and High Blood Pressure

    MedlinePlus

    ... Disease Venous Thromboembolism Aortic Aneurysm More How High Blood Pressure Can Lead to Stroke Updated:May 3,2017 ... This content was last reviewed October 2016. High Blood Pressure • Home • Get the Facts About HBP • Know Your ...

  5. Electrokinetically pumped high pressure sprays

    DOEpatents

    Schoeniger, Joseph S.; Paul, Phillip H.; Schoeniger, Luke

    2002-01-01

    An electrokinetic pump capable of producing high pressure is combined with a nozzle having a submicron orifice to provide a high pressure spray device. Because of its small size, the device can be contained within medical devices such as an endoscope for delivering biological materials such as DNA, chemo therapeutic agents, or vaccines to tissues and cells.

  6. Electrokinetically pumped high pressure sprays

    DOEpatents

    Schoeniger, Joseph S.; Paul, Phillip H.; Schoeniger, Luke

    2005-11-01

    An electrokinetic pump capable of producing high pressure is combined with a nozzle having a submicron orifice to provide a high pressure spray device. Because of its small size, the device can be contained within medical devices such as an endoscope for delivering biological materials such as DNA, chemo therapeutic agents, or vaccines to tissues and cells.

  7. Managing High Blood Pressure Medications

    MedlinePlus

    ... Artery Disease Venous Thromboembolism Aortic Aneurysm More Managing High Blood Pressure Medications Updated:Jan 3,2017 When your doctor ... health. This content was last reviewed October 2016. High Blood Pressure • Home • Get the Facts About HBP • Know Your ...

  8. High Blood Pressure and Women

    MedlinePlus

    ... Peripheral Artery Disease Venous Thromboembolism Aortic Aneurysm More High Blood Pressure and Women Updated:Dec 14,2016 Pregnancy and ... Women . This content was last reviewed October 2016. High Blood Pressure • Home • Get the Facts About HBP • Know Your ...

  9. High pressure ices

    PubMed Central

    Hermann, Andreas; Ashcroft, N. W.; Hoffmann, Roald

    2012-01-01

    H2O will be more resistant to metallization than previously thought. From computational evolutionary structure searches, we find a sequence of new stable and meta-stable structures for the ground state of ice in the 1–5 TPa (10 to 50 Mbar) regime, in the static approximation. The previously proposed Pbcm structure is superseded by a Pmc21 phase at p = 930 GPa, followed by a predicted transition to a P21 crystal structure at p = 1.3 TPa. This phase, featuring higher coordination at O and H, is stable over a wide pressure range, reaching 4.8 TPa. We analyze carefully the geometrical changes in the calculated structures, especially the buckling at the H in O-H-O motifs. All structures are insulating—chemistry burns a deep and (with pressure increase) lasting hole in the density of states near the highest occupied electronic levels of what might be component metallic lattices. Metallization of ice in our calculations occurs only near 4.8 TPa, where the metallic C2/m phase becomes most stable. In this regime, zero-point energies much larger than typical enthalpy differences suggest possible melting of the H sublattice, or even the entire crystal. PMID:22207625

  10. Medications for High Blood Pressure

    MedlinePlus

    ... Products For Consumers Home For Consumers Consumer Updates Medications for High Blood Pressure Share Tweet Linkedin Pin ... all their lives. back to top Types of Medications FDA has approved many medications to treat high ...

  11. High pressure synthesis gas fermentation

    SciTech Connect

    Not Available

    1991-01-01

    Construction of the high pressure gas phase fermentation system is nearing completion. All non-explosion proof components will be housed separately in a gas-monitored plexiglas cabinet. A gas-monitoring system has been designed to ensure the safety of the operations in case of small or large accidental gas releases. Preliminary experiments investigating the effects of high pressure on Clostridium 1jungdahlii have shown that growth and CO uptake are not negatively affected and CO uptake by an increased total pressure of 100 psig at a syngas partial pressure of 10 psig.

  12. Nanomaterials under high-pressure.

    PubMed

    San-Miguel, Alfonso

    2006-10-01

    The use of high-pressure for the study and elaboration of homogeneous nanostructures is critically reviewed. Size effects, the interaction between nanostructures and guest species or the interaction of the nanosystem with the pressure transmitting medium are emphasized. Phase diagrams and the possibilities opened by the combination of pressure and temperature for the elaboration of new nanomaterials is underlined through the examination of three different systems: nanocrystals, nano-cage materials which include fullerites and group-14 clathrates, and single wall nanotubes. This tutorial review is addressed to scientist seeking an introduction or a panoramic view of the study of nanomaterials under high-pressure.

  13. High-Pressure Vibrational Spectroscopy.

    NASA Astrophysics Data System (ADS)

    Pogson, Mark

    1987-09-01

    Available from UMI in association with The British Library. Requires signed TDF. The study of solids at high pressure and variable temperature enables development of accurate interatomic potential functions over wide ranges of interatomic distances. A review of the main models used in the determination of these potentials is given in Chapter one. A discussion of phonon frequency as a variable physical parameter reflecting the interatomic potential is given. A high pressure Raman study of inorganic salts of the types MSCN, (M = K,Rb,Cs & NH_4^+ ) and MNO_2, (M = K,Na) has been completed. The studies have revealed two new phases in KNO_2 and one new phase in NaNO _2 at high pressure. The accurate phonon shift data have enabled the determination of the pure and biphasic stability regions of the phases of KNO _2. A discussion of the B1, B2 relationship of univalent nitrites is also given. In the series of thiocyanates studied new phases have been found in all four materials. In both the potassium and rubidium salts two new phases have been detected, and in the ceasium salt one new phase has been detected, all at high pressure, from accurate phonon shift data. These transitions are discussed in terms of second-order mechanisms with space groups suggested for all phases, based on Landau's theory of second-order phase transitions. In the ammonium salt one new phase has been detected. This new phase transition has been interpreted as a second-order transition. The series of molecular crystals CH_3 HgX, (X = Cl,Br & I) has been studied at high pressure and at variable temperature. In Chapter five, their phase behaviour at high pressure is detailed along with the pressure dependencies of their phonon frequencies. In the chloride and the bromide two new phases have been detected. In the bromide one has been detected at high temperature and one at high pressure, and latter being interpreted as the stopping of the methyl rotation. In the chloride one phase has been found at

  14. High Blood Pressure Increasing Worldwide

    MedlinePlus

    ... other ways to control blood pressure, including healthy lifestyle choices and maintaining a normal weight, Roth said. Murray said some of the factors responsible for the worldwide increase in high blood pressure are unhealthy diets and obesity. In addition, in developing countries, more people are ...

  15. Steam Oxidation at High Pressure

    SciTech Connect

    Holcomb, Gordon R.; Carney, Casey

    2013-07-19

    A first high pressure test was completed: 293 hr at 267 bar and 670{degrees}C; A parallel 1 bar test was done for comparison; Mass gains were higher for all alloys at 267 bar than at 1 bar; Longer term exposures, over a range of temperatures and pressures, are planned to provide information as to the commercial implications of pressure effects; The planned tests are at a higher combination of temperatures and pressures than in the existing literature. A comparison was made with longer-term literature data: The short term exposures are largely consistent with the longer-term corrosion literature; Ferritic steels--no consistent pressure effect; Austenitic steels--fine grain alloys less able to maintain protective chromia scale as pressure increases; Ni-base alloys--more mass gains above 105 bar than below. Not based on many data points.

  16. High-pressure optical studies

    SciTech Connect

    Drickamer, H.G.

    1981-01-01

    High pressure experimentation may concern intrinsically high pressure phenomena, or it may be used to gain a better understanding of states or processes at one atmosphere. The latter application is probably more prevelant in condensed matter physics. Under this second rubric one may either use high pressure to perturb various electronic energy levels and from this pressure tuning characterize states or processes, or one can use pressure to change a macroscopic parameter in a controlled way, then measure the effect on some molecular property. In this paper, the pressure tuning aspect is emphasized, with a lesser discussion of macroscopic - molecular relationships. In rare earth chelates the efficiency of 4f-4f emission of the rare earth is controlled by the feeding from the singlet and triplet levels of the organic ligand. These ligand levels can be strongly shifted by pressure. A study of the effect of pressure on the emission efficiency permits one to understand the effect of ligand modification at one atmosphere. Photochromic crystals change color upon irradiation due to occupation of a metastable ground state. In thermochromic crystals, raising the temperature accomplishes the same results. For a group of molecular crystals (anils) at high pressure, the metastable state can be occupied at room temperature. The relative displacement of the energy levels at high pressure also inhibits the optical process. Effects on luminescence intensity are shown to be consistent. In the area of microscopic - molecular relationships, the effect of viscosity and dielectric properties on rates of non-radiative (thermal) and radiative emission, and on peak energy for luminescence is demonstrated. For systems which can emit from either of two excited states depending on the interaction with the environment, the effect of rigidity of the medium on the rate of rearrangement of the excited state is shown.

  17. High School Press Pressures.

    ERIC Educational Resources Information Center

    Rogers, Luella P.

    History shows that the high school press suffers through cycles that reflect economic factors and cultural climates within communities, states, and the nation. The direction of that cycle in the 1960s and early 1970s was toward more open, free-flowing information by a vigorous student press, but those economic and cultural signs now are pointing…

  18. High School Press Pressures.

    ERIC Educational Resources Information Center

    Rogers, Luella P.

    History shows that the high school press suffers through cycles that reflect economic factors and cultural climates within communities, states, and the nation. The direction of that cycle in the 1960s and early 1970s was toward more open, free-flowing information by a vigorous student press, but those economic and cultural signs now are pointing…

  19. High pressure ceramic joint

    DOEpatents

    Ward, Michael E.; Harkins, Bruce D.

    1993-01-01

    Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present joint when used with recuperators increases the use of ceramic components which do not react to highly corrosive gases. Thus, the present joint used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present joint is comprised of a first ceramic member, a second ceramic member, a mechanical locking device having a groove defined in one of the first ceramic member and the second ceramic member. The joint and the mechanical locking device is further comprised of a refractory material disposed in the groove and contacting the first ceramic member and the second ceramic member. The present joint mechanically provides a high strength load bearing joint having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

  20. High pressure ceramic joint

    DOEpatents

    Ward, M.E.; Harkins, B.D.

    1993-11-30

    Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present joint when used with recuperators increases the use of ceramic components which do not react to highly corrosive gases. Thus, the present joint used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present joint is comprised of a first ceramic member, a second ceramic member, a mechanical locking device having a groove defined in one of the first ceramic member and the second ceramic member. The joint and the mechanical locking device is further comprised of a refractory material disposed in the groove and contacting the first ceramic member and the second ceramic member. The present joint mechanically provides a high strength load bearing joint having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures. 4 figures.

  1. High pressure synthesis gas fermentation

    SciTech Connect

    Not Available

    1992-01-01

    The construction of the high pressure gas phase fermentation system has been completed. Photographs of the various components of the system are presented, along with an operating procedure for the equipment.

  2. High Blood Pressure and Pregnancy

    MedlinePlus

    ... damage. Some women with gestational hypertension eventually develop preeclampsia. Chronic hypertension. Chronic hypertension is high blood pressure ... determine when it began. Chronic hypertension with superimposed preeclampsia. This condition occurs in women with chronic hypertension ...

  3. What Is High Blood Pressure?

    MedlinePlus

    ... consistently too high. How your blood pressure and circulatory system work In order to survive and function properly, ... and organs need the oxygenated blood that your circulatory system carries throughout the body. When the heart beats, ...

  4. High Pressure Industrial Water Facility

    NASA Technical Reports Server (NTRS)

    1992-01-01

    In conjunction with Space Shuttle Main Engine testing at Stennis, the Nordberg Water Pumps at the High Pressure Industrial Water Facility provide water for cooling the flame deflectors at the test stands during test firings.

  5. Electrokinetic high pressure hydraulic system

    DOEpatents

    Paul, Phillip H.; Rakestraw, David J.

    2000-01-01

    A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.

  6. Microcolumns with self-assembled particle frits for proteomics.

    PubMed

    Ishihama, Yasushi; Rappsilber, Juri; Andersen, Jens S; Mann, Matthias

    2002-12-06

    LC-MS-MS experiments in proteomics are usually performed with packed microcolumns employing frits or outlets smaller than the particle diameter to retain the packing material. We have developed packed microcolumns using self-assembled particles (SAPs) as frits that are smaller than the size of the outlet. A five to one ratio of outlet size to particle diameter appears to be the upper maximum. In these situations the particles assembled into an arch over the outlet like the stones in a stone bridge. When 3 microm particles were packed into a tapered column with an 8 microm outlet, two particles bridged the outlet with 0.3 pl dead volume and perfect success rate. In peptide analysis by LC-MS, the peak width at half height was normally less than 6 s, compared to 12 s without SAPs. The LC-MS-MS system provided 37% sequence coverage (21 matched peptides) for a tryptically-digested sample of 10 fmol bovine serum albumin. We also describe application of the SAP principle to make disposable pipette tip columns with short pieces of fused-silica capillary as the outlet.

  7. Simultaneous determination of fat-soluble vitamins and provitamins in milk by microcolumn liquid chromatography.

    PubMed

    Gomis, D B; Fernández, M P; Gutiérrez Alvarez, M D

    2000-09-01

    The fat-soluble vitamins A, D2, D3, E and K1, retinyl acetate, retinyl palmitate, tocopherol acetate, ergosterol and 7-dehydrocholesterol in milk were separated on a packed reversed-phase fused-silica microcolumn, and determined with UV detection. Conventional liquid chromatographic equipment was adapted for such purposes, providing a highly efficient and sensitive analytical system. The vitamins could be separated in gradient mode with detection limits comprised between 0.02 ng/ml for retinol and 2 ng/ml for vitamin E. All vitamins were separated in less than 17 min. Recovery studies showed good results for all solutes (89-107%) and the intra-day coefficients of variations ranged from 2 to 8%. Application of the proposed method to the quantification of fat-soluble vitamins in milk is reported.

  8. Electrokinetic high pressure hydraulic system

    DOEpatents

    Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

    2003-06-03

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based system. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  9. Electrokinetic high pressure hydraulic system

    DOEpatents

    Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

    2001-01-01

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  10. High-pressure creep tests

    NASA Technical Reports Server (NTRS)

    Bhattacharyya, S.; Lamoureux, J.; Hales, C.

    1986-01-01

    The automotive Stirling engine, presently being developed by the U.S. Department of Energy and NASA, uses high-pressure hydrogen as a working fluid; its long-term effects on the properties of alloys are relatively unknown. Hence, creep-rupture testing of wrought and cast high-temperature alloys in high-pressure hydrogen is an essential part of the research supporting the development of the Stirling cycle engine. Attention is given to the design, development, and operation of a 20 MPa hydrogen high-temperature multispecimen creep-rupture possessing high sensitivity. This pressure vessel allows for the simultaneous yet independent testing of six specimens. The results from one alloy, XF-818, are presented to illustrate how reported results are derived from the raw test data.

  11. High pressure synthesis gas conversion. Task 3: High pressure profiles

    SciTech Connect

    Not Available

    1993-05-01

    The purpose of this research project was to build and test a high pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system were procured or fabricated and assembled in our laboratory. This system was then used to determine the effects of high pressure on growth and ethanol production by C. 1jungdahlii. The limits of cell concentration and mass transport relationships were found in CSTR and immobilized cell reactors (ICR). The minimum retention times and reactor volumes were found for ethanol production in these reactors.

  12. Electrochemical studies at high pressure

    SciTech Connect

    Cruanes, M.T.

    1993-01-01

    This research has dealt with the development and application of a methodology that permits electrochemical measurements at high pressure. The initial efforts focused on the design and construction of an electrochemical cell functional at hydrostatic pressures as high as 10 kbar. This cell was equipped with an Ag/AgCl/KCl (0.1M) reference electrode which provides reliable control of the potential at all pressures. The potential of this reference electrode can be considered to be constant with pressure. Measurements of formal potentials (E[degrees][prime]) of several transition-metal complexes vs the Ag/AgCl electrode rendered volumes of reactions whose magnitudes support the prediction of the negligible pressure dependence of the reference electrode. The main systems that have been investigated at high pressure are surface-modified electrodes. The author studied the effect of compression on the dynamics of charge transport in quaternized poly(4-vinylpyridine) (QPVP) films placed on gold electrodes, loaded with potassium ferricyanide, and equilibrated in potassium nitrate. Pressure accomplished the continuous change in the structure of the polymer network. This change causes a pronounced restriction in the propagation of charge and in the motion of mass. This high-pressure methodology has also allowed the spatial characterization of electron transfer events taking place between a gold electrode and ferrocene molecules covalently attached to the end of 1-undodecanethiol chains self-assembled on the electrode surface. The volumes of reaction and activation for the oxidation process are both positive, indicating that a volume expansion is associated with the formation of ferricinium. A model is proposed in which the creation of a vacancy in the self-assembled monolayer, for the accommodation of the ferricinium ion or a charge-compensating anion, is coupled with the electron transfer step.

  13. Electronic phenomena at high pressure

    SciTech Connect

    Drickamer, H.G.

    1981-01-01

    High pressure research is undertaken either to investigate intrinsically high pressure phenomena or in order to get a better understanding of the effect of the chemical environment on properties or processes at one atmosphere. Studies of electronic properties which fall in each area are presented. Many molecules and complexes can assume in the excited state different molecular arrangements and intermolecular forces depending on the medium. Their luminescence emission is then very different in a rigid or a fluid medium. With pressure one can vary the viscosity of the medium by a factor of 10/sup 7/ and thus control the distribution and rate of crossing between the excited state conformations. In rare earth chelates the efficiency of 4f-4f emission of the rare earth is controlled by the feeding from the singlet and triplet levels of the organic ligand. These ligand levels can be strongly shifted by pressure. A study of the effect of pressure on the emission efficiency permits one to understand the effect of ligand chemistry at one atmosphere. At high pressure electronic states can be sufficiently perturbed to provide new ground states. In EDA complexes these new ground states exhibit unusual chemical reactivity and new products.

  14. High pressure neon arc lamp

    DOEpatents

    Sze, Robert C.; Bigio, Irving J.

    2003-07-15

    A high pressure neon arc lamp and method of using the same for photodynamic therapies is provided. The high pressure neon arc lamp includes a housing that encloses a quantity of neon gas pressurized to about 500 Torr to about 22,000 Torr. At each end of the housing the lamp is connected by electrodes and wires to a pulse generator. The pulse generator generates an initial pulse voltage to breakdown the impedance of the neon gas. Then the pulse generator delivers a current through the neon gas to create an electrical arc that emits light having wavelengths from about 620 nanometers to about 645 nanometers. A method for activating a photosensitizer is provided. Initially, a photosensitizer is administered to a patient and allowed time to be absorbed into target cells. Then the high pressure neon arc lamp is used to illuminate the target cells with red light having wavelengths from about 620 nanometers to about 645 nanometers. The red light activates the photosensitizers to start a chain reaction that may involve oxygen free radicals to destroy the target cells. In this manner, a high pressure neon arc lamp that is inexpensive and efficiently generates red light useful in photodynamic therapy is provided.

  15. High pressure liquid level monitor

    DOEpatents

    Bean, Vern E.; Long, Frederick G.

    1984-01-01

    A liquid level monitor for tracking the level of a coal slurry in a high-pressure vessel including a toroidal-shaped float with magnetically permeable bands thereon disposed within the vessel, two pairs of magnetic field generators and detectors disposed outside the vessel adjacent the top and bottom thereof and magnetically coupled to the magnetically permeable bands on the float, and signal processing circuitry for combining signals from the top and bottom detectors for generating a monotonically increasing analog control signal which is a function of liquid level. The control signal may be utilized to operate high-pressure control valves associated with processes in which the high-pressure vessel is used.

  16. A computational model for the loss of neuronal organization in microcolumns.

    PubMed

    Henderson, Maxwell; Urbanc, Brigita; Cruz, Luis

    2014-05-20

    A population of neurons in the cerebral cortex of humans and other mammals organize themselves into vertical microcolumns perpendicular to the pial surface. Anatomical changes to these microcolumns have been correlated with neurological diseases and normal aging; in particular, in area 46 of the rhesus monkey brain, the strength of microcolumns was shown to decrease with age. These changes can be caused by alterations in the spatial distribution of the neurons in microcolumns and/or neuronal loss. Using a three-dimensional computational model of neuronal arrangements derived from thin tissue sections and validated in brain tissue from rhesus monkeys, we show that neuronal loss is inconsistent with the findings in aged individuals. In contrast, a model of simple random neuronal displacements, constrained in magnitude by restorative harmonic forces, is consistent with observed changes and provides mechanistic insights into the age-induced loss of microcolumnar structure. Connection of the model to normal aging and disease are discussed.

  17. Anxiety: A Cause of High Blood Pressure?

    MedlinePlus

    ... Conditions High blood pressure (hypertension) Can anxiety cause high blood pressure? Answers from Sheldon G. Sheps, M.D. Anxiety doesn't cause long-term high blood pressure (hypertension). But episodes of anxiety can cause dramatic, ...

  18. High Blood Pressure: Medicines to Help You

    MedlinePlus

    ... For Consumers Consumer Information by Audience For Women High Blood Pressure--Medicines to Help You Share Tweet Linkedin Pin ... Click here for the Color Version (PDF 533KB) High blood pressure is a serious illness. High blood pressure is ...

  19. Micro-column plasma emission liquid chromatograph. [Patent application

    DOEpatents

    Gay, D.D.

    1982-08-12

    In a direct current plasma emission spectrometer for use in combination with a microcolumn liquid chromatograph, an improved plasma source unit is claimed. The plasma source unit includes a quartz capillary tube having an inlet means, outlet off gas means and a pair of spaced electrodes defining a plasma region in the tube. The inlet means is connected to and adapted to receive eluant of the liquid chromatograph along with a stream of plasma-forming gas. There is an opening through the wall of the capillary tube penetrating into the plasma region. A soft glass capillary light pipe is disposed at the opening, is connected to the spectrometer, and is adapted to transmit light passing from the plasma region to the spectrometer. There is also a source of electromotive force connected to the electrodes sufficient to initiate and sustain a plasma in the plasma region of the tube.

  20. High-pressure water facility

    NASA Technical Reports Server (NTRS)

    2006-01-01

    NASA Test Operations Group employees, from left, Todd Pearson, Tim Delcuze and Rodney Wilkinson maintain a water pump in Stennis Space Center's high-pressure water facility. The three were part of a group of employees who rode out Hurricane Katrina at the facility and helped protect NASA's rocket engine test complex.

  1. High-pressure water facility

    NASA Image and Video Library

    2006-02-15

    NASA Test Operations Group employees, from left, Todd Pearson, Tim Delcuze and Rodney Wilkinson maintain a water pump in Stennis Space Center's high-pressure water facility. The three were part of a group of employees who rode out Hurricane Katrina at the facility and helped protect NASA's rocket engine test complex.

  2. High-pressure water facility

    NASA Technical Reports Server (NTRS)

    2006-01-01

    NASA Test Operations Group employees, from left, Todd Pearson, Tim Delcuze and Rodney Wilkinson maintain a water pump in Stennis Space Center's high-pressure water facility. The three were part of a group of employees who rode out Hurricane Katrina at the facility and helped protect NASA's rocket engine test complex.

  3. High pressure paint gun injuries.

    PubMed

    Booth, C M

    1977-11-19

    Despite their use for the past 20 years the dangers of injuries from high pressure paint guns are not widely known. Two cases treated incorrectly through ignorance in our casualty department resulted in amputation of digits. Paint solvents are far moe damaging than paint of grease injection. All cases should be treated urgently by an experienced surgeon as fairly extensive surgery may be needed.

  4. High Pressure Treatment in Foods

    PubMed Central

    Torres Bello, Edwin Fabian; González Martínez, Gerardo; Klotz Ceberio, Bernadette F.; Rodrigo, Dolores; Martínez López, Antonio

    2014-01-01

    High hydrostatic pressure (HHP), a non-thermal technology, which typically uses water as a pressure transfer medium, is characterized by a minimal impact on food characteristics (sensory, nutritional, and functional). Today, this technology, present in many food companies, can effectively inactivate bacterial cells and many enzymes. All this makes HHP very attractive, with very good acceptance by consumers, who value the organoleptic characteristics of products processed by this non-thermal food preservation technology because they associate these products with fresh-like. On the other hand, this technology reduces the need for non-natural synthetic additives of low consumer acceptance. PMID:28234332

  5. High Pressure Treatment in Foods.

    PubMed

    Bello, Edwin Fabian Torres; Martínez, Gerardo González; Ceberio, Bernadette F Klotz; Rodrigo, Dolores; López, Antonio Martínez

    2014-08-19

    High hydrostatic pressure (HHP), a non-thermal technology, which typically uses water as a pressure transfer medium, is characterized by a minimal impact on food characteristics (sensory, nutritional, and functional). Today, this technology, present in many food companies, can effectively inactivate bacterial cells and many enzymes. All this makes HHP very attractive, with very good acceptance by consumers, who value the organoleptic characteristics of products processed by this non-thermal food preservation technology because they associate these products with fresh-like. On the other hand, this technology reduces the need for non-natural synthetic additives of low consumer acceptance.

  6. High pressure rinsing system comparison

    SciTech Connect

    D. Sertore; M. Fusetti; P. Michelato; Carlo Pagani; Toshiyasu Higo; Jin-Seok Hong; K. Saito; G. Ciovati; T. Rothgeb

    2007-06-01

    High pressure rinsing (HPR) is a key process for the surface preparation of high field superconducting cavities. A portable apparatus for the water jet characterization, based on the transferred momentum between the water jet and a load cell, has been used in different laboratories. This apparatus allows to collected quantitative parameters that characterize the HPR water jet. In this paper, we present a quantitative comparison of the different water jet produced by various nozzles routinely used in different laboratories for the HPR process

  7. High-field/high-pressure ESR

    NASA Astrophysics Data System (ADS)

    Sakurai, T.; Okubo, S.; Ohta, H.

    2017-07-01

    We present a historical review of high-pressure ESR systems with emphasis on our recent development of a high-pressure, high-field, multi-frequency ESR system. Until 2000, the X-band system was almost established using a resonator filled with dielectric materials or a combination of the anvil cell and dielectric resonators. Recent developments have shifted from that in the low-frequency region, such as X-band, to that in multi-frequency region. High-pressure, high-field, multi-frequency ESR systems are classified into two types. First are the systems that use a vector network analyzer or a quasi-optical bridge, which have high sensitivity but a limited frequency region; the second are like our system, which has a very broad frequency region covering the THz region, but lower sensitivity. We will demonstrate the usefulness of our high-pressure ESR system, in addition to its experimental limitations. We also discuss the recent progress of our system and future plans.

  8. High-speed pressure clamp.

    PubMed

    Besch, Stephen R; Suchyna, Thomas; Sachs, Frederick

    2002-10-01

    We built a high-speed, pneumatic pressure clamp to stimulate patch-clamped membranes mechanically. The key control element is a newly designed differential valve that uses a single, nickel-plated piezoelectric bending element to control both pressure and vacuum. To minimize response time, the valve body was designed with minimum dead volume. The result is improved response time and stability with a threefold decrease in actuation latency. Tight valve clearances minimize the steady-state air flow, permitting us to use small resonant-piston pumps to supply pressure and vacuum. To protect the valve from water contamination in the event of a broken pipette, an optical sensor detects water entering the valve and increases pressure rapidly to clear the system. The open-loop time constant for pressure is 2.5 ms for a 100-mmHg step, and the closed-loop settling time is 500-600 micros. Valve actuation latency is 120 micros. The system performance is illustrated for mechanically induced changes in patch capacitance.

  9. High pressure and high temperature apparatus

    DOEpatents

    Voronov, Oleg A.

    2005-09-13

    A design for high pressure/high temperature apparatus and reaction cell to achieve .about.30 GPa pressure in .about.1 cm volume and .about.100 GPa pressure in .about.1 mm volumes and 20-5000.degree. C. temperatures in a static regime. The device includes profiled anvils (28) action on a reaction cell (14, 16) containing the material (26) to be processed. The reaction cell includes a heater (18) surrounded by insulating layers and screens. Surrounding the anvils are cylindrical inserts and supporting rings (30-48) whose hardness increases towards the reaction cell. These volumes may be increased considerably if applications require it, making use of presses that have larger loading force capability, larger frames and using larger anvils.

  10. High-pressure injection injuries.

    PubMed

    Neal, N C; Burke, F D

    1991-11-01

    A retrospective review of the 11 patients attending the Hand Unit at the Derbyshire Royal Infirmary over the last 5 years with high-pressure injection injuries is presented. The machines and materials that cause these injuries are outlined and the methods of treatment and rehabilitation are described in detail. The study demonstrates the morbidity of high-pressure injection injuries, particularly those inflicted by paint spray guns, and highlights a frequent delay between injury and decompression of the injured part. We wish to emphasize the importance of early diagnosis, referral, exploration and rehabilitation to ensure an optimal outcome, and to point out that failure to refer early is becoming an increasing focus of negligence claims.

  11. High pressure paint gun injuries.

    PubMed Central

    Booth, C M

    1977-01-01

    Despite their use for the past 20 years the dangers of injuries from high pressure paint guns are not widely known. Two cases treated incorrectly through ignorance in our casualty department resulted in amputation of digits. Paint solvents are far moe damaging than paint of grease injection. All cases should be treated urgently by an experienced surgeon as fairly extensive surgery may be needed. Images FIG 1 FIG 2 FIG 3 FIG 4 PMID:589172

  12. High Blood Pressure (Hypertension) (For Parents)

    MedlinePlus

    ... Old Feeding Your 1- to 2-Year-Old High Blood Pressure (Hypertension) KidsHealth > For Parents > High Blood Pressure (Hypertension) A ... posture, and medications. continue Long-Term Effects of High Blood Pressure When someone has high blood pressure, the heart ...

  13. High pressure xenon ionization detector

    DOEpatents

    Markey, J.K.

    1989-11-14

    A method is provided for detecting ionization comprising allowing particles that cause ionization to contact high pressure xenon maintained at or near its critical point and measuring the amount of ionization. An apparatus is provided for detecting ionization, the apparatus comprising a vessel containing a ionizable medium, the vessel having an inlet to allow high pressure ionizable medium to enter the vessel, a means to permit particles that cause ionization of the medium to enter the vessel, an anode, a cathode, a grid and a plurality of annular field shaping rings, the field shaping rings being electrically isolated from one another, the anode, cathode, grid and field shaping rings being electrically isolated from one another in order to form an electric field between the cathode and the anode, the electric field originating at the anode and terminating at the cathode, the grid being disposed between the cathode and the anode, the field shaping rings being disposed between the cathode and the grid, the improvement comprising the medium being xenon and the vessel being maintained at a pressure of 50 to 70 atmospheres and a temperature of 0 to 30 C. 2 figs.

  14. High pressure xenon ionization detector

    DOEpatents

    Markey, John K.

    1989-01-01

    A method is provided for detecting ionization comprising allowing particles that cause ionization to contact high pressure xenon maintained at or near its critical point and measuring the amount of ionization. An apparatus is provided for detecting ionization, the apparatus comprising a vessel containing a ionizable medium, the vessel having an inlet to allow high pressure ionizable medium to enter the vessel, a means to permit particles that cause ionization of the medium to enter the vessel, an anode, a cathode, a grid and a plurality of annular field shaping rings, the field shaping rings being electrically isolated from one another, the anode, cathode, grid and field shaping rings being electrically isolated from one another in order to form an electric field between the cathode and the anode, the electric field originating at the anode and terminating at the cathode, the grid being disposed between the cathode and the anode, the field shaping rings being disposed between the cathode and the grid, the improvement comprising the medium being xenon and the vessel being maintained at a pressure of 50 to 70 atmospheres and a temperature of 0.degree. to 30.degree. C.

  15. High pressure synthesis gas fermentation

    SciTech Connect

    Not Available

    1991-01-01

    The purpose of this research project is to build and test a pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system will be procured or fabricated and assembled in our laboratory. This system will then be used to determine the effects of high pressure on growth and ethanol production by clostridium ljungdahlii. The limits of cell concentration and mass transport relationships will be found in continuous stirred tank reactor and immobilized cell reactors. The minimum retention times and reactor volumes will be found for ethanol production in these reactors. Retention times of a few seconds are expected to result from these experiments. 2 figs., 2 tabs.

  16. High Pressure Electrolyzer System Evaluation

    NASA Technical Reports Server (NTRS)

    Prokopius, Kevin; Coloza, Anthony

    2010-01-01

    This report documents the continuing efforts to evaluate the operational state of a high pressure PEM based electrolyzer located at the NASA Glenn Research Center. This electrolyzer is a prototype system built by General Electric and refurbished by Hamilton Standard (now named Hamilton Sunstrand). It is capable of producing hydrogen and oxygen at an output pressure of 3000 psi. The electrolyzer has been in storage for a number of years. Evaluation and testing was performed to determine the state of the electrolyzer and provide an estimate of the cost for refurbishment. Pressure testing was performed using nitrogen gas through the oxygen ports to ascertain the status of the internal membranes and seals. It was determined that the integrity of the electrolyzer stack was good as there were no appreciable leaks in the membranes or seals within the stack. In addition to the integrity testing, an itemized list and part cost estimate was produced for the components of the electrolyzer system. An evaluation of the system s present state and an estimate of the cost to bring it back to operational status was also produced.

  17. Silicon nanowires under high pressure

    NASA Astrophysics Data System (ADS)

    Wang, Yuejian

    2009-03-01

    Silicon nanowires (Si NWs), one-dimensional single crystalline, have recently drawn extensive attention, thanks to their robust applications in electrical and optical devices as well as in the strengthening of diamond/SiC superhard composites. Here, we conducted high-pressure synchrotron diffraction experiments in a diamond anvil cell to study phase transitions and compressibility of Si NWs. Our results revealed that the onset pressure for the Si I-II transformation in Si NWs is approximately 2.0 GPa lower than previously determined values for bulk Si, a trend that is consistent with the analysis of misfit in strain energy. The bulk modulus of Si-I NWs derived from the pressure-volume measurements is 123 GPa, which is comparable to that of Si-V NWs but 25% larger than the reported values for bulk silicon. The reduced compressibility in Si NWs indicates that the unique wire-like structure in nanoscale plays vital roles in the elastic behavior of condensed matter..

  18. Improved high pressure turbine shroud

    NASA Technical Reports Server (NTRS)

    Bessen, I. I.; Rigney, D. V.; Schwab, R. C.

    1977-01-01

    A new high pressure turbine shroud material has been developed from the consolidation of prealloyed powders of Ni, Cr, Al and Y. The new material, a filler for cast turbine shroud body segments, is called Genaseal. The development followed the identification of oxidation resistance as the primary cause of prior shroud deterioration, since conversion to oxides reduces erosion resistance and increases spalling under thermal cycled engine conditions. The NICrAlY composition was selected in preference to NIAL and FeCRALY alloys, and was formulated to a prescribed density range that offers suitable erosion resistance, thermal conductivity and elastic modulus for improved behavior as a shroud.

  19. Electokinetic high pressure hydraulic system

    DOEpatents

    Paul, Phillip H.; Rakestraw, David J.

    2000-01-01

    A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.

  20. Nano Materials Under High Pressures

    SciTech Connect

    Karmakar, S.; Garg, Nandini; Sharma, Surinder M.

    2010-12-01

    Materials comprising of units or particles of the size of a few nano-meters have significantly different high pressure behavior than their bulk counterparts. This is abundantly elucidated in our studies on transition metals encapsulated in carbon nanotubes. Carbon nanotubes filled with Argon also show that it affects the behavior of tubes as well as argon. Studies on nano-crystalline Si displays an interesting crystalline-amorphous reversible transition, unique of its kind in elemental solids. We also demonstrate that in some cases of nanocrystalline samples, a phase perceived to be an intermediate-transient may be actually realized.

  1. Enhancing local luminescence in a hollow ZnO microcolumn by antiresonant reflecting

    NASA Astrophysics Data System (ADS)

    Yang, Y. H.; He, X. T.; Dong, H. M.; Dong, J. W.; Lei, H. X.; Li, B. J.; Yang, G. W.

    2016-04-01

    Hollow ZnO microcolumns with size induced photoluminescence and cathodoluminescence properties were prepared by a thermal chemical vapor transport and condensation method. It was found that the luminescence emission could be confined in the nano-sized hollow core and the wavelength dependent light intensity could be influenced by the geometric structure of the ZnO microcolumn, which can act as a hollow optical waveguide. Based on the antiresonant reflection in the optical waveguide, we established a theoretical model to address the field enhancement in the hollow ZnO microcolumn, which systematically clarifies the influence of the geometric structure of the microcolumn on the field enhancement. We report for the first time, the enhanced emission of the near ultraviolet light (working wavelength of 385 nm) along the axial direction of the ZnO microcolumn. The corresponding microsized light emitter has also been obtained. Experiments agree well with both theoretical predictions and computer simulations based on the finite-difference time-domain method with perfectly matched layer boundary conditions. These findings provide valuable information for the application of ZnO micro- and nanostructures in optoelectronic devices.

  2. Modeling Higher-Order Correlations within Cortical Microcolumns

    PubMed Central

    Köster, Urs; Sohl-Dickstein, Jascha; Gray, Charles M.; Olshausen, Bruno A.

    2014-01-01

    We statistically characterize the population spiking activity obtained from simultaneous recordings of neurons across all layers of a cortical microcolumn. Three types of models are compared: an Ising model which captures pairwise correlations between units, a Restricted Boltzmann Machine (RBM) which allows for modeling of higher-order correlations, and a semi-Restricted Boltzmann Machine which is a combination of Ising and RBM models. Model parameters were estimated in a fast and efficient manner using minimum probability flow, and log likelihoods were compared using annealed importance sampling. The higher-order models reveal localized activity patterns which reflect the laminar organization of neurons within a cortical column. The higher-order models also outperformed the Ising model in log-likelihood: On populations of 20 cells, the RBM had 10% higher log-likelihood (relative to an independent model) than a pairwise model, increasing to 45% gain in a larger network with 100 spatiotemporal elements, consisting of 10 neurons over 10 time steps. We further removed the need to model stimulus-induced correlations by incorporating a peri-stimulus time histogram term, in which case the higher order models continued to perform best. These results demonstrate the importance of higher-order interactions to describe the structure of correlated activity in cortical networks. Boltzmann Machines with hidden units provide a succinct and effective way to capture these dependencies without increasing the difficulty of model estimation and evaluation. PMID:24991969

  3. Modeling higher-order correlations within cortical microcolumns.

    PubMed

    Köster, Urs; Sohl-Dickstein, Jascha; Gray, Charles M; Olshausen, Bruno A

    2014-07-01

    We statistically characterize the population spiking activity obtained from simultaneous recordings of neurons across all layers of a cortical microcolumn. Three types of models are compared: an Ising model which captures pairwise correlations between units, a Restricted Boltzmann Machine (RBM) which allows for modeling of higher-order correlations, and a semi-Restricted Boltzmann Machine which is a combination of Ising and RBM models. Model parameters were estimated in a fast and efficient manner using minimum probability flow, and log likelihoods were compared using annealed importance sampling. The higher-order models reveal localized activity patterns which reflect the laminar organization of neurons within a cortical column. The higher-order models also outperformed the Ising model in log-likelihood: On populations of 20 cells, the RBM had 10% higher log-likelihood (relative to an independent model) than a pairwise model, increasing to 45% gain in a larger network with 100 spatiotemporal elements, consisting of 10 neurons over 10 time steps. We further removed the need to model stimulus-induced correlations by incorporating a peri-stimulus time histogram term, in which case the higher order models continued to perform best. These results demonstrate the importance of higher-order interactions to describe the structure of correlated activity in cortical networks. Boltzmann Machines with hidden units provide a succinct and effective way to capture these dependencies without increasing the difficulty of model estimation and evaluation.

  4. High pressure apparatus for magnetization measurements

    SciTech Connect

    Uwatoko, Y.; Hotta, T.; Mori, H.

    1997-10-01

    A hydrostatic high pressure micro cell for studying heavy-fermion materials in a commercial magnetometer is developed. Experiments of pressures up to 10 kbar and temperature range 2 K {le} T {le} 300 K have been carried out. The sensitivity of measurement of under high pressure is as same as ambient pressure one within experimental error.

  5. Method of producing a high pressure gas

    DOEpatents

    Bingham, Dennis N.; Klingler, Kerry M.; Zollinger, William T.

    2006-07-18

    A method of producing a high pressure gas is disclosed and which includes providing a container; supplying the container with a liquid such as water; increasing the pressure of the liquid within the container; supplying a reactant composition such as a chemical hydride to the liquid under pressure in the container and which chemically reacts with the liquid to produce a resulting high pressure gas such as hydrogen at a pressure of greater than about 100 pounds per square inch of pressure; and drawing the resulting high pressure gas from the container.

  6. Optical calibration of pressure sensors for high pressures and temperatures

    SciTech Connect

    Goncharov, A F; Gregoryanz, E; Zaug, J M; Crowhurst, J C

    2004-10-04

    We present the results of Raman scattering measurements of diamond ({sup 12}C) and of cubic boron nitride (cBN), and fluorescence measurements of ruby, Sm:YAG, and SrB{sub 4}O{sub 7}:Sm{sup 2+} in the diamond anvil cell (DAC) at high pressures and temperatures. These measurements were accompanied by synchrotron x-ray diffraction measurements on gold. We have extended the room-temperature calibration of Sm:YAG in a quasihydrostatic regime up to 100 GPa. The ruby scale is shown to systematically underestimate pressure at high pressures and temperatures compared with all other sensors. On this basis, we propose a new high-temperature ruby pressure scale that should be valid to at least 100 GPa and 850 K. Historically, the accurate determination of pressure at high temperature and ultrahigh pressure has been extremely difficult. In fact, the lack of a general pressure scale nullifies, to a significant extent, the great innovations that have been made in recent years in DAC experimental techniques [1]. Now, more than ever a scale is required whose accuracy is comparable with that of the experimental data. Since pressure in the DAC is dependent on temperature (due to thermal pressure and also to changes in the properties of the materials that constitute the DAC) such a scale requires quantitative, and separate measurements of pressure and temperature.

  7. High-pressure microhydraulic actuator

    DOEpatents

    Mosier, Bruce P [San Francisco, CA; Crocker, Robert W [Fremont, CA; Patel, Kamlesh D [Dublin, CA

    2008-06-10

    Electrokinetic ("EK") pumps convert electric to mechanical work when an electric field exerts a body force on ions in the Debye layer of a fluid in a packed bed, which then viscously drags the fluid. Porous silica and polymer monoliths (2.5-mm O.D., and 6-mm to 10-mm length) having a narrow pore size distribution have been developed that are capable of large pressure gradients (250-500 psi/mm) when large electric fields (1000-1500 V/cm) are applied. Flowrates up to 200 .mu.L/min and delivery pressures up to 1200 psi have been demonstrated. Forces up to 5 lb-force at 0.5 mm/s (12 mW) have been demonstrated with a battery-powered DC-DC converter. Hydraulic power of 17 mW (900 psi@ 180 uL/min) has been demonstrated with wall-powered high voltage supplies. The force and stroke delivered by an actuator utilizing an EK pump are shown to exceed the output of solenoids, stepper motors, and DC motors of similar size, despite the low thermodynamic efficiency.

  8. Electrical Transport Experiments at High Pressure

    SciTech Connect

    Weir, S

    2009-02-11

    High-pressure electrical measurements have a long history of use in the study of materials under ultra-high pressures. In recent years, electrical transport experiments have played a key role in the study of many interesting high pressure phenomena including pressure-induced superconductivity, insulator-to-metal transitions, and quantum critical behavior. High-pressure electrical transport experiments also play an important function in geophysics and the study of the Earth's interior. Besides electrical conductivity measurements, electrical transport experiments also encompass techniques for the study of the optoelectronic and thermoelectric properties of materials under high pressures. In addition, electrical transport techniques, i.e., the ability to extend electrically conductive wires from outside instrumentation into the high pressure sample chamber have been utilized to perform other types of experiments as well, such as high-pressure magnetic susceptibility and de Haas-van Alphen Fermi surface experiments. Finally, electrical transport techniques have also been utilized for delivering significant amounts of electrical power to high pressure samples, for the purpose of performing high-pressure and -temperature experiments. Thus, not only do high-pressure electrical transport experiments provide much interesting and valuable data on the physical properties of materials extreme compression, but the underlying high-pressure electrical transport techniques can be used in a number of ways to develop additional diagnostic techniques and to advance high pressure capabilities.

  9. High-pressure cryogenic seals for pressure vessels

    NASA Technical Reports Server (NTRS)

    Buggele, A. E.

    1977-01-01

    This investigation of the problems associated with reliably containing gaseous helium pressurized to 1530 bars (22 500 psi) between 4.2 K and 150 K led to the following conclusions: (1) common seal designs used in existing elevated-temperature pressure vessels are unsuitable for high-pressure cryogenic operation, (2) extrusion seal-ring materials such as Teflon, tin, and lead are not good seal materials for cryogenic high-pressure operation; and (3) several high-pressure cryogenic seal systems suitable for large-pressure vessel applications were developed; two seals required prepressurization, and one seal functioned repeatedly without any prepressurization. These designs used indium seal rings, brass or 304 stainless-steel anvil rings, and two O-rings of silicone rubber or Kel-F.

  10. High blood pressure and eye disease

    MedlinePlus

    ... this page: //medlineplus.gov/ency/article/000999.htm High blood pressure and eye disease To use the sharing features on this page, please enable JavaScript. High blood pressure can damage blood vessels in the retina . The ...

  11. Avoid the Consequences of High Blood Pressure

    MedlinePlus

    ... Aneurysm More Avoid the Consequences of High Blood Pressure Infographic Updated:Oct 31,2016 View a downloadable version of this infographic High Blood Pressure • Home • Get the Facts About HBP • Know Your ...

  12. Feedthrough Seal For High-Pressure Vessel

    NASA Technical Reports Server (NTRS)

    Williams, R.; Mullins, O.; Smith, D.; Teasley, G.

    1984-01-01

    Combination of ceramic and plastic withstands many depressurizations. Stack of washers surrounds leadthrough electrode. Under pressure washers expand to fill leadthrough hole in high-pressure vessel. Seal thus formed withstands 20 or more pressurization/depressurization cycles. Seal composed of neoprene, polytetrafluoroethylene, nylon and high-purity, high-density commercial alumina ceramic.

  13. Optimization of electrostatic lens systems for low-energy scanning microcolumn applications

    SciTech Connect

    Oh, Tae-Sik; Kim, Dae-Wook; Ahn, Seungjoon; Kim, Young Chul; Kim, Ho-Seob; Ahn, Seong Joon

    2008-11-15

    The optimization of a low-energy scanning microcolumn is proposed by adopting a modified Einzel lens sandwiched between an aligner and a deflector. The modified Einzel lens is composed of four electrodes, and the two center electrodes are specially designed quadrupole lenses having keyhole type rather than circular apertures. The outer electrodes of the Einzel lens having circular apertures are grounded, and the quadrupole lens is operated by applying the quadrupole voltages. The effects of the separated deflector system and the static quadrupole lens were investigated by analyzing the scanning electron beam spot at the target, and the results show that the proposed system can improve the performance of the scanning microcolumn.

  14. Development of an electric charge-tunable micro-column for capillary liquid chromatography.

    PubMed

    Takahashi, Kouji; Fukano, Mizue; Yoshida, Saori; Ogawa, Masahiro; Kusu, Fumiyo

    2012-01-01

    An electric charge-tunable micro-column (CTMC) was developed as a precolumn for reversed-phase capillary chromatography using conductive carbon fibers as the stationary phase. The carbon fibers, which constitute one electrode, are packed into a heat-shrinkable tube, which is attached to a stainless-steel column body. The mobile phase flows into CTMC through a stainless-steel tube that acts as a counter electrode. The retention times for hydrophobic and ionic compounds are controlled by the applied potential. The characteristics, such as the electrolysis efficiency and shift in retention factor, were evaluated. As a case study, estrogens in spiked beef were analyzed by capillary chromatography. With no applied potential, the resolution between the unknown peak and estriol and the recoveries of estriol were 0.81 and 65.5%, respectively. These values improved to 1.2 and 78.8%, respectively, upon applying +500 mV. These results indicate that a high-resolution capillary chromatography system can be achieved with CTMC.

  15. High-Pressure Lightweight Thrusters

    NASA Technical Reports Server (NTRS)

    Holmes, Richard; McKechnie, Timothy; Shchetkovskiy, Anatoliy; Smirnov, Alexander

    2013-01-01

    Returning samples of Martian soil and rock to Earth is of great interest to scientists. There were numerous studies to evaluate Mars Sample Return (MSR) mission architectures, technology needs, development plans, and requirements. The largest propulsion risk element of the MSR mission is the Mars Ascent Vehicle (MAV). Along with the baseline solid-propellant vehicle, liquid propellants have been considered. Similar requirements apply to other lander ascent engines and reaction control systems. The performance of current state-ofthe- art liquid propellant engines can be significantly improved by increasing both combustion temperature and pressure. Pump-fed propulsion is suggested for a single-stage bipropellant MAV. Achieving a 90-percent stage propellant fraction is thought to be possible on a 100-kg scale, including sufficient thrust for lifting off Mars. To increase the performance of storable bipropellant rocket engines, a high-pressure, lightweight combustion chamber was designed. Iridium liner electrodeposition was investigated on complex-shaped thrust chamber mandrels. Dense, uniform iridium liners were produced on chamber and cylindrical mandrels. Carbon/carbon composite (C/C) structures were braided over iridium-lined mandrels and densified by chemical vapor infiltration. Niobium deposition was evaluated for forming a metallic attachment flange on the carbon/ carbon structure. The new thrust chamber was designed to exceed state-of-the-art performance, and was manufactured with an 83-percent weight savings. High-performance C/Cs possess a unique set of properties that make them desirable materials for high-temperature structures used in rocket propulsion components, hypersonic vehicles, and aircraft brakes. In particular, more attention is focused on 3D braided C/Cs due to their mesh-work structure. Research on the properties of C/Cs has shown that the strength of composites is strongly affected by the fiber-matrix interfacial bonding, and that weakening

  16. Manufacturing Diamond Under Very High Pressure

    NASA Technical Reports Server (NTRS)

    Voronov, Oleg

    2007-01-01

    A process for manufacturing bulk diamond has been made practical by the invention of the High Pressure and Temperature Apparatus capable of applying the combination of very high temperature and high pressure needed to melt carbon in a sufficiently large volume. The apparatus includes a reaction cell wherein a controlled static pressure as high as 20 GPa and a controlled temperature as high as 5,000 C can be maintained.

  17. Risk Factors for High Blood Pressure

    MedlinePlus

    ... to achieve target blood pressure goals with treatment. Overweight You are more likely to develop prehypertension or high blood pressure if you’re overweight or obese . The terms “overweight” and “obese” refer ...

  18. High blood pressure in women.

    PubMed

    Calhoun, D A; Oparil, S

    1997-01-01

    There is a sexual dimorphism in blood pressure of humans and experimental animals: males tend to have higher blood pressure than females with functional ovaries, while ovariectomy or menopause tends to abolish the sexual dimorphism and cause females to develop a "male" pattern of blood pressure. Hypertensive male laboratory animals tend to have NaCl-sensitive blood pressure, while females are NaCl resistant unless their ovaries are removed, in which case NaCl sensitivity appears. The hormonal basis of NaCl sensitivity of blood pressure and of the sexual dimorphism of hypertension remains to be defined. Synthetic estrogens and progestins, as found in oral contraceptives, tend to elevate blood pressure, while naturally occurring estrogens lower it, or have no effect. Hypertension increases cardiovascular risk in women, as well as men, although the benefits of antihypertensive treatment have been more difficult to demonstrate in women. In the population of the United States, women are more aware of their hypertension, more likely to be treated medically, and more likely to have their blood pressure controlled.

  19. High pressure pulsed capillary viscometry

    NASA Technical Reports Server (NTRS)

    Smith, R. L.; Walowitt, J. A.; Pan, C. H. T.

    1972-01-01

    An analytical and test program was conducted in order to establish the feasibility of a multichamber pulsed-capillary viscometer. The initial design incorporated a piston, ram, and seals which produced measured pulses up to 30,000 psi in the closed chamber system. Pressure pulses from one to ten milliseconds were investigated in a system volume of 1 cuin. Four test fluids: a MIL-L-7808, a 5P4E polyphenyl ether, a MIL-L-23699A, and a synthetic hydrocarbon were examined in the test pressure assembly. The pressure-viscosity coefficient and viscosity delay time were determined for the MIL-L-7808 lubricant tested.

  20. Optical calibration of pressure sensors for high pressures and temperatures

    SciTech Connect

    Goncharov, Alexander F.; Zaug, Joseph M.; Crowhurst, Jonathan C.; Gregoryanz, Eugene

    2005-05-01

    We present the results of Raman-scattering measurements of diamond ({sup 12}C) and of cubic boron nitride, and fluorescence measurements of ruby, Sm:yttrium aluminum garnet (Sm:YAG), and SrB{sub 4}O{sub 7}:Sm{sup 2+} in the diamond anvil cell at high pressures and temperatures. These measurements were accompanied by synchrotron x-ray-diffraction measurements on gold. We have extended the room-temperature calibration of Sm:YAG in a quasihydrostatic regime up to 100 GPa. The ruby scale is found to systematically underestimate pressure at high pressures and temperatures compared with all the other sensors. On this basis, we propose an alternative high-temperature ruby pressure scale that is valid to at least 100 GPa and 850 K.

  1. High pressure synthesis gas conversion. Final report

    SciTech Connect

    Not Available

    1993-05-01

    The purpose of this research project is to build and test a high pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system were procured or fabricated and assembled in our laboratory. This system was then used to determine the effects of high pressure on growth and ethanol production by Clostridium ljungdahlii. The limits of cell concentration and mass transport relationships were found in CSTR and immobilized cell reactors (ICR). The minimum retention times and reactor volumes were found for ethanol production in these reactors. A maximum operating pressure of 150 psig has been shown to be possible for C. ljungdahlli with the medium of Phillips et al. This medium was developed for atmospheric pressure operation in the CSTR to yield maximum ethanol concentrations and thus is not best for operation at elevated pressures. It is recommended that a medium development study be performed for C. ljungdahlii at increased pressure. Cell concentration, gas conversion and product concentration profiles were presented for C. ljungdahlii as a function of gas flow rate, the variable which affects bacterium performance the most. This pressure was chosen as a representative pressure over the 0--150 psig operating pressure range for the bacterium. Increased pressure negatively affected ethanol productivity probably due to the fact that medium composition was designed for atmospheric pressure operation. Medium development at increased pressure is necessary for high pressure development of the system.

  2. High Precision Pressure Measurement with a Funnel

    ERIC Educational Resources Information Center

    Lopez-Arias, T.; Gratton, L. M.; Oss, S.

    2008-01-01

    A simple experimental device for high precision differential pressure measurements is presented. Its working mechanism recalls that of a hydraulic press, where pressure is supplied by insufflating air under a funnel. As an application, we measure air pressure inside a soap bubble. The soap bubble is inflated and connected to a funnel which is…

  3. High Precision Pressure Measurement with a Funnel

    ERIC Educational Resources Information Center

    Lopez-Arias, T.; Gratton, L. M.; Oss, S.

    2008-01-01

    A simple experimental device for high precision differential pressure measurements is presented. Its working mechanism recalls that of a hydraulic press, where pressure is supplied by insufflating air under a funnel. As an application, we measure air pressure inside a soap bubble. The soap bubble is inflated and connected to a funnel which is…

  4. Metallicity of boron carbides at high pressure

    NASA Astrophysics Data System (ADS)

    Dekura, Haruhiko; Shirai, Koun; Yanase, Akira

    2010-03-01

    Electronic structure of semiconducting boron carbide at high pressure has been theoretically investigated, because of interests in the positive pressure dependence of resistivity, in the gap closure, and in the phase transition. The most simplest form B12(CCC) is assumed. Under assumptions of hydrostatic pressure and neglecting finite-temperature effects, boron carbide is quite stable at high pressure. The crystal of boron carbide is stable at least until a pressure higher than previous experiments showed. The gap closure occurs only after p=600 GPa on the assumption of the original crystal symmetry. In the low pressure regime, the pressure dependence of the energy gap almost diminishes, which is an exceptional case for semiconductors, which could be one of reasons for the positive pressure dependence of resistivity. A monotonous increase in the apex angle of rhombohedron suggests that the covalent bond continues to increase. The C chain inserted in the main diagonal of rhombohedral structure is the chief reason of this stability.

  5. High-pressure fiber optic acoustic sensor

    NASA Astrophysics Data System (ADS)

    Huang, Zhengyu; Deng, Jiangdong; Peng, Wei; Pickrell, Gary R.; Wang, Anbo

    2004-12-01

    This paper describes a diaphragm-based external Fabry-Perot interferometric (EFPI) fiber acoustic sensor with pressure-isolation structure. The structure minimizes the crosstalk generated by environmental pressure while enables considerable amount of acoustic signal power being delivered to the sensor, which allows the sensor to work in high-pressure environment. The detailed analysis on sensor design, pressure isolation and sensor fabrication as well as sensor performance are presented.

  6. NETL- High-Pressure Combustion Research Facility

    SciTech Connect

    2013-07-08

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  7. NETL- High-Pressure Combustion Research Facility

    ScienceCinema

    None

    2016-07-12

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  8. CHRONOBIOLOGY OF HIGH BLOOD PRESSURE

    PubMed Central

    Cornélissen, G.; Halberg, F.; Bakken, E. E.; Wang, Z.; Tarquini, R.; Perfetto, F.; Laffi, G.; Maggioni, C.; Kumagai, Y.; Homolka, P.; Havelková, A.; Dušek, J.; Svačinová, H.; Siegelová, J.; Fišer, B.

    2008-01-01

    BIOCOS, the project aimed at studying BIOlogical systems in their COSmos, has obtained a great deal of expertise in the fields of blood pressure (BP) and heart rate (HR) monitoring and of marker rhythmometry for the purposes of screening, diagnosis, treatment, and prognosis. Prolonging the monitoring reduces the uncertainty in the estimation of circadian parameters; the current recommendation of BIOCOS requires monitoring for at least 7 days. The BIOCOS approach consists of a parametric and a non-parametric analysis of the data, in which the results from the individual subject are being compared with gender- and age-specified reference values in health. Chronobiological designs can offer important new information regarding the optimization of treatment by timing its administration as a function of circadian and other rhythms. New technological developments are needed to close the loop between the monitoring of blood pressure and the administration of antihypertensive drugs. PMID:19122770

  9. Multicomponent fuel vaporization at high pressures.

    SciTech Connect

    Torres, D. J.; O'Rourke, P. J.

    2002-01-01

    We extend our multicomponent fuel model to high pressures using a Peng-Robinson equation of state, and implement the model into KIVA-3V. Phase equilibrium is achieved by equating liquid and vapor fugacities. The latent heat of vaporization and fuel enthalpies are also corrected for at high pressures. Numerical simulations of multicomponent evaporation are performed for single droplets for a diesel fuel surrogate at different pressures.

  10. High frequency dynamic pressure calibration technique

    NASA Technical Reports Server (NTRS)

    Davis, P. A.; Zasimowich, R. F.

    1985-01-01

    A high frequency dynamic calibration technique for pressure transducers has been developed using a siren pressure generator (SPG). The SPG is an inlet-area-modulated device generating oscillating waveforms with dynamic pressure amplitudes up to 58.6 kPa (8.5 psi) in a frequency range of 1 to 10 kHz. A description of the generator, its operating characteristics and instrumentation used for pressure amplitude and frequency measurements is given. Waveform oscillographs and spectral analysis of the pressure transducers' output signals are presented.

  11. High frequency dynamic pressure calibration technique

    NASA Astrophysics Data System (ADS)

    Davis, P. A.; Zasimowich, R. F.

    A high frequency dynamic calibration technique for pressure transducers has been developed using a siren pressure generator (SPG). The SPG is an inlet-area-modulated device generating oscillating waveforms with dynamic pressure amplitudes up to 58.6 kPa (8.5 psi) in a frequency range of 1 to 10 kHz. A description of the generator, its operating characteristics and instrumentation used for pressure amplitude and frequency measurements is given. Waveform oscillographs and spectral analysis of the pressure transducers' output signals are presented.

  12. Fuel droplet burning rates at high pressures.

    NASA Technical Reports Server (NTRS)

    Canada, G. S.; Faeth, G. M.

    1973-01-01

    Combustion of methanol, ethanol, propanol-1, n-pentane, n-heptane, and n-decane was observed in air under natural convection conditions, at pressures up to 100 atm. The droplets were simulated by porous spheres, with diameters in the range from 0.63 to 1.90 cm. The pressure levels of the tests were high enough so that near-critical combustion was observed for methanol and ethanol. Due to the high pressures, the phase-equilibrium models of the analysis included both the conventional low-pressure approach as well as high-pressure versions, allowing for real gas effects and the solubility of combustion-product gases in the liquid phase. The burning-rate predictions of the various theories were similar, and in fair agreement with the data. The high-pressure theory gave the best prediction for the liquid-surface temperatures of ethanol and propanol-1 at high pressure. The experiments indicated the approach of critical burning conditions for methanol and ethanol at pressures on the order of 80 to 100 atm, which was in good agreement with the predictions of both the low- and high-pressure analysis.

  13. Elastomers Compatible With High-Pressure Oxygen

    NASA Technical Reports Server (NTRS)

    Martin, Jon W.

    1987-01-01

    Compatibility increased by fluorination. Report describes experiments aimed at improving compatibility of some fluorinated elastomers with high-pressure oxygen. Such elastomers needed for seals, gaskets, and positive-expulsion devices used with high-pressure oxygen. Oxygen - compatibility tests carried out on five elastomers chosen on the basis of literature survey.

  14. High Blood Pressure Often Undiagnosed, Untreated

    MedlinePlus

    ... Health, or the U.S. Department of Health and Human Services. More Health News on: Heart Attack High Blood Pressure Stroke Recent Health News Related MedlinePlus Health Topics Heart Attack High Blood Pressure Stroke ... Bethesda, MD 20894 U.S. Department of Health and Human Services National Institutes of Health Page last updated ...

  15. Laser techniques in high-pressure geophysics

    NASA Technical Reports Server (NTRS)

    Hemley, R. J.; Bell, P. M.; Mao, H. K.

    1987-01-01

    Laser techniques in conjunction with the diamond-anvil cell can be used to study high-pressure properties of materials important to a wide range of problems in earth and planetary science. Spontaneous Raman scattering of crystalline and amorphous solids at high pressure demonstrates that dramatic changes in structure and bonding occur on compression. High-pressure Brillouin scattering is sensitive to the pressure variations of single-crystal elastic moduli and acoustic velocities. Laser heating techniques with the diamond-anvil cell can be used to study phase transitions, including melting, under deep-earth conditions. Finally, laser-induced ruby fluorescence has been essential for the development of techniques for generating the maximum pressures now possible with the diamond-anvil cell, and currently provides a calibrated in situ measure of pressure well above 100 gigapascals.

  16. Laser techniques in high-pressure geophysics

    NASA Technical Reports Server (NTRS)

    Hemley, R. J.; Bell, P. M.; Mao, H. K.

    1987-01-01

    Laser techniques in conjunction with the diamond-anvil cell can be used to study high-pressure properties of materials important to a wide range of problems in earth and planetary science. Spontaneous Raman scattering of crystalline and amorphous solids at high pressure demonstrates that dramatic changes in structure and bonding occur on compression. High-pressure Brillouin scattering is sensitive to the pressure variations of single-crystal elastic moduli and acoustic velocities. Laser heating techniques with the diamond-anvil cell can be used to study phase transitions, including melting, under deep-earth conditions. Finally, laser-induced ruby fluorescence has been essential for the development of techniques for generating the maximum pressures now possible with the diamond-anvil cell, and currently provides a calibrated in situ measure of pressure well above 100 gigapascals.

  17. High-resolution, high-pressure NMR studies of proteins.

    PubMed Central

    Jonas, J; Ballard, L; Nash, D

    1998-01-01

    Advanced high-resolution NMR spectroscopy, including two-dimensional NMR techniques, combined with high pressure capability, represents a powerful new tool in the study of proteins. This contribution is organized in the following way. First, the specialized instrumentation needed for high-pressure NMR experiments is discussed, with specific emphasis on the design features and performance characteristics of a high-sensitivity, high-resolution, variable-temperature NMR probe operating at 500 MHz and at pressures of up to 500 MPa. An overview of several recent studies using 1D and 2D high-resolution, high-pressure NMR spectroscopy to investigate the pressure-induced reversible unfolding and pressure-assisted cold denaturation of lysozyme, ribonuclease A, and ubiquitin is presented. Specifically, the relationship between the residual secondary structure of pressure-assisted, cold-denatured states and the structure of early folding intermediates is discussed. PMID:9649405

  18. Abnormally high formation pressures, Potwar Plateau, Pakistan

    USGS Publications Warehouse

    Law, B.E.; Shah, S.H.A.; Malik, M.A.

    1998-01-01

    Abnormally high formation pressures in the Potwar Plateau of north-central Pakistan are major obstacles to oil and gas exploration. Severe drilling problems associated with high pressures have, in some cases, prevented adequate evaluation of reservoirs and significantly increased drilling costs. Previous investigations of abnormal pressure in the Potwar Plateau have only identified abnormal pressures in Neogene rocks. We have identified two distinct pressure regimes in this Himalayan foreland fold and thrust belt basin: one in Neogene rocks and another in pre-Neogene rocks. Pore pressures in Neogene rocks are as high as lithostatic and are interpreted to be due to tectonic compression and compaction disequilibrium associated with high rates of sedimentation. Pore pressure gradients in pre-Neogene rocks are generally less than those in Neogene rocks, commonly ranging from 0.5 to 0.7 psi/ft (11.3 to 15.8 kPa/m) and are most likely due to a combination of tectonic compression and hydrocarbon generation. The top of abnormally high pressure is highly variable and doesn't appear to be related to any specific lithologic seal. Consequently, attempts to predict the depth to the top of overpressure prior to drilling are precluded.

  19. High-pressure minerals in shocked meteorites

    NASA Astrophysics Data System (ADS)

    Tomioka, Naotaka; Miyahara, Masaaki

    2017-09-01

    Heavily shocked meteorites contain various types of high-pressure polymorphs of major minerals (olivine, pyroxene, feldspar, and quartz) and accessory minerals (chromite and Ca phosphate). These high-pressure minerals are micron to submicron sized and occur within and in the vicinity of shock-induced melt veins and melt pockets in chondrites and lunar, howardite-eucrite-diogenite (HED), and Martian meteorites. Their occurrence suggests two types of formation mechanisms (1) solid-state high-pressure transformation of the host-rock minerals into monomineralic polycrystalline aggregates, and (2) crystallization of chondritic or monomineralic melts under high pressure. Based on experimentally determined phase relations, their formation pressures are limited to the pressure range up to 25 GPa. Textural, crystallographic, and chemical characteristics of high-pressure minerals provide clues about the impact events of meteorite parent bodies, including their size and mutual collision velocities and about the mineralogy of deep planetary interiors. The aim of this article is to review and summarize the findings on natural high-pressure minerals in shocked meteorites that have been reported over the past 50 years.

  20. Combustion of liquid sprays at high pressures

    NASA Technical Reports Server (NTRS)

    Shearer, A. J.; Faeth, G. M.

    1977-01-01

    The combustion of pressure atomized fuel sprays in high pressure stagnant air was studied. Measurements were made of flame and spray boundaries at pressures in the range 0.1-9 MPa for methanol and n-pentane. At the higher test pressure levels, critical phenomena are important. The experiments are compared with theoretical predictions based on a locally homogeneous two-phase flow model. The theory correctly predicted the trends of the data, but underestimates flame and spray boundaries by 30-50 percent, indicating that slip is still important for the present experiments (Sauter mean diameters of 30 microns at atmospheric pressure under cold flow conditions). Since the sprays are shorter at high pressures, slip effects are still important even though the density ratio of the phases approach one another as the droplets heat up. The model indicates the presence of a region where condensed water is present within the spray and provides a convenient means of treating supercritical phenomena.

  1. Portable high precision pressure transducer system

    NASA Astrophysics Data System (ADS)

    Piper, T. C.; Morgan, J. P.; Marchant, N. J.; Bolton, S. M.

    A high precision pressure transducer system for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank is presented. Since the response of the pressure transducer is temperature sensitive, it is continually housed in a battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on-board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum fluorescent display.

  2. Portable high precision pressure transducer system

    DOEpatents

    Piper, Thomas C.; Morgan, John P.; Marchant, Norman J.; Bolton, Steven M.

    1994-01-01

    A high precision pressure transducer system for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank. Since the response of the pressure transducer is temperature sensitive, it is continually housed in an battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum florescent display.

  3. Portable high precision pressure transducer system

    DOEpatents

    Piper, T.C.; Morgan, J.P.; Marchant, N.J.; Bolton, S.M.

    1994-04-26

    A high precision pressure transducer system is described for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank. Since the response of the pressure transducer is temperature sensitive, it is continually housed in an battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum fluorescent display. 2 figures.

  4. High-pressure mechanical instability in rocks

    USGS Publications Warehouse

    Byerlee, J.D.; Brace, W.F.

    1969-01-01

    At a confining pressure of a few kilobars, deformation of many sedimentary rocks, altered mafic rocks, porous volcanic rocks, and sand is ductile, in that instabilities leading to audible elastic shocks are absent. At pressures of 7 to 10 kilobars, however, unstable faulting and stick-slip in certain of these rocks was observed. This high pressure-low temperature instability might be responsible for earthquakes in deeply buried sedimentary or volcanic sequences.

  5. High-pressure cryogenic seals for pressure vessels

    NASA Technical Reports Server (NTRS)

    Buggle, A. E.

    1977-01-01

    Problems associated with maintaining high pressures at cryogenic temperatures in pressure vessels are investigated. The goals were to identify the appropriate materials and design for a seal intended for cryogenic applications at pressures up to 4,080 bars (60,000 psi), and to examine the factors affecting the seal performance. The method employed and the apparatus used in a series of experimental seal system tests, and the test results are described in detail. It is concluded that the common seal designs and extrusion seal-ring materials such as Teflon, tin, and lead are not suitable. However, new seal systems developed using indium seal rings, brass or 304 stainless steel anvil rings, and two 0-rings of silicone rubber or Kel-F did prove suitable.

  6. Carbon in iron phases under high pressure

    NASA Astrophysics Data System (ADS)

    Huang, L.; Skorodumova, N. V.; Belonoshko, A. B.; Johansson, B.; Ahuja, R.

    2005-11-01

    The influence of carbon impurities on the properties of iron phases (bcc, hcp, dhcp, fcc) has been studied using the first-principles projector augmented-wave (PAW) method for a wide pressure range. It is shown that the presence of ~6 at. % of interstitial carbon has a little effect on the calculated structural sequence of the iron phases under high pressure. The bcc -> hcp transition both for pure iron and iron containing carbon takes place around 9 GPa. According to the enthalpies comparison, the solubility of carbon into the iron solid is decreased by high pressure. The coexistence of iron carbide (Fe3C) + pure hcp Fe is most stable phase at high pressure compared with other phases. Based on the analysis of the pressure-density dependences for Fe3C and hcp Fe, we suggest that there might be some fraction of iron carbide present in the core.

  7. High Pressure Solution Kinetics of Metal Complexes.

    ERIC Educational Resources Information Center

    Suvachittanont, Surapong

    1983-01-01

    Describes use of activation volumes derived from the effect of pressure reaction rates in aiding the understanding of reaction mechanism. Topics discussed include determination and interpretation of activation volumes, high pressure equipment/techniques, and application of activation volumes in mechanistic elucidation of several inorganic…

  8. High Pressure Solution Kinetics of Metal Complexes.

    ERIC Educational Resources Information Center

    Suvachittanont, Surapong

    1983-01-01

    Describes use of activation volumes derived from the effect of pressure reaction rates in aiding the understanding of reaction mechanism. Topics discussed include determination and interpretation of activation volumes, high pressure equipment/techniques, and application of activation volumes in mechanistic elucidation of several inorganic…

  9. How Is High Blood Pressure Treated?

    MedlinePlus

    ... secondary high blood pressure, he or she will work to treat the other condition or change the medicine suspected of causing your ... when the medications they are taking do not work well for them or another medical condition is leading to uncontrolled blood pressure. Health care ...

  10. High gas pressure effects on yeast.

    PubMed

    Espinasse, V; Perrier-Cornet, J-M; Marecat, A; Gervais, P

    2008-11-01

    Dried microorganisms are particularly resistant to high hydrostatic pressure effects. However, exposure to high pressures of nitrogen proved to be effective in inactivating dried yeasts. In this study, we tried to elucidate this mechanism on Saccharomyces cerevisiae. High-pressure treatments were performed using different inert gases at 150 MPa and 25 degrees C with holding time values up to 12 months. The influence of cell hydration was also investigated. For fully hydrated cells, pressurized gases had little specific effect: cell inactivation was mainly due to compression effects. However, dried cells were sensitive to high pressure of gases. In this latter case, two inactivation kinetics were observed. For holding time up to 1 h, the inactivation rate increased to 4 log and was linked to a loss of membrane integrity and the presence of damage on the cell wall. In such case cell inactivation would be due to gas sorption and desorption phenomena which would rupture dried cells during a fast pressure release. Gas sorption would occur in cell lipid phases. For longer holding times, the inactivation rate increased more slightly due to compression effects and/or to a slower gas sorption. Water therefore played a key role in cell sensitivity to fast gas pressure release. Two hypotheses were proposed to explain this phenomenon: the rigidity of vitrified dried cells and the presence of glassy solid phases which would favor intracellular gas expansion. Our results showed that dried microorganisms can be ruptured and inactivated by a fast pressure release with gases.

  11. Small, high-pressure liquid hydrogen turbopump

    NASA Technical Reports Server (NTRS)

    Csomor, A.; Sutton, R.

    1977-01-01

    A high pressure, liquid hydrogen turbopump was designed, fabricated, and tested to a maximum speed of 9739 rad/s and a maximum pump discharge pressure of 2861 N/sq. cm. The approaches used in the analysis and design of the turbopump are described, and fabrication methods are discussed. Data obtained from gas generator tests, turbine performance calibration, and turbopump testing are presented.

  12. Microcolumn Formation due to Induced-Charge Electroosmosis in a Floating Mode

    NASA Astrophysics Data System (ADS)

    Sugioka, Hideyuki; Dan, Hironobu; Hanazawa, Yuya

    2017-10-01

    Self-organization of particles is important since it may provide new functional materials. Previously, by using two-dimensional multiphysics simulations, we theoretically showed microcolumn formation due to induced-charge electroosmosis (ICEO). In this study, we experimentally demonstrate that gold leaves on a water surface move slowly and dynamically form a microcolumn due to a hydrodynamic interaction under an ac electric field. Further, by numerically analyzing video data, we show the time evolutions of the maximum cluster length and the maximum cluster area. In addition, by cluster analysis, we show the dependences of the average velocity on the applied voltage and frequency to clarify the phenomena. We believe that our findings make a new stage in the development of new functional materials on a water surface.

  13. High pressure study of acetophenone azine

    NASA Astrophysics Data System (ADS)

    Tang, X. D.; Ding, Z. J.; Zhang, Z. M.

    2009-02-01

    High pressure Raman spectra of acetophenone azine (APA) have been measured up to 17.7 GPa with a diamond anvil cell. Two crystalline-to-crystalline phase transformations are found at pressures about 3.6 and 5.8 GPa. A disappearance of external modes and the C-H vibration at pressures higher than 8.7 GPa suggests that the sample undergoes a phase transition to amorphous or orientationally disordered (plastic) state, and the amorphization was completed at about 12.1 GPa. The disordered state is unstable and, then, a polymerization transformation reaction occurs with a further pressure increase. After the pressure has been released, the polymerization state can remain at the ambient condition, indicating that the virgin crystalline state is not recovered. The results show that the phenomenon underlying the pressure induced phase transition of APA may involve profound changes in the coordination environments of the symmetric aromatic azine.

  14. Raman Study of SWNT Under High Pressure

    NASA Astrophysics Data System (ADS)

    Venkateswaran, U.; Rao, A. M.; Richter, E.; Eklund, P. C.; Smalley, R. E.

    1998-03-01

    A gasketed Merrill-Bassett-type diamond anvil cell was used for high pressure Raman measurements at room temperature. A 4:1 methanol-ethanol mixture served as the pressure transmitting medium. The radial mode (denoted as R, occuring at 186 cm-1 at 1 bar) and tangential modes (designated T_1, T_2, and T_3, located, respectively, at 1550, 1567, and 1593 cm-1 at 1 bar) were recorded for several representative pressures. With increasing pressure, both the R and T modes shift to higher frequencies with gradual weakening of intensity and broadening of linewidth. The radial mode disappears around ~ 2 GPa whereas the tangential modes, albeit weak in intensity, persist until 5.2 GPa. The decrease in Raman intensity under pressure can be attributed to a loss of resonance, since the strong Raman signals observed at ambient pressure have been interpreted as due a resonance with the electronic bands [1]. The R and T mode frequencies are fit to quadratic function of pressure i.e., ω=ω(0)+aP+bP^2 where `a' represents the linear pressure shift of the mode frequency which is proportional to the mode Gruneisen parameter. The linear pressure coefficient for the R mode is found to be nearly twice that of the high frequency T mode. A. M. Rao et al., Science 275, 187, 1997

  15. Magnetic and Superconducting Materials at High Pressures

    SciTech Connect

    Struzhkin, Viktor V.

    2015-03-24

    The work concentrates on few important tasks in enabling techniques for search of superconducting compressed hydrogen compounds and pure hydrogen, investigation of mechanisms of high-Tc superconductivity, and exploring new superconducting materials. Along that route we performed several challenging tasks, including discovery of new forms of polyhydrides of alkali metal Na at very high pressures. These experiments help us to establish the experimental environment that will provide important information on the high-pressure properties of hydrogen-rich compounds. Our recent progress in RIXS measurements opens a whole field of strongly correlated 3d materials. We have developed a systematic approach to measure major electronic parameters, like Hubbard energy U, and charge transfer energy Δ, as function of pressure. This technique will enable also RIXS studies of magnetic excitations in iridates and other 5d materials at the L edge, which attract a lot of interest recently. We have developed new magnetic sensing technique based on optically detected magnetic resonance from NV centers in diamond. The technique can be applied to study superconductivity in high-TC materials, to search for magnetic transitions in strongly correlated and itinerant magnetic materials under pressure. Summary of Project Activities; development of high-pressure experimentation platform for exploration of new potential superconductors, metal polyhydrides (including newly discovered alkali metal polyhydrides), and already known superconductors at the limit of static high-pressure techniques; investigation of special classes of superconducting compounds (high-Tc superconductors, new superconducting materials), that may provide new fundamental knowledge and may prove important for application as high-temperature/high-critical parameter superconductors; investigation of the pressure dependence of superconductivity and magnetic/phase transformations in 3d transition metal compounds, including

  16. Raman spectroscopy of triolein under high pressures

    NASA Astrophysics Data System (ADS)

    Tefelski, D. B.; Jastrzębski, C.; Wierzbicki, M.; Siegoczyński, R. M.; Rostocki, A. J.; Wieja, K.; Kościesza, R.

    2010-03-01

    This article presents results of the high pressure Raman spectroscopy of triolein. Triolein, a triacylglyceride (TAG) of oleic acid, is an unsaturated fat, present in natural oils such as olive oil. As a basic food component and an energy storage molecule, it has considerable importance for food and fuel industries. To generate pressure in the experiment, we used a high-pressure cylindrical chamber with sapphire windows, presented in (R.M. Siegoczyński, R. Kościesza, D.B. Tefelski, and A. Kos, Molecular collapse - modification of the liquid structure induced by pressure in oleic acid, High Press. Res. 29 (2009), pp. 61-66). Pressure up to 750 MPa was applied. A Raman spectrometer in "macro"-configuration was employed. Raman spectroscopy provides information on changes of vibrational modes related to structural changes of triolein under pressure. Interesting changes in the triglyceride C‒H stretching region at 2650-3100 cm-1 were observed under high-pressures. Changes were also observed in the ester carbonyl (C˭ O) stretching region 1700-1780 cm-1 and the C‒C stretching region at 1050-1150 cm-1. The overall luminescence of the sample decreased under pressure, making it possible to set longer spectrum acquisition time and obtain more details of the spectrum. The registered changes suggest that the high-pressure solid phase of triolein is organized as β-polymorphic, as was reported in (C. Akita, T. Kawaguchi, and F. Kaneko, Structural study on polymorphism of cis-unsaturated triacylglycerol: Triolein, J. Phys. Chem. B 110 (2006), pp. 4346-4353; E. Da Silva and D. Rousseau, Molecular order and thermodynamics of the solid-liquid transition in triglycerides via Raman spectroscopy, Phys. Chem. Chem. Phys. 10 (2008), pp. 4606-4613) (with temperature-induced phase transitions). The research has shown that Raman spectroscopy in TAGs under pressure reveals useful information about its structural changes.

  17. Nanophotonic production, modulation and switching of ions by silicon microcolumn arrays

    DOEpatents

    Vertes, Akos; Walker, Bennett N.

    2013-09-10

    The production and use of silicon microcolumn arrays that harvest light from a laser pulse to produce ions are described. The systems of the present invention seem to behave like a quasi-periodic antenna array with ion yields that show profound dependence on the plane of laser light polarization and the angle of incidence. By providing photonic ion sources, this enables enhanced control of ion production on a micro/nano scale and direct integration with miniaturized analytical devices.

  18. Nanophotonic production, modulation and switching of ions by silicon microcolumn arrays

    DOEpatents

    Vertes, Akos [Reston, VA; Walker, Bennett N [Washington, DC

    2012-02-07

    The production and use of silicon microcolumn arrays that harvest light from a laser pulse to produce ions are described. The systems of the present invention seem to behave like a quasi-periodic antenna array with ion yields that show profound dependence on the plane of laser light polarization and the angle of incidence. By providing photonic ion sources, this enables enhanced control of ion production on a micro/nano scale and direct integration with miniaturized analytical devices.

  19. Nanophotonic production, modulation and switching of ions by silicon microcolumn arrays

    DOEpatents

    Vertes, Akos; Walker, Bennett N

    2015-04-07

    The production and use of silicon microcolumn arrays that harvest light from a laser pulse to produce ions are described. The systems of the present invention seem to behave like a quasi-periodic antenna array with ion yields that show profound dependence on the plane of laser light polarization and the angle of incidence. By providing photonic ion sources, this enables enhanced control of ion production on a micro/nano scale and direct integration with miniaturized analytical devices.

  20. Preeclampsia and High Blood Pressure During Pregnancy

    MedlinePlus

    ... thrombophilia , or lupus • are obese •had in vitro fertilization What are the risks for my baby if ... blood cells. Hypertension: High blood pressure. In Vitro Fertilization: A procedure in which an egg is removed ...

  1. Design of high pressure waterjet nozzles

    NASA Technical Reports Server (NTRS)

    Mazzoleni, Andre P.

    1994-01-01

    The Hydroblast Research Cell at Marshall Space Flight Center is used to investigate the use of high pressure waterjets to strip paint, grease, adhesive and thermal spray coatings from various substrates. Current methods of cleaning often use ozone depleting chemicals (ODC) such as chlorinated solvents. High pressure waterjet cleaning has proven to be a viable alternative to the use of solvents. A popular method of waterjet cleaning involves the use of a rotating, multijet, high pressure water nozzle which is robotically controlled. This method enables rapid cleaning of a large area, but problems such as incomplete coverage and damage to the substrate from the waterjet have been observed. This report summarizes research consisting of identifying and investigating the basic properties of rotating, multijet, high pressure water nozzles, and how particular designs and modes of operation affect such things as stripping rate, standoff distance and completeness of coverage. The study involved computer simulations, an extensive literature review, and experimental studies of different nozzle designs.

  2. Preeclampsia and High Blood Pressure During Pregnancy

    MedlinePlus

    ... mellitus , thrombophilia , or lupus • are obese •had in vitro fertilization What are the risks for my baby if ... red blood cells. Hypertension: High blood pressure. In Vitro Fertilization: A procedure in which an egg is removed ...

  3. High Pressure Waterjet Cutting Industrial Needs Survey

    DTIC Science & Technology

    1989-08-25

    Report No. LO High Pressure Waterjet Cutting Industrial Needs Survey N Contract Number N00140-88-C-RC21 I John Klavuhn and Bruce Baker Metalworking...NO. NO ACCESSION NO. Washington, DC 20360-5100 1I TITLE (Include Security Classification) High Pressure Waterjet Cutting Industrial Needs Survey 12...block number) FIELD GROUP SUB-GROUP FIELD__ GROUP____UB-GROUP Waterjet cutting , abrasive waterjet cutting ’. ABSTRACT (Continue on reverse if

  4. Ultra High Pressure (UHP) Technology (BRIEFING SLIDES)

    DTIC Science & Technology

    2008-08-25

    AFRL-RX-TY-TP-2008-4600 POSTPRINT ULTRA HIGH PRESSURE ( UHP ) TECHNOLOGY (BRIEFING SLIDES) Patrick D. Sullivan Air Force Research...Since the discovery of the unprecedented effectiveness of 1500 psi Ultra High Pressure ( UHP ) technology in September of 2002 , AFRL scientists and... engineers have sought to increase Aircraft Rescue Fire Fighting (ARFF) performance by moving to higher flow rates to obtain greater throw distance and

  5. High pressure ceramic heat exchanger

    DOEpatents

    Harkins, B.D.; Ward, M.E.

    1998-09-22

    Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a strengthening reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the strengthening reinforcing member. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures. 5 figs.

  6. High pressure ceramic heat exchanger

    DOEpatents

    Harkins, Bruce D.; Ward, Michael E.

    1998-01-01

    Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a strengthening reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the strengthening reinforcing member. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

  7. High pressure ceramic heat exchanger

    DOEpatents

    Harkins, Bruce D.; Ward, Michael E.

    1999-01-01

    Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the reinforcing member and having a strengthening member wrapped around the refractory material. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

  8. Elasticity of orthoenstatite at high-pressure

    NASA Astrophysics Data System (ADS)

    Zhang, D.; Jackson, J. M.; Chen, B.; Zhao, J.; Yan, J.

    2011-12-01

    Orthoenstatite is an abundant yet complex mineral in Earth's upper mantle. Despite its abundance, the properties of orthopyroxene at high pressure remain ambiguous (e.g., Zhang et al. 2011; Jahn 2008; Kung et al. 2004). We explored select properties of a synthetic powdered orthoenstatite (Mg0.8757Fe0.13)2Si2O6 sample by X-ray diffraction (XRD) and nuclear resonance inelastic X-ray scattering (NRIXS) as a function of pressure in a neon pressure medium at 300 K. The XRD measurements were carried out at beamline 12.2.2 of the Advanced Light Source (Berkeley, CA), and the sample was studied up to 34 GPa. NRIXS measurements were carried out at sector 3ID-B of the Advanced Photon Source (Chicago, IL) in the pressure range of 3 to 17 GPa. From the raw NRIXS data, the partial phonon density of states (DOS) was derived (e.g., Sturhahn 2004). The volume (or pressure) dependence of several properties, such as the Lamb-Mössbauer factor, mean force constant, specific heat, vibrational entropy, and vibrational kinetic energy were determined from the DOS. We will discuss our results from these combined studies and the implications for Earth's upper mantle. References Zhang, D., J.M. Jackson, W. Sturhahn, and Y. Xiao (2011): Local structure variations observed in orthoenstatite at high-pressures. American Mineralogist, in press. Jahn, S. (2008) High-pressure phase transitions in MgSiO3 orthoenstatite studied by atomistic computer simulation. American Mineralogist, 93(4), 528-532. Kung, J., Li, B., Uchida, T., Wang, Y., Neuville, D., and Liebermann, R. (2004) In situ measurements of sound velocities and densities across the orthopyroxene high-pressure clinopyroxene transition in MgSiO3 at high pressure. Physics of the Earth and Planetary Interiors, 147(1), 27-44. Sturhahn, W. (2004): Nuclear Resonant Spectroscopy. J. Phys. Condens. Matter, 16, S497-S530.

  9. High pressure optical combustion probe

    SciTech Connect

    Woodruff, S.D.; Richards, G.A.

    1995-06-01

    The Department of Energy`s Morgantown Energy Technology Center has developed a combustion probe for monitoring flame presence and heat release. The technology involved is a compact optical detector of the OH radical`s UV fluorescence. The OH Monitor/Probe is designed to determine the flame presence and provide a qualitative signal proportional to the flame intensity. The probe can be adjusted to monitor a specific volume in the combustion zone to track spatial fluctuations in the flame. The probe is capable of nanosecond time response and is usually slowed electronically to fit the flame characteristics. The probe is a sapphire rod in a stainless steel tube which may be inserted into the combustion chamber and pointed at the flame zone. The end of the sapphire rod is retracted into the SS tube to define a narrow optical collection cone. The collection cone may be adjusted to fit the experiment. The fluorescence signal is collected by the sapphire rod and transmitted through a UV transmitting, fused silica, fiber optic to the detector assembly. The detector is a side window photomultiplier (PMT) with a 310 run line filter. A Hamamatsu photomultiplier base combined with a integral high voltage power supply permits this to be a low voltage device. Electronic connections include: a power lead from a modular DC power supply for 15 VDC; a control lead for 0-1 volts to control the high voltage level (and therefore gain); and a lead out for the actual signal. All low voltage connections make this a safe and easy to use device while still delivering the sensitivity required.

  10. Determination of 1-hydroxypyrene in human urine by acid hydrolysis coupled to solid-phase microextraction and semi-microcolumn liquid chromatography.

    PubMed

    Chen, Hong-Wen

    2007-10-01

    This study developed an acid hydrolysis coupled to a solid-phase microextraction method employing a semi-microcolumn liquid chromatography system, instead of enzyme hydrolysis with solid-phase extraction for the pretreatment of human urine samples, to detect urinary 1-hydroxypyrene (1-OHP). The complete separation and detection of urinary 1-hydroxyprene was performed using a high-performance liquid-chromatography fluorescence detection system with an analytical C(18) semi-microcolumn, 60% (v/v) aqueous acetonitrile elution, and a lambda(ex/em) = 348/388 nm pair detection wavelength. Calibration graphs were linear with very good correlation coefficients (r = 0.9997), and the detection limit was 1.0 ng/L. These important parameters for acid hydrolysis and solid-phase microextraction were investigated. The total recovery was above 83% in acid hydrolysis with solid-phase microextraction. The proposed method provided a relatively simple, convenient, and practical procedure to determine the level of urinary 1-hydroxypyrene in biological samples, and was successfully applied to detect the urine of students.

  11. In-Line Desalting of Proteins from Buffer and Synthetic Urine Solution Prior to ESI-MS Analysis via a Capillary-Channeled Polymer Fiber Microcolumn

    NASA Astrophysics Data System (ADS)

    Burdette, Carolyn Q.; Marcus, R. Kenneth

    2013-06-01

    Presented here is a novel in-line solid phase extraction (SPE) method utilizing a capillary-channeled polymer (C-CP) fiber microcolumn prior to introduction to an electrospray ionization (ESI) source. The high permeability of the microcolumn allows for operation under syringe pump or HPLC driven flow, ultimately providing greater mass spectral clarity and accurate molecular weight determinations for different protein/buffer combinations. Studies presented here focus on the desalting of several target proteins from a standard phosphate buffered saline (PBS) matrix and a synthetic urine solution prior to ESI-MS determinations. In every case, responses for μM-level proteins in PBS improve from the situation of not permitting molecular weight determinations to values that are precise to better than ±10 Da, without internal standards, with relative improvements in the signal-to-background ratios (S/B) on the order of 3,000×. De-salting of a myoglobin-spiked (12 μM) synthetic urine results in equally-improved spectral quality.

  12. Structural behaviour of YGa under high pressure

    SciTech Connect

    Sekar, M. Shekar, N. V. Chandra Sahu, P. Ch.; Babu, R.

    2014-04-24

    High pressure X-ray diffraction studies on rare-earth gallide YGa was carried up to a pressure of ∼ 33 GPa using rotating anode x-ray source in an angle dispersive mode. YGa exhibits CrB (B33) type orthorhombic structure (space group Cmcm) at ambient pressure. It undergoes a reversible structural phase transition from orthorhombic to tetragonal structure at ∼ 8.8 GPa. Both the phases coexist up to the highest pressure studied. The zero pressure bulk modulus and its derivative for parent phase have been estimated to be B{sub o} = 60 ± 3 GPa, B{sub o}' = 4.6 ± 1.5.

  13. Pressure sensor for high-temperature liquids

    DOEpatents

    Forster, George A.

    1978-01-01

    A pressure sensor for use in measuring pressures in liquid at high temperatures, especially such as liquid sodium or liquid potassium, comprises a soft diaphragm in contact with the liquid. The soft diaphragm is coupled mechanically to a stiff diaphragm. Pressure is measured by measuring the displacment of both diaphragms, typically by measuring the capacitance between the stiff diaphragm and a fixed plate when the stiff diaphragm is deflected in response to the measured pressure through mechanical coupling from the soft diaphragm. Absolute calibration is achieved by admitting gas under pressure to the region between diaphragms and to the region between the stiff diaphragm and the fixed plate, breaking the coupling between the soft and stiff diaphragms. The apparatus can be calibrated rapidly and absolutely.

  14. Fluid hydrogen at high density - Pressure ionization

    NASA Technical Reports Server (NTRS)

    Saumon, Didier; Chabrier, Gilles

    1992-01-01

    The Helmholtz-free-energy model for nonideal mixtures of hydrogen atoms and molecules by Saumon and Chabrier (1991) is extended to describe dissociation and ionization in similar mixtures in chemical equilibrium. A free-energy model is given that describes partial ionization in the pressure and temperature ionization region. The plasma-phase transition predicted by the model is described for hydrogen mixtures including such components as H2, H, H(+), and e(-). The plasma-phase transition has a critical point at Tc = 15,300 K and Pc = 0.614 Mbar, and thermodynamic instability is noted in the pressure-ionization regime. The pressure dissociation and ionization of fluid hydrogen are described well with the model yielding information on the nature of the plasma-phase transition. The model is shown to be valuable for studying dissociation and ionization in astrophysical objects and in high-pressure studies where pressure and temperature effects are significant.

  15. Sample injector for high pressure liquid chromatography

    DOEpatents

    Paul, Phillip H.; Arnold, Don W.; Neyer, David W.

    2001-01-01

    Apparatus and method for driving a sample, having a well-defined volume, under pressure into a chromatography column. A conventional high pressure sampling valve is replaced by a sample injector composed of a pair of injector components connected in series to a common junction. The injector components are containers of porous dielectric material constructed so as to provide for electroosmotic flow of a sample into the junction. At an appropriate time, a pressure pulse from a high pressure source, that can be an electrokinetic pump, connected to the common junction, drives a portion of the sample, whose size is determined by the dead volume of the common junction, into the chromatographic column for subsequent separation and analysis. The apparatus can be fabricated on a substrate for microanalytical applications.

  16. High pressure studies of potassium perchlorate

    DOE PAGES

    Pravica, Michael; Wang, Yonggang; Sneed, Daniel; ...

    2016-07-29

    Two experiments are reported on KClO4 at extreme conditions. A static high pressure Raman study was first conducted to 18.9 GPa. Evidence for at least two new phases was observed: one between 2.4 and 7.7 GPa (possibly sluggish), and the second near 11.7 GPa. Then, the X-ray induced decomposition rate of potassium perchlorate (KClO4 hv→ KCl + 2O2) was studied up to 15.2 GPa. The time-dependent growth of KCl and O2 was monitored. The decomposition rate slowed at higher pressures. As a result, we present the first direct evidence for O2 crystallization at higher pressures, demonstrating that O2 molecules aggregatemore » at high pressure.« less

  17. High pressure studies of potassium perchlorate

    SciTech Connect

    Pravica, Michael; Wang, Yonggang; Sneed, Daniel; Reiser, Sharissa; White, Melanie

    2016-07-29

    Two experiments are reported on KClO4 at extreme conditions. A static high pressure Raman study was first conducted to 18.9 GPa. Evidence for at least two new phases was observed: one between 2.4 and 7.7 GPa (possibly sluggish), and the second near 11.7 GPa. Then, the X-ray induced decomposition rate of potassium perchlorate (KClO4 hv→ KCl + 2O2) was studied up to 15.2 GPa. The time-dependent growth of KCl and O2 was monitored. The decomposition rate slowed at higher pressures. As a result, we present the first direct evidence for O2 crystallization at higher pressures, demonstrating that O2 molecules aggregate at high pressure.

  18. Polymerization of formic acid under high pressure

    SciTech Connect

    Goncharov, A.F.; Manaa, M.R.; Zaug, J.M.; Gee, R.H.; Fried, L.E.; Montgomery, W.B.

    2010-07-19

    We report Raman, infrared, and x-ray diffraction (XRD) measurements, along with ab initio calculations on formic acid (FA) under pressure up to 50 GPa. We find an infinite chain Pna2{sub 1} structure to be a high-pressure phase at room temperature. Our data indicate the symmetrization and a partially covalent character of the intrachain hydrogen bonds above approximately 20 GPa. Raman spectra and XRD patterns indicate a loss of long-range order at pressures above 40 GPa, with a large hysteresis upon decompression. We attribute this behavior to a three-dimensional polymerization of FA.

  19. Efficient High-Pressure State Equations

    NASA Technical Reports Server (NTRS)

    Harstad, Kenneth G.; Miller, Richard S.; Bellan, Josette

    1997-01-01

    A method is presented for a relatively accurate, noniterative, computationally efficient calculation of high-pressure fluid-mixture equations of state, especially targeted to gas turbines and rocket engines. Pressures above I bar and temperatures above 100 K are addressed The method is based on curve fitting an effective reference state relative to departure functions formed using the Peng-Robinson cubic state equation Fit parameters for H2, O2, N2, propane, methane, n-heptane, and methanol are given.

  20. High pressure oxygen utilization by NASA

    NASA Technical Reports Server (NTRS)

    Belles, F. E.

    1973-01-01

    Although NASA is not one of the country's major oxygen consumers, it uses oxygen under severe conditions including very high flow rates and pressure. Materials for such applications must be carefully selected for compatibility, because susceptibility to ignition increases as operating pressure is raised. Much work is needed, however to define the selection criteria. Some of the work in this area that is being performed under sponsorship of NASA's Aerospace Safety Research and Data Institute (ASRDI) is described.

  1. Efficient High-Pressure State Equations

    NASA Technical Reports Server (NTRS)

    Harstad, Kenneth G.; Miller, Richard S.; Bellan, Josette

    1997-01-01

    A method is presented for a relatively accurate, noniterative, computationally efficient calculation of high-pressure fluid-mixture equations of state, especially targeted to gas turbines and rocket engines. Pressures above I bar and temperatures above 100 K are addressed The method is based on curve fitting an effective reference state relative to departure functions formed using the Peng-Robinson cubic state equation Fit parameters for H2, O2, N2, propane, methane, n-heptane, and methanol are given.

  2. (High-pressure structural studies of promethium)

    SciTech Connect

    Haire, R.G.

    1988-11-15

    The primary object of the foreign travel was to carry out collaborative high-pressure structural studies at the European Institute for Transuranium Elements (EITU), Karlsruhe, Federal Republic of Germany. These studies reestablished previous collaborative investigations by ORNL and EITU that have been very productive scientifically during the past few years. The study during the present travel period was limited to a structural study of promethium metal under pressure.

  3. High Temperature Dynamic Pressure Measurements Using Silicon Carbide Pressure Sensors

    NASA Technical Reports Server (NTRS)

    Okojie, Robert S.; Meredith, Roger D.; Chang, Clarence T.; Savrun, Ender

    2014-01-01

    Un-cooled, MEMS-based silicon carbide (SiC) static pressure sensors were used for the first time to measure pressure perturbations at temperatures as high as 600 C during laboratory characterization, and subsequently evaluated in a combustor rig operated under various engine conditions to extract the frequencies that are associated with thermoacoustic instabilities. One SiC sensor was placed directly in the flow stream of the combustor rig while a benchmark commercial water-cooled piezoceramic dynamic pressure transducer was co-located axially but kept some distance away from the hot flow stream. In the combustor rig test, the SiC sensor detected thermoacoustic instabilities across a range of engine operating conditions, amplitude magnitude as low as 0.5 psi at 585 C, in good agreement with the benchmark piezoceramic sensor. The SiC sensor experienced low signal to noise ratio at higher temperature, primarily due to the fact that it was a static sensor with low sensitivity.

  4. Single Molecule Raman Spectroscopy Under High Pressure

    NASA Astrophysics Data System (ADS)

    Fu, Yuanxi; Dlott, Dana

    2014-06-01

    Pressure effects on surface-enhanced Raman scattering spectra of Rhdoamine 6G adsorbed on silver nanoparticle surfaces was studied using a confocal Raman microscope. Colloidal silver nanoparticles were treated with Rhodamine 6G (R6G) and its isotopically substituted partner, R6G-d4. Mixed isotopomers let us identify single-molecule spectra, since multiple-molecule spectra would show vibrational transitions from both species. The nanoparticles were embedded into a poly vinyl alcohol film, and loaded into a diamond anvil cell for the high-pressure Raman scattering measurement. Argon was the pressure medium. Ambient pressure Raman scattering spectra showed few single-molecule spectra. At moderately high pressure ( 1GPa), a surprising effect was observed. The number of sites with observable spectra decreased dramatically, and most of the spectra that could be observed were due to single molecules. The effects of high pressure suppressed the multiple-molecule Raman sites, leaving only the single-molecule sites to be observed.

  5. Thermal Transport at Static High-Pressures

    NASA Astrophysics Data System (ADS)

    Pangilinan, G. I.; Ladouceur, H. D.; Russell, T. P.

    2000-03-01

    Static properties and dynamic processes at high pressures and high temperatures are critically dependent on thermal properties of materials. Measurements of thermal properties at high pressures have only slowly developed through the years. Here we present a novel method, utilizing gem anvil cells, to measure specific heat, thermal conductivity and thermal diffusivity. The method involves launching a thermal wave in a sample. Subsequently, a localized sensor measures the temporal behavior of the temperature at a fixed point downstream in the material. A pulsed laser is used to deliver the heating pulse, while time-resolved fluorescence from a ruby sphere is used to measure the temperature. The thermal properties are inferred from the temporal behavior of the temperature and the heat conduction equations with appropriate boundary conditions. The thermal properties of table salt (NaCl) are obtained using this method. Impact to current and future high-pressure research, including materials science and geophysics will be addressed.

  6. A high-temperature wideband pressure transducer

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.

    1975-01-01

    Progress in the development of a pressure transducer for measurement of the pressure fluctuations in the high temperature environment of a jet exhaust is reported. A condenser microphone carrier system was adapted to meet the specifications. A theoretical analysis is presented which describes the operation of the condenser microphone in terms of geometry, materials, and other physical properties. The analysis was used as the basis for design of a prototype high temperature microphone. The feasibility of connecting the microphone to a converter over a high temperature cable operating as a half-wavelength transmission line was also examined.

  7. Crystal structures at high pressures and temperatures

    NASA Astrophysics Data System (ADS)

    Caldwell, Wendel Alexander

    2000-10-01

    The diamond anvil cell (DAC) is a unique instrument that can generate pressures equivalent to those inside planetary interiors (pressures on the order of 1 million atmospheres) under sustained conditions. When combined with a bright source of collimated x-rays, the DAC can be used to probe the structure of materials in-situ at ultra-high pressures. An understanding of the high-pressure structure of materials is important in determining what types of processes may take place in the Earth at great depths. Motivated by previous studies showing that xenon becomes metallic at pressures above ˜1 megabar (100 GPa), we examined the stable structures and reactivity of xenon at pressures approaching that of the core-mantle boundary in the Earth. Our findings indicate the transformation of xenon from face-centered cubic (fcc) to hexagonal close-packed (hcp) structures is kinetically hindered at room temperature, with the equilibrium fcc--hcp phase boundary at 21 (+/-3) gigapascals, a pressure lower than was previously thought. Additionally, we find no tendency on the part of xenon to form a metal alloy with iron or platinum to at least 100 to 150 gigapascals, making it unlikely that the Earth's core serves as a reservoir for primordial xenon. Measurements of the compressibility of natural (Mg.75,Fe .25)2SiO4 gamma-spinel at pressures of the Earth's transition zone yield a pressure derivative of the bulk modulus K0 ' = 6.3 (+/-0.3). As gamma-spinel is considered to be a dominant mineral phase of the transition-zone of the Earth's mantle (400--670 km depth), the relatively high value of K0' for gamma-spinel may help explain the rapid increase with depth of seismic velocities through the transition zone. The thermodynamics, mechanisms and kinetics of pressure-induced amorphization are not well understood. We report here new studies indicating little or no entropy difference between the crystalline and glassy states of Ca(OH) 2 (portlandite). Additional work on the pressure

  8. High pressure, high current, low inductance, high reliability sealed terminals

    DOEpatents

    Hsu, John S [Oak Ridge, TN; McKeever, John W [Oak Ridge, TN

    2010-03-23

    The invention is a terminal assembly having a casing with at least one delivery tapered-cone conductor and at least one return tapered-cone conductor routed there-through. The delivery and return tapered-cone conductors are electrically isolated from each other and positioned in the annuluses of ordered concentric cones at an off-normal angle. The tapered cone conductor service can be AC phase conductors and DC link conductors. The center core has at least one service conduit of gate signal leads, diagnostic signal wires, and refrigerant tubing routed there-through. A seal material is in direct contact with the casing inner surface, the tapered-cone conductors, and the service conduits thereby hermetically filling the interstitial space in the casing interior core and center core. The assembly provides simultaneous high-current, high-pressure, low-inductance, and high-reliability service.

  9. High pressure and high temperature behaviour of ZnO

    SciTech Connect

    Thakar, Nilesh A.; Bhatt, Apoorva D.; Pandya, Tushar C.

    2014-04-24

    The thermodynamic properties with the wurtzite (B4) and rocksalt (B1) phases of ZnO under high pressures and high temperatures have been investigated using Tait's Equation of state (EOS). The effects of pressures and temperatures on thermodynamic properties such as bulk modulus, thermal expansivity and thermal pressure are explored for both two structures. It is found that ZnO material gradually softens with increase of temperature while it hardens with the increment of the pressure. Our predicted results of thermodynamics properties for both the phases of ZnO are in overall agreement with the available data in the literature.

  10. Curved and conformal high-pressure vessel

    SciTech Connect

    Croteau, Paul F.; Kuczek, Andrzej E.; Zhao, Wenping

    2016-10-25

    A high-pressure vessel is provided. The high-pressure vessel may comprise a first chamber defined at least partially by a first wall, and a second chamber defined at least partially by the first wall. The first chamber and the second chamber may form a curved contour of the high-pressure vessel. A modular tank assembly is also provided, and may comprise a first mid tube having a convex geometry. The first mid tube may be defined by a first inner wall, a curved wall extending from the first inner wall, and a second inner wall extending from the curved wall. The first inner wall may be disposed at an angle relative to the second inner wall. The first mid tube may further be defined by a short curved wall opposite the curved wall and extending from the second inner wall to the first inner wall.

  11. Fluid hydrogen at high density - Pressure dissociation

    NASA Technical Reports Server (NTRS)

    Saumon, Didier; Chabrier, Gilles

    1991-01-01

    A model for the Helmholtz free energy of fluid hydrogen at high density and high temperature is developed. This model aims at describing both pressure and temperature dissociation and ionization and bears directly on equations of state of partially ionized plasmas, as encountered in astrophysical situations and high-pressure experiments. This paper focuses on a mixture of hydrogen atoms and molecules and is devoted to the study of the phenomenon of pressure dissociation at finite temperatures. In the present model, the strong interactions are described with realistic potentials and are computed with a modified Weeks-Chandler-Andersen fluid perturbation theory that reproduces Monte Carlo simulations to better than 3 percent. Theoretical Hugoniot curves derived from the model are in excellent agreement with experimental data.

  12. Fluid hydrogen at high density - Pressure dissociation

    NASA Technical Reports Server (NTRS)

    Saumon, Didier; Chabrier, Gilles

    1991-01-01

    A model for the Helmholtz free energy of fluid hydrogen at high density and high temperature is developed. This model aims at describing both pressure and temperature dissociation and ionization and bears directly on equations of state of partially ionized plasmas, as encountered in astrophysical situations and high-pressure experiments. This paper focuses on a mixture of hydrogen atoms and molecules and is devoted to the study of the phenomenon of pressure dissociation at finite temperatures. In the present model, the strong interactions are described with realistic potentials and are computed with a modified Weeks-Chandler-Andersen fluid perturbation theory that reproduces Monte Carlo simulations to better than 3 percent. Theoretical Hugoniot curves derived from the model are in excellent agreement with experimental data.

  13. High pressure electrical insulated feed thru connector

    DOEpatents

    Oeschger, Joseph E.; Berkeland, James E.

    1979-11-13

    A feed-thru type hermetic electrical connector including at least one connector pin feeding through an insulator block within the metallic body of the connector shell. A compression stop arrangement coaxially disposed about the insulator body is brazed to the shell, and the shoulder on the insulator block bears against this top in a compression mode, the high pressure or internal connector being at the opposite end of the shell. Seals between the pin and an internal bore at the high pressure end of the insulator block and between the insulator block and the metallic shell at the high pressure end are hermetically brazed in place, the first of these also functioning to transfer the axial compressive load without permitting appreciable shear action between the pin and insulator block.

  14. High pressure chemistry of substituted acetylenes

    SciTech Connect

    Chellappa, Raja; Dattelbaum, Dana; Sheffield, Stephen; Robbins, David

    2011-01-25

    High pressure in situ synchrotron x-ray diffraction experiments were performed on substituted polyacetylenes: tert-butyl acetylene [TBA: (CH{sub 3}){sub 3}-C{triple_bond}CH] and ethynyl trimethylsilane [ETMS: (CH{sub 3}){sub 3}-Si{triple_bond}CH] to investigate pressure-induced chemical reactions. The starting samples were the low temperature crystalline phases which persisted metastably at room temperature and polymerized beyond 11 GPa and 26 GPa for TBA and ETMS respectively. These reaction onset pressures are considerably higher than what we observed in the shockwave studies (6.1 GPa for TBA and 6.6 GPa for ETMS). Interestingly, in the case of ETMS, it was observed with fluid ETMS as starting sample, reacts to form a semi-crystalline polymer (crystalline domains corresponding to the low-T phase) at pressures less than {approx}2 GPa. Further characterization using vibrational spectroscopy is in progress.

  15. Phonon Drag Dislocations at High Pressures

    SciTech Connect

    Wolfer, W.G.

    1999-10-19

    Phonon drag on dislocations is the dominant process which determines the flow stress of metals at elevated temperatures and at very high plastic deformation rates. The dependence of the phonon drag on pressure or density is derived using a Mie-Grueneisen equation of state. The phonon drag is shown to increase nearly linearly with temperature but to decrease with density or pressure. Numerical results are presented for its variation for shock-loaded copper and aluminum. In these cases, density and temperature increase simultaneously, resulting in a more modest net increase in the dislocation drag coefficient. Nevertheless, phonon drag increases by more than an order of magnitude during shock deformations which approach melting. Since the dependencies of elastic moduli and of the phonon drag coefficient on pressure and temperature are fundamentally different, the effect of pressure on the constitutive law for plastic deformation can not simply be accounted for by its effect on the elastic shear modulus.

  16. Hydrogen at high pressure and temperatures

    SciTech Connect

    Nellis, W J

    1999-09-30

    Hydrogen at high pressures and temperatures is challenging scientifically and has many real and potential applications. Minimum metallic conductivity of fluid hydrogen is observed at 140 GPa and 2600 K, based on electrical conductivity measurements to 180 GPa (1.8 Mbar), tenfold compression, and 3000 K obtained dynamically with a two-stage light-gas gun. Conditions up to 300 GPa, sixfold compression, and 30,000 K have been achieved in laser-driven Hugoniot experiments. Implications of these results for the interior of Jupiter, inertial confinement fusion, and possible uses of metastable solid hydrogen, if the metallic fluid could be quenched from high pressure, are discussed.

  17. High pressure freon decontamination of remote equipment

    SciTech Connect

    Wilson, C.E.

    1987-01-01

    A series of decontamination tests using high pressure FREON 113 was conducted in the 200 Area of the Hanford site. The intent of these tests was to evaluate the effectiveness of FREON 113 in decontamination of manipulator components, tools, and equipment items contaminated with mixed fission products. The test results indicated that high pressure FREON 113 is very effective in removing fissile material from a variety of objects and can reduce both the quantity and the volume of the radioactive waste material presently being buried.

  18. Superelastic carbon spheres under high pressure

    NASA Astrophysics Data System (ADS)

    Li, Meifen; Guo, Junjie; Xu, Bingshe

    2013-03-01

    We report a superelastic deformation behavior of carbon spheres by the in situ Raman spectroscopy in a high-pressure diamond anvil cell. The carbon spheres produced by arc discharging in toluene have a mean diameter of 200 nm and an onion-like multilayer graphitic structure. We find that the elastic coefficients, during both the compression and decompression processes, remain a constant up to 10 GPa, indicating a superior high-pressure structural stability. Such superelastic behavior is related to the isotropic and concentric configuration of carbon spheres and provides additional insight into improving the microscopic mechanical properties of small-scale particles.

  19. High pressure water jet cutting and stripping

    NASA Technical Reports Server (NTRS)

    Hoppe, David T.; Babai, Majid K.

    1991-01-01

    High pressure water cutting techniques have a wide range of applications to the American space effort. Hydroblasting techniques are commonly used during the refurbishment of the reusable solid rocket motors. The process can be controlled to strip a thermal protective ablator without incurring any damage to the painted surface underneath by using a variation of possible parameters. Hydroblasting is a technique which is easily automated. Automation removes personnel from the hostile environment of the high pressure water. Computer controlled robots can perform the same task in a fraction of the time that would be required by manual operation.

  20. High pressure water jet mining machine

    DOEpatents

    Barker, Clark R.

    1981-05-05

    A high pressure water jet mining machine for the longwall mining of coal is described. The machine is generally in the shape of a plowshare and is advanced in the direction in which the coal is cut. The machine has mounted thereon a plurality of nozzle modules each containing a high pressure water jet nozzle disposed to oscillate in a particular plane. The nozzle modules are oriented to cut in vertical and horizontal planes on the leading edge of the machine and the coal so cut is cleaved off by the wedge-shaped body.

  1. Exotic stable cesium polynitrides at high pressure

    PubMed Central

    Peng, Feng; Han, Yunxia; Liu, Hanyu; Yao, Yansun

    2015-01-01

    New polynitrides containing metastable forms of nitrogen are actively investigated as potential high-energy-density materials. Using a structure search method based on the CALYPSO methodology, we investigated the stable stoichiometries and structures of cesium polynitrides at high pressures. Along with the CsN3, we identified five new stoichiometric compounds (Cs3N, Cs2N, CsN, CsN2, and CsN5) with interesting structures that may be experimentally synthesizable at modest pressures (i.e., less than 50 GPa). Nitrogen species in the predicted structures have various structural forms ranging from single atom (N) to highly endothermic molecules (N2, N3, N4, N5, N6) and chains (N∞). Polymeric chains of nitrogen were found in the high-pressure C2/c phase of CsN2. This structure contains a substantially high content of single N-N bonds that exceeds the previously known nitrogen chains in pure forms, and also exhibit metastability at ambient conditions. We also identified a very interesting CsN crystal that contains novel N44− anion. To our best knowledge, this is the first time a charged N4 species being reported. Results of the present study suggest that it is possible to obtain energetic polynitrogens in main-group nitrides under high pressure. PMID:26581175

  2. Exotic stable cesium polynitrides at high pressure

    DOE PAGES

    Peng, Feng; Han, Yunxia; Liu, Hanyu; ...

    2015-11-19

    New polynitrides containing metastable forms of nitrogen are actively investigated as potential high energy-density materials. Using a structure search method based on the CALYPSO methodology, we investigated the stable stoichiometries and structures of cesium polynitrides at high pressures. Along with the CsN3, we identified five new stoichiometric compounds (Cs3N, Cs2N, CsN, CsN2, and CsN5) with interesting structures that may be experimentally synthesizable at modest pressures (i.e., less than 50 GPa). Nitrogen species in the predicted structures have various structural forms ranging from single atom (N) to highly endothermic molecules (N2, N3 , N4, N5, N6) and chains (N∞). Polymeric chainsmore » of nitrogen were found in the high-pressure C2/c phase of CsN2. This structure contains a substantially high content of single N-N bonds that exceeds the previously known nitrogen chains in pure forms, and also exhibit metastability at ambient conditions. We also identified a very interesting CsN crystal that contains novel N44- anion. In conclusion, to our best knowledge, this is the first time a charged N4 species being reported. Results of the present study suggest that it is possible to obtain energetic polynitrogens in main-group nitrides under high pressure.« less

  3. Introduction to High-Pressure Science

    NASA Astrophysics Data System (ADS)

    Dera, Przemyslaw

    To a common person pressure is just one of the parameters that describe a thermodynamic state. We all hear about it in everyday weather forecasts, and most of us do not associate it with anything particularly unique. Probably the most intuitive idea of the effect of high-pressure comes from movies, where submarine sinking to the bottom of the ocean is gradually crushed by the surrounding water, until its hull implodes. Why, then hundreds of scientists throughout the world spent their lifelong careers studying high-pressure phenomena? Despite all the developments in experimental technologies and instrumentation, modern scientist has very few tools that allow him or her to "grab" two atoms and bring them, in a very controllable way, closer together. Being able to achieve this task means the ability to directly probe interatomic interaction potentials and can cause transformations as dramatic as turning of a common gas into solid metal. Before the reader delves into more advanced topics described later in this book, this introductory chapter aims to explain several elementary, but extremely important concepts in high-pressure science. We will start with a brief discussion of laboratory devices used to produce pressure, address the issue of hydrostaticity, elastic and plastic compression, and will conclude with a short discussion of unique effects of anisotropic stress.

  4. High pressure effects on allergen food proteins.

    PubMed

    Somkuti, Judit; Smeller, László

    2013-12-15

    There are several proteins, which can cause allergic reaction if they are inhaled or ingested. Our everyday food can also contain such proteins. Food allergy is an IgE-mediated immune disorder, a growing health problem of great public concern. High pressure is known to affect the structure of proteins; typically few hundred MPa pressure can lead to denaturation. That is why several trials have been performed to alter the structure of the allergen proteins by high pressure, in order to reduce its allergenicity. Studies have been performed both on simple protein solutions and on complex food systems. Here we review those allergens which have been investigated under or after high pressure treatment by methods capable of detecting changes in the secondary and tertiary structure of the proteins. We focus on those allergenic proteins, whose structural changes were investigated by spectroscopic methods under pressure in correlation with the observed allergenicity (IgE binding) changes. According to this criterion we selected the following allergen proteins: Mal d 1 and Mal d 3 (apple), Bos d 5 (milk), Dau c 1 (carrot), Gal d 2 (egg), Ara h 2 and Ara h 6 (peanut), and Gad m 1 (cod). Copyright © 2013 Elsevier B.V. All rights reserved.

  5. Raman study of opal at high pressure

    NASA Astrophysics Data System (ADS)

    Farfan, G.; Wang, S.; Mao, W. L.

    2011-12-01

    More commonly known for their beauty and lore as gemstones, opals are also intriguing geological materials which may have potential for materials science applications. Opal lacks a definite crystalline structure, and is composed of an amorphous packing of hydrated silica (SiO2) spheroids, which provides us with a unique nano-scaled mineraloid with properties unlike those of other amorphous materials like glass. Opals from different localities were studied at high pressure using a diamond anvil cell to apply pressure and Raman spectroscopy to look at changes in bonding as pressure was increased. We first tested different samples from Virgin Valley, NV, Spencer, ID, Juniper Ridge, OR, and Australia, which contain varying amounts of water at ambient conditions, using Raman spectroscopy to determine if they were opal-CT (semicrystalline cristobalite-trydimite volcanic origin) or opal-A (amorphous sedimentary origin). We then used x-ray diffraction and Raman spectroscopy in a diamond anvil cell to see how their bonding and structure changed under compression and to determine what effect water content had on their high pressure behavior. Comparison of our results on opal to other high pressure studies of amorphous materials like glass has implications from a geological and materials science standpoint.

  6. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect

    Stefano Orsino

    2005-03-30

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction

  7. Design guide for high pressure oxygen systems

    NASA Technical Reports Server (NTRS)

    Bond, A. C.; Pohl, H. O.; Chaffee, N. H.; Guy, W. W.; Allton, C. S.; Johnston, R. L.; Castner, W. L.; Stradling, J. S.

    1983-01-01

    A repository for critical and important detailed design data and information, hitherto unpublished, along with significant data on oxygen reactivity phenomena with metallic and nonmetallic materials in moderate to very high pressure environments is documented. This data and information provide a ready and easy to use reference for the guidance of designers of propulsion, power, and life support systems for use in space flight. The document is also applicable to designs for industrial and civilian uses of high pressure oxygen systems. The information presented herein are derived from data and design practices involving oxygen usage at pressures ranging from about 20 psia to 8000 psia equal with thermal conditions ranging from room temperatures up to 500 F.

  8. Too Many Americans Have High Blood Pressure, Doctors Warn

    MedlinePlus

    ... news/fullstory_163468.html Too Many Americans Have High Blood Pressure, Doctors Warn With February designated National Heart Month, ... physicians warns that too many Americans struggle with high blood pressure. High blood pressure is a major risk factor ...

  9. Advanced Diagnostics for High Pressure Spray Combustion.

    SciTech Connect

    Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

    2014-06-01

    The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

  10. Solid-phase microcolumn extraction and gas chromatography-mass spectrometry identification of volatile organic compounds emitted by paper.

    PubMed

    Hrivnák, Ján; Tölgyessy, Peter; Figedyová, Sona; Katuscák, Svetozár

    2009-11-15

    A rapid non-destructive sampling technique for the analysis of volatile organic compounds (VOCs) emitted by paper sheets is described. A capillary, which is connected to a microcolumn packed with Tenax TA, is inserted between two sheets at the centre of a paper stack encapsulated inside a PET/Al/PE composite foil. The other end of the microcolumn is connected to a gas-tight syringe and an appropriate volume of gaseous phase is aspirated. The microcolumn is then thermally desorbed in a modified GC inlet (modification is presented) and analysed by gas chromatography-mass spectrometry (GC-MS). In the chromatogram from the analysis of artificially aged paper sample 21 compounds were identified. Advantages of the method including the short sampling time (1 min), simplicity and economic aspect are discussed.

  11. Cobalt ferrite nanoparticles under high pressure

    SciTech Connect

    Saccone, F. D.; Ferrari, S.; Grinblat, F.; Bilovol, V.; Errandonea, D.

    2015-08-21

    We report by the first time a high pressure X-ray diffraction and Raman spectroscopy study of cobalt ferrite (CoFe{sub 2}O{sub 4}) nanoparticles carried out at room temperature up to 17 GPa. In contrast with previous studies of nanoparticles, which proposed the transition pressure to be reduced from 20–27 GPa to 7.5–12.5 GPa (depending on particle size), we found that cobalt ferrite nanoparticles remain in the spinel structure up to the highest pressure covered by our experiments. In addition, we report the pressure dependence of the unit-cell parameter and Raman modes of the studied sample. We found that under quasi-hydrostatic conditions, the bulk modulus of the nanoparticles (B{sub 0} = 204 GPa) is considerably larger than the value previously reported for bulk CoFe{sub 2}O{sub 4} (B{sub 0} = 172 GPa). In addition, when the pressure medium becomes non-hydrostatic and deviatoric stresses affect the experiments, there is a noticeable decrease of the compressibility of the studied sample (B{sub 0} = 284 GPa). After decompression, the cobalt ferrite lattice parameter does not revert to its initial value, evidencing a unit cell contraction after pressure was removed. Finally, Raman spectroscopy provides information on the pressure dependence of all Raman-active modes and evidences that cation inversion is enhanced by pressure under non-hydrostatic conditions, being this effect not fully reversible.

  12. Material Composite Behavior Under High-Pressure

    NASA Astrophysics Data System (ADS)

    Conil, N.; Kavner, A.

    2004-12-01

    In situ x-ray diffraction techniques under relevant pressure and temperature conditions provide unique information about phase stability, elasticity and deformation behavior of Earth materials. Often samples consist of a calibrated standard intermixed with the material of interest. Accurate measurements of equation of state are based on two assumptions: that the equation of state of the calibrant is known precisely, and that the pressures of these two materials are the same. However, except under strict conditions of hydrostaticity, pressures are not necessary equal. To provide a detailed examination of the pressure relationship in the diamond anvil cell sample chamber, we analyzed two standard materials mixed together in a controlled geometry. Our samples consisted of unidirectional Al2O3 ceramic fibers ( ˜ 1μ m diameter) distributed in an Al metal matrix. This was ideal because both materials are existing high-pressure standards and the oxide/metal mixture is similar to many experiments. We conducted room temperature radial x-ray diffraction experiments using a diamond anvil cell at the X17C beamline at National Synchrotron Light Source. We studied two different fiber orientations with respect to the diamond anvil cell compression axis: one with fibers oriented vertically and the second, horizontally. In each case we measured the d-spacing of lattice planes as a function of rotation angle between principle stress axes and diffraction geometry. From these data, we calculated pressure and supported differential stress of both Al and Al2O3. We found that geometry plays an important role in determining the relative pressure and strength behavior of the two materials. At comparable pressures, in the vertical fibers case, PAl ˜ 8.7 GPa, PAl2O3 ˜ 10.2 GPa and in the horizontal fibers case, PAl ˜ 9.6 GPa when PAl2O3 ˜ 10.2 GPa. Thus, when the fibers are oriented vertically, aluminum pressure is always smaller than alumina pressure; whereas in the horizontal case

  13. Stability of xenon oxides at high pressures.

    PubMed

    Zhu, Qiang; Jung, Daniel Y; Oganov, Artem R; Glass, Colin W; Gatti, Carlo; Lyakhov, Andriy O

    2013-01-01

    Xenon, which is quite inert under ambient conditions, may become reactive under pressure. The possibility of the formation of stable xenon oxides and silicates in the interior of the Earth could explain the atmospheric missing xenon paradox. Using an ab initio evolutionary algorithm, we predict the existence of thermodynamically stable Xe-O compounds at high pressures (XeO, XeO(2) and XeO(3) become stable at pressures above 83, 102 and 114 GPa, respectively). Our calculations indicate large charge transfer in these oxides, suggesting that large electronegativity difference and high pressure are the key factors favouring the formation of xenon compounds. However, xenon compounds cannot exist in the Earth's mantle: xenon oxides are unstable in equilibrium with the metallic iron occurring in the lower mantle, and xenon silicates are predicted to decompose spontaneously at all mantle pressures (<136 GPa). However, it is possible that xenon atoms may be retained at defects in mantle silicates and oxides.

  14. Sounding experiments of high pressure gas discharge

    SciTech Connect

    Biele, Joachim K.

    1998-07-10

    A high pressure discharge experiment (200 MPa, 5{center_dot}10{sup 21} molecules/cm{sup 3}, 3000 K) has been set up to study electrically induced shock waves. The apparatus consists of the combustion chamber (4.2 cm{sup 3}) to produce high pressure gas by burning solid propellant grains to fill the electrical pump chamber (2.5 cm{sup 3}) containing an insulated coaxial electrode. Electrical pump energy up to 7.8 kJ at 10 kV, which is roughly three times of the gas energy in the pump chamber, was delivered by a capacitor bank. From the current-voltage relationship the discharge develops at rapidly decreasing voltage. Pressure at the combustion chamber indicating significant underpressure as well as overpressure peaks is followed by an increase of static pressure level. These data are not yet completely understood. However, Lorentz forces are believed to generate pinching with subsequent pinch heating, resulting in fast pressure variations to be propagated as rarefaction and shock waves, respectively. Utilizing pure axisymmetric electrode initiation rather than often used exploding wire technology in the pump chamber, repeatable experiments were achieved.

  15. Nanoshells as a high-pressure gauge

    NASA Astrophysics Data System (ADS)

    Tempere, Jacques; van den Broeck, Nick; Putteneers, Katrijn; Silvera, Isaac

    2012-02-01

    Nanoshells, consisting of multiple spherical layers, have an extensive list of applications, usually performing the function of a probe. We add a new application to this list in the form of a high-pressure gauge in a Diamond Anvil Cell (DAC). In a DAC, where high pressures are reached by pressing two diamonds together, existing gauges fail at higher pressures because of calibration difficulties and obscuring effects in the diamonds. The nanoshell gauge does not face this issue since its optical spectrum can be engineered by altering the thickness of its layers. Furthermore their properties are measured by broad band optical transmission spectroscopy leading to a very large signal-to-noise ratio even in the multi-megabar pressure regime where ruby measurements become challenging. Theoretical calculations based on the Maxwell equations in a spherical geometry combined with the Vinet equation of state show that a three-layer geometry (SiO2-Au-SiO2) indeed has a measurable pressure-dependent optical response desirable for gauges.

  16. High temperature pressure coupled ultrasonic waveguide

    DOEpatents

    Caines, Michael J.

    1983-01-01

    A pressure coupled ultrasonic waveguide is provided to which one end may be attached a transducer and at the other end a high temperature material for continuous ultrasonic testing of the material. The ultrasonic signal is coupled from the waveguide into the material through a thin, dry copper foil.

  17. High pressure studies of planetary matter

    SciTech Connect

    Ross, M.

    1989-06-01

    Those materials which are of greatest interest to the physics of the deep planetary interiors are Fe, H/sub 2/, He and the Ices. These are sufficiently diverse and intensively studied to offer an overview of present day high pressure research. 13 refs., 1 fig.

  18. Hurricane risk mitigation - High Pressure Gas Facility

    NASA Technical Reports Server (NTRS)

    2008-01-01

    A worker pours concrete as part of a nitrogen risk mitigation project at the High Pressure Gas Facility at Stennis Space Center. The concrete slab will provide the foundation needed to place new pumps at the site and is part of ongoing hurricane-related mitigation work at Stennis.

  19. High Pressure Inactivation of HAV within Mussels

    USDA-ARS?s Scientific Manuscript database

    The potential of hepatitis A virus (HAV) to be inactivated within Mediterranean mussels (Mytilus galloprovincialis) and blue mussels (Mytilus edulis) by high pressure processing was evaluated. HAV was bioaccumulated within mussels to approximately 6-log10 PFU by exposure of mussels to HAV-contamina...

  20. Hurricane risk mitigation - High Pressure Gas Facility

    NASA Image and Video Library

    2008-07-29

    A worker pours concrete as part of a nitrogen risk mitigation project at the High Pressure Gas Facility at Stennis Space Center. The concrete slab will provide the foundation needed to place new pumps at the site and is part of ongoing hurricane-related mitigation work at Stennis.

  1. High pressure luminescence probes in polymers

    SciTech Connect

    Drickamer, H.G.

    1980-01-01

    High pressure luminescence has proved to be a very powerful tool for characterizing crystalline solids and liquids. Two problems involving glassy polymers are analyzed. In the first problem the excited states of azulene and its derivatives are used to probe intermolecular interactions in PMMA and PS. In the second problem the change in emission intensity with pressure from two excimer states of polyvinylcarbazole as a pure polymer and in dilute solution in polystyrene (PS), polymethylmethacrylate (PMMA) and polyisoliutylene (PIB) is studied. The relative emission from the two states depends strongly on the possibility for motion of polymer segments. The observations are related to the proximity to the glass transition.

  2. Efficient High Pressure MixtureState Equations

    NASA Technical Reports Server (NTRS)

    Harstad, K. G.; Miller, R. S.; Bellan, J.

    1996-01-01

    A method is presented for an accurate noniterative, computationally efficient calculation of high pressure fluid mixture equations of state, especially targeted to gas turbines and rocket engines. Pressures above 1 bar and temperatures above 100 K are addressed. The method is based on curve fitting an effective reference state relative to departure funcitons formed using the Peng-Robinson cubic state equation. Fit parameters for H(sub 2), O(sub 2), N(sub 2), propane, n-heptane and methanol are given.

  3. Submarine High Pressure Dehydrator Performance Test

    DTIC Science & Technology

    1988-06-07

    Hatala of September 1985. Prepared for NAVSEA 05N under contract number N00024-33-C-2111. 13. General Dynamics Corporation, High Pressure Air Filtration...Cooling Water Pump Gear Ratio ............... 4:1 Cooling Water Pump Full Load Speed .......... 3500 rpm Water Pump TDH @ 3400 RPM & 15 GPM...Temperature Monitor Thomas A. Edison, Inc. 12-1/2" x 7-1/4" x 9" 25 lbs. Motor Electro Dynamic 2𔄁-1/16" x 2𔃾-1/4" x 2𔃻-1/4" 1150 lbs. S Pressure

  4. (Ultra) high pressure homogenization for continuous high pressure sterilization of pumpable foods - a review.

    PubMed

    Georget, Erika; Miller, Brittany; Callanan, Michael; Heinz, Volker; Mathys, Alexander

    2014-01-01

    Bacterial spores have a strong resistance to both chemical and physical hurdles and create a risk for the food industry, which has been tackled by applying high thermal intensity treatments to sterilize food. These strong thermal treatments lead to a reduction of the organoleptic and nutritional properties of food and alternatives are actively searched for. Innovative hurdles offer an alternative to inactivate bacterial spores. In particular, recent technological developments have enabled a new generation of high pressure homogenizer working at pressures up to 400 MPa and thus, opening new opportunities for high pressure sterilization of foods. In this short review, we summarize the work conducted on (ultra) high pressure homogenization (U)HPH to inactivate endospores in model and food systems. Specific attention is given to process parameters (pressure, inlet, and valve temperatures). This review gathers the current state of the art and underlines the potential of UHPH sterilization of pumpable foods while highlighting the needs for future work.

  5. (Ultra) High Pressure Homogenization for Continuous High Pressure Sterilization of Pumpable Foods – A Review

    PubMed Central

    Georget, Erika; Miller, Brittany; Callanan, Michael; Heinz, Volker; Mathys, Alexander

    2014-01-01

    Bacterial spores have a strong resistance to both chemical and physical hurdles and create a risk for the food industry, which has been tackled by applying high thermal intensity treatments to sterilize food. These strong thermal treatments lead to a reduction of the organoleptic and nutritional properties of food and alternatives are actively searched for. Innovative hurdles offer an alternative to inactivate bacterial spores. In particular, recent technological developments have enabled a new generation of high pressure homogenizer working at pressures up to 400 MPa and thus, opening new opportunities for high pressure sterilization of foods. In this short review, we summarize the work conducted on (ultra) high pressure homogenization (U)HPH to inactivate endospores in model and food systems. Specific attention is given to process parameters (pressure, inlet, and valve temperatures). This review gathers the current state of the art and underlines the potential of UHPH sterilization of pumpable foods while highlighting the needs for future work. PMID:25988118

  6. Apparatus for testing high pressure injector elements

    NASA Technical Reports Server (NTRS)

    Myers, William Neill (Inventor); Scott, Ewell M. (Inventor); Forbes, John C. (Inventor); Shadoan, Michael D. (Inventor)

    1993-01-01

    An apparatus for testing and evaluating the spray pattern of high pressure fuel injector elements for use in supplying fuel to combustion engines is presented. Prior art fuel injector elements were normally tested by use of low pressure apparatuses which did not provide a purge to prevent mist from obscuring the injector element or to prevent frosting of the view windows; could utilize only one fluid during each test; and had their viewing ports positioned one hundred eighty (180 deg) apart, thus preventing optimum use of laser diagnostics. The high pressure fluid injector test apparatus includes an upper hub, an upper weldment or housing, a first clamp and stud/nut assembly for securing the upper hub to the upper weldment, a standoff assembly within the upper weldment, a pair of window housings having view glasses within the upper weldment, an injector block assembly and purge plate within the upper weldment for holding an injector element to be tested and evaluated, a lower weldment or housing, a second clamp and stud/nut assembly for securing the lower weldment to the upper weldment, a lower hub, a third clamp and stud/nut assembly for securing the lower hub to the lower weldment, mechanisms for introducing fluid under high pressure for testing an injector element, and mechanisms for purging the apparatus to prevent frosting of view glasses within the window housings and to permit unobstructed viewing of the injector element.

  7. Amorphous boron nitride at high pressure

    NASA Astrophysics Data System (ADS)

    Durandurdu, Murat

    2016-06-01

    The pressure-induced phase transformation in hexagonal boron nitrite and amorphous boron nitrite is studied using ab initio molecular dynamics simulations. The hexagonal-to-wurtzite phase transformation is successfully reproduced in the simulation with a transformation mechanism similar to one suggested in experiment. Amorphous boron nitrite, on the other hand, gradually transforms to a high-density amorphous phase with the application of pressure. This phase transformation is irreversible because a densified amorphous state having both sp3 and sp2 bonds is recovered upon pressure release. The high-density amorphous state mainly consists of sp3 bonds and its local structure is quite similar to recently proposed intermediate boron nitrite phases, in particular tetragonal structure (P42/mnm), rather than the known the wurtzite or cubic boron nitrite due to the existence of four membered rings and edge sharing connectivity. On the basis of this finding we propose that amorphous boron nitrite might be best candidate as a starting structure to synthesize the intermediate phase(s) at high pressure and temperature (probably below 800 °C) conditions.

  8. Apparatus for testing high pressure injector elements

    NASA Technical Reports Server (NTRS)

    Myers, William Neill (Inventor); Scott, Ewell M. (Inventor); Forbes, John C. (Inventor); Shadoan, Michael D. (Inventor)

    1995-01-01

    An apparatus for testing and evaluating the spray pattern of high pressure fuel injector elements for use in supplying fuel to combustion engines is presented. Prior art fuel injector elements were normally tested by use of low pressure apparatuses which did not provide a purge to prevent mist from obscuring the injector element or to prevent frosting of the view windows; could utilize only one fluid during each test; and had their viewing ports positioned one hundred eighty (180 deg) apart, thus preventing optimum use of laser diagnostics. The high pressure fluid injector test apparatus includes an upper hub, an upper weldment or housing, a first clamp and stud/nut assembly for securing the upper hub to the upper weldment, a standoff assembly within the upper weldment, a pair of window housings having view glasses within the upper weldment, an injector block assembly and purge plate within the upper weldment for holding an injector element to be tested and evaluated, a lower weldment or housing, a second clamp and stud/nut assembly for securing the lower weldment to the upper hub, a third clamp and stud/nut assembly for securing the lower hub to the lower weldment, mechanisms for introducing fluid under high pressure for testing an injector element, and mechanisms for purging the apparatus to prevent frosting of view glasses within the window housings and to permit unobstructed viewing of the injector element.

  9. Determination of beer aroma compounds using headspace solid-phase microcolumn extraction.

    PubMed

    Hrivňák, Ján; Smogrovičová, Daniela; Nádaský, Pavol; Lakatošová, Jana

    2010-11-15

    A rapid sampling technique for the analysis of beer aroma compounds is described. The headspace (10 ml) is passed through the microcolumn filled with 5mg of Tenax TA and thermally desorbed in a modified GC inlet (modification is described). Eight compounds (from acetaldehyde to 2-phenylethanol) in four beer samples were analyzed. The correlation coefficients (r(2)), repeatability (RSD) and limits of detection (LOD) were 0.9973-0.9994, 2.1-6.9% and 0.00002-0.13 mg/l, respectively. The methodology can be useful for routine beer sample analysis.

  10. Small, high-pressure liquid oxygen turbopump

    NASA Technical Reports Server (NTRS)

    Csomor, A.; Sutton, R.

    1977-01-01

    A small, high-pressure, liquid oxygen turbopump was designed, fabricated, and tested. The pump was of a single-stage, centrifugal type; power to the pump was supplied by a single-stage, partial emission, axial-impulse turbine. Design conditions included an operating speed of 70,000 rpm, pump discharge pressure of 2977 N/sq cm (4318 psia), and a pump flowrate of 16.4 kg/s (36.21 lb/sec). The turbine was propelled by LO2/LH2 combustion products at 1041 K (1874 R) inlet temperature, and at a design pressure ratio of 1.424. The approaches used in the detail analysis and design of the turbopump are described, and fabrication methods are discussed. Data obtained from gas generator tests, turbine performance calibration, and turbopump testing are presented.

  11. Small, high-pressure, liquid oxygen turbopump

    NASA Technical Reports Server (NTRS)

    Csomor, A.

    1978-01-01

    A small, high-pressure, LOX turbopump was designed, fabricated, and tested. The pump was of a single-stage, centrifugal type; power to the pump was supplied by a single-stage, partial-admission, axial-impulse turbine. Design conditions included an operating speed of 7330 rad/sec (70,000 rpm) pump discharge pressure of 2977 N/sq cm (4318 psia), and a pump flowrate of 16.4 kg/s (36.21 lb/sec). The turbine was propelled by LOX/LH2 combustion products at 1041 K (1874 R) inlet temperature, and at a design pressure ratio of 1.424. Test data obtained with the turbopump are presented and mechanical performance is discussed.

  12. Zeeman Effect in Ruby at High Pressures

    NASA Astrophysics Data System (ADS)

    Dan, Ioana

    2012-02-01

    We have developed a versatile fiber-coupled system for magneto-optical spectroscopy measurements at high pressure. The system is based on a miniature Cu-alloy Diamond Anvil Cell (from D'Anvils, Ltd) fitted with a custom-designed He gas-actuated membrane for in-situ pressure control, and coupled with a He transfer cryostat incorporating a superconducting magnet (from Quantum Designs). This system allows optical measurements (Raman, photoluminescence, reflectivity) within wide ranges of pressures (up to 100GPa), temperatures (4.2-300K) and magnetic fields (0-9T). We employ this system to examine the effect of pressure and non-hydrostatic stress on the Zeeman split d-d transitions of Cr^3+ in ruby (Al2O3: Cr^3+). We determine the effect of pressure and non-hydrostaticity on the trigonal crystal field in this material, and discuss the use of the Zeman-split ruby fluorescence as a possible probe for deviatoric stresses in diamond anvil cell experiments.

  13. High-pressure oxidation of ethane

    DOE PAGES

    Hashemi, Hamid; Jacobsen, Jon G.; Rasmussen, Christian T.; ...

    2017-05-02

    Here, ethane oxidation at intermediate temperatures and high pressures has been investigated in both a laminar flow reactor and a rapid compression machine (RCM). The flow-reactor measurements at 600–900 K and 20–100 bar showed an onset temperature for oxidation of ethane between 700 and 825 K, depending on pressure, stoichiometry, and residence time. Measured ignition delay times in the RCM at pressures of 10–80 bar and temperatures of 900–1025 K decreased with increasing pressure and/or temperature. A detailed chemical kinetic model was developed with particular attention to the peroxide chemistry. Rate constants for reactions on the C2H5O2 potential energy surfacemore » were adopted from the recent theoretical work of Klippenstein. In the present work, the internal H-abstraction in CH3CH2OO to form CH2CH2OOH was treated in detail. Modeling predictions were in good agreement with data from the present work as well as results at elevated pressure from literature. The experimental results and the modeling predictions do not support occurrence of NTC behavior in ethane oxidation. Even at the high-pressure conditions of the present work where the C2H5 + O2 reaction yields ethylperoxyl rather than C2H4 + HO2, the chain branching sequence CH3CH2OO → CH2CH2OOH → +O2 OOCH2CH2OOH → branching is not competitive, because the internal H-atom transfer in CH3CH2OO to CH2CH2OOH is too slow compared to thermal dissociation to C2H4 and HO2.« less

  14. High Pressure Behavior of FeOOH

    NASA Astrophysics Data System (ADS)

    Reagan, M. M.; Gleason, A. E.; Mao, W. L.

    2013-12-01

    Understanding the stability and properties of simple hydroxides at high pressures and temperatures offers an important first step toward quantifying more complex hydrogen-bearing compounds relevant to the Earth's interior. We focus on iron-oxy-hydroxides because they may be an important Fe and water bearing component in the deep Earth. Goethite (α-FeOOH) transforms to a high-pressure phase, ɛ-FeOOH, which is isostructural with δ-AlOOH, a material which may transport hydrogen to the core-mantle boundary. Here we present XES spectroscopy data of powder samples of synthesized alpha-FeOOH, beta-FeOOH and gamma-FeOOH monitoring their electronic spin transition. The samples was loaded into a Beryllium gasket, where a 50 micron hole served as the sample chamber with 300 micron culet diamond paired with a beveled 150 micron diamond in a diamond-anvil cell (DAC) without a pressure transmitting medium. Pressure was determined using ruby fluorescence (Mao et al. 1978). Using the incident X-ray energy centered at 11.3 KeV from the Advanced Photon Source, beam line HPCAT 16-ID-D, we measured Fe K-β 13 emission to pressures greater than 73 GPa. For alpha-FeOOH, we saw a clear shift in the main peak to lower energy, and an increasingly diminishing K beta prime peak intensity, indicating the sample was undergoing an electronic spin transition. The K beta prime peak completely disappeared at a pressure greater than 73 GPa. Beta-FeOOH showed no evidence of the beginnings of a spin transition, while gamma- FeOOH underwent an incomplete transition.

  15. Topaz and Kyanite Luminescence Under High Pressure

    NASA Astrophysics Data System (ADS)

    O'Bannon, E. F., III; Williams, Q. C.

    2014-12-01

    The luminescence spectra of Cr3+ in heat-treated topaz Al2SiO4(OH,F)2 and natural kyanite Al2SiO5 were measured from 650 - 800 nm in a hydrostatic environment up to pressures of 15 GPa. The R1 and R2 peaks of topaz shift at average rates of 0.30 nm/GPa and 0.22 nm/GPa, respectively, implying that the deformation of the Cr3+ octahedra increases with pressure. Three peaks are fit under each R line of topaz at both room and high pressure, and these peaks are associated with different Al sites into which the Cr substitutes. The shift of the R lines in topaz under pressure is remarkably linear, which appears to be a general feature of many Cr3+-bearing oxides: the underlying cause of this linearity may lie in anharmonic coupling with lattice vibrations. In this context, we also characterize the frequency shifts of two vibronic peaks within topaz. The R1 and R2 peaks of kyanite shift at 0.37 nm/GPa and 0.88 nm/GPa respectively. Two peaks are fit under R1 and three peaks are fit under R2 of kyanite at both room and high pressure; this result is also consistent with three different Cr3+ sites in this material. The R lines in kyanite are notably optically anisotropic, depending strongly on crystallographic orientation: this is most strongly manifested in the R2 peak. The Cr3+ luminescence in these materials provides a sensitive probe of pressure-dependent shifts in the local geometry of the Al-sites in these materials, which are analyzed in the context of previous single-crystal x-ray diffraction measurements.

  16. High-pressure oxygen impact tester

    NASA Technical Reports Server (NTRS)

    Raniere, F. D.; Hood, G. A.; Marker, H. E.

    1972-01-01

    To extend the compatibility evaluation of candidate materials in oxygen, a high-pressure oxygen impact tester has been designed, developed, and installed at NASA/MSFC, Huntsville, Alabama. The tester has an operating range from ambient to 69,000 newton/sq m (10,000 psig) pressures and from the normal boiling point of liquid oxygen to 394 K (121 C) temperatures. The tester was designed to deliver 97.63 joules (72 ft-lb) of impact energy; however, variable height and weight can be achieved for threshold analysis. The system is completely remote and highly automated to furnish safe, reliable operation. High-frequency, fast-response instrumentation capabilities are provided to ensure maximum information output with the hope of minimizing the number of tests required for material acceptance.

  17. Metallic and superconducting gallane under high pressure

    NASA Astrophysics Data System (ADS)

    Gao, Guoying; Wang, Hui; Bergara, Aitor; Li, Yinwei; Liu, Guangtao; Ma, Yanming

    2011-08-01

    Using our newly developed particle swarm optimization algorithm on crystal structural prediction, we characterized the pressure-induced structural transition sequence of gallane (GaH3). As has been observed in alane (AlH3), enthalpy calculations reveal that the Pm3¯n structure of GaH3 becomes stable above 160 GPa, below which it is unstable with respect to elemental decomposition. Interestingly, the Pm3¯n structure is metallic, and the application of the Allen-Dynes modified McMillan equation reveals a high superconducting transition temperature (Tc), which reaches 86 K at 160 GPa and increases with decreasing pressure (Tc = 102 K at 120 GPa). Our band structure calculations demonstrate that GaH3 within the Pm3¯n structure is a highly ionic solid, where the ionicity of H atoms plays an important role in the predicted high temperature superconductivity.

  18. Exotic stable cesium polynitrides at high pressure

    SciTech Connect

    Peng, Feng; Han, Yunxia; Liu, Hanyu; Yao, Yansun

    2015-11-19

    New polynitrides containing metastable forms of nitrogen are actively investigated as potential high energy-density materials. Using a structure search method based on the CALYPSO methodology, we investigated the stable stoichiometries and structures of cesium polynitrides at high pressures. Along with the CsN3, we identified five new stoichiometric compounds (Cs3N, Cs2N, CsN, CsN2, and CsN5) with interesting structures that may be experimentally synthesizable at modest pressures (i.e., less than 50 GPa). Nitrogen species in the predicted structures have various structural forms ranging from single atom (N) to highly endothermic molecules (N2, N3 , N4, N5, N6) and chains (N). Polymeric chains of nitrogen were found in the high-pressure C2/c phase of CsN2. This structure contains a substantially high content of single N-N bonds that exceeds the previously known nitrogen chains in pure forms, and also exhibit metastability at ambient conditions. We also identified a very interesting CsN crystal that contains novel N44- anion. In conclusion, to our best knowledge, this is the first time a charged N4 species being reported. Results of the present study suggest that it is possible to obtain energetic polynitrogens in main-group nitrides under high pressure.

  19. Sleep Deprivation: A Cause of High Blood Pressure?

    MedlinePlus

    ... High blood pressure (hypertension) Is it true that sleep deprivation can cause high blood pressure? Answers from ... be linked to increased blood pressure. People who sleep five hours or less a night may be ...

  20. Picosecond High Pressure Gas Switch experiment

    SciTech Connect

    Cravey, W.R.; Freytag, E.K.; Goerz, D.A.; Poulsen, P.; Pincosy, P.A.

    1993-08-01

    A high Pressure Gas Switch has been developed and tested at LLNL. Risetimes on the order of 200 picoseconds have been observed at 1 kHz prf and 1 atmosphere pressures. Calculations show that switching closure times on the order of tens of picoseconds can be achieved at higher pressures and electric fields. A voltage hold-off of 1 MV/cm has been measured at 10 atmospheres and several MV/cm appears possible with the HPGS. With such high electric field levels, energy storage of tens of Joules in a reasonably sized package is achievable. Initial HPGS performance has been characterized using the WASP pulse generator at LLNL. A detailed description of the switch used for initial testing is given. Switch recovery times of 1-ms have been measured at 1 atmosphere. Data on the switching uniformity, voltage hold-off recovery, and pulse repeatability, is presented. In addition, a physics switch model is described and results are compared with experimental data. Modifications made to the WASP HV pulser in order to drive the HPGS will also be discussed. Recovery times of less than 1 ms were recorded without gas flow in the switch chambers. Low pressure synthetic air was used as the switch dielectric. Longer recovery times were required when it was necessary to over-voltage the switch.

  1. Strain engineered pyrochlore at high pressure

    DOE PAGES

    Rittman, Dylan R.; Turner, Katlyn M.; Park, Sulgiye; ...

    2017-05-22

    Strain engineering is a promising method for next-generation materials processing techniques. Here, we use mechanical milling and annealing followed by compression in diamond anvil cell to tailor the intrinsic and extrinsic strain in pyrochlore, Dy2Ti2O7 and Dy2Zr2O7. Raman spectroscopy, X-ray pair distribution function analysis, and X-ray diffraction were used to characterize atomic order over short-, medium-, and long-range spatial scales, respectively, under ambient conditions. Raman spectroscopy and X-ray diffraction were further employed to interrogate the material in situ at high pressure. High-pressure behavior is found to depend on the species and concentration of defects in the sample at ambient conditions.more » Overall, we show that defects can be engineered to lower the phase transformation onset pressure by ~50% in the ordered pyrochlore Dy2Ti2O7, and lower the phase transformation completion pressure by ~20% in the disordered pyrochlore Dy2Zr2O7. Lastly, these improvements are achieved without significantly sacrificing mechanical integrity, as characterized by bulk modulus.« less

  2. Is sodium a superconductor under high pressure?

    PubMed

    Tutchton, Roxanne; Chen, Xiaojia; Wu, Zhigang

    2017-01-07

    Superconductivity has been predicted or measured for most alkali metals under high pressure, but the computed critical temperature (Tc) of sodium (Na) at the face-centered cubic (fcc) phase is vanishingly low. Here we report a thorough, first-principles investigation of superconductivity in Na under pressures up to 260 GPa, where the metal-to-insulator transition occurs. Linear-response calculations and density functional perturbation theory were employed to evaluate phonon distributions and the electron-phonon coupling for bcc, fcc, cI16, and tI19 Na. Our results indicate that the maximum electron-phonon coupling parameter, λ, is 0.5 for the cI16 phase, corresponding to a theoretical peak in the critical temperature at Tc≈1.2 K. When pressure decreases or increases from 130 GPa, Tc drops quickly. This is mainly due to the lack of p-d hybridization in Na even at 260 GPa. Since current methods based on the Eliashberg and McMillian formalisms tend to overestimate the Tc (especially the peak values) of alkali metals, we conclude that under high pressure-before the metal-to-insulator transition at 260 GPa-superconductivity in Na is very weak, if it is measurable at all.

  3. Nucleation and droplet growth at high pressure

    NASA Astrophysics Data System (ADS)

    Luijten, Carlo Cornelis Maria

    Homogeneous nucleation, the first stage of droplet formation in the absence of foreign particles, usually takes place in the presence of one or more supercritical carrier gases. The present work aimed at a systematic investigation of the effects of carrier gas pressure on nucleation and droplet growth. Using the so-called nucleation pulse method, nucleation and droplet growth can be separated in time, which facilitates quantitative study of these processes using Constant Angle Mie Scattering and light extinction. The method was implemented in a modified shock tube, using gas dynamic principles to create the pulse. In this way, nucleation and growth rates were measured as a function of temperature, pressure, and composition. Composition measurement at high pressure was achieved along two different routes. Water vapour concentrations were determined using a commercial humidity sensor, after calibration with total pressure as an independent parameter. Gas chromatography was used to determine hydrocarbon concentrations, after pressure reduction of the mixture over a thermostatic capillary tube. Using the above analysis techniques, nucleation and droplet growth experiments were performed for several vapour-gas mixtures, at pressures between 1 and 40 bar. Mixtures with a varying degree of interaction were selected, to allow for a systematic investigation of carrier gas influence. Besides these binary mixtures, the first quantitative nucleation and growth rates for- multicomponent-natural gas were obtained. Theoretical models for both nucleation and droplet growth were adapted to take into account the presence of a carrier gas, under condition of small carrier gas solubility. The main effects involved are the increase of saturated vapour density and decrease of surface tension with pressure. On the basis of our experiments, these effects were demonstrated to play important and counteracting roles in high pressure nucleation. Using Density Functional Theory, both effects

  4. High pressure liquid chromatographic gradient mixer

    DOEpatents

    Daughton, Christian G.; Sakaji, Richard H.

    1985-01-01

    A gradient mixer which effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum "band-broadening".

  5. High-pressure liquid chromatographic gradient mixer

    DOEpatents

    Daughton, C.G.; Sakaji, R.H.

    1982-09-08

    A gradient mixer effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum band-broadening.

  6. Water solubility in pyrope at high pressures

    NASA Astrophysics Data System (ADS)

    Mookherjee, M.; Karato, S.-

    2006-12-01

    To address how much water is stored within the Earth's mantle, we need to understand the water solubility in the nominally anhydrous minerals. Much is known about olivine and pyroxene. Garnet is another important component, approaching 40% by volume in the transition zone. Only two studies on water solubility in pyrope at high-pressures exist which contradict each other. Lu and Keppler (1997) observed increase in water solubility in a natural pyrope up to 200 ppm wt of water, till 10 GPa. They concluded that the proton is located in the interstitial site. Withers et al. (1998) on the contrary, observed increasing water content in Mg-rich pyrope till 6 GPa, then sudden decrease of water, beyond detection, at 7 GPa. Based on infrared spectra, Withers et al. (1998), concluded hydrogarnet (Si^{4+} replaced by 4H+ to form O4H4) substitution in synthetic magnesium rich pyrope. They argued that at high pressure owing to larger volume, hydrogarnet substitution is unstable and water is expelled out of garnet. In transition zone conditions, however, majorite garnet seems to contain around 600-700 ppm wt of water (Bolfan-Casanova et al. 2000; Katayama et al. 2003). The cause for such discrepancy is not clear and whether garnet could store a significant amount of water at mantle condition is unconstrained. In order to understand the solubility mechanism of water in pyrope at high-pressure, we have conducted high- pressure experiments on naturally occurring single crystals of pyrope garnet (from Arizona, Aines and Rossman, 1984). To ascertain water-saturated conditions, we use olivine single-crystal as an internal standard. Preliminary results indicate that natural pyrope is capable of dissolving water at high-pressures, however, water preferentially enters olivine than in pyrope. We are undertaking systematic study to estimate the solubility of water in pyrope as a function of pressure. This will enable us to develop solubility models to understand the defect mechanisms

  7. High-pressure structures of yttrium hydrides

    DOE PAGES

    Liu, Lu -Lu; Sun, Hui -Juan; Wang, C. Z.; ...

    2017-07-14

    In this study, the crystal structures of YH3 and YH4 at high pressure (100–250 GPa) have been explored using a genetic algorithm combined with first-principles calculations. New structures of YH3 with space group symmetries of P21/m and I4/mmm were predicted. The electronic structures and the phonon dispersion properties of various YH3 and YH4 structures at different temperatures and pressures were investigated. Among YH3 phases, the P21/m structure of YH3 was found to have a relatively high superconducting transformation temperature T c of 19 K at 120 GPa, which is reduced to 9 K at 200 GPa. Other YH3 structures havemore » much lower T cs. Compared with YH3, the T c of the YH4 compound is much higher, i.e. 94 K at 120 GPa and 55 K at 200 GPa.« less

  8. Novel chemistry of matter under high pressure

    NASA Astrophysics Data System (ADS)

    Miao, Maosheng

    2015-03-01

    The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry, rooted in the atomic shell structure. Within compounds, Group I elements, for example, invariably assume the +1 oxidation state, and their chemical properties differ completely from those of the p-block elements. These general rules govern our understanding of chemical structures and reactions. Using first principles calculations, we demonstrate that under high pressure, the above doctrines can be broken. We show that both the inner shell electrons and the outer shell empty orbitals of Cs and other elements can involve in chemical reactions. Furthermore, we show that the quantized orbitals of the enclosed interstitial space may play the same role as atomic orbitals, an unprecedented view that led us to a unified theory for the recently observed high-pressure electride phenomenon.

  9. Cavity closure arrangement for high pressure vessels

    DOEpatents

    Amtmann, Hans H.

    1981-01-01

    A closure arrangement for a pressure vessel such as the pressure vessel of a high temperature gas-cooled reactor wherein a liner is disposed within a cavity penetration in the reactor vessel and defines an access opening therein. A closure is adapted for sealing relation with an annular mounting flange formed on the penetration liner and has a plurality of radially movable locking blocks thereon having outer serrations adapted for releasable interlocking engagement with serrations formed internally of the upper end of the penetration liner so as to effect high strength closure hold-down. In one embodiment, ramping surfaces are formed on the locking block serrations to bias the closure into sealed relation with the mounting flange when the locking blocks are actuated to locking positions.

  10. High pressure injection injuries: an overview.

    PubMed

    Fialkov, J A; Freiberg, A

    1991-01-01

    Injuries resulting from the use of high pressure injectors and spray guns are relatively rare; however, the potential tissue damage caused by the injury as well as the extent of the injury itself may go unrecognized by the primary physician. The purpose of this paper is to inform the emergency physician of the nature and standard management of this type of injury. A basic understanding of the pathophysiology of the high pressure injection injury (HPII) is essential in avoiding the mistakes in management that have been reported in the literature. The emergency management of the HPII includes: evaluation and immobilization, tetanus and antimicrobial prophylaxis, supportive and resuscitative measures, analgesia, and minimizing the time to definitive surgical treatment.

  11. Diagnostics of a High Pressure Helium Microplasma

    NASA Astrophysics Data System (ADS)

    Wang, Qiang; Koleva, Ivanka; Economou, Demetre; Donnelly, Vincent

    2004-09-01

    Gas and plasma diagnostics were performed in a slot-type DC microplasma (200 microns gap) discharge at high pressures. The gas temperature in a helium discharge was estimated by adding small quantities of nitrogen (<100 ppm) into the gas feed. Specific rotational bands of the N2 second positive system were carefully selected to avoid interference with emission from He atoms and He2 excimer. At 250 Torr pressure and 200 mA/cm2 current density, the gas temperature was Tg = 350 +/- 25 K. The measured gas temperature was almost independent (to within experimental uncertainty) of pressure (in the range of 150 Torr - 600 Torr), and current density (in the range of 100 mA/cm2 - 400 mA/cm2). These measurements were consistent with a simple heat transfer model. Spatially resolved measurements of electron temperature were also performed using trace rare gas optical emission actinometry (TRG-OES). These measurements are greatly complicated by collisional quenching at the high operating pressures. Electron density and electron temperature profiles was deduced by comparing emission intensities from the Paschen 2px (x = 1-10) manifold of Ne, Ar, Kr and Xe trace gases. Results suggested that the electron temperature peaks in the cathode sheath region, while the plasma density peaks away from the cathode sheath. A self-consistent fluid model of a DC helium microdischarge was in agreement with the experimental data. The model was used to study the dependence of discharge characteristics on operating conditions (pressure, gap spacing, current density, etc.).

  12. Small, high pressure liquid hydrogen turbopump

    NASA Technical Reports Server (NTRS)

    Csomor, A.; Warren, D. J.

    1980-01-01

    A high pressure, low capacity, liquid hydrogen turbopump was designed, fabricated, and tested. The design configuration of the turbopump is summarized and the results of the analytical and test efforts are presented. Approaches used to pin point the cause of poor suction performance with the original design are described and performance data are included with an axial inlet design which results in excellent suction capability.

  13. Modeling High Pressure Micro Hollow Cathode Discharges

    DTIC Science & Technology

    2007-11-02

    calculations in glow discharge in argon and neon . A Monte Carlo simulation of the ions and Grant 033083 – Final report 7 the fast neutrals generated...in high pressure xenon or in rare gas mixtures containing xenon are of interest in the context of UV and VUV generation. Numerical experiments on...The shape of the calculated characteristic is similar to those measured by Schoenbach et al1 in argon and by Moselhy and Schoenbach9 in xenon . There

  14. High pressure hydrogen time projection chamber

    SciTech Connect

    Goulianos, K.

    1983-01-01

    We describe a high pressure hydrogen gas time projection chamber which consists of two cylindrical drift regions each 45 cm in diameter and 75 cm long. Typically, at 15 atm of H/sub 2/ with 2 kV/cm drift field and 7 kV on the 35..mu.. sense wires, the drift velocity is about 0.5 cm/..mu..sec and the spatial resolution +-200..mu...

  15. Amorphization of Serpentine at High Pressure and High Temperature

    PubMed

    Irifune; Kuroda; Funamori; Uchida; Yagi; Inoue; Miyajima

    1996-06-07

    Pressure-induced amorphization of serpentine was observed at temperatures of 200° to 300°C and pressures of 14 to 27 gigapascals with a combination of a multianvil apparatus and synchrotron radiation. High-pressure phases then crystallized rapidly when the temperature was increased to 400°C. These results suggest that amorphization of serpentine is an unlikely mechanism for generating deep-focus earthquakes, as the temperatures of subducting slabs are significantly higher than those of the rapid crystallization regime.

  16. Structures of xenon oxides at high pressures

    NASA Astrophysics Data System (ADS)

    Worth, Nicholas; Pickard, Chris; Needs, Richard; Dewaele, Agnes; Loubeyre, Paul; Mezouar, Mohamed

    2014-03-01

    For many years, it was believed that noble gases such as xenon were entirely inert. It was only in 1962 that Bartlett first synthesized a compound of xenon. Since then, a number of other xenon compounds, including oxides, have been synthesized. Xenon oxides are unstable under ambient conditions but have been predicted to stabilize under high pressure. Here we present the results of a combined theoretical and experimental study of xenon oxides at pressures of 80-100 GPa. We have synthesized new xenon oxides at these pressures and they have been characterized with X-ray diffraction and Raman spectroscopy. Calculations were performed with a density-functional theory framework. We have used the ab-initio random structure searching (AIRSS) method together with a data-mining technique to determine the stable compounds in the xenon-oxygen system in this pressure range. We have calculated structural and optical properties of these phases, and a good match between theoretical and experimental results has been obtained. Funding for computational research provided by the engineering and physical sciences research council (EPSRC; UK). Computing resources provided by Cambridge HPC and HECToR. X-ray diffraction experiments performed at ESRF.

  17. 7 CFR 58.219 - High pressure pumps and lines.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false High pressure pumps and lines. 58.219 Section 58.219....219 High pressure pumps and lines. High pressure lines may be cleaned-in-place and shall be of such construction that dead ends, valves and the high pressure pumps can be disassembled for hand cleaning. The...

  18. 7 CFR 58.219 - High pressure pumps and lines.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 3 2013-01-01 2013-01-01 false High pressure pumps and lines. 58.219 Section 58.219....219 High pressure pumps and lines. High pressure lines may be cleaned-in-place and shall be of such construction that dead ends, valves and the high pressure pumps can be disassembled for hand cleaning. The...

  19. Microcolumn sorption of antimony(III) chelate for antimony speciation studies

    NASA Astrophysics Data System (ADS)

    Garboś, Sławomir; Rzepecka, Monika; Bulska, Ewa; Hulanicki, Adam

    1999-05-01

    Selective sorption of the Sb(III) chelate with ammonium pyrrolidine dithiocarbamate (APDC) on a microcolumn packed with C 16-bonded silica gel phase was used for the determination of Sb(III) and of total inorganic antimony after reducing Sb(V) to Sb(III) by L-cysteine. A flow injection system composed of a microcolumn connected to the tip of the autosampler was used for preconcentration. The sorbed antimony was directly eluted with ethanol into the graphite furnace and determined by AAS. The detection limit for antimony was significantly lowered to 0.007 μg l -1 in comparison to 1.7 μg l -1 for direct injection GFAAS. This procedure was applied for speciation determinations of inorganic antimony in tap water, snow and urine samples. For the investigation of long-term stability of antimony species a flow injection hydride generation atomic absorption spectrometry with quartz tube atomization (FI HG QT AAS) and GFAAS were used for selective determination of Sb(III) in the presence of Sb(V) and total content of antimony, respectively. Investigations on the stability of antimony in several natural samples spiked with Sb(III) and Sb(V) indicated instability of Sb(III) in tap water and satisfactory stability of inorganic Sb species in the presence of urine matrix.

  20. Characterization of adsorption of aqueous arsenite and arsenate onto charred dolomite in microcolumn systems.

    PubMed

    Salameh, Yousef; Al-Muhtaseb, Ala'a H; Mousa, Hasan; Walker, Gavin M; Ahmad, Mohammad N M

    2014-01-01

    In this work, the removal of arsenite, As(III), and arsenate, As(V), from aqueous solutions onto thermally processed dolomite (charred dolomite) via microcolumn was evaluated. The effects of mass of adsorbent (0.5-2 g), initial arsenic concentration (50-2000 ppb) and particle size (<0.355-2 mm) on the adsorption capacity of charred dolomite in a microcolumn were investigated. It was found that the adsorption of As(V) and As(III) onto charred dolomite exhibited a characteristic 'S' shape. The adsorption capacity increased as the initial arsenic concentration increased. A slow decrease in the column adsorption capacity was noted as the particle size increased from>0.335 to 0.710-2.00 mm. For the binary system, the experimental data show that the adsorption of As(V) and As(III) was independent of both ions in solution. The experimental data obtained from the adsorption process were successfully correlated with the Thomas Model and Bed Depth Service Time Model.

  1. Engine having a high pressure hydraulic system and low pressure lubricating system

    DOEpatents

    Bartley, Bradley E.; Blass, James R.; Gibson, Dennis H.

    2000-01-01

    An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

  2. Sulfidation kinetics of dolomite at high pressure and high temperature

    SciTech Connect

    Misro, S.K.; Jadhav, R.; Gupta, H.; Agnihotri, R.; Chauk, S.; Fan, L.S.

    1999-07-01

    Kinetic studies of the dolomite sulfidation reaction are carried out at high pressure (15 atm) and high temperature (600--900 C) in a differential bed flow-through reactor. The dolomite particles are exposed to simulated coal gas environments and the extent of conversion determined. Experiments are carried out to determine the influence of total pressure, reaction temperature and partial pressure of H{sub 2}S on the extent of fully calcined dolomite (FCD) sulfidation. Based on the grain theory it is found that towards the later stages of the reaction the FCD sulfidation is product layer diffusion controlled. The reaction is found to be first order with respect to H{sub 2}S partial pressure. A low apparent activation energy of 4.6 kcal/gmol for the product layer diffusion controlled reaction is attributed to the presence of porous MgO along with the low porosity CaS product layer. A comparison of the performance of dolomite and limestone as sorbents for desulfurization shows that dolomite is a better sorbent with higher conversions even at higher CO{sub 2} partial pressures. The high pressure sulfidation kinetic data obtained in this study would be useful in understanding and optimizing the in-gasifier H{sub 2}S capture using dolomite sorbents.

  3. Very high-pressure orogenic garnet peridotites

    PubMed Central

    Liou, J. G.; Zhang, R. Y.; Ernst, W. G.

    2007-01-01

    Mantle-derived garnet peridotites are a minor component in many very high-pressure metamorphic terranes that formed during continental subduction and collision. Some of these mantle rocks contain trace amounts of zircon and micrometer-sized inclusions. The constituent minerals exhibit pre- and postsubduction microstructures, including polymorphic transformation and mineral exsolution. Experimental, mineralogical, petrochemical, and geochronological characterizations using novel techniques with high spatial, temporal, and energy resolutions are resulting in unexpected discoveries of new phases, providing better constraints on deep mantle processes. PMID:17519341

  4. A high frequency silicon pressure sensor

    NASA Technical Reports Server (NTRS)

    Kahng, S. K.; Gross, C.

    1980-01-01

    Theoretical and design considerations as well as fabrication and experimental work involved in the development of high-frequency silicon pressure sensors with an ultra-small diaphragm are discussed. A sensor is presented with a rectangular diaphragm of 0.0127 cm x 0.0254 cm x 1.06 micron; the sensor has a natural frequency of 625 kHz and a sensitivity of 0.82 mv/v-psi. High-frequency results from shock tube testing and low-frequency (less than 50 kHz) comparison with microphones are given.

  5. Dissociation of methane under high pressure.

    PubMed

    Gao, Guoying; Oganov, Artem R; Ma, Yanming; Wang, Hui; Li, Peifang; Li, Yinwei; Iitaka, Toshiaki; Zou, Guangtian

    2010-10-14

    Methane is an extremely important energy source with a great abundance in nature and plays a significant role in planetary physics, being one of the major constituents of giant planets Uranus and Neptune. The stable crystal forms of methane under extreme conditions are of great fundamental interest. Using the ab initio evolutionary algorithm for crystal structure prediction, we found three novel insulating molecular structures with P2(1)2(1)2(1), Pnma, and Cmcm space groups. Remarkably, under high pressure, methane becomes unstable and dissociates into ethane (C(2)H(6)) at 95 GPa, butane (C(4)H(10)) at 158 GPa, and further, carbon (diamond) and hydrogen above 287 GPa at zero temperature. We have computed the pressure-temperature phase diagram, which sheds light into the seemingly conflicting observations of the unusually low formation pressure of diamond at high temperature and the failure of experimental observation of dissociation at room temperature. Our results support the idea of diamond formation in the interiors of giant planets such as Neptune.

  6. High-Pressure Trocar Insertion Technique

    PubMed Central

    Reich, Harry; Conti Ribeiro, Sergio; Rasmussen, Carsten; Rosenberg, Jay

    1999-01-01

    Background: The majority of laparoscopic complications occur at the time of Veress needle and trocar insertion. Although not very frequent, they increase the morbidity and mortality of both diagnostic and operative laparoscopic procedures. Alternative techniques of trocar insertion have been described but have not completely eliminated the risk of injury. Technique: After Veress needle insertion and establishment of pneumoperitoneum to 25 to 30 mm Hg, insertion of a short trocar is performed in the deepest part of the umbilicus without elevation of the anterior abdominal wall. The result is a parietal peritoneal puncture directly beneath the umbilicus. The high-pressure setting used during initial insertion of the trocar is lowered as soon as safe abdominal entry is documented. Experience: The trocar insertion technique described above was performed in 3041 procedures. No vascular injury occurred. There were two bowel perforations. No complications related to the increased intra-abdominal pressure were observed. Conclusion: The high-pressure abdominal entry technique has the advantage of reducing intra-abdominal trocar-related injuries without requiring additional instrumentation or additional training. PMID:10323169

  7. Dietary spermidine for lowering high blood pressure

    PubMed Central

    Zimmermann, Andreas; Schroeder, Sabrina; Pendl, Tobias; Harger, Alexandra; Stekovic, Slaven; Schipke, Julia; Magnes, Christoph; Schmidt, Albrecht; Ruckenstuhl, Christoph; Dammbrueck, Christopher; Gross, Angelina S; Herbst, Viktoria; Carmona-Gutierrez, Didac; Pietrocola, Federico; Pieber, Thomas R; Sigrist, Stephan J; Linke, Wolfgang A; Mühlfeld, Christian; Sadoshima, Junichi; Dengjel, Joern; Kiechl, Stefan; Kroemer, Guido; Sedej, Simon; Madeo, Frank

    2017-01-01

    Loss of cardiac macroautophagy/autophagy impairs heart function, and evidence accumulates that an increased autophagic flux may protect against cardiovascular disease. We therefore tested the protective capacity of the natural autophagy inducer spermidine in animal models of aging and hypertension, which both represent major risk factors for the development of cardiovascular disease. Dietary spermidine elicits cardioprotective effects in aged mice through enhancing cardiac autophagy and mitophagy. In salt-sensitive rats, spermidine supplementation also delays the development of hypertensive heart disease, coinciding with reduced arterial blood pressure. The high blood pressure-lowering effect likely results from improved global arginine bioavailability and protection from hypertension-associated renal damage. The polyamine spermidine is naturally present in human diets, though to a varying amount depending on food type and preparation. In humans, high dietary spermidine intake correlates with reduced blood pressure and decreased risk of cardiovascular disease and related death. Altogether, spermidine represents a cardio- and vascular-protective autophagy inducer that can be readily integrated in common diets. PMID:28118075

  8. Establishment of an Australian high pressure standard

    NASA Astrophysics Data System (ADS)

    Man, J. K. L.

    2005-12-01

    A controlled-clearance pressure standard has been established at the National Measurement Institute of Australia as a high pressure standard for the realization of the national scale up to 200 MPa. The area of the piston was determined by comparison with a 25 mm diameter piston cylinder assembly that was measured dimensionally and the distortion coefficient was found by calculation and experiment. The controlled-clearance piston gauge was used to calibrate a 100 MPa piston cylinder unit with results agreed to 10 × 10-6 with calibration done at LNE. This 100 MPa unit was used in a regional key comparison with agreement to within 20 × 10-6 of the reference value.

  9. High stored energy of metallic glasses induced by high pressure

    NASA Astrophysics Data System (ADS)

    Wang, C.; Yang, Z. Z.; Ma, T.; Sun, Y. T.; Yin, Y. Y.; Gong, Y.; Gu, L.; Wen, P.; Zhu, P. W.; Long, Y. W.; Yu, X. H.; Jin, C. Q.; Wang, W. H.; Bai, H. Y.

    2017-03-01

    Modulating energy states of metallic glasses (MGs) is significant in understanding the nature of glasses and controlling their properties. In this study, we show that high stored energy can be achieved and preserved in bulk MGs by high pressure (HP) annealing, which is a controllable method to continuously alter the energy states of MGs. Contrary to the decrease in enthalpy by conventional annealing at ambient pressure, high stored energy can occur and be enhanced by increasing both annealing temperature and pressure. By using double aberration corrected scanning transmission electron microscopy, it is revealed that the preserved high energy, which is attributed to the coupling effect of high pressure and high temperature, originates from the microstructural change that involves "negative flow units" with a higher atomic packing density compared to that of the elastic matrix of MGs. The results demonstrate that HP-annealing is an effective way to activate MGs into higher energy states, and it may assist in understanding the microstructural origin of high energy states in MGs.

  10. Filament wound pressure vessels - Effects of using liner tooling of low pressure vessels for high pressure vessels development

    NASA Astrophysics Data System (ADS)

    Lal, Krishna M.

    High performance pressure vessels have been recently demanded for aerospace and defense applications. Filament wound pressure vessels consist of a metallic thin liner, which also acts as a mandrel, and composite/epoxy overwrap. Graphite/epoxy overwrapped vessels have been developed to obtain the performance ratio, PV/W, as high as one million inches. Under very high pressure the isotropic metallic liner deforms elasto-plastically, and orthotropic composite fibers deform elastically. Sometimes, for the development of ultra high pressure vessels, composite pressure vessels industry uses the existing liner tooling developed for low burst pressure capacity composite vessels. This work presents the effects of various design variables including the low pressure liner tooling for the development of the high burst pressure capacity Brilliant Pebbles helium tanks. Advance stress analysis and development of an ultra high pressure helium tank.

  11. Nonicosahedral boron allotrope synthesized at high pressure and high temperature

    NASA Astrophysics Data System (ADS)

    Chuvashova, Irina; Bykova, Elena; Bykov, Maxim; Prakapenka, Vitali; Glazyrin, Konstantin; Mezouar, Mohamed; Dubrovinsky, Leonid; Dubrovinskaia, Natalia

    2017-05-01

    Theoretical predictions of pressure-induced phase transformations often become long-standing enigmas because of limitations of contemporary available experimental possibilities. Hitherto the existence of a nonicosahedral boron allotrope has been one of them. Here we report on a nonicosahedral boron allotrope, which we denoted as ζ -B, with the orthorhombic α -Ga-type structure (space group Cmce) synthesized in a diamond-anvil cell at extreme high-pressure high-temperature conditions (115 GPa and 2100 K). The structure of ζ -B was solved using single-crystal synchrotron x-ray diffraction and its compressional behavior was studied in the range of very high pressures (115-135 GPa). Experimental validation of theoretical predictions reveals the degree of our up-to-date comprehension of condensed matter and promotes further development of solid-state physics and chemistry.

  12. Highly Loaded Low Pressure Turbine (LPT)

    NASA Technical Reports Server (NTRS)

    Ortiz, Milt; Dalsania, Vithal

    2001-01-01

    The goal of this study is to evaluate aspirated and non-aspirated aerodynamics on highly loaded LPT design. The objective is to increase stage loading by 30 to 50 percent without loss of efficiency for an existing low pressure turbine design. A study conducted on a NASA highly loaded multistage fan drive turbine (NASA CR-1964) indicated that end-wall bleed at the hub is a more significant parameter compared to aspirated airfoil. Based on this study, a 3-stage LPT is redesigned to 2-stage LIT with and without end-wall bleed. Both aerodynamic design and mechanical design are completed. In addition to end-wall bleed, exit guide vanes are designed with aspirated airfoils to reduce the losses. The LPT is redesigned with all constraints necessary for practical application. The benefit of the high-performance, highly loaded LPT shows up in reduced stage and part count, reduced size and weight, and reduced cost.

  13. 30 CFR 57.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false High-pressure hose connections. 57.13021... Air and Boilers § 57.13021 High-pressure hose connections. Except where automatic shutoff valves are...-pressure hose lines of 3/4-inch inside diameter or larger, and between high-pressure hose lines of...

  14. 30 CFR 57.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false High-pressure hose connections. 57.13021... Air and Boilers § 57.13021 High-pressure hose connections. Except where automatic shutoff valves are...-pressure hose lines of 3/4-inch inside diameter or larger, and between high-pressure hose lines of...

  15. 30 CFR 57.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false High-pressure hose connections. 57.13021... Air and Boilers § 57.13021 High-pressure hose connections. Except where automatic shutoff valves are...-pressure hose lines of 3/4-inch inside diameter or larger, and between high-pressure hose lines of...

  16. 30 CFR 57.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false High-pressure hose connections. 57.13021... Air and Boilers § 57.13021 High-pressure hose connections. Except where automatic shutoff valves are...-pressure hose lines of 3/4-inch inside diameter or larger, and between high-pressure hose lines of...

  17. 30 CFR 57.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false High-pressure hose connections. 57.13021... Air and Boilers § 57.13021 High-pressure hose connections. Except where automatic shutoff valves are...-pressure hose lines of 3/4-inch inside diameter or larger, and between high-pressure hose lines of...

  18. 7 CFR 58.219 - High pressure pumps and lines.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... pressure pump shall comply with the 3-A Sanitary Standard for Homogenizers and Pumps of the Plunger Type. ... 7 Agriculture 3 2011-01-01 2011-01-01 false High pressure pumps and lines. 58.219 Section 58.219....219 High pressure pumps and lines. High pressure lines may be cleaned-in-place and shall be of...

  19. 7 CFR 58.219 - High pressure pumps and lines.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... pressure pump shall comply with the 3-A Sanitary Standard for Homogenizers and Pumps of the Plunger Type. ... 7 Agriculture 3 2014-01-01 2014-01-01 false High pressure pumps and lines. 58.219 Section 58.219....219 High pressure pumps and lines. High pressure lines may be cleaned-in-place and shall be of...

  20. 7 CFR 58.219 - High pressure pumps and lines.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... pressure pump shall comply with the 3-A Sanitary Standard for Homogenizers and Pumps of the Plunger Type. ... 7 Agriculture 3 2012-01-01 2012-01-01 false High pressure pumps and lines. 58.219 Section 58.219....219 High pressure pumps and lines. High pressure lines may be cleaned-in-place and shall be of...

  1. High Pressure Microwave Powered UV Light Sources

    NASA Astrophysics Data System (ADS)

    Cekic, M.; Frank, J. D.; Popovic, S.; Wood, C. H.

    1997-10-01

    Industrial microwave powered (*electrodeless*) light sources have been limited to quiescent pressures of 300 Torr of buffer gas and metal- halide fills. Recently developed multi-atmospheric electronegative bu lb fills (noble gas-halide excimers, metal halide) require electric field s for ionization that are often large multiples of the breakdown voltage for air. For these fills an auxiliary ignition system is necessary. The most successful scheme utilizes a high voltage pulse power supply and a novel field emission source. Acting together they create localized condition of pressure reduction and high free electron density. This allows the normal microwave fields to drive this small region into avalanche, ignite the bulb, and heat the plasma to it's operating poin t Standard diagnostic techniques of high density discharges are inapplicable to the excimer bulbs, because of the ionic molecular exci ted state structure and absence of self-absorption. The method for temperature determination is based on the equilibrium population of certain vibrational levels of excimer ionic excited states. Electron d ensity was determined from the measurements of Stark profiles of H_β radiation from a small amount of hydrogen mixed with noble gas and halogens. At the present time, high pressure (Te 0.5eV, ne 3 x 10^17 cm-3) production bulbs produce over 900W of radiation in a 30nm band, centered at 30nm. Similarly, these prototypes when loaded with metal-halide bulb fills produce 1 kW of radiation in 30nm wide bands, centered about the wavelength of interest.

  2. Menopause and High Blood Pressure: What's the Connection?

    MedlinePlus

    ... blood pressure (hypertension) Is there a connection between menopause and high blood pressure? Answers from Shannon K. ... Tommaso, M.D. Blood pressure generally increases after menopause. Some doctors think this increase suggests that hormonal ...

  3. LHDAC setup for high temperature and high pressure studies

    SciTech Connect

    Patel, Nishant N. Meenakshi, S. Sharma, Surinder M.

    2014-04-24

    A ytterbium fibre laser (λ = 1.07 μm) based laser heated diamond anvil cell (LHDAC) facility has been recently set up at HP and SRPD, BARC for simultaneous high temperature and high pressure investigation of material properties. Synthesis of GaN was carried out at pressure of ∼9 GPa and temperature of ∼1925 K in a Mao-Bell type diamond anvil cell (DAC) using the LHDAC facility. The retrieved sample has been characterized using our laboratory based micro Raman setup.

  4. 49 CFR 192.621 - Maximum allowable operating pressure: High-pressure distribution systems.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Maximum allowable operating pressure: High-pressure distribution systems. 192.621 Section 192.621 Transportation Other Regulations Relating to... STANDARDS Operations § 192.621 Maximum allowable operating pressure: High-pressure distribution systems....

  5. 49 CFR 192.621 - Maximum allowable operating pressure: High-pressure distribution systems.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... STANDARDS Operations § 192.621 Maximum allowable operating pressure: High-pressure distribution systems. (a) No person may operate a segment of a high pressure distribution system at a pressure that exceeds the... segment of a distribution system otherwise designed to operate at over 60 p.s.i. (414 kPa) gage, unless...

  6. High pressure phase transitions in lawsonite at simultaneous high pressure and temperature: A single crystal study

    NASA Astrophysics Data System (ADS)

    O'Bannon, E. F., III; Vennari, C.; Beavers, C. C. G.; Williams, Q. C.

    2015-12-01

    Lawsonite (CaAl2Si2O7(OH)2.H2O) is a hydrous mineral with a high overall water content of ~11.5 wt.%. It is a significant carrier of water in subduction zones to depths greater than ~150 km. The structure of lawsonite has been extensively studied under room temperature, high-pressure conditions. However, simultaneous high-pressure and high-temperature experiments are scarce. We have conducted synchrotron-based simultaneous high-pressure and temperature single crystal experiments on lawsonite up to a maximum pressure of 8.4 GPa at ambient and high temperatures. We used a natural sample of lawsonite from Valley Ford, California (Sonoma County). At room pressure and temperature lawsonite crystallizes in the orthorhombic system with Cmcm symmetry. Room temperature compression indicates that lawsonite remains in the orthorhombic Cmcm space group up to ~9.0 GPa. Our 5.0 GPa crystal structure is similar to the room pressure structure, and shows almost isotropic compression of the crystallographic axes. Unit cell parameters at 5.0 GPa are a- 5.7835(10), b- 8.694(2), and c- 13.009(3). Single-crystal measurements at simultaneous high-pressure and temperature (e.g., >8.0 GPa and ~100 oC) can be indexed to a monoclinic P-centered unit cell. Interestingly, a modest temperature increase of ~100 oC appears to initiate the orthorhombic to monoclinic phase transition at ~0.6-2.4 GPa lower than room temperature compression studies have shown. There is no evidence of dehydration or H atom disorder under these conditions. This suggests that the orthorhombic to monoclinic transition could be kinetically impeded at 298 K, and that monoclinic lawsonite could be the dominant water carrier through much of the depth range of upper mantle subduction processes.

  7. High-pressure promoted combustion chamber

    NASA Technical Reports Server (NTRS)

    Rucker, Michelle A. (Inventor); Stoltzfus, Joel M. (Inventor)

    1991-01-01

    In the preferred embodiment of the promoted combusiton chamber disclosed herein, a thick-walled tubular body that is capable of withstanding extreme pressures is arranged with removable upper and lower end closures to provide access to the chamber for dependently supporting a test sample of a material being evaluated in the chamber. To facilitate the real-time analysis of a test sample, several pressure-tight viewing ports capable of withstanding the simulated environmental conditions are arranged in the walls of the tubular body for observing the test sample during the course of the test. A replaceable heat-resistant tubular member and replaceable flame-resistant internal liners are arranged to be fitted inside of the chamber for protecting the interior wall surfaces of the combustion chamber during the evaluation tests. Inlet and outlet ports are provided for admitting high-pressure gases into the chamber as needed for performing dynamic analyses of the test sample during the course of an evaluation test.

  8. High-pressure Raman study of Terephthalonitrile

    NASA Astrophysics Data System (ADS)

    Li, DongFei; Zhang, KeWei; Song, MingXing; Zhai, NaiCui; Sun, ChengLin; Li, HaiBo

    2017-02-01

    The in situ high-pressure Raman spectra of Terephthalonitrile (TPN) have been investigated from ambient to 12.6 GPa at room temperature. All the fundamental vibrational modes of TPN at ambient were assigned based on the first-principle calculations. A detailed Raman spectroscopy analysis revealed that TPN underwent a phase transition at 5.3 GPa. The frequencies of the TPN Raman peaks increase with increasing the pressure which can be attributed to the reduction in the interatomic distances and the escalation of effective force constants. The intensity of the C-C-C ring-out-plane deformation mode increases gradually as the frequency remains almost constant during the compression which can be explained by the existence of π-π interactions in TPN molecules. Additionally, the pressure-induced structural changes of TPN on the Fermi resonance between the C ≡ N out-of-plane vibration mode and the C - CN out-of-plane vibration mode have been analyzed.

  9. High-pressure transformations in xenon hydrates

    PubMed Central

    Sanloup, Chrystèle; Mao, Ho-kwang; Hemley, Russell J.

    2002-01-01

    A high-pressure investigation of the Xe⋅H2O chemical system was conducted by using diamond-anvil cell techniques combined with in situ Raman spectroscopy, synchrotron x-ray diffraction, and laser heating. Structure I xenon clathrate was observed to be stable up to 1.8 GPa, at which pressure it transforms to a new Xe clathrate phase stable up to 2.5 GPa before breaking down to ice VII plus solid xenon. The bulk modulus and structure of both phases were determined: 9 ± 1 GPa for Xe clathrate A with structure I (cubic, a = 11.595 ± 0.003 Å, V = 1,558.9 ± 1.2 Å3 at 1.1 GPa) and 45 ± 5 GPa for Xe clathrate B (tetragonal, a = 8.320 ± 0.004 Å, c = 10.287 ± 0.007 Å, V = 712.1 ± 1.2 Å3 at 2.2 GPa). The extended pressure stability field of Xe clathrate structure I (A) and the discovery of a second Xe clathrate (B) above 1.8 GPa have implications for xenon in terrestrial and planetary interiors. PMID:11756690

  10. High blood pressure in children and adolescents.

    PubMed

    Riley, Margaret; Bluhm, Brian

    2012-04-01

    High blood pressure in children and adolescents is a growing health problem that is often overlooked by physicians. Normal blood pressure values for children and adolescents are based on age, sex, and height, and are available in standardized tables. Prehypertension is defined as a blood pressure in at least the 90th percentile, but less than the 95th percentile, for age, sex, and height, or a measurement of 120/80 mm Hg or greater. Hypertension is defined as blood pressure in the 95th percentile or greater. A secondary etiology of hypertension is much more likely in children than in adults, with renal parenchymal disease and renovascular disease being the most common. Overweight and obesity are strongly correlated with primary hypertension in children. A history and physical examination are needed for all children with newly diagnosed hypertension to help rule out underlying medical disorders. Children with hypertension should also be screened for other risk factors for cardiovascular disease, including diabetes mellitus and hyperlipidemia, and should be evaluated for target organ damage with a retinal examination and echocardiography. Hypertension in children is treated with lifestyle changes, including weight loss for those who are overweight or obese; a healthy, low-sodium diet; regular physical activity; and avoidance of tobacco and alcohol. Children with symptomatic hypertension, secondary hypertension, target organ damage, diabetes, or persistent hypertension despite nonpharmacologic measures should be treated with antihypertensive medications. Thiazide diuretics, angiotensin-converting enzyme inhibitors, angiotensin II receptor blockers, beta blockers, and calcium channel blockers are safe, effective, and well tolerated in children.

  11. Conformable pressure vessel for high pressure gas storage

    DOEpatents

    Simmons, Kevin L.; Johnson, Kenneth I.; Lavender, Curt A.; Newhouse, Norman L.; Yeggy, Brian C.

    2016-01-12

    A non-cylindrical pressure vessel storage tank is disclosed. The storage tank includes an internal structure. The internal structure is coupled to at least one wall of the storage tank. The internal structure shapes and internally supports the storage tank. The pressure vessel storage tank has a conformability of about 0.8 to about 1.0. The internal structure can be, but is not limited to, a Schwarz-P structure, an egg-crate shaped structure, or carbon fiber ligament structure.

  12. HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT

    SciTech Connect

    Chris Guenther, Ph.D.

    2003-01-28

    SRI has completed the NBFZ test program, made modification to the experimental furnace for the HPBO test. The NBFZ datasets provide the information NEA needs to simulate the combustion and fuel-N conversion with detailed chemical reaction mechanisms. BU has determined a linear swell of 1.55 corresponding to a volumetric increase of a factor of 3.7 and a decrease in char density by the same factor. These results are highly significant, and indicate significantly faster burnout at elevated pressure due to the low char density and large diameter.

  13. High-Pressure Oxygen Test Evaluations

    NASA Technical Reports Server (NTRS)

    Schwinghamer, R. J.; Key, C. F.

    1974-01-01

    The relevance of impact sensitivity testing to the development of the space shuttle main engine is discussed in the light of the special requirements for the engine. The background and history of the evolution of liquid and gaseous oxygen testing techniques and philosophy is discussed also. The parameters critical to reliable testing are treated in considerable detail, and test apparatus and procedures are described and discussed. Materials threshold sensitivity determination procedures are considered and a decision logic diagram for sensitivity threshold determination was plotted. Finally, high-pressure materials sensitivity test data are given for selected metallic and nonmetallic materials.

  14. Purification using high pressure molten aluminum

    NASA Astrophysics Data System (ADS)

    Sample, Vivek M.; Cassada, William A.

    A novel technique has been developed to separate eutectic forming elements using a continuous supply of high pressure molten aluminum. In this continuous process, enriched liquid in the mushy zone is selectively expelled from the solidifying mold through a permeable membrane. The fraction of expelled liquid and the level of purification attained can be controlled in real time. Applications of this technique for refining smelter grade aluminum as well as recycling aluminum scrap are being explored. Unique aspects and advantages of the process will be discussed.

  15. A picosecond high pressure gas switch

    SciTech Connect

    Cravey, W.R.; Poulsen, P.P.; Pincosy, P.A.

    1992-06-01

    Work is being done to develop a high pressure gas switch (HPGS) with picosecond risetimes for UWB applications. Pulse risetimes on the order of 200 picoseconds have been observed at 1 kHz prf and 1 atmosphere. Calculations show that switching closure times on the order of tens of picoseconds can be achieved at high pressures and higher electric fields. A voltage hold-off of 1 MV/cm has been measured at 10 atmospheres and several MV/cm appears possible with the HPGS. With these high electric field levels, energy storage of tens of Joules in a reasonably sized package is achievable. Initial HPGS performance has been characterized on the WASP pulse generator at LLNL. A detailed description of the switch used for initial testing is given. Switch recovery times of 1-ms have been measured at 1 atmosphere. Data on the switching uniformity, voltage hold-off recovery, and pulse repeatability, is presented. In addition, a physics switch model is described and results are compared with lab data.

  16. [Hypertensive urgency or high blood pressure variability?

    PubMed

    Rodionov, A V

    2017-01-01

    Hypertensive urgency (HU) is a common reason particularly for elderly patients to seek medical advice. Severe asymptomatic hypertension and situational high blood pressure (BP) in patients with its high variability is frequently taken as HU. The use of short-acting antihypertensive drugs is not only indicated in these situations, but it may also increase the risk of cardiovascular events (CVE). Over the past decade, increased BP variability is an independent predictor for a higher risk of CVE. Among the major groups of antihypertensive drugs, there are calcium antagonists, mainly amlodipine, which has the greatest potential to reduce BP variability. Thus, calcium antagonists can be considered as first-line drugs for patients with high BP variability.

  17. Method transfer from high-pressure liquid chromatography to ultra-high-pressure liquid chromatography. II. Temperature and pressure effects.

    PubMed

    Åsberg, Dennis; Samuelsson, Jörgen; Leśko, Marek; Cavazzini, Alberto; Kaczmarski, Krzysztof; Fornstedt, Torgny

    2015-07-03

    The importance of the generated temperature and pressure gradients in ultra-high-pressure liquid chromatography (UHPLC) are investigated and compared to high-pressure liquid chromatography (HPLC). The drug Omeprazole, together with three other model compounds (with different chemical characteristics, namely uncharged, positively and negatively charged) were used. Calculations of the complete temperature profile in the column at UHPLC conditions showed, in our experiments, a temperature difference between the inlet and outlet of 16 °C and a difference of 2 °C between the column center and the wall. Through van't Hoff plots, this information was used to single out the decrease in retention factor (k) solely due to the temperature gradient. The uncharged solute was least affected by temperature with a decrease in k of about 5% while for charged solutes the effect was more pronounced, with k decreases up to 14%. A pressure increase of 500 bar gave roughly 5% increase in k for the uncharged solute, while omeprazole and the other two charged solutes gave about 25, 20 and 15% increases in k, respectively. The stochastic model of chromatography was applied to estimate the dependence of the average number of adsorption/desorption events (n) and the average time spent by a molecule in the stationary phase (τs) on temperature and pressure on peak shape for the tailing, basic solute. Increasing the temperature yielded an increase in n and decrease in τs which resulted in less skew at high temperatures. With increasing pressure, the stochastic modeling gave interesting results for the basic solute showing that the skew of the peak increased with pressure. The conclusion is that pressure effects are more pronounced for both retention and peak shape than the temperature effects for the polar or charged compounds in our study.

  18. High blood pressure and visual sensitivity

    NASA Astrophysics Data System (ADS)

    Eisner, Alvin; Samples, John R.

    2003-09-01

    The study had two main purposes: (1) to determine whether the foveal visual sensitivities of people treated for high blood pressure (vascular hypertension) differ from the sensitivities of people who have not been diagnosed with high blood pressure and (2) to understand how visual adaptation is related to standard measures of systemic cardiovascular function. Two groups of middle-aged subjects-hypertensive and normotensive-were examined with a series of test/background stimulus combinations. All subjects met rigorous inclusion criteria for excellent ocular health. Although the visual sensitivities of the two subject groups overlapped extensively, the age-related rate of sensitivity loss was, for some measures, greater for the hypertensive subjects, possibly because of adaptation differences between the two groups. Overall, the degree of steady-state sensitivity loss resulting from an increase of background illuminance (for 580-nm backgrounds) was slightly less for the hypertensive subjects. Among normotensive subjects, the ability of a bright (3.8-log-td), long-wavelength (640-nm) adapting background to selectively suppress the flicker response of long-wavelength-sensitive (LWS) cones was related inversely to the ratio of mean arterial blood pressure to heart rate. The degree of selective suppression was also related to heart rate alone, and there was evidence that short-term changes of cardiovascular response were important. The results suggest that (1) vascular hypertension, or possibly its treatment, subtly affects visual function even in the absence of eye disease and (2) changes in blood flow affect retinal light-adaptation processes involved in the selective suppression of the flicker response from LWS cones caused by bright, long-wavelength backgrounds.

  19. High-pressure coal fuel processor development

    SciTech Connect

    Greenhalgh, M.L.

    1992-11-01

    The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

  20. Stable magnesium peroxide at high pressure

    PubMed Central

    Lobanov, Sergey S.; Zhu, Qiang; Holtgrewe, Nicholas; Prescher, Clemens; Prakapenka, Vitali B.; Oganov, Artem R.; Goncharov, Alexander F.

    2015-01-01

    Rocky planets are thought to comprise compounds of Mg and O as these are among the most abundant elements, but knowledge of their stable phases may be incomplete. MgO is known to be remarkably stable to very high pressure and chemically inert under reduced condition of the Earth’s lower mantle. However, in exoplanets oxygen may be a more abundant constituent. Here, using synchrotron x-ray diffraction in laser-heated diamond anvil cells, we show that MgO and oxygen react at pressures above 96 GPa and T = 2150 K with the formation of I4/mcm MgO2. Raman spectroscopy detects the presence of a peroxide ion (O22−) in the synthesized material as well as in the recovered specimen. Likewise, energy-dispersive x-ray spectroscopy confirms that the recovered sample has higher oxygen content than pure MgO. Our finding suggests that MgO2 may be present together or instead of MgO in rocky mantles and rocky planetary cores under highly oxidized conditions. PMID:26323635

  1. Stable Lithium Argon compounds under high pressure

    PubMed Central

    Li, Xiaofeng; Hermann, Andreas; Peng, Feng; Lv, Jian; Wang, Yanchao; Wang, Hui; Ma, Yanming

    2015-01-01

    High pressure can fundamentally alter the bonding patterns of chemical elements. Its effects include stimulating elements thought to be “inactive” to form unexpectedly stable compounds with unusual chemical and physical properties. Here, using an unbiased structure search method based on CALYPSO methodology and density functional total energy calculations, the phase stabilities and crystal structures of Li−Ar compounds are systematically investigated at high pressure up to 300 GPa. Two unexpected LimArn compounds (LiAr and Li3Ar) are predicted to be stable above 112 GPa and 119 GPa, respectively. A detailed analysis of the electronic structure of LiAr and Li3Ar shows that Ar in these compounds attracts electrons and thus behaves as an oxidizing agent. This is markedly different from the hitherto established chemical reactivity of Ar. Moreover, we predict that the P4/mmm phase of Li3Ar has a superconducting transition temperature of 17.6 K at 120 GPa. PMID:26582083

  2. High pressure-resistant nonincendive emulsion explosive

    DOEpatents

    Ruhe, Thomas C.; Rao, Pilaka P.

    1994-01-01

    An improved emulsion explosive composition including hollow microspheres/bulking agents having high density and high strength. The hollow microspheres/bulking agents have true particle densities of about 0.2 grams per cubic centimeter or greater and include glass, siliceous, ceramic and synthetic resin microspheres, expanded minerals, and mixtures thereof. The preferred weight percentage of hollow microspheres/bulking agents in the composition ranges from 3.0 to 10.0 A chlorinated paraffin oil, also present in the improved emulsion explosive composition, imparts a higher film strength to the oil phase in the emulsion. The emulsion is rendered nonincendive by the production of sodium chloride in situ via the decomposition of sodium nitrate, a chlorinated paraffin oil, and sodium perchlorate. The air-gap sensitivity is improved by the in situ formation of monomethylamine perchlorate from dissolved monomethylamine nitrate and sodium perchlorate. The emulsion explosive composition can withstand static pressures to 139 bars and dynamic pressure loads on the order of 567 bars.

  3. High Pressure Hydrogen from First Principles

    NASA Astrophysics Data System (ADS)

    Morales, M. A.

    2014-12-01

    Typical approximations employed in first-principles simulations of high-pressure hydrogen involve the neglect of nuclear quantum effects (NQE) and the approximate treatment of electronic exchange and correlation, typically through a density functional theory (DFT) formulation. In this talk I'll present a detailed analysis of the influence of these approximations on the phase diagram of high-pressure hydrogen, with the goal of identifying the predictive capabilities of current methods and, at the same time, making accurate predictions in this important regime. We use a path integral formulation combined with density functional theory, which allows us to incorporate NQEs in a direct and controllable way. In addition, we use state-of-the-art quantum Monte Carlo calculations to benchmark the accuracy of more approximate mean-field electronic structure calculations based on DFT, and we use GW and hybrid DFT to calculate the optical properties of the solid and liquid phases near metallization. We present accurate predictions of the metal-insulator transition on the solid, including structural and optical properties of the molecular phase. This work was supported by the U.S. Department of Energy at the Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344 and by LDRD Grant No. 13-LW-004.

  4. Pressure Distribution Over Airfoils at High Speeds

    NASA Technical Reports Server (NTRS)

    Briggs, L J; Dryden, H L

    1927-01-01

    This report deals with the pressure distribution over airfoils at high speeds, and describes an extension of an investigation of the aerodynamic characteristics of certain airfoils which was presented in NACA Technical Report no. 207. The results presented in report no. 207 have been confirmed and extended to higher speeds through a more extensive and systematic series of tests. Observations were also made of the air flow near the surface of the airfoils, and the large changes in lift coefficients were shown to be associated with a sudden breaking away of the flow from the upper surface. The tests were made on models of 1-inch chord and comparison with the earlier measurements on models of 3-inch chord shows that the sudden change in the lift coefficient is due to compressibility and not to a change in the Reynolds number. The Reynolds number still has a large effect, however, on the drag coefficient. The pressure distribution observations furnish the propeller designer with data on the load distribution at high speeds, and also give a better picture of the air-flow changes.

  5. High-pressure structures of yttrium hydrides

    NASA Astrophysics Data System (ADS)

    Liu, Lu-Lu; Sun, Hui-Juan; Wang, C. Z.; Lu, Wen-Cai

    2017-08-01

    In this work, the crystal structures of YH3 and YH4 at high pressure (100-250 GPa) have been explored using a genetic algorithm combined with first-principles calculations. New structures of YH3 with space group symmetries of P21/m and I4/mmm were predicted. The electronic structures and the phonon dispersion properties of various YH3 and YH4 structures at different temperatures and pressures were investigated. Among YH3 phases, the P21/m structure of YH3 was found to have a relatively high superconducting transformation temperature T c of 19 K at 120 GPa, which is reduced to 9 K at 200 GPa. Other YH3 structures have much lower T cs. Compared with YH3, the T c of the YH4 compound is much higher, i.e. 94 K at 120 GPa and 55 K at 200 GPa.

  6. Synthesis of sodium polyhydrides at high pressures

    DOE PAGES

    Struzhkin, Viktor V.; Kim, Duck Young; Stavrou, Elissaios; ...

    2016-07-28

    Archetypal ionic NaH is the only known compound of sodium and hydrogen. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry have had only limited success in spite of several theoretical predictions. Here we report the first observation of the formation of polyhydrides of Na (NaH3 and NaH7) above 40 GPa and 2,000 K. Moreover, we combine synchrotron X-ray diffraction and Raman spectroscopy in a laser-heated diamond anvil cell and theoretical random structure searching, which both agree on the stable structures and compositions. Our results support the formationmore » of multicenter bonding in a material with unusual stoichiometry. These results are applicable to the design of new energetic solids and high-temperature superconductors based on hydrogen-rich materials.« less

  7. Food processing by high hydrostatic pressure.

    PubMed

    Yamamoto, Kazutaka

    2017-04-01

    High hydrostatic pressure (HHP) process, as a nonthermal process, can be used to inactivate microbes while minimizing chemical reactions in food. In this regard, a HHP level of 100 MPa (986.9 atm/1019.7 kgf/cm(2)) and more is applied to food. Conventional thermal process damages food components relating color, flavor, and nutrition via enhanced chemical reactions. However, HHP process minimizes the damages and inactivates microbes toward processing high quality safe foods. The first commercial HHP-processed foods were launched in 1990 as fruit products such as jams, and then some other products have been commercialized: retort rice products (enhanced water impregnation), cooked hams and sausages (shelf life extension), soy sauce with minimized salt (short-time fermentation owing to enhanced enzymatic reactions), and beverages (shelf life extension). The characteristics of HHP food processing are reviewed from viewpoints of nonthermal process, history, research and development, physical and biochemical changes, and processing equipment.

  8. Model of current enhancement at high pressure

    SciTech Connect

    Yu, S.S.; Melendez, R.E.

    1983-04-05

    A model is proposed to account for the phenomenon of net current enhancement at high pressures recently observed on the Experimental Test Accelerator. The proposed mechanism involves energetic secondary electrons (delta rays) which are pushed forward by the self-magnetic field of the electron beam. For high current beams, the forward delta ray current can build up to a significant fraction of the beam current. Analytic calculations of the steady-state solution as well as the rate of buildup of the delta ray current are presented in this paper. In addition, numerical results from a nonlocal Boltzmann code, NUTS, are presented. The analytic and numerical results have many features which are in qualitative agreement with the experiments, but quantitative discrepancies still exist.

  9. Synthesis of sodium polyhydrides at high pressures

    NASA Astrophysics Data System (ADS)

    Struzhkin, Viktor V.; Kim, Duck Young; Stavrou, Elissaios; Muramatsu, Takaki; Mao, Ho-Kwang; Pickard, Chris J.; Needs, Richard J.; Prakapenka, Vitali B.; Goncharov, Alexander F.

    2016-07-01

    The only known compound of sodium and hydrogen is archetypal ionic NaH. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry have had only limited success in spite of several theoretical predictions. Here we report the first observation of the formation of polyhydrides of Na (NaH3 and NaH7) above 40 GPa and 2,000 K. We combine synchrotron X-ray diffraction and Raman spectroscopy in a laser-heated diamond anvil cell and theoretical random structure searching, which both agree on the stable structures and compositions. Our results support the formation of multicenter bonding in a material with unusual stoichiometry. These results are applicable to the design of new energetic solids and high-temperature superconductors based on hydrogen-rich materials.

  10. Synthesis of sodium polyhydrides at high pressures

    SciTech Connect

    Struzhkin, Viktor V.; Kim, Duck Young; Stavrou, Elissaios; Muramatsu, Takaki; Mao, Ho-kwang; Pickard, Chris J.; Needs, Richard J.; Prakapenka, Vitali B.; Goncharov, Alexander F.

    2016-07-28

    Archetypal ionic NaH is the only known compound of sodium and hydrogen. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry have had only limited success in spite of several theoretical predictions. Here we report the first observation of the formation of polyhydrides of Na (NaH3 and NaH7) above 40 GPa and 2,000 K. Moreover, we combine synchrotron X-ray diffraction and Raman spectroscopy in a laser-heated diamond anvil cell and theoretical random structure searching, which both agree on the stable structures and compositions. Our results support the formation of multicenter bonding in a material with unusual stoichiometry. These results are applicable to the design of new energetic solids and high-temperature superconductors based on hydrogen-rich materials.

  11. Synthesis of sodium polyhydrides at high pressures

    PubMed Central

    Struzhkin, Viktor V.; Kim, Duck Young; Stavrou, Elissaios; Muramatsu, Takaki; Mao, Ho-kwang; Pickard, Chris J.; Needs, Richard J.; Prakapenka, Vitali B.; Goncharov, Alexander F.

    2016-01-01

    The only known compound of sodium and hydrogen is archetypal ionic NaH. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry have had only limited success in spite of several theoretical predictions. Here we report the first observation of the formation of polyhydrides of Na (NaH3 and NaH7) above 40 GPa and 2,000 K. We combine synchrotron X-ray diffraction and Raman spectroscopy in a laser-heated diamond anvil cell and theoretical random structure searching, which both agree on the stable structures and compositions. Our results support the formation of multicenter bonding in a material with unusual stoichiometry. These results are applicable to the design of new energetic solids and high-temperature superconductors based on hydrogen-rich materials. PMID:27464650

  12. A new microcolumn-type microchip for examining the expression of chimeric fusion genes using a nucleic acid sandwich hybridization technique.

    PubMed

    Ohnishi, Michihiro; Sasaki, Naoyuki; Kishimoto, Takuya; Watanabe, Hidetoshi; Takagi, Masatoshi; Mizutani, Shuki; Kishii, Noriyuki; Yasuda, Akio

    2014-11-01

    We report a new type of microcolumn installed in a microchip. The architecture allows use of a nucleic acid sandwich hybridization technique to detect a messenger RNA (mRNA) chain as a target. Data are presented that demonstrate that the expression of a chimeric fusion gene can be detected. The microcolumn was filled with semi-transparent microbeads made of agarose gel that acted as carriers, allowing increased efficiency of the optical detection of fluorescence from the microcolumn. The hybrid between the target trapped on the microbeads and a probe DNA labeled with a fluorescent dye was detected by measuring the intensity of the fluorescence from the microcolumn directly. These results demonstrate an easy and simple method for determining the expression of chimeric fusion genes with no preamplification. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Rheological assessment of nanofluids at high pressure high temperature

    NASA Astrophysics Data System (ADS)

    Kanjirakat, Anoop; Sadr, Reza

    2013-11-01

    High pressure high temperature (HPHT) fluids are commonly encountered in industry, for example in cooling and/or lubrications applications. Nanofluids, engineered suspensions of nano-sized particles dispersed in a base fluid, have shown prospective as industrial cooling fluids due to their enhanced rheological and heat transfer properties. Nanofluids can be potentially utilized in oil industry for drilling fluids and for high pressure water jet cooling/lubrication in machining. In present work rheological characteristics of oil based nanofluids are investigated at HPHT condition. Nanofluids used in this study are prepared by dispersing commercially available SiO2 nanoparticles (~20 nm) in a mineral oil. The basefluid and nanofluids with two concentrations, namely 1%, and 2%, by volume, are considered in this investigation. The rheological characteristics of base fluid and the nanofluids are measured using an industrial HPHT viscometer. Viscosity values of the nanofluids are measured at pressures of 100 kPa to 42 MPa and temperatures ranging from 25°C to 140°C. The viscosity values of both nanofluids as well as basefluid are observed to have increased with the increase in pressure. Funded by Qatar National Research Fund (NPRP 08-574-2-239).

  14. New developments in high pressure x-ray spectroscopy beamline at High Pressure Collaborative Access Team

    SciTech Connect

    Xiao, Y. M. Chow, P.; Boman, G.; Bai, L. G.; Rod, E.; Bommannavar, A.; Kenney-Benson, C.; Sinogeikin, S.; Shen, G. Y.

    2015-07-15

    The 16 ID-D (Insertion Device - D station) beamline of the High Pressure Collaborative Access Team at the Advanced Photon Source is dedicated to high pressure research using X-ray spectroscopy techniques typically integrated with diamond anvil cells. The beamline provides X-rays of 4.5-37 keV, and current available techniques include X-ray emission spectroscopy, inelastic X-ray scattering, and nuclear resonant scattering. The recent developments include a canted undulator upgrade, 17-element analyzer array for inelastic X-ray scattering, and an emission spectrometer using a polycapillary half-lens. Recent development projects and future prospects are also discussed.

  15. Stable xenon nitride at high pressures

    NASA Astrophysics Data System (ADS)

    Peng, Feng; Wang, Yanchao; Wang, Hui; Zhang, Yunwei; Ma, Yanming

    2015-09-01

    Nitrides in many ways are fascinating since they often appear as superconductors, high-energy density, and hard materials. Though there exist a large variety of nitrides, noble gas nitrides are missing in nature. Pursuit of noble gas nitrides has therefore become the subject of topical interests, but remains as a great challenge since molecular nitrogen (N2, a major form of nitrogen) and noble gases are both inert systems and do not interact at normal conditions. We show through a first-principles swarm-structure search that high pressure enables a direct interaction of N2 and xenon (Xe) above 146 GPa. The resultant Xe nitride has a peculiar stoichiometry of XeN6, possessing a high-energy density of approximately 2.4 kJg -1, rivaling that of the modern explosives. Structurally, XeN6 is intriguing with the appearance of chaired N6 hexagons and unusually high 12-coordination of Xe bonded with N. Our work opens up the possibility of achieving Xe nitride with superior high-energy density whose formation is long sought as impossible.

  16. Polymer-coated fibrous extraction medium for sample preparation coupled to microcolumn liquid-phase separations.

    PubMed

    Imaizumi, Motohiro; Saito, Yoshihiro; Hayashida, Makiko; Takeichi, Tsutomu; Wada, Hiroo; Jinno, Kiyokatsu

    2003-01-15

    Polymer-coated fibrous material has been introduced as the extraction medium for a miniaturized sample preparation method being coupled with microcolumn liquid chromatography. The preconcentration and the subsequent liquid chromatographic separation of tricyclic antidepressants (TCAs) drugs, amitriptyline, imipramine, nortriptyline and desipramine, was carried out with the hyphenated system. Several basic experimental parameters, such as extraction and separation conditions, were investigated along with the applicability of the method for the analysis of biological fluids. The results clearly showed that the on-line coupled system could be a powerful tool for the analysis of complex mixtures in biological matrix without a large solvent consumption and specially designed instruments. The lowest limit of quantification was quite acceptable for the analysis of TCAs in clinical and forensic situations.

  17. High-pressure coal fuel processor development

    SciTech Connect

    Greenhalgh, M.L. )

    1992-12-01

    Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

  18. High pressure FAST of nanocrystalline barium titanate

    SciTech Connect

    Fraga, Martin B.; Delplanque, Jean -Pierre; Yang, Nancy; Lavernia, Enrique J.; Monson, Todd C.

    2016-06-01

    Here, this work studies the microstructural evolution of nanocrystalline (<1 µm) barium titanate (BaTiO3), and presents high pressure in field-assisted sintering (FAST) as a robust methodology to obtain >100 nm BaTiO3 compacts. Using FAST, two commercial ~50 nm powders were consolidated into compacts of varying densities and grain sizes. Microstructural inhomogeneities were investigated for each case, and an interpretation is developed using a modified Monte Carlo Potts (MCP) simulation. Two recurrent microstructural inhomogeneities are highlighted, heterogeneous grain growth and low-density regions, both ubiqutously present in all samples to varying degrees. In the worst cases, HGG presents an area coverage of 52%. Because HGG is sporadic but homogenous throughout a sample, the catalyst (e.g., the local segregation of species) must be, correspondingly, distributed in a homogenous manner. MCP demonstrates that in such a case, a large distance between nucleating abnormal grains is required—otherwise abnormal grains prematurely impinge on each other, and their size is not distinguishable from that of normal grains. Compacts sintered with a pressure of 300 MPa and temperatures of 900 °C, were 99.5% dense and had a grain size of 90±24 nm. These are unprecedented results for commercial BaTiO3 powders or any starting powder of 50 nm particle size—other authors have used 16 nm lab-produced powder to obtain similar results.

  19. High pressure FAST of nanocrystalline barium titanate

    DOE PAGES

    Fraga, Martin B.; Delplanque, Jean -Pierre; Yang, Nancy; ...

    2016-06-01

    Here, this work studies the microstructural evolution of nanocrystalline (<1 µm) barium titanate (BaTiO3), and presents high pressure in field-assisted sintering (FAST) as a robust methodology to obtain >100 nm BaTiO3 compacts. Using FAST, two commercial ~50 nm powders were consolidated into compacts of varying densities and grain sizes. Microstructural inhomogeneities were investigated for each case, and an interpretation is developed using a modified Monte Carlo Potts (MCP) simulation. Two recurrent microstructural inhomogeneities are highlighted, heterogeneous grain growth and low-density regions, both ubiqutously present in all samples to varying degrees. In the worst cases, HGG presents an area coverage ofmore » 52%. Because HGG is sporadic but homogenous throughout a sample, the catalyst (e.g., the local segregation of species) must be, correspondingly, distributed in a homogenous manner. MCP demonstrates that in such a case, a large distance between nucleating abnormal grains is required—otherwise abnormal grains prematurely impinge on each other, and their size is not distinguishable from that of normal grains. Compacts sintered with a pressure of 300 MPa and temperatures of 900 °C, were 99.5% dense and had a grain size of 90±24 nm. These are unprecedented results for commercial BaTiO3 powders or any starting powder of 50 nm particle size—other authors have used 16 nm lab-produced powder to obtain similar results.« less

  20. [High blood pressure and physical exercise].

    PubMed

    Sosner, P; Gremeaux, V; Bosquet, L; Herpin, D

    2014-06-01

    High blood pressure is a frequent pathology with many cardiovascular complications. As highlighted in guidelines, the therapeutic management of hypertension relies on non-pharmacological measures, which are diet and regular physical activity, but both patients and physicians are reluctant to physical activity prescription. To acquire the conviction that physical activity is beneficial, necessary and possible, we can take into account some fundamental and clinical studies, as well as the feedback of our clinical practice. Physical inactivity is a major risk factor for cardiovascular morbidity and mortality, and hypertension contributes to increase this risk. Conversely, regular practice of physical activity decreases very significantly the risk by up to 60%. The acute blood pressure changes during exercise and post-exercise hypotension differs according to the dynamic component (endurance or aerobic and/or strength exercises), but the repetition of the sessions leads to the chronic hypotensive benefit of physical activity. Moreover, physical activity prescription must take into account the assessment of global cardiovascular risk, the control of the hypertension, and the opportunities and desires of the patient in order to promote good adherence and beneficial lifestyle change. Copyright © 2014 Elsevier Masson SAS. All rights reserved.

  1. Engineering Model of High Pressure Moist Air

    NASA Astrophysics Data System (ADS)

    Hyhlík, Tomáš

    The article deals with the moist air equation of state. There are equations of state discussed in the article, i.e. the model of an ideal mixture of ideal gases, the model of an ideal mixture of real gases and the model based on the virial equation of state. The evaluation of sound speed based on the ideal mixture concept is mentioned. The sound speed calculated by the model of an ideal mixture of ideal gases is compared with the sound speed calculated by using the model based on the concept of an ideal mixture of real gases. The comparison of enthalpy end entropy based on the model of an ideal mixture of ideal gases and the model of an ideal mixture of real gases is performed. It is shown that the model of an ideal mixture of real gases deviates from the model of an ideal mixture of ideal gases only in the case of high pressure. An impossibility of the definition of partial pressure in the mixture of real gases is discussed, where the virial equation of state is used.

  2. High pressure FAST of nanocrystalline barium titanate

    SciTech Connect

    Fraga, Martin B.; Delplanque, Jean -Pierre; Yang, Nancy; Lavernia, Enrique J.; Monson, Todd C.

    2016-06-01

    Here, this work studies the microstructural evolution of nanocrystalline (<1 µm) barium titanate (BaTiO3), and presents high pressure in field-assisted sintering (FAST) as a robust methodology to obtain >100 nm BaTiO3 compacts. Using FAST, two commercial ~50 nm powders were consolidated into compacts of varying densities and grain sizes. Microstructural inhomogeneities were investigated for each case, and an interpretation is developed using a modified Monte Carlo Potts (MCP) simulation. Two recurrent microstructural inhomogeneities are highlighted, heterogeneous grain growth and low-density regions, both ubiqutously present in all samples to varying degrees. In the worst cases, HGG presents an area coverage of 52%. Because HGG is sporadic but homogenous throughout a sample, the catalyst (e.g., the local segregation of species) must be, correspondingly, distributed in a homogenous manner. MCP demonstrates that in such a case, a large distance between nucleating abnormal grains is required—otherwise abnormal grains prematurely impinge on each other, and their size is not distinguishable from that of normal grains. Compacts sintered with a pressure of 300 MPa and temperatures of 900 °C, were 99.5% dense and had a grain size of 90±24 nm. These are unprecedented results for commercial BaTiO3 powders or any starting powder of 50 nm particle size—other authors have used 16 nm lab-produced powder to obtain similar results.

  3. Laser desorption/ionization from nanostructured surfaces: nanowires, nanoparticle films and silicon microcolumn arrays

    NASA Astrophysics Data System (ADS)

    Chen, Yong; Luo, Guanghong; Diao, Jiajie; Chornoguz, Olesya; Reeves, Mark; Vertes, Akos

    2007-04-01

    Due to their optical properties and morphology, thin films formed of nanoparticles are potentially new platforms for soft laser desorption/ionization (SLDI) mass spectrometry. Thin films of gold nanoparticles (with 12±1 nm particle size) were prepared by evaporation-driven vertical colloidal deposition and used to analyze a series of directly deposited polypeptide samples. In this new SLDI method, the required laser fluence for ion detection was equal or less than what was needed for matrix-assisted laser desorption/ionization (MALDI) but the resulting spectra were free of matrix interferences. A silicon microcolumn array-based substrate (a.k.a. black silicon) was developed as a new matrix-free laser desorption ionization surface. When low-resistivity silicon wafers were processed with a 22 ps pulse length 3×ω Nd:YAG laser in air, SF6 or water environment, regularly arranged conical spikes emerged. The radii of the spike tips varied with the processing environment, ranging from approximately 500 nm in water, to ~2 µm in SF6 gas and to ~5 µm in air. Peptide mass spectra directly induced by a nitrogen laser showed the formation of protonated ions of angiotensin I and II, substance P, bradykinin fragment 1-7, synthetic peptide, pro14-arg, and insulin from the processed silicon surfaces but not from the unprocessed areas. Threshold fluences for desorption/ionization were similar to those used in MALDI. Although compared to silicon nanowires the threshold laser pulse energy for ionization is significantly (~10×) higher, the ease of production and robustness of microcolumn arrays offer complementary benefits.

  4. Determination of phenylenediamine isomers in hair dyes by coal cinders micro-column extraction and MEKC.

    PubMed

    Wu, Yiwei; Jiang, Feng; Chen, Lin; Zheng, Jing; Deng, Zhenli; Tao, Qing; Zhang, Jing; Han, Lijuan; Wei, Xiaoshu; Yu, Aimin; Zhang, Haili

    2011-06-01

    A new micellar electrokinetic chromatography (MEKC) method using beta-cyclodextrins (β-CDs) and 1-butyl-3-methylimidazolium hexafluorophosphates (ionic liquids) as additives was successfully developed for determination of para-, meta-, and ortho-phenylenediamines isomers (p-P, m-P, and o-P) in hair dyes. To improve the sensitivity of the MEKC-UV, a simple and cheap flow injection (FI) technique using a micro-column packed with coal cinders (the by-products from combustion in a boiler) as solid-phase extractant was also investigated. In the presence of 20 mmol L(-1) phosphates at pH 5.5, addition of 12 mmol L(-1) ionic liquids and 8 mmol L(-1) β-CDs greatly improved the separation efficiency. The three analytes could be quantitatively adsorbed by coal cinders, and desorbed readily with 0.15 mL of 0.01 mol L(-1) NaOH. Under the optimum conditions, an enrichment factor (EF) of 33.3 was obtained, and determination limits of p-P, m-P, and o-P were 1.97 × 10(-7), 0.99 × 10(-7), and 0.61 × 10(-7) mol L(-1), respectively. The adsorption capacities of the coal cinders micro-column for p-P, m-P, and o-P were all 1.20 mg g(-1). The presented procedure was successfully applied to the determination of p-P, m-P, and o-P in hair dyes with satisfactory results.

  5. Micro-columns packed with Chlorella vulgaris immobilised on silica gel for mercury speciation.

    PubMed

    Tajes-Martínez, P; Beceiro-González, E; Muniategui-Lorenzo, S; Prada-Rodríguez, D

    2006-02-28

    A method has been developed for mercury speciation in water by using columns packed with Chlorella vulgaris immobilised on silica gel. The method involves the retention of CH(3)Hg(+) and Hg(2+) in micro-columns prepared by packing immobilised algae in polypropylene tubes, followed by selective and sequential elution with 0.03 and 1.5M HCl for CH(3)Hg(+) and Hg(2+), respectively. The adsorption capacity of the micro-algae for Hg(2+) and CH(3)Hg(+) has been evaluated using free and immobilised C. vulgaris. The efficiency uptake for both species at pH 3 was higher than 97%. Studies were carried out on the effect of retention and elution conditions for both species. Furthermore, the stability of mercury species retained on algae-silica gel micro-columns and lifetime of the columns were also investigated. Hg(2+) showed a higher stability than CH(3)Hg(+) at 0 degrees C (21 and 3 days, respectively) and a better lifetime than for the organic species. The developed method was applied to the analysis of spiked tap, sea and wastewater samples. Recovery studies on tap and filtered seawater provided results between 96+/-3 and 106+/-2 for Hg(2+) and from 98+/-5 to 107+/-5 for CH(3)Hg(+), for samples spiked with single species. For samples spiked with both CH(3)Hg(+) and Hg(2+), the average recoveries varied from 96+/-5 to 99+/-3 and from 103+/-6 to 115+/-5 for Hg(2+) and CH(3)Hg(+), respectively. However, the percentages of retention and elution on wastewater and unfiltered seawater were only adequate for the inorganic species.

  6. How to Prevent High Blood Pressure

    MedlinePlus

    ... provider will use a gauge, a stethoscope or electronic sensor, and a blood pressure cuff. For most ... pressure. Stress management techniques include exercising, listening to music, focusing on something calm or peaceful, and meditating. ...

  7. High pressure fiber optic sensor system

    DOEpatents

    Guida, Renato; Xia, Hua; Lee, Boon K; Dekate, Sachin N

    2013-11-26

    The present application provides a fiber optic sensor system. The fiber optic sensor system may include a small diameter bellows, a large diameter bellows, and a fiber optic pressure sensor attached to the small diameter bellows. Contraction of the large diameter bellows under an applied pressure may cause the small diameter bellows to expand such that the fiber optic pressure sensor may measure the applied pressure.

  8. Windowless High-Pressure Solar Reactor

    NASA Technical Reports Server (NTRS)

    Ramohalli, K. N. R.

    1985-01-01

    Obscuration by reaction products eliminated. Chemical reactor heated by Sunlight employs rocket technology to maintain internal pressure. Instead of keeping chamber tightly closed, pressure maintained by momentum balance between incoming and outgoing materials. Windowless solar reactor admits concentrated Sunlight through exhaust aperture. Pressure in reactor maintained dynamically.

  9. Very high temperature silicon on silicon pressure transducers

    NASA Technical Reports Server (NTRS)

    Kurtz, Anthony D.; Nunn, Timothy A.; Briggs, Stephen A.; Ned, Alexander

    1992-01-01

    A silicon on silicon pressure sensor has been developed for use at very high temperatures (1000 F). The design principles used to fabricate the pressure sensor are outlined and results are presented of its high temperature performance.

  10. A Nutritional Strategy for the Treatment of High Blood Pressure.

    ERIC Educational Resources Information Center

    Podell, Richard N.

    1984-01-01

    Some physicians wonder if high blood pressure can be controlled without the use of drugs and their potential side effects. Current findings concerning nutrition and high blood pressure are presented. (RM)

  11. High blood pressure - what to ask your doctor

    MedlinePlus

    What to ask your doctor about high blood pressure; Hypertension - what to ask your doctor ... problems? What medicines am I taking to treat high blood pressure? Do they have any side effects? What should ...

  12. High Blood Pressure, Afib and Your Risk of Stroke

    MedlinePlus

    ... Peripheral Artery Disease Venous Thromboembolism Aortic Aneurysm More High Blood Pressure, AFib and Your Risk of Stroke Updated:Aug ... have a stroke for the first time have high blood pressure . And an irregular atrial heart rhythm — a condition ...

  13. A Nutritional Strategy for the Treatment of High Blood Pressure.

    ERIC Educational Resources Information Center

    Podell, Richard N.

    1984-01-01

    Some physicians wonder if high blood pressure can be controlled without the use of drugs and their potential side effects. Current findings concerning nutrition and high blood pressure are presented. (RM)

  14. High Blood Pressure, Afib and Your Risk of Stroke

    MedlinePlus

    ... Peripheral Artery Disease Venous Thromboembolism Aortic Aneurysm More High Blood Pressure, Afib and Your Risk of Stroke Updated:Sep ... have a stroke for the first time have high blood pressure . And an irregular atrial heart rhythm — a condition ...

  15. DNS of High Pressure Supercritical Combustion

    NASA Astrophysics Data System (ADS)

    Chong, Shao Teng; Raman, Venkatramanan

    2016-11-01

    Supercritical flows have always been important to rocket motors, and more recently to aircraft engines and stationary gas turbines. The purpose of the present study is to understand effects of differential diffusion on reacting scalars using supercritical isotropic turbulence. Focus is on fuel and oxidant reacting in the transcritical region where density, heat capacity and transport properties are highly sensitive to variations in temperature and pressure. Reynolds and Damkohler number vary as a result and although it is common to neglect differential diffusion effects if Re is sufficiently large, this large variation in temperature with heat release can accentuate molecular transport differences. Direct numerical simulations (DNS) for one step chemistry reaction between fuel and oxidizer are used to examine the differential diffusion effects. A key issue investigated in this paper is if the flamelet progress variable approach, where the Lewis number is usually assumed to be unity and constant for all species, can be accurately applied to simulate supercritical combustion.

  16. Low energy high pressure miniature screw valve

    DOEpatents

    Fischer, Gary J.; Spletzer, Barry L.

    2006-12-12

    A low energy high pressure screw valve having a valve body having an upper portion and a lower portion, said lower portion of said valve body defining an inlet flow passage and an outlet flow passage traversing said valve body to a valve seat, said upper portion of said valve body defining a cavity at said valve seat, a diaphragm restricting flow between said upper portion of said valve body and said lower portion, said diaphragm capable of engaging said valve seat to restrict fluid communication between said inlet passage and said outlet passage, a plunger within said cavity supporting said diaphragm, said plunger being capable of engaging said diaphragm with said valve seat at said inlet and outlet fluid passages, said plunger being in point contact with a drive screw having threads engaged with opposing threads within said upper portion of said valve body such engagement allowing motion of said drive screw within said valve body.

  17. Safety improvements in high pressure thermal machines

    SciTech Connect

    Otters, J.L.

    1988-02-09

    In a thermal machine of the type including a machine body having a main axis extending between a thermal end and a work end, a working fluid at relatively high pressure in a working fluid chamber defined in the body and a displacer element reciprocable within the chamber for subjecting the fluid to a thermodynamic cycle in cooperation with a reciprocable work piston, the improvement is described comprising outer shell means enclosing the machine body for maintaining a substantially sealed atmosphere about the machine body, and diffuser means arranged between the machine body and the outer shell means for diffusing a shock wave traveling towards the outer shell means resulting from explosive failure of the machine body and for shielding the outer shell means against fragments projected upon such failure.

  18. High Pressure Quick Disconnect Particle Impact Tests

    NASA Technical Reports Server (NTRS)

    Rosales, Keisa R.; Stoltzfus, Joel M.

    2009-01-01

    NASA Johnson Space Center White Sands Test Facility (WSTF) performed particle impact testing to determine whether there is a particle impact ignition hazard in the quick disconnects (QDs) in the Environmental Control and Life Support System (ECLSS) on the International Space Station (ISS). Testing included standard supersonic and subsonic particle impact tests on 15-5 PH stainless steel, as well as tests performed on a QD simulator. This paper summarizes the particle impact tests completed at WSTF. Although there was an ignition in Test Series 4, it was determined the ignition was caused by the presence of a machining imperfection. The sum of all the test results indicates that there is no particle impact ignition hazard in the ISS ECLSS QDs. KEYWORDS: quick disconnect, high pressure, particle impact testing, stainless steel

  19. Ceramic high pressure gas path seal

    NASA Technical Reports Server (NTRS)

    Liotta, G. C.

    1987-01-01

    Stage 1 ceramic shrouds (high pressure turbine gas path seal) were developed for the GE T700 turbine helicopter engine under the Army/NASA Contract NAS3-23174. This contract successfully proved the viability and benefits of a Stage 1 ceramic shroud for production application. Stage 1 ceramic shrouds were proven by extensive component and engine testing. This Stage 1 ceramic shroud, plasma sprayed ceramic (ZrOs-BY2O3) and bond coating (NiCrAlY) onto a cast metal backing, offers significant engine performance improvement. Due to the ceramic coating, the amount of cooling air required is reduced 20% resulting in a 0.5% increase in horsepower and a 0.3% decrease in specific fuel consumption. This is accomplished with a component which is lower in cost than the current production shroud. Stage 1 ceramic shrouds will be introduced into field service in late 1987.

  20. Condensed matter at high shock pressures

    SciTech Connect

    Nellis, W.J.; Holmes, N.C.; Mitchell, A.C.; Radousky, H.B.; Hamilton, D.

    1985-07-12

    Experimental techniques are described for shock waves in liquids: Hugoniot equation-of-state, shock temperature and emission spectroscopy, electrical conductivity, and Raman spectroscopy. Experimental data are reviewed and presented in terms of phenomena that occur at high densities and temperatures in shocked He, Ar, N/sub 2/, CO, SiO/sub 2/-aerogel, H/sub 2/O, and C/sub 6/H/sub 6/. The superconducting properties of Nb metal shocked to 100 GPa (1 Mbar) and recovered intact are discussed in terms of prospects for synthesizing novel, metastable materials. Ultrahigh pressure data for Cu is reviewed in the range 0.3 to 6TPa (3 to 60 Mbar). 56 refs., 9 figs., 1 tab.

  1. Urea and deuterium mixtures at high pressures

    SciTech Connect

    Donnelly, M. Husband, R. J.; Frantzana, A. D.; Loveday, J. S.; Bull, C. L.; Klotz, S.

    2015-03-28

    Urea, like many network forming compounds, has long been known to form inclusion (guest-host) compounds. Unlike other network formers like water, urea is not known to form such inclusion compounds with simple molecules like hydrogen. Such compounds if they existed would be of interest both for the fundamental insight they provide into molecular bonding and as potential gas storage systems. Urea has been proposed as a potential hydrogen storage material [T. A. Strobel et al., Chem. Phys. Lett. 478, 97 (2009)]. Here, we report the results of high-pressure neutron diffraction studies of urea and D{sub 2} mixtures that indicate no inclusion compound forms up to 3.7 GPa.

  2. High-pressure behavior of hydrous phases

    NASA Astrophysics Data System (ADS)

    Mookherjee, M.; Tsuchiya, J.; Hermann, A.; Speziale, S.

    2016-12-01

    One of the most distinguishing features of the Earth is its surface water, which is a crucial component in making it a habitable planet. How this water is partitioned among the various reservoirs within the Earth's interior is of considerable interest to the Solid Earth Sciences community. In convergent plate margins such as subduction zone, the hydrous phases in the subducting slabs deliver water into the Earth's interior. Upon reaching greater depths, depending on the limits of their thermodynamic stability, the hydrous phases dehydrate, releasing water. A fraction of water is released back into the hydrosphere through arc volcanism. Recent estimates show that the worldwide flux of water from subducting slabs amounts to about one ocean mass over the age of the Earth. The water in the Earth's interior is stored in several distinct forms: as aqueous fluids; hydrous silicate melts; nominally anhydrous phases; grain boundaries, and various hydrous phases. Among these multiple hosts, hydrous phases are particularly important because they influence solid earth processes in the crust and mantle. The thermodynamic stability of hydrous phases dictates how efficiently they transport and store water in the Earth's interior. Their presence severely affects the onset of melting. Hydrous phases that are likely to be stable at higher pressures are often not recorded in natural samples. It is possible that these hydrous phases are not sampled by melts that arise from depths that are shallower than where high-pressure hydrous phases may occur. It is also possible that these hydrous phases do not survive exhumation. In addition, many hydrous phases might have limited thermal stability. High-pressure experiments and first-principles simulations based on density functional theory (DFT) have been crucial in enhancing our understanding of hydrous phases that are likely to be present in the Earth's mantle and subduction zones. In this study, we present DFT results and compare them with

  3. Digital valve for high pressure high flow applications

    NASA Astrophysics Data System (ADS)

    Badescu, Mircea; Sherrit, Stewart; Lewis, Derek; Bao, Xiaoqi; Bar-Cohen, Yoseph; Hall, Jeffery L.

    2016-04-01

    To address the challenges, which are involved with the development of flow control valves that can meet high demand requirements such as high pressure, high flow rate, limited power and limited space, the authors have conceived a novel design configuration. This design consists of a digitalized flow control valve with multipath and multistage pressure reduction structures. Specifically, the valve is configured as a set of parallel flow paths from the inlet to the outlet. A choke valve controls the total flow rate by digitally opening different paths or different combination of the paths. Each path is controlled by a poppet cap valve basically operated in on-off states. The number of flow states is 2N where N is the number of flow paths. To avoid erosion from sand in the fluid and high speed flow, the seal area of the poppet cap valve is located at a distance from the flow inlet away from the high speed flow and the speed is controlled to stay below a predefined erosion safe limit. The path is a multistage structure composed of a set of serial nozzles-expansion chambers that equally distribute the total pressure drop to each stage. The pressure drop of each stage and, therefore, the flow speed at the nozzles and expansion chambers is controlled by the number of stages. The paths have relatively small cross section and could be relatively long for large number of stages and still fit in a strict annular space limit. The paper will present the design configuration, analysis and preliminary test results.

  4. System design for buried high-pressure/high-temperature pipelines

    SciTech Connect

    1998-06-01

    A pipeline expands or contracts when temperatures or pressures vary from the conditions at the time the pipeline was installed. Buried pipelines operating at high temperatures and pressures experience extreme compressive loads. Because radial expansion is limited by soil restraint, buried pipelines expand axially. High axial forces combined with imperfections in the seabed may overstress the pipeline or result in upheaval buckling. Methods to control expansion and upheaval buckling were investigated for the design of a buried high-pressure/high temperature (HP/HT) sour-gas flowline in Mobile Bay, Alabama. After investigating conventional and unconventional methods, the decision was made to use expansion loops over the length of the pipeline to protect the risers and reduce axial force in the middle of the pipeline. Expansion loops and doglegs act as springs to absorb pipeline expansion. Methods were investigated to prevent soil from accumulating around the buried expansion loops. Commercially available concrete dog houses used to protect pipelines and expansion loops from dropped objects were not suitable for burial, and fabrication of custom concrete housing was expensive. Fabrication of a steel enclosure was the solution chosen. A mathematical model based on internal-design guidelines and ultimate soil friction was used to determine placement and size of the expansion loops.

  5. Effect of high pressure on mesophilic lactic fermentation streptococci

    NASA Astrophysics Data System (ADS)

    Reps, A.; Kuźmicka, M.; Wiśniewska, K.

    2008-07-01

    The research concerned the effect of high pressure on mesophilic lactic fermentation streptococci, present in two cheese-making commercial inocula produced by Christian-Hansen. Water solutions of inocula were pressurized at 50-800 MPa, at room temperature, for 30-120 min. Pressurization at 50-100 MPa slightly increased or reduced the number of lactic streptococci, depending on the inoculum and pressurization time. Pressurization at 200 MPa caused a reduction in the number of streptococci by over 99.9%, whereas the pressure of 400 MPa and above almost completely inactivated streptococci. Pressurization also reduced the dynamics of microorganism growth and acidification, to the degree depending on the pressure.

  6. High rate internal pressurization of the human eye to determine dynamic rupture pressure.

    PubMed

    Bisplinghoff, Jill A; McNally, Craig; Yang, Siyang; Herring, Ian P; Brozoski, Fred T; Duma, Stefan M

    2008-01-01

    Over 1.9 million people suffer from eye injuries in the United States, occurring from automobile accidents, sports related impacts, and military combat. The purpose of the current study is to analyze the rupture pressure of human eyes using a high rate pressurization system. Internal pressure was dynamically induced into the eye with a drop tower pressurization system. The rupture pressure was measured with a small pressure sensor inserted into the optic nerve. A total of 10 human eye dynamic pressure tests were performed to determine rupture pressure and to compare the results with previous data. It was found that the average high rate rupture pressure of human eyes is 0.89+/- 0.25 MPa. In comparing these data with previous studies, it is concluded that as the loading rate increases the rupture pressure also increases.

  7. 77 FR 37712 - High Pressure Steel Cylinders From China

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-22

    ... COMMISSION High Pressure Steel Cylinders From China Determinations On the basis of the record \\1\\ developed... imports of high pressure steel cylinders from China, provided for in subheading 7311.00.00 of the... following notification of preliminary determinations by Commerce that imports of high pressure...

  8. What about African Americans and High Blood Pressure?

    MedlinePlus

    ... whites. • Heredity —A tendency to have high blood pressure runs in families. • Age — In general, the older you get, the greater your chance of developing high blood pressure. • Sex — Men tend to develop high blood pressure ...

  9. Metabolic Activity of Bacteria at High Pressure

    NASA Astrophysics Data System (ADS)

    Picard, A.; Daniel, I.; Oger, P.

    2008-12-01

    Over the last 20 years, there has been increasing evidence for the presence of a large number of microbes in the oceanic subsurface. Such a habitat has a very low energy input because it is deprived of light. A few meters below the sediment surface, conditions are already anoxic in most cases, sulfate reduction and/or methanogenesis becoming thus the primary respiratory reactions of organic matter. Neither the fate of methanogenesis, nor the fate of Dissimilatory Metal-Reduction (DMR) has been investigated so far as a function of pressure. For this reason, we measured experimentally the pressure limits of microbial anaerobic energetic metabolism. In practice, we measured in situ the kinetics of selenite respiration by the bacterial model Shewanella oneidensis MR-1 under high hydrostatic pressure (HHP) between 0 and 150 MPa at 30°C. MR-1 stationary-phase cells were used in Luria-Bertani (LB) medium amended with lactate as an additional electron donor and sodium selenite as an electron acceptor. In situ measurements were performed by X- ray Absorption Near-Edge Structure (XANES) spectroscopy in both a diamond-anvil cell and an autoclave. A red precipitate of amorphous Se(0) was virtually observed at any pressure to 150 MPa. A progressive reduction of selenite Se(IV) into selenium Se(0) was also observed in the evolution of XANES spectra with time. All kinetics between 0.1 and 150 MPa can be adjusted to a first order kinetic law. MR-1 respires all available selenite up to 60 MPa. Above 60 MPa, the respiration yield decreases linearly as a function of pressure and reaches 0 at 155 ±5 MPa. This indicates that selenite respiration by Shewanella oneidensis MR-1 stops at about 155 MPa, whereas its growth is arrested at 50 MPa. Hence, the present results show that the respiration of selenium by the strain MR-1 occurs efficiently up to 60 MPa and 30°C, i.e. from the surface of a continental sediment to an equivalent depth of about 2 km, or beneath a 5-km water column and

  10. Electrical resistivity of iron at high pressure and high temperature

    NASA Astrophysics Data System (ADS)

    Deng, L.; Seagle, C.; Fei, Y.; Shahar, A.

    2011-12-01

    Knowledge of thermal conductivity of iron under high-pressure and temperature conditions is crucial to understand the heat transport and the thermal evolution of planetary interior. However, measurements of thermal conductivity at high pressure and temperature are challenging and experimental data are limited. In this study, we report the measured electrical resistivity of iron at high pressure and temperature. The data are then translated to thermal conductivity through Wiedemann-Franz law. A four-probe method was employed to measure the resistances of a cylindrical wire during heating cycles at high pressure. Experiments at 5, 7 and 13 GPa were performed on an iron wire sample by using a multi-anvil apparatus at the Geophysical Laboratory. At 5, 7 and 13 GPa, the measured electrical resistivity of iron at room temperature are 9.06 mΩ-cm (bcc phase), 8.85 mΩ-cm (bcc phase) and 12.72 mΩ-cm (hcp phase), respectively. The results are in a good agreement with reported room-temperature data. The kinks in electrical resistivity associated with the phase transitions of iron were clearly observed in each run. At 5 and 7 GPa, kinks in the electrical resistivity can be noticed at 677 oC and 652 oC, respectively, due to the bcc to fcc phase transition. At 5 GPa and 1687 oC, melting led to a discontinuous change in electrical resistivity. The temperature dependence of the electrical resistivity for bcc, fcc, and hcp iron are well constrained from these measurements. The hcp iron displays the strongest temperature dependence compared with that of the bcc and fcc phases. Our results provide critical thermodynamic parameters to constrain heat transport in the planetary cores.

  11. Probing Hydrogen Diffusion under High Pressure

    NASA Astrophysics Data System (ADS)

    Bove, L. E.; Klotz, S.; Strassle, T.; Saitta, M.

    2012-12-01

    The study of the microscopic mechanism governing hydrogen and hydrogen-based liquids (as water, ammonia and methane) diffusion is crucial for a variety of scientific issues spanning most of natural sciences. As an example, characterizing hydrogen diffusion in a confined medium, like in porous systems or zeolites, is fundamental in problems relating to environment, hydrogen storage and industrial applications [1]. The presence of water diffusion in the minerals of the Earth's mantle have strong incidence on the processes governing volcanic eruptions and intermediate-depth seismicity. As last example, knowing in details the microscopic dynamics of hydrogen-based simple liquids under extreme conditions is essential in order to interpret observations and develop models of planet interiors [2]. On the other hand, water and other simple hydrogen-based liquids have always been key systems in the development of modern condensed-matter physics, because of their simple electronic structure and the peculiar properties deriving from the hydrogen-bond network. Their high compressibility and chemical reactivity have made these systems very challenging to study experimentally under static high P-T conditions. In the last few years, a large effort has been undertaken by several groups around the world [2] to extend the static and dynamic techniques to high temperatures and pressures, a program in which our group has been actively involved [3-6]. However, while the structure of water and other hydrogenated liquids of geological interest, is now known up to almost 20 GPa, the study of their transport properties greatly lags behind. We have recently developed a new large-volume gasket-anvil ensemble for the Paris-Edinburgh press based on a novel toroidal design [7], which allows to perform quasi elastic neutron scattering measurements on hydrogen based liquids up to one order of magnitude higher pressures (5 GPa) respect to what was achievable with standard methods [8]. The large

  12. Effects of high pressure in liquid chromatography

    SciTech Connect

    Martin, Michel; Guiochon, Georges A

    2005-08-01

    All the experimental parameters that the chromatographers are used to consider as constant (the column length and its diameter, the particle size, the column porosities, the phase ratio, the column hold-up volume, the pressure gradient along the column, the mobile phase density and its viscosity, the diffusion coefficients, the equilibrium constants, the retention factors, the efficiency parameters) depend on pressure to some extent. While this dependence is negligible as long as experiments, measurements, and separations are carried out under conventional pressures not exceeding a few tens of megapascal, it is no longer so when the inlet pressure becomes much larger and exceeds 100 MPa. Equations are developed to determine the extent of the influence of pressure on all these parameters and to account for it. The results obtained are illustrated with graphics. The essential results are that (1) many parameters depend on the inlet pressure, hence on the flow rate; (2) the apparent reproducibility of parameters as simple as the retention factor will be poor if measurements are carried out at different flow rates, unless due corrections are applied to the results; (3) the influence of the temperature on the equilibrium constants should be studied under constant inlet pressure rather than at a constant flow rate, to minimize the coupling effect of pressure and temperature through the temperature dependence of the viscosity; and (4) while reproducibility of results obtained at constant pressure and flow rate will not be affected, method development becomes far more complex because of the pressure dependence of everything.

  13. High Pressure Rotary Shaft Sealing Mechanism

    DOEpatents

    Dietle, Lannie; Gobeli, Jeffrey D.

    2001-05-08

    A laterally translatable pressure staged rotary shaft sealing mechanism having a seal housing with a shaft passage therein being exposed to a fluid pressure P1 and with a rotary shaft being located within the shaft passage. At least one annular laterally translatable seal carrier is provided. First and second annular resilient sealing elements are supported in axially spaced relation by the annular seal carriers and have sealing relation with the rotary shaft. The seal housing and at least one seal carrier define a first pressure staging chamber exposed to the first annular resilient sealing element and a second pressure staging chamber located between and exposed to the first and second annular resilient sealing elements. A first fluid is circulated to the first pressure chamber at a pressure P1, and a second staging pressure fluid is circulated to the second pressure chamber at a fraction of pressure P1 to achieve pressure staging, cooling of the seals. Seal placement provides hydraulic force balancing of the annular seal carriers.

  14. PS foams at high pressure drop rates

    NASA Astrophysics Data System (ADS)

    Tammaro, Daniele; De Maio, Attilio; Carbone, Maria Giovanna Pastore; Di Maio, Ernesto; Iannace, Salvatore

    2014-05-01

    In this paper, we report data on PS foamed at 100 °C after CO2 saturation at 10 MPa in a new physical foaming batch that achieves pressure drop rates up to 120 MPa/s. Results show how average cell size of the foam nicely fit a linear behavior with the pressure drop rate in a double logarithmic plot. Furthermore, foam density initially decreases with the pressure drop rate, attaining a constant value at pressure drop rates higher than 40 MPa/s. Interestingly, furthermore, we observed that the shape of the pressure release curve has a large effect on the final foam morphology, as observed in tests in which the maximum pressure release rate was kept constant but the shape of the curve changed. These results allow for a fine tuning of the foam density and morphology for specific applications.

  15. Calculating Mass Diffusion in High-Pressure Binary Fluids

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Harstad, Kenneth

    2004-01-01

    A comprehensive mathematical model of mass diffusion has been developed for binary fluids at high pressures, including critical and supercritical pressures. Heretofore, diverse expressions, valid for limited parameter ranges, have been used to correlate high-pressure binary mass-diffusion-coefficient data. This model will likely be especially useful in the computational simulation and analysis of combustion phenomena in diesel engines, gas turbines, and liquid rocket engines, wherein mass diffusion at high pressure plays a major role.

  16. High-pressure Raman spectroscopy of carbon onions and nanocapsules

    NASA Astrophysics Data System (ADS)

    Guo, J. J.; Liu, G. H.; Wang, X. M.; Fujita, T.; Xu, B. S.; Chen, M. W.

    2009-08-01

    We report high-pressure Raman spectra of carbon onions and nanocapsules investigated by diamond anvil cell experiments. The pressure coefficient and elastic behavior of carbon onions and nanocapsules are found to be very similar to those of multiwall carbon nanotubes. Additionally, detectable structure changes, particularly the collapse of the concentric graphite structure, cannot been seen at pressures as high as ˜20 GPa, demonstrating that carbon onions and nanocapsules have significant hardness and can sustain very high pressures.

  17. High pressure, high-temperature vessel, especially for nuclear reactors

    SciTech Connect

    Mitterbacher, P.; Schoning, J.; Schwiers, H.G.

    1980-09-23

    A pressure vessel susceptible to high temperatures, especially for containment of a nuclear-reactor core, is constituted of a cylindrical shell from a cast material such as cast steel, cast iron or concrete, and is prestressed by vertical cables which extend parallel to generatrices of the shell. Peripheral (Circumferential) prestressing cables are provided around the shell which can be externally insulated. The peripheral tensioning cables are exposed externally of the insulation material and bear upon the shell of the vessel with heatresistant elements of high compressive strength which extend through the external insulation.

  18. Pargasite at high pressure and temperature

    NASA Astrophysics Data System (ADS)

    Comboni, Davide; Lotti, Paolo; Gatta, G. Diego; Merlini, Marco; Liermann, Hanns-Peter; Frost, Daniel J.

    2017-08-01

    The P-T phase stability field, the thermoelastic behavior and the P-induced deformation mechanisms at the atomic scale of pargasite crystals, from the "phlogopite peridotite unit" of the Finero mafic-ultramafic complex (Ivrea-Verbano Formation, Italy), have been investigated by a series of in situ experiments: (a) at high pressure (up to 20.1 GPa), by single-crystal synchrotron X-ray diffraction with a diamond anvil cell, (b) at high temperature (up to 823 K), by powder synchrotron X-ray diffraction using a hot air blower device, and (c) at simultaneous HP-HT conditions, by single-crystal synchrotron X-ray diffraction with a resistive-heated diamond anvil cell (P max = 16.5 GPa, T max = 1200 K). No phase transition has been observed within the P-T range investigated. At ambient T, the refined compressional parameters, calculated by fitting a second-order Birch-Murnaghan Equation of State (BM-EoS), are: V 0 = 915.2(8) Å3 and K P0,T0 = 95(2) GPa (β P0,T0 = 0.0121(2) GPa-1) for the unit-cell volume; a 0 = 9.909(4) Å and K(a) P0,T0 = 76(2) GPa for the a-axis; b 0 = 18.066(7) Å and K(b) P0,T0 = 111(2) GPa for the b-axis; c 0 = 5.299(5) Å and K(c) P0,T0 = 122(12) GPa for the c-axis [K(c) P0,T0 K(b) P0,T0 > K(a) P0,T0]. The high-pressure structure refinements (at ambient T) show a moderate contraction of the TO4 double chain and a decrease of its bending in response to the hydrostatic compression, along with a pronounced compressibility of the A- and M(4)-polyhedra [K P0, T0(A) = 38(2) GPa, K P0, T0(M4) = 79(5) GPa] if compared to the M(1)-, M(2)-, M(3)-octahedra [K P0, T0(M1,2,3) ≤ 120 GPa] and to the rigid tetrahedra [K P0, T0(T1,T2) 300 GPa]. The thermal behavior, at ambient pressure up to 823 K, was modelled with Berman's formalism, which gives: V 0 = 909.1(2) Å3, α0 = 2.7(2)·10-5 K-1 and α1 = 1.4(6)·10-9 K-2 [with α0(a) = 0.47(6)·10-5 K-1, α0(b) = 1.07(4)·10-5 K-1, and α0(c) = 0.97(7)·10-5 K-1]. The petrological implications for the experimental

  19. Numerical simulation of high pressure water jet impacting concrete

    NASA Astrophysics Data System (ADS)

    Liu, Jialiang; Wang, Mengjin; Zhang, Di

    2017-08-01

    High pressure water jet technology is an unconventional concrete crushing technology. In order to reveal the mechanism of high pressure water jet impacting concrete, it built a three-dimensional numerical model of high pressure water jet impacting concrete based on fluid mechanics and damage mechanics. And the numerical model was verified by theoretical analysis and experiments. Based on this model, it studied the stress characteristics in concrete under high pressure water jet impacting at different time, and quantified the damage evolution rules in concrete along the water jet radial direction. The results can provide theoretical basis and guidance for the high pressure water jet crushing concrete technology.

  20. High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds

    SciTech Connect

    John C. Chen; Vinayak N. Kabadi

    1998-11-12

    The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography.

  1. High-temperature, high-pressure optical cells

    NASA Technical Reports Server (NTRS)

    Holland, L. R.; Smith, R.; Harris, R. P.

    1983-01-01

    For measuring the thermal diffusivity of HgCdTe melts by the laser-pulse method, an infrared transparent cell with flat windows of sufficient strength to withstand the high-vapor pressure of mercury had to be developed. Since mercury telluride expands on freezing, certain difficulties arose in returning the cell to room temperature without cracking it. T08 commercial fused silica is used in the construction of the cell, and the cells are transparent for wavelengths from about 3.5 microns in the infrared to 260 nm in the ultraviolet. The construction procedure for the required cells has been laborious. However, the obtained cell has routinely withstood internal pressures in excess of 60 atm at 900 C. Attention is given to the design of the windows, aspects of cell construction, and questions of loading.

  2. Development of Enhanced Capacity Affinity Microcolumns by using a Hybrid of Protein Cross-linking/Modification and Immobilization

    PubMed Central

    Zheng, Xiwei; Podariu, Maria; Bi, Cong; Hage, David S.

    2015-01-01

    A hybrid method was examined for increasing the binding capacity and activity of protein-based affinity columns by using a combination of protein cross-linking/modification and covalent immobilization. Various applications of this approach in the study of drug-protein interactions and in use with affinity microcolumns were considered. Human serum albumin (HSA) was utilized as a model protein for this work. Bismaleimidohexane (BMH, a homobifunctional maleimide) was used to modify and/or cross-link HSA through the single free sulfhydryl group that is present on this protein. Up to a 75-113% increase in protein content was obtained when comparing affinity supports that were prepared with BMH versus reference supports that were made by using only covalent immobilization. Several drugs that are known to bind HSA (e.g., warfarin, verapamil and carbamazepine) were further found to have a significant increase in retention on HSA microcolumns that were treated with BMH (i.e., a 70-100% increase in protein-based retention). These BMH-treated HSA microcolumns were used in chiral separations and in ultrafast affinity extraction to measure free drug fractions in drug/protein mixtures, with the latter method giving association equilibrium constants that had good agreement with literature values. In addition, it was found that the reversible binding of HSA with ethacrynic acid, an agent that can combine irreversibly with the free sulfhydryl group on this protein, could be examined by using the BMH-treated HSA microcolumns. The same hybrid immobilization method could be extended to other proteins or alternative applications that may require protein-based affinity columns with enhanced binding capacities and activities. PMID:25981291

  3. High Blood Pressure and Kidney Disease

    MedlinePlus

    ... Kidney disease is diagnosed with urine and blood tests. Health care providers measure blood pressure with a blood pressure ... the sample to a lab for analysis. A health care provider may order a blood test to estimate how much blood the kidneys filter ...

  4. Single stage high pressure centrifugal slurry pump

    DOEpatents

    Meyer, John W.; Bonin, John H.; Daniel, Arnold D.

    1984-03-27

    Apparatus is shown for feeding a slurry to a pressurized housing. An impeller that includes radial passages is mounted in the loose fitting housing. The impeller hub is connected to a drive means and a slurry supply means which extends through the housing. Pressured gas is fed into the housing for substantially enveloping the impeller in a bubble of gas.

  5. Studies on droplet evaporation and combustion in high pressures

    NASA Technical Reports Server (NTRS)

    Sato, J.

    1993-01-01

    High pressure droplet evaporation and combustion have been studied up to 15 MPa under normal and microgravity fields. From the evaporation studies, it has been found that in the supercritical environments, the droplet evaporation rate and lifetime take a maximum and a minimum at an ambient pressure over the critical pressure. Its maximum and minimum points move toward the lower ambient pressures if the ambient temperature is increased. It has been found from the combustion studies that the burning life time takes a minimum at an ambient pressure being equal to the critical pressure. It is attributable to both the pressure dependency of the diffusion rate and the droplet evaporation characteristics described above.

  6. Superconductivity in the metallic elements at high pressures

    NASA Astrophysics Data System (ADS)

    Hamlin, J. J.

    2015-07-01

    Although the highest superconducting critical temperature, Tc , found in an elemental solid at ambient pressure is 9.2 K (niobium), under the application of ultra-high pressures, several elements exhibit Tc values near or above 20 K. This review includes a survey of the occurrence and understanding of pressure-induced superconductivity in the subset of elements that are metallic at ambient pressure. A particular focus is directed towards those elements that display the highest superconducting critical temperatures or exhibit substantial increases in Tc with pressure. A separate article in this issue by Shimizu will cover pressure-induced superconductivity in elements that are insulating at ambient pressure.

  7. Automated high pressure cell for pressure jump x-ray diffraction

    SciTech Connect

    Brooks, Nicholas J.; Gauthe, Beatrice L. L. E.; Templer, Richard H.; Ces, Oscar; Seddon, John M.; Terrill, Nick J.; Rogers, Sarah E.

    2010-06-15

    A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

  8. Automated high pressure cell for pressure jump x-ray diffraction.

    PubMed

    Brooks, Nicholas J; Gauthe, Beatrice L L E; Terrill, Nick J; Rogers, Sarah E; Templer, Richard H; Ces, Oscar; Seddon, John M

    2010-06-01

    A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

  9. 76 FR 38697 - High Pressure Steel Cylinders From China

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-01

    ... COMMISSION High Pressure Steel Cylinders From China Determinations On the basis of the record \\1\\ developed... injured by reason of imports from China of high pressure steel cylinders, provided for in subheading 7311... pressure steel cylinders from China. Accordingly, effective May 11, 2011, the Commission...

  10. Equation of state of unreacted high explosives at high pressures

    SciTech Connect

    Yoo, C-S

    1998-08-14

    Isotherms of unreacted high explosives (HMX, RDX, and PETN) have been determined to quasi-hydrostatic high pressures below 45 GPa, by using a diamond-anvil cell angle-resolved synchrotron x-ray diffraction method. The equation-of-state parameters (bulk modulus Bo, and its derivatives B' ) are presented for the 3rd-order Birch-Murnaghan formula based on the measured isotherms. The results are also used to retrieve unreacted Hugoniots in these high explosives and to develop the equations of state and kinetic models for composite high explolsivcs such as XTX-8003 and LX-04. The evidence of shear-induced chemistry of HMX in non-hydrostatic conditions is also presented.

  11. High pressure waterjet cutting industrial needs survey

    NASA Astrophysics Data System (ADS)

    Klavuhn, John; Baker, Bruce

    1989-08-01

    The results are presented of a survey conducted by personnel of the National Center for Excellence in Metalworking Technology (NCEMT) to assess the industrial needs in high pressure water jet cutting (WJC) technology. Survey forms were mailed to approximately 1400 individuals obtained from three mailing lists. The respondents included approximately 200 individuals associated with a variety of industries: 12 percent were WJC equipment suppliers, 40 percent were WJC users, and 48 percent were neither suppliers nor users. The survey addressed five specific areas of WJC technology: research and development, standards, systems, new products, and training and service. Results show that the need having the highest priority is the establishment of a database on WJC that contains the cutting parameters for a wide range of materials. Associated with this objective is the expressed need for an independent demonstration and test center for testing, data generation and operator training. A further need was found for establishing organized efforts in hardware development and research in mechanisms of cutting.

  12. 9. General view of engine between cylinders with high pressure ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. General view of engine between cylinders with high pressure cylinder on left and low pressure cylinder on right. - Carnegie Steel-Ohio Works, Steam Engines, 912 Salt Springs Road, Youngstown, Mahoning County, OH

  13. How High Blood Pressure Can Lead to Stroke

    MedlinePlus

    ... Thromboembolism Aortic Aneurysm More How High Blood Pressure Can Lead to Stroke Updated:May 3,2017 Stroke ... your risk of stroke by understanding those you can control. Popular Articles 1 Understanding Blood Pressure Readings ...

  14. Single-molecule imaging at high hydrostatic pressure

    NASA Astrophysics Data System (ADS)

    Vass, Hugh; Lucas Black, S.; Flors, Cristina; Lloyd, Diarmuid; Bruce Ward, F.; Allen, Rosalind J.

    2013-04-01

    Direct microscopic fluorescence imaging of single molecules can provide a wealth of mechanistic information, but up to now, it has not been possible under high pressure conditions, due to limitations in microscope pressure cell design. We describe a pressure cell window design that makes it possible to image directly single molecules at high hydrostatic pressure. We demonstrate our design by imaging single molecules of Alexa Fluor 647 dye bound to DNA, at 120 and 210 bar, and following their fluorescence photodynamics. We further show that the failure pressure of this type of pressure cell window can be in excess of 1 kbar.

  15. Imaging in (high pressure) Micromegas TPC detectors

    NASA Astrophysics Data System (ADS)

    Luzón, G.; Cebrián, S.; Castel, J.; Dafni, Th.; Galán, J.; Garza, J. G.; Irastorza, I. G.; Iguaz, F. J.; Mirallas, H.; Ruíz-Choliz, E.

    2016-11-01

    The T-REX project of the group of the University of Zaragoza includes a number of R&D and prototyping activities to explore the applicability of gaseous Time Projection Chambers (TPCs) with Micromesh Gas Structures (Micromegas) in rare event searches where the pattern recognition of the signal is crucial for background discrimination. In the CAST experiment (CERN Axion Solar Telescope) a background level as low as 0.8 × 10-6 counts keV-1 cm-2 s-1 was achieved. Prototyping and simulations promise a 105 better signal-to-noise ratio than CAST for the future IAXO (International Axion Observatory) using x-ray telescopes. A new strategy is also explored in the search of WIMPS based on high gas pressure: the TREX-DM experiment, a low energy threshold detector. In both cases, axion and WIMP searches, the image of the expected signal is quite simple: a one cluster deposition coming from the magnet bore in the case of axions and, if possible, with a tadpole form in the case of WIMPs. It is the case of double beta decay (DBD) where imaging and pattern recognition play a major role. Results obtained in Xe + trimethylamine (TMA) mixture point to a reduction in electron diffusion which improves the quality of the topological pattern, with a positive impact on the discrimination capability, as shown in TREX-ββ prototype. Microbulk Micromegas are able to image the DBD ionization signature with high quality while, at the same time, measuring its energy deposition with a resolution of at least a ~ 3% FWHM at the transition energy Qββ and even better (up to ~ 1% FWHM) as extrapolated from low energy events. That makes Micromegas-based HPXe TPC a very competitive technique for the next generation DBD experiments (as PANDAX-III). Here, it will be shown the last results of the TREX project detectors and software concerning Axions, Dark matter and double beta decay.

  16. Bacillus spore inactivation differences after combined mild temperature and high pressure processing using two pressurizing fluids.

    PubMed

    Robertson, Rosalind E; Carroll, Tim; Pearce, Lindsay E

    2008-06-01

    Spores of six species (28 strains) of dairy Bacillus isolates were added to sterile reconstituted skim milk and pressure processed (600 MPa for 60 s at 75 degrees C) using either a water-based pressurizing fluid or silicon oil. Processing temperatures peaked at 88 and 90 degrees C, respectively, for both fluids. For all strains, the log inactivation was consistently higher in the silicon oil than in the water-based fluid. This has potential implications for food safety assessment of combined pressure-temperature processes. High pressure processing causes mild heating during pressurization of both the target sample (i.e., spores) and the pressurizing fluid used for pressure delivery. Primarily, the adiabatic heat of compression of the fluids as well as other heat-transfer properties of the fluids and equipment determines the magnitude of this heating. Pressure cycles run with silicon oil were 7 to 15 degrees C higher in temperature during pressurization than pressure cycles run with the water-based pressurizing fluid, due to the greater adiabatic heat of compression of silicon oil. At and around the target pressure, however, the temperatures of both pressurizing fluids were similar, and they both dropped at the same rate during the holding time at the target pressure. We propose that the increased spore inactivation in the silicon oil system can be attributed to additional heating of the spore preparation when pressurized in oil. This could be explained by the temperature difference between the silicon oil and the aqueous spore preparation established during the pressurization phase of the pressure cycle. These spore-inactivation differences have practical implications because it is common practice to develop inactivation kinetic data on small, jacketed laboratory systems pressurized in oil, with extensive heat loss. However, commercial deployment is invariably on large industrial systems pressurized in water, with limited heat loss. Such effects should be

  17. A control system for maintaining high stability in gas pressure

    SciTech Connect

    Wuest, C.R.; Hendricks, C.D.

    1987-09-01

    A pressure control system has been implemented on an experiment designed to detect the presence of fractional charges in bulk matter. The experiment utilizes a liquid-droplet generation technique requiring high-stability gas-pressure delivery to ensure accurate data collection. The pressure control system consists of a pressurized mercury reservoir containing a low-vapor-pressure, diffusion-pump oil. A commercially available differential pressure transducer, servo-driven valve, and controller sense the pressure fluctuations with respect to a static reference pressure. The system can maintain constant pressure to better than one part in 10,000 at working pressures in the range of 100 to 300 psi. 3 refs., 7 figs.

  18. High-pressure synthesis of lithium hydride

    NASA Astrophysics Data System (ADS)

    Howie, Ross T.; Narygina, Olga; Guillaume, Christophe L.; Evans, Shaun; Gregoryanz, Eugene

    2012-08-01

    By compressing elemental lithium and hydrogen in a diamond anvil cell, we have synthesized lithium hydride (LiH) at pressures as low as 50 MPa at room temperature. Combined Raman spectroscopy and synchrotron x-ray diffraction measurements reveal that, once synthesized, LiH remains stable at 300 K up to 160 GPa in the presence of molecular hydrogen. The mixture of lithium hydride and molecular hydrogen and application of pressure alone cannot form a higher H2 content hydride (LiHx, x>1) as was suggested from the theoretical ab initio calculations and therefore, cannot be considered as a route to low-pressure hydrogen rich material metallization.

  19. Elastic properties of anorthite at high temperature and high pressure

    NASA Astrophysics Data System (ADS)

    Matsukage, K. N.; Nishihara, Y.; Noritake, F.; Tsujino, N.; Sakurai, M.; Higo, Y.; Kawamura, K.; Takahashi, E.

    2012-12-01

    To understand the elastic properties of subducted crustal minerals at P-T conditions of crust and upper most mantle, we performed in situ measurement of the elastic wave velocities of anorthite at temperatures up to 1100 oC at less than 2.0 GPa (in stability field) and up to 500 oC at 2.0-7.0 GPa. A fine grained polycrystalline anorthite was synthesised by using gas pressure apparatus installed at magma factory in Tokyo Institute of Technology. The quenched glass with anorthite composition was ground in ethanol and was loaded into a sealed Pt tube (3.0 mm inner diameter and 0.2 mm thickness) container. The sample was preheated at 900°C for 2 hours, and then keep at 1100°C for 20 hours at pressure of 0.3 GPa. The maximum grain size of the synthesized polycrystalline anorthite was about 15μm. The experiments were performed using the SPEED-1500 apparatus installed on beam line BL04B1 at synchrotron facility of SPring-8, Japan (Utsumi et al. 1998). The experimental design for in situ elastic wave velocities measurement at BL04B1 was presented by Higo et al. (2009). Pressure was generated by eight 26 mm tungsten carbide anvils with 11 mm truncated edge length. A Co-doped semi-sintered MgO octahedron with an 18 mm edge length was used as a pressure medium. The sample was enclosed in a BN sleeve container, and was placed in the central part (hot spot) of the furnace. Platinum foils (2.5 μm in thickness) were inserted at the both side of the sample for determination of sample length by using X-ray radiographic imaging techniques. An Al2O3 rod (5.3 mm in length and 2.0 mm in diameter) was used as buffer rod which transmit ultrasonic wave to the sample. Temperature was measured by a W97Re3-W75Re25 thermocouple. MgO was used as a pressure marker, and it was mixed with BN (MgO:BN = 1:1 by weight) to prevent grain growth at high temperatures. The ultrasonic signals were generated and received by 10oY-cut LiNbO3 transducer of 50 μm in thickness and 3.2 mm in diameter. We

  20. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    SciTech Connect

    Vinayak N. Kabadi

    1999-02-20

    It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

  1. Hydraulic High Pressure Valve Controller Using the In-Situ Pressure Difference

    NASA Technical Reports Server (NTRS)

    Bao, Xiaoqi (Inventor); Sherrit, Stewart (Inventor); Badescu, Mircea (Inventor); Bar-Cohen, Yoseph (Inventor); Hall, Jeffery L. (Inventor)

    2016-01-01

    A hydraulic valve controller that uses an existing pressure differential as some or all of the power source for valve operation. In a high pressure environment, such as downhole in an oil or gas well, the pressure differential between the inside of a pipe and the outside of the pipe may be adequately large to drive a linear slide valve. The valve is operated hydraulically by a piston in a bore. When a higher pressure is applied to one end of the bore and a lower pressure to the other end, the piston moves in response to the pressure differential and drives a valve attached to it. If the pressure differential is too small to drive the piston at a sufficiently high speed, a pump is provided to generate a larger pressure differential to be applied. The apparatus is conveniently constructed using multiport valves, which can be rotary valves.

  2. What Is High Blood Pressure Medicine?

    MedlinePlus

    ... make the other lifestyle changes that will help reduce blood pressure, including: reaching and maintaining a healthy weight, lowering sodium (salt) intake, eating a heart-healthy diet, being more regularly physically active, and limiting alcohol ...

  3. Propagation Limits of High Pressure Cool Flames

    NASA Astrophysics Data System (ADS)

    Ju, Yiguang

    2016-11-01

    The flame speeds and propagation limits of premixed cool flames at elevated pressures with radiative heat loss are numerically modelled using dimethyl ether mixtures. The primary focus is paid on the effects of pressure, mixture dilution, flame size, and heat loss on cool flame propagation. The results showed that cool flames exist on both fuel lean and fuel rich sides and thus dramatically extend the lean and rich flammability limits. There exist three different flame regimes, hot flame, cool flame, and double flame. A new flame flammability diagram including both cool flames and hot flames is obtained at elevated pressure. The results show that pressure significantly changes cool flame propagation. It is found that the increases of pressure affects the propagation speeds of lean and rich cool flames differently due to the negative temperature coefficient effect. On the lean side, the increase of pressure accelerates the cool flame chemistry and shifts the transition limit of cool flame to hot flame to lower equivalence ratio. At lower pressure, there is an extinction transition from hot flame to cool flame. However, there exists a critical pressure above which the cool flame to hot flame transition limit merges with the lean flammability limit of the hot flame, resulting in a direct transition from hot flame to cool flame. On the other hand, the increase of dilution reduces the heat release of hot flame and promotes cool flame formation. Moreover, it is shown that a smaller flame size and a higher heat loss also extend the cool flame transition limit and promote cool flame formation.

  4. Development of high pressure gas cells at ISIS

    NASA Astrophysics Data System (ADS)

    Kirichek, O.; Done, R.; Goodway, C. M.; Kibble, M. G.; Evans, B.; Bowden, Z. A.

    2012-02-01

    High-pressure research is one of the fastest-growing areas of natural science, and one that attracts as diverse communities as those of physics, bio-physics, chemistry, materials science and earth science. In condensed matter physics there are a number of highly topical areas, such as quantum criticality, pressure-induced superconductivity or non-Fermi liquid behaviour, where pressure is a fundamental parameter. Reliable, safe and user-friendly high pressure gas handling systems with gas pressures up to 1GPa should make a significant impact on the range of science possible. The ISIS facility is participating in the NMI3 FP7 sample environment project supported by the European Commission which includes high pressure gas cell development. In this paper the progress in designing, manufacturing and testing a new generation of high pressure gas cells for neutron scattering experiments is discussed.

  5. An accuracy statement for a facility used to calibrate static pressure transducers and differential pressure transducers at high base pressure

    NASA Astrophysics Data System (ADS)

    Sindt, C. F.; Labrecque, J. F.

    1982-06-01

    A facility was developed to calibrate pressure transducers that are used in a gas mass flow facility. Both static and differential pressure transducers can be calibrated. An air dead weight tester is the standard for static transducers in the range from 3.8 to 4.5 MPa. An air dead weight tester is also the standard for the differential pressure transducers in the range of 2.5 kPa to 50 MPa; a cistern manometer. This, plus the uncertainties in the high pressure corrections to the cistern manometer and measurement of the mercury temperature, contributes plus or minus 690 ppm to the uncertainty of the differential pressure transducer calibrations.

  6. Osmium Metal Studied under High Pressure and Nonhydrostatic Stress

    SciTech Connect

    Weinberger,M.; Tolbert, S.; Kavner, A.

    2008-01-01

    Interest in osmium as an ultra-incompressible material and as an analog for the behavior of iron at high pressure has inspired recent studies of its mechanical properties. We have measured elastic and plastic deformation of Os metal at high pressures using in situ high pressure x-ray diffraction in the radial geometry. We show that Os has the highest yield strength observed for any pure metal, supporting up to 10 GPa at a pressure of 26 GPa. Furthermore, our data indicate changes in the nonhydrostatic apparent c/a ratio and clear lattice preferred orientation effects at pressures above 15 GPa.

  7. Studies of basic mechanisms in high pressure gases: Applications to high efficiency high power lasers

    NASA Technical Reports Server (NTRS)

    Verdeyen, J. T.; Cherrington, B. E.; Leslie, S. G.; Millar, W. S.; Edwards, B. E.

    1976-01-01

    A high power pulsed dye laser was used to optically excite high pressure cesium-xenon mixtures and the resulting measurements are presented. A microwave discharge in rubidium at relatively high xenon pressure was achieved. Preliminary studies of cadium-rare gas mixtures are discussed and a detailed description of the entire experimental apparatus is given.

  8. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    SciTech Connect

    Vinayak N. Kabadi

    2000-05-01

    The Vapor Liquid Equilibrium measurement setup of this work was first established several years ago. It is a flow type high temperature high pressure apparatus which was designed to operate below 500 C temperature and 2000 psia pressure. Compared with the static method, this method has three major advantages: the first is that large quantity of sample can be obtained from the system without disturbing the equilibrium state which was established before; the second is that the residence time of the sample in the equilibrium cell is greatly reduced, thus decomposition or contamination of the sample can be effectively prevented; the third is that the flow system allows the sample to degas as it heats up since any non condensable gas will exit in the vapor stream, accumulate in the vapor condenser, and not be recirculated. The first few runs were made with Quinoline-Tetralin system, the results were fairly in agreement with the literature data . The former graduate student Amad used the same apparatus acquired the Benzene-Ethylbenzene system VLE data. This work used basically the same setup (several modifications had been made) to get the VLE data of Ethylbenzene-Quinoline system.

  9. Molecular dynamics simulation of solvated protein at high pressure.

    PubMed

    Kitchen, D B; Reed, L H; Levy, R M

    1992-10-20

    We have completed a molecular dynamics simulation of protein (bovine pancreatic trypsin inhibitor, BPTI) in solution at high pressure (10 kbar). The structural and energetic effects of the application of high pressure to solvated protein are analyzed by comparing the results of the high-pressure simulation with a corresponding simulation at low pressure. The volume of the simulation cell containing one protein molecule plus 2943 water molecules decreases by 24.7% at high pressure. This corresponds to a compressibility for the protein solution of beta = 1.8 x 10(-2) kbar-1. The compressibility of the protein is estimated to be about one-tenth that of bulk water, while the protein hydration layer water is found to have a greater compressibility as compared to the bulk, especially for water associated with hydrophobic groups. The radius of gyration of BPTI decreases by 2% and there is a one third decrease in the protein backbone atomic fluctuations at high pressure. We have analyzed pressure effects on the hydration energy of the protein. The total hydration energy is slightly (4%) more favorable at high pressure even though the surface accessibility of the protein has decreased by a corresponding amount. Large pressure-induced changes in the structure of the hydration shell are observed. Overall, the solvation shell waters appear more ordered at high pressure; the pressure-induced ordering is greatest for nonpolar surface groups. We do not observe evidence of pressure-induced unfolding of the protein over the 100-ps duration of the high-pressure simulation. This is consistent with the results of high-pressure optical experiments on BPTI.(ABSTRACT TRUNCATED AT 250 WORDS)

  10. High-temperature, high-pressure optical cell

    NASA Technical Reports Server (NTRS)

    Harris, R. P. (Inventor); Holland, L. R. (Inventor); Smith, R. E. (Inventor)

    1986-01-01

    The invention is an optical cell for containment of chemicals under conditions of high temperature and high pressure. The cell is formed of a vitreous silica tube, two optical windows comprising a vitreous silica rod inserted into the ends of a tube, and fused into position in the tube ends. Windows are spaced apart to form a cavity enclosed by the tube and the windows. A hole is drilled radially through the tube and into the cavity. Another vitreous silica tube is fused to the silica tube around the hole to form the stem, which is perpendicular to the long axis of the tube. The open end of the stem is used to load chemicals into the cavity. Then the stem may be sealed, and if desired, it may be shortened in order to reduce the volume of the cavity, which extends into the stem.

  11. High-pressure vibrational properties of polyethylene

    NASA Astrophysics Data System (ADS)

    Fontana, Luca; Santoro, Mario; Bini, Roberto; Vinh, Diep Q.; Scandolo, Sandro

    2010-11-01

    The pressure evolution of the vibrational spectrum of polyethylene was investigated up to 50 GPa along different isotherms by Fourier-transform infrared and Raman spectroscopy and at 0 K by density-functional theory calculations. The infrared data allow for the detection of the orthorhombic Pnam to monoclinic P21/m phase transition which is characterized by a strong hysteresis both on compression and decompression experiments. However, an upper and lower boundary for the transition pressure are identified. An even more pronounced hysteresis is observed for the higher-pressure transition to the monoclinic A2/m phase. The hysteresis does not allow in this case the determination of a well defined P-T transition line. The ambient structural properties of polyethylene are fully recovered after compression/decompression cycles indicating that the polymer is structurally and chemically stable up to 50 GPa. A phase diagram of polyethylene up to 50 GPa and 650 K is proposed. Analysis of the pressure evolution of the Davydov splittings and of the anomalous intensification with pressure of the IR active wagging mode provides insight about the nature of the intermolecular interactions in crystalline polyethylene.

  12. High pressure/high temperature thermogravimetric apparatus. Final report

    SciTech Connect

    Calo, J.M.; Suuberg, E.M.

    1999-12-01

    The purpose of this instrumentation grant was to acquire a state-of-the-art, high pressure, high temperature thermogravimetric apparatus (HP/HT TGA) system for the study of the interactions between gases and carbonaceous solids for the purpose of solving problems related to coal utilization and applications of carbon materials. The instrument that we identified for this purpose was manufactured by DMT (Deutsche Montan Technologies)--Institute of Cokemaking and Coal Chemistry of Essen, Germany. Particular features of note include: Two reactors: a standard TGA reactor, capable of 1100 C at 100 bar; and a high temperature (HT) reactor, capable of operation at 1600 C and 100 bar; A steam generator capable of generating steam to 100 bar; Flow controllers and gas mixing system for up to three reaction gases, plus a separate circuit for steam, and another for purge gas; and An automated software system for data acquisition and control. The HP/TP DMT-TGA apparatus was purchased in 1996 and installed and commissioned during the summer of 1996. The apparatus was located in Room 128 of the Prince Engineering Building at Brown University. A hydrogen alarm and vent system were added for safety considerations. The system has been interfaced to an Ametek quadruple mass spectrometer (MA 100), pumped by a Varian V250 turbomolecular pump, as provided for in the original proposed. With this capability, a number of gas phase species of interest can be monitored in a near-simultaneous fashion. The MS can be used in a few different modes. During high pressure, steady-state gasification experiments, it is used to sample, measure, and monitor the reactant/product gases. It can also be used to monitor gas phase species during nonisothermal temperature programmed reaction (TPR) or temperature programmed desorption (TPD) experiments.

  13. High pressure (>1 atm) electrospray ionization mass spectrometry.

    PubMed

    Chen, Lee Chuin; Mandal, Mridul Kanti; Hiraoka, Kenzo

    2011-03-01

    High pressure electrospray ionization mass spectrometry has been performed by pressurizing a custom made ion source chamber with compressed air to a pressure higher than the atmospheric pressure. The ion source was coupled to a commercial time-of-flight mass spectrometer using a nozzle-skimmer arrangement. The onset voltage for the electrospray of aqueous solution was found to be independent on the operating pressure. The onset voltage for the corona discharge, however, increased with the rise of pressure following the Paschen's law. Thus, besides having more working gas for the desolvation process, gaseous breakdown could also be avoided by pressurizing the ESI ion source with air to an appropriate level. Stable electrospray ionization has been achieved for the sample solution with high surface tension such as pure water in both positive and negative ion modes. Fragmentation of labile compounds during the ionization process could also be reduced by optimizing the operating pressure of the ion source.

  14. High pressure and anesthesia: pressure stimulates or inhibits bacterial bioluminescence depending upon temperature.

    PubMed

    Nosaka, S; Kamaya, H; Ueda, I

    1988-10-01

    Although high pressure is often viewed as a nonspecific stimulus counteracting anesthesia, pressure can either excite or inhibit biological activity depending on the temperature at application. Temperature and pressure are two independent variables that determine equilibrium quantity, e.g., the state of organisms in terms of activity and anesthesia depth. We used the light intensity of luminous bacteria (Vibrio fischeri) as an activity parameter, and studied the effects of pressure and anesthetics on the bacteria's light intensity at various temperatures. The light intensity was greatest at about 30 degrees C at ambient pressure. When the system was pressurized up to 204 atm, the temperature for maximum light intensity was shifted to higher temperatures. Above the optimal temperature for the maximal light intensity, high pressure increased the light intensity. Below the optimal temperature, pressure decreased light intensity. Pressure only shifts the reaction equilibrium to the lower volume state (Le Chatelier's principle). When the volume of the excited state is larger than the resting state, high pressure inhibits excitation, and vice versa. Halothane 0.008 atm and isoflurane 0.021 atm inhibited the light intensity both above and below the optimal temperature. When pressurized, the light intensity increased in the high temperature range but decreased in the low temperature range, as in the control. Thus, high pressure seemingly potentiated the anesthetic action at low temperatures. When the ratio of the light intensity in bacteria exposed to anesthesia and those not exposed to anesthesia was plotted against the pressure, however, the value approached unity in proportion to the pressure increase.(ABSTRACT TRUNCATED AT 250 WORDS)

  15. Elasticity of Mantle Minerals and their High-Pressure Polymorphs at High Pressures and Temperatures

    NASA Astrophysics Data System (ADS)

    Liebermann, R. C.; Li, B.; Kung, J.; Weidner, D. J.

    2002-12-01

    In his 1952 paper, Francis Birch concluded "New phases are required to account for the high elasticity of the deeper part of the mantle (below 900 km), and it is suggested that, beginning at about 200 to 300 km, there is a gradual shift toward high-pressure modifications of the ferro-magnesian silicates, probably close-packed oxides, with the transition complete at about 800 to 900 km." In the subsequent quarter century, experimental evidence for such transitions to high-pressure polymorphs emerged in laboratories around the world, most notably in those of Akimoto in Japan and Ringwood in Australia; these studies confirmed the existence of stable silicate phases with the wadsleyite, ringwoodite, majorite, ilmenite [now akimotoite], and perovskite structures. In the 1970s and 1980s, single crystal and polycrystalline specimens of these high-pressure phases were synthesized, thereby enabling studies of their elastic properties in the laboratory at ambient conditions [see Brillouin studies of the Weidner and Basssett laboratories, and ultrasonic studies by Mizutani and Fujisawa in Japan and Liebermann and colleagues in Australia]. This work often started with experiments on crystal chemical analogues of mantle silicates, following the original suggestions of Goldschmidt and Bernal in the 1930s (repeated by Birch in 1952), and then moved on to the real mantle compositions. Prior to 1988, most of these acoustic experiments were conducted versus presssure at room temperature or versus temperature at room presssure; these conditions fell far short of those achieved in the Earth's mantle. Substantial progress has been made in the past decade, making it feasible to perform acoustic experiments at conditions approaching those for the transition zone (at depths greater than 400 km); this progress has been achieved in many laboratories, including those at the University of Washington, Geophysical Laboratory, Bayreuth Geoinstitut, Nagoya University, Australian National

  16. Announcement: National High Blood Pressure Education Month - May 2016.

    PubMed

    2016-05-27

    May is National High Blood Pressure Education Month. High blood pressure (hypertension) is a major contributor to heart disease and stroke, two leading causes of death in the United States.* High blood pressure affects one third of U.S. adults, or approximately 75 million persons, yet approximately 11 million of these persons are not aware they have hypertension, and approximately 18 million are not being treated (unpublished data) (1,2).

  17. High-pressure magic angle spinning nuclear magnetic resonance

    NASA Astrophysics Data System (ADS)

    Hoyt, David W.; Turcu, Romulus V. F.; Sears, Jesse A.; Rosso, Kevin M.; Burton, Sarah D.; Felmy, Andrew R.; Hu, Jian Zhi

    2011-10-01

    A high-pressure magic angle spinning (MAS) NMR capability, consisting of a reusable high-pressure MAS rotor, a high-pressure rotor loading/reaction chamber for in situ sealing and re-opening of the high-pressure MAS rotor, and a MAS probe with a localized RF coil for background signal suppression, is reported. The unusual technical challenges associated with development of a reusable high-pressure MAS rotor are addressed in part by modifying standard ceramics for the rotor sleeve by abrading the internal surface at both ends of the cylinder. In this way, not only is the advantage of ceramic cylinders for withstanding very high-pressure utilized, but also plastic bushings can be glued tightly in place so that other removable plastic sealing mechanisms/components and O-rings can be mounted to create the desired high-pressure seal. Using this strategy, sealed internal pressures exceeding 150 bars have been achieved and sustained under ambient external pressure with minimal loss of pressure for 72 h. As an application example, in situ13C MAS NMR studies of mineral carbonation reaction intermediates and final products of forsterite (Mg 2SiO 4) reacted with supercritical CO 2 and H 2O at 150 bar and 50 °C are reported, with relevance to geological sequestration of carbon dioxide.

  18. High-pressure magic angle spinning nuclear magnetic resonance.

    PubMed

    Hoyt, David W; Turcu, Romulus V F; Sears, Jesse A; Rosso, Kevin M; Burton, Sarah D; Felmy, Andrew R; Hu, Jian Zhi

    2011-10-01

    A high-pressure magic angle spinning (MAS) NMR capability, consisting of a reusable high-pressure MAS rotor, a high-pressure rotor loading/reaction chamber for in situ sealing and re-opening of the high-pressure MAS rotor, and a MAS probe with a localized RF coil for background signal suppression, is reported. The unusual technical challenges associated with development of a reusable high-pressure MAS rotor are addressed in part by modifying standard ceramics for the rotor sleeve by abrading the internal surface at both ends of the cylinder. In this way, not only is the advantage of ceramic cylinders for withstanding very high-pressure utilized, but also plastic bushings can be glued tightly in place so that other removable plastic sealing mechanisms/components and O-rings can be mounted to create the desired high-pressure seal. Using this strategy, sealed internal pressures exceeding 150 bars have been achieved and sustained under ambient external pressure with minimal loss of pressure for 72 h. As an application example, in situ(13)C MAS NMR studies of mineral carbonation reaction intermediates and final products of forsterite (Mg(2)SiO(4)) reacted with supercritical CO(2) and H(2)O at 150 bar and 50°C are reported, with relevance to geological sequestration of carbon dioxide.

  19. High-pressure magic angle spinning nuclear magnetic resonance

    SciTech Connect

    Hoyt, David W.; Turcu, Romulus V. F.; Sears, Jesse A.; Rosso, Kevin M.; Burton, Sarah D.; Felmy, Andrew R.; Hu, Jian Zhi

    2011-10-01

    A high-pressure magic angle spinning (MAS) NMR capability, consisting of a reusable high-pressure MAS rotor, a high-pressure rotor loading/reaction chamber for in situ sealing and re-opening of the high-pressure MAS rotor, and a MAS probe with a localized RF coil for background signal suppression, is reported. The unusual technical challenges associated with development of a reusable high-pressure MAS rotor are addressed in part by modifying standard ceramics for the rotor sleeve by abrading the internal surface at both ends of the cylinder. In this way, not only is the advantage of ceramic cylinders for withstanding very high-pressure utilized, but also plastic bushings can be glued tightly in place so that other removable plastic sealing mechanisms/components and O-rings can be mounted to create the desired high-pressure seal. Using this strategy, sealed internal pressures exceeding 150 bars have been achieved and sustained under ambient external pressure with minimal loss of pressure for 72 h. Finally, as an application example, in situ13C MAS NMR studies of mineral carbonation reaction intermediates and final products of forsterite (Mg2SiO4) reacted with supercritical CO2 and H2O at 150 bar and 50 °C are reported, with relevance to geological sequestration of carbon dioxide.

  20. Transient High-Pressure Fuel Injection

    NASA Astrophysics Data System (ADS)

    Jarrahbashi, Dorrin

    Break-up and atomization of liquid fuel jet during transient injection process has a significant effect on the Diesel engine combustion efficiency and pollution. The mechanisms responsible for liquid jet instability and break-up at high pressure, during the transient start-up and steady mass flux periods, has been investigated using Navier-Stokes and level-set computations. Via post-processing, the role of vorticity dynamics is examined and shown to reveal crucial new insights. An unsteady, axisymmetric full-jet case is solved. Then, a less computationally intensive case is studied with a segment of the jet core undergoing temporal instability; agreement with the full-jet calculation is satisfactory justifying the segment analysis for three-dimensional computation. The results for surface-shape development are in agreement with experimental observations and other three-dimensional computations; the initial, axisymmetric waves at the jet surface created by Kelvin-Helmholtz instability distort to cone shapes; next, three-dimensional character develops through an azimuthal instability that leads to the creation of streamwise vorticity, lobe shapes on the cones, and formation of liquid ligaments which extend from lobes on the cones. The cause of this azimuthal instability has been widely described as a Rayleigh-Taylor instability. However, additional and sometimes more important causes are identified here. Counter-rotating, streamwise vortices within and around the ligaments show a relationship in the instability behavior for jets flowing into like-density fluid; thus, density difference cannot explain fully the three-dimensional instability as previously suggested. Furthermore, the formation of ligaments that eventually break into droplets and the formation of streamwise vorticity are caused by the same vortical dynamics. Waviness is identified on the ligaments which should result in droplet formation. The nonlinear development of the shorter azimuthal waves and

  1. High temperature pressurized high frequency testing rig and test method

    DOEpatents

    De La Cruz, Jose; Lacey, Paul

    2003-04-15

    An apparatus is described which permits the lubricity of fuel compositions at or near temperatures and pressures experienced by compression ignition fuel injector components during operation in a running engine. The apparatus consists of means to apply a measured force between two surfaces and oscillate them at high frequency while wetted with a sample of the fuel composition heated to an operator selected temperature. Provision is made to permit operation at or near the flash point of the fuel compositions. Additionally a method of using the subject apparatus to simulate ASTM Testing Method D6079 is disclosed, said method involving using the disclosed apparatus to contact the faces of prepared workpieces under a measured load, sealing the workface contact point into the disclosed apparatus while immersing said contact point between said workfaces in a lubricating media to be tested, pressurizing and heating the chamber and thereby the fluid and workfaces therewithin, using the disclosed apparatus to impart a differential linear motion between the workpieces at their contact point until a measurable scar is imparted to at least one workpiece workface, and then evaluating the workface scar.

  2. High-Differential-Pressure Heat Exchanger

    NASA Technical Reports Server (NTRS)

    Hylin, Edward C.

    1987-01-01

    Heat exchanger accommodates large pressure difference between heat-transfer fluids. Designed so all welded joints inspected with x rays to ensure leak-free operation over many years. Joints between fluids and between each fluid and environment radiographically inspectable. Used in Stirling-cycle engines, including those in proposed nuclear and solar powerplants.

  3. The Mechanism of High Pressure Oxidations of Aliphatic Acids.

    DTIC Science & Technology

    ACETIC ACID , *OXIDATION), (*CARBOXYLIC ACIDS, OXIDATION), CHROMIUM ALLOYS, REACTION KINETICS, COPPER ALLOYS, NICKEL ALLOYS, TEMPERATURE, HIGH PRESSURE, CATALYSTS, GAS CHROMATOGRAPHY, VOLUMETRIC ANALYSIS, THESES

  4. CDC Vital Signs: High Blood Pressure and Cholesterol

    MedlinePlus

    ... 1.36 MB] Read the MMWR Science Clips High Blood Pressure and Cholesterol Out of Control Recommend on Facebook ... by County http://apps.nccd.cdc.gov/GISCVH2/ High Blood Pressure and High Cholesterol Among US Adults SOURCES: National ...

  5. High Pressure Inactivation of Food-borne Viruses

    USDA-ARS?s Scientific Manuscript database

    Over the past half dozen years or so, the USDA Seafood Safety laboratory has endeavored to evaluate the potential of high pressure processing (HPP) for inactivation of food-borne viruses. As a commercial food technology, high pressure processing is highly advantageous because it can inactivate path...

  6. Rotating rod renewable microcolumns for automated, solid-phase DNA hybridization studies.

    PubMed

    Bruckner-Lea, C J; Stottlemyre, M S; Holman, D A; Grate, J W; Brockman, F J; Chandler, D P

    2000-09-01

    The development of a new temperature-controlled renewable microcolumn flow cell for solid-phase nucleic acid hybridization in an automated sequential injection system is described. The flow cell included a stepper motor-driven rotating rod with the working end cut to a 45 degrees angle. In one position, the end of the rod prevented passage of microbeads while allowing fluid flow; rotation of the rod by 180 degrees releases the beads. This system was used to rapidly test many hybridization and elution protocols to examine the temperature and solution conditions required for sequence-specific nucleic acid hybridization. Target nucleic acids labeled with a near-infrared fluorescent dye were detected immediately postcolumn during all column perfusion and elution steps using a flow-through fluorescence detector. Temperature control of the column and the presence of Triton X-100 surfactant were critical for specific hybridization. Perfusion of the column with complementary oligonucleotide (200 microL, 10 nM) resulted in hybridization with 8% of the DNA binding sites on the microbeads with a solution residence time of less than 1 s and a total sample perfusion time of 40 s. The use of the renewable column system for detection of an unlabeled PCR product in a sandwich assay was also demonstrated.

  7. Tellurium Hydrides at High Pressures: High-Temperature Superconductors

    NASA Astrophysics Data System (ADS)

    Zhong, Xin; Wang, Hui; Zhang, Jurong; Liu, Hanyu; Zhang, Shoutao; Song, Hai-Feng; Yang, Guochun; Zhang, Lijun; Ma, Yanming

    2016-02-01

    Observation of high-temperature superconductivity in compressed sulfur hydrides has generated an irresistible wave of searches for new hydrogen-containing superconductors. We herein report the prediction of high-Tc superconductivity in tellurium hydrides stabilized at megabar pressures identified by first-principles calculations in combination with a swarm structure search. Although tellurium is isoelectronic to sulfur or selenium, its heavier atomic mass and weaker electronegativity makes tellurium hydrides fundamentally distinct from sulfur or selenium hydrides in stoichiometries, structures, and chemical bondings. We identify three metallic stoichiometries of H4Te , H5Te2 , and HTe3 , which are not predicted or known stable structures for sulfur or selenium hydrides. The two hydrogen-rich H4Te and H5Te2 phases are primarily ionic and contain exotic quasimolecular H2 and linear H3 units, respectively. Their high-Tc (e.g., 104 K for H4Te at 170 GPa) superconductivity originates from the strong electron-phonon couplings associated with intermediate-frequency H-derived wagging and bending modes, a superconducting mechanism which differs substantially with those in sulfur or selenium hydrides where the high-frequency H-stretching vibrations make considerable contributions.

  8. [Genesis study of omphacite at high pressure and high temperature].

    PubMed

    Xiao, Ben-Fu; Yi, Li; Wang, Duo-Jun; Xie, Chao; Tang, Xue-Wu; Liu, Lei; Cui, Yue-Ju

    2013-11-01

    The melting and recrystallizing experiments of alkali basalt powder and mixture of pure oxides mixed as stoichiometry were performed at 3 GPa and 1 200 degrees C. Electronic microprobe analysis and Raman spectra showed that the recrystallized products were omphacites, the FWHM (full width at half maximum) of the Raman peak was narrow and its shape was sharp, which is attributed to the stable Si-O tetrahedral structure and the high degree of order in omphacite. Based on the results of previous studies, the influencing factors of omphacite genesis and its primary magma were discussed. The results showed that the formation of omphacite could be affected by many factors, such as the composition of parent rocks, the concentration of fluid in the system and the conditions of pressure and temperature. This result could support some experimental evidences on the genesis studies of omphacite and eclogite.

  9. Foil-like manganin gauges for dynamic high pressure measurements

    NASA Astrophysics Data System (ADS)

    Duan, Zhuoping; Liu, Yan; Pi, Aiguo; Huang, Fenglei

    2011-07-01

    Foil-like manganin gauges with a variety of shapes used in different ranges of pressure for the one-dimensional strain mode and axisymmetric strain mode were designed for measuring the detonation pressures of explosives and high shock pressure in materials. In the stress range of 0-53.5 GPa, the pressure-piezoresistance relationships of the manganin gauges were calibrated by the light gas gun and the planar lens of explosive. The piezoresistance coefficients were obtained in different ranges of pressure. To verify the coefficients, the detonation pressure (CJ pressure) of TNT explosive was measured by the manganin gauges, which give similar CJ pressure values to those reported by Zhang et al (2009 Detonation Physics (Beijing: Ordnance Industry Press)) with the maximum relative deviation being less than 3%.

  10. High-Pressure Polymorph of Iron.

    PubMed

    Takahashi, T; Bassett, W A

    1964-07-31

    An x-ray diffraction study of iron under pressure has shown that alpha-iron (body-centered cubic) transforms to hexagonal-close-packing (designated epsilon-iron) at 130 kb, room temperature. The volume change for the transformation is -0.20 +/- 0.03 cm2/ mole. The slope for the gamma-epsilon phase boundary has been calculated to be 2 +/- 1 degrees C/kb. The molar volume of iron decreases from 7.10 cm3/mole (density = 7.85 g/cm(3)) at room pressure to 6.10 +/- 0.08 cm(3)/mole (density = 9.1 +/- 0.1 g/cm(3)) at 200 kb and room temperature. The extrapolation of the gamma-epsilon phase boundary, consistent with shock wave data, suggests that it may have an influence on the properties of the earth's core.

  11. Phonon Anomaly in High-Pressure Zn

    NASA Astrophysics Data System (ADS)

    Li, Zhiqiang; Tse, John S.

    2000-12-01

    The equation of states and phonon dispersions of hexagonal zinc have been calculated by the plane-wave pseudopotential method within the generalized-gradient approximation. Weak discontinuities are found in the pressure-volume relation as well as the c/a-volume curve. Phonon dispersions of Zn under pressure have been obtained with a direct method and the results are consistent with the neutron scattering data. At V/V0~0.88, the calculated frequencies of the acoustic phonons near the zone center softened substantially as a result of an electronic topological transition. The theoretical result is consistent with the observed anomaly in the Lam-Mössbauer factor at low temperature.

  12. High-pressure, high-temperature bioreactor for comparing effects of hyperbaric and hydrostatic pressure on bacterial growth.

    PubMed Central

    Nelson, C M; Schuppenhauer, M R; Clark, D S

    1992-01-01

    We describe a high-pressure reactor system suitable for simultaneous hyperbaric and hydrostatic pressurization of bacterial cultures at elevated temperatures. For the deep-sea thermophile ES4, the growth rate at 500 atm (1 atm = 101.29 kPa) and 95 degrees C under hydrostatic pressure was ca. three times the growth rate under hyperbaric pressure and ca. 40% higher than the growth rate at 35 atm. PMID:1622255

  13. Basic Studies on High Pressure Air Plasmas

    DTIC Science & Technology

    2006-08-30

    33, 2268 (2000). [3] Non- Equilibrium Air Plasmas at Atmospheric Pressure, K.H. Becker, U. Kogelschatz, K.H. Schoenbach, and R.J. Barker, eds., IOP...10). Note that LIFBASE assumes local thermodynamic equilibrium . 120 100 oExperimentalm Siuation 80 60 20- 0 -J ~ LkXi 3060 3070 3080 3090 3100...Dual laser interferometer for plasma density measurements on large tokamaks >>, Rev. Sci. Instrum. 49 p.919 (1978) [5] C.W. Gowers, C. Lamb, « A

  14. Ion Based High-Temperature Pressure Sensor

    DTIC Science & Technology

    2004-01-01

    Humphrey, and Chapman - Jouguet Detonation cycles to be 27%, 47%, and 49% respectively.1 In addition to the clear thermodynamic advantages, the PDE also...and durable (vibration resistant) devices. Traditional pressure sensors can be used, however thermal insulating materials must be used to protect the...ignited using a traditional spark plug connected to an ignition coil. A low DC voltage is applied across the ion sensor, a Champion RC12LYC spark plug

  15. High pressure rotary piston coal feeder

    NASA Technical Reports Server (NTRS)

    Gardner, J. F.; Gencsoy, H. T.; Strimbeck, D. C.

    1977-01-01

    This feeder concept uniquely combines the functions of solids feeding, metering, and pressurization into one compact system. Success with the rotary-piston concept would provide a lower-cost alternative to lock-hopper systems. The design of the feeder is presented, with special emphasis on the difficult problem of seal design. Initial tests will be to check seal performance. Subsequent tests will evaluate solids-feeding ability.

  16. Evaluation of high-pressure drilling fluid supply systems

    SciTech Connect

    McDonald, M.C.; Reichman, J.M.; Theimer, K.J.

    1981-10-01

    A study was undertaken to help determine the technical and economic feasibility of developing a high-pressure fluid-jet drilling system for the production of geothermal wells. Three system concepts were developed and analyzed in terms of costs, component availability, and required new-component development. These concepts included a single-conduit system that supplies the downhole cutting nozzles directly via surface-located high-pressure pumps; a single-conduit system utilizing low-pressure surface pumps to supply and operate a high-pressure downhole pump, which in turn supplies the cutting nozzles; and a dual-conduit system supplying surface-generated high-pressure fluid for cutting via one conduit and low-pressure scavenging fluid via the other. It is concluded that the single-conduit downhole pump system concept has the greatest potential for success in this application. 28 figures, 11 tables.

  17. High-pressure behavior of superconducting boron-doped diamond

    NASA Astrophysics Data System (ADS)

    Abdel-Hafiez, Mahmoud; Kumar, Dinesh; Thiyagarajan, R.; Zhang, Q.; Howie, R. T.; Sethupathi, K.; Volkova, O.; Vasiliev, A.; Yang, W.; Mao, H. K.; Rao, M. S. Ramachandra

    2017-05-01

    This work investigates the high-pressure structure of freestanding superconducting (Tc=4.3 K) boron-doped diamond (BDD) and how it affects the electronic and vibrational properties using Raman spectroscopy and x-ray diffraction in the 0-30 GPa range. High-pressure Raman scattering experiments revealed an abrupt change in the linear pressure coefficients, and the grain boundary components undergo an irreversible phase change at 14 GPa. We show that the blueshift in the pressure-dependent vibrational modes correlates with the negative pressure coefficient of Tc in BDD. The analysis of x-ray diffraction data determines the equation of state of the BDD film, revealing a high bulk modulus of B0=510 ±28 GPa. The comparative analysis of high-pressure data clarified that the s p2 carbons in the grain boundaries transform into hexagonal diamond.

  18. Nitrous Oxide at High Pressure and Temperature: any Silica-like Polymorphs at High Pressure?

    NASA Astrophysics Data System (ADS)

    Iota, V.; Yoo, C.; Cynn, H.

    2001-12-01

    The crystal structures and phase stabilities of both four and six-fold silicon dioxide (SiO2) polymorphs are fundamental to the Earth's mineral physics and chemistry. The recent discovery of extended-solid phases of carbon dioxide (structurally similar to SiO2 polymorphs), offer a tantalizing new concept of mineral and geo-chemistry, considering the richness of oxygen, carbon, and silicon in the Earth's mantle and crust. In this study, we ask if nitrous oxide (N2O), an isoelectronic molecular analog to CO2, forms similar SiO2-like polymorphs at high pressures and temperatures. Our results based on in-situ and ex-situ Raman and X-ray diffraction measurements indicate that N2O indeed behaves similarly to CO2 at relatively low temperatures below 1000 K at high pressures up to 100 GPa. However, at higher temperatures, we find no transition to a polymeric phase of N2O. Instead, it disproportionates into a novel ionic phase of NO2 dimer (NO+NO3-) and N2. In this paper, we will discuss about the systematic of the phase diagrams of these triatomics, CO2 and N2O, in comparison with the polymorphs of SiO2, the Earth most abundant mineral.

  19. High-Pressure Study on Lead Fluorapatite

    SciTech Connect

    Liu, X.; Shieh, S; Fleet, M; Akhmetov, A

    2008-01-01

    The compressional behavior of a synthetic lead fluorapatite [Pb9.35(PO4)6F2] has been investigated in situ up to about 16.7 GPa at 300 K, using a diamond-anvil cell and synchrotron X-ray diffraction. We find that the compressibility of lead fluorapatite is significantly different from that of fluorapatite [Ca10(PO4)6F2], chlorapatite [Ca10(PO4)6Cl2], and hydroxylapatite [Ca10(PO4)6(OH)2]: lead fluorapatite is much more compressible, and elastically isotropic in the investigated pressure range. The pressure-volume data fitted to the third-order Birch-Murnaghan equation yield an isothermal bulk modulus (KT) of 54.3(18) GPa and the pressure derivative (KT') of 8.1(6). If KT' is fixed at 4, the obtained KT is 68.4(16) GPa, which is approximately only two-thirds of the isothermal bulk modulus of the calcium apatites.

  20. Inverted equations of state for solids under high pressures

    NASA Astrophysics Data System (ADS)

    Chauhan, R. S.; Lal, K.; Singh, C. P.

    2011-09-01

    In the present communication we have reviewed some inverted type equations of state for solids under high pressures. An inverted equation of state (EOS) gives volume as a function of pressure for a solid under isothermal conditions. We have considered various equations of state proposed by earlier workers which express volume as a function of pressure. Expressions for bulk modulus and its pressure derivatives based on such EOSs are obtained and reported here. It is emphasized here that the high pressure derivative properties are very sensitive to the forms of equations of state representing volume-pressure relationships. We have also studied the thermoelastic properties of solids based on pressure derivatives of bulk modulus. Applications have been extended in the present review article to the solids which are metals as well as non-metals including geophysical minerals present in the lower mantle and core of the Earth.

  1. Implement and application of ultra-high pressures environment

    NASA Astrophysics Data System (ADS)

    Xian Zhang, Yu; Li, Nan; Liu, Bin Bin; Wang, Hong

    2017-09-01

    A hydraulic system was designed which was used to generate hydrostatic ultra-high pressure environment. The functions and roles of the main elements in the hydraulic system were introduced. Deformation theory based on ultrahigh pressure cylinder was analyzed. The principle and method about measuring ultra-high pressure cylinder radial and circumferential elastic line-strain by a dial indicator were illustrated. A practical example was given to illustrate the practicability and validity of this method. The measures to decrease the measurement error were pointed out. The described priciples and methods have a certain theoretical and practical significance in engineering research and application of ultra-high pressure.

  2. Investigation of High-Pressure Hydraulic Vortex Rate Sensor

    DTIC Science & Technology

    stability - augmentation system . The feasibility of low-pressure fluid stabilization systems was demonstrated. The primary component that requires development for implementation in a high pressure system is the vortex rate sensor. The high-pressure hydraulic vortex rate sensor has an on-board built-in supply of hydraulic fluid which is used in the primary hydro-mechanical flight control of the vehicle. A small amount of hydraulic fluid under high pressure can be diverted from the main system to the vortex rate sensor, used to perform a sensing function, and

  3. CARS Diagnostics of High Pressure Combustion - 2. Measurements of NO, H2O and High Pressure Flames

    DTIC Science & Technology

    1985-12-01

    R85-956328-F CARS DIAGNOSTICS OF r HIGH PRESSURE COMBUSTION -I MEASUREMENTS OF NO, H 0 AND HIGH PRESSURE FLAMES Final Report J.H. Stufflebeam DTIC I7...High Pressure Flames Final Report ~ 5%~ J. H. Stufflebeam J. A. Shirley December 1985 𔃿** U. S. Army Research Office Contract: DAAG29-83-C-OOO1...ClaIiation, CARS Diagnostics of High Pressure Combustion II 12. PERSONAL AUTHOR(S) Stufflebeam , 7. H., ShirleyJA 113a. TYPE OF REPORT 13b. TIME COVERED

  4. Structural behaviour of niobium oxynitride under high pressure

    SciTech Connect

    Sharma, Bharat Bhooshan Poswal, H. K. Pandey, K. K. Sharma, Surinder M.; Yakhmi, J. V.; Ohashi, Y.; Kikkawa, S.

    2014-04-24

    High pressure investigation of niobium oxynitrides (NbN{sub 0.98}O{sub 0.02}) employing synchrotron based angle dispersive x-ray diffraction experiments was carried out in very fine pressure steps using membrane driven diamond anvil cell. Ambient cubic phase was found to be stable up to ∼18 GPa. At further high pressure cubic phase showed rhombohedral distortion.

  5. High pressure-induced structural effects in plastic packaging

    NASA Astrophysics Data System (ADS)

    Richter, Tobias; Sterr, Julia; Jost, Verena; Langowski, Horst-Christian

    2010-12-01

    Today, flexible vacuum packages are predominantly used for products to be subjected to high pressure treatment. However, tray packages with a modified atmosphere are in demand, which provide a high failure rate with respect to gas and water vapour permeability and packaging integrity. Methods to follow permeation processes under high pressure were developed and used together with optical microscopy, confocal scanning laser microscopy, Raman spectroscopy and atomic force microscopy to identify the mechanisms for changes in permeability and damage to the packaging materials. Single film samples and pouch packages filled with model products were studied. Results indicate a reversible decrease in the coefficients of diffusion and permeation under the impact of high pressure, due to the compression of the polymeric bulk. Irreversible changes in the polymeric materials are associated with gases in the packaging head space, which cause high local temperatures and create damage due to rapid deliberation upon the pressure drop at the end of the high pressure cycle.

  6. Development of a high temperature capacitive pressure transducer

    NASA Technical Reports Server (NTRS)

    Egger, R. L.

    1977-01-01

    High temperature pressure transducers capable of continuous operation while exposed to 650 C were developed and evaluated over a full-scale differential pressure range of + or - 69 kPa. The design of the pressure transducers was based on the use of a diaphragm to respond to pressure, variable capacitive elements arranged to operate as a differential capacitor to measure diaphragm response and on the use of fused silica for the diaphragm and its supporting assembly. The uncertainty associated with measuring + or - 69 kPa pressures between 20C and 650C was less than + or - 6%.

  7. Journey to the Center of the Earth: Exploring High Pressure

    SciTech Connect

    Mao, Wendy

    2009-09-29

    The deeper we go into the Earth, the higher the pressure. At the pressures found within the center of our planet, minerals do not simply compress. Pressure dramatically alters all materials properties, in the process creating numerous novel phases not found on the surface. This lecture will describe how we simulate the conditions found in planetary interiors in the lab, what kinds of new behavior we find, and how these observations can explain what is going on within the Earth. High pressure explorations also lead to discoveries of novel materials with potential for practical applications in our low-pressure, environment.

  8. 6. Fire Protection (high pressure), view to the east. Located ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Fire Protection (high pressure), view to the east. Located on the pipe floor between Unit 3 and Unit 4, the high pressure CO2 tanks are connected to the generator barrel of all four units. - Washington Water Power Clark Fork River Cabinet Gorge Hydroelectric Development, Powerhouse, North Bank of Clark Fork River at Cabinet Gorge, Cabinet, Bonner County, ID

  9. 30 CFR 56.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false High-pressure hose connections. 56.13021... and Boilers § 56.13021 High-pressure hose connections. Except where automatic shutoff valves are used, safety chains or other suitable locking devices shall be used at connections to machines of...

  10. 30 CFR 56.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false High-pressure hose connections. 56.13021... and Boilers § 56.13021 High-pressure hose connections. Except where automatic shutoff valves are used, safety chains or other suitable locking devices shall be used at connections to machines of...

  11. 30 CFR 56.13021 - High-pressure hose connections.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false High-pressure hose connections. 56.13021... and Boilers § 56.13021 High-pressure hose connections. Except where automatic shutoff valves are used, safety chains or other suitable locking devices shall be used at connections to machines of...

  12. High Blood Pressure in Pregnancy - Multiple Languages: MedlinePlus

    MedlinePlus

    ... الدم أثناء الحمل - العربية Bilingual PDF Health Information Translations Bosnian (Bosanski) High Blood Pressure in Pregnancy Visok ... u trudnoći - Bosanski (Bosnian) Bilingual PDF Health Information Translations Chinese - Simplified (简体中文) High Blood Pressure in Pregnancy ...

  13. Vacuum Surface Flashover And High Pressure Gas Streamers

    DTIC Science & Technology

    1997-06-01

    Optical Emission Characteristics of Polycrystalline Diamond During Surface Flashover in Vacuum ," 1996 IEEE 1~ International Symposium on... VACUUM SURFACE FLASHOVER AND HIGH PRESSURE GAS STREAMERS J. M. Elizondo, M. L. Krogh, D. Smith, D. Stoltz, and S. N. Wright AlliedSignal Federal...breakdown current traces obtained during high pressure gas breakdown and vacuum surface flashover show similar signatures. The initial

  14. Heart and Artery Damage and High Blood Pressure

    MedlinePlus

    ... Artery Disease Venous Thromboembolism Aortic Aneurysm More How High Blood Pressure Can Lead to a Heart Attack Updated:Dec ... sheet This content was last reviewed October 2016. High Blood Pressure • Home • Get the Facts About HBP • Know Your ...

  15. Americans with High Blood Pressure Still Eating Too Much Salt

    MedlinePlus

    ... medlineplus.gov/news/fullstory_163977.html Americans With High Blood Pressure Still Eating Too Much Salt Average sodium intake ... March 8, 2017 (HealthDay News) -- For Americans with high blood pressure, cutting back on salt is an important way ...

  16. 15. VIEW OF MODULE H, THE HIGH PRESSURE ASSEMBLY AREA. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    15. VIEW OF MODULE H, THE HIGH PRESSURE ASSEMBLY AREA. PROCESSES IN THIS MODULE OCCURRED UNDER HIGH PRESSURES AND TEMPERATURES. (5/70) - Rocky Flats Plant, Plutonium Manufacturing Facility, North-central section of Plant, just south of Building 776/777, Golden, Jefferson County, CO

  17. High Pressure Crystal Chemistry of Hydrous Ringwoodite

    NASA Astrophysics Data System (ADS)

    Holl, C. M.; Smyth, J. R.; Frost, D. J.; Jacobsen, S. D.

    2002-12-01

    Single crystals of hydrous Fo90 ringwoodite up to 800 μm in diameter have been synthesized in a multi-anvil press at 1400°C and 20 GPa. The crystals are deep blue in color and contain approximately 0.8 percent H2O by weight as measured by IR spectroscopy. The unit cell parameter of this material has been refined by single-crystal X-ray diffraction at 15 different pressures up to 3.8 GPa. Pressure was determined by refinement of the until cell volume of a standard quartz crystal. Preliminary values for the bulk modulus give a K0 = 172 +/- 9 GPa and K' = 5.1 +/- 1.6 over the range studied. The crystal structure of this material has been refined at six pressures up to 3.8 GPa. Refinements were obtained from an average of 13 unique data with values of Rf < 5%. Preliminary estimates of the polyhedral compressibilities are 1.0x10-2 GPa-1 (K = 100 GPa) for MgVI and 6.3x10-3 GPa-1 (K = 160 GPa) for SiIV. Comparison of the present data with previous results shows a systematic decrease in the bulk modulus of ringwoodite with H content. This decrease is larger than the effect of temperature within the allowable ranges of each so that an increase in H2O content of one percent would have an effect on the bulk modulus equivalent to raising the temperature by 500°C.

  18. High-pressure studies of pharmaceutical compounds and energetic materials.

    PubMed

    Fabbiani, Francesca P A; Pulham, Colin R

    2006-10-01

    The effects of high pressure on pharmaceutical compounds and energetic materials can have important implications for both the properties and performance of these important classes of material. Pharmaceutical compounds are frequently subjected to pressure during processing and formulation, causing interconversion between solid forms that may affect properties such as solubility and bio-availability. Energetic materials experience extremes of both pressure and temperature under conditions of detonation and deflagration, causing changes in properties such as sensitivity to shock and chemical reactivity. This tutorial review outlines the various methods used to study these materials at high pressure, describes how pressure can be used to explore polymorphism, and provides examples of compounds that have been studied at high pressure.

  19. Introduction to high-pressure bioscience and biotechnology.

    PubMed

    Bartlett, Douglas H

    2010-02-01

    The manipulation of biological materials using elevated pressure is providing an ever-growing number of opportunities in both the applied and basic sciences. Manipulation of pressure is a useful parameter for enhancing food quality and shelf life; inactivating microbes, viruses, prions, and deleterious enzymes; affecting recombinant protein production; controlling DNA hybridization; and improving vaccine preparation. In biophysics and biochemistry, pressure is used as a tool to study intermediates in protein folding, enzyme kinetics, macromolecular interactions, amyloid fibrous protein aggregation, lipid structural changes, and to discern the role of solvation and void volumes in these processes. Biologists, including many microbiologists, examine the utility and basis of pressure inactivation of cells and cellular processes, and conversely seek to discover how deep-sea life has evolved a preference for high-pressure environments. This introduction and the papers that follow provide information on the nature and promise of the highly interdisciplinary field of high-pressure bioscience and biotechnology (HPBB).

  20. Strong environmental tolerance of Artemia under very high pressure

    NASA Astrophysics Data System (ADS)

    Minami, K.; Ono, F.; Mori, Y.; Takarabe, K.; Saigusa, M.; Matsushima, Y.; Saini, N. L.; Yamashita, M.

    2010-03-01

    It was shown by the present authors group that a tardigrade in its tun-state can survive after exposed to 7.5 GPa for 13 hours. We have extended this experiment to other tiny animals searching for lives under extreme conditions of high hydrostatic pressure. Artemia, a kind of planktons, in its dried egg-state have strong environmental tolerance. Dozens of Artemia eggs were sealed in a small Teflon capsule together with a liquid pressure medium, and exposed to the high hydrostatic pressure of 7.5 GPa. After the pressure was released, they were soaked in seawater to observe hatching rate. It was proved that 80-90% of the Artemia eggs were alive and hatched into Nauplii after exposed to the maximum pressure of 7.5 GPa for up to 48 hours. Comparing with Tardigrades, Artemia are four-times stronger against high pressure.

  1. Experimental investigation on pressurization performance of cryogenic tank during high-temperature helium pressurization process

    NASA Astrophysics Data System (ADS)

    Lei, Wang; Yanzhong, Li; Yonghua, Jin; Yuan, Ma

    2015-03-01

    Sufficient knowledge of thermal performance and pressurization behaviors in cryogenic tanks during rocket launching period is of importance to the design and optimization of a pressurization system. In this paper, ground experiments with liquid oxygen (LO2) as the cryogenic propellant, high-temperature helium exceeding 600 K as the pressurant gas, and radial diffuser and anti-cone diffuser respectively at the tank inlet were performed. The pressurant gas requirements, axial and radial temperature distributions, and energy distributions inside the propellant tank were obtained and analyzed to evaluate the comprehensive performance of the pressurization system. It was found that the pressurization system with high-temperature helium as the pressurant gas could work well that the tank pressure was controlled within a specified range and a stable discharging liquid rate was achieved. For the radial diffuser case, the injected gas had a direct impact on the tank inner wall. The severe gas-wall heat transfer resulted in about 59% of the total input energy absorbed by the tank wall. For the pressurization case with anti-cone diffuser, the direct impact of high-temperature gas flowing toward the liquid surface resulted in a greater deal of energy transferred to the liquid propellant, and the percentage even reached up to 38%. Moreover, both of the two cases showed that the proportion of energy left in ullage to the total input energy was quite small, and the percentage was only about 22-24%. This may indicate that a more efficient diffuser should be developed to improve the pressurization effect. Generally, the present experimental results are beneficial to the design and optimization of the pressurization system with high-temperature gas supplying the pressurization effect.

  2. Pressurized metallurgy for high performance special steels and alloys

    NASA Astrophysics Data System (ADS)

    Jiang, Z. H.; Zhu, H. C.; Li, H. B.; Li, Y.; Liu, F. B.

    2016-07-01

    The pressure is one of the basic parameters which greatly influences the metallurgical reaction process and solidification of steels and alloys. In this paper the history and present situation of research and application of pressurized metallurgy, especially pressurized metallurgy for special steels and alloys have been briefly reviewed. In the following part the physical chemistry of pressurized metallurgy is summarized. It is shown that pressurizing may change the conditions of chemical reaction in thermodynamics and kinetics due to the pressure effect on gas volume, solubility of gas and volatile element in metal melt, activity or activity coefficient of components, and change the physical and chemical properties of metal melt, heat transfer coefficient between mould and ingot, thus greatly influencing phase transformation during the solidification process and the solidification structure, such as increasing the solidification nucleation rate, reducing the critical nucleation radius, accelerating the solidification speed and significant macro/micro-structure refinement, and eliminating shrinkage, porosity and segregation and other casting defects. In the third part the research works of pressured metallurgy performed by the Northeastern University including establishment of pressurized induction melting (PIM) and pressurized electroslag remelting (PESR) equipments and development of high nitrogen steels under pressure are described in detail. Finally, it is considered in the paper that application of pressurized metallurgy in manufacture of high performance special steels and alloys is a relatively new research area, and its application prospects will be very broad and bright.

  3. Microstructures define melting of molybdenum at high pressures

    NASA Astrophysics Data System (ADS)

    Hrubiak, Rostislav; Meng, Yue; Shen, Guoyin

    2017-03-01

    High-pressure melting anchors the phase diagram of a material, revealing the effect of pressure on the breakdown of the ordering of atoms in the solid. An important case is molybdenum, which has long been speculated to undergo an exceptionally steep increase in melting temperature when compressed. On the other hand, previous experiments showed nearly constant melting temperature as a function of pressure, in large discrepancy with theoretical expectations. Here we report a high-slope melting curve in molybdenum by synchrotron X-ray diffraction analysis of crystalline microstructures, generated by heating and subsequently rapidly quenching samples in a laser-heated diamond anvil cell. Distinct microstructural changes, observed at pressures up to 130 gigapascals, appear exclusively after melting, thus offering a reliable melting criterion. In addition, our study reveals a previously unsuspected transition in molybdenum at high pressure and high temperature, which yields highly textured body-centred cubic nanograins above a transition temperature.

  4. High-Pressure Oxygen Generation for Outpost EVA Study

    NASA Technical Reports Server (NTRS)

    Jeng, Frank F.; Conger, Bruce; Ewert, Michael K.; Anderson, Molly S.

    2009-01-01

    The amount of oxygen consumption for crew extravehicular activity (EVA) in future lunar exploration missions will be significant. Eight technologies to provide high pressure EVA O2 were investigated. They are: high pressure O2 storage, liquid oxygen (LOX) storage followed by vaporization, scavenging LOX from Lander followed by vaporization, LOX delivery followed by sorption compression, water electrolysis followed by compression, stand-alone high pressure water electrolyzer, Environmental Control and Life Support System (ECLSS) and Power Elements sharing a high pressure water electrolyzer, and ECLSS and In-Situ Resource Utilization (ISRU) Elements sharing a high pressure electrolyzer. A trade analysis was conducted comparing launch mass and equivalent system mass (ESM) of the eight technologies in open and closed ECLSS architectures. Technologies considered appropriate for the two architectures were selected and suggested for development.

  5. High-Pressure Oxygen Generation for Outpost EVA Study

    NASA Technical Reports Server (NTRS)

    Jeng, Frank F.; Conger, Bruce; Ewert, Michael K.; Anderson, Molly S.

    2009-01-01

    The amount of oxygen consumption for crew extravehicular activity (EVA) in future lunar exploration missions will be significant. Eight technologies to provide high pressure EVA O2 were investigated. They are: high pressure O2 storage, liquid oxygen (LOX) storage followed by vaporization, scavenging LOX from Lander followed by vaporization, LOX delivery followed by sorption compression, water electrolysis followed by compression, stand-alone high pressure water electrolyzer, Environmental Control and Life Support System (ECLSS) and Power Elements sharing a high pressure water electrolyzer, and ECLSS and In-Situ Resource Utilization (ISRU) Elements sharing a high pressure electrolyzer. A trade analysis was conducted comparing launch mass and equivalent system mass (ESM) of the eight technologies in open and closed ECLSS architectures. Technologies considered appropriate for the two architectures were selected and suggested for development.

  6. Microstructures define melting of molybdenum at high pressures

    PubMed Central

    Hrubiak, Rostislav; Meng, Yue; Shen, Guoyin

    2017-01-01

    High-pressure melting anchors the phase diagram of a material, revealing the effect of pressure on the breakdown of the ordering of atoms in the solid. An important case is molybdenum, which has long been speculated to undergo an exceptionally steep increase in melting temperature when compressed. On the other hand, previous experiments showed nearly constant melting temperature as a function of pressure, in large discrepancy with theoretical expectations. Here we report a high-slope melting curve in molybdenum by synchrotron X-ray diffraction analysis of crystalline microstructures, generated by heating and subsequently rapidly quenching samples in a laser-heated diamond anvil cell. Distinct microstructural changes, observed at pressures up to 130 gigapascals, appear exclusively after melting, thus offering a reliable melting criterion. In addition, our study reveals a previously unsuspected transition in molybdenum at high pressure and high temperature, which yields highly textured body-centred cubic nanograins above a transition temperature. PMID:28248309

  7. Structure of carbonate melts at high pressure

    NASA Astrophysics Data System (ADS)

    Hudspeth, J.; Sanloup, C.; Cochain, B.; Konopkova, Z.; Afonina, V.; Morgenroth, W.

    2015-12-01

    Carbonate melts are rare magmas with only a single active volcano (Oldoinyo Lengai,Tanzania [1]). They are of fundamental interest for their role in the Earth's deep carbon cycle and are of immense economic importance due to their affinity for REE strategic metals (niobium, uranium, tantalum, etc). They have remarkable physical properties such as very low viscosity [2] and magmatic temperatures for alkaline carbonate lavas [3] and it has been predicted that their compressibility could be significantly higher than that of silicate melts [4,5]. Despite the atomic structure of carbonate melts being fundamental for controlling their physical and chemical behavior in natural systems, very few structural studies have been reported and these have been largely computational. Here we present initial structural investigations of carbonate melts at mantle pressures using in situ x-ray diffraction in diamond anvil cells. The structure factor S(Q) is transformed to obtain the real space pair distribution function G(R) which describes the local and intermediate range atomic ordering allowing bond length and coordination number changes with pressure to be determined. [1] Krafft and Keller, Science 245:168-170, 1989 [2] Yono et al., Nat. Commun. 5:5091, 2014 [3] Dobson et al., Earth Planet. Sci. Lett. 143:207-215, 1996 [4] Genge et al., Earth Planet. Sci. Lett. 131:225-238, 1995 [5] Jones et al., Rev. Mineral. Geochem. 75:289-322, 2013

  8. Theoretical Thermodynamics of Mixtures at High Pressures

    NASA Technical Reports Server (NTRS)

    Hubbard, W. B.

    1985-01-01

    The development of an understanding of the chemistry of mixtures of metallic hydrogen and abundant, higher-z material such as oxygen, carbon, etc., is important for understanding of fundamental processes of energy release, differentiation, and development of atmospheric abundances in the Jovian planets. It provides a significant theoretical base for the interpretation of atmospheric elemental abundances to be provided by atmospheric entry probes in coming years. Significant differences are found when non-perturbative approaches such as Thomas-Fermi-Dirac (TFD) theory are used. Mapping of the phase diagrams of such binary mixtures in the pressure range from approx. 10 Mbar to approx. 1000 Mbar, using results from three-dimensional TFD calculations is undertaken. Derivation of a general and flexible thermodynamic model for such binary mixtures in the relevant pressure range was facilitated by the following breakthrough: there exists an accurate nd fairly simple thermodynamic representation of a liquid two-component plasma (TCP) in which the Helmholtz free energy is represented as a suitable linear combination of terms dependent only on density and terms which depend only on the ion coupling parameter. It is found that the crystal energies of mixtures of H-He, H-C, and H-O can be satisfactorily reproduced by the same type of model, except that an effective, density-dependent ionic charge must be used in place of the actual total ionic charge.

  9. Structure and stability of hydrous minerals at high pressure

    NASA Technical Reports Server (NTRS)

    Duffy, T. S.; Fei, Y.; Meade, C.; Hemley, R. J.; Mao, H. K.

    1994-01-01

    The presence of even small amounts of hydrogen in the Earth's deep interior may have profound effects on mantle melting, rheology, and electrical conductivity. The recent discovery of a large class of high-pressure H-bearing silicates further underscores the potentially important role for hydrous minerals in the Earth's mantle. Hydrogen may also be a significant component of the Earth's core, as has been recently documented by studies of iron hydride at high pressure. In this study, we explore the role of H in crystal structures at high pressure through detailed Raman spectroscopic and x ray diffraction studies of hydrous minerals compressed in diamond anvil cells. Brucite, Mg(OH)2, has a simple structure and serves as an analogue for the more complex hydrous silicates. Over the past five years, this material has been studied at high pressure using shock-compression, powder x ray diffraction, infrared spectroscopy, Raman spectroscopy, and neutron diffraction. In addition, we have recently carried out single-crystal synchrotron x-ray diffraction on Mg(OH)2 and Raman spectroscopy on Mg(OD)2 at elevated pressure. From all these studies, an interesting picture of the crystal chemical behavior of this material at high pressure is beginning to emerge. Some of the primary conclusions are as follows: First, hydrogen bonding is enhanced by the application of pressure. Second, layered minerals which are elastically anisotropic at low pressure may not be so at high pressure. Furthermore, the brucite data place constraints on the effect of hydrogen on seismic velocities and density at very high pressure. Third, the stability of hydrous minerals may be enhanced at high P by subtle structural rearrangements that are difficult to detect using traditional probes and require detailed spectroscopic analyses. Finally, brucite appears to be unique in that it undergoes pressure-induced disordering that is confined solely to the H-containing layers of the structure.

  10. Structure and stability of hydrous minerals at high pressure

    NASA Technical Reports Server (NTRS)

    Duffy, T. S.; Fei, Y.; Meade, C.; Hemley, R. J.; Mao, H. K.

    1994-01-01

    The presence of even small amounts of hydrogen in the Earth's deep interior may have profound effects on mantle melting, rheology, and electrical conductivity. The recent discovery of a large class of high-pressure H-bearing silicates further underscores the potentially important role for hydrous minerals in the Earth's mantle. Hydrogen may also be a significant component of the Earth's core, as has been recently documented by studies of iron hydride at high pressure. In this study, we explore the role of H in crystal structures at high pressure through detailed Raman spectroscopic and x ray diffraction studies of hydrous minerals compressed in diamond anvil cells. Brucite, Mg(OH)2, has a simple structure and serves as an analogue for the more complex hydrous silicates. Over the past five years, this material has been studied at high pressure using shock-compression, powder x ray diffraction, infrared spectroscopy, Raman spectroscopy, and neutron diffraction. In addition, we have recently carried out single-crystal synchrotron x-ray diffraction on Mg(OH)2 and Raman spectroscopy on Mg(OD)2 at elevated pressure. From all these studies, an interesting picture of the crystal chemical behavior of this material at high pressure is beginning to emerge. Some of the primary conclusions are as follows: First, hydrogen bonding is enhanced by the application of pressure. Second, layered minerals which are elastically anisotropic at low pressure may not be so at high pressure. Furthermore, the brucite data place constraints on the effect of hydrogen on seismic velocities and density at very high pressure. Third, the stability of hydrous minerals may be enhanced at high P by subtle structural rearrangements that are difficult to detect using traditional probes and require detailed spectroscopic analyses. Finally, brucite appears to be unique in that it undergoes pressure-induced disordering that is confined solely to the H-containing layers of the structure.

  11. Structure and stability of hydrous minerals at high pressure

    NASA Astrophysics Data System (ADS)

    Duffy, T. S.; Fei, Y.; Meade, C.; Hemley, R. J.; Mao, H. K.

    The presence of even small amounts of hydrogen in the Earth's deep interior may have profound effects on mantle melting, rheology, and electrical conductivity. The recent discovery of a large class of high-pressure H-bearing silicates further underscores the potentially important role for hydrous minerals in the Earth's mantle. Hydrogen may also be a significant component of the Earth's core, as has been recently documented by studies of iron hydride at high pressure. In this study, we explore the role of H in crystal structures at high pressure through detailed Raman spectroscopic and x ray diffraction studies of hydrous minerals compressed in diamond anvil cells. Brucite, Mg(OH)2, has a simple structure and serves as an analogue for the more complex hydrous silicates. Over the past five years, this material has been studied at high pressure using shock-compression, powder x ray diffraction, infrared spectroscopy, Raman spectroscopy, and neutron diffraction. In addition, we have recently carried out single-crystal synchrotron x-ray diffraction on Mg(OH)2 and Raman spectroscopy on Mg(OD)2 at elevated pressure. From all these studies, an interesting picture of the crystal chemical behavior of this material at high pressure is beginning to emerge. Some of the primary conclusions are as follows: First, hydrogen bonding is enhanced by the application of pressure. Second, layered minerals which are elastically anisotropic at low pressure may not be so at high pressure. Furthermore, the brucite data place constraints on the effect of hydrogen on seismic velocities and density at very high pressure. Third, the stability of hydrous minerals may be enhanced at high P by subtle structural rearrangements that are difficult to detect using traditional probes and require detailed spectroscopic analyses. Finally, brucite appears to be unique in that it undergoes pressure-induced disordering that is confined solely to the H-containing layers of the structure.

  12. Instrument for high resolution magnetization measurements at high pressures, high magnetic fields and low temperatures

    NASA Astrophysics Data System (ADS)

    Koyama, K.; Hane, S.; Kamishima, K.; Goto, T.

    1998-08-01

    An instrument has been developed for the first time that makes high resolution magnetization measurements at high pressures, high magnetic fields and low temperatures. The instrument consists of an extraction-type magnetometer, a nonmagnetic high pressure clamp cell and a 20 T superconducting magnet with a 3He refrigerator and is able to precisely measure the magnetization of weakly magnetic materials. TiCu alloy with 3 wt % Ti is employed as a nonmagnetic material with high mechanical strength for the high pressure clamp cell. This apparatus can be used in the pressure range 0⩽P⩽13 kbar, the field range 0⩽H⩽200 kOe and the temperature range 0.5⩽T⩽4.2 K. The resolution of the instrument is estimated to be ±0.002 emu. For demonstrating the ability of the instrument, the experimental results on a heavy fermion antiferromagnet Ce7Ni3 is presented.

  13. Analysis of Free Drug Fractions in Serum by Ultrafast Affinity Extraction and Two-Dimensional Affinity Chromatography using α1-Acid Glycoprotein Microcolumns

    PubMed Central

    Bi, Cong; Zheng, Xiwei; Hage, David S.

    2016-01-01

    In the circulatory system, many drugs are reversibly bound to serum proteins such as human serum albumin (HSA) and alpha1-acid glycoprotein (AGP), resulting in both free and protein-bound fractions for these drugs. This report examined the use of microcolumns containing immobilized AGP for the measurement of free drug fractions by ultrafast affinity extraction and a two-dimensional affinity system. Several drugs known to bind AGP were used as models to develop and evaluate this approach. Factors considered during the creation of this method included the retention of the drugs on the microcolumns, the injection flow rate, the microcolumn size, and the times at which a second AGP column was placed on-line with the microcolumn. The final system had residence times of only 110–830 ms during sample passage through the AGP microcolumns and allowed free drug fractions to be determined within 10–20 min when using only 3–10 µL of sample per injection. This method was used to measure the free fractions of the model drugs at typical therapeutic levels in serum, giving good agreement with the results obtained by ultrafiltration. This approach was also used to estimate the binding constants for each drug with AGP in serum, even for drugs that had significant interactions with both AGP and HSA in such samples. These results indicated that AGP microcolumns could be used with ultrafast affinity extraction to measure free drug fractions in a label-free manner and to study the binding of drugs with AGP in complex samples such as serum. PMID:26797422

  14. Amorphous diamond: a high-pressure superhard carbon allotrope.

    PubMed

    Lin, Yu; Zhang, Li; Mao, Ho-kwang; Chow, Paul; Xiao, Yuming; Baldini, Maria; Shu, Jinfu; Mao, Wendy L

    2011-10-21

    Compressing glassy carbon above 40 GPa, we have observed a new carbon allotrope with a fully sp(3)-bonded amorphous structure and diamondlike strength. Synchrotron x-ray Raman spectroscopy revealed a continuous pressure-induced sp(2)-to-sp(3) bonding change, while x-ray diffraction confirmed the perseverance of noncrystallinity. The transition was reversible upon releasing pressure. Used as an indenter, the glassy carbon ball demonstrated exceptional strength by reaching 130 GPa with a confining pressure of 60 GPa. Such an extremely large stress difference of >70 GPa has never been observed in any material besides diamond, indicating the high hardness of this high-pressure carbon allotrope.

  15. Amorphous diamond: A high-pressure superhard carbon allotrope

    SciTech Connect

    Lin, Yu; Zhang, Li; Mao, Ho Kwang; Chow, Paul; Xiao, Yuming; Baldini, Maria; Shu, Jinfu; Mao, Wendy L.

    2011-01-01

    Compressing glassy carbon above 40 GPa, we have observed a new carbon allotrope with a fully sp³-bonded amorphous structure and diamondlike strength. Synchrotron x-ray Raman spectroscopy revealed a continuous pressure-induced sp²-to-sp³ bonding change, while x-ray diffraction confirmed the perseverance of noncrystallinity. The transition was reversible upon releasing pressure. Used as an indenter, the glassy carbon ball demonstrated exceptional strength by reaching 130 GPa with a confining pressure of 60 GPa. Such an extremely large stress difference of >70 GPa has never been observed in any material besides diamond, indicating the high hardness of this high-pressure carbon allotrope.

  16. Carbon Nanotubes as High-Pressure Cylinders and Nanoextruders

    NASA Astrophysics Data System (ADS)

    Sun, L.; Banhart, F.; Krasheninnikov, A. V.; Rodríguez-Manzo, J. A.; Terrones, M.; Ajayan, P. M.

    2006-05-01

    Closed-shell carbon nanostructures, such as carbon onions, have been shown to act as self-contracting high-pressure cells under electron irradiation. We report that controlled irradiation of multiwalled carbon nanotubes can cause large pressure buildup within the nanotube cores that can plastically deform, extrude, and break solid materials that are encapsulated inside the core. We further showed by atomistic simulations that the internal pressure inside nanotubes can reach values higher than 40 gigapascals. Nanotubes can thus be used as robust nanoscale jigs for extruding and deforming hard nanomaterials and for modifying their properties, as well as templates for the study of individual nanometer-sized crystals under high pressure.

  17. High pressure ferroelastic phase transition in SrTiO₃.

    PubMed

    Salje, E K H; Guennou, M; Bouvier, P; Carpenter, M A; Kreisel, J

    2011-07-13

    High pressure measurements of the ferroelastic phase transition of SrTiO₃ (Guennou et al 2010 Phys. Rev. B 81 054115) showed a linear pressure dependence of the transition temperature between the cubic and tetragonal phase. Furthermore, the pressure induced transition becomes second order while the temperature dependent transition is near a tricritical point. The phase transition mechanism is characterized by the elongation and tilt of the TiO₆ octahedra in the tetragonal phase, which leads to strongly nonlinear couplings between the structural order parameter, the volume strain and the applied pressure. The phase diagram is derived from the Clausius-Clapeyron relationship and is directly related to a pressure dependent Landau potential. The nonlinearities of the pressure dependent strains lead to an increase of the fourth order Landau coefficient with increasing pressure and, hence, to a tricritical-second order crossover. This behaviour is reminiscent of the doping related crossover in isostructural KMnF₃.

  18. Effect of high pressure on hydrocarbon-degrading bacteria

    PubMed Central

    2014-01-01

    The blowout of the Deepwater Horizon in the Gulf of Mexico in 2010 occurred at a depth of 1500 m, corresponding to a hydrostatic pressure of 15 MPa. Up to now, knowledge about the impact of high pressure on oil-degrading bacteria has been scarce. To investigate how the biodegradation of crude oil and its components is influenced by high pressures, like those in deep-sea environments, hydrocarbon degradation and growth of two model strains were studied in high-pressure reactors. The alkane-degrading strain Rhodococcus qingshengii TUHH-12 grew well on n-hexadecane at 15 MPa at a rate of 0.16 h−1, although slightly slower than at ambient pressure (0.36 h−1). In contrast, the growth of the aromatic hydrocarbon degrading strain Sphingobium yanoikuyae B1 was highly affected by elevated pressures. Pressures of up to 8.8 MPa had little effect on growth of this strain. However, above this pressure growth decreased and at 12 MPa or more no more growth was observed. Nevertheless, S. yanoikuyae continued to convert naphthalene at pressure >12 MPa, although at a lower rate than at 0.1 MPa. This suggests that certain metabolic functions of this bacterium were inhibited by pressure to a greater extent than the enzymes responsible for naphthalene degradation. These results show that high pressure has a strong influence on the biodegradation of crude oil components and that, contrary to previous assumptions, the role of pressure cannot be discounted when estimating the biodegradation and ultimate fate of deep-sea oil releases such as the Deepwater Horizon event. PMID:25401077

  19. A high-temperature wideband pressure transducer

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.

    1977-01-01

    A condenser microphone AM carrier system, which has been developed to measure pressure fluctuations at elevated temperatures, consists of the following components: a condenser microphone designed for operation at elevated temperatures; existing carrier electronics developed under two previous research grants but adapted to meet present requirements; a 6 m cable operating as a half-wavelength transmission line between the microphone and carrier electronics; and a voltage-controlled oscillator used in a feedback loop for automatic tuning control. Both theoretical and practical aspects of the development program are considered. The three predominant effects of temperature changes are changes in the membrane-backplate gap, membrane tension, and air viscosity. The microphone is designed so that changes in gap and membrane tension tend to have compensating effects upon the microphone sensitivity.

  20. High pressure compressor component performance report

    NASA Technical Reports Server (NTRS)

    Cline, S. J.; Fesler, W.; Liu, H. S.; Lovell, R. C.; Shaffer, S. J.

    1983-01-01

    A compressor optimization study defined a 10 stage configuration with a 22.6:1 pressure ratio, an adiabatic efficiency goal of 86.1%, and a polytropic efficiency of 90.6%; the corrected airflow is 53.5 kg/s. Subsequent component testing included three full scale tests: a six stage rig test, a 10 stage rig test, and another 10 stage rig test completed in the second quarter of 1982. Information from these tests is used to select the configuration for a core engine test and an integrated core/low spool test. The test results will also provide data base for the flight propulsion system. The results of the test series with both aerodynamic and mechanical performance of each compressor build are presented. The second 10 stage compressor adiabatic efficiency was 0.848 at a cruise operating point versus a test goal of 0.846.

  1. High-pressure applications in medicine and pharmacology

    NASA Astrophysics Data System (ADS)

    Silva, Jerson L.; Foguel, Debora; Suarez, Marisa; Gomes, Andre M. O.; Oliveira, Andréa C.

    2004-04-01

    High pressure has emerged as an important tool to tackle several problems in medicine and biotechnology. Misfolded proteins, aggregates and amyloids have been studied, which point toward the understanding of the protein misfolding diseases. High hydrostatic pressure (HHP) has also been used to dissociate non-amyloid aggregates and inclusion bodies. The diverse range of diseases that result from protein misfolding has made this theme an important research focus for pharmaceutical and biotech companies. The use of high pressure promises to contribute to identifying the mechanisms behind these defects and creating therapies against these diseases. High pressure has also been used to study viruses and other infectious agents for the purpose of sterilization and in the development of vaccines. Using pressure, we have detected the presence of a ribonucleoprotein intermediate, where the coat protein is partially unfolded but bound to RNA. These intermediates are potential targets for antiviral compounds. The ability of pressure to inactivate viruses, prions and bacteria has been evaluated with a view toward the applications of vaccine development and virus sterilization. Recent studies demonstrate that pressure causes virus inactivation while preserving the immunogenic properties. There is increasing evidence that a high-pressure cycle traps a virus in the 'fusion intermediate state', not infectious but highly immunogenic.

  2. Temperature control for high pressure processes up to 1400 MPa

    NASA Astrophysics Data System (ADS)

    Reineke, K.; Mathys, A.; Heinz, V.; Knorr, D.

    2008-07-01

    Pressure- assisted sterilisation is an emerging technology. Hydrostatic high pressure can reduce the thermal load of the product and this allows quality retention in food products. To guarantee the safety of the sterilisation process it is necessary to investigate inactivation kinetics especially of bacterial spores. A significant roll during the inactivation of microorganisms under high pressure has the thermodynamic effect of the adiabatic heating. To analyse the individual effect of pressure and temperature on microorganism inactivation an exact temperature control of the sample to reach ideal adiabatic conditions and isothermal dwell times is necessary. Hence a heating/cooling block for a high pressure unit (Stansted Mini-Food-lab; high pressure capillary with 300 μL sample volume) was constructed. Without temperature control the sample would be cooled down during pressure built up, because of the non-adiabatic heating of the steel made vessel. The heating/cooling block allows an ideal adiabatic heat up and cooling of the pressure vessel during compression and decompression. The high pressure unit has a pressure build-up rate up to 250 MPa s-1 and a maximum pressure of 1400 MPa. Sebacate acid was chosen as pressure transmitting medium because it had no phase shift over the investigate pressure and temperature range. To eliminate the temperature difference between sample and vessel during compression and decompression phase, the mathematical model of the adiabatic heating/cooling of water and sebacate acid was implemented into a computational routine, written in Test Point. The calculated temperature is the setpoint of the PID controller for the heating/cooling block. This software allows an online measurement of the pressure and temperature in the vessel and the temperature at the outer wall of the vessel. The accurate temperature control, including the model of the adiabatic heating opens up the possibility to realise an ideal adiabatic heating and cooling as

  3. High Pressure Oxygen A-Band Spectra

    NASA Astrophysics Data System (ADS)

    Drouin, Brian; Sung, Keeyoon; Yu, Shanshan; Lunny, Elizabeth M.; Bui, Thinh Quoc; Okumura, Mitchio; Rupasinghe, Priyanka; Bray, Caitlin; Long, David A.; Hodges, Joseph; Robichaud, David; Benner, D. Chris; Devi, V. Malathy; Hoo, Jiajun

    2015-06-01

    Composition measurements from remote sensing platforms require knowledge of air mass to better than the desired precision of the composition. Oxygen spectra allow determination of air mass since the mixing ratio of oxygen is fixed. The OCO-2 mission is currently retrieving carbon dioxide concentration using the oxygen A-band for air mass normalization. The 0.25% accuracy desired for the carbon dioxide concentration has pushed the state-of-the-art for oxygen spectroscopy. To produce atmospheric pressure A-band cross-sections with this accuracy requires a sophisticated line-shape model (Galatry or Speed-Dependent) with line mixing (LM) and collision induced absorption (CIA). Models of each of these phenomena exist, but an integrated self-consistent model must be developed to ensure accuracy. This presentation will describe the ongoing effort to parameterize these phenomena on a representative data set created from complementary experimental techniques. The techniques include Fourier transform spectroscopy (FTS), photo-acoustic spectroscopy (PAS) and cavity ring-down spectroscopy (CRDS). CRDS data allow long-pathlength measurements with absolute intensities, providing lineshape information as well as LM and CIA, however the subtleties of the lineshape are diminished in the saturated line-centers. Conversely, the short paths and large dynamic range of the PAS data allow the full lineshape to be discerned, but with an arbitrary intensity axis. Finally, the FTS data provides intermediate paths and consistency across a broad pressure range. These spectra are all modeled with the Labfit software using first the spectral line database HITRAN, and then model values are adjusted and fitted for better agreement with the data.

  4. The effect of high pressure on nitrogen compounds of milk

    NASA Astrophysics Data System (ADS)

    Kielczewska, Katarzyna; Czerniewicz, Maria; Michalak, Joanna; Brandt, Waldemar

    2004-04-01

    The effect of pressurization at different pressures (from 200 to 1000 MPa, at 200 MPa intervals, tconst. = 15 min) and periods of time (from 15 to 35 min, at 10 min intervals, pconst. = 800 MPa) on the changes of proteins and nitrogen compounds of skimmed milk was studied. The pressurization caused an increase in the amount of soluble casein and denaturation of whey proteins. The level of nonprotein nitrogen compounds and proteoso-peptone nitrogen compounds increased as a result of the high-pressure treatment. These changes increased with an increase in pressure and exposure time. High-pressure treatment considerably affected the changes in the conformation of milk proteins, which was reflected in the changes in the content of proteins sedimenting and an increase in their degree of hydration.

  5. Rotational viscometer for high-pressure, high-temperature fluids

    DOEpatents

    Carr, K.R.

    1983-06-06

    The invention is a novel rotational viscometer which is well adapted for use with fluids at high temperatures and/or pressures. In one embodiment, the viscometer include a substantially non-magnetic tube having a closed end and having an open end in communication with a fluid whose viscosity is to be determined. An annular drive magnet is mounted for rotation about the tube. The tube encompasses and supports a rotatable shaft assembly which carries a rotor, or bob, for insertion in the fluid. Affixed to the shaft are (a) a second magnet which is magnetically coupled to the drive magnet and (b) a third magnet. In a typical operation, the drive magnet is rotated to turn the shaft assembly while the shaft rotor is immersed in the fluid. The viscous drag on the rotor causes the shaft assembly to lag the rotation of the drive magnet by an amount which is a function of the amount of viscous drag. A first magnetic pickup generates a waveform whose phase is a function of the angular position of the drive magnet. A second magnetic pickup generates a waveform whose phase is a function of the angular position of the third magnet. Means are provided to generate an output indicative of the phase difference between the two waveforms. The viscometer is comparatively simple, inexpensive, rugged, and does not require shaft seals.

  6. High pressure, high strain rate material strength studies

    NASA Astrophysics Data System (ADS)

    Remington, B. A.; Arsenlis, A.; Barton, N.; Belof, J.; Cavallo, R.; Maddox, B.; Park, H.-S.; Prisbrey, S.; Rudd, R.; Comley, A.; Meyers, M.; Wark, J.

    2011-10-01

    Constitutive models for material strength are currently being tested at high pressures by comparing 2D simulations with experiments measuring the Rayleigh-Taylor (RT) instability evolution in solid-state samples of vanadium (V), tantalum (Ta), and iron (Fe). The multiscale strength models being tested combine molecular dynamics, dislocation dynamics, and continuum simulations. Our analysis for the V experiments suggests that the material deformation at these conditions falls into the phonon drag regime, whereas for Ta, the deformation resides mainly in the thermal activation regime. Recent Fe-RT experiments suggest perturbation growth about the alpha-epsilon (bcc-hcp) phase transition threshold has been observed. Using the LLNL multiscale models, we decompose the strength as a function of strain rate into its dominant components of thermal activation, phonon drag, and work hardening. We have also developed a dynamic diffraction diagnostic technique to measure strength directly from shock compressed single crystal samples. Finally, recovery experiments allow a comparison of residual dislocation density with predictions from the multiscale model. This work performed under the auspices of the U.S. DoE by LLNL Security, LLC under Contract DE-AC52-07NA27344.

  7. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    SciTech Connect

    Vinayak N. Kabadi

    2000-05-01

    The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for this project. The modifications include better and more accurate sampling technique, addition of a digital recorder to monitor temperature and pressure inside the VLE cell, and a new technique for remote sensing of the liquid level in the cell. VLE data measurements for three binary systems, tetralin-quinoline, benzene--ethylbenzene and ethylbenzene--quinoline, have been completed. The temperature ranges of data measurements were 325 C to 370 C for the first system, 180 C to 300 C for the second system, and 225 C to 380 C for the third system. The smoothed data were found to be fairly well behaved when subjected to thermodynamic consistency tests. SETARAM C-80 calorimeter was used for incremental enthalpy and heat capacity measurements for benzene--ethylbenzene binary liquid mixtures. Data were measured from 30 C to 285 C for liquid mixtures covering the entire composition range. An apparatus has been designed for simultaneous measurement of excess volume and incremental enthalpy of liquid mixtures at temperatures from 30 C to 300 C. The apparatus has been tested and is ready for data measurements. A flow apparatus for measurement of heat of mixing of liquid mixtures at high temperatures has also been designed, and is currently being tested and calibrated.

  8. Rotational viscometer for high-pressure high-temperature fluids

    DOEpatents

    Carr, Kenneth R.

    1985-01-01

    The invention is a novel rotational viscometer which is well adapted for use with fluids at high temperatures and/or pressures. In one embodiment, the viscometer includes a substantially non-magnetic tube having a closed end and having an open end in communication with a fluid whose viscosity is to be determined. An annular drive magnet is mounted for rotation about the tube. The tube encompasses and supports a rotatable shaft assembly which carries a rotor, or bob, for insertion in the fluid. Affixed to the shaft are (a) a second magnet which is magnetically coupled to the drive magnet and (b) a third magnet. In a typical operation, the drive magnet is rotated to turn the shaft assembly while the shaft rotor is immersed in the fluid. The viscous drag on the rotor causes the shaft assembly to lag the rotation of the drive magnet by an amount which is a function of the amount of viscous drag. A first magnetic pickup generates a waveform whose phase is a function of the angular position of the drive magnet. A second magnetic pickup generates a waveform whose phase is a function of the angular position of the third magnet. An output is generated indicative of the phase difference between the two waveforms.

  9. Cryogenic Transport of High-Pressure-System Recharge Gas

    NASA Technical Reports Server (NTRS)

    Ungar, Eugene K,; Ruemmele, Warren P.; Bohannon, Carl

    2010-01-01

    A method of relatively safe, compact, efficient recharging of a high-pressure room-temperature gas supply has been proposed. In this method, the gas would be liquefied at the source for transport as a cryogenic fluid at or slightly above atmospheric pressure. Upon reaching the destination, a simple heating/expansion process would be used to (1) convert the transported cryogenic fluid to the room-temperature, high-pressure gaseous form in which it is intended to be utilized and (2) transfer the resulting gas to the storage tank of the system to be recharged. In conventional practice for recharging high-pressure-gas systems, gases are transported at room temperature in high-pressure tanks. For recharging a given system to a specified pressure, a transport tank must contain the recharge gas at a much higher pressure. At the destination, the transport tank is connected to the system storage tank to be recharged, and the pressures in the transport tank and the system storage tank are allowed to equalize. One major disadvantage of the conventional approach is that the high transport pressure poses a hazard. Another disadvantage is the waste of a significant amount of recharge gas. Because the transport tank is disconnected from the system storage tank when it is at the specified system recharge pressure, the transport tank still contains a significant amount of recharge gas (typically on the order of half of the amount transported) that cannot be used. In the proposed method, the cryogenic fluid would be transported in a suitably thermally insulated tank that would be capable of withstanding the recharge pressure of the destination tank. The tank would be equipped with quick-disconnect fluid-transfer fittings and with a low-power electric heater (which would not be used during transport). In preparation for transport, a relief valve would be attached via one of the quick-disconnect fittings (see figure). During transport, the interior of the tank would be kept at a near

  10. Studies in chemical physics through high-pressure luminescence

    SciTech Connect

    Drickamer, H.G.

    1981-01-01

    Energy transfer in chelates of Eu/sup 3 +/ with ligands (dibenzylmethane) was studied as a function of pressure. Rate of thermal dissipation of electronic excitation was correlated with viscosity and dielectric constant for indoles in a series of solvents, and with pressure for porphyrins. Effects of medium (dielectric constant, viscosity) on complexes were studied. Studies on 3-hydroxyflavone are also summarized. These studies show the power of high pressure luminescence as a tool in chemical physics. 11 figures. (DLC)

  11. High pressure synthesis gas conversion. Task 2: Determination of maximum operating pressure

    SciTech Connect

    Not Available

    1993-05-01

    The purpose of this research project was to build and test a high pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system were procured or fabricated and assembled in our laboratory. This system was then used to determine the effects of high pressure on growth and ethanol production by C. ljungdahlil. The limits of cell concentration and mass transport relationships were found in CSTR and immobilized cell reactors (ICR). The minimum retention times and reactor volumes were found for ethanol production in these reactors. The purpose of this report was to present the results of high pressure experiments aimed at determining the maximum operating pressure of C. ljungdahlil. Preliminary experiments carried out in approaching the pressure maximum are presented, as well as experimental results at the maximum pressure of 150 psig. This latter pressure was the maximum operating pressure when using the defined medium of Phillips et al., and is expected to change if alternative media are employed.

  12. Laboratory investigation of high pressure survival in Shewanella oneidensis MR-1 into the gigapascal pressure range

    PubMed Central

    Hazael, Rachael; Foglia, Fabrizia; Kardzhaliyska, Liya; Daniel, Isabelle; Meersman, Filip; McMillan, Paul

    2014-01-01

    The survival of Shewanella oneidensis MR-1 at up to 1500 MPa was investigated by laboratory studies involving exposure to high pressure followed by evaluation of survivors as the number (N) of colony forming units (CFU) that could be cultured following recovery to ambient conditions. Exposing the wild type (WT) bacteria to 250 MPa resulted in only a minor (0.7 log N units) drop in survival compared with the initial concentration of 108 cells/ml. Raising the pressure to above 500 MPa caused a large reduction in the number of viable cells observed following recovery to ambient pressure. Additional pressure increase caused a further decrease in survivability, with approximately 102 CFU/ml recorded following exposure to 1000 MPa (1 GPa) and 1.5 GPa. Pressurizing samples from colonies resuscitated from survivors that had been previously exposed to high pressure resulted in substantially greater survivor counts. Experiments were carried out to examine potential interactions between pressure and temperature variables in determining bacterial survival. One generation of survivors previously exposed to 1 GPa was compared with WT samples to investigate survival between 37 and 8°C. The results did not reveal any coupling between acquired high pressure resistance and temperature effects on growth. PMID:25452750

  13. Design principles for high-pressure force fields: Aqueous TMAO solutions from ambient to kilobar pressures.

    PubMed

    Hölzl, Christoph; Kibies, Patrick; Imoto, Sho; Frach, Roland; Suladze, Saba; Winter, Roland; Marx, Dominik; Horinek, Dominik; Kast, Stefan M

    2016-04-14

    Accurate force fields are one of the major pillars on which successful molecular dynamics simulations of complex biomolecular processes rest. They have been optimized for ambient conditions, whereas high-pressure simulations become increasingly important in pressure perturbation studies, using pressure as an independent thermodynamic variable. Here, we explore the design of non-polarizable force fields tailored to work well in the realm of kilobar pressures--while avoiding complete reparameterization. Our key is to first compute the pressure-induced electronic and structural response of a solute by combining an integral equation approach to include pressure effects on solvent structure with a quantum-chemical treatment of the solute within the embedded cluster reference interaction site model (EC-RISM) framework. Next, the solute's response to compression is taken into account by introducing pressure-dependence into selected parameters of a well-established force field. In our proof-of-principle study, the full machinery is applied to N,N,N-trimethylamine-N-oxide (TMAO) in water being a potent osmolyte that counteracts pressure denaturation. EC-RISM theory is shown to describe well the charge redistribution upon compression of TMAO(aq) to 10 kbar, which is then embodied in force field molecular dynamics by pressure-dependent partial charges. The performance of the high pressure force field is assessed by comparing to experimental and ab initio molecular dynamics data. Beyond its broad usefulness for designing non-polarizable force fields for extreme thermodynamic conditions, a good description of the pressure-response of solutions is highly recommended when constructing and validating polarizable force fields.

  14. Design principles for high-pressure force fields: Aqueous TMAO solutions from ambient to kilobar pressures

    NASA Astrophysics Data System (ADS)

    Hölzl, Christoph; Kibies, Patrick; Imoto, Sho; Frach, Roland; Suladze, Saba; Winter, Roland; Marx, Dominik; Horinek, Dominik; Kast, Stefan M.

    2016-04-01

    Accurate force fields are one of the major pillars on which successful molecular dynamics simulations of complex biomolecular processes rest. They have been optimized for ambient conditions, whereas high-pressure simulations become increasingly important in pressure perturbation studies, using pressure as an independent thermodynamic variable. Here, we explore the design of non-polarizable force fields tailored to work well in the realm of kilobar pressures - while avoiding complete reparameterization. Our key is to first compute the pressure-induced electronic and structural response of a solute by combining an integral equation approach to include pressure effects on solvent structure with a quantum-chemical treatment of the solute within the embedded cluster reference interaction site model (EC-RISM) framework. Next, the solute's response to compression is taken into account by introducing pressure-dependence into selected parameters of a well-established force field. In our proof-of-principle study, the full machinery is applied to N,N,N-trimethylamine-N-oxide (TMAO) in water being a potent osmolyte that counteracts pressure denaturation. EC-RISM theory is shown to describe well the charge redistribution upon compression of TMAO(aq) to 10 kbar, which is then embodied in force field molecular dynamics by pressure-dependent partial charges. The performance of the high pressure force field is assessed by comparing to experimental and ab initio molecular dynamics data. Beyond its broad usefulness for designing non-polarizable force fields for extreme thermodynamic conditions, a good description of the pressure-response of solutions is highly recommended when constructing and validating polarizable force fields.

  15. Criterion for Identifying Vortices in High-Pressure Flows

    NASA Technical Reports Server (NTRS)

    Bellan, Josette; Okong'o, Nora

    2007-01-01

    A study of four previously published computational criteria for identifying vortices in high-pressure flows has led to the selection of one of them as the best. This development can be expected to contribute to understanding of high-pressure flows, which occur in diverse settings, including diesel, gas turbine, and rocket engines and the atmospheres of Jupiter and other large gaseous planets. Information on the atmospheres of gaseous planets consists mainly of visual and thermal images of the flows over the planets. Also, validation of recently proposed computational models of high-pressure flows entails comparison with measurements, which are mainly of visual nature. Heretofore, the interpretation of images of high-pressure flows to identify vortices has been based on experience with low-pressure flows. However, high-pressure flows have features distinct from those of low-pressure flows, particularly in regions of high pressure gradient magnitude caused by dynamic turbulent effects and by thermodynamic mixing of chemical species. Therefore, interpretations based on low-pressure behavior may lead to misidentification of vortices and other flow structures in high-pressure flows. The study reported here was performed in recognition of the need for one or more quantitative criteria for identifying coherent flow structures - especially vortices - from previously generated flow-field data, to complement or supersede the determination of flow structures by visual inspection of instantaneous fields or flow animations. The focus in the study was on correlating visible images of flow features with various quantities computed from flow-field data.

  16. Viscosity of mafic magmas at high pressures

    NASA Astrophysics Data System (ADS)

    Cochain, B.; Sanloup, C.; Leroy, C.; Kono, Y.

    2017-01-01

    While it is accepted that silica-rich melts behave anomalously with a decrease of their viscosity at increased pressures (P), the viscosity of silica-poor melts is much less constrained. However, modeling of mantle melts dynamics throughout Earth's history, including the magma ocean era, requires precise knowledge of the viscous properties of silica-poor magmas. We extend here our previous measurements on fayalite melt to natural end-members pyroxenite melts (MgSiO3 and CaSiO3) using in situ X-ray radiography up to 8 GPa. For all compositions, viscosity decreases with P, rapidly below 5 GPa and slowly above. The magnitude of the viscosity decrease is larger for pyroxene melts than for fayalite melt and larger for the Ca end-member within pyroxene melts. The anomalous viscosity decrease appears to be a universal behavior for magmas up to 13 GPa, while the P dependence of viscosity beyond this remains to be measured. These results imply that mantle melts are very pervasive at depth.

  17. Multilayer graphane synthesized under high hydrogen pressure

    DOE PAGES

    Antonov, V. E.; Bashkin, I. O.; Bazhenov, A. V.; ...

    2015-12-19

    A new hydrocarbon – hydrographite – with the composition close to CH is shown to form from graphite and gaseous hydrogen at pressures above 2 GPa and temperatures from 450 to 700 °C. Hydrographite is a black solid thermally stable under ambient conditions. When heated in vacuum, it decomposes into graphite and molecular hydrogen at temperatures from 500 to 650 °C. Powder X-ray diffraction characterizes hydrographite as a multilayer “graphane II” phase predicted by ab initio calculations [Wen X-D et al. PNAS 2011; 108:6833] and consisting of graphane sheets in the chair conformation stacked along the hexagonal c axis inmore » the -ABAB- sequence. The crystal structure of the synthesized phase belongs to the P63mc space group. Moreover, the unit cell parameters are a = 2.53(1) Å and c = 9.54(1) Å and therefore exceed the corresponding parameters of graphite by 2.4(2)% and 42.0(3)%. Stretching vibrations of C–H groups on the surface of the hydrographite particles are examined by infrared spectroscopy.« less

  18. Multilayer graphane synthesized under high hydrogen pressure

    SciTech Connect

    Antonov, V. E.; Bashkin, I. O.; Bazhenov, A. V.; Bulychev, B. M.; Fedotov, V. K.; Fursova, T. N.; Kolesnikov, A. I.; Kulakov, V. I.; Lukashev, R. V.; Matveev, D. V.; Sakharov, M. K.; Shulga, Y. M.

    2015-12-19

    A new hydrocarbon – hydrographite – with the composition close to CH is shown to form from graphite and gaseous hydrogen at pressures above 2 GPa and temperatures from 450 to 700 °C. Hydrographite is a black solid thermally stable under ambient conditions. When heated in vacuum, it decomposes into graphite and molecular hydrogen at temperatures from 500 to 650 °C. Powder X-ray diffraction characterizes hydrographite as a multilayer “graphane II” phase predicted by ab initio calculations [Wen X-D et al. PNAS 2011; 108:6833] and consisting of graphane sheets in the chair conformation stacked along the hexagonal c axis in the -ABAB- sequence. The crystal structure of the synthesized phase belongs to the P63mc space group. Moreover, the unit cell parameters are a = 2.53(1) Å and c = 9.54(1) Å and therefore exceed the corresponding parameters of graphite by 2.4(2)% and 42.0(3)%. Stretching vibrations of C–H groups on the surface of the hydrographite particles are examined by infrared spectroscopy.

  19. Studies of Alkali Sorption Kinetics for Pressurized Fluidized Bed Combustion by High Pressure Mass Spectrometry

    SciTech Connect

    Wolf, K.J.; Willenborg, W.; Fricke, C.; Prikhodovsky, A.; Hilpert, K.; Singheiser, L.

    2002-09-20

    This work describes the first approach to use High Pressure Mass Spectrometry (HPMS) for the quantification and analysis of alkali species in a gas stream downstream a sorbent bed of different tested alumosilicates.

  20. Germination of vegetable seeds exposed to very high pressure

    NASA Astrophysics Data System (ADS)

    Mori, Y.; Yokota, S.; Ono, F.

    2012-07-01

    Effects of high hydrostatic pressure were investigated on vegetable seeds in the GPa range to examine the potentialities of breed improvement by high-pressure processing. Specimens of several seeds of broccoli (Brassica oleracea var. italica), Turnip leaf (Brassica rapa var. perviridis) and Potherb Mustard (Brassica rapa var. nipposinica) were put in a teflon capsule with liquid high pressure medium, fluorinate, and inserted into a pyrophillite cube. By using a cubic anvil press a hydrostatic pressure of 5.5 GP a was applied to these seeds for 15 minutes. After being brought back to ambient pressure, they were seeded on humid soil in a plant pot. Many of these vegetable seeds began to germinate within 6 days after seeded.