Mixing in three-phase systems: Implications for enhanced oil recovery and unconventional gas extraction

NASA Astrophysics Data System (ADS)

Jimenez-Martinez, J.; Porter, M. L.; Hyman, J.; Carey, J. W.; Viswanathan, H. S.

2015-12-01

Although the mixing of fluids within a porous media is a common process in natural and industrial systems, how the degree of mixing depends on the miscibility of multiple phases is poorly characterized. Often, the direct consequence of miscible mixing is the modification of the resident fluid (brine and hydrocarbons) rheological properties. We investigate supercritical (sc)CO2 displacement and mixing processes in a three-phase system (scCO2, oil, and H2O) using a microfluidics experimental system that accommodates the high pressures and temperatures encountered in fossil fuel extraction operations. The miscibility of scCO2 with the resident fluids, low with aqueous solutions and high with hydrocarbons, impacts the mixing processes that control sweep efficiency in enhanced oil recovery (EOR) and the unlocking of the system in unconventional oil and gas extraction. Using standard volume-averaging techniques we upscale the aqueous phase saturation to the field-scale (i.e., Darcy scale) and interpret the results as a simpler two-phase system. This process allows us to perform a statistical analysis to quantify i) the degree of heterogeneity in the system resulting from the immiscible H2O and ii) how that heterogeneity impacts mixing between scCO2 and oil and their displacement. Our results show that when scCO2 is used for miscible displacement, the presence of an aqueous solution, which is common in secondary and tertiary EOR and unconventional oil and gas extraction, strongly impacts the mixing of scCO2 with the hydrocarbons due to low scCO2-H2O miscibility. H2O, which must be displaced advectively by the injected scCO2, introduces spatio-temporal variability into the system that acts as a barrier between the two miscibile fluids. This coupled with the effect of viscosity contrast, i.e., viscous fingering, has an impact on the mixing of the more miscible pair.

Miscibility, chain packing, and hydration of 1-palmitoyl-2-oleoyl phosphatidylcholine and other lipids in surface phases.

PubMed

Smaby, J M; Brockman, H L

1985-11-01

The miscibility of 1-palmitoyl-2-oleoyl phosphatidylcholine with triolein, 1,2-diolein, 1,3-diolein, 1(3)-monoolein, oleyl alcohol, methyl oleate, oleic acid, and oleyl cyanide (18:1 lipids) was studied at the argon-water interface. The isothermal phase diagrams for the mixtures at 24 degrees were characterized by two compositional regions. At the limit of miscibility with lower mol fractions of 18:1 lipid, the surface pressure was composition-independent, but above a mixture-specific stoichiometry, surface pressure at the limit of miscibility was composition-dependent. From the two-dimensional phase rule, it was determined that at low mol fractions of 18:1 lipids, the surface consisted of phospholipid and a preferred packing array or complex of phospholipid and 18:1 lipid, whereas, above the stoichiometry of the complex, the surface phase consisted of complex and excess 18:1 lipids. In both regions of the phase diagram, mixing along the phase boundary was apparently ideal allowing application of an equation of state described earlier (J. M. Smaby and H. L. Brockman, 1984, Biochemistry, 23:3312-3316). From such analysis, apparent partial molecular areas and hydrations for phospholipid, complex, and 18:1 lipid were obtained. Comparison of these calculated parameters for the complexed and uncomplexed states shows that the aliphatic moieties behave independently of polar head group. The transition of each 18:1 chain to the complexed state involves the loss of about one interfacial water molecule and its corresponding area. For 18:1 lipids with more than one chain another two water molecules per additional chain are present in both states but contribute little to molecular area. In contrast to 18:1 lipids, the phospholipid area and hydration change little upon complexation. The uniformity of chain packing and hydration behavior among 18:1 lipid species contrasts with complex stoichiometries that vary from 0.04 to 0.65. This suggests that the stoichiometry of the preferred packing array is determined by interactions involving the more polar moieties of the 18:1 lipids and the phospholipid.

Multiphase flow of miscible liquids: jets and drops

NASA Astrophysics Data System (ADS)

Walker, Travis W.; Logia, Alison N.; Fuller, Gerald G.

2015-05-01

Drops and jets of liquids that are miscible with the surrounding bulk liquid are present in many processes from cleaning surfaces with the aid of liquid soaps to the creation of biocompatible implants for drug delivery. Although the interactions of immiscible drops and jets show similarities to miscible systems, the small, transient interfacial tension associated with miscible systems create distinct outcomes such as intricate droplet shapes and breakup resistant jets. Experiments have been conducted to understand several basic multiphase flow problems involving miscible liquids. Using high-speed imaging of the morphological evolution of the flows, we have been able to show that these processes are controlled by interfacial tensions. Further multiphase flows include investigating miscible jets, which allow the creation of fibers from inelastic materials that are otherwise difficult to process due to capillary breakup. This work shows that stabilization from the diminishing interfacial tensions of the miscible jets allows various elongated morphologies to be formed.

Molecular driving forces behind the tetrahydrofuran–water miscibility gap

DOE PAGES

Smith, Micholas Dean; Mostofian, Barmak; Petridis, Loukas; ...

2016-01-06

The tetrahydrofuran water binary system exhibits an unusual closed-loop miscibility gap (transitions from a miscible regime to an immiscible regime back to another miscible regime as the temperature increases). Here, using all-atom molecular dynamics simulations, we probe the structural and dynamical behavior of the binary system in the temperature regime of this gap at four different mass ratios, and we compare the behavior of bulk water and tetrahydrofuran. The changes in structure and dynamics observed in the simulations indicate that the temperature region associated with the miscibility gap is distinctive. Within the miscibility-gap temperature region, the self diffusion of watermore » is significantly altered and the second virial coefficients (pair interaction strengths) show parabolic-like behavior. Altogether, the results suggest that the gap is the result of differing trends with temperature of minor structural changes, which produces interaction virials with parabolic temperature dependence near the miscibility gap.« less

Thermodynamics and Phase Behavior of Miscible Polymer Blends in the Presence of Supercritical Carbon Dioxide

NASA Astrophysics Data System (ADS)

Young, Nicholas Philip

The design of environmentally-benign polymer processing techniques is an area of growing interest, motivated by the desire to reduce the emission of volatile organic compounds. Recently, supercritical carbon dioxide (scCO 2) has gained traction as a viable candidate to process polymers both as a solvent and diluent. The focus of this work was to elucidate the nature of the interactions between scCO2 and polymers in order to provide rational insight into the molecular interactions which result in the unexpected mixing thermodynamics in one such system. The work also provides insight into the nature of pairwise thermodynamic interactions in multicomponent polymer-polymer-diluent blends, and the effect of these interactions on the phase behavior of the mixture. In order to quantify the strength of interactions in the multicomponent system, the binary mixtures were characterized individually in addition to the ternary blend. Quantitative analysis of was made tractable through the use of a model miscible polymer blend containing styrene-acrylonitrile copolymer (SAN) and poly(methyl methacrylate) (dPMMA), a mixture which has been considered for a variety of practical applications. In the case of both individual polymers, scCO2 is known to behave as a diluent, wherein the extent of polymer swelling depends on both temperature and pressure. The solubility of scCO 2 in each polymer as a function of temperature and pressure was characterized elsewhere. The SAN-dPMMA blend clearly exhibited lower critical solution temperature behavior, forming homogeneous mixtures at low temperatures and phase separating at elevated temperature. These measurements allowed the determination of the Flory-Huggins interaction parameter chi23 for SAN (species 2) and dPMMA (species 3) as a function of temperature at ambient pressure, in the absence of scCO2 (species 1). Characterization of the phase behavior of the multicomponent (ternary) mixture was also carried out by SANS. An in situ SANS environment was developed to allow measurement of blend miscibility in the presence of scCO2. The pressure-temperature phase behavior of the system could be mapped by approaching the point of phase separation by spinodal decomposition through pressure increases at constant temperature. For a roughly symmetric mixture of SAN and dPMMA, the temperature at which phase separation occurred could be decreased by over 125 °C. The extent to which the phase behavior of the multicomponent system could be tuned motivated further investigation into the interactions present within the homogeneous mixtures. Analysis of the SANS results for homogeneous mixtures was undertaken using a new multicomponent formalism of the random phase approximation theory. The scattering profiles obtained from the scCO2-SAN-dPMMA system could be predicted with reasonable success. The success of the theoretical predictions was facilitated by directly employing the interactions found in the binary experiments. Exploitation of the condition of homogeneity with respect to chemical potential allowed determination of interaction parameters for scCO2-SAN and 2-dPMMA within the multicomponent mixture (chi12 and chi13, respectively). Studying this system over a large range of the supercritical regime yielded insight on the nature of interactions in the system. Near the critical point of scCO 2, chi12 and chi13 increase monotonically as a function of pressure. Conversely, at elevated temperature away from the critical point, the interaction parameters are found to go through a minimum as a pressure increases. Analysis of the critical phenomenon associated with scCO2 suggests that the observed dependence of chi12 and chi13 on pressure are related to the magnitude of scCO 2 density fluctuations and the proximity of the system to the so-called density fluctuation ridge. By tuning the system parameters of the multicomponent mixture, the phase behavior can be altered through the balance of pairwise interactions been the constituent species. The presence of scCO2 in the mixtures appears to eliminate the existence of the metastable state that epitomizes most polymer-polymer mixtures. Thus it is shown that knowledge of the individual pairwise interactions in such multicomponent mixtures can greatly influence the resulting phase behavior, and provide insight into the design of improved functional materials with decreased environmental impacts.

Integrated Reservoir Modeling of CO2-EOR Performance and Storage Potential in the Farnsworth Field Unit, Texas.

NASA Astrophysics Data System (ADS)

Ampomah, W.; Balch, R. S.; Cather, M.; Dai, Z.

2017-12-01

We present a performance assessment methodology and storage potential for CO2 enhanced oil recovery (EOR) in partially depleted reservoirs. A three dimensional heterogeneous reservoir model was developed based on geological, geophysics and engineering data from Farnsworth field Unit (FWU). The model aided in improved characterization of prominent rock properties within the Pennsylvanian aged Morrow sandstone reservoir. Seismic attributes illuminated previously unknown faults and structural elements within the field. A laboratory fluid analysis was tuned to an equation of state and subsequently used to predict the thermodynamic minimum miscible pressure (MMP). Datasets including net-to-gross ratio, volume of shale, permeability, and burial history were used to model initial fault transmissibility based on Sperivick model. An improved history match of primary and secondary recovery was performed to set the basis for a CO2 flood study. The performance of the current CO2 miscible flood patterns was subsequently calibrated to historical production and injection data. Several prediction models were constructed to study the effect of recycling, addition of wells and /or new patterns, water alternating gas (WAG) cycles and optimum amount of CO2 purchase on incremental oil production and CO2 storage in the FWU. The history matching study successfully validated the presence of the previously undetected faults within FWU that were seen in the seismic survey. The analysis of the various prediction scenarios showed that recycling a high percentage of produced gas, addition of new wells and a gradual reduction in CO2 purchase after several years of operation would be the best approach to ensure a high percentage of recoverable incremental oil and sequestration of anthropogenic CO2 within the Morrow reservoir. Larger percentage of stored CO2 were dissolved in residual oil and less amount existed as supercritical free CO2. The geomechanical analysis on the caprock proved to an excellent seal to ensure long-term security of injected CO2.

Miscibility and interactions of animal and plant sterols with choline plasmalogen in binary and multicomponent model systems.

PubMed

Hąc-Wydro, Katarzyna; Luty, Katarzyna

2014-04-01

In this work miscibility and interactions of sterols with choline plasmalogen (PC-plasm) in Langmuir monolayers were studied. Moreover, the properties of cholesterol/phosphatidylcholine/plasmalogen mixtures of different PC-plasm concentration were investigated. The foregoing systems were treated as a model of cancer cell membranes, which are of higher plasmalogen level than normal cells. Finally, the influence of β-sitosterol and stigmasterol (phytosterols differing in anticancer potency) on these mixtures was verified. The properties of monolayers were analyzed based on the parameters derived from the surface pressure-area isotherms and images taken with Brewster Angle Microscope. It was found that at 30% of sterol in sterol/plasmalogen monolayer the lipids are immiscible and 3D crystallites are formed within the film. Cholesterol molecules mix favorably with PC-plasm at Xchol ≥ 0.5, while the investigated phytosterols only at their prevailing proportion in binary system. The increase of choline plasmalogen in cholesterol/phosphatidylcholine monolayer causes destabilization of the system. Moreover, the incorporation of phytosterols into cholesterol/phosphatidylcholine+PC-plasm mixtures disturbed membrane morphology and this effect was stronger for β-sitosterol as compared to stigmasterol. It was concluded that the presence of vinyl ether bond at sn-1 position in PC-plasm molecule strongly affects miscibility of choline plasmalogen with sterols. The comparison of the collected data with those reported in literature allowed one to conclude that miscibility and interactions of sterols with PC-plasm are less favorable than those with phosphatidylcholine. It was also suggested that overexpression of plasmalogens in cancer cell membranes may be a factor differentiating sensitivity of cells to anticancer effect of phytosterols. Copyright © 2014 Elsevier B.V. All rights reserved.

Improvement of Sweep Efficiency in Gasflooding

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kishore Mohanty

2008-12-31

Miscible and near-miscible gasflooding has proven to be one of the few cost effective enhance oil recovery techniques in the past twenty years. As the scope of gas flooding is being expanded to medium viscosity oils in shallow sands in Alaska and shallower reservoirs in the lower 48, there are questions about sweep efficiency in near-miscible regions. The goal of this research is to evaluate sweep efficiency of various gas flooding processes in a laboratory model and develop numerical tools to estimate their effectiveness in the field-scale. Quarter 5-spot experiments were conducted at reservoir pressure to evaluate the sweep efficiencymore » of gas, WAG and foam floods. The quarter 5-spot model was used to model vapor extraction (VAPEX) experiments at the lab scale. A streamline-based compositional simulator and a commercial simulator (GEM) were used to model laboratory scale miscible floods and field-scale pattern floods. An equimolar mixture of NGL and lean gas is multicontact miscible with oil A at 1500 psi; ethane is a multicontact miscible solvent for oil B at pressures higher than 607 psi. WAG improves the microscopic displacement efficiency over continuous gas injection followed by waterflood in corefloods. WAG improves the oil recovery in the quarter 5-spot over the continuous gas injection followed by waterflood. As the WAG ratio increases from 1:2 to 2:1, the sweep efficiency in the 5-spot increases, from 39.6% to 65.9%. A decrease in the solvent amount lowers the oil recovery in WAG floods, but significantly higher amount of oil can be recovered with just 0.1 PV solvent injection over just waterflood. Use of a horizontal production well lowers the oil recovery over the vertical production well during WAG injection phase in this homogeneous 5-spot model. Estimated sweep efficiency decreases from 61.5% to 50.5%. In foam floods, as surfactant to gas slug size ratio increases from 1:10 to 1:1, oil recovery increases. In continuous gasflood VAPEX processes, as the distance between the injection well and production well decreases, the oil recovery and rate decreases in continuous gasflood VAPEX processes. Gravity override is observed for gas injection simulations in vertical (X-Z) cross-sections and 3-D quarter five spot patterns. Breakthrough recovery efficiency increases with the viscous-to-gravity ratio in the range of 1-100. The speed up for the streamline calculations alone is almost linear with the number of processors. The overall speed up factor is sub-linear because of the overhead time spent on the finite-difference calculation, inter-processor communication, and non-uniform processor load. Field-scale pattern simulations showed that recovery from gas and WAG floods depends on the vertical position of high permeability regions and k{sub v}/k{sub h} ratio. As the location of high permeability region moves down and k{sub v}/k{sub h} ratio decreases, oil recovery increases. There is less gravity override. The recovery from the field model is lower than that from the lab 5-spot model, but the effect of WAG ratio is similar.« less

Initial temperatures effect on the mixing efficiency and flow modes in T-shaped micromixer

NASA Astrophysics Data System (ADS)

Lobasov, A. S.; Shebeleva, A. A.

2017-09-01

Flow patterns and mixing of liquids with different initial temperatures in T-shaped micromixers are numerically investigated on the Reynolds number range from 1 to 250. The temperature of the one of mixing media was set equal to 20°C, while the temperature of the another mixing media was varied from 10°C to 50°C its effect on the flow structure and the mixing was studied. The dependences of the mixing efficiency and the pressure difference in this mixer on the difference in initial temperatures of miscible fluids and the Reynolds number were obtained. It was shown that the presence of a difference in initial temperatures of miscible fluids leads to a shift of flow regimes and the flow and mixing of two fluids with different initial temperatures can be considered as self-similar pattern with regard to the reduced Reynolds number.

New immiscible refrigeration lubricant for HFCs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sunami, Motoshi; Takigawa, Katsuya; Suda, Satoshi

1995-12-31

This study examines the capability of a family of very low-viscosity alkylbenzenes (AB) used in high-side rotary compressors for HFCs. In the development of refrigeration lubricants for HFCs, miscibility is one of the most important problems to be solved. Therefore, PAG (polyalkylene glycols) and POE (polyol esters), which have good miscibility, have been applied in new HFC applications. However, it is difficult for these lubricants to maintain long-term durability in high-side rotary compressors. In friction tests under high HFC pressure, ABs with much lower viscosities than mineral oil maintained a much stronger oil film than the combination of mineral oil/R-12more » or POE/HFCs. These results were also proven by compressor durability tests. From the study of the solubility of ABs and HFCs, it is suggested that the total amount of refrigerant can be reduced because HFCs are barely soluble with ABs inside the high-side shell.« less

Miscibility and Morphology of Poly(lactic ACID)/POLY(Β-HYDROXYBUTYRATE) Blends

NASA Astrophysics Data System (ADS)

Tri Phuong, Nguyen; Guinault, Alain; Sollogoub, Cyrille

2011-01-01

The miscibility and morphology of poly(lactic)acid (PLA)/polyβ-hydroxybutyrate (PHB) prepared by melt blending method were investigated by Fourier transform infrared (FTIR), Differential scanning calorimetry (DSC), melt rheology and scanning electron microscopy (SEM) observations. FTIR and DSC methods present some limits to examine the miscibility state of PLA/PHB blends. This drawback can be overcome with the Cole-Cole method by observing the η" = f(η') curves to confirm the miscibility of semicrystalline PLA/ semicrystalline PHB blends. MEB micrographs of fractured surface of blends were also used to investigate the miscibility of these blends.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barnhill, William C.; Qu, Jun; Luo, Huimin

In our previous work we suggest great potential for a phosphonium-organophosphate ionic liquid (IL) as an antiwear lubricant additive. In this study, a set of five ILs were carefully designed and synthesized, with identical organophosphate anions but dissimilar phosphonium cations, to allow systematic investigation of the effects of cation alkyl chain length and symmetry on physicochemical and tribological properties. Symmetric cations with shorter alkyl chains seem to increase the density and thermal stability due to closer packing. On the other hand, either higher cation symmetry or longer alkyl moieties induce a higher viscosity, though the viscosity index is dependent moremore » on molecular mass than on symmetry. While a larger cation size generally increases an IL’s solubility in nonpolar hydrocarbon oils, six-carbon seems to be the critical minimum alkyl chain length for high oil miscibility. Both the two ILs, that are mutually oil miscible, have demonstrated promising lubricating performance at 1.04% treat rate, though the symmetric-cation IL moderately outperformed the asymmetric-cation IL. Moreover, characterizations on the tribofilm formed by the best-performing symmetric-cation IL revealed the film thickness, nanostructure, and chemical composition. Our results provide fundamental insights for future molecular design in developing oil-soluble ILs as lubricant additives.« less

Prediction of solubility parameters and miscibility of pharmaceutical compounds by molecular dynamics simulations.

PubMed

Gupta, Jasmine; Nunes, Cletus; Vyas, Shyam; Jonnalagadda, Sriramakamal

2011-03-10

The objectives of this study were (i) to develop a computational model based on molecular dynamics technique to predict the miscibility of indomethacin in carriers (polyethylene oxide, glucose, and sucrose) and (ii) to experimentally verify the in silico predictions by characterizing the drug-carrier mixtures using thermoanalytical techniques. Molecular dynamics (MD) simulations were performed using the COMPASS force field, and the cohesive energy density and the solubility parameters were determined for the model compounds. The magnitude of difference in the solubility parameters of drug and carrier is indicative of their miscibility. The MD simulations predicted indomethacin to be miscible with polyethylene oxide and to be borderline miscible with sucrose and immiscible with glucose. The solubility parameter values obtained using the MD simulations values were in reasonable agreement with those calculated using group contribution methods. Differential scanning calorimetry showed melting point depression of polyethylene oxide with increasing levels of indomethacin accompanied by peak broadening, confirming miscibility. In contrast, thermal analysis of blends of indomethacin with sucrose and glucose verified general immiscibility. The findings demonstrate that molecular modeling is a powerful technique for determining the solubility parameters and predicting miscibility of pharmaceutical compounds. © 2011 American Chemical Society

Application of film-casting technique to investigate drug-polymer miscibility in solid dispersion and hot-melt extrudate.

PubMed

Parikh, Tapan; Gupta, Simerdeep Singh; Meena, Anuprabha K; Vitez, Imre; Mahajan, Nidhi; Serajuddin, Abu T M

2015-07-01

Determination of drug-polymer miscibility is critical for successful development of solid dispersions. This report details a practical method to predict miscibility and physical stability of drug with various polymers in solid dispersion and, especially, in melt extrudates by applying a film-casting technique. Mixtures of itraconazole (ITZ) with hydroxypropylmethylcellulose phthalate (HPMCP), Kollidon(®) VA 64, Eudragit(®) E PO, and Soluplus(®) were film-casted, exposed to 40°C/75% RH for 1 month and then analyzed using differential scanning calorimetry (DSC), powder X-ray diffractometry, and polarized light microscopy (PLM). ITZ had the highest miscibility with HPMCP, being miscible at drug to polymer ratio of 6:4 (w/w). There was a downward trend of lower miscibility with Soluplus(®) (miscible at 3:7, w/w, and a few microcrystals present at 4:6, w/w), Kollidon(®) VA 64 (2:8, w/w) and Eudragit(®) E PO (<1:9, w/w). PLM was found more sensitive to detect drug crystallization than DSC and powder X-ray diffractometry. There was general correlation between results of film casting and hot-melt extrusion (HME) using a twin screw extruder. For ITZ-Soluplus(®) mixtures, HME at 4:6 (w/w) resulted in a single phase, whereas drug crystallization was observed at higher drug load. HME of ITZ-Kollidon(®) VA 64 mixtures also correlated well with the miscibility predicted by film casting. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

Miscibility and Speciation in the Water/carbon Dioxide System

NASA Astrophysics Data System (ADS)

Abramson, E.; Bollengier, O.; Brown, J. M.

2017-12-01

We have been exploring fluid-fluid solubilities and speciation in mixed systems of CO2-H2O. Fluid-fluid immiscibility extends to the highest pressures and temperatures yet explored (7 GPa, 700K). In this region, commonly used COH fluid models agree neither with the data nor among themselves. The range of immiscibility is extended by addition of NaCl, but miscibility limits determined in preliminary experiments are not as expected from extrapolation of lower pressure (<0.2 GPa) results. For majority-water systems (XCO2<0.5) an abrupt increase of solubility with pressure is linked to an observed change in speciation as CO2(aq) reacts with water. The identity of the newly formed species is, as of the writing of this abstract, unknown, but presumed to be either H2CO3 or HCO3-. A reasonable match between the observed equilibria and an application of HKF theory suggests that the new species is, indeed, HCO3-, but with a Raman frequency shifted from that found in the dilute aqueous solution. Application of HKF theory to the CO2(f)-CO2(aq) equilibrium suffers from an incompatibility of the usual formulation of the theory with known molar volumes of CO2(f) at higher pressures. On the basis of these studies we conclude that models of CO2-H2O fluids must take into account major changes in speciation, and that simple equations-of-state, of a few fitted parameters, will not afford an adequate description of such fluids. "First principles" models, tested against real data, seem more likely to yield the desired results. This statement extends as well to the calculation of the dielectric constants of these mixed fluids, the basis of ionic solution chemistry. Further, semi-empirical formulations of solution thermodynamics, which function well at pressures of kbars, ought to be re-worked for use over larger pressure ranges.

Monte Carlo simulation of star/linear and star/star blends with chemically identical monomers

NASA Astrophysics Data System (ADS)

Theodorakis, P. E.; Avgeropoulos, A.; Freire, J. J.; Kosmas, M.; Vlahos, C.

2007-11-01

The effects of chain size and architectural asymmetry on the miscibility of blends with chemically identical monomers, differing only in their molecular weight and architecture, are studied via Monte Carlo simulation by using the bond fluctuation model. Namely, we consider blends composed of linear/linear, star/linear and star/star chains. We found that linear/linear blends are more miscible than the corresponding star/star mixtures. In star/linear blends, the increase in the volume fraction of the star chains increases the miscibility. For both star/linear and star/star blends, the miscibility decreases with the increase in star functionality. When we increase the molecular weight of linear chains of star/linear mixtures the miscibility decreases. Our findings are compared with recent analytical and experimental results.

Drop impact onto a thin film: Miscibility effect

NASA Astrophysics Data System (ADS)

Chen, Ningli; Chen, H.; Amirfazli, A.

2017-09-01

In this work a systematic experimental study was performed to understand the process of liquid drop impact onto a thin film made of a different liquid from drop. The drop and film liquids can be miscible or immiscible. Three general outcomes of deposition, crown formation without splashing, and splashing, were observed in the advancing phase of the drop impact onto a solid surface covered by either a miscible or an immiscible thin film. However, for a miscible film, a larger Weber number and film thickness are needed for the formation of a crown and splashing comparing with immiscible cases. The advancing phase of drop impact onto a thin immiscible film with a large viscosity is similar to that of drop impact onto a dry surface; for a miscible film viscous film, the behavior is far from that of a dry surface. The behavior of liquid lamella in the receding phase of drop impact onto a thin miscible film is reported for the first time. The results show that immiscibility is not a necessary condition for the existence of a receding phase. The existence of a receding phase is highly dependent on the interfacial tension between the drop and the film. The miscibility can significantly affect the receding morphology as it will cause mixing of the two liquids.

Transient Interfacial Phenomena in Miscible Polymer Systems (TIPMPS)

NASA Technical Reports Server (NTRS)

Pojman, John A.; Bessonov, Nicholas; Volpert, Vitaly; Wilke, Hermann

2003-01-01

Almost one hundred years ago Korteweg published a theory of how stresses could be induced in miscible fluids by concentration gradients, causing phenomena that would appear to be the same as with immiscible fluids. Miscible fluids could manifest a transient or effective interfacial tension (EIT). To this day, there has been no definitive experiment to confirm Korteweg's model but numerous fascinating and suggestive experiments have been reported. The goal of TIPMPS is to answer the question: Can concentration and temperature gradients in miscible materials induce stresses that cause convection? Many polymer processes involving miscible monomer and polymer systems could be affected by fluid flow and so this work could help understand miscible polymer processing, not only in microgravity, but also on earth. Demonstrating the existence of this phenomenon in miscible fluids will open up a new area of study for materials science. The science objectives of TIPMPS are: (1) Determine if convection can be induced by variation of the width of a miscible interface; (2) Determine if convection can be induced by variation of temperature along a miscible interface; (3) Determine if convection can be induced by variation of conversion along a miscible interface An interface between two miscible fluids can best be created via a spatially-selective photopolymerization of dodecyl acrylate with a photoinitiator, which allows the creation of precise and accurate concentration gradients between polymer and monomer. Optical techniques will be used to measure the refractive index variation caused by the resultant temperature and concentration fields. The viscosity of the polymer will be measured from the increase in the fluorescence of pyrene. Because the large concentration and temperature gradients cause buoyancy-driven convection that prevents the observation of the predicted flows, the experiment must be done in microgravity. In this report, we will consider our efforts to estimate the square gradient parameter, k, and our use of the estimates in modeling of the planned TIPMPS experiments. We developed a model consisting of the heat and diffusion equations with convective terms and of the Navier-Stokes equations with an additional volume force written in the form of the Korteweg stresses arising from nonlocal interaction in the fluid. The fluid's viscosity dependence on polymer conversion and temperature was taken from measurements of poly(dodecyl acrylate). Numerical modeling demonstrated that significant flows would arise for conditions corresponding to the planned experiments.

Dialysis without membranes: how and why?

PubMed

Leonard, Edward F; West, Alan C; Shapley, Nina C; Larsen, Mona U

2004-01-01

Dialysis between two flowing, miscible fluids without an intervening membrane enhances both the transport rate and biocompatibility. Unfortunately, it also presents serious challenges, including the loss of pressure as a driving force for volume transport, the need for sterile dialysate in greater quantity than in conventional dialysis, the possibility of unacceptable protein loss, and even the possibility of blood cell loss. This paper quantifies these advantages and disadvantages, and evaluate the means by which the latter might be surmounted. Preliminary data are provided to show that stable flows of one fluid sheathing another, miscible fluid are achievable and that molecular exchange between the fluids is orderly and in qualitative agreement with the theory. Extension of the concept to other blood purification tasks, especially in the treatment of liver failure and various macromolecular separations, is also discussed. In conclusion, membraneless separations will require a secondary process and a recycle stream. Under these conditions, its advantages can be preserved and its disadvantages controlled. Copyright 2004 S. Karger AG, Basel

Supramolecular Phase-Selective Gelation by Peptides Bearing Side-Chain Azobenzenes: Effect of Ultrasound and Potential for Dye Removal and Oil Spill Remediation

PubMed Central

Bachl, Jürgen; Oehm, Stefan; Mayr, Judith; Cativiela, Carlos; Marrero-Tellado, José Juan; Díaz Díaz, David

2015-01-01

Phase selective gelation (PSG) of organic phases from their non-miscible mixtures with water was achieved using tetrapeptides bearing a side-chain azobenzene moiety. The presence of the chromophore allowed PSG at the same concentration as the minimum gelation concentration (MGC) necessary to obtain the gels in pure organic phases. Remarkably, the presence of the water phase during PSG did not impact the thermal, mechanical, and morphological properties of the corresponding organogels. In the case of miscible oil/water mixtures, the entire mixture was gelled, resulting in the formation of quasi-hydrogels. Importantly, PSG could be triggered at room temperature by ultrasound treatment of the mixture or by adding ultrasound-aided concentrated solution of the peptide in an oil-phase to a mixture of the same oil and water. Moreover, the PSG was not affected by the presence of salts or impurities existing in water from natural sources. The process could be scaled-up, and the oil phases (e.g., aromatic solvents, gasoline, diesel fuel) recovered almost quantitatively after a simple distillation process, which also allowed the recovery and reuse of the gelator. Finally, these peptidic gelators could be used to quantitatively remove toxic dyes from aqueous solutions. PMID:26006247

Phosphonium-Organophosphate Ionic Liquids as Lubricant Additives: Effects of Cation Structure on Physicochemical and Tribological Characteristics

DOE PAGES

Barnhill, William C.; Qu, Jun; Luo, Huimin; ...

2014-11-17

In our previous work we suggest great potential for a phosphonium-organophosphate ionic liquid (IL) as an antiwear lubricant additive. In this study, a set of five ILs were carefully designed and synthesized, with identical organophosphate anions but dissimilar phosphonium cations, to allow systematic investigation of the effects of cation alkyl chain length and symmetry on physicochemical and tribological properties. Symmetric cations with shorter alkyl chains seem to increase the density and thermal stability due to closer packing. On the other hand, either higher cation symmetry or longer alkyl moieties induce a higher viscosity, though the viscosity index is dependent moremore » on molecular mass than on symmetry. While a larger cation size generally increases an IL’s solubility in nonpolar hydrocarbon oils, six-carbon seems to be the critical minimum alkyl chain length for high oil miscibility. Both the two ILs, that are mutually oil miscible, have demonstrated promising lubricating performance at 1.04% treat rate, though the symmetric-cation IL moderately outperformed the asymmetric-cation IL. Moreover, characterizations on the tribofilm formed by the best-performing symmetric-cation IL revealed the film thickness, nanostructure, and chemical composition. Our results provide fundamental insights for future molecular design in developing oil-soluble ILs as lubricant additives.« less

Steric Pressure among Membrane-Bound Polymers Opposes Lipid Phase Separation.

PubMed

Imam, Zachary I; Kenyon, Laura E; Carrillo, Adelita; Espinoza, Isai; Nagib, Fatema; Stachowiak, Jeanne C

2016-04-19

Lipid rafts are thought to be key organizers of membrane-protein complexes in cells. Many proteins that interact with rafts have bulky polymeric components such as intrinsically disordered protein domains and polysaccharide chains. Therefore, understanding the interaction between membrane domains and membrane-bound polymers provides insights into the roles rafts play in cells. Multiple studies have demonstrated that high concentrations of membrane-bound polymeric domains create significant lateral steric pressure at membrane surfaces. Furthermore, our recent work has shown that lateral steric pressure at membrane surfaces opposes the assembly of membrane domains. Building on these findings, here we report that membrane-bound polymers are potent suppressors of membrane phase separation, which can destabilize lipid domains with substantially greater efficiency than globular domains such as membrane-bound proteins. Specifically, we created giant vesicles with a ternary lipid composition, which separated into coexisting liquid ordered and disordered phases. Lipids with saturated tails and poly(ethylene glycol) (PEG) chains conjugated to their head groups were included at increasing molar concentrations. When these lipids were sparse on the membrane surface they partitioned to the liquid ordered phase. However, as they became more concentrated, the fraction of GUVs that were phase-separated decreased dramatically, ultimately yielding a population of homogeneous membrane vesicles. Experiments and physical modeling using compositions of increasing PEG molecular weight and lipid miscibility phase transition temperature demonstrate that longer polymers are the most efficient suppressors of membrane phase separation when the energetic barrier to lipid mixing is low. In contrast, as the miscibility transition temperature increases, longer polymers are more readily driven out of domains by the increased steric pressure. Therefore, the concentration of shorter polymers required to suppress phase separation decreases relative to longer polymers. Collectively, our results demonstrate that crowded, membrane-bound polymers are highly efficient suppressors of phase separation and suggest that the ability of lipid domains to resist steric pressure depends on both their lipid composition and the size and concentration of the membrane-bound polymers they incorporate.

Effect of PEO molecular weight on the miscibility and dynamics in epoxy/PEO blends.

PubMed

Lu, Shoudong; Zhang, Rongchun; Wang, Xiaoliang; Sun, Pingchuan; Lv, Weifeng; Liu, Qingjie; Jia, Ninghong

2015-11-01

In this work, the effect of poly(ethylene oxide) (PEO) molecular weight in blends of epoxy (ER) and PEO on the miscibility, inter-chain weak interactions and local dynamics were systematically investigated by multi-frequency temperature modulation DSC and solid-state NMR techniques. We found that the molecular weight (M(w)) of PEO was a crucial factor in controlling the miscibility, chain dynamics and hydrogen bonding interactions between PEO and ER. A critical PEO molecular weight (M(crit)) around 4.5k was found. PEO was well miscible with ER when the molecular weight was below M(crit), where the chain motion of PEO was restricted due to strong inter-chain hydrogen bonding interactions. However, for the blends with high molecular weight PEO (M(w) > M(crit)), the miscibility between PEO and ER was poor, and most of PEO chains were considerably mobile. Finally, polarization inversion spin exchange at magic angle (PISEMA) solid-state NMR experiment further revealed the different mobility of the PEO in ER/PEO blends with different molecular weight of PEO at molecular level. Based on the DSC and NMR results, a tentative model was proposed to illustrate the miscibility in ER/PEO blends.

Apparatus and method for pumping hot, erosive slurry of coal solids in coal derived, water immiscible liquid

DOEpatents

Ackerman, Carl D.

1983-03-29

An apparatus for and method of pumping hot, erosive slurry of coal solids in a coal derived, water immiscible liquid to higher pressure involves the use of a motive fluid which is miscible with the liquid of the slurry. The apparatus includes a pump 12, a remote check valve 14 and a chamber 16 between and in fluid communication with the pump 12 and check valve 14 through conduits 18,20. Pump 12 exerts pressure on the motive fluid and thereby on the slurry through a concentration gradient of coal solids within chamber 16 to alternately discharge slurry under pressure from the outlet port of check valve 14 and draw slurry in through the inlet port of check valve 14.

Deformation of interface in a partially miscible system during favorable displacement

NASA Astrophysics Data System (ADS)

Suzuki, Ryuta; Nagatsu, Yuichiro; Mishra, Manoranjan; Ban, Takahiko

2017-11-01

The Saffman-Taylor instability triggers a well-known viscous fingering (VF, called unfavorable displacement), occurring when a less viscous fluid displaces a more viscous one in porous media or in a Hele-Shaw cell because the boundary of the two fluids becomes hydrodynamically unstable. In the reverse situation (called favorable displacement) in which a more viscous fluid displaces a less viscous one, no instabilities occur due to hydrodynamically stable system. It has been reported that the favorable displacements become unstable by several physicochemical effects. So far, studies of both displacements have focused on fluids that are either fully miscible or immiscible. However, little attention has been paid to displacements in partially miscible system. Here, we have discovered that a partial miscibility triggers fingering instability in a favorable displacement without any chemical reactions. The occurrence of this new instability is induced by not hydrodynamic effects but a thermodynamic effect that is so-called Korteweg effect in which convection is induced during phase separation process in a partially miscible system.

Hydrodynamic instabilities in miscible fluids

NASA Astrophysics Data System (ADS)

Truzzolillo, Domenico; Cipelletti, Luca

2018-01-01

Hydrodynamic instabilities in miscible fluids are ubiquitous, from natural phenomena up to geological scales, to industrial and technological applications, where they represent the only way to control and promote mixing at low Reynolds numbers, well below the transition from laminar to turbulent flow. As for immiscible fluids, the onset of hydrodynamic instabilities in miscible fluids is directly related to the physics of their interfaces. The focus of this review is therefore on the general mechanisms driving the growth of disturbances at the boundary between miscible fluids, under a variety of forcing conditions. In the absence of a regularizing mechanism, these disturbances would grow indefinitely. For immiscible fluids, interfacial tension provides such a regularizing mechanism, because of the energy cost associated to the creation of new interface by a growing disturbance. For miscible fluids, however, the very existence of interfacial stresses that mimic an effective surface tension is debated. Other mechanisms, however, may also be relevant, such as viscous dissipation. We shall review the stabilizing mechanisms that control the most common hydrodynamic instabilities, highlighting those cases for which the lack of an effective interfacial tension poses deep conceptual problems in the mathematical formulation of a linear stability analysis. Finally, we provide a short overview on the ongoing research on the effective, out of equilibrium interfacial tension between miscible fluids.

Characterization of interfaces in Binary and Ternary Polymer Blends by Positron Lifetime Spectroscopy

NASA Astrophysics Data System (ADS)

Ranganathaiah, C.

2015-06-01

A miscible blend is a single-phase system with compact packing of the polymeric chains/segments due configuration/conformational changes upon blending. Differential Scanning Calorimetry (DSC) is the most employed method to ascertain whether the blend is miscible or immiscible. Positron Lifetime Spectroscopy (PLS) has been employed in recent times to study miscibility properties of polymer blends by monitoring the ortho-Positronium annihilation lifetimes as function of composition. However, just free volume monitoring and the DSC methods fail to provide the composition dependent miscibility of blends. To overcome this limitation, an alternative approach based on hydrodynamic interactions has been developed to derive this information using the same o-Ps lifetime measurements. This has led to the development of a new method of measuring composition dependent miscibility level in binary and ternary polymer blends. Further, the new method also provides interface characteristics for immiscible blends. The interactions between the blend components has a direct bearing on the strength of adhesion at the interface and hence the hydrodynamic interaction. Understanding the characteristic of interfaces which decides the miscibility level of the blend and their end applications is made easy by the present method. The efficacy of the present method is demonstrated for few binary and ternary blends.

49 CFR 192.623 - Maximum and minimum allowable operating pressure; Low-pressure distribution systems.

Code of Federal Regulations, 2012 CFR

2012-10-01

... distribution systems. (a) No person may operate a low-pressure distribution system at a pressure high enough to...) No person may operate a low pressure distribution system at a pressure lower than the minimum... 49 Transportation 3 2012-10-01 2012-10-01 false Maximum and minimum allowable operating pressure...

49 CFR 192.623 - Maximum and minimum allowable operating pressure; Low-pressure distribution systems.

Code of Federal Regulations, 2011 CFR

2011-10-01

... distribution systems. (a) No person may operate a low-pressure distribution system at a pressure high enough to...) No person may operate a low pressure distribution system at a pressure lower than the minimum... 49 Transportation 3 2011-10-01 2011-10-01 false Maximum and minimum allowable operating pressure...

49 CFR 192.623 - Maximum and minimum allowable operating pressure; Low-pressure distribution systems.

Code of Federal Regulations, 2013 CFR

2013-10-01

... distribution systems. (a) No person may operate a low-pressure distribution system at a pressure high enough to...) No person may operate a low pressure distribution system at a pressure lower than the minimum... 49 Transportation 3 2013-10-01 2013-10-01 false Maximum and minimum allowable operating pressure...

49 CFR 192.623 - Maximum and minimum allowable operating pressure; Low-pressure distribution systems.

Code of Federal Regulations, 2014 CFR

2014-10-01

... distribution systems. (a) No person may operate a low-pressure distribution system at a pressure high enough to...) No person may operate a low pressure distribution system at a pressure lower than the minimum... 49 Transportation 3 2014-10-01 2014-10-01 false Maximum and minimum allowable operating pressure...

49 CFR 192.623 - Maximum and minimum allowable operating pressure; Low-pressure distribution systems.

Code of Federal Regulations, 2010 CFR

2010-10-01

... distribution systems. (a) No person may operate a low-pressure distribution system at a pressure high enough to...) No person may operate a low pressure distribution system at a pressure lower than the minimum... 49 Transportation 3 2010-10-01 2010-10-01 false Maximum and minimum allowable operating pressure...

Influence of miscibility phenomenon on crystalline polymorph transition in poly(vinylidene fluoride)/acrylic rubber/clay nanocomposite hybrid.

PubMed

Abolhasani, Mohammad Mahdi; Naebe, Minoo; Jalali-Arani, Azam; Guo, Qipeng

2014-01-01

In this paper, intercalation of nanoclay in the miscible polymer blend of poly(vinylidene fluoride) (PVDF) and acrylic rubber(ACM) was studied. X-ray diffraction was used to investigate the formation of nanoscale polymer blend/clay hybrid. Infrared spectroscopy and X-ray analysis revealed the coexistence of β and γ crystalline forms in PVDF/Clay nanocomposite while α crystalline form was found to be dominant in PVDF/ACM/Clay miscible hybrids. Flory-Huggins interaction parameter (B) was used to further explain the miscibility phenomenon observed. The B parameter was determined by combining the melting point depression and the binary interaction model. The estimated B values for the ternary PVDF/ACM/Clay and PVDF/ACM pairs were all negative, showing both proper intercalation of the polymer melt into the nanoclay galleries and the good miscibility of PVDF and ACM blend. The B value for the PVDF/ACM blend was almost the same as that measured for the PVDF/ACM/Clay hybrid, suggesting that PVDF chains in nanocomposite hybrids interact with ACM chains and that nanoclay in hybrid systems is wrapped by ACM molecules.

Binary breath figures for straightforward and controllable self-assembly of microspherical caps.

PubMed

Gong, Jianliang; Xu, Bingang; Tao, Xiaoming; Li, Lei

2016-05-11

The intense interest surrounding asymmetrical microparticles originates from their unique anisotropic properties and promising applications. In this work, direct self-assembly of polymeric microspherical caps without the assistance of any additives has been achieved by using low-surface-tension methanol (MeOH) and high-surface-tension water as binary breath figures (BFs). With the evaporation of polystyrene (PS) solution containing low-boiling-point solvent in the binary vapors, the formed MeOH BFs could quickly diffuse into solution, while water BFs tended to remain at the solution surface. This led to the formation of a gradient nonsolvent layer at the vapor/solution interface, which induced the formation of nuclei and guided further asymmetrical growth of polymer particles. After the spontaneous removal of MeOH, water and residual solvent by evaporation, polymeric microspherical caps were left on the substrate. Through controlling the proportion of water introduced by adjusting the ratios of MeOH and water, polymeric microspherical caps with a range of controllable shapes (divided at different positions of a sphere) were successfully obtained. The formation mechanism was explained based on the difference of vapor pressure, surface tension and miscibility between the employed solvents and nonsolvents. A solvent possessing a high vapor pressure, low surface tension and good miscibility with MeOH contributed to the formation of microspherical caps. This flexible, green and straightforward technique is a nondestructive strategy, and avoids complicated work on design, preparation and removal of hard templates and additives.

Miscibility, Crystallization, and Rheological Behavior of Solution Casting Poly(3-hydroxybutyrate)/poly(ethylene succinate) Blends Probed by Differential Scanning Calorimetry, Rheology, and Optical Microscope Techniques

NASA Astrophysics Data System (ADS)

Sun, Wei-hua; Qiao, Xiao-ping; Cao, Qi-kun; Liu, Jie-ping

2010-02-01

The miscibility and crystallization of solution casting biodegradable poly(3-hydroxybutyrate)/poly(ethylene succinate) (PHB/PES) blends was investigated by differential scanning calorimetry, rheology, and optical microscopy. The blends showed two glass transition temperatures and a depression of melting temperature of PHB with compositions in phase diagram, which indicated that the blend was partially miscible. The morphology observation supported this result. It was found that the PHB and PES can crystallize simultaneously or upon stepwise depending on the crystallization temperatures and compositions. The spherulite growth rate of PHB increased with increasing of PES content. The influence of compositions on the spherulitic growth rate for the partially miscible polymer blends was discussed.

Role of Thickness Confinement on Relaxations of the Fast Component in a Miscible A/B Blend

DOE Office of Scientific and Technical Information (OSTI.GOV)

Green, Peter; Sharma, Ravi P.; Dong, Ban Xuan

Spatial compositional heterogeneity strongly influences the dynamics of the A and B components of bulk miscible blends. Its effects are especially apparent in mixtures, such as poly(vinyl methyl ether) (PVME)/polystyrene (PS), where there exist significant disparities between the component glass transition temperatures (Tgs) and relaxation times. The relaxation processes characterized by distinct temperature dependencies and relaxation rates manifest different local compositional environments for temperatures above and below the glass transition temperature of the miscible blend. This same behavior is shown to exist in miscible PS/PVME films as thin as 100 nm. Moreover, in thin films, the characteristic segmental relaxation timesmore » t of the PVME component of miscible PVME/PS blends confined between aluminum (Al) substrates decrease with increasing molecular weight M of the PS component. These relaxation rates are film thickness dependent, in films up to a few hundred nanometers in thickness. This is in remarkable contrast to homopolymer films, where thickness confinement effects are apparent only on length scales on the order of nanometers. These surprisingly large length scales and M dependence are associated with the preferential interfacial enrichment - wetting layer formation - of the PVME component at the external Al interfaces, which alters the local spatial blend composition within the interior of the film. The implications are that the dynamics of miscible thin film blends are dictated in part by component Tg differences, disparities in component relaxation rates, component-substrate interactions, and chain lengths (entropy of mixing).« less

Influence of Miscibility Phenomenon on Crystalline Polymorph Transition in Poly(Vinylidene Fluoride)/Acrylic Rubber/Clay Nanocomposite Hybrid

PubMed Central

Abolhasani, Mohammad Mahdi; Naebe, Minoo; Jalali-Arani, Azam; Guo, Qipeng

2014-01-01

In this paper, intercalation of nanoclay in the miscible polymer blend of poly(vinylidene fluoride) (PVDF) and acrylic rubber(ACM) was studied. X-ray diffraction was used to investigate the formation of nanoscale polymer blend/clay hybrid. Infrared spectroscopy and X-ray analysis revealed the coexistence of β and γ crystalline forms in PVDF/Clay nanocomposite while α crystalline form was found to be dominant in PVDF/ACM/Clay miscible hybrids. Flory-Huggins interaction parameter (B) was used to further explain the miscibility phenomenon observed. The B parameter was determined by combining the melting point depression and the binary interaction model. The estimated B values for the ternary PVDF/ACM/Clay and PVDF/ACM pairs were all negative, showing both proper intercalation of the polymer melt into the nanoclay galleries and the good miscibility of PVDF and ACM blend. The B value for the PVDF/ACM blend was almost the same as that measured for the PVDF/ACM/Clay hybrid, suggesting that PVDF chains in nanocomposite hybrids interact with ACM chains and that nanoclay in hybrid systems is wrapped by ACM molecules. PMID:24551141

Vapor condensation onto a non-volatile liquid drop

DOE Office of Scientific and Technical Information (OSTI.GOV)

Inci, Levent; Bowles, Richard K., E-mail: richard.bowles@usask.ca

2013-12-07

Molecular dynamics simulations of miscible and partially miscible binary Lennard–Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the system volume is large, the driving force for condensation is low and only a submonolayer of the solvent is adsorbed onto the liquid drop. A small degree of mixing of the solvent phase into the core of the particles occurs for the miscible system. At smaller volumes, complete film formation is observed and the dynamics of film growth are dominated by cluster-cluster coalescence. Mixing into the coremore » of the droplet is also observed for partially miscible systems below an onset volume suggesting the presence of a solubility transition. We also develop a non-volatile liquid drop model, based on the capillarity approximations, that exhibits a solubility transition between small and large drops for partially miscible mixtures and has a hysteresis loop similar to the one observed in the deliquescence of small soluble salt particles. The properties of the model are compared to our simulation results and the model is used to study the formulation of classical nucleation theory for systems with low free energy barriers.« less

Gasdynamic Inlet Isolation in Rotating Detonation Engine

DTIC Science & Technology

2010-12-01

2D Total Variation Diminishing (TVD): Continuous Riemann Solver Minimum Dissipation: LHS & RHS Activate pressure switch : Supersonic Activate...Total Variation Diminishing (TVD) limiter: Continuous Riemann Solver Minimum Dissipation: LHS & RHS Activate pressure switch : Supersonic Activate...Continuous 94 Riemann Solver Minimum Dissipation: LHS & RHS Activate pressure switch : Supersonic Activate pressure gradient switch: Normal

Miscibility of ethyl cellulose/copolyamide6/66/1010 blends by viscometry and refractive index method

NASA Astrophysics Data System (ADS)

Zhang, Xiuzhen; Shen, Yuhua; Xie, Anjian; Gao, Sulian; Xing, Zhiying

2011-04-01

The miscibility of ethyl cellulose (EC)/copolyamide6/66/1010 (PA-130) in formic acid is studied by viscometry and refractive index techniques at 25°C. Using viscosity data, the criteria Δ b, Δ b', Δ[η]m, interaction parameter μ, β and thermodynamic parameter α are calculated. These investigations indicate that blend of EC/PA-130 is miscible when the ethyl cellulose content is more than 50 wt % in the blend. Further the result was also confirmed by refractive index measurements.

Influence of supercritical CO(2) pressurization on the phase behavior of mixed cholesteryl esters.

PubMed

Huang, Zhen; Feng, Mei; Su, Junfeng; Guo, Yuhua; Liu, Tie-Yan; Chiew, Yee C

2010-09-15

Evidences indicating the presence of phase transformations in the mixed cholesteryl benzoate (CBE) and cholesteryl butyrate (CBU) under the supercritical CO(2) pressurization, by means of differential scanning calorimetry (DSC) and X-ray diffraction (XRD), are presented in this work. These include (1) the DSC heating curve of pure CBU; (2) the DSC heating curves of CBU/CBE mixtures; (3) the XRD spectra of pure CBU; (4) the XRD spectra of CBU/CBE mixtures; (5) CBU and CBE are miscible in either solid phase or liquid phase over the whole composition range. As a result of the presence of these phase transformations induced by pressurization, it could be deduced that a solid solution of the CBU/CBE mixture might have formed at the interfaces under supercritical conditions, subsequently influencing their dissolving behaviors in supercritical CO(2). Copyright 2010 Elsevier B.V. All rights reserved.

Viscous fingering with partially miscible fluids

NASA Astrophysics Data System (ADS)

Fu, Xiaojing; Cueto-Felgueroso, Luis; Juanes, Ruben

2017-10-01

Viscous fingering—the fluid-mechanical instability that takes place when a low-viscosity fluid displaces a high-viscosity fluid—has traditionally been studied under either fully miscible or fully immiscible fluid systems. Here we study the impact of partial miscibility (a common occurrence in practice) on the fingering dynamics. Through a careful design of the thermodynamic free energy of a binary mixture, we develop a phase-field model of fluid-fluid displacements in a Hele-Shaw cell for the general case in which the two fluids have limited (but nonzero) solubility into one another. We show, by means of high-resolution numerical simulations, that partial miscibility exerts a powerful control on the degree of fingering: fluid dissolution hinders fingering while fluid exsolution enhances fingering. We also show that, as a result of the interplay between compositional exchange and the hydrodynamic pattern-forming process, stronger fingering promotes the system to approach thermodynamic equilibrium more quickly.

Impact of sodium chloride on the expansion of a liquid-liquid miscibility gap in an API/water system. Case study of Brivaracetam.

PubMed

Couvrat, Nicolas; Mahieux, Julien; Fours, Baptiste; Cartigny, Yohann; Schenkel, Eric; Aerts, Luc; Quéré, Luc; Coquerel, Gérard

2016-12-30

Brivaracetam, or (2S)-2-[(4R)-2-oxo-4-propyl-pyrrolidin-1-yl] butanamide, is an active pharmaceutical ingredient designed for the treatment of epilepsy. During the development of the IV administration mode, a liquid-liquid miscibility gap has been observed with pure water, isotonic and hypertonic solutions (vehicle at 0.9% w/w and 5%w/w NaCl respectively). The study reveals that the NaCl concentration has a direct impact on the extent of the demixing domain; from a sub-micronic demixing in pure water towards a macroscopic miscibility gap in hypertonic aqueous solutions. The thorough exploration of these heterogeneous equilibria led to define experimental parameters for safe IV injections without risk of liquid - liquid miscibility gap at 37°C. Copyright © 2016 Elsevier B.V. All rights reserved.

Influence of water-miscible cutting fluid on tool wear behavior of various coated high-speed steel tools in hobbing

NASA Astrophysics Data System (ADS)

Sato, Yuta; Matsuoka, Hironori; Kubo, Akio; Ono, Hajime; Ryu, Takahiro; Qiu, Hua; Nakae, Takashi; Shuto, Shuichi; Watanabe, Suguru; Anan, Ruito

2017-04-01

This paper deals with the influence of water-miscible cutting fluid on tool life (flank wear) compared with that with dry cutting and water-insoluble cutting oil in hobbing. Experiments were conducted by simulating hobbing by fly tool cutting on a milling machine. The following results were clarified. (1) The water-miscible cutting fluid used in the test prolongs the tool life for TiN-, TiAlN-, TiSiN- and AlCrSiN-coated tools in comparison with that obtained by dry cutting and water-insoluble cutting oil. (2) It was presumed that the tool wear decreases and the tool life is improved by the lubrication effect of the synthetic lubrication additive, mineral oil and sulfuric EP additive contained in the water-miscible cutting fluid, and also by the cooling effect.

Combustion of two-component miscible droplets in reduced gravity

NASA Technical Reports Server (NTRS)

Shaw, Benjamin D.; Aharon, Israel; Gage, James W.; Jenkins, Andrew J.; Kahoe, Thomas J.

1995-01-01

This research focuses on the combustion of binary miscible droplets initially in the mm size range. Experiments are performed using the NASA Lewis 2.2 sec drop tower in Cleveland, Ohio, where mixtures of alkanes and/or alcohols are studied. The fuel components are selected to have significantly different volatilities. Initial oxygen mole fractions from about 0.15-0.5 and initial pressures from 0.2-2 atm are employed. Different inerts are used (He, CO2, Ar, N2) to change burning rates and sooting behaviors. Objectives are to observe the following: (1) Transient droplet diameters (including three-staged combustion behaviors and microexplosion; (2) Transient flow behaviors (sudden flame contraction, luminosity, extinction); and (3) Behaviors of observable soot particles. theoretical and computational research in support of this program has also been undertaken. This research includes analytical studies to determine the effects of small but nonzero gravitational levels on droplet gasification, analytical studies of hydrodynamic stability of spherically-symmetrical droplet gasification (to address the question as to whether spherically-symmetrical droplet gasification may be destabilized from capillary, i.e., Marangoni effects), and computational modeling of effects of capillary stresses on droplet gasification.

Discretization limits of multi-component lattice-Boltzmann methods and implications on the real porous media simulations

NASA Astrophysics Data System (ADS)

Herring, A. L.; Li, Z.; Middleton, J.; Varslot, T.; McClure, J. E.; Sheppard, A.

2017-12-01

Multicomponent lattice-Boltzmann (LB) modeling is widely applied to study two-phase flow in various porous media. However, the impact on LB modeling of the fundamental trade-off between image resolution and field of view has received relatively little attention. This is important since 3D images of geological samples rarely have both sufficient resolution to capture fine structure and sufficient field of view to capture a full representative elementary volume of the medium. To optimize the simulations, it is important to know the minimum number of grid points that LB methods require to deliver physically meaningful results, and allow for the sources of measurement uncertainty to be appropriately balanced. In this work, we study the behavior of the Shan-Chen (SC) and Rothman-Keller (RK) models when the phase interfacial radius of curvature and the feature size of the medium approach the discrete unit size of the computational grid. Both simple, small-scale test geometries and real porous media are considered. Models' behavior in the extreme discrete limit is classified ranging from gradual loss of accuracy to catastrophic numerical breakdown. Based on this study, we provide guidance for experimental data collection and how to apply the LBM to accurately resolve physics of interest for two-fluid flow in porous media. Resolution effects are particularly relevant to the study of low-porosity systems, including fractured materials, when the typical pore width may only be a few voxels across.Overall, we find that the shortcoming of the SC model predominantly arises from the strongly pressure-dependent miscibility of the fluid components, where small droplets with high interfacial curvature have an exaggerated tendency to dissolve into the surrounding fluid. For the RK model, the most significant shortcoming is unphysical flow of non-wetting phase through narrow channels and crevices (2 voxels across or smaller), which we observed both in simple capillary tube and realistic porous medium. This process generates unphysical non-wetting phase ganglia that are hard to distinguish from ganglia of physical origin (e.g. arising from snap-off). While both methods have advantages and shortcomings, the RK model with modern enhancements seems to exhibit fewer instabilities, and is more suitable for system of low miscibility.

COSOLVENCY AND SOPRTION OF HYDROPHOBIC ORGANIC CHEMICALS

EPA Science Inventory

Sorption of hydrophobic organic chemicals (HOCs) by two soils was measured from mixed solvents containing water plus completely miscible organic solvents (CMOSs) and partially miscible organic solvents (PMOSs). The utility of the log-linear cosolvency model for predicting HOC sor...

Miscibility and Thermodynamics of Mixing of Different Models of Formamide and Water in Computer Simulation.

PubMed

Kiss, Bálint; Fábián, Balázs; Idrissi, Abdenacer; Szőri, Milán; Jedlovszky, Pál

2017-07-27

The thermodynamic changes that occur upon mixing five models of formamide and three models of water, including the miscibility of these model combinations itself, is studied by performing Monte Carlo computer simulations using an appropriately chosen thermodynamic cycle and the method of thermodynamic integration. The results show that the mixing of these two components is close to the ideal mixing, as both the energy and entropy of mixing turn out to be rather close to the ideal term in the entire composition range. Concerning the energy of mixing, the OPLS/AA_mod model of formamide behaves in a qualitatively different way than the other models considered. Thus, this model results in negative, while the other ones in positive energy of mixing values in combination with all three water models considered. Experimental data supports this latter behavior. Although the Helmholtz free energy of mixing always turns out to be negative in the entire composition range, the majority of the model combinations tested either show limited miscibility, or, at least, approach the miscibility limit very closely in certain compositions. Concerning both the miscibility and the energy of mixing of these model combinations, we recommend the use of the combination of the CHARMM formamide and TIP4P water models in simulations of water-formamide mixtures.

Polymer-fullerene miscibility: a metric for screening new materials for high-performance organic solar cells.

PubMed

Treat, Neil D; Varotto, Alessandro; Takacs, Christopher J; Batara, Nicolas; Al-Hashimi, Mohammed; Heeney, Martin J; Heeger, Alan J; Wudl, Fred; Hawker, Craig J; Chabinyc, Michael L

2012-09-26

The improvement of the power conversion efficiency (PCE) of polymer bulk heterojunction (BHJ) solar cells has generally been achieved through synthetic design to control frontier molecular orbital energies and molecular ordering of the electron-donating polymer. An alternate approach to control the PCE of a BHJ is to tune the miscibility of the fullerene and a semiconducting polymer by varying the structure of the fullerene. The miscibility of a series of 1,4-fullerene adducts in the semiconducting polymer, poly(3-hexylselenophene), P3HS, was measured by dynamic secondary ion mass spectrometry using a model bilayer structure. The microstructure of the bilayer was investigated using high-angle annular dark-field scanning transmission microscopy and linked to the polymer-fullerene miscibility. Finally, P3HS:fullerene BHJ solar cells were fabricated from each fullerene derivative, enabling the correlation of the active layer microstructure to the charge collection efficiency and resulting PCE of each system. The volume fraction of polymer-rich, fullerene-rich, and polymer-fullerene mixed domains can be tuned using the miscibility leading to improvement in the charge collection efficiency and PCE in P3HS:fullerene BHJ solar cells. These results suggest a rational approach to the design of fullerenes for improved BHJ solar cells.

Miscibility comparison for three refrigerant mixtures and four component refrigerants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kang, H.M.; Pate, M.B.

1999-07-01

Miscibility data were taken and compared for seven different refrigerants when mixed with the same polyol ester (POE) lubricant. Four of the seven refrigerants were single-component refrigerants while three of the refrigerants were mixtures composed of various combinations of the pure refrigerants. The purpose of this research was to investigate the difference in miscibility characteristics between refrigerant mixtures and their respective component refrigerants. The POE lubricant was a penta erythritol mixed-acid type POE which has a viscosity ISO32. The four pure refrigerants were R-32, R-125, R-134a, and R-143a and the three refrigerant mixtures were R-404A, R407C, and R-410A. The miscibilitymore » tests were performed in a test facility consisting of a series of miniature test cells submerged in a constant temperature bath. The test cells were constructed to allow for complete visibility of the refrigerant/lubricant mixtures under all test conditions. The tests were performed over a concentration range of 0 to 100% and a temperature range of {minus}40 to 194 F. The miscibility test results for refrigerant mixtures are compared to component refrigerants. In all cases, the refrigerant mixtures appear to have better miscibility than their most immiscible pure component.« less

An investigation of the thermodynamic miscibility between VeTPGS and polymers.

PubMed

Li, Jinjiang; Chiappetta, Doris

2008-02-28

Within the past decade, more than half of the drug candidates generated are poorly water soluble and therefore overcoming the low aqueous solubility of drug candidates becomes critical for product development. Vitamin E TPGS (VeTPGS), a non-ionic surfactant, has been used in both liquid and solid dosage forms to solubilize compounds and improve their bioavailability. To prepare solid dosage forms using VeTPGS, VeTPGS is often mixed with other excipients, mostly polymers. However, there is still a lack of understanding of miscibility between VeTPGS and polymers from a thermodynamic point of view. In this paper, the miscibility of VeTPGS with polymers has been studied in the light of the Flory-Huggins (F-H) theory with an objective to understand the effect of dispersion forces (solubility parameter) and nondispersive interactions on the miscibility between VeTPGS and polymers. A series of polymers with similar solubility parameters and structure similarity were selected. Binary blends of polymers and VeTPGS were prepared using a vapor evaporation technique followed by XRPD, DSC, and SEM characterization. Results suggest that the miscibility between VeTPGS and PMMA is very likely due to a specific interaction between the hydrophobic portion of VeTPGS (Vitamin E) and PMMA.

When immiscible becomes miscible-Methane in water at high pressures.

PubMed

Pruteanu, Ciprian G; Ackland, Graeme J; Poon, Wilson C K; Loveday, John S

2017-08-01

At low pressures, the solubility of gases in liquids is governed by Henry's law, which states that the saturated solubility of a gas in a liquid is proportional to the partial pressure of the gas. As the pressure increases, most gases depart from this ideal behavior in a sublinear fashion, leveling off at pressures in the 1- to 5-kbar (0.1 to 0.5 GPa) range with solubilities of less than 1 mole percent (mol %). This contrasts strikingly with the well-known marked increase in solubility of simple gases in water at high temperature associated with the critical point (647 K and 212 bar). The solubility of the smallest hydrocarbon, the simple gas methane, in water under a range of pressure and temperature is of widespread importance, because it is a paradigmatic hydrophobe and occurs widely in terrestrial and extraterrestrial geology. We report measurements up to 3.5 GPa of the pressure dependence of the solubility of methane in water at 100°C-well below the latter's critical temperature. Our results reveal a marked increase in solubility between 1 and 2 GPa, leading to a state above 2 GPa where the maximum solubility of methane in water exceeds 35 mol %.

MISCIBILITY, SOLUBILITY, AND VISCOSITY MEASUREMENTS FOR R-236EA WITH POTENTIAL LUBRICANTS

EPA Science Inventory

The report gives results of miscibility, solubility, and viscosity measurements of refrigerant R-236ea with three potential lubricants. (NOTE: The data were needed to determine the suitability of refrigerant/lubricant combinations for use in refrigeration systems.) The lubricants...

Dolomitic marbles from the ultrahigh-pressure metamorphic Kimi complex in Rhodope, N.E. Greece

NASA Astrophysics Data System (ADS)

Mposkos, E.; Baziotis, I.; Proyer, A.; Hoinkes, G.

2006-09-01

Dolomitic marbles from the Organi and Pandrosos areas of the ultrahigh-pressure (UHP) metamorphic Kimi complex in East Rhodope, N.E. Greece have the mineral assemblage: Cal + Dol + Ol + Phl ± Di ± Hbl ± Spl ± Ti Chu + retrograde Srp and Chl. Several generations of calcite and dolomite with variable composition and texture represent different stages of the P T evolution: The first stage is represented by matrix dolomite (X_MgCO_3 = 0.48) and relic domains of homogenous composition in matrix calcite (X_MgCO_3 = 0.11 0.13); the second stage is evident from precipitation of lath-shaped and vermicular dolomite in matrix calcite. The third stage is represented by veinlets of almost pure CaCO3 and domainal replacement of prior calcite by nearly pure CaCO3 + Ca-rich dolomite (X_MgCO_3 = 0.34 0.43). Matrix dolomite adjacent to CaCO3 veinlets also becomes Ca-rich (X_MgCO_3 = 0.42). In fact, Ca-rich dolomites with X_MgCO_3 in the range of 0.40 0.34 are reported for the first time from metamorphic marbles. Coexisting Ca-rich dolomite and Mg-poor calcite cannot be explained by the calcite-dolomite miscibility gap. This assemblage rather suggests that Mg-poor calcite was aragonite originally, which formed together with Ca-rich dolomite according to the reaction Mg Cal → Arg + Dol (1) at ultrahigh pressures and temperatures above at least 850 °C, when dolomite becomes disordered and incorporates more Ca than coexisting aragonite does in terms of Mg. The simplest explanation of these observations probably is to suggest two metamorphic events: The first one represented by relic matrix carbonates at relatively low to moderate pressures and temperatures of ca. 750 °C, and the second one limited by the minimum temperatures for dolomite disorder (ca. 850 °C) and in the aragonite + dolomite stability field, i.e. at a minimum pressure of 3 GPa and, if the presence of diamond-bearing metapelites nearby is considered, at conditions of at least 850 °C and 4.3 GPa in the diamond stability field. As there is hardly any back-reaction of Ca-rich dolomite + Mg-poor calcite to Mg-rich calcite, peak temperatures remained below the reaction (1) and the exhumation path probably crossed the aragonite-calcite transition at much lower than peak temperature. Cooling and decompression must have both occurred extremely fast in order for the µm-sized Ca-rich dolomite textures to be preserved. An alternative explanation of the formation of “UHP”-textures and compositions is by a fluid influx that not only caused serpentinisation and chloritisation of silicates but also Mg-leaching from carbonates, particularly from Mg-rich calcite and its fine grained dolomite-precipitates, thus transforming them into Mg-poor calcite + Ca-rich dolomite.

MISCIBILITY, SOLUBILITY, VISCOSITY, AND DENSITY MEASUREMENTS FOR R-236FA WITH POTENTIAL LUBRICANTS

EPA Science Inventory

The report gives results of miscibility, solubility, viscosity, and density measurements for refrigerant R-236fa and two potential lubricants . (The data are needed to determine the suitability of refrigerant/lubricant combinations for use in refrigeration systems.) The tested oi...

Miscibility, solubility, viscosity, and density measurements for R-236ea with four different Exxon lubricants. Final report, March 1995-March 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kang, H.M.; Pate, M.B.

1999-06-15

The report discusses miscibility, solubility, viscosity, and density data for the refrigerant hydrofluorocarbon (HFC)-236ea (or R-236ea) and four lubricants supplied by Exxon Corporation. The miscibility tests were performed in a test facility consisting of a series of miniature test cells submerged in a constant temperature bath, precisely controlled over a range of {minus}50 to 90 C. Critical solution temperatures obtained from the miscibility data are presented for each refrigerant/lubricant combination. Data for the R-236ea in each of the test lubricants have been collected for refrigerant concentrations of 10--90%. The raw data have been presented, and the results have been summarized.more » Solubility, viscosity, and density data were also obtained for R-236ea mixed with the same four oils for a refrigerant concentration range of 0--40 wt% refrigerant over a temperature range of 30--100 C.« less

Flash-point prediction for binary partially miscible mixtures of flammable solvents.

PubMed

Liaw, Horng-Jang; Lu, Wen-Hung; Gerbaud, Vincent; Chen, Chan-Cheng

2008-05-30

Flash point is the most important variable used to characterize fire and explosion hazard of liquids. Herein, partially miscible mixtures are presented within the context of liquid-liquid extraction processes. This paper describes development of a model for predicting the flash point of binary partially miscible mixtures of flammable solvents. To confirm the predictive efficacy of the derived flash points, the model was verified by comparing the predicted values with the experimental data for the studied mixtures: methanol+octane; methanol+decane; acetone+decane; methanol+2,2,4-trimethylpentane; and, ethanol+tetradecane. Our results reveal that immiscibility in the two liquid phases should not be ignored in the prediction of flash point. Overall, the predictive results of this proposed model describe the experimental data well. Based on this evidence, therefore, it appears reasonable to suggest potential application for our model in assessment of fire and explosion hazards, and development of inherently safer designs for chemical processes containing binary partially miscible mixtures of flammable solvents.

Miscible viscous fingering with chemical reaction involving precipitation.

NASA Astrophysics Data System (ADS)

Bae, Si-Kyun; Nagatsu, Yuichiro; Kato, Yoshihito; Tada, Yutaka

2007-11-01

When a reactive and miscible less-viscous liquid displaces a more-viscous liquid in a Hele-Shaw cell, reactive miscible viscous fingering takes place. The present study has experimentally examined how precipitation produced by chemical reaction affects miscible viscous fingering pattern. A 97 wt % glycerin solution containing iron(III) nitrate (yellow) and a solution containing potassium hexacyano ferrate(II) (colorless) were used as the more- and less-viscous liquids, respectively. In this case, the chemical reaction instantaneously takes place and produces the precipitation being dark blue in color. The experiments were done by varying reactant concentrations, the cell's gap width, and the displacement speed. We compared the patterns involving the precipitation reaction with those in the non-reactive cases. We have found fylfot-like pattern is observed, depending on the experimental condition, which has never been formed in the non-reactive experiments. As the reactant concentrations are increased or the displacement speed is decreased, the effects of the precipitation on the patterns are more pronounced.

Sensitivity analysis and economic optimization studies of inverted five-spot gas cycling in gas condensate reservoir

NASA Astrophysics Data System (ADS)

Shams, Bilal; Yao, Jun; Zhang, Kai; Zhang, Lei

2017-08-01

Gas condensate reservoirs usually exhibit complex flow behaviors because of propagation response of pressure drop from the wellbore into the reservoir. When reservoir pressure drops below the dew point in two phase flow of gas and condensate, the accumulation of large condensate amount occurs in the gas condensate reservoirs. Usually, the saturation of condensate accumulation in volumetric gas condensate reservoirs is lower than the critical condensate saturation that causes trapping of large amount of condensate in reservoir pores. Trapped condensate often is lost due to condensate accumulation-condensate blockage courtesy of high molecular weight, heavy condensate residue. Recovering lost condensate most economically and optimally has always been a challenging goal. Thus, gas cycling is applied to alleviate such a drastic loss in resources. In gas injection, the flooding pattern, injection timing and injection duration are key parameters to study an efficient EOR scenario in order to recover lost condensate. This work contains sensitivity analysis on different parameters to generate an accurate investigation about the effects on performance of different injection scenarios in homogeneous gas condensate system. In this paper, starting time of gas cycling and injection period are the parameters used to influence condensate recovery of a five-spot well pattern which has an injection pressure constraint of 3000 psi and production wells are constraint at 500 psi min. BHP. Starting injection times of 1 month, 4 months and 9 months after natural depletion areapplied in the first study. The second study is conducted by varying injection duration. Three durations are selected: 100 days, 400 days and 900 days. In miscible gas injection, miscibility and vaporization of condensate by injected gas is more efficient mechanism for condensate recovery. From this study, it is proven that the application of gas cycling on five-spot well pattern greatly enhances condensate recovery preventing financial, economic and resource loss that previously occurred.

Helping HAN for hybrid rockets

NASA Astrophysics Data System (ADS)

Ramohalli, Kumar; Dowler, Warren

1995-01-01

Hydroxyl amine nitrate (HAN) is a powerful oxidizer for hybrid rocket flight motors. Miscible with water up to 95% by mass, it also has high density and has been extensively characterized for materials compatibility, safety, transportation, storage and handling. Before any serious attempt to use the proposed oxidizer in hybrids, though, the usual performance figures must first be obtained. The simplest are time-independent, equilibrium rocket performance numbers that include chamber temperature, temperature at the nozzle throat, and key species in the exhaust. These numbers must be followed by several other important performance evaluation, including burning rates, pressure dependence, susceptibility to instabilities and temperature sensitivity.

Thermochemical generation of hydrogen

NASA Technical Reports Server (NTRS)

Lawson, D. D.; Petersen, G. R. (Inventor)

1982-01-01

The direct fluid contact heat exchange with H2SO4 at about 330 C prior to high temperature decomposition at about 830 C in the oxygen release step of several thermochemical cycles for splitting water into hydrogen and oxygen provides higher heat transfer rates, savings in energy and permits use of cast vessels rather than expensive forged alloy indirect heat exchangers. Among several candidate perfluorocarbon liquids tested, only perfluoropropylene oxide polymers having a degree of polymerization from about 10 to 60 were chemically stable, had low miscibility and vapor pressure when tested with sulfuric acid at temperatures from 300 C to 400 C.

HYDRAULICS AND MIXING EVALUATIONS FOR NT-21/41 TANKS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, S.; Barnes, O.

2014-11-17

The hydraulic results demonstrate that pump head pressure of 20 psi recirculates about 5.6 liters/min flowrate through the existing 0.131-inch orifice when a valve connected to NT-41 is closed. In case of the valve open to NT-41, the solution flowrates to HB-Line tanks, NT-21 and NT-41, are found to be about 0.5 lpm and 5.2 lpm, respectively. The modeling calculations for the mixing operations of miscible fluids contained in the HB-Line tank NT-21 were performed by taking a three-dimensional Computational Fluid Dynamics (CFD) approach. The CFD modeling results were benchmarked against the literature results and the previous SRNL test resultsmore » to validate the model. Final performance calculations were performed for the nominal case by using the validated model to quantify the mixing time for the HB-Line tank. The results demonstrate that when a pump recirculates a solution volume of 5.7 liters every minute out of the 72-liter tank contents containing two acid solutions of 2.7 M and 0 M concentrations (i.e., water), a minimum mixing time of 1.5 hours is adequate for the tank contents to get the tank contents adequately mixed. In addition, the sensitivity results for the tank contents of 8 M existing solution and 1.5 M incoming species show that the mixing time takes about 2 hours to get the solutions mixed.« less

Dynamic stabilization of the Rayleigh-Taylor instability of miscible liquids and the related "frozen waves"

NASA Astrophysics Data System (ADS)

Wolf, Gerd Gerhard H.

2018-02-01

Superimposed miscible liquids, the heavier one on top, when subjected to vibrations vertical to their interface (dynamic stabilization), can only be maintained for a certain period. A mechanism is presented explaining the resulting process of degradation and "anomalous diffusion" through that interface. Superimposed liquids, the lighter one on top, exposed to horizontal vibrations, develop a saw-tooth-like pattern called "frozen waves." These are subject to conditions similar to those of dynamic stabilization and, if miscible, thus can also only be maintained for a certain period. A further analysis of these processes would be desirable, also in view of their relation to analogue phenomena.

MISCIBILITY, SOLUBILITY, VISCOSITY, AND DENSITY MEASUREMENTS FOR R-236EA WITH FOUR DIFFERENT EXXON LUBRICANTS

EPA Science Inventory

The report discusses miscibility, solubility, viscosity, and density data for the refrigerant hydrofluorocarbon (HFC)-236ea (or R-236ea) and four lubricants supplied by Exxon Corporation. Such data are needed to determine the suitability of refrigerant/lubricant combinations for ...

42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

Code of Federal Regulations, 2012 CFR

2012-10-01

... test; Type C supplied-air respirator, pressure-demand class; minimum requirements. (a) The static... 42 Public Health 1 2012-10-01 2012-10-01 false Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum requirements. 84.157 Section 84.157 Public Health PUBLIC HEALTH...

42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

Code of Federal Regulations, 2013 CFR

2013-10-01

... test; Type C supplied-air respirator, pressure-demand class; minimum requirements. (a) The static... 42 Public Health 1 2013-10-01 2013-10-01 false Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum requirements. 84.157 Section 84.157 Public Health PUBLIC HEALTH...

42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

Code of Federal Regulations, 2014 CFR

2014-10-01

... test; Type C supplied-air respirator, pressure-demand class; minimum requirements. (a) The static... 42 Public Health 1 2014-10-01 2014-10-01 false Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum requirements. 84.157 Section 84.157 Public Health PUBLIC HEALTH...

42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

Code of Federal Regulations, 2010 CFR

2010-10-01

... respirator, pressure-demand class; minimum requirements. 84.157 Section 84.157 Public Health PUBLIC HEALTH... test; Type C supplied-air respirator, pressure-demand class; minimum requirements. (a) The static... the facepiece shall not fall below atmospheric at inhalation airflows less than 115 liters (4 cubic...

42 CFR 84.157 - Airflow resistance test; Type C supplied-air respirator, pressure-demand class; minimum...

Code of Federal Regulations, 2011 CFR

2011-10-01

... respirator, pressure-demand class; minimum requirements. 84.157 Section 84.157 Public Health PUBLIC HEALTH... test; Type C supplied-air respirator, pressure-demand class; minimum requirements. (a) The static... the facepiece shall not fall below atmospheric at inhalation airflows less than 115 liters (4 cubic...

Concentration dependent refractive index of a binary mixture at high pressure.

PubMed

Croccolo, Fabrizio; Arnaud, Marc-Alexandre; Bégué, Didier; Bataller, Henri

2011-07-21

In the present work binary mixtures of varying concentrations of two miscible hydrocarbons, 1,2,3,4-tetrahydronaphtalene (THN) and n-dodecane (C12), are subjected to increasing pressure up to 50 MPa in order to investigate the dependence of the so-called concentration contrast factor (CF), i.e., (∂n/∂c)(p, T), on pressure level. The refractive index is measured by means of a Mach-Zehnder interferometer. The setup and experimental procedure are validated with different pure fluids in the same pressure range. The refractive index of the THN-C12 mixture is found to vary both over pressure and concentration, and the concentration CF is found to exponentially decrease as the pressure is increased. The measured values of the refractive index and the concentration CFs are compared with values obtained by two different theoretical predictions, the well-known Lorentz-Lorenz formula and an alternative one proposed by Looyenga. While the measured refractive indices agree very well with predictions given by Looyenga, the measured concentration CFs show deviations from the latter of the order of 6% and more than the double from the Lorentz-Lorenz predictions.

Phospholipid lateral diffusion in phosphatidylcholine-sphingomyelin-cholesterol monolayers; effects of oxidatively truncated phosphatidylcholines.

PubMed

Parkkila, Petteri; Stefl, Martin; Olżyńska, Agnieszka; Hof, Martin; Kinnunen, Paavo K J

2015-01-01

Oxidative stress is involved in a number of pathological conditions and the generated oxidatively modified lipids influence membrane properties and functions, including lipid-protein interactions and cellular signaling. Brewster angle microscopy demonstrated oxidatively truncated phosphatidylcholines to promote phase separation in monolayers of 1-palmitoyl-2-oleoyl-sn-glycerol-3-phosphocholine (POPC), sphingomyelin (SM) and cholesterol (Chol). More specifically, 1-palmitoyl-2-azelaoyl-sn-glycero-3-phosphocholine (PazePC), was found to increase the miscibility transition pressure of the SM/Chol-phase. Lateral diffusion of lipids is influenced by a variety of membrane properties, thus making it a sensitive parameter to observe the coexistence of different lipid phases, for instance. The dependence on lipid lateral packing of the lateral diffusion of fluorophore-containing phospholipid analogs was investigated in Langmuir monolayers composed of POPC, SM, and Chol and additionally containing oxidatively truncated phosphatidylcholines, using fluorescence correlation spectroscopy (FCS). To our knowledge, these are the first FCS results on miscibility transition in ternary lipid monolayers, confirming previous results obtained using Brewster angle microscopy on such lipid monolayers. Wide-field fluorescence microscopy was additionally employed to verify the transition, i.e. the loss and reformation of SM/Chol domains. Copyright © 2014. Published by Elsevier B.V.

Nonergodicity in binary alloys

NASA Astrophysics Data System (ADS)

Son, Leonid; Sidorov, Valery; Popel, Pjotr; Shulgin, Dmitry

2015-09-01

For binary liquids with limited miscibility of the components, we provide the corrections to the equation of state which arise from the nonergogic diffusivity. It is shown that these corrections result in lowering of critical miscibility point. In some cases, it may result in a bifurcation of miscibility curve: the mixtures near 50% concentration which are homogeneous at the microscopic level, occur to be too stable to provide a quasi - eutectic triple point. These features provide a new look on the phase diagrams of some binary systems. In present work, we discuss Ga-Pb, Fe-Cu, and Cu-Zr alloys. Our investigation corresponds their complex behavior in liquid state to the shapes of their phase diagrams.

Studies on droplet evaporation and combustion in high pressures

NASA Technical Reports Server (NTRS)

Sato, J.

1993-01-01

High pressure droplet evaporation and combustion have been studied up to 15 MPa under normal and microgravity fields. From the evaporation studies, it has been found that in the supercritical environments, the droplet evaporation rate and lifetime take a maximum and a minimum at an ambient pressure over the critical pressure. Its maximum and minimum points move toward the lower ambient pressures if the ambient temperature is increased. It has been found from the combustion studies that the burning life time takes a minimum at an ambient pressure being equal to the critical pressure. It is attributable to both the pressure dependency of the diffusion rate and the droplet evaporation characteristics described above.

The numerical simulation on swelling factor and extraction rate of a tight crude oil and SC-CO2 system

NASA Astrophysics Data System (ADS)

Zou, Hongjun; Gong, Houjian; Li, Yajun; Dong, Mingzhe

2018-03-01

A method was established to study swelling and extraction between CO2 and crude oil, and the influences of pressure, temperature and molecular weight were investigated. Firstly, laboratory analysis was conducted to determine the pseudo-component and other parameters of the crude oil. Then swelling and extraction of the crude oil and SC-CO2 system were calculated by computer simulation. The results show that the pressure and temperature have little influence on the swelling and extraction between CO2 and crude oil when the mole fraction of CO2 is lower. A higher pressure and temperature is more beneficial to the interaction of CO2 and crude oil, while the swelling and extraction will not be obvious when the system is miscible. And the smaller the molecular weight of the oil is, the larger the maximum value of the swelling factor of CO2 and crude oil changes. The study of swelling and extraction plays an important role in the oilfield stimulation.

CONTROLLING THE AQUEOUS MISCIBILITY OF IONIC LIQUIDS: A NOVEL AQUEOUS BIPHASIC SYSTEM FROM WATER-MISCIBLE IONIC LIQUID AND A WATER-STRUCTURING SALT. (R828257)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

Fabrication of thermoplastic ductile films of chitin butyrate/poly(ɛ-caprolactone) blends and their cytocompatibility.

PubMed

Hashiwaki, Hiroki; Teramoto, Yoshikuni; Nishio, Yoshiyuki

2014-12-19

We fabricate thermoplastic films of chitin burtyrate (ChB)/poly(ɛ-caprolactone) (PCL) blends with different degree of miscibility (miscible (M), partially miscible (PM), and immiscible (IM)), and examined the feasibility as a cell scaffold system through evaluating mechanical properties and cytocompatibility. We found a remediation of the brittleness and an increase in ductility of ChB by blending PCL for the M and PM blends. The blend films were subjected to alkaline hydrolysis (2-M NaOH/37°C/48 h) with expectation of the improvement of the surface hydrophilicity and cell accessibility. ATR-FTIR spectroscopy of the alkaline-treated PM and IM films revealed that PCL component and ester side-chains of acyl chitin were selectively removed from the surface domain. L929 fibroblast cells well adhered and proliferated on these films. Therefore, the materials possess a great potential for the utilization as a thermoplastic cell scaffold in tissue engineering by adequate selection of the degree of miscibility and post treatment. Copyright © 2014 Elsevier Ltd. All rights reserved.

Preparation and Analysis of Co-precipitated, Biodegradable Poly-(Lactide-co-Glycolide) and Polyethylene Glycol Microspheres Prepared by Spray Drying

NASA Astrophysics Data System (ADS)

Javiya, Curie

Biodegradable poly-(d,l-lactide-co-glycolide) (PLGA) based microspheres are commonly used for numerous clinical applications. PEG is a widely used polymer due to its hydrophilic, biocompatible, and nontoxic nature. In this study, different blends of PLGA/PEG microspheres were prepared using a spray drying technique. The microspheres were spherical with maximum yield found to be 60.3% and average particle size in the range of 2.4 to 3.1 microm. Under the spray drying processing conditions, the polymers showed full miscibility slightly below 15% w/w and partial miscibility up to 20% w/w of PEG in the blended microspheres. At higher temperatures, PLGA and PEG were miscible in all proportions used for the blended microspheres. Blending 10% w/w PEG in PLGA membranes showed significant reduction in attachment of macrophages compared to PLGA membranes. The in-vitro response of macrophage towards the miscible blends of PLGA/PEG microspheres was further characterized. Results showed some reduction in macrophage viability and activation, however, significant effects with PLGA/PEG microspheres were not observed.

Miscibility Studies on Polymer Blends Modified with Phytochemicals

NASA Astrophysics Data System (ADS)

Chandrasekaran, Neelakandan; Kyu, Thein

2009-03-01

The miscibility studies related to an amorphous poly(amide)/poly(vinyl pyrrolidone) [PA/PVP] blend with a crystalline phytochemical called ``Mangiferin'' is presented. Phytochemicals are plant derived chemicals which intrinsically possess multiple salubrious properties that are associated with prevention of diseases such as cancer, diabetes, cardiovascular disease, and hypertension. Incorporation of phytochemicals into polymers has shown to have very promising applications in wound healing, drug delivery, etc. The morphology of these materials is crucial to applications like hemodialysis, which is governed by thermodynamics and kinetics of the phase separation process. Hence, miscibility studies of PA/PVP blends with and without mangiferin have been carried out using dimethyl sulfoxide as a common solvent. Differential scanning calorimetry studies revealed that the binary PA/PVP blends were completely miscible at all compositions. However, the addition of mangiferin has led to liquid-liquid phase separation and liquid-solid phase transition in a composition dependent manner. Fourier transformed infrared spectroscopy was undertaken to determine specific interaction between the polymer constituents and the role of possible hydrogen bonding among three constituents will be discussed.

Anomalous Capacitance Maximum of the Glassy Carbon-Ionic Liquid Interface through Dilution with Organic Solvents.

PubMed

Bozym, David J; Uralcan, Betül; Limmer, David T; Pope, Michael A; Szamreta, Nicholas J; Debenedetti, Pablo G; Aksay, Ilhan A

2015-07-02

We use electrochemical impedance spectroscopy to measure the effect of diluting a hydrophobic room temperature ionic liquid with miscible organic solvents on the differential capacitance of the glassy carbon-electrolyte interface. We show that the minimum differential capacitance increases with dilution and reaches a maximum value at ionic liquid contents near 5-10 mol% (i.e., ∼1 M). We provide evidence that mixtures with 1,2-dichloroethane, a low-dielectric constant solvent, yield the largest gains in capacitance near the open circuit potential when compared against two traditional solvents, acetonitrile and propylene carbonate. To provide a fundamental basis for these observations, we use a coarse-grained model to relate structural variations at the double layer to the occurrence of the maximum. Our results reveal the potential for the enhancement of double-layer capacitance through dilution.

Melt Miscibility in Block Copolymers Containing Polyethylene and Substituted Polynorbornenes

NASA Astrophysics Data System (ADS)

Mulhearn, William; Register, Richard

Very few polymer species exist with a sufficiently weak repulsive interaction against polyethylene (PE), characterized by a low Flory parameter χ or interaction energy density X, to be useful for preparing PE-containing block copolymers with disordered melts at high molecular weights. Most suitably miscible polymers are chemically similar to PE, such as copolymers of ethylene with a minority content of an α-olefin, and so are only marginally useful for property modification due to similar physical properties like the glass transition temperature (Tg) . However, the family of polymers consisting of substituted norbornenes prepared via ring-opening metathesis polymerization (ROMP) and subsequent hydrogenation is unique in that many of its members exhibit very low X against PE (comparable with the interaction energy between poly(ethylene-alt-propylene) and PE), and some of these also exhibit high Tg. The miscibility between PE and a substituted, hydrogenated ROMP polynobornene, or between two dissimilar hydrogenated polynorbornenes, is a strong function of the substituent appended to the norbornene monomer. The mixing thermodynamics of this polymer series are irregular, in that the interaction energies do not follow X = (δ1 - δ2)2 where δ is the solubility parameter. However, other systematic trends do apply and we develop a set of mixing rules to quantitatively describe the experimental miscibility behavior. We also investigate statistical copolymerization of two norbornene monomers as a means to continuously tune miscibility with a homopolymer of a third monomer.

Miscibility and in vitro osteocompatibility of biodegradable blends of poly[(ethyl alanato) (p-phenyl phenoxy) phosphazene] and poly(lactic acid-glycolic acid).

PubMed

Deng, Meng; Nair, Lakshmi S; Nukavarapu, Syam P; Kumbar, Sangamesh G; Jiang, Tao; Krogman, Nicholas R; Singh, Anurima; Allcock, Harry R; Laurencin, Cato T

2008-01-01

Previously we demonstrated the ability of ethyl glycinato substituted polyphosphazenes to neutralize the acidic degradation products and control the degradation rate of poly(lactic acid-glycolic acid) (PLAGA) by blending. In this study, blends of high strength poly[(50% ethyl alanato) (50% p-phenyl phenoxy) phosphazene] (PNEA(50)PhPh(50)) and 85:15 PLAGA were prepared using a mutual solvent approach. Three different solvents, methylene chloride (MC), chloroform (CF) and tetrahydrofuran (THF) were studied to investigate solvent effects on blend miscibility. Three different blends were then fabricated at various weight ratios namely 25:75 (BLEND25), 50:50 (BLEND50), and 75:25 (BLEND75) using THF as the mutual solvent. The miscibility of the blends was evaluated by scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR). Among these, BLEND25 was miscible while BLEND50 and BLEND75 were partially miscible. Furthermore, BLEND25 formed apatite layers on its surface as evidenced in a biomimetic study performed. These novel blends showed cell adhesion and proliferation comparable to PLAGA. However, the PNEA(50)PhPh(50) component in the blends was able to increase the phenotypic expression and mineralized matrix synthesis of the primary rat osteoblasts (PRO) in vitro. Blends of high strength PNEA(50)PhPh(50) and 85:15 PLAGA are promising biomaterials for a variety of musculoskeletal applications.

The Dynamics of Miscible Interfaces: Simulations

NASA Technical Reports Server (NTRS)

Meiburg, Eckart

2002-01-01

The goal of this experimental/computational investigation (joint with Prof Maxworthy at USC) has been to study the dynamics of miscible interfaces, both from a scientific and a practical point of view, and to prepare a related experiment to be flown on the International Space Station. In order to address these effects, we have focused experimental and computational investigations on miscible displacements in cylindrical capillary tubes, as well as in Hele-Shaw cells. Regarding the flow in a capillary tube, the question was addressed as to whether Korteweg stresses and/or divergence effects can potentially account for discrepancies observed between conventional Stokes flow simulations and experiments for miscible flows in capillary tubes. An estimate of the vorticity and streamfunction fields induced by the Kortewegs stresses was derived, which shows these stresses to result in the formation of a vortex ring structure near the tip of the concentration front. Through this mechanism the propagation velocity of the concentration front is reduced, in agreement with the experimental observations. Divergence effects, on the other hand, were seen to be very small, and they have a negligible influence on the tip velocity. As a result, it can be concluded that they are not responsible for the discrepancies between experiments and conventional Stokes simulations. A further part of our investigation focussed on the development of high-accuracy three-dimensional spectral element simulation techniques for miscible flows in capillary tubes, including the effects of variable density and viscosity. Towards this end, the conservation equations are treated in cylindrical coordinates.

Miscibility and in vitro osteocompatibility of biodegradable blends of poly[(ethyl alanato) (p-phenyl phenoxy) phosphazene] and poly(lactic acid-glycolic acid)

PubMed Central

Deng, Meng; Nair, Lakshmi S.; Nukavarapu, Syam P.; Kumbar, Sangamesh G.; Jiang, Tao; Krogman, Nicholas R.; Singh, Anurima; Allcock, Harry R.; Laurencin, Cato T.

2007-01-01

Previously we demonstrated the ability of ethyl glycinato substituted polyphosphazenes to neutralize the acidic degradation products and control the degradation rate of poly(lactic acid-glycolic acid) by blending. In this study, blends of high strength poly[(50% ethyl alanato) (50% p-phenyl phenoxy) phosphazene] (PNEA50PhPh50) and 85:15 poly(lactic acid-glycolic acid) (PLAGA) were prepared using a mutual solvent approach. Three different solvents, methylene chloride (MC), chloroform (CF) and tetrahydrofuran (THF) were studied to investigate solvent effects on blend miscibility. Three different blends were then fabricated at various weight ratios namely 25:75 (BLEND25), 50:50 (BLEND50), and 75:25 (BLEND75) using THF as the mutual solvent. The miscibility of the blends was evaluated by scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR). Among these, BLEND25 was miscible while BLEND50 and BLEND75 were partially miscible. Furthermore, BLEND25 formed apatite layers on its surface as evidenced in a biomimetic study performed. These novel blends showed cell adhesion and proliferation comparable to PLAGA. However, the PNEA50PhPh50 component in the blends was able to increase the phenotypic expression and mineralized matrix synthesis of the primary rat osteoblasts (PRO) in vitro. Blends of high strength poly[(50% ethyl alanato) (50% p-phenyl phenoxy) phosphazene] (PNEA50PhPh50) and 85:15 poly(lactic acid-glycolic acid) (PLAGA) are promising biomaterials for a variety of musculoskeletal applications. PMID:17942150

Miscibility of poly(lactic acid) and poly(ethylene oxide) solvent polymer blends and nanofibers made by solution blow spinning

USDA-ARS?s Scientific Manuscript database

The miscibility of blends of poly(lactic acid) (PLA) and poly(ethylene oxide) (PEO) was studied in polymer solutions by dilute solution viscometry and in solution blow spun nanofibers by microscopy (SEM, TEM) and by thermal and spectral analysis. Three blends of PLA and PEO were solution blended in...

A smoothed particle hydrodynamics model for miscible flow in three-dimensional fractures and the two-dimensional Rayleigh–Taylor instability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tartakovsky, Alexandre M.; Meakin, Paul

2005-08-10

A numerical model based on smoothed particle hydrodynamics (SPH) has been developed and used to simulate the classical two-dimensional Rayleigh–Taylor instability and three-dimensional miscible flow in fracture apertures with complex geometries. To model miscible flow fluid particles with variable, composition dependent, masses were used. By basing the SPH equations on the particle number density artificial surface tension effects were avoided. The simulation results for the growth of a single perturbation driven by the Rayleigh – Taylor instability compare well with numerical results obtained by Fournier et al., and the growth of a perturbation with time can be represented quite wellmore » by a second-degree polynomial, in accord with the linear stability analysis of Duff et al. The dispersion coefficient found from SPH simulation of flow and diffusion in an ideal fracture was in excellent agreement with the value predicted by the theory of Taylor and Aris. The simulations of miscible flow in fracture apertures can be used to determination dispersion coefficients for transport in fractured media - a parameter used in large-scale simulations of contaminant transport.« less

Glide twinning and pseudotwinning in peristerite: Si,Al diffusional stabilization and implications for the peristerite solvus

NASA Astrophysics Data System (ADS)

Brown, William L.

1989-07-01

Albite glide pseudotwins related to grain-boundary stresses have been observed in an exsolved peristerite (Brown 1989). The glide operation transposes the pre-existing periodic oligoclase/albite lamellae and interfaces into a position rotated by only ˜0.5° in the pseudotwins, but transforms the indices from (1bar 80) outside to ( 081) inside the pseudotwin. The pseudotwin is anti-ordered with respect to Al and Si and both it and the transposed interface are unstable. They should revert to the initial state on stress removal. If however the stresses are maintained for a sufficiently long time, the pseudotwins are stabilized by inversion of Si,Al order and re-orientation of the interface by an angle of about 30° into a position close to \\underline {(1bar 80)} . The continuous lamellae break up into a series of discs by diffusion of NaSi and CaAl, the minimum diffusion path being about the same as the thickness of the lamellae. On extrapolating available interdiffusion data in Ab-rich plagioclases to low temperatures, possible diffusion times may be calculated. The calculated times are long so that either the peristerite miscibility gap must be at a higher temperature than previously supposed or the low-temperature interdiffusion coefficients must be higher than the extrapolated experimental ones, or both. From recent data on ordering in albite, the crest of the gap is estimated to lie close to 650 625° C at low pressure and it is possible that interdiffusion under natural conditions is facilitated by hydrogen (protons) in feldspars.

Reactive sputter deposition of metal oxide nanolaminates

NASA Astrophysics Data System (ADS)

Rubin Aita, Carolyn

2008-07-01

We discuss the reactive sputter deposition of metal oxide nanolaminates on unheated substrates using four archetypical examples: ZrO2 Al2O3, HfO2 Al2O3, ZrO2 Y2O3, and ZrO2 TiO2. The pseudobinary bulk phase diagrams corresponding to these nanolaminates represent three types of interfaces. I. Complete immiscibility (ZrO2 Al2O3 and HfO2 Al2O3). II. Complete miscibility (ZrO2 Y2O3). III. Limited miscibility without a common end-member lattice (ZrO2 TiO2). We found that, although reactive sputter deposition is a far-from-equilibrium process, thermodynamic considerations strongly influence both phase formation within layers and at interfaces. We show that pseudobinary phase diagrams can be used to predict interfacial cation mixing in the nanolaminates. However, size effects must be considered to predict specific structures. In the absence of pseudoepitaxy, size effects play a significant role in determining the nanocrystalline phases that form within a layer (e.g. tetragonal ZrO2, tetragonal HfO2, and orthorhombic HfO2) and at interfaces (e.g. monoclinic (Zr,Ti)O2). These phases are not bulk standard temperature and pressure phases. Their formation is understood in terms of self-assembly into the lowest energy structure in individual critical nuclei.

Passive blast pressure sensor

DOEpatents

King, Michael J.; Sanchez, Roberto J.; Moss, William C.

2013-03-19

A passive blast pressure sensor for detecting blast overpressures of at least a predetermined minimum threshold pressure. The blast pressure sensor includes a piston-cylinder arrangement with one end of the piston having a detection surface exposed to a blast event monitored medium through one end of the cylinder and the other end of the piston having a striker surface positioned to impact a contact stress sensitive film that is positioned against a strike surface of a rigid body, such as a backing plate. The contact stress sensitive film is of a type which changes color in response to at least a predetermined minimum contact stress which is defined as a product of the predetermined minimum threshold pressure and an amplification factor of the piston. In this manner, a color change in the film arising from impact of the piston accelerated by a blast event provides visual indication that a blast overpressure encountered from the blast event was not less than the predetermined minimum threshold pressure.

Dynamics of miscible displacements in round tubes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meiburg, E.; Maxworthy, T.; Chen, C.Y.

A combined experimental and numerical investigation of miscible two-phase flow in a capillary tube is reported. The fraction of fluid left behind on the wall is obtained as a function of the Peclet, Atwood, and Froude numbers. Scaling arguments are presented for two distinct flow regimes, dominated by diffusion and convection, respectively. In the latter one, an effective surface tension value can be estimated.

Low Mach number fluctuating hydrodynamics of multispecies liquid mixtures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Donev, Aleksandar, E-mail: donev@courant.nyu.edu; Bhattacharjee, Amit Kumar; Nonaka, Andy

We develop a low Mach number formulation of the hydrodynamic equations describing transport of mass and momentum in a multispecies mixture of incompressible miscible liquids at specified temperature and pressure, which generalizes our prior work on ideal mixtures of ideal gases [Balakrishnan et al., “Fluctuating hydrodynamics of multispecies nonreactive mixtures,” Phys. Rev. E 89 013017 (2014)] and binary liquid mixtures [Donev et al., “Low mach number fluctuating hydrodynamics of diffusively mixing fluids,” Commun. Appl. Math. Comput. Sci. 9(1), 47-105 (2014)]. In this formulation, we combine and extend a number of existing descriptions of multispecies transport available in the literature. Themore » formulation applies to non-ideal mixtures of arbitrary number of species, without the need to single out a “solvent” species, and includes contributions to the diffusive mass flux due to gradients of composition, temperature, and pressure. Momentum transport and advective mass transport are handled using a low Mach number approach that eliminates fast sound waves (pressure fluctuations) from the full compressible system of equations and leads to a quasi-incompressible formulation. Thermal fluctuations are included in our fluctuating hydrodynamics description following the principles of nonequilibrium thermodynamics. We extend the semi-implicit staggered-grid finite-volume numerical method developed in our prior work on binary liquid mixtures [Nonaka et al., “Low mach number fluctuating hydrodynamics of binary liquid mixtures,” http://arxiv.org/abs/1410.2300 (2015)] and use it to study the development of giant nonequilibrium concentration fluctuations in a ternary mixture subjected to a steady concentration gradient. We also numerically study the development of diffusion-driven gravitational instabilities in a ternary mixture and compare our numerical results to recent experimental measurements [Carballido-Landeira et al., “Mixed-mode instability of a miscible interface due to coupling between Rayleigh–Taylor and double-diffusive convective modes,” Phys. Fluids 25, 024107 (2013)] in a Hele-Shaw cell. We find that giant nonequilibrium fluctuations can trigger the instability but are eventually dominated by the deterministic growth of the unstable mode, in both quasi-two-dimensional (Hele-Shaw) and fully three-dimensional geometries used in typical shadowgraph experiments.« less

Phase Behaviour and Miscibility Studies of Collagen/Silk Fibroin Macromolecular System in Dilute Solutions and Solid State.

PubMed

Ghaeli, Ima; de Moraes, Mariana A; Beppu, Marisa M; Lewandowska, Katarzyna; Sionkowska, Alina; Ferreira-da-Silva, Frederico; Ferraz, Maria P; Monteiro, Fernando J

2017-08-18

Miscibility is an important issue in biopolymer blends for analysis of the behavior of polymer pairs through the detection of phase separation and improvement of the mechanical and physical properties of the blend. This study presents the formulation of a stable and one-phase mixture of collagen and regenerated silk fibroin (RSF), with the highest miscibility ratio between these two macromolecules, through inducing electrostatic interactions, using salt ions. For this aim, a ternary phase diagram was experimentally built for the mixtures, based on observations of phase behavior of blend solutions with various ratios. The miscibility behavior of the blend solutions in the miscible zones of the phase diagram was confirmed quantitatively by viscosimetric measurements. Assessing the effects of biopolymer mixing ratio and salt ions, before and after dialysis of blend solutions, revealed the importance of ion-specific interactions in the formation of coacervate-based materials containing collagen and RSF blends that can be used in pharmaceutical, drug delivery, and biomedical applications. Moreover, the conformational change of silk fibroin from random coil to beta sheet, in solution and in the final solid films, was detected by circular dichroism (CD) and Fourier transform infrared spectroscopy (FTIR), respectively. Scanning electron microscopy (SEM) exhibited alterations of surface morphology for the biocomposite films with different ratios. Surface contact angle measurement illustrated different hydrophobic properties for the blended film surfaces. Differential scanning calorimetry (DSC) showed that the formation of the beta sheet structure of silk fibroin enhances the thermal stability of the final blend films. Therefore, the novel method presented in this study resulted in the formation of biocomposite films whose physico-chemical properties can be tuned by silk fibroin conformational changes by applying different component mixing ratios.

Dancing droplets: Chemical space, substrates, and control

NASA Astrophysics Data System (ADS)

Cira, Nate; Benusiglio, Adrien; Prakash, Manu

2015-11-01

Previously we showed that droplets of propylene glycol and water display remarkable properties when placed on clean glass due to an interplay between surface tension and evaporation. (Cira, Benusiglio, Prakash: Nature, 2015). We showed that these mechanisms apply to a range of two-component mixtures of miscible liquids where one component has both higher surface tension and higher vapor pressure on a variety of high energy surfaces. We now show how this rule can be cheated using a simple trick. We go on to demonstrate applications for cleaning, and show how this system works on substrates prepared only with sunlight. We finish by demonstrating active control of droplets, allowing access to a host of new possibilities.

Firefighter's compressed air breathing system pressure vessel development program

NASA Technical Reports Server (NTRS)

Beck, E. J.

1974-01-01

The research to design, fabricate, test, and deliver a pressure vessel for the main component in an improved high-performance firefighter's breathing system is reported. The principal physical and performance characteristics of the vessel which were required are: (1) maximum weight of 9.0 lb; (2) maximum operating pressure of 4500 psig (charge pressure of 4000 psig); (3) minimum contained volume of 280 in. 3; (4) proof pressure of 6750 psig; (5) minimum burst pressure of 9000 psig following operational and service life; and (6) a minimum service life of 15 years. The vessel developed to fulfill the requirements described was completely sucessful, i.e., every category of performence was satisfied. The average weight of the vessel was found to be about 8.3 lb, well below the 9.0 lb specification requirement.

Development of a test method for distillation of diesel-biodiesel-alcohols mixtures at reduced pressure

NASA Astrophysics Data System (ADS)

Niculescu, R.; Iosub, I.; Clenci, A.; Zaharia, C.; Iorga-Simăn, V.

2017-10-01

Increased environmental awareness and depletion of fossil petroleum resources are driving the automotive industry to seek out and use alternative fuels. For instance, the biofuel is a major renewable energy source to supplement declining fossil fuel resources. The addition of alcohols like methanol and ethanol is practical in biodiesel blends due to its miscibility with the pure biodiesel. Alcohols also improve physico-chemical properties of biodiesel blends, which lead to improved combustion efficiency. Proper volatility of fuels is critical to the operation of internal combustion engines with respect to both performance and emissions. Volatility may be characterised by various measurements, the most common of which are vapour pressure, distillation and the vapour/liquid ratio. The presence of ethanol or other oxygenates may affect these properties and, as a result, performance and emissions, as well. However, in the case of diesel-biodiesel-alcohols mixtures, the variance of component volatility makes difficult the analysis of the overall volatility. Thus, the paper presents an experimental method of distilling diesel-biodiesel-alcohols mixtures by adjusting the boiler pressure of an i-Fischer Dist equipment.

Mobility control experience in the Joffre Viking miscible CO[sub 2] flood

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luhning, R.W.; Stephenson, D.J.; Graham, A.G.

1993-08-01

This paper discusses mobility control in the Joffre Viking field miscible CO[sub 2] flood. Since 1984, three injection strategies have been tried: water-alternating-CO[sub 2] (WACO[sub 2]), continuous CO[sub 2], and simultaneous CO[sub 2] and water. The studies showed that simultaneous injection results in the best CO[sub 2] conformance. CO[sub 2]-foam injection has also been investigated.

Structure functions in decomposing Au-Pt systems

NASA Astrophysics Data System (ADS)

Glas, R.; Blaschko, O.; Rosta, L.

1992-09-01

The evolution of Au-Pt alloys quenched within the miscibility gap is investigated by small-angle neutron-scattering techniques. Moreover, in the vicinity of fundamental Bragg reflections the evolution of ``sideband'' satellites induced by a lattice-parameter modulation connected with the precipitation pattern is investigated by diffuse scattering methods. Structure functions are evaluated for a series of concentrations within the miscibility gap and compared to recent results of the literature.

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal), Class I

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bou-Mikael, Sami

This project outlines a proposal to improve the recovery of light oil from waterflooded fluvial dominated deltaic (FDD) reservoir through a miscible carbon dioxide (CO2) flood. The site is the Port Neches Field in Orange County, Texas. The field is well explored and well exploited. The project area is 270 acres within the Port Neches Field.

Implications of surfactant-induced flow for miscible-displacement estimation of air-water interfacial areas in unsaturated porous media.

PubMed

Costanza-Robinson, Molly S; Zheng, Zheng; Henry, Eric J; Estabrook, Benjamin D; Littlefield, Malcolm H

2012-10-16

Surfactant miscible-displacement experiments represent a conventional means of estimating air-water interfacial area (A(I)) in unsaturated porous media. However, changes in surface tension during the experiment can potentially induce unsaturated flow, thereby altering interfacial areas and violating several fundamental method assumptions, including that of steady-state flow. In this work, the magnitude of surfactant-induced flow was quantified by monitoring moisture content and perturbations to effluent flow rate during miscible-displacement experiments conducted using a range of surfactant concentrations. For systems initially at 83% moisture saturation (S(W)), decreases of 18-43% S(W) occurred following surfactant introduction, with the magnitude and rate of drainage inversely related to the surface tension of the surfactant solution. Drainage induced by 0.1 mM sodium dodecyl benzene sulfonate, commonly used for A(I) estimation, resulted in effluent flow rate increases of up to 27% above steady-state conditions and is estimated to more than double the interfacial area over the course of the experiment. Depending on the surfactant concentration and the moisture content used to describe the system, A(I) estimates varied more than 3-fold. The magnitude of surfactant-induced flow is considerably larger than previously recognized and casts doubt on the reliability of A(I) estimation by surfactant miscible-displacement.

Giant Plasma Membrane Vesicles: An Experimental Tool for Probing the Effects of Drugs and Other Conditions on Membrane Domain Stability.

PubMed

Gerstle, Zoe; Desai, Rohan; Veatch, Sarah L

2018-01-01

Giant plasma membrane vesicles (GPMVs) are isolated directly from living cells and provide an alternative to vesicles constructed of synthetic or purified lipids as an experimental model system for use in a wide range of assays. GPMVs capture much of the compositional protein and lipid complexity of intact cell plasma membranes, are filled with cytoplasm, and are free from contamination with membranes from internal organelles. GPMVs often exhibit a miscibility transition below the growth temperature of their parent cells. GPMVs labeled with a fluorescent protein or lipid analog appear uniform on the micron-scale when imaged above the miscibility transition temperature, and separate into coexisting liquid domains with differing membrane compositions and physical properties below this temperature. The presence of this miscibility transition in isolated GPMVs suggests that a similar phase-like heterogeneity occurs in intact plasma membranes under growth conditions, albeit on smaller length scales. In this context, GPMVs provide a simple and controlled experimental system to explore how drugs and other environmental conditions alter the composition and stability of phase-like domains in intact cell membranes. This chapter describes methods to generate and isolate GPMVs from adherent mammalian cells and to interrogate their miscibility transition temperatures using fluorescence microscopy. © 2018 Elsevier Inc. All rights reserved.

Understanding How the Presence of Uniform Electric Fields Can Shift the Miscibility of Polystyrene/Poly(vinyl methyl ether) Blends

NASA Astrophysics Data System (ADS)

Kriisa, Annika; Roth, Connie B.

2015-03-01

Techniques which can externally control and manipulate the phase behavior of polymeric systems, without altering chemistry on a molecular level, have great practical benefits. One such possible mechanism is the use of electric fields, shown to cause interfacial instabilities, orientation of morphologies, and phase transitions in polymer blends and block copolymers. We have recently demonstrated that the presence of uniform electric fields can also strongly enhance the miscibility of polystyrene (PS) / poly(vinyl methyl ether) (PVME) blends [J. Chem. Phys. 2014, 141, 134908]. Using fluorescence to measure the phase separation temperature Ts of PS/PVME blends with and without electric fields, we show that Ts can be reproducibly and reversibly increased by 13.5 +/- 1.4 K for electric fields of 17 kV/mm for this lower critical solution temperature (LCST) blend. This increase in blend miscibility with electric fields represents some of the largest absolute shifts in Ts ever recorded, well outside of experimental error. The best theoretical prediction for the expected shift in Ts with electric field for this system is still two orders of magnitude smaller than that observed experimentally. We discuss the limitations of this theoretical prediction and consider possible factors affecting miscibility that may need to be also included.

Oesophageal bioadhesion of sodium alginate suspensions: particle swelling and mucosal retention.

PubMed

Richardson, J Craig; Dettmar, Peter W; Hampson, Frank C; Melia, Colin D

2004-09-01

This paper describes a prospective bioadhesive liquid dosage form designed to specifically adhere to the oesophageal mucosa. It contains a swelling polymer, sodium alginate, suspended in a water-miscible vehicle and is activated by dilution with saliva to form an adherent layer of polymer on the mucosal surface. The swelling of alginate particles and the bioadhesion of 40% (w/w) sodium alginate suspensions were investigated in a range of vehicles: glycerol, propylene glycol, PEG 200 and PEG 400. Swelling of particles as a function of vehicle dilution with artificial saliva was quantified microscopically using 1,9-dimethyl methylene blue (DMMB) as a visualising agent. The minimum vehicle dilution to initiate swelling varied between vehicles: glycerol required 30% (w/w) dilution whereas PEG 400 required nearly 60% (w/w). Swelling commenced when the Hildebrand solubility parameter of the diluted vehicle was raised to 37 MPa(1/2). The bioadhesive properties of suspensions were examined by quantifying the amount of sodium alginate retained on oesophageal mucosa after washing in artificial saliva. Suspensions exhibited considerable mucoretention and strong correlations were obtained between mucosal retention, the minimum dilution to initiate swelling, and the vehicle Hildebrand solubility parameter. These relationships may allow predictive design of suspensions with specific mucoretentive properties, through judicious choice of vehicle characteristics.

Recycle of mixed automotive plastics: A model study

NASA Astrophysics Data System (ADS)

Woramongconchai, Somsak

This research investigated blends of virgin automotive plastics which were identified through market analysis. The intent was that this study could be used as a basis for further research in blends of automotive plastics recyclate. The effects of temperature, shear, time, and degree of mixing in a two-roll mill, a single-screw extruder, and a twin-screw extruder were investigated. Properties were evaluated in terms of melt flow, rigidity, strength, impact, heat resistance, electrical resistivity, color, and resistance to water and gasoline. Torque rheometry, dynamic mechanical analysis (DMA), optical and scanning electron microscopy were used to characterize the processability and morphology of major components of the blends. The two-roll mill was operated at high temperature, short time, and low roll speed to avoid discolored and degraded materials. The single-screw extruder and twin-screw extruder were operated at medium and high temperature and high screw speed, respectively, for optimizing head pressure, residence time, shear and degree of mixing of the materials. Melt index increased with extrusion temperature. Flexural modulus increased with the processing temperatures in milling or twin-screw extrusion, but decreased with the increasing single-screw extrusion temperature. Tensile modulus was also enhanced by increasing processing temperature. The tensile strengths for each process were similar and relatively low. The impact strength increased with temperature and roll speed in two-roll milling, was unaffected by the single-screw extrusion temperature and decreased with increasing twin-screw extrusion temperature. Heat resistance was always reduced by higher processing temperature. The volume resistivity increased, water absorption was unaffected and gasoline absorption altered by increased processing temperature. The latter increased somewhat with mill temperature, roll speed (two-roll mill) and higher extrusion temperature (single-screw extruder), but decreased with increased twin-screw extrusion temperature. The flexural modulus of the recycled mixed automotive plastics expected in 2003 was higher than the 1980s and 1990 recycle. Flexural strength effects were not large enough for serious consideration, but were more dominant when compared to those in the 1980s and 1990s. Impact strengths at 20-30 J/m were the lowest value compared to the 1980s and 1990s mixed automotive recycle. Torque rheometry, dynamic mechanical analysis and optical and electron microscopy agreed with each other on the characterization of the processability and morphology of the blends. LLDPE and HDPE were miscible while PP was partially miscible with polyethylene. ABS and nylon-6 were immiscible with the polyolefins, but partially miscible with each other. As expected, the polyurethane foam was immiscible with the other components. The minor components of the model recycle of mixed automotive materials were probably partially miscible with ABS/nylon-6, but there were multiple and unresolved phases in the major blends.

Investigation of immiscible systems and potential applications

NASA Technical Reports Server (NTRS)

Markworth, A. J.; Oldfield, W.; Duga, J.; Gelles, S. H.

1975-01-01

The droplet coalescence kinetics at 0 g and 1 g were considered for two systems which contained liquid droplets in a host liquid. One of these (Al-In) typified a system containing a liquid phase miscibility gap and the order (oil-water) a mixture of two essentially insoluble liquids. A number of coalescence mechanisms potentially prominent at low g in this system were analyzed and explanations are presented for the observed unusual stability of the emulsion. Ground base experiments were conducted on the coalescence of In droplets in and Al-In alloy during cooling through the miscibility gap at different cooling rates. These were in qualitative agreement with the computer simulation. Potential applications for systems with liquid phase miscibility gaps were explored. Possibilities included superconductors, electrical contact materials, superplastic materials, catalysts, magnetic materials, and others. The role of space processing in their production was also analyzed.

Numerical simulation of miscible viscous fingering with viscosity change in a displacing fluid by chemical reaction

NASA Astrophysics Data System (ADS)

Omori, Keiichiro; Nagatsu, Yuichiro

2017-11-01

Viscous fingering (VF) with viscosity changes by chemical reactions in case of miscible systems have been investigated both experimentally and theoretically in the recent years. Nagatsu et al. investigated experimentally miscible VF in which viscosity of the displaced fluid or the displacing one is changed by fast chemical reaction They showed that VF was more dense by the viscosity increase whereas less dense by the viscosity increase regardless of whether the viscosity change occurs in the displaced fluid or displacing one. From a theoretical viewpoint, numerical simulation performed on the reactive VF where viscosity of the displaced fluid is changed by instantaneously fast chemical reaction. The results had a good agreement with those in the corresponding experiment. In this work, we have conducted numerical simulation on such reactive VF where viscosity of the displacing fluid is changed. We have found the results have a good agreement with the corresponding experimental ones.

Miscibility phase diagram of ring-polymer blends: A topological effect.

PubMed

Sakaue, Takahiro; Nakajima, Chihiro H

2016-04-01

The miscibility of polymer blends, a classical problem in polymer science, may be altered, if one or both of the component do not have chain ends. Based on the idea of topological volume, we propose a mean-field theory to clarify how the topological constraints in ring polymers affect the phase behavior of the blends. While the large enhancement of the miscibility is expected for ring-linear polymer blends, the opposite trend toward demixing, albeit comparatively weak, is predicted for ring-ring polymer blends. Scaling formulas for the shift of critical point for both cases are derived. We discuss the valid range of the present theory, and the crossover to the linear polymer blends behaviors, which is expected for short chains. These analyses put forward a view that the topological constraints could be represented as an effective excluded-volume effects, in which the topological length plays a role of the screening factor.

Analytical and variational numerical methods for unstable miscible displacement flows in porous media

NASA Astrophysics Data System (ADS)

Scovazzi, Guglielmo; Wheeler, Mary F.; Mikelić, Andro; Lee, Sanghyun

2017-04-01

The miscible displacement of one fluid by another in a porous medium has received considerable attention in subsurface, environmental and petroleum engineering applications. When a fluid of higher mobility displaces another of lower mobility, unstable patterns - referred to as viscous fingering - may arise. Their physical and mathematical study has been the object of numerous investigations over the past century. The objective of this paper is to present a review of these contributions with particular emphasis on variational methods. These algorithms are tailored to real field applications thanks to their advanced features: handling of general complex geometries, robustness in the presence of rough tensor coefficients, low sensitivity to mesh orientation in advection dominated scenarios, and provable convergence with fully unstructured grids. This paper is dedicated to the memory of Dr. Jim Douglas Jr., for his seminal contributions to miscible displacement and variational numerical methods.

Computer-aided method for the determination of Hansen solubility parameters. Application to the miscibility of refrigerating lubricant and new refrigerant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Remigy, J.C.; Nakache, E.; Brechot, P.D.

This article presents a method which allows one to find the Hansen solubility parameters by means of data processing. In the first part, the authors present the thermodynamical principle of Hansen parameters, and then they explain the model used to find parameters from experimental data. They validate the method by studying the solubility parameters of CFC-12 (dichlorodifluoromethane), HFC-134a (1,1,1,2-tetrafluoroethane), neopentylglycol esters, trimethylolpropane esters, dipentaerythritol esters, and pentaerythritol esters. Then, the variation of Hansen parameters are studied as well as the relation between the miscibility temperature (the temperature at which a blend passes from the miscible state to the immiscible state)more » and the interaction distance. The authors establish the critical interaction distance of HFC-134a which determines the solubility limit and they study its variation with temperature.« less

DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni

This report describes the progress of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the second project year (October 1, 2003--September 30, 2004). There are three main tasks in this research project. Task 1 is scaled physical model study of GAGD process. Task 2 is further development of vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. In Section I, preliminary design of the scaled physical model using the dimensional similarity approach has been presented. Scaled experiments onmore » the current physical model have been designed to investigate the effect of Bond and capillary numbers on GAGD oil recovery. Experimental plan to study the effect of spreading coefficient and reservoir heterogeneity has been presented. Results from the GAGD experiments to study the effect of operating mode, Bond number and capillary number on GAGD oil recovery have been reported. These experiments suggest that the type of the gas does not affect the performance of GAGD in immiscible mode. The cumulative oil recovery has been observed to vary exponentially with Bond and capillary numbers, for the experiments presented in this report. A predictive model using the bundle of capillary tube approach has been developed to predict the performance of free gravity drainage process. In Section II, a mechanistic Parachor model has been proposed for improved prediction of IFT as well as to characterize the mass transfer effects for miscibility development in reservoir crude oil-solvent systems. Sensitivity studies on model results indicate that provision of a single IFT measurement in the proposed model is sufficient for reasonable IFT predictions. An attempt has been made to correlate the exponent (n) in the mechanistic model with normalized solute compositions present in both fluid phases. IFT measurements were carried out in a standard ternary liquid system of benzene, ethanol and water using drop shape analysis and capillary rise techniques. The experimental results indicate strong correlation among the three thermodynamic properties solubility, miscibility and IFT. The miscibility determined from IFT measurements for this ternary liquid system is in good agreement with phase diagram and solubility data, which clearly indicates the sound conceptual basis of VIT technique to determine fluid-fluid miscibility. Model fluid systems have been identified for VIT experimentation at elevated pressures and temperatures. Section III comprises of the experimental study aimed at evaluating the multiphase displacement characteristics of the various gas injection EOR process performances using Berea sandstone cores. During this reporting period, extensive literature review was completed to: (1) study the gravity drainage concepts, (2) identify the various factors influencing gravity stable gas injection processes, (3) identify various multiphase mechanisms and fluid dynamics operative during the GAGD process, and (4) identify important dimensionless groups governing the GAGD process performance. Furthermore, the dimensional analysis of the GAGD process, using Buckingham-Pi theorem to isolate the various dimensionless groups, as well as experimental design based on these dimensionless quantities have been completed in this reporting period. On the experimental front, recommendations from previous WAG and CGI have been used to modify the experimental protocol. This report also includes results from scaled preliminary GAGD displacements as well as the details of the planned GAGD corefloods for the next quarter. The technology transfer activities have mainly consisted of preparing technical papers, progress reports and discussions with industry personnel for possible GAGD field tests.« less

49 CFR 178.44 - Specification 3HT seamless steel cylinders for aircraft use.

Code of Federal Regulations, 2011 CFR

2011-10-01

... with a water capacity (nominal) of not over 150 pounds and a service pressure of at least 900 psig. (b...., should be held to a minimum consistent with good high stress pressure vessel manufacturing practices. If... wall thickness must be such that the wall stress at the minimum specified test pressure may not exceed...

46 CFR 162.028-3 - Requirements.

Code of Federal Regulations, 2012 CFR

2012-10-01

... which are subjected to pressure, exclusive of the hose, shall be at least five times the maximum working... which will withstand a minimum bursting pressure of 6,000 p.s.i., and a discharge hose or tube which will withstand a minimum bursting pressure of 5,000 p.s.i. The hose shall be constructed with either a...

46 CFR 162.028-3 - Requirements.

Code of Federal Regulations, 2014 CFR

2014-10-01

... which are subjected to pressure, exclusive of the hose, shall be at least five times the maximum working... which will withstand a minimum bursting pressure of 6,000 p.s.i., and a discharge hose or tube which will withstand a minimum bursting pressure of 5,000 p.s.i. The hose shall be constructed with either a...

46 CFR 162.028-3 - Requirements.

Code of Federal Regulations, 2013 CFR

2013-10-01

... which are subjected to pressure, exclusive of the hose, shall be at least five times the maximum working... which will withstand a minimum bursting pressure of 6,000 p.s.i., and a discharge hose or tube which will withstand a minimum bursting pressure of 5,000 p.s.i. The hose shall be constructed with either a...

Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni

This is the final report describing the evolution of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' from its conceptual stage in 2002 to the field implementation of the developed technology in 2006. This comprehensive report includes all the experimental research, models developments, analyses of results, salient conclusions and the technology transfer efforts. As planned in the original proposal, the project has been conducted in three separate and concurrent tasks: Task 1 involved a physical model study of the new GAGD process, Task 2 was aimed at further developing the vanishing interfacialmore » tension (VIT) technique for gas-oil miscibility determination, and Task 3 was directed at determining multiphase gas-oil drainage and displacement characteristics in reservoir rocks at realistic pressures and temperatures. The project started with the task of recruiting well-qualified graduate research assistants. After collecting and reviewing the literature on different aspects of the project such gas injection EOR, gravity drainage, miscibility characterization, and gas-oil displacement characteristics in porous media, research plans were developed for the experimental work to be conducted under each of the three tasks. Based on the literature review and dimensional analysis, preliminary criteria were developed for the design of the partially-scaled physical model. Additionally, the need for a separate transparent model for visual observation and verification of the displacement and drainage behavior under gas-assisted gravity drainage was identified. Various materials and methods (ceramic porous material, Stucco, Portland cement, sintered glass beads) were attempted in order to fabricate a satisfactory visual model. In addition to proving the effectiveness of the GAGD process (through measured oil recoveries in the range of 65 to 87% IOIP), the visual models demonstrated three possible multiphase mechanisms at work, namely, Darcy-type displacement until gas breakthrough, gravity drainage after breakthrough and film-drainage in gas-invaded zones throughout the duration of the process. The partially-scaled physical model was used in a series of experiments to study the effects of wettability, gas-oil miscibility, secondary versus tertiary mode gas injection, and the presence of fractures on GAGD oil recovery. In addition to yielding recoveries of up to 80% IOIP, even in the immiscible gas injection mode, the partially-scaled physical model confirmed the positive influence of fractures and oil-wet characteristics in enhancing oil recoveries over those measured in the homogeneous (unfractured) water-wet models. An interesting observation was that a single logarithmic relationship between the oil recovery and the gravity number was obeyed by the physical model, the high-pressure corefloods and the field data.« less

Developing a pressure ulcer risk factor minimum data set and risk assessment framework.

PubMed

Coleman, Susanne; Nelson, E Andrea; Keen, Justin; Wilson, Lyn; McGinnis, Elizabeth; Dealey, Carol; Stubbs, Nikki; Muir, Delia; Farrin, Amanda; Dowding, Dawn; Schols, Jos M G A; Cuddigan, Janet; Berlowitz, Dan; Jude, Edward; Vowden, Peter; Bader, Dan L; Gefen, Amit; Oomens, Cees W J; Schoonhoven, Lisette; Nixon, Jane

2014-10-01

To agree a draft pressure ulcer risk factor Minimum Data Set to underpin the development of a new evidenced-based Risk Assessment Framework. A recent systematic review identified the need for a pressure ulcer risk factor Minimum Data Set and development and validation of an evidenced-based pressure ulcer Risk Assessment Framework. This was undertaken through the Pressure UlceR Programme Of reSEarch (RP-PG-0407-10056), funded by the National Institute for Health Research and incorporates five phases. This article reports phase two, a consensus study. Consensus study. A modified nominal group technique based on the Research and Development/University of California at Los Angeles appropriateness method. This incorporated an expert group, review of the evidence and the views of a Patient and Public Involvement service user group. Data were collected December 2010-December 2011. The risk factors and assessment items of the Minimum Data Set (including immobility, pressure ulcer and skin status, perfusion, diabetes, skin moisture, sensory perception and nutrition) were agreed. In addition, a draft Risk Assessment Framework incorporating all Minimum Data Set items was developed, comprising a two stage assessment process (screening and detailed full assessment) and decision pathways. The draft Risk Assessment Framework will undergo further design and pre-testing with clinical nurses to assess and improve its usability. It will then be evaluated in clinical practice to assess its validity and reliability. The Minimum Data Set could be used in future for large scale risk factor studies informing refinement of the Risk Assessment Framework. © 2014 The Authors. Journal of Advanced Nursing Published by John Wiley & Sons Ltd.

Activation of porous MOF materials

DOEpatents

Hupp, Joseph T; Farha, Omar K

2013-04-23

A method for the treatment of solvent-containing MOF material to increase its internal surface area involves introducing a liquid into the MOF in which liquid the solvent is miscible, subjecting the MOF to supercritical conditions for a time to form supercritical fluid, and releasing the supercritical conditions to remove the supercritical fluid from the MOF. Prior to introducing the liquid into the MOF, occluded reaction solvent, such as DEF or DMF, in the MOF can be exchanged for the miscible solvent.

Activation of porous MOF materials

DOEpatents

Hupp, Joseph T; Farha, Omar K

2014-04-01

A method for the treatment of solvent-containing MOF material to increase its internal surface area involves introducing a liquid into the MOF in which liquid the solvent is miscible, subjecting the MOF to supercritical conditions for a time to form supercritical fluid, and releasing the supercritical conditions to remove the supercritcal fluid from the MOF. Prior to introducing the liquid into the MOF, occluded reaction solvent, such as DEF or DMF, in the MOF can be exchanged for the miscible solvent.

Vapor-liquid equilibria for R-22, R-134a, R-125, and R-32/125 with a polyol ester lubricant: Measurements and departure from ideality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martz, W.L.; Burton, C.M.; Jacobi, A.M.

1996-11-01

The effect of a polyol ester lubricant on equilibrium pressure, liquid density, and viscosity is presented for R-22, R-125, and R-134a at varying temperatures and concentrations. Preliminary vapor-liquid equilibrium (VLE) data and miscibility observations are also presented for an R-32/R-125 blend (50%/50%) with the ISO 68 polyol ester (POE). Real-gas behavior is modeled using the vapor-phase fugacity, and vapor pressure effects on liquid fugacities are taken into account with the Poynting effect. Positive, negative, and mixed deviations form the Lewis-Randall rule are observed in the activity coefficient behavior. Departures from ideality are related to molecular size differences, intermolecular forces inmore » the mixture, and other factors. The data are discussed in the context of previous results for other refrigerants and thermodynamic modeling of refrigerant and oil mixtures.« less

Miscibility and Phase Behavior of N-Acylethanolamine/Diacylphosphatidylethanolamine Binary Mixtures of Matched Acyl Chainlengths (n = 14, 16)

PubMed Central

Kamlekar, Ravi Kanth; Satyanarayana, S.; Marsh, Derek; Swamy, Musti J.

2007-01-01

The miscibility and phase behavior of hydrated binary mixtures of two N-acylethanolamines (NAEs), N-myristoylethanolamine (NMEA), and N-palmitoylethanolamine (NPEA), with the corresponding diacyl phosphatidylethanolamines (PEs), dimyristoylphosphatidylethanolamine (DMPE), and dipalmitoylphosphatidylethanolamine (DPPE), respectively, have been investigated by differential scanning calorimetry (DSC), spin-label electron spin resonance (ESR), and 31P-NMR spectroscopy. Temperature-composition phase diagrams for both NMEA/DMPE and NPEA/DPPE binary systems were established from high sensitivity DSC. The structures of the phases involved were determined by 31P-NMR spectroscopy. For both systems, complete miscibility in the fluid and gel phases is indicated by DSC and ESR, up to 35 mol % of NMEA in DMPE and 40 mol % of NPEA in DPPE. At higher contents of the NAEs, extensive solid-fluid phase separation and solid-solid immiscibility occur depending on the temperature. Characterization of the structures of the mixtures formed with 31P-NMR spectroscopy shows that up to 75 mol % of NAE, both DMPE and DPPE form lamellar structures in the gel phase as well as up to at least 65°C in the fluid phase. ESR spectra of phosphatidylcholine spin labeled at the C-5 position in the sn-2 acyl chain present at a probe concentration of 1 mol % exhibit strong spin-spin broadening in the low-temperature region for both systems, suggesting that the acyl chains pack very tightly and exclude the spin label. However, spectra recorded in the fluid phase do not exhibit any spin-spin broadening and indicate complete miscibility of the two components. The miscibility of NAE and diacyl PE of matched chainlengths is significantly less than that found earlier for NPEA and dipalmitoylphosphatidylcholine, an observation that is consistent with the notion that the NAEs are most likely stored as their precursor lipids (N-acyl PEs) and are generated only when the system is subjected to membrane stress. PMID:17369415

Dual resin bonded joints in polyetheretherketone (PEEK) matrix composites

NASA Astrophysics Data System (ADS)

Zelenak, Steve; Radford, Donald W.; Dean, Michael W.

1993-04-01

The paper describes applications of the dual resin (miscible polymer) bonding technique (Smiley, 1989) developed as an alternative to traditional bonding approaches to joining thermoplastic matrix composite subassemblies into structures. In the experiments, the performance of joint geometries, such as those that could be used to assemble large truss structures in space, are investigated using truss joint models consisting of woven carbon fiber/PEEK tubes of about 1 mm wall thickness. Specific process conditions and hand-held hardware used to apply heat and pressure were chosen to simulate a field asembly technique. Results are presented on tube/cruciform double lap shear tests, pinned-pinned tube compression tests, and single lap shear bond tests of joints obtained using the dual resin bonding technique.

Airfoil profiles for minimum pressure drag at supersonic velocities -- general analysis with application to linearized supersonic flow

NASA Technical Reports Server (NTRS)

Chapman, Dean R

1952-01-01

A theoretical investigation is made of the airfoil profile for minimum pressure drag at zero lift in supersonic flow. In the first part of the report a general method is developed for calculating the profile having the least pressure drag for a given auxiliary condition, such as a given structural requirement or a given thickness ratio. The various structural requirements considered include bending strength, bending stiffness, torsional strength, and torsional stiffness. No assumption is made regarding the trailing-edge thickness; the optimum value is determined in the calculations as a function of the base pressure. To illustrate the general method, the optimum airfoil, defined as the airfoil having minimum pressure drag for a given auxiliary condition, is calculated in a second part of the report using the equations of linearized supersonic flow.

Preparation of polydopamine nanocapsules in a miscible tetrahydrofuran-buffer mixture.

PubMed

Ni, Yun-Zhou; Jiang, Wen-Feng; Tong, Gang-Sheng; Chen, Jian-Xin; Wang, Jie; Li, Hui-Mei; Yu, Chun-Yang; Huang, Xiao-hua; Zhou, Yong-Feng

2015-01-21

A miscible tetrahydrofuran-tris buffer mixture has been used to fabricate polydopamine hollow capsules with a size of 200 nm and with a shell thickness of 40 nm. An unusual non-emulsion soft template mechanism has been disclosed to explain the formation of capsules. The results indicate that the capsule structure is highly dependent on the volume fraction of tetrahydrofuran as well as the solvent, and the shell thickness of capsules can be controlled by adjusting the reaction time and dopamine concentration.

Video of Miscible Fluid Experiment Conducted on NASA Low Gravity Airplane

NASA Technical Reports Server (NTRS)

2003-01-01

This is a video of dyed water being injected into glycerin in a 2.2 centimeter (cm) diameter test tube. The experiment was conducted on the KC-135 aircraft, a NASA plane that creates microgravity and 2g conditions as it maneuvers through multiple parabolas. The water is less dense and so it rises to the top of the glycerin. The goal of the experiment was to determine if a blob of a miscible fluid would spontaneously become spherical in a microgravity environment.

Free volume study on the miscibility of PEEK/PEI blend using positron annihilation and dynamic mechanical thermal analysis

NASA Astrophysics Data System (ADS)

Ramani, R.; Alam, S.

2015-06-01

High performance polymer blend of poly(ether ether ketone) (PEEK) and poly(ether imide) (PEI) was examined for their free volume behaviour using positron annihilation lifetime spectroscopy and dynamic mechanical thermal analysis methods. The fractional free volume obtained from PALS shows a negative deviation from linear additivity rule implying good miscibility between PEEK and PEI. The dynamic modulus and loss tangent were obtained for the blends at three different frequencies 1, 10 and 100 Hz at temperatures close to and above their glass transition temperature. Applying Time-Temperature-Superposition (TTS) principle to the DMTA results, master curves were obtained at a reference temperature To and the WLF coefficients c01 and c02 were evaluated. Both the methods give similar results for the dependence of fractional free volume on PEI content in this blend. The results reveal that free volume plays an important role in determining the visco-elastic properties in miscible polymer blends.

Development of a prototype experiment for treating CELSS and PCELSS wastes to produce nutrients for plant growth

NASA Technical Reports Server (NTRS)

1983-01-01

Future long term spaceflights require extensive recycling of wastes to minimize the need for resupplying the vessel. The recycling occurs in a fully or partially closed environment life support system (CELSS or PCELSS). The National Aeronautics and Space Administration (NASA) is interested in converting wastewater into potable water or water for hydroponic farming as part of a CELSS. The development of technologies for wastewater treatment that produce a minimum of by-products is essential. One process that achieves good conversion of moderately concentrated organic wastes in water (1 to 20% by weight) completely to carbon dioxide and water is oxidation in supercritical water. Both air (or oxygen) and many organics are completely miscible with supercritical water, so there are no interphase mass transport resistances that limits the overall oxidation reaction. The temperature of supercritical water, which must be above 374 C, is also sufficient to have rapid reaction kinetics for the oxidations.

Droplet squeezing through a narrow constriction: Minimum impulse and critical velocity

NASA Astrophysics Data System (ADS)

Zhang, Zhifeng; Drapaca, Corina; Chen, Xiaolin; Xu, Jie

2017-07-01

Models of a droplet passing through narrow constrictions have wide applications in science and engineering. In this paper, we report our findings on the minimum impulse (momentum change) of pushing a droplet through a narrow circular constriction. The existence of this minimum impulse is mathematically derived and numerically verified. The minimum impulse happens at a critical velocity when the time-averaged Young-Laplace pressure balances the total minor pressure loss in the constriction. Finally, numerical simulations are conducted to verify these concepts. These results could be relevant to problems of energy optimization and studies of chemical and biomedical systems.

Structural, Electronic, and Optical Properties of BiOX1-xYx (X, Y = F, Cl, Br, and I) Solid Solutions from DFT Calculations.

PubMed

Zhao, Zong-Yan; Liu, Qing-Lu; Dai, Wen-Wu

2016-08-23

Six BiOX1-xYx (X, Y = F, Cl, Br, and I) solid solutions have been systematically investigated by density functional theory calculations. BiOCl1-xBrx, BiOBr1-xIx, and BiOCl1-xIx solid solutions have very small bowing parameters; as such, some of their properties increase almost linearly with increasing x. For BiOF1-xYx solid solutions, the bowing parameters are very large and it is extremely difficult to fit the related calculated data by a single equation. Consequently, BiOX1-xYx (X, Y = Cl, Br, and I) solid solutions are highly miscible, while BiOF1-xYx (Y = Cl, Br, and I) solid solutions are partially miscible. In other words, BiOF1-xYx solid solutions have miscibility gaps or high miscibility temperature, resulting in phase separation and F/Y inhomogeneity. Comparison and analysis of the calculated results and the related physical-chemical properties with different halogen compositions indicates that the parameters of BiOX1-xYx solid solutions are determined by the differences of the physical-chemical properties of the two halogen compositions. In this way, the large deviation of some BiOX1-xYx solid solutions from Vegard's law observed in experiments can be explained. Moreover, the composition ratio of BiOX1-xYx solid solutions can be measured or monitored using optical measurements.

Small Angle Neutron Scattering Studies on Blends of Poly (Styrene-ran-Vinyl Phenol) with Liquid Crystalline Polyurethane

NASA Astrophysics Data System (ADS)

Mehta, Rujul

2005-03-01

Molecular composites, composed of uniformly dispersed rigid-rod liquid crystalline polymer (LCP) molecules in a flexible amorphous polymer matrix, have remained hitherto elusive due to a scarcity of miscible systems containing a LCP and an amorphous polymer. The production of such a blend, with an experimentally accessible miscibility window, has become possible by modifying the architecture of the flexible polymer, so as to induce favorable intermolecular hydrogen bonding. Specifically, liquid crystalline polyurethanes (LCPU) are found to be miscible with a copolymer of styrene and vinyl phenol; with optimum hydrogen bonding between the carbonyl groups of the urethane linkages and the hydroxyl groups present in the styrenic matrix. Availability of a truly miscible molecular composite presents a unique opportunity of studying the confirmation of polymer chains containing rigid-rods that are uniformly dispersed in a flexible coil matrix. A system consisting of the LCPU and the deuterated styrenic copolymer containing 20% vinyl phenol is examined by Small Angle Neutron Scattering at the National Center for Neutron Research at Gaithersburg and Technology, and the Institute of Solid State Research (IFF) at Jülich. Scattering curves for neat dPS-VPh did not fit the Debye-Bueche model; indicating complex structure. A two correlation length Debye-Bueche model was considered to accommodate for this nonlinear behavior. This model utilizes four fitting parameters, including two correlation lengths a1 and a2, corresponding to a Debye-Bueche model and Guinier model.

Comparison between hot-melt extrusion and spray-drying for manufacturing solid dispersions of the graft copolymer of ethylene glycol and vinylalcohol.

PubMed

Guns, Sandra; Dereymaker, Aswin; Kayaert, Pieterjan; Mathot, Vincent; Martens, Johan A; Van den Mooter, Guy

2011-03-01

To investigate the effect of the manufacturing method (spray-drying or hot-melt extrusion) on the kinetic miscibility of miconazole and the graft copolymer poly(ethyleneglycol-g-vinylalcohol). The effect of heat pre-treatment of solutions used for spray-drying and the use of spray-dried copolymer as excipient for hot-melt extrusion was investigated. The solid dispersions were prepared at different drug-polymer ratios and analyzed with modulated differential scanning calorimetry and X-ray powder diffraction. Miconazole either mixed with the PEG-fraction of the copolymer or crystallized in the same or a different polymorph as the starting material. The kinetic miscibility was higher for the solid dispersions obtained from solutions which were pre-heated compared to those spray-dried from solutions at ambient temperature. Hot-melt extrusion resulted in an even higher mixing capability. Here the use of the spray-dried copolymer did not show any benefit concerning the kinetic miscibility of the drug and copolymer, but it resulted in a remarkable decrease in the torque experienced by the extruder allowing extrusion at lower temperature and torque. The manufacturing method has an influence on the mixing capacity and phase behavior of solid dispersions. Heat pre-treatment of the solutions before spray-drying can result in a higher kinetic miscibility. Amorphization of the copolymer by spray-drying before using it as an excipient for hot-melt extrusion can be a manufacturing benefit.

42 CFR 84.82 - Gas pressure gages; minimum requirements.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 42 Public Health 1 2012-10-01 2012-10-01 false Gas pressure gages; minimum requirements. 84.82 Section 84.82 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Self...

42 CFR 84.82 - Gas pressure gages; minimum requirements.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 42 Public Health 1 2014-10-01 2014-10-01 false Gas pressure gages; minimum requirements. 84.82 Section 84.82 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Self...

42 CFR 84.82 - Gas pressure gages; minimum requirements.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Gas pressure gages; minimum requirements. 84.82 Section 84.82 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Self...

42 CFR 84.82 - Gas pressure gages; minimum requirements.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 42 Public Health 1 2013-10-01 2013-10-01 false Gas pressure gages; minimum requirements. 84.82 Section 84.82 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Self...

42 CFR 84.82 - Gas pressure gages; minimum requirements.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 42 Public Health 1 2011-10-01 2011-10-01 false Gas pressure gages; minimum requirements. 84.82 Section 84.82 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Self...

The transition from blueschist to greenschist facies modeled by the reaction glaucophane + 2 diopside + 2 quartz = tremolite + 2 albite

NASA Astrophysics Data System (ADS)

Jenkins, David M.

2011-10-01

The reaction glaucophane + 2 diopside + 2 quartz = tremolite + 2 albite is proposed to model the transition from the blueschist to greenschist facies. This reaction was investigated experimentally over the range of 1.0-2.1 GPa and 500-800°C using synthetic phases in the chemical system Na2O-CaO-MgO-Al2O3-SiO2-H2O. Reversals of this reaction were possible at 500 and 550°C and growth of the low-pressure assemblage at 600°C; however, at temperatures of 600°C and higher and at pressures above 1.6 GPa omphacite nucleation (at the expense of diopside and albite) became quite strong and prevented attaining clear reversals of this reaction. Compositional changes in the amphiboles were determined by both electron microprobe analyses and correlations between unit-cell dimensions and composition. Glaucophane and particularly tremolite showed clear signs of compositional re-equilibration and merged to a single amphibole of winchite composition by about 754°C. These data were used to model the miscibility gap between glaucophane and tremolite using either the asymmetric multicomponent formulism parameters of W TR,GL of 68 kJ with αTR of 1.0 and αGL of 0.75 or a simple two-site asymmetric thermodynamic mixing expression with Margules parameters W NaCa of 13.4 kJ and W CaNa of 19.3 kJ. Combination of these thermodynamic models of the miscibility gap with extant thermodynamic data for the other phases yields a calculated location of the above reaction, involving pure diopside and albite, that is in good agreement with the observed experimental reversals and amphibole compositions over the range of 0.94-1.93 GPa and 400-754°C. The calculated effect of jadeite solid solution into diopside is to reduce the dP/dT slope from 0.0028 to 0.0021 GPa/°C and decrease the pressure by 0.28 GPa at 754°C. The dP/dT slope of this reaction boundary lies close to a linear geotherm of 13°C/km and is consistent with the slopes of other solid-solid reactions that have been used to model the blueschist-to-greenschist facies transition.

Generalization of low pressure, gas-liquid, metastable sound speed to high pressures

NASA Technical Reports Server (NTRS)

Bursik, J. W.; Hall, R. M.

1981-01-01

A theory is developed for isentropic metastable sound propagation in high pressure gas-liquid mixtures. Without simplification, it also correctly predicts the minimum speed for low pressure air-water measurements where other authors are forced to postulate isothermal propagation. This is accomplished by a mixture heat capacity ratio which automatically adjusts from its single phase values to approximately the isothermal value of unity needed for the minimum speed. Computations are made for the pure components parahydrogen and nitrogen, with emphasis on the latter. With simplifying assumptions, the theory reduces to a well known approximate formula limited to low pressure.

42 CFR 84.86 - Component parts exposed to oxygen pressures; minimum requirements.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 42 Public Health 1 2013-10-01 2013-10-01 false Component parts exposed to oxygen pressures; minimum requirements. 84.86 Section 84.86 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY...

42 CFR 84.86 - Component parts exposed to oxygen pressures; minimum requirements.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 42 Public Health 1 2012-10-01 2012-10-01 false Component parts exposed to oxygen pressures; minimum requirements. 84.86 Section 84.86 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY...

42 CFR 84.86 - Component parts exposed to oxygen pressures; minimum requirements.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 42 Public Health 1 2011-10-01 2011-10-01 false Component parts exposed to oxygen pressures; minimum requirements. 84.86 Section 84.86 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY...

42 CFR 84.86 - Component parts exposed to oxygen pressures; minimum requirements.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 42 Public Health 1 2014-10-01 2014-10-01 false Component parts exposed to oxygen pressures; minimum requirements. 84.86 Section 84.86 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY...

42 CFR 84.86 - Component parts exposed to oxygen pressures; minimum requirements.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Component parts exposed to oxygen pressures; minimum requirements. 84.86 Section 84.86 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES OCCUPATIONAL SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY...

Entanglement in miscible blends

NASA Astrophysics Data System (ADS)

Watanabe, Hiroshi

2010-03-01

The entanglement length Le of polymer chains (corresponding to the entanglement molecular weight Me) is not an intrinsic material parameter but changes with the interaction with surrounding chains. For miscible blends of cis-polyisoprene (PI) and poly(tert-butyl styrene) (PtBS), changes of Le on blending was examined. It turned out that the Le averaged over the number fractions of the Kuhn segments of the components (PI and PtBS) satisfactorily describes the viscoelastic behavior of pseudo-monodisperse blends in which the terminal relaxation time is the same for PI and PtBS.

Evidence of a miscibility gap in the FeTe1-xSex polycrystalline samples prepared with a melting process

NASA Astrophysics Data System (ADS)

Sala, A.; Palenzona, A.; Bernini, C.; Caglieris, F.; Cimberle, M. R.; Ferdeghini, C.; Lamura, G.; Martinelli, A.; Pani, M.; Hecher, J.; Eisterer, M.; Putti, M.

2014-05-01

The study of overdoped FeTe1-xSex (0.5 < x < 1) polycrystalline superconductor samples is reported. The samples were prepared using a melting technique previously developed by our group. Increasing the Se content a phase separation related to the formation of FeSe inside the Fe(Se,Te) phase happens, as demonstrated by structural analysis and magnetic characterization. The proposed phase separation picture is likely the fingerprint of a miscibility gap in the Fe(Se,Te) system.

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir, Class I

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bou-Mikael, Sami

This report demonstrates the effectiveness of the CO2 miscible process in Fluvial Dominated Deltaic reservoirs. It also evaluated the use of horizontal CO2 injection wells to improve the overall sweep efficiency. A database of FDD reservoirs for the gulf coast region was developed by LSU, using a screening model developed by Texaco Research Center in Houston. The results of the information gained in this project is disseminated throughout the oil industry via a series of SPE papers and industry open forums.

Interrelationships between intranarial pressure and biosonar clicks in the bottlenose dolphin (Tursiops truncatus)

NASA Astrophysics Data System (ADS)

Elsberry, Wesley R.; Cranford, Ted W.; Ridgway, Sam H.; Carder, Donald A.; Vanbonn, William G.; Blackwood, Diane J.; Carr, Jennifer A.; Evans, William E.

2002-05-01

Three Atlantic bottlenose dolphins (Tursiops truncatus) were given a target recognition biosonar task. During their performance of the task, both acoustic data in the far field and pressure within the bony nasal passages were digitally recorded (Elsberry et al., 1999). Analysis of over 15000 biosonar clicks provided new insights into odontocete biosonar sound production and is consistent with acoustic and pressure data taken from white whales (Delphinapterus leucas) during biosonar (Ridgway and Carder, 1988). Our work provides the first evidence for a minimum intranarial pressure during biosonar click production for any odontocete (11.8+/-0.5 kPascals over basal pressure). All three subjects exhibited nearly the same minimum tranarial pressure difference during biosonar click production. Clicks produced at or near this minimum intranarial pressure exhibited a wide range of acoustic power values. The acoustic power of a biosonar click was not highly correlated with intranarial pressure (R2=0.116). The radiated acoustic energy in biosonar clicks ranged from 1 to 1370 microJoules. Estimates of mechanical work during pressurization events were produced using a piston/cylinder model and intranarial volume data from prepared specimens and computed tomography scans. Mechanical work during pressurization events ranged from 2.74 to 23.0 Joules, with an average of 10.3 Joules.

Relation between inflammables and ignition sources in aircraft environments

NASA Technical Reports Server (NTRS)

Scull, Wilfred E

1951-01-01

A literature survey was conducted to determine the relation between aircraft ignition sources and inflammables. Available literature applicable to the problem of aircraft fire hazards is analyzed and discussed. Data pertaining to the effect of many variables on ignition temperatures, minimum ignition pressures, minimum spark-ignition energies of inflammables, quenching distances of electrode configurations, and size of openings through which flame will not propagate are presented and discussed. Ignition temperatures and limits of inflammability of gasoline in air in different test environments, and the minimum ignition pressures and minimum size of opening for flame propagation in gasoline-air mixtures are included; inerting of gasoline-air mixtures is discussed.

Vocal warm-up increases phonation threshold pressure in soprano singers at high pitch.

PubMed

Motel, Tamara; Fisher, Kimberly V; Leydon, Ciara

2003-06-01

Vocal warm-up is thought to optimize singing performance. We compared effects of short-term, submaximal, vocal warm-up exercise with those of vocal rest on the soprano voice (n = 10, ages 19-21 years). Dependent variables were the minimum subglottic air pressure required for vocal fold oscillation to occur (phonation threshold pressure, Pth), and the maximum and minimum phonation fundamental frequency. Warm-up increased Pth for high pitch phonation (p = 0.033), but not for comfortable (p = 0.297) or low (p = 0.087) pitch phonation. No significant difference in the maximum phonation frequency (p = 0.193) or minimum frequency (p = 0.222) was observed. An elevated Pth at controlled high pitch, but an unchanging maximum and minimum frequency production suggests that short-term vocal exercise may increase the viscosity of the vocal fold and thus serve to stabilize the high voice.

49 CFR 178.58 - Specification 4DA welded steel cylinders for aircraft use.

Code of Federal Regulations, 2010 CFR

2010-10-01

... stress in pounds psi; P = test pressure prescribed for water jacket test, i.e., at least 2 times service... seamless hemispheres) or a circumferentially welded cylinder (two seamless drawn shells) with a water... the wall stress at the minimum specified test pressure may not exceed 67 percent of the minimum...

49 CFR 195.306 - Test medium.

Code of Federal Regulations, 2010 CFR

2010-10-01

... which produces a hoop stress of 50 percent of specified minimum yield strength; (3) The test section is... pressure is equal to or greater than a pressure that produces a hoop stress of 50 percent of specified minimum yield strength; (3) The maximum hoop stress during the test does not exceed 80 percent of...

49 CFR 195.306 - Test medium.

Code of Federal Regulations, 2012 CFR

2012-10-01

... which produces a hoop stress of 50 percent of specified minimum yield strength; (3) The test section is... pressure is equal to or greater than a pressure that produces a hoop stress of 50 percent of specified minimum yield strength; (3) The maximum hoop stress during the test does not exceed 80 percent of...

49 CFR 179.300-6 - Thickness of plates.

Code of Federal Regulations, 2010 CFR

2010-10-01

....037 Where: d = inside diameter in inches; E = 1.0 welded joint efficiency; P = minimum required bursting pressure in psig; S = minimum tensile strength of plate material in p.s.i. as prescribed in § 179... −d 2) where: d = inside diameter in inches; D = outside diameter in inches; p = tank test pressure in...

The effects of forced small-wavelength, finite-bandwidth initial perturbations and miscibility on the turbulent Rayleigh–Taylor instability

DOE PAGES

Roberts, M. S.; Jacobs, J. W.

2015-12-07

Rayleigh–Taylor instability experiments are performed using both immiscible and miscible incompressible liquid combinations having a relatively large Atwood number ofmore » $$A\\equiv ({\\it\\rho}_{2}-{\\it\\rho}_{1})/({\\it\\rho}_{2}+{\\it\\rho}_{1})=0.48$$. The liquid-filled tank is attached to a test sled that is accelerated downwards along a vertical rail system using a system of weights and pulleys producing approximately$1g$$net acceleration. The tank is backlit and images are digitally recorded using a high-speed video camera. The experiments are either initiated with forced initial perturbations or are left unforced. The forced experiments have an initial perturbation imposed by vertically oscillating the liquid-filled tank to produce Faraday waves at the interface. The unforced experiments rely on random interfacial fluctuations, resulting from background noise, to seed the instability. The main focus of this study is to determine the effects of forced initial perturbations and the effects of miscibility on the growth parameter,$${\\it\\alpha}$$. Measurements of the mixing-layer width,$$h$$, are acquired, from which$${\\it\\alpha}$$is determined. It is found that initial perturbations of the form used in this study do not affect measured$${\\it\\alpha}$$values. However, miscibility is observed to strongly affect$${\\it\\alpha}$$, resulting in a factor of two reduction in its value, a finding not previously observed in past experiments. In addition, all measured$${\\it\\alpha}$values are found to be smaller than those obtained in previous experimental studies.« less

Live cell plasma membranes do not exhibit a miscibility phase transition over a wide range of temperatures.

PubMed

Lee, Il-Hyung; Saha, Suvrajit; Polley, Anirban; Huang, Hector; Mayor, Satyajit; Rao, Madan; Groves, Jay T

2015-03-26

Lipid/cholesterol mixtures derived from cell membranes as well as their synthetic reconstitutions exhibit well-defined miscibility phase transitions and critical phenomena near physiological temperatures. This suggests that lipid/cholesterol-mediated phase separation plays a role in the organization of live cell membranes. However, macroscopic lipid-phase separation is not generally observed in cell membranes, and the degree to which properties of isolated lipid mixtures are preserved in the cell membrane remain unknown. A fundamental property of phase transitions is that the variation of tagged particle diffusion with temperature exhibits an abrupt change as the system passes through the transition, even when the two phases are distributed in a nanometer-scale emulsion. We support this using a variety of Monte Carlo and atomistic simulations on model lipid membrane systems. However, temperature-dependent fluorescence correlation spectroscopy of labeled lipids and membrane-anchored proteins in live cell membranes shows a consistently smooth increase in the diffusion coefficient as a function of temperature. We find no evidence of a discrete miscibility phase transition throughout a wide range of temperatures: 14-37 °C. This contrasts the behavior of giant plasma membrane vesicles (GPMVs) blebbed from the same cells, which do exhibit phase transitions and macroscopic phase separation. Fluorescence lifetime analysis of a DiI probe in both cases reveals a significant environmental difference between the live cell and the GPMV. Taken together, these data suggest the live cell membrane may avoid the miscibility phase transition inherent to its lipid constituents by actively regulating physical parameters, such as tension, in the membrane.

The Dynamics of Miscible Interfaces: Simulations

NASA Technical Reports Server (NTRS)

Meiburg, Eckart

2005-01-01

This research project focuses on the dynamics of interfacial regions between miscible fluids. While much attention has focused on immiscible interfaces in the past, miscible interfaces have been explored to a much lesser degree, so that there are many open questions regarding their dynamics at this time. Among the more pressing issues is the role that nonconventional stresses can play in such interfacial regions. Such stresses are typically not accounted for in efforts to model the dynamics of miscible flows. Our research aims to clarify under which circumstances these stresses do have to be taken into account, and what quantitative approaches are most suitable in this regard. In order to address these issues, we have focused on conducting linear stability analyses and nonlinear simulations for capillary tube and Hele-Shaw flows, and to compare the results with corresponding experiments performed in the labs of our co-investigators Prof. Maxworthy at USC, and Dr. Balasubramaniam at NASA. Over the duration of the project we have, among other things, focused on the effects of variable diffusion coefficients in such flows, and specifically on their influence in the growth of instabilities. Furthermore, our three-dimensional spectral element simulations have made good progress, so that we have come to a point where we can conduct more detailed comparisons with experimental observations. We are currently focusing our efforts on reproducing the tip-splitting instability observed by Maxworthy. Finally, we have discovered a new core-annular flow instability in the Stokes flow regime during the last year. This represents a significant finding, as this instability does not have an immiscible counterpart.

Assessing the Strength Enhancement of Heterogeneous Networks of Miscible Polymer Blends

NASA Astrophysics Data System (ADS)

Giller, Carl; Roland, Mike

2013-03-01

At the typical crosslink densities of elastomers, the failure properties vary inversely with mechanical stiffness, so that compounding entails a compromise between stiffness and strength. Our approach to circumvent this conventional limitation is by forming networks of two polymers that: (i) are thermodynamically miscible, whereby the chemical composition is uniform on the segmental level; and (ii) have markedly different reactivities for network formation. The resulting elastomer consists of one highly crosslinked component and one that is lightly or uncrosslinked. This disparity in crosslinking causes their respective contributions to the network mechanical response to differ diametrically. Earlier results showed some success with this approach for thermally crosslinked blends of 1,2-polybutadiene (PVE) and polyisoprene (PI), as well as ethylene-propylene copolymer (EPM) and ethylene-propylene-diene random terpolymer (EPDM), taking advantage of their differing reactivities to sulfur. In this work we demonstrate the miscibility of polyisobutylene (PIB) with butyl rubber (BR) (a copolymer of PIB and polyisoprene) and show that networks in which only the BR is crosslinked possess greater tensile strengths than neat BR over the same range of moduli. Office of Naval Research

A test-tube model for rainfall

NASA Astrophysics Data System (ADS)

Wilkinson, Michael

2014-05-01

If the temperature of a cell containing two partially miscible liquids is changed very slowly, so that the miscibility is decreased, microscopic droplets nucleate, grow and migrate to the interface due to their buoyancy. The system may show an approximately periodic variation of the turbidity of the mixture, as the mean droplet size fluctuates. These precipitation events are analogous to rainfall. This paper considers a theoretical model for these experiments. After nucleation the initial growth is by Ostwald ripening, followed by a finite-time runaway growth of droplet sizes due to larger droplets sweeping up smaller ones. The model predicts that the period \\Delta t and the temperature sweep rate ξ are related by \\Delta t\\sim C \\xi^{-3/7} , and is in good agreement with experiments. The coefficient C has a power-law divergence approaching the critical point of the miscibility transition: C\\sim (T-T_{\\text{c}})^{-\\eta} , and the critical exponent η is determined. It is argued that while the mechanism does not provide a quantitative description of terrestrial rainfall, it may be a faithful model for precipitation on other planets.

Viscometric investigation of compatibilization of the poly(vinyl chloride)/poly(ethylene-co-vinyl acetate) blends by terpolymer of maleic anhydride styrene vinyl acetate

NASA Astrophysics Data System (ADS)

İmren, Dilek; Boztuğ, Ali; Yılmaz, Ersen; Zengin, H. Bayram

2008-11-01

In this study, a blend of poly(vinyl chloride) (PVC)/ethylene-co-vinyl acetate (EVA) was compatibilized by terpolymer of maleic anhydride-styrene-vinyl acetate (MAStVA) used as a compatibilizer. It was prepared the blends of 50/50 PVC/EVA containing 2-10% of the terpolymer. The compatibility experiences of these blends were investigated by using viscometric method in the range of concentrations (0.5-2.0 g dL -1) where tetrahydrofuran (THF) is the solvent. The interaction parameter (Δ b) was used to study the miscibility and compatibility of polymer blend in solution, obtained from the modified Krigbaum and Wall theory. Turbidity and FTIR measurements were also used to investigate the miscibility of this pair of polymers. The values of the relative viscosities of the each polymer solution and their blends were measured by a Cannon-Fenske type viscometer. In consequence of the study, it was observed that a considerable improvement was achieved in the miscibility of PVC/EVA blends by adding among 5 and 10 wt% of compatibilizer.

Characterization of Physical and Mechanical Properties of Miscible Lactose-Sugars Systems.

PubMed

Li, Runjing; Roos, Yrjö H; Miao, Song

2017-09-01

Lactose-sugars systems were produced by spray drying. They were lactose, lactose-glucose (4:1) mixtures, lactose-maltose (4:1) mixtures, lactose-sucrose (4:1) mixtures, lactose-trehalose (4:1) mixtures, and lactose-corn syrup solids (CSS) (4:1) mixtures. The physical characteristics, water sorption behavior, glass transition, and mechanical properties of miscible lactose-sugars systems were investigated. Lactose-glucose mixtures had larger particle size than other lactose-sugars systems after spray drying. The presence of glucose or sucrose in lactose-sugars mixtures decreased the glass transition temperatures of amorphous systems, while the presence of maltose and trehalose had only minor impact on the glass transition temperatures. Moreover, glucose accelerated the crystallization of amorphous system at 0.44 a w , but its presence delayed the loss of sorbed water at higher water activities (≥0.54 a w ). Mechanical property study indicated that glucose and sucrose in amorphous system could result in an increase of molecular mobility, while the presence of CSS could decrease the free volume and maintain the stiffness of the miscible systems. © 2017 Institute of Food Technologists®.

49 CFR 178.58 - Specification 4DA welded steel cylinders for aircraft use.

Code of Federal Regulations, 2011 CFR

2011-10-01

... stress in pounds psi; P = test pressure prescribed for water jacket test, i.e., at least 2 times service... hemispheres) or a circumferentially welded cylinder (two seamless drawn shells) with a water capacity not over... the wall stress at the minimum specified test pressure may not exceed 67 percent of the minimum...

Relation Between Inflammables and Ignition Sources in Aircraft Environments

NASA Technical Reports Server (NTRS)

Scull, Wilfred E

1950-01-01

A literature survey was conducted to determine the relation between aircraft ignition sources and inflammables. Available literature applicable to the problem of aircraft fire hazards is analyzed and, discussed herein. Data pertaining to the effect of many variables on ignition temperatures, minimum ignition pressures, and minimum spark-ignition energies of inflammables, quenching distances of electrode configurations, and size of openings incapable of flame propagation are presented and discussed. The ignition temperatures and the limits of inflammability of gasoline in air in different test environments, and the minimum ignition pressure and the minimum size of openings for flame propagation of gasoline - air mixtures are included. Inerting of gasoline - air mixtures is discussed.

An advanced analytical solution for pressure build-up during CO2 injection into infinite saline aquifers: The role of compressibility

NASA Astrophysics Data System (ADS)

Wu, Haiqing; Bai, Bing; Li, Xiaochun

2018-02-01

Existing analytical or approximate solutions that are appropriate for describing the migration mechanics of CO2 and the evolution of fluid pressure in reservoirs do not consider the high compressibility of CO2, which reduces their calculation accuracy and application value. Therefore, this work first derives a new governing equation that represents the movement of complex fluids in reservoirs, based on the equation of continuity and the generalized Darcy's law. A more rigorous definition of the coefficient of compressibility of fluid is then presented, and a power function model (PFM) that characterizes the relationship between the physical properties of CO2 and the pressure is derived. Meanwhile, to avoid the difficulty of determining the saturation of fluids, a method that directly assumes the average relative permeability of each fluid phase in different fluid domains is proposed, based on the theory of gradual change. An advanced analytical solution is obtained that includes both the partial miscibility and the compressibility of CO2 and brine in evaluating the evolution of fluid pressure by integrating within different regions. Finally, two typical sample analyses are used to verify the reliability, improved nature and universality of this new analytical solution. Based on the physical characteristics and the results calculated for the examples, this work elaborates the concept and basis of partitioning for use in further work.

Approach to knowledge of the interaction between the constituents of contact lenses and ocular tears: mixed monolayers of poly(methyl methacrylate) and dipalmitoyl phosphatidyl choline.

PubMed

Miñones Conde, M; Conde, O; Trillo, J M; Miñones, J

2011-04-05

Mixed monolayers of poly(methyl methacrylate) (PMMA), the main component of hard contact lenses, and dipalmitoyl phosphatidyl choline (DPPC), a characteristic phospholipidic constituent of ocular tear films, were selected as an in vitro model in order to observe the behavior of contact lenses on the eye. Using Langmuir monolayer and Brewster angle microscopy (BAM) techniques, the interaction between both components was analyzed from the data of surface pressure-area isotherms, compressional modulus-surface pressure, and relative film thickness versus time elapsed from the beginning of compression, together with BAM images. Regardless of the surface pressure at which the molecular/monomer areas (A(m)) were recorded, the A(m) mole fractions of PMMA (X(PMMA)) plots show that the experimental results match the theoretical values calculated from additivity rule A(m) = X(PMMA)A(PMMA) + X(DPPC)A(DPPC). The application of the Crisp phase rule to the phase diagram of the PMMA-DPPC system can explain the existence of a mixed monolayer made up of miscible components with ideal behavior at surface pressures below 25 mN/m. However, at very high surface pressures, when collapse is reached (at 60 mN/m), the single collapsed components are segregated into two independent phases. These results allows us to argue that PMMA hard contact lenses in the eye do not alter the structural characteristics of the phospholipid (DPPC) in tears.

Surface Complexation Modeling of Calcite Zeta Potential Measurement in Mixed Brines for Carbonate Wettability Characterization

NASA Astrophysics Data System (ADS)

Song, J.; Zeng, Y.; Biswal, S. L.; Hirasaki, G. J.

2017-12-01

We presents zeta potential measurements and surface complexation modeling (SCM) of synthetic calcite in various conditions. The systematic zeta potential measurement and the proposed SCM provide insight into the role of four potential determining cations (Mg2+, SO42- , Ca2+ and CO32-) and CO2 partial pressure in calcite surface charge formation and facilitate the revealing of calcite wettability alteration induced by brines with designed ionic composition ("smart water"). Brines with varying potential determining ions (PDI) concentration in two different CO2 partial pressure (PCO2) are investigated in experiments. Then, a double layer SCM is developed to model the zeta potential measurements. Moreover, we propose a definition for contribution of charged surface species and quantitatively analyze the variation of charged species contribution when changing brine composition. After showing our model can accurately predict calcite zeta potential in brines containing mixed PDIs, we apply it to predict zeta potential in ultra-low and pressurized CO2 environments for potential applications in carbonate enhanced oil recovery including miscible CO2 flooding and CO2 sequestration in carbonate reservoirs. Model prediction reveals that pure calcite surface will be positively charged in all investigated brines in pressurized CO2 environment (>1atm). Moreover, the sensitivity of calcite zeta potential to CO2 partial pressure in the various brine is found to be in the sequence of Na2CO3 > Na2SO4 > NaCl > MgCl2 > CaCl2 (Ionic strength=0.1M).

Enhanced sampling simulation analysis of the structure of lignin in the THF–water miscibility gap

DOE PAGES

Smith, Micholas Dean; Petridis, Loukas; Cheng, Xiaolin; ...

2016-01-26

Using temperature replica-exchange molecular dynamics, we characterize a globule-to-coil transition for a softwood-like lignin biopolymer in a tetrahydrofuran (THF)-water cosolvent system at temperatures at which the cosolvent undergoes a de-mixing transition. The lignin is found to be in a coil state, similar to that in the high-temperature miscible region. Analysis of the transition kinetics indicates that THF acts in a surfactant-like fashion. In conclusion, the present study thus suggests that THF-water based pretreatments may efficiently remove lignin from biomass even at relatively low (non-water boiling) temperatures.

Initial Observations on the Burning of an Ethanol Droplet in Microgravity

NASA Technical Reports Server (NTRS)

Kazakov, Andrei; Urban, Bradley; Conley, Jordan; Dryer, Frederick L.; Ferkul, Paul (Technical Monitor)

1999-01-01

Combustion of liquid ethanol represents an important system both from fundamental and practical points of view, Ethanol is currently being used as an additive to gasoline in order to reduce carbon monoxide and particulate emissions as well as to improve the fuel octane rating. A detailed physical understanding of liquid ethanol combustion is therefore necessary to achieve an optimal performance of such fuel blends in practical conditions. Ethanol is also a relatively simple model compound suitable for investigation of important combustion characteristics typical of more complex fuels. In particular, ethanol has been proposed for studies of sooting behavior during droplet burning. The sooting nature of ethanol has pressure sensitivities similar to that of n-heptane, but shifted to a higher range of pressures (1-3 atm). Additionally, liquid ethanol is miscible with water produced during its combustion forming mixtures with azeotropic behavior, a phenomenon important for understanding multi-component, liquid fuel combustion. In this work, we present initial results obtained in a series of recent space-based experiments and develop a detailed model describing the burning of ethanol droplet in microgravity.

Synthesis and phase behavior of end-functionalized associating polymers

NASA Astrophysics Data System (ADS)

Wrue, Michelle H.

We have explored polymer blend phase behavior in the presence of multiple hydrogen bonding end-groups. This work details the synthesis of functionalized polymers and their subsequent use in miscibility studies. The synthesis of end-functionalized hydrogen bonding polymers and the investigation of their physical properties and miscibility is presented. Mono-functional and telechelic ureidopyrimidinone (UPy) functionalized polymers were prepared by two main routes: post-polymerization functionalization (of commercially available or synthesized polymers); and polymerization of monomers using a functionalized initiator. UPy-functionalized polymers were prepared with a variety of polymer backbones including poly(ethylene oxide)s; poly(butadiene)s, poly(dimethyl siloxanxe)s; poly(styrene)s and poly(methyl methacrylate)s. The most successful route to polymers with UPy end-groups was atom transfer radical polymerization (ATRP) using a UPy-functionalized initiator, followed by atom transfer radical coupling (ATRC). The incorporation of ureidopyrimidinone end-groups was shown to affect the physical properties of the polymer backbone. Parent polymers that were liquids became viscous liquids or waxy solids upon UPy-functionalization of chain end. UPy-functionalization of a hydroxyl-terminated polybutadiene (HO-PB-OH) resulted in a waxy solid while the HO-PB-OH precursor was a viscous liquid. The thermal properties of functionalized polymers also differed from those of the unfunctionalized parent polymers. Hot-stage optical microscopy revealed that UPy-functionalized PEO displayed a depressed melting point relative to the analogous unfunctionalized precursor. Differential scanning calorimetry was also used to investigate the synthesized UPy-polymers. UPy-functionalized polystyrenes and poly(methyl methacrylate)s showed an increased T g compared to the equivalent homopolymer standards. This increased Tg was determined to be dependent upon the fraction of UPy groups present and chemical cleavage of the end-groups resulted in Tgs near those observed for polymer standards of comparable molecular weight. Aggregation of UPy end-groups in solution was observed using gel permeation chromatography. Aggregation was only observed for telechelic samples of low molecular weight, indicating that the aggregation of end-groups is dependent upon the concentration of the end-groups. The effect of UPy end-groups on blend miscibility was studied in solution using laser light scattering and in the melt state was using laser light scattering, optical microscopy and differential scanning calorimetry. The incorporation of associating groups onto one end of either blend component decreases miscibility relative to unfunctionalized parent blends. Lower miscibility was also observed for blends in which both components were mono-functionalized with associating end-groups. The largest decrease in miscibility was observed for blends containing telechelic UPy-functionalized polymers, which were immiscible across the entire composition range.

Multi-bottle, no compressor, mean pressure control system for a Stirling engine

DOEpatents

Corey, John A.

1990-01-01

The invention relates to an apparatus for mean pressure control of a Stirling engine without the need for a compressor. The invention includes a multi-tank system in which there is at least one high pressure level tank and one low pressure level tank wherein gas flows through a maximum pressure and supply line from the engine to the high pressure tank when a first valve is opened until the maximum pressure of the engine drops below that of the high pressure tank opening an inlet regulator to permit gas flow from the engine to the low pressure tank. When gas flows toward the engine it flows through the minimum pressure supply line 2 when a second valve is opened from the low pressure tank until the tank reaches the engine's minimum pressure level at which time the outlet regulator opens permitting gas to be supplied from the high pressure tank to the engine. Check valves between the two tanks prevent any backflow of gas from occurring.

30 CFR 18.98 - Enclosures, joints, and fastenings; pressure testing.

Code of Federal Regulations, 2013 CFR

2013-07-01

... consistent with unyielding components during a pressure-time history as derived from a series of oscillograms...; pressure testing. (a) Cast or welded enclosures shall be designed to withstand a minimum internal pressure...

30 CFR 18.98 - Enclosures, joints, and fastenings; pressure testing.

Code of Federal Regulations, 2012 CFR

2012-07-01

... consistent with unyielding components during a pressure-time history as derived from a series of oscillograms...; pressure testing. (a) Cast or welded enclosures shall be designed to withstand a minimum internal pressure...

30 CFR 18.98 - Enclosures, joints, and fastenings; pressure testing.

Code of Federal Regulations, 2014 CFR

2014-07-01

... consistent with unyielding components during a pressure-time history as derived from a series of oscillograms...; pressure testing. (a) Cast or welded enclosures shall be designed to withstand a minimum internal pressure...

30 CFR 18.98 - Enclosures, joints, and fastenings; pressure testing.

Code of Federal Regulations, 2010 CFR

2010-07-01

... consistent with unyielding components during a pressure-time history as derived from a series of oscillograms...; pressure testing. (a) Cast or welded enclosures shall be designed to withstand a minimum internal pressure...

30 CFR 18.98 - Enclosures, joints, and fastenings; pressure testing.

Code of Federal Regulations, 2011 CFR

2011-07-01

... consistent with unyielding components during a pressure-time history as derived from a series of oscillograms...; pressure testing. (a) Cast or welded enclosures shall be designed to withstand a minimum internal pressure...

49 CFR 178.50 - Specification 4B welded or brazed steel cylinders.

Code of Federal Regulations, 2011 CFR

2011-10-01

...)] / (D2 − d2) Where: S = wall stress in psi; P = minimum test pressure prescribed for water jacket test or... seams that are forged lap-welded or brazed and with water capacity (nominal) not over 1,000 pounds and a... calculated wall stress at minimum test pressure (paragraph (i)(4) of this section) may not exceed the...

49 CFR 178.50 - Specification 4B welded or brazed steel cylinders.

Code of Federal Regulations, 2010 CFR

2010-10-01

...)] / (D2 − d2) Where: S = wall stress in psi; P = minimum test pressure prescribed for water jacket test or... longitudinal seams that are forged lap-welded or brazed and with water capacity (nominal) not over 1,000 pounds... calculated wall stress at minimum test pressure (paragraph (i)(4) of this section) may not exceed the...

Multiscale structure, interfacial cohesion, adsorbed layers, miscibility and properties in dense polymer-particle mixtures

NASA Astrophysics Data System (ADS)

Schweizer, Ken

2012-02-01

A major goal in polymer nanocomposite research is to understand and predict how the chemical and physical nature of individual polymers and nanoparticles, and thermodynamic state (temperature, composition, solvent dilution, filler loading), determine bulk assembly, miscibility and properties. Microscopic PRISM theory provides a route to this goal for equilibrium disordered mixtures. A major prediction is that by manipulating the net polymer-particle interfacial attraction, miscibility is realizable via the formation of thin thermodynamically stable adsorbed layers, which, however, are destroyed by entropic depletion and bridging attraction effects if interface cohesion is too weak or strong, respectively. This and related issues are quantitatively explored for miscible mixtures of hydrocarbon polymers, silica nanospheres, and solvent using x-ray scattering, neutron scattering and rheology. Under melt conditions, quantitative agreement between theory and silica scattering experiments is achieved under both steric stabilization and weak depletion conditions. Using contrast matching neutron scattering to characterize the collective structure factors of polymers, particles and their interface, the existence and size of adsorbed polymer layers, and their consequences on microstructure, is determined. Failure of the incompressible RPA, accuracy of PRISM theory, the nm thickness of adsorbed layers, and qualitative sensitivity of the bulk modulus to interfacial cohesion and particle size are demonstrated for concentrated PEO-silica-ethanol nanocomposites. Temperature-dependent complexity is discovered when water is the solvent, and nonequilibrium effects emerge for adsorbing entangled polymers that strongly impact structure. By varying polymer chemistry, the effect of polymer-particle attraction on the intrinsic viscosity is explored with striking non-classical effects observed. This work was performed in collaboration with S.Y.Kim, L.M.Hall, C.Zukoski and B.Anderson.

Methods and apparatus for moving and separating materials exhibiting different physical properties

DOEpatents

Peterson, Stephen C.; Brimhall, Owen D.; McLaughlin, Thomas J.; Baker, Charles D.; Sparks, Sam L.

1991-01-01

Methods and apparatus for controlling the movement of materials having different physical properties when one of the materials is a fluid. The invention does not rely on flocculation, sedimentation, centrifugation, the buoyancy of the materials, or any other gravity dependent characteristic, in order to achieve its desired results. The methods of the present invention provide that a first acoustic wave is propagated through a vessel containing the materials. A second acoustic wave, at a frequency different than the first acoustic wave, is also propagated through the vessel so that the two acoustic waves are superimposed upon each other. The superimposition of the two waves creates a beat frequency wave. The beat frequency wave comprises pressure gradients dividing regions of maximum and minimum pressure. The pressure gradients and the regions of maximum and minimum pressure move through space and time at a group velocity. The moving pressure gradients and regions of maximum and minimum pressure act upon the materials so as to move one of the materials towards a predetermined location in the vessel. The present invention provides that the materials may be controllably moved toward a location, aggregated at a particular location, or physically separated from each other.

Methods and apparatus for moving and separating materials exhibiting different physical properties

DOEpatents

Peterson, Stephen C.; Brimhall, Owen D.; McLaughlin, Thomas J.; Baker, Charles D.; Sparks, Sam L.

1988-01-01

Methods and apparatus for controlling the movement of materials having different physical properties when one of the materials is a fluid. The invention does not rely on flocculation, sedimentation, centrifugation, the buoyancy of the materials, or any other gravity dependent characteristic, in order to achieve its desired results. The methods of the present invention provide that a first acoustic wave is progpagated through a vessel containing the materials. A second acoustic wave, at a frequency different than the first acoustic wave, is also propagated through the vessel so that the two acoustic waves are superimposed upon each other. The superimposition of the two waves creates a beat frequency wave. The beat frequency wave comprises pressure gradients dividing regions of maximum and minimum pressure. The pressure gradients and the regions of maximum and minimum pressure move through space and time at a group velocity. The moving pressure gradients and regions of maximum and minimum pressure act upon the marterials so as to move one of the materials towards a predetermined location in the vessel. The present invention provides that the materials may be controllably moved toward a location, aggreated at a particular location, or physically separated from each other.

30 CFR 250.616 - Blowout prevention equipment.

Code of Federal Regulations, 2014 CFR

2014-07-01

... pressure rating of the BOP system and system components shall exceed the expected surface pressure to which they may be subjected. If the expected surface pressure exceeds the rated working pressure of the... pressure limitations that will be applied during each mode of pressure control. (b) The minimum BOP system...

30 CFR 250.616 - Blowout prevention equipment.

Code of Federal Regulations, 2013 CFR

2013-07-01

... pressure rating of the BOP system and system components shall exceed the expected surface pressure to which they may be subjected. If the expected surface pressure exceeds the rated working pressure of the... pressure limitations that will be applied during each mode of pressure control. (b) The minimum BOP system...

30 CFR 250.615 - Blowout prevention equipment.

Code of Federal Regulations, 2012 CFR

2012-07-01

... pressure rating of the BOP system and system components shall exceed the expected surface pressure to which they may be subjected. If the expected surface pressure exceeds the rated working pressure of the... pressure limitations that will be applied during each mode of pressure control. (b) The minimum BOP system...

Investigation of alternative layouts for the supercritical carbon dioxide Brayton cycle for a sodium-cooled fast reactor.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moisseytsev, A.; Sienicki, J. J.

2009-07-01

Analyses of supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle performance have largely settled on the recompression supercritical cycle (or Feher cycle) incorporating a flow split between the main compressor downstream of heat rejection, a recompressing compressor providing direct compression without heat rejection, and high and low temperature recuperators to raise the effectiveness of recuperation and the cycle efficiency. Alternative cycle layouts have been previously examined by Angelino (Politecnico, Milan), by MIT (Dostal, Hejzlar, and Driscoll), and possibly others but not for sodium-cooled fast reactors (SFRs) operating at relatively low core outlet temperature. Thus, the present authors could not be suremore » that the recompression cycle is an optimal arrangement for application to the SFR. To ensure that an advantageous alternative layout has not been overlooked, several alternative cycle layouts have been investigated for a S-CO{sub 2} Brayton cycle coupled to the Advanced Burner Test Reactor (ABTR) SFR preconceptual design having a 510 C core outlet temperature and a 470 C turbine inlet temperature to determine if they provide any benefit in cycle performance (e.g., enhanced cycle efficiency). No such benefits were identified, consistent with the previous examinations, such that attention was devoted to optimizing the recompression supercritical cycle. The effects of optimizing the cycle minimum temperature and pressure are investigated including minimum temperatures and/or pressures below the critical values. It is found that improvements in the cycle efficiency of 1% or greater relative to previous analyses which arbitrarily fixed the minimum temperature and pressure can be realized through an optimal choice of the combination of the minimum cycle temperature and pressure (e.g., for a fixed minimum temperature there is an optimal minimum pressure). However, this leads to a requirement for a larger cooler for heat rejection which may impact the tradeoff between efficiency and capital cost. In addition, for minimum temperatures below the critical temperature, a lower heat sink temperature is required the availability of which is dependent upon the climate at the specific plant site.« less

Control of surface adatom kinetics for the growth of high-indium content InGaN throughout the miscibility gap

NASA Astrophysics Data System (ADS)

Moseley, Michael; Lowder, Jonathan; Billingsley, Daniel; Doolittle, W. Alan

2010-11-01

The surface kinetics of InGaN alloys grown via metal-modulated epitaxy (MME) are explored in combination with transient reflection high-energy electron diffraction intensities. A method for monitoring and controlling indium segregation in situ is demonstrated. It is found that indium segregation is more accurately associated with the quantity of excess adsorbed metal, rather than the metal-rich growth regime in general. A modified form of MME is developed in which the excess metal dose is managed via shuttered growth, and high-quality InGaN films throughout the miscibility gap are grown.

A study examining the effects of water-miscible cutting fluids for end milling process of carbon fiber reinforced plastic

NASA Astrophysics Data System (ADS)

Anan, Ruito; Matsuoka, Hironori; Ono, Hajime; Ryu, Takahiro; Nakae, Takashi; Shuto, Schuichi; Watanabe, Suguru; Sato, Yuta

2017-04-01

This study examined the improvements to the tool life and finished surface roughness by using water-miscible cutting fluids in carbon fiber reinforced plastics end milling. In cutting tests, it was found that the use of emulsion type, soluble type, and solution type cutting fluids improved tool life compared with the case of dry cutting. Specifically, significant differences in tool life were observed at a high cutting speed of 171 m/min. In addition, the finished surface exhibited a low level of roughness when the solution type cutting fluid was used, regardless of the cutting speed.

Gradient and size effects on spinodal and miscibility gaps

NASA Astrophysics Data System (ADS)

Tsagrakis, Ioannis; Aifantis, Elias C.

2018-05-01

A thermodynamically consistent model of strain gradient elastodiffusion is developed. Its formulation is based on the enhancement of a robust theory of gradient elasticity, known as GRADELA, to account for a Cahn-Hilliard type of diffusion. Linear stability analysis is employed to determine the influence of concentration and strain gradients on the spinodal decomposition. For finite domains, spherically symmetric conditions are considered, and size effects on spinodal and miscibility gaps are discussed. The theoretical predictions are in agreement with the experimental trends, i.e., both gaps shrink as the grain diameter decreases and they are completely eliminated for crystals smaller than a critical size.

Instability patterns in a miscible core annular flow

NASA Astrophysics Data System (ADS)

D'Olce, Marguerite; Martin, Jerome; Rakotomalala, Nicole; Salin, Dominique; Talon, Laurent

2006-11-01

Laboratoire FAST, batiment 502, campus universitaire, 91405 Orsay Cedex (France). Experiments are performed with two miscible fluids of equal density but different viscosities. The fluids are injected co-currently and concentrically into a cylindrical pipe. The so-obtained base state is an axisymmetric parallel flow, for which the ratio of the flow rates of the two fluids monitors the relative amount (and so the radius) of the fluids. Depending on this relative amount and on the total flow rate of the fluids, unstable axisymmetric patterns such as mushrooms and pearls are observed. We delineate the diagram of occurrence of the two patterns and characterize the instabilities.

Improved Efficiency of Miscible CO(2) Floods and Enhanced Prospects for CO(2) Flooding Heterogeneous Reservoirs.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grigg, R.B.; Schechter, D.S.

The overall goal of this project was to improve the efficiency of miscible C0{sub 2} floods and enhance the prospects for flooding heterogeneous reservoirs. This objective was accomplished through experimental and modeling research in three task areas: (1) foams for selective mobility control in heterogeneous reservoirs,( 2) reduction of the amount of C0{sub 2} required in C0{sub 2} floods, and (3) low IFT processe and the possibility of C0{sub 2} flooding in fractured reservoirs. This report provides results from the three-year project for each of the three task areas.

Buoyancy driven mixing of miscible fluids by volumetric energy deposition of microwaves.

PubMed

Wachtor, Adam J; Mocko, Veronika; Williams, Darrick J; Goertz, Matthew P; Jebrail, Farzaneh F

2013-01-01

An experiment that seeks to investigate buoyancy driven mixing of miscible fluids by microwave volumetric energy deposition is presented. The experiment involves the use of a light, non-polar fluid that initially rests on top of a heavier fluid which is more polar. Microwaves preferentially heat the polar fluid, and its density decreases due to thermal expansion. As the microwave heating continues, the density of the lower fluid eventually becomes less than that of the upper, and buoyancy driven Rayleigh-Taylor mixing ensues. The choice of fluids is crucial to the success of the experiment, and a description is given of numerous fluid combinations considered and characterized. After careful consideration, the miscible pair of toluene/tetrahydrofuran (THF) was determined as having the best potential for successful volumetric energy deposition buoyancy driven mixing. Various single fluid calibration experiments were performed to facilitate the development of a heating theory. Thereafter, results from two-fluid mixing experiments are presented that demonstrate the capability of this novel Rayleigh-Taylor driven experiment. Particular interest is paid to the onset of buoyancy driven mixing and unusual aspects of the experiment in the context of typical Rayleigh-Taylor driven mixing.

Lifecycle of miscible viscous fingering: onset to shutdown

NASA Astrophysics Data System (ADS)

Nijjer, Japinder S.; Hewitt, Duncan R.; Neufeld, Jerome A.

2017-11-01

When a viscous fluid is injected into a porous medium or Hele-Shaw cell that is initially saturated with a more viscous fluid, the flow can be unstable to viscous fingering. We investigate the long-time dynamics of miscible viscous fingering in a homogeneous, planar, two-dimensional porous medium using high-resolution numerical simulations. At late times, we identify a new flow regime which consists of a pair of counter-propagating fingers that diffuse and slow, leaving a linearly well-mixed interior. We derive an analytic solution for this regime, and show that, in contrast to previous suggestions, the flow always evolves to this regime irrespective of the viscosity ratio and Peclet number. As a consequence, we find the instability can only ever generate a finite amount of advective mixing. We also describe the full life-cycle of miscible viscous fingering, which can be partitioned into three regimes: an early-time linearly unstable regime, an intermediate-time non-linear regime, and a late-time exchange-flow regime. We identify, using linear stability theory, a critical Peclet number below which the flow is always stable, and derive a model for the evolution of the transversely averaged concentration in the intermediate-time regime, which extends previous empirical models.

Competing Stereocomplexation and Homocrystallization of Poly(l-lactic acid)/Poly(d-lactic acid) Racemic Mixture: Effects of Miscible Blending with Other Polymers.

PubMed

Bao, Jianna; Xue, Xiaojia; Li, Kai; Chang, Xiaohua; Xie, Qing; Yu, Chengtao; Pan, Pengju

2017-07-20

Promoting the stereocomplexation ability of high-molecular-weight poly(l-lactic acid) (PLLA) and poly(d-lactic acid) (PDLA) is an efficient way to improve the thermal resistance of the resulting materials. Herein, we studied the competing crystallization kinetics, polymorphic crystalline structure, and lamellae structure of the PLLA/PDLA component in its miscible blends with poly(vinyl acetate) (PVAc) and proposed a method to improve the stereocomplexation ability of PLLA and PDLA through miscible blending with the other polymer. Crystallization of the PLLA/PDLA component is suppressed after the addition of PVAc, due to the dilution effect. The stereocomplexation ability of PLLA and PDLA is enhanced by blending with PVAc; this becomes more obvious at a high PVAc content (≥50 wt %) but less significant with the further increase of PLLA, PDLA molecular weights. Almost exclusive formation of SCs is achieved for PLLA and PDLA after blending with a large proportion of PVAc (e.g., 75 wt %). Incorporation of PVAc also facilitates the HC-to-SC structural reorganization upon heating. The increased chain mobility, decreased equilibrium melting point, and enhanced intermolecular interactions may account for the preferential stereocomplexation in PLLA/PDLA/PVAc blends.

Permanganate gel (PG) for groundwater remediation: compatibility, gelation, and release characteristics.

PubMed

Lee, Eung Seok; Olson, Pamela R; Gupta, Neha; Solpuker, Utku; Schwartz, Franklin W; Kim, Yongje

2014-02-01

Permanganate (MnO4(-)) is a strong oxidant that is widely used for treating chlorinated ethylenes in groundwater. This study aims to develop hyper-saline MnO4(-) solution (MnO4(-) gel; PG) that can be injected into aquifers via wells, slowly gelates over time, and slowly release MnO4(-) to flowing water. In this study, compatibility and miscibility of gels, such as chitosan, aluminosilicate, silicate, and colloidal silica gels, with MnO4(-) were tested. Of these gels, chitosan was reactive with MnO4(-). Aluminosilicates were compatible but not readily miscible with MnO4(-). Silicates and colloidal silica were both compatible and miscible with MnO4(-), and gelated with addition of KMnO4 granules. Colloidal silica has low initial viscosity (<15cP), exhibited delayed gelation characteristics with the lag times ranging from 0 to 200min. Release of MnO4(-) from the colloidal silica-based PG gel occurred in a delayed fashion, with maximum duration of 24h. These results suggested that colloidal silica can be used to create PG or delayed-gelling forms containing other oxidants which can be used for groundwater remediation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Extraction of orange peel's essential oil by solvent-free microwave extraction

NASA Astrophysics Data System (ADS)

Qadariyah, Lailatul; Amelia, Prilia Dwi; Admiralia, Cininta; Bhuana, Donny S.; Mahfud, Mahfud

2017-05-01

Sweet orange peel (Citrus sinensis) is part of orange plant that contains essential oils. Generally, taking essential oil from orange peel is still using hydrodistillation and steam-hydrodistillation method which still needs solvent and takes a long time to produce high quality essential oil. Therefore, the objectives of this experiment are to study the process of orange peel's essential oil extraction using Solvent Free Microwave Extraction (SFME) and to study the operating condition that effect an optimum yield and quality of the essential oil. In this experiment, extraction process with SFME method goes for 60 minutes at atmospheric pressure. Variables for SFME are: variation of orange peel condition (fresh and dry), ratio orange peel mass to distiller volume (0,1; 0,2; 0,3; 0,4 g/mL), orange peel size (±0,5; ±2; ±3,5 cm width), and microwave power (100, 264, 400 Watt). Moisture content of fresh peel is 71,4% and for dry peel is 17,37% which is obtained by sun drying. The result of this experiment will be analyzed with GC-MS, SEM, density, and miscibility in ethanol 90%. The optimum result obtained from this experiment based on the number of the yield under condition of fresh orange peel is at peel mass/distiller volume 0,1 g/mL, orange peel size ±3,5 cm width, and microwave power 400 Watt, results 1,6738% yield. The result of GC-MS for fresh orange peel shows that the dominant compound is Limonene 54,140% and for dry orange peel is Limonene 59,705%. The density obtained is around 0,8282-0,8530 g/mL and miscibility in ethanol 90% is 1:5.

Multi-component fluid flow through porous media by interacting lattice gas computer simulation

NASA Astrophysics Data System (ADS)

Cueva-Parra, Luis Alberto

In this work we study structural and transport properties such as power-law behavior of trajectory of each constituent and their center of mass, density profile, mass flux, permeability, velocity profile, phase separation, segregation, and mixing of miscible and immiscible multicomponent fluid flow through rigid and non-consolidated porous media. The considered parameters are the mass ratio of the components, temperature, external pressure, and porosity. Due to its solid theoretical foundation and computational simplicity, the selected approaches are the Interacting Lattice Gas with Monte Carlo Method (Metropolis Algorithm) and direct sampling, combined with particular collision rules. The percolation mechanism is used for modeling initial random porous media. The introduced collision rules allow to model non-consolidated porous media, because part of the kinetic energy of the fluid particles is transfered to barrier particles, which are the components of the porous medium. Having gained kinetic energy, the barrier particles can move. A number of interesting results are observed. Some findings include, (i) phase separation in immiscible fluid flow through a medium with no barrier particles (porosity p P = 1). (ii) For the flow of miscible fluids through rigid porous medium with porosity close to percolation threshold (p C), the flux density (measure of permeability) shows a power law increase ∝ (pC - p) mu with mu = 2.0, and the density profile is found to decay with height ∝ exp(-mA/Bh), consistent with the barometric height law. (iii) Sedimentation and driving of barrier particles in fluid flow through non-consolidated porous medium. This study involves developing computer simulation models with efficient serial and parallel codes, extensive data analysis via graphical utilities, and computer visualization techniques.

Intraocular pressure reduction and regulation system

NASA Technical Reports Server (NTRS)

Baehr, E. F.; Burnett, J. E.; Felder, S. F.; Mcgannon, W. J.

1979-01-01

An intraocular pressure reduction and regulation system is described and data are presented covering performance in: (1) reducing intraocular pressure to a preselected value, (2) maintaining a set minimum intraocular pressure, and (3) reducing the dynamic increases in intraocular pressure resulting from external loads applied to the eye.

Influence of nitromethane concentration on ignition energy and explosion parameters in gaseous nitromethane/air mixtures.

PubMed

Zhang, Qi; Li, Wei; Lin, Da-Chao; He, Ning; Duan, Yun

2011-01-30

The aim of this paper is to provide new experimental data of the minimum ignition energy (MIE) of gaseous nitromethane/air mixtures to discuss the explosion pressure and the flame temperature as a function of nitromethane concentration. Observations on the influence of nitromethane concentration on combustion pressure and temperature through the pressure and temperature measure system show that peak temperature (the peak of combustion temperature wave) is always behind peak pressure (the peak of the combustion pressure wave) in arrival time, the peak combustion pressure of nitromethane increases in the range of its volume fraction 10-40% as the concentration of nitromethane increases, and it slightly decreases in the range of 40-50%. The maximum peak pressure is equal to 0.94 MPa and the minimum peak pressure 0.58 MPa. Somewhat similar to the peak pressure, the peak combustion temperature increases with the volume fraction of nitromethane in the range of 10-40%, and slightly decreases in 40-50%. The maximum peak temperature is 1340 °C and the minimum 860 °C. The combustion temperature rise rate increases with the concentration of nitromethane in 10-30%, while decreases in 30-50% and its maximum value of combustion temperature rise rate in 10-50% is 4200 °C/s at the volume fraction of 30%. Influence of the concentration of nitromethane on the combustion pressure rise rate is relatively complicated, and the maximum value of rise rate of combustion pressure wave in 10-50% is 11 MPa/s at the concentration 20%. Copyright © 2010 Elsevier B.V. All rights reserved.

"Deflategate": Time, Temperature, and Moisture Effects on Football Pressure

NASA Astrophysics Data System (ADS)

Blumenthal, Jack; Beljak, Lauren; Macatangay, Dahlia-Marie; Helmuth-Malone, Lilly; McWilliams, Catharina; Raptis, Sofia

2016-09-01

In a recent paper in TPT, DiLisi and Rarick used the National Football League "Deflategate" controversy to introduce to physics students the physics of a bouncing ball. In this paper, we measure and analyze the environmental effects of time, ambient temperature, and moisture on the internal pressure of an NFL football. We focus on the rate of pressure recovery that occurs when a cold football (either wet or dry) is returned to the warm locker room environment where the pressure was initially measured. Both studies stem from the so-called NFL "Deflategate" controversy in which footballs that initially met a minimum internal pressure requirement were rechecked at halftime of the AFC Championship game, and in some cases were reported to have fallen below the minimum pressure requirement. The question is whether the pressure changes were due to environmental exposure or rather to some air being released from the balls, or both.

40 CFR Table 3 to Subpart Ec of... - Operating Parameters To Be Monitored and Minimum Measurement and Recording Frequencies

Code of Federal Regulations, 2011 CFR

2011-07-01

... scrubber followed by fabric filter Wet scrubber Dry scrubber followed by fabric filter and wet scrubber... flow rate Hourly 1×hour ✔ ✔ Minimum pressure drop across the wet scrubber or minimum horsepower or amperage to wet scrubber Continuous 1×minute ✔ ✔ Minimum scrubber liquor flow rate Continuous 1×minute...

Effects of tidal current phase at the junction of two straits

USGS Publications Warehouse

Warner, J.; Schoellhamer, D.; Burau, J.; Schladow, G.

2002-01-01

Estuaries typically have a monotonic increase in salinity from freshwater at the head of the estuary to ocean water at the mouth, creating a consistent direction for the longitudinal baroclinic pressure gradient. However, Mare Island Strait in San Francisco Bay has a local salinity minimum created by the phasing of the currents at the junction of Mare Island and Carquinez Straits. The salinity minimum creates converging baroclinic pressure gradients in Mare Island Strait. Equipment was deployed at four stations in the straits for 6 months from September 1997 to March 1998 to measure tidal variability of velocity, conductivity, temperature, depth, and suspended sediment concentration. Analysis of the measured time series shows that on a tidal time scale in Mare Island Strait, the landward and seaward baroclinic pressure gradients in the local salinity minimum interact with the barotropic gradient, creating regions of enhanced shear in the water column during the flood and reduced shear during the ebb. On a tidally averaged time scale, baroclinic pressure gradients converge on the tidally averaged salinity minimum and drive a converging near-bed and diverging surface current circulation pattern, forming a "baroclinic convergence zone" in Mare Island Strait. Historically large sedimentation rates in this area are attributed to the convergence zone. 

A Transmission Electron Microscope Study of Experimentally Shocked Pregraphitic Carbon

NASA Technical Reports Server (NTRS)

Rietmeijer, Frans J. M.

1995-01-01

A transmission electron microscope study of experimental shock metamorphism in natural pre-graphitic carbon simulates the response of the most common natural carbons to increased shock pressure. The d-spacings of this carbon are insensitive to the shock pressure and have no apparent diagnostic value, but progressive comminution occurs in response to increased shock pressure up to 59.6 GPa. The function, P = 869.1 x (size(sub minimum )(exp -0.83), describes the relationship between the minimum root-mean-square subgrain size (nm) and shock pressure (GPa). While a subgrain texture of natural pregraphitic carbons carries little information when pre-shock textures are unknown, this texture may go unnoticed as a shock metamorphic feature.

High-pressure high-temperature stability of hcp-Ir xOs 1-x (x = 0.50 and 0.55) alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yusenko, Kirill V.; Bykova, Elena; Bykov, Maxim

2016-12-23

Hcp-Ir 0.55Os 0.45 and hcp-Ir 0.50Os 0.50 alloys were synthesised by thermal decomposition of single-source precursors in hydrogen atmosphere. Both alloys correspond to a miscibility gap in the Ir–Os binary phase diagram and therefore are metastable at ambient conditions. An in situ powder X-ray diffraction has been used for a monitoring a formation of hcp-Ir0.55Os0.45 alloy from (NH 4) 2[Ir 0.55Os 0.45Cl 6] precursor. A crystalline intermediate compound and nanodimentional metallic particles with a large concentration of defects has been found as key intermediates in the thermal decomposition process in hydrogen flow. High-temperature stability of titled hcp-structured alloys has beenmore » investigated upon compression up to 11 GPa using a multi-anvil press and up to 80 GPa using laser-heated diamond-anvil cells to obtain a phase separation into fcc + hcp mixture. Compressibility curves at room temperature as well as thermal expansion at ambient pressure and under compression up to 80 GPa were collected to obtain thermal expansion coefficients and bulk moduli. hcp-Ir 0.55Os 0.45 alloy shows bulk moduli B0 = 395 GPa. Thermal expansion coefficients were estimated as α = 1.6·10 -5 K -1 at ambient pressure and α = 0.3·10 -5 K -1 at 80 GPa. Obtained high-pressure high-temperature data allowed us to construct the first model for pressure-dependent Ir–Os phase diagram.« less

46 CFR 154.408 - Cargo tank external pressure load.

Code of Federal Regulations, 2010 CFR

2010-10-01

... minimum internal pressure (maximum vacuum), and the maximum external pressure to which any portion of the... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo tank external pressure load. 154.408 Section 154... Equipment Cargo Containment Systems § 154.408 Cargo tank external pressure load. For the calculation...

Real-Time Optical Monitoring and Simulations of Gas Phase Kinetics in InN Vapor Phase Epitaxy at High Pressure

NASA Technical Reports Server (NTRS)

Dietz, Nikolaus; Woods, Vincent; McCall, Sonya D.; Bachmann, Klaus J.

2003-01-01

Understanding the kinetics of nucleation and coalescence of heteroepitaxial thin films is a crucial step in controlling a chemical vapor deposition process, since it defines the perfection of the heteroepitaxial film both in terms of extended defect formation and chemical integrity of the interface. The initial nucleation process also defines the film quality during the later stages of film growth. The growth of emerging new materials heterostructures such as InN or In-rich Ga(x)In(1-x)N require deposition methods operating at higher vapor densities due to the high thermal decomposition pressure in these materials. High nitrogen pressure has been demonstrated to suppress thermal decomposition of InN, but has not been applied yet in chemical vapor deposition or etching experiments. Because of the difficulty with maintaining stochiometry at elevated temperature, current knowledge regarding thermodynamic data for InN, e.g., its melting point, temperature-dependent heat capacity, heat and entropy of formation are known with far less accuracy than for InP, InAs and InSb. Also, no information exists regarding the partial pressures of nitrogen and phosphorus along the liquidus surfaces of mixed-anion alloys of InN, of which the InN(x)P(1-x) system is the most interesting option. A miscibility gap is expected for InN(x)P(1-x) pseudobinary solidus compositions, but its extent is not established at this point by experimental studies under near equilibrium conditions. The extension of chemical vapor deposition to elevated pressure is also necessary for retaining stoichiometric single phase surface composition for materials that are characterized by large thermal decomposition pressures at optimum processing temperatures.

On-Shore Central Hydraulic Power Generation for Wind and Tidal Energy

NASA Technical Reports Server (NTRS)

Jones, Jack A.; Bruce, Allan; Lim, Steven; Murray, Luke; Armstrong, Richard; Kimball, Richard; Cook-Chenault, Kimberly; DeGennaro, Sean

2012-01-01

Tidal energy, offshore wind energy, and onshore wind energy can be converted to electricity at a central ground location by means of converting their respective energies into high-pressure hydraulic flows that are transmitted to a system of generators by high-pressure pipelines. The high-pressure flows are then efficiently converted to electricity by a central power plant, and the low-pressure outlet flow is returned. The Department of Energy (DOE) is presently supporting a project led by Sunlight Photonics to demonstrate a 15 kilowatt tidal hydraulic power generation system in the laboratory and possibly later submerged in the ocean. All gears and submerged electronics are completely eliminated.A second portion of this DOE project involves sizing and costing a 15 megawatt tidal energy system for a commercial tidal energy plant. For this task, Atlantis Resources Corporation's 18-m diameter demonstrated tidal blades are rated to operate in a nominal 2.6 m/sec tidal flow to produce approximately one megawatt per set of tidal blades. Fifteen units would be submerged in a deep tidal area, such as in Maine's Western Passage. All would be connected to a high-pressure (20 megapascals, 2900 pounds per square inch) line that is 35 cm ID. The high-pressure HEPG fluid flow is transported 500-m to on-shore hydraulic generators. HEPG is an environmentally-friendly, biodegradable, water-miscible fluid. Hydraulic adaptations to ORPC's cross-flow turbines are also discussed.For 15 megawatt of wind energy that is onshore or offshore, a gearless, high efficiency, radial piston pump can replace each set of top-mounted gear-generators. The fluid is then pumped to a central, easily serviceable generator location. Total hydraulic/electrical efficiency is 0.81 at full rated wind or tidal velocities and increases to 0.86 at 1/3 rated velocities.

Automatic procedure for stable tetragonal or hexagonal structures: application to tetragonal Y and Cd

NASA Astrophysics Data System (ADS)

Marcus, P. M.; Jona, F.

2005-05-01

A simple effective procedure (MNP) for finding equilibrium tetragonal and hexagonal states under pressure is described and applied. The MNP procedure finds a path to minima of the Gibbs free energy G at T=0 K (G=E+pV, E=energy per atom, p=pressure, V=volume per atom) for tetragonal and hexagonal structures by using the approximate expansion of G in linear and quadratic strains at an arbitrary initial structure to find a change in the strains which moves toward a minimum of G. Iteration automatically proceeds to a minimum within preset convergence criteria on the calculation of the minimum. Comparison is made with experimental results for the ground states of seven metallic elements in hexagonal close-packed (hcp), face- and body-centered cubic structures, and with a previous procedure for finding minima based on tracing G along the epitaxial Bain path (EBP) to a minimum; the MNP is more easily generalized than the EBP procedure to lower symmetry and more atoms in the unit cell. Comparison is also made with a molecular-dynamics program for crystal equilibrium structures under pressure and with CRYSTAL, a program for crystal equilibrium structures at zero pressure. Application of MNP to the elements Y and Cd, which have hcp ground states at zero pressure, finds minima of E at face-centered cubic (fcc) structure for both Y and Cd. Evaluation of all the elastic constants shows that fcc Y is stable, hence a metastable phase, but fcc Cd is unstable.

49 CFR 179.220-6 - Thickness of plates.

Code of Federal Regulations, 2010 CFR

2010-10-01

... heads; P = Minimum required bursting pressure in psig; S = Minimum tensile strength of plate material in p.s.i. as prescribed in AAR Specifications for Tank Cars, appendix M, Table M1; t = Minimum... seamless heads; L = Main inside radius to which head is dished, measured on concave side in inches; P...

Impacts of coronary artery eccentricity on macro-recirculation and pressure drops using computational fluid dynamics

NASA Astrophysics Data System (ADS)

Poon, Eric; Thondapu, Vikas; Barlis, Peter; Ooi, Andrew

2017-11-01

Coronary artery disease remains a major cause of mortality in developed countries, and is most often due to a localized flow-limiting stenosis, or narrowing, of coronary arteries. Patients often undergo invasive procedures such as X-ray angiography and fractional flow reserve to diagnose flow-limiting lesions. Even though such diagnostic techniques are well-developed, the effects of diseased coronary segments on local flow are still poorly understood. Therefore, this study investigated the effect of irregular geometries of diseased coronary segments on the macro-recirculation and local pressure minimum regions. We employed an idealized coronary artery model with a diameter of stenosis of 75%. By systematically adjusting the eccentricity and the asymmetry of the coronary stenosis, we uncovered an increase in macro-recirculation size. Most importantly, the presence of this macro-recirculation signifies a local pressure minimum (identified by λ2 vortex identification method). This local pressure minimum has a profound effect on the pressure drops in both longitudinal and planar directions, which has implications for diagnosis and treatment of coronary artery disease. Supported by Australian Research Council LP150100233 and National Computational Infrastructure m45.

Composition-dependent damping and relaxation dynamics in miscible polymer blends above glass transition temperature by anelastic spectroscopy

NASA Astrophysics Data System (ADS)

Wu, Xuebang; Shang, Shuying; Xu, Qiaoling; Liu, Changsong; Zhu, Zhengang; Zhang, Guangzhao

2008-07-01

Anelastic spectroscopy is used to study the composition dependence of the damping and molecular relaxation dynamics in miscible poly(ethylene oxide) (PEO)/poly(methyl methacrylate) (PMMA) blends above the glass transition temperature. The ultrahigh damping peak of the relaxation type is shown to be associated with the liquid-liquid transition of PMMA. A higher PEO concentration leads to a higher damping performance and a lower transition temperature. The decreasing activation energy with increasing PEO concentration indicates a drastic increase in molecular mobility. Moreover, the relaxation time reveals a transition from the Vogel-Fulcher-Tamman behavior to the Arrhenius behavior due to the intermolecular guest-host interactions.

Solvent for urethane adhesives and coatings and method of use

DOEpatents

Simandl, Ronald F.; Brown, John D.; Holt, Jerrid S.

2010-08-03

A solvent for urethane adhesives and coatings, the solvent having a carbaldehyde and a cyclic amide as constituents. In some embodiments the solvent consists only of miscible constituents. In some embodiments the carbaldehyde is benzaldehyde and in some embodiments the cyclic amide is N-methylpyrrolidone (M-pyrole). An extender may be added to the solvent. In some embodiments the extender is miscible with the other ingredients, and in some embodiments the extender is non-aqueous. For example, the extender may include isopropanol, ethanol, tetrahydro furfuryl alcohol, benzyl alcohol, Gamma-butyrolactone or a caprolactone. In some embodiments a carbaldehyde and a cyclic amide are heated and used to separate a urethane bonded to a component.

Molecular Probe Fluorescence Monitoring of Polymerization

NASA Technical Reports Server (NTRS)

Bunton, Patrick

2002-01-01

This project investigated the feasibility of using fluorescence spectroscopy to determine viscosity of polymer/monomer in support of Transient Interfacial Phenomena in Miscible Polymer Systems (TIPMPS). This project will attempt to measure gradient induced flow at a miscible interface during and / or after in-flight polymerization of dodecyl acrylate (lauryl acrylate). Concentration and temperature gradients will be intentionally introduced during polymerization and the resultant fluid flow determined by Particle Imaging Velocimetry (PIV). This report describes an investigation of the feasibility of using fluorescence of a probe molecule to monitor viscosity and/or concentration during and after polymerization. The probe used was pyrene which has been shown to be sensitive to its local environment in methyl methacrylate.

Co-Optimization of CO 2-EOR and Storage Processes in Mature Oil Reservoirs

DOE PAGES

Ampomah, William; Balch, Robert S.; Grigg, Reid B.; ...

2016-08-02

This article presents an optimization methodology for CO 2 enhanced oil recovery in partially depleted reservoirs. A field-scale compositional reservoir flow model was developed for assessing the performance history of an active CO 2 flood and for optimizing both oil production and CO 2 storage in the Farnsworth Unit (FWU), Ochiltree County, Texas. A geological framework model constructed from geophysical, geological, and engineering data acquired from the FWU was the basis for all reservoir simulations and the optimization method. An equation of state was calibrated with laboratory fluid analyses and subsequently used to predict the thermodynamic minimum miscible pressure (MMP).more » Initial history calibrations of primary, secondary and tertiary recovery were conducted as the basis for the study. After a good match was achieved, an optimization approach consisting of a proxy or surrogate model was constructed with a polynomial response surface method (PRSM). The PRSM utilized an objective function that maximized both oil recovery and CO 2 storage. Experimental design was used to link uncertain parameters to the objective function. Control variables considered in this study included: water alternating gas cycle and ratio, production rates and bottom-hole pressure of injectors and producers. Other key parameters considered in the modeling process were CO 2 purchase, gas recycle and addition of infill wells and/or patterns. The PRSM proxy model was ‘trained’ or calibrated with a series of training simulations. This involved an iterative process until the surrogate model reached a specific validation criterion. A sensitivity analysis was first conducted to ascertain which of these control variables to retain in the surrogate model. A genetic algorithm with a mixed-integer capability optimization approach was employed to determine the optimum developmental strategy to maximize both oil recovery and CO 2 storage. The proxy model reduced the computational cost significantly. The validation criteria of the reduced order model ensured accuracy in the dynamic modeling results. The prediction outcome suggested robustness and reliability of the genetic algorithm for optimizing both oil recovery and CO 2 storage. The reservoir modeling approach used in this study illustrates an improved approach to optimizing oil production and CO 2 storage within partially depleted oil reservoirs such as FWU. Lastly, this study may serve as a benchmark for potential CO 2–EOR projects in the Anadarko basin and/or geologically similar basins throughout the world.« less

Co-optimization of CO 2 -EOR and Storage Processes under Geological Uncertainty

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ampomah, William; Balch, Robert; Will, Robert

This paper presents an integrated numerical framework to co-optimize EOR and CO 2 storage performance in the Farnsworth field unit (FWU), Ochiltree County, Texas. The framework includes a field-scale compositional reservoir flow model, an uncertainty quantification model and a neural network optimization process. The reservoir flow model has been constructed based on the field geophysical, geological, and engineering data. A laboratory fluid analysis was tuned to an equation of state and subsequently used to predict the thermodynamic minimum miscible pressure (MMP). A history match of primary and secondary recovery processes was conducted to estimate the reservoir and multiphase flow parametersmore » as the baseline case for analyzing the effect of recycling produced gas, infill drilling and water alternating gas (WAG) cycles on oil recovery and CO 2 storage. A multi-objective optimization model was defined for maximizing both oil recovery and CO 2 storage. The uncertainty quantification model comprising the Latin Hypercube sampling, Monte Carlo simulation, and sensitivity analysis, was used to study the effects of uncertain variables on the defined objective functions. Uncertain variables such as bottom hole injection pressure, WAG cycle, injection and production group rates, and gas-oil ratio among others were selected. The most significant variables were selected as control variables to be used for the optimization process. A neural network optimization algorithm was utilized to optimize the objective function both with and without geological uncertainty. The vertical permeability anisotropy (Kv/Kh) was selected as one of the uncertain parameters in the optimization process. The simulation results were compared to a scenario baseline case that predicted CO 2 storage of 74%. The results showed an improved approach for optimizing oil recovery and CO 2 storage in the FWU. The optimization process predicted more than 94% of CO 2 storage and most importantly about 28% of incremental oil recovery. The sensitivity analysis reduced the number of control variables to decrease computational time. A risk aversion factor was used to represent results at various confidence levels to assist management in the decision-making process. The defined objective functions were proved to be a robust approach to co-optimize oil recovery and CO 2 storage. The Farnsworth CO 2 project will serve as a benchmark for future CO 2–EOR or CCUS projects in the Anadarko basin or geologically similar basins throughout the world.« less

Co-optimization of CO 2 -EOR and Storage Processes under Geological Uncertainty

DOE PAGES

Ampomah, William; Balch, Robert; Will, Robert; ...

2017-07-01

This paper presents an integrated numerical framework to co-optimize EOR and CO 2 storage performance in the Farnsworth field unit (FWU), Ochiltree County, Texas. The framework includes a field-scale compositional reservoir flow model, an uncertainty quantification model and a neural network optimization process. The reservoir flow model has been constructed based on the field geophysical, geological, and engineering data. A laboratory fluid analysis was tuned to an equation of state and subsequently used to predict the thermodynamic minimum miscible pressure (MMP). A history match of primary and secondary recovery processes was conducted to estimate the reservoir and multiphase flow parametersmore » as the baseline case for analyzing the effect of recycling produced gas, infill drilling and water alternating gas (WAG) cycles on oil recovery and CO 2 storage. A multi-objective optimization model was defined for maximizing both oil recovery and CO 2 storage. The uncertainty quantification model comprising the Latin Hypercube sampling, Monte Carlo simulation, and sensitivity analysis, was used to study the effects of uncertain variables on the defined objective functions. Uncertain variables such as bottom hole injection pressure, WAG cycle, injection and production group rates, and gas-oil ratio among others were selected. The most significant variables were selected as control variables to be used for the optimization process. A neural network optimization algorithm was utilized to optimize the objective function both with and without geological uncertainty. The vertical permeability anisotropy (Kv/Kh) was selected as one of the uncertain parameters in the optimization process. The simulation results were compared to a scenario baseline case that predicted CO 2 storage of 74%. The results showed an improved approach for optimizing oil recovery and CO 2 storage in the FWU. The optimization process predicted more than 94% of CO 2 storage and most importantly about 28% of incremental oil recovery. The sensitivity analysis reduced the number of control variables to decrease computational time. A risk aversion factor was used to represent results at various confidence levels to assist management in the decision-making process. The defined objective functions were proved to be a robust approach to co-optimize oil recovery and CO 2 storage. The Farnsworth CO 2 project will serve as a benchmark for future CO 2–EOR or CCUS projects in the Anadarko basin or geologically similar basins throughout the world.« less

Co-Optimization of CO 2-EOR and Storage Processes in Mature Oil Reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ampomah, William; Balch, Robert S.; Grigg, Reid B.

This article presents an optimization methodology for CO 2 enhanced oil recovery in partially depleted reservoirs. A field-scale compositional reservoir flow model was developed for assessing the performance history of an active CO 2 flood and for optimizing both oil production and CO 2 storage in the Farnsworth Unit (FWU), Ochiltree County, Texas. A geological framework model constructed from geophysical, geological, and engineering data acquired from the FWU was the basis for all reservoir simulations and the optimization method. An equation of state was calibrated with laboratory fluid analyses and subsequently used to predict the thermodynamic minimum miscible pressure (MMP).more » Initial history calibrations of primary, secondary and tertiary recovery were conducted as the basis for the study. After a good match was achieved, an optimization approach consisting of a proxy or surrogate model was constructed with a polynomial response surface method (PRSM). The PRSM utilized an objective function that maximized both oil recovery and CO 2 storage. Experimental design was used to link uncertain parameters to the objective function. Control variables considered in this study included: water alternating gas cycle and ratio, production rates and bottom-hole pressure of injectors and producers. Other key parameters considered in the modeling process were CO 2 purchase, gas recycle and addition of infill wells and/or patterns. The PRSM proxy model was ‘trained’ or calibrated with a series of training simulations. This involved an iterative process until the surrogate model reached a specific validation criterion. A sensitivity analysis was first conducted to ascertain which of these control variables to retain in the surrogate model. A genetic algorithm with a mixed-integer capability optimization approach was employed to determine the optimum developmental strategy to maximize both oil recovery and CO 2 storage. The proxy model reduced the computational cost significantly. The validation criteria of the reduced order model ensured accuracy in the dynamic modeling results. The prediction outcome suggested robustness and reliability of the genetic algorithm for optimizing both oil recovery and CO 2 storage. The reservoir modeling approach used in this study illustrates an improved approach to optimizing oil production and CO 2 storage within partially depleted oil reservoirs such as FWU. Lastly, this study may serve as a benchmark for potential CO 2–EOR projects in the Anadarko basin and/or geologically similar basins throughout the world.« less

Pressure Testing of a Minimum Gauge PRSEUS Panel

NASA Technical Reports Server (NTRS)

Lovejoy, Andrew J.; Rouse, Marshall; Linton, Kim A.; Li, Victor P.

2011-01-01

Advanced aircraft configurations that have been developed to increase fuel efficiency require advanced, novel structural concepts capable of handling the unique load conditions that arise. One such concept is the Pultruded Rod Stitched Efficient Unitized Structure (PRSEUS) developed by the Boeing Company. The PRSEUS concept is being investigated by NASA s Environmentally Responsible Aviation (ERA) Program for use in a hybrid-wing body (HWB) aircraft. This paper summarizes the analysis and test of a PRSEUS panel subjected to internal pressure, the first such pressure test for this structural concept. The pressure panel used minimum gauge skin, with stringer and frame configurations consistent with previous PRSEUS tests. Analysis indicated that for the minimum gauge skin panel, the stringer locations exhibit fairly linear response, but the skin bays between the stringers exhibit nonlinear response. Excellent agreement was seen between nonlinear analysis and test results in the critical portion at the center of the panel. The pristine panel was capable of withstanding the required 18.4 psi pressure load condition without exhibiting any damage. The impacted panel was capable of withstanding a pressure load in excess of 28 psi before initial failure occurred at the center stringer, and the panel was capable of sustaining increased pressure load after the initial failure. This successful PRSEUS panel pressure panel test was a critical step in the building block approach for enabling the use of this advanced structural concept on future aircraft, such as the HWB.

A variable pressure method for characterizing nanoparticle surface charge using pore sensors.

PubMed

Vogel, Robert; Anderson, Will; Eldridge, James; Glossop, Ben; Willmott, Geoff

2012-04-03

A novel method using resistive pulse sensors for electrokinetic surface charge measurements of nanoparticles is presented. This method involves recording the particle blockade rate while the pressure applied across a pore sensor is varied. This applied pressure acts in a direction which opposes transport due to the combination of electro-osmosis, electrophoresis, and inherent pressure. The blockade rate reaches a minimum when the velocity of nanoparticles in the vicinity of the pore approaches zero, and the forces on typical nanoparticles are in equilibrium. The pressure applied at this minimum rate can be used to calculate the zeta potential of the nanoparticles. The efficacy of this variable pressure method was demonstrated for a range of carboxylated 200 nm polystyrene nanoparticles with different surface charge densities. Results were of the same order as phase analysis light scattering (PALS) measurements. Unlike PALS results, the sequence of increasing zeta potential for different particle types agreed with conductometric titration.

Nanocellular foam with solid flame retardant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Liang; Kelly-Rowley, Anne M.; Bunker, Shana P.

Prepare nanofoam by (a) providing an aqueous solution of a flame retardant dissolved in an aqueous solvent, wherein the flame retardant is a solid at 23.degree. C. and 101 kiloPascals pressure when in neat form; (b) providing a fluid polymer composition selected from a solution of polymer dissolved in a water-miscible solvent or a latex of polymer particles in a continuous aqueous phase; (c) mixing the aqueous solution of flame retardant with the fluid polymer composition to form a mixture; (d) removing water and, if present, solvent from the mixture to produce a polymeric composition having less than 74 weight-percentmore » flame retardant based on total polymeric composition weight; (e) compound the polymeric composition with a matrix polymer to form a matrix polymer composition; and (f) foam the matrix polymer composition into nanofoam having a porosity of at least 60 percent.« less

Supercritical waste oxidation of aqueous wastes

NASA Technical Reports Server (NTRS)

Modell, M.

1986-01-01

For aqueous wastes containing 1 to 20 wt% organics, supercritical water oxidation is less costly than controlled incineration or activated carbon treatment and far more efficient than wet oxidation. Above the critical temperature (374 C) and pressure (218 atm) of water, organic materials and gases are completely miscible with water. In supercritical water oxidation, organics, air and water are brought together in a mixture at 250 atm and temperatures above 400 C. Organic oxidation is initiated spontaneously at these conditions. The heat of combustion is released within the fluid and results in a rise in temperature 600 to 650 C. Under these conditions, organics are destroyed rapidly with efficiencies in excess of 99.999%. Heteroatoms are oxidized to acids, which can be precipitated out as salts by adding a base to the feed. Examples are given for process configurations to treat aqueous wastes with 10 and 2 wt% organics.

A low-cost gradient system for high-performance liquid chromatography. Quantitation of complex pharmaceutical raw materials.

PubMed

Erni, F; Frei, R W

1976-09-29

A device is described that makes use of an eight-port motor valve to generate step gradients on the low-pressure side of a piston pump with a low dead volume. Such a gradient device with an automatic control unit, which also permits repetition of previous steps, can be built for about half the cost of a gradient system with two pumps. Applications of this gradient unit to the separation of complex mixtures of glycosides and alkaloids are discussed and compared with separations systems using two high-pressure pumps. The gradients that are used on reversed-phase material with solvent mixtures of water and completely miscible organic solvents are suitable for quantitative routine control of pharmaceutical products. The reproducibility of retention data is excellent over several months and, with the use of loop injectors, major components can be determined quantitatively with a reproducibility of better than 2% (relative standard deviation). The step gradient selector valve can also be used as an introduction system for very large sample volumes. Up to 11 can be injected and samples with concentrations of less than 1 ppb can be determined with good reproducibilities.

Solvent/Non-Solvent Sintering To Make Microsphere Scaffolds

NASA Technical Reports Server (NTRS)

Laurencin, Cato T.; Brown, Justin L.; Nair, Lakshmi

2011-01-01

A solvent/non-solvent sintering technique has been devised for joining polymeric microspheres to make porous matrices for use as drug-delivery devices or scaffolds that could be seeded with cells for growing tissues. Unlike traditional sintering at elevated temperature and pressure, this technique is practiced at room temperature and pressure and, therefore, does not cause thermal degradation of any drug, protein, or other biochemical with which the microspheres might be loaded to impart properties desired in a specific application. Also, properties of scaffolds made by this technique are more reproducible than are properties of comparable scaffolds made by traditional sintering. The technique involves the use of two miscible organic liquids: one that is and one that is not a solvent for the affected polymer. The polymeric microspheres are placed in a mold having the size and shape of the desired scaffold, then the solvent/non-solvent mixture is poured into the mold to fill the void volume between the microspheres, then the liquid mixture is allowed to evaporate. Some of the properties of the resulting scaffold can be tailored through choice of the proportions of the liquids and the diameter of the microspheres.

Entanglement Length in Miscible Blends of cis-Polyisoprene and Poly(ptert-butylstyrene)

NASA Astrophysics Data System (ADS)

Watanabe, Hiroshi; Matsumiya, Yumi

In miscible polymer blends, the entanglement length is common for the components, but its changes with the composition w remain unclear. For this problem, this study analyzed viscoelastic data for miscible blends of cis-polyisoprene (PI) and poly(ptert-butylstyrene) (PtBS), considering the basic feature that the local relaxation is determined only by wPI. On the basis of this feature, a series of unentangled low- M PI/PtBS blends having various M and a given wPI were utilized as references for well-entangled high- M PI/PtBS blends having the same wPI, and the modulus data of the references were subtracted from the high- M blend data. For an optimally chosen reference, the storage modulus Ge'of the high- M blends obtained after the subtraction exhibited a clear entanglement plateau GN and the corresponding Ge' ' decreased in proportion to 1/ ω at high frequencies ω. Thus, the onset of entanglement relaxation was detected. The GN values were well described by a linear mixing rule of the entanglement length with the number fraction of Kuhn segments of the components being utilized as the averaging weight. This result, not explained by a mean-field picture of entanglement, is discussed in relation to local packing of bulky PtBS chains and skinny PI chains.

Ionic liquid compatibility in polyethylene oxide/siloxane ion gel membranes

DOE PAGES

Kusuma, Victor A.; Macala, Megan K.; Liu, Jian; ...

2018-10-02

Ion gel films were prepared by incorporating eight commercially available ionic liquids in two different cross-linked polymer matrices to evaluate their phase miscibility, gas permeability and ionic conductivity for potential applications as gas separation membranes and solid electrolyte materials. The ionic liquids cations were 1-ethyl-3-methylimidazolium, 1-ethyl-3-methylpyridinium, 1-butyl-1-methylpyrrolidinium, tributylmethylphosphonium, and butyltrimethylammonium with a common anion (bis(trifluoromethylsulfonyl)imide). In addition, ionic liquids with 1-ethyl-3-methylimidazolium cation with acetate, dicyanamide and tetrafluoroborate counterions were evaluated. The two polymers were cross-linked poly(ethylene oxide) and cross-linked poly(ethylene oxide)/siloxane copolymer. Differential scanning calorimetry, X-ray diffractometry and visual observations were performed to evaluate the ion gels’ miscibility, thermal stabilitymore » and homogeneity. Ionic liquids with the least basic anion (bis(trifluoromethylsulfonyl)imide) and aromatic cations containing acidic proton (e.g. imidazolium and pyridinium) gave the most stable and miscible ion gels. Phase stability was shown to be a function of both ionic liquid content and temperature, with phase separation observed at elevated temperatures. In conclusion, gas permeability testing with carbon dioxide and nitrogen and ionic conductivity measurements confirmed that these ionic liquids increased the gas permeability and ionic conductivity of the polymers.« less

Ionic liquid compatibility in polyethylene oxide/siloxane ion gel membranes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kusuma, Victor A.; Macala, Megan K.; Liu, Jian

Ion gel films were prepared by incorporating eight commercially available ionic liquids in two different cross-linked polymer matrices to evaluate their phase miscibility, gas permeability and ionic conductivity for potential applications as gas separation membranes and solid electrolyte materials. The ionic liquids cations were 1-ethyl-3-methylimidazolium, 1-ethyl-3-methylpyridinium, 1-butyl-1-methylpyrrolidinium, tributylmethylphosphonium, and butyltrimethylammonium with a common anion (bis(trifluoromethylsulfonyl)imide). In addition, ionic liquids with 1-ethyl-3-methylimidazolium cation with acetate, dicyanamide and tetrafluoroborate counterions were evaluated. The two polymers were cross-linked poly(ethylene oxide) and cross-linked poly(ethylene oxide)/siloxane copolymer. Differential scanning calorimetry, X-ray diffractometry and visual observations were performed to evaluate the ion gels’ miscibility, thermal stabilitymore » and homogeneity. Ionic liquids with the least basic anion (bis(trifluoromethylsulfonyl)imide) and aromatic cations containing acidic proton (e.g. imidazolium and pyridinium) gave the most stable and miscible ion gels. Phase stability was shown to be a function of both ionic liquid content and temperature, with phase separation observed at elevated temperatures. In conclusion, gas permeability testing with carbon dioxide and nitrogen and ionic conductivity measurements confirmed that these ionic liquids increased the gas permeability and ionic conductivity of the polymers.« less

Amorphous stabilization and dissolution enhancement of amorphous ternary solid dispersions: combination of polymers showing drug-polymer interaction for synergistic effects.

PubMed

Prasad, Dev; Chauhan, Harsh; Atef, Eman

2014-11-01

The purpose of this study was to understand the combined effect of two polymers showing drug-polymer interactions on amorphous stabilization and dissolution enhancement of indomethacin (IND) in amorphous ternary solid dispersions. The mechanism responsible for the enhanced stability and dissolution of IND in amorphous ternary systems was studied by exploring the miscibility and intermolecular interactions between IND and polymers through thermal and spectroscopic analysis. Eudragit E100 and PVP K90 at low concentrations (2.5%-40%, w/w) were used to prepare amorphous binary and ternary solid dispersions by solvent evaporation. Stability results showed that amorphous ternary solid dispersions have better stability compared with amorphous binary solid dispersions. The dissolution of IND from the ternary dispersion was substantially higher than the binary dispersions as well as amorphous drug. Melting point depression of physical mixtures reveals that the drug was miscible in both the polymers; however, greater miscibility was observed in ternary physical mixtures. The IR analysis confirmed intermolecular interactions between IND and individual polymers. These interactions were found to be intact in ternary systems. These results suggest that the combination of two polymers showing drug-polymer interaction offers synergistic enhancement in amorphous stability and dissolution in ternary solid dispersions. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

The Dynamics of Miscible Fluids: A Space Flight Experiment (MIDAS)

NASA Technical Reports Server (NTRS)

Maxworthy, T.; Meiburg, E.; Balasubramaniam, R.; Rashidnia, N.; Lauver, R.

2001-01-01

We propose a space flight experiment to study the dynamics of miscible interfaces. A less viscous fluid displaces one of higher viscosity within a tube. The two fluids are miscible in all proportions. An intruding "finger" forms that occupies a fraction of the tube. As time progresses diffusion at the interface combined with flow induced straining between the two fluids modifies the concentration and velocity distributions within the whole tube. Also, under such circumstances it has been proposed that the interfacial stresses could depend on the local concentration gradients (Korteweg stresses) and that the divergence of the velocity need not be zero, even though the flow is incompressible. We have obtained reasonable agreement for the tip velocity between numerical simulations (that ignored the Korteweg stress and divergence effects) and physical experiments only at high Peelet Numbers. However at moderate to low Pe agreement was poor. As one possibility we attributed this lack of agreement to the disregard of these effects. We propose a space experiment to measure the finger shape, tip velocity, and the velocity and concentration fields. From intercomparisons between the experiment and the calculations we can then extract values for the coefficients of the Korteweg stress terms and confirm or deny the importance of these stresses.

The Dynamics of Miscible Fluids: A Space Flight Experiment (MIDAS)

NASA Technical Reports Server (NTRS)

Maxworthy, T.; Meiburg, E.; Balasubramaniam, R.; Rashidnia, N.; Lauver, R.

2001-01-01

We propose a space flight experiment to study the dynamics of miscible interfaces. A less viscous fluid displaces one of higher viscosity within a tube. The two fluids are miscible in all proportions. An intruding "finger" forms that occupies a fraction of the tube. As time progresses diffusion at the interface combined with flow induced straining between the two fluids modifies the concentration and velocity distributions within the whole tube. Also, under such circumstances it has been proposed that the interfacial stresses could depend on the local concentration gradients (Korteweg stresses) and that the divergence of the velocity need not be zero, even though the flow is incompressible. We have obtained reasonable agreement for the tip velocity between numerical simulations (that ignored the Korteweg stress and divergence effects) and physical experiments only at high Peclet Numbers. However at moderate to low Pe agreement was poor. As one possibility we attributed this lack of agreement to the disregard of these effects. We propose a space experiment to measure the finger shape, tip velocity, and the velocity and concentration fields. From intercomparisons between the experiment and the calculations we can then extract values for the coefficients of the Korteweg stress terms and confirm or deny the importance of these stresses.

A Molecular-Level View of the Physical Stability of Amorphous Solid Dispersions

NASA Astrophysics Data System (ADS)

Yuan, Xiaoda

Many pharmaceutical compounds being developed in recent years are poorly soluble in water. This has led to insufficient oral bioavailability of many compounds in vitro. The amorphous formulation is one of the promising techniques to increase the oral bioavailability of these poorly water-soluble compounds. However, an amorphous drug substance is inherently unstable because it is a high energy form. In order to increase the physical stability, the amorphous drug is often formulated with a suitable polymer to form an amorphous solid dispersion. Previous research has suggested that the formation of an intimately mixed drug-polymer mixture contributes to the stabilization of the amorphous drug compound. The goal of this research is to better understand the role of miscibility, molecular interactions and mobility on the physical stability of amorphous solid dispersions. Methods were developed to detect different degrees of miscibility on nanometer scale and to quantify the extent of hydrogen-bonding interactions between the drug and the polymer. Miscibility, hydrogen-bonding interactions and molecular mobility were correlated with physical stability during a six-month period using three model systems. Overall, this research provides molecular-level insights into many factors that govern the physical stability of amorphous solid dispersions which can lead to a more effective design of stable amorphous formulations.

Miscibility of choline-substituted polyphosphazenes with PLGA and osteoblast activity on resulting blends.

PubMed

Weikel, Arlin L; Owens, Steven G; Morozowich, Nicole L; Deng, Meng; Nair, Lakshmi S; Laurencin, Cato T; Allcock, Harry R

2010-11-01

The preparation of phosphazene tissue engineering scaffolds with bioactive side groups has been accomplished using the biological buffer, choline chloride. Mixed-substituent phosphazene cyclic trimers (as model systems) and polymers with choline chloride and glycine ethyl ester, alanine ethyl ester, valine ethyl ester, or phenylalanine ethyl ester were synthesized. Two different synthetic protocols were examined. A sodium hydride mediated route resulted in polyphosphazenes with a low choline content, while a cesium carbonate mediated process produced polyphosphazenes with higher choline content. The phosphazene structures and physical properties were studied using multinuclear NMR, differential scanning calorimetry (DSC), and gel permeation chromatography (GPC) techniques. The resultant polymers were then blended with PLGA (50:50) or PLGA (85:15) and characterized by DSC analysis and scanning electron microscopy (SEM). Polymer products obtained via the sodium hydride route produced miscible blends with both ratios of PLGA, while the cesium carbonate route yielded products with reduced blend miscibility. Heterophase hydrolysis experiments in aqueous media revealed that the polymer blends hydrolyzed to near-neutral pH media (∼5.8 to 6.8). The effect of different molecular structures on cellular adhesion showed osteoblast proliferation with an elevated osteoblast phenotype expression compared to PLGA over a 21-day culture period. Copyright © 2010 Elsevier Ltd. All rights reserved.

Ternary Solar Cells Based on Two Small Molecule Donors with Same Conjugated Backbone: The Role of Good Miscibility and Hole Relay Process.

PubMed

Xiao, Liangang; Liang, Tianxiang; Gao, Ke; Lai, Tianqi; Chen, Xuebin; Liu, Feng; Russell, Thomas P; Huang, Fei; Peng, Xiaobin; Cao, Yong

2017-09-06

Ternary organic solar cells (OSCs) are very attractive for further enhancing the power conversion efficiencies (PCEs) of binary ones but still with a single active layer. However, improving the PCEs is still challenging because a ternary cell with one more component is more complicated on phase separation behavior. If the two donors or two acceptors have similar chemical structures, good miscibility can be expected to reduce the try-and-error work. Herein, we report ternary devices based on two small molecule donors with the same backbone but different substituents. Whereas both binary devices show PCEs about 9%, the PCE of the ternary cells is enhanced to 10.17% with improved fill factor and short-circuit current values and external quantum efficiencies almost in the whole absorption wavelength region from 440 to 850 nm. The same backbone enables the donors miscible at molecular level, and the donor with a higher HOMO level plays hole relay process to facilitate the charge transportation in the ternary devices. Since side-chain engineering has been well performed to tune the active materials' energy levels in OSCs, our results suggest that their ternary systems are promising for further improving the binary cells' performance although their absorptions are not complementary.

Three-dimensional Rayleigh-Taylor convection of miscible fluids in a porous medium

NASA Astrophysics Data System (ADS)

Suekane, Tetsuya; Nakanishi, Yuji; Wang, Lei

2017-11-01

Natural convection of miscible fluids in a porous medium is relevant for fields, such as geoscience and geoengineering, and for the geological storage of CO2. In this study, we use X-ray computer tomography to visualize 3D fingering structures associated with the Rayleigh-Taylor instability between miscible fluids in a porous medium. In the early stages of the onset of the Rayleigh-Taylor instability, a fine crinkling pattern gradually appears at the interface. As the wavelength and amplitude increase, descending fingers form on the interface and extend vertically downward; moreover, ascending and highly symmetric fingers form. The adjacent fingers are cylindrical in shape and coalesce to form large fingers. Fingers appearing on the interface tend to become finer with increasing Rayleigh number, which is consistent with linear perturbation theory. If the Péclet number exceeds 10, the transverse dispersion increases the finger diameter and enhances finger coalescence, strongly impacting the decay in finger number density. When mechanical dispersion is negligible, the finger-extension velocity, the mass-transfer rate, and the onset time scale with Rayleigh number. Mechanical dispersion not only reduces the onset time but also enhances mass transport, which indicates that mechanical dispersion influences the long-term dissolution process of CO2 injected into aquifers.

Behavior of CO2/water flow in porous media for CO2 geological storage.

PubMed

Jiang, Lanlan; Yu, Minghao; Liu, Yu; Yang, Mingjun; Zhang, Yi; Xue, Ziqiu; Suekane, Tetsuya; Song, Yongchen

2017-04-01

A clear understanding of two-phase fluid flow properties in porous media is of importance to CO 2 geological storage. The study visually measured the immiscible and miscible displacement of water by CO 2 using MRI (magnetic resonance imaging), and investigated the factor influencing the displacement process in porous media which were filled with quartz glass beads. For immiscible displacement at slow flow rates, the MR signal intensity of images increased because of CO 2 dissolution; before the dissolution phenomenon became inconspicuous at flow rate of 0.8mLmin -1 . For miscible displacement, the MR signal intensity decreased gradually independent of flow rates, because supercritical CO 2 and water became miscible in the beginning of CO 2 injection. CO 2 channeling or fingering phenomena were more obviously observed with lower permeable porous media. Capillary force decreases with increasing particle size, which would increase permeability and allow CO 2 and water to invade into small pore spaces more easily. The study also showed CO 2 flow patterns were dominated by dimensionless capillary number, changing from capillary finger to stable flow. The relative permeability curve was calculated using Brooks-Corey model, while the results showed the relative permeability of CO 2 slightly decreases with the increase of capillary number. Copyright © 2016 Elsevier Inc. All rights reserved.

49 CFR 195.300 - Scope.

Code of Federal Regulations, 2012 CFR

2012-10-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF HAZARDOUS LIQUIDS BY PIPELINE Pressure Testing § 195.300 Scope. This subpart prescribes minimum requirements for the pressure...

49 CFR 195.300 - Scope.

Code of Federal Regulations, 2013 CFR

2013-10-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF HAZARDOUS LIQUIDS BY PIPELINE Pressure Testing § 195.300 Scope. This subpart prescribes minimum requirements for the pressure...

49 CFR 195.300 - Scope.

Code of Federal Regulations, 2011 CFR

2011-10-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF HAZARDOUS LIQUIDS BY PIPELINE Pressure Testing § 195.300 Scope. This subpart prescribes minimum requirements for the pressure...

49 CFR 195.300 - Scope.

Code of Federal Regulations, 2010 CFR

2010-10-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF HAZARDOUS LIQUIDS BY PIPELINE Pressure Testing § 195.300 Scope. This subpart prescribes minimum requirements for the pressure...

49 CFR 195.300 - Scope.

Code of Federal Regulations, 2014 CFR

2014-10-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) PIPELINE SAFETY TRANSPORTATION OF HAZARDOUS LIQUIDS BY PIPELINE Pressure Testing § 195.300 Scope. This subpart prescribes minimum requirements for the pressure...

49 CFR 178.45 - Specification 3T seamless steel cylinder.

Code of Federal Regulations, 2011 CFR

2011-10-01

..., and service pressure. A DOT 3T cylinder is a seamless steel cylinder with a minimum water capacity of...) Wall thickness. The minimum wall thickness must be such that the wall stress at the minimum specified... the physical tests required in paragraphs (j) and (k) of this section. A wall stress of more than 90...

Oxygen miscibility gap and spin glass formation in the pyrochlore Lu{sub 2}Mo{sub 2}O{sub 7}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clark, L.; Ritter, C.; Harrison, A.

2013-07-15

Rare earth (R) molybdate pyrochlores, R{sub 2}Mo{sub 2}O{sub 7}, are of interest as frustrated magnets. Polycrystalline samples of Lu{sub 2}Mo{sub 2}O{sub 7−x} prepared at 1600 °C display a coexistence of cubic pyrochlore phases. Rietveld fits to powder neutron diffraction data and chemical analyses show that the miscibility gap is between a stoichiometric x=0 and an oxygen-deficient x≈0.4 phase. Lu{sub 2}Mo{sub 2}O{sub 7} behaves as a spin glass material, with a divergence of field cooled and zero field cooled DC magnetic susceptibilities at a spin freezing temperature T{sub f}=16 K, that varies with frequency in AC measurements following a Vogel–Fulcher law.more » Lu{sub 2}Mo{sub 2}O{sub 6.6} is more highly frustrated spin glass and has T{sub f}=20 K. - Graphical abstract: The cubic Lu{sub 2}Mo{sub 2}O{sub 7−x} system exhibits a miscibility gap between coexisting pyrochlore phases at 1600 °C. Neutron powder diffraction refinement and chemical analysis shows that the gap separates stoichiometric x=0 and oxygen-deficient x≈0.4 phases. Lu{sub 2}Mo{sub 2}O{sub 7−x} has a frustrated spin glass ground state that is sensitive to the oxygen content. - Highlights: • The cubic Lu{sub 2}Mo{sub 2}O{sub 7−x} system has a miscibility gap between coexisting pyrochlore phases at 1600 °C. • Neutron powder diffraction shows that the gap separates x=0 and oxygen-deficient x≈0.4 phases. • Lu{sub 2}Mo{sub 2}O{sub 7−x} has a frustrated spin glass ground state that is sensitive to the oxygen content.« less

Novel Shapes of Miscible Interfaces Observed

NASA Technical Reports Server (NTRS)

Balasubramaniam, Ramaswamy; Rashidnia, Nasser

2001-01-01

The dynamics of miscible displacements in a cylindrical tube are being investigated experimentally and numerically, with a view to understand the complex processes that occur, for example, in enhanced oil recovery, hydrology, and filtration. We have observed complex shapes of the interface between two liquids that mix with each other when the less viscous liquid is displaced by the more viscous one in a tube. A less viscous fluid that displaces a more viscous fluid is known to propagate in the form of a "finger," and a flight experiment proposed by Maxworthy et al. to investigate the miscible-interface dynamics is currently being developed by NASA. From the current theory of miscible displacements, which was developed for a porous medium satisfying Darcy's law, it can be shown that in the absence of gravity the interface between the fluids is destabilized and thus susceptible to fingering only when a more viscous fluid is displaced by a less viscous one. Therefore, if the interface is initially flat and the more viscous fluid displaces the less viscous fluid, the interface ought to be stable and remain flat. However, numerical simulations by Chen and Meiburg for such displacement in a cylindrical tube show that the interface is unstable and a finger of the more viscous fluid is indeed formed. Preliminary experiments performed at the NASA Glenn Research Center show that not only can fingering occur when the more viscous fluid displaces a less viscous one in a cylindrical tube, but also that under certain conditions the advancing finger achieves a sinuous or snakelike shape. These experiments were performed using silicone oils in a vertical pipette of small diameter. In the initial configuration, the more viscous fluid rested on top of the less viscous one, and the interface was nominally flat. A dye was added to the upper liquid for ease of observation of the interface between the fluids. The flow was initiated by draining the lower fluid from the bottom of the pipette, at speeds less than 0.1 mm/sec.

Buoyancy-driven instabilities around miscible A+B→C reaction fronts: a general classification.

PubMed

Trevelyan, P M J; Almarcha, C; De Wit, A

2015-02-01

Upon contact between miscible solutions of reactants A and B along a horizontal interface in the gravity field, various buoyancy-driven instabilities can develop when an A+B→C reaction takes place and the density varies with the concentrations of the various chemicals. To classify the possible convective instability scenarios, we analyze the spatial dependence of the large time asymptotic density profiles as a function of the key parameters of the problem, which are the ratios of diffusion coefficients and of solutal expansion coefficients of species A, B, and C. We find that 62 different density profiles can develop in the reactive problem, whereas only 6 of them can be obtained in the nonreactive one.

Osmosis-driven viscous fingering of oil-in-water emulsions

NASA Astrophysics Data System (ADS)

Liu, Ying; Rallabandi, Bhargav; Baskaran, Mrudhula; Stone, Howard

2017-11-01

Viscous fingering occurs when a low viscosity fluid invades a more viscous fluid. Fingering of two miscible fluids is more complicated than that of immiscible fluids in that there is no sharp fluid-fluid interface and diffusion occurs between the phases. We experimentally studied the fingering of two miscible fluids: an oil-in-water emulsion and a sodium chloride solution. When the concentration of sodium chloride in the water phase in the emulsion exceeds that in the sodium chloride solution, the consequent osmotic flow automatically facilitates the occurrence of the fingering. On the contrary, when the sodium chloride solution has higher concentration, the spreading of emulsion is more uniform than the case without the concentration difference. We provide a model to rationalize and quantify these observations.

The association of remotely-sensed outdoor temperature with blood pressure levels in REGARDS: a cross-sectional study of a large, national cohort of African-American and white participants

PubMed Central

2011-01-01

Background Evidence is mounting regarding the clinically significant effect of temperature on blood pressure. Methods In this cross-sectional study the authors obtained minimum and maximum temperatures and their respective previous week variances at the geographic locations of the self-reported residences of 26,018 participants from a national cohort of blacks and whites, aged 45+. Linear regression of data from 20,623 participants was used in final multivariable models to determine if these temperature measures were associated with levels of systolic or diastolic blood pressure, and whether these relations were modified by stroke-risk region, race, education, income, sex hypertensive medication status, or age. Results After adjustment for confounders, same-day maximum temperatures 20°F lower had significant associations with 1.4 mmHg (95% CI: 1.0, 1.9) higher systolic and 0.5 mmHg (95% CI: 0.3, 0.8) higher diastolic blood pressures. Same-day minimum temperatures 20°F lower had a significant association with 0.7 mmHg (95% CI: 0.3, 1.0) higher systolic blood pressures but no significant association with diastolic blood pressure differences. Maximum and minimum previous-week temperature variabilities showed significant but weak relationships with blood pressures. Parameter estimates showed effect modification of negligible magnitude. Conclusions This study found significant associations between outdoor temperature and blood pressure levels, which remained after adjustment for various confounders including season. This relationship showed negligible effect modification. PMID:21247466

49 CFR 192.627 - Tapping pipelines under pressure.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Tapping pipelines under pressure. 192.627 Section... NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Operations § 192.627 Tapping pipelines under pressure. Each tap made on a pipeline under pressure must be performed by a crew qualified to make...

The pressure recovery ratio: The invasive index of LV relaxation during filling. Model-based prediction with in-vivo validation.

PubMed

Zhang, Wei; Shmuylovich, Leonid; Kovacs, Sandor J

2009-01-01

Using a simple harmonic oscillator model (PDF formalism), every early filling E-wave can be uniquely described by a set of parameters, (x(0), c, and k). Parameter c in the PDF formalism is a damping or relaxation parameter that measures the energy loss during the filling process. Based on Bernoulli's equation and kinematic modeling, we derived a causal correlation between the relaxation parameter c in the PDF formalism and a feature of the pressure contour during filling - the pressure recovery ratio defined by the left ventricular pressure difference between diastasis and minimum pressure, normalized to the pressure difference between a fiducial pressure and minimum pressure [PRR = (P(Diastasis)-P(Min))/(P(Fiducial)-P(Min))]. We analyzed multiple heart beats from one human subject to validate the correlation. Further validation among more patients is warranted. PRR is the invasive causal analogue of the noninvasive E-wave relaxation parameter c. PRR has the potential to be calculated using automated methodology in the catheterization lab in real time.

On pressure measurement and seasonal pressure variations during the Phoenix mission

NASA Astrophysics Data System (ADS)

Taylor, Peter A.; Kahanpää, Henrik; Weng, Wensong; Akingunola, Ayodeji; Cook, Clive; Daly, Mike; Dickinson, Cameron; Harri, Ari-Matti; Hill, Darren; Hipkin, Victoria; Polkko, Jouni; Whiteway, Jim

2010-03-01

In situ surface pressures measured at 2 s intervals during the 150 sol Phoenix mission are presented and seasonal variations discussed. The lightweight Barocap®/Thermocap® pressure sensor system performed moderately well. However, the original data processing routine had problems because the thermal environment of the sensor was subject to more rapid variations than had been expected. Hence, the data processing routine was updated after Phoenix landed. Further evaluation and the development of a correction are needed since the temperature dependences of the Barocap sensor heads have drifted after the calibration of the sensor. The inaccuracy caused by this appears when the temperature of the unit rises above 0°C. This frequently affects data in the afternoons and precludes a full study of diurnal pressure variations at this time. Short-term fluctuations, on time scales of order 20 s are unaffected and are reported in a separate paper in this issue. Seasonal variations are not significantly affected by this problem and show general agreement with previous measurements from Mars. During the 151 sol mission the surface pressure dropped from around 860 Pa to a minimum (daily average) of 724 Pa on sol 140 (Ls 143). This local minimum occurred several sols earlier than expected based on GCM studies and Viking data. Since battery power was lost on sol 151 we are not sure if the timing of the minimum that we saw could have been advanced by a low-pressure meteorological event. On sol 95 (Ls 122), we also saw a relatively low-pressure feature. This was accompanied by a large number of vertical vortex events, characterized by short, localized (in time), low-pressure perturbations.

49 CFR 173.337 - Nitric oxide.

Code of Federal Regulations, 2010 CFR

2010-10-01

... charged to a pressure of not more than 5,170 kPa (750 psi) at 21 °C (70 °F). Transportation of nitric... with a minimum test pressure of 200 bar. The maximum working pressure of the cylinder must not exceed 50 bar. The pressure in the cylinder at 65 °C (149 °F) may not exceed the test pressure. The use of...

49 CFR 173.337 - Nitric oxide.

Code of Federal Regulations, 2014 CFR

2014-10-01

... charged to a pressure of not more than 5,170 kPa (750 psi) at 21 °C (70 °F). Transportation of nitric... with a minimum test pressure of 200 bar. The maximum working pressure of the cylinder must not exceed 50 bar. The pressure in the cylinder at 65 °C (149 °F) may not exceed the test pressure. The use of...

49 CFR 173.337 - Nitric oxide.

Code of Federal Regulations, 2011 CFR

2011-10-01

... charged to a pressure of not more than 5,170 kPa (750 psi) at 21 °C (70 °F). Transportation of nitric... with a minimum test pressure of 200 bar. The maximum working pressure of the cylinder must not exceed 50 bar. The pressure in the cylinder at 65 °C (149 °F) may not exceed the test pressure. The use of...

49 CFR 173.337 - Nitric oxide.

Code of Federal Regulations, 2012 CFR

2012-10-01

... charged to a pressure of not more than 5,170 kPa (750 psi) at 21 °C (70 °F). Transportation of nitric... with a minimum test pressure of 200 bar. The maximum working pressure of the cylinder must not exceed 50 bar. The pressure in the cylinder at 65 °C (149 °F) may not exceed the test pressure. The use of...

49 CFR 173.337 - Nitric oxide.

Code of Federal Regulations, 2013 CFR

2013-10-01

... charged to a pressure of not more than 5,170 kPa (750 psi) at 21 °C (70 °F). Transportation of nitric... with a minimum test pressure of 200 bar. The maximum working pressure of the cylinder must not exceed 50 bar. The pressure in the cylinder at 65 °C (149 °F) may not exceed the test pressure. The use of...

Fuel control for gas turbine with continuous pilot flame

DOEpatents

Swick, Robert M.

1983-01-01

An improved fuel control for a gas turbine engine having a continuous pilot flame and a fuel distribution system including a pump drawing fuel from a source and supplying a line to the main fuel nozzle of the engine, the improvement being a control loop between the pump outlet and the pump inlet to bypass fuel, an electronically controlled throttle valve to restrict flow in the control loop when main nozzle demand exists and to permit substantially unrestricted flow without main nozzle demand, a minimum flow valve in the control loop downstream of the throttle valve to maintain a minimum pressure in the loop ahead of the flow valve, a branch tube from the pilot flame nozzle to the control loop between the throttle valve and the minimum flow valve, an orifice in the branch tube, and a feedback tube from the branch tube downstream of the orifice to the minimum flow valve, the minimum flow valve being operative to maintain a substantially constant pressure differential across the orifice to maintain constant fuel flow to the pilot flame nozzle.

49 CFR 192.359 - Customer meter installations: Operating pressure.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Customer meter installations: Operating pressure... SAFETY TRANSPORTATION OF NATURAL AND OTHER GAS BY PIPELINE: MINIMUM FEDERAL SAFETY STANDARDS Customer Meters, Service Regulators, and Service Lines § 192.359 Customer meter installations: Operating pressure...

Retrieving air humidity, global solar radiation, and reference evapotranspiration from daily temperatures: development and validation of new methods for Mexico. Part I: humidity

NASA Astrophysics Data System (ADS)

Lobit, P.; López Pérez, L.; Lhomme, J. P.; Gómez Tagle, A.

2017-07-01

This study evaluates the dew point method (Allen et al. 1998) to estimate atmospheric vapor pressure from minimum temperature, and proposes an improved model to estimate it from maximum and minimum temperature. Both methods were evaluated on 786 weather stations in Mexico. The dew point method induced positive bias in dry areas but also negative bias in coastal areas, and its average root mean square error for all evaluated stations was 0.38 kPa. The improved model assumed a bi-linear relation between estimated vapor pressure deficit (difference between saturated vapor pressure at minimum and average temperature) and measured vapor pressure deficit. The parameters of these relations were estimated from historical annual median values of relative humidity. This model removed bias and allowed for a root mean square error of 0.31 kPa. When no historical measurements of relative humidity were available, empirical relations were proposed to estimate it from latitude and altitude, with only a slight degradation on the model accuracy (RMSE = 0.33 kPa, bias = -0.07 kPa). The applicability of the method to other environments is discussed.

A study to evaluate STS heads-up ascent trajectory performance employing a minimum-Hamiltonian optimization strategy

NASA Technical Reports Server (NTRS)

Sinha, Sujit

1988-01-01

A study was conducted to evaluate the performance implications of a heads-up ascent flight design for the Space Transportation System, as compared to the current heads-down flight mode. The procedure involved the use of the Minimum Hamiltonian Ascent Shuttle Trajectory Evaluation Program, which is a three-degree-of-freedom moment balance simulation of shuttle ascent. A minimum-Hamiltonian optimization strategy was employed to maximize injection weight as a function of maximum dynamic pressure constraint and Solid Rocket Motor burnrate. Performance Reference Mission Four trajectory groundrules were used for consistency. The major conclusions are that for heads-up ascent and a mission nominal design maximum dynamic pressure value of 680 psf, the optimum solid motor burnrate is 0.394 ips, which produces a performance enhancement of 4293 lbm relative to the baseline heads-down ascent, with 0.368 ips burnrate solid motors and a 680 psf dynamic pressure constraint. However, no performance advantage exists for heads-up flight if the current Solid Rocket Motor target burnrate of 0.368 ips is used. The advantage of heads-up ascent flight employing the current burnrate is that Space Shuttle Main Engine throttling for dynamic pressure control is not necessary.

Prediction of Phase Behavior of Spray-Dried Amorphous Solid Dispersions: Assessment of Thermodynamic Models, Standard Screening Methods and a Novel Atomization Screening Device with Regard to Prediction Accuracy

PubMed Central

Chavez, Pierre-François; Meeus, Joke; Robin, Florent; Schubert, Martin Alexander; Somville, Pascal

2018-01-01

The evaluation of drug–polymer miscibility in the early phase of drug development is essential to ensure successful amorphous solid dispersion (ASD) manufacturing. This work investigates the comparison of thermodynamic models, conventional experimental screening methods (solvent casting, quench cooling), and a novel atomization screening device based on their ability to predict drug–polymer miscibility, solid state properties (Tg value and width), and adequate polymer selection during the development of spray-dried amorphous solid dispersions (SDASDs). Binary ASDs of four drugs and seven polymers were produced at 20:80, 40:60, 60:40, and 80:20 (w/w). Samples were systematically analyzed using modulated differential scanning calorimetry (mDSC) and X-ray powder diffraction (XRPD). Principal component analysis (PCA) was used to qualitatively assess the predictability of screening methods with regards to SDASD development. Poor correlation was found between theoretical models and experimentally-obtained results. Additionally, the limited ability of usual screening methods to predict the miscibility of SDASDs did not guarantee the appropriate selection of lead excipient for the manufacturing of robust SDASDs. Contrary to standard approaches, our novel screening device allowed the selection of optimal polymer and drug loading and established insight into the final properties and performance of SDASDs at an early stage, therefore enabling the optimization of the scaled-up late-stage development. PMID:29518936

Miscibility and interaction between 1-alkanol and short-chain phosphocholine in the adsorbed film and micelles.

PubMed

Takajo, Yuichi; Matsuki, Hitoshi; Kaneshina, Shoji; Aratono, Makoto; Yamanaka, Michio

2007-09-01

The miscibility and interaction of 1-hexanol (C6OH) and 1-heptanol (C7OH) with 1,2-dihexanoyl-sn-glycero-3-phosphocholine (DHPC) in the adsorbed films and micelles were investigated by measuring the surface tension of aqueous C6OH-DHPC and aqueous C7OH-DHPC solutions. The surface density, the mean molecular area, the composition of the adsorbed film, and the excess Gibbs energy of adsorption g(H,E), were estimated. Further, the critical micelle concentration of the mixtures was determined from the surface tension versus molality curves; the micellar composition was calculated. The miscibility of the 1-alkanols and DHPC molecules in the adsorbed film and micelles was examined using the phase diagram of adsorption (PDA) and that of micellization (PDM). The PDA and the composition dependence of g(H,E) indicated the non-ideal mixing of the 1-alkanols and DHPC molecules due to the attractive interaction between the molecules in the adsorbed film, while the PDM indicated that the 1-alkanol molecules were not incorporated in the micelles within DHPC rich region. The dependence of the mean molecular area of the mixtures on the surface composition suggested that the packing property of the adsorbed film depends on the chain length of 1-alkanol: C6OH expands the DHPC adsorbed film more than C7OH.

Richtmyer-Meshkov instability experiments of miscible and immiscible incompressible fluids

NASA Astrophysics Data System (ADS)

Krivets, Vitaliy; Holt, Brason; Mokler, Matthew; Jacobs, Jeffrey

2017-11-01

Experiments were conducted in a 3 m tall vertical drop tower setup. A flat interface separating two liquids of differing density is formed in the Plexiglas tank with the heavier fluid in the bottom and the lighter one on top. Two liquids pairs were utilized, one - miscible (isopropyl alcohol and a calcium nitrate water mixture) and the other immiscible (silicone oil with the same heavy liquid), both with Atwood near 0.2. The tank is mounted on a rail mounted sled at 2 m initial height where an initial perturbation is generated using vertical periodic motion with 10 Hz frequency and 1 mm displacement, thus producing 3D interfacial waves. An impulsive acceleration, with approximately 100g magnitude, is imparted to the sled by a rail mounted weight released and allowed to fall, impacting the sled from above. Both weight and sled then travel freely down the rails where they are smoothly decelerated at the bottom of drop tower by magnetic brakes. PLIF is used to visualize mixing process by seeding fluorescein in the bottom fluid and illuminating using laser diode from above forming thin vertical sheet. The resulting fluorescent image sequences are captured using a digital camera mounted to the sled operating at a 100 Hz framing rate. Comparisons of the measured growth of the mixing zone for both immiscible and miscible liquid combinations with theoretical models are presented.

Molecular Dynamics Simulation of Amorphous Hydroxypropylmethylcellulose and Its Mixtures With Felodipine and Water.

PubMed

Xiang, Tian-Xiang; Anderson, Bradley D

2017-03-01

Understanding drug-polymer molecular interactions, their miscibility, supersaturation potential, and the effects of water uptake may be invaluable for selecting amorphous polymer dispersions that can maximize the oral bioavailability of poorly water-soluble drugs. Molecular dynamics simulations were performed using a model for hydroxypropylmethylcellulose (HPMC) resembling the substitution patterns found experimentally. HPMC at low and high water contents (0.9%-23.0% wt/wt) and mixtures with a hydrophobic drug, felodipine (FEL), were constructed. T g values and densities after ∼30 ns aging at 298 K were close to published results. Except for hydrogen bonds (HBs) between the 5-O- and a 3-OH group in a neighboring repeat unit, HPMC oxygen atoms have a low HB probability (p < 0.1) perhaps due to shielding by surrounding substituents. Water molecules tend to be isolated at low water content while clusters were prevalent at ≥10.7% water. The Flory-Huggins FEL-HPMC interaction parameter (-0.20 ± 0.07) predicts complete miscibility at all HPMC compositions, in agreement with experiments. However, HBs between the FEL-N-H and HPMC favoring miscibility are disrupted with increasing water. Apparent diffusion coefficients versus water content were generated for water and FEL and a theory for the non-Einsteinian nature of water diffusion is proposed. Copyright © 2017 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

An experimental study of non-isothermal miscible displacements in a Hele-Shaw cell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagatsu, Yuichiro; Fujita, Norihito; Kato, Yoshihito

Non-isothermal miscible displacements in a radial Hele-Shaw cell were experimentally investigated using a scheme in which room temperature liquids of relatively high viscosity were displaced by high-temperature (80 C), less-viscous liquids. Fundamental characteristics have been presented regarding how the effect of a non-isothermal field on miscible displacement patterns varies in terms of factors such as the viscosity ratio of the more- and less-viscous liquids at 20 C, M{sub 20}, the rate of an increase in the pattern's area, R, and the gap width of the cell, b. The concept of area density was used to quantitatively evaluate the effect ofmore » the non-isothermal fields on the patterns. We have found that the effect of the non-isothermal field on the patterns does not monotonically vary with M{sub 20} and b. In contrast, it increases with R in the present experimental condition. The experimental results can be explained by introducing an assumption in which heat is transferred mainly to the plates of the cell, in other words, the temperature of the more-viscous liquid remains constant, whereas that of the less-viscous liquid spatiotemporally decreases and the viscosity of it increases along with the temperature decrease. Visualization of non-isothermal field in the cell has been done by means of a thermo sheet and the results support the assumption mentioned above. (author)« less

Pseudolatex preparation using a novel emulsion-diffusion process involving direct displacement of partially water-miscible solvents by distillation.

PubMed

Quintanar-Guerrero, D; Allémann, E; Fessi, H; Doelker, E

1999-10-25

Pseudolatexes were obtained by a new process based on an emulsification-diffusion technique involving partially water-miscible solvents. The preparation method consisted of emulsifying an organic solution of polymer (saturated with water) in an aqueous solution of a stabilizing agent (saturated with solvent) using conventional stirrers, followed by direct solvent distillation. The technique relies on the rapid displacement of the solvent from the internal into the external phase which thereby provokes polymer aggregation. Nanoparticle formation is believed to occur because rapid solvent diffusion produces regions of local supersaturation near the interface, and nanoparticles are formed due to the ensuing interfacial phase transformations and polymer aggregation that occur in these interfacial domains. Using this method, it was possible to prepare pseudolatexes of biodegradable and non-biodegradable polymers such as poly(D,L-lactic acid) and poly(epsilon-caprolactone), Eudragit E, cellulose acetate phthalate, cellulose acetate trimellitate using ethyl acetate or 2-butanone as partially water-miscible solvents and poly(vinyl alcohol) or poloxamer 407 as stabilizing agent. A transition from nano- to microparticles was observed at high polymer concentrations. At concentrations above 30% w/v of Eudragit E in ethyl acetate or cellulose acetate phthalate in 2-butanone only microparticles were obtained. This behaviour was attributed to decreased transport of polymer molecules into the aqueous phase.

Effect of stirring on the safety of flammable liquid mixtures.

PubMed

Liaw, Horng-Jang; Gerbaud, Vincent; Chen, Chan-Cheng; Shu, Chi-Min

2010-05-15

Flash point is the most important variable employed to characterize fire and explosion hazard of liquids. The models developed for predicting the flash point of partially miscible mixtures in the literature to date are all based on the assumption of liquid-liquid equilibrium. In real-world environments, however, the liquid-liquid equilibrium assumption does not always hold, such as the collection or accumulation of waste solvents without stirring, where complete stirring for a period of time is usually used to ensure the liquid phases being in equilibrium. This study investigated the effect of stirring on the flash-point behavior of binary partially miscible mixtures. Two series of partially miscible binary mixtures were employed to elucidate the effect of stirring. The first series was aqueous-organic mixtures, including water+1-butanol, water+2-butanol, water+isobutanol, water+1-pentanol, and water+octane; the second series was the mixtures of two flammable solvents, which included methanol+decane, methanol+2,2,4-trimethylpentane, and methanol+octane. Results reveal that for binary aqueous-organic solutions the flash-point values of unstirred mixtures were located between those of the completely stirred mixtures and those of the flammable component. Therefore, risk assessment could be done based on the flammable component flash-point value. However, for the assurance of safety, it is suggested to completely stir those mixtures before handling to reduce the risk. Copyright (c) 2010 Elsevier B.V. All rights reserved.

Dependence on sphere size of the phase behavior of mixtures of rods and spheres

NASA Astrophysics Data System (ADS)

Urakami, Naohito; Imai, Masayuki

2003-07-01

By the addition of chondroitin sulfate (Chs) to the aqueous suspension of tobacco mosaic virus (TMV), the aggregation of TMV occurs at very dilute TMV concentration compared with the addition of polyethylene oxide (PEO). The difference of physical behavior between Chs and PEO is the chain conformation in solution. The Chs chain has a semirigid nature, whereas the PEO chain has a flexible nature. In this study, the Chs and PEO chains are simplified to spherical particles having different size, and we use the spherocylinder model for TMV particle. The effect of the sphere size on the phase behaviors in the mixtures of rods and spheres is investigated by Monte Carlo simulations. By the addition of small spheres, the system transforms from the miscible isotropic phase to the miscible nematic phase. On the other hand, by the addition of large spheres, the system changes from the miscible isotropic phase to the immiscible nematic phase through the immiscible isotropic phase. The different phase behaviors between the small and the large spheres originate from the difference of overlapping volume of the depletion zone. In addition, we perform the Monte Carlo simulations in the case that semirigid chains are used as the Chs chain models. The same phase behaviors are observed as the mixtures of rods and large spheres. Thus the sphere model captures the phase behaviors of rod and polymer mixture systems.

Effect of poly(ethylene oxide) homopolymer and two different poly(ethylene oxide-b-poly(propylene oxide)-b-poly(ethylene oxide) triblock copolymers on morphological, optical, and mechanical properties of nanostructured unsaturated polyester.

PubMed

Builes, Daniel H; Hernández-Ortiz, Juan P; Corcuera, Ma Angeles; Mondragon, Iñaki; Tercjak, Agnieszka

2014-01-22

Novel nanostructured unsaturated polyester resin-based thermosets, modified with poly(ethylene oxide) (PEO), poly(propylene oxide) (PPO), and two poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) block copolymers (BCP), were developed and analyzed. The effects of molecular weights, blocks ratio, and curing temperatures on the final morphological, optical, and mechanical properties were reported. The block influence on the BCP miscibility was studied through uncured and cured mixtures of unsaturated polyester (UP) resins with PEO and PPO homopolymers having molecular weights similar to molecular weights of the blocks of BCP. The final morphology of the nanostructured thermosetting systems, containing BCP or homopolymers, was investigated, and multiple mechanisms of nanostructuration were listed and explained. By considering the miscibility of each block before and after curing, it was determined that the formation of the nanostructured matrices followed a self-assembly mechanism or a polymerization-induced phase separation mechanism. The miscibility between PEO or PPO blocks with one of two phases of UP matrix was highlighted due to its importance in the final thermoset properties. Relationships between the final morphology and thermoset optical and mechanical properties were examined. The mechanisms and physics behind the morphologies lead toward the design of highly transparent, nanostructured, and toughened thermosetting UP systems.

Miscibility as a factor for component crystallization in multisolute frozen solutions.

PubMed

Izutsu, Ken-Ichi; Shibata, Hiroko; Yoshida, Hiroyuki; Goda, Yukihiro

2014-07-01

The relationship between the miscibility of formulation ingredients and their crystallization during the freezing segment of the lyophilization process was studied. The thermal properties of frozen solutions containing myo-inositol and cosolutes were obtained by performing heating scans from -70 °C before and after heat treatment at -20 °C to -5 °C. Addition of dextran 40,000 reduced and prevented crystallization of myo-inositol. In the first scan, some frozen solutions containing an inositol-rich mixture with dextran showed single broad transitions (Tg's: transition temperatures of maximally freeze-concentrated solutes) that indicated incomplete mixing of the concentrated amorphous solutes. Heat treatment of these frozen solutions induced separation of the solutes into inositol-dominant and solute mixture phases (Tg' splitting) following crystallization of myo-inositol (Tg' shifting). The crystal growth involved myo-inositol molecules in the solute mixture phase. The amorphous-amorphous phase separation and resulting loss of the heteromolecular interaction in the freeze-concentrated inositol-dominant phase should allow ordered assembly of the solute molecules required for nucleation. Some dextran-rich and intermediate concentration ratio frozen solutions retained single Tg's of the amorphous solute mixture, both before and after heat treatments. The relevance of solute miscibility on the crystallization of myo-inositol was also indicated in the systems containing glucose or recombinant human albumin. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

In situ stress and pore pressure in the Kumano Forearc Basin, offshore SW Honshu from downhole measurements during riser drilling

NASA Astrophysics Data System (ADS)

Saffer, D. M.; Flemings, P. B.; Boutt, D.; Doan, M.-L.; Ito, T.; McNeill, L.; Byrne, T.; Conin, M.; Lin, W.; Kano, Y.; Araki, E.; Eguchi, N.; Toczko, S.

2013-05-01

situ stress and pore pressure are key parameters governing rock deformation, yet direct measurements of these quantities are rare. During Integrated Ocean Drilling Program (IODP) Expedition #319, we drilled through a forearc basin at the Nankai subduction zone and into the underlying accretionary prism. We used the Modular Formation Dynamics Tester tool (MDT) for the first time in IODP to measure in situ minimum stress, pore pressure, and permeability at 11 depths between 729.9 and 1533.9 mbsf. Leak-off testing at 708.6 mbsf conducted as part of drilling operations provided a second measurement of minimum stress. The MDT campaign included nine single-probe (SP) tests to measure permeability and in situ pore pressure and two dual-packer (DP) tests to measure minimum principal stress. Permeabilities defined from the SP tests range from 6.53 × 10-17 to 4.23 × 10-14 m2. Pore fluid pressures are near hydrostatic throughout the section despite rapid sedimentation. This is consistent with the measured hydraulic diffusivity of the sediments and suggests that the forearc basin should not trap overpressures within the upper plate of the subduction zone. Minimum principal stresses are consistently lower than the vertical stress. We estimate the maximum horizontal stress from wellbore failures at the leak-off test and shallow MDT DP test depths. The results indicate a normal or strike-slip stress regime, consistent with the observation of abundant active normal faults in the seaward-most part of the basin, and a general decrease in fault activity in the vicinity of Site C0009.

Measurement of Capillary Radius and Contact Angle within Porous Media.

PubMed

Ravi, Saitej; Dharmarajan, Ramanathan; Moghaddam, Saeed

2015-12-01

The pore radius (i.e., capillary radius) and contact angle determine the capillary pressure generated in a porous medium. The most common method to determine these two parameters is through measurement of the capillary pressure generated by a reference liquid (i.e., a liquid with near-zero contact angle) and a test liquid. The rate of rise technique, commonly used to determine the capillary pressure, results in significant uncertainties. In this study, we utilize a recently developed technique for independently measuring the capillary pressure and permeability to determine the equivalent minimum capillary radii and contact angle of water within micropillar wick structures. In this method, the experimentally measured dryout threshold of a wick structure at different wicking lengths is fit to Darcy's law to extract the maximum capillary pressure generated by the test liquid. The equivalent minimum capillary radii of different wick geometries are determined by measuring the maximum capillary pressures generated using n-hexane as the working fluid. It is found that the equivalent minimum capillary radius is dependent on the diameter of pillars and the spacing between pillars. The equivalent capillary radii of micropillar wicks determined using the new method are found to be up to 7 times greater than the current geometry-based first-order estimates. The contact angle subtended by water at the walls of the micropillars is determined by measuring the capillary pressure generated by water within the arrays and the measured capillary radii for the different geometries. This mean contact angle of water is determined to be 54.7°.

Influence of geomagnetic activity and atmospheric pressure on human arterial pressure during the solar cycle 24

NASA Astrophysics Data System (ADS)

Azcárate, T.; Mendoza, B.; Levi, J. R.

2016-11-01

We performed a study of the systolic (SBP) and diastolic (DBP) arterial blood pressure behavior under natural variables such as the atmospheric pressure (AtmP) and the horizontal geomagnetic field component (H). We worked with a sample of 304 healthy normotense volunteers, 152 men and 152 women, with ages between 18 and 84 years in Mexico City during the period 2008-2014, corresponding to the minimum, ascending and maximum phases of the solar cycle 24. The data was divided by gender, age and day/night cycle. We studied the time series using three methods: Correlations, bivariate and superposed epochs (within a window of three days around the day of occurrence of a geomagnetic storm) analysis, between the SBP and DBP and the natural variables (AtmP and H). The correlation analysis indicated correlation between the SBP and DBP and AtmP and H, being the largest during the night. Furthermore, the correlation and bivariate analysis showed that the largest correlations are between the SBP and DBP and the AtmP. The superposed epoch analysis found that the largest number of significant SBP and DBP changes occurred for women. Finally, the blood pressure changes are larger during the solar minimum and ascending solar cycle phases than during the solar maximum; the storms of the minimum were more intense than those of the maximum and this could be the reason of behavior of the blood pressure changes along the solar cycle.

Low temperature synthesis of Ru-Cu alloy nanoparticles with the compositions in the miscibility gap

NASA Astrophysics Data System (ADS)

Martynova, S. A.; Filatov, E. Yu.; Korenev, S. V.; Kuratieva, N. V.; Sheludyakova, L. A.; Plusnin, P. E.; Shubin, Yu. V.; Slavinskaya, E. M.; Boronin, A. I.

2014-04-01

A complex salt [Ru(NH3)5Cl][Cu(C2O4)2H2O]-the precursor of nanoalloys combining ruthenium and copper was prepared. It crystallizes in the monoclinic space group P21/n. Thermal properties of the prepared salt were examined in different atmospheres (helium, hydrogen, oxygen). Thermal decomposition of the precursor in inert atmosphere was thoroughly examined and the intermediate products were characterized. Experimental conditions for preparation of copper-rich (up to 12 at% of copper) metastable solid solution CuxRu1-x (based on Ru structure) were optimized, what is in sharp contrast to the bimetallic miscibility gap known for the bulk counterparts in a wide composition range. Catalytic properties of copper-ruthenium oxide composite were tested in catalytic oxidation of CO.

Liquid Phase Miscibility Gap Materials

NASA Technical Reports Server (NTRS)

Gelles, S. H.; Markworth, A. J.

1985-01-01

The manner in which the microstructural features of liquid-phase miscibility gap alloys develop was determined. This will allow control of the microstructures and the resultant properties of these alloys. The long-duration low gravity afforded by the shuttle will allow experiments supporting this research to be conducted with minimal interference from buoyancy effects and gravitationally driven convection currents. Ground base studies were conducted on Al-In, Cu-Pb, and Te-Tl alloys to determine the effect of cooling rate, composition, and interfacial energies on the phase separation and solidification processes that influence the development of microstructure in these alloys. Isothermal and directional cooling experiments and simulations are conducted. The ground based activities are used as a technological base from which flight experiments formulated and to which these flight experiments are compared.

Interface instabilities during displacements of two miscible fluids in a vertical pipe

NASA Astrophysics Data System (ADS)

Scoffoni, J.; Lajeunesse, E.; Homsy, G. M.

2001-03-01

We study experimentally the downward vertical displacement of one miscible fluid by another in a vertical pipe at sufficiently high velocities for diffusive effects to be negligible. For certain viscosity ratios and flow rates, the interface between the two fluids can destabilize. We determine the dimensionless flow rate Uc above which the instability is triggered and its dependence on the viscous ratio M, resulting in a stability map Uc=Uc(M). Two different instability modes have been observed: an asymmetric "corkscrew" mode and an axisymmetric one. We remark that the latter is always eventually disturbed by "corkscrew" type instabilities. We speculate that these instabilities are driven by the viscosity stratification and are analogous to those already observed in core annular flows of immiscible fluids.

Investigations on transparent liquid-miscibility gap systems

NASA Technical Reports Server (NTRS)

Lacy, L. L.; Nishioka, G.; Ross, S.

1979-01-01

Sedimentation and phase separation is a well known occurrence in monotectic or miscibility gap alloys. Previous investigations indicate that it may be possible to prepare such alloys in a low-gravity space environment but recent experiments indicate that there may be nongravity dependent phase separation processes which can hinder the formation of such alloys. Such phase separation processes are studied using transparent liquid systems and holography. By reconstructing holograms into a commercial-particle-analysis system, real time computer analysis can be performed on emulsions with diameters in the range of 5 micrometers or greater. Thus dynamic effects associated with particle migration and coalescence can be studied. Characterization studies on two selected immiscible systems including an accurate determination of phase diagrams, surface and interfacial tension measurements, surface excess and wetting behavior near critical solution temperatures completed.

DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni

This report describes the progress of the project ''Development And Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the thirteenth project quarter (Oct 1, 2005 to Dec 30, 2005). There are three main tasks in this research project. Task 1 is a scaled physical model study of the GAGD process. Task 2 is further development of a vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. Section I reports experimental work designed to investigate wettability effects of porous medium, on secondary andmore » tertiary mode GAGD performance. The experiments showed a significant improvement of oil recovery in the oil-wet experiments versus the water-wet runs, both in secondary as well as tertiary mode. When comparing experiments conducted in secondary mode to those run in tertiary mode an improvement in oil recovery was also evident. Additionally, this section summarizes progress made with regard to the scaled physical model construction and experimentation. The purpose of building a scaled physical model, which attempts to include various multiphase mechanics and fluid dynamic parameters operational in the field scale, was to incorporate visual verification of the gas front for viscous instabilities, capillary fingering, and stable displacement. Preliminary experimentation suggested that construction of the 2-D model from sintered glass beads was a feasible alternative. During this reporting quarter, several sintered glass mini-models were prepared and some preliminary experiments designed to visualize gas bubble development were completed. In Section II, the gas-oil interfacial tensions measured in decane-CO{sub 2} system at 100 F and live decane consisting of 25 mole% methane, 30 mole% n-butane and 45 mole% n-decane against CO{sub 2} gas at 160 F have been modeled using the Parachor and newly proposed mechanistic Parachor models. In the decane-CO{sub 2} binary system, Parachor model was found to be sufficient for interfacial tension calculations. The predicted miscibility from the Parachor model deviated only by about 2.5% from the measured VIT miscibility. However, in multicomponent live decane-CO{sub 2} system, the performance of the Parachor model was poor, while good match of interfacial tension predictions has been obtained experimentally using the proposed mechanistic Parachor model. The predicted miscibility from the mechanistic Parachor model accurately matched with the measured VIT miscibility in live decane-CO2 system, which indicates the suitability of this model to predict miscibility in complex multicomponent hydrocarbon systems. In the previous reports to the DOE (15323R07, Oct 2004; 15323R08, Jan 2005; 15323R09, Apr 2005; 15323R10, July 2005 and 154323, Oct 2005), the 1-D experimental results from dimensionally scaled GAGD and WAG corefloods were reported for Section III. Additionally, since Section I reports the experimental results from 2-D physical model experiments; this section attempts to extend this 2-D GAGD study to 3-D (4-phase) flow through porous media and evaluate the performance of these processes using reservoir simulation. Section IV includes the technology transfer efforts undertaken during the quarter. This research work resulted in one international paper presentation in Tulsa, OK; one journal publication; three pending abstracts for SCA 2006 Annual Conference and an invitation to present at the Independents Day session at the IOR Symposium 2006.« less

Estimating Fluctuating Pressures From Distorted Measurements

NASA Technical Reports Server (NTRS)

Whitmore, Stephen A.; Leondes, Cornelius T.

1994-01-01

Two algorithms extract estimates of time-dependent input (upstream) pressures from outputs of pressure sensors located at downstream ends of pneumatic tubes. Effect deconvolutions that account for distoring effects of tube upon pressure signal. Distortion of pressure measurements by pneumatic tubes also discussed in "Distortion of Pressure Signals in Pneumatic Tubes," (ARC-12868). Varying input pressure estimated from measured time-varying output pressure by one of two deconvolution algorithms that take account of measurement noise. Algorithms based on minimum-covariance (Kalman filtering) theory.

49 CFR 232.103 - General requirements for all train brake systems.

Code of Federal Regulations, 2013 CFR

2013-10-01

... the air compressor governor starting or loading pressure. (l) Except as otherwise provided in this... brake pipe air pressure: Road Service 90 Switch Service 60 (2) Minimum differential between brake pipe and main reservoir air pressures, with brake valve in running position 15 (3) Safety valve for...

49 CFR 232.103 - General requirements for all train brake systems.

Code of Federal Regulations, 2012 CFR

2012-10-01

... the air compressor governor starting or loading pressure. (l) Except as otherwise provided in this... brake pipe air pressure: Road Service 90 Switch Service 60 (2) Minimum differential between brake pipe and main reservoir air pressures, with brake valve in running position 15 (3) Safety valve for...

Dynamic fracture toughness of ASME SA508 Class 2a ASME SA533 grade A Class 2 base and heat affected zone material and applicable weld metals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Logsdon, W.A.; Begley, J.A.; Gottshall, C.L.

1978-03-01

The ASME Boiler and Pressure Vessel Code, Section III, Article G-2000, requires that dynamic fracture toughness data be developed for materials with specified minimum yield strengths greater than 50 ksi to provide verification and utilization of the ASME specified minimum reference toughness K/sub IR/ curve. In order to qualify ASME SA508 Class 2a and ASME SA533 Grade A Class 2 pressure vessel steels (minimum yield strengths equal 65 kip/in./sup 2/ and 70 kip/in./sup 2/, respectively) per this requirement, dynamic fracture toughness tests were performed on these materials. All dynamic fracture toughness values of SA508 Class 2a base and HAZ material,more » SA533 Grade A Class 2 base and HAZ material, and applicable weld metals exceeded the ASME specified minimum reference toughness K/sub IR/ curve.« less

42 CFR 84.201 - Head harnesses; minimum requirements.

Code of Federal Regulations, 2010 CFR

2010-10-01

... of pressure over the entire area in contact with the face. (2) Facepieces for single-use vinyl... adequate tension during use and an even distribution of pressure over the entire area in contact with the...

CO/sub 2/ line design needs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Recht, D.L.

Large volumes of carbon dioxide are required for tertiary oil recovery projects that utilize the carbon dioxide miscible flooding method. Carbon dioxide can be successfully transported as a supercritical fluid through a pipeline designed and operated similar to a natural gas pipeline, with careful consideration given to specific differences in design and materials of construction. Carbon dioxide is a colorless, odorless, nonflammable, non-toxic substance that may exist as a gas, as a liquid, as a solid, or in all three forms at its triple point. The critical pressure and temperature of CO/sub 2/ are 1,070 psia and 88/sup 0/F, respectively.more » It is present in the normal atmosphere in a concentration of approximately 330 ppm, and somewhat higher concentrations may occur in occupied buildings. Air in lungs contains approximately 5.5% (55,000 ppm) of CO/sub 2/. Although it is non-toxic, air containing 10% to 20% CO/sub 2/ concentrations by volume is immediately hazardous to life by causing unconsciousness, failure of respiratory muscles, and a change in the pH of the blood stream. Carbon dioxide is commonly used for carbonated beverages, aerosol propellants, fire extinguishers, enrichment of air in greenhouses, fracturing and acidizing of oil wells, as a shielding gas for welding, and as dry ice for refrigeration. In tertiary recovery projects of suitable oil reservoirs, CO/sub 2/ is injected into the formation where it dissolves in the oil, swells the oil, reduces the oil's viscosity, exerts an acidic effect on the reservoir rock (in some cases), and vaporizes some of the oil. As a rough rule of thumb, approximately 6 to 10 mcf of CO/sub 2/ are required to be injected for recovery of 1 bbl of oil. Carbon dioxide miscible flooding will recover approximately 10% to 15% of the oil remaining in place after a waterflood program.« less

30 CFR 250.1003 - Installation, testing, and repair requirements for DOI pipelines.

Code of Federal Regulations, 2010 CFR

2010-07-01

.... (a)(1) Pipelines greater than 8-5/8 inches in diameter and installed in water depths of less than 200... shall be pressure tested with water at a stabilized pressure of at least 1.25 times the MAOP for at... pressure tested with water or processed natural gas at a minimum stabilized pressure of at least 1.25 times...

Role of medium heterogeneity and viscosity contrast in miscible flow regimes and mixing zone growth: A computational pore-scale approach

NASA Astrophysics Data System (ADS)

Afshari, Saied; Hejazi, S. Hossein; Kantzas, Apostolos

2018-05-01

Miscible displacement of fluids in porous media is often characterized by the scaling of the mixing zone length with displacement time. Depending on the viscosity contrast of fluids, the scaling law varies between the square root relationship, a sign for dispersive transport regime during stable displacement, and the linear relationship, which represents the viscous fingering regime during an unstable displacement. The presence of heterogeneities in a porous medium significantly affects the scaling behavior of the mixing length as it interacts with the viscosity contrast to control the mixing of fluids in the pore space. In this study, the dynamics of the flow and transport during both unit and adverse viscosity ratio miscible displacements are investigated in heterogeneous packings of circular grains using pore-scale numerical simulations. The pore-scale heterogeneity level is characterized by the variations of the grain diameter and velocity field. The growth of mixing length is employed to identify the nature of the miscible transport regime at different viscosity ratios and heterogeneity levels. It is shown that as the viscosity ratio increases to higher adverse values, the scaling law of mixing length gradually shifts from dispersive to fingering nature up to a certain viscosity ratio and remains almost the same afterwards. In heterogeneous media, the mixing length scaling law is observed to be generally governed by the variations of the velocity field rather than the grain size. Furthermore, the normalization of mixing length temporal plots with respect to the governing parameters of viscosity ratio, heterogeneity, medium length, and medium aspect ratio is performed. The results indicate that mixing length scales exponentially with log-viscosity ratio and grain size standard deviation while the impact of aspect ratio is insignificant. For stable flows, mixing length scales with the square root of medium length, whereas it changes linearly with length during unstable flows. This scaling procedure allows us to describe the temporal variation of mixing length using a generalized curve for various combinations of the flow conditions and porous medium properties.

Phase separation of comb polymer nanocomposite melts.

PubMed

Xu, Qinzhi; Feng, Yancong; Chen, Lan

2016-02-07

In this work, the spinodal phase demixing of branched comb polymer nanocomposite (PNC) melts is systematically investigated using the polymer reference interaction site model (PRISM) theory. To verify the reliability of the present method in characterizing the phase behavior of comb PNCs, the intermolecular correlation functions of the system for nonzero particle volume fractions are compared with our molecular dynamics simulation data. After verifying the model and discussing the structure of the comb PNCs in the dilute nanoparticle limit, the interference among the side chain number, side chain length, nanoparticle-monomer size ratio and attractive interactions between the comb polymer and nanoparticles in spinodal demixing curves is analyzed and discussed in detail. The results predict two kinds of distinct phase separation behaviors. One is called classic fluid phase boundary, which is mediated by the entropic depletion attraction and contact aggregation of nanoparticles at relatively low nanoparticle-monomer attraction strength. The second demixing transition occurs at relatively high attraction strength and involves the formation of an equilibrium physical network phase with local bridging of nanoparticles. The phase boundaries are found to be sensitive to the side chain number, side chain length, nanoparticle-monomer size ratio and attractive interactions. As the side chain length is fixed, the side chain number has a large effect on the phase behavior of comb PNCs; with increasing side chain number, the miscibility window first widens and then shrinks. When the side chain number is lower than a threshold value, the phase boundaries undergo a process from enlarging the miscibility window to narrowing as side chain length increases. Once the side chain number overtakes this threshold value, the phase boundary shifts towards less miscibility. With increasing nanoparticle-monomer size ratio, a crossover of particle size occurs, above which the phase separation is consistent with that of chain PNCs. The miscibility window for this condition gradually narrows while the other parameters of the PNCs system are held constant. These results indicate that the present PRISM theory can give molecular-level details of the underlying mechanisms of the comb PNCs. It is hoped that the results can be used to provide useful guidance for the future design control of novel, thermodynamically stable comb PNCs.

Theoretical and experimental investigation of drug-polymer interaction and miscibility and its impact on drug supersaturation in aqueous medium.

PubMed

Baghel, Shrawan; Cathcart, Helen; O'Reilly, Niall J

2016-10-01

Amorphous solid dispersions (ASDs) have the potential to offer higher apparent solubility and bioavailability of BCS class II drugs. Knowledge of the solid state drug-polymer solubility/miscibility and their mutual interaction are fundamental requirements for the effective design and development of such systems. To this end, we have carried out a comprehensive investigation of various ASD systems of dipyridamole and cinnarizine in polyvinylpyrrolidone (PVP) and polyacrylic acid (PAA) at different drug loadings. Theoretical and experimental examinations (by implementing binary and ternary Flory-Huggins (F-H) theory) related to drug-polymer interaction/miscibility including solubility parameter approach, melting point depression method, phase diagram, drug-polymer interaction in the presence of moisture and the effect of drug loading on interaction parameter were performed. The information obtained from this study was used to predict the stability of ASDs at different drug loadings and under different thermal and moisture conditions. Thermal and moisture sorption analysis not only provided the composition-dependent interaction parameter but also predicted the composition dependent miscibility. DPM-PVP, DPM-PAA and CNZ-PAA systems have shown molecular level mixing over the complete range of drug loading. For CNZ-PVP, the presence of a single Tg at lower drug loadings (10, 20 and 35%w/w) indicates the formation of solid solution. However, drug recrystallization was observed for samples with higher drug weight fractions (50 and 65%w/w). Finally, the role of polymer in maintaining drug supersaturation has also been explored. It has been found that drug-polymer combinations capable of hydrogen-bonding in the solution state (DPM-PVP, DPM-PAA and CNZ-PAA) are more effective in preventing drug crystallization compared to the drug-polymer systems without such interaction (CNZ-PVP). The DPM-PAA system outperformed all other ASDs in various stability conditions (dry-state, in the presence of moisture and in solution state), which was attributed to the drug's low crystallization tendency, the strong DPM-PAA interaction, the robustness of this interaction against moisture or water and the ability of PAA in maintaining DPM supersaturation. Copyright © 2016 Elsevier B.V. All rights reserved.

Lunar and Planetary Science XXXV: Terrestrial Planets: Building Blocks and Differentiation

NASA Technical Reports Server (NTRS)

2004-01-01

The session "Terrestrial Planets: Building Blocks and Differentiation: included the following topics:Magnesium Isotopes in the Earth, Moon, Mars, and Pallasite Parent Body: High-Precision Analysis of Olivine by Laser-Ablation Multi-Collector ICPMS; Meteoritic Constraints on Collision Rates in the Primordial Asteroid Belt and Its Origin; New Constraints on the Origin of the Highly Siderophile Elements in the Earth's Upper Mantle; Further Lu-Hf and Sm-Nd Isotopic Data on Planetary Materials and Consequences for Planetary Differentiation; A Deep Lunar Magma Ocean Based on Neodymium, Strontium and Hafnium Isotope Mass Balance Partial Resetting on Hf-W System by Giant Impacts; On the Problem of Metal-Silicate Equilibration During Planet Formation: Significance for Hf-W Chronometry ; Solid Metal-Liquid Metal Partitioning of Pt, Re, and Os: The Effect of Carbon; Siderophile Element Abundances in Fe-S-Ni-O Melts Segregated from Partially Molten Ordinary Chondrite Under Dynamic Conditions; Activity Coefficients of Silicon in Iron-Nickel Alloys: Experimental Determination and Relevance for Planetary Differentiation; Reinvestigation of the Ni and Co Metal-Silicate Partitioning; Metal/Silicate Paritioning of P, Ga, and W at High Pressures and Temperatures: Dependence on Silicate Melt Composition; and Closure of the Fe-S-Si Liquid Miscibility Gap at High Pressure and Its Implications for Planetary Core Formation.

Interfacial behavior of Myristic acid in mixtures with DMPC and Cholesterol

NASA Astrophysics Data System (ADS)

Khattari, Z.; Sayyed, M. I.; Qashou, S. I.; Fasfous, I.; Al-Abdullah, T.; Maghrabi, M.

2017-06-01

Binary mixture monolayers of Myristic acid (MA) with the same length of saturated acyl chain lipid viz 1,2-myristoyl-sn-glycero-3-phosphocholine (DMPC) and Cholesterol (Chol), were investigated under different experimental conditions using Langmuir monolayers (LMs). The interfacial pressure-area (π-A) isotherms, excess molecular area, excess free energy and fluorescence microscopy (FM) images were recorded at the air/water interface. Monolayers of both systems (e.g. MA/DMPC, MA/Chol) reach the closest acyl hydrophobic chain packing in the range 0.20 < xMA < 0.70. Thermodynamic analysis indicates miscibility of the binary mixtures when spread at the air/water interface with negative deviation from the ideal behavior. Morphological features of MA/DMPC systems were found to depend strongly on MA mole fraction and pressures by showing two extreme minima in Gibbs free energy of mixing, while MA/Chol systems showed only an effective condensing effect at xMA = 0.90. In the whole range of compositions studied here, the liquid-expanded (LE) to liquid-condensed (LC) phase transition occurs at increasing xAM as it accomplished by a huge increase in the inverse compressibility modulus. FM observations confirmed the phase-transition and condensing effects of both mixture monolayers as evidenced by Gibbs free energy of mixing in a limited range of compositions.

Multimodal pressure-flow method to assess dynamics of cerebral autoregulation in stroke and hypertension.

PubMed

Novak, Vera; Yang, Albert C C; Lepicovsky, Lukas; Goldberger, Ary L; Lipsitz, Lewis A; Peng, Chung-Kang

2004-10-25

This study evaluated the effects of stroke on regulation of cerebral blood flow in response to fluctuations in systemic blood pressure (BP). The autoregulatory dynamics are difficult to assess because of the nonstationarity and nonlinearity of the component signals. We studied 15 normotensive, 20 hypertensive and 15 minor stroke subjects (48.0 +/- 1.3 years). BP and blood flow velocities (BFV) from middle cerebral arteries (MCA) were measured during the Valsalva maneuver (VM) using transcranial Doppler ultrasound. A new technique, multimodal pressure-flow analysis (MMPF), was implemented to analyze these short, nonstationary signals. MMPF analysis decomposes complex BP and BFV signals into multiple empirical modes, representing their instantaneous frequency-amplitude modulation. The empirical mode corresponding to the VM BP profile was used to construct the continuous phase diagram and to identify the minimum and maximum values from the residual BP (BPR) and BFV (BFVR) signals. The BP-BFV phase shift was calculated as the difference between the phase corresponding to the BPR and BFVR minimum (maximum) values. BP-BFV phase shifts were significantly different between groups. In the normotensive group, the BFVR minimum and maximum preceded the BPR minimum and maximum, respectively, leading to large positive values of BP-BFV shifts. In the stroke and hypertensive groups, the resulting BP-BFV phase shift was significantly smaller compared to the normotensive group. A standard autoregulation index did not differentiate the groups. The MMPF method enables evaluation of autoregulatory dynamics based on instantaneous BP-BFV phase analysis. Regulation of BP-BFV dynamics is altered with hypertension and after stroke, rendering blood flow dependent on blood pressure.

Power Doppler of the urethra in continent or incontinent, pre- and postmenopausal women.

PubMed

Jármy-Di Bella, Z I; Girão, M J; Sartori, M F; Di Bella Júnior, V; Lederman, H M; Baracat, E C; Lima, G R

2000-06-01

Urethral pressure should exceed bladder pressure, both at rest and on stress, for urinary continence to occur. A decrease in urethral pressure is a major factor explaining the pathogenesis of urinary incontinence. A number of elements, such as smooth and striated periurethral muscles, and connective, vascular and elastic tissues, contribute to urethral pressure. The periurethral vessels are influenced by hormonal changes during the menstrual cycle, during pregnancy and postmenopause. We studied the periurethral vessels in 97 women, 57 of whom were incontinent and 40 continent, using power color Doppler velocimetry. The number of periurethral vessels, systolic peak, minimum diastolic values, pulsatility and resistance indexes, as well as systolic-diastolic ratio, were assessed. Statistically significant differences were found between incontinent women in the premenopausal period and those in the postmenopausal period, regarding the number of periurethral vessels, systolic peak, minimum diastolic values, pulsatility and resistance indexes.

Intercooler cooling-air weight flow and pressure drop for minimum drag loss

NASA Technical Reports Server (NTRS)

Reuter, J George; Valerino, Michael F

1944-01-01

An analysis has been made of the drag losses in airplane flight of cross-flow plate and tubular intercoolers to determine the cooling-air weight flow and pressure drop that give a minimum drag loss for any given cooling effectiveness and, thus, a maximum power-plant net gain due to charge-air cooling. The drag losses considered in this analysis are those due to (1) the extra drag imposed on the airplane by the weight of the intercooler, its duct, and its supports and (2) the drag sustained by the cooling air in flowing through the intercooler and its duct. The investigation covers a range of conditions of altitude, airspeed, lift-drag ratio, supercharger-pressure ratio, and supercharger adiabatic efficiency. The optimum values of cooling air pressure drop and weight flow ratio are tabulated. Curves are presented to illustrate the results of the analysis.

76 FR 9449 - National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-17

... chemistry, scrubber pressure drop, and scrubber inlet gas temperature hourly. The final rule does not... pressure) and inlet gas temperature to be based on the minimum flow rate (or line pressure) or maximum inlet gas temperature established during the initial performance test. It also includes two additional...

Oxygen Concentration Flammability Threshold Tests for the Constellation Program

NASA Technical Reports Server (NTRS)

Williams, James H.

2007-01-01

CEV atmosphere will likely change because craft will be used as LEO spacecraft, lunar spacecraft, orbital spacecraft. Possible O2 % increase and overall pressure decrease pressure vessel certs on spacecraft. Want 34% minimum threshold. Higher, better when atmosphere changes. WSTF suggests testing all materials/components to find flammability threshold, pressure and atmosphere.

Aerodynamics of a Transitioning Turbine Stator Over a Range of Reynolds Numbers

NASA Technical Reports Server (NTRS)

Boyle, R. J.; Lucci, B. L.; Verhoff, V. G.; Camperchioli, W. P.; La, H.

1998-01-01

Midspan aerodynamic measurements for a three vane-four passage linear turbine vane cascade are given. The vane axial chord was 4.45 cm. Surface pressures and loss coefficients were measured at exit Mach numbers of 0.3, 0.7, and 0.9. Reynolds number was varied by a factor of six at the two highest Mach numbers, and by a factor of ten at the lowest Mach number. Measurements were made with and without a turbulence grid. Inlet turbulence intensities were less than I% and greater than IO%. Length scales were also measured. Pressurized air fed the test section, and exited to a low pressure exhaust system. Maximum inlet pressure was two atmospheres. The minimum inlet pressure for an exit Mach number of 0.9 was one-third of an atmosphere, and at a Mach number of 0.3, the minimum pressure was half this value. The purpose of the test was to provide data for verification of turbine vane aerodynamic analyses, especially at low Reynolds numbers. Predictions obtained using a Navier-Stokes analysis with an algebraic turbulence model are also given.

Correlations of catalytic combustor performance parameters

NASA Technical Reports Server (NTRS)

Bulzan, D. L.

1978-01-01

Correlations for combustion efficiency percentage drop and the minimum required adiabatic reaction temperature necessary to meet emissions goals of 13.6 g CO/kg fuel and 1.64 g HC/kg fuel are presented. Combustion efficiency was found to be a function of the cell density, cell circumference, reactor length, reference velocity, and adiabatic reaction temperature. The percentage pressure drop at an adiabatic reaction temperature of 1450 K was found to be proportional to the reference velocity to the 1.5 power and to the reactor length. It is inversely proportional to the pressure, cell hydraulic diameter, and fractional open area. The minimum required adiabatic reaction temperature was found to increase with reference velocity and decrease with cell circumference, cell density and reactor length. A catalyst factor was introduced into the correlations to account for differences between catalysts. Combustion efficiency, the percentage pressure drop, and the minimum required adiabatic reaction temperature were found to be a function of the catalyst factor. The data was from a 12 cm-diameter test rig with noble metal reactors using propane fuel at an inlet temperature of 800 K.

Notes: Water Flow and Chemical Retardation in Soils: A Simple Effective Laboratory Demonstration.

ERIC Educational Resources Information Center

Bowman, R. S.; And Others

1988-01-01

Describes a laboratory demonstration that illustrates principles of miscible displacement and chemical retardation in soils. Discusses how the experimental apparatus can be constructed from readily available materials. (TW)

42 CFR 84.152 - Breathing tube test; minimum requirements.

Code of Federal Regulations, 2010 CFR

2010-10-01

...: (i) Be employed on Type C supplied-air respirators of the demand and pressure-demand class; and (ii... SAFETY AND HEALTH RESEARCH AND RELATED ACTIVITIES APPROVAL OF RESPIRATORY PROTECTIVE DEVICES Supplied-Air Respirators § 84.152 Breathing tube test; minimum requirements. (a)(1) Type A and Type B supplied-air...

Contribution to the thermodynamic description of the corium - The U-Zr-O system

NASA Astrophysics Data System (ADS)

Quaini, A.; Guéneau, C.; Gossé, S.; Dupin, N.; Sundman, B.; Brackx, E.; Domenger, R.; Kurata, M.; Hodaj, F.

2018-04-01

In order to understand the stratification process that may occur in the late phase of the fuel degradation during a severe accident in a PWR, the thermodynamic knowledge of the U-Zr-O system is crucial. The presence of a miscibility gap in the U-Zr-O liquid phase may lead to a stratified configuration, which will impact the accidental scenario management. The aim of this work was to obtain new experimental data in the U-Zr-O liquid miscibility gap. New tie-line data were provided at 2567 ± 25 K. The related thermodynamic models were reassessed using present data and literature values. The reassessed model will be implemented in the TAF-ID international database. The composition and density of phases potentially formed during stratification will be predicted by coupling current thermodynamic model with thermal-hydraulics codes.

Effect of solvent evaporation and coagulation on morphology development of asymmetric membranes

NASA Astrophysics Data System (ADS)

Chandrasekaran, Neelakandan; Kyu, Thein

2008-03-01

Miscibility behavior of blends of amorphous polyamide (PA) and polyvinylpyrrolidone (PVP) was studied in relation to membrane formation. Dimethylsulfoxide (DMSO) and water were used as solvent and non-solvent, respectively. Differential scanning calorimetry and cloud point measurements revealed that the binary PA/PVP blends as well as the ternary PA/PVP/DMSO system were completely miscible at all compositions. However, the addition of non-solvent (water) to this ternary system has led to phase separation. Visual turbidity study was used to establish a ternary liquid-liquid phase diagram of the PA-PVP/DMSO/water system. Scanning Electron Microscopy (SEM) showed the development of finger-like and sponge-like cross sectional morphologies during coagulation. Effects of polymer concentration, PA/PVP blend ratio, solvent/non-solvent quality, and evaporation time on the resulting membrane morphology will be discussed.

How the flow affects the phase behaviour and microstructure of polymer nanocomposites.

PubMed

Stephanou, Pavlos S

2015-02-14

We address the issue of flow effects on the phase behaviour of polymer nanocomposite melts by making use of a recently reported Hamiltonian set of evolution equations developed on principles of non-equilibrium thermodynamics. To this end, we calculate the spinodal curve, by computing values for the nanoparticle radius as a function of the polymer radius-of-gyration for which the second derivative of the generalized free energy of the system becomes zero. Under equilibrium conditions, we recover the phase diagram predicted by Mackay et al. [Science 311, 1740 (2006)]. Under non-equilibrium conditions, we account for the extra terms in the free energy due to changes in the conformations of polymer chains by the shear flow. Overall, our model predicts that flow enhances miscibility, since the corresponding miscibility window opens up for non-zero shear rate values.

Brewster Angle Microscopy Study of Model Stratum Corneum Lipid Monolayers at the Air-Water Interface

NASA Astrophysics Data System (ADS)

Adams, Ellen; Champagne, Alex; William, Joseph; Allen, Heather

2012-04-01

As the first and last barrier in the body, the stratum corneum (SC) is essential to life. Understanding the interactions and organization of lipids within the SC provides insight into essential physiological processes, including water loss prevention and the adsorption of substances from the environment. Langmuir monolayers have long been used to study complex systems, such as biological membranes and marine aerosols, due to their ability to shed light on intermolecular interactions. In this study, lipid mixtures with varying cholesterol and cerebroside ratios were investigated at the air/water interface. Surface tension measurements along with Brewster angle microscopy (BAM) images were used to examine the lipid phase transitions. Results indicate that cholesterol and cerebrosides form miscible monolayers, exhibiting ideal behavior. BAM images of a singular, uniform collapse phase also suggest formation of a miscible monolayer.

Crystallization of D-mannitol in binary mixtures with NaCl: phase diagram and polymorphism.

PubMed

Telang, Chitra; Suryanarayanan, Raj; Yu, Lian

2003-12-01

To study the crystallization, polymorphism, and phase behavior of D-mannitol in binary mixtures with NaCl to better understand their interactions in frozen aqueous solutions. Differential scanning calorimetry, hot-stage microscopy, Raman microscopy, and variable-temperature X-ray diffractometry were used to characterize D-mannitol-NaCl mixtures. NaCl and D-mannitol exhibited significant melt miscibility (up to 7.5% w/w or 0.20 mole fraction of NaCl) and a eutectic phase diagram (eutectic composition 7.5% w/w NaCl; eutectic temperature 150 degrees C for the alpha and beta polymorphs of D-mannitol and 139 degrees C for the delta). The presence of NaCl did not prevent mannitol from crystallizing but, depending on sample size, affected the polymorph crystallized: below 10 mg, delta was obtained; above 100 mg, alpha was obtained. Pure mannitol crystallized under the same conditions first as the delta polymorph and then as the a polymorph, with the latter nucleating on the former. KCl showed similar eutectic points and melt miscibility with D-mannitol as NaCl. LiCl yielded lower eutectic melting points, inhibited the crystallization of D-mannitol during cooling, and enabled the observation of its glass transition. Despite their structural dissimilarity, significant melt miscibility exists between D-mannitol and NaCl. Their phase diagram has been determined and features polymorph-dependent eutectic points. NaCl influences the polymorphic behavior of mannitol, and the effect is linked to the crystallization of mannitol in two polymorphic stages.

CFD study of mixing miscible liquid with high viscosity difference in a stirred tank

NASA Astrophysics Data System (ADS)

Madhania, S.; Cahyani, A. B.; Nurtono, T.; Muharam, Y.; Winardi, S.; Purwanto, W. W.

2018-03-01

The mixing process of miscible liquids with high viscosity difference is crucial role even though the solution mutually dissolved. This paper describes the mixing behaviour of the water-molasses system in a conical-bottomed cylindrical stirred tank (D = 0.28 m and H = 0.395 m) equipped with a side-entry Marine propeller (d = 0.036 m) under the turbulence regime using a three-dimensional and transient CFD-simulation. The objective of this work is to compare the solution strategies was applied in the computational analysis to capture the detail phenomena of mixing two miscible liquid with high viscosity difference. Four solution strategies that have been used are the RANS Standards k-ε (SKE) model as the turbulence model coupled with the Multiple Reference Frame (MRF) method for impeller motion, the RANS Realizable k-ε (RKE) combine with the MRF, the Large Eddy Simulation (LES) coupled with the Sliding Mesh (SM) method and the LES-MRF combination. The transient calculations were conducted with Ansys Fluent 17.1 version. The mixing behaviour and the propeller characteristic are to be compared and discussed in this work. The simulation results show the differences of flow pattern and the molasses distribution profile for every solution strategy. The variation of the flow pattern which happened in each solution strategy showing an instability of the mixing process in stirred tank. The LES-SM strategy shows the realistic direction of flow than another solution strategies.

Amorphous and Crystalline Particulates: Challenges and Perspectives in Drug Delivery.

PubMed

Al-Obaidi, Hisham; Majumder, Mridul; Bari, Fiza

2017-01-01

Crystalline and amorphous dispersions have been the focus of academic and industrial research due to their potential role in formulating poorly water-soluble drugs. This review looks at the progress made starting with crystalline carriers in the form of eutectics moving towards more complex crystalline mixtures. It also covers using glassy polymers to maintain the drug as amorphous exhibiting higher energy and entropy. However, the amorphous form tends to recrystallize on storage, which limits the benefits of this approach. Specific interactions between the drug and the polymer may retard this spontaneous conversion of the amorphous drug. Some studies have shown that it is possible to maintain the drug in the amorphous form for extended periods of time. For the drug and the polymer to form a stable mixture they have to be miscible on a molecular basis. Another form of solid dispersions is pharmaceutical co-crystals, for which research has focused on understanding the chemistry, crystal engineering and physico-chemical properties. USFDA has issued a guidance in April 2013 suggesting that the co-crystals as a pharmaceutical product may be a reality; but just not yet! While some of the research is still oriented towards application of these carriers, understanding the mechanism by which drug-carrier miscibility occurs is also covered. Within this context is the use of thermodynamic models such as Flory-Huggins model with some examples of studies used to predict miscibility. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

Time-of-flight expansion of binary Bose–Einstein condensates at finite temperature

NASA Astrophysics Data System (ADS)

Lee, K. L.; Jørgensen, N. B.; Wacker, L. J.; Skou, M. G.; Skalmstang, K. T.; Arlt, J. J.; Proukakis, N. P.

2018-05-01

Ultracold quantum gases provide a unique setting for studying and understanding the properties of interacting quantum systems. Here, we investigate a multi-component system of 87Rb–39K Bose–Einstein condensates (BECs) with tunable interactions both theoretically and experimentally. Such multi-component systems can be characterized by their miscibility, where miscible components lead to a mixed ground state and immiscible components form a phase-separated state. Here we perform the first full simulation of the dynamical expansion of this system including both BECs and thermal clouds, which allows for a detailed comparison with experimental results. In particular we show that striking features emerge in time-of-flight (TOF) for BECs with strong interspecies repulsion, even for systems which were separated in situ by a large gravitational sag. An analysis of the centre of mass positions of the BECs after expansion yields qualitative agreement with the homogeneous criterion for phase-separation, but reveals no clear transition point between the mixed and the separated phases. Instead one can identify a transition region, for which the presence of a gravitational sag is found to be advantageous. Moreover, we analyse the situation where only one component is condensed and show that the density distribution of the thermal component also shows some distinct features. Our work sheds new light on the analysis of multi-component systems after TOF and will guide future experiments on the detection of miscibility in these systems.

Calcium Ions as “Miscibility Switch”: Colocalization of Surfactant Protein B with Anionic Lipids under Absolute Calcium Free Conditions

PubMed Central

Saleem, Mohammed; Meyer, Michaela C.; Breitenstein, Daniel; Galla, Hans-Joachim

2009-01-01

Abstract One of the main determinants of lung surfactant function is the complex interplay between its protein and lipid components. The lipid specificity of surfactant protein B (SP-B), however, and the protein's ability to selectively squeeze out lipids, has remained contradictory. In this work we present, for the first time to our knowledge, by means of time-of-flight secondary ion mass spectrometry chemical imaging, a direct evidence for colocalization of SP-B as well as its model peptide KL4 with negatively charged dipalmitoylphosphatidylglycerol under absolute calcium free conditions. Our results prove that protein/lipid localization depends on the miscibility of all surfactant components, which itself is influenced by subphase ionic conditions. In contrast to our earlier studies reporting SP-B/KL4 colocalization with zwitterionic dipalmitoylphosphatidylcholine, in the presence of even the smallest traces of calcium, we finally evidence an apparent reversal of protein/lipid mixing behavior upon calcium removal with ethylene diamine tetraacetic acid. In addition, scanning force microscopy measurements reveal that by depleting the subphase from calcium ions the protrusion formation ability of SP-B or KL4 is not hampered. However, in the case of KL4, distinct differences in protrusion morphology and height are visible. Our results support the idea that calcium ions act as a “miscibility switch” in surfactant model systems and probably are one of the major factors steering lipid/protein mixing behavior as well as influencing the protein's protrusion formation ability. PMID:19619464

Surface-bonded ionic liquid stationary phases in high-performance liquid chromatography--a review.

PubMed

Pino, Verónica; Afonso, Ana M

2012-02-10

Ionic liquids (ILs) are a class of ionic, nonmolecular solvents which remain in liquid state at temperatures below 100°C. ILs possess a variety of properties including low to negligible vapor pressure, high thermal stability, miscibility with water or a variety of organic solvents, and variable viscosity. IL-modified silica as novel high-performance liquid chromatography (HPLC) stationary phases have attracted considerable attention for their differential behavior and low free-silanol activity. Indeed, around 21 surface-confined ionic liquids (SCIL) stationary phases have been developed in the last six years. Their chromatographic behavior has been studied, and, despite the presence of a positive charge on the stationary phase, they showed considerable promise for the separation of neutral solutes (not only basic analytes), when operated in reversed phase mode. This aspect points to the potential for truly multimodal stationary phases. This review attempts to summarize the state-of-the-art about SCIL phases including their preparation, chromatographic behavior, and analytical performance. Copyright © 2011 Elsevier B.V. All rights reserved.

Preparation of powders suitable for conversion to useful .beta.-aluminas

DOEpatents

Morgan, Peter E. D.

1982-01-01

A process for forming a precursor powder which, when suitably pressed and sintered forms highly pure, densified .beta.- or .beta."-alumina, comprising the steps of: (1) forming a suspension (or slurry) of Bayer-derived Al(OH).sub.3 in a water-miscible solvent; (2) adding an aqueous solution of a Mg compound, a Li compound, a Na compound or mixtures thereof to the Bayer-derived Al(OH).sub.3 suspension while agitating the mixture formed thereby, to produce a gel; (3) drying the gel at a temperature above the normal boiling point of water to produce a powder material; (4) lightly ball milling and sieving said powder material; and (5) heating the ball-milled and sieved powder material at a temperature of between 350.degree. to 900.degree. C. to form the .beta.- or .beta."-alumina precursor powder. The precursor powder, thus formed, may be subsequently isopressed at a high pressure and sintered at an elevated temperature to produce .beta.- or .beta."-alumina. BACKGROUND OF THE INVENTION

Efficient capture of SO2 by a binary mixture of caprolactam tetrabutyl ammonium bromide ionic liquid and water.

PubMed

Duan, Erhong; Guo, Bin; Zhang, Miaomiao; Guan, Yanan; Sun, Hua; Han, Jing

2011-10-30

The solubility of SO(2) in a binary mixture of water and caprolactam tetrabutyl ammonium bromide ionic liquid (CPL-TBAB IL) was investigated. Though the ionic liquid and water were fully miscible, a phase separation occurred when SO(2) was introduced into the mixture. The SO(2) concentrated in the lower layer, and it could be released by heating the solution under reduced pressure (382.2K, 10.1 kPa). After desorption, the mixture could be reused to absorb SO(2). It was found that SO(2) acts as a switch to cause the water and CPL-TBAB IL to phase separate, and the mechanics of this phase separation process was studied by gas chromatography-mass spectrometry, fourier transform-infrared spectroscopy and Karl-Fisher titration. The absorption and desorption of SO(2) in the CPL-TBAB/water mixtures were reversible. Copyright © 2011 Elsevier B.V. All rights reserved.

Liquid-solid equilibria involving spinel, ilmenite, and ferropseudobrookite in the system 'FeO'-Al2O3-TiO2 in contact with metallic iron

NASA Technical Reports Server (NTRS)

Schreifels, W. A.; Muan, A.

1975-01-01

Phase relations in the liquidus temperature region of the system 'FeO'-Al2O3-TiO2 in contact with metallic iron, at a total pressure below 1 atm, have been determined by the quenching technique. Four invariant points have been located, with phase assemblages and temperatures as follows; wuestite, ulvoespinel, nercynite and liquid, 1306 C; ulvoespinel, ilmenite, ferropseudobrookite and liquid, 1340 C; ulvoespinel, hercynite, ferropseudobrookite and liquid, 1367 C; hercynite, ferropseudobrookite, corundum and liquid, 1465 C. The data obtained confirm the presence of a miscibility gap between titanate and aluminate spinels, and provide quantitative data for the effect of Al2O3 on mutual stability relations among spinel, ilmenite, and ferropseudobrookite phases in the presence of liquid at high temperatures and strongly reducing conditions. It is shown that Al2O3 has a strong stabilizing effect on the phase assemblage ferropseudobrookite and spinel relative to ilmenite.

24 CFR 200.926e - Supplemental information for use with the CABO One and Two Family Dwelling Code.

Code of Federal Regulations, 2014 CFR

2014-04-01

... shall be in accordance with section 7 of ASCE 7-88. (c) Wind pressures. The minimum Design Wind Pressures (net pressures) set forth below apply to areas designated as experiencing basic wind speeds up to and including 80 mph, as shown in ASCE 7-88, Figure 1, Basic Wind Speed Map. These pressures also...

24 CFR 200.926e - Supplemental information for use with the CABO One and Two Family Dwelling Code.

Code of Federal Regulations, 2013 CFR

2013-04-01

... shall be in accordance with section 7 of ASCE 7-88. (c) Wind pressures. The minimum Design Wind Pressures (net pressures) set forth below apply to areas designated as experiencing basic wind speeds up to and including 80 mph, as shown in ASCE 7-88, Figure 1, Basic Wind Speed Map. These pressures also...

24 CFR 200.926e - Supplemental information for use with the CABO One and Two Family Dwelling Code.

Code of Federal Regulations, 2012 CFR

2012-04-01

... shall be in accordance with section 7 of ASCE 7-88. (c) Wind pressures. The minimum Design Wind Pressures (net pressures) set forth below apply to areas designated as experiencing basic wind speeds up to and including 80 mph, as shown in ASCE 7-88, Figure 1, Basic Wind Speed Map. These pressures also...

24 CFR 200.926e - Supplemental information for use with the CABO One and Two Family Dwelling Code.

Code of Federal Regulations, 2010 CFR

2010-04-01

... shall be in accordance with section 7 of ASCE 7-88. (c) Wind pressures. The minimum Design Wind Pressures (net pressures) set forth below apply to areas designated as experiencing basic wind speeds up to and including 80 mph, as shown in ASCE 7-88, Figure 1, Basic Wind Speed Map. These pressures also...

24 CFR 200.926e - Supplemental information for use with the CABO One and Two Family Dwelling Code.

Code of Federal Regulations, 2011 CFR

2011-04-01

... shall be in accordance with section 7 of ASCE 7-88. (c) Wind pressures. The minimum Design Wind Pressures (net pressures) set forth below apply to areas designated as experiencing basic wind speeds up to and including 80 mph, as shown in ASCE 7-88, Figure 1, Basic Wind Speed Map. These pressures also...

High methane natural gas/air explosion characteristics in confined vessel.

PubMed

Tang, Chenglong; Zhang, Shuang; Si, Zhanbo; Huang, Zuohua; Zhang, Kongming; Jin, Zebing

2014-08-15

The explosion characteristics of high methane fraction natural gas were investigated in a constant volume combustion vessel at different initial conditions. Results show that with the increase of initial pressure, the peak explosion pressure, the maximum rate of pressure rise increase due to a higher amount (mass) of flammable mixture, which delivers an increased amount of heat. The increased total flame duration and flame development time result as a consequence of the higher amount of flammable mixture. With the increase of the initial temperature, the peak explosion pressures decrease, but the pressure increase during combustion is accelerated, which indicates a faster flame speed and heat release rate. The maximum value of the explosion pressure, the maximum rate of pressure rise, the minimum total combustion duration and the minimum flame development time is observed when the equivalence ratio of the mixture is 1.1. Additionally, for higher methane fraction natural gas, the explosion pressure and the maximum rate of pressure rise are slightly decreased, while the combustion duration is postponed. The combustion phasing is empirically correlated with the experimental parameters with good fitting performance. Furthermore, the addition of dilute gas significantly reduces the explosion pressure, the maximum rate of pressure rise and postpones the flame development and this flame retarding effect of carbon dioxide is stronger than that of nitrogen. Copyright © 2014 Elsevier B.V. All rights reserved.

40 CFR 65.84 - Operating requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

...-tight means that the pressure in a truck or railcar tank will not drop more than 750 pascals (0.11 pound per square inch) within 5 minutes after it is pressurized to a minimum of 4,500 pascals (0.65 pound...

BOREAS AES READAC Surface Meteorological Data

NASA Technical Reports Server (NTRS)

Atkinson, G. Barrie; Funk, Barry; Hall, Forrest G. (Editor); Knapp, David E. (Editor)

2000-01-01

Canadian AES personnel collected and processed data related to surface atmospheric meteorological conditions over the BOREAS region. This data set contains 15-minute meteorological data from one READAC meteorology station in Hudson Bay, Saskatchewan. Parameters include day, time, type of report, sky condition, visibility, mean sea level pressure, temperature, dewpoint, wind, altimeter, opacity, minimum and maximum visibility, station pressure, minimum and maximum air temperature, a wind group, precipitation, and precipitation in the last hour. The data were collected non-continuously from 24-May-1994 to 20-Sep-1994. The data are provided in tabular ASCII files, and are classified as AFM-Staff data.

Phase behavior of metastable liquid silicon at negative pressure: Ab initio molecular dynamics

NASA Astrophysics Data System (ADS)

Zhao, G.; Yu, Y. J.; Yan, J. L.; Ding, M. C.; Zhao, X. G.; Wang, H. Y.

2016-04-01

Extensive first-principle molecular dynamics simulations are performed to study the phase behavior of metastable liquid Si at negative pressure. Our results show that the high-density liquid (HDL) and HDL-vapor spinodals indeed form a continuous reentrant curve and the liquid-liquid critical point seems to just coincide with its minimum. The line of density maxima also has a strong tendency to pass through this minimum. The phase behaviour of metastable liquid Si therefore tends to be a critical-point-free scenario rather than a second-critical-point one based on SW potential.

Effect of geometry on hydrodynamic film thickness

NASA Technical Reports Server (NTRS)

Brewe, D. E.; Hamrock, B. J.; Taylor, C. M.

1978-01-01

The influence of geometry on the isothermal hydrodynamic film separating two rigid solids was investigated. Pressure-viscosity effects were not considered. The minimum film thickness is derived for fully flooded conjunctions by using the Reynolds conditions. It was found that the minimum film thickness had the same speed, viscosity, and load dependence as Kapitza's classical solution. However, the incorporation of Reynolds boundary conditions resulted in an additional geometry effect. Solutions using the parabolic film approximation are compared with those using the exact expression for the film in the analysis. Contour plots are shown that indicate in detail the pressure developed between the solids.

Effect of geometry on hydrodynamic film thickness

NASA Technical Reports Server (NTRS)

Brewe, D. E.; Hamrock, B. J.; Taylor, C. M.

1978-01-01

The influence of geometry on the isothermal hydrodynamic film separating two rigid solids was investigated. Pressure-viscosity effects were not considered. The minimum film thickness is derived for fully flooded conjunctions by using the Reynolds boundary conditions. It was found that the minimum film thickness had the same speed, viscosity, and load dependence as Kapitza's classical solution. However, the incorporation of Reynolds boundary conditions resulted in an additional geometry effect. Solutions using the parabolic film approximation are compared with those using the exact expression for the film in the analysis. Contour plots are shown that indicate in detail the pressure developed between the solids.

A novel cell weighing method based on the minimum immobilization pressure for biological applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Qili; Institute of Robotics and Automatic Information System, Nankai University, Tianjin 300071; Shirinzadeh, Bijan

2015-07-28

A novel weighing method for cells with spherical and other regular shapes is proposed in this paper. In this method, the relationship between the cell mass and the minimum aspiration pressure to immobilize the cell (referred to as minimum immobilization pressure) is derived for the first time according to static theory. Based on this relationship, a robotic cell weighing process is established using a traditional micro-injection system. Experimental results on porcine oocytes demonstrate that the proposed method is able to weigh cells at an average speed of 16.3 s/cell and with a success rate of more than 90%. The derived cellmore » mass and density are in accordance with those reported in other published results. The experimental results also demonstrated that this method is able to detect less than 1% variation of the porcine oocyte mass quantitatively. It can be conducted by a pair of traditional micropipettes and a commercial pneumatic micro-injection system, and is expected to perform robotic operation on batch cells. At present, the minimum resolution of the proposed method for measuring the cell mass can be 1.25 × 10{sup −15 }kg. Above advantages make it very appropriate for quantifying the amount of the materials injected into or moved out of the cells in the biological applications, such as nuclear enucleations and embryo microinjections.« less

Optimal glottal configuration for ease of phonation.

PubMed

Lucero, J C

1998-06-01

Recent experimental studies have shown the existence of optimal values of the glottal width and convergence angle, at which the phonation threshold pressure is minimum. These results indicate the existence of an optimal glottal configuration for ease of phonation, not predicted by the previous theory. In this paper, the origin of the optimal configuration is investigated using a low dimensional mathematical model of the vocal fold. Two phenomena of glottal aerodynamics are examined: pressure losses due to air viscosity, and air flow separation from a divergent glottis. The optimal glottal configuration seems to be a consequence of the combined effect of both factors. The results agree with the experimental data, showing that the phonation threshold pressure is minimum when the vocal folds are slightly separated in a near rectangular glottis.

Design of MSR primary circuit with minimum pressure losses

NASA Astrophysics Data System (ADS)

Noga, Tomáš; Žitek, Pavel; Valenta, Václav

This article describes a design of a MSR primary circuit with minimum pressure losses. It includes a brief description of this type of a reactor and its integral layout, properties, purpose, etc. The objective of this paper is to define problems of pressure losses calculation and to design a proper device for a primary circuit of MSR reactor, including its basic dimensions. Thanks to this, it can become an initial project for a construction of a real piece of work. This is the main contribution of the carried out study. Of course, this article is not a detailed solution, but it points out facts and problems, which future designers may have to face. The further step of our work will be a reconstruction of the current experiment for a two-stage flowing.

46 CFR 38.05-2 - Design and construction of cargo tanks-general-TB/ALL.

Code of Federal Regulations, 2010 CFR

2010-10-01

... a pressure equal to the setting of the relief valve. (b) The service temperature is the minimum...=Service temperature. t w=Boiling temperature of gas at normal working pressure of tank but not higher than +32 °F. t b=Boiling temperature of gas at atmospheric pressure. (c) Heat transmission studies, where...

46 CFR 38.05-2 - Design and construction of cargo tanks-general-TB/ALL.

Code of Federal Regulations, 2011 CFR

2011-10-01

... a pressure equal to the setting of the relief valve. (b) The service temperature is the minimum...=Service temperature. t w=Boiling temperature of gas at normal working pressure of tank but not higher than +32 °F. t b=Boiling temperature of gas at atmospheric pressure. (c) Heat transmission studies, where...

49 CFR 178.56 - Specification 4AA480 welded steel cylinders.

Code of Federal Regulations, 2011 CFR

2011-10-01

...) Type, size, and service pressure. A DOT 4AA480 cylinder is a welded steel cylinder having a water capacity (nominal) not over 1,000 pounds water capacity and a service pressure of 480 psig. Closures welded... that the calculated wall stress at the minimum test pressure (in paragraph (i) of this section) may not...

49 CFR 178.68 - Specification 4E welded aluminum cylinders.

Code of Federal Regulations, 2011 CFR

2011-10-01

...) Where: S = wall stress in psi; P = minimum test pressure prescribed for water jacket test; D = outside... and service pressure. A DOT 4E cylinder is a welded aluminum cylinder with a water capacity (nominal... stress at twice service pressure may not exceed the lesser value of either of the following: (i) 20,000...

77 FR 19069 - Airworthiness Directives; Goodrich Evacuation Systems Approved Under Technical Standard Order...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-30

... seal and allowed the pressure in certain slides/ rafts to fall below the minimum raft mode pressure for the unit. We are issuing this AD to prevent loss of pressure in the escape slides/rafts after an emergency evacuation, which could result in inadequate buoyancy to support the raft's passenger capacity...

14 CFR 23.1443 - Minimum mass flow of supplemental oxygen.

Code of Federal Regulations, 2011 CFR

2011-01-01

... displaced by water vapor pressure when the breathed air becomes saturated with water vapor at 37 °C). (2) STPD means Standard, Temperature, and Pressure, Dry (which is, 0 °C at 760 mm. Hg with no water vapor...

14 CFR 23.1443 - Minimum mass flow of supplemental oxygen.

Code of Federal Regulations, 2013 CFR

2013-01-01

... displaced by water vapor pressure when the breathed air becomes saturated with water vapor at 37 °C). (2) STPD means Standard, Temperature, and Pressure, Dry (which is 0 °C at 760mm Hg with no water vapor...

14 CFR 23.1443 - Minimum mass flow of supplemental oxygen.

Code of Federal Regulations, 2014 CFR

2014-01-01

... displaced by water vapor pressure when the breathed air becomes saturated with water vapor at 37 °C). (2) STPD means Standard, Temperature, and Pressure, Dry (which is 0 °C at 760mm Hg with no water vapor...

Quartz Solubility and Thermodynamics Above the Upper Critical End Point

NASA Astrophysics Data System (ADS)

Hunt, J. D.; Manning, C. E.

2010-12-01

Silica is among the most abundant solutes in crustal and mantle fluids, especially at conditions nearing the upper critical end point of the SiO2-H2O system (~10 kbar, 1080 °C). However, the solubility of silica is not well determined at higher pressures. In addition, the thermodynamic mixing relations of the supercritical SiO2-H2O system are poorly known. We made new measurements on quartz solubility in H2O at 15 and 20 kbar at 900-1100 °C. At SiO2 mole fraction below 0.1, solubility was determined by weight loss of single crystals equilibrated with H2O. At higher SiO2 concentrations, solubility was determined by bracketing the presence of absence of quartz in charges with known bulk SiO2 concentration. The measured solubilities imply that there is a solubility minimum above 1050 °C between 10 and 20 kbar. Quartz solubility measurements from Manning (1994), Newton and Manning (2003; 2008), Nakamura (1975) and this study were fitted to a modified sub-regular solution model. A term representing the Gibbs free energy (ΔGr) of the reaction 1/2 H2O + 1/2 O2- = OH- (the depolymerization reaction that occurs when silica is dissolved in water) was added to the free energy of mixing parameterization. Thirteen independent parameters describe the T and P variation of the weak sub-regular interaction terms (Ws and Wh) and the strong interaction term (ΔGr). Nine of the parameters are linear in T and P, and the other four are quadratic: Ws and ΔGr vary with P2, and ΔGr also varies with T2 and PT. The average error between the data and the model is 5%. Because the Gibbs free energy change of the depolymerization reaction is included in the fit, the model predicts an average state of aqueous silica polymerization of solutions in equilibrium with quartz at P between 10 and 20 kbar and T above 500 °C. The results also highlight what can be inferred from the steep hydrothermal melting curve of quartz - that while pressure does determine whether the system is subcritical or supercritical, it has a comparatively minor effect on the transition from an H2O-rich fluid to an SiO2-rich fluid. Whether due to melting or complete miscibility, the composition of a fluid in equilibrium with quartz increases dramatically between 900 and 1100 °C.

The effect of pressure on the hydration structure around hydrophobic solute: A molecular dynamics simulation study

NASA Astrophysics Data System (ADS)

Sarma, Rahul; Paul, Sandip

2012-03-01

Molecular dynamics simulations are performed to study the effects of pressure on the hydrophobic interactions between neopentane molecules immersed in water. Simulations are carried out for five different pressure values ranging from 1 atm to 8000 atm. From potential of mean force calculations, we find that with enhancement of pressure, there is decrease in the well depth of contact minimum (CM) and the relative stability of solvent separated minimum over CM increases. Lower clustering of neopentane at high pressure is also observed in association constant and cluster-structure analysis. Selected site-site radial distribution functions suggest efficient packing of water molecules around neopentane molecules at elevated pressure. The orientational profile calculations of water molecules show that the orientation of water molecules in the vicinity of solute molecule is anisotropic and this distribution becomes flatter as we move away from the solute. Increasing pressure slightly changes the water distribution. Our hydrogen bond properties and dynamics calculations reveal pressure-induced formation of more and more number of water molecules with five and four hydrogen bond at the expense of breaking of two and three hydrogen bonded water molecules. We also find lowering of water-water continuous hydrogen bond lifetime on application of pressure. Implication of these results for relative dispersion of hydrophobic molecules at high pressure are discussed.

NASA Requirements for Ground-Based Pressure Vessels and Pressurized Systems (PVS). Revision C

NASA Technical Reports Server (NTRS)

Greulich, Owen Rudolf

2017-01-01

The purpose of this document is to ensure the structural integrity of PVS through implementation of a minimum set of requirements for ground-based PVS in accordance with this document, NASA Policy Directive (NPD) 8710.5, NASA Safety Policy for Pressure Vessels and Pressurized Systems, NASA Procedural Requirements (NPR) 8715.3, NASA General Safety Program Requirements, applicable Federal Regulations, and national consensus codes and standards (NCS).

Growth and analysis of gallium arsenide-gallium antimonide single and two-phase nanoparticles

NASA Astrophysics Data System (ADS)

Schamp, Crispin T.

When evaluating the path of phase transformations in systems with nanoscopic dimensions one often relies on bulk phase diagrams for guidance because of the lack of phase diagrams that show the effect of particle size. The GaAs-GaSb pseudo-binary alloy is chosen for study to gain insight into the size dependence of solid-solubility in a two-phase system. To this end, a study is performed using independent laser ablation of high purity targets of GaAs and GaSb. The resultant samples are analyzed by transmission electron microscopy. Experimental results indicate that GaAs-GaSb nanoparticles have been formed with compositions that lie within the miscibility gap of bulk GaAs-GaSb. An unusual nanoparticle morpohology resembling the appearance of ice cream cones has been observed in single component experiments. These particles are composed of a spherical cap of Ga in contact with a crystalline cone of either GaAs or GaSb. The cones take the projected 2-D shape of a triangle or a faceted gem. The liquid Ga is found to consistently be of spherical shape and wets to the widest corners of the cone, suggesting an energy minimum exists at that wetting condition. To explore this observation a liquid sphere is modeled as being penetrated by a solid gem. The surface energies of the solid and liquid, and interfacial energy are summed as a function of penetration depth, with the sum showing a cusped minimum at the penetration depth corresponding to the waist of the gem. The angle of contact of the liquid wetting the cone is also calculated, and Young's contact angle is found to occur when the derivative of the total energy with respect to penetration depth is zero, which can be a maximum or a minimum depending on the geometrical details. The spill-over of the meniscus across the gem corners is found to be energetically favorable when the contact angle achieves the value of the equilibrium angle; otherwise the meniscus is pinned at the corners.

Dome of magnetic order inside the nematic phase of sulfur-substituted FeSe under pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiang, Li; Kaluarachchi, Udhara; Bohmer, Anna

2017-07-18

The pressure dependence of the structural, magnetic, and superconducting transitions and of the superconducting upper critical field were studied in sulfur-substituted Fe ( Se 1 - x S x ) . We performed resistance measurements on single crystals with three substitution levels ( x = 0.043 , 0.096, 0.12) under hydrostatic pressures up to 1.8 GPa and in magnetic fields up to 9 T and were compared to data on pure FeSe. Our results illustrate the effects of chemical and physical pressure on Fe ( Se 1 - x S x ). Furthermore, on increasing sulfur content, magnetic order inmore » the low-pressure range is strongly suppressed to a small domelike region in the phase diagrams. But, T s is much less suppressed by sulfur substitution, and T c of Fe ( Se 1 - x S x ) exhibits similar nonmonotonic pressure dependence with a local maximum and a local minimum present in the low-pressure range for all x . The local maximum in T c coincides with the emergence of the magnetic order above T c . At this pressure the slope of the upper critical field decreases abruptly, which may indicate a Fermi-surface reconstruction. The minimum of T c correlates with a broad maximum of the upper critical field slope normalized by T c .« less

40 CFR 86.1232-96 - Vehicle preconditioning.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Emission Test Procedures for New Gasoline-Fueled, Natural Gas-Fueled, Liquefied Petroleum Gas-Fueled and... liquefied petroleum gas-fueled vehicles. Prior draining of the fuel tanks is not called for if the fuel in... be filled to a minimum of 75% of service pressure for natural gas-fueled vehicles or a minimum of 75...

Factors determining the level and changes in intra-articular pressure in the knee joint of the dog.

PubMed Central

Nade, S; Newbold, P J

1983-01-01

Intra-articular pressure levels were determined for joint positions throughout the normal physiological range of movement of dogs' knee joints. Change in joint position resulted in change in intra-articular pressure. It was demonstrated that intra-articular pressure is highest with the joint in the fully flexed position. Minimum pressure was recorded at a position between 80 degrees and 120 degrees. Minimum pressures were usually subatmospheric. The rate of change of joint position affected intra-articular pressure. The relationship of intra-articular pressure and joint position before and after full flexion demonstrated a hysteresis effect; the pressures were lower than for the same joint position before flexion. Maintenance of the joint in the fully flexed position for increasing periods of time between repeated movement cycles resulted in a similar reduction, of constant magnitude, in pressure between joint positions before and after each period of flexion. However, there was also a progressive decrease in pressure for all joint angles over the total number of movement cycles. There is a contribution to intra-articular pressure of joint capsular compliance and fluid movement into and out of the joint (both of which are time-dependent). The recording of intra-articular pressure in conscious, upright dogs revealed similar pressure levels to those measured in anaesthetized supine dogs. The major determinants of intra-articular pressure in normal dog knee joints include joint size, synovial fluid volume, position of joint, peri-articular tissue and joint anatomy, membrane permeability, capsular compliance, and movement of fluid into and out of the joint. Images Fig. 1 PMID:6875957

Multimodal pressure-flow method to assess dynamics of cerebral autoregulation in stroke and hypertension

PubMed Central

Novak, Vera; Yang, Albert CC; Lepicovsky, Lukas; Goldberger, Ary L; Lipsitz, Lewis A; Peng, Chung-Kang

2004-01-01

Background This study evaluated the effects of stroke on regulation of cerebral blood flow in response to fluctuations in systemic blood pressure (BP). The autoregulatory dynamics are difficult to assess because of the nonstationarity and nonlinearity of the component signals. Methods We studied 15 normotensive, 20 hypertensive and 15 minor stroke subjects (48.0 ± 1.3 years). BP and blood flow velocities (BFV) from middle cerebral arteries (MCA) were measured during the Valsalva maneuver (VM) using transcranial Doppler ultrasound. Results A new technique, multimodal pressure-flow analysis (MMPF), was implemented to analyze these short, nonstationary signals. MMPF analysis decomposes complex BP and BFV signals into multiple empirical modes, representing their instantaneous frequency-amplitude modulation. The empirical mode corresponding to the VM BP profile was used to construct the continuous phase diagram and to identify the minimum and maximum values from the residual BP (BPR) and BFV (BFVR) signals. The BP-BFV phase shift was calculated as the difference between the phase corresponding to the BPR and BFVR minimum (maximum) values. BP-BFV phase shifts were significantly different between groups. In the normotensive group, the BFVR minimum and maximum preceded the BPR minimum and maximum, respectively, leading to large positive values of BP-BFV shifts. Conclusion In the stroke and hypertensive groups, the resulting BP-BFV phase shift was significantly smaller compared to the normotensive group. A standard autoregulation index did not differentiate the groups. The MMPF method enables evaluation of autoregulatory dynamics based on instantaneous BP-BFV phase analysis. Regulation of BP-BFV dynamics is altered with hypertension and after stroke, rendering blood flow dependent on blood pressure. PMID:15504235

Stabilization of a finite slice in miscible displacement in homogeneous porous media

NASA Astrophysics Data System (ADS)

Pramanik, Satyajit; Mishra, Manoranjan

2016-11-01

We numerically studied the miscible displacement of a finite slice of variable viscosity and density. The stability of the finite slice depends on different flow parameters, such as displacement velocity U, mobility ratio R , and the density contrast. Series of numerical simulations corresponding to different ordered pair (R, U) in the parameter space, and a given density contrast reveal six different instability regions. We have shown that independent of the width of the slice, there always exists a region of stable displacement, and below a critical value of the slice width, this stable region increases with decreasing slice width. Further we observe that the viscous fingering (buoyancy-induced instability) at the upper interface induces buoyancy-induced instability (viscous fingering) at the lower interface. Besides the fundamental fluid dynamics understanding, our results can be helpful to model CO2 sequestration and chromatographic separation.

Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR FT-IR) Mapping Coupled with Multivariate Curve Resolution (MCR) for Studying the Miscibility of Chlorobutyl Rubber/Polyamide-12 Blends.

PubMed

Tang, Yongjiao; Jing, Nan; Zhang, Pudun

2015-11-01

A series of chlorobutyl rubber/polyamide-12 (CIIR/PA-12) blends compatibilized by different amounts of maleic anhydride (MAH) grafted polypropylene (PP-g-MAH) were investigated by attenuated total reflection Fourier transform infrared spectroscopy (ATR FT-IR) mapping. Multivariate curve resolution (MCR) was used to process the FT-IR images. Both the spectra of pure components in the blends and their concentration distributions in a micro-region were acquired. Our results demonstrated that the blend with 15 parts per hundred rubber PP-g-MAH showed the best miscibility. An amide interphase and an imide interphase were inferred by analyzing the spectra of MCR component 3 of the blends with and without PP-g-MAH, respectively. Correspondingly, two different compatibilizing mechanisms were proposed for these blends.

Miscible viscous fingering involving production of gel by chemical reactions

NASA Astrophysics Data System (ADS)

Nagatsu, Yuichiro; Hoshino, Kenichi

2015-11-01

We have experimentally investigated miscible viscous fingering with chemical reactions producing gel. Here, two systems were employed. In one system, sodium polyacrylate (SPA) solution and aluminum ion (Al3 +) solution were used as the more and less viscous liquids, respectively. In another system, SPA solution and ferric ion (Fe3 +) solution were used as the more and less viscous liquids, respectively. In the case of Al3 +, displacement efficiency was smaller than that in the non-reactive case, whereas in the case of Fe3 +, the displacement efficiency was larger. We consider that the difference in change of the patterns in the two systems will be caused by the difference in the properties of the gels. Therefore, we have measured the rheological properties of the gels by means of a rheometer. We discuss relationship between the VF patterns and the rheological measurement.

Density profiles around A+B→C reaction-diffusion fronts in partially miscible systems: A general classification.

PubMed

Loodts, V; Trevelyan, P M J; Rongy, L; De Wit, A

2016-10-01

Various spatial density profiles can develop in partially miscible stratifications when a phase A dissolves with a finite solubility into a host phase containing a dissolved reactant B. We investigate theoretically the impact of an A+B→C reaction on such density profiles in the host phase and classify them in a parameter space spanned by the ratios of relative contributions to density and diffusion coefficients of the chemical species. While the density profile is either monotonically increasing or decreasing in the nonreactive case, reactions combined with differential diffusivity can create eight different types of density profiles featuring up to two extrema in density, at the reaction front or below it. We use this framework to predict various possible hydrodynamic instability scenarios inducing buoyancy-driven convection around such reaction fronts when they propagate parallel to the gravity field.

Internal density waves of shock type induced by chemoconvection in miscible reacting liquids

NASA Astrophysics Data System (ADS)

Bratsun, D. A.

2017-10-01

A theoretical explanation of the phenomenon of spontaneous emergence of density waves experimentally observed recently in bilayered systems of miscible liquids placed in a narrow vertical gap of the Hele-Shaw cell in the gravitational field is provided. Upper and lower layers represent aqueous solutions of acids and bases, respectively, whose contact leads to the beginning of a neutralization reaction. The process is accompanied by a strong dependence of the reagent's diffusion coefficients on their concentrations, giving rise to the generation of local density pockets, in which convection develops. The cavities collapse under certain conditions, causing a density jump, which moves faster than typical perturbations in a medium and takes the form of a shock wave. A mathematical model of the phenomenon is proposed, which can be formally reduced to equations of motion of a compressible gas under certain assumptions. Numerical calculations are given and compared with the experimental data.

Electro-optical properties of low viscosity driven holographic polymer dispersed liquid crystals

NASA Astrophysics Data System (ADS)

Moon, K. R.; Bae, S. Y.; Kim, B. K.

2015-04-01

Relative diffraction efficiency (RDE), operating voltage, and response times are most important performance characteristics of holographic polymer dispersed liquid crystals (HPDLC). Two types of triallyl isocyanurate (TI) having different structures were incorporated into the conventional transmission grating of HPDLC. Premix viscosity decreased by 13-18% with up to 3% TI, beyond which it increased. TI eliminated induction period and augmented initial grating formation rate at all contents. Saturation RDE increased over 200% while threshold voltage and rise time decreased to about half and 2/3, respectively up to 3% TI, beyond which the tendencies were reversed. Among the two TIs, low viscosity monomer (TA) showed high RDE, while high miscibility monomer (TE) low characteristic voltages and short response times. It is concluded that grating formation is largely favored by low viscosity, while interface tensions and electro-optical performances by miscibility at similar viscosities.

Miscibility and crystallization behavior of poly (3-hydroxybutyrate) and poly (ethylene glycol) blends studied by positron annihilation spectroscopy

NASA Astrophysics Data System (ADS)

Abdel-Hady, E. E.; Abdel-Hamed, M. O.; Hammam, A. M.

2011-01-01

Positron annihilation Lifetime (PAL) spectroscopy has been used to study the effect of PEG concentrations on the free volume properties of PHB. The data revealed that the ortho-positronium (o-Ps) lifetime τPs increases with 20% increase in concentration, decrease as the concentration increases to 40%, then rapid increase at 50% concentration of PEG. The o-Ps intensity, I3, shows a linear dependence as the concentration increases with a discontinuity at 20% concentration of PEG. Furthermore, the results presented and discussed in this work show that the PHB and PEG are miscible up to 40% of PEG but greater than 40%, the blend is immiscible. In addition, the mechanical properties of PHB are well improved by the addition of PEG with a low concentration up to 20%, while at higher concentration the blend becomes waxy.

Confinement effects on the miscibility of block copolymer blends.

PubMed

Spencer, Russell K W; Matsen, Mark W

2016-04-01

Thin films of long and short symmetric AB diblock copolymers are examined using self-consistent field theory (SCFT). We focus on hard confining walls with a preference for the A component, such that the lamellar domains orient parallel to the film with an even number ν of monolayers. For neat melts, confinement causes the lamellar period, D, to deviate from its bulk value, Db, in order to be commensurate with the film thickness, i.e., L = νD/2. For blends, however, the melt also has the option of macrophase separating into ν(l) large and ν((s)) small monolayers so as to provide a better fit, where L = ν(l)D(l)/2 + ν(s)D((s))/2. In addition to performing full SCFT calculations of the entire film, we develop a semi-analytical calculation for the coexistence of thick and thin monolayers that helps explain the complicated interplay between miscibility and commensurability.

Polymer collapse in miscible good solvents is a generic phenomenon driven by preferential adsorption

PubMed Central

Mukherji, Debashish; Marques, Carlos M.; Kremer, Kurt

2014-01-01

Water and alcohol, such as methanol or ethanol, are miscible and, individually, good solvents for poly(N-isopropylacrylamide) (PNIPAm), but this polymer precipitates in water–alcohol mixtures. The intriguing behaviour of solvent mixtures that cannot dissolve a given polymer or a given protein, while the same macromolecule dissolves well in each of the cosolvents, is called cononsolvency. It is a widespread phenomenon, relevant for many formulation steps in the physicochemical and pharmaceutical industry, that is usually explained by invoking specific chemical details of the mixtures: as such, it has so far eluded any generic explanation. Here, by using a combination of simulations and theory, we present a simple and universal treatment that requires only the preferential interaction of one of the cosolvents with the polymer. The results show striking quantitative agreement with experiments and chemically specific simulations, opening a new perspective towards an operational understanding of macromolecular solubility. PMID:25216245

Buoyant miscible displacement flow of shear-thinning fluids: Experiments and Simulations

NASA Astrophysics Data System (ADS)

Ale Etrati Khosroshahi, Seyed Ali; Frigaard, Ian

2017-11-01

We study displacement flow of two miscible fluids with density and viscosity contrast in an inclined pipe. Our focus is mainly on displacements where transverse mixing is not significant and thus a two-layer, stratified flow develops. Our experiments are carried out in a long pipe, covering a wide range of flow-rates, inclination angles and viscosity ratios. Density and viscosity contrasts are achieved by adding Glycerol and Xanthan gum to water, respectively. At each angle, flow rate and viscosity ratio are varied and density contrast is fixed. We identify and map different flow regimes, instabilities and front dynamics based on Fr , Re / Frcosβ and viscosity ratio m. The problem is also studied numerically to get a better insight into the flow structure and shear-thinning effects. Numerical simulations are completed using OpenFOAM in both pipe and channel geometries and are compared against the experiments. Schlumberger, NSERC.

Post waterflood CO{sub 2} miscible flood in light oil, fluvial-dominated deltaic reservoir. FY 1993 annual report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, D.W.

1995-03-01

The project is a Class 1 DOE-sponsored field demonstration project of a CO{sub 2} miscible flood project at the Port Neches Field in Orange County, Texas. The project will determine the recovery efficiency of CO{sub 2} flooding a waterflooded and a partial waterdrive sandstone reservoir at a depth of 5,800. The project will also evaluate the use of a horizontal CO{sub 2} injection well placed at the original oil-water contact of the waterflooded reservoir. A PC-based reservoir screening model will be developed by Texaco`s research lab in Houston and Louisiana State University will assist in the development of a databasemore » of fluvial-dominated deltaic reservoirs where CO{sub 2} flooding may be applicable. This technology will be transferred throughout the oil industry through a series of technical papers and industry open forums.« less

Effect of critical molecular weight of PEO in epoxy/EPO blends as characterized by advanced DSC and solid-state NMR

NASA Astrophysics Data System (ADS)

Wang, Xiaoliang; Lu, Shoudong; Sun, Pingchuan; Xue, Gi

2013-03-01

The differential scanning calorimetry (DSC) and solid state NMR have been used to systematically study the length scale of the miscibility and local dynamics of the epoxy resin/poly(ethylene oxide) (ER/PEO) blends with different PEO molecular weight. By DSC, we found that the diffusion behavior of PEO with different Mw is an important factor in controlling these behaviors upon curing. We further employed two-dimensional 13C-{1H}PISEMA NMR experiment to elucidate the possible weak interaction and detailed local dynamics in ER/PEO blends. The CH2O group of PEO forms hydrogen bond with hydroxyl proton of cured-ER ether group, and its local dynamics frozen by such interaction. Our finding indicates that molecular weight (Mw) of PEO is a crucial factor in controlling the miscibility, chain dynamics and hydrogen bonding interaction in these blends.

Development of a Polarizable Force Field for Molecular Dynamics Simulations of Poly (Ethylene Oxide) in Aqueous Solution.

PubMed

Starovoytov, Oleg N; Borodin, Oleg; Bedrov, Dmitry; Smith, Grant D

2011-06-14

We have developed a quantum chemistry-based polarizable potential for poly(ethylene oxide) (PEO) in aqueous solution based on the APPLE&P polarizable ether and the SWM4-DP polarizable water models. Ether-water interactions were parametrized to reproduce the binding energy of water with 1,2-dimethoxyethane (DME) determined from high-level quantum chemistry calculations. Simulations of DME-water and PEO-water solutions at room temperature using the new polarizable potentials yielded thermodynamic properties in good agreement with experimental results. The predicted miscibility of PEO and water as a function of the temperature was found to be strongly correlated with the predicted free energy of solvation of DME. The developed nonbonded force field parameters were found to be transferrable to poly(propylene oxide) (PPO), as confirmed by capturing, at least qualitatively, the miscibility of PPO in water as a function of the molecular weight.

Miscible displacement of a non-Newtonian fluid in a capillary tube

NASA Astrophysics Data System (ADS)

Soori, Tejaswi; Ward, Thomas

2017-11-01

This talk focuses on experiments conducted to further our understanding of how to displace an aqueous polymer within a capillary tube (diameter < 1 mm) using a Newtonian fluid. Estimates of the residual film were measured as a function of Reynolds (Re), viscous Atwood (At) and Péclet (Pé) numbers. Aqueous polymers were prepared by mixing ϕ = 0.01-0.1% (wt/wt) Carboxymethyl Cellulose (CMC) in water. We measure the shear viscosity of the aqueous polymer over a broad range of shear rates and fit the data obtained to the Carreau fluid parameters. Separately we measure the average bulk diffusion coefficient of the aqueous polymer and water in water and aqueous polymer phases respectively. Previous studies on the immiscible displacement of polymers have shown residual film thickness to be dependent on the tube diameter. We will investigate if this is true when the two fluids are miscible in nature. American Chemical Society Petroleum Research Fund.

Oscillatory interfacial instability between miscible fluids

NASA Astrophysics Data System (ADS)

Shevtsova, Valentina; Gaponenko, Yuri; Mialdun, Aliaksandr; Torregrosa, Marita; Yasnou, Viktar

Interfacial instabilities occurring between two fluids are of fundamental interest in fluid dynamics, biological systems and engineering applications such as liquid storage, solvent extraction, oil recovery and mixing. Horizontal vibrations applied to stratified layers of immiscible liquids may generate spatially periodic waving of the interface, stationary in the reference frame of the vibrated cell, referred to as a "frozen wave". We present experimental evidence that frozen wave instability exists between two ordinary miscible liquids of similar densities and viscosities. At the experiments and at the numerical model, two superimposed layers of ordinary liquids, water-alcohol of different concentrations, are placed in a closed cavity in a gravitationally stable configuration. The density and viscosity of these fluids are somewhat similar. Similar to the immiscible fluids this instability has a threshold. When the value of forcing is increased the amplitudes of perturbations grow continuously displaying a saw-tooth structure. The decrease of gravity drastically changes the structure of frozen waves.

Ground-State Wave Function with Interactions between Different Species in M-Component Miscible Bose-Einstein Condensates

NASA Astrophysics Data System (ADS)

Kohno, Wataru; Kirikoshi, Akimitsu; Kita, Takafumi

2018-03-01

We construct a variational ground-state wave function of weakly interacting M-component Bose-Einstein condensates beyond the mean-field theory by incorporating the dynamical 3/2-body processes, where one of the two colliding particles drops into the condensate and vice versa. Our numerical results with various masses and particle numbers show that the 3/2-body processes between different particles make finite contributions to lowering the ground-state energy, implying that many-body correlation effects between different particles are essential even in the weak-coupling regime of the Bose-Einstein condensates. We also consider the stability condition for 2-component miscible states using the new ground-state wave function. Through this calculation, we obtain the relation UAB2/UAAUBB < 1 + α , where Uij is the effective contact potential between particles i and j and α is the correction, which originates from the 3/2- and 2-body processes.

Double-cross hydrostatic pressure sample injection for chip CE: variable sample plug volume and minimum number of electrodes.

PubMed

Luo, Yong; Wu, Dapeng; Zeng, Shaojiang; Gai, Hongwei; Long, Zhicheng; Shen, Zheng; Dai, Zhongpeng; Qin, Jianhua; Lin, Bingcheng

2006-09-01

A novel sample injection method for chip CE was presented. This injection method uses hydrostatic pressure, generated by emptying the sample waste reservoir, for sample loading and electrokinetic force for dispensing. The injection was performed on a double-cross microchip. One cross, created by the sample and separation channels, is used for formation of a sample plug. Another cross, formed by the sample and controlling channels, is used for plug control. By varying the electric field in the controlling channel, the sample plug volume can be linearly adjusted. Hydrostatic pressure takes advantage of its ease of generation on a microfluidic chip, without any electrode or external pressure pump, thus allowing a sample injection with a minimum number of electrodes. The potential of this injection method was demonstrated by a four-separation-channel chip CE system. In this system, parallel sample separation can be achieved with only two electrodes, which is otherwise impossible with conventional injection methods. Hydrostatic pressure maintains the sample composition during the sample loading, allowing the injection to be free of injection bias.

Preliminary Data on the Effects of Inlet Pressure Distortions on the J57-P-1 Turbojet Engine

NASA Technical Reports Server (NTRS)

Wallner, Lewis E.; Lubick, Robert J.; Einstein, Thomas H.

1954-01-01

An investigation to determine the steady-state and surge characteristics of the J57-P-1 two-spool turbojet engine with various inlet air-flow distortions was conducted in the altitude wind tunnel at the NACA Lewis laboratory. Along with a uniform inlet total-pressure distribution, one circumferential and three radial pressure distortions were investigated. Data were obtained over a complete range of compressor speeds both with and without intercompressor air bleed at a flight Mach number of 0.8 and at altitudes of 35,000 and 50,000 feet. Total-pressure distortions of the magnitudes investigated had very little effect on the steady-state operating line for either the outer or inner compressor. The small radial distortions investigated also had engine over that obtained with the uniform inlet pressure distribution. The circumferential distortion, however, raised the minimum speed at which the engine could operate without encountering surge when the intercompressor bleeds were closed. This increase in minimum speed resulted in a substantial reduction in the operable speed range accompanied by a reduction in the altitude operating limit.

30 CFR 250.1003 - Installation, testing, and repair requirements for DOI pipelines.

Code of Federal Regulations, 2011 CFR

2011-07-01

... installed in water depths of less than 200 feet shall be buried to a depth of at least 3 feet unless they... damage potential exists. (b)(1) Pipelines shall be pressure tested with water at a stabilized pressure of... repair, the pipeline shall be pressure tested with water or processed natural gas at a minimum stabilized...

External Catalyst Breakup Phenomena

DTIC Science & Technology

1976-06-01

catalyst particle can cause high internal pressures which result in particle destruction. Analytical results suggest rhat erosion effects from solid...mechanisms. * Pressure Forces. High G loadings and bed pressure drops should be avoided. Bed pre-loads should be kept at a minimum value. Thruster...5.2.7.1 Failure Theories ............................ 243 5.2.7.2 Maximum Tension Stress Criterion ............ 244 5.2.7.3 Distortion Energy Approach

30 CFR 250.523 - How long do I keep records of casing pressure and diagnostic tests?

Code of Federal Regulations, 2011 CFR

2011-07-01

... and diagnostic tests? 250.523 Section 250.523 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT... long do I keep records of casing pressure and diagnostic tests? Records of casing pressure and diagnostic tests must be kept at the field office nearest the well for a minimum of 2 years. The last casing...

14 CFR 23.1443 - Minimum mass flow of supplemental oxygen.

Code of Federal Regulations, 2012 CFR

2012-01-01

..., minus 47 mm. Hg, which is the tracheal pressure displaced by water vapor pressure when the breathed air becomes saturated with water vapor at 37 °C). (2) STPD means Standard, Temperature, and Pressure, Dry (which is, 0 °C at 760 mm. Hg with no water vapor). [Doc. No. 26344, 58 FR 18978, Apr. 9, 1993] § 23.1443...

Laser ignition of liquid petroleum gas at elevated pressures

NASA Astrophysics Data System (ADS)

Loktionov, E.; Pasechnikov, N.; Telekh, V.

2017-11-01

Recent development of laser spark plugs for internal combustion engines have shown lack of data on laser ignition of fuel mixtures at multi-bar pressures needed for laser pulse energy and focusing optimisation. Methane and hydrogen based mixtures are comparatively well investigated, but propane and butane based ones (LPG), which are widely used in vehicles, are still almost unstudied. Optical breakdown thresholds in gases decrease with pressure increase up to ca. 100 bar, but breakdown is not a sufficient condition for combustion ignition. So minimum ignition energy (MIE) becomes more important for combustion core onset, and its dependency on mixture composition and pressure has several important features. For example, unlike breakdown threshold, is poorly dependent on laser pulse length, at least in pico- and to microsecond range. We have defined experimentally the dependencies of minimum picosecond laser pulse energies (MIE related value) needed for ignition of LPG based mixtures of 1.0 to 1.6 equivalence ratios and pressure of 1.0 to 3.5 bar. In addition to expected values decrease, low-energy flammability range broadening has been found at pressure increase. Laser ignition of LPG in Wankel rotary engine is reported for the first time.

Note: measurement of extreme-short current pulse duration of runaway electron beam in atmospheric pressure air.

PubMed

Tarasenko, V F; Rybka, D V; Burachenko, A G; Lomaev, M I; Balzovsky, E V

2012-08-01

This note reports the time-amplitude characteristic of the supershort avalanche electron beam with up to 20 ps time resolution. For the first time it is shown that the electron beam downstream of small-diameter diaphragms in atmospheric pressure air has a complex structure which depends on the interelectrode gap width and cathode design. With a spherical cathode and collimator the minimum duration at half maximum of the supershort avalanche electron beam current pulse was shown to be ~25 ps. The minimum duration at half maximum of one peak in the pulses with two peaks can reach ~25 ps too.

Magnetic energy dissipation in force-free jets

NASA Technical Reports Server (NTRS)

Choudhuri, Arnab Rai; Konigl, Arieh

1986-01-01

It is shown that a magnetic pressure-dominated, supersonic jet which expands or contracts in response to variations in the confining external pressure can dissipate magnetic energy through field-line reconnection as it relaxes to a minimum-energy configuration. In order for a continuous dissipation to occur, the effective reconnection time must be a fraction of the expansion time. The dissipation rate for the axisymmetric minimum-energy field configuration is analytically derived. The results indicate that the field relaxation process could be a viable mechanism for powering the synchrotron emission in extragalactic jets if the reconnection time is substantially shorter than the nominal resistive tearing time in the jet.

Torrejon AB, Madrid, Spain. revised uniform summary of surface weather observations (RUSSWO). parts a-f. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1978-10-03

This report is a six-part statistical summary of surface weather observations for Torrejon AB, Madrid Spain. It contains the following parts: (A) Weather Conditions; Atmospheric Phenomena; (B) Precipitation, Snowfall and Snow Depth (daily amounts and extreme values); (C) Surface winds; (D) Ceiling Versus Visibility; Sky Cover; (E) Psychrometric Summaries (daily maximum and minimum temperatures, extreme maximum and minimum temperatures, psychrometric summary of wet-bulb temperature depression versus dry-bulb temperature, means and standard deviations of dry-bulb, wet-bulb and dew-point temperatures and relative humidity); and (F) Pressure Summary (means, standard, deviations, and observation counts of station pressure and sea-level pressure). Data in thismore » report are presented in tabular form, in most cases in percentage frequency of occurrence or cumulative percentage frequency of occurrence tables.« less

Synthesis and evaluation of novel siloxane-methacrylate monomers used as dentin adhesives

PubMed Central

Ge, Xueping; Ye, Qiang; Song, Linyong; Misra, Anil; Spencer, Paulette

2014-01-01

Objectives The objectives of this study were to synthesize two new siloxane-methacrylate (SM) monomers for application in dentin adhesives and to investigate the influence of different functionality of the siloxane-containing monomers on the adhesive photopolymerization, water sorption, and mechanical properties. Materials and method Two siloxane-methacrylate monomers (SM1 and SM2) with four and eight methacrylate groups were synthesized. Dentin adhesives containing BisGMA, HEMA and the siloxane-methacrylate monomers were photo-polymerized. The experimental adhesives were compared with the control adhesive (HEMA/BisGMA 45/55 w/w) and characterized with regard to degree of conversion (DC), water miscibility of the liquid resin, water sorption and dynamic mechanical analysis (DMA). Results The experimental adhesives exhibited improved water miscibility as compared to the control. When cured in the presence of 12 wt % water to simulate the wet environment of the mouth, the SM-containing adhesives showed DC comparable to the control. The experimental adhesives showed higher rubbery modulus than the control under dry conditions. Under wet conditions, the mechanical properties of the formulations containing SM monomer with increased functionality were comparable with the control, even with more water sorption. Significance The concentration and functionality of the newly synthesized siloxane-methacrylate monomers affected the water miscibility, water sorption and mechanical properties of the adhesives. The experimental adhesives show improved water compatibility compared with the control. The mechanical properties were enhanced with an increase of the functionality of the siloxane-containing monomers. The results provide critical structure/property relationships and important information for future development of durable, versatile siloxane-containing dentin adhesives. PMID:24993811

A new method to simulate the effects of viscous fingering on miscible displacement processes in porous media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vossoughi, S.; Green, D.W.; Smith, J.E.

Dispersion and viscous fingering are important parameters in miscible displacement. Effects of dispersion on concentration profiles in porous media can be simulated when the viscosity ratio is favorable. The capability to simulate viscous fingering is limited. This paper presents a new method to simulate effects of viscous fingering on miscible displacement processes in porous media. The method is based on the numerical solution of a general form of the convection-dispersion equation. In this equation the convection term is represented by a fractional flow function. The fractional flow function is derived from Darcy's law by using a concentration-dependent average viscosity andmore » relative flow area to each fluid at any point in the bed. The method was extended to the description of a polymer flood by including retention and inaccessible PV. A Langmuir-type model for polymer retention in the rock was used. The resulting convection-dispersion equation for displacement by polymer was solved numerically by the use of a finite-element method with linear basis functions and Crank-Nicholson derivative approximation. History matches were performed on four sets of laboratory data to verify the model: (1) an unfavorable viscosity ratio displacement, (2) stable displacement of glycerol by polymer solution, (3) unstable displacement of brine by a slug of polymer solution, and (4) a favorable viscosity ratio displacement. In general, computed results from the model matched laboratory data closely. Good agreement of the model with experiments over a significant range of variables lends support to the analysis.« less

Nonequilibrium Interfacial Tension in Simple and Complex Fluids

NASA Astrophysics Data System (ADS)

Truzzolillo, Domenico; Mora, Serge; Dupas, Christelle; Cipelletti, Luca

2016-10-01

Interfacial tension between immiscible phases is a well-known phenomenon, which manifests itself in everyday life, from the shape of droplets and foam bubbles to the capillary rise of sap in plants or the locomotion of insects on a water surface. More than a century ago, Korteweg generalized this notion by arguing that stresses at the interface between two miscible fluids act transiently as an effective, nonequilibrium interfacial tension, before homogenization is eventually reached. In spite of its relevance in fields as diverse as geosciences, polymer physics, multiphase flows, and fluid removal, experiments and theoretical works on the interfacial tension of miscible systems are still scarce, and mostly restricted to molecular fluids. This leaves crucial questions unanswered, concerning the very existence of the effective interfacial tension, its stabilizing or destabilizing character, and its dependence on the fluid's composition and concentration gradients. We present an extensive set of measurements on miscible complex fluids that demonstrate the existence and the stabilizing character of the effective interfacial tension, unveil new regimes beyond Korteweg's predictions, and quantify its dependence on the nature of the fluids and the composition gradient at the interface. We introduce a simple yet general model that rationalizes nonequilibrium interfacial stresses to arbitrary mixtures, beyond Korteweg's small gradient regime, and show that the model captures remarkably well both our new measurements and literature data on molecular and polymer fluids. Finally, we briefly discuss the relevance of our model to a variety of interface-driven problems, from phase separation to fracture, which are not adequately captured by current approaches based on the assumption of small gradients.

Synthesis and evaluation of novel siloxane-methacrylate monomers used as dentin adhesives.

PubMed

Ge, Xueping; Ye, Qiang; Song, Linyong; Misra, Anil; Spencer, Paulette

2014-09-01

The objectives of this study were to synthesize two new siloxane-methacrylate (SM) monomers for application in dentin adhesives and to investigate the influence of different functionality of the siloxane-containing monomers on the adhesive photopolymerization, water sorption, and mechanical properties. Two siloxane-methacrylate monomers (SM1 and SM2) with four and eight methacrylate groups were synthesized. Dentin adhesives containing BisGMA, HEMA and the siloxane-methacrylate monomers were photo-polymerized. The experimental adhesives were compared with the control adhesive (HEMA/BisGMA, 45/55, w/w) and characterized with regard to degree of conversion (DC), water miscibility of the liquid resin, water sorption and dynamic mechanical analysis (DMA). The experimental adhesives exhibited improved water miscibility as compared to the control. When cured in the presence of 12 wt% water to simulate the wet environment of the mouth, the SM-containing adhesives showed DC comparable to the control. The experimental adhesives showed higher rubbery modulus than the control under dry conditions. Under wet conditions, the mechanical properties of the formulations containing SM monomer with increased functionality were comparable with the control, even with more water sorption. The concentration and functionality of the newly synthesized siloxane-methacrylate monomers affected the water miscibility, water sorption and mechanical properties of the adhesives. The experimental adhesives show improved water compatibility compared with the control. The mechanical properties were enhanced with an increase of the functionality of the siloxane-containing monomers. The results provide critical structure/property relationships and important information for future development of durable, versatile siloxane-containing dentin adhesives. Published by Elsevier Ltd.

Physicochemical properties of film-coated melt-extruded pellets.

PubMed

Young, Chistopher R; Crowley, Michael; Dietzsch, Caroline; McGinity, James W

2007-02-01

The purpose of this study was to investigate the physicochemical properties of poly(ethylene oxide) (PEO) and guaifenesin containing beads prepared by a melt-extrusion process and film-coated with a methacrylic acid copolymer. Solubility parameter calculations, thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), modulated differential scanning calorimetry (MDSC), X-ray powder diffraction (XRPD) and high performance liquid chromatography (HPLC) were used to determine drug/polymer miscibility and/or the thermal processibility of the systems. Powder blends of guaifenesin, PEO and functional excipients were processed using a melt-extrusion and spheronization technique and then film-coated in a fluidized bed apparatus. Solubility parameter calculations were used to predict miscibility between PEO and guaifenesin, and miscibility was confirmed by SEM and observation of a single melting point for extruded drug/polymer blends during MDSC investigations. The drug was stable following melt-extrusion as determined by TGA and HPLC; however, drug release rate from pellets decreased upon storage in sealed HDPE containers with silica desiccants at 40 degrees C/75% RH. The weight loss on drying, porosity and tortuosity determinations were not influenced by storage. Recrystallization of guaifenesin and PEO was confirmed by SEM and XRPD. Additionally, the pellets exhibited a change in adhesion behaviour during dissolution testing. The addition of ethylcellulose to the extruded powder blend decreased and stabilized the drug release rate from the thermally processed pellets. The current study also demonstrated film-coating to be an efficient process for providing melt-extruded beads with pH-dependent drug release properties that were stable upon storage at accelerated conditions.

Entropic depletion in colloidal suspensions and polymer liquids: Role of nanoparticle surface topography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Banerjee, Debapriya; Yang, Jian; Schweizer, Kenneth S.

2015-01-01

Here, we employ a hybrid Monte Carlo plus integral equation theory approach to study how dense fluids of small nanoparticles or polymer chains mediate entropic depletion interactions between topographically rough particles where all interaction potentials are hard core repulsion. The corrugated particle surfaces are composed of densely packed beads which present variable degrees of controlled topographic roughness and free volume associated with their geometric crevices. This pure entropy problem is characterized by competing ideal translational and (favorable and unfavorable) excess entropic contributions. Surface roughness generically reduces particle depletion aggregation relative to the smooth hard sphere case. However, the competition betweenmore » ideal and excess packing entropy effects in the bulk, near the particle surface and in the crevices, results in a non-monotonic variation of the particle-monomer packing correlation function as a function of the two dimensionless length scale ratios that quantify the effective surface roughness. As a result, the inter-particle potential of mean force (PMF), second virial coefficient, and spinodal miscibility volume fraction vary non-monotonically with the surface bead to monomer diameter and particle core to surface bead diameter ratios. A miscibility window is predicted corresponding to an optimum degree of surface roughness that completely destroys depletion attraction resulting in a repulsive PMF. Variation of the (dense) matrix packing fraction can enhance or suppress particle miscibility depending upon the amount of surface roughness. Connecting the monomers into polymer chains destabilizes the system via enhanced contact depletion attraction, but the non-monotonic variations with surface roughness metrics persist.« less

Vortex servovalve for fluidic or electrical input

NASA Technical Reports Server (NTRS)

Honda, T. S.

1972-01-01

Proportional-pressure control servovalve consisting of fluid amplifier bellows-driven jet-pipe and two vortex valves operating in push-pull, with a pair of bellows for pressure feedback is tolerant to comtaminant particles and meets minimum standby flow requirements for applications such as rocket thruster nozzles.

Phase Equilibrium Investigation on 2-Phenylethanol in Binary and Ternary Systems: Influence of High Pressure on Density and Solid-Liquid Phase Equilibrium.

PubMed

Domańska, Urszula; Królikowski, Marek; Wlazło, Michał; Więckowski, Mikołaj

2018-05-30

Ionic liquids (ILs) are important new solvents proposed for applications in different separation processes. Herein, an idea of possible use of high pressure in a general strategy of production of 2-phenylethanol (PEA) is discussed. In this work, we present the influence of pressure on the density in binary systems of {1-hexyl-1-methylpyrrolidynium bis{(trifluoromethyl)sulfonyl}imide, [HMPYR][NTf 2 ], or 1-dodecyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide, [DoMIM][NTf 2 ] + PEA} in a wide range of temperatures (298.15-348.15 K) and pressures (0.1-40 MPa). The densities at ambient and high pressures are measured to present the physicochemical properties of the ILs used in the process of separation of PEA from aqueous phase. The Tait equation was used for the correlation of density of one-component and two-component systems as a function of mole fraction, temperature, and pressure. The influence of pressure is not significant. These systems exhibit mainly negative molar excess volumes, V E . The solid-liquid phase equilibrium (SLE) of [DoMIM][NTf 2 ] in PEA at atmospheric pressure was measured and compared to the SLE high-pressure results. Additionally, the ternary liquid-liquid phase equilibrium (LLE) at ambient pressure in the {[DoMIM][NTf 2 ] (1) + PEA (2) + water (3)} at temperature T = 308.15 K was investigated. The solubility of water in the [DoMIM][NTf 2 ] is quite high in comparison with that measured by us earlier for ILs ( x 3 = 0.403) at T = 308.15 K, which results in not very successful average selectivity of extraction of PEA from the aqueous phase. The [DoMIM][NTf 2 ] has shown strong interaction with PEA without the immiscibility region. The ternary system revealed Treybal's type phase equilibrium in which two partially miscible binaries ([DoMIM][NTf 2 ] + water) and (PEA + water) exist. From the results of LLE in the ternary system, the selectivity and the solute distribution ratio of separation of water/PEA were calculated and compared to the results obtained for the ILs measured earlier by us. The popular NRTL model was used to correlate the experimental tie-lines in ternary LLE. These results may help in a new technological project of "in situ" extraction of PEA from aqueous phase during the biosynthesis.

An analysis of data related to the minimum temperatures for valid testing in cryogenic wind tunnels using nitrogen as the test gas

NASA Technical Reports Server (NTRS)

Hall, R. M.

1976-01-01

The minimum operating temperature which avoids adverse low temperature effects, such as condensation, has been determined at a free stream Mach number of 0.85 for flow over a 0.137 meter airfoil mounted at zero incidence in the Langley 1/3 meter transonic cryogenic tunnel. The onset of low temperature effects is established by comparing the pressure coefficient measured at a given orifice for a particular temperature with those measured at temperatures sufficiently above where low temperature effects might be expected to occur. The pressure distributions over the airfoil are presented in tabular form. In addition, the comparisons of the pressure coefficient as a function of total temperature are presented graphically for chord locations of 0, 25, 50, and 75 percent. Over the 1.2 to 4.5 atmosphere total pressure range investigated, low temperature effects are not detected until total temperatures are 2 K, or more, below free stream saturation temperatures.

The Interplay Between Saline Fluid Flow and Dynamic Permeability in Magmatic-Hydrothermal Systems

NASA Astrophysics Data System (ADS)

Weis, P.

2014-12-01

Magmatic-hydrothermal ore deposits document the interplay between saline fluid flow and rock permeability. Numerical simulations of multi-phase flow of variably miscible, compressible H20-NaCl fluids in concert with a dynamic permeability model can reproduce characteristics of porphyry copper and epithermal gold systems. This dynamic permeability model incorporates depth-dependent permeability profiles characteristic for tectonically active crust as well as pressure- and temperature-dependent relationships describing hydraulic fracturing and the transition from brittle to ductile rock behavior. In response to focused expulsion of magmatic fluids from a crystallizing upper crustal magma chamber, the hydrothermal system self-organizes into a hydrological divide, separating an inner part dominated by ascending magmatic fluids under near-lithostatic pressures from a surrounding outer part dominated by convection of colder meteoric fluids under near-hydrostatic pressures. This hydrological divide also provides a mechanism to transport magmatic salt through the crust, and prevents the hydrothermal system to become "clogged" by precipitation of solid halite due to depressurization of saline, high-temperature magmatic fluids. The same physical processes at similar permeability ranges, crustal depths and flow rates are relevant for a number of active systems, including geothermal resources and excess degassing at volcanos. The simulations further suggest that the described mechanism can separate the base of free convection in high-enthalpy geothermal systems from the magma chamber as a driving heat source by several kilometers in the vertical direction in tectonic settings with hydrous magmatism. This hydrology would be in contrast to settings with anhydrous magmatism, where the base of the geothermal systems may be closer to the magma chamber.

49 CFR 178.47 - Specification 4DS welded stainless steel cylinders for aircraft use.

Code of Federal Regulations, 2011 CFR

2011-10-01

... the formula: S = PD / 4tE Where: S = Wall stress in psi; P = Test pressure prescribed for water jacket... stainless steel sphere (two seamless hemispheres) or circumferentially welded cylinder both with a water... thickness. The minimum wall thickness must be such that the wall stress at the minimum specified test...

Development of a test facility and preliminary testing of flow boiling heat transfer of R410A refrigerant with Al2O3 nanolubricants

NASA Astrophysics Data System (ADS)

Wong, Thiam

In vapor compression cycles, a small portion of the oil circulates with the refrigerant throughout the system components, while most of the oil stays in the compressors. In heat exchangers, the lubricant in excess penalizes the heat transfer and increases the pressure losses: both effects are highly undesired but yet unavoidable. Nanoparticles dispersed in the excess lubricant are expected to provide enhancements in heat transfer. While solubility and miscibility of refrigerants in polyolesters (POE) lubricant are well established knowledge, there is a lack of information regarding if and how nanoparticles dispersed in the lubricant affect these properties. This thesis presents experimental data of solubility of two types of Al2O3 nanolubricants with refrigerant R-410A. The nanoparticles were dispersed in POE lubricant by using different surfactants and dispersion methods. The nanolubricants appeared to have slightly lower solubility than that of R-410A but actually the solid nanoparticles did not really interfere with the POE oil solubility characteristics. A test facility and experimental methodology was developed for the investigation of heat transfer coefficient and pressure drop. The pressure drop of the refrigerant lubricant mixtures during flow boiling depended on the mass flux of the refrigerant. Greater augmentation was seen in the pressure drop results with decreasing mass flow rate. Pure refrigerant R410A showed the lowest pressure drop, addition of nanolubricants to the refrigerant showed a slightly higher pressure drop and POE-refrigerant mixture showed the highest pressure drop in the tests conducted. Enhancement or degradation in heat transfer coefficient during flow boiling depended on the nanoparticle concentration in the lubricant as well as the lubricant concentration in refrigerant. R410A showed the highest heat transfer coefficient for all conditions tested. For a concentration of 1% nanolubricant in refrigerant, the heat transfer coefficient showed more enhancement with increase in nanoparticle concentration compared to POE refrigerant mixtures. For a concentration of 3% nanolubricant in refrigerant mixtures there was little to no enhancement for tests conducted.

Thermodynamic properties of hematite — ilmenite — geikielite solid solutions

NASA Astrophysics Data System (ADS)

Ghiorso, Mark S.

1990-11-01

A solution model is developed for rhombohedral oxide solid solutions having compositions within the ternary system ilmenite [(Fe{2+/ s }Ti{4+/1- s }) A (Fe{2+/1- s }Ti{4+/s}) B O3]-geikielite [(Mg{2+/ t }Ti{4+/1- t }) A (Mg{2+/1- t }Ti{4+/ t }) B O3]-hematite [(Fe3+) A (Fe3+) B O3]. The model incorporates an expression for the configurational entropy of solution, which accounts for varying degrees of structural long-range order (0≤s, t≤1) and utilizes simple regular solution theory to characterize the excess Gibbs free energy of mixing within the five-dimensional composition-ordering space. The 13 model parameters are calibrated from available data on: (1) the degree of long-range order and the composition-temperature dependence of theRbar 3c - Rbar 3 transition along the ilmenite-hematite binary join; (2) the compositions of coexisting olivine and rhombohedral oxide solid solutions close to the Mg-Fe2+ join; (3) the shape of the miscibility gap along the ilmenite-hematite join; (4) the compositions of coexisting spinel and rhombohedral oxide solid solutions along the Fe2+-Fe3+ join. In the course of calibration, estimates are obtained for the reference state enthalpy of formation of ulvöspinel and stoichiometric hematite (-1488.5 and -822.0 kJ/mol at 298 K and 1 bar, respectively). The model involves no excess entropies of mixing nor does it incorporate ternary interaction parameters. The formulation fits the available data and represents an internally consistent energetic model when used in conjuction with the standard state thermodynamic data set of Berman (1988) and the solution theory for orthopyroxenes, olivines and Fe-Mg titanomagnetite-aluminate-chromate spinels developed by Sack and Ghiorso (1989, 1990a, b). Calculated activity-composition relations for the end-members of the series, demonstrate the substantial degree of nonideality associated with interactions between the ordered and disordered structures and the dominant influence of the miscibility gap across much of the ternary system. The predicted shape of the miscibility gap, and the orientation of tie-lines relating the compositions of coexisting phases, display the effects of coupling between the excess enthalpy of solution and the degree of long-range order. One limb of the miscibility gap follows the composititiontemperature surface corresponding to the ternaryRbar 3 - Rbar 3c second-order transition.

Elastohydrodynamic lubrication of elliptical contacts

NASA Technical Reports Server (NTRS)

Hamrock, B. J.

1981-01-01

The determination of the minimum film thickness within contact is considered for both fully flooded and starved conditions. A fully flooded conjunction is one in which the film thickness is not significantly changed when the amount of lubricant is increased. The fully flooded results presented show the influence of contact geometry on minimum film thickness as expressed by the ellipticity parameter and the dimensionless speed, load, and materials parameters. These results are applied to materials of high elastic modulus (hard EHL), such as metal, and to materials of low elastic modulus(soft EHL), such as rubber. In addition to the film thickness equations that are developed, contour plots of pressure and film thickness are given which show the essential features of elastohydrodynamically lubricated conjunctions. The crescent shaped region of minimum film thickness, with its side lobes in which the separation between the solids is a minimum, clearly emerges in the numerical solutions. In addition to the 3 presented for the fully flooded results, 15 more cases are used for hard EHL contacts and 18 cases are used for soft EHL contacts in a theoretical study of the influence of lubricant starvation on film thickness and pressure. From the starved results for both hard and soft EHL contacts, a simple and important dimensionless inlet boundary distance is specified. This inlet boundary distance defines whether a fully flooded or a starved condition exists in the contact. Contour plots of pressure and film thickness in and around the contact are shown for conditions.

Computational fluid dynamics endpoints to characterize obstructive sleep apnea syndrome in children

PubMed Central

Luo, Haiyan; Persak, Steven C.; Sin, Sanghun; McDonough, Joseph M.; Isasi, Carmen R.; Arens, Raanan

2013-01-01

Computational fluid dynamics (CFD) analysis may quantify the severity of anatomical airway restriction in obstructive sleep apnea syndrome (OSAS) better than anatomical measurements alone. However, optimal CFD model endpoints to characterize or assess OSAS have not been determined. To model upper airway fluid dynamics using CFD and investigate the strength of correlation between various CFD endpoints, anatomical endpoints, and OSAS severity, in obese children with OSAS and controls. CFD models derived from magnetic resonance images were solved at subject-specific peak tidal inspiratory flow; pressure at the choanae was set by nasal resistance. Model endpoints included airway wall minimum pressure (Pmin), flow resistance in the pharynx (Rpharynx), and pressure drop from choanae to a minimum cross section where tonsils and adenoids constrict the pharynx (dPTAmax). Significance of endpoints was analyzed using paired comparisons (t-test or Wilcoxon signed rank test) and Spearman correlation. Fifteen subject pairs were analyzed. Rpharynx and dPTAmax were higher in OSAS than control and most significantly correlated to obstructive apnea-hypopnea index (oAHI), r = 0.48 and r = 0.49, respectively (P < 0.01). Airway minimum cross-sectional correlation to oAHI was weaker (r = −0.39); Pmin was not significantly correlated. CFD model endpoints based on pressure drops in the pharynx were more closely associated with the presence and severity of OSAS than pressures including nasal resistance, or anatomical endpoints. This study supports the usefulness of CFD to characterize anatomical restriction of the pharynx and as an additional tool to evaluate subjects with OSAS. PMID:24265282

Locating and sealing air leaks in multiroomed buildings

NASA Technical Reports Server (NTRS)

Britton, J. M.

1968-01-01

Industrial, nontoxic smoke bombs are used in multiroomed buildings to locate and fill discovered leak areas with polyurethane foam. All obvious air escape routes are sealed and the room is then pressurized to a minimum of 0.1 inch water above the pressure of adjoining rooms.

Pressure fluctuation generated by the interaction of blade and tongue

NASA Astrophysics Data System (ADS)

Zheng, Lulu; Dou, Hua-Shu; Chen, Xiaoping; Zhu, Zuchao; Cui, Baoling

2018-02-01

Pressure fluctuation around the tongue has large effect on the stable operation of a centrifugal pump. In this paper, the Reynolds averaged Navier-Stokes equations (RANS) and the RNG k-epsilon turbulence model is employed to simulate the flow in a pump. The flow field in the centrifugal pump is computed for a range of flow rate. The simulation results have been compared with the experimental data and good agreement has been achieved. In order to study the interaction of the tongue with the impeller, fifteen monitor probes are evenly distributed circumferentially at three radii around the tongue. Pressure distribution is investigated at various blade positions while the blade approaches to and leaves the tongue region. Results show that pressure signal fluctuates largely around the tongue, and it is more intense near the tongue surface. At design condition, standard deviation of pressure fluctuation is the minimum. At large flow rate, the increased low pressure region at the blade trailing edge results in the increases of pressure fluctuation amplitude and pressure spectra at the monitor probes. Minimum pressure is obtained when the blade is facing to the tongue. It is found that the amplitude of pressure fluctuation strongly depends on the blade positions at large flow rate, and pressure fluctuation is caused by the relative movement between blades and tongue. At small flow rate, the rule of pressure fluctuation is mainly depending on the structure of vortex flow at blade passage exit besides the influence from the relative position between the blade and the tongue.

Automatic safety rod for reactors. [LMFBR

DOEpatents

Germer, J.H.

1982-03-23

An automatic safety rod for a nuclear reactor containing neutron absorbing material and designed to be inserted into a reactor core after a loss-of-flow. Actuation is based upon either a sudden decrease in core pressure drop or the pressure drop decreases below a predetermined minimum value. The automatic control rod includes a pressure regulating device whereby a controlled decrease in operating pressure due to reduced coolant flow does not cause the rod to drop into the core.

Automatic safety rod for reactors

DOEpatents

Germer, John H.

1988-01-01

An automatic safety rod for a nuclear reactor containing neutron absorbing material and designed to be inserted into a reactor core after a loss-of-core flow. Actuation is based upon either a sudden decrease in core pressure drop or the pressure drop decreases below a predetermined minimum value. The automatic control rod includes a pressure regulating device whereby a controlled decrease in operating pressure due to reduced coolant flow does not cause the rod to drop into the core.

Numerical Modelling of Extended Leak-Off Test with a Pre-Existing Fracture

NASA Astrophysics Data System (ADS)

Lavrov, A.; Larsen, I.; Bauer, A.

2016-04-01

Extended leak-off test (XLOT) is one of the few techniques available for stress measurements in oil and gas wells. Interpretation of the test is often difficult since the results depend on a multitude of factors, including the presence of natural or drilling-induced fractures in the near-well area. Coupled numerical modelling of XLOT has been performed to investigate the pressure behaviour during the flowback phase as well as the effect of a pre-existing fracture on the test results in a low-permeability formation. Essential features of XLOT known from field measurements are captured by the model, including the saw-tooth shape of the pressure vs injected volume curve, and the change of slope in the pressure vs time curve during flowback used by operators as an indicator of the bottomhole pressure reaching the minimum in situ stress. Simulations with a pre-existing fracture running from the borehole wall in the radial direction have revealed that the results of XLOT are quite sensitive to the orientation of the pre-existing fracture. In particular, the fracture initiation pressure and the formation breakdown pressure increase steadily with decreasing angle between the fracture and the minimum in situ stress. Our findings seem to invalidate the use of the fracture initiation pressure and the formation breakdown pressure for stress measurements or rock strength evaluation purposes.

Monolithic composites of silica aerogels by reactive supercritical deposition of hydroxy-terminated poly(dimethylsiloxane).

PubMed

Sanli, D; Erkey, C

2013-11-27

Monolithic composites of silica aerogels with hydroxyl-terminated poly(dimethylsiloxane) (PDMS(OH)) were developed with a novel reactive supercritical deposition technique. The method involves dissolution of PDMS(OH) in supercritical CO2 (scCO2) and then exposure of the aerogel samples to this single phase mixture of PDMS(OH)-CO2. The demixing pressures of the PDMS(OH)-CO2 binary mixtures determined in this study indicated that PDMS(OH) forms miscible mixtures with CO2 at a wide composition range at easily accessible pressures. Upon supercritical deposition, the polymer molecules were discovered to react with the hydroxyl groups on the silica aerogel surface and form a conformal coating on the surface. The chemical attachment of the polymer molecules on the aerogel surface were verified by prolonged extraction with pure scCO2, simultaneous deposition with superhydrophobic and hydrophilic silica aerogel samples and ATR-FTIR analysis. All of the deposited silica aerogel samples were obtained as monoliths and retained their transparency up to around 30 wt % of mass uptake. PDMS(OH) molecules were found to penetrate all the way to the center of the monoliths and were distributed homogenously throughout the cylindrical aerogel samples. Polymer loadings as high as 75.4 wt % of the aerogel mass could be attained. It was shown that the polymer uptake increases with increasing exposure time, as well as the initial polymer concentration in the vessel.

40 CFR 63.9921 - What are the installation, operation and maintenance requirements for my monitors?

Code of Federal Regulations, 2010 CFR

2010-07-01

... operating limits in § 63.9890(b) for pressure drop and scrubber water flow rate, you must install, operate...) For the pressure drop CPMS, you must: (i) Locate the pressure sensor(s) in or as close to a position... sensitivity of 0.5 inch of water or a transducer with a minimum measurement sensitivity of 1 percent of the...

42 CFR 84.149 - Type C supplied-air respirator, demand and pressure demand class; minimum requirements.

Code of Federal Regulations, 2010 CFR

2010-10-01

... per square inch) with from 6 to 76 m. (15 to 250 feet) of air-supply hose. (c) The specified air... pounds per square inch gage). (d)(1) Where the pressure in the air-supply system exceeds 863 kN/m.2 (125 pounds per square inch gage), the respirator shall be equipped with a pressure-release mechanism that...

42 CFR 84.149 - Type C supplied-air respirator, demand and pressure demand class; minimum requirements.

Code of Federal Regulations, 2011 CFR

2011-10-01

... per square inch) with from 6 to 76 m. (15 to 250 feet) of air-supply hose. (c) The specified air... pounds per square inch gage). (d)(1) Where the pressure in the air-supply system exceeds 863 kN/m.2 (125 pounds per square inch gage), the respirator shall be equipped with a pressure-release mechanism that...

42 CFR 84.149 - Type C supplied-air respirator, demand and pressure demand class; minimum requirements.

Code of Federal Regulations, 2012 CFR

2012-10-01

... per square inch) with from 6 to 76 m. (15 to 250 feet) of air-supply hose. (c) The specified air... pounds per square inch gage). (d)(1) Where the pressure in the air-supply system exceeds 863 kN/m.2 (125 pounds per square inch gage), the respirator shall be equipped with a pressure-release mechanism that...

42 CFR 84.149 - Type C supplied-air respirator, demand and pressure demand class; minimum requirements.

Code of Federal Regulations, 2013 CFR

2013-10-01

... per square inch) with from 6 to 76 m. (15 to 250 feet) of air-supply hose. (c) The specified air... pounds per square inch gage). (d)(1) Where the pressure in the air-supply system exceeds 863 kN/m.2 (125 pounds per square inch gage), the respirator shall be equipped with a pressure-release mechanism that...

42 CFR 84.149 - Type C supplied-air respirator, demand and pressure demand class; minimum requirements.

Code of Federal Regulations, 2014 CFR

2014-10-01

... per square inch) with from 6 to 76 m. (15 to 250 feet) of air-supply hose. (c) The specified air... pounds per square inch gage). (d)(1) Where the pressure in the air-supply system exceeds 863 kN/m.2 (125 pounds per square inch gage), the respirator shall be equipped with a pressure-release mechanism that...

49 CFR 232.217 - Train brake tests conducted using yard air.

Code of Federal Regulations, 2013 CFR

2013-10-01

... reduction of brake pipe air pressure at the same, or slower, rate as an engineer's brake valve. (b) The yard... (f). (2) At a minimum, yard air pressure shall be 60 psi at the end of the consist or block of cars... device. (3) If the air pressure of the yard test device is less than 80 psi, then a brake pipe leakage or...

49 CFR 232.217 - Train brake tests conducted using yard air.

Code of Federal Regulations, 2014 CFR

2014-10-01

... reduction of brake pipe air pressure at the same, or slower, rate as an engineer's brake valve. (b) The yard... (f). (2) At a minimum, yard air pressure shall be 60 psi at the end of the consist or block of cars... device. (3) If the air pressure of the yard test device is less than 80 psi, then a brake pipe leakage or...

49 CFR 232.217 - Train brake tests conducted using yard air.

Code of Federal Regulations, 2012 CFR

2012-10-01

... reduction of brake pipe air pressure at the same, or slower, rate as an engineer's brake valve. (b) The yard... (f). (2) At a minimum, yard air pressure shall be 60 psi at the end of the consist or block of cars... device. (3) If the air pressure of the yard test device is less than 80 psi, then a brake pipe leakage or...

49 CFR 232.217 - Train brake tests conducted using yard air.

Code of Federal Regulations, 2011 CFR

2011-10-01

... reduction of brake pipe air pressure at the same, or slower, rate as an engineer's brake valve. (b) The yard... (f). (2) At a minimum, yard air pressure shall be 60 psi at the end of the consist or block of cars... device. (3) If the air pressure of the yard test device is less than 80 psi, then a brake pipe leakage or...

PREDICTION OF THE SOLUBILITY OF HYDROPHOBIC COMPOUNDS IN NONIDEAL SOLVENT MIXTURES

EPA Science Inventory

The solubility of hydrophobic organic chemicals (HOCs) in partially-miscible solvent mixtures was investigated. In agreement with previous findings, it was observed that there is a limited domain in which nonideality effects are important; appreciable concentrations of partially-...

SORPTION KINETICS OF PAHS IN METHANOL-WATER SYSTEMS

EPA Science Inventory

The objectives of this study were to evaluate the relationships between the equilibrium sorption constant (Kp), the first-order desorption rate coefficient (k2), and the volumetric fraction of water miscible solvent (fc); and to utilize SPARC-calculated (SPARC Performs Automatic ...

Validated Test Method 5030C: Purge-and-Trap for Aqueous Samples

EPA Pesticide Factsheets

This method describes a purge-and-trap procedure for the analysis of volatile organic compoundsin aqueous samples & water miscible liquid samples. It also describes the analysis of high concentration soil and waste sample extracts prepared in Method 5035.

Melt density and the average composition of basalt

NASA Technical Reports Server (NTRS)

Stolper, E.; Walker, D.

1980-01-01

Densities of residual liquids produced by low pressure fractionation of olivine-rich melts pass through a minimum when pyroxene and plagioclase joint the crystallization sequence. The observation that erupted basalt compositions cluster around the degree of fractionation from picritic liquids corresponding to the density minimum in the liquid line of descent may thus suggest that the earth's crust imposes a density fiber on the liquids that pass through it, favoring the eruption of the light liquids at the density minimum over the eruption of denser more fractionated and less fractionated liquids.

49 CFR 192.3 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-10-01

... header or manifold. SMYS means specified minimum yield strength is: (1) For steel pipe manufactured in... the waters from the mean high water mark of the coast of the Gulf of Mexico and its inlets open to the... water. High-pressure distribution system means a distribution system in which the gas pressure in the...

49 CFR 192.3 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-10-01

... header or manifold. SMYS means specified minimum yield strength is: (1) For steel pipe manufactured in... the waters from the mean high water mark of the coast of the Gulf of Mexico and its inlets open to the... water. High-pressure distribution system means a distribution system in which the gas pressure in the...

49 CFR 192.3 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-10-01

... header or manifold. SMYS means specified minimum yield strength is: (1) For steel pipe manufactured in... the waters from the mean high water mark of the coast of the Gulf of Mexico and its inlets open to the... water. High-pressure distribution system means a distribution system in which the gas pressure in the...

49 CFR 192.3 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-10-01

... header or manifold. SMYS means specified minimum yield strength is: (1) For steel pipe manufactured in... the waters from the mean high water mark of the coast of the Gulf of Mexico and its inlets open to the... water. High-pressure distribution system means a distribution system in which the gas pressure in the...

49 CFR 192.3 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-10-01

... header or manifold. SMYS means specified minimum yield strength is: (1) For steel pipe manufactured in... the waters from the mean high water mark of the coast of the Gulf of Mexico and its inlets open to the... water. High-pressure distribution system means a distribution system in which the gas pressure in the...

49 CFR 195.306 - Test medium.

Code of Federal Regulations, 2011 CFR

2011-10-01

... this section, water must be used as the test medium. (b) Except for offshore pipelines, liquid... which produces a hoop stress of 50 percent of specified minimum yield strength; (3) The test section is... pressure is equal to or greater than a pressure that produces a hoop stress of 50 percent of specified...

46 CFR 153.370 - Minimum relief valve setting for ambient temperature cargo tanks.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 5 2014-10-01 2014-10-01 false Minimum relief valve setting for ambient temperature... temperature cargo tanks. The relief valve setting for a containment system that carries a cargo at ambient temperature must at least equal the cargo's vapor pressure at 46 °C (approx. 115 °F). [CGD 81-078, 50 FR 21173...

46 CFR 153.370 - Minimum relief valve setting for ambient temperature cargo tanks.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 5 2013-10-01 2013-10-01 false Minimum relief valve setting for ambient temperature... temperature cargo tanks. The relief valve setting for a containment system that carries a cargo at ambient temperature must at least equal the cargo's vapor pressure at 46 °C (approx. 115 °F). [CGD 81-078, 50 FR 21173...

46 CFR 153.370 - Minimum relief valve setting for ambient temperature cargo tanks.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 5 2012-10-01 2012-10-01 false Minimum relief valve setting for ambient temperature... temperature cargo tanks. The relief valve setting for a containment system that carries a cargo at ambient temperature must at least equal the cargo's vapor pressure at 46 °C (approx. 115 °F). [CGD 81-078, 50 FR 21173...

46 CFR 153.370 - Minimum relief valve setting for ambient temperature cargo tanks.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Minimum relief valve setting for ambient temperature... temperature cargo tanks. The relief valve setting for a containment system that carries a cargo at ambient temperature must at least equal the cargo's vapor pressure at 46 °C (approx. 115 °F). [CGD 81-078, 50 FR 21173...

46 CFR 153.370 - Minimum relief valve setting for ambient temperature cargo tanks.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 5 2011-10-01 2011-10-01 false Minimum relief valve setting for ambient temperature... temperature cargo tanks. The relief valve setting for a containment system that carries a cargo at ambient temperature must at least equal the cargo's vapor pressure at 46 °C (approx. 115 °F). [CGD 81-078, 50 FR 21173...

40 CFR Table 3 to Subpart Hhh of... - Operating Parameters To Be Monitored and Minimum Measurement and Recording Frequencies

Code of Federal Regulations, 2011 CFR

2011-07-01

... rural HMIWI HMIWI a with dry scrubber followed by fabric filter HMIWI a with wet scrubber HMIWI a with dry scrubber followed by fabric filter and wet scrubber Maximum operating parameters: Maximum charge... mercury (Hg) sorbent flow rate Hourly Once per hour ✔ ✔ Minimum pressure drop across the wet scrubber or...

Generating a Simulated Fluid Flow Over an Aircraft Surface Using Anisotropic Diffusion

NASA Technical Reports Server (NTRS)

Rodriguez, David L. (Inventor); Sturdza, Peter (Inventor)

2013-01-01

A fluid-flow simulation over a computer-generated aircraft surface is generated using a diffusion technique. The surface is comprised of a surface mesh of polygons. A boundary-layer fluid property is obtained for a subset of the polygons of the surface mesh. A pressure-gradient vector is determined for a selected polygon, the selected polygon belonging to the surface mesh but not one of the subset of polygons. A maximum and minimum diffusion rate is determined along directions determined using a pressure gradient vector corresponding to the selected polygon. A diffusion-path vector is defined between a point in the selected polygon and a neighboring point in a neighboring polygon. An updated fluid property is determined for the selected polygon using a variable diffusion rate, the variable diffusion rate based on the minimum diffusion rate, maximum diffusion rate, and angular difference between the diffusion-path vector and the pressure-gradient vector.

Variation of the pressure limits of flame propagation with tube diameter for propane-air mixtures

NASA Technical Reports Server (NTRS)

Belles, Frank E; Simon, Dorothy M

1951-01-01

An investigation was made of the variation of the pressure limits of flame propagation with tube diameter for quiescent propane with tube diameter for quiescent propane-air mixtures. Pressure limits were measured in glass tubes of six different inside diameters, with a precise apparatus. Critical diameters for flame propagation were calculated and the effect of pressure was determined. The critical diameters depended on the pressure to the -0.97 power for stoichiometric mixtures. The pressure dependence decreased with decreasing propane concentration. Critical diameters were related to quenching distance, flame speeds, and minimum ignition energy.

Directly measured cabin pressure conditions during Boeing 747-400 commercial aircraft flights.

PubMed

Kelly, Paul T; Seccombe, Leigh M; Rogers, Peter G; Peters, Matthew J

2007-07-01

In the low pressure environment of commercial aircraft, hypoxaemia may be common and accentuated in patients with lung or heart disease. Regulations specify a cabin pressure not lower than 750 hPa but it is not known whether this standard is met. This knowledge is important in determining the hazards of commercial flight for patients and the validity of current flight simulation tests. Using a wrist-watch recording altimeter, cabin pressure was recorded at 60 s intervals on 45 flights in Boeing 747-400 aircraft with three airlines. A log was kept of aircraft altitude using the in-flight display. Change in cabin pressure during flight, relationship between aircraft altitude and cabin pressure and proportion of flight time with cabin pressure approaching the minimum specified by regulation were determined. Flight duration averaged 10 h. Average cabin pressure during flight was 846 hPa. There was a linear fall in cabin pressure as the aircraft cruising altitude increased. At 10,300 m (34,000 ft) cabin pressure was 843 hPa and changed 8 hPa for every 300 m (1000 ft) change in aircraft altitude (r(2) = 0.993; P < 0.001). Lowest cabin pressure was 792 hPa at 12 200 m (40,000 ft) but during only 2% of flight time was cabin pressure less than 800 hPa. Cabin pressure is determined only by the engineering of the aircraft and its altitude and in the present study was always higher than required by regulation. Current fitness-to-fly evaluations simulate cabin conditions that passengers will not experience on these aircraft. There may be increased risks to patients should new or older aircraft operate nearer to the present minimum standard.

Relation between Pressure Balance Structures and Polar Plumes from Ulysses High Latitude Observations

NASA Technical Reports Server (NTRS)

Yamauchi, Yohei; Suess, Steven T.; Sakurai, Takashi

2002-01-01

Ulysses observations have shown that pressure balance structures (PBSs) are a common feature in high-latitude, fast solar wind near solar minimum. Previous studies of Ulysses/SWOOPS plasma data suggest these PBSs may be remnants of coronal polar plumes. Here we find support for this suggestion in an analysis of PBS magnetic structure. We used Ulysses magnetometer data and applied a minimum variance analysis to magnetic discontinuities in PBSs. We found that PBSs preferentially contain tangential discontinuities, as opposed to rotational discontinuities and to non-PBS regions in the solar wind. This suggests that PBSs contain structures like current sheets or plasmoids that may be associated with network activity at the base of plumes.

Relation Between Pressure Balance Structures and Polar Plumes from Ulysses High Latitude Observations

NASA Technical Reports Server (NTRS)

Yamauchi, Y.; Suess, Steven T.; Sakurai, T.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

Ulysses observations have shown that pressure balance structures (PBSs) are a common feature in high-latitude, fast solar wind near solar minimum. Previous studies of Ulysses/SWOOPS plasma data suggest these PBSs may be remnants of coronal polar plumes. Here we find support for this suggestion in an analysis of PBS magnetic structure. We used Ulysses magnetometer data and applied a minimum variance analysis to discontinuities. We found that PBSs preferentially contain tangential discontinuities, as opposed to rotational discontinuities and to non-PBS regions in the solar wind. This suggests that PBSs contain structures like current sheets or plasmoids that may be associated with network activity at the base of plumes.

Optimal Design and Operation of Permanent Irrigation Systems

NASA Astrophysics Data System (ADS)

Oron, Gideon; Walker, Wynn R.

1981-01-01

Solid-set pressurized irrigation system design and operation are studied with optimization techniques to determine the minimum cost distribution system. The principle of the analysis is to divide the irrigation system into subunits in such a manner that the trade-offs among energy, piping, and equipment costs are selected at the minimum cost point. The optimization procedure involves a nonlinear, mixed integer approach capable of achieving a variety of optimal solutions leading to significant conclusions with regard to the design and operation of the system. Factors investigated include field geometry, the effect of the pressure head, consumptive use rates, a smaller flow rate in the pipe system, and outlet (sprinkler or emitter) discharge.

Low-Pressure Capability of NASA Glenn's 10- by 10-Foot Supersonic Wind Tunnel Expanded

NASA Technical Reports Server (NTRS)

Roeder, James W.

2004-01-01

Extremely low dynamic pressure Q conditions are desired for space-related research including the testing of parachute designs and other decelerator concepts for future vehicles landing on Mars. Therefore, the low-pressure operating capability of the Abe Silverstein 10- by 10-foot Supersonic Wind Tunnel (10 10 SWT) at NASA Glenn Research Center was recently increased. Successful checkout tests performed in the fall of 2002 showed significantly reduced minimum operating pressures in the wind tunnel.

SORPTION OF VINCLOZOLIN AND ATRAZINE ON FOUR GEOSORBENTS

EPA Science Inventory

The objectives of this study were to evaluate the magnitude and kinetics of vinclozolin and atrazine sorption on one surface soil and three freshwater sediments using batch and column techniques. Data from miscible displacement column studies were analyzed using a two-domain, fir...

COSOLVENT EFFECTS ON SORPTION AND MOBILITY OF ORGANIC CONTAMINANTS IN SOILS

EPA Science Inventory

Batch equilibrium and column miscible displacement techniques were used to investigate the influence of an organic cosolvent (methanol) on the sorption and transport of three hydrophobic organic chemicals (HOCs) — naphthalene, phenanthrene, and diuron herbicide — in a sandy surfa...

Analysis of starvation effects on hydrodynamic lubrication in nonconforming contacts

NASA Technical Reports Server (NTRS)

Brewe, D. E.; Hamrock, B. J.

1981-01-01

The effects of lubricant starvation on minimum film thickness, under conditions of a hydrodynamic point contact, are determined by numerical methods where: (1) starvation is effected by varying the fluid inlet level; (2) the Reynolds boundary conditions are applied at the cavitation boundary; and (3) zero pressure is stipulated at the meniscus or inlet boundary. Seventy-four cases were used to numerically determine a minimum-film-thickness equation, as a function of the ratio of dimensionless load to dimensionless speed for varying degrees of starvation. A film reduction factor was in turn determined as a function of the fluid inlet level, and a starved, fully-flooded boundary was defined along with an expression determining the onset of starvation. It is found that as the degree of starvation increases, the minimum film thickness decreases gradually until the fluid inlet becomes critical. The changes in the inlet pressure buildup due to changing the available lubricant supply are presented in the form of three-dimensional isometric plots.

Axisymmetric inlet minimum weight design method

NASA Technical Reports Server (NTRS)

Nadell, Shari-Beth

1995-01-01

An analytical method for determining the minimum weight design of an axisymmetric supersonic inlet has been developed. The goal of this method development project was to improve the ability to predict the weight of high-speed inlets in conceptual and preliminary design. The initial model was developed using information that was available from inlet conceptual design tools (e.g., the inlet internal and external geometries and pressure distributions). Stiffened shell construction was assumed. Mass properties were computed by analyzing a parametric cubic curve representation of the inlet geometry. Design loads and stresses were developed at analysis stations along the length of the inlet. The equivalent minimum structural thicknesses for both shell and frame structures required to support the maximum loads produced by various load conditions were then determined. Preliminary results indicated that inlet hammershock pressures produced the critical design load condition for a significant portion of the inlet. By improving the accuracy of inlet weight predictions, the method will improve the fidelity of propulsion and vehicle design studies and increase the accuracy of weight versus cost studies.

Formulation of 3D Printed Tablet for Rapid Drug Release by Fused Deposition Modeling: Screening Polymers for Drug Release, Drug-Polymer Miscibility and Printability.

PubMed

Solanki, Nayan G; Tahsin, Md; Shah, Ankita V; Serajuddin, Abu T M

2018-01-01

The primary aim of this study was to identify pharmaceutically acceptable amorphous polymers for producing 3D printed tablets of a model drug, haloperidol, for rapid release by fused deposition modeling. Filaments for 3D printing were prepared by hot melt extrusion at 150°C with 10% and 20% w/w of haloperidol using Kollidon ® VA64, Kollicoat ® IR, Affinsiol ™ 15 cP, and HPMCAS either individually or as binary blends (Kollidon ® VA64 + Affinisol ™ 15 cP, 1:1; Kollidon ® VA64 + HPMCAS, 1:1). Dissolution of crushed extrudates was studied at pH 2 and 6.8, and formulations demonstrating rapid dissolution rates were then analyzed for drug-polymer, polymer-polymer and drug-polymer-polymer miscibility by film casting. Polymer-polymer (1:1) and drug-polymer-polymer (1:5:5 and 2:5:5) mixtures were found to be miscible. Tablets with 100% and 60% infill were printed using MakerBot printer at 210°C, and dissolution tests of tablets were conducted at pH 2 and 6.8. Extruded filaments of Kollidon ® VA64-Affinisol ™ 15 cP mixtures were flexible and had optimum mechanical strength for 3D printing. Tablets containing 10% drug with 60% and 100% infill showed complete drug release at pH 2 in 45 and 120 min, respectively. Relatively high dissolution rates were also observed at pH 6.8. The 1:1-mixture of Kollidon ® VA64 and Affinisol ™ 15 cP was thus identified as a suitable polymer system for 3D printing and rapid drug release. Copyright © 2018 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Stability of viscosity stratified flows down an incline: Role of miscibility and wall slip

NASA Astrophysics Data System (ADS)

Ghosh, Sukhendu; Usha, R.

2016-10-01

The effects of wall velocity slip on the linear stability of a gravity-driven miscible two-fluid flow down an incline are examined. The fluids have the matched density but different viscosity. A smooth viscosity stratification is achieved due to the presence of a thin mixed layer between the fluids. The results show that the presence of slip exhibits a promise for stabilizing the miscible flow system by raising the critical Reynolds number at the onset and decreasing the bandwidth of unstable wave numbers beyond the threshold of the dominant instability. This is different from its role in the case of a single fluid down a slippery substrate where slip destabilizes the flow system at the onset. Though the stability properties are analogous to the same flow system down a rigid substrate, slip is shown to delay the surface mode instability for any viscosity contrast. It has a damping/promoting effect on the overlap modes (which exist due to the overlap of critical layer of dominant disturbance with the mixed layer) when the mixed layer is away/close from/to the slippery inclined wall. The trend of slip effect is influenced by the location of the mixed layer, the location of more viscous fluid, and the mass diffusivity of the two fluids. The stabilizing characteristics of slip can be favourably used to suppress the non-linear breakdown which may happen due to the coexistence of the unstable modes in a flow over a substrate with no slip. The results of the present study suggest that it is desirable to design a slippery surface with appropriate slip sensitivity in order to meet a particular need for a specific application.

Compatibility Studies Of Blends Of PPG 4000 And PEG 4000 Using Viscosity Technique

NASA Astrophysics Data System (ADS)

Venkatramanan, K.; Arumugam, V.

2010-06-01

Certain properties of polymers can be enhanced by mixing it with another polymer. When two or more polymers are intimately mixed in a single continuous solid product, the composition is generally referred to as a polymer blend or polyblend. Depending upon the degree of miscibility or immiscibility, such a polyblend may resemble a random copolymer or a block or graft copolymer or it may show micro or macro heterogeneous separation into a multiphase system. Viscosity method is simple and it offers very useful information about the relationship between dilute solution properties and bulk structure of the polymer blend. The basic idea of using viscosity as a parameter for compatibility determination of polymer blends lies in the fact that in solution the repulsive interaction may cause shrinkage of polymer coils resulting in a viscosity of the polymer mixture that is lower than the value calculated from viscosities of the pure components on the assumption of the additive law. In the present study, an attempt has been made to blend PPG 4000 with PEG 4000 in 1,4 -Dioxane at 303K at 1% concentration. The blend compositions were formed in the ratio 0:1, 0.2:0.8, 0.4:0.6, 0.5:0.5, 0.6:0.4, 0.8:0.2, 1:0. Relative viscosity of the blend compositions was determined and the values are nonlinear which showed incompatibility. Miscibility nature of the blends were determined further using additive law, log additive law and free volume additive law and the experimental values in all the cases showed negative deviation which is a characteristic of immiscible blend. The miscibility nature of the blend was further confirmed through density, ultrasonic velocity, refractive index and other techniques. The blend showed immiscibility.

The influence of guaifenesin and ketoprofen on the properties of hot-melt extruded polyethylene oxide films.

PubMed

Crowley, Michael M; Fredersdorf, Anke; Schroeder, Britta; Kucera, Shawn; Prodduturi, Suneela; Repka, Michael A; McGinity, James W

2004-08-01

Films containing polyethylene oxide (PEO) and a model drug, either guaifenesin (GFN) or ketoprofen (KTP), were prepared by hot-melt extrusion. The thermal properties of the hot-melt extruded films were investigated using differential scanning calorimetry (DSC). Scanning electron microscopy (SEM) was used to examine the surface morphology of the films, and wide angle X-ray diffraction (XRD) was used to investigate the crystalline properties of the polymer, drugs and physical mixtures as well as the solid state structure of the films. The stability of the polymer was studied using gel permeation chromatography. The mechanical properties, including percent elongation and tensile strength of the films, were determined on an Instron according to American Society for Testing Materials (ASTM) procedures. The Hansen solubility parameter was calculated using the Hoftyzer or van Krevelen method to estimate the likelihood of drug--polymer miscibility. Both GFN and KTP were stable during the extrusion process. Melting points corresponding to the crystalline drugs were not observed in the films. Crystallization of GFN on the surface of the film was observed at all concentrations studied, however KTP crystallization did not occur until reaching the 15% level. Guaifenesin and ketoprofen were found to decrease drive load, increase PEO stability and plasticize the polymer during extrusion. The Hansen solubility parameters predicted miscibility between PEO and KTP and poor miscibility between PEO and GFN. The predictions of the solubility parameters were in agreement with the XRD and SEM results. The percent elongation decreased with increasing GFN concentrations and significantly increased with increasing levels of KTP. Both GFN and KTP decreased the tensile strength of the extruded film.

Effect of gamma ray on poly(lactic acid)/poly(vinyl acetate-co-vinyl alcohol) blends as biodegradable food packaging films

NASA Astrophysics Data System (ADS)

Razavi, Seyed Mohammad; Dadbin, Susan; Frounchi, Masoud

2014-03-01

Poly(lactic acid) (PLA)/poly(vinyl acetate-co-vinyl alcohol) [P(VAc-co-VA)] blends as new transparent film packaging materials were prepared at various blend compositions and different vinyl alcohol contents. The blends and pure PLA were irradiated by gamma rays to investigate the extent of changes in the packaging material during gamma ray sterilization process. The miscibility of the blends was dependent on the blend composition and vinyl alcohol content; gamma irradiation had little effect on the extent of miscibility. The glass transition temperature of pure PLA and PLA/P(VAc-co-VA) miscible blends reduced after irradiation. On the other hand in PLA/P(VAc-co-VA) immiscible blends, while the glass transition temperature of the PLA phase decreased; that of the copolymer phase slightly increased. The reduction in the glass transition was about 10 percent for samples irradiated with 50 kGy indicating dominance of chain scission of PLA molecules at high irradiation dose. The latter was verified by drop in mechanical properties of pure PLA after exposing to gamma irradiation at 50 kGy. Blending of PLA with the copolymer P(VAc-co-VA) compensated greatly the adverse effects of irradiation on PLA. The oxygen-barrier property of the blend was superior to the neat PLA and remained almost intact with irradiation. The un-irradiated and irradiated blends had excellent transparency. Gamma ray doses used for sterilization purposes are usually less than 20 kGy. It was shown that gamma irradiation at 20 kGy had no or little adverse effects on PLA/P(VAc-co-VA) blends mechanical and gas barrier properties.

Increased physical stability and improved dissolution properties of itraconazole, a class II drug, by solid dispersions that combine fast- and slow-dissolving polymers.

PubMed

Six, Karel; Verreck, Geert; Peeters, Jef; Brewster, Marcus; Van Den Mooter, Guy

2004-01-01

Solid dispersions were prepared of itraconazole-Eudragit E100, itraconazole-PVPVA64, and itraconazole-Eudragit E100/PVPVA64 using a corotating twin-screw hot-stage extruder. Modulated temperature differential scanning calorimetry (MTDSC) was used to evaluate the miscibility of the extrudates, and dissolution experiments were performed in simulated gastric fluid without pepsin (SGF(sp)). Itraconazole and Eudragit E100 are miscible up to 13% w/w drug loading. From that concentration on, phase separation is observed. Pharmaceutical performance of this dispersion was satisfactory because 80% of the drug dissolved after 30 min. Extrudates of itraconazole and PVPVA64 were completely miscible but the pharmaceutical performance was low, with 45% of drug dissolved after 3 h. Combination of both polymers in different ratios, with a fixed drug loading of 40% w/w, was evaluated. MTDSC results clearly indicated a two-phase system consisting of itraconazole-Eudragit E100 and itraconazole-PVPVA64 phases. In these extrudates, no free crystalline or glassy clusters of itraconazole were observed; all itraconazole was mixed with one of both polymers. The pharmaceutical performance was tested in SGF(sp) for different polymer ratios, and Eudragit E100/PVPVA64 ratios of 50/50 and 60/40 showed significant increases in dissolution rate and level. Polymer ratios of 70/30 and 80/20, on the other hand, had a release of 85% after 30 min. Precipitation of the drug was never observed. The combination of the two polymers provides a solid dispersion with good dissolution properties and improved physical stability compared with the binary solid dispersions of itraconazole. Copyright 2004 Wiley-Liss, Inc.

Continuous melt granulation: Influence of process and formulation parameters upon granule and tablet properties.

PubMed

Monteyne, Tinne; Vancoillie, Jochem; Remon, Jean-Paul; Vervaet, Chris; De Beer, Thomas

2016-10-01

The pharmaceutical industry has a growing interest in alternative manufacturing models allowing automation and continuous production in order to improve process efficiency and reduce costs. Implementing a switch from batch to continuous processing requires fundamental process understanding and the implementation of quality-by-design (QbD) principles. The aim of this study was to examine the relationship between formulation-parameters (type binder, binder concentration, drug-binder miscibility), process-parameters (screw speed, powder feed rate and granulation temperature), granule properties (size, size distribution, shape, friability, true density, flowability) and tablet properties (tensile strength, friability, dissolution rate) of four different drug-binder formulations using Design of experiments (DOE). Two binders (polyethylene glycol (PEG) and Soluplus®) with a different solid state, semi-crystalline vs amorphous respectively, were combined with two model-drugs, metoprolol tartrate (MPT) and caffeine anhydrous (CAF), both having a contrasting miscibility with the binders. This research revealed that the granule properties of miscible drug-binder systems depended on the powder feed rate and barrel filling degree of the granulator whereas the granule properties of immiscible systems were mainly influenced by binder concentration. Using an amorphous binder, the tablet tensile strength depended on the granule size. In contrast, granule friability was more important for tablet quality using a brittle binder. However, this was not the case for caffeine-containing blends, since these phenomena were dominated by the enhanced compression properties of caffeine Form I, which was formed during granulation. Hence, it is important to gain knowledge about formulation behavior during processing since this influences the effect of process parameters onto the granule and tablet properties. Copyright © 2016 Elsevier B.V. All rights reserved.

Relating hydrogen-bonding interactions with the phase behavior of naproxen/PVP K 25 solid dispersions: evaluation of solution-cast and quench-cooled films.

PubMed

Paudel, Amrit; Nies, Erik; Van den Mooter, Guy

2012-11-05

In this work, we investigated the relationship between various intermolecular hydrogen-bonding (H-bonding) interactions and the miscibility of the model hydrophobic drug naproxen with the hydrophilic polymer polyvinylpyrrolidone (PVP) across an entire composition range of solid dispersions prepared by quasi-equilibrium film casting and nonequilibrium melt quench cooling. The binary phase behavior in solid dispersions exhibited substantial processing method dependence. The solid state solubility of crystalline naproxen in PVP to form amorphous solid dispersions was 35% and 70% w/w naproxen in solution-cast films and quench-cooled films, respectively. However, the presence of a single mixed phase glass transition indicated the amorphous miscibility to be 20% w/w naproxen for the films, beyond which amorphous-amorphous and/or crystalline phase separations were apparent. This was further supported by the solution state interactions data such as PVP globular size distribution and solution infrared spectral profiles. The borderline melt composition showed cooling rate dependence of amorphization. The glass transition and melting point depression profiles of the system were treated with the analytical expressions based on Flory-Huggins mixing theory to interpolate the equilibrium solid solubility. FTIR analysis and subsequent spectral deconvolution revealed composition and miscibility dependent variations in the strength of drug-polymer intermolecular H-bonding. Two types of H-bonded populations were evidenced from 25% w/w and 35% w/w naproxen in solution-cast films and quench-cooled films, respectively, with the higher fraction of strongly H-bonded population in the drug rich domains of phase separated amorphous film compositions and highly drug loaded amorphous quench-cooled dispersions.

Construction of drug-polymer thermodynamic phase diagrams using Flory-Huggins interaction theory: identifying the relevance of temperature and drug weight fraction to phase separation within solid dispersions.

PubMed

Tian, Yiwei; Booth, Jonathan; Meehan, Elizabeth; Jones, David S; Li, Shu; Andrews, Gavin P

2013-01-07

Amorphous drug-polymer solid dispersions have the potential to enhance the dissolution performance and thus bioavailability of BCS class II drug compounds. The principle drawback of this approach is the limited physical stability of amorphous drug within the dispersion. Accurate determination of the solubility and miscibility of drug in the polymer matrix is the key to the successful design and development of such systems. In this paper, we propose a novel method, based on Flory-Huggins theory, to predict and compare the solubility and miscibility of drug in polymeric systems. The systems chosen for this study are (1) hydroxypropyl methylcellulose acetate succinate HF grade (HPMCAS-HF)-felodipine (FD) and (2) Soluplus (a graft copolymer of polyvinyl caprolactam-polyvinyl acetate-polyethylene glycol)-FD. Samples containing different drug compositions were mixed, ball milled, and then analyzed by differential scanning calorimetry (DSC). The value of the drug-polymer interaction parameter χ was calculated from the crystalline drug melting depression data and extrapolated to lower temperatures. The interaction parameter χ was also calculated at 25 °C for both systems using the van Krevelen solubility parameter method. The rank order of interaction parameters of the two systems obtained at this temperature was comparable. Diagrams of drug-polymer temperature-composition and free energy of mixing (ΔG(mix)) were constructed for both systems. The maximum crystalline drug solubility and amorphous drug miscibility may be predicted based on the phase diagrams. Hyper-DSC was used to assess the validity of constructed phase diagrams by annealing solid dispersions at specific drug loadings. Three different samples for each polymer were selected to represent different regions within the phase diagram.

Stability of miscible core?annular flows with viscosity stratification

NASA Astrophysics Data System (ADS)

Selvam, B.; Merk, S.; Govindarajan, Rama; Meiburg, E.

The linear stability of variable viscosity, miscible core-annular flows is investigated. Consistent with pipe flow of a single fluid, the flow is stable at any Reynolds number when the magnitude of the viscosity ratio is less than a critical value. This is in contrast to the immiscible case without interfacial tension, which is unstable at any viscosity ratio. Beyond the critical value of the viscosity ratio, the flow can be unstable even when the more viscous fluid is in the core. This is in contrast to plane channel flows with finite interface thickness, which are always stabilized relative to single fluid flow when the less viscous fluid is in contact with the wall. If the more viscous fluid occupies the core, the axisymmetric mode usually dominates over the corkscrew mode. It is demonstrated that, for a less viscous core, the corkscrew mode is inviscidly unstable, whereas the axisymmetric mode is unstable for small Reynolds numbers at high Schmidt numbers. For the parameters under consideration, the switchover occurs at an intermediate Schmidt number of about 500. The occurrence of inviscid instability for the corkscrew mode is shown to be consistent with the Rayleigh criterion for pipe flows. In some parameter ranges, the miscible flow is seen to be more unstable than its immiscible counterpart, and the physical reasons for this behaviour are discussed.A detailed parametric study shows that increasing the interface thickness has a uniformly stabilizing effect. The flow is least stable when the interface between the two fluids is located at approximately 0.6 times the tube radius. Unlike for channel flow, there is no sudden change in the stability with radial location of the interface. The instability originates mainly in the less viscous fluid, close to the interface.

Physicochemical characterization of spray-dried PLGA/PEG microspheres, and preliminary assessment of biological response.

PubMed

Javiya, Curie; Jonnalagadda, Sriramakamal

2016-09-01

The use of spray-drying to prepare blended PLGA:PEG microspheres with lower immune detection. To study physical properties, polymer miscibility and alveolar macrophage response for blended PLGA:PEG microspheres prepared by a laboratory-scale spray-drying process. Microspheres were prepared by spray-drying 0-20% w/w ratios of PLGA 65:35 and PEG 3350 in dichloromethane. Particle size and morphology was studied using scanning electron microscopy. Polymer miscibility and residual solvent levels evaluated by thermal analysis (differential scanning calorimetry - DSC and thermogravimetric analysis - TGA). Immunogenicity was assessed in vitro by response of rat alveolar macrophages (NR8383) by the MTT-based cell viability assay and reactive oxygen species (ROS) detection. The spray dried particles were spherical, with a size range of about 2-3 µm and a yield of 16-60%. Highest yield was obtained at 1% PEG concentration. Thermal analysis showed a melting peak at 59 °C (enthalpy: 170.61 J/g) and a degradation-onset of 180 °C for PEG 3350. PLGA 65:35 was amorphous, with a Tg of 43 °C. Blended PLGA:PEG microspheres showed a delayed degradation-onset of 280 °C, and PEG enthalpy-loss corresponding to 15% miscibility of PEG in PLGA. NR8383 viability studies and ROS detection upon exposure to these cells suggested that blended PLGA:PEG microspheres containing 1 and 5% PEG are optimal in controling cell proliferation and activation. This research establishes the feasibility of using a spray-drying process to prepare spherical particles (2-3 µm) of molecularly-blended PLGA 65:35 and PEG 3350. A PEG concentration of 1-5% was optimal to maximize process yield, with minimal potential for immune detection.

Pressure ulcer and patient characteristics--A point prevalence study in a tertiary hospital of India based on the European Pressure Ulcer Advisory Panel minimum data set.

PubMed

Mehta, Chitra; George, Joby V; Mehta, Yatin; Wangmo, Namgyal

2015-08-01

Pressure ulcers is a frequent problem in hospitalized patients. Several prevalence studies have been conducted across the globe. Little information is available regarding prevalence of pressure ulcers in India. The aim was to identify the prevalence of pressure ulcers in one of the tertiary hospital in northern India and the factors associated with its development. A cross sectional point prevalence study. European Pressure Ulcer Advisory Panel (EPUAP) data collection form. Ethics approval was obtained prior to start of the study. Total of 358 patients were enrolled in the study. All patients above 18 years of age admitted in intensive care units and wards were included in the study. Patients admitted in emergency, day care, coronary care unit were excluded because of their short duration of hospital stay (varies from 24 to 72 h usually). All patients admitted before midnight on the predetermined day were included. The Braden scale was used to identify the risk of developing pressure ulcers. European Pressure ulcer advisory panel (EPUAP) minimum data set was used to collect prevalence data. The overall prevalence rate was 7.8%.The sacrum and heel were more commonly affected. Grade III pressure ulcers were the most common (42.8%). The pressure ulcer prevalence rate in our hospital was lower than that published in international studies. Severe forms of pressure ulcers were commonly encountered This data provides background information that may help us in developing protocols for applying effective practices for prevention of pressure ulcers. Copyright © 2015 Tissue Viability Society. Published by Elsevier Ltd. All rights reserved.

CO{sub 2}-philic oligomers as novel solvents for CO{sub 2} absorption

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, Matthew B; Luebke, David R; Enick, Robert M

2010-01-01

Desirable properties for an oligomeric CO{sub 2}-capture solvent in an integrated gasification combined cycle (IGCC) plant include high selectivity for CO{sub 2} over H{sub 2} and water, low viscosity, low vapor pressure, low cost, and minimal environmental, health, and safety impacts. The neat solvent viscosity and solubility of CO{sub 2}, measured via bubble-point loci and presented on a pressure−composition diagram (weight basis), and water miscibility in CO{sub 2}-philic solvents have been determined and compared to results obtained with Selexol, a commercial oligomeric CO{sub 2} solvent. The solvents tested include polyethyleneglycol dimethylether (PEGDME), polypropyleneglycol dimethylether (PPGDME), polypropyleneglycol diacetate (PPGDAc), polybutyleneglycol diacetatemore » (PBGDAc), polytetramethyleneetherglycol diacetate (PTMEGDAc), glyceryl triacetate (GTA), polydimethyl siloxane (PDMS), and perfluorpolyether (PFPE) that has a perfluorinated propyleneglycol monomer unit. Overall, PDMS and PPGDME are the best oligomeric solvents tested and exhibit properties that make them very promising alternatives for the selective absorption of CO{sub 2} from a mixed gas stream, especially if the absorption of water is undesirable.« less

Bovine insulin-phosphatidylcholine mixed Langmuir monolayers: behavior at the air-water interface.

PubMed

Pérez-López, S; Blanco-Vila, N M; Vila-Romeu, N

2011-08-04

The behavior of the binary mixed Langmuir monolayers of bovine insulin (INS) and phosphatidylcholine (PC) spread at the air-water interface was investigated under various subphase conditions. Pure and mixed monolayers were spread on water, on NaOH and phosphate-buffered solutions of pH 7.4, and on Zn(2+)-containing solutions. Miscibility and interactions between the components were studied on the basis of the analysis of the surface pressure (π)-mean molecular area (A) isotherms, surface compression modulus (C(s)(-1))-π curves, and plots of A versus mole fraction of INS (X(INS)). Our results indicate that intermolecular interactions between INS and PC depend on both the monolayer state and the structural characteristics of INS at the interface, which are strongly influenced by the subphase pH and salt content. Brewster angle microscopy (BAM) was applied to investigate the peptide aggregation pattern at the air-water interface in the presence of the studied lipid under any experimental condition investigated. The influence of the lipid on the INS behavior at the interface strongly depends on the subphase conditions.

Neutrally Charged Gas/Liquid Interface by a Catanionic Langmuir Monolayer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vaknin, David; Bu, Wei

Surface-sensitive synchrotron X-ray scattering and spectroscopic experiments were performed to explore the characteristics of Langmuir monolayers of oppositely charged mixed amphiphiles. A premixed (molar 1:1 stearic acid/stearylamine) solution was spread as a monolayer at the gas/liquid interface on pure water and on mono- and divalent salt solutions, revealing that the negatively charged carboxyl groups and positively charged amine groups are miscible into one another and tend to bond together to form a nearly neutral surface. Similar control experiments on pure stearic acid (SA) and stearylamine (ST) were also conducted for comparison. Due to the strong bonding, hexagonal structures in smallmore » domains with acyl-chains normal to the liquid surface are formed at zero surface pressures, that is, at molecular areas much larger than those of the densely packed acyl chains. In-plane X-ray diffraction indicates that the catanionic surface is highly ordered and modifies the structure of the water surface and thus can serve as a model system for interactions of an amino acid template with solutes.« less

Compatibilized Immiscible Polymer Blends for Gas Separations

PubMed Central

Panapitiya, Nimanka; Wijenayake, Sumudu; Nguyen, Do; Karunaweera, Chamaal; Huang, Yu; Balkus, Kenneth; Musselman, Inga; Ferraris, John

2016-01-01

Membrane-based gas separation has attracted a great deal of attention recently due to the requirement for high purity gasses in industrial applications like fuel cells, and because of environment concerns, such as global warming. The current methods of cryogenic distillation and pressure swing adsorption are energy intensive and costly. Therefore, polymer membranes have emerged as a less energy intensive and cost effective candidate to separate gas mixtures. However, the use of polymeric membranes has a drawback known as the permeability-selectivity tradeoff. Many approaches have been used to overcome this limitation including the use of polymer blends. Polymer blending technology synergistically combines the favorable properties of different polymers like high gas permeability and high selectivity, which are difficult to attain with a single polymer. During polymer mixing, polymers tend to uncontrollably phase separate due to unfavorable thermodynamics, which limits the number of completely miscible polymer combinations for gas separations. Therefore, compatibilizers are used to control the phase separation and to obtain stable membrane morphologies, while improving the mechanical properties. In this review, we focus on immiscible polymer blends and the use of compatibilizers for gas separation applications. PMID:28773766

Zeolitic imidazolate framework-methacrylate composite monolith characterization by inverse gas chromatography.

PubMed

Yusuf, Kareem; Badjah-Hadj-Ahmed, Ahmed Yacine; Aqel, Ahmad; Aouak, Taieb; ALOthman, Zeid Abdullah

2016-04-22

Thermodynamic characterization of butyl methacrylate-co-ethylene dimethacrylate neat monolith and zeolitic imidazolate framework-8 incorporated with butyl methacrylate-co-ethylene dimethacrylate composite monolith were studied using inverse gas chromatography at infinite dilution under 1MPa column pressure and various column temperatures. The free energy of adsorption (ΔGA), enthalpy of adsorption (ΔHA) and entropy of adsorption (ΔSA) were determined using a series of n-alkanes. The dispersive component of surface energy (γS(D)) was estimated by Dorris-Gray and Schultz et al. The composite monolith showed a more energetic surface than the neat monolith. The acidic, KA, and basic, KD, parameters for both materials were estimated using a group of polar probes. A basic character was concluded with more basic behavior for the neat monolith. Flory-Huggins parameter, χ, was taken as a measure of miscibility between the probes with the low molecular weight and the high molecular weight monolith. Inverse gas chromatography provides a better understanding of the role of incorporated zeolitic imidazolate framework (ZIF-8) into the polymer matrix in its monolithic form. Copyright © 2016 Elsevier B.V. All rights reserved.

Uranus and Neptune: internal heat flow

NASA Astrophysics Data System (ADS)

Hofstadter, M. D.; Simon, A. A.; Banfield, D. J.; Fortney, J. J.; Hayes, A. G., Jr.; Hedman, M.; Hospodarsky, G. B.; Mandt, K.; Showalter, G. M.; Soderlund, K. M.; Turtle, E. P.; Hofstadter, M. D.; Sayanagi, K. M.; Simon, A. A.; Banfield, D. J.; Fortney, J. J.; Hayes, A.; Hedman, M.; Hospodarsky, G. B.; Mandt, K.; Showalter, G. M.; Soderlund, K. M.; Turtle, E. P.; Nettelmann, N.; Scheibe, L.; Redmer, R.

2017-12-01

Uranus and Neptune offer unique possibilities to study the behavior of gas-ice-rock mixtures at high pressures, the formation of planets, planetary magnetic field generation [1], and planetary atmospheres. While Uranus and Neptune interior models have been constructed that satisfy some of the observational constraints, so far there are no physically motivated models that are consistent with all of them. Especially the observed intrinsic heat fluxes pose challenges [2]. Here I present the thermal boundary layer approach [3] to explain both the extraordinary low heat flux of Uranus and the high heat flux of Neptune, and discuss implications. In particular, current models suggest miscibility of ices with rocks at P>1 Mbar and super-solar ice-to-rock ratios, for Uranus an irradiated exoplanet-like evolution in equilibrium with the stellar incident flux, and fully convective deep interiors. The Figure illustrates such an ice giant interior model.[1] Soderlund K.M., Heimpel, M.H., King E.M. Aurnou J.M. (2013), Icarus 224, 97 [2] Guillot T. (2005), Annu. Rev. Earth Planet. Sci. 33, 493 [3] Nettelmann N., Wang K., Fortney J.J. et al (2016), Icarus 275, 107

40 CFR Table 3 to Subpart Ddddd of... - Operating Limits for Boilers and Process Heaters With Mercury Emission Limits and Boilers and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... minimum pressure drop and liquid flow-rate at or above the operating levels established during the... leak detection system alarm does not sound more than 5 percent of the operating time during a 6-month... control Maintain the minimum sorbent or carbon injection rate at or above the operating levels established...

40 CFR Table 3 to Subpart Ddddd of... - Operating Limits for Boilers and Process Heaters With Mercury Emission Limits and Boilers and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... minimum pressure drop and liquid flow-rate at or above the operating levels established during the... leak detection system alarm does not sound more than 5 percent of the operating time during a 6-month... control Maintain the minimum sorbent or carbon injection rate at or above the operating levels established...

Numerical design and optimization of hydraulic resistance and wall shear stress inside pressure-driven microfluidic networks.

PubMed

Damiri, Hazem Salim; Bardaweel, Hamzeh Khalid

2015-11-07

Microfluidic networks represent the milestone of microfluidic devices. Recent advancements in microfluidic technologies mandate complex designs where both hydraulic resistance and pressure drop across the microfluidic network are minimized, while wall shear stress is precisely mapped throughout the network. In this work, a combination of theoretical and modeling techniques is used to construct a microfluidic network that operates under minimum hydraulic resistance and minimum pressure drop while constraining wall shear stress throughout the network. The results show that in order to minimize the hydraulic resistance and pressure drop throughout the network while maintaining constant wall shear stress throughout the network, geometric and shape conditions related to the compactness and aspect ratio of the parent and daughter branches must be followed. Also, results suggest that while a "local" minimum hydraulic resistance can be achieved for a geometry with an arbitrary aspect ratio, a "global" minimum hydraulic resistance occurs only when the aspect ratio of that geometry is set to unity. Thus, it is concluded that square and equilateral triangular cross-sectional area microfluidic networks have the least resistance compared to all rectangular and isosceles triangular cross-sectional microfluidic networks, respectively. Precise control over wall shear stress through the bifurcations of the microfluidic network is demonstrated in this work. Three multi-generation microfluidic network designs are considered. In these three designs, wall shear stress in the microfluidic network is successfully kept constant, increased in the daughter-branch direction, or decreased in the daughter-branch direction, respectively. For the multi-generation microfluidic network with constant wall shear stress, the design guidelines presented in this work result in identical profiles of wall shear stresses not only within a single generation but also through all the generations of the microfluidic network under investigation. The results obtained in this work are consistent with previously reported data and suitable for a wide range of lab-on-chip applications.

33 CFR Appendix A to Part 154 - Guidelines for Detonation Flame Arresters

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CG-522). 1. Scope 1.1This standard provides the minimum requirements for design, construction.../Circ. 373/Rev. 1—Revised Standards for the Design, Testing and Locating of Devices to Prevent the... maximum design pressure drop for that maximum flow rate. 6.1.10Maximum operating pressure. 7. Materials 7...

Flight Demonstration of a Shock Location Sensor Using Constant Voltage Hot-Film Anemometry

NASA Technical Reports Server (NTRS)

Moes, Timothy R.; Sarma, Garimella R.; Mangalam, Siva M.

1997-01-01

Flight tests have demonstrated the effectiveness of an array of hot-film sensors using constant voltage anemometry to determine shock position on a wing or aircraft surface at transonic speeds. Flights were conducted at the NASA Dryden Flight Research Center using the F-15B aircraft and Flight Test Fixture (FTF). A modified NACA 0021 airfoil was attached to the side of the FTF, and its upper surface was instrumented to correlate shock position with pressure and hot-film sensors. In the vicinity of the shock-induced pressure rise, test results consistently showed the presence of a minimum voltage in the hot-film anemometer outputs. Comparing these results with previous investigations indicate that hot-film anemometry can identify the location of the shock-induced boundary layer separation. The flow separation occurred slightly forward of the shock- induced pressure rise for a laminar boundary layer and slightly aft of the start of the pressure rise when the boundary layer was tripped near the airfoil leading edge. Both minimum mean output and phase reversal analyses were used to identify the shock location.

Performance Charts for a Turbojet System

NASA Technical Reports Server (NTRS)

Karp, Irving M.

1947-01-01

Convenient charts are presented for computing the thrust, fuel consumption, and other performance values of a turbojet system. These charts take into account the effects of ram pressure, compressor pressure ratio, ratio of combustion-chamber-outlet temperature to atmospheric temperature, compressor efficiency, turbine efficiency, combustion efficiency, discharge-nozzle coefficient, losses in total pressure in the inlet to the jet-propulsion unit and in the combustion chamber, and variation in specific heats with temperature. The principal performance charts show clearly the effects of the primary variables and correction charts provide the effects of the secondary variables. The performance of illustrative cases of turbojet systems is given. It is shown that maximum thrust per unit mass rate of air flow occurs at a lower compressor pressure ratio than minimum specific fuel consumption. The thrust per unit mass rate of air flow increases as the combustion-chamber discharge temperature increases. For minimum specific fuel consumption, however, an optimum combustion-chamber discharge temperature exists, which in some cases may be less than the limiting temperature imposed by the strength temperature characteristics of present materials.

ORGANIC COSOLVENT EFFECTS ON THE SORPTION AND TRANSPORT OF NEUTRAL ORGANIC CHEMICALS

EPA Science Inventory

Soil column miscible displacement techniques were used to investigate the effects of an organic cosolvent (methanol) on the sorption and transport of three neutral organic chemicals; naphthalene, phenanthrene, and the herbicide diuron, through a sandy surface soil. A two-domain, ...

Simulation of Layered Magma Chambers.

ERIC Educational Resources Information Center

Cawthorn, Richard Grant

1991-01-01

The principles of magma addition and liquid layering in magma chambers can be demonstrated by dissolving colored crystals. The concepts of density stratification and apparent lack of mixing of miscible liquids is convincingly illustrated with hydrous solutions at room temperature. The behavior of interstitial liquids in "cumulus" piles…

HYDROLYSIS OF MTBE TO TBA IN GROUND WATER SAMPLES WITH HYDROCHLORIC ACID

EPA Science Inventory

Conventional sampling and analytical protocols have poor sensitivity for fuel oxygenates that are alcohols, such as tert-butyl alcohol (TBA). Because alcohols are miscible or highly soluble in water, alcohols are not efficiently transferred to the gas chromatograph for analysis....

NASA Research Announcement

NASA Technical Reports Server (NTRS)

Chiaramonte, Fran

2002-01-01

This paper presents viewgraphs of NASA's strategic and fundamental research program at the Office of Biological and Physical Research (OBPR). The topics include: 1) Colloid-Polymer Samples; 2) Pool Boiling Experiment; 3) The Dynamics of Miscible Interfaces: A Space Flight Experiment (MIDAS); and 4) ISS and Ground-based Facilities.

MISCIBLE FLUID DISPLACEMENT STABILITY IN UNCONFINED POROUS MEDIA: TWO-DIMENSIONAL FLOW EXPERIMENTS AND SIMULATIONS

EPA Science Inventory

In situ flushing groundwater remediation technologies, such as cosolvent flushing, rely on the stability of the interface between the resident and displacing fluids for efficient removal of contaminants. Contrasts in density and viscosity between the resident and displacing flui...

Physical properties of mixed dairy food proteins

USDA-ARS?s Scientific Manuscript database

Mixed food protein gels are complex systems, which changes functional behaviors such as gelling properties and viscosity depending on the miscibility of the proteins. We have noted that differences in co-solubility of mixed proteins created unique network structures and gel properties. The effects o...

4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

DOE Office of Scientific and Technical Information (OSTI.GOV)

Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes

2005-09-01

The objective of this research project is to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data to observe changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansasmore » City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 18 months of seismic monitoring, one baseline and six monitor surveys clearly imaged changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators.« less

Spiral pattern in a radial displacement in a Hele-Shaw cell

NASA Astrophysics Data System (ADS)

Ban, Mitsumasa; Nagatsu, Yuichiro; Hayashi, Atsushi; Kato, Yoshihiro; Tada, Yutaka

2008-11-01

When a reactive and miscible less-viscous liquid displaces a more-viscous liquid in a Hele-Shaw cell, reactive miscible viscous fingering takes place. We have experimentally shown that the pattern created by the displacement of a more-viscous fluid by a less-viscous one in a radial Hele-Shaw cell develops not radially but spirally when a more-viscous sodium polyacrylate solution is displaced by a less-viscous trivalent iron ion (Fe^3+) solution with a sufficiently high concentration of Fe^3+. Another experiment in order to investigate the mechanism of spiral pattern formation revealed that an instantaneous chemical reaction takes place between the two fluids and at high Fe^3+ concentrations it produces a film of the gel at the contact plane. The gel is formed by three-dimensional network structures between the polyacrylate solution and the trivalent iron ion (Fe^3+) solution. We have proposed a physical model that the gel's film is responsible for the form of the spiral pattern.

Solutal Marangoni flows of miscible liquids drive transport without surface contamination

NASA Astrophysics Data System (ADS)

Kim, Hyoungsoo; Muller, Koen; Shardt, Orest; Afkhami, Shahriar; Stone, Howard A.

2017-11-01

Mixing and spreading of different liquids are omnipresent in nature, life and technology, such as oil pollution on the sea, estuaries, food processing, cosmetic and beverage industries, lab-on-a-chip devices, and polymer processing. However, the mixing and spreading mechanisms for miscible liquids remain poorly characterized. Here, we show that a fully soluble liquid drop deposited on a liquid surface remains as a static lens without immediately spreading and mixing, and simultaneously a Marangoni-driven convective flow is generated, which are counterintuitive results when two liquids have different surface tensions. To understand the dynamics, we develop a theoretical model to predict the finite spreading time and length scales, the Marangoni-driven convection flow speed, and the finite timescale to establish the quasi-steady state for the Marangoni flow. The fundamental understanding of this solutal Marangoni flow may enable driving bulk flows and constructing an effective drug delivery and surface cleaning approach without causing surface contamination by immiscible chemical species.

Dispersion Morphology of Poly(methyl acrylate)/Silica Nanocomposites

DOE Office of Scientific and Technical Information (OSTI.GOV)

D Janes; J Moll; S Harton

Nearly monodisperse poly(methyl acrylate) (PMA) and spherical SiO{sub 2} nanoparticles (NP, d = 14 {+-} 4 nm) were co-cast from 2-butanone, a mutually good solvent and a displacer of adsorbed PMA from silica. The effects of NP content and post-casting sample history on the dispersion morphology were found by small-angle X-ray scattering supplemented by transmission electron microscopy. Analysis of the X-ray results show that cast and thermally annealed samples exhibited a nearly random particle dispersion. That the same samples, prior to annealing, were not well-dispersed is indicative of thermodynamic miscibility during thermal annealing over the range of NP loadings studied.more » A simple mean-field thermodynamic model suggests that miscibility results primarily from favorable polymer segment/NP surface interactions. The model also indicates, and experiments confirm, that subsequent exposure of the composites to the likely displacer ethyl acetate results in entropic destabilization and demixing into NP-rich and NP-lean phases.« less

Method for separating water soluble organics from a process stream by aqueous biphasic extraction

DOEpatents

Chaiko, David J.; Mego, William A.

1999-01-01

A method for separating water-miscible organic species from a process stream by aqueous biphasic extraction is provided. An aqueous biphase system is generated by contacting a process stream comprised of water, salt, and organic species with an aqueous polymer solution. The organic species transfer from the salt-rich phase to the polymer-rich phase, and the phases are separated. Next, the polymer is recovered from the loaded polymer phase by selectively extracting the polymer into an organic phase at an elevated temperature, while the organic species remain in a substantially salt-free aqueous solution. Alternatively, the polymer is recovered from the loaded polymer by a temperature induced phase separation (cloud point extraction), whereby the polymer and the organic species separate into two distinct solutions. The method for separating water-miscible organic species is applicable to the treatment of industrial wastewater streams, including the extraction and recovery of complexed metal ions from salt solutions, organic contaminants from mineral processing streams, and colorants from spent dye baths.

Miscibility Gap Closure, Interface Morphology, and Phase Microstructure of 3D Li xFePO 4 Nanoparticles from Surface Wetting and Coherency Strain

DOE PAGES

Welland, Michael J.; Karpeyev, Dmitry; O’Connor, Devin T.; ...

2015-09-10

We study the mesoscopic effects which suppress phase-segregation in Li xFePO 4 nanoparticles using a multiphysics phase-field model implement on a high performance cluster. We simulate 3D spherical particles of radii from 3nm to 40nm and examine the equilibrium microstructure and voltage profiles as a they depend on size and overall lithiation. The model includes anisotropic, concentration-dependent elastic moduli, misfit strain, and facet dependent surface wetting within a Cahn-Hilliard formulation. Here, we find that the miscibility gap vanishes for particles of radius ~ 5 nm, and the solubility limits change with overall particle lithiation. The corresponding voltage plateau, indicative ofmore » phase-segregation, changes in extent and also vanishes. Surface wetting is found to have a strong effect on stabilizing a variety of microstructures, exaggerating the shifting of solubility limits, and shortening the voltage plateau.« less

Nonconvective mixing of miscible ionic liquids.

PubMed

Frost, Denzil S; Machas, Michael; Perea, Brian; Dai, Lenore L

2013-08-13

Ionic liquids (ILs) are ionic compounds that are liquid at room temperature. We studied the spontaneous mixing behavior between two ILs, ethylammonium nitrate (EAN) and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]), and observed notable phenomena. Experimental studies showed that the interface between the two ILs was unusually long-lived, despite the ILs being miscible with one another. Molecular dynamics (MD) simulations supported these findings and provided insight into the micromixing behavior of the ILs. We found that not only did the ions experience slow diffusion as they mix but also exhibited significant ordering into distinct regions. We suspect that this ordering disrupted concentration gradients in the direction normal to the interface, thus hindering diffusion in this direction and allowing the macroscopic interface to remain for long periods of time. Intermolecular interactions responsible for this behavior included the O-NH interaction between the EAN ions and the carbon chain-carbon chain interactions between the [BMIM](+) cations, which associate more strongly in the mixed state than in the pure IL state.

High-temperature phase relations and thermodynamics in the iron-lead-sulfur system

NASA Astrophysics Data System (ADS)

Eric, R. Hurman; Ozok, Hakan

1994-01-01

The PbS activities in FeS-PbS liquid mattes were obtained at 1100 °C and 1200 °C by the dew-point method. Negative deviations were observed, and the liquid-matte solutions were modeled by the Krupkowski formalism. The liquid boundaries of the FeS-PbS phase diagram were derived from the model equations yielding a eutectic temperature of 842 °C at X Pbs = 0.46. A phase diagram of the pseudobinary FeS-PbS was also verified experimentally by quenching samples equilibrated in evacuated and sealed silica capsules. No terminal solid solution ranges could be found. Within the Fe-Pb-S ternary system, the boundaries of the immiscibility region together with the tie-line distributions were established at 1200 °C. Activities of Pb were measured by the dew-point technique along the metal-rich boundary of the miscibility gap. Activities of Fe, Pb, and S, along the miscibility gap were also calculated by utilizing the bounding binary thermodynamics, phase equilibria, and tie-lines.

Abnormal strong burn-in degradation of highly efficient polymer solar cells caused by spinodal donor-acceptor demixing

PubMed Central

Li, Ning; Perea, José Darío; Kassar, Thaer; Richter, Moses; Heumueller, Thomas; Matt, Gebhard J.; Hou, Yi; Güldal, Nusret S.; Chen, Haiwei; Chen, Shi; Langner, Stefan; Berlinghof, Marvin; Unruh, Tobias; Brabec, Christoph J.

2017-01-01

The performance of organic solar cells is determined by the delicate, meticulously optimized bulk-heterojunction microstructure, which consists of finely mixed and relatively separated donor/acceptor regions. Here we demonstrate an abnormal strong burn-in degradation in highly efficient polymer solar cells caused by spinodal demixing of the donor and acceptor phases, which dramatically reduces charge generation and can be attributed to the inherently low miscibility of both materials. Even though the microstructure can be kinetically tuned for achieving high-performance, the inherently low miscibility of donor and acceptor leads to spontaneous phase separation in the solid state, even at room temperature and in the dark. A theoretical calculation of the molecular parameters and construction of the spinodal phase diagrams highlight molecular incompatibilities between the donor and acceptor as a dominant mechanism for burn-in degradation, which is to date the major short-time loss reducing the performance and stability of organic solar cells. PMID:28224984

Viscous and gravitational contributions to mixing during vertical brine transport in water-saturated porous media

PubMed Central

Flowers, Tracey C.; Hunt, James R.

2010-01-01

The transport of fluids miscible with water arises in groundwater contamination and during remediation of the subsurface environment. For concentrated salt solutions, i.e., brines, the increased density and viscosity determine mixing processes between these fluids and ambient groundwater. Under downward flow conditions, gravitational and viscous forces work against each other to determine the interfacial mixing processes. Historically, mixing has been modeled as a dispersive process, as viscous fingering, and as a combination of both using approaches that were both analytical and numerical. A compilation of previously reported experimental data on vertical miscible displacements by fluids with significant density and viscosity contrasts reveals some agreement with a stability analysis presented by Hill (1952). Additional experimental data on one-dimensional dispersion during downward displacement of concentrated salt solutions by freshwater and freshwater displacement by brines support the stability analysis and provides an empirical representation for dispersion coefficients as functions of a gravity number and a mobility ratio. PMID:20300476

Investigation of phase diagrams and physical stability of drug-polymer solid dispersions.

PubMed

Lu, Jiannan; Shah, Sejal; Jo, Seongbong; Majumdar, Soumyajit; Gryczke, Andreas; Kolter, Karl; Langley, Nigel; Repka, Michael A

2015-01-01

Solid dispersion technology has been widely explored to improve the solubility and bioavailability of poorly water-soluble compounds. One of the critical drawbacks associated with this technology is the lack of physical stability, i.e. the solid dispersion would undergo recrystallization or phase separation thus limiting a product's shelf life. In the current study, the melting point depression method was utilized to construct a complete phase diagram for felodipine (FEL)-Soluplus® (SOL) and ketoconazole (KTZ)-Soluplus® (SOL) binary systems, respectively, based on the Flory-Huggins theory. The miscibility or solubility of the two compounds in SOL was also determined. The Flory-Huggins interaction parameter χ values of both systems were calculated as positive at room temperature (25 °C), indicating either compound was miscible with SOL. In addition, the glass transition temperatures of both solid dispersion systems were theoretically predicted using three empirical equations and compared with the practical values. Furthermore, the FEL-SOL solid dispersions were subjected to accelerated stability studies for up to 3 months.

CPAP Devices for Emergency Prehospital Use: A Bench Study.

PubMed

Brusasco, Claudia; Corradi, Francesco; De Ferrari, Alessandra; Ball, Lorenzo; Kacmarek, Robert M; Pelosi, Paolo

2015-12-01

CPAP is frequently used in prehospital and emergency settings. An air-flow output minimum of 60 L/min and a constant positive pressure are 2 important features for a successful CPAP device. Unlike hospital CPAP devices, which require electricity, CPAP devices for ambulance use need only an oxygen source to function. The aim of the study was to evaluate and compare on a bench model the performance of 3 orofacial mask devices (Ventumask, EasyVent, and Boussignac CPAP system) and 2 helmets (Ventukit and EVE Coulisse) used to apply CPAP in the prehospital setting. A static test evaluated air-flow output, positive pressure applied, and FIO2 delivered by each device. A dynamic test assessed airway pressure stability during simulated ventilation. Efficiency of devices was compared based on oxygen flow needed to generate a minimum air flow of 60 L/min at each CPAP setting. The EasyVent and EVE Coulisse devices delivered significantly higher mean air-flow outputs compared with the Ventumask and Ventukit under all CPAP conditions tested. The Boussignac CPAP system never reached an air-flow output of 60 L/min. The EasyVent had significantly lower pressure excursion than the Ventumask at all CPAP levels, and the EVE Coulisse had lower pressure excursion than the Ventukit at 5, 15, and 20 cm H2O, whereas at 10 cm H2O, no significant difference was observed between the 2 devices. Estimated oxygen consumption was lower for the EasyVent and EVE Coulisse compared with the Ventumask and Ventukit. Air-flow output, pressure applied, FIO2 delivered, device oxygen consumption, and ability to maintain air flow at 60 L/min differed significantly among the CPAP devices tested. Only the EasyVent and EVE Coulisse achieved the required minimum level of air-flow output needed to ensure an effective therapy under all CPAP conditions. Copyright © 2015 by Daedalus Enterprises.

Carbon-bearing MgSiO3 melt at deep mantle conditions

NASA Astrophysics Data System (ADS)

Ghosh, D. B.; Bajgain, S. K.; Mookherjee, M.; Karki, B. B.

2016-12-01

Carbon di-oxide and water are two important volatiles that are often present in silicate magmas and volcanic eruptions. To address the influence of these volatiles in deep seated melts, their properties (e.g., structure, transport, thermodynamics) at relevant pressure-temperature (P-T) conditions along with compositional variance need to be explored. MgSiO3 being one of the major components of the mantle, the study of carbonated MgSiO3 melts is of great contextual relevance. In the present work we investigate the structure and thermodynamics of carbon bearing MgSiO3 melts under conditions of the entire mantle.Our first-principles molecular dynamics (MD) simulations of the MgSiO3-CO2 system show that pressure profoundly influences the behavior of carbon-bearing silicate melts. Our results encompassing from 5 - 30 wt.% CO2 in MgSiO3 demonstrate that: (1) carbon speciation consists of distinct molecular CO2 and carbonate ions ( (CO3)2-) below 15 GPa and interestingly almost all of the carbonate ions are bound to Mg polyhedra; (2) with compression they evolve to silicon-polyhedral bound carbonate (along with Mg polyhedra bound), CO4 , and di-carbonate species. Accordingly, carbon solubility in the silicate melt becomes nearly ideal and carbon remains completely miscible with increasing pressure. Carbon reduces the melt density modestly by 0.015 to 0.005 g cm-3 per wt.% CO2 between 15 and 140 GPa. These results imply that deep-seated silicate melts above and below the transition zone, and atop the core-mantle boundary may be able to sequester significant amounts of carbon without making melts gravitationally unstable.

Surface phase behavior and microstructure of lipid/PEG-emulsifier monolayer-coated microbubbles.

PubMed

Borden, Mark A; Pu, Gang; Runner, Gabriel J; Longo, Marjorie L

2004-06-01

Langmuir trough methods and fluorescence microscopy were combined to investigate the phase behavior and microstructure of monolayer shells coating micron-scale bubbles (microbubbles) typically used in biomedical applications. The monolayer shell consisted of a homologous series of saturated acyl chain phospholipids and an emulsifier containing a single hydrophobic stearate chain and polyethylene glycol (PEG) head group. PEG-emulsifier was fully miscible with expanded phase lipids and phase separated from condensed phase lipids. Phase coexistence was observed in the form of dark condensed phase lipid domains surrounded by a sea of bright, emulsifier-rich expanded phase. A rich assortment of condensed phase area fractions and domain morphologies, including networks and other novel structures, were observed in each batch of microbubbles. Network domains were reproduced in Langmuir monolayers under conditions of heating-cooling followed by compression-expansion, as well as in microbubble shells that underwent surface flow with slight compression. Domain size decreased with increased cooling rate through the phase transition temperature, and domain branching increased with lipid acyl chain length at high cooling rates. Squeeze-out of the emulsifier at a surface pressure near 35 mN/m was indicated by a plateau in Langmuir isotherms and directly visualized with fluorescence microscopy, although collapse of the solid lipid domains occurred at much higher surface pressures. Compression of the monolayer past the PEG-emulsifier squeeze-out surface pressure resulted in a dark shell composed entirely of lipid. Under certain conditions, the PEG-emulsifier was reincorporated upon subsequent expansion. Factors that affect shell formation and evolution, as well as implications for the rational design of microbubbles in medical applications, are discussed.

Development of a two-phase SPH model for sediment laden flows

NASA Astrophysics Data System (ADS)

Shi, Huabin; Yu, Xiping; Dalrymple, Robert A.

2017-12-01

A SPH model based on a general formulation for solid-fluid two-phase flows is proposed for suspended sediment motion in free surface flows. The water and the sediment are treated as two miscible fluids, and the multi-fluid system is discretized by a single set of SPH particles, which move with the water velocity and carry properties of the two phases. Large eddy simulation (LES) is introduced to deal with the turbulence effect, and the widely used Smagorinsky model is modified to take into account the influence of sediment particles on the turbulence. The drag force is accurately formulated by including the hindered settling effect. In the model, the water is assumed to be weakly compressible while the sediment is incompressible, and a new equation of state is proposed for the pressure in the sediment-water mixture. Dynamic boundary condition is employed to treat wall boundaries, and a new strategy of Shepard filtering is adopted to damp the pressure oscillation. The developed two-phase SPH model is validated by comparing the numerical results with analytical solutions for idealized cases of still water containing both neutrally buoyant and naturally settling sand and for plane Poiseuille flows carrying neutrally buoyant particles, and is then applied to sand dumping from a line source into a water tank, where the sand cloud settles with a response of the free water surface. It is shown that the numerical results are in good agreement with the experimental data as well as the empirical formulas. The characteristics of the settling sand cloud, the pressure field, and the flow vortices are studied. The motion of the free water surface is also discussed. The proposed two-phase SPH model is proven to be effective for numerical simulation of sand dumping into waters.

Performance of transonic fan stage with weight flow per unit annulus area of 178 kilograms per second per square meter (6.5(lb/sec)/(sq ft))

NASA Technical Reports Server (NTRS)

Moore, R. D.; Urasek, D. C.; Kovich, G.

1973-01-01

The overall and blade-element performances are presented over the stable flow operating range from 50 to 100 percent of design speed. Stage peak efficiency of 0.834 was obtained at a weight flow of 26.4 kg/sec (58.3 lb/sec) and a pressure ratio of 1.581. The stall margin for the stage was 7.5 percent based on weight flow and pressure ratio at stall and peak efficiency conditions. The rotor minimum losses were approximately equal to design except in the blade vibration damper region. Stator minimum losses were less than design except in the tip and damper regions.

KINETICS OF ETHANOL BIODEGRADATION UNDER METHANOGENIC CONDITIONS IN GASOLINE SPILLS

EPA Science Inventory

Ethanol is commonly used as a fuel oxygenate. A concern has been raised that biodegradation of ethanol from a spill of gasoline may inhibit the natural biodegradation of fuel hydrocarbons, including benzene. Ethanol is miscible in water, and ethanol is readily metabolized by mi...

COSOLVENT EFFECTS ON PHENANTHRENE SORPTION-DESORPTION ON A FRESH-WATER SEDIMENT

EPA Science Inventory

This study evaluated the effects of the water-miscible cosolvent methanol on the sorption-desorption of phenanthrene by the natural organic matter (NOM) of a fresh-water sediment. A biphasic pattern was observed in the relationship between the log of the carbon-normalized sorpti...

EFFECT OF ETHANOL ON THE NATURAL ANAEROBIC BIODEGRADATION OF BENZENE

EPA Science Inventory

Ethanol is commonly used as a fuel oxygenate. A concern has been raised that the presence of ethanol from a spill of gasoline may inhibit the natural biodegradation of fuel hydrocarbons, including benzene. Ethanol is miscible in water, and ethanol is readily metabolized by micr...

A unique concept for automatically controlling the braking action of wheeled vehicles during minimum distance stops

NASA Technical Reports Server (NTRS)

Barthlome, D. E.

1975-01-01

Test results of a unique automatic brake control system are outlined and a comparison is made of its mode of operation to that of an existing skid control system. The purpose of the test system is to provide automatic control of braking action such that hydraulic brake pressure is maintained at a near constant, optimum value during minimum distance stops.

The Effect of Minimum Wages on the Labor Force Participation Rates of Teenagers.

ERIC Educational Resources Information Center

Wessels, Walter J.

In light of pressure on Congress to raise the minimum wage from $5.15 to $6.15 per hour, a study looked at the effects such a raise would have on more than 10 million workers, many of them teenagers. The study used quarterly data on the labor force participation rates of teenagers from 1978 through 1999 and other studies to assess the effects of…

Pars plana Ahmed valve and vitrectomy in patients with glaucoma associated with posterior segment disease.

PubMed

Wallsh, Josh O; Gallemore, Ron P; Taban, Mehran; Hu, Charles; Sharareh, Behnam

2013-01-01

To assess the safety and efficacy of a modified technique for pars plana placement of the Ahmed valve in combination with pars plana vitrectomy in the treatment of glaucoma associated with posterior segment disease. Thirty-nine eyes with glaucoma associated with posterior segment disease underwent pars plana vitrectomy combined with Ahmed valve placement. All valves were placed in the pars plana using a modified technique, without the pars plana clip, and using a scleral patch graft. The 24 eyes diagnosed with neovascular glaucoma had an improvement in intraocular pressure from 37.6 mmHg to 13.8 mmHg and best-corrected visual acuity from 2.13 logarithm of minimum angle of resolution to 1.40 logarithm of minimum angle of resolution. Fifteen eyes diagnosed with steroid-induced glaucoma had an improvement in intraocular pressure from 27.9 mmHg to 14.1 mmHg and best-corrected visual acuity from 1.38 logarithm of minimum angle of resolution to 1.13 logarithm of minimum angle of resolution. Complications included four cases of cystic bleb formation and one case of choroidal detachment and explantation for hypotony. Ahmed valve placement through the pars plana during vitrectomy is an effective option for managing complex cases of glaucoma without the use of the pars plana clip.

Pressure-enhanced ortho-para conversion in solid hydrogen up to 58 GPa.

PubMed

Eggert, J H; Karmon, E; Hemley, R J; Mao, A; Goncharov, A F

1999-10-26

We measured the ortho-para conversion rate in solid hydrogen by using Raman scattering in a diamond-anvil cell, extending previous measurements by a factor of 60 in pressure. We confirm previous experiments that suggested a decrease in the conversion rate above about 0.5 GPa. We observe a distinct minimum at 3 GPa followed by a drastic increase in the conversion rate to our maximum pressure of 58 GPa. This pressure enhancement of conversion is not predicted by previous theoretical treatments and must be due to a new conversion pathway.

Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle

DOEpatents

Butcher, Thomas A.; Celebi, Yusuf; Fisher, Leonard

2000-09-15

The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

30 CFR 250.522 - When do I have to repeat casing diagnostic testing?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., previously on gas lift, has been shut-in or returned to flowing status without gas lift for more than 180... active gas lift are exempt from diagnostic testing. (c) your casing pressure request becomes invalid... percent of its minimum internal yield pressure (MIYP), except for production casings on active gas lift...

30 CFR 250.523 - How long do I keep records of casing pressure and diagnostic tests?

Code of Federal Regulations, 2010 CFR

2010-07-01

... field office nearest the well for a minimum of 2 years. The last casing diagnostic test for each casing... and diagnostic tests? 250.523 Section 250.523 Mineral Resources MINERALS MANAGEMENT SERVICE... Gas Well-Completion Operations Casing Pressure Management § 250.523 How long do I keep records of...

46 CFR 154.560 - Cargo hose: Prototype test.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo hose: Prototype test. 154.560 Section 154.560... Hose § 154.560 Cargo hose: Prototype test. (a) Each cargo hose must be of a type that passes a prototype test at a pressure of at least five times its maximum working pressure at or below the minimum...

40 CFR Table 3 to Subpart Dddd of... - Model Rule-Operating Limits for Wet Scrubbers

Code of Federal Regulations, 2010 CFR

2010-07-01

... Scrubbers 3 Table 3 to Subpart DDDD of Part 60 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...—Model Rule—Operating Limits for Wet Scrubbers For these operating parameters You must establish these... intermittent units) a Pressure drop across the wet scrubber or amperage to wet scrubber Minimum pressure drop...

40 CFR Table 3 to Subpart Dddd of... - Model Rule-Operating Limits for Wet Scrubbers

Code of Federal Regulations, 2011 CFR

2011-07-01

... Scrubbers 3 Table 3 to Subpart DDDD of Part 60 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...—Model Rule—Operating Limits for Wet Scrubbers For these operating parameters You must establish these... intermittent units) a Pressure drop across the wet scrubber or amperage to wet scrubber Minimum pressure drop...

Bromine cycle in subduction zones through in situ Br monitoring in diamond anvil cells

NASA Astrophysics Data System (ADS)

Bureau, Hélène; Foy, Eddy; Raepsaet, Caroline; Somogyi, Andrea; Munsch, Pascal; Simon, Guilhem; Kubsky, Stefan

2010-07-01

The geochemical partitioning of bromine between hydrous haplogranitic melts, initially enriched with respect to Br and aqueous fluids, has been continuously monitored in situ during decompression. Experiments were carried out in diamond anvil cells from 890 °C to room temperature and from 1.7 GPa to room pressure, typically from high P, T conditions corresponding to total miscibility (presence of a supercritical fluid). Br contents were measured in aqueous fluids, hydrous melts and supercritical fluids. Partition coefficients of bromine were characterized at pressure and temperature between fluids, hydrous melts and/or glasses, as appropriate: DBrfluid/melt = (Br) fluid/(Br) melt, ranges from 2.18 to 9.2 ± 0.5 for conditions within the ranges 0.66-1.7 GPa, 590-890 °C; and DBrfluid/glass = (Br) fluid/(Br) glass ranges from 60 to 375 at room conditions. The results suggest that because high pressure melts and fluids are capable of accepting high concentrations of bromine, this element may be efficiently removed from the slab to the mantle source of arc magmas. We show that Br may be highly concentrated in subduction zone magmas and strongly enriched in subduction-related volcanic gases, because its mobility is strongly correlated with that of water during magma degassing. Furthermore, our experimental results suggest that a non negligible part of Br present in the subducted slab may remain in the down-going slab, being transported toward the transition zone. This indicates that the Br cycle in subduction zones is in fact divided in two related but independent parts: (1) a shallower one where recycled Br may leave the slab with a water and silica-bearing "fluid" leading to enriched arc magmas that return Br to the atmosphere. (2) A deeper cycle where Br may be recycled back to the mantle maybe to the transition zone, where it may be present in high pressure water-rich metasomatic fluids.

A dynamic pressure view cell for acoustic stimulation of fluids--Micro-bubble generation and fluid movement in porous media.

PubMed

Stewart, Robert A; Shaw, J M

2015-09-01

The development and baseline operation of an acoustic view cell for observing fluids, and fluid-fluid and fluid-solid interfaces in porous media over the frequency range of 10-5000 Hz is described. This range includes the industrially relevant frequency range 500-5000 Hz that is not covered by existing devices. Pressure waveforms of arbitrary shape are generated in a 17.46 mm ID by 200 mm and 690.5 mm long glass tubes at flow rates up to 200 ml/min using a syringe pump. Peak-to-peak amplitudes exceeding 80 kPa are readily realized at frequencies from 10 to 5000 Hz in bubble free fluids when actuated with 20 Vpp as exemplified using castor oil. At resonant frequencies, peak-to-peak pressure amplitudes exceeding 500 kPa were obtained (castor oil at 2100 Hz when actuated with 20 Vpp). Impacts of vibration on macroscopic liquid-liquid and liquid-vapour interfaces and interface movement are illustrated. Pressure wave transmission and attenuation in a fluid saturated porous medium, randomly packed 250-330 μm spherical silica beads, is also demonstrated. Attenuation differences and frequency shifts in resonant peaks are used to detect the presence and generation of dispersed micro-bubbles (<180 μm diameter), and bubbles within porous media that are not readily visualized. Envisioned applications include assessment of the impacts of vibration on reaction, mass transfer, and flow/flow pattern outcomes. This knowledge will inform laboratory and pilot scale process studies, where nuisance vibrations may affect the interpretation of process outcomes, and large scale or in situ processes in aquifers or hydrocarbon reservoirs where imposed vibration may be deployed to improve aspects of process performance. Future work will include miscible interface observation and quantitative measurements in the bulk and in porous media where the roles of micro-bubbles comprise subjects of special interest.

40 CFR Appendix III to Part 86 - Constant Volume Sampler Flow Calibration

Code of Federal Regulations, 2014 CFR

2014-07-01

... ETI °F ±.1°F. Pressure depression upstream of LFE EPI “H20 ±.1“H20. Pressure drop across the LFE matrix EDP “H20 ±.005“H20. Air temperature at CVS pump inlet PTI °F ±.5°F. Pressure depression at CVS... condition in an increment of pump inlet depression (about 4″ H2O) that will yield a minimum of six data...

40 CFR Appendix III to Part 86 - Constant Volume Sampler Flow Calibration

Code of Federal Regulations, 2010 CFR

2010-07-01

... ETI °F ±.1 °F. Pressure depression upstream of LFE EPI “H20 ±.1“H20. Pressure drop across the LFE matrix EDP “H20 ±.005“H20. Air temperature at CVS pump inlet PTI °F ±.5 °F. Pressure depression at CVS... condition in an increment of pump inlet depression (about 4″ H2O) that will yield a minimum of six data...