Middle to Late Devonian-Carboniferous collapse basins on the Finnmark Platform and in the southwesternmost Nordkapp basin, SW Barents Sea

NASA Astrophysics Data System (ADS)

Koehl, Jean-Baptiste P.; Bergh, Steffen G.; Henningsen, Tormod; Faleide, Jan Inge

2018-03-01

The SW Barents Sea margin experienced a pulse of extensional deformation in the Middle-Late Devonian through the Carboniferous, after the Caledonian Orogeny terminated. These events marked the initial stages of formation of major offshore basins such as the Hammerfest and Nordkapp basins. We mapped and analyzed three major fault complexes, (i) the Måsøy Fault Complex, (ii) the Rolvsøya fault, and (iii) the Troms-Finnmark Fault Complex. We discuss the formation of the Måsøy Fault Complex as a possible extensional splay of an overall NE-SW-trending, NW-dipping, basement-seated Caledonian shear zone, the Sørøya-Ingøya shear zone, which was partly inverted during the collapse of the Caledonides and accommodated top-NW normal displacement in Middle to Late Devonian-Carboniferous times. The Troms-Finnmark Fault Complex displays a zigzag-shaped pattern of NNE-SSW- and ENE-WSW-trending extensional faults before it terminates to the north as a WNW-ESE-trending, NE-dipping normal fault that separates the southwesternmost Nordkapp basin in the northeast from the western Finnmark Platform and the Gjesvær Low in the southwest. The WNW-ESE-trending, margin-oblique segment of the Troms-Finnmark Fault Complex is considered to represent the offshore prolongation of a major Neoproterozoic fault complex, the Trollfjorden-Komagelva Fault Zone, which is made of WNW-ESE-trending, subvertical faults that crop out on the island of Magerøya in NW Finnmark. Our results suggest that the Trollfjorden-Komagelva Fault Zone dies out to the northwest before reaching the western Finnmark Platform. We propose an alternative model for the origin of the WNW-ESE-trending segment of the Troms-Finnmark Fault Complex as a possible hard-linked, accommodation cross fault that developed along the Sørøy-Ingøya shear zone. This brittle fault decoupled the western Finnmark Platform from the southwesternmost Nordkapp basin and merged with the Måsøy Fault Complex in Carboniferous times. Seismic data over the Gjesvær Low and southwesternmost Nordkapp basin show that the low-gravity anomaly observed in these areas may result from the presence of Middle to Upper Devonian sedimentary units resembling those in Middle Devonian, spoon-shaped, late- to post-orogenic collapse basins in western and mid-Norway. We propose a model for the formation of the southwesternmost Nordkapp basin and its counterpart Devonian basin in the Gjesvær Low by exhumation of narrow, ENE-WSW- to NE-SW-trending basement ridges along a bowed portion of the Sørøya-Ingøya shear zone in the Middle to Late Devonian-early Carboniferous. Exhumation may have involved part of a large-scale metamorphic core complex that potentially included the Lofoten Ridge, the West Troms Basement Complex and the Norsel High. Finally, we argue that the Sørøya-Ingøya shear zone truncated and decapitated the Trollfjorden-Komagelva Fault Zone during the Caledonian Orogeny and that the western continuation of the Trollfjorden-Komagelva Fault Zone was mostly eroded and potentially partly preserved in basement highs in the SW Barents Sea.

Stage boundary recognition in the Eastern Americas realm based on rugose corals

USGS Publications Warehouse

Oliver, W.A.

2000-01-01

Most Devonian stages contain characteristic coral assemblages but these tend to be geographically and facies limited and may or may not be useful for recognising stage boundaries. Within eastern North America, corals contribute to the recognition of two boundaries: the base of the Lochkovian (Silurian-Devonian boundary) and the base of the Eifelian (Lower-Middle Devonian Series boundary).

The pre-Devonian tectonic framework of Xing'an-Mongolia orogenic belt (XMOB) in north China

NASA Astrophysics Data System (ADS)

Xu, Bei; Zhao, Pan; Wang, Yanyang; Liao, Wen; Luo, Zhiwen; Bao, Qingzhong; Zhou, Yongheng

2015-01-01

A new tectonic division of the Xing'an-Mongolia orogenic belt (XMOB) in north China has been presented according to our research and a lot of new data of tectonics, geochronology and geochemistry. Four blocks and four sutures have been recognized in the XMOB, including the Erguna (EB), Xing'an-Airgin Sum (XAB), Songliao-Hunshandake (SHB), and Jiamusi (JB), and Xinlin-Xiguitu (XXS), Xilinhot-Heihe (XHS), Mudanjiang (MS) and Ondor Sum-Yongji sutures (OYS). The framework of the XMOB is characterized by a tectonic collage of the blocks and orogenic belts between them. Different Precambrian basements have been found in the blocks, including the Neoproterozoic metamorphic rocks and plutons in the EB, the Neoproterozoic metamorphic rocks in western and eastern of segments of the XAB, Mesoproterozoic and Neoproterozoic metamorphic rocks in middle segments of the XAB, respectively, the Neoproterozoic metamorphic rocks and Mesoproterozoic volcanic rocks and plutons in the SHB, and Neoproterozoic metamorphic rocks in the JB. The XXS resulted from a northwestward subduction of the XAB beneath the EB during the Cambrian, which was followed by the forming of the XHS and OYS in the northwest and south margins of the SHB in the Silurian, respectively. The MS was caused by a westward subduction of the JB beneath the east margin of the SHB during the middle Devonian. The three Cambrian, Silurian and middle Devonian events indicate that the XMOB belongs to a pre-middle Devonian multiple orogenic belt in the Central Asian Orogenic Belt (CAOB). Forming of the XMOB suggests that the southeast part of the Paleo Asian Ocean closed before the middle Devonian.

Identification of remagnetization processes in Paleozoic sedimentary rocks of the northeast Rhenish Massif in Germany by K-Ar dating and REE tracing of authigenic illite and Fe oxides

NASA Astrophysics Data System (ADS)

Zwing, A.; Clauer, N.; Liewig, N.; Bachtadse, V.

2009-06-01

This study combines mineralogical, chemical (rare earth elemental (REE)) and isotopic (K-Ar) data of clay minerals as well as chemical compositions (major and REE) of Fe oxide leachates from remagnetized Palaeozoic sedimentary rocks from NE Rhenish Massif in Germany, for which the causes of remagnetization are not yet clear. The dominant carrier of the syntectonic, pervasive Carboniferous magnetization is magnetite. The Middle Devonian clastic rocks record an illitization event at 348 ± 7 Ma probably connected to a major magmatic event in the Mid-German Crystalline Rise, whereas a second illitization episode at 324 ± 3 Ma is coeval to the northward migrating deformation through the Rhenish Massif, being only detected in Upper Devonian and Lower Carboniferous rocks. The age of that younger illitization is not significantly different from that of the remagnetization, which, however, is not restricted to the upper part of the orogenic belt, but affects also the Middle Devonian strata. The REE patterns of the Fe-enriched leachates support two mineralization episodes with varied oxidation-reduction conditions outlined by varied Eu and Ce anomalies. This is not compatible with a unique, pervasive migration of orogenic fluids on a regional scale to explain the remagnetization in the studied region. While clay diagenesis and remagnetization are time-equivalent in Upper Devonian and Lower Carboniferous rocks, they are not so in Middle Devonian rocks. Transformation of smectite into illite cannot, therefore, account for the growth of associated authigenic magnetite, which must have been triggered by a different process. Since remagnetization and deformation ages are similar, the mechanism could relate to local physical conditions such as pressure solution and changing pore fluid pressure due to tectonic stress as well as to chemical conditions such as changing composition of the pore fluids.

Concordant paleolatitudes for Neoproterozoic ophiolitic rocks of the Trinity Complex, Klamath Mountains, California

USGS Publications Warehouse

Mankinen, E.A.; Lindsley-Griffin, N.; Griffin, J.R.

2002-01-01

New paleomagnetic results from the eastern Klamath Mountains of northern California show that Neoproterozoic rocks of the Trinity ophiolitic complex and overlying Middle Devonian volcanic rocks are latitudinally concordant with cratonal North America. Combining paleomagnetic data with regional geologic and faunal evidence suggests that the Trinity Complex and related terranes of the eastern Klamath plate were linked in some fashion to the North American craton throughout that time, but that distance between them may have varied considerably. A possible model that is consistent with our paleomagnetic results and the geologic evidence is that the Trinity Complex formed and migrated parallel to paleolatitude in the basin between Laurasia and Australia-East Antarctica as the Rodinian supercontinent began to break up. It then continued to move parallel to paleolatitude at least through Middle Devonian time. Although the eastern Klamath plate served as a nucleus against which more western components of the Klamath Mountains province amalgamated, the Klamath superterrane was not accreted to North America until Early Cretaceous time.

Towards a High-resolution Time Scale for the Early Devonian

NASA Astrophysics Data System (ADS)

Dekkers, M. J.; da Silva, A. C.

2017-12-01

High-resolution time scales are crucial to understand Earth's history in detail. The construction of a robust geological time scale, however, inevitably becomes increasingly harder further back in time. Uncertainties associated with anchor radiometric ages increase in size, not speaking of the mere presence of suitable datable strata. However, durations of stages can be tightly constrained by making use of cyclic expressions in sediments, an approach that revolutionized the Cenozoic time scale. When precisely determined durations are stitched together, ultimately, a very precise time scale is the result. For the Mesozoic and Paleozoic an astronomical solution as a tuning target is not available but the dominant periods of eccentricity, obliquity and precession are reasonably well constrained for the entire Phanerozoic which enables their detection by means of spectral analysis. Eccentricity is time-invariant and is used as the prime building block. Here we focus on the Early Devonian, on its lowermost three stages: the Lochkovian, Pragian and Emsian. The uncertainties on the Devonian stage boundaries are currently in the order of several millions of years. The preservation of climatic cycles in diagenetically or even anchimetamorphically affected successions, however, is essential. The fit of spectral peak ratios with those calculated for orbital cycles, is classically used as a strong argument for a preserved climatic signal. Here we use primarily the low field magnetic susceptibility (MS) as proxy parameter, supported by gamma-ray spectrometry to test for consistency. Continuous Wavelet Transform, Evolutive Harmonic Analysis, Multitaper Method, and Average Spectral Misfit are used to reach an optimal astronomical interpretation. We report on classic Early Devonian sections from the Czech Republic: the Pozar-CS (Lochkovian and Pragian), Pod Barrandovem (Pragian and Lower Emsian), and Zlichov (Middle-Upper Emsian). Also a Middle-Upper Emsian section from the US (Road 199 section, Kingston, New York) will be targeted. Strata display Milankovitch cycles to a varying visible degree but spectral analysis of MS with supporting magnetic property tests enables to constrain durations up to an order of magnitude more precise than in the current (2012) Geological Time Scale.

Sequence stratigraphy and a revised sea-level curve for the Middle Devonian of eastern North America

USGS Publications Warehouse

Brett, Carlton E.; Baird, G.C.; Bartholomew, A.J.; DeSantis, M.K.; Ver Straeten, C.A.

2011-01-01

The well-exposed Middle Devonian rocks of the Appalachian foreland basin (Onondaga Formation; Hamilton Group, Tully Formation, and the Genesee Group of New York State) preserve one of the most detailed records of high-order sea-level oscillation cycles for this time period in the world. Detailed examination of coeval units in distal areas of the Appalachian Basin, as well as portions of the Michigan and Illinois basins, has revealed that the pattern of high-order sea-level oscillations documented in the New York-Pennsylvania section can be positively identified in all areas of eastern North America where coeval units are preserved. The persistence of the pattern of high-order sea-level cycles across such a wide geographic area suggests that these cycles are allocyclic in nature with primary control on deposition being eustatic sea-level oscillation, as opposed to autocylic controls, such as sediment supply, which would be more local in their manifestation. There is strong evidence from studies of cyclicity and spectral analysis that these cycles are also related to Milankovitch orbital variations, with the short and long-term eccentricity cycles (100. kyr and 405. kyr) being the dominant oscillations in many settings. Relative sea-level oscillations of tens of meters are likely and raise considerable issues about the driving mechanism, given that the Middle Devonian appears to record a greenhouse phase of Phanerozoic history. These new correlations lend strong support to a revised high-resolution sea-level oscillation curve for the Middle Devonian for the eastern portion of North America. Recognized third-order sequences are: Eif-1 lower Onondaga Formation, Eif-2: upper Onondaga and Union Springs formations; Eif-Giv: Oatka Creek Formation; Giv-1: Skaneateles, Giv-2: Ludlowville, Giv-3: lower Moscow, Giv-4: upper Moscow-lower Tully, and Giv-5: middle Tully-Geneseo formations. Thus, in contrast with the widely cited eustatic curve of Johnson et al. (1985), which recognizes just one major transgressive-regressive (T-R) cycle in the early-mid Givetian (If) prior to the major late Givetian Taghanic unconformity (IIa, upper Tully-Geneseo Shale), we recognize four T-R cycles: If (restricted), Ig, Ih, and Ii. We surmise that third-order sequences record eustatic sea-level fluctuations of tens of meters with periodicities of 0.8-2. myr, while their medial-scale (fourth-order) subdivisions record lesser variations primarily of 405. kyr duration (long-term eccentricity). This high-resolution record of sea-level change provides strong evidence for high-order eustatic cycles with probable Milankovitch periodicities, despite the fact that no direct evidence for Middle Devonian glacial sediments has been found to date. ?? 2010.

Invasive species and biodiversity crises: testing the link in the late devonian.

PubMed

Stigall, Alycia L

2010-12-29

During the Late Devonian Biodiversity Crisis, the primary driver of biodiversity decline was the dramatic reduction in speciation rates, not elevated extinction rates; however, the causes of speciation decline have been previously unstudied. Speciation, the formation of new species from ancestral populations, occurs by two primary allopatric mechanisms: vicariance, where the ancestral population is passively divided into two large subpopulations that later diverge and form two daughter species, and dispersal, in which a small subset of the ancestral population actively migrates then diverges to form a new species. Studies of modern and fossil clades typically document speciation by vicariance in much higher frequencies than speciation by dispersal. To assess the mechanism behind Late Devonian speciation reduction, speciation rates were calculated within stratigraphically constrained species-level phylogenetic hypotheses for three representative clades and mode of speciation at cladogenetic events was assessed across four clades in three phyla: Arthropoda, Brachiopoda, and Mollusca. In all cases, Devonian taxa exhibited a congruent reduction in speciation rate between the Middle Devonian pre-crisis interval and the Late Devonian crisis interval. Furthermore, speciation via vicariance is almost entirely absent during the crisis interval; most episodes of speciation during this time were due to dispersal. The shutdown of speciation by vicariance during this interval was related to widespread interbasinal species invasions. The lack of Late Devonian vicariance is diametrically opposed to the pattern observed in other geologic intervals, which suggests the loss of vicariant speciation attributable to species invasions during the Late Devonian was a causal factor in the biodiversity crisis. Similarly, modern ecosystems, in which invasive species are rampant, may be expected to exhibit similar shutdown of speciation by vicariance as an outcome of the modern biodiversity crisis.

Placoderms (Armored Fish): Dominant Vertebrates of the Devonian Period

NASA Astrophysics Data System (ADS)

Young, Gavin C.

2010-05-01

Placoderms, the most diverse group of Devonian fishes, were globally distributed in all habitable freshwater and marine environments, like teleost fishes in the modern fauna. Their known evolutionary history (Early Silurian-Late Devonian) spanned at least 70 million years. Known diversity (335 genera) will increase when diverse assemblages from new areas are described. Placoderms first occur in the Early Silurian of China, but their diversity remained low until their main evolutionary radiation in the Early Devonian, after which they became the dominant vertebrates of Devonian seas. Most current placoderm data are derived from the second half of the group's evolutionary history, and recent claims that they form a paraphyletic group are based on highly derived Late Devonian forms; 16 shared derived characters are proposed here to support placoderm monophyly. Interrelationships of seven placoderm orders are unresolved because Silurian forms from China are still poorly known. The relationship of placoderms to the two major extant groups of jawed fishes—osteichthyans (bony fishes) and chondrichthyans (cartilaginous sharks, rays, and chimaeras)—remains uncertain, but the detailed preservation of placoderm internal braincase structures provides insights into the ancestral gnathostome (jawed vertebrate) condition. Placoderms provide the most complex morphological and biogeographic data set for the Middle Paleozoic; marked discrepancies in stratigraphic occurrence between different continental regions indicate strongly endemic faunas that were probably constrained by marine barriers until changes in paleogeography permitted range enlargement into new areas. Placoderm distributions in time and space indicate major faunal interchange between Gondwana and Laurussia near the Frasnian-Famennian boundary; closure of the Devonian equatorial ocean is a possible explanation.

Assessment of Appalachian basin oil and gas resources: Devonian gas shales of the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System: Chapter G.9 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Milici, Robert C.; Swezey, Christopher S.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

This report presents the results of a U.S. Geological Survey (USGS) assessment of the technically recoverable undiscovered natural gas resources in Devonian shale in the Appalachian Basin Petroleum Province of the eastern United States. These results are part of the USGS assessment in 2002 of the technically recoverable undiscovered oil and gas resources of the province. This report does not use the results of a 2011 USGS assessment of the Devonian Marcellus Shale because the area considered in the 2011 assessment is much greater than the area of the Marcellus Shale described in this report. The USGS assessment in 2002 was based on the identification of six total petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian gas shales described in this report are within the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System, which extends generally from New York to Tennessee. This total petroleum system is divided into ten assessment units (plays), four of which are classified as conventional and six as continuous. The Devonian shales described in this report make up four of these continuous assessment units. The assessment results are reported as fully risked fractiles (F95, F50, F5, and the mean); the fractiles indicate the probability of recovery of the assessment amount. The products reported are oil, gas, and natural gas liquids. The mean estimates for technically recoverable undiscovered hydrocarbons in the four gas shale assessment units are 12,195.53 billion cubic feet (12.20 trillion cubic feet) of gas and 158.91 million barrels of natural gas liquids

The Valley and Ridge Province of eastern Pennsylvania - stratigraphic and sedimentologic contributions and problems ( USA).

USGS Publications Warehouse

Epstein, J.B.

1986-01-01

The rocks in the area, which range from Middle Ordovician to Late Devonian in age, are more than 7620 m thick. This diversified group of sedimentary rocks was deposited in many different environments, ranging from deep sea, through neritic and tidal, to alluvial. In general, the Middle Ordovician through Lower Devonian strata are a sedimentary cycle related to the waxing and waning of Taconic tectonism. The sequence began with a greywacke-argillite suite (Martinsburg Formation) representing synorogenic basin deepening. This was followed by basin filling and progradation of a sandstone-shale clastic wedge (Shawangunk Formation and Bloomsburg Red Beds) derived from the erosion of the mountains that were uplifted during the Taconic orogeny. The sequence ended with deposition of many thin units of carbonate, sandstone, and shale on a shelf marginal to a land area of low relief. Another tectonic-sedimentary cycle, related to the Acadian orogeny, began with deposition of Middle Devonian rocks. Deep-water shales (Marcellus Shale) preceded shoaling (Mahantango Formation) and turbidite sedimentation (Trimmers Rock Formation) followed by another molasse (Catskill Formation). -from Author

Devonian (Emsian-Eifelian) fish from the Lower Bokkeveld Group (Ceres Subgroup), South Africa

NASA Astrophysics Data System (ADS)

Anderson, M. E.; Almond, J. E.; Evans, F. J.; Long, J. A.

1999-07-01

Four major groups of fish are represented by fragmentary remains from South Africa's Lower Bokkeveld Group of Early to Middle Devonian age: the Acanthodii, Chondrichthyes, Placodermi and Osteichthyes. These represent the oldest known occurrences of these groups in southern Africa, as well as an important addition to the very meagre record of earlier Devonian fish from the Malvinokaffric Province of southwestern Gondwana. Bokkeveld fish material comes from the Gydo (Late Emsian) and Tra Tra (Middle Eifelian) Formations of the Western Cape and Eastern Cape Provinces. The cosmopolitan marine acanthodian Machæracanthus is represented only by isolated fin spines which may belong to two different species on the basis of their external ornamentation, cross-sectional outline and internal histology. The elasmobranchs are represented by four elements: (1) a flattened chondrocranium which bears affinity to the Late Devonian-Carboniferous symmoriid (protacrodont) 'cladodont' sharks. It is probably the earliest known (Emsian) shark chondrocranium; (2) an isolated, primitive scapulocoracoid with a very short coracoidal ridge; (3) ankylosed and isolated radials, interpreted as parts of pterygial plates of a paired fin of an unknown chondrichthyan bearing affinity to the Middle Devonian Zamponiopteron from Bolivia; and (4) isolated barlike structures, perhaps gill arch or a jaw elements, thought to be from the same taxon as (3). The placoderms are represented by an incomplete trunk armour and fragmentary, finely ornamented plates of a primitive antiarch. The Osteichthyes are represented by a single large scale of an unidentified dipnoan from the Eifelian of the Cedarberg range, as well as a probable sarcopterygian dermal plate from the Emsian of the Prince Albert area. These are among the earliest sarcopterygian remains recorded from the Malvinokaffric Province.

The rise of fire: Fossil charcoal in late Devonian marine shales as an indicator of expanding terrestrial ecosystems, fire, and atmospheric change

USGS Publications Warehouse

Rimmer, Susan M.; Hawkins, Sarah J.; Scott, Andrew C.; Cressler, Walter L.

2015-01-01

Fossil charcoal provides direct evidence for fire events that, in turn, have implications for the evolution of both terrestrial ecosystems and the atmosphere. Most of the ancient charcoal record is known from terrestrial or nearshore environments and indicates the earliest occurrences of fire in the Late Silurian. However, despite the rise in available fuel through the Devonian as vascular land plants became larger and trees and forests evolved, charcoal occurrences are very sparse until the Early Mississippian where extensive charcoal suggests well-established fire systems. We present data from the latest Devonian and Early Mississippian of North America from terrestrial and marine rocks indicating that fire became more widespread and significant at this time. This increase may be a function of rising O2 levels and the occurrence of fire itself may have contributed to this rise through positive feedback. Recent atmospheric modeling suggests an O2 low during the Middle Devonian (around 17.5%), with O2 rising steadily through the Late Devonian and Early Mississippian (to 21–22%) that allowed for widespread burning for the first time. In Devonian-Mississippian marine black shales, fossil charcoal (inertinite) steadily increases up-section suggesting the rise of widespread fire systems. There is a concomitant increase in the amount of vitrinite (preserved woody and other plant tissues) that also suggests increased sources of terrestrial organic matter. Even as end Devonian glaciation was experienced, fossil charcoal continued to be a source of organic matter being introduced into the Devonian oceans. Scanning electron and reflectance microscopy of charcoal from Late Devonian terrestrial sites indicate that the fires were moderately hot (typically 500–600 °C) and burnt mainly surface vegetation dominated by herbaceous zygopterid ferns and lycopsids, rather than being produced by forest crown fires. The occurrence and relative abundance of fossil charcoal in marine black shales are significant in that these shales may provide a more continuous record of fire than is preserved in terrestrial environments. Our data support the idea that major fires are not seen in the fossil record until there is both sufficient and connected fuel and a high enough atmospheric O2 content for it to burn.

Paleomagnetism of Devonian dykes in the northern Kola Peninsula and its bearing on the apparent polar wander path of Baltica in the Precambrian

NASA Astrophysics Data System (ADS)

Veselovskiy, Roman V.; Bazhenov, Mikhail L.; Arzamastsev, Andrey A.

2016-04-01

Mafic dykes and large alkaline and carbonatite intrusions of Middle-Late Devonian age are widespread on the Kola Peninsula in NE Fennoscandia. These magmatic rocks are well characterized with petrographic, geochemical and geochronological data but no paleomagnetic results have been reported yet. We studied dolerite dykes from the northern part of the Peninsula and isolated three paleomagnetic components in these rocks. A low-temperature component is aligned along the present-day field, while a major constituent of natural remanent magnetization is an intermediate-temperature component (Decl. = 79.6°, Inc. = 78.5°, α95 = 5,9°, N = 17 sites) that is present in most Devonian dykes but is found in some baked metamorphic rocks and Proterozoic dykes too. Finally, a primary Devonian component could be reliably isolated from two dykes only. Rock-magnetic studies point to presumably primary low-Ti titanomagnetite and/or pure magnetite as the main remanence carriers but also reveal alteration of the primary minerals and the formation of new magnetic phases. The directions of a major component differ from the Middle Paleozoic reference data for Baltica but closely match those for the 190 ± 10 Ma interval recalculated from the apparent polar wander path of the craton. We assume that this Early Jurassic component is a low-temperature overprint of chemical origin. The main impact of the new results is not to mid-Paleozoic or Early Mesozoic times but to much older epochs. Analysis of paleomagnetic data shows that the directionally similar remanences are present in objects with the ages ranging from 500 Ma to 2 Ga over entire Fennoscandia. Hence we argue that an Early Jurassic remagnetization is of regional extent but cannot link it to a certain process and a certain tectonic event. If true, this hypothesis necessitates a major revision of the APWP for Baltica over a wide time interval.

Geometry of an outcrop-scale duplex in Devonian flysch, Maine

USGS Publications Warehouse

Bradley, D.C.; Bradley, L.M.

1994-01-01

We describe an outcrop-scale duplex consisting of 211 exposed repetitions of a single bed. The duplex marks an early Acadian (Middle Devonian) oblique thrust zone in the Lower Devonian flysch of northern Maine. Detailed mapping at a scale of 1:8 has enabled us to measure accurately parameters such as horse length and thickness, ramp angles and displacements; we compare these and derivative values with those of published descriptions of duplexes, and with theoretical models. Shortening estimates based on line balancing are consistently smaller than two methods of area balancing, suggesting that layer-parallel shortening preceded thrusting. ?? 1994.

Dutrochus, a new microdomatid (Gastropoda) genus from the Middle Devonian (Eifelian) of west-central Alaska

USGS Publications Warehouse

Blodgett, R.B.

1993-01-01

A new gastropod genus, Dutrochus, is established for members of the family Microdomatidae that are characterized by a reticulate ornament of spiral cords and intersecting, finer collabral threads, with all but one spiral cord being of nearly equal strength, and the single remaining cord being of stronger (nearly twice the order) magnitude and being situated at the periphery. It is represented by the type and only known species, Dutrochus alaskensis n. gen. and sp., from the upper part (lower Eifelian) of the Lower? and Middle Devonian Cheeneetnuk Limestone. The genus is very close and nearly homeomorphic to the Permian microdomatid genus Glyptospira. -from Author

Origins and relationships of colonial Heliophyllum in the upper Middle Devonian (Givetian) of New York

USGS Publications Warehouse

Oliver, W.A.

1997-01-01

Heliophyllum halli Milne-Edwards and Haime is common to abundant in many Lower and Middle Devonian stratigraphic units in New York. Most Heliophyllum are solitary, but both branching and massive colonies are known. Four 'populations' of colonial Heliophyllum in the Givetian part of the sequence are distinct, as is a fifth form that occurs through the section. Each of the colonial forms is interpreted as an independent derivative of solitary forms of H. halli. The relationships appear to range from infrasubspecific to specific, and it is suggested that the complex should be recognized as the Heliophyllum halli species group.

Representatives of the family Actinostromatidae (Stromatoporoidea) in the Devonian of southern Poland and their ecological significance

NASA Astrophysics Data System (ADS)

Wolniewicz, Paweł

2016-09-01

Stromatoporoids of the family Actinostromatidae are common constituents of Givetian to Frasnian (Devonian) organic buildups. The species-level structure of actinostromatid assemblages from the Devonian of southern Poland is described in the present paper, with special emphasis on ecological factors that influenced species composition of the communities. Nine species of the genera Actinostroma and Bifariostroma are distinguished. Members of the family Actinostromatidae predominated in stromatoporoid assemblages within lower Frasnian carbonate buildup margins. The most diverse actinostromatid faunas were found within the middle Givetian Stringocephalus Bank, in the upper Givetian-lower Frasnian biostromal complex and in the lower Frasnian organic buildups. Species-level biodiversity was lowest within detrital facies which surrounded the Frasnian carbonate buildups. Species of Actinostroma with well-developed colliculi are commonest within the middle Givetian to early Frasnian coral-stromatoporoid biostromal complexes, whereas species with strongly reduced colliculi predominate early-middle Frasnian organic buildups. The skeletal structure of actinostromatids reflects environmental changes, documenting a transition from species with thin, close-set pillars and widely spaced laminae (common in the middle Givetian) to those with long, thick pillars and megapillars (in Bifariostroma), which were predominant during the early and middle Frasnian. The distribution of growth forms among species reveals a significant intraspecific variation. Species of Actinostroma can be either tabular or low domical, depending on the palaeoenvironmental setting. Thus, the present study confirms that stromatoporoid morphology was influenced by environmental conditions.

Geology of the Devonian Marcellus Shale--Valley and Ridge province, Virginia and West Virginia--a field trip guidebook for the American Association of Petroleum Geologists Eastern Section Meeting, September 28-29, 2011

USGS Publications Warehouse

Enomoto, Catherine B.; Coleman, James L.; Haynes, John T.; Whitmeyer, Steven J.; McDowell, Ronald R.; Lewis, J. Eric; Spear, Tyler P.; Swezey, Christopher S.

2012-01-01

Detailed and reconnaissance field mapping and the results of geochemical and mineralogical analyses of outcrop samples indicate that the Devonian shales of the Broadtop Synclinorium from central Virginia to southern Pennsylvania have an organic content sufficiently high and a thermal maturity sufficiently moderate to be considered for a shale gas play. The organically rich Middle Devonian Marcellus Shale is present throughout most of the synclinorium, being absent only where it has been eroded from the crests of anticlines. Geochemical analyses of outcrop and well samples indicate that hydrocarbons have been generated and expelled from the kerogen originally in place in the shale. The mineralogical characteristics of the Marcellus Shale samples from the Broadtop Synclinorium are slightly different from the averages of samples from New York, Pennsylvania, northeast Ohio, and northern West Virginia. The Middle Devonian shale interval is moderately to heavily fractured in all areas, but in some areas substantial fault shearing has removed a regular "cleat" system of fractures. Conventional anticlinal gas fields in the study area that are productive from the Lower Devonian Oriskany Sandstone suggest that a continuous shale gas system may be in place within the Marcellus Shale interval at least in a portion of the synclinorium. Third-order intraformational deformation is evident within the Marcellus shale exposures. Correlations between outcrops and geophysical logs from exploration wells nearby will be examined by field trip attendees.

An exceptionally preserved Late Devonian actinopterygian provides a new model for primitive cranial anatomy in ray-finned fishes

PubMed Central

Giles, Sam; Darras, Laurent; Clément, Gaël; Blieck, Alain; Friedman, Matt

2015-01-01

Actinopterygians (ray-finned fishes) are the most diverse living osteichthyan (bony vertebrate) group, with a rich fossil record. However, details of their earliest history during the middle Palaeozoic (Devonian) ‘Age of Fishes' remains sketchy. This stems from an uneven understanding of anatomy in early actinopterygians, with a few well-known species dominating perceptions of primitive conditions. Here we present an exceptionally preserved ray-finned fish from the Late Devonian (Middle Frasnian, ca 373 Ma) of Pas-de-Calais, northern France. This new genus is represented by a single, three-dimensionally preserved skull. CT scanning reveals the presence of an almost complete braincase along with near-fully articulated mandibular, hyoid and gill arches. The neurocranium differs from the coeval Mimipiscis in displaying a short aortic canal with a distinct posterior notch, long grooves for the lateral dorsal aortae, large vestibular fontanelles and a broad postorbital process. Identification of similar but previously unrecognized features in other Devonian actinopterygians suggests that aspects of braincase anatomy in Mimipiscis are apomorphic, questioning its ubiquity as stand-in for generalized actinopterygian conditions. However, the gill skeleton of the new form broadly corresponds to that of Mimipiscis, and adds to an emerging picture of primitive branchial architecture in crown gnathostomes. The new genus is recovered in a polytomy with Mimiidae and a subset of Devonian and stratigraphically younger actinopterygians, with no support found for a monophyletic grouping of Moythomasia with Mimiidae. PMID:26423841

The Devonian Marcellus Shale and Millboro Shale

USGS Publications Warehouse

Soeder, Daniel J.; Enomoto, Catherine B.; Chermak, John A.

2014-01-01

The recent development of unconventional oil and natural gas resources in the United States builds upon many decades of research, which included resource assessment and the development of well completion and extraction technology. The Eastern Gas Shales Project, funded by the U.S. Department of Energy in the 1980s, investigated the gas potential of organic-rich, Devonian black shales in the Appalachian, Michigan, and Illinois basins. One of these eastern shales is the Middle Devonian Marcellus Shale, which has been extensively developed for natural gas and natural gas liquids since 2007. The Marcellus is one of the basal units in a thick Devonian shale sedimentary sequence in the Appalachian basin. The Marcellus rests on the Onondaga Limestone throughout most of the basin, or on the time-equivalent Needmore Shale in the southeastern parts of the basin. Another basal unit, the Huntersville Chert, underlies the Marcellus in the southern part of the basin. The Devonian section is compressed to the south, and the Marcellus Shale, along with several overlying units, grades into the age-equivalent Millboro Shale in Virginia. The Marcellus-Millboro interval is far from a uniform slab of black rock. This field trip will examine a number of natural and engineered exposures in the vicinity of the West Virginia–Virginia state line, where participants will have the opportunity to view a variety of sedimentary facies within the shale itself, sedimentary structures, tectonic structures, fossils, overlying and underlying formations, volcaniclastic ash beds, and to view a basaltic intrusion.

Devonian post-orogenic extension-related volcano-sedimentary rocks in the northern margin of the Tibetan Plateau, NW China: Implications for the Paleozoic tectonic transition in the North Qaidam Orogen

NASA Astrophysics Data System (ADS)

Qin, Yu; Feng, Qiao; Chen, Gang; Chen, Yan; Zou, Kaizhen; Liu, Qian; Jiao, Qianqian; Zhou, Dingwu; Pan, Lihui; Gao, Jindong

2018-05-01

The Maoniushan Formation in the northern part of the North Qaidam Orogen (NQO), NW China, contains key information on a Paleozoic change in tectonic setting of the NQO from compression to extension. Here, new zircon U-Pb, petrological, and sedimentological data for the lower molasse sequence of the Maoniushan Formation are used to constrain the timing of this tectonic transition. Detrital zircons yield U-Pb ages of 3.3-0.4 Ga with major populations at 0.53-0.4, 1.0-0.56, 2.5-1.0, and 3.3-2.5 Ga. The maximum depositional age of the Maoniushan Formation is well constrained by a youngest detrital zircon age of ∼409 Ma. Comparing these dates with geochronological data for the region indicates that Proterozoic-Paleozoic zircons were derived mainly from the NQO as well as the Oulongbuluk and Qaidam blocks, whereas Archean zircons were probably derived from the Oulongbuluk Block and the Tarim Craton. The ∼924, ∼463, and ∼439 Ma tectonothermal events recorded in this region indicate that the NQO was involved in the early Neoproterozoic assembly of Rodinia and early Paleozoic microcontinental convergence. A regional angular unconformity between Devonian and pre-Devonian strata within the NQO suggests a period of strong mountain building between the Oulongbuluk and Qaidam blocks during the Silurian, whereas an Early Devonian post-orogenic molasse, evidence of extensional collapse, and Middle to Late Devonian bimodal volcanic rocks and Carboniferous marine carbonate rocks clearly reflect long-lived tectonic extension. Based on these results and the regional geology, we suggest that the Devonian volcano-sedimentary rocks within the NQO were formed in a post-orogenic extensional setting similar to that of the East Kunlun Orogen, indicating that a major tectonic transition from compression to extension in these two orogens probably commenced in the Early Devonian.

Geological Structure of the Basement of Western and Eastern Parts of the West-Siberian Plain

ERIC Educational Resources Information Center

Ivanov, Kirill S.; Erokhin, Yuriy V.; Ponomarev, Vladimir S.; Pogromskaya, Olga E.; Berzin, Stepan V.

2016-01-01

The U-Pb dating (SHRIMP-II on zircon) was obtained for the first time from the basement of the West Siberian Plain in the Western half of the region. It is established that a large part of the protolith of the metamorphic depth in the Shaim-Kuznetsov meganticlinorium contained sedimentary late- and middle-Devonian rocks (395-358 million years).…

Paleozoic subduction complex and Paleozoic-Mesozoic island-arc volcano-plutonic assemblages in the northern Sierra terrane

USGS Publications Warehouse

Hanson, Richard E.; Girty, Gary H.; Harwood, David S.; Schweickert, Richard A.

2000-01-01

This field trip provides an overview of the stratigraphic and structural evolution of the northern Sierra terrane, which forms a significant part of the wall rocks on the western side of the later Mesozoic Sierra Nevada batholith in California. The terrane consists of a pre-Late Devonian subduction complex (Shoo Fly Complex) overlain by submarine arc-related deposits that record the evolution of three separate island-arc systems in the Late Sevonian-Early Mississippian, Permian, and Late Triassic-Jurassic. The two Paleozoic are packages and the underlying Shoo Fly Complex have an important bearing on plate-tectonic processes affecting the convergent margin outboard of the Paleozoic Cordilleran miogeocline, although their original paleogeographic relations to North America are controversial. The third arc package represents an overlap assemblage that ties the terrane to North America by the Late Triassic and helps constrain the nature and timing of Mesozoic orogenesis. Several of the field-trip stops examine the record of pre-Late Devonian subduction contained in the Shoo Fly Complex, as well as the paleovolcanology of the overlying Devonian to Jurassic arc rocks. Excellent glaciated exposures provide the opportunity to study a cross section through a tilted Devonian volcano-plutonic association. Additional stops focus on plutonic rocks emplaced during the Middle Jurassic arc magmatism in the terrane, and during the main pulse of Cretaceous magmatism in the Sierra Nevada batholith to the east.

Paracontinuous boundaries within the Devonian Columbus Limestone and Delaware Formation of central Ohio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conkin, J.E.; Conkin, B.M.

1994-04-01

Internal units within the Columbus Limestone (Early Devonian Emsian [Schoharie] to Middle Devonian Eifelian [late Onesquethawan]) and the Delaware Formation (Middle Devonian early Givetian [Cazenovian]) of central Ohio are separated by disconformities of the magnitude of paracontinuities. Stauffer (1909) divided the Columbus Limestone into zones A--H and the Delaware Formation into zones I--M. Within the Columbus, the A Zone (conglomerate at the base of Bellepoint Member) disconformably overlies Late Silurian beds. The D zone at top of the Bellepoint Member (bearing the Kawkawlin Metabentonite horizon) is overlain paracontinuously by the Marblehead Member (Lower Paraspirifer acuminatus-Spirifer macrothyris to Brevispirifer gregarius-Moellerina greeneimore » zones [= E--G zones]), with the Onondagan Indian Nation Metabentonite in the top of the G Zone. The Marblehead Member is overlain paracontinuously by a bone bed at base of the Venice Member (H zone = Upper Paraspirifer acuminatus- Spirifer duodenarius'' Zone). I Zone (Dublin Shale=Marcellus) of the Delaware Formation overlies the Columbus and has two bone beds at its base; Tioga Metabentonite (restricted) overlies the I Zone bone beds and is a few tenths to 1.85 feet above the base of the I Zone. Paracontinuities and bone beds occur at the bases of J, K, and L zones. Conkin and Conkin (1975) have shown Stauffer's (1909) M Zone is an extension of his L Zone. The Olentangy paracontinuously overlies the L Zone.« less

New U-Pb zircon ages and the duration and division of Devonian time

USGS Publications Warehouse

Tucker, R.D.; Bradley, D.C.; Ver Straeten, C.A.; Harris, A.G.; Ebert, J.R.; McCutcheon, S.R.

1998-01-01

Newly determined U-Pb zircon ages of volcanic ashes closely tied to biostratigraphic zones are used to revise the Devonian time-scale. They are: 1) 417.6 ?? 1.0 Ma for an ash within the conodont zone of Icriodus woschmidti/I. w. hesperius Lochkovian); 2) 408.3 ?? 1.9 Ma for an ash of early Emsian age correlated with the conodont zones of Po. dehiscens--Lower Po. inversus; 3) 391.4 ?? 1.8 Ma for an ash within the Po. c. costatus Zone and probably within the upper half of the zone (Eifelian); and 4) 381.1 ?? 1.3 Ma for an ash within the range of the Frasnian conodont Palmatolepis punctata (Pa. punctata Zone to Upper Pa. hassi Zone). U-Pb zircon ages for two rhyolites bracketing a palyniferous bed of the pusillites-lepidophyta spore zone, are dated at 363.8 ?? 2.2 Ma and 363 ?? 2.2 Ma and 363.4 ?? 1.8 Ma, respectively, suggesting an age of ~363 Ma for a level within the late Famennian Pa. g. expansa Zone. These data, together with other published zircon ages, suggest that the base and top of the Devonian lie close to 418 Ma and 362 Ma, respectively, thus lengthening the period of ~20% over current estimates. We suggest that the duration of the Middle Devonian (Eifelian and Givitian) is rather brief, perhaps no longer than 11.5 Myr (394 Ma-382.5 Ma), and that the Emsian and Famennian are the longest stages in the period with estimated durations of ~15.5 Myr and 14.5 Myr, respectively.

Devonian alkaline magmatic belt along the northern margin of the North China Block: Petrogenesis and tectonic implications

NASA Astrophysics Data System (ADS)

Zhang, Qi-Qi; Zhang, Shuan-Hong; Zhao, Yue; Liu, Jian-Min

2018-03-01

Some Devonian magmatic rocks have been identified from the northern margin of the North China Block (NCB) in recent years. However, their petrogenesis and tectonic setting are still highly controversial. Here we present new geochronological, Sr-Nd-Hf isotopic and whole-rock chemical data on several newly identified and previously reported Devonian alkaline complexes, including mafic-ultramafic rocks (pyroxenites and gabbros), alkaline rocks (syenites, monzonites) and alkaline granites in the northern NCB. We firstly identified some mafic-ultramafic rocks coeval with monzonite and quartz monzonite in the Sandaogou and Wulanhada alkaline intrusions. New zircon U-Pb dating of 16 samples from the Baicaigou, Gaojiacun, Sandaogou, Wulanhada and Chifeng alkaline intrusions combined with previous geochronological results indicate that the Devonian alkaline rocks emplaced during the early-middle Devonian at around 400-380 Ma and constitute an E-W-trending alkaline magmatic belt that extend ca. 900 km long along the northern margin of the NCB. Whole-rock geochemical and Sr-Nd-Hf isotopic data reveal that the Devonian alkaline rocks were mainly originated from partial melting of a variably enriched lithospheric mantle with different involvement of ancient lower crustal component and fractional crystallization. The Devonian alkaline magmatic belt rocks in the northern NCB are characterized by very weak or no deformations and were most likely related to post-collision extension after arc-continent collision between the Bainaimiao island arc and the northern margin of North China Craton during the latest Silurian. Partial melting of subcontinental lithospheric mantle to produce the Devonian alkaline magmatic rocks suggests that the northern North China Craton has an inhomogeneous, variably enriched subcontinental lithospheric mantle and was characterized by significant vertical crustal growth during the Devonian period.

Rock-inhabiting fungi originated during periods of dry climate in the late Devonian and middle Triassic.

PubMed

Gueidan, Cécile; Ruibal, Constantino; de Hoog, G S; Schneider, Harald

2011-10-01

Non-lichenized rock-inhabiting fungi (RIF) are slow-growing melanized ascomycetes colonizing rock surfaces in arid environments. They possess adaptations, which allow them to tolerate extreme abiotic conditions, such as high UV radiations and extreme temperatures. They belong to two separate lineages, one consisting in the sister classes Dothideomycetes and Arthoniomycetes (Dothideomyceta), and the other consisting in the order Chaetothyriales (Eurotiomycetes). Because RIF often form early diverging groups in Chaetothyriales and Dothideomyceta, the ancestors of these two lineages were suggested to most likely be rock-inhabitants. The lineage of RIF related to the Chaetothyriales shows a much narrower phylogenetic spectrum than the lineage of RIF related to Dothideomyceta, suggesting a much more ancient origin for the latter. Our study aims at investigating the times of origin of RIF using a relaxed clock model and several fossil and secondary calibrations. Our results show that the RIF in Dothideomyceta evolved in the late Devonian, much earlier than the RIF in Chaetothyriales, which originated in the middle Triassic. The origin of the chaetothyrialean RIF correlates well with a period of recovery after the Permian-Triassic mass extinction and an expansion of arid landmasses. The period preceding the diversification of the RIF related to Dothideomyceta (Silurian--Devonian) is also characterized by large arid landmasses, but temperatures were much cooler than during the Triassic. The paleoclimate record provides a good explanation for the diversification of fungi subjected to abiotic stresses and adapted to life on rock surfaces in nutrient-poor habitats. Copyright © 2011 British Mycological Society. Published by Elsevier Ltd. All rights reserved.

Two hundred years of palaeontological discovery: Review of research on the Early to Middle Devonian Bokkeveld Group (Cape Supergroup) of South Africa

NASA Astrophysics Data System (ADS)

Penn-Clarke, C. R.; Rubidge, B. S.; Jinnah, Z. A.

2018-01-01

Documentation of the palaeontological heritage of the Early to Middle Devonian Bokkeveld Group of South Africa has been recorded as far back as the early nineteenth century with the arrival of the first European settlers, merchants and explorers to the Cape region. Anecdotal evidence suggests that indigenous peoples had knowledge of fossils in the Bokkeveld Group from as early as the Middle-to-Late Stone Age. Within the first hundred years of the expansion of the Cape Colony the first geological maps of the Bokkeveld Group were produced alongside the first description of fossils as well as their Devonian age and marine origin. These early investigations provided a foundation for establishing faunal endemism common to South Africa, South America and the Falkland Islands. During the early twentieth century considerable progress was made in the description of fossil fauna of the Bokkeveld Group, most notably of invertebrates and plants. This research demonstrated that invertebrate fossils from the Bokkeveld Group, as well as those from time equivalents in South America and the Falkland Islands, were distinct from the Devonian Period elsewhere (e.g. Europe and North America). The role of fossils from the Bokkeveld Group proved critical in the formal designation and delineation of a broad region of endemism, the Malvinokaffric Realm that persisted at high subpolar-to-polar palaeolatitudes in southwestern Gondwana and extended from South Africa, Bolivia, Brazil, Argentina, Antarctica and the Falkland Islands with possible elements in Guinea-Bissau, Senegal and Ghana during the Emsian-Eifelian Stages. In the latter half of the twentieth century developments in understanding the sedimentology and stratigraphy of the Bokkeveld Group lead to the premise that the succession accumulated in a storm-and-wave dominated deltaic palaeoenvironment, and enabled inferences on the palaeoecology of the fossil taxa. During this period detailed revisions of numerous invertebrate and plant taxa were undertaken as well as the first descriptions of fossil fish. Research in the twenty-first century has shown a general decline in palaeontological interest, but developments are currently underway in refining the taxonomy of fossil echinoderms and fish from the Bokkeveld Group as well as understanding the Group's palaeoenvironmental history, geochronology and understanding the decline of the Malvinokaffric Realm in South Africa and its causation.

Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant

NASA Astrophysics Data System (ADS)

Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J.; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F.; Hao, Shougang

2016-08-01

The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant-soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus. The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet-dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant-soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated.

Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant.

PubMed

Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F; Hao, Shougang

2016-08-23

The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant-soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet-dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant-soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated.

Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant

PubMed Central

Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J.; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F.; Hao, Shougang

2016-01-01

The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant−soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus. The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet−dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant−soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated. PMID:27503883

Paleozoic strata of the Dyckman Mountain area, northeastern Medfra quadrangle, Alaska: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1998

USGS Publications Warehouse

Dumoulin, Julie A.; Bradley, Dwight C.; Harris, Anita G.

2000-01-01

Paleozoic rocks in the Dyckman Mountain area (northeastern Medfra quadrangle; Farewell terrane) include both shallowand deep-water lithologies deposited on and adjacent to a carbonate platform. Shallow-water strata, which were recognized by earlier workers but not previously studied in detail, consist of algal-laminated micrite and skeletal-peloidal wackestone, packstone, and lesser grainstone. These rocks are, at least in part, of Early and (or) Middle Devonian age but locally could be as old as Silurian; they accumulated in shallow subtidal to intertidal settings with periodically restricted water circulation. Deepwater facies, reported here for the first time, are thin, locally graded beds of micrite and calcisiltite and subordinate thick to massive beds of lime grainstone and conglomerate. Conodonts indicate an age of Silurian to Middle Devonian; the most tightly dated intervals are early Late Silurian (early to middle Ludlow). These strata formed as hemipelagic deposits, turbidites, and debris flows derived from shallow-water lithologies of the Nixon Fork subterrane. Rocks in the Dyckman Mountain area are part of a broader facies belt that is transitional between the Nixon Fork carbonate platform to the west and deeper water, basinal lithologies (Minchumina “terrane”) to the east. Transitional facies patterns are complex because of Paleozoic shifts in the position of the platform margin, Mesozoic shortening, and Late Cretaceous-Tertiary disruption by strike-slip faulting.

History of displacement along Ste. Genevieve Fault Zone, Southwestern Illinois

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwalb, H.R.

1983-09-01

The Ste. Genevieve fault zone extends eastward from Missouri across the Mississippi River into Jackson County, Illinois, about 75 mi (120 km) southeast of St. Louis. Outcrop studies have dated movement along portions of the zone as pre-Middle Devonian, post-Mississippian, and post-Pennsylvanian. Present displacement is down to the north and east with throw ranging up to 3,000 ft (915 m). However, pre-Middle Devonian movement was down to the south and west. The present upthrown block shows no evidence of vertical movement during the Cambrian and Ordovician. Nor is there any indication that the fault zone was part of the northernmore » border of the Reelfoot basin, where earliest Paleozoic sediments infilled an aulacogen at the northern end of the Mississippi embayment.« less

Deep in shadows, deep in time: the oldest mesophotic coral ecosystems from the Devonian of the Holy Cross Mountains (Poland)

NASA Astrophysics Data System (ADS)

Zapalski, Mikołaj K.; Wrzołek, Tomasz; Skompski, Stanisław; Berkowski, Błażej

2017-09-01

Recent mesophotic coral ecosystems (MCE) occur at depths between 30 and 150 m and are characterized by dominance of platy corals. Such morphology is an effect of specific adaptation to efficient light harvesting. Here, we describe and analyze platy coral assemblages from two Middle Devonian localities in the Holy Cross Mountains (Poland) that during this time were located on the southern shelf of Laurussia at tropical latitudes. The Eifelian argillaceous sediments of Skały are dominated by platy and encrusting tabulate corals ( Roseoporella, Platyaxum and Alveolites). Coeval faunas from the shallow-water parts of the Holy Cross Mountains basin display bulbous and branching morphology, thus indicating a Paleozoic coral zonation similar to that known in the Recent. Hence, the Skały site seems to be the oldest known MCE (ca. 390 Ma). A Givetian biostrome from Laskowa Quarry is a second example dominated by platy corals, with abundant branching forms; this site can be recognized as another Devonian MCE. Frondescent Platyaxum, common at both sites, had a growth habit similar to that of Recent Leptoseris, Mycedium or Pavona. Platy morphology is photoadaptive and may evidence photosymbiosis in tabulate ( Alveolites, Roseoporella, Platyaxum) and rugose corals ( Phillipsastrea). Furthermore, it may serve as a tool for recognition of the lower euphotic zone in the fossil record.

Implications of latest Pennsylvanian to Middle Permian paleontological and U-Pb SHRIMP data from the Tecomate Formation to re-dating tectonothermal events in the Acatlán Complex, Southern Mexico

USGS Publications Warehouse

Keppie, J. Duncan; Sandberg, Charles A.; Miller, B.V.; Sanchez-Zavala, J. L.; Nance, R.D.; Poole, Forrest G.

2004-01-01

Limestones in the highly deformed Tecomate Formation, uppermost unit of the Acatla??n Complex, are latest Pennsylvanian-earliest Middle Permian in age rather than Devonian, the latter based on less diagnostic fossils. Conodont collections from two marble horizons now constrain its age to range from latest Pennsylvanian to latest Early Permian or early Middle Permian. The older collection contains Gondolella sp., Neostreptognathodus sp., and Streptognathodus sp., suggesting an oldest age limit close to the Pennsylvanian-Permian time boundary. The other collection contains Sweet-ognathus subsymmetricus, a short-lived species ranging only from Kungurian (latest Leonardian) to Wordian (earliest Guadelupian: 272 ?? 4 to 264 ?? 2 Ma). A fusilinid, Parafusulina c.f. P. antimonioensis Dunbar, in a third Tecomate marble horizon is probably Wordian (early Guadelupian, early Middle Permian). Furthermore, granite pebbles in a Tecomate conglomerate have yielded ???320-264 Ma U-Pb SHRIMP ages probably derived from the ???288 Ma, arc-related Totoltepec pluton. Collectively, these data suggest a correlation with two nearby units: (1) the Missourian-Leonardian carbonate horizons separated by a Wolfcampian(?) conglomerate in the upper part of the less deformed San Salvador Patlanoaya Formation; and (2) the clastic, Westphalian-Leonardian Matzitzi Formation. This requires that deformation in the Tecomate Formation be of Early-Middle Permian age rather than Devonian. These three formations are re-interpreted as periarc deposits with deformation related to oblique subduction. The revised dating of the Tecomate Formation is consistent with new data, which indicates that the unconformity between the Tecomate and the Piaxtla Group is mid-Carboniferous and corresponds to a tectonothermal event. ?? 2004 by V. H. Winston and Son, Inc. All rights reserved.

The potential source of lead in the Permian Kupferschiefer bed of Europe and some selected Paleozoic mineral deposits in the Federal Republic of Germany

USGS Publications Warehouse

Wedepohl, K.H.; Delevaux, M.H.; Doe, B.R.

1978-01-01

New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed. ?? 1978 Springer-Verlag.

A Systems Approach to Identifying Exploration and Development Opportunities in the Illinois Basin: Digital Portifolio of Plays in Underexplored Lower Paleozoic Rocks [Part 1 of 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seyler, Beverly; Harris, David; Keith, Brian

2008-06-30

This study examined petroleum occurrence in Ordovician, Silurian and Devonian reservoirs in the Illinois Basin. Results from this project show that there is excellent potential for additional discovery of petroleum reservoirs in these formations. Numerous exploration targets and exploration strategies were identified that can be used to increase production from these underexplored strata. Some of the challenges to exploration of deeper strata include the lack of subsurface data, lack of understanding of regional facies changes, lack of understanding the role of diagenetic alteration in developing reservoir porosity and permeability, the shifting of structural closures with depth, overlooking potential producing horizons,more » and under utilization of 3D seismic techniques. This study has shown many areas are prospective for additional discoveries in lower Paleozoic strata in the Illinois Basin. This project implemented a systematic basin analysis approach that is expected to encourage exploration for petroleum in lower Paleozoic rocks of the Illinois Basin. The study has compiled and presented a broad base of information and knowledge needed by independent oil companies to pursue the development of exploration prospects in overlooked, deeper play horizons in the Illinois Basin. Available geologic data relevant for the exploration and development of petroleum reservoirs in the Illinois Basin was analyzed and assimilated into a coherent, easily accessible digital play portfolio. The primary focus of this project was on case studies of existing reservoirs in Devonian, Silurian, and Ordovician strata and the application of knowledge gained to future exploration and development in these underexplored strata of the Illinois Basin. In addition, a review of published reports and exploration in the New Albany Shale Group, a Devonian black shale source rock, in Illinois was completed due to the recent increased interest in Devonian black shales across the United States. The New Albany Shale is regarded as the source rock for petroleum in Silurian and younger strata in the Illinois Basin and has potential as a petroleum reservoir. Field studies of reservoirs in Devonian strata such as the Geneva Dolomite, Dutch Creek Sandstone and Grassy knob Chert suggest that there is much additional potential for expanding these plays beyond their current limits. These studies also suggest the potential for the discovery of additional plays using stratigraphic concepts to develop a subcrop play on the subkaskaskia unconformity boundary that separates lower Devonian strata from middle Devonian strata in portions of the basin. The lateral transition from Geneva Dolomite to Dutch Creek Sandstone also offers an avenue for developing exploration strategies in middle Devonian strata. Study of lower Devonian strata in the Sesser Oil Field and the region surrounding the field shows opportunities for development of a subcrop play where lower Devonian strata unconformably overlie Silurian strata. Field studies of Silurian reservoirs along the Sangamon Arch show that opportunities exist for overlooked pays in areas where wells do not penetrate deep enough to test all reservoir intervals in Niagaran rocks. Mapping of Silurian reservoirs in the Mt. Auburn trend along the Sangamon Arch shows that porous reservoir rock grades laterally to non-reservoir facies and several reservoir intervals may be encountered in the Silurian with numerous exploration wells testing only the uppermost reservoir intervals. Mapping of the Ordovician Trenton and shallower strata at Centralia Field show that the crest of the anticline shifted through geologic time. This study illustrates that the axes of anticlines may shift with depth and shallow structure maps may not accurately predict structurally favorable reservoir locations at depth.« less

Devonian-Carboniferous unconformity in Argentina and its relation to the Eo-Hercynian orogeny in southern South America

NASA Astrophysics Data System (ADS)

López-Gamundí, O. R.; Rossello, E. A.

1993-04-01

The Devonian-Carboniferous contact in southern South America, characterized by a sharp unconformity, has been related to the Late Devonian-Early Carboniferous Eo-Hercynian orogeny. The Calingasta-Uspallata basin of western Argentina and the Sauce-Grande basin (Ventana Foldbelt) of eastern Argentina have been selected to characterize this unconformity. The Eo-Hercynian movements were accompanied in western Argentina by igneous activity related to a Late Devonian—Early Carboniferous magmatic arc mainly exposed today along the Andean Cordillera. This magmatic activity is partly reflected also in eastern Argentina (Ventana Foldbelt), where isotopic dates suggest a thermal event also related to the intrusions present to the west in the North Patagonian Massif and Sierras Pampeanas. The scarcity of Lower Carboniferous deposits in the stratigraphic record of southern South America suggests that the Early Carboniferous was a time interval dominated by uplift and erosion followed by widespread subsidence during the Middle and Late Carboniferous. The origin of the Eo-Hercynian orogeny can be linked with the convergence between the Arequipa Massif, and its southern extension, and the South American continent. Its effects are best represented along the ‘Palaeo-Pacific’ margin, although distant effects are discernible in the cratonic areas of eastern South America.

Silurian and Devonian in Vietnam—Stratigraphy and facies

NASA Astrophysics Data System (ADS)

Thanh, Tống Duy; Phương, Tạ Hoàng; Janvier, Philippe; Hùng, Nguyễn Hữu; Cúc, Nguyễn Thị Thu; Dương, Nguyễn Thùy

2013-09-01

Silurian and Devonian deposits in Viet Nam are present in several zones and regions, including Quang Ninh, East Bac Bo, and West Bac Bo Zones of the Bac Bo Region, the Dien Bien-Nghe An and Binh Tri Thien Zones of the Viet-Lao Region, and the South Trung Bo, and Western Nam Bo Zones of the South Viet Nam Region (Fig. 1). The main lithological features and faunal composition of the Silurian and Devonian Units in all these zones are briefly described. The Silurian consists of deep-water deposits of the upper parts of the Co To and Tan Mai Formations in the Quang Ninh Zone, the upper parts of the Phu Ngu Formation in the East Bac Bo Zone and the upper parts of the Long Dai and Song Ca Formations in the Viet-Lao Region. Shallow water facies Silurian units containing benthic faunas are more widely distributed, including the upper part of the Sinh Vinh and Bo Hieng Formations in the West Bac Bo Zone, the Kien An Formation in the Quang Ninh Zone, and, in the Viet-Lao Region, the Dai Giang Formation and the upper part of the Tay Trang Formation. No Lower and Middle Devonian deposits indicate deep water facies, but they are characterized by different shallow water facies. Continental to near shore, deltaic facies characterize the Lower Devonian Song Cau Group in the East Bac Bo Zone, the Van Canh Formation in the Quang Ninh Zone, and the A Choc Formation in the Binh Tri Thien Zone. Similar facies also occur in the Givetian Do Son Formation of the Quang Ninh Zone, and the Tan Lap Formation in the East Bac Bo Zone, and consist of coarse terrigenous deposits—cross-bedded conglomerates, sandstone, etc. Most Devonian units are characterized by shallow marine shelf facies. Carbonate and terrigenous-carbonate facies dominate, and terrigenous facies occur in the Lower and Middle Devonian sections in some areas only. The deep-water-like facies is characteriztic for some Upper Devonian formations in the Bac Bo (Bang Ca and Toc Tat Formations) and Viet-Lao Regions (Thien Nhan and Xom Nha Formations). These formations contain cherty shale or siliceous limestone, and fossils consist of conodonts, but there are also brachiopods and other benthos. They were possibly deposited in a deep water environment on the slope of the continental shelf. Most Devonian units distributed in the North and the Central Viet Nam consist of self shallow water sediments, and apparently they were deposited in a passive marginal marine environment. The coarse clastic continental or subcontinental deposits are distributed only in some areas of the East Bac Bo and of the Quang Ninh zones of the Bac Bo Region, and in the south of the Binh Tri Thien Zone. This situation suggests the influence of the Caledonian movement at the end of the Silurian period that called the Guangxi movement in South China.

The Middle to Late Devonian Eden-Comerong-Yalwal Volcanic Zone of Southeastern Australia: An ancient analogue of the Yellowstone-Snake River Plain region of the USA

NASA Astrophysics Data System (ADS)

Dadd, K. A.

1992-11-01

The Middle to Late Devonian Yalwal Volcanics, Comerong Volcanics, Boyd Volcanic Complex and associated gabbroic and A-type granitic plutons form part of a continental volcano-tectonic belt, the Eden-Comerong-Yalwal Volcanic Zone (EVZ), located parallel to the coast of southeastern Australia. The EVZ is characterised by an elongate outcrop pattern, bimodal basalt-rhyolite volcanism, and a paucity of sedimentary rocks. Volcanic centres were located along the length of the volcanic zone at positions indicated by subvolcanic plutons, dykes, rhyolite lavas and other proximal vent indicators including surge bedforms in tuff rings, and hydrothermal alteration. Previous interpretations that suggested the volcanic zone was a fault bounded rift are rejected in favour of a volcano-tectonic belt. The Yellowstone-Snake River Plain region (Y-SRP) in the USA is an appropriate analogue. Both regions have basalt lavas which range in composition from olivine tholeiite to ferrobasalt, alkalic rhyolitic rocks enriched in Y, Zr and Th, large rhyolite lava flows, plains-type basalt lava flows, and a paucity of sedimentary rocks. The Y-SRP is inferred to have developed by migration of the American plate over a fixed hot spot leading to a northeast temporal progression of the focus of volcanic activity. Application of a similar hot spot model to the EVZ (using a length of 300 km and a time range for volcanic activity of 5-10 Ma), suggests that during the Middle to Late Devonian the Australian plate was moving at a rate of between 3 and 6 cm/yr relative to the hot spot and that the northern extent of the volcanic zone at any time was a topographically high region with rhyolitic activity, similar to present day Yellowstone. As the focus of activity moved northward, the high region subsided and the depression was flooded by basalt. The EVZ was much wider (up to 70 km) and much longer than the belt defined by present-day outcrop and was of comparable scale to the Y-SRP. The main difference between the two volcanic belts is the lack of large pyroclastic flows and identifiable caldera complexes in the EVZ.

Upper Paleozoic Marine Shale Characteristics and Exploration Prospects in the Northwestern Guizhong Depression, South China

NASA Astrophysics Data System (ADS)

Zhu, Zhenhong; Yao, Genshun; Lou, Zhanghua; Jin, Aimin; Zhu, Rong; Jin, Chong; Chen, Chao

2018-05-01

Multiple sets of organic-rich shales developed in the Upper Paleozoic of the northwestern Guizhong Depression in South China. However, the exploration of these shales is presently at a relatively immature stage. The Upper Paleozoic shales in the northwestern Guizhong Depression, including the Middle Devonian Luofu shale, the Nabiao shale, and the Lower Carboniferous Yanguan shale, were investigated in this study. Mineral composition analysis, organic matter analysis (including total organic carbon (TOC) content, maceral of kerogen and the vitrinite reflection (Ro)), pore characteristic analysis (including porosity and permeability, pore type identification by SEM, and pore size distribution by nitrogen sorption), methane isothermal sorption test were conducted, and the distribution and thickness of the shales were determined, Then the characteristics of the two target shales were illustrated and compared. The results show that the Upper Paleozoic shales have favorable organic matter conditions (mainly moderate to high TOC content, type I and II1 kerogen and high to over maturity), good fracability potential (brittleness index (BI) > 40%), multiple pore types, stable distribution and effective thickness, and good methane sorption capacity. Therefore, the Upper Paleozoic shales in the northern Guizhong Depression have good shale gas potential and exploration prospects. Moreover, the average TOC content, average BI, thickness of the organic-rich shale (TOC > 2.0 wt%) and the shale gas resources of the Middle Devonian shales are better than those of the Lower Carboniferous shale. The Middle Devonian shales have better shale gas potential and exploration prospects than the Lower Carboniferous shales.

Evaporite karst of northern lower Michigan

USGS Publications Warehouse

Black, T.J.

1997-01-01

Michigan has three main zones of evaporite karst: collapse breccia in Late Silurian deposits of the Mackinac Straits region; breccia, collapse sinks, and mega-block collapse in Middle Devonian deposits of Northern Lower Michigan, which overlaps the preceding area; and areas of soil swallows in sinks of Mississippian deposits between Turner and Alabaster in Arenac and Iosco counties, and near Grand Rapids in Kent County. The author has focused his study on evaporite karst of the Middle Devonian deposits. The Middle Devonian depos its are the Detroit River Group: a series consisting of limestone, dolomite, shale, salt, gypsum, and anhydrite. The group occurs from subcrop, near the surface, to nearly 1400 feet deep from the northern tip of the Southern Peninsula to the south edge of the "solution front" Glacial drift is from zero to 350 feet thick. Oil and gas exploration has encountered some significant lost-circulation zones throughout the area. Drilling without fluid returns, casing-seal failures, and lost holes are strong risks in some parts of the region. Lost fluid returns near the top of the group in nearby areas indicate some karst development shortly after deposition. Large and irregular lost-circulation zones, linear and patch trends of large sink holes, and 0.25 mile wide blocks of down-dropped land in the northern Lower Peninsula of Michigan were caused by surface- and ground-water movement along faults into the Detroit River Group. Glaciation has removed some evidence of the karst area at the surface. Sinkhole development, collapse valleys, and swallows developed since retreat of the glacier reveal an active solution front in the Detroit River Group.

Lithologies of the basement complex (Devonian and older) in the National Petroleum Reserve - Alaska

USGS Publications Warehouse

Dumoulin, Julie A.; Houseknecht, David W.

2001-01-01

Rocks of the basement complex (Devonian and older) were encountered in at least 30 exploratory wells in the northern part of the NPRA. Fine-grained, variably deformed sedimentary rocks deposited in a slope or basinal setting predominate and include varicolored (mainly red and green) argillite in the Simpson area, dark argillite and chert near Barrow, and widespread gray argillite. Chitinozoans of Middle-Late Ordovician and Silurian age occur in the dark argillite and chert unit. Sponge spicules and radiolarians establish a Phanerozoic age for the varicolored and gray argillite units, both of which contain local interbeds of chert-rich sandstone and silt-stone. Conglomerate and sandstone, also chert-rich but interbedded with mudstone and coal and of Early-Middle Devonian age, occur in the Topagoruk area; these strata formed in a fluvial environment. At East Teshekpuk, granite of probable Devonian age was penetrated. Brecciated, quartz-veined rock of uncertain protolith that may be part of the basement complex was encountered in the Ikpikpuk well. Seismic data indicate that angular unconformities truncate all sedimentary units of the basement complex in NPRA. Rocks correlative in age and lithofacies with the dark argillite and chert unit occur in the subsurface near Prudhoe Bay. Other argillite units in NPRA have similarities to basement rocks in the subsurface adjacent to ANWR and the Ordovician-Silurian Iviagik Group at Cape Lisburne, but lack the interbedded limestones found in the ANWR strata, and are less metamorphosed than, and compositionally distinct from, the Iviagik. The Topagoruk conglomerate and the East Teshekpuk granite resemble the Ulungarat formation and the Okpilak batholith, respectively, in the northeastern Brooks Range.

The Timan-Pechora Basin province of northwest Arctic Russia; Domanik, Paleozoic total petroleum system

USGS Publications Warehouse

Lindquist, Sandra J.

1999-01-01

The Domanik-Paleozoic oil-prone total petroleum system covers most of the Timan-Pechora Basin Province of northwestern Arctic Russia. It contains nearly 20 BBOE ultimate recoverable reserves (66% oil). West of the province is the early Precambrian Eastern European craton margin. The province itself was the site of periodic Paleozoic tectonic events, culminating with the Hercynian Uralian orogeny along its eastern border. The stratigraphic record is dominated by Paleozoic platform and shelf-edge carbonates succeeded by Upper Permian to Triassic molasse siliciclastics that are locally present in depressions. Upper Devonian (Frasnian), deep marine shale and limestone source rocks ? with typically 5 wt % total organic carbon ? by middle Mesozoic time had generated hydrocarbons that migrated into reservoirs ranging in age from Ordovician to Triassic but most focused in Devonian and Permian rocks. Carboniferous structural inversions of old aulacogen borders, and Hercynian (Permian) to Early Cimmerian (Late Triassic to Early Jurassic) orogenic compression not only impacted depositional patterns, but also created and subsequently modified numerous structural traps within the province.

Sequences, stratigraphy and scenarios: what can we say about the fossil record of the earliest tetrapods?

PubMed

Friedman, Matt; Brazeau, Martin D

2011-02-07

Past research on the emergence of digit-bearing tetrapods has led to the widely accepted premise that this important evolutionary event occurred during the Late Devonian. The discovery of convincing digit-bearing tetrapod trackways of early Middle Devonian age in Poland has upset this orthodoxy, indicating that current scenarios which link the timing of the origin of digited tetrapods to specific events in Earth history are likely to be in error. Inspired by this find, we examine the fossil record of early digit-bearing tetrapods and their closest fish-like relatives from a statistical standpoint. We find that the Polish trackways force a substantial reconsideration of the nature of the early tetrapod record when only body fossils are considered. However, the effect is less drastic (and often not statistically significant) when other reliably dated trackways that were previously considered anachronistic are taken into account. Using two approaches, we find that 95 per cent credible and confidence intervals for the origin of digit-bearing tetrapods extend into the Early Devonian and beyond, spanning late Emsian to mid Ludlow. For biologically realistic diversity models, estimated genus-level preservation rates for Devonian digited tetrapods and their relatives range from 0.025 to 0.073 per lineage-million years, an order of magnitude lower than species-level rates for groups typically considered to have dense records. Available fossils of early digited tetrapods and their immediate relatives are adequate for documenting large-scale patterns of character acquisition associated with the origin of terrestriality, but low preservation rates coupled with clear geographical and stratigraphic sampling biases caution against building scenarios for the origin of digits and terrestrialization tied to the provenance of particular specimens or faunas.

The Inskip Formation, the Harmony Formation, and the Havallah Sequence of Northwestern Nevada - An Interrelated Paleozoic Assemblage in the Home of the Sonoma Orogeny

USGS Publications Warehouse

Ketner, Keith B.

2008-01-01

An area between the towns of Winnemucca and Battle Mountain in northwestern Nevada, termed the arkosic triangle, includes the type areas of the middle to upper Paleozoic Inskip Formation and Havallah sequence, the Upper Devonian to Mississippian Harmony Formation, the Sonoma orogeny, and the Golconda thrust. According to an extensive body of scientific literature, the Havallah sequence, a diverse assemblage of oceanic rocks, was obducted onto the continent during the latest Permian or earliest Triassic Sonoma orogeny by way of the Golconda thrust. This has been the most commonly accepted theory for half a century, often cited but rarely challenged. The tectonic roles of the Inskip and Harmony Formations have remained uncertain, and they have never been fully integrated into the accepted theory. New, and newly interpreted, data are incompatible with the accepted theory and force comprehensive stratigraphic and tectonic concepts that include the Inskip and Harmony Formations as follows: middle to upper Paleozoic strata, including the Inskip, Harmony, and Havallah, form an interrelated assemblage that was deposited in a single basin on an autochthonous sequence of Cambrian, Ordovician, and lowest Silurian strata of the outer miogeocline. Sediments composing the Upper Devonian to Permian sequence entered the basin from both sides, arkosic sands, gravel, limestone olistoliths, and other detrital components entered from the west, and quartz, quartzite, chert, and other clasts from the east. Tectonic activity was expressed as: (1) Devonian uplift and erosion of part of the outer miogeocline; (2) Late Devonian depression of the same area, forming a trough, probably fault-bounded, in which the Inskip, Harmony, and Havallah were deposited; (3) production of intraformational and extrabasinal conglomerates derived from the basinal rocks; and (4) folding or tilting of the east side of the depositional basin in the Pennsylvanian. These middle to upper Paleozoic deposits were compressed in the Jurassic, causing east-verging thrusts in the eastern part of the depositional basin (Golconda thrust) and west-verging thrusts and folds in the western part. Hypotheses involving a far-traveled allochthon that was obducted from an ocean or back-arc basin are incompatible with modern observations and concepts.

Birth and demise of the Rheic Ocean magmatic arc(s): Combined U-Pb and Hf isotope analyses in detrital zircon from SW Iberia siliciclastic strata

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Gutíerrez-Alonso, G.; Murphy, J. B.; Drost, K.; Gama, C.; Silva, J. B.

2017-05-01

Paleozoic continental reconstructions indicate that subduction of Rheic oceanic lithosphere led to collision between Laurussia and Gondwana which was a major event in the formation of the Ouachita-Appalachian-Variscan orogenic belt and the amalgamation of Pangea. However, arc systems which record Rheic Ocean subduction are poorly preserved. The preservation of Devonian detrital zircon in Late Devonian-Early Carboniferous siliciclastic rocks of SW Iberia, rather than arc-related igneous rocks indicates that direct evidence of the arc system may have been largely destroyed by erosion. Here we report in-situ detrital zircon U-Pb isotopic analyses of Late Devonian-Early Carboniferous siliciclastic rocks from the Pulo do Lobo Zone, which is a reworked Late Paleozoic suture zone located between Laurussia and Gondwana. Detrital zircon age spectra from the Pulo do Lobo Zone Frasnian formations show striking similarities, revealing a wide range of ages dominated by Neoproterozoic and Paleoproterozoic grains sourced from rocks typical of peri-Gondwanan terranes, such as Avalonia, the Meguma terrane and the Ossa-Morena Zone. Pulo do Lobo rocks also include representative populations of Mesoproterozoic and Early Silurian zircons that are typical of Avalonia and the Meguma terrane which are absent in the Ossa-Morena Zone. The Famennian-Tournaisian formations from the Pulo do Lobo Zone, however, contain more abundant Middle-Late Devonian zircon indicating the contribution from a previously unrecognized source probably related to the Rheic Ocean magmatic arc(s). The Middle-Late Devonian to Early Carboniferous zircon ages from the siliciclastic rocks of SW Iberia (South Portuguese, Pulo do Lobo and Ossa-Morena zones) have a wide range in εHfT values (- 8.2 to + 8.3) indicating the likely crystallization from magmas formed in a convergent setting. The missing Rheic Ocean arc was probably built on a Meguma/Avalonia type basement. We propose for the Pulo do Lobo Zone that the Frasnian sedimentation occurred through the opening of a back-arc basin formed along the Laurussian active margin during Rheic Ocean subduction, as has been recently proposed for the Rhenohercynian Zone in Central Europe. Detrital zircon ages in the Frasnian siliciclastic rocks indicate provenance in the Meguma terrane, Avalonia and Devonian Rheic Ocean arc(s). As a result of back-arc basin inversion, the Frasnian formations underwent deformation, metamorphism and denudation and were unconformably overlain by Famennian to Visean siliciclastic strata (including the Phyllite-Quartzite Formation of the South Portuguese Zone). The Latest Devonian-Early Carboniferous detritus were probably shed to the Pulo do Lobo Zone (Represa and Santa Iria formations) by recycling of Devonian siliciclastic rocks, from the South Portuguese Zone (Meguma terrane) and from a new distinct source with Baltica/Laurentia derivation (preserved in the Horta da Torre Formation and Alajar Mélange).

The Calvin impact crater and its associated oil production, Cass County, Michigan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milstein, R.L.

1996-01-01

The Calvin impact crater is an isolated, nearly circular subsurface structure of Late Ordovician age in southwestern Michigan. The crater is defined by 110 oil and gas test wells, has a diameter of 6.2 km, and consists of a central dome exhibiting 415 m of structural uplift, an annular depression, and an encircling anticlinal rim. Exploration and development of three Devonian oil fields associated wit this structure provide all available subsurface data. All oil production is from the Middle Devonian Traverse Limestone, with the exception of one well producing from the Middle Devonian Sylvania Sandstone. This study models the grossmore » morphology of the Calvin structure using multiple tools and compares the results to known impact craters. Combined results of reflection seismic, gravity, magnetic, and resistivity data, as well as organized relationships between stratigraphic displacement and structural diameters observed in complex impact craters, suggest the Calvin structure is morphologically similar to recognized complex impact craters in sedimentary targets. In addition, individual quartz grains recovered from the Calvin structure exhibit decorated shock lamellae, Boehm lamellae, rhombohederal cleavage, and radiating concussion fractures. Based on the available data, I conclude the Calvin structure is a buried complex impact crater and that the trapping and reservoir characteristics of the associated Calvin 20, Juno Lake, and Calvin 28 oil fields are resultant of the craters morphology.« less

The Calvin impact crater and its associated oil production, Cass County, Michigan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milstein, R.L.

1996-12-31

The Calvin impact crater is an isolated, nearly circular subsurface structure of Late Ordovician age in southwestern Michigan. The crater is defined by 110 oil and gas test wells, has a diameter of 6.2 km, and consists of a central dome exhibiting 415 m of structural uplift, an annular depression, and an encircling anticlinal rim. Exploration and development of three Devonian oil fields associated wit this structure provide all available subsurface data. All oil production is from the Middle Devonian Traverse Limestone, with the exception of one well producing from the Middle Devonian Sylvania Sandstone. This study models the grossmore » morphology of the Calvin structure using multiple tools and compares the results to known impact craters. Combined results of reflection seismic, gravity, magnetic, and resistivity data, as well as organized relationships between stratigraphic displacement and structural diameters observed in complex impact craters, suggest the Calvin structure is morphologically similar to recognized complex impact craters in sedimentary targets. In addition, individual quartz grains recovered from the Calvin structure exhibit decorated shock lamellae, Boehm lamellae, rhombohederal cleavage, and radiating concussion fractures. Based on the available data, I conclude the Calvin structure is a buried complex impact crater and that the trapping and reservoir characteristics of the associated Calvin 20, Juno Lake, and Calvin 28 oil fields are resultant of the craters morphology.« less

Geochemical and strontium isotope characterization of produced waters from Marcellus Shale natural gas extraction.

PubMed

Chapman, Elizabeth C; Capo, Rosemary C; Stewart, Brian W; Kirby, Carl S; Hammack, Richard W; Schroeder, Karl T; Edenborn, Harry M

2012-03-20

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ~375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε(Sr)(SW) = +13.8 to +41.6, where ε(Sr) (SW) is the deviation of the (87)Sr/(86)Sr ratio from that of seawater in parts per 10(4)); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

Ichnology applied to sequence stratigraphic analysis of Siluro-Devonian mud-dominated shelf deposits, Paraná Basin, Brazil

NASA Astrophysics Data System (ADS)

Sedorko, Daniel; Netto, Renata G.; Savrda, Charles E.

2018-04-01

Previous studies of the Paraná Supersequence (Furnas and Ponta Grossa formations) of the Paraná Basin in southern Brazil have yielded disparate sequence stratigraphic interpretations. An integrated sedimentological, paleontological, and ichnological model was created to establish a refined sequence stratigraphic framework for this succession, focusing on the Ponta Grossa Formation. Twenty-nine ichnotaxa are recognized in the Ponta Grossa Formation, recurring assemblages of which define five trace fossil suites that represent various expressions of the Skolithos, Glossifungites and Cruziana ichnofacies. Physical sedimentologic characteristics and associated softground ichnofacies provide the basis for recognizing seven facies that reflect a passive relationship to bathymetric gradients from shallow marine (shoreface) to offshore deposition. The vertical distribution of facies provides the basis for dividing the Ponta Grossa Formation into three major (3rd-order) depositional sequences- Siluro-Devonian and Devonian I and II-each containing a record of three to seven higher-order relative sea-level cycles. Major sequence boundaries, commonly coinciding with hiatuses recognized from previously published biostratigraphic data, are locally marked by firmground Glossifungites Ichnofacies associated with submarine erosion. Maximum transgressive horizons are prominently marked by unbioturbated or weakly bioturbated black shales. By integrating observations of the Ponta Grossa Formation with those recently made on the underlying marginal- to shallow-marine Furnas Formation, the entire Paraná Supersequence can be divided into four disconformity-bound sequences: a Lower Silurian (Llandovery-Wenlock) sequence, corresponding to lower and middle units of the Furnas; a Siluro-Devonian sequence (?Pridoli-Early Emsian), and Devonian sequences I (Late Emsian-Late Eifelian) and II (Late Eifelian-Early Givetian). Stratigraphic positions of sequence boundaries generally coincide with regressive phases on established global sea-level curves for the Silurian-Devonian.

Zirconology of lherzolites in the Nurali Massif

NASA Astrophysics Data System (ADS)

Krasnobaev, A. A.; Rusin, A. I.; Anfilogov, V. N.; Valizer, P. M.; Busharina, S. V.; Medvedeva, E. V.

2017-06-01

The age trend (SHRIMP U/Pb) of the evolution of zircon is obtained for the first time in lherzolites of the Nurali Massif. Zircons are subdivided into groups by the crystallomorphological and geochemical features. These specific features in zircon development are confirmed by the age dates. Precambrian dates (no younger than 1190 Ma) correspond to mantle sources of the lherzolite block. The Early Silurian (445-448 and 439-440 Ma) wass the time of lherzolite magmatism of 10-15 Ma in duration. The Middle Devonian (382.9 ± 8.7 Ma) corresponded to postmagmatic processes related to the effect of gabbro-diorite intrusions crowning in the Nurali Massif.

Preliminary report on the clay mineralogy of the Upper Devonian Shales in the southern and middle Appalachian Basin

USGS Publications Warehouse

Hosterman, John W.; Loferski, Patricia J.

1978-01-01

The distribution of kaolinite in parts of the Devonian shale section is the most significant finding of this work. These shales are composed predominately of 2M illite and illitic mixed-layer clay with minor amounts of chlorite and kaolinite. Preliminary data indicate that kaolinite, the only allogenic clay mineral, is present in successively older beds of the Ohio Shale from south to north in the southern and middle parts of the Appalachian basin. This trend in the distribution of kaolinite shows a paleocurrent direction to the southwest. Three well-known methods of preparing the clay fraction for X-ray diffraction analysis were tested and evaluated. Kaolinite was not identified in two of the methods because of layering due to differing settling rates of the clay minerals. It is suggested that if one of the two settling methods of sample preparation is used, the clay film be thin enough for the X-ray beam to penetrate the entire thickness of clay.

187Re - 187Os nuclear geochronometry: age dating with permil precision

NASA Astrophysics Data System (ADS)

Roller, Goetz

2016-04-01

Recently, 187Re - 187Os nuclear geochronometry, a new dating method combining ideas of nuclear astrophysics with geochronology, has successfully been used to calculate two-point-isochron (TPI) ages for Devonian black gas shales using the isotopic signature of an r-process geochronometer as one data point in a TPI diagram [1]. Based upon a nuclear production ratio 187Re/188Os = 5.873, TPI ages were calculated for 12 SDO-1 (Devonian Ohio Shale, Appalachian Basin) aliquants, for which repeated Re-Os measurements are reported in the literature [2]. TPI ages range from 384.5 ± 2.7 Ma (187Os/188Osi = 0.29413 ± 0.00023) to 387.7 ± 2.1 Ma (187Os/188Osi = 0.29407 ± 0.00019) with a mean of 386.67 ± 1.79 Ma). The result is consistent with the isochronous age from the 12 aliquants alone (386 ± 16 Ma, 187Os/188Osi = 0.31±0.31), which is bracketed by U-Pb ages for the Belpre Ash (381.1 ± 3.3 Ma) and the Tioga Ash bed (390.0 ± 2.5 Ma) [3] from the Appalachian Basin. Hence, SDO-1 can be assigned to the Givetian stage (varcus-zone) of the Middle Devonian, close to the Eifelian/Givetian boundary (using the time-scale of [3] or [4]). If an age is calculated from an isochron diagram for the 12 aliquants including the nuclear geochronometer, a permil precision can be achieved, an interesting feature with respect to any effort towards calibrating the Geologic Timescale. Additionally, a Th/U evolution (or: Th/U-time) diagram can be plotted using U-Pb zircon age data and Th/U ratios from volcanic rocks and ashes reported in the literature [3] for specific Devonian samples from the Appalachian Basin. Since the Re-Os age obtained for SDO-1 can also be connected to its Th/U ratio, it turns out, that Th/U ratios might be helpful age indicators, as demonstrated for the Devonian using the U-Pb and Re-Os datasets. [1] Roller (2015), GSA Abstr. with Programs 47, #248-14. [2] Du Vivier et al. (2014), Earth Planet. Sci. Lett. 389, 23 - 33. [3] Tucker et al. (1998), Earth Planet. Sci. Lett. 158, 175 - 186. [4] Kaufmann (2006), Earth-Sci. Revs. 76, 175 - 190.

Bedrock geology of the Mount Carmel and Southington quadrangles, Connecticut

USGS Publications Warehouse

Fritts, Crawford Ellswroth

1962-01-01

New data concerning the geologic structure, stratigraphy, petrography, origin, and ages of bedrock formations in an area of approximately 111 square miles in south-central Connecticut were obtained in the course of detailed geologic mapping from 1957 to 1960. Mapping was done at a scale of 1:24,000 on topographic base maps having a 10-foot contour interval. Bedrock formations are classified in two principal categories. The first includes metasedimentary, meta-igneous, and igneous rocks of Precambrian to Devonian age, which crop out in the western parts of both quadrangles. The second includes sedimentary and igneous rocks of the Newark Group of Late Triassic age, which crop out in the eastern parts of the quadrangles. Diabase dikes, which are Late Triassic or younger in age, intruded rocks in both the western and eastern parts of the map area. Rocks in the western part of the area underwent progressive regional metamorphism in Middle to Late Devonian time. The arrangement of the chlorite, garnet, biotite, staurolite, and kyanite zones here is approximately the mirror-image of metamorphic zones in Dutchess County, New York. However, garnet appeared before biotite in politic rocks in the map area, because the ration MgO/FeO is low. Waterbury Gneiss and the intrusive Woodtick Gneiss are parts of a basement complex of Precambrian age, which forms the core of the Waterbury dome. This structure is near the southern end of a line of similar domes that lie along the crest of a geanticline east of the Green Mountain anticlinorium. The Waterbury Gneiss is believed to have been metamorphosed in Precambrian time as well as in Paleozoic time. The Woodtick Gneiss also may have been metamorphosed more than once. In Paleozoic time, sediments were deposited in geosynclines during two main cycles of sedimentation. The Straits, Southington Mountain, and Derby Hill Schists, which range in age from Cambrian to Ordovician, reflect a transition from relatively clean politic sediments to thinly layered sediments that contained rather high percentages of fine-grained volcanic debris. Metadiabase and metabasalt extrusives above Derby Hill Schist south of the map area represent more intense volcanic activity before or during the early stages of the Taconic disturbance in Late Ordovician time. Impure argillaceous, siliceous, and minor calcareous sediments of the Wepawaug Schist, which is Silurian and Devonian in age, were deposited unconformably on older rocks during renewed subsidence of a geosyncline. The Wepawaug now occupies the trough of a tight syncline, which formed before and during progressive regional metamorphism at the time of the Acadian orogeny in middle to Late Devonian time. Felsic igneous rocks were intruded into the metasedimentary formations of Paleozoic age before the climax of the latest progressive regional metamorphism. Intrusives that gave rise to the Prospect and Ansonia Gneisses were emplaced mainly in the Southington Mountain Schist, and the igneous rocks as well as the host rocks were metamorphosed in the staurolite zone. Although it is possible that these two intrusives were emplaced during the Taconic disturbance, the writer believes it more likely that the igneous rocks from which the Prospect and Ansonia Gneisses formed were emplaced during the Acadian orogeny. Woodbridge Granite, which intruded the Wepawaug Schist, is Devonian in age and undoubtedly was emplaced during the Acadian orogeny. In this area the granite is essentially unmetamorphosed, because it is in the chlorite, garnet, and biotite zones. Southwest of the map area, however, metamorphic equivalents of the Woodbridge are found in Wepawaug Schist in the staurolite zone. The Ansonia Gneiss, therefore, may be a metamorphic equivalent of the Woodbridge Granite. Rocks of Late Triassic age formerly covered the entire map area, but were eroded from the western part after tilting and faulting in Late Triassic time. The New Haven Arkose of the Newark

The problem of the age and structural position of the Blyb metamorphic complex (Fore Range zone, Great Caucasus) granitoids.

NASA Astrophysics Data System (ADS)

Kamzolkin, Vladimir; Latyshev, Anton; Ivanov, Stanislav

2016-04-01

The Blyb metamorphic complex (BMC) of the Fore Range zone is one of the most high-grade metamorphosed element of the Great Caucasus fold belt. Determination of the timing and the mechanism of formation of the Fore Range fold-thrust structures are not possible without investigation of the BMC located at the basement of its section. At the same time, the conceptions about its structure and age are outdated and need revision. Somin (2011) determined the age of the protolith and metamorphism of the Blyb complex as the Late Devonian - Early Carboniferous. We have recently shown that the BMC has not the dome, as previously thought, but nappe structure (Vidjapin, Kamzolkin, 2015), and is metamorphically coherent with the peak metamorphism pressures up to 22 kbar (Kamzolkin et al., 2015; Konilov et al., 2013). Considering the age and structure of the Blyb complex it is necessary to revise the age of granitoid intrusions and their relations with gneisses and schists, which constitute the main part of the section of the complex. Most authors (Gamkrelidze, Shengelia, 2007; Lavrischev, 2002; Baranov, 1967) adheres to Early Paleozoic age of intrusives, which is doubtful, considering the younger age of metamorphic rocks. We suppose, that the intrusive bodies broke through a BMC nappe structure during the exhumation of the complex (Perchuk, 1991) at the Devonian - Carboniferous boundary. Seemingly, the massive monzodiorites body (Lavrischev, 2002), intruding garnet-muscovite schists and amphibolite gneisses of the Blyb complex and cut by the Main Caucasian fault (MCF), are younger. Given the timing of termination of the MCF movement activity as the Middle Jurassic (Greater Caucasus..., 2005), their age should be in the Early Carboniferous - Middle Jurassic interval. At the same time, on the modern geological map (Lavrischev, 2002) monzodiorites body is assigned to the Middle Paleozoic. The study of the BMC granitoids and monzodiorites will help in determining of the mechanism and age of exhumation of the Blyb metamorphic complex high-pressure rocks. The reported study was partially supported by RFBR, research projects No. 16-35-00571mol_a; 16-05-01012a

Do fossil plants signal palaeoatmospheric carbon dioxide concentration in the geological past?

PubMed Central

McElwain, J. C.

1998-01-01

Fossil, subfossil, and herbarium leaves have been shown to provide a morphological signal of the atmospheric carbon dioxide environment in which they developed by means of their stomatal density and index. An inverse relationship between stomatal density/index and atmospheric carbon dioxide concentration has been documented for all the studies to date concerning fossil and subfossil material. Furthermore, this relationship has been demonstrated experimentally by growing plants under elevated and reducedcarbon dioxide concentrations. To date, the mechanism that controls the stomatal density response to atmospheric carbon dioxide concentration remains unknown. However, stomatal parameters of fossil plants have been successfully used as a proxy indicator of palaeo-carbon dioxide levels. This paper presents new estimates of palaeo-atmospheric carbon dioxide concentrations for the Middle Eocene (Lutetian), based on the stomatal ratios of fossil Lauraceae species from Bournemouth in England. Estimates of atmospheric carbon dioxide concentrations derived from stomatal data from plants of the Early Devonian, Late Carboniferous, Early Permian and Middle Jurassic ages are reviewed in the light of new data. Semi-quantitative palaeo-carbon dioxide estimates based on the stomatal ratio (a ratio of the stomatal index of a fossil plant to that of a selected nearest living equivalent) have in the past relied on the use of a Carboniferous standard. The application of a new standard based on the present-day carbon dioxide level is reported here for comparison. The resultant ranges of palaeo-carbon dioxide estimates made from standardized fossil stomatal ratio data are in good agreement with both carbon isotopic data from terrestrial and marine sources and long-term carbon cycle modelling estimates for all the time periods studied. These data indicate elevated atmospheric carbon dioxide concentrations during the Early Devonian, Middle Jurassic and Middle Eocene, and reduced concentrations during the Late Carboniferous and Early Permian. Such data are important in demonstrating the long-term responses of plants to changing carbon dioxide concentrations and in contributing to the database needed for general circulation model climatic analogues.

Geochronology, stratigraphy and geochemistry of Cambro-Ordovician, Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean-island magmatism

NASA Astrophysics Data System (ADS)

Höhn, Stefan; Koglin, Nikola; Klopf, Lisa; Schüssler, Ulrich; Tragelehn, Harald; Frimmel, Hartwig E.; Zeh, Armin; Brätz, Helene

2018-01-01

Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were sampled for geochemical characterisation and U-Pb zircon dating. The oldest rock suite comprises quartz keratophyre, brecciated keratophyre, quartz keratophyre tuff and basalt, formed in Upper Cambrian to Tremadocian time (c. 497-478 Ma). Basaltic volcanism continued until the Silurian. Quartz keratophyre shows post-collisional calc-alkaline signature, the Ordovician-Silurian basalt has alkaline signature typical of continental rift environments. The combined datasets provide evidence of Cambro-Ordovician bimodal volcanism and successive rifting until the Silurian. This evolution very likely resulted from break-up of the northern Gondwana margin, as recorded in many terranes throughout Europe. The position at the northern Gondwana margin is supported by detrital zircon grains in some tuffs, with typical Gondwana-derived age spectra mostly recording ages of 550-750 Ma and minor age populations of 950-1100 and 1700-2700 Ma. The absence of N-MORB basalt in the Frankenwald area points to a retarded break-off of the Saxothuringian terrane along a continental rift system from Uppermost Cambrian to Middle Silurian time. Geochemical data for a second suite of Upper Devonian basalt provide evidence of emplacement in a hot spot-related ocean-island setting south of the Rheic Ocean. Our results also require partial revision of the lithostratigraphy of the Frankenwald area. The basal volcanic unit of the Randschiefer Formation yielded a Tremadocian age and, therefore, should be attributed to the Vogtendorf Formation. Keratophyre of the Vogtendorf Formation, previously assigned to the Tremadoc, is most likely of Upper Devonian age.

Late Devonian Anoxia Events in the Central Asian Orogenic Belt: a Global Phenomenon

NASA Astrophysics Data System (ADS)

Carmichael, S. K.; Waters, J. A.; Suttner, T. J.; Kido, E.; DeReuil, A. A.; Moore, L. M.; Batchelor, C. J.

2013-12-01

Atmospheric CO2 values decreased dramatically during the Middle Devonian due to the rapid rise of land plants. These changing environmental conditions resulted in widespread anoxia and extinction events throughout the Late Devonian, including the critical Kellwasser and Hangenberg anoxia events, which are associated with major mass extinctions at both the beginning and end of the Famennian Stage of the Late Devonian. Fammenian sediments in northwestern Xinjiang Province, China, represent a highly fossiliferous shallow marine setting associated with a Devonian oceanic island arc complex. Analysis of multiple geochemical proxies (such as U/Th, Ba, normalized P2O5, V/Cr, Zr), magnetic susceptibility, and mineralogical data (biogenic apatite and pyrite framboids) indicates that these Famennian sequences record not only the Upper Kellwasser Anoxic Event at the Frasnian/Famennian (F/F) boundary but also the rebound from the F/F extinction event. Preliminary evidence suggests that the Hangenberg Anoxic Event can also be recognized in the same sequence, although our biostratigraphic control is less precise. Previous studies of the Kellwasser and Hangenberg Events have been performed on continental shelf environments of Laurussia, Gondwana, Siberia, and South China. The Devonian formations of northwest Xinjiang in this study, however, are part of the Central Asian Orogenic Belt (CAOB), which is thought to have formed as part of a complex amalgamation of intra-oceanic island arcs and continental fragments prior to the end of the latest Carboniferous. These results allow us to confirm the presence of the Kellwasser and Hangenberg Events in the open oceanic part of Paleotethys, indicating that both events were global in scope. The presence of an abundant diverse Famennian fauna between these anoxia/extinction events suggests that the shallow marine ecosystems in the CAOB were somewhat protected due to their tectonic location and relative isolation within an open ocean system. Our new data puts the Late Devonian anoxic events recognized in the CAOB into a global rather than regional context, and helps constrain the nature of ocean anoxia during this period by analysis of locations outside subequatorial North America and Europe.

Timing and pacing of the Late Devonian mass extinction event regulated by eccentricity and obliquity.

PubMed

De Vleeschouwer, David; Da Silva, Anne-Christine; Sinnesael, Matthias; Chen, Daizhao; Day, James E; Whalen, Michael T; Guo, Zenghui; Claeys, Philippe

2017-12-22

The Late Devonian envelops one of Earth's big five mass extinction events at the Frasnian-Famennian boundary (374 Ma). Environmental change across the extinction severely affected Devonian reef-builders, besides many other forms of marine life. Yet, cause-and-effect chains leading to the extinction remain poorly constrained as Late Devonian stratigraphy is poorly resolved, compared to younger cataclysmic intervals. In this study we present a global orbitally calibrated chronology across this momentous interval, applying cyclostratigraphic techniques. Our timescale stipulates that 600 kyr separate the lower and upper Kellwasser positive δ 13 C excursions. The latter excursion is paced by obliquity and is therein similar to Mesozoic intervals of environmental upheaval, like the Cretaceous Ocean-Anoxic-Event-2 (OAE-2). This obliquity signature implies coincidence with a minimum of the 2.4 Myr eccentricity cycle, during which obliquity prevails over precession, and highlights the decisive role of astronomically forced "Milankovitch" climate change in timing and pacing the Late Devonian mass extinction.

Ontogenetic and intraspecific variation in the late Emsian - Eifelian (Devonian) conodonts Polygnathus serotinus and P. bultyncki in the Prague Basin (Czech Republic) and Nevada (western U.S.)

NASA Astrophysics Data System (ADS)

Klapper, Gilbert; Vodrážková, Stanislava

2013-06-01

Klapper, G. and Vodražkova, S. 2013. Ontogenetic and intraspecific variation in the late Emsian - Eifelian (Devonian) conodonts Polygnathus serotinus and P. bultyncki in the Prague Basin (Czech Republic) and Nevada (western U.S.). Acta Geologica Polonica, 63 (2), 153-174, Warszawa. Samples from populations of Polygnathus serotinus Telford 1975 and P. bultyncki Weddige 1977 from the Prague Basin and Nevada display normal variation for Devonian conodont species. A considerable number of previous authors, however, have proposed unnecessary synonyms of these two species, primarily because they have not recognized ontogenetic variation. In contrast, we interpret the variation as ontogenetic as well as intraspecific and present detailed synonymies as a result. A third species, P. praetrigonicus Bardashev 1992, which has been carried in open nomenclature for many years, is an important indicator of the basal costatus Zone in the Prague Basin, New York, and Nevada. We review the stratigraphic distribution of these three species and the conodont zonation across the Emsian-Eifelian (Lower-Middle Devonian) boundary. Polygnathus pseudocostatus sp. nov. (partitus-costatus zones, central Nevada) is described herein. We have observed a decrease in the pit size during ontogeny in P. bultyncki although we have not measured enough specimens to rule out intraspecific versus ontogenetic variation.

Stratigraphic and structural distribution of reservoirs in Romania

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stefanescu, M.O.

1991-08-01

In Romania, there are reservoirs at different levels of the whole Cambrian-Pliocene interval, but only some of these levels have the favorable structural conditions to accumulate hydrocarbons in commercial quantities. These levels are the Devonian, Triassic, Middle Jurassic, Lower Cretaceous (locally including the uppermost Jurassic), Eocene, Oligocene-lower Miocene, middle and upper Miocene, and Pliocene. The productive reservoirs are represented either by carbonate rocks (in Devonian, Middle Triassic and uppermost Jurassic-Lower Cretaceous) or by detrital rocks (in Lower and Upper Triassic, Middle Jurassic, Eocene, Oligocene, Miocene, and Pliocene). From the structural point of view, the Romanian territory is characterized by themore » coexistence both of platforms (East European, Scythian, and Moesian platforms) and of the strongly tectonized orogenes (North Dobrogea and Carpathian orogenes). Each importance crust shortening was followed by the accumulation of post-tectonic covers, some of them being folded during subsequently tectonic movements. The youngest post-tectonic cover is common both for the platforms (foreland) and Carpathian orogene, representing the Carpathian foredeep. Producing reservoirs are present in the East European and Moesian platforms, in the outer Carpathian units (Tarcau and Marginal folds nappes) and in certain post-tectonic covers which fill the Carpathian foredeep and the Transylvanian and Pannonian basins. In the platforms, hydrocarbons accumulated both in calcareous and detrital reservoirs, whereas in the Carpathian units and in their reservoirs, whereas in the Carpathian units and in their post-tectonic covers, hydrocarbons accumulated only in detrital reservoirs.« less

Utility of palmatolepids and icriodontids in recognizing Upper Devonian Series, Stage, and possible substage boundaries

USGS Publications Warehouse

Ziegler, W.; Sandberg, C.A.

2000-01-01

Conodonts are accepted internationally to define Devonian Series and Stage boundaries. Hence, the evolution and taxonomy of pelagic palmatolepids, primarily Palmatolepis and its direct ancestor Mesotaxis, and shallow-water icriodontids, Icriodus, Pelekysgnathus, and "Icriodus", are the major tools for recognizing subdivisions of the Upper Devonian. Palmatolepids are the basis for the Late Devonian Standard Conodont Zonation (ZIEGLER & SANDBERG 1990), whereas icriodontids are the basis for the alternative, integrated shallow-water zonation (SANDBERG & DREESEN 1984). However, an alternative palmatolepid taxonomy for some Frasnian species has been employed recently by some conodont workers using the Montagne Noire (M.N.) zonation, shape analyses of Pa elements, and multielement reconstructions of KLAPPER (1989), KLAPPER & FOSTER (1993); and KLAPPER et al. (1996). Herein, the evolution of palmatolepids and icriodontids is summarized in terms of our zonation and some of the taxonomic differences with the alternative M.N. zonation are exemplified. One of the problems in relating the Standard and M.N. zonations arises from previous errors of interpretation and drafting of the Martenberg section in Germany. This section was designated the reference section for the Frasnian transitans through jamieae Zones by ZIEGLER & SANDBERG (1990). Herein, the early and middle Frasnian zonal boundaries at Martenberg are improved by re-study of our old and recent collections from three profiles, spaced only 4 m apart. Serious problems exist with the Global Stratotype Sections and Points (GSSP's), selected by the Subcommission on Devonian Stratigraphy, following the paleontologic definition of the bases of the Frasnian, Famennian, and Tournaisian Stages, because of the difficulty in making global correlations from these GSSP's. Our summary of these problems should be helpful if future workers decide to relocate these GSSP's.

Late Devonian glacial deposits from the eastern United States signal an end of the mid-Paleozoic warm period

USGS Publications Warehouse

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.; Stamm, R.

2008-01-01

A Late Devonian polymictic diamictite extends for more than 400??km from northeastern Pennsylvania across western Maryland and into east-central West Virginia. The matrix-supported, unbedded, locally sheared diamictite contains subangular to rounded clasts up to 2??m in diameter. The mostly rounded clasts are both locally derived and exotic; some exhibit striations, faceting, and polish. The diamictite commonly is overlain by laminated siltstone/mudstone facies associations (laminites). The laminites contain isolated clasts ranging in size from sand and pebbles to boulders, some of which are striated. The diamictite/laminite sequence is capped by massive, coarse-grained, pebbly sandstone that is trough cross-bedded. A stratigraphic change from red, calcic paleo-Vertisols in strata below the diamictite to non-calcic paleo-Spodosols and coal beds at and above the diamictite interval suggests that the climate became much wetter during deposition of the diamictite. The diamictite deposit is contemporaneous with regressive facies that reflect fluvial incision during the Late Devonian of the Appalachian basin. These deposits record a Late Devonian episode of climatic cooling so extreme that it produced glaciation in the Appalachian basin. Evidence for this episode of climatic cooling is preserved as the interpreted glacial deposits of diamictite, overlain by glaciolacustrine varves containing dropstones, and capped by sandstone interpreted as braided stream outwash. The Appalachian glacigenic deposits are contemporaneous with glacial deposits in South America, and suggest that Late Devonian climatic cooling was global. This period of dramatic global cooling may represent the end of the mid-Paleozoic warm interval that began in the Middle Silurian. ?? 2008 Elsevier B.V. All rights reserved.

Development of multiple unconformities during the Devonian-Carboniferous transition on parts of Laurussia

USGS Publications Warehouse

Ettensohn, F.R.; Pashin, J.C.

1997-01-01

The Devonian-Carboniferous transition on Laurussia was a time of diverse geologic activity associated with the assembly of Pangea, including episodes of Late Devonian glacial-eustatic lowstand and active orogeny on four margins. Six widespread unconformities are present in the Devonian-Carboniferous (Mississippian) interval on southern parts of Laurussia. We suggest that attention to the timing and plan of the unconformities may provide ways of discerning tectonic and climatic controls on their respective origins. Indeed, unconformities generated by pure eustasy are ideally of interregional extent, whereas unconformities generated by tectonism reflect more local factors associated with the evolution of sedimentary basins. Each of the six unconformities analyzed provides evidence for concurrent eustasy and tectonism. Glaciation was apparently the dominant factor driving the development of unconformities during the latest Devonian. During the Early Carboniferous, however, the volume of glacial ice available to drive eustasy was limited and, at times, tectonism may have been the source of a subordinate eustatic signal. Development of unconformities in southern Laurussia appear to be local manifestations of tectonic and climatic processes associated with supercontinent assembly. Thus, the time may be at hand for construction of a new global stratigraphic paradigm that is based on the plate tectonic supercycle affecting continentality and climate.

Petrogenesis of the postcollisional Middle Devonian monzonitic to granitic magmatism of the Sierra de San Luis, Argentina

NASA Astrophysics Data System (ADS)

López de Luchi, Mónica G.; Siegesmund, Siegfried; Wemmer, Klaus; Nolte, Nicole

2017-09-01

Middle Devonian granitoids intruded the Eastern Sierras Pampeanas basement ca. 600 km east of the inferred proto-Pacific margin of Gondwana along which a ca. 390 Ma collisional event developed. In the Sierra de San Luis, voluminous Middle Devonian (393-382 Ma) batholiths are composed of I- to A-type hybrid Monzonite and Granite suites. Shoshonite and subordinated high-K series, stocks, synplutonic dikes and enclaves make up the Monzonite Suite; rocks are metaluminous alkali-calcic magnesian porphyritic or equigranular monzonite, quartz monzonite, monzodiorite and scarce monzogabbro. High-K and subordinated shoshonite series metaluminous to mildly peraluminous magnesian alkali-calcic to calc-alkalic porphyritic or equigranular quartz monzonite, granodiorite, monzogranite and equigranular leucomonzogranites make up the Granite Suite plutons and batholiths. Only a small group of highly evolved granites are ferroan. SiO2 (46-62%), Cr, Ni, V, Sc, LILE, LREE, Th, Zr and variable, Sr/Y, (La/Yb)N and (Tb/Yb)N, smooth Eu/Eu*, moderate Na2O (ca 3.5), and troughs at Nb and Ta for Monzonite Suite rocks suggest an subduction-related enriched lithospheric mantle source. Sm-Nd data (TDM 0.98-1.08 Ga, εNd(380 Ma) 0.66-1.47) and 87Sr/86Sri (0.703520-0.704203) are compatible with an enriched mantle source. The metaluminous porphyritic quartz monzonite-monzogranite and the mildly peraluminous equigranular biotite monzogranites of the Granite Suite are characterized by relatively moderate Al2O3, CaO, and 87Sr/86Sri, high LILE, Cr, variable Sr/Y, (La/Yb)N and Eu/Eu* and low Rb/Sr (< 1.2) suggest a mafic source. The porphyritic monzogranite (TDM 1.20-1.28 Ga, εNd(380Ma) - 3.02 to - 3.3, 87Sr/86Sri 0.706578-0.707027) and the biotite monzogranites (TDM 1.31 Ga, εNd(380Ma) - 3.3, 87Sr/86Sri 0.707782) would share a common source. The equigranular alkali-calcic leucomonzogranites are characterized by Rb/Sr > 1.5, ASI 1.05-1.18, and Ga/Al 2.6-3.9, εNd(380 Ma) - 3.74 to - 3.95 and (87Sr/86Sr)i 0.710743-0.712955 which would point to metasedimentary or felsic igneous crustal sources. Nevertheless their TDM 1.36-1.38 Ga is considerably younger than the mean 1.8-1.6 Ga Eastern Sierras Pampeanas crustal residence age and less radiogenic. Middle Devonian magmatism would record an episode of crustal growth by enriched mantle derived magma input and variable degrees of partial melting of a lower crustal source at the waning stages of the Achalian orogeny.

The diversification of Paleozoic fire systems and fluctuations in atmospheric oxygen concentration

PubMed Central

Scott, Andrew C.; Glasspool, Ian J.

2006-01-01

By comparing Silurian through end Permian [≈250 million years (Myr)] charcoal abundance with contemporaneous macroecological changes in vegetation and climate we aim to demonstrate that long-term variations in fire occurrence and fire system diversification are related to fluctuations in Late Paleozoic atmospheric oxygen concentration. Charcoal, a proxy for fire, occurs in the fossil record from the Late Silurian (≈420 Myr) to the present. Its presence at any interval in the fossil record is already taken to constrain atmospheric oxygen within the range of 13% to 35% (the “fire window”). Herein, we observe that, as predicted, atmospheric oxygen levels rise from ≈13% in the Late Devonian to ≈30% in the Late Permian so, too, fires progressively occur in an increasing diversity of ecosystems. Sequentially, data of note include: the occurrence of charcoal in the Late Silurian/Early Devonian, indicating the burning of a diminutive, dominantly rhyniophytoid vegetation; an apparent paucity of charcoal in the Middle to Late Devonian that coincides with a predicted atmospheric oxygen low; and the subsequent diversification of fire systems throughout the remainder of the Late Paleozoic. First, fires become widespread during the Early Mississippian, they then become commonplace in mire systems in the Middle Mississippian; in the Pennsylvanian they are first recorded in upland settings and finally, based on coal petrology, become extremely important in many Permian mire settings. These trends conform well to changes in atmospheric oxygen concentration, as predicted by modeling, and indicate oxygen levels are a significant control on long-term fire occurrence. PMID:16832054

Lithostratigraphic, conodont, and other faunal links between lower Paleozoic strata in northern and central Alaska and northeastern Russia

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Anita G.; Gagiev, Mussa; Bradley, Dwight C.; Repetski, John E.

2002-01-01

Lower Paleozoic platform carbonate strata in northern Alaska (parts of the Arctic Alaska, York, and Seward terranes; herein called the North Alaska carbonate platform) and central Alaska (Farewell terrane) share distinctive lithologic and faunal features, and may have formed on a single continental fragment situated between Siberia and Laurentia. Sedimentary successions in northern and central Alaska overlie Late Proterozoic metamorphosed basement; contain Late Proterozoic ooid-rich dolostones, Middle Cambrian outer shelf deposits, and Ordovician, Silurian, and Devonian shallow-water platform facies, and include fossils of both Siberian and Laurentian biotic provinces. The presence in the Alaskan terranes of Siberian forms not seen in wellstudied cratonal margin sequences of western Laurentia implies that the Alaskan rocks were not attached to Laurentia during the early Paleozoic.The Siberian cratonal succession includes Archean basement, Ordovician shallow-water siliciclastic rocks, and Upper Silurian–Devonian evaporites, none of which have counterparts in the Alaskan successions, and contains only a few of the Laurentian conodonts that occur in Alaska. Thus we conclude that the lower Paleozoic platform successions of northern and central Alaska were not part of the Siberian craton during their deposition, but may have formed on a crustal fragment rifted away from Siberia during the Late Proterozoic. The Alaskan strata have more similarities to coeval rocks in some peri-Siberian terranes of northeastern Russia (Kotelny, Chukotka, and Omulevka). Lithologic ties between northern Alaska, the Farewell terrane, and the peri-Siberian terranes diminish after the Middle Devonian, but Siberian afµnities in northern and central Alaskan biotas persist into the late Paleozoic.

Chemostratigraphic and U-Pb geochronologic constraints on carbon cycling across the Silurian-Devonian boundary

NASA Astrophysics Data System (ADS)

Husson, Jon M.; Schoene, Blair; Bluher, Sarah; Maloof, Adam C.

2016-02-01

The Devonian Period hosts extraordinary changes to Earth's biosphere. Land plants began their rise to prominence, with early vascular vegetation beginning its colonization of near-shore environments in the latest Silurian. Across the Silurian-Devonian (Pridoli-Lochkovian) transition, carbon isotope analyses of bulk marine carbonates (δC13carb) from Laurentian and Baltic successions reveal a positive δC13carb shift. Known as the Klonk Event, values reach + 5.8 ‰, making it one of the largest carbon isotope excursions in the Phanerozoic. Assigning rates and durations to these significant events requires a robust, precise Devonian time scale. Here we present 675 micritic matrix and 357 fossil-specific δC13carb analyses from the lower Devonian Helderberg Group of New York and West Virginia that exhibit the very positive δC13carb values observed in other Silurian-Devonian basins. This chemostratigraphic dataset is coupled with 66 ID-TIMS U-Pb dates on single zircons from six ash falls intercalated within Helderberg sediments, including dates on the stratigraphically lowest Devonian ashes yet developed. In this work, we (a) demonstrate that matrix and fossil-specific δC13carb values track one another closely in the Helderberg Group, (b) estimate the Silurian-Devonian boundary age in New York to be 421.3 ± 1.2 Ma (2σ; including decay constant uncertainties), and (c) calculate the time required to evolve from baseline to peak δC13carb values at the onset of the Klonk event to be 1.00 ± 0.25 Myr. Under these constraints, a steady-state perturbation to the global carbon cycle can explain the observed excursion with modern fluxes, as long as DIC concentration in the Devonian ocean remained below ∼2× the modern value. Therefore, potential drivers, such as enhanced burial of organic carbon, need not rely on anomalously high total fluxes of carbon to explain the Klonk Event.

Late Devonian conodonts and event stratigraphy in northwestern Algerian Sahara

NASA Astrophysics Data System (ADS)

Mahboubi, Abdessamed; Gatovsky, Yury

2015-01-01

Conodonts recovered from the Late Devonian South Marhouma section comprise 5 genera with 31 species (3 undetermined). The fauna establishes the presence of MN Zones 5, undifferentiated 6/7, 8/10 for the Middle Frasnian, the MN Zones 11, 12, 13 for the Upper Frasnian as well as the Early through Late triangularis Zones in the basal Famennian. The outcropping lithological succession is one of mostly nodular calcilutites alternating with numerous marly and shaly deposits, which, in the lower and upper part, comprise several dysoxic dark shale intervals. Among these the Upper Kellwasser horizon can be precisely dated and as such the presence of the terminal Frasnian Kellwasser Event is recognized for the first time in Algeria. Both the Middlesex and Rhinestreet Events cannot yet be precisely located, but supposedly occur among the dark shale horizons in the lower part of the section. However, their assignment to a precise level has so far not been established. Though poor in conodont abundance the South Marhouma section provides first evidence of the presence of several Montagne Noire conodont zones within the so far widely unstudied Frasnian of the Ougarta Chain. As such it is considered representative for the northwestern Algerian Saoura region.

A new model for the provenance of the Upper Devonian Old Red Sandstone (UORS) of southern Ireland

NASA Astrophysics Data System (ADS)

Ennis, Meg; Meere, Pat; Timmerman, Martin

2010-05-01

The geology of Southern Ireland is dominated by the influence of both the Caledonian and Variscan orogenies which have shaped the landscape of today. The Old Red Sandstone (ORS) sequences of the Middle - Upper Devonian Munster Basin have traditionally been viewed as a post-orogenic molasse deposit sourced from the Caledonides (Friend et al. 2000 & references therein), which were subsequently deformed by the Late Carboniferous Variscan Orogeny. This model does not take into account the potential impact of the Acadian Orogeny, an Early to Mid Devonian transpressional tectonic event which culminated in Mid Emsian times and resulted in the deformation and inversion of Lower ORS (LORS) basins across Britain and Ireland (Soper & Woodcock 2003; Meere & Mulchrone 2006). Evidence of Acadian deformation in Southern Ireland is recorded in the LORS sequence of the Lower-Middle Devonian basin, the Dingle Basin. Meere & Mulchrone (2006) show that penetrative deformation visible in the LORS of the Dingle Basin has an Acadian signature and is not associated with Late Carboniferous Variscan compression (Parkin 1976; Todd 2000). The role of the Acadian Orogeny in the tectono-sedimentary evolution of Southern Ireland has been analyzed in this study using a multidisciplinary approach. Petrographic analysis of both the LORS and Upper ORS (UORS) of southern Ireland suggests an alternative provenance model in which there is a direct genetic link between the two Devonian deposits. There is a fining-up relationship between the two basins and the volcanic lithic fragments - while extremely limited in occurrence in the Munster Basin - are strikingly similar in both units. The absence of conglomeratic units at the base of the Munster Basin provide further evidence that the UORS does not represent a classic molasse deposit. This is supported by EMPA data from both basins which indicates identical mica chemistries in both the LORS and UORS. A comparison with the white mica chemistries from a variety of source areas suggests that the mica chemistry is similar to both the Irish Caledonides and also to the Scandian micas; therefore the ultimate source area of the ORS detritus remains ambiguous. This relationship is confirmed by the 40Ar/39Ar step-heating and total fusion age dating which yields Acadian apparent ages for the detrital white mica component in both basins; apparent ages for the Munster Basin micas are in the range 403 to 388 Ma. The Dingle Basin micas yield ages in the range 405 to 385 Ma. The presence of Acadian age micas in both basins and the similarity in mica chemistry suggest an alternative provenance model in which the LORS deposits of the Dingle Basin are inverted and recycled southwards into the UORS Munster Basin. References: Friend, P.F., Williams, B.P.J. and Williams, E.A. 2000. Kinematics and dynamics of Old Red Sandstone basins. In: Friend, P.F., and Williams, B.P.J. (eds.). New Perspectives on the Old Red Sandstone. Geological Society of London Special Publications, 180, 29-60. Meere, P.A. and Mulchrone, K.F. 2006. Timing of deformation within the Old Red Sandstone lithologies from the Dingle Peninsula, SW Ireland. Journal of the Geological Society of London, 163, 461-469. Parkin, J. 1976. Silurian rocks of the Bull's Head, Annascaul and Derrymore Glen inliers, Co. Kerry. Proceedings of the Royal Irish Academy 76B, 577-606. Soper, N.J., and Woodcock, N.H., 2003, The lost Lower Old Red Sandstone of England and Wales: a record of post-Iapetan flexure or Early Devonian transtension? Geological Magazine, 140, 627-647. Todd, S.P., Connery, C., Higgs, K.T. and Murphy, F.C. 2000. An Early Ordovician age for the Annascaul Formation of the SE Dingle Peninsula, SW Ireland. Journal of the Geological Society of London, 157, 823-833.

The effect of long-term regional pumping on hydrochemistry and dissolved gas content in an undeveloped shale-gas-bearing aquifer in southwestern Ontario, Canada

NASA Astrophysics Data System (ADS)

Hamilton, Stewart M.; Grasby, Stephen E.; McIntosh, Jennifer C.; Osborn, Stephen G.

2015-02-01

Baseline groundwater geochemical mapping of inorganic and isotopic parameters across 44,000 km2 of southwestern Ontario (Canada) has delineated a discreet zone of natural gas in the bedrock aquifer coincident with an 8,000-km2 exposure of Middle Devonian shale. This study describes the ambient geochemical conditions in these shales in the context of other strata, including Ordovician shales, and discusses shale-related natural and anthropogenic processes contributing to hydrogeochemical conditions in the aquifer. The three Devonian shales—the Kettle Point Formation (Antrim equivalent), Hamilton Group and Marcellus Formation—have higher DOC, DIC, HCO3, CO2(aq), pH and iodide, and much higher CH4(aq). The two Ordovician shales—the Queenston and Georgian-Bay/Blue Mountain Formations—are higher in Ca, Mg, SO4 and H2S. In the Devonian shale region, isotopic zones of Pleistocene-aged groundwater have halved in size since first identified in the 1980s; potentiometric data implicate regional groundwater extraction in the shrinkage. Isotopically younger waters invading the aquifer show rapid increases in CH4(aq), pH and iodide with depth and rapid decrease in oxidized carbon species including CO2, HCO3 and DIC, suggesting contemporary methanogenesis. Pumping in the Devonian shale contact aquifer may stimulate methanogenesis by lowering TDS, removing products and replacing reactants, including bicarbonate, derived from overlying glacial sedimentary aquifers.

Affinities and architecture of Devonian trunks of Prototaxites loganii.

PubMed

Retallack, G J; Landing, Ed

2014-01-01

Devonian fossil logs of Prototaxites loganii have been considered kelp-like aquatic algae, rolled up carpets of liverworts, enormous saprophytic fungal fruiting bodies or giant lichens. Algae and rolled liverwort models cannot explain the proportions and branching described here of a complete fossil of Prototaxites loganii from the Middle Devonian (386 Ma) Bellvale Sandstone on Schunnemunk Mountain, eastern New York. The "Schunnemunk tree" was 8.83 m long and had six branches, each about 1 m long and 9 cm diam, on the upper 1.2 m of the main axis. The coalified outermost layer of the Schunnemunk trunk and branches have isotopic compositions (δ(13)CPDB) of -25.03 ± 0.13‰ and -26.17 ± 0.69‰, respectively. The outermost part of the trunk has poorly preserved invaginations above cortical nests of coccoid cells embraced by much-branched tubular cells. This histology is unlike algae, liverworts or vascular plants and most like lichen with coccoid chlorophyte phycobionts. Prototaxites has been placed within Basidiomycota but lacks clear dikaryan features. Prototaxites and its extinct order Nematophytales may belong within Mucoromycotina or Glomeromycota. © 2014 by The Mycological Society of America.

An Exceptionally Preserved Transitional Lungfish from the Lower Permian of Nebraska, USA, and the Origin of Modern Lungfishes

PubMed Central

Pardo, Jason D.; Huttenlocker, Adam K.; Small, Bryan J.

2014-01-01

Complete, exceptionally-preserved skulls of the Permian lungfish Persephonichthys chthonica gen. et sp. nov. are described. Persephonichthys chthonica is unique among post-Devonian lungfishes in preserving portions of the neurocranium, permitting description of the braincase of a stem-ceratodontiform for the first time. The completeness of P. chthonica permits robust phylogenetic analysis of the relationships of the extant lungfish lineage within the Devonian lungfish diversification for the first time. New analyses of the relationships of this new species within two published matrices using both maximum parsimony and Bayesian inference robustly place P. chthonica and modern lungfishes within dipterid-grade dipnoans rather than within a clade containing Late Devonian ‘phaneropleurids’ and common Late Paleozoic lungfishes such as Sagenodus. Monophyly of post-Devonian lungfishes is not supported and the Carboniferous-Permian taxon Sagenodus is found to be incidental to the origins of modern lungfishes, suggesting widespread convergence in Late Paleozoic lungfishes. Morphology of the skull, hyoid arch, and pectoral girdle suggests a deviation in feeding mechanics from that of Devonian lungfishes towards the more dynamic gape cycle and more effective buccal pumping seen in modern lungfishes. Similar anatomy observed previously in ‘Rhinodipterus’ kimberyensis likely represents an intermediate state between the strict durophagy observed in most Devonian lungfishes and the more dynamic buccal pump seen in Persephonichthys and modern lungfishes, rather than adaptation to air-breathing exclusively. PMID:25265394

Sea-level changes vs. organic productivity as controls on Early and Middle Devonian bioevents: Facies- and gamma-ray based sequence-stratigraphic correlation of the Prague Basin, Czech Republic

NASA Astrophysics Data System (ADS)

Bábek, Ondřej; Faměra, Martin; Šimíček, Daniel; Weinerová, Hedvika; Hladil, Jindřich; Kalvoda, Jiří

2018-01-01

The Devonian marine stratigraphic record is characterized by a number of bioevents - overturns in pelagic and benthic faunal assemblages, which are associated with distinct changes in lithology. The coincidence of lithologic and biotic changes can be explained by the causal link between biotic evolution, carbonate production and relative sea-level changes. To gain insight into the sea-level history of Early and Middle Devonian bioevents (the Lochkovian/Pragian Event, Basal Zlíchovian E., Daleje E., and Choteč E.) we carried out a sequence-stratigraphic analysis of carbonate-dominated successions in the Prague Basin (peri-Gondwana), a classic area of Devonian bioevents. The study is based on a basin-wide correlation of facies and field gamma-ray spectrometry (GRS) logs from 18 sections (Lochkovian to Eifelian), supported by element geochemistry and published biostratigraphic and carbon isotope data. Devonian carbonate deposition in the Prague Basin alternated between two end-member modes: an oligotrophic, homoclinal ramp (Praha and Daleje-Třebotov Formations) and a mesotrophic, distally steepened ramp (Lochkov, Zlíchov, and Choteč Formations). They show contrasting facies, particularly the absence/presence of gravity-flow deposits, allochem composition, U/Th ratios, and geochemical composition (productivity proxies such as P/Al, Si/Al, Zn/Al, TOC and stable carbon isotopes). The mesotrophic systems reflect an increased availability of nutrients on the shelf during the late Lochkovian, early Emsian (Zlíchovian), and Eifelian periods when sea surface temperature, pCO2, and silicate weathering rates were higher. The oligotrophic systems deposited during the Pragian-to-earliest Emsian and late Emsian (Dalejan) periods reflect reversed palaeoclimatic trends. We identified three depositional sequences (DS), DS1 (base of Pragian to early Emsian); DS2 (early Emsian to mid Emsian); and DS3 (mid Emsian to mid Eifelian). These sequences were integrated into a peri-Gondwana relative sea-level curve, which was then compared with the Euramerican sea-level curve of Johnson et al. (1985). The bioevents coincided with several sequence stratigraphic surfaces, representing variable limbs of the relative sea-level curve. On the other hand, their conspicuous coincidence with the switching intervals between the colder oligotrophic and warmer mesotrophic modes suggests that organic production linked to global climate was the primary control on biotic overturns, while sea-level fluctuations may have only amplified its effects.

Structural evolution and petroleum productivity of the Baltic basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ulmishek, G.F.

The Baltic basin is an oval depression located in the western part of the Russian craton; it occupies the eastern Baltic Sea and adjacent onshore areas. The basin contains more than 5,000 m of sedimentary rocks ranging from latest Proterozoic to Tertiary in age. These rocks consist of four tectonostratigraphic sequences deposited during major tectonic episodes of basin evolution. Principal unconformities separate the sequences. The basin is underlain by a rift probably filled with Upper Proterozoic rocks. Vendian and Lower Cambrian rocks (Baikalian sequence) form two northeast-trending depressions. The principal stage of the basin development was during deposition of amore » thick Middle Cambrian-Lower Devonian (Caledonian) sequence. This stage was terminated by the most intense deformations in the basin history. The Middle Devonian-Carboniferous (Hercynian) and Permian-Tertiary (Kimmerian-Alpine) tectonic and depositional cycles only slightly modified the basin geometry and left intact the main structural framework of underlying rocks. The petroleum productivity of the basin is related to the Caledonian tectonostratigraphic sequence that contains both source rocks and reservoirs. However, maturation of source rocks, migration of oil, and formation of fields took place mostly during deposition of the Hercynian sequence.« less

Diagenesis and evolution of microporosity of Middle-Upper Devonian Kee Scarp reefs, Norman Wells, Northwest Territories, Canada: Petrographic and chemical evidence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Aasm, I.S.; Azmy, K.K.

The Middle-Upper Devonian Kee Scarp reef complexes of Norman Wells, Northwest Territories, Canada, are oil-producing, stromatoporoid-dominated carbonates. Episodic increases in the rate of sea level rise produced multiple cycles of reef growth that exhibit backstepping characteristics. These carbonates, composed of invariably altered limestones, have original interskeletal, intraskeletal, and intergranular porosity, mostly occluded by nonferroan, dull luminescent cements. Secondary porosity, represented by micropores of various types, developed during diagenesis by aggrading neomorphism and dissolution. The micropores represent the main reservoir porosity in the Kee Scarp limestone. Petrographic, chemical, and isotopic studies of Kee Scarp reef components reveal a complex diagenetic historymore » involving marine fluids modified by increasing water/rock interaction and burial. Neomorphic stabilization of skeletal components caused further depletion in {gamma}{sup 18}O but very little change in {gamma}{sup 13}C, an argument for modification of the original marine fluids with increasing burial. Variations in magnitude of water/rock interaction with depth, facies changes, and porosity modifications probably exerted some control on fractionation and distribution of stable isotopes and trace elements in reef components.« less

Linking the southern West Junggar terrane to the Yili Block: Insights from the oldest accretionary complexes in West Junggar, NW China

NASA Astrophysics Data System (ADS)

Ren, Rong; Han, Bao-Fu; Guan, Shu-Wei; Liu, Bo; Wang, Zeng-Zhen

2018-06-01

West Junggar is known to tectonically correlate with East Kazakhstan; however, the tectonic link of the southern West Junggar terrane to adjacent regions still remains uncertain. Here, we examined the oldest accretionary complexes, thus constraining its tectonic evolution and link during the Early-Middle Paleozoic. They have contrasting lithologic, geochemical, and geochronological features and thus, provenances and tectonic settings. The Laba Unit was derived from the Late Ordovician-Early Devonian continental arc system (peaking at 450-420 Ma) with Precambrian substrate, which formed as early as the Early Devonian and metamorphosed during the Permian; however, the Kekeshayi Unit was accumulated in an intra-oceanic arc setting, and includes the pre-Late Silurian and Late Silurian subunits with or without Precambrian sources. Integrated with the regional data, the southern West Junggar terrane revealed a tectonic link to the northern Yili Block during the Late Silurian to Early Devonian, as suggested by the comparable Precambrian zircon age spectra between the southern West Junggar terrane and the micro-continents in the southern Kazakhstan Orocline, the proximal accumulation of the Laba Unit in the continental arc atop the Yili Block, and the sudden appearance of Precambrian zircons in the Kekeshayi Unit during the Late Silurian. This link rejects the proposals of the southern West Junggar terrane as an extension of the northern Kazakhstan Orocline and the Middle Paleozoic amalgamation of West Junggar. A new linking model is thus proposed, in which the southern West Junggar terrane first evolved individually, and then collided with the Yili Block to constitute the Kazakhstan continent during the Late Silurian. The independent and contrasting intra-oceanic and continental arcs also support the Paleozoic archipelago-type evolution of the Central Asian Orogenic Belt.

Geology of Paleozoic Rocks in the Upper Colorado River Basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, Excluding the San Juan Basin

USGS Publications Warehouse

Geldon, Arthur L.

2003-01-01

The geology of the Paleozoic rocks in the Upper Colorado River Basin in Arizona, Colorado, New Mexico, Utah, and Wyoming, was studied as part of the U.S. Geological Survey's Regional Aquifer-System Analysis Program to provide support for hydrogeological interpretations. The study area is segmented by numerous uplifts and basins caused by folding and faulting that have recurred repeatedly from Precambrian to Cenozoic time. Paleozoic rocks in the study area are 0-18,000 feet thick. They are underlain by Precambrian igneous, metamorphic, and sedimentary rocks and are overlain in most of the area by Triassic formations composed mostly of shale. The overlying Mesozoic and Tertiary rocks are 0-27,000 feet thick. All Paleozoic systems except the Silurian are represented in the region. The Paleozoic rocks are divisible into 11 hydrogeologic units. The basal hydrogeologic unit consisting of Paleozoic rocks, the Flathead aquifer, predominantly is composed of Lower to Upper Cambrian sandstone and quartzite. The aquifer is 0-800 feet thick and is overlain gradationally to unconformably by formations of Cambrian to Mississippian age. The Gros Ventre confining unit consists of Middle to Upper Cambrian shale with subordinate carbonate rocks and sandstone. The confining unit is 0-1,100 feet thick and is overlain gradationally to unconformably by formations of Cambrian to Mississippian age. The Bighom aquifer consists of Middle Cambrian to Upper Ordovician limestone and dolomite with subordinate shale and sandstone. The aquifer is 0-3,000 feet thick and is overlain unconformably by Devonian and Mississipplan rocks. The Elbert-Parting confining unit consists of Lower Devonian to Lower Mississippian limestone, dolomite, sandstone, quartzite, shale, and anhydrite. It is 0-700 feet thick and is overlain conformably to unconformably by Upper Devonian and Mississippian rocks. The Madison aquifer consists of two zones of distinctly different lithology. The lower (Redwall-Leadville) zone is 0-2,500 feet thick and is composed almost entirely of Upper Devonian to Upper Mississippian limestone, dolomite, and chert. The overlying (Darwin-Humbug) zone is 0-800 feet thick and consists of Upper Mississippian limestone, dolomite, sandstone, shale, gypsum, and solution breccia. The Madison aquifer is overlain conformably by Upper Mississippian and Pennsylvanian rocks. The Madison aquifer in most areas is overlain by Upper Mississippian to Middle Pennsylvanian rocks of the Four Comers confining unit. The lower part of this confining unit, the Belden-Molas subunit, consists of as much as 4,300 feet of shale with subordinate carbonate rocks, sandstone, and minor gypsum. The upper part of the confining unit, the Paradox-Eagle Valley subunit, in most places consists of as much as 9,700 feet of interbedded limestone, dolomite, shale, sandstone, gypsum, anhydrite, and halite. Locally, the evaporitic rocks are deformed into diapirs as much as 15,000 feet thick. The Four Corners confining unit is overlain gradationally to disconformably by Pennsylvanian rocks. The uppermost Paleozoic rocks comprise the Canyonlands aquifer, which is composed of three zones with distinctly different lithologies. The basal (Cutler-Maroon) zone consists of as much as 16,500 feet of Lower Pennsylvanian to Lower Permian sandstone, conglomerate, shale, limestone, dolomite, and gypsum. The middle (Weber-De Chelly) zone consists of as much as 4,000 feet of Middle Pennsylvanian to Lower Permian quartz sandstone with minor carbonate rocks and shale. The upper (Park City-State Bridge) zone consists of as much as 800 feet of Lower to Upper Permian limestone, dolomite, shale, sandstone, phosphorite, chert, and gypsum. The Canyonlands aquifer is overlain disconformably to unconformably by formations of Triassic and Jurassic age.

Widespread effects of middle Mississippian deformation in the Great Basin of western North America

USGS Publications Warehouse

Trexler, J.H.; Cashman, P.H.; Cole, J.C.; Snyder, W.S.; Tosdal, R.M.; Davydov, V.I.

2003-01-01

Stratigraphic analyses in central and eastern Nevada reveal the importance of a deformation event in middle Mississippian time that caused widespread deformation, uplift, and erosion. It occurred between middle Osagean and late Meramecian time and resulted in deposition of both synorogenic and postorogenic sediments. The deformation resulted in east-west shortening, expressed as east-vergent folding and east-directed thrusting; it involved sedimentary rocks of the Antler foredeep as well as strata associated with the Roberts Mountains allochthon. A latest Meramecian to early Chesterian unconformity, with correlative conformable lithofacies changes, postdates this deformation and occurs throughout Nevada. A tectonic highland-created in the middle Mississippian and lasting into the Pennsylvanian and centered in the area west and southwest of Carlin, Nevada- shed sediments eastward across the Antler foreland, burying the unconformity. Postorogenic strata are late Meramecian to early Chesterian at the base and are widespread throughout the Great Basin. The tectonism therefore occurred 20 to 30 m.y. after inception of the Late Devonian Antler orogeny, significantly extending the time span of this orogeny or representing a generally unrecognized orogenic event in the Paleozoic evolution of western North America. We propose a revised stratigraphic nomenclature for Mississippian strata in Nevada, based on detailed age control and the recognition of unconformities. This approach resolves the ambiguity of some stratigraphic names and emphasizes genetic relationships within the upper Paleozoic section. We take advantage of better stratigraphic understanding to propose two new stratigraphic units for southern and eastern Nevada: the middle Mississippian Gap Wash and Late Mississippian Captain Jack Formations.

Sedimentology and stratigraphy of the Kanayut Conglomerate, central and western Brooks Range, Alaska; report of 1981 field season

USGS Publications Warehouse

Nilsen, T.H.; Moore, T.E.

1982-01-01

The Upper Devonian and Lower Mississippian(?) Kanayut Conglomerate forms a major stratigraphic unit along the crest of the Brooks Range of northern Alaska. It crops out for an east-west distance of about 900 km and a north-south distance of about 65 km. The Kanayut is wholly allochthonous and has probably been transported northward on a series of thrust plates. The Kanayut is as thick as 2,600 m in the east-central Brooks Range. It thins and fines to the south and west. The Kanayut forms the middle part of the allochthonous sequence of the Endicott Group, an Upper Devonian and Mississippian clastic sequence underlain by platform limestones of the Baird Group and overlain by platform limestone, carbonaceous shale, and black chert of the Lisburne Group. The Kanayut overlies the marine Upper Devonian Noatak Sandstone or, where it is missing, the marine Upper Devonian Hunt Fork Shale. It is overlain by the marine Mississippian Kayak Shale. The Kanayut Conglomerate forms the fluvial part of a large, coarse-grained delta that prograded to the southwest in Late Devonian time and retreated in Early Mississippian time. Four sections of the Kanayut Conglomerate in the central Brooks Range and five in the western Brooks Range were measured in 1981. The sections from the western Brooks Range document the presence of fluvial cycles in the Kanayut as far west as the shores of the Chukchi Sea. The Kanayut in this area is generally finer grained than it is in the central and eastern Brooks Range, having a maximum clast size of 3 cm. It is probably about 300 m thick. The upper and lower contacts of the Kanayut are gradational. The lower Kanayut contains calcareous, marine-influenced sandstone within channel deposits, and the upper Kanayut contains probable marine interdistributary-bay shale sequences. The members of the Kanayut Conglomerate cannot be differentiated in this region. In the central Brooks Range, sections of the Kanayut Conglomerate at Siavlat Mountain and Kakivilak Creek are typically organized into fining-upward fluvial cycles. The maximum clast size is about 3 cm in this area. The Kanayut in this region is 200-500 m thick and can be divided into the Ear Peak, Shainin Lake, and Stuver Members. The upper contact of the Kanayut with the Kayak Shale is very gradational at Kakivilak Creek and very abrupt at Siavlat Mountain. Paleocurrents from fluvial strata of the Kanayut indicate sediment transport toward the west and south in both the western and central Brooks Range. The maximum clast size distribution generally indicates westward fining from the Shainin Lake region.

Geologic map of the Nelson quadrangle, Lewis and Clark County, Montana

USGS Publications Warehouse

Reynolds, Mitchell W.; Hays, William H.

2003-01-01

The geologic map of the Nelson quadrangle, scale 1:24,000, was prepared as part of the Montana Investigations Project to provide new information on the stratigraphy, structure, and geologic history of an area in the geologically complex southern part of the Montana disturbed belt. In the Nelson area, rocks ranging in age from Middle Proterozoic through Cretaceous are exposed on three major thrust plates in which rocks have been telescoped eastward. Rocks within the thrust plates are folded and broken by thrust faults of smaller displacement than the major bounding thrust faults. Middle and Late Tertiary sedimentary and volcaniclastic rocks unconformably overlie the pre-Tertiary rocks. A major normal fault displaces rocks of the western half of the quadrangle down on the west with respect to strata of the eastern part. Alluvial and terrace gravels and local landslide deposits are present in valley bottoms and on canyon walls in the deeply dissected terrain. Different stratigraphic successions are exposed at different structural levels across the quadrangle. In the northeastern part, strata of the Middle Cambrian Flathead Sandstone, Wolsey Shale, and Meagher Limestone, the Middle and Upper Cambrian Pilgrim Formation and Park Shale undivided, the Devonian Maywood, Jefferson, and lower part of the Three Forks Formation, and Lower and Upper Mississippian rocks assigned to the upper part of the Three Forks Formation and the overlying Lodgepole and Mission Canyon Limestones are complexly folded and faulted. These deformed strata are overlain structurally in the east-central part of the quadrangle by a succession of strata including the Middle Proterozoic Greyson Formation and the Paleozoic succession from the Flathead Sandstone upward through the Lodgepole Limestone. In the east-central area, the Flathead Sandstone rests unconformably on the middle part of the Greyson Formation. The north edge, northwest quarter, and south half of the quadrangle are underlain by a succession of rocks that includes not only strata equivalent to those of the remainder of the quadrangle, but also the Middle Proterozoic Newland, Greyson, and Spokane Formations, Pennsylvanian and Upper Mississippian Amsden Formation and Big Snowy Group undivided, the Permian and Pennsylvanian Phosphoria and Quadrant Formations undivided, the Jurassic Ellis Group and Lower Cretaceous Kootenai Formation. Hornblende diorite sills and irregular bodies of probable Late Cretaceous age intrude Middle Proterozoic, Cambrian and Devonian strata. No equivalent intrusive rocks are present in structurally underlying successions of strata. In this main part of the quadrangle, the Flathead Sandstone cuts unconformably downward from south to north across the Spokane Formation into the upper middle part of the Greyson Formation. Tertiary (Miocene?) strata including sandstone, pebble and cobble conglomerate, and vitric crystal tuff underlie, but are poorly exposed, in the southeastern part of the quadrangle where they are overlain by late Tertiary and Quaternary gravel. The structural complexity of the quadrangle decreases from northeast to southwest across the quadrangle. At the lowest structural level (Avalanche Butte thrust plate) exposed in the canyon of Beaver Creek, lower and middle Paleozoic rocks are folded in northwest-trending east-inclined disharmonic anticlines and synclines that are overlain by recumbently folded and thrust faulted Devonian and Mississippian rocks. The Mississippian strata are imbricated adjacent to the recumbent folds. In the east-central part of the quadrangle, a structurally overlying thrust plate, likely equivalent to the Hogback Mountain thrust plate of the Hogback Mountain quadrangle adjacent to the east (Reynolds, 20xx), juxtaposes recumbently folded Middle Proterozoic and unconformably overlying lower Paleozoic rocks on the complexly folded and faulted rocks of the Avalanche Butte thrust plate. The highest structural plate, bounded below

Devonian salt dissolution-collapse breccias flooring the Cretaceous Athabasca oil sands deposit and development of lower McMurray Formation sinkholes, northern Alberta Basin, Western Canada

NASA Astrophysics Data System (ADS)

Broughton, Paul L.

2013-01-01

The sub-Cretaceous paleotopography underlying giant Lower Cretaceous Athabasca oil sands, northern Alberta, has an orthogonal lattice pattern of troughs up to 50 km long and 100 m deep between pairs of cross-cutting lineaments. These structures are interpreted to have been inherited from a similar pattern of dissolution collapse-subsidence troughs in the underlying Middle Devonian salt beds. Removal of more than 100 m of halite salt fragmented the overlying Upper Devonian strata into fault blocks and collapse breccias that subsided into the underlying dissolution troughs. The unusually low 1:2 to 1:3 thickness ratios of halite salts to the overlying strata resulted in the Upper Devonian strata collapse-subsidence into underlying salt dissolution troughs being more cataclysmic during the first phase of salt removal. The second phase of slower but complete salt removal between the earlier troughs resulted in a more gradual subsidence of the overlying strata. This obliterated the earlier pattern of giant cross-cutting dissolution troughs bounded by major lineaments. The collapse breccia fabrics underlying the earlier troughs differ from those from areas between the troughs. Collapse breccias underlying the large troughs often have crushed fabrics distributed in zones that rapidly pinched out between fault blocks. Breccias between troughs developed as giant mosaics of detached carbonate blocks that formed breccia pipe complexes. Multiple sinkholes up to 100 m deep aligned along multi-km linear valley trends that dissected the sub-Cretaceous paleotopography. These sinkhole trends formed orthogonal patterns inherited from underlying lattice of NW-SE and NE-SW salt structured lineaments. These cross-cutting sinkhole trends have a smaller 5 km scale reticulate pattern similar to the giant 50 km scale pattern of collapse-subsidence troughs. Other sinkholes developed as lower McMurray strata sagged when underlying Devonian fault blocks and breccia pipes differentially subsided.

Paleozoic Hydrocarbon-Seep Limestones

NASA Astrophysics Data System (ADS)

Peckmann, J.

2007-12-01

To date, five Paleozoic hydrocarbon-seep limestones have been recognized based on carbonate fabrics, associated fauna, and stable carbon isotopes. These are the Middle Devonian Hollard Mound from the Antiatlas of Morocco [1], Late Devonian limestone lenses with the dimerelloid brachiopod Dzieduszyckia from the Western Meseta of Morocco [2], Middle Mississippian limestones with the dimerelloid brachiopod Ibergirhynchia from the Harz Mountains of Germany [3], Early Pennsylvanian limestones from the Tantes Mound in the High Pyrenees of France [4], and Late Pennsylvanian limestone lenses from the Ganigobis Shale Member of southern Namibia [5]. Among these examples, the composition of seepage fluids varied substantially as inferred from delta C-13 values of early diagenetic carbonate phases. Delta C-13 values as low as -50 per mil from the Tantes Mound and -51 per mil from the Ganigobis limestones reveal seepage of biogenic methane, whereas values of -12 per mil from limestones with Dzieduszyckia associated with abundant pyrobitumen agree with oil seepage. Intermediate delta C-13 values of carbonate cements from the Hollard Mound and Ibergirhynchia deposits probably reflect seepage of thermogenic methane. It is presently very difficult to assess the faunal evolution at seeps in the Paleozoic based on the limited number of examples. Two of the known seeps were typified by extremely abundant rhynchonellide brachiopods of the superfamily Dimerelloidea. Bivalve mollusks and tubeworms were abundant at two of the known Paleozoic seep sites; one was dominated by bivalve mollusks (Hollard Mound, Middle Devonian), another was dominated by tubeworms (Ganigobis Shale Member, Late Pennsylvanian). The tubeworms from these two deposits are interpreted to represent vestimentiferan worms, based on studies of the taphonomy of modern vestimentiferans. However, this interpretation is in conflict with the estimated evolutionary age of vestimentiferans based on molecular clock methods, which suggest a maximal age of 126 million years for this group. 1. Peckmann et al. (1999) Facies 40, 281. 2. Peckmann et al. (2007) Palaios 22, 114. 3. Peckmann et al. (2001) Geology 29, 271. 4. Buggisch and Krumm (2005) Facies 51, 566. 5. Himmler et al. (submitted) Palaeogeogr., Palaeoclimatol., Palaeoecol.

Oxygenation history of the Neoproterozoic to early Phanerozoic and the rise of land plants

NASA Astrophysics Data System (ADS)

Wallace, Malcolm W.; Hood, Ashleigh vS.; Shuster, Alice; Greig, Alan; Planavsky, Noah J.; Reed, Christopher P.

2017-05-01

There has been extensive debate about the history of Earth's oxygenation and the role that land plant evolution played in shaping Earth's ocean-atmosphere system. Here we use the rare earth element patterns in marine carbonates to monitor the structure of the marine redox landscape through the rise and diversification of animals and early land plants. In particular, we use the relative abundance of cerium (Ceanom), the only redox-sensitive rare earth element, in well-preserved marine cements and other marine precipitates to track seawater oxygen levels. Our results indicate that there was only a moderate increase in oceanic oxygenation during the Ediacaran (average Cryogenian Ceanom = 1.1, average Ediacaran Ceanom = 0.62), followed by a decrease in oxygen levels during the early Cambrian (average Cryogenian Ceanom = 0.90), with significant ocean anoxia persisting through the early and mid Paleozoic (average Early Cambrian-Early Devonian Ceanom = 0.84). It was not until the Late Devonian that oxygenation levels are comparable to the modern (average of all post-middle Devonian Ceanom = 0.55). Therefore, this work confirms growing evidence that the oxygenation of the Earth was neither unidirectional nor a simple two-stage process. Further, we provide evidence that it was not until the Late Devonian, when large land plants and forests first evolved, that oxygen levels reached those comparable to the modern world. This is recorded with the first modern-like negative Ceanom (values <0.6) occurring at around 380 Ma (Frasnian). This suggests that land plants, rather than animals, are the 'engineers' responsible for the modern fully oxygenated Earth system.

Petroleum geology and resources of the Dnieper-Donets Basin, Ukraine and Russia

USGS Publications Warehouse

Ulmishek, Gregory F.

2001-01-01

The Dnieper-Donets basin is almost entirely in Ukraine, and it is the principal producer of hydrocarbons in that country. A small southeastern part of the basin is in Russia. The basin is bounded by the Voronezh high of the Russian craton to the northeast and by the Ukrainian shield to the southwest. The basin is principally a Late Devonian rift that is overlain by a Carboniferous to Early Permian postrift sag. The Devonian rift structure extends northwestward into the Pripyat basin of Belarus; the two basins are separated by the Bragin-Loev uplift, which is a Devonian volcanic center. Southeastward, the Dnieper-Donets basin has a gradational boundary with the Donbas foldbelt, which is a structurally inverted and deformed part of the basin. The sedimentary succession of the basin consists of four tectono-stratigraphic sequences. The prerift platform sequence includes Middle Devonian to lower Frasnian, mainly clastic, rocks that were deposited in an extensive intracratonic basin. 1 The Upper Devonian synrift sequence probably is as thick as 4?5 kilometers. It is composed of marine carbonate, clastic, and volcanic rocks and two salt formations, of Frasnian and Famennian age, that are deformed into salt domes and plugs. The postrift sag sequence consists of Carboniferous and Lower Permian clastic marine and alluvial deltaic rocks that are as thick as 11 kilometers in the southeastern part of the basin. The Lower Permian interval includes a salt formation that is an important regional seal for oil and gas fields. The basin was affected by strong compression in Artinskian (Early Permian) time, when southeastern basin areas were uplifted and deeply eroded and the Donbas foldbelt was formed. The postrift platform sequence includes Triassic through Tertiary rocks that were deposited in a shallow platform depression that extended far beyond the Dnieper-Donets basin boundaries. A single total petroleum system encompassing the entire sedimentary succession is identified in the Dnieper-Donets basin. Discovered reserves of the system are 1.6 billion barrels of oil and 59 trillion cubic feet of gas. More than one-half of the reserves are in Lower Permian rocks below the salt seal. Most of remaining reserves are in upper Visean-Serpukhovian (Lower Carboniferous) strata. The majority of discovered fields are in salt-cored anticlines or in drapes over Devonian horst blocks; little exploration has been conducted for stratigraphic traps. Synrift Upper Devonian carbonate reservoirs are almost unexplored. Two identified source-rock intervals are the black anoxic shales and carbonates in the lower Visean and Devonian sections. However, additional source rocks possibly are present in the deep central area of the basin. The role of Carboniferous coals as a source rock for gas is uncertain; no coal-related gas has been identified by the limited geochemical studies. The source rocks are in the gas-generation window over most of the basin area; consequently gas dominates over oil in the reserves. Three assessment units were identified in the Dnieper-Donets Paleozoic total petroleum system. The assessment unit that contains all discovered reserves embraces postrift Carboniferous and younger rocks. This unit also contains the largest portion of undiscovered resources, especially gas. Stratigraphic and combination structural and stratigraphic traps probably will be the prime targets for future exploration. The second assessment unit includes poorly known synrift Devonian rocks. Carbonate reef reservoirs along the basin margins probably will contain most of the undiscovered resources. The third assessment unit is an unconventional, continuous, basin-centered gas accumulation in Carboniferous low-permeability clastic rocks. The entire extent of this accumulation is unknown, but it occupies much of the basin area. Resources of this assessment unit were not estimated quantitatively.

Devonian paleomagnetism of the North Tien Shan: Implications for the middle-Late Paleozoic paleogeography of Eurasia

NASA Astrophysics Data System (ADS)

Levashova, Natalia M.; Mikolaichuk, Alexander V.; McCausland, Philip J. A.; Bazhenov, Mikhail L.; Van der Voo, Rob

2007-05-01

The Ural-Mongol belt (UMB), between Siberia, Baltica and Tarim, is widely recognized as the locus of Asia's main growth during the Paleozoic, but its evolution remains highly controversial, as illustrated by the disparate paleogeographic models published in the last decade. One of the largest tectonic units of the UMB is the Kokchetav-North Tien Shan Domain (KNTD) that stretches from Tarim in the south nearly to the West Siberian Basin. The KNTD comprises several Precambrian microcontinents and numerous remnants of Early Paleozoic island arcs, marginal basins and accretionary complexes. In Late Ordovician time, all these structures had amalgamated into a single contiguous domain. Its paleogeographic position is of crucial importance for elucidating the Paleozoic evolution of the UMB in general and of the Urals in particular. The Aral Formation, located in Kyrgyzstan in the southern part of the KNTD, consists of a thick Upper Devonian (Frasnian) basalt-andesite sequence. Paleomagnetic data show a dual-polarity characteristic component (Dec/Inc = 286° / + 56°, α95 = 9°, k = 21, N = 15 sites). The primary origin of this magnetization is confirmed by a positive test on intraformational conglomerates. We combine this result with other Paleozoic data from the KNTD and show its latitudinal motion from the Late Ordovician to the end of the Paleozoic. The observed paleolatitudes are found to agree well with the values extrapolated from Baltica to a common reference point (42.5°N, 73°E) in our sampling area for the entire interval; hence coherent motion of the KNTD and Baltica is strongly indicated for most of the Paleozoic. This finding contradicts most published models of the UMB evolution, where the KNTD is separated from Baltica by a rather wide Ural Ocean containing one or more major plate boundaries. An exception is the model of Şengör and Natal'in [A.M.C. Şengör, B.A. Natal'in, Paleotectonics of Asia: fragments of a synthesis, in: A. Yin and M. Harrison (eds.), The tectonic evolution of Asia, Cambridge University Press, Cambridge (1996) 486-640], in which coherent paleolatitudinal motion of Baltica and the KNTD is hypothesized — the latter as part of the Kipchak Arc. We suggest a parallel hypothesis, which explains coherent motion of the KNTD and Baltica. In particular, we argue that if a basin with oceanic crust ever existed between the KNTD and Baltica, it was a narrow one without (significant) active spreading in Middle to Late Paleozoic time. Notably, the paleogeographic position of Siberia during the Middle Paleozoic and hence, the width of the Khanty-Mansi Ocean between Siberia, on the one hand, and Baltica-KNTD, on the other hand, remains largely unconstrained, because of the paucity of high-quality Silurian, Devonian and Carboniferous paleomagnetic results from Siberia.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCollum, L.B.; Buchanan, J.P.; McCollum, M.B.

The Antler orogeny is a textbook example of a Paleozoic mountain building and crustal shortening event in western North America. A relatively complex geologic history of the type Antler at Battle Mountain, Nevada, is interpreted as distinct thrust plates of Lower Cambrian Scott Canyon Formation, Upper Cambrian Harmony Sandstone, and Ordovician Valmy Formation, overlain unconformably by the Middle Pennsylvanian Battle Formation. Mississippian crustal deformation and emplacement of the Roberts Mountain thrust have previously been thought to characterize the Antler orogen. Detailed sedimentology studies of the Scott Canyon and Harmony, and the relationship with the overlying Battle Formation at the typemore » section of the Antler orogeny, cast doubt on the previously accepted geologic history. The Scott Canyon is an interbedded sequence of pillow basalts, Late Devonian radiolarian cherts, and mudstone debris flows with numerous limestone olistoliths, many containing undescribed archaeocyathid fauna. The contact of the Harmony with the Battle Formation appears channeled, but otherwise conformable, and the Battle has been interpreted as an alluvial fan facies. The paleoenvironmental interpretation of these sediments is that the Scott Canyon was deposited upon a Late Devonian active continental margin setting, with prograding fan deposits of the Harmony Sandstone, overlain by Middle Pennsylvanian fanglomerates of the Battle Formation. This conformable sequence appears to preclude any major uplift within the type Antler orogen.« less

Late Ordovician (post-Sardic) rifting branches in the North Gondwanan Montagne Noire and Mouthoumet massifs of southern France

NASA Astrophysics Data System (ADS)

Javier Álvaro, J.; Colmenar, Jorge; Monceret, Eric; Pouclet, André; Vizcaïno, Daniel

2016-06-01

Upper Ordovician-Lower Devonian rocks of the Cabrières klippes (southern Montagne Noire) and the Mouthoumet massif in southern France rest paraconformably or with angular discordance on Cambrian-Lower Ordovician strata. Neither Middle-Ordovician volcanism nor associated metamorphism is recorded, and the subsequent Middle-Ordovician stratigraphic gap is related to the Sardic phase. Upper Ordovician sedimentation started in the rifting branches of Cabrières and Mouthoumet with deposition of basaltic lava flows and lahar deposits (Roque de Bandies and Villerouge formations) of continental tholeiite signature (CT), indicative of continental fracturing. The infill of both rifting branches followed with the onset of (1) Katian (Ka1-Ka2) conglomerates and sandstones (Glauzy and Gascagne formations), which have yielded a new brachiopod assemblage representative of the Svobodaina havliceki Community; (2) Katian (Ka2-Ka4) limestones, marlstones, and shales with carbonate nodules, reflecting development of bryozoan-echinoderm meadows with elements of the Nicolella Community (Gabian and Montjoi formations); and (3) the Hirnantian Marmairane Formation in the Mouthoumet massif that has yielded a rich and diverse fossil association representative of the pandemic Hirnantia Fauna. The sealing of the subaerial palaeorelief generated during the Sardic phase is related to Silurian and Early Devonian transgressions leading to onlapping patterns and the record of high-angle discordances.

Trace elements and REE geochemistry of Middle Devonian carbonate mounds (Maïder Basin, Eastern Anti-Atlas, Morocco): Implications for early diagenetic processes

NASA Astrophysics Data System (ADS)

Franchi, Fulvio; Turetta, Clara; Cavalazzi, Barbara; Corami, Fabiana; Barbieri, Roberto

2016-08-01

Trace and rare earth elements (REEs) have proven their utility as tools for assessing the genesis and early diagenesis of widespread geological bodies such as carbonate mounds, whose genetic processes are not yet fully understood. Carbonates from the Middle Devonian conical mud mounds of the Maïder Basin (eastern Anti-Atlas, Morocco) have been analysed for their REE and trace element distribution. Collectively, the carbonates from the Maïder Basin mud mounds appear to display coherent REE patterns. Three different geochemical patterns, possibly related with three different diagenetic events, include: i) dyke fills with a normal marine REE pattern probably precipitated in equilibrium with seawater, ii) mound micrite with a particular enrichment of overall REE contents and variable Ce anomaly probably related to variation of pH, increase of alkalinity or dissolution/remineralization of organic matter during early diagenesis, and iii) haematite-rich vein fills precipitated from venting fluids of probable hydrothermal origin. Our results reinforce the hypothesis that these mounds were probably affected by an early diagenesis induced by microbial activity and triggered by abundance of dispersed organic matter, whilst venting may have affected the mounds during a later diagenetic phase.

Troglomorphism in the middle Triassic crinoids from Poland.

PubMed

Brom, Krzysztof R; Brachaniec, Tomasz; Salamon, Mariusz A

2015-10-01

In this paper, we document the Middle Triassic marine fauna recovered from the fissure/cave system of Stare Gliny (southern Poland) developed in the Devonian host dolomite. The fossils are mostly represented by in situ preserved and small-sized holdfasts of crinoids (Crinoidea) that are attached to the cave walls. Other fossils found in the cave infills include articulated brittle stars and brachiopods. Our findings constitute the oldest Mesozoic evidence for troglophile crinoids. We suggest that troglomorphism in these echinoderms was likely related to protection against predation, which underscores the magnitude of anti-predatory adaptations to increased predation pressure that occurred during the Early Mesozoic Marine Revolution.

A synthesis of mineralization styles and geodynamic settings of the Paleozoic and Mesozoic metallic ore deposits in the Altay Mountains, NW China

NASA Astrophysics Data System (ADS)

Yang, Fuquan; Geng, Xinxia; Wang, Rui; Zhang, Zhixin; Guo, Xuji

2018-06-01

The Altay Mountains within the Xinjiang region of northwestern China hosts major metallic ore deposits. Here we review the geological characteristics, metallogenic features and tectonic settings of these deposits. The metallic ore deposits in the Altay Mountains occur mainly within four regions: North Altay, Central Altay, South Altay and Erqis. We recognize seven types of metallic ore deposits in the Altay Mountains: VMS, submarine volcanogenic iron, magmatic, skarn, pegmatite, hydrothermal vein (Cu-Zn, Fe) and orogenic gold. Among these types, the VMS, pegmatite, orogenic gold and skarn deposits are the most common. Most of the rare metal pegmatite deposits are distributed in Central Altay, with only a few in South Altay. The VMS, submarine volcanogenic type iron and skarn-type deposits are distributed in South Altay, whereas the orogenic-type gold deposits are distributed in the Erqis Fault belt. The hydrothermal vein-type deposits occur in the Erqis Fault belt and Chonghu'er Basin in South Altay. Magmatic-type deposits are mostly in the Erqis Fault belt and Central Altay. Based on isotopic age data, the VMS, submarine volcanogenic-type Fe and skarn-type Cu, Pb, Zn, Fe mineralization occurred during Early-Middle Devonian (∼410-377 Ma), orogenic-type Au, magmatic-type Cu-Ni, and a small number of skarn-type Fe, hydrothermal vein-type Cu-Zn, pegmatite-type rare-metal deposits in Early-Middle Permian (293-261 Ma), pegmatite-type rare-metal deposits, few skarn-type Fe deposit in Early-Middle Triassic (248-232 Ma), and dominantly represented by pegmatite-type rare-metal deposits in Late Triassic-Early Jurassic (223-180 Ma). The metallic ore deposits in the Altay Mountains formed in various tectonic settings, such as the Early-Middle Devonian continental arc and oceanic island arc, Early-Middle Permian post-collisional extensional setting, and Triassic-Early Jurassic intracontinental setting.

Regional stratigraphy and petroleum potential, Ghadames basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Emme, J.J.; Sunderland, B.L.

1991-03-01

The Ghadames basin in east-central Algeria extends over 65,000 km{sup 2} (25,000 mi{sup 2}), of which 90% is covered by dunes of the eastern Erg. This intracratonic basin consists of up to 6000 m (20,000 ft) of dominantly clastic Paleozoic through Mesozoic strata. The Ghadames basin is part of a larger, composite basin complex (Ilizzi-Ghadames-Triassic basins) where Paleozoic strata have been truncated during a Hercynian erosional event and subsequently overlain by a northward-thickening wedge of Mesozoic sediments. Major reservoir rocks include Triassic sandstones that produce oil, gas, and condensate in the western Ghadames basin, Siluro-Devonian sandstones that produce mostly oilmore » in the shallower Ilizzi basin to the south, and Cambro-Ordovician orthoquartzites that produce oil at Hassi Messaoud to the northwest. Organic shales of the Silurian and Middle-Upper Devonian are considered primary source rocks. Paleozoic shales and Triassic evaporite/red bed sequences act as seals for hydrocarbon accumulations. The central Ghadames basin is underexplored, with less than one wildcat well/1700 km{sup 2} (one well/420,000 ac). Recent Devonian and Triassic oil discoveries below 3500 m (11,500 ft) indicate that deep oil potential exists. Exploration to date has concentrated on structural traps. Subcrop and facies trends indicate that potential for giant stratigraphic or combination traps exists for both Siluro-Devonian and Triassic intervals. Modern seismic acquisition and processing techniques in high dune areas can be used to successfully identify critical unconformity-bound sequences with significant stratigraphic trap potential. Advances in seismic and drilling technology combined with creative exploration should result in major petroleum discoveries in the Ghadames basin.« less

Tectonic setting of synorogenic gold deposits of the Pacific Rim

USGS Publications Warehouse

Goldfarb, R.J.; Phillips, G.N.; Nokleberg, W.J.

1998-01-01

More than 420 million oz of gold were concentrated in circum-Pacific synorogenic quartz loades mainly during two periods of continental growth, one along the Gondwanan margin in the Palaeozoic and the other in the northern Pacific basin between 170 and 50 Ma. These ores have many features in common and can be grouped into a single type of lode gold deposit widespread throughout clastic sedimentary-rock dominant terranes. The auriferous veins contain only a few percent sulphide minerals, have gold:silver ratios typically greater than 1:1, show a distinct association with medium grade metamorphic rocks, and may be associated with large-scale fault zone. Ore fluids are consistently of low salinity and are CO2-rich. In the early and middle Palaeozoic in the southern Pacific basin, a single immense turbidite sequence was added to the eastern margin of Gondwanaland. Deformation of these rocks in southeastern Australia was accompanied by deposition of at least 80 million oz of gold in the Victorian sector of the Lachlan fold belt mainly during the Middle and Late Devonian. Lesser Devonian gold accumulations characterized the more northerly parts of the Gondwanan margin within the Hodgkinson-Broken River and Thomson fold belts. Additional lodes were emplaced in this flyschoid sequence in Devonian or earlier Palaeozoic times in what is now the Buller Terrane, Westland, New Zealand. Minor post-Devonian growth of Gondwanaland included terrane collision and formation of gold-bearing veins in the Permian in Australia's New England fold belt and in the Jurassic-Early Cretaceous in New Zealand's Otago schists. Collision and accretion of dozens of terranes for a 100-m.y.-long period against the western margin of North America and eastern margin of Eurasia led to widespread, lattest Jurassic to Eocene gold veining in the northern Pacific basin. In the former location, Late Jurassic and Early Cretaceous veins and related placer deposits along the western margin of the Sierra Nevada batholith have yielded more than 100 million oz of gold. Additional significant ore-forming events during the development of North America's Cordilleran orogen included those in the Klamath Mountains region, California in the Late Jurassic and Early Cretaceous; the Klondike district, Yukon by the Early Cretaceous; the Nome and Fairbanks districts, Alaska, and the Bridge River district, British Columbia in the middle Cretaceous; and the Juneau gold belt, Alaska in the Eocene. Gold-bearing veins deposited during the Late Jurassic and Early Cretaceous terrane collision that formed the present-day Russian Far East have been the source for more than 130 million oz of placer gold. The abundance of gold-bearing quartz-carbonate veins throughout the Gondwanan, North American and Eurasian continental margins suggests the migration and concentration of large fluid volumes during continental growth. Such volumes could be released during orogenic heating of hydrous silicate mineral phases within accreted marine strata. The common temporal association between gold veining and magmatism around the Pacific Rim reflects these thermal episodes. Melting of the lower thickened crust during arc formation, slab rollback and extensional tectonism, and subduction of a slab window beneath the seaward part of the forearc region can all provide the required heat for initation of the ore-forming processes.

Skarn-mineralized porphyry adakites in the Harlik arc at Kalatage, E. Tianshan (NW China): Slab melting in the Devonian-early Carboniferous in the southern Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Mao, Qigui; Yu, Mingjie; Xiao, Wenjiao; Windley, Brian F.; Li, Yuechen; Wei, Xiaofeng; Zhu, Jiangjian; Lü, Xiaoqiang

2018-03-01

The geodynamic control of mineralization in the accretionary evolution of the Central Asian Orogenic Belt (CAOB) has long been controversial. Here we report new field, geochemical and geochronological data on recently defined porphyry and skarn-type ore deposits (Devonian-Early Carboniferous) in the Kalatage area in the middle of the Harlik-Dananhu arc, Eastern Tianshan, NW China in the southern CAOB, with the aim of better understanding the accretionary tectonics and genesis of porphyry and skarn-type mineralization. The Yudai porphyry Cu-(Au) deposits and the Xierqu skarn Cu-Fe-(Au) deposits are closely associated with Middle Devonian adakitic diorite porphyries (382-390 Ma), which are calc-alkaline and characterized by high Na2O/K2O ratios and Sr contents (310-1020 ppm), strong depletion of HREE (e.g., Yb = 0.80-1.44 ppm) and Y (7.68-14.50 ppm), and all enriched in Rb, Sr, Ba, K and depleted in Nb and Ti. They are characterized by distinctive Eu positive anomalies, high Na2O contents and MORB-like Sr and Nd isotope signatures (high εNd(t) = +6.1 to +7.0 and low (87Sr/86Sr)i = 0.70412-0.70462). These adakites most likely formed by melting of a young/hot subducted oceanic slab, and adakites in general are important carriers of porphyry Cu ± (Au) deposits. Early Carboniferous adakites in the Tuwu area south of Kalatage are known to have similar features. Therefore, skarn-mineralized porphyry adakites get younger from north to south, suggesting southward migration of the Harlik-Dananhu arc from 390 Ma to 322 Ma. These data indicate that partial melting of hot (and/or young) oceanic crustal slabs were an important mechanism of accretionary crustal growth and mineralization in the southern CAOB.

From success to persistence: Identifying an evolutionary regime shift in the diverse Paleozoic aquatic arthropod group Eurypterida, driven by the Devonian biotic crisis.

PubMed

Lamsdell, James C; Selden, Paul A

2017-01-01

Mass extinctions have altered the trajectory of evolution a number of times over the Phanerozoic. During these periods of biotic upheaval a different selective regime appears to operate, although it is still unclear whether consistent survivorship rules apply across different extinction events. We compare variations in diversity and disparity across the evolutionary history of a major Paleozoic arthropod group, the Eurypterida. Using these data, we explore the group's transition from a successful, dynamic clade to a stagnant persistent lineage, pinpointing the Devonian as the period during which this evolutionary regime shift occurred. The late Devonian biotic crisis is potentially unique among the "Big Five" mass extinctions in exhibiting a drop in speciation rates rather than an increase in extinction. Our study reveals eurypterids show depressed speciation rates throughout the Devonian but no abnormal peaks in extinction. Loss of morphospace occupation is random across all Paleozoic extinction events; however, differential origination during the Devonian results in a migration and subsequent stagnation of occupied morphospace. This shift appears linked to an ecological transition from euryhaline taxa to freshwater species with low morphological diversity alongside a decrease in endemism. These results demonstrate the importance of the Devonian biotic crisis in reshaping Paleozoic ecosystems. © 2016 The Author(s). Evolution © 2016 The Society for the Study of Evolution.

Odontomariinae, a new middle paleozoic subfamily of slit-bearing euophaloidean gastropods (Euophalomorpha, Gastropoda)

USGS Publications Warehouse

Fryda, J.; Heidelberger, D.; Blodgett, R.B.

2006-01-01

A new subfamily, the Odontomariinae subfam. nov., is established herein for a distinctive group of uncoiled, slit-bearing Middle Devonian euomphalid gastropods. Its taxonomic position is based on the recent discovery of open coiled protoconchs and it is placed within the Euomphalomorpha. The genera Odontomaria Odontomaria C. F. Roemer and Tubiconcha n. gen. belonging to this new subfamily are enlarged based on studies on new material of the following species: Odontomaria semiplicata (Sandberger & Sandberger), Odontomaria gracilis n. sp., Odontomaria jankei n. sp., Odontomaria cheeneetnukensis n. sp., Odontomaria cindiprellerae n. sp. and Tubiconcha leunissi (Heidelberger, 2001). Members of the Odontomariinae were mainly sedentary organisms in high-energy, moderately shallow water. ?? 2006 E. Schweizerbart'sche Verlagsbuchhandlung.

A new reconstruction of the Paleozoic continental margin of southwestern North America: Implications for the nature and timing of continental truncation and the possible role of the Mojave-Sonora megashear

USGS Publications Warehouse

Stevens, C.H.; Stone, P.; Miller, J.S.

2005-01-01

Data bearing on interpretations of the Paleozoic and Mesozoic paleogeography of southwestern North America are important for testing the hypothesis that the Paleozoic miogeocline in this region has been tectonically truncated, and if so, for ascertaining the time of the event and the possible role of the Mojave-Sonora megashear. Here, we present an analysis of existing and new data permitting reconstruction of the Paleozoic continental margin of southwestern North America. Significant new and recent information incorporated into this reconstruction includes (1) spatial distribution of Middle to Upper Devonian continental-margin facies belts, (2) positions of other paleogeographically significant sedimentary boundaries on the Paleozoic continental shelf, (3) distribution of Upper Permian through Upper Triassic plutonic rocks, and (4) evidence that the southern Sierra Nevada and western Mojave Desert are underlain by continental crust. After restoring the geology of western Nevada and California along known and inferred strike-slip faults, we find that the Devonian facies belts and pre-Pennsylvanian sedimentary boundaries define an arcuate, generally south-trending continental margin that appears to be truncated on the southwest. A Pennsylvanian basin, a Permian coral belt, and a belt of Upper Permian to Upper Triassic plutons stretching from Sonora, Mexico, into westernmost central Nevada, cut across the older facies belts, suggesting that truncation of the continental margin occurred in the Pennsylvanian. We postulate that the main truncating structure was a left-lateral transform fault zone that extended from the Mojave-Sonora megashear in northwestern Mexico to the Foothills Suture in California. The Caborca block of northwestern Mexico, where Devonian facies belts and pre-Pennsylvanian sedimentary boundaries like those in California have been identified, is interpreted to represent a missing fragment of the continental margin that underwent ???400 km of left-lateral displacement along this fault zone. If this model is correct, the Mojave-Sonora megashear played a direct role in the Pennsylvanian truncation of the continental margin, and any younger displacement on this fault has been relatively small. ?? 2005 Geological Society of America.

Devonian magmatism in the Timan Range, Arctic Russia - subduction, post-orogenic extension, or rifting?

NASA Astrophysics Data System (ADS)

Pease, V.; Scarrow, J. H.; Silva, I. G. Nobre; Cambeses, A.

2016-11-01

Devonian mafic magmatism of the northern East European Craton (EEC) has been variously linked to Uralian subduction, post-orogenic extension associated with Caledonian collision, and rifting. New elemental and isotopic analyses of Devonian basalts from the Timan Range and Kanin Peninsula, Russia, in the northern EEC constrain magma genesis, mantle source(s) and the tectonic process(es) associated with this Devonian volcanism to a rift-related context. Two compositional groups of low-K2O tholeiitic basalts are recognized. On the basis of Th concentrations, LREE concentrations, and (LREE/HREE)N, the data suggest two distinct magma batches. Incompatible trace elements ratios (e.g., Th/Yb, Nb/Th, Nb/La) together with Nd and Pb isotopes indicate involvement of an NMORB to EMORB 'transitional' mantle component mixed with variable amounts of a continental component. The magmas were derived from a source that developed high (U,Th)/Pb, U/Th and Sm/Nd over time. The geochemistry of Timan-Kanin basalts supports the hypothesis that the genesis of Devonian basaltic magmatism in the region resulted from local melting of transitional mantle and lower crust during rifting of a mainly non-volcanic continental rifted margin.

Assessment of Appalachian basin oil and gas resources:Devonian shale - Middle and Upper Paleozoic Total Petroleum System

USGS Publications Warehouse

Milici, Robert C.; Swezey, Christopher S.

2006-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the technically recoverable undiscovered hydrocarbon resources of the Appalachian Basin Province. The assessment province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia and Alabama. The assessment was based on six major petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) extends generally from New York to Tennessee. This petroleum system has produced a large proportion of the oil and natural gas that has been discovered in the Appalachian basin since the drilling of the Drake well in Pennsylvania in 1859. For assessment purposes, the TPS was divided into 10 assessment units (plays), 4 of which were classified as conventional and 6 as continuous. The results were reported as fully risked fractiles (F95, F50, F5 and the Mean), with the fractiles indicating the probability of recovery of the assessment amount. Products reported were oil (millions of barrels of oil, MMBO), gas (billions of cubic feet of gas, BCFG), and natural gas liquids (millions of barrels of natural gas liquids, MMBNGL). The mean estimates for technically recoverable undiscovered hydrocarbons in the TPS are: 7.53 MMBO, 31,418.88 BCFG (31.42 trillion cubic feet) of gas, and 562.07 MMBNGL.

Seven 365-Million-Year-Old Trilobites Moulting within a Nautiloid Conch

NASA Astrophysics Data System (ADS)

Zong, Rui-Wen; Fan, Ruo-Ying; Gong, Yi-Ming

2016-10-01

A nautiloid conch containing many disarticulated exoskeletons of Omegops cornelius (Phacopidae, Trilobita) was found in the Upper Devonian Hongguleleng Formation of the northwestern margin of the Junggar Basin, NW China. The similar number of cephala, thoraces and pygidia, unbroken thoraces, explicit exuviae, and lack of other macrofossils in the conch, indicate that at least seven individual trilobites had moulted within the nautiloid living chamber, using the vacant chamber of a dead nautiloid as a communal place for ecdysis. This exuvial strategy manifests cryptic behaviour of trilobites, which may have resulted from the adaptive evolution induced by powerful predation pressure, unstable marine environments, and competition pressure of organisms occupying the same ecological niche in the Devonian period. The unusual presence of several trilobites moulting within a nautiloid conch is possibly associated with social behaviours in face of a serious crisis. New materials in this study open a window for understanding the survival strategy of marine benthic organisms, especially predator-prey interactions and the behavioural ecology of trilobites in the middle Palaeozoic.

From carbonate platform to euxinic sea - the collapse of an Early/Middle Devonian reef, Cantabrian Mountains (Spain)

NASA Astrophysics Data System (ADS)

Loevezijn, Gerard B. S. van; Raven, J. G. M.

2017-12-01

The Santa Lucía Formation represents the major phase in Devonian reef development of the Cantabrian Zone (Cantabrian Mountains, northwest Spain). In the present study the transition from the carbonate platform deposits of the Santa Lucía Formation to the overlying euxinic basinal deposits of the Huergas Formation is described. These transitional strata are connected to the Basal Choteč Event and represent a condensed sedimentation of micritic dark-grey and black limestones with an upward increase of dark shale intercalations with iron mineralisation surfaces and storm-induced brachiopod coquinas. The transitional beds are grouped into a new unit, the Cabornera Bed, which consists of limestone, limestone-shale and shale facies associations, representing a sediment-starved euxinic offshore area just below the storm wave base. Four stages in reef decline can be recognised: a reef stage, an oxygen-depleted, nutrient-rich stage, a siliciclastic-influx stage and a pelagic-siliciclastic stage. Additional geochemical and geophysical investigations are needed to verify the results presented herein.

Onondage pinnacle reefs in New York State

DOE Office of Scientific and Technical Information (OSTI.GOV)

Friedman, G.M.

1995-09-01

Onondaga pinnacle reefs, part of the Onondaga Formation, developed in an epeiric setting of the lowermost Middle Devonian (Eifelian). The reefs were initiated as coral-crinoidal mounds in the Edgecliff Member of the formation. Whereas most Devonian reefs are composed of rugose corals. Coral is the predominant kind of fossil, followed by crinoids, brachiopods, mollusks, undifferentiated skeletal debris, and possible sponges. The initial mineralogy of the corals is inferred to have been calcite. The porosity of these reefs is almost unique among reef reservoirs. most reefs produce from secondary or diagenetic porosity; by contrast Onondaga reefs display primary intracoralline or frameworkmore » porosity. Between framework builders and/or skeletal particles cryptocrystalline/microcrystalline cement fills pores. As observed in modern reefs this kind of cement resembles micrite, but probable formed as high-magnesian calcite in a high-energy setting. Syntaxial or rim cement common lines crinoid particles. Some of these pinnacle reefs, formerly gas producers, are presently under development as gas-storage reservoirs.« less

Reevaluation of the Piermont-Frontenac allochthon in the Upper Connecticut Valley: Restoration of a coherent Boundary Mountains–Bronson Hill stratigraphic sequence

USGS Publications Warehouse

Rankin, Douglas W.; Tucker, Robert D.; Amelin, Yuri

2013-01-01

The regional extent and mode and time of emplacement of the Piermont-Frontenac allochthon in the Boundary Mountains–Bronson Hill anticlinorium of the Upper Connecticut Valley, New Hampshire–Vermont, are controversial. Moench and coworkers beginning in the 1980s proposed that much of the autochthonous pre–Middle Ordovician section of the anticlinorium was a large allochthon of Silurian to Early Devonian rocks correlated to those near Rangeley, Maine. This ∼200-km-long allochthon was postulated to have been transported westward in the latest Silurian to Early Devonian as a soft-sediment gravity slide on a hypothesized Foster Hill fault. New mapping and U-Pb geochronology do not support this interpretation. The undisputed Rangeley sequence in the Bean Brook slice is different from the disputed sequence in the proposed larger Piermont-Frontenac allochthon, and field evidence for the Foster Hill fault is lacking. At the type locality on Foster Hill, the postulated “fault” is a stratigraphic contact within the Ordovician Ammonoosuc Volcanics. The proposed Foster Hill fault would place the Piermont-Frontenac allochthon over the inverted limb of the Cornish(?) nappe, which includes the Emsian Littleton Formation, thus limiting the alleged submarine slide to post-Emsian time. Mafic dikes of the 419 Ma Comerford Intrusive Complex intrude previously folded strata attributed to the larger Piermont-Frontenac allochthon as well as the autochthonous Albee Formation and Ammonoosuc Volcanics. The Lost Nation pluton intruded and produced hornfels in previously deformed Albee strata. Zircons from an apophysis of the pluton in the hornfels have a thermal ionization mass spectrometry 207Pb/206Pb age of 444.1 ± 2.1 Ma. Tonalite near Bath, New Hampshire, has a zircon sensitive high-resolution ion microprobe 206Pb/238U age of 492.5 ± 7.8 Ma. The tonalite intrudes the Albee Formation, formerly interpreted as the Silurian Perry Mountain Formation of the proposed allochthon. Collectively, these features indicate that the large Piermont-Frontenac allochthon gravity slide of Silurian-Devonian strata, as previously proposed, cannot exist. Allochthonous rocks are restricted to a 25 km2 klippe, the Bean Brook slice, emplaced by hard-rock thrusting in the post-Emsian Devonian. The Albee Formation, the oldest unit in the study area, is older than the Late Cambrian tonalite at Bath. The correlation and apparent continuity along strike to the northeast of the Albee Formation with the Dead River Formation suggest that the Albee Formation, like the Dead River Formation, is of Ganderian affinity and that the Bronson Hill magmatic arc in the Upper Connecticut Valley was built on Ganderian crust. The Dead River Formation is unconformably overlain by Middle and Upper Ordovician volcanic units; the unconformity is attributed to the pre-Arenig Penobscottian orogeny. Some of the pre-Silurian deformation in the Upper Connecticut Valley may be Penobscottian rather than Taconian. New stratigraphic units defined herein include the pelitic Scarritt Member of the Albee Formation, the Ordovician Washburn Brook Formation consisting of synsedimentary breccia and coticule, chert, and ironstone, and the Devonian–Silurian Sawyer Mountain Formation, probably correlative with the Frontenac Formation. The Partridge Formation is partially coeval with the Ammonoosuc Volcanics.

Evaluation of shale gas potential based on organic matter characteristics and gas concentration in the Devonian Horn River Formation, Canada

NASA Astrophysics Data System (ADS)

Choi, Jiyoung; Hong, Sung Kyung; Lee, Hyun Suk

2017-04-01

In this study, we investigate organic matter characteristics from the analysis of Rock-Eval6 and biomarker, and estimate methane concentration from headspace method in the Devonian Horn River Formation, which is one of the largest shale reservoir in western Canada. The Horn River Formation consists of the Evie, Otterpark and Muskwa members in ascending stratigraphic order. Total Organic Carbon (TOC) ranges from 0.34 to 7.57 wt%, with an average of 2.78 wt%. The Evie, middle Otterpark and Muskwa members have an average TOC of more than 3%, whereas those of the lower and upper Otterpark Member are less than 2%. Based on Pristane/n-C17 (0.2 0.6) and Phytane/n-C18 (0.3 0.9) ratios, the organic matter in the Evie, middle Otterpark and Muskwa members mainly consists of type II kerogen which are formed in reducing marine environment. Thermal maturity were examined through the use of the distributions of Phenanthrene (P) and Methylphenantrenes (MP) based on m/z 178 and 192 mass chromatograms, respectively (Radke et al., 1982). The methylphenanthrene index (MPI-1) are calculated as follows : MPI-1 = 1.5 × (2MP+3MP)/(P+1MP+9MP), and Ro are calculated as follows : Ro = -0.6 × MPI-1 + 2.3. Estimated Ro ranges between 1.88 and 1.93%, which indicates the last stage of wet gas generation. The methane concentrations in headspace range from 15 to 914 ppmv, with an average of 73.5 ppmv. The methane concentrations in the Evie, middle Otterpark and Muskwa members (up to 914 ppmv) are higher than those of the lower and upper Otterpark Member (up to 75 ppmv). Considering the organic geochemical characteristics and gas concentrations, the shale gas potentials of the Evie, middle Otterpark and Muskwa members are higher than those of other members.

Middle Devonian to Early Carboniferous event stratigraphy of Devils Gate and Northern Antelope Range sections, Nevada, U.S.A

USGS Publications Warehouse

Sandberg, C.A.; Morrow, J.R.; Poole, F.G.; Ziegler, W.

2003-01-01

The classic type section of the Devils Gate Limestone at Devils Gate Pass is situated on the eastern slope of a proto-Antler forebulge that resulted from convergence of the west side of the North American continent with an ocean plate. The original Late Devonian forebulge, the site of which is now located between Devils Gate Pass and the Northern Antelope Range, separated the continental-rise to deep-slope Woodruff basin on the west from the backbulge Pilot basin on the east. Two connections between these basins are recorded by deeper water siltstone beds at Devils Gate; the older one is the lower tongue of the Woodruff Formation, which forms the basal unit of the upper member of the type Devils Gate, and the upper one is the overlying, thin lower member of the Pilot Shale. The forebulge and the backbulge Pilot basin originated during the middle Frasnian (early Late Devonian) Early hassi Zone, shortly following the Alamo Impact within the punctata Zone in southern Nevada. Evidence of this impact is recorded by coeval and reworked shocked quartz grains in the Northern Antelope Range and possibly by a unique bypass-channel or megatsunami-uprush sandy diamictite within carbonate-platform rocks of the lower member of the type Devils Gate Limestone. Besides the Alamo Impact and three regional events, two other important global events are recorded in the Devils Gate section. The semichatovae eustatic rise, the maximum Late Devonian flooding event, coincides with the sharp lithogenetic change at the discordant boundary above the lower member of the Devils Gate Limestone. Most significantly, the Devils Gate section contains the thickest and most complete rock record in North America across the late Frasnian linguiformis Zone mass extinction event. Excellent exposures include not only the extinction shale, but also a younger. Early triangularis Zone tsunamite breccia, produced by global collapse of carbonate platforms during a shallowing event that continued into the next younger Famennian Stage. The Northern Antelope Range section is located near the top of the west side of the proto-Antler forebulge. Because of its unusual, tectonically active location, unmatched at any other Nevada localities, this section records only four regional and global events during a timespan slightly longer than that of the Devils Gate section. The global semichatovae rise and late Frasnian mass extinction event are largely masked because of the depositional complexities resulting from this location.

Early Paleozoic magmatic events in the eastern Klamath Mountains, northern California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wallin, E.T.; Mattinson, J.M.; Potter, A.W.

1988-02-01

New U-Pb zircon ages for nine samples of tonalite and pegmatitic trondhjemite from the Trinity ophiolite and associated melange reveal a complex history of magmatic activity extending back into the earliest Cambrian, much older than previously believed. Earlier investigations, based on limited data, recognized lower Paleozoic crustal elements in the eastern Klamath terrane (EKT) ranging in age from Middle Ordovician to Early to Middle Devonian. The new work in the Yreka-Callahan area of the EKT confirms the Ordovician (440-475 Ma) and younger ages, but reveals for the first time the presence of tonalitic rocks that crystallized during a narrow timemore » interval at about 565-570 Ma. The authors also recognize younger, Late Silurian magmatism at 412 Ma. In the context of available mapping, these ages indicate that the Trinity ophiolite is broadly polygenetic because parts of it yield crystallization ages that span approximately 150 m.y. Superjacent dismembered units of probable early Paleozoic age may be tectonostratigraphically equivalent to the Sierra City melange in the northern Sierra Nevada.« less

Metamorphism and plutonism around the middle and south forks of the Feather River, California

USGS Publications Warehouse

Hietanen, Anna Martta

1976-01-01

The area around the Middle and South Forks of the Feather River provides information on metamorphic and igneous processes that bear on the origin of andesitic and granitic magmas in general and on the variation of their potassium content in particular. In the north, the area joins the Pulga and Bucks Lake quadrangles studied previously. Tectonically, this area is situated in the southern part of an arcuate segment of the Nevadan orogenic belt in the northwestern Sierra Nevada. The oldest rocks are metamorphosed calcalkaline island-arc-type andesite, dacite, and sodarhyolite with interbedded tuff layers (the Franklin Canyon Formation), all probably correlative with Devonian rocks in the Klamath Mountains. Younger rocks form a sequence of volcanic, volcaniclastic, and sedimentary rocks including some limestone (The Horseshoe Bend Formation), probably Permian in age. All the volcanic and sedimentary rocks were folded and recrystallized to the greenschist facies during the Nevadan (Jurassic) orogeny and were invaded by monzotonalitic magmas shortly thereafter. A second lineation and metamorphism to the epidote-amphibolite facies developed in a narrow zone around the plutons. In light of the concept of plate tectonics, it is suggested that the early (Devonian?) island-arc-type andesite, dacite, and sodarhyolite (the Franklin Canyon Formation) were derived from the mantle above a Benioff zone by partial melting of peridotite in hydrous conditions. The water was probably derived from an oceanic plate descending to the mantle. Later (Permian?) magmas were mainly basaltic; some discontinuous layers of potassium-rich rhyolite indicate a change into anhydrous conditions and a deeper level of magma generation. The plutonic magmas that invaded the metamorphic rocks at the end of the Jurassic may contain material from the mantle, the subducted oceanic lithosphere, and the downfolded metamorphic rocks. The ratio of partial melts from these three sources may have changed with time, giving rise to the diversity in composition of magmas.

Paleozoic carbonate buildup (reef) inventory, central and southeastern Idaho

DOE Office of Scientific and Technical Information (OSTI.GOV)

Isaacson, P.E.

1987-08-01

Knowledge of central and southeastern Idaho's Paleozoic rocks to date suggest that three styles of buildup (reef) complexes occur in Late Devonian, Mississippian, and Pennsylvanian-Permian time. The Late Devonian Jefferson Formation has stromatoporoid and coral (both rugosan and tabulate) organisms effecting a buildup in the Grandview Canyon vicinity; Early Mississippian Waulsortian-type mud mounds occur in the Lodgepole formation of southeastern Idaho; there are Late Mississippian Waulsortian-type mounds in the Surrett Canyon Formation of the Lost River Range; and cyclic Pennsylvanian-Permian algal and hydrozoan buildups occur in the Juniper gulch Member of the Snaky Canyon Formation in the Arco Hills andmore » Lemhi Range. Late Devonian (Frasnian) carbonates of the Jefferson formation show buildup development on deep ramp sediments.« less

U-Pb (zircon) and geochemical constraints on the age, origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu-Au district, southern Mongolia

USGS Publications Warehouse

Wainwright, A.J.; Tosdal, R.M.; Wooden, J.L.; Mazdab, F.K.; Friedman, R.M.

2011-01-01

Uranium-Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu-Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt, the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions (??Nd(t) range from +3.1 to +7.5 and 206Pb/204Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have <1.5% TiO2) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu-Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism. Uranium-Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu-Au deposits are ~372Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu-Au mineralization are ~366Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu-Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu-Au deposits from younger magmatic suites in the district. ?? 2010 Elsevier B.V.

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...

Devonian Terrestrial Revolution: the palaeoenvironment of the oldest known tetrapod tracks, Zachełmie Quarry, Poland

NASA Astrophysics Data System (ADS)

Niedźwiedzki, G.

2012-04-01

Numerous trackways and isolated prints with digit impressions, which are similar to the foot anatomy of early tetrapods such as Ichthyostega, were found on the three dolomite bed-surfaces in the lower part of the Wojciechowice Formation exposed in the Zachełmie Quarry in the Holy Cross Mountains (south-central Poland), (Niedźwiedzki et al., 2010). The age of the tetrapod track-bearing strata is well-constrained, but the detailed sedimentology of the lower section with tetrapod ichnites is still under study. The Wojciechowice Formation represent one of the first carbonate stages of a transgressive succession that begins with Early Devonian continental to marginal marine clastics and culminates in the development of a Givetian coral-stromatoporoid carbonate platform. The tetrapod track-bearing complex is composed of grey to reddish, thin- to medium-bedded dolomitic shales and marly dolomite mudstones. These deposits from the tetrapod track-bearing horizon lack definitive marine body fossils, and may have formed in a marginal marine environment, e.g. around a coastal lagoon. Mudcracks, columnar peds, root traces, and microbially induced sedimentary structures were found in three distinct pedotypes of very weakly to weakly developed paleosols (Retallack, 2011). Conodonts of the costatus zone (mid-Eifelian) were found 20 m above the uppermost surface with tetrapod tracks in limestones of the upper Wojciechowice Formation, which contain also brachiopod and crinoidal debris. The overlying Kowala Formation is a marine coral limestone and dolostone. The parts of profile with tetrapod ichnites and invertebrate and conodont fossils contain also records of invertebrate traces. Seven ichnotaxa are distributed among four recognized ichnoassemblages. The recognized ichnocoenoses are typical for the shallow-marine (Cruziana ichnofacies) and land-water transitional (Skolithos/Psilonichnus ichnofacies) carbonate depositional environments. The ichnocoenoses are dominated by trace fossils produced by arthropods (probably crustaceans), a group that can create large and distinctive burrows. The palaeoecological information from the Zachełmie section has direct bearing on the interpretation of environmental aspects of tetrapod emergence and terrestrialization. It should be fully integrated with data from other Devonian tetrapod tracksites. Niedźwiedzki, G., Szrek P., Narkiewicz K., Narkiewicz M. and Ahlberg P.E. 2010. Tetrapod trackways from the early Middle Devonian period of Poland. Nature, 463: 43-48. Retallack, G.J. 2011. Woodland Hypothesis for Devonian Tetrapod Evolution. The Journal of Geology, 119, 3: 235-258

Rotational and accretionary evolution of the Klamath Mountains, California and Oregon, from Devonian to present time

USGS Publications Warehouse

Irwin, William P.; Mankinen, Edward A.

1998-01-01

The purpose of this report is to show graphically how the Klamath Mountains grew from a relatively small nucleus in Early Devonian time to its present size while rotating clockwise approximately 110°. This growth occurred by the addition of large tectonic slices of oceanic lithosphere, volcanic arcs, and melange during a sequence of accretionary episodes. The Klamath Mountains province consists of eight lithotectonoic units called terranes, some of which are divided into subterranes. The Eastern Klamath terrane, which was the early Paleozoic nucleus of the province, is divided into the Yreka, Trinity, and Redding subterranes. Through tectonic plate motion, usually involving subduction, the other terranes joined the early Paleozoic nucleus during seven accretionary episodes ranging in age from Early Devonian to Late Jurassic. The active terrane suture is shown for each episode by a bold black line. Much of the western boundary of the Klamath Mountains is marked by the South Fork and correlative faults along which the Klamath terranes overrode the Coast Range rocks during an eighth accretionary episode, forming the South Fork Mountain Schist in Early Cretaceous time.

Middle Pennsylvanian recurrent uplift of the Ouachita fold belt and basin subsidence in the Arkoma basin, Oklahoma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmore, R.D.; Sutherland, P.K.; White, P.B.

1990-09-01

Recurrent uplift of the Ouachita fold belt in Oklahoma coincided with the disruption of the Arkoma basin following the deposition of the Boggy Formation (early Desmoinesian time). The Boggy, composed of sandstone-shale sequences that record southerly progradation of coal-bearing, fluvially dominated deltaic complexes into the Arkoma basin, was folded at the time of uplift of the Ouachita fold belt. The uplift ended the progressive subsidence of the Arkoma basin and shifted the depocenter to the northwest. Subsequently, the Thurman Formation (middle Desmoinesian), which had a source in the southeast, was deposited in the smaller resurgent foreland basin over the foldedmore » and eroded surface of the Boggy. Chert-pebble conglomerates in the Thurman were derived from the erosion of newly elevated Ordovician and Devonian cherts in the core of the Ouachita foldbelt. Sandstone-shale packages are found in both formations. The origin of the coal-bearing cycles in the Boggy are enigmatic, but they probably were controlled by a combination of factors such as glacio-eustatic changes in sea level and delta-lobe abandonment. In contrast, cycles in the Thurman probably were strongly influenced by episodic thrust faulting and uplift in the Ouachitas.« less

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2013 CFR

2013-04-01

... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2012 CFR

2012-04-01

... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2014 CFR

2014-04-01

... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...

500 Myr of thermal history elucidated by multi-method detrital thermochronology of North Gondwana Cambrian sandstone (Eilat area, Israel)

NASA Astrophysics Data System (ADS)

Vermeesch, P.; Avigad, D.

2009-04-01

Following the Neoproterozoic Pan-African orogeny, the Arabian-Nubian Shield (ANS) of North Africa and Arabia was eroded and then covered by Cambrian sandstones that record the onset of platform sedimentation. We applied K-feldspar 40Ar/39Ar, zircon and apatite fission track and apatite (U-Th)/He thermochronology to detritus from Cambrian sandstones of southern Israel deposited at about 500 Ma. U-Pb detrital zircon ages from these sandstones predate deposition and record the earlier Neoproterozoic crustal evolution of the Pan-African orogens. 40Ar/39Ar ages from 50 single grains of K-feldspar yield a Cambrian mean of approximately 535 Ma. The 40Ar/39Ar age spectrum of a multi-grain K-feldspar aliquot displays diffusion behaviour compatible with >560 Ma cooling later affected by a heating event. Assuming that the high temperature domains of the K-feldspars have not been affected by subsequent (hydro)thermal events, and taking previously published K-Ar and Rb-Sr ages from other parts of the East African Orogen at face value, these ages apparently record Pan-African thermal resetting below a thick volcano-sedimentary pile similar to the Saramuj conglomerate in Jordan and/or the Hammamat in Egypt. Detrital zircon fission track (ZFT) ages cluster around 380 Ma, consistent with previous ZFT results from Neoproterozoic basement and sediments of the region, revealing that the Cambrian platform sequence experienced a middle Devonian thermal event and low-grade metamorphism. Regional correlation indicates that during Devonian time the sedimentary cover atop the Cambrian in Israel was never in excess of 2.5 km, requiring an abnormally steep geothermal gradient to explain the complete ZFT annealing. A basal Carboniferous unconformity can be traced from Syria to southern Saudi Arabia, suggesting that the observed Devonian ZFT ages represent a regional tectonothermal event. Similar Devonian ZFT ages were reported from ANS basement outcrops in the Eastern Desert, 500 km south of Eilat. The detrital apatites we studied all have extremely rounded cores suggestive of a distant provenance, but some grains also feature distinct euhedral U-rich apatite overgrowth rims. Authigenic apatite may have grown during the late Devonian thermal event we dated by ZFT, coinciding with existing Rb-Sr ages from authigenic clays in the same deposits and leading to the conclusion that the Devonian event was probably hydrothermal. Like the ZFT ages, the detrital apatite fission track (AFT) ages were also completely reset after deposition. Sixty single grain detrital apatite fission track (AFT) ages group at ~270 Ma with significant dispersion. Inverse modeling of the AFT data indicate extended and/or repeated residence in the AFT partial annealing zone, in turn suggesting an episodic burial-erosion history during the Mesozoic caused by low-amplitude vertical motions. Seven detrital apatite (U-Th)/He ages scatter between 33 and 77 Ma, possibly resulting from extreme compositional zonation associated with the authigenic U-rich overgrowths. The ~70 Ma (U-Th)/He ages are more likely to be accurate, setting 1-2 km as an upper limit (depending on the geothermal gradient) on the post-Cretaceous exhumation of the Cambrian sandstone and showing no evidence for substantial denudation related to Tertiary rifting of the Red Sea.

Cyclostratigraphic calibration of the Famennian stage (Late Devonian, Illinois Basin, USA)

NASA Astrophysics Data System (ADS)

Pas, Damien; Hinnov, Linda; Day, James E. (Jed); Kodama, Kenneth; Sinnesael, Matthias; Liu, Wei

2018-04-01

The Late Devonian biosphere was affected by two of the most severe biodiversity crises in Earth's history, the Kellwasser and Hangenberg events near the Frasnian-Famennian (F-F) and the Devonian-Carboniferous (D-C) boundaries, respectively. Current hypotheses for the causes of the Late Devonian extinctions are focused on climate changes and associated ocean anoxia. Testing these hypotheses has been impeded by a lack of sufficient temporal resolution in paleobiological, tectonic and climate proxy records. While there have been recent advances in astronomical calibration that have improved the accuracy of the Frasnian time scale and part of the Famennian, the time duration of the entire Famennian Stage remains poorly constrained. During the Late Devonian, a complete Late Frasnian-Early Carboniferous succession of deep-shelf deposits accumulated in the epieric sea in Illinois Basin of the central North-American mid-continent. A record of this sequence is captured in three overlapping cores (H-30, Sullivan and H-32). The H-30 core section spans the F-F boundary; the Sullivan section spans almost all of the Famennian and the H-32 section sampled spans the interval of the Upper Famennian and the D-C boundary. To have the best chance of capturing Milankovitch cycles, 2000 rock samples were collected at minimum 5-cm-interval across the entire sequence. Magnetic susceptibility (MS) was measured on each sample and the preservation of climatic information into the MS signal was verified through geochemical analyses and low-temperature magnetic susceptibility acquisition. To estimate the duration of the Famennian Stage, we applied multiple spectral techniques and tuned the MS signal using the highly stable 405 kyr cycle for Sullivan and the obliquity cycle for the H-30 and H-32 cores. Based on the correlation between the cores we constructed a Famennian floating astronomical time scale, which indicates a duration of 13.5 ± 0.5 myr. An uncertainty of 0.5 myr was estimated for the uncertainties arising from the errors in the stratigraphic position of the F-F and D-C boundaries, and the 405 kyr cycle counting. Interpolated from the high-resolution U-Pb radiometric ages available for the Devonian-Carboniferous boundary we recalibrated the Frasnian-Famennian boundary numerical age to 372.4 ± 0.9 Ma.

Upper Devonian outcrop stratigraphy, southwestern Virginia and southeastern West Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennison, J.M.; Filer, J.K.; Rossbach, T.J.

Ongoing outcrop studies are resulting in the extension of existing formal lithostratigraphic units and revision of previously less refined subdivisions of Upper Devonian strata in southwestern Virginia and southeastern West Virginia. A 425 km (263 mi) long stratigraphic cross-section has been constructed primarily from the outcrop belt along the Allegheny Structural Front, supplemented by sections from nearby outcrop belts. This NE-SW striking cross-section is oblique to the nearly due N-S depositional strike of the Upper Devonian Acadian orogenic wedge. To the southwest, the Upper Devonian section thins from 2,100 meters (6,900 feet) to 230 meters (756 feet) as progressively moremore » distal deposits are encountered. An integrated approach has been taken to establish chronostratigraphic control within the cross-section. The best time markers include particularly regressive parasequences which can be identified across facies boundaries (especially the Pound and Briery Gap Sandstones and their equivalents), volcanic ashes, and an organic-rich shale zone marking the base of a major transgression (equivalent to the base of the Huron Shale in Ohio and the Dunkirk Shale of New York). These tools provide chronostratigraphic correlation through the undivided Brallier Formation. Supplemental control includes biostratigraphic markers as well as marine dull redbeds within the Foreknobs which parallel other time lines and may represent partially reduced influxes of oxidized coastal plain sediments during minor parasequence scale regressions.« less

Evolution of groundwater composition in the depression cone of Riga region

NASA Astrophysics Data System (ADS)

Raga, B.; Kalvans, A.; Delina, A.; Perkone, E.; Retike, I.

2012-04-01

Riga is the capital of Latvia with around 0.9 million inhabitants where the main water supply is centralised and decentralised, mostly from groundwater sources, that is from the the Arukilas-Amatas multi-aquifer system, which consists of sandstones and siltstone. These rocks belong to the middle and upper Devonian and have good properties for groundwater extraction: they have high permeability and are widely spread. Below this system lies the middle Devonian Narvas aquitard, that consists of marl and clay. But in the southern and western part of Riga this system covers the upper Devonian Salaspils formation which consists of marl and gypsum. In the second half of the 20th century an intensive groundwater extraction from the Arukilas-Amtas multi-aquifer system took place in Riga, causing sharp and significant lowering of piezometric surfaces. The maximal decline of groundwater level was observed in 1972, when it was 16 m lower than the average. From the end of 80's started a regeneration of water table, when the volume of water usage began to decrease. Nowadays piezometric surface in the Arukilas-Amatas multi-aquifer system is being renewed and fluctuations are insignificant. The territory, where natural regime of groundwater has changed and that is induced by antropogenic effect is called "Large Riga". To track chemical changes and evolution in the Arukila-Amata multi-aquifer system long - term monitoring data is used. Data on major ions and piezometric surfaces from 45 monitoring wells that groups in 17 monitoring stations is being analysed. The area is dived into three zones - central, middle and periphery, which differ from each other by the volume of the groundwater level decline. These zones are determined from maps, that shows the piezometric surface difference between two periods: 1949-1951, that describes the natural situation, and 1970-1972, where the minimal groundwater level in the Gauja aquifer was observed. On this basis it was studied how rapidly water chemistry change in aquifers shows up and how these trends change. It was found out that the sources of water with high SO42- which worsen the quality of water in deeper aquifers, are from the Salaspils aquifer, because the first signs were observed in aquifers, that lie below the Salaspils formation. The same water composition changes in deeper aquifers with a time lag. When piezometric surface rised up, the mixing from different aquifers ended, that can be clearly observed in the upper Devonian Plavinu aquifer where, in the latest samples, is an increasing concentration of HCO3- ion. These are the first signs that the situation in this multi-aquifer system begins to return into natural conditions. Despite that Riga is lying near the sea, the lowering of water table in the Arukilas-Amatas multi-aquifer system hasn't induced intensive intrusion of sea water. This process is observed only in some areas, where intrusion occurs through the bed of river Daugava where the Plavinas aquifer dolomites are situated. The significant water composition changes are observed in the central part, where the greatest piezometric surface lowering is, which was sufficient enough to cause stronger downward flow from upper aquifers, that induced the mixing water from different aquifers in this territory. As a result, in this zone there are great water composition changes. Also the first signs about water composition changes show up very quickly, but the return to the natural situation is relatively slow. This study is supported by the European Social Fund project No. 2009/0212/1DP/1.1.1.2.0/09/APIA/VIAA/060

Carbon isotope chemostratigraphy and precise dating of middle Frasnian (lower Upper Devonian) Alamo Breccia, Nevada, USA

USGS Publications Warehouse

Morrow, J.R.; Sandberg, C.A.; Malkowski, K.; Joachimski, M.M.

2009-01-01

At Hancock Summit West, Nevada, western USA, uppermost Givetian (upper Middle Devonian) and lower and middle Frasnian (lower Upper Devonian) rocks of the lower Guilmette Formation include, in stratigraphic sequence, carbonate-platform facies of the conodont falsiovalis, transitans, and punctata Zones; the type Alamo Breccia Member of the middle punctata Zone; and slope facies of the punctata and hassi Zones. The catastrophically deposited Alamo Breccia and related phenomena record the ~ 382??Ma Alamo event, produced by a km-scale bolide impact into a marine setting seaward of an extensive carbonate platform fringing western North America. Re-evaluation of conodonts from the lower Guilmette Formation and Alamo Breccia Member, together with regional sedimentologic and conodont biofacies comparisons, now firmly locates the onset of the Johnson et al. (1985) transgressive-regressive (T-R) cycle IIc, which occurred after the start of the punctata Zone, within a parautochthonous megablock low in the Alamo Breccia. Whole-rock carbon isotope analyses through the lower Guilmette Formation and Alamo Breccia Member reveal two positive ??13Ccarb excursions: (1) a small, 3??? excursion, which is possibly correlative with the falsiovalis Event previously identified from sections in Western Europe and Australia, occurs below the breccia in the Upper falsiovalis Zone to early part of the transitans Zone; and (2) a large, multi-part excursion, dominated by a 6??? positive shift, begins above the start of the punctata Zone and onset of T-R cycle IIc and continues above the Alamo Breccia, ending near the punctata- hassi zonal boundary. This large excursion correlates with the punctata Event, a major positive ??13C excursion previously recognized in eastern Laurussia and northern Gondwana. Consistent with previous studies, at Hancock Summit West the punctata Event is apparently not associated with any regional extinctions or ecosystem reorganizations. In the study area, onset of the main punctata Event began after the start of both the punctata Zone and T-R cycle IIc, and preceded the Alamo impact by less than 650??k.y., as inferred from conodont biochronologic and regional rock-accumulation rate estimates. Although complicated by the heterolithic, high-energy deposits of the Alamo Breccia, the carbon isotope record of the breccia and post-breccia beds does not indicate a major impact-correlative perturbation to the carbon cycle. This study extends recognition of the punctata Event to western Laurussia, further reinforcing the potential global scale of the event and its potential importance to understanding early to middle Frasnian marine geochemistry and palaeoenvironments. Based on previous models and our observations, increased tectonic activity, increased nutrient flux to oceans, increased marine bioproductivity, widespread anoxia, and increased organic carbon burial were all likely key factors in driving the punctata Event excursion. Furthermore, periodic eustatic and regional relative sea-level rises may have played an important role in promoting organic carbon burial and in maintaining a link between the primary open-marine geochemical signal and that recorded on the shallow-marine, lower Guilmette carbonate platform. ?? 2009 Elsevier B.V. All rights reserved.

Tectonic control of Middle Devonian reef building in the Mechra ben Abbou (northern Rehamna, Morocco)Contrôle tectonique de l'édification des récifs Dévonien moyen de Mechra ben Abbou (Rehamna, Maroc)

NASA Astrophysics Data System (ADS)

El Kamel, Fouad; El Hassani, Ahmed; Mohsine, Assia; Remmal, Toufik

2000-01-01

In the carbonated platform of Upper Emsian to Givetian age, the reef edification is previous to, and contemporaneous with, a tilted block tectonic that has favoured the bioconstruction in its upper part. The tectonic expression is illustrated by several instability marks, such as tension faults, progressive unconformity and the resulting landslide, observed in both the reef development zone and the external platform.

Confirmation of the southwest continuation of the Cat Square terrane, southern Appalachian Inner Piedmont, with implications for middle Paleozoic collisional orogenesis

USGS Publications Warehouse

Huebner, Matthew T.; Hatcher, Robert D.; Merschat, Arthur J.

2017-01-01

Detailed geologic mapping, U-Pb zircon geochronology and whole-rock geochemical analyses were conducted to test the hypothesis that the southwestern extent of the Cat Square terrane continues from the northern Inner Piedmont (western Carolinas) into central Georgia. Geologic mapping revealed the Jackson Lake fault, a ∼15 m-thick, steeply dipping sillimanite-grade fault zone that truncates lithologically distinct granitoids and metasedimentary units, and roughly corresponds with a prominent aeromagnetic lineament hypothesized to represent the southern continuation of the terrane-bounding Brindle Creek fault. Results of U-Pb SHRIMP geochronology indicate Late Ordovician to Silurian granitoids (444–439 Ma) occur exclusively northwest of the fault, whereas Devonian (404–371 Ma) granitoids only occur southeast of the fault. The relatively undeformed Indian Springs granodiorite (three individual bodies dated 317–298 Ma) crosscuts the fault and occurs on both sides, which indicates the Jackson Lake fault is a pre-Alleghanian structure. However, detrital zircon signatures from samples southeast of the Jackson Lake fault reveal dominant Grenville provenance, in contrast to Cat Square terrane detrital zircon samples from the northern Inner Piedmont, which include peri-Gondwanan (600–500 Ma) and a prominent Ordovician-Silurian (∼430 Ma) signature. We interpret the rocks southeast of the Jackson Lake fault to represent the southwestern extension of the Cat Square terrane primarily based on the partitioning of granitoid ages and lithologic distinctions similar to the northern Inner Piedmont.Data suggest Cat Square terrane metasedimentary rocks were initially deposited in a remnant ocean basin setting and developed into an accretionary prism in front of the approaching Carolina superterrane, ultimately overridden by it in Late Devonian to Early Mississippian time. Burial to >20 km resulted in migmatization of lower plate rocks, forming an infrastructure beneath the Carolina superterrane suprastructure. Provenance patterns support ∼250 km of Devonian dextral translation of the composite Inner Piedmont, which places the northern portion of the Inner Piedmont adjacent to a suite of ∼430 Ma plutons in the Virginia Blue Ridge during deposition. The megascopic thrust-nappe structural style of the northern Inner Piedmont, combined with southwest-directed lateral extrusion at mid-crustal depths, may reconcile differences in timing of metamorphism between the Carolina and central Georgia Inner Piedmont and structural contrasts between the Brindle Creek and Jackson Lake faults.

Unique growth strategy in the Earth's first trees revealed in silicified fossil trunks from China.

PubMed

Xu, Hong-He; Berry, Christopher M; Stein, William E; Wang, Yi; Tang, Peng; Fu, Qiang

2017-11-07

Cladoxylopsida included the earliest large trees that formed critical components of globally transformative pioneering forest ecosystems in the Mid- and early Late Devonian (ca. 393-372 Ma). Well-known cladoxylopsid fossils include the up to ∼1-m-diameter sandstone casts known as Eospermatopteris from Middle Devonian strata of New York State. Cladoxylopsid trunk structure comprised a more-or-less distinct cylinder of numerous separate cauline xylem strands connected internally with a network of medullary xylem strands and, near the base, externally with downward-growing roots, all embedded within parenchyma. However, the means by which this complex vascular system was able to grow to a large diameter is unknown. We demonstrate-based on exceptional, up to ∼70-cm-diameter silicified fossil trunks with extensive preservation of cellular anatomy from the early Late Devonian (Frasnian, ca. 374 Ma) of Xinjiang, China-that trunk expansion is associated with a cylindrical zone of diffuse secondary growth within ground and cortical parenchyma and with production of a large amount of wood containing both rays and growth increments concentrically around individual xylem strands by normal cambia. The xylem system accommodates expansion by tearing of individual strand interconnections during secondary development. This mode of growth seems indeterminate, capable of producing trees of large size and, despite some unique features, invites comparison with secondary development in some living monocots. Understanding the structure and growth of cladoxylopsids informs analysis of canopy competition within early forests with the potential to drive global processes. Published under the PNAS license.

Edgecliff reefs - Devonian temperate water carbonate deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolosz, T.H.

1991-03-01

The Middle Devonian Edgecliff Member of the Onondaga Formation in New York and Ontario, Canada, is a coral-rich, reefy,' crinoidal grainstone/packstone. The reefs contain only rare stromatoporoids and are devoid of algae, having been constructed by a fauna of mound and thicket-forming branching colonial rugosans, and large sheet favositids that populated grainstone/packstone flank beds and banks. Despite the restricted fauna, the reefs display a variety of growth patterns. Rugosan mounds range in size from 2-3 m diameter by 1 m thick, up to 230 m diameter by 15 m thick. Composite structures consist of interbedded rugosan buildups and packstone/grainstone flanks,more » ranging from shield-shaped reefs (240 m diameter by 6 m thick) in which the rugosans occur only as thickets, to pinnacle reefs (up to 3 km diameter by 60 m thick) in which rugosan mounds are interbedded with crinoidal flanks. Geographic distribution of these reef types and analysis of surrounding facies suggests that reef growth pattern was controlled by water depth and local rate of subsidence. Despite superfacial resemblance to modern deep water ahermatypic coral mounds and thickets, abundant coral breakage and overturning, and erosion of at least one reef core during an intermediate stage of reef growth supports a shallow water origin of these reefs. It is suggested that the Edgecliff and its reefs represent an example of Devonian cool water carbonate deposition, a hypothesis supported by a trend of increasing stromatoporoid abundance westwards across New York (in the direction of the paleo-equator).« less

Stratigraphy of lower to middle Paleozoic rocks of northern Nevada and the Antler orogeny

USGS Publications Warehouse

Ketner, Keith B.

2013-01-01

Commonly accepted concepts concerning the lower Paleozoic stratigraphy of northern Nevada are based on the assumption that the deep-water aspects of Ordovician to Devonian siliceous strata are due to their origin in a distant oceanic environment, and their presence where we find them is due to tectonic emplacement by the Roberts Mountains thrust. The concept adopted here is based on the assumption that their deep-water aspects are the result of sea-level rise in the Cambrian, and all of the Paleozoic strata in northern Nevada are indigenous to that area. The lower part of the Cambrian consists mainly of shallow-water cross-bedded sands derived from the craton. The upper part of the Cambrian, and part of the Ordovician, consists mainly of deep-water carbonate clastics carried by turbidity currents from the carbonate shelf in eastern Nevada, newly constructed as a result of sea-level rise. Ordovician to mid-Devonian strata are relatively deep-water siliceous deposits, which are the western facies assemblage. The basal contact of this assemblage on autochthonous Cambrian rocks is exposed in three mountain ranges and is clearly depositional in all three. The western facies assemblage can be divided into distinct stratigraphic units of regional extent. Many stratigraphic details can be explained simply by known changes in sea level. Upper Devonian to Mississippian strata are locally and westerly derived orogenic clastic beds deposited disconformably on the western facies assemblage. This disconformity, clearly exposed in 10 mountain ranges, indicates regional uplift and erosion of the western facies assemblage and absence of local deformation. The disconformity represents the Antler orogeny.

Record of the Late Devonian Hangenberg global positive carbon-isotope excursion in an epeiric sea setting: Carbonate production, organic-carbon burial and paleoceanography during the late Famennian

USGS Publications Warehouse

Cramer, Bradley D.; Saltzman, Matthew R.; Day, J.E.; Witzke, B.J.

2008-01-01

Latest Famennian marine carbonates from the mid-continent of North America were examined to investigate the Late Devonian (very late Famennian) Hangenberg positive carbon-isotope (??13 Ccarb) excursion. This global shift in the ?? 13C of marine waters began during the late Famennian Hangenberg Extinction Event that occurred during the Middle Siphonodella praesulcata conodont zone. The post-extinction recovery interval spans the Upper S. praesulcata Zone immediately below the Devonian-Carboniferous boundary. Positive excursions in ?? 13 Ccarb are often attributed to the widespread deposition of organic-rich black shales in epeiric sea settings. The Hangenberg ??13 Ccarb excursion documented in the Louisiana Limestone in this study shows the opposite trend, with peak ??13 Ccarb values corresponding to carbonate production in the U.S. mid-continent during the highstand phase of the very late Famennian post-glacial sea level rise. Our data indicate that the interval of widespread black shale deposition (Hangenberg Black Shale) predates the peak isotope values of the Hangenberg ??13 Ccarb excursion and that peak values of the Hangenberg excursion in Missouri are not coincident with and cannot be accounted for by high Corg burial in epeiric seas. We suggest instead that sequestration and burial of Corg in the deep oceans drove the peak interval of the ??13Ccarb excursion, as a result of a change in the site of deep water formation to low-latitude epeiric seas as the global climate shifted between cold and warm states.

Secular distribution of highly metalliferous black shales corresponds with peaks in past atmosphere oxygenation

NASA Astrophysics Data System (ADS)

Johnson, Sean C.; Large, Ross R.; Coveney, Raymond M.; Kelley, Karen D.; Slack, John F.; Steadman, Jeffrey A.; Gregory, Daniel D.; Sack, Patrick J.; Meffre, Sebastien

2017-08-01

Highly metalliferous black shales (HMBS) are enriched in organic carbon and a suite of metals, including Ni, Se, Mo, Ag, Au, Zn, Cu, Pb, V, As, Sb, Se, P, Cr, and U ± PGE, compared to common black shales, and are distributed at particular times through Earth history. They constitute an important future source of metals. HMBS are relatively thin units within thicker packages of regionally extensive, continental margin or intra-continental marine shales that are rich in organic matter and bio-essential trace elements. Accumulation and preservation of black shales, and the metals contained within them, usually require low-oxygen or euxinic bottom waters. However, whole-rock redox proxies, particularly Mo, suggest that HMBS may have formed during periods of elevated atmosphere pO2. This interpretation is supported by high levels of nutrient trace elements within these rocks and secular patterns of Se and Se/Co ratios in sedimentary pyrite through Earth history, with peaks occurring in the middle Paleoproterozoic, Early Cambrian to Early Ordovician, Middle Devonian, Middle to late Carboniferous, Middle Permian, and Middle to Late Cretaceous, all corresponding with time periods of HMBS deposition. This counter-intuitive relationship of strongly anoxic to euxinic, localized seafloor conditions forming under an atmosphere of peak oxygen concentrations is proposed as key to the genesis of HMBS. The secular peaks and shoulders of enriched Se in sedimentary pyrite through time correlate with periods of tectonic plate collision, which resulted in high nutrient supply to the oceans and consequently maximum productivity accompanying severe drawdown into seafloor muds of C, S, P, and nutrient trace metals. The focused burial of C and S over extensive areas of the seafloor, during these anoxic to euxinic periods, likely resulted in an O2 increase in the atmosphere, causing short-lived peaks in pO2 that coincide with the deposition of HMBS. As metals become scarce, particularly Mo, Ni, Se, Ag, and U, the geological times of these narrow HMBS horizons will become a future focus for exploration.

The Cambrian-Ordovician rocks of Sonora, Mexico, and southern Arizona, southwestern margin of North America (Laurentia): chapter 35

USGS Publications Warehouse

Page, William R.; Harris, Alta C.; Repetski, John E.; Derby, James R.; Fritz, R.D.; Longacre, S.A.; Morgan, W.A.; Sternbach, C.A.

2013-01-01

The most complete sections of Ordovician shelf rocks in Sonora are 50 km (31 mi) northwast of Hermosillo. In these sections, the Lower Ordovician is characterized by intraclastic limestone, siltstone, shale, and chert. The Middle Ordovician is mostly silty limestone and quartzite, and the Upper Ordovician is cherty limestone and some argillaceous limestone. A major disconformity separates the Middle Ordovician quartzite from the overlying Upper Ordovician carbonate rocks and is similar to the disconformity between the Middle and Upper Ordovician Eureka Quartzite and Upper Ordovician Ely Springs Dolomite in Nevada and California. In parts of northwestern Sonora, Ordovician rocks are disconformably overlain by Upper Silurain rocks. Northeastward in Sonora and Arizona, toward the craton, Ordovician rocks are progressively truncated by a major onlap unconformity and are overliand by Devonian rocks. Except in local area, Ordovician rocks are generally absent in cratonic platform sequences in northern Sonora and southern Arizona.

Nature and regional significance of unconformities associated with the Middle Ordovician Hagan K-bentonite complex in the North American midcontinent

USGS Publications Warehouse

Kolata, Dennis R.; Huff, W.D.; Bergstrom, Stig M.

1998-01-01

Stratal patterns of the Middle Ordovician Hagan K-bentonite complex and associated rocks show that the Black River-Trenton unconformity in the North American midcontinent formed through the complex interplay of eustasy, sediment accumulation rates, siliciclastic influx, bathymetry, seawater chemistry, and perhaps local tectonic uplift. The unconformity is diachronous and is an amalgamated surface that resulted from local late Turinian lowstand exposure followed by regional early Chatfieldian transgressive drowning and sediment starvation. The duration of the unconformity is greatest in southern Wisconsin, northern Illinois, and northern Indiana, where the Deicke and Millbrig K-bentonite Beds converge at the unconformity. On the basis of published isotopic ages for the Deicke and Millbrig beds, it is possible that in these regions erosion and non-deposition spanned a period of as much as 3.2 m.y. Two broad coeval depositional settings are recognized within the North American midcontinent during early Chatfieldian time. 1) An inner shelf, subtidal facies of fossiliferous shale (Spechts Ferry Shale Member and Ion Shale Member of the Decorah Formation) and argillaceous lime mudstone and skeletal wackestone (Guttenberg and Kings Lake Limestone Members) extended from the Canadian shield and Transcontinental arch southeastward through Minnesota, Wisconsin, Iowa, and Missouri. 2) A seaward, relatively deep subtidal, sediment-starved, middle shelf extended eastward from the Mississippi Valley region to the Taconian foreland basins in the central and southern Appalachians and southward through the pericratonic Arkoma and Black Warrior basins. In the inner shelf region, the Black River-Trenton unconformity is a composite of at least two prominent hardground omission surfaces, one at the top of the Castlewood and Carimona Limestone Members and the other at the top of the Guttenberg and Kings Lake Limestone Members, both merging to a single surface in the middle shelf region. The inner and middle shelves redeveloped later in approximately the same regions during Devonian and Mississippian time.

A global cyclostratigraphic framework constrains the timing and pacing of environmental changes over the Late Devonian (Frasnian - Famennian) mass extinction

NASA Astrophysics Data System (ADS)

De Vleeschouwer, David; Da Silva, Anne-Christine; Day, James E.; Whalen, Michael; Claeys, Philippe

2016-04-01

Milankovitch cycles (obliquity, eccentricity and precession) result in changes in the distribution of solar energy over seasons, as well as over latitudes, on time scales of ten thousands of years to millions of years. These changing patterns in insolation have induced significant variations in Earth's past climate over the last 4.5 billion years. Cyclostratigraphy and astrochronology utilize the geologic imprint of such quasi-cyclic climatic variations to measure geologic time. In recent years, major improvements of the Geologic Time Scale have been proposed through the application of cyclostratigraphy, mostly for the Mesozoic and Cenozoic (Gradstein et al., 2012). However, the field of Paleozoic cyclostratigraphy and astrochronology is still in its infancy and the application of cyclostratigraphic techniques in the Paleozoic allows for a whole new range of research questions. For example, unraveling the timing and pacing of environmental changes over the Late Devonian mass extinction on a 105-year time-scale concerns such a novel research question. Here, we present a global cyclostratigraphic framework for late Frasnian to early Famennian climatic and environmental change, through the integration of globally distributed sections. The backbone of this relative time scale consists of previously published cyclostratigraphies for western Canada and Poland (De Vleeschouwer et al., 2012; De Vleeschouwer et al., 2013). We elaborate this Euramerican base by integrating new proxy data -interpreted in terms of astronomical climate forcing- from the Iowa basin (USA, magnetic susceptibility and carbon isotope data) and Belgium (XRF and carbon isotope data). Next, we expand this well-established cyclostratigraphic framework towards the Paleo-Tethys Ocean, using magnetic susceptibility and carbon isotope records from the Fuhe section in South China (Whalen et al., 2015). The resulting global cyclostratigraphic framework implies an important refinement of the late Frasnian to early Famennian stratigraphy, but also allows for an evaluation of the role of astronomical forcing in perturbing the global carbon cycle and pacing anoxic conditions throughout the Late Devonian mass extinction event. The late Frasnian anoxic Kellwasser events, for example, each represent only a portion of a 405-kyr eccentricity cycle, with the onset of both events separated by 500-600 kyr. References: De Vleeschouwer, D., Whalen, M. T., Day, J. E., and Claeys, P., 2012, Cyclostratigraphic calibration of the Frasnian (Late Devonian) time scale (western Alberta, Canada): Geological Society of America Bulletin, v. 124, no. 5-6, p. 928-942. De Vleeschouwer, D., Rakociński, M., Racki, G., Bond, D. P., Sobień, K., and Claeys, P., 2013, The astronomical rhythm of Late-Devonian climate change (Kowala section, Holy Cross Mountains, Poland): Earth and Planetary Science Letters, v. 365, p. 25-37. Gradstein, F. M., Ogg, J. G., Schmitz, M., and Ogg, G., 2012, The Geologic Time Scale 2012 2-Volume Set, Elsevier. Whalen, M. T., Śliwiński, M. G., Payne, J. H., Day, J. E., Chen, D., and da Silva, A.-C., 2015, Chemostratigraphy and magnetic susceptibility of the Late Devonian Frasnian-Famennian transition in western Canada and southern China: implications for carbon and nutrient cycling and mass extinction: Geological Society, London, Special Publications, v. 414.

Early evolution of the lungfish pectoral fin endoskeleton: evidence from the Middle Devonian (Givetian) Pentlandia macroptera

NASA Astrophysics Data System (ADS)

Jude, Emma; Johanson, Zerina; Kearsley, Anton; Friedman, Matt

2014-08-01

As the closest living relatives of tetrapods, lungfishes are frequently used as extant models for exploring the fin-to-limb transition. These studies have generally given little consideration to fossil taxa. This is because although lungfish fins are relatively common in the fossil record, the internal structure of these fins is virtually unknown. Information on pectoral-fin endoskeletons in fossil representatives of Dipnomorpha (the lungfish total group) is limited to poorly preserved remains in the lungfish Dipterus and Conchopoma and more complete material in the porolepiform Glyptolepis. Here we describe a well-preserved pectoral-fin endoskeleton in the Middle Devonian (Givetian) lungfish Pentlandia macroptera from the John O’Groats fish bed, Caithness, northeastern Scotland. The skeleton is in association with a cleithrum and clavicle, and consists of a series of at least eight mesomeres. Extensive series of preaxial and postaxial radials are present. Some of the radials are jointed, but none branch. No mesomere articulates with multiple radials on either its pre- or post-axial face. The first two mesomeres, corresponding to the humerus and ulna, bear well-developed axial processes. Uniquely among dipnomorphs, a distinct ossification centre corresponding to the radius is present in Pentlandia. A review of anatomy and development of the pectoral-fin endoskeleton in the living Neoceratodus is presented based on cleared and stained material representing different size stages. These developmental data, in conjunction with new details of primitive lungfish conditions based on Pentlandia, highlight many of the derived features of the pectoral-fin skeleton of Neoceratodus, and clarify patterns of appendage evolution within the dipnomorphs more generally.

Formation waters from Mississippian-Pennsylvanian reservoirs, Illinois basin, USA: Chemical and isotopic constraints on evolution and migration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stueber, A.M.; Walter, L.M.; Huston, T.J.

1993-02-01

We have analyzed a suite of seventy-four formation-water samples from Mississippian and Pennsylvanian carbonate and siliciclastic strata in the Illinois basin for major, minor, and trace element concentrations and for strontium isotopic composition. A subset of these samples was also analyzed for boron isotopic composition. Data are used to interpret origin of salinity and chemical and Sr isotopic evolution of the brines and in comparison with a similar data set from an earlier study of basin formation waters from Silurian-Devonian reservoirs. Systematics of Cl-Br-Na show that present Mississippian-Pennsylvanian brine salinity can be explained by a combination of subaerial seawater evaporationmore » short of halite saturation and subsurface dissolution of halite from an evaporite zone in the middle Mississippian St. Louis Limestone, along with extensive dilution by mixing with meteoric waters. Additional diagenetic modifications in the subsurface interpreted from cation/Br ratios include K depletion through interaction with clay minerals, Ca enrichment, and Mg depletion by dolomitization, and Sr enrichment through CaCO[sub 3] recrystallization and dolomitization. Ste. Genevieve Limestone (middle Mississippian) formation waters show [sup 87]Sr/[sup 86]Sr ratios in the range 0.70782-0.70900, whereas waters from the siliciclastic reservoirs are in the rante 0.70900-0.71052. Inverse correlations between [sup 87]Sr/[sup 86]Sr and B,Li, and Mg concentrations suggest that the brines acquired radiogenic [sup 87]Sr through interaction with siliciclastic minerals. Completely unsystematic relations between [sup 87]Fr/[sup 86]Sr and 1/Sr are observed; Sr concentrations in Ste. Genevieve and Aux Vases (middle Mississippian) waters appear to be buffered by equilibrium with respect to SrSo[sub 4]. These formation waters are distinguished from Silurian-Devonian brines in the basin by elevated Cl/Br and Na/Br ratios and by unsystematic Sr isotope relationships.« less

Geological duration of ammonoids controlled their geographical range of fossil distribution.

PubMed

Wani, Ryoji

2017-01-01

The latitudinal distributions in Devonian-Cretaceous ammonoids were analyzed at the genus level, and were compared with the hatchling sizes (i.e., ammonitella diameters) and the geological durations. The results show that (1) length of temporal ranges of ammonoids effected broader ranges of fossil distribution and paleobiogeography of ammonoids, and (2) the hatchling size was not related to the geographical range of fossil distribution of ammonoids. Reducing the influence of geological duration in this analysis implies that hatchling size was one of the controlling factors that determined the distribution of ammonoid habitats at any given period in time: ammonoids with smaller hatchling sizes tended to have broader ammonoid habitat ranges. These relationships were somewhat blurred in the Devonian, Carboniferous, Triassic, and Jurassic, which is possibly due to (1) the course of development of a reproductive strategy with smaller hatchling sizes in the Devonian and (2) the high origination rates after the mass extinction events.

Magnetostratigraphy of late Devonian carbonates of Western Australia: Integrating reversal history with biostratigraphic and 13C records

NASA Astrophysics Data System (ADS)

Tohver, E.; Playton, T.; Hillbun, K.; Yan, M.; Pisarevsky, S.; Hansma, J.; Roelofs, B.; Trinajstic, K.; Kirschvink, J. L.; Haines, P.

2016-12-01

The Global Polarity Timescale presents a useful basis for chronostratigraphic correlations, but pre-Jurassic records depend on records from sedimentary basins preserved on the continents. At present, the record for the late Devonian is poorly established. Here we present an integrated magnetostratigraphic, biostratigraphic and C-isotope study of the Canning Basin of Western Australia, located on the northern margin of eastern Gondwana. The study region is part of the classic "Devonian Great Barrier Reef", and preserves an outstanding marine record of a prominent mass extinction event (i.e., the Frasnian-Fammenian event, the fifth of the "Big Five" mass extinctions). We present magnetostratigraphic profiles from six different sections (2200 m total) from four separate localities that record different paleowater depths, i.e., lowermost slope to reef/platform deposits of the basin. Correlations between localities are based on conodont assemblages that can be correlated to global records. Paleomagnetic sampling was carried out at the meter-scale for magnetostratigraphic analysis, with duplicate specimens used for carbon isotope stratigraphy. Most samples record a magnetic overprint parallel to the modern geomagnetic direction, but this remanence was removed by laboratory heating to ca. 180°C. Approximately forty percent of samples retain a high temperature characteristic remanent magnetization (ChRM), typically carried by magnetite or hematite. Before using these ChRMs to assign a magnetic polarity, we filtered paleomagnetic directions to eliminate directions >45 degrees from the Fisherian mean direction, avoiding spurious directions and low latitude virtual geomagnetic poles (VGPs) from transitional field directions. The resulting magnetostratigraphic profiles were used to correlate different sections on the basis of matching reversal records, yielding a composite record of the Middle to Late Devonian geomagnetic reversal record. We recognized seventeen major magnetozones, although the total number of individual reversals is much higher. We examine the distribution of both VGPs and ChRMs to assess whether non-Fisherian statistics should be applied to magnetostratigraphic datasets, and we assess the factors that might cause ellipticity of both datasets.

Lower Paleozoic deep-water facies of the Medfra area, central Alaska: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1997

USGS Publications Warehouse

Dumoulin, Julie A.; Bradley, Dwight C.; Harris, Anita G.; Repetski, John E.

1999-01-01

Deep-water facies, chiefly hemipelagic deposits and turbidites, of Cambrian through Devonian age are widely exposed in the Medfra and Mt. McKinley quadrangles. These strata include the upper part of the Telsitna Formation (Middle-Upper Ordovician) and the Paradise Fork Formation (Lower Silurian-Lower Devonian) in the Nixon Fork terrane, the East Fork Hills Formation (Upper Cambrian-Lower Devonian) in the East Fork subterrane of the Minchumina terrane, and the chert and argillite unit (Ordovician) and the argillite and quartzite unit (Silurian- Devonian? and possibly older) in the Telida subterrane of the Minchumina terrane.In the western part of the study area (Medfra quadrangle), both hemipelagic deposits and turbidites are largely calcareous and were derived from the Nixon Fork carbonate platform. East- ern exposures (Mt. McKinley quadrangle; eastern part of the Telida subterrane) contain much less carbonate; hemipelagic strata are mostly chert, and turbidites contain abundant rounded quartz and lesser plagioclase and potassium feldspar. Deep-water facies in the Medfra quadrangle correlate well with rocks of the Dillinger terrane exposed to the south (McGrath quadrangle), but coeval strata in the Mt. McKinley quadrangle are compositionally similar to rocks to the northeast (Livengood quadrangle). Petrographic data thus suggest that the Telida subterranes presently defined is an artificial construct made up of two distinct sequences of disparate provenance.Restoration of 90 and 150 km of dextral strike-slip on the Iditarod and Farewell faults, respectively, aligns the deep-water strata of the Minchumina and Dillinger terranes in a position east of the Nixon Fork carbonate platform. This restoration supports the interpretation that lower Paleozoic rocks in the Nixon Fork and Dillinger terranes, and in the western part of the Minchumina terrane (East Fork subterrane and western part of the Telida subterrane), formed along a single continental margin. Rocks in the eastern part of the Telida subterrane are compositionally distinct from those to the west and may have had a different origin and history.

Rhenium and osmium isotopes in black shales and Ni-Mo-PGE-rich sulfide layers, Yukon Territory, Canada, and Hunan and Guizhou provinces, China

USGS Publications Warehouse

Horan, M.F.; Morgan, J.W.; Grauch, R.I.; Coveney, R.M.; Murowchick, J.B.; Hulbert, L.J.

1994-01-01

Rhenium and osmium abundances and osmium isotopic compositions were determined by negative thermal ionization mass spectrometry for samples of Devonian black shale and an associated Ni-enriched sulfide layer from the Yukon Territory, Canada. The same composition information was also obtained for samples of early Cambrian Ni-Mo-rich sulfide layers hosted in black shale in Guizhou and Hunan provinces, China. This study was undertaken to constrain the origin of the PGE enrichment in the sulfide layers. Samples of the Ni sulfide layer from the Yukon Territory are highly enriched in Re, Os, and other PGE, with distinctly higher Re/192Os but similar Pt/Re, compared to the black shale host. Re-Os isotopic data of the black shale and the sulfide layer are approximately isochronous, and the data plot close to reference isochrons which bracket the depositional age of the enclosing shales. Samples of the Chinese sulfide layers are also highly enriched in Re, Os, and the other PGE. Re/192Os are lower than in the Yukon sulfide layer. Re-Os isotopic data for the sulfide layers lie near a reference isochron with an age of 560 Ma, similar to the depositional age of the black shale host. The osmium isotopic data suggest that Re and PGE enrichment of the brecciated sulfide layers in both the Yukon Territory and in southern China may have occurred near the time of sediment deposition or during early diagenesis, during the middle to late Devonian and early Cambrian, respectively. ?? 1994.

Thermal maturity map of Devonian shale in the Illinois, Michigan, and Appalachian basins of North America

USGS Publications Warehouse

East, Joseph A.; Swezey, Christopher S.; Repetski, John E.; Hayba, Daniel O.

2012-01-01

Much of the oil and gas in the Illinois, Michigan, and Appalachian basins of eastern North America is thought to be derived from Devonian shale that is within these basins (for example, Milici and others, 2003; Swezey, 2002, 2008, 2009; Swezey and others, 2005, 2007). As the Devonian strata were buried by younger sediments, the Devonian shale was subjected to great temperature and pressure, and in some areas the shale crossed a thermal maturity threshold and began to generate oil. With increasing burial (increasing temperature and pressure), some of this oil-generating shale crossed another thermal maturity threshold and began to generate natural gas. Knowledge of the thermal maturity of the Devonian shale is therefore useful for predicting the occurrence and the spatial distribution of oil and gas within these three basins. This publication presents a thermal maturity map of Devonian shale in the Illinois, Michigan, and Appalachian basins. The map shows outlines of the three basins (dashed black lines) and an outline of Devonian shale (solid black lines). The basin outlines are compiled from Thomas and others (1989) and Swezey (2008, 2009). The outline of Devonian shale is a compilation from Freeman (1978), Thomas and others (1989), de Witt and others (1993), Dart (1995), Nicholson and others (2004), Dicken and others (2005a,b), and Stoeser and others (2005).

Zaphrentis and the Zaphrentidae (Devonian; anthozoa, rugosa)

USGS Publications Warehouse

Oliver, W.A.

2007-01-01

Zaphrentis is one of the most widely used names in Paleozoic coral paleontology. Species of "Zaphrentis" have been named from every Paleozoic System except the Cambrian. Variants of the word, such as zaphrentoid, are widely used with varied meanings. Nomenclatural spinoffs are numerous: Neozaphrentis and Heterophrentis are obvious examples, but dozens of additional genera have type species that were originally described in Zaphrentis. Many paleontologists are familiar with the word but few really know what it means. Zaphrentis (as a subgenus) and five new species were named in 1820, based on corals from the Falls of the Ohio River between Louisville, Kentucky, and Clarksville, Indiana. Descriptions were minimal, none was illustrated, and no specimens were preserved as types. Nominal species of "Zaphrentis" proliferated for over 100 years before a redescription based on Falls specimens was published (1938), the probable source beds recognized (1942), a neotype selected (1965) and adequately described and illustrated (1981). At this time, I recognize only four zaphrentid genera: Zaphrentis (middle Eifelian), Heliophyllum (middle Emsian through Givetian), Aemulophyllum (middle Emsian), and Cyathocylindrium (lower Emsian?; middle Emsian through Eifelian). All four genera seem to have originated in the Eastern Americas Biogeographic Realm. Heliophyllum is the most common, has the longest stratigraphic range, and is the only one known to occur outside of its area of origin. Heliophyllum modicum n. sp., once discussed as a possible Zaphrentis, is described and compared with both the type species of Zaphrentis and other Heliophyllum species. A single coral specimen from the Indian Cove Formation (upper Pragian or lower Emsian), Gaspe??, Quebec, is considered the earliest known zaphrentid and is described as Cyathocylindrium? n. sp.

Petrological, geochemical, isotopic, and geochronological constraints for the Late Devonian-Early Carboniferous magmatism in SW Gondwana (27-32°LS): an example of geodynamic switching

NASA Astrophysics Data System (ADS)

Dahlquist, Juan A.; Alasino, Pablo H.; Basei, Miguel A. S.; Morales Cámera, Matías M.; Macchioli Grande, Marcos; da Costa Campos Neto, Mario

2018-04-01

We report a study integrating 13 new U-Pb LA-MC-ICP-MS zircon ages and Hf-isotope data from dated magmatic zircons together with complete petrological and whole-rock geochemistry data for the dated granitic rocks. Sample selection was strongly based on knowledge reported in previous investigations. Latest Devonian-Early Carboniferous granite samples were collected along a transect of 900 km, from the inner continental region (present-day Eastern Sierras Pampeanas) to the magmatic arc (now Western Sierras Pampeanas and Frontal Cordillera). Based on these data together with ca. 100 published whole-rock geochemical analyses we conclude that Late Devonian-Early Carboniferous magmatism at this latitude represents continuous activity (ranging from 322 to 379 Ma) on the pre-Andean margin of SW Gondwana, although important whole-rock and isotopic compositional variations occurred through time and space. Combined whole-rock chemistry and isotope data reveal that peraluminous A-type magmatism started in the intracontinental region during the Late Devonian, with subsequent development of synchronous Carboniferous peraluminous and metaluminous A-type magmatism in the retro-arc region and calc-alkaline magmatism in the western paleomargin. We envisage that magmatic evolution was mainly controlled by episodic fluctuations in the angle of subduction of the oceanic plate (between flat-slab and normal subduction), supporting a geodynamic switching model. Subduction fluctuations were relatively fast (ca. 7 Ma) during the Late Devonian and Early Carboniferous, and the complete magmatic switch-off and switch-on process lasted for 57 Ma. Hf T DM values of zircon (igneous and inherited) from some Carboniferous peraluminous A-type granites in the retro-arc suggest that Gondwana continental lithosphere formed during previous orogenies was partly the source of the Devonian-Carboniferous granitic magmas, thus precluding the generation of the parental magmas from exotic terranes.

Ten Windows Into the Meteorite Flux to Earth During the Past 500 Million Years

NASA Astrophysics Data System (ADS)

Schmitz, B.

2017-12-01

Almost nothing is known about the variations through deep time in the types of meteorites arriving at Earth. In an ongoing project we are searching ancient sediments from ten different time periods through the Phanerozoic for relict extraterrestrial spinel grains from micrometeorites (Schmitz, 2013). Samples, 300-1500 kg large, of slowly formed pelagic limestone are dissolved in acids leaving a residue of extraterrestrial spinels. The time periods studied include the middle Cambrian, Ordovician before and after the breakup of the L-chondrite parent body, late Silurian, late Devonian, middle Jurassic, early and late Cretaceous, early Paleocene and late Eocene. The approach builds on complex methodological considerations and a thorough understanding also of the spinel fraction in recent meteorites is necessary. In order to obtain some insights into the changes in the meteorite flux carefully calibrated analyses of the isotopic and elemental composition of the recovered spinel grains as well as consistent data treatment is required for the different time windows. Our results indicate that the background meteorite flux has changed significantly through the Phanerozoic. The results so far suggest that there may have been a gradual long-term (on the order of hundred million years) turnover in the meteorite flux from dominance of achondrites in the early Phanerozoic to ordinary chondrites in the late Phanerozoic interrupted by short-term (a few million years) meteorite cascades from single asteroid breakup events. This scenario may change, however, as results from additional time windows emerge. B. Schmitz (2013) Extraterrestrial spinels and the astronomical perspective on Earth's geological record and evolution of life: Chemie der Erde 73:117-145.

Chronology of paleozoic metamorphism and deformation in the Blue Ridge thrust complex, North Carolina and Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldberg, S.A.; Dallmeyer, R.D.

1997-05-01

The Blue Ridge province in northwestern North Carolina and northeastern Tennessee records a multiphase collisional and accretionary history from the Mesoproterozoic through the Paleozoic. To constrain the tectonothermal evolution in this region, radiometric ages have been determined for 23 regionally metamorphosed amphibolites, granitic gneisses, and pelitic schists and from mylonites along shear zones that bound thrust sheets and within an internal shear zone. The garnet ages from the Pumpkin Patch a thrust sheet (458, 455, and 451 Ma) are similar to those from the structurally overlying Spruce Pine thrust sheet (460, 456, 455, and 450 Ma). Both thrust sheets exhibitmore » similar upper amphibolite-facies conditions. Because of the high closure temperature for garnet, the garnet ages are interpreted to date growth at or near the peak of Taconic metamorphism. Devonian metamorphic ages are recognized in the Spruce Pine thrust sheet, where Sm-Nd and Rb-Sr garnet ages of 386 and 393 Ma and mineral isochron ages of 397 {+-} 14 and 375 {+-} 27 Ma are preserved. Hornblendes record similar {sup 40}Ar/{sup 39}Ar, Sm-Nd, and Rb-Sr ages of 398 to 379 Ma. Devonian {sup 40}Ar/{sup 39}Ar hornblende ages are also recorded in the structurally lower Pumpkin Patch thrust sheet. The Devonian mineral ages are interpreted to date a discrete tectonothermal event, as opposed to uplift and slow cooling from an Ordovician metamorphic event. The Mississippian mylonitization is interpreted to represent thrusting and initial assembly of crystalline sheets associated with the Alleghanian orogeny. The composite thrust stack of the Blue Ridge complex was subsequently thrust northwestward along the Linville Falls fault during middle Alleghanian orogeny (about 300 Ma).« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.

This document consists of the following papers: inorganic geochemistry studies of the Eastern Kentucky Gas Field; lithology studies of upper Devonian well cuttings in the Eastern Kentucky Gas Field; possible effects of plate tectonics on the Appalachian Devonian black shale production in eastern Kentucky; preliminary depositional model for upper Devonian Huron age organic black shale in the Eastern Kentucky Gas Field; the anatomy of a large Devonian black shale gas field; the Cottageville (Mount Alto) Gas Field, Jackson County, West Virginia: a case study of Devonian shale gas production; the Eastern Kentucky Gas Field: a geological study of the relationshipsmore » of Ohio Shale gas occurrences to structure, stratigraphy, lithology, and inorganic geochemical parameters; and a statistical analysis of geochemical data for the Eastern Kentucky Gas Field.« less

The pre-Mesozoic tectonic unit division of the Xing-Meng orogenic belt (XMOB)

NASA Astrophysics Data System (ADS)

Xu, Bei; Zhao, Pan

2014-05-01

According to the viewpoint that the paleo-Asian ocean closed by the end of early Paleozoic and extended during the late Paleozoic, a pre-Mesozoic tectonic unit division has been suggested. Five blocks and four sutures have been recognized in the pre-Devonia stage, the five blocks are called Erguna (EB), Xing'an (XB), Airgin Sum-Xilinhot (AXB), Songliao-Hunshandak (SHB) and Jiamusi (JB) blocks and four sutures, Xinlin-Xiguitu (XXS), Airgin Sum-Xilinhot-Heihe (AXHS), Ondor Sum-Jizhong-Yanji (OJYS) and Mudanjiang (MS) sutures. The EB contains the Precambrian base with the ages of 720-850Ma and ɛHf(T)=+2.5to +8.1. The XB is characterized by the Paleoproterozoic granitic gneiss with ɛHf(T)=-3.9 to -8.9. Several ages from 1150 to 1500 Ma bave been acquired in the AXB, proving presence of old block that links with Hutag Uul block in Mongolia to the west. The Paleoproterozoic (1.8-1.9Ga) and Neoproterozoic (750-850Ma) ages have been reported from southern and eastern parts of the SHB, respectively. As a small block in east margin of the XMOB, the JB outcrops magmatite and granitic gneiss bases with ages of 800-1000Ma. The XXS is marked by blueschists with zircon ages of 490-500Ma in Toudaoqiao village, ophiolites in Xiguitu County and granite with ages of about 500Ma along the northern segment of XXS. The AXHS is characterized by the early Paleozoic arc magmatic rocks with ages from 430Ma to 490Ma, mélange and the late Devonia molass basins, which indicates a northward subduction of the SHB beneath the AXB during the early-middle Paleozoic. The OJYS is composed of the early Paleozoic volcanic rocks, diorites and granites with ages of 425-475Ma, blueschists, ophiolitic mélange, the late Silurian flysch and Early-Middle Devonian molasses in western segment, granites (420-450Ma) in middle segment, and plagiogranites (443Ma) and the late Silurian molasses in eastern segment. This suture was caused by a southward subduction of the SHB beneath the North China block. The MS is between the SHB and JB, marked by the three phase granites of 485, 450 and 425Ma in the SHB. Tectonic units of the middle Devonian-Carboniferous tectonic stage include the middle-late Devonian continental basin, Carboniferious continental and epeiric sea basin, intrusive and irruptive igneous rock belt with ages from 300Ma to 330Ma containing granites, diorites, gabbros and biomodal volcanic rocks, and early Carboniferious ophiolites of 330-350Ma in Hegenshan and Erenhot. The Permian tectonic units can be divided into continental rift belt, ophiolite belt, alkaline rock belt and "red sea"-like ocean basin, which indicates an continuous extension environment during the Permian. The continental rift belt is composed of thick continental sedimentary rocks containing plant fossils, biomodal volcanic rocks (270-290Ma). The alkaline rocks can be divided into north and south belts by their distribution. The Solonker ophiolite is a thrust sheet that is inserted in a thrust stack containing the Upper Carboniferious epeiric sea clastic rocks and carbornates. The "red sea"-like ocean basin is characterized by basalt sequences with ages of 246-260Ma, which shows an affinity to E-MORB and a tendency towards OIB.

Geology of the Cupsuptic quadrangle, Maine

USGS Publications Warehouse

Harwood, David S.

1966-01-01

The Cupsuptic quadrangle, in west-central Maine, lies in a relatively narrow belt of pre-Silurian rocks extending from the Connecticut River valley across northern New Hampshire to north-central Maine. The Albee Formation, composed of green, purple, and black phyllite with interbedded-quartzite, is exposed in the core of a regional anticlinorium overlain to the southeast by greenstone of the Oquossoc Formation which in turn is overlain by black slate of the Kamankeag Formation. In the northern part of the quadrangle the Albee Formation is overlain by black slate, feldspathic graywacke, and minor greenstone of the Dixville Formation. The Kamankeag Formation is dated as 1-ate Middle Ordovician by graptolites (zone 12) found near the base of the unit. The Dixville Formation is correlated with the Kamankeag Formation and Oquossoc Formation and is considered to be Middle Ordovician. The Albee Formation is considered to be Middle to Lower Ordovician from correlations with similar rocks in northeastern and southwestern Vermont. The Oquossoc and Kamankeag Formations are correlated with the Amonoosuc and Partridge Formations of northern New Hampshire. The pre-Silurian rocks are unconformably overlain by unnamed rocks of Silurian age in the southeast, west-central, and northwest ninths of the quadrangle. The basal Silurian units are boulder to cobble polymict conglomerate and quartz-pebble conglomerate of late Lower Silurian (Upper Llandovery) age. The overlying rocks are either well-bedded slate and quartzite, silty limestone, or arenaceous limestone. Thearenaceous limestone contains Upper Silurian (Lower Ludlow) brachiopods. The stratified rocks have been intruded by three stocks of biotite-muscovite quartz monzonite, a large body of metadiorite and associated serpentinite, smaller bodies of gabbro, granodiorite, and intrusive felsite, as well as numerous diabase and quartz monzonite dikes. The metadiorite and serpentinite, and possibly the gabbro and granodiorite are Late Ordovician in age. The quartz monzonite is considered to be Late Devonian. Five tectonic events are inferred from the structural features in the area. The earliest was a period of folding producing tightly-appressed, northeast-trending folds in the rocks of pre-Silurian age. In the second stage the folded pre-Silurian rocks were uplifted, eroded, and truncated to produce a major unconformity between the Middle Ordovician and Lower Silurian rocks. These events constitute the Taconic orogeny. The third tectonic event was a period of folding, probably of Middle Devonian age, that warped the unconformity and overlying rocks into open, gently-plunging, east-trending folds. This period of folding undoubtedly changed the attitude of the early folds in the pre-Silurian units but it did not produce any recognizable, cross-cutting planar features in the older rocks. The fourth tectonic event was a period of igneous intrusion that locally deformed the northeast-trending folds in the pre-Silurian rocks into a macroscopic drag fold plunging at 80 degrees in a direction S.10?w. A north-trending, subvertical slip cleavage was produced locally during this period of Late Devonian (?) deformation. A period of faulting, possibly of Triassic age, dislocated some of the earlier features. The rocks are in the chlorite zone of regional metamorphism, but have been contact metamorphosed to sillimanite-bearing hornfels adjacent to the quartz monzonite stocks. The chemical changes in chlorite, biotite, garnet, cordierite, and muscovite in the chlorite, biotite, andalusite, and sillimanite zones have been-studied by optical and x-ray methods and by partial chemical analyses. The progressive changes in mineral assemblages have been graphically portrayed on quaternary diagrams and ternary projections.

An outline of the palaeogeographic evolution of the Australasian region since the beginning of the Neoproterozoic

NASA Astrophysics Data System (ADS)

Li, Z. X.; Powell, C. McA.

2001-04-01

In the last 1000 million years, Australia has been part of two supercontinents: Palaeozoic Gondwanaland and Neoproterozoic Rodinia. Neoproterozoic Australia was covered by shallow epicontinental seas, and, in the late Neoproterozoic, by low-latitude glaciers. The breakup of Rodinia along the Tasman Line occurred at the end of the Sturtian glaciation (760 Ma) giving rise to the Palaeo-Pacific Ocean. Gondwanaland formed in the Early Cambrian, at the same time as the Tarim block broke away from northwestern Australia. Westward subduction of the Palaeo-Pacific Ocean along the eastern margin of Australia-Antarctica commenced during the Early Cambrian in northern Victoria Land and in the Middle Cambrian in South Australia, and culminated to the Late Cambrian-Early Ordovician Ross-Delamerian Mountains. In the Ordovician, the magmatic arc retreated from Australia's then-eastern continental margin, forming a marginal sea and offshore island arc. A shallow seaway across Australia in the Late Cambrian and Ordovician gradually gave way to desert-like conditions in Central Australia and the adjacent Canning Basin by Silurian time. The Silurian to mid-Devonian was an interval of rapidly changing palaeogeography in eastern Australia with deep volcanogenic troughs formed in a dextral transtensional tectonic setting. Widespread deformation in the Tasman orogenic zone in the Middle Devonian to Early Carboniferous, was accompanied by the development of an Andean-style magmatic arc along the Pacific continental margin of Australia. The most widespread Phanerozoic mountain-building stage in Central Australia occurred in the Late Devonian to mid-Carboniferous, as part of a world-wide Variscan orogenic episode associated with the collision of Gondwanaland with Laurussia to form Pangea. In the late Visean, Australia drifted rapidly southward from previous low latitudes to a near-polar position. Glacial conditions dominated the Late Carboniferous and earliest Permian. Transtensional basins associated with dextral oroclinal shear along the Panthalassan eastern margin of Australia developed in the Late Carboniferous and persisted until the Late Permian, when an Andean-style magmatic arc was re-established. Large foreland basins inboard of the Late Permian to Early Triassic magmatic arc accumulated major coal deposits during Late Permian volcanic phases, but drastic climatic changes at the end of the Permian, possibly caused by global greenhouse conditions, led to red-bed deposition in the Early Triassic. Pangea began to rift in the mid-Triassic, and by the Late Triassic, the Cimmerian blocks, which lay off northwestern Australia throughout the Palaeozoic, had departed the northern margin of Gondwanaland. A new Andean-style continental magmatic arc became established along the Pacific Ocean margin of Australia. Breakup between Australia-Antarctica and the northern part of Greater India commenced ca. 130 Ma, and between Australia and Antarctica around 96 Ma. At the beginning of the Palaeogene, Australia commenced its northward drift towards its present position. Seafloor spreading between Australia and Antarctica was at first slow, but increased to ca. 5 cm per year around 45 Ma. By 35 Ma, the circum-Antarctic current became established, thereby triggering glaciation in Antarctica. Northern Australia reached the tropics by the beginning of the Miocene, and Australia has progressively moved northwards at 7 to 8 cm per year since.

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Natural gas produced... DETERMINATION PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.303 Natural gas produced from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale...

18 CFR 270.303 - Natural gas produced from Devonian shale.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Natural gas produced... DETERMINATION PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.303 Natural gas produced from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale...

Reported middle Paleozoic fossils and new geochronological data from the southern and central Appalachians: Disposable outrageous hypothesis or justification for major revision of tectonic history

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hatcher, R.D. Jr.

Recently published interpretations of fossil fragments from the Walden Creek Group (Ocoee Supergroup) suggesting that these rocks are middle Paleozoic (Devonian to Early Carboniferous), and new geochronological data that yield late Paleozoic age dates on rocks and major faults in the Blue Ridge and piedmont, if taken alone, would permit speculation that most of the deformation and metamorphism affecting this part of the orogen is Alleghanian. The two Ordovician clastic wedges (Sevier, Llanvirn, and Martinsburg, Caradoc-Ashgill) and the Carboniferous-Permian wedge(s), along with many radiometric ages on plutons, indicate uplift and sediment dispersal from the interior of the southern and centralmore » Appalachians (SCA) that may have resulted from Taconian and Alleghanian deformation. Combining the reproducible fossil evidence, including that from Alabama and a recently discovered crinoid fragment from the upper part of the Murphy belt sequence, with the most current geochronological data requires that peak metamorphism and penetrative deformation be at least Devonian or younger at the southwestern end of the orogen, and Late Ordovician or younger in the Carolinas and northern Georgia. Zircon ages reported from large thrust and dextral strike-slip faults bounding the Pine Mountain window indicate all of the faults there may be Alleghanian, except the younger sinistral Mesozoic faults, and requires that both metamorphism and penetrative deformation there also be Alleghanian. As in New England, the southern Appalachian Alleghanian metamorphic core is now known to be much more extensive. The older data require that the Taconian and perhaps the Acadian orogenies were significant events in the SCA, but these new data reconfirm the dominance of Alleghanian continent-continent collision processes here.« less

Stable isotopic compositions of early calcite cements in the Middle Devonian Coralville Formation (Cedar Valley Group), eastern Iowa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ludvigson, G.A.; Gonzalez, L.S.; Witzke, B.J.

1993-03-01

The Middle-Upper Devonian Cedar Valley Gp in Iowa is subdivided into four formations each representing a broad transgressive-regressive (T-R) cycle of deposition. Cycles consist of basal open marine facies that shallow upward into capping peritidal facies. Results from ongoing diagenetic studies of the Coralville Fm (late Givetian), the second T-R cycle of the Cedar Valley Gp, have focused attention on the origins of early cements. Early calcite cements in the Coralville Fm of Johnson County, Iowa, include blocky equant spars filling fenestral voids in birdseye limestones of the Iowa City Mbr and isopachous bladed spars that occur throughout the Coralville.more » Bladed spars fill stromatactis and microkarstic voids in the Iowa City Mbr, and sheltered voids in underlying open-marine skeletal packstones of the Cou Falls Mbr (lower Coralville cycle). The bladed spars include nonluminescent inclusion-free domains that contain up to 4,000 ppm Mg, and luminescent inclusion-rich domains that contain less than 2,000 ppm Mg. Birdseye spars have a constructive oscillatory luminescent-nonluminescent zonation controlled by Mn contents and contain less than 1,000 ppm Mg. Nonluminescent domains in bladed spars have the heaviest oxygen isotopic compositions of all components in the Coralville, similar to the isotopically heaviest nonluminescent brachiopods but have [delta][sup 13]C values ranging from [minus]3 to [minus]5 [per thousand]. They are interpreted to have precipitated from marine fluids saturated by CO[sub 2] produced from bacterial oxidation of organic matter. Altered luminescent domains in the bladed spars have the same [delta][sup 13]C compositions, but have widely varying [delta][sup 18]O compositions, ranging to [minus]9 [per thousand].« less

An intramontane pull-apart basin in tectonic escape deformation: Elbistan Basin, Eastern Taurides, Turkey

NASA Astrophysics Data System (ADS)

Yusufoğlu, H.

2013-04-01

The Elbistan Basin in the east-Central Anatolia is an intramontane structural depression in the interior part of the Anatolide-Tauride Platform. The Neogene fill in and around Elbistan Basin develops above the Upper Devonian to lower Tertiary basement and comprises two units separated by an angular unconformity: (1) intensely folded and faulted Miocene shallow marine to terrestrial and lacustrine sediments and (2) nearly flat-lying lignite-bearing lacustrine (lower unit) and fluvial (upper unit) deposits of Plio-Quaternary Ahmetçik Formation. The former is composed of Lower-Middle Miocene Salyan, Middle-upper Middle Miocene Gövdelidağ and Upper Miocene Karamağara formations whereas the latter one is the infill of the basin itself in the present configuration of the Elbistan Basin. The basin is bound by normal faults with a minor strike-slip component. It commenced as an intramontane pull-apart basin and developed as a natural response to Early Pliocene tectonic escape-related strike-slip faulting subsequent to post-collisional intracontinental compressional tectonics during which Miocene sediments were intensely deformed. The Early Pliocene time therefore marks a dramatic changeover in tectonic regime and is interpreted as the beginning of the ongoing last tectonic evolution and deformation style in the region unlike to previous views that it commenced before that time. Consequently, the Elbistan Basin is a unique structural depression that equates the extensional strike-slip regime in east-Central Anatolia throughout the context of the neotectonical framework of Turkey across progressive collision of Arabia with Eurasia. Its Pliocene and younger history differs from and contrasts with that of the surrounding pre-Pliocene basins such as Karamağara Basin, on which it has been structurally superimposed.

Sedimentology of gas-bearing Devonian shales of the Appalachian Basin

NASA Astrophysics Data System (ADS)

Potter, P. E.; Maynard, J. B.; Pryor, W. A.

1981-01-01

Sedimentology of the Devonian shales and its relationship to gas, oil, and uranium are reported. Information about the gas bearing Devonian shales of the Appalachian Basin is organized in the following sections: paleogeography and basin analysis; lithology and internal stratigraphy; paleontology; mineralogy, petrology, and chemistry; and gas oil, and uranium.

Devonian and Mississippian rocks of the northern Antelope Range, Eureka County, Nevada

USGS Publications Warehouse

Hose, Richard Kenneth; Armstrong, A.K.; Harris, A.G.; Mamet, B.L.

1982-01-01

Lower through Upper Devonian rocks of the northern Antelope Range, Nev., consist of four formational rank units more than 800 m thick, separated from Mississippian units by an unconformity. The lower three Devonian units, the Beacon Peak Dolomite, McColley Canyon Formation, and Denay Limestone are known in other areas; the top unit, the Fenstermaker Wash Formation, is new. The Mississippian units, more than 280 m thick, are divisible into three units which are unlike coeval units elsewhere, and are herein named the Davis Spring Formation, Kinkead Spring Limestone, and Antelope Range Formation. Systematic sampling of the Devonian sequence has yielded relatively abundant conodonts containing several biostratigraphic ally significant taxa. The Mississippian units contain redeposited conodonts of chiefly Late Devonian and Early Mississippian (Kinderhookian) age together with indigenous Osagean foraminifers and algae in the Kinkead Spring Limestone.

Emsian synorogenic paleogeography of the Maine Applachians

USGS Publications Warehouse

Bradley, D.; Tucker, R.

2002-01-01

The Acadian deformation front in the northern Appalachians of Maine and New Hampshire can now be closely located during the early Emsian (Early Devonian; 408-406 Ma). Tight correlations between paleontologically and isotopically dated rocks are possible only because of a new 408-Ma time scale tie point for the early Emsian. The deformation front lay between a belt of Lower Devonian flysch and molasse that were deposited in an Acadian foreland basin and had not yet been folded and a belt of early Emsian plutons that intruded folded Lower Devonian rocks. This plutonic belt includes the newly dated Ore Mountain gabbro (U/Pb; 406 Ma), which hosts magmatic-sulfide mineralization. Along the deformation front, a 407-Ma pluton that locally truncates Acadian folds (Katahdin) was the feeder to volcanic rocks (Traveler Rhyolite; 406-407 Ma) that are part of the foreland-basin succession involved in these same folds. The Emsian igneous rocks thus define a syncollisional magmatic province that straddled the deformation front. These findings bear on three alternative subduction geometries for the Acadian collision.

Volcanic arc emplacement onto the southernmost Appalachian Laurentian shelf: Characteristics and constraints

USGS Publications Warehouse

Tull, J.F.; Barineau, C.I.; Mueller, P.A.; Wooden, J.L.

2007-01-01

In the southernmost Appalachians, the Hillabee Greenstone, an Ordovician volcanic arc fragment, lies directly atop the outermost Laurentian Devonian-earliest Mississippian(?) shelf sequence at the structural top of the greenschist facies Talladega belt, the frontal metamorphic allochthon along this orogenic segment. The Hillabee Greenstone was emplaced between latest Devonian and middle Mississippian time. It and the uppermost Laurentian section were later repeated together within a series of map-scale imbricate slices of a postmetamorphic, dextral, transpressional, Alleghanian thrust duplex system that placed the high-grade eastern Blue Ridge allochthon atop the Talladega belt. Geochemical and geochronologic (U-Pb zircon) studies indicate that the Hillabee Greenstone's interstratified tholeiitic metabasalt and calc-alkaline metadacite/rhyolite formed within an extensional setting on continental crust ca. 460-470 Ma. Palinspastic reconstructions of the southern Appalachian Ordovician margin place the Hillabee Greenstone outboard of the present position of the Pine Mountain terrane and suggest links to Ordovician plutonism in the overlying eastern Blue Ridge, and possibly to widespread K-bentonite deposits within Ordovician platform units. The tectonic evolution of the Hillabee Greenstone exhibits many unusual and intriguing features, including: (1) premetamorphic emplacement along a basal cryptic thrust, which is remarkably concordant to both hanging wall and footwall sequences across its entire extent (>230 km), (2) formation, transport, and emplacement of the arc fragment accompanied by minimal deformation of the Hillabee Greenstone and underlying outer-margin shelf rocks, (3) emplacement temporally coincident with the adjacent collision of the younger, tectonically independent Ouachita volcanic arc with southeastern Laurentia. These features highlight strong contrasts in the Ordovician-Taconian evolution of the southern and northern parts of the Appalachian orogen. ?? 2007 Geological Society of America.

The structural evolution of the Ghadames and Illizi basins during the Paleozoic, Mesozoic and Cenozoic: Petroleum implications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gauthier, F.J.; Boudjema, A.; Lounis, R.

1995-08-01

The Ghadames and Illizi basins cover the majority of the eastern Sahara of Algeria. Geologicaly, this part of the Central Saharan platform has been influenced by a series of structural arches and {open_quotes}moles{close_quotes} (continental highs) which controlled sedimentation and structure through geologic time. These features, resulting from and having been affected by nine major tectonic phases ranging from pre-Cambrian to Tertiary, completely bound the Ghadames and Illizi Basins. During the Paleozoic both basins formed one continuous depositional entity with the Ghadames basin being the distal portion of the continental sag basin where facies and thickness variations are observed over largemore » distances. It is during the Mesozoic-Cenozoic that the Ghadames basin starts to evolve differently from the Illizi Basin. Eustatic low-stand periods resulted in continental deposition yielding the major petroleum-bearing reservoir horizons (Cambrian, Ordovician, Siluro-Devonian and Carboniferous). High-stand periods corresponds to the major marine transgressions covering the majority of the Saharan platform. These transgressions deposited the principal source rock intervals of the Silurian and Middle to Upper Devonian. The main reservoirs of the Mesozoic and Cenozoic are Triassic sandstone sequences which are covered by a thick evaporite succession forming a super-seal. Structurally, the principal phases affecting this sequence are the extensional events related to the breakup of Pangea and the Alpine compressional events. The Ghadames and Illizi basins, therefore, have been controlled by a polphase tectonic history influenced by Pan African brittle basement fracturing which resulted in complex structures localized along the major basin bounding trends as well as several subsidiary trends within the basin. These trends, as demonstrated with key seismic data, have been found to contain the majority of hydrocarbons trapped.« less

The impact of precession and obliquity on the Late-Devonian greenhouse climate

NASA Astrophysics Data System (ADS)

De Vleeschouwer, D.; Crucifix, M.; Bounceur, N.; Claeys, P. F.

2012-12-01

To date, only few general circulation model (GCM) have been used to simulate the extremely warm greenhouse climate of the Late-Devonian (~370 Ma). As a consequence, the current knowledge on Devonian climate dynamics comes almost exclusively from geological proxy data. Given the fragmentary nature of these data sources, the understanding of the Devonian climate is rather limited. Nonetheless, the Late-Devonian is a key-period in the evolution of life on Earth: the continents were no longer bare but were invaded by land plants, the first forests appeared, soils were formed, fish evolved to amphibians and 70-80% of all animal species were wiped out during the Late Devonian extinction (~376 Ma). In order to better understand the functioning of the climate system during this highly important period in Earth's history, we applied the HadSM3 climate model to the Devonian period under different astronomical configurations. This approach provides insight into the response of Late-Devonian climate to astronomical forcing due to precession and obliquity. Moreover, the assessment of the sensitivity of the Late-Devonian climate to astronomical forcing, presented here, will allow cyclostratigraphers to make better and more detailed interpretations of recurring patterns often observed in Late-Devonian sections. We simulated Late-Devonian climates by prescribing palaeogeography, vegetation distribution and pCO2 concentration (2180 ppm). Different experiments were carried out under 31 different astronomical configurations: three levels for obliquity (ɛ = 22°; 23.5° and 24.5°) and eccentricity (e = 0; 0.03 and 0.07) were chosen. For precession, 8 levels were considered (longitude of the perihelion= 0°; 45°; 90°; 135°; 180°; 235°; 270°). First results suggest that the intensity of precipitation on the tropical Euramerican continent (also known as Laurussia) is highly dependent on changes in precession: During precession maxima (= maximal insolation in SH during winter solstice), precipitation is up to 300 mm/month higher compared to precession minima during the wet season (September - May). During the dry season (June-July-August), the climate is up to 7°C colder during a precession maxima compared to a precession minima. Obliquity doesn't show a significant influence on the climate of the tropical Euramerican continent. However, the imprint of obliquity on the polar climates is extensive with up to 6°C temperature-differences between obliquity maxima and minima at both poles.

A late Devonian impact event and its association with a possible extinction event on Eastern Gondwana

NASA Technical Reports Server (NTRS)

Wang, K.; Geldsetzer, H. H. J.

1992-01-01

Evidence from South China and Western Australia for a 365-Ma impact event in the Lower crepida conodont zone of the Famennian stage of the Late Devonian (about 1.5 Ma after the Frasnian/Famennian extinction event) includes microtektitelike glassy microspherules, geochemical anomalies (including a weak Ir), a probable impact crater (greater than 70 k) at Taihu in South China, and an Ir anomaly in Western Australia. A brachiopod faunal turnover in South China, and the 'strangelove ocean'-like c-delta 13 excursions in both Chinese and Australian sections indicate that at least a regional-scale extinction might have occurred at the time of the impact. A paleoreconstruction shows that South China was very close to and facing Western Australia in the Late Devonian. The carbon isotopic excursions, which occur at the same stratigraphic level in both South China and Western Australia cannot be explained as being coincidental. The c-delta 13 excursions and the brachiopod faunal turnover in South China indicate that there might have been at least a regional (possibly global) extinction in the Lower crepida zone. The impact-derived microspherules and geochemical anomalies (especially the Ir) indicate a Lower crepida zone impact event on eastern Gondwana. The location, type of target rocks, and possibly age of the Taihu Lake crater qualify as the probable site of this Late Devonian impact.

Stratigraphic setting and mineralogy of the Arctic volcanogenic massive sulfide prospect, Ambler district, Alaska.

USGS Publications Warehouse

Schmidt, J.M.

1986-01-01

The Arctic prospect, south central Brooks Range, is among the 30 largest of 508 volcanic-hosted massive sulphide deposits in the world. The massive sulphide lenses are interlayered with graphitic schist between metamorphosed rhyolite porphyries in Middle Devonian to early Mississippian metamorphosed volcanic, volcaniclastic and sedimentary rocks. Hydrothermal alteration is of three types: chloritic, phyllic s.l., and pyrite-phengite, each type strata-distinctively and respectively below, in, and above the sulphides. Maximum alteration conforms with metal zoning in the sulfides to suggest predominantly northwestward dispersal from a linear vent area in the elongate basin containing the deposit.-G.J.N.

SEM/STEM observations of magnetite in carbonates of eastern North America: Evidence for chemical remagnettzation during the Alleghenian Orogeny

NASA Astrophysics Data System (ADS)

Suk, Dongwoo; Van der Voo, Rob; Peacor, Donald R.

Early to middle Paleozoic carbonates of eastern North America have been pervasively remagnetized. In order to determine the process of remagnetization, scanning and scanning transmission electron microscopy have been used to characterize magnetite in thin sections and in concentrated separates. Samples included Ordovician Knox carbonates from east Tennessee, Ordovician Trenton limestone and Devonian Onondaga and Helderberg limestones from New York, and Ordovician Trenton carbonates from Michigan. Inclusions of authigenic minerals within magnetite grains, lack of cations other than iron, and a variety of textural relations all imply that the magnetite is authigenic. These data are consistent with estimates that paleotemperatures never exceeded values that would reset magnetic directions. The remagnetization is thus a chemical remanent magnetization (CRM) rather than viscous remanent magnetization (VRM). As the timing of remagnetization corresponds to the Alleghenian orogeny, the observed relations imply stress-induced crystallization of magnetite that was mediated by fluids, consistent with but not requiring fluid flow on a regional basis.

Sea-level and environmental changes around the Devonian-Carboniferous boundary in the Namur-Dinant Basin (S Belgium, NE France): A multi-proxy stratigraphic analysis of carbonate ramp archives and its use in regional and interregional correlations

NASA Astrophysics Data System (ADS)

Kumpan, Tomáš; Bábek, Ondřej; Kalvoda, Jiří; Matys Grygar, Tomáš; Frýda, Jiří

2014-08-01

The paper focuses on high-resolution multidisciplinary research on three Devonian-Carboniferous boundary sections in shallow-water carbonate rocks in the Namur-Dinant Basin (Belgium, France). The aim of the study is to provide palaeo-environmental reconstructions and correlations supported by several independent quantitative proxies. We describe several correlative horizons and provide their sequence-stratigraphic interpretation based on facies analysis, spectral gamma-ray data, element concentrations (XRF) and δ13Ccarb, with foraminifer-biostratigraphy age control. The most prominent surface is a basal surface of forced regression, which is indicated by a sharp basinwards facies shift and a drop in clay-gamma-ray values and Al concentrations at the base of the Hastière and Avesnelles formations in more distal settings. In proximal settings, this surface merges with a hiatus at the Devonian-Carboniferous boundary inferred from foraminifer biostratigraphy. This hiatus can be correlated with the global Hangenberg sandstone event, which indicates a glacioeustatic sea-level fall. Increasing values of Zr/Al, K/Al, Sr/Al and Mn/Al coincide with the proximal facies of the falling stage system tract and lowstand system tract in the Hastière and Avesnelles formations as a consequence of the enhanced input of siliciclastics and nutrients during low sea levels. The top of the middle Hastière member is interpreted as the maximum regression surface, which is overlain by transgressive system tract of the upper Hastière member. The patterns of gamma-ray, δ13Ccarb, Th/K, Al and Zr/Al curves are well correlated between the studied sections. The δ13Ccarb excursions are correlated with the unnamed excursion in the Upper expansa conodont zone (Carnic Alps) and with the global Hangenberg event s.l. excursion in the kockeli conodont zone. This sequence-stratigraphic framework is used for correlations with deltaic successions from the Tafilalt Basin, Morocco. The basal surface of the forced regression equivalent to the Hangenberg sandstone event, which is typical for deeper-water settings, is easily recognisable and correlatable with gaps in more-shallow water settings. We suggest that it should be taken into account as a possible candidate for the “natural solution” of the Devonian-Carboniferous boundary in discussions concerning its redefinition.

Earth’s oldest ‘Bobbit worm’ – gigantism in a Devonian eunicidan polychaete

PubMed Central

Eriksson, Mats E.; Parry, Luke A.; Rudkin, David M.

2017-01-01

Whilst the fossil record of polychaete worms extends to the early Cambrian, much data on this group derive from microfossils known as scolecodonts. These are sclerotized jaw elements, which generally range from 0.1–2 mm in size, and which, in contrast to the soft-body anatomy, have good preservation potential and a continuous fossil record. Here we describe a new eunicidan polychaete, Websteroprion armstrongi gen. et sp. nov., based primarily on monospecific bedding plane assemblages from the Lower-Middle Devonian Kwataboahegan Formation of Ontario, Canada. The specimens are preserved mainly as three-dimensional moulds in the calcareous host rock, with only parts of the original sclerotized jaw walls occasionally present. This new taxon has a unique morphology and is characterized by an unexpected combination of features seen in several different Palaeozoic polychaete families. Websteroprion armstrongi was a raptorial feeder and possessed the largest jaws recorded in polychaetes from the fossil record, with maxillae reaching over one centimetre in length. Total body length of the species is estimated to have reached over one metre, which is comparable to that of extant ‘giant eunicid’ species colloquially referred to as ‘Bobbit worms’. This demonstrates that polychaete gigantism was already a phenomenon in the Palaeozoic, some 400 million years ago. PMID:28220886

Geologic map of the White Hall quadrangle, Frederick County, Virginia, and Berkeley County, West Virginia

USGS Publications Warehouse

Doctor, Daniel H.; Orndorff, Randall C.; Parker, Ronald A.; Weary, David J.; Repetski, John E.

2010-01-01

The White Hall 7.5-minute quadrangle is located within the Valley and Ridge province of northern Virginia and the eastern panhandle of West Virginia. The quadrangle is one of several being mapped to investigate the geologic framework and groundwater resources of Frederick County, Va., as well as other areas in the northern Shenandoah Valley of Virginia and West Virginia. All exposed bedrock outcrops are clastic and carbonate strata of Paleozoic age ranging from Middle Cambrian to Late Devonian. Surficial materials include unconsolidated alluvium, colluvium, and terrace deposits of Quaternary age, and local paleo-terrace deposits possibly of Tertiary age. The quadrangle lies across the northeast plunge of the Great North Mountain anticlinorium and includes several other regional folds. The North Mountain fault zone cuts through the eastern part of the quadrangle; it is a series of thrust faults generally oriented northeast-southwest that separate the Silurian and Devonian clastic rocks from the Cambrian and Ordovician carbonate rocks and shales. Karst development in the quadrangle occurs in all of the carbonate rocks. Springs occur mainly near or on faults. Sinkholes occur within all of the carbonate rock units, especially where the rocks have undergone locally intensified deformation through folding, faulting, or some combination.

Paleozoic intrusive rocks from the Dunhuang tectonic belt, NW China: Constraints on the tectonic evolution of the southernmost Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Zhao, Yan; Sun, Yong; Diwu, Chunrong; Zhu, Tao; Ao, Wenhao; Zhang, Hong; Yan, Jianghao

2017-05-01

The Dunhuang tectonic belt (DTB) is of great importance for understanding the tectonic evolution of the southernmost Central Asian Orogenic Belt (CAOB). In this study, the temporal-spatial distribution, petrogenesis and tectonic setting of the Paleozoic representative intrusive rocks from the DTB were systematically investigated to discuss crustal evolution history and tectonic regime of the DTB during Paleozoic. Our results reveal that the Paleozoic magmatism within the DTB can be broadly divided into two distinct episodes of early Paleozoic and late Paleozoic. The early Paleozoic intrusive rocks, represented by a suite metaluminous-slight peraluminous and medium- to high-K calc-alkaline I-type granitoids crystallized at Silurian (ca. 430-410 Ma), are predominantly distributed along the northern part of the DTB. They were probably produced with mineral assemblage of eclogite or garnet + amphibole + rutile in the residue, and were derived from magma mixing source of depleted mantle materials with various proportions of Archean-Mesoproterozoic continental crust. The late Paleozoic intrusive rocks can be further subdivided into two stages of late Devonian stage (ca. 370-360 Ma) and middle Carboniferous stage (ca. 335-315 Ma). The former stage is predominated by metaluminous to slight peraluminous and low-K tholeiite to high-K calc-alkaline I-type granitic rocks distributed in the central part of the DTB. They were also generated with mineral assemblage of amphibolite- to eclogite-facies in the residue, and originated from magma source of depleted mantle materials mixed with different degrees of old continental crust. The later stage is represented by adakite and alkali-rich granite exposed in the southern part of the DTB. The alkali-rich granites studied in this paper were possibly produced with mineral assemblage of granulite-facies in the residue and were generated by partial melting of thickened lower continental crust. Zircon Hf isotopes and field distribution of those Paleozoic intrusive rocks reveal that both the Silurian and the late Devonian magmatic activities predominantly represent crustal growth processes in the DTB, accompanied by different degrees of reworking of pre-existing continental crust. However, the middle Carboniferous (ca. 335-315 Ma) magmatic activity reflects a crustal reworking process. The Silurian and late Devonian intrusive rocks were most likely formed in the arc-related subduction zones, whereas, the middle Carboniferous intrusive rocks were possibly formed in a transitional tectonic setting from compression to extension, representing the final stage of Paleozoic orogeny in the DTB. These Paleozoic magmatic rocks further suggest that the DTB has reactivated from a stable block to an orogen and undergone two episodes (the early Paleozoic and the late Paleozoic) of orogeny during Paleozoic. It represents a Paleozoic accretionary orogen of the southernmost margin of the CAOB between the Tarim Craton and North China Craton, and tectonically extends northward to the Beishan orogen and westward to the eastern South Tianshan Belt.

Devonian-Carboniferous boundary succession in Eastern Taurides, Turkey

NASA Astrophysics Data System (ADS)

Atakul-Özdemir, Ayşe; Altıner, Demir; Özkan-Altıner, Sevinç

2015-04-01

The succession covering the Devonian-Carboniferous boundary in Eastern Taurides comprises mainly limestones, shales and siltstones. The studied section starts at the base with bioturbated limestones alternating with shales and is followed upwards by platy limestones, and continues with the alternations of bioturbated and platy limestones. Towards the upper part of the succession the alternations of limestone, shales and siltstones reappear again and the top of the section is capped by quartz arenitic sandstone. The studied section spanning the Uppermost Devonian-Lower Carboniferous interval yields a not very abundant, but quite important assemblage of conodont taxa including species of Bispathodus, Polygnathus, Palmatolepis, Spathognathodus and Vogelgnathus. The uppermost Devonian part of the succession is characterized by the presence of Bispathodus costatus, Bispathodus aculeatus aculeatus, Polygnathus communis communis, Palmatolepis gracilis gracilis and Spathognathodus sp.. The Lower Carboniferous in the studied section is represented by the appearance of Polygnathus inornatus and Polygnathus communis communis. Based on the recovered conodont assemblages, Devonian-Carboniferous boundary in Eastern Turides has been determined by the appearance and disappearance of major conodont species.

Carbon and nitrogen isotopic analysis of coral-associated nitrogen in rugose corals of the Middle Devonian, implications for paleoecology and paleoceanography.

NASA Astrophysics Data System (ADS)

Hickey, A. N.; Junium, C. K.; Uveges, B. T.; Ivany, L. C.; Martindale, R. C.

2017-12-01

The Middle Devonian Appalachian Basin of Central New York hosts an extraordinary diversity of well-studied fossil invertebrates within the shallow marine sequences of the Givetian Age, Hamilton Group. Of particular interest are a series of aerially expansive coral beds with diverse assemblages of rugose corals. These well-preserved specimens provide an excellent opportunity to test the feasibility of δ15N and δ13C analyses in rugose corals in an effort to resolve outstanding issues regarding their paleoecology and ontogeny as well environmental dynamics within the Devonian Appalachian Basin. Here we present carbon and nitrogen isotope analyses of the rugose corals Heliophyllum and Siphonophrentis from the Joshua Coral Bed. Corals were cleaned of the host calcareous shale and sonicated sequentially in deionized water and methanol, and then oxidatively cleaned. Cleaned corals were sectioned into 0.5cm billets to obtain enough residual organic material for analysis. The organic content of the corals is low, but nanoEA allows for serial sampling of 5-10 samples per coral. Coral sections were decarbonated and the residual organic material is filtered and dried prior to analysis. Coral organic matter is analyzed in triplicate using nanoEA, which is a cryo-trapping, capillary focusing technique for δ15N and δ13C. The δ15N of organic matter extracted from rugose corals is, on average, enriched by 2-4‰ relative to the bulk nitrogen in the host rock. As well, the δ13C of organic carbon from the corals is 13C-enriched relative to the bulk rock, but to a lesser degree (no more than 1.5‰). Assuming that the bulk rock carbon and nitrogen are largely representative of the long-term primary production background, the modest enrichment is consistent with a trophic effect, and that rugose corals are likely planktivores. In an individual coral, δ15N ranges by 3-4‰ over its length, and when adjusted for trophic enrichment varies around the average δ15N of bulk sedimentary organic matter (+2.0‰). There is no apparent trajectory in the isotopic composition of organic matter, which suggests that over the sampled life history of the corals we cannot resolve any ontogenetic trends. Therefore, the variability in the δ15N of the coral organic matter likely reflects short-term variability in basinal conditions or changes in coral food supply.

Linking Fossil Fish Cyclicity and Paleoenvironmental Proxies in the mid-Devonian

NASA Astrophysics Data System (ADS)

Grogan, D.; Whiteside, J. H.; Trewin, N. H.; Johnson, J. E.

2009-12-01

The significant radiation of fishes throughout the Devonian, combined with the abundance of well-preserved fossil fish assemblages from this period, provides for a high-resolution record of prevalent fish taxa in the Orcadian basin of North Scotland. In addition to their ability to serve as a lake-level and lake-chemistry proxy, the waxing and waning of dominant fish taxa exhibit a pronounced cyclicity, suggesting they respond to broader climate rhythms. Recent studies of mid-Devonian lacustrine sedimentary sequences have quantitatively demonstrated the presence of Milankovitch cyclicity in geochemical and gamma ray proxy records. Spectral analysis of gamma ray data show a strong obliquity peak usually associated with ice-house conditions; this obliquity signal is unexpected as tropical latitudes in the mid-Devonian are traditionally thought to have been in a greenhouse climate. Geochemical data include the measurement of bulk carbon and nitrogen stable isotopes, molecule-specific carbon isotopes of plant biomarkers, and depth ranks from eight sections of the Caithness Flagstone Group of the Orcadian Basin. Evidence for orbital forcing of climate change paired with the fossil fish record provides a unique opportunity to establish an astronomically calibrated timescale for the mid-Devonian, as well as to make a quantitative assessment of the validity of a greenhouse climate existing in the mid-Devonian.

Basin-mountain structures and hydrocarbon exploration potential of west Junggar orogen in China

NASA Astrophysics Data System (ADS)

Wu, Xiaozhi; He, Dengfa; Qi, Xuefeng

2016-04-01

Situated in northern Xinjiang, China, in NE-SW trend, West Junggar Orogen is adjacent to Altai fold belt on the north with the Ertix Fault as the boundary, North Tianshan fold belt on the south with the Ebinur Lake Strike-slip Fault as the boundary, and the Junggar Basin on the southeast with Zaire-Genghis Khan-Hala'alat fold belt as the boundary. Covering an area of about 10×104 km2 in China, there are medium and small intermontane basins, Burqin-Fuhai, Tacheng, Hefeng and Hoxtolgay, distributing inside the orogen. Tectonically West Junggar Orogen lies in the middle section of the Palaeo-Asian tectonic domain where the Siberia, Kazakhstan and Tarim Plates converge, and is the only orogen trending NE-SW in the Palaeo-Asian tectonic domain. Since the Paleozoic, the orogen experienced pre-Permian plate tectonic evolution and post-Permian intra-plate basin evolution. Complex tectonic evolution and multi-stage structural superimposition not only give rise to long term controversial over the basin basement property but also complex basin-mountain coupling relations, structures and basin superimposition modes. According to analysis of several kinds of geological and geophysical data, the orogen was dominated by compressive folding and thrust napping from the Siberia plate in the north since the Late Paleozoic. Compressive stress weakened from north to south, corresponding to subdued vertical movement and enhanced horizontal movement of crustal surface from north to south, and finally faded in the overthrust-nappe belt at the northwest margin of the Junggar Basin. The variation in compressive stress is consistent with the surface relief of the orogen, which is high in the north and low in the south. There are two kinds of basin-mountain coupling relationships, i.e. high angle thrusting and overthrusting and napping, and two kinds of basin superimposition modes, i.e. inherited and progressive, and migrating and convulsionary modes. West Junggar orogen has rich oil and gas shows, and oil and gas fields have also been discovered in the Zaysan Basin in adjacent Kazakhstan and in adjacent Junggar, Tuha and Santanghu Basins. Drilling data, geochemical analysis of outcrop data, and the disection of ancient Bulongguoer oil reservoir at the south margin of the Hefeng Basin show there developed two sets of good transitional source rocks, the lower Hujierste Formation in the Middle Devonian (D2h1) and the Hebukehe Formation in the Upper Devonian and Lower Carboniferous (D3-C1h) in this area, which, 10 to 300 m thick, mainly distribute in the shoal water zone along Tacheng-Ertai Late Paleozoic island arc belt. Reservoirs were mainly formed in the Jurassic and then adjusted in two periods, one from the end of the Jurassic to middle Cretaceous and the other in early Paleogene. Those early oil reservoirs might be destroyed in areas such as Bulongguoer with poor preservation conditions, but in an area with good geologic and preserving conditions, oil and gas might accumulate again to form new reservoirs. Therefore, a potential Middle Devonian-Lower Carboniferous petroleum system may exist in Tacheng-Ertai island arc belt, which may become a new domain for exploration, north faulted fold belt in the Heshituoluogai basin, and Hongyan fault bench zone in north Ulungur Depression in the Junggar Basin are promising areas for hydrocarbon exploration.

Collision of the Tacheng block with the Mayile-Barleik-Tangbale accretionary complex in Western Junggar, NW China: Implication for Early-Middle Paleozoic architecture of the western Altaids

NASA Astrophysics Data System (ADS)

Zhang, Ji'en; Xiao, Wenjiao; Luo, Jun; Chen, Yichao; Windley, Brian F.; Song, Dongfang; Han, Chunming; Safonova, Inna

2018-06-01

Western Junggar in NW China, located to the southeast of the Boshchekul-Chingiz (BC) Range and to the north of the Chu-Balkhash-Yili microcontinent (CBY), played a key role in the architectural development of the western Altaids. However, the mutual tectonic relationships have been poorly constrained. In this paper, we present detailed mapping, field structural geology, and geochemical data from the Barleik-Mayile-Tangbale Complex (BMTC) in Western Junggar. The Complex is divisible into Zones I, II and III, which are mainly composed of Cambrian-Silurian rocks. Zone I contains pillow lava, siliceous shale, chert, coral-bearing limestone, sandstone and purple mudstone. Zone II consists of basaltic lava, siliceous shale, chert, sandstone and mudstone. Zone III is characterized by basalt, chert, sandstone and mudstone. These rocks represent imbricated ocean plate stratigraphy, which have been either tectonically juxtaposed by thrusting or form a mélange with a block-in-matrix structure. All these relationships suggest that the BMTC is an Early-Middle Paleozoic accretionary complex in the eastern extension of the BC Range. These Early Paleozoic oceanic rocks were thrust onto Silurian sediments forming imbricate thrust stacks that are unconformably overlain by Devonian limestone, conglomerate and sandstone containing fossils of brachiopoda, crinoidea, bryozoa, and plant stems and leaves. The tectonic vergence of overturned folds in cherts, drag-related curved cleavages and σ-type structures on the main thrust surface suggests top-to-the-NW transport. Moreover, the positive εNd(t) values of volcanic rocks from the Tacan-1 drill-core, and the positive εHf(t) values and post-Cambrian ages of detrital zircons from Silurian and Devonian strata to the south of the Tacheng block indicate that its basement is a depleted and juvenile lithosphere. And there was a radial outward transition from coral-bearing shallow marine (shelf) to deep ocean (pelagic) environments, and from OIB/E-MORB to N-MORB lava geochemistry away from the Tacheng block. Comparisons with published data suggest that these positive isotopic values, stratigraphic, structural and geochemical relationships can be best understood as an analogue of the relationships between the Ontong Java oceanic plateau and the Pacific oceanic crust. Therefore we propose that the basement of the Tacheng block was an Early Paleozoic oceanic plateau. The southern part of the Tacheng block was an accretionary complex and the northern part was an oceanic basin in the Early Paleozoic, the configuration of which is similar to that of the present Ontong Java oceanic plateau situated on the Pacific oceanic crust, and its accretion into the Solomon accretionary complex. The presence of Ordovician SSZ-type ophiolites, early Paleozoic blueschist and Silurian SSZ-type intrusions in the BMTC, and Early-Middle Paleozoic continental arc-related intrusive rocks in the northern margin of the CBY provide further corroboration of a former subduction zone between the southern West Junggar and the northern margin of the CBY. Furthermore, consideration of the fact that the Kokchetav-North Tianshan range was collaged to the southern margin of the CBY in the Ordovician-Devonian indicates that both ranges were amalgamated synchronously with the CBY constructing the Early-Middle Paleozoic architecture of western Altaids.

Root evolution at the base of the lycophyte clade: insights from an Early Devonian lycophyte

PubMed Central

Matsunaga, Kelly K. S.; Tomescu, Alexandru M. F.

2016-01-01

Background and Aims The evolution of complex rooting systems during the Devonian had significant impacts on global terrestrial ecosystems and the evolution of plant body plans. However, detailed understanding of the pathways of root evolution and the architecture of early rooting systems is currently lacking. We describe the architecture and resolve the structural homology of the rooting system of an Early Devonian basal lycophyte. Insights gained from these fossils are used to address lycophyte root evolution and homology. Methods Plant fossils are preserved as carbonaceous compressions at Cottonwood Canyon (Wyoming), in the Lochkovian–Pragian (∼411 Ma; Early Devonian) Beartooth Butte Formation. We analysed 177 rock specimens and documented morphology, cuticular anatomy and structural relationships, as well as stratigraphic position and taphonomic conditions. Key Results The rooting system of the Cottonwood Canyon lycophyte is composed of modified stems that bear fine, dichotomously branching lateral roots. These modified stems, referred to as root-bearing axes, are produced at branching points of the above-ground shoot system. Root-bearing axes preserved in growth position exhibit evidence of positive gravitropism, whereas the lateral roots extend horizontally. Consistent recurrence of these features in successive populations of the plant preserved in situ demonstrates that they represent constitutive structural traits and not opportunistic responses of a flexible developmental programme. Conclusions This is the oldest direct evidence for a rooting system preserved in growth position. These rooting systems, which can be traced to a parent plant, include some of the earliest roots known to date and demonstrate that substantial plant–substrate interactions were under way by Early Devonian time. The morphological relationships between stems, root-bearing axes and roots corroborate evidence that positive gravitropism and root identity were evolutionarily uncoupled in lycophytes, and challenge the hypothesis that roots evolved from branches of the above-ground axial system, suggesting instead that lycophyte roots arose as a novel organ. PMID:26921730

Contrasting tectonothermal domains and faulting in the Potomac terrane, Virginia-Maryland - Discrimination by 40Ar/39Ar and fission-track thermochronology

USGS Publications Warehouse

Kunk, Michael J.; Wintsch, R.P.; Naeser, C.W.; Naeser, N.D.; Southworth, C.S.; Drake, Avery A.; Becker, J.L.

2005-01-01

New 40Ar/39Ar data reveal ages and thermal discontinuities that identify mapped and unmapped fault boundaries in the Potomac terrane in northern Virginia, thus confirming previous interpretations that it is a composite terrane. The rocks of the Potomac terrane were examined along the Potomac River, where it has been previously subdivided into three units: the Mather Gorge, Sykesville, and Laurel Formations. In the Mather Gorge Formation, at least two metamorphic thermal domains were identified, the Blockhouse Point and Bear Island domains, separated by a fault active in the late Devonian. Early Ordovician (ca. 475 Ma) cooling ages of amphibole in the Bear Island domain reflect cooling from Taconic metamorphism, whereas the Blockhouse Point domain was first metamorphosed in the Devonian. The 40Ar/39Ar data from muscovites in a third (eastern) domain within the Mather Gorge Formation, the Stubblefield Falls domain, record thrusting of the Sykesville Formation over the Mather Gorge Formation on the Plummers Island fault in the Devonian. The existence of two distinctly different thermal domains separated by a tectonic boundary within the Mather Gorge argues against its status as a formation. Hornblende cooling ages in the Sykesville Formation are Early Devonian (ca. 400 Ma), reflecting cooling from Taconic and Acadian metamorphism. The ages of retrograde and overprinting muscovite in phyllonites from domain-bounding faults are late Devonian (Acadian) and late Pennsylvanian (Alleghanian), marking the time of assembly of these domains and subsequent movement on the Plummers Island fault. Our data indicate that net vertical motion between the Bear Island domain of the Mather Gorge complex and the Sykesville Formation across the Plummers Island fault is east-side-up. Zircon fission-track cooling ages demonstrate thermal equillbrium across the Potomac terrane in the early Permian, and apatite fission-track cooling ages record tilting of the Potomac terrane in the Cretaceous or later with the west side up at least 1 km. ?? 2005 Geological Society of America.

A newly discovered K-bentonite zone in the Lower Devonian of the Appalachian Basin; Basal Esopus and Needmore Formations (Late Pragian-Emsian)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ver Straeten, C.A.

1992-01-01

The K-bentonite-rich interval of the Esopus Formation (eastern New York and northeastern Pennsylvania) overlies the coeval Oriskany/Glenerie/Ridgely Formations and ranges from 1 to 6.3 m in thickness. Six to seventeen soapy-feeling, yellow, tan, green, or gray clay to claystone beds (0.001 to 0.5 m-thick) interbedded with thin siltstone and chert beds (0.02--1 m-thick) characterize outcrops in eastern New York. Heavy mineral separates from these layers yield abundant uncorraded euhedral zircons and apatites, indicating that these are K-bentonites. In eastern Pennsylvania, the westernmost outcrop of the Esopus Formation displays a 2.3 m-thick massive, soapy-feeling clay to claystone-dominated interval. The presence ofmore » both coarse, highly abraded and small, fragile, pristine-appearing zircons and apatites from a 20 cm sampled interval may indicate a complex amalgamation/reworking history to the relatively thick, clay-dominated strata. Similar clay/claystone-rich strata have been found in the lower 0.15 to 1 m of the Beaverdam Member (Needmore Formation) in central Pennsylvania. Interbedded clays and claystones with or without minor siltstone beds characterize some outcrops. Other localities are clay-dominated, with minor amounts of quartz sand present in strata immediately overlying the Ridgely Sandstone. These newly discovered K-bentonite-rich strata mark a transition from shelfal orthoquartzites and carbonates to basinal black/dark gray shales similar to the overlying Middle Devonian Tioga ash interval. Deposition of ash-rich strata, associated with increased volcanic activity, coincided with subsidence of the foreland basin/relative sea level rise. These events were concurrent with a flush of siliciclastic sediments into the basin and are indicative of the onset of an early tectophase of the Devonian Acadian Orogeny.« less

Carbonate rocks of the Seward Peninsula, Alaska: Their correlation and paleogeographic significance

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Alta; Repetski, John E.

2014-01-01

Paleozoic carbonate strata deposited in shallow platform to off-platform settings occur across the Seward Peninsula and range from unmetamorphosed Ordovician–Devonian(?) rocks of the York succession in the west to highly deformed and metamorphosed Cambrian–Devonian units of the Nome Complex in the east. Faunal and lithologic correlations indicate that early Paleozoic strata in the two areas formed as part of a single carbonate platform. The York succession makes up part of the York terrane and consists of Ordovician, lesser Silurian, and limited, possibly Devonian rocks. Shallow-water facies predominate, but subordinate graptolitic shale and calcareous turbidites accumulated in deeper water, intraplatform basin environments, chiefly during the Middle Ordovician. Lower Ordovician strata are mainly lime mudstone and peloid-intraclast grainstone deposited in a deepening upward regime; noncarbonate detritus is abundant in lower parts of the section. Upper Ordovician and Silurian rocks include carbonate mudstone, skeletal wackestone, and coral-stromatoporoid biostromes that are commonly dolomitic and accumulated in warm, shallow to very shallow settings with locally restricted circulation. The rest of the York terrane is mainly Ordovician and older, variously deformed and metamorphosed carbonate and siliciclastic rocks intruded by early Cambrian (and younger?) metagabbros. Older (Neoproterozoic–Cambrian) parts of these units are chiefly turbidites and may have been basement for the carbonate platform facies of the York succession; younger, shallow- and deep-water strata likely represent previously unrecognized parts of the York succession and its offshore equivalents. Intensely deformed and altered Mississippian carbonate strata crop out in a small area at the western edge of the terrane. Metacarbonate rocks form all or part of several units within the blueschist- and greenschist-facies Nome Complex. The Layered sequence includes mafic meta¬igneous rocks and associated calcareous metaturbidites of Ordovician age as well as shallow-water Silurian dolostones. Scattered metacarbonate rocks are chiefly Cambrian, Ordovician, Silurian, and Devonian dolostones that formed in shallow, warm-water settings with locally restricted circulation and marbles of less constrained Paleozoic age. Carbonate metaturbidites occur on the northeast and southeast coasts and yield mainly Silurian and lesser Ordovician and Devonian conodonts; the northern succession also includes debris flows with meter-scale clasts and an argillite interval with Late Ordovician graptolites and lenses of radiolarian chert. Mafic igneous rocks at least partly of Early Devonian age are common in the southern succession. Carbonate rocks on Seward Peninsula experienced a range of deformational and thermal histories equivalent to those documented in the Brooks Range. Conodont color alteration indices (CAIs) from Seward Peninsula, like those from the Brooks Range, define distinct thermal provinces that likely reflect structural burial. Penetratively deformed high-pressure metamorphic rocks of the Nome Complex (CAIs ≥5) correspond to rocks of the Schist belt in the southern Brooks Range; both record subduction during early stages of the Jurassic–Cretaceous Brooks Range orogeny. Weakly metamorphosed to unmetamorphosed strata of the York terrane (CAIs mainly 2–5), like Brooks Range rocks in the Central belt and structural allochthons to the north, experienced moderate to shallow burial during the main phase of the Brooks Range orogeny. The nature of the contact between the York terrane and the Nome Complex is uncertain; it may be a thrust fault, an extensional surface, or a thrust fault later reactivated as an extensional fault. Lithofacies and biofacies data indicate that, in spite of their divergent Mesozoic histories, rocks of the York terrane and protoliths of the Nome Complex formed as part of the same lower Paleozoic carbonate platform. Stratigraphies in both

Geologic Map of the Weaverville 15' Quadrangle, Trinity County, California

USGS Publications Warehouse

Irwin, William P.

2009-01-01

The Weaverville 15' quadrangle spans parts of five generally north-northwest-trending accreted terranes. From east to west, these are the Eastern Klamath, Central Metamorphic, North Fork, Eastern Hayfork, and Western Hayfork terranes. The Eastern Klamath terrane was thrust westward over the Central Metamorphic terrane during early Paleozoic (Devonian?) time and, in Early Cretaceous time (approx. 136 Ma), was intruded along its length by the massive Shasta Bally batholith. Remnants of overlap assemblages of the Early Cretaceous (Hauterivian) Great Valley sequence and the Tertiary Weaverville Formation cover nearly 10 percent of the quadrangle. The base of the Eastern Klamath terrane in the Weaverville quadrangle is a peridotite-gabbro complex that probably is correlative to the Trinity ophiolite (Ordovician), which is widely exposed farther north beyond the quadrangle. In the northeast part of the Weaverville quadrangle, the peridotite-gabbro complex is overlain by the Devonian Copley Greenstone and the Mississippian Bragdon Formation. Where these formations were intruded by the Shasta Bally batholith, they formed an aureole of gneissic and other metamorphic rocks around the batholith. Westward thrusting of the Eastern Klamath terrane over an adjacent body of mafic volcanic and overlying quartzose sedimentary rocks during Devonian time formed the Salmon Hornblende Schist and the Abrams Mica Schist of the Central Metamorphic terrane. Substantial beds of limestone in the quartzose sedimentary unit, generally found near the underlying volcanic rock, are too metamorphosed for fossils to have survived. Rb-Sr analysis of the Abrams Mica Schist indicates a metamorphic age of approx. 380 Ma. West of Weavervillle, the Oregon Mountain outlier of the Eastern Klamath terrane consists mainly of Bragdon Formation(?) and is largely separated from the underlying Central Metamorphic terrane by serpentinized peridotite that may be a remnant of the Trinity ophiolite. The North Fork terrane is faulted against the west edge of the Central Metamorphic terrane, and its northerly trend is disrupted by major left-lateral offsets along generally west-northwest-trending faults. The serpentinized peridotite-gabbro complex that forms the western base of the terrane is the Permian North Fork ophiolite, which to the east is overlain by broken formation of mafic-volcanic rocks, red chert, siliceous tuff, argillite, minor limestone, and clastic sedimentary rocks. The chert and siliceous tuff contain radiolarians of Permian and Mesozoic ages, and some are as young as Early Jurassic (Pliensbachian). Similar Pliensbachian radiolarians are found in Franciscan rocks of the Coast Ranges. The Eastern Hayfork terrane is broken formation and melange of mainly chert, sandstone, argillite, and various exotic blocks. The cherts yield radiolarians of Permian and Triassic ages but none of clearly Jurassic age. Limestone bodies of the Eastern Hayfork terrane contain Permian microfaunas of Tethyan affinity. The Western Hayfork terrane, exposed only in a small area in the southwestern part of the quadrangle, consists dominantly of mafic tuff and dark slaty argillite. Sparse paleontologic data indicate a Mesozoic age for the strata. The terrane includes small bodies of diorite that are related to the nearby Wildwood pluton of Middle Jurassic age and probably are related genetically to the stratified rocks. The terrane is interpreted to be the accreted remnants of a Middle Jurassic volcanic arc. Shortly after intrusion by Shasta Bally batholith (approx. 136 Ma), much of the southern half of the Weaverville quadrangle was overlapped by Lower Cretaceous, dominantly Hauterivian, marine strata of the Great Valley sequence, and to a lesser extent later during Oligocene and (or) Miocene time by fluvial and lacustrine deposits of the Weaverville Formation. This map of the Weaverville Quadrangle is a digital rendition of U.S. Geological Survey Miscellaneous Field

Silurian pinnacle reefs of the Canadian Arctic

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Freitas, T.A.; Dixon, O.A.; Mayr, U.

1993-04-01

Pinnacle reefs are commonly an attractive target for oil exploration because they are usually porous carbonate bodies entombed in impervious, deep-water shales that provide both the source and the seal for hydrocarbons. Silurian pinnacle reefs, the first described in the Canadian Arctic Archipelago, are exposed on Ellesmere and Devon Islands. Two main reef trends occur, one of early middle Llandovery to middle Ludlow age and a second of middle Ludlow to Late Silurian or Early Devonian age. Reefs of both phases contain lime mudstone cores: some are stromatactoid-rich and others consist predominantly of microbialite-rich lime mudstone or microbial boundstone. Faciesmore » sequences of both reef phases show evidence of upward-shallowing overall, but, in the older reefs, isochronous capping facies are dominated either by coral-mirian or by stromatoporoid boundstone and floatstone. This difference perhaps reflects variation in wave stress and apparent ability of a few corals,thickly encrusted by or associated with microbial boundstone and skeletal algae, to withstand greater wave energy than a stromatoporoid-coral-rich reef community. These reefs constitute one of the bright prospects of hydrocarbon exploration in rocks of the Franklinian succession. 43 refs., 9 figs.« less

Study of hydrocarbon production from the Devonian shale in Letcher, Knott, Floyd, Martin, and Pike Counties, eastern Kentucky annual technical report, July 1, 1984-June 30, 1985

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frankie, W.T.

The Kentucky Geological Survey (KGS) at the University of Kentucky is conducting a 2-year research project funded by the Gas Research Institute (GRI) to study hydrocarbon production from the Devonian shale in eastern Kentucky. Objectives are to develop an understanding of relationships between stratigraphy and hydrocarbon production, create a data base, and prepare geologic reports for each county in the study area. Data were compiled from the KGS, GRI Eastern Gas Data System (EGDS), U. S. Department of Energy (DOE), and industry. Research for Letcher County was completed and 270 Devonian wells were entered into the KGS computer data base.more » Devonian black-shale units were correlated using gamma-ray logs. Structure and isopach maps, and stratigraphic cross sections have been constructed. An isopotential map defining areas of equal initial gas production has been prepared. Statistics for Letcher County have been run on the data base using Datatrieve software package. Statistical analyses focused on different types of formation treatments and the resulting production. Temperature logs were used to detect gas-producing intervals within the Mississippian-Devonian black-shale sequence. The results of the research provide the petroleum industry with a valuable tool for gas exploration in the Devonian shales.« less

The Caspian megabasin: tectonics and evolution

NASA Astrophysics Data System (ADS)

Khain, V. E.; Bogdanov, N. A.

2003-04-01

The Caspian Sea occupies at longitudinally elongated depression, superimposed in the latest Miocene on different structural units, oriented in WNW-ESE direction and belonging to the southern edge of the East European Craton and to the Mediterranean mobile belt. The Caspian megabasin comprises three basins - Northern, Middle and Southern with different age of basement and sedimentary fill, structural style and recent tectonics. The evolution of the whole region could be followed from Neoproterozoic onwards. At that epoch, an oceanic basin-Prototethys appeared after the breakup of Rodinia between Baltica and Gondwana. Its volcano-sedimentary sequence outcrops in the Greater Caucasus and Dzirula massif in Transcaucasia. After the Baikalian (=Cadomian/Panafrican) orogeny the central and southern part of the region was cratonised and formed the northern rim of Gondwana, presumably separated from Baltica by a relic of Prototethys. In Ordovician two branches of the Paleotethys crossed the region - the northern passed through the Greater Caucasus, the southern through Talesh; they were separated by the Transcaucasian microcontinent. At the southern edge of Baltica the Donets-Karpinsky Ridge rift system was formed in mid-Devonian. The northern branch of the Paleotethys was severely deformed, intruded by granites and metamorphosed by the Hercynian orogeny; only a remnant marine basin persisted to the south of the orogen. It was deformed in its tour, along with the southern-Paleotethys branch by the Eocimmerian orogeny which also caused the final inversion of the Donets-Karpinsky rift system. After these events the Fore-Caucasus region became the young Scythian platform - part of the Eurasian continent. In the Early Jurassic rifting opened the Greater Caucasus basin, marginal in respect to the Neotethys, one of the main branch of which passed through the Lesser Caucasus and probably along the southern border of the Alborz Range, separating it from the Iranian microcontinent. A volcanic arc developed in the Middle Jurassic on the Transcaucasian microcontinent over a zone of subduction of the Tethyan crust. In the Latest Miocene, under the impulse of the Afro-Arabian plate moving north, orogeny began in the Greater and Lesser Caucasus and Alborz. At that time the South Caspian basin was definitely formed and filled in the Oligocene-Miocene by a thick clayey Maikop series. The Middle Caspian basin developed over the Terek-Caspian foredeep of the Greater Caucasus and the adjacent Scythian-Turanian platform. The North Caspian basin is much older and existed already in the Devonian and till the Early Permian was a deep-water basin, bordered in the south by carbonate platforms. In mid-Permian time it was the site of salt accumulation and later of shelf or paralic sedimentation. At the end of Miocene, the advance of the Arabian Plate toward the southern border of Eurasia led to the transversal uplift of the Caucasian isthmus and the separation of the Caspian megabasin from the Black Sea. In Early Pliocene the North and Middle Caspian became dry land, and the Volga river pursued its course toward thee South Caspian, which was filled by a thick sandy-clayey formation - main productive hydrocarbon reservoir of Azerbaijan and Turkmenistan. Clayey diapirs and mud volcanoes were formed there and the South Caspian microplate with oceanic type crust experienced subduction to the north under the Apsheron-Balkhan sill. This work was supported by RFBR (grants 99-05-64009 and 02-05-64392).

How Reducing was the Late Devonian Ocean? The Role of Extensive Expansion of Anoxia in Marine Biogeochemical Cycles of Redox Sensitive Metals.

NASA Astrophysics Data System (ADS)

Sahoo, S. K.; Jin, H.

2017-12-01

The evolution of Earth's biogeochemical cycles is intimately linked to the oxygenation of the oceans and atmosphere. The Late Devonian is no exception as its characterized with mass extinction and severe euxinia. Here we use concentrations of Molybdenum (Mo), Vanadium (V), Uranium (U) and Chromium (Cr) in organic rich black shales from the Lower Bakken Formation of the Williston Basin, to explore the relationship between extensive anoxia vs. euxinia and it's relation with massive release of oxygen in the ocean atmosphere system. XRF data from 4 core across the basin shows that modern ocean style Mo, U and Cr enrichments are observed throughout the Lower Bakken Formation, yet V is not enriched until later part of the formation. Given the coupling between redox-sensitive-trace element cycles and ocean redox, various models for Late Devonian ocean chemistry imply different effects on the biogeochemical cycling of major and trace nutrients. Here, we examine the differing redox behavior of molybdenum and vanadium under an extreme anoxia and relatively low extent of euxinia. The model suggests that Late Devonian was perhaps extensively anoxic- 40-50% compared to modern seafloor area, and a very little euxinia. Mo enrichments extend up to 500 p.p.m. throughout the section, representative of a modern reducing ocean. However, coeval low V enrichments only support towards anoxia, where anoxia is a source of V, and a sink for Mo. Our model suggests that the oceanic V reservoir is extremely sensitive to perturbations in the extent of anoxic condition, particularly during post glacial times.

Armorican provenance for the mélange deposits below the Lizard ophiolite (Cornwall, UK): evidence for Devonian obduction of Cadomian and Lower Palaeozoic crust onto the southern margin of Avalonia

NASA Astrophysics Data System (ADS)

Strachan, Rob A.; Linnemann, Ulf; Jeffries, Teresa; Drost, Kerstin; Ulrich, Jens

2014-07-01

Devonian sedimentary rocks of the Meneage Formation within the footwall of the Lizard ophiolite complex in SW England are thought to have been derived from erosion of the over-riding Armorican microplate during collision with Avalonia and the closure of the Rheic Ocean. We further test this hypothesis by comparison of their detrital zircon suites with those of autochthonous Armorican strata. Five samples analysed from SW England (Avalonia) and NW France (Armorica) have a bimodal U-Pb zircon age distribution dominated by late Neoproterozoic to middle Cambrian (c. 710-518 Ma) and Palaeoproterozoic (c. 1,800-2,200 Ma) groupings. Both can be linked with lithologies exposed within the Cadomian belt as well as the West African craton, which is characterized by major tectonothermal events at 2.0-2.4 Ga. The detrital zircon signature of Avalonia is distinct from that of Armorica in that there is a much larger proportion of Mesoproterozoic detritus. The common provenance of the samples is therefore consistent with: (a) derivation of the Meneage Formation mélange deposits from the Armorican plate during Rheic Ocean closure and obduction of the Lizard Complex and (b) previous correlation of quartzite blocks within the Meneage Formation with the Ordovician Grès Armoricain Formation of NW France.

Geochronology and geochemistry of late Paleozoic-early Mesozoic igneous rocks of the Erguna Massif, NE China: Implications for the early evolution of the Mongol-Okhotsk tectonic regime

NASA Astrophysics Data System (ADS)

Li, Yu; Xu, Wen-Liang; Wang, Feng; Tang, Jie; Zhao, Shuo; Guo, Peng

2017-08-01

We undertook geochemical and geochronological studies on late Paleozoic-early Mesozoic igneous rocks from the Erguna Massif with the aim of constraining the early evolution of the Mongol-Okhotsk tectonic regime. Zircon crystals from nine representative samples are euhedral-subhedral, display oscillatory growth zoning, and have Th/U values of 0.14-6.48, indicating a magmatic origin. U-Pb dating of zircon using SIMS and LA-ICP-MS indicates that these igneous rocks formed during the Late Devonian (∼365 Ma), late Carboniferous (∼303 Ma), late Permian (∼256 Ma), and Early-Middle Triassic (246-238 Ma). The Late Devonian rhyolites, together with coeval A-type granites, formed in an extensional environment related to the northwestwards subduction of the Heihe-Nenjiang oceanic plate. Their positive εHf(t) values (+8.4 to +14.4) and Hf two-stage model ages (TDM2 = 444-827 Ma) indicate they were derived from a newly accreted continental crustal source. The late Carboniferous granodiorites are geochemically similar to adakites, and their εHf(t) values (+10.4 to +12.3) and Hf two-stage model ages (TDM2 = 500-607 Ma) suggest they were sourced from thickened juvenile lower crustal material, this thickening may be related to the amalgamation of the Erguna-Xing'an and Songnen-Zhangguangcai Range massifs. Rocks of the late Permian to Middle Triassic suite comprise high-K calc-alkaline monzonites, quartz monzonites, granodiorites, and monzogranites. These rocks are relatively enriched in light rare earth elements and large ion lithophile elements, and depleted in heavy rare earth elements and high field strength elements. They were emplaced, together with coeval porphyry-type ore deposits, along an active continental margin where the Mongol-Okhotsk oceanic plate was subducting beneath the Erguna Massif.

Well-Production Data and Gas-Reservoir Heterogeneity -- Reserve Growth Applications

USGS Publications Warehouse

Dyman, Thaddeus S.; Schmoker, James W.

2003-01-01

Oil and gas well production parameters, including peakmonthly production (PMP), peak-consecutive-twelve month production (PYP), and cumulative production (CP), are tested as tools to quantify and understand the heterogeneity of reservoirs in fields where current monthly production is 10 percent or less of PMP. Variation coefficients, defined as VC= (F5-F95)/F50, where F5, F95, and F50 are the 5th, 95th, and 50th (median) fractiles of a probability distribution, are calculated for peak and cumulative production and examined with respect to internal consistency, type of production parameter, conventional versus unconventional accumulations, and reservoir depth. Well-production data for this study were compiled for 69 oil and gas fields in the Lower Pennsylvanian Morrow Formation of the Anadarko Basin, Oklahoma. Of these, 47 fields represent production from marine clastic facies. The Morrow data were supplemented by data from the Upper Cambrian and Lower Ordovician Arbuckle Group, Middle Ordovician Simpson Group, Middle Pennsylvanian Atoka Formation, and Silurian and Lower Devonian Hunton Group of the Anadarko Basin, one large gas field in Upper Cretaceous reservoirs of north-central Montana (Bowdoin field), and three areas of the Upper Devonian and Lower Mississippian Bakken Formation continuous-type (unconventional) oil accumulation in the Williston Basin, North Dakota and Montana. Production parameters (PMP, PYP, and CP) measure the net result of complex geologic, engineering, and economic processes. Our fundamental hypothesis is that well-production data provide information about subsurface heterogeneity in older fields that would be impossible to obtain using geologic techniques with smaller measurement scales such as petrographic, core, and well-log analysis. Results such as these indicate that quantitative measures of production rates and production volumes of wells, expressed as dimensionless variation coefficients, are potentially valuable tools for documenting reservoir heterogeneity in older fields for field redevelopment and risk analysis.

Environmental conditions as the cause of the great mass extinction of marine organisms in the Late Devonian

NASA Astrophysics Data System (ADS)

Barash, M. S.

2017-08-01

During the Late Devonian extinction, 70-82% of all marine species disappeared. The main causes of this mass extinction include tectonic activity, climate and sea-level fluctuations, volcanism, and the collision of the Earth with cosmic bodies (impact events). The major causes are considered to be volcanism accompanying formation of the Viluy traps and, probably, basaltic magmatism in the Southern Urals, alkaline magmatism within the East European platform, and volcanism in northern Iran and northern and southern China. Several large impact craters of Late Devonian age have been documented in different parts of the world. The available data indicate that this time period on the Earth was marked by two major sequences of events: terrestrial events that resulted in extensive volcanism and cosmic (or impact) events. They produced similar effects such as emissions of harmful chemical compounds and aerosols to cause greenhouse warming and the darkening of the atmosphere, which prevented photosynthesis and cause ocean stagnation and anoxia. This disrupted the food chain and reduced ecosystem productivity. As a result, all vital processes were disturbed and a large part of the marine biota became extinct.

Late Devonian shale deposition based on known and predicted occurrence of Foerstia in Michigan basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matthews, R.D.

The fossil Foerstia (Protosalvinia) marks a time zone within Late Devonian shale sequences in the eastern US. Its recent discovery in Michigan has led to more accurate correlations among the three large eastern basins. Subdivisions of the Devonian-Mississippi shale sequence in Michigan based on gamma-ray correlations reveal an idealized black shale geometry common to other eastern black shales, such as the Sunbury of Michigan and Ohio, the Clegg Creek of Indiana, the Dunkirk of Pennsylvania and New York, and the lower Huron of Ohio and West Virginia. In Michigan, Foerstia occurs at a stratigraphic position postulated to mark a majormore » change in depositional conditions and source areas. This position strengthens the physical and paleontologic evidence for a formal division of the Antrim. Isopach maps of the shale sequence above and below Foerstia show a relatively uniform and continuous black shale deposit (units 1A, 1B, and 1C) below Foerstia. This deposit is unlike the wedge of sediment found above Foerstia, which is composed of a western facies (Ellsworth) and an eastern facies (upper Antrim) that should be combined in a single stratigraphic unit conforming to Forgotson's concept of a format.« less

Fossil record of stem groups employed in evaluating the chronogram of insects (Arthropoda: Hexapoda)

PubMed Central

Wang, Yan-hui; Engel, Michael S.; Rafael, José A.; Wu, Hao-yang; Rédei, Dávid; Xie, Qiang; Wang, Gang; Liu, Xiao-guang; Bu, Wen-jun

2016-01-01

Insecta s. str. (=Ectognatha), comprise the largest and most diversified group of living organisms, accounting for roughly half of the biodiversity on Earth. Understanding insect relationships and the specific time intervals for their episodes of radiation and extinction are critical to any comprehensive perspective on evolutionary events. Although some deeper nodes have been resolved congruently, the complete evolution of insects has remained obscure due to the lack of direct fossil evidence. Besides, various evolutionary phases of insects and the corresponding driving forces of diversification remain to be recognized. In this study, a comprehensive sample of all insect orders was used to reconstruct their phylogenetic relationships and estimate deep divergences. The phylogenetic relationships of insect orders were congruently recovered by Bayesian inference and maximum likelihood analyses. A complete timescale of divergences based on an uncorrelated log-normal relaxed clock model was established among all lineages of winged insects. The inferred timescale for various nodes are congruent with major historical events including the increase of atmospheric oxygen in the Late Silurian and earliest Devonian, the radiation of vascular plants in the Devonian, and with the available fossil record of the stem groups to various insect lineages in the Devonian and Carboniferous. PMID:27958352

Tectonics of Antarctica

USGS Publications Warehouse

Hamilton, W.

1967-01-01

Antarctica consists of large and wholly continental east Antarctica and smaller west Antarctica which would form large and small islands, even after isostatic rebound, if its ice cap were melted. Most of east Antarctica is a Precambrian Shield, in much of which charnockites are characteristic. The high Transantarctic Mountains, along the Ross and Weddell Seas, largely follow a geosyncline of Upper Precambrian sedimentary rocks that were deformed, metamorphosed and intruded by granitic rocks during Late Cambrian or Early Ordovician time. The rocks of the orogen were peneplained, then covered by thin and mostly continental Devonian-Jurassic sediments, which were intruded by Jurassic diabase sheets and overlain by plateau-forming tholeiites. Late Cenozoic doming and block-faulting have raised the present high mountains. Northeastern Victoria Land, the end of the Transantarctic Mountains south of New Zealand, preserves part of a Middle Paleozoic orogen. Clastic strata laid unconformably upon the Lower Paleozoic plutonic complex were metamorphosed at low grade, highly deformed and intruded by Late Devonian or Early Carboniferous granodiorites. The overlying Triassic continental sedimentary rocks have been broadly folded and normal-faulted. Interior west Antarctica is composed of miogeosynclinal clastic and subordinate carbonate rocks which span the Paleozoic Era and which were deformed, metamorphosed at generally low grade, and intruded by granitic rocks during Early Mesozoic time and possibly during other times also. Patterns of orogenic belts, if systematic, cannot yet be defined; but fragmentation and rotation of crustal blocks by oroclinal folding and strike-slip faulting can be suggested. The Ellsworth Mountains, for example, consist of Cambrian-Permian metasedimentary rocks that strike northward toward the noncorrelative and latitudinally striking Mesozoic terrane of the Antarctic Peninsula in one direction and southward toward that of the Lower Paleozoic: terrane of the Transantarctic Mountains in the other; the three regions may be separated by great strike-slip faults. The Antarctic Peninsula in west Antarctica, south of South America, consists of metavolcanic and metasedimentary rocks intruded by Late Cretaceous quartz diorite. The pre-granitic rocks are of Jurassic and Early Cretaceous ages wherever they have been dated by fossils, although some crystalline complexes may be older. The S-shape of the peninsula may represent oroclinal bending within Cenozoic time as part of a motion system in which a narrow continental bridge between South America and Antarctica was deformed and ruptured. Perhaps this bridge lagged behind as the larger continental plates drifted into the Pacific Ocean Basin. ?? 1967.

Sedimentology, conodonts and ostracods of the Devonian - Carboniferous strata of the Anseremme railway bridge section, Dinant Basin, Belgium

USGS Publications Warehouse

Casier, J.-G.; Mamet, B.; Preat, A.; Sandberg, C.A.

2004-01-01

Seven major carbonate microfacies are defined in the Devonian - Carboniferous (D/C) strata (50 m) of the Anseremme railway bridge section, south of Dinant. They permit recognition of several levels encompassing the Etroeungt and Hastie??re formations. "Bathymetric" sequences range from open marine, below the storm wave base, to semi-restricted lagoon. This sequence records a shallowing-upward trend of the relative sea level, from environments below the storm wave base to strongly eroded supraticial pre-evaporitic environments. Faunal components (echinoderms, brachiopods...) indicate open-marine domain for the first six microfacies located within the dysphoticeuphotic zone in relatively shallow waters. The textures of the rocks (mudstones to rudstones) associated with lamination characteristics indicate the position of the storm (SWB) and the fair-weather (FWWB) wave bases. Microfacies seven suggests a semi-restricted platform with salinity fluctuations from hypersaline brines to brackish waters. Thus, the boundary of the Etroeungt/Hastie??re formations is marked by an abrupt drop in sea level. Carbonate micro-conglomerates recording an important erosive phase and a sedimentary hiatus. The environment is again open marine in the upper part of the Hastie??re Formation. Our conclusion is that the Anseremme section is not a reliable continuous succession for the study of the D/C boundary. This confirms the VAN STEENWINKEL (1988, 1993 hypothesis based on other arguments. Conodont faunas demonstrate that the Devonian sequence spans the five youngest conodont zones, but that two of these zones are not represented. The Epinette Formation is dated as the youngest part of the Middle expansa Zone. Thus, the boundary with the Late praesulcata Zone probably coincides with the sharp sedimentological change at the base of the Etroeungt Formation, which is interpreted to belong entirely to this zone. The disconformably overlying basal bed 159 of the Hastie??re Formation is dated as Late praesulcata Zone, with the Early and Middle praesulcata Zones unrepresented because of an hiatus or unconformity. Sparse conodont faunas suggest that only the two next-to-oldest Carboniferous duplicata and sandbergi Zones are represented in the higher part of the Hastie??re Formation. The oldest Carboniferous sulcata Zone and possibly part ofthe duplicata Zone are unrepresented because of an hiatus or unconformity above bed 159. Ostracods are abundant and diversified at most levels in the Anseremme railway bridge section and sixty taxa, the majority in open nomenclature, have been identified and nearly all of them are figured. The ostracod fauna is indicative of shallow-marine environments between fair-weather and storm wave bases in the Etroeungt Formation, and to shallower water conditions periodically subjected to minor salinity variations in the base of the Hastie??re Formation. The upper part of the Hastie??re Formation is marked by a sea-level rise associated with a moderate decrease of the oxygenation of bottom waters. The intra-Devonian hiatus at the Etroeungt-Hastie??re boundary shows no abnormal extinctions and no appearance of new taxa. Thus, the Hangenberg Event is not recognizable in the studied section. Neither the sedimentological analysis nor the palaeontological study of the Bocahut quarry in the Avesnois and of the Anseremme railway bridge section confirm the hypothesis of a highstand for the Hastie??re Formation.

Bedrock Geology and Asbestos Deposits of the Upper Missisquoi Valley and Vicinity, Vermont

USGS Publications Warehouse

Cady, Wallace Martin; Albee, Arden Leroy; Chidester, A.H.

1963-01-01

The upper Missisquoi Valley and vicinity as described in this report covers an area of about 250 square miles at the headwaters of the Missisquoi River in north-central Vermont. About 90 percent of the area is forested and the remainder is chiefly farm land. The topography reflects the geologic structure and varied resistance of the bedrock to erosion. Most of the area is on the east limb of the Green Mountain anticlinorium, which is the principal structural feature of Vermont. The bedrock is predominantly sedimentary and volcanic rock that has been regionally metamorphosed. It was intruded before metamorphism by mafic and ultramafic igneous rocks, and after metamorphism by felsic and mafic igneous rocks. The metamorphosed sedimentary and volcanic rocks range in age from Cambrian(?) to Middle Silurian, the intrusive igneous rocks from probably Late Ordovician to probably late Permian. Metamorphism and principal folding in the region occurred in Middle Devonian time. The metamorphosed sedimentary and volcanic rocks make up a section at least 25,000 feet thick and can be divided into nine formations. The Hazens Notch formation of Cambrian(?) and Early Cambrian age is characterized by carbonaceous schist. It is succeeded in western parts of the area by the Jay Peak formation of Early Cambrian age, which is chiefly a schist that is distinguished by the general absence of carbonaceous zones; in central parts of the area the Hazens Notch formation is followed by the Belvidere Mountain amphibolite, probably the youngest of the formations of Early Cambrian age. The Ottauquechee formation, composed of carbonaceous phyllite and quartzite, and phyllitic graywacke, is of Middle Cambrian age. The Stowe formation of Late Cambrian(?) and Early(?) Ordovician age overlies the Ottauquechee and is predominantly noncarbonaceous schist, though it also contains greenstone and carbonaceous schist and phyllite. The Umbrella Hill formation of Middle Ordovician age is characteristically a conglomerate in which the mineral chloritoid is common. The overlying Moretown formation, also of Middle Ordovician age, contains granulite and slate, also greenstone and amphibolite of the Coburn Hill volcanic member. The Shaw Mountain formation, made up of conglomerate, phyllite, and limestone, is the oldest Silurian unit. The Shaw Mountain formation is succeeded by the Northfield slate of Middle Silurian age. The igneous rocks of the region include various ultramafic plutonic rocks, such as dunite, peridotite, and serpentinite, probably of Late Ordovician age; sills and nearly concordant dikes of metagabbro of Late Ordovician age; biotite granite plutons or Middle or Late Devonian age, most notably on Eltey Mountain; and hypabyssallamprophyre, probably of late Permian age. Metamorphic zoning is shown by the distribution of rocks of the epidote-amphibolite facies and the greenschist facies in and near the Green Mountains, and near Coburn Hill and Eltey Mountain. Metasomatism related to regional metamorphism has produced porphyroblasts and quartz segregations in the sedimentary and volcanic rocks, and steatitization and carbonatization of serpentinite. Contact metamorphism has formed rocks of the epidote-amphibolite facies near granite plutons, and probably calc-silicate rock at the contacts of ultramafic plutons. The axial anticline of the Green Mountain anticlinorium and other anticlines and synclines to the east are the major longitudinal structural features of the area. These structures are complicated by transverse folds, particularly a syncline in the vicinity of Tillotson Peak. Early minor cross folds that are best developed in the Hazens Notch formation are believed to be genetically related to the transverse folds. The axial planes of the cross folds are folded about the axes of the later longitudinal folds of the Green Mountain anticlinorium. The longitudinal and transverse fold systems probably formed in the same episode of defor

Devonian of the Northern Rocky Mountains and plains

USGS Publications Warehouse

Sandberg, Charles A.; Mapel, William J.

1967-01-01

5. Undivided uppermost Devonian (Famennian, to V-VI) and lowermost Mississippian (Tournaisian, cuI-lower cuIIα) carbonaceous and clastic rocks deposited in six shallow basins interspersed among areas uplifted during the penecontemporaneous Antler orogeny.

Strontium isotopic study of subsurface brines from Illinois basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

hetherington, E.A.; Stueber, A.M.; Pushkar, P.

1986-05-01

The abundance of the radiogenic isotope /sup 87/Sr in a subsurface brine can be used as a tracer of brine origin, evolution, and diagenetic effects. The authors have determined the /sup 87/Sr//sup 86/Sr ratios of over 60 oil-field waters from the Illinois basin, where brine origin is perplexing because of the absence of any significant evaporite strata. Initially, they analyzed brines from 15 petroleum-producing sandstone and carbonate units; waters from Ordovician, Silurian, Devonian, and Mississippian strata have /sup 87/Sr//sup 86/Sr ratios in the range 0.7079-0.7108. All but those from the Ste. Genevieve Limestone (middle Mississippian) are more radiogenic in /supmore » 87/Sr//sup 86/Sr than seawater values for this interval of geologic time. The detrital source of the more radiogenic /sup 87/Sr may be the New Albany Shale group, considered to be a major petroleum source rock in the basin. The /sup 87/Sr//sup 86/Sr ratios of Ste. Genevieve brines apparently evolved without a contribution from fluid-shale interaction.« less

Thermal maturity of type II kerogen from the New Albany Shale assessed by13C CP/MAS NMR

USGS Publications Warehouse

Werner-Zwanziger, U.; Lis, G.; Mastalerz, Maria; Schimmelmann, A.

2005-01-01

Thermal maturity of oil and gas source rocks is typically quantified in terms of vitrinite reflectance, which is based on optical properties of terrestrial woody remains. This study evaluates 13C CP/MAS NMR parameters in kerogen (i.e., the insoluble fraction of organic matter in sediments and sedimentary rocks) as proxies for thermal maturity in marine-derived source rocks where terrestrially derived vitrinite is often absent or sparse. In a suite of samples from the New Albany Shale (Middle Devonian to the Early Mississippian, Illinois Basin) the abundance of aromatic carbon in kerogen determined by 13C CP/MAS NMR correlates linearly well with vitrinite reflectance. ?? 2004 Elsevier Inc. All rights reserved.

No geochemical evidence for an asteroidal impact at late Devonian mass extinction horizon

NASA Astrophysics Data System (ADS)

McGhee, G. R., Jr.; Gilmore, J. S.; Orth, C. J.; Olsen, E.

1984-04-01

Three sedimentary sequences in New York State (Dunkirk Beach, Walnut Creek Gorge, and Mills Mills) and one sedimentary sequence in Belgium (Sinsin), that cross the Devonian Frasnian-Famennian boundary, were examined for an iridium (Ir) anomaly to determine whether the biotic extinctions at the end of the Cretaceous could have been caused by an asteroidal impact. The sampling at three of the four areas was on 2-cm center points, and 15 to 20 g of sample were collected. The instrumental neutron activation method required 5 g samples, and consequently the distance between samples was less than 1 cm. Though the Devonian samples studied had a high probability of locating an Ir anomaly, none was found. The highest Ir values were between 0.2 and 2 percent of those reported for the marine and terrestrial Ir analyses at the Cretaceous-Tertiary boundary, and Devonian pyrite-rich sediments did not exhibit high Ir concentrations.

Root evolution at the base of the lycophyte clade: insights from an Early Devonian lycophyte.

PubMed

Matsunaga, Kelly K S; Tomescu, Alexandru M F

2016-04-01

The evolution of complex rooting systems during the Devonian had significant impacts on global terrestrial ecosystems and the evolution of plant body plans. However, detailed understanding of the pathways of root evolution and the architecture of early rooting systems is currently lacking. We describe the architecture and resolve the structural homology of the rooting system of an Early Devonian basal lycophyte. Insights gained from these fossils are used to address lycophyte root evolution and homology. Plant fossils are preserved as carbonaceous compressions at Cottonwood Canyon (Wyoming), in the Lochkovian-Pragian (∼411 Ma; Early Devonian) Beartooth Butte Formation. We analysed 177 rock specimens and documented morphology, cuticular anatomy and structural relationships, as well as stratigraphic position and taphonomic conditions. The rooting system of the Cottonwood Canyon lycophyte is composed of modified stems that bear fine, dichotomously branching lateral roots. These modified stems, referred to as root-bearing axes, are produced at branching points of the above-ground shoot system. Root-bearing axes preserved in growth position exhibit evidence of positive gravitropism, whereas the lateral roots extend horizontally. Consistent recurrence of these features in successive populations of the plant preserved in situ demonstrates that they represent constitutive structural traits and not opportunistic responses of a flexible developmental programme. This is the oldest direct evidence for a rooting system preserved in growth position. These rooting systems, which can be traced to a parent plant, include some of the earliest roots known to date and demonstrate that substantial plant-substrate interactions were under way by Early Devonian time. The morphological relationships between stems, root-bearing axes and roots corroborate evidence that positive gravitropism and root identity were evolutionarily uncoupled in lycophytes, and challenge the hypothesis that roots evolved from branches of the above-ground axial system, suggesting instead that lycophyte roots arose as a novel organ. © The Author 2016. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Detrital zircon ages in Korean mid-Paleozoic meta-sandstones (Imjingang Belt and Taean Formation): Constraints on tectonic and depositional setting, source regions and possible affinity with Chinese terranes

NASA Astrophysics Data System (ADS)

Han, Seokyoung; de Jong, Koen; Yi, Keewook

2017-08-01

Sensitive High-Resolution Ion Microprobe (SHRIMP) U-Th-Pb isotopic data of detrital zircons from mature, quartz-rich meta-sandstones are used to constrain possible tectonic affinities and source regions of the rhythmically layered and graded-bedded series in the Yeoncheon Complex (Imjingang Belt) and the correlative Taean Formation. These metamorphic marine turbidite sequences presently occur along the Paleoproterozoic (1.93-1.83 Ga) Gyeonggi Massif, central Korea's main high-grade metamorphic gneiss terrane. Yet, detrital zircons yielded highly similar multimodal age spectra with peaks that do not match the age repartition in these basement rocks, as late (1.9-1.8 Ga) and earliest (∼ 2.5 Ga) Paleoproterozoic detrital modes are subordinate but, in contrast, Paleozoic (440-425 Ma) and Neoproterozoic (980-920 Ma) spikes are prominent, yet the basement essentially lacks lithologies with such ages. The youngest concordant zircon ages in each sample are: 378, 394 and 423 Ma. The maturity of the meta-sandstones and the general roundness of zircons of magmatic signature, irrespective of their age, suggest that sediments underwent considerable transport from source to sink, and possibly important weathering and recycling, which may have filtered out irradiation-weakened metamorphic zircon grains. In combination with these isotopic data, presence of a low-angle ductile fault contact between the Yeoncheon Complex and the Taean Formation and the underlying mylonitized Precambrian basement implies that they are in tectonic contact and do not have a stratigraphic relationship, as often assumed. Consequently, in all likelihood, both meta-sedimentary formations: (1) are at least of early Late Devonian age, (2) received much of their detritus from distant (reworked) Silurian-Devonian and Early Neoproterozoic magmatic sources, not present in the Gyeonggi Massif, (3) and not from Paleoproterozoic crystalline rocks of this massif, or other Korean Precambrian basement terranes, and (4) should be viewed as independent tectonic units that had sources not exposed in Korea. A thorough literature review reveals that the Yeoncheon Complex and the Taean Formation were potentially sourced from the Liuling, Nanwan and Foziling groups in the Qinling-Dabie Belt, which all show very similar detrital zircon age spectra. These immature middle-late Devonian sandstones were deposited in a pro-foreland basin formed as a result of the aborted subduction of the South Qinling Terrane below the North Qinling Terrane, which was uplifted and eroded during post-collision isostatic rebound. The submarine fans where the mature distal turbiditic Yeoncheon and Taean sandstones were deposited may have constituted the eastern terminal part of a routing system originating in the uplifted and eroded middle Paleozoic Qinling Belt and adjacent part of the foreland basin.

The anatomy of a major late-stage thrust and implications for models of late-stage collisional orogenesis in the Caledonian crust of northern Scandinavia

NASA Astrophysics Data System (ADS)

Anderson, Mark; Hames, Willis; Stokes, Alison

2010-05-01

Within the stack of Caledonian crystalline thrust sheets of northern Scandinavia, a single amphibolite facies lithotectonic unit, the Småtinden nappe, is identified as a major, basement-coupled ("stretching") shear zone. This dominantly pelitic unit achieved peak metamorphic conditions of 535-550°C and 8-9kbars, and the stretching geometry suggests that this most likely occurred in response to overthrusting of a hot, pre-assembled Caledonian thrust stack. Along-strike variations in microstructural geometries and patterns of mineral zoning in widely developed porphyroblast phases suggest, however, subsequent strain partitioning within the zone during late-stage decoupling of the thrust stack from the basement along major out-of-sequence thrusts. Large parts of the nappe are characterised by relatively late, static growth preserving concordant Si-Se relationships, and typically symmetrical external fabrics consistent with formation under dominantly pure shear conditions. In the Salangen area, however, the nappe is characterised by early garnet growth, with discordant Si-Se relationships and asymmetric external fabric geometries consistent with formation during ESE-directed simple shear. Remarkably consistent thermometric estimates from chlorites in both regimes (post- and syn-shearing) suggest that out-of-sequence ramping occurred at temperatures in the range 370-400 ̊C, within the typical range of blocking temperatures for argon retention in muscovite. 40Ar-39Ar dating of muscovites from S-C fabrics in the out-of-sequence shear zone suggest that late-stage thrusting occurred during the middle-late Devonian (ca. 395-375 Ma). Hanging-wall and footwall geometries coupled with these radiometric dates indicate that the development of these late thrusts closely relates to reactivation of pre-Caledonian Baltic basement during the Devonian (400-370 Ma). East-west contraction during the upper end of this time frame is peculiar considering that this was the period of large magnitude and rapid extension in western Norway.

Bimodal Silurian and Lower Devonian volcanic rock assemblages in the Machias-Eastport area, Maine

USGS Publications Warehouse

Gates, Olcott; Moench, R.H.

1981-01-01

Exposed in the Machias-Eastport area of southeastern Maine is the thickest (at least 8,000 m), best exposed, best dated, and most nearly complete succession of Silurian and Lower Devonian volcanic strata in the coastal volcanic belt, remnants of which crop out along the coasts of southern New Brunswick, Canada, and southeastern New England in the United States. The volcanics were erupted through the 600-700-million-year-old Avalonian sialic basement. To test the possibility that this volcanic belt was a magmatic arc above a subduction zone prior to presumed Acadian continental collision, samples representing the entire section in the Machias-Eastport area of Maine were chemically analyzed. Three strongly bimodal assemblages of volcanic rocks and associated intrusives are recognized, herein called the Silurian, older Devonian, and younger Devonian assemblages. The Silurian assemblage contains typically nonporphyritic high-alumina tholeiitic basalts, basaltic andesites, and diabase of continental characterand calc-alkalic rhyolites, silicic dacites, and one known dike of andesite. These rocks are associated with fossiliferous, predominantly marine strata of the Quoddy, Dennys, and Edmunds Formations, and the Leighton Formation of the Pembroke Group (the stratigraphic rank of both is revised herein for the Machias-Eastport area), all of Silurian age. The shallow marine Hersey Formation (stratigraphic rank also revised herein) of the Pembroke Group, of latest Silurian age (and possibly earliest Devonian, as suggested by an ostracode fauna), contains no known volcanics; and it evidently was deposited during a volcanic hiatus that immediately preceded emergence of the coastal volcanic belt and the eruption of the older Devonian assemblage. The older Devonian assemblage, in the lagoonal to subaerial Lower Devonian Eastport Formation, contains tholeiitic basalts and basaltic andesites, typically with abundant plagioclase phenocrysts and typically richer in iron and titanium and poorer in magnesium and nickel than the Silurian basalts; and the Eastport Formation has rhyolites and silicic dacites that have higher average SiO2 and K2O contents and higher ratios of FeO* to MgO than the Silurian ones. The younger Devonian assemblage is represented by one sample of basalt from a flow in red beds of the post-Acadian Upper Devonian Perry Formation, and by three samples from pre-Acadian diabases that intrude the Leighton and Hersey Formations. These rocks are even richer in titanium and iron and poorer in magnesium and nickel than the older Devonian basalts. Post-Acadian granitic plutons exposed along the coastal belt for which analyses are available are tentatively included in the younger Devonian assemblage. The most conspicuous features of the coastal volcanics and associated intrusives are the preponderance of rocks of basaltic composition ( < 52 percent SiO2 ) in the Silurian assemblage, and the near absence in all assemblages of intermediate rocks having 57-67 percent SiO2 (calculated without volatiles). All the rocks are variably altered spilites and keratophyres. The basaltic types are adequately defined, however, by eight samples of least altered basalts having calcic plagioclase, clinopyroxene, and 0.5 percent or less CO2 , The more altered basalts are variably enriched or depleted in Na2O, K2O, and CaO relative to the least altered ones. In the silicic rocks no primary ferromagnesian minerals are preserved. The Na2O and K2O contents of the silicic rocks are erratic; they are approximately reciprocal, possibly owing to alkali exchange while the rocks were still glassy. We propose that the coastal volcanic belt extended along an axis of thermal swelling in the Earth's mantle and upward intrusion of partially melted mantle into the sialic Avalonian crust. These processes were accompanied by shoaling and emergence of the belt, and they produced the bimodal volcanism. Tholeiitic basaltic melts segregated from mantle material

Bedrock geologic map of the Miles Pond and Concord quadrangles, Essex and Caledonia Counties, Vermont, and Grafton County, New Hampshire

USGS Publications Warehouse

Rankin, Douglas W.

2018-04-20

The bedrock geologic map of the Miles Pond and Concord quadrangles covers an area of approximately 107 square miles (276 square kilometers) in east-central Vermont and adjacent New Hampshire, north of and along the Connecticut River. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. The majority of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Silurian sedimentary, volcanic, and plutonic rocks. A major feature on the map is the Monroe fault, interpreted to be a west-directed, steeply dipping Late Devonian (Acadian) thrust fault. To the west of the Monroe fault, rocks of the Connecticut Valley-Gaspé trough dominate and consist primarily of metamorphosed Silurian and Devonian sedimentary rocks. To the north, the Victory pluton intrudes the Bronson Hill anticlinorium. The Bronson Hill anticlinorium consists of the metamorphosed Albee Formation, the Ammonoosuc Volcanics, the Comerford Intrusive Complex, the Highlandcroft Granodiorite, and the Joselin Turn tonalite. The Albee Formation is an interlayered, feldspathic metasandstone and pelite that is locally sulfidic. Much of the deformed metasandstone is tectonically pinstriped. In places, one can see compositional layering that was transposed by a steeply southeast-dipping foliation. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of siltstone, phyllite, graywacke, and grit. The Comerford Intrusive Complex crops out east of the Monroe fault and consists of metamorphosed gabbro, diorite, tonalite, aplitic tonalite, and crosscutting diabase dikes. Abundant mafic dikes from the Comerford Intrusive Complex intruded the Albee Formation and Ammonoosuc Volcanics east of the Monroe fault. The Highlandcroft Granodiorite and Joslin Turn tonalite plutons intruded during the Middle to Late Ordovician.West of the Monroe fault, the Connecticut Valley-Gaspé trough consists of the Silurian and Devonian Waits River and Gile Mountain Formations. The Waits River Formation is a carbonaceous muscovite-biotite-quartz (±garnet) phyllite containing abundant beds of micaceous quartz-rich limestone. The Gile Mountain Formation consists of interlayered metasandstone and graphitic (and commonly sulfidic) slate, along with minor calcareous metasandstone and ironstone. Graded bedding is common in the Gile Mountain Formation. Rocks of the Devonian New Hampshire Plutonic Suite intruded as plutons, dikes, and sills. The largest of these is the Victory pluton, which consists of weakly foliated, biotite granite and granodiorite. The Victory pluton also intruded a large part of the Albee Formation to the north.This report consists of a geologic map and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information. The geologic map is intended to serve as a foundation for applying geologic information to problems involving land use decisions, groundwater availability and quality, earth resources such as natural aggregate for construction, assessment of natural hazards, and engineering and environmental studies for waste disposal sites and construction projects.

Paleozoic and Lower Mesozoic magmas from the eastern Klamath Mountains (North California) and the geodynamic evolution of northwestern America

NASA Astrophysics Data System (ADS)

Lapierre, H.; Brouxel, M.; Albarede, F.; Coulin, C.; Lecuyer, C.; Martin, P.; Mascle, G.; Rouer, O.

1987-09-01

The Paleozoic to Early Mesozoic geology of the eastern Klamath Mountains (N California) is characterized by three major magmatic events of Ordovician, Late Ordovician to Early Devonian, and Permo-Triassic ages. The Ordovician event is represented by a calc-alkalic island-arc sequence (Lovers Leap Butte sequence) developed in the vicinity of a continental margin. The Late Ordovician to Early Devonian event consists of the 430-480 Ma old Trinity ophiolite formed during the early development of a marginal basin, and a series of low-K tholeiitic volcanic suites (Lovers Leap Basalt—Keratophyre unit, Copley and Balaklala Formations) belonging to intraoceanic island-arcs. Finally, the Permo-Triassic event gave rise to three successives phases of volcanic activity (Nosoni, Dekkas and Bully Hill) represented by the highly differentiated basalt-to-rhyolite low-K tholeiitic series of mature island-arcs. The Permo-Triassic sediments are indicative of shallow to moderate depth in an open, warm sea. The geodynamic evolution of the eastern Klamath Mountains during Paleozoic to Early Mesozoic times is therefore constrained by the geological, petrological and geochemical features of its island-arcs and related marginal basin. A consistent plate-tectonic model is proposed for the area, consisting of six main stages: (1) development during Ordovician times of a calc-alkalic island-arc in the vicinity of a continental margin; (2) extrusion during Late Ordovician to Silurian times of a primitive basalt-andesite intraoceanic island-arc suite, which terminated with boninites, the latter suggest rifting in the fore-arc, followed by the breakup of the arc; (3) opening and development of the Trinity back-arc basin around 430-480 Ma ago; (4) eruption of the Balaklala Rhyolite either in the arc or in the fore-arc, ending in Early Devonian time with intrusion of the 400 Ma Mule Mountain stock; (5) break in volcanic activity from the Early Devonian to the Early Permian; and (6) development of a mature island-arc from the Early Permian to the Late Triassic. The eastern Klamath Mountains island-arc formations and ophiolitic suite are part of the "Cordilleran suspect terranes", considered to be Gondwana margin fragments, that have undergone large northward translations before final collision with the North American craton during Late Mesozoic or Cenozoic times. These eastern Klamath Mountains island-arcs could be associated with the paleo-Pacific oceanic plate that led to accretion of these allochthonous terranes to the American margin.

Eastern Devonian shales: Organic geochemical studies, past and present

USGS Publications Warehouse

Breger, I.A.; Hatcher, P.G.; Romankiw, L.A.; Miknis, F.P.

1983-01-01

The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Ilinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of the fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales will be reviewed. Recent solid state 13C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a "coaly" nature and hence more prone to producing natural gas.

Eastern Devonian shales: Organic geochemical studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berger, I.A.; Hatchner, P.G.; Miknis, F.P.

The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Illinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of themore » fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales are reviewed. Recent solid state /sup 13/C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a ''coaly'' nature and hence more prone to producing natural gas.« less

Eastern Madre de Dios Devonian generated large volumes of oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Wagner, J.B.; Carpenter, D.G.

This is the second part of an article giving details of a Mobil Corp. regional geological, geophysical, and geochemical study of the Madre de Dios basin. The assessment covered the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks.

Reconnaissance geology of the Central Mastuj Valley, Chitral State, Pakistan

USGS Publications Warehouse

Stauffer, Karl W.

1975-01-01

The Mastuj Valley in Chitral State is a part of the Hindu Kush Range, and is one of the structurally most complicated areas in northern Pakistan. Sedimentary rocks ranging from at least Middle Devonian to Cretaceous, and perhaps Early Tertiary age lie between ridge-forming granodiorite intrusions and are cut by thrust faults. The thrust planes dip 10? to 40? to the north- west. Movement of the upper thrust plates has been toward the southeast relative to the lower blocks. If this area is structurally typical of the Hindu-Kush and Karakoram Ranges, then these mountains are much more tectonically disturbed than previously recorded, and suggest compression on a scale compatible with the hypothesis that the Himalayan, Karakoram, and Hindu Kush Ranges form part of a continental collision zone. The thrust faults outline two plates consisting of distinctive sedimentary rocks. The lower thrust plate is about 3,000 feet thick and consists of the isoclinally folded Upper Cretaceous to perhaps lower Tertiary Reshun Formation. It has overridden the Paleozoic metasedimentary rocks of the Chitral Slate unit. This thrust plate is, in turn, overridden by an 8,000-foot thick sequence consisting largely of Devonian to Carboniferous limestones and quartzites. A key factor in the tectonic processes has been the relatively soft and plastic lithology of the siltstone layers in the Reshun Formation which have acted as lubricants along the principal thrust faults, where they are commonly found today as fault slices and smears. The stratigraphic sequence, in the central Mastuj Valley was tentatively divided into 9 mapped units. The fossiliferous shales and carbonates of the recently defined Shogram Formation and the clastlcs of the Reshun Formation have been fitted into a sequence of sedimentary rocks that has a total thick- ness of at least 13,000 feet and ranges in age from Devonian to Neogene. Minerals of potential economic significance include antimony sulfides which have been mined elsewhere in Chitral, the tungstate, scheelite, which occurs in relatively high concentrations in heavy-mineral fractions of stream sands, and an iron-rich lateritic rock.

Homogenity of geological units with respect to the radon risk in the Walloon region of Belgium.

PubMed

Tondeur, François; Cinelli, Giorgia; Dehandschutter, Boris

2014-10-01

In the process of mapping indoor radon risk, an important step is to define geological units well-correlated with indoor radon. The present paper examines this question for the Walloon region of Belgium, using a database of more than 18,000 indoor radon measurements. With a few exceptions like the Carboniferous (to be divided into Tournaisian, Visean and Namurian-Westphalian) and the Tertiary (in which all Series may be treated together), the Series/Epoch stratigraphic level is found to be the most appropriate geological unit to classify the radon risk. A further division according to the geological massif or region is necessary to define units with a reasonable uniformity of the radon risk. In particular, Paleozoic series from Cambrian to Devonian show strong differences between different massifs. Local hot-spots are also observed in the Brabant massif. Finally, 35 geological units are defined according to their radon risk, 6 of which still present a clear weak homogeneity. In the case of 4 of these units (Jurassic, Middle Devonian of Condroz and of Fagne-Famenne, Ordovician of the Stavelot massif) homogeneity is moderate, but the data are strongly inhomogeneous for Visean in Condroz and in the Brabant massif. The 35 geological units are used in an ANOVA analysis, to evaluate the part of indoor radon variability which can be attributed to geology. The result (15.4-17.7%) agrees with the values observed in the UK. Copyright © 2014 The Authors. Published by Elsevier Ltd.. All rights reserved.

The major-ion composition of Carboniferous seawater

NASA Astrophysics Data System (ADS)

Holt, Nora M.; García-Veigas, Javier; Lowenstein, Tim K.; Giles, Peter S.; Williams-Stroud, Sherilyn

2014-06-01

The major-ion chemistry (Na+, Mg2+, Ca2+, K+, SO42-, and Cl-) of Carboniferous seawater was determined from chemical analyses of fluid inclusions in marine halites, using the cryo scanning electron microscopy (Cryo-SEM) X-ray energy-dispersive spectrometry (EDS) technique. Fluid inclusions in halite from the Mississippian Windsor and Mabou Groups, Shubenacadie Basin, Nova Scotia, Canada (Asbian and Pendleian Substages, 335.5-330 Ma), and from the Pennsylvanian Paradox Formation, Utah, USA, (Desmoinesian Stage 309-305 Ma) contain Na+-Mg2+-K+-Ca2+-Cl- brines, with no measurable SO42-, which shows that the Carboniferous ocean was a “CaCl2 sea”, relatively enriched in Ca2+ and low in SO42- with equivalents Ca2+ > SO42- + HCO3-. δ34S values from anhydrite in the Mississippian Shubenacadie Basin (13.2-14.0 ‰) and the Pennsylvanian Paradox Formation (11.2-12.6 ‰) support seawater sources. Br in halite from the Shubenacadie Basin (53-111 ppm) and the Paradox Basin (68-147 ppm) also indicate seawater parentages. Carboniferous seawater, modeled from fluid inclusions, contained ∼22 mmol Ca2+/kg H2O (Mississippian) and ∼24 mmol Ca2+/kg H2O (Pennsylvanian). Estimated sulfate concentrations are ∼14 mmol SO42-/kg H2O (Mississippian), and ∼12 mmol SO42-/kg H2O (Pennsylvanian). Calculated Mg2+/Ca2+ ratios are 2.5 (Mississippian) and 2.3 (Pennsylvanian), with an estimated range of 2.0-3.2. The fluid inclusion record of seawater chemistry shows a long period of CaCl2 seas in the Paleozoic, from the Early Cambrian through the Carboniferous, when seawater was enriched in Ca2+ and relatively depleted in SO42-. During this ∼200 Myr interval, Ca2+ decreased and SO42- increased, but did not cross the Ca2+-SO42- chemical divide to become a MgSO4 sea (when SO42- in seawater became greater than Ca2+) until the latest Pennsylvanian or earliest Permian (∼309-295 Ma). Seawater remained a MgSO4 sea during the Permian and Triassic, for ∼100 Myr. Fluid inclusions also record a long interval, from the Early Cambrian to the Middle Devonian, when seawater had low Mg2+/Ca2+ ratios (<2) that coincide with calcite seas. The Mg2+/Ca2+ ratio of seawater rose from 0.9 in the Middle Devonian, to 2.5 in the Middle/Late Mississippian, 2.3 in the Middle Pennsylvanian, and 3.5 in the Early Permian. The transition from calcite seas to aragonite seas, established from the mineralogy of oölites and early marine cements, occurred in the Late Mississippian. Fluid inclusions show that seawater Mg2+/Ca2+ ratios rose above 2 by the Middle to Late Mississippian coinciding exactly with the shift to aragonite seas. Aragonite seas existed for ∼100 Myr, from the Late Mississippian until the Late Triassic/Early Jurassic.

Timing of terrane accretion in eastern and east-central Maine

NASA Astrophysics Data System (ADS)

Ludman, Allan

1986-05-01

The Norumbega fault zone is often cited as a post-Acadian suture between exotic blocks, even though stratigraphic, structural, and metamorphic data indicate that there is little offset of the Silurian-Devonian strata that the zone cuts in eastern Maine. Similarly, the Kingman fault zone has been shown by gravity and geochemical studies to separate distinct crustal blocks, whereas mapping shows that it lies entirely within a Silurian turbidite package. These conflicts are resolved if the two fault zones represent boundaries between Ordovician or older crustal blocks that had accreted to form a composite terrane prior to deposition of the cover sequences. The faults now mapped within these younger rocks formed by reactivation of the pre-Silurian boundaries during late Acadian time; movement continued until the late Carboniferous. Most of the accretionary history of Maine had thus ended before the Silurian. A complex composite terrane may have formed during Cambrian-Ordovician time that (1) interacted with cratonic North America during the Taconian orogeny and (2) became the “basement” upon which the Silurian and Lower Devonian strata of eastern Maine were deposited.

Reconstructing multiple arc-basin systems in the Altai-Junggar area (NW China): Implications for the architecture and evolution of the western Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Di; He, Dengfa; Tang, Yong

2016-05-01

The Altai-Junggar area in northwestern China is a critical region to gain insights on the tectonic framework and geological evolution of the western Central Asian Orogenic Belt (CAOB). In this study, we report results from integrated geological, geochemical and geophysical investigations on the Wulungu Depression of the Junggar Basin to determine the basement nature of the basin and understand its amalgamation history with the Chinese Altai, within the broad tectonic evolution of the Altai-Junggar area. Based on borehole and seismic data, the Wulungu Depression is subdivided into two NW-trending tectonic units (Suosuoquan Sag and Hongyan High) by southward-vergent thrust faults. The Suosuoquan Sag consists of the Middle-Late Devonian basaltic andesite, andesite, dacite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava flows and shallow marine sediments from a proximal juvenile provenance (zircon εHf(t) = 6.0-14.9), compared to the Late Carboniferous andesite and rhyolite in the Hongyan High. Zircon SIMS U-Pb ages for dacites and andesites indicate that these volcanics in the Suosuoquan Sag and Hongyan High erupted at 376.3 Ma and 313.4 Ma, respectively. The Middle-Late Devonian basaltic andesites from well LC1 are calc-alkaline and exhibit primitive magma-like MgO contents (7.9-8.6%) and Mg# values (66-68), with low initial 87Sr/86Sr (0.703269-0.704808) and positive εNd(t) values (6.6-7.6), and relatively high Zr abundance (98.2-116.0 ppm) and Zr/Y ratios (5.1-5.4), enrichment in LREEs and LILEs (e.g., Th and U) and depletion in Nb, Ta and Ti, suggesting that they were probably derived from a metasomatized depleted mantle in a retro-arc extensional setting. The well LC1 andesitic tuffs, well L8 dacites, well WL1 dacitic tuffs and well L5 andesites belong to calc-alkaline and metaluminous to peraluminous (A/CNK = 0.8-1.7) series, and display low Mg# values (35-46) and variably positive εNd(t) (4.5-8.5) and εHf(t) (10.2-16.8) values, as well as young isotopic model ages. These Devonian-Carboniferous intermediate-felsic volcanics are interpreted as the products of partial melting of a juvenile lower crust with some contributions from mantle components in an evolved island arc setting from immature to mature island arc. The basin filling pattern and the distribution of arc volcanics and their zircon Hf model ages with the eruptive time suggest that the Wulungu Depression represents an island arc-basin system with the development of a Carboniferous retro-arc basin. In combination with previous work, we propose that the northern Junggar area comprises three arc-basin belts from south to north: the Darbut-Luliang-Karamaili, Wulungu-Yemaquan, and Saur-Fuhai-Dulate. Such tectonic subdivisions are consistent with the regional gravity and magnetic anomaly data. The recognition of the Wulungu arc-basin system demonstrates that the Junggar Basin is likely underlain by juvenile continental crust rather than ancient Precambrian basement, and also implies that the CAOB was built by amalgamation of multiple linear arcs and accretionary complexes.

A Remaining Open Paleogeography of Paleo-Asian Ocean by Early Permian, Paleomagnetic Constraints from Eastern CAOB

NASA Astrophysics Data System (ADS)

Zhang, Donghai; Huang, Baochun; Zhao, Jie; Meert, Joseph; Zhang, Ye; Liang, Yalun; Bai, Qianhui; Zhao, Qian; Zhou, Tinghong

2017-04-01

We carry out a combined paleomagnetic and U-Pb geochronologic study on Paleozoic strata ranging from Lower Devonian to Upper Permian in mid-eastern Inner Mongolia, NE China with the purpose of puzzling out the timing and location of the final closure of Paleo-Asian Ocean (PAO), and thus provides further implications for the evolution of eastern Central Asian Orogenic Belt (CAOB). Inside North Margin of North China Block (NMNCB), 20 sites from Middle Permian Elitu formation and 9 sites from Lower Permian Sanmianjing formation yields a high temperature Characteristic Remanent Magnetism (ChRM) of Dg=330.9, Ig=54.3, Kg=4.9, a95g=14.9 N= 24 before and Ds=347.4, Is=38.1, Ks=28.6, a95s=5.6, N=24 after tilt correction. 13 sites from Songliao-Xilinhot Block (SXB) isolate a ChRM of Dg=196.6, Ig=36.4, Kg=18.0, a95g=11.1, N=13; Ds=222.9, Is=20.5, Ks=15.7 a95s=11.9, N=13 with a positive fold test, which suggests a likely primary magnetization. Inside of Khingan-Airgin Sum Block (KAB), 2 different component is extracted from Lower Devonian Niqiuhe formation, Upper Carboniferous Baoligaomiao formation and Lower Permian Dashizhai formation. A high temperature Component A (Dg=28.3, Ig=29.7, Kg=24.4, a95g=6.6, N= 21; Ds=49.8, Is=62.1, Ks=57.4, a95s=4.2, N=21) with a synfolding origin is derived from 21 sites of Baoligaomiao formation in west KAB, which is traditionally named as Uliastai passive continental margin, whilst 11 sites from Lower Devonian Niqiuhe formation in east KAB generate a post-folding Component B (Dg=196.6, Ig=36.4, Kg=18.0, a95g=11.1, N=11; Ds=222.9, Is=20.5, Ks=15.7, a95s=11.9, N=11) with a possible remagnetization in early Permian suggested by widely exposed granitic intrusion of 299 Ma in adjacent areas. Accordingly, 4 paleomagnetic poles are calculated as early-middle Permian of NMNCB (Plat=67.9°N, Plong=326.7°E, A95=4.2°), early Permian of SXB (Plat=45.3°N, Plong=250.3°E, A95=5.8°), late Carboniferous of west KAB (Plat=55.1°N, Plong=187.8°E, A95=6.2°) and early Permian of (Plat=-16.3°N, Plong=109.1°E, A95=8.4°). The early Permian paleomagnetic pole of SXB and NMNCB are located at a common small circle centered around the reference site (43° N, 114° E), whilst late Carboniferous pole of west KAB and early Permian pole of east KAB share a similar paleolatitude, about 17.8° higher than that of SXB and NMNCB, with a huge 85° longitudinal difference in between. These data indicate the final closure of PAO happened at the northern Hegenshan-Heihe Suture Zone (HHSZ) after early Permian instead of the pre-assumed southern Solonker-Xar Moron Suture Zone (SXMSZ) with a remaining open paleogeography of Paleo-Asian Ocean between SXB and KAB by early Permian. Keywords: Paleo-Asian Ocean, Central Asian Orogenic Belt, Paleomagnetism, Paleolatitude, Late Paleozoic, XMOB.

Assessment of undiscovered continuous gas resources in Upper Devonian Shales of the Appalachian Basin Province, 2017

USGS Publications Warehouse

Enomoto, Catherine B.; Trippi, Michael H.; Higley, Debra K.; Rouse, William A.; Dulong, Frank T.; Klett, Timothy R.; Mercier, Tracey J.; Brownfield, Michael E.; Leathers-Miller, Heidi M.; Finn, Thomas M.; Marra, Kristen R.; Le, Phuong A.; Woodall, Cheryl A.; Schenk, Christopher J.

2018-04-19

Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable continuous resources of 10.7 trillion cubic feet of natural gas in Upper Devonian shales of the Appalachian Basin Province.

Causes of the great mass extinction of marine organisms in the Late Devonian

NASA Astrophysics Data System (ADS)

Barash, M. S.

2016-11-01

The second of the five great mass extinctions of the Phanerozoic occurred in the Late Devonian. The number of species decreased by 70-82%. Major crises occurred at the Frasnian-Famennian and Devonian-Carboniferous boundary. The lithological and geochemical compositions of sediments, volcanic deposits, impactites, carbon and oxygen isotope ratios, evidence of climate variability, and sea level changes reflect the processes that led the critical conditions. Critical intervals are marked by layers of black shales, which were deposited in euxinic or anoxic environments. These conditions were the main direct causes of the extinctions. The Late Devonian mass extinction was determined by a combination of impact events and extensive volcanism. They produced similar effects: emissions of harmful chemical compounds and aerosols to cause greenhouse warming; darkening of the atmosphere, which prevented photosynthesis; and stagnation of oceans and development of anoxia. Food chains collapsed and biological productivity decreased. As a result, all vital processes were disturbed and a large portion of the biota became extinct.

Geochemical Aspects of Formation of Large Oil Deposits in the Volga-Ural Sedimentary Basin

NASA Astrophysics Data System (ADS)

Plotnikova, I.; Nosova, F.; Pronin, N.; Nosova, J.; Budkevich, T.

2012-04-01

The study of the rocks domanikoid type in the territory of the Ural-Volga region has an almost century-long history, beginning with the first studies of A.D. Archangelsky in the late 20's of last century. But nevertheless the question of the source of oil that formed the industrial deposits of Volga-Ural oil and gas province (OGP), where Romashkinskoye oil field occupies a special place, remains unresolved and topical. According to the sedimentary-migration theory of origin of oil and gas, it is supposed that the primary source of hydrocarbons in this area are the deposits of domanikoid type that contain a large ammount of sapropel organic matter (OM). Semiluki (domanik) horizon of srednefranski substage of the Upper Devonian is considered to be a typical domanikoid stratum. Investigation of the OM of the rocks and oils of the sedimentary cover on the basis of chromato-mass spectrometry method allows us to study the correlations between rock and oil and to assess the location (or absence) of the sources of hydrocarbons in the Paleozoic sedimentary cover. The results of geochemical study of dispersed organic matter (DOM) of rocks from Semiluksky horizon of the Upper Devonian and of the oil from Pashiysky horizon of the Middle Devonian form the basis of this paper. The objectives of this study were the following: to determine the original organic matter of the rocks, which would indicate the conditions of sedimentation of the supposed rock-oil sources; the study of chemofossils (biomarkers) in oil from Pashiyskiy horizon; and the identification of genetic association of DOM rocks from Semiluksky horizon with this oil on the basis of the oil-DOM correlation. The study of biomarkers was carried out with the help of chromato-mass spectrometry in the Laboratory of Geochemistry of Fossil Fuels (Kazan Federal University). In this study we used several informative parameters characterizing the depositional environment, the type of source OM and its maturity: STER / PENT, hC35/hC34, GAM / HOP, S27/S28/S29 (steranes), DIA / REG, Ts / Tm, MOR / HOP, NOR / HOP, TET / TRI, C29SSR, C29BBAA, C31HSR, S30STER, TRI / PENT, TRI / HOP. Comparison in the rock-oil system was performed primarily according to the parameters indicating the depositional environment of the source rock that contains syngenetic DOM - according to the coefficients that determine lithological conditions for the formation of the supposed oil-source bed strata (DIA / REG, Ts / Tm, NOR / HOP, TRI / HOP and STER / PENT). Biomarker ratios indicate a different type of sedimentation basins. Sediments, which accumulated DOM from Semilukskiy horizon, can be characterized by low clay content, or its absence, that is consistent with the carbonate type of cut of the horizon. The bacterial material that was accumulated under reducing conditions of sedimentation appeared to be the source of syngenetic OM. Chemofossils found in oils from Pashiyskiy horizon are typical of sedimentary strata that contain clay - for clastic rocks, which in the study area are mainly represented by deposits and Eyfel Givetian layers of the Middle Devonian and lowfransk substage of the Upper Devonian. The study of correlations obtained for the different coefficients of OM and oils showed that only the relationships between Ts/Tm and DIA/REG and between NOR/HOP and TRI/HOP are characteristic of close, almost similar values of correlation both for the dispersed organic matter and for oil. In all other cases, the character of the correlation of OM is significantly different from that of oil. The differences in values and ranges of biomarker ratios as well as the character of their correlation indicates the absence of genetic connection between the oil from Pashiyskiy horizon for the dispersed organic matter from Semilukskiy horizon. This conclusion is based on the study of five biomarker parameters (DIA/REG, Ts/Tm, NOR/HOP, TRI/HOP and STER/PENT). The research results described in the article clearly indicate the need for further studies of geochemical features of the organic matter of the Paleozoic mantle rocks and the underlying sedimentary and crystalline complexes of Precambrian.

The geology of Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lambert, Richard A.; White, William B.; Lucas, Philip C.; Garrity, Christopher P.

2015-01-01

Burnsville Cove is a karst region in Bath and Highland Counties of Virginia. A new geologic map of the area reveals various units of limestone, sandstone, and siliciclastic mudstone (shale) of Silurian through Devonian age, as well as structural features such as northeast-trending anticlines and synclines, minor thrust faults, and prominent joints. Quaternary features include erosional (strath) terraces and accumulations of mud, sand, and gravel. The caves of Burnsville Cove are located within predominantly carbonate strata above the Silurian Williamsport Sandstone and below the Devonian Oriskany Sandstone. Most of the caves are located within the Silurian Tonoloway Limestone, rather than the Silurian-Devonian Keyser Limestone as reported previously.

Hydrocarbon potential of Upper Devonian black shale, eastern Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnston, I.M.; Frankie, W.T.; Moody, J.R.

The gas-producing Upper Devonian black shales of eastern Kentucky represent cycles of organic units alternating with less-organic units that were dominated by an influx of clastics from a northeastern source. This pattern of sedimentation is typical throughout the southern Appalachian basin in areas basinal to, yet still influenced by, the Catskill delta to the northwest. These black shales, which thin westward onto the Cincinnati arch, dip eastward into the Appalachian basin. To evaluate the future gas potential of Devonian shale, a data base has been compiled, consisting of specific geologic and engineering information from 5920 Devonian shale wells in Letcher,more » Knott, Floyd, Martin, and Pike Counties, Kentucky. The first successful gas completion in eastern Kentucky was drilled in Martin County in 1901. Comparison of initial open-flow potential (IP) and long-term production data for these wells demonstrates that higher IP values generally indicate wells of higher production potential. Areas of higher IP are aligned linearly, and these lineaments are interpreted to be related to fracture systems within the Devonian shale. These fractures may be basement influenced. Temperature log analyses indicate that the greatest number of natural gas shows occur in the lower Huron Member of the Ohio Shale. Using both the temperature log to indicate gas shows and the gamma-ray log to determine the producing unit is a workable method for selecting the interval for treatment.« less

Bedrock geologic map of the Lisbon quadrangle, and parts of the Sugar Hill and East Haverhill quadrangles, Grafton County, New Hampshire

USGS Publications Warehouse

Rankin, Douglas W.

2018-04-20

The bedrock geologic map of the Lisbon quadrangle, and parts of the Sugar Hill and East Haverhill quadrangles, Grafton County, New Hampshire, covers an area of approximately 73 square miles (189 square kilometers) in west-central New Hampshire. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. A large part of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Devonian sedimentary, volcanic, and plutonic rocks.The Bronson Hill anticlinorium is the apex of the Middle Ordovician to earliest-Silurian Bronson Hill magmatic arc that contains the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic Suite, and extends from Maine, through western New Hampshire (down the eastern side of the Connecticut River), through southern New England to Long Island Sound. The deformed and partially eroded arc is locally overlain by a relatively thin Silurian section of metasedimentary rocks (Clough Quartzite and Fitch Formation) that thickens to the east. The Silurian section near Littleton is disconformably overlain by a thicker, Lower Devonian section that includes mostly metasedimentary and minor metavolcanic rocks of the Littleton Formation. The Bronson Hill anticlinorium is bisected by a series of northeast-southwest trending Mesozoic normal faults. Primarily among them is the steeply northwest-dipping Ammonoosuc fault that divides older and younger units (lower and upper sections) of the Ammonoosuc Volcanics. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of slate, phyllite, ironstone, chert, sandstone, and pelite. The Albee Formation underlies the Ammonoosuc Volcanics and is predominantly composed of interbedded metamorphosed sandstone, siltstone, and phyllite.During the Late Ordovician, a series of arc-related plutons intruded the Ammonoosuc Volcanics including the Moody Ledge pluton and the Scrag granite of Billings (1937). Subsequent plutonism related to the Acadian orogeny occurred after volcanism and deposition resulted in the Littleton Formation during the Late Devonian, including the intrusion of the Haverhill pluton and French Pond Granite found in the southern part of the map.This report consists of a geologic map and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information. The geologic map is intended to serve as a foundation for applying geologic information to problems involving land use decisions, groundwater availability and quality, earth resources such as natural aggregate for construction, assessment of natural hazards, and engineering and environmental studies for waste disposal sites and construction projects.

Geology of the Volga-Ural petroleum province and detailed description of the Ramashkino and Arlan oil fields

USGS Publications Warehouse

Peterson, James A.; Clarke, James W.

1983-01-01

The Volga-Ural petroleum province is in general coincident with the Volga-Ural regional high, a broad upwarp of the east-central part of the Russian (East European) platform. The central part of the province is occupied by the Tatar arch, which contains the major share of the oil fields of the province. The Perm-Bashkir arch forms the northeastern part of the regional high, and the Zhigulevsko-Orenburg arch makes up the southern part. These arches are separated from one another by elongate downwarps. The platform cover overlies an Archean crystalline basement and consists of seven main sedimentation cycles as follows: 1) Riphean (lower Bavly) continental sandstone, shale, and conglomerate beds from 500 to 5,000 m thick deposited in aulacogens. 2) Vendian (upper Bavly) continental and marine shale and sandstone up to 3,000 m thick. 3) Middle Devonian-Tournaisian transgressive deposits, which are sandstone, siltstone, and shale in the lower part and carbonates with abundant reefs in the upper; thickness is 300-1,000 m. In the upper carbonate part is the Kamsko-Kinel trough system, which consists of narrow interconnected deep-water troughs. 4) The Visean-Namurian-Bashkirian cycle, which began with deposition of Visean clastics that draped over reefs of the previous cycle and filled in an erosional relief that had formed in some places on the sediments of the previous cycle. The Visean clastics are overlain by marine carbonates. Thickness of the cycle is 50-800 m. 5) Early Moscovian-Early Permian terrigenous clastic deposits and marine carbonate beds 1,000-3,000 m thick. 6) The late Early Permian-Late Permian cycle, which reflects maximum growth of the Ural Mountains and associated Ural foredeep. Evaporites were first deposited, then marine limestones and dolomites, which intertongue eastward with clastic sediments from the Ural Mountains. 7) Continental redbeds of Triassic age and mixed continental and marine elastic beds of Jurassic and Cretaceous age, which were deposited on the southern, southwestern, and northern margins of the Russian platform; they are generally absent in the Volga-Ural province, however. The Volga-Ural oil and gas basin is a single artesian system that contains seven aquifers separated by seals. The areas of greatest hydraulic head are in the eastern parts of the basin near areas where the aquifers crop out on the western slopes of the Ural Mountains. The Peri-Caspian basin is the principal drainage area of the artesian system. Approximately 600 oil and gas fields and 2,000 pools have been found in the Volga-Ural province. Nine productive sequences are recognized as follows: 1) Upper Proterozoic (Bavly beds), which are promising but not yet commercial. 2) Clastic Devonian, which contains the major reserves and includes the main pays of the super-giant Romashkino field. 3) Carbonate Upper Devonian and lowermost Carboniferous, which is one of the main reef-bearing intervals. 4) Visean (Lower Carboniferous) elastics, which are the main pays in the super-giant Arian field. 5) Carbonate Lower and Middle Carboniferous. 6) Clastic Middle Carboniferous Moscovian. 7) Carbonate Middle and Upper Carboniferous. 8) Carbonate-evaporite Lower Permian, which contains the major gas reserves and the lower part of the Melekess tar deposits. 9) Clastic-carbonate Upper Permian, which contains the major part of the Melekess tar deposits. The Volga-Ural province is divided into several productive regions on a basis of differences in structure, distribution of reservoir and source-rock facies, and general composition of the petroleum accumulations. These regions are the Tatar arch, Birsk saddle, Upper Kama depression, Perm-Bashkir arch, Ufa-Orenburg monocline, Melekess-Sernovodsko-Abdulino basin, Zhligulevsko-Orenburg arch, Ural foredeep, and north borders of the Peri-Casplan depression. Exploration activity has declined in recent years; however, interest remains high in several parts of the province, particula

18 CFR 270.306 - Devonian shale wells in Michigan.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Devonian shale wells in Michigan. 270.306 Section 270.306 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY...) Attesting the applicant has no knowledge of any information not described in the application which is...

Devonian volcanic rocks of the southern Chinese Altai, NW China: Petrogenesis and implication for a propagating slab-window magmatism induced by ridge subduction during accretionary orogenesis

NASA Astrophysics Data System (ADS)

Ma, Xiaomei; Cai, Keda; Zhao, Taiping; Bao, Zihe; Wang, Xiangsong; Chen, Ming; Buslov, M. M.

2018-07-01

Ridge-trench interaction is a common tectonic process of the present-day Pacific Rim accretionary orogenic belts, and this process may facilitate "slab-window" magmatism that can produce significant thermal anomalies and geochemically unusual magmatic events. However, ridge-trench interaction has rarely been well-documented in the ancient geologic record, leading to grossly underestimation of this process in tectonic syntheses of plate margins. The Chinese Altai was inferred to have undergone ridge subduction in the Devonian and a slab-window model is proposed to interpret its high-temperature metamorphism and geochemically unique magmatic rocks, which can serve as an excellent and unique place to refine the tectonic evolution associated with ridge subduction in an ancient accretionary orogeny. For this purpose, we carried out geochemical and geochronological studies on Devonian basaltic rocks in this region. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating results yield an age of 376.2 ± 2.4 Ma, suggesting an eruption at the time of Late Devonian. Geochemically, the samples in this study have variable SiO2 (43.3-58.3 wt%), low K2O (0.02-0.07 wt%) and total alkaline contents (2.16-5.41 wt%), as well as Fe2O3T/MgO ratios, showing typical tholeiitic affinity. On the other hand, the basaltic rocks display MORB-like REE patterns ((La/Yb)N = 0.90-2.57) and (Ga/Yb)N = 0.97-1.28), and have moderate positive εNd(t) values (+4.4 to +5.4), which collectively suggest a derivation from a mixing source comprising MORB-like mantle of a mature back-arc basin and subordinate arc mantle wedge. These basaltic rocks are characterized by Low La/Yb (1.26-3.69), Dy/Yb (1.51-1.77) and Sm/Yb (0.83-1.32) ratios, consistent with magmas derived from low degree (∼10%) partial melting of the spinel lherzolite source at a quite shallow mantle depth. Considering the distinctive petrogenesis of the basaltic rocks in this region, the Late Devonian basalts in the southern Chinese Altai is suggested to have witnessed the propagating process of slab-window magmatism that was induced by ridge subduction in a nascent rifting stage of a back-arc basin.

Thermal maturity of northern Appalachian Basin Devonian shales: Insights from sterane and terpane biomarkers

USGS Publications Warehouse

Hackley, Paul C.; Ryder, Robert T.; Trippi, Michael H.; Alimi, Hossein

2013-01-01

To better estimate thermal maturity of Devonian shales in the northern Appalachian Basin, eleven samples of Marcellus and Huron Shale were characterized via multiple analytical techniques. Vitrinite reflectance, Rock–Eval pyrolysis, gas chromatography (GC) of whole rock extracts, and GC–mass spectrometry (GCMS) of extract saturate fractions were evaluated on three transects that lie across previously documented regional thermal maturity isolines. Results from vitrinite reflectance suggest that most samples are immature with respect to hydrocarbon generation. However, bulk geochemical data and sterane and terpane biomarker ratios from GCMS suggest that almost all samples are in the oil window. This observation is consistent with the presence of thermogenic gas in the study area and higher vitrinite reflectance values recorded from overlying Pennsylvanian coals. These results suggest that vitrinite reflectance is a poor predictor of thermal maturity in early mature areas of Devonian shale, perhaps because reported measurements often include determinations of solid bitumen reflectance. Vitrinite reflectance interpretations in areas of early mature Devonian shale should be supplanted by evaluation of thermal maturity information from biomarker ratios and bulk geochemical data.

Euryhaline ecology of early tetrapods revealed by stable isotopes.

PubMed

Goedert, Jean; Lécuyer, Christophe; Amiot, Romain; Arnaud-Godet, Florent; Wang, Xu; Cui, Linlin; Cuny, Gilles; Douay, Guillaume; Fourel, François; Panczer, Gérard; Simon, Laurent; Steyer, J-Sébastien; Zhu, Min

2018-06-01

The fish-to-tetrapod transition-followed later by terrestrialization-represented a major step in vertebrate evolution that gave rise to a successful clade that today contains more than 30,000 tetrapod species. The early tetrapod Ichthyostega was discovered in 1929 in the Devonian Old Red Sandstone sediments of East Greenland (dated to approximately 365 million years ago). Since then, our understanding of the fish-to-tetrapod transition has increased considerably, owing to the discovery of additional Devonian taxa that represent early tetrapods or groups evolutionarily close to them. However, the aquatic environment of early tetrapods and the vertebrate fauna associated with them has remained elusive and highly debated. Here we use a multi-stable isotope approach (δ 13 C, δ 18 O and δ 34 S) to show that some Devonian vertebrates, including early tetrapods, were euryhaline and inhabited transitional aquatic environments subject to high-magnitude, rapid changes in salinity, such as estuaries or deltas. Euryhalinity may have predisposed the early tetrapod clade to be able to survive Late Devonian biotic crises and then successfully colonize terrestrial environments.

Exceptionally preserved crustaceans from western Canada reveal a cryptic Cambrian radiation

NASA Astrophysics Data System (ADS)

Harvey, Thomas H. P.; Vélez, Maria I.; Butterfield, Nicholas J.

2012-01-01

The early history of crustaceans is obscured by strong biases in fossil preservation, but a previously overlooked taphonomic mode yields important complementary insights. Here we describe diverse crustacean appendages of Middle and Late Cambrian age from shallow-marine mudstones of the Deadwood Formation in western Canada. The fossils occur as flattened and fragmentary carbonaceous cuticles but provide a suite of phylogenetic and ecological data by virtue of their detailed preservation. In addition to an unprecedented range of complex, largely articulated filtering limbs, we identify at least four distinct types of mandible. Together, these fossils provide the earliest evidence for crown-group branchiopods and total-group copepods and ostracods, extending the respective ranges of these clades back from the Devonian, Pennsylvanian, and Ordovician. Detailed similarities with living forms demonstrate the early origins and subsequent conservation of various complex food-handling adaptations, including a directional mandibular asymmetry that has persisted through half a billion years of evolution. At the same time, the Deadwood fossils indicate profound secular changes in crustacean ecology in terms of body size and environmental distribution. The earliest radiation of crustaceans is largely cryptic in the fossil record, but "small carbonaceous fossils" reveal organisms of surprisingly modern aspect operating in an unfamiliar biosphere.

The Neoacadian orogenic core of the souther Appalachians: a Geo-traverse through the migmatitic inner Piedmont from the Brushy Mountains to Lincolnton, North Carolina

USGS Publications Warehouse

Merschat, Arthur J.; Hatcher, Robert D.; Byars, Heather E.; Gilliam, William G.; Eppes, Martha Cary; Bartholomew, Mervin J.

2012-01-01

The Inner Piedmont extends from North Carolina to Alabama and comprises the Neoacadian (360–345 Ma) orogenic core of the southern Appalachian orogen. Bordered to west by the Blue Ridge and the exotic Carolina superterrane to the east, the Inner Piedmont is cored by an extensive region of migmatitic, sillimanite-grade rocks. It is a composite of the peri-Laurentian Tugaloo terrane and mixed Laurentian and peri-Gondwanan affinity Cat Square terrane, which are exposed in several gentle-dipping thrust sheets (nappes). The Cat Square terrane consists of Late Silurian to Early Devonian pelitic schist and metagraywacke intruded by several Devonian to Mississippian peraluminous granitoids, and juxtaposed against the Tugaloo terrane by the Brindle Creek fault. This field trip through the North Carolina Inner Piedmont will examine the lithostratigraphies of the Tugaloo and Cat Square terranes, deformation associated with Brindle Creek fault, Devonian-Mississippian granitoids and charnockite of the Cat Square terrane, pervasive amphibolite-grade Devonian-Mississippian (Neoacadian) deformation and metamorphism throughout the Inner Piedmont, and existence of large crystalline thrust sheets in the Inner Piedmont. Consistent with field observations, geochronology and other data, we have hypothesized that the Carolina superterrane collided obliquely with Laurentia near the Pennsylvania embayment during the Devonian, overrode the Cat Square terrane and Laurentian margin, and squeezed the Inner Piedmont out to the west and southwest as an orogenic channel buttressed against the footwall of the Brevard fault zone.

Unsuspected functional disparity in Devonian fishes revealed by tooth morphometrics?

NASA Astrophysics Data System (ADS)

Gauchey, Samuel; Girard, Catherine; Adnet, Sylvain; Renaud, Sabrina

2014-09-01

The shape of features involved in key biological functions, such as teeth in nutrition, can provide insights into ecological processes even in ancient time, by linking the occupation of the morphological space (disparity) to the occupation of the ecological space. Investigating disparity in radiating groups may provide insights into the ecological diversification underlying evolution of morphological diversity. Actinopterygian fishes initiated their radiation in the Devonian, a period characterized by the diversification of marine ecosystem. Although a former morpho-functional analysis of jaw shape concluded to conservative and poorly diversified morphologies in this early part of their history, fish tooth disparity evidenced here an unsuspected diversity of possible functional significance in the pivotal period of the Late Devonian (Famennian). All teeth being caniniforms, some were stocky and robust, in agreement with expectations for active generalist predators. More surprisingly, elongated teeth also occurred at the beginning of Famennian. Their needle-like shape challenges morpho-functional interpretations by making them fragile in response to bending or torsion. The occurrence of both types of fish teeth during the beginning of the Famennian points to a discrete but real increase in disparity, thus testifying a first burst of feeding specialization despite overall conservative jaw morphology. The disappearance of these needle-like teeth in the Late Famennian might have been related to a relay in dental diversity with abundant co-occurring groups, namely conodonts and chondrichthyans (sharks).

Ste. Genevieve Fault Zone, Missouri and Illinois. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, W.J.; Lumm, D.K.

1985-07-01

The Ste. Genevieve Fault Zone is a major structural feature which strikes NW-SE for about 190 km on the NE flank of the Ozark Dome. There is up to 900 m of vertical displacement on high angle normal and reverse faults in the fault zone. At both ends the Ste. Genevieve Fault Zone dies out into a monocline. Two periods of faulting occurred. The first was in late Middle Devonian time and the second from latest Mississippian through early Pennsylvanian time, with possible minor post-Pennsylvanian movement. No evidence was found to support the hypothesis that the Ste. Genevieve Fault Zonemore » is part of a northwestward extension of the late Precambrian-early Cambrian Reelfoot Rift. The magnetic and gravity anomalies cited in support of the ''St. Louis arm'' of the Reelfoot Rift possible reflect deep crystal features underlying and older than the volcanic terrain of the St. Francois Mountains (1.2 to 1.5 billion years old). In regard to neotectonics no displacements of Quaternary sediments have been detected, but small earthquakes occur from time to time along the Ste. Genevieve Fault Zone. Many faults in the zone appear capable of slipping under the current stress regime of east-northeast to west-southwest horizontal compression. We conclude that the zone may continue to experience small earth movements, but catastrophic quakes similar to those at New Madrid in 1811-12 are unlikely. 32 figs., 1 tab.« less

The Cannery Formation--Devonian to Early Permian arc-marginal deposits within the Alexander Terrane, Southeastern Alaska

USGS Publications Warehouse

Karl, Susan M.; Layer, Paul W.; Harris, Anita G.; Haeussler, Peter J.; Murchey, Benita L.

2011-01-01

The Cannery Formation consists of green, red, and gray ribbon chert, siliceous siltstone, graywacke-chert turbidites, and volcaniclastic sandstone. Because it contains early Permian fossils at and near its type area in Cannery Cove, on Admiralty Island in southeastern Alaska, the formation was originally defined as a Permian stratigraphic unit. Similar rocks exposed in Windfall Harbor on Admiralty Island contain early Permian bryozoans and brachiopods, as well as Mississippian through Permian radiolarians. Black and green bedded chert with subordinate lenses of limestone, basalt, and graywacke near Kake on Kupreanof Island was initially correlated with the Cannery Formation on the basis of similar lithology but was later determined to contain Late Devonian conodonts. Permian conglomerate in Keku Strait contains chert cobbles inferred to be derived from the Cannery Formation that yielded Devonian and Mississippian radiolarians. On the basis of fossils recovered from a limestone lens near Kake and chert cobbles in the Keku Strait area, the age of the Cannery Formation was revised to Devonian and Mississippian, but this revision excludes rocks in the type locality, in addition to excluding bedded chert on Kupreanof Island east of Kake that contains radiolarians of Late Pennsylvanian and early Permian age. The black chert near Kake that yielded Late Devonian conodonts is nearly contemporaneous with black chert interbedded with limestone that also contains Late Devonian conodonts in the Saginaw Bay Formation on Kuiu Island. The chert cobbles in the conglomerate in Keku Strait may be derived from either the Cannery Formation or the Saginaw Bay Formation and need not restrict the age of the Cannery Formation, regardless of their source. The minimum age of the Cannery Formation on both Admiralty Island and Kupreanof Island is constrained by the stratigraphically overlying fossiliferous Pybus Formation, of late early and early late Permian age. Because bedded radiolarian cherts on both Admiralty and Kupreanof Islands contain radiolarians as young as Permian, the age of the Cannery Formation is herein extended to Late Devonian through early Permian, to include the early Permian rocks exposed in its type locality. The Cannery Formation is folded and faulted, and its stratigraphic thickness is unknown but inferred to be several hundred meters. The Cannery Formation represents an extended period of marine deposition in moderately deep water, with slow rates of deposition and limited clastic input during Devonian through Pennsylvanian time and increasing argillaceous, volcaniclastic, and bioclastic input during the Permian. The Cannery Formation comprises upper Paleozoic rocks in the Alexander terrane of southeastern Alaska. In the pre-Permian upper Paleozoic, the tectonic setting of the Alexander terrane consisted of two or more evolved oceanic arcs. The lower Permian section is represented by a distinctive suite of rocks in the Alexander terrane, which includes sedimentary and volcanic rocks containing early Permian fossils, metamorphosed rocks with early Permian cooling ages, and intrusive rocks with early Permian cooling ages, that form discrete northwest-trending belts. After restoration of 180 km of dextral displacement of the Chilkat-Chichagof block on the Chatham Strait Fault, these belts consist, from northeast to southwest, of (1) bedded chert, siliceous argillite, volcaniclastic turbidites, pillow basalt, and limestone of the Cannery Formation and the Porcupine Slate of Gilbert and others (1987); (2) greenschist-facies Paleozoic metasedimentary and metavolcanic rocks that have Permian cooling ages; (3) silty limestone and calcareous argillite interbedded with pillow basalt and volcaniclastic rocks of the Halleck Formation and the William Henry Bay area; and (4) intermediate-composition and syenitic plutons. These belts correspond to components of an accretionary complex, contemporary metamorphic rocks, forearc-basin deposits,

Unusual anal fin in a Devonian jawless vertebrate reveals complex origins of paired appendages

PubMed Central

Sansom, Robert S.; Gabbott, Sarah E.; Purnell, M. A.

2013-01-01

Jawed vertebrates (gnathostomes) have undergone radical anatomical and developmental changes in comparison with their jawless cousins (cyclostomes). Key among these is paired appendages (fins, legs and wings), which first evolved at some point on the gnathostome stem. The anatomy of fossil stem gnathostomes is, therefore, fundamental to our understanding of the nature and timing of the origin of this complex innovation. Here, we show that Euphanerops, a fossil jawless fish from the Devonian, possessed paired anal-fin radials, but no pectoral or pelvic fins. This unique condition occurs at an early stage on the stem-gnathostome lineage. This condition, and comparison with the varied condition of paired fins in other ostracoderms, indicates that there was a large amount of developmental plasticity during this episode—rather than a gradual evolution of this complex feature. Apparently, a number of different clades were exploring morphospace or undergoing multiple losses. PMID:23576777

Strike-slip faulting at Thebes Gap, Missouri and Illinois; implications for New Madrid tectonism

USGS Publications Warehouse

Harrison, Richard W.; Schultz, Art

1994-01-01

Numerous NNE and NE striking strike-slip faults and associated normal faults, folds, and transtensional grabens occur in the Thebes Gap area of Missouri and Illinois. These structures developed along the northwestern margin of the buried Reelfoot rift of Precambrian-Cambrian age at the northern edge of the Mississippi embayment. They have had a long-lived and complex structural history. This is an area of recent moderate seismicity, approximately 45 km north of the New Madrid seismic zone. Stratigraphic evidence suggests that these faults were active during the Middle Ordovician. They were subsequently reactivated between the Early Devonian and Late Cretaceous, probably in response to both the Acadian and Ouachita orogenies. Deformation during this period was characterized by strongly faulted and folded Ordovician through Devonian rocks. In places, these deformed rocks are overlain with angular unconformity by undeformed Cretaceous strata. Fault motion is interpreted as dominantly strike slip. A still younger period of reactivation involved Late Cretaceous and Cenozoic formations as young as the Miocene or Pliocene Mounds Gravel. These formations have experienced both minor high-angle normal faulting and subsequent major, right-lateral strike-slip faulting. En echelon north-south folds, ENE striking normal faults, regional fracture patterns, and drag folds indicate the right-lateral motion for this major episode of faulting which predates deposition of Quaternary loess. Several nondefinitive lines of evidence suggest Quaternary faulting. Similar fault orientations and kinematics, as well as recent seismicity and proximity, clearly suggest a structural relationship between deformation at Thebes Gap and tectonism associated with the New Madrid area.

Low Pressure-High Temperature Metamorphism and the Advection of Heat to the Continental Crust: A Case Study from Northwest New Guinea

NASA Astrophysics Data System (ADS)

Jost, B.; Webb, M.; White, L. T.

2017-12-01

In northwest New Guinea, Palaeozoic basement rocks forming part of the northern margin of the Australian continent are exposed in a rugged mountain range. This remote and understudied region provides a unique window into the complex Palaeozoic evolution and tectonic history of this region, which we help unravel with new field, petrographic, geochemical, and geochronological data. The basement rocks consist of extensive meta-turbidites that were subject to low pressure-high temperature metamorphism along their eastern margin. They are cross-cut by predominantly acidic granitoids. U-Pb zircon dating reveals that these granitoids intruded in three episodes in the Devonian-Carboniferous, the Carboniferous, and the Triassic. The first episode has not previously been reported in the region. The granitoids are strongly peraluminous, suggesting that partial melting of the meta-sedimentary country rock contributed to their petrogenesis (S-type). The occurrence and character of country rock xenoliths and migmatites supports this interpretation. Equilibrium thermodynamic modelling of the metapelites and the migmatites indicates that a substantial amount of heat was added to the lower and middle crust to cause partial melting and regional metamorphism at relatively low pressure. We propose repeated intrusion of hot magma as the mechanism responsible for advecting the necessary heat from the mantle. This likely occurred in an active continental margin setting during the Devonian-Carboniferous and the Triassic, possibly separated by an interval of magmatic quiescence during most of the Permian. New biostratigraphic and low-temperature thermochronological data reveal very recent Pliocene-Pleistocene uplift and unroofing of these basement rocks.

Material composition of the basalt-trachyte series of the early Devonian of the Saralin graben-rift

NASA Astrophysics Data System (ADS)

Grinev, O. M.; Grinev, R. O.; Bogorodov, A. A.; Adylbaev, R. R.

2017-12-01

The article clarifies the structural-tectonic position of the Saralin graben. It is determined that, along with the Balyksinsky graben located to the south and the Goryachegorsky volcanic plateau to the north, they are the connecting structural links between the Kuznetsk-Alatau alkaline province and the adjacent Minusinsk trough. In the early Devonian, the alkaline province was formed as a vaulted-block structure (the “shoulder” of the rift), and the Minusinsk deflection as a depression with the dominant volcanism in it. The boundary between these positive and negative structures was the deep Balyksinsko-Saralinsky fault. In the stratigraphic section of the graben, the lower molassoid part (Ustkundustylskaya stratum), the middle trachybasaltoid stratum (Bazarskay) and the upper problematic Ashpanian stratum are distinguished. In addition to analcime basalts, a large extrusive-subvolcanic dome-shaped construction of trachytes is considered. By petrographic and material composition, volcanites of graben are represented by the dominant basalt-trachyte series in the composition of basanites, trachybasalts, trachyandesites, trachytes. The rocks of the basalt-andesibasalt-andesite series are limited. Foidites are rare. Geochemical data indicate the genetic relationship of the volcanics of the studied series. Geochemically, they are clearly specialized in Sc, Ti, Zn, Zr, Th, U, Mn and P. According to the content of some of these elements, the rocks may have an industrial potential. In geodynamic and genetic plans, graben and its volcanics were formed during plume-tectonic processes involving mantle plume, enriched mantle, and recycling processes of these formations with the substance of the consolidated PR-PZ1 cortex.

Late Devonian (Frasnian) phyllopod and phyllocarid crustacean shields from Belgium reinterpreted as ammonoid anaptychi

NASA Astrophysics Data System (ADS)

Goolaerts, Stijn; Denayer, Julien; Mottequin, Bernard

2017-12-01

The taxonomic affinities of fossils from the Frasnian succession of Belgium previously described as phyllopod and phyllocarid crustacean shields are discussed. The rediscovery of the holotype of Ellipsocaris dewalquei, the type species of the genus Ellipsocaris Woodward in Dewalque, 1882, allows to end the discussion on the taxonomic assignation of the genus Ellipsocaris. It is removed from the phyllopod crustaceans as interpreted originally and considered here as an ammonoid anaptychus. Furthermore, it is considered to be a junior synonym of the genus Sidetes Giebel, 1847. Similarly, Van Straelen's (1933) lower to middle Frasnian record Spathiocaris chagrinensis Ruedemann, 1916, is also an ammonoid anaptychus. Although ammonoids can be relatively frequent in some Frasnian horizons of Belgium, anaptychi remain particularly scarce and the attribution to the present material to peculiar ammonoid species is not possible.

Some contrasting biostratigraphic links between the Baker and Olds Ferry Terranes, eastern Oregon

USGS Publications Warehouse

Nestell, Merlynd K.; Blome, Charles D.

2016-01-01

New stratigraphic and paleontologic data indicate that ophiolitic melange windows in the Olds Ferry terrane of eastern Oregon contain limestone blocks and chert that are somewhat different in age than those present in the adjacent Baker terrane melange. The melange windows in the Olds Ferry terrane occur as inliers in the flyschoid Early and Middle Jurassic age Weatherby Formation, which depositionally overlies the contact between the melange-rich Devonian to Upper Triassic rocks of the Baker terrane on the north, and Upper Triassic and Early Jurassic volcanic arc rocks of the Huntington Formation on the south. The Baker terrane and Huntington Formation represent fragments of a subduction complex and related volcanic island arc, whereas the Weatherby Formation consists of forearc basin sedimentary deposits. The tectonic blocks in the melange windows of the Weatherby Formation (in the Olds Ferry terrane) are dated by scarce biostratigraphic evidence as Upper Pennsylvanian to Lower Permian and Upper Triassic. In contrast, tectonic blocks of limestone in theBaker terrane yield mostly fusulinids and small foraminifers of Middle Pennsylvanian Moscovian age at one locality.Middle Permian (Guadalupian) Tethyan fusulinids and smaller foraminifers (neoschwagerinids and other Middle Permian genera) are present at a few other localities. Late Triassic conodonts and bryozoans are also present in a few of the Baker terrane tectonic blocks. These limestone blocks are generally embedded in Permian and Triassic radiolarian bearing chert or argillite. Based on conodont, radiolarian and fusulinid data, the age limits of the meange blocks in the Weatherby Formation range from Pennsylvanian to Late Triassic.

Refining the Early Devonian time scale using Milankovitch cyclicity in Lochkovian-Pragian sediments (Prague Synform, Czech Republic)

NASA Astrophysics Data System (ADS)

Da Silva, A. C.; Hladil, J.; Chadimová, L.; Slavík, L.; Hilgen, F. J.; Bábek, O.; Dekkers, M. J.

2016-12-01

The Early Devonian geological time scale (base of the Devonian at 418.8 ± 2.9 Myr, Becker et al., 2012) suffers from poor age control, with associated large uncertainties between 2.5 and 4.2 Myr on the stage boundaries. Identifying orbital cycles from sedimentary successions can serve as a very powerful chronometer to test and, where appropriate, improve age models. Here, we focus on the Lochkovian and Pragian, the two lowermost Devonian stages. High-resolution magnetic susceptibility (χin - 5 to 10 cm sampling interval) and gamma ray spectrometry (GRS - 25 to 50 cm sampling interval) records were gathered from two main limestone sections, Požár-CS (118 m, spanning the Lochkov and Praha Formations) and Pod Barrandovem (174 m; Praha Formation), both in the Czech Republic. An additional section (Branžovy, 65 m, Praha Formation) was sampled for GRS (every 50 cm). The χin and GRS records are very similar, so χin variations are driven by variations in the samples' paramagnetic clay mineral content, reflecting changes in detrital input. Therefore, climatic variations are very likely captured in our records. Multiple spectral analysis and statistical techniques such as: Continuous Wavelet Transform, Evolutive Harmonic Analysis, Multi-taper method and Average Spectral Misfit, were used in concert to reach an optimal astronomical interpretation. The Požár-CS section shows distinctly varying sediment accumulation rates. The Lochkovian (essentially equivalent to the Lochkov Formation (Fm.)) is interpreted to include a total of nineteen 405 kyr eccentricity cycles, constraining its duration to 7.7 ± 2.8 Myr. The Praha Fm. includes fourteen 405 kyr eccentricity cycles in the three sampled sections, while the Pragian Stage only includes about four 405 kyr eccentricity cycles, thus exhibiting durations of 5.7 ± 0.6 Myr and 1.7 ± 0.7 Myr respectively. Because the Lochkov Fm. contains an interval with very low sediment accumulation rate and because the Praha Fm. was cross-validated in three different sections, the uncertainty in the duration of the Lochkov Fm. and the Lochkovian is larger than that of the Praha Fm. and Pragian. The new floating time scales for the Lochkovian and Pragian stages have an unprecedented precision, with reduction in the uncertainty by a factor of 1.7 for the Lochkovian and of ∼6 for the Pragian. Furthermore, longer orbital modulation cycles are also identified with periodicities of ∼1000 kyr and 2000-2500 kyr.

U-Pb ages and metamorphic evolution of the La Pampa Gneisses: Implications for the evolution of the Chilenia Terrane and Permo-Triassic tectonics of north Central Chile

NASA Astrophysics Data System (ADS)

Álvarez, Javier; Mpodozis, Constantino; Blanco-Quintero, Idael; García-Casco, Antonio; Arriagada, César; Morata, Diego

2013-11-01

The La Pampa Gneisses are an enclave of orthogneisses emplaced within late Paleozoic to Triassic granitoids of the Chollay Batholith, in the Cordillera Frontal, to the east of Vallenar. Previous geochronological data (a Rb/Sr “errorchron” of 415 ± 4 Ma) allowed to some authors to suggest that these rocks were part of the Chilenia Terrane accreted to Gondwana during the Middle Devonian (ca. 390 Ma). New petrographic, chemical and geothermobarometric studies, together with U-Pb geochronological data show that the protolith of the La Pampa Gneisses derives from peraluminous tonalites emplaced during the Pennsylvanian at 306.5 ± 1.8 Ma, ruling out the hypothesis considering these rocks as remnant of the pre-collisional Chilenia basement. The tonalites were metamorphosed between 5.06 and 5.58 kbar and 709-779 °C during the middle Permian (267.6 ± 2.1 Ma), possibly in conjunction with the San Rafael tectonic event and the emplacement of the oldest granitoids of the Chollay Batholith. A new intrusive episode occurred at ca. 240 Ma, followed by exhumation and cooling during a regional Triassic extensional episode.

Climate effects caused by land plant invasion in the Devonian

NASA Astrophysics Data System (ADS)

Hir guillaume, Le; yannick, Donnadieu; yves, Goddéris; brigitte, Meyer-Berthaud; gilles, Ramstein

2017-04-01

Land plants invaded continents during the Mid-Paleozoic. Their spreading and diversification have been compared to the Cambrian explosion in terms of intensity and impact on the diversification of life on Earth. Whereas prior studies were focused on the evolution of the root system and its weathering contribution, here we investigated the biophysical impacts of plant colonization on the surface climate through changes in continental albedo, roughness, thermal properties, and potential evaporation using a 3D-climate model coupled to a global biogeochemical cycles associated to a simple model for vegetation dynamics adapted to Devonian conditions. From the Early to the Late Devonian, we show that continental surface changes induced by land plants and tectonic drift have produced a large CO2 drawdown without being associated to a global cooling, because the cooling trend is counteracted by a warming trend resulting from the surface albedo reduction. If CO2 is consensually assumed as the main driver of the Phanerozoic climate, during land-plant invasion, the modifications of soil properties could have played in the opposite direction of the carbon dioxide fall, hence maintaining warm temperatures during part of the Devonian.

Discovery of the fossiliferous Cu Brei Formation (Lower Devonian) in the Kon Tum Block (South Viet Nam)

NASA Astrophysics Data System (ADS)

Thanh, Tong-Dzuy; Duyen, Than Duc; Hung, Nguyen Huu; My, Bui Phu

2007-01-01

Lower Devonian corals and stromatoporoids have recently been discovered in limestones among low grade metamorphic rocks on the western margin of the Kon Tum Block (South Viet Nam). This unit has been identified as the Cu Brei Formation. Coral and stromatoporoid species have been described including Squameofavosites aff. spongiosus, Parallelostroma cf. multicolumnum, Amphipora cf. rasilis, A. cf. raritalis, Simplexodictyon cf. artyschtense, Stromatopora cf. boriarchinovi and Stromatopora sp. indet. The Cu Brei Formation is exposed in a small area 6 km in length and 3 km wide at the foot of Cu Brei Mountain (Sa Thay District, Kon Tum Province). As this formation is in marine shelf facies it is probable that further exposures of Lower Devonian sediments may be discovered in the Kon Tum Block. This discovery raises the question of the tectonic history of the metamorphic Kon Tum Block. It is possible that the block was not an area of positive uplift from the beginning of Paleozoic as has been supposed, but was submerged in a marine environment, at least on its outer margins, in the Devonian, and possibly even earlier, in Early Paleozoic.

Hydrology, water quality, and effects of drought in Monroe County, Michigan

USGS Publications Warehouse

Nicholas, J.R.; Rowe, Gary L.; Brannen, J.R.

1996-01-01

Monroe County relies heavily on its aquifers and streams for drinking water, irrigation, and other ~ses; however, increased water use, high concentrations of certain constituents in ground water, and droughts may limit the availability of water resources. Although the most densely populated parts of the county use water from the Great Lakes, large amounts of ground water are withdrawn for quarry dewatering, domestic supply, and irrigation.Unconsolidated deposits and bedrock of Silurian and Devonian age underlie Mon_roe County. The unconsolidated deposits are mostly clayey and less than 50 feet thick. Usable amounts of ground water generally are obtained from thin, discontinuous surficial sand deposits or, in the northwestern part of the county, from deep glaciofluvial deposits. In most of the county, however, ground water in unconsolidated deposits is highly susceptible to effects of droughts and to contamination.The bedrock is mostly carbonate rock, and usable quantities of ground water can be obtained from fractures and other secondary openings throughout the county. Transmissivities of the Silurian-Devonian aquifer range from 10 to 6,600 feet squared per day. Aquifer tests and historical informati.on indicate that the Silurian-Devonian aquifer is confmed throughout most of the county. The major recharge area for the Silurian-Devonian aquifer in Monroe County is in the southwest, and groundwater flow is mostly southeastward toward Lake Erie. In the northeastern and southeastern parts of the county, the potentiometric surface of the SilurianDevonian aquifers has been lowered by pumpage to below the elevation of Lake Erie.Streams and artificial drains in Monroe County are tributary to Lake Erie. Most streams are perennial because of sustained discharge from the sand aquifer and the Silurian-Devonian aquifer; however, the lower reaches of River Raisin and Plum Creek lost water to the Silurian-Devonian aquifer in July 1990.The quality of ground water and of streamwater at low flow is suitable for most domestic u~es, irrigation, and recreation. In ground water, dissolved solids and hydrogen sulfide are present at concentrations objectionable to some users. Indicators of ground-water contamination from agricultural activities-pesticides and nitrates-were not present at detectable concentrations or were below U.S. Environmental Protection Agency (USEPA) limits. In streamwater, some treatment to remove bacteria may be necessary in summer months; nitrate concentrations, however, were found to be below USEPA limits.Tritium concentrations indicative of recent recharge to the Silurian-Devonian aquifer are present in a southwest-to-northeast-trending band from Whiteford to Berlin Townships. Generally, where glacial deposits are thicker than 30 feet, rech~rge.takes more than 40 years. Carbon isotope data md1cate that some of the ground water in the Silurian-Devonian aquifer is more than 14,000 years old.Mild droughts are common in Michigan, but long severe droughts, such as those during 1930-37 and 1960-67, are infrequent. The most recent drought, during 1988, was severe but short. Ground-water levels declined throughout the county; the largest declines were probably in the southwest. Shallow bedrock wells completed in only the upper part of the Silurian-Devonian aquifer and near large uses of ground water were especially susceptible to the effects of drought. Deep bedrock wells continued to produce water through the drought of 1988.During droughts, streamflow is reduced because of low ground-water levels and high consumptive uses of surface water. In 1988, annual discharge on the River Raisin was near normal, but monthly averages were below normal from March through August. The quality of surface water during droughts is similar to that during normal lowflow conditions.

Cope's Rule and Romer's theory: patterns of diversity and gigantism in eurypterids and Palaeozoic vertebrates

PubMed Central

Lamsdell, James C.; Braddy, Simon J.

2010-01-01

Gigantism is widespread among Palaeozoic arthropods, yet causal mechanisms, particularly the role of (abiotic) environmental factors versus (biotic) competition, remain unknown. The eurypterids (Arthropoda: Chelicerata) include the largest arthropods; gigantic predatory pterygotids (Eurypterina) during the Siluro-Devonian and bizarre sweep-feeding hibbertopterids (Stylonurina) from the Carboniferous to end-Permian. Analysis of family-level originations and extinctions among eurypterids and Palaeozoic vertebrates show that the diversity of Eurypterina waned during the Devonian, while the Placodermi radiated, yet Stylonurina remained relatively unaffected; adopting a sweep-feeding strategy they maintained their large body size by avoiding competition, and persisted throughout the Late Palaeozoic while the predatory nektonic Eurypterina (including the giant pterygotids) declined during the Devonian, possibly out-competed by other predators including jawed vertebrates. PMID:19828493

The first direct evidence of a Late Devonian coelacanth fish feeding on conodont animals

NASA Astrophysics Data System (ADS)

Zatoń, Michał; Broda, Krzysztof; Qvarnström, Martin; Niedźwiedzki, Grzegorz; Ahlberg, Per Erik

2017-04-01

We describe the first known occurrence of a Devonian coelacanth specimen from the lower Famennian of the Holy Cross Mountains, Poland, with a conodont element preserved in its digestive tract. A small spiral and phosphatic coprolite (fossil excrement) containing numerous conodont elements and other unrecognized remains was also found in the same deposits. The coprolite is tentatively attributed to the coelacanth. Although it is unclear whether the Late Devonian coelacanth from Poland was an active predator or a scavenger, these finds provide the first direct evidence of feeding on conodont animals by early coelacanth fish, and one of the few evidences of feeding on these animals known to date. It also expands our knowledge about the diet and trophic relations between the Paleozoic marine animals in general.

Rifting along the northern Gondwana margin and the evolution of the Rheic Ocean: A Devonian age for the El Castillo volcanic rocks (Salamanca, Central Iberian Zone)

NASA Astrophysics Data System (ADS)

Gutiérrez-Alonso, G.; Murphy, J. B.; Fernández-Suárez, J.; Hamilton, M. A.

2008-12-01

Exposures of volcanic rocks (El Castillo) in the Central Iberian Zone near Salamanca, Spain, are representative of Paleozoic volcanic activity along the northern Gondwanan passive margin. Alkaline basalts and mafic volcaniclastic rocks of this sequence are structurally preserved in the core of the Variscan-Tamames Syncline. On the basis of the occurrence of graptolite fossils in immediately underlying strata, the El Castillo volcanics traditionally have been regarded as Lower Silurian in age. In contrast, most Paleozoic volcanic units in western Iberia are rift-related mafic to felsic rocks emplaced during the Late Cambrian-Early Ordovician, and are attributed to the opening of the Rheic Ocean. We present new zircon U-Pb TIMS data from a mafic volcaniclastic rock within the El Castillo unit. These data yield a near-concordant, upper intercept age of 394.7 ± 1.4 Ma that is interpreted to reflect a Middle Devonian (Emsian-Eifelian) age for the magmatism, demonstrating that the El Castillo volcanic rocks are separated from underlying lower Silurian strata by an unconformity. The U-Pb age is coeval with a widespread extensional event in Iberia preserved in the form of a generalized paraconformity surface described in most of the Iberian Variscan realm. However, in the inner part of the Gondwanan platform, the Cantabrian Zone underwent a major, coeval increase in subsidence and the generation of sedimentary troughs. From this perspective, the eruption age reported here probably represents a discrete phase of incipient rifting along the southern flank of the Rheic Ocean. Paleogeographic reconstructions indicate that this rifting event was coeval with widespread orogeny and ridge subduction along the conjugate northern flank of the Rheic Ocean, the so called Acadian "orogeny". We speculate that ridge subduction resulted in geodynamic coupling of the northern and southern flanks of the Rheic Ocean, and that the extension along the southern flank of the Rheic Ocean is a manifestation of slab pull along the northern flank. This scenario provides a uniform explanation for many features that form at ca. 395 Ma along the Gondwanan margin and has implications for the origin of the coeval oceanic Devonian mafic rocks currently exposed in the Variscan suture of NW Iberia.

Bedrock geologic map of the Littleton and Lower Waterford quadrangles, Essex and Caledonia Counties, Vermont, and Grafton County, New Hampshire

USGS Publications Warehouse

Rankin, Douglas W.

2018-06-13

The bedrock geologic map of the Littleton and Lower Waterford quadrangles covers an area of approximately 107 square miles (277 square kilometers) north and south of the Connecticut River in east-central Vermont and adjacent New Hampshire. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. A large part of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Devonian sedimentary, volcanic, and plutonic rocks. The northwestern part of the map is divided by the Monroe fault which separates Early Devonian rocks of the Connecticut Valley-Gaspé trough from rocks of the Bronson Hill anticlinorium.The Bronson Hill anticlinorium is the apex of the Middle Ordovician to earliest-Silurian Bronson Hill magmatic arc that contains the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic suite, and extends from Maine, down the eastern side of the Connecticut River in New Hampshire, to Long Island Sound. The deformed and partially eroded arc is locally overlain by a relatively thin Silurian section of metasedimentary rocks (Clough Quartzite and Fitch Formation) that thickens to the east. The Silurian section near Littleton is disconformably overlain by a thicker, Lower Devonian section that includes mostly metasedimentary rocks and minor metavolcanic rocks of the Littleton Formation. The Bronson Hill anticlinorium is bisected by a series of northeast-southwest trending Mesozoic normal faults. Primarily among them is the steeply northwest-dipping Ammonoosuc fault that divides older and younger units (upper and lower sections) of the Ammonoosuc Volcanics. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of metamorphic and metasedimentary rocks. The Ammonoosuc Volcanics overlies the Albee Formation that consists of interlayered feldspathic sandstone, siltstone, pelite, and slate.During the Late Ordovician, a series of arc-related plutons intruded the Ammonoosuc Volcanics, including the Whitefield pluton to the east, the Scrag granite of Billing (1937) in the far southeastern corner of the map, the Highlandcroft Granodiorite just to the west of the Ammonoosuc fault, and the Joslin Turn tonalite (just north of the Connecticut River). To the east of the Monroe fault lies the late Silurian Comerford Intrusive Complex, which consists of metamorphosed gabbro, diorite, tonalite, aplitic tonalite, and crosscutting diabase dikes. Abundant mafic dikes of the Comerford Intrusive Complex intruded the Albee Formation and Ammonoosuc Volcanics well east of the Monroe fault.This report consists of a single geologic map sheet and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information.

Discovery of a Devonian mafic magmatism on the western border of the Murzuq basin (Saharan metacraton): Paleomagnetic dating and geodynamical implications

NASA Astrophysics Data System (ADS)

Derder, M. E. M.; Maouche, S.; Liégeois, J. P.; Henry, B.; Amenna, M.; Ouabadi, A.; Bellon, H.; Bruguier, O.; Bayou, B.; Bestandji, R.; Nouar, O.; Bouabdallah, H.; Ayache, M.; Beddiaf, M.

2016-03-01

Intraplate deformation is most often linked to major stress applied on plate margins. When such intraplate events are accompanied by magmatism, the use of several dating methods integrated within a multidisciplinary approach can bring constraints on the age, nature and source mobilized for generating the magma and in turn on the nature of the intraplate deformation. This study focuses on the large gabbro Arrikine sill (35 km in extension) emplaced within the Silurian sediments of the western margin of the Murzuq cratonic basin in southeastern Algeria. Its emplacement is dated during the early Devonian (415-400 Ma) through the determination of a reliable paleomagnetic pole by comparison with the Gondwana Apparent Polar Wander Path (APWP). This age can be correlated with deep phreatic eruptions before Pragian time thought to be at the origin of sand injections and associated circular structures in Algeria and Libya. For the sill, the K-Ar age of 325.6 ± 7.7 Ma is related to a K-rich aplitic phase that has K-enriched by more than 20% the Devonian gabbro. Laser-ICP-MS U-Pb method dates only inherited zircons mostly at c. 2030 Ma with additional ages at c. 2700 Ma and younger ones in the 766-598 Ma age range. The Arrikine sill is a high-Ti alkaline gabbro having the geochemical composition of a hawaiite akin to several intraplate continental and oceanic provinces, including the contemporaneous Aïr ring complexes province in Niger, but also to the Mauna Loa volcano in Hawaii. This peculiar composition akin to that of the contemporaneous Aïr province is in agreement with a lower Devonian age for the Arrikine sill. The lower Devonian Arrikine sill emplacement is related to a "Caledonian" transtensive reactivation of the western metacratonic boundary of the Murzuq craton. This event also generated in the Saharan platform the so-called "Caledonian unconformity" of regional extension, the Aïr ring complexes and magmatic rocks that produced sand injections. It could be related to rifting of the Hun terranes that occurred at the plate margin to the north (Stampfli and Borel, 2002, Blackey, 2008 and references therein). The mid-Carboniferous (c. 326 Ma) reactivation corresponds to Variscan compression on NW Africa generating aplitic fluids, but also to the major "Hercynian unconformity" of regional extension. The generation of the Arrikine magma is attributed to partial melting through adiabatic pressure release of uprising asthenosphere along tectonically reactivated mega-shear zones, here bordering the relictual Murzuq craton enclosed in the Saharan metacraton.

Alligator ridge district, East-Central Nevada: Carlin-type gold mineralization at shallow depths

USGS Publications Warehouse

Nutt, C.J.; Hofstra, A.H.

2003-01-01

Carlin-type deposits in the Alligator Ridge mining district are present sporadically for 40 km along the north-striking Mooney Basin fault system but are restricted to a 250-m interval of Devonian to Mississippian strata. Their age is bracketed between silicified ca. 45 Ma sedimentary rocks and unaltered 36.5 to 34 Ma volcanic rocks. The silicification is linked to the deposits by its continuity with ore-grade silicification in Devonian-Mississippian strata and by its similar ??18O values (_e1???17???) and trace element signature (As, Sb, Tl, Hg). Eocene reconstruction indicates that the deposits formed at depths of ???300 to 800 m. In comparison to most Carlin-type gold deposits, they have lower Au/Ag, Au grades, and contained Au, more abundant jasperoid, and textural evidence from deposition of an amorphous silica precursor in jasperoid. These differences most likely result from their shallow depth of formation. The peak fluid temperature (_e1???230??C) and large ??18OH2O value shift from the meteroric water line (_e1???20???) suggest that ore fluids were derived from depths of 8 km or more. A magnetotelluric survey indicates that the Mooney Basin fault system penetrates to mid-crustal depths. Deep circulation of meteoric water along the Mooney Basin fault system may have been in response to initial uplift of the East Humboldt-Ruby Mountains metamorphic core complex; convection also may have been promoted by increased heat flow associated with large magnitude extension in the core complex and regional magmatism. Ore fluids ascended along the fault system until they encountered impermeable Devonian and Mississippian shales, at which point they moved laterally through permeable strata in the Devonian Guilmette Formation, Devonian-Mississippian Pilot Shale, Mississippian Joana Limestone, and Mississippian Chainman Shale toward erosional windows where they ascended into Eocene fluvial conglomerates and lake sediments. Most gold precipitated by sulfidation of host-rock Fe and mixing with local ground water in zones of lateral fluid flow in reactive strata, such as the Lower Devonian-Mississippian Pilot Shale.

Geology of the Devonian black shales of the Appalachian basin

USGS Publications Warehouse

Roen, J.B.

1983-01-01

Black shales of Devonian age in the Appalachian basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. Concurrent with periodic and varied economic exploitations of the black shales are geologic studies. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies produced a regional stratigraphic network that correlates the 15-foot sequence in Tennessee with 3,000 feet of interbedded black and gray shales in central New York. The classic Devonian black-shale sequence in New York has been correlated with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long range correlations within the Appalachian basin and provided a basis for correlations with the black shales of the Illinois and Michigan basins. Areal distribution of selected shale units along with paleocurrent studies, clay mineralogy, and geochemistry suggests variations in the sediment source and transport directions. Current structures, faunal evidence, lithologic variations, and geochemical studies provide evidence to support interpretation of depositional environments. In addition, organic geochemical data combined with stratigraphic and structural characteristics of the shale within the basin allow an evaluation of the resource potential of natural gas in the Devonian shale sequence.

Terrestrial-marine teleconnections in the Devonian: links between the evolution of land plants, weathering processes, and marine anoxic events

PubMed Central

Algeo, T. J.

1998-01-01

The Devonian Period was characterized by major changes in both the terrestrial biosphere, e.g. the evolution of trees and seed plants and the appearance of multi-storied forests, and in the marine biosphere, e.g. an extended biotic crisis that decimated tropical marine benthos, especially the stromatoporoid-tabulate coral reef community. Teleconnections between these terrestrial and marine events are poorly understood, but a key may lie in the role of soils as a geochemical interface between the lithosphere and atmosphere/hydrosphere, and the role of land plants in mediating weathering processes at this interface. The effectiveness of terrestrial floras in weathering was significantly enhanced as a consequence of increases in the size and geographic extent of vascular land plants during the Devonian. In this regard, the most important palaeobotanical innovations were (1) arborescence (tree stature), which increased maximum depths of root penetration and rhizoturbation, and (2) the seed habit, which freed land plants from reproductive dependence on moist lowland habitats and allowed colonization of drier upland and primary successional areas. These developments resulted in a transient intensification of pedogenesis (soil formation) and to large increases in the thickness and areal extent of soils. Enhanced chemical weathering may have led to increased riverine nutrient fluxes that promoted development of eutrophic conditions in epicontinental seaways, resulting in algal blooms, widespread bottomwater anoxia, and high sedimentary organic carbon fluxes. Long-term effects included drawdown of atmospheric pCO2 and global cooling, leading to a brief Late Devonian glaciation, which set the stage for icehouse conditions during the Permo-Carboniferous. This model provides a framework for understanding links between early land plant evolution and coeval marine anoxic and biotic events, but further testing of Devonian terrestrial-marine teleconnections is needed.

Stratigraphy, depositional environments, and carbonate petrology of the Toroweap and Kaibab Formations (lower Permian), Grand Canyon region, Arizona

NASA Astrophysics Data System (ADS)

Clark, R. A.

Sediments deposited in northwestern Arizona during Late Leonardian and Early Guadalupian (Permian) were controlled chiefly by an arid climate and the tectonic setting. Eastward thrusting of eugeosynclinal rocks onto miogeosynclinal deposits during Middle Devonian to Early Mississippian had a major influence on shelf sedimentation. The Toroweap and Kaibab formations represent two such platform sequences of northwestern Arizona and southern Utah deposited during this phase of sedimentation. The Toroweap Formation is subdivided into three members and represents sediments deposited during initial transgression, maximum extent of the sea, and regression (Seligman, Brady Canyon, and Woods Ranch members respectively). The Fossil Mountain Member of the Kaibab Formation documents the most extensive phase of sedimentation for all members of the Toroweap and Kaibab formations. The Harrisburg Member documents the final phase of sedimentation at the close of the Paleozoic Era.

Evaluation of Methane Sources in Groundwater in Northeastern Pennsylvania

PubMed Central

Molofsky, Lisa J; Connor, John A; Wylie, Albert S; Wagner, Tom; Farhat, Shahla K

2013-01-01

Testing of 1701 water wells in northeastern Pennsylvania shows that methane is ubiquitous in groundwater, with higher concentrations observed in valleys vs. upland areas and in association with calcium-sodium-bicarbonate, sodium-bicarbonate, and sodium-chloride rich waters—indicating that, on a regional scale, methane concentrations are best correlated to topographic and hydrogeologic features, rather than shale-gas extraction. In addition, our assessment of isotopic and molecular analyses of hydrocarbon gases in the Dimock Township suggest that gases present in local water wells are most consistent with Middle and Upper Devonian gases sampled in the annular spaces of local gas wells, as opposed to Marcellus Production gas. Combined, these findings suggest that the methane concentrations in Susquehanna County water wells can be explained without the migration of Marcellus shale gas through fractures, an observation that has important implications for understanding the nature of risks associated with shale-gas extraction. PMID:23560830

Geologic structure and occurrence of gas in part of southwestern New York. Part 1, Structure and gas possibilities of the Oriskany sandstone in Steuben, Yates, and parts of the adjacent counties

USGS Publications Warehouse

Bradley, W.H.; Pepper, J.F.

1941-01-01

The area covered by this report is in southwestern New York and includes a little more than 3,000 square miles in Steuben and Yates counties and parts of the six adjacent counties. This area has been mapped to determine the structural attitude of the exposed rocks, so as to aid those interested in prospecting for natural gas in the Oriskany sandstone of Lower Devonian age.Because of the gentle regional dip toward the southwest, the youngest beds are exposed in the southwest corner of the area, and progressively older beds crop out northeastward in successive bands that strike generally northwest. All the exposed rocks are of Upper Devonian age except those in a narrow belt at the extreme north edge of the area, where a small thickness of Middle Devonian rocks crops out. The maximum thickness of beds so exposed is nearly 4,000 feet, of which the lower part is predominantly soft dark shale and the upper part predominantly fine-grained sandstone and gray shale. All the beds are marine except a few tongues of continental deposits red shale and sandstone and gray mudstone in the youngest beds. All the beds thicken southeastward, so that there is a northwestward convergence between any two lithologic units in the series. More than 30 key horizons that are persistent and distinctive were mapped, and altitudes on these key horizons served as a basis for constructing the structure contour map. Many of the key horizons are formation or member boundaries, but others are the tops or bottoms of limestone or sandstone beds within formations. All the stratigraphic units mapped are purely lithologic. (See pi. 2.)The Tully limestone, which crops out along the northern border of the area, is an easily recognizable and therefore valuable key bed for subsurface correlations in this part of the State. Below the Tully limestone is a thick body of Middle Devonian shales of the Hamilton group which rests on another valuable key bed, the hard, cherty Onondaga limestone, also of Middle Devonian age. Below the Onondaga limestone is the Lower Devonian Oriskany sandstone, which is the gas-producing bed. Unlike the Onondaga, the Oriskany is locally thin or absent.The structure of most of the area is shown by contour lines at 25-foot intervals, but where key horizons are lacking the structure is indicated by dip symbols. Upon the regional south and southwest dip are superposed numerous gentle folds whose axes trend approximately northeastward in the greater part of the area but more nearly eastward in the eastern part. The folds generally tend to become narrower and steeper, and therefore more closely spaced, southwestward. Many of the anticlines fork southwestward, whereas the synclines. tend to fork northeastward. All the folds have a westward or southwestward plunge. Throughout the area the rocks are jointed in two dominant sets one that trends northwest and the other east or northeast. No evident relation .between these joints, which were measured only in the hard, relatively brittle beds, and the individual folds or domes was discernible.The faults are concentrated in the northeastern and southwestern parts of the area and trend either northeastward or northwestward. Some are nearly vertical normal faults; others are steep reverse faults. Subsurface data show that most of the faults increase in throw downward and also that many subsurface faults do not reach the surface. A group of faults in the northwestern part of the Greenwood quadrangle and the southwestern part of the Hornell quadrangle were active during Upper Devonian time, while the Gowanda shale and overlying beds were being deposited. At this stratigraphic horizon the beds in a zone a few hundred feet thick are highly deformed in a wide belt on both sides of the faults. Sandstone layers are thinned out into long stringers or swollen into thick masses and in places are bent acutely without fracture. Thin layers of shale, coquina, and sand have flowed together into intricately plicated zones that lack cleavage and joints. These features show that the sediments were deformed while wet and plastic and buried only a little way below the sea floor. The beds that were laid down over these disturbed zones were not involved in this deformation. Many of the sharper flexures and most of the faults are not evident in the beds several hundred feet stratigraphically higher. Accordingly, broad, gentle folds in these higher beds in parts of the area south and west of the northwest corner of the Greenwood quadrangle may conceal, at considerable depths below them, narrow folds separated by abrupt flexures or faults.Several of the larger streams and rivers occupy strike valleys, and their j courses swing to follow the changing strike of the rocks where they cross ( successive folds. But, with few exceptions, the small streams are not adjusted to the bedrock structure. Domes likely to serve as traps for natural gas are concentrated in the northeastern and southwestern parts of the area. The Wayne-Dundee gas field is in the northeastern part. All the other potentially valuable domes in this part of the area have been drilled and found valueless except one small structural feature in the southern part of the Ovid quadrangle, which, if the Oriskany is present, may trap a small quantity of gas.In the Greenwood quadrangle in the southwestern part of the area there is one gas field and four well-defined domes, all of which may be productive if the Oriskany sandstone is present. In the northwest corner of the quadrangle the dips indicate at least two domes that can be adequately defined and evaluated only by geophysical prospecting. The State Line gas field is in tbe Wellsville quadrangle. In the southeast corner of this quadrangle there are three other domes of comparable size that may also be productive if underlain by the Oriskany sandstone. At other places in the Wellsville quadrangle the dips suggest several anticlinal axes on which analogous productive domes maybe found. The structural features in this quadrangle, however, are defined by contours only in the southeastern part. In the Woodhull quadrangle a large dome east of Jasper may be productive, and the western top of the large Woodhull dome in the southwestern part of the quadrangle seems to warrant drilling, despite the absence of the Oriskany in a well on the eastern top. Two wells drilled in 1936 and 1937 a little northeast of a broad, nearly flat-topped dome in the Hornell quadrangle, a few miles east of Hornell,, struck small flows of gas, suggesting that wells drilled higher on this dome may be productive.In much of the southwestern part of the area seismograph surveys should be of great value in determining the structure at the Tully and Onondaga horizons. Without abundant subsurface control of this sort, the danger of drilling into subsurface faults can hardly be overemphasized. Three closed or nearly closed synclines in the Greenwood and Wellsville quadrangles appear to be favorable places to drill for oil in the shallow sands presumably parts of the Dunkirk sandstone.

Geologic structure and occurrence of gas in part of southwestern New York

USGS Publications Warehouse

Bradley, Wilmot H.; Pepper, James F.; Richardson, G.B.

1941-01-01

The area covered by this report is in southwestern New York and includes a little more than 3,000 square miles in Steuben and Yates counties and parts of the six adjacent counties. This area has been mapped to determine the structural attitude of the exposed rocks, so as to aid those interested in prospecting for natural gas in the Oriskany sandstone of Lower Devonian age.Because of the gentle regional dip toward the southwest, the youngest beds are exposed in the southwest corner of the area, and progressively older beds crop out northeastward in successive bands that strike generally northwest. All the exposed rocks are of Upper Devonian age except those in a narrow belt at the extreme north edge of the area, where a small thickness of Middle Devonian rocks crops out. The maximum thickness of beds so exposed is nearly 4,000 feet, of which the lower part is predominantly soft dark shale and the upper part predominantly fine-grained sandstone and gray shale. All the beds are marine except a few tongues of continental deposits—red shale and sandstone and gray mudstone—in the youngest beds. All the beds thicken southeastward, so that there is a northwestward convergence between any two lithologic units in the series. More than 30 key horizons that are persistent and distinctive were mapped, and altitudes on these key horizons served as a basis for constructing the structure contour map. Many of the key horizons are formation or member boundaries, but others are the tops or bottoms of limestone or sandstone beds within formations. All the stratigraphic units mapped are purely lithologic. (See pl. 2.)The Tully limestone, which crops out along the northern border of the area, is an easily recognizable and therefore valuable key bed for subsurface correlations in this part of the State. Below the Tully limestone is a thick body of Middle Devonian shales of the Hamilton group which rests on another valuable key bed, the hard, cherty Onondaga limestone, also of Middle Devonian age. Below the Onondaga limestone is the Lower Devonian Oriskany sandstone, which is the gas-producing bed. Unlike the Onondaga, the Oriskany is locally thin or absent.The structure of most of the area is shown by contour lines at 25-foot intervals, but, where key horizons are lacking the structure is indicated by dip symbols. Upon the regional south and southwest dip are superposed numerous gentle folds whose axes trend approximately northeastward in the greater part of the area but more nearly eastward in the eastern part. The folds generally tend to become narrower and steeper, and therefore more closely spaced, southwestward. Many of the anticlines fork southwestward, whereas the synclines tend to fork northeastward. All the folds have a westward or southwestward plunge.Throughout the area the rocks are jointed in two dominant sets—one that trends northwest and the other east or northeast. No evident relation between these joints, which were measured only in the hard, relatively brittle beds, and the individual folds or domes was discernible.The faults are concentrated in the northeastern and southwestern parts of the area and trend either northeastward or northwestward. Some are nearly vertical normal faults ; others are steep reverse faults. Subsurface data show that most of the faults increase in throw downward and also that many subsurface faults do not reach the surface. A group of faults in the northwestern part of the Greenwood quadrangle and the southwestern part of the Hornell quadrangle were active during Upper Devonian time, while the Gowanda shale and overlying beds were being deposited. At this stratigraphic horizon the beds in a zone a few hundred feet thick are highly deformed in a wide belt on both sides of the faults. Sandstone layers are thinned out into long stringers or swollen into thick masses and in places are bent acutely without fracture. Thin layers of shale, coquina, and sand have flowed together into intricately plicated zones that lack cleavage and joints. These features show that the sediments were deformed while wet and plastic and buried only a little way below the sea floor. The beds that were laid down over these disturbed zones were not involved in this deformation. Many of the sharper flexures and most of the faults are not evident in the beds several hundred feet stratigraphically higher. Accordingly, broad, gentle folds in these higher beds in parts of the area south and west of the northwest corner of the Greenwood quadrangle may conceal, at considerable depths below them, narrow folds separated by abrupt flexures or faults.Several of the larger streams and rivers occupy strike valleys, and their courses swing to follow the changing strike of the rocks where they cross successive folds. But, with few exceptions, the small streams are not adjusted to the bedrock structure.Domes likely to serve as traps for natural gas are concentrated in the northeastern and southwestern parts of the area. The Wayne-Dundee gas field is in the northeastern part. All the other potentially valuable domes in this part of the area have been drilled and found valueless except one small structural feature in the southern part of the Ovid quadrangle, which, if the Oriskany is present, may trap a small quantity of gas.In the Greenwood quadrangle in the southwestern part of the area there is one gas field and four well-defined domes, all of which may be productive if the Oriskany sandstone is present. In the northwest corner of the quadrangle the dips indicate at least two domes that can be adequately defined and evaluated only by geophysical prospecting. The State Line gas field is in the Wellsville quadrangle. In the southeast corner of this quadrangle there are three other domes of comparable size that may also be productive if underlain by the Oriskany sandstone. At other places in the Wellsville quadrangle the dips suggest several anticlinal axes on which analogous productive domes may be found. The structural features in this quadrangle, however, are defined by contours only in the southeastern part. In the Woodhull quadrangle a large dome east of Jasper may be productive, and the western top of the large Wood-hull dome in the southwestern part of the quadrangle seems to warrant drilling, despite the absence of the Oriskany in a well on the eastern top. Two wells drilled in 1936 and 1937 a little northeast of a broad, nearly flat-topped dome in the Hornell quadrangle, a few miles east of Hornell, struck small flows of gas, suggesting that wells drilled higher on this dome may be productive.In much of the southwestern part of the area seismograph surveys should be of great value in determining the structure at the Tully and Onondaga horizons. Without abundant subsurface control of this sort, the danger of drilling into subsurface faults can hardly be overemphasized.Three closed or nearly closed synclines in the Greenwood and Wellsville quadrangles appear to be favorable places to drill for oil in the shallow sands— presumably parts of the Dunkirk sandstone.

Paleozoic and mesozoic evolution of East-Central California

USGS Publications Warehouse

Stevens, C.H.; Stone, P.; Dunne, G.C.; Greene, D.C.; Walker, J.D.; Swanson, B.J.

1997-01-01

East-central California, which encompasses an area located on the westernmost part of sialic North America, contains a well-preserved record of Paleozoic and Mesozoic tectonic events that reflect the evolving nature of the Cordilleran plate margin to the west. After the plate margin was formed by continental rifting in the Neoproterozoic, sediments comprising the Cordilleran miogeocline began to accumulate on the subsiding passive margin. In east-central California, sedimentation did not keep pace with subsidence, resulting in backstepping of a series of successive carbonate platforms throughout the early and middle Paleozoic. This phase of miogeoclinal development was brought to a close by the Late Devonian-Early Mississippian Antler orogeny, during the final phase of which oceanic rocks were emplaced onto the continental margin. Subsequent Late Mississippian-Pennsylvanian faulting and apparent reorientation of the carbonate platform margin are interpreted to have been associated with truncation of the continental plate on a sinistral transform fault zone. In the Early Permian, contractional deformation in east-central California led to the development of a narrow, uplifted thrust belt flanked by marine basins in which thick sequences of deep-water strata accumulated. A second episode of contractional deformation in late Early Permian to earliest Triassic time widened and further uplifted the thrust belt and produced the recently identified Inyo Crest thrust, which here is correlated with the regionally significant Last Chance thrust. In the Late Permian, about the time of the second contractional episode, extensional faulting created shallow sedimentary basins in the southern Inyo Mountains. In the El Paso Mountains to the south, deformation and plutonism record the onset of subduction and arc magmatism in late Early Permian to earliest Triassic time along this part of the margin. Tectonism had ceased in most of east-central California by middle to late Early Triassic time, and marine sediment deposited on the subsiding continental shelf overlapped the previously deformed Permian rocks. Renewed contractional deformation, probably in the Middle Triassic, is interpreted to be associated with emplacement of the Golconda allochthon onto the margin of the continent. This event, which is identified with certainty in the Sierra Nevada, also may have significantly affected rocks in the White and Inyo Mountains to the east. Subduction and arc magmatism that created most of the Sierra Nevada batholith began in the Late Triassic and lasted through the remainder of the Mesozoic. During this time, the East Sierran thrust system (ESTS) developed as a narrow zone of intense, predominantly E-vergent contractional deformation along the eastern margin of the growing batholith. Activity on the ESTS took place over an extended part of Mesozoic time, both before and after intrusion of voluminous Middle Jurassic plutons, and is interpreted to have been mechanically linked to emplacement of the batholith. Deformation on the ESTS and magmatism in the Sierra Nevada both ended prior to the close of the Cretaceous.

U.S. Geological Survey 2013 assessment of undiscovered resources in the Bakken and Three Forks Formations of the U.S. Williston Basin Province

USGS Publications Warehouse

Gaswirth, Stephanie B.; Marra, Kristen R.

2014-01-01

The Upper Devonian Three Forks and Upper Devonian to Lower Mississippian Bakken Formations comprise a major United States continuous oil resource. Current exploitation of oil is from horizontal drilling and hydraulic fracturing of the Middle Member of the Bakken and upper Three Forks, with ongoing exploration of the lower Three Forks, and the Upper, Lower, and Pronghorn Members of the Bakken Formation. In 2008, the U.S. Geological Survey (USGS) estimated a mean of 3.65 billion bbl of undiscovered, technically recoverable oil resource within the Bakken Formation. The USGS recently reassessed the Bakken Formation, which included an assessment of the underlying Three Forks Formation. The Pronghorn Member of the Bakken Formation, where present, was included as part of the Three Forks assessment due to probable fluid communication between reservoirs. For the Bakken Formation, five continuous and one conventional assessment units (AUs) were defined. These AUs are modified from the 2008 AU boundaries to incorporate expanded geologic and production information. The Three Forks Formation was defined with one continuous and one conventional AU. Within the continuous AUs, optimal regions of hydrocarbon recovery, or “sweet spots,” were delineated and estimated ultimate recoveries were calculated for each continuous AU. Resulting undiscovered, technically recoverable resource estimates were 3.65 billion bbl for the five Bakken continuous oil AUs and 3.73 billion bbl for the Three Forks Continuous Oil AU, generating a total mean resource estimate of 7.38 billion bbl. The two conventional AUs are hypothetical and represent a negligible component of the total estimated resource (8 million barrels of oil).

Early Silurian Foraminifera from Gondwana - an early origin of the multichambered globothalamids?

NASA Astrophysics Data System (ADS)

Kaminski, Michael

2017-04-01

Early Silurian foraminifera until now have been regarded to consist of simple single-chambered monothalamids and two-chambered tubothalamids with an agglutinated wall. Although pseudo-multichambered agglutinated foraminifera first appeared in the mid-Ordovician (Kaminski et al. 2009), the origin of true multichambered forms was not believed to have taken place until the early or middle Devonian at the earliest (Holcová, 2002). New discoveries from the Lower Silurian Qusaiba Shale Member in Saudi Arabia point to an earlier origin of the multichambered globothalamid Foraminifera than the currently accepted estimate of 350 Ma (Pawlowski et al. 2003). The agglutinated foraminiferal genera Ammobaculites and Sculptobaculites have been recovered from dark graptolite-bearing claystones of Telychian age, from the transitional facies between the Qusaiba and Sharawa Members of the Qasim Formation at the type locality near Qusaiba town, Saudi Arabia. The multichambered lituolids occur as rare components in a foraminiferal assemblage consisting mostly of monothalamids. This new finding revises our understanding of the early evolution of the multichambered globothalamid foraminifera. The fossil record now shows that the globothalamids were already present in Gondwana by 435 m.y. Holcová, K. 2002. Silurian and Devonian foraminifers and other acid-resistant microfossils from the Barrandian area. Acta Musei Nationalis Pragae, Series B, Historia Naturalis, 58 (3-4), 83-140. Kaminski, M.A., Henderson, A.S., Cetean, C.G. & Waskowska-Oliwa, A. 2009. A new family of agglutinated foraminifera: the Ammolagenidae n.fam., and the evolution of multichambered tests. Micropaleontology, 55 (5), 487-494. Pawlowski, J., Holzmann, M., Berney, C., Fahrni, J.F., Gooday, Aj., Cedhagen, T., Habura, A., & Bowser, SS. 2003. The evolution of early Foraminifera. Proceedings of the National Academy of Sciences, 100 (20), 11494-11498

Geology and mineral deposits of the Minnie Moore and Bullion mineralized areas, Blaine County, Idaho

USGS Publications Warehouse

Link, Paul Karl; Worl, Ronald G.

2001-01-01

In the early 1880?s the discovery of rich ores in the Minnie Moore and Bullion mineralized areas sparked a rush to settle and develop the Wood River valley. Silver and lead discoveries in these areas spurred the boom in mining after completion of the Oregon Short Line Railroad to Hailey in 1883. In both areas the ore comprises galena, sphalerite, and tetrahedrite in a gangue of siderite, calcite, or quartz. Minor goldbearing quartz veins are also present. The ore is in fissure and replacement veins along fracture systems that formed in Late Cretaceous time, after intrusion of nearby granodiorite or quartz diorite stocks. The ore formed under mesothermal conditions and heat was supplied by the nearby plutons. In the Minnie Moore area, the mineralized veins are cut by low-angle normal faults that are of probable Eocene age. In the Minnie Moore mineralized area, the host rock is the middle part of the Devonian Milligen Formation, (the informal Lucky Coin limestone and Triumph argillite), which is the same stratigraphic level as the host ore in the rich Triumph mine northeast of Hailey. In the Bullion mineralized area, the ore is hosted by the lower member of the Middle Pennsylvanian to Lower Permian Dollarhide Formation. Rich ore was mined in several tunnels that reached the Mayflower vein, a northwest-striking mineralized shear zone. The deposits are thought to be mainly mesothermal veins that formed in association with Cretaceous magmatism. The syngenetic stratiform model of ore formation has often been applied to these deposits, however, no evidence of syngenetic mineralization was found in this study. Faulting has displaced most of the major orebodies and thus has made mining these deposits a challenge.

Givetian ostracods of the Candás Formation (Asturias, North-western Spain): taxonomy, stratigraphy, palaeoecology, relationship to global events and palaeogeographical implications.

PubMed

Maillet, Sebastien; Milhau, Bruno; Vreulx, Michel; Posada, Luis-Carlos Sánchez De

2016-01-27

Asturian ostracods of the Givetian carbonate Candás Formation are documented for the first time from the Peran-Perlora and Carranques reference sections. More than 1,200 specimens were extracted from 44 samples by means of the hot acetolysis method. In all, 75 taxa are described herein, of which 21 are formally described and one, Evlanella peranensis Maillet n. sp., is new. All the taxa are marine benthic and belong to the Eifelian Mega-Assemblage. The assemblages recognized are representative of semi-restricted to shallow open-marine palaeoenvironments above the storm wave base. The stratigraphical distribution of the taxa shows a strong faunal renewal in the top of the Candás Formation. Long-ranging taxa found at the base of the formation, of which many are known from the base of the Middle Devonian, disappear within the base of the member C and are replaced above, around the Middle/Upper Givetian boundary, by more cosmopolitan taxa characteristic of the Frasnian. The lower half of the member C is also characterized both by unstable environments and occurrence of some short-ranging opportunistic ostracod taxa. This renewal within shallow water ostracod communities is probably a consequence of the global Taghanic Biocrisis, leading world-widely to extinctions in several faunal groups. Faunal affinities with Givetian ostracod taxa reported in other areas of the world reflect the commonly accepted palaeogeographical patterns. Close relations between the Cantabrian Zone (NW-Spain), the Armorican Massif (W-France), the Mouthoumet Massif (S-France) and North Africa (Morocco and Algeria) suggest a narrow oceanic space between the western European terranes and the northern Gondwanan margin that involves an advanced phase of closure of the Medio-European Ocean.

Stable isotope analysis of Dacryoconarid carbonate microfossils: a new tool for Devonian oxygen and carbon isotope stratigraphy.

PubMed

Frappier, Amy Benoit; Lindemann, Richard H; Frappier, Brian R

2015-04-30

Dacryoconarids are extinct marine zooplankton known from abundant, globally distributed calcite microfossils in the Devonian, but their shell stable isotope composition has not been previously explored. Devonian stable isotope stratigraphy is currently limited to less common invertebrates or bulk rock analyses of uncertain provenance. As with Cenozoic planktonic foraminifera, isotopic analysis of dacryoconarid shells could facilitate higher-resolution, geographically widespread stable isotope records of paleoenvironmental change, including marine hypoxia events, climate changes, and biocrises. We explored the use of Dacryoconarid isotope stratigraphy as a viable method in interpreting paleoenvironments. We applied an established method for determining stable isotope ratios (δ(13) C, δ(18) O values) of small carbonate microfossils to very well-preserved dacryoconarid shells. We analyzed individual calcite shells representing five common genera using a Kiel carbonate device coupled to a MAT 253 isotope ratio mass spectrometer. Calcite shell δ(13) C and δ(18) O values were compared by taxonomic group, rock unit, and locality. Single dacryoconarid calcite shells are suitable for stable isotope analysis using a Kiel-IRMS setup. The dacryoconarid shell δ(13) C values (-4.7 to 2.3‰) and δ(18) O values (-10.3 to -4.8‰) were consistent across taxa, independent of shell size or part, but varied systematically through time. Lower fossil δ(18) O values were associated with warmer water temperature and more variable δ(13) C values were associated with major bioevents. Dacryoconarid δ(13) C and δ(18) O values differed from bulk rock carbonate values. Dacryoconarid individual microfossil δ(13) C and δ(18) O values are highly sensitive to paleoenvironmental changes, thus providing a promising avenue for stable isotope chemostratigraphy to better resolve regional to global paleoceanographic changes throughout the upper Silurian to the upper Devonian. Our results warrant further exploration of dacryoconarid stable isotope proxy sensitivity, the isotopic contrast among dacryoconarids, other taxa, and bulk rock, as well as other potential dacryoconarid proxies (Mg/Ca, Sr/Ca, (87) Sr/(86) Sr, microlaser and ion microprobe isotope techniques, and clumped isotopes) for stratigraphic research. Copyright © 2015 John Wiley & Sons, Ltd.

The application of improved NeuroEvolution of Augmenting Topologies neural network in Marcellus Shale lithofacies prediction

NASA Astrophysics Data System (ADS)

Wang, Guochang; Cheng, Guojian; Carr, Timothy R.

2013-04-01

The organic-rich Marcellus Shale was deposited in a foreland basin during Middle Devonian. In terms of mineral composition and organic matter richness, we define seven mudrock lithofacies: three organic-rich lithofacies and four organic-poor lithofacies. The 3D lithofacies model is very helpful to determine geologic and engineering sweet spots, and consequently useful for designing horizontal well trajectories and stimulation strategies. The NeuroEvolution of Augmenting Topologies (NEAT) is relatively new idea in the design of neural networks, and shed light on classification (i.e., Marcellus Shale lithofacies prediction). We have successfully enhanced the capability and efficiency of NEAT in three aspects. First, we introduced two new attributes of node gene, the node location and recurrent connection (RCC), to increase the calculation efficiency. Second, we evolved the population size from an initial small value to big, instead of using the constant value, which saves time and computer memory, especially for complex learning tasks. Third, in multiclass pattern recognition problems, we combined feature selection of input variables and modular neural network to automatically select input variables and optimize network topology for each binary classifier. These improvements were tested and verified by true if an odd number of its arguments are true and false otherwise (XOR) experiments, and were powerful for classification.

Cambrian to Devonian evolution of alluvial systems: The sedimentological impact of the earliest land plants

NASA Astrophysics Data System (ADS)

Davies, Neil S.; Gibling, Martin R.

2010-02-01

In present-day alluvial environments, the impact of vegetation on sedimentological processes and deposits is well known. A vegetated catchment may decrease sediment yield, sediment erodibility, Hortonian overland flow, aeolian winnowing of fines, the proportion of sediment transported as bedload, and may increase bank stability, infiltration into substrates, and bed roughness. Vegetation also promotes the production of chemically-weathered clays and soils and the adoption of a meandering style. It is generally understood that, prior to the evolution of terrestrial vegetation during the Early Palaeozoic, ancient alluvial systems were markedly different from modern systems, with many systems adopting a "sheet-braided" style. This understanding has previously informed the interpretations of many Precambrian pre-vegetation alluvial successions, but there has been relatively little work regarding Early Palaeozoic alluvial successions laid down prior to and during the initial colonization of the Earth's surface by plants. A comprehensive review of 144 Cambrian to Devonian alluvial successions documented in published literature was combined with original field data from 34 alluvial successions across Europe and North America. The study was designed to identify changes in alluvial style during the period that vegetation was evolving and first colonizing alluvial environments. An increase in mudrock proportion and sandstone maturity is apparent, along with a decrease in overall sand grain size through the Early Palaeozoic. These trends suggest that primitive vegetation cover promoted the production and preservation of muds from the mid Ordovician onwards and increased the residence time of sand-grade sediment in alluvial systems. The compilation also enables the first stratigraphic occurrence of certain vegetation-dependent sedimentary features to be pinpointed and related to the evolution of specific palaeobotanical adaptations. The first markedly heterolithic alluvial sequences appeared at about the same time as the most primitive terrestrial vegetation in the Ordovician, and prolific pedogenic calcite, charcoal and bioturbated floodplain fines first appeared in the rock record at about the same time as vascular-plant macrofossils became abundant in the late Silurian. Lateral accretion sets in channel deposits appeared near the Silurian-Devonian boundary, at or shortly before the appearance of underground rooting systems, and become progressively more abundant in the record during the Devonian, implying a major expansion of meandering rivers as rooted plants stabilized river banks. Coals become abundant after the development of plant arborescence. The analysis suggests that the evolution of embryophytes had a profound effect on fluvial processes and deposits, and this period of landscape evolution must be considered amongst the most significant environmental and geomorphological changes in Earth history, with profound consequences for all aspects of the Earth system.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Potter, P.E.; Maynard, J.B.; Pryor, W.A.

Studies of shales in the Appalachian area are reported (mainly in the form of abstracts of reports or manuscripts). They discuss the geology, lithology, stratigraphy, radioactivity, organic matter, the isotopic abundance of carbon and sulfur isotopes, etc. of shales in this area with maps. One report discusses Devonian paliocurrents in the central and northern Appalachian basin. Another discusses sedimentology of the Brallier Formation. The stratigraphy of upper Devonian shales along the southern shore of Lake Erie was also studied. (LTN)

Subsurface stratigraphy of upper Devonian clastics in southern West Virginia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neal, D.W.; Patchen, D.G.

Studies of upper Devonian shales and siltstones in southern West Virginia have resulted in a refinement of the stratigraphic framework used in characterizing the gas-producing Devonian shales. Gamma-ray log correlation around the periphery of the Appalachian Basin has extended the usage of New York stratigraphic nomenclature for the interval between the base of the Dunkirk shale and the top of the Tully limestone to southern West Virginia. Equivalents of the Dunkirk shale and younger rocks of New York are recognized in southwestern West Virginia and are named according to Ohio usage. Gas production is primarily from the basal black shalemore » member of the Ohio shale. Gas shows from older black shale units (Rhinestreet and Marcellus shales) are recorded from wells east of the major producing trend. Provided suitable stimulation techniques can be developed, these older and deeper black shales may prove to be another potential gas resource.« less

World class Devonian potential seen in eastern Madre de Dios basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Wagner, J.B.; Carpenter, D.G.

The Madre de Dios basin in northern Bolivia contains thick, laterally extensive, organic-rich Upper Devonian source rocks that reached the oil-generative stage of thermal maturity after trap and seal formation. Despite these facts, less than one dozen exploration wells have been drilled in the Madre de Dios basin, and no significant reserves have been discovered. Mobil geoscientists conducted a regional geological, geophysical, and geochemical study of the Madre de Dios basin. The work reported here was designed to assess the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks. It is supported by data from over 3,000 mmore » of continuous slimhole core in two of the five Mobil wells in the basin. Source potential also exists in Cretaceous, Mississippian, and Permian intervals. The results of this study have important implications for future exploration in Bolivia and Peru.« less

Benefits of applying technology to Devonian shale wells. Topical report, July-December 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Voneiff, G.W.; Gatens, J.M.

1993-01-01

The report summarizes the benefits of applying technology to Devonian Shales wells in the Appalachian Basin. The results of the work suggest that an intermediate level of technology application, with an incremental cost of $6,700/well, is best for routine application in the Devonian Shales. The technology level uses conventional well tests, rock mechanical properties logs, a borehole camera, and a moderate logging suite. Most of these tools and technologies should be used on only a portion of the wells in multi-well projects, reducing the per well cost of the technology. Determining the correct reservoir description is critical to optimizing themore » stimulation treatment. The most critical reservoir properties are bulk and matrix permeabilities, net pay, stress profile, and natural fracture spacing in the direction perpendicular to induced hydraulic fractures. Applying technology to improve the accuracy of the reservoir description can significantly increase well profitability.« less

The Paleotethys suture in Central Iran

NASA Astrophysics Data System (ADS)

Bagheri, S.; Stampfli, G. M.

2003-04-01

The Triassic rocks of the Nakhlak area have been used to justify the hypothesis of the rotation of the Central-East Iranian microplate, mainly based on paleomagnetic data. Davoudzadeh and his coworkers (1981) pointed out the existing contrast between the Nakhlakh succession and the time-equivalent lithostratigraphic units exposed in the surrounding regions and compared them with the Triassic rocks of the Aghdarband area on the southern edge of the Turan plate. We recently gathered evidences that this part of central Iran effectively belongs to the Northern Iranian Paleo-Tethys suture zone and related Variscan terrains of the Turan plate. This is the case for the northwestern part of central Iran, where the Anarak-Khur belt (Anarak schists and their thick Cretaceous-Paleocene sedimentary cover) presents all the elements of an orogenic zone such as dismembered ophiolites and silisiclastics, calcareous and volcanic cover which has been deformed and metamorphosed. This belt is separated to the northwest from the Alborz microcontinent by the Great Kavir fault and Cretaceous ophiolite mélanges. To the southeast it is bounded by the Biabanak fault and serpentinites and the Biabanak block, part of the central-east Iranian plate. The later zone is formed by Proterozoic metamorphic basement and marine sedimentary cover, nearly continuous from the Ordovician to the Triassic, at the uppermost part upper Triassic-lower Jurassic bauxites and silisiclastics are observed. Excepted the Ordovician angular unconformities and the boundary between lower Jurassic and younger layers, this sequence displays no significant main unconformities and can be attributed to the Cimmerian super-terrain. Thus, this sequences represents the classical evolution of the southern Paleo-Tethys passive margin, as found in the Alborz microcontinent or the Band-e Bayan zone of Afghanistan and is the witness of large scale duplication of the Paleo-Tethys suture zone through major Alpine strike-slip faults. Within the Anarak-Khur belt limit and to the northeast of the Nakhlak succession, the area of Godar-e Siah of Jandaq, remnants of the Eurasian active margin are found, represented by: 1- A lower Paleozoic to upper Devonian unit consisting mainly of metamorphosed rocks including ophiolitic rocks, pelagic sediments, flysch-like deposits and shallow-water limestones of Devonian age belonging to the Anarak and Kabudan areas. Folding and thrusting was pre-Carboniferous and all geochronological dating based on K/Ar for the Anarak and Kaboudan schists placed this metamorphic event between middle Devonian and Visean. 2- the main part of the lower Carboniferous unit consists of a volcano-sedimentary complex with intercalations of limestone containing Coral, Brachiopod and Foraminiferas. Pyroclastic deposits are followed by continental red beds containing a great variety of grain types, such as hypabyssal to several types of granitoid rock fragments derived from the arc, accompanied by pebbles of chert, fossiliferous carbonate and serpentinite recycled from the accretionary complex, pointing to a fore-arc environment of deposition. 3- The middle Carboniferous to Permian unit consists of coarse littoral conglomerate and sandstones derived from ophiolitic to felsic material with some platform limestones. They represent the final infill of the fore-arc basin and rest unconformably on both the metamorphites and Lower Carboniferous units. These tectono-stratigraphic units are similar to the western Hindu Kush sequences of Afghanistan and Tuarkyr in Turkmenistan and belong to the northern active margin of Paleo-Tethys. Therefore, the Anarak-Khur belt was part of the Variscan terranes located along this margin. Volcano-sedimentary strata with Conodont-bearing limestones of Permian to Triassic age have been found in direct contact with the Biabanak fault which, therefore, is most likely following and reactivating the Paleo-Tethys suture zone.

Spinel and orthopyroxene exsolved from clinopyroxene in the Haladala pluton in the middle Tianshan (Xinjiang, China)

NASA Astrophysics Data System (ADS)

Zhu, Yongfeng; Chen, Jing; Xue, Yunxin; Feng, Wanyi; Jiang, Jiuyang

2017-12-01

The Haladala pluton, consisting of troctolite, olivine gabbro and gabbro with zircon SHRIMP U-Pb age of 309 ± 2 Ma (MSWD = 0.72), intruded the Devonian-Carboniferous arc segments in the middle Tianshan. Amphibole, coexisting with magnetite, amphibole, and phlogopite, crystallized in a magma chamber at depth of 20 km (6.9-7.4 kbar, 934-943 °C) based on various thermobaramoters. Two kinds of exsolution textures (spinel rods in clinopyroxene, orthopyroxene lamellae in clinopyroxene) occur in troctolite and olivine gabbro. We describe oriented spinel rods and orthopyroxene lamellae exsolved from the host clinopyroxene based on optical and high-resolution transmission electron microscope (HRTEM) observations. The spinel rods (100) are parallel to their host clinopyroxene (010). Orthopyroxene lamellae (010) are coherent and strictly parallel to their host clinopyroxene (010). Exsolution of spinel rods from the host clinopyroxene is controlled by the reaction of (Ca0.5M2+ 0.5)Fe3+[AlSiO6]in clinopyroxene → (Ca0.86-0.17M2+ 0.14-0.17)(M2 + 1.00-0.96Al0-0.04)[Al0.17-0.10Si1.83-1.90O6] + Fe3O4 + O2.

Exploration in Ordovician of central Michigan Basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fisher, J.H.; Barratt, M.W.

1985-12-01

Deep wells in the central Michigan basin have provided sufficient data to define two new mappable formations - the Foster Formation and the Bruggers Formation. Recent conodont studies have corrected the age assignments of the strata containing these formations. Previously, the lower section (Foster) was classified as mostly Cambrian, and the upper unit (Bruggers) was identified as Early Ordovician. Conodont identifications indicate an Early and Middle Ordovician age for the Foster Formation and a Middle Ordovician age for the Bruggers Formation. The Michigan basin existed in embryonic form in the Late Cambrian, but the full outline of the present-day basinmore » did not develop until Early Ordovician. Gas and condensate are produced from the Bruggers Formation as deep as 11,252 ft (3429 m). Geothermal investigations suggest that gas production is possible to the base of the Paleozoic section in the central basin (17,000 ft or 5181 m). Paleotemperatures were higher during the Paleozoic owing to 3000-4000 ft (914-1291 m) of additional sedimentary cover. Five wells are producing from the Bruggers Formation. All are deeper tests in anticlines producing from Devonian reservoirs discovered earlier. The structures are the result of vertical movements of basement fault blocks activated by regional stresses. 12 figures, 2 tables.« less

Geology of the Stroudsburg quadrangle and Adjacent areas, Pennsylvania--New Jersey

USGS Publications Warehouse

Epstein, Jack Burton

1971-01-01

The Stroudsburg area is within the Valley and Ridge and Great Valley physiographic provinces, Northampton and Monroe Counties, Pennsylvania, and Warren County, New Jersey. The northeast-trending subparallel valleys and ridges resulted from erosion of folded heterogeneous sedimentary rocks. These are Middle Ordovician to Middle Devonian in age and are more than 17,000 feet thick. Deposition of a thick flysch sequence (Martinsburg Formation of Ordovician age) accompanied onset of Taconic orogenesis. It was followed by deposition of a thick molasse sequence of Silurian and Early Devonian age (continental and marginal-marine clastics--Shawangunk Formation and Bloomsburg Red Beds--overlain by predominantly marginal-marine and subtidal limestone, dolomite, shale, and sandstone--Poxono Island Formation through Oriskany Group). Basin deepening and gradual shallowing occurred during Esopus through Mahantango deposition, heralding the Acadian clastic wedge exposed north of the Stroudsburg area. Interpretation of sedimentary structures and regional stratigraphic relations suggest that the Silurian and Devonian rocks were deposited in the following environments: A1luviated coastal plain (meandering and braided streams), tidal flats (supratidal and intertidal), barrier zone, and neritic zone (upper and lower). The rock stratigraphic units have been grouped into four lithotectonic units, each having a different style of deformation. Folds produced in these rocks are disharmonic, and it is believed that each rock sequence is set off from units above and below by decollements, or zones of detachment. Movement was northwest into the Appalachian basin, primarily by gravitational sliding. The contact between the Shawangunk Formation of Silurian age and Martinsburg Formation of Ordovician age, is one zone of detachment as well as an angular unconformity. Deformational effects of the Middle to Late Ordovician Taconic orogeny are elusive, but it appears that the folds and most minor structures, including the prominent regional cleavage, were produced during the late Paleozoic Appalachian orogeny and are superimposed upon larger Taconic folds and faults. Field relations and microscopic study suggest that the regional cleavage in the Stroudsburg area is due to laminar flow of pelitic material along cleavage folia accompanied by mechanical reorientation of platy and elongate minerals and neocrystallization of mica, quartz, chlorite, and probably albite. Numerous lines of evidence point to the conclusion that cleavage developed after the rock was indurated and formed at, and Just below, conditions of low-grade metamorphism. Intensity of cleavage development increases to the southeast across the area. Second-generation slip cleavage, also believed to be Appalachian in age, formed by mechanical reorientation of minerals as well as by limited new mineral growth. The topography had a profound effect on the direction of movement of the Wisconsin glacier, as well as the manner of its retreat and the deposits that were formed. Till and stratified drift of Wisconsin age and till of Illinoian(?) age are common in the area. Wisconsin deglaciation occurred by northeastward retreat and by stagnation. A conspicuous terminal moraine marks the limit of Wisconsin ice movement. Lake Sciota was dammed between the retreating ice, the moraine, and the surrounding ridges north of Godfrey Ridge. Several deltas mark ice stand positions during the retreat of the ice. Lake-bottom and kame deposits are locally common in Cherry Valley. South of Kittatinny Mountain, on the other hand, melt water was freely discharged to the south. The wind and water gaps in the Stroudsburg area (including Delaware Water Gap and Wind Gap) are structurally controlled; specifically they are located where folds die out in short distances, where folding is locally more intense, or where resistant rocks dip steeply and have a narrow width of outcrop. This conclusion is contrary to

Peeking out of the basins: looking for the Late Devonian Kellwasser Event in the open ocean in the Central Asian Orogenic Belt, southwestern Mongolia

NASA Astrophysics Data System (ADS)

Thomas, R. M., Jr.; Carmichael, S. K.; Waters, J. A.; Batchelor, C. J.

2017-12-01

Two of the top five most devastating mass extinctions in Earth's history occurred during the Late Devonian (419.2 Ma - 358.9 Ma), and are commonly associated with the black shale deposits of the Kellwasser and Hangenberg ocean anoxia events. Our understanding of these extinction events is incomplete partly due to sample bias, as 95% of the field sites studying the Late Devonian are limited to continental shelves and continental marine basins, and 77% of these sites are derived from the Euramerican paleocontinent. The Samnuuruul Formation at the Hoshoot Shiveetiin Gol locality (HSG), located in southwestern Mongolia, offers a unique opportunity to better understand global oceanic conditions during the Late Devonian. The HSG locality shows a continuous sequence of terrestrial to marine sediments on the East Junggar arc; an isolated, open-ocean island arc within the Central Asian Orogenic Belt (CAOB). Samples from this near shore locality consist of volcanogenic silts, sands and immature conglomerates as well as calc-alkalic basalt lava flows. Offshore sections contain numerous limestones with Late Devonian fossil assemblages. Preliminary biostratigraphy of the associated marine and terrestrial sequences can only constrain the section to a general Late Devonian age, but TIMS analysis of detrital zircons from volcanogenic sediments from the Samnuuruul Formation in localities 8-50 km from the site suggests a late Frasnian age (375, 376 Ma). To provide a more precise radiometric age of the HSG locality, zircon geochronology using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) will be performed at UNC-Chapel Hill. If the HSG section crosses the Frasnian-Famennian boundary, geochemical, mineralogical, and ichnological signatures of the Kellwasser Event are expected to be preserved, if the Kellwasser Event was indeed global in scope (as suggested by Carmichael et al. (2014) for analogous sites on the West Junggar arc in the CAOB). Black shale accumulation anywhere in the CAOB would be unlikely due to the paleoenvironment and arc topography, so additional multiproxy techniques are required for recognition of the Kellwasser Event in regions such as the HSG, which are outside of the basins where they have historically been studied. Carmichael et al. (2014) Paleo3 399, 394-403.

Constraints on Earth degassing history from the argon isotope composition of Devonian atmosphere

NASA Astrophysics Data System (ADS)

Stuart, F. M.; Mark, D.

2012-04-01

The primordial and radiogenic isotopes of the noble gases combine to make them a powerful tool for determining the time and tempo of the outgassing of the Earth's interior. The outgassing history of the Earth is largely constrained from measurements of the isotopic composition of He, Ne, Ar and Xe in samples of modern mantle, crust and atmosphere. There have been few unequivocal measurement of the isotopic composition of noble gases in ancient atmosphere. We have re-visited whether ancient Ar is trapped in the ~400 Ma Rhynie chert [1]. We have analysed samples of pristine Rhynie chert using the ARGUS multi-collector mass spectrometer calibrated against the new determination of atmospheric Ar isotope ratios [2]. 40Ar/36Ar ratios are low, with many lower than the modern air value (298.8). Importantly these are accompanied by atmospheric 38Ar/36Ar ratios indicating that the low 40Ar/36Ar are not due to mass fractionation. We conclude that the Rhynie chert has captured Devonian atmosphere-derived Ar. The data indicate that the Devonian atmosphere 40Ar/36Ar was at least 3 % lower than the modern air value. Thus the Earth's atmosphere has accumulated at least 5 ± 0.2 x 1016 moles of 40Ar in the last 400 million years, at an average rate of 1.24 ± 0.06 x 108 mol 40Ar/year. This overlaps the rate determined from ice cores for the last 800,000 years [3] and implies that there has been no resolvable temporal change in Earth outgassing rate since mid-Palaeozoic times. The new data require the Earth outgassed early, and suggests that pristine samples of Archaean and Proterozoic chert may prove useful as palaeo-atmosphere tracers. [1] G. Turner, J. Geol. Soc. London 146, 147-154 (1989) [2] D. Mark, F.M. Stuart, M. de Podesta, Geochim. Cosmochim. Acta 75, 7494-7501 [3] M. Bender et al., Proc. Nat. Acad. Sci. 105, 8232-8237 (2008)

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes in central Iran: New geological data, relationships and tectonic implications

NASA Astrophysics Data System (ADS)

Bagheri, Sasan; Stampfli, Gérard M.

2008-04-01

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian-Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician-Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block. The "Variscan accretionary complex" is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New 40Ar/ 39Ar ages are obtained as 333-320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian-Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some 40Ar/ 39Ar radiometric ages of 163-156 Ma. The "Variscan" accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280-230 Ma 40Ar/ 39Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U-Pb age for the trondhjemite-rhyolite association of that area. The Triassic Bayazeh flysch filled the foreland basin during the final closure of the Paleo-Tethys Ocean and was partly deposited and/or thrusted onto the Cimmerian Yazd block. The Paleo-Tethys magmatic arc products have been well-preserved in the Late Devonian-Carboniferous Godar-e-Siah intra-arc deposits and the Triassic Nakhlak fore-arc succession. On the passive margin of the Cimmerian block, in the Yazd region, the nearly continuous Upper Paleozoic platform-type deposition was totally interrupted during the Middle to Late Triassic. Local erosion, down to Lower Paleozoic levels, may be related to flexural bulge erosion. The platform was finally unconformably covered by Liassic continental molassic deposits of the Shemshak. One of the extensional periods related to Neo-Tethyan back-arc rifting in Late Cretaceous time finally separated parts of the Eocimmerian collisional domain from the Eurasian Turan domain. The opening and closing of this new ocean, characterized by the Nain and Sabzevar ophiolitic mélanges, finally transported the Anarak-Jandaq composite terrane to Central Iran, accompanied by large scale rotation of the Central-East Iranian Microcontinent (CEIM). Due to many similarities between the Posht-e-Badam metamorphic complex and the Anarak-Jandaq composite terrane, the former could be part of the latter, if it was transported further south during Tertiary time.

Insect herbivory fluctuations through geological time.

PubMed

Pinheiro, Esther R S; Iannuzzi, Roberto; Duarte, Leandro D S

2016-09-01

Arthropods and land plants are the major macroscopic sources of biodiversity on the planet. Knowledge of the organization and specialization of plant-herbivore interactions, such as their roles in food webs is important for understanding the processes for maintaining biodiversity. A limited number of studies have examined herbivory through geological time. The most have analyzed localities from one restricted interval within a geological period, or a time transition such as the Paleocene-Eocene boundary interval. In the present study, we analyzed the frequency of herbivory and density of damage type (DT) from the Middle Devonian to the early Miocene. The data were compiled from literature sources and focused on studies that describe occurrences of leaves with DTs indicating herbivore consumption as a proportion of the total number of leaves analyzed. The data were standardized based on the DT categories in the Damage Type Guide, and the age of each locality was updated based on the most recent geochronological standard and expressed in millions of years. Temperature and geological age were the best descriptors of the variation in herbivory frequency, which tended to increase at higher temperatures. Two models were equivalent to explain DT density: the interaction between CO 2 levels and geological age, and O 2 levels and geological age had the same predictive power. The density of DT tended to increase with higher content of atmospheric CO 2 and O 2 compared to modern values. The frequency of herbivory and the density of DTs appear to be influenced by long-term atmospheric variables. © 2016 by the Ecological Society of America.

Geochronology and geochemistry of basaltic rocks from the Sartuohai ophiolitic mélange, NW China: Implications for a Devonian mantle plume within the Junggar Ocean

NASA Astrophysics Data System (ADS)

Yang, Gaoxue; Li, Yongjun; Santosh, M.; Yang, Baokai; Yan, Jing; Zhang, Bing; Tong, Lili

2012-10-01

The West Junggar domain in NW China is a distinct tectonic unit of the Central Asian Orogenic Belt (CAOB). It is composed of Paleozoic ophiolitic mélanges, arcs and accretionary complexes. The Sartuohai ophiolitic mélange in the eastern West Junggar forms the northeastern part of the Darbut ophiolitic mélange, which contains serpentinized harzburgite, pyroxenite, dunite, cumulate, pillow lava, abyssal radiolarian chert and podiform chromite, overlain by the Early Carboniferous volcano-sedimentary rocks. In this paper we report new geochronological and geochemical data from basaltic and gabbroic blocks embedded within the Sartuohai ophiolitic mélange, to assess the possible presence of a Devonian mantle plume in the West Junggar, and evaluate the petrogenesis and implications for understanding of the Paleozoic continental accretion of CAOB. Zircon U-Pb analyses from the alkali basalt and gabbro by laser ablation inductively coupled plasma mass spectrometry yielded weighted mean ages of 375 ± 2 Ma and 368 ± 11 Ma. Geochemically, the Sartuohai ophiolitic mélange includes at least two distinct magmatic units: (1) a Late Devonian fragmented ophiolite, which were produced by ca. 2-10% spinel lherzolite partial melting in arc-related setting, and (2) contemporary alkali lavas, which were derived from 5% to 10% garnet + minor spinel lherzolite partial melting in an oceanic plateau or a seamount. Based on detailed zircon U-Pb dating and geochemical data for basalts and gabbros from the Sartuohai ophiolitic mélange, in combination with previous work, indicate a complex evolution by subduction-accretion processes from the Devonian to the Carboniferous. Furthermore, the alkali basalts from the Sartuohai ophiolitic mélange might be correlated to a Devonian mantle plume-related magmatism within the Junggar Ocean. If the plume model as proposed here is correct, it would suggest that mantle plume activity significantly contributed to the crustal growth in the CAOB.

Late Paleozoic SEDEX deposits in South China formed in a carbonate platform at the northern margin of Gondwana

NASA Astrophysics Data System (ADS)

Qiu, Wenhong Johnson; Zhou, Mei-Fu; Liu, Zerui Ray

2018-05-01

SEDEX sulfide deposits hosted in black shale and carbonate are common in the South China Block. The Dajiangping pyrite deposit is the largest of these deposits and is made up of stratiform orebodies hosted in black shales. Sandstone interlayered with stratiform orebodies contains detrital zircon grains with the youngest ages of 429 Ma. Pyrite from the orebodies has a Re-Os isochron age of 389 ± 62 Ma, indicative of formation of the hosting strata and syngenetic pyrite ores in the mid-late Devonian. The hosting strata is a transgression sequence in a passive margin and composed of carbonaceous limestone in the lower part and black shales in the upper part. The ore-hosting black shales have high TOC (total organic carbon), Mo, As, Pb, Zn and Cd, indicating an anoxic-euxinic deep basin origin. The high redox proxies, V/(V + Ni) > 0.6 and V/Cr > 1, and the positive correlations of TOC with Mo and V in black shales are also consistent with an anoxic depositional environment. The Dajiangping deposit is located close to the NE-trending Wuchuan-Sihui fault, which was active during the Devonian. The mid-late Devonian mineralization age and the anoxic-euxinic deep basinal condition of this deposit thus imply that the formation of this deposit was causally linked to hydrothermal fluid exhalation in an anoxic fault-bounded basin that developed in a carbonate platform of the South China Block. The regional distribution of many Devonian, stratiform, carbonaceous sediment-hosted sulfide deposits along the NE-trending fault-bounded basins in South China, similar to the Dajiangping deposit, indicates that these deposits formed at a basin developed in the passive margin setting of the South China Block during the Devonian. This environment was caused by the break-up and northward migration of the South China Block from Gandwana.

Rare earth and trace elements of fossil vertebrate bioapatite as palaeoenvironmental and sedimentological proxies

NASA Astrophysics Data System (ADS)

Žigaitė, Živilė; Fadel, Alexandre; Pérez-Huerta, Alberto; Jeffries, Teresa

2015-04-01

Rare earth (REE) and trace element compositions of fossil vertebrate dental microremains have been studied in Silurian and Devonian vertebrate dental scales and spines in-situ, using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Samples were selected from the well-known Silurian bone beds of Vesiku and Ohesaare in Saaremaa island of Estonia, and a number of Lower Devonian localities from Spitsbergen (Svalbard), Andrée Land group. Biomineral preservation was assessed using spot semi-quantitative elemental chemistry (SEM-EDS) and electron back-scatter difractometry (EBSD) for cristallinity imaging. The obtained PAAS shale-normalised REE concentrations were evaluated using basic geochemical calculations and quantifications. The REE patterns from the Lower Devonian vertebrate apatite from Andrée Land, Spitsbergen (Wood Bay and Grey Hœk formations) did not show any recognisable taxon-specific behavior, but had rather well expressed differences of REE compositions related to biomineral structure and sedimentary settings, suggesting REE instead to reflect burial environments and sedimentological history. The Eu anomaly recorded in two of the studied localities but not in the other indicate different taphonomic conditions and palaeoenvironment, while La/Sm, La/Yb ratios sugeest considerable influence of terrestrial freshwater during the early diagenesis. The La/Yb and La/Sm plots also agree with the average REE concentrations, reflecting domination of the adsoption over substitution as principal REE uptake mechanism in the fossils which had significantly lower overall REE concentrations, and vice versa. Vesiku (Homerian, Wenlock) microremains yielded very uniform REE patterns with slightly lower overall REE concentrations in enameloid than in dentine, with strong enrichment in middle REE and depletion in heavy REE. Negative Europium (Eu) anomaly was pronounced in all the profiles, but Cerium (Ce) anomalies were not detected suggesting possible suboxic to anoxic conditions of the bottom and pore waters during the formation of Vesiku bone bed. In Ohesaare (Pridoli), the REE compositions were nearly identical across all the morphotypes and histologies of acanthodian microremains showing flat REE patterns with slight depletion in HREE. There were no visible enrichment in MREE, indicating relatively good preservation of original bioapatite and likely absence of any pronounced fractionated REE incorporation during later stages of diagenesis. The shale normalised (La/Yb)SN and (La/Sm)SN REE ratio compilations showed addsorption as dominating REE uptake mechanism across all the studied microfossils. The absence of well-defined Ce anomaly suggest oxic palaeoseawater conditions, which agrees with existing interpretations of Ohesaare sequence as high-energy shoal and regressive open ocean sedimentary environment.

Hearing of the African lungfish (Protopterus annectens) suggests underwater pressure detection and rudimentary aerial hearing in early tetrapods.

PubMed

Christensen, Christian Bech; Christensen-Dalsgaard, Jakob; Madsen, Peter Teglberg

2015-02-01

In the transition from an aquatic to a terrestrial lifestyle, vertebrate auditory systems have undergone major changes while adapting to aerial hearing. Lungfish are the closest living relatives of tetrapods and their auditory system may therefore be a suitable model of the auditory systems of early tetrapods such as Acanthostega. Therefore, experimental studies on the hearing capabilities of lungfish may shed light on the possible hearing capabilities of early tetrapods and broaden our understanding of hearing across the water-to-land transition. Here, we tested the hypotheses that (i) lungfish are sensitive to underwater pressure using their lungs as pressure-to-particle motion transducers and (ii) lungfish can detect airborne sound. To do so, we used neurophysiological recordings to estimate the vibration and pressure sensitivity of African lungfish (Protopterus annectens) in both water and air. We show that lungfish detect underwater sound pressure via pressure-to-particle motion transduction by air volumes in their lungs. The morphology of lungfish shows no specialized connection between these air volumes and the inner ears, and so our results imply that air breathing may have enabled rudimentary pressure detection as early as the Devonian era. Additionally, we demonstrate that lungfish in spite of their atympanic middle ear can detect airborne sound through detection of sound-induced head vibrations. This strongly suggests that even vertebrates with no middle ear adaptations for aerial hearing, such as the first tetrapods, had rudimentary aerial hearing that may have led to the evolution of tympanic middle ears in recent tetrapods. © 2015. Published by The Company of Biologists Ltd.

Combined Detrital U/Pb Zircon and 40Ar/39Ar Mica Geoochronology to Test Structural Models for a Devonian Orogenic Collapse Basin in the Norwegian Caledonides

NASA Astrophysics Data System (ADS)

Templeton, J.; Anders, M.; Fossen, H.

2014-12-01

The Hornelen basin is the largest of the Devonian 'Old Red' sandstone basins in Norway, comprising 25 km of alluvial-fluvial deposits which are organized into basin-wide, coarsening-upward megacycles. Hornelen sits with several smaller basins in the hanging wall a major extensional shear zone along which the ultra-high pressure metamorphic core of subducted Baltican crust was rapidly exhumed during the extensional collapse of the Caledonian orogeny. The timing of orogenic collapse corresponds closely to the timing of the basins, which are loosely constrained by sparse trace-fossil assemblages to a mid-Devonian age. Further, the basins are now in brittle fault contact with the underlying mylonitic shear zone and the metamorphic core, implying that they are the upper-crustal expression of large-scale extension and deep-crustal exhumation. Two distinct structural models have been proposed for Hornelen to account for these observations. The strike-slip model juxtaposes different source terranes across the basin-controlling fault and predicts spatially changing provenance within chronostratigraphic units. The supradetachment model links the filling of the basin directly to unroofing of the metamorphic core on a low-angle detachment fault, and predicts basin-wide changes in provenance through time with progressive exhumation of the metamorphic hinterland. We present an extensive new provenance dataset, spanning the Hornelen basin strata through space and time. Detrital zircon U/Pb ages from 18 new samples comprise three distinct populations (1.6, 1.0, and 0.43 Ga) with the Caledonian-aged zircons (ca 0.43 Ga) present mainly along the northern margin of the basin, representing an Upper Allochthon source not found on the southern or eastern margins of the basin. Juxtaposition of different source terranes across the basin supports the strike-slip model. 40Ar/39Ar detrital white mica from the same sample set documents a younging of the dominant age peak from 432 Ma in the oldest sediments to 401 Ma in the youngest units, but does not document any difference between northern and southern mica sources. This trend supports the supradetachment model, but may also be explained by passive, isostatically-driven erosional unroofing of the overthickened orogenic crust.

Provenance and petrofacies, Upper Devonian sandstones, Philip Smith Mountains and Arctic quandrangles, Brooks Range, Alaska: Final report, Project No. 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, A.V.; Coney, P.J.

1987-11-01

Late Devonian sandstone beds are exposed as allochthonous sequences that extend for over 1000 km along the east-west strike of the Brooks Range in northern Alaska. These horizons, at least in part, record Late Devonian tectonism and deposition along the southern margin of the Arctic Alaska block. This study identifies clastic petrofacies in the western Philip Smith Mountains and southern Arctic quadrangles and infers the composition of the source terrane. The paleogeography is not known and the original distribution of lithofacies is uncertain, owing to the extensive post-depositional tectonism. In the study area the sandstones are exposed along rugged mountainmore » tops and high ridges. Although exposures are excellent, access is often difficult. Samples were collected from exposures near the western end of the Chandalar Shelf, Atigun Pass, and the Atigun River valley in the Philip Smith Mountains quadrangle and from the Crow Nest Creek and Ottertail Creek areas in the Arctic quadrangle. 34 refs., 17 figs.« less

Wangshangkia, a new Devonian ostracod genus from Dushan of Guizhou, South China

NASA Astrophysics Data System (ADS)

Song, Junjun; Gong, Yiming

2018-02-01

Wangshangkia, a new genus of Ostracoda, from the Late Devonian in Dushan of Guizhou, South China, is described. This genus belongs to the family Bairdiocyprididae Shaver, 1961 and includes two new species, i.e. Wangshangkia dushaniensis and W. bailouiensis. The new genus is characterized by a wide ventral carina with radial striae. It is reported from the Famennian of South China and disappeared just below the Devonian-Carboniferous boundary. Wangshangkia is essentially a benthic crawler and is restricted to the shallow-marine depositional environment with a low hydrodynamic condition. Wangshangkia: urn:lsid:zoobank.org:act:34BF01D4-D202-492D-8E27-BC508EF7EFFB W. dushaniensis: urn:lsid:zoobank.org:act:D267C362-7510-4D19-996B-EA1848D7D025 W. bailouiensis: urn:lsid:zoobank.org:act:FE988AA0-7363-4D9E-A5AB-1526C8DBCDD9

Paleozoic evolution of active margin basins in the southern Central Andes (northwestern Argentina and northern Chile)

NASA Astrophysics Data System (ADS)

Bahlburg, H.; Breitkreuz, C.

The geodynamic evolution of the Paleozoic continental margin of Gondwana in the region of the southern Central Andes is characterized by the westward progression of orogenic basin formation through time. The Ordovician basin in the northwest Argentinian Cordillera Oriental and Puna originated as an Early Ordovician back-arc basin. The contemporaneous magmatic arc of an east-dipping subduction zone was presumably located in northern Chile. In the back-arc basin, a ca. 3500 meter, fining-up volcaniclastic apron connected to the arc formed during the Arenigian. Increased subsidence in the late Arenigian allowed for the accomodation of large volumes of volcaniclastic turbidites during the Middle Ordovician. Subsidence and sedimentation were caused by the onset of collision between the para-autochthonous Arequipa Massif Terrane (AMT) and the South American margin at the Arenigian-Llanvirnian transition. This led to eastward thrusting of the arc complex over its back-arc basin and, consequently, to its transformation into a marine foreland basin. As a result of thrusting in the west, a flexural bulge formed in the east, leading to uplift and emergence of the Cordillera Oriental shelf during the Guandacol Event at the Arenigian-Llanvirnian transition. The basin fill was folded during the terminal collision of the AMT during the Oclóyic Orogeny (Ashgillian). The folded strata were intruded post-tectonically by the presumably Silurian granitoids of the "Faja Eruptiva de la Puna Oriental." The orogeny led to the formation of the positive area of the Arco Puneño. West of the Arco Puneño, a further marine basin developed during the Early Devonian, the eastern shelf of which occupied the area of the Cordillera Occidental, Depresión Preandina, and Precordillera. The corresponding deep marine turbidite basin was located in the region of the Cordillera de la Costa. Deposition continued until the basin fill was folded in the early Late Carboniferous Toco Orogeny. The basin originated as an extensional structure at the continental margin of Gondwana. Independent lines of evidence imply that basin evolution was not connected to subduction. Thus, the basin could not have been in a fore-arc position as previously postulated. Above the folded Devonian-Early Carboniferous strata, a continental volcanic arc developed from the Late Carboniferous to the Middle Triassic. It represents the link between the Choiyoi Province in central Chile and Argentina, and the Mitu Group rift in southern Peru. The volcanic arc succession is characterized by the prevalence of silicic lavas and tuffs and volcaniclastic sedimentary rocks. During the latest Carboniferous, a thick ostracod-bearing lacustrine unit formed in an extended lake in the area of the Depresión Preandina. This lake basin originated in an intra-arc tensional setting. During the Early Permian, marine limestones were deposited on a marine platform west and east of the volcanic arc, connected to the depositional area of the Copacabana Formation in southern Peru.

Plate collision and mounting building separated by long periods of time. Possible causes

NASA Astrophysics Data System (ADS)

Artyushkov, Eugene; Chekhovich, Peter; Massonne, Hans-Joachim

2017-04-01

According to a popular scheme of orogenesis, superposition of thick nappe on continental crust results in concomitant mountain building. In many cases plate collision was not accompanied by mountain building which actually occurred 10-100 Myr later. Thus in East Carpathians 12 Ma ago thick nappe was superimposed on the western margin of the East European Craton. The nappe remained near to sea level and mountain building began only 3 myr ago. In the Middle Urals collision developed in a number of phases during 70 Myr since the Late Devonian and until the earliest Permian; however, this produced no high topography. The formation of orogenic granitoids took place at the main stage of collision 306-300 Ma ago. High mountains were formed in the earliest Permian 10 Myr after the end of collision. In the Northern Tien Shan collision with intrusion of large granitic plutons occurred in the Late Ordovician-Middle Devonian. In the Southern Tien Shan these phenomena refer to the Late Carboniferous and Late Jurassic. In both regions collision was not accompanied by mountain building. High mountains were formed in the Tien Shan quite recently. Shortening of strong lithospheric layer becomes possible only at short epochs of its softening under infiltration of fluids from the mantle. The absence of large uplift during shortening and thickening of the crust indicates a concomitant density increase in this layer. As follows from the analysis of typical phase diagrams of crustal rocks this can be explained by metamorphic reactions taking place in a presence of fluids under the pressure increase due to the nappe emplacement. As follows from the absence of large crustal uplift in shortened regions mantle lithosphere remains preserved in them after plate collision. At the epochs of infiltration from the mantle of large volumes of fluids it becomes softened. This ensures a possibility of convective replacement by the asthenosphere of fertile and dense mantle lithosphere of the Phanerozoic age which should result in a strong isostatic crustal uplift. Pronounced asthenospheric upwelling is indeed observed under high mountains in many Phanerozoic fold belts. New temperature distribution arises in the thickened crust after its shortening. As a result retrograde metamorphism with expansion became possible in dense rocks which underwent deep metamorphism at the preceding epochs of collision. This is another mechanism of mountain building. Analysis of the data on the Tien Shan shows that both these mechanisms are responsible for its uplift by 2 km and more during the last 2 Myr. In the gravity field the force acting along the lithospheric layer that necessary to shorten the crust increases with the altitude of topography. Termination of shortening after reaching only a very low altitude indicates that the forces which ensure collision are not large. They can be estimated as 3 × 1012 N m which is comparable with the plate driving force of ridge push.

Further study of Late Devonian seed plant Cosmosperma polyloba: its reconstruction and evolutionary significance.

PubMed

Liu, Le; Wang, Deming; Meng, Meicen; Xue, Jinzhuang

2017-06-26

The earliest seed plants in the Late Devonian (Famennian) are abundant and well known. However, most of them lack information regarding the frond system and reconstruction. Cosmosperma polyloba represents the first Devonian ovule in China and East Asia, and its cupules, isolated synangiate pollen organs and pinnules have been studied in the preceding years. New fossils of Cosmosperma were obtained from the type locality, i.e. the Leigutai Member of the Wutong Formation in Fanwan Village, Changxing County, Zhejiang Province, South China. The collection illustrates stems and fronds extensively covered in prickles, as well as fertile portions including uniovulate cupules and anisotomous branches bearing synangiate pollen organs. The stems are unbranched and bear fronds helically. Fronds are dimorphic, displaying bifurcate and trifurcate types, with the latter possibly connected to fertile rachises terminated by pollen organs. Tertiary and quaternary rachises possessing pinnules are arranged alternately (pinnately). The cupule is uniovulate and the ovule has four linear integumentary lobes fused in basal 1/3. The striations on the stems and rachises may indicate a Sparganum-type cortex. Cosmosperma further demonstrates diversification of frond branching patterns in the earliest seed plants. The less-fused cupule and integument of this plant are considered primitive among Devonian spermatophytes with uniovulate cupules. We tentatively reconstructed Cosmosperma with an upright, semi-self-supporting habit, and the prickles along stems and frond rachises were interpreted as characteristics facilitating supporting rather than defensive structures.

Pre-lithification tectonic foliation development in a clastic sedimentary sequence

NASA Astrophysics Data System (ADS)

Meere, Patrick; Mulchrone, Kieran; McCarthy, David; Timmermann, Martin; Dewey, John

2016-04-01

The current view regarding the timing of regionally developed penetrative tectonic fabrics in sedimentary rocks is that their development postdates lithification of those rocks. In this case fabric development is achieved by a number of deformation mechanisms including grain rigid body rotation, crystal-plastic deformation and pressure solution (wet diffusion). The latter is believed to be the primary mechanism responsible for shortening and the domainal structure of cleavage development commonly observed in low grade metamorphic rocks. In this study we combine field observations with strain analysis and modelling to fully characterise considerable (>50%) mid-Devonian Acadian crustal shortening in a Devonian clastic sedimentary sequence from south west Ireland. Despite these high levels of shortening and associated penetrative tectonic fabric there is a marked absence of the expected domainal cleavage structure and intra-clast deformation, which are expected with this level of deformation. In contrast to the expected deformation processes associated with conventional cleavage development, fabrics in these rocks are a product of translation, rigid body rotation and repacking of extra-formational clasts during deformation of an un-lithified clastic sedimentary sequence.

First Record of Soft Tissue Preservation in the Upper Devonian of Poland

PubMed Central

Zatoń, Michał; Broda, Krzysztof

2015-01-01

Soft tissue preservation is reported from Upper Devonian deposits of the Holy Cross Mountains, central Poland, for the first time. The preserved soft tissues are muscles associated with arthropod cuticle fragments. The muscles are phosphatized with variable states of preservation. Well-preserved specimens display the typical banding of striated muscles. Other muscle fragments are highly degraded and/or recrystallized such that their microstructure is barely visible. The phosphatized muscles and associated cuticle are fragmented, occur in patches and some are scattered on the bedding plane. Due to the state of preservation and the lack of diagnostic features, the cuticle identification is problematic; however, it may have belonged to a phyllocarid crustacean. Taphonomic features of the remains indicate that they do not represent fossilized fecal matter (coprolite) but may represent a regurgitate, but the hypothesis is difficult to test. Most probably they represent the leftover remains after arthropod or fish scavenging. The present study shows that soft tissues, which even earlier were manipulated by scavenger, may be preserved if only special microenvironmental conditions within and around the animal remains are established. PMID:26559060

First Record of Soft Tissue Preservation in the Upper Devonian of Poland.

PubMed

Zatoń, Michał; Broda, Krzysztof

2015-01-01

Soft tissue preservation is reported from Upper Devonian deposits of the Holy Cross Mountains, central Poland, for the first time. The preserved soft tissues are muscles associated with arthropod cuticle fragments. The muscles are phosphatized with variable states of preservation. Well-preserved specimens display the typical banding of striated muscles. Other muscle fragments are highly degraded and/or recrystallized such that their microstructure is barely visible. The phosphatized muscles and associated cuticle are fragmented, occur in patches and some are scattered on the bedding plane. Due to the state of preservation and the lack of diagnostic features, the cuticle identification is problematic; however, it may have belonged to a phyllocarid crustacean. Taphonomic features of the remains indicate that they do not represent fossilized fecal matter (coprolite) but may represent a regurgitate, but the hypothesis is difficult to test. Most probably they represent the leftover remains after arthropod or fish scavenging. The present study shows that soft tissues, which even earlier were manipulated by scavenger, may be preserved if only special microenvironmental conditions within and around the animal remains are established.

Repeated kimberlite magmatism beneath Yakutia and its relationship to Siberian flood volcanism: Insights from in situ U-Pb and Sr-Nd perovskite isotope analysis

NASA Astrophysics Data System (ADS)

Sun, Jing; Liu, Chuan-Zhou; Tappe, Sebastian; Kostrovitsky, Sergey I.; Wu, Fu-Yuan; Yakovlev, Dmitry; Yang, Yue-Heng; Yang, Jin-Hui

2014-10-01

We report combined U-Pb ages and Sr-Nd isotope compositions of perovskites from 50 kimberlite occurrences, sampled from 9 fields across the Yakutian kimberlite province on the Siberian craton. The new U-Pb ages, together with previously reported geochronological constraints, suggest that kimberlite magmas formed repeatedly during at least 4 episodes: Late Silurian-Early Devonian (419-410 Ma), Late Devonian-Early Carboniferous (376-347 Ma), Late Triassic (231-215 Ma), and Middle/Late Jurassic (171-156 Ma). Recurrent kimberlite melt production beneath the Siberian craton - before and after flood basalt volcanism at 250 Ma - provides a unique opportunity to test existing models for the origin of global kimberlite magmatism. The internally consistent Sr and Nd isotope dataset for perovskites reveals that the Paleozoic and Mesozoic kimberlites of Yakutia have distinctly different initial radiogenic isotope compositions. There exists a notable increase in the initial 143Nd/144Nd ratios through time, with an apparent isotopic evolution that is intermediate between that of Bulk Earth and Depleted MORB Mantle. While the Paleozoic samples range between initial 87Sr/86Sr of 0.7028-0.7034 and 143Nd/144Nd of 0.51229-0.51241, the Mesozoic samples show values between 0.7032-0.7038 and 0.51245-0.51271, respectively. Importantly, perovskites from all studied Yakutian kimberlite fields and age groups have moderately depleted initial εNd values that fall within a relatively narrow range between +1.8 and +5.5. The perovskite isotope systematics of the Yakutian kimberlites are interpreted to reflect magma derivation from the convecting upper mantle, which appears to have a record of continuous melt depletion and crustal recycling throughout the Phanerozoic. The analyzed perovskites neither record highly depleted nor highly enriched isotopic components, which had been previously identified in likely plume-related Siberian Trap basalts. The Siberian craton has frequently been suggested to represent a type example of an association between kimberlite eruptions and flood basaltic volcanism within a single large igneous province (LIP), but our new extensive age and isotopic tracer constraints do not support a genetic link between these contrasting types of mantle-derived magmatism.

Continental crust melting induced by subduction initiation of the South Tianshan Ocean: Insight from the Latest Devonian granitic magmatism in the southern Yili Block, NW China

NASA Astrophysics Data System (ADS)

Bao, Zihe; Cai, Keda; Sun, Min; Xiao, Wenjiao; Wan, Bo; Wang, Yannan; Wang, Xiangsong; Xia, Xiaoping

2018-03-01

The Tianshan belt of the southwestern Central Asian Orogenic Belt was generated by Paleozoic multi-stage subduction and final closure of several extinct oceans, including the South Tianshan Ocean between the Kazakhstan-Yili and Tarim blocks. However, the subduction initiation and polarity of the South Tianshan Ocean remain issues of highly debated. This study presents new zircon U-Pb ages, geochemical compositions and Sr-Nd isotopes, as well as zircon Hf isotopic data of the Latest Devonian to Early Carboniferous granitic rocks in the Wusun Mountain of the Yili Paleozoic convergent margin, which, together with the spatial-temporal distributions of regional magmatic rocks, are applied to elucidate their petrogenesis and tectonic linkage to the northward subduction initiation of the South Tianshan Ocean. Our zircon U-Pb dating results reveal that these granites were emplaced at the time interval of 362.0 ± 1.2-360.3 ± 1.9 Ma, suggesting a marked partial melting event of the continental crust in the Latest Devonian to Early Carboniferous. These granites, based on their mineral compositions and textures, can be categorized as monzogranites and K-feldspar granites. Geochemically, both monzogranites and K-feldspar granites have characters of I-type granites with high K2O contents (4.64-4.83 wt.%), and the K-feldspar granites are highly fractionated I-type granites, while the monzogranites have features of unfractionated I-type granites. Whole-rock Sr-Nd isotopic modeling results suggest that ca. 20-40% mantle-derived magmas may be involved in magma mixing with continental crust partial melts to generate the parental magmas of the granites. The mantle-derived basaltic magmas was inferred not only to be a major component of magma mixture but also as an important heat source to fuse the continental crust in an extensional setting, which is evidenced by the high zircon saturation temperatures (713-727 °C and 760-782 °C) of the studied granites. The Latest Devonian to Early Carboniferous extensional setting in the Wusun Mountain region of the Yili Paleozoic convergent margin is addressed by the subduction initiation of the South Tianshan Ocean and constituted a late Paleozoic nascent arc- back-arc system in the southwestern CAOB.

Controls of late Palaeozoic and Mesozoic extension in the British Isles: evidence from seismic reflection data in the Central North Sea

NASA Astrophysics Data System (ADS)

Smith, K.; Cameron, T. D. J.

2009-04-01

Controls of late Palaeozoic and Mesozoic extension in the British Isles: evidence from seismic reflection data in the Central North Sea. Kevin Smith (1) and Don Cameron (2) (1) British Geological Survey, Murchison House, West Mains Road, Edinburgh, EH9 3LA. (ksm@bgs.ac.uk). (2) British Geological Survey, 376 Gilmerton Road, Edinburgh, EH17 7QS. In the area of the British Isles during the late Devonian and early Carboniferous, the oblique convergence of Laurentia and Gondwana imposed a torque on the adjoining terranes of Baltica and Avalonia. Their resulting clockwise rotation was accommodated by widely distributed N-S extension in the intervening zones previously formed by Caledonian and Acadian convergence. South of Laurentia and Baltica, late Palaeozoic extension was focused (1) at terrane margins, (2) in areas of limited Caledonian-Acadian plutonism, and (3) in places where the western (Iapetus) and eastern (Tornquist) convergence zones intersect at a high angle. One of these latter areas lies in Central England immediately north of the Midland Microcraton (part of Eastern Avalonia), where thermal subsidence associated with early Carboniferous extension gave rise to the late Carboniferous Pennine Basin. Interpretation of an extensive set of 3D and 2D long-offset seismic reflection data suggests that a similar area of enhanced extension at a fold belt intersection lies to north of the Mid North Sea High in the middle of the Central North Sea. Variscan uplift and inversion of the late Palaeozoic basins began to predominate in mid-Carboniferous times as final amalgamation of all the different terranes to form Pangaea curtailed the initial episode of extension and thermal subsidence. This change in the tectonic regime was associated with the onset of tholeiitic volcanism within the convergence zones, and was followed by localised extension during the earliest Permian. Evidence obtained from seismic interpretation of the deep structure of the UK sector of the Central North Sea, suggests that late Carboniferous uplift and inversion along a northerly-trending axis analogous to the Pennine anticline controlled rift orientation during the episode of late Jurassic and early Cretaceous extension that formed the Central Graben. Other evidence indicates that subsequent local inversion of the Mesozoic basins in the same area can be spatially linked to the previous framework of late Devonian and early Carboniferous extension. In Scotland, north of the Southern Uplands, the pattern of late Palaeozoic extension in the Midland Valley is similar to that in England and the Central North Sea. Minor differences can be attributed to the greater effect of Laurentian tectonics in Scotland, including the development of Lower Devonian basins and volcanic rocks, and the influence of strike-slip faults of the NNE-trending Great Glen set, which originated between Laurentia and Baltica, largely to the north of the terranes of southern, Gondwanan, affinity. Published regional interpretations of variation in depth to the Moho in the UK can be used to examine the relative contribution of crustal stretching and magmatic underplating across the area.

Hydrogeology and simulation of ground-water flow in the Silurian-Devonian aquifer system, Johnson County, Iowa

USGS Publications Warehouse

Tucci, Patrick; McKay, Robert M.

2006-01-01

The greatest limitation to the model is the lack of measured or estimated water-budget components for comparison to simulated water-budget components. Because the model is only calibrated to measured water levels, and not to water-budget components, the model results are nonunique. Other model limitations include the relatively coarse grid scale, lack of detailed information on pumpage from the quarry and from private developments and domestic wells, and the lack of separate water-level data for the Silurian- and Devonian-age rocks.

Arthropod colonization of land--linking molecules and fossils in oribatid mites (Acari, Oribatida).

PubMed

Schaefer, Ina; Norton, Roy A; Scheu, Stefan; Maraun, Mark

2010-10-01

Terrestrial fossils that document the early colonization of land are scarce for >100 my after the Cambrian explosion. This raises the question whether life on land did not exist or just did not fossilize. With a molecular dating technique, we analyzed the origin of terrestrial chelicerate microarthropods (Acari, Oribatida) which have a fossil record since the Middle Devonian that is exceptional among soil animals. Our results suggest that oribatid mites originated in the Precambrian (571+/-37 mya) and that the radiation of basal groups coincides with the gap in the terrestrial fossil record between the Cambrian explosion and the earliest fossilized records of continental ecosystems. Further, they suggest that the colonization of land started via the interstitial, approximately 150 my earlier than the oldest fossils of terrestrial ecosystems. Overall, the results imply that omnivorous and detritivorous arthropods formed a major component in early terrestrial food webs, thereby facilitating the invasion of terrestrial habitats by later colonizers of higher trophic levels. Copyright 2010 Elsevier Inc. All rights reserved.

Total petroleum systems of the Illizi Province, Algeria and Libya; Tanezzuft-Illizi

USGS Publications Warehouse

Klett, T.R.

2000-01-01

Undiscovered conventional oil and gas resources were assessed within a total petroleum system of the Illizi Province (2056) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Illizi Province is in eastern Algeria and a small portion of western Libya. The province and its total petroleum system coincide with the Illizi Basin. Although several total petroleum systems may exist within the Illizi Province, only one “composite” total petroleum system is identified. This total petroleum system comprises a single assessment unit. The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. The total petroleum system was named after the oldest major source rock and the basin in which it resides. The estimated means of the undiscovered conventional petroleum volumes in the Tanezzuft-Illizi Total Petroleum System are 2,814 million barrels of oil (MMBO), 27,785 billion cubic feet of gas (BCFG), and 873 million barrels of natural gas liquids (MMBNGL).

Evaluation of methane sources in groundwater in northeastern Pennsylvania.

PubMed

Molofsky, Lisa J; Connor, John A; Wylie, Albert S; Wagner, Tom; Farhat, Shahla K

2013-01-01

Testing of 1701 water wells in northeastern Pennsylvania shows that methane is ubiquitous in groundwater, with higher concentrations observed in valleys vs. upland areas and in association with calcium-sodium-bicarbonate, sodium-bicarbonate, and sodium-chloride rich waters--indicating that, on a regional scale, methane concentrations are best correlated to topographic and hydrogeologic features, rather than shale-gas extraction. In addition, our assessment of isotopic and molecular analyses of hydrocarbon gases in the Dimock Township suggest that gases present in local water wells are most consistent with Middle and Upper Devonian gases sampled in the annular spaces of local gas wells, as opposed to Marcellus Production gas. Combined, these findings suggest that the methane concentrations in Susquehanna County water wells can be explained without the migration of Marcellus shale gas through fractures, an observation that has important implications for understanding the nature of risks associated with shale-gas extraction. © 2013, Cabot Oil and Gas Corporation. Groundwater © 2013, National GroundWater Association.

Synthrusting deposition of the Pennsylvanian and Permian Strathearn Formation, Northern Carlin Trend, Nevada

USGS Publications Warehouse

Theodore, T.G.; Berger, V.I.; Singer, D.A.; Harris, A.G.; Stevens, C.H.

2004-01-01

The middle Upper Pennsylvanian and middle Lower Permian Strathearn Formation belongs to the overlap assemblage of the Antler orogen in Nevada. At Beaver Peak, near the Carlin Trend of gold deposits, it contains synorogenic conglomerate deposits associated with emplacement of a regionally extensive, 1-km-thick tectonic wedge that is floored by the Coyote thrust. Normal marine conodont biofacies throughout the Strathearn Formation suggest middle shelf or deeper, depositional environments. The allochthon floored by the Coyote thrust has been thrust above a middle Upper Pennsylvanian, lower conglomerate unit of the Strathearn Formation. A middle Lower Permian upper conglomerate unit, the highest unit recognized in the Strathearn Formation, as well as similarly aged dolomitic siltstone, onlap directly onto Ordovician quartzarenite of the Vinini Formation that makes up most of the Coyote allochthon. Quartz grains and quartzarenite fragments of variable roundness and shape in the conglomerate units were derived from the presently adjoining tectonic lobe of mostly quartzarenite that advanced southeast (present geographic coordinates) during the late Paleozoic into the developing Strathearn basin. Chert fragments in the conglomerates probably were derived mostly from Devonian Slaven Chert, including a widespread thick me??lange unit of the Slaven Chert in the footwall of the Coyote thrust.Lithologic and shape ratio data from approximately 4200 clasts at 17 sites of the two major conglomerate units in the Strathearn Formation at Beaver Peak are roughly similar in that they contain only chert and quartzarenite clasts, and chert clasts predominate in both units. They differ in the relative proportion of the two lithologies whereby quartzarenite clasts increase sixfold in the upper unit (middle Lower Permian) versus its content in the lower conglomerate unit. Relations at the unconformity between the upper conglomerate unit and its underlying quartzarenite shows quartzarenite fragments actually breaking away from an immediately subjacent source. Ordovocian quartzarenite, which forms a tectonically uplifted wedge with the Coyote thrust at its base, became a source region for much of the quartzarenite detritus deposited preferentially in the upper parts of the Strathearn Formation. The conglomerate units of the Strathearn Formation temporally bracket emplacement of the Coyote thrust. Thrusting related to contractional reactivation of the Robert Mountains thrust system largely was completed by middle Early Permian. ?? 2004 Published by Elsevier B.V.

Detrital zircon U-Pb geochronology, Lu-Hf isotopes and REE geochemistry constrains on the provenance and tectonic setting of Indochina Block in the Paleozoic

NASA Astrophysics Data System (ADS)

Wang, Ce; Liang, Xinquan; Foster, David A.; Fu, Jiangang; Jiang, Ying; Dong, Chaoge; Zhou, Yun; Wen, Shunv; Van Quynh, Phan

2016-05-01

In situ U-Pb geochronology, Lu-Hf isotopes and REE geochemical analyses of detrital zircons from Cambrian-Devonian sandstones in the Truong Son Belt, central Vietnam, are used to provide the information of provenance and tectonic evolution of the Indochina Block. The combined detrital zircon age spectra of all of the samples ranges from 3699 Ma to 443 Ma and shows with dominant age peaks at ca. 445 Ma and 964 Ma, along with a number of age populations at 618-532 Ma, 1160-1076 Ma, 1454 Ma, 1728 Ma and 2516 Ma. The zircon age populations are similar to those from time equivalent sedimentary sequences in continental blocks disintegrated from the East Gondwana during the Phanerozoic. The younger zircon grains with age peaks at ca. 445 Ma were apparently derived from middle Ordovician-Silurian igneous and metamorphic rocks in Indochina. Zircons with ages older than about 600 Ma were derived from other Gondwana terrains or recycled from the Precambrian basement of the Indochina Block. Similarities in the detrital zircon U-Pb ages suggest that Paleozoic strata in the Indochina, Yangtze, Cathaysia and Tethyan Himalayas has similar provenance. This is consistent with other geological constrains indicating that the Indochina Block was located close to Tethyan Himalaya, northern margin of the India, and northwestern Australia in Gondwana.

Geometry, kinematics and tectonic models of the Kazakhstan Orocline, Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Pengfei; Sun, Min; Rosenbaum, Gideon; Yuan, Chao; Safonova, Inna; Cai, Keda; Jiang, Yingde; Zhang, Yunying

2018-03-01

The Central Asian Orogenic Belt (CAOB) is one of the largest accretionary orogens on Earth and is characterized by the occurrence of tight oroclines (Kazakhstan and Tuva-Mongolian oroclines). The origin of these large-scale orogenic curvatures is not quite understood, but is fundamentally important for understanding crustal growth and tectonic evolution of the CAOB. Here we provide an outline of available geological and paleomagnetic data around the Kazakhstan Orocline, with an aim of clarifying the geometry, kinematics and geodynamic origin of the orocline. The Kazakhstan Orocline is evident in a total magmatic image, and can be traced by the continuation of high magnetic anomalies associated with the Devonian Volcanic Belt and the Late Devonian to Carboniferous Balkhash-Yili arc. Paleomagnetic data show ∼112-126° clockwise rotation of the northern limb relative to the southern limb in the Late Devonian to Early Carboniferous, as well as ∼15-28° clockwise rotation of the northern limb and ∼39-40° anticlockwise rotation of the southern limb relative to the hinge of the orocline during the Late Carboniferous to Permian. We argue that the Kazakhstan Orocline experienced two-stage bending with the early stage of bending (Late Devonian to Early Carboniferous; ∼112-126°) driven by slab rollback, and the later stage (Late Carboniferous to Permian; 54-68°) possibly associated with the amalgamation of the Siberian, Tarim and Baltic cratons. This new tectonic model is compatible with the occurrence of rift basins, the spatial migration of magmatic arc, and the development of large-scale strike-slip fault systems during oroclinal bending.

Leaf evolution in early-diverging ferns: insights from a new fern-like plant from the Late Devonian of China

PubMed Central

Wang, De-Ming; Xu, Hong-He; Xue, Jin-Zhuang; Wang, Qi; Liu, Le

2015-01-01

Background and Aims With the exception of angiosperms, the main euphyllophyte lineages (i.e. ferns sensu lato, progymnosperms and gymnosperms) had evolved laminate leaves by the Late Devonian. The evolution of laminate leaves, however, remains unclear for early-diverging ferns, largely represented by fern-like plants. This study presents a novel fern-like taxon with pinnules, which provides new insights into the early evolution of laminate leaves in early-diverging ferns. Methods Macrofossil specimens were collected from the Upper Devonian (Famennian) Wutong Formation of Anhui and Jiangsu Provinces, South China. A standard degagement technique was employed to uncover compressed plant portions within the rock matrix. Key Results A new fern-like taxon, Shougangia bella gen. et sp. nov., is described and represents an early-diverging fern with highly derived features. It has a partially creeping stem with adventitious roots only on one side, upright primary and secondary branches arranged in helices, tertiary branches borne alternately or (sub)oppositely, laminate and usually lobed leaves with divergent veins, and complex fertile organs terminating tertiary branches and possessing multiple divisions and numerous terminal sporangia. Conclusions Shougangia bella provides unequivocal fossil evidence for laminate leaves in early-diverging ferns. It suggests that fern-like plants, along with other euphyllophyte lineages, had independently evolved megaphylls by the Late Devonian, possibly in response to a significant decline in atmospheric CO2 concentration. Among fern-like plants, planate ultimate appendages are homologous with laminate pinnules, and in the evolution of megaphylls, fertile organs tend to become complex. PMID:25979918

Geology of the Devonian black shales of the Appalachian Basin

USGS Publications Warehouse

Roen, J.B.

1984-01-01

Black shales of Devonian age in the Appalachian Basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies by Federal and State agencies and academic institutions produced a regional stratigraphic network that correlates the 15 ft black shale sequence in Tennessee with 3000 ft of interbedded black and gray shales in central New York. These studies correlate the classic Devonian black shale sequence in New York with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long-range correlations within the Appalachian Basin. Basinwide correlations, including the subsurface rocks, provided a basis for determining the areal distribution and thickness of the important black shale units. The organic carbon content of the dark shales generally increases from east to west across the basin and is sufficient to qualify as a hydrocarbon source rock. Significant structural features that involve the black shale and their hydrocarbon potential are the Rome trough, Kentucky River and Irvine-Paint Creek fault zone, and regional decollements and ramp zones. ?? 1984.

Geology of quadrangles H-12, H-13, and parts of I-12 and I-13, (zone III) in northeastern Santander Department, Colombia

USGS Publications Warehouse

Ward, Dwight Edward; Goldsmith, Richard; Cruz, Jaime B.; Restrepo, Hernan A.

1974-01-01

A program of geologic mapping and mineral investigation in Colombia was undertaken cooperatively by the Colombian Instituto Nacional de Investigaciones Geologico-Mineras (formerly known as the Inventario Minero Nacional), and the U. S. Geological Survey; by the Government of Colombia and the Agency for International Development, U. S. Department of State. The purpose was to study, and evaluate mineral resources (excluding of petroleum, coal, emeralds, and alluvial gold) of four selected areas, designated Zones I to IV, that total about 70,000 km2. The work in Zone III, in the Cordillera Oriental, was done from 1965 to 1968. The northeast trend of the Cordillera Oriental of Colombia swings abruptly to north-northwest in the area of this report, and divides around the southern end of the Maracaibo Basin. This section of the Cordillera Oriental is referred to as the Santander Massif. Radiometric age determinations indicate that the oldest rocks of the Santander massif are Precambrian and include high-grade gneiss, schist, and migmatite of the Bucaramanga Formation. These rocks were probably part of the Precambrian Guayana Shield. Low- to medium-grade metamorphic rocks of late Precambrian to Ordovician age .include phyllite, schist, metasiltstone, metasandstone, and marble of the Silgara Formation, a geosynclinal series of considerable extent in the Cordillera Oriental and possibly the Cordillera de Merida of Venezuela. Orthogneiss ranging from granite to tonalite is widely distributed in the high- and medium-grade metamorphic rocks of the central core of the massif and probably represents rocks of two ages, Precambrian and Ordovician to Early Devonian. Younger orthogneiss and the Silgara are overlain by Middle Devonian beds of the Floresta Formation which show a generally low but varying degree of metamorphism. Phyllite and argillite are common, and infrequent marble and other calcareous beds are fossiliferous. Except for recrystallization in limestones of !the Permian-Carboniferous Diamante Formation, sedimentary rocks younger than Devonian are unmetamorphosed. The effects of Precambrian regional dynamothermal metamorphism and plutonism on Precambrian geosynclinal deposits reached the upper amphibolite facies in the Bucaramanga Gneiss. The geosynclinal Silgara Formation was subjected to similar conditions in Late Ordovician and Early Silurian time but reached only the greenschist or lower amphibolite facies. Orthogneisses generally show a concordance of foliation and lineation with the neighboring Silgara Formation and the Bucaramanga Gneiss as well as similarities in grade of metamorphism. Regional dynamothermal metamorphism in Late Permian and Triassic time reached, low grade in the Floresta Formation and caused recrystallization of limestone of the Diamante Formation. The Bucaramanga and Silgara metamorphic rocks show evidence of metrogressive metamorphism accompanied by high activity or potassium and water, but whether this occurred at the time the Floresta was metamorphosed or later is not clear. Batholiths, plutons, and stocks of igneous rocks in the Santander massif range from diorite to granite. Radioactive age data indicate that most belong to a single plutonic interval. These are referred to as the Santander Plutoniq Group and are Jurassic and Jurassic-Triassic- Two suites of this group are pink granite and quartz monzonite, and gray quartz monzonite and granodiorite. Contact relations indicate that the pink and more granitic rocks are younger than the gray and more mafic rocks, but radioactive age data are in conflict with this. Undated plutonic rocks that are not clearly related to the group are assigned to relatively older or younger age positions. West of the Bucanamanga fault rhyolite makes up a small body at one locality and forms an intrusive sheet with granophyre and intrusive breccias in Triassic sedimentary rocks at another locality. Its age is unknown, but it probably is younger than the

Bedrock geologic map of the Nashua South quadrangle, Hillsborough County, New Hampshire, and Middlesex County, Massachusetts

USGS Publications Warehouse

Walsh, Gregory J.; Jahns, Richard H.; Aleinikoff, John N.

2013-01-01

The bedrock geology of the 7.5-minute Nashua South quadrangle consists primarily of deformed Silurian metasedimentary rocks of the Berwick Formation. The metasedimentary rocks are intruded by a Late Silurian to Early Devonian diorite-gabbro suite, Devonian rocks of the Ayer Granodiorite, Devonian granitic rocks of the New Hampshire Plutonic Suite including pegmatite and the Chelmsford Granite, and Jurassic diabase dikes. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing hydrogeologic characterization of the fractured bedrock of Massachusetts and New Hampshire. This report presents mapping by G.J. Walsh and R.H. Jahns and zircon U-Pb geochronology by J.N. Aleinikoff. The complete report consists of a map, text pamphlet, and GIS database. The map and text pamphlet are only available as downloadable files (see frame at right). The GIS database is available for download in ESRITM shapefile and Google EarthTM formats, and includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, photographs, and a three-dimensional model.

Stratigraphy, geochronology, and accretionary terrane settings of two Bronson Hill arc sequences, northern New England

USGS Publications Warehouse

Moench, R.H.; Aleinikoff, J.N.

2002-01-01

The Ammonoosuc Volcanics, Partridge Formation, and the Oliverian and Highlandcroft Plutonic Suites of the Bronson Hill anticlinorium (BHA) in axial New England are widely accepted as a single Middle to Late Ordovician magmatic arc that was active during closure of Iapetus. Mapping and U-Pb dating indicate, however, that the BHA contains two volcano-sedimentary-intrusive sequences of probable opposite subduction polarity, here termed the Ammonoosuc and Quimby sequences. The Ammonoosuc sequence is defined by the Middle Ordovician Ammonoosuc Volcanics near Littleton, N.H., the type area, northeast to Milan, N.H., and Oquossoc, Me.; it also includes black slate of the Partidge Formation (C. bicornis zone graptolites, ???457 Ma). Related metamorphosed intrusive are the tonalitic Joslin Turn pluton (469 ?? 2 Ma), the Cambridge Black granitic pluton (468 ?? 3 Ma), and gabbro, tonalite (467 ?? 4 Ma), and sheeted diabase of the Chickwolnepy instructions. These intrusives cut lowermost Ammonoosuc (therefore>469 Ma). Probable uppermost Ammonoosuc is dated at 465 ?? 6 and 461 ?? 8 Ma. Successively below the Ammonoosuc are the Dead River and Hurricane Mountain Formations (flysch and melange), and the Jim Pond Formation (484 ?? 5 Ma) and Boil Mountain Complex (both ophiolite), which are structurally underlain by the Neoproterozoic(?) Chain Lakes massif. The Quimby sequence is defined by the Lower Silurian(?) to Upper Ordovician Quimby Formation, composed of bimodal volcanics (443 ?? 4 Ma) and sulfidic shale and graywacke that lie conformably to unconformably above the Ammonoosuc Volcanics and Partridge Formation. Also in the Quimby sequence are several granitic to sparsely gabbroic plutons of the Highlandcroft (441-452 Ma) and Oliverian (435-456 Ma) Plutonic Suites, which intrude the Dead River, Ammonoosuc and Partridge, but not the Quimby Formation. Based on faunal, paleolatitude, and isotropic data, the Ammonoosuc sequence and its correlative and underlying sequences formed off the southern Laurentian margin, but northwest of the principal Iapetan suture, or Red Indian line (RIL). The Boil Mountain-Jim Pond-Hurricane Mountain sequence was ramped northwestward over the Chain Lakes massif at ???475 Ma, on the basal Boil Mountain surface. This obduction probably occurred slightly before obduction on the Baie Verte-Brompton surface (BBL), farther NW, over the Laurentian margin, and was followed by Dead River flysch sedimentation, which ended with the abrupt onset of Ammonoosuc-sequence arc magmatism at ???470 Ma. Ammonoosuc eruptions probably ended at ???460 Ma, when Iapetus closed along the Red Indian line. During a following magmatic hiatus of ???3-5 m.y., now represented by portions of the Partridge Formation that overlie the Ammonoosuc Volcanics, subduction polarity reversed, and subduction resumed below the northwest-dipping Brunswick subduction complex (BSC) of New Brunswick, Canada. Quimby-sequence magmatism (???456-435 Ma) on the the newly accreted Laurentian margin occurred above the BSC, whose footwall is now buried to the southeast by mainly Silurian clastic sediments of the Merrimack-Fredericton trough, deposited in the "Fredericton Sea". In Silurian to Early Devonian time, the NW-dipping BSC footwall was paired with a SE-dipping subduction zone that produced arc magmas of the Coastal Volcanic belt, built on the composite Avalon and adjacent peri-Avalonian terranes. Orogen-normal extension produced by rapid rollback of both subduction zones narrowed the Fredericton Sea, produced the Central Maine and Connecticut Valley-Gaspe?? basins, and culminated in the Acadian orogeny when the sea completely closed in Early Devonian time. Published by Elsevier Science Ltd.

Stratigraphy, geochronology, and accretionary terrane settings of two Bronson Hill arc sequences, northern New England

USGS Publications Warehouse

Moench, R.H.; Aleinikoff, J.N.

2003-01-01

The Ammonoosuc Volcanics, Partridge Formation, and the Oliverian and Highlandcroft Plutonic Suites of the Bronson Hill anticlinorium (BHA) in axial New England are widely accepted as a single Middle to Late Ordovician magmatic arc that was active during closure of Iapetus. Mapping and U-Pb dating indicate, however, that the BHA contains two volcano-sedimentary-intrusive sequences of probable opposite subduction polarity, here termed the Ammonoosuc and Quimby sequences. The Ammonoosuc sequence is defined by the Middle Ordovician Ammonoosuc Volcanics near Littleton, NH, the type area, northeast to Milan, NH, and Oquossoc, ME; it also includes black slate of the Partridge Formation ( C. bicornis--zone graptolites, ???457 Ma). Related metamorphosed intrusives are the tonalitic Joslin Turn pluton (469 ?? 2 Ma), the Cambridge Black granitic pluton (468 ?? 3 Ma), and gabbro, tonalite (467 ?? 4 Ma), and sheeted diabase of the Chickwolnepy intrusions. These intrusives cut lowermost Ammonoosuc (therefore >469 Ma). Probable uppermost Ammonoosuc is dated at 465 ?? 6 and 461 ?? 8 Ma. Successively below the Ammonoosuc are the Dead River and Hurricane Mountain Formations (flysch and melange), and the Jim Pond Formation (484 ?? 5 Ma) and Boil Mountain Complex (both ophiolite), which are structurally underlain by the Neoproterozoic(?) Chain Lakes massif. The Quimby sequence is defined by the Lower Silurian(?) to Upper Ordovician Quimby Formation, composed of bimodal volcanics (443 ?? 4 Ma) and sulfidic shale and graywacke that lie conformably to unconformably above the Ammmonoosuc Volcanics and Partridge Formation. Also in the Quimby sequence are several granitic to sparsely gabbroic plutons of the Highlandcroft (441-452 Ma) and Oliverian (435-456 Ma) Plutonic Suites, which intrude the Dead River, Ammonoouc and Partridge, but not the Quimby Formation. Based on faunal, paleolatitude, and isotopic data, the Ammonoosuc sequence and its correlatives and underlying sequences formed off the southern Laurentian margin, but northwest of the principal Iapetan suture, or Red Indian line. The Boil Mountain-Jim Pond-Hurricane Mountain sequence was ramped northwestward over the Chain Lakes massif at ???475 Ma, on the basal Boil Mountain surface. This obduction probably occurred slightly before obduction on the Baie Vert-Brompton surface (BBL), farther NW, over the Laurentian margin, and was followed by Dead River flysch sedimentation, which ended with the abrupt onset of Ammonoosuc-sequence arc magmatism at ???470 Ma. Ammonoosuc eruptions probably ended at ???460 Ma, when Iapetus closed along the Red Indian line. During a following magmatic hiatus of ???3-5 m.y., now represented by portions of the Partridge Formation that overlie the Ammonoosuc Volcanics, subduction polarity reversed, and subduction resumed below the northwest-dipping Brunswick subduction complex (BSC) of New Brunswick, Canada. Quimby-sequence magmatism (???456-435 Ma) on the newly accreted Laurentian margin occurred above the BSC, whose footwall is now buried to the southeast by mainly Silurian clastic sediments of the Merrimack-Fredericton trough, deposited in the "Fredericton Sea". In Silurian to Early Devonian time, the NW-dipping BSC footwall was paired with a SE-dipping subduction zone that produced arc magmas of the Coastal Volcanic belt, built on the composite Avalon and adjacent peri-Avalonian terranes. Orogen-normal extension produced by rapid rollback of both subduction zones narrowed the Fredericton Sea, produced the Central Maine and Connecticut Valley-Gaspe?? basins, and culminated in the Acadian orogeny when the sea completely closed in Early Devonian time. Published by Elsevier Science Ltd.

Stratigraphy, geochronology, and accretionary terrane settings of two Bronson Hill arc sequences, northern New England

NASA Astrophysics Data System (ADS)

Moench, Robert H.; Aleinikoff, John N.

The Ammonoosuc Volcanics, Partridge Formation, and the Oliverian and Highlandcroft Plutonic Suites of the Bronson Hill anticlinorium (BHA) in axial New England are widely accepted as a single Middle to Late Ordovician magmatic arc that was active during closure of Iapetus. Mapping and U-Pb dating indicate, however, that the BHA contains two volcano-sedimentary-intrusive sequences of probable opposite subduction polarity, here termed the Ammonoosuc and Quimby sequences. The Ammonoosuc sequence is defined by the Middle Ordovician Ammonoosuc Volcanics near Littleton, NH, the type area, northeast to Milan, NH, and Oquossoc, ME; it also includes black slate of the Partridge Formation ( C. bicornis--zone graptolites, ∼457 Ma). Related metamorphosed intrusives are the tonalitic Joslin Turn pluton (469 ± 2 Ma), the Cambridge Black granitic pluton (468 ± 3 Ma), and gabbro, tonalite (467 ± 4 Ma), and sheeted diabase of the Chickwolnepy intrusions. These intrusives cut lowermost Ammonoosuc (therefore >469 Ma). Probable uppermost Ammonoosuc is dated at 465 ± 6 and 461 ± 8 Ma. Successively below the Ammonoosuc are the Dead River and Hurricane Mountain Formations (flysch and melange), and the Jim Pond Formation (484 ± 5 Ma) and Boil Mountain Complex (both ophiolite), which are structurally underlain by the Neoproterozoic(?) Chain Lakes massif. The Quimby sequence is defined by the Lower Silurian(?) to Upper Ordovician Quimby Formation, composed of bimodal volcanics (443 ± 4 Ma) and sulfidic shale and graywacke that lie conformably to unconformably above the Ammmonoosuc Volcanics and Partridge Formation. Also in the Quimby sequence are several granitic to sparsely gabbroic plutons of the Highlandcroft (441-452 Ma) and Oliverian (435-456 Ma) Plutonic Suites, which intrude the Dead River, Ammonoouc and Partridge, but not the Quimby Formation. Based on faunal, paleolatitude, and isotopic data, the Ammonoosuc sequence and its correlatives and underlying sequences formed off the southern Laurentian margin, but northwest of the principal Iapetan suture, or Red Indian line. The Boil Mountain-Jim Pond-Hurricane Mountain sequence was ramped northwestward over the Chain Lakes massif at ∼475 Ma, on the basal Boil Mountain surface. This obduction probably occurred slightly before obduction on the Baie Vert-Brompton surface (BBL), farther NW, over the Laurentian margin, and was followed by Dead River flysch sedimentation, which ended with the abrupt onset of Ammonoosuc-sequence arc magmatism at ∼470 Ma. Ammonoosuc eruptions probably ended at ∼460 Ma, when Iapetus closed along the Red Indian line. During a following magmatic hiatus of ∼3-5 m.y., now represented by portions of the Partridge Formation that overlie the Ammonoosuc Volcanics, subduction polarity reversed, and subduction resumed below the northwest-dipping Brunswick subduction complex (BSC) of New Brunswick, Canada. Quimby-sequence magmatism (∼456-435 Ma) on the newly accreted Laurentian margin occurred above the BSC, whose footwall is now buried to the southeast by mainly Silurian clastic sediments of the Merrimack-Fredericton trough, deposited in the “Fredericton Sea”. In Silurian to Early Devonian time, the NW-dipping BSC footwall was paired with a SE-dipping subduction zone that produced arc magmas of the Coastal Volcanic belt, built on the composite Avalon and adjacent peri-Avalonian terranes. Orogen-normal extension produced by rapid rollback of both subduction zones narrowed the Fredericton Sea, produced the Central Maine and Connecticut Valley-Gaspé basins, and culminated in the Acadian orogeny when the sea completely closed in Early Devonian time.

Stratigraphy, geochronology, and accretionary terrane settings of two Bronson Hill arc sequences, northern New England

NASA Astrophysics Data System (ADS)

Moench, Robert H.; Aleinikoff, John N.

2002-01-01

The Ammonoosuc Volcanics, Partridge Formation, and the Oliverian and Highlandcroft Plutonic Suites of the Bronson Hill anticlinorium (BHA) in axial New England are widely accepted as a single Middle to Late Ordovician magmatic arc that was active during closure of Iapetus. Mapping and U-Pb dating indicate, however, that the BHA contains two volcano-sedimentary-intrusive sequences of probable opposite subduction polarity, here termed the Ammonoosuc and Quimby sequences. The Ammonoosuc sequence is defined by the Middle Ordovician Ammonoosuc Volcanics near Littleton, N.H., the type area, northeast to Milan, N.H., and Oquossoc, Me.; it also includes black slate of the Partidge Formation ( C. bicornis zone graptolites, ∼457 Ma). Related metamorphosed intrusive are the tonalitic Joslin Turn pluton (469±2 Ma), the Cambridge Black granitic pluton (468±3 Ma), and gabbro, tonalite (467±4 Ma), and sheeted diabase of the Chickwolnepy instructions. These intrusives cut lowermost Ammonoosuc (therefore >469 Ma). Probable uppermost Ammonoosuc is dated at 465±6 and 461±8 Ma. Successively below the Ammonoosuc are the Dead River and Hurricane Mountain Formations (flysch and melange), and the Jim Pond Formation (484±5 Ma) and Boil Mountain Complex (both ophiolite), which are structurally underlain by the Neoproterozoic(?) Chain Lakes massif. The Quimby sequence is defined by the Lower Silurian(?) to Upper Ordovician Quimby Formation, composed of bimodal volcanics (443±4 Ma) and sulfidic shale and graywacke that lie conformably to unconformably above the Ammonoosuc Volcanics and Partridge Formation. Also in the Quimby sequence are several granitic to sparsely gabbroic plutons of the Highlandcroft (441-452 Ma) and Oliverian (435-456 Ma) Plutonic Suites, which intrude the Dead River, Ammonoosuc and Partridge, but not the Quimby Formation. Based on faunal, paleolatitude, and isotropic data, the Ammonoosuc sequence and its correlative and underlying sequences formed off the southern Laurentian margin, but northwest of the principal Iapetan suture, or Red Indian line (RIL). The Boil Mountain-Jim Pond-Hurricane Mountain sequence was ramped northwestward over the Chain Lakes massif at ∼475 Ma, on the basal Boil Mountain surface. This obduction probably occurred slightly before obduction on the Baie Verte-Brompton surface (BBL), farther NW, over the Laurentian margin, and was followed by Dead River flysch sedimentation, which ended with the abrupt onset of Ammonoosuc-sequence arc magmatism at ∼470 Ma. Ammonoosuc eruptions probably ended at ∼460 Ma, when Iapetus closed along the Red Indian line. During a following magmatic hiatus of ∼3-5 m.y., now represented by portions of the Partridge Formation that overlie the Ammonoosuc Volcanics, subduction polarity reversed, and subduction resumed below the northwest-dipping Brunswick subduction complex (BSC) of New Brunswick, Canada. Quimby-sequence magmatism (∼456-435 Ma) on the the newly accreted Laurentian margin occurred above the BSC, whose footwall is now buried to the southeast by mainly Silurian clastic sediments of the Merrimack-Fredericton trough, deposited in the “Fredericton Sea”. In Silurian to Early Devonian time, the NW-dipping BSC footwall was paired with a SE-dipping subduction zone that produced arc magmas of the Coastal Volcanic belt, built on the composite Avalon and adjacent peri-Avalonian terranes. Orogen-normal extension produced by rapid rollback of both subduction zones narrowed the Fredericton Sea, produced the Central Maine and Connecticut Valley-Gaspé basins, and culminated in the Acadian orogeny when the sea completely closed in Early Devonian time.

Multistage extensional evolution of the central East Greenland Caledonides

NASA Astrophysics Data System (ADS)

White, Arthur P.; Hodges, Kip V.

2002-10-01

Recent field investigations in the central East Greenland Caledonides (72°-74°N) resulted in the identification of an orogen-scale extensional fault system called the Fjord Region Detachment (FRD). Previous geochronologic constraints on this deformation indicated that the FRD was active circa 430-425 Ma, a time when the Baltica-Laurentia collision was thought to be occurring, and continued to be active for up to 80 million years. We present new 40Ar/39Ar thermochronologic data from an E-W transect that cuts across two splays of the FRD. Our data demonstrate that at least two distinct episodes of faulting were responsible for extension in the East Greenland Caledonides: an earlier phase (circa 425-423 Ma) that was synorogenic and penetrated to middle-crustal levels, followed by a post-Caledonian phase of reactivation (˜414 to 380 Ma) that affected even deeper structural levels. Furthermore, we present in situ UV laser 40Ar/39Ar data for pseudotachylite collected along the deepest splay of the FRD that indicate this fault was active again as recently as ˜357 Ma (coeval with Devonian basin formation). Altogether, our data suggest that rather than being active continuously for 80 million years, the FRD consisted of multiple splays that were active for shorter intervals over discrete time periods separated by as much as 60 million years. Finally, our data provide evidence that young extensional deformation associated with postorogenic collapse in East Greenland was not restricted to the formation of sedimentary basins in the far eastern part of the orogen, but also resulted in deformation of the Archean-Paleozoic crystalline basement.

Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico

NASA Astrophysics Data System (ADS)

Ramos-Arias, M. A.; Keppie, J. D.; Ortega-Rivera, A.; Lee, J. W. K.

2008-02-01

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle-Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle-Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a 40Ar/ 39Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian-Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE-SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. 40Ar/ 39Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of ˜ 260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E-W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a 40Ar/ 39Ar plateau age of 299 ± 6 Ma, which records cooling through ˜ 490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian (˜ 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at ˜ 350-340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates (˜ 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.

Characteristics of the Late Devonian Tsagaan Suvarga Cu-Mo deposit, Southern Mongolia

NASA Astrophysics Data System (ADS)

Tungalag, Naidansuren; Jargalan, Sereenen; Khashgerel, Bat-Erdene; Mijiddorj, Chuluunbaatar; Kavalieris, Imants

2018-05-01

The Late Devonian Tsagaan Suvarga deposit (255 Mt at 0.55% Cu, 0.02% Mo) is located on the NW margin of the Tsagaan Suvarga Complex (TSC), which extends ENE over 15 × 10 km and comprises mainly medium-grained equigranular hornblende-biotite quartz monzonite and monzodiorite. Distinct mineralized intrusions are inferred from distribution of Cu-Mo mineralization but are not clearly discernible. The Tsagaan Suvarga Complex is a window within Carboniferous volcanic and sedimentary rocks, and wall rocks to the TSC are not known or exposed in the nearby district. Whole-rock analyses and Sr-Nd isotopes, 87Sr/86Sr0 = 0.7027 to 0.7038 (n = 12) and ɛNd0 = + 4.26 to + 2.77 (n = 12), show that the granitoids are subduction-related I-type, high K-calc-alkaline to shoshonitic series and derived from a mantle source. They exhibit fractionated light rare earth elements, without depleted Eu and depleted middle heavy rare earth elements and Y, typical of oxidized, fertile porphyry magmatic suites. Early porphyry-style quartz veins include A- and B-type. Molybdenite occurs in monomineralic veins (1-5 mm) or A veins. Copper mineralization occurs mainly as chalcopyrite and subordinate bornite, disseminated and associated with quartz-muscovite veins. Pyrite (vol%) content is less than chalcopyrite and bornite combined. Deep oxidation to about 50 m depth has formed zones of malachite and covellite in late fractures. The most important alteration is actinolite-biotite-chlorite-magnetite replacing hornblende and primary biotite. Quartz-K-feldspar alteration is minor. Late albite replaces primary K-feldspar and enhances sodic rims on plagioclase crystals. Quartz-muscovite (or sericitic alteration) overprints actinolite-biotite and porphyry-type quartz veins. Field observations and petrographic studies suggest that the bulk of the chalcopyrite-bornite mineralization at the Tsagaan Suvarga formed together with coarse muscovite alteration.

Algoma-, Superior-, and oolitic-type iron deposits of the Islamic Republic of Mauritania (phase V, deliverable 83): Chapter O in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

USGS Publications Warehouse

Taylor, Cliff D.; Finn, Carol A.; Anderson, Eric D.; Joud, M. Y.; Taleb, M. A.; Horton, John D.

2015-01-01

Phanerozoic oolitic ironstones are hosted in the upper Silurian and lower Devonian rocks of the Gara Bouya Ali Group and the Zemmour Group in the Tindouf Basin in northern Mauritania and in the end Ordovician Tichit Group, the Silurian Oued Chig Group, and the lower Devonian Tenemouj Group in the Taoudeni Basin near Tidjikja. These rock groups define 11 permissive tracts for Algoma-, Superior-, and oolitic-type iron deposits in Mauritania.

Petrology and sedimentology of the Horlick Formation (Lower Devonian), Ohio Range, Transantarctic Mountains

USGS Publications Warehouse

McCartan, Lucy; Bradshaw, Margaret A.

1987-01-01

The Horlick Formation of Early Devonian age is as thick as 50 m and consists of subhorizontal, interbedded subarkosic sandstone and chloritic shale and mudstone. The Horlick overlies an erosion surface cut into Ordovician granitic rocks and is, in turn, overlain by Carboniferous and Permian glacial and periglacial deposits. Textures, sedimentary structures, and ubiquitous marine body fossils and animal traces suggest that the Horlick was deposited on a shallow shelf having moderate wave energy and a moderate tidal range. The source terrane probably lay to the north, and longshore transport was toward the west.

The stratigraphic utility of the trace fossil Pteridichnites biseriatus in the Upper Devonian of eastern West Virginia and western Virginia, USA

USGS Publications Warehouse

McDowell, R.R.; Avary, K.L.; Matchen, D.L.; Britton, J.Q.

2007-01-01

Similar lithologies and lithofacies are present in two Upper Devonian siliciclastic units, the Brallier and Foreknobs formations, in eastern West Virginia and western Virginia, USA. Specimens of an unusual trace fossil, Pteridichnites biseriatus, occur in variable numbers throughout both stratigraphic units. P. biseriatus is present in abundance in the lowermost Brallier and this abundance-zone serves as a local stratigraphic marker for the Brallier. The trace fossil, originally suggested as an indication of polychaete or arthropod locomotion, is herein proposed as the locomotion trace of an unidentified ophiuroid.

Plate tectonic history of the Arctic

NASA Technical Reports Server (NTRS)

Burke, K.

1984-01-01

Tectonic development of the Arctic Ocean is outlined, and geological maps are provided for the Arctic during the mid-Cenozoic, later Cretaceous, late Jurassic, early Cretaceous, early Jurassic and late Devonian. It is concluded that Arctic basin history is moulded by the events of the following intervals: (1) continental collision and immediately subsequent rifting and ocean formation in the Devonian, and continental rifting ocean formation, rapid rotation of microcontinents, and another episode of collision in the latest Jurassic and Cretaceous. It is noted that Cenozoic Arctic basin formation is a smaller scale event superimposed on the late Mesozoic ocean basin.

Evidence of land plant affinity for the Devonian fossil Protosalvinia (Foerstia)

USGS Publications Warehouse

Romankiw, L.A.; Hatcher, P.G.; Roen, J.B.

1988-01-01

The Devonian plant fossil Protosalvinia (Foerstia) has been examined by solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and pyrolysis-gas chromatography-mass spectrometry (PY-GC-MS). Results of these studies reveal that the chemical structure of Protosalvinia is remarkably similar to that of coalified wood. A well-defined phenolic carbon peak in the NMR spectra and the appearance of phenol and alkylated phenols in pyrolysis products are clearly indicative of lignin-like compounds. These data represent significant new information on the chemical nature of Protosalvinia and provide the first substantial organic geochemical evidence for land plant affinity. -Authors

The Lower Devonian marginal-marine ecosystems of the Holy Cross Mountains, Poland - new discoveries and observations

NASA Astrophysics Data System (ADS)

Szrek, P.; Niedźwiedzki, G.; Dec, M.

2012-04-01

Despite of more than 100 years of study, the Lower Devonian deposits of the Holy Cross Mountains (central Poland) are still not well understood from the biostratigraphical, environmental and also paleontological point of views. During field works and excavations conducted in 2011 numerous fossils (body and trace fossils) were discovered in a few Lower Devonian outcrops of the region. The siliciclastic sequence of the Lower Devonian of the southern part of the Holy Cross Mountains, is renowned for abundant vertebrate fossils, including mainly the jawless fish and placoderm remains. During the first detailed taphonomic study of the vertebrate assemblage from the so-called "Placoderm Sandstones" cropping out at the Podłazie near Daleszyce, abundant vertebrate remains have been collected (more than 600 specimens). Their analysis (that is in progress) will be the first description of so rich and numerous vertebrates association from the Central Europe that contains placoderms, sharks, acathodians and sarcopterygians. The degree of fragmentation of the bones and disarticulation of the skeletons suggest that the carcasses were reworked and transported before burial. Sedimentological data suggest deposition in a shallow marine environment. Numerous invertebrate ichnofossils (Phycodes isp. Skolithos isp., Diplichnites isp., Monomorphichnus isp., Lockeia cf. siliquaria, Corophioides isp. and Teichinus isp.) particularly well preserved were ascertained in another Lower Devonian site near Iwaniska. Moreover a very interesting assemblage of trace fossils corresponding to traces of feeding fishes were discovered. They are very similar to those found in much younger deposits (e.g. from the Eocene of Turkey). Its interpretation found them as made by placoderms is taken into consideration recently, because of its fiting to whole morphology of small coccosteids. They are also important that they could be the first imprints of soft body of the placoderm as a life animal according to good preservation of particular specimens. The occurrence of characteristic trace fossils is taken as strong evidence of marine influences of the studied section, where sedimentological features are not so clear, with exceptions of very few surfaces covered with symmetrical wave marks. The distribution of the most common trace fossils recognized in the field allowed for different interpretation than was proposed in the past which set up the river influence in the Lower Dewonian of the eastern part of the Holy Cross Mountains, but it is not confirmed by mentioned above invertebrate ichnofossils. Instead of this the development of Skolithos and Cruziana ichnofacies in Iwaniska profile, indicate high energy conditions in foreshore zone, respectively. All the Lower Devonian sites with trace fossils and vertebrate bonebeds from the Holy Cross Mountains are associated with sandy deposits and have been formed in a sea-coastal zone during rather rapid sedimentation episodes, but differ in fossil abundance and degree of preservation.

Stratigraphy and lithofacies of Lisburne Group carbonate rocks (Carboniferous - Permian) in the National Petroleum Reserve - Alaska

USGS Publications Warehouse

Dumoulin, Julie A.; Bird, Kenneth J.; Houseknecht, David W.

2001-01-01

Carbonate rocks of the Lisburne Group (Carboniferous-Permian) occur widely throughout northern Alaska. In the NPRA, seismic mapping and well penetrations show that the Lisburne occurs throughout the subsurface except in northernmost NPRA where it is missing by depositional onlap. Lisburne strata encountered in 11 exploratory wells in the northern part of the NPRA are essentially undeformed, consist of limestone and lesser dolostone, sandstone, siltstone, and shale, encompass a wide array of chiefly shallow-water facies, and range in age from Early Mississippian to Permian. Basins and platforms that formed during Mississippian (and possibly Devonian) time greatly affected depositional patterns of the Lisburne. Total thickness of the Lisburne in northern NPRA wells varies from almost 4000 ft in the Ikpikpuk-Umiat Basin to 300 ft on the north edge of the Fish Creek Platform. Lisburne strata of Mississippian age are found in northeastern NPRA, comprise three subunits (lower limestone, middle dolostone, and upper limestone) and are oldest (Osagean) in the Ikpikpuk-Umiat Basin. All wells that penetrated the Lisburne in northern NPRA encountered rocks of Pennsylvanian age; these intervals are mainly limestone and characterized by decameter-scale shallowing-upward sequences. Lisburne sections of prob-able Early-middle Permian age range from thin (≤60 ft) intervals of dolostone and limestone in the Fish Creek Platform area to thick (500-1000 ft) successions of interbedded limestone and siliciclastic sediment in the Ikpikpuk-Umiat Basin and northwestern NPRA. Abundant non-carbonate detritus, primarily quartz and chert with locally notable plagioclase feldspar and metamorphic lithic clasts, occurs throughout the Lisburne Group in northern NPRA. Per-mian strata and a persistent non-carbonate detrital component are also seen in the Lisburne in subsurface beneath the Chukchi Sea (Hanna Trough) to the northwest, but are not found in Lisburne successions elsewhere in Alaska.

The Carboniferous of the Western Karakoram (Pakistan)

NASA Astrophysics Data System (ADS)

Gaetani, M.; Zanchi, A.; Angiolini, L.; Olivini, G.; Sciunnach, D.; Brunton, H.; Nicora, A.; Mawson, R.

2004-05-01

The results of the study of the Carboniferous successions in the western part of the Northern Karakoram during three geological expeditions are summarized here. Rocks of that period are not uniformly preserved in the several thrust sheets forming the Northern Karakoram. In most of them only the basal part of the Carboniferous, up to the Visean, is preserved, whilst in the Karambar thrust sheet a more complete section—previously almost unknown—is preserved. Four new lithostratigraphic units, time-constrained by brachiopod and conodont biostratigraphy, are described, from bottom to top: (1) the Margach Formation: prevailing dark shales with subordinate fine subarkoses and quartzarenites, up to 300 m thick (mid-Famennian to middle Tournaisian); (2) the Ribat Formation: grey crinoidal limestones passing upwards to dark marly limestones and marls, at least 300 m thick (middle Tournaisian to Serpukhovian); (3) the Lupsuk Formation: subarkoses to feldspathic quartzarenites in thick beds, alternating with dark shales and siltstones, up to 400 m thick (Serpukhovian to uppermost Carboniferous); (4) within the Lupsuk Formation a local member, the Twin Valleys Member, up to 100 m thick, a bioclastic limestone intercalation of post-Moscovian age, is distinguished. The Carboniferous successions are invariably sealed by the arkoses to quartzarenites of the Gircha Formation, 133 m above the base of which, in the Karambar area, an Asselian brachiopod fauna was recovered. The Carboniferous succession is interpreted as recording the evolution of the passive margin of the Northern Karakoram Terrane, from early rifting stage in the Late Devonian to syn-rift events during the Late Carboniferous. The basal part of the Gircha Formation, of latest Carboniferous-earliest Permian age, is considered to have been deposited above a break-up unconformity, linked to the early drifting in the seaway bordering the Karakoram. In the palaeontological appendix the most significant brachiopod taxa (19 species, one new) are described.

Late Frasnian-Famennian climates based on palynomorph analyses and the question of the Late Devonian glaciations

NASA Astrophysics Data System (ADS)

Streel, Maurice; Caputo, Mário V.; Loboziak, Stanislas; Melo, José Henrique G.

2000-11-01

Palynomorph distribution in Euramerica and western Gondwana, from the Latest Givetian to the Latest Famennian, may be explained, to some extent, by climatic changes. Detailed miospore stratigraphy dates accurately the successive steps of these changes. Interpretation is built on three postulates which are discussed: Euramerica at slightly lower latitudes than generally accepted by most paleomagnetic reconstructions; a conodont time-scale accepted as the most used available subdivision of time; and Late Devonian sea-level fluctuations mainly governed by glacio-eustasy. The Frasnian-Famennian timescale is also evaluated. The comparison, based on conodont correlations, between Givetian and most of the Frasnian miospore assemblages from, respectively, northern and southern Euramerica demonstrates a high taxonomic diversity in the equatorial belt and much difference between supposed equatorial and (sub) tropical vegetations. On the contrary, a similar vegetation pattern and therefore probably compatible climatic conditions were present from tropical to subpolar areas. A rather hot climate culminated during the Latest Frasnian when equatorial miospore assemblages reached their maximum width. The miospore diversity shows also a rather clear global Late Frasnian minimum which is also recorded during the Early and Middle Famennian but only in low latitude regions while, in high latitude, very cold climates without perennial snow may explain the scarcity of miospores and so, of vegetation. The Early and Middle Famennian conspicuous latitudinal gradient of the vegetation seems to attenuate towards the Late and Latest Famennian but this might be above all the result of the development, of cosmopolitan coastal lowland vegetations (downstream swamps) depending more on the moisture and equable local microclimates than on the probably adverse climates of distant hinterland areas. During that time, periods of cold climate without perennial snow cover and with rare vegetation may have alternated with less cold but wetter climates, thus giving rise to the development of mountain glaciers in high latitudes and explaining the jerking character of the global major marine regression. In high latitude regions, the development of an ice cap reaching sea level is only recorded by the end of the Latest Famennian, immediately below the DCB but, even if glacial evidences are not known at near the FFB, a short (0.1 Ma?) glaciation seems the best reasonable explanation of the major eustatic fall following the Kellwasser Event. The sudden growth and decay of a hypothetical Earliest Famennian ice sheet can be explained by the reduction and, later, increase in greenhouse capacity of the atmosphere. These changes in the atmospheric CO 2 might have provoked changes in the mode of ocean-atmosphere operation. It may also be partly controlled by a volcanic paroxysm and/or bolide impacts. The Hony microtektites represent the best known evidence of the impact of extraterrestrial bodies on Earth corresponding to the UKW, and they are immediately followed by a regression, suggested by the quantitative analysis of acritarch assemblages. In the paleo-tropical Late Famennian, a peat-forming vascular plant community occurs for the first time and makes possible quantitative palynology of autochthonous sediments allowing the recognition of different swamp and near-swamp characteristic miospores. The early Latest Famennian starts with a widespread transgression which could correspond to the melting phases of the hypothetical Late Famennian mountain glaciers. During the end-Famennian, the coastal lowland vegetation has a worldwide distribution from sub-polar to equatorial regions. The climate has become less cold in high latitudes but wetter than before probably because the midlatitude cyclonic activity allows sufficient polar transportation of moisture to form large snow cover. Extensive coastal glaciers developed in different Bolivian and Brazilian basins, well dated by miospores. Rapid climatic changes characterize the onset of glaciation. The cyclic nature of climate allowed even intertropical marine faunas to reach occasionally the subpolar regions. For the plant kingdom, the crisis which follows the Hangenberg Event was more severe than the Late Frasnian Crisis.

The Rhynie hot-spring system: implications for the Devonian timescale, development of Devonian biota, gold mineralization, evolution of the atmosphere and Earth outgassing

NASA Astrophysics Data System (ADS)

Mark, D.; Rice, C.; Stuart, F.; Trewin, N.

2011-12-01

The Rhynie cherts are hot spring sinters that contain world-renowned plant and animal remains and anomalously high quantities of heavy metals, including gold. The biota in several beds is preserved undeformed with plants in life positions thus establishing that they and the indurating hydrothermal fluids were coeval. Despite the international importance of the Rhynie cherts their age has been poorly constrained for three reasons: (1) lack of a precise radio-isotopic age, (2) low resolution of spore biostratigraphic schemes for Devonian terrestrial deposits, with only one to a few zones per stage, and (3) poor resolution of the early Devonian timescale. Wellman (2004) assigned a Pragian-?earliest Emsian age to the Rhynie cherts on the basis of the spore assemblage. An 40Ar/39Ar dating study targeting Rhynie chert yielded an age of 395 ± 12 Ma (1σ) (Rice et al., 1995). This contribution discusses a new high-precision 40Ar/39Ar age (407.1 ± 2.2 Ma, 2σ) for the Devonian hot-spring system at Rhynie (Mark et al., 2011) and demonstrates that a proposed U-Pb age (411.5 ± 1.1 Ma, 2σ) for the Rhynie cherts (Parry et al., 2011) is inconsistent with both field evidence and our interpretation of the U-Pb data. The 40Ar/39Ar age provides a robust marker for the polygonalis-emsiensis Spore Assemblage Biozone within the Pragian-?earliest Emsian. It also constrains the age of a wealth of flora and fauna preserved in life positions as well as dating gold mineralization. Furthermore, we have now determined the Ar isotope composition of pristine samples of the Rhynie chert using an ARGUS multi-collector mass spectrometer and a low blank laser extraction technique. 40Ar/36Ar are systematically lower than the modern air value (Lee et al., 2006), and are not accompanied by non-atmospheric 38Ar/36Ar ratios. We conclude that the Rhynie chert captured and has preserved Devonian atmosphere-derived Ar. The data indicate that the 40Ar/36Ar of Devonian atmosphere was at least 3 % lower than the modern air value (Lee et al., 2006). Thus the Earth's atmosphere has accumulated at least 5 ± 0.2 x 1016 moles of 40Ar in the last c. 407 Ma, at an average rate of 1.24 ± 0.06 x 108 mol 40Ar/year. This overlaps the 40Ar accumulation rate determined from ice cores for the last 800,000 years (Bender et al. 2008) and implies that there has been no resolvable temporal change in outgassing rate since the mid-Palaeozoic. The new chronological and Ar isotope data provide a unique tie point and dictate outgassing of the Earth's interior early in Earth history. [1] Bender, M. et al. (2008) Proceedings of the National Academy of Sciences, 105, 8232-8237. [2] Wellman, C.H., 2004. Proceedings of the Royal Society of London. Biological Sciences, 271, 985-992. [3] Lee, J.Y. et al. (2006) Geochimica et Cosmochimica Acta, 70, 4507-4512. [4] Mark, D.F. et al. (2011) Geochimica et Cosmochimica Acta, 75, 555-569. [5] Parry, S.F. et al. (2011) Journal of the Geological Society, London, 168, 863-872. [6] Rice, C.M. et al. (1995) Journal of the Geological Society, London, 152, 229-2250.

Mid to late Devonian back-arc rift basins in the Brooks Range, AK, and across the Arctic: a possible paleogeographic piercing point for Arctic reconstructions

NASA Astrophysics Data System (ADS)

Hoiland, C. W.; Miller, E. L.; Hourigan, J. K.

2013-12-01

The westernmost Brooks Range, Alaska, is underlain by basement of probable Baltic or Timanian affinity (e.g. Miller et al., 2011; Amato et al., 2009), while the eastern Brooks Range is underlain by Laurentian affinity basement (e.g. Strauss et al., 2013). A post-Timanian and pre-Mississippian suture or contact is thus required based on continuity of late Devonian and younger strata across the Brooks Range (e.g. Dumoulin et al., 2002). This inferred juxtaposition has been proposed as the distal and diachronous (though possibly non-collisional) continuation of the Caledonian orogen (e.g. Moore et al., 2012) but the actual location and character of this suture within basement rocks of the Brooks Range remain speculative. New laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb single grain detrital zircon (DZ) geochronology of basement rocks from the Cosmos Hills, Slate Creek, and Wiseman regions suggest that metamorphic rocks in these regions are Devonian, not pre-Devonian. New SHRIMP-RG analyses of the Kogoluktuk orthogneiss (Cosmos) (zircon: 383 Ma × 5 Ma, 2-sigma errors, consistent with Dillon et al. 1980) revealed no inherited cores from which to infer basement affinity. DZ spectra from metasedimentary and metavolcanic wall rock contain youngest detrital zircon populations with ages (390 Ma) just barely older than the cross-cutting intrusive age, providing tight bracketing of depositional age. These zircon ages are noticeably younger than Caledonian magmatic ages (430-420 Ma) suggesting deposition in a volcanically and tectonically active setting (likely extensional) as originally suggested by Hitzman et al (1986). Zircon spectra (Cosmos) contain notable amounts of "Timanian" age zircons (c. 700-550 Ma), and a spread of zircons from 1-2 Ga (including 1.5-1.6 Ga ages of the Laurentian "magmatic gap', e.g. Grove et al. 2008) more typical of derivation from Baltic rather than Laurentian sources. East in the Wiseman and Slate Creek localities, the detrital signature becomes characteristically Laurentian, with a notable absence of Timanian and "magmatic gap" ages. A youngest age population of 390 Ma still provides a maximum depositional age, but minimum age is poorly constrained. The coarse and feldspathic nature of many of these intercalated volcanic and clastic sequences suggests a proximal provenance, thus serving as a proxy for local pre-Devonian basement ages and affinity. We might, therefore, infer a non-Laurentian basement for the AACM at least as far east as the Cosmos Hills but not further east than the Wiseman region. These Devonian-age volcanic/rift basins may be related to slab roll-back and induced backarc rifting that occurred obliquely across a 'Caledonian' suture, possibly in response to global plate re-organization. Rifting, accompanied by bimodal volcanism (the Ambler Sequence), may have aided the removal and translation of peri-Baltic terranes to a position outboard of the proto-Cordilleran margin ('Northwestern Passage' of Colpron & Nelson, 2009). Further correlations might be drawn with the Sakmarian-Magnitogorsk arcs of the pre-Uralian margin of Europe. These Devonian backarc rift sequences - more widespread than previously thought - may serve as critical additional tie-points for paleogeographic reconstructions of the Arctic.

Leaf evolution in early-diverging ferns: insights from a new fern-like plant from the Late Devonian of China.

PubMed

Wang, De-Ming; Xu, Hong-He; Xue, Jin-Zhuang; Wang, Qi; Liu, Le

2015-06-01

With the exception of angiosperms, the main euphyllophyte lineages (i.e. ferns sensu lato, progymnosperms and gymnosperms) had evolved laminate leaves by the Late Devonian. The evolution of laminate leaves, however, remains unclear for early-diverging ferns, largely represented by fern-like plants. This study presents a novel fern-like taxon with pinnules, which provides new insights into the early evolution of laminate leaves in early-diverging ferns. Macrofossil specimens were collected from the Upper Devonian (Famennian) Wutong Formation of Anhui and Jiangsu Provinces, South China. A standard degagement technique was employed to uncover compressed plant portions within the rock matrix. A new fern-like taxon, SHOUGANGIA BELLA GEN ET SP NOV: , is described and represents an early-diverging fern with highly derived features. It has a partially creeping stem with adventitious roots only on one side, upright primary and secondary branches arranged in helices, tertiary branches borne alternately or (sub)oppositely, laminate and usually lobed leaves with divergent veins, and complex fertile organs terminating tertiary branches and possessing multiple divisions and numerous terminal sporangia. Shougangia bella provides unequivocal fossil evidence for laminate leaves in early-diverging ferns. It suggests that fern-like plants, along with other euphyllophyte lineages, had independently evolved megaphylls by the Late Devonian, possibly in response to a significant decline in atmospheric CO2 concentration. Among fern-like plants, planate ultimate appendages are homologous with laminate pinnules, and in the evolution of megaphylls, fertile organs tend to become complex. © The Author 2015. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Sedimentology, CSFe relationships and stable isotopic compositions in Devonian black mudrocks, Mackenzie Mountains, Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Al-Aasm, I. S.; Morad, S.; Durocher, S.; Muir, I.

1996-11-01

An integrated approach combining CSFe relationships, stable isotopic compositions, and lithofacies characterization was utilized to constrain the palaeoenvironmental and early diagenetic conditions of Middle-Upper Devonian (Eifelian-Frasnian) mudrocks from the Mackenzie Mountains, Northwest Territories, Canada. These rocks include the Hare Indian Formation (informally subdivided into the lower Bluefish Member and the Hare Indian Upper Member), Carcajou Marker and Canol Formation. The Bluefish Member is dominated by black, laminated, organic-rich shales (TOC = 0.35-10.34 wt.%; av. 5.83 wt.) with moderate degrees of pyritization (DOP) of 0.34-0.67 (av. 0.55). These mudrocks were deposited in dysoxic marine bottom-waters that became progressively more oxygenated with time. Variations in TOC, DOP and organic matter δ 13C PDB values (-29.7% to -19.9%; av. -27.2%) are attributed to repeated clastic dilution and increased input of terrestrial organic matter in association with shallowing-upward ramp-clinothem cycles. Pyrite δ 34S CDT values (-32.7% to -18.8%; av. -24.9%) indicate an open system, bacteriogenic seawater-sulphate reduction. Conversely, the overlying Hare Indian Upper Member, characterized by clinothem facies, is composed of grey to green mudstone with minor argillaceous limestones and considerably less organic matter contents (TOC = 0.28-2.99 wt.%; δ 13C = -29.5% to -22.5%). Deposition occurred in oxic to slightly dysoxic waters (DOP = 0.20-0.54; δ 34S = -23.0% to -20.9%), depending on the palaeotopographic location along the depositional slope. A rapid rise in sea level drowned the carbonate 'ramp' member of the Ramparts Formation and produced the thin, organic-rich Carcajou Marker. Bottom-water stagnation that resulted from subdued ramp palaeotopography produced anoxic sea bottom. Black, laminated, organic-rich shales from the Canol Formation (TOC = 1.37-6.68 wt.%) are very similar to those of the Bluefish Member, and are likewise basinal sediments. However, TOC, DOP and organic-matter δ 13C PDB values (-29.1% to -20.8%; av. -26.2%) do not show pronounced variations and indicate that low-energy, quietwater conditions persisted over relatively long, uninterrupted periods of time. High DOP values (0.72-0.93) throughout the Canol Formation suggest that deposition occurred in anoxic bottom-waters, but as basin-fill conditions continued there was a shift to a dysoxic environment (DOP = 0.55-0.65), which grades into nearshore and offshore sequences of the overlying Imperial Formation. In contrast with the Hare Indian Formation, much heavier δ 34S CDT values of pyrite in Canol mudrocks (-11.1% to +5.3%; av. -3.1%) point to bacterial sulphate reduction in a closed to semi-closed system with respect to seawater sulphate.

Impact ejecta layer from the mid-Devonian: possible connection to global mass extinctions.

PubMed

Ellwood, Brooks B; Benoist, Stephen L; El Hassani, Ahmed; Wheeler, Christopher; Crick, Rex E

2003-06-13

We have found evidence for a bolide impacting Earth in the mid-Devonian ( approximately 380 million years ago), including high concentrations of shocked quartz, Ni, Cr, As, V, and Co anomalies; a large negative carbon isotope shift (-9 per mil); and microspherules and microcrysts at Jebel Mech Irdane in the Anti Atlas desert near Rissani, Morocco. This impact is important because it is coincident with a major global extinction event (Kacák/otomari event), suggesting a possible cause-and-effect relation between the impact and the extinction. The result may represent the extinction of as many as 40% of all living marine animal genera.

Input-form data for the U.S. Geological Survey assessment of the Devonian and Mississippian Bakken and Devonian Three Forks Formations of the U.S. Williston Basin Province, 2013

USGS Publications Warehouse

,; Gaswirth, Stephanie B.; Marra, Kristen R.; Cook, Troy A.; Charpentier, Ronald R.; Gautier, Donald L.; Higley, Debra K.; Klett, Timothy R.; Lewan, Michael D.; Lillis, Paul G.; Schenk, Christopher J.; Tennyson, Marilyn E.; Whidden, Katherine J.

2013-01-01

In 2013, the U.S. Geological Survey assessed the technically recoverable oil and gas resources of the Bakken and Three Forks Formations of the U.S. portion of the Williston Basin. The Bakken and Three Forks Formations were assessed as continuous and hypothetical conventional oil accumulations using a methodology similar to that used in the assessment of other continuous- and conventional-type assessment units throughout the United States. The purpose of this report is to provide supplemental documentation and information used in the Bakken-Three Forks assessment.

Impact Ejecta Layer from the Mid-Devonian: Possible Connection to Global Mass Extinctions

NASA Astrophysics Data System (ADS)

Ellwood, Brooks B.; Benoist, Stephen L.; Hassani, Ahmed El; Wheeler, Christopher; Crick, Rex E.

2003-06-01

We have found evidence for a bolide impacting Earth in the mid-Devonian (~380 million years ago), including high concentrations of shocked quartz, Ni, Cr, As, V, and Co anomalies; a large negative carbon isotope shift (-9 per mil); and microspherules and microcrysts at Jebel Mech Irdane in the Anti Atlas desert near Rissani, Morocco. This impact is important because it is coincident with a major global extinction event (Kacák/otomari event), suggesting a possible cause-and-effect relation between the impact and the extinction. The result may represent the extinction of as many as 40% of all living marine animal genera.

Thermal maturity patterns in New York State using CAI and %Ro

USGS Publications Warehouse

Weary, D.J.; Ryder, R.T.; Nyahay, R.E.

2001-01-01

New conodont alteration index (CAI) and vitrinite reflectance (%Ro) data collected from drill holes in the Appalachian basin of New York State allow refinement of thermal maturity maps for Ordovician and Devonian rocks. CAI isotherms on the new maps show a pattern that approximates that published by Harris et al. (1978) in eastern and western New York, but it differs in central New York, where the isotherms are shifted markedly westward by more than 100 km and are more tightly grouped. This close grouping of isograds reflects a steeper thermal gradient than previously noted by Harris et al. (1978) and agrees closely with the abrupt west-to-east increase in thermal maturity across New York noted by Johnsson (1986). These data show, in concordance with previous studies, that thermal maturity levels in these rocks are higher than can be explained by simple burial heating beneath the present thickness of overburden. The Ordovician and Devonian rocks of the Appalachian Basin in New York must have been buried by very thick post-Devonian sediments (4-6 km suggested by Sarwar and Friedman 1995) or were exposed to a higher-than-normal geothermal flux caused by crustal extension, or a combination of the two.

Suprasubduction volcanic rocks of the Char ophiolite belt, East Kazakhstan: new geochemical and first geochronological data

NASA Astrophysics Data System (ADS)

Safonova, Inna; Simonov, Vladimir; Seltmann, Reimar; Yamamoto, Shinji; Xiao, Wenjiao

2016-04-01

The Char ophiolite belt is located in the western Central Asian Orogenic Belt, a world largest accretionary orogen, which has evolved during more than 800 Ma. The Char belt formed during Kazakhstan - Siberia collision. It has been known for hosting fragments of Late Devonian-Early Carboniferous oceanic crust, MORB, OPB and OIB, of the Paleo-Asian Ocean (Safonova et al., 2012). The Char is surrounded by two Paleozoic island-arc terranes: Zharma-Saur in the west and Rudny Altai in the east, however, until recent times, no island-arc units have been found within it. We were the first to find island-arc units as tectonic sheets occurring adjacent to those consisting of oceanic rocks. In places, island-arc andesites cut oceanic basalts. The Char volcanic and subvolcanic rocks of a probable suprasubduction origin are basalt, microgabbro, dolerite, andesite, tonalite and dacite. The mafic to andesitic volcanics possessing low TiO2 (0.85 wt.%av.) and show MgO vs. major elements crystallization trends suggesting two magma series: tholeiitic and calc-alkaline. The tholeiitic varieties are less enriched in incompatible elements then the calc-alkaline ones. Two samples are high-Mg and low-Ti andesibasalts similar to boninites. The rocks possess moderately LREE enriched rare-earth element patterns and are characterized by negative Nb anomalies present on the multi-element spectra (Nb/Lapm = 0.14-0.47; Nb/Thpm = 0.7-1.6).The distribution of rare-earth elements (La/Smn = 0.8-2.3, Gd/Ybn = 0.7-1.9) and the results of geochemical modeling in the Nb-Yb system suggest high degrees of melting of a depleted harzburgite-bearing mantle source at spinel facies depths. Fractional crystallization of clinopyroxene, plagioclase and opaque minerals also affected the final composition of the volcanic rocks. Clinopyroxene monomineral thermometry indicates crystallization of melts at 1020-1180°C. Melt inclusion composition based numerical calculations show that primary melts were derived at 1350-1530°C and 14-26 kbar and crystallized at 1150-1190°C (Simonov et al., 2010). All these features are indicative of a supra-subduction origin of rocks. The age of gabbro, dolerite, andesite and tonalite was determined by LA ICP MS U-Pb zircon dating performed in the University of Kyoto, Japan. The andesites and tonalites yielded Carboniferous ages of ca. 322-336 Ma and the gabbro and dolerite appeared Devonian (387-395 Ma). Thus, the Char volcanic rocks possess geochemical signatures of supra-subduction magmas and could be derived at high degree melting of relatively shallow mantle sources. The volcanic units probably formed at one or two island-arcs or at an intra-oceanic arc and continental margin arc during the Middle Devonian - Mississippian. Later, the island-arc units were probably accreted to the active margin of the Kazakhstan continent. The work was supported by RFBR Project no. 16-05-00313. Contribution to IGCP#592 of UNESCO-IUGS. Safonova, I.Yu., Simonov V.A., Kurganskaya E.V., Obut O.T., Romer R.L., Seltmann R., 2012. Late Paleozoic oceanic basalts hosted by the Char suture-shear zone, East Kazakhstan: geological position, geochemistry, petrogenesis and tectonic setting. Journal of Asian Earth Sciences 49, 20-39. Simonov V.A., Safonova I.Yu., Kovyazin S.V., 2010. Petrogenesis of island-arc complexes of the Char zone, East Kazakhstan. Petrology 18, 59-72.

Assessment of Paleozoic terrane accretion along the southern central Andes using detrital zircon geochronology

NASA Astrophysics Data System (ADS)

McKenzie, R.; Horton, B. K.; Fuentes, F.; Fosdick, J. C.; Capaldi, T.; Stockli, D. F.; Alvarado, P. M.

2015-12-01

Two distinct Paleozoic terranes known as Cuyania and Chilenia occupy the southern central Andes of Argentina and Chile. Because the proposed terrane boundaries coincide with major structural elements of the modern Andean system at 30-36°S, it is important to understand their origins and potential role in guiding later Andean deformation. The Cuyania terrane of western Argentina encompasses the Precordillera (PC) and a thick-skinned thrust block of the western Sierras Pampeanas, persisting southward to the San Rafael Basin (SRB). Although recently challenged, Cuyania has been long considered a piece of southern Laurentia that rifted away during the early Cambrian and collided with the Argentine margin during the Ordovician. Chilenia is situated west of Cuyania and includes the Frontal Cordillera (FC) and Andean magmatic arc. This less-studied terrane was potentially accreted during an enigmatic Devonian orogenic event. We present new detrital zircon U-Pb age data from siliciclastic sedimentary rocks that span the entire Paleozoic to Triassic from the FC, PC, and SRB. Cambrian rocks of the PC exhibit similar zircon age distributions with prominent ~1.4 and subordinate ~1.1 Ga populations, which are distinct from other Paleozoic strata. Plutonic rocks with these ages are common in southern Laurentia, whereas ~1.4 Ga zircons are uncommon in South American age distributions. This supports a Laurentian origin for Cuyania in isolation from Argentina during the Cambrian. Upper Paleozoic strata from the PC, FC, and SRB all yield similar age data suggesting shared provenance across the proposed Cuyania-Chilenia suture. Age distributions also notably lack Devonian-age grains. The regional paucity of Devonian plutonic rocks and detrital zircon casts doubt on a possible arc system between these terranes at this time, a key requisite for the mid-Paleozoic transfer and accretion of Chilenia to the Argentine margin. Collectively, these data question the precise boundaries of the Chilenia terrane.

Provenance and paleogeography of the Devonian Durazno Group, southern Parana Basin in Uruguay

NASA Astrophysics Data System (ADS)

Uriz, N. J.; Cingolani, C. A.; Basei, M. A. S.; Blanco, G.; Abre, P.; Portillo, N. S.; Siccardi, A.

2016-03-01

A succession of Devonian cover rocks occurs in outcrop and in the subsurface of central-northern Uruguay where they were deposited in an intracratonic basin. This Durazno Group comprises three distinct stratigraphic units, namely the Cerrezuelo, Cordobés and La Paloma formations. The Durazno Group does not exceed 300 m of average thickness and preserves a transgressive-regressive cycle within a shallow-marine siliciclastic shelf platform, and is characterized by an assemblage of invertebrate fossils of Malvinokaffric affinity especially within the Lower Devonian Cordobés shales. The sedimentary provenance of the Durazno Group was determined using petrography, geochemistry, and morphological studies of detrital zircons as well as their U-Pb ages. Sandstone petrography of Cerrezuelo and La Paloma sequences shows that they have a dominantly quartz-feldspathic composition with a minor contribution of other minerals. Whole-rock geochemical data indicate that alteration was strong in each of the three formations studied; chondritic-normalized REE patterns essentially parallel to PAAS, the presence of a negative Eu-anomaly, and Th/Sc and La/Hf ratios point to an average source composition similar to UCC or slightly more felsic. Within the Cerrezuelo Formation, recycling of older volcano-metasedimentary sources is interpreted from Zr/Sc ratios and high Hf, Zr, and REE concentrations. U-Pb detrital zircon age populations of the Cerrezuelo and La Paloma formations indicate that the principal source terranes are of Neoproterozoic age, but include also minor populations derived from Mesoproterozoic and Archean-Paleoproterozoic rocks. A provenance from the Cuchilla Dionisio-Dom Feliciano, Nico Pérez and Piedra Alta terranes of Uruguay and southern Brazil is likely. This study establishes an intracratonic extensional tectonic setting during Durazno time. Considering provenance age sources, regional paleocurrent distributions and the established orogenic history recorded in SW Gondwana, we suggest that the basin fill was derived from paleohighs located in what is currently SE Uruguay.

The giant Carlin gold province: A protracted interplay of orogenic, basinal, and hydrothermal processes above a lithospheric boundary

USGS Publications Warehouse

Emsbo, P.; Groves, D.I.; Hofstra, A.H.; Bierlein, F.P.

2006-01-01

Northern Nevada hosts the only province that contains multiple world-class Carlin-type gold deposits. The first-order control on the uniqueness of this province is its anomalous far back-arc tectonic setting over the rifted North American paleocontinental margin that separates Precambrian from Phanerozoic subcontinental lithospheric mantle. Globally, most other significant gold provinces form in volcanic arcs and accreted terranes proximal to convergent margins. In northern Nevada, periodic reactivation of basement faults along this margin focused and amplified subsequent geological events. Early basement faults localized Devonian synsedimentary extension and normal faulting. These controlled the geometry of the Devonian sedimentary basin architecture and focused the discharge of basinal brines that deposited syngenetic gold along the basin margins. Inversion of these basins and faults during subsequent contraction produced the complex elongate structural culminations that characterize the anomalous mineral deposit "trends." Subsequently, these features localized repeated episodes of shallow magmatic and hydrothermal activity that also deposited some gold. During a pulse of Eocene extension, these faults focused advection of Carlin-type fluids, which had the opportunity to leach gold from gold-enriched sequences and deposit it in reactive miogeoclinal host rocks below the hydrologic seal at the Roberts Mountain thrust contact. Hence, the vast endowment of the Carlin province resulted from the conjunction of spatially superposed events localized by long-lived basement structures in a highly anomalous tectonic setting, rather than by the sole operation of special magmatic or fluid-related processes. An important indicator of the longevity of this basement control is the superposition of different gold deposit types (e.g., Sedex, porphyry, Carlin-type, epithermal, and hot spring deposits) that formed repeatedly between the Devonian and Miocene time along the trends. Interestingly, the large Cretaceous Alaska-Yukon intrusion-related gold deposits (e.g., Fort Knox) are associated with the northern extension of the same lithospheric margin in the Selwyn basin, which experienced an analogous series of geologic events. ?? Springer-Verlag 2006.

Peronosporomycetes (Oomycota) from a Middle Permian Permineralised Peat within the Bainmedart Coal Measures, Prince Charles Mountains, Antarctica

PubMed Central

Slater, Ben J.; McLoughlin, Stephen; Hilton, Jason

2013-01-01

The fossil record of Peronosporomycetes (water moulds) is rather sparse, though their distinctive ornamentation means they are probably better reported than some true fungal groups. Here we describe a rare Palaeozoic occurrence of this group from a Guadalupian (Middle Permian) silicified peat deposit in the Bainmedart Coal Measures, Prince Charles Mountains, Antarctica. Specimens are numerous and comprise two morphologically distinct kinds of ornamented oogonia, of which some are attached to hyphae by a septum. Combresomyces caespitosus sp. nov. consists of spherical oogonia bearing densely spaced, long, hollow, slender, conical papillae with multiple sharply pointed, strongly divergent, apical branches that commonly form a pseudoreticulate pattern under optical microscopy. The oogonia are attached to a parental hypha by a short truncated stalk with a single septum. Combresomyces rarus sp. nov. consists of spherical oogonia bearing widely spaced, hollow, broad, conical papillae that terminate in a single bifurcation producing a pair of acutely divergent sharply pointed branches. The oogonium bears a short truncate extension where it attaches to the parental hypha. We propose that similarities in oogonium shape, size, spine morphology and hyphal attachment between the Permian forms from the Prince Charles Mountains and other reported Peronosporomycetes from Devonian to Triassic strata at widely separated localities elsewhere in the world delimit an extinct but once cosmopolitan Palaeozoic to early Mesozoic branch of the peronosporomycete clade. We name this order Combresomycetales and note that it played an important role in late Palaeozoic and early Mesozoic peatland ecosystems worldwide. PMID:23936465

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dallmeyer, R.D.; Gee, D.G.; Beckholmen, M.

In central portions of the Scandinavian Caledonides, greenschist facies volcanosedimentary successions within the Koeli Nappe Complex have been thrust several hundred kilometers eastward onto the Baltoscandian platform. These were derived from eugeoclinal terranes situated outboard (west) of the Baltica continent during the early Paleozoic. The Koeli Nappe Complex is tectonically underlain by higher grade units within the Seve Nappe Complex. These are composed of amphibolite and granulite facies rocks and locally contain eclogites. The Seve Nappes tectonically separate Koeli units from structurally lower allochthons derived from more inboard environments along the Baltoscandian miogeocline. Previous mineral isotopic age-determinations from Seve andmore » Koeli units have been in the 430 to 390 Ma range and have been interpreted to presumably date cooling following Scandian (Middle Silurian to Early Devonian) metamorphism. However, incremental-release /sup 40/Ar//sup 39/Ar dates recorded by minerals within some of the Koeli and Seve Nappes exposed in Jaemtland, Sweden (Taennforsen and Are districts) provide evidence of earlier tectonothermal activity. Hornblendes from the Seve and Koeli Nappe Complexes display variably discordant age spectra as a result of low-temperature, experimental evolution of loosely bound extraneous argon components. However, in most analyses plateau ages of 510 to 475 Ma (Koeli) and 465 to 455 Ma (Seve) are defined. In contrast, muscovite and biotite from all tectonic units record Scandian cooling ages between 245 and 410 Ma. The older events recorded by hornblende within these Seve and Koeli units are evidence of early Caledonian tectonothermal activity and subsequent diachronous cooling during the Early-Middle Ordovician.« less

Paleoclimatic and paleomagnetic constraints on the Paleozoic reconstructions of south China, north China and Tarim

NASA Astrophysics Data System (ADS)

Shangyou, Nie

1991-10-01

Paleomagnetic and paleoclimatic data provide the most useful latitudinal constraints for plate reconstructions. Distributions through the Paleozoic of five types of climatically sensitive sediments (coals, evaporites, reefs, dolomites and limestones) for south China, north China and Tarim are shown on 15 maps that include 1578 reliable data points. These paleoclimatic data agree reasonably well with available paleomagnetic directions, although significant divergence between the two exists for the Early Paleozoic. These data indicate the following: (1) South China was in low latitudes during the entire Paleozoic, with a subtropical position in the Cambrian. (2) North China also remained near the equator in the Early and Late Paleozoic, except for the Ordovian and the Late Permian when extensive evaporites suggest slightly higher latitudinal positions, while its Middle Paleozoic position is uncertain due to the missing stratigraphie record. (3) In south China, local tectonics appears to have played a dominant role in determining paleogeography and therefore marine sedimentation, especially after the Late Ordovician-Early Silurian, because the areal coverage of marine sediments through time is distinctly different from what would be expected from published global sea-level curves. (4) Paleoclimatic and paleomagnetic data are compatible with biogeographic data which suggest that south China was part of eastern Gondwana in the Early Paleozoic, but was widely separated from Gondwana in the Late Paleozoic, and the split between the two probably happened in the Devonian, giving rise to a major break-up unconformity in central south China.

"Belgian black and red marbles" as potential candidates for Global Heritage Stone Resource

NASA Astrophysics Data System (ADS)

Tourneur, Francis; Pereira, Dolores

2016-04-01

The Paleozoic substrate of South Belgium is rich in compact limestones, able to take a good polished finishing and to be used as "marbles". Among them, the black and red varieties were and still are of special importance, intensively exploited and largely exported, almost worldwide. The pure black marbles were extracted mostly from Frasnian (Upper Devonian) and Viséan (Lower Carboniferous) strata, in many localities like Namur, Dinant, Theux and Basècles. Today only the Frasnian variety is still exploited in a spectacular underground quarry in Golzinne, close to the town of Gembloux. These black marbles, already known in Antiquity, were exported since the Middle Age, first in Western Europe, then, from the 19th c., at a larger scale, almost worldwide. Among their most frequent uses figured of course funeral objects, like the epitaph of the Pope Adrian the 1st, offered by Charlemagne and preserved in the St-Pieter basilica in Rom. Another famous reference is the tombs of the Dukes of Burgundy in Dijon, with white crystalline marble and alabaster. The red marbles are limestones from reefal origin, forming mudmounds more or less rich in fossils of Late Frasnian (Late Devonian) age. They show a strong variability in colors, from dark red to light pinkish grey, and in texture, with many sedimentary structures and/or tectonic veins. The outcrops are non-stratified, which allows extraction of large blocks, for example for high columns. Known in the Roman time, they were intensively exploited since at least the 16th c. During the 19th and beginning of 20th c., more than hundred quarries were active in South Belgium, from Rance at West to Chaudfontaine at East, around Philippeville and Rochefort. They were largely used both in civil and religious buildings, mostly for inside decoration, for examples as altars or fireplaces. Among the most symbolic places, the Belgian red marbles were massively employed in Versailles, like in the famous "Galerie des Glaces". But many examples of historical buildings are known around the world, for examples the decoration of the harem of Topkapi in Istanbul in the 19th c. or in the floors of the St-Pieter basilica in Rom. Today, only one quarry is active, in Vodelée, a village close to Philippeville but all the varieties of colors and textures can be obtained from this unique source. Both referred materials present the characteristics needed to be candidates to the Global Heritage Stone Resource designation.

The potential of paleozoic nonmarine trace fossils for paleoecological interpretations

USGS Publications Warehouse

Maples, C.G.; Archer, A.W.

1989-01-01

Many Late Paleozoic environments have been interpreted as marine because of the co-occurrence of supposedly exclusively marine trace fossils. Beginning in the Late Ordovician, however, nonmarine trace-fossil diversity increased throughout the Paleozoic. This diversification of nonmarine organisms and nonmarine trace fossils was especially prevalent in Devonian and later times. Diversification of freshwater organisms is indicated by the large number of freshwater fish, arthropods, annelids and molluscs that had developed by the Carboniferous. In addition to diverse freshwater assemblages, entirely terrestrial vertebrate and invertebrate ecosystems had developed by the Devonian. This rapid diversification of freshwater and terrestrial organisms is inherently linked to development and diversification of land plants and subsequent shedding of large quantities of organic detritus in nonmarine and marginal-marine areas. Nearshore marine organisms and their larvae that are able to tolerate relatively short periods of lowered salinities will follow salt-water wedges inland during times of reduced freshwater discharge. Similarly, amphidromous marine organisms will migrate periodically inland into nonmarine environments. Undoubtedly, both of these processes were active in the Paleozoic. However, both processes are restricted to stream/distributary channels, interdistributary bays, or estuaries. Therefore, the presence of diverse trace-fossil assemblages in association with floodplain deposits is interpreted to reflect true nonmarine adaptation and diversity. Conversely, diverse trace-fossil assemblages in association with stream/distributary channel deposits, interdistributary-bay deposits, or estuarine deposits may reflect migration of salt-water wedges inland, or migration of marine organisms into freshwater environments (amphidromy), or both. ?? 1989.

Late paleozoic base and precious metal deposits, East Tianshan, Xinjiang, China: Characteristics and geodynamic setting

USGS Publications Warehouse

Mao, J.; Goldfarb, R.J.; Wang, Y.; Hart, C.J.; Wang, Z.; Yang, J.

2005-01-01

The East Tianshan is a remote Gobi area located in eastern Xinjiang, northwestern China. In the past several years, a number of gold, porphyry copper, and Fe(-Cu) and Cu-Ag-Pb-Zn skarn deposits have been discovered there and are attracting exploration interest. The East Tianshan is located between the Junggar block to the north and early Paleozoic terranes of the Middle Tianshan to the south. It is part of a Hercynian orogen with three distinct E-W-trending tectonic belts: the Devonian-Early Carboniferous Tousuquan-Dananhu island arc on the north and the Carboniferous Aqishan - Yamansu rift basin to the south, which are separated by rocks of the Kanggurtag shear zone. The porphyry deposits, dated at 322 Ma, are related to the late evolutionary stages of a subduction-related oceanic or continental margin arc. In contrast, the skarn, gold, and magmatic Ni-Cu deposits are associated with post-collisional tectonics at ca. 290-270 Ma. These Late Carboniferous - Early Permian deposits are associated with large-scale emplacement and eruption of magmas possibly caused by lithosphere delamination and rifting within the East Tianshan.

A geologic framework for mineralization in the western Brooks Range

USGS Publications Warehouse

Young, Lorne E.

2004-01-01

The Brooks Range is a 950-km-long north-vergent fold and thrust belt, which was formed during Mesozoic convergence of the continental Arctic Alaska terrane and the oceanic Angayucham terrane and was further shortened and uplifted in Tertiary time. The Arctic Alaska terrane consists of parautochthonous rocks and the Endicott Mountains and De Long Mountains subterranes. The Endicott Mountains allochthon of the western Brooks Range is the setting for many sulfide and barite occurrences, such as the supergiant Red Dog zinc-lead mine. Mineralization is sediment hosted and most commonly is present in black shale and carbonate turbidites of the Mississippian Kuna Formation. The reconstructed Kuna basin is a 200 by +600 km feature that represents the culmination of a remarkable chain of events that includes three fluvial-deltaic and two or more orogenic cycles, Middle Devonian to Mississippian episodes of extension and igneous activity, and the emergence of a seaward Lower Proterozoic landmass that may have constituted a barrier to marine circulation. Mississippian extension and related horst-and-graben architecture in the western Brooks Range is manifested in part by strong facies variability between coeval units of allochthons and structural plates. Shallow marine to possibly nonmarine arkose, platform to shelf carbonate, slope-to-basin shale, chert and carbonate turbidites, and submarine volcanic rocks are all represented in Mississippian time. The structural setting of Mississippian sedimentation, volcanism, and mineralization in the Kuna basin may be comparable to documented Devono-Mississippian extensional sags or half-grabens in the subsurface north of the Brooks Range. Climate, terrestrial ecosystems, multiple fluvial-deltaic aquifers, and structural architecture affected the liberation, movement, and redeposition of metals in ways that are incompletely understood.

Geochemical and mineralogical sampling of the Devonian shales in the Broadtop synclinorium, Appalachian basin, in Virginia, West Virginia, Maryland, and Pennsylvania

USGS Publications Warehouse

Enomoto, Catherine B.; Coleman, James L.; Swezey, Christopher S.; Niemeyer, Patrick W.; Dulong, Frank T.

2015-01-01

The presence of conventional anticlinal gas fields in the study area that are productive from the underlying Lower Devonian Oriskany Sandstone suggests that an unconventional (or continuous) shale gas system may be in place within the Marcellus Shale in the study area. Results of this study indicate that the Marcellus Shale in the Broadtop synclinorium generally is similar in organic geochemical nature throughout its extent, and based on the sample analyses, there are no clearly identifiable high potential areas (or “sweet spots”) in the study area. This report contains analyses of 132 outcrop and well drill-cuttings samples.

Spatial and temporal correlation of water quality parameters of produced waters from devonian-age shale following hydraulic fracturing.

PubMed

Barbot, Elise; Vidic, Natasa S; Gregory, Kelvin B; Vidic, Radisav D

2013-03-19

The exponential increase in fossil energy production from Devonian-age shale in the Northeastern United States has highlighted the management challenges for produced waters from hydraulically fractured wells. Confounding these challenges is a scant availability of critical water quality parameters for this wastewater. Chemical analyses of 160 flowback and produced water samples collected from hydraulically fractured Marcellus Shale gas wells in Pennsylvania were correlated with spatial and temporal information to reveal underlying trends. Chloride was used as a reference for the comparison as its concentration varies with time of contact with the shale. Most major cations (i.e., Ca, Mg, Sr) were well-correlated with chloride concentration while barium exhibited strong influence of geographic location (i.e., higher levels in the northeast than in southwest). Comparisons against brines from adjacent formations provide insight into the origin of salinity in produced waters from Marcellus Shale. Major cations exhibited variations that cannot be explained by simple dilution of existing formation brine with the fracturing fluid, especially during the early flowback water production when the composition of the fracturing fluid and solid-liquid interactions influence the quality of the produced water. Water quality analysis in this study may help guide water management strategies for development of unconventional gas resources.

Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-11-01

This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivitymore » values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.« less

A new osteichthyan from the late Silurian of Yunnan, China.

PubMed

Choo, Brian; Zhu, Min; Qu, Qingming; Yu, Xiaobo; Jia, Liantao; Zhao, Wenjin

2017-01-01

Our understanding of early gnathostome evolution has been hampered by a generally scant fossil record beyond the Devonian. Recent discoveries from the late Silurian Xiaoxiang Fauna of Yunnan, China, have yielded significant new information, including the earliest articulated osteichthyan fossils from the Ludlow-aged Kuanti Formation. Here we describe the partial postcranium of a new primitive bony fish from the Kuanti Formation that represents the second known taxon of pre-Devonian osteichthyan revealing articulated remains. The new form, Sparalepis tingi gen. et sp. nov., displays similarities with Guiyu and Psarolepis, including a spine-bearing pectoral girdle and a placoderm-like dermal pelvic girdle, a structure only recently identified in early osteichthyans. The squamation with particularly thick rhombic scales shares an overall morphological similarity to that of Psarolepis. However, the anterior flank scales of Sparalepis possess an unusual interlocking system of ventral bulges embraced by dorsal concavities on the outer surfaces. A phylogenetic analysis resolves Sparalepis within a previously recovered cluster of stem-sarcopterygians including Guiyu, Psarolepis and Achoania. The high diversity of osteichthyans from the Ludlow of Yunnan strongly contrasts with other Silurian vertebrate assemblages, suggesting that the South China block may have been an early center of diversification for early gnathostomes, well before the advent of the Devonian "Age of Fishes".

Global microbial carbonate proliferation after the end-Devonian mass extinction: Mainly controlled by demise of skeletal bioconstructors

PubMed Central

Yao, Le; Aretz, Markus; Chen, Jitao; Webb, Gregory E.; Wang, Xiangdong

2016-01-01

Microbial carbonates commonly flourished following mass extinction events. The end-Devonian (Hangenberg) mass extinction event is a first-order mass extinction on the scale of the ‘Big Five’ extinctions. However, to date, it is still unclear whether global microbial carbonate proliferation occurred after the Hangenberg event. The earliest known Carboniferous stromatolites on tidal flats are described from intertidal environments of the lowermost Tournaisian (Qianheishan Formation) in northwestern China. With other early Tournaisian microbe-dominated bioconstructions extensively distributed on shelves, the Qianheishan stromatolites support microbial carbonate proliferation after the Hangenberg extinction. Additional support comes from quantitative analysis of the abundance of microbe-dominated bioconstructions through the Famennian and early Tournaisian, which shows that they were globally distributed (between 40° latitude on both sides of the palaeoequator) and that their abundance increased distinctly in the early Tournaisian compared to the latest Devonian (Strunian). Comparison of variations in the relative abundance of skeleton- versus microbe-dominated bioconstructions across the Hangenberg and ‘Big Five’ extinctions suggests that changes in abundance of skeletal bioconstructors may play a first-order control on microbial carbonate proliferation during extinction transitions but that microbial proliferation is not a general necessary feature after mass extinctions. PMID:28009013

Modern methods rediscover deep gas. [Texas

DOE Office of Scientific and Technical Information (OSTI.GOV)

McDonald, J.S.

1979-03-01

In 1973, Northern Natural Gas (NNG) Co.'s Midland exploration and production district acquired a 7-section lease block on a Devonian-Montoya prospect suggested by trend geology and limited seismic data. This acreage block was 2 miles west of the abandoned Hershey field, and included acreage on which the Devonian was tested at noncommercial rates in 1962. Additional seismic data confirmed the presence of a drillable prospect on NNG's acreage block. Engineering analyses of the reservoir characteristics suggested that modern completion and treatment techniques would result in a commercial producer. NNG's management approved the expenditure and the first well was spudded inmore » April, 1977. This well, the No. 1 Hershenson, was completed in Sept., 1977 as the discovery well in the Hershey West (Devonian-Montoya) field for a calculated open flow potential (CAOFP) of 20.5 mmcfd dry gas from perforations at 15,445 to 16,017 ft. The confirmation well, No. 1 Hershenson 6, was spudded in May, 1978, and completed in Oct., 1978, for a CAOFP of 86.3 mmcfd from perforations at 16,000 to 16,624 ft. A third well, No. 1 Maddox-Willbanks 15, was spudded in Nov., 1978. Rediscovered field potential justified construction of a gas processing plant and a 16-mile pipeline.« less

Drilling of a deviated well: E. C. Newell 10056-D Meigs County, Ohio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodgers, J.A.

1982-09-30

The Department of Energy's (DOE) Eastern Gas Shales Program (EGSP) has focused primarily on the resource characterization of the Devonian shales in the Appalachian, Michigan and Illinois Basins, where the collective volume of gas in place is estimated to be on the order of 280 Tcf. From an early assessment of the petrophysical properties of these shales, attention now has turned to an understanding of the mechanisms controlling production of this unconventional-gas source. However, present knowledge of the production history of the Devonian shales is inadequate for an accurate estimation of the gas reserves, the optimum well spacing for gasmore » extraction, and the preferred stimulation techniques to be used. As part of this program, a Deviated Well Test was designed to evaluate the spacing of natural fractures in the Devonian shale in Meigs County, Ohio as a follow-on test to further define shale production characteristics and to assess the benefit of additional section gained by drilling through the producing interval at the approximate angle for dip of 60/sup 0/ from vertical. The Columbia Gas Transmission Company, E.C. Newell 10056-D well, on the same site as a previous Off-Set Well Test, was selected for this investigation. This report summarizes drilling operations on this Deviated Well Test.« less

Global climatic changes during the Devonian-Mississippian: Stable isotope biogeochemistry of brachiopods

NASA Astrophysics Data System (ADS)

Brand, Uwe

1989-12-01

A progressive trend towards heavier δ 13C values of Devonian-Mississippian brachiopods from North America, Europe, Afghanistan and Algeria probably reflects expansion of the terrestrestrial and/or marine biomass and/or burial of carbon in soils/sediments. Oceanic Productivity crises, based on perturbations in the overall δ 13C trend, are recognized for the Mid Givetian, Early Famennian, Late Kinderhookian, Late Osagean and Early and Late Meramecian. The Givetian productivity crisis was probably accompanied by massive overturn of biologically toxic deep-ocean water. Temperature data, adjusted for the possible secular variation of seawater, support the hypothesis of global greenhouse conditions for the Devonian (mean of 30°C, mean of 26°C if extrinsic data are deleted) and icehouse conditions for the Mississippian (mean of 17°C). During the Mid Givetian, Frasnian and Early Famennian calculated water temperatures for tropical epeiric seas were generally above the thermal threshold limit (˜ 38°C) of most marine invertebrates or epeiric seawater was characterized by unusually low salinities (˜ pp ppt) or a combination of the two. These elevated water temperatures and/or low salinities, in conjunction with the postulated productivity crises and overturning of toxic deep waters are considered prime causes for the biotic crisis of the Late Devonian. In addition, a presumed expanding oxygen-minimum zone and general anoxia in the oceans prevented shallow-water organisms from escaping these inhospitable conditions. Re-population of the tropical seas occurred, after either water temperatures had dropped below the thermal threshold limit and/or salinities were back to normal, and oceanic productivity had increased due to more vigorous oceanic circulation, sometime during the Mid-Late Famennian. Migration of eurythermal, shallow- and deeper-water organisms into the vacant niches of the shallow seas was possible because of, generally, slightly lower sea levels, but, more importantly of more restricted oxygen-minimum zone and generally reduced oceanic anoxia.

A new Late Devonian genus with seed plant affinities.

PubMed

Wang, Deming; Liu, Le

2015-02-26

Many ovules of Late Devonian (Famennian) seed plants have been well studied. However, because few taxa occur with anatomically preserved stems and/or petioles, the vascular system of these earliest spermatophytes is little understood and available data come mostly from Euramerica. There remains great controversy over the anatomical differentiation of Late Devonian and Carboniferous seed plant groups of Buteoxylonales, Calamopityales and Lyginopteridales. Protostele evolution of these early spermatophytes needs more research. A new taxon Yiduxylon trilobum gen. et sp. nov. with seed plant affinities has been discovered in the Upper Devonian (Famennian) Tizikou Formation of Hubei Province, China. It is represented by stems, helically arranged and bifurcate fronds with two orders of pinnae and planate pinnules. Both secondary pinnae and pinnules are borne alternately. Stems contain a small protostele with three primary xylem ribs possessing a single peripheral protoxylem strand. Thick secondary xylem displays multiseriate bordered pitting on the tangential and radial walls of the tracheids, and has biseriate to multiseriate and high rays. A narrow cortex consists of inner cortex without sclerotic nests and sparganum-type outer cortex with peripheral bands of vertically aligned sclerenchyma cells. Two leaf traces successively arise tangentially from each primary xylem rib and they divide once to produce four circular-oval traces in the stem cortex. Four vascular bundles occur in two C-shaped groups at each petiole base with ground tissue and peripheral bands of sclerenchyma cells. Yiduxylon justifies the assignment to a new genus mainly because of the protostele with protoxylem strands only near the periphery of primary xylem ribs, leaf trace origination and petiolar vascular supply structure. It shares many definitive characters with Calamopityales and Lyginopteridales, further underscoring the anatomical similarities among early seed plants. The primary vascular system, pycnoxylic-manoxylic secondary xylem with bordered pits on both tangential and radial walls of a tracheid and leaf trace divergence of Yiduxylon suggest transitional features between the early spermatophytes and ancestral aneurophyte progymnosperms.

Late Devonian glacigenic and associated facies from the central Appalachian Basin, eastern United States

USGS Publications Warehouse

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.

2010-01-01

Late Devonian strata in the eastern United States are generally considered as having been deposited under warm tropical conditions. However, a stratigraphically restricted Late Devonian succession of diamictite- mudstonesandstone within the Spechty Kopf and Rockwell Formations that extends for more than 400 km along depositional strike within the central Appalachian Basin may indicate other wise. This lithologic association unconformably overlies the Catskill Formation, where a 3- to 5-m-thick interval of deformed strata occurs immediately below the diamictite strata. The diamictite facies consists of several subfacies that are interpreted to be subglacial, englacial, supraglacial meltout, and resedimented deposits. The mudstone facies that overlies the diamictite consists of subfacies of chaotically bedded, clast-poor mudstone, and laminated mudstone sub facies that represent subaqueous proximal debris flows and distal glaciolacustrine rhythmites or varvites, respectively. The pebbly sandstone facies is interpreted as proglacial braided outwash deposits that both preceded glacial advance and followed glacial retreat. Both the tectonic and depositional frameworks suggest that the facies were deposited in a terrestrial setting within the Appalachian foreland basin during a single glacial advance and retreat. Regionally, areas that were not covered by ice were subject to increased rainfall as indicated by wet-climate paleosols. River systems eroded deeper channels in response to sea-level drop during glacial advance. Marine facies to the west contain iceborne dropstone boulders preserved within contemporaneous units of the Cleveland Shale Member of the Ohio Shale.The stratigraphic interval correlative with sea-level drop, climate change, and glacigenic succession represents one of the Appalachian Basin's most prolific oil-and gas-producing intervals and is contemporaneous with a global episode of sea-level drop responsible for the deposition of the Hangenberg Shale/Sandstone of Europe. This interval records the Hangenberg biotic crisis near the Devonian-Carboniferous boundary. ?? 2009 Geological Society of America.

New Plants from the Lower Devonian Pingyipu Group, Jiangyou County, Sichuan Province, China

PubMed Central

Edwards, Dianne; Geng, Bao-Yin; Li, Cheng-Sen

2016-01-01

Descriptions of Lower Devonian plants from Yunnan, South China, have revolutionized concepts of diversity and disparity in tracheophytes soon after they became established on land. Sichuan assemblages have received little attention since their discovery almost 25 years ago and require revision. With this objective, fieldwork involving detailed logging and collection of fossils was undertaken in the Longmenshan Mountain Region, Jiangyou County and yielded the two new taxa described here. They are preserved as coalified compressions and impressions that allowed morphological but not anatomical analyses. Yanmenia (Zosterophyllum) longa comb nov is based on numerous rarely branching shoots with enations resembling lycophyte microphylls, without evidence for vasculature. The presence of sporangia is equivocal making assignation to the Lycopsida conjectural. The plant was recently described as a zosterophyll, but lacks strobili. These are present in the second plant and comprise bivalved sporangia. The strobili terminate aerial stems which arise from a basal axial complex displaying diversity in branching including H- and K- forms. These features characterise the Zosterophyllopsida, although the plant differs from Zosterophyllum in valve shape. Comparisons indicate greatest similarities to the Lower Devonian Guangnania cuneata, from Yunnan, but differences, particularly in the nature of the sporangium border, require the erection of a new species, G. minor. Superficial examination of specimens already published indicate a high degree of endemism at both species and generic level, while this study shows that Yanmenia is confined to Sichuan and Guangnania is one of the very few genera shared with Yunnan, where assemblages also show a high proportion of further endemic genera. Such provincialism noted in the Chinese Lower Devonian is explained by the palaeogeographic isolation of the South China plate, but this cannot account for differences/endemism between the Sichuan and Yunnan floras. Such an enigma demands further integrated geological, palaeobotanical and palynological studies. PMID:27851760

Porphyry-Style Petropavlovskoe Gold Deposit, the Polar Urals: Geological Position, Mineralogy, and Formation Conditions

NASA Astrophysics Data System (ADS)

Vikentyev, I. V.; Mansurov, R. Kh.; Ivanova, Yu. N.; Tyukova, E. E.; Sobolev, I. D.; Abramova, V. D.; Vykhristenko, R. I.; Trofimov, A. P.; Khubanov, V. B.; Groznova, E. O.; Dvurechenskaya, S. S.; Kryazhev, S. G.

2017-11-01

Geological and structural conditions of localization, hydrothermal metasomatic alteration, and mineralization of the Petropavlovskoe gold deposit (Novogodnenskoe ore field) situated in the northern part of the Lesser Ural volcanic-plutonic belt, which is a constituent of the Middle Paleozoic island-arc system of the Polar Urals, are discussed. The porphyritic diorite bodies pertaining to the late phase of the intrusive Sob Complex play an ore-controlling role. The large-volume orebodies are related to the upper parts of these intrusions. Two types of stringer-disseminated ores have been revealed: (1) predominant gold-sulfide and (2) superimposed low-sulfide-gold-quartz ore markedly enriched in Au. Taken together, they make up complicated flattened isometric orebodies transitory to linear stockworks. The gold potential of the deposit is controlled by pyrite-(chlorite)-albite metasomatic rock of the main productive stage, which mainly develops in a volcanic-sedimentary sequence especially close to the contacts with porphyritic diorite. The relationships between intrusive and subvolcanic bodies and dating of individual zircon crystals corroborate a multistage evolution of the ore field, which predetermines its complex hydrothermal history. Magmatic activity of mature island-arc plagiogranite of the Sob Complex and monzonite of the Kongor Complex initiated development of skarn and beresite alterations accompanied by crystallization of hydrothermal sulfides. In the Early Devonian, due to emplacement of the Sob Complex at a depth of approximately 2 km, skarn magnetite ore with subordinate sulfides was formed. At the onset of the Middle Devonian, the large-volume gold porphyry Au-Ag-Te-W ± Mo,Cu stockworks related to quartz diorite porphyry—the final phase of the Sob Complex— were formed. In the Late Devonian, a part of sulfide mineralization was redistributed with the formation of linear low-sulfide quartz vein zones. Isotopic geochemical study has shown that the ore is deposited from reduced, substantially magmatic fluid, which is characterized by close to mantle values δ34S = 0 ± 1‰, δ13C =-6 to-7‰, and δ18O = +5‰ as the temperature decreases from 420-300°C (gold-sulfide ore) to 250-130°C (gold-(sulfide)-quartz ore) and pressure decreases from 0.8 to 0.3 kbar. According to the data of microanalysis (EPMA and LA-ICP-MS), the main trace elements in pyrite of gold orebodies are represented by Co (up to 2.52 wt %), As (up to 0.70 wt %), and Ni (up to 0.38 wt %); Te, Se, Ag, Au, Bi, Sb, and Sn also occur. Pyrite of the early assemblages is characterized by high Co, Te, Au, and Bi contents, whereas the late pyrite is distinguished by elevated concentrations of As (up to 0.7 wt %), Ni (up to 0.38 wt %), Se (223 ppm), Ag (up to 111 ppm), and Sn (4.4 ppm). The minimal Au content in pyrite of the late quartz-carbonate assemblage is up to 1.7 ppm and geometric average is 0.3 ppm. The significant correlation between Au and As (furthermore, negative-0.6) in pyrite from ore of the Petropavlovskoe deposit is recorded only for the gold-sulfide assemblage, whereas it is not established for other assemblages. Pyrite with higher As concentration (up to 0.7 wt %) is distinguished only for the Au-Te mineral assemblage. Taking into account structural-morphological and mineralogical-geochemical features, the ore-magmatic system of the Petropavlovskoe deposit is referred to as gold porphyry style. Among the main criteria of such typification are the spatial association of orebodies with bodies of subvolcanic porphyry-like intrusive phases at the roof of large multiphase pluton; the stockwork-like morphology of gold orebodies; 3D character of ore-alteration zoning and distribution of ore components; geochemical association of gold with Ag, W, Mo, Cu, As, Te, and Bi; and predominant finely dispersed submicroscopic gold in ore.

A new Trimerocephalus species (Trilobita, Phacopidae) from the Late Devonian (Early Famennian) of Poland.

PubMed

Kin, Adrian; Błażejowski, Błażej

2013-01-01

This study presents a detailed morphological analysis of a new species belonging to the blind trilobite Trimerocephalus McCoy, 1849, T. chopini n. sp., based on exceptionally well preserved articulated specimens from the Late Devonian (Early Famennian) of the Holy Cross Mountains in central Poland. The occurrence of this taxon in Kowala Quarry near Kielce has been reported previously, with specimens often found in single-file queues representing migratory behaviour that was followed by a mass mortality event that preserved these assemblages. The new taxon is compared with other species of Trimerocephalus and is interpreted as being most closely related to a clade consisting of T. caecus, T. lelievrei, T, inimbi, T. shotoriensis and T. tardispinosus.

Sedimentology of the Pennsylvanian and Permian Strathearn Formation, Northern Carlin Trend, Nevada; with a section on microfossil controls on the age of the Strathearn Formation

USGS Publications Warehouse

Berger, Vladimir I.; Singer, Donald A.; Theodore, Ted G.; Harris, Anita G.; Stevens, Calvin H.

2001-01-01

Two framework-supported, poorly bedded conglomerate units of the middle Upper Pennsylvanian and middle Lower Permian Strathearn Formation belonging to the overlap assemblage of the Antler orogen are prominent in the northern Carlin trend. These horizons stratigraphically and temporally bracket thrust emplacement of a major allochthonous thrust plate of mainly quartzarenite of the Ordovician Vinini Formation. Lithologic and shape-ratio data from approximately 4,200 pebbles and cobbles at 17 sites as well as biostratigraphic data in the Strathearn, and their geologic implications, are included in this report. Conodont biofacies throughout the Strathearn Formation are normal marine and suggest middle shelf or deeper depositional environments. The conglomerate units roughly are similar in that they contain only chert and quartzarenite pebbles, but they differ in compositional proportions of the two lithologies. The relative proportion of quartzarenite pebbles increases sixfold in the middle Lower Permian upper conglomerate unit versus its content in the middle Upper Pennsylvanian lower unit, whereas chert pebbles predominate in both units. Various roundness categories of chert pebbles in both conglomerate units of the Strathearn show that the equant pebble class (B/A) = 1 clearly is represented strongly even in the subangular category, the lowest roundness categories for the pebbles. Thus, development of equant pebbles cannot be ascribed totally to a rounding process during predeposition transport. The equant character of many pebbles might, in part, be an original feature inherited from pre-erosion rock fractures and (or) bedding that control overall form of the fragments prior to their release to the transport environment. The allochthon of the Coyote thrust has been thrust above the lower conglomerate unit of the Strathearn during a regionally extensive contractional event in the late Paleozoic. The middle Lower Permian upper conglomerate unit, highest unit recognized in the Strathearn Formation, as well as similarly-aged dolomitic siltstone, onlap directly onto quartzarenite that comprises the allochthon of the Coyote thrust. The conglomerate units thus represent submarine fanglomerates whose quartz grains and quartzarenite fragments of variable roundness and shape were derived from a sedimentologically restored largely southeastward advancing late Paleozoic allochthonous lobe of mostly quartzarenite of the Ordovician Vinini Formation. Chert fragments in the conglomerates probably were derived mostly from Devonian Slaven Chert, including a widespread thick melange unit of the Slaven in the footwall of the Coyote thrust. Some chert pebbles may have been derived from the Ordovician Vinini Formation.

Total Petroleum Systems of the Carpathian - Balkanian Basin Province of Romania and Bulgaria

USGS Publications Warehouse

Pawlewicz, Mark

2007-01-01

The U.S. Geological Survey defined the Moesian Platform Composite Total Petroleum System and the Dysodile Schist-Tertiary Total Petroleum System, which contain three assessment units, in the Carpathian-Balkanian Basin Province of Romania and Bulgaria. The Moesian Platform Assessment Unit, contained within the Moesian Platform Composite Total Petroleum System, is composed of Mesozoic and Cenozoic rocks within the Moesian platform region of southern Romania and northern Bulgaria and also within the Birlad depression in the northeastern platform area. In Romania, hydrocarbon sources are identified as carbonate rocks and bituminous claystones within the Middle Devonian, Middle Jurassic, Lower Cretaceous, and Neogene stratigraphic sequences. In the Birlad depression, Neogene pelitic strata have the best potential for generating hydrocarbons. In Bulgaria, Middle and Upper Jurassic shales are the most probable hydrocarbon sources. The Romania Flysch Zone Assessment Unit in the Dysodile Schist-Tertiary Total Petroleum System encompasses three structural and paleogeographic subunits within the Pre-Carpathian Mountains region: (1) the Getic depression, a segment of the Carpathian foredeep; (2) the flysch zone of the eastern Carpathian Mountains (also called the Marginal Fold nappe); and (3) the Miocene zone (also called the Sub-Carpathian nappe). Source rocks are interpreted to be Oligocene dysodile schist and black claystone, along with Miocene black claystone and marls. Also part of the Dysodile Schist-Tertiary Total Petroleum System is the Romania Ploiesti Zone Assessment Unit, which includes a zone of diapir folds. This zone lies between the Rimnicu Sarat and Dinibovita valleys and between the folds of the inner Carpathian Mountains and the external flanks of the Carpathian foredeep. The Oligocene Dysodile Schist is considered the main hydrocarbon source rock and Neogene black marls and claystones are likely secondary sources; all are thought to be at their maximum thermal maturation. Undiscovered resources in the Carpathian-Balkanian Basin Province are estimated, at the mean, to be 2,076 billion cubic feet of gas, 1,013 million barrels of oil, and 116 million barrels of natural gas liquids.

Paleozoic Assemblage of the Northern Sierra Terrane: New Geochronology And Geochemical Data From the Stitching Late Devonian - Early Carboniferous Bowman Lake Batholith, and Associated Rocks

NASA Astrophysics Data System (ADS)

Powerman, V.; Hanson, R. E.; Girty, G.; Tretiakov, A.

2016-12-01

Previous study (Grove et al., 2008) of detrital zircon ages and the timing of magmatism within the Northern Sierra terrane (NST) suggest that it is exotic relative to western Laurentia, and link it to the Paleozoic Arctic Realm, Baltica and Caledonides. NST is a composite terrane in the North America Cordillera, consisting of four distinct allochthons, thrusted upon each other. As a first step towards the understanding of the origin and tectonic development of the NST we have undertaken the SHRIMP-RG U-Pb zircon dating of the rocks from granites, granodiorites, trondhjemites, tonalites and hypabyssal intrusions, composing the Bowman Lake batholith. The batholith stitches the allochthons of the NST and its crystallization age signifies the timing of juxtaposition SHRIMP-RG analyses from 14 samples yielded an age range of ca. 352-369 Ma, which overlaps the Devonian-Mississipian boundary and constrains the minimum age for amalgamation. Additionally, we have acquired multiple XRF data, favoring the island arc provenance of the Bowman Lake batholith Batholith. Previously proposed ties between NST and Robert Mountains allochthon seem unlikely because the latter was accreted onto the western miogeocline of Laurentia during the Late Dev.-Early Miss. while the NST was most probably still situated within the Arctic Realm. This work has been supported by the grant #14.Z50.31.0017 of the Government of the Russian Federation and by the Russian Foundation for Basic Research grant #15-55-10055. We are grateful to Stanford-USGS SHRIMP-RG center, and personally to Marty Grove and Elizabeth Miller.

Phanerozoic geological evolution of Northern and Central Africa: An overview

NASA Astrophysics Data System (ADS)

Guiraud, R.; Bosworth, W.; Thierry, J.; Delplanque, A.

2005-10-01

The principal paleogeographic characteristics of North and Central Africa during the Paleozoic were the permanency of large exposed lands over central Africa, surrounded by northerly and northwesterly dipping pediplanes episodically flooded by epicontinental seas related to the Paleotethys Ocean. The intra-continental Congo-Zaire Basin was also a long-lived feature, as well as the Somali Basin from Late Carboniferous times, in conjunction with the development of the Karoo basins of southern Africa. This configuration, in combination with eustatic sea-level fluctuations, had a strong influence on facies distributions. Significant transgressions occurred during the Early Cambrian, Tremadocian, Llandovery, Middle to Late Devonian, Early Carboniferous, and Moscovian. The Paleozoic tectonic history shows an alternation of long periods of predominantly gentle basin subsidence and short periods of gentle folding and occasionally basin inversion. Some local rift basins developed episodically, located mainly along the northern African-Arabian plate margin and near the West African Craton/Pan-African Belt suture. Several arches or spurs, mainly N-S to NE-SW trending and inherited from late Pan-African fault swarms, played an important role. The Nubia Province was the site of numerous alkaline anorogenic intrusions, starting in Ordovician times, and subsequently formed a large swell. Paleozoic compressional events occurred in the latest Early Cambrian ("Iskelian"), Medial Ordovician to earliest Silurian ("pre-Caradoc" and "Taconian"), the end Silurian ("Early Acadian" or "Ardennian"), mid-Devonian ("Mid-Acadian"), the end Devonian ("Late Acadian" or "Bretonnian"), the earliest Serpukhovian ("Sudetic"), and the latest Carboniferous-earliest Permian ("Alleghanian" or "Asturian"). The strongest deformations, including folding, thrusting, and active strike-slip faulting, were registered in Northwestern Africa during the last stage of the Pan-African Belt development around the West African Craton (end Early Cambrian) and during the polyphased Hercynian-Variscan Orogeny that extended the final closure of the Paleotethys Ocean and resulted in the formation of the Maghrebian and Mauritanides belts. Only gentle deformation affected central and northeastern African during the Paleozoic, the latter remaining a passive margin of the Paleotethys Ocean up to the Early Permian when the development of the Neotethys initiated along the Eastern Mediterranean Basins. The Mesozoic-Cenozoic sedimentary sequence similarly consists of a succession of eustatically and tectonically controlled depositional cycles. Through time, progressive southwards shift of the basin margins occurred, related to the opening of the Neotethys Ocean and to the transgressions resulting from warming of the global climate and associated rise of the global sea level. The Guinean-Nigerian Shield, the Hoggar, Tibesti-Central Cyrenaica, Nubia, western Saudi Arabia, Central African Republic, and other long-lived arches delimited the principal basins. The main tectonic events were the polyphased extension, inversion, and folding of the northern African-Arabian shelf margin resulting in the development of the Alpine Maghrebian and Syrian Arc belts, rifting and drifting along the Central Atlantic, Somali Basins, and Gulf of Aden-Red Sea domains, inversion of the Murzuq-Djado Basin, and rifting and partial inversion along the Central African Rift System. Two major compressional events occurred in the Late Santonian and early Late Eocene. The former entailed folding and strike-slip faulting along the northeastern African-northern Arabian margin (Syrian Arc) and the Central African Fold Belt System (from Benue to Ogaden), and thrusting in Oman. The latter ("Pyrenean-Atlasic") resulted in folding, thrusting, and local metamorphism of the northern African-Arabian plate margin, and rejuvenation of intra-plate fault zones. Minor or more localized compressional deformations took place in the end Cretaceous, the Burdigalian, the Tortonian and Early Quaternary. Recent tectonic activity is mainly concentrated along the Maghrebian Alpine Belt, the offshore Nile Delta, the Red Sea-East African Rifts Province, the Aqaba-Dead Sea-Bekaa sinistral strike-slip fault zone, and some major intra-plate fault zones including the Guinean-Nubian, Aswa, and central Sinai lineaments. Large, long-lived magmatic provinces developed in the Egypt-Sudan confines (Nubia), in the Hoggar-Air massifs, along the Cameroon Line and Nigerian Jos Plateau, and along the Levant margin, resulting in uplifts that influenced the paleogeography. Extensive tholeiitic basaltic magmatism at ˜200 Ma preceded continental break-up in the Central Atlantic domain, while extensive alkaline to transitional basaltic magmatism accompanied the Oligocene to Recent rifting along the Red Sea-Gulf of Aden-East African rift province.

The emergence of lobsters: phylogenetic relationships, morphological evolution and divergence time comparisons of an ancient group (decapoda: achelata, astacidea, glypheidea, polychelida).

PubMed

Bracken-Grissom, Heather D; Ahyong, Shane T; Wilkinson, Richard D; Feldmann, Rodney M; Schweitzer, Carrie E; Breinholt, Jesse W; Bendall, Matthew; Palero, Ferran; Chan, Tin-Yam; Felder, Darryl L; Robles, Rafael; Chu, Ka-Hou; Tsang, Ling-Ming; Kim, Dohyup; Martin, Joel W; Crandall, Keith A

2014-07-01

Lobsters are a ubiquitous and economically important group of decapod crustaceans that include the infraorders Polychelida, Glypheidea, Astacidea and Achelata. They include familiar forms such as the spiny, slipper, clawed lobsters and crayfish and unfamiliar forms such as the deep-sea and "living fossil" species. The high degree of morphological diversity among these infraorders has led to a dynamic classification and conflicting hypotheses of evolutionary relationships. In this study, we estimated phylogenetic relationships among the major groups of all lobster families and 94% of the genera using six genes (mitochondrial and nuclear) and 195 morphological characters across 173 species of lobsters for the most comprehensive sampling to date. Lobsters were recovered as a non-monophyletic assemblage in the combined (molecular + morphology) analysis. All families were monophyletic, with the exception of Cambaridae, and 7 of 79 genera were recovered as poly- or paraphyletic. A rich fossil history coupled with dense taxon coverage allowed us to estimate and compare divergence times and origins of major lineages using two drastically different approaches. Age priors were constructed and/or included based on fossil age information or fossil discovery, age, and extant species count data. Results from the two approaches were largely congruent across deep to shallow taxonomic divergences across major lineages. The origin of the first lobster-like decapod (Polychelida) was estimated in the Devonian (∼409-372 Ma) with all infraorders present in the Carboniferous (∼353-318 Ma). Fossil calibration subsampling studies examined the influence of sampling density (number of fossils) and placement (deep, middle, and shallow) on divergence time estimates. Results from our study suggest including at least 1 fossil per 10 operational taxonomic units (OTUs) in divergence dating analyses. [Dating; decapods; divergence; lobsters; molecular; morphology; phylogenetics.]. © The Author(s) 2014. Published by Oxford University Press, on behalf of the Society of Systematic Biologists. All rights reserved.For Permissions, please email: journals.permissions@oup.com.

Breathing air in air: in what ways might extant amphibious fish biology relate to prevailing concepts about early tetrapods, the evolution of vertebrate air breathing, and the vertebrate land transition?

PubMed

Graham, Jeffrey B; Lee, Heather J

2004-01-01

The air-breathing fishes have heuristic importance as possible models for the Paleozoic evolution of vertebrate air breathing and the transition to land. A recent hypothesis about this transition suggests that the diverse assemblage of marine amphibious fishes occurring primarily in tropical, high intertidal zone habitats are analogs of early tetrapods and that the intertidal zone, not tropical freshwater lowlands, was the springboard habitat for the Devonian land transition by vertebrates. Here we argue that selection pressures imposed by life in the intertidal zone are insufficient to have resulted in the requisite aerial respiratory capacity or the degree of separation from water required for the vertebrate land transition. The extant marine amphibious fishes, which occur mainly on rocky shores or mudflats, have reached the limit of their niche expansion onto land and remain tied to water by respiratory structures that are less efficient in air and more vulnerable to desiccation than lungs. We further argue that evolutionary contingencies actuated by the Devonian origin of the tetrapods marked a critical point of divergence for a way of life in which selection pressures would operate on the physiology, morphology, and natural history of the different vertebrate groups. While chronically hypoxic and shallow water conditions in the habitats of some primitive bony fishes and some amphibians appear similar to the conditions that prevailed in the Devonian, markedly different selection pressures have operated on other amphibians and bony fishes over the 300 million years since the vertebrate land transition. For example, both egg development and larval metamorphosis in extant amphibians are geared mainly toward compensating for the uncertainty of habitat water quality or even the absence of water by minimizing the time required to develop there. In contrast, reproduction by most intertidal (and amphibious) fishes, all of which are teleosts, remains dependent on a planktonic larval phase and is characterized by specializations (brooding) that minimize overdispersal and maximize recruitment back to the littoral habitat.

An organismal concept for Sengelia radicans gen. et sp. nov. – morphology and natural history of an Early Devonian lycophyte

PubMed Central

Tomescu, Alexandru M. F.

2017-01-01

Abstract Background and Aims Fossil plants are found as fragmentary remains and understanding them as natural species requires assembly of whole-organism concepts that integrate different plant parts. Such concepts are essential for incorporating fossils in hypotheses of plant evolution and phylogeny. Plants of the Early Devonian are crucial to reconstructing the initial radiation of tracheophytes, yet few are understood as whole organisms. Methods This study assembles a whole-plant concept for the Early Devonian lycophyte Sengelia radicans gen. et sp. nov., based on morphometric data and taphonomic observations from >1000 specimens collected in the Beartooth Butte Formation (Wyoming, USA). Key Results Sengelia radicans occupies a key position between stem-group and derived lycophyte lineages. Sengelia had a rooting system of downward-growing root-bearing stems, formed dense monotypic mats of prostrate shoots in areas that experienced periodic flooding, and was characterized by a life-history strategy adapted for survival after floods, dominated by clonality, and featuring infrequent sexual reproduction. Conclusions Sengelia radicans is the oldest among the very few early tracheophytes for which a detailed, rigorous whole-plant concept integrates morphology, growth habit, life history and growth environment. This plant adds to the diversity of body plans documented among lycophytes and may help elucidate patterns of morphological evolution in the clade. PMID:28334100

Syngenetic Au on the Carlin trend: Implications for Carlin-type deposits

USGS Publications Warehouse

Emsbo, P.; Hutchinson, R.W.; Hofstra, A.H.; Volk, J.A.; Bettles, K.H.; Baschuk, G.J.; Johnson, C.A.

1999-01-01

A new type of gold occurrence recently discovered in the Carlin trend, north-central Nevada, is clearly distinct from classic Carlin-type gold ore. These occurrences are interpreted to be of sedimentary exhalative (sedex) origin because they are stratiform and predate compaction and lithification of their unaltered Devonian host rocks. They contain barite that exhibits ??34S and ??18O values identical to sulfate in Late Devonian seawater and sedex-type barite deposits. Abrupt facies changes in the host rocks strongly suggest synsedimentary faulting and foundering of the carbonate shelf during mineralization, as is characteristic of sedex deposits. Gold occurs both as native inclusions in synsedimentary base-metal sulfides and barite, and as chemical enrichments in sulfide minerals. The absence of alteration and lack of ??13C and ??18O isotopic shift of primary carbonates in these rocks is strong evidence that this gold was not introduced with classic Carlin-type mineralization. Collectively, these features show that the Devonian strata were significantly enriched in gold some 300 m.y. prior to generation of the mid-Tertiary Carlin-type deposits. These strata may have been an important, perhaps even vital, source of gold for the latter. Although gold is typically low in most Zn-Pb-rich sedex deposits, our evidence suggests that transport of gold in basinal fluids, and its subsequent deposition in the sedex environment, can be significant.

Stratigraphy and facies development of the marine Late Devonian near the Boulongour Reservoir, northwest Xinjiang, China

NASA Astrophysics Data System (ADS)

Suttner, Thomas J.; Kido, Erika; Chen, Xiuqin; Mawson, Ruth; Waters, Johnny A.; Frýda, Jiří; Mathieson, David; Molloy, Peter D.; Pickett, John; Webster, Gary D.; Frýdová, Barbora

2014-02-01

Late Devonian to Early Carboniferous stratigraphic units within the 'Zhulumute' Formation, Hongguleleng Formation (stratotype), 'Hebukehe' Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and 'Hebukehe' formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding 'Hebukehe' Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. 'Blastoid Hill') and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.

The geology and petroleum potential of the North Afghan platform and adjacent areas (northern Afghanistan, with parts of southern Turkmenistan, Uzbekistan and Tajikistan)

NASA Astrophysics Data System (ADS)

Brookfield, Michael E.; Hashmat, Ajruddin

2001-10-01

The North Afghan platform has a pre-Jurassic basement unconformably overlain by a Jurassic to Paleogene oil- and gas-bearing sedimentary rock platform cover, unconformably overlain by Neogene syn- and post-orogenic continental clastics. The pre-Jurassic basement has four units: (1) An ?Ordovician to Lower Devonian passive margin succession developed on oceanic crust. (2) An Upper Devonian to Lower Carboniferous (Tournaisian) magmatic arc succession developed on the passive margin. (3) A Lower Carboniferous (?Visean) to Permian rift-passive margin succession. (4) A Triassic continental magmatic arc succession. The Mesozoic-Palaeogene cover has three units: (1) A ?Late Triassic to Middle Jurassic rift succession is dominated by variable continental clastics. Thick, coarse, lenticular coal-bearing clastics were deposited by braided and meandering streams in linear grabens, while bauxites formed on the adjacent horsts. (2) A Middle to Upper Jurassic transgressive-regressive succession consists of mixed continental and marine Bathonian to Lower Kimmeridgian clastics and carbonates overlain by regressive Upper Kimmeridgian-Tithonian evaporite-bearing clastics. (3) A Cretaceous succession consists of Lower Cretaceous red beds with evaporites, resting unconformably on Jurassic and older deposits, overlain (usually unconformably) by Cenomanian to Maastrichtian shallow marine limestones, which form a fairly uniform transgressive succession across most of Afghanistan. (4) A Palaeogene succession rests on the Upper Cretaceous limestones, with a minor break marked by bauxite in places. Thin Palaeocene to Upper Eocene limestones with gypsum are overlain by thin conglomerates, which pass up into shales with a restricted brackish-water ?Upper Oligocene-?Lower Miocene marine fauna. The Neogene succession consists of a variable thickness of coarse continental sediments derived from the rising Pamir mountains and adjacent ranges. Almost all the deformation of the North Afghan platform began in the Miocene. Oil and gas traps are mainly in Upper Jurassic carbonates and Lower Cretaceous sandstones across the entire North Afghan block. Upper Jurassic carbonate traps, sealed by evaporites, occur mainly north of the southern limit of the Upper Jurassic salt. Lower Cretaceous traps consist of fine-grained continental sandstones, sealed by Aptian-Albian shales and siltstones. Upper Cretaceous-Palaeocene carbonates, sealed by Palaeogene shales are the main traps along the northern edge of the platform and in the Tajik basin. Almost all the traps are broad anticlines related to Neogene wrench faulting, in this respect, like similar traps along the San Andreas fault. Hydrocarbon sources are in the Mesozoic section. The Lower-Middle Jurassic continental coal-bearing beds provide about 75% of the hydrocarbons; the Callovian-Oxfordian provides about 10%; the Neocomian a meagre 1%, and the Aptian-Albian about 14%. The coal-bearing source rocks decrease very markedly in thickness southwards cross the North Afghan platform. Much of the hydrocarbon generation probably occurred during the Late Cretaceous-Paleogene and migrated to structural traps during Neogene deformation. Since no regional structural dip aids southward hydrocarbon migration, and since the traps are all structural and somewhat small, then there is little chance of very large petroleum fields on the platform. Nevertheless, further studies of the North Afghan platform should be rewarding because: (a) the traps of strike-slip belts are difficult to find without detailed exploration; (b) the troubles of the last 20 years mean that almost no exploration has been done; and, (c) conditions may soon become more favorable. There should be ample potential for oil, and particularly gas, discoveries especially in the northern and western parts of the North Afghan platform.

The Late Devonian Gogo Formation Lägerstatte of Western Australia: Exceptional Early Vertebrate Preservation and Diversity

NASA Astrophysics Data System (ADS)

Long, John A.; Trinajstic, Kate

2010-05-01

The Gogo Formation of Western Australia preserves a unique Late Devonian (Frasnian) reef fauna. The exceptional three-dimensional preservation of macrofossils combined with unprecedented soft-tissue preservation (including muscle bundles, nerve cells, and umbilical structures) has yielded a particularly rich assemblage with almost 50 species of fishes described. The most significant discoveries have contributed to resolving placoderm phylogeny and elucidating their reproductive physiology. Specifically, these discoveries have produced data on the oldest known vertebrate embryos; the anatomy of the primitive actinopterygian neurocranium and phylogeny of the earliest actinopterygians; the histology, radiation, and plasticity of dipnoan (lungfish) dental and cranial structures; the anatomy and functional morphology of the extinct onychodonts; and the anatomy of the primitive tetrapodomorph head and pectoral fin.

Integration of new geologic mapping and satellite-derived quartz mapping yields insights into the structure of the Roberts Mountains allochthon applicable to assessments for concealed Carlin-type gold deposits

USGS Publications Warehouse

Holm-Denoma, Christopher S.; Hofstra, Albert H.; Rockwell, Barnaby W.; Noble, Paula J.

2012-01-01

Geologic mapping and remote sensing across north-central Nevada enable recognition of a thick sheet of Middle and Upper Ordovician Valmy Formation quartzite that structurally overlies folded and faulted Ordovician through Devonian stratigraphic units of the Roberts Mountains allochthon. In the northern Independence Mountains and nearby Double Mountain area, the Valmy Formation is in fault contact with Ordovician through Silurian, predominantly clastic, sedimentary rocks of the Roberts Mountains allochthon that were deformed prior to, or during, emplacement of the Valmy thrust sheet. Similar structural relations are recognized discontinuously for 200 kilometers along the strike of the Roberts Mountains allochthon in mapping guided by regional remote-sensing-based (ASTER) quartz maps. Overall thicknesses of deformed Roberts Mountains allochthon units between the base of the Valmy and the top of underlying carbonate rocks that host large Carlin-type gold deposits varies on the order of hundreds of meters but is not known to exceed 700 meters. The base of the Valmy thrust sheet is a complimentary datum in natural resource exploration and mineral resource assessment for concealed Carlin-type gold deposits.

Geochemical and multi-isotopic ( 87Sr/ 86Sr, 143Nd/ 144Nd, 238U/ 235U) perspectives of sediment sources, depositional conditions, and diagenesis of the Marcellus Shale, Appalachian Basin, USA

DOE PAGES

Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.; ...

2017-10-25

Here, we investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from –7.8 to –6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from amore » well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns.« less

Group I introns are inherited through common ancestry in the nuclear-encoded rRNA of Zygnematales (Charophyceae).

PubMed Central

Bhattacharya, D; Surek, B; Rüsing, M; Damberger, S; Melkonian, M

1994-01-01

Group I introns are found in organellar genomes, in the genomes of eubacteria and phages, and in nuclear-encoded rRNAs. The origin and distribution of nuclear-encoded rRNA group I introns are not understood. To elucidate their evolutionary relationships, we analyzed diverse nuclear-encoded small-subunit rRNA group I introns including nine sequences from the green-algal order Zygnematales (Charophyceae). Phylogenetic analyses of group I introns and rRNA coding regions suggest that lateral transfers have occurred in the evolutionary history of group I introns and that, after transfer, some of these elements may form stable components of the host-cell nuclear genomes. The Zygnematales introns, which share a common insertion site (position 1506 relative to the Escherichia coli small-subunit rRNA), form one subfamily of group I introns that has, after its origin, been inherited through common ancestry. Since the first Zygnematales appear in the middle Devonian within the fossil record, the "1506" group I intron presumably has been a stable component of the Zygnematales small-subunit rRNA coding region for 350-400 million years. PMID:7937917

Bedrock geologic and joint trend map of the Pinardville quadrangle, Hillsborough County, New Hampshire

USGS Publications Warehouse

Burton, William C.; Armstrong, Thomas R.

2013-01-01

The bedrock geology of the Pinardville quadrangle includes the Massabesic Gneiss Complex, exposed in the core of a regional northeast-trending anticlinorium, and highly deformed metasedimentary rocks of the Rangeley Formation, exposed along the northwest limb of the anticlinorium. Both formations were subjected to high-grade metamorphism and partial melting: the Rangeley during the middle Paleozoic Acadian orogeny, and the Massabesic Gneiss Complex during both the Acadian and the late Paleozoic Alleghanian orogeny. Granitoids produced during these orogenies range in age from Devonian (Spaulding Tonalite) to Permian (granite at Damon Pond), each with associated pegmatite. In the latest Paleozoic the Massabesic Gneiss Complex was uplifted with respect to the Rangeley Formation along the ductile Powder Hill fault, which also had a left-lateral component. Uplift continued into the early Mesozoic, producing the 2-kilometer-wide Campbell Hill fault zone, which is marked by northwest-dipping normal faults and dilational map-scale quartz bodies. Rare, undeformed Jurassic diabase dikes cut all older lithologies and structures. A second map is a compilation of joint orientations measured at all outcrops in the quadrangle. There is a great diversity of strike trends, with northeast perhaps being the most predominant.

Results of coal bed methane drilling, Mylan Park, Monongalia County, West Virginia

USGS Publications Warehouse

Ruppert, Leslie F.; Fedorko, Nick; Warwick, Peter D.; Grady, William C.; Crangle, Robert D.; Britton, James Q.

2004-01-01

The Department of Energy National Energy Technology Laboratory funded drilling of a borehole (39.64378 deg E , -80.04376 deg N) to evaluate the potential for coal bed methane and carbon dioxide sequestration at Mylan Park, Monongalia County, West Virginia. The drilling commenced on September 23, 2002 and was completed on November 14, 2002. The 2,525 ft deep hole contained 1,483.41 ft of Pennsylvanian coal-bearing strata, 739.67 feet of Mississippian strata, and 301.93 ft. of Devonian strata. The drill site was located directly over abandoned Pittsburgh and Sewickley coal mines. Coal cores from remaining mine pillars were cut and retrieved for desorption from both mines. In addition, coals were cored and desorbed from the Pittsburgh Roof, Little Pittsburgh, Elk Lick, Brush Creek, Upper Kittanning, Middle Kittanning, Clarion, Upper Mercer, Lower Mercer, and Quakertown coal beds. All coals are Pennsylvanian in age and are high-volatile-A bituminous in rank. A total of 34.75 ft of coal was desorbed over a maximum period of 662 days, although most of the coal was desorbed for about 275 days. This report is provided in Adobe Acrobat format. Appendix 3 is provided in Excel format.

Geochemical and multi-isotopic ( 87Sr/ 86Sr, 143Nd/ 144Nd, 238U/ 235U) perspectives of sediment sources, depositional conditions, and diagenesis of the Marcellus Shale, Appalachian Basin, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.

Here, we investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from –7.8 to –6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from amore » well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns.« less

Reassessing the improbability of a muscular crinoid stem

PubMed Central

Gorzelak, Przemysław; Głuchowski, Edward; Salamon, Mariusz A.

2014-01-01

Muscular articulations in modern stalked crinoids are only present in the arms. Although it has been suggested that certain coiled-stemmed fossil taxa may have been functionally adapted to utilize muscles, evidence supporting this interpretation is lacking. Here, we use cathodoluminescence and SEM to reveal the skeletal microstructure of the enigmatic coiled-stemmed taxon Ammonicrinus (Flexibilia). Based on the well-established link between skeletal microstructure and the nature of infilling soft tissues in modern echinoderms, we reconstructed the palaeoanatomy of the Middle Devonian ammonicrinids. We show that their median columnals with elongated lateral columnal enclosure extensions (LCEE) have stereom microstructure unexpectedly resembling that in the crinoid muscular arm plates. In particular, large ligamentary facets, that are present on each side of a transverse ridge, are mainly comprised of fine galleried stereom that is indicative of the mutable collagenous tissues. In contrast, fine labyrinthic stereom, commonly associated with muscles, is situated in the periphery on each side of the surface of elongated LCEE. Our findings thus strongly suggest that the muscles may have also been present in the stem of ammonicrinids. These results reassess the previous hypotheses about evolution of muscles in crinoids and provide new insights into the mode of life of Ammonicrinus. PMID:25116414

Reassessing the improbability of a muscular crinoid stem

NASA Astrophysics Data System (ADS)

Gorzelak, Przemysław; Głuchowski, Edward; Salamon, Mariusz A.

2014-08-01

Muscular articulations in modern stalked crinoids are only present in the arms. Although it has been suggested that certain coiled-stemmed fossil taxa may have been functionally adapted to utilize muscles, evidence supporting this interpretation is lacking. Here, we use cathodoluminescence and SEM to reveal the skeletal microstructure of the enigmatic coiled-stemmed taxon Ammonicrinus (Flexibilia). Based on the well-established link between skeletal microstructure and the nature of infilling soft tissues in modern echinoderms, we reconstructed the palaeoanatomy of the Middle Devonian ammonicrinids. We show that their median columnals with elongated lateral columnal enclosure extensions (LCEE) have stereom microstructure unexpectedly resembling that in the crinoid muscular arm plates. In particular, large ligamentary facets, that are present on each side of a transverse ridge, are mainly comprised of fine galleried stereom that is indicative of the mutable collagenous tissues. In contrast, fine labyrinthic stereom, commonly associated with muscles, is situated in the periphery on each side of the surface of elongated LCEE. Our findings thus strongly suggest that the muscles may have also been present in the stem of ammonicrinids. These results reassess the previous hypotheses about evolution of muscles in crinoids and provide new insights into the mode of life of Ammonicrinus.

Oceanic Impact: Mechanisms and Environmental Perturbations

NASA Technical Reports Server (NTRS)

Gersonde, Rainer (Editor); Deutsch, Alex (Editor); Ivanov, Boris A. (Editor); Kyte, Frank T. (Editor)

2002-01-01

The contents include the following: Oceanic impacts-a growing field of fundamental geoscience. Shock metamorphism on the ocean floor (numerical simulations). Numerical modeling of impact-induced modifications of the deep-sea floor. Computer modelling of the water resurge at a marine impact: the Lockne crater, Sweden. Experimental investigation of the role of water in impact vaporization chemistry. Calcareous plankton stratigraphy around the Pliocene Eltanin asteroid impact area (SE Pacific): documentation and application for geological and paleoceanographic reconstruction. Composition of impact melt debris from the Eltanin impact strewn field, Bellingshausen Sea. Iridium concentrations and abundances of meteoritic ejecta from the Eltanin impact in sediment cores from Polarstern expedition ANT XII/4. Unmelted meteoritic debris collected from Eltanin ejecta in Polarstern cores from expedition ANT XII/4. Impact tsunami-Eltanin. Ancient impact structures on modern continental shelves: The Chesapeake Bay, Montagnais, and Toms Canyon craters, Atlantic margin of North America. The Mjolnir marine impact crater porosity anomaly. Kardla (Hiiu-maa Island, Estonia) - the buried and well-preserved Ordovician marine impact structure. Long-term effect of the Kardla crater (Hiiu-maa, Estonia) on Late Ordovician carbonate sedimentation. The middle Devonian Kaluga impact crater (Russia): new interpretation of marine setting.

Potentiometric surface of the Ozark aquifer in northern Arkansas, 2004

USGS Publications Warehouse

Schrader, T.P.

2005-01-01

The Ozark aquifer in northern Arkansas comprises dolomites, limestones, sandstones, and shales of Late Cambrian to Middle Devonian age, and ranges in thickness from approximately 1,100 feet to more than 4,000 feet. Hydrologically, the aquifer is complex, characterized by discrete and discontinuous flow components with large variations in permeability. The potentiometric-surface map, based on 59 well and 5 spring water-level measurements collected in 2004 in Arkansas and Missouri, indicates maximum water-level altitudes of about 1,188 feet in Benton County and minimum water-level altitudes of about 116 feet in Randolph County. Regionally, the flow within the aquifer is to the south and southeast in the eastern and central part of the study area and to the northwest and north in the western part of the study area. Comparing the 2004 potentiometric- surface map with a predevelopment potentiometricsurface map indicates general agreement between the two surfaces. Potentiometric-surface differences could be attributed to differences in pumping related to changing population from 1990 to 2000, change in source for public supplies, processes or water use outside the study area, or differences in data-collection or map-construction methods.

Precise U/Pb zircons dates of bentonites in Upper Ordovician and Lower Silurian reference sections in North America and Britain.

NASA Astrophysics Data System (ADS)

Suarez, S. E.; Brookfield, M. E.; Catlos, E. J.; Stockli, D. F.; Batchelor, R. A.

2016-12-01

The end of the Ordovician marks one of the greatest of the Earth's mass extinctions. One hypothesis explains this mass extinction as the result of a short-lived, major glaciation preceded by episodes of increased volcanism brought on by the Taconic orogeny. K-bentonites, weathered volcanic ash, provide evidence for increased volcanism. However, there is a lack of modern precise U-Pb dating of these ashes and some confusion in the biostratigraphy. The aim of this study is to obtain more precise U-Pb zircon ages from biostratigraphically constrained bentonites which will lead to better correlation of the Upper Ordovician and Lower Silurian relative time scales, as well as time the pulses of eruption. Zircon grains were extracted from the samples by heavy mineral separation and U-Pb dated using the Laser Ablation-Inductively Coupled Plasma-Mass Spectrometer at the University of Texas-Austin. We report here 3 precise U-Pb zircon ages from the Trenton Group, Ontario, Canada, and Dob's Linn, Scotland. The youngest age from the top of the Kirkfield Formation in Ontario is 448.0 +/- 18 Ma, which fits with existing late Ordovician stratigraphic ages. At Dob's Linn, Scotland, the site of the Ordovician/Silurian Global Boundary Stratigraphic Section and Point (GSSP), the youngest age for DL7, a bentonite 5 meters below the GSSP is 402.0 +/- 12.0 Ma, and for DL24L, a bentonite 8 meters above the GSSP is 358.2 +/- 7.9 Ma. These are Devonian ages in current timescales - the current age for the GSSP is 443.8 +/- 1.8 Ma, based on an U/Pb dates from a bentonite 1.6 meters above the GSSP at Dob's Linn. We are confident that our techniques rule out contamination and the most likely explanation is that the small zircons we analyzed either suffered Pb loss, or grew overgrowths during low grade hydrothermal metamorphism of the sediments during the intrusion of the Southern Upland Devonian granites during the Caledonian orogeny. These Devonian ages suggest that the 443.8 +/- 1.8 Ma age may also be suspect. The Dob's Linn site is therefore unsuitable for calibrating the biostratigraphic horizons. Work in progress will provide more U-Pb dating of bentonites from around the Ordovician-Silurian boundary in Canada, United States, Britain and Scandinavia with the aim of calibrating the local series and stages in order to help in International correlations.

Formation and inversion of transtensional basins in the western part of the Lachlan Fold Belt, Australia, with emphasis on the Cobar Basin

NASA Astrophysics Data System (ADS)

Glen, R. A.

The Palaeozoic history of the western part of the Lachlan Fold Belt in New South Wales was dominated by strike-slip tectonics. In the latest Silurian to late Early Devonian, an area of crust >25,000 km 2 lying west of the Gilmore Suture underwent regional sinistral transtension, leading to the development of intracratonic successor basins, troughs and flanking shelves. The volcaniclastic deep-water Mount Hope Trough and Rast Trough, the siliciclastic Cobar Basin and the volcanic-rich Canbelego-Mineral Hill Belt of the Kopyje Shelf all were initiated around the Siluro-Devonian boundary. They all show clear evidence of having evolved by both active syn-rift processes and passive later post-rift (sag-phase) processes. Active syn-rift faulting is best documented for the Cobar Basin and Mount Hope Trough. In the former case, the synchronous activity on several fault sets suggests that the basin formed by sinistral transtension in response to a direction of maximum extension oriented NE-SW. Structures formed during inversion of the Cobar Basin and Canbelego-Mineral Hill Belt indicate closure under a dextral transpressive strain regime, with a far-field direction of maximum shortening oriented NE-SW. In the Cobar Basin, shortening was partitioned into two structural zones. A high-strain zone in the east was developed into a positive half-flower structure by re-activation of early faults and by formation of short-cut thrusts, some with strike-slip movement, above an inferred steep strike-slip fault. Intense subvertical cleavage, a steep extension lineation and variably plunging folds are also present. A lower-strain zone to the west developed by syn-depositional faults being activated as thrusts soling into a gently dipping detachment. A subvertical cleavage and steep extension lineation are locally present, and variably plunging folds are common. Whereas Siluro-Devonian basin-opening appeared to be synchronous in the western part of the fold belt, the different period of basin inversion in the Cobar region (late Early Devonian and Carboniferous) may reflect different movement histories on the master strike-slip faults in this part of the fold belt, the Gilmore Suture and Kiewa Fault.

Variability over time in the sources of South Portuguese Zone turbidites: evidence of denudation of different crustal blocks during the assembly of Pangaea

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Ribeiro, C.; Vilallonga, F.; Chichorro, M.; Drost, K.; Silva, J. B.; Albardeiro, L.; Hofmann, M.; Linnemann, U.

2014-07-01

This study combines geochemical and geochronological data in order to decipher the provenance of Carboniferous turbidites from the South Portuguese Zone (SW Iberia). Major and trace elements of 25 samples of graywackes and mudstones from the Mértola (Visean), Mira (Serpukhovian), and Brejeira (Moscovian) Formations were analyzed, and 363 U-Pb ages were obtained on detrital zircons from five samples of graywackes from the Mira and Brejeira Formations using LA-ICPMS. The results indicate that turbiditic sedimentation during the Carboniferous was marked by variability in the sources, involving the denudation of different crustal blocks and a break in synorogenic volcanism. The Visean is characterized by the accumulation of immature turbidites (Mértola Formation and the base of the Mira Formation) inherited from a terrane with intermediate to mafic source rocks. These source rocks were probably formed in relation to Devonian magmatic arcs poorly influenced by sedimentary recycling, as indicated by the almost total absence of pre-Devonian zircons typical of the Gondwana and/or Laurussia basements. The presence of Carboniferous grains in Visean turbidites indicates that volcanism was active at this time. Later, Serpukhovian to Moscovian turbiditic sedimentation (Mira and Brejeira Formations) included sedimentary detritus derived from felsic mature source rocks situated far from active magmatism. The abundance of Precambrian and Paleozoic zircons reveals strong recycling of the Gondwana and/or Laurussia basements. A peri-Gondwanan provenance is indicated by zircon populations with Neoproterozoic (Cadomian-Avalonian and Pan-African zircon-forming events), Paleoproterozoic, and Archean ages. The presence of late Ordovician and Silurian detrital zircons in Brejeira turbidites, which have no correspondence in the Gondwana basement of SW Iberia, indicates Laurussia as their most probable source.

Unravelling Orbital Climatic Cycles from Devonian Magnetic Susceptibility Signal - The Quest for a Better Age Model for the Lochkovian and Pragian Stages (Czech Republic)

NASA Astrophysics Data System (ADS)

da Silva, A. C.; Chadimova, L.; Hladil, J.; Slavik, L.; Hilgen, F. J.; Dekkers, M. J.

2015-12-01

The uncertainties on the Devonian stage boundaries are currently in the order of several millions of years. When shown to reflect a detrital signal, which is influenced by climatic variations, Magnetic Susceptibility (MS) has been proven as a useful tool for identifying climatic cycles; which can subsequently be used to improve the time scale. Here, we focus on two sections from the Prague Synform (Czech Republic) cutting through the Lochkovian, Pragian and the lower part of the Emsian. Sedimentation is rhythmic, dominated by slightly clayey offshore limestones, being mostly calciturbidites and hemipelagites. We provide hysteresis analysis in order to get insight into the nature and the origin of the magnetic minerals driving the variation in the MS signal. The results point to a MS signal mostly carried by clay minerals. Subsequently, to improve estimation of the duration of the stages, we apply different spectral analysis techniques on this MS signal. From the Continuous Wavelet Transform (CWT), Evolutive Harmonic Analysis (EHA) and field observations, we subdivide the section into portions with a steady sedimentation rate (a first estimate of this rate is also delivered by these analyzes). Then, we apply Multitaper Method (MTM) and Multitaper harmonic Analysis (F-test) and extract the frequencies reaching 95% Confidence Level. These frequencies are then implemented into the Average Spectral Misfit procedures (ASM) which enables comparison with orbital targets. By combining these different techniques, 405 kyr cyclicty is identifed, a powerful duration paleochronometer. These new results indicate a duration of 7.7 ± 2 Myr for the Lochkovian stage and of 1.7 Myr ± 1.4 for the Pragian stage (compared to respectively 8.4 ± 6 Myr and 3.2 ± 5.4 Myr in the 2012 Geological Time Scale).

Trace-element budgets in the Ohio/Sunbury shales of Kentucky: Constraints on ocean circulation and primary productivity in the Devonian-Mississippian Appalachian Basin

USGS Publications Warehouse

Perkins, R.B.; Piper, D.Z.; Mason, C.E.

2008-01-01

The hydrography of the Appalachian Basin in late Devonian-early Mississippian time is modeled based on the geochemistry of black shales and constrained by others' paleogeographic reconstructions. The model supports a robust exchange of basin bottom water with the open ocean, with residence times of less than forty years during deposition of the Cleveland Shale Member of the Ohio Shale. This is counter to previous interpretations of these carbon-rich units having accumulated under a stratified and stagnant water column, i.e., with a strongly restricted bottom bottom-water circulation. A robust circulation of bottom waters is further consistent with the palaeoclimatology, whereby eastern trade-winds drove upwelling and arid conditions limited terrestrial inputs of siliciclastic sediment, fresh waters, and riverine nutrients. The model suggests that primary productivity was high (~ 2??g C m- 2 d- 1), although no higher than in select locations in the ocean today. The flux of organic carbon settling through the water column and its deposition on the sea floor was similar to fluxes found in modern marine environments. Calculations based on the average accumulation rate of the marine fraction of Ni suggest the flux of organic carbon settling out of the water column was approximately 9% of primary productivity, versus an accumulation rate (burial) of organic carbon of 0.5% of primary productivity. Trace-element ratios of V:Mo and Cr:Mo in the marine sediment fraction indicate that bottom waters shifted from predominantly anoxic (sulfate reducing) during deposition of the Huron Shale Member of the Ohio Shale to predominantly suboxic (nitrate reducing) during deposition of the Cleveland Shale Member and the Sunbury Shale, but with anoxic conditions occurring intermittently throughout this period. ?? 2008 Elsevier B.V.

The earliest seeds

USGS Publications Warehouse

Gillespie, W.H.; Rothwell, G.W.; Scheckler, S.E.

1981-01-01

Lagenostomalean-type seeds in bifurcating cupule systems have been discovered in the late Devonian Hampshire Formation of Randolph County, West Virginia, USA (Fig. 1). The associated megaflora, plants from coal balls, and vertebrate and invertebrate faunas demonstrate that the material is Famennian; the microflora indicates a more specific Fa2c age. Consequently, these seeds predate Archaeosperma arnoldii1 from the Fa2d of northeastern Pennsylvania, the oldest previously reported seed. By applying precision fracture, transfer, de??gagement, and thin-section techniques to selected cupules from the more than 100 specimens on hand, we have determined the three-dimensional morphology and histology of the seeds (Fig. 2a-h, k) and cupule systems. A comparison with known late Devonian to early Carboniferous seeds reveals that ours are more primitively organized than all except Genomosperma2,3. ?? 1981 Nature Publishing Group.

Paleocurrent analysis of a deformed Devonian foreland basin in the northern Appalachians, Maine, USA

USGS Publications Warehouse

Bradley, D.C.; Hanson, L.S.

2002-01-01

New paleocurrent data indicate that the widespread Late Silurian and Devonian flysch and molasse succession in Maine was deposited in an ancestral, migrating foreland basin adjacent to an advancing Acadian orogenic belt. The foreland-basin sequence spread across a varied Silurian paleogeography of deep basins and small islands-the vestiges of an intraoceanic arc complex that not long before had collided with the Laurentian passive margin during the Ordovician Taconic Orogeny. We report paleocurrents from 43 sites representing 12 stratigraphic units, the most robust and consistent results coming from three units: Madrid Formation (southwesterly paleoflow), Carrabassett Formation (northerly paleoflow), and Seboomook Group (westerly paleoflow). Deformation and regional metamorphism are sufficiently intense to test the limits of paleocurrent analysis requiring particular care in retrodeformation. ?? 2002 Elsevier Science B.V. All rights reserved.

Post-early cretaceous landform evolution along the western margin of the banca~nnia trough, western nsw

USGS Publications Warehouse

Gibson, D.L.

2000-01-01

Previously undated post-Devonian sediments outcropping north of Fowlers Gap station near the western margin of the Bancannia Trough are shown by plant macro- and microfossil determinations to be of Early Cretaceous (most likely Neocomian and/or Aptian) age, and thus part of the Eromanga Basin. They are assigned to the previously defined Telephone Creek Formation. Study of the structural configuration of this unit and the unconformably underlying Devonian rocks suggests that the gross landscape architecture of the area results from post-Early Cretaceous monoclinal folding along blind faults at the western margin of the trough, combined with the effects of differential erosion. This study shows that, while landscape evolution in the area has been dynamic, the major changes that have occurred are on a geological rather than human timescale.

Preliminary stratigraphic cross section showing radioactive zones in the Devonian dark shales in the eastern part of the Appalachian Basin

USGS Publications Warehouse

West, Mareta N.

1978-01-01

The U.S. Geological Survey (USGS), in a cooperative agreement with the U.S. Department of Energy (DOE), is participating in the Eastern Gas Shales Project. The purpose of the DOE project is to increase the production of natural gas from eastern United States shales in petroliferous basins through improved exploration and extraction techniques. The USGS participation includes stratigraphic studies which will contribute to the characterization and appraisal of the natural gas resources of Devonian shale in the Appalachian basin.This cross section differs from others in this series partly because many of the shales in the eastern part of the basin are less radioactive than those farther west and because in this area shales that may be gas-productive are not necessarily highly radioactive and black.

Petroleum geology and resources of the Volga-Ural province, U.S.S.R.

USGS Publications Warehouse

Peterson, James A.; Clarke, James W.

1983-01-01

The Volga-Ural petroleum province is, in general, coincident with the Volga-Ural regional high, a broad upwarp of the east-central part of the Russian (East European) Platform. The central part of the province is occupied by the Tatar arch, which contains the major share of the oilfields of the province. The Komi-Perm arch forms the northeastern part of the regional high, and the Zhigulevsko-Pugachev and Orenburg arches make up the southern part. These arches are separated from one another by elongate downwarps. The platform cover overlies an Archean crystalline basement and consists of seven main sedimentation cycles. (1) Riphean (lower Bavly) continental sandstone, shale, and conglomerate beds, from 500 to 5,000 m thick, were deposited in aulacogens. (2) Vendian (upper Bavly) continental and marine shale and sandstone are up to 3,000 m thick. (3) Middle Devonian-Tournaisian transgressive deposits, which are sandstone, siltstone, and shale in the lower part and carbonates and abundant reefs in the upper part, range from 300 to 1,000 m in thickness. The upper carbonate part includes the Kamsko-Kinel trough system, which consists of narrow, interconnected, deepwater troughs. (4) The Visean-Namurian-Bashkirian cycle began with deposition of Visean clastic deposits, which draped over reefs of the previous cycle and filled in an erosional relief that had formed in some places on the sediments of the previous cycle. The Visean clastic deposits are overlain by marine carbonate beds. The cycle is from 50 to 800 m thick. (5) The lower Moscovian-Lower Permian cycle consists of 1,000 to 3,000 m of terrigenous clastic deposits and marine carbonate beds. (6) The upper Lower Permian-Upper Permian cycle reflects the maximum growth of the Ural Mountains and the associated Ural foredeep. Evaporite deposits were first laid down, followed by marine limestones and dolomites, which intertongue eastward with clastic sediments from the Ural Mountains. (7) Continental red beds of Triassic age and mixed continental and marine clastic beds of Jurassic and Cretaceous age were deposited on the western, southwestern, and northern margins of the Russian Platform; they are generally absent in the Volga-Ural province, however. Approximately 600 oilfields and gasfields and 2,000 pools have been found in the Volga-Ural province. Nine productive sequences are recognized; these are, in general, the same as the sedimentation cycles, although some subdivisions have been added. The clastic section of Middle and early Late Devonian age contains the major recoverable oil accumulations, including the supergiant Romashkino field. Cumulative production to 1980 is estimated at 30 to 35 billion barrels of oil equivalent, identified reserves at about 10 billion barrels of oil equivalent, and undiscovered resources at about 7 billion barrels of oil equivalent. Identified reserves of natural gas are estimated at 100 trillion cubic feet and undiscovered resources at 63 trillion cubic feet.

An organismal concept for Sengelia radicans gen. et sp. nov. - morphology and natural history of an Early Devonian lycophyte.

PubMed

Matsunaga, Kelly K S; Tomescu, Alexandru M F

2017-05-01

Fossil plants are found as fragmentary remains and understanding them as natural species requires assembly of whole-organism concepts that integrate different plant parts. Such concepts are essential for incorporating fossils in hypotheses of plant evolution and phylogeny. Plants of the Early Devonian are crucial to reconstructing the initial radiation of tracheophytes, yet few are understood as whole organisms. This study assembles a whole-plant concept for the Early Devonian lycophyte Sengelia radicans gen. et sp. nov., based on morphometric data and taphonomic observations from >1000 specimens collected in the Beartooth Butte Formation (Wyoming, USA). Sengelia radicans occupies a key position between stem-group and derived lycophyte lineages. Sengelia had a rooting system of downward-growing root-bearing stems, formed dense monotypic mats of prostrate shoots in areas that experienced periodic flooding, and was characterized by a life-history strategy adapted for survival after floods, dominated by clonality, and featuring infrequent sexual reproduction. Sengelia radicans is the oldest among the very few early tracheophytes for which a detailed, rigorous whole-plant concept integrates morphology, growth habit, life history and growth environment. This plant adds to the diversity of body plans documented among lycophytes and may help elucidate patterns of morphological evolution in the clade. © The Author 2017. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com

Faulting at Thebes Gap, Mo. -Ill. : Implications for New Madrid tectonism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrison, R.W.; Schultz, A.P.

1992-01-01

Recent geologic mapping in the Thebes Gap area has identified numerous NNE- and NE-striking faults having a long-lived and complex structural history. The faults are located in an area of moderate recent seismicity at the northern margin of the Mississippi embayment, approximately 45 km north of the New Madrid seismic zone. Earliest deformation occurred along dextral strike-slip faults constrained as post-Devonian and pre-Cretaceous. Uplift and erosion of all Carboniferous strata suggest that this faulting is related to development of the Pascola arch (Ouachita orogeny). This early deformation is characterized by strongly faulted and folded Ordovician through Devonian rocks overlain inmore » places with angular unconformity by undeformed Cretaceous strata. Elsewhere, younger deformation involves Paleozoic, Cretaceous, Paleocene, and Eocene formations. These units have experienced both minor high-angle normal faulting and major, dextral strike-slip faulting. Quaternary-Tertiary Mounds Gravel is also involved in the latest episode of strike-slip deformation. Enechelon north-south folds, antithetic R[prime] shears, and drag folds indicate right-lateral motion. Characteristic positive and negative flower structures are commonly revealed in cross section. Right-stepping fault strands have produced pull-apart basins where Ordovician, Silurian, Devonian, Cretaceous, and Tertiary units are downdropped several hundreds of meters and occur in chaotic orientations. Similar fault orientations and kinematics, as well as recent seismicity and close proximity, clearly suggest a structural relationship between deformation at Thebes Gap and tectonism associated with the New Madrid area.« less

Bedrock geologic map of the Montpelier and Barre West quadrangles, Washington and Orange Counties, Vermont

USGS Publications Warehouse

Walsh, Gregory J.; Kim, Jonathan; Gale, Marjorie H.; King, Sarah M.

2010-01-01

The bedrock geology of the Montpelier and Barre West quadrangles consists of Silurian and Devonian metasedimentary rocks of the Connecticut Valley-Gaspe synclinorium (CVGS) and metasedimentary, metavolcanic, and metaintrusive rocks of the Cambrian and Ordovician Moretown and Cram Hill Formations. Devonian granite dikes occur throughout the two quadrangles but are more abundant in the Silurian and Devonian rocks. The pre-Silurian rocks are separated from the rocks of the CVGS by the informally named 'Richardson Memorial Contact,' historically interpreted as either an unconformity or a fault. The results of this report represent mapping by G.J. Walsh, Jonathan Kim, and M.H. Gale from 2002 to 2005. S.M. King assisted Kim and Gale from 2002 to 2003. A.M. Satkoski (Indiana University) assisted Walsh, and L.R. Pascale (University of Vermont) and C.M. Orsi (Middlebury College) assisted Kim and Gale as summer interns in 2003. This study was designed to map the bedrock geology in the area. This map supersedes a preliminary map of the Montpelier quadrangle (Kim, Gale, and others, 2003). A companion study in the Barre West quadrangle (Walsh and Satkoski, 2005) determined the levels of naturally occurring radioactivity in the bedrock from surface measurements at outcrops during the course of 1:24,000-scale geologic mapping to identify which rock types were potential sources of radionuclides. Results of that study indicate that the carbonaceous phyllites in the CVGS have the highest levels of natural radioactivity.

Stratigraphic and palaeoenvironmental summary of the south-east Georgia embayment: a correlation of exploratory wells

USGS Publications Warehouse

Poppe, Lawrence J.; Popenoe, Peter; Poag, C. Wylie; Swift, B. Ann

1995-01-01

A Continental Offshore Stratigraphic Test (COST) well and six exploratory wells have been drilled in the south-east Georgia embayment. The oldest rocks penetrated are weakly metamorphosed Lower Ordovician quartz arenites and Silurian shales and argillites in the Transco 1005-1 well and Upper Devonian argillites in the COST GE-1 well. These marine strata, which are equivalent to the Tippecanoe sequence in Florida, underlie the post-rift unconformity and represent part of a disjunct fragment of Gondwana that was sutured to the North American craton during the late Palaeozoic Alleghanian orogeny. The Palaeozoic strata are unconformably overlain by interbedded non-marine Jurassic (Bajocian and younger) sandstones and shales and marginal marine Lower Cretaceous sandstones, calcareous shales and carbonates, which contain scattered beds of coal and evaporite. Together, these rocks are stratigraphically equivalent to the onshore Fort Pierce and Cotton Valley(?) Formations and rocks of the Lower Cretaceous Comanchean Provincial Series. The abundance of carbonates and evaporites in this interval, which reflects marine influences within the embayment, increases upwards, eastwards and southwards. The Upper Cretaceous part of the section is composed mainly of neritic calcareous shales and shaley limestones stratigraphically equivalent to the primarily marginal marine facies of the onshore Atkinson, Cape Fear and Middendorf Formations and Black Creek Group, and to limestones and shales of the Lawson Limestone and Peedee Formations. Cenozoic strata are primarily semiconsolidated marine carbonates. Palaeocene to middle Eocene strata are commonly cherty; middle Miocene to Pliocene strata are massive and locally phosphatic and glauconitic; Quaternary sediments are dominated by unconsolidated carbonate sands. The effects of eustatic changes and shifts in the palaeocirculation are recorded in the Upper Cretaceous and Tertiary strata.

A carbon isotopic and sedimentological record of the latest Devonian (Famennian) from the Western U.S. and Germany

USGS Publications Warehouse

Myrow, P.M.; Strauss, J.V.; Creveling, J.R.; Sicard, K.R.; Ripperdan, R.; Sandberg, C.A.; Hartenfels, S.

2011-01-01

New carbon isotopic data from upper Famennian deposits in the western United States reveal two previously unrecognized major positive isotopic excursions. The first is an abrupt ~. 3??? positive excursion, herein referred to as ALFIE (A Late Famennian Isotopic Excursion), recorded in two sections of the Pinyon Peak Limestone of north-central Utah. Integration of detailed chemostratigraphic and biostratigraphic data suggests that ALFIE is the Laurentian record of the Dasberg Event, which has been linked to transgression in Europe and Morocco. Sedimentological data from the Chaffee Group of western Colorado also record transgression at a similar biostratigraphic position, with a shift from restricted to open-marine lithofacies. ALFIE is not evident in chemostratigraphic data from age-equivalent strata in Germany studied herein and in southern Europe, either because it is a uniquely North American phenomenon, or because the German sections are too condensed relative to those in Laurentia. A second positive carbon isotopic excursion from the upper Chaffee Group of Colorado is recorded in transgressive strata deposited directly above a previously unrecognized paleokarst interval. The age of this excursion, and the duration of the associated paleokarst hiatus, are not well constrained, although the events occurred sometime after the Late Famennian Middle expansa Zone. The high positive values recorded in this excursion are consistent with those associated with the youngest Famennian Middle to Late praesulcata Hangenberg Isotopic Excursion in Europe, the isotopic expression of the Hangenberg Event, which included mass extinction, widespread black shale deposition, and a glacio-eustatic fall and rise. If correct, this would considerably revise the age of the Upper Chaffee Group strata of western Colorado. ?? 2011 Elsevier B.V.

New insight on petroleum system modeling of Ghadames basin, Libya

NASA Astrophysics Data System (ADS)

Bora, Deepender; Dubey, Siddharth

2015-12-01

Underdown and Redfern (2008) performed a detailed petroleum system modeling of the Ghadames basin along an E-W section. However, hydrocarbon generation, migration and accumulation changes significantly across the basin due to complex geological history. Therefore, a single section can't be considered representative for the whole basin. This study aims at bridging this gap by performing petroleum system modeling along a N-S section and provides new insights on source rock maturation, generation and migration of the hydrocarbons using 2D basin modeling. This study in conjunction with earlier work provides a 3D context of petroleum system modeling in the Ghadames basin. Hydrocarbon generation from the lower Silurian Tanezzuft formation and the Upper Devonian Aouinet Ouenine started during the late Carboniferous. However, high subsidence rate during middle to late Cretaceous and elevated heat flow in Cenozoic had maximum impact on source rock transformation and hydrocarbon generation whereas large-scale uplift and erosion during Alpine orogeny has significant impact on migration and accumulation. Visible migration observed along faults, which reactivated during Austrian unconformity. Peak hydrocarbon expulsion reached during Oligocene for both the Tanezzuft and the Aouinet Ouenine source rocks. Based on modeling results, capillary entry pressure driven downward expulsion of hydrocarbons from the lower Silurian Tanezzuft formation to the underlying Bir Tlacsin formation observed during middle Cretaceous. Kinetic modeling has helped to model hydrocarbon composition and distribution of generated hydrocarbons from both the source rocks. Application of source to reservoir tracking technology suggest some accumulations at shallow stratigraphic level has received hydrocarbons from both the Tanezzuft and Aouinet Ouenine source rocks, implying charge mixing. Five petroleum systems identified based on source to reservoir correlation technology in Petromod*. This Study builds upon the original work of Underdown and Redfern, 2008 and offers new insights and interpretation of the data.

Phanerozoic polyphase orogenies recorded in the northeastern Okcheon Belt, Korea from SHRIMP U-Pb detrital zircon and K-Ar illite geochronologies

NASA Astrophysics Data System (ADS)

Jang, Yirang; Kwon, Sanghoon; Song, Yungoo; Kim, Sung Won; Kwon, Yi Kyun; Yi, Keewook

2018-05-01

We present the SHRIMP U-Pb detrital zircon and K-Ar illite 1Md/1M and 2M1 ages, suggesting new insight into the Phanerozoic polyphase orogenies preserved in the northeastern Okcheon Belt, Korea since the initial basin formation during Neoproterozoic rifting through several successive contractional orogens. The U-Pb detrital zircon ages from the Early Paleozoic strata of the Taebaeksan Zone suggest a Cambrian maximum deposition age, and are supported by trilobite and conodont biostratigraphy. Although the age spectra from two sedimentary groups, the Yeongwol and Taebaek Groups, show similar continuous distributions from the Late Paleoproterozoic to Early Paleozoic ages, a Grenville-age hiatus (1.3-0.9 Ga) in the continuous stratigraphic sequence from the Taebaek Group suggests the existence of different peripheral clastic sources along rifted continental margin(s). In addition, we present the K-Ar illite 1Md/1M ages of the fault gouges, which confirm fault formation/reactivation during the Late Cretaceous to Early Paleogene (ca. 82-62 Ma) and the Early Miocene (ca. 20-18 Ma). The 2M1 illite ages, at least those younger than the host rock ages, provide episodes of deformation, metamorphism and hydrothermal effects related to the tectonic events during the Devonian (ca.410 Ma) and Permo-Triassic (ca. 285-240 Ma). These results indicate that the northeastern Okcheon Belt experienced polyphase orogenic events, namely the Okcheon (Middle Paleozoic), Songrim (Late Paleozoic to Early Mesozoic), Daebo (Middle Mesozoic) and Bulguksa (Late Mesozoic to Early Cenozoic) Orogenies, reflecting the Phanerozoic tectonic evolution of the Korean Peninsula along the East Asian continental margin.

The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation

USGS Publications Warehouse

Claypool, George E.; Holser, William T.; Kaplan, Isaac R.; Sakai, Hitoshi; Zak, Israel

1980-01-01

Three hundred new samples of marine evaporite sulfate, of world-wide distribution, were analyzed for δ34S, and 60 of these also for δ18O in the sulfate ion. Detailed δ34S age curves for Tertiary—Cretaceous, Permian—Pennsylvanian, Devonian, Cambrian and Proterozoic times document large variations in δ34S. A summary curve forδ18O also shows definite variations, some at different times than δ34S, and always smaller. The measured δ34S and δ18O correspond to variations in these isotopes in sulfate of the world ocean surface. The variations of δ18O are controlled by input and output fluxes of sulfur in the ocean, three of which are the same that control δ34S: deposition and erosion of sulfate, and deposition of sulfide. Erosion of sulfide differs in its effect on the S and O systems. δ18O in the sulfate does not seem to be measurably affected by equilibration with either seawater or with subsurface waters after crystallization. In principle, the simultaneous application of both δ34S and δ18O age curves should help reduce the number of assumptions in calculations of the cycles of sulfur and oxygen through geological time, and a new model involving symmetrical fluxes is introduced here to take advantage of the oxygen data. However, all previously published models as well as this one lead to anomalies, such as unreasonable calcium or oxygen depletions in the ocean—atmosphere system. In addition, most models are incapable of reproducing the sharp rises of the δ34S curve in the late Proterozoic, the Devonian and the Triassic which would be the result of unreasonably fast net sulfide deposition. This fast depletion could result from an ocean that has not always been mixed (as previously assumed in all model calculations).

Carboniferous paleogeographic, phytogeographic, and paleoclimatic reconstructions

USGS Publications Warehouse

Rowley, D.B.; Raymond, A.; Parrish, Judith T.; Lottes, A.L.; Scotese, C.R.; Ziegler, A.M.

1985-01-01

Two revised paleogeographic reconstructions of the Visean and Westphalian C-D stages are presented based on recent paleomagnetic, phytogeographic, stratigraphic, and tectonic data. These data change the positions of some continental blocks, and allow the definition of several new ones. The most important modifications that have been incorporated in these reconstructions are: (1) a proposed isthmus linking North America and Siberia across the Bering Strait; and (2) the separation of China and Southeast Asia in six major blocks, including South China, North China, Shan Thai-Malaya, Indochina, Qangtang, and Tarim blocks. Evidence is presented that suggests that at least the South China, Shan Thai-Malaya, and Qangtang blocks were derived from the northern margin of Gondwana. Multivariate statistical analysis of phytogeographic data from the middle and late Paleozoic allow definition of a number of different phytogeographic units for four time intervals: (1) the Early Devonian, (2) Tournaisian-early Visean, (3) Visean, and (4) late Visean-early Namurian A. Pre-late Visean-early Namurian A floral assemblages from South China show affinities with northern Gondwana floras suggesting a southerly position and provides additional support for our reconstruction of South China against the northern margin of Gondwana. There is a marked decrease in the diversity of phytogeographic units in the Namurian and younger Carboniferous. This correlates closely with the time of assembly of most of Pangaea. The general pattern of Carboniferous phytogeographic units corresponds well with global distribution of continents shown on our paleogeographic reconstructions. In addition, we have constructed paleoclimatic maps for the two Carboniferous time intervals. These maps stress the distribution of rainfall, as this should be strongly correlated with the floras. There is marked change in the rainfall patterns between the Visean and Westphalian C-D. This change corresponds with the closing of the Appalachian-Ouachita ocean between Laurussia and Gondwana, and reflects the removal of a low-latitude moisture source that probably gave rise to monsoonal conditions along the northern margin of Gondwana in the Visean and earlier times. As well, the presence of a substantial heat source at high elevation in the Late Carboniferous significantly influenced the distribution of climatic belts. ?? 1986.

Mid and Late Devonian arenites deposited by sheet-flood, braided streams and rivers in the northern Barrier Ranges, far western New South Wales, Australia

NASA Astrophysics Data System (ADS)

Neef, G.; Bottrill, R. S.; Cohen, D. R.

1996-05-01

Extensive and well exposed, fine-grained fluvial sandstone and less common pebbly coarse-grained fluvial sandstone of Devonian age, crop out in the northern Barrier Ranges of far west New South Wales, Australia. These strata were deposited largely on low-gradient alluvial fans in a basin and range landscape and contain common sedimentary structures (especially streaming lineations and tabular cross-beds). Around 400 of these sedimentary structures were measured to determine the palaeoflow trends of the sheet floods, streams or rivers which deposited the sandstone. The strata are mapped as the Mid Devonian Coco Range Sandstone and the Late Devonian Nundooka Sandstone, which together are around 2.7 km thick. They were deposited at the western margin of the large Emsian to Early Carboniferous Darling Basin. The Coco Range Sandstone is Emsian to Eifelian in age (based on fragments) of fossil fish) and it is separated from the Frasnian-Famennian (Late Devonian) Nundooka Sandstone by the north-trending Nundooka Creek Fault. The eastern boundary of the Nundooka Sandstone is formed by the Western Boundary Fault. Eastward of this fault is the north-trending and 40 km wide Bancannia Trough, which contains gently folded Late Silurian to Early Carboniferous strata up to 7.5 km thick. Most of the Coco Range Sandstone and all of the Nundooka Sandstone are non-graded, fine and very fine-grained, light brown sub-litharenites which are considered to have been deposited mainly on low-gradient alluvial fans. Sedimentary successions of 1.75 to 5.25 m thickness in the fine-grained arenite usually commence with Sm (massive or slumped) → Sh (laminated arenite) or St (trough cross-beds) → Sp (tabular cross-bedded sandstone). An erosional surface commonly underlies the sedimentary successions and they are interpreted to be the result of deposition from decelerating sheet floods. Units composed of tabular cross-bedded strata several metres thick are rarely channelised and are interpreted to represent deposition within braided streams flowing upon the fans or deposited at the margin of sheet floods. In the Coco Range Sandstone there are two sheet-like coarse pebbly arenite units (The Valley Tank and Copi Dam Members) which together total 200 m in thickness. Unimodal palaeocurrent trends and heavy mineral suites from within the coarse-grained arenite indicate a derivation from the south near Broken Hill. Sedimentary structures within the coarse-grained arenite indicate a Platte River style of deposition upon distal braid plains, whereas local interdigitation of coarse-grained arenite with fine arenite strata shows that deposition was essentially continuous (i.e. the coarse arenite do not overlie unconformities) and the two lithotypes represent interdigitation of alluvial fans and braid plain deposition. The northward progradation of the coarse arenite units was probably due to a sudden retardation of basement downwarping.

Identifying heterogeneity in rates of morphological evolution: discrete character change in the evolution of lungfish (Sarcopterygii; Dipnoi).

PubMed

Lloyd, Graeme T; Wang, Steve C; Brusatte, Stephen L

2012-02-01

Quantifying rates of morphological evolution is important in many macroevolutionary studies, and critical when assessing possible adaptive radiations and episodes of punctuated equilibrium in the fossil record. However, studies of morphological rates of change have lagged behind those on taxonomic diversification, and most authors have focused on continuous characters and quantifying patterns of morphological rates over time. Here, we provide a phylogenetic approach, using discrete characters and three statistical tests to determine points on a cladogram (branches or entire clades) that are characterized by significantly high or low rates of change. These methods include a randomization approach that identifies branches with significantly high rates and likelihood ratio tests that pinpoint either branches or clades that have significantly higher or lower rates than the pooled rate of the remainder of the tree. As a test case for these methods, we analyze a discrete character dataset of lungfish, which have long been regarded as "living fossils" due to an apparent slowdown in rates since the Devonian. We find that morphological rates are highly heterogeneous across the phylogeny and recover a general pattern of decreasing rates along the phylogenetic backbone toward living taxa, from the Devonian until the present. Compared with previous work, we are able to report a more nuanced picture of lungfish evolution using these new methods. © 2011 The Author(s). Evolution© 2011 The Society for the Study of Evolution.

Geologic framework of pre-Cretaceous rocks in the Southern Ute Indian Reservation and adjacent areas, southwestern Colorado and northwestern New Mexico

USGS Publications Warehouse

Condon, Steven M.

1992-01-01

This report is a discussion and summary of Jurassic and older rocks in the Southern Ute Indian Reservation and adjacent areas, southwestern Colorado and northwestern New Mexico, and is based on analysis of geophysical logs and observations of outcrops. The Reservation, which is located in the northern San Juan Basin, has been the site of deposition of sediments for much of the Phanerozoic. Geologic times represented on the Reservation are the Precambrian, Cambrian, Devonian, Mississippian, Pennsylvanian, Permian, Triassic, Jurassic, Cretaceous, Tertiary, and Quaternary. Rocks of Ordovician and Silurian age have not been reported in this region. Thicknesses of pre-Cretaceous sedimentary rocks range from about 750 feet (229 meters) on the Archuleta arch, east of the Reservation, to more than 8,300 feet (2,530 meters) just northwest of the Reservation. About 5,500 feet (1,676 meters) of pre-Cretaceous sedimentary rocks occur in the central part of the Reservation, near Ignacio. At Ignacio the top of the Jurassic lies at a depth of 7,600 feet (2,316 meters) below the surface, which is composed of Tertiary rocks. As much as 2,500 feet (762 meters) of Tertiary rocks occur in the area. More than 10,000 feet (3,048 meters) of Cretaceous and younger rocks, and 15,600 feet (4,755 meters) of all Phanerozoic sedimentary rocks occur in the vicinity of the Reservation. In the early Paleozoic the area that includes the Southern Ute Reservation was on the stable western shelf of the craton. During this time sediments that compose the following shallow-marine clastic and carbonate rocks were deposited: the Upper Cambrian Ignacio Quartzite (0-150 feet; 0-46 meters), Upper Devonian Elbert Formation (50-200 feet; 15-61 meters), Upper Devonian Ouray Limestone (10-75 feet; 3-23 meters), and Mississippian Leadville Limestone (0-250 feet; 0-76 meters). Mixed carbonate and clastic deposition, which was punctuated by a unique episode of deposition of evaporite sediments, continued through the Pennsylvanian after a significant episode of erosion at the end of the Mississippian. Pennsylvanian rocks on the Reservation are the Molas Formation (20-100 feet; 6-30 meters) and Hermosa Group (400-2,800 feet; 122-853 meters), which consists of the Pinkerton Trail Formation (40-120 feet; 12-36 meters), Paradox Formation and equivalent rocks (200-1,800 feet; 61-549 meters), and Honaker Trail Formation (200-1,300 feet; 61-396 meters). A unit that is transitional between the Pennsylvanian and Permian is the Rico Formation, which is about 200 feet (61 meters) thick across most of the Reservation area. The close of the Paleozoic Era was marked by a great influx of arkosic clastic sediments from uplifted highlands to the north of the Reservation area during the Permian. Near the paleomountain front the Cutler Formation (presently as thick as 8,000 feet; 2,438 meters) formed as a result of deposition of arkosic sediments; however, the original thickness of the Cutler is unknown due to an unconformity at its top. In the area of the Reservation the Cutler has group status and has been divided into several formations: the Halgaito Formation (350-800 feet; 107-244 meters), Cedar Mesa Sandstone and equivalent rocks (150-350 feet; 46-107 meters), Organ Rock Formation (500-900 feet; 152-274 meters), and De Chelly Sandstone (0-100 feet; 0-30 meters). The sediments of these formations were deposited in a variety of environments, including eolian, mud-flat, and fluvial systems. Following an episode of erosion in the Early and Middle(?) Triassic, deposition in the area of the Southern Ute Reservation continued during the Mesozoic. Sediments of the Upper Triassic Dolores and correlative Chinle Formations were deposited in fluvial, lacustrine, and minor eolian environments. On the Reservation the Dolores is 500-1,200 feet (152-366 meters) thick. Lower Jurassic eolian and fluvial deposits may have been present in much of the Reservation area but have been removed

Correlation of LANDSAT lineaments with Devonian gas fields in Lawrence County, Ohio

NASA Technical Reports Server (NTRS)

Johnson, G. O.

1981-01-01

In an effort to locate sources of natural gas in Ohio, the fractures and lineaments in Black Devonian shale were measured by: (1) field mapping of joints, swarms, and fractures; (2) stereophotointerpretation of geomorphic lineaments with precise photoquads; and (3) by interpreting the linear features on LANDSAT images. All results were compiled and graphically represented on 1:250,000 scale maps. The geologic setting of Lawrence County was defined and a field fracture map was generated and plotted as rose patterns at the exposure site. All maps were compared, contrasted, and correlated by superimposing each over the other as a transparency. The LANDSAT lineaments had significant correlation with the limits of oil and gas producing fields. These limits included termination of field production as well as extensions to other fields. The lineaments represent real rock fractures with zones of increased permeability in the near surface bedrock.

Gold Veins near Great Falls, Maryland

USGS Publications Warehouse

Reed, John Calvin; Reed, John C.

1969-01-01

Small deposits of native gold are present along an anastomosing system of quartz veins and shear zones just east of Great Falls, Montgomery County, Md. The deposits were discovered in 1861 and were worked sporadically until 1951, yielding more than 5,000 ounces of gold. The vein system and the principal veins within it strike a few degrees west of north, at an appreciable angle to foliation and fold axial planes in enclosing rocks of the Wissahickon Formation of late Precambrian (?) age. The veins cut granitic rocks of Devonian or pre-Devonian age and may be as young as Triassic. Further development of the deposits is unlikely under present economic conditions because of their generally low gold content and because much of the vein system lies on park property, but study of the Great Falls vein system may be useful in the search for similar deposits elsewhere in the Appalachian Piedmont.

Indirect and direct tensile behavior of Devonian oil shales

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chong, K.P.; Chen, J.L.; Dana, G.F.

1984-03-01

Ultimate indirect tensile strengths of Devonian oil shales across the bedding planes is a mechanical property parameter important to predicting how oil shale will break. This is particularly important to in-situ fragmentation. The Split Cylinder Test was used to determine the indirect tensile strengths between the bedding planes. Test specimens, cored perpendicular to the bedding planes, representing oil shales of different oil yields taken from Silver Point Quad in DeKalb County, Tennessee and Friendship in Scioto County, Ohio, were subjected to the Split Cylinder Test. Linear regression equations relating ultimate tensile strength across the bedding planes to volume percent ofmore » organic matter in the rock were developed from the test data. In addition, direct tensile strengths were obtained between the bedding planes for the Tennessee oil shales. This property is important for the design of horizontal fractures in oil shales. Typical results were presented.« less

An enigmatic fossil fungus from the 410 Ma Rhynie chert that resembles Macrochytrium (Chytridiomycota) and Blastocladiella (Blastocladiomycota).

PubMed

Krings, Michael; Taylor, Thomas N; Martin, Helmut

2016-01-01

Litter layers in the Lower Devonian (~ 410 Ma) Rhynie chert were inhabited by a wide variety of saprotrophic fungi, however, only a few of these organisms have been described formally. A new microfungus, Trewinomyces annulifer gen. et sp. nov., occurs as tufts on decaying land plant axes from the Rhynie chert. The fungus consists of an intramatrical rhizoidal system and an erect extramatrical hypha (stalk) that bears a single, terminal sporangium. One or two successive rings often are present in the stalk immediately below the sporangium base. Overall morphology of T. annulifer resembles the extant genera Macrochytrium (Chytridiomycota) and Blastocladiella (Blastocladiomycota). However, the rhizoids are septate or pseudoseptate, a feature not known in extant zoosporic fungi, and thus render the systematic affinities of T. annulifer unresolved. Trewinomyces annulifer offers a rare view of the morphology of a distinctive Early Devonian saprotrophic microfungus. © 2016 by The Mycological Society of America.

The largest Silurian vertebrate and its palaeoecological implications

PubMed Central

Choo, Brian; Zhu, Min; Zhao, Wenjin; Jia, Liaotao; Zhu, You'an

2014-01-01

An apparent absence of Silurian fishes more than half-a-metre in length has been viewed as evidence that gnathostomes were restricted in size and diversity prior to the Devonian. Here we describe the largest pre-Devonian vertebrate (Megamastax amblyodus gen. et sp. nov.), a predatory marine osteichthyan from the Silurian Kuanti Formation (late Ludlow, ~423 million years ago) of Yunnan, China, with an estimated length of about 1 meter. The unusual dentition of the new form suggests a durophagous diet which, combined with its large size, indicates a considerable degree of trophic specialisation among early osteichthyans. The lack of large Silurian vertebrates has recently been used as constraint in palaeoatmospheric modelling, with purported lower oxygen levels imposing a physiological size limit. Regardless of the exact causal relationship between oxygen availability and evolutionary success, this finding refutes the assumption that pre-Emsian vertebrates were restricted to small body sizes. PMID:24921626

Ornamentation of dermal bones of Placodermi from the Lower Devonian of Morocco as a measure of biodiversity

NASA Astrophysics Data System (ADS)

Antczak, Mateusz; Berkowski, Błażej

2017-06-01

Dermal bones are formed early during growth and thus constitute an important tool in studies of ontogenetic and evolutionary changes amongst early vertebrates. Ornamentation of dermal bones of terrestrial vertebrates is often used as a taxonomic tool, for instance in Aetosauria, extant lungfishes (Dipnoi) and ray-finned fishes (Actinopterygii), for which it have been proved to be of use in differentiating specimens to species level. However, it has not been utilised to the same extent in placoderms. Several features of the ornamentation of Early Devonian placoderms from Hamar Laghdad (Morocco) were examined using both optical and scanning electron microscopy to determine whether it is possible to distinguish armoured Palaeozoic fishes. Four distinct morphotypes, based on ornamentation of dermal bones, are differentiated. These distinct types of ornamentation may be the result of either different location of dermal plates on the body or of ontogenetic (intraspecific) and/or interspecific variation.

Improving global paleogeography since the late Paleozoic using paleobiology

NASA Astrophysics Data System (ADS)

Cao, Wenchao; Zahirovic, Sabin; Flament, Nicolas; Williams, Simon; Golonka, Jan; Dietmar Müller, R.

2017-12-01

Paleogeographic reconstructions are important to understand Earth's tectonic evolution, past eustatic and regional sea level change, paleoclimate and ocean circulation, deep Earth resources and to constrain and interpret the dynamic topography predicted by mantle convection models. Global paleogeographic maps have been compiled and published, but they are generally presented as static maps with varying map projections, different time intervals represented by the maps and different plate motion models that underlie the paleogeographic reconstructions. This makes it difficult to convert the maps into a digital form and link them to alternative digital plate tectonic reconstructions. To address this limitation, we develop a workflow to restore global paleogeographic maps to their present-day coordinates and enable them to be linked to a different tectonic reconstruction. We use marine fossil collections from the Paleobiology Database to identify inconsistencies between their indicative paleoenvironments and published paleogeographic maps, and revise the locations of inferred paleo-coastlines that represent the estimated maximum transgression surfaces by resolving these inconsistencies. As a result, the consistency ratio between the paleogeography and the paleoenvironments indicated by the marine fossil collections is increased from an average of 75 % to nearly full consistency (100 %). The paleogeography in the main regions of North America, South America, Europe and Africa is significantly revised, especially in the Late Carboniferous, Middle Permian, Triassic, Jurassic, Late Cretaceous and most of the Cenozoic. The global flooded continental areas since the Early Devonian calculated from the revised paleogeography in this study are generally consistent with results derived from other paleoenvironment and paleo-lithofacies data and with the strontium isotope record in marine carbonates. We also estimate the terrestrial areal change over time associated with transferring reconstruction, filling gaps and modifying the paleogeographic geometries based on the paleobiology test. This indicates that the variation of the underlying plate reconstruction is the main factor that contributes to the terrestrial areal change, and the effect of revising paleogeographic geometries based on paleobiology is secondary.

Crustal melting and recycling: geochronology and sources of Variscan syn-kinematic anatectic granitoids of the Tormes Dome (Central Iberian Zone). A U-Pb LA-ICP-MS study

NASA Astrophysics Data System (ADS)

López-Moro, F. J.; López-Plaza, M.; Gutiérrez-Alonso, G.; Fernández-Suárez, J.; López-Carmona, A.; Hofmann, M.; Romer, R. L.

2018-04-01

In this study, we report U-Pb Laser Ablation ICP-MS zircon and ID-TIMS monazite ages for peraluminous granitoid plutons (biotite ± muscovite ± cordierite ± sillimanite) in the Tormes Dome, one of the gneiss-cored domes located in the Central Iberian Zone of the Variscan belt of northern Spain. Textural domains in zircon, interpreted to represent the magmatic crystallization of the granitoids (and one monazite fraction in the Ledesma pluton) yielded ages around 320 Ma, in agreement with other geochronological studies in the region. This age is interpreted to date the timing of decompression crustal melting driven by the extensional collapse of the orogenic belt in this domain of the Variscan chain of western Europe. In addition, there are several populations of inherited (xenocrystic) zircon: (1) Carboniferous zircon crystals (ca. 345 Ma) as well as one of the monazite fractions in the coarse-grained facies of the Ledesma pluton that also yielded an age of ca. 343 Ma. (2) Devonian-Silurian zircon xenocrysts with scattered ages between ca. 390 and 432 Ma. (3) Middle Cambrian-Ordovician (ca. 450-511 Ma). (4) Ediacaran-Cryogenian zircon ages (ca. 540-840 Ma). (5) Mesoproterozoic to Archaean zircon (900-2700 Ma). The abundance of Carboniferous-inherited zircon shows that crustal recycling/cannibalization may often happen at a fast pace in orogenic scenarios with only short lapses of quiescence. In our case study, it seems plausible that a "crustal layer" of ca. 340 Ma granitoids/migmatites was recycled, partially or totally, only 15-20 My after its emplacement.

A search for stratiform massive-sulfide exploration targets in Appalachian Devonian rocks; a case study using computer-assisted attribute-coincidence mapping

USGS Publications Warehouse

Wedow, Helmuth

1983-01-01

The empirical model for sediment-associated, stratiform, exhalative, massive-sulfide deposits presented by D. Large in 1979 and 1980 has been redesigned to permit its use in a computer-assisted search for exploration-target areas in Devonian rocks of the Appalachian region using attribute-coincidence mapping (ACM). Some 36 gridded-data maps and selected maps derived therefrom were developed to show the orthogonal patterns, using the 7-1/2 minute quadrangle as an information cell, of geologic data patterns relevant to the empirical model. From these map and data files, six attribute-coincidence maps were prepared to illustrate both variation in the application of ACM techniques and the extent of possible significant exploration-target areas. As a result of this preliminary work in ACM, four major (and some lesser) exploration-target areas needing further study and analysis have been defined as follows: 1) in western and central New York in the outcrop area of lowermost Upper Devonian rocks straddling the Clarendon-Linden fault; 2) in western Virginia and eastern West Virginia in an area largely coincident with the well-known 'Oriskany' Mn-Fe ores; 3) an area in West Virginia, Maryland, and Virginia along and nearby the trend of the Alabama-New York lineament of King and Zietz approximately between 38- and 40-degrees N. latitude; and 4) an area in northeastern Ohio overlying an area coincident with a significant thickness of Silurian salt and high modern seismic activity. Some lesser, smaller areas suggested by relatively high coincidence may also be worthy of further study.

Geochemistry of formation waters from the Wolfcamp and “Cline” shales: Insights into brine origin, reservoir connectivity, and fluid flow in the Permian Basin, USA

USGS Publications Warehouse

Engle, Mark A.; Reyes, Francisco R.; Varonka, Matthew S.; Orem, William H.; Lin, Ma; Ianno, Adam J.; Westphal, Tiffani M.; Xu, Pei; Carroll, Kenneth C.

2016-01-01

Despite being one of the most important oil producing provinces in the United States, information on basinal hydrogeology and fluid flow in the Permian Basin of Texas and New Mexico is lacking. The source and geochemistry of brines from the basin were investigated (Ordovician- to Guadalupian-age reservoirs) by combining previously published data from conventional reservoirs with geochemical results for 39 new produced water samples, with a focus on those from shales. Salinity of the Ca–Cl-type brines in the basin generally increases with depth reaching a maximum in Devonian (median = 154 g/L) reservoirs, followed by decreases in salinity in the Silurian (median = 77 g/L) and Ordovician (median = 70 g/L) reservoirs. Isotopic data for B, O, H, and Sr and ion chemistry indicate three major types of water. Lower salinity fluids (<70 g/L) of meteoric origin in the middle and upper Permian hydrocarbon reservoirs (1.2–2.5 km depth; Guadalupian and Leonardian age) likely represent meteoric waters that infiltrated through and dissolved halite and anhydrite in the overlying evaporite layer. Saline (>100 g/L), isotopically heavy (O and H) water in Leonardian [Permian] to Pennsylvanian reservoirs (2–3.2 km depth) is evaporated, Late Permian seawater. Water from the Permian Wolfcamp and Pennsylvanian “Cline” shales, which are isotopically similar but lower in salinity and enriched in alkalis, appear to have developed their composition due to post-illitization diffusion into the shales. Samples from the “Cline” shale are further enriched with NH4, Br, I and isotopically light B, sourced from the breakdown of marine kerogen in the unit. Lower salinity waters (<100 g/L) in Devonian and deeper reservoirs (>3 km depth), which plot near the modern local meteoric water line, are distinct from the water in overlying reservoirs. We propose that these deep meteoric waters are part of a newly identified hydrogeologic unit: the Deep Basin Meteoric Aquifer System. Chemical, isotopic, and pressure data suggest that despite over-pressuring in the Wolfcamp shale, there is little potential for vertical fluid migration to the surface environment via natural conduits.

On the fossil faunas of the Upper Devonian: The Genesee section, New York

USGS Publications Warehouse

Williams, Henry Shaler

1887-01-01

I have the honor to transmit herewith for publication as a bulletin a second contribution to the study of Devonian paleontology, Bulletin No. 3, "On the Fossil Faunas of the Upper Devonian," having been designed as the first of a series of papers on the comparative paleontology of the Devonian and Carboniferous.In that paper I gave the results of a study of the section along the meridian of Ithaca and Cayuga Lake, running southward, which may be called the Cayuga section.In 1883 examination was made south along the meridian running through Genesee County, New York, into McKean County, Pennsylvania, where the Alton coal beds were reached. The general results of this survey were communicated to the Director of the United States Geological Survey and an abstract of my communication was published in Science, Vol. II, pp. 836, 837, December 28, 1883. The present paper is a detailed report of the study of the materials of this Genesee section.Since the field work was done several additional sections have been examined: in 1884, sections through Western New York (and adjoining Pennsylvania) from Chautauqua County westward and into Ohio as far as the meridian of Cleveland; and in 1885 the region between the Cayuga section and those of Delaware and Otsego Counties, as far as Oneonta, were examined. The materials are under investigation and will be reported upon as soon as their study is completed.The sections are made along meridians, in order to make them more readily and simply comparable. Each long meridional section runs through the same stratigraphical series of deposits and is made up of a series of small local sections, such as the individual outcrop of the rocks renders possible.It is not supposed that in any case these sections are exhaustive, but it is intended that so far as they go the relative position of the faunas in the sections shall be precise and the association of species in each horizon shall be given as it is, so that the faunas can be identified, and thus, while they will leave much to be added, these studies, it is hoped, will give an outline of the geographical distribution and geological range of faunas and their species which will make a comparative study of the faunas possible.Respectfully yours, HENRY S. WILLIAMS.

Biostratigraphy and structure of paleozoic host rocks and their relationship to Carlin-type gold deposits in the Jerritt Canyon mining district, Nevada

USGS Publications Warehouse

Peters, S.G.; Armstrong, A.K.; Harris, A.G.; Oscarson, R.L.; Noble, P.J.

2003-01-01

The Jerritt Canyon mining district in the northern Independence Range, northern Nevada, contains multiple, nearly horizontal, thrust masses of platform carbonate rocks that are exposed in a series of north- to northeast-elongated, tectonic windows through rocks of the Roberts Mountains allochthon. The Roberts Mountains allochthon was emplaced during the Late Devonian to Early Mississippian Antler orogeny. These thrust masses contain structurally and stratigraphically controlled Carlin-type gold deposits. The gold deposits are hosted in tectonically truncated units of the Silurian to Devonian Hanson Creek and Roberts Mountains Formations that lie within structural slices of an Eastern assemblage of Cambrian to Devonian carbonate rocks. In addition, these multiply thrust-faulted and folded host rocks are structurally interleaved with Mississippian siliciclastic rocks and are overlain structurally by Cambrian to Devonian siliciclastic units of the Roberts Mountains allochthon. All sedimentary rocks were involved in thrusting, high-angle faulting, and folding, and some of these events indicate substantial late Paleozoic and/or Mesozoic regional shortening. Early Pennsylvanian and late Eocene dikes also intrude the sedimentary rocks. These rocks all were uplifted into a northeast-trending range by subsequent late Cenozoic Basin and Range faulting. Eocene sedimentary and volcanic rocks flank part of the range. Pathways of hydrothermal fluid flow and locations of Carlin-type gold orebodies in the Jerritt Canyon mining district were controlled by structural and host-rock geometries within specific lithologies of the stacked thrust masses of Eastern assemblage rocks. The gold deposits are most common proximal to intersections of northeast-striking faults, northwest-striking dikes, and thrust planes that lie adjacent to permeable stratigraphic horizons. The host stratigraphic units include carbonate sequences that contained primary intercrystalline permeability, which provided initial pathways for fluid flow and later served as precipitation sites for ore minerals. Alteration, during, and perhaps prior to mineralization, enhanced primary permeability by dissolution, by removal of calcite, and by formation of dolomite. Ore-stage sulfide minerals and alteration minerals commonly precipitated in pore spaces among dolomite grains. Microveinlets and microbrecciation in zones of intense alteration also provided networks of secondary permeability that further enhanced fluid flux and produced additional sites for ore deposition.

Geologic controls on cave development in Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lucas, Philip C.; Lambert, Richard A.

2017-01-01

Burnsville Cove in Bath and Highland Counties (Virginia, USA) is a karst region in the Valley and Ridge Province of the Appalachian Mountains. The region contains many caves in Silurian to Devonian limestone, and is well suited for examining geologic controls on cave location and cave passage morphology. In Burnsville Cove, many caves are located preferentially near the axes of synclines and anticlines. For example, Butler Cave is an elongate cave where the trunk channel follows the axis of Sinking Creek syncline and most of the side passages follow joints at right angles to the syncline axis. In contrast, the Water Sinks Subway Cave, Owl Cave, and Helictite Cave have abundant maze patterns, and are located near the axis of Chestnut Ridge anticline. The maze patterns may be related to fact that the anticline axis is the site of the greatest amount of flexure, leading to more joints and (or) greater enlargement of joints. Many of the larger caves of Burnsville Cove (e.g., Breathing Cave, Butler Cave–Sinking Creek Cave System, lower parts of the Water Sinks Cave System) are developed in the Silurian Tonoloway Limestone, the stratigraphic unit with the greatest surface exposure in the area. Other caves are developed in the Silurian to Devonian Keyser Limestone of the Helderberg Group (e.g., Owl Cave, upper parts of the Water Sinks Cave System) and in the Devonian Shriver Chert and (or) Licking Creek Limestone of the Helderberg Group (e.g., Helictite Cave). Within the Tonoloway Limestone, the larger caves are developed in the lower member of the Tonoloway Limestone immediately below a bed of silica-cemented sandstone. In contrast, the larger caves in the Keyser Limestone are located preferentially in limestone beds containing stromatoporoid reefs, and some of the larger caves in the Licking Creek Limestone are located in beds of cherty limestone below the Devonian Oriskany Sandstone. Geologic controls on cave passage morphology include joints, bedding planes, and folds. The influence of joints results in tall and narrow cave passages, whereas the influence of bedding planes results in cave passages with flat ceilings and (or) floors. The influence of folds is less common, but a few cave passages follow fold axes and have distinctive arched ceilings.

Sandstone provenance and U-Pb ages of detrital zircons from Permian-Triassic forearc sediments within the Sukhothai Arc, northern Thailand: Record of volcanic-arc evolution in response to Paleo-Tethys subduction

NASA Astrophysics Data System (ADS)

Hara, Hidetoshi; Kunii, Miyuki; Miyake, Yoshihiro; Hisada, Ken-ichiro; Kamata, Yoshihito; Ueno, Katsumi; Kon, Yoshiaki; Kurihara, Toshiyuki; Ueda, Hayato; Assavapatchara, San; Treerotchananon, Anuwat; Charoentitirat, Thasinee; Charusiri, Punya

2017-09-01

Provenance analysis and U-Pb dating of detrital zircons in Permian-Triassic forearc sediments from the Sukhothai Arc in northern Thailand clarify the evolution of a missing arc system associated with Paleo-Tethys subduction. The turbidite-dominant formations within the forearc sediments include the Permian Ngao Group (Kiu Lom, Pha Huat, and Huai Thak formations), the Early to earliest Late Triassic Lampang Group (Phra That and Hong Hoi formations), and the Late Triassic Song Group (Pha Daeng and Wang Chin formations). The sandstones are quartzose in the Pha Huat, Huai Thak, and Wang Chin formations, and lithic wacke in the Kiu Lom, Phra That, Hong Hoi and Pha Daeng formations. The quartzose sandstones contain abundant quartz, felsic volcanic and plutonic fragments, whereas the lithic sandstones contain mainly basaltic to felsic volcanic fragments. The youngest single-grain (YSG) zircon U-Pb age generally approximates the depositional age in the study area, but in the case of the limestone-dominant Pha Huat Formation the YSG age is clearly older. On the other hand, the youngest cluster U-Pb age (YC1σ) represents the peak of igneous activity in the source area. Geological evidence, geochemical signatures, and the YC1σ ages of the sandstones have allowed us to reconstruct the Sukhothai arc evolution. The initial Sukhothai Arc (Late Carboniferous-Early Permian) developed as a continental island arc. Subsequently, there was general magmatic quiescence with minor I-type granitic activity during the Middle to early Late Permian. In the latest Permian to early Late Triassic, the Sukhothai Arc developed in tandem with Early to Middle Triassic I-type granitic activity, Middle to Late Triassic volcanism, evolution of an accretionary complex, and an abundant supply of sediments from the volcanic rocks to the trench through a forearc basin. Subsequently, the Sukhothai Arc became quiescent as the Paleo-Tethys closed after the Late Triassic. In addition, parts of sediments of supposed Devonian-Carboniferous age within the Sukhothai Arc were revised as the Triassic Lampang Group, and the Early Cretaceous Khorat Group.

Devonian to Carboniferous collision in the Greenland Caledonides: U-Pb zircon and Sm-Nd ages of high-pressure and ultrahigh-pressure metamorphism

NASA Astrophysics Data System (ADS)

Gilotti, Jane A.; Nutman, Allen P.; Brueckner, Hannes K.

2004-10-01

A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) 206Pb/238U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic 207Pb/206Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th/U values than the HP ones, no Eu anomaly, and are thus comparable to UHP zircons in the literature. The 206Pb/238U age of these zircons is 360±5 Ma, much younger than the HP eclogites. The same sample gives a Sm-Nd age of 342±6 Ma. Unlike the HP eclogites, the Sm-Nd age of the UHP rock is ca. 20 Ma younger than the U-Pb zircon age and most likely records slow cooling through the closure temperature, since peak temperatures were in excess of 900°C. Widespread HP metamorphism of both the Laurentian and Baltica continental margins marks the culmination of this continent continent collision in the Devonian. Carboniferous UHP conditions, though localized in the east, suggest a prolonged collisional history rather than a short-lived Scandian orogeny. The traditional Silurian Scandian orogeny should thus be extended through the Devonian.

Geodynamic interpretation of the 40Ar/39Ar dating of ophiolitic and arc-related mafics and metamafics of the northern part of the Anadyr-Koryak region

USGS Publications Warehouse

Palandzhyan, S.A.; Layer, P.W.; Patton, W.W.; Khanchuk, A.I.

2011-01-01

Isotope datings of amphibole-bearing mafics and metamafics in the northern part of the Anadyr-Koryak region allow clarification of the time of magmatic and metamorphic processes, which are synchronous with certain stages of the geodynamic development of the northwest segment of the Pacific mobile belt in the Phanerozoic. To define the 40Ar/39Ar age of amphiboles, eight samples of amphibole gabbroids and metamafics were selected during field work from five massifs representing ophiolites and mafic plutons of the island arc. Rocks from terranes of three foldbelts: 1) Pekulnei (Chukotka region), 2) Ust-Belaya (West Koryak region), and 3) the Tamvatnei and El'gevayam subterranes of the Mainits terrane (Koryak-Kamchatka region), were studied. The isotope investigations enabled us to divide the studied amphiboles into two groups varying in rock petrographic features. The first was represented by gabbroids of the Svetlorechensk massif of the Pekulnei Range and by ophiolites of the Tamvatnei Mts.; their magmatic amphiboles show the distribution of argon isotopes in the form of clearly distinguished plateau with an age ranging within 120-129 Ma. The second group includes metamorphic amphiboles of metagabbroids and apogabbro amphibolites of the Ust-Belaya Mts., Pekulnei and Kenkeren ranges (El'gevayam subterranes). Their age spectra show loss of argon and do not provide well defined plateaus the datings obtained for them are interpreted as minimum ages. Dates of amphiboles from the metagabbro of the upper tectonic plate of the Ust-Belaya allochthon points to metamorphism in the suprasubduction environment in the fragment of Late Neoproterozoic oceanic lithosphere in Middle-Late Devonian time, long before the Uda-Murgal island arc system was formed. The amphibolite metamorphism in the dunite-clinopyroxenite-metagabbro Pekulnei sequence was dated to occur at the Permian-Triassic boundary. The age of amphiboles from gabbrodiorites of the Kenkeren Range was dated to be Early Jurassic that confirmed their assignment to the El'gevayam volcanic-plutonic assemblage. These data are consistent with geological concepts and make more precise the available age dates. Neocomian-Aptian 40Ar/39Ar age of amphibolites from the Pekulnei and Tamvatnei gabbroids make evident that mafics of these terranes (varying in geodynamic formation settings and in petrogenesis) were generated in later stages of the development of the West Pekulnei and Mainits-Algan Middle-Late Jurassic-Early Cretaceous island arc systems, presumably due to breakup of island arcs in the Neocomian. ?? 2011 Pleiades Publishing, Ltd.

Late Proterozoic-Paleozoic evolution of the Arctic Alaska-Chukotka terrane based on U-Pb igneous and detrital zircon ages: Implications for Neoproterozoic paleogeographic reconstructions

USGS Publications Warehouse

Amato, J.M.; Toro, J.; Miller, E.L.; Gehrels, G.E.; Farmer, G.L.; Gottlieb, E.S.; Till, A.B.

2009-01-01

The Seward Peninsula of northwestern Alaska is part of the Arctic Alaska-Chukotka terrane, a crustal fragment exotic to western Laurentia with an uncertain origin and pre-Mesozoic evolution. U-Pb zircon geochronology on deformed igneous rocks reveals a previously unknown intermediate-felsic volcanic event at 870 Ma, coeval with rift-related magmatism associated with early breakup of eastern Rodinia. Orthogneiss bodies on Seward Peninsula yielded numerous 680 Ma U-Pb ages. The Arctic Alaska-Chukotka terrane has pre-Neoproterozoic basement based on Mesoproterozoic Nd model ages from both 870 Ma and 680 Ma igneous rocks, and detrital zircon ages between 2.0 and 1.0 Ga in overlying cover rocks. Small-volume magmatism occurred in Devonian time, based on U-Pb dating of granitic rocks. U-Pb dating of detrital zircons in 12 samples of metamorphosed Paleozoic siliciclastic cover rocks to this basement indicates that the dominant zircon age populations in the 934 zircons analyzed are found in the range 700-540 Ma, with prominent peaks at 720-660 Ma, 620-590 Ma, 560-510 Ma, 485 Ma, and 440-400 Ma. Devonian- and Pennsylvanian-age peaks are present in the samples with the youngest detrital zircons. These data show that the Seward Peninsula is exotic to western Laurentia because of the abundance of Neoproterozoic detrital zircons, which are rare or absent in Lower Paleozoic Cordilleran continental shelf rocks. Maximum depositional ages inferred from the youngest detrital age peaks include latest Proterozoic-Early Cambrian, Cambrian, Ordovician, Silurian, Devonian, and Pennsylvanian. These maximum depositional ages overlap with conodont ages reported from fossiliferous carbonate rocks on Seward Peninsula. The distinctive features of the Arctic Alaska-Chukotka terrane include Neoproterozoic felsic magmatic rocks intruding 2.0-1.1 Ga crust overlain by Paleozoic carbonate rocks and Paleozoic siliciclastic rocks with Neoproterozoic detrital zircons. The Neoproterozoic ages are similar to those in the peri-Gondwanan Avalonian-Cadomian arc system, the Timanide orogen of Baltica, and other circum-Arctic terranes that were proximal to Arctic Alaska prior to the opening of the Amerasian basin in the Early Cretaceous. Our Neoproterozoic reconstruction places the Arctic Alaska-Chukotka terrane in a position near Baltica, northeast of Laurentia, in an arc system along strike with the Avalonian-Cadomian arc terranes. Previously published faunal data indicate that Seward Peninsula had Siberian and Laurentian links by Early Ordovician time. The geologic links between the Arctic Alaska-Chukotka terrane and eastern Laurentia, Baltica, peri-Gondwanan arc terranes, and Siberia from the Paleoproterozoic to the Paleozoic help to constrain paleogeographic models from the Neoproterozoic history of Rodinia to the Mesozoic opening of the Arctic basin. ?? 2009 Geological Society of America.

Tentaculate fossils from the Cambrian of Canada (British Columbia) and China (Yunnan) interpreted as primitive deuterostomes.

PubMed

Caron, Jean-Bernard; Conway Morris, Simon; Shu, Degan

2010-03-08

Molecular and morphological evidence unite the hemichordates and echinoderms as the Ambulacraria, but their earliest history remains almost entirely conjectural. This is on account of the morphological disparity of the ambulacrarians and a paucity of obvious stem-groups. We describe here a new taxon Herpetogaster collinsi gen. et sp. nov. from the Burgess Shale (Middle Cambrian) Lagerstätte. This soft-bodied vermiform animal has a pair of elongate dendritic oral tentacles, a flexible stolon with an attachment disc, and a re-curved trunk with at least 13 segments that is directed dextrally. A differentiated but un-looped gut is enclosed in a sac suspended by mesenteries. It consists of a short pharynx, a conspicuous lenticular stomach, followed by a narrow intestine sub-equal in length. This new taxon, together with the Lower Cambrian Phlogites and more intriguingly the hitherto enigmatic discoidal eldoniids (Cambrian-Devonian), form a distinctive clade (herein the cambroernids). Although one hypothesis of their relationships would look to the lophotrochozoans (specifically the entoprocts), we suggest that the evidence is more consistent with their being primitive deuterostomes, with specific comparisons being made to the pterobranch hemichordates and pre-radial echinoderms. On this basis some of the earliest ambulacrarians are interpreted as soft-bodied animals with a muscular stalk, and possessing prominent tentacles.

Unroofing history of Late Paleozoic magmatic arcs within the ``Turan Plate'' (Tuarkyr, Turkmenistan)

NASA Astrophysics Data System (ADS)

Garzanti, E.; Gaetani, M.

2002-07-01

Stratigraphic, sedimentologic and petrographic data collected on the Kizilkaya sedimentary succession (Western Turkmenistan) demonstrate that the "Turan Plate" consists in fact of an amalgamation of Late Paleozoic to Triassic continental microblocks separated by ocean sutures. In the Kizilkaya area, an ophiolitic sequence including pyroxenite, gabbro, pillow basalt and chert, interpreted as the oceanic crust of a back-arc or intra-arc basin, is tectonically juxtaposed against volcaniclastic redbeds documenting penecontemporaneous felsic arc magmatism (Amanbulak Group). A collisional event took place around ?mid-Carboniferous times, when oceanic rocks underwent greenschist-facies metamorphism and a thick volcaniclastic wedge, with pyroclastic rocks interbedded in the lower part, accumulated (Kizilkaya Formation). The climax of orogenic activity is testified by arid fanglomerates shed from the rapid unroofing of a continental arc sequence, including Middle-Upper Devonian back-reef carbonates and cherts, and the underlying metamorphic and granitoid basement rocks (Yashmu Formation). After a short period of relative quiescence, renewed tectonic activity is indicated by a conglomeratic sequence documenting erosion of a sedimentary and metasedimentary succession including chert, sandstone, slate and a few carbonates. A final stage of rhyolitic magmatism took place during rapid unroofing of granitoid basement rocks (Kizildag Formation). Such a complex sequence of events recorded by the Kizilkaya episutural basin succession documents the stepwise assemblage of magmatic arcs and continental fragments to form the Turan microblock collage during the Late Paleozoic. Evolution of detrital modes is compatible with that predicted for juvenile to accreted and unroofed crustal blocks. The deposition of braidplain lithic arkoses in earliest Triassic time indicates that strong subsidence continued after the end of the volcanic activity, possibly in retroarc foreland basin settings. The occurrence of transgressive coquinas yielding endemic ammonoids ( Dorikranites) characteristic of the whole Caspian area suggests proximity to the southern margin of the newly formed Eurasian continent in the late Early Triassic. The Late Triassic Eo-Cimmerian Orogeny caused only mild tilting and rejuvenation of the underlying succession in the study area. Only at this time were the Turan blocks, a series of Indonesian-type terranes comprised between the Mashad Paleo-Tethys Suture in the south and the Mangyshlak belt in the north, finally incorporated into the Eurasian landmass.

Discovering Fossils--A Hands-on Lab.

ERIC Educational Resources Information Center

Goldstein, Alan

2002-01-01

Describes fossil investigations developed and provided by the Falls of the Ohio State Park near Louisville, Kentucky. The Devonian shale beds contain representatives of over 600 species including corals, sponges, brachiopods, mollusks, and echinoderms. Rather than focusing on identification, the activities emphasize the past ecological…

Geochemical Evidence for Possible Natural Migration of Marcellus Formation Brine to Shallow Aquifers in Pennsylvania

NASA Astrophysics Data System (ADS)

Warner, N. R.; Darrah, T. H.; Jackson, R. B.; Osborn, S.; Down, A.; Vengosh, A.

2012-12-01

The acceleration in production of natural gas from shale formations through horizontal drilling and hydraulic fracturing has altered the landscape of domestic energy production in the USA. Yet shale gas exploration has generated an increased awareness of risks to drinking water quality amid concerns for the possible migration of stray gas or hydraulic fracturing fluid and/or flowback brine to shallow drinking water aquifers. The degree to which shallow drinking water is at risk from hydraulic fracturing could depend upon the hydraulic connectivity between the shale gas formations and the surface. In this study, we analyzed the geochemistry of over 400 water samples located across six counties of northeastern Pennsylvania in the three principle aquifers, two Upper Devonian Age bedrock aquifers (Catskill and Lock Haven) and one Quaternary Age (Alluvium) that overlie the Marcellus Formation. Based on a detailed analysis of major (Br, Cl, Na, Mg, Ba, and Sr) and trace (Li) element geochemistry, coupled with utilization of a specific spectrum of isotopic tracers (87Sr/86Sr, 228Ra/ 226Ra, 2H/H, 18O/16O), we identify a salinized (Cl> 20 mg/L) shallow groundwater type which suggests conservative mixing relationships between fresh shallow groundwater and an underlying brine. Identification of the brine source is complicated as many of the brines in the northern Appalachian Basin likely share a common origin as the expelled remnants of the formation of the Silurian Salina evaporate deposits. To determine the ultimate source of the diluted brine we compared the observed geochemistry to over 80 brines produced from northern Appalachian Basin formations. The shallow salinized groundwater most closely resembles diluted produced water from the Middle Devonian Marcellus Formation. The 18O/16O and 2H/H of the salinized groundwater indicate that the brine is likely diluted with post-glacial (<10,000 ybp) meteoric water. Combined, these data indicate that hydraulic connections allowed cross formational migration of brine from deeper formations (1-2 kilometers below ground surface) and subsequent dilution. The occurrence of the saline water does not appear to be correlated with the location of shale-gas wells. Also, salinized groundwater with similar major element chemistry was reported prior to the most recent shale-gas development in the region. The source of the salinized water is likely not the recent drilling and hydraulic fracturing; instead brine migrated into the shallow aquifers and was recently diluted through natural pathways and processes. However, the presence of natural hydraulic connections to deeper formations suggests specific structural and hydrodynamic regimes in northeastern Pennsylvania where shallow drinking water resources are at greater risk of contamination, particularly with fugitive gases, during drilling and hydraulic fracturing of shale gas. The severity of the risk could depend upon the presence of pathways that allow the migration of fluids into the shallow aquifers on human time scales.

Precambrian Continent Arctida: A New Kinematic Reconstruction of Late Precambrian - Early Paleozoic Arctida U Europe (baltia) Collision

NASA Astrophysics Data System (ADS)

Borisova, T. P.; Guertseva, M. V.; Egorov, A. Ju.; Kononov, M. V.; Kouznetsov, N. B.

In according to L.P.Zonenshain and L.M.Natapov (1988, 1990), different size conti- nental blocks locating at the margins and inside of present-day Arctic ocean composed the hypothetical early Paleozoic paleocontinent Arctida. The blocks are Kara block (north part of Taymir peninsula, Severnaja Zemlja archipelago and Franz Joseph Land archipelago), north part of Alaska (northward Bruks ridge), Chukchi block, Novosi- birsky block (Novosibirskiye islands together their shelves), several fragments north- ward to the Innuitian orogen (north parts of Peary Land and Ellesmere Island), and Lomonosov ridgeSs block. In the previous kinematic reconstruction it was believed that Arctida as a whole collided with north flanks of Laurentia (Innuitian margin) and Europe (Baltia, Barentsia margin) in middle Paleozoic time. Later, the Arctida (been a fragment of supercontinent Pangea) was fragmented due to a spreading in the Arctic ocean and north part of Atlantic ocean in late Mesozoic and Cenozoic times. Then ArctidaSs fragments were accreted to the Eurasia and North America conti- nents. During the last decade "AEROGEOLOGIA" company has been gathered new data (geologic, stratigraphical, paleomagnetic, and others) of Russian Arctic sector and Svalbard. The data were summarized into "Paleogeographical Atlas for the Rus- sian Arctic sector and Svalbard from Vendian to Jurassic times" (see Abstact SE1.04, ID-NR: EGS02-A-02453). An analyzing of the maps for Vend and Cambrian times allows us to reconsider a few stages of kinematic scenario of late Precambrian - early Paleozoic Arctida U Europe collision. 1) Old interpretation: Arctida was considered as an isolated paleocontinent during early Paleozoic time. New interpretation: during the early Paleozoic Arctida together Europe (Baltia) were assembled into a paleo- continent named us Arcteurope. This conclusion is based on excellent coincidence of Paleozoic paleomagnetic poles of the Kara block (which is a part of Arctida) and Europe (Baltia). 2) Old interpretation: the dextral Kara-Barents shear zone was con- sidered as Europe (Baltia) U Arctida late Devonian suture zone. New interpretation: A collision of Europe (Baltia) and Arctida occurred about the time boundary between Vend and Cambrian times on the Timan suture zone. Time of the collision marked 1 by the Cambrian granitoids of the Timan ridge and west slope of North Urals. 3). Old interpretation: During late Precambrian times Barentsia sialic block was believed as an isolated microcontinent, been accreted to the Europe (Baltia) in the latest Ven- dian time. New interpretation: Barentsia sialic block was a part of Arctida during late Precambrian time. 2

Temporal correlation between dyke swarms and crustal extension in the middle Palaeozoic Vilyui rift basin, Siberian platform

NASA Astrophysics Data System (ADS)

Polyansky, Oleg P.; Prokopiev, Andrei V.; Koroleva, Olga V.; Tomshin, Mikhail D.; Reverdatto, Vladimir V.; Selyatitsky, Alexander Yu.; Travin, Alexei V.; Vasiliev, Dmitry A.

2017-06-01

This paper presents results from new 40Ar/39Ar isotope dating of nine mafic dykes from three large dyke swarms (Vilyui-Markha, Kontai-Dzherba, and Chara-Sinsk) of the Yakutsk-Vilyui large igneous province (LIP), in addition to a reconstruction of the subsidence history of the middle Palaeozoic Vilyui paleorift basin (eastern Siberian platform). All previously published 40Ar/39Ar and U-Pb dates are summarized. Statistical analysis of the dyke ages reveals repeated magmatic events in the study area. Two major pulses of mafic magmatism are identified: one at the Frasnian-Famennian boundary, with a main peak at ca. 374.1 Ma, and another in the latest Devonian with a peak at ca. 363.4 Ma. The time of maximum intensity of dyke intrusion coincides (within uncertainty) with rapid subsidence in the Vilyui basin. The minimum total volume of middle Palaeozoic magmatism produced in the Yakutsk-Vilyui LIP is 100-215 K km3, which is much less than earlier estimates. Most of the mafic material within the Yakutsk-Vilyui LIP is related to the Vilyui basin and associated dyke swarms. Backstripping analysis of sedimentation in depressions of the Vilyui basin was carried out. Estimates were obtained for the spatial distribution of the stretching factor of the crust and mantle lithosphere, averaging 1.17 and 1.44, respectively. The amount of extension due to dyke intrusion is estimated to be 6%. Backstripping analysis of sedimentation in the Vilyui basin was used to assess the effect of both intraplate far-field forces and upwelling magma flows initiated by a mantle plume. A numerical thermomechanical model was developed to investigate the relations between two possible mechanisms by which the Vilyui rift was initiated: intraplate extension (passive rifting) and the ascent of a mantle magmatic diapir (active rifting). A model considering both of these mechanisms shows the contribution of the far-field extension forces and the effect of convective flows around the mantle plume, assuming a temperature of 1500 °C for a heat source operating for ≥ 10 Myr. The best-fit model predicts the formation of the Vilyui basin under extensional conditions with a depth-integrated horizontal driving force of 2.0 × 1013 N/m, which corresponds to a lithostatic pressure of 0.73. Appendix B. Numerical model; Appendix C, Table S1. Major and trace element average data for reference materials W-1, JB-3 and internal standard ST-1A. Table S2. Laboratory precision (Diamond and Precious Metal Geology Institute, Siberian Branch of Russian Academy of Sciences). Table S3. Chemical composition of plagioclase from samples dated in this work. Table S4. Chemical composition of clinopyroxene from samples dated in this work.

Geochemistry, palynology, and regional geology of worldclass Upper Devonian source rocks in the Madre de Dios basin, Bolivia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, K.E.; Conrad, K.T.; Carpenter, D.G.

Recent exploration drilling indicates the existence of world-class source rock in the Madre de Dios basin, Bolivia. In the Pando-1 X and -2X wells, over 200 m of poorly bioturbated, organic-rich (TOC = 3-16 wt.%) prodelta to shelf mudstones in the Frasnian-Famennian Tomachi Formation contain oil-prone organic matter (hydrogen index = 400-600 mg HC/g TOC). Our calculated source prolificity indices for this interval in these wells (SPI = 15-18 tons of hydrocarbons per square meter of source rock) exceed that for the Upper Jurassic in Central Saudi Arabia. The Tomachi interval is lithologically equivalent to the Colpacucho Formation in themore » northern Altiplano, the Iquiri Formation in the Cordillera Oriental, and is coeval with other excellent source rocks in North America, Africa, and Eurasia. All of these rocks were deposited under conditions favorable for accumulation of organic matter, including a global highstand and high productivity. However, the Madre de Dios basin was situated at high latitude during the Late Devonian and some of the deposits are interpreted to be of glacial origin, indicating conditions not generally associated with organic-rich deposition. A biomarker and palynological study of Upper Devonian rocks in the Pando-1X well suggests deposition under conditions similar to certain modern fjords. High productivity resulted in preservation of abundant organic matter in the bottom sediments despite a cold, toxic water column. Low-sulfur crude oil produced from the Pando-1X well is geochemically similar to, but more mature than, extracts from associated organic-rich Tomachi samples, and was generated from deeper equivalents of these rocks.« less

Microbes and mass extinctions: paleoenvironmental distribution of microbialites during times of biotic crisis.

PubMed

Mata, S A; Bottjer, D J

2012-01-01

Widespread development of microbialites characterizes the substrate and ecological response during the aftermath of two of the 'big five' mass extinctions of the Phanerozoic. This study reviews the microbial response recorded by macroscopic microbial structures to these events to examine how extinction mechanism may be linked to the style of microbialite development. Two main styles of response are recognized: (i) the expansion of microbialites into environments not previously occupied during the pre-extinction interval and (ii) increases in microbialite abundance and attainment of ecological dominance within environments occupied prior to the extinction. The Late Devonian biotic crisis contributed toward the decimation of platform margin reef taxa and was followed by increases in microbialite abundance in Famennian and earliest Carboniferous platform interior, margin, and slope settings. The end-Permian event records the suppression of infaunal activity and an elimination of metazoan-dominated reefs. The aftermath of this mass extinction is characterized by the expansion of microbialites into new environments including offshore and nearshore ramp, platform interior, and slope settings. The mass extinctions at the end of the Triassic and Cretaceous have not yet been associated with a macroscopic microbial response, although one has been suggested for the end-Ordovician event. The case for microbialites behaving as 'disaster forms' in the aftermath of mass extinctions accurately describes the response following the Late Devonian and end-Permian events, and this may be because each is marked by the reduction of reef communities in addition to a suppression of bioturbation related to the development of shallow-water anoxia. © 2011 Blackwell Publishing Ltd.

Novel reef fabrics from the Devonian Canning Basin, Western Australia

NASA Astrophysics Data System (ADS)

Wood, Rachel

1998-11-01

Large cement-filled cavities (0.2 to 1.5 m wide) are well developed in slope-margin sediments of the spectacular Upper Devonian (Frasnian) reefs of the Canning Basin, Western Australia, where they account for up to 50% of the primary porosity. These are here interpreted as primary reef framework cavities that formed beneath a variety of domal, tabular or laminar stromatoporoid sponges. Of particular note are those created by unusual, very thin (2 to 8 mm), laminar stromatoporoids (mainly Stachyodes australe), that formed arching, hollow domes up to 0.3 m in height and 1.5 m in diameter over the sediment surface to enclose flat-based cavities. The free undersurface of these stromatoporoids often supported a hitherto unrecognised cryptic community, dominated by pendent growth of the putative calcified cyanobacterium Renalcis, with rare intergrown lithistid sponges and spiny atrypid brachiopods. The uneven growth surface of the cryptos imparts an irregular, stromatactis-like texture to the upper surface of the remaining cavity, which is filled by early marine, finely banded, fibrous cements (mainly radiaxial calcite) interbedded with often multiple generations of geopetal sediment containing peloids and ostracod debris. This ecology yields the tabular stromatoporoid- Renalcis fabric described ubiquitously from the Canning Basin reef complex. Such unusual reef fabrics are a consequence of the ecology of shallow marine mid-Palaeozoic reefs which were quite unlike that of modern coral reefs. The frequent preservation of relatively delicate, in situ communities was due to (1) rapid and pervasive early cementation, (2) growth under non-energetic conditions, and (3) the relative insignificance of bioeroders associated with reefs at this time.

Productivity Contribution of Paleozoic Woodlands to the Formation of Shale-Hosted Massive Sulfide Deposits in the Iberian Pyrite Belt (Tharsis, Spain)

NASA Astrophysics Data System (ADS)

Fernández-Remolar, David C.; Harir, Mourad; Carrizo, Daniel; Schmitt-Kopplin, Philippe; Amils, Ricardo

2018-03-01

The geological materials produced during catastrophic and destructive events are an essential source of paleobiological knowledge. The paleobiological information recorded by such events can be rich in information on the size, diversity, and structure of paleocommunities. In this regard, the geobiological study of late Devonian organic matter sampled in Tharsis (Iberian Pyrite Belt) provided some new insights into a Paleozoic woodland community, which was recorded as massive sulfides and black shale deposits affected by a catastrophic event. Sample analysis using TOF-SIMS (Time of Flight Secondary Ion Mass Spectrometer), and complemented by GC/MS (Gas Chromatrograph/Mass Spectrometer) identified organic compounds showing a very distinct distribution in the rock. While phytochemical compounds occur homogeneously in the sample matrix that is composed of black shale, the microbial-derived organics are more abundant in the sulfide nodules. The cooccurrence of sulfur bacteria compounds and the overwhelming presence of phytochemicals provide support for the hypothesis that the formation of the massive sulfides resulted from a high rate of vegetal debris production and its oxidation through sulfate reduction under suboxic to anoxic conditions. A continuous supply of iron from hydrothermal activity coupled with microbial activity was strictly necessary to produce this massive orebody. A rough estimate of the woodland biomass was made possible by accounting for the microbial sulfur production activity recorded in the metallic sulfide. As a result, the biomass size of the late Devonian woodland community was comparable to modern woodlands like the Amazon or Congo rainforests.

18 CFR 270.101 - General definitions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...

18 CFR 270.101 - General definitions.

Code of Federal Regulations, 2012 CFR

2012-04-01

... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...

18 CFR 270.101 - General definitions.

Code of Federal Regulations, 2013 CFR

2013-04-01

... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...

18 CFR 270.101 - General definitions.

Code of Federal Regulations, 2010 CFR

2010-04-01

... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...

18 CFR 270.101 - General definitions.

Code of Federal Regulations, 2014 CFR

2014-04-01

... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...

Publications - PIR 2004-3 | Alaska Division of Geological & Geophysical

Science.gov Websites

) Keywords Alaska, State of; Alluvial Deposits; Amy Creek Assemblage; Amy Dolomite; Ar-Ar; Bison Fossils ; Cambrian; Caribou Fossils; Cascaden Ridge Unit; Cenozoic; Colluvial Deposits; Cretaceous; Devonian ; Engineering Geology; Eolian; Fox Fossils; Geochemistry; Geochronology; Geologic Hazards; Geologic Materials

Organic content of Devonian shale in western Appalachian basin.

USGS Publications Warehouse

Schmoker, J.W.

1980-01-01

In the organic-rich facies of the Devonian shale in the western part of the Appalachian basin, the distribution of organic matter provides an indirect measure of both gas in place and the capacity of the shale to supply gas to permeable pathways.The boundary between organic-rich ('black') and organic-poor ('gray') facies is defined here as 2% organic content by volume. The thickness of organic-rich facies ranges from 200ft in central Kentucky to 1000ft along the Kentucky-West Virginia border. The average content of the organic-rich facies increases from 5% by volume on the edge to 16% in central Kentucky. The net thickness of organic matter in the organic-rich facies shows the amount of organic material in the shale, and is the most fundamental of the organic-content characterizations. Net thickness of organic matter ranges between 20 and 80ft (6.1 and 24.4m) within the mapped area.-from Author

A study of secondary fabrics in rocks from the lizard Peninsula and adjacent areas in southwest cornwall, england

NASA Astrophysics Data System (ADS)

Rathore, Jaswant Singh

1980-09-01

Magnetic susceptibility anisotropy techniques were applied to samples taken in selected areas of the Lizard Peninsula in order to study secondary fabrics due to: (1) the intrusion of granites into sediments; (2) the compression in the sediments to the north of the Lizard thrust boundary; and (3) the intrusion of serpentine into hornblende schists of the Lizard metamorphic block. The magnetic fabric around the Carnmenellis and Godolphin granite masses shows a strong compressional fabric, tending to suggest that the Devonian sediments were compressed radially as the granites intruded them. The high degree of anisotropy observed at the Lizard boundary falls, with increasing distance from the thrust, systematically down to low values in the Devonian sediments. The distinct changes in the fabric parameters at the north end of Church Cove-Landewednack and the southern end of Cadgwith Cove appear to be the remnant secondary fabrics due to the intrusion of serpentine into hornblende schists.

A resource evaluation of the Bakken Formation (Upper Devonian and Lower Mississippian) continuous oil accumulation, Williston Basin, North Dakota and Montana

USGS Publications Warehouse

Schmoker, J.W.

1996-01-01

The Upper Devonian and Lower Mississippian Bakken Formation in the United States portion of the Williston Basin is both the source and the reservoir for a continuous oil accumulation - in effect a single very large field - underlying approximately 17,800 mi2 (46,100 km2) of North Dakota and Montana. Within this area, the Bakken Formation continuous oil accumulation is not significantly influenced by the water column and cannot be analyzed in terms of conventional, discrete fields. Rather, the continuous accumulation can be envisioned as a collection of oil-charged cells, virtually all of which are capable of producing some oil, but which vary significantly in their production characteristics. Better wellperformance statistics are linked regionally to higher levels of thermal maturity and to lower levels of reservoir heterogeneity. Although portions of the Bakken Formation continuous oil accumulation have reached a mature stage of development, the accumulation as a whole is far from depleted.

Enhanced recovery of unconventional gas. Volume II. The program. [Tight gas basins; Devonian shale; coal seams; geopressured aquifers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuuskraa, V.A.; Brashear, J.P.; Doscher, T.M.

1978-10-01

This study was conducted to assist public decision-makers in selecting among many choices to obtain new gas supplies by addressing 2 questions: 1) how severe is the need for additional future supplies of natural gas, and what is the economic potential of providing part of future supply through enhanced recovery from unconventional natural gas resources. The study also serves to assist the DOE in designing a cost-effective R and D program to stimulate industry to recover this unconventional gas and to produce it sooner. Tight gas basins, Devonian shale, methane from coal seams, and methane from geopressured aquifers are considered.more » It is concluded that unconventional sources, already providing about 1 Tcf per year, could provide from 3 to 4 Tcf in 1985 and from 6 to 8 Tcf in 1990 (at $1.75 and $3.00 per Mcf, respectively). However, even with these additions to supply, gas supply is projected to remain below 1977 usage levels. (DLC)« less

Parental Sources of High-Alumina Alkaline Melts: Nd, Sr, Pb, and O Isotopic Evidence from the Devonian Kiya-Shaltyr Gabbro-Urtite Intrusion, South Siberia

NASA Astrophysics Data System (ADS)

Vrublevskii, V. V.; Gertner, I. F.; Chugaev, A. V.

2018-04-01

The isotope geochemistry (ɛNd( t) 4.8-5.4, 206Pb/204Pb in 18.05-18.36, 207Pb/204Pbin 15.53-15.57, 208Pb/204Pb in 37.59-37.83, 87Sr/86Sr( t) 0.7048-0.7057, δ18OSMOW 8-10.5‰) and trace element composition of the Kiya-Shaltyr gabbro-urtite pluton allow us to suggest a heterogeneous source and complex geodynamic settings of the Devonian alkali magmatism in the Kuznetsk Alatau. It is assumed that its evolution took place under conditions of partial mingling of matter of the depleted (PREMA) and enriched (EM) mantle with crustal contamination of the evolving melt. Such an interaction could have been a result of superposition of a mantle plume and an active margin (OIB and IAB components). In fold belts this led to the formation of hybrid high-alumina foidoite magmas.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

To evaluate the potential of the Devonian shale as a source of natural gas, the US Department of Energy (DOE) has undertaken the Eastern Gas Shales Project (EGSP). The EGSP is designed not only to identify the resource, but also to test improved methods of inducing permeability to facilitate gas drainage, collection, and production. The ultimate goal of this project is to increase the production of gas from the eastern shales through advanced exploration and exploitation techniques. The purpose of this report is to inform the general public and interested oil and gas operators about EGSP results as they pertainmore » to the Devonian gas shales of the Appalachian basin in Pennsylvania. Geologic data and interpretations are summarized and areas where the accumulation of gas may be large enough to justify commercial production are outlined. Because the data presented in this report are generalized and not suitable for evaluation of specific sites for exploration, the reader should consult the various reports cited for more detail and discussion of the data, concepts, and interpretations presented.« less

New porcellioidean gastropods from early Devonian of Royal Creek area, Yukon Territory, Canada, with notes on their early phylogeny

USGS Publications Warehouse

Fryda, J.; Blodgett, R.B.; Lenz, A.C.; Manda, S.

2008-01-01

This paper presents a description of new gastropods belonging to the superfamily Porcellioidea (Vetigastropoda) from the richly diverse Lower Devonian gastropod fauna of the Road River Formation in the Royal Creek area, Yukon Territory. This fauna belongs to Western Canada Province of the Old World Realm. The Pragian species Porcellia (Porcellia) yukonensis n. sp. and Porcellia (Paraporcellia) sp. represent the oldest presently known members of subgenera Porcellia (Porcellia) and Porcellia (Paraporcellia). Their simple shell ornamentation fits well with an earlier described evolutionary trend in shell morphology of the Porcellinae. Late Pragian to early Emsian Perryconcha pulchra n. gen. and n. sp. is the first member of the Porcellioidea bearing a row of tremata on adult teleoconch whorls. The occurrence of this shell feature in the Porcellioidea is additional evidence that the evolution of the apertural slit was much more complicated than has been proposed in classical models of Paleozoic gastropod evolution. Copyright ?? 2008, The Paleontological Society.

Questioning hagfish affinities of the enigmatic Devonian vertebrate Palaeospondylus

NASA Astrophysics Data System (ADS)

Johanson, Zerina; Smith, Moya; Sanchez, Sophie; Senden, Tim; Trinajstic, Kate; Pfaff, Cathrin

2017-07-01

Palaeospondylus gunni Traquair, 1890 is an enigmatic Devonian vertebrate whose taxonomic affinities have been debated since it was first described. Most recently, Palaeospondylus has been identified as a stem-group hagfish (Myxinoidea). However, one character questioning this assignment is the presence of three semicircular canals in the otic region of the cartilaginous skull, a feature of jawed vertebrates. Additionally, new tomographic data reveal that the following characters of crown-group gnathostomes (chondrichthyans + osteichthyans) are present in Palaeospondylus: a longer telencephalic region of the braincase, separation of otic and occipital regions by the otico-occipital fissure, and vertebral centra. As well, a precerebral fontanelle and postorbital articulation of the palatoquadrate are characteristic of certain chondrichthyans. Similarities in the structure of the postorbital process to taxa such as Pucapampella, and possible presence of the ventral cranial fissure, both support a resolution of Pa. gunni as a stem chondrichthyan. The internally mineralized cartilaginous skeleton in Palaeospondylus may represent a stage in the loss of bone characteristic of the Chondrichthyes.

The hyper-enrichment of V and Zn in black shales of the Late Devonian-Early Mississippian Bakken Formation (USA)

USGS Publications Warehouse

Scott, Clinton T.; Slack, John F.; Kelley, Karen Duttweiler

2017-01-01

Black shales of the Late Devonian to Early Mississippian Bakken Formation are characterized by high concentrations of organic carbon and the hyper-enrichment (> 500 to 1000s of mg/kg) of V and Zn. Deposition of black shales resulted from shallow seafloor depths that promoted rapid development of euxinic conditions. Vanadium hyper-enrichments, which are unknown in modern environments, are likely the result of very high levels of dissolved H2S (~ 10 mM) in bottom waters or sediments. Because modern hyper-enrichments of Zn are documented only in Framvaren Fjord (Norway), it is likely that the biogeochemical trigger responsible for Zn hyper-enrichment in Framvaren Fjord was also present in the Bakken basin. With Framvaren Fjord as an analogue, we propose a causal link between the activity of phototrophic sulfide oxidizing bacteria, related to the development of photic-zone euxinia, and the hyper-enrichment of Zn in black shales of the Bakken Formation.

Assessing Data Accuracy When Involving Students in Authentic Paleontological Research.

ERIC Educational Resources Information Center

Harnik, Paul G.; Ross, Robert M.

2003-01-01

Regards Student-Scientist Partnerships (SSPs) as beneficial collaborations for both students and researchers. Introduces the Paleontological Research Institution (PRI), which developed and pilot tested an SSP that involved grade 4-9 students in paleontological research on Devonian marine fossil assemblages. Reports formative data assessment and…

Publications - PIR 2004-3A | Alaska Division of Geological & Geophysical

Science.gov Websites

; Bedrock; Bedrock Geology; Cambrian; Caribou Fossils; Cascaden Ridge Unit; Cenozoic; Colluvial Deposits ; Cretaceous; Devonian; Eolian; Fox Fossils; Generalized; Geochemistry; Geochronology; Geologic Map; Geology ; Holocene; Horse Fossils; Igneous Rocks; K-Ar; Livengood Bench; Livengood Dome Chert; Lost Creek Unit

Metals in Devonian kerogenous marine strata at Gibellini and Bisoni properties in southern Fish Creek Range, Eureka County, Nevada

USGS Publications Warehouse

Desborough, George A.; Poole, F.G.; Hose, R.K.; Radtke, A.S.

1979-01-01

A kerogen-rich sequence of siliceous mudstone, siltstone, and chert as much as 60 m thick on ridge 7129 in the southern Fish Creek Range, referred to as Gibellini facies of the Woodruff Formation, has been evaluated on the surface and in drill holes principally for its potential resources of vanadium, zinc, selenium, molybdenum, and syncrude oil content. The strata are part of a strongly deformed allochthonous mass of eugeosynclinal Devonian marine rocks that overlie deformed allochthonous Mississippian siliceous rocks and relatively undeformed autochthonous Mississippian Antler flysch at this locality. The vanadium in fresh black rocks obtained from drill holes and fresh exposures in trenches and roadcuts occurs chiefly in organic matter. Concentrations of vanadium oxide (V2O5) in unoxidized samples range from 3,000 to 7,000 ppm. In oxidized and bleached rock that is prevalent at the surface, concentrations of vanadium oxide range from 6,000 to 8,000 ppm, suggesting a tendency toward enrichment due to surficial weathering and ground-water movement. Zinc occurs in sphalerite, and selenium occurs in organic matter; molybdenum appears to occur both in molybdenite and in organic matter. Concentrations of zinc in unoxidized rock range from 4,000 to 18,000 ppm, whereas in oxidized rock they range from 30 to 100 ppm, showing strong depletion due to weathering. Concentrations of selenium in unoxidized rock range from 30 to 200 ppm, whereas in oxidized rock they range from 200 to 400 ppm, indicating some enrichment upon weathering. Concentrations of molybdenum in unoxidized rock range from 70 to 960 ppm, whereas in oxidized rock they range from 30 to 80 ppm, indicating strong depletion upon weathering. Most fresh black rock is low-grade oil shale, and yields as much as 12 gallons/short ton of syncrude oil. Metahewettite is the principal vanadium mineral in the oxidized zone, but it also occurs sparsely as small nodules and fillings of microfractures in unweathered strata. In fresh rock, bluish-white opaline-like silica (chalcedonic quartz) fills microfractures, and is believed to have originated by diagenetic mobilization of opaline silica from radiolarian tests and sponge spicules. As revealed by microscopic study, the Gibellini facies originally consisted of siliceous muds, slimes, and oozes high in organic constituents. The organic matter is amorphous flaky and stringy sapropel, and probably includes remains of bacteria, phytoplankton, zooplankton, and minor higher plants. Recognizable organic remnants include radiolarian tests, sponge spicules, conodonts, brachiopod shells, algae, and humic debris. Diagnostic radiolarians indicate a Late Devonian age for the Gibellini facies of the Woodruff Formation. Some pyrite is disseminated through the rock and may be primary (syngenetic) but significant pyrite and marcasite occur in chalcedonic quartz veinlets and appear to be diagenetic. In fresh rock, black solid bitumen and liquid oil fill voids and microfractures. These early phase hydrocarbons probably were released during diagenesis from complex nonhydrocarbon molecular structures originating from living organisms, and formed without any major thermal degradation of the kerogen. Gas chromatographic analysis of the saturated hydrocarbon fraction indicates a very complex mixture dominated by branched and cyclic compounds. Conodont and palynomorph color alteration, vitrinite reflectance, and other organic geochemical data suggest that the organic matter in the rock is thermally immature and has not been subjected to temperatures greater than 60?C since deposition in Devonian time. All of these characteristics are consistent with the interpretation of a relatively low temperature and a shallow-burial history for the Gibellini facies on ridge 7129.

Tracing source terranes using U-Pb-Hf isotopic analysis of detrital zircons: provenance of the Orhanlar Unit of the Palaeotethyan Karakaya subduction-accretion complex, NW Turkey

NASA Astrophysics Data System (ADS)

Ustaömer, Timur; Ayda Ustaömer, Petek; Robertson, Alastair; Gerdes, Axel

2016-04-01

Sandstones of the Late Palaeozoic-Early Mesozoic Karakaya Complex are interpreted to have accumulated along an active continental margin related to northward subduction of Palaeotethys. The age of deposition and provenance of the sandstones are currently being determined using radiometric dating of detrital zircons, coupled with dating of potential source terranes. Our previous work shows that the U-Pb-Hf isotopic characteristics of the sandstones of all but one of the main tectonostratigraphic units of the Karakaya Complex are compatible with a provenance that was dominated by Triassic and Permo-Carboniferous magmatic arc-type rocks, together with a minor contribution from Lower to Mid-Devonian igneous rocks (Ustaömer et al. 2015). However, one of the tectono-stratigraphic units, the Orhanlar Unit, which occurs in a structurally high position, differs in sedimentary facies and composition from the other units of the Karakaya Complex. Here, we report new isotopic age data for the sandstones of the Orhanlar Unit and also from an extensive, associated tectonic slice of continental metamorphic rocks (part of the regional Sakarya Terrane). Our main aim is to assess the provenance of the Orhanlar Unit sandstones in relation to the tectonic development of the Karakaya Complex as a whole. The Orhanlar Unit is composed of shales, sandstone turbidites and debris-flow deposits, which include blocks of Devonian radiolarian chert and Carboniferous and Permian neritic limestones. The sandstones are dominated by rock fragments, principally volcanic and plutonic rocks of basic-to-intermediate composition, metamorphic rocks and chert, together with common quartz, feldspar and mica. This modal composition contrasts significantly with the dominantly arkosic composition of the other Karakaya Complex sandstones. The detrital zircons were dated by the U-Pb method, coupled with determination of Lu-Hf isotopic compositions using a laser ablation microprobe attached to a multicollector-inductively coupled plasma-mass spectrometer (LA-MC-ICP-MS) at Goethe University, Frankfurt. A total of 399 U-Pb spot analyses were carried out on zircons from the sandstones of the Orhanlar Unit. 84% of the data yielded Precambrian ages, which is in marked contrast with the typical arkosic sandstones of the Karakaya Complex in which Precambrian zircons form only 10% of the population. Three zircon grains of Ladinian age suggest a maximum depositional age for the Orhanlar Unit. The most prominent zircon population is of Ediacaran-Cryogenian age (31%). The second largest population is Tonian-Stenian (22%), the third largest Cryogenian-Tonian (9%) and the fourth Devonian-Carboniferous (7%). There are also minor zircon populations of Palaeoproterozoic and Neo-Archean ages. The Precambrian zircon populations in the Orhanlar Unit sandstones are identical to those in the schists of the Sakarya continental crust (P.A. Ustaömer et al. 2012; this study). Their Hf isotope compositions also overlap, suggesting that the Sakarya continental crust could be a source for the sandstones of the Orhanlar Unit. On the other hand, the Hf(t) values of most of the Devonian and Carboniferous detrital zircons differ from those of the Devonian and Carboniferous granites that intrude the Sakarya continental crust. The Karakaya Complex as a whole appears to have been derived from two different source terranes, of which the Orhanlar Unit sandstones represent a minor, but significant component. Possible explanations are that two different source terranes already existed in the same region but that these were not exposed to erosion at the same time or, if exposed simultaneously, experienced different depositional pathways (without mixing); alternatively, the Orhanar Unit represents part of a different tectono-stratigraphic terrane from the other Karakaya Complex units, with which it was tectonically amalgamated prior to Early Jurassic deposition of a common sedimentary cover. Ustaömer PA, Ustaömer T, Robertson AHF (2012), Turkish Journal of Earth Sciences, doi:10.3906/yer-1103-1 Ustaömer T, Ustaömer PA, Robertson AHF, Gerdes A (2015), International Journal of Earth Sciences, DOI 10.1007/s00531-015-1225-8. This work was supported by TUBITAK, Project no 111R015

Detrital zircon geochronology of pre- and syncollisional strata, Acadian orogen, Maine Appalachians

USGS Publications Warehouse

Bradley, Dwight C.; O'Sullivan, Paul B.

2017-01-01

The Central Maine Basin is the largest expanse of deep-marine, Upper Ordovician to Devonian metasedimentary rocks in the New England Appalachians, and is a key to the tectonics of the Acadian Orogeny. Detrital zircon ages are reported from two groups of strata: (1) the Quimby, Rangeley, Perry Mountain and Smalls Falls Formations, which were derived from inboard, northwesterly sources and are supposedly older; and (2) the Madrid, Carrabassett and Littleton Formations, which were derived from outboard, easterly sources and are supposedly younger. Deep-water deposition prevailed throughout, with the provenance shift inferred to mark the onset of foredeep deposition and orogeny. The detrital zircon age distribution of a composite of the inboard-derived units shows maxima at 988 and 429 Ma; a composite from the outboard-derived units shows maxima at 1324, 1141, 957, 628, and 437 Ma. The inboard-derived units have a greater proportion of zircons between 450 and 400 Ma. Three samples from the inboard-derived group have youngest age maxima that are significantly younger than the nominal depositional ages. The outboard-derived group does not share this problem. These results are consistent with the hypothesised provenance shift, but they signal potential problems with the established stratigraphy, structure, and (or) regional mapping. Shallow-marine deposits of the Silurian to Devonian Ripogenus Formation, from northwest of the Central Maine Basin, yielded detrital zircons featuring a single age maximum at 441 Ma. These zircons were likely derived from a nearby magmatic arc now concealed by younger strata. Detrital zircons from the Tarratine Formation, part of the Acadian foreland-basin succession in this strike belt, shows age maxima at 1615, 980 and 429 Ma. These results are consistent with three episodes of zircon recycling beginning with the deposition of inboard-derived strata of the Central Maine Basin, which were shed from post-Taconic highlands located to the northwest. Next, southeasterly parts of this succession were deformed in the Acadian orogeny, shedding detritus towards the northwest into what remained of the basin. Finally, by Pragian time, all strata in the Central Maine Basin had been deformed and detritus from this new source accumulated as the Tarratine Formation in a new incarnation of the foreland basin. Silurian-Devonian strata from the Central Maine Basin have similar detrital zircon age distributions to coeval rocks from the Arctic Alaska and Farewell terranes of Alaska and the Northwestern terrane of Svalbard. We suggest that these strata were derived from different segments of the 6500-km-long Appalachian-Caledonide orogen.

Elucidating tectonic events and processes from variably tectonized conglomerate clast detrital geochronology: examples from the Hongliuhe Formation in the southern Central Asian Orogenic Belt, NW China

NASA Astrophysics Data System (ADS)

Cleven, Nathan; Lin, Shoufa; Davis, Donald; Xiao, Wenjiao; Guilmette, Carl

2017-04-01

This work expands upon detrital zircon geochronology with a sampling and analysis strategy dating granitoid conglomerate clasts that exhibit differing degrees of internal ductile deformation. As deformation textures within clastic material reflect the variation and history of tectonization in the source region of a deposit, we outline a dating methodology that can provide details of the provenance's tectonomagmatic history from deformation-relative age distributions. The method involves bulk samples of solely granitoid clasts, as they are representative of the magmatic framework within the provenance. The clasts are classified and sorted into three subsets: undeformed, slightly deformed, and deformed. LA-ICPMS U-Pb geochronology is performed on zircon separates of each subset. Our case study, involving the Permian Hongliuhe Formation in the southern Central Asian Orogenic Belt, analyzes each of the three clast subsets, as well as sandstone detrital samples, at three stratigraphic levels to yield a profile of the unroofed provenance. The age spectra of the clast samples exhibit different, wider distributions than sandstone samples, considered an effect of proximity to the respective provenance. Comparisons of clast data to sandstone data, as well as comparisons between stratigraphic levels, yield indications of key tectonic processes, in addition to the typical characteristics provided by detrital geochronology. The clast data indicates a minimal lag time, implying rapid exhumation rates, whereas sandstone data alone would indicate a 90 m.y. lag time. Early Paleozoic arc building episodes appear as Ordovician peaks in sandstone data, and Silurian-Devonian peaks in clast data, indicating a younging of magmatism towards the proximal provenance. A magmatic hiatus starts in the Devonian, correlating with the latest age of deformed clasts, interpreted as timing of collisional tectonics. Provenance interpretation using the correlations seen between the clast and sandstone data proves to be more detailed and more robust than that determined from sandstone samples alone. The variably tectonized clast detrital geochronology method offers a regional reconnaissance tool that can address the practical limits of studying regional granitoid distributions.

Changing CO2 and the evolution of terrestrial and marine photosynthetic organisms during the terrestrialization process in the Palaeozoic.

NASA Astrophysics Data System (ADS)

Vecoli, M.; Strother, P. K.; Servais, T.

2009-04-01

The comparative analysis, at the scale of the entire Phanerozoic, of the curves of modelled variation in atmospheric CO2, of global phytoplankton diversity, and of the major steps in land plant evolution, shows interesting and somewhat unexpected correlations that can be explained in a coherent conceptual model linking the terrestrialization process, the global carbon cycle, and the evolution of the large oceanic phytoplankton. A simple model for the evolution of land plants can be proposed which subdivides the terrestrialization process into a sequence of four successive terrestrial autotrophic biomes: a cyanobacterial-dominated microbial landscape (microbial mats: 2.2 Gy), a bryophyte-dominated subaerial biome similar to posterlands, sensu Retallack (1993) (thalloid bryophytes: 523-513 My), a polysporangiophytic biome that includes both rhyniophytoids and tracheophytes which do not possess secondary xylem (tracheophyes: 426-423 My), and a forested biome composed of plants that possessed secondary xylem (lignophytes: 385-375 My). These stages represent successive incremental increases levels of biomass (thus of sequestration of carbon), and of weathering of parent rock (depth of the rhizosphere). Apart from the microbial mats biome, each of the three successive stages corresponds to a subsequent drop in paleo-CO2 levels as established in the GEOCARB III model. This was not an expected result of our analysis, because the primary effect of terrestrialization should not have been felt until the rise of the forested (Lignophyte) biome during the Late Devonian. Nevertheless, it seems a remarkable coincidence that each of three periods of the most significant drops in the CO2 model begins exactly at the time of the origin of each successive vegetative biome. It is therefore proposed that the cumulative increase in biomass retention (which corresponds to the successive establishment of terrestrial biomes) contributed significantly to a drawdown of pCO2 due to the sequestration of Corg in organic matter trapped in plant biomass, litter, soils, and buried in sediments, adding up to the better known effect of increased weathering due to the evolution of deep rooting systems during late Devonian time onwards. In this study, we also examined the potential perturbations to the phytoplankton of the mid-Palaeozoic marine realm as CO2(aq) declined and as POM and DOM delivery to the shallow shelf increased nutrient flux to the oceans. We used the fossil record of acritarchs as a proxy for the large phytoplankton of the Palaeozoic. Our data show that the standing diversity of acritarchs (genus-level taxon richness) is highly correlated with the decline in Palaeozoic pCO2 as modelled by Berner and Kothavala (2001); the two curves show the same trends, the acritarch diversity curve being offset, on average, by a -10 my time lag. We propose that the gradual (and not catastrophic as previously assumed) decline in acritarch diversity observed during late Silurian - late Devonian times was causally linked to the decline in dissolved CO2 in the oceans and the associated increase in oceanic pH, which were in turn caused by the falling pCO2 in the atmosphere. These observations appear to link the decline of the acritarchs to the rise of the terrestrial biota through the effect of terrestrialization on pCO2.

18 CFR 270.201 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-04-01

... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...

18 CFR 270.201 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-04-01

... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...

18 CFR 270.201 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-04-01

... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...

18 CFR 270.201 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-04-01

... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...

18 CFR 270.201 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-04-01

... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...

Retrospective Case Study in Northeastern Pennsylvania, Study of the Potential Impacts of Hydraulic Fracturing On Drinking Water Resources

EPA Science Inventory

This report describes the retrospective case study for northeastern Pennsylvania, which was conducted in Bradford and Susquehanna Counties where some of the most intensive unconventional gas production from the Devonian-age Marcellus Shale has occurred. Gas production from the M...

Retrospective Case Study in Southwestern Pennsylvania, Study of the Potential Impacts of Hydraulic Facturing on Drinking Water Resources

EPA Science Inventory

This report describes the retrospective case study for southwestern Pennsylvania, which was conducted in Amwell, Cross Creek, Hopewell, and Mount Pleasant Townships in Washington County, locations that have witnessed unconventional gas production from the Devonian-age Marcellus S...

Publications - PIR 2002-1C | Alaska Division of Geological & Geophysical

Science.gov Websites

fortymile_eaglea1_surficial Shapefile 3.3 M Metadata - Read me Keywords Alaska, State of; Alluvial Deposits; Bison Fossils ; Boundary (Place); Caribou Fossils; Cenozoic; Colluvial Deposits; Complex Deposits; Cretaceous; Devonian ; Fortymile Mining District; Fortymile River; Geologic Map; Geology; Glacial Deposits; Holocene; Horse Fossils

The ichnologic record of the continental invertebrate invasion: evolutionary trends in environmental expansion, ecospace utilization, and behavioral complexity

USGS Publications Warehouse

Buatois, L.A.; Mangano, M.G.; Genise, Jorge F.; Taylor, T.N.

1998-01-01

The combined study of continental trace fossils and associated sedimentary facies provides valuable evidence of colonization trends and events throughout the Phanerozoic. Colonization of continental environments was linked to the exploitation of empty or under-utilized ecospace. Although the nonmarine trace fossil record probably begins during the Late Ordovician, significant invasion of nonmarine biotopes began close to the Silurian-Devonian transition with the establishment of a mobile arthropod epifauna (Diplichnites ichnoguild) in coastal marine to alluvial plain settings. Additionally, the presence of vertical burrows in Devonian high-energy fluvial deposits reflects the establishment of a stationary, deep suspension-feeding infauna of the Skolithos ichnoguild. The earliest evidence of plant-arthropod interaction occurred close to the Silurian-Devonian boundary, but widespread and varied feeding patterns are known from the Carboniferous. During the Carboniferous, permanent subaqueous lacustrine settings were colonized by a diverse, mobile detritus-feeding epifauna of the Mermia ichnoguild, which reflects a significant palaeoenvironmental expansion of trace fossils. Paleozoic ichnologic evidence supports direct routes to the land from marginal marine environments, and migration to lakes from land settings. All nonmarine sedimentary environments were colonized by the Carboniferous, and subsequent patterns indicate an increase in ecospace utilization within already colonized depositional settings. During the Permian, back-filled traces of the Scoyenia ichnoguild record the establishment of a mobile, intermediate-depth, deposit-feeding in-fauna in alluvial and transitional alluvial-lacustrine sediment. Diversification of land plants and the establishment of ecologically diverse plant communities through time provided new niches to be exploited by arthropods. Nevertheless, most ot the evolutionary feeding innovations took place relatively early, during the Late Palaeozoic or early Mesozoic. A stationary deep unfauna, the Camborygma ichnoguild, was developed in Triassic transitional alluvial-lacustrinbe deposits. Terrestrial environments hosted the rise of complex social behavioral patterns, as suggested by the probable presence of hymenopteran and isopteran nests in Triassic paleosols. An increase in diversity of trace fossils is detected in Triassic-Jurassic eolian deposits, where the ichnofauna displays more varied behavioral patterns than their Paleozoic counterparts. Also, a mobile, intermediate-depth, deposit-feeding infauna, the Vagorichnus ichnoguild, was established in deep lake environments during the Jurassic. In contrast to Paleozoic permanent subaqueous assemblages typified by surface trails, Jurassic ichnocoenoses are dominated by infaunal burrows. High density of infaunal deposit-feeding traces of the Planolites ichnoguild caused major disruption of lacustrine sedimentary fabrics during the Cretaceous. Most insect mouthpart classes, functional feeding groups, and dietary guilds were established by the end of the Cretaceous. Diversification of modern insects is recorded by the abundance and complexity of structures produced by wasps, bees, dung-beetles, and termites in Cretaceous-Tertiary paleosols. The increase in bioturbation migrated from fluvial and lake-margin settings to permanent subaqueous lacustrine environments through time.

Natural Gases in Ground Water near Tioga Junction, Tioga County, North-Central Pennsylvania - Occurrence and Use of Isotopes to Determine Origins, 2005

USGS Publications Warehouse

Breen, Kevin J.; Revesz, Kinga; Baldassare, Fred J.; McAuley, Steven D.

2007-01-01

In January 2001, State oil and gas inspectors noted bubbles of natural gas in well water during a complaint investigation near Tioga Junction, Tioga County, north-central Pa. By 2004, the gas occurrence in ground water and accumulation in homes was a safety concern; inspectors were taking action to plug abandoned gas wells and collect gas samples. The origins of the natural-gas problems in ground water were investigated by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, in wells throughout an area of about 50 mi2, using compositional and isotopic characteristics of methane and ethane in gas and water wells. This report presents the results for gas-well and water-well samples collected from October 2004 to September 2005. Ground water for rural-domestic supply and other uses near Tioga Junction is from two aquifer systems in and adjacent to the Tioga River valley. An unconsolidated aquifer of outwash sand and gravel of Quaternary age underlies the main river valley and extends into the valleys of tributaries. Fine-grained lacustrine sediments separate shallow and deep water-bearing zones of the outwash. Outwash-aquifer wells are seldom deeper than 100 ft. The river-valley sediments and uplands adjacent to the valley are underlain by a fractured-bedrock aquifer in siliciclastic rocks of Paleozoic age. Most bedrock-aquifer wells produce water from the Lock Haven Formation at depths of 250 ft or less. A review of previous geologic investigations was used to establish the structural framework and identify four plausible origins for natural gas. The Sabinsville Anticline, trending southwest to northeast, is the major structural feature in the Devonian bedrock. The anticline, a structural trap for a reservoir of deep native gas in the Oriskany Sandstone (Devonian) (origin 1) at depths of about 3,900 ft, was explored and tapped by numerous wells from 1930-60. The gas reservoir in the vicinity of Tioga Junction, depleted of native gas, was converted to the Tioga gas-storage field for injection and withdrawal of non-native gases (origin 2). Devonian shale gas (shallow native gas) also has been reported in the area (origin 3). Gas might also originate from microbial degradation of buried organic material in the outwash deposits (origin 4). An inventory of combustible-gas concentrations in headspaces of water samples from 91 wells showed 49 wells had water containing combustible gases at volume fractions of 0.1 percent or more. Well depth was a factor in the observed occurrence of combustible gas for the 62 bedrock wells inventoried. As well-depth range increased from less than 50 ft to 51-150 ft to greater than 151 ft, the percentage of bedrock-aquifer wells with combustible gas increased. Wells with high concentrations of combustible gas occurred in clusters; the largest cluster was near the eastern boundary of the gas-storage field. A subsequent detailed gas-sampling effort focused on 39 water wells with the highest concentrations of combustible gas (12 representing the outwash aquifer and 27 from the bedrock aquifer) and 8 selected gas wells. Three wells producing native gas from the Oriskany Sandstone and five wells (two observation wells and three injection/withdrawal wells) with non-native gas from the gas-storage field were sampled twice. Chemical composition, stable carbon and hydrogen isotopes of methane (13CCH4 and DCH4), and stable carbon isotopes of ethane (13CC2H6) were analyzed. No samples could be collected to document the composition of microbial gas originating in the outwash deposits (outwash or 'drift' gas) or of native natural gas originating solely in Devonian shale at depths shallower than the Oriskany Sandstone, although two of the storage-field observation wells sampled reportedly yielded some Devonian shale gas. Literature values for outwash or 'drift' gas and Devonian shale gases were used to supplement the data collection. Non-native gases fr

Importance of inorganic geochemical characteristics on assessment of shale gas potential in the Devonian Horn River Formation of western Canada

NASA Astrophysics Data System (ADS)

Hong, Sung Kyung; Shinn, Young Jae; Choi, Jiyoung; Lee, Hyun Suk

2017-04-01

The gas generation and storage potentials of shale has mostly been assessed by original TOC (TOCo) and original kerogen type. However, in the Horn River Formation, organic geochemical tools and analysis are barely sufficient for assessing the TOCo and original kerogen type because residual carbon contents represent up to 90% of TOC in shales. Major and trace elements are used as proxies for the bottom water oxygen level, for terrestrial sediment input and for productivity, which is related with variation of kerogen type. By using the inorganic geochemical proxies, we attempt to assess original kerogen type in shale gas formation and suggest its implication for HIo (original Hydrogen Index) estimation. The estimated HIo in this study allows us to calculate a reliable TOCo. These results provide new insights into the accurate estimation of the hydrocarbon potential of shale gas resources. The inorganic geochemical proxies indicate vertical variations of productivity (EX-SiO2 and Baauth), terrestrial sediment input (Al2O3, Zr, Hf, and Nb) and oxygen content in bottom water during deposition (Moauth, Uauth and Th/U), which represent the temporal changes in the mixing ratio between Type II and III kerogens. The Horn River Formation has different HIo values calculated from EX-SiO2 (biogenic origin) and it is ranked by HIo value in descending order: Evie and Muskwa members (500-700 mgHC/gTOC) > middle Otterpark Member (400-500 mgHC/gTOC) > upper Otterpark Member (300-400 mgHC/gTOC) > lower Otterpark Member (200 mgHC/gTOC). Based on the original kerogen type and TOCo, the gas generation and storage potentials of the Evie, middle Otterpark and Muskwa members are higher than those of other members. The source rock potential is excellent for the Evie Member with a remarkable difference between TOCo and measured TOC.

Groundwater Discharges to Rivers in the Western Canadian Oil Sands Region

NASA Astrophysics Data System (ADS)

Ellis, J.; Jasechko, S.

2016-12-01

Groundwater discharges into rivers impacts the movement and fate of nutrients and contaminants in the environment. Understanding groundwater-surface water interactions is especially important in the western Canadian oil sands, where groundwater contamination risks are elevated and baseline water chemistry data is lacking, leading to substantial uncertainties about anthropogenic influences on local river quality. High salinity groundwater springs sourced from deep aquifers, comprised of Pleistocene-aged glacial meltwater, are known to discharge into many rivers in the oil sands. Understanding connections between deep aquifers and surficial waterways is important in order to determine natural inputs into these rivers and to assess the potential for injected wastewater or oil extraction fluids to enter surface waters. While these springs have been identified, their spatial distribution along rivers has not been fully characterized. Here we present river chemistry data collected along a number of major river corridors in the Canadian oil sands region. We show that saline groundwater springs vary spatially along the course of these rivers and tend to be concentrated where the rivers incise Devonian- or Cretaceous-aged aquifers along an evaporite dissolution front. Our results suggest that water sourced from Devonian aquifers may travel through bitumen-bearing Cretaceous units and discharge into local rivers, implying a strong groundwater-surface water connection in specialized locations. These findings indicate that oil sands process-affected waters that are injected at depth have the potential to move through these aquifers and reach the rivers at the surface at some time in the future. Groundwater-surface water interactions remain key to understanding the risks oil sands activities pose to aquatic ecosystems and downstream communities.

Remote sensing and field analysis of the Palaeozoic structural style in NW Libya: The Qarqaf arch a paleo-transfer fault zone between the Ghadamis and Murzuq basins

NASA Astrophysics Data System (ADS)

Chorowicz, Jean; Benissa, Mahmoud

2016-11-01

The N75°E-trending Qarqaf arch in NW Libya separates the Ghadamis and Murzuq basins. We have updated existing geological maps by remote sensing analysis and fieldwork in order to describe the tectonic style of the Palaeozoic units. We have evidenced a Bir Aishah anticline, a Wadi Ash Shabiyat graben and arrays of sedimentary and/or vein quartz dykes that relate to extension fractures or open faults some of them being filled up by on-going sedimentation. We show that continuous brittle syn-depositional deformation occurred throughout the Palaeozoic and progressively with time focused into major faults. The Qarqaf arch is a Palaeozoic right-lateral fault zone comprising main conjugate dextral N60°E and sinistral N90°E fault families. It also comprises ∼ N-striking extensional faults with related drag or fault-propagation folds. The Palaeozoic tectonic style is that of rift basins connected by a major transfer fault zone. The arch is as a consequence of strike-slip mechanism. In order to account for distinct folds affecting the Carboniferous strata we argue that partly consolidated silty Devonian and Carboniferous deposits slid in mass by places at the end of their deposition over tilting Devonian layers. Our model is alternative to the currently considered concept of major Variscan compressional orogen in this area. The regional so called 'Variscan' age disconformity actually is the Triassic early Neo-Tethyan event. These general concepts have potential impact on basin modelling of subsidence, uplift, thermal history and hydrocarbon migration. Any new structural geology study in this area is important for oil exploration.

Determining the source and genetic fingerprint of natural gases using noble gas geochemistry: a northern Appalachian Basin case study

USGS Publications Warehouse

Hunt, Andrew G.; Darrah, Thomas H.; Poreda, Robert J.

2012-01-01

Silurian and Devonian natural gas reservoirs present within New York state represent an example of unconventional gas accumulations within the northern Appalachian Basin. These unconventional energy resources, previously thought to be noneconomically viable, have come into play following advances in drilling (i.e., horizontal drilling) and extraction (i.e., hydraulic fracturing) capabilities. Therefore, efforts to understand these and other domestic and global natural gas reserves have recently increased. The suspicion of fugitive mass migration issues within current Appalachian production fields has catalyzed the need to develop a greater understanding of the genetic grouping (source) and migrational history of natural gases in this area. We introduce new noble gas data in the context of published hydrocarbon carbon (C1,C2+) (13C) data to explore the genesis of thermogenic gases in the Appalachian Basin. This study includes natural gases from two distinct genetic groups: group 1, Upper Devonian (Marcellus shale and Canadaway Group) gases generated in situ, characterized by early mature (13C[C1  C2][13C113C2]: –9), isotopically light methane, with low (4He) (average, 1  103 cc/cc) elevated 4He/40Ar and 21Ne/40Ar (where the asterisk denotes excess radiogenic or nucleogenic production beyond the atmospheric ratio), and a variable, atmospherically (air-saturated–water) derived noble gas component; and group 2, a migratory natural gas that emanated from Lower Ordovician source rocks (i.e., most likely, Middle Ordovician Trenton or Black River group) that is currently hosted primarily in Lower Silurian sands (i.e., Medina or Clinton group) characterized by isotopically heavy, mature methane (13C[C1 – C2] [13C113C2]: 3), with high (4He) (average, 1.85  103 cc/cc) 4He/40Ar and 21Ne/40Ar near crustal production levels and elevated crustal noble gas content (enriched 4He,21Ne, 40Ar). Because the release of each crustal noble gas (i.e., He, Ne, Ar) from mineral grains in the shale matrix is regulated by temperature, natural gases obtain and retain a record of the thermal conditions of the source rock. Therefore, noble gases constitute a valuable technique for distinguishing the genetic source and post-genetic processes of natural gases.

Organic metamorphism in the Lower Mississippian-Upper Devonian Bakken shales. Part 1: Rock-Eval pyrolysis and vitrinite reflectance.

USGS Publications Warehouse

Price, L.C.; Daws, T.; Pawlewicz, M.

1986-01-01

The Williston basin is an intracratonic basin extending across parts of several states, principally North Dakota, on the US/Canadian frontier. A sequence of up to 16 000 ft of Phanerozoic rocks exists in the basin; the Bakken formation is a relatively thin clastic unit composed of three members, of which the middle one is a black shale. Both core chip and cutting chip samples from a series of widely-distributed well locations were taken for laboratory analysis. Pyrolysis data showed 'wide variations' in maturity indices in samples from equivalent depths at different well locations. This suggests that a number of different palaeoheat-flow regimes have existed in the basin, resulting in the optimization of hydrocarbon formation processes at varying depths at different localities. The vitrinite reflectance profiles presented illustrate the expected trend of linearly-increasing maturity with depth to around 6500 ft. Between 6700 and 10 000 ft, however, this trend is interrupted by two 'reversals'. It is suggested that these reversals are due to suppression of the vitrinite reflectance values in samples with high concentrations of H-rich organic matter, and that they may therefore be associated with transitions from 'terrestrial-derived' to marine-depositional conditions. Consequently, the precise identification of the thresholds of intense hydrocarbon generation within the basin is problematic.-J.M.H.

Tentaculate Fossils from the Cambrian of Canada (British Columbia) and China (Yunnan) Interpreted as Primitive Deuterostomes

PubMed Central

Caron, Jean-Bernard; Conway Morris, Simon; Shu, Degan

2010-01-01

Molecular and morphological evidence unite the hemichordates and echinoderms as the Ambulacraria, but their earliest history remains almost entirely conjectural. This is on account of the morphological disparity of the ambulacrarians and a paucity of obvious stem-groups. We describe here a new taxon Herpetogaster collinsi gen. et sp. nov. from the Burgess Shale (Middle Cambrian) Lagerstätte. This soft-bodied vermiform animal has a pair of elongate dendritic oral tentacles, a flexible stolon with an attachment disc, and a re-curved trunk with at least 13 segments that is directed dextrally. A differentiated but un-looped gut is enclosed in a sac suspended by mesenteries. It consists of a short pharynx, a conspicuous lenticular stomach, followed by a narrow intestine sub-equal in length. This new taxon, together with the Lower Cambrian Phlogites and more intriguingly the hitherto enigmatic discoidal eldoniids (Cambrian-Devonian), form a distinctive clade (herein the cambroernids). Although one hypothesis of their relationships would look to the lophotrochozoans (specifically the entoprocts), we suggest that the evidence is more consistent with their being primitive deuterostomes, with specific comparisons being made to the pterobranch hemichordates and pre-radial echinoderms. On this basis some of the earliest ambulacrarians are interpreted as soft-bodied animals with a muscular stalk, and possessing prominent tentacles. PMID:20221405

Earth observation taken by the Expedition 20 crew

NASA Image and Video Library

2009-07-25

ISS020-E-026195 (25 July 2009) --- Aorounga Impact Crater is featured in this image photographed by an Expedition 20 crew member on the International Space Station. Aorounga Impact Crater is located in the Sahara Desert of north-central Chad and is one of the best preserved impact structures in the world. According to scientists, the crater is thought to be middle or upper Devonian to lower Mississippian (approximately 345 ? 370 million years old) based on the age of the sedimentary rocks deformed by the impact. Spaceborne Imaging Radar (SIR) data collected in 1994 suggests that Aorounga is one of a set of three craters formed by the same impact event. The other two suggested impact structures are buried by sand deposits. The concentric ring structure of the Aorounga crater ? renamed Aorounga South in the multiple-crater interpretation of SIR data ? is clearly visible in this detailed photograph. The central highland, or peak, of the crater is surrounded by a small sand-filled trough; this in turn is surrounded by a larger circular trough. Linear rock ridges alternating with light orange sand deposits cross the image from upper left to lower right; these are called yardangs by geomorphologists. Yardangs form by wind erosion of exposed rock layers in a unidirectional wind field. The wind blows from the northeast at Aorounga, and sand dunes formed between the yardangs are actively migrating to the southwest.

Geologic Map of the Warm Spring Canyon Area, Death Valley National Park, Inyo County, California, With a Discussion of the Regional Significance of the Stratigraphy and Structure

USGS Publications Warehouse

Wrucke, Chester T.; Stone, Paul; Stevens, Calvin H.

2007-01-01

Warm Spring Canyon is located in the southeastern part of the Panamint Range in east-central California, 54 km south of Death Valley National Park headquarters at Furnace Creek Ranch. For the relatively small size of the area mapped (57 km2), an unusual variety of Proterozoic and Phanerozoic rocks is present. The outcrop distribution of these rocks largely resulted from movement on the east-west-striking, south-directed Butte Valley Thrust Fault of Jurassic age. The upper plate of the thrust fault comprises a basement of Paleoproterozoic schist and gneiss overlain by a thick sequence of Mesoproterozoic and Neoproterozoic rocks, the latter of which includes diamictite generally considered to be of glacial origin. The lower plate is composed of Devonian to Permian marine formations overlain by Jurassic volcanic and sedimentary rocks. Late Jurassic or Early Cretaceous plutons intrude rocks of the area, and one pluton intrudes the Butte Valley Thrust Fault. Low-angle detachment faults of presumed Tertiary age underlie large masses of Neoproterozoic dolomite in parts of the area. Movement on these faults predated emplacement of middle Miocene volcanic rocks in deep, east-striking paleovalleys. Excellent exposures of all the rocks and structural features in the area result from sparse vegetation in the dry desert climate and from deep erosion along Warm Spring Canyon and its tributaries.

Stream measurements locate thermogenic methane fluxes in groundwater discharge in an area of shale-gas development.

PubMed

Heilweil, Victor M; Grieve, Paul L; Hynek, Scott A; Brantley, Susan L; Solomon, D Kip; Risser, Dennis W

2015-04-07

The environmental impacts of shale-gas development on water resources, including methane migration to shallow groundwater, have been difficult to assess. Monitoring around gas wells is generally limited to domestic water-supply wells, which often are not situated along predominant groundwater flow paths. A new concept is tested here: combining stream hydrocarbon and noble-gas measurements with reach mass-balance modeling to estimate thermogenic methane concentrations and fluxes in groundwater discharging to streams and to constrain methane sources. In the Marcellus Formation shale-gas play of northern Pennsylvania (U.S.A.), we sampled methane in 15 streams as a reconnaissance tool to locate methane-laden groundwater discharge: concentrations up to 69 μg L(-1) were observed, with four streams ≥ 5 μg L(-1). Geochemical analyses of water from one stream with high methane (Sugar Run, Lycoming County) were consistent with Middle Devonian gases. After sampling was completed, we learned of a state regulator investigation of stray-gas migration from a nearby Marcellus Formation gas well. Modeling indicates a groundwater thermogenic methane flux of about 0.5 kg d(-1) discharging into Sugar Run, possibly from this fugitive gas source. Since flow paths often coalesce into gaining streams, stream methane monitoring provides the first watershed-scale method to assess groundwater contamination from shale-gas development.

Environmental control on concretion-forming processes: Examples from Paleozoic terrigenous sediments of the North Gondwana margin, Armorican Massif (Middle Ordovician and Middle Devonian) and SW Sardinia (Late Ordovician)

NASA Astrophysics Data System (ADS)

Dabard, Marie-Pierre; Loi, Alfredo

2012-08-01

Concretions of various compositions are common in the Paleozoic terrigenous successions of the north Gondwana margin. This study focuses on phosphatic (P) and siliceous (Si) concretions present in some successions of the Armorican Massif (NW France) and SW Sardinia (W Italy). It shows that they consist of mudstones, fine- to very fine-grained sandstones or shellbeds with a more or less abundant P-cement and form a continuum between a phosphatic end-member and a siliceous biogenic end-member. The P2O5 contents are ranging from 0.26% to 21.5% and are related to apatite. The SiO2 contents vary from 25% to 82% and are linked both to a terrigenous phase and to a biogenic silica phase. Concretions showing the lower P-contents (P2O5 < 1.5%) are often enriched in biogenic silica (SiO2/Al2O3 > 5). Comparison with the surrounding sediments shows that all the concretions are enriched in chlorite and in Middle Rare Earth Elements (Las/Gds: 0.12-0.72) and some of them in Y (up to 974 ppm), Rare Earth Elements (more than 300 ppm) and Sr (260-880 ppm). The concretions with highest biogenic silica concentrations are contained in the outer shelf sediments whereas the other concretions are present from the proximal part of the inner shelf to the outer shelf. A genetic model in two stages is proposed. During early diagenesis, the dissolution of shells and degradation of organic matter progressively enrich the pore water in dissolved Si, Ca and P. When the suboxic zone is reached, P-precipitation begins, leading to the formation of protoconcretions. In shallow environments, the relative permeability of sediments and the winnowing or reworking of the upper few centimetres by bottom currents allow for suboxic conditions to be maintained, leading to P-rich concretion formation. In deeper environments, the anoxic zone is reached more rapidly, thereby preventing extensive phosphogenesis. Nevertheless in the protoconcretions the early P-cement preserves pore spaces from compaction. In the presence of biogenic siliceous particles, the fluids are enriched in dissolved silica and diffuse towards the protoconcretions. Silica precipitation can thus occur later in the intergranular spaces.

Retrospective Case Study in Killdeer, North Dakota, Study of the Potential Impacts of Hydraulic Fracturing on Drinking Water Resources.

EPA Science Inventory

This report describes the retrospective case study conducted near Killdeer, Dunn County, North Dakota. The Killdeer study area is the location of historical oil and gas production, with current unconventional oil and gas production occurring in the late Devonian/early Mississipp...

Composition and genesis of the Konevinsky gold deposit, Eastern Sayan, Russia

NASA Astrophysics Data System (ADS)

Damdinov, B. B.; Zhmodik, S. M.; Roshchektaev, P. A.; Damdinova, L. B.

2016-03-01

The Konevinsky gold deposit in southeast Eastern Sayan is distinguished from most known deposits in this region (Zun-Kholba, etc.) by the geological setting and composition of mineralization. To elucidate the cause of the peculiar mineralization, we have studied the composition, formation conditions, and origin of this deposit, which is related to the Ordovician granitoid pluton 445-441 Ma in age cut by intermediate and basic dikes spatially associated with metavolcanic rocks of the Devonian-Carboniferous Ilei Sequence. Four mineral assemblages are recognized: (1) quartz-pyrite-molybdenite, (2) quartz-gold-pyrite, (3) gold-polysulfide, and (4) telluride. Certain indications show that the ore was formed as a result of the superposition of two distinct mineral assemblages differing in age. The first stage dated at ~440 Ma is related to intrusions generating Cu-Mo-Au porphyry mineralization and gold-polysulfide veins. The second stage is controlled by dikes pertaining to the Devonian-Carboniferous volcanic-plutonic association. The second stage is characterized by gain of Hg and Te and formation of gold-mercury-telluride paragenesis.

Characterization of the Helderberg Group as a geologic seal for CO 2 sequestration

USGS Publications Warehouse

Lewis, J.E.; McDowell, R.R.; Avary, K.L.; Carter, K.M.

2009-01-01

The Midwest Regional Carbon Sequestration Partnership recognizes that both the Devonian Oriskany Sandstone and the Silurian Salina Group offer potential for subsurface carbon dioxide storage in northern West Virginia. The Silurian-Devonian Helderberg Group lies stratigraphically between these two units, and consequendy, its potential as a geologic seal must be evaluated. Predominantly a carbonate interval with minor interbedded siliciclastics and chert, the Helderberg Group was deposited in an ancient epeiric sea. Although most previous investigations of this unit have concentrated on outcrops in eastern West Virginia, new information is available from an injection well drilled along the Ohio River at First Energy's R. E. Burger electric power plant near Shadyside, Ohio. Geophysical, seismic, and core data from this well have been combined with existing outcrop information to evaluate the Helderberg Group's potential as a seal. The data collected suggest that only secondary porosity remains, and permeability, if it exists, most likely occurs along faults or within fractures. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Provenance of upper Triassic sandstone, southwest Iberia (Alentejo and Algarve basins): tracing variability in the sources

NASA Astrophysics Data System (ADS)

Pereira, M. F.; Ribeiro, C.; Gama, C.; Drost, K.; Chichorro, M.; Vilallonga, F.; Hofmann, M.; Linnemann, U.

2017-01-01

Laser ablation ICP-MS U-Pb analyses have been conducted on detrital zircon of Upper Triassic sandstone from the Alentejo and Algarve basins in southwest Iberia. The predominance of Neoproterozoic, Devonian, Paleoproterozoic and Carboniferous detrital zircon ages confirms previous studies that indicate the locus of the sediment source of the late Triassic Alentejo Basin in the pre-Mesozoic basement of the South Portuguese and Ossa-Morena zones. Suitable sources for the Upper Triassic Algarve sandstone are the Upper Devonian-Lower Carboniferous of the South Portuguese Zone (Phyllite-Quartzite and Tercenas formations) and the Meguma Terrane (present-day in Nova Scotia). Spatial variations of the sediment sources of both Upper Triassic basins suggest a more complex history of drainage than previously documented involving other source rocks located outside present-day Iberia. The two Triassic basins were isolated from each other with the detrital transport being controlled by two independent drainage systems. This study is important for the reconstruction of the late Triassic paleogeography in a place where, later, the opening of the Central Atlantic Ocean took place separating Europe from North America.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barron, L.S.; Ettensohn, F.R.

The Devonian-Mississippian black-shale sequence is one of the most prominent and well-known stratigraphic horizons in the Paleozoic of the United States, yet the paleontology and its paleoecologic and paleoenvironmental implications are poorly known. This is in larger part related to the scarcity of fossils preserved in the shale - in terms of both diversity and abundance. Nonetheless, that biota which is preserved is well-known and much described, but there is little synthesis of this data. The first step in such a synthesis is the compilation of an inclusive bibliography such as this one. This bibliography contains 1193 entries covering allmore » the major works dealing with Devonian-Mississippian black-shale paleontology and paleoecology in North America. Articles dealing with areas of peripheral interest, such as paleogeography, paleoclimatology, ocean circulation and chemistry, and modern analogues, are also cited. In the index, the various genera, taxonomic groups, and other general topics are cross-referenced to the cited articles. It is hoped that this compilation will aid in the synthesis of paleontologic and paleoecologic data toward a better understanding of these unique rocks and their role as a source of energy.« less

Bedrock Geologic Map of the Old Lyme Quadrangle, New London and Middlesex Counties, Connecticut

USGS Publications Warehouse

Walsh, Gregory J.; Scott, Robert B.; Aleinikoff, John N.; Armstrong, Thomas R.

2009-01-01

The bedrock geology of the Old Lyme quadrangle consists of Neoproterozoic and Permian gneisses and granites of the Gander and Avalon terranes, Silurian metasedimentary rocks of the Merrimack terrane, and Silurian to Devonian metasedimentary rocks of uncertain origin. The Avalon terrane rocks crop out within the Selden Neck block, and the Gander terrane rocks crop out within the Lyme dome. The Silurian to Devonian rocks crop out between these two massifs. Previous mapping in the Old Lyme quadrangle includes the work by Lawrence Lundgren, Jr. Lundgren's work provides an excellent resource for rock descriptions and detailed modal analyses of rock units that will not be duplicated in this current report. New research that was not covered in detail by Lundgren is the focus of this report and includes (1) evaluation of the rocks in the core of the Lyme dome in an effort to subdivide units in this area; (2) structural analysis of foliations and folds in and around the Lyme dome; (3) geochronology of selected units within the Lyme dome; and (4) analysis of joints and the fracture properties of the rocks.

A Devonian tetrapod-like fish reveals substantial parallelism in stem tetrapod evolution.

PubMed

Zhu, Min; Ahlberg, Per E; Zhao, Wen-Jin; Jia, Lian-Tao

2017-10-01

The fossils assigned to the tetrapod stem group document the evolution of terrestrial vertebrates from lobe-finned fishes. During the past 18 years the phylogenetic structure of this stem group has remained remarkably stable, even when accommodating new discoveries such as the earliest known stem tetrapod Tungsenia and the elpistostegid (fish-tetrapod intermediate) Tiktaalik. Here we present a large lobe-finned fish from the Late Devonian period of China that disrupts this stability. It combines characteristics of rhizodont fishes (supposedly a basal branch in the stem group, distant from tetrapods) with derived elpistostegid-like and tetrapod-like characters. This mélange of characters may reflect either detailed convergence between rhizodonts and elpistostegids plus tetrapods, under a phylogenetic scenario deduced from Bayesian inference analysis, or a previously unrecognized close relationship between these groups, as supported by maximum parsimony analysis. In either case, the overall result reveals a substantial increase in homoplasy in the tetrapod stem group. It also suggests that ecological diversity and biogeographical provinciality in the tetrapod stem group have been underestimated.

The Eastern Gas Shales Project (EGSP) Data System: A case study in data base design, development, and application

USGS Publications Warehouse

Dyman, T.S.; Wilcox, L.A.

1983-01-01

The U.S. Geological Survey and Petroleum Information Corporation in Denver, Colorado, developed the Eastern Gas Shale Project (EGSP)Data System for the U.S. Department of Energy, Morgantown, West Virginia. Geological, geochemical, geophysical, and engineering data from Devonian shale samples from more than 5800 wells and outcrops in the Appalachian basin were edited and converted to a Petroleum Information Corporation data base. Well and sample data may be retrieved from this data system to produce (1)production-test summaries by formation and well location; (2)contoured isopach, structure, and trendsurface maps of Devonian shale units; (3)sample summary reports for samples by location, well, contractor, and sample number; (4)cross sections displaying digitized log traces, geochemical, and lithologic data by depth for wells; and (5)frequency distributions and bivariate plots. Although part of the EGSP Data System is proprietary, and distribution of complete well histories is prohibited by contract, maps and aggregated well-data listings are being made available to the public through published reports. ?? 1983 Plenum Publishing Corporation.

Trace Metal Characterization and Ion Exchange Capacity of Devonian to Pennsylvanian Age Bedrock in New York and Pennsylvania in Relation to Drinking Water Quality

NASA Astrophysics Data System (ADS)

Spradlin, J.; Fiorentino, A. J., II; Siegel, D. I.

2014-12-01

We report the results of an evaluation of the trace and major metal composition of shallow sedimentary rock formations in the Appalachian Basin that control the quality of potable water produced in domestic and other wells. In particular, we quantify the mobile and total metals for which there are health concerns related to unconventional gas exploitation; Fe, Mn, Sr, Ba, As, and Pb. To do this, we sampled the upper 400 feet of Devonian to Pennsylvanian aged bedrock from Marcellus, NY to State College, PA. We used a variation of the U.S. Geological Survey Field Leach Test to assess water reactivity and leaching potential. Al, Zn, and U potentially can be leached from aquifer rocks naturally under acidic conditions, such as where pyrite might oxidize, to above current allowable regulatory values for these metals (2 mg/L, 5 mg/L, and 0.03 mg/L respectively) from some of the clay-rich formations. Groundwater analyses from both New York and Pennsylvania show that natural ion exchange occurs along flow paths from ridges to valleys. We find the laboratory cation exchange capacity (CEC) spans what might be expected for illite and chlorite commonly found in these rocks. Given the low surface area of the mineral surfaces of the fractures through which most of the water moves, the observed ion exchange in these rocks is not well understood. Along with this broad scale study area we investigated a Devonian outcrop 4 miles North of Cortland, NY to evaluate small-scale trace metal heterogeneity within a single stratigraphic section. Together these two studies provide important information to determine the extent to which ground water might be naturally high in trace metal composition, either because of geochemical conditions or entrainment of suspended material not removed prior to sampling.

Origin of red pelagic carbonates as an interplay of global climate and local basin factors: Insight from the Lower Devonian of the Prague Basin, Czech Republic

NASA Astrophysics Data System (ADS)

Bábek, Ondřej; Faměra, Martin; Hladil, Jindřich; Kapusta, Jaroslav; Weinerová, Hedvika; Šimíček, Daniel; Slavík, Ladislav; Ďurišová, Jana

2018-02-01

Red pelagic sediments are relatively common in the Phanerozoic. They are often interpreted as products of sea-bottom oxidation during greenhouse climate showing a conspicuous alternation with black shales and thus carrying important palaeoceanographic information. The Lower Devonian (Pragian) carbonate strata of the Prague Basin, Czech Republic (Praha Formation) contain a marked band of red pelagic carbonate, up to 15 m thick, which can be correlated for several tens of km. We investigated seven sections (17 to 255 m thick) of the Prague Basin using the methods of facies analysis, outcrop gamma-ray logging, diffuse reflectance spectroscopy, optical microscopy, element geochemistry, magneto-mineralogy and electron microprobe analysis. The aim was to find the mineral carriers of the red colour, investigate the stratigraphic context of the red carbonates and evaluate the local and global prerequisites for their formation. The red pigmentation represents enrichment by hematite with respect to goethite. Approximately 31% of the total reflectance falling in the red colour band represents a threshold for red coloration. The red pigmentation is carried by submicronic hematite dispersed in argillaceous pelagic calcilutite and/or inside skeletal allochems. Gamma-ray log correlation indicates that the red carbonate band developed in stratigraphic levels with low sedimentation rates, typically from 1 to 7.1 mm/kyr, which are comparable to the Mesozoic Rosso Ammonitico facies. The red beds and the whole Praha Formation (Pragian to early Emsian) are characterized by low TOC values (< 0.05%) and low U/Th, Mo/Al, V/Al, Zn/Al, Cu/Al and P/Al ratios indicating oligotrophic, highly oxic sea-bottom conditions. This period was characterized by global cooling, a drop in silicate weathering rates and in atmospheric pCO2 levels. The lower Devonian successions of the Prague Basin indicate that switching between two greenhouse climatic modes, colder oligotropic and warmer mesotrophic, may have been responsible for the alternation of red and grey carbonate strata, respectively.

Geology and hydrocarbon potential of the Oued Mya Basin, Algeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benamrane, O.; Messaoudi, M.; Messelles, H.

1992-01-01

The hydrocarbon System Ourd Mya is located in the Sahara Basin. It is one of the producing basin in Algeria. The stratigraphic section consists of Paleozoic and Mesosoic, it is about 5000m thick. In the eastern part, the basin is limited by the Hassi-Messaoud high zone which is a giant oil field producing from the Cambrian sands. The western part is limited by Hassi R'mel which is one of the biggest gas field in the world, it is producing from the triassic sands. The Mesozoic section is laying on the lower Devonian and in the eastern part, on the Cambrian.more » The main source rock is the Silurian shale with an average thickness of 50m and a total organic matter of 6% (14% in some cases). Results of maturation modeling indicate that the lower Silurian source is in the oil window. The Ordovician shales are also a source rock, but in a second order. Clastic reservoirs are in the Triassic sequence which is mainly fluvial deposits with complex alluvial channels, it is the main target in the basin. Clastic reservoirs within the lower Devonian section have a good hydrocarbon potential in the east of the basin through a southwest-northeast orientation. The late Triassic-Early Jurassic evaporites overlie the Triassic clastic interval and extend over the entire Oued Mya Basin. This is considered as a super-seal evaporate package, which consists predominantly of anhydrite and halite. For Paleozoic targets, a large number of potential seals exist within the stratigraphic column. The authors infer that a large amount of the oil volume generated by the Silurian source rock from the beginning of Cretaceous until now, still not discovered could be trapped within structure closures and mixed or stratigraphic traps related to the fluvial Triassic sandstones, marine Devonian sands and Cambro-Ordovician reservoirs.« less

Detrital zircon age distribution from Devonian and Carboniferous sandstone in the Southern Variscan Fold-and-Thrust belt (Montagne Noire, French Massif Central), and their bearings on the Variscan belt evolution

NASA Astrophysics Data System (ADS)

Lin, Wei; Faure, Michel; Li, Xian-hua; Chu, Yang; Ji, Wenbin; Xue, Zhenhua

2016-05-01

In the Southern French Massif Central, the Late Paleozoic sedimentary sequences of the Montagne Noire area provide clues to decipher the successive tectonic events that occurred during the evolution of the Variscan belt. Previous sedimentological studies already demonstrated that the siliciclastic deposits were supplied from the northern part of the Massif Central. In this study, detrital zircon provenance analysis has been investigated in Early Devonian (Lochkovian) conglomerate and sandstone, and in Carboniferous (Visean to Early Serpukhovian) sandstone from the recumbent folds and the foreland basin of the Variscan Southern Massif Central in Montagne Noire. The zircon grains from all of the samples yielded U-Pb age spectra ranging from Neoarchean to Late Paleozoic with several age population peaks at 2700 Ma, 2000 Ma, 980 Ma, 750 Ma, 620 Ma, 590 Ma, 560 Ma, 480 Ma, 450 Ma, and 350 Ma. The dominant age populations concentrate on the Neoproterozoic and Paleozoic. The dominant concordant detrital zircon age populations in the Lochkovian samples, the 480-445 Ma with a statistical peak around 450 Ma, are interpreted as reflecting the rifting event that separated several continental stripes, such as Armorica, Mid-German Crystalline Rise, and Avalonia from the northern part of Gondwana. However, Ediacaran and Cambrian secondary peaks are also observed. The detrital zircons with ages at 352 - 340 Ma, with a statistical peak around 350 Ma, came from the Early Carboniferous volcanic and plutonic rocks similar to those exposed in the NE part of the French Massif Central. Moreover, some Precambrian grains recorded a more complex itinerary and may have experienced a multi-recycling history: the Archean and Proterozoic grains have been firstly deposited in Cambrian or Ordovician terrigenous rocks, and secondly re-sedimented in Devonian and/or Carboniferous formations. Another possibility is that ancient grains would be inherited grains, scavenged from an underlying but not exposed Precambrian basement.

The formation of Pangea

NASA Astrophysics Data System (ADS)

Stampfli, G. M.; Hochard, C.; Vérard, C.; Wilhem, C.; vonRaumer, J.

2013-05-01

The making of Pangea is the result of large-scale amalgamation of continents and micro-continents, which started at the end of the Neoproterozoic with the formation of Gondwana. As pieces were added to Gondwana on its South-American, Antarctica and Australia side, ribbon-like micro-continents were detached from its African and South-Chinese side: Cadomia in the late Neoproterozoic, Avalonia and Hunia in the Ordovician, Galatia in the Devonian and Cimmeria in the Permian. Cadomia was re-accreted to Gondwana, but the other ribbon-continents were accreted to Baltica, North-China, Laurussia or Laurasia. Finding the origin of these numerous terranes is a major geological challenge. Recently, a global plate tectonic model was developed together with a large geological/geodynamic database, at the Lausanne University, covering the last 600 Ma of the Earth's history. Special attention was given to the placing of Gondwana derived terranes in their original position, using all possible constraints. We propose here a solution for the Variscan terranes, another paper deals with the Altaids. The Galatian super-terrane was detached from Gondwana in the Devonian, during the opening of Paleotethys, and was quickly separated into four sub-terranes that started to by-pass each other. The leading terranes collided at the end of the Devonian with the Hanseatic terrane detached from Laurussia. In the Carboniferous, Gondwana started to impinge onto the amalgamated terranes, creating the Variscan chain and the Pangean super-continent. East of Spain Paleotethys remained opened until the Triassic, subducting northward under Laurasia. Roll-back of the Paleotethyan slab triggered the collapse of most of the European Variscan orogen, which was replaced by series of Permian rifts, some of them becoming oceanized back-arc basins during the Triassic. Major force changes at the Pangean plate limits at the end of the Triassic provoked its break-up, through the opening of the proto-Caribbean, central-Atlantic, Alpine-Tethys oceanic seaways.

Petrogenesis and tectonic setting of the Devonian Xiqin A-type granite in the northeastern Cathaysia Block, SE China

NASA Astrophysics Data System (ADS)

Cai, Da-wei; Tang, Yong; Zhang, Hui; Lv, Zheng-Hang; Liu, Yun-long

2017-06-01

Most Silurian-Devonian granites in South China are S- or I-type granites, which are suggested to be petrogenetically related to the Wuyi-Yunkai orogeny. In this paper, we present the detailed LA-ICP-MS zircon U-Pb dating, major and trace element geochemical, and Nd-Hf isotopic data for Xiqin A-type granites in the northeastern Cathaysia Block, SE China. Zircon U-Pb dating results show that the Xiqin granites were emplaced at about 410 Ma, indicating that they were generated at the end of Wuyi-Yunkai orogeny. These granites are high in K2O + Na2O (6.31-8.79 wt%), high field strength elements (Zr + Nb + Ce + Y = 427-699 ppm), rare earth elements (total REE = 221-361 ppm) as well as high Ga/Al ratios (10,000 Ga/Al = 2.50-3.10), and show characteristics typical of A-type granites. εHf(t) values of the Xiqin granites mainly vary from -0.4 to -3.1 and yield Mesoproterozoic T2DM(Hf) (mainly ranging from 1.29 to 1.45 Ga). The εNd(t) values are from -1.23 to -2.11 and T2DM(Nd) vary from 1.25 to 1.32 Ga. These isotopic data suggest that the Xiqin granites were generated by partial melting of metavolcanic rocks with minor metasedimentary rocks in the lower crust. Our data on the Xiqin granites, coupled with previous studies of Silurian-Devonian magmatism, suggest that the tectonic regime had changed to a strongly post-collisional extension environment in the Wuyi-Yunkai orogen at least since 410 Ma, and that delamination, which accounts for the change in stress from the compression to extension and asthenospheric upwelling during the early Paleozoic, plays a significant role in the generation of Xiqin A-type granites.

Late Paleozoic closure of the Ob-Zaisan Ocean along the Irtysh/Chara shear zone and implications for arc amalgamation and oroclinal bending in the western Central Asian Orogenic Belt

NASA Astrophysics Data System (ADS)

Li, Pengfei; Sun, Min; Rosenbaum, Gideon

2016-04-01

The Irtysh/Chara Shear Zone is one of the largest strike-slip systems in the Central Asian Orogenic Belt (CAOB). It records collisional processes of the peri-Siberian orogenic system with the West Junggar-Kazakhstan-Tianshan orogenic system following the closure of the Ob-Zaisan Ocean, but the exact timing of these events remains enigmatic. We conducted detailed structural analysis along the Irtysh Shear Zone (NW China), which together with new geochronological data allows us to reconstruct the tectonic evolution during the final closure of the Ob-Zaisan Ocean. Our results showed that subduction-accretion processes lasted at least until the Late Carboniferous in the Chinese Altai and the East/West Junggar. The subsequent arc amalgamation is characterized by a cycle of crustal thickening, orogenic collapse and transpressional thickening. On a larger scale, the West Junggar- Kazakhstan -Tianshan orogenic system defines a U-shape oroclinal structure (e.g. Xiao et al., 2010). A major phase of oroclinal bending that involved ~110° rotation may have occurred during the Late Devonian to Early Carboniferous (Levashova et al., 2012). Previous authors have linked oroclinal bending with the late Paleozoic amalgamation of the western CAOB, and proposed that a quasi-linear West Junggar- Kazakhstan -Tianshan orogenic system was buckled during the convergence of the Siberian and Tarim cratons following the closure of the Ob-Zaisan Ocean (in the north) and the South Tianshan Ocean (in the south) (e.g. Abrajevitch et al., 2008). This model, however, is not supported by our new data that constrain the closure of the Ob-Zaisan Ocean to the Late Carboniferous. Alternatively, we propose that oroclinal bending may have involved two phases of bending, with the ~110° rotation in the Late Devonian to Early Carboniferous possibly associated with trench retreat. Further tightening may have occurred in response to the convergence of the Siberian and Tarim cratons during the Late Carboniferous to Permian. References: Abrajevitch, A., Van der Voo, R., Bazhenov, M.L., Levashova, N.M., McCausland, P.J.A., 2008. The role of the Kazakhstan orocline in the late Paleozoic amalgamation of Eurasia. Tectonophysics 455, 61-76. Levashova, N., Degtyarev, K., Bazhenov, M., 2012. Oroclinal bending of the Middle and Late Paleozoic volcanic belts in Kazakhstan: Paleomagnetic evidence and geological implications. Geotectonics 46, 285-302. Xiao, W., Huang, B., Han, C., Sun, S., Li, J., 2010. A review of the western part of the Altaids: A key to understanding the architecture of accretionary orogens. Gondwana Research 18, 253-273. Acknowledgements: This study was financially supported by the Major Basic Research Project of the Ministry of Science and Technology of China (Grant: 2014CB448000 and 2014CB440801), Hong Kong Research Grant Council (HKU705311P, HKU704712P and HKU17303415), National Science Foundation of China (41273048), HKU seed funding (201111159137) and HKU CRCG grants. This work is a contribution of the Joint Laboratory of Chemical Geodynamics between HKU and CAS (Guangzhou Institute of Geochemistry), IGCP 592 and PROCORE France/Hong Kong Joint Research Scheme.

Deformation of the Roberts Mountains Allochthon in north-central Nevada

USGS Publications Warehouse

Evans, James George; Theodore, Ted G.

1978-01-01

During the Antler orogeny in Late Devonian and Early Mississippian time, early and middle Paleozoic siliceous rocks, largely chert and sha1e, were thrust eastward for 90 to 160 km over coexisting carbonate rocks. Minor and major structures of two small areas of the allochthon at Battle Mountain and in the southern Tuscarora Mountains were studied in order to characterize the deformation and test the consistency of the movement plan with respect to the large eastward displacement. In the Battle Mountain area, the lower Paleozoic Scott Canyon and Valmy Formations were deformed in the Antler orogeny but were unaffected by later tectonism during late Paleozoic or early Mesozoic. In the southern Tuscarora Mountains area, the Ordovician and Silurian siliceous rocks deformed in the Antler Orogeny were deformed by later, possibly Mesozoic, folding and thrusting. Most of the minor folding visible in the allochthon is in the cheret, but proportionally more of the strain was taken up in the shale and argillite, both poorly exposed but predominant rock types. Most minor folds, concentric in form, plunge at small angles to the north-northeast and south-southwest with steeply dipping or vertical axial planes. The b-fabric axis, parallel to these folds, is identical apparently to the B-kinematic axis. The horizontal component of tectonic shortening of the allochthon, N. 70?-75? W. both in the Battle Mountain area and in the southern Tuscarora Mountains area, is therefore consistent with an eastward direction of movement of the allochthon. Folds with west- northwest trends locally present in the allochthon, may have formed in the direction of tectonic transport. In the southern Tuscarora Mountains, local strain in and below the allochthon was different from the prevailing strain in the allochthon, and tectonic shortening was locally at large angles to the accepted direction of movement of the allochthon.

Radium content of oil- and gas-field produced waters in the northern Appalachian Basin (USA)—Summary and discussion of data

USGS Publications Warehouse

Rowan, E.L.; Engle, M.A.; Kirby, C.S.; Kraemer, T.F.

2011-01-01

Radium activity data for waters co-produced with oil and gas in New York and Pennsylvania have been compiled from publicly available sources and are presented together with new data for six wells, including one time series. When available, total dissolved solids (TDS), and gross alpha and gross beta particle activities also were compiled. Data from the 1990s and earlier are from sandstone and limestone oil/gas reservoirs of Cambrian-Mississippian age; however, the recent data are almost exclusively from the Middle Devonian Marcellus Shale. The Marcellus Shale represents a vast resource of natural gas the size and significance of which have only recently been recognized. Exploitation of the Marcellus involves hydraulic fracturing of the shale to release tightly held gas. Analyses of the water produced with the gas commonly show elevated levels of salinity and radium. Similarities and differences in radium data from reservoirs of different ages and lithologies are discussed. The range of radium activities for samples from the Marcellus Shale (less than detection to 18,000 picocuries per liter (pCi/L)) overlaps the range for non-Marcellus reservoirs (less than detection to 6,700 pCi/L), and the median values are 2,460 pCi/L and 734 pCi/L, respectively. A positive correlation between the logs of TDS and radium activity can be demonstrated for the entire dataset, and controlling for this TDS dependence, Marcellus shale produced water samples contain statistically more radium than non-Marcellus samples. The radium isotopic ratio, Ra-228/Ra-226, in samples from the Marcellus Shale is generally less than 0.3, distinctly lower than the median values from other reservoirs. This ratio may serve as an indicator of the provenance or reservoir source of radium in samples of uncertain origin.

Subsurface Onondaga reefs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Tyne, A.M.

1995-09-01

Seven subsurface Onondaga reefs have been found in southwestern New York (6) and northwestern Pennsylvania (1). These reefs have had a maximum thickness of about 200 feet and cover an area of a few hundred acres. They are similar to nearly 30 smaller reefs in the same geologic section which have previously been found along the Onodaga outcrop. The discovery well for Onodaga reef gas, although not recognized as such at the time, was the No. 1 Quinlan Oil. The well was drilled in 1933 in the Town of Olean, Cattaraugus County, New York near the New York-Pennsylvania State line.more » The first of the more recent Onondaga reef discoveries occurred in 1967 at Wyckoff in the Town of Jasper, Steuben County, New York. This discovery touched off a leasing and seismic exploration boom in this area of New York. As a result of these studies, two more reefs were discovered in 1971, two in 1974 and the last so far in 1981. These seven reefs have produced 7.1 billion cubic feet of gas. The smallest, Flatstone, has production to data of about 700 million cubic feet. The Onondaga reefs are of basal Onondaga, or Edgecliff, age. The Edgecliff is a light gray, coarsely crystalline, biostromal limestone. Onondaga reefs may have begun forming on somewhat higher parts of the sea floor in crinoid thickets. Because the Onondaga is considerably thicker in that area these so-called {open_quotes}reefs{close_quotes} are buried entirely within the total Onondaga section. They have been called reefs mainly because gas shows have been encountered in the lower Onondaga when it was drilled through by wells aiming for deeper Medina sandstones gas production. Nevertheless, gas production from them has been minimal. The seal consists of surrounding and overlapping black and gray middle Devonian Hamilton shales. The basal portions are surrounded by onlapping upper Onondaga limestones. The source of the gas is believed to be the highly organic Hamilton shale.« less

Biotic immigration events, speciation, and the accumulation of biodiversity in the fossil record

NASA Astrophysics Data System (ADS)

Stigall, Alycia L.; Bauer, Jennifer E.; Lam, Adriane R.; Wright, David F.

2017-01-01

Biotic Immigration Events (BIMEs) record the large-scale dispersal of taxa from one biogeographic area to another and have significantly impacted biodiversity throughout geologic time. BIMEs associated with biodiversity increases have been linked to ecologic and evolutionary processes including niche partitioning, species packing, and higher speciation rates. Yet substantial biodiversity decline has also been documented following BIMEs due to elevated extinction and/or reduced speciation rates. In this review, we develop a conceptual model for biodiversity accumulation that links BIMEs and geographic isolation with local (α) diversity, regional (β) diversity, and global (γ) diversity metrics. Within the model, BIME intervals are characterized by colonization of existing species within new geographic regions and a lack of successful speciation events. Thus, there is no change in γ-diversity, and α-diversity increases at the cost of β-diversity. An interval of regional isolation follows in which lineage splitting results in successful speciation events and diversity increases across all three metrics. Alternation of these two regimes can result in substantial biodiversity accumulation. We tested this conceptual model using a series of case studies from the paleontological record. We primarily focus on two intervals during the Middle through Late Ordovician Period (470-458 Ma): the globally pervasive BIMEs during the Great Ordovician Biodiversification Event (GOBE) and a regional BIME, the Richmondian Invasion. We further test the conceptual model by examining the Great Devonian Interchange, Neogene mollusk migrations and diversification, and the Great American Biotic Interchange. Paleontological data accord well with model predictions. Constraining the mechanisms of biodiversity accumulation provides context for conservation biology. Because α-, β-, and γ-diversity are semi-independent, different techniques should be considered for sustaining various diversity partitions. Maintaining natural migration routes and population sizes among isolated regions are vital to preserving both extant biodiversity and biogeographic pathways requisite for future diversity generation.

The Fossil Fauna of the Islands Region of Western Lake Erie.

ERIC Educational Resources Information Center

Bowe, Lulu M., Comp.

The islands of western Lake Erie are rock-bound isles that abound in rocky outcrops and quarries. The rocks of these islands are of two distinct types, Silurian dolomites and Devonian limestones. The dolomites, exposed in the Bass Islands and Sister Islands are virtually devoid of fossils. Conversely, the limestones of Johnson Island, Marblehead,…

The astronomical rhythm of Late-Devonian climate change (Kowala section, Holy Cross Mountains, Poland)

NASA Astrophysics Data System (ADS)

De Vleeschouwer, David; Rakociński, Michał; Racki, Grzegorz; Bond, David P. G.; Sobień, Katarzyna; Claeys, Philippe

2013-03-01

Rhythmical alternations between limestone and shales or marls characterize the famous Kowala section, Holy Cross Mountains, Poland. Two intervals of this section were studied for evidence of orbital cyclostratigraphy. The oldest interval spans the Frasnian-Famennian boundary, deposited under one of the hottest greenhouse climates of the Phanerozoic. The youngest interval encompasses the Devonian-Carboniferous (D-C) boundary, a pivotal moment in Earth's climatic history that saw a transition from greenhouse to icehouse. For the Frasnian-Famennian sequence, lithological variations are consistent with 405-kyr and 100-kyr eccentricity forcing and a cyclostratigraphic floating time-scale is presented. The interpretation of observed lithological rhythms as eccentricity cycles is confirmed by amplitude modulation patterns in agreement with astronomical theory and by the recognition of precession cycles in high-resolution stable isotope records. The resulting relative time-scale suggests that ˜800 kyr separate the Lower and Upper Kellwasser Events (LKE and UKE, respectively), two periods of anoxia that culminated in massive biodiversity loss at the end of the Frasnian. Th/U and pyrite framboid analyses indicate that during the UKE, oxygen levels remained low for 400 kyr and δ13Corg measurements demonstrate that more than 600 kyr elapsed before the carbon cycle reached a steady state after a +3‰ UKE excursion. The Famennian-Tournaisian (D-C) interval also reveals eccentricity and precession-related lithological variations. Precession-related alternations clearly demonstrate grouping into 100-kyr bundles. The Famennian part of this interval is characterized by several distinctive anoxic black shales, including the Annulata, Dasberg and Hangenberg shales. Our high-resolution cyclostratigraphic framework indicates that those shales were deposited at 2.2 and 2.4 Myr intervals respectively. These durations strongly suggest a link between the long-period (˜2.4 Myr) eccentricity cycle and the development of the Annulata, Dasberg and Hangenberg anoxic shales. It is assumed that these black shales form under transgressive conditions, when extremely high eccentricity promoted the collapse of small continental ice-sheets at the most austral latitudes of western Gondwana.

87Sr/86Sr Across the Devonian-Carboniferous Transition Within the Pho Han Formation, Cat Ba Island, Vietnam: New Data Outside of an Old Orogeny

NASA Astrophysics Data System (ADS)

Paschall, O. C.; Carmichael, S. K.; Dombrowski, A. D.; Batchelor, C. J.; Coleman, D. S.; Waters, J. A.; Königshof, P.

2017-12-01

The Devonian-Carboniferous (D-C) transition is a period of mass extinction and rapid global faunal changes that affected both marine and terrestrial ecosystems. Although the paleontology and carbon and oxygen isotopes across of the D-C boundary have been studied in detail, there is very little continuous 87Sr/86Sr isotope data for this time iteration due to unconformities and/or diagenetic alteration in many sections. Conodont biostratigraphy indicates that the D-C boundary is present within the Pho Han Formation on Cat Ba Island in northeastern Vietnam. This unit represents a starved basinal facies on the South China carbonate platform, and has continuous sedimentation across the D-C boundary. Whole rock geochemical results indicate increased clastic input at the D-C transition, potentially due to the regression observed in many Hangenberg Event localities around the world, but the isolated nature of the basin could instead indicate complete shutdown of the carbonate factory. New 87Sr/86Sr measurements of carbonate across the D-C boundary in the Pho Han Formation indicate oscillating fluctuations from 0.708052 to 0.708672. Many of these values are within the McArthur et al. (2012) LOWESS fit for seawater, with excursions towards higher values tentatively identified at the boundary between the Palmatolepis expansa and lower Siphonodella praesulcata conodont zones, and within the Siphonodella duplicata zone. There is a lack of correlation between 87Sr/86Sr values with whole rock geochemistry and δ18O isotope values across the section, suggesting that these 87Sr/86Sr values are not due to clastic contamination and that the samples have not experienced major diagenetic alteration. The continuous sedimentation in this section and its location in an area far from the Variscan orogeny make this unit a valuable site in which to compare 87Sr/86Sr ratios to existing studies in Europe and North America which experienced substantial sediment shedding from the Appalachian Mountains. McArthur et al. (2012) The Geologic Time Scale, 1: 127-144.

Arizona expects more wildcat drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stremel, K.

1984-01-01

Wildcat oil drilling is on the rise in Arizona. Several remote tests have drawn a considerable amount of industry attention, and could account for a moderate increase in activity. A 3900-ft. Devonian test is planned on High Plains Petroleum Corp.'s Apache County acreage south of the Navajo reservation. This article discusses the oil drilling activity planned for the state this year.