INDEPENDENT SIGNALS FROM THE INFLUENCE OF INTERNAL MAGNETIC LAYERS ON THE FREQUENCIES OF SOLAR p-MODES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Foullon, C.; Nakariakov, V. M.

2010-05-01

The discovery that p-mode frequencies of low degree do not follow changes of solar surface activity during the recent solar minimum offers the possibility of a new diagnostic signature of the responsible pressure perturbation in the wave guiding medium, potentially rich of information regarding the structure of the Sun and the cause of the unusually long solar minimum. Magnetic fields, as well as temperature changes, introduce equilibrium pressure deviations that modify the resonant frequencies of p-mode oscillations. Assuming the perturbation to be caused by a horizontal layer of magnetic field located in a plane-stratified model of the Sun, we compilemore » analytical frequency shifts and process them to allow direct comparison with observations. The effect of magnetism itself on the central p-mode frequencies can be neglected in comparison with the thermal effect of a perturbative layer buried in the solar interior. A parametric study shows that a layer as thin as 2100 km at subsurface depths is able to reproduce reported mean anomalous frequency shifts (not correlated with the surface activity), while a layer of size around 4200 km increasing by a small amount at depths near 0.08 R {sub sun} can explain individual low-degree shifts. It is also possible to obtain the mean shifts via the upward motion through depths near 0.03 R {sub sun} of a rising perturbative layer of thickness around 7000 km. Hence, the anomalous frequency shifts are best explained by thermal effects in the upper regions of the convection zone. The effects of latitudinal distribution are not treated here.« less

Characteristic vibration patterns of odor compounds from bread-baking volatiles upon protein binding: density functional and ONIOM study and principal component analysis.

PubMed

Treesuwan, Witcha; Hirao, Hajime; Morokuma, Keiji; Hannongbua, Supa

2012-05-01

As the mechanism underlying the sense of smell is unclear, different models have been used to rationalize structure-odor relationships. To gain insight into odorant molecules from bread baking, binding energies and vibration spectra in the gas phase and in the protein environment [7-transmembrane helices (7TMHs) of rhodopsin] were calculated using density functional theory [B3LYP/6-311++G(d,p)] and ONIOM [B3LYP/6-311++G(d,p):PM3] methods. It was found that acetaldehyde ("acid" category) binds strongly in the large cavity inside the receptor, whereas 2-ethyl-3-methylpyrazine ("roasted") binds weakly. Lys296, Tyr268, Thr118 and Ala117 were identified as key residues in the binding site. More emphasis was placed on how vibrational frequencies are shifted and intensities modified in the receptor protein environment. Principal component analysis (PCA) suggested that the frequency shifts of C-C stretching, CH(3) umbrella, C = O stretching and CH(3) stretching modes have a significant effect on odor quality. In fact, the frequency shifts of the C-C stretching and C = O stretching modes, as well as CH(3) umbrella and CH(3) symmetric stretching modes, exhibit different behaviors in the PCA loadings plot. A large frequency shift in the CH(3) symmetric stretching mode is associated with the sweet-roasted odor category and separates this from the acid odor category. A large frequency shift of the C-C stretching mode describes the roasted and oily-popcorn odor categories, and separates these from the buttery and acid odor categories.

Bernstein wave aided laser third harmonic generation in a plasma

NASA Astrophysics Data System (ADS)

Tyagi, Yachna; Tripathi, Deepak; Kumar, Ashok

2016-09-01

The process of Bernstein wave aided resonant third harmonic generation of laser in a magnetized plasma is investigated. The extra-ordinary mode (X-mode) laser of frequency ω 0 and wave number k → 0 , travelling across the magnetic field in a plasma, exerts a second harmonic ponderomotive force on the electrons imparting them an oscillatory velocity v → 2 ω0 , 2 k → 0 . This velocity beats with the density perturbation due to the Bernstein wave to produce a density perturbation at cyclotron frequency shifted second harmonic. The density perturbation couples with the oscillatory velocity v → ω0 , k → 0 of X-mode of the laser to produce the cyclotron frequency shifted third harmonic current density leading to harmonic radiation. The phase matching condition for the up shifted frequency is satisfied when the Bernstein wave is nearly counter-propagating to the laser. As the transverse wave number of the Bernstein wave is large, it is effective in the phase matched third harmonic generation, when the laser frequency is not too far from the upper hybrid frequency.

Interpretation of frequency sweeping of n=0 mode in JET

NASA Astrophysics Data System (ADS)

Berk, H. L.

2006-04-01

Persistent rapid up and down frequency chirping modes with a toroidal mode number of zero (n=0) are observed in the JET tokamak when energetic ions, in the range of several hundred keV, are created by high field side ion cyclotron resonance frequency heating. Fokker-Planck calculations demonstrate that the heating method enables the formation of an energetically inverted ion distribution which supplies the free energy for the ions to excite a global geodesic acoustic mode (GGAM). The large frequency shifts of this mode are attributed to the formation of phase space structures whose frequencies, which are locked to an ion orbit resonance frequency, are forced to continually shift so that energetic particle energy can be released to counterbalance the energy dissipation present in the background plasma. In collaboration with C.J. Boswell, MIT; D. Borba, A.C.A. Figueiredo, Center for Nuclear Fusion Association; T. Johnson, Alfven Laboratory, KTH; M.F.F. Nave, Center for Nuclear Fusion Association; S.D. Pinches, Max Planck Institute for Plasma Physics; S.E. Sharapov, UKEA Culham Science Centre; and T. Zhou, University of Texas at Austin.

Interstellar PAH Emission in the 11-14 micron Region: New Insights and a Tracer of Ionized PAHs

NASA Technical Reports Server (NTRS)

Hudgins, Douglas M.; Allamandola, Louis J.; Mead, Susan (Technical Monitor)

1999-01-01

The Ames infrared spectral database of isolated, neutral and ionized polycyclic aromatic hydrocarbons (PAHs) shows that aromatic CH out-of-plane bending frequencies are significantly shifted upon ionization. For non-adjacent and doubly-adjacent CH groups, the shift is pronounced and consistently toward higher frequencies. The non-adjacent modes are blueshifted by an average of 27 per cm and the doubly-adjacent modes by an average of 17 per cm. For triply- and quadruply-adjacent CH out-of-plane modes the ionization shifts are more erratic and typically more modest. As a result of these ionization shifts, both the non-adjacent and doubly-adjacent CH out-of-plane modes move out of the regions classically associated with their respective vibrations in neutral PAHs. The doubly-adjacent modes of ionized PAHs tend to fall into the frequency range traditionally associated with the non-adjacent modes, while the non-adjacent modes are shifted to frequencies above those normally attributed to out-of-plane bending vibrations. Consequently, the origin of the interstellar infrared emission feature near 11.2 microns, traditionally attributed to the out-of-plane bending of non-adjacent CH groups on PAHs is rendered ambiguous. Instead, this feature likely reflects contributions from both non-adjacent CH units in neutral PAHs and doubly-adjacent CH units in PAH cations, the dominant charge state in the most energetic emission regions. This greatly relieves the structural constraints placed on the interstellar PAH population by the dominance of the 11.2 micron band in this region and eliminates the necessity to invoke extensive dehydrogenation of the emitting species. Furthermore, these results indicate that the emission between 926 and 904 per cm (10.8 and 11.1 microns) observed in many sources can be unambiguously attributed to the non-adjacent CH out-of-plane bending modes of moderately-sized (fewer than 50 carbon atom) PAH cations making this emission an unequivocal tracer of ionized interstellar PAHs.

Frequency shift of a crystal quartz resonator in thickness-shear modes induced by an array of hemispherical material units.

PubMed

Yuantai Hu; Huiliang Hu; Bin Luo; Huan Xue; Jiemin Xie; Ji Wang

2013-08-01

A two-dimensional model was established to study the dynamic characteristics of a quartz crystal resonator with the upper surface covered by an array of hemispherical material units. A frequency-dependent equivalent mass ratio was proposed to simulate the effect of the covered units on frequency shift of the resonator system. It was found that the equivalent mass ratio alternately becomes positive or negative with change of shear modulus and radius of each material unit, which indicates that the equivalent mass ratio is strongly related to the vibration mode of the covered loadings. The further numerical results show the cyclical feature in the relationship of frequency shift and shear modulus/radius as expected. The solutions are useful in the analysis of frequency stability of quartz resonators and acoustic wave sensors.

Estimating the pressure of laser-induced plasma shockwave by stimulated Raman shift of lattice translational modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li Zhanlong; College of Physics, Jilin University, Changchun 130012; Shan Xiaoning

2012-07-09

The current paper investigates stimulated Raman scattering (SRS) when laser-induced plasma is formed in heavy water by focusing an intense pulsed 532 nm Nd:YAG laser beam at room temperature. An unexpected low-frequency SRS line attributed to the lattice translational modes of ice-VII (D{sub 2}O) is observed. The pressure of the plasma shockwave is estimated using low-frequency SRS line shift.

FIBER AND INTEGRATED OPTICS: Radio-frequency electrooptic modulation in optical fibers

NASA Astrophysics Data System (ADS)

Bulyuk, A. N.

1992-10-01

The electrooptic interaction in single-mode optical fibers with both linear and circular birefringe is analyzed. In most cases, a large interaction length imposes a limit on the modulation frequency. A circular birefringence in an optical fiber may lead to an effective coupling of polarization normal modes if a phase-matching condition is satisfied. Through an appropriate choice of polarization states of the light at the entrance and exit of the device, one can achieve a polarization modulation or a frequency shift of the light. There are possible applications in rf polarization modulators, devices for shifting the frequency of light, and detectors of electromagnetic fields.

Solvent dependent frequency shift and Raman noncoincidence effect of S=O stretching mode of Dimethyl sulfoxide in liquid binary mixtures.

PubMed

Upadhyay, Ganesh; Devi, Th Gomti; Singh, Ranjan K; Singh, A; Alapati, P R

2013-05-15

The isotropic and anisotropic Raman peak frequencies of S=O stretching mode of Dimethyl sulfoxide (DMSO) have been discussed in different chemical and isotopic solvent molecules using different mechanisms. The shifting of peak frequency in further dilution of DMSO with solvent molecule is observed for all solvents. Transition dipole - transition dipole interaction and hydrogen bonding may play a major role in shifting of peak frequencies. The non-coincidence effect (NCE) of DMSO was determined for all the solvents and compared with four theoretical models such as McHale's model, Mirone's modification of McHale's model, Logan's model and Onsager-Fröhlich dielectric continuum model respectively. Most of the theoretical models are largely consistent with our experimental data. Copyright © 2013. Published by Elsevier B.V.

Comments on Landau damping due to synchrotron frequency spread

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ng, K.Y.; /Fermilab

2005-01-01

An inductive/space-charge impedance shifts the synchrotron frequency downwards above/below transition, but it is often said that the coherent synchrotron frequency of the bunch is not shifted in the rigid-dipole mode. On the other hand, the incoherent synchrotron frequency due to the sinusoidal rf always spreads in the downward direction. This spread will therefore not be able to cover the coherent synchrotron frequency, implying that there will not be any Landau damping no matter how large the frequency spread is. By studying the dispersion relation, it is shown that the above argument is incorrect, and there will be Landau damping ifmore » there is sufficient frequency spread. The main reason is that the coherent frequency of the rigid-dipole mode will no longer remain unshifted in the presence of a synchrotron frequency spread.« less

A resonance shift prediction based on the Boltzmann-Ehrenfest principle for cylindrical cavities with a rigid sphere.

PubMed

Santillan, Arturo O; Cutanda-Henríquez, Vicente

2008-11-01

An investigation on the resonance frequency shift for a plane-wave mode in a cylindrical cavity produced by a rigid sphere is reported in this paper. This change of the resonance frequency has been previously considered as a cause of oscillational instabilities in single-mode acoustic levitation devices. It is shown that the use of the Boltzmann-Ehrenfest principle of adiabatic invariance allows the derivation of an expression for the resonance frequency shift in a simpler and more direct way than a method based on a Green's function reported in literature. The position of the sphere can be any point along the axis of the cavity. Obtained predictions of the resonance frequency shift with the deduced equation agree quite well with numerical simulations based on the boundary element method. The results are also confirmed by experiments. The equation derived from the Boltzmann-Ehrenfest principle appears to be more general, and for large spheres, it gives a better approximation than the equation previously reported.

An Ongoing Shift in Pacific Ocean Sea Level

NASA Astrophysics Data System (ADS)

Cheon, S. H.; Hamlington, B.; Thompson, P. R.; Merrifield, M. A.; Nerem, R. S.; Leben, R. R.; Kim, K. Y.

2016-12-01

According to the satellite altimeter data, local sea level trends have shown considerable diversity spatially as well as temporally. In particular, dramatic changes in sea level in the Pacific have been observed throughout the altimeter record, with high trends in the western tropical Pacific (WTP) and comparatively lower trends in the eastern Pacific. In recent years, however, a shift appears to be occurring, with falling trends in the (WTP) and rising trends in the eastern tropical and northeastern Pacific (ETP and NEP). From a planning perspective, it is important to figure out whether these sharp changes are part of a short-term shift or the beginning of a longer-term change in sea level. In this study, we distinguish the origins of the recent shift in Pacific Ocean sea level. Cyclostationary empirical orthogonal function (CSEOF) analysis is applied to separate the properties of the recent sea level change in the Pacific Ocean. From the CSEOF analysis results, we point out two dominant modes of sea level shift in the Pacific Ocean. The first mode is related to the biennial oscillation associated with El Nino-Southern Oscillation (ENSO) and the other is related to lower-frequency variability with a strong signal in the northern Pacific. Considering a relatively high correlation between recent sea level change and the low-frequency mode, we suggest that the low-frequency mode has played a dominant role in the sea level shift in the Pacific Ocean. Using a reconstructed sea level dataset, we examine the variability of this low-frequency mode in the past, and find similar periods of dramatic sea level change in the Pacific. Based on the sea level record of the last five years and according to the analysis, we conclude that in the coming decades, higher sea level trends off the U.S. West Coast should be expected, while reduced trends in the WTP will likely be observed.

Raman intensity and vibrational modes of armchair CNTs

NASA Astrophysics Data System (ADS)

Hur, Jaewoong; Stuart, Steven J.

2017-07-01

Raman intensity changes and frequency patterns have been studied using the various armchair (n, n) to understand the variations of bond polarizability, in regard to changing diameters, lengths, and the number of atoms in the (n, n). The Raman intensity trends of the (n, n) are validated by those of Cn isomers. For frequency trends, similar frequency patterns and frequency inward shifts for the (n, n) are characterized. Also, VDOS trends of the (n, n) expressing Raman modes are interpreted. The decomposition of vibrational modes in the (n, n) into radial, longitudinal, and tangential mode is beneficially used to recognize the distinct characteristics of vibrational modes.

Interstellar PAH emission in the 11-14 micron region: new insights from laboratory data and a tracer of ionized PAHs

NASA Technical Reports Server (NTRS)

Hudgins, D. M.; Allamandola, L. J.

1999-01-01

The Ames infrared spectral database of isolated, neutral and ionized polycyclic aromatic hydrocarbons (PAHS) shows that aromatic CH out-of-plane bending frequencies are significantly shifted upon ionization. For solo- and duet-CH groups, the shift is pronounced and consistently toward higher frequencies. The solo-CH modes are blueshifted by an average of 27 cm-1 and the duet-CH modes by an average of 17 cm-1. For trio- and quartet-CH groups, the ionization shifts of the out-of-plane modes are more erratic and typically more modest. As a result of these ionization shifts, the solo-CH out-of-plane modes move out of the region classically associated with these vibrations in neutral PAHS, falling instead at frequencies well above those normally attributed to out-of-plane bending, vibrations of any type. In addition, for the compact PAHs studied, the duet-CH out-of-plane modes are shifted into the frequency range traditionally associated with the solo-CH modes. These results refine our understanding of the origin of the dominant interstellar infrared emission feature near 11.2 microns, whose envelope has traditionally been attributed only to the out-of-plane bending of solo-CH groups on PAHS, and provide a natural explanation for the puzzling emission feature near 11.0 microns within the framework of the PAH model. Specifically, the prevalent but variable long-wavelength wing or shoulder that is often observed near 11.4 microns likely reflects the contributions of duet-CH units in PAH cations. Also, these results indicate that the emission between 926 and 904 cm-1 (10.8 and 11.1 microns) observed in many sources can be unambiguously attributed to the out-of-plane wagging, of solo-CH units in moderately sized (fewer than 50 carbon atom) PAH cations, making this emission an unequivocal tracer of ionized interstellar PAHS.

Resonance-Based Detection of Magnetic Nanoparticles and Microbeads Using Nanopatterned Ferromagnets

NASA Astrophysics Data System (ADS)

Sushruth, Manu; Ding, Junjia; Duczynski, Jeremy; Woodward, Robert C.; Begley, Ryan A.; Fangohr, Hans; Fuller, Rebecca O.; Adeyeye, Adekunle O.; Kostylev, Mikhail; Metaxas, Peter J.

2016-10-01

Biosensing with ferromagnet-based magnetoresistive devices has been dominated by electrical detection of particle-induced changes to a device's (quasi-)static magnetic configuration. There are however potential advantages to be gained from using field dependent, high frequency resonant magnetization dynamics for magnetic particle detection. Here, we demonstrate the use of nanoconfined ferromagnetic resonances in periodically nanopatterned magnetic films for the detection of adsorbed magnetic particles having diameters ranging from 6 nm to 4 μ m . The nanopatterned films contain arrays of holes which appear to act as preferential adsorption sites for small particles. Hole-localized particles act in unison to shift the frequencies of the patterned layer's ferromagnetic-resonance modes, with shift polarities determined by the localization of each mode within the nanopattern's repeating unit cell. The same polarity shifts are observed for a large range of coverages, even when quasicontinuous particle sheets form above the hole-localized particles. For large particles, preferential adsorption no longer occurs, leading to resonance shifts with polarities that are independent of the mode localization, and amplitudes that are comparable to those seen in continuous layers. Indeed, for nanoparticles adsorbed onto a continuous layer, the particle-induced shift of the layer's fundamental mode is up to 10 times less than that observed for nanoconfined modes in the nanopatterned systems, the low shift being induced by relatively weak fields emanating beyond the particle in the direction of the static applied field. This result highlights the importance of having particles consistently positioned in the close vicinity of confined modes.

Energetic-particle-modified global Alfvén eigenmodes

NASA Astrophysics Data System (ADS)

Lestz, J. B.; Belova, E. V.; Gorelenkov, N. N.

2018-04-01

Fully self-consistent hybrid MHD/particle simulations reveal strong energetic particle modifications to sub-cyclotron global Alfvén eigenmodes (GAEs) in low-aspect ratio, NSTX-like conditions. Key parameters defining the fast ion distribution function—the normalized injection velocity v0/vA and central pitch—are varied in order to study their influence on the characteristics of the excited modes. It is found that the frequency of the most unstable mode changes significantly and continuously with beam parameters, in accordance with the Doppler-shifted cyclotron resonances which drive the modes, and depending most substantially on v0/vA . This unexpected result is present for both counter-propagating GAEs, which are routinely excited in NSTX, and high frequency co-GAEs, which have not been previously studied. Large changes in frequency without clear corresponding changes in the mode structure are signatures of an energetic particle mode, referred to here as an energetic-particle-modified GAE. Additional simulations conducted for a fixed MHD equilibrium demonstrate that the GAE frequency shift cannot be explained by the equilibrium changes due to energetic particle effects.

Energetic-particle-modified global Alfven eigenmodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lestz, J. B.; Belova, E. V.; Gorelenkov, N. N.

Fully self-consistent hybrid MHD/particle simulations reveal strong energetic particle modifications to sub-cyclotron global Alfvén eigenmodes (GAEs) in low-aspect ratio, NSTX-like conditions. Key parameters defining the fast ion distribution function—the normalized injection velocity v 0/v A and central pitch—are varied in order to study their influence on the characteristics of the excited modes. It is found that the frequency of the most unstable mode changes significantly and continuously with beam parameters, in accordance with the Doppler-shifted cyclotron resonances which drive the modes, and depending most substantially on v 0/v A. This unexpected result is present for both counter-propagating GAEs, which aremore » routinely excited in NSTX, and high frequency co-GAEs, which have not been previously studied. Large changes in frequency without clear corresponding changes in the mode structure are signatures of an energetic particle mode, referred to here as an energetic-particle-modified GAE. In conclusion, additional simulations conducted for a fixed MHD equilibrium demonstrate that the GAE frequency shift cannot be explained by the equilibrium changes due to energetic particle effects.« less

Energetic-particle-modified global Alfven eigenmodes

DOE PAGES

Lestz, J. B.; Belova, E. V.; Gorelenkov, N. N.

2018-04-30

Fully self-consistent hybrid MHD/particle simulations reveal strong energetic particle modifications to sub-cyclotron global Alfvén eigenmodes (GAEs) in low-aspect ratio, NSTX-like conditions. Key parameters defining the fast ion distribution function—the normalized injection velocity v 0/v A and central pitch—are varied in order to study their influence on the characteristics of the excited modes. It is found that the frequency of the most unstable mode changes significantly and continuously with beam parameters, in accordance with the Doppler-shifted cyclotron resonances which drive the modes, and depending most substantially on v 0/v A. This unexpected result is present for both counter-propagating GAEs, which aremore » routinely excited in NSTX, and high frequency co-GAEs, which have not been previously studied. Large changes in frequency without clear corresponding changes in the mode structure are signatures of an energetic particle mode, referred to here as an energetic-particle-modified GAE. In conclusion, additional simulations conducted for a fixed MHD equilibrium demonstrate that the GAE frequency shift cannot be explained by the equilibrium changes due to energetic particle effects.« less

Vibrational spectroscopy of the electronically excited state. 4. Nanosecond and picosecond time-resolved resonance Raman spectroscopy of carotenoid excited states

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dallinger, R.F.; Farquharson, S.; Woodruff, W.H.

Resonance Raman and electronic absorption spectra are reported for the S/sub 0/ and T/sub 1/ states of the carotenoids ..beta..-carotene, zeaxanthin, echinenone, canthaxanthin, dihydroxylycopene, astaxanthin, decapreno(C/sub 50/)-..beta..-carotene, ..beta..-apo-8'-carotenal, and ethyl ..beta..-apo-8'-carotenoate. The results reveal qualitatively similar ground-state spectra and similar frequency shifts in all observed resonance Raman modes between S/sub 0/ and T/sub 1/, regardless of carotenoid structure. Examinations of the relationship of the putative C--C and C==C frequencies in S/sub 0/ and T/sub 1/ reveals anomalous shifts to lower frequency in the ''single-bond'' mode upon electronic excitation. These shifts may be due to molecular distortions in the excited statemore » which force changes in molecular motions comprising the observed modes. However, another possibility requiring no distortion is that the interaction (off-diagonal) force constants connecting the C--C and C==C modes change sign upon electronic excitation. This latter phenomenon may provide a unitary explanation for the ''anomalous'' frequency shifts in the C--C and C==C modes, both in the T/sub 1/ states of carotenoids and in the S/sub 1/ states of simpler polyenes, without postulating large, unpredicted structural changes upon excitation or general errors in existing vibrational or theoretical analyses. Resonance Raman and absorbance studies with 35-ps time resolution suggest that S/sub 1/ lifetime (of the /sup 1/B/sub u/ and/or the /sup 1/A/sub g/* states) of ..beta..-carotene in benzene is less than 1 ps.« less

Recoil-free Fraction in Amorphous and Nanocrystalline Aluminium Based Alloys

NASA Astrophysics Data System (ADS)

Sitek, Jozef

2008-10-01

Aluminium based rapidly quenched alloys of nominal composition Al90Fe7Nb3 and Al94Fe2V4 were studied by Mössbauer spectroscopy. We have measured the recoil-free fraction and thermal shift at room and liquid nitrogen temperature. The frequency modes of atomic vibrations were determined and consequently the characteristic Debye temperature was derived. Characteristic temperature calculated from f-factor was lower than those fitted from second order Doppler shift. This indicates the presence of different frequency modes for amorphous and nanocrystalline states.

Brillouin lasing in coupled silica toroid microcavities

NASA Astrophysics Data System (ADS)

Honda, Yoshihiro; Yoshiki, Wataru; Tetsumoto, Tomohiro; Fujii, Shun; Furusawa, Kentaro; Sekine, Norihiko; Tanabe, Takasumi

2018-05-01

We demonstrate stimulated Brillouin scattering lasing in a strongly coupled microcavity system. By coupling two silica toroid microcavities, we achieve large mode splitting of 11 GHz, whose frequency separation matches the Brillouin frequency shift of silica. The stimulated Brillouin scattering light is resonantly amplified by pumping at the higher frequency side of the supermode splitting resonance. Since the mode splitting is adjusted by changing the gap distance between the two cavities, our system does not require precise control of a mm-sized cavity diameter to match the free-spectral spacing with the Brillouin frequency shift. It also allows us to use a small cavity, and hence, our system has the potential to achieve the lasing threshold at a very low power.

Mass sensor based on split-nanobeam optomechanical oscillator

NASA Astrophysics Data System (ADS)

Zhang, Yeping; Ai, Jie; Xiang, Yanjun; He, Qinghua; Li, Tao; Ma, Jingfang

2016-03-01

Mass sensing based on monitoring the frequency shifts induced by added mass in oscillators is a well-known and widely used technique. The optomechanical crystal cavity has strong interaction between optical mode and mechanical mode. Radiation pressure driven optomechanical crystal cavity are excellent candidates for mass detection due to their simplicity, sensitivity and all optical operation. In an optomechanical crystal cavity, a high quality factor optical mode simultaneously serves as an efficient actuator and a sensitive probe for precise monitoring the mechanical frequency change of the cavity structure. Here, a split-nanobeam optomechanical crystal cavity is proposed, the sensing resolution as small as 0.33ag (1ag=10-21kg) and the frequency shift is more than 30MHz. This is important and promising for achieve ultimate-precision mass sensing including proteins and other molecules.

Evidence for the frequency-shift of the OA A_1g mode in Hg-based superconductors

NASA Astrophysics Data System (ADS)

Yang, In-Sang; Lee, Hye-Gyong

1996-03-01

The Hg-based superconductors, HgBa_2Ca_n-1Cu_nO_2n+2+δ (n=1,2,3) have two strong Raman peaks at ~ 570 and 590 cm-1 in the high-frequency region. From the results of Raman measurements of Tl-doped Hg-1223 system, it is concluded that the peak at ~ 570 cm-1 does not arise from the vibration of the interstitial oxygen O_δ in the Hg/Tl-O plane, but from the frequency-shift of the A_1g-type vibration of the apical oxygen O_A. The peak at 570 cm-1 is from the O_As surrounded by the O_δs in the nearest neighbor, while the 590 cm-1 mode is from the O_As without the O_δs in the immediate neighbor. The intensity of the 570 cm-1 mode increases with the O_δ content, but the Raman frequencies of both modes do not change significantly. This suggests that the increase of the frequency of the OA A_1g mode under high pressure (I.-S. Yang et al., Phys. Rev. B 51, 644 (1995)) is independent from the O_δ content, in the Hg-based superconductors.

Control of the frequency of the (2,0) mode of liquid bridges using active electrostatic fields

NASA Astrophysics Data System (ADS)

Wei, Wei; Thiessen, David B.; Marston, Philip L.

2004-11-01

Active control of radial electrostatic fields was previously used to suppress the growth of the Plateau-Rayleigh instability in long liquid bridges in a Plateau tank [1] and (for bridges in air) in low gravity [2]. In the present research we use a Plateau tank bridge system having unusually low damping to explore the shift in the (2,0) mode frequency introduced by amplitude feedback for naturally stable bridges. The shift in the mode frequency is the result of the active stiffening of the bridge through the application of the appropriate Maxwell stress projection proportional to the model amplitude. The technique may be important for reducing the response of capillary systems (such as liquid bridges) to ambient vibrations for situations where a spectral peak of the excitation lies close to the natural frequency of an unstiffened mode. [1] M. J. Marr-Lyon, D. B. Thiessen, F. J. Blonigen, and P. L. Marston, Phys. Fluids 12, 986-995 (2000). [2] D. B. Thiessen, M. J. Marr-Lyon, and P. L. Marston, J. Fluid Mech. 457, 285-294 (2002).

Excitation of half-integer up-shifted decay channel and quasi-mode in plasma edge for high power electron Bernstein wave heating scenario

NASA Astrophysics Data System (ADS)

Ali Asgarian, M.; Abbasi, M.

2018-04-01

Electron Bernstein waves (EBW) consist of promising tools in driving localized off-axis current needed for sustained operation as well as effective selective heating scenarios in advanced over dense fusion plasmas like spherical tori and stellarators by applying high power radio frequency waves within the range of Megawatts. Here some serious non-linear effects like parametric decay modes are highly expect-able which have been extensively studied theoretically and experimentally. In general, the decay of an EBW depends on the ratio of the incident frequency and electron cyclotron frequency. At ratios less than two, parametric decay leads to a lower hybrid wave (or an ion Bernstein wave) and EBWs at a lower frequency. For ratios more than two, the daughter waves constitute either an electron cyclotron quasi-mode and another EBW or an ion wave and EBW. However, in contrast with these decay patterns, the excitation of an unusual up-shifted frequency decay channel for the ratio less than two is demonstrated in this study which is totally different as to its generation and persistence. It is shown that this mode varies from the conventional parametric decay channels which necessarily satisfy the matching conditions in frequency and wave-vector. Moreover, the excitation of some less-known local non-propagating quasi-modes (virtual modes) through weak-turbulence theory and their contributions to energy leakage from conversion process leading the reduction in conversion efficiency is assessed.

Asymptotic theory of intermediate- and high-degree solar acoustic oscillations

NASA Technical Reports Server (NTRS)

Brodsky, M.; Vorontsov, S. V.

1993-01-01

A second-order asymptotic approximation is developed for adiabatic nonradial p-modes of a spherically symmetric star. The exact solutions of adiabatic oscillations are assumed in the outermost layers, where the asymptotic description becomes invalid, which results in a eigenfrequency equation with model-dependent surface phase shift. For lower degree modes, the phase shift is a function of frequency alone; for high-degree modes, its dependence on the degree is explicitly taken into account.

Kinetic theory and Vlasov simulation of nonlinear ion-acoustic waves in multi-ion species plasmas.

PubMed

Chapman, T; Berger, R L; Brunner, S; Williams, E A

2013-05-10

The theory of damping and nonlinear frequency shifts from particles resonant with ion-acoustic waves (IAWs) is presented for multi-ion species plasma and compared to driven wave Vlasov simulations. Two distinct IAW modes may be supported in multi-ion species plasmas, broadly classified as fast and slow by their phase velocity relative to the constituent ion thermal velocities. In current fusion-relevant long pulse experiments, the ion to electron temperature ratio, T(i)/T(e), is expected to reach a level such that the least damped and thus more readily driven mode is the slow mode, with both linear and nonlinear properties that are shown to differ significantly from the fast mode. The lighter ion species of the slow mode is found to make no significant contribution to the IAW frequency shift despite typically being the dominant contributor to the Landau damping.

Natural frequency changes due to damage in composite beams

NASA Astrophysics Data System (ADS)

Negru, I.; Gillich, G. R.; Praisach, Z. I.; Tufoi, M.; Gillich, N.

2015-07-01

Transversal cracks in structures affect their stiffness as well as the natural frequency values. This paper presents a research performed to find the way how frequencies of sandwich beams change by the occurrence of damage. The influence of the locally stored energy, for ten transverse vibration modes, on the frequency shifts is derived from a study regarding the effect of stiffness decrease, realized by means of the finite element analysis. The relation between the local value of the bending moment and the frequency drop is exemplified by a concrete case. It is demonstrated that a reference curve representing the damage severity exists whence any frequency shift is derivable in respect to damage depth and location. This curve is obtained, for isotropic and multi-layer beams as well, from the stored energy (i.e. stiffness decrease), and is similar to that attained using the stress intensity factor in fracture mechanics. Also, it is proved that, for a given crack, irrespective to its depth, the frequency drop ratio of any two transverse modes is similar. This permitted separating the effect of damage location from that of its severity and to define a Damage Location Indicator as a sequence of squared of the normalized mode shape curvatures.

Correlations between the resonant frequency shifts and the thermodynamic quantities for the α-β transition in quartz

NASA Astrophysics Data System (ADS)

Lider, M. C.; Yurtseven, H.

2018-05-01

The resonant frequency shifts are related to the thermodynamic quantities (compressibility, order parameter and susceptibility) for the α-β transition in quartz. The experimental data for the resonant frequencies and the bulk modulus from the literature are used for those correlations. By calculating the order parameter from the mean field theory, correlation between the resonant frequencies of various modes and the order parameter is examined according to the quasi-harmonic phonon theory for the α-β transition in quartz. Also, correlation between the bulk modulus in relation to the resonant frequency shifts and the order parameter susceptibility is constructed for the α-β transition in this crystalline system.

Resonant nonlinear ultrasound spectroscopy

DOEpatents

Johnson, Paul A.; TenCate, James A.; Guyer, Robert A.; Van Den Abeele, Koen E. A.

2001-01-01

Components with defects are identified from the response to strains applied at acoustic and ultrasound frequencies. The relative resonance frequency shift .vertline..DELTA..function./.function..sub.0.vertline., is determined as a function of applied strain amplitude for an acceptable component, where .function..sub.0 is the frequency of the resonance peak at the lowest amplitude of applied strain and .DELTA..function. is the frequency shift of the resonance peak of a selected mode to determine a reference relationship. Then, the relative resonance frequency shift .vertline..DELTA..function./.function..sub.0 is determined as a function of applied strain for a component under test, where fo .function..sub.0 the frequency of the resonance peak at the lowest amplitude of applied strain and .DELTA..function. is the frequency shift of the resonance peak to determine a quality test relationship. The reference relationship is compared with the quality test relationship to determine the presence of defects in the component under test.

Hybrid Alfven resonant mode generation in the magnetosphere-ionosphere coupling system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hiraki, Yasutaka; Watanabe, Tomo-Hiko

2012-10-15

Feedback unstable Alfven waves involving global field-line oscillations and the ionospheric Alfven resonator (IAR) were comprehensively studied to clarify their properties of frequency dispersion, growth rate, and eigenfunctions. It is discovered that a new mode called here the hybrid Alfven resonant (HAR) mode can be destabilized in the magnetosphere-ionosphere coupling system with a realistic Alfven velocity profile. The HAR mode found in a high frequency range over 0.3 Hz is caused by coupling of IAR modes with strong dispersion and magnetospheric cavity resonances. The harmonic relation of HAR eigenfrequencies is characterized by a constant frequency shift from those of IARmore » modes. The three modes are robustly found even if effects of two-fluid process and ionospheric collision are taken into account and thus are anticipated to be detected by magnetic field observations in a frequency range of 0.3-1 Hz in auroral and polar-cap regions.« less

High speed strain measurement of active mode locking FBG laser sensor using chirped FBG cavity

NASA Astrophysics Data System (ADS)

Kim, Gyeong Hun; Kim, Joon Young; Park, Chang Hyun; Kim, Chang-Seok; Lee, Hwi Don; Chung, Youngjoo

2017-04-01

We propose a high speed strain measurement method using an active mode locking (AML) fiber Bragg grating (FBG) laser sensor with a chirped FBG cavity. The mode-locked frequency of the AML laser depends on both the position and Bragg wavelength of the FBG. Thus, the mode-locked frequency of cascaded FBGs can be detected independently along the cavity length of cascaded FBGs. The strain across FBGs can be interrogated dynamically by monitoring the change in mode-locked frequency. In this respect, the chirped FBG critically improves the frequency sensitivity to Bragg wavelength shift as a function of increasing dispersion in the AML cavity. The strain measurement of the FBG sensor shows a highly linear response, with an R-squared value of 0.9997.

Tuning the resonance frequencies and mode shapes in a large range multi-degree of freedom micromirror.

PubMed

Morrison, Jessica; Imboden, Matthias; Bishop, David J

2017-04-03

The ability to actively shift the primary resonance of a 2D scanning micromirror allows the user to set the scanning direction, set the scanning frequency, and lift otherwise degenerate modes in a symmetrically designed system. In most cases, resonant scanning micromirrors require frequency stability in order to perform imaging and projection functions properly. This paper suggests a method to tune the tip and tilt resonant frequencies in real time while actively suppressing or allowing degeneracy of the two modes in a symmetric electrothermal micromirror. We show resonant frequency tuning with a range of degeneracy separation of 470 Hz or by approximately ±15% and controllable coupling.

Raman spectroscopy and lattice dynamics of MgSiO3-perovskite at high pressure

NASA Astrophysics Data System (ADS)

Hemley, R. J.; Cohen, R. E.; Yeganeh-Haeri, A.; Mao, H. K.; Weidner, D. J.; Ito, E.

Vibrational Raman spectra have been obtained for 50 to 100 μm single crystals of MgSiO3 perovskite in situ at high pressure. Seven bands were tracked as a function of pressure to 26 GPa using a diamond-anvil high-pressure cell with rare-gas pressure-transmitting media. The frequency shifts with pressure are positive, and no soft modes were observed, in agreement with the present and previous lattice dynamics calculations. Zero-pressure frequency shifts (dυi/dP)0 vary between 1.7 and 4.2 cm-1/GPa, which contrasts with the uniform shift of 2.6 cm-1/GPa for modes measured in high-pressure mid-infrared spectra. The mode-Grüneisen parameters γi, determined from the present data span the range 1.6-1.9, and are generally higher than those reported in the infrared study. The Raman data are interpreted using the lattice dynamics calculated from the potential-induced breathing (PIB) model, a Gordon-Kim approach that includes the effects of charge relaxation on the dynamics. Good agreement with the experimentally determined frequencies is obtained, particularly in the lower frequency range, in comparison with previous rigid-ion results. The high thermal expansivity for MgSiO3-perovskite is shown to be due to the comparatively high values for γi associated with the lower frequency modes. Thermal weighting of the individual γi is required for an accurate calculation of the thermal Grüneisen parameter γTH and thermal expansivity.

Excited stilbene: intramolecular vibrational redistribution and solvation studied by femtosecond stimulated Raman spectroscopy.

PubMed

Weigel, A; Ernsting, N P

2010-06-17

Excited-state relaxation of cis- and trans-stilbene is traced with femtosecond stimulated Raman spectroscopy, exploiting S(n) <-- S(1) resonance conditions. For both isomers, decay in Raman intensity, shift of spectral positions, and broadening of the bands indicate intramolecular vibrational redistribution (IVR). In n-hexane this process effectively takes 0.5-0.7 ps. Analysis of the intensity decay allows us to further distinguish two phases for trans-stilbene: fast IVR within a subset of modes (approximately 0.3 ps) followed by slower equilibration over the full vibrational manifold (approximately 0.9 ps). In acetonitrile IVR completes with 0.15 ps; this acceleration may originate from symmetry breakage induced by the polar solvent. Another process, dynamic solvation by acetonitrile, is seen as spectral narrowing and characteristic band shifts of the C=C stretch and phenyl bending modes with 0.69 ps. Wavepacket motion is observed in both isomers as oscillation of low-frequency bands with their pertinent mode frequency (90 or 195 cm(-1) in trans-stilbene; 250 cm(-1) in cis-stilbene). Anharmonic coupling shows up as a modulation of high-frequency peak positions by phenyl/ethylene torsion modes of 57 and 90 cm(-1). Decay and shift of the 90 cm(-1) inverse Raman band within the first 0.3 ps suggests a gradual involvement of phenyl/ethylene torsion in relaxation. In cis- and trans-stilbene, low-frequency spectral changes are found within 0.15 ps, indicating an additional ultrafast process.

Wave propagation in strongly coupled classical plasmas in an external magnetic field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Genga, R.O.

When a small perturbation is applied to the plasma dispersion, a small shift of frequency due to correlation occurs. This is justified even for strong coupling, since the effect is proportional to k/sup 2/ (k is the wave vector) and it is sufficient to consider the k ..-->.. 0 limit. Then by solving the dispersion relations for delta omega, the shift of frequency due to correlation, at different angles of propagation, we obtain all information needed. The plasma modes in which we are primarily interested are the whistler and the extraordinary modes. In this work the STLS (Singwi, Tosi, Land,more » and Sjolander) approximation scheme is used. It is seen that the correlational effects enter only through terms of order k/sup 6/ for the whistler mode and terms of order k/sup 2/ for the nonresonant situation of the extraordinary mode.« less

Multi-Mode Excitation and Data Reduction for Fatigue Crack Characterization in Conducting Plates

NASA Technical Reports Server (NTRS)

Wincheski, B.; Namkung, M.; Fulton, J. P.; Clendenin, C. G.

1992-01-01

Advances in the technique of fatigue crack characterization by resonant modal analysis have been achieved through a new excitation mechanism and data reduction of multiple resonance modes. A non-contacting electromagnetic device is used to apply a time varying Lorentz force to thin conducting sheets. The frequency and direction of the Lorentz force are such that resonance modes are generated in the test sample. By comparing the change in frequency between distinct resonant modes of a sample, detecting and sizing of fatigue cracks are achieved and frequency shifts caused by boundary condition changes can be discriminated against. Finite element modeling has been performed to verify experimental results.

Modelling of rotation-induced frequency shifts in whispering gallery modes

NASA Astrophysics Data System (ADS)

Venediktov, V. Yu; Kukaev, A. S.; Filatov, Yu V.; Shalymov, E. V.

2018-02-01

We study the angular velocity sensors based on whispering gallery mode resonators. Rotation of such resonators gives rise to various effects that can cause a spectral shift of their modes. Optical methods allow this shift to be determined with high precision, which can be used practically to measure the angular velocity in inertial orientation and navigation systems. The basic principles of constructing the angular velocity sensors utilising these effects are considered, their advantages and drawbacks are indicated. We also study the interrelation between the effects and the possibility of their mutual influence on each other. Based on the analytical studies of the effects, we consider the possibility of their combined application for angular velocity measurements.

Biosensing in a microelectrofluidic system using optical whispering-gallery mode spectroscopy

PubMed Central

Huang, Lei; Guo, Zhixiong

2011-01-01

Label-free detection of biomolecules using an optical whispering-gallery mode sensor in a microelectrofluidic channel is simulated. Negatively charged bovine serum albumin is considered as the model protein analyte. The analyte transport in aqueous solution is controlled by an externally applied electrical field. The finite element method is employed for solving the equations of the charged species transport, the Poisson equation of electric potential, the equations of conservation of momentum and energy, and the Helmholtz equations of electromagnetic waves. The adsorption process of the protein molecules on the microsensor head surface is monitored by the resonance frequency shifts. Frequency shift caused by temperature variation due to Joule heating is analyzed and found to be negligible. The induced shifts behave in a manner similar to Langmuir-like adsorption kinetics; but the time constant increases due to the presence of the external electrical field. A correlation of the frequency shift, the analyte feed concentration in the solution, and the applied voltage gradient is obtained, in which an excellent linear relationship between the frequency shift and the analyte concentration is revealed. The applied voltage gradient enhances significantly the analyte concentration in the vicinity of the sensor surface; thus, the sensor sensitivity which has a power function of the voltage gradient with exponent 2.85 in the controlled voltage range. Simulated detection of extremely low protein concentration to the pico-molar level is carried out. PMID:22662041

Coherent radio-frequency detection for narrowband direct comb spectroscopy.

PubMed

Anstie, James D; Perrella, Christopher; Light, Philip S; Luiten, Andre N

2016-02-22

We demonstrate a scheme for coherent narrowband direct optical frequency comb spectroscopy. An extended cavity diode laser is injection locked to a single mode of an optical frequency comb, frequency shifted, and used as a local oscillator to optically down-mix the interrogating comb on a fast photodetector. The high spectral coherence of the injection lock generates a microwave frequency comb at the output of the photodiode with very narrow features, enabling spectral information to be further down-mixed to RF frequencies, allowing optical transmittance and phase to be obtained using electronics commonly found in the lab. We demonstrate two methods for achieving this step: a serial mode-by-mode approach and a parallel dual-comb approach, with the Cs D1 transition at 894 nm as a test case.

Electron temperature and density probe for small aeronomy satellites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oyama, K.-I.; Institute of Space and Plasma Sciences, National Cheng Kung University, Tainan, Taiwan; International Center for Space Weather Study and education, Kyushu University, Fukuoka

2015-08-15

A compact and low power consumption instrument for measuring the electron density and temperature in the ionosphere has been developed by modifying the previously developed Electron Temperature Probe (ETP). A circuit block which controls frequency of the sinusoidal signal is added to the ETP so that the instrument can measure both T{sub e} in low frequency mode and N{sub e} in high frequency mode from the floating potential shift of the electrode. The floating potential shift shows a minimum at the upper hybrid resonance frequency (f{sub UHR}). The instrument which is named “TeNeP” can be used for tiny satellites whichmore » do not have enough conductive surface area for conventional DC Langmuir probe measurements. The instrument also eliminates the serious problems associated with the contamination of satellite surface as well as the sensor electrode.« less

Mode suppression means for gyrotron cavities

DOEpatents

Chodorow, Marvin; Symons, Robert S.

1983-08-09

In a gyrotron electron tube of the gyro-klystron or gyro-monotron type, having a cavity supporting an electromagnetic mode with circular electric field, spurious resonances can occur in modes having noncircular electric field. These spurious resonances are damped and their frequencies shifted by a circular groove in the cavity parallel to the electric field.

A Raman Spectroscopic Study of Kernite to 25 GPa

NASA Astrophysics Data System (ADS)

Silva, M. E.; O'Bannon, E. F., III; Williams, Q. C.

2015-12-01

A Raman spectroscopic study of kernite to 25 GPaMarcus Silva, Earl O'Bannon III, and Quentin Williams Department of Earth & Planetary Sciences, University of California Santa Cruz The Raman spectrum of kernite (Na2B4O6(OH)2·3(H2O)) has been characterized up to ~25 GPa in order to explore pressure-induced changes in a structurally novel mineral that contains mixed coordination borate groups (three- and four-fold), and both hydroxyl units and water. During compression, all of the ~30 modes monitored shift positively and monotonically until ~2.2 GPa where a few low frequency modes disappear and tetrahedral borate modes merge. The low frequency modes that disappear at ~2.2 GPa are likely associated with Na vibrations, and their disappearance suggests that dramatic changes occur in the Na sites at ~2.2 GPa. The merging of the boron bending and stretching modes at ~2.2 GPa suggests that the local symmetry of the BO4 tetrahedra changes at this pressure, and likely becomes more symmetric. The remaining modes shift positively up to ~7.4 GPa where a second notable change occurs. All but 5 modes (with initial frequencies of 150, 166, 289, 307, and 525 cm-1) disappear at ~7.4 GPa. This indicates that a second phase transition has occurred which affects both the BO3H and BO4­ groups: based on the loss of modes, this transition may be associated with disordering of the crystal. These 5 modes persist and shift monotonically up to ~25 GPa. On decompression, the 5 modes shift smoothly down to ~2.0 GPa where a few new modes appear in the spectrum. When fully decompressed to room pressure, the Raman spectrum of the recovered sample is significantly different from the ambient spectrum of the initial sample. Thus, our results are suggest a phase transition occurring at 2.2 GPa with changes in the Na and tetrahedral boron sites, followed by an additional transition at 7.4 GPa that may involve disordering of the crystal. In the latter transition, at least the BO3H groups appear to be destabilized, implying that the three-fold coordination of boron groups is, in contrast to the case of carbon, unstable in crystalline phases at relatively modest pressure conditions.

Large amplitude m=1 diocotron mode measurements in the Electron Diffusion Gauge experiment

NASA Astrophysics Data System (ADS)

Jenkins, Thomas G.; Morrison, Kyle A.; Davidson, Ronald C.; Paul, Stephen F.

2002-01-01

Smaller-diameter pure electron plasmas are generated in the Electron Diffusion Gauge (EDG) using a thoriated tungsten filament wound into a spiral shape with an outer diameter which is 1/4 of the trap wall diameter. The m=1 diocotron mode is excited in the plasma by means of the resistive-wall instability, using a resistor-relay circuit which allows the mode to be induced at various initial amplitudes. The dynamics of this mode may be predicted using linear theory when the amplitude is small. However, it has been observed [e.g., Fine et al., Phys. Rev. Lett. 63, 2232 (1989)] [1] that at larger amplitudes the frequency of this mode (relative to the small-amplitude frequency) exhibits a quadratic dependence on the mode amplitude. In this paper, the frequency shift and nonlinear dynamics of the m=1 diocotron mode in the EDG device are investigated.

Triple-mode single-transistor graphene amplifier and its applications.

PubMed

Yang, Xuebei; Liu, Guanxiong; Balandin, Alexander A; Mohanram, Kartik

2010-10-26

We propose and experimentally demonstrate a triple-mode single-transistor graphene amplifier utilizing a three-terminal back-gated single-layer graphene transistor. The ambipolar nature of electronic transport in graphene transistors leads to increased amplifier functionality as compared to amplifiers built with unipolar semiconductor devices. The ambipolar graphene transistors can be configured as n-type, p-type, or hybrid-type by changing the gate bias. As a result, the single-transistor graphene amplifier can operate in the common-source, common-drain, or frequency multiplication mode, respectively. This in-field controllability of the single-transistor graphene amplifier can be used to realize the modulation necessary for phase shift keying and frequency shift keying, which are widely used in wireless applications. It also offers new opportunities for designing analog circuits with simpler structure and higher integration densities for communications applications.

Fundamental (f) oscillations in a magnetically coupled solar interior-atmosphere system - An analytical approach

NASA Astrophysics Data System (ADS)

Pintér, Balázs; Erdélyi, R.

2018-01-01

Solar fundamental (f) acoustic mode oscillations are investigated analytically in a magnetohydrodynamic (MHD) model. The model consists of three layers in planar geometry, representing the solar interior, the magnetic atmosphere, and a transitional layer sandwiched between them. Since we focus on the fundamental mode here, we assume the plasma is incompressible. A horizontal, canopy-like, magnetic field is introduced to the atmosphere, in which degenerated slow MHD waves can exist. The global (f-mode) oscillations can couple to local atmospheric Alfvén waves, resulting, e.g., in a frequency shift of the oscillations. The dispersion relation of the global oscillation mode is derived, and is solved analytically for the thin-transitional layer approximation and for the weak-field approximation. Analytical formulae are also provided for the frequency shifts due to the presence of a thin transitional layer and a weak atmospheric magnetic field. The analytical results generally indicate that, compared to the fundamental value (ω =√{ gk }), the mode frequency is reduced by the presence of an atmosphere by a few per cent. A thin transitional layer reduces the eigen-frequencies further by about an additional hundred microhertz. Finally, a weak atmospheric magnetic field can slightly, by a few percent, increase the frequency of the eigen-mode. Stronger magnetic fields, however, can increase the f-mode frequency by even up to ten per cent, which cannot be seen in observed data. The presence of a magnetic atmosphere in the three-layer model also introduces non-permitted propagation windows in the frequency spectrum; here, f-mode oscillations cannot exist with certain values of the harmonic degree. The eigen-frequencies can be sensitive to the background physical parameters, such as an atmospheric density scale-height or the rate of the plasma density drop at the photosphere. Such information, if ever observed with high-resolution instrumentation and inverted, could help to gain further insight into solar magnetic structures by means of solar magneto-seismology, and could provide further insight into the role of magnetism in solar oscillations.

Ultralow-frequency collective compression mode and strong interlayer coupling in multilayer black phosphorus

DOE PAGES

Dong, Shan; Zhang, Anmin; Liu, Kai; ...

2016-02-26

The recent renaissance of black phosphorus (BP) as a two-dimensional (2D) layered material has generated tremendous interest, but its unique structural characters underlying many of its outstanding properties still need elucidation. Here we report Raman measurements that reveal an ultralow-frequency collective compression mode (CCM) in BP, which is unprecedented among similar 2D layered materials. This novel CCM indicates an unusually strong interlayer coupling, and this result is quantitatively supported by a phonon frequency analysis and first-principles calculations. Moreover, the CCM and another branch of low-frequency Raman modes shift sensitively with changing number of layers, allowing an accurate determination of themore » thickness up to tens of atomic layers, which is considerably higher than previously achieved by using high-frequency Raman modes. Lastly, these findings offer fundamental insights and practical tools for further exploration of BP as a highly promising new 2D semiconductor.« less

Diversified pulse generation from frequency shifted feedback Tm-doped fibre lasers.

PubMed

Chen, He; Chen, Sheng-Ping; Jiang, Zong-Fu; Hou, Jing

2016-05-19

Pulsed fibre lasers operating in the eye-safe 2 μm spectral region have numerous potential applications in areas such as remote sensing, medicine, mid-infrared frequency conversion, and free-space communication. Here, for the first time, we demonstrate versatile 2 μm ps-ns pulses generation from Tm-based fibre lasers based on frequency shifted feedback and provide a comprehensive report of their special behaviors. The lasers are featured with elegant construction and the unparalleled capacity of generating versatile pulses. The self-starting mode-locking is initiated by an intra-cavity acousto-optical frequency shifter. Diversified mode-locked pulse dynamics were observed by altering the pump power, intra-cavity polarization state and cavity structure, including as short as 8 ps single pulse sequence, pulse bundle state and up to 12 nJ, 3 ns nanosecond rectangular pulse. A reflective nonlinear optical loop mirror was introduced to successfully shorten the pulses from 24 ps to 8 ps. Beside the mode-locking operation, flexible Q-switching and Q-switched mode-locking operation can also be readily achieved in the same cavity. Up to 78 μJ high energy nanosecond pulse can be generated in this regime. Several intriguing pulse dynamics are characterized and discussed.

The interplay between the kinetic nonlinear frequency shift and the flowing gradient in stimulated Brillouin scattering

NASA Astrophysics Data System (ADS)

Wang, Q.; Y Zheng, C.; Liu, Z. J.; Xiao, C. Z.; Feng, Q. S.; Zhang, H. C.; He, X. T.

2018-02-01

The effect of the kinetic nonlinear frequency shift (KNFS) on backward stimulated Brillouin scattering (SBS) in homogeneous plasmas and inhomogeneous flowing plasmas is investigated by three-wave coupled-mode equations. When the positive contribution to the KNFS from electrons as well as the negative contribution from ions is included, the net KNFS can become positive at a large electron-ion temperature ratio {{ZT}}e/{T}i. In homogeneous plasmas, KNFS can greatly reduce the SBS reflectivity at low or large {{ZT}}e/{T}i but has a weak effect on SBS at {{ZT}}e/{T}i where the positive frequency shifts from electrons almost cancels out the negative shifts from ions. In inhomogeneous plasmas, the net negative frequency shift can enhance the backward SBS reflectivity for the negative gradient of the plasma flowing, and can suppress the reflectivity for the positive case. On the contrary, the net positive frequency can suppress the reflectivity for the negative case of the flowing gradient and enhance the reflectivity for the positive case. This indicates that the SBS in inhomogeneous flowing plasmas can be controlled by changing the sign of the nonlinear frequency shift.

Acoustic levitation and the Boltzmann-Ehrenfest principle

NASA Technical Reports Server (NTRS)

Putterman, S.; Rudnick, Joseph; Barmatz, M.

1989-01-01

The Boltzmann-Ehrenfest principle of adiabatic invariance relates the acoustic potential acting on a sample positioned in a single-mode cavity to the shift in resonant frequency caused by the presence of this sample. This general and simple relation applies to samples and cavities of arbitrary shape, dimension, and compressibility. Positioning forces and torques can, therefore, be determined from straightforward measurements of frequency shifts. Applications to the Rayleigh disk phenomenon and levitated cylinders are presented.

Nonlinear frequency doubling characteristics of asymmetric vortices of tunable, broad orbital angular momentum spectrum

NASA Astrophysics Data System (ADS)

Alam, Sabir Ul; Rao, A. Srinivasa; Ghosh, Anirban; Vaity, Pravin; Samanta, G. K.

2018-04-01

We report on a simple experimental scheme to generate and control the orbital angular momentum (OAM) spectrum of the asymmetric vortex beams in a nonlinear frequency conversion process. Using a spiral phase plate (SPP) and adjusting the transverse shift of the SPP with respect to the incident Gaussian beam axis, we have transformed the symmetric (intensity distribution) optical vortex of order l into an asymmetric vortex beam of measured broad spectrum of OAM modes of orders l, l - 1, l - 2, …, 0 (Gaussian mode). While the position of the SPP determines the distribution of the OAM modes, we have also observed that the modal distribution of the vortex beam changes with the shift of the SPP of all orders and finally results in a Gaussian beam (l = 0). Using single-pass frequency doubling of the asymmetric vortices, we have transferred the pump OAM spectra, l, l - 1, l - 2, …, 0, into the broad spectra of higher order OAM modes, 2l, 2l - 1, 2l - 2, …, 0 at green wavelength, owing to OAM conservation in nonlinear processes. We also observed an increase in single-pass conversion efficiency with the increase in asymmetry of the pump vortices producing a higher power vortex beam of mixed OAM modes at a new wavelength than that of the pure OAM mode.

Photodissociation Spectroscopy of Cold Protonated Synephrine: Surprising Differences between IR-UV Hole-Burning and IR Photodissociation Spectroscopy of the O-H and N-H Modes.

PubMed

Nieuwjaer, N; Desfrançois, C; Lecomte, F; Manil, B; Soorkia, S; Broquier, M; Grégoire, G

2018-04-19

We report the UV and IR photofragmentation spectroscopies of protonated synephrine in a cryogenically cooled Paul trap. Single (UV or IR) and double (UV-UV and IR-UV) resonance spectroscopies have been performed and compared to quantum chemistry calculations, allowing the assignment of the lowest-energy conformer with two rotamers depending on the orientation of the phenol hydroxyl (OH) group. The IR-UV hole burning spectrum exhibits the four expected vibrational modes in the 3 μm region, i.e., the phenol OH, C β -OH, and two NH 2 + stretches. The striking difference is that, among these modes, only the free phenol OH mode is active through IRPD. The protonated amino group acts as a proton donor in the internal hydrogen bond and displays large frequency shifts upon isomerization expected during the multiphoton absorption process, leading to the so-called IRMPD transparency. More interestingly, while the C β -OH is a proton acceptor group with moderate frequency shift for the different conformations, this mode is still inactive through IRPD.

Shape Oscillations of Gas Bubbles With Newtonian Interfacial Rheological Properties

NASA Technical Reports Server (NTRS)

Nadim, Ali

1996-01-01

The oscillation frequency and damping rate for small-amplitude axisymmetric shape modes of a gas bubble in an ideal liquid are obtained, in the limit when the bubble interface possesses Newtonian interfacial rheology with constant surface shear and dilatational viscosities. Such results permit the latter surface properties to be measured by analyzing experimental data on frequency shift and damping rate of specific shape modes of suspended bubbles in the presence of surfactants.

Integrated nanophotonic frequency shifter on the silicon-organic hybrid (SOH) platform for laser vibrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lauermann, M.; Weimann, C.; Palmer, R.

2014-05-27

We demonstrate a waveguide-based frequency shifter on the silicon photonic platform, enabling frequency shifts up to 10 GHz. The device is realized by silicon-organic hybrid (SOH) integration. Temporal shaping of the drive signal allows the suppression of spurious side-modes by more than 23 dB.

Multi-mode of Four and Six Wave Parametric Amplified Process

NASA Astrophysics Data System (ADS)

Zhu, Dayu; Yang, Yiheng; Zhang, Da; Liu, Ruizhou; Ma, Danmeng; Li, Changbiao; Zhang, Yanpeng

2017-03-01

Multiple quantum modes in correlated fields are essential for future quantum information processing and quantum computing. Here we report the generation of multi-mode phenomenon through parametric amplified four- and six-wave mixing processes in a rubidium atomic ensemble. The multi-mode properties in both frequency and spatial domains are studied. On one hand, the multi-mode behavior is dominantly controlled by the intensity of external dressing effect, or nonlinear phase shift through internal dressing effect, in frequency domain; on the other hand, the multi-mode behavior is visually demonstrated from the images of the biphoton fields directly, in spatial domain. Besides, the correlation of the two output fields is also demonstrated in both domains. Our approach supports efficient applications for scalable quantum correlated imaging.

Multi-mode of Four and Six Wave Parametric Amplified Process.

PubMed

Zhu, Dayu; Yang, Yiheng; Zhang, Da; Liu, Ruizhou; Ma, Danmeng; Li, Changbiao; Zhang, Yanpeng

2017-03-03

Multiple quantum modes in correlated fields are essential for future quantum information processing and quantum computing. Here we report the generation of multi-mode phenomenon through parametric amplified four- and six-wave mixing processes in a rubidium atomic ensemble. The multi-mode properties in both frequency and spatial domains are studied. On one hand, the multi-mode behavior is dominantly controlled by the intensity of external dressing effect, or nonlinear phase shift through internal dressing effect, in frequency domain; on the other hand, the multi-mode behavior is visually demonstrated from the images of the biphoton fields directly, in spatial domain. Besides, the correlation of the two output fields is also demonstrated in both domains. Our approach supports efficient applications for scalable quantum correlated imaging.

Optical frequency-domain chromatic dispersion measurement method for higher-order modes in an optical fiber.

PubMed

Ahn, Tae-Jung; Jung, Yongmin; Oh, Kyunghwan; Kim, Dug Young

2005-12-12

We propose a new chromatic dispersion measurement method for the higher-order modes of an optical fiber using optical frequency modulated continuous-wave (FMCW) interferometry. An optical fiber which supports few excited modes was prepared for our experiments. Three different guiding modes of the fiber were identified by using far-field spatial beam profile measurements and confirmed with numerical mode analysis. By using the principle of a conventional FMWC interferometry with a tunable external cavity laser, we have demonstrated that the chromatic dispersion of a few-mode optical fiber can be obtained directly and quantitatively as well as qualitatively. We have also compared our measurement results with those of conventional modulation phase-shift method.

Pressure Dependence of the Radial Breathing Mode of Carbon Nanotubes: The Effect of Fluid Adsorption

NASA Astrophysics Data System (ADS)

Longhurst, M. J.; Quirke, N.

2007-04-01

The pressure dependence of shifts in the vibrational modes of individual carbon nanotubes is strongly affected by the nature of the pressure transmitting medium as a result of adsorption at the nanotube surface. The adsorbate is treated as an elastic shell which couples with the radial breathing mode (RBM) of the nanotube via van der Waal interactions. Using analytical methods as well as molecular simulation, we observe a low frequency breathing mode for the adsorbed fluid at ˜50cm-1, as well as diameter dependent upshifts in the RBM frequency with pressure, suggesting metallic nanotubes may wet more than semiconducting ones.

Experimental study of the effect of 2/1 classical tearing mode on (intermediate, small)-scale microturbulence in the core of an EAST L mode plasma

NASA Astrophysics Data System (ADS)

Sun, P. J.; Li, Y. D.; Ren, Y.; Zhang, X. D.; Wu, G. J.; Lyu, B.; Shi, T. H.; Xu, L. Q.; Wang, F. D.; Li, Q.; Zhang, J. Z.; Hu, L. Q.; Li, J. G.; the EAST Team

2018-02-01

In this paper, we report an experimental study of the effect of a m/n = -2/-1 (m, n being poloidal and toroidal mode number, separately) classical tearing mode on (intermediate, small)-scale microturbulence (see the definition in section 1) in the core of an EAST L mode plasma discharge. The microturbulence at different scales k ⊥ = 10, 18 and 26 cm-1 (i.e., {k}\\perp {ρ }i˜ 2, 3.6 and 5.2, respectively. Here, {ρ }i is the ion gyroradius and k ⊥ is the perpendicular wavenumber) were measured simultaneously by the EAST multi-channel tangential CO2 laser collective scattering diagnostics. Experimental results confirm that the decrease of microturbulent Doppler shift ({f}{{Doppler}}={k}t{v}t/2π ), inversely correlated to the increase of microturbulent mean frequency (defined in equation (1)), is due to the 2/1 tearing mode. Temporal evolution of frequency-integrated spectral power S tot of microturbulence, found to be correlated with the width of 2/1 magnetic island, suggests the modulation effect on microturbulence by the tearing mode beyond Doppler shift effect. Modulation effects on microturbulence by the tearing mode are further demonstrated by the correlation between microturbulent envelope and magnetic fluctuations.

Duffing revisited: phase-shift control and internal resonance in self-sustained oscillators

NASA Astrophysics Data System (ADS)

Arroyo, Sebastián I.; Zanette, Damián H.

2016-01-01

We address two aspects of the dynamics of the forced Duffing oscillator which are relevant to the technology of micromechanical devices and, at the same time, have intrinsic significance to the field of nonlinear oscillating systems. First, we study the stability of periodic motion when the phase shift between the external force and the oscillation is controlled - contrary to the standard case, where the control parameter is the frequency of the force. Phase-shift control is the operational configuration under which self-sustained oscillators - and, in particular, micromechanical oscillators - provide a frequency reference useful for time keeping. We show that, contrary to the standard forced Duffing oscillator, under phase-shift control oscillations are stable over the whole resonance curve, and provide analytical approximate expressions for the time dependence of the oscillation amplitude and frequency during transients. Second, we analyze a model for the internal resonance between the main Duffing oscillation mode and a higher-harmonic mode of a vibrating solid bar clamped at its two ends. We focus on the stabilization of the oscillation frequency when the resonance takes place, and present preliminary experimental results that illustrate the phenomenon. This synchronization process has been proposed to counteract the undesirable frequency-amplitude interdependence in nonlinear time-keeping micromechanical devices. Supplementary material in the form of one pdf file and one gif file available from the Journal web page at http://dx.doi.org/10.1140/epjb/e2015-60517-3

Bernstein modes in a non-neutral plasma column

NASA Astrophysics Data System (ADS)

Walsh, Daniel; Dubin, Daniel H. E.

2018-05-01

This paper presents theory and numerical calculations of electrostatic Bernstein modes in an inhomogeneous cylindrical plasma column. These modes rely on finite Larmor radius effects to propagate radially across the column until they are reflected when their frequency matches the upper hybrid frequency. This reflection sets up an internal normal mode on the column and also mode-couples to the electrostatic surface cyclotron wave (which allows the normal mode to be excited and observed using external electrodes). Numerical results predicting the mode spectra, using a novel linear Vlasov code on a cylindrical grid, are presented and compared to an analytical Wentzel Kramers Brillouin (WKB) theory. A previous version of the theory [D. H. E. Dubin, Phys. Plasmas 20(4), 042120 (2013)] expanded the plasma response in powers of 1/B, approximating the local upper hybrid frequency, and consequently, its frequency predictions are spuriously shifted with respect to the numerical results presented here. A new version of the WKB theory avoids this approximation using the exact cold fluid plasma response and does a better job of reproducing the numerical frequency spectrum. The effect of multiple ion species on the mode spectrum is also considered, to make contact with experiments that observe cyclotron modes in a multi-species pure ion plasma [M. Affolter et al., Phys. Plasmas 22(5), 055701 (2015)].

Anharmonic phonon-polariton dynamics in ferroelectric LiNbO3 studied with single-shot pump-probe imaging spectroscopy

NASA Astrophysics Data System (ADS)

Kuribayashi, T.; Motoyama, T.; Arashida, Y.; Katayama, I.; Takeda, J.

2018-05-01

We demonstrate that single-shot pump-probe imaging spectroscopy with an echelon mirror enables us to disclose the ferroelectric phonon-polariton dynamics across a wide temperature range from 10 K to 375 K while avoiding the photorefractive effects that appear prominently at low temperatures. The E-mode phonon-polaritons corresponding to the two transverse optical modes, TO1 and TO3, up to ˜7 THz were induced in LiNbO3 through an impulsive stimulated Raman scattering process. Subsequently, using single-shot pump-probe imaging spectroscopy over a minimal cumulative time, we successfully visualized the phonon-polariton dynamics in time-wavelength space even at low temperatures. We found that the phase-matching condition significantly affected the observed temperature-dependent phonon-polariton frequency shift. The anharmonicity of the TO1 and TO3 modes was then evaluated based on an anharmonic model involving higher-order interactions with acoustic phonons while eliminating the influence of the frequency shift due to the phase-matching condition. The observed wavenumber-dependent damping rate was analyzed by considering the bilinear coupling of the TO1 or TO3 modes with the thermally activated relaxation mode. We found that the phonon-polariton with a higher frequency and wavenumber had a higher damping rate at high temperatures because of its frequent interaction with the thermally activated relaxation mode and acoustic phonons. The TO3 mode displayed greater bilinear coupling than the TO1 mode, which may also have contributed to the observed high damping rate. Thus, using our unique single-shot spectroscopy technique, we could reveal the overall anharmonic characteristics of the E-mode phonon-polaritons arising from both the acoustic phonons and the relaxation mode.

Acoustic Mode Hybridization in a Single Dimer of Gold Nanoparticles.

PubMed

Girard, Adrien; Gehan, Hélène; Mermet, Alain; Bonnet, Christophe; Lermé, Jean; Berthelot, Alice; Cottancin, Emmanuel; Crut, Aurélien; Margueritat, Jérémie

2018-06-13

The acoustic vibrations of single monomers and dimers of gold nanoparticles were investigated by measuring for the first time their ultralow-frequency micro-Raman scattering. This experiment provides access not only to the frequency of the detected vibrational modes but also to their damping rate, which is obscured by inhomogeneous effects in measurements on ensembles of nano-objects. This allows a detailed analysis of the mechanical coupling occurring between two close nanoparticles (mediated by the polymer surrounding them) in the dimer case. Such coupling induces the hybridization of the vibrational modes of each nanoparticle, leading to the appearance in the Raman spectra of two ultralow-frequency modes corresponding to the out-of-phase longitudinal and transverse (with respect to the dimer axis) quasi-translations of the nanoparticles. Additionally, it is also shown to shift the frequency of the quadrupolar modes of the nanoparticles. Experimental results are interpreted using finite-element simulations, which enable the unambiguous identification of the detected modes and despite the simplifications made lead to a reasonable reproduction of their measured frequencies and quality factors. The demonstrated feasibility of low-frequency Raman scattering experiments on single nano-objects opens up new possibilities to improve the understanding of nanoscale vibrations with this technique being complementary with single nano-object time-resolved spectroscopy as it gives access to different vibrational modes.

Unusual phonon behavior and ultra-low thermal conductance of monolayer InSe.

PubMed

Zhou, Hangbo; Cai, Yongqing; Zhang, Gang; Zhang, Yong-Wei

2017-12-21

Monolayer indium selenide (InSe) possesses numerous fascinating properties, such as high electron mobility, quantum Hall effect and anomalous optical response. However, its phonon properties, thermal transport properties and the origin of its structural stability remain unexplored. Using first-principles calculations, we show that the atoms in InSe are highly polarized and such polarization causes strong long-range dipole-dipole interaction (DDI). For acoustic modes, DDI is essential for maintaining its structural stability. For optical modes, DDI causes a significant frequency shift of its out-of-phase vibrations. Surprisingly, we observed that there were two isolated frequency regimes, which were completely separated from other frequency regimes with large frequency gaps. Within each frequency regime, only a single phonon mode exists. We further reveal that InSe possesses the lowest thermal conductance among the known two-dimensional materials due to the low cut-off frequency, low phonon group velocities and the presence of large frequency gaps. These unique behaviors of monolayer InSe can enable the fabrication of novel devices, such as thermoelectric module, single-mode phonon channel and phononic laser.

Frequency stabilization and transverse mode discrimination in injection-seeded unstable resonator TEA CO2 lasers

NASA Technical Reports Server (NTRS)

Ancellet, G. M.; Menzies, R. T.; Brothers, A. M.

1987-01-01

Longitudinal mode selection by injection has been demonstrated as a viable technique for TEA-CO2 lasers with pulse energies of a Joule or greater. Once reliable generation of single-longitudinal-mode (SLM) pulses is obtained, the characteristics and the causes of intrapulse frequency variation can be studied. These include the effect of the decaying plasma, the thermal gradient due to the energy dissipation associated with the laser mechanism itself, and the pressure shift of the center frequency of the laser transition. The use of the positive-branch unstable resonator as an efficient means of coupling a discharge with large spatial dimensions to an optical cavity mode introduces another concern: namely, what can be done to emphasize transverse mode discrimination in an unstable resonator cavity while maintaining high coupling efficiency. These issues are discussed in this paper, and relevant experimental results are included.

Infrared and Raman spectroscopic study of BDA-TTP [2,5-bis(1,3-dithian-2-ylidene) 1,3,4,6-tetrathiapentalene] and its charge-transfer salts

NASA Astrophysics Data System (ADS)

Uruichi, Mikio; Nakano, Chikako; Tanaka, Masayuki; Yakushi, Kyuya; Kaihatsu, Takayuki; Yamada, Jun-ichi

2008-09-01

Infrared and Raman spectra in the frequency range of 1200-1600 cm -1 were observed using BDA-TTP and (BDA-TTP)CuCl 2 crystals. The C =C stretching and CH 2 bending modes in this frequency region were assigned based on quantum chemical calculation of the normal modes by the density functional theory (DFT) method. The three C =C stretching modes of BDA-TTP showed a significant low-frequency shift upon oxidation. One of the Raman-active C =C stretching modes is strongly coupled with the charge-transfer excited state. Vibrational analysis was applied to β-(BDA-TTP) 2I 3. The infrared-active C =C stretching mode strongly suggests that the insulating state of β-(BDA-TTP) 2I 3 is characterized as a dimer-Mott state below 150 K.

Predator-prey modeling of the coupling of co-propagating CAE to kink modes

NASA Astrophysics Data System (ADS)

Fredrickson, Eric

2012-10-01

Co-propagating Compressional Alfven eigenmodes (CAE) with shorter wavelength and higher frequency than the counter-propagating CAE and Global Alfven eigenmodes (GAE) often accompany a low frequency n=1 kink. The lower frequency CAE and GAE are excited through a Doppler-shifted cyclotron resonance; the high frequency CAE (hfCAE) through a simple parallel resonance. We present measurements of the mode structure and spectrum of the hfCAE, and compare those measurements to predictions of a simple model for CAE. The modes are bursting with a typical burst frequency on the order of a few kHz. The n=1 kink frequency is usually higher than this, but when the kink frequency does drop towards the hfCAE burst frequency, the hfCAE burst frequency can become locked with the kink frequency. A simple predator-prey model to simulate the hfCAE bursting demonstrates that a modulation of the growth or damping rate by a few percent, at a frequency near the natural burst frequency, can lock the burst frequency to the modulation frequency. The modulation of the damping rate is postulated to be through a coupling of the kink with a symmetry-breaking error field. The deeper question is how the kink interaction with a locked mode can affect the damping/growth rates of the CAE.

Single-resonator double-negative metamaterial

DOEpatents

Warne, Larry K.; Basilio, Lorena I.; Langston, William L.; Johnson, William A.; Ihlefeld, Jon; Ginn, III, James C.; Clem, Paul G.; Sinclair, Michael B.

2016-06-21

Resonances can be tuned in dielectric resonators in order to construct single-resonator, negative-index metamaterials. For example, high-contrast inclusions in the form of metallic dipoles can be used to shift the first electric resonance down (in frequency) to the first magnetic resonance, or alternatively, air splits can be used to shift the first magnetic resonance up (in frequency) near the first electric resonance. Degenerate dielectric designs become especially useful in infrared- or visible-frequency applications where the resonator sizes associated with the lack of high-permittivity materials can become of sufficient size to enable propagation of higher-order lattice modes in the resulting medium.

Frequency-dependent behavior of the barotropic and baroclinic modes of zonal jet variability

NASA Astrophysics Data System (ADS)

Sheshadri, A.; Plumb, R. A.

2016-12-01

Stratosphere-troposphere interactions are frequently described in terms of the leading modes of variability, i.e. the annular modes. An idealized dynamical core model is used to explore the differences between the low- and high- frequency (periods greater and less than 30 days) behavior of the first two principal components of zonal mean zonal wind and eddy kinetic energy, i.e., the barotropic/baroclinic annular modes of variability of the extratropical circulation. The modes show similar spatial characteristics in the different frequency ranges considered, however the ranking of the modes switches in some cases from one range to the other. There is some cancelation in the signatures of eddy heat flux and eddy kinetic energy in the leading low-pass and high-pass filtered zonal wind mode, partly explaining their small signature in the total. At low frequencies, the first zonal wind mode describes latitudinal shifts of both the midlatitude jet and its associated storm tracks, and the persistence of zonal wind anomalies appears to be sustained primarily by a baroclinic, rather than a barotropic, feedback. On shorter time scales, the behavior is more complicated and transient.

A numerical analysis of GeO2-doped multi-step index single-mode fiber for stimulated Brillouin scattering

NASA Astrophysics Data System (ADS)

Xiao, H.; Ren, G.; Dong, Y.; Li, H.; Xiao, S.; Wu, B.; Jian, S.

2018-06-01

A numerical analysis of a GeO2-doped single-mode optical fiber with a multi-step index core toward stimulated Brillouin scattering (SBS) based dual-parameter sensing applications is proposed. Adjusting the parameters in the fiber design, higher-order acoustic modes are sufficiently enhanced, making the fiber feasible for discriminative measurements of temperature and strain in the meantime. Numerical simulations indicate that the Brillouin frequency shifts and peak SBS efficiencies are strongly dependent on the doping concentration and the thickness of low-index ring in the proposed fiber. With appropriate structural and optical parameters, this fiber could support two distinct acoustic modes with comparable peak SBS efficiencies and well-spaced Brillouin frequency shifts. The sensing characteristics contributed by the dual-peak feature in the Brillouin gain spectrum are explored. Calculated accuracies of temperature and strain in simultaneous measurements can be up to 0.64 °C and 15.4 με, respectively. The proposed fiber might have potential applications for long-haul distributed dual-parameter simultaneous measurements.

The Delta Scuti star 38 Eri from the ground and from space

NASA Astrophysics Data System (ADS)

Paparó, M.; Kolláth, Z.; Shobbrook, R. R.; Matthews, J. M.; Antoci, V.; Benkő, J. M.; Park, N.-K.; Mirtorabi, M. T.; Luedeke, K.; Kusakin, A.; Bognár, Zs; Sódor, Á.; García-Hernández, A.; Pe na, J. H.; Kuschnig, R.; Moffat, A. F. J.; Rowe, J.; Rucinski, S. M.; Sasselov, D.; Weiss, W. W.

2018-04-01

We present and discuss the pulsational characteristics of the Delta Scuti star 38 Eri from photometric data obtained at two widely spaced epochs, partly from the ground (1998) and partly from space (MOST, 2011). We found 18 frequencies resolving the discrepancy among the previously published frequencies. Some of the frequencies appeared with different relative amplitudes at two epochs, however, we carried out investigation for amplitude variability for only the MOST data. Amplitude variability was found for one of three frequencies that satisfy the necessary frequency criteria for linear-combination or resonant-mode coupling. Checking the criteria of beating and resonant-mode coupling we excluded them as possible reason for amplitude variability. The two recently developed methods of rotational-splitting and sequence-search were applied to find regular spacings based only on frequencies. Doublets or incomplete multiplets with l = 1, 2 and 3 were found in the rotational splitting search. In the sequence search method we identified four sequences. The averaged spacing, probably a combination of the large separation and the rotational frequency, is 1.724 ± 0.092 d-1. Using the spacing and the scaling relation \\bar{ρ }= [0.0394, 0.0554] gcm-3 was derived. The shift of the sequences proved to be the integer multiple of the rotational splitting spacing. Using the precise MOST frequencies and multi-colour photometry in a hybrid way, we identified four modes with l = 1, two modes with l = 2, two modes with l = 3, and two modes as l = 0 radial modes.

Local vibrational modes of the formic acid dimer - the strength of the double hydrogen bond

NASA Astrophysics Data System (ADS)

Kalescky, R.; Kraka, E.; Cremer, D.

2013-07-01

The 24 normal and 24 local vibrational modes of the formic acid dimer formed by two trans formic acid monomers to a ring (TT1) are analysed utilising preferentially experimental frequencies, but also CCSD(T)/CBS and ωB97X-D harmonic vibrational frequencies. The local hydrogen bond (HB) stretching frequencies are at 676 cm-1 and by this 482 and 412 cm-1 higher compared to the measured symmetric and asymmetric HB stretching frequencies at 264 and 194 cm-1. The adiabatic connection scheme between local and normal vibrational modes reveals that the lowering is due to the topology of dimer TT1, mass coupling, and avoided crossings involving the HṡṡṡOC bending modes. The HB local mode stretching force constant is related to the strength of the HB whereas the normal mode stretching force constant and frequency lead to an erroneous underestimation of the HB strength. The HB in TT1 is stabilised by electron delocalisation in the O=C-O units fostered by forming a ring via double HBs. This implies that the CO apart from the OH local stretching frequencies reflect the strength of the HB via their red or blue shifts relative to their corresponding values in trans formic acid.

Air-coupled ultrasonic through-transmission thickness measurements of steel plates.

PubMed

Waag, Grunde; Hoff, Lars; Norli, Petter

2015-02-01

Non-destructive ultrasonic testing of steel structures provide valuable information in e.g. inspection of pipes, ships and offshore structures. In many practical applications, contact measurements are cumbersome or not possible, and air-coupled ultrasound can provide a solution. This paper presents air-coupled ultrasonic through-transmission measurements on a steel plate with thicknesses 10.15 mm; 10.0 mm; 9.8 mm. Ultrasound pulses were transmitted from a piezoelectric transducer at normal incidence, through the steel plate, and were received at the opposite side. The S1, A2 and A3 modes of the plate are excited, with resonance frequencies that depend on the material properties and the thickness of the plate. The results show that the resonances could be clearly identified after transmission through the steel plate, and that the frequencies of the resonances could be used to distinguish between the three plate thicknesses. The S1-mode resonance was observed to be shifted 10% down compared to a simple plane wave half-wave resonance model, while the A2 and S2 modes were found approximately at the corresponding plane-wave resonance frequencies. A model based on the angular spectrum method was used to predict the response of the through-transmission setup. This model included the finite aperture of the transmitter and receiver, and compressional and shear waves in the solid. The model predicts the frequencies of the observed modes of the plate to within 1%, including the down-shift of the S1-mode. Copyright © 2014 Elsevier B.V. All rights reserved.

Global-Mode Analysis of Full-Disk Data from the Michelson Doppler Imager and the Helioseismic and Magnetic Imager

NASA Astrophysics Data System (ADS)

Larson, Timothy P.; Schou, Jesper

2018-02-01

Building upon our previous work, in which we analyzed smoothed and subsampled velocity data from the Michelson Doppler Imager (MDI), we extend our analysis to unsmoothed, full-resolution MDI data. We also present results from the Helioseismic and Magnetic Imager (HMI), in both full resolution and processed to be a proxy for the low-resolution MDI data. We find that the systematic errors that we saw previously, namely peaks in both the high-latitude rotation rate and the normalized residuals of odd a-coefficients, are almost entirely absent in the two full-resolution analyses. Furthermore, we find that both systematic errors seem to depend almost entirely on how the input images are apodized, rather than on resolution or smoothing. Using the full-resolution HMI data, we confirm our previous findings regarding the effect of using asymmetric profiles on mode parameters, and also find that they occasionally result in more stable fits. We also confirm our previous findings regarding discrepancies between 360-day and 72-day analyses. We further investigate a six-month period previously seen in f-mode frequency shifts using the low-resolution datasets, this time accounting for solar-cycle dependence using magnetic-field data. Both HMI and MDI saw prominent six-month signals in the frequency shifts, but we were surprised to discover that the strongest signal at that frequency occurred in the mode coverage for the low-resolution proxy. Finally, a comparison of mode parameters from HMI and MDI shows that the frequencies and a-coefficients agree closely, encouraging the concatenation of the two datasets.

Effect of intermolecular hydrogen bonding, vibrational analysis and molecular structure of a biomolecule: 5-Hydroxymethyluracil

NASA Astrophysics Data System (ADS)

Çırak, Çağrı; Sert, Yusuf; Ucun, Fatih

2014-06-01

In the present work, the experimental and theoretical vibrational spectra of 5-hydroxymethyluracil were investigated. The FT-IR (4000-400 cm-1) spectrum of the molecule in the solid phase was recorded. The geometric parameters (bond lengths and bond angles), vibrational frequencies, Infrared intensities of the title molecule in the ground state were calculated using density functional B3LYP and M06-2X methods with the 6-311++G(d,p) basis set for the first time. The optimized geometric parameters and theoretical vibrational frequencies were found to be in good agreement with the corresponding experimental data, and with the results found in the literature. The vibrational frequencies were assigned based on the potential energy distribution using the VEDA 4 program. The dimeric form of 5-hydroxymethyluracil molecule was also simulated to evaluate the effect of intermolecular hydrogen bonding on its vibrational frequencies. It was observed that the Nsbnd H stretching modes shifted to lower frequencies, while its in-plane and out-of-plane bending modes shifted to higher frequencies due to the intermolecular Nsbnd H⋯O hydrogen bond. Also, the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies and diagrams were presented.

The role of coherent structures in the generation of noise for subsonic jets

NASA Technical Reports Server (NTRS)

Morrison, G. L.

1982-01-01

The coherent structure in high Reynolds number (184,000 to 262,000), Mach number 0.6 to 0.8 axisymmetric cold air jets exhausting at atmospheric pressure was studied. The mean flow and the statistical time averaged turbulence properties were measured. Spectra showed a very broad frequency content which shifted towards the lower frequencies as the flow progressed downstream. Axial wave number measurements indicate that the axial wave number-frequency relationship was the same for a wide range of Mach (0.3 to 2.5) and Reynolds (3,700 to over 200,000) numbers. Measurements of the azimuthal mode numbers show that several modes from n = -3 to +3 exist simultaneously in various quantities that the different frequencies studied. Acoustic measurements were made in the near field of the Mach number 0.6 jet. Sound pressure level contours showed that noise appeared to be radiated from a location near the end of the potential core. Directivity plots revealed that the spectra of this noise shifted towards higher frequencies as the angle from the jet axis increased. It was also found that mid-band excitation frequencies produced an increase in full spectrum noise.

FREQUENCY SHIFTS OF RESONANT MODES OF THE SUN DUE TO NEAR-SURFACE CONVECTIVE SCATTERING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhattacharya, J.; Hanasoge, S.; Antia, H. M.

Measurements of oscillation frequencies of the Sun and stars can provide important independent constraints on their internal structure and dynamics. Seismic models of these oscillations are used to connect structure and rotation of the star to its resonant frequencies, which are then compared with observations, the goal being that of minimizing the difference between the two. Even in the case of the Sun, for which structure models are highly tuned, observed frequencies show systematic deviations from modeled frequencies, a phenomenon referred to as the “surface term.” The dominant source of this systematic effect is thought to be vigorous near-surface convection,more » which is not well accounted for in both stellar modeling and mode-oscillation physics. Here we bring to bear the method of homogenization, applicable in the asymptotic limit of large wavelengths (in comparison to the correlation scale of convection), to characterize the effect of small-scale surface convection on resonant-mode frequencies in the Sun. We show that the full oscillation equations, in the presence of temporally stationary three-dimensional (3D) flows, can be reduced to an effective “quiet-Sun” wave equation with altered sound speed, Brünt–Väisäla frequency, and Lamb frequency. We derive the modified equation and relations for the appropriate averaging of 3D flows and thermal quantities to obtain the properties of this effective medium. Using flows obtained from 3D numerical simulations of near-surface convection, we quantify their effect on solar oscillation frequencies and find that they are shifted systematically and substantially. We argue therefore that consistent interpretations of resonant frequencies must include modifications to the wave equation that effectively capture the impact of vigorous hydrodynamic convection.« less

Frequencies of solar p-mode oscillations

NASA Technical Reports Server (NTRS)

Duvall, T. L., Jr.; Harvey, J. W.; Libbrecht, K. G.; Popp, B. D.; Pomerantz, M. A.

1988-01-01

A list is presented of frequencies that can be used as a basis for helioseismic investigations of the average structure of the solar interior as a function of depth. The list includes measurements of frequencies of p-mode multiplets covering the l range from 4 to 99. Two different data sets are employed: one based on Doppler shift measurements made in 1985 at the Big Bear Solar Observatory and another based on intensity measurements made in 1981 at the geographic South Pole. Frequencies from the two data sets are compared, and systematic frequency differences are found that range from less than 0.1 microHz at low values of l to about 0.6 microHz at l = 99; the uncertainty is + or - 0.1 microHz.

Explaining Polarization Reversals in STEREO Wave Data

NASA Technical Reports Server (NTRS)

Breneman, A.; Cattell, C.; Wygant, J.; Kersten, K.; Wilson, L, B., III; Dai, L.; Colpitts, C.; Kellogg, P. J.; Goetz, K.; Paradise, A.

2012-01-01

Recently Breneman et al. reported observations of large amplitude lightning and transmitter whistler mode waves from two STEREO passes through the inner radiation belt (L<2). Hodograms of the electric field in the plane transverse to the magnetic field showed that the transmitter waves underwent periodic polarization reversals. Specifically, their polarization would cycle through a pattern of right-hand to linear to left-hand polarization at a rate of roughly 200 Hz. The lightning whistlers were observed to be left-hand polarized at frequencies greater than the lower hybrid frequency and less than the transmitter frequency (21.4 kHz) and right-hand polarized otherwise. Only righthand polarized waves in the inner radiation belt should exist in the frequency range of the whistler mode and these reversals were not explained in the previous paper. We show, with a combination of observations and simulated wave superposition, that these polarization reversals are due to the beating of an incident electromagnetic whistler mode wave at 21.4 kHz and linearly polarized, symmetric lower hybrid sidebands Doppler-shifted from the incident wave by +/-200 Hz. The existence of the lower hybrid waves is consistent with the parametric decay mechanism of Lee and Kuo whereby an incident whistler mode wave decays into symmetric, short wavelength lower hybrid waves and a purely growing (zero-frequency) mode. Like the lower hybrid waves, the purely growing mode is Doppler-shifted by 200 Hz as observed on STEREO. This decay mechanism in the upper ionosphere has been previously reported at equatorial latitudes and is thought to have a direct connection with explosive spread F enhancements. As such it may represent another dissipation mechanism of VLF wave energy in the ionosphere and may help to explain a deficit of observed lightning and transmitter energy in the inner radiation belts as reported by Starks et al.

Frequency stabilization in injection controlled pulsed CO2 lasers

NASA Technical Reports Server (NTRS)

Menzies, Robert T.; Ancellet, Gerard M.

1987-01-01

Longitudinal mode selection by injection has been demonstrated as a viable technique for tailoring a TEA-CO2 laser with pulse energies of a Joule or greater to fit the requirements of a coherent lidar transmitter. Once reliable generation of single-longitudinal-mode (SLM) pulses is obtained, one can study the intrapulse frequency variation and attempt to determine the sources of frequency sweeping, or chirp. These sources include the effect of the decaying plasma, the thermal gradient due to the energy dissipation associated with the laser mechanism itself, and the pressure shift of the center frequency of the laser transition. The use of the positive-branch unstable resonator as an efficient means of coupling a discharge with transverse spatial dimensions of the order of centimeters to an optical cavity mode introduces another concern: namely, what can be done to emphasize transverse mode discrimination in an unstable resonator cavity while maintaining high coupling efficiency. These issues are briefly discussed in the paper, and representative experimental examples are included.

Laser Gyro Theory Extension.

DTIC Science & Technology

1980-12-01

A 60 Kiz. A scanning Fabry - Perot etalon was used to measure the frequency spectrum. I -.8 -.4 0 .4 .8 n(O/sec) a 4-mode (expt) / 2-mode(expt) / -- 4...light from one mode into the counter- rotating one is Doppler shifted. In summary, a two-mode ring laser gyro has two counter- Fig. 4. The demodulated ...input rate so that the locking Fig. 4 shows the demodulated beat note versus rotation rate region is avoided. The rotation rate measurement then depends

Parasitic modes removal out of operating mode neighbourhood in the DAW accelerating structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andreev, V.G.; Belugin, V.M.; Esin, S.K.

1983-08-01

The disk and washer (DAW) accelerating structure finds its use in a number of new projects (PIGMI, SNQ etc ). It composes the main part of the accelerating structure of the meson factory now under construction in the Institute for Nuclear Research (INR), Moscow. It is known that the parasitic modes with azimuthal field variations exist at the operating mode region. In this report different methods of the parasitic modes frequency shift are considered. The main attention is given to the resonant methods, which are the most efficient.

Study on the characteristic and application of DFB semiconductor lasers under optical injection for microwave photonics

NASA Astrophysics Data System (ADS)

Pu, Tao; Wang, Wei wei

2018-01-01

In order to apply optical injection effect in Microwave Photonics system, The red-shift effect of the cavity mode of the DFB semiconductor laser under single-frequency optical injection is studied experimentally, and the red-shift curve of the cavity mode is measured. The wavelength-selective amplification property of the DFB semiconductor laser under multi-frequency optical injection is also investigated, and the gain curves for the injected signals in different injection ratios are measured in the experiment. A novel and simple structure to implement a single-passband MPF with wideband tunability based on the wavelength-selective amplification of a DFB semiconductor laser under optical injection is proposed and experimentally demonstrated. MPFs with center frequency tuned from 13 to 41 GHz are realized in the experiment. A wideband and frequency-tunable optoelectronic oscillator based on a directly modulated distributed feedback (DFB) semiconductor laser under optical injection is proposed and experimentally demonstrated. By optical injection, the relaxation oscillation frequency of the DFB laser is enhanced and its high modulation efficiency makes the loop oscillate without the necessary of the electrical filter. An experiment is performed; microwave signals with frequency tuned from 5.98 to 15.22 GHz are generated by adjusting the injection ratio and frequency detuning between the master and slave lasers.

Tunable single frequency fiber laser based on FP-LD injection locking.

PubMed

Zhang, Aiqin; Feng, Xinhuan; Wan, Minggui; Li, Zhaohui; Guan, Bai-ou

2013-05-20

We propose and demonstrate a tunable single frequency fiber laser based on Fabry Pérot laser diode (FP-LD) injection locking. The single frequency operation principle is based on the fact that the output from a FP-LD injection locked by a multi-longitudinal-mode (MLM) light can have fewer longitudinal-modes number and narrower linewidth. By inserting a FP-LD in a fiber ring laser cavity, single frequency operation can be possibly achieved when stable laser oscillation established after many roundtrips through the FP-LD. Wavelength switchable single frequency lasing can be achieved by adjusting the tunable optical filter (TOF) in the cavity to coincide with different mode of the FP-LD. By adjustment of the drive current of the FP-LD, the lasing modes would shift and wavelength tunable operation can be obtained. In experiment, a wavelength tunable range of 32.4 nm has been obtained by adjustment of the drive current of the FP-LD and a tunable filter in the ring cavity. Each wavelength has a side-mode suppression ratio (SMSR) of at least 41 dB and a linewidth of about 13 kHz.

Infrared Reflectance Spectroscopy of Porous Silicas

NASA Astrophysics Data System (ADS)

Guiton, Theresa Anne

Fourier transform infrared (FTIR) specular reflectance spectroscopy was used to examine the fundamental phonon behavior of a series of porous silicas including porous Vycor, xerogels, aerogels, and colloidal solids. The spectra were deconvoluted using Kramers-Kronig analysis techniques, and the corresponding optical constants were determined via the Fresnel equations. The resulting spectra represent the first compilation of such data for low density silicas. The porous silicas revealed unique resonance modes for the imaginary dielectric function and energy loss function. A key distinction amongst the spectra was the change in the band shape of the antisymmetric Si-O-Si stretching modes. For instance, as the porosity level of the particulate systems increased, the peak maxima of the imaginary dielectric functions shifted to higher frequencies while the peak maxima of the associated energy loss function shifted to lower frequencies. In essence, with increasing porosity, the peak maxima of the imaginary dielectric functions and the energy loss functions were converging towards frequencies intermediate to the transverse optical and longitudinal optical modes of fused silica. A similar trend was not observed for the semi-continuous silica matrices. Maxwell Garnett effective medium modeling verified that these modes were a function of the porous microstructure and can be attributed to surface phonon modes. The effect of surface phonon modes was also evident in the absorption coefficient data. However, contrary to the traditional view that changes in the absorption spectra of porous silicas are strictly due to molecular structure, this study has demonstrated that variations can be attributed--both qualitatively and quantitatively--to electrostatic screening effects of finite particles.

Suppression and spectral splitting of the amplitude noise due to mode beatings in a single-frequency injection laser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bogatov, A.P.; Eliseev, P.G.; Kobildzhanov, O.A.

1987-06-01

Investigations of intensity fluctuations in a single-frequency injection laser showed that they are due to beatings between coherent field and superluminescent spontaneous emission. It has been experimentally found that in the region of developed laser emission, the level of fluctuations is decreased with an increase of the output power, and so the relative spectral shift of external cavity superluminescent mode frequencies is dependent on the laser output power. The explanation of this phenomenon was made on the basis of the mechanism of a nonlinear interaction of a field in the active region of a laser diode.

Vibrational dynamics of hydrogen-bonded complexes in solutions studied with ultrafast infrared pump-probe spectroscopy.

PubMed

Banno, Motohiro; Ohta, Kaoru; Yamaguchi, Sayuri; Hirai, Satori; Tominaga, Keisuke

2009-09-15

In aqueous solution, the basis of all living processes, hydrogen bonding exerts a powerful effect on chemical reactivity. The vibrational energy relaxation (VER) process in hydrogen-bonded complexes in solution is sensitive to the microscopic environment around the oscillator and to the geometrical configuration of the hydrogen-bonded complexes. In this Account, we describe the use of time-resolved infrared (IR) pump-probe spectroscopy to study the vibrational dynamics of (i) the carbonyl CO stretching modes in protic solvents and (ii) the OH stretching modes of phenol and carboxylic acid. In these cases, the carbonyl group acts as a hydrogen-bond acceptor, whereas the hydroxyl group acts as a hydrogen-bond donor. These vibrational modes have different properties depending on their respective chemical bonds, suggesting that hydrogen bonding may have different mechanisms and effects on the VER of the CO and OH modes than previously understood. The IR pump-probe signals of the CO stretching mode of 9-fluorenone and methyl acetate in alcohol, as well as that of acetic acid in water, include several components with different time constants. Quantum chemical calculations indicate that the dynamical components are the result of various hydrogen-bonded complexes that form between solute and solvent molecules. The acceleration of the VER is due to the increasing vibrational density of states caused by the formation of hydrogen bonds. The vibrational dynamics of the OH stretching mode in hydrogen-bonded complexes were studied in several systems. For phenol-base complexes, the decay time constant of the pump-probe signal decreases as the band peak of the IR absorption spectrum shifts to lower wavenumbers (the result of changing the proton acceptor). For phenol oligomers, the decay time constant of the pump-probe signal decreases as the probe wavenumber decreases. These observations show that the VER time strongly correlates with the strength of hydrogen bonding. This acceleration may be due to increased coupling between the OH stretching mode and the accepting mode of the VER, because the low-frequency shift caused by hydrogen bond formation is very large. Unlike phenol oligomers, however, the pump-probe signals of phenol-base complexes did not exhibit probe frequency dependence. For these complexes, rapid interconversion between different conformations causes rapid fluctuations in the vibrational frequency of the OH stretching modes, and these fluctuations level the VER times of different conformations. For the benzoic acid dimer, a quantum beat at a frequency of around 100 cm(-1) is superimposed on the pump-probe signal. This result indicates the presence of strong anharmonic coupling between the intramolecular OH stretching and the intermolecular stretching modes. From a two-dimensional plot of the OH stretching wavenumber and the low-frequency wavenumber, the wavenumber of the low-frequency mode is found to increase monotonically as the probe wavenumber is shifted toward lower wavenumbers. Our results represent a quantitative determination of the acceleration of VER by the formation of hydrogen bonds. Our studies merit further evaluation and raise fundamental questions about the current theory of vibrational dynamics in the condensed phase.

Polarization beam splitter based on a photonic crystal heterostructure.

PubMed

Schonbrun, E; Wu, Q; Park, W; Yamashita, T; Summers, C J

2006-11-01

The design and characterization of a photonic crystal (PC) polarization beam splitter (PBS) that operates with an extinction ratio of greater than 15 dB for both polarizations are presented. The PBS is fabricated on a silicon-on-insulator (SOI) wafer where the input and output ports consist of 5 mum wide ridge waveguides. A large spectral shift is observed in the dispersion plots of the lowest-order even (TE-like) and odd (TM-like) modes due to the SOI confinement. Because of this shift, the TE-like mode is close to a directional gap at the top of the band, and the TM-like mode is in a low-frequency regime where the dispersion surface is almost isotropic. We show that the TE-like mode has very high reflection at the interface between the two PCs, whereas the TM-like mode exhibits a very high transmission.

Acousto-optical interaction of surface acoustic and optical waves in a two-dimensional phoxonic crystal hetero-structure cavity.

PubMed

Ma, Tian-Xue; Zou, Kui; Wang, Yue-Sheng; Zhang, Chuanzeng; Su, Xiao-Xing

2014-11-17

Phoxonic crystal is a promising material for manipulating sound and light simultaneously. In this paper, we theoretically demonstrate the propagation of acoustic and optical waves along the truncated surface of a two-dimensional square-latticed phoxonic crystal. Further, a phoxonic crystal hetero-structure cavity is proposed, which can simultaneously confine surface acoustic and optical waves. The interface motion and photoelastic effects are taken into account in the acousto-optical coupling. The results show obvious shifts in eigenfrequencies of the photonic cavity modes induced by different phononic cavity modes. The symmetry of the phononic cavity modes plays a more important role in the single-phonon exchange process than in the case of the multi-phonon exchange. Under the same deformation, the frequency shift of the photonic transverse electric mode is larger than that of the transverse magnetic mode.

Circuit filling factor (CFF) for multiply tuned probes, revisited

NASA Astrophysics Data System (ADS)

Conradi, Mark S.; Zens, Albert P.

2018-07-01

The concept of circuit filling factor (CFF) is re-examined for multi-tuned, multi-inductor probe circuits. The CFF is the fraction of magnetic stored energy residing in the NMR coil. The CFF theorem states that the CFF sums to unity across all the resonant normal modes. It dictates that improved performance from a large CFF in one mode comes at the expense of CFF (and performance) at the other mode(s). Simple analytical calculations of two-mode circuits are used to demonstrate and confirm the CFF theorem. A triple-resonance circuit is calculated to show the large trade-offs involved there. The theorem can provide guidance for choosing the best circuit and relative inductances in multi-nuclear probes. The CFF is directly accessible from ball frequency-shift measurements. We give experimental measures of the CFF from ball shifts and compare to calculated values of the CFF, with good agreement.

Narrow-band injection seeding of a terahertz frequency quantum cascade laser: Selection and suppression of longitudinal modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nong, Hanond, E-mail: Nong.Hanond@rub.de; Markmann, Sergej; Hekmat, Negar

2014-09-15

A periodically poled lithium niobate (PPLN) crystal with multiple poling periods is used to generate tunable narrow-bandwidth THz pulses for injection seeding a quantum cascade laser (QCL). We demonstrate that longitudinal modes of the quantum cascade laser close to the gain maximum can be selected or suppressed according to the seed spectrum. The QCL emission spectra obtained by electro-optic sampling from the quantum cascade laser, in the most favorable case, shows high selectivity and amplification of the longitudinal modes that overlap the frequency of the narrow-band seed. Proper selection of the narrow-band THz seed from the PPLN crystal discretely tunesmore » the longitudinal mode emission of the quantum cascade laser. Moreover, the THz wave build-up within the laser cavity is studied as a function of the round-trip time. When the seed frequency is outside the maximum of the gain spectrum the laser emission shifts to the preferential longitudinal mode.« less

Can two H2 molecules be inserted into C60 - an accurate first-principles exploration of structural, energetic and vibrational properties of the 2H2@C60 complex

NASA Astrophysics Data System (ADS)

Dolgonos, Grygoriy A.; Peslherbe, Gilles H.

2016-10-01

The 2H2@C60 minimum structure of C2 symmetry has been fully characterized at the density-fitting local second-order Møller-Plesset (DF-LMP2) level of theory. Its uncorrected and zero-point energy (ZPE) corrected complexation energies equal 1.9 and 6.2 kcal/mol, respectively, confirming the instability of the complex. This structure exhibits the largest intermolecular host-guest and guest-guest separations among all the complexes studied in this work. The calculated infrared spectrum of 2H2@C60 does not show any frequency shifts for the modes associated with radial or tangential displacements in C60 (except for one mode), but shows a weak red Hsbnd H vibrational frequency shift.

The Delta Scuti star 38 Eri from the ground and from space

NASA Astrophysics Data System (ADS)

Paparó, M.; Kolláth, Z.; Shobbrook, R. R.; Matthews, J. M.; Antoci, V.; Benkő, J. M.; Park, N.-K.; Mirtorabi, M. T.; Luedeke, K.; Kusakin, A.; Bognár, Zs; Sódor, Á.; García-Hernández, A.; Peña, J. H.; Kuschnig, R.; Moffat, A. F. J.; Rowe, J.; Rucinski, S. M.; Sasselov, D.; Weiss, W. W.

2018-07-01

We present and discuss the pulsational characteristics of the Delta Scuti star 38 Eri from photometric data obtained at two widely spaced epochs, partly from the ground (1998) and partly from space (MOST, 2011). We found 18 frequencies resolving the discrepancy among the previously published frequencies. Some of the frequencies appeared with different relative amplitudes at two epochs, however, we carried out investigation for amplitude variability for only the MOST (Microvariability and Oscillation of STars) data. Amplitude variability was found for one of the three frequencies that satisfy the necessary frequency criteria for linear-combination or resonant-mode coupling. Checking the criteria of beating and resonant-mode coupling we excluded them as possible reason for amplitude variability. The two recently developed methods of rotational splitting and sequence search were applied to find regular spacings based only on frequencies. Doublets or incomplete multiplets with l = 1, 2, and 3 were found in the rotational splitting search. In the sequence search method we identified four sequences. The averaged spacing, probably a combination of the large separation and the rotational frequency, is 1.724 ± 0.092 d-1. Using the spacing and the scaling relation \\bar{ρ}= [0.0394, 0.0554] g cm-3 was derived. The shift of the sequences proved to be the integer multiple of the rotational splitting spacing. Using the precise MOST frequencies and multicolour photometry in a hybrid way, we identified four modes with l = 1, two modes with l = 2, two modes with l = 3, and two modes as l = 0 radial modes.

Cyclotron line resonant transfer through neutron star atmospheres

NASA Technical Reports Server (NTRS)

Wang, John C. L.; Wasserman, Ira M.; Salpeter, Edwin E.

1988-01-01

Monte Carlo methods are used to study in detail the resonant radiative transfer of cyclotron line photons with recoil through a purely scattering neutron star atmosphere for both the polarized and unpolarized cases. For each case, the number of scatters, the path length traveled, the escape frequency shift, the escape direction cosine, the emergent frequency spectra, and the angular distribution of escaping photons are investigated. In the polarized case, transfer is calculated using both the cold plasma e- and o-modes and the magnetic vacuum perpendicular and parallel modes.

Characteristics of enhanced-mode AlGaN/GaN MIS HEMTs for millimeter wave applications

NASA Astrophysics Data System (ADS)

Lee, Jong-Min; Ahn, Ho-Kyun; Jung, Hyun-Wook; Shin, Min Jeong; Lim, Jong-Won

2017-09-01

In this paper, an enhanced-mode (E-mode) AlGaN/GaN high electron mobility transistor (HEMT) was developed by using 4-inch GaN HEMT process. We designed and fabricated Emode HEMTs and characterized device performance. To estimate the possibility of application for millimeter wave applications, we focused on the high frequency performance and power characteristics. To shift the threshold voltage of HEMTs we applied the Al2O3 insulator to the gate structure and adopted the gate recess technique. To increase the frequency performance the e-beam lithography technique was used to define the 0.15 um gate length. To evaluate the dc and high frequency performance, electrical characterization was performed. The threshold voltage was measured to be positive value by linear extrapolation from the transfer curve. The device leakage current is comparable to that of the depletion mode device. The current gain cut-off frequency and the maximum oscillation frequency of the E-mode device with a total gate width of 150 um were 55 GHz and 168 GHz, respectively. To confirm the power performance for mm-wave applications the load-pull test was performed. The measured power density of 2.32 W/mm was achieved at frequencies of 28 and 30 GHz.

Longitudinal optical phonon-plasmon coupled modes of degenerate Al-doped ZnO films

NASA Astrophysics Data System (ADS)

Ding, K.; Hu, Q. C.; Lin, W. W.; Huang, J. K.; Huang, F.

2012-07-01

We have investigated the interaction between carriers and polar phonons by using Raman scattering spectroscopy in highly conductive Al-doped ZnO films grown by metalorganic chemical vapor deposition. Different from the longitudinal optical phonon-plasmon coupled modes (LOPPCM) observed in nondegenerate ZnO, an A1(LO)-like mode appears at the low frequency side of the uncoupled A1(LO) mode, and it monotonically shifts to higher frequencies and approaches to the uncoupled A1(LO) mode as Al composition increases. Based on line shape calculations, the A1(LO)-like mode is assigned to the large wave-vector LOPPCM arising from nonconserving scattering dominated by the Al impurity-induced Fröhlich mechanism. Benefiting from the nonmonotonic Al composition dependence of the electron density, it is revealed that the LOPPCM depends mainly on the doping level but not the carrier concentration.

LIF excitation spectra for S 0 → S 1 transition of deuterated anthranilic acid COOD, ND 2 in supersonic-jet expansion

NASA Astrophysics Data System (ADS)

Kolek, Przemysław; Leśniewski, Sebastian; Andrzejak, Marcin; Góra, Maciej; Cias, Pawel; Weģrzynowicz, Adam; Najbar, Jan

2010-12-01

Laser induced fluorescence (LIF) excitation spectrum for the S 0 → S 1 transition of anthranilic acid molecules deuterated in the substituent groups (COOD, ND 2) was investigated. Analysis of the LIF spectrum allowed for the assignment of the six most prominent fundamental in-plane modes of frequencies up to ca. 850 cm. The experimental results show good correlation with the frequency changes upon deuteration computed with CIS (CI-Singles) and TD-DFT for the S 1 state. Deuteration induced red-shifts of the identified fundamental bands are used for examination of the alternative assignments proposed in earlier studies. Potential energy distributions (PED) and overlaps of the in-plane normal modes with frequencies below 850 cm indicate that the correspondence of the respective vibrations of the deuterated and non-deuterated molecule is very good. A blue-shift of the 00 transition due to the isotopic substitution, is equal to 47 cm. This relatively large value is caused primarily by a significant decrease of the N-H stretching frequency associated with the increase of strength of the intramolecular hydrogen bond upon the electronic excitation. The deuteration shift of the 00 band was interpreted in terms of the differences of the zero point energy (ZPE) between the S 0 and S 1 electronic states, computed with DFT and TD-DFT methods, respectively.

Terahertz transmission properties of a triadic-Cantor-set photonic crystal containing a semiconductor

NASA Astrophysics Data System (ADS)

King, Tzu-Chyang; Liu, Chi-Chung; Huang, Chih-Hsi; Wu, Chien-Jang

2016-08-01

Terahertz transmission properties of a stage 3 triadic-Cantor-set photonic crystal (S3 TCS PC) containing a semiconductor of n-InSb are theoretically investigated. With the resonant frequency in the permittivity function of n-InSb, transmission responses can be classified as three regions. In the two regions with frequencies well above and below the resonant frequency, the permittivity functions are nearly a positive constant and n-InSb is dielectric-like. For these two regions, transmittance response of S3 TCS PC at a given number of periods Np reveals that, within a photonic band gap, there are two groups of defect modes with numbers of Np and Np-1, respectively. Defect modes are shown to be blue-shifted as the angle of incidence increases for both TE and TM waves. Additionally, adjusting the layer thickness enables us to control mode positions for the group of (Np-1)-mode, but the one with Np-mode is not able to be controlled. In a region of 5.1-6.2 THz, where the loss is large, there also are many transmission modes.

Effect of intermolecular hydrogen bonding, vibrational analysis and molecular structure of a biomolecule: 5-Hydroxymethyluracil.

PubMed

Çırak, Çağrı; Sert, Yusuf; Ucun, Fatih

2014-06-05

In the present work, the experimental and theoretical vibrational spectra of 5-hydroxymethyluracil were investigated. The FT-IR (4000-400cm(-1)) spectrum of the molecule in the solid phase was recorded. The geometric parameters (bond lengths and bond angles), vibrational frequencies, Infrared intensities of the title molecule in the ground state were calculated using density functional B3LYP and M06-2X methods with the 6-311++G(d,p) basis set for the first time. The optimized geometric parameters and theoretical vibrational frequencies were found to be in good agreement with the corresponding experimental data, and with the results found in the literature. The vibrational frequencies were assigned based on the potential energy distribution using the VEDA 4 program. The dimeric form of 5-hydroxymethyluracil molecule was also simulated to evaluate the effect of intermolecular hydrogen bonding on its vibrational frequencies. It was observed that the NH stretching modes shifted to lower frequencies, while its in-plane and out-of-plane bending modes shifted to higher frequencies due to the intermolecular NH⋯O hydrogen bond. Also, the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies and diagrams were presented. Copyright © 2014 Elsevier B.V. All rights reserved.

Effect of intermolecular hydrogen bonding, vibrational analysis and molecular structure of 4-chlorobenzothioamide

NASA Astrophysics Data System (ADS)

Çırak, Çağrı; Sert, Yusuf; Ucun, Fatih

2013-09-01

In the present work, the experimental and theoretical vibrational spectra of 4-chlorobenzothioamide were investigated. The FT-IR (400-4000 cm-1) and μ-Raman spectra (100-4000 cm-1) of 4-chlorobenzothioamide in the solid phase were recorded. The geometric parameters (bond lengths and bond angles), vibrational frequencies, Infrared and Raman intensities of the title molecule in the ground state were calculated using ab initio Hartree-Fock and density functional theory (B3LYP) methods with the 6-311++G(d,p) basis set for the first time. The optimized geometric parameters and the theoretical vibrational frequencies were found to be in good agreement with the corresponding experimental data and with the results found in the literature. The vibrational frequencies were assigned based on the potential energy distribution using the VEDA 4 program. The dimeric form of 4-chlorobenzothioamide was also simulated to evaluate the effect of intermolecular hydrogen bonding on the vibrational frequencies. It was observed that the Nsbnd H stretching modes shifted to lower frequencies, while the in-plane and out-of-plane bending modes shifted to higher frequencies due to the intermolecular Nsbnd H⋯S hydrogen bond. Also, the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies and diagrams were presented.

Spatially resolved measurements of two-dimensional turbulent structures in DIII-D plasmas

DOE PAGES

Zemedkun, Samuel E.; Che, S.; Chen, Y.; ...

2015-12-21

Here, two-dimensional observations of spatially-coherent electron temperature fluctuations at drift wave scales (k ~1 cm -1) have been made using the electron cyclotron emission imaging (ECEI) diagnostic on the DIII-D tokamak. These measurements enable the extraction of spectral properties, including poloidal dispersion relations. Temperature fluctuation levels are found to be ˜ T e/< T e > = 1.2%, and the phase velocity of the fluctuations is found to be constant across frequencies, consistent with modes having real frequencies low compared to the rotation-induced Doppler shifts. Comparisons with radially global linear gyrokinetic simulations suggest that the observed modes may be trappedmore » electron modes (TEM).« less

Stacking sequence determines Raman intensities of observed interlayer shear modes in 2D layered materials – A general bond polarizability model

PubMed Central

Luo, Xin; Lu, Xin; Cong, Chunxiao; Yu, Ting; Xiong, Qihua; Ying Quek, Su

2015-01-01

2D layered materials have recently attracted tremendous interest due to their fascinating properties and potential applications. The interlayer interactions are much weaker than the intralayer bonds, allowing the as-synthesized materials to exhibit different stacking sequences, leading to different physical properties. Here, we show that regardless of the space group of the 2D materials, the Raman frequencies of the interlayer shear modes observed under the typical configuration blue shift for AB stacked materials, and red shift for ABC stacked materials, as the number of layers increases. Our predictions are made using an intuitive bond polarizability model which shows that stacking sequence plays a key role in determining which interlayer shear modes lead to the largest change in polarizability (Raman intensity); the modes with the largest Raman intensity determining the frequency trends. We present direct evidence for these conclusions by studying the Raman modes in few layer graphene, MoS2, MoSe2, WSe2 and Bi2Se3, using both first principles calculations and Raman spectroscopy. This study sheds light on the influence of stacking sequence on the Raman intensities of intrinsic interlayer modes in 2D layered materials in general, and leads to a practical way of identifying the stacking sequence in these materials. PMID:26469313

Stacking sequence determines Raman intensities of observed interlayer shear modes in 2D layered materials--A general bond polarizability model.

PubMed

Luo, Xin; Lu, Xin; Cong, Chunxiao; Yu, Ting; Xiong, Qihua; Quek, Su Ying

2015-10-15

2D layered materials have recently attracted tremendous interest due to their fascinating properties and potential applications. The interlayer interactions are much weaker than the intralayer bonds, allowing the as-synthesized materials to exhibit different stacking sequences, leading to different physical properties. Here, we show that regardless of the space group of the 2D materials, the Raman frequencies of the interlayer shear modes observed under the typical z(xx)z configuration blue shift for AB stacked materials, and red shift for ABC stacked materials, as the number of layers increases. Our predictions are made using an intuitive bond polarizability model which shows that stacking sequence plays a key role in determining which interlayer shear modes lead to the largest change in polarizability (Raman intensity); the modes with the largest Raman intensity determining the frequency trends. We present direct evidence for these conclusions by studying the Raman modes in few layer graphene, MoS2, MoSe2, WSe2 and Bi2Se3, using both first principles calculations and Raman spectroscopy. This study sheds light on the influence of stacking sequence on the Raman intensities of intrinsic interlayer modes in 2D layered materials in general, and leads to a practical way of identifying the stacking sequence in these materials.

Comparison between whole-body and head and neck neurovascular coils for 3-T magnetic resonance proton resonance frequency shift thermography guidance in the head and neck region.

PubMed

Ginat, Daniel Thomas; Anthony, Gregory J; Christoforidis, Gregory; Oto, Aytekin; Dalag, Leonard; Sammet, Steffen

2018-02-01

The purpose of this study is to compare the image quality of magnetic resonance (MR) treatment planning images and proton resonance frequency (PRF) shift thermography images and inform coil selection for MR-guided laser ablation of tumors in the head and neck region. Laser ablation was performed on an agar phantom and monitored via MR PRF shift thermography on a 3-T scanner, following acquisition of T1-weighted (T1W) planning images. PRF shift thermography images and T2-weighted (T2W) planning images were also performed in the neck region of five normal human volunteers. Signal-to-noise ratios (SNR) and temperature uncertainty were calculated and compared between scans acquired with the quadrature mode body integrated coil and a head and neck neurovascular coil. T1W planning images of the agar phantom produced SNRs of 4.0 and 12.2 for the quadrature mode body integrated coil and head and neck neurovascular coil, respectively. The SNR of the phantom MR thermography magnitude images obtained using the quadrature mode body integrated coil was 14.4 versus 59.6 using the head and neck coil. The average temperature uncertainty for MR thermography performed on the phantom with the quadrature mode body integrated coil was 1.1 versus 0.3 °C with the head and neck coil. T2W planning images of the neck in five human volunteers produced SNRs of 28.3 and 91.0 for the quadrature mode body integrated coil and head and neck coil, respectively. MR thermography magnitude images of the neck in the volunteers obtained using the quadrature mode body integrated coil had a signal-to-noise ratio of 8.3, while the SNR using the head and neck coil was 16.1. The average temperature uncertainty for MR thermography performed on the volunteers with the body coil was 2.5 versus 1.6 °C with the head and neck neurovascular coil. The quadrature mode body integrated coil provides inferior image quality for both basic treatment planning sequences and MR PRF shift thermography compared with a neurovascular coil, but may nevertheless be adequate for clinical purposes.

Low-Frequency Interlayer Raman Modes to Probe Interface of Twisted Bilayer MoS 2

DOE PAGES

Huang, Shengxi; Liang, Liangbo; Ling, Xi; ...

2016-02-21

A variety of van der Waals homo- and hetero- structures assembled by stamping monolayers together present optoelectronic properties suitable for diverse applications. Understanding the details of the interlayer stacking and resulting coupling is crucial for tuning these properties. Twisted bilayer transition metal dichalcogenides offer a great platform for developing a precise understanding of the structure/property relationship. Here, we study the low-frequency interlayer shear and breathing Raman modes (<50 cm-1) in twisted bilayer MoS 2 by Raman spectroscopy and first-principles modeling. Twisting introduces both rotational and translational shifts and significantly alters the interlayer stacking and coupling, leading to notable frequency andmore » intensity changes of low-frequency modes. The frequency variation can be up to 8 cm-1 and the intensity can vary by a factor of ~5 for twisting near 0 and 60 , where the stacking is a mixture of multiple high-symmetry stacking patterns and is thus especially sensitive to twisting. Moreover, for twisting angles between 20 and 40 , the interlayer coupling is nearly constant since the stacking results in mismatched lattices over the entire sample. It follows that the Raman signature is relatively uniform. Interestingly, unlike the breathing mode, the shear mode is extremely sensitive to twisting: it disappears between 20 and 40 as its frequency drops to almost zero due to the stacking-induced mismatch. Note that for some samples, multiple breathing mode peaks appear, indicating non-uniform coupling across the interface. In contrast to the low-frequency interlayer modes, high-frequency intralayer Raman modes are much less sensitive to interlayer stacking and coupling, showing negligible changes upon twisting. Our research demonstrates the effectiveness of low-frequency Raman modes for probing the interfacial coupling and environment of twisted bilayer MoS2, and potentially other two-dimensional materials and heterostructures.« less

Sound diffraction at wall impedance discontinuities in a circular cylinder, investigated using Wiener-Hopf technique

NASA Technical Reports Server (NTRS)

Cho, Y. C.

1983-01-01

Rigorous solutions are presented for sound diffraction in a circular cylinder with axial discontinuities of the wall admittance (or impedance). Analytical expressions are derived for the reflection and the transmission coefficients for duct modes. The results are discussed quantitatively in the limits of small admittance shifts (delta) and of low frequencies (ka). One of the results is the low frequency behavior of the reflection coefficient R(o) sub 00 of the fundamental mode. For the mode of a hardwall duct reflected from the junction with a softwall duct, (R(o) sub oo yields - (1-square root of (ka) square root of (2/i delta)); this result is in contrast to the frequency dependence of the reflection from the open end of a hardwall duct, for which R(o) sub oo yields - 1-(ka) squared/2 .

Overlapping double potential wells in a single optical microtube cavity with vernier-scale-like tuning effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Madani, A.; Schmidt, O. G.; Material Systems for Nanoelectronics, Chemnitz University of Technology, Reichenhainer Str. 70, 09107 Chemnitz

2016-04-25

Spatially and temporally overlapping double potential wells are realized in a hybrid optical microtube cavity due to the coexistence of an aggregate of luminescent quantum dots embedded in the tube wall and the cone-shaped tube's geometry. The double potential wells produce two independent sets of optical modes with different sets of mode numbers, indicating phase velocity separation for the modes overlapping at the same frequency. The overlapping mode position can be tuned by modifying the tube cavity, where these mode sets shift with different magnitudes, allowing for a vernier-scale-like tuning effect.

Study of digital charge coupled devices

NASA Technical Reports Server (NTRS)

Wilson, D. D.; Young, V. F.

1980-01-01

Charge coupled devices represent unique usage of the metal oxide semiconductor concept. These devices can sample an AC signal at the input, transfer charge proportional to this signal through the CCD shift register and then provide an output of the same frequency and shape as the input. The delay time between input and output is controlled by the CCD operating frequency and the number of stages in the shift resistor. This work is a reliability evaluation of the buried channel and surface channel CCD technologies. The constructions are analyzed, failure modes are described, and test results are reported.

Robust calibration of an optical-lattice depth based on a phase shift

NASA Astrophysics Data System (ADS)

Cabrera-Gutiérrez, C.; Michon, E.; Brunaud, V.; Kawalec, T.; Fortun, A.; Arnal, M.; Billy, J.; Guéry-Odelin, D.

2018-04-01

We report on a method to calibrate the depth of an optical lattice. It consists of triggering the intrasite dipole mode of the cloud by a sudden phase shift. The corresponding oscillatory motion is directly related to the interband frequencies on a large range of lattice depths. Remarkably, for a moderate displacement, a single frequency dominates the oscillation of the zeroth and first orders of the interference pattern observed after a sufficiently long time of flight. The method is robust against atom-atom interactions and the exact value of the extra weak external confinement superimposed to the optical lattice.

Laser frequency stabilization by light shift of optical-magnetic double resonances

NASA Astrophysics Data System (ADS)

Zhan, Yuanzhi; Peng, Xiang; Lin, Zaisheng; Gong, Wei; Guo, Hong

2015-05-01

This work adopts the light shift of optical-magnetic double resonance frequency in metastable-state 4He atoms to lock the laser center frequency to the magic point. At this magic frequency, both the left-circularly and right-circularly optical pumping processes will give the same value of optical-magnetic double resonance. With this method and after locking, experimental results show that the laser frequency fluctuation is dramatically reduced to 2.79 MHz in 3600 seconds, comparing with 34.1 MHz drift in the free running mode. In application, with the locked magic laser frequency, the heading error for laser pumped 4He magnetometer can be eliminated much. The National Science Fund for Distinguished Young Scholars of China (Grant No. 61225003), the National Natural Science Foundation of China (Grant No. 61101081), and the National Hi-Tech Research and Development (863) Program.

The detection and characterization of high frequency and high wavenumber solar oscillations. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Fernandes, David Neil

1992-01-01

Doppler shift measurements of the Na D(sub 1) absorption line have revealed solar oscillations in a new regime of frequency and wavenumber. Oscillations of vertical velocities in the temperature minimum and low chromosphere of the Sun are observed with frequencies ranging up to 9.5 mHz. There is no evidence for chromospheric modes of 3 minute period. This indicates that the chromosphere does not form a good cavity for acoustic waves. The fundamental-modes appear with wavenumbers up to 5.57 M per m (equivalent spherical harmonic degree, 3877). The frequencies lie below the predicted values at wavenumbers above 1 M per m. The values are in agreement with previous measurements that exist for wavenumbers up to 2.67 M per m. Spatial maps of velocity power show that high wavenumber oscillations are suppressed in active regions. The shape of the power depression indicates that wave motion is affected in the layer of atmosphere where the measurement is made. The f-modes are suppressed in the same way as p-modes, indicating that the mechanism for wave suppression affects velocity fluctuations. Mode frequencies are not affected by the magnetic fields by more than 50 micro Hz, the precision of the measurement.

The Nature of Accelerating Modes in PBG Fibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noble, TRobert J.; /SLAC

Transverse magnetic (TM) modes with phase velocities at or just below the speed of light, c, are intended to accelerate relativistic particles in hollow-core, photonic band gap (PBG) fibers. These are so-called 'surface defect modes', being lattice modes perturbed by the defect to have their frequencies shifted into the band gap, and they can have any phase velocity. PBG fibers also support so-called 'core defect modes' which are characterized as having phase velocities always greater than c and never cross the light line. In this paper we explore the nature of these two classes of accelerating modes and compare theirmore » properties.« less

Dual-Mode Operation of an Optical Lattice Clock Using Strontium and Ytterbium Atoms.

PubMed

Akamatsu, Daisuke; Kobayashi, Takumi; Hisai, Yusuke; Tanabe, Takehiko; Hosaka, Kazumoto; Yasuda, Masami; Hong, Feng-Lei

2018-06-01

We have developed an optical lattice clock that can operate in dual modes: a strontium (Sr) clock mode and an ytterbium (Yb) clock mode. Dual-mode operation of the Sr-Yb optical lattice clock is achieved by alternately cooling and trapping 87 Sr and 171 Yb atoms inside the vacuum chamber of the clock. Optical lattices for Sr and Yb atoms were arranged with horizontal and vertical configurations, respectively, resulting in a small distance of the order of between the trapped Sr and Yb atoms. The 1 S 0 - 3 P 0 clock transitions in the trapped atoms were interrogated in turn and the clock lasers were stabilized to the transitions. We demonstrated the frequency ratio measurement of the Sr and Yb clock transitions by using the dual-mode operation of the Sr-Yb optical lattice clock. The dual-mode operation can reduce the uncertainty of the blackbody radiation shift in the frequency ratio measurement, because both Sr and Yb atoms share the same blackbody radiation.

Microcantilever-based gas sensor employing two simultaneous physical sensing modes

DOEpatents

Loui, Albert; Sirbuly, Donald J; Elhadj, Selim; McCall, Scott K; Hart, Bradley R; Ratto, Timothy V

2014-06-24

According to one embodiment, a system for detecting and identifying gases includes a piezoresistive microcantilever transducer, wherein dissipation of heat from the piezoresistive microcantilever into one or more gases is measured by changes in an electrical resistance of the piezoresistor, a vibrating microcantilever transducer, wherein shifts are measured in resonant frequency of the vibrating microcantilever due to viscous damping thereof by the one or more gases, and a subsystem for correlating the measured resistance changes and the resonant frequency shifts to the one or more gases. In another embodiment, a method for detecting and identifying one or more gases includes determining dissipation of heat from a microcantilever into one or more gases, and determining shifts in resonant frequency of the microcantilever due to viscous damping thereof by the one or more gases. Other systems, methods, and computer program products are also described according to more embodiments.

Nanoscale welding aerosol sensing based on whispering gallery modes in a cylindrical silica resonator.

PubMed

Lee, Aram; Mills, Thomas; Xu, Yong

2015-03-23

We report an experimental technique where one uses a standard silica fiber as a cylindrical whispering gallery mode (WGM) resonator to sense airborne nanoscale aerosols produced by electric arc welding. We find that the accumulation of aerosols on the resonator surface induces a measurable red-shift in resonance frequency, and establish an empirical relation that links the magnitude of resonance shift with the amount of aerosol deposition. The WGM quality factors, by contrast, do not decrease significantly, even for samples with a large percentage of surface area covered by aerosols. Our experimental results are discussed and compared with existing literature on WGM-based nanoparticle sensing.

Vibrational, NMR and quantum chemical investigations of acetoacetanilde, 2-chloroacetoacetanilide and 2-methylacetoacetanilide.

PubMed

Arjunan, V; Kalaivani, M; Senthilkumari, S; Mohan, S

2013-11-01

The vibrational assignment and analysis of the fundamental modes of the compounds acetoacetanilide (AAA), 2-chloroacetoacetanilide (2CAAA) and 2-methylacetoacetanilide (2MAAA) have been performed. Density functional theory studies have been carried out with B3LYP method utilising 6-311++G(**) and cc-pVTZ basis sets to determine structural, thermodynamic and vibrational characteristics of the compounds and also to understand the influence of chloro and methyl groups on the characteristic frequencies of amide (CONH) group. Intramolecular hydrogen bond exists in acetoacetanilide and o-substituted acetoacetanilide molecules and the N⋯O distance is found to be around 2.7Å. The (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecules were determined and the same have been calculated using the gauge independent atomic orbital (GIAO) method. The energies of the frontier molecular orbitals have been determined. In AAA, 2CAAA and 2MAAA molecules, the nN→πCO(∗) interaction between the nitrogen lone pair and the amide CO antibonding orbital gives strong stabilization of 64.75, 62.84 and 64.18kJmol(-1), respectively. The blue shift in amide-II band of 2MAAA is observed by 45-50cm(-1) than that of AAA. The steric effect of ortho methyl group significantly operating on the NH bond properties. The amide-III, the CN stretching mode of methyl and chloro substituted acetoacetanilide compounds are not affected by the substitution while the amide-V band, the NH out of plane bending mode of 2-chloroacetoacetanilide compound is shifted to a higher frequency than that of AAA. The substituent chlorine plays significantly and the blue shift in o-substituted compounds than the parent in the amide-V vibration is observed. The amide-VI, CO out of plane bending modes of 2MAAA and 2CAAA are significantly raised than that of AAA. A blue shift of amide-VI, CO out of plane bending modes of 2MAAA and 2CAAA than AAA is observed. Copyright © 2013 Elsevier B.V. All rights reserved.

Neoclassical quasilinear theory in the superbanana plateau regime and banana kinetics in tokamaks

NASA Astrophysics Data System (ADS)

Shaing, K. C.

2017-12-01

Neoclassical quasilinear transport theory, which is part of a more general theory that unifies neoclassical and quasilinear theories, is extended to the superbanana plateau regime for low frequency (of the order of the drift frequency) electrostatic fluctuations. The physics mechanism that is responsible for the transport losses in this regime is the superbanana plateau resonance. Besides the usual magnetic drifts, Doppler shifted mode frequency also contributes to the resonance condition. Because the characteristic frequency involved in the resonance is of the order of the drift frequency, which is lower than either the bounce or the transit frequency of the particles, the transport losses are higher than the losses calculated in the conventional quasilinear theory. The important effects of the finite banana width, i.e., banana kinetics, are included and are found to reduce the transport losses for short wavelength modes. The implications on the energetic alpha particle energy loss are discussed.

Two modes resonant combined motion for insect wings kinematics reproduction and lift generation

NASA Astrophysics Data System (ADS)

Faux, D.; Thomas, O.; Cattan, E.; Grondel, S.

2018-03-01

This paper presents an original concept using a two resonant vibration modes combined motion to reproduce insect wings kinematics and generate lift. The key issue is to design the geometry and the elastic characteristics of artificial wings such that a combination of flapping and twisting motions in a quadrature phase shift could be obtained. This qualitatively implies to bring the frequencies of the two resonant modes closer. For this purpose, a polymeric prototype was micromachined with a wingspan of 3 cm, flexible wings and a single actuator. An optimal wings configuration was determined with a modeling and validated through experimental modal analyses to verify the proximity of the two modes frequencies. A dedicated lift force measurement bench was developed and used to demonstrate a lift force equivalent to the prototype weight. Finally, at the maximum lift frequency, high-speed camera measurements confirmed a kinematics of the flexible wings with flapping and twisting motions in phase quadrature as expected.

Separation of overlapping vibrational peaks in terahertz spectra using two-dimensional correlation spectroscopy

NASA Astrophysics Data System (ADS)

Hoshina, Hiromichi; Ishii, Shinya; Otani, Chiko

2014-07-01

In this study, the terahertz (THz) absorption spectra of poly(3-hydroxybutyrate) (PHB) were measured during isothermal crystallization at 90-120 °C. The temporal changes in the absorption spectra were analyzed using two-dimensional correlation spectroscopy (2DCOS). In the asynchronous plot, cross peaks were observed around 2.4 THz, suggesting that two vibrational modes overlap in the raw spectrum. By comparing this to the peak at 2.9 THz corresponding to the stretching mode of the helical structure of PHB and the assignment obtained using polarization spectroscopy, we concluded that the high-frequency band could be attributed to the vibration of the helical structure and the low-frequency band to the vibration between the helical structures. The exact frequencies of the overlapping vibrational bands and their assignments provide a new means to inspect the thermal behavior of the intermolecular vibrational modes. The large red-shift of the interhelix vibrational mode suggests a large anharmonicity in the vibrational potential.

Heisenberg symmetry and collective modes of one dimensional unitary correlated fermions

NASA Astrophysics Data System (ADS)

Abhinav, Kumar; Chandrasekhar, B.; Vyas, Vivek M.; Panigrahi, Prasanta K.

2017-02-01

The correlated fermionic many-particle system, near infinite scattering length, reveals an underlying Heisenberg symmetry in one dimension, as compared to an SO (2 , 1) symmetry in two dimensions. This facilitates an exact map from the interacting to the non-interacting system, both with and without a harmonic trap, and explains the short-distance scaling behavior of the wave-function. Taking advantage of the phenomenological Calogero-Sutherland-type interaction, motivated by the density functional approach, we connect the ground-state energy shift, to many-body correlation effect. For the excited states, modes at integral values of the harmonic frequency ω are predicted in one dimension, in contrast to the breathing modes with frequency 2ω in two dimensions.

Stochastic effects on phase-space holes and clumps in kinetic systems near marginal stability

DOE PAGES

Woods, Benjamin J. Q.; Duarte, Vinicius N.; De-Gol, Anthony J.; ...

2018-01-23

The creation and subsequent evolution of marginally-unstable modes have been observed in a wide range of fusion devices. This behaviour has been successfully explained, for a single frequency shifting mode, in terms of phase-space structures known as a 'hole' and 'clump'. Here in this paper, we introduce stochasticity into a 1D kinetic model, affecting the formation and evolution of resonant modes in the system. We find that noise in the fast particle distribution or electric field leads to a shift in the asymptotic behaviour of a chirping resonant mode; this noise heuristically maps onto radial microturbulence via canonical toroidal momentummore » scattering, affecting hole and clump formation. While the mechanism allowing for the formation of the hole and clump is coherent, the lifetime of a hole and clump is shown to be highly sensitive to initial conditions, affecting the temporal profile of a single bursting event in mode amplitude.« less

Stochastic effects on phase-space holes and clumps in kinetic systems near marginal stability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woods, Benjamin J. Q.; Duarte, Vinicius N.; De-Gol, Anthony J.

The creation and subsequent evolution of marginally-unstable modes have been observed in a wide range of fusion devices. This behaviour has been successfully explained, for a single frequency shifting mode, in terms of phase-space structures known as a 'hole' and 'clump'. Here in this paper, we introduce stochasticity into a 1D kinetic model, affecting the formation and evolution of resonant modes in the system. We find that noise in the fast particle distribution or electric field leads to a shift in the asymptotic behaviour of a chirping resonant mode; this noise heuristically maps onto radial microturbulence via canonical toroidal momentummore » scattering, affecting hole and clump formation. While the mechanism allowing for the formation of the hole and clump is coherent, the lifetime of a hole and clump is shown to be highly sensitive to initial conditions, affecting the temporal profile of a single bursting event in mode amplitude.« less

VLBI Radar of the 2012 DA14 Asteroid

NASA Astrophysics Data System (ADS)

Nechaeva, M. B.; Dugin, N. A.; Antipenko, A. A.; Bezrukov, D. A.; Bezrukov, V. V.; Voytyuk, V. V.; Dement'ev, A. F.; Jekabsons, N.; Klapers, M.; Konovalenko, A. A.; Kulishenko, V. F.; Nabatov, A. S.; Nesteruk, V. N.; Putillo, D.; Reznichenko, A. M.; Salerno, E.; Snegirev, S. D.; Tikhomirov, Yu. V.; Khutornoy, R. V.; Skirmante, K.; Shmeld, I.; Chagunin, A. K.

2015-03-01

An experiment on VLBI radar of the 2012 DA14 asteroid was carried out on February 15-16, 2011 at the time of its closest approach to the Earth. The research teams of Kharkov (Institute of Radio Astronomy of the National Academy of Sciences of Ukraine), Evpatoria (National Space Facilities Control and Test Center), Nizhny Novgorod (Radiophysical Research Institute), Bologna (Istituto di Radioastronomia (INAF)), and Ventspils (Ventspils International Radioastronomy Center) took part in the experiment. The asteroid was irradiated by the RT-70 planetary radar (Evpatoria) at a frequency of 5 GHz. The reflected signal was received using two 32-m radio telescopes in Medicina (Italy) and Irbene (Latvia) in radiointerferometric mode. The Doppler frequency shifts in bi-static radar mode and interference frequency in VLBI mode were measured. Accuracy of the VLBI radar method for determining the radial and angular velocities of the asteroid were estimated.

Raman spectroscopy of KxCo2-ySe2 single crystals near the ferromagnet-paramagnet transition

DOE PAGES

Opacic, M.; Lazarevic, N.; Radonjic, M. M.; ...

2016-10-05

Polarized Raman scattering spectra of the K xCo 2-ySe 2 (x = :::; y = :::) single crystals reveal the presence of two phonon modes, assigned as of the A1g and B1g symmetry. Absence of additional modes excludes the possibility of vacancy ordering, unlike in K xCo 2-ySe 2 . The ferromagnetic (FM) phase transition at Tc 74 K leaves a clear fingerprint on the temperature dependence of the Raman mode energy and linewidth. For T > Tc the temperature dependence looks conventional, driven by the thermal expansion and anharmonicity. The Raman modes are rather broad due to the electron-phononmore » coupling increased by the disorder and spin fluctuation e ects. In the FM phase the phonon frequency of both modes increases, while an opposite trend is seen in their linewidth: the A1g mode narrows in the FM phase, whereas the B 1g mode broadens. We argue that the large asymmetry and anomalous frequency shift of the B 1g mode is due to the coupling of spin fluctuations and vibration. Our density functional theory (DFT) calculations for the phonon frequencies agree rather well with the Raman measurements, with some discrepancy being expected since the DFT calculations neglect the spin fluctuations.« less

Effect of intermolecular hydrogen bonding, vibrational analysis and molecular structure of 4-chlorobenzothioamide.

PubMed

Çırak, Çağrı; Sert, Yusuf; Ucun, Fatih

2013-09-01

In the present work, the experimental and theoretical vibrational spectra of 4-chlorobenzothioamide were investigated. The FT-IR (400-4000 cm(-1)) and μ-Raman spectra (100-4000 cm(-1)) of 4-chlorobenzothioamide in the solid phase were recorded. The geometric parameters (bond lengths and bond angles), vibrational frequencies, Infrared and Raman intensities of the title molecule in the ground state were calculated using ab initio Hartree-Fock and density functional theory (B3LYP) methods with the 6-311++G(d,p) basis set for the first time. The optimized geometric parameters and the theoretical vibrational frequencies were found to be in good agreement with the corresponding experimental data and with the results found in the literature. The vibrational frequencies were assigned based on the potential energy distribution using the VEDA 4 program. The dimeric form of 4-chlorobenzothioamide was also simulated to evaluate the effect of intermolecular hydrogen bonding on the vibrational frequencies. It was observed that the N-H stretching modes shifted to lower frequencies, while the in-plane and out-of-plane bending modes shifted to higher frequencies due to the intermolecular N-H···S hydrogen bond. Also, the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies and diagrams were presented. Copyright © 2013 Elsevier B.V. All rights reserved.

Methods and apparatus for broadband frequency comb stabilization

DOEpatents

Cox, Jonathan A; Kaertner, Franz X

2015-03-17

Feedback loops can be used to shift and stabilize the carrier-envelope phase of a frequency comb from a mode-locked fibers laser or other optical source. Compared to other frequency shifting and stabilization techniques, feedback-based techniques provide a wideband closed-loop servo bandwidth without optical filtering, beam pointing errors, or group velocity dispersion. It also enables phase locking to a stable reference, such as a Ti:Sapphire laser, continuous-wave microwave or optical source, or self-referencing interferometer, e.g., to within 200 mrad rms from DC to 5 MHz. In addition, stabilized frequency combs can be coherently combined with other stable signals, including other stabilized frequency combs, to synthesize optical pulse trains with pulse durations of as little as a single optical cycle. Such a coherent combination can be achieved via orthogonal control, using balanced optical cross-correlation for timing stabilization and balanced homodyne detection for phase stabilization.

Inflow/Outflow Conditions for Unsteady Aerodynamics and Aeroacoustics in Nonuniform Flow

NASA Technical Reports Server (NTRS)

Atassi, Oliver V.; Grady, Joseph E. (Technical Monitor)

2003-01-01

The effect of a nonuniform mean flow on the normal modes; the inflow/outflow nonreflecting boundary conditions; and the sound power are studied. The normal modes in an annular duct are computed using a spectral method in combination with a shooting method. The swirl causes force imbalance which couples the acoustic and vortical modes. The acoustic modes are distinguished from the vortical modes by their large pressure and small vorticity content. The mean swirl also produces a Doppler shift in frequency. This results in more counter-spinning modes cut-on at a given frequency than modes spinning with the swirl. Nonreflecting boundary conditions are formulated using the normal mode solutions. The inflow/outflow boundary conditions are implemented in a linearized Euler scheme and validated by computing the propagation of acoustic and vortical waves in a duct for a variety of swirling mean flows. Numerical results show that the evolution of the vortical disturbances is sensitive to the inflow conditions and the details of the wake excitations. All three components of the wake velocity must be considered to correctly compute the wake evolution and the blade upwash. For high frequencies, the acoustic-vortical mode coupling is weak and a conservation equation for the acoustic energy can be derived. Sound power calculations show significant mean flow swirl effects, but mode interference effects are small.

Quasi-continuous frequency tunable terahertz quantum cascade lasers with coupled cavity and integrated photonic lattice.

PubMed

Kundu, Iman; Dean, Paul; Valavanis, Alexander; Chen, Li; Li, Lianhe; Cunningham, John E; Linfield, Edmund H; Davies, A Giles

2017-01-09

We demonstrate quasi-continuous tuning of the emission frequency from coupled cavity terahertz frequency quantum cascade lasers. Such coupled cavity lasers comprise a lasing cavity and a tuning cavity which are optically coupled through a narrow air slit and are operated above and below the lasing threshold current, respectively. The emission frequency of these devices is determined by the Vernier resonance of longitudinal modes in the lasing and the tuning cavities, and can be tuned by applying an index perturbation in the tuning cavity. The spectral coverage of the coupled cavity devices have been increased by reducing the repetition frequency of the Vernier resonance and increasing the ratio of the free spectral ranges of the two cavities. A continuous tuning of the coupled cavity modes has been realized through an index perturbation of the lasing cavity itself by using wide electrical heating pulses at the tuning cavity and exploiting thermal conduction through the monolithic substrate. Single mode emission and discrete frequency tuning over a bandwidth of 100 GHz and a quasi-continuous frequency coverage of 7 GHz at 2.25 THz is demonstrated. An improvement in the side mode suppression and a continuous spectral coverage of 3 GHz is achieved without any degradation of output power by integrating a π-phase shifted photonic lattice in the laser cavity.

Vibrational dynamics and boson peak in a supercooled polydisperse liquid.

PubMed

Abraham, Sneha Elizabeth; Bagchi, Biman

2010-03-01

Vibrational density of states (VDOS) in a supercooled polydisperse liquid is computed by diagonalizing the Hessian matrix evaluated at the potential energy minima for systems with different values of polydispersity. An increase in polydispersity leads to an increase in the relative population of localized high-frequency modes. At low frequencies, the density of states shows an excess compared to the Debye squared-frequency law, which has been identified with the boson peak. The height of the boson peak increases with polydispersity and shows a rather narrow sensitivity to changes in temperature. While the modes comprising the boson peak appear to be largely delocalized, there is a sharp drop in the participation ratio of the modes that exist just below the boson peak indicative of the quasilocalized nature of the low-frequency vibrations. Study of the difference spectrum at two different polydispersity reveals that the increase in the height of boson peak is due to a population shift from modes with frequencies above the maximum in the VDOS to that below the maximum, indicating an increase in the fraction of the unstable modes in the system. The latter is further supported by the facilitation of the observed dynamics by polydispersity. Since the strength of the liquid increases with polydispersity, the present result provides an evidence that the intensity of boson peak correlates positively with the strength of the liquid, as observed earlier in many experimental systems.

Millimeter Wave Generation by Relativistic Electron Beams.

DTIC Science & Technology

1984-12-01

frequency and wave vector matching relations for influence of various nonlinear effects on this instability is this four-wave interaction require...following coupled mode equations _ 6 = 6 _ (14)-- v vx (14) ." .’ for the lower hybrid sidebands: v - V 2 - The x component of the resultant vector equation...involves a purely growing modte, a four-wave interaction plitoces is analysed, including a u ap ti wave- vector up-shifted and ilown-shiftes upper

High-resolution Raman microscopy of curled carbon nanotubes

NASA Astrophysics Data System (ADS)

Ko, Hyunhyub; Pikus, Yuri; Jiang, Chaoyang; Jauss, Andrea; Hollricher, Olaf; Tsukruk, Vladimir V.

2004-09-01

Patterned carbon nanotube assemblies with bent nanotube bundles were investigated with combined atomic force microscopy and confocal Raman imaging spectroscopy to identify conditions of carbon nanotubes in the bent state. We showed that the tangential G mode on Raman spectra systematically shifts downward upon nanotube bending as was predicted earlier. This lower frequency shift is attributed to the tensile stress, which results in the loosening of C -C bonds in the outer nanotube walls.

Stimulated low-frequency Raman scattering in aqueous suspension of nanoparticles

NASA Astrophysics Data System (ADS)

Averyushkin, Anatolii S.; Baranov, Anatoly N.; Bulychev, Nikolay A.; Kazaryan, Mishik A.; Kudryavtseva, Anna D.; Shevchenko, Mikhail A.; Strokov, Maxim A.; Tcherniega, Nikolay V.; Zemskov, Konstantin I.

2018-04-01

The low-frequency acoustic mode in nanoparticles of different nature in aqueous suspension has been studied by stimulated low-frequency Raman scattering (SLFRS). Nanoparticles investigated (CuO, Ag, Au, ZnS) had different dimensions and different vibrational properties. Synthesis of cupric oxide nanoparticles in acoustoplasma discharge is described in details. SLFRS has been excited by nanosecond pulses of ruby laser. Spectra of the scattered light had been registered with the help of Fabry-Perot interferometer. SLFRS conversion efficiency, threshold and frequency shift of the scattered light are measured.

Advanced investigation of two-phase charge-coupled devices

NASA Technical Reports Server (NTRS)

Kosonocky, W. F.; Carnes, J. E.

1973-01-01

The performance of experimental two phase, charge-coupled shift registers constructed using polysilicon gates overlapped by aluminum gates was studied. Shift registers with 64, 128, and 500 stages were built and operated. Devices were operated at the maximum clock frequency of 20 MHz. Loss per transfer of less than .0001 was demonstrated for fat zero operation. The effect upon transfer efficiency of various structural and materials parameters was investigated including substrate orientation, resistivity, and conductivity type; channel width and channel length; and method of channel confinement. Operation of the devices with and without fat zero was studied as well as operation in the complete charge transfer mode and the bias charge, or bucket brigade mode.

Shuttle ku-band communications/radar technical concepts

NASA Technical Reports Server (NTRS)

Griffin, J. W.; Kelley, J. S.; Steiner, A. W.; Vang, H. A.; Zrubek, W. E.; Huth, G. K.

1985-01-01

Technical data on the Shuttle Orbiter K sub u-band communications/radar system are presented. The more challenging aspects of the system design and development are emphasized. The technical problems encountered and the advancements made in solving them are discussed. The radar functions are presented first. Requirements and design/implementation approaches are discussed. Advanced features are explained, including Doppler measurement, frequency diversity, multiple pulse repetition frequencies and pulse widths, and multiple modes. The communications functions that are presented include advances made because of the requirements for multiple communications modes. Spread spectrum, quadrature phase shift keying (QPSK), variable bit rates, and other advanced techniques are discussed. Performance results and conclusions reached are outlined.

Bistability in Josephson Junction array resonator

NASA Astrophysics Data System (ADS)

Muppalla, Phani Raja; Alexandre Blais Collaboration; Christian Kraglund Andersen Collaboration; Ioan Pop, Lukas Gruenhaupt Collaboration; Michel Devoret Collaboration; Oscar Garguilo, Gerhard Kirchmair Team

``We present an experimental analysis of the Kerr effect of extended plasma resonances in a 1000 Josephson junction (JJ) chain resonator inside a rectangular waveguide. The Kerr effect manifests itself as a frequency shift that depends linearly on the number of photons in a resonant mode. We study the bistable behavior, using a pump probe scheme on two modes of the JJ array, exploiting the Cross-Kerr effect in our system. In order to understand the behavior of the bi-stability we perform continuous time measurements to observe the switching between the two metastable states. We observe a strong dependence of the switching rates on the photon number and the drive frequency.''

Role of antenna modes and field enhancement in second harmonic generation from dipole nanoantennas.

PubMed

de Ceglia, Domenico; Vincenti, Maria Antonietta; De Angelis, Costantino; Locatelli, Andrea; Haus, Joseph W; Scalora, Michael

2015-01-26

We study optical second harmonic generation from metallic dipole antennas with narrow gaps. Enhancement of the fundamental-frequency field in the gap region plays a marginal role on conversion efficiency. In the symmetric configuration, i.e., with the gap located at the center of the antenna axis, reducing gap size induces a significant red-shift of the maximum conversion efficiency peak. Either enhancement or inhibition of second-harmonic emission may be observed as gap size is decreased, depending on the antenna mode excited at the harmonic frequency. The second-harmonic signal is extremely sensitive to the asymmetry introduced by gap's displacements with respect to the antenna center. In this situation, second-harmonic light can couple to all the available antenna modes. We perform a multipolar analysis that allows engineering the far-field SH emission and find that the interaction with quasi-odd-symmetry modes generates radiation patterns with a strong dipolar component.

Single-mode dispersive waves and soliton microcomb dynamics

PubMed Central

Yi, Xu; Yang, Qi-Fan; Zhang, Xueyue; Yang, Ki Youl; Li, Xinbai; Vahala, Kerry

2017-01-01

Dissipative Kerr solitons are self-sustaining optical wavepackets in resonators. They use the Kerr nonlinearity to both compensate dispersion and offset optical loss. Besides providing insights into nonlinear resonator physics, they can be applied in frequency metrology, precision clocks, and spectroscopy. Like other optical solitons, the dissipative Kerr soliton can radiate power as a dispersive wave through a process that is the optical analogue of Cherenkov radiation. Dispersive waves typically consist of an ensemble of optical modes. Here, a limiting case is studied in which the dispersive wave is concentrated into a single cavity mode. In this limit, its interaction with the soliton induces hysteresis behaviour in the soliton's spectral and temporal properties. Also, an operating point of enhanced repetition-rate stability occurs through balance of dispersive-wave recoil and Raman-induced soliton-self-frequency shift. The single-mode dispersive wave can therefore provide quiet states of soliton comb operation useful in many applications. PMID:28332495

Cooperative Lamb shift and superradiance in an optoelectronic device

NASA Astrophysics Data System (ADS)

Frucci, G.; Huppert, S.; Vasanelli, A.; Dailly, B.; Todorov, Y.; Beaudoin, G.; Sagnes, I.; Sirtori, C.

2017-04-01

When a single excitation is shared between a large number of two-level systems, a strong enhancement of the spontaneous emission appears. This phenomenon is known as superradiance. This enhanced rate can be accompanied by a shift of the emission frequency, the cooperative Lamb shift, issued from the exchange of virtual photons between the emitters. In this work we present a semiconductor optoelectronic device allowing the observation of these two phenomena at room temperature. We demonstrate experimentally and theoretically that plasma oscillations in spatially separated quantum wells interact through real and virtual photon exchange. This gives rise to a superradiant mode displaying a large cooperative Lamb shift.

Observations of highly sheared turbulence in the H-mode pedestal using Phase Contrast Imaging on DIII-D

NASA Astrophysics Data System (ADS)

Rost, J. C.; Marinoni, A.; Davis, E. M.; Porkolab, M.; Burrell, K. H.

2017-10-01

Highly sheared turbulence with short radial correlation lengths has been measured near the top of the H-mode pedestal, in addition to the previously measured highly-sheared turbulence measured in the Er well. Turbulence in regions of large velocity shear is characterized by radial correlation lengths shorter than the poloidal wavelength (L < λ 2 cm) and large Doppler-shifted frequencies (f > 200 kHz). The phase contrast imaging (PCI) diagnostic on DIII-D is ideally suited to measuring this density turbulence due to the measurement geometry and high frequency bandwidth. Radial localization is achieved by optical filtering, varying the ExB profile, and shifting the plasma position. Reconfiguration of the Er well, such as at the L-H transition or the transition to wide pedestal QH-mode, shows a near-instantaneous change (t < 1 ms) to the sheared turbulence in the Er well ( 1 cm inside the separatrix). In contrast, the sheared turbulence near the top of the pedestal ( 2 cm inside the separatrix) varies over times scales of tens of ms, consistent with pedestal evolution. Work supported by the US Department of Energy under DE-FG02-94ER54235 and DE-FC02-04ER54698.

Vibrational dynamics of the CO stretching of 9-fluorenone studied by visible-pump and infrared-probe spectroscopy.

PubMed

Fukui, Yuki; Ohta, Kaoru; Tominaga, Keisuke

2015-01-01

We studied the effects of hydrogen bonds on the vibrational structures and vibrational dynamics of the CO stretching mode of 9-fluorenone (FL) in the electronically excited state in aprotic and protic solvents using sub-picosecond visible-pump and IR-probe spectroscopy. The transient IR spectrum of the CO stretching band in methanol-d4 has two bands at 1529.9 cm(-1) and 1543.4 cm(-1), which are assigned to an FL-solvent complex and free FL, respectively. In the aprotic solvents, the CO stretching bands show blue-shifts in time. This shift is due to vibrational cooling, which is derived from anharmonic couplings with some low-frequency modes. Interestingly, a red-shift is observed at later delay time for the band at 1529.9 cm(-1) in methanol-d4. A possible mechanism of this spectral shift is related to the hydrogen bond dynamics between the solute and solvent.

Theoretical Study on Sers of Wagging Vibrations of Benzyl Radical Adsorbed on Silver Electrodes

NASA Astrophysics Data System (ADS)

Wu, De-Yin; Chen, Yan-Li; Tian, Zhong-Qun

2016-06-01

Electrochemical surface-enhanced Raman spectroscopy (EC-SERS) has been used to characterize adsorbed species widely but reaction intermediates rarely on electrodes. In previous studies, the observed SERS signals were proposed from surface benzyl species due to the electrochemical reduction of benzyl chloride on silver electrode surfaces. In this work, we reinvestigated the vibrational assignments of benzyl chloride and benzyl radical as the reaction intermediate. On the basis of density functional theoretical (DFT) calculations and normal mode analysis, our systematical results provide more reasonable new assignments for both surface species. Further, we investigated adsorption configurations, binding energies, and vibrational frequency shifts of benzyl radical interacting with silver. Our calculated results show that the wagging vibration displays significant vibrational frequency shift, strong coupling with some intramolecular modes in the phenyl ring, and significant changes in intensity of Raman signals. The study also provides absolute Raman intensity in benzyl halides and discuss the enhancement effect mainly due to the binding interaction with respect to free benzyl radical.

A finite element analysis of the vibrational behaviour of the intra-operatively manufactured prosthesis-femur system.

PubMed

Pastrav, L C; Devos, J; Van der Perre, G; Jaecques, S V N

2009-05-01

In total hip replacement (THR) a good initial stability of the prosthetic stem in the femur, which corresponds to a good overall initial contact, will help assure a good long-term result. During the insertion the implant stability increases and, as a consequence, the resonance frequencies increase, allowing the assessment of the implant fixation by vibration analysis. The influence of changing contact conditions on the resonance frequencies was however not yet quantitatively understood and therefore a finite element analysis (FEA) was set up. Modal analyses on the hip stem-femur system were performed in various contact situations. By modelling the contact changes by means of the contact tolerance options in the finite element software, contact could be varied over the entire hip stem surface or only in specific zones (proximal, central, distal) while keeping other system parameters constant. The results are in agreement with previous observations: contact increase causes positive resonance frequency shifts and the dynamic behaviour is most influenced by contact changes in the proximal zone. Although the finite element analysis did not establish a monotonous relationship between the vibrational mode number and the magnitude of the resonance frequency shift, in general the higher modes are more sensitive to the contact change.

On the Role of Resonances in Nonradial Pulsators

NASA Technical Reports Server (NTRS)

Buchler, J. R.; Goupil, M. J.; Hansen, C. J.

1997-01-01

Resonances or near resonances are ubiquitous among the excited nonradial pulsation modes of variable stars and they must play an important role in determining their pulsational behavior. Here in a first step at nonlinear asteroseismology, we explore some of the consequences of resonances by means of the amplitude equation formalism. We show how parity and angular momentum constraints can be used to eliminate many of the possible nonlinear resonant couplings between modes (and multiplets of modes), and how the amplitude equations can thus be simplified. Even when we may not be able, nor wish, to make an ab initio computation of the values of the coupling coefficients, it is still possible to obtain constraints on the nature of the excited modes if a resonance between observed frequencies can be identified. Resonances can cause nonlinear frequency locking of modes. This means that the observed frequencies appear in exact resonance even though the linear frequencies are only approximately in resonance. The nonlinear frequency lock, when it occurs, it does so over a range of departures from linear resonance, and it is accompanied by constant pulsation amplitudes. The locked, nonlinear frequencies can differ noticeably from their nonresonant counterparts which are usually used in seismology. This is particularly true for multiplets of modes split by rotation. Beyond the regime of the frequency lock, amplitude and frequency modulations can appear in the pulsations. Far from the resonance condition one recovers the regime of steady pulsations with nonresonant frequencies for which the seismological studies, as they are presently carried out, are justified (provided furthermore, of course, that nonlinear frequency shifts are negligible). Success in identifying a resonance in an observed power spectrum depends on the quality of the data. While keeping this limitation in mind, ew discuss the possible existence of peculiar resonances the pulsations specific variable white dwarfs and delta Scuti stars.

Mitigating leakage errors due to cavity modes in a superconducting quantum computer

NASA Astrophysics Data System (ADS)

McConkey, T. G.; Béjanin, J. H.; Earnest, C. T.; McRae, C. R. H.; Pagel, Z.; Rinehart, J. R.; Mariantoni, M.

2018-07-01

A practical quantum computer requires quantum bit (qubit) operations with low error probabilities in extensible architectures. We study a packaging method that makes it possible to address hundreds of superconducting qubits by means of coaxial Pogo pins. A qubit chip is housed in a superconducting box, where both box and chip dimensions lead to unwanted modes that can interfere with qubit operations. We analyze these interference effects in the context of qubit coherent leakage and qubit decoherence induced by damped modes. We propose two methods, half-wave fencing and antinode pinning, to mitigate the resulting errors by detuning the resonance frequency of the modes from the qubit frequency. We perform electromagnetic field simulations indicating that the resonance frequency of the modes increases with the number of installed pins and can be engineered to be significantly higher than the highest qubit frequency. We estimate that the error probabilities and decoherence rates due to suitably shifted modes in realistic scenarios can be up to two orders of magnitude lower than the state-of-the-art superconducting qubit error and decoherence rates. Our methods can be extended to different types of packages that do not rely on Pogo pins. Conductive bump bonds, for example, can serve the same purpose in qubit architectures based on flip chip technology. Metalized vias, instead, can be used to mitigate modes due to the increasing size of the dielectric substrate on which qubit arrays are patterned.

Self-consistent frequencies of the electron-photon system

NASA Astrophysics Data System (ADS)

Hawton, Margaret

1993-09-01

The Heisenberg equations describing the dynamics of coupled Fermion photon operators are solved self-consistently. Photon modes, for which ω~=kc, and particlelike Bohr modes with frequencies ωnI~=(En-EI)/ħ are both approximate solutions to the system of equations that results if the current density is the source in the operator Maxwell equations. Current fluctuations associated with the Bohr modes and required by a fluctuation-dissipation theorem are attributed to the point nature of the particle. The interaction energy is given by the Casimir-force-like expression ΔE=1/2ħtsum(ΔωnI+Δωkc) or by the expectation value of 1/2(qcphi-qp^.A^/mc+q2A2/mc2). It is verified that the equal-time momentum-density and vector-potential operators commute if the contributions of both the Bohr modes and vacuum fluctuations are included. Both electromagnetic and Bohr or radiation-reaction modes are found to contribute equally to spontaneous emission and to the Lamb shift.

Communication: Probing non-equilibrium vibrational relaxation pathways of highly excited C≡N stretching modes following ultrafast back-electron transfer.

PubMed

Lynch, Michael S; Slenkamp, Karla M; Khalil, Munira

2012-06-28

Fifth-order nonlinear visible-infrared spectroscopy is used to probe coherent and incoherent vibrational energy relaxation dynamics of highly excited vibrational modes indirectly populated via ultrafast photoinduced back-electron transfer in a trinuclear cyano-bridged mixed-valence complex. The flow of excess energy deposited into four C≡N stretching (ν(CN)) modes of the molecule is monitored by performing an IR pump-probe experiment as a function of the photochemical reaction (τ(vis)). Our results provide experimental evidence that the nuclear motions of the molecule are both coherently and incoherently coupled to the electronic charge transfer process. We observe that intramolecular vibrational relaxation dynamics among the highly excited ν(CN) modes change significantly en route to equilibrium. The experiment also measures a 7 cm(-1) shift in the frequency of a ∼57 cm(-1) oscillation reflecting a modulation of the coupling between the probed high-frequency ν(CN) modes for τ(vis) < 500 fs.

Strain mapping in single-layer two-dimensional crystals via Raman activity

NASA Astrophysics Data System (ADS)

Yagmurcukardes, M.; Bacaksiz, C.; Unsal, E.; Akbali, B.; Senger, R. T.; Sahin, H.

2018-03-01

By performing density functional theory-based ab initio calculations, Raman-active phonon modes of single-layer two-dimensional (2D) materials and the effect of in-plane biaxial strain on the peak frequencies and corresponding activities of the Raman-active modes are calculated. Our findings confirm the Raman spectrum of the unstrained 2D crystals and provide expected variations in the Raman-active modes of the crystals under in-plane biaxial strain. The results are summarized as follows: (i) frequencies of the phonon modes soften (harden) under applied tensile (compressive) strains; (ii) the response of the Raman activities to applied strain for the in-plane and out-of-plane vibrational modes have opposite trends, thus, the built-in strains in the materials can be monitored by tracking the relative activities of those modes; (iii) in particular, the A peak in single-layer Si and Ge disappears under a critical tensile strain; (iv) especially in mono- and diatomic single layers, the shift of the peak frequencies is a stronger indication of the strain rather than the change in Raman activities; (v) Raman-active modes of single-layer ReX2 (X =S , Se) are almost irresponsive to the applied strain. Strain-induced modifications in the Raman spectrum of 2D materials in terms of the peak positions and the relative Raman activities of the modes could be a convenient tool for characterization.

A Novel Method to Reconstruct the Force Curve by Higher Harmonics of the First Two Flexural Modes in Frequency Modulation Atomic Force Microscope (FM-AFM).

PubMed

Zhang, Suoxin; Qian, Jianqiang; Li, Yingzi; Zhang, Yingxu; Wang, Zhenyu

2018-06-04

Atomic force microscope (AFM) is an idealized tool to measure the physical and chemical properties of the sample surfaces by reconstructing the force curve, which is of great significance to materials science, biology, and medicine science. Frequency modulation atomic force microscope (FM-AFM) collects the frequency shift as feedback thus having high force sensitivity and it accomplishes a true noncontact mode, which means great potential in biological sample detection field. However, it is a challenge to establish the relationship between the cantilever properties observed in practice and the tip-sample interaction theoretically. Moreover, there is no existing method to reconstruct the force curve in FM-AFM combining the higher harmonics and the higher flexural modes. This paper proposes a novel method that a full force curve can be reconstructed by any order higher harmonics of the first two flexural modes under any vibration amplitude in FM-AFM. Moreover, in the small amplitude regime, short range forces are reconstructed more accurately by higher harmonics analysis compared with fundamental harmonics using the Sader-Jarvis formula.

Effect of pressure on the Raman-active modes of zircon (ZrSiO4): a first-principles study

NASA Astrophysics Data System (ADS)

Sheremetyeva, Natalya; Cherniak, Daniele J.; Watson, E. Bruce; Meunier, Vincent

2018-02-01

Density-functional theory (DFT) was employed in a first-principles study of the effects of pressure on the Raman-active modes of zircon (ZrSiO4), using both the generalized gradient and local density approximations (GGA and LDA, respectively). Beginning with the equilibrium structure at zero pressure, we conducted a calibration of the effect of pressure in a manner procedurally similar to an experimental calibration. For pressures between 0 and 7 GPa, we find excellent qualitative agreement of frequency-pressure slopes partial ω /partial P calculated from GGA DFT with results of previous experimental studies. In addition, we were able to rationalize the ω vs. P behavior based on details of the vibrational modes and their atomic displacements. Most of the partial ω /partial P slopes are positive as expected, but the symmetry of the zircon lattice also results in two negative slopes for modes that involve slight shearing and rigid rotation of SiO4 tetrahedra. Overall, LDA yields absolute values of the frequencies of the Raman-active modes in good agreement with experimental values, while GGA reproduces the shift in frequency with pressure especially well.

High-resolution quantization based on soliton self-frequency shift and spectral compression in a bi-directional comb-fiber architecture

NASA Astrophysics Data System (ADS)

Zhang, Xuyan; Zhang, Zhiyao; Wang, Shubing; Liang, Dong; Li, Heping; Liu, Yong

2018-03-01

We propose and demonstrate an approach that can achieve high-resolution quantization by employing soliton self-frequency shift and spectral compression. Our approach is based on a bi-directional comb-fiber architecture which is composed of a Sagnac-loop-based mirror and a comb-like combination of N sections of interleaved single-mode fibers and high nonlinear fibers. The Sagnac-loop-based mirror placed at the terminal of a bus line reflects the optical pulses back to the bus line to achieve additional N-stage spectral compression, thus single-stage soliton self-frequency shift (SSFS) and (2 N - 1)-stage spectral compression are realized in the bi-directional scheme. The fiber length in the architecture is numerically optimized, and the proposed quantization scheme is evaluated by both simulation and experiment in the case of N = 2. In the experiment, a quantization resolution of 6.2 bits is obtained, which is 1.2-bit higher than that of its uni-directional counterpart.

Impact of bootstrap current and Landau-fluid closure on ELM crashes and transport

NASA Astrophysics Data System (ADS)

Chen, J. G.; Xu, X. Q.; Ma, C. H.; Lei, Y. A.

2018-05-01

Results presented here are from 6-field Landau-Fluid simulations using shifted circular cross-section tokamak equilibria on BOUT++ framework. Linear benchmark results imply that the collisional and collisionless Landau resonance closures make a little difference on linear growth rate spectra which are quite close to the results with the flux limited Spitzer-Härm parallel flux. Both linear and nonlinear simulations show that the plasma current profile plays dual roles on the peeling-ballooning modes that it can drive the low-n peeling modes and stabilize the high-n ballooning modes. For fixed total pressure and current, as the pedestal current decreases due to the bootstrap current which becomes smaller when the density (collisionality) increases, the operational point is shifted downwards vertically in the Jped - α diagram, resulting in threshold changes of different modes. The bootstrap current can slightly increase radial turbulence spreading range and enhance the energy and particle transports by increasing the perturbed amplitude and broadening cross-phase frequency distribution.

Nonlinear optical modulation in a plasmonic Bi:YIG Mach-Zehnder interferometer

NASA Astrophysics Data System (ADS)

Firby, C. J.; Elezzabi, A. Y.

2017-02-01

In this work, we propose a magnetoplasmonic modulator for nonlinear radio-frequency (RF) modulation of an integrated optical signal. The modulator consists of a plasmonic Mach-Zehnder interferometer (MZI), constructed of the ferrimagnetic garnet, bismuth-substituted yttrium iron garnet (Bi:YIG). The transverse component of the Bi:YIG magnetization induces a nonreciprocal phase shift (NRPS) onto the guided optical mode, which can be actively modulated through external magnetic fields. In an MZI, the modulated phase shift in turn modulates the output optical intensity. Due to the highly nonlinear evolution of the Bi:YIG magnetization, we show that the spectrum of the output modulated intensity signal can contain harmonics of the driving RF field, frequency splitting around the driving frequency, down-conversion, or mixing of multiple RF signals. This device provides a unique mechanism of simultaneously generating a number of modulation frequencies within a single device.

Influence of La doping on structural and dielectric properties of SrBi2Nb2O9 ceramics

NASA Astrophysics Data System (ADS)

Verma, Maya; Sreenivas, K.; Gupta, Vinay

2009-01-01

Lanthanum doped SrBi2Nb2O9 ceramics with the chemical formula SrBi2-xLaxNb2O9 (SBLN) (x =0-0.5) have been prepared through conventional solid state route. X-ray diffraction reveals the shrinkage of unit cell of strontium bismuth niobate with incorporation of La3+ dopant, having no lone pair electrons. Shifting of Raman phonon modes indicates the reduced rattling space of NbO6 octahedra with increase in La doping concentration. Further, the softening of lowest frequency phonon mode with increasing x in SBLN shows the transition from ferroelectric to paraelectric at room temperature. The dielectric properties for all the compositions are studied as a function of temperature (25 to 500 °C) over the frequency range of 10 kHz-1 MHz. With increase in lanthanum doping concentration the phase transition becomes diffused and transition temperature gets shifted toward lower temperature. A phase transition from normal ferroelectric to paraelectric has been observed via relaxor-type ferroelectrics with increase in x. The frequency dependence of transition temperature was studied in terms of Vogel-Fulcher relation for SBLN (x =0.4).

Femtosecond coherent nuclear dynamics of excited tetraphenylethylene: Ultrafast transient absorption and ultrafast Raman loss spectroscopic studies

NASA Astrophysics Data System (ADS)

Kayal, Surajit; Roy, Khokan; Umapathy, Siva

2018-01-01

Ultrafast torsional dynamics plays an important role in the photoinduced excited state dynamics. Tetraphenylethylene (TPE), a model system for the molecular motor, executes interesting torsional dynamics upon photoexcitation. The photoreaction of TPE involves ultrafast internal conversion via a nearly planar intermediate state (relaxed state) that further leads to a twisted zwitterionic state. Here, we report the photoinduced structural dynamics of excited TPE during the course of photoisomerization in the condensed phase by ultrafast Raman loss (URLS) and femtosecond transient absorption (TA) spectroscopy. TA measurements on the S1 state reveal step-wise population relaxation from the Franck-Condon (FC) state → relaxed state → twisted state, while the URLS study provides insights on the vibrational dynamics during the course of the reaction. The TA spectral dynamics and vibrational Raman amplitudes within 1 ps reveal vibrational wave packet propagating from the FC state to the relaxed state. Fourier transformation of this oscillation leads to a ˜130 cm-1 low-frequency phenyl torsional mode. Two vibrational marker bands, Cet=Cet stretching (˜1512 cm-1) and Cph=Cph stretching (˜1584 cm-1) modes, appear immediately after photoexcitation in the URLS spectra. The initial red-shift of the Cph=Cph stretching mode with a time constant of ˜400 fs (in butyronitrile) is assigned to the rate of planarization of excited TPE. In addition, the Cet=Cet stretching mode shows initial blue-shift within 1 ps followed by frequency red-shift, suggesting that on the sub-picosecond time scale, structural relaxation is dominated by phenyl torsion rather than the central Cet=Cet twist. Furthermore, the effect of the solvent on the structural dynamics is discussed in the context of ultrafast nuclear dynamics and solute-solvent coupling.

Femtosecond coherent nuclear dynamics of excited tetraphenylethylene: Ultrafast transient absorption and ultrafast Raman loss spectroscopic studies.

PubMed

Kayal, Surajit; Roy, Khokan; Umapathy, Siva

2018-01-14

Ultrafast torsional dynamics plays an important role in the photoinduced excited state dynamics. Tetraphenylethylene (TPE), a model system for the molecular motor, executes interesting torsional dynamics upon photoexcitation. The photoreaction of TPE involves ultrafast internal conversion via a nearly planar intermediate state (relaxed state) that further leads to a twisted zwitterionic state. Here, we report the photoinduced structural dynamics of excited TPE during the course of photoisomerization in the condensed phase by ultrafast Raman loss (URLS) and femtosecond transient absorption (TA) spectroscopy. TA measurements on the S 1 state reveal step-wise population relaxation from the Franck-Condon (FC) state → relaxed state → twisted state, while the URLS study provides insights on the vibrational dynamics during the course of the reaction. The TA spectral dynamics and vibrational Raman amplitudes within 1 ps reveal vibrational wave packet propagating from the FC state to the relaxed state. Fourier transformation of this oscillation leads to a ∼130 cm -1 low-frequency phenyl torsional mode. Two vibrational marker bands, C et =C et stretching (∼1512 cm -1 ) and C ph =C ph stretching (∼1584 cm -1 ) modes, appear immediately after photoexcitation in the URLS spectra. The initial red-shift of the C ph =C ph stretching mode with a time constant of ∼400 fs (in butyronitrile) is assigned to the rate of planarization of excited TPE. In addition, the C et =C et stretching mode shows initial blue-shift within 1 ps followed by frequency red-shift, suggesting that on the sub-picosecond time scale, structural relaxation is dominated by phenyl torsion rather than the central C et =C et twist. Furthermore, the effect of the solvent on the structural dynamics is discussed in the context of ultrafast nuclear dynamics and solute-solvent coupling.

Unveiling Extreme Anisotropy in Elastic Structured Media

NASA Astrophysics Data System (ADS)

Lefebvre, G.; Antonakakis, T.; Achaoui, Y.; Craster, R. V.; Guenneau, S.; Sebbah, P.

2017-06-01

Periodic structures can be engineered to exhibit unique properties observed at symmetry points, such as zero group velocity, Dirac cones, and saddle points; identifying these and the nature of the associated modes from a direct reading of the dispersion surfaces is not straightforward, especially in three dimensions or at high frequencies when several dispersion surfaces fold back in the Brillouin zone. A recently proposed asymptotic high-frequency homogenization theory is applied to a challenging time-domain experiment with elastic waves in a pinned metallic plate. The prediction of a narrow high-frequency spectral region where the effective medium tensor dramatically switches from positive definite to indefinite is confirmed experimentally; a small frequency shift of the pulse carrier results in two distinct types of highly anisotropic modes. The underlying effective equation mirrors this behavior with a change in form from elliptic to hyperbolic exemplifying the high degree of wave control available and the importance of a simple and effective predictive model.

Analysis of self-homodyne detection for 6-mode fiber with low-modal crosstalk

NASA Astrophysics Data System (ADS)

Guo, Meng; Hu, Guijun

2017-12-01

In this paper, we present an appropriate analysis on self-homodyne coherent system with 56 × 5 × 3 Gb / s WDM-PDM-MDM quadrature phase-shift keying (QPSK) signals using 6-mode weakly coupled few mode fiber. The mode division technology can effectively improve the spectral efficiency (SE) of self-homodyne detection. Of all the LP modes, LP01 mode is used to transmit the pilot tone (PT), while the others for signal channels. The influence of inter-mode crosstalk is analyzed. The proposed frequency domain MMA shows a better BER performance for intra-mode crosstalk elimination. The path-length misalignment's influence caused by mode differential group delay (MDGD) is also investigated. The system tolerance for different laser's line-width is compared as well as the influence of PT filter's bandwidth.

NSLS-II BPM System Protection from Rogue Mode Coupling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blednykh, A.; Bach, B.; Borrelli, A.

2011-03-28

Rogue mode RF shielding has been successfully designed and implemented into the production multipole vacuum chambers. In order to avoid systematic errors in the NSLS-II BPM system we introduced frequency shift of HOM's by using RF metal shielding located in the antechamber slot of each multipole vacuum chamber. To satisfy the pumping requirement the face of the shielding has been perforated with roughly 50 percent transparency. It stays clear of synchrotron radiation in each chamber.

Nonlinear modal resonances in low-gravity slosh-spacecraft systems

NASA Technical Reports Server (NTRS)

Peterson, Lee D.

1991-01-01

Nonlinear models of low gravity slosh, when coupled to spacecraft vibrations, predict intense nonlinear eigenfrequency shifts at zero gravity. These nonlinear frequency shifts are due to internal quadratic and cubic resonances between fluid slosh modes and spacecraft vibration modes. Their existence has been verified experimentally, and they cannot be correctly modeled by approximate, uncoupled nonlinear models, such as pendulum mechanical analogs. These predictions mean that linear slosh assumptions for spacecraft vibration models can be invalid, and may lead to degraded control system stability and performance. However, a complete nonlinear modal analysis will predict the correct dynamic behavior. This paper presents the analytical basis for these results, and discusses the effect of internal resonances on the nonlinear coupled response at zero gravity.

Thermal stress effects on the flexural wave bandgap of a two-dimensional locally resonant acoustic metamaterial

NASA Astrophysics Data System (ADS)

Li, Zhen; Zhu, Yun; Li, Yueming

2018-05-01

The elastic wave bandgap is obviously affected by heat while considering thermal stress. Nevertheless, the flat band, occurring in the lowest flexural branch, has not yet been explained clearly. This study investigates the influence of thermal stress on a flexural wave bandgap in a two-dimensional three-component acoustic metamaterial. Simulation results demonstrate that the band structure shifts to a lower frequency range, and the vibration response appears at a larger amplitude due to the bending stiffness being softened by the compressive membrane force. In addition, the first flexural band reduces to zero frequency in the central Brillouin zone. By viewing the vibration modes of the proposed unit cell, it is found that the out-of-plane mode shape attenuates with increasing temperature, while the in-plane vibration modes are unaffected by thermal stress.

Quasinormal modes and quantization of area/entropy for noncommutative BTZ black hole

NASA Astrophysics Data System (ADS)

Huang, Lu; Chen, Juhua; Wang, Yongjiu

2018-04-01

We investigate the quasinormal modes and area/entropy spectrum for the noncommutative BTZ black hole. The exact expressions for QNM frequencies are presented by expanding the noncommutative parameter in horizon radius. We find that the noncommutativity does not affect conformal weights (hL, hR), but it influences the thermal equilibrium. The intuitive expressions of the area/entropy spectrum are calculated in terms of Bohr-Sommerfeld quantization, and our results show that the noncommutativity leads to a nonuniform area/entropy spectrum. We also find that the coupling constant ξ , which is the coupling between the scalar and the gravitational fields, shifts the QNM frequencies but not influences the structure of area/entorpy spectrum.

On the origin of amplitude reduction mechanism in tapping mode atomic force microscopy

NASA Astrophysics Data System (ADS)

Keyvani, Aliasghar; Sadeghian, Hamed; Goosen, Hans; van Keulen, Fred

2018-04-01

The origin of amplitude reduction in Tapping Mode Atomic Force Microscopy (TM-AFM) is typically attributed to the shift in resonance frequency of the cantilever due to the nonlinear tip-sample interactions. In this paper, we present a different insight into the same problem which, besides explaining the amplitude reduction mechanism, provides a simple reasoning for the relationship between tip-sample interactions and operation parameters (amplitude and frequency). The proposed formulation, which attributes the amplitude reduction to an interference between the tip-sample and dither force, only deals with the linear part of the system; however, it fully agrees with experimental results and numerical solutions of the full nonlinear model of TM-AFM.

A scenario for magnonic spin-wave traps

PubMed Central

Busse, Frederik; Mansurova, Maria; Lenk, Benjamin; von der Ehe, Marvin; Münzenberg, Markus

2015-01-01

Spatially resolved measurements of the magnetization dynamics on a thin CoFeB film induced by an intense laser pump-pulse reveal that the frequencies of resulting spin-wave modes depend strongly on the distance to the pump center. This can be attributed to a laser generated temperature profile. We determine a shift of 0.5 GHz in the spin-wave frequency due to the spatial thermal profile induced by the femtosecond pump pulse that persists for up to one nanosecond. Similar experiments are presented for a magnonic crystal composed of a CoFeB-film based antidot lattice with a Damon Eshbach mode at the Brillouin zone boundary and its consequences are discussed. PMID:26279466

Self-starting picosecond optical pulse source using stimulated Brillouin scattering in an optical fiber.

PubMed

Tang, W W; Shu, C

2005-02-21

We demonstrate a regeneratively mode-locked optical pulse source at about 10 GHz using an optoelectronic oscillator constructed with an electro-absorption modulator integrated distributed feedback laser diode. The 10 GHz RF component is derived from the interaction between the pump wave and the backscattered, frequency-downshifted Stokes wave resulted from stimulated Brillouin scattering in an optical fiber. The component serves as a modulation source for the 1556 nm laser diode without the need for any electrical or optical RF filter to perform the frequency extraction. Dispersion-compensated fiber, dispersion-shifted fiber, and standard single-mode fiber have been used respectively to generate optical pulses at variable repetition rates.

Stitching-error reduction in gratings by shot-shifted electron-beam lithography

NASA Technical Reports Server (NTRS)

Dougherty, D. J.; Muller, R. E.; Maker, P. D.; Forouhar, S.

2001-01-01

Calculations of the grating spatial-frequency spectrum and the filtering properties of multiple-pass electron-beam writing demonstrate a tradeoff between stitching-error suppression and minimum pitch separation. High-resolution measurements of optical-diffraction patterns show a 25-dB reduction in stitching-error side modes.

Improved MIMO radar GMTI via cyclic-shift transmission of orthogonal frequency division signals

NASA Astrophysics Data System (ADS)

Li, Fuyou; He, Feng; Dong, Zhen; Wu, Manqing

2018-05-01

Minimum detectable velocity (MDV) and maximum detectable velocity are both important in ground moving target indication (GMTI) systems. Smaller MDV can be achieved by longer baseline via multiple-input multiple-output (MIMO) radar. Maximum detectable velocity is decided by blind velocities associated with carrier frequencies, and blind velocities can be mitigated by orthogonal frequency division signals. However, the scattering echoes from different carrier frequencies are independent, which is not good for improving MDV performance. An improved cyclic-shift transmission is applied in MIMO GMTI system in this paper. MDV performance is improved due to the longer baseline, and maximum detectable velocity performance is improved due to the mitigation of blind velocities via multiple carrier frequencies. The signal model for this mode is established, the principle of mitigating blind velocities with orthogonal frequency division signals is presented; the performance of different MIMO GMTI waveforms is analysed; and the performance of different array configurations is analysed. Simulation results by space-time-frequency adaptive processing proves that our proposed method is a valid way to improve GMTI performance.

Fast Eigensolver for Computing 3D Earth's Normal Modes

NASA Astrophysics Data System (ADS)

Shi, J.; De Hoop, M. V.; Li, R.; Xi, Y.; Saad, Y.

2017-12-01

We present a novel parallel computational approach to compute Earth's normal modes. We discretize Earth via an unstructured tetrahedral mesh and apply the continuous Galerkin finite element method to the elasto-gravitational system. To resolve the eigenvalue pollution issue, following the analysis separating the seismic point spectrum, we utilize explicitly a representation of the displacement for describing the oscillations of the non-seismic modes in the fluid outer core. Effectively, we separate out the essential spectrum which is naturally related to the Brunt-Väisälä frequency. We introduce two Lanczos approaches with polynomial and rational filtering for solving this generalized eigenvalue problem in prescribed intervals. The polynomial filtering technique only accesses the matrix pair through matrix-vector products and is an ideal candidate for solving three-dimensional large-scale eigenvalue problems. The matrix-free scheme allows us to deal with fluid separation and self-gravitation in an efficient way, while the standard shift-and-invert method typically needs an explicit shifted matrix and its factorization. The rational filtering method converges much faster than the standard shift-and-invert procedure when computing all the eigenvalues inside an interval. Both two Lanczos approaches solve for the internal eigenvalues extremely accurately, comparing with the standard eigensolver. In our computational experiments, we compare our results with the radial earth model benchmark, and visualize the normal modes using vector plots to illustrate the properties of the displacements in different modes.

Research Investigation Directed Toward Extending the Useful Range of the Electromagnetic Spectrum [Special Technical Report]: Further Aspects of the Theory of the Maser.

DOE R&D Accomplishments Database

Shimoda, K.; Wang, T. C.; Townes, C. H.

1956-03-01

The theory of the molecular transitions which are induced by the microwave field in a maser and the effects of various design parameters are examined in detail. It is shown that the theoretical minimum detectable beam intensity when the maser is used as a spectrometer for the 3-3 line of ammonia is about 10{sup 9} molecules/sec under typical experimental conditions. Various systematic frequency shifts and random frequency fluctuations of the maser oscillator are discussed and evaluated. The most prominent of the former are the "frequency-pulling" effect which arises from detuning of the cavity and the Doppler shift due to the asymmetrical coupling of the beam with the two travelling wave components of the standing waves which are set up in the cavity. These two effects may produce fractional shifts as large as one part in 10{sup 9}. If adequate precautions are taken, however, they can be reduced to one part in 10{sup 10} or possibly less. The random fluctuations are shown to be of the order of one part in 10{sup 13} under typical operating conditions. For molecular beams in which the electric-dipole transition is used the TM{sub 010} mode is usually the most suitable for the maser which atomic beams in which magnetic transitions are utilized, the TE{sub 011} mode is to be preferred.

Design and engineering of organic molecules for customizable Terahertz tags

NASA Astrophysics Data System (ADS)

Ray, Shaumik; Dash, Jyotirmayee; Nallappan, Kathirvel; Kaware, Vaibhav; Basutkar, Nitin; Ambade, Ashootosh; Joshi, Kavita; Pesala, Bala

2014-03-01

Terahertz (THz) frequency band lies between the microwave and infrared region of the electromagnetic spectrum. Molecules having strong resonances in this frequency range are ideal for realizing "Terahertz tags" which can be easily incorporated into various materials. THz spectroscopy of molecules, especially at frequencies below 10 THz, provides valuable information on the low frequency vibrational modes, viz. intermolecular vibrational modes, hydrogen bond stretching, torsional vibrations in several chemical and biological compounds. So far there have been very few attempts to engineer molecules which can demonstrate customizable resonances in the THz frequency region. In this paper, Diamidopyridine (DAP) based molecules are used as a model system to demonstrate engineering of THz resonances (< 10 THz) by fine-tuning the molecular mass and bond strengths. Density Functional Theory (DFT) simulations have been carried out to explain the origin of THz resonances and factors contributing to the shift in resonances due to the addition of various functional groups. The design approach presented here can be easily extended to engineer various organic molecules suitable for THz tags application.

Rotational level-dependent collisional broadening and line shift of the A2Sigma(+)-X2Pi (1,0) band of OH in hydrogen-air combustion gases

NASA Technical Reports Server (NTRS)

Kessler, W. J.; Allen, M. G.; Davis, S. J.

1993-01-01

Measurements of the collisional broadening and line shift of the (1,0) band of the A2Sigma(+)-X2Pi system of OH are reported in atmospheric pressure hydrogen-air combustion gases. The measurements were made using a single-mode, narrow linewidth, frequency-doubled ring dye laser operating near 283 nm. The OH was generated in the combustion gases of a flat flame H2-air burner. Collisional broadening parameters for equilibrium mixtures of H2, O2, H2O, and N2 were obtained spanning a range of fuel/air equivalence ratios from 0.6 to 1.6 and temperatures from 1500 to 2050 K. Measurements were obtained spanning rotational quantum numbers from 4.5 to 16.5. The collision induced frequency shift was determined to be 0.1 that of the collisional broadening.

Reason and Condition for Mode Kissing in MASW Method

NASA Astrophysics Data System (ADS)

Gao, Lingli; Xia, Jianghai; Pan, Yudi; Xu, Yixian

2016-05-01

Identifying correct modes of surface waves and picking accurate phase velocities are critical for obtaining an accurate S-wave velocity in MASW method. In most cases, inversion is easily conducted by picking the dispersion curves corresponding to different surface-wave modes individually. Neighboring surface-wave modes, however, will nearly meet (kiss) at some frequencies for some models. Around the frequencies, they have very close roots and energy peak shifts from one mode to another. At current dispersion image resolution, it is difficult to distinguish different modes when mode-kissing occurs, which is commonly seen in near-surface earth models. It will cause mode misidentification, and as a result, lead to a larger overestimation of S-wave velocity and error on depth. We newly defined two mode types based on the characteristics of the vertical eigendisplacements calculated by generalized reflection and transmission coefficient method. Rayleigh-wave mode near the kissing points (osculation points) change its type, that is to say, one Rayleigh-wave mode will contain different mode types. This mode type conversion will cause the mode-kissing phenomenon in dispersion images. Numerical tests indicate that the mode-kissing phenomenon is model dependent and that the existence of strong S-wave velocity contrasts increases the possibility of mode-kissing. The real-world data shows mode misidentification caused by mode-kissing phenomenon will result in higher S-wave velocity of bedrock. It reminds us to pay attention to this phenomenon when some of the underground information is known.

Whispering gallery resonators for optical sensing

NASA Astrophysics Data System (ADS)

Madugani, Ramgopal; Kasumie, Sho; Yang, Yong; Ward, Jonathan; Lei, Fuchuan; Nic Chormaic, Síle

2017-04-01

In recent years, whispering gallery mode devices have extended their functionality across a number of research fields from photonics to sensing applications. Here, we will discuss environmental sensing applications, such as pressure, flow, and temperature using ultrahigh Q-factor microspheres fabricated from ultrathin optical fiber and microbubbles fabricated from pretapered glass capillary. We will discuss device fabrication and the different types of sensing that can be pursued using such systems. Finally, we will introduce the concept of using cavity ring-up spectroscopy to perform dispersive transient sensing, whereby a perturbation to the environment leads to a frequency mode shift, and dissipative transient sensing, which can lead to broadening of the mode, in a whispering gallery mode resonator.

High frequency resonant waveguide grating imager for assessing drug-induced cardiotoxicity

NASA Astrophysics Data System (ADS)

Ferrie, Ann M.; Wu, Qi; Deichmann, Oberon D.; Fang, Ye

2014-05-01

We report a high-frequency resonant waveguide grating imager for assessing compound-induced cardiotoxicity. The imager sweeps the wavelength range from 823 nm to 838 nm every 3 s to identify and monitor compound-induced shifts in resonance wavelength and then switch to the intensity-imaging mode to detect the beating rhythm and proarrhythmic effects of compounds on induced pluripotent stem cell-derived cardiomyocytes. This opens possibility to study cardiovascular biology and compound-induced cardiotoxicity.

Effect of oxygen vacancies and strain on the phonon spectrum of HfO2 thin films

NASA Astrophysics Data System (ADS)

Gao, Lingyuan; Yalon, Eilam; Chew, Annabel R.; Deshmukh, Sanchit; Salleo, Alberto; Pop, Eric; Demkov, Alexander A.

2017-06-01

The effect of strain and oxygen deficiency on the Raman spectrum of monoclinic HfO2 is investigated theoretically using first-principles calculations. 1% in-plane compressive strain applied to a and c axes is found to blue shift the phonon frequencies, while 1% tensile strain does the opposite. The simulations are compared, and good agreement is found with the experimental results of Raman frequencies greater than 110 cm-1 for 50 nm HfO2 thin films. Several Raman modes measured below 110 cm-1 and previously assigned to HfO2 are found to be rotational modes of gases present in air ambient (nitrogen and oxygen). However, localized vibrational modes introduced by threefold-coordinated oxygen (O3) vacancies are identified at 96.4 cm-1 computationally. These results are important for a deeper understanding of vibrational modes in HfO2, which has technological applications in transistors and particularly in resistive random-access memory whose operation relies on oxygen-deficient HfOx.

High-pressure, high-temperature Raman spectroscopy of Ca 2GeO 4 (olivine form): some insights on anharmonicity

NASA Astrophysics Data System (ADS)

Gillet, Philippe; Guyot, Francois; Malezieux, Jean-Marie

1989-12-01

High pressure (up to 2.7 GPa) and high temperature (up to 1000 K) Raman spectra of Ca 2GeO 4 (olivine form) have been recorded. Measurements of the pressure- and temperature-induced frequency shifts of 14 modes have been performed. The classical mode Gruneisen parameter and a corresponding parameter related to temperature variation are calculated. For the high frequency modes (GeO stretching) we calculate these parameters with local tetrahedral elastic parameters. From these parameters anharmonic parameters are calculated for each Raman active mode. The effect of anharmonicity on the specific heat is calculated and compared with calorimetric data. Taking anharmonicity into account leads to a departure from the Dulong and Petit limit of the order of 2% at 1000 K and more than 6% at 2000 K, in good accord with experimental data. We propose that, eventually, such effects might be significant in the calculations of thermodynamic properties of mantle silicates like forsterite and its polymorphs.

Demonstration of highly efficient forward stimulated Brillouin scattering in partly suspended silicon nanowire racetrack resonators

NASA Astrophysics Data System (ADS)

Zhang, Ruiwen; Sun, Junqiang; Chen, Guodong; Cheng, Ming; Jiang, Jialin

2017-07-01

We demonstrate the forward stimulated Brillouin scattering (FSBS) in a partly suspended silicon nanowire racetrack resonator. To realize the tight confinement of the transverse acoustic modes in the nanoscale silicon core, the racetrack resonator is supported by the tiny pillar. The Brillouin amplification of 2.25 dB is achieved with the resonator radius of 100 μm under a low-power pump laser of 8 mW. The influences of the waveguide width and the top width of the tiny pillar on the Brillouin frequency shift and Brillouin gain are presented and analyzed. The Brillouin frequency shift is conveniently manipulated by the changes in waveguide widths. Our proposed approach furnishes an alternative towards harnessing FSBS in integrated photonic circuits.

H irradiation effects on the GaAs-like Raman modes in GaAs1-xNx/GaAs1-xNx:H planar heterostructures

NASA Astrophysics Data System (ADS)

Giulotto, E.; Geddo, M.; Patrini, M.; Guizzetti, G.; Felici, M.; Capizzi, M.; Polimeni, A.; Martelli, F.; Rubini, S.

2014-12-01

The GaAs-like longitudinal optical phonon frequency in two hydrogenated GaAs1-xNx/GaAs1-xNx:H microwire heterostructures—with similar N concentration, but different H dose and implantation conditions—has been investigated by micro-Raman mapping. In the case of GaAs0.991N0.009 wires embedded in barriers where GaAs-like properties are recovered through H irradiation, the phonon frequency in the barriers undergoes a blue shift with respect to the wires. In GaAs0.992N0.008 wires embedded in less hydrogenated barriers, the phonon frequency exhibits an opposite behavior (red shift). Strain, disorder, phonon localization effects induced by H-irradiation on the GaAs-like phonon frequency are discussed and related to different types of N-H complexes formed in the hydrogenated barriers. It is shown that the red (blue) character of the frequency shift is related to the dominant N-2H (N-3H) type of complexes. Moreover, for specific experimental conditions, an all-optical determination of the uniaxial strain field is obtained. This may improve the design of recently presented devices that exploit the correlation between uniaxial stress and the degree of polarization of photoluminescence.

Comparison of Frequencies and Rotational Splittings of Solar Acoustic Modes of Low Angular Degree from Simultaneous MDI and GOLF Observations

NASA Astrophysics Data System (ADS)

Bertello, L.; Henney, C. J.; Ulrich, R. K.; Varadi, F.; Kosovichev, A. G.; Scherrer, P. H.; Cortés, T. Roca; Thiery, S.; Boumier, P.; Gabriel, A. H.; Turck-Chièze, S.

2000-06-01

During the years 1996 through 1998 the Michelson Doppler Imager (MDI) and the Global Oscillations at Low Frequency (GOLF) experiments on the Solar and Heliospheric Observatory (SOHO) mission have provided unique and nearly uninterrupted sequences of helioseismic observations. This paper describes the analysis carried out on power spectra from 759 days of calibrated disk-averaged velocity signals provided by these two experiments. The period investigated in this work is from 1996 May 25 to 1998 June 22. We report the results of frequency determination of low-degree (l<=3) acoustic modes in the frequency range between 1.4 mHz and 3.7 mHz. Rotational splittings are also measured for nonradial modes up to 3.0 mHz. The power spectrum estimation of the signals is performed using classical Fourier analysis and the line-profile parameters of the modes are determined by means of a maximum likelihood method. All parameters have been estimated using both symmetrical and asymmetrical line profile-fitting formula. The line asymmetry parameter of all modes with frequency higher than 2.0 mHz is systematically negative and independent of l. This result is consistent with the fact that both MDI and GOLF data sets investigated in this paper are predominantly velocity signals, in agreement with previous results. A comparison of the results between the symmetric and asymmetric fits shows that there is a systematic shift in the frequencies for modes above 2.0 mHz. Below this frequency, the line width of the modes is very small and the time base of the data does not provide enough statistics to reveal an asymmetry. In general, the results show that frequency and rotational splitting values obtained from both the MDI and GOLF signals are in excellent agreement, and no significant differences exist between the two data sets within the accuracy of the measurements. Our results are consistent with a uniform rotation of the solar core at the rate of about 435 nHz and show only very small deviations of the core structure from the standard solar model.

Identifying the first folded alkylbenzene via ultraviolet, infrared, and Raman spectroscopy of pentylbenzene through decylbenzene

DOE PAGES

Hewett, Daniel M.; Bocklitz, Sebastian; Tabor, Daniel P.; ...

2017-05-23

The conformational preferences of pentyl- through decylbenzene are studied under jet-cooled conditions in the gas phase. Laser-induced fluorescence excitation spectra, fluorescence-dip infrared spectra in the alkyl CH stretch region, and Raman spectra are combined to provide assignments for the observed conformers. Density functional theory calculations at the B3LYP-D3BJ/def2TZVP level of theory provide relative energies and normal mode vibrations that serve as inputs for an anharmonic local mode theory introduced in earlier work on alkylbenzenes with n = 2–4. This model explicitly includes anharmonic mixing of the CH stretch modes with the overtones of scissors/bend modes of the CH 2 andmore » CH 3 groups in the alkyl chain, and is used to assign and interpret the single-conformation IR spectra. In octylbenzene, a pair of LIF transitions shifted -92 and -78 cm -1 from the all-trans electronic origin have unique alkyl CH stretch transitions that are fit by the local model to a g1g3g4 conformation in which the alkyl chain folds back over the aromatic ring π cloud. Its calculated energy is only 1.0 kJ mol -1 above the all-trans global minimum. This fold is at an alkyl chain length less than half that of the pure alkanes (n = 18), consistent with a smaller energy cost for the g1 dihedral and the increased dispersive interaction of the chain with the π cloud. Local site frequencies for the entire set of conformers from the local mode model show ‘edge effects’ that raise the site frequencies of CH 2(1) and CH 2(2) due to the phenyl ring and CH 2(n - 1) due to the methyl group. The g1g3g4 conformer also shows local sites shifted up in frequency at CH 2(3) and CH 2(6) due to interaction with the π cloud.« less

Search for supersolidity in solid 4He using multiple-mode torsional oscillators

PubMed Central

Eyal, Anna; Mi, Xiao; Talanov, Artem V.; Reppy, John D.

2016-01-01

In 2004, Kim and Chan (KC) reported a decrease in the period of torsional oscillators (TO) containing samples of solid 4He, as the temperature was lowered below 0.2 K [Kim E, Chan MHW (2004) Science 305(5692):1941–1944]. These unexpected results constituted the first experimental evidence that the long-predicted supersolid state of solid 4He may exist in nature. The KC results were quickly confirmed in a number of other laboratories and created great excitement in the low-temperature condensed-matter community. Since that time, however, it has become clear that the period shifts seen in the early experiments can in large part be explained by an increase in the shear modulus of the 4He solid identified by Day and Beamish [Day J, Beamish J (2007) Nature 450(7171):853–856]. Using multiple-frequency torsional oscillators, we can separate frequency-dependent period shifts arising from changes in the elastic properties of the solid 4He from possible supersolid signals, which are expected to be independent of frequency. We find in our measurements that as the temperature is lowered below 0.2 K, a clear frequency-dependent contribution to the period shift arising from changes in the 4He elastic properties is always present. For all of the cells reported in this paper, however, there is always an additional small frequency-independent contribution to the total period shift, such as would be expected in the case of a transition to a supersolid state. PMID:27222579

1THz synchronous tuning of two optical synthesizers

NASA Astrophysics Data System (ADS)

Neuhaus, Rudolf; Rohde, Felix; Benkler, Erik; Puppe, Thomas; Raab, Christoph; Unterreitmayer, Reinhard; Zach, Armin; Telle, Harald R.; Stuhler, Jürgen

2016-04-01

Single-frequency optical synthesizers (SFOS) provide an optical field with arbitrarily adjustable frequency and phase which is phase-coherently linked to a reference signal. Ideally, they combine the spectral resolution of narrow linewidth frequency stabilized lasers with the broad spectral coverage of frequency combs in a tunable fashion. In state-of-the-art SFOSs tuning across comb lines requires comb line order switching,1, 2 which imposes technical overhead with problems like forbidden frequency gaps or strong phase glitches. Conventional tunable lasers often tune over only tens of GHz before mode-hops occur. Here, we present a novel type of SFOSs, which relies on a serrodyne technique with conditional flyback,3 shifting the carrier frequency of the employed frequency comb without an intrusion into the comb generator. It utilizes a new continuously tunable diode laser that tunes mode-hop-free across the full gain spectrum of the integrated laser diode. We investigate the tuning behavior of two identical SFOSs that share a common reference, by comparing the phases of their output signals. Previously, we achieved phase-stable and cycle-slip free frequency tuning over 28.1 GHz with a maximum zero-to-peak phase deviation of 62 mrad4 when sharing a common comb generator. With the new continuously tunable lasers, the SFOSs tune synchronously across nearly 17800 comb lines (1 THz). The tuning range in this approach can be extended to the full bandwidth of the frequency comb and the 110 nm mode-hop-free tuning range of the diode laser.

Dynamics of Oscillating and Rotating Liquid Drop using Electrostatic Levitator

NASA Astrophysics Data System (ADS)

Matsumoto, Satoshi; Awazu, Shigeru; Abe, Yutaka; Watanabe, Tadashi; Nishinari, Katsuhiro; Yoda, Shinichi

2006-11-01

In order to understand the nonlinear behavior of liquid drop with oscillatory and/or rotational motions, an experimental study was performed. The electrostatic levitator was employed to achieve liquid drop formation on ground. A liquid drop with about 3 mm in diameter was levitated. The oscillation of mode n=2 along the vertical axis was induced by an external electrostatic force. The oscillatory motions were observed to clarify the nonlinearities of oscillatory behavior. A relationship between amplitude and frequency shift was made clear and the effect of frequency shift on amplitude agreed well with the theory. The frequency shift became larger with increasing the amplitude of oscillation. To confirm the nonlinear effects, we modeled the oscillation by employing the mass-spring-damper system included the nonlinear term. The result indicates that the large-amplitude oscillation includes the effect of nonlinear oscillation. The sound pressure was imposed to rotate the liquid drop along a vertical axis by using a pair of acoustic transducers. The drop transited to the two lobed shape due to centrifugal force when nondimensional angular velocity exceeded to 0.58.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rabello-Soares, M. Cristina; Bogart, Richard S.; Scherrer, Philip H., E-mail: cristina@fisica.ufmg.br

In order to quantify the influence of magnetic fields on acoustic mode parameters and flows in and around active regions, we analyze the differences in the parameters in magnetically quiet regions nearby an active region (which we call “nearby regions”), compared with those of quiet regions at the same disk locations for which there are no neighboring active regions. We also compare the mode parameters in active regions with those in comparably located quiet regions. Our analysis is based on ring-diagram analysis of all active regions observed by the Helioseismic and Magnetic Imager (HMI) during almost five years. We findmore » that the frequency at which the mode amplitude changes from attenuation to amplification in the quiet nearby regions is around 4.2 mHz, in contrast to the active regions, for which it is about 5.1 mHz. This amplitude enhacement (the “acoustic halo effect”) is as large as that observed in the active regions, and has a very weak dependence on the wave propagation direction. The mode energy difference in nearby regions also changes from a deficit to an excess at around 4.2 mHz, but averages to zero over all modes. The frequency difference in nearby regions increases with increasing frequency until a point at which the frequency shifts turn over sharply, as in active regions. However, this turnover occurs around 4.9 mHz, which is significantly below the acoustic cutoff frequency. Inverting the horizontal flow parameters in the direction of the neigboring active regions, we find flows that are consistent with a model of the thermal energy flow being blocked directly below the active region.« less

Complex phase error and motion estimation in synthetic aperture radar imaging

NASA Astrophysics Data System (ADS)

Soumekh, M.; Yang, H.

1991-06-01

Attention is given to a SAR wave equation-based system model that accurately represents the interaction of the impinging radar signal with the target to be imaged. The model is used to estimate the complex phase error across the synthesized aperture from the measured corrupted SAR data by combining the two wave equation models governing the collected SAR data at two temporal frequencies of the radar signal. The SAR system model shows that the motion of an object in a static scene results in coupled Doppler shifts in both the temporal frequency domain and the spatial frequency domain of the synthetic aperture. The velocity of the moving object is estimated through these two Doppler shifts. It is shown that once the dynamic target's velocity is known, its reconstruction can be formulated via a squint-mode SAR geometry with parameters that depend upon the dynamic target's velocity.

A Spectroscopic and Theoretical Study of Weak Intramolecular OH\\cdots π Interactions in Allyl Carbinol and Methallyl Carbinol

NASA Astrophysics Data System (ADS)

Schroeder, Sidsel D.; Mackeprang, Kasper; Kjaergaard, Henrik G.

2013-06-01

The weak intramolecular OH\\cdots π interactions in allyl carbinol and methallyl carbinol have been studied using a combination of NIR spectroscopy and theory. The third OH-stretching overtone region of vapor phase allyl carbinol and methallyl carbinol have been recorded with intracavity laser photoacoustic spectroscopy to study the effect of an enhanced OH\\cdots π interaction in methallyl carbinol arising from the electron donating methyl group. Local mode calculations were employed to assign the observed bands. The OH-stretching transition frequency of methallyl carbinol was observed to be red shifted relative to the OH-stretching transition frequency of allyl carbinol. A red shift of the transition frequency is in this context normally interpreted as a signature of hydrogen bonding. Whether the OH\\cdots π interaction can be categorized as a hydrogen bond will be discussed in this talk.

The tension sensor of Photonic Crystal Fiber based on core-offset splicing and waist-enlarged fiber taper

NASA Astrophysics Data System (ADS)

Fu, Guangwei; Li, Qifeng; Li, Yunpu; Yang, Jiandong; Fu, Xinghu; Bi, Weihong; Li, Yanjun

2016-10-01

A tension sensor of Photonic Crystal Fiber(PCF) is presented based on core-offset splicing and waist-enlarged fiber taper. The tension response characteristics of the sensor are studied experimentally. To analyzing the modal interference, many samples with different PCF lengths between the two splicing areas, different core-offset distances and different waist-enlarged fiber taper diameters are fabricated and tested. When the tension range is 0 to 4000μɛ, the results show that the spectrum is blue shift with the increasing of the axial tension. The sensitivity is-2.1 pm/μɛ. The experimental results show that the tension sensitivity can be not influenced by the PCF lengths, the core-offset distances.The waist-enlarged fiber taper diameters and the tension sensor is very sensitive to axial tension and the relationship between the wavelength shift and tension is linearity. To determine the number of the interfering modes, the transmission spectra of these sensor is transformed by the fast fourier transform (FFT) method. There are several peaks in the spatial frequency spectra at these sensors. Only one cladding mode is dominantly excited, while the other cladding modes are weak. The spatial frequency is proportional to the differential mode group index. Compared with the traditional fiber sensor, this sensor has some advantages including the easily fabricated, simple structure and high sensitivity. It can be used in industrial production, building monitoring, aerospace and other fields.

Characterizing Chemical Similarity with Vibrational Spectroscopy: New Insights into the Substituent Effects in Monosubstituted Benzenes.

PubMed

Tao, Yunwen; Zou, Wenli; Cremer, Dieter; Kraka, Elfi

2017-10-26

A novel approach is presented to assess chemical similarity based the local vibrational mode analysis developed by Konkoli and Cremer. The local mode frequency shifts are introduced as similarity descriptors that are sensitive to any electronic structure change. In this work, 59 different monosubstituted benzenes are compared. For a subset of 43 compounds, for which experimental data was available, the ortho-/para- and meta-directing effect in electrophilic aromatic substitution reactions could be correctly reproduced, proving the robustness of the new similarity index. For the remaining 16 compounds, the directing effect was predicted. The new approach is broadly applicable to all compounds for which either experimental or calculated vibrational frequency information is available.

Instantaneous lineshape analysis of Fourier domain mode-locked lasers.

PubMed

Todor, Sebastian; Biedermann, Benjamin; Wieser, Wolfgang; Huber, Robert; Jirauschek, Christian

2011-04-25

We present a theoretical and experimental analysis of the instantaneous lineshape of Fourier domain mode-locked (FDML) lasers, yielding good agreement. The simulations are performed employing a recently introduced model for FDML operation. Linewidths around 10 GHz are found, which is significantly below the sweep filter bandwidth. The effect of detuning between the sweep filter drive frequency and cavity roundtrip time is studied revealing features that cannot be resolved in the experiment, and shifting of the instantaneous power spectrum against the sweep filter center frequency is analyzed. We show that, in contrast to most other semiconductor based lasers, the instantaneous linewidth is governed neither by external noise sources nor by amplified spontaneous emission, but it is directly determined by the complex FDML dynamics.

Faithful state transfer between two-level systems via an actively cooled finite-temperature cavity

NASA Astrophysics Data System (ADS)

Sárkány, Lőrinc; Fortágh, József; Petrosyan, David

2018-03-01

We consider state transfer between two qubits—effective two-level systems represented by Rydberg atoms—via a common mode of a microwave cavity at finite temperature. We find that when both qubits have the same coupling strength to the cavity field, at large enough detuning from the cavity mode frequency, quantum interference between the transition paths makes the swap of the excitation between the qubits largely insensitive to the number of thermal photons in the cavity. When, however, the coupling strengths are different, the photon-number-dependent differential Stark shift of the transition frequencies precludes efficient transfer. Nevertheless, using an auxiliary cooling system to continuously extract the cavity photons, we can still achieve a high-fidelity state transfer between the qubits.

Experimental and theoretical quantum chemical investigations of 8-hydroxy-5-nitroquinoline.

PubMed

Arjunan, V; Balamourougane, P S; Kalaivani, M; Raj, Arushma; Mohan, S

2012-10-01

The FT-IR and FT-Raman spectra of 8-hydroxy-5-nitroquinoline have been recorded in the regions 4000-400 and 4000-100 cm(-1), respectively. The spectra were interpreted in terms of fundamentals modes, combination and overtone bands. The normal coordinate analysis was carried out to confirm the precision of the assignments. The structure of the compound was optimised and the structural characteristics were determined by density functional theory (DFT) using B3LYP method with 6-31G(**), 6-311++G(**) and cc-pVDZ basis sets. The vibrational frequencies were calculated in all these methods and were compared with the experimental frequencies which yield good agreement between observed and calculated frequencies. The infrared and Raman spectra were also predicted from the calculated intensities. (1)H and (13)C NMR spectra were recorded and (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecule were calculated using the gauge independent atomic orbital (GIAO) method. UV-Visible spectrum of the compound was recorded and the electronic properties HOMO and LUMO energies were measured by time-dependent TD-DFT approach. The influences of the nitro and hydroxy groups on the skeletal modes and on the proton chemical shifts have been investigated. Copyright © 2012 Elsevier B.V. All rights reserved.

A delicate case of unidirectional proton transfer from water to an aromatic heterocyclic anion.

PubMed

Biswas, Sohag; Mallik, Bhabani S

2016-11-21

We present the characteristic proton transfer process from water to the pyrazole anion, infrared signatures of hydroxyl groups and the free energy profile of the process in aqueous solution combining first principles simulations, wavelet analysis and metadynamics. Our results show that the presence of minimum three water molecules in the gas phase cluster with a particular arrangement is sufficient to facilitate the proton transfer process from water to the anion. The overall reaction is very rapid in aqueous solution, and the free energy barrier for this process is found to be 4.2 kcal mol -1 . One of the earlier reported fundamental reasons for the transfer of proton from water to the anion is the change in the acidity of OH groups surrounding the anion. We have correlated the stretching frequencies of the surrounding OH groups with this acidity. We find that the development of less energetic vibrational states, and the OH mode having lowest average stretching frequency contains the most acidic proton. A large frequency shift of the OH mode belonging to one of the surrounding water molecules is observed during the transfer of proton from water to the anion; this shift is due to the change in acidity of the adjacent hydroxyl groups in the vicinity of the anion.

Dynamics of an [Fe4S4(SPh)4]2- cluster explored via IR, Raman, and nuclear resonance vibrational spectroscopy (NRVS)-analysis using 36S substitution, DFT calculations, and empirical force fields.

PubMed

Xiao, Yuming; Koutmos, Markos; Case, David A; Coucouvanis, Dimitri; Wang, Hongxin; Cramer, Stephen P

2006-05-14

We have used four vibrational spectroscopies--FT-IR, FT-Raman, resonance Raman, and 57Fe nuclear resonance vibrational spectroscopy (NRVS)--to study the normal modes of the Fe-S cluster in [(n-Bu)4N]2[Fe4S4(SPh)4]. This [Fe4S4(SR)4]2- complex serves as a model for the clusters in 4Fe ferredoxins and high-potential iron proteins (HiPIPs). The IR spectra exhibited differences above and below the 243 K phase transition. Significant shifts with 36S substitution into the bridging S positions were also observed. The NRVS results were in good agreement with the low temperature data from the conventional spectroscopies. The NRVS spectra were interpreted by normal mode analysis using optimized Urey-Bradley force fields (UBFF) as well as from DFT theory. For the UBFF calculations, the parameters were refined by comparing calculated and observed NRVS frequencies and intensities. The frequency shifts after 36S substitution were used as an additional constraint. A D 2d symmetry Fe4S4S'4 model could explain most of the observed frequencies, but a better match to the observed intensities was obtained when the ligand aromatic rings were included for a D 2d Fe4S4(SPh)4 model. The best results were obtained using the low temperature structure without symmetry constraints. In addition to stretching and bending vibrations, low frequency modes between approximately 50 and 100 cm(-1) were observed. These modes, which have not been seen before, are interpreted as twisting motions with opposing sides of the cube rotating in opposite directions. In contrast with a recent paper on a related Fe4S4 cluster, we find no need to assign a large fraction of the low frequency NRVS intensity to 'rotational lattice modes'. We also reassign the 430 cm(-1) band as primarily an elongation of the thiophenolate ring, with approximately 10% terminal Fe-S stretch character. This study illustrates the benefits of combining NRVS with conventional Raman and IR analysis for characterization of Fe-S centers. DFT theory is shown to provide remarkable agreement with the experimental NRVS data. These results provide a reference point for the analysis of more complex Fe-S clusters in proteins.

Modulation characteristics of a high-power semiconductor Master Oscillator Power Amplifier (MOPA)

NASA Technical Reports Server (NTRS)

Cornwell, Donald Mitchell, Jr.

1992-01-01

A semiconductor master oscillator-power amplifier was demonstrated using an anti-reflection (AR) coated broad area laser as the amplifier. Under CW operation, diffraction-limited single-longitudinal-mode powers up to 340 mW were demonstrated. The characteristics of the far-field pattern were measured and compared to a two-dimensional reflective Fabry-Perot amplifier model of the device. The MOPA configuration was modulated by the master oscillator. Prior to injection into the amplifier, the amplitude and frequency modulation properties of the master oscillator were characterized. The frequency response of the MOPA configuration was characterized for an AM/FM modulated injection beam, and was found to be a function of the frequency detuning between the master oscillator and the resonant amplifier. A shift in the phase was also observed as a function of frequency detuning; this phase shift is attributed to the optical phase shift imparted to a wave reflected from a Fabry-Perot cavity. Square-wave optical pulses were generated at 10 MHz and 250 MHz with diffraction-limited peak powers of 200 mW and 250 mW. The peak power for a given modulation frequency is found to be limited by the injected power and the FM modulation at that frequency. The modulation results make the MOPA attractive for use as a transmitter source in applications such as free-space communications and ranging/altimetry.

High-frequency solitons in media with induced scattering from damped low-frequency waves with nonuniform dispersion and nonlinearity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aseeva, N. V., E-mail: vtyutin@hse.ru; Gromov, E. M.; Tyutin, V. V.

2015-12-15

The dynamics of high-frequency field solitons is considered using the extended nonhomogeneous nonlinear Schrödinger equation with induced scattering from damped low-frequency waves (pseudoinduced scattering). This scattering is a 3D analog of the stimulated Raman scattering from temporal spatially homogeneous damped low-frequency modes, which is well known in optics. Spatial inhomogeneities of secondorder linear dispersion and cubic nonlinearity are also taken into account. It is shown that the shift in the 3D spectrum of soliton wavenumbers toward the short-wavelength region is due to nonlinearity increasing in coordinate and to decreasing dispersion. Analytic results are confirmed by numerical calculations.

Investigation of a metallic photonic crystal high power microwave mode converter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Dong, E-mail: mr20001@sina.com; Qin, Fen; Xu, Sha

2015-02-15

It is demonstrated that an L band metallic photonic crystal TEM-TE{sub 11} mode converter is suitable for narrow band high power microwave application. The proposed mode converter is realized by partially filling metallic photonic crystals along azimuthal direction in a coaxial transmission line for phase-shifting. A three rows structure is designed and simulated by commercial software CST Microwave Studio. Simulation results show that its conversion efficiency is 99% at the center frequency 1.58 GHz. Over the frequency range of 1.56-1.625 GHz, the conversion efficiency exceeds 90 %, with a corresponding bandwidth of 4.1 %. This mode converter has a gigawattmore » level power handling capability which is suitable for narrow band high power microwave application. Using magnetically insulated transmission line oscillator(MILO) as a high power microwave source, particle-in-cell simulation is carried out to test the performance of the mode converter. The expected TE{sub 11} mode microwave output is obtained and the MILO works well. Mode conversion performance of the converter is tested by far-field measurement method. And the experimental result confirms the validity of our design. Then, high power microwave experiment is carried out on a Marx-driven Blumlein water line pulsed power accelerator. Microwave frequency, radiated pattern and power are measured in the far-field region and the results agree well with simulation results. The experiment also reveals that no microwave breakdown or pulse shortening took place in the experimental setup.« less

NONLINEAR AND FIBER OPTICS: Influence of nonlinearity of the parameters of guided modes in fiber waveguides

NASA Astrophysics Data System (ADS)

Goncharenko, I. A.

1990-04-01

The shift formula method is used to obtain analytic expressions which provide estimates of the influence of nonlinearity on the parameters of fiber waveguide modes. Depending on the sign of the nonlinear susceptibility of the waveguide core, the nonlinearity can improve or impair (right down to complete loss) the waveguiding properties of fibers. The optical power at which a fiber loses its guiding properties is constant far from the cutoff, but rises steeply near the critical cutoff frequency. The nonlinearity can be used to vary the zero dispersion wavelength and the range of single-mode operation of a fiber waveguide.

On the dispersion management of fluorite whispering-gallery mode resonators for Kerr optical frequency comb generation in the telecom and mid-infrared range.

PubMed

Lin, Guoping; Chembo, Yanne K

2015-01-26

Optical whispering gallery mode (WGM) resonators have been very attracting platforms for versatile Kerr frequency comb generations. We report a systematic study on the material dispersion of various optical materials that are capable of supporting quality factors above 10⁹. Using an analytical approximation of WGM resonant frequencies in disk resonators, we investigate the effect of the geometry and transverse mode order on the total group-velocity dispersion (GVD). We demonstrate that the major radii and the radial mode indices play an important role in tailoring the GVD of WGM resonators. In particular, our study shows that in WGM disk-resonators, the polar families of modes have very similar GVD, while the radial families of modes feature dispersion values that can differ by up to several orders of magnitude. The effect of these giant dispersion shifts are experimentally evidenced in Kerr comb generation with magnesium fluoride. From a more general perspective, this critical feature enables to push the zero-dispersion wavelength of fluorite crystals towards the mid-infrared (mid-IR) range, thereby allowing for efficient Kerr comb generation in that spectral range. We show that barium fluoride is the most interesting crystal in this regard, due to its zero dispersion wavelength (ZDW) at 1.93 μm and an optimal dispersion profile in the mid-IR regime. We expect our results to facilitate the design of different platforms for Kerr frequency comb generations in both telecommunication and mid-IR spectral ranges.

Frequency Control: Proceedings of the 40th Annual Symposium on held in Philadelphia, Pennsylvania on 28-30 May 1986

DTIC Science & Technology

1986-05-30

nonuniform and in part not specified. The actual values of the calculable quantities listed in TABLE IV and obtained on the basis of 61 observations of...is zero. GROUND FOR Since there are no known data on frequency shifts of PPER ELECTRODE. WHEN USED crystals for such nonuniform fields and voltages...PROTECTED BY US COPYRIGHT’ distribution of motional activity. In practical IRE National Convention Record, Part 6, cases, the nonuniform mode shape

Normal vibrational modes of phospholipid bilayers observed by low-frequency Raman scattering

NASA Astrophysics Data System (ADS)

Surovtsev, N. V.; Dmitriev, A. A.; Dzuba, S. A.

2017-03-01

Low-frequency Raman spectra of multilamellar vesicles made either of 1-palmitoyl-2-oleoyl-s n -glycero-3-phosphocholine (POPC) or 1,2-dipalmitoyl-s n -glycero-3-phosphocholine (DPPC) have been studied in a wide temperature range. Below 0 ∘C two peaks are found at frequencies around 8-9 and 14 -17 c m -1 and attributed to the normal vibrational modes of the phospholipid bilayer, which are determined by the bilayer thickness and stiffness (elastic modulus). The spectral positions of the peaks depend on the temperature and the bilayer composition. It is suggested that the ratio of the intensities of the first and second peaks can serve as a measure of the interleaflet elastic coupling. The addition of cholesterol to the phospholipid bilayer leads to peak shift and broadening, which may be assigned to the composition heterogeneities commonly attributed to the lipid raft formation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gayner, Chhatrasal; Kar, Kamal K., E-mail: kamalkk@iitk.ac.in; Department of Mechanical Engineering, Advanced Nanoengineering Materials Laboratory, Indian Institute of Technology Kanpur, Kanpur 208016

Polycrystalline lead selenide (PbSe) doped with copper (Cu) and nickel (Ni) was prepared to understand its magnetic behaviour and Raman activity. The processing conditions, influence of dopants (magnetically active and non-active) and their respective compositions on the magnetic properties and Raman active mode were studied. A surprising/anomalous room temperature ferromagnetism (hysteresis loop) is noticed in bulk diamagnetic PbSe, which is found to be natural or inherent characteristic of material, and depends on the crystallite size, dopant, and developed strain due to dopant/defects. The magnetic susceptibility (−1.71 × 10{sup −4} emu/mol Oe) and saturated magnetic susceptibility (−2.74 × 10{sup −4} emu/mol Oe) are found tomore » be higher than the earlier reported value (diamagnetic: −1.0 × 10{sup −4} emu/mol Oe) in bulk PbSe. With increase of Cu concentration (2% to 10%) in PbSe, the saturated magnetic susceptibility decreases from −1.22 × 10{sup −4} to −0.85 × 10{sup −4} emu/mol Oe. Whereas for Ni dopant, the saturated magnetic susceptibility increases to −2.96 × 10{sup −4} emu/mol Oe at 2% Ni doped PbSe. But it further decreases with dopant concentration. In these doped PbSe, the shifting of longitudinal (LO) phonon mode was also studied by the Raman spectroscopy. The shifting of LO mode is found to be dopant dependent, and the frequency shift of LO mode is associated with the induced strain that created by the dopants and vacancies. This asymmetry in LO phonon mode (peak shift and shape) may be due to the intraband electronic transition of dopants. The variation in magnetic susceptibility and Raman shifts are sensitive to crystallite size, nature of dopant, concentration of dopants, and induced strain due to dopants.« less

Hydrogen bond strengthening between o-nitroaniline and formaldehyde in electronic excited states: A theoretical study

NASA Astrophysics Data System (ADS)

Yang, Juan; Li, An Yong

2018-06-01

To study the hydrogen bonds upon photoexcited, the time dependent density function method (TD DFT) was performed to investigate the excited state hydrogen bond properties of between o-nitroaniline (ONA) and formaldehyde (CH2O). The optimized structures of the complex and the monomers both in the ground state and the electronically excited states are calculated using DFT and TD DFT method respectively. Quantum chemical calculations of the electronic and vibrational absorption spectra are also carried out by TD DFT method at the different level. The complex ONA⋯CH2O forms the intramolecular hydrogen bond and intermolecular hydrogen bonds. Since the strength of hydrogen bonds can be measured by studying the vibrational absorption spectra of the characteristic groups on the hydrogen bonding acceptor and donor, it evidently confirms that the hydrogen bonds is strengthened in the S1/S2/T1 excited states upon photoexcitation. As a result, the hydrogen bonds cause that the CH stretch frequency of the proton donor CH2O has a blue shift, and the electron excitations leads to a frequency red shift of Ndbnd O and Nsbnd H stretch modes in the o-nitroaniline(ONA) and a small frequency blue shift of CH stretch mode in the formaldehyde(CH2O) in the S1 and S2 excited states. The excited states S1, S2 and T1 are locally excited states where only the ONA moiety is excited, but the CH2O moiety remains in its ground state.

Dual-comb coherent Raman spectroscopy with lasers of 1-GHz pulse repetition frequency.

PubMed

Mohler, Kathrin J; Bohn, Bernhard J; Yan, Ming; Mélen, Gwénaëlle; Hänsch, Theodor W; Picqué, Nathalie

2017-01-15

We extend the technique of multiplex coherent Raman spectroscopy with two femtosecond mode-locked lasers to oscillators of a pulse repetition frequency of 1 GHz. We demonstrate a spectra of liquids, which span 1100  cm^-1 of Raman shifts. At a resolution of 6  cm^-1, their measurement time may be as short as 5 μs for a refresh rate of 2 kHz. The waiting period between acquisitions is improved 10-fold compared to previous experiments with two lasers of 100-MHz repetition frequencies.

Exchange anisotropy pinning of a standing spin-wave mode

NASA Astrophysics Data System (ADS)

Magaraggia, R.; Kennewell, K.; Kostylev, M.; Stamps, R. L.; Ali, M.; Greig, D.; Hickey, B. J.; Marrows, C. H.

2011-02-01

Standing spin waves in a thin film are used as sensitive probes of interface pinning induced by an antiferromagnet through exchange anisotropy. Using coplanar waveguide ferromagnetic resonance, pinning of the lowest energy spin-wave thickness mode in Ni80Fe20/Ir25Mn75 exchange-biased bilayers was studied for a range of Ir25Mn75 thicknesses. We show that pinning of the standing mode can be used to amplify, relative to the fundamental resonance, frequency shifts associated with exchange bias. The shifts provide a unique “fingerprint” of the exchange bias and can be interpreted in terms of an effective ferromagnetic film thickness and ferromagnet-antiferromagnet interface anisotropy. Thermal effects are studied for ultrathin antiferromagnetic Ir25Mn75 thicknesses, and the onset of bias is correlated with changes in the pinning fields. The pinning strength magnitude is found to grow with cooling of the sample, while the effective ferromagnetic film thickness simultaneously decreases. These results suggest that exchange bias involves some deformation of magnetic order in the interface region.

The free oscillations of the earth excited by three strongest earthquakes of the past decade according to deformation observations

NASA Astrophysics Data System (ADS)

Milyukov, V. K.; Vinogradov, M. P.; Mironov, A. P.; Myasnikov, A. V.; Perelygin, N. A.

2015-03-01

Based on the deformation data provided by the Baksan laser interferometer-strainmeter measurements, the free oscillations of the Earth (FOE) excited by the three strongest earthquakes of the past decade are analyzed. These seismic events include the Great Sumatra-Andaman earthquake that occurred in 2004 in the Indian Ocean, the Mauli earthquake of 2010 in Chile, and the Great Tohoku earthquake of March 2011 in Japan. The frequency-time structure of the free oscillations is studied, and the pattern of interaction between the modes with close frequencies (cross-coupling effect) is explored. For each earthquake, the correspondence of the observed FOE modes to the model predictions by the PREM model is investigated. A reliable consistent shift towards the high frequency of the toroidal modes with angular degree l = 12-19 is revealed. The maximal energy density of the toroidal oscillations is concentrated in the upper mantle of the Earth. Therefore, the established effect corresponds to the higher velocity of the shear waves in the upper mantle than it is predicted by the PREM model.

Neutral Mass Spectrometry of Mega-Dalton Particles with Single-Particle Resolution using a Nano-Electromechanical System

NASA Astrophysics Data System (ADS)

Kelber, Scott; Hanay, Mehmet; Naik, Akshay; Chi, Derrick; Hentz, Sebastien; Bullard, Caryn; Collinet, Eric; Duraffourg, Laurent; Roukes, Michael

2012-02-01

Nanoelectromechanical systems (NEMS) enable mass sensing with unprecedented sensitivity and mass dynamic range. Previous works have relied on statistical analysis of multiple landing events to assemble mass spectra. Here we demonstrate the utility of using multiple modes of the NEMS device in determining the mass of individual molecules landing on the NEMS. Analyte particles in vapor form are produced using matrix assisted laser desorption ionization. Resonant frequencies of the first two modes of a single NEMS device, placed in close proximity to the analyte source, are tracked using parallel phase locked loops. Each analyte molecule landing on the NEMS generates a distinct frequency shift in the two modes. These time correlated frequency jumps are used to evaluate the mass of each analyte particle landing on the NEMS and thus generate mass spectra. We present the latest experimental results using this scheme and also demonstrate the utility for mass spectrometry of large biomolecules. This NEMS-Mass Spec. system offers a new tool for structural biology and pathology for the analysis of large proteins, protein complexes, and viruses.

Global MHD modeling of resonant ULF waves: Simulations with and without a plasmasphere.

PubMed

Claudepierre, S G; Toffoletto, F R; Wiltberger, M

2016-01-01

We investigate the plasmaspheric influence on the resonant mode coupling of magnetospheric ultralow frequency (ULF) waves using the Lyon-Fedder-Mobarry (LFM) global magnetohydrodynamic (MHD) model. We present results from two different versions of the model, both driven by the same solar wind conditions: one version that contains a plasmasphere (the LFM coupled to the Rice Convection Model, where the Gallagher plasmasphere model is also included) and another that does not (the stand-alone LFM). We find that the inclusion of a cold, dense plasmasphere has a significant impact on the nature of the simulated ULF waves. For example, the inclusion of a plasmasphere leads to a deeper (more earthward) penetration of the compressional (azimuthal) electric field fluctuations, due to a shift in the location of the wave turning points. Consequently, the locations where the compressional electric field oscillations resonantly couple their energy into local toroidal mode field line resonances also shift earthward. We also find, in both simulations, that higher-frequency compressional (azimuthal) electric field oscillations penetrate deeper than lower frequency oscillations. In addition, the compressional wave mode structure in the simulations is consistent with a radial standing wave oscillation pattern, characteristic of a resonant waveguide. The incorporation of a plasmasphere into the LFM global MHD model represents an advance in the state of the art in regard to ULF wave modeling with such simulations. We offer a brief discussion of the implications for radiation belt modeling techniques that use the electric and magnetic field outputs from global MHD simulations to drive particle dynamics.

Coherent coupling of molecular resonators with a microcavity mode

NASA Astrophysics Data System (ADS)

Shalabney, A.; George, J.; Hutchison, J.; Pupillo, G.; Genet, C.; Ebbesen, T. W.

2015-01-01

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties, such as lasing, room temperature polariton condensation and the modification of excited electronic landscapes involved in molecular isomerization. Here we show that molecular vibrational modes of the electronic ground state can also be coherently coupled with a microcavity mode at room temperature, given the low vibrational thermal occupation factors associated with molecular vibrations, and the collective coupling of a large ensemble of molecules immersed within the cavity-mode volume. This enables the enhancement of the collective Rabi-exchange rate with respect to the single-oscillator coupling strength. The possibility of inducing large shifts in the vibrational frequency of selected molecular bonds should have immediate consequences for chemistry.

Quasi-laminar stability and sensitivity analyses for turbulent flows: Prediction of low-frequency unsteadiness and passive control

NASA Astrophysics Data System (ADS)

Mettot, Clément; Sipp, Denis; Bézard, Hervé

2014-04-01

This article presents a quasi-laminar stability approach to identify in high-Reynolds number flows the dominant low-frequencies and to design passive control means to shift these frequencies. The approach is based on a global linear stability analysis of mean-flows, which correspond to the time-average of the unsteady flows. Contrary to the previous work by Meliga et al. ["Sensitivity of 2-D turbulent flow past a D-shaped cylinder using global stability," Phys. Fluids 24, 061701 (2012)], we use the linearized Navier-Stokes equations based solely on the molecular viscosity (leaving aside any turbulence model and any eddy viscosity) to extract the least stable direct and adjoint global modes of the flow. Then, we compute the frequency sensitivity maps of these modes, so as to predict before hand where a small control cylinder optimally shifts the frequency of the flow. In the case of the D-shaped cylinder studied by Parezanović and Cadot [J. Fluid Mech. 693, 115 (2012)], we show that the present approach well captures the frequency of the flow and recovers accurately the frequency control maps obtained experimentally. The results are close to those already obtained by Meliga et al., who used a more complex approach in which turbulence models played a central role. The present approach is simpler and may be applied to a broader range of flows since it is tractable as soon as mean-flows — which can be obtained either numerically from simulations (Direct Numerical Simulation (DNS), Large Eddy Simulation (LES), unsteady Reynolds-Averaged-Navier-Stokes (RANS), steady RANS) or from experimental measurements (Particle Image Velocimetry - PIV) — are available. We also discuss how the influence of the control cylinder on the mean-flow may be more accurately predicted by determining an eddy-viscosity from numerical simulations or experimental measurements. From a technical point of view, we finally show how an existing compressible numerical simulation code may be used in a black-box manner to extract the global modes and sensitivity maps.

On the nonlinear forced response of the North Atlantic atmosphere to meridional shifts of the Gulf Stream path

NASA Astrophysics Data System (ADS)

Seo, H.; Kwon, Y. O.; Joyce, T. M.; Ummenhofer, C.

2016-12-01

This study examines the North Atlantic atmospheric circulation response to the meridional shift of Gulf Stream path using a large-ensemble, high-resolution, and hemispheric-scale WRF simulations. The model is forced with wintertime SST anomalies derived from a wide range of Gulf Stream shift scenarios. The key result of the model experiments, supported in part by an independent analysis of a reanalysis data set, is that the large-scale, quasi-steady North Atlantic circulation response is unambiguously nonlinear about the sign and amplitude of chosen SST anomalies. This nonlinear response prevails over the weak linear response and resembles the negative North Atlantic Oscillation, the leading intrinsic mode of variability in the model and the observations. Further analysis of the associated dynamics reveals that the nonlinear responses are accompanied by the anomalous southward shift of the North Atlantic eddy-driven jet stream, which is reinforced nearly equally by the high-frequency transient eddy feedback and the low-frequency high-latitude wave breaking events. The result highlights the importance of the intrinsically nonlinear transient eddy dynamics and eddy-mean flow interactions in generating the nonlinear forced response to the meridional shift in the Gulf Stream.

Amplitude-dependent topological edge states in nonlinear phononic lattices

NASA Astrophysics Data System (ADS)

Pal, Raj Kumar; Vila, Javier; Leamy, Michael; Ruzzene, Massimo

2018-03-01

This work investigates the effect of nonlinearities on topologically protected edge states in one- and two-dimensional phononic lattices. We first show that localized modes arise at the interface between two spring-mass chains that are inverted copies of each other. Explicit expressions derived for the frequencies of the localized modes guide the study of the effect of cubic nonlinearities on the resonant characteristics of the interface, which are shown to be described by a Duffing-like equation. Nonlinearities produce amplitude-dependent frequency shifts, which in the case of a softening nonlinearity cause the localized mode to migrate to the bulk spectrum. The case of a hexagonal lattice implementing a phononic analog of a crystal exhibiting the quantum spin Hall effect is also investigated in the presence of weakly nonlinear cubic springs. An asymptotic analysis provides estimates of the amplitude dependence of the localized modes, while numerical simulations illustrate how the lattice response transitions from bulk-to-edge mode-dominated by varying the excitation amplitude. In contrast with the interface mode of the first example studies, this occurs both for hardening and softening springs. The results of this study provide a theoretical framework for the investigation of nonlinear effects that induce and control topologically protected wave modes through nonlinear interactions and amplitude tuning.

Structural and vibrational properties of solid nitromethane under high pressure by density functional theory.

PubMed

Liu, Hong; Zhao, Jijun; Wei, Dongqing; Gong, Zizheng

2006-03-28

The structural, vibrational, and electronic properties of solid nitromethane under hydrostatic pressure of up to 20 GPa have been studied using density functional theory. The changes of cell volume, the lattice constants, and the molecular geometry of solid nitromethane under hydrostatic loading are examined, and the bulk modulus B0 and its pressure derivative B0' are fitted from the volume-pressure relation. Our theoretical results are compared with available experiments. The change of electron band gap of nitromethane under high pressure is also discussed. Based on the optimized crystal structures, the vibrational frequencies for the internal and lattice modes of the nitromethane crystal at ambient and high pressures are computed, and the pressure-induced frequency shifts of these modes are discussed.

The effect of rocking stapes motions on the cochlear fluid flow and on the basilar membrane motion.

PubMed

Edom, Elisabeth; Obrist, Dominik; Henniger, Rolf; Kleiser, Leonhard; Sim, Jae Hoon; Huber, Alexander M

2013-11-01

The basilar membrane (BM) and perilymph motion in the cochlea due to rocking stapes motion (RSM) and piston-like stapes motion (PSM) is modeled by numerical simulations. The full Navier-Stokes equations are solved in a two-dimensional box geometry. The BM motion is modeled by independent oscillators using an immersed boundary technique. The traveling waves generated by both stimulation modes are studied. A comparison of the peak amplitudes of the BM motion is presented and their dependence on the frequency and on the model geometry (stapes position and cochlear channel height) is investigated. It is found that the peak amplitudes for the RSM are lower and decrease as frequency decreases whereas those for the PSM increase as frequency decreases. This scaling behavior can be explained by the different mechanisms that excite the membrane oscillation. Stimulation with both modes at the same time leads to either a slight increase or a slight decrease of the peak amplitudes compared to the pure PSM, depending on the phase shift between the two modes. While the BM motion is dominated by the PSM mode under normal conditions, the RSM may lead to hearing if no PSM is present or possible, e.g., due to round window atresia.

Gyrokinetic Simulations of JET Carbon and ITER-Like Wall Pedestals

NASA Astrophysics Data System (ADS)

Hatch, David; Kotschenreuther, Mike; Mahajan, Swadesh; Liu, Xing; Blackmon, Austin; Giroud, Carine; Hillesheim, Jon; Maggi, Costanza; Saarelma, Samuli; JET Contributors Team

2017-10-01

Gyrokinetic simulations using the GENE code are presented, which target a fundamental understanding of JET pedestal transport and, in particular, its modification after installation of an ITER like wall (ILW). A representative pre-ILW (carbon wall) discharge is analyzed as a base case. In this discharge, magnetic diagnostics observe washboard modes, which preferentially affect the temperature pedestal and have frequencies (accounting for Doppler shift) consistent with microtearing modes and inconsistent with kinetic ballooning modes. A similar ILW discharge is examined, which recovers a similar value of H98, albeit at reduced pedestal temperature. This discharge is distinguished by a much higher value of eta, which produces strong ITG and ETG driven instabilities in gyrokinetic simulations. Experimental observations provide several targets for comparisons with simulation data, including the toroidal mode number and frequency of magnetic fluctuations, heat fluxes, and inter-ELM profile evolution. Strategies for optimizing pedestal performance will also be discussed. This work was supported by U.S. DOE Contract No. DE-FG02-04ER54742 and by EUROfusion under Grant No. 633053.

Characterization of beam-driven instabilities and current redistribution in MST plasmas

NASA Astrophysics Data System (ADS)

Parke, E.

2015-11-01

A unique, high-rep-rate (>10 kHz) Thomson scattering diagnostic and a high-bandwidth FIR interferometer-polarimeter on MST have enabled characterization of beam-driven instabilities and magnetic equilibrium changes observed during high power (1 MW) neutral beam injection (NBI). While NBI leads to negligible net current drive, an increase in on-axis current density observed through Faraday rotation is offset by a reduction in mid-radius current. Identification of the phase flip in temperature fluctuations associated with tearing modes provides a sensitive measure of rational surface locations. This technique strongly constrains the safety factor for equilibrium reconstruction and provides a powerful new tool for measuring the equilibrium magnetic field. For example, the n = 6 temperature structure is observed to shift inward 1.1 +/- 0.6 cm, with an estimated reduction of q0 by 5%. This is consistent with a mid-radius reduction in current, and together the Faraday rotation and Thomson scattering measurements corroborate an inductive redistribution of current that compares well with TRANSP/MSTFit predictions. Interpreting tearing mode temperature structures in the RFP remains challenging; the effects of multiple, closely-spaced tearing modes on the mode phase measurement require further verification. In addition to equilibrium changes, previous work has shown that the large fast ion population drives instabilities at higher frequencies near the Alfvén continuum. Recent observations reveal a new instability at much lower frequency (~7 kHz) with strongly chirping behavior. It participates in extensive avalanches of the higher frequency energetic particle and Alfvénic modes to drive enhanced fast ion transport. Internal structures measured from Te and ne fluctuations, their dependence on the safety factor, as well as frequency scaling motivate speculation about mode identity. Work supported by U.S. DOE.

Highly Sensitive Refractive Index Sensors with Plasmonic Nanoantennas-Utilization of Optimal Spectral Detuning of Fano Resonances.

PubMed

Mesch, Martin; Weiss, Thomas; Schäferling, Martin; Hentschel, Mario; Hegde, Ravi S; Giessen, Harald

2018-05-25

We analyze and optimize the performance of coupled plasmonic nanoantennas for refractive index sensing. The investigated structure supports a sub- and super-radiant mode that originates from the weak coupling of a dipolar and quadrupolar mode, resulting in a Fano-type spectral line shape. In our study, we vary the near-field coupling of the two modes and particularly examine the influence of the spectral detuning between them on the sensing performance. Surprisingly, the case of matched resonance frequencies does not provide the best sensor. Instead, we find that the right amount of coupling strength and spectral detuning allows for achieving the ideal combination of narrow line width and sufficient excitation strength of the subradiant mode, and therefore results in optimized sensor performance. Our findings are confirmed by experimental results and first-order perturbation theory. The latter is based on the resonant state expansion and provides direct access to resonance frequency shifts and line width changes as well as the excitation strength of the modes. Based on these parameters, we define a figure of merit that can be easily calculated for different sensing geometries and agrees well with the numerical and experimental results.

Acoustic system for material transport

NASA Technical Reports Server (NTRS)

Barmatz, M. B.; Trinh, E. H.; Wang, T. G.; Elleman, D. D.; Jacobi, N. (Inventor)

1983-01-01

An object within a chamber is acoustically moved by applying wavelengths of different modes to the chamber to move the object between pressure wells formed by the modes. In one system, the object is placed in one end of the chamber while a resonant mode, applied along the length of the chamber, produces a pressure well at the location. The frequency is then switched to a second mode that produces a pressure well at the center of the chamber, to draw the object. When the object reaches the second pressure well and is still traveling towards the second end of the chamber, the acoustic frequency is again shifted to a third mode (which may equal the first model) that has a pressure well in the second end portion of the chamber, to draw the object. A heat source may be located near the second end of the chamber to heat the sample, and after the sample is heated it can be cooled by moving it in a corresponding manner back to the first end of the chamber. The transducers for levitating and moving the object may be all located at the cool first end of the chamber.

Vibration responses of h-BN sheet to charge doping and external strain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Wei; Yang, Yu; Zheng, Fawei

2013-12-07

Based on density functional theory and density functional perturbation theory calculations, we systematically investigate the vibration responses of h-BN sheet to charge doping and external strains. It is found that under hole doping, the phonon frequencies of the ZO and TO branches at different wave vector q shift linearly with different slopes. Under electron doping, although the phonon frequencies shift irregularly, the shifting values are different at different phonon wave vectors. Interestingly, we find that external strain can restrain the irregular vibration responses of h-BN sheet to electron doping. The critical factor is revealed to be the relative position ofmore » the nearly free electron and boron p{sub z} states of h-BN sheet. Under external strains, the vibration responses of h-BN sheet are also found to be highly dependent on the phonon branches. Different vibration modes at different q points are revealed to be responsible for the vibration responses of h-BN sheet to charge doping and external strain. Our results point out a new way to detect the doping or strain status of h-BN sheet by measuring the vibration frequencies at different wave vector.« less

New look at the Badger-Bauer rule: Correlations of spectroscopic IR and NMR parameters with hydrogen bond energy and geometry. FHF complexes

NASA Astrophysics Data System (ADS)

Tupikina, E. Yu.; Denisov, G. S.; Melikova, S. M.; Kucherov, S. Yu.; Tolstoy, P. M.

2018-07-01

In this work correlation dependencies between hydrogen bond energy ΔE for complexes with Fsbnd H⋯F hydrogen bond and their spectroscopic characteristics of the IR and NMR spectra are presented. We considered 26 complexes in a wide hydrogen bond energy range 0.2-47 kcal/mol. For each complex we calculated complexation energy (MP2/6-311++G(d,p)), IR spectroscopic parameters (FH stretching frequency ν, FH stretching frequency in local mode approximation νLM at MP2/6-311++G(d,p) level) and NMR parameters (chemical shift of hydrogen δH and fluorine nuclei δF, Nuclear Independent Chemical Shielding and spin-spin coupling constants 1JFH, 1hJH...F, 2hJFF at B3LYP/pcSseg-2 level). It was shown that changes of parameters upon complexation, i.e. changes of the stretching frequency in local mode approximation ΔνLM, change of the proton chemical shift ΔδH and change of the absolute value of spin-spin coupling constant 1JFH could be used for estimation of corresponding hydrogen bond strength. Furthermore, we build correlation dependencies between abovementioned spectroscopic characteristics and geometric ones, such as the asymmetry of bridging proton position q1 = 0.5·(rFH - rH…F).

The properties of electromagnetic responses and optical modulation in terahertz metamaterials

NASA Astrophysics Data System (ADS)

Chen, Wei; Shi, Yulei; Wang, Wei; Zhou, Qingli; Zhang, Cunlin

2016-11-01

Metamaterials with subwavelength structural features show unique electromagnetic responses that are unattainable with natural materials. Recently, the research on these artificial materials has been pushed forward to the terahertz (THz) region because of potential applications in biological fingerprinting, security imaging, and high frequency magnetic and electric resonant devices. Furthermore, active control of their properties could further facilitate and open up new applications in terms of modulation and switching. In our work, we will first present our studies of dipole arrays at terahertz frequencies. Then in experimental and theoretical studies of terahertz subwavelength L-shaped structure, we proposed an unusual-mode current resonance responsible for low-frequency characteristic dip in transmission spectra. Comparing spectral properties of our designed simplified structures with that of split-ring resonators, we attribute this unusual mode to the resonance coupling and splitting under the broken symmetry of the structure. Finally, we use optical pump-terahertz probe method to investigate the spectral and dynamic behaviour of optical modulation in the split-ring resonators. We have observed the blue-shift and band broadening in the spectral changes of transmission under optical excitation at different delay times. The calculated surface currents using finite difference time domain simulation are presented to characterize these resonances, and the blue-shift can be explained by the changed refractive index and conductivity in the photoexcited semiconductor substrate.

Applications of free-electron lasers to measurements of energy transfer in biopolymers and materials

NASA Astrophysics Data System (ADS)

Edwards, Glenn S.; Johnson, J. B.; Kozub, John A.; Tribble, Jerri A.; Wagner, Katrina

1992-08-01

Free-electron lasers (FELs) provide tunable, pulsed radiation in the infrared. Using the FEL as a pump beam, we are investigating the mechanisms for energy transfer between localized vibrational modes and between vibrational modes and lattice or phonon modes. Either a laser-Raman system or a Fourier transform infrared (FTIR) spectrometer will serve as the probe beam, with the attribute of placing the burden of detection on two conventional spectroscopic techniques that circumvent the limited response of infrared detectors. More specifically, the Raman effect inelastically shifts an exciting laser line, typically a visible frequency, by the energy of the vibrational mode; however, the shifted Raman lines also lie in the visible, allowing for detection with highly efficient visible detectors. With regards to FTIR spectroscopy, the multiplex advantage yields a distinct benefit for infrared detector response. Our group is investigating intramolecular and intermolecular energy transfer processes in both biopolymers and more traditional materials. For example, alkali halides contain a number of defect types that effectively transfer energy in an intermolecular process. Similarly, the functioning of biopolymers depends on efficient intramolecular energy transfer. Understanding these mechanisms will enhance our ability to modify biopolymers and materials with applications to biology, medecine, and materials science.

Retardation effects on the dispersion and propagation of plasmons in metallic nanoparticle chains

NASA Astrophysics Data System (ADS)

Downing, Charles A.; Mariani, Eros; Weick, Guillaume

2018-01-01

We consider a chain of regularly-spaced spherical metallic nanoparticles, where each particle supports three degenerate localized surface plasmons. Due to the dipolar interaction between the nanoparticles, the localized plasmons couple to form extended collective modes. Using an open quantum system approach in which the collective plasmons are interacting with vacuum electromagnetic modes and which, importantly, readily incorporates retardation via the light-matter coupling, we analytically evaluate the resulting radiative frequency shifts of the plasmonic bandstructure. For subwavelength-sized nanoparticles, our analytical treatment provides an excellent quantitative agreement with the results stemming from laborious numerical calculations based on fully-retarded solutions to Maxwell’s equations. Indeed, the explicit expressions for the plasmonic spectrum which we provide showcase how including retardation gives rise to a logarithmic singularity in the bandstructure of transverse-polarized plasmons. We further study the impact of retardation effects on the propagation of plasmonic excitations along the chain. While for the longitudinal modes, retardation has a negligible effect, we find that the retarded dipolar interaction can significantly modify the plasmon propagation in the case of transverse-polarized modes. Moreover, our results elucidate the analogy between radiative effects in nanoplasmonic systems and the cooperative Lamb shift in atomic physics.

Thickness shear mode (TSM) resonators used for biosensing

NASA Astrophysics Data System (ADS)

Bailey, Claude A.; Fiebor, Ben; Yen, Wei; Vodyanoy, Vitaly; Cernosek, Richard W.; Chin, Bryan A.

2002-02-01

The Auburn University Detection and Food Safety Center has demonstrated real-time biosensor for the detection of Salmonella typimhurium, consisting of a thickness shear-mode (TSM) quartz resonator with antibodies immobilized in a Langmuir-Blodgett surface film. Scanning Electron Microscopy (SEM) images of bound Salmonella bacteria to both polished and unpolished TSM resonators were taken to correlate the mass of the bound organism to the Sauerbrey equation. Theoretical frequency shifts for unpolished TSM resonators predicted by the Sauerbrey equation are much smaller than experimentally measured frequency shift. The Salmonella detector operates in a liquid environment. The viscous properties of this liquid overlayer could influence the TSM resonator's response. Various liquid media were studied as a function of temperature (0 to 50 degree(s)C). The chicken exudate samples with varying fat content show coagulation occurring at temperatures above 35 degree(s)C. Kinematic viscosity test were performed with buffer solutions containing varying quantities of Salmonella bacteria. Since the TSM resonators only entrain a boundary layer of fluid near the surface, they do not respond to these background viscous property changes. Bilk viscosity increases when bacteria concentrations are high. This paper describes investigations of TSM resonator surface acoustic interactions - mass, fluid viscosity, and viscoelasticity - that affect the sensor.

Oscillatory fluid flow in deformable tubes: Implications for pore-scale hydromechanics from comparing experimental observations with theoretical predictions.

PubMed

Kurzeja, Patrick; Steeb, Holger; Strutz, Marc A; Renner, Jörg

2016-12-01

Oscillatory flow of four fluids (air, water, two aqueous sodium-tungstate solutions) was excited at frequencies up to 250 Hz in tubes of two materials (steel, silicone) covering a wide range in length, diameter, and thickness. The hydrodynamical response was characterized by phase shift and amplitude ratio between pressures in an upstream (pressure excitation) and a downstream reservoir connected by the tubes. The resulting standing flow waves reflect viscosity-controlled diffusive behavior and inertia-controlled wave behavior for oscillation frequencies relatively low and high compared to Biot's critical frequency, respectively. Rigid-tube theories correspond well with the experimental results for steel tubes filled with air or water. The wave modes observed for silicone tubes filled with the rather incompressible liquids or air, however, require accounting for the solid's shear and bulk modulus to correctly predict speed of pressure propagation and deformation mode. The shear mode may be responsible for significant macroscopic attenuation in porous materials with effective frame-shear moduli lower than the bulk modulus of the pore fluid. Despite notable effects of the ratio of densities and of acoustic and shear velocity of fluid and solid, Biot's frequency remains an approximate indicator of the transition from the viscosity to the inertia controlled regime.

Correlated Photon-Pair Generation in Reverse Proton-Exchange PPLN Waveguides With Integrated Mode Demultiplexer at 10 GHz Clock

DTIC Science & Technology

2007-07-31

number of photon-pairs per pulse is μ ( 1<<μ ) and the laser repetition frequency isν . The average noise photon numbers per pulse are sμ and iμ for the...and 1563-nm center wavelength pass through a tunable bandpass filter to remove the background noise from the EDFA. The pump is then frequency doubled...generation in dispersion-shifted fiber: suppression of noise photons by cooling fiber", Opt. Express, 13, 7832 (2005) #83485 - $15.00 USD Received 29 May

Synchronization of pulses from mode-locked lasers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harvey, G.T.

A study of the synchronization of mode-locked lasers is presented. In particular, we investigate the timing of the laser output pulses with respect to the radio frequency (RF) signal driving the mode-locking elements in the laser cavity. Two types of mode-locked lasers are considered: a cw loss-modulated mode-locked argon ion laser; and a q-switched active-passive mode-locked Nd:YAG laser. We develop theoretical models for the treatment of laser pulse synchronization in both types of lasers. Experimental results are presented on a combined laser system that synchronizes pulses from both an argon ion and a Nd:YAG laser by using a common RFmore » signal to drive independent mode-lockers in both laser cavities. Shot to shot jitter as low as 18 ps (RMS) was measured between the output pulses from the two lasers. The theory of pulse synchronization for the cw loss-modulated mode-locked argon ion laser is based on the relationship between the timing of the mode-locked laser pulse (with respect to the peak of the RF signal) and the length of the laser cavity. Experiments on the argon laser include the measurement of the phase shift of the mode-locked pulse as a function of cavity length and intracavity intensity. The theory of synchronization of the active-passive mode-locked Nd:YAG laser is an extension of the pulse selection model of the active-passive laser. Experiments on the active-passive Nd:YAG laser include: measurement of the early noise fluctuations; measurement of the duration of the linear build-up stage (time between laser threshold and saturation of the absorber); measurement of jitter as a function of the mode-locker modulation depth; and measurement of the output pulse phase shift as a function of cavity length.« less

Study of hydrogen bonding in ethanol-water binary solutions by Raman spectroscopy

NASA Astrophysics Data System (ADS)

Li, Fabing; Men, Zhiwei; Li, Shuo; Wang, Shenghan; Li, Zhanlong; Sun, Chenglin

2018-01-01

Raman spectra of ethanol-water binary solutions have been observed at room temperature and atmospheric pressure. We find that with increasing ethanol concentration, the symmetric and asymmetric Osbnd H stretching vibrational mode (3286 and 3434 cm- 1) of water are shifted to lower frequency and the weak shoulder peak at 3615 cm- 1 (free OH) disappears. These results indicate that ethanol strengthens hydrogen bonds in water. Simultaneously, our experiment shows that Raman shifts of ethanol reverses when the volume ratio of ethanol and the overall solution is 0.2, which demonstrates that ethanol-water structure undergoes a phase transition.

Wavemode identification in the dissipation/dispersion range of solar wind turbulence: Kinetic Alfven Waves and/or Whistlers? (Invited)

NASA Astrophysics Data System (ADS)

Salem, C. S.; Sundkvist, D. J.; Bale, S.

2009-12-01

Electromagnetic fluctuations in the inertial range of solar wind MHD turbulence and beyond (up to frequencies of 10Hz) have been studied for the first time using both magnetic field and electric field measurements on Cluster [Bale et al., 2005]. It has been shown that at frequencies above the spectral breakpoint at ~0.4Hz, in the dissipation range, the wave modes become dispersive and are consistent with Kinetic Alfven Waves (KAW). This interpretation, consistent with findings from recent theoretical studies, is based on the simple assumption that the measured frequency spectrum is actually a Doppler shifted wave number spectrum (ω ≈ k Vsw), commonly used in the solar wind and known as Taylor's hypothesis. While Taylor's hypothesis is valid in the inertial range of solar wind turbulence, it may break down in the dissipation range where temporal fluctuations can become important. We recently analyzed the effect of Doppler shift on KAW as well as compressional proton whistler waves [Salem et al., 2009]. The dispersive properties of the KAW and the whistler wave modes, as well as the electric to magnetic field (E/B) ratio, have been determined both analytically and numerically in the plasma and the spacecraft frame, with the goal of directly comparing those analytical/numerical estimates in the spacecraft frame with the data as measured. We revisit here Cluster electric field and magnetic field data in the solar wind using this approach. We focus our analysis on several ambient solar wind intervals with varying plasma parameters, allowing for a statistical study. We show that this technique provides an efficient diagnostics for wave-mode identification in the dissipation/dispersion range of solar wind turbulence.

Theory of Talbot lasers

NASA Astrophysics Data System (ADS)

Guillet de Chatellus, H.; Lacot, E.; Glastre, W.; Jacquin, O.; Hugon, O.

2013-09-01

We provide a theoretical study of frequency-shifted feedback (FSF) lasers, i.e., lasers with an internal frequency shifter, seeded with a monochromatic wave. The resulting spectrum consists in a set of equidistant modes, labeled by n, whose phases vary quadratically with n. We prove the emergence of a temporal fractional Talbot effect, leading to generation of Fourier-transform-limited pulses at a repetition rate tunable by the parameters of the FSF cavity (cavity length and frequency shift per round trip), and limited by the spectral bandwidth of the laser. We characterize in detail the output field of this so-called “Talbot laser” and emphasize its specific intensity fluctuations. We evidence connections with some aspects of number theory by the appearance of Gauss sums and theta series in the expression of the laser field. Our predictions are in full agreement with the experimental results published in Guillet de Chatellus [Opt. ExpressOPEXFF1094-408710.1364/OE.21.015065 21, 15065 (2013)]. Practical applications and limitations are discussed.

Spectro-spatial analysis of wave packet propagation in nonlinear acoustic metamaterials

NASA Astrophysics Data System (ADS)

Zhou, W. J.; Li, X. P.; Wang, Y. S.; Chen, W. Q.; Huang, G. L.

2018-01-01

The objective of this work is to analyze wave packet propagation in weakly nonlinear acoustic metamaterials and reveal the interior nonlinear wave mechanism through spectro-spatial analysis. The spectro-spatial analysis is based on full-scale transient analysis of the finite system, by which dispersion curves are generated from the transmitted waves and also verified by the perturbation method (the L-P method). We found that the spectro-spatial analysis can provide detailed information about the solitary wave in short-wavelength region which cannot be captured by the L-P method. It is also found that the optical wave modes in the nonlinear metamaterial are sensitive to the parameters of the nonlinear constitutive relation. Specifically, a significant frequency shift phenomenon is found in the middle-wavelength region of the optical wave branch, which makes this frequency region behave like a band gap for transient waves. This special frequency shift is then used to design a direction-biased waveguide device, and its efficiency is shown by numerical simulations.

A 12 GHz wavelength spacing multi-wavelength laser source for wireless communication systems

NASA Astrophysics Data System (ADS)

Peng, P. C.; Shiu, R. K.; Bitew, M. A.; Chang, T. L.; Lai, C. H.; Junior, J. I.

2017-08-01

This paper presents a multi-wavelength laser source with 12 GHz wavelength spacing based on a single distributed feedback laser. A light wave generated from the distributed feedback laser is fed into a frequency shifter loop consisting of 50:50 coupler, dual-parallel Mach-Zehnder modulator, optical amplifier, optical filter, and polarization controller. The frequency of the input wavelength is shifted and then re-injected into the frequency shifter loop. By re-injecting the shifted wavelengths multiple times, we have generated 84 optical carriers with 12 GHz wavelength spacing and stable output power. For each channel, two wavelengths are modulated by a wireless data using the phase modulator and transmitted through a 25 km single mode fiber. In contrast to previously developed schemes, the proposed laser source does not incur DC bias drift problem. Moreover, it is a good candidate for radio-over-fiber systems to support multiple users using a single distributed feedback laser.

Implementation of a quantum metamaterial using superconducting qubits.

PubMed

Macha, Pascal; Oelsner, Gregor; Reiner, Jan-Michael; Marthaler, Michael; André, Stephan; Schön, Gerd; Hübner, Uwe; Meyer, Hans-Georg; Il'ichev, Evgeni; Ustinov, Alexey V

2014-10-14

The key issue for the implementation of a metamaterial is to demonstrate the existence of collective modes corresponding to coherent oscillations of the meta-atoms. Atoms of natural materials interact with electromagnetic fields as quantum two-level systems. Artificial quantum two-level systems can be made, for example, using superconducting nonlinear resonators cooled down to their ground state. Here we perform an experiment in which 20 of these quantum meta-atoms, so-called flux qubits, are embedded into a microwave resonator. We observe the dispersive shift of the resonator frequency imposed by the qubit metamaterial and the collective resonant coupling of eight qubits. The realized prototype represents a mesoscopic limit of naturally occurring spin ensembles and as such we demonstrate the AC-Zeeman shift of a resonant qubit ensemble. The studied system constitutes the implementation of a basic quantum metamaterial in the sense that many artificial atoms are coupled collectively to the quantized mode of a photon field.

Matrix-isolation and computational study of the HXeY⋯H2O complexes (Y = Cl, Br, and I).

PubMed

Tsuge, Masashi; Berski, Sławomir; Räsänen, Markku; Latajka, Zdzisław; Khriachtchev, Leonid

2014-01-28

The HXeY⋯H2O complexes (Y = Cl, Br, and I) are studied theoretically and experimentally. The calculations at the CCSD(T)/def2-TZVPPD level of theory predict two stable structures for Y = Cl and Br and one structure for Y = I, with interaction energies up to about -7 kcal mol(-1). In the experiments, we have identified several infrared absorption bands originating from the H-Xe stretching mode of these complexes in a xenon matrix. The monomer-to-complex frequency shifts of this mode are up to +82 cm(-1) (Y = Cl), +101 cm(-1) (Y = Br), and +138 cm(-1) (Y = I), i.e., the shift is smaller for more strongly bound molecules. Based on the agreement of the experimental and theoretical results, the observed bands are assigned to the most stable planar structure with an O-H⋯Y-Xe hydrogen bond.

Low temperature FTIR spectra and hydrogen bonds in polycrystalline cytidine.

PubMed

Rozenberg, M; Jung, C; Shoham, G

2004-08-01

FTIR spectra of polycrystalline samples of cytidine, pure and containing a small quantity of N(O)H or N(O)D groups (<20%), were measured in KBr pellets from 4000 to 400 cm(-1) at temperatures from 300 to 20K. For the first time the bands of the narrow isotopically decoupled proton stretching vibration mode (nu(1)) of OH- and NH- groups were found; their number corresponds to the number of H-bonds in crystal according to structural data. The FTIR spectra at low temperature in the out-of-plane bending nu(4) proton mode range (lower than 1000 cm(-1)) of N(O)H groups revealed narrow bands, which correspond to nu(1) bands together with several "extra" bands, which are influenced by the isotopic exchange and (or) cooling. All of them have their counterparts in the N(O)D-substance spectrum with an isotopic frequency ratio of 1.30-1.40. The "extra" bands are assigned to the H-bound OH and NH protons, which are disordered and cannot be seen with X-ray crystal structure analysis. The peak positions of both mode bands (expressed as the red shift of nu(1) or blue shift of nu(4) modes relatively free molecules) were used for the estimation of the energy of different H-bonds using previously established empirical correlations between spectral and thermodynamic parameters of hydrogen bonds. The correlation of the red shift and H-bond length is also confirmed for all five H-bonds of cytidine.

Exciton-phonon system on a star graph: A perturbative approach.

PubMed

Yalouz, Saad; Pouthier, Vincent

2016-05-01

Based on the operatorial formulation of the perturbation theory, the properties of an exciton coupled with optical phonons on a star graph are investigated. Within this method, the dynamics is governed by an effective Hamiltonian, which accounts for exciton-phonon entanglement. The exciton is dressed by a virtual phonon cloud whereas the phonons are clothed by virtual excitonic transitions. In spite of the coupling with the phonons, it is shown that the energy spectrum of the dressed exciton resembles that of a bare exciton. The only differences originate in a polaronic mechanism that favors an energy shift and a decay of the exciton hopping constant. By contrast, the motion of the exciton allows the phonons to propagate over the graph so that the dressed normal modes drastically differ from the localized modes associated to bare phonons. They define extended vibrations whose properties depend on the state occupied by the exciton that accompanies the phonons. It is shown that the phonon frequencies, either red shifted or blue shifted, are very sensitive to the model parameter in general, and to the size of the graph in particular.

Twin peak high-frequency quasi-periodic oscillations as a spectral imprint of dual oscillation modes of accretion tori

NASA Astrophysics Data System (ADS)

Bakala, P.; Goluchová, K.; Török, G.; Šrámková, E.; Abramowicz, M. A.; Vincent, F. H.; Mazur, G. P.

2015-09-01

Context. High-frequency (millisecond) quasi-periodic oscillations (HF QPOs) are observed in the X-ray power-density spectra of several microquasars and low-mass X-ray binaries. Two distinct QPO peaks, so-called twin peak QPOs, are often detected simultaneously exhibiting their frequency ratio close or equal to 3:2. A widely discussed class of proposed QPOs models is based on oscillations of accretion toroidal structures orbiting in the close vicinity of black holes or neutron stars. Aims: Following the analytic theory and previous studies of observable spectral signatures, we aim to model the twin peak QPOs as a spectral imprint of specific dual oscillation regime defined by a combination of the lowest radial and vertical oscillation mode of slender tori. We consider the model of an optically thick slender accretion torus with constant specific angular momentum. We examined power spectra and fluorescent Kα iron line profiles for two different simulation setups with the mode frequency relations corresponding to the epicyclic resonance HF QPOs model and modified relativistic precession QPOs model. Methods: We used relativistic ray-tracing implemented in the parallel simulation code LSDplus. In the background of the Kerr spacetime geometry, we analyzed the influence of the distant observer inclination and the spin of the central compact object. Relativistic optical projection of the oscillating slender torus is illustrated by images in false colours related to the frequency shift. Results: We show that performed simulations yield power spectra with the pair of dominant peaks that correspond to the frequencies of radial and vertical oscillation modes and with the peak frequency ratio equal to the proper value 3:2 on a wide range of inclinations and spin values. We also discuss exceptional cases of a very low and very high inclination, as well as unstable high spin relativistic precession-like configurations that predict a constant frequency ratio equal to 1:2. We demonstrate a significant dependency of broadened Kα iron line profiles on the inclination of the distant observer. Conclusions: This study presents a further step towards the proper model of oscillating accretion tori producing HF QPOs. More realistic future simulations should be based on incorporating the resonant coupling of oscillation modes, the influence of torus opacity, and the pressure effects on the mode frequencies and the torus shape.

Transverse Mode Coupling Instability of the Bunch with Oscillating Wake Field and Space Charge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balbekov, V.

Transverse mode coupling instability of a single bunch caused by oscillating wake field is considered in the paper. The instability threshold is found at different frequencies of the wake with space charge tune shift taken into account. The wake phase advance in the bunch length from 0 up tomore » $$4\\pi$$ is investigated. It is shown that the space charge can push the instability threshold up or down dependent on the phase advance. Transition region is investigated thoroughly, and simple asymptotic formulas for the threshold are represented.« less

Dipolar interaction induced band gaps and flat modes in surface-modulated magnonic crystals

NASA Astrophysics Data System (ADS)

Gallardo, R. A.; Schneider, T.; Roldán-Molina, A.; Langer, M.; Fassbender, J.; Lenz, K.; Lindner, J.; Landeros, P.

2018-04-01

Theoretical results for the magnetization dynamics of a magnonic crystal formed by grooves on the surface of a ferromagnetic film, called a surface-modulated magnonic crystal, are presented. For such a system, the role of the periodic dipolar field induced by the geometrical modulation is addressed by using the plane-wave method. The results reveal that, under the increasing of the depth of the grooves, zones with magnetizing and demagnetizing fields act on the system in such a way that magnonic band gaps are observed in both Damon-Eshbach and backward volume geometries. Particularly, in the backward volume configuration, high-frequency band gaps and low-frequency flat modes are obtained. By taking into account the properties of the internal field induced by the grooves, the flattening of the modes and their shift towards low frequencies are discussed and explained. To test the validity of the model, the theoretical results of this work are confirmed by micromagnetic simulations, and good agreement between both methods is achieved. The theoretical model allows for a detailed understanding of the physics underlying these kinds of systems, thereby providing an outlook for potential applications on magnonic devices.

Volatile organic compounds discrimination based on dual mode detection

NASA Astrophysics Data System (ADS)

Yu, Yuanyuan; Wu, Enxiu; Chen, Yan; Feng, Zhihong; Zheng, Shijun; Zhang, Hao; Pang, Wei; Liu, Jing; Zhang, Daihua

2018-06-01

We report on a volatile organic compound (VOC) sensor that can provide concentration-independent signals toward target gases. The device is based on a dual-mode detection mechanism that can simultaneously record the mechanical (resonant frequency, f r) and electrical (current, I) responses of the same gas adsorption event. The two independent signals form a unique I–f r trace for each target VOC as the concentration varies. The mechanical response (frequency shift, Δf r) resulting from mass load on the device is directly related to the amount of surface adsorptions, while the electrical response (current variation, ΔI) is associated with charge transfer across the sensing interface and changes in carrier mobility. The two responses resulting from independent physical processes reflect intrinsic physical properties of each target gas. The ΔI–Δf r trace combined with the concentration dependent frequency (or current) signals can therefore be used to achieve target both recognition and quantification. The dual-mode device is designed and fabricated using standard complementary metal oxide semiconductor (CMOS) compatible processes. It exhibits consistent and stable performance in our tests with six different VOCs including ethanol, methanol, acetone, formaldehyde, benzene and hexane.

Experimental investigation of the radiation of sound from an unflanged duct and a bellmouth, including the flow effect

NASA Technical Reports Server (NTRS)

Ville, J. M.; Silcox, R. J.

1980-01-01

The radiation of sound from an inlet as a function of flow velocity, frequency, duct mode structure, and inlet geometry was examined by using a spinning mode synthesizer to insure a given space-time structure inside the duct. Measurements of the radiation pattern (amplitude and phase) and of the pressure reflection coefficient were obtained over an azimuthal wave number range of 0 to 6 and a frequency range up to 5000 Hz for an unflanged duct and a bellmouth. The measured radiated field and pressure reflection coefficient without flow for the unflanged duct agree reasonably well with theory. The influence of the inlet contour appears to be very drastic near the cut-on frequency of a mode and reasonable agreement is found between the bellmouth pressure reflection coefficient and a infinite hyperboloidal inlet theory. It is also shown that the flow has a weak effect on the amplitude of the directivity factor but significantly shifts the directivity factor phase. The influence of the flow on the modulus of the pressure reflection coefficient is found to be well described by a theoretical prediction.

Liquid density analysis of sucrose and alcoholic beverages using polyimide guided Love-mode acoustic wave sensors

NASA Astrophysics Data System (ADS)

Turton, Andrew; Bhattacharyya, Debabrata; Wood, David

2006-02-01

A liquid density sensor using Love-mode acoustic waves has been developed which is suitable for use in the food and drinks industries. The sensor has an open flat surface allowing immersion into a sample and simple cleaning. A polyimide waveguide layer allows cheap and simple fabrication combined with a robust chemically resistant surface. The low shear modulus of polyimide allows thin guiding layers giving a high sensitivity. A dual structure with a smooth reference device exhibiting viscous coupling with the wave, and a patterned sense area to trap the liquid causing mass loading, allows discrimination of the liquid density from the square root of the density-viscosity product (ρη)0.5. Frequency shift and insertion loss change were proportional to (ρη)0.5 with a non-linear response due to the non-Newtonian nature of viscous liquids at high frequencies. Measurements were made with sucrose solutions up to 50% and different alcoholic drinks. A maximum sensitivity of 0.13 µg cm-3 Hz-1 was achieved, with a linear frequency response to density. This is the highest liquid density sensitivity obtained for acoustic mode sensors to the best of our knowledge.

Geometry and Raman spectra of P.R. 255 and its furo-furanone analogue

NASA Astrophysics Data System (ADS)

Luňák, Stanislav, Jr.; Frumarová, Božena; Vyňuchal, Jan; Hrdina, Radim

2009-05-01

Fourier transform Raman spectra of two π-isoelectronic compounds 3,6-diphenyl-2,5-dihydro-pyrrolo-[3,4-c]pyrrole-1,4-dione (BPPB, C.I. Pigment Red 255) and 3,6-diphenyl-2,5-dihydro-furo-[3,4-c]furanone (BFFB) with the same 1,4-diphenyl-buta-1,3-diene (DPB) backbone were first time measured in polycrystalline phase. The ground state geometry and vibrational frequencies together with Raman intensities were computed by density functional theory (DFT: B3LYP/6-311G++(d,p)). All intensive observed Raman frequencies were identified as totally symmetric. The difference of carbon-carbon bond lengths of BPPB and BFFB compared to DPB, relating very well with the shifts of C dbnd C and C-C stretching modes frequencies, was explained by aromatization of central butadiene unit bounded in diketo-pyrrolo-pyrrole and furo-furanone heterocycles. A strong coupling of modes was observed for BFFB enhancing selectively the intensity of one peak 1593 cm -1 in C dbnd C stretching region and one peak 1372 cm -1 in C-C stretching region. C dbnd O stretching and N-H bending modes of BPPB are significantly affected by intermolecular hydrogen bonding.

Volatile organic compounds discrimination based on dual mode detection.

PubMed

Yu, Yuanyuan; Wu, Enxiu; Chen, Yan; Feng, Zhihong; Zheng, Shijun; Zhang, Hao; Pang, Wei; Liu, Jing; Zhang, Daihua

2018-06-15

We report on a volatile organic compound (VOC) sensor that can provide concentration-independent signals toward target gases. The device is based on a dual-mode detection mechanism that can simultaneously record the mechanical (resonant frequency, f r ) and electrical (current, I) responses of the same gas adsorption event. The two independent signals form a unique I-f r trace for each target VOC as the concentration varies. The mechanical response (frequency shift, Δf r ) resulting from mass load on the device is directly related to the amount of surface adsorptions, while the electrical response (current variation, ΔI) is associated with charge transfer across the sensing interface and changes in carrier mobility. The two responses resulting from independent physical processes reflect intrinsic physical properties of each target gas. The ΔI-Δf r trace combined with the concentration dependent frequency (or current) signals can therefore be used to achieve target both recognition and quantification. The dual-mode device is designed and fabricated using standard complementary metal oxide semiconductor (CMOS) compatible processes. It exhibits consistent and stable performance in our tests with six different VOCs including ethanol, methanol, acetone, formaldehyde, benzene and hexane.

Spectroscopic and Quantum Mechanical Calculation Study of the Effect of Isotopic Substitution on NIR Spectra of Methanol.

PubMed

Grabska, Justyna; Czarnecki, Mirosław A; Beć, Krzysztof B; Ozaki, Yukihiro

2017-10-19

In this work, we studied methanol and its deuterated derivatives (CH 3 OH, CH 3 OD, CD 3 OH, CD 3 OD) by NIR spectroscopy and anharmonic quantum chemical calculations. Vibrational bands corresponding to up to three quanta transitions (first and second overtones, binary and ternary combination modes) were predicted by the use of the VPT2 route. The accuracy of prediction of NIR modes was evaluated through density functional theory (DFT) with selected density functionals and basis sets. On the basis of the theoretical NIR spectra, detailed band assignments for all studied molecules were proposed. It was found that the pattern of bands in NIR spectra of deuterated methanols can be used for identification of isotopically equalized forms. Calculations of NIR spectra of all possible forms of CXXXOX (X = H, D) molecules demonstrated that the isotopic contamination can be identified due to a coexistence of bands specific to OH and OD groups. Also, bands from partially deuterated methyl groups can be distinguished in NIR spectra. Since the VPT2 framework is known to be sensitive to inaccuracy in the case of highly anharmonic modes, we obtained an independent insight by numerical solving of the time-independent Schrödinger equation corresponding to the O-X stretching mode scanned within -0.4 to 2.0 Å over a dense grid of 0.005 Å. This way the energies of vibrational levels of the CX1X2X3OX4 (X = H, D) isotopomers and the corresponding transition frequencies were obtained with high accuracy (<0.1 cm -1 ). The change in normal coordinate influences the reduced mass of the oscillator and thus its frequency. Our results lead to a conclusion that the effect of deuterization of the methyl group introduces a very specific and consistent frequency shift of the first overtone of the O-X stretching mode depending on the substitution of X1, X2, or X3 positions (<2 cm -1 ). However, the pattern of this shift is not reproduced accurately and is also largely overestimated by VPT2 calculations.

High-frequency plasma-heating apparatus

DOEpatents

Brambilla, Marco; Lallia, Pascal

1978-01-01

An array of adjacent wave guides feed high-frequency energy into a vacuum chamber in which a toroidal plasma is confined by a magnetic field, the wave guide array being located between two toroidal current windings. Waves are excited in the wave guide at a frequency substantially equal to the lower frequency hybrid wave of the plasma and a substantially equal phase shift is provided from one guide to the next between the waves therein. For plasmas of low peripheral density gradient, the guides are excited in the TE.sub.01 mode and the output electric field is parallel to the direction of the toroidal magnetic field. For exciting waves in plasmas of high peripheral density gradient, the guides are excited in the TM.sub.01 mode and the magnetic field at the wave guide outlets is parallel to the direction of the toroidal magnetic field. The wave excited at the outlet of the wave guide array is a progressive wave propagating in the direction opposite to that of the toroidal current and is, therefore, not absorbed by so-called "runaway" electrons.

Quantum plasmons with optical-range frequencies in doped few-layer graphene

NASA Astrophysics Data System (ADS)

Shirodkar, Sharmila N.; Mattheakis, Marios; Cazeaux, Paul; Narang, Prineha; Soljačić, Marin; Kaxiras, Efthimios

2018-05-01

Although plasmon modes exist in doped graphene, the limited range of doping achieved by gating restricts the plasmon frequencies to a range that does not include the visible and infrared. Here we show, through the use of first-principles calculations, that the high levels of doping achieved by lithium intercalation in bilayer and trilayer graphene shift the plasmon frequencies into the visible range. To obtain physically meaningful results, we introduce a correction of the effect of plasmon interaction across the vacuum separating periodic images of the doped graphene layers, consisting of transparent boundary conditions in the direction perpendicular to the layers; this represents a significant improvement over the exact Coulomb cutoff technique employed in earlier works. The resulting plasmon modes are due to local field effects and the nonlocal response of the material to external electromagnetic fields, requiring a fully quantum mechanical treatment. We describe the features of these quantum plasmons, including the dispersion relation, losses, and field localization. Our findings point to a strategy for fine-tuning the plasmon frequencies in graphene and other two-dimensional materials.

Active cancellation of residual amplitude modulation in a frequency-modulation based Fabry-Perot interferometer.

PubMed

Yu, Yinan; Wang, Yicheng; Pratt, Jon R

2016-03-01

Residual amplitude modulation (RAM) is one of the most common noise sources known to degrade the sensitivity of frequency modulation spectroscopy. RAM can arise as a result of the temperature dependent birefringence of the modulator crystal, which causes the orientation of the crystal's optical axis to shift with respect to the polarization of the incident light with temperature. In the fiber-based optical interferometer used on the National Institute of Standards and Technology calculable capacitor, RAM degrades the measured laser frequency stability and correlates with the environmental temperature fluctuations. We have demonstrated a simple approach that cancels out excessive RAM due to polarization mismatch between the light and the optical axis of the crystal. The approach allows us to measure the frequency noise of a heterodyne beat between two lasers individually locked to different resonant modes of a cavity with an accuracy better than 0.5 ppm, which meets the requirement to further determine the longitudinal mode number of the cavity length. Also, this approach has substantially mitigated the temperature dependency of the measurements of the cavity length and consequently the capacitance.

Oscillatory Dynamics of Single Bubbles and Agglomeration in a Sound Field in Microgravity

NASA Technical Reports Server (NTRS)

Marston, Philip L.; Trinh, Eugene H.; Depew, Jon; Asaki, Thomas J.

1994-01-01

A dual-frequency acoustic levitator containing water was developed for studying bubble and drop dynamics in low gravity. It was flown on USML-1 where it was used in the Glovebox facility. High frequency (21 or 63 kHz) ultrasonic waves were modulated by low frequencies to excite shape oscillations on bubbles and oil drops ultrasonically trapped in the water. Bubble diameters were typically close to 1 cm or larger. When such large bubbles are acoustically trapped on the Earth, the acoustic radiation pressure needed to overcome buoyancy tends to shift the natural frequency for quadrupole (n = 2) oscillations above the prediction of Lamb's equation. In low gravity, a much weaker trapping force was used and measurements of n = 2 and 3 mode frequencies were closer to the ideal case. Other video observations in low gravity include: (i) the transient reappearance of a bulge where a small bubble has coalesced with a large one, (ii) observations of the dynamics of bubbles coated by oil indicating that shape oscillations can shift a coated bubble away from the oil-water interface of the coating giving a centering of the core, and (iii) the agglomeration of bubbles induced by the sound field.

Capillary bridge stability and dynamics: Active electrostatic stress control and acoustic radiation pressure

NASA Astrophysics Data System (ADS)

Wei, Wei

2005-11-01

In low gravity, the stability of liquid bridges and other systems having free surfaces is affected by the ambient vibration of the spacecraft. Such vibrations are expected to excite capillary modes. The lowest unstable mode of cylindrical liquid bridges, the (2,0) mode, is particularly sensitive to the vibration when the ratio of the bridge length to the diameter approaches pi. In this work, a Plateau tank has been used to simulate the weightless condition. An optical system has been used to detect the (2,0) mode oscillation amplitude and generate an error signal which is determined by the oscillation amplitude. This error signal is used by the feedback system to produce proper voltages on the electrodes which are concentric with the electrically conducting, grounded bridge. A mode-coupled electrostatic stress is thus generated on the surface of the bridge. The feedback system is designed such that the modal force applied by the Maxwell stress can be proportional to the modal amplitude or modal velocity, which is the derivative of the modal amplitude. Experiments done in the Plateau tank demonstrate that the damping of the capillary oscillation can be enhanced by using the electrostatic stress in proportion to the modal velocity. On the other hand, using the electrostatic stress in proportion to the modal amplitude can raise the natural frequency of the bridge oscillation. If a spacecraft vibration frequency is close to a capillary mode frequency, the amplitude gain can be used to shift the mode frequency away from that of the spacecraft and simultaneously add some artificial damping to further reduce the effect of g-jitter. It is found that the decay of a bridge (2,0) mode oscillation is well modeled by a Duffing equation with a small cubic soft-spring term. The nonlinearity of the bridge (3,0) mode is also studied. The experiments reveal the hysteresis of (3,0) mode bridge oscillations, and this behavior is a property of the soft nonlinearity of the bridge. Relevant to acoustical bridge stabilization, the theoretical radiation force on a compressible cylinder in an acoustic standing wave is also investigated.

The influence of disk's flexibility on coupling vibration of shaft disk blades systems

NASA Astrophysics Data System (ADS)

Yang, Chia-Hao; Huang, Shyh-Chin

2007-03-01

The coupling vibrations among shaft-torsion, disk-transverse and blade-bending in a shaft-disk-blades unit are investigated. The equations of motion for the shaft-disk-blades unit are first derived from the energy approach in conjunction with the assumed modes method. The effects of disk flexibility, blade's stagger angle and rotational speed upon the natural frequencies and mode shapes are particularly studied. Previous studies have shown that there were four types of coupling modes, the shaft-blade (SB), the shaft-disk-blades (SDBs), the disk-blades (DB) and the blade-blade (BB) in such a unit. The present research focuses on the influence of disk flexibility on the coupling behavior and discovers that disk's flexibility strongly affects the modes bifurcation and the transition of modes. At slightly flexible disk, the BB modes bifurcate into BB and DB modes. As disk goes further flexible, SB modes shift into SDB modes. If it goes furthermore, additional disk-predominating modes are generated and DB modes appear before the SDB mode. Examination of stagger angle β proves that at two extreme cases; at β=0° the shaft and blades coupled but not the disk, and at β=90° the disk and blades coupled but not the shaft. In between, coupling exists among three components. Increasing β may increase or decrease SB modes, depending on which, the disk or shaft's first mode, is more rigid. The natural frequencies of DB modes usually decrease with the increase of β. Rotation effects show that bifurcation, veering and merging phenomena occur due to disk flexibility. Disk flexibility is also observed to induce more critical speeds in the SDBs systems.

Spatial mapping of electronic states in κ-(BEDT-TTF)2X using infrared reflectivity

PubMed Central

Sasaki, Takahiko; Yoneyama, Naoki

2009-01-01

We review our recent work on spatial inhomogeneity of the electronic states in the strongly correlated molecular conductors κ-(BEDT-TTF)2X. Spatial mapping of infrared spectra (SMIS) is used for imaging the distribution of the local electronic states. In molecular materials, the infrared response of the specific molecular vibration mode with a strong electron–molecular vibration coupling can reflect the electronic states via the change in the vibration frequency. By spatially mapping the frequency shift of the molecular vibration mode, an electronic phase separation has been visualized near the first-order Mott transition in the bandwidth-controlled organic conductor κ-(BEDT-TTF)2Cu[N(CN)2]Br. In addition to reviewing SMIS of the phase separation, we briefly mention the electronic and optical properties of κ-(BEDT-TTF)2X. PMID:27877279

Damping of quasiparticles in a Bose-Einstein condensate coupled to an optical cavity

NASA Astrophysics Data System (ADS)

Kónya, G.; Szirmai, G.; Domokos, P.

2014-07-01

We present a general theory for calculating the damping rate of elementary density-wave excitations in a Bose-Einstein condensate strongly coupled to a single radiation field mode of an optical cavity. Thereby we give a detailed derivation of the huge resonant enhancement in the Beliaev damping of a density-wave mode, predicted recently by Kónya et al. [Phys. Rev. A 89, 051601(R) (2014), 10.1103/PhysRevA.89.051601]. The given density-wave mode constitutes the polaritonlike soft mode of the self-organization phase transition. The resonant enhancement takes place, in both the normal and the ordered phases, outside the critical region. We show that the large damping rate is accompanied by a significant frequency shift of this polariton mode. Going beyond the Born-Markov approximation and determining the poles of the retarded Green's function of the polariton, we reveal a strong coupling between the polariton and a collective mode in the phonon bath formed by the other density-wave modes.

Elastic properties of compressed emulsions

NASA Astrophysics Data System (ADS)

Jorjadze, Ivane; Brujic, Jasna

2012-02-01

Visualizing the packing of a dense emulsion in 3D as a function of the external pressure allows us to characterize the geometry and the local stress distribution inside this jammed system. We first test the scaling laws of the pressure and average coordination number over two orders of magnitude in density. We find deviations from theoretical exponents due to the non-affine motion of the particles. Second, we observe that the distribution of forces changes from a broad exponential at the jamming point to a narrower Gaussian-like distribution under high compression. Finally, we calculate the density of states from the measured force network in the approximation of a harmonic potential. Close to jamming, the number of low frequency modes is high, while the application of pressure shifts the distribution to higher frequencies, indicative of a rigid network. The confocal images reveal the structural features associated with the low frequency modes, as well as their localization within the packing. These data are then compared with published results from numerical simulations.

Frequency shift measurement in shock-compressed materials

DOEpatents

Moore, David S.; Schmidt, Stephen C.

1985-01-01

A method for determining molecular vibrational frequencies in shock-compressed transparent materials. A single laser beam pulse is directed into a sample material while the material is shock-compressed from a direction opposite that of the incident laser beam. A Stokes beam produced by stimulated Raman scattering is emitted back along the path of the incident laser beam, that is, in the opposite direction to that of the incident laser beam. The Stokes beam is separated from the incident beam and its frequency measured. The difference in frequency between the Stokes beam and the incident beam is representative of the characteristic frequency of the Raman active mode of the sample. Both the incident beam and the Stokes beam pass perpendicularly through the shock front advancing through the sample, thereby minimizing adverse effects of refraction.

Frequency shift measurement in shock-compressed materials

DOEpatents

Moore, D.S.; Schmidt, S.C.

1984-02-21

A method is disclosed for determining molecular vibrational frequencies in shock-compressed transparent materials. A single laser beam pulse is directed into a sample material while the material is shock-compressed from a direction opposite that of the incident laser beam. A Stokes beam produced by stimulated Raman scattering is emitted back along the path of the incident laser beam, that is, in the opposite direction to that of the incident laser beam. The Stokes beam is separated from the incident beam and its frequency measured. The difference in frequency between the Stokes beam and the incident beam is representative of the characteristic frequency of the Raman active mode of the sample. Both the incident beam and the Stokes beam pass perpendicularly through the stock front advancing through the sample, thereby minimizing adverse effects of refraction.

Individual and collective modes of surface magnetoplasmon in thiolate-protected silver nanoparticles studied by MCD spectroscopy.

PubMed

Yao, Hiroshi; Shiratsu, Taisuke

2016-06-07

Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD) spectroscopy. The samples examined are decanethiol (DT)-, azobenzenethiol (ABT)-, and ABT/DT mixed-monolayer-protected Ag nanoparticles. ABT-protected Ag nanoparticles are somewhat aggregated and thus exhibit a broad, collective mode of plasmonic absorption, whereas other samples with highly-dispersed nanoparticles show an individual mode of LSPR absorption. In all Ag nanoparticles, a derivative-like MCD signal is observed under an applied magnetic field of 1.6 T, which can be explained in terms of two circular modes of magnetoplasmon caused by the increase (or decrease) in the Lorentz force imparted on the free electrons that oscillate in the left (or right) circular orbits in the nanosphere. For the Ag nanoparticles exhibiting an individual LSPR mode, in particular, simultaneous deconvolution analysis of UV-vis absorption and MCD spectra reveal that (i) the amplitude of the magnetoplasmonic component with lower frequency (ω-), resulting from the reduction in the confinement strength of collective electrons by the Lorentz force, is stronger than that with a higher frequency (ω+); (ii) the accurate shift or cyclotron frequency between two magnetoplasmonic modes (ωc = ω+-ω-) is size-dependent, and presents a very large value with implications for the apparent enhancement of the local magnetic-field in the Ag nanoparticles. These results strongly suggest that the Ag-thiolate layer or Ag-S bonding on the nanoparticle surface plays a significant role in the MO enhancement.

Carrier-envelope phase-controlled quantum interference of injected photocurrents in semiconductors.

PubMed

Fortier, T M; Roos, P A; Jones, D J; Cundiff, S T; Bhat, R D R; Sipe, J E

2004-04-09

We demonstrate quantum interference control of injected photocurrents in a semiconductor using the phase stabilized pulse train from a mode-locked Ti:sapphire laser. Measurement of the comb offset frequency via this technique results in a signal-to-noise ratio of 40 dB (10 Hz resolution bandwidth), enabling solid-state detection of carrier-envelope phase shifts of a Ti:sapphire oscillator.

Stability of hypersonic boundary-layer flows with chemistry

NASA Technical Reports Server (NTRS)

Reed, Helen L.; Stuckert, Gregory K.; Haynes, Timothy S.

1993-01-01

The effects of nonequilibrium chemistry and three dimensionality on the stability characteristics of hypersonic flows are discussed. In two-dimensional (2-D) and axisymmetric flows, the inclusion of chemistry causes a shift of the second mode of Mack to lower frequencies. This is found to be due to the increase in size of the region of relative supersonic flow because of the lower speeds of sound in the relatively cooler boundary layers. Although this shift in frequency is present in both the equilibrium and nonequilibrium air results, the equilibrium approximation predicts modes which are not observed in the nonequilibrium calculations (for the flight conditions considered). These modes are superpositions of incoming and outgoing unstable disturbances which travel supersonically relative to the boundary-layer edge velocity. Such solutions are possible because of the finite shock stand-off distance. Their corresponding wall-normal profiles exhibit an oscillatory behavior in the inviscid region between the boundary-layer edge and the bow shock. For the examination of three-dimensional (3-D) effects, a rotating cone is used as a model of a swept wing. An increase of stagnation temperature is found to be only slightly stabilizing. The correlation of transition location (N = 9) with parameters describing the crossflow profile is discussed. Transition location does not correlate with the traditional crossflow Reynolds number. A new parameter that appears to correlate for boundary-layer flow was found. A verification with experiments on a yawed cone is provided.

Development of an acoustic measurement protocol to monitor acetabular implant fixation in cementless total hip Arthroplasty: A preliminary study.

PubMed

Goossens, Quentin; Leuridan, Steven; Henyš, Petr; Roosen, Jorg; Pastrav, Leonard; Mulier, Michiel; Desmet, Wim; Denis, Kathleen; Vander Sloten, Jos

2017-11-01

In cementless total hip arthroplasty (THA), the initial stability is obtained by press-fitting the implant in the bone to allow osseointegration for a long term secondary stability. However, finding the insertion endpoint that corresponds to a proper initial stability is currently based on the tactile and auditory experiences of the orthopedic surgeon, which can be challenging. This study presents a novel real-time method based on acoustic signals to monitor the acetabular implant fixation in cementless total hip arthroplasty. Twelve acoustic in vitro experiments were performed on three types of bone models; a simple bone block model, an artificial pelvic model and a cadaveric model. A custom made beam was screwed onto the implant which functioned as a sound enhancer and insertor. At each insertion step an acoustic measurement was performed. A significant acoustic resonance frequency shift was observed during the insertion process for the different bone models; 250 Hz (35%, second bending mode) to 180 Hz (13%, fourth bending mode) for the artificial bone block models and 120 Hz (11%, eighth bending mode) for the artificial pelvis model. No significant frequency shift was observed during the cadaveric experiment due to a lack of implant fixation in this model. This novel diagnostic method shows the potential of using acoustic signals to monitor the implant seating during insertion. Copyright © 2017 IPEM. Published by Elsevier Ltd. All rights reserved.

Non-linear Frequency Shifts, Mode Couplings, and Decay Instability of Plasma Waves

NASA Astrophysics Data System (ADS)

Affolter, Mathew; Anderegg, F.; Driscoll, C. F.; Valentini, F.

2015-11-01

We present experiments and theory for non-linear plasma wave decay to longer wavelengths, in both the oscillatory coupling and exponential decay regimes. The experiments are conducted on non-neutral plasmas in cylindrical Penning-Malmberg traps, θ-symmetric standing plasma waves have near acoustic dispersion ω (kz) ~kz - αkz2 , discretized by kz =mz (π /Lp) . Large amplitude waves exhibit non-linear frequency shifts δf / f ~A2 and Fourier harmonic content, both of which are increased as the plasma dispersion is reduced. Non-linear coupling rates are measured between large amplitude mz = 2 waves and small amplitude mz = 1 waves, which have a small detuning Δω = 2ω1 -ω2 . At small excitation amplitudes, this detuning causes the mz = 1 mode amplitude to ``bounce'' at rate Δω , with amplitude excursions ΔA1 ~ δn2 /n0 consistent with cold fluid theory and Vlasov simulations. At larger excitation amplitudes, where the non-linear coupling exceeds the dispersion, phase-locked exponential growth of the mz = 1 mode is observed, in qualitative agreement with simple 3-wave instability theory. However, significant variations are observed experimentally, and N-wave theory gives stunningly divergent predictions that depend sensitively on the dispersion-moderated harmonic content. Measurements on higher temperature Langmuir waves and the unusual ``EAW'' (KEEN) waves are being conducted to investigate the effects of wave-particle kinetics on the non-linear coupling rates. Department of Energy Grants DE-SC0002451and DE-SC0008693.

Helicons in uniform fields. II. Poynting vector and angular momenta

NASA Astrophysics Data System (ADS)

Stenzel, R. L.; Urrutia, J. M.

2018-03-01

The orbital and spin angular momenta of helicon modes have been determined quantitatively from laboratory experiments. The current density is obtained unambiguously from three dimensional magnetic field measurements. The only approximation made is to obtain the electric field from Hall Ohm's law which is usually the case for low frequency whistler modes. This allows the evaluation of the Poynting vector from which the angular momentum is obtained. Comparing two helicon modes (m = 0 and m = 1), one can separate the contribution of angular momentum of a rotating and non-rotating wave field. The orbital angular momentum is important to assess the wave-particle interaction by the transverse Doppler shift of rotating waves which has not been considered so far.

Study of the O-mode in a relativistic degenerate electron plasma

NASA Astrophysics Data System (ADS)

Azra, Kalsoom; Ali, Muddasir; Hussain, Azhar

2017-03-01

Using the linearized relativistic Vlasov-Maxwell equations, a generalized expression for the plasma conductivity tensor is derived. The dispersion relation for the O-mode in a relativistic degenerate electron plasma is investigated by employing the Fermi-Dirac distribution function. The propagation characteristics of the O-mode (cut offs, resonances, propagation regimes, harmonic structure) are examined by using specific values of the density and the magnetic field that correspond to different relativistic dense environments. Further, it is observed that due to the relativistic effects the cut off and the resonance points are shifted to low frequency values, as a result the propagation regime is reduced. The dispersion relations for the non-relativistic and the ultra-relativistic limits are also presented.

Electron heating and the Electrical Asymmetry Effect in capacitively coupled RF discharges

NASA Astrophysics Data System (ADS)

Schulze, Julian

2011-10-01

For applications of capacitive radio frequency discharges, the control of particle distribution functions at the substrate surface is essential. Their spatio-temporal shape is the result of complex heating mechanisms of the respective species. Enhanced process control, therefore, requires a detailed understanding of the heating dynamics. There are two known modes of discharge operation: α- and γ-mode. In α-mode, most ionization is caused by electron beams generated by the expanding sheaths and field reversals during sheath collapse, while in γ-mode secondary electrons dominate the ionisation. In strongly electronegative discharges, a third heating mode is observed. Due to the low electron density in the discharge center the bulk conductivity is reduced and a high electric field is generated to drive the RF current through the discharge center. In this field, electrons are accelerated and cause significant ionisation in the bulk. This bulk heating mode is observed experimentally and by PIC simulations in CF4 discharges. The electron dynamics and mode transitions as a function of driving voltage and pressure are discussed. Based on a detailed understanding of the heating dynamics, the concept of separate control of the ion mean energy and flux in classical dual-frequency discharges is demonstrated to fail under process relevant conditions. To overcome these limitations of process control, the Electrical Asymmetry Effect (EAE) is proposed in discharges driven at multiple consecutive harmonics with adjustable phase shifts between the driving frequencies. Its concept and a recipe to optimize the driving voltage waveform are introduced. The functionality of the EAE in different gases and first applications to large area solar cell manufacturing are discussed. Finally, limitations caused by the bulk heating in strongly electronegative discharges are outlined.

IR spectral assignments for the hydrated excess proton in liquid water.

PubMed

Biswas, Rajib; Carpenter, William; Fournier, Joseph A; Voth, Gregory A; Tokmakoff, Andrei

2017-04-21

The local environmental sensitivity of infrared (IR) spectroscopy to a hydrogen-bonding structure makes it a powerful tool for investigating the structure and dynamics of excess protons in water. Although of significant interest, the line broadening that results from the ultrafast evolution of different solvated proton-water structures makes the assignment of liquid-phase IR spectra a challenging task. In this work, we apply a normal mode analysis using density functional theory of thousands of proton-water clusters taken from reactive molecular dynamics trajectories of the latest generation multistate empirical valence bond proton model (MS-EVB 3.2). These calculations are used to obtain a vibrational density of states and IR spectral density, which are decomposed on the basis of solvated proton structure and the frequency dependent mode character. Decompositions are presented on the basis of the proton sharing parameter δ, often used to distinguish Eigen and Zundel species, the stretch and bend character of the modes, the mode delocalization, and the vibrational mode symmetry. We find there is a wide distribution of vibrational frequencies spanning 1200-3000 cm -1 for every local proton configuration, with the region 2000-2600 cm -1 being mostly governed by the distorted Eigen-like configuration. We find a continuous red shift of the special-pair O⋯H + ⋯O stretching frequency, and an increase in the flanking water bending intensity with decreasing δ. Also, we find that the flanking water stretch mode of the Zundel-like species is strongly mixed with the flanking water bend, and the special pair proton oscillation band is strongly coupled with the bend modes of the central H 5 O2+moiety.

IR spectral assignments for the hydrated excess proton in liquid water

NASA Astrophysics Data System (ADS)

Biswas, Rajib; Carpenter, William; Fournier, Joseph A.; Voth, Gregory A.; Tokmakoff, Andrei

2017-04-01

The local environmental sensitivity of infrared (IR) spectroscopy to a hydrogen-bonding structure makes it a powerful tool for investigating the structure and dynamics of excess protons in water. Although of significant interest, the line broadening that results from the ultrafast evolution of different solvated proton-water structures makes the assignment of liquid-phase IR spectra a challenging task. In this work, we apply a normal mode analysis using density functional theory of thousands of proton-water clusters taken from reactive molecular dynamics trajectories of the latest generation multistate empirical valence bond proton model (MS-EVB 3.2). These calculations are used to obtain a vibrational density of states and IR spectral density, which are decomposed on the basis of solvated proton structure and the frequency dependent mode character. Decompositions are presented on the basis of the proton sharing parameter δ, often used to distinguish Eigen and Zundel species, the stretch and bend character of the modes, the mode delocalization, and the vibrational mode symmetry. We find there is a wide distribution of vibrational frequencies spanning 1200-3000 cm-1 for every local proton configuration, with the region 2000-2600 cm-1 being mostly governed by the distorted Eigen-like configuration. We find a continuous red shift of the special-pair O⋯H+⋯O stretching frequency, and an increase in the flanking water bending intensity with decreasing δ. Also, we find that the flanking water stretch mode of the Zundel-like species is strongly mixed with the flanking water bend, and the special pair proton oscillation band is strongly coupled with the bend modes of the central H5+O2 moiety.

The mechanism of growth of the low-frequency East Asia-Pacific teleconnection and the triggering role of tropical intraseasonal oscillation

NASA Astrophysics Data System (ADS)

Wang, Jiabao; Wen, Zhiping; Wu, Renguang; Guo, Yuanyuan; Chen, Zesheng

2016-06-01

The East Asia-Pacific (EAP) pattern is a well-known meridional teleconnection over East Asia during boreal summer. In this study, the mechanism for growth of the EAP on intraseasonal timescale is investigated through a vorticity budget. It is found that the beta-effect and high-frequency transient eddies have primary contributions to the growth of the low-frequency EAP. The former leads to a westward shift of disturbances associated with the low-frequency EAP and the latter favors an amplification of disturbances, respectively. The interaction between low-frequency disturbances and zonal flow has a damping effect by dragging disturbances eastward. The impact of boreal summer intraseasonal oscillation (BSISO) on the triggering of the low-frequency EAP is also examined in this study based on observational analysis and a linear model experiment. It is shown that an elongated anomalous convection band located in the vicinity of Philippines associated with the dominant mode of BSISO has a significant impact on the initiation of low-frequency EAP via Rossby wave propagation, whereas anomalous convection located over the North Indian Ocean has a limited impact. Based on the results of present study, the low-frequency EAP could be a self-sustained mode, and the BSISO plays a substantial role in triggering the low-frequency EAP.

Thermal transport and anharmonic phonons in strained monolayer hexagonal boron nitride

NASA Astrophysics Data System (ADS)

Li, Shasha; Chen, Yue

2017-03-01

Thermal transport and phonon-phonon coupling in monolayer hexagonal boron nitride (h-BN) under equibiaxial strains are investigated from first principles. Phonon spectra at elevated temperatures have been calculated from perturbation theory using the third-order anharmonic force constants. The stiffening of the out-of-plane transverse acoustic mode (ZA) near the Brillouin zone center and the increase of acoustic phonon lifetimes are found to contribute to the dramatic increase of thermal transport in strained h-BN. The transverse optical mode (TO) at the K point, which was predicted to lead to mechanical failure of h-BN, is found to shift to lower frequencies at elevated temperatures under equibiaxial strains. The longitudinal and transverse acoustic modes exhibit broad phonon spectra under large strains in sharp contrast to the ZA mode, indicating strong in-plane phonon-phonon coupling.

Planar Microwave Sensor for Theranostic Therapy of Organic Tissue Based on Oval Split Ring Resonators

PubMed Central

Reimann, Carolin; Puentes, Margarita; Maasch, Matthias; Hübner, Frank; Bazrafshan, Babak; Vogl, Thomas J.; Damm, Christian; Jakoby, Rolf

2016-01-01

Microwave sensors in medical environments play a significant role due to the contact-less and non-invasive sensing mechanism to determine dielectric properties of tissue. In this work, a theranostic sensor based on Split Ring Resonators (SRRs) is presented that provides two operation modes to detect and treat tumor cells, exemplary in the liver. For the detection mode, resonance frequency changes due to abnormalities are evaluated, and in the treatment mode, microwave ablation is performed. The planar sensor structure can be integrated into a needle like a surgery tool that evokes challenges concerning size limitations and biocompatibility. To meet the size requirements and provide a reasonable operating frequency, properties of oval shaped SRRs are investigated. By elongating the radius of the SRR in one direction, the resonance frequency can be decreased significantly compared to circular SRR by a factor of two below 12 GHz. In order to validate the detection and treatment characteristics of the sensor, full wave simulations and measurements are examined. Clear resonance shifts are detected for loading the sensor structures with phantoms mimicking healthy and malignant tissue. For treatment mode evaluation, ex vivo beef liver tissue was ablated leading to a lesion zone 1.2 cm × 1 cm × 0.3 cm with a three minute exposure of maximum 2.1 W. PMID:27618050

Mode conversion in metal-insulator-metal waveguide with a shifted cavity

NASA Astrophysics Data System (ADS)

Wang, Yueke; Yan, Xin

2018-01-01

We propose a method, which is utilized to achieve the plasmonic mode conversion in metal-insulator-metal (MIM) waveguide, theoretically. Our proposed structure is composed of bus waveguides and a shifted cavity. The shifted cavity can choose out a plasmonic mode (a- or s-mode) when it is in Fabry-Perot (FP) resonance. The length of the shifted cavity L is carefully chosen, and our structure can achieve the mode conversion between a- and s-mode in the communication region. Besides, our proposed structure can also achieve plasmonic mode-division multiplexing. All the numerical simulations are carried on by the finite element method to verify our design.

Normal mode and experimental analysis of TNT Raman spectrum

NASA Astrophysics Data System (ADS)

Liu, Yuemin; Perkins, Richard; Liu, Yucheng; Tzeng, Nianfeng

2017-04-01

In this study, a Raman spectrum of TNT was characterized through experiments and simulated using 22 hybrid density functional theory (DFT) methods. Among the different hybrid DFT methods, it was found that the most accurate simulation results of the Raman shift frequency were calculated by the O3LYP method. However, the deviations of the calculated Raman frequencies from the experimental value showed no dependency on the abilities of the DFT methods in recovering the correlation energy. The accuracies of the DFT methods in predicting the Raman bands are probably determined by the numerical grid and convergence criteria for optimizations of each DFT method. It was also decided that the prominent Raman shift 1362 cm-1 is mainly caused by symmetric stretching of the 4-nitro groups. Findings of this study can facilitate futuristic development of more effective surface enhanced Raman spectroscopy/scattering (SERS) substrates for explosive characterization and detection.

Acoustic mode measurements in the inlet of a model turbofan using a continuously rotating rake: Data collection/analysis techniques

NASA Technical Reports Server (NTRS)

Hall, David G.; Heidelberg, Laurence; Konno, Kevin

1993-01-01

The rotating microphone measurement technique and data analysis procedures are documented which are used to determine circumferential and radial acoustic mode content in the inlet of the Advanced Ducted Propeller (ADP) model. Circumferential acoustic mode levels were measured at a series of radial locations using the Doppler frequency shift produced by a rotating inlet microphone probe. Radial mode content was then computed using a least squares curve fit with the measured radial distribution for each circumferential mode. The rotating microphone technique is superior to fixed-probe techniques because it results in minimal interference with the acoustic modes generated by rotor-stator interaction. This effort represents the first experimental implementation of a measuring technique developed by T. G. Sofrin. Testing was performed in the NASA Lewis Low Speed Anechoic Wind Tunnel at a simulated takeoff condition of Mach 0.2. The design is included of the data analysis software and the performance of the rotating rake apparatus. The effect of experiment errors is also discussed.

Acoustic mode measurements in the inlet of a model turbofan using a continuously rotating rake - Data collection/analysis techniques

NASA Technical Reports Server (NTRS)

Hall, David G.; Heidelberg, Laurence; Konno, Kevin

1993-01-01

The rotating microphone measurement technique and data analysis procedures are documented which are used to determine circumferential and radial acoustic mode content in the inlet of the Advanced Ducted Propeller (ADP) model. Circumferential acoustic mode levels were measured at a series of radial locations using the Doppler frequency shift produced by a rotating inlet microphone probe. Radial mode content was then computed using a least squares curve fit with the measured radial distribution for each circumferential mode. The rotating microphone technique is superior to fixed-probe techniques because it results in minimal interference with the acoustic modes generated by rotor-stator interaction. This effort represents the first experimental implementation of a measuring technique developed by T. G. Sofrin. Testing was performed in the NASA Lewis Low Speed Anechoic Wind Tunnel at a simulated takeoff condition of Mach 0.2. The design is included of the data analysis software and the performance of the rotating rake apparatus. The effect of experiment errors is also discussed.

A diffuse reflectance infrared Fourier transform spectroscopic study of adsorbed hydrazines

NASA Technical Reports Server (NTRS)

Davis, Dennis D.; Kilduff, Jan E.; Koontz, Steven L.

1988-01-01

Diffuse reflectance spectroscopy of fuel hydrazines adsorbed on silica, silica-alumina and alimina surfaces indicates that the primary surface-hydrazine interaction is hydrogen bonding. Hydrazine, on adsorption to a deuterated silica surface, undergoes a rapid H/D exchange with deuterated surface silanol (Si-OD) groups. Adsorption equilibria are rapidly established at room temperature. Monomethylhydrazine and unsymmetrical dimethylhydrazine are similarly adsorbed. On adsorption, the C-H stretching and methyl deformation modes of the methylhydrazines are shifted to higher frequencies by 10 to 20 cm(-1). These shifts are postulated to be due to changes in the lone-pair electro-density on the adjacent nitrogen atom and an electronegativity effect.

Precision Isotope Shift Measurements in Calcium Ions Using Quantum Logic Detection Schemes.

PubMed

Gebert, Florian; Wan, Yong; Wolf, Fabian; Angstmann, Christopher N; Berengut, Julian C; Schmidt, Piet O

2015-07-31

We demonstrate an efficient high-precision optical spectroscopy technique for single trapped ions with nonclosed transitions. In a double-shelving technique, the absorption of a single photon is first amplified to several phonons of a normal motional mode shared with a cotrapped cooling ion of a different species, before being further amplified to thousands of fluorescence photons emitted by the cooling ion using the standard electron shelving technique. We employ this extension of the photon recoil spectroscopy technique to perform the first high precision absolute frequency measurement of the 2D(3/2)→2P(1/2) transition in calcium, resulting in a transition frequency of f=346 000 234 867(96)  kHz. Furthermore, we determine the isotope shift of this transition and the 2S(1/2)→2P(1/2) transition for 42Ca+, 44Ca+, and 48Ca+ ions relative to 40Ca+ with an accuracy below 100 kHz. Improved field and mass shift constants of these transitions as well as changes in mean square nuclear charge radii are extracted from this high resolution data.

The study of dispersive 'b'-mode in monolayer MoS2 in temperature dependent resonant Raman scattering experiments

NASA Astrophysics Data System (ADS)

Kutrowska-Girzycka, Joanna; Jadczak, Joanna; Bryja, Leszek

2018-07-01

We report on resonant Raman scattering studies of monolayer MoS2 as a function of the excitation laser energy (1.959-2.033 eV) and temperature (T = 7-295 K). In complementary reflectivity contrast experiments we determined the temperature evolution of the A exciton and trion resonances. We focus our studies on the dispersive, second order 'b' mode related to the resonant two phonon Raman process of successive emissions of the acoustic LA and TA phonons at K points. We found that when excitation laser energy is tuned across the A exciton level this mode shifts almost linearly to lower frequency with the rate equal -83 and -71 cm-1/eV at T = 7 and 295 K, respectively, which is about two times higher rate than those reported in the previous studies of monolayer MoS2 but very close the relevant rate recorded for bulk MoS2. We interpret this effect as related to the difference of concentration of two dimensional electron gas. We also determined, using excitation with the He-Ne laser the temperature shifts of the Raman peaks of dispersive 'b' and dispersionless E‧ and A1‧ modes. We found that absolute value of the temperature coefficient of 'b' mode, equals 3.5 × 10-2 cm-1/K, is much higher than those of E‧ and A1‧ modes, equal 0.4 × 10-2 and 0.8 × 10-2 cm-1/K, respectively.

Terahertz spectroscopy and solid-state density functional theory calculation of anthracene: Effect of dispersion force on the vibrational modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Feng; Tominaga, Keisuke, E-mail: atmyh@ntu.edu.tw, E-mail: tominaga@kobe-u.ca.jp, E-mail: junichi.nishizawa@hanken.jp; Hayashi, Michitoshi, E-mail: atmyh@ntu.edu.tw, E-mail: tominaga@kobe-u.ca.jp, E-mail: junichi.nishizawa@hanken.jp

2014-05-07

The phonon modes of molecular crystals in the terahertz frequency region often feature delicately coupled inter- and intra-molecular vibrations. Recent advances in density functional theory such as DFT-D{sup *} have enabled accurate frequency calculation. However, the nature of normal modes has not been quantitatively discussed against experimental criteria such as isotope shift (IS) and correlation field splitting (CFS). Here, we report an analytical mode-decoupling method that allows for the decomposition of a normal mode of interest into intermolecular translation, libration, and intramolecular vibrational motions. We show an application of this method using the crystalline anthracene system as an example. Themore » relationship between the experimentally obtained IS and the IS obtained by PBE-D{sup *} simulation indicates that two distinctive regions exist. Region I is associated with a pure intermolecular translation, whereas region II features coupled intramolecular vibrations that are further coupled by a weak intermolecular translation. We find that the PBE-D{sup *} data show excellent agreement with the experimental data in terms of IS and CFS in region II; however, PBE-D{sup *} produces significant deviations in IS in region I where strong coupling between inter- and intra-molecular vibrations contributes to normal modes. The result of this analysis is expected to facilitate future improvement of DFT-D{sup *}.« less

Acoustic emission signatures of damage modes in concrete

NASA Astrophysics Data System (ADS)

Aggelis, D. G.; Mpalaskas, A. C.; Matikas, T. E.; Van Hemelrijck, D.

2014-03-01

The characterization of the dominant fracture mode may assist in the prediction of the remaining life of a concrete structure due to the sequence between successive tensile and shear mechanisms. Acoustic emission sensors record the elastic responses after any fracture event converting them into electric waveforms. The characteristics of the waveforms vary according to the movement of the crack tips, enabling characterization of the original mode. In this study fracture experiments on concrete beams are conducted. The aim is to examine the typical acoustic signals emitted by different fracture modes (namely tension due to bending and shear) in a concrete matrix. This is an advancement of a recent study focusing on smaller scale mortar and marble specimens. The dominant stress field and ultimate fracture mode is controlled by modification of the four-point bending setup while acoustic emission is monitored by six sensors at fixed locations. Conclusions about how to distinguish the sources based on waveform parameters of time domain (duration, rise time) and frequency are drawn. Specifically, emissions during the shear loading exhibit lower frequencies and longer duration than tensile. Results show that, combination of AE features may help to characterize the shift between dominant fracture modes and contribute to the structural health monitoring of concrete. This offers the basis for in-situ application provided that the distortion of the signal due to heterogeneous wave path is accounted for.

Magnetostatic modes in ferromagnetic samples with inhomogeneous internal fields

NASA Astrophysics Data System (ADS)

Arias, Rodrigo

2015-03-01

Magnetostatic modes in ferromagnetic samples are very well characterized and understood in samples with uniform internal magnetic fields. More recently interest has shifted to the study of magnetization modes in ferromagnetic samples with inhomogeneous internal fields. The present work shows that under the magnetostatic approximation and for samples of arbitrary shape and/or arbitrary inhomogeneous internal magnetic fields the modes can be classified as elliptic or hyperbolic, and their associated frequency spectrum can be delimited. This results from the analysis of the character of the second order partial differential equation for the magnetostatic potential under these general conditions. In general, a sample with an inhomogeneous internal field and at a given frequency, may have regions of elliptic and hyperbolic character separated by a boundary. In the elliptic regions the magnetostatic modes have a smooth monotonic character (generally decaying form the surfaces (a ``tunneling'' behavior)) and in hyperbolic regions an oscillatory wave-like character. A simple local criterion distinguishes hyperbolic from elliptic regions: the sign of a susceptibility parameter. This study shows that one may control to some extent magnetostatic modes via external fields or geometry. R.E.A. acknowledges Financiamiento Basal para Centros Cientificos y Tecnologicos de Excelencia under Project No. FB 0807 (Chile), Grant No. ICM P10-061-F by Fondo de Innovacion para la Competitividad-MINECON, and Proyecto Fondecyt 1130192.

Coherent anti-Stokes Raman scattering enhancement of thymine adsorbed on graphene oxide

PubMed Central

2014-01-01

Coherent anti-Stokes Raman scattering (CARS) of carbon nanostructures, namely, highly oriented pyrolytic graphite, graphene nanoplatelets, graphene oxide, and multiwall carbon nanotubes as well CARS spectra of thymine (Thy) molecules adsorbed on graphene oxide were studied. The spectra of the samples were compared with spontaneous Raman scattering (RS) spectra. The CARS spectra of Thy adsorbed on graphene oxide are characterized by shifts of the main bands in comparison with RS. The CARS spectra of the initial nanocarbons are definitely different: for all investigated materials, there is a redistribution of D- and G-mode intensities, significant shift of their frequencies (more than 20 cm-1), and appearance of new modes about 1,400 and 1,500 cm-1. The D band in CARS spectra is less changed than the G band; there is an absence of 2D-mode at 2,600 cm-1 for graphene and appearance of intensive modes of the second order between 2,400 and 3,000 cm-1. Multiphonon processes in graphene under many photon excitations seem to be responsible for the features of the CARS spectra. We found an enhancement of the CARS signal from thymine adsorbed on graphene oxide with maximum enhancement factor about 105. The probable mechanism of CARS enhancement is discussed. PMID:24948887

Tuning the Quantum Efficiency of Random Lasers - Intrinsic Stokes-Shift and Gain

PubMed Central

Lubatsch, Andreas; Frank, Regine

2015-01-01

We report the theoretical analysis for tuning the quantum efficiency of solid state random lasers. Vollhardt-Wölfle theory of photonic transport in disordered non-conserving and open random media, is coupled to lasing dynamics and solved positionally dependent. The interplay of non-linearity and homogeneous non-radiative frequency conversion by means of a Stokes-shift leads to a reduction of the quantum efficiency of the random laser. At the threshold a strong decrease of the spot-size in the stationary state is found due to the increase of non-radiative losses. The coherently emitted photon number per unit of modal surface is also strongly reduced. This result allows for the conclusion that Stokes-shifts are not sufficient to explain confined and extended mode regimes. PMID:26593237

Tuning the Quantum Efficiency of Random Lasers - Intrinsic Stokes-Shift and Gain.

PubMed

Lubatsch, Andreas; Frank, Regine

2015-11-23

We report the theoretical analysis for tuning the quantum efficiency of solid state random lasers. Vollhardt-Wölfle theory of photonic transport in disordered non-conserving and open random media, is coupled to lasing dynamics and solved positionally dependent. The interplay of non-linearity and homogeneous non-radiative frequency conversion by means of a Stokes-shift leads to a reduction of the quantum efficiency of the random laser. At the threshold a strong decrease of the spot-size in the stationary state is found due to the increase of non-radiative losses. The coherently emitted photon number per unit of modal surface is also strongly reduced. This result allows for the conclusion that Stokes-shifts are not sufficient to explain confined and extended mode regimes.

Individual and collective modes of surface magnetoplasmon in thiolate-protected silver nanoparticles studied by MCD spectroscopy

NASA Astrophysics Data System (ADS)

Yao, Hiroshi; Shiratsu, Taisuke

2016-05-01

Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD) spectroscopy. The samples examined are decanethiol (DT)-, azobenzenethiol (ABT)-, and ABT/DT mixed-monolayer-protected Ag nanoparticles. ABT-protected Ag nanoparticles are somewhat aggregated and thus exhibit a broad, collective mode of plasmonic absorption, whereas other samples with highly-dispersed nanoparticles show an individual mode of LSPR absorption. In all Ag nanoparticles, a derivative-like MCD signal is observed under an applied magnetic field of 1.6 T, which can be explained in terms of two circular modes of magnetoplasmon caused by the increase (or decrease) in the Lorentz force imparted on the free electrons that oscillate in the left (or right) circular orbits in the nanosphere. For the Ag nanoparticles exhibiting an individual LSPR mode, in particular, simultaneous deconvolution analysis of UV-vis absorption and MCD spectra reveal that (i) the amplitude of the magnetoplasmonic component with lower frequency (ω-), resulting from the reduction in the confinement strength of collective electrons by the Lorentz force, is stronger than that with a higher frequency (ω+) (ii) the accurate shift or cyclotron frequency between two magnetoplasmonic modes (ωc = ω+ - ω-) is size-dependent, and presents a very large value with implications for the apparent enhancement of the local magnetic-field in the Ag nanoparticles. These results strongly suggest that the Ag-thiolate layer or Ag-S bonding on the nanoparticle surface plays a significant role in the MO enhancement.Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD) spectroscopy. The samples examined are decanethiol (DT)-, azobenzenethiol (ABT)-, and ABT/DT mixed-monolayer-protected Ag nanoparticles. ABT-protected Ag nanoparticles are somewhat aggregated and thus exhibit a broad, collective mode of plasmonic absorption, whereas other samples with highly-dispersed nanoparticles show an individual mode of LSPR absorption. In all Ag nanoparticles, a derivative-like MCD signal is observed under an applied magnetic field of 1.6 T, which can be explained in terms of two circular modes of magnetoplasmon caused by the increase (or decrease) in the Lorentz force imparted on the free electrons that oscillate in the left (or right) circular orbits in the nanosphere. For the Ag nanoparticles exhibiting an individual LSPR mode, in particular, simultaneous deconvolution analysis of UV-vis absorption and MCD spectra reveal that (i) the amplitude of the magnetoplasmonic component with lower frequency (ω-), resulting from the reduction in the confinement strength of collective electrons by the Lorentz force, is stronger than that with a higher frequency (ω+) (ii) the accurate shift or cyclotron frequency between two magnetoplasmonic modes (ωc = ω+ - ω-) is size-dependent, and presents a very large value with implications for the apparent enhancement of the local magnetic-field in the Ag nanoparticles. These results strongly suggest that the Ag-thiolate layer or Ag-S bonding on the nanoparticle surface plays a significant role in the MO enhancement. Electronic supplementary information (ESI) available: EDX spectroscopic analysis of various Ag nanoparticle samples; MCD signals normalized to absorbance for the Ag(DT)L and Ag(DT)S samples; deconvolution of UV-vis absorption and MCD spectra using three Lorentzian components; IR spectral changes upon photoisomerization; thermal cis-to-trans relaxation of azobenzene in the Ag(ABT) sample; UV-vis absorption spectra of Ag nanoparticle samples in the presence/absence of a magnetic field of 1.6 T. See DOI: 10.1039/c6nr00631k

Carrier-envelope phase control by a composite plate.

PubMed

Ell, Richard; Birge, Jonathan R; Araghchini, Mohammad; Kärtner, Franz X

2006-06-12

We demonstrate a new concept to vary the carrier-envelope phase of a mode-locked laser by a composite plate while keeping all other pulse parameters practically unaltered. The effect is verified externally in an interferometric autocorrelator, as well as inside the cavity of an octave-spanning femtosecond oscillator. The carrier-envelope frequency can be shifted by half the repetition rate with negligible impact on pulse spectrum and energy.

Segmented Liner to Control Mode Scattering

NASA Technical Reports Server (NTRS)

Gerhold, Carl H.; Jones, Michael G.; Brown, Martha C.

2013-01-01

The acoustic performance of duct liners can be improved by segmenting the treatment. In a segmented liner treatment, one stage of liner reduces the target sound and scatters energy into other acoustic modes, which are attenuated by a subsequent stage. The Curved Duct Test Rig is an experimental facility in which sound incident on the liner can be generated in a specific mode and the scatter of energy into other modes can be quantified. A series of experiments is performed in which the baseline configuration is asymmetric, that is, a liner is on one side wall of the test duct and the wall opposite is acoustically hard. Segmented liner treatment is achieved by progressively replacing sections of the hard wall opposite with liner in the axial direction, from 25% of the wall surface to 100%. It is found that the energy scatter from the (0,0) to the (0,1) mode reduces as the percentage of opposite wall treatment increases, and the frequency of peak attenuation shifts toward higher frequency. Similar results are found when the incident mode is of order (0,1) and scatter is into the (0,0) mode. The propagation code CDUCT-LaRC is used to predict the effect of liner segmenting on liner performance. The computational results show energy scatter and the effect of liner segmentation that agrees with the experimental results. The experiments and computations both show that segmenting the liner treatment is effective to control the scatter of incident mode energy into other modes. CDUCT-LaRC is shown to be a valuable tool to predict trends of liner performance with liner configuration.

Cascaded Brillouin lasing in monolithic barium fluoride whispering gallery mode resonators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Guoping, E-mail: guoping.lin@femto-st.fr; Diallo, Souleymane; Saleh, Khaldoun

2014-12-08

We report the observation of stimulated Brillouin scattering and lasing at 1550 nm in barium fluoride (BaF{sub 2}) crystal. Brillouin lasing was achieved with ultra-high quality (Q) factor monolithic whispering gallery mode mm-size disk resonators. Overmoded resonators were specifically used to provide cavity resonances for both the pump and all Brillouin Stokes waves. Single and multiple Brillouin Stokes radiations with frequency shift ranging from 8.2 GHz up to 49 GHz have been generated through cascaded Brillouin lasing. BaF{sub 2} resonator-based Brillouin lasing can find potential applications for high-coherence lasers and microwave photonics.

Optical ferris wheel for ultracold atoms

NASA Astrophysics Data System (ADS)

Franke-Arnold, S.; Leach, J.; Padgett, M. J.; Lembessis, V. E.; Ellinas, D.; Wright, A. J.; Girkin, J. M.; Ohberg, P.; Arnold, A. S.

2007-07-01

We propose a versatile optical ring lattice suitable for trapping cold and quantum degenerate atomic samples. We demonstrate the realisation of intensity patterns from pairs of Laguerre-Gauss (exp(iℓө) modes with different ℓ indices. These patterns can be rotated by introducing a frequency shift between the modes. We can generate bright ring lattices for trapping atoms in red-detuned light, and dark ring lattices suitable for trapping atoms with minimal heating in the optical vortices of blue-detuned light. The lattice sites can be joined to form a uniform ring trap, making it ideal for studying persistent currents and the Mott insulator transition in a ring geometry.

Effects of Imidazole Deprotonation on Vibrational Spectra of High-Spin Iron(II) Porphyrinates

PubMed Central

Hu, Chuanjiang; Peng, Qian; Silvernail, Nathan J.; Barabanschikov, Alexander; Zhao, Jiyong; Alp, E. Ercan; Sturhahn, Wolfgang; Sage, J. Timothy; Scheidt, W. Robert

2013-01-01

The effects of the deprotonation of coordinated imidazole on the dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes in the vibrational spectra are clearly related to structural differences in the molecular structures that occur when imidazole is deprotonated. Most modes involving the simultaneous motion of iron and imidazolate are unresolved but the one mode that is resolved is found at higher frequency in the imidazolates. These out-of-plane results are in accord with earlier resonance Raman studies of heme proteins. We also show the imidazole vs. imidazolate differences in the in-plane vibrations that are not accessible to resonance Raman studies. The in-plane vibrations are at lower frequency in the imidazolate derivatives; the doming mode shifts are inconclusive. The stiffness, an experimentally determined force constant that averages the vibrational details to quantify the nearest-neighbor interactions, confirms that deprotonation inverts the relative strengths of axial and equatorial coordination. PMID:23470205

Numerical simulation of the generation of turbulence from cometary ion pick-up

NASA Technical Reports Server (NTRS)

Goldstein, M. L.; Roberts, D. A.; Matthaeus, W. H.

1987-01-01

Observations of magnetic field fluctuations near Comet Halley have revealed a rapid development of a Kolmogoroff-like turbulence spectrum extending from below 0.01 Hz to above 0.1 Hz. Spectra obtained far from the comet have a strong peak in power near the Doppler-shifted ion-cyclotron frequency of singly ionized water. Closer to the comet, the spectrum at higher frequencies is enhanced in power level over the background solar wind spectrum by approximately an order of magnitude. The equations of incompressible MHD are solved using a two-dimensional 256 x 256 mode spectral method code to simulate this spectral evolution as an inertial range turbulent cascade. The initial conditions contained a constant magnetic field and a single coherent wave mode at a low wave number. The solar wind turbulence was modeled by a background noise spectrum having a Kolmogoroff spectral index. The coherent mode decayed into an inertial range spectrum with Kolmogoroff slope within a few eddy-turnover times. Both the time scale and the increase in power level of the turbulence seen in the simulation are in accord with the Giotto observations.

Testing boundary conditions for the conjunction fallacy: effects of response mode, conceptual focus, and problem type.

PubMed

Wedell, Douglas H; Moro, Rodrigo

2008-04-01

Two experiments used within-subject designs to examine how conjunction errors depend on the use of (1) choice versus estimation tasks, (2) probability versus frequency language, and (3) conjunctions of two likely events versus conjunctions of likely and unlikely events. All problems included a three-option format verified to minimize misinterpretation of the base event. In both experiments, conjunction errors were reduced when likely events were conjoined. Conjunction errors were also reduced for estimations compared with choices, with this reduction greater for likely conjuncts, an interaction effect. Shifting conceptual focus from probabilities to frequencies did not affect conjunction error rates. Analyses of numerical estimates for a subset of the problems provided support for the use of three general models by participants for generating estimates. Strikingly, the order in which the two tasks were carried out did not affect the pattern of results, supporting the idea that the mode of responding strongly determines the mode of thinking about conjunctions and hence the occurrence of the conjunction fallacy. These findings were evaluated in terms of implications for rationality of human judgment and reasoning.

Plucking a hydrogen bond: A near infrared study of all four intermolecular modes in (DF)2

NASA Astrophysics Data System (ADS)

Davis, Scott; Anderson, David T.; Nesbitt, David J.

1996-10-01

The near ir combination band spectra of supersonically cooled (DF)2 in the 2900 to 3300 cm-1 region have been recorded with a high resolution slit jet spectrometer. Twelve vibration-rotation-tunneling (VRT) bands are observed, representing each of the four intermolecular modes (van der Waals stretch ν4, geared bend ν5, out-of-plane torsion ν6, and antigeared bend ν3) built as combination bands on either the ν1 (free) or ν2 (bound) DF stretches. Analysis of the rotationally resolved spectra provide spectroscopic constants, intermolecular frequencies, tunneling splittings, and predissociation rates as a function of both intra- and intermolecular excitation. The intermolecular frequencies demonstrate a small but systematic dependence on intramolecular mode, which is exploited to yield frequency predictions relevant to far-ir studies, as well as facilitate direct comparison with full 6-D quantum calculations on trial potential surfaces. The tunneling splittings demonstrate a much stronger dependence upon intermolecular mode, increasing by as much as an order of magnitude for geared bend excitation. Conversely, high resolution line shape analysis reveals that vibrational predissociation broadening is only modestly affected by intermolecular excitation, and instead exhibits mode specific behavior controlled predominantly by intramolecular excitation. Detailed H/D isotopic vibrational shifts are obtained by comparison with previous combination band studies of all four intermolecular modes in (HF)2. In contrast to the strong state mixing previously observed for (HF)2, the van der Waals stretch and geared bend degrees of freedom are largely decoupled in (DF)2, due to isotopically ``detuning'' of resonances between bend-stretch intermolecular vibrations. Four-dimensional quantum calculations of the (HF)2 and (DF)2 eigenfunctions indicate that the isotopic dependence of this bend-stretch resonance behavior is incorrectly predicted by current hydrogen bond potential surfaces.

Design of Silicon Photonic Crystal Waveguides for High Gain Raman Amplification Using Two Symmetric Transvers-Electric-Like Slow-Light Modes

NASA Astrophysics Data System (ADS)

Hsiao, Yi-Hua; Iwamoto, Satoshi; Arakawa, Yasuhiko

2013-04-01

We designed silicon photonic crystal (PhC) waveguides (WGs) for efficient silicon Raman amplifiers and lasers. We adopted narrow-width WGs to utilize two symmetric transvers-electric-like (TE-like) guided modes, which permit efficient external coupling for both the pump and Stokes waves. Modifying the size and shape of air holes surrounding the line-defect WG structures could tune the frequency difference between these two modes, at the Brillouin-zone edge, to match the Raman shift of silicon. Thus, small group velocities are also available both for pump and Stokes waves simultaneously, which results in a large enhancement of Raman gain. The enhancement factor of the Raman gain in the designed structure is more than 100 times that reported previously.

Comparison between firing tests and numerical simulation of vortex shedding in a 2-D test solid motor

NASA Astrophysics Data System (ADS)

Lupoglazoff, N.; Vuillot, F.

Some comparisons between firing tests and numerical simulations of vortex shedding via a simple test case called 'C1experimental' are presented. These experiments are performed to validate further numerical simulations, as well as to serve as a tool for facilitating interpretation. At ignition time, spectra of pressure are more complex: it is the effect of vortex pairings. For 6.5-mm burnt, the second longitudinal mode dominates. For 8-mm burnt, the first longitudinal mode dominates. For 11.5-mm burnt, there is only the first longitudinal mode, with a slight shift of the frequency value. Tables are presented which give the pressure oscillation amplitudes of 'C1experimental' with operating pressures, and these amplitudes relative to the corresponding operating pressure.

Stress dependence of the Raman spectrum of polycrystalline barium titanate in presence of localized domain texture

NASA Astrophysics Data System (ADS)

Sakashita, Tatsuo; Deluca, Marco; Yamamoto, Shinsuke; Chazono, Hirokazu; Pezzotti, Giuseppe

2007-06-01

The stress dependence of the Raman spectrum of polycrystalline barium titanate (BaTiO3, BT) ceramics has been examined with microprobe polarized Raman spectroscopy. The angular dependence of the Raman spectrum of the tetragonal BT crystal has been theoretically established, enabling us to assess the stress dependence of selected spectral modes without the influence of crystallographic domain orientation. Upon considering the frequency shift of selected Raman modes as a function of orientation between the crystallographic axis and the polarization vector of incident and scattered light, a suitable instrumental configuration has been selected, which allowed a direct residual stress measurement according to a modified piezospectroscopic procedure. The analysis is based on the selection of mixed photostimulated spectral modes in two perpendicular angular orientations.

Identification of strained black phosphorous by Raman spectroscopy

NASA Astrophysics Data System (ADS)

Wan, Jiawei; Guo, Junhong; Hu, Fangren

2017-04-01

Phosphorene has a very high hole mobility and can be a tuned band structure, and has become an ideal material for electronic devices. For this new type of two-dimensional material, in the applied strain, black phosphorus (BP) can be changed into an indirect band gap and metallic materials from the direct band gap semiconductor material, which greatly affect its inherent physical characteristics. How to identify strained microstructure changes becomes an important problem. The calculated Raman spectra disclose that the A{}{{g}}2 mode and B{}2{{g}} mode will split and the Raman spectra appear, while the A{}{{g}}1 mode is shifted to low-frequency region. The deformation induced by strain will effectively change the Raman mode position and intensity, this can be used to identify phosphorus changes. Project supported by the National Science Foundation of China (Nos. 61505085, 61574080, 61274127) and the Innovation Project of Jiangsu Graduate Student, China (No. SJLX15_0379).

Dynamic response of a riser under excitation of internal waves

NASA Astrophysics Data System (ADS)

Lou, Min; Yu, Chenglong; Chen, Peng

2015-12-01

In this paper, the dynamic response of a marine riser under excitation of internal waves is studied. With the linear approximation, the governing equation of internal waves is given. Based on the rigid-lid boundary condition assumption, the equation is solved by Thompson-Haskell method. Thus the velocity field of internal waves is obtained by the continuity equation. Combined with the modified Morison formula, using finite element method, the motion equation of riser is solved in time domain with Newmark-β method. The computation programs are compiled to solve the differential equations in time domain. Then we get the numerical results, including riser displacement and transfiguration. It is observed that the internal wave will result in circular shear flow, and the first two modes have a dominant effect on dynamic response of the marine riser. In the high mode, the response diminishes rapidly. In different modes of internal waves, the deformation of riser has different shapes, and the location of maximum displacement shifts. Studies on wave parameters indicate that the wave amplitude plays a considerable role in response displacement of riser, while the wave frequency contributes little. Nevertheless, the internal waves of high wave frequency will lead to a high-frequency oscillation of riser; it possibly gives rise to fatigue crack extension and partial fatigue failure.

Temperature and chain length dependence of ultrafast vibrational dynamics of thiocyanate in alkylimidazolium ionic liquids: A random walk on a rugged energy landscape.

PubMed

Brinzer, Thomas; Garrett-Roe, Sean

2017-11-21

Ultrafast two-dimensional infrared spectroscopy of a thiocyanate vibrational probe (SCN - ) was used to investigate local dynamics in alkylimidazolium bis-[trifluoromethylsulfonyl]imide ionic liquids ([Im n,1 ][Tf 2 N], n = 2, 4, 6) at temperatures from 5 to 80 °C. The rate of frequency fluctuations reported by SCN - increases with increasing temperature and decreasing alkyl chain length. Temperature-dependent correlation times scale proportionally to temperature-dependent bulk viscosities of each ionic liquid studied. A multimode Brownian oscillator model demonstrates that very low frequency (<10 cm -1 ) modes primarily drive the observed spectral diffusion and that these modes broaden and blue shift on average with increasing temperature. An Arrhenius analysis shows activation barriers for local motions around the probe between 5.5 and 6.5 kcal/mol that are very similar to those for translational diffusion of ions. [Im 6,1 ][Tf 2 N] shows an unexpected decrease in activation energy compared to [Im 4,1 ][Tf 2 N] that may be related to mesoscopically ordered polar and nonpolar domains. A model of dynamics on a rugged potential energy landscape provides a unifying description of the observed Arrhenius behavior and the Brownian oscillator model of the low frequency modes.

Observation of Intermolecular Hydrogen Bonding Interactions in Biosynthesized and Biodegradable Poly [(R)-3-hydroxybutyrate- co-(R)-3-hydroxyhexanoate] in Chloroform and 1,1,1,3,3,3-Hexafluoro-2-propanol (HFIP).

PubMed

Sobieski, Brian J; Noda, Isao; Rabolt, John F; Chase, D Bruce

2017-10-01

In this work, we describe polymer-solvent interactions in biosynthesized and biodegradable poly[(R)-3-hydroxybutyrate- co-(R)-3-hydroxyhexanoate] (PHBHx) and the atactic homopolymer, poly(3-hydroxybutyrate) (a-PHB), which were studied both as neat polymers and in solutions of chloroform and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP). Specifically, infrared frequency shifts of the carbonyl band were observed in semi-crystalline PHBHx, but not in a-PHB, because it cannot form the helical conformation required for crystallization. The carbonyl band of PHBHx exhibited the high frequency associated with amorphous structure in chloroform and the lower frequency traditionally attributed to the helical crystalline structure in HFIP. The same results were obtained for a-PHB, demonstrating that the helical structure is not required for a lower frequency carbonyl-stretching mode. It is proposed that the band shift is due to hydrogen bonding between the carbonyl and hydroxyl hydrogen in HFIP. Therefore, the carbonyl frequency observed upon crystallization is most likely due to hydrogen bonding between the carbonyl and methyl hydrogen of the neighboring polymer chain in the crystal lattice as previously suggested.

Time-frequency analysis of electric motors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bentley, C.L.; Dunn, M.E.; Mattingly, J.K.

1995-12-31

Physical signals such as the current of an electric motor become nonstationary as a consequence of degraded operation and broken parts. In this instance, their power spectral densities become time dependent, and time-frequency analysis techniques become the appropriate tools for signal analysis. The first among these techniques, generally called the short-time Fourier transform (STFT) method, is the Gabor transform 2 (GT) of a signal S(t), which decomposes the signal into time-local frequency modes: where the window function, {Phi}(t-{tau}), is a normalized Gaussian. Alternatively, one can decompose the signal into its multi-resolution representation at different levels of magnification. This representation ismore » achieved by the continuous wavelet transform (CWT) where the function g(t) is a kernel of zero average belonging to a family of scaled and shifted wavelet kernels. The CWT can be interpreted as the action of a microscope that locates the signal by the shift parameter b and adjusts its magnification by changing the scale parameter a. The Fourier-transformed CWT, W,{sub g}(a, {omega}), acts as a filter that places the high-frequency content of a signal into the lower end of the scale spectrum and vice versa for the low frequencies. Signals from a motor in three different states were analyzed.« less

Structural and magnetic properties of Ni-doped SnO{sub 2}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dwivedi, Sonam, E-mail: vdinesh33@rediffmail.com, E-mail: sonam.dwivedi88@gmail.com; Kumar, Ashwini; Dar, Mashkoor A.

2015-06-24

Samples of Ni doped SnO{sub 2} nanocrystalline were successfully prepared by chemical co-precipitation method. X-ray diffraction pattern infers that Sn{sub 1-x}Ni{sub x}O{sub 2} (x=0.00, 0.10, 0.15 and 0.20) samples are in single phase with tetragonal structure (P4{sub 2}/mnm). Raman spectroscopy reveals the observed phonon modes of SnO{sub 2} are at about 387-397, and 559 - 572 cm{sup −1}. For Sn{sub 0.9}Ni{sub 0.1}O{sub 2}, these peaks are shifted to higher wave numbers, while to that for Sn{sub 0.85}Ni{sub 0.15}O{sub 2} and Sn{sub 0.8}Ni{sub 0.2}O{sub 2}, peaks are shifted to the lower wave numbers. The frequency dependent dielectric constant decreases with the increasemore » in the frequency and becomes constant at high frequencies for all compositions of Ni substituted SnO{sub 2}. The magnetization curve confirms the paramagnetic nature of all Ni doped SnO{sub 2} samples.« less

Temporal genetic structure in a poecilogonous polychaete: the interplay of developmental mode and environmental stochasticity

PubMed Central

2014-01-01

Background Temporal variation in the genetic structure of populations can be caused by multiple factors, including natural selection, stochastic environmental variation, migration, or genetic drift. In benthic marine species, the developmental mode of larvae may indicate a possibility for temporal genetic variation: species with dispersive planktonic larvae are expected to be more likely to show temporal genetic variation than species with benthic or brooded non-dispersive larvae, due to differences in larval mortality and dispersal ability. We examined temporal genetic structure in populations of Pygospio elegans, a poecilogonous polychaete with within-species variation in developmental mode. P. elegans produces either planktonic, benthic, or intermediate larvae, varying both among and within populations, providing a within-species test of the generality of a relationship between temporal genetic variation and larval developmental mode. Results In contrast to our expectations, our microsatellite analyses of P. elegans revealed temporal genetic stability in the UK population with planktonic larvae, whereas there was variation indicative of drift in temporal samples of the populations from the Baltic Sea, which have predominantly benthic and intermediate larvae. We also detected temporal variation in relatedness within these populations. A large temporal shift in genetic structure was detected in a population from the Netherlands, having multiple developmental modes. This shift could have been caused by local extiction due to extreme environmental conditions and (re)colonization by planktonic larvae from neighboring populations. Conclusions In our study of P. elegans, temporal genetic variation appears to be due to not only larval developmental mode, but also the stochastic environment of adults. Large temporal genetic shifts may be more likely in marine intertidal habitats (e.g. North Sea and Wadden Sea) which are more prone to environmental stochasticity than the sub-tidal Baltic habitats. Sub-tidal and/or brackish (less saline) habitats may support smaller P. elegans populations and these may be more susceptible to the effects of random genetic drift. Moreover, higher frequencies of asexual reproduction and the benthic larval developmental mode in these populations leads to higher relatedness and contributes to drift. Our results indicate that a general relationship between larval developmental mode and temporal genetic variation may not exist. PMID:24447386

Temporal genetic structure in a poecilogonous polychaete: the interplay of developmental mode and environmental stochasticity.

PubMed

Kesäniemi, Jenni E; Mustonen, Marina; Boström, Christoffer; Hansen, Benni W; Knott, K Emily

2014-01-22

Temporal variation in the genetic structure of populations can be caused by multiple factors, including natural selection, stochastic environmental variation, migration, or genetic drift. In benthic marine species, the developmental mode of larvae may indicate a possibility for temporal genetic variation: species with dispersive planktonic larvae are expected to be more likely to show temporal genetic variation than species with benthic or brooded non-dispersive larvae, due to differences in larval mortality and dispersal ability. We examined temporal genetic structure in populations of Pygospio elegans, a poecilogonous polychaete with within-species variation in developmental mode. P. elegans produces either planktonic, benthic, or intermediate larvae, varying both among and within populations, providing a within-species test of the generality of a relationship between temporal genetic variation and larval developmental mode. In contrast to our expectations, our microsatellite analyses of P. elegans revealed temporal genetic stability in the UK population with planktonic larvae, whereas there was variation indicative of drift in temporal samples of the populations from the Baltic Sea, which have predominantly benthic and intermediate larvae. We also detected temporal variation in relatedness within these populations. A large temporal shift in genetic structure was detected in a population from the Netherlands, having multiple developmental modes. This shift could have been caused by local extiction due to extreme environmental conditions and (re)colonization by planktonic larvae from neighboring populations. In our study of P. elegans, temporal genetic variation appears to be due to not only larval developmental mode, but also the stochastic environment of adults. Large temporal genetic shifts may be more likely in marine intertidal habitats (e.g. North Sea and Wadden Sea) which are more prone to environmental stochasticity than the sub-tidal Baltic habitats. Sub-tidal and/or brackish (less saline) habitats may support smaller P. elegans populations and these may be more susceptible to the effects of random genetic drift. Moreover, higher frequencies of asexual reproduction and the benthic larval developmental mode in these populations leads to higher relatedness and contributes to drift. Our results indicate that a general relationship between larval developmental mode and temporal genetic variation may not exist.

Dynamics Evolution Investigation of Mack Mode Instability in a Hypersonic Boundary Layer by Bicoherence Spectrum Analysis

NASA Astrophysics Data System (ADS)

Han, Jian; Jiang, Nan

2012-07-01

The instability of a hypersonic boundary layer on a cone is investigated by bicoherence spectrum analysis. The experiment is conducted at Mach number 6 in a hypersonic wind tunnel. The time series signals of instantaneous fluctuating surface-thermal-flux are measured by Pt-thin-film thermocouple temperature sensors mounted at 28 stations on the cone surface along streamwise direction to investigate the development of the unstable disturbances. The bicoherence spectrum analysis based on wavelet transform is employed to investigate the nonlinear interactions of the instability of Mack modes in hypersonic laminar boundary layer transition. The results show that wavelet bicoherence is a powerful tool in studying the unstable mode nonlinear interaction of hypersonic laminar-turbulent transition. The first mode instability gives rise to frequency shifts to higher unstable modes at the early stage of hypersonic laminar-turbulent transition. The modulations subsequently lead to the second mode instability occurrence. The second mode instability governs the last stage of instability and final breakdown to turbulence with multi-scale disturbances growth.

Temperature dependence of the vibrational spectra of acetanilide: Davydov solitons or Fermi coupling?

NASA Astrophysics Data System (ADS)

Johnston, Clifford T.; Swanson, Basil I.

1985-03-01

The unusual temperature dependence of the amide-I region in the IR spectrum of acetanilide (C 6H 5NHCOCH 3) has recently been attributed to a self-trapped Davydov-like soliton. The temperature dependence of the single-crystal Raman scattering, from acetanilide and its ND and 13CO substituted analogs in the phonon and internal mode regions has now been studied. The behavior of the amide-I region in the Raman spectra of the normal isotopic species is similar to that observed earlier in infrared studies. However, on the basis of results obtained from the ND and 13CO substituted species the unusual temperature dependence in the 1650 cm -1 region has been attributed to Fermi coupling of the amide-I fundamental and a combination band involving the in-plane NH deformation and a low-frequency torsional mode. As temperature is lowered, the strong blue-shift of the torsional mode results in a commensurate blue-shift in the combination level thereby increasing the Fermi coupling. Temperature tuning of the Fermi coupling results in the anomalous intensity changes observed in the IR and Raman spectra of the amide-I region for the normal isotopic species.

Raman spectroscopic investigations of Hg-Cd-Te melts

NASA Technical Reports Server (NTRS)

Morrobel-Sosa, Anny

1987-01-01

Raman scattering measurements are reported for a series of Hg sub1-xCd subxTe (with x less than or =0.2) materials from 295 K (room temperature) to 1126K (up to and above their liquidus temperatures), and for Hg sub1-xCd subxTe (x=0.3) at 285K. The samples were contained in high-temperature optically-flat fused silica cell. Variable temperature measurements were effected in a three-zone, high-temperature furnace equipped with optical windows, and monitored externally by three independently programmable temperature controllers. All studies were made in the backscattering geometry using the 5145 A line of an Ar+ ion laser, with incident power less than 250 mW, as the excitiation source. An intensity enhancement is observed for a mode in each of the compositions studied. The frequency of this mode varies with composition, 142/cm for HgTe, and 128/cm for both the Hg sub1-xCd subxTe (x=0.053 and 0.204) samples. In addition, a shift to lower frequency as a function of temperature is observed in all samples. This shift is most prominent for the x=0.053 sample. The temperature dependence of these modes as the liquidus temperatures are achieved and surpassed for these samples is presented as being associated with a structural transition in the Hg-rich compositions of the Hg sub1-xCd subxTe series. To our knowledge, this is the first reported study of Raman scattering by phonons in the melts of these materials.

In-duct identification of a rotating sound source with high spatial resolution

NASA Astrophysics Data System (ADS)

Heo, Yong-Ho; Ih, Jeong-Guon; Bodén, Hans

2015-11-01

To understand and reduce the flow noise generation from in-duct fluid machines, it is necessary to identify the acoustic source characteristics precisely. In this work, a source identification technique, which can identify the strengths and positions of the major sound radiators in the source plane, is studied for an in-duct rotating source. A linear acoustic theory including the effects of evanescent modes and source rotation is formulated based on the modal summation method, which is the underlying theory for the inverse source reconstruction. A validation experiment is conducted on a duct system excited by a loudspeaker in static and rotating conditions, with two different speeds, in the absence of flow. Due to the source rotation, the measured pressure spectra reveal the Doppler effect, and the amount of frequency shift corresponds to the multiplication of the circumferential mode order and the rotation speed. Amplitudes of participating modes are estimated at the shifted frequencies in the stationary reference frame, and the modal amplitude set including the effect of source rotation is collected to investigate the source behavior in the rotating reference frame. By using the estimated modal amplitudes, the near-field pressure is re-calculated and compared with the measured pressure. The obtained maximum relative error is about -25 and -10 dB for rotation speeds at 300 and 600 rev/min, respectively. The spatial distribution of acoustic source parameters is restored from the estimated modal amplitude set. The result clearly shows that the position and magnitude of the main sound source can be identified with high spatial resolution in the rotating reference frame.

Simulation of a Hydraulic Pump Control Valve

NASA Technical Reports Server (NTRS)

Molen, G. Vander; Akers, A.

1987-01-01

This paper describes the mode of operation of a control valve assembly that is used with a hydraulic pump. The operating system of the valve is modelled in a simplified form, and an analogy for hydraulic resonance of the pressure sensing system is presented. For the control valve investigated, air entrainment, length and diameter of the resonator neck, and valve mass produced the greatest shift in resonant frequency. Experimental work was conducted on the hydraulic system so that the resonance levels and frequencies could be measured and the accuracy of the theory verified. The results obtained make it possible to evaluate what changes to any of the variables considered would be most effective in driving the second harmonic frequency above the operating range.

A system for measuring complex dielectric properties of thin films at submillimeter wavelengths using an open hemispherical cavity and a vector network analyzer.

PubMed

Rahman, Rezwanur; Taylor, P C; Scales, John A

2013-08-01

Quasi-optical (QO) methods of dielectric spectroscopy are well established in the millimeter and submillimeter frequency bands. These methods exploit standing wave structure in the sample produced by a transmitted Gaussian beam to achieve accurate, low-noise measurement of the complex permittivity of the sample [e.g., J. A. Scales and M. Batzle, Appl. Phys. Lett. 88, 062906 (2006); R. N. Clarke and C. B. Rosenberg, J. Phys. E 15, 9 (1982); T. M. Hirovnen, P. Vainikainen, A. Lozowski, and A. V. Raisanen, IEEE Trans. Instrum. Meas. 45, 780 (1996)]. In effect the sample itself becomes a low-Q cavity. On the other hand, for optically thin samples (films of thickness much less than a wavelength) or extremely low loss samples (loss tangents below 10(-5)) the QO approach tends to break down due to loss of signal. In such a case it is useful to put the sample in a high-Q cavity and measure the perturbation of the cavity modes. Provided that the average mode frequency divided by the shift in mode frequency is less than the Q (quality factor) of the mode, then the perturbation should be resolvable. Cavity perturbation techniques are not new, but there are technological difficulties in working in the millimeter/submillimeter wave region. In this paper we will show applications of cavity perturbation to the dielectric characterization of semi-conductor thin films of the type used in the manufacture of photovoltaics in the 100 and 350 GHz range. We measured the complex optical constants of hot-wire chemical deposition grown 1-μm thick amorphous silicon (a-Si:H) film on borosilicate glass substrate. The real part of the refractive index and dielectric constant of the glass-substrate varies from frequency-independent to linearly frequency-dependent. We also see power-law behavior of the frequency-dependent optical conductivity from 316 GHz (9.48 cm(-1)) down to 104 GHz (3.12 cm(-1)).

Integrated and dispersed photon echo studies of nitrile stretching vibration of 4-cyanophenol in methanol.

PubMed

Ha, Jeong-Hyon; Lee, Kyung-Koo; Park, Kwang-Hee; Choi, Jun-Ho; Jeon, Seung-Joon; Cho, Minhaeng

2009-05-28

By means of integrated and dispersed IR photon echo measurement methods, the vibrational dynamics of C-N stretch modes in 4-cyanophenol and 4-cyanophenoxide in methanol is investigated. The vibrational frequency-frequency correlation function (FFCF) is retrieved from the integrated photon echo signals by assuming that the FFCF is described by two exponential functions with about 400 fs and a few picosecond components. The excited state lifetimes of the C-N stretch modes of neutral and anionic 4-cyanophenols are 1.45 and 0.91 ps, respectively, and the overtone anharmonic frequency shifts are 25 and 28 cm(-1). At short waiting times, a notable underdamped oscillation, which is attributed to a low-frequency intramolecular vibration coupled to the CN stretch, in the integrated and dispersed vibrational echo as well as transient grating signals was observed. The spectral bandwidths of IR absorption and dispersed vibrational echo spectra of the 4-cyanophenoxide are significantly larger than those of its neutral form, indicating that the strong interaction between phenoxide and methanol causes large frequency fluctuation and rapid population relaxation. The resonance effects in a paradisubstituted aromatic compound would be of interest in understanding the conjugation effects and their influences on chemical reactivity of various aromatic compounds in organic solvents.

Elastic dependence of defect modes in one-dimensional photonic crystals with a cholesteric elastomer slab

NASA Astrophysics Data System (ADS)

Avendanño, Carlos G.; Martínez, Daniel

2018-07-01

We studied the transmission spectra in a one-dimensional dielectric multilayer photonic structure containing a cholesteric liquid crystal elastomer layer as a defect. For circularly polarized incident electromagnetic waves, we analyzed the optical defect modes induced in the band gap spectrum as a function of the incident angle and the axial strain applied along the same axis as the periodic medium. The physical parameters of the structure were chosen in such a way the photonic band gap of the cholesteric elastomer lies inside that of the multilayer. We found that, in addition to the defect modes associated with the thickness of the defect layer and the anisotropy of the elastic polymer, two new defect modes appear at both band edges of the cholesteric structure, whose amplitudes and spectral positions can be elastically tuned. Particularly, we showed that, at normal incidence, the defect modes shift toward the long-wavelength region with the strain; whereas, for constant elongation, such defects move toward larger frequencies with the incidence angle.

X-ray diffraction, inelastic neutron scattering (INS) and infrared (IR) studies on 2:1 hexamethylbenzene (HMB) tetracyanoethylene (TCNE) complex

NASA Astrophysics Data System (ADS)

Pawlukojć, A.; Sawka-Dobrowolska, W.; Bator, G.; Sobczyk, L.; Grech, E.; Nowicka-Scheibe, J.

2006-09-01

The structure of the 2:1 hexamethylbenzene (HMB)-tetracyanoethylene (TCNE) complex was determined at 100 K. In the crystalline lattice the molecules of HMB (D) and TCNE (A) are arranged in DDADDADD stacks along the b-axis. Based on the red shift of the ν(C tbnd N) IR frequencies the charge transfer (CT) degree ( Z) was estimated to be equal to 0.14. It is markedly higher than that for the complex of HMB with tetracyanoquinodimethane (TCNQ) for which Z = 0.06. The analysis of vibrational modes connected with torsional motion in the low frequency region was performed based on the inelastic neutron scattering (INS) experiments and DFT theoretical calculations. The correlation between νexp/ νcalc and νcalc shows a deviation of experimental values from calculated ones. It is the higher the lower is the frequency of the analysed mode. The comparison of correlations for neat HMB and its complexes with TCNQ and TCNE suggests that some role in decreasing the barrier to rotation can be played by the charge transfer between D and A molecules.

Distributed ice accretion sensor for smart aircraft structures

NASA Technical Reports Server (NTRS)

Gerardi, J. J.; Hickman, G. A.

1989-01-01

A distributed ice accretion sensor is presented, based on the concept of smart structures. Ice accretion is determined using spectral techniques to process signals from piezoelectric sensors integral to the airfoil skin. Frequency shifts in the leading edge structural skin modes are correlated to ice thickness. It is suggested that this method may be used to detect ice over large areas with minimal hardware. Results are presented from preliminary tests to measure simulated ice growth.

Vibrational spectra for uric acid and its D- and 15N-substituted analogues. Assignments for its normal modes from ab initio 3-21G force field.

NASA Astrophysics Data System (ADS)

Majoube, M.; Vergoten, G.

1993-03-01

FTR, Raman, FTIR spectra are obtained for polycrystalline uric acid and seven of its D-and 15N-substituted analogues. Assignments are given from a normal coordinate analysis carried out using a 3-21G ab initio force field. These are discussed by considering observed and calculated frequencies and D- and 15N-isotopic shifts.

Vibrational coherence in polar solutions of Zn(II) tetrakis(N-methylpyridyl)porphyrin with Soret-band excitation: rapidly damped intermolecular modes with clustered solvent molecules and slowly damped intramolecular modes from the porphyrin macrocycle.

PubMed

Dillman, Kevin L; Shelly, Katherine R; Beck, Warren F

2009-04-30

Ground-state coherent wavepacket motions arising from intermolecular modes with clustered, first-shell solvent molecules were observed using the femtosecond dynamic absorption technique in polar solutions of Zn(II) meso-tetrakis(N-methylpyridyl)porphyrin (ZnTMPyP) with excitation in the Soret absorption band. As was observed previously in bacteriochlorophyll a solution, the pump-probe transients in ZnTMPyP solutions are weakly modulated by slowly damped (effective damping time gamma > 1 ps) features that are assigned to intramolecular modes, the skeletal normal modes of vibration of the porphyrin. The 40 cm(-1) and 215 cm(-1) modes from the metal-doming and metal-solvent-ligand modes, respectively, are members of this set of modulation components. A slowly damped 2-4 cm(-1) component is assigned to the internal rotation of the N-methylpyridyl rings with respect to the porphyrin macrocycle; this mode obtains strong resonance Raman intensity enhancement from an extensive delocalization of pi-electron density from the porphyrin in the ground state onto the rings in the pi* excited states. The dominant features observed in the pump-probe transients are a pair of rapidly damped (gamma < 250 fs) modulation components arising from intermolecular modes with solvent molecules. This structural assignment is supported by an isotope-dependent shift of the average mode frequencies in methanol and perdeuterated methanol. The solvent dependence of the mean intermolecular mode frequency is consistent with a van der Waals intermolecular potential that has significant contributions only from the London dispersion and induction interactions; ion-dipole or ion-induced-dipole terms do not make large contributions because the pi-electron density is not extensively delocalized onto the N-methylpyridyl rings. The modulation depth associated with the intermolecular modes exhibits a marked dependence on the electronic structure of the solvent that is probably related to the degree of covalency; the strongest modulations are observed in acetonitrile and dimethylsulfoxide. The results strongly support a structural assignment of the low-frequency modes that are coupled to the primary and secondary electron-transfer reactions in photosynthetic reaction centers to intermolecular modes between the redox-active chromophores and first-solvation shell groups from the surrounding protein, and an important additional function of the intermolecular modes in the stabilization of charged intermediates is suggested.

Metal isotope and density functional study of the tetracarboxylatodicopper(II) core vibrations

NASA Astrophysics Data System (ADS)

Drożdżewski, Piotr; Brożyna, Anna

2005-11-01

Vibrational spectra of tetrakis(acetato)diaquadicopper(II) complex have been deeply examined in order to provide a detailed description of dynamics of [Cu 2O 8C 4] core being a typical structural unit of most copper(II) carboxylates. Low frequency bands related to significant motions of metal atoms were detected by metal isotope substitution. Observed spectra and isotope shifts were reproduced in DFT calculations. For clear presentation of computed normal vibrations, a D 4h symmetry approximation was successfully applied. Basing on observed isotope shifts and calculation results, all skeletal vibrations have been analyzed including normal mode with the largest Cu ⋯Cu stretching amplitude assigned to Raman band at 178 cm -1.

Fast optical cooling of a nanomechanical cantilever by a dynamical Stark-shift gate.

PubMed

Yan, Leilei; Zhang, Jian-Qi; Zhang, Shuo; Feng, Mang

2015-10-12

The efficient cooling of nanomechanical resonators is essential to exploration of quantum properties of the macroscopic or mesoscopic systems. We propose such a laser-cooling scheme for a nanomechanical cantilever, which works even for the low-frequency mechanical mode and under weak cooling lasers. The cantilever is coupled by a diamond nitrogen-vacancy center under a strong magnetic field gradient and the cooling is assisted by a dynamical Stark-shift gate. Our scheme can effectively enhance the desired cooling efficiency by avoiding the off-resonant and undesired carrier transitions, and thereby cool the cantilever down to the vicinity of the vibrational ground state in a fast fashion.

Fast optical cooling of a nanomechanical cantilever by a dynamical Stark-shift gate

PubMed Central

Yan, Leilei; Zhang, Jian-Qi; Zhang, Shuo; Feng, Mang

2015-01-01

The efficient cooling of nanomechanical resonators is essential to exploration of quantum properties of the macroscopic or mesoscopic systems. We propose such a laser-cooling scheme for a nanomechanical cantilever, which works even for the low-frequency mechanical mode and under weak cooling lasers. The cantilever is coupled by a diamond nitrogen-vacancy center under a strong magnetic field gradient and the cooling is assisted by a dynamical Stark-shift gate. Our scheme can effectively enhance the desired cooling efficiency by avoiding the off-resonant and undesired carrier transitions, and thereby cool the cantilever down to the vicinity of the vibrational ground state in a fast fashion. PMID:26455901

Real-time vibration measurement by a spatial phase-shifting technique with a tilted holographic interferogram.

PubMed

Nakadate, S; Isshiki, M

1997-01-01

Real-time vibration measurement by a tilted holographic interferogram is presented that utilizes the real-time digital fringe processor of a video signal. Three intensity data sampled at every one-third of the fringe spacing of the tilted fringes are used to calculate the modulation term of the fringe that is a function of a vibration amplitude. A three-dimensional lookup table performs the calculation in a TV repetition rate to give a new fringe profile that contours the vibration amplitude. Vibration modes at the resonant frequencies of a flat speaker were displayed on a monitor as changing the exciting frequency of vibration.

Parametric Amplification Protocol for Frequency-Modulated Magnetic Resonance Force Microscopy Signals

NASA Astrophysics Data System (ADS)

Harrell, Lee; Moore, Eric; Lee, Sanggap; Hickman, Steven; Marohn, John

2011-03-01

We present data and theoretical signal and noise calculations for a protocol using parametric amplification to evade the inherent tradeoff between signal and detector frequency noise in force-gradient magnetic resonance force microscopy signals, which are manifested as a modulated frequency shift of a high- Q microcantilever. Substrate-induced frequency noise has a 1 / f frequency dependence, while detector noise exhibits an f2 dependence on modulation frequency f . Modulation of sample spins at a frequency that minimizes these two contributions typically results in a surface frequency noise power an order of magnitude or more above the thermal limit and may prove incompatible with sample spin relaxation times as well. We show that the frequency modulated force-gradient signal can be used to excite the fundamental resonant mode of the cantilever, resulting in an audio frequency amplitude signal that is readily detected with a low-noise fiber optic interferometer. This technique allows us to modulate the force-gradient signal at a sufficiently high frequency so that substrate-induced frequency noise is evaded without subjecting the signal to the normal f2 detector noise of conventional demodulation.

Ultrafast phosphate hydration dynamics in bulk H{sub 2}O

DOE Office of Scientific and Technical Information (OSTI.GOV)

Costard, Rene, E-mail: costard@mbi-berlin.de; Tyborski, Tobias; Fingerhut, Benjamin P., E-mail: fingerhut@mbi-berlin.de

2015-06-07

Phosphate vibrations serve as local probes of hydrogen bonding and structural fluctuations of hydration shells around ions. Interactions of H{sub 2}PO{sub 4}{sup −} ions and their aqueous environment are studied combining femtosecond 2D infrared spectroscopy, ab-initio calculations, and hybrid quantum-classical molecular dynamics (MD) simulations. Two-dimensional infrared spectra of the symmetric (ν{sub S}(PO{sub 2}{sup −})) and asymmetric (ν{sub AS}(PO{sub 2}{sup −})) PO{sub 2}{sup −} stretching vibrations display nearly homogeneous lineshapes and pronounced anharmonic couplings between the two modes and with the δ(P-(OH){sub 2}) bending modes. The frequency-time correlation function derived from the 2D spectra consists of a predominant 50 fs decaymore » and a weak constant component accounting for a residual inhomogeneous broadening. MD simulations show that the fluctuating electric field of the aqueous environment induces strong fluctuations of the ν{sub S}(PO{sub 2}{sup −}) and ν{sub AS}(PO{sub 2}{sup −}) transition frequencies with larger frequency excursions for ν{sub AS}(PO{sub 2}{sup −}). The calculated frequency-time correlation function is in good agreement with the experiment. The ν(PO{sub 2}{sup −}) frequencies are mainly determined by polarization contributions induced by electrostatic phosphate-water interactions. H{sub 2}PO{sub 4}{sup −}/H{sub 2}O cluster calculations reveal substantial frequency shifts and mode mixing with increasing hydration. Predicted phosphate-water hydrogen bond (HB) lifetimes have values on the order of 10 ps, substantially longer than water-water HB lifetimes. The ultrafast phosphate-water interactions observed here are in marked contrast to hydration dynamics of phospholipids where a quasi-static inhomogeneous broadening of phosphate vibrations suggests minor structural fluctuations of interfacial water.« less

An Extrinsic Fabry-Perot Interferometric Sensor using Intermodal Phase Shifting and Demultiplexing of the Propagating Modes in a Few-Mode Fiber

NASA Astrophysics Data System (ADS)

Chatterjee, Julius

This dissertation demonstrates a fiber-optic phase shifted Fabry-Perot interferometer (PS-FPI) as a sensor using modal demultiplexing. Single wavelength Fabry-Perot interferometers suffer from fringe ambiguity and loss of sensitivity at fringe extremes. These hindrances cause it to be a secondary choice when being selected for a measurement task at hand, and more often than not, white light based sensors are selected in favor of the single wavelength Fabry-Perot sensors. This work aims to introduce a technique involving the demultiplexing of the propagating linearly polarized (LP) modes in few mode fibers to obtain two fringe systems from the same sensing cavity. This results in a few-mode interferometer that effectively has two to three orders of magnitude higher perturbation sensitivity than a conventional few mode interferometer for the same sensing region. In this work, two different modal demultiplexing techniques (MD) are used to demodulate the propagating modes and to obtain two fringe sets. These output fringe sets are shifted in phase with respect to each other by a phase shift due to the propagation of the modes in the fiber-optic layout. A method of controlling this phase shift by straining a length of a two mode fiber located separate from the PS-FPI cavity is demonstrated and corresponding changes in phase shifts are shown. The results show a controllable phase shift for both the MD techniques, which is useful in sensing by permitting quadrature demodulation of interferometric fringes and also results in a novel few-mode sensing system having more than two orders of magnitude sensitivity than conventional few-mode devices.

LORETA EEG phase reset of the default mode network.

PubMed

Thatcher, Robert W; North, Duane M; Biver, Carl J

2014-01-01

The purpose of this study was to explore phase reset of 3-dimensional current sources in Brodmann areas located in the human default mode network (DMN) using Low Resolution Electromagnetic Tomography (LORETA) of the human electroencephalogram (EEG). The EEG was recorded from 19 scalp locations from 70 healthy normal subjects ranging in age from 13 to 20 years. A time point by time point computation of LORETA current sources were computed for 14 Brodmann areas comprising the DMN in the delta frequency band. The Hilbert transform of the LORETA time series was used to compute the instantaneous phase differences between all pairs of Brodmann areas. Phase shift and lock durations were calculated based on the 1st and 2nd derivatives of the time series of phase differences. Phase shift duration exhibited three discrete modes at approximately: (1) 25 ms, (2) 50 ms, and (3) 65 ms. Phase lock duration present primarily at: (1) 300-350 ms and (2) 350-450 ms. Phase shift and lock durations were inversely related and exhibited an exponential change with distance between Brodmann areas. The results are explained by local neural packing density of network hubs and an exponential decrease in connections with distance from a hub. The results are consistent with a discrete temporal model of brain function where anatomical hubs behave like a "shutter" that opens and closes at specific durations as nodes of a network giving rise to temporarily phase locked clusters of neurons for specific durations.

Undamped electrostatic plasma waves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Valentini, F.; Perrone, D.; Veltri, P.

2012-09-15

Electrostatic waves in a collision-free unmagnetized plasma of electrons with fixed ions are investigated for electron equilibrium velocity distribution functions that deviate slightly from Maxwellian. Of interest are undamped waves that are the small amplitude limit of nonlinear excitations, such as electron acoustic waves (EAWs). A deviation consisting of a small plateau, a region with zero velocity derivative over a width that is a very small fraction of the electron thermal speed, is shown to give rise to new undamped modes, which here are named corner modes. The presence of the plateau turns off Landau damping and allows oscillations withmore » phase speeds within the plateau. These undamped waves are obtained in a wide region of the (k,{omega}{sub R}) plane ({omega}{sub R} being the real part of the wave frequency and k the wavenumber), away from the well-known 'thumb curve' for Langmuir waves and EAWs based on the Maxwellian. Results of nonlinear Vlasov-Poisson simulations that corroborate the existence of these modes are described. It is also shown that deviations caused by fattening the tail of the distribution shift roots off of the thumb curve toward lower k-values and chopping the tail shifts them toward higher k-values. In addition, a rule of thumb is obtained for assessing how the existence of a plateau shifts roots off of the thumb curve. Suggestions are made for interpreting experimental observations of electrostatic waves, such as recent ones in nonneutral plasmas.« less

Bounce-harmonic Landau Damping of Plasma Waves

NASA Astrophysics Data System (ADS)

Anderegg, Francois

2015-11-01

We present measurement of plasma wave damping, spanning the temperature regimes of direct Landau damping, bounce-harmonic Landau damping, inter-species drag damping, and viscous damping. Direct Landau damping is dominant at high temperatures, but becomes negligible as v

Modal analysis of the thermal conductivity of nanowires: examining unique thermal transport features.

PubMed

Samaraweera, Nalaka; Larkin, Jason M; Chan, Kin L; Mithraratne, Kumar

2018-06-06

In this study, unique thermal transport features of nanowires over bulk materials are investigated using a combined analysis based on lattice dynamics and equilibrium molecular dynamics (EMD). The evaluation of the thermal conductivity (TC) of Lenard-Jones nanowires becomes feasible due to the multi-step normal mode decomposition (NMD) procedure implemented in the study. A convergence issue of the TC of nanowires is addressed by the NMD implementation for two case studies, which employ pristine nanowires (PNW) and superlattice nanowires. Interestingly, mode relaxation times at low frequencies of acoustic branches exhibit signs of approaching constant values, thus indicating the convergence of TC. The TC evaluation procedure is further verified by implementing EMD-based Green-Kubo analysis, which is based on a fundamentally different physical perspective. Having verified the NMD procedure, the non-monotonic trend of the TC of nanowires is addressed. It is shown that the principal cause for the observed trend is due to the competing effects of long wavelength phonons and phonon-surface scatterings as the nanowire's cross-sectional width is changed. A computational procedure is developed to decompose the different modal contribution to the TC of shell alloy nanowires (SANWs) using virtual crystal NMD and the Allen-Feldman theory. Several important conclusions can be drawn from the results. A propagons to non-propagons boundary appeared, resulting in a cut-off frequency (ω cut ); moreover, as alloy atomic mass is increased, ω cut shifts to lower frequencies. The existence of non-propagons partly causes the low TC of SANWs. It can be seen that modes with low frequencies demonstrate a similar behavior to corresponding modes of PNWs. Moreover, lower group velocities associated with higher alloy atomic mass resulted in a lower TC of SANWs.

Modal analysis of the thermal conductivity of nanowires: examining unique thermal transport features

NASA Astrophysics Data System (ADS)

Samaraweera, Nalaka; Larkin, Jason M.; Chan, Kin L.; Mithraratne, Kumar

2018-06-01

In this study, unique thermal transport features of nanowires over bulk materials are investigated using a combined analysis based on lattice dynamics and equilibrium molecular dynamics (EMD). The evaluation of the thermal conductivity (TC) of Lenard–Jones nanowires becomes feasible due to the multi-step normal mode decomposition (NMD) procedure implemented in the study. A convergence issue of the TC of nanowires is addressed by the NMD implementation for two case studies, which employ pristine nanowires (PNW) and superlattice nanowires. Interestingly, mode relaxation times at low frequencies of acoustic branches exhibit signs of approaching constant values, thus indicating the convergence of TC. The TC evaluation procedure is further verified by implementing EMD-based Green–Kubo analysis, which is based on a fundamentally different physical perspective. Having verified the NMD procedure, the non-monotonic trend of the TC of nanowires is addressed. It is shown that the principal cause for the observed trend is due to the competing effects of long wavelength phonons and phonon–surface scatterings as the nanowire’s cross-sectional width is changed. A computational procedure is developed to decompose the different modal contribution to the TC of shell alloy nanowires (SANWs) using virtual crystal NMD and the Allen–Feldman theory. Several important conclusions can be drawn from the results. A propagons to non-propagons boundary appeared, resulting in a cut-off frequency (ω cut); moreover, as alloy atomic mass is increased, ω cut shifts to lower frequencies. The existence of non-propagons partly causes the low TC of SANWs. It can be seen that modes with low frequencies demonstrate a similar behavior to corresponding modes of PNWs. Moreover, lower group velocities associated with higher alloy atomic mass resulted in a lower TC of SANWs.

Terahertz surface plasmon resonance sensor for material sensing

NASA Astrophysics Data System (ADS)

Hailu, Daniel M.; Alqarni, Sondos; Cui, Bo; Saeedkia, Daryoosh

2013-10-01

This paper presents the use of Terahertz (THz) SPR near-field sensor to characterize materials such as PMMA and those used in organic light emitting diode (OLED). The SPR device contains 2D periodic circular or square hole array in 500 nm Al on an 5 mm-thick intrinsic silicon, and was fabricated by photolithography and wet etching. For THz spectrum measurement, the SPR device with and without thin (PMMA) film on it is placed at the focus of the THz beam in transmission THz Time Domain Spectroscopy (TDS), where the spectrum is obtained from the Fourier-transformed sample and reference THz pulses. The transmission is obtained from the ratio between the sample spectrum and reference spectrum, whereas the phase change is the phase difference between the two spectra. To avoid overlap with water absorption lines, the optimal SPR device design has a period of 320 μm and square holes of 150 μm side length. The theoretical SPR frequencies in the THz range are determined for the metal-silicon modes and metal-air modes (0.9375 THz for mode (0, 1) at the metal-air interface). The measurement results confirmed the theoretical SPR frequencies for metal-silicon mode and demonstrate a shift to 0.9211 THz due to 2 μm of PMMA layer on the surface.

Electron-transfer boat-vibration mechanism for superconductivity in organic molecules based on BEDT-TTF

DOE Office of Scientific and Technical Information (OSTI.GOV)

Demiralp, E.; Dasgupta, S.; Goddard, W.A. III

1995-08-09

The highest T{sub c} organic superconductors all involve the organic molecule bis(ethylenedithio)tetrathiafulvalene (denoted as BEDT-TTF or ET) coupled with an appropriate acceptor. This leads to ET, ET{sup +}, or (ET){sub 2}{sup +} species in the crystal. Using ab initio Hartree-Fock calculations (6-31G** basis set), we show that ET deforms to a boat structure with an energy 28 meV (0.65 kcal/mol) lower than that of planar ET (D{sub 2} symmetry). On the other hand, ET{sup +} is planar. Thus, conduction in this system leads to a coupling between charge transfer and the boat deformation vibrational modes at 20 cm{sup -1} (ET)more » and 28 cm{sup -1} (ET{sup +}). We suggest that this electron-phonon coupling is responsible for the superconductivity and predict the isotope shifts ({delta}T{sub c}) for experimental tests of the electron-transfer boat-vibration (ET-BV) mechanism. The low frequency of this boat mode and its coupling to various lattice modes could explain the sensitivity of T{sub c} to defects, impurities, and pressure. We suggest that new higher temperature organic donors can be sought by finding modifications that change the frequency and stability of this boat distortion mode. 25 refs., 5 figs., 4 tabs.« less

Effect of chromium doping on the structural and vibrational properties of Mn-Zn ferrites

NASA Astrophysics Data System (ADS)

Saleem, M.; Varshney, Dinesh

2018-05-01

The synthesis of Mn0.5Zn0.5-xCrxFe2O4 (x = 0.0, 0.1, 0.2 and 0.5) via sol-gel Auto-combustion technique is reported. The x-ray diffraction spectra analysis revealed the cubic spinel structure for all the prepared spinel ferrite samples with the space group Fd3m. The structural studies identify the decrease of lattice parameter however the crystallite size decreases on increasing the Cr concentration. The Raman spectrum reveals five active phonon modes at room temperature and shifting of modes toward the higher frequency side on moving from Mn-ZnFe2O4 to Mn-CrFe2O4.

CORRELATED ERRORS IN EARTH POINTING MISSIONS

NASA Technical Reports Server (NTRS)

Bilanow, Steve; Patt, Frederick S.

2005-01-01

Two different Earth-pointing missions dealing with attitude control and dynamics changes illustrate concerns with correlated error sources and coupled effects that can occur. On the OrbView-2 (OV-2) spacecraft, the assumption of a nearly-inertially-fixed momentum axis was called into question when a residual dipole bias apparently changed magnitude. The possibility that alignment adjustments and/or sensor calibration errors may compensate for actual motions of the spacecraft is discussed, and uncertainties in the dynamics are considered. Particular consideration is given to basic orbit frequency and twice orbit frequency effects and their high correlation over the short science observation data span. On the Tropical Rainfall Measuring Mission (TRMM) spacecraft, the switch to a contingency Kalman filter control mode created changes in the pointing error patterns. Results from independent checks on the TRMM attitude using science instrument data are reported, and bias shifts and error correlations are discussed. Various orbit frequency effects are common with the flight geometry for Earth pointing instruments. In both dual-spin momentum stabilized spacecraft (like OV-2) and three axis stabilized spacecraft with gyros (like TRMM under Kalman filter control), changes in the initial attitude state propagate into orbit frequency variations in attitude and some sensor measurements. At the same time, orbit frequency measurement effects can arise from dynamics assumptions, environment variations, attitude sensor calibrations, or ephemeris errors. Also, constant environment torques for dual spin spacecraft have similar effects to gyro biases on three axis stabilized spacecraft, effectively shifting the one-revolution-per-orbit (1-RPO) body rotation axis. Highly correlated effects can create a risk for estimation errors particularly when a mission switches an operating mode or changes its normal flight environment. Some error effects will not be obvious from attitude sensor measurement residuals, so some independent checks using imaging sensors are essential and derived science instrument attitude measurements can prove quite valuable in assessing the attitude accuracy.

Theoretical investigation on the molecular structure, Infrared, Raman and NMR spectra of para-halogen benzenesulfonamides, 4-X-C 6H 4SO 2NH 2 (X = Cl, Br or F)

NASA Astrophysics Data System (ADS)

Karabacak, Mehmet; Çınar, Mehmet; Çoruh, Ali; Kurt, Mustafa

2009-02-01

In the present study, the structural properties of para-halogen benzenesulfonamides, 4-XC 6H 4SO 2NH 2 (4-chlorobenzenesulfonamide (I), 4-bromobenzenesulfonamide (II) and 4-fluorobenzenesulfonamide (III)) have been studied extensively utilizing ab initio Hartree-Fock (HF) and density functional theory (DFT) employing B3LYP exchange correlation. The vibrational frequencies were calculated and scaled values were compared with experimental values. The complete assignments were performed on the basis of the total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanics (SQM) method. The effects of the halogen substituent on the characteristic benzenesulfonamides bands in the spectra are discussed. The 1H and 13C nuclear magnetic resonance (NMR) chemical shifts of the molecules were calculated using the Gauge-Invariant Atomic Orbital (GIAO) method. Finally, geometric parameters, vibrational bands and chemical shifts were compared with available experimental data of the molecules. The fully optimized geometries of the molecules were found to be consistent with the X-ray crystal structures. The observed and calculated frequencies and chemical shifts were found to be in very good agreement.

Strain of laser annealed silicon surfaces

NASA Astrophysics Data System (ADS)

Nemanich, R. J.; Haneman, D.

1982-05-01

High resolution Raman scattering measurements have been carried out on pulse and continuous-wave laser annealed silicon samples with various surface preparations. These included polished and ion-bombarded wafers, and saw-cut crystals. The pulse annealing treatments were carried out in ultrahigh vacuum and in air. The residual strain was inferred from the frequency shift of the first-order Raman active mode of Si, and was detectable in the range 10-2-10-3 in all except the polished samples.

Infrared signature of micro-hydration in the organophosphate sarin: An ab initio study

DOE PAGES

Alam, Todd M.; Pearce, Charles Joseph

2015-06-28

The infrared (IR) spectra of micro-hydrated Sarin•(H 2O) n clusters containing between one and four explicit waters have been studied using ab initio density functional theory (DFT) methods. The phosphate group P=O bond vibration region (~1270 to 1290 cm –1) revealed the largest frequency variation with hydration, with a frequency red shift reflecting the direct hydrogen bond formation between the P=O of Sarin and water. Small variations to the P-F stretch (~810 to 815 cm –1) and the C-O-P vibrational modes (~995 to 1004 cm –1) showed that the water interactions with these functional groups were minor, and that themore » structures of Sarin were not extensively perturbed in the hydrated complexes. Increasing the number of explicit hydration waters produced only small vibrational changes in the lowest free energy complexes. These minor changes were consistent with a single water-phosphate hydrogen bond being the dominant structure, though a second water-phosphate hydrogen bond was observed in some complexes and was identified by an additional red shift of the P=O bond vibration. As a result, the H 2O•H 2O vibrational modes (~3450 to 3660 cm –1) increased in complexity with higher hydration levels and reflect the extended hydrogen bonding networks formed between the explicit waters in the hydrated Sarin clusters.« less

Regime shift of Indian summer monsoon rainfall to a persistent arid state: external forcing versus internal variability

NASA Astrophysics Data System (ADS)

Srivastava, Ankur; Pradhan, Maheswar; Goswami, B. N.; Rao, Suryachandra A.

2017-11-01

The high propensity of deficient monsoon rainfall over the Indian sub-continent in the recent 3 decades (seven deficient monsoons against 3 excess monsoon years) compared to the prior 3 decades has serious implications on the food and water resources in the country. Motivated by the need to understand the high occurrence of deficient monsoon during this period, we examine the change in predictability of the Indian summer monsoon (ISM) and its teleconnections with Indo-Pacific sea surface temperatures between the two periods. The shift in the tropical climate in the late 1970s appears to be one of the major reasons behind this. We find an increased predictability of the ISM in the recent 3 decades owing to reduced `internal' interannual variability (IAV) due to the high-frequency modes, while the `external' IAV arising from the low-frequency modes has remained largely the same. The Indian Ocean Dipole-ISM teleconnection has become positive during the monsoon season in the recent period thereby compensating for the weakened ENSO-ISM teleconnection. The central Pacific El-Niño and the Indian Ocean (IO) warming during the recent 3 decades are working together to realise enhanced ascending motion in the equatorial IO between 70°E and 100°E, preconditioning the Indian monsoon system prone to a deficient state.

Temperature Dependence in the Terahertz Spectrum of Nicotinamide: Anharmonicity and Hydrogen-Bonded Network.

PubMed

Takahashi, Masae; Okamura, Nubuyuki; Fan, Xinyi; Shirakawa, Hitoshi; Minamide, Hiroaki

2017-04-06

We have investigated the terahertz-spectral property of nicotinamide focusing on the temperature dependence in the range of 14-300 K. We observed that almost all peaks in the terahertz spectrum of the nicotinamide crystal showed a remarkable shift with temperature, whereas the lowest-frequency peak at 34.8 cm -1 showed a negligible shift with temperature. By analyzing the terahertz spectrum with the dispersion-corrected density functional theory calculations, we found that the difference in the temperature dependence of the peak shift is well understood in terms of the presence/absence of stretching vibration of the intermolecular hydrogen bond in the mode and the change of cell parameters. The anharmonicity in the dissociation potential energy of very weak intermolecular hydrogen bonding causes the remarkable peak shift with temperature in the terahertz spectrum of nicotinamide. This finding suggests that the assignment and identification of peaks in the terahertz spectrum are systematically enabled by temperature-dependent measurements.

Behavior of a Light Solid in a Rotating Horizontal Cylinder with Liquid Under Vibration

NASA Astrophysics Data System (ADS)

Karpunin, I. E.; Kozlova, A. N.; Kozlov, N. V.

2018-06-01

Dynamics of a cylindrical body in a rotating cavity is experimentally studied under transversal translational vibrations of the cavity rotation axis. Experiments are run at high rotation rate, when under the action of centrifugal force the body shifts to the rotation axis (the centrifuged state). In the absence of vibrations, the lagging rotation of the body is observed, due to the body radial shift from the axis of rotation caused by gravity. The body average rotation regime depends on the cavity rotation rate. The vibrations lead to the excitation of different regimes of body differential rotation (leading or lagging) associated with the excitation of its inertial oscillations. The dependence of the differential speed of the body rotation on the vibration frequency is investigated. The body dynamics has a complex character depending on the dimensionless vibration frequency. The analysis of body oscillation trajectory revealed that the body oscillatory motion consists of several modes, which contribute to the averaged dynamics of the body and the flows in the cavity.

A experiment on radio location of objects in the near-Earth space with VLBI in 2012

NASA Astrophysics Data System (ADS)

Nechaeva, M.; Antipenko, A.; Bezrukovs, V.; Bezrukov, D.; Dementjev, A.; Dugin, N.; Konovalenko, A.; Kulishenko, V.; Liu, X.; Nabatov, A.; Nesteruk, V.; Pupillo, G.; Reznichenko, A.; Salerno, E.; Shmeld, I.; Shulga, O.; Sybiryakova, Y.; Tikhomirov, Yu.; Tkachenko, A.; Volvach, A.; Yang, W.-J.

An experiment on radar location of space debris objects using of the method of VLBI was carried out in April, 2012. The radar VLBI experiment consisted in irradiation of some space debris objects (4 rocket stages and 5 inactive satellites) with a signal of the transmitter with RT-70 in Evpatoria, Ukraine. Reflected signals were received by a complex of radio telescopes in the VLBI mode. The following VLBI stations took part in the observations: Ventspils (RT-32), Urumqi (RT-25), Medicina (RT-32) and Simeiz (RT-22). The experiment included measurements of the Doppler frequency shift and the delay for orbit refining, and measurements of the rotation period and sizes of objects by the amplitudes of output interferometer signals. The cross-correlation of VLBI-data is performed at a correlator NIRFI-4 of Radiophysical Research Institute (Nizhny Novgorod). Preliminary data processing resulted in the series of Doppler frequency shifts, which comprised the information on radial velocities of the objects. Some results of the experiment are presented.

Spectrally- and Time-Resolved Sum Frequency Generation (STiR-SFG): a new tool for ultrafast hydrogen bond dynamics at interfaces.

NASA Astrophysics Data System (ADS)

Benderskii, Alexander; Bordenyuk, Andrey; Weeraman, Champika

2006-03-01

The recently developed spectrally- and time-resolved Sum Frequency Generation (STiR-SFG) is a surface-selective 3-wave mixing (IR+visible) spectroscopic technique capable of measuring ultrafast spectral evolution of vibrational coherences. A detailed description of this measurement will be presented, and a noniterative method or deconvolving the laser pulses will be introduced to obtain the molecular response function. STiR-SFG, combined with the frequency-domain SFG spectroscopy, was applied to study hydrogen bonding dynamics at aqueous interfaces (D2O/CaF2). Spectral dynamics of the OD-stretch on the 50-150 fs time scale provides real-time observation of ultrafast H-bond rearrangement. Tuning the IR wavelength to the blue or red side of the OD-stretch transition, we selectively monitor the dynamics of different sub-ensembles in the distribution of the H-bond structures. The blue-side excitation (weaker H-bonding) shows monotonic red-shift of the OD-frequency. In contrast, the red-side excitation (stronger H-bonding structures) produces a blue-shift and a recursion, which may indicate the presence of an underdamped intermolecular mode of interfacial water. Effect of electrolyte concentration on the H-bond dynamics will be discussed.

The vibrational spectrum of H2O3: An ab initio investigation

NASA Technical Reports Server (NTRS)

Jackels, Charles F.

1991-01-01

Theoretically determined frequencies and absorption intensities are reported for the vibrational spectrum of the covalent HOOOH and hydrogen bonded HO---HOO intermediates that may form in the reaction of the hydroxyl and hydroperoxyl radicals. Basis sets of DZP quality, augmented by diffuse and second sets of polarization functions have been used with CASSCF wave functions. The calculated harmonic vibrational frequencies of HOOOH have been corrected with empirical factors and presented in the form of a 'stick' spectrum. The oxygen backbone vibrations, predicted to occur at 519, 760, and 870 cm(exp -1), are well separated from most interferences, and may be the most useful for the species' identification. In the case of the hydrogen bonded isomer, emphasis has been placed upon prediction of the shifts in the intramolecular vibrational frequencies that take place upon formation of the complex. In particular, the HO stretch and HOO bend of HO2 are predicted to have shifts of -59 and 53 cm(exp -1), respectively, which should facilitate their identification. It is also noted that the antisymmetric stretching frequency of the oxygen backbone in HOOOH exhibits a strong sensitivity to the degree of electron correlation, such as has been previously observed for the same mode in ozone.

Noble Gas-Uranium Coordination and Intersystem Crossing for the CUO(Ne)x(Ng)n (Ng = Ar, Kr, Xe) Complexes in Solid Neon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andrews, Lester; Liang, Binyong; Li, Jun

2004-02-15

Atomic uranium excited by laser ablation reacts with CO in excess neon to produce the novel CUO molecule, which forms weak complexes CUO(Ne)m with neon and stronger complexes CUO(Ne)x(Ng)n (Ng = Ar, Kr, Xe) when the heavier noble gas atoms are present. The heavier CUO(Ne)m-1(Ng) complexes are identified through the effects of CO isotopic and Ng substitution on the neon matrix infrared spectra and by comparison to DFT frequency calculations on model complexes CUO(Ng) (Ng = Ne, Ar, Kr, Xe). The U-C and U-O stretching frequencies of CUO(Ne)m-1(Ng) complexes are slightly red shifted from 1047 and 872 cm-1 frequencies formore » the 1Sigma+ CUO ground state neon complex, which identifies singlet ground state CUO(Ne)m-1(Ng) complexes in solid neon. The next singlet CUO(Ne)x(Ng)2 complexes in excess neon follow in like manner. However, stretching modes and the isotopic shifts of the higher CUO(Ne)x(Ng)n complex approach those of the pure argon matrix CUO(Ar)n complex, which characterizes triple t ground state complexes by comparison to DFT frequency calculations.« less

Tunable Magnetic Resonance in Microwave Spintronics Devices

NASA Technical Reports Server (NTRS)

Chen, Yunpeng; Fan, Xin; Xie, Yunsong; Zhou, Yang; Wang, Tao; Wilson, Jeffrey D.; Simons, Rainee N.; Chui, Sui-Tat; Xiao, John Q.

2015-01-01

Magnetic resonance is one of the key properties of magnetic materials for the application of microwave spintronics devices. The conventional method for tuning magnetic resonance is to use an electromagnet, which provides very limited tuning range. Hence, the quest for enhancing the magnetic resonance tuning range without using an electromagnet has attracted tremendous attention. In this paper, we exploit the huge exchange coupling field between magnetic interlayers, which is on the order of 4000 Oe and also the high frequency modes of coupled oscillators to enhance the tuning range. Furthermore, we demonstrate a new scheme to control the magnetic resonance frequency. Moreover, we report a shift in the magnetic resonance frequency as high as 20 GHz in CoFe based tunable microwave spintronics devices, which is 10X higher than conventional methods.

Tunable Magnetic Resonance in Microwave Spintronics Devices

NASA Technical Reports Server (NTRS)

Chen, Yunpeng; Fan, Xin; Xie, Yungsong; Zhou, Yang; Wang, Tao; Wilson, Jeffrey D.; Simons, Rainee N.; Chui, Sui-Tat; Xiao, John Q.

2015-01-01

Magnetic resonance is one of the key properties of magnetic materials for the application of microwave spintronics devices. The conventional method for tuning magnetic resonance is to use an electromagnet, which provides very limited tuning range. Hence, the quest for enhancing the magnetic resonance tuning range without using an electromagnet has attracted tremendous attention. In this paper, we exploit the huge exchange coupling field between magnetic interlayers, which is on the order of 4000 Oe and also the high frequency modes of coupled oscillators to enhance the tuning range. Furthermore, we demonstrate a new scheme to control the magnetic resonance frequency. Moreover, we report a shift in the magnetic resonance frequency as high as 20 GHz in CoFe-based tunable microwave spintronics devices, which is 10X higher than conventional methods.

Viscous Overstability in Saturn's B-Ring. II. Hydrodynamic Theory and Comparison to Simulations

NASA Astrophysics Data System (ADS)

Schmidt, Jürgen; Salo, Heikki; Spahn, Frank; Petzschmann, Olaf

2001-10-01

We investigate the viscous oscillatory instability (overstability) of an unperturbed dense planetary ring, an instability that might play a role in the formation of radial structure in Saturn's B-ring. We generalize existing hydrodynamic models by including the heat flow equation in the analysis and compare our results to the development of overstable modes in local particle simulations. With the heat flow, in addition to the balance equations for mass and momentum, we take into account the balance law for the energy of the random motion; i.e., we allow for a thermal mode in a stability analysis of the stationary Keplerian flow. We also incorporate the effects of nonlocal transport of momentum and energy on the stability of the ring. In a companion paper (Salo, H., J. Schmidt, and F. Spahn 2001. Icarus, doi:10.1006/icar.2001.6680) we describe the determination of the local and nonlocal parts of the viscosity, the heat conductivity, the pressure, as well as the collisional cooling, together with their dependences on temperature and density, in local event-driven simulations of a planetary ring. The ring's self-gravity is taken into account in these simulations by an enhancement of the frequency of vertical oscillations Ω z>Ω. We use these values as parameters in our hydrodynamic model for the comparison to overstability in simulated rings of meter-sized inelastic particles of large optical depth with Ω z/Ω=3.6. We find that the inclusion of the energy-balance equation has a stabilizing influence on the overstable modes, shifting the stability boundary to higher optical depths, and moderating the growth rates of the instability, as compared to a purely isothermal treatment. The non-isothermal model predicts correctly the growth rates and oscillation frequencies of overstable modes in the simulations, as well as the phase shifts and relative amplitudes of the perturbations in density and radial and tangential velocity.

Tolerance of the frequency deviation of LO sources at a MIMO system

NASA Astrophysics Data System (ADS)

Xiao, Jiangnan; Li, Xingying; Zhang, Zirang; Xu, Yuming; Chen, Long; Yu, Jianjun

2015-11-01

We analyze and simulate the tolerance of frequency offset at a W-band optical-wireless transmission system. The transmission system adopts optical polarization division multiplexing (PDM), and multiple-input multiple-output (MIMO) reception. The transmission signal adopts optical quadrature phase shift keying (QPSK) modulation, and the generation of millimeter-wave is based on the optical heterodyning technique. After 20-km single-mode fiber-28 (SMF-28) transmission, tens of Gb/s millimeter-wave signal is delivered. At the receiver, two millimeter-wave signals are down-converted into electrical intermediate-frequency (IF) signals in the analog domain by mixing with two electrical local oscillators (LOs) with different frequencies. We investigate the different frequency LO effect on the 2×2 MIMO system performance for the first time, finding that the process during DSP of implementing frequency offset estimation (FOE) before cascaded multi-modulus-algorithm (CMMA) equalization can get rid of the inter-channel interference (ICI) and improve system bit-error-ratio (BER) performance in this type of transmission system.

Demonstration of a near-IR line-referenced electro-optical laser frequency comb for precision radial velocity measurements in astronomy.

PubMed

Yi, X; Vahala, K; Li, J; Diddams, S; Ycas, G; Plavchan, P; Leifer, S; Sandhu, J; Vasisht, G; Chen, P; Gao, P; Gagne, J; Furlan, E; Bottom, M; Martin, E C; Fitzgerald, M P; Doppmann, G; Beichman, C

2016-01-27

An important technique for discovering and characterizing planets beyond our solar system relies upon measurement of weak Doppler shifts in the spectra of host stars induced by the influence of orbiting planets. A recent advance has been the introduction of optical frequency combs as frequency references. Frequency combs produce a series of equally spaced reference frequencies and they offer extreme accuracy and spectral grasp that can potentially revolutionize exoplanet detection. Here we demonstrate a laser frequency comb using an alternate comb generation method based on electro-optical modulation, with the comb centre wavelength stabilized to a molecular or atomic reference. In contrast to mode-locked combs, the line spacing is readily resolvable using typical astronomical grating spectrographs. Built using commercial off-the-shelf components, the instrument is relatively simple and reliable. Proof of concept experiments operated at near-infrared wavelengths were carried out at the NASA Infrared Telescope Facility and the Keck-II telescope.

Demonstration of a near-IR line-referenced electro-optical laser frequency comb for precision radial velocity measurements in astronomy

PubMed Central

Yi, X.; Vahala, K.; Li, J.; Diddams, S.; Ycas, G.; Plavchan, P.; Leifer, S.; Sandhu, J.; Vasisht, G.; Chen, P.; Gao, P.; Gagne, J.; Furlan, E.; Bottom, M.; Martin, E. C.; Fitzgerald, M. P.; Doppmann, G.; Beichman, C.

2016-01-01

An important technique for discovering and characterizing planets beyond our solar system relies upon measurement of weak Doppler shifts in the spectra of host stars induced by the influence of orbiting planets. A recent advance has been the introduction of optical frequency combs as frequency references. Frequency combs produce a series of equally spaced reference frequencies and they offer extreme accuracy and spectral grasp that can potentially revolutionize exoplanet detection. Here we demonstrate a laser frequency comb using an alternate comb generation method based on electro-optical modulation, with the comb centre wavelength stabilized to a molecular or atomic reference. In contrast to mode-locked combs, the line spacing is readily resolvable using typical astronomical grating spectrographs. Built using commercial off-the-shelf components, the instrument is relatively simple and reliable. Proof of concept experiments operated at near-infrared wavelengths were carried out at the NASA Infrared Telescope Facility and the Keck-II telescope. PMID:26813804

Lamb Shift in the Near Field of Hyperbolic Metamaterial Half Space

NASA Astrophysics Data System (ADS)

Deng, Nai Jing; Yu, Kin Wah

2013-03-01

Hyperbolic metamaterials give a large magnification of the density of states in a specific frequency ranges, and has motivated various applications in emission lifetime reduction, strong absorption, and extraordinary black body radiation, etc. The boost of vacuum energy, which is proportional to the density of states, is expected in hyperbolic metamaterial. We have studied the Lamb shift in vacuum-hyperbolic-metamterial half spaces and shown the non-trivial role of vacuum energy. In our calculation, the easy-fabricated multilayer structure is employed to generate a hyperbolic dispersion relation. The spectrum of hydrogen atoms is calculated with a perturbation method after quantizing the half spaces with a complete mode expansion. It appears that the shift of spectrum is mainly contributed by the terahertz response of materials, which has been well described and predicted in both theories and experiments. Work supported by the General Research Fund of the Hong Kong SAR Government

Ab initio and classical molecular dynamics studies of the structural and dynamical behavior of water near a hydrophobic graphene sheet.

PubMed

Rana, Malay Kumar; Chandra, Amalendu

2013-05-28

The behavior of water near a graphene sheet is investigated by means of ab initio and classical molecular dynamics simulations. The wetting of the graphene sheet by ab initio water and the relation of such behavior to the strength of classical dispersion interaction between surface atoms and water are explored. The first principles simulations reveal a layered solvation structure around the graphene sheet with a significant water density in the interfacial region implying no drying or cavitation effect. It is found that the ab initio results of water density at interfaces can be reproduced reasonably well by classical simulations with a tuned dispersion potential between the surface and water molecules. Calculations of vibrational power spectrum from ab initio simulations reveal a shift of the intramolecular stretch modes to higher frequencies for interfacial water molecules when compared with those of the second solvation later or bulk-like water due to the presence of free OH modes near the graphene sheet. Also, a weakening of the water-water hydrogen bonds in the vicinity of the graphene surface is found in our ab initio simulations as reflected in the shift of intermolecular vibrational modes to lower frequencies for interfacial water molecules. The first principles calculations also reveal that the residence and orientational dynamics of interfacial water are somewhat slower than those of the second layer or bulk-like molecules. However, the lateral diffusion and hydrogen bond relaxation of interfacial water molecules are found to occur at a somewhat faster rate than that of the bulk-like water molecules. The classical molecular dynamics simulations with tuned Lennard-Jones surface-water interaction are found to produce dynamical results that are qualitatively similar to those of ab initio molecular dynamics simulations.

Dynamically reconfigurable holographic metasurface aperture for a Mills-Cross monochromatic microwave camera.

PubMed

Yurduseven, Okan; Marks, Daniel L; Fromenteze, Thomas; Smith, David R

2018-03-05

We present a reconfigurable, dynamic beam steering holographic metasurface aperture to synthesize a microwave camera at K-band frequencies. The aperture consists of a 1D printed microstrip transmission line with the front surface patterned into an array of slot-shaped subwavelength metamaterial elements (or meta-elements) dynamically tuned between "ON" and "OFF" states using PIN diodes. The proposed aperture synthesizes a desired radiation pattern by converting the waveguide-mode to a free space radiation by means of a binary modulation scheme. This is achieved in a holographic manner; by interacting the waveguide-mode (reference-wave) with the metasurface layer (hologram layer). It is shown by means of full-wave simulations that using the developed metasurface aperture, the radiated wavefronts can be engineered in an all-electronic manner without the need for complex phase-shifting circuits or mechanical scanning apparatus. Using the dynamic beam steering capability of the developed antenna, we synthesize a Mills-Cross composite aperture, forming a single-frequency all-electronic microwave camera.

Faraday spectroscopy of ultracold atoms guided in hollow core optical fibers

NASA Astrophysics Data System (ADS)

Fatemi, Fredrik; Pechkis, Joseph

2013-05-01

We have performed spatially and temporally resolved magnetometry using Faraday spectroscopy of ultracold rubidium atoms confined in hollow core optical fibers. We first guide 105 Rb atoms into a 3-cm-long, 100-micron-core hollow fiber using blue-detuned hollow waveguide modes. Inside the fiber, the atoms are exposed to an optical pumping pulse, and the Larmor precession is monitored by the polarization rotation of a probe laser beam detuned by 50 GHz. The intense guide beams can perturb the detected Larmor precession frequencies, but we show that by confining the atoms to the intensity null of higher order blue-detuned hollow modes, these perturbations are reduced by over 95% compared to red-detuned guides. By adjusting the guide beam detuning and polarization, the deleterious effects of both photon scattering and frequency shifts can be suppressed such that multiple magnetic field measurements with sensitivity of 30 nT per sampling pulse can be obtained throughout the length of the fiber in a single loading cycle. Work supported by ONR and DARPA.

Ultrafast Solvation Dynamics and Vibrational Coherences of Halogenated Boron-Dipyrromethene Derivatives Revealed through Two-Dimensional Electronic Spectroscopy.

PubMed

Lee, Yumin; Das, Saptaparna; Malamakal, Roy M; Meloni, Stephen; Chenoweth, David M; Anna, Jessica M

2017-10-18

Boron-dipyrromethene (BODIPY) chromophores have a wide range of applications, spanning areas from biological imaging to solar energy conversion. Understanding the ultrafast dynamics of electronically excited BODIPY chromophores could lead to further advances in these areas. In this work, we characterize and compare the ultrafast dynamics of halogenated BODIPY chromophores through applying two-dimensional electronic spectroscopy (2DES). Through our studies, we demonstrate a new data analysis procedure for extracting the dynamic Stokes shift from 2DES spectra revealing an ultrafast solvent relaxation. In addition, we extract the frequency of the vibrational modes that are strongly coupled to the electronic excitation, and compare the results of structurally different BODIPY chromophores. We interpret our results with the aid of DFT calculations, finding that structural modifications lead to changes in the frequency, identity, and magnitude of Franck-Condon active vibrational modes. We attribute these changes to differences in the electron density of the electronic states of the structurally different BODIPY chromophores.

Anatomical and functional assemblies of brain BOLD oscillations

PubMed Central

Baria, Alexis T.; Baliki, Marwan N.; Parrish, Todd; Apkarian, A. Vania

2011-01-01

Brain oscillatory activity has long been thought to have spatial properties, the details of which are unresolved. Here we examine spatial organizational rules for the human brain oscillatory activity as measured by blood oxygen level-dependent (BOLD). Resting state BOLD signal was transformed into frequency space (Welch’s method), averaged across subjects, and its spatial distribution studied as a function of four frequency bands, spanning the full bandwidth of BOLD. The brain showed anatomically constrained distribution of power for each frequency band. This result was replicated on a repository dataset of 195 subjects. Next, we examined larger-scale organization by parceling the neocortex into regions approximating Brodmann Areas (BAs). This indicated that BAs of simple function/connectivity (unimodal), vs. complex properties (transmodal), are dominated by low frequency BOLD oscillations, and within the visual ventral stream we observe a graded shift of power to higher frequency bands for BAs further removed from the primary visual cortex (increased complexity), linking frequency properties of BOLD to hodology. Additionally, BOLD oscillation properties for the default mode network demonstrated that it is composed of distinct frequency dependent regions. When the same analysis was performed on a visual-motor task, frequency-dependent global and voxel-wise shifts in BOLD oscillations could be detected at brain sites mostly outside those identified with general linear modeling. Thus, analysis of BOLD oscillations in full bandwidth uncovers novel brain organizational rules, linking anatomical structures and functional networks to characteristic BOLD oscillations. The approach also identifies changes in brain intrinsic properties in relation to responses to external inputs. PMID:21613505

Lateral interactions in (NO+O) coadsorbate layers on Ru(001): fundamental and overtone modes

NASA Astrophysics Data System (ADS)

Jakob, P.

1999-06-01

A systematic investigation of various (NO+O) coadsorbate layers on Ru(001) is presented. By using infrared absorption spectroscopy, fundamental and overtone bands were studied in a wide temperature range to extract dynamical information on lifetime broadening (low-temperature limit) and dephasing behavior (thermal broadening and line shifts). The layers studied were (1) 3NO-(2×2)/Ru(001), (2) (2NO+O)(2×2)/Ru(001) and (3) (NO+2O)(2×2)/Ru(001). It is found that replacing hollow-site NO by oxygen atoms causes characteristic frequency shifts of νRu-NO and νN-O of linearly bond on-top NO which is present for all three layers. In agreement with earlier results on CO/Ru(001) and with theoretical prediction, the νN-O″ overtone band displays rapid broadening with increasing temperature (about four times faster than the respective localized νN-O fundamental band) while the temperature-dependent line shift and the 0 K linewidth is twice as high as observed for νN-O. An unusually large bandwidth close to 100 cm -1 is found for the νN-O mode of the row-like (NO+O)(2×1)/Ru(001) overlayer.

Vibrating Optical Fibers to Make Laser Speckle Disappear

NASA Technical Reports Server (NTRS)

McGill, Matthew; Scott, V. Stanley

2005-01-01

In optical systems in which laser illumination is delivered via multimode optical fibers, laser speckle can be rendered incoherent by a simple but highly effective technique. The need to eliminate speckle arises because speckle can make it difficult to observe edges and other sharp features, thereby making it difficult to perform precision alignment of optical components. The basic ideas of the technique is to vibrate the optical fiber(s) to cause shifting of electromagnetic modes within the fiber(s) and consequent shifting of the speckle pattern in the light emerging from the fiber(s). If the frequency of vibration is high enough, a human eye cannot follow the shifting speckle pattern, so that instead of speckle, a human observer sees a smoothed pattern of light corresponding to a mixture of many electromagnetic modes. If necessary, the optical fiber(s) could be vibrated manually. However, in a typical laboratory situation, it would be more practical to attach a vibrating mechanism to the fiber(s) for routine use as part of the fiber-optic illuminator. In experiments, a commercially available small, gentle, quiet, variable- speed vibratory device was used in this way, with the result that the appearance of speckle was eliminated, as expected. Figures 1 and 2 illustrate the difference.

On the relationship between large-scale climate modes and regional synoptic patterns that drive Victorian rainfall

NASA Astrophysics Data System (ADS)

Verdon-Kidd, D. C.; Kiem, A. S.

2009-04-01

In this paper regional (synoptic) and large-scale climate drivers of rainfall are investigated for Victoria, Australia. A non-linear classification methodology known as self-organizing maps (SOM) is used to identify 20 key regional synoptic patterns, which are shown to capture a range of significant synoptic features known to influence the climate of the region. Rainfall distributions are assigned to each of the 20 patterns for nine rainfall stations located across Victoria, resulting in a clear distinction between wet and dry synoptic types at each station. The influence of large-scale climate modes on the frequency and timing of the regional synoptic patterns is also investigated. This analysis revealed that phase changes in the El Niño Southern Oscillation (ENSO), the Indian Ocean Dipole (IOD) and/or the Southern Annular Mode (SAM) are associated with a shift in the relative frequency of wet and dry synoptic types on an annual to inter-annual timescale. In addition, the relative frequency of synoptic types is shown to vary on a multi-decadal timescale, associated with changes in the Inter-decadal Pacific Oscillation (IPO). Importantly, these results highlight the potential to utilise the link between the regional synoptic patterns derived in this study and large-scale climate modes to improve rainfall forecasting for Victoria, both in the short- (i.e. seasonal) and long-term (i.e. decadal/multi-decadal scale). In addition, the regional and large-scale climate drivers identified in this study provide a benchmark by which the performance of Global Climate Models (GCMs) may be assessed.

The Coupling between Earth's Inertial and Rotational Eigenmodes

NASA Astrophysics Data System (ADS)

Triana, S. A.; Rekier, J.; Trinh, A.; Laguerre, R.; Zhu, P.; Dehant, V. M. A.

2017-12-01

Wave motions in the Earth's fluid core, supported by the restoring action of both buoyancy (within the stably stratified top layer) and the Coriolis force, lead to the existence of global oscillation modes, the so-called gravito-inertial modes. These fluid modes can couple with the rotational modes of the Earth by exerting torques on the mantle and the inner core. Viscous shear stresses at the fluid boundaries, along with pressure and gravitation, contribute to the overall torque balance. Previous research by Rogister & Valette (2009) suggests that indeed rotational and gravito-inertial modes are coupled, thus shifting the frequencies of the Chandler Wobble (CW), the Free Core Nutation (FCN) and the Free Inner Core Nutation (FICN). Here we present the first results from a numerical model of the Earth's fluid core and its interaction with the rotational eigenmodes. In this first step we consider a fluid core without a solid inner core and we restrict to ellipticities of the same order as the Ekman number. We formulate the problem as a generalised eigenvalue problem that solves simultaneously the Liouville equation for the rotational modes (the torque balance), and the Navier-Stokes equation for the inertial modes.

Inertial wave beams and inertial wave modes in a rotating cylinder with time-modulated rotation rate

NASA Astrophysics Data System (ADS)

Borcia, Ion D.; Ghasemi V., Abouzar; Harlander, Uwe

2014-05-01

Inertial gravity waves play an crucial role in atmospheres, oceans, and the fluid inside of planets and moons. In the atmosphere, the effect of rotation is neglected for small wavelength and the waves bear the character of internal gravity waves. For long waves, the hydrostatic assumption is made which in turn makes the atmosphere inelastic with respect to inertial motion. In contrast, in the Earth's interior, pure inertial waves are considered as an important fundamental part of the motion. Moreover, as the deep ocean is nearly homogeneous, there the inertial gravity waves bear the character of inertial waves. Excited at the oceans surface mainly due to weather systems the waves can propagate downward and influence the deep oceans motion. In the light of the aforesaid it is important to understand better fundamental inertial wave dynamics. We investigate inertial wave modes by experimental and numerical methods. Inertial modes are excited in a fluid filled rotating annulus by modulating the rotation rate of the outer cylinder and the upper and lower lids. This forcing leads to inertial wave beams emitted from the corner regions of the annulus due to periodic motions in the boundary layers (Klein et al., 2013). When the forcing frequency matches with the eigenfrequency of the rotating annulus the beam pattern amplitude is increasing, the beams broaden and mode structures can be observed (Borcia et al., 2013a). The eigenmodes are compared with analytical solutions of the corresponding inviscid problem (Borcia et al, 2013b). In particular for the pressure field a good agreement can be found. However, shear layers related to the excited wave beams are present for all frequencies. This becomes obvious in particular in the experimental visualizations that are done by using Kalliroscope particles, highlighting relative motion in the fluid. Comparing the eigenfrequencies we find that relative to the analytical frequencies, the experimental and numerical ones show a small shift towards higher frequencies. This frequency shift is due to the reduction of the effective resonance volume that results from the existence of a Stokes boundary layer at the outer librating wall. Due to the symmetry of the forcing not all possible modes can be excited. It is shown that only symmetric modes with respect to the rotation axis exist. From a fundamental perspective, the study might help to understand better inertial mode excitation in librating planets and moons where inertial waves are emitted from critical points on the inner or outer spherical boundary. Recently, Zhang et al. (2013) pointed out the resonance should not occur in symmetric librating bodies without precession. We will discuss how this assumption depends on the boundary conditions. It might turn out that even when the projection of the Euler (or Poincare) force on the modes is zero, the projection of the excited wave beams on the modes is non-zero. K. Zhang, K. H. Chan, X. Liao, and J. M. Aurnou. The non-resonant response of fluid in a rapidly rotating sphere undergoing longitudinal libration, J. Fluid Mech.,720, 212-235, 2013. I. D. Borcia and U. Harlander. Inertial waves in a rotating annulus with inclined inner cylinder, Theoret. Comp. Fluid Dynamics, 27, 397-413, 2013. I. D. Borcia, A. Ghasemi V., and U. Harlander. Inertial wave mode excitation inside a rotating cylindrical container with librating walls, submitted to Fluid Dyn. Res.,2013. M. Klein, T. Seelig, M. V. Kurgansky, A. Ghasemi V., I. D. Borcia, A. Will, E. Schaller, C. Egbers, and Uwe Harlander. Inertial wave excitation and focusing in a liquid bounded by a frustum and a cylinder, submitted to J. Fluid Mech., 2013.

RF signal detection by a tunable optoelectronic oscillator based on a PS-FBG.

PubMed

Shao, Yuchen; Han, Xiuyou; Li, Ming; Zhao, Mingshan

2018-03-15

Low-power radio frequency (RF) signal detection is highly desirable for many applications, ranging from wireless communication to radar systems. A tunable optoelectronic oscillator (OEO) based on a phase-shifted fiber Bragg grating for detecting low-power RF signals is proposed and experimentally demonstrated. When the frequency of the input RF signal is matched with the potential oscillation mode of the OEO, it is detected and amplified. The frequency of the RF signal under detection can be estimated simultaneously by scanning the wavelength of the laser source. The RF signals from 1.5 to 5 GHz as low as -91  dBm are detected with a gain of about 10 dB, and the frequency is estimated with an error of ±100  MHz. The performance of the OEO system for detecting an RF signal with different modulation rates is also investigated.

Collective dynamics in atomistic models with coupled translational and spin degrees of freedom

DOE PAGES

Perera, Dilina; Nicholson, Don M.; Eisenbach, Markus; ...

2017-01-26

When using an atomistic model that simultaneously treats the dynamics of translational and spin degrees of freedom, we perform combined molecular and spin dynamics simulations to investigate the mutual influence of the phonons and magnons on their respective frequency spectra and lifetimes in ferromagnetic bcc iron. Furthermore, by calculating the Fourier transforms of the space- and time-displaced correlation functions, the characteristic frequencies and the linewidths of the vibrational and magnetic excitation modes were determined. A comparison of the results with that of the stand-alone molecular dynamics and spin dynamics simulations reveals that the dynamic interplay between the phonons and magnonsmore » leads to a shift in the respective frequency spectra and a decrease in the lifetimes. Moreover, in the presence of lattice vibrations, additional longitudinal magnetic excitations were observed with the same frequencies as the longitudinal phonons.« less

Qubit-flip-induced cavity mode squeezing in the strong dispersive regime of the quantum Rabi model

PubMed Central

Joshi, Chaitanya; Irish, Elinor K.; Spiller, Timothy P.

2017-01-01

Squeezed states of light are a set of nonclassical states in which the quantum fluctuations of one quadrature component are reduced below the standard quantum limit. With less noise than the best stabilised laser sources, squeezed light is a key resource in the field of quantum technologies and has already improved sensing capabilities in areas ranging from gravitational wave detection to biomedical applications. In this work we propose a novel technique for generating squeezed states of a confined light field strongly coupled to a two-level system, or qubit, in the dispersive regime. Utilising the dispersive energy shift caused by the interaction, control of the qubit state produces a time-dependent change in the frequency of the light field. An appropriately timed sequence of sudden frequency changes reduces the quantum noise fluctuations in one quadrature of the field well below the standard quantum limit. The degree of squeezing and the time of generation are directly controlled by the number of frequency shifts applied. Even in the presence of realistic noise and imperfections, our protocol promises to be capable of generating a useful degree of squeezing with present experimental capabilities. PMID:28358025

Instabilities in rapid directional solidification under weak flow

NASA Astrophysics Data System (ADS)

Kowal, Katarzyna N.; Davis, Stephen H.; Voorhees, Peter W.

2017-12-01

We examine a rapidly solidifying binary alloy under directional solidification with nonequilibrium interfacial thermodynamics viz. the segregation coefficient and the liquidus slope are speed dependent and attachment-kinetic effects are present. Both of these effects alone give rise to (steady) cellular instabilities, mode S , and a pulsatile instability, mode P . We examine how weak imposed boundary-layer flow of magnitude |V | affects these instabilities. For small |V | , mode S becomes a traveling and the flow stabilizes (destabilizes) the interface for small (large) surface energies. For small |V | , mode P has a critical wave number that shifts from zero to nonzero giving spatial structure. The flow promotes this instability and the frequencies of the complex conjugate pairs each increase (decrease) with flow for large (small) wave numbers. These results are obtained by regular perturbation theory in powers of V far from the point where the neutral curves cross, but requires a modified expansion in powers of V1 /3 near the crossing. A uniform composite expansion is then obtained valid for all small |V | .

Few-mode optical fiber based simultaneously distributed curvature and temperature sensing.

PubMed

Wu, Hao; Tang, Ming; Wang, Meng; Zhao, Can; Zhao, Zhiyong; Wang, Ruoxu; Liao, Ruolin; Fu, Songnian; Yang, Chen; Tong, Weijun; Shum, Perry Ping; Liu, Deming

2017-05-29

The few-mode fiber (FMF) based Brillouin sensing operated in quasi-single mode (QSM) has been reported to achieve the distributed curvature measurement by monitoring the bend-induced strain variation. However, its practicality is limited by the inherent temperature-strain cross-sensitivity of Brillouin sensors. Here we proposed and experimentally demonstrated an approach for simultaneously distributed curvature and temperature sensing, which exploits a hybrid QSM operated Raman-Brillouin system in FMFs. Thanks to the larger spot size of the fundamental mode in the FMF, the Brillouin frequency shift change of the FMF is used for curvature estimation while the temperature variation is alleviated through Raman signals with the enhanced signal-to-noise ratio (SNR). Within 2 minutes measuring time, a 1.5 m spatial resolution is achieved along a 2 km FMF. The worst resolution of the square of fiber curvature is 0.333 cm -2 while the temperature resolution is 1.301 °C at the end of fiber.

Terminal Hydride Species in [FeFe]-Hydrogenases are Vibrationally Coupled to the Active Site Environment.

PubMed

Cramer, Stephen Paul; Pham, Cindy C; Mulder, David W; Pelmenschikov, Vladimir; King, Paul W; Ratzloff, Michael W; Wang, Hongxin; Mishra, Nakul; Alp, Ercan; Zhao, Jiyong; Hu, Michael Y; Tamasaku, Kenji; Yoda, Yoshitaka

2018-06-19

A combination of NRVS and FT-IR spectroscopies and DFT calculations was used to observe and characterize Fe-H/D bending modes in CrHydA1 [FeFe]-hydrogenase Cys-to-Ser variant C169S. Mutagenesis of cysteine to serine at position 169 changes the functional group adjacent to the H-cluster from a -SH to -OH, thus altering the proton transfer pathway. C169S has a significant reduction in catalytic activity compared to the native CrHydA1, presumably due to less efficient transfer of protons to the H-cluster. This mutation allowed effective capture of a hydride/deuteride intermediate and facilitated direct detection of the Fe-H/D normal modes. We find a significant shift to higher frequency in a Fe-H bending mode of the C169S variant, as compared to previous findings with reconstituted native and oxadithiolate (ODT) substituted CrHydA1. Rationalized by DFT calculations, we propose that this shift is caused by a stronger interaction between the -OH of C169S with the bridgehead -NH- of the active site, as compared to the -SH of C169 in the native enzyme. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Inter/intra molecular dynamics in gases and liquids studied by terahertz time-domain spectroscopy

NASA Astrophysics Data System (ADS)

Xin, Xuying

This thesis presents a description of the low-frequency terahertz (THz) absorption spectrum of a variety of materials that are of interest to many biological and chemical processes. The work described here encompasses the development of time-domain THz spectrometers, based on amplified Ti: Sapphire lasers systems as well as mode-locked Erbium doped fiber lasers as the driving source. These systems were applied to characterize the absorption spectrum of liquid water and water vapor, heavy water vapor, methanol vapor and tryptophan in the 0.2-2.2THz frequency range. The absorption profiles observed are closely related to the intermolecular or intramolecular motions in the materials of interest. In liquid water, the absorption profile shows evidence for modes due to large-scale structure amongst individual water molecules. The effects on the overall absorption profile are further deduced by the addition of various solutes which can enhance or break the formation of molecule networks. Various solutions are examined such as KCl in liquid water. Ions can change the strength of hydrogen bond in liquid water in the similar way as temperature does. Both K+ and Cl- are considered to be strong "structure breakers" in terms of their functions as softening the strength of hydrogen bond in liquid water. Theoretically, this will cause a red shift of some mode frequencies, reducing the absorption intensity at those frequencies and, at the same time, increasing the absorption at non-mode frequencies toward the vicinity of the low frequencies. For liquid water, the vapor phase was also examined, where for varying concentrations (humidity) Beer's Law does not hold to explain the observed absorption profiles. Again the reduced absorption of certain modes is explained by interactions between water monomers and their nature due to hydrogen spins. There are two species of water molecules in terms of the nuclear spin effect of hydrogen atoms in water molecule, ortho-water and para-water. The two types of water molecules present significantly different properties, e.g. different surface adsorption on metals. The effects of para-water and ortho-water on the THz absorption profile are discussed. Finally, I discuss the absorption profile of methanol vapor and tryptophan. In methanol vapor we observe coherent echoes after absorption by a THz transient and attribute it to the relaxation of the molecule due to the regularly spaced rotational manifold. In tryptophan two distinct absorption modes are observed due to torsional modes. These "soft-modes" are calculated and attributed to intramolecular motions between various atoms. The results of this body of work are discussed in the context of applications ranging from medicine, pharmaceuticals and the cosmetics industries.

Vibrational spectra of water solutions of azoles from QM/MM calculations: effects of solvation.

PubMed

Tanzi, Luana; Ramondo, Fabio; Guidoni, Leonardo

2012-10-18

Using microsolvation models and mixed quantum/classical ab initio molecular dynamics simulations, we investigate the vibrational properties of two azoles in water solution: pyrazole and oxazole. The effects of the water-azole hydrogen bonding are rationalized by an extensive comparison between structural parameters and harmonic frequencies obtained by microsolvation models. Following the effective normal-mode analysis introduced by Martinez et al. [Martinez et al., J. Chem. Phys. 2006, 125, 144106], we identify the vibrational frequencies of the solutes using the decomposition of the vibrational density of states of the gas phase and solution dynamics. The calculated shifts from gas phase to solution are fairly in agreement with the available experimental data.

Design, fabrication, and measurement of reflective metasurface for orbital angular momentum vortex wave in radio frequency domain

NASA Astrophysics Data System (ADS)

Yu, Shixing; Li, Long; Shi, Guangming; Zhu, Cheng; Zhou, Xiaoxiao; Shi, Yan

2016-03-01

In this paper, a reflective metasurface is designed, fabricated, and experimentally demonstrated to generate an orbital angular momentum (OAM) vortex wave in radio frequency domain. Theoretical formula of phase-shift distribution is deduced and used to design the metasurface producing vortex radio waves. The prototype of a practical configuration is designed, fabricated, and measured to validate the theoretical analysis at 5.8 GHz. The simulated and experimental results verify that the vortex waves with different OAM mode numbers can be flexibly generated by using sub-wavelength reflective metasurfaces. The proposed method and metasurface pave a way to generate the OAM vortex waves for radio and microwave wireless communication applications.

Investigation of Ferroelectric Domain Walls by Raman Spectroscopy

NASA Astrophysics Data System (ADS)

Stone, Gregory A.

Ferroelectric materials are characterized by an intrinsic spontaneous electric dipole moment that can be manipulated by the application of an electric field. Regions inside the crystal, known as domains, can have the spontaneous dipole moments oriented in a different direction than the surrounding crystal. Due to favorable piezoelectric, pyroelectric, electro-optic, and nonlinear optical properties, ferroelectric materials are attractive for commercial applications. Many devices, such as nonlinear frequency converters, require precisely engineered domain patterns. The properties of domains and their boundaries, known as domain walls, are vital to the performance and limitations of these devices. As a result, ferroelectric domains and the domain walls have been the focus of many scientific studies. Despite all this work, questions remain regarding their properties. This work is aimed at developing a better understanding of the properties of the domain wall using confocal Raman spectroscopy. Raman spectra taken from domain walls in Lithium Niobate and Lithium Tantalate reveal two distinct changes in the Raman spectra: (1) Shifts in frequency of the bulk Raman modes, which persists over a range of 0.2-0.5 mu m from the domain wall. The absence of this effect in defect free stoichiometric Lithium Tantalate indicates that the shifts are related to defects inside the crystal. (2) The presence of Raman modes corresponding to phonons propagating orthogonal to the laser beam axis, which are not collected in the bulk crystal. The phonons also preferential propagate normal to the domain wall. These modes are detected up to 0.35 mum from the domain wall. The observation and separation of these effects was made possible by the optimized spatial resolution (0.23 mum) of a home-built scanning confocal microscope and the fact that degeneracy of the transverse and longitudinal phonon polarization is lifted by polar phonons in Lithium Niobate and Lithium Tantalate. Raman investigations on other interfaces such as front, side and bottom surfaces revealed a similar appearance of modes due to distortion of wave fronts and reflection. These surfaces are studied to provide insight into mechanism that give rise to Raman modes typically absent for the particular orientation of the crystal.

Plasma influence on the dispersion properties of finite-length, corrugated waveguides

NASA Astrophysics Data System (ADS)

Shkvarunets, A.; Kobayashi, S.; Weaver, J.; Carmel, Y.; Rodgers, J.; Antonsen, T. M., Jr.; Granatstein, V. L.; Destler, W. W.; Ogura, K.; Minami, K.

1996-03-01

We present an experimental study of the electromagnetic properties of transverse magnetic modes in a corrugated-wall cavity filled with a radially inhomogeneous plasma. The shifts of the resonant frequencies of a finite-length, corrugated cavity were measured as a function of the background plasma density and the dispersion diagram was reconstructed up to a peak plasma density of 1012 cm-3. Good agreement with a calculated dispersion diagram is obtained for plasma densities below 5×1011 cm-3.

Ultra-low frequency Raman spectroscopy of SWNTs under high pressure

NASA Astrophysics Data System (ADS)

Shen, Y.; Quirke, N.; Zerulla, D.

2016-09-01

Radial deformation phenomena of carbon nanotubes (CNTs) are attracting increased attention because even minimal changes of the CNT's cross section can result in significant changes of their electronic and optical properties. It is therefore important to have the ability to sensitively probe and characterize this radial deformation. High pressure Raman spectroscopy offers a general and powerful method to study such effects in SWNTs. In this experimental work, we focus in particular on one theoretically predicted Raman vibrational mode, the so-called "Squash Mode" (SM), named after its vibrational mode pattern, which has an E2g symmetry representation and exists at shifts below the radial breathing mode (RBM) region. The Squash mode was predicted to be more sensitive to environmental changes than the RBM. Here we report on a detailed, experimental detection of SMs of aligned SWNT arrays with peaks as close as 18 cm-1 to the laser excitation energy. Furthermore, we investigate how the SM of aligned CNT arrays reacts when exposed to a high pressure environment of up to 9 GPa. The results confirm the theoretical predictions regarding the angular and polarization dependent variations of the SM's intensity with respect to their excitation. Furthermore, clear Raman upshifts of SM under pressures of up to 9 GPa are presented. The relative changes of these upshifts, and hence the sensitivity, are much higher than that of RBMs because of larger radial displacement of some of the participating carbon atoms during the SM vibration. These novel ultra-sensitive Raman SM shifts of SWNTs provide enhanced sensitivity and demonstrate new opportunities for nano-optical sensors applications.

Nonlinear characterization of a bolted, industrial structure using a modal framework

NASA Astrophysics Data System (ADS)

Roettgen, Daniel R.; Allen, Matthew S.

2017-02-01

This article presents measurements from a sub assembly of an off-the-shelf automotive exhaust system containing a bolted-flange connection and uses a recently proposed modal framework to develop a nonlinear dynamic model for the structure. The nonlinear identification and characterization methods used are reviewed to highlight the strengths of the current approach and the areas where further development is needed. This marks the first use of these new testing and nonlinear identification tools, and the associated modal framework, on production hardware with a realistic joint and realistic torque levels. To screen the measurements for nonlinearities, we make use of a time frequency analysis routine designed for transient responses called the zeroed early-time fast Fourier transform (ZEFFT). This tool typically reveals the small frequency shifts and distortions that tend to occur near each mode that is affected by the nonlinearity. The damping in this structure is found to be significantly nonlinear and a Hilbert transform is used to characterize the damping versus amplitude behavior. A model is presented that captures these effects for each mode individually (e.g. assuming negligible nonlinear coupling between modes), treating each mode as a single degree-of-freedom oscillator with a spring and viscous damping element in parallel with a four parameter Iwan model. The parameters of this model are identified for each of the structure's modes that exhibited nonlinearity and the resulting nonlinear model is shown to capture the stiffness and damping accurately over a large range of response amplitudes.

Resonant Raman scattering study of BexZn1-xO thin films grown on sapphire by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Wang, Yu-Chao; Su, Long-Xing; Zhao, Yu; Liu, Jian-Feng; Shen, Zheng-Chuan; Feng, Yu-Hua; Wu, Tian-Zhun; Tang, Zi-Kang

2017-07-01

Resonance Raman spectra of BexZn1-xO alloy materials were studied using 325 nm Laser. The research showed that the Raman spectra of BexZn1-xO alloys presents a dual-mode vibration. Compare BexZn1-xO alloy with ZnO single crystal, the A1 (LO) phonon vibration mode of BexZn1-xO alloy moved to the larger wave number direction. The position of A1 (LO) phonon vibration modes of Be0.08Zn0.92O and Be0.12Zn0.88O was 580 cm-1 and 582 cm-1, respectively. In addition, the temperature-dependent Raman spectroscopy was employed for Be0.12Zn0.88O, and the phonon mode frequency shift with temperature was studied in detail. Finally, the stability of the polar and nonpolar BexZn1-xO alloy materials was studied using resonance Raman spectroscopy. The results showed that the A1 (LO) phonon mode frequency of polar BexZn1-xO alloy remained in the same position, while the nonpolar BexZn1-xO alloys moved nearly 3.5 cm-1 to larger direction after being placed in the air for two years. The reason may be that the stability of the nonpolar BexZn1-xO alloy is relatively poor upon interaction with molecule such as H2O, O2 in the air.

Synthesis, spectroscopic investigation and computational study of 3-(1-(((methoxycarbonyl)oxy)imino)ethyl)-2H-chromen-2-one

NASA Astrophysics Data System (ADS)

Gokula Krishnan, K.; Sivakumar, R.; Thanikachalam, V.; Saleem, H.; Arockia doss, M.

2015-06-01

The molecular structure and vibrational modes of 3-acetylcoumarin oxime carbonate (abbreviated as 3-ACOC) have been investigated by FT-IR, FT-Raman, NMR spectra and also by computational methods using HF and B3LYP with 6-311++G(d,p) basis set. The optimized geometric parameters (bond lengths, bond angles and dihedral angles) were in good agreement with the corresponding experimental values of 3-ACOC. The calculated vibrational frequencies of normal modes from DFT method matched well with the experimental values. The complete assignments were made on the basis of the total energy distribution (TED) of the vibrational modes. NMR (1H and 13C) chemical shifts were calculated by GIAO method and the results were compared with the experimental values. The other parameters like dipole moment, polarizability, first order hyperpolarizability, zero-point vibrational energy, EHOMO, ELUMO, heat capacity and entropy have also been computed.

Raman bandshape analysis on CH and CSC stretching modes of dimethyl sulfoxide in liquid binary mixture: comparative study with quantum-chemical calculations.

PubMed

Upadhyay, Ganesh; Gomti Devi, Th

2014-12-10

The interacting nature of dimethyl sulfoxide (DMSO) in binary mixtures has been carried out on CH and CSC stretching modes of vibration using chloroform (CLF), chloroform-d (CLFd), acetonitrile (ACN) and acetonitrile-d3 (ACNd) solvents. Peak frequencies of both the stretching modes show blue shift with the increase in solvent concentration. Variation of Raman bandwidth with the solvent concentration was discussed using different mechanisms. Ab initio calculation for geometry optimization and vibrational wavenumber calculation have been performed on monomer and dimer structures of DMSO to explain the experimentally observed Raman spectra. Theoretically calculated values are found in good agreement with the experimental results. Vibrational and reorientational relaxation times have been studied corresponding to solvent concentrations to elucidate the interacting mechanisms of binary mixtures. Copyright © 2014 Elsevier B.V. All rights reserved.

New Class of Quasinormal Modes of Neutron Stars in Scalar-Tensor Gravity

NASA Astrophysics Data System (ADS)

Mendes, Raissa F. P.; Ortiz, Néstor

2018-05-01

Detection of the characteristic spectrum of pulsating neutron stars can be a powerful tool not only to probe the nuclear equation of state but also to test modifications to general relativity. However, the shift in the oscillation spectrum induced by modified theories of gravity is often small and degenerate with our ignorance of the equation of state. In this Letter, we show that the coupling to additional degrees of freedom present in modified theories of gravity can give rise to new families of modes, with no counterpart in general relativity, which could be sufficiently well resolved in frequency space to allow for clear detection. We present a realization of this idea by performing a thorough study of radial oscillations of neutron stars in massless scalar-tensor theories of gravity. We anticipate astrophysical scenarios where the presence of this class of quasinormal modes could be probed with electromagnetic and gravitational wave measurements.

Polaron physics and crossover transition in magnetite probed by pressure-dependent infrared spectroscopy.

PubMed

Ebad-Allah, J; Baldassarre, L; Sing, M; Claessen, R; Brabers, V A M; Kuntscher, C A

2013-01-23

The optical properties of magnetite at room temperature were studied by infrared reflectivity measurements as a function of pressure up to 8 GPa. The optical conductivity spectrum consists of a Drude term, two sharp phonon modes, a far-infrared band at around 600 cm(-1) and a pronounced mid-infrared absorption band. With increasing pressure both absorption bands shift to lower frequencies and the phonon modes harden in a linear fashion. Based on the shape of the MIR band, the temperature dependence of the dc transport data, and the occurrence of the far-infrared band in the optical conductivity spectrum, the polaronic coupling strength in magnetite at room temperature should be classified as intermediate. For the lower energy phonon mode an abrupt increase of the linear pressure coefficient occurs at around 6 GPa, which could be attributed to minor alterations of the charge distribution among the different Fe sites.

Phase shift of TE and TM modes in an optical fiber due to axial strain (exact solution)

NASA Technical Reports Server (NTRS)

Egalon, Claudio O.; Rogowski, Robert S.

1992-01-01

Axial strain may be determined by monitoring the phase shift of modes of a variety of optical fiber sensors. In this paper, the exact solution of a circular optical fiber is used to calculate the phase shift of the TE and TM modes. Whenever an optical fiber is stressed, the optical path length, the index of refraction, and the propagation constants of each fiber mode change. In consequence, the modal phase term, beta(ln)z, of the fields is shifted by an amount Delta phi. In certain cases, it is desirable to control the phase shift term in order to make the fiber either more or less sensitive to certain kinds of strain. It is shown that it can be accomplished by choosing appropriate fiber parameters.

Use of shift gradient in the second dimension to improve the separation space in comprehensive two-dimensional liquid chromatography.

PubMed

Li, Duxin; Schmitz, Oliver J

2013-08-01

Comprehensive two-dimensional liquid chromatography (LC × LC) has received much attention because it offers much higher peak capacities than separation in a single dimension. The advantageous peak capacity makes it attractive for the separation of complex samples. Various gradient methods have been used in LC × LC systems. The use of continuous shift gradient is advantageous because it combines the peak compression effect of full gradient mode and the tailed gradient program in parallel gradient mode. Here, a comparison of LC × LC analysis of Chinese herbal medicine with full gradient mode and shift gradient mode in the second dimension was performed. A correlation between the first and second dimensions was found in full gradient mode, and this was significantly reduced with shift gradient mode. The orthogonality increased by 43.7%. The effective peak distribution area increased significantly, which produced better separation.

Flux-driven algebraic damping of m = 1 diocotron mode

NASA Astrophysics Data System (ADS)

Chim, Chi Yung; O'Neil, Thomas M.

2016-07-01

Recent experiments with pure electron plasmas in a Malmberg-Penning trap have observed the algebraic damping of m = 1 diocotron modes. Transport due to small field asymmetries produces a low density halo of electrons moving radially outward from the plasma core, and the mode damping begins when the halo reaches the resonant radius r = Rw at the wall of the trap. The damping rate is proportional to the flux of halo particles through the resonant layer. The damping is related to, but distinct from, spatial Landau damping, in which a linear wave-particle resonance produces exponential damping. This paper explains with analytic theory the new algebraic damping due to particle transport by both mobility and diffusion. As electrons are swept around the "cat's eye" orbits of the resonant wave-particle interaction, they form a dipole (m = 1) density distribution. From this distribution, the electric field component perpendicular to the core displacement produces E × B-drift of the core back to the axis, that is, damps the m = 1 mode. The parallel component produces drift in the azimuthal direction, that is, causes a shift in the mode frequency.

Multichannel tunable filter properties of 1D magnetized ternary plasma photonic crystal in the presence of evanescent wave

NASA Astrophysics Data System (ADS)

Awasthi, Suneet Kumar; Panda, Ranjita; Shiveshwari, Laxmi

2017-07-01

The multichannel tunable filter properties of one-dimensional ternary plasma photonic crystal composed of magnetized plasma and lossless dielectric have been theoretically investigated using transfer matrix method in the microwave region. The proposed filters possess 2N - 2 comb-like sharp resonant peaks also called transmission channels for N > 1 in transmission spectra in the absence and presence of an external magnetic field. Due to the coupling between evanescent waves and propagating modes in plasma and dielectric layers, respectively, 2N - 2 transmission channels are found without the addition of any defect, enabling the structure to work as a multichannel filter. Next, the filter properties can be made tunable by the application of an external magnetic field, i.e., channel frequency can either be red or blue shifted depending upon the orientation of an external magnetic field. The number of channels and their positions can also be modulated by changing the number of periods (N) and the incident angle (θo), respectively, for both transverse electric (TE) and transverse magnetic (TM) modes besides other parameters such as plasma collision frequency, thickness of the plasma layer, plasma frequency, etc.

Phase locking of a 1.5 Terahertz quantum cascade laser and use as a local oscillator in a heterodyne HEB receiver.

PubMed

Rabanus, D; Graf, U U; Philipp, M; Ricken, O; Stutzki, J; Vowinkel, B; Wiedner, M C; Walther, C; Fischer, M; Faist, J

2009-02-02

We demonstrate for the first time the closure of an electronic phase lock loop for a continuous-wave quantum cascade laser (QCL) at 1.5 THz. The QCL is operated in a closed cycle cryo cooler. We achieved a frequency stability of better than 100 Hz, limited by the resolution bandwidth of the spectrum analyser. The PLL electronics make use of the intermediate frequency (IF) obtained from a hot electron bolometer (HEB) which is downconverted to a PLL IF of 125 MHz. The coarse selection of the longitudinal mode and the fine tuning is achieved via the bias voltage of the QCL. Within a QCL cavity mode, the free-running QCL shows frequency fluctuations of about 5 MHz, which the PLL circuit is able to control via the Stark-shift of the QCL gain material. Temperature dependent tuning is shown to be nonlinear, and of the order of -16 MHz/K. Additionally we have used the QCL as local oscillator (LO) to pump an HEB and perform, again for the first time at 1.5 THz, a heterodyne experiment, and obtain a receiver noise temperature of 1741 K.

Dual demodulation interferometer with two-wave mixing in GaAs photorefractive crystal

NASA Astrophysics Data System (ADS)

Zhenzhen, Zhang; Zhongqing, Jia; Guangrong, Ji; Qiwu, Wang

2018-07-01

A dual demodulation interferometer with two-wave mixing (TWM) in the GaAs photorefractive crystal (PRC) is proposed and experimentally demonstrated. The GaAs PRC has tiny temperature change under high voltage thus not requiring thermoelectric cooler (TEC) to stabilize the temperature, and adaptive to low frequency fluctuation below 200 Hz. The system is an unbalanced TWM interferometer, which could demodulate the phase change both space variation and wavelength shift induced by strain. Two demodulation modes' formulas are provided in theory respectively. Experimental results have been tested and compared with theoretical analysis, demonstrating that it is a practical and flexible system for detection of mechanical vibration or structure health monitoring (SHM) in engineering by selecting different demodulation mode.

Markers of pathological excitability derived from principal dynamic modes of hippocampal neurons

NASA Astrophysics Data System (ADS)

Kang, Eunji E.; Zalay, Osbert C.; Serletis, Demitre; Carlen, Peter L.; Bardakjian, Berj L.

2012-10-01

Transformation of principal dynamic modes (PDMs) under epileptogenic conditions was investigated by computing the Volterra kernels in a rodent epilepsy model derived from a mouse whole hippocampal preparation, where epileptogenesis was induced by altering the concentrations of Mg2 + and K+ of the perfusate for different levels of excitability. Both integrating and differentiating PDMs were present in the neuronal dynamics, and both of them increased in absolute magnitude for increased excitability levels. However, the integrating PDMs dominated at all levels of excitability in terms of their relative contributions to the overall response, whereas the dominant frequency responses of the differentiating PDMs were shifted to higher ranges under epileptogenic conditions, from ripple activities (75-200 Hz) to fast ripple activities (200-500 Hz).

Markers of pathological excitability derived from principal dynamic modes of hippocampal neurons.

PubMed

Kang, Eunji E; Zalay, Osbert C; Serletis, Demitre; Carlen, Peter L; Bardakjian, Berj L

2012-10-01

Transformation of principal dynamic modes (PDMs) under epileptogenic conditions was investigated by computing the Volterra kernels in a rodent epilepsy model derived from a mouse whole hippocampal preparation, where epileptogenesis was induced by altering the concentrations of Mg(2 +) and K(+) of the perfusate for different levels of excitability. Both integrating and differentiating PDMs were present in the neuronal dynamics, and both of them increased in absolute magnitude for increased excitability levels. However, the integrating PDMs dominated at all levels of excitability in terms of their relative contributions to the overall response, whereas the dominant frequency responses of the differentiating PDMs were shifted to higher ranges under epileptogenic conditions, from ripple activities (75-200 Hz) to fast ripple activities (200-500 Hz).

Incoherent neutron scattering in acetanilide and three deuterated derivatives

NASA Astrophysics Data System (ADS)

Barthes, Mariette; Almairac, Robert; Sauvajol, Jean-Louis; Moret, Jacques; Currat, Roland; Dianoux, José

1991-03-01

Incoherent-neutron-scattering measurements of the vibrational density of states of acetanilide and three deuterated derivatives are presented. These data allow one to identify an intense maximum, assigned to the N-H out-of-plane bending mode. The data display the specific behavior of the methyl torsional modes: large isotopic shift and strong low-temperature intensity; confirm our previous inelastic-neutron-scattering studies, indicating no obvious anomalies in the range of frequency of the acoustic phonons. In addition, the data show the existence of thermally activated quasielastic scattering above 100 K, assigned to the random diffusive motion of the methyl protons. These results are discussed in the light of recent theoretical models proposed to explain the anomalous optical properties of this crystal.

Transmission of 100-MHz-range ultrasound through a fused quartz fiber.

PubMed

Irie, Takasuke; Tagawa, Norio; Tanabe, Masayuki; Moriya, Tadashi; Yoshizawa, Masasumi; Iijima, Takashi; Itoh, Kouichi; Yokoyama, Taku; Kumagai, Hideki; Taniguchi, Nobuyuki

2011-07-01

This paper describes an investigation into direct observation of microscopic images of tissue using a thin acoustic wave guide. First, the characteristics of the ultrasonic wave propagated in a fused quartz fiber were measured using the reflection method in order to study the insertion loss and the frequency shift of the ultrasonic wave transmitted from the transducer. Next, a receiving transducer was placed close to the end of the fiber, and the characteristics of the ultrasonic waves propagated through the acoustic coupling medium were measured using the penetration method in order to study the insertion loss and the frequency-dependent attenuation of the penetrated waves. Finally, a C-mode image was obtained by optimizing the measuring conditions using the results of the above measurements and scanning the ultrasonic beams on a target (coin) in water. A reflected wave with a peak frequency of approximately 220 MHz was obtained from the end of the fiber. The transmitted ultrasonic waves propagated through the acoustic coupling medium were detected with a frequency range of approximately 125-170 MHz, and the maximum detectable distance of the waves was approximately 1.2 mm within the 100-MHz frequency range. Finally, a high-frequency C-mode image of a coin in water was obtained using a tapered fused quartz fiber. The results suggest that it is necessary to improve the signal-to-noise ratio and reduce the insertion loss in the experimental system in order to make it possible to obtain microscopic images of tissue.

LORETA EEG phase reset of the default mode network

PubMed Central

Thatcher, Robert W.; North, Duane M.; Biver, Carl J.

2014-01-01

Objectives: The purpose of this study was to explore phase reset of 3-dimensional current sources in Brodmann areas located in the human default mode network (DMN) using Low Resolution Electromagnetic Tomography (LORETA) of the human electroencephalogram (EEG). Methods: The EEG was recorded from 19 scalp locations from 70 healthy normal subjects ranging in age from 13 to 20 years. A time point by time point computation of LORETA current sources were computed for 14 Brodmann areas comprising the DMN in the delta frequency band. The Hilbert transform of the LORETA time series was used to compute the instantaneous phase differences between all pairs of Brodmann areas. Phase shift and lock durations were calculated based on the 1st and 2nd derivatives of the time series of phase differences. Results: Phase shift duration exhibited three discrete modes at approximately: (1) 25 ms, (2) 50 ms, and (3) 65 ms. Phase lock duration present primarily at: (1) 300–350 ms and (2) 350–450 ms. Phase shift and lock durations were inversely related and exhibited an exponential change with distance between Brodmann areas. Conclusions: The results are explained by local neural packing density of network hubs and an exponential decrease in connections with distance from a hub. The results are consistent with a discrete temporal model of brain function where anatomical hubs behave like a “shutter” that opens and closes at specific durations as nodes of a network giving rise to temporarily phase locked clusters of neurons for specific durations. PMID:25100976

First artificial periodic inhomogeneity experiments at HAARP

NASA Astrophysics Data System (ADS)

Hysell, D. L.; McCarrick, M. J.; Fallen, C. T.; Vierinen, J.

2015-03-01

Experiments involving the generation and detection of artificial periodic inhomogeneities have been performed at the High Frequency Active Auroral Research Program (HAARP) facility. Irregularities were created using powerful X-mode HF emissions and then probed using short (10 μs) X- and O-mode pulses. Reception was performed using a portable software-defined receiver together with the crossed rhombic antenna from the local ionosonde. Echoes were observed reliably between about 85 and 140 km altitude with signal-to-noise ratios as high as about 30 dB. The Doppler shift of the echoes can be associated with the vertical neutral wind in this altitude range. Small but persistent Doppler shifts were observed. The decay time constant of the echoes is meanwhile indicative of the ambipolar diffusion coefficient which depends on the plasma temperature, composition, and neutral gas density. The measured time constants appear to be consistent with theoretical expectations and imply a methodology for measuring neutral density profiles. The significance of thermospheric vertical neutral wind and density measurements which are difficult to obtain using ground-based instruments by other means is discussed.

Optical Fibers Would Sense Local Strains

NASA Technical Reports Server (NTRS)

Egalon, Claudio O.; Rogowski, Robert S.

1994-01-01

Proposed fiber-optic transducers measure local strains. Includes lead-in and lead-out lengths producing no changes in phase shifts, plus short sensing length in which phase shift is sensitive to strain. Phase shifts in single-mode fibers vary with strains. In alternative version, multiple portions of optical fiber sensitive to strains characteristic of specific vibrational mode of object. Same principle also used with two-mode fiber.

Elimination of the light shift in rubidium gas cell frequency standards using pulsed optical pumping

NASA Technical Reports Server (NTRS)

English, T. C.; Jechart, E.; Kwon, T. M.

1978-01-01

Changes in the intensity of the light source in an optically pumped, rubidium, gas cell frequency standard can produce corresponding frequency shifts, with possible adverse effects on the long-term frequency stability. A pulsed optical pumping apparatus was constructed with the intent of investigating the frequency stability in the absence of light shifts. Contrary to original expectations, a small residual frequency shift due to changes in light intensity was experimentally observed. Evidence is given which indicates that this is not a true light-shift effect. Preliminary measurements of the frequency stability of this apparatus, with this small residual pseudo light shift present, are presented. It is shown that this pseudo light shift can be eliminated by using a more homogeneous C-field. This is consistent with the idea that the pseudo light shift is due to inhomogeneity in the physics package (position-shift effect).

On the relationship between large-scale climate modes and regional synoptic patterns that drive Victorian rainfall

NASA Astrophysics Data System (ADS)

Verdon-Kidd, D.; Kiem, A. S.

2008-10-01

In this paper regional (synoptic) and large-scale climate drivers of rainfall are investigated for Victoria, Australia. A non-linear classification methodology known as self-organizing maps (SOM) is used to identify 20 key regional synoptic patterns, which are shown to capture a range of significant synoptic features known to influence the climate of the region. Rainfall distributions are assigned to each of the 20 patterns for nine rainfall stations located across Victoria, resulting in a clear distinction between wet and dry synoptic types at each station. The influence of large-scale climate modes on the frequency and timing of the regional synoptic patterns is also investigated. This analysis revealed that phase changes in the El Niño Southern Oscillation (ENSO), the Southern Annular Mode (SAM) and/or Indian Ocean Dipole (IOD) are associated with a shift in the relative frequency of wet and dry synoptic types. Importantly, these results highlight the potential to utilise the link between the regional synoptic patterns derived in this study and large-scale climate modes to improve rainfall forecasting for Victoria, both in the short- (i.e. seasonal) and long-term (i.e. decadal/multi-decadal scale). In addition, the regional and large-scale climate drivers identified in this study provide a benchmark by which the performance of Global Climate Models (GCMs) may be assessed.

A system for measuring complex dielectric properties of thin films at submillimeter wavelengths using an open hemispherical cavity and a vector network analyzer

NASA Astrophysics Data System (ADS)

Rahman, Rezwanur; Taylor, P. C.; Scales, John A.

2013-08-01

Quasi-optical (QO) methods of dielectric spectroscopy are well established in the millimeter and submillimeter frequency bands. These methods exploit standing wave structure in the sample produced by a transmitted Gaussian beam to achieve accurate, low-noise measurement of the complex permittivity of the sample [e.g., J. A. Scales and M. Batzle, Appl. Phys. Lett. 88, 062906 (2006);, 10.1063/1.2172403 R. N. Clarke and C. B. Rosenberg, J. Phys. E 15, 9 (1982);, 10.1088/0022-3735/15/1/002 T. M. Hirovnen, P. Vainikainen, A. Lozowski, and A. V. Raisanen, IEEE Trans. Instrum. Meas. 45, 780 (1996)], 10.1109/19.516996. In effect the sample itself becomes a low-Q cavity. On the other hand, for optically thin samples (films of thickness much less than a wavelength) or extremely low loss samples (loss tangents below 10-5) the QO approach tends to break down due to loss of signal. In such a case it is useful to put the sample in a high-Q cavity and measure the perturbation of the cavity modes. Provided that the average mode frequency divided by the shift in mode frequency is less than the Q (quality factor) of the mode, then the perturbation should be resolvable. Cavity perturbation techniques are not new, but there are technological difficulties in working in the millimeter/submillimeter wave region. In this paper we will show applications of cavity perturbation to the dielectric characterization of semi-conductor thin films of the type used in the manufacture of photovoltaics in the 100 and 350 GHz range. We measured the complex optical constants of hot-wire chemical deposition grown 1-μm thick amorphous silicon (a-Si:H) film on borosilicate glass substrate. The real part of the refractive index and dielectric constant of the glass-substrate varies from frequency-independent to linearly frequency-dependent. We also see power-law behavior of the frequency-dependent optical conductivity from 316 GHz (9.48 cm-1) down to 104 GHz (3.12 cm-1).

From sedentary to active school commute: Multi-level factors associated with travel mode shifts.

PubMed

Lee, Chanam; Yoon, Jeongjae; Zhu, Xuemei

2017-02-01

Previous research has examined personal, social, and environmental correlates of active commuting to school, but most were cross-sectional and mode choice studies. This exploratory case study utilized a retrospective natural experiment opportunity, where a group of students transferred to a new school, and therefore experienced changes in their home-to-school travel environments. It examined whether such changes led to mode shifts from sedentary (car or school bus) to active (walking and bicycling) and what factors were associated with those shifts. Retrospective parental survey data (n=165, response rate=46%) were collected in 2011 from a new elementary school that opened in 2010 in Austin, Texas. The survey asked about the child's school travel mode and parental perceptions of home-to-school travel environments before and after the transfer, as well as personal and social factors. Multivariate logistic regressions were used to predict the odds of shifting from sedentary to active modes, using personal, social, and physical environmental variables. Sixty-eight (41.2%) respondents reported a sedentary-to-active mode shift for school commuting. Such shifts were associated with changes in school travel environments (e.g., shorter travel distance, improved safety, and decreased availability of bike lanes/paths) and relevant programs/services (e.g., increase in walking-promotion programs, and decrease in school bus service due to shortened distances). Targeting the current sedentary mode users is important to bring health benefits through increased physical activity and environmental benefits from reduced automobile use. Sedentary-to-active mode shifts may be encouraged by providing walking-promotion programs and by reducing travel distances and safety threats en route to school. Copyright © 2016 Elsevier Inc. All rights reserved.

Frequency-agile dual-frequency lidar for integrated coherent radar-lidar architectures.

PubMed

Vercesi, Valeria; Onori, Daniel; Laghezza, Francesco; Scotti, Filippo; Bogoni, Antonella; Scaffardi, Mirco

2015-04-01

We propose a novel architecture for implementing a dual-frequency lidar (DFL) exploiting differential Doppler shift measurement. The two frequency tones, needed for target velocity measurements, are selected from the spectrum of a mode-locked laser operating in the C-band. The tones' separation is easily controlled by using a programmable wavelength selective switch, thus allowing for a dynamic trade-off among robustness to atmospheric turbulence and sensitivity. Speed measurements for different tone separations equal to 10, 40, 80, and 160 GHz are demonstrated, proving the system's capability of working in different configurations. Thanks to the acquisition system based on an analog-to-digital converter and digital-signal processing, real-time velocity measurements are demonstrated. The MLL-based proposed architecture enables the integration of the DFL with a photonic-based radar that exploits the same laser for generating and receiving radio-frequency signal with high performance, thus allowing for simultaneous or complementary target observations by exploiting the advantages of both radar and lidar.

Tunable sub-gap radiation detection with superconducting resonators

NASA Astrophysics Data System (ADS)

Dupré, O.; Benoît, A.; Calvo, M.; Catalano, A.; Goupy, J.; Hoarau, C.; Klein, T.; Le Calvez, K.; Sacépé, B.; Monfardini, A.; Levy-Bertrand, F.

2017-04-01

We have fabricated planar amorphous indium oxide superconducting resonators ({T}{{c}}˜ 2.8 K) that are sensitive to frequency-selective radiation in the range of 7-10 GHz. Those values lay far below twice the superconducting gap that is worth about 200 GHz. The photon detection consists in a shift of the fundamental resonance frequency. We show that the detected frequency can be adjusted by modulating the total length of the superconducting resonator. We attribute those observations to the excitation of higher-order resonance modes. The coupling between the fundamental lumped and the higher order distributed resonance is due to the kinetic inductance nonlinearity with current. These devices, that we have called sub-gap kinetic inductance detectors, are to be distinguished from the standard kinetic inductance detectors in which quasi-particles are generated when incident light breaks down Cooper pairs.

Displacement of polarons by vibrational modes in doped conjugated polymers

NASA Astrophysics Data System (ADS)

Anderson, M.; Ramanan, C.; Fontanesi, C.; Frick, A.; Surana, S.; Cheyns, D.; Furno, M.; Keller, T.; Allard, S.; Scherf, U.; Beljonne, D.; D'Avino, G.; von Hauff, E.; Da Como, E.

2017-10-01

Organic pi-conjugated polymers are deemed to be soft materials with strong electron-phonon coupling, which results in the formation of polarons, i.e., charge carriers dressed by self-localized distortion of the nuclei. Universal signatures for polarons are optical resonances below the band gap and intense vibrational modes (IVMs), both found in the infrared (IR) spectral region. Here, we study p -doped conjugated homo- and copolymers by combining first-principles modelling and optical spectroscopy from the far-IR to the visible. Polaronic IVMs are found to feature absorption intensities comparable to purely electronic transitions and, most remarkably, show only loose resemblance to the Raman or IR-active modes of the neutral polymer. The IVM frequency is dramatically scaled down (up to 50%) compared to the backbone carbon-stretching modes in the pristine polymers. The very large intensity of IVMs is associated with displacement of the excess positive charge along the backbone driven by specific vibrational modes. We propose a quantitative picture for the identification of these polaron shifting modes that solely based on structural information, directly correlates with their IR intensity. This finding finally discloses the elusive microscopic mechanism behind the huge IR intensity of IVMs in doped polymeric semiconductors.

Investigation of the Frequency Shift of a SAD Circuit Loop and the Internal Micro-Cantilever in a Gas Sensor

PubMed Central

Guan, Liu; Zhao, Jiahao; Yu, Shijie; Li, Peng; You, Zheng

2010-01-01

Micro-cantilever sensors for mass detection using resonance frequency have attracted considerable attention over the last decade in the field of gas sensing. For such a sensing system, an oscillator circuit loop is conventionally used to actuate the micro-cantilever, and trace the frequency shifts. In this paper, gas experiments are introduced to investigate the mechanical resonance frequency shifts of the micro-cantilever within the circuit loop(mechanical resonance frequency, MRF) and resonating frequency shifts of the electric signal in the oscillator circuit (system working frequency, SWF). A silicon beam with a piezoelectric zinc oxide layer is employed in the experiment, and a Self-Actuating-Detecting (SAD) circuit loop is built to drive the micro-cantilever and to follow the frequency shifts. The differences between the two resonating frequencies and their shifts are discussed and analyzed, and a coefficient α related to the two frequency shifts is confirmed. PMID:22163588

Safe and simple detection of sparse hydrogen by Pd-Au alloy/air based 1D photonic crystal sensor

NASA Astrophysics Data System (ADS)

Mitra, S.; Biswas, T.; Chattopadhyay, R.; Ghosh, J.; Bysakh, S.; Bhadra, S. K.

2016-11-01

A simple integrated hydrogen sensor using Pd-Au alloy/air based one dimensional photonic crystal with an air defect layer is theoretically modeled. Structural parameters of the photonic crystal are delicately scaled to generate photonic band gap frequencies in a visible spectral regime. An optimized defect thickness permits a localized defect mode operating at a frequency within the photonic band gap region. Hydrogen absorption causes modification in the band gap characteristics due to variation of refractive index and lattice parameters of the alloy. As a result, the transmission peak appeared due to the resonant defect state gets shifted. This peak shifting is utilized to detect sparse amount of hydrogen present in the surrounding environment. A theoretical framework is built to calculate the refractive index profile of hydrogen loaded alloy using density functional theory and Bruggeman's effective medium approximation. The calculated refractive index variation of Pd3Au alloy film due to hydrogen loading is verified experimentally by measuring the reflectance characteristics. Lattice expansion properties of the alloy are studied through X-ray diffraction analyses. The proposed structure shows about 3 nm red shift of the transmission peak for a rise of 1% atomic hydrogen concentration in the alloy.

FTIR, FT-Raman, FT-NMR, UV-visible and quantum chemical investigations of 2-amino-4-methylbenzothiazole.

PubMed

Arjunan, V; Sakiladevi, S; Rani, T; Mythili, C V; Mohan, S

2012-03-01

The FT-IR (4000-400 cm(-1)) and FT-Raman (4000-100 cm(-1)) spectral measurements and complete assignments of the observed spectra of 2-amino-4-methylbenzothiazole (2A4MBT) have been proposed. Ab initio and DFT calculations have been performed and the structural parameters of the compound were determined from the optimised geometry with 6-31G(d,p), 6-311++G(d,p) and cc-pVDZ basis sets and giving energies, harmonic vibrational frequencies, depolarisation ratios, IR intensities and Raman activities. (1)H and (13)C NMR spectra were recorded and (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecule were calculated using the gauge independent atomic orbital (GIAO) method. UV-visible spectrum of the compound was also recorded and the electronic properties, such as HOMO, LUMO and band gap energies were measured by time-dependent DFT (TD-DFT) approach. The geometric parameters, energies, harmonic vibrational frequencies, IR intensities, Raman activities chemical shifts and absorption wavelengths were compared with the available experimental data of the molecule. The influences of methyl and amino groups on the skeletal modes and on the proton chemical shifts have been investigated. Copyright © 2011 Elsevier B.V. All rights reserved.

Thickness-shear mode quartz crystal resonators in viscoelastic fluid media

NASA Astrophysics Data System (ADS)

Arnau, A.; Jiménez, Y.; Sogorb, T.

2000-10-01

An extended Butterworth-Van Dyke (EBVD) model to characterize a thickness-shear mode quartz crystal resonator in a semi-infinite viscoelastic medium is derived by means of analysis of the lumped elements model described by Cernosek et al. [R. W. Cernosek, S. J. Martin, A. R. Hillman, and H. L. Bandey, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 45, 1399 (1998)]. The EBVD model parameters are related to the viscoelastic properties of the medium. A capacitance added to the motional branch of the EBVD model has to be included when the elastic properties of the fluid are considered. From this model, an explicit expression for the frequency shift of a quartz crystal sensor in viscoelastic media is obtained. By combining the expressions for shifts in the motional series resonant frequency and in the motional resistance, a simple equation that relates only one unknown (the loss factor of the fluid) to those measurable quantities, and two simple explicit expressions for determining the viscoelastic properties of semi-infinite fluid media have been derived. The proposed expression for the parameter Δf/ΔR is compared with the corresponding ratio obtained with data computed from the complete admittance model. Relative errors below 4.5%, 3%, and 1.2% (for the ratios of the load surface mechanical impedance to the quartz shear characteristic impedance of 0.3, 0.25, and 0.1, respectively), are obtained in the range of the cases analyzed. Experimental data from the literature are used to validate the model.

Measurement of mechanical properties of metallic glass at elevated temperature using sonic resonance method

NASA Astrophysics Data System (ADS)

Kaluvan, Suresh; Zhang, Haifeng; Mridha, Sanghita; Mukherjee, Sundeep

2017-04-01

Bulk metallic glasses are fully amorphous multi-component alloys with homogeneous and isotropic structure down to the atomic scale. Some attractive attributes of bulk metallic glasses include high strength and hardness as well as excellent corrosion and wear resistance. However, there are few reports and limited understanding of their mechanical properties at elevated temperatures. We used a nondestructive sonic resonance method to measure the Young's modulus and Shear modulus of a bulk metallic glass, Zr41.2Ti13.8Cu12.5Ni10Be22.5, at elevated temperatures. The measurement system was designed using a laser displacement sensor to detect the sonic vibration produced by a speaker on the specimen in high-temperature furnace. The OMICRON Bode-100 Vector Network Analyzer was used to sweep the frequency and its output was connected to the speaker which vibrated the material in its flexural mode and torsional modes. A Polytec OFV-505 laser vibrometer sensor was used to capture the vibration of the material at various frequencies. The flexural and torsional mode frequency shift due to the temperature variation was used to determine the Young's modulus and Shear modulus. The temperature range of measurement was from 50°C to 350°C. The Young's modulus was found to reduce from 100GPa to 94GPa for the 300°C temperature span. Similarly, the Shear modulus decreased from 38.5GPa at 50°C to 36GPa at 350°C.

Applications of Space-Time Duality

NASA Astrophysics Data System (ADS)

Plansinis, Brent W.

The concept of space-time duality is based on a mathematical analogy between paraxial diffraction and narrowband dispersion, and has led to the development of temporal imaging systems. The first part of this thesis focuses on the development of a temporal imaging system for the Laboratory for Laser Energetics. Using an electro-optic phase modulator as a time lens, a time-to-frequency converter is constructed capable of imaging pulses between 3 and 12 ps. Numerical simulations show how this system can be improved to image the 1-30 ps range used in OMEGA-EP. By adjusting the timing between the pulse and the sinusoidal clock of the phase modulator, the pulse spectrum can be selectively narrowed, broadened, or shifted. An experimental demonstration of this effect achieved spectral narrowing and broadening by a factor of 2. Numerical simulations show narrowing by a factor of 8 is possible with modern phase modulators. The second part of this thesis explores the space-time analog of reflection and refraction from a moving refractive index boundary. From a physics perspective, a temporal boundary breaks translational symmetry in time, requiring the momentum of the photon to remain unchanged while its energy may change. This leads to a shifting and splitting of the pulse spectrum as the boundary is crossed. Equations for the reflected and transmitted frequencies and a condition for total internal reflection are found. Two of these boundaries form a temporal waveguide, which confines the pulse to a narrow temporal window. These waveguides have a finite number of modes, which do not change during propagation. A single-mode waveguide can be created, allowing only a single pulse shape to form within the waveguide. Temporal reflection and refraction produce a frequency dependent phase shift on the incident pulse, leading to interference fringes between the incident light and the reflected light. In a waveguide, this leads to self-imaging, where the pulse shape reforms periodically at finite propagation lengths. Numerical simulations are performed for the specific case where the moving boundary is produced through cross-phase modulation. In this case, the Kerr nonlinearity causes the boundary to change during propagation, leading to unique temporal and spectral behavior.

Liquid core microbubble resonators for highly sensitive temperature sensing

NASA Astrophysics Data System (ADS)

Ward, Jonathan M.; Yang, Yong; Nic Chormaic, Sile

2014-03-01

It is experimentally shown that a large thermal blue shift of up to 100 GHz/K (0.2 nm/K at a wavelength of 775 nm) can be achieved with higher order radial modes in an ethanol-filled microbubble whispering gallery mode resonator (WGR). Q-factors for the most thermally sensitive modes are typically 105, equivalent to a measurement resolution of 8.5 mK. The thermal shift rate is determined for different modes when the core of the microbubble is filled with air, water, and ethanol. The measured shifts are compared against Finite Element Model (FEM) simulations. It is also shown that, if the microbubble is in the quasi-droplet regime, the fundamental TE mode in a bubble with a 500 nm wall is estimated to experience a shift of 35 GHz/K, while the effective index is still high enough to allow efficient coupling to a tapered optical fiber. Nonetheless, at a wall thickness of 1 μm, the most sensitive modes (n = 2) observed were still strongly coupled.

A method for modelling peak signal statistics on a mobile satellite transponder

NASA Technical Reports Server (NTRS)

Bilodeau, Andre; Lecours, Michel; Pelletier, Marcel; Delisle, Gilles Y.

1990-01-01

A simulation method is proposed. The simulation was developed to model the peak duration and energy content of signal peaks in a mobile communication satellite operating in a Frequency Division Multiple Access (FDMA) mode and presents an estimate of those power peaks for a system where the channels are modeled as band limited Gaussian noise, which is taken as a reasonable representation for Amplitude Commanded Single Sideband (ACSSB), Minimum Shift Keying (MSK), or Phase Shift Keying (PSK) modulated signals. The simulation results show that, under this hypothesis, the level of the signal power peaks for 10 percent, 1 percent, and 0.1 percent of the time are well described by a Rayleigh law and that their duration is extremely short and inversely proportional to the total FDM system bandwidth.

Bit-rate transparent DPSK demodulation scheme based on injection locking FP-LD

NASA Astrophysics Data System (ADS)

Feng, Hanlin; Xiao, Shilin; Yi, Lilin; Zhou, Zhao; Yang, Pei; Shi, Jie

2013-05-01

We propose and demonstrate a bit-rate transparent differential phase shift-keying (DPSK) demodulation scheme based on injection locking multiple-quantum-well (MQW) strained InGaAsP FP-LD. By utilizing frequency deviation generated by phase modulation and unstable injection locking state with Fabry-Perot laser diode (FP-LD), DPSK to polarization shift-keying (PolSK) and PolSK to intensity modulation (IM) format conversions are realized. We analyze bit error rate (BER) performance of this demodulation scheme. Experimental results show that different longitude modes, bit rates and seeding power have influences on demodulation performance. We achieve error free DPSK signal demodulation under various bit rates of 10 Gbit/s, 5 Gbit/s, 2.5 Gbit/s and 1.25 Gbit/s with the same demodulation setting.

Laser characteristics at 1535 nm and thermal effects of an Er:Yb phosphate glass microchip pumped by Ti:sapphire laser

NASA Astrophysics Data System (ADS)

Cai, Zhiping; Chardon, Alain; Xu, Huiying; Féron, Patrice; Michel Stéphan, Guy

2002-03-01

An Er:Yb codoped phosphate glass microchip laser has been studied under pumping with a Ti:sapphire laser ranging from 945 to 990 nm. The characteristics (threshold, slope efficiency) are first described for an optimized laser. The gain spectrum is calculated for the transition 4I13/2→ 4I15/2 around 1535 nm from fundamental spectroscopic data and from experimental results. Red-shift effect on the frequency of a single mode is experimentally observed when the pump power is increased, originating from thermal effects. Temperature inside the microchip cavity and thermal expansion coefficient were determined by employing the intensity ratio of two green upconversion emission line centered at 530 and 554 nm, respectively, which quantitatively explain this red shift.

Extending the Local Mode Hamiltonian Into the Condensed Phase: Using Vibrational Sum Frequency Generation to Study the Benzene-Air Interface

NASA Astrophysics Data System (ADS)

Johnson, Britta; Sibert, Edwin

2017-06-01

Surfaces and interfaces play an important role in understanding many chemical process; they also contain molecular configurations and vibrations that are unique compared to those seen in the bulk and gas phases. Sum frequency generated (SFG) vibrational spectroscopy provides an incredibly detailed picture of these interfaces. In particular, the CH stretch region of the spectrum contains an extensive degree of information about the molecular vibrations and arrangements at the surface or interface. The presence of a strong bandwidth SFG signal for the benzene/air interface has generated controversy since it was discovered; since benzene is centrosymmetric, no SFG signal is expected. It has been hypothesized that this signal is primarily a result of bulk contributions that results from electric quadrupole transitions. Our work focuses on testing this conclusion by calculating a theoretical VSF spectrum from pure surface contributions using a mixed quantum/classical local mode Hamiltonian. We take as a starting point our local mode CH/OH stretch Hamiltonian, that was previously used to study alkylbenzenes, benzene-(H_2O)_n, and DPOE-water clusters, and extend it to the condensed phase by including shifts in the intensities and frequencies as a function of the environment. This environment is modeled using a SAPT-based force-field that accurately reproduces the quadrupole for the benzene dimer. A series of independent time-dependent trajectories are used to obtain an ensemble of surface configurations and calculate the appropriate correlation functions. These correlations functions allow us to determine the origins of the VSF signal. Our talk will focus on the challenges of extending our local mode Hamiltonian into the condensed phase.

Stabilizing windings for tilting and shifting modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jardin, S.C.; Christensen, U.R.

1982-02-26

This invention provides simple, inexpensive, independent and passive, conducting loops for stabilizing a plasma ring having externally produced equilibrium fields on opposite sides of the plasma ring and internal plasma currents that interact to tilt and/or shift the plasma ring relative to the externally produced equilibrium field so as to produce unstable tilting and/or shifting modes in the plasma ring. More particularly this invention provides first and second passive conducting loops for containing first and second induced currents in first and second directions corresponding to the amplitude and directions of the unstable tilting and/or shifting modes in the plasma ring.more » To this end, the induced currents provide additional magnetic fields for producing restoring forces and/or restoring torques for counteracting the tilting and/or shifting modes when the conducting loops are held fixed in stationary positions relative to the externally produced equilibrium fields on opposite sides of the plasma ring.« less

Frequency-time coherence for all-optical sampling without optical pulse source

PubMed Central

Preußler, Stefan; Raoof Mehrpoor, Gilda; Schneider, Thomas

2016-01-01

Sampling is the first step to convert an analogue optical signal into a digital electrical signal. The latter can be further processed and analysed by well-known electrical signal processing methods. Optical pulse sources like mode-locked lasers are commonly incorporated for all-optical sampling, but have several drawbacks. A novel approach for a simple all-optical sampling is to utilise the frequency-time coherence of each signal. The method is based on only using two coupled modulators driven with an electrical sine wave. Since no optical source is required, a simple integration in appropriate platforms, such as Silicon Photonics might be possible. The presented method grants all-optical sampling with electrically tunable bandwidth, repetition rate and time shift. PMID:27687495

FIBER AND INTEGRATED OPTICS: Multiplexed optical-fiber sensors with autodyne detection

NASA Astrophysics Data System (ADS)

Potapov, V. T.; Mamedov, A. M.; Shatalin, S. V.; Yushkaĭtis, R. V.

1993-09-01

A method is proposed for multiplexing optical-fiber interference sensors. The method involves autodyne reception of frequency-modulated radiation reflected back to the laser. The response of a He-Ne laser with a linearly varying generation frequency to radiation reflected back from a single-mode fiber is studied. The spectrum of beats caused in the laser radiation by the reflection is shown to be governed by the distribution of reflectors along the fiber. The phases of the spectral components contain information about the phase shift of the reflected optical signal. A hydrophone array with a sensitivity of 30 μrad/Hz1/2 is described. A distributed temperature sensor with a spatial resolution of 1 m is also described.

Instantaneous flow measurements in a supersonic wind tunnel using spectrally resolved Rayleigh scattering

NASA Technical Reports Server (NTRS)

Seasholtz, Richard G.; Buggele, Alvin E.; Reeder, Mark F.

1995-01-01

Results of a feasibility study to apply laser Rayleigh scattering to non-intrusively measure flow properties in a small supersonic wind tunnel are presented. The technique uses an injection seeded, frequency doubled Nd:YAG laser tuned to an absorption band of iodine. The molecular Rayleigh scattered light is filtered with an iodine cell to block light at the laser frequency. The Doppler-shifted Rayleigh scattered light that passes through the iodine cell is analyzed with a planar mirror Fabry-Perot interferometer used in a static imaging mode. An intensified CCD camera is used to record the images. The images are analyzed at several subregions, where the flow velocity is determined. Each image is obtained with a single laser pulse, giving instantaneous measurements.

Generating multiple orbital angular momentum vortex beams using a metasurface in radio frequency domain

NASA Astrophysics Data System (ADS)

Yu, Shixing; Li, Long; Shi, Guangming; Zhu, Cheng; Shi, Yan

2016-06-01

In this paper, an electromagnetic metasurface is designed, fabricated, and experimentally demonstrated to generate multiple orbital angular momentum (OAM) vortex beams in radio frequency domain. Theoretical formula of compensated phase-shift distribution is deduced and used to design the metasurface to produce multiple vortex radio waves in different directions with different OAM modes. The prototype of a practical configuration of square-patch metasurface is designed, fabricated, and measured to validate the theoretical analysis at 5.8 GHz. The simulated and experimental results verify that multiple OAM vortex waves can be simultaneously generated by using a single electromagnetic metasurface. The proposed method paves an effective way to generate multiple OAM vortex waves in radio and microwave wireless communication applications.

Nonlinear acoustic experiments for landmine detection: the significance of the top-plate normal modes

NASA Astrophysics Data System (ADS)

Korman, Murray S.; Alberts, W. C. K., II; Sabatier, James M.

2004-09-01

In nonlinear acoustic detection experiments involving a buried inert VS 2.2 anti-tank landmine, airborne sound at two closely spaced primary frequencies f1 and f2 couple into the ground and interact nonlinearly with the soil-top pressure plate interface. Scattering generates soil vibration at the surface at the combination frequencies | m f1 +- n f2 | , where m and n are integers. The normal component of the particle velocity at the soil surface has been measured with a laser Doppler velocimeter (LDV) and with a geophone by Sabatier et. al. [SPIE Proceedings Vol. 4742, (695-700), 2002; Vol. 5089, (476-486), 2003] at the gravel lane test site. Spatial profiles of the particle velocity measured for both primary components and for various combination frequencies indicate that the modal structure of the mine is playing an important role. Here, an experimental modal analysis is performed on a VS 1.6 inert anti-tank mine that is resting on sand but is not buried. Five top-plate mode shapes are described. The mine is then buried in dry finely sifted natural loess soil and excited at f1 = 120 Hz and f2 = 130 Hz. Spatial profiles at the primary components and the nonlinearly generated f1 - (f2 - f1) component are characterized by a single peak. For the 2f1+f2 and 2f2 + f1 components, the doubly peaked profiles can be attributed to the familiar mode shape of a timpani drum (that is shifted lower in frequency due to soil mass loading). Other nonlinear profiles appear to be due to a mixture of modes. This material is based upon work supported by the U. S. Army RDECOM CERDEC Night Vision and Electronic Sensors Directorate under Contract DAAB15-02-C-0024.

Triboelectric Nanogenerator as a Self-Powered Communication Unit for Processing and Transmitting Information.

PubMed

Yu, Aifang; Chen, Xiangyu; Wang, Rui; Liu, Jingyu; Luo, Jianjun; Chen, Libo; Zhang, Yang; Wu, Wei; Liu, Caihong; Yuan, Hongtao; Peng, Mingzeng; Hu, Weiguo; Zhai, Junyi; Wang, Zhong Lin

2016-04-26

In this paper, we demonstrate an application of a triboelectric nanogenerator (TENG) as a self-powered communication unit. An elaborately designed TENG is used to translate a series of environmental triggering signals into binary digital signals and drives an electronic-optical device to transmit binary digital data in real-time without an external power supply. The elaborately designed TENG is built in a membrane structure that can effectively drive the electronic-optical device in a bandwidth from 1.30 to 1.65 kHz. Two typical communication modes (amplitude-shift keying and frequency-shift keying) are realized through the resonant response of TENG to different frequencies, and two digital signals, i.e., "1001" and "0110", are successfully transmitted and received through this system, respectively. Hence, in this study, a simple but efficient method for directly transmitting ambient vibration to the receiver as a digital signal is established using an elaborately designed TENG and an optical communication technique. This type of the communication system, as well as the implementation method presented, exhibits great potential for applications in the smart city, smart home, password authentication, and so on.

Tapered Glass-Fiber Microspike: High-Q Flexural Wave Resonator and Optically Driven Knudsen Pump.

PubMed

Pennetta, Riccardo; Xie, Shangran; Russell, Philip St J

2016-12-30

Appropriately designed optomechanical devices are ideal for making ultra-sensitive measurements. Here we report a fused-silica microspike that supports a flexural resonance with a quality factor greater than 100 000 at room temperature in vacuum. Fashioned by tapering single-mode fiber (SMF), it is designed so that the core-guided optical mode in the SMF evolves adiabatically into the fundamental mode of the air-glass waveguide at the tip. The very narrow mechanical linewidth (20 mHz) makes it possible to measure extremely small changes in resonant frequency. In a vacuum chamber at low pressure, the weak optical absorption of the glass is sufficient to create a temperature gradient along the microspike, which causes it to act as a microscopic Knudsen pump, driving a flow of gas molecules towards the tip where the temperature is highest. The result is a circulating molecular flow within the chamber. Momentum exchange between the vibrating microspike and the flowing molecules causes an additional restoring force that can be measured as a tiny shift in the resonant frequency. The effect is strongest when the mean free path of the gas molecules is comparable with the dimensions of the vacuum chamber. The system offers a novel means of monitoring the behavior of weakly absorbing optomechanical sensors operating in vacuum.

Study of non-spherical bubble oscillations near a surface in a weak acoustic standing wave field.

PubMed

Xi, Xiaoyu; Cegla, Frederic; Mettin, Robert; Holsteyns, Frank; Lippert, Alexander

2014-04-01

The interaction of acoustically driven bubbles with a wall is important in many applications of ultrasound and cavitation, as the close boundary can severely alter the bubble dynamics. In this paper, the non-spherical surface oscillations of bubbles near a surface in a weak acoustic standing wave field are investigated experimentally and numerically. The translation, the volume, and surface mode oscillations of bubbles near a flat glass surface were observed by a high speed camera in a standing wave cell at 46.8 kHz. The model approach is based on a modified Keller-Miksis equation coupled to surface mode amplitude equations in the first order, and to the translation equations. Modifications are introduced due to the adjacent wall. It was found that a bubble's oscillation mode can change in the presence of the wall, as compared to the bubble in the bulk liquid. In particular, the wall shifts the instability pressure thresholds to smaller driving frequencies for fixed bubble equilibrium radii, or to smaller equilibrium radii for fixed excitation frequency. This can destabilize otherwise spherical bubbles, or stabilize bubbles undergoing surface oscillations in the bulk. The bubble dynamics observed in experiment demonstrated the same trend as the theoretical results.

Theory and evidence of global Rossby waves in upper main-sequence stars: r-mode oscillations in many Kepler stars

NASA Astrophysics Data System (ADS)

Saio, Hideyuki; Kurtz, Donald W.; Murphy, Simon J.; Antoci, Victoria L.; Lee, Umin

2018-02-01

Asteroseismic inference from pressure modes (p modes) and buoyancy, or gravity, modes (g modes) is ubiquitous for stars across the Hertzsprung-Russell diagram. Until now, however, discussion of r modes (global Rossby waves) has been rare. Here we derive the expected frequency ranges of r modes in the observational frame by considering the visibility of these modes. We find that the frequencies of r modes of azimuthal order m appear as groups at slightly lower frequency than m times the rotation frequency. Comparing the visibility curves for r modes with Fourier amplitude spectra of Kepler light curves of upper main-sequence B, A, and F stars, we find that r modes are present in many γ Dor stars (as first discovered by Van Reeth et al.), spotted stars, and so-called heartbeat stars, which are highly eccentric binary stars. We also find a signature of r modes in a frequently bursting Be star observed by Kepler. In the amplitude spectra of moderately to rapidly rotating γ Dor stars, r-mode frequency groups appear at lower frequency than prograde g-mode frequency groups, while in the amplitude spectra of spotted early A to B stars, groups of symmetric (with respect to the equator) r-mode frequencies appear just below the frequency of a structured peak that we suggest represents an approximate stellar rotation rate. In many heartbeat stars, a group of frequencies can be fitted with symmetric m = 1 r modes, which can be used to obtain rotation frequencies of these stars.

Modeling the CH Stretch Vibrational Spectroscopy of M(+)[Cyclohexane] (M = Li, Na, and K) Ions.

PubMed

Sibert, Edwin L; Tabor, Daniel P; Lisy, James M

2015-10-15

The CH stretch vibrations of M(+)[cyclohexane][Ar] (M = Li, Na, and K) cluster ions were theoretically modeled. Results were compared to the corresponding infrared photodissociation spectra of Patwari and Lisy [ J. Chem. Phys A 2007 , 111 , 7585 ]. The experimental spectra feature a substantial spread in CH stretch vibration frequencies due to the alkali metal cation binding to select hydrogens of cyclohexane. This spread was observed to increase with decreasing metal ion size. Exploring the potential energy landscape revealed the presence of three conformers whose energy minima lie within ∼1 kcal of each other. It was determined that in all conformers the metal ion interacts with three hydrogen atoms; these hydrogen atoms can be either equatorial or axial. The corresponding spectra for these conformers were obtained with a theoretical model Hamiltonian [ J. Chem. Phys. 2013 , 138 , 064308 ] that consists of local mode CH stretches bilinearly coupled to each other and Fermi coupled to lower frequency modes. Frequencies and coupling parameters were obtained from electronic structure calculations that were subsequently scaled on the basis of previous studies. Theoretical spectra of a single low energy conformer were found to match well with the experimental spectra. The relative frequency shifts with changing metal ion size were accurately modeled with parameters generated by using ωB97X-D/6-311++(2d,p) calculations.

Refractive-index-sensing fiber comb using intracavity multi-mode interference fiber sensor

NASA Astrophysics Data System (ADS)

Oe, Ryo; Minamikawa, Takeo; Taue, Shuji; Fukano, Hideki; Nakajima, Yoshiaki; Minoshima, Kaoru; Yasui, Takeshi

2018-02-01

Refractive index measurement is important for evaluation of liquid materials, optical components, and bio sensing. One promising approach for such measurement is use of optical fiber sensors such as surface plasmonic resonance or multi-mode interference (MMI), which measure the change of optical spectrum resulting from the refractive index change. However, the precision of refractive index measurement is limited by the performance of optical spectrum analyzer. If such the refractive index measurement can be performed in radio frequency (RF) region in place of optical region, the measurement precision will be further improved by the frequency-standard-based RF measurement. To this end, we focus on the disturbance-to-RF conversion in a fiber optical frequency comb (OFC) cavity. Since frequency spacing frep of OFC depends on an optical cavity length nL, frep sensitively reflects the external disturbance interacted with nL. Although we previously demonstrated the precise strain measurement based on the frep measurement, the measurable physical quantity is limited to strain or temperature, which directly interacts with the fiber cavity itself. If a functional fiber sensor can be installed into the fiber OFC cavity, the measurable physical quantity will be largely expanded. In this paper, we introduce a MMI fiber sensor into a ring-type fiber OFC cavity for refractive index measurement. We confirmed the refractive-index-dependent frep shift.

The influence of the solar atmospheric stratification on the form of p-mode ridges

NASA Astrophysics Data System (ADS)

Steffens, S.; Schmitz, F.

2000-02-01

We investigate properties of non-radial solar p-modes of high angular degree. We consider linear adiabatic oscillations with the transition layer as an ideal reflector. Ionization of hydrogen and helium and dissociation of hydrogen are included in the equation of state and consequently in the adiabatic sound speed. Because of the restriction to high-degree modes we use the plane layer approximation with constant gravity. Our standard atmospheric model is the VAL-C atmosphere. This atmosphere is joined to the upper part of a convection zone. A model corona is matched to the transition region. Boundary conditions are applied at the temperature maximum of the corona and at a depth in the convection zone far below the lower turning point of the non-radial p-modes determined by the Lamb-frequency. We vary the temperature stratification of the atmosphere and shift the position of the transition region to obtain a family of eight different equilibrium models. By this strategy we can study the formation of structures in the diagnostic diagram and we can take into account uncertainties of the VAL-chromosphere. It is shown how the classical p-modes of a convection zone with zero pressure boundary condition are deformed when the thickness of the overlying atmosphere is enlarged. In no case, the atmosphere generates additional modes. By strong bending, horizontally passing parts of the ridges are formed. These parts produce more or less pronounced chromospheric ridges or features. These chromospheric ridges appear at frequencies where observations show enhanced power in the diagnostic diagram. Their locations sensitively depend on the atmospheric model. A simple two layer model shows that the occurence of bending of the ridges in the diagnostic diagram is quite natural and independent of atmospheric details.

Frequency-Switchable Microfluidic CSRR-Loaded QMSIW Band-Pass Filter Using a Liquid Metal Alloy

PubMed Central

Eom, Seunghyun; Memon, Muhammad Usman; Lim, Sungjoon

2017-01-01

In this paper, we have proposed a frequency-switchable complementary split-ring resonator (CSRR)-loaded quarter-mode substrate-integrated-waveguide (QMSIW) band-pass filter. For frequency switching, a microfluidic channel and liquid metal are used. The liquid metal used is eutectic gallium-indium (EGaIn), consisting of 24.5% indium and 75.5% gallium. The microfluidic channels are built using the elastomer polydimethylsiloxane (PDMS) and three-dimensional-printed microfluidic channel frames. The CSRR-loaded QMSIW band-pass filter is designed to have two states. Before the injection of the liquid metal, the measured center frequency and fractional bandwidths are 2.205 GHz and 6.80%, respectively. After injection, the center frequency shifts from 2.205 GHz to 2.56 GHz. Although the coupling coefficient is practically unchanged, the fractional bandwidth changes from 6.8% to 9.38%, as the CSRR shape changes and the external quality factor decreases. After the removal of the liquid metal, the measured values are similar to the values recorded before the liquid metal was injected. The repeatability of the frequency-switchable mechanism is, therefore, verified. PMID:28350355

N-H stretching modes of adenosine monomer in solution studied by ultrafast nonlinear infrared spectroscopy and ab initio calculations.

PubMed

Greve, Christian; Preketes, Nicholas K; Costard, Rene; Koeppe, Benjamin; Fidder, Henk; Nibbering, Erik T J; Temps, Friedrich; Mukamel, Shaul; Elsaesser, Thomas

2012-07-26

The N-H stretching vibrations of adenine, one of the building blocks of DNA, are studied by combining infrared absorption and nonlinear two-dimensional infrared spectroscopy with ab initio calculations. We determine diagonal and off-diagonal anharmonicities of N-H stretching vibrations in chemically modified adenosine monomer dissolved in chloroform. For the single-quantum excitation manifold, the normal mode picture with symmetric and asymmetric NH(2) stretching vibrations is fully appropriate. For the two-quantum excitation manifold, however, the interplay between intermode coupling and frequency shifts due to a large diagonal anharmonicity leads to a situation where strong mixing does not occur. We compare our findings with previously reported values obtained on overtone spectroscopy of coupled hydrogen stretching oscillators.

Surface phonons on Bi2Sr2CaCu2O8+δ

NASA Astrophysics Data System (ADS)

Phelps, R. B.; Akavoor, P.; Kesmodel, L. L.; Demuth, J. E.; Mitzi, D. B.

1993-11-01

We report measurements of surface optical phonons on Bi2Sr2CaCu2O8+δ with high-resolution electron-energy-loss spectroscopy (HREELS). In addition to peaks near 50 and 80 meV (403 and 645 cm-1), which have been previously observed, our loss spectra exhibit a peak at 26 meV (210 cm-1). Loss spectra were measured at temperatures from 45 to 146 K, and the temperature dependence of the peaks was found to be weak. The 50 and 80 meV peaks shift to lower frequency by ~1.5 meV over this temperature range. All three peaks are attributed to surface optical phonons. The identification of particular bulk modes corresponding to the surface modes observed with HREELS is discussed.

Ferroelectric thin film acoustic devices with electrical multiband switching ability.

PubMed

Ptashnik, Sergey V; Mikhailov, Anatoliy K; Yastrebov, Alexander V; Petrov, Peter K; Liu, Wei; Alford, Neil McN; Hirsch, Soeren; Kozyrev, Andrey B

2017-11-10

Design principles of a new class of microwave thin film bulk acoustic resonators with multiband resonance frequency switching ability are presented. The theory of the excitation of acoustic eigenmodes in multilayer ferroelectric structures is considered, and the principle of selectivity for resonator with an arbitrary number of ferroelectric layers is formulated. A so called "criterion function" is suggested that allows to determine the conditions for effective excitation at one selected resonance mode with suppression of other modes. The proposed theoretical approach is verifiedusing thepreexisting experimental data published elsewhere. Finally, the possible application of the two ferroelectric layers structures for switchable microwave overtone resonators, binary and quadrature phase-shift keying modulators are discussed. These devices could play a pivotal role in the miniaturization of microwave front-end antenna circuits.

Pressure-induced emergence of unusually high-frequency transverse excitations in a liquid alkali metal: Evidence of two types of collective excitations contributing to the transverse dynamics at high pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bryk, Taras; Lviv Polytechnic National University, 12 S. Bandera Street, UA-79013 Lviv; Ruocco, G.

Unlike phonons in crystals, the collective excitations in liquids cannot be treated as propagation of harmonic displacements of atoms around stable local energy minima. The viscoelasticity of liquids, reflected in transition from the adiabatic to elastic high-frequency speed of sound and in absence of the long-wavelength transverse excitations, results in dispersions of longitudinal (L) and transverse (T) collective excitations essentially different from the typical phonon ones. Practically, nothing is known about the effect of high pressure on the dispersion of collective excitations in liquids, which causes strong changes in liquid structure. Here dispersions of L and T collective excitations inmore » liquid Li in the range of pressures up to 186 GPa were studied by ab initio simulations. Two methodologies for dispersion calculations were used: direct estimation from the peak positions of the L/T current spectral functions and simulation-based calculations of wavenumber-dependent collective eigenmodes. It is found that at ambient pressure, the longitudinal and transverse dynamics are well separated, while at high pressures, the transverse current spectral functions, density of vibrational states, and dispersions of collective excitations yield evidence of two types of propagating modes that contribute strongly to transverse dynamics. Emergence of the unusually high-frequency transverse modes gives evidence of the breakdown of a regular viscoelastic theory of transverse dynamics, which is based on coupling of a single transverse propagating mode with shear relaxation. The explanation of the observed high-frequency shift above the viscoelastic value is given by the presence of another branch of collective excitations. With the pressure increasing, coupling between the two types of collective excitations is rationalized within a proposed extended viscoelastic model of transverse dynamics.« less

Single-longitudinal mode distributed-feedback fiber laser with low-threshold and high-efficiency

NASA Astrophysics Data System (ADS)

Jiang, Man; Zhou, Pu; Gu, Xijia

2018-01-01

Single-frequency fiber laser has attracted a lot of interest in recent years due to its numerous application potentials in telecommunications, LIDAR, high resolution sensing, atom frequency standard, etc. Phosphate glass fiber is one of the candidates for building compact high gain fiber lasers because of its capability of high-concentration of rare-earth ions doping in fiber core. Nevertheless, it is challenging for the integration of UV-written intra-core fiber Bragg gratings into the fiber laser cavity due to the low photosensitivity of phosphate glass fiber. The research presented in this paper will focus on demonstration of UV-written Bragg gratings in phosphate glass fiber and its application in direct-written short monolithic single-frequency fiber lasers. Strong π-phase shift Bragg grating structure is direct-inscribed into the Er/Yb co-doped gain fiber using an excimer laser, and a 5-cm-long phase mask is used to inscribe a laser cavity into the Er/Yb co-doped phosphate glass fibers. The phase mask is a uniform mask with a 50 μm gap in the middle. The fiber laser device emits output power of 10.44 mW with a slope efficiency of 21.5% and the threshold power is about 42.8 mW. Single-longitudinal mode operation is validated by radio frequency spectrum measurement. Moreover, the output spectrum at the highest power shows an excellent optical signal to noise ratio of about 70 dB. These results, to the best of our knowledge, show the lowest power threshold and highest efficiency among the reports that using the same structure to achieve single-longitudinal mode laser output.

Mercury Trapped Ion Frequency Standard for Ultra-Stable Reference Applications

NASA Technical Reports Server (NTRS)

Larsen, Kameron (Inventor); Burt, Eric A. (Inventor); Tjoelker, Robert L. (Inventor); Hamell, Robert L. (Inventor); Tucker, Blake C. (Inventor)

2017-01-01

An atomic clock including an ion trap assembly, a C-field coil positioned for generating a first magnetic field in the interrogation region of the ion trap assembly, a compensation coil positioned for generating a second magnetic field in the interrogation region, wherein the combination of the first and second magnetic fields produces an ion number-dependent second order Zeeman shift (Zeeman shift) in the resonance frequency that is opposite in sign to an ion number-dependent second order Doppler shift (Doppler shift) in the resonance frequency, the C-field coil has a radius selected using data indicating how changes in the radius affect an ion-number-dependent shift in the resonance frequency, such that a difference in magnitude between the Doppler shift and the Zeeman shift is controlled or reduced, and the resonance frequency, including the adjustment by the Zeeman shift, is used to obtain the frequency standard.

High sensitivity of p-modes near the acoustic cutoff frequency to solar model parameters

NASA Technical Reports Server (NTRS)

Guenther, D. B.

1991-01-01

The p-mode frequencies of low l have been calculated for solar models with initial helium mass fraction varying from Y = 0.2753-0.2875. The differences in frequency of the p-modes in the frequency range, 2500-4500 microHz, do not exceed 1-5 microHz among the models. But in the vicinity of the acoustic cutoff frequency, near 5000 microHz the p-mode frequency differences are enhanced by a factor of 4. The enhanced sensitivity of p-modes near the acoustic cutoff frequency was further tested by calculating and comparing p-mode frequencies of low l for two solar models one incorporating the Eddington T-tau relation and the other the Krishna Swamy T-tau relation. Again, it is found that p-modes with frequencies near the acoustic cutoff frequency show a significant increase in sensitivity to the different T-tau relations, compared to lower frequency p-modes. It is noted that frequencies above the acoustic cutoff frequency are complex, hence, cannot be modeled by the adiabatic pulsation code (assumes real eigenfrequencies) used in these calculations.

The bonding of FeN2, FeCO, and Fe2N2 - Model systems for side-on bonding of CO and N2

NASA Technical Reports Server (NTRS)

Bauschlicher, Charles W., Jr.; Pettersson, Lars G. M.; Siegbahn, Per E. M.

1987-01-01

Qualitative calculations are performed to elucidate the nature of the side-on interaction of both N2 and CO with a single Fe atom. The systems are found to be quite similar, with bonding leading to an increase in the CO or N2 bond length and a decrease in the vibrational frequency. The CO or N2 stretching modes lead to a large dipole derivative along the metal-ligand bond axis. The populations show an almost identical, large donation from the Fe 3d orbitals into the CO or N2 Pi-asterisk. The larger system Fe2N2 is then considered, with the N2 bridging the Fe2, both parallel and perpendicular to the Fe2 bond axis for two different Fe-Fe distances. For FeN2, the shift in the observed N2 frequency is smaller than observed for the alpha state of N2/Fe(111). The shift in the N2 vibrational frequency increases when the N2 interacts with two Fe atoms, either at the Fe-Fe nearest neighbor distance or at the first layer Fe-Fe distance, when the side-on N2 axis is oriented perpendicular to an Fe-Fe bond.

Quantitative evaluations of mechanisms of radiofrequency interactions with biological molecules and processes.

PubMed

Sheppard, Asher R; Swicord, Mays L; Balzano, Quirino

2008-10-01

The complexity of interactions of electromagnetic fields up to 10(12) Hz with the ions, atoms, and molecules of biological systems has given rise to a large number of established and proposed biophysical mechanisms applicable over a wide range of time and distance scales, field amplitudes, frequencies, and waveforms. This review focuses on the physical principles that guide quantitative assessment of mechanisms applicable for exposures at or below the level of endogenous electric fields associated with development, wound healing, and excitation of muscles and the nervous system (generally, 1 to 10(2) V m(-1)), with emphasis on conditions where temperature increases are insignificant (<1 K). Experiment and theory demonstrate possible demodulation at membrane barriers for frequencies < or =10 MHz, but not at higher frequencies. Although signal levels somewhat below system noise can be detected, signal-to-noise ratios substantially less than 0.1 cannot be overcome by cooperativity, signal averaging, coherent detection, or by nonlinear dynamical systems. Sensory systems and possible effects on biological magnetite suggest paradigms for extreme sensitivity at lower frequencies, but there are no known radiofrequency (RF) analogues. At the molecular level, vibrational modes are so overdamped by water molecules that excitation of molecular modes below the far infrared cannot occur. Two RF mechanisms plausibly may affect biological matter under common exposure conditions. For frequencies below approximately 150 MHz, shifts in the rate of chemical reactions can be mediated by radical pairs and, at all frequencies, dielectric and resistive heating can raise temperature and increase the entropy of the affected biological system.

On temporal dynamics of Sn2P2S6 oscillation in semi-linear cavity.

PubMed

Arciszewski, D; Shumelyuk, A; Odoulov, S

2013-06-01

Experimental measurements and calculations revealed an unusual type of oscillation dynamics of Sn(2)P(2)S(6) in the semi-linear cavity. It consists of a pronounced saw-tooth modulation of oscillation intensity--although it is not 100% in contrast--with the cw component being shifted in frequency with respect to the pump wave. This effect is attributed to the hybrid mode of two semi-linear oscillation geometries, one with a single pump wave and the other with two counterpropagating pump waves.

Modal processing for acoustic communications in shallow water experiment.

PubMed

Morozov, Andrey K; Preisig, James C; Papp, Joseph

2008-09-01

Acoustical array data from the Shallow Water Acoustics experiment was processed to show the feasibility of broadband mode decomposition as a preprocessing method to reduce the effective channel delay spread and concentrate received signal energy in a small number of independent channels. The data were collected by a vertical array designed at the Woods Hole Oceanographic Institution. Phase-shift Keying (PSK) m-sequence modulated signals with different carrier frequencies were transmitted at a distance 19.2 km from the array. Even during a strong internal waves activity a low bit error rate was achieved.

Fluid mass and thermal loading effects on the modal characteristics of space shuttle main engine liquid oxygen inlet splitter vanes

NASA Technical Reports Server (NTRS)

Panossian, H. V.; Boehnlein, J. J.

1987-01-01

An analysis and evaluation of experimental modal survey test data on the variations of modal characteristics induced by pressure and thermal loading events are presented. Extensive modal survey tests were carried out on a Space Shuttle Main Engine (SSME) test article using liquid nitrogen under cryogenic temperatures and high pressures. The results suggest that an increase of pressure under constant cryogenic temperature or a decrease of temperature under high pressure induces an upward shift of frequencies of various modes of the structures.

Nonlinear oscillations of inviscid free drops

NASA Technical Reports Server (NTRS)

Patzek, T. W.; Benner, R. E., Jr.; Basaran, O. A.; Scriven, L. E.

1991-01-01

The present analysis of free liquid drops' inviscid oscillations proceeds through solution of Bernoulli's equation to obtain the free surface shape and of Laplace's equation for the velocity potential field. Results thus obtained encompass drop-shape sequences, pressure distributions, particle paths, and the temporal evolution of kinetic and surface energies; accuracy is verified by the near-constant drop volume and total energy, as well as the diminutiveness of mass and momentum fluxes across drop surfaces. Further insight into the nature of oscillations is provided by Fourier power spectrum analyses of mode interactions and frequency shifts.

Far-infrared spectra of acetanilide revisited

NASA Astrophysics Data System (ADS)

Spire, A.; Barthes, M.; Kellouai, H.; De Nunzio, G.

2000-03-01

A new investigation of the temperature dependence of the far-infrared spectra of acetanilide and some isotopomers is presented. Four absorption bands are considered at 31, 42, 64, and 80 cm-1, and no significant change of their integrated intensity is observed when reducing the temperature. The temperature induced frequency shift values and other properties of these bands are consistent with an assignment as anharmonic lattice phonons. These results rule out the assignment of the 64, 80, and 106 cm-1 bands as normal modes of the polaronic excitation, as previously suggested.

Multimodal pressure-flow method to assess dynamics of cerebral autoregulation in stroke and hypertension.

PubMed

Novak, Vera; Yang, Albert C C; Lepicovsky, Lukas; Goldberger, Ary L; Lipsitz, Lewis A; Peng, Chung-Kang

2004-10-25

This study evaluated the effects of stroke on regulation of cerebral blood flow in response to fluctuations in systemic blood pressure (BP). The autoregulatory dynamics are difficult to assess because of the nonstationarity and nonlinearity of the component signals. We studied 15 normotensive, 20 hypertensive and 15 minor stroke subjects (48.0 +/- 1.3 years). BP and blood flow velocities (BFV) from middle cerebral arteries (MCA) were measured during the Valsalva maneuver (VM) using transcranial Doppler ultrasound. A new technique, multimodal pressure-flow analysis (MMPF), was implemented to analyze these short, nonstationary signals. MMPF analysis decomposes complex BP and BFV signals into multiple empirical modes, representing their instantaneous frequency-amplitude modulation. The empirical mode corresponding to the VM BP profile was used to construct the continuous phase diagram and to identify the minimum and maximum values from the residual BP (BPR) and BFV (BFVR) signals. The BP-BFV phase shift was calculated as the difference between the phase corresponding to the BPR and BFVR minimum (maximum) values. BP-BFV phase shifts were significantly different between groups. In the normotensive group, the BFVR minimum and maximum preceded the BPR minimum and maximum, respectively, leading to large positive values of BP-BFV shifts. In the stroke and hypertensive groups, the resulting BP-BFV phase shift was significantly smaller compared to the normotensive group. A standard autoregulation index did not differentiate the groups. The MMPF method enables evaluation of autoregulatory dynamics based on instantaneous BP-BFV phase analysis. Regulation of BP-BFV dynamics is altered with hypertension and after stroke, rendering blood flow dependent on blood pressure.

Investigation of an Ultrafast Harmonic Resonant RF Kicker

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Yulu

An Energy Recovery Linac (ERL) based multi-turn electron Circulator Cooler Ring (CCR) is envisaged in the proposed Jefferson Lab Electron Ion Collider (JLEIC) to cool the ion bunches with high energy (55 MeV), high current (1.5 A), high repetition frequency (476.3 MHz), high quality magnetized electron bunches. A critical component in this scheme is a pair of ultrafast kickers for the exchange of electron bunches between the ERL and the CCR. The ultrafast kicker should operate with the rise and fall time in less than 2.1 ns, at the repetition rate of ~10s MHz, and should be able to runmore » continuously during the whole period of cooling. These -and-fall time being combined together, are well beyond the state-of-art of traditional pulsed power supplies and magnet kickers. To solve this technical challenge, an alternative method is to generate this high repetition rate, fast rise-and-fall time short pulse continuous waveform by summing several finite number of (co)sine waves at harmonic frequencies of the kicking repetition frequency, and these harmonic modes can be generated by the Quarter Wave Resonater (QWR) based multifrequency cavities. Assuming the recirculator factor is 10, 10 harmonic modes (from 47.63 MHz to 476.3 MHz) with proper amplitudes and phases, plus a DC offset are combined together, a continuous short pulse waveform with the rise-and-fall time in less than 2.1 ns, repetition rate of 47.63 MHz waveform can be generated. With the compact and matured technology of QWR cavities, the total cost of both hardware development and operation can be reduced to a modest level. Focuse on the technical scheme, three main topics will be discussed in this thesis: the synthetization of the kicking pulse, the design and optimization of the deflecting QWR multi-integer harmonic frequency resonator and the fabrication and bench measurements of a half scale copper prototype. In the kicking pulse synthetization part, we begin with the Fourier Series expansion of an ideal square pulse, and get a Flat-Top waveform which will give a uniform kick over the bunch length of the kicked electron bunches, thus the transverse emittance of these kicked electron bunches can be maintained. By using two identical kickers with the betatron phase advance of 180 degree or its odd multiples, the residual kick voltage wave slopes at the unkicked bunch position will be totally cancelled out. Flat-Top waveform combined with two kicker scheme, the transverse emittance of the cooling electron bunches will be conserved during the whole injection, recirculation, and ejection processes. In the cavity design part, firstly, the cavity geometry is optimized to get high transverse shunt impedance thus less than 100 W of RF losses on the cavity wall can be achieved for all these 10 harmonic modes. To support all these 10 harmonic modes, group of four QWRs are adopted with the mode distribution of 5:3:1:1. In the multi-frequency cavities such as the five-mode-cavity and the three-mode-cavity, tunings are required to achieve the design frequencies for each mode. Slight segments of taper design on the inner conductor help to get the frequencies to be exactly on the odd harmonic modes. Stub tuners equal to the number of resonant modes are inserted to the outer conductor wall to compensate the frequency shifts due manufacturing errors and other perturbations during the operation such as the change of the cavity temperature. Single loop couple is designed for all harmonic modes in each cavity. By adjusting its loop size, position and rotation, it is possible to get the fundamental mode critical coupled and other higher harmonic modes slightly over coupled. A broadband circulator will be considered for absorbing the reflected power. Finally in this part, multipole field components due to the asymmetric cylindrical structure around the beam axis of the cavity as well as the beam-induced higher order mode (HOM) issues will be analyzed and discussed in this thesis. A half-scale copper prototype cavity (resonant frequencies from 95.26 MHz to 857.34 MHz) was fabricated to validate the electromagnetic characteristics. With this half scale prototype, the tuning processes of multiple harmonic frequencies, unloaded quality factor measurements of each mode, and bead-pull measurements are performed. The bench measurement results matched well with the simulation results, which have validated our cavity design and construction methods. Finally, a simple mode combining experiment with five separate signal generators was performed on this prototype cavity and the desired fast rise/fall time (1.2 ns), high repetition rate (95.26 MHz) waveform was captured, which finally proved our design of this ultrafast harmonic kicker.« less

Electron plasma wave filamentation in the kinetic regime

NASA Astrophysics Data System (ADS)

Lushnikov, Pavel; Rose, Harvey; Silantyev, Denis

2016-10-01

We consider nonlinear electron plasma wave (EPW) dynamics in the kinetic wavenumber regime, 0.25 < kλD < 0.45 , which is typical for current high temperature laser-plasma interaction experiments, where k is the EPW wavenumber and λD is the electron Debye length. In this kinetic regime, EPW frequency reduction due to electron trapping may dominate the ponderomotive frequency shift. Previous 3D PIC simulations showed that the trapped electron EPW filamentation instability can saturate stimulated Raman backscatter by reducing the EPWs coherence but multidimensional Vlasov simulations [1] are needed to address that saturation in details. We performed nonlinear, non-equilibrium 2D Vlasov simulations to study the EPW filamentation. The initial conditions are created either by external forcing or by constructing the appropriate 1D travelling Bernstein-Greene-Kruskal (BGK) mode. Transverse perturbations of any of these initial conditions grow with time eventually producing strongly nonlinear filamentation followed by plasma turbulence. We compared these simulations with the theoretical results on growth rates of the transverse instability BGK mode showing the satisfactory agreement. Supported by the New Mexico Consortium and NSF DMS-1412140.

A fast switch, combiner and narrow-band filter for high-power millimetre wave beams

NASA Astrophysics Data System (ADS)

Kasparek, W.; Petelin, M. I.; Shchegolkov, D. Yu; Erckmann, V.; Plaum, B.; Bruschi, A.; ECRH Groups at IPP Greifswald; Karlsruhe, FZK; Stuttgart, IPF

2008-05-01

A fast directional switch (FADIS) is described, which allows controlled switching of high-power microwaves between two outputs. A possible application could be synchronous stabilization of neoclassical tearing modes (NTMs). Generally, the device can be used to share the installed EC power between different types of launchers or different applications (e.g. in ITER, midplane/upper launcher). The switching is performed electronically without moving parts by a small frequency-shift keying of the gyrotron (some tens of megahertz), and a narrow-band diplexer. The device can be operated as a beam combiner also, which offers attractive transmission perspectives in multi-megawatt ECRH systems. In addition, these diplexers are useful for plasma diagnostic systems employing high-power sources due to their filter characteristics. The principle and the design of a four-port quasi-optical resonator diplexer is presented. Low-power measurements of switching contrast, mode purity and efficiency show good agreement with theory. Preliminary frequency modulation characteristics of gyrotrons are shown, and first results from high-power switching experiments using the ECRH system for W7-X are presented.

Terahertz vibrational signature of bacterial spores arising from nanostructure decorated endospore surface.

PubMed

Datta, Debopam; Stroscio, Michael A; Dutta, Mitra; Zhang, Weidong; Brown, Elliott R

2018-05-03

This theoretical effort is the first to explore the possible hypothesis that terahertz optical activity of Bacillus spores arises from normal vibrational modes of spore coat subcomponents in the terahertz frequency range. Bacterial strains like Bacillus and Clostridium form spores with a hardened coating made of peptidoglycan to protect its genetic material in harsh conditions. In recent years, electron microscopy and atomic force microscopy has revealed that bacterial spore surfaces are decorated with nanocylinders and honeycomb nanostructures. In this article, a simple elastic continuum model is used to describe the vibration of these nanocylinders mainly in Bacillus subtilis, which also leads to the conclusion that the terahertz signature of these spores arises from the vibration of these nanostructures. Three vibrating modes: radial/longitudinal, torsional and flexural, have been identified and discussed for the nanocylinders. The effect of bound water, which shifts the vibration frequency, is also discussed. The peptidoglycan molecule consists of polar and charged amino acids; hence, the sporal surface local vibrations interact strongly with the terahertz radiation. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Audiometric notch and extended high-frequency hearing threshold shift in relation to total leisure noise exposure: An exploratory analysis.

PubMed

Wei, Wenjia; Heinze, Stefanie; Gerstner, Doris G; Walser, Sandra M; Twardella, Dorothee; Reiter, Christina; Weilnhammer, Veronika; Perez-Alvarez, Carmelo; Steffens, Thomas; Herr, Caroline E W

2017-01-01

Studies investigating leisure noise effect on extended high frequency hearing are insufficient and they have inconsistent results. The aim of this study was to investigate if extended high-frequency hearing threshold shift is related to audiometric notch, and if total leisure noise exposure is associated with extended high-frequency hearing threshold shift. A questionnaire of the Ohrkan cohort study was used to collect information on demographics and leisure time activities. Conventional and extended high-frequency audiometry was performed. We did logistic regression between extended high-frequency hearing threshold shift and audiometric notch as well as between total leisure noise exposure and extended high-frequency hearing threshold shift. Potential confounders (sex, school type, and firecrackers) were included. Data from 278 participants (aged 18-23 years, 53.2% female) were analyzed. Associations between hearing threshold shift at 10, 11.2, 12.5, and 14 kHz with audiometric notch were observed with a higher prevalence of threshold shift at the four frequencies, compared to the notch. However, we found no associations between total leisure noise exposure and hearing threshold shift at any extended high frequency. This exploratory analysis suggests that while extended high-frequency hearing threshold shifts are not related to total leisure noise exposure, they are strongly associated with audiometric notch. This leads us to further explore the hypothesis that extended high-frequency threshold shift might be indicative of the appearance of audiometric notch at a later time point, which can be investigated in the future follow-ups of the Ohrkan cohort.

Climatic controls on hurricane patterns: a 1200-y near-annual record from Lighthouse Reef, Belize

NASA Astrophysics Data System (ADS)

Denommee, K. C.; Bentley, S. J.; Droxler, A. W.

2014-01-01

Tropical cyclones (TCs) are powerful agents of destruction, and understanding climatic controls on TC patterns is of great importance. Over timescales of seasons to several decades, relationships among TC track, frequency, intensity and basin-scale climate changes are well documented by instrumental records. Over centuries to millennia, climate-shift influence on TC regimes remains poorly constrained. To better understand these relationships, records from multiple locations of TC strikes spanning millennia with high temporal resolution are required, but such records are rare. Here we report on a highly detailed sedimentary proxy record of paleo-TC strikes from the Blue Hole of Lighthouse Reef, Belize. Our findings provide an important addition to other high-resolution records, which collectively demonstrate that shifts between active and inactive TC regimes have occurred contemporaneously with shifts hemispheric-scale oceanic and atmospheric circulation patterns such as MDR SSTs and NAO mode, rather than with changes in local climate phenomena as has previously been suggested.

Raman shifts in electron-irradiated monolayer MoS 2

DOE PAGES

Parkin, William M.; Balan, Adrian; Liang, Liangbo; ...

2016-03-21

Here, we report how the presence of electron-beam-induced sulfur vacancies affects first-order Raman modes and correlate the effects with the evolution of the in situ transmission-electron microscopy (TEM) two-terminal conductivity of monolayer MoS 2 under electron irradiation. We observe a redshift in the E Raman peak and a less pronounced blueshift in the A' 1 peak with increasing electron dose. Using energy-dispersive X-ray spectroscopy (EDS), we show that irradiation causes partial removal of sulfur and correlate the dependence of the Raman peak shifts with S vacancy density (a few %), which is confirmed by first-principles density functional theory calculations. Inmore » situ device current measurements show exponential decrease in channel current upon irradiation. Our analysis demonstrates that the observed frequency shifts are intrinsic properties of the defective systems and that Raman spectroscopy can be used as a quantitative diagnostic tool to characterize MoS 2-based transport channels.« less

A novel piezo vibration platform for probe dynamic performance calibration

NASA Astrophysics Data System (ADS)

Liang, Rong; Jusko, Otto; Lüdicke, Frank; Neugebauer, Michael

2001-09-01

A novel piezo vibration platform of compact size (120×120×120 mm3) for probe dynamic performance calibration has been developed. A piezo tube is employed to generate movement which is measured in real time by a miniature fibre interferometer and close-loop controlled by a fast digital signal processor, thus the calibration can be made traceable to the national length standard. 20 kHz control-loop frequency with 1.71 nm uncertainty has been achieved. The maximum calibration range is 20 µm with 0.3 nm resolution. The piezo vibration platform can generate up to 300 Hz sinusoidal signal and various other waveforms, such as square, triangle and saw tooth. It can also work in sweep mode to shift the frequency up to 100 Hz continuously, which is a very useful function when the amplitude-frequency response of the probe is to be investigated.

Membrane-constrained acoustic metamaterials for low frequency sound insulation

NASA Astrophysics Data System (ADS)

Wang, Xiaole; Zhao, Hui; Luo, Xudong; Huang, Zhenyu

2016-01-01

We present a constrained membrane-type acoustic metamaterial (CMAM) that employs constraint sticks to add out-of-plane dimensions in the design space of MAM. A CMAM sample, which adopts constraint sticks to suppress vibrations at the membrane center, was fabricated to achieve a sound transmission loss (STL) peak of 26 dB at 140 Hz, with the static areal density of 6.0 kg/m2. The working mechanism of the CMAM as an acoustic metamaterial is elucidated by calculating the averaged normal displacement, the equivalent areal density, and the effective dynamic mass of a unit cell through finite element simulations. Furthermore, the vibration modes of the CMAM indicate that the eigenmodes related to STL dips are shifted into high frequencies, thus broadening its effective bandwidth significantly. Three samples possessing the same geometry and material but different constraint areas were fabricated to illustrate the tunability of STL peaks at low frequencies.

Reassessing regime shifts in the North Pacific: incremental climate change and commercial fishing are necessary for explaining decadal-scale biological variability.

PubMed

Litzow, Michael A; Mueter, Franz J; Hobday, Alistair J

2014-01-01

In areas of the North Pacific that are largely free of overfishing, climate regime shifts - abrupt changes in modes of low-frequency climate variability - are seen as the dominant drivers of decadal-scale ecological variability. We assessed the ability of leading modes of climate variability [Pacific Decadal Oscillation (PDO), North Pacific Gyre Oscillation (NPGO), Arctic Oscillation (AO), Pacific-North American Pattern (PNA), North Pacific Index (NPI), El Niño-Southern Oscillation (ENSO)] to explain decadal-scale (1965-2008) patterns of climatic and biological variability across two North Pacific ecosystems (Gulf of Alaska and Bering Sea). Our response variables were the first principle component (PC1) of four regional climate parameters [sea surface temperature (SST), sea level pressure (SLP), freshwater input, ice cover], and PCs 1-2 of 36 biological time series [production or abundance for populations of salmon (Oncorhynchus spp.), groundfish, herring (Clupea pallasii), shrimp, and jellyfish]. We found that the climate modes alone could not explain ecological variability in the study region. Both linear models (for climate PC1) and generalized additive models (for biology PC1-2) invoking only the climate modes produced residuals with significant temporal trends, indicating that the models failed to capture coherent patterns of ecological variability. However, when the residual climate trend and a time series of commercial fishery catches were used as additional candidate variables, resulting models of biology PC1-2 satisfied assumptions of independent residuals and out-performed models constructed from the climate modes alone in terms of predictive power. As measured by effect size and Akaike weights, the residual climate trend was the most important variable for explaining biology PC1 variability, and commercial catch the most important variable for biology PC2. Patterns of climate sensitivity and exploitation history for taxa strongly associated with biology PC1-2 suggest plausible mechanistic explanations for these modeling results. Our findings suggest that, even in the absence of overfishing and in areas strongly influenced by internal climate variability, climate regime shift effects can only be understood in the context of other ecosystem perturbations. © 2013 John Wiley & Sons Ltd.

Investigation of attractive and repulsive interactions associated with ketones in supercritical CO2, based on Raman spectroscopy and theoretical calculations.

PubMed

Kajiya, Daisuke; Saitow, Ken-ichi

2013-08-07

Carbonyl compounds are solutes that are highly soluble in supercritical CO2 (scCO2). Their solubility governs the efficiency of chemical reactions, and is significantly increased by changing a chromophore. To effectively use scCO2 as solvent, it is crucial to understand the high solubility of carbonyl compounds, the solvation structure, and the solute-solvent intermolecular interactions. We report Raman spectroscopic data, for three prototypical ketones dissolved in scCO2, and four theoretical analyses. The vibrational Raman spectra of the C=O stretching modes of ketones (acetone, acetophenone, and benzophenone) were measured in scCO2 along the reduced temperature Tr = T∕Tc = 1.02 isotherm as a function of the reduced density ρr = ρ∕ρc in the range 0.05-1.5. The peak frequencies of the C=O stretching modes shifted toward lower energies as the fluid density increased. The density dependence was analyzed by using perturbed hard-sphere theory, and the shift was decomposed into attractive and repulsive energy components. The attractive energy between the ketones and CO2 was up to nine times higher than the repulsive energy, and its magnitude increased in the following order: acetone < acetophenone < benzophenone. The Mulliken charges of the three solutes and CO2 molecules obtained by using quantum chemistry calculations described the order of the magnitude of the attractive energy and optimized the relative configuration between each solute and CO2. According to theoretical calculations for the dispersion energy, the dipole-induced-dipole interaction energy, and the frequency shift due to their interactions, the experimentally determined attractive energy differences in the three solutes were attributed to the dispersion energies that depended on a chromophore attached to the carbonyl groups. It was found that the major intermolecular interaction with the attractive shift varied from dipole-induced dipole to dispersion depending on the chromophore in the ketones in scCO2. As the common conclusion for the Raman spectral measurements and the four theoretical calculations, solute polarizability, modified by the chromophore, was at the core of the solute-solvent interactions of the ketones in scCO2.

An experimental study of turbulence by phase-contrast imaging in the DIII-D tokamak

NASA Astrophysics Data System (ADS)

Coda, Stefano

1997-10-01

A CO2-laser imaging system employing the Zernike phase-contrast technique was designed, built, installed, and operated on the DIII-D tokamak. This system measures the line integrals of plasma density fluctuations along 16 vertical chords at the outer edge of the tokamak (0.85

Widely tunable laser frequency offset lock with 30 GHz range and 5 THz offset.

PubMed

Biesheuvel, J; Noom, D W E; Salumbides, E J; Sheridan, K T; Ubachs, W; Koelemeij, J C J

2013-06-17

We demonstrate a simple and versatile method to greatly extend the tuning range of optical frequency shifting devices, such as acousto-optic modulators (AOMs). We use this method to stabilize the frequency of a tunable narrow-band continuous-wave (CW) laser to a transmission maximum of an external Fabry-Perot interferometer (FPI) with a tunable frequency offset. This is achieved through a servo loop which contains an in-loop AOM for simple radiofrequency (RF) tuning of the optical frequency over the full 30 GHz mode-hop-free tuning range of the CW laser. By stabilizing the length of the FPI to a stabilized helium-neon (HeNe) laser (at 5 THz offset from the tunable laser) we simultaneously transfer the ~ 1 MHz absolute frequency stability of the HeNe laser to the entire 30 GHz range of the tunable laser. Thus, our method allows simple, wide-range, fast and reproducible optical frequency tuning and absolute optical frequency measurements through RF electronics, which is here demonstrated by repeatedly recording a 27-GHz-wide molecular iodine spectrum at scan rates up to 500 MHz/s. General technical aspects that determine the performance of the method are discussed in detail.

Synthesis and characterization of Ce, Cu co-doped ZnS nanoparticles

NASA Astrophysics Data System (ADS)

Harish, G. S.; Sreedhara Reddy, P.

2015-09-01

Ce, Cu co-doped ZnS nanoparticles were prepared at room temperature using a chemical co-precipitation method. The prepared nanoparticles were characterized by X- ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive analysis of X-rays (EDAX), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) and high resolution Raman spectroscopic techniques. Transmission electron microscopy (TEM) and X-ray diffraction studies showed that the diameter of the particles was around 2-3 nm. Broadened XRD peaks revealed the formation of nanoparticles with a face centered cubic (fcc) structure. DRS studies confirmed that the band gap increased with an increase in the dopant concentration. The Raman spectra of undoped and Ce, Cu ions co-doped ZnS nanoparticles showed longitudinal optical mode and transverse optical mode. Compared with the Raman modes (276 and 351 cm-1) of undoped ZnS nanoparticles, the Raman modes of Ce, Cu co- doped ZnS nanoparticles were slightly shifted towards lower frequency. PL spectra of the samples showed remarkable enhancement in the intensity upon doping.

Radial plasma drifts deduced from VLF whistler mode signals - A modelling study

NASA Astrophysics Data System (ADS)

Poulter, E. M.; Andrews, M. K.; Bailey, G. J.; Moffett, R. J.

1984-05-01

VLF whistler mode signals have previously been used to infer radial plasma drifts in the equatorial plane of the plasmasphere and the field-aligned ionosphere-protonosphere coupling fluxes. Physical models of the plasmasphere consisting of O(+) adn H(+) ions along dipole magnetic field lines, and including radial E x B drifts, are applied to a mid-latitude flux tube appropriate to whistler mode signals received at Wellington, New Zealand, from the fixed frequency VLF transmitter NLK (18.6 kHz) in Seattle, U.S.A. These models are first shown to provide a good representation of the recorded Doppler shift and group delay data. They are then used to simulate the process of deducing the drifts and fluxes from the recorded data. Provided the initial whistler mode duct latitude and the ionospheric contributions are known, the drifts at the equatorial plane can be estimated to about + or - 20 m/s (approximately 10-15 percent), and the two hemisphere ionosphere-protonosphere coupling fluxes to about + or - 10 to the 12th/sq m-sec (approximately 40 percent).

On the analysis of photo-electron spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, C.-Z., E-mail: gao@irsamc.ups-tlse.fr; CNRS, LPT; Dinh, P.M.

2015-09-15

We analyze Photo-Electron Spectra (PES) for a variety of excitation mechanisms from a simple mono-frequency laser pulse to involved combination of pulses as used, e.g., in attosecond experiments. In the case of simple pulses, the peaks in PES reflect the occupied single-particle levels in combination with the given laser frequency. This usual, simple rule may badly fail in the case of excitation pulses with mixed frequencies and if resonant modes of the system are significantly excited. We thus develop an extension of the usual rule to cover all possible excitation scenarios, including mixed frequencies in the attosecond regime. We find thatmore » the spectral distributions of dipole, monopole and quadrupole power for the given excitation taken together and properly shifted by the single-particle energies provide a pertinent picture of the PES in all situations. This leads to the derivation of a generalized relation allowing to understand photo-electron yields even in complex experimental setups.« less

Flattened optical frequency-locked multi-carrier generation by cascading one EML and one phase modulator driven by different RF clocks

NASA Astrophysics Data System (ADS)

Li, Xinying; Xiao, Jiangnan

2015-06-01

We propose a novel scheme for optical frequency-locked multi-carrier generation based on one electro-absorption modulated laser (EML) and one phase modulator (PM) in cascade driven by different sinusoidal radio-frequency (RF) clocks. The optimal operating zone for the cascaded EML and PM is found out based on theoretical analysis and numerical simulation. We experimentally demonstrate 25 optical subcarriers with frequency spacing of 12.5 GHz and power difference less than 5 dB can be generated based on the cascaded EML and PM operating in the optimal zone, which agrees well with the numerical simulation. We also experimentally demonstrate 28-Gbaud polarization division multiplexing quadrature phase shift keying (PDM-QPSK) modulated coherent optical transmission based on the cascaded EML and PM. The bit error ratio (BER) can be below the pre-forward-error-correction (pre-FEC) threshold of 3.8 × 10-3 after 80-km single-mode fiber-28 (SMF-28) transmission.

Normal compression wave scattering by a permeable crack in a fluid-saturated poroelastic solid

NASA Astrophysics Data System (ADS)

Song, Yongjia; Hu, Hengshan; Rudnicki, John W.

2017-04-01

A mathematical formulation is presented for the dynamic stress intensity factor (mode I) of a finite permeable crack subjected to a time-harmonic propagating longitudinal wave in an infinite poroelastic solid. In particular, the effect of the wave-induced fluid flow due to the presence of a liquid-saturated crack on the dynamic stress intensity factor is analyzed. Fourier sine and cosine integral transforms in conjunction with Helmholtz potential theory are used to formulate the mixed boundary-value problem as dual integral equations in the frequency domain. The dual integral equations are reduced to a Fredholm integral equation of the second kind. It is found that the stress intensity factor monotonically decreases with increasing frequency, decreasing the fastest when the crack width and the slow wave wavelength are of the same order. The characteristic frequency at which the stress intensity factor decays the fastest shifts to higher frequency values when the crack width decreases.

Analysis of dynamic cantilever behavior in tapping mode atomic force microscopy.

PubMed

Deng, Wenqi; Zhang, Guang-Ming; Murphy, Mark F; Lilley, Francis; Harvey, David M; Burton, David R

2015-10-01

Tapping mode atomic force microscopy (AFM) provides phase images in addition to height and amplitude images. Although the behavior of tapping mode AFM has been investigated using mathematical modeling, comprehensive understanding of the behavior of tapping mode AFM still poses a significant challenge to the AFM community, involving issues such as the correct interpretation of the phase images. In this paper, the cantilever's dynamic behavior in tapping mode AFM is studied through a three dimensional finite element method. The cantilever's dynamic displacement responses are firstly obtained via simulation under different tip-sample separations, and for different tip-sample interaction forces, such as elastic force, adhesion force, viscosity force, and the van der Waals force, which correspond to the cantilever's action upon various different representative computer-generated test samples. Simulated results show that the dynamic cantilever displacement response can be divided into three zones: a free vibration zone, a transition zone, and a contact vibration zone. Phase trajectory, phase shift, transition time, pseudo stable amplitude, and frequency changes are then analyzed from the dynamic displacement responses that are obtained. Finally, experiments are carried out on a real AFM system to support the findings of the simulations. © 2015 Wiley Periodicals, Inc.

Generation of auroral kilometric and Z mode radiation by the cyclotron maser mechanism

NASA Technical Reports Server (NTRS)

Omidi, N.; Gurnett, D. A.; Wu, C. S.

1984-01-01

The relativistic Doppler-shifted cyclotron resonance condition for EM wave interactions with a plasma defines an ellipse in velocity space when the product of the index of refraction and cosine of the wave normal angle is less than or equal to unity, and defines a partial ellipse when the product is greater than unity. It is also noted that waves with frequencies greater than the gyrofrequency can only resonate with particles moving in the same direction along the magnetic field, while waves with lower frequencies than these resonate with particles moving in both directions along the magnetic field. It is found, in the case of auroral kilometric radiation, that both the upgoing and the downgoing electrons are unstable and can give rise to this radiation's growth. The magnitudes of the growth rates for both the upgoing and downgoing auroral kilometric radiation are comparable, and indicate that the path lengths needed to account for the observed intensities of this radiation are of the order of a few hundred km, which is probably too large. Growth rate calculations for the Z mode radiation show that, for wave frequencies just below the gyrofrequency and wave normal angles at or near 90 deg, the electron distribution is unstable and the growth rates are large enough to account for the observed intensities.

1 million-Q optomechanical microdisk resonators for sensing with very large scale integration

NASA Astrophysics Data System (ADS)

Hermouet, M.; Sansa, M.; Banniard, L.; Fafin, A.; Gely, M.; Allain, P. E.; Santos, E. Gil; Favero, I.; Alava, T.; Jourdan, G.; Hentz, S.

2018-02-01

Cavity optomechanics have become a promising route towards the development of ultrasensitive sensors for a wide range of applications including mass, chemical and biological sensing. In this study, we demonstrate the potential of Very Large Scale Integration (VLSI) with state-of-the-art low-loss performance silicon optomechanical microdisks for sensing applications. We report microdisks exhibiting optical Whispering Gallery Modes (WGM) with 1 million quality factors, yielding high displacement sensitivity and strong coupling between optical WGMs and in-plane mechanical Radial Breathing Modes (RBM). Such high-Q microdisks with mechanical resonance frequencies in the 102 MHz range were fabricated on 200 mm wafers with Variable Shape Electron Beam lithography. Benefiting from ultrasensitive readout, their Brownian motion could be resolved with good Signal-to-Noise ratio at ambient pressure, as well as in liquid, despite high frequency operation and large fluidic damping: the mechanical quality factor reduced from few 103 in air to 10's in liquid, and the mechanical resonance frequency shifted down by a few percent. Proceeding one step further, we performed an all-optical operation of the resonators in air using a pump-probe scheme. Our results show our VLSI process is a viable approach for the next generation of sensors operating in vacuum, gas or liquid phase.

Spectra analysis of nonuniform FBG-based acousto-optic modulator by using Fourier mode coupling theory.

PubMed

Liu, Chao; Pei, Li; Li, Zhuoxuan; Ning, Tigang; Yu, Shaowei; Kang, Zexin

2013-05-10

Fourier mode coupling theory was first employed in the spectral analysis of several nonuniform fiber Bragg grating (FBG)-based acousto-optic modulators (NU-FBG-AOMs) with the effects of Gaussian-apodization (GA), phase shift (PS), and linear chirp (LC). Because of the accuracy and simplicity of the algorithm applied in this model, the modulation performances of these modulators can be acquired effectively and efficiently. Based on the model, the reflected spectra of these modulators were simulated under various acoustic frequencies and acoustically induced strains. The simulation results of the GA-FBG-AOM and PS-FBG-AOM showed that the wavelength spacing between the primary reflection peak and the secondary reflection peak is proportional to the acoustic frequency, and the reflectivity of reflection peaks depends on the acoustically induced strains. But for the LC-FBG-AOM, the wavelength spacing between the neighboring reflection peaks increased linearly and inversely with the acoustic frequency, and the extinction ratio of each peak relates to the acoustically induced strain. These numerical analysis results, which were effectively used in the designs and fabrications of these NU-FBG-AOMs, can broaden the AOM-based application scope and shed light on the performance optimization of optical wavelength-division multiplex system.

Structural-change localization and monitoring through a perturbation-based inverse problem.

PubMed

Roux, Philippe; Guéguen, Philippe; Baillet, Laurent; Hamze, Alaa

2014-11-01

Structural-change detection and characterization, or structural-health monitoring, is generally based on modal analysis, for detection, localization, and quantification of changes in structure. Classical methods combine both variations in frequencies and mode shapes, which require accurate and spatially distributed measurements. In this study, the detection and localization of a local perturbation are assessed by analysis of frequency changes (in the fundamental mode and overtones) that are combined with a perturbation-based linear inverse method and a deconvolution process. This perturbation method is applied first to a bending beam with the change considered as a local perturbation of the Young's modulus, using a one-dimensional finite-element model for modal analysis. Localization is successful, even for extended and multiple changes. In a second step, the method is numerically tested under ambient-noise vibration from the beam support with local changes that are shifted step by step along the beam. The frequency values are revealed using the random decrement technique that is applied to the time-evolving vibrations recorded by one sensor at the free extremity of the beam. Finally, the inversion method is experimentally demonstrated at the laboratory scale with data recorded at the free end of a Plexiglas beam attached to a metallic support.

Sound absorption and transmission through flexible micro-perforated panels backed by an air layer and a thin plate.

PubMed

Bravo, Teresa; Maury, Cédric; Pinhède, Cédric

2012-05-01

This paper describes theoretical and experimental investigations into the sound absorption and transmission properties of micro-perforated panels (MPP) backed by an air cavity and a thin plate. A fully coupled modal approach is proposed to calculate the absorption coefficient and the transmission loss of finite-sized micro-perforated panels-cavity-panel (MPPCP) partitions with conservative boundary conditions. It is validated against infinite partition models and experimental data. A practical methodology is proposed using collocated pressure-velocity sensors to evaluate in an anechoic environment the transmission and absorption properties of conventional MPPCPs. Results show under which conditions edge scattering effects should be accounted for at low frequencies. Coupled mode analysis is also performed and analytical approximations are derived from the resonance frequencies and mode shapes of a flexible MPPCP. It is found that the Helmholtz-type resonance frequency is deduced from the one associated to the rigidly backed MPPCP absorber shifted up by the mass-air mass resonance of the flexible non-perforated double-panel. Moreover, it is shown analytically and experimentally that the absorption mechanisms at the resonances are governed by a large air-frame relative velocity over the MPP surface, with either in-phase or out-of-phase relationships, depending on the MPPCP parameters.

Extended Essay Marking on Screen: Is Examiner Marking Accuracy Influenced by Marking Mode?

ERIC Educational Resources Information Center

Johnson, Martin; Hopkin, Rebecca; Shiell, Hannah; Bell, John F.

2012-01-01

In the UK and elsewhere, large-scale educational assessment agencies are shifting the mode of school examination marking towards having examiners mark examination scripts on screen rather than on paper. This shift has prompted questions about whether the mode of marking might influence examiner marking accuracy, particularly in relation to…

Configuration Effects on Liner Performance

NASA Technical Reports Server (NTRS)

Gerhold, Carl H.; Brown, Martha C.; Jones, Michael G.; Howerton, Brian M.

2012-01-01

The acoustic performance of a duct liner depends not only on the intrinsic properties of the liner but also on the configuration of the duct in which it is used. A series of experiments is performed in the NASA Langley Research Center Curved Duct Test Rig (at Mach 0.275) to evaluate the effect of duct configuration on the acoustic performance of single degree of freedom perforate-over-honeycomb liners. The liners form the sidewalls of the duct's test section. Variations of duct configuration include: asymmetric (liner on one side and hard wall opposite) and symmetric (liner on both sides) wall treatment; inlet and exhaust orientation, in which the sound propagates either against or with the flow; and straight and curved flow path. The effect that duct configuration has on the overall acoustic performance, particularly the shift in frequency and magnitude of peak attenuation, is quantified. The redistribution of incident mode content is shown. The liners constitute the side walls of the liner test section and the scatter of incident horizontal order 1 mode by the asymmetric treatment and order 2 mode by the symmetric treatment into order 0 mode is shown. Scatter of order 0 incident modes into higher order modes is also shown. This redistribution of mode content is significant because it indicates that the liner design can be manipulated such that energy is scattered into more highly attenuated modes, thus enhancing liner performance.

Audiometric Notch and Extended High-Frequency Hearing Threshold Shift in Relation to Total Leisure Noise Exposure: An Exploratory Analysis

PubMed Central

Wei, Wenjia; Heinze, Stefanie; Gerstner, Doris G.; Walser, Sandra M.; Twardella, Dorothee; Reiter, Christina; Weilnhammer, Veronika; Perez-Alvarez, Carmelo; Steffens, Thomas; Herr, Caroline E.W.

2017-01-01

Background: Studies investigating leisure noise effect on extended high frequency hearing are insufficient and they have inconsistent results. The aim of this study was to investigate if extended high-frequency hearing threshold shift is related to audiometric notch, and if total leisure noise exposure is associated with extended high-frequency hearing threshold shift. Materials and Methods: A questionnaire of the Ohrkan cohort study was used to collect information on demographics and leisure time activities. Conventional and extended high-frequency audiometry was performed. We did logistic regression between extended high-frequency hearing threshold shift and audiometric notch as well as between total leisure noise exposure and extended high-frequency hearing threshold shift. Potential confounders (sex, school type, and firecrackers) were included. Results: Data from 278 participants (aged 18–23 years, 53.2% female) were analyzed. Associations between hearing threshold shift at 10, 11.2, 12.5, and 14 kHz with audiometric notch were observed with a higher prevalence of threshold shift at the four frequencies, compared to the notch. However, we found no associations between total leisure noise exposure and hearing threshold shift at any extended high frequency. Conclusion: This exploratory analysis suggests that while extended high-frequency hearing threshold shifts are not related to total leisure noise exposure, they are strongly associated with audiometric notch. This leads us to further explore the hypothesis that extended high-frequency threshold shift might be indicative of the appearance of audiometric notch at a later time point, which can be investigated in the future follow-ups of the Ohrkan cohort. PMID:29319010

A diode laser-based velocimeter providing point measurements in unseeded flows using modulated filtered Rayleigh scattering (MFRS)

NASA Astrophysics Data System (ADS)

Jagodzinski, Jeremy James

2007-12-01

The development to date of a diode-laser based velocimeter providing point-velocity-measurements in unseeded flows using molecular Rayleigh scattering is discussed. The velocimeter is based on modulated filtered Rayleigh scattering (MFRS), a novel variation of filtered Rayleigh scattering (FRS), utilizing modulated absorption spectroscopy techniques to detect a strong absorption of a relatively weak Rayleigh scattered signal. A rubidium (Rb) vapor filter is used to provide the relatively strong absorption; alkali metal vapors have a high optical depth at modest vapor pressures, and their narrow linewidth is ideally suited for high-resolution velocimetry. Semiconductor diode lasers are used to generate the relatively weak Rayleigh scattered signal; due to their compact, rugged construction diode lasers are ideally suited for the environmental extremes encountered in many experiments. The MFRS technique utilizes the frequency-tuning capability of diode lasers to implement a homodyne detection scheme using lock-in amplifiers. The optical frequency of the diode-based laser system used to interrogate the flow is rapidly modulated about a reference frequency in the D2-line of Rb. The frequency modulation is imposed on the Rayleigh scattered light that is collected from the probe volume in the flow under investigation. The collected frequency modulating Rayleigh scattered light is transmitted through a Rb vapor filter before being detected. The detected modulated absorption signal is fed to two lock-in amplifers synchronized with the modulation frequency of the source laser. High levels of background rejection are attained since the lock-ins are both frequency and phase selective. The two lock-in amplifiers extract different Fourier components of the detected modulated absorption signal, which are ratioed to provide an intensity normalized frequency dependent signal from a single detector. A Doppler frequency shift in the collected Rayleigh scattered light due to a change in the velocity of the flow under investigation results in a change in the detected modulated absorption signal. This change in the detected signal provides a quantifiable measure of the Doppler frequency shift, and hence the velocity in the probe volume, provided that the laser source exhibits acceptable levels of frequency stability (determined by the magnitude of the velocities being measured). An extended cavity diode laser (ECDL) in the Littrow configuration provides frequency tunable, relatively narrow-linewidth lasing for the MFRS velocimeter. Frequency stabilization of the ECDL is provided by a proportional-integral-differential (PID) controller based on an error signal in the reference arm of the experiment. The optical power of the Littrow laser source is amplified by an antireflection coated (AR coated) broad stripe diode laser. The single-mode, frequency-modulatable, frequency-stable O(50 mW) of optical power provided by this extended cavity diode laser master oscillator power amplifier (ECDL-MOPA) system provided sufficient scattering signal from a condensing jet of CO2 to implement the MFRS technique in the frequency-locked mode of operation.

Progress in understanding the enhanced pedestal H-mode in NSTX

DOE PAGES

Gerhardt, S. P.; Canik, J. M.; Maingi, R.; ...

2014-08-01

The paper describes the enhanced pedestal (EP) H-mode observed in the National Spherical Torus Experiment (NSTX). The defining characteristics of EP H-mode are given, namely i)transition after the L- to H-mode transition, ii) region of very steep ion temperature gradient, and iii) associated region of strong rotational shear. A newly observed long-pulse EP H-mode example shows quiescent behavior for as long as the heating and current drive sources are maintained. Cases are shown where the region of steep ion temperature gradient is located at the very edge, and cases where it is shifted up to 10 cm inward from themore » plasma edge; these cases are united by a common dependence of the ion temperature gradient on the toroidal rotation frequency shear. EP H-mode examples have been observed across a wide range of q95 and pedestal collisionality. No strong changes in the fluctuation amplitudes have been observed following the eP H-mode transition, and transport analysis indicates that the ion t hermal transport is comparable to or less than anticipated from a simple neoclassical transport model. Cases are shown where EP H-modes were reliably generated, through these low-q95 examples were difficult to sustain. A case where an externally triggered ELM precipitates the transition to EP H-mode is also shown, though an initial experiment designed to trigger EP-H-modes in this fashion was successful.« less

Temporal shaping of quantum states released from a superconducting cavity memory

NASA Astrophysics Data System (ADS)

Burkhart, L.; Axline, C.; Pfaff, W.; Zou, C.; Zhang, M.; Narla, A.; Frunzio, L.; Devoret, M. H.; Jiang, L.; Schoelkopf, R. J.

State transfer and entanglement distribution are essential primitives in network-based quantum information processing. We have previously demonstrated an interface between a quantum memory and propagating light fields in the microwave domain: by parametric conversion in a single Josephson junction, we have coherently released quantum states from a superconducting cavity resonator into a transmission line. Protocols for state transfer mediated by propagating fields typically rely on temporal mode-matching of couplings at both sender and receiver. However, parametric driving on a single junction results in dynamic frequency shifts, raising the question of whether the pumps alone provide enough control for achieving this mode-matching. We show, in theory and experiment, that phase and amplitude shaping of the parametric drives allows arbitrary control over the propagating field, limited only by the drives bandwidth and amplitude constraints. This temporal mode shaping technique allows for release and capture of quantum states, providing a credible route towards state transfer and entanglement generation in quantum networks in which quantum states are stored and processed in cavities.

Fiber-Laser-Based Ultrasound Sensor for Photoacoustic Imaging

PubMed Central

Liang, Yizhi; Jin, Long; Wang, Lidai; Bai, Xue; Cheng, Linghao; Guan, Bai-Ou

2017-01-01

Photoacoustic imaging, especially for intravascular and endoscopic applications, requires ultrasound probes with miniature size and high sensitivity. In this paper, we present a new photoacoustic sensor based on a small-sized fiber laser. Incident ultrasound waves exert pressures on the optical fiber laser and induce harmonic vibrations of the fiber, which is detected by the frequency shift of the beating signal between the two orthogonal polarization modes in the fiber laser. This ultrasound sensor presents a noise-equivalent pressure of 40 Pa over a 50-MHz bandwidth. We demonstrate this new ultrasound sensor on an optical-resolution photoacoustic microscope. The axial and lateral resolutions are 48 μm and 3.3 μm. The field of view is up to 1.57 mm2. The sensor exhibits strong resistance to environmental perturbations, such as temperature changes, due to common-mode cancellation between the two orthogonal modes. The present fiber laser ultrasound sensor offers a new tool for all-optical photoacoustic imaging. PMID:28098201

Modeling of the control of the driven current profile in ICRF MCCD on EAST plasma

NASA Astrophysics Data System (ADS)

Yin, L.; Yang, C.; Gong, X. Y.; Lu, X. Q.; Cao, J. J.; Wu, Z. Y.; Chen, Y.; Du, D.

2018-05-01

Control of the current profile is a crucial issue for improved confinement and the inhibition of instability in advanced tokamak operation. Using typical discharge data for the Experimental Advanced Superconducting Tokamak, numerical simulations of driven-current profile control in mode conversion current drive (MCCD) in the ion cyclotron range of frequencies were performed employing a full-wave method and Ehst-Karney efficiency formula. Results indicate that the driven current profile in MCCD can be effectively modified by shifting the mode conversion layer. The peak of the driven current can be located at an aimed position in the normalized minor radius range (-0.60 ≤r/a≤0) by changing the radiofrequency and the minority-ion concentration. The efficiency of the off-axis MCCD can reach 233 kA/MW through optimization, and the mode converted ion cyclotron wave plays an important role in such scenarios. The effects of electron temperature and plasma density on the driven current profile are also investigated.

Observation of strain effect on the suspended graphene by polarized Raman spectroscopy

PubMed Central

2012-01-01

We report the strain effect of suspended graphene prepared by micromechanical method. Under a fixed measurement orientation of scattered light, the position of the 2D peaks changes with incident polarization directions. This phenomenon is explained by a proposed mode in which the peak is effectively contributed by an unstrained and two uniaxial-strained sub-areas. The two axes are tensile strain. Compared to the unstrained sub-mode frequency of 2,672 cm−1, the tension causes a red shift. The 2D peak variation originates in that the three effective sub-modes correlate with the light polarization through different relations. We develop a method to quantitatively analyze the positions, intensities, and polarization dependences of the three sub-peaks. The analysis reflects the local strain, which changes with detected area of the graphene film. The measurement can be extended to detect the strain distribution of the film and, thus, is a promising technology on graphene characterization. PMID:23013616

Stimulated Brillouin Scattering: its Generation and Applications in Optical Fibre

NASA Astrophysics Data System (ADS)

Culverhouse, David

1992-01-01

Available from UMI in association with The British Library. In the work presented in this thesis, the generation of stimulated Brillouin scattering and its applications in optical fibres is theoretically and experimentally investigated. The study pursues three special cases: (i) Backward stimulated Brillouin scattering in long fibre lengths; (ii) Backward stimulated Brillouin scattering in high finesse all fibre ring resonators; (iii) Forward stimulated Brillouin scattering in dual moded single core fibres. Stimulated Brillouin scattering (SBS) occurs for relatively low input powers in monomode optical fibres, as the power density is very high because of the relatively small core size. For applications such as optical communications, SBS is seen as a potentially deleterious effect because it can limit the maximum optical power transmitted by the fibre and hence decrease the distance between repeaters. SBS, however, can also be used to advantage in optical fibres, for example to produce amplification. In this thesis the comprehensive study of SBS in relation to other non-linear scattering mechanisms in optical fibres leads to the derivation of explicit definitions for the Brillouin gain and the Brillouin threshold. The study of SBS in high finesse all fibre ring resonators also demonstrates how threshold powers can be reduced, typically, from milliwatts observed in long fibre lengths to microwatts. Because Brillouin scattering is primarily a result of the interaction of the incident optical beam with spontaneously generated (thermal) fluctuations in the density of the medium, the spectral features show a considerable variation with temperature thus providing a mechanism with sufficient sensitivity to realise tunable microwave generation and frequency shifting devices. Finally, the observation of stimulated Brillouin scattering in a forward direction (FSBS) in dual moded single-core fibre is also reported. Frequency shifts in the order of 17MHz are observed in optical fibre supporting LP_ {01} and LP_{11} modes at 514.5nm. The phenomenon is examined here in detail and the governing differential equations of the three wave parametric process (involving pump/laser, Brillouin signal and acoustic flexural wave phonon) is derived and solved. FSBS is possible because, although the overlap integral between a fibre flexural mode and the light is small, the phonon lifetime is much longer than in conventional SBS. FSBS may also be the first example of a non-linear effect which is enhanced by increasing the optical mode area at constant pump power.

Multi-mode radio frequency device

DOEpatents

Gilbert, Ronald W [Morgan Hill, CA; Carrender, Curtis Lee [Morgan Hill, CA; Anderson, Gordon A [Benton City, WA; Steele, Kerry D [Kennewick, WA

2007-02-13

A transponder device having multiple modes of operation, such as an active mode and a passive mode, wherein the modes of operation are selected in response to the strength of a received radio frequency signal. A communication system is also provided having a transceiver configured to transmit a radio frequency signal and to receive a responsive signal, and a transponder configured to operate in a plurality of modes and to activate modes of operation in response to the radio frequency signal. Ideally, each mode of operation is activated and deactivated independent of the other modes, although two or more modes may be concurrently operational.

Temperature Measurement by a Nanoscale Electron Probe Using Energy Gain and Loss Spectroscopy

NASA Astrophysics Data System (ADS)

Idrobo, Juan Carlos; Lupini, Andrew R.; Feng, Tianli; Unocic, Raymond R.; Walden, Franklin S.; Gardiner, Daniel S.; Lovejoy, Tracy C.; Dellby, Niklas; Pantelides, Sokrates T.; Krivanek, Ondrej L.

2018-03-01

Heat dissipation in integrated nanoscale devices is a major issue that requires the development of nanoscale temperature probes. Here, we report the implementation of a method that combines electron energy gain and loss spectroscopy to provide a direct measurement of the local temperature in the nanoenvironment. Loss and gain peaks corresponding to an optical-phonon mode in boron nitride were measured from room temperature to ˜1600 K . Both loss and gain peaks exhibit a shift towards lower energies as the sample is heated up. First-principles calculations of the temperature-induced phonon frequency shifts provide insights into the origin of this effect and confirm the experimental data. The experiments and theory presented here open the doors to the study of anharmonic effects in materials by directly probing phonons in the electron microscope.

Effects of hydrogen atom spin exchange collisions on atomic hydrogen maser oscillation frequency

NASA Technical Reports Server (NTRS)

Crampton, S. B.

1979-01-01

Frequency shifts due to collisions between hydrogen atoms in an atomic hydrogen maser frequency standard are studied. Investigations of frequency shifts proportional to the spin exchange frequency shift cross section and those proportional to the duration of exchange collisions are discussed. The feasibility of operating a hydrogen frequency standard at liquid helium temperatures is examined.

Characteristics of hydrogen produced by partial oxidation and auto-thermal reforming in a small methanol reformer

NASA Astrophysics Data System (ADS)

Horng, Rong-Fang; Chou, Huann-Ming; Lee, Chiou-Hwang; Tsai, Hsien-Te

This paper investigates experimentally, the transient characteristics of a small methanol reformer using partial oxidation (POX) and auto-thermal reforming (ATR) for fuel cell applications. The parameters varied were heating temperature, methanol supply rate, steady mode shifting temperature, O 2/C (O 2/CH 3OH) and S/C (H 2O/CH 3OH) molar ratios with the main aim of promoting a rapid response and a high flow rate of hydrogen. The experiments showed that a high steady mode shifting temperature resulted in a faster temperature rise at the catalyst outlet and vice versa and that a low steady mode shifting temperature resulted in a lower final hydrogen concentration. However, when the mode shifting temperature was too high, the hydrogen production response was not necessarily improved. It was subsequently shown that the optimum steady mode shifting temperature for this experimental set-up was approximately 75 °C. Further, the hydrogen concentration produced by the auto-thermal process was as high as 49.12% and the volume flow rate up to 23.0 L min -1 compared to 40.0% and 20.5 L min -1 produced by partial oxidation.

New insights into ETS-10 and titanate quantum wire: a comprehensive characterization.

PubMed

Jeong, Nak Cheon; Lee, Young Ju; Park, Jung-Hyun; Lim, Hyunjin; Shin, Chae-Ho; Cheong, Hyeonsik; Yoon, Kyung Byung

2009-09-16

The titanate quantum wires in ETS-10 crystals remain intact during ion exchange of the pristine cations (Na(+)(0.47) + K(+)(0.53)) with M(n+) ions (M(n+) = Na(+), K(+), Mg(2+), Ca(2+), Sr(2+), Ba(2+), Pb(2+), Cd(2+), Zn(2+)) and during reverse exchange of the newly exchanged cations with Na(+). The binding energies of O(1s) and Ti(2p) decrease as the electronegativity of the cation decreases, and they are inversely proportional to the negative partial charge of the framework oxygen [-delta(O(f))]. At least five different oxygen species were identified, and their binding energies (526.1-531.9 eV) indicate that the titanate-forming oxides are much more basic than those of aluminosilicate zeolites (530.2-533.3 eV), which explains the vulnerability of the quantum wire to acids and oxidants. The chemical shifts of the five NMR-spectroscopically nonequivalent Si sites, delta(I(A)), delta(I(B)), delta(II(A)), delta(II(B)), and delta(III), shift downfield as -delta(O(f)) increases, with slopes of 2.5, 18.6, 133.5, 216.3, and 93.8 ppm/[-delta(O(f))], respectively. The nonuniform responses of the chemical shifts to -delta(O(f)) arise from the phenomenon that the cations in the 12-membered-ring channels shift to the interiors of the cages surrounded by four seven-membered-ring windows. On the basis of the above, we assign delta(I(A)), delta(I(B)), delta(II(A)), and delta(II(B)) to the chemical shifts arising from Si(12,12), Si(12,7), Si(7,12), and Si(7,7) atoms, respectively. The frequency of the longitudinal stretching vibration of the titanate quantum wire increases linearly and the bandwidth decreases nonlinearly with increasing -delta(O(f)), indicating that the titanate quantum wire resembles a metallic carbon nanotube. As the degree of hydration increases, the vibrational frequency shifts linearly to higher frequencies while the bandwidth decreases. We identified another normal mode of vibration of the quantum wire, which vibrates in the region of 274-280 cm(-1). In the dehydrated state, the band-gap energy and the first absorption maximum shift to lower energies as -delta(O(f)) increases, indicating the oxide-to-titanium(IV) charge-transfer nature of the transitions.

Restricted Modal Analysis Applied to Internal Annular Combustor Autospectra and Cross-Spectra Measurements

NASA Technical Reports Server (NTRS)

Miles, Jeffrey Hilton

2007-01-01

A treatment of the modal decomposition of the pressure field in a combustor as determined by two pressure time history measurements is developed herein. It is applied to a Pratt and Whitney PW4098 engine combustor over a range of operating conditions. For modes other than the plane wave the assumption is made that there are distinct frequency bands in which the individual modes, including the plane wave mode, overlap such that if circumferential mode m and circumferential mode m-1 are present then circumferential mode m-2 is not. In the analysis used herein at frequencies above the first cutoff mode frequency, only pairs of circumferential modes are individually present at each frequency. Consequently, this is a restricted modal analysis. As part of the analysis one specifies mode cut-on frequencies. This creates a set of frequencies that each mode spans. One finding was the successful use of the same modal span frequencies over a range of operating conditions for this particular engine. This suggests that for this case the cut-on frequencies are in proximity at each operating condition. Consequently, the combustion noise spectrum related to the circumferential modes might not change much with operating condition.

Magnetic field shift due to mechanical vibration in functional magnetic resonance imaging.

PubMed

Foerster, Bernd U; Tomasi, Dardo; Caparelli, Elisabeth C

2005-11-01

Mechanical vibrations of the gradient coil system during readout in echo-planar imaging (EPI) can increase the temperature of the gradient system and alter the magnetic field distribution during functional magnetic resonance imaging (fMRI). This effect is enhanced by resonant modes of vibrations and results in apparent motion along the phase encoding direction in fMRI studies. The magnetic field drift was quantified during EPI by monitoring the resonance frequency interleaved with the EPI acquisition, and a novel method is proposed to correct the apparent motion. The knowledge on the frequency drift over time was used to correct the phase of the k-space EPI dataset. Since the resonance frequency changes very slowly over time, two measurements of the resonance frequency, immediately before and after the EPI acquisition, are sufficient to remove the field drift effects from fMRI time series. The frequency drift correction method was tested "in vivo" and compared to the standard image realignment method. The proposed method efficiently corrects spurious motion due to magnetic field drifts during fMRI. (c) 2005 Wiley-Liss, Inc.

Voltage-sensing domain mode shift is coupled to the activation gate by the N-terminal tail of hERG channels.

PubMed

Tan, Peter S; Perry, Matthew D; Ng, Chai Ann; Vandenberg, Jamie I; Hill, Adam P

2012-09-01

Human ether-a-go-go-related gene (hERG) potassium channels exhibit unique gating kinetics characterized by unusually slow activation and deactivation. The N terminus of the channel, which contains an amphipathic helix and an unstructured tail, has been shown to be involved in regulation of this slow deactivation. However, the mechanism of how this occurs and the connection between voltage-sensing domain (VSD) return and closing of the gate are unclear. To examine this relationship, we have used voltage-clamp fluorometry to simultaneously measure VSD motion and gate closure in N-terminally truncated constructs. We report that mode shifting of the hERG VSD results in a corresponding shift in the voltage-dependent equilibrium of channel closing and that at negative potentials, coupling of the mode-shifted VSD to the gate defines the rate of channel closure. Deletion of the first 25 aa from the N terminus of hERG does not alter mode shifting of the VSD but uncouples the shift from closure of the cytoplasmic gate. Based on these observations, we propose the N-terminal tail as an adaptor that couples voltage sensor return to gate closure to define slow deactivation gating in hERG channels. Furthermore, because the mode shift occurs on a time scale relevant to the cardiac action potential, we suggest a physiological role for this phenomenon in maximizing current flow through hERG channels during repolarization.

Mode shift of the voltage sensors in Shaker K+ channels is caused by energetic coupling to the pore domain

PubMed Central

Haddad, Georges A.

2011-01-01

The voltage sensors of voltage-gated ion channels undergo a conformational change upon depolarization of the membrane that leads to pore opening. This conformational change can be measured as gating currents and is thought to be transferred to the pore domain via an annealing of the covalent link between voltage sensor and pore (S4-S5 linker) and the C terminus of the pore domain (S6). Upon prolonged depolarizations, the voltage dependence of the charge movement shifts to more hyperpolarized potentials. This mode shift had been linked to C-type inactivation but has recently been suggested to be caused by a relaxation of the voltage sensor itself. In this study, we identified two ShakerIR mutations in the S4-S5 linker (I384N) and S6 (F484G) that, when mutated, completely uncouple voltage sensor movement from pore opening. Using these mutants, we show that the pore transfers energy onto the voltage sensor and that uncoupling the pore from the voltage sensor leads the voltage sensors to be activated at more negative potentials. This uncoupling also eliminates the mode shift occurring during prolonged depolarizations, indicating that the pore influences entry into the mode shift. Using voltage-clamp fluorometry, we identified that the slow conformational change of the S4 previously correlated with the mode shift disappears when uncoupling the pore. The effects can be explained by a mechanical load that is imposed upon the voltage sensors by the pore domain and allosterically modulates its conformation. Mode shift is caused by the stabilization of the open state but leads to a conformational change in the voltage sensor. PMID:21518834

Generating multiple orbital angular momentum vortex beams using a metasurface in radio frequency domain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Shixing; Li, Long, E-mail: lilong@mail.xidian.edu.cn, E-mail: gmshi@xidian.edu.cn; Shi, Guangming, E-mail: lilong@mail.xidian.edu.cn, E-mail: gmshi@xidian.edu.cn

In this paper, an electromagnetic metasurface is designed, fabricated, and experimentally demonstrated to generate multiple orbital angular momentum (OAM) vortex beams in radio frequency domain. Theoretical formula of compensated phase-shift distribution is deduced and used to design the metasurface to produce multiple vortex radio waves in different directions with different OAM modes. The prototype of a practical configuration of square-patch metasurface is designed, fabricated, and measured to validate the theoretical analysis at 5.8 GHz. The simulated and experimental results verify that multiple OAM vortex waves can be simultaneously generated by using a single electromagnetic metasurface. The proposed method paves an effectivemore » way to generate multiple OAM vortex waves in radio and microwave wireless communication applications.« less

A code-aided carrier synchronization algorithm based on improved nonbinary low-density parity-check codes

NASA Astrophysics Data System (ADS)

Bai, Cheng-lin; Cheng, Zhi-hui

2016-09-01

In order to further improve the carrier synchronization estimation range and accuracy at low signal-to-noise ratio ( SNR), this paper proposes a code-aided carrier synchronization algorithm based on improved nonbinary low-density parity-check (NB-LDPC) codes to study the polarization-division-multiplexing coherent optical orthogonal frequency division multiplexing (PDM-CO-OFDM) system performance in the cases of quadrature phase shift keying (QPSK) and 16 quadrature amplitude modulation (16-QAM) modes. The simulation results indicate that this algorithm can enlarge frequency and phase offset estimation ranges and enhance accuracy of the system greatly, and the bit error rate ( BER) performance of the system is improved effectively compared with that of the system employing traditional NB-LDPC code-aided carrier synchronization algorithm.

Acoustically induced oscillation and rotation of a large drop in space

NASA Astrophysics Data System (ADS)

Jacobi, N.; Croonquist, A. P.; Elleman, D. D.; Wang, T. G.

1982-03-01

A 2.5 cm diameter water drop was successfully deployed and manipulated in a triaxial acoustic resonance chamber during a 240 sec low-gravity SPAR rocket flight. Oscillation and rotation were induced by modulating and phase shifting the signals to the speakers. Portions of the film record were digitized and analyzed. Spectral analysis brought out the n = 2, 3, 4 free oscillation modes of the drop, its very low-frequency center-of-mass motion in the acoustic potential well, and the forced oscillation frequency. The drop boundaries were least-square fitted to general ellipses, providing eccentricities of the distorted drop. The normalized equatorial area of the rotating drop was plotted vs a rotational parameter, and was in excellent agreement with values derived from the theory of equilibrium shapes of rotating liquid drops.

Phase difference in modulated signals of two orthogonally polarized outputs of a Nd:YAG microchip laser with anisotropic optical feedback.

PubMed

Zhang, Peng; Tan, Yi-Dong; Liu, Ning; Wu, Yun; Zhang, Shu-Lian

2013-11-01

We present an experimental observation of the output responses of a Nd:YAG microchip laser with an anisotropic external cavity under weak optical feedback. The feedback mirror is stationary during the experiments. A pair of acousto-optic modulators is used to produce a frequency shift in the feedback light with respect to the initial light. The laser output is a beat signal with 40 kHz modulation frequency and is separated into two orthogonal directions by a Wollaston prism. Phase differences between the two intensity curves are observed as the laser works in two orthogonal modes, and vary with the external birefringence element and the pump power. Theoretical analyses are given, and the simulated results are consistent with the experimental phenomena.