Distribution of elements in the Salt Wash member of the Morrison Formation in the Jo Dandy area, Montrose County, Colorado

USGS Publications Warehouse

Newman, William L.; Elston, Donald P.

1957-01-01

A study of the distribution of elements in the Salt Wash member of the Morrison formation of Jurassic age from samples taken in the Jo Dandy area, Montrose County, Colo., was made to determine average chemical composition of mudstone and sandstone and to determine the magnitude of variations in concentrations of elements within similar rock types. Analytical data were obtained by semiquantitative spectrographic and radiometric methods. Results of the study show that variations in concentrations of about 20 elements commonly detected by semiquantititive spectrographic analyses of sedimentary rocks are small for a specific rock type; therefore, considerable confidence may be placed upon the average chemical appears to be no significant relation between chemical composition of mudstone or sandstone and distance from known uranium-vanadium ore or mineralization rock. Mudstone generally contains greater concentrations of the elements studied than sandstone. The chemical composition of red mudstone is similar to the chemical composition of green mudstone except that red mudstone was found to contain almost twice as much calcium as green mudstone in the Jo Dandy area. Samples of the unoxidized sandstone from the Jo Dandy area contain about twice as much calcium, three times as much strontium, but only about one-half as much as zirconium as oxidized sandstone; except for these elements the chemical compositions of both categories of sandstone are similar. Samples of sandstone of the Salt Wash member in the Jo Dandy area contain more potassium, magnesium, vanadium, and nickel than “average sandstone” of the Salt Wash member. The distribution of bismuth in rocks of the Jo Dandy area suggests that bismuth and perhaps part of the potassium and magnesium found in rocks of the Salk Wash member were either derived from solutions which ascended from the underlying salt- and gypsum-bearing Paradox member that was incorporated with rocks of the Salt Wash during sedimentation.

Carbonate-shelf depositional environments of the Ordovician Viola formation in South-Central Kansas

USGS Publications Warehouse

Newell, K.D.

2000-01-01

The Upper Ordovician Viola Formation, an important petroleum reservoir in the Midcontinent, is a carbonate unit present over much of the subsurface in Kansas. The Viola is composed of two fining-upward sedimentary packages that are separated from each other by a minor karstic surface representing a brief period of exposure. Each package represents a third-order sedimentary cycle and consists of an echinoderm-rich packstone overlain by a thicker lime mudstone. The echinoderm-rich packstone was deposited nearshore in agitated waters, but subsequently was bioturbated. The overlying lime mudstone was deposited in deeper, quiet waters, and locally contains storm-deposited carbonate sands. Subtle growth of the Central Kansas Arch and Pratt Anticline (structures transecting the depositional shelf) is indicated by packstones and grainstones being thicker over these arches, whereas finer grained lithologies dominate in basinal areas on the arch flanks. Structureless lime mudstones, probably intensely bioturbated, grade into laminated lime mudstones farther basinward.

Laboratory Testing of Silica Sol Grout in Coal Measure Mudstones.

PubMed

Pan, Dongjiang; Zhang, Nong; Xie, Zhengzheng; Feng, Xiaowei; Kong, Yong

2016-11-22

The effectiveness of silica sol grout on mudstones is reported in this paper. Using X-ray diffraction (XRD), the study investigates how the silica sol grout modifies mudstone mineralogy. Micropore sizes and mechanical properties of the mudstone before and after grouting with four different materials were determined with a surface area/porosity analyser and by uniaxial compression. Tests show that, after grouting, up to 50% of the mesopore volumes can be filled with grout, the dominant pore diameter decreases from 100 nm to 10 nm, and the sealing capacity is increased. Uniaxial compression tests of silica sol grouted samples shows that their elastic modulus is 21%-38% and their uniaxial compressive strength is 16%-54% of the non-grouted samples. Peak strain, however, is greater by 150%-270%. After grouting, the sample failure mode changes from brittle to ductile. This paper provides an experimental test of anti-seepage and strengthening properties of silica sol.

The Cretaceous-Paleogene boundary in the Brazos River area (Texas): new sections and revised interpretations

NASA Astrophysics Data System (ADS)

Hart, M.; Leighton, A.; Yancey, T.; Miller, B.; Smart, C.; Twitchett, R.

2012-04-01

The Brazos River area of Texas is famous for outcrops of the K/Pg transition and lowermost Paleocene strata. A number of new, un-described sections have been investigated and they provide biostratigraphical and sedimentological information on the events preceding, during and following the Chixculub impact event. The mudstones of the Corsicana Formation (Maastrichtian) contain a number of very thin volcanic ashes, including the yellow/white gypsum-rich horizon incorrectly regarded by some workers as evidence of a pre-K/Pg boundary impact. The mudstones of the Corsicana Mudstone Fm (uppermost Maastrichtian) were significantly eroded by the end-Cretaceous tsunami and the surficial unconsolidated muds as well as a thickness of lithified mudstone eroded and put into suspension, thereby providing the reworked Cretaceous assemblages of microfossils recorded by a number of authors. Erosional relief on the 75-100 m deep sea floor is visible in Cottonmouth Creek and the new River Bank South section as a series of ridges and erosional troughs, trending NW-SE. Trough lows are in-filled with mud-matrix mass flow deposits containing large blocks of Maastrichtian mudstones and transported concretions. These are overlain with granular shell-rich sediments containing spherules, fish teeth, bone fragments and re-worked foraminifera and hummocky cross-stratified storm sands with mudstone inter-beds. Sea floor ridges remained exposed to open marine waters and were colonized with a thin oyster pavement before burial by Kincaid Formation mudstones and siltstones. A return to quiet water conditions during the earliest Paleocene is recorded in a new 3-6 m section of foraminifera-rich mudstones, siltstones and sandstones bounded above and below with zones of carbonate and pyrite concretions, best seen in the River bank South section. The foraminiferal sand unit contains steinkerns and phosphatic concretions indicative of a condensed deposit. The P1a/P1b zonal boundary lies near the top of these foraminiferal sands. Our investigations for the foraminifera and other microfossils from these successions are on-going and the newly discovered volcanic ashes are being investigated and dated. The timing of the events at the K/Pg boundary in Texas can be correlated with the successions in Denmark (Stevns Klint) and the Atlantic Ocean (e.g., Demerara Rise), thereby giving an holistic picture of the end-Cretaceous events.

Sedimentology of SPICE (Steptoean positive carbon isotope excursion): A high-resolution trace fossil and microfabric analysis of the middle to late Cambrian Alum Shale Formation, southern Sweden

USGS Publications Warehouse

Egenhoff, Sven; Fishman, Neil; Ahlberg, Per; Maletz, Jorg; Jackson, Allison; Kolte, Ketki; Lowers, Heather; Mackie, James; Newby, Warren; Petrowsky, Matthew

2015-01-01

The Cambrian Alum Shale Formation in the Andrarum-3 core from Scania, southern Sweden, consists of black siliciclastic mudstone with minor carbonate intercalations. Four facies comprise three siliciclastic mudstones and one fine-grained carbonate. The facies reflect deposition along a transect from deep ramp to basin on a Cambrian shelf. The three mudstone facies contain abundant clay clasts and laterally variable siltstone laminae. Bed-load transport processes seem to have dominated deposition on this deep shelf. These sedimentary rocks record mainly event deposition, and only relatively few, thin laminae probably resulted from suspension settling. The Alum Shale Formation deep shelf did not show a bioturbation gradient, but fecal strings are common and Planolites burrows are rare in all mudstone facies. Evidence for biotic colonization indicates that this mudstone environment was not persistently anoxic, but rather was most likely intermittently dysoxic. The Alum Shale Formation in the Andrarum-3 core shows an overall decrease of grain size, preserved energy indicators, and carbonate content upsection interpreted to reflect a deepening upward. The succession can also be divided into four small-scale fining-upward cycles that represent deepening, and four overlying coarsening-upward cycles that represent upward shallowing.

Possible Significance of Early Paleozoic Fluctuations in Bottom Current Intensity, Northwest Iapetus Ocean

NASA Astrophysics Data System (ADS)

Lash, Gary G.

1986-06-01

Sedimentologic and geochemical characteristics of red and green deep water mudstone exposed in the central Appalachian orogen define climatically-induced fluctuations in bottom current intensity along the northwest flank of the Iapetus Ocean in Early and Middle Ordovician time. Red mudstone accumulated under the influence of moderate to vigorous bottom current velocities in oxygenated bottom water produced during climatically cool periods. Interbedded green mudstone accumulated at greater sedimentation rates, probably from turbidity currents, under the influence of reduced thermohaline circulation during global warming periods. The close association of green mudstone and carbonate turbidites of Early Ordovician (late Tremadocian to early Arenigian) age suggests that a major warming phase occurred at this time. Increasing temperatures reduced bottom current velocities and resulted in increased production of carbonate sediment and organic carbon on the carbonate platform of eastern North America. Much of the excess carbonate sediment and organic carbon was transported into deep water by turbidity currents. Although conclusive evidence is lacking, this eustatic event may reflect a climatic warming phase that followed the postulated glacio-eustatic Black Mountain event. Subsequent Middle Ordovician fluctuations in bottom current intensity recorded by thin red-green mudstone couplets probably reflect periodic growth and shrinkage of an ice cap rather than major glacial episodes.

Mechanical Stability of Fractured Rift Basin Mudstones: from lab to basin scale

NASA Astrophysics Data System (ADS)

Zakharova, N. V.; Goldberg, D.; Collins, D.; Swager, L.; Payne, W. G.

2016-12-01

Understanding petrophysical and mechanical properties of caprock mudstones is essential for ensuring good containment and mechanical formation stability at potential CO2 storage sites. Natural heterogeneity and presence of fractures, however, create challenges for accurate prediction of mudstone behavior under injection conditions and at reservoir scale. In this study, we present a multi-scale geomechanical analysis for Mesozoic mudstones from the Newark Rift basin, integrating petropyshical core and borehole data, in situ stress measurements, and caprock stability modeling. The project funded by the U.S. Department of Energy's National Energy Technology Laboratory (NETL) focuses on the Newark basin as a representative locality for a series of the Mesozoic rift basins in eastern North America considered as potential CO2 storage sites. An extensive core characterization program, which included laboratory CT scans, XRD, SEM, MICP, porosity, permeability, acoustic velocity measurements, and geomechanical testing under a range of confining pressures, revealed large variability and heterogeneity in both petrophysical and mechanical properties. Estimates of unconfined compressive strength for these predominantly lacustrine mudstones range from 5,000 to 50,000 psi, with only a weak correlation to clay content. Thinly bedded intervals exhibit up to 30% strength anisotropy. Mineralized fractures, abundant in most formations, are characterized by compressive strength as low as 10% of matrix strength. Upscaling these observations from core to reservoir scale is challenging. No simple one-to-one correlation between mechanical and petrophyscial properties exists, and therefore, we develop multivariate empirical relationships among these properties. A large suite of geophysical logs, including new measurements of the in situ stress field, is used to extrapolate these relationships to a basin-scale geomechanical model and predict mudstone behavior under injection conditions.

Constraints on the Mineralogy of Gale Crater Mudstones from MSL SAM Evolved Water

NASA Technical Reports Server (NTRS)

McAdam, A. C.; Sutter, B.; Franz, H. B.; Hogancamp, J. V. (Clark); Knudson, C. A.; Andrejkovicova, S.; Archer, P. D.; Eigenbrode, J. L.; Ming, D. W.; Mahaffy, P. R.

2017-01-01

The Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments on the Mars Science Laboratory (MSL) have analysed more than 150 micron fines from 14 sites at Gale Crater. Here we focus on the mudstone samples. Two were drilled from sites John Klein (JK) and Cumberland (CB) in the Sheepbed mudstone. Six were drilled from Murray Formation mudstone: Confidence Hills (CH), Mojave (MJ), Telegraph Peak (TP), Buckskin (BK), Oudam (OU), Marimba (MB). SAM's evolved gas analysis mass spectrometry (EGA-MS) detected H2O, CO2, O2, H2, SO2, H2S, HCl, NO, and other trace gases, including organic fragments. The identity and evolution temperature of evolved gases can support CheMin mineral detection and place constraints on trace volatile-bearing phases or phases difficult to characterize with X-ray diffraction (e.g., amorphous phases). Here we will focus on SAM H2O data and comparisons to SAM-like analyses of key reference materials.

Mineral Trends in Early Hesperian Lacustrine Mudstone at Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Ming, D. W.; Grotzinger, J. P.; Morris, R. V.; Blake, D. F.; Vaniman, D. T.; Bristow, T. F.; Morrison, S. M.; Yen, A. S.; Chipera, S. J.;

Shear Resistance Variations in Experimentally Sheared Mudstone Granules: A Possible Shear-Thinning and Thixotropic Mechanism

NASA Astrophysics Data System (ADS)

Hu, Wei; Xu, Qiang; Wang, Gonghui; Scaringi, Gianvito; Mcsaveney, Mauri; Hicher, Pierre-Yves

2017-11-01

We present results of ring shear frictional resistance for mudstone granules of different size obtained from a landslide shear zone. Little rate dependency of shear resistance was observed in sand-sized granules in any wet or dry test, while saturated gravel-sized granules exhibited significant and abrupt reversible rate-weakening (from μ = 0.6 to 0.05) at about 2 mm/s. Repeating resistance variations occurred also under constant shear displacement rate. Mudstone granules generate mud as they are crushed and softened. Shear-thinning and thixotropic behavior of the mud can explain the observed behavior: with the viscosity decreasing, the mud can flow through the coarser soil pores and migrate out from the shear zone. This brings new granules into contact which produces new mud. Thus, the process can start over. Similarities between experimental shear zones and those of some landslides in mudstone suggest that the observed behavior may play a role in some landslide kinematics.

Laboratory Testing of Silica Sol Grout in Coal Measure Mudstones

PubMed Central

Pan, Dongjiang; Zhang, Nong; Xie, Zhengzheng; Feng, Xiaowei; Kong, Yong

2016-01-01

The effectiveness of silica sol grout on mudstones is reported in this paper. Using X-ray diffraction (XRD), the study investigates how the silica sol grout modifies mudstone mineralogy. Micropore sizes and mechanical properties of the mudstone before and after grouting with four different materials were determined with a surface area/porosity analyser and by uniaxial compression. Tests show that, after grouting, up to 50% of the mesopore volumes can be filled with grout, the dominant pore diameter decreases from 100 nm to 10 nm, and the sealing capacity is increased. Uniaxial compression tests of silica sol grouted samples shows that their elastic modulus is 21%–38% and their uniaxial compressive strength is 16%–54% of the non-grouted samples. Peak strain, however, is greater by 150%–270%. After grouting, the sample failure mode changes from brittle to ductile. This paper provides an experimental test of anti-seepage and strengthening properties of silica sol. PMID:28774061

Application of self-balanced loading test to socketed pile in weak rock

NASA Astrophysics Data System (ADS)

Cheng, Ye; Gong, Weiming; Dai, Guoliang; Wu, JingKun

2008-11-01

Method of self-balanced loading test differs from the traditional methods of pile test. The key equipment of the test is a cell. The cell specially designed is used to exert load which is placed in pile body. During the test, displacement values of the top plate and the bottom plate of the cell are recorded according to every level of load. So Q-S curves can be obtained. In terms of test results, the bearing capacity of pile can be judged. Equipments of the test are simply and cost of it is low. Under some special conditions, the method will take a great advantage. In Guangxi Province, tertiary mudstone distributes widely which is typical weak rock. It is usually chosen as the bearing stratum of pile foundation. In order to make full use of its high bearing capacity, pile is generally designed as belled pile. Foundations of two high-rise buildings which are close to each other are made up of belled socketed piles in weak rock. To obtain the bearing capacity of the belled socketed pile in weak rock, loading test in situ should be taken since it is not reasonable that experimental compression strength of the mudstone is used for design. The self-balanced loading test was applied to eight piles of two buildings. To get the best test effect, the assembly of cell should be taken different modes in terms of the depth that pile socketed in rock and the dimension of the enlarged toe. The assembly of cells had been taken three modes, and tests were carried on successfully. By the self-balanced loading test, the large bearing capacities of belled socketed piles were obtained. Several key parameters required in design were achieved from the tests. For the data of tests had been analyzed, the bearing performance of pile tip, pile side and whole pile was revealed. It is further realized that the bearing capacity of belled socketed pile in the mudstone will decrease after the mudstone it socketed in has been immerged. Among kinds of mineral ingredient in the mudstone, montmorillonite is much. And in the size composition, content of cosmid is high. For specific surface area of cosmid is large and water intake capacity of it is strong, water content has great effect on strength of the mudstone. Along with water content increasing, strength of the mudstone declines nonlinear apparently. Since effective measures had been taken, the mudstone was prohibited from being immerged during construction. And valuable experience has been accumulated for similar projects construction henceforth.

The Implementation of 2-D Resistivity Method in Verifying Paleozoic Aquifer Properties at Bukit Chondong, Perlis (Malaysia)

NASA Astrophysics Data System (ADS)

Maslinda, Umi; Nordiana, M. M.; Bery, A. A.; Afiq Saharudin, Muhamad; Hisham, Hazrul; Taqiuddin, Z. M.; Sulaiman, Nabila; Nur Amalina, M. K. A.; Nordiana, A. N.

2017-04-01

The research was conducted using 2-D resistivity in verifying Paleozoic aquifer. Since most geologic materials behave as electrical insulators, surface measurements of earth resistivity are controlled by the electrolytic ability of interstitial water. The subsurface distribution of water is controlled by the porosity of the formations. The study area is at Bukit Chondong, Beseri, Perlis. Bukit Chondong is made of sedimentary rock which mostly is sandstone. Bukit Chondong is from uppermost of the Kubang Pasu Formation that represented by a thick unit of grey mudstone interbedded with sandstone. The Kubang Pasu Formation was influenced by shallow marine during the early age. Paleocurrent and fossils traces were found on the mudstone at the study area. The area is suspected to be a Paleozoic aquifer because the sandstone can be a productive aquifer with diffuse flow. The water movement in sandstone is through the fractures and joints. Most of the water stores and transmits in sandstone. The interbedded sandstone and mudstone is one of the aquifer characteristic. Sandstone and mudstone are water-bearing rocks and low-permeable rocks respectively. The data was processed according to the geological information of the study area since there was an outcrop. The study area have low resistivity value which both sandstone and mudstone give less than 800 Ohm-m due to the water content (Sulphide and clay).

Making synthetic mudstone: Parametric resedimentation studies at high effective stress to determine controls on breakthrough pressure and permeability

NASA Astrophysics Data System (ADS)

Guiltinan, E. J.; Cardenas, M. B.; Cockrell, L.; Espinoza, N.

2017-12-01

The geologic sequestration of CO2 is widely considered a potential solution for decreasing anthropogenic atmospheric CO2 emissions. As CO2 rises buoyantly within a reservoir it pools beneath a caprock and a pressure is exerted upon the pores of the caprock proportionally to the height of the pool. The breakthrough pressure is the point at which CO2 begins to flow freely across the caprock. Understanding the mineralogical and grain size controls on breakthrough pressure is important for screening the security of CO2 sequestration sites. However, breakthrough pressure and permeability measurements on caprocks are difficult to conduct in a systematic manner given the variability in and heterogeneity of naturally occurring mudstones and shales causing significant noise and scatter in the literature. Recent work has even revealed the ability for CO2 to pass through thin shale beds at relatively low pressures. To broaden the understanding of shale breakthrough and permeability, we developed an approach that allows for the creation of resedimented mudstones at high effective stresses. Resedimented samples also include calcium carbonate cement. Using this technique, we explore the controls on entry pressure, breakthrough pressure, and permeability of synthetic mudstones. Understanding the effect of mineralogy and grain size on the permeability and breakthrough pressure of mudstones at reservoir stresses will help in the selection and uncertainty quantification of secure CO2 storage sites.

SUBSURFACE WELL-LOG CORRELATION OF ARSENIC-BEARING LITHOFACIES IN THE PERMIAN GARBER SANDSTONE AND WELLINGTON FORMATION, CENTRAL OKLAHOMA AQUIFER (COA), CLEVELAND COUNTY, OKLAHOMA

EPA Science Inventory

The fluvial Garber Sandstone and the underlying Wellington Formation are important sources of drinking water in central Oklahoma. These formations, which make up much of the COA, consist of amalgamated sandstones with some interbedded mudstones, siltstones, and local mudstone- a...

Conservatism of Late Pennsylvanian vegetational patterns during short-term cyclic and long-term directional environmental change, western equatorial Pangea.

PubMed

Tabor, Neil J; Romanchock, Charles M; Looy, Cynthia V; Hotton, Carol L; Dimichele, William A; Chaney, Dan S

2013-09-19

Patterns of plant distribution by palaeoenvironment were examined across the Pennsylvanian-Permian transition in North-Central Texas. Stratigraphically recurrent packages of distinct lithofacies, representing different habitats, contain qualitatively and quantitatively different macrofloras and microfloras. The species pools demonstrate niche conservatism, remaining closely tied to specific habitats, during both short-term cyclic environmental change and a long-term trend of increasing aridity. The deposits examined principally comprise the terrestrial Markley and its approximate marine equivalent, the Harpersville Formation and parts of lower Archer City Formation. Fossiliferous deposits are lens-like, likely representing fill sequences of channels formed during abandonment phases. Palaeosols, represented by blocky mudstones, comprise a large fraction of the deposits. They suggest progressive climate change from minimally seasonal humid to seasonal subhumid to seasonal dry subhumid. Five lithofacies yielded plants: kaolinite-dominated siltstone, organic shale, mudstone beds within organic shale, coarsening upward mudstone-sandstone interbeds and channel sandstone. Both macro- and microflora were examined. Lithofacies proved compositionally distinct, with different patterns of dominance diversity. Organic shales (swamp deposits), mudstone partings (swamp drainages) and coarsening upward mudstone-sandstone interbeds (floodplains) typically contain Pennsylvanian wetland vegetation. Kaolinite-dominated siltstones and (to the extent known) sandstones contain taxa indicative of seasonally dry substrates. Some kaolinite-dominated siltstones and organic shales/coals yielded palynomorphs. Microfloras are more diverse, with greater wetland-dryland overlap than macrofloras. It appears that these two floras were coexistent at times on the regional landscape.

Depositional settings and evolution of a fjord system during the carboniferous glaciation in Northwest Argentina

NASA Astrophysics Data System (ADS)

Alonso-Muruaga, Pablo J.; Limarino, Carlos O.; Spalletti, Luis A.; Colombo Piñol, Ferrán

2018-07-01

Fjord systems, represented by glacial diamictites and postglacial transgressive shales, formed in the basins of western Argentina during the late Carboniferous Gondwana glaciation. Well exposed fjord deposits of the Guandacol Formation were studied in the Loma de Los Piojos region (Protoprecordillera), where they fill a 2.9 km wide paleovalley with steep side walls and a relatively flat floor. The valley cross-cuts Lower Devonian sandstones and Mississippian mudstones and sandstones, and provides evidence of glacial abrasion, including striated pavements and glacial microtopography (grooves, ridges, and striae). Based on the analysis of seven sedimentary logs, eight sedimentary facies in the valley fill were recognized: (A) Massive diamictites; (B) Laminated mudstones with dropstones; (C) Stratified diamictites; (D) Clast-supported conglomerates and sandstones; (E) Deformed diamictites, conglomerates and sandstones; (F) Folded diamictites; (G) Mudstones interbedded with sandstones, and (H) Stacked and amalgamated sandstones. These sedimentary facies are grouped into two principal facies assemblages that represent different stages of the paleovalley fill. Assemblage 1 is composed of diamictites (Facies A, C and F), laminated mudstones with dropstones (Facies B), and conglomerates (Facies D and E), which represent glacially influenced sedimentation in the paleovalley. Assemblage 2 represents the paleovalley fill when glacial influence ceased, and comprises laminated mudstones interbedded with sandstones (facies G) and stacked sandstone beds (facies H) that mostly record deltaic sedimentation. Stratigraphic relationships, plant fossils found in the paleovalley walls and palynological assemblages recovered in mudstones of facies D help to establish an early Pennsylvanian age for both the incision and the filling of the paleovalley. The studied paleovalley records an exceptional example of the western Gondwanan glacial to postglacial transition. Due to the continuous stratigraphic succession within the paleovalley as well as palynological, megafloristic and radiometric data, this example provides a complete framework of the late Carboniferous postglacial evolution in western Gondwana.

Astronomical forcing of a Middle Permian chert sequence in Chaohu, South China

NASA Astrophysics Data System (ADS)

Yao, Xu; Zhou, Yaoqi; Hinnov, Linda A.

2015-07-01

Astronomical forcing has been shown to be a fundamental driver of climate change through geological time. Pelagic, bedded cherts deposited in Mesozoic ocean basins with chert-mudstone cycles have been shown to contain the imprint of Milankovitch astronomical climate forcing. In the Chaohu region, South China, we studied a Middle Permian radiolarian chert sequence (Gufeng Formation) with chert-mudstone couplets reminiscent of the Mesozoic cherts, but deposited on a continental shelf. Spectral analysis of lithologic bed thickness data from two sections of this chert sequence reveals that 13 cm to 20 cm chert-mudstone cycles in the stratigraphic domain match theoretical 32-kyr Middle Permian obliquity cycling, together with a hierarchy of other cycles with 12 cm, 9 cm, 7 cm, 6.6 cm and 5.4 cm wavelengths. Tuning the 13 cm to 20 cm stratigraphic cycles to Earth's obliquity cycle periodicity indicates that the cm-scale cycles are precession-scale variations with a strong ∼400 kyr amplitude modulation. Tuning to theoretical precession terms provides further support for the astronomical forcing of the chert sequence. We propose that monsoon-controlled upwelling contributed to the development of the chert-mudstone cycles. A seasonal monsoon controlled by astronomical forcing (i.e., insolation) influenced the intensity of upwelling. Stronger upwelling increased radiolarian productivity in the surface ocean, increasing silica deposition. Glacio-eustatic oscillations from ice sheet dynamics in southern Gondwana modulated terrigenous mud flux to the basin. The two processes jointly contributed to the astronomical rhythms of these tropical chert-mudstone sequences, which are characterized by comparably strong obliquity and precession responses. Subsequent diagenesis distorted the chert and mudstone layering, but not enough to destroy the original stratigraphic patterns. The resulting astronomical time scale (ATS) assumes a Roadian/Wordian boundary age of 268.8 Ma for the onset of the first chert layer at the base of the sequence and ends at 264.1 Ma, for a total duration of 4.7 myr.

Depositional facies, environments and sequence stratigraphic interpretation of the Middle Triassic-Lower Cretaceous (pre-Late Albian) succession in Arif El-Naga anticline, northeast Sinai, Egypt

NASA Astrophysics Data System (ADS)

El-Azabi, M. H.; El-Araby, A.

2005-01-01

The Middle Triassic-Lower Cretaceous (pre-Late Albian) succession of Arif El-Naga anticline comprises various distinctive facies and environments that are connected with eustatic relative sea-level changes, local/regional tectonism, variable sediment influx and base-level changes. It displays six unconformity-bounded depositional sequences. The Triassic deposits are divided into a lower clastic facies (early Middle Triassic sequence) and an upper carbonate unit (late Middle- and latest Middle/early Late Triassic sequences). The early Middle Triassic sequence consists of sandstone with shale/mudstone interbeds that formed under variable regimes, ranging from braided fluvial, lower shoreface to beach foreshore. The marine part of this sequence marks retrogradational and progradational parasequences of transgressive- and highstand systems tract deposits respectively. Deposition has taken place under warm semi-arid climate and a steady supply of clastics. The late Middle- and latest Middle/early Late Triassic sequences are carbonate facies developed on an extensive shallow marine shelf under dry-warm climate. The late Middle Triassic sequence includes retrogradational shallow subtidal oyster rudstone and progradational lower intertidal lime-mudstone parasequences that define the transgressive- and highstand systems tracts respectively. It terminates with upper intertidal oncolitic packstone with bored upper surface. The next latest Middle/early Late Triassic sequence is marked by lime-mudstone, packstone/grainstone and algal stromatolitic bindstone with minor shale/mudstone. These lower intertidal/shallow subtidal deposits of a transgressive-systems tract are followed upward by progradational highstand lower intertidal lime-mudstone deposits. The overlying Jurassic deposits encompass two different sequences. The Lower Jurassic sequence is made up of intercalating lower intertidal lime-mudstone and wave-dominated beach foreshore sandstone which formed during a short period of rising sea-level with a relative increase in clastic supply. The Middle-Upper Jurassic sequence is represented by cycles of cross-bedded sandstone topped with thin mudstone that accumulated by northerly flowing braided-streams accompanying regional uplift of the Arabo-Nubian shield. It is succeeded by another regressive fluvial sequence of Early Cretaceous age due to a major eustatic sea-level fall. The Lower Cretaceous sequence is dominated by sandy braided-river deposits with minor overbank fines and basal debris flow conglomerate.

Pyritized mudstone and associated facies in the Permian-Triassic boundary of the Çürük Daǧ section, Southern Turkey

NASA Astrophysics Data System (ADS)

Varol, Baki; Koşun, Erdal; Ünal Pinar, Neslihan; Ayranci, Korhan

2011-03-01

This paper is the first study of pyritized mudstones (PM) in the Permian-Triassic (P-T) boundary section of the Çürük Dağ (Taurus, Antalya Nappes, Turkey). The mudstones were generally formed as lensoidal-shaped layers or infill materials within nodular platform limestones (hardground). Normal marine fauna is diminished in the pyritized limestones, whereas tube-like microorganisms are apparently increased with the association of pyrite crystals consisting of both framboidal and cubic crystals. The total rock volumes are up to 50-60% clay minerals and are mainly made up of in situ kaolinite and subordinate mixed layer clays (illite-vermiculite). Kaolinite preferentially developed on feldspar crystals, sometimes covering ostracoda bivalves together with gypsum micronodules composed of fan-shaped gypsum crystals. The origin of the kaolinite is, in situ, directly related to feldspar dissolution via heterotrophic bacteria. Thus, kaolinite is found along with bacterial structures. Other mineralogical compositions include established quartz (mostly β-quartz), gypsum crystals (100-200 μm) glauconite and magnetite. Magnetite grains comprise a minor amount (1-2%) and show some bacterial-induced crystal orientations. Glauconite is formed as an accessory mineral that occurs as infill material in biogenic grains. On the other hand, some microspheres represented by a silica-dominated composition are only observed in scanning electron microscopes (SEM) studies under high magnification. Isotope values (d34S) obtained from the pyritized mudstones show an isotopic heterogeneity that suggests that the pyritized mudstone consists of at least two components, with different sulphur-concentrations and d34S values.

Mudstone sedimentation at high latitudes: Ice as a transport medium for mud and supplier of nutrients

USGS Publications Warehouse

Macquaker, J.H.S.; Keller, M.A.

2005-01-01

Controls on mudstone deposition at high latitudes are poorly known relative to low latitudes. In recent sediments deposited in these environments, ice significantly influences sediment transport and primary productivity. The products of ice transport are relatively well known in glacimarine settings, but are less well known from below melting sea ice. This latter setting is significant as today it is associated with high primary organic productivity. The aim of this study is to assess how sea ice might have controlled lithofacies variability and organic-matter distribution and preservation in an ancient marine, siliciclastic mudstone-dominated succession deposited at high latitudes. Combined sedimentary logging, optical and electron optical (back-scatte red electron imagery), geochemical, and isotopic methods were used to determine sample variability in forty-five samples collected from the Lower Cretaceous succession in the Mikkelsen Bay State #1 borehole (North Slope, Alaska). The succession overall fines upward and contains muddy sandstones and sand- and silt-bearing, clay-rich mudstones towards its base in contrast to clay-rich and clay-dominated mudstones towards its top. Some of the mudstone units exhibit thin (< 5 mm), relic-beds that fine upward weakly. In some units small (0.5 mm), bed-parallel silt-filled microburrows disrupt depositional laminae whereas in others pervasive burrowing completely obliterates original depositional textures. Many of the units are pelleted. These mudstones are unusual in that they contain minor but very striking outsize grains, composed of subrounded to rounded sand and granule-size material. In addition, they are good petroleum source rocks, with between 2.8 and 5.9 wt % total organic carbon, of predominantly Type II kerogen. The organic matter has an isotopic signature ranging from -25.4??? ??13C to -28.1??? ??13C. Thin tuffs (< 20 mm) and carbonate-cemented units are also present. Given the absence of significant polar ice in the Early Cretaceous the outsized grains are interpreted to have been deposited from a combination of melting, dirty anchor, and fast ice. The mud fraction, which forms the bulk of the sediment, is interpreted to have been deposited from melting, sediment-laden frazil ice, and fast ice. After deposition sediments were partially reworked by bottom currents generated by brine rejection during sea ice formation. Sympagic organisms, grazing on algae and bacteria both within and below the ice, pelleted the sediment. Bioturbation, which varies through the succession, indicates that sedimentation probably occurred beneath a predominantly oxic or dysoxic water column. In this setting productivity was fueled by nutrients released from melting sea ice in the marginal ice zone. The good petroleum source potential of these mudstones is attributed to high organic productivity coupled to episodic and rapid sedimentation rather than existence of bottom-water anoxia linked to upwelling. Because sea-ice rafting was probably the dominant sediment transport mechanism it is not appropriate to use sequence stratigraphic methodology to predict lithofacies variability in this environment. Copyright ?? 2005, SEPM (Society for Sedimentary Geology).

Characterization of the mississippian chat in South-central Kansas

USGS Publications Warehouse

Watney, W.L.; Guy, W.J.; Byrnes, A.P.

2001-01-01

To understand production from low resistivity-high porosity Mississippian chat reservoirs in south-central Kansas it is necessary to understand the nature of deposition and diagenesis, how tectonics is a factor, the lithofacies controls on petrophysical properties, and log response to these properties. The initial mudstones to sponge-spicule wacke-packstones were deposited in transgressive-regressive (T-R) cycles on a shelf to shelf margin setting, resulting in a series of shallowing-upward cycles. Sponge-spicule content appears to increase upward with increasing cycle thickness. After early silicification, inter- and post-Mississippian subaerial exposure resulted in further diagenesis, including sponge-spicule dissolution, vuggy porosity development in moldic-rich rocks, and autobrecciation. Meteoric water infiltration is limited in depth below the exposure surface and in distance downdip into unaltered, cherty Cowley Formation facies. Areas of thicker preserved chat and increased diagenesis can be correlated with structural lineaments and, in some areas, with recurrent basement block movement. Combination of folding or block fault movement prior to or during development of the basal Pennsylvanian unconformity, sponge-spicule concentration, and possibly thickness of overlying bioclastic wacke-grainstones resulted in variable reservoir properties and the creation of pods of production separated by nonproductive cherty dolomite mudstones. These events also resulted in alteration of the depositional cycles to produce a series of lithofacies that exhibit unique petrophysical properties. From bottom to top in a complete cycle seven lithofacies are present: (1) argillaceous dolomite mudstone, (2) argillaceous dolomite mudstone that has chert nodules, (3) clean dolomite mudstone that has nodular chert, (4) nodular to bedded chert, (5) autoclastic chert, (6) autoclastic chert that has clay infill, and (7) bioclastic wacke-grainstone. The uppermost cycle was terminated by another lithofacies, a chert conglomerate of Mississippian and/or Pennsylvanian age. The chert facies exhibit porosities ranging from 25 to 50% and permeabilities greater than 5 md. The cherty dolomite mudstones, argillaceous dolomite mudstones, and bioclastic wacke-grainstones exhibit nonreservoir properties. Reservoir production, numerical simulation, and whole core data indicate fracturing can be present in chat reservoirs and can enhance permeability by as much as an order of magnitude. Capillary pressure data indicate the presence of microporosity and can explain high water saturations and low resistivity observed in wire-line logs. Relative permeabilities to oil decrease rapidly for saturations greater than 60% and may be influenced by dual pore systems. Archie cementation exponents increase from 1.8 for mudstones to more than 2.5 in the cherts that have increasing sponge-spicule mold and vug content. Detailed modified Pickett plot analysis of logs reveals critical aspects of chat character and can provide reliable indices of reservoir properties and pay delineation. Models developed provide additional insight into the chat of south-central Kansas and understanding of the nature of controls on shallow-shelf chert reservoir properties.

Topographic inversion of early interdune deposits, Navajo Sandstone (Lower Jurassic), Colorado Plateau, USA

NASA Astrophysics Data System (ADS)

Bromley, Michael

1992-09-01

Outliers of Navajo Sandstone (Lower Jurassic Glen Canyon Group) form low paleohills east of the main body of the Formation in the Salt Anticline region of southwestern Colorado. The paleohills consist of interdune deposits which developed topographic inversion during erosion of the Jurassic J-2 unconformity owing to a tough shell of early cemented sandstones and cherty limestones. The interdune deposits accumulated over playa mudstones of the Kayenta Formation which formed in a structural low between the Uncompahgre Uplift and the Paradox Valley salt anticline. Open-framework textures indicate the early formation of quartz or chert cement in sandstone beds immediately above the impermeable playa mudstones. The mudstones enhanced the subsequent formation of wet interdune deposits keeping groundwater near the surface. Microcrystalline quartz cements and fresh feldspars suggest that groundwater was alkaline. A source of alkalinity may have been eolian dust carried from emergent Pennsylvanian evaporite intrusions upwind of the playa deposits. The high specific surface of siliceous and evaporite dusts combined with shallow groundwater and high evaporation rates resulted in the rapid formation of quartzitic silcrete crusts above the playa mudstone aquacludes. As these early silcretes were buried, the impermeable mudstone foundations beneath them continued to serve as aquacludes. The inclined potentiometric surface of perched water tables above the isolated aquacludes intersected the land surface at progressively higher levels as the mudstone lenses were buried. Groundwater moving laterally from above the aquacludes carried dissolved material towards the inclined water tables at their margins. This mobilized material was redeposited as early cement where the capillary fringe intersected the land surface. As the land surface aggraded vertically, the zone of cement formation migrated laterally in response of a change of the relative positions of the land surface and an inclined perched water table. The final products of this process were topographic remnants of Navajo Sandstone with a resistant rind of cemented material enclosing a core of leached, compacted and friable sandstones. Erosion of the J-2 unconformity left the cemented rind in relief while removing all material around it. The resulting hills survived the onlap of the Middle Jurassic Entrada Formation, leaving considerable relief beneath the unconformity.

Mudstone Mineralogy from Curiosity CheMin, 2013 to 2016

NASA Image and Video Library

2016-12-13

This series of pie charts shows similarities and differences in the mineral compositions of mudstones at 10 sites where NASA's Curiosity Mars rover collected rock-powder samples and analyzed them with the rover's Chemistry and Mineralogy (CheMin) instrument. The charts are arrayed in chronological order, with an indication of relative elevation as the rover first sampled two sites on the floor of Gale Crater in 2013 and later began climbing the crater's central mound, Mount Sharp. The pie chart farthest to the right and uphill shows composition at the "Sebina" target, sampled in October 2016. Five non-mudstone rock targets that the rover drilled and analyzed within this time frame are not included. The mineralogical variations in these mudstones may be due to differences in any or all of these factors: the source materials deposited by water that entered lakes, the processes of sedimentation and rock forming, and how the rocks were later altered. One trend that stands out is that the mineral jarosite -- shown in purple -- was more prominent in the "Pahrump Hills" area of lower Mount Sharp than at sites examined either earlier or later. Jarosite is an indicator of acidic water. Mudstone layers uphill from Pahrump Hills have barely detectable amounts of jarosite, indicating a shift away from acidic conditions in these overlying -- thus younger -- layers. Clay minerals, shown as green, declined in abundance at sites midway through this series, then came back as the rover climbed higher. Each drilled-and-analyzed target is identified with a two-letter abbreviation: JK for "John Klein," CB for "Cumberland." CH for "Confidence Hills," MJ for "Mojave," TP for "Telegraph Peak," BK for "Buckskin," OD for "Oudam," MB for "Marimba," QL for "Quela," and SB for Sebina. http://photojournal.jpl.nasa.gov/catalog/PIA21146

Geochemical signature of provenance, tectonics and chemical weathering in the Quaternary flood plain sediments of the Hindon River, Gangetic plain, India

NASA Astrophysics Data System (ADS)

Mondal, M. E. A.; Wani, H.; Mondal, Bulbul

2012-09-01

The Ganga basin in the Himalayan foreland is a part of the world's largest area of modern alluvial sedimentation. Flood plain sediments of the Hindon River of the Gangetic plain have been analyzed for sediment texture, major and trace elements including rare earth elements (REEs). The results have been used to characterize the source rock composition and to understand the intensity of chemical weathering, tectonics and their interplay in the Hindon flood plain. The sediments of the Hindon flood plain dominantly consist of sand sized particles with little silt and clay. The geochemistry of the Hindon sediments has been compared to the Siwalik mudstone of the Siwalik Group (Siwaliks). The Siwalik sedimentary rocks like sandstones, mudstones and conglomerates are the known source rocks for the Hindon flood plain sediments. Mudstone geochemistry has been considered best to represent the source rock characteristics. The UCC (Upper Continental Crust) normalized major and trace elements of the Hindon flood plain sediments are very similar to the Siwalik mudstone except for Th and Cr. Furthermore, the average chondrite normalized REE pattern of the Hindon flood plain sediments is similar to the Siwalik mudstone. Textural immaturity, K/Rb ratios and the average CIA (Chemical Index of Alteration) and PIA (Plagioclase Index of Alteration) values of the Hindon flood plain sediments indicate that the sediments have not been affected by chemical weathering. Our study suggests that the active tectonics of the Himalayas and monsoon climate enhances only physical erosion of the source rocks (Siwaliks) rather than the chemical alteration. These factors help the Hindon sediments to retain their parental and tectonic signature even after recycling.

Multiple stages of aqueous alteration along fractures in mudstone and sandstone strata in Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Yen, A. S.; Ming, D. W.; Vaniman, D. T.; Gellert, R.; Blake, D. F.; Morris, R. V.; Morrison, S. M.; Bristow, T. F.; Chipera, S. J.; Edgett, K. S.; Treiman, A. H.; Clark, B. C.; Downs, R. T.; Farmer, J. D.; Grotzinger, J. P.; Rampe, E. B.; Schmidt, M. E.; Sutter, B.; Thompson, L. M.; MSL Science Team

2017-08-01

The Mars rover Curiosity in Gale crater conducted the first-ever direct chemical and mineralogical comparisons of samples that have clear parent (unaltered) and daughter (altered) relationships. The mineralogy and chemistry of samples within and adjacent to alteration halos in a sandstone formation were established by the Chemistry and Mineralogy (CheMin) X-ray diffraction (XRD) instrument and the Alpha Particle X-ray Spectrometer (APXS), respectively. The Stimson formation sandstones unconformably overlie the Murray mudstone formation and represent the youngest stratigraphic unit explored by Curiosity to date. Aqueous alteration of the parent sandstone resulted in a loss of half of the original crystalline mineral phases and a three-fold increase in X-ray amorphous material. Aqueous fluids extensively leached Mg, Al, Mn, Fe, Ni, Zn and other elements from the parent material, decreased the pyroxene to feldspar ratio by a factor of two, introduced Ca and mixed-cation sulfates, and both passively and actively enriched the silica content. Leaching of Mg, Al, Mn, Fe, Ni and Zn and enrichment of Si and S are also observed in alteration halos in the underlying mudstone. These observations are consistent with infiltration of subsurface fluids, initially acidic and then alkaline, propagating along fractures crosscutting the Stimson sandstone and Murray mudstone. The geochemistry and mineralogy suggest a complicated diagenetic history with multiple stages of aqueous alteration under a variety of environmental conditions (e.g. both low and moderate pH). The formation of these alteration halos post-dates lithification of the sandstones and mudstones and represents one of the youngest hydrogeologic events presently known to have occurred in Gale crater.

The Hydrocarbon Fingerprints of Organic-rich Shales

NASA Astrophysics Data System (ADS)

Davies, S. J.; Sommariva, R.; Blake, R.; Ortega, M.; Cuss, R. J.; Harrington, J.; Emmings, J.; Lovell, M.; Monks, P.

2016-12-01

Geological characterization of key source rocks and potential unconventional reservoirs from the UK Mississippian has shed new light on the heterogeneous character of shales (mudstones) and also on the mechanisms for preserving organic matter of different types and abundances. Sedimentological studies of these mudstones suggest that systematic variations in total organic carbon (TOC) content are related to the dominant sediment delivery process (hemipelagic suspension settling vs. sediment gravity flows). Questions remain, however, as to how the physical character and chemical composition (e.g. lithology, mineralogy, organic matter type, maturity and abundance) of a mudstone relates to the volume and type of hydrocarbon gas that could be released. Using novel proof-of-principle laboratory experiments, we demonstrate that it is possible to quantify, in real-time (second by second), methane and a wide range of non-methane hydrocarbons (NMHC) gases as they are released from a crushed mudstone sample. Real time measurements are undertaken using proton-transfer-reaction time-of-flight mass spectrometry (PTR- TOF- MS). The PTR technique is not sensitive to some classes of NHMC and the whole range of hydrocarbons is analyzed using thermal desorption gas chromatography mass spectrometry (TD- GC- MS). Our data indicate that NMHC gases (mostly alkanes and aromatics) are released with temperature and humidity-dependent release rates, which depend on the physio-chemical characteristics of the different hydrocarbons classes and on the mode of storage within the shale. Knowledge of the abundance of methane and the speciated NMHC, and how that relates to geological characteristics of a mudstone is important to understand both the source rock potential and the potential pollutants. Ultimately, we aim to link these results to the geomechanical properties of shales. We discuss the implications of our findings for the environment and for the industrial and commercial exploitation of source rocks and unconventional reservoirs.

In situ radiometric and exposure age dating of the martian surface.

PubMed

Farley, K A; Malespin, C; Mahaffy, P; Grotzinger, J P; Vasconcelos, P M; Milliken, R E; Malin, M; Edgett, K S; Pavlov, A A; Hurowitz, J A; Grant, J A; Miller, H B; Arvidson, R; Beegle, L; Calef, F; Conrad, P G; Dietrich, W E; Eigenbrode, J; Gellert, R; Gupta, S; Hamilton, V; Hassler, D M; Lewis, K W; McLennan, S M; Ming, D; Navarro-González, R; Schwenzer, S P; Steele, A; Stolper, E M; Sumner, D Y; Vaniman, D; Vasavada, A; Williford, K; Wimmer-Schweingruber, R F

2014-01-24

We determined radiogenic and cosmogenic noble gases in a mudstone on the floor of Gale Crater. A K-Ar age of 4.21 ± 0.35 billion years represents a mixture of detrital and authigenic components and confirms the expected antiquity of rocks comprising the crater rim. Cosmic-ray-produced (3)He, (21)Ne, and (36)Ar yield concordant surface exposure ages of 78 ± 30 million years. Surface exposure occurred mainly in the present geomorphic setting rather than during primary erosion and transport. Our observations are consistent with mudstone deposition shortly after the Gale impact or possibly in a later event of rapid erosion and deposition. The mudstone remained buried until recent exposure by wind-driven scarp retreat. Sedimentary rocks exposed by this mechanism may thus offer the best potential for organic biomarker preservation against destruction by cosmic radiation.

In Situ Radiometric and Exposure Age Dating of the Martian Surface

NASA Technical Reports Server (NTRS)

Farley, K. A.; Malespin, C.; Mahaffy, P.; Grotzinger, J. P.; Vasconcelos, P. M.; Milliken, R. E.; Malin, M.; Edgett, K. S.; Pavlov, A. A.; Hurowitz, J. A.;

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale crater, Mars.

PubMed

Ming, D W; Archer, P D; Glavin, D P; Eigenbrode, J L; Franz, H B; Sutter, B; Brunner, A E; Stern, J C; Freissinet, C; McAdam, A C; Mahaffy, P R; Cabane, M; Coll, P; Campbell, J L; Atreya, S K; Niles, P B; Bell, J F; Bish, D L; Brinckerhoff, W B; Buch, A; Conrad, P G; Des Marais, D J; Ehlmann, B L; Fairén, A G; Farley, K; Flesch, G J; Francois, P; Gellert, R; Grant, J A; Grotzinger, J P; Gupta, S; Herkenhoff, K E; Hurowitz, J A; Leshin, L A; Lewis, K W; McLennan, S M; Miller, K E; Moersch, J; Morris, R V; Navarro-González, R; Pavlov, A A; Perrett, G M; Pradler, I; Squyres, S W; Summons, R E; Steele, A; Stolper, E M; Sumner, D Y; Szopa, C; Teinturier, S; Trainer, M G; Treiman, A H; Vaniman, D T; Vasavada, A R; Webster, C R; Wray, J J; Yingst, R A

2014-01-24

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

Origin of Chlorobenzene Detected by the Curiosity Rover in Yellowknife Bay: Evidence for Martian Organics in the Sheepbed Mudstone

NASA Technical Reports Server (NTRS)

Glavin, D.; Freissnet, C.; Eigenbrode, J.; Miller, K.; Martin, M.; Summons, R. E.; Steele, A.; Archer, D.; Brunner, A.; Buch, A.;

Diagenetic Crystal Clusters and Dendrites, Lower Mount Sharp, Gale Crater

NASA Technical Reports Server (NTRS)

Kah, L. C.; Kronyak, R.; Van Beek, J.; Nachon, M.; Mangold, N.; Thompson, L.; Wiens, R.; Grotzinger, J.; Farmer, J.; Minitti, M.;

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale crater, Mars

USGS Publications Warehouse

Ming, D. W.; Archer, P.D.; Glavin, D.P.; Eigenbrode, J.L.; Franz, H.B.; Sutter, B.; Brunner, A.E.; Stern, J.C.; Freissinet, C.; McAdam, A.C.; Mahaffy, P.R.; Cabane, M.; Coll, P.; Campbell, J.L.; Atreya, S.K.; Niles, P.B.; Bell, J.F.; Bish, D.L.; Brinckerhoff, W.B.; Buch, A.; Conrad, P.G.; Des Marais, D.J.; Ehlmann, B.L.; Fairén, A.G.; Farley, K.; Flesch, G.J.; Francois, P.; Gellert, Ralf; Grant, J. A.; Grotzinger, J.P.; Gupta, S.; Herkenhoff, K. E.; Hurowitz, J.A.; Leshin, L.A.; Lewis, K.W.; McLennan, S.M.; Miller, Karl E.; Moersch, J.; Morris, R.V.; Navarro- González, R.; Pavlov, A.A.; Perrett, G.M.; Pradler, I.; Squyres, S. W.; Summons, Roger E.; Steele, A.; Stolper, E.M.; Sumner, D.Y.; Szopa, C.; Teinturier, S.; Trainer, M.G.; Treiman, A.H.; Vaniman, D.T.; Vasavada, A.R.; Webster, C.R.; Wray, J.J.; Yingst, R.A.

2014-01-01

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

The nature of porosity in organic-rich mudstones of the Upper Jurassic Kimmeridge Clay Formation, North Sea, offshore United Kingdom

USGS Publications Warehouse

Fishman, Neil S.; Hackley, Paul C.; Lowers, Heather; Hill, Ronald J.; Egenhoff, Sven O.; Eberl, Dennis D.; Blum, Alex E.

2012-01-01

Analyses of organic-rich mudstones from wells that penetrated the Upper Jurassic Kimmeridge Clay Formation, offshore United Kingdom, were performed to evaluate the nature of both organic and inorganic rock constituents and their relation to porosity in this world-class source rock. The formation is at varying levels of thermal maturity, ranging from immature in the shallowest core samples to mature in the deepest core samples. The intent of this study was to evaluate porosity as a function of both organic macerals and thermal maturity. At least four distinct types of organic macerals were observed in petrographic and SEM analyses and they all were present across the study area. The macerals include, in decreasing abundance: 1) bituminite admixed with clays; 2) elongate lamellar masses (alginite or bituminite) with small quartz, feldspar, and clay entrained within it; 3) terrestrial (vitrinite, fusinite, semifusinite) grains; and 4) Tasmanites microfossils. Although pores in all maceral types were observed on ion-milled surfaces of all samples, the pores (largely nanopores with some micropores) vary as a function of maceral type. Importantly, pores in the macerals do not vary systematically as a function of thermal maturity, insofar as organic pores are of similar size and shape in both the immature and mature Kimmeridge rocks. If any organic pores developed during the generation of hydrocarbons, they were apparently not preserved, possibly because of the highly ductile nature of much of the rock constituents of Kimmeridge mudstones (clays and organic material). Inorganic pores (largely micropores with some nanopores) have been observed in all Kimmeridge mudstones. These pores, particularly interparticle (i.e., between clay platelets), and intraparticle (i.e., in framboidal pyrite, in partially dissolved detrital K-feldspar, and in both detrital and authigenic dolomite) are noteworthy because they compose much of the observable porosity in the shales in both immature and mature samples. The absence of a systematic increase in organic porosity as a function of either maceral type or thermal maturity indicates that such porosity was probably unrelated to hydrocarbon generation. Instead, much of the porosity within mudstones of the Kimmeridge appears to be largely intraparticle and interparticle (adjacent to inorganic constituents), so the petroleum storage potential in these organic-rich mudstones largely resides in inorganic pores.

Facies architecture of basin-margin units in time and space: Lower to Middle Miocene Sivas Basin, Turkey

NASA Astrophysics Data System (ADS)

Çiner, A.; Kosun, E.

2003-04-01

The Miocene Sivas Basin is located within a collision zone, forming one of the largest basins in Central Turkey that developed unconformably on a foundered Paleozoic-Mesozoic basement and Eocene-Oligocene deposits. The time and space relationships of sedimentary environments and depositional evolution of Lower to Middle Miocene rocks exposed between Zara and Hafik towns is studied. A 4 km thick continuous section is subdivided into the Agilkaya and Egribucak Formations. Each formation shows an overall fining upward trend and contains three members. Although a complete section is present at the western part (near Hafik) of the basin, to the east the uppermost two members (near Zara) are absent. The lower members of both formations are composed of fluvial sheet-sandstone and red mudstone that migrate laterally on a flood basin within a semi-arid fan system. In the Agilkaya Formation that crops out near Zara, alluvial fans composed of red-pink volcanic pebbles are also present. The middle members are composed of bedded to massive gypsum and red-green mudstone of a coastal and/or continental sabkha environment. While the massive gypsum beds reach several 10’s of m in Hafik area, near Zara, they are only few m thick and alternate with green mudstones. In Hafik, bedded gypsums are intercalated with lagoonal dolomitic limestone and bituminous shale in the Agilkaya Formation and with fluvial red-pink sandstone-red mudstone in the Egribucak Formation. The upper members are made up of fossiliferous mudstone and discontinuous sandy limestone beds with gutter casts, HCS, and 3-D ripples. They indicate storm-induced sedimentation in a shallow marine setting. The disorganized accumulations of ostreid and cerithiid shells, interpreted as coquina bars, are the products of storm generated reworking processes in brackish environments. Rapid vertical and horizontal facies changes and the facies associations in both formations reflect the locally subsiding nature of this molassic basin.

Gas storage in the Upper Devonian-Lower Mississippian Woodford Shale, Arbuckle Mountains, Oklahoma: how much of a role do the cherts play?

USGS Publications Warehouse

Fishman, Neil S.; Ellis, Geoffrey S.; Paxton, Stanley T.; Abbott, Marvin M.; Boehlke, Adam

2010-01-01

Microfractures also contribute to Woodford Shale porosity but they appear to be lithologically controlled. Fractures are relatively well-developed and are typically perpendicular to bedding in cherts, but these fractures typically end abruptly or become much more diffuse in adjacent mudstones. The brittle nature of the cherts, due to their high quartz content, is most likely the reason for their excellent fracture development, particularly relative to the mudstones, which are composed of much more ductile clay and Tasmanites constituents. Interestingly, the overlap of some petrophysical properties of cherts and mudstones (e.g., porosity, pore apertures) in the Woodford Shale for samples from the Arbuckle Mountains indicates that for shallowly-buried (i.e. minimally compacted) parts of the formation, both lithologies may have exhibited similar behavior relative to fluid movement. Where the Woodford has been more deeply buried and subjected to more intense compaction (i.e. in the Anadarko Basin), the petrophysical characteristics of cherts are likely to have changed only minimally due to their rigid fabric, whereas the petrophysical characteristics of the mudstones are likely to have changed significantly due to compaction and the resultant compression and collapse of ductile constituents such as clays and Tasmanites microfossils (those without quartz infilling). Moldic porosity, which could be expected to develop in kerogen as a consequence of maturation (Loucks and others, 2009), is more likely in the high TOC mudstones, but would also occur in Woodford cherts, which contain lower TOC contents. Owing to the potential for Woodford cherts to better retain porosity, coupled with their contained TOC, cherts may indeed provide important overlooked intervals of gas generation and overall gas storage in the formation. Thus, Woodford cherts may contribute a significant portion of the gas that is produced from the formation. As such, chert beds may play a very significant, heretofore overlooked role as source and reservoir intervals within the Woodford in the Anadarko Basin.

Porosity, petrophysics and permeability of the Whitby Mudstone (UK)

NASA Astrophysics Data System (ADS)

Houben, M.; Barnhoorn, A.; Hardebol, N.; Ifada, M.; Boersma, Q.; Douma, L.; Peach, C. J.; Bertotti, G.; Drury, M. R.

2016-12-01

Typically pore diameters in shales range from the µm down to the nm scale and the effective permeability of shale reservoirs is a function of the interconnectivity between the pore space and the natural fracture network present. The length and spacing of mechanical induced and natural fractures is one of the factors controlling gas produtivity from unconventional reservoirs. Permeability of the Whitby Mudstone measured on 1 inch cores was linked to microstructure and combined with natural fracture spacing present in outcrops along the Yorkshire coast (UK) to get insight into possible fluid pathways from reservoir to well. We used a combination of different techniques to characterize the porosity (gas adsorption, Scanning Electron Microscopy), mineralogy (X-Ray Fluorescence, X-Ray Diffraction, Scanning Electron Microscopy) and permeability (pressure step decay) of the Whitby Mudstone. In addition, we mapped the natural fracture network as present in outcrops along the Yorkshire coast (UK) at the 10-2-101m scale. Mineralogically we are dealing with a rock that is high in clay content and has an average organic matter content of about 10%. Results show a low porosity (max. 7%) as well as low permeability for the Whitby Mudstone. The permeability, measured parallel to bedding, depends on the confining pressure and is 86 nanodarcy at 10 MPa effective confining pressure and decreases to 16 nanodarcy at 40 MPa effective confining pressure. At the scale of observation the average distance to nearest natural fracture is in the order of 0.13 meter and 90 percent of all matrix elements are spaced within 0.4 meter to the nearest fracture. By assuming darcy flow, a permeability of 100 nanodarcy and 10% of overpressure we calculated that for the Whitby mudstone most of the gas resides in the matrix for less than 60 days until it reaches the fracture network.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hurst, J.M.; Lapointe, P.A.; Nyein, U.K.

Three Oligocene-Miocene carbonate depositional morphologies commonly occur: shoals, reefs, and isolated platforms. Lenticular shoals (0-25 m thick, 1 km long) are stacked and intercalated with siliciclastic mudstones. Facies include trough/festoon cross-bedded benthic foram grainstones passing laterally and vertically into red-algal dominated graded-laminated beds, bioturbated silty calcareous mudstone, and siliciclastic sandy foram wackestone and packstone. The morphology and facies are hydrodynamically controlled. Pinnacle reefs (1-2 km[sup 2]) dominated by red-algae, branching corals, and large mollusks occur on structure or aligned within shelf mudstones. The latter location reflects low sedimentation rates and hydrodynamic control. Isolated platforms (up to 150 km[sup 2]) aremore » environmental mosaics of marginal path reefs and shoals, interior lagoons, and islands plus marginal slopes. Facies are similar to shoals and reefs except there are more muddy fabrics and less high-energy facies. They develop on tilted fault blocks or eroded submerged arcs in the offshore Gulf of Martaban, distal to the ancestral Irrawaddy delta.« less

Micro-PIXE characterisation of uranium occurrence in the coal zones and the mudstones of the Springbok Flats Basin, South Africa

NASA Astrophysics Data System (ADS)

Nxumalo, V.; Kramers, J.; Mongwaketsi, N.; Przybyłowicz, W. J.

2017-08-01

Uranium occurrence and characterisation in the coal samples of the upper coal zones of the Vryheid Formation and mudstones of the Volksrust Formation was investigated using micro-PIXE (Proton-Induced X-ray Emission) and proton backscattering spectrometry (BS) in conjunction with the nuclear microprobe. Two styles of uranium mineralisation in the Springbok Flats Basin were found: syngenetic mineralisation in which uranium occurs organically bound with coal matrix, with no discrete uranium minerals formed, and epigenetic mineralisation in which uranium occurs in veins that are filled with coffinite with botryoidal texture in the mudstones of the Volksrust Formation, overlying the coal zones. Micro-PIXE analysis made it possible to map out trace elements (including uranium) associated with the coals at low levels of detection, which other techniques such as SEM-EDS and ore microscopy failed. This information will help in better understanding of the best extraction methods to be employed to recover uranium from the coals of the Springbok Flats Basin.

Stratigraphy and depositional environments of the Lower Mississippian Joana Limestone in southern White Pine and northern Lincoln Counties, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilmore, T.J.

1990-04-01

The Lower Mississippian Joana Limestone in the southern Schell Creek and Egan ranges of east-central Nevada is composed of three depositional facies: the unbedded wackestone with grainstone/packstone facies or Facies 1; the bedded wackestone with mudstone facies or Facies 2; and the restricted wackestone, mudstone/shale facies, or Facies 3. Facies 1 is characterized by Waulsortian-type carbonate buildups with massive unbedded wackestone cores, grainstone flanking beds and grainstone/packstone capping units. Facies 2 is characterized by an upward progression of sedimentary bedding types from thinly laminated to large scale trough cross-bedding that indicates a shoaling upward of this facies. Facies 3 ismore » characterized by sparse wackestones, mudstones, and shale which show a decrease in both faunal types and diversity and an increase in fine clastics. The restricted wackestone, mudstone/shale facies grades upward into the Mississippian Chainman Shale. The age of the Joana Limestone is confirmed as late Kinderhookian to early Osagean based primarily on conodonts and foraminifera. In the middle beds of the Joana Limestone, the previously unreported upper Siphonodella crenulata conodont zone occurs which helps correlate the Joana Limestone with regional transgressive/regressive sea level events. Color alteration indices of these conodonts are 1.5 to 2, and occur in the oil generation window. Additionally, oil staining was observed in numerous samples located primarily in the lower half of the formation, represented by Facies 3, the unbedded wackestone with grainstone/packstone facies.« less

Porosity and pore size distribution in a sedimentary rock: Implications for the distribution of chlorinated solvents

NASA Astrophysics Data System (ADS)

Shapiro, Allen M.; Evans, Christopher E.; Hayes, Erin C.

2017-08-01

Characterizing properties of the rock matrix that control retention and release of chlorinated solvents is essential in evaluating the extent of contamination and the application of remediation technologies in fractured rock. Core samples from seven closely spaced boreholes in a mudstone subject to trichloroethene (TCE) contamination were analyzed using Mercury Intrusion Porosimetry to investigate porosity and pore size distribution as a function of mudstone characteristics, and depth and lateral extent in the aquifer; organic carbon content was also evaluated to identify the potential for adsorption. Porosity and retardation factor varied over two orders of magnitude, with the largest porosities and largest retardation factors associated with carbon-rich mudstone layers. Larger porosities were also measured in the shallow rock that has been subject to enhanced groundwater flow. Porosity also varied over more than an order of magnitude in spatially continuous mudstone layers. The analyses of the rock cores indicated that the largest pore diameters may be accessible to entry of the nonaqueous form of TCE. Although the porosity associated with the largest pore diameters is small ( 0.1%), that volume of TCE can significantly affect the total TCE that is retained in the rock matrix. The dimensions of the largest pore diameters may also be accessible to microbes responsible for reductive dechlorination; however, the small percentage of the pore space that can accommodate microbes may limit the extent of reductive dechlorination in the rock matrix.

Preservation of organic matter on Mars by sulfur

NASA Astrophysics Data System (ADS)

Eigenbrode, J. L.; Steele, A.; Summons, R. E.; McAdam, A.; Sutter, B.; Franz, H. B.; Freissinet, C.; Millan, M.; Glavin, D. P.; Szopa, C.; Conrad, P. G.; Mahaffy, P. R.

2016-12-01

Deltaic-lacustrine mudstones at Pahrump Hills, Gale Crater, Mars yielded a variety of sulfur-containing volatiles upon heating to 500-860°C, as detected by the Sample Analysis at Mars (SAM) instrument onboard the Curiosity rover. The detection of organosulfur compounds comprising thiophenes, dimethylsulfide and thiols by gas chromatography-mass spectrometry and evolved gas analyses, together with aromatic and other hydrocarbon molecules with distributions specific to the sample (i.e., not from the SAM background) indicate that some or all of these organic fragments released at high temperatures are indigenous to the mudstones. The organosulfur compounds are most likely derived from sulfur organics in the sediments. However, there is a possibility that sulfurization of some organic fragments occurred in the oven. On Earth, sulfurization of organic matter is a key process that aids preservation over geological time-scales. This is because it reduces reactive functional groups and adds cross links between small unstable molecules thereby converting them into recalcitrant macromolecules. Sulfurization of organic materials prior to deposition and during early diagenesis may have been a key mechanism responsible for organic matter preservation in the Murray formation mudstones. Sulfur-bearing organics have also been observed in carbonaceous meteorites and there is indication of their presence in the Tissint martian meteorite. A quantitative assessment of organosulfur compounds relative to their non-organic counterparts will be presented for the Murray formation mudstones analyzed by SAM and meteorites analyzed in the laboratory under similar analytical conditions.

Porosity and pore size distribution in a sedimentary rock: Implications for the distribution of chlorinated solvents

USGS Publications Warehouse

Shapiro, Allen M.; Evans, Chrsitopher E.; Hayes, Erin C.

2017-01-01

Characterizing properties of the rock matrix that control retention and release of chlorinated solvents is essential in evaluating the extent of contamination and the application of remediation technologies in fractured rock. Core samples from seven closely spaced boreholes in a mudstone subject to trichloroethene (TCE) contamination were analyzed using Mercury Intrusion Porosimetry to investigate porosity and pore size distribution as a function of mudstone characteristics, and depth and lateral extent in the aquifer; organic carbon content was also evaluated to identify the potential for adsorption. Porosity and retardation factor varied over two orders of magnitude, with the largest porosities and largest retardation factors associated with carbon-rich mudstone layers. Larger porosities were also measured in the shallow rock that has been subject to enhanced groundwater flow. Porosity also varied over more than an order of magnitude in spatially continuous mudstone layers. The analyses of the rock cores indicated that the largest pore diameters may be accessible to entry of the nonaqueous form of TCE. Although the porosity associated with the largest pore diameters is small (~ 0.1%), that volume of TCE can significantly affect the total TCE that is retained in the rock matrix. The dimensions of the largest pore diameters may also be accessible to microbes responsible for reductive dechlorination; however, the small percentage of the pore space that can accommodate microbes may limit the extent of reductive dechlorination in the rock matrix.

Identification of Phyllosilicates in Mudstone Samples Using Water Releases Detected by the Sample Analysis at Mars (SAM) Instrument in Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Hogancamp, J. V. (Clark); Ming, D. W.; McAdam, A. C.; Archer, P. D.; Morris, R. V.; Bristow, T. F.; Rampe, E. B.; Mahaffy, P. R.; Gellert, R.

2017-01-01

The Sample Analysis at Mars (SAM) instrument on board the Curiosity Rover has detected high temperature water releases from mud-stones in the areas of Yellowknife Bay, Pahrump Hills, Naukluft Plateau, and Murray Buttes in Gale crater. Dehydroxylation of phyllosilicates may have caused the high temperature water releases observed in these samples. Because each type of phyllosilicate undergoes dehydroxylation at distinct temperatures, these water releases can be used to help constrain the type of phyllosilicate present in each sample.

Modeling of Sulfide Microenvironments on Mars

NASA Technical Reports Server (NTRS)

Schwenzer, S. P.; Bridges, J. C.; McAdam, A.; Steer, E. D.; Conrad, P. G.; Kelley, S. P.; Wiens, R. C.; Mangold, N.; Grotzinger, J.; Eigenbrode, J. L.;

Mechanical-Stratigraphic Characterization of the Eagle Ford Formation in Outcrop and Core, McMullen and Terrell Counties, Texas

NASA Astrophysics Data System (ADS)

Xu, G.; Chester, J. S.; Chester, F. M.

2017-12-01

The objective of this project is to characterize the geomechanical properties of individual and composite lithologic units over length scales of decimeter to tens of meters. We have characterized the stratigraphy and lithology of the Eagle Ford Formation in outcrops at Lozier and Antonio Canyons of West TX, and in core taken at 3.2 km depth in McMullen County, TX. Dominant lithologies examined include reworked ash layers, argillaceous mudstone, organic-rich mudstone, foraminifera wackestone, packstone, pyritic packstone, and foraminifera/dolomitic packstone-grainstone. Samples of these units are deformed in triaxial compression at 1- 40 MPa confining pressure (Pc), and room temperature and humidity. The elastic properties, pre-fracture yielding (ductility), and fracture strength are primarily a function of particle size, texture (degree of mud versus grain support), and composition. Young's Modulus (YM) and Poison's Ratio (PR) increase similarly with an increase in grain-support and carbonate content, and a decrease in organic matter and clay. The greatest change occurs at the transition from mud-supported to grain-supported textures where YM and PR increase by a factor of 3 and 1.5, respectively. Both YM and PR can display anisotropy with directional variation of 30%, most notably in micro-laminated units, but also in the more massive pyritic packstones. Overall, pre-fracture ductility decreases with an increase in carbonate content; ductile strain in the argillaceous- and organic-rich-mudstones is 1.4%, 3-4 times greater than that in the packstone/grainstone. Fracture strength increases with an increase in carbonate content and a decrease in clay content. The organic rich mudstone fails at 130 MPa, is nearly 2 times stronger than argillaceous mudstones, and 50% weaker than packstone/grainstones at 1 MPa Pc. The angle of internal friction is 45 degrees for all lithologies, consistent with a transition in fracture from opening- to shear-mode between 1 to 15 MPa Pc. These data indicate that the Eagle Ford Formation is mechanically anisotropic at all length scales, and although elastic and inelastic properties correlate overall, significant variations between properties reflect differences in dependence on composition and texture.

Initial characterization of mudstone nanoporosity with small angle neutron scattering using caprocks from carbon sequestration sites.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCray, John; Navarre-Sitchler, Alexis; Mouzakis, Katherine

Geological carbon sequestration relies on the principle that CO{sub 2} injected deep into the subsurface is unable to leak to the atmosphere. Structural trapping by a relatively impermeable caprock (often mudstone such as a shale) is the main trapping mechanism that is currently relied on for the first hundreds of years. Many of the pores of the caprock are of micrometer to nanometer scale. However, the distribution, geometry and volume of porosity at these scales are poorly characterized. Differences in pore shape and size can cause variation in capillary properties and fluid transport resulting in fluid pathways with different capillarymore » entry pressures in the same sample. Prediction of pore network properties for distinct geologic environments would result in significant advancement in our ability to model subsurface fluid flow. Specifically, prediction of fluid flow through caprocks of geologic CO{sub 2} sequestration reservoirs is a critical step in evaluating the risk of leakage to overlying aquifers. The micro- and nanoporosity was analyzed in four mudstones using small angle neutron scattering (SANS). These mudstones are caprocks of formations that are currently under study or being used for carbon sequestration projects and include the Marine Tuscaloosa Group, the Lower Tuscaloosa Group, the upper and lower shale members of the Kirtland Formation, and the Pennsylvanian Gothic shale. Total organic carbon varies from <0.3% to 4% by weight. Expandable clay contents range from 10% to {approx}40% in the Gothic shale and Kirtland Formation, respectively. Neutrons effectively scatter from interfaces between materials with differing scattering length density (i.e. minerals and pores). The intensity of scattered neutrons, I(Q), where Q is the scattering vector, gives information about the volume of pores and their arrangement in the sample. The slope of the scattering data when plotted as log I(Q) vs. log Q provides information about the fractality or geometry of the pore network. Results from this study, combined with high-resolution TEM imaging, provide insight into the differences in volume and geometry of porosity between these various mudstones.« less

Natural fault and fracture network versus anisotropy in the Lower Paleozoic rocks of Pomerania (Poland)

NASA Astrophysics Data System (ADS)

Haluch, Anna; Rybak-Ostrowska, Barbara; Konon, Andrzej

2017-04-01

Knowledge of the anisotropy of rock fabric, geometry and distribution of the natural fault and fracture network play a crucial role in the exploration for unconventional hydrocarbon recourses. Lower Paleozoic rocks from Pomerania within the Polish part of Peri-Baltic Basin, as prospective sequences, can be considered a laboratory for analysis of fault and fracture arrangement in relation to the mineral composition of the host rocks. A microstructural study of core samples from five boreholes in Pomerania indicate that the Silurian succession in the study area is predominantly composed of claystones and mudstones interbedded with thin layers of tuffites. Intervals with a high content of detrital quartz or diagenetic silica also occur. Most of the Silurian deposits are abundant in pyrite framboids forming layers or isolated small concretions. Early diagenetic carbonate concretions are also present. The direction and distribution of natural faults and fractures have resulted not only from paleostress. Preliminary study reveals that the fault and fracture arrangement is related to the mechanical properties of the host rocks that depend on their fabric and mineralogical composition: subvertical fractures in mudstones and limestones show steeper dips than those within the more clayey intervals; bedding-parallel fractures occur within organic-rich claystones and along the boundaries between different lithologies; tuffites and radiolaria-bearing siliceous mudstones are more brittle and show denser nets of fractures or wider mineral apertures; and, fracture refraction is observed at competence contrast or around spherical concretions. The fault and fracture mineralization itself is prone to the heterogenity of the rock profile. Thus, fractures infilled with calcite occur in all types of the studied rocks, but mineral growth is syntaxial within marly mudstones because of chemical uniformity, and antitaxial within sillicous mudstones. Fractures infilled with quartz are restricted to tuffites and claystones with biogenic silica. Matching the complex microstructural and mineralogical data with the geomechanical analysis of the host rocks will be the base for further studies on induced fault and fracture development. The study was supported by grant no.: 13-03-00-501-90-472946, funded by the National Centre for Research and Development (NCBiR)

Rill erosion of mudstone slope-a case study of southern Taiwan

NASA Astrophysics Data System (ADS)

Yang, Ci-Jian; Lin, Jiun-chuan; Cheng, Yuan-Chang

2014-05-01

Soil erosion has been studied by many scientists for decades (Zingg, 1940; Meyer & Wischmeier, 1969; Foster, 1982; Luk, 1988) and many soil erosion prediction equations have already been developed, such as USLE, RUSLE. In spite of WEEP is based on hydrological physical model, all of the above models are restricted to predict concentrate flow. On the other hand, rill erosion is not understood completely. The amounts of rill erosion are always underestimated. Rill Erosion correlate closely to gradient (Cerda & Garcia-Fayos, 1997; Fox & Bryan, 1999; Fu,et al., 2011; Clarke & Rendell, 2006), slope length (Gabriel, 1999; Yair, 2004), particle distribution (Gabriel, 1999), proportion of clay (Luk,1977; Bryan2000), rainfall intensity (Römkens et al. 2001), and land use (Dotterweich, 2008). However, the effect of micromorphology of mud rock surface, such as mud-cracks, could be studied in more details. This research aims to simulate rill development by hydraulic flume to observe the morphological change caused by rill/erosion process. Mudstone specimens sampled from the mudstone area of Long-Chi, southern Taiwan. The results show that: (1) The erosion pattern of mudstone slope can be divided into four steps: (a) inter-rill erosion, ( b) rill erosion, (c) rill development, (d) slope failure. (2) Slopes with mud-cracks caused 125% soil loss than smooth slopes. (3) Mud-cracks affect spatial distribution of rill development (4) The sediment concentration decreased sharply in the beginning of experiments, however increased due to rill development. This paper demonstrated such a rill development. 1: Department of Geography, National Taiwan University. E-mail:maxpossibilism0929@gmail.com

Martian Chlorobenzene Identified by Curiosity in Yellowknife Bay: Evidence for the Preservation of Organics in a Mudstone on Mars

NASA Technical Reports Server (NTRS)

Glavin, D.; Freissinet, C.; Mahaffy, P.; Miller, K.; Eigenbrode, J.; Summons, R.; Martin, M.; Franz, H.; Steele, A.; Archer, D.;

Palaeogeography of Late Triassic red-beds in Singapore and the Indosinian Orogeny

NASA Astrophysics Data System (ADS)

Oliver, Grahame; Prave, Anthony

2013-10-01

A red-bed facies of the Upper Triassic Jurong Formation has been logged on Sentosa Island, Singapore. An overall coarsening and thickening-upward pattern is well developed. The lower part of the section is dominated by purple-red, massive to finely laminated illite-smectite-kaolin-rich mudstones containing thin, discontinuous lenses of fine sandstone marked by low-angle lamination and small ripples. One dinosaur-like foot print has been discovered in a loose block of red mudstone. It is concluded that this is a lacustrine sequence and it is proposed to name the lake, Lake Sentosa. The upper part of the sequence consists of flat-laminated to trough cross-bedded medium-grained sandstone and granule to cobble conglomerates alternating with purple-red mudstone. The mudstone-sandstone packages are arranged in decametre-scale coarsening-upward cycles. The channelling and decimetre-scale cross-bedding characterising the sandstone and conglomeratic beds is evidence for deposition by flashy fluvial flood processes, possibly feeding into the lake as a fresh water delta. One possible dinosaur trackway in granule size conglomerate has been located. Detrital zircon U-Pb ages vary from 2.7 Ba to 209 Ma with significant populations at ˜245 Ma and 220 Ma. These ages throw light on the timing of the Indosinian Orogeny. The molasse red-beds of the Jurong Formation were deposited in a half graben formed in the hangingwall of the Bukit Timah Fault when central Peninsular Malaysia went into extension following the climax of the Indosinian Orogeny in the Late Triassic.

Various causes behind the desorption hysteresis of carboxylic acids on mudstones.

PubMed

Rasamimanana, S; Lefèvre, G; Dagnelie, R V H

2017-02-01

Adsorption desorption is a key factor for leaching, migration and (bio)degradation of organic pollutants in soils and sediments. Desorption hysteresis of apolar organic compounds is known to be correlated with adsorption/diffusion into soil organic matter. This work focuses on the desorption hysteresis of polar organic compounds on a natural mudstone sample. Acetic, citric and ortho-phthalic acids displayed adsorption-desorption hysteresis on Callovo-Oxfordian mudstone. The non-reversible behaviours resulted from three different mechanisms. Adsorption and desorption kinetics were evaluated using 14C- and 3H-labelled tracers and an isotopic exchange method. The solid-liquid distribution ratio of acetate decreased using a NaN 3 bactericide, indicating a rapid bacterial consumption compared with negligible adsorption. The desorption hysteresis of phthalate was apparent and suppressed by the equilibration of renewal pore water with mudstone. This confirms the significant and reversible adsorption of phthalate. Finally, persistent desorption hysteresis was evidenced for citrate. In this case, a third mechanism should be considered, such as the incorporation of citrate in the solid or a chemical perturbation, leading to strong desorption resilience. The results highlighted the different pathways that polar organic pollutants might encounter in a similar environment. Data on phthalic acid is useful to predict the retarded transport of phthalate esters and amines degradation products in sediments. The behaviour of citric acid is representative of polydentate chelating agents used in ore and remediation industries. The impact of irreversible adsorption on solid/solution partitioning and transport deserves further investigation. Copyright © 2016 Elsevier Ltd. All rights reserved.

Geological setting of oil shales in the Permian phosphoria formation and some of the geochemistry of these rocks

USGS Publications Warehouse

Maughan, E.K.

1983-01-01

Recent studies of the Meade Peak and the Retort Phosphatic Shale Members of the Phosphoria Formation have investigated the organic carbon content and some aspects of hydrocarbon generation from these rocks. Phosphorite has been mined from the Retort and Meade Peak members in southeastern Idaho, northern Utah, western Wyoming and southwestern Montana. Organic carbon-rich mudstone beds associated with the phosphorite in these two members also were natural sources of petroleum. These mudstone beds were differentially buried throughout the region so that heating of these rocks has been different from place to place. Most of the Phosphoria source beds have been deeply buried and naturally heated to catagenetically form hydrocarbons. Deepest burial was in eastern Idaho and throughout most of the northeastern Great Basin where high ambient temperatures have driven the catagenesis to its limit and beyond to degrade or to destroy the hydrocarbons. In southwest Montana, however, burial in some areas has been less than 2 km, ambient temperatures remained low and the kerogen has not produced hydrocarbons (2). In these areas in Montana, the kerogen in the carbonaceous mudstone has retained the potential for hydrocarbon generation and the carbon-rich Retort Member is an oil shale from which hydrocarbons can be synthetically extracted. The Phosphoria Formation was deposited in a foreland basin between the Cordilleran geosyncline and the North American craton. This foreland basin, which coincides with the area of deposition of the two organic carbon-rich mudstone members of the Phosphoria, has been named the Sublett basin (Maughan, 1979). The basin has a northwest-southeast trending axis and seems to have been deepest in central Idaho where deep-water sedimentary rocks equivalent to the Phosphoria Formation are exceptionally thick. The depth of the basin was increasingly shallower away from central Idaho toward the Milk River uplift - a land area in Montana, the ancestral Rocky Mountains. The basin is composed of land areas in Colorado, the Humboldt highland in northeastern Nevada and intervening carbonate shelves in Utah and Wyoming. The phosphorites and the carbonaceous mudstones were deposited on the foreslope between the carbonate and littoral sand deposits on the shelf and the dominantly cherty mudstone sediments in the axial part of the basin. Paleomagnetic evidence indicates that in the Permian the region would have been within the northern hemispheric trade wind belt; and wind-direction studies determined from studies of sand dunes, indicate that the prevailing winds from the Milk River uplift would have blown offshore across the Phosphoria sea. Offshore winds would have carried surface water away from the shore and generated upwelling in the sea in eastern Idaho and adjacent areas in Montana, Wyoming and Utah. Prior to deposition of the Phosphoria, the region was the site of extensive deposition of shallow-water carbonate sediments. Equivalent rocks in the northern part of the basin are dominantly sandstone derived from the adjacent Milk River uplift and similar sandstone strata in the southeastern sector were derived from the ancestral Rocky Mountains uplift. Tectonic subsidence of the Sublett basin in part of the region seems to have provided a sea-floor profile favorable for upwelling circulation and the shift in deposition from regional carbonates and local sandstone into a more complex depositional pattern that included the accumulation of the mudstone-chert-phosphorite facies that comprises the Phosphoria Formation. High biological productivity and the accumulation of sapropel on the sea floor is associated with contemporary coastal upwelling (1) and similar environmental and depositional conditions are attributed to the rich accumulations of organic matter in the Phosphoria Formation. Sapropelic mudstone and phosphorite composing the Meade Peak Member are approximately 60 m thick near the center of the Sublett basin. The Meade

Attributes and origins of ancient submarine slides and filled embayments: examples from the Gulf Coast basin

USGS Publications Warehouse

Morton, Robert

1993-01-01

Submarine slides exhibit landward-dipping, wavy, mounded, and chaotic seismic reflections that are manifestations of slump blocks and other mass transport material. Composition of these internally derived slide deposits depends on the composition of the preexisting shelf margin. Embayment fill above the slide consists mostly of externally derived mudstones and sandstones deposited by various disorganized slope processes, as well as more organized submarine channel-levee systems. Thickest slope sandstones, which are potential hydrocarbon reservoirs, commonly occur above the basal slide mudstones where seismic reflections change from chaotic patterns to overlying wavy or subhorizontal reflections.

Arctic Alaska’s Lower Cretaceous (Hauterivian and Barremian) mudstone succession - Linking lithofacies, texture, and geochemistry to marine processes: Chapter B in Studies by the U.S. Geological Survey in Alaska, vol. 15

USGS Publications Warehouse

Keller, Margaret A.; Macquaker, Joe H.S.

2015-01-01

Our results document the variation in facies and textures of the Hauterivian and Barremian Lower Cretaceous mudstone succession of Arctic Alaska. Comparison of these characteristics to the products of modern processes on the North Slope of Alaska, in the Beaufort Sea, and elsewhere suggest that this succession formed primarily from depositional processes related to seasonal sea ice with intermittent fluvial-sourced sediment deposited by density currents and episodic erosion and reworking by storms and other currents.

The Mineralogical and Chemical Case for Habitability at Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Blake, David Frederick; Vaniman, David; Grotzinger, John P.; Conrad, Pamela Gales; Ming, Douglas W.; Bish, David L.; Farmer, Jack D.; Bristow, Thomas

2013-01-01

Sediments of the Yellowknife Bay formation (Gale crater) include the Sheepbed member, a mudstone cut by light-toned veins. Two drill samples, John Klein and Cumberland, were collected and analyzed by the CheMin XRD/XRF instrument and the Sample Analysis at Mars (SAM) evolved gas and isotopic analysis suite of instruments. Drill cuttings were also analyzed by the Alpha Particle X-ray Spectrometer (APXS) for bulk composition. The CheMin XRD analysis shows that the mudstone contains basaltic minerals (Fe-forsterite, augite, pigeonite, plagioclase), as well as Fe-oxide/hydroxides, Fe-sulfides, amorphous materials, and trioctahedral phyllosilicates. SAM evolved gas analysis of higher-temperature OH matches the CheMin XRD estimate of 20% clay minerals in the mudstone. The light-toned veins contain Ca-sulfates; anhydrite and bassanite are detected by XRD but gypsum is also indicated from Mastcam spectral mapping. These sulfates appear to be almost entirely restricted to late-diagenetic veins. The sulfate content of the mudstone matrix itself is lower than other sediments analyzed on Mars. The presence of phyllosilicates indicates that the activity of water was high during their formation and/or transport and deposition (should they have been detrital). Lack of chlorite places limits on the maximum temperature of alteration (likely <100 C). The presence of Ca-sulfates rather than Mg- or Fe-sulfates suggests that the pore water pH was near-neutral and of relatively low ionic strength (although x-ray amorphous Mg-and Fe- sulfates could be present and undetectable by CheMin). The presence of Fe and S in both reduced and oxidized states represents chemical disequilibria that could have been utilized by chemolithoautotrophic biota, if present. When compared to the nearby Rocknest sand shadow mineralogy or the normative mineralogy of Martian soil, both John Klein and Cumberland exhibit a near-absence of olivine and a surplus of magnetite (7-9% of the crystalline component). The magnetite is interpreted as an authigenic product formed when olivine was altered to phyllosilicate. Saponitization of olivine (a process analogous to serpentinization) could have produced H2 in situ. Indeed, early diagenetic hollow nodules ("minibowls") present in the Cumberland mudstone are interpreted by some as forming when gas bubbles accumulated in the unconsolidated mudstone. Lastly, all of these early diagenetic features appear to have been preserved with minimal alteration since their formation, as indicated by the ease of drilling (weak lithification, lack of cementing phases), the presence of 20-30% amorphous material, and the late-stage fracturing with emplacement of calcium sulfate veins and minibowl infills, where they were intersected by veins. A rough estimate of the minimum duration of the lacustrine environment is provided by the minimum thickness of the Sheepbed member. Given 1.5 meters, and applying a mean sediment accumulation rate for lacustrine strata of 1 m/1000 yrs yields a duration of 1,500 years. If the aqueous environments represented by overlying strata are considered, such as Gillespie Lake and Shaler, then this duration increases. The Sheepbed mudstone meets all the requirements of a habitable environment: Aqueous deposition at clement conditions of P, T, pH, Eh and ionic strength, plus the availability of sources of chemical energy.

Micropillar Compression Technique Applied to Micron-Scale Mudstone Elasto-Plastic Deformation

NASA Astrophysics Data System (ADS)

Dewers, T. A.; Boyce, B.; Buchheit, T.; Heath, J. E.; Chidsey, T.; Michael, J.

2010-12-01

Mudstone mechanical testing is often limited by poor core recovery and sample size, preservation and preparation issues, which can lead to sampling bias, damage, and time-dependent effects. A micropillar compression technique, originally developed by Uchic et al. 2004, here is applied to elasto-plastic deformation of small volumes of mudstone, in the range of cubic microns. This study examines behavior of the Gothic shale, the basal unit of the Ismay zone of the Pennsylvanian Paradox Formation and potential shale gas play in southeastern Utah, USA. Precision manufacture of micropillars 5 microns in diameter and 10 microns in length are prepared using an ion-milling method. Characterization of samples is carried out using: dual focused ion - scanning electron beam imaging of nano-scaled pores and distribution of matrix clay and quartz, as well as pore-filling organics; laser scanning confocal (LSCM) 3D imaging of natural fractures; and gas permeability, among other techniques. Compression testing of micropillars under load control is performed using two different nanoindenter techniques. Deformation of 0.5 cm in diameter by 1 cm in length cores is carried out and visualized by a microscope loading stage and laser scanning confocal microscopy. Axisymmetric multistage compression testing and multi-stress path testing is carried out using 2.54 cm plugs. Discussion of results addresses size of representative elementary volumes applicable to continuum-scale mudstone deformation, anisotropy, and size-scale plasticity effects. Other issues include fabrication-induced damage, alignment, and influence of substrate. This work is funded by the US Department of Energy, Office of Basic Energy Sciences. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.

Geology of the Carnegie museum dinosaur quarry site of Diplodocus carnegii, Sheep Creek, Wyoming

USGS Publications Warehouse

Brezinski, D.K.; Kollar, A.D.

2008-01-01

The holotype of Diplodocus carnegii Hatcher, 1901, consists of a partial skeleton (CM 84) that was recovered, along with a second partial skeleton of the same species (CM 94), from the upper 10 m of the Talking Rock facies of the Brushy Basin Member of the Morrison Formation exposed along Bone Quarry Draw, a tributary of Sheep Creek in Albany County, Wyoming. A composite measured section of the stratigraphic interval exposed adjacent to the quarry indicates that the Brushy Basin Member in this area is a stacked succession of lithofacies consisting of hackly, greenish gray, calcareous mudstone and greenish brown, dense, fine-grained limestone. The more erosion resistant limestone layers can be traced over many hundreds of meters. Thus, these strata do not appear to represent a highly localized deposit such as a stream channel, oxbow lake, or backwater pond. The Sheep Creek succession is interpreted as representing a clastic-dominated lake where high turbidity and sediment influx produced deposition of calcareous mudstone. During drier periods the lake's turbidity decreased and limestone and dolomite precipitation replaced mud deposition. Microkarsting at the top of some limestone/ dolomite layers suggests subaerial deposition may have prevailed during these dry episodes. The quarry of D. carnegii was excavated within the top strata of one of the numerous intervals of hackly, greenish gray, calcareous mudstone that represent an ephemeral freshwater lake. The quarry strata are directly overlain by 0.3 m of dolomite-capped limestone that was deposited shortly after interment of D. carnegii in the lake mudstones. The close vertical proximity of the overlying limestone to the skeleton's stratigraphic: level suggests that the animal's carcass may have been buried beneath the drying lake deposits during a period of decreased rainfall.

Diagenetic Crystal Growth in the Murray Formation, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Kah, L. C.; Kronyak, R. E.; Ming, D. W.; Grotzinger, J. P.; Schieber, J.; Sumner, D. Y.; Edgett, K. S.

2015-01-01

The Pahrump region (Gale Crater, Mars) marks a critical transition between sedimentary environments dominated by alluvial-to-fluvial materials associated with the Gale crater rim, and depositional environments fundamentally linked to the crater's central mound, Mount Sharp. At Pahrump, the Murray formation consists of an approximately 14-meter thick succession dominated by massive to finely laminated mudstone with occasional interbeds of cross-bedded sandstone, and is best interpreted as a dominantly lacustrine environment containing tongues of prograding fluvial material. Murray formation mudstones contain abundant evidence for early diagenetic mineral precipitation and its subsequent removal by later diagenetic processes. Lenticular mineral growth is particularly common within lacustrine mudstone deposits at the Pahrump locality. High-resolution MAHLI images taken by the Curiosity rover permit detailed morphological and spatial analysis of these features. Millimeter-scale lenticular features occur in massive to well-laminated mudstone lithologies and are interpreted as pseudomorphs after calcium sulfate. The distribution and orientation of lenticular features suggests deposition at or near the sediment-water (or sediment-air) interface. Retention of chemical signals similar to host rock suggests that original precipitation was likely poikilotopic, incorporating substantial amounts of the primary matrix. Although poikilotopic crystal growth is common in burial environments, it also occurs during early diagenetic crystal growth within unlithified sediment where high rates of crystal growth are common. Loss of original calcium sulfate mineralogy suggests dissolution by mildly acidic, later-diagenetic fluids. As with lenticular voids observed at Meridiani by the Opportunity Rover, these features indicate that calcium sulfate deposition may have been widespread on early Mars; dissolution of depositional and early diagenetic minerals is a likely source for both calcium and sulfate ion-enrichment in burial fluids that precipitated in ubiquitous late-stage hydrofracture veins

High resolution study of petroleum source rock variation, Lower Cretaceous (Hauterivian and Barremian) of Mikkelsen Bay, North Slope, Alaska

USGS Publications Warehouse

Keller, Margaret A.; Macquaker, Joe H.S.; Lillis, Paul G.

2001-01-01

Open File Report 01-480 was designed as a large format poster for the Annual Meeting of the American Association of Petroleum Geologists and the Society for Sedimentary Geology in Denver Colorado in June 2001. It is reproduced here in digital format to make widely available some unique images of mudstones. The images include description, interpretation, and Rock-Eval data that resulted from a high-resolution study of petroleum source rock variation of the Lower Cretaceous succession of the Mobil-Phillips Mikkelsen Bay State #1 well on the North Slope of Alaska. Our mudstone samples with Rock-Eval data plus color images are significant because they come from one of the few continuously cored and complete intervals of the Lower Cretaceous succession on the North Slope. This succession, which is rarely preserved in outcrop and very rarely cored in the subsurface, is considered to include important petroleum source rocks that have not previously been described nor explained Another reason these images are unique is that the lithofacies variability within mudstone dominated successions is relatively poorly known in comparison with that observed in coarser clastic and carbonate successions. They are also among the first published scans of thin sections of mudstone, and are of excellent quality because the sections are well made, cut perpendicular to bedding, and unusually thin, 20 microns. For each of 15 samples, we show a thin section scan (cm scale) and an optical photomicrograph (mm scale) that illustrates the variability present. Several backscattered SEM images are also shown. Rock-Eval data for the samples can be compared with the textures and mineralogy present by correlating sample numbers and core depth.

Lithofacies variation across the Mammoth Cave-Pope Megagroup boundary -- a sequence stratigraphic approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

McDonald, T.A.; Tabor, E.; Marzolf, J.E.

1994-04-01

Regional stratigraphic relations in southern Illinois suggest a major unconformity near the top of the St. Genevieve Limestone. Large exposures below the unconformity within the Anna quarries display a retrogradational parasequence-stacking pattern. Eight to 12 m-thick parasequences comprise thinning-upward marine bioclastic wackestone overlain by oolitic and bioclastic thickening-upward eolian( ) grainstone. An eolian origin for the bioclastic grainstones is supported by large scale cross stratification (0.5 to 2 m-thick sets), reworked character of rounded, coated bioclasts, and preserved duneforms. At the quarries, the unconformity is directly overlain by mudstones and sandstones. Thinning-upward mudstones interbedded with very thin (1 to 3more » cm thick) intraclastic packstone tempestites crop out in a roadcut about 500 m NE of the quarries. Small-scale ripples and absence of trace fossils in lower mudstone units suggest an estuarine or lagoonal, brackish-waver environment. The trace fossil Conostichus and horizontal burrows appear abruptly in the upper, thin mudstone units. Highly bioturbated green and red shales overlying a 1 to 4 m-thick covered interval in a roadcut 610 m farther north are interbedded with tidally deposited, medium- to coarse-grained, bioclastic grainstones. The shale-draped, medium cross-bedded grainstones document ten or more tidal bundles. The cross-bedded grainstone is overlain by wavy- to flaser-bedded very fine-grained sandstone suggestive of sand flat origin. These sandstones are overlain by the Aux Vases Sandstone. Numerous low-angle bounding surfaces within the Aux Vases enclose low-angle, wedge-planar cross-bedding. A single irregular surface coated by a few centimeters of poorly sorted unstratified sandstone defines a ravinement surface near the base of the Aux Vases Sandstone.« less

Facies heterogeneity, pay continuity, and infill potential in barrier-island, fluvial, and submarine fan reservoirs: examples from the Texas Gulf Coast and Midland basins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ambrose, W.A.; Tyler, N.

1989-03-01

Three reservoirs representing different depositional environments - barrier island (West Ranch field, south-central Texas), fluvial (La Gloria field, south Texas), and submarine fan (Spraberry trend, Midland basin) - illustrate variations in reservoir continuity. Pay continuity methods based on facies geometry and variations in permeability and thickness between wells can quantify reservoir heterogeneity in each of these examples. Although barrier-island reservoirs are relatively homogeneous, West Ranch field contains wide (1000-5000 ft or 300-1500 m) dip-parallel belts of lenticular inlet-fill facies that disrupt reservoir continuity in the main barrier-core facies. Other reservoir compartments in West Ranch field are in flood-tidal delta depositsmore » partly encased in lagoonal mudstones updip of the barrier core. Fluvial reservoirs have a higher degree of internal complexity than barrier-island reservoirs. In La Gloria field, reservoirs exhibit significant heterogeneity in the form of numerous sandstone stringers bounded vertically and laterally by thin mudstone layers. Successful infill wells in La Gloria field contact partly drained reservoir compartments in splay deposits that pinch out laterally into flood-plain mudstones. Recompletions in vertically isolated sandstone stringers in La Gloria field contact other reservoir compartments. Submarine fan deposits are extremely heterogeneous and may have the greatest potential for infill drilling to tap isolated compartments in clastic reservoirs. The Spraberry trend contains thin discontinuous reservoir sandstones deposited in complex mid-fan channels. Although facies relationships in Spraberry reservoirs are similar to those in fluvial reservoirs in La Gloria field, individual pay stringers are thinner and more completely encased in low-permeability mudstone facies.« less

Origin of Chlorobenzene Detected by the Curiosity Rover in Yellowknife Bay: Evidence for Martian Organics in the Sheepbed Mudstone?

NASA Technical Reports Server (NTRS)

Glavin, Daniel P.; Freissinet, Caroline; Eigenbrode, J.; Miller, K.; Martin, M.; Summons, R.; Steele, A.; Franz, H.; Archer, D.; Brinkerhoff, W.;

The Amorphous Composition of Three Mudstone Samples from Gale Crater: Implications for Weathering and Diagenetic Processes on Mars

NASA Technical Reports Server (NTRS)

Achilles, C. N.; Downs, R. T.; Rampe, E. B.; Morris, R. V.; Bristow, T. F.; Ming, D. W.; Blake, D. F.; Vaniman, D. T.; Morrison, S. M.; Sutter, B.;

Sedimentary structures and stratal geometries at the foothills of Mount Sharp: their role in paleoenvironmental interpretation

NASA Astrophysics Data System (ADS)

Gupta, S.; Rubin, D. M.; Sumner, D. Y.; Grotzinger, J. P.; Lewis, K. W.; Stack, K.; Kah, L. C.; Banham, S.; Edgett, K. S.

2015-12-01

The Mars Science Laboratory Curiosity rover has been exploring sedimentary rocks at the foothills of Mount Sharp since August 2014. Robust interpretation of the paleoenvironmental contexts requires detailed facies analysis of these rocks including analysis and interpretation of sedimentary structures and sediment body geometries. Here, we describe some of the detailed sedimentary structures and sedimentary geometries observed by Curiosity between the Pahrump_Hills field site and its current location at Marias Pass. The Pahrump Hills sedimentary section comprises a succession dominated by finely laminated mudstones of the Murray formation that are interpreted to have been deposited in an ancient lake within Gale crater. Toward the top of the Pahump Hills succession, we observe the appearance of coarser-grained sandstones that are interstratified within the lacustrine mudstones. These sandstones that include Whale Rock and Newspaper Rock show lenticular geometries, and are pervasively cross-stratified. These features indicate that currents eroded shallow scours in the lake beds that were then infilled by deposition from migrating subaqueous dunes. The paleoenvironmental setting may represent either a gullied delta front setting or one in which lake level fall caused fluvial erosion and infilling of the shallow scours. Since leaving Pahrump_Hills, Curiosity has imaged extensive exposures of strata that are partly correlative with and stratigraphically overlie the uppermost part of the Pahrump section. Isolated cross-bedded sandstones and possible interstratified conglomerates beds occur within Murray formation mudstones. Capping sandstones with a likely variety of environmental contexts overlie mudstones. Where imaged in detail, sedimentary structures, such as trough-cross bedding and possible eolian pinstriping, provide constraints on plausible sedimentary processes and bounds on depositional setting.

An improved evaluation method for measuring TOC of the Longmaxi Formation shale in the Sichuan Basin, south China

NASA Astrophysics Data System (ADS)

Zhang, Y.; Hu, C.; Wang, M.

2017-12-01

The evaluation of total organic carbon (TOC) in shale using logging data is one of the most crucial steps in shale gas exploration. However, it didn't achieve the ideal effect for the application of `ΔlogR' method in the Longmaxi Formation shale of Sichuan Basin.The reason may be the organic matter carbonization in Longmaxi Formation. An improved evaluation method, using the classification by lithology and sedimentary structure: 1) silty mudstone (wellsite logging data show silty); 2) calcareous mudstone (calcareous content > 25%); 3) laminated mudstone (laminations are recognized by core and imaging logging technology); 4) massive mudstone (massive textures are recognized by core and imaging logging technology, was proposed. This study compares two logging evaluation methods for measuring TOC in shale: the △logR method and the new proposed method. The results showed that the correlation coefficient between the calculated TOC and the tested TOC, based on the △logR method, was only 0.17. The correlation coefficient obtained according to the new method reached 0.80. The calculation results illustrated that, because of the good correlation between lithologies and sedimentary structure zones and TOC of different types of shale, the shale reservoirs could be graded according to four shale types. The new proposed method is more efficient, faster, and has higher vertical resolution than the △logR method. In addition, a new software had been completed. It was found to be especially effective under conditions of insufficient data during the early stages of shale gas exploration in the Silurian Longmaxi Formation, Muai Syncline Belt, south of the Sichuan Basin.

Investigation of quartz diagenesis in mudstones of the Spraberry and Wolfcamp Formations

NASA Astrophysics Data System (ADS)

Eakin, A.; Reece, J. S.

2016-12-01

Here we present preliminary core analysis of the diagenetic variability existing within a siliceous mudstone facies of the Permian Spraberry and Wolfcamp Formations in the Midland Basin, Texas. Within this mudstone facies, the carbonate content varies from absent in several Wolfcamp Formation samples to >40 wt. % in the Spraberry Formation. A normalized ratio of quartz to clay content with carbonate removed reveals a systematic decrease in quartz content with increasing clay content. This relationship is typical of rocks with variable amounts of detrital quartz content. However, in this siliceous mudstone facies, the abundance of detrital quartz silt grains does not vary widely. Additionally, for the same clay content, the Wolfcamp Formation shows a higher concentration of quartz than the Spraberry Formation. Scanning electron microscopy (SEM) reveals the presence of microcrystalline quartz cement that likely accounts for the increased quartz content in the Wolfcamp Formation. This research tests the hypothesis that the increased quartz cement in the Wolfcamp Formation may occur at the expense of the carbonate cement present in the overlying Spraberry Formation. Furthermore, the deviation in quartz content for the same clay concentration only occurs once the ratio of quartz to clay content increases beyond 1.2. This ratio may represent a threshold of detrital quartz in the clay matrix required to have enough porosity and nucleation surface area for authigenic quartz growth. The presence of matrix cement may impact the mechanical properties to favor fracturing and cataclasis over more ductile deformation. This would enhance development of secondary porosity, while also increasing permeability through the connection of primary pores. Acquiring a fundamental understanding of diagenesis in the Spraberry and Wolfcamp Formations will aid in better prediction of mechanical behavior during drilling and optimized resource recovery.

Mars Organic Matter Revealed by the Detection of Organo-chlorinated Molecules from Pyro-GCMS Analyses of Yellowknife Bay Mudstone

NASA Astrophysics Data System (ADS)

Szopa, C.; Freissinet, C.; Glavin, D. P.; Buch, A.; Coll, P. J.; Cabane, M.; Millan, M.; Belmahadi, I.; Navarro-Gonzalez, R.; Steele, A.; Summons, R. E.; Eigenbrode, J. L.; Mahaffy, P. R.

2015-12-01

Mudstones collected on the Yellowknife Bay site in Gale crater by the Curiosity rover, were analyzed with the Sample Analysis at Mars (SAM) chemical laboratory with the aim (among others) to detect and identify organic molecules in the Martian reglith [1]. The pyrolysis (to 900°C)-gas chromatography-mass spectrometry (Pyro-GCMS) analytical mode was systematically used to reach that goal. It revealed the existence of complex interactions between compounds present in the soil sample (e.g. oxychlorines [2]) and internal components of the SAM experiment (e.g. derivatization reactant) resulting in signals complex to interpret [3]. By comparing these results with those obtained for the other Mars samples analysed with SAM, and by carefully identifying, from laboratory work, the possible SAM internal contributions to the organic molecules detected [4], chlorobenzene has already been identified as mainly originating from organics present in the mudstone [5]. Since this discovery, we did additional studies of the chromatograms that reveal the presence of dichlorobenzene originating from an organic source endogenous to the sample. Even if the exact original source of these organic molecules cannot be strictly identified, the detection of several chlorinated aromatic molecules suggests the presence of a significant amount of aromatized materials which are in an oxidized state involving oxygen in the mudstone. We present here the corresponding results and the implication it can have on the origin of these organic materials References: [1] Mahaffy, P. et al. (2012) Space Sci Rev, 170, 401-478. [2] Glavin, D. et al. (2013), JGR. [3] Ming D. et al. (2013), Science 32, 64, [4] Miller K. et al. (In press), JGR, [5] Freissinet et al., (2015), JGR Pla. 120, 495.

Middle Devonian depositional environments for Rapid Member (Cedar Valley Group) interpreted from exposures at the Coralville spillway and elsewhere in eastern Iowa

DOE Office of Scientific and Technical Information (OSTI.GOV)

Witzke, B.J.; Bunker, B.J.

1994-04-01

Ongoing studies of the Cedar Valley Group were fortuitously aided by the exhumation of Rapid Mbr (Little Cedar Fm) carbonate strata below the coralville spillway, Johnson Co., Iowa, during the summer floods of 1993. Extensive bedding-plane exposures provided an exceptional opportunity to document fine-scale lateral biotic and lithologic variations within the member, and to compare these with data from elsewhere in eastern Iowa. The base of the Rapid Mbr is drawn at an abrupt lithic change above packstones of the Solon Mbr, marking a regional transgressive event. The basal 2.6 m of the Rapid is dominated by argillaceous skeletal wackestonesmore » with common brachiopods and echinoderm debris, interspersed with thin mudstones. The overlying 4 m comprises a series of 50--100 cm thick couplets which display alternations of thin mudstones and thicker brachiopod-rich wackepackstones. The next unit (2.9 m) is dominated by sparse-skeletal argillaceous mudstones. The paucity of burrowing and skeletal benthos through much of the unit is interpreted to reflect bottom oxygen stress in a relatively deep, possibly stratified cratonic seaway. Nevertheless, skeletal horizons within the unit indicate episodically favorable benthic conditions. The mudstone unit shallows upward into a brachiopod-rich wackestone interval which is, in turn, capped by a condensed horizon of phosphatic and glauconitic enrichment (near base of subterminus Fauna). Above this, two regionally extensive coral-rich biostromes occur. Upper Rapid strata show a complex of wackestone and packstone facies, with glauconitic enrichment and hardgrounds noted. The member is capped by shoal-water grainstones in the Coralville area, and by peritidal facies in northern Iowa.« less

Overpressure, Low Effective Stress, and Slope Failure in the Ursa Region, Deep-Water Gulf of Mexico

NASA Astrophysics Data System (ADS)

Sawyer, D. E.; Flemings, P. B.

2004-12-01

Slope failures are associated with overpressured pore fluids and low effective stresses in the Quaternary strata of the Ursa Region, deep-water Gulf of Mexico. At Ursa, a permeable turbidite sandstone (the Blue Unit) is overlain by a low-permeability mudstone. Overpressure in the mudstone, measured with a pore pressure penetrometer (piezoprobe), begin within a few meters of the seafloor and extend 250-450 meters down to the Blue Unit. The overpressure ratio (λ *=(Pp-Phydrostatic)\\ (Sv-Phydrostatic), where Sv is the overburden stress, Pp is pore pressure, and Phydrostatic is the hydrostatic pressure) ranges from 0.8 where the overburden is thin to 0.4 where the overburden is thick. Detachment surfaces, mapped with high resolution 3D seismic data, are associated with zones where effective stresses are low. Four subsurface slumps were mapped and are oriented generally northwest-southeast. Slump surface areas are less than 250 km2 and maximum scarp-wall height on the largest slide is ˜120 meters. We interpret that asymmetric loading of the Blue Unit by low-permeable mudstone has driven fluids to where overburden is thin, decreased effective stress, and generated slope instability.

Lithostratigraphy, provenance and facies distribution of Archaean cratonic successions in western Kenya

NASA Astrophysics Data System (ADS)

Ngecu, Wilson M.; Gaciri, Steve J.

1995-10-01

The greenstone belt of the Tanzanian shield in Western Kenya is composed of two supracrustal successions, which form the Nyanzian and Kavirondian Groups. The Nyanzian Group at the base is composed of mafic tholeiitic basalts, calc-alkaline dacites and rhyolites. The group is unconformably overlain by the Kavirondian Group. During recent field mapping, the Kavirondian Group was divided into three formations. The Shivakala Formation consists of thickly bedded basal conglomerates, which are interbedded with thin sandstone beds. The Igukhu Formation conformably overlies the Shivakala Formation and is composed of thickly and locally thinly bedded greywacke. The uppermost Mudaa Formation is composed of blocky mudstones and thinly laminated shales. A high proportion of volcanic, granitic and chert pebbles in the conglomerates, along with abundant quartz, feldspars and mudstone fragments in the greywacke, indicates a mixed provenance of volcanic, granitic and recycled sedimentary rocks. Primary sedimentary structures and lithofacies associations indicate that the conglomerates were deposited in an alluvial fan/fan-delta setting. The greywackes represent proximal turbidites while the mudstone and shales were deposited mainly as distal turbidites. In the study area there is no evidence of transitional nearshore or shallow marine facies transitional to the continental and deep marine facies.

In situ estimation of the effective chemical diffusion coefficient of a rock matrix in a fractured aquifer

USGS Publications Warehouse

Gebrekristos, R.A.; Shapiro, A.M.; Usher, B.H.

2008-01-01

An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8??10-6 m2/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment. ?? Springer-Verlag 2007.

Mechanical behavior in the Nankai inner accretionary prism, IODP Site C0002

NASA Astrophysics Data System (ADS)

Valdez, R. D., II; Saffer, D. M.

2017-12-01

Understanding the processes that control seismogenesis and stress state at subduction zones requires knowledge of fault zone and sediment physical and mechanical properties. As part of the International Ocean Discovery Program (IODP) Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE), Expedition 348 drilled into the Kumano forearc basin and underlying inner accretionary prism at Site C0002, located 35 km landward of the trench. One primary objective was to sample and characterize the mechanical behavior of the inner accretionary prism. Here we report on the frictional and unconfined compressive strength (UCS) of mudstone samples and a clay-rich shear zone recovered from 2182-2209 meters below sea floor (mbsf), determined from triaxial deformation tests at confining pressures from 1 to 7 MPa (UCS measurements on mudstones) and 36 MPa (strength of fault zone). Our results show that at a confining pressure of 1 MPa, the wall rock sediments fail at a peak differential stress of 9.1 MPa with a residual stress of 2.8 MPa. A clear peak and evolution to residual strength remains present at 7 MPa, and both the peak and residual strengths of the mudstones increases systematically with confining pressure. At a confining pressure of 36 MPa, the shear zone sediment yields at a differential stress of 25.2 MPa followed by strain-hardening to a maximum stress of 33.1 MPa. The shear zone is frictionally weaker than the surrounding mudstones, with a friction coefficient (μ) of 0.26-0.31, versus µ = 0.45 for the wall rock. The suite of tests defines a UCS for the mudstone of 7.9 MPa. Our friction data suggest that the inner wedge may be weaker than commonly assumed in applications of critical wedge theory to estimate the properties and conditions in accretionary prisms. One key implication is that for a given basal detachment friction coefficient, higher basal pore pressures (or lower wedge pore pressures) would be required to sustain observed taper angles. Additionally, the UCS we define is significantly lower than predicted by widely-adopted empirical relations between P wave velocity and UCS for shales (UCS of 15.5 MPa), suggesting that existing analyses of stress magnitudes from borehole breakout widths may overestimate horizontal stress magnitudes.

Grain Size Distribution in Mudstones: A Question of Nature vs. Nurture

NASA Astrophysics Data System (ADS)

Schieber, J.

2011-12-01

Grain size distribution in mudstones is affected by the composition of the source material, the processes of transport and deposition, and post-depositional diagenetic modification. With regard to source, it does make a difference whether for example a slate belt is eroded vs a stable craton. The former setting tends to provide a broad range of detrital quartz in the sub 62 micron size range in addition to clays and greenschist grade rock fragments, whereas the latter may be biased towards coarser quartz silt (30-60 microns), in addition to clays and mica flakes. In flume experiments, when fine grained materials are transported in turbulent flows at velocities that allow floccules to transfer to bedload, a systematic shift of grain size distribution towards an increasingly finer grained suspended load is observed as velocity is lowered. This implies that the bedload floccules are initially constructed of only the coarsest clay particles at high velocities, and that finer clay particles become incorporated into floccules as velocity is lowered. Implications for the rock record are that clay beds deposited from decelerating flows should show subtle internal grading of coarser clay particles; and that clay beds deposited from continuous fast flows should show a uniform distribution of coarse clays. Still water settled clays should show a well developed lower (coarser) and upper (finer) subdivision. A final complication arises when diagenetic processes, such as the dissolution of biogenic silica, give rise to diagenetic quartz grains in the silt to sand size range. This diagenetic silica precipitates in fossil cavities and pore spaces of uncompacted muds, and on casual inspection can be mistaken for detrital quartz. In distal mudstone successions close to 100 % of "apparent" quartz silt can be of that origin, and reworking by bottom currents can further enhance a detrital perception by producing rippled and laminated silt beds. Although understanding how size distributions in mudstones evolve is considered central to problems in hillslope, fluvial, aeolian, coastal, and submarine systems, one can not simply measure distributions and hope to arrive at an answer. The complex origins of mudstones are reflected in their very broad compositional range, and multiple overprinted processes have to be considered in order to make sense out of observed grain size distributions.

Evidence for Smectite Clays from MSL SAM Analyses of Mudstone at Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

McAdam, Amy; Franz, Heather; Mahaffy, Paul R.; Eigenbrode, Jennifer L.; Stern, Jennifer C.; Brunner, Anna; Archer, Paul Douglas; Ming, Douglas W.; Morris, Richard V.; Atreya, Sushil K.

2013-01-01

Drilled samples of mudstone from the Sheepbed unit at Yellowknife Bay were analyzed by MSL instruments including the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments in MSL's Analytical Laboratory. CheMin analyses revealed the first in situ X-ray diffraction based evidence of clay minerals on Mars, which are likely trioctahedral smectites (e.g., saponite) and comprise approx 20% of the mudstone sample (e.g., Bristow et al., this meeting). SAM analyses, which heated the mudstone samples to 1000 C and monitored volatiles evolved to perform in situ evolved gas analysis mass spectrometry (EGA-MS), resulted in a H2O trace exhibiting a wide evolution at temperatures < 500 C, and an evolution peak at higher temperatures near approx 750 C. The low temperature H2O evolution has many potential contributors, including adsorbed H2O, smectite interlayer H2O, and structural H2O/OH from bassanite and akaganeite (identified by CheMin) and H2O/OH from amorphous phases in the sample. The high temperature H2O is consistent with the evolution of H2O from the dehydroxylation of the smectite clay mineral. Comparison to EGA-MS data collected under SAM-like conditions on a variety of clay mineral reference materials indicate that a trioctahedral smectite, such as saponite, is most consistent with the high temperature H2O evolution observed. There may also be SAM EGA-MS evidence for a small high temperature H2O evolution from scoop samples from the Yellowknife Bay Rocknest sand shadow bedform. As in the mudstone samples, this evolution may indicate the detection of smectite clays, and the idea that minor clays may be present in Rocknest materials that could be expected to be at least partially derived from local sources is reasonable. But, because smectite clays were not definitively observed in CheMin analyses of Rocknest materials, they must be present at much lower abundances than the approx 20% observed in the mudstone samples. This potential detection underscores the complementary nature of the MSL CheMin and SAM instruments for investigations of martian sample mineralogy. Information on the nature of Yellowknife Bay clay minerals may also be available from the detection of H2 evolved during SAM EGA-MS at high temperature. A likely source of at least some of this H2 is H2O evolved from the smectite clays at high temperature, and it is possible these evolutions can be used in a similar fashion to high temperature H2O releases to provide constraints on the clay minerals in a sample. In addition, the D/H of this high temperature H2, as well as the H2O, can be derived from SAM MS and Tunable Laser Spectrometer (TLS) data, respectively. These D/H values may help to inform the provenance of high and low temperature water evolved from martian samples

Depositional sequences and facies in the Torok Formation, National Petroleum Reserve, Alaska (NPRA)

USGS Publications Warehouse

Houseknecht, David W.; Schenk, Christopher J.

2002-01-01

Brookian turbidites (Cretaceous through Tertiary) have become oil exploration objectives on the NorthSlope of Alaska during the past decade, and it is likely this focus will extend into the National Petroleum Reserve-Alaska (NPRA). A regional grid of 2-D seismic data, sparse well control, and field work in the Brooks Range foothills provide constraints for an ongoing effort to establish a sequence stratigraphic framework for Brookian turbidites in the Torok Formation across NPRA. The Torok Formation and overlying Nanushuk Formation (both mostly Albian) display the overall seismic geometry of bottomset-clinoform-topset strata indicating northeastward migration of a shelf margin. Within bottomset and clinoform strata of the Torok, depositional sequences have been identified that represent four distinct phases of shelf-margin sedimentation. (1) Regression, representing low relative sea level, is characterized by the development of an erosional surface on the shelf and upper slope, and the deposition of turbidite channel deposits on the middle to lower slope and submarine fan deposits at the base of slope. These deposits constitute a lowstand systems tract (LST). (2) Transgression, representing rising relative sea level, is characterized by the deposition of a mudstone drape on the basin floor, slope, and outer shelf. This drape comprises relatively condensed facies that constitute a transgressive systems tract (TST). (3) Aggradation, representing high relative sea level, is characterized by the deposition of relatively thick strata on the outer shelf and moderately thick mudstones on the slope. (4) Progradation, also representing high relative sea level, is characterized by the deposition of relatively thin strata on the outer shelf and very thick mudstones on the slope. Together, deposits of the aggradation and progradation phases constitute a highstand systems tract (HST). Large scale geometries of Torok strata vary across the Colville basin. In southern NPRA, high rates of subsidence accommodated the deposition of a "foredeep clinoform wedge" that contains a high proportion of sand-rich LST deposits. In northern NPRA, lower rates of subsidence favored the accumulation of mud-rich HST deposits. The most favorable stratigraphic trapping geometries in the Torok Formation occur where amalgamated sandstones deposited in turbidite channels incised on the mid- to lower-slope and on the proximal parts of submarine fans during regression (LSTs) are capped by relatively condensed mudstone facies deposited during transgression (TSTs). Common successions observed in Torok cores include a spectrum of slope and turbidite facies. Upper slope facies comprise laminated mudstones and siltstones that locally display evidence of slumping, sliding, and chaotic failure. Lower slope facies comprise heterolithic turbidites at some locations and interlaminated mudstones and thin, very fine-grained sandstones at others. Torok turbidites include amalgamated sandstones deposited in channel systems as well as thin-bedded, widespread sandstones deposited by unconfined flows on lobes or in channel overbank settings. These turbidite facies likely occur in both channel-lobe systems and slope apron systems within the Torok.

Distribution of leached radioactive material in the Legin Group Area, San Miguel County, Colorado

USGS Publications Warehouse

Rogers, Allen S.

1950-01-01

Radioactivity anomalies, which are small in magnitude, and probably are not caused by extensions of known uranium-vanadium ore bodies, were detected during the gamma-ray logging of diamond-drill holes in the Legin group of claims, southwest San Miguel County, Colo. The positions of these anomalies are at the top surfaces of mudstone strata within, and at the base of, the ore-bearing sandstone of the Salt Wash member of the Morrison formation. The distribution of these anomalies suggests that ground water has leached radioactive material from the ore bodies and has carried it down dip and laterally along the top surfaces of underlying impermeable mudstone strata for distance as great as 300 feet. The anomalies are probably caused by radon and its daughter elements. Preliminary tests indicate that radon in quantities up to 10-7 curies per liter may be present in ground water flowing along sandstone-mudstone contacts under carnotite ore bodies. In comparison, the radium content of the same water is less than 10-10 curies per liter. Further substantiation of the relationship between ore bodies, the movement of water, and the radon-caused anomalies may greatly increase the scope of gamma-ray logs of drill holes as an aid to prospecting.

Collision-induced tectonism along the northwestern margin of the Indian subcontinent as recorded in the Upper Paleocene to Middle Eocene strata of central Pakistan (Kirthar and Sulaiman Ranges)

USGS Publications Warehouse

Warwick, Peter D.; Johnson, Edward A.; Khan, Intizar H.

1998-01-01

Outcrop data from the Upper Paleocene to Middle Eocene Ghazij Formation of central Pakistan provide information about the depositional environments, source areas, and paleogeographic and tectonic settings along the northwestern margin of the Indian subcontinent during the closing of the Tethys Ocean. In this region, in the lower part of the exposed stratigraphic sequence, are various marine carbonate-shelf deposits (Jurassic to Upper Paleocene). Overlying these strata is the Ghazij, which consists of marine mudstone (lower part), paralic sandstone and mudstone (middle part), and terrestrial mudstone and conglomerate (upper part). Petrographic examination of sandstone samples from the middle and upper parts reveals that rock fragments of the underlying carbonate-shelf deposits are dominant; also present are volcanic rock fragments and chromite grains. Paleocurrent measurements from the middle and upper parts suggest that source areas were located northwest of the study area. We postulate that the source areas were uplifted by the collision of the subcontinent with a landmass during the final stages of the closing of the Tethys Ocean. Middle Eocene carbonate-shelf deposits that overlie the Ghazij record a return to marine conditions prior to the Miocene to Pleistocene sediment influx denoting the main collision with Eurasia.

Mineralogical and Geochemical Trends in a Fluviolacustrine Sequence in Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Rampe, E.; Ming, D.; Morris, R.; Blake, D.; Vaniman, D.; Bristow, T.; Chipera, S.; Yen, A.; Grotzinger, J.; DesMarais, D.

2016-01-01

The Mars Science Laboratory rover, Curiosity, landed at Gale crater in August 2012 and has been investigating a sequence of dominantly fluviolacustrine sediments deposited 3.6-3.2 billion years ago. Curiosity collects quantitative mineralogical data with the CheMin XRD/XRF instrument and quantitative chemical data with the APXS and ChemCam instruments. These datasets show stratigraphic mineralogical and geochemical variability that suggest a complex aqueous history. The Murray Formation, primarily composed of fine-laminated mudstone, has been studied in detail since the arrival at the Pahrump Hills in September 2014. CheMin data from four samples show variable amounts of iron oxides, phyllosilicates, sulfates, amorphous and crystalline silica, and mafic silicate minerals. Geochemical data throughout the section show that there is significant variability in Zn, Ni, and Mn concentrations. Mineralogical and geochemical trends with stratigraphy suggest one of possibly several aqueous episodes involved alteration in an open system under acidic pH, though other working hypotheses may explain these and other trends. Data from the Murray Formation contrast with those collected from the Sheepbed mudstone located approximately 60 meters below the base of the Murray Formation, which showed evidence for diagenesis in a closed system at circumneutral pH. Ca-sulfates filled late-stage veins in both mudstones.

Hydrothermal Synthesis of Analcime from Kutingkeng Formation Mudstone

NASA Astrophysics Data System (ADS)

Hsiao, Yin-Hsiu; Chen, Kuan-Ting; Ray, Dah-Tong

2015-04-01

In southwest of Taiwan, the foothill located in Tainan-Kaohsiung city is the exposed area of Pliocene strata to early Pleistocene strata. The strata are about a depth of five thousand, named as Kutigkeng Formation. The outcrop of Kutigkeng Formation is typical badlands, specifically called 'Moon World.' It is commonly known as no important economic applications of agricultural land. The mineral compositions of Kutingkeng Formation are quartz, clay minerals and feldspar. The clay minerals consist of illite, clinochlore and swelling clays. To study how the phase and morphology of analcime formed by hydrothermal synthesis were affected, analcime was synthesized from the mudstone of Kutinkeng Formation with microwave hydrothermal reaction was investigated. The parameters of the experiment were the reaction temperature, the concentration of mineralizer, solids/liquid ratio and time. The sodium silicate (Na2SiO3) were used as mineralizer. The results showed that the analcime could be synthesized by hydrothermal reaction above 180° from Kutinkeng Formation mudstone samples. At the highest temperature (240°) of this study, the high purity analcime could be produced. When the concentration of Na2SiO3=3~6M, analcime could be synthesized at 240°. The best solids/liquid ratio was approximate 1 to 5. The hydrothermal reaction almost was completed after 4 hours.

Proximal impact deposits at the Cretaceous-Tertiary boundary in the Gulf of Mexico: a restudy of DSDP Leg 77 Sites 536 and 540

NASA Technical Reports Server (NTRS)

Alvarez, W.; Smit, J.; Lowrie, W.; Asaro, F.; Margolis, S. V.; Claeys, P.; Kastner, M.; Hildebrand, A. R.

1992-01-01

Restudy of Deep Sea Drilling Project Sites 536 and 540 in the southeast Gulf of Mexico gives evidence for a giant wave at Cretaceous-Tertiary boundary time. Five units are recognized: (1) Cenomanian limestone underlies a hiatus in which the five highest Cretaceous stages are missing, possibly because of catastrophic K-T erosion. (2) Pebbly mudstone, 45 m thick, represents a submarine landslide possibly of K-T age. (3) Current-bedded sandstone, more than 2.5 m thick, contains anomalous iridium, tektite glass, and shocked quartz; it is interpreted as ejecta from a nearby impact crater, reworked on the deep-sea floor by the resulting tsunami. (4) A 50-cm interval of calcareous mudstone containing small Cretaceous planktic foraminifera and the Ir peak is interpreted as the silt-size fraction of the Cretaceous material suspended by the impact-generated wave. (5) Calcareous mudstone with basal Tertiary forams and the uppermost tail of the Ir anomaly overlies the disturbed interval, dating the impact and wave event as K-T boundary age. Like Beloc in Haiti and Mimbral in Mexico, Sites 536 and 540 are consistent with a large K-T age impact at the nearby Chicxulub crater.

Application of Unmanned Aerial System-based Photogrammetry to Monitor Landforms Evolution of Mudstone Badlands

NASA Astrophysics Data System (ADS)

Chen, Yichin

2017-04-01

Mudstone badlands are the area characteristized by its rapid erosion and steep, fractured, and barren landforms. Monitoring the topography changes in badland help improve our knowledge of the hillslope and river processing on landforms and develop susceptibility model for surface erosion hazards. Recently, advances in unmanned aerial system (UAS) and close-range photogrammetry technology have opened up the possibility of effectively measuring topography changes with high spatiotemporal resolutions. In this study, we used the UAS and close-range photogrammetry technology to monitor the topography changes in a rapidly eroded badland, south-western Taiwan. A small mudstone hillslope with area of 0.2 ha approximately and with slope gradient of 37 degrees was selected as the study site. A widely used and commercial quadcopter equipped non-metric camera was used to take images with ground sampling distance (GSD) 5 mm approximately. The Pix4DMapper, a commercial close-range photogrammetry software, was used to perform stereo matching, extract point clouds, generate digital surface models (DSMs) and orthoimage. To control model accuracy, a set of ground control points was surveyed by using eGPS. The monitoring was carried out after every significant rainfall event that may induced observable erosion in the badland site. The results show that DSMs have the GSDs of 4.0 5.4 mm and vertical accuracy of 61 116 mm. The accuracy largely depends on the quality of ground control points. The spatial averaged erosion rate during six months of monitoring was 328 mm, which is higher in the gully sides than in the ridges. The erosion rate is positively correlated with the slope gradient and drainage contributing area that implies the important role of surface gully erosion in mudstone badland erosion. This study shows that UAS and close-range photogrammetry technology can be used to monitor the topography change in badland areas effectively and can provide high spatiotemporal resolutions of DSMs for developing distributed surface erosion models.

Paleomagnetic results from Late Pennsylvanian marls and Early Permian red paleosols of the Dunkard group, Ohio and West Virginia, U.S.A.

NASA Astrophysics Data System (ADS)

Abrajevitch, A.; Oliva, B.; Peters, S.; Beehr, A.; van der Voo, R.

2006-12-01

Sediments of the Dunkard Gr. were deposited in the Appalachian foreland basin during the Pennsylvanian and Early Permian, an interval encompassing the long reverse polarity Kiaman chron. Lithofacies in the Dunkard Gr. in eastern Ohio and western West Virginia include lenticular and sheet-form cross-bedded micaceous sandstones, coal, mottled red and purple mudstones, gray laminated mudstones and argillaceous lime mudstones. They are indicative of deposition on a low-gradient, tropical wet-dry fluvial plain. Few lithofacies are laterally persistent over sufficiently long distances, so that correlation schemes are based largely on coal horizons, partly for historical economic reasons and partly because coal beds appear to be more laterally persistent than most other lithofacies. Magnetostratigraphy would therefore provide a powerful additional correlation tool in the Dunkard Gr, A short normal polarity interval has been reported in the Dunkard Gr. (Helsley, 1965), but to date such a change in magnetic field polarity has not been confirmed by later studies. To confirm the presence of the normal polarity subchron and to explore the possibility of using it as a correlation tool in the Dunkard Gr., we sampled 5 sections thought to straddle the Late Pennyslvanian-Early Permian boundary. Sampled lithofacies include red and mottled red-purple paleosols, grey mudstones containing siderite concretions, micaceous sandstones, and dark gray argillaceous limestones. Samples were demagnetized thermally and by AF. The remanent magnetic directions agree with those expected for the Early Permian. A change in polarity was detected in three of the studied sections. Magnetization is carried by several different magnetic minerals, mostly hematite in paleosols and iron sulfides in combination with magnetite in sandstones, marls and limestones. Although we have found good evidence for the normal polarity interval within Kiaman age rocks of the Dunkard Gr., additional magnetostratigraphic data are needed to validate the present lithology-based correlations and to determine the temporal extent of the normal polarity chron.

Lithologic Controls on Structure Highlight the Role of Fluids in Failure of a Franciscan Complex Accretionary Prism Thrust Fault

NASA Astrophysics Data System (ADS)

Bartram, H.; Tobin, H. J.; Goodwin, L. B.

2015-12-01

Plate-bounding subduction zone thrust systems are the source of major earthquakes and tsunamis, but their mechanics and internal structure remain poorly understood and relatively little-studied compared to faults in continental crust. Exposures in exhumed accretionary wedges present an opportunity to study seismogenic subduction thrusts in detail. In the Marin Headlands, a series of thrusts imbricates mechanically distinct lithologic units of the Mesozoic Franciscan Complex including pillow basalt, radiolarian chert, black mudstone, and turbidites. We examine variations in distribution and character of structure and vein occurrence in two exposures of the Rodeo Cove thrust, a fossil plate boundary exposed in the Marin Headlands. We observe a lithologic control on the degree and nature of fault localization. At Black Sand Beach, deformation is localized in broad fault cores of sheared black mudstone. Altered basalts, thrust over greywacke, mudstone, and chert, retain their coherence and pillow structures. Veins are only locally present. In contrast, mudstone is virtually absent from the exposure 2 km away at Rodeo Beach. At this location, deformation is concentrated in the altered basalts, which display evidence of extensive vein-rock interaction. Altered basalts exhibit a pervasive foliation, which is locally disrupted by both foliation-parallel and cross-cutting carbonate-filled veins and carbonate cemented breccia. Veins are voluminous (~50%) at this location. All the structures are cut by anastomosing brittle shear zones of foliated cataclasite or gouge. Analyses of vein chemistry will allow us to compare the sources of fluids that precipitated the common vein sets at Rodeo Beach to the locally developed veins at Black Sand Beach. These observations lead us to hypothesize that in the absence of a mechanically weak lithology, elevated pore fluid pressure is required for shear failure. If so, the vein-rich altered basalt at Rodeo Beach may record failure of an igneous basement asperity.

Evidence for Smectite Clays from MSL SAM Analyses of Mudstone at Yellowknife Bay, Gale Crater, Mars

NASA Astrophysics Data System (ADS)

McAdam, A.; Franz, H.; Mahaffy, P. R.; Eigenbrode, J. L.; Stern, J. C.; Brunner, A.; Sutter, B.; Archer, P. D.; Ming, D. W.; Morris, R. V.; Atreya, S. K.; Team, M.

2013-12-01

Drilled samples of mudstone from the Sheepbed unit at Yellowknife Bay were analyzed by MSL instruments including the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments in MSL's Analytical Laboratory. CheMin analyses revealed the first in situ X-ray diffraction based evidence of clay minerals on Mars, which are likely trioctahedral smectites (e.g., saponite) and comprise ~20% of the mudstone sample (e.g., Bristow et al., this meeting). SAM analyses, which heated the mudstone samples to 1000oC and monitored volatiles evolved to perform in situ evolved gas analysis mass spectrometry (EGA-MS), resulted in a H2O trace exhibiting a wide evolution at temperatures <500oC, and an evolution peak at higher temperatures near ~750oC. The low temperature H2O evolution has many potential contributors, including adsorbed H2O, smectite interlayer H2O, and structural H2O/OH from bassanite and akaganeite (identified by CheMin) and H2O/OH from amorphous phases in the sample. The high temperature H2O is consistent with the evolution of H2O from the dehydroxylation of the smectite clay mineral. Comparison to EGA-MS data collected under SAM-like conditions on a variety of clay mineral reference materials indicate that a trioctahedral smectite, such as saponite, is most consistent with the high temperature H2O evolution observed. There may also be SAM EGA-MS evidence for a small high temperature H2O evolution from scoop samples from the Yellowknife Bay Rocknest sand shadow bedform. As in the mudstone samples, this evolution may indicate the detection of smectite clays, and the idea that minor clays may be present in Rocknest materials that could be expected to be at least partially derived from local sources is reasonable. But, because smectite clays were not definitively observed in CheMin analyses of Rocknest materials, they must be present at much lower abundances than the ~20% observed in the mudstone samples. This potential detection underscores the complementary nature of the MSL CheMin and SAM instruments for investigations of martian sample mineralogy. Information on the nature of Yellowknife Bay clay minerals may also be available from the detection of H2 evolved during SAM EGA-MS at high temperature. A likely source of at least some of this H2 is H2O evolved from the smectite clays at high temperature, and it is possible these evolutions can be used in a similar fashion to high temperature H2O releases to provide constraints on the clay minerals in a sample. In addition, the D/H of this high temperature H2, as well as the H2O, can be derived from SAM MS and Tunable Laser Spectrometer (TLS) data, respectively. These D/H values may help to inform the provenance of high and low temperature water evolved from martian samples (Mahaffy et al., this meeting).

Spatio-Temporal Self-Organization in Mudstones (Invited)

NASA Astrophysics Data System (ADS)

Dewers, T. A.

2010-12-01

Shales and other mudstones are the most abundant rock types in sedimentary basins, yet have received comparatively little attention. Common as hydrocarbon seals, these are increasingly being targeted as unconventional gas reservoirs, caprocks for CO2 sequestration, and storage repositories for waste. The small pore and grain size, large specific surface areas, and clay mineral structures lend themselves to rapid reaction rates, high capillary pressures, and semi-permeable membrane behavior accompanying changes in stress, pressure, temperature and chemical conditions. Under far from equilibrium conditions, mudrocks display a variety of spatio-temporal self-organized phenomena arising from nonlinear thermo-mechano-chemo-hydro coupling. Beginning with a detailed examination of nano-scale pore network structures in mudstones, we discuss the dynamics behind such self-organized phenomena as pressure solitons in unconsolidated muds, chemically-induced flow self focusing and permeability transients, localized compaction, time dependent well-bore failure, and oscillatory osmotic fluxes as they occur in clay-bearing sediments. Examples are draw from experiments, numerical simulation, and the field. These phenomena bear on the ability of these rocks to serve as containment barriers. This work is funded by the US Department of Energy, Office of Basic Energy Sciences. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000

Cyclic transgressive and regressive sequences, Paleocene Suite, Sirte basin, Libya

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abushagur, S.A.

1986-05-01

The Farrud lithofacies represent the main reservoir rock of the Ghani oil field and Western Concession Eleven of the Sirte basin, Libya. Eight microfacies are recognized in the Farrud lithofacies in the Ghani field area: (1) bryozoan-bioclastic (shallow, warm, normal marine shelf deposits); (2) micrite (suggesting quiet, low-energy conditions such as may have existed in a well-protected lagoon); (3) dasycladacean (very shallow, normal marine environment); (4) bioclastic (very shallow, normal marine environment with moderate to vigorous energy); (5) mgal (very shallow, normal marine environment in a shelf lagoon); (6) pelletal-skeletal (deposition within slightly agitated waters of a sheltered lagoon withmore » restricted circulation); (7) dolomicrite (fenestrate structures indicating a high intertidal environment of deposition); and (8) anhydrite (supratidal environment). The Paleocene suite of the Farrud lithofacies generally shows a prograding, regressive sequence of three facies: (1) supratidal facies, characterized by nonfossiliferous anhydrite, dolomite, and dolomitic pelletal carbonate mudstone; (2) intertidal to very shallow subtidal facies, characterized by fossiliferous, pelletal, carbonate mudstone and skeletal calcarenite; and (3) subtidal facies, characterized by a skeletal, pelletal, carbonate mudstone. Source rocks were primarily organic-rich shales overlying the Farrud reservoir rock. Porosity and permeability were developed in part by such processes as dolomitization, leaching, and fracturing in the two progradational, regressive carbonate facies. Hydrocarbons were trapped by a supratidal, anhydrite cap rock.« less

Chemical variations in Yellowknife Bay formation sedimentary rocks analyzed by ChemCam on board the Curiosity rover on Mars

USGS Publications Warehouse

Mangold, Nicolas; Forni, Olivier; Dromart, G.; Stack, K.M.; Wiens, Roger C.; Gasnault, Olivier; Sumner, Dawn Y.; Nachon, Marion; Meslin, Pierre-Yves; Anderson, Ryan B.; Barraclough, Bruce; Bell, J.F.; Berger, G.; Blaney, D.L.; Bridges, J.C.; Calef, F.; Clark, Brian R.; Clegg, Samuel M.; Cousin, Agnes; Edgar, L.; Edgett, Kenneth S.; Ehlmann, B.L.; Fabre, Cecile; Fisk, M.; Grotzinger, John P.; Gupta, S.C.; Herkenhoff, Kenneth E.; Hurowitz, J.A.; Johnson, J. R.; Kah, Linda C.; Lanza, Nina L.; Lasue, Jeremie; Le Mouélic, S.; Lewin, Eric; Malin, Michael; McLennan, Scott M.; Maurice, S.; Melikechi, Noureddine; Mezzacappa, Alissa; Milliken, Ralph E.; Newsome, H.L.; Ollila, A.; Rowland, Scott K.; Sautter, Violaine; Schmidt, M.E.; Schroder, S.; D'Uston, C.; Vaniman, Dave; Williams, R.A.

2015-01-01

The Yellowknife Bay formation represents a ~5 m thick stratigraphic section of lithified fluvial and lacustrine sediments analyzed by the Curiosity rover in Gale crater, Mars. Previous works have mainly focused on the mudstones that were drilled by the rover at two locations. The present study focuses on the sedimentary rocks stratigraphically above the mudstones by studying their chemical variations in parallel with rock textures. Results show that differences in composition correlate with textures and both manifest subtle but significant variations through the stratigraphic column. Though the chemistry of the sediments does not vary much in the lower part of the stratigraphy, the variations in alkali elements indicate variations in the source material and/or physical sorting, as shown by the identification of alkali feldspars. The sandstones contain similar relative proportions of hydrogen to the mudstones below, suggesting the presence of hydrous minerals that may have contributed to their cementation. Slight variations in magnesium correlate with changes in textures suggesting that diagenesis through cementation and dissolution modified the initial rock composition and texture simultaneously. The upper part of the stratigraphy (~1 m thick) displays rocks with different compositions suggesting a strong change in the depositional system. The presence of float rocks with similar compositions found along the rover traverse suggests that some of these outcrops extend further away in the nearby hummocky plains.

Mineralogical Results from the Mars Science Laboratory Rover Curiosity

NASA Technical Reports Server (NTRS)

Blake, David Frederick.

2017-01-01

NASA's CheMin instrument, the first X-ray Diffractometer flown in space, has been operating on Mars for nearly five years. CheMin was first to establish the quantitative mineralogy of the Mars global soil (1). The instrument was next used to determine the mineralogy of a 3.7 billion year old lacustrine mudstone, a result that, together with findings from other instruments on the MSL Curiosity rover, documented the first habitable environment found on another planet (2). The mineralogy of this mudstone from an ancient playa lake was also used to derive the maximum concentration of CO2 in the early Mars atmosphere, a surprisingly low value that calls into question the current theory that CO2 greenhouse warming was responsible for the warm and wet environment of early Mars. CheMin later identified the mineral tridymite, indicative of silica-rich volcanism, in mudstones of the Murray formation on Mt. Sharp. This discovery challenges the paradigm of Mars as a basaltic planet and ushers in a new chapter of comparative terrestrial planetology (3). CheMin is now being used to systematically sample the sedimentary layers that comprise the lower strata of Mt. Sharp, a 5,000 meter sequence of sedimentary rock laid down in what was once a crater lake, characterizing isochemical sediments that through their changing mineralogy, document the oxidation and drying out of the Mars in early Hesperian time.

A Permo-Carboniferous tide-storm interactive system: Talchir formation, Raniganj Basin, India

NASA Astrophysics Data System (ADS)

Bhattacharya, H. N.; Bhattacharya, Biplab

2006-08-01

Sandstone/siltstone-mudstone interbedded facies of the Permo-Carboniferous Talchir formation, Gondwana Supergroup, is exposed in the Raniganj Basin and records the activities of tidal currents in a terminoglacial, storm-influenced shallow marine setting. Tidal bundles of various types with pause plane drapes, evidence of time-velocity asymmetry and rare bidirectional current flow patterns are indicative of tidal activity. Chance preservation of such structures from storm reworking might have occurred due to dampening of storm waves on the low-gradient muddy substrate of the tidal flat. The tide-generated stratifications are draped by over-thickened muddy-siltstone with wavy/hummocky laminations. Increased suspended sediment concentrations following a storm yielded such thick mudstone drapes. Thin beds containing tidal structures indicate poor sediment supply in a blind tidal embayment.

Drilling the Mediterranean Messinian Evaporites to Answer Key Questions Related to Massive Microbial Dolomite Formation under Hypersaline Alkaline Conditions

NASA Astrophysics Data System (ADS)

McKenzie, Judith A.; Bontognali, Tomaso R. R.; Vasconcelos, Crisogono

2014-05-01

Deep-sea drilling in the Mediterranean during DSSP Leg 13 in 1970 revealed the basin-wide occurrence of a Messinian evaporite formation. This spectacular discovery was pursued further during a subsequent drilling program, DSDP Leg 42A, in 1975, which was designed, in part, to obtain continuous cores to study the evolution of the salinity crisis itself (Hsü, Montadert, et al., 1978). Specifically, drilling at a water depth of 4,088 m in the Ionian Sea, DSDP Site 374: Messina Abyssal Plain, penetrated about 80 m into the uppermost part of the Messinian upper evaporite formation. The sedimentary sequence comprises dolomitic mudstone overlying dolomitic mudstone/gypsum cycles, which in turn overlie anhydrite and halite. The non-fossiliferous dolomitic mudstone is generally rich in organic carbon, with TOC values ranging from 0.9% to 5.3%, of possible marine origin with a good source rock potential. Commonly laminated dolomitic mudstones contain preserved filamentous cyanobacterial remains suggesting that conditions were conducive for microbial mat growth. The Ca-dolomite, composed of fine-grained anhedral crystals in the size range of 2-4 μm, is probably a primary precipitate. The unusual interstitial brines of the dolomitic mudstone units have very high alkalinities with a low pH of 5 to 6. The Mg concentration (2250 mmoles/l) is extremely elevated, whereas the Ca concentration is nearly zero. Finally, the drilled evaporite sedimentary sequence was interpreted as being deposited in an alkaline lake/sea ("Lago Mare"), which covered the area during the latest Messinian. Projecting forward 40 years since the DSDP Leg 42A drilling campaign, research into the factors controlling dolomite precipitation under Earth surface conditions has led to the development of new models involving the metabolism of microorganisms and associated biofilms to overcome the kinetic inhibitions associated with primary dolomite precipitation. Together with laboratory experiments, microbial dolomite precipitation has been studied extensively in rare modern environments, such as the arid coastal sabkhas of Abu Dhabi, UAE and the hypersaline coastal lagoons in Brazil. However, extrapolation of these studies of relatively limited aerial extent to interpret larger-scale, ancient dolomite formation of putative evaporitic origin remains elusive. Such ancient micritic dolomite formations with associated micro-porosity represent extremely valuable hydrocarbon reservoirs. Therefore, a comprehensive investigation of a relatively recent micritic dolomite deposit that has not experienced extensive burial depths and diagenesis is essential to extend our understanding of these important reservoir systems. Based on the limited data obtained during drilling at DSDP Site 374: Messina Abyssal Plain, the dolomitic mudstones of the uppermost Messinian evaporite complex represent an ideal candidate for such an extensive study in a "natural laboratory". Thus, to increase our understanding of the biogeochemical processes associated with ancient massive dolomite formation, we propose to document the scientific objectives to support a major new drilling campaign to study the sub-seafloor Messinian evaporite complex in the deep Mediterranean basins, using greatly enhanced drilling technology that is currently available within the new International Ocean Discovery Program (IODP). Hsü, K., Montadert, L. et al., 1978. Initial Reports of the Deep Sea Drilling Project, Volume 42, Part 1: Washington (U.S. Government Printing Office).

JOINTS AND SYN-SEDIMENTARY FAULTS NETWORKS IN MARINE CLAYS AND MUDSTONES. Importance for Radwaste storage

NASA Astrophysics Data System (ADS)

Arnould, M.

2009-12-01

There is a number of marine clays, mudstones, marls, 100 to 200 m thick, showing smectites, mixed layers illite/smectite, with a small percentage of organic matter and sulphides with a variable clay, silt, and carbonate content. I published (Arnould , 2006) examples from Lower Cambrian to Miocene in age and from the Baltic shore to Spain in Europe. Observations were made mostly in quarries and pits down to more than 40 m and in underground research laboratories (URL). Only visible on fresh cuts amongst a variety of fissures there is always a network of joints. Schematically one family is the bedding (horizontal) the two others are normal to the bedding and orthogonal between them. The orientations of vertical joints are different from the orientations of pits and quarries’s walls. The networks are intrinsic. It was first well described by Skempton & al (1969) in Eocene London Clay. Joints are matt in texture, clean, without filling or cement. The order of magnitude of their linear dimensions is decimeter to meter. It is necessary to start from the original sediment: mud. Deposited in flakes mud has a bee’s nest microscopic structure. Each nest is full of water. Hence mud may have a water content up to 300%, reported to its dry weight. Paradoxically mud is impervious. As proposed by Cosgrove (2001) progressive but discontinuous hydraulic fracturing could be the origin of vertical joints, with drainage upwards and compaction of the sediment. Geological observations show that ioints are formed during the sedimentation process. There is also a world literature concluding at the necessary early fracturing of mudstones and marls hosts of sand dykes. Very few faults are identified in field observations and on exploration logs. But it is obvious that drainage and compaction of mud over thousands square kilometers induced differential settlements with many syn-sedimentary non tectonic faults constituting another discontinuity network. These faults inside the same material with rather small throws are difficult to identify. Their number increases wifh accuracy of geophysical research. Conclusions for underground storage of radioactive waste . There are four underground laboratories on duty in mudstones and clays in Western Europe. No natural discontinuities, joints or faults have been observed during their excavation rapidly followed by lining.This draw some people to the imprudent conclusion that there were no natural discontinuities. In accordance to the very low permeabilities measured by in situ tests all natural discontinuities are closed up at depth by the stresss field. They are sealed but not healed because the temperature of diagenesis remained below 50°C. They can reopen by relaxation of stresses and by desiccation, as in Tournemire tunnel /URL in toarcian mudstones and at Mont Terri URL in Opalinus Clay. Open fissures visible in non lined parts of galleries appear weeks or months after the excavation. After the change of concept from burial to storage and retrievability the problem should not be underestimated. References : Arnould M (2006) Discontinuity networks in mudstones : a geological approach. Bull Eng Geol Environ. Springer ed 65:413-422 Skempton & al (1969) Joints and fissures in the London Clay at Wraysbury and Edgware Geotechnique 19 : 205-217.

An 110 Ma Crocodilian-Bearing Vertebrate Assemblage Preserved Between Basalt Flows on a mid-Pacific Seamount, ODP Site 865, Allison Guyot

NASA Astrophysics Data System (ADS)

Firth, J. V.; Yancey, T.; Alvarez-Zarikian, C.

2006-12-01

Crocodilian teeth, fish teeth, scales, and bones, and teeth and bones of uncertain affinities occur within a mudstone deposit sandwiched between basalt flows at the base of ODP Hole 865A on Allison Guyot in the middle of the Pacific Ocean. Age control from large benthic foraminifers, Sr-isotope stratigraphy, and radiometric ages of the basalt place the age of this assemblage at 110 \\mp 1.2 Ma, or late Aptian/early Albian. This deposit contains the oldest known crocodilian remains in the Pacific Realm. The vertebrate-bearing interval lies within a 30 cm mudstone unit overlying lithified fossiliferous limestone and underlying fossiliferous clayey limestone. The surface of the lithified limestone contains fish scales, vertebrate teeth and bones, and a carapace of the ostracod Cytherella. The lower 17 cm of mudstone is the prime vertebrate-bearing layer. It has a fining-upwards grain size trend, and an upward increase in dark coloration. The sand sized fraction is primarily pelletal glauconite, pyrite and fish debris. Limestone clasts up to several mm in diameter occur through the lower portion, whereas the higher portion contains sand laminae. A pristine 1 cm long crocodilian tooth, along with several smaller crocodilian teeth from this interval, attest to the presence of a saltwater crocodilian within the lagoon of this drowned mid-Pacific atoll. Common and varied fish teeth include both slender forms for piercing and grasping mobile prey and blunt flat-topped forms for crushing and grinding hard-shelled bottom living organisms such as oysters. The crushing teeth resemble those of the modern Black Drum fish, a bottom feeder common in shallow coastal environments. Abundant fish scales include both heavy phosphatic ganoid scales, a type present on many Mesozoic fish, and thin flexible scales of a type present on most modern fish. Some teeth and bone fragments are currently unidentified, and may represent vertebrates other than fish or crocodilians. No calcareous fossils are found within this unit. The lower unit grades upwards into a 5 cm thick black organic mudstone consisting of mostly amorphous organic debris, colonial algae, and smaller amounts of terrestrial spores, carbonized plant debris, and amber. No vertebrate remains are observed within the black mudstone. This unit in turn grades upwards into an 8 cm unit of mudstone with a coarsening-upwards grain size trend. This upper 8 cm unit contains only rare vertebrate remains, but has numerous oyster fragments and abundant, well preserved, articulated ostracod shells. The ostracod assemblage consists entirely of Cytherella (Suborder Platycopina). The entire 30 cm unit contains common pyrite, glauconite, and plant debris, and lacks calcareous fossils except in the uppermost part. This, as well as the occurrence of abundant Cytherella indicate sediment deposition in a restricted marine environment with low oxygen conditions. This discovery represents possibly the only known record of mid-Cretaceous reptilian remains from the mid- Pacific region, and the entire fossil assemblage provides valuable data for understanding the history of biotic migrations across the Cretaceous Pacific oceanic island realm. The intercalations of basalt flows with restricted marine and terrestrial sediments can be found not only in this ODP drill core but in others around the Pacific and shows the possibility of future discoveries of this type by scientific drilling of old seamounts.

Pyritic event beds and sulfidized Fe (oxyhydr)oxide aggregates in metalliferous black mudstones of the Paleoproterozoic Talvivaara formation, Finland

NASA Astrophysics Data System (ADS)

Virtasalo, Joonas J.; Laitala, Jaakko J.; Lahtinen, Raimo; Whitehouse, Martin J.

2015-12-01

The Paleoproterozoic, 2.0-1.9 Ga Talvivaara formation of Finland was deposited during the Shunga Event, a worldwide episode of enhanced accumulation of organic-rich sediments in the aftermath of the Lomagundi-Jatuli carbon isotope excursion. Sulfidic carbonaceous mudstones in the Talvivaara formation contain one of the largest known shale-hosted nickel deposits. In order to gain new insight into this Shungian sedimentary environment, sedimentological, petrographical and in situ S and Fe isotopic microanalyses were carried out on samples representing depositional and early-diagenetic conditions. The event-bedded lithology with tidal signatures in the organic-rich mudstones strongly indicates deposition from predominantly river-delivered mud on a highly-productive coastal area, below storm-wave base. The riverine supply of phosphorus, sulfate and iron supported high primary productivity and resulted in strong lateral and vertical chemical gradients in the nearshore waters with a shallow oxic surface layer underlain by euxinic water. The stratigraphic upper part of the Talvivaara formation contains banded intervals of thin alternating pyrite beds and carbonaceous mudstone beds. The pyrite beds were deposited by seaward excursions of the concentrated, acidic Fe-rich river plume subsequent to droughts or dry seasons, which led to intense pyrite precipitation upon mixing with euxinic waters. δ34S and δ56Fe values of the bedded pyrite (median δ34S = - 10.3 ‰ and δ56Fe = - 0.79 ‰) are consistent with the reaction of dissolved Fe(II) with H2S from bacterial sulfate reduction. Organic-rich clayey Fe-monosulfide-bearing granules were transported from the muddy estuary, and enclosed in Fe (oxyhydr)oxide aggregates that were forming by wave and current reworking in nearshore accumulations of river-delivered iron. The isotopic composition of these presently pyrrhotitic inclusions (median δ34S = - 3.3 ‰ and δ56Fe = - 1.6 ‰) indicates microbial iron reduction. The Fe (oxyhydr)oxide aggregates were transported in muddy debris flows to the distal euxinic seafloor. Their Fe (oxyhydr)oxide matrix was replaced by pyrite (median δ34S = + 5.8 ‰ and δ56Fe = + 0.81 ‰) at shallow sediment depths with 34S and 56Fe-enriched porewater. Wavy-crinkly laminae of possible microbial origin developed on the euxinic seafloor during low sedimentation. These results indicate episodic deposition at seasonal to multiannual time scales. δ34S and δ56Fe values in the studied Fe-sulfides provide evidence of microbial isotope fractionation processes and syndepositional and early-diagenetic origin, finding no support for the previously proposed local hydrothermal activity in the Talvivaara mudstones.

Deep-sea fan deposition of the lower Tertiary Orca Group, eastern Prince William Sound, Alaska

USGS Publications Warehouse

Winkler, Gary R.

1976-01-01

The Orca Group is a thick, complexly deformed, sparsely fossiliferous sequence of flysch-like sedimentary and tholeiitic volcanic rocks of middle or late Paleocene age that crops out over an area of. roughly 21,000 km2 in the Prince William Sound region and the adjacent Chugach Mountains. The Orca Group also probably underlies a large part of the Gulf of Alaska Tertiary province and the continental shelf south of the outcrop belt; coextensive rocks to the southwest on Kodiak Island are called the Ghost Rocks and Sitkalidak Formations. The Orca Group was pervasively faulted, tightly folded, and metamorphosed regionally to laumontite and prehnite-pumpellyite facies prior to, and perhaps concurrently with, intrusion of early Eocene granodiorite and quartz monzonite plutons. In eastern Prince William Sound, 95% of the Orca sedimentary rocks are interbedded feldspathic and lithofeldspathic sandstone, siltstone, and mudstone turbidites. Lithic components vary widely in abundance and composition, but labile sedimentary and volcanic grains dominate. A widespread yet minor amount of the mudstone is hemipelagic or pelagic, with scattered foraminifers. Pebbly mudstone with rounded clasts of exotic lithologies and locally conglomerate with angular blocks of deformed sandstone identical to the enclosing matrix are interbedded with the turbidites. Thick and thin tabular bodies of altered tholeiitic basalt are locally and regionally conformable with the sedimentary rocks, and constitute 15-20% of Orca outcrops in eastern Prince William Sound. The basalt consists chiefly of pillowed and nonpillowed flows, but also includes minor pillow breccia, tuff, and intrusive rocks. Nonvolcanic turbidites are interbedded with the basalt; lenticular bioclastic limestone, red and green mudstone, chert, and conglomerate locally overlie the basalt, but are supplanted upward by turbidites. From west to east, basalts within the Orca Group become increasingly fragmental and amygdaloidal. Such textural changes probably indicate shallower water to the east. A radial distribution of paleocurrents and distinctive associations of turbidite facies within the sedimentary rocks suggest that the Orca Group in eastern Prince William Sound was deposited on a westward-sloping, complex deep-sea fan. Detritus was derived primarily from 'tectonized' sedimentary, volcanic, and plutonic rocks. Coeval submarine volcanism resulted in intercalation of basalt within prisms of terrigenous sediment.

Study of Sedimentary Outcrop of Semanggol Formation with the Correlation of Geology, Geotechnical and Geophysics Technique

NASA Astrophysics Data System (ADS)

Nordiana, A. N.; Nordiana, M. M.; Jia, Teoh Ying; Hisham, Hazrul; Sulaiman, Nabila; Maslinda, Umi; Taqiuddin, Z. M.; Nur Amalina, M. K. A.; Afiq Saharudin, Muhamad

2017-04-01

The study location was at Bukit Kukus, Kuala Ketil, Kedah, Malaysia where the geological outcrop of this Semanggol Formation comprises of chert, mudstone, and volcanic tuff. The study was conducted using two geophysical methods, which are 2-D Resistivity and Ground Penetrating Radar (GPR). The objectives of the study are to correlate both of the geophysical methods through the value of conductivity and to identify the physical properties of rocks through the value of porosity and permeability. The data acquisition for both methods was conducted on the same line. For 2-D Resistivity method, the length of the line is 60 m with 1.5 m electrode spacing and the array used was Wenner-Schlumberger. For GPR method, the survey line was on top of the resistivity line, and the frequency of the antenna used is 250 MHz. A good correlation exists between both of the GPR signature and contour maps for resistivity from the surfer 10 software with the outcrop feature. Conductivity value from both GPR and Resistivity method was compared and the range value of conductivity obtained from GPR method almost equivalent with Resistivity method based on derivation and calculation for the sedimentary rocks, which are 0.037 to 0.574 miliSiemens per metre (mS/m) for chert and 0.186 to 10.142 miliSiemens per metre (mS/m) for mudstone. Two types of rock samples were taken, and several geotechnical tests were conducted, but only the value of permeability, K and porosity, ɸ of chert can be calculated, which are 1.95E-22 m2 (original condition) and 2.27E-22 m2 (dry condition) and 3 percent respectively as the sample of mudstone was damaged. The parameter of the 2-D resistivity method derived from Archie’s law was used to calculate the porosity, ɸf value using the Formation Factor equation. The range values of porosity, ɸf for chert mostly in the range of 5 to 25 percent, which is 6.26 to 13.36 percent but slightly out of range for mudstone, which is 14.12 to 36.02 percent.

ChemCam at Gale Crater: Highlights and Discoveries from Three Years of Chemical Measurements on Mars

NASA Astrophysics Data System (ADS)

Blaney, Diana L.; Wiens, Roger; Maurice, Sylvestre; Gasnault, Olivier; Anderson, Ryan; Bridges, John; Bridges, Nathan; Clegg, Samuel; Clark, Benton; Ehlmann, Bethany; Dyar, Melinda D.; Fisk, Martin; Francis, Raymond; Fabre, Cecile; Forni, Olivier; Frydenvang, Jens; Johnson, Jeffery; Lanza, Nina; Leveille, Richard; Lasue, Jeremie; Le Deit, Laetitia; Mangold, Nicholas; Melikechi, Noureddine; Nachon, Marion; Newsom, Horton; Payre, Valerie; Rapin, William; Sautter, Violane; Vaniman, David; Grotzinger, John; Vasavad, Ashwin; Crisp, Joy

2015-11-01

ChemCam has undertaken a detailed chemical investigation of the rocks and soils at Gale crater over the last three years with over six thousand separate geochemical measurements. Recent recalibration of the ChemCam data using a new library of >350 geochemical standards has enabled increased elemental accuracies over a wider compositional range. The increased accuracy combined with ChemCam’s small spot size allows for the chemistry of mineral end members including feldspars, high silica, oxide rich grains to be identified. ChemCam has observed both sedimentary and igneous compositions. Igneous compositions are generally present in conglomerates and in float rocks. Compositions show a wide range of igneous chemistry ranging from basaltic to feldspar rich assemblages.Sedimentary rocks have a wide range of compositions reflecting both differences in chemical source regions and in depositional and diagenetic histories. The “Sheepbed” mudstones cluster around Martian average crustal compositions. The “Kimberley” outcrop showed enhanced potassium reaching concentrations up to ~6 wt% K2O. More recent observations in the Murray Formation at the base of Mt. Sharp reveal mudstones that are lower in magnesium and higher in silica and aluminum than the more basaltic mudstones previously investigated. Extremely high silica (75-85 wt%) deposits have also been identified. The high silica observations were associated with increased TiO2, While the Murray mudstones are generally low in magnesium, local enhancements in magnesium have also been noted associated with resistant facies in the outcrop. Chemical trends also indicate that iron oxide phases may also be present as cements. Sandstone facies with a mafic composition are also present. Veins in the unit also show a wide range of compositions indicating fluid chemistries rich in calcium sulfate, fluorine, magnesium and iron were present. Vein chemistry could be the result of distinct fluids migrating through from a distance with a pre-established chemical signature, fluids locally evolved from water rock interactions, or both. Thus the chemical relationships between the Pahrump bedrock and the veins’ chemistry can be used to constrain the origin of the fluids.

Organic matter preserved in 3-billion-year-old mudstones at Gale crater, Mars

NASA Astrophysics Data System (ADS)

Eigenbrode, Jennifer L.; Summons, Roger E.; Steele, Andrew; Freissinet, Caroline; Millan, Maëva; Navarro-González, Rafael; Sutter, Brad; McAdam, Amy C.; Franz, Heather B.; Glavin, Daniel P.; Archer, Paul D.; Mahaffy, Paul R.; Conrad, Pamela G.; Hurowitz, Joel A.; Grotzinger, John P.; Gupta, Sanjeev; Ming, Doug W.; Sumner, Dawn Y.; Szopa, Cyril; Malespin, Charles; Buch, Arnaud; Coll, Patrice

2018-06-01

Establishing the presence and state of organic matter, including its possible biosignatures, in martian materials has been an elusive quest, despite limited reports of the existence of organic matter on Mars. We report the in situ detection of organic matter preserved in lacustrine mudstones at the base of the ~3.5-billion-year-old Murray formation at Pahrump Hills, Gale crater, by the Sample Analysis at Mars instrument suite onboard the Curiosity rover. Diverse pyrolysis products, including thiophenic, aromatic, and aliphatic compounds released at high temperatures (500° to 820°C), were directly detected by evolved gas analysis. Thiophenes were also observed by gas chromatography–mass spectrometry. Their presence suggests that sulfurization aided organic matter preservation. At least 50 nanomoles of organic carbon persists, probably as macromolecules containing 5% carbon as organic sulfur molecules.

SAM-Like Evolved Gas Analyses of Phyllosilicate Minerals and Applications to SAM Analyses of the Sheepbed Mudstone, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

McAdam, A. C.; Franz, H. B.; Mahaffy, P. R.; Eigenbrode, J. L.; Stern, J. C.; Brunner, B.; Sutter, B.; Archer, P. D.; Ming , D. W.; Morris, R. V.;

Impact of silica diagenesis on the porosity of fine-grained strata: An analysis of Cenozoic mudstones from the North Sea

NASA Astrophysics Data System (ADS)

Wrona, Thilo; Taylor, Kevin G.; Jackson, Christopher A.-L.; Huuse, Mads; Najorka, Jens; Pan, Indranil

2017-04-01

Silica diagenesis has the potential to drastically change the physical and fluid flow properties of its host strata and therefore plays a key role in the development of sedimentary basins. The specific processes involved in silica diagenesis are, however, still poorly explained by existing models. This knowledge gap is addressed by investigating the effect of silica diagenesis on the porosity of Cenozoic mudstones of the North Viking Graben, northern North Sea through a multiple linear regression analysis. First, we identify and quantify the mineralogy of these rocks by scanning electron microscopy and X-ray diffraction, respectively. Mineral contents and host rock porosity data inferred from wireline data of two exploration wells are then analyzed by multiple linear regressions. This robust statistical analysis reveals that biogenic opal-A is a significant control and authigenic opal-CT is a minor influence on the porosity of these rocks. These results suggest that the initial porosity of siliceous mudstones increases with biogenic opal-A production during deposition and that the porosity reduction during opal-A/CT transformation results from opal-A dissolution. These findings advance our understanding of compaction, dewatering, and lithification of siliceous sediments and rocks. Moreover, this study provides a recipe for the derivation of the key controls (e.g., composition) on a rock property (e.g., porosity) that can be applied to a variety of problems in rock physics.

The 1997 core drilling through Ordovician and Silurian strata at Röstånga, S. Sweden: preliminary stratigraphic assessment and regional comparison

USGS Publications Warehouse

Bergstrom, Stig M.; Huff, W.D.; Koren', T.; Larsson, K.; Ahlberg, P.; Kolata, Dennis R.

1999-01-01

A core drilling at Ro??sta??nga, the first such drilling ever undertaken in this classical Lower Paleozoic outcrop area in W-central Scania, penetrated an approximately 96 m thick succession of Lower Silurian-upper Middle Ordovician marine rocks. The drilling was stopped at a depth of 132.59 m in an interval of crushed rocks, probably a prominent fault zone, that proved impossible to drill through. The core contains a stratigraphical sequence from the basal Upper Llandoverian (Telychian Stage) to the upper Middle Ordovician (Harjuan Stage). The following units are recognized in descending stratigraphic order (approximate thickness in parenthesis): Kallholn Formation (35 m), Lindega??rd Mudstone (27 m), Fja??cka Shale (13 m), Mossen Formation (0.75 m), Skagen Formation (2.5 m), and Sularp Shale (19 m+). Except for the Skagen Formation, the drilled sequence consists of shales and mudstones with occasional thin limestone interbeds and is similar to coeval successions elsewhere in Scania. There are 11 K-bentonite beds in the Kallholn Formation, 2(3?) in the Lindega??rd Mudstone, 1 in the Mossen Formation, 7 in the Skagen Formation, and 33 in the Sularp Shale. The core serves as an excellent Lower Silurian-upper Middle Ordovician reference standard not only for the Ro??sta??nga area but also for southernmost Sweden in general because the cored sequence is the stratigraphically most complete one known anywhere in this region.

Overpressure and consolidation near the seafloor of Brazos-Trinity Basin IV, northwest deepwater Gulf of Mexico

NASA Astrophysics Data System (ADS)

Schneider, Julia; Flemings, Peter B.; Dugan, Brandon; Long, Hui; Germaine, John T.

2009-05-01

Pore water overpressures (u*) within mudstones beneath Brazos-Trinity Basin IV (deepwater Gulf of Mexico, offshore Texas) are greater than 70% of the hydrostatic vertical effective stress (σ'vh) [λ* = 0.7 = (u*/σ'vh)]. These results are compatible with recent observations that suggest sedimentation rates in this region are rapid (6 mm/a). We compare the petrophysical properties and pore pressures within a 127-m-thick package of mudstone penetrated at two locations: Integrated Ocean Drilling Program (IODP) sites U1319 and U1320. Site U1319 is at the margin of Brazos-Trinity Basin IV, whereas Site U1320 lies at its center, beneath 180 m of turbidite fill. Experimentally derived preconsolidation stresses and an in situ pore pressure measurement record overpressure at Site U1319 and Site U1320 (λ* ˜ 0.2 to 0.8 and λ* ˜ 0.8, respectively). We use these data to define an average vertical effective stress gradient. Assuming that void ratio (e) is proportional to the log of vertical effective stress (σ'v), we predict pore pressures (u) throughout the mudstone at both sites using bulk density data. Overpressures are greater at Site U1320 due to rapid deposition of the overlying turbidites. However, a large fraction of the overpressure induced by the turbidite load applied at Site U1320 has dissipated by drainage into the overlying basin fill. High overpressures near the seafloor drive shallow fluid flow, reduce slope stability, and may explain large submarine landslides.

Conservatism of Late Pennsylvanian vegetational patterns during short-term cyclic and long-term directional environmental change, western equatorial Pangea

PubMed Central

TABOR, NEIL J.; ROMANCHOCK, CHARLES M.; LOOY, CYNTHIA V.; HOTTON, CAROL L.; DIMICHELE, WILLIAM A.; CHANEY, DAN S.

2014-01-01

Patterns of plant distribution by palaeoenvironment were examined across the Pennsylvanian–Permian transition in North–Central Texas. Stratigraphically recurrent packages of distinct lithofacies, representing different habitats, contain qualitatively and quantitatively different macrofloras and microfloras. The species pools demonstrate niche conservatism, remaining closely tied to specific habitats, during both short-term cyclic environmental change and a long-term trend of increasing aridity. The deposits examined principally comprise the terrestrial Markley and its approximate marine equivalent, the Harpersville Formation and parts of lower Archer City Formation. Fossiliferous deposits are lens-like, likely representing fill sequences of channels formed during abandonment phases. Palaeosols, represented by blocky mudstones, comprise a large fraction of the deposits. They suggest progressive climate change from minimally seasonal humid to seasonal subhumid to seasonal dry subhumid. Five lithofacies yielded plants: kaolinite-dominated siltstone, organic shale, mudstone beds within organic shale, coarsening upward mudstone–sandstone interbeds and channel sandstone. Both macro- and microflora were examined. Lithofacies proved compositionally distinct, with different patterns of dominance diversity. Organic shales (swamp deposits), mudstone partings (swamp drainages) and coarsening upward mudstone–sandstone interbeds (floodplains) typically contain Pennsylvanian wetland vegetation. Kaolinite-dominated siltstones and (to the extent known) sandstones contain taxa indicative of seasonally dry substrates. Some kaolinite-dominated siltstones and organic shales/coals yielded palynomorphs. Microfloras are more diverse, with greater wetland–dryland overlap than macrofloras. It appears that these two floras were coexistent at times on the regional landscape. PMID:25339793

Clay mineral diversity and abundance in sedimentary rocks of Gale crater, Mars.

PubMed

Bristow, Thomas F; Rampe, Elizabeth B; Achilles, Cherie N; Blake, David F; Chipera, Steve J; Craig, Patricia; Crisp, Joy A; Des Marais, David J; Downs, Robert T; Gellert, Ralf; Grotzinger, John P; Gupta, Sanjeev; Hazen, Robert M; Horgan, Briony; Hogancamp, Joanna V; Mangold, Nicolas; Mahaffy, Paul R; McAdam, Amy C; Ming, Doug W; Morookian, John Michael; Morris, Richard V; Morrison, Shaunna M; Treiman, Allan H; Vaniman, David T; Vasavada, Ashwin R; Yen, Albert S

2018-06-01

Clay minerals provide indicators of the evolution of aqueous conditions and possible habitats for life on ancient Mars. Analyses by the Mars Science Laboratory rover Curiosity show that ~3.5-billion year (Ga) fluvio-lacustrine mudstones in Gale crater contain up to ~28 weight % (wt %) clay minerals. We demonstrate that the species of clay minerals deduced from x-ray diffraction and evolved gas analysis show a strong paleoenvironmental dependency. While perennial lake mudstones are characterized by Fe-saponite, we find that stratigraphic intervals associated with episodic lake drying contain Al-rich, Fe 3+ -bearing dioctahedral smectite, with minor (3 wt %) quantities of ferripyrophyllite, interpreted as wind-blown detritus, found in candidate aeolian deposits. Our results suggest that dioctahedral smectite formed via near-surface chemical weathering driven by fluctuations in lake level and atmospheric infiltration, a process leading to the redistribution of nutrients and potentially influencing the cycling of gases that help regulate climate.

Monitoring the Vertical Distribution of Rainfall-Induced Strain Changes in a Landslide Measured by Distributed Fiber Optic Sensing With Rayleigh Backscattering

NASA Astrophysics Data System (ADS)

Kogure, Tetsuya; Okuda, Yudai

2018-05-01

Distributed fiber optic sensing with Rayleigh backscattering, which has been recognized as a novel technique for measuring differences in temperature or strain, was adopted in a borehole to a depth of 16 m in an actual landslide to detect a vertical profile of strain changes. Strain changes were measured every 6 hr from 19 June 2017 to 18 October 2017 with a spatial resolution of 10 cm and strain resolution of 1.87 μɛ. The measurements provided a clear-cut vertical profile of the strain changes caused by rainfalls that cannot be detected by conventional methods. The results show that there are two types of deformation in the landslide mass: (1) sliding at the boundary between tuff and mudstone and (2) creep in mudstone layers. Activation of deeper sections of the landslide by heavy rainfalls has also been detected.

Facies Distribution and Petrophysical Properties of Shoreface-Offshore Transition Environment in Sandakan Formation, NE Sabah Basin

NASA Astrophysics Data System (ADS)

Majid, M. Firdaus A.; Suhaili Ismail, M.; Rahman, A. Hadi A.; Azfar Mohamed, M.

2017-10-01

Newly exposed outcrop of Miocene shallow marine sandstone in Sandakan Formation, allows characterization of the facies distribution and petrophysical properties of shoreface to offshore transition environment. Six facies are defined: (1) Poorly bioturbated Hummocky Cross Stratified (HCS) sandstone (F1), (2) Moderately bioturbated HCS sandstone (F2), (3) Well bioturbated HCS sandstone (F3), (4) Poorly bioturbated Swaley Cross Stratified (SCS) sandstone (F4), (5) Interbedded HCS sandstone with sand-silt mudstone, (6) Heterolithic mudstone. The sedimentary successions were deposited in upper to lower shoreface, and offshore transition environment. Facies F3, F4 and F5 shows good reservoir quality with good porosity and fair permeability values from 20% to 21% and 14 mD to 33 mD respectively. While Facies F1 exhibits poor reservoir quality with low permeability values 3.13 mD.

Correlative microscopy of the constituents of a dinosaur rib fossil and hosting mudstone: Implications on diagenesis and fossil preservation.

PubMed

Kim, Jung-Kyun; Kwon, Yong-Eun; Lee, Sang-Gil; Kim, Chang-Yeon; Kim, Jin-Gyu; Huh, Min; Lee, Eunji; Kim, Youn-Joong

2017-01-01

We have applied correlative microscopy to identify the key constituents of a dorsal rib fossil from Koreanosaurus boseongensis and its hosting mudstone discovered at the rich fossil site in Boseong, South Korea, to investigate the factors that likely contributed to diagenesis and the preservation of fossil bone. Calcite and illite were the commonly occurring phases in the rib bone, hosting mudstone, and the boundary region in-between. The boundary region may have contributed to bone preservation once it fully formed by acting as a protective shell. Fluorapatite crystals in the rib bone matrix signified diagenetic alteration of the original bioapatite crystals. While calcite predominantly occupied vascular channels and cracks, platy illite crystals widely occupied miniscule pores throughout the bone matrix. Thorough transmission electron microscopy (TEM) study of illite within the bone matrix indicated the solid-state transformation of 1M to 2M without composition change, which was more evident from the lateral variation of 1M to 2M within the same layer. The high level of lattice disordering of 2M illite suggested an early stage of 1M to 2M transformation. Thus, the diagenetic alteration of both apatite and illite crystals within the bone matrix may have increased its overall density, as the preferred orientation of apatite crystals from moderate to strong degrees was evident despite the poor preservation of osteohistological features. The combined effects of rapid burial, formation of a boundary region, and diagenesis of illite and apatite within the bone matrix may have contributed to the rib bone preservation.

The Shale Gas potential of Lower Carboniferous Sediments in Germany

NASA Astrophysics Data System (ADS)

Kerschke, D.; Mihailovic, A.; Schulz, H., -M.; Horsfield, B.

2012-04-01

Organic-rich Carboniferous sediments are proven source rocks for conventional gas systems in NW Europe and are likely gas shale candidates. Within the framework of GeoEnergie, an initiative to strengthen scientific excellence, funded by the German Ministry of Education and Research (BMBF), the influence of palaeogeography and basin dynamics on sedimentology and diagenesis is being investigated. Our aim is to unravel the evolution of shale gas-relevant properties which control gas prospectivity and production parameters like porosity, brittleness, etc. for the Lower Carboniferous in Germany. Northern Germany is underlain by thick, mudstone-bearing Carboniferous successions with a wide range of thermal maturities. Some of these mudstone horizons are rich in organic carbon which is either of marine and/or terrigenous origin. During the Carboniferous deposition of fine-grained, TOC-rich basinal sediments changed into shallow marine to paralic siliciclastic sediments (carbonates during the Lower Carboniferous) in the north, and grade into coarse-grained sediments close to the uprising Variscan mountains in the south. As a result different architectural elements including TOC-rich fine-grained sediments like basinal shales, fine-grained parts of turbidites, and shallow marine mudstones occur in both the Lower and the Upper Carboniferous section. A high shale gas potential occurs in basinal shales of Namurian age with marine organic material and TOC contents of up to 8 % (Rhenish Alum Shales). Such sediments with thermal maturities between 1.3 to 3.0 % vitrinite reflectance and sufficient quartz contents occur in wide areas of present-day Central European Basins System (CEBS), and are at favourable depth for shale gas exploration predominantly along the southern CEBS margin.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hamlin, H.S.; Dutton, S.P.; Tyler, N.

The Tirrawarra Sandstone contains 146 million bbl of oil in Tirrawarra field in the Cooper basin of South Australia. We used core, well logs, and petro-physical data to construct a depositional-facies-based flow-unit model of the reservoir, which describes rock properties and hydrocarbon saturations in three dimensions. Using the model to calculate volumes and residency of original and remaining oil in place, we identified an additional 36 million bbl of oil in place and improved understanding of past production patterns. The Tirrawarra Sandstone reservoir was deposited in a Carboniferous-Permian proglacial intracratonic setting and is composed of lacustrine and fluvial facies assemblages.more » The stratigraphic framework of these nonmarine facies is defined by distinctive stacking patterns and erosional unconformities. Mudstone dominated zones that are analogous to marine maximum flooding surfaces bound the reservoir. At its base a progradational lacustrine-delta system, composed of lenticular mud-clast-rich sandstones enclosed in mudstone, is truncated by an unconformity. Sandstones in these lower deltaic facies lost most of their porosity by mechanical compaction of ductile grains. Sediment reworking by channel migration and locally shore-zone processes created by quartz-rich, multilateral sandstones, which retained the highest porosity and permeability of all the reservoir facies and contained most of the original oil in place. Braided-channel sandstones, however, are overlain by lenticular meandering-channel sandstones, which in turn grade upward into widespread mudstones and coals. Thus, this uppermost part of the reservoir displays a retrogradational stacking pattern and upward-decreasing reservoir quality. Our results demonstrate that depositional variables are the primary controls on reservoir quality and productivity in the Tirrawarra Sandstone.« less

Conditioning geostatistical simulations of a heterogeneous paleo-fluvial bedrock aquifer using lithologs and pumping tests

NASA Astrophysics Data System (ADS)

Niazi, A.; Bentley, L. R.; Hayashi, M.

2016-12-01

Geostatistical simulations are used to construct heterogeneous aquifer models. Optimally, such simulations should be conditioned with both lithologic and hydraulic data. We introduce an approach to condition lithologic geostatistical simulations of a paleo-fluvial bedrock aquifer consisting of relatively high permeable sandstone channels embedded in relatively low permeable mudstone using hydraulic data. The hydraulic data consist of two-hour single well pumping tests extracted from the public water well database for a 250-km2 watershed in Alberta, Canada. First, lithologic models of the entire watershed are simulated and conditioned with hard lithological data using transition probability - Markov chain geostatistics (TPROGS). Then, a segment of the simulation around a pumping well is used to populate a flow model (FEFLOW) with either sand or mudstone. The values of the hydraulic conductivity and specific storage of sand and mudstone are then adjusted to minimize the difference between simulated and actual pumping test data using the parameter estimation program PEST. If the simulated pumping test data do not adequately match the measured data, the lithologic model is updated by locally deforming the lithology distribution using the probability perturbation method and the model parameters are again updated with PEST. This procedure is repeated until the simulated and measured data agree within a pre-determined tolerance. The procedure is repeated for each well that has pumping test data. The method creates a local groundwater model that honors both the lithologic model and pumping test data and provides estimates of hydraulic conductivity and specific storage. Eventually, the simulations will be integrated into a watershed-scale groundwater model.

Organic molecules in the Sheepbed Mudstone, Gale Crater, Mars

PubMed Central

Freissinet, C; Glavin, D P; Mahaffy, P R; Miller, K E; Eigenbrode, J L; Summons, R E; Brunner, A E; Buch, A; Szopa, C; Archer, P D; Franz, H B; Atreya, S K; Brinckerhoff, W B; Cabane, M; Coll, P; Conrad, P G; Des Marais, D J; Dworkin, J P; Fairén, A G; François, P; Grotzinger, J P; Kashyap, S; ten Kate, I L; Leshin, L A; Malespin, C A; Martin, M G; Martin-Torres, F J; McAdam, A C; Ming, D W; Navarro-González, R; Pavlov, A A; Prats, B D; Squyres, S W; Steele, A; Stern, J C; Sumner, D Y; Sutter, B; Zorzano, M-P

2015-01-01

The Sample Analysis at Mars (SAM) instrument on board the Mars Science Laboratory Curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of Mars at Gale Crater. Central to this task is the development of an inventory of any organic molecules present to elucidate processes associated with their origin, diagenesis, concentration, and long-term preservation. This will guide the future search for biosignatures. Here we report the definitive identification of chlorobenzene (150–300 parts per billion by weight (ppbw)) and C2 to C4 dichloroalkanes (up to 70 ppbw) with the SAM gas chromatograph mass spectrometer (GCMS) and detection of chlorobenzene in the direct evolved gas analysis (EGA) mode, in multiple portions of the fines from the Cumberland drill hole in the Sheepbed mudstone at Yellowknife Bay. When combined with GCMS and EGA data from multiple scooped and drilled samples, blank runs, and supporting laboratory analog studies, the elevated levels of chlorobenzene and the dichloroalkanes cannot be solely explained by instrument background sources known to be present in SAM. We conclude that these chlorinated hydrocarbons are the reaction products of Martian chlorine and organic carbon derived from Martian sources (e.g., igneous, hydrothermal, atmospheric, or biological) or exogenous sources such as meteorites, comets, or interplanetary dust particles. Key Points First in situ evidence of nonterrestrial organics in Martian surface sediments Chlorinated hydrocarbons identified in the Sheepbed mudstone by SAM Organics preserved in sample exposed to ionizing radiation and oxidative condition PMID:26690960

Organic molecules in the Sheepbed Mudstone, Gale Crater, Mars.

PubMed

Freissinet, C; Glavin, D P; Mahaffy, P R; Miller, K E; Eigenbrode, J L; Summons, R E; Brunner, A E; Buch, A; Szopa, C; Archer, P D; Franz, H B; Atreya, S K; Brinckerhoff, W B; Cabane, M; Coll, P; Conrad, P G; Des Marais, D J; Dworkin, J P; Fairén, A G; François, P; Grotzinger, J P; Kashyap, S; Ten Kate, I L; Leshin, L A; Malespin, C A; Martin, M G; Martin-Torres, F J; McAdam, A C; Ming, D W; Navarro-González, R; Pavlov, A A; Prats, B D; Squyres, S W; Steele, A; Stern, J C; Sumner, D Y; Sutter, B; Zorzano, M-P

2015-03-01

The Sample Analysis at Mars (SAM) instrument on board the Mars Science Laboratory Curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of Mars at Gale Crater. Central to this task is the development of an inventory of any organic molecules present to elucidate processes associated with their origin, diagenesis, concentration, and long-term preservation. This will guide the future search for biosignatures. Here we report the definitive identification of chlorobenzene (150-300 parts per billion by weight (ppbw)) and C 2 to C 4 dichloroalkanes (up to 70 ppbw) with the SAM gas chromatograph mass spectrometer (GCMS) and detection of chlorobenzene in the direct evolved gas analysis (EGA) mode, in multiple portions of the fines from the Cumberland drill hole in the Sheepbed mudstone at Yellowknife Bay. When combined with GCMS and EGA data from multiple scooped and drilled samples, blank runs, and supporting laboratory analog studies, the elevated levels of chlorobenzene and the dichloroalkanes cannot be solely explained by instrument background sources known to be present in SAM. We conclude that these chlorinated hydrocarbons are the reaction products of Martian chlorine and organic carbon derived from Martian sources (e.g., igneous, hydrothermal, atmospheric, or biological) or exogenous sources such as meteorites, comets, or interplanetary dust particles. First in situ evidence of nonterrestrial organics in Martian surface sediments Chlorinated hydrocarbons identified in the Sheepbed mudstone by SAM Organics preserved in sample exposed to ionizing radiation and oxidative condition.

Sedimentology of the lower part of the Upper Triassic Chinle Formation and its relationship to uranium deposits, White Canyon area, southeastern Utah

USGS Publications Warehouse

Dubiel, Russell F.

1983-01-01

Closely spaced measured stratigraphic sections of the lower part of the Late Triassic Chinle Formation in the White Canyon area of southeastern Utah depict a fluvial-deltaic-lacustrine depositional sequence that hosts uranium deposits in basal fluvial sandstones. The basal Shinarump Member consists of predominantly trough-crossbedded, coarse-grained sandstone and minor gray, carbonaceous mudstone and is interpreted as a valley-fill sequence overlain by deposits of a braided stream system. The overlying Monitor Butte Member is composed of cyclic- and foreset-bedded siltstone, sandstone, and mudstone and is interpreted as a succession of low-energy fluvial, deltaic and orqanicrich, lacustrine-marsh sediments. The overlying Moss Back Member is composed of a laterally extensive, coarse- to medium-grained, conglomeratic sandstone and is interpreted as a braided-stream system that flowed north to northwest. The entire sequence was deposited in response to changes in local base level associated with a large lake that lay to the west. Isopachs of lithofacies indicate distinct lacustrine basins and a correspondence between these facies and modern structural synclines. Facies changes and coincidence of isopach thicks suggest that structural synclines were active in the Late Triassic and influenced the pattern of sediment distribution within the basins. Uranium mineralization appears to be related to certain low-energy depositional environments in that uranium is localized in fluvial sandstones that lie beneath organic-rich lacustrine-marsh mudstones and carbonaceous delta-front sediments. The reducing environment preserved in these facies may have played an important role in the localization of uranium.

Mars Science Laboratory's rover, Curiosity: Ongoing investigations into the habitability of Mars

NASA Astrophysics Data System (ADS)

Meyer, Michael; Vasavada, Ashwin

2015-11-01

NASA’s Curiosity rover has the objective to determine whether Mars was habitable. The rover’s science team has achieved that and more, including two major firsts in planetary science. First, Gale Crater was determined to once have an aqueous environment and able to support microbial life, evidenced by conglomerates and the detailed analyses of the drill samples [1]. Second, the age dating of rock on another planet - radiogenic and cosmogenic noble gases in a mudstone yielded a K-Ar age of 4.21 ± 0.35 Ga while 3He, 21Ne, and 36Ar yielded surface exposure ages of 78 ± 30 Ma [2], suggesting the potential to find rocks whose organic content has not yet been destroyed by cosmic rays. Indeed, organic compounds have been found in samples from the Sheepbed mudstone [3]. Reports of plumes of methane in the martian atmosphere have defied explanation to date. Curiosity measured a constant background level of atmospheric methane with a mean value of 0.69 ± 0.25 ppbv, consistent with methane released from the degradation of interplanetary dust and meteorites. However, in four consecutive measurements spanning two months, the rover measured a ten-fold increase (7.2 ± 2.1 ppbv), suggesting that methane was actively added from an unknown source [3]. Periodic measurements will continue, perhaps revealing the possible sources of high methane, whether biological or abiological. Enhancing our concept of Mars’ capability to support life, the Curiosity rover has detected nitrogen-bearing compounds of 110-300 ppm of nitrate in scooped sand, and 70-1,100 ppm of nitrate in drilled mudstone. Discovery of martian nitrogen has important implications for a nitrogen cycle at some point in martian history [4]. More recent exploration has focused on the investigation of a mudstone-sandstone geologic contact, high Si and H abundances, and organics. These and the latest results from Curiosity will be discussed, exploring the transition of Mars from a habitable world to the desert planet it is today. [1] Grotzinger, et al. Science 343: 388 (2014), [2] Farley, et al. Science 343: 389 (2014), [3] Feissinet et al. JGR, 120: 495-514 (2015), [3] Webster, et al., Science, 347: 415-427 (2015), [4] Stern, et al., PNAS 112: 4245-4250 (2015).

Algal blooms and "Marine snow": Mechanisms that enhance preservation of organic carbon in ancient fine-grained sediments

USGS Publications Warehouse

Macquaker, Joe H.S.; Keller, Margaret A.; Davies, Sarah J.

2010-01-01

Combined petrographic and geochemical methods are used to investigate the microfabrics present in thin sections prepared from representative organic carbon-rich mudstones collected from three successions (the Kimmeridge Clay Formation, the Jet Rock Member of the Whitby Mudstone Formation, and the pebble shale and Hue Shale). This study was initiated to determine how organic carbon-rich materials were being delivered to the sediment–water interface, and what happened to them after deposition, prior to deep burial.Analyses of the fabrics present shows that they exhibit many common attributes. In particular they are all: (1) highly heterogeneous on the scale of a thin section, (2) organized into thin beds (< 10 mm thick) composed mainly of mineral mixtures of fine-grained siliciclastic detritus and carbonate materials, and (3) contain significant concentrations of organic carbon, much of which is organized into laminasets that contain abundant organomineralic aggregates and pellets. In addition, framboidal pyrite (range of sizes from < 20 μm to < 1 μm) and abundant agglutinated foraminifers are present in some units. The individual beds are commonly sharp-based and overlain by thin, silt lags. The tops of many of the beds have been homogenized and some regions of the pelleted laminasets contain small horizontal burrows.The organomineralic aggregates present in these mudstones are interpreted to be ancient examples of marine snow. This marine snow likely formed in the water column, particularly during phytoplankton blooms, and was then transported rapidly to the seafloor. The existence of the thin beds with homogenized tops and an in-situ infauna indicates that between blooms there was sufficient oxygen and time for a mixed layer to develop as a result of sediment colonization by diminutive organisms using either aerobic or dysaerobic metabolic pathways. These textures suggest that the constituents of these mudstones were delivered neither as a continuous rain of sediment nor were the bottom waters persistently anoxic. In addition, the presence of thin lags and sharp-based beds suggests that the seafloor was being episodically reworked during deposition. These fabrics indicate that conditions in the water columns and at the seafloors while these rocks were being deposited were very dynamic, and episodic fluxes of high concentrations of organic carbon to the seafloor, during phytoplankton blooms, likely enhanced preservation of organic carbon.

Chemical Composition of Diagenetic Features at Lower Aeolis Mons, Mars as Measured by Curiosity's APXS

NASA Astrophysics Data System (ADS)

Berger, J. A.; Schmidt, M. E.; Gellert, R.; Boyd, N.; Campbell, J. L.; Desouza, E.; Fisk, M. R.; Perrett, G. M.; Thompson, L. M.; VanBommel, S.; Yen, A. S.

2015-12-01

Curiosity's APXS investigation of the Murray Fm. (sols 755 - 950) at lower Aeolis Mons (Mt. Sharp) in Gale Crater, Mars has revealed (Mg, Ni)-sulfate diagenetic features and dark gray Ca-rich veins. The (Mg, Ni)-sulfate features occur as ~2 cm wide dendritic and botryoidal concretions that stand out in relief ~1 cm above the mudstone surface. APXS rasters over the features (Moenkopi, Mammoth, Morrison, Rosamond, Potatoe; sols 758 - 810) resulted in 1:1 molar variation of S and Mg consistent with a MgSO4 phase. The sulfate is not pure; the features are a mixture of 10 - 15% MgSO4 with the host mudstone. This mixture suggests the sulfates precipitated within pre-existing pore spaces, or were partially dissolved and replaced by sediment, preserving the crystal morphology. The sulfate features are enriched in Ni (2000 - 4250 ppm), indicating Ni-sulfate. The Murray Fm. mudstones that host the diagenetic features range to high SiO2 (60-73 wt%) and have bulk elemental signatures that are consistent with alteration by acid leaching. Low MgO (3.0 wt%) and low Ni (100 - 300 ppm) in the most apparently altered (highest SiO2) mudstones may link the acidic alteration with the fluids that formed the (Mg, Ni)-sulfates. Diagenetic Ca-sulfate-bearing veins that were abundant across Aeolis Palus persist at lower Aeolis Mons. A new vein type containing dark gray material as a separate crystalline phase within white Ca-sulfate veins was discovered in a cluster of veins in the Murray Fm. (Coalville, Alvord Mt., Amboy; sols 930 - 948). APXS rasters of the dark-toned material indicate high CaO (20 - 30 wt%) without concomitant increases in SO3. Ge (up to 650 ppm; 6.5X surrounding bedrock) and MnO (up to 1.0 wt%; 4X surrounding bedrock) are both enriched in the dark veins. These chemical observations are consistent with fluorite, although F (L.O.D. >5%) is not detectable in APXS spectra. The diagenetic features indicate that Ca, Mg, and Ni were mobilized with S in aqueous fluids, and that F may have played a role in the acidic alteration of the Murray Fm.

Depositional environments during the Late Palaeozoic ice age (LPIA) in northern Ethiopia, NE Africa

NASA Astrophysics Data System (ADS)

Bussert, Robert

2014-11-01

The Late Palaeozoic sediments in northern Ethiopia record a series of depositional environments during and after the Late Paleozoic ice age (LPIA). These sediments are up to 200 m thick and exceptionally heterogeneous in lithofacies composition. A differentiation of numerous types of lithofacies associations forms the basis for the interpretation of a large range of depositional processes. Major glacigenic lithofacies associations include: (1) sheets of diamictite, either overlying glacially eroded basement surfaces or intercalated into the sediment successions, and representing subglacial tillites, (2) thick massive to weakly stratified muddy clast-poor diamictites to lonestone-bearing laminated mudstones originating from a combination of suspension settling of fines and iceberg rainout, (3) lensoidal or thin-bedded diamictites deposited from debris flows, (4) wedges of traction and gravity transported coarse-grained sediments deposited in outwash fans, (5) irregular wedges or sheets of mudstones deformed primarily by extension and incorporating deformed beds or rafts of other lithofacies formed by slumping, and (6) irregular bodies of sandstone, conglomerate and diamictite deformed by glacial pushing. The dominance of laminated or massive clast-bearing mudstones in most successions indicates ice-contact water bodies as the major depositional environment. Into this environment, coarse-grained sediments were transported by various gravity driven transport processes, including dropstone activity of ice-bergs, slumping, cohesive debris flow, hyperconcentrated to concentrated flow, hyperpycnal flow, and by turbidity flow. Close to glacier termini, wedge-shaped bodies of conglomerate, sandstone, diamictite and mudstone were deposited primarily in subaqueous outwash-fans. Soft-sediment deformation of these sediments either records ice push during glacier advance or re-sedimentation by slumping. Apart from an initial glacier advance when thick ice of temperate or polythermal glaciers covered the whole basin, many sections document at least a second major phase of ice advance and retreat, and some sections additional minor advance-retreat cycles. Whether most of the LPIA sediments in northern Ethiopia were deposited in lakes or in fjords is not yet clear. Although univocal evidence of marine conditions is missing, the presence of carbonate-rich beds and the trace fossil assemblage are compatible with a restricted marine environment such as broad palaeofjords affected by strong freshwater discharge during deglaciation. A restricted marine environment for most of the sediments in northern Ethiopia could challenge models of the LPIA sediments in Arabia as primarily glaciolacustrine and glaciofluviatile deposits.

The Search for Organic Compounds of Martian Origin in Gale Crater by the Sample Analysis at Mars (SAM) Instrument on Curiosity

NASA Technical Reports Server (NTRS)

Glavin, Daniel; Freissinet, Caroline; Mahaffy, Paul; Miller, Kristen; Eigenbrode, Jennifer; Summons, Roger; Archer, Douglas, Jr.; Brunner, Anna; Martin, Mildred; Buch, Arrnaud;

Lithostratigraphy of Upper Ordovician strata exposed in Kentucky

USGS Publications Warehouse

Weir, Gordon Whitney; Peterson, Warren Lee; Swadley, W.C.

1984-01-01

Ordovician formations above the Lexington Limestone crop out in the Blue Grass region of Kentucky and along the Cumberland River and its tributaries. The formations are all conformable and in places intertongue and intergrade. The major Ordovician units above the Lexington Limestone in the Blue Grass region are: The Clays Ferry Formation, the Kope Formation, the Garrard Siltstone, the Fairview Formation, the Calloway Creek Limestone, the Grant Lake Limestone, the Ashlock Formation, the Bull Fork Formation, and the Drakes Formation. The Clays Ferry Formation is made up of subequal amounts of fossiliferous limestone and shale and minor siltstone; the Clays Ferry is as much as 300 ft thick and intertongues with the Lexington Limestone and the Kope Formation. The Kope Formation resembles the partly equivalent Clays Ferry but has a higher shale content (60-80 percent) and thicker layers of shale; the Kope, as much as 275 ft thick, is mostly restricted to the northern part of the State. The Garrard Siltstone, which consists of very calcitic siltstone and minor shale, overlies the Clays Ferry Formation in the southeastern part of the Blue Grass region; the Garrard, as much as 100 ft thick, feathers out into the upper part of the Clays Ferry in southern central and northern east-central Kentucky. The Fairview Formation is characterized by even-bedded limestone interlayered with nearly equal amounts of shale and minor siltstone. The Fairview crops out in the northern part of the Blue Grass region, where it generally overlies the Kope Formation or the Garrard Siltstone; it grades southward into the Calloway Creek Limestone. The Calloway Creek contains more limestone (generally at least 70 percent) and is more irregularly and thinner bedded than the Fairview. The Grant Lake Limestone is composed of nodular-bedded limestone (70-90 percent), interlayered and intermixed with shale; it overlies the Fairview Formation in the northern part of the Blue Grass region and the Calloway Creek Limestone in the western and central parts. In east-central Kentucky, the Grant Lake is classified as a member of the Ashlock Formation, an assemblage of lithologically distinct units that were combined to facilitate mapping in the southeastern and southern part of the region. The Ashlock consists of the following members, in ascending order: The Tate (calcitic and dolomitic mudstone), the Grant Lake, the Gilbert (micrograined limestone and shale), the Stingy Creek (nodular-bedded mudstone and limestone), the Terrill (dolomitic and calcitic mudstone), the Sunset (micrograined limestone), and the Reba (nodular-bedded limestone and shale). The Bull Fork Formation, which overlies the Grant Lake Limestone, is made up of subequal amounts of thin-bedded highly fossiliferous limestone and shale; limestone makes up about 80 percent of the basal part of the formation and decreases in abundance irregularly upward to only 20 percent of the top part. On the east side of the Blue Grass region, the Bull Fork grades into the Reba Member of the Ashlock Formation; on the west side, it grades into the Grant Lake. The uppermost formation in the region is the Drakes Formation, which in east-central Kentucky consists of the Rowland Member (calcitic to dolomitic mudstone) overlain by the Preachersville Member (dolomitic to calcitic mudstone and dolomite and dolomitic siltstone). In northeast Kentucky, the Drakes is represented by only the Preachersville Member. In most of central and north-central Kentucky, the formation consists of three members: the Rowland at the base (dolomitic mudstone to muddy limestone), the Bardstown (fossiliferous limestone and shale), and the Saluda Dolomite (dolomite, in part calcitic and muddy). In northern north-central Kentucky, the Drakes is represented by only the Saluda Dolomite Member. The top of the Ordovician sequence in the Blue Grass region is generally formed by members of the Drakes Formation, which are overlain by str

Development of a rockfall hazard rating matrix for the State of Ohio : executive summary report.

DOT National Transportation Integrated Search

2005-06-30

The geology in Ohio is characterized by the : presence of gently dipping, harder, more competent : strata (siltstones, sandstones, limestones) alternating : with softer, less competent strata (claystones, : mudstones, sha les). This type of stratigra...

Development of a Rockfall Hazard Rating Matrix for the State of Ohio : Executive Summary Report

DOT National Transportation Integrated Search

2005-06-01

The geology in Ohio is characterized by the : presence of gently dipping, harder, more competent : strata (siltstones, sandstones, limestones) alternating : with softer, less competent strata (claystones, : mudstones, sha les). This type of stratigra...

Mineralogy of Rocks and Sediments at Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Achilles, Cherie; Downs, Robert; Blake, David; Vaniman, David; Ming, Doug; Rampe, Elizabeth; Morris, Dick; Morrison, Shaunna; Treiman, Allan; Chipera, Steve; Yen, Albert; Bristow, Thomas; Craig, Patricia; Hazen, Robert; Crisp, Joy; Grotzinger, John; Des Marias, David; Farmer, Jack; Sarrazin, Philippe; Morookian, John Michael

2017-04-01

The Mars Science Laboratory rover, Curiosity, is providing in situ mineralogical, geochemical, and sedimentological assessments of rocks and soils in Gale crater. Since landing in 2012, Curiosity has traveled over 15 km, providing analyses of mudstones and sandstones to build a stratigraphic history of the region. The CheMin X-ray diffraction (XRD) instrument is the first instrument on Mars to provide quantitative mineralogical analyses of drilled powders and scooped sediment based on X-ray crystallography. CheMin identifies and determines mineral abundances and unit-cell parameters of major crystalline phases, and identifies minor phases at abundances >1 wt%. In conjunction with elemental analyses, CheMin-derived crystal chemistry allows for the first calculations of crystalline and amorphous material compositions. These mineralogy, crystal chemistry, and amorphous chemistry datasets are playing central roles in the characterization of Gale crater paleoenvironments. CheMin has analyzed 17 rock and sediment samples. In the first phase of the mission, Curiosity explored the sedimentary units of Aeolis Palus (Bradbury group), including two mudstones from Yellowknife Bay. CheMin analyses of the Yellowknife Bay mudstones identified clay minerals among an overall basaltic mineral assemblage. These mineralogical results, along with imaging and geochemical analyses, were used to characterize an ancient lacustrine setting that is thought to have once been a habitable environment. Following the investigations of the Bradbury group, Curiosity arrived at the lower reaches of Aeolis Mons, commonly called Mt. Sharp. A strategic sample campaign was initiated, drilling bedrock at <25 m elevation intervals in order to compile a comprehensive stratigraphic column of Mt. Sharp sedimentary units. Two formations have been sampled thus far, the lower-most Murray formation and the Stimson formation, which lies unconformably over the Murray. The Stimson formation is a cross-bedded sandstone interpreted as ancient, lithified eolian dunes. The mineralogy of this sandstone is dominated by plagioclase, pyroxene, magnetite and X-ray amorphous phases. Adjacent to fractures, light-toned, halo-like zones are thought to result from significant aqueous alteration of the primary sandstone and show decreased abundances of feldspar and pyroxene, and an increase in the amorphous component, specifically high-silica phases. The Murray formation is the most sampled stratigraphic unit in Gale crater. Composed mainly of finely laminated mudstones and interpreted as lacustrine deposits, the mineralogy of Murray rocks reveals a complex aqueous history. Within the lower Murray strata, CheMin identified clay minerals, crystalline and amorphous silica, hematite, magnetite, and jarosite. The mineralogy suggests a paleolake that experienced variable redox conditions and sediment influx from multiple sources. Younger Murray strata have high abundances of clay minerals, hematite, and calcium sulfate but show lower variability in mineralogy compared to the older bedforms. CheMin's identification of tridymite in one of the Murray mudstone samples led to the first in situ identification of silicic volcanism on Mars. This presentation will discuss the mineralogy of sedimentary samples analyzed by CheMin and how these data are used to characterize the depositional and diagenetic environment of Gale crater's long-lived lake system.

Clay Mineral Structure Similar to Clays Observed in Mudstone on Mars

NASA Image and Video Library

2013-12-09

This schematic shows the atomic structure of the smallest units that make up the layers and interlayer region of clay minerals. This structure is similar to the clay mineral in drilled rock powder collected by NASA Curiosity Mars rover.

Stratigraphy and depositional environment of unnamed (lower Miocene) submarine-fan sandstone unit in Sierra Madre and San Rafael Mountains, northeastern Santa Barbara County, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomas, G.D.; Fritsche, A.E.; Condon, M.W.

1988-03-01

A relatively thick and extensive, previously unnamed, lower Miocene sandstone unit occurs in the central Sierra Madre and in the Hurricane Deck area of the San Rafael Mountains of northeastern Santa Barbara County, California. It is underlain conformably and interfingers with a dark mudstone that correlates with the Soda Lake Shale Member of the Vaqueros Formation; it is overlain conformably and interfingers with a brown shale that correlates with the Saltos Member of the Monterey Shale. Northeastern exposures along the north flank of the Sierra Madre are almost exclusively medium to coarse-grained, structureless sandstone with scattered pebbly conglomerate beds. Thicknessmore » ranges from zero in the southeastern part of the Sierra Madre to 70 m in the northeast, 75 m in the northwest, and 600 m in the central part of the range. Toward the southwest in the Hurricane Deck area of the San Rafael Mountains, the unit becomes thicker and more extensively interbedded with mudstone. Lithology of the unit consists of 0.3-3.5 m thick beds of medium to coarse-grained, structureless to vaguely graded sandstone with scoured contacts at the base. Sandstone beds 0.3-3.0 m thick, which are more distinctly graded from coarse to very fine are also present. The interbedded mudstone commonly is bioturbated, so bedding is indistinct. Thickness ranges from 1020 m in the central part of the area to 750 m toward the southwest and 92 m toward the northwest. The unit most likely represents deposition in a submarine-canyon and fan complex that had its channel head in the northeast and spread southwestward into a thick sequence of submarine-fan sandstone lobes, which were confined in a narrow west-trending trough.« less

Submarine fan facies of Upper Cretaceous Strata, Southern San Rafael Mountains, Santa Barbara County, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Toyne, C.D.

1986-04-01

A 2900-m thick Campanian-Maestrichtian(.) turbidite sequence in Upper Mono Creek Canyon is interpreted to be a progradational submarine fan complex comprised of outer fan, middle fan, inner fan, and slope facies. The basal 600 m of the section consists of thinly bedded, laterally continuous fine sandstones, siltstones, and mudstones (mainly Mutti and Ricci Lucci facies D), interpreted to be outer fan interlobe and lobe-fringe deposits. These are punctuated by infrequent medium to very thickly bedded, flat-based, fine to coarse sandstones (facies C and B), which commonly coarsen and thicken upward, and are interpreted to be depositional lobes. Overlying these depositsmore » are approximately 1400 m of middle fan deposits composed of frequent lenticular, commonly channelized and amalgamated, thickly bedded, fine to very coarse sandstones (facies C and B) organized in fining- and thinning-upward sequences, interpreted to be braided-channel deposits. These alternate with less common nonchannelized coarsening- and thickening-upward sequences suggestive of lobe-apical cycles. These multistory sand deposits are nested within thick intervals of fine sandstones, siltstones, and mudstones (facies C and D), interpreted to be levee, crevasse-splay, and interchannel deposits. Interfingered with and overlying these deposits are approximately 500 m of fining- and thinning-upward or noncyclic, erosionally based, commonly amalgamated, very thickly bedded, medium to very coarse sandstones, pebbly sandstones, and conglomerates (facies A and B), interpreted to be inner fan deposits. Intercalated within this facies, infrequent, laterally discontinuous, thin to thickly bedded, fine to coarse sandstones, siltstones, and mudstones exist, interpreted to be interchannel, levee, and possibly channel-fill deposits.« less

Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity during the Prime Mission: Implications for Diagenesis

NASA Astrophysics Data System (ADS)

Rampe, E. B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T.; Chipera, S.; Blake, D. F.; Ming, D. W.; Farmer, J.; Morrison, S. M.; Treiman, A. H.; Achilles, C.; Crisp, J.; Des Marais, D. J.; Downs, R. T.; Morookian, J. M.; Sarrazin, P.; Spanovich, N.; Yen, A.

2014-12-01

The Mars Science Laboratory rover Curiosity investigated sedimentary rocks that were deposited in a diversity of fluvio-lacustrine settings. The entire science payload was employed to characterize the mineralogy and chemistry of the Sheepbed mudstone at Yellowknife Bay and the Windjana sandstone at the Kimberley. Data from the CheMin instrument, a transmission X-ray diffractometer, were used to determine the quantitative mineralogy of both samples. The Sheepbed mudstone contains detrital basaltic minerals, calcium sulfates, iron oxides or hydroxides, iron sulfides, trioctahedral smectite, and amorphous material. The mineral assemblage and chemical data from APXS suggest that the trioctahedral smectite and magnetite formed authigenically as a result of alteration of olivine. The apparent lack of higher-grade phyllosilicates (e.g., illite and chlorite) and the presence of anhydrite indicate diagenesis at ~50-80 ºC. The mineralogy of the Windjana sandstone is different than the Sheepbed mudstone. Windjana contains significant abundances of K-feldspar, low- and high-Ca pyroxenes, magnetite, phyllosilicates, and amorphous material. At least two distinct phyllosilicate phases exist: a 10 Å phase and a component that is expanded with a peak at ~11.8 Å. The identity of the expanded phase is currently unknown, but could be a smectite with interlayer H2O, and the 10 Å phase could be illite or collapsed smectite. Further work is necessary to characterize the phyllosilicates, but the presence of illite could suggest that Windjana experienced burial diagenesis. Candidates for the cementing agents include fine-grained phyllosilicates, Fe-oxides, and/or amorphous material. Interpretations of CheMin data from the Windjana sandstone are ongoing at the time of writing, but we will present an estimate of the composition of the amorphous material from mass balance calculations using the APXS bulk chemistry and quantitative mineralogy from CheMin.

Oxygen deficient Ti oxides (natural magnéli phases) from mudstone xenoliths with native iron from Disko, central West Greenland

NASA Astrophysics Data System (ADS)

Pedersen, A. K.; Rønsbo, J. G.

1987-05-01

Mudstone xenoliths in a strongly reduced andesitic subaquatic breccia with native iron from the Asuk Member on Disko contain Ti oxides which are oxygen deficient relative to rutile. Ore microscopy reveals that the mudstone xenoliths contain former clastic oxide grains which have equilibrated to blue Ti oxides and grey aluminous Ti oxides. They also contain still immature coal fragments in a glassy matrix with native iron. The blue oxides are compositionally similar to magnéli phases TinO2n-1 within the range n=4 to 7, and several grains contain more than one natural magnéli phase. Two other phases found are 1) pale orange blebs in magnéli phases with a composition approaching Al1Ti{1/3+}Ti{2/4+}O7 (AlTi phase B) and 2) grey oxide rims on magnéli phases or independent grains of the compositional series Al2-x(Ti{0.5/4+}(Mg,Fe)0.5)xTi{n-2/4+}O2n-1 with n mostly between 7 and 10 (AlTi phase A). The natural magnéli phases equilibrated at oxygen fugacities 4 to 5 log units below the Fe-W oxygen buffer at igneous temperatures and represent the most reduced high-temperature environment yet recorded among native iron bearing rocks from Disko. The extremely reducing conditions were met in rocks where coal fragments were still in a state of degassing hydrocarbon components at the time of quenching. Field geology and carbon barometry indicate equilibration at pressures of less than 10 bars.

Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity During the Prime Mission: Implications for Diagenesis

NASA Technical Reports Server (NTRS)

Rampe, Elizabeth B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T. F.; Chipera, S. J.; Blake, D. F.; Ming, D. W.; Farmer, J. D.; Morrison, S. M.;

Similarities Across Mars: Acidic Fluids at Both Meridiani Planum and Gale Crater in the Formation of Magnesium-Nickel Sulfates

NASA Astrophysics Data System (ADS)

Yen, A. S.; Ming, D. W.; Gellert, R.; Mittlefehldt, D. W.; Vaniman, D. T.; Thompson, L. M.; Morris, R. V.; Clark, B. C.; Arvidson, R. E.

2016-12-01

In-situ identification of sulfates at the martian surface by the Mars Exploration Rovers and the Mars Science Laboratory have included calcium sulfates with various states of hydration (gypsum, bassanite, anhydrite), iron sulfates of likely fumarolic origin, massive deposits of iron hydroxysulfates indicative of an acidic history, and minor occurrences of magnesium sulfates. Recent measurements by the Opportunity and Curiosity Alpha Particle X-ray Spectrometers (APXS) have indicated the presence of Ni-substituted Mg-sulfates at the Meridiani Planum and Gale Crater landing sites. The Opportunity rover has traversed nearly 43 km and is currently exploring the impact breccias of the rim of Endeavour crater, near a location where signatures of aqueous alteration have been established from orbit. APXS analyses of subsurface materials excavated by a rover wheel show clear evidence for a Mg(Ni)-sulfate with Mg:Ni 100:1 (molar). On the other side of the planet, Curiosity is continuing its climb up Mount Sharp after driving 13 km since landing. Over the last 4 km of the traverse, there have been multiple chemical analyses of erosionally-resistant nodules and dendritic features in a finely laminated mudstone unit which also indicate Mg(Ni)-sulfate (Mg:Ni 30:1, molar). The geologic settings for the Endeavour rim and the Mount Sharp mudstones are clearly different, but similar formation conditions for these sulfates may be possible. Ni(2+) readily substitutes for Mg(2+) in a variety of geochemical processes due to their comparable ionic radii. The availability of soluble Ni at the time of Mg-sulfate precipitation suggests acidic solutions. The fluids responsible for alteration in the Endeavour rim and for the formation of nodules in Gale mudstones may have had similar chemical characteristics at the time the Mg-sulfates were formed.

Apparent overconsolidation of mudstones in the Kumano Basin of southwest Japan: Implications for fluid pressure and fluid flow within a forearc setting

NASA Astrophysics Data System (ADS)

Guo, Junhua; Underwood, Michael B.; Likos, William J.; Saffer, Demian M.

2013-04-01

The Kumano Basin is located in the Nankai Trough subduction zone of southwest Japan. During the past 1.6 million years, approximately 800 meters of sandy turbidites and hemipelagic mud were deposited near the distal edge of the forearc basin, at Site C0002 of the Integrated Ocean Drilling Program. Constant-rate-of-strain consolidation tests yield estimates of in situ permeability that range from 2.6 × 10-17 m2 to 2.5 × 10-18 m2; overconsolidation ratios range from 1.7 to 2.6, and values of the compression index range from 0.39 to 0.78. Several processes contributed to the apparent overconsolidation. Strata dip toward land, and pore fluids probably migrate up-dip and vent along a bathymetric notch near the seaward edge of the basin. Efficient lateral drainage through sandy turbidites has kept pore pressures within interbeds of mudstone at (or close to) hydrostatic. In addition, alteration of dispersed volcanic glass, precipitation of authigenic clay minerals, and collapse of random grain fabric has probably strengthened the bonding among grains. Cementation is particularly likely within the lower basin (unit III), where values of porosity remain anomalously high. If fluid overpressures (and underconsolidation) exist anywhere within the basin, the most likely loci are where sandy turbidites terminate against impermeable mudstones along landward-dipping on-lap surfaces. Those types of on-lap geometries, in addition to structural closures, might provide promising targets for oil/gas accumulation in other forearc basins, particularly where petroleum source rocks have been buried to the optimal depths of catagenesis.

Impact of Diagenesis on Biosignature Preservation Potential in Playa Lake Evaporites in Verde Formation, Arizona: Implications for Mars Exploration

NASA Astrophysics Data System (ADS)

Shkolyar, S.; Farmer, J. D.

2015-12-01

Major priorities for Mars science include assessing the preservation potential and impact of diagenesis on biosignature preservation in aqueous sedimentary environments. We address these priorities with field and lab studies of playa evaporites of the Verde Formation (upper Pliocene) in Arizona. Evaporites studied include bottom-nucleated halite and displacive growth gypsum in magnesite-rich mudstone. These lithotypes are potential analogs for ancient lacustrine habitable environments on Mars. This study aimed to understand organic matter preservation potential under different diagenetic histories. Methods combined outcrop-scale field observations and lab analyses, including: (1) thin-section petrography to understand diagenetic processes and paragenesis; (2) X-ray powder diffraction to obtain bulk mineralogy; (3) Raman spectroscopy to identify and place phases (and kerogenous fossil remains) within a microtextural context; (4) Total Organic Carbon (TOC) analyses to estimate weight percentages of preserved organic carbon for each subfacies endmember; and (5) electron microprobe to create 2D kerogen maps semi-quantifying kerogen preservation in each subfacies. Results revealed complex diagenetic histories for each evaporite subfacies and pathways for organic matter preservation. Secondary gypsum grew displacively within primary playa lake mudstones during early diagenesis. Mudstones then experienced cementation by Mg-carbonates. Displacive-growth gypsum was sometimes dissolved, forming crystal molds. These molds were later either infilled by secondary sulfates or recrystallized to gypsum pseudomorphs with minor phases present (i.e., glauberite). These observations helped define taphonomic models for organic matter preservation in each subfacies. This work has the potential to inform in situ target identification, sampling strategies, and data interpretations for future Mars Sample Return missions (e.g., sample caching strategies for NASA's Mars 2020 mission).

Pore-Lining Composition and Capillary Breakthrough Pressure of Mudstone Caprocks: Sealing Efficiency of Geologic CO2 Storage Sites

NASA Astrophysics Data System (ADS)

Heath, J. E.; Dewers, T. A.; McPherson, B. J.; Kotula, P. G.

2010-12-01

Subsurface containment of CO2 is predicated on effective caprock sealing. Many previous studies have relied on macroscopic measurements of capillary breakthrough pressure and other petrophysical properties without direct examination of solid phases that line pore networks and directly contact fluids. However, pore-lining phases strongly contribute to sealing behavior through interfacial interactions among CO2, brine, and the mineral or non-mineral phases. Our high resolution (i.e., sub-micron) examination of the composition of pore-lining phases of several continental and marine mudstones indicates that sealing efficiency (i.e., breakthrough pressure) is governed by pore shapes and pore-lining phases that are not identifiable except through direct characterization of pores. Bulk X-ray diffraction data does not indicate which phases line the pores and may be especially lacking for mudstones with organic material. Organics can line pores and may represent once-mobile phases that modify the wettability of an originally clay-lined pore network. For shallow formations (i.e., < ~800 m depth), interfacial tension and contact angles result in breakthrough pressures that may be as high as those needed to fracture the rock—thus, in the absence of fractures, capillary sealing efficiency is indicated. Deeper seals have poorer capillary sealing if mica-like wetting dominates the wettability. We thank the U.S. Department of Energy’s National Energy Technology Laboratory and the Office of Basic Energy Sciences, and the Southeast and Southwest Carbon Sequestration Partnerships for supporting this work. Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Company, for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.

Paleolimnology of Lake Tubutulik, an iron-meromictic Eocene Lake, eastern Seward Peninsula, Alaska

USGS Publications Warehouse

Dickinson, K.A.

1988-01-01

Sideritic lacustrine mudstone was found in drill core from a uranium deposit in the Death Valley area in the eastern part of the Seward Peninsula, Alaska. The precursor sediments for this rock were deposited in an unusual "iron-meromictic" Eocene lake, herein named Lake Tubutulik, which occupied part of the Boulder Creek basin, a structural graben that is probably a southern extension of the larger Death Valley basin. The Boulder Creek basin is bounded on the west by granite of the Late Cretaceous Darby Pluton, on the east by Precambrian to Paleozoic metasedimentary rocks. The lake basin was formed by basaltic flows that dammed the river valley of the ancestral Tubutulik River in early Eocene time. Lake Tubutulik contained a nearshore facies of fine-grained organic mud and an offshore facies of laminated sideritic mud. The offshore (profundal) laminated mudstone consists of alternating layers of authigenic siderite and detrital layers containing mostly quartz and clay minerals. Both lacustrine facies contain turbidities. The lacustrine sediments graded laterally into an onshore facies of colluvial and fluvial sandstone, paludal mudstone, and coal. The ancient lake apparently occupied a small deep basin in a tectonically active area of high relief. Meromixus was probably stabilized by reduced iron and bicarbonate dissolved in the monimolimnion. The intensity of meromixus decreased as the lake became shallower from sediment filling. The source of the iron, abundant in the monimolimnion of Lake Tubutulik, was probably the Eocene basalt. Based on carbon isotope analysis of the siderite, the dissolved bicarbonate in the profundal facies was largely inorganic. Sideritic carbon in one sample from the onshore paludal facies has an isotopic signature (??13C = +16.9) consistent with residual carbon formed during methanogenic fermentation. ?? 1988.

Relationship between pore geometric characteristics and SIP/NMR parameters observed for mudstones

NASA Astrophysics Data System (ADS)

Robinson, J.; Slater, L. D.; Keating, K.; Parker, B. L.; Robinson, T.

2017-12-01

The reliable estimation of permeability remains one of the most challenging problems in hydrogeological characterization. Cost effective, non-invasive geophysical methods such as spectral induced polarization (SIP) and nuclear magnetic resonance (NMR) offer an alternative to traditional sampling methods as they are sensitive to the mineral surfaces and pore spaces that control permeability. We performed extensive physical characterization, SIP and NMR geophysical measurements on fractured rock cores extracted from a mudstone site in an effort to compare 1) the pore size characterization determined from traditional and geophysical methods and 2) the performance of permeability models based on these methods. We focus on two physical characterizations that are well-correlated with hydraulic properties: the pore volume normalized surface area (Spor) and an interconnected pore diameter (Λ). We find the SIP polarization magnitude and relaxation time are better correlated with Spor than Λ, the best correlation of these SIP measures for our sample dataset was found with Spor divided by the electrical formation factor (F). NMR parameters are, similarly, better correlated with Spor than Λ. We implement previously proposed mechanistic and empirical permeability models using SIP and NMR parameters. A sandstone-calibrated SIP model using a polarization magnitude does not perform well while a SIP model using a mean relaxation time performs better in part by more sufficiently accounting for the effects of fluid chemistry. A sandstone-calibrated NMR permeability model using an average measure of the relaxation time does not perform well, presumably due to small pore sizes which are either not connected or contain water of limited mobility. An NMR model based on the laboratory determined portions of the bound versus mobile portions of the relaxation distribution performed reasonably well. While limitations exist, there are many opportunities to use geophysical data to predict permeability in mudstone formations.

Whitby Mudstone, flow from matrix to fractures

NASA Astrophysics Data System (ADS)

Houben, Maartje; Hardebol, Nico; Barnhoorn, Auke; Boersma, Quinten; Peach, Colin; Bertotti, Giovanni; Drury, Martyn

2016-04-01

Fluid flow from matrix to well in shales would be faster if we account for the duality of the permeable medium considering a high permeable fracture network together with a tight matrix. To investigate how long and how far a gas molecule would have to travel through the matrix until it reaches an open connected fracture we investigated the permeability of the Whitby Mudstone (UK) matrix in combination with mapping the fracture network present in the current outcrops of the Whitby Mudstone at the Yorkshire coast. Matrix permeability was measured perpendicular to the bedding using a pressure step decay method on core samples and permeability values are in the microdarcy range. The natural fracture network present in the pavement shows a connected network with dominant NS and EW strikes, where the NS fractures are the main fracture set with an orthogonal fracture set EW. Fracture spacing relations in the pavements show that the average distance to the nearest fracture varies between 7 cm (EW) and 14 cm (NS), where 90% of the matrix is 30 cm away from the nearest fracture. By making some assumptions like; fracture network at depth is similar to what is exposed in the current pavements and open to flow, fracture network is at hydrostatic pressure at 3 km depth, overpressure between matrix and fractures is 10% and a matrix permeability perpendicular to the bedding of 0.1 microdarcy, we have calculated the time it takes for a gas molecule to travel to the nearest fracture. These input values give travel times up to 8 days for a distance of 14 cm. If the permeability is changed to 1 nanodarcy or 10 microdarcy travel times change to 2.2 years or 2 hours respectively.

Braidplain, floodplain and playa lake, alluvial-fan, aeolian and palaeosol facies composing a diversified lithogenetical sequence in the permian and triassic of South Devon (England)

NASA Astrophysics Data System (ADS)

Mader, Detlef

The Permian and Triassic of South Devon (England) are a continental red bed sequence of very diversified lithogenetical composition. Within the thick series, the distribution of the main depositional environments being fluvial braidplain, fluvial floodplain and playa lake, alluvial fan, aeolian dune and calcrete palaeosol changes repeatedly in both horizontal and vertical direction. Significant sedimentary milieus such as aeolian dunes and calcrete palaeosols occur repeatedly within the succession, but are also lacking in several parts of the sequence. Fluvial braidplain deposits comprise conglomerates, sandstones, intraformational reworking horizons and mudstones and originate in channels and overbank plains of a braided river system. Conglomerates and sandstones are formed by migration of bars and spreading out of sheets during infilling of streams and aggradation of flats. Gravel is often enriched as lag pockets or veneers within steeper scour holes and kolk pots or on the plane floor of the watercourse. Finer-grained sandstones and mudstones are laid down by suspension settling in stagnant water bodies such as small lakes in the overbank area and residual pools in interbar depressions during low-stage or waning-flow in active channels or in abandoned streams. Spectacular bioturbation features in some sandstones with both horizontal tubes and vertical burrows testify to the colonization of the sediments at the bottom of the rivers with declining discharge and transport capacity. Intraformational reworking horizons with ghost-like remnants of degraded sandstones, mudstones and pedogenic carbonates document partially severe condensation of the sequence by removal of some facies elements from the depositional record. The occasionally occurring gravel-bearing mudstones or silty-clayey sandstones represent products of high-energy water surges overspilling the channel banks and transporting sandy and gravelly bed-load in limited amounts beyond the levee wall. The interbedded sand layers within the mudstone sequences are often subjected to various types of deformation, depending on the state of dewatering and thus consolidation of the mudstones. Loading of partially dewatered mudstones with thinner sandstone beds results in division of the sand into isolated balls and pillows which frequently sink down into the mud. Burial of still plastic mudstones by thicker sandstones gives rise to intrusion of the mobile clay into the loose sand as domes and pillars. Infilling of mud cracks by sand at the contacts of both lithologies reflects total stabilization of silty-clayey sediments by desiccation during subaerial exposure. The cohesion of the mud in an advanced stage of dewatering is also underlined by the downcutting of bizarre erosional reliefs with steep walls and overhanging, undercut flanks in some negative features and steep residual pillars as positive remnants of degradation. Fluvial floodplain and playa lake sediments comprising mudstones and sandstones originate in lakes, ponds and puddles in overbank plains intersected by alluvial channels and in extensive flood flats of playa type lacking intervening watercourses, with the delimitation between floodplain and plays a lake being arbitrary and fluent. Mudstones are laid down during partially prolonged periods of quiet water which are only occasionally interrupted by invasion of channelized or sheet-type flood surges that result in spreading out of sand blankets at the floor of the lake. The rarity of bioturbation in many parts of the mudstone sequences gives evidence of high rates of suspension fallout over longer periods of time thereby inhibiting the colonization of the ground of the water bodies. Alluvial-fan deposits comprising breccias, sandstones and mudstones originate by stream-flood, sheet-flood and stream-flow in channels and on flats of an alluvial-fan complex. Blankets and drapes of breccias are spread out on the slope of alluvial-fan cones and are spilled onto the sand flat seaming the toes of the fan chain. Sedimentation is characterized by flashy discharge with many episodic flood pulses of short periodicity and mainly rapid waning of high-water phases with quick underrunning of the threshold velocity for keeping the large clasts rolling. Pronounced slack water episodes allow occasionally the draping of gravel sheets with thin veneers of waning-flow and stagnant-water fines. Spectacular invertebrate burrows in finer breccias underline the flashy nature of most of the flood and flow events, allowing the colonization of the sediments with ground-living invertebrates during interruptions of transport and accumulation. Some peculiar dewatering structures being infilling of crack systems in breccias with wash-load sand are probably induced by earthquake shocks thus pointing to the active tectonic setting of the depositional area. Aeolian sands originate as transverse dune ridges in restricted dune fields and extensive sand seas and as sheet sands in interdune playa depressions. Associated mudstones and ventifact gravel form in wet interdunes or in playa lakes and in deflationary interdunes, respectively. Accumulation of aeolian dunes and interdune sheet sands takes place by both spreading out of drapes on flats and infilling of abandoned fluvial channels which enhance the trapping of sand by topographical effects. The dunes and wind ripple trains migrate across dry interdune floors under predominantly unidirectional winds. Sedimentary processes are grainfall and grainflow on the lee slope of dunes and subcritical climbing of wind ripples. Episodical wetting and dampening of dry interdune flats by intermittent rainfall, periodical dew and even ephemeral fluvial or alluvial-fan incursions allow formation of adhesion-rippled sands on damp surfaces and origin of sandy and silty-clayey lacustrine sediments in shallow water veneers of the flooded playa. Aquatic modification of aeolian sands by invading flood surges of atmospheric or alluvial provenance is highlighted by downcutting of steep scour holes and kolk pots with overhanging, undercut walls and by reworking of large blocks of sand which are mainly released gravitationally by collapse of undermined channel banks, with considerable stabilization of the aeolian sand by humidhesion permitting the formation of bizarre erosional morphologies and the reworking as clasts (apart from dispersing loose aeolian sand within the fluvial bed-load which is also of particular significance). Inundations from surrounding alluvial fans and adjoining fluvial channels results also in spreading out of aquatic bed-load veneers across the interdune flats which bury the aeolian dunes and wind ripple trains and thus interrupt deflation and wind-borne accumulation. Ventifact gravel testifies to grinding of facets by sand-blasting activity of strong winds and degradation of pebbly fluvial sediments by winnowing of the sandy matrix. Ventifacts which are concentrated as residual gravel lag veneers at the floor of the serir erg are of considerable importance in testifying to limited aeolian influence on fluvial deposition when reworked and dispersed within alluvial rudites. Calcrete palaeosol features comprise autochthonous carbonate precipitations and violet colour streaks as well as allochthonous Bröckelbank carbonate breccias. In situ carbonate precipitations from by crystallization of carbonate minerals in the soil as isometrical nodules, flat discs and vertical tubes. Progressive maturing gives rise to coalescence of isolated nodules to aggregates and amalgamation to dense crusts. In terms of time and space of origin of carbonate concretions, distinction has to be made between early formation during subaerial exposure and early to late subaqueous growth under a cover of water or precipitation within the ground after burial by younger sediments. The development of calcrete palaeosols is often limited to the origin of nodules and tubes within the sandy substrates, with infiltration and neoformation of mud during illuviation, conversion of colour to blue-violet by significant hematite growth and pedoturbation being frequently restricted to the initial stages or even being totally suppressed. Root tubes testify to the colonization of soils by vegetation. Crystallization of syngenetic carbonates in aeolian sands forming dikaka horizons is of considerable importance for enhancing their preservation potential by stabilization against both fluvial erosion and aeolian deflation. The coexistence of aeolian sands and calcrete palaeosols (in contrast to their mutually exclusive occurrence in the Upper Buntsandstein of the German Basin) is the result of the limited maturity of the pedogenic horizons with preservation of sandy matrix thus still permitting reasonable winnowing at least in parts of the depositional area, and restriction of atmospheric precipitation to shorter phases alternating with longer dry periods that allow desiccation of the surface and migration of aeolian bedforms. Bröckelbank carbonate breccias representing reworking horizons of calcrete palaeosols are indirect indicators of pedogenesis in the alluvial plain even in case of subsequently complete removal of in situ pedogenic features from the depositional record. Calcrete palaeosol formation overprints almost all the sedimentary units in the alluvial plain regardless of their composition, but is particularly frequent and well-developed in fluvial and aeolian substrates. The sequence of alluvial fans and fluvial braidplains with associated aeolian dune fields and intertonguing with fluvial floodplains to playa lakes in time and space, interrupted by various palaeotectonical and palaeoclimatological events, results in a very diversified depositional history in the Permian and Triassic part of the New Red Sandstone in South Devon.

Sequence stratigraphic control on prolific HC reservoir development, Southwest Iran

USGS Publications Warehouse

Lasemi, Y.; Kondroud, K.N.

2008-01-01

An important carbonate formation in the Persian Gulf and the onshore oil fields of Southwest Iran is the Lowermost Cretaceous Fahliyan formation. The formation in Darkhowain field consists of unconformity-bounded depositional sequences containing prolific hydrocarbon reservoirs of contrasting origin. Located in the high stand systems tract (HST) of the lower sequence encompassing over 200m of oil column are the most prolific reservoir. Another reservoir is over 80m thick consisting of shallowing-upward cycles that are best developed within the transgressive systems tract of the upper sequence. Vertical facies distribution and their paleobathymetry and geophysical log signatures of the Fahliyan formation in the Darkhowain platform reveal the presence of two unconformity-bounded depositional sequences in Vail et al., Van Wagoner et al., and Sarg. The Fahliyan formation mainly consists of platform carbonates composed of restricted bioclastic lime mudstone to packstone of the platform interior, Lithocodium boundstone or ooid-intraclast-bioclast grainstone of the high energy platform margin and the bioclast packstone to lime mudstone related to the off-platform setting.

Organic matter preserved in 3-billion-year-old mudstones at Gale crater, Mars.

PubMed

Eigenbrode, Jennifer L; Summons, Roger E; Steele, Andrew; Freissinet, Caroline; Millan, Maëva; Navarro-González, Rafael; Sutter, Brad; McAdam, Amy C; Franz, Heather B; Glavin, Daniel P; Archer, Paul D; Mahaffy, Paul R; Conrad, Pamela G; Hurowitz, Joel A; Grotzinger, John P; Gupta, Sanjeev; Ming, Doug W; Sumner, Dawn Y; Szopa, Cyril; Malespin, Charles; Buch, Arnaud; Coll, Patrice

2018-06-08

Establishing the presence and state of organic matter, including its possible biosignatures, in martian materials has been an elusive quest, despite limited reports of the existence of organic matter on Mars. We report the in situ detection of organic matter preserved in lacustrine mudstones at the base of the ~3.5-billion-year-old Murray formation at Pahrump Hills, Gale crater, by the Sample Analysis at Mars instrument suite onboard the Curiosity rover. Diverse pyrolysis products, including thiophenic, aromatic, and aliphatic compounds released at high temperatures (500° to 820°C), were directly detected by evolved gas analysis. Thiophenes were also observed by gas chromatography-mass spectrometry. Their presence suggests that sulfurization aided organic matter preservation. At least 50 nanomoles of organic carbon persists, probably as macromolecules containing 5% carbon as organic sulfur molecules. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

Llandovery green/grey and black mudrock facies of the northern Holy Cross Mountains (Poland) and their relation to early Silurian sea-level changes and benthic oxygen level

NASA Astrophysics Data System (ADS)

Trela, Wiesław; Podhalańska, Teresa; Smolarek, Justyna; Marynowski, Leszek

2016-08-01

The Llandovery mudrock facies in the northern Holy Cross Mountains reveal lithological variability allowing their interpretation in the context of post-Ordovician climate and sea-level changes in the Caledonian foredeep basin developed along the present SW margin of Baltica. They form a succession up to 50 m thick made up of grey and greenish clayey mudstones interrupted by black shales. The sedimentary and geochemical data (total organic carbon, pyrite framboids and trace metals) clearly show that the black shales document periods of the significant sediment starvation and oxygen- deficient conditions. Their occurrence is confined to the persculptus-acuminatus, vesiculosus, cyphus, convolutus-sedgwickii, turriculatus-crispus, crenulata and spiralis graptolite biozones and they can be correlated with post-glacial transgressions. In contrast, the grey and greenish mudstones are interpreted as lithofacies reflecting permanent benthic oxygenation driven by deep-water ventilation during the Aeronian and Telychian regressions supported by sedimentary and geochemical studies, and diameters of pyrite framboids

Clay mineral diversity and abundance in sedimentary rocks of Gale crater, Mars

PubMed Central

Chipera, Steve J.; Hazen, Robert M.; Horgan, Briony; Hogancamp, Joanna V.; Mangold, Nicolas; Morookian, John Michael; Morris, Richard V.; Vaniman, David T.; Yen, Albert S.

2018-01-01

Clay minerals provide indicators of the evolution of aqueous conditions and possible habitats for life on ancient Mars. Analyses by the Mars Science Laboratory rover Curiosity show that ~3.5–billion year (Ga) fluvio-lacustrine mudstones in Gale crater contain up to ~28 weight % (wt %) clay minerals. We demonstrate that the species of clay minerals deduced from x-ray diffraction and evolved gas analysis show a strong paleoenvironmental dependency. While perennial lake mudstones are characterized by Fe-saponite, we find that stratigraphic intervals associated with episodic lake drying contain Al-rich, Fe3+-bearing dioctahedral smectite, with minor (3 wt %) quantities of ferripyrophyllite, interpreted as wind-blown detritus, found in candidate aeolian deposits. Our results suggest that dioctahedral smectite formed via near-surface chemical weathering driven by fluctuations in lake level and atmospheric infiltration, a process leading to the redistribution of nutrients and potentially influencing the cycling of gases that help regulate climate. PMID:29881776

Constraining the alteration history of a Late Cretaceous Patagonian volcaniclastic bentonite-ash-mudstone sequence using K-Ar and 40Ar/39Ar isotopes

NASA Astrophysics Data System (ADS)

Warr, L. N.; Hofmann, H.; van der Pluijm, B. A.

2017-01-01

Smectite is typically considered unsuitable for radiometric dating, as argon (40Ar) produced from decay of exchangeable potassium (40K) located in the interlayer sites can be lost during fluid-rock interaction and/or during wet sample preparation in the laboratory. However, age analysis of Late Cretaceous Argentinian bentonites and associated volcaniclastic rocks from Lago Pellegrini, Northern Patagonia, indicates that, in the case of these very low-permeability rocks, the radioactive 40Ar was retained and thus can provide information on smectite age and the timing of rock alteration. This study presents isotopic results that indicate the ash-to-bentonite conversion and alteration of the overlying tuffaceous mudstones in Northern Patagonia was complete 13-17 my after middle Campanian sedimentation when the system isotopically closed. The general absence of illite in these smectite-rich lithologies reflects the low activity of K and the low temperature (<60 °C) of the formation waters that altered the parent ash.

Documenting mudstone heterogeneity by use of principal component analysis of X-ray diffraction and portable X-ray fluorescence data: A case study in the Triassic Shublik Formation, Alaska North Slope

USGS Publications Warehouse

Boehlke, Adam; Whidden, Katherine J.; Benzel, William M.

2017-01-01

Determining the chemical and mineralogical variability within fine-grained mudrocks poses analytical challenges but is potentially useful for documenting subtle stratigraphic differences in physicochemical environments that may influence petroleum reservoir properties and behavior. In this study, we investigate the utility of combining principal component analysis (PCA) of X-ray diffraction (XRD) data and portable X-ray fluorescence (pXRF) data to identify simplifying relationships within a large number of samples and subsequently evaluate a subset that encompasses the full spectrum or range of mineral and chemical variability within a vertical section. Samples were collected and analyzed from a vertical core of the Shublik Formation, a heterogeneous, phosphate-rich, calcareous mudstone-to-marl unit deposited in the Arctic Alaska Basin (AAB) during the Middle and Late Triassic. The Shublik is a major petroleum source rock in the Alaskan North Slope, and is considered a prime target for continuous self-sourced resource plays.

Fossil Scenedesmus (Chlorococcales) from the Raton Formation, Colorado and New Mexico, U.S.A.

USGS Publications Warehouse

Farley, Fleming R.

1989-01-01

Fossilized coenobia of the alga Scenedesmus (Chlorococcales) were recovered in palynomorph assemblages from a lower Paleocene mudstone in the Upper Cretaceous and Paleocene Raton Formation of Colorado and New Mexico. This is the first description of fossil Scenedesmus from Tertiary rocks. Two species, Scenedesmus tschudyi sp. nov. and Scenedesmus hanleyi sp. nov., are present in the assemblages. Coenobia of S. tschudyi sp. nov. are characterized by lunate terminal cells and fusiform median cells. As in species of modern Scenedesmus, coenobia of S. tschudyi sp. nov. occur with four or eight cells. Coenobia of S. hanleyi sp. nov. have four oval cells and are smaller than coenobia of S. tschudyi sp. nov. Fossil coenobia of Scenedesmus co-occur with the fossil alga Pediastrum in Raton Formation mudstones. Because these genera co-occur in modern lakes and ponds, the co-occurrence of fossil Scenedesmus and Pediastrum in ancient nonmarine rocks is interpreted to indicate deposition of sediment in freshwater lakes and ponds. ?? 1989.

Comparison of caprock pore networks which potentially will be impacted by carbon sequestration projects.

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCray, John; Navarre-Sitchler, Alexis; Mouzakis, Katherine

Injection of CO2 into underground rock formations can reduce atmospheric CO2 emissions. Caprocks present above potential storage formations are the main structural trap inhibiting CO2 from leaking into overlying aquifers or back to the Earth's surface. Dissolution and precipitation of caprock minerals resulting from reaction with CO2 may alter the pore network where many pores are of the micrometer to nanometer scale, thus altering the structural trapping potential of the caprock. However, the distribution, geometry and volume of pores at these scales are poorly characterized. In order to evaluate the overall risk of leakage of CO2 from storage formations, amore » first critical step is understanding the distribution and shape of pores in a variety of different caprocks. As the caprock is often comprised of mudstones, we analyzed samples from several mudstone formations with small angle neutron scattering (SANS) and high-resolution transmission electron microscopy (TEM) imaging to compare the pore networks. Mudstones were chosen from current or potential sites for carbon sequestration projects including the Marine Tuscaloosa Group, the Lower Tuscaloosa Group, the upper and lower shale members of the Kirtland Formation, and the Pennsylvanian Gothic shale. Expandable clay contents ranged from 10% to approximately 40% in the Gothic shale and Kirtland Formation, respectively. During SANS, neutrons effectively scatter from interfaces between materials with differing scattering length density (i.e., minerals and pores). The intensity of scattered neutrons, I(Q), where Q is the scattering vector, gives information about the volume and arrangement of pores in the sample. The slope of the scattering data when plotted as log I(Q) vs. log Q provides information about the fractality or geometry of the pore network. On such plots slopes from -2 to -3 represent mass fractals while slopes from -3 to -4 represent surface fractals. Scattering data showed surface fractal dimensions for the Kirtland formation and one sample from the Tuscaloosa formation close to 3, indicating very rough surfaces. In contrast, scattering data for the Gothic shale formation exhibited mass fractal behavior. In one sample of the Tuscaloosa formation the data are described by a surface fractal at low Q (larger pores) and a mass fractal at high Q (smaller pores), indicating two pore populations contributing to the scattering behavior. These small angle neutron scattering results, combined with high-resolution TEM imaging, provided a means for both qualitative and quantitative analysis of the differences in pore networks between these various mudstones.« less

Source-to-Sink System Evolution as Recorded in Clastic Facies in Two New Zealand Examples: the Bounty System of South Island and the Waipaoa System of North Island

NASA Astrophysics Data System (ADS)

Marsaglia, K. M.

2010-12-01

New Zealand river sources and their submarine sinks are excellent examples for modeling source-to-sink systems. In particular, the sand fractions of these systems can be used as tracers to document links and/or disconnects between fluvial, shelf, slope, and bathyal components. Within any given system, the ability to use sand as a tracer depends on the nature of the rocks exposed in source river drainage basins. In evolving systems, the potential for erosional unroofing, change of outcrop lithology through time, can be important. Additionally, the ability of a given lithology to generate sediment of a certain size may also vary. For example in the New Zealand examples, Cenozoic mudstones generate mostly mud but can liberate recycled sand grains (if present), as well as a smaller proportion of mudstone lithic fragments depending on degree of mudstone induration; schist generates copious sand and quartz-vein pebbles; and thin-bedded sandy turbidites can generate significant gravel, as well as mud and sand. Sediment production mode also comes into play with glacial processes (South Island) generating rock flour, as well as coarser debris. The major outcropping unit across both islands is a sedimentary to metasedimentary forearc succession, the Torlesse Terrane. It served as the protolith of the Otago schist (South Island) and the source of detritus for Cretaceous and Cenozoic sedimentary units on both islands. Local magmatism also supplied sand-sized material: intraplate (South Island) volcanism produced intrabasinal epiclastic debris and magmatic arc (North Island) volcanism produced extrabasinal pyroclastic debris. Various lithologies have characteristic detrital signatures. For example, in the Cenozoic units of the Waipaoa system, Pliocene calcareous mudstone fragments are key lithic components in tracing sediment transport from source-to sink, whereas the major fingerprint of Otago schist input into the Bounty System of South Island is mica. Critical to defining sedimentary budgets in both New Zealand systems is defining the net proportion of dip-fed vs. strike-fed clastic components. The former are supplied directly to the system by coast-perpendicular rivers, and the latter are transported into or out of the system by coast-parallel currents (e.g., longshore, shelf, slope). Tectonic events in the fluvial drainage basin can also have major influences on the supply of sediment to offshore basins. There is evidence for lacustrine sediment traps in each New Zealand system and evidence, in at least one case, that they modified sediment input to the marine part of the system (Bounty Fan).

Characterizing porosity of selected Early Palaeozoic shales from the Baltic Basin: organic petrology, gas adsorption and WIP and KIP approach.

NASA Astrophysics Data System (ADS)

Słomski, Piotr; Mastalerz, Maria; Szczepański, Jacek; Derkowski, Arkadiusz; Topór, Tomasz

2017-04-01

The porosity in the selected Ordovician and Silurian mudstones from the Baltic Basin collected from three wells (W1, M1, B1 and O3) was examined in a suite of 78 samples representing the Kopalino, Sasino, Prabuty, Pasłęk (including Jantar Member) and Pelplin Formations. Organic petrology, mineral composition along with N2 low-pressure adsorption (NLPA), water and kerosene immersion porosimetry (WIP and KIP, respectively) as well as image analysis techniques were used to determine pore volumes, pore sizes and pore-size distributions and to evaluate factors controlling porosity. The majority of the investigated samples represent argillaceous mudstones. Only a few samples from O3 and W1 are different lithologically and represent siliceous-argillaceous, calcareous, or calcareous-argillicaous mudstones. The samples are characterized by total organic carbon (TOC) content ranging from 0.13 to 7.20 wt. % and vitrinite reflectance (Ro) ranging from 1.02 to 1.22%, indicating late mature rocks within condensate - wet gas window. Total porosity measured using WIP is in the range from 4.6 % to 10 %, while KIP gave values from 1.5 % to 8.9 %. NLPA technique on the 75 µm size fraction revealed that mesopores area is in the range from 10.59 to 34.34 m2/g, while mesopores volume ranges from 0.024 to 0.062 cm3/g. Correlation between mesopores surface area and Ro is weak, but in general the surface area of mesopores is the largest in the least mature samples. Moreover, as indicated by gas adsorption data, both pores greater than 30 nm and smaller than 4 nm are important contributors to the total mesoporess surface area. In general, rather weak correlation between different mudstone constituents (including kerogen types) and porosity measured by means of various techniques (WIP, KIP and NLPA) reveal that there is no single factor controlling porosity in the investigated suite of samples. This conclusion is also confirmed by image analysis performed on large-scale high-resolution BSE images for selected representative samples. However, for mesopores, the dominant contribution comes from organic matter for the Jantar, Prabuty and Sasino Formations, as indicated by NLPA technique. Furthermore, importance of clay minerals for macropore volume is indicated by WIP and KIP technique. Acknowledgments: the study was supported from grant SHALESEQ (No PL12-0109) and SHALEMECH (No BG2/ShaleMech/14) funded by the National Centre for Research and Development.

Variations in petrophysical properties of shales along a stratigraphic section in the Whitby mudstone (UK)

NASA Astrophysics Data System (ADS)

Barnhoorn, Auke; Houben, Maartje; Lie-A-Fat, Joella; Ravestein, Thomas; Drury, Martyn

2015-04-01

In unconventional tough gas reservoirs (e.g. tight sandstones or shales) the presence of fractures, either naturally formed or hydraulically induced, is almost always a prerequisite for hydrocarbon productivity to be economically viable. One of the formations classified so far as a potential interesting formation for shale gas exploration in the Netherlands is the Lower Jurassic Posidonia Shale Formation (PSF). However data of the Posidonia Shale Formation is scarce so far and samples are hard to come by, especially on the variability and heterogeneity of the petrophysical parameters of this shale little is known. Therefore research and sample collection is conducted on a time and depositional analogue of the PSF: the Whitby Mudstone Formation (WMF) in the United Kingdom. A large number of samples along a ~7m stratigraphic section of the Whitby Mudstone Formation have been collected and analysed. Standard petrophysical properties such as porosity and matrix densities are quantified for a number of samples throughout the section, as well as mineral composition analysis based on XRD/XRF and SEM analyses. Seismic velocity measurements are also conducted at multiple heights in the section and in multiple directions to elaborate on anisotropy of the material. Attenuation anisotropy is incorporated as well as Thomsen's parameters combined with elastic parameters, e.g. Young's modulus and Poisson's ratio, to quantify the elastic anisotropy. Furthermore rock mechanical experiments are conducted to determine the elastic constants, rock strength, fracture characteristics, brittleness index, fraccability and rock mechanical anisotropy across the stratigraphic section of the Whitby mudstone formation. Results show that the WMF is highly anisotropic and it exhibits an anisotropy on the large limit of anisotropy reported for US gas shales. The high anisotropy of the Whitby shales has an even larger control on the formation of the fracture network. Furthermore, most petrophysical properties are highly variable. They vary per sample, but even within a sample on a mm-scale, large variations in e.g. the porosity occur. These relatively large variations influence the potential for future shale gas exploration for these Lower Jurassic shales in northern Europe and need to be quantified in detail beforehand. Compositional analyses and rock deformation experiments on the first samples indicate relatively low brittleness indices for the Whitby shale, but variation of these parameters within the stratigraphy are present. All petrophysical analyses combined will provide a complete assessment of the potential for shale gas exploration of these Lower Jurassic shales.

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: Depth- and strata-dependent spatial variability from rock-core sampling

NASA Astrophysics Data System (ADS)

Goode, Daniel J.; Imbrigiotta, Thomas E.; Lacombe, Pierre J.

2014-12-01

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently dipping mudstones. Despite more than 18 years of pump and treat (P&T) remediation, and natural attenuation processes, CVOC concentrations in aqueous samples pumped from these deeper strata remain elevated in isolated intervals. DNAPL was detected in one borehole during coring at a depth of 27 m. In contrast to core samples from the weathered zone, concentrations in core samples from deeper unweathered and unfractured strata are typically below detection. However, high CVOC concentrations were found in isolated samples from fissile black carbon-rich strata and fractured gray laminated strata. Aqueous-phase concentrations were correspondingly high in samples pumped from these strata via short-interval wells or packer-isolated zones in long boreholes. A refined conceptual site model considers that prior to P&T remediation groundwater flow was primarily subhorizontal in the higher-permeability near surface strata, and the bulk of contaminant mass was shallow. CVOCs diffused into these fractured and weathered mudstones. DNAPL and high concentrations of CVOCs migrated slowly down in deeper unweathered strata, primarily along isolated dipping bedding-plane fractures. After P&T began in 1995, using wells open to both shallow and deep strata, downward transport of dissolved CVOCs accelerated. Diffusion of TCE and other CVOCs from deeper fractures penetrated only a few centimeters into the unweathered rock matrix, likely due to sorption of CVOCs on rock organic carbon. Remediation in the deep, unweathered strata may benefit from the relatively limited migration of CVOCs into the rock matrix. Synthesis of rock core sampling from closely spaced boreholes with geophysical logging and hydraulic testing improves understanding of the controls on CVOC delineation and informs remediation design and monitoring.

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: depth- and strata-dependent spatial variability from rock-core sampling

USGS Publications Warehouse

Goode, Daniel J.; Imbrigiotta, Thomas E.; Lacombe, Pierre J.

2014-01-01

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently dipping mudstones. Despite more than 18 years of pump and treat (P&T) remediation, and natural attenuation processes, CVOC concentrations in aqueous samples pumped from these deeper strata remain elevated in isolated intervals. DNAPL was detected in one borehole during coring at a depth of 27 m. In contrast to core samples from the weathered zone, concentrations in core samples from deeper unweathered and unfractured strata are typically below detection. However, high CVOC concentrations were found in isolated samples from fissile black carbon-rich strata and fractured gray laminated strata. Aqueous-phase concentrations were correspondingly high in samples pumped from these strata via short-interval wells or packer-isolated zones in long boreholes. A refined conceptual site model considers that prior to P&T remediation groundwater flow was primarily subhorizontal in the higher-permeability near surface strata, and the bulk of contaminant mass was shallow. CVOCs diffused into these fractured and weathered mudstones. DNAPL and high concentrations of CVOCs migrated slowly down in deeper unweathered strata, primarily along isolated dipping bedding-plane fractures. After P&T began in 1995, using wells open to both shallow and deep strata, downward transport of dissolved CVOCs accelerated. Diffusion of TCE and other CVOCs from deeper fractures penetrated only a few centimeters into the unweathered rock matrix, likely due to sorption of CVOCs on rock organic carbon. Remediation in the deep, unweathered strata may benefit from the relatively limited migration of CVOCs into the rock matrix. Synthesis of rock core sampling from closely spaced boreholes with geophysical logging and hydraulic testing improves understanding of the controls on CVOC delineation and informs remediation design and monitoring.

Sedimentary characteristics and depositional model of a Paleocene-Eocene salt lake in the Jiangling Depression, China

NASA Astrophysics Data System (ADS)

Yu, Xiaocan; Wang, Chunlian; Liu, Chenglin; Zhang, Zhaochong; Xu, Haiming; Huang, Hua; Xie, Tengxiao; Li, Haonan; Liu, Jinlei

2015-11-01

We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation, thin section identification, scanning electron microscopy, and X-ray diffraction analysis. On the basis of sedimentary characteristics we have summarized the petrological and mineralogical characteristics of the salt lake and proposed 9 types of grade IV salt rhythms. The deposition shows a desalting to salting order of halite-argillaceous-mudstone-mud dolostonemud anhydrock-glauberite-halite. The relationship among grade IV rhythms, water salinity and climate fluctuations was analyzed. Based on the analysis of the relationship between boron content and mudstone color and by combining the mineralogy and sedimentary environment characteristics, we propose that the early and late Paleocene Shashi Formation in the Jiangling Depression was a paleolacustrine depositional environment with a high salt content, which is a representation of the shallow water salt lake depositional model. The middle Paleocene Shashi Formation and the early Eocene Xingouzui Formation were salt and brackish sedimentary environments with low salt content in a deep paleolake, which represents a deep salt lake depositional model.

Rock-Eval pyrolysis and vitrinite reflectance results from the Sheep Creek 1 well, Susitna basin, south-central Alaska

USGS Publications Warehouse

Stanley, Richard G.; Lillis, Paul G.; Pawlewicz, Mark J.; Haeussler, Peter J.

2014-01-01

We used Rock-Eval pyrolysis and vitrinite reflectance to examine the petroleum source potential of rock samples from the Sheep Creek 1 well in the Susitna basin of south-central Alaska. The results show that Miocene nonmarine coal, carbonaceous shale, and mudstone are potential sources of hydrocarbons and are thermally immature with respect to the oil window. In the samples that we studied, coals are more organic-rich and more oil-prone than carbonaceous shales and silty mudstones, which appear to be potential sources of natural gas. Lithologically similar rocks may be present in the deeper parts of the subsurface Susitna basin located west of the Sheep Creek 1 well, where they may have been buried deeply enough to generate oil and (or) gas. The Susitna basin is sparsely drilled and mostly unexplored, and no commercial production of hydrocarbons has been obtained. However, the existence of potential source rocks of oil and gas, as shown by our Rock-Eval results, suggests that undiscovered petroleum accumulations may be present in the Susitna basin.

Synthesis of Akaganeite in the Presence of Sulfate: Implications for Akaganeite Formation in Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Peretyazhko, T. S.; Fox, A.; Sutter, B.; Niles, P. B.; Adams, M.; Morris, R. V.; Ming, D. W.

2016-01-01

Akaganeite (beta-FeOOH) is an Fe(III) (hydr)oxide with a tunnel structure usually occupied by chloride. Akaganeite has been recently discovered in a mudstone on the surface of Mars by the Chemistry and Mineralogy (CheMin) and Sample Analysis at Mars (SAM) instruments onboard the Mars Science Laboratory (MSL) Curiosity Rover in Gale crater [1, 2]. Akaganeite was detected together with sulfate minerals [anhydrite (CaSO4) and basanite (2CaSO4·2H2O)] in the drilled Cumberland and John Clein mudstone samples at Yellowknife Bay [2]. Discovery of akaganeite and sulfates in the same samples suggests that sulfate ions could be present in aqueous solution during akaganeite formation. However, mechanism and aqueous environmental conditions of akaganeite formation (e.g., pH and range of sulfate concentration) in Yellowknife Bay remain unknown. The objective of our work was to perform synthesis of akaganeite without or with sulfate addition at variable pHs in order to constrain formation conditions of akaganeite in Yellowknife Bay, Gale crater on Mars.

A study on a instability slope in Taiwan subjected to rainfalls

NASA Astrophysics Data System (ADS)

Hsiao, D. H.; Hsieh, C. S.; Yeh, L. C.; Lin, D. Y.; T-A Phan, V.

2018-04-01

After the long-term monitoring on the Chaishan area in Taiwan from 2005 to 2012 by Kaohsiung City Government, the obtained results showed that annual lateral displacements in the region are about 7-8cm to the Taiwan Strait. The geological surface profiles of Chaishan area are in sequence weathered limestone, clay layer, limestone and mudstone layer, respectively. Thus the frictional resistance between weathered soils and rock layer could decrease after infiltration of rainwater due to impervious to water of the lowest mudstone layer. Typhoon invades often Taiwan each year, resulting in rainfall infiltration and rising groundwater level, as well as increased pore water pressure within the soil mass, causing the earth movements in some parts of Chaishan, especially in the Temple A (Shan Hai Temple) accompanied with cracking phenomenon. In this paper, limit equilibrium (LE) and finite element method (FEM) are used for slope analysis, in which the slope is considered as unsaturated soil. Results showed groundwater amounts are easy to accumulate and increasing pore water pressure give resulting in decreased safety factor. Both of groundwater level and rain durations were also considered in this study.

The Impact of Climate Change in Rainfall Erosivity Index on Humid Mudstone Area

NASA Astrophysics Data System (ADS)

Yang, Ci-Jian; Lin, Jiun-Chuan

2017-04-01

It has been quite often pointed out in many relevant studies that climate change may result in negative impacts on soil erosion. Then, humid mudstone area is highly susceptible to climate change. Taiwan has extreme erosion in badland area, with annual precipitation over 2000 mm/y which is a considerably 3 times higher than other badland areas around the world, and with around 9-13 cm/y in denudation rate. This is the reason why the Erren River, a badland dominated basin has the highest mean sediment yield in the world, over 105 t km2 y. This study aims to know how the climate change would affect soil erosion from the source in the Erren River catchment. Firstly, the data of hourly precipitation from 1992 to 2016 are used to establish the regression between rainfall erosivity index (R, one of component for USLE) and precipitation. Secondly, using the 10 climate change models (provide form IPCC AR5) simulates the changes of monthly precipitation in different scenario from 2017 to 2216, and then over 200 years prediction R values can be use to describe the tendency of soil erosion in the future. The results show that (1) the relationship between rainfall erosion index and precipitation has high correction (>0.85) during 1992-2016. (2) From 2017 to 2216, 7 scenarios show that annual rainfall erosion index will increase over 2-18%. In contrast, the others will decrease over 7-14%. Overall, the variations of annual rainfall erosion index fall in the range of -14 to 18%, but it is important to pay attention to the variation of annual rainfall erosion index in extreme years. These fall in the range of -34 to 239%. This explains the extremity of soil erosion will occur easily in the future. Keywords: Climate Change, Mudstone, Rainfall Erosivity Index, IPCC AR5

Similarities Across Mars: Acidic Fluids at Both Meridiani Planum and Gale Crater in the Formation of Magnesium-Nickel Sulfates

NASA Technical Reports Server (NTRS)

Yen, Albert S.; Ming, Douglas W.; Gellert, Ralf; Mittlefehldt, David W.; Vaniman, David T.; Thompson, Lucy M.; Morris, Richard V.; Clark, Benton C.; Arvidson, Raymond

2016-01-01

In-situ identification of sulfates at the martian surface by the Mars Exploration Rovers and the Mars Science Laboratory have included calcium sulfates with various states of hydration (gypsum, bassanite, anhydrite), iron sulfates of likely fumarolic origin, massive deposits of iron hydroxysulfates indicative of an acidic history, and minor occurrences of magnesium sulfates. Recent measurements by the Opportunity and Curiosity Alpha Particle X-ray Spectrometers (APXS) have indicated the presence of Ni-substituted Mg-sulfates at the Meridiani Planum and Gale Crater landing sites. The Opportunity rover has traversed nearly 43 km and is currently exploring the impact breccias of the rim of Endeavour crater, near a location where signatures of aqueous alteration have been established from orbit. APXS analyses of subsurface materials excavated by a rover wheel show clear evidence for a Mg(Ni)-sulfate with Mg:Ni (is) approximately 100:1 (molar). On the other side of the planet, Curiosity is continuing its climb up Mount Sharp after driving (is) approximately 13 km since landing. Over the last 4 km of the traverse, there have been multiple chemical analyses of erosionally-resistant nodules and dendritic features in a finely laminated mudstone unit which also indicate Mg(Ni)-sulfate (Mg:Ni (is) approximately 30:1, molar). The geologic settings for the Endeavour rim and the Mount Sharp mudstones are clearly different, but similar formation conditions for these sulfates may be possible. Ni(2+) readily substitutes for Mg(2+) in a variety of geochemical processes due to their comparable ionic radii. The availability of soluble Ni at the time of Mg-sulfate precipitation suggests acidic solutions. The fluids responsible for alteration in the Endeavour rim and for the formation of nodules in Gale mudstones may have had similar chemical characteristics at the time the Mg-sulfates were formed.

Evaluating the Poroelastic Effect on Anisotropic, Organic-Rich, Mudstone Systems

NASA Astrophysics Data System (ADS)

Suarez-Rivera, Roberto; Fjær, Erling

2013-05-01

Understanding the poroelastic effect on anisotropic organic-rich mudstones is of high interest and value for evaluating coupled effects of rock deformation and pore pressure, during drilling, completion and production operations in the oilfield. These applications include modeling and prevention of time-dependent wellbore failure, improved predictions of fracture initiation during hydraulic fracturing operations (Suarez-Rivera et al. Presented at the Canadian Unconventional Resources Conference held in Calgary, Alberta, Canada, 15-17 November 2011. CSUG/SPE 146998 2011), improved understanding of the evolution of pore pressure during basin development, including subsidence and uplift, and the equilibrated effective in situ stress (Charlez, Rock mechanics, vol 2 1997; Katahara and Corrigan, Pressure regimes in sedimentary basins and their prediction: AAPG Memoir, vol 76, pp 73-78 2002; Fjær et al. Petroleum related rock mechanics. 2nd edn 2008). In isotropic rocks, the coupled poro-elastic deformations of the solid framework and the pore fluids are controlled by the Biot and Skempton coefficients. These are the two fundamental properties that relate the rock framework and fluid compressibility and define the magnitude of the poroelastic effect. In transversely isotropic rocks, one desires to understand the variability of these coefficients along the directions parallel and longitudinal to the principal directions of material symmetry (usually the direction of bedding). These types of measurements are complex and uncommon in low-porosity rocks, and particularly problematic and scarce in tight shales. In this paper, we discuss a methodology for evaluating the Biot's coefficient, its variability along the directions parallel and perpendicular to bedding as a function of stress, and the homogenized Skempton coefficient, also as a function of stress. We also predict the pore pressure change that results during undrained compression. Most importantly, we provide values of transverse and longitudinal Biot's coefficients and the homogenized Skempton coefficient for two important North American, gas-producing, organic-rich mudstones. These results could be used for petroleum-related applications.

Silicic volcanism on Mars evidenced by tridymite in high-SiO2 sedimentary rock at Gale crater

NASA Astrophysics Data System (ADS)

Morris, Richard V.; Vaniman, David T.; Blake, David F.; Gellert, Ralf; Chipera, Steve J.; Rampe, Elizabeth B.; Ming, Douglas W.; Morrison, Shaunna M.; Downs, Robert T.; Treiman, Allan H.; Yen, Albert S.; Grotzinger, John P.; Achilles, Cherie N.; Bristow, Thomas F.; Crisp, Joy A.; Des Marais, David J.; Farmer, Jack D.; Fendrich, Kim V.; Frydenvang, Jens; Graff, Trevor G.; Morookian, John-Michael; Stolper, Edward M.; Schwenzer, Susanne P.

2016-06-01

Tridymite, a low-pressure, high-temperature (>870 °C) SiO2 polymorph, was detected in a drill sample of laminated mudstone (Buckskin) at Marias Pass in Gale crater, Mars, by the Chemistry and Mineralogy X-ray diffraction instrument onboard the Mars Science Laboratory rover Curiosity. The tridymitic mudstone has ˜40 wt.% crystalline and ˜60 wt.% X-ray amorphous material and a bulk composition with ˜74 wt.% SiO2 (Alpha Particle X-Ray Spectrometer analysis). Plagioclase (˜17 wt.% of bulk sample), tridymite (˜14 wt.%), sanidine (˜3 wt.%), cation-deficient magnetite (˜3 wt.%), cristobalite (˜2 wt.%), and anhydrite (˜1 wt.%) are the mudstone crystalline minerals. Amorphous material is silica-rich (˜39 wt.% opal-A and/or high-SiO2 glass and opal-CT), volatile-bearing (16 wt.% mixed cation sulfates, phosphates, and chlorides-perchlorates-chlorates), and has minor TiO2 and Fe2O3T oxides (˜5 wt.%). Rietveld refinement yielded a monoclinic structural model for a well-crystalline tridymite, consistent with high formation temperatures. Terrestrial tridymite is commonly associated with silicic volcanism, and detritus from such volcanism in a “Lake Gale” catchment environment can account for Buckskin's tridymite, cristobalite, feldspar, and any residual high-SiO2 glass. These cogenetic detrital phases are possibly sourced from the Gale crater wall/rim/central peak. Opaline silica could form during diagenesis from high-SiO2 glass, as amorphous precipitated silica, or as a residue of acidic leaching in the sediment source region or at Marias Pass. The amorphous mixed-cation salts and oxides and possibly the crystalline magnetite (otherwise detrital) are primary precipitates and/or their diagenesis products derived from multiple infiltrations of aqueous solutions having variable compositions, temperatures, and acidities. Anhydrite is post lithification fracture/vein fill.

Mesozoic lacustrine system in the Parnaíba Basin, northeastern Brazil: Paleogeographic implications for west Gondwana

NASA Astrophysics Data System (ADS)

Cardoso, Alexandre Ribeiro; Nogueira, Afonso César Rodrigues; Abrantes, Francisco Romério; Rabelo, Cleber Eduardo Neri

2017-03-01

The fragmentation of the West Gondwana during Early Triassic to Cretaceous was marked by intense climatic changes, concomitant with the establishment of extensive desertic/lacustrine systems. These deposits succeeded the emplacement and extrusion of lava flows, related to the pre-rift phase and initial opening of the Equatorial Atlantic Ocean. The thermal phase is recorded in the Upper Jurassic-Lower Cretaceous Pastos Bons Formation, exposed mainly in southeast parts of the Parnaíba Basin, Northeastern Brazil. The sedimentary facies of this unit were grouped in two facies associations (FA), representative of a shallow lacustrine system, influenced by episodic hyperpycnal and oscillatory flows. Central lake facies association (FA1) is composed by laminated mudstone (Ml), sandstone/mudstone rhythmite (S/Mr) and sandstone with even-parallel lamination (Sel). Flysch-like delta front (FA2) consists in sandstones with wave structures (Sw), sandstones with even-parallel stratification (Ses), massive sandstones (Sm), sandstones with soft-sediment deformation structures (Sd) and laminated mudstones (Ml). FA1 was deposited in the deepest portions of the lake, characterized by low energy, episodically disturbed by siliciclastic influx. FA2 presents sandy deposits generated by unconfined flow, probably fed by ephemeral stream flows that generated thickening upward of tabular sandstone beds. The progressive filling of the lake resulted in recurrent shoaling up of the water level and reworking by wave action. The installation of Pastos Bons lakes was controlled by thermal subsidence, mainly in restricted depocenters. The siliciclastic fluvial inflow can be related to the adjacent humid desertic facies, formed under climatic attenuation, typical of post-Triassic period, with reduced biological activity. Smectite and abundant feldspars, in lacustrine facies, corroborate an arid climate, with incipient chemical weathering. The new facies and stratigraphic data present in this paper provide an explanation about the implantation of a huge lacustrine system in the southern of Parnaiba Basin, with strong paleogeographic implications for the West-Central Gondwana during Late Jurassic to Early Cretaceous.

Diagenetic Features in Yellowknife Bay, Gale Crater, Mars: Implications for Substrate Rheology and Potential Gas Release

NASA Technical Reports Server (NTRS)

Kah, L. C.; Stack, K; Siebach, K.; Grotzinger, J.; Summer, D.; Farien, A.; Oehler, D.; Schieber, J.; Leville, R.; Edgar, L;

Involvement of magmatic fluids at the Laloki and Federal Flag massive sulfide Cu-Zn-Au-Ag deposits, Astrolabe mineral district, Papua New Guinea: sulfur isotope evidence

NASA Astrophysics Data System (ADS)

Noku, Shadrach K.; Espi, Joseph O.; Matsueda, Hiroharu

2015-01-01

We present the first sulfur (S) isotope data of sulfides, sulfates, pyrite in host mudstone, and bulk sulfur of gabbroic rocks from the Laloki and Federal Flag massive Cu-Zn-Au-Ag deposits in the Astrolabe mineral district, Papua New Guinea. Early-stage pyrite-marcasite, chalcopyrite, and sphalerite from Laloki display wide range of δ34S values from -4.5 to +7.0 ‰ ( n = 16). Late-stage pyrite, chalcopyrite, and sphalerite have restricted δ34S values of -1.9 to +4.7 ‰ ( n = 16). The mineralizing stage these correspond to had moderately saline (5.9-8.4 NaCl eq. wt%) mineralizing fluids of possible magmatic origin. A single analysis of late-stage barite has a value of δ34S +17.9 ‰, which is likely similar to coexisting seawater sulfate. Pyrite from the foot-wall mudstone at Laloki has very light δ34S values of -36.1 to -33.8 ‰ ( n = 2), which suggest an organic source for S. Pyrite-marcasite and chalcopyrite from Federal Flag show δ34S values of -2.4 to -1.9 ‰ ( n = 2), consistent with a magmatic origin, either leached from intrusive magmatic rocks or derived from magmatic-hydrothermal fluids. The very narrow range and near-zero δ34S values (-1.0 to +0.6 ‰) of bulk gabbroic samples is consistent with mantle-derived magmatic S. Sulfur isotope characteristics of sulfides and sulfates are, however, very similar to base metal sulfide accumulations associated with modern volcanic arcs and sedimented mid-ocean ridges. The most reasonable interpretation is that the range of the sulfide and sulfate δ34S values from both Laloki and Federal Flag massive sulfide deposits is indicative of the complex interaction of magmatic fluids, seawater, gabbroic rocks, and mudstone.

Sedimentology of Hirnantian glaciomarine deposits in the Balkan Terrane, western Bulgaria: Fixing a piece of the north peri-Gondwana jigsaw puzzle

NASA Astrophysics Data System (ADS)

Chatalov, Athanas

2017-04-01

Glaciomarine deposits of late Hirnantian age in the western part of the Palaeozoic Balkan Terrane have persistent thickness ( 7 m) and lateral uniformity in rock colour, bedding pattern, lithology, and sedimentary structures. Four lithofacies are distinguished from base to top: lonestone-bearing diamictites, interbedded structureless mudstones, crudely laminated diamictites, and finely laminated mudstones. The diamictites are clast-poor to clast-rich comprising muddy to sandy varieties. Their compositional maturity is evidenced by the very high amount of detrital quartz compared to the paucity of feldspar and unstable lithic grains. Other textural components include extraclasts derived from the local Ordovician basement, mudstone intraclasts, and sediment aggregates. Turbate structures, grain lineations, and soft sediment deformation of the matrix below larger grains are locally observed. Sedimentological analysis reveals that deposition occurred in an ice-intermediate to ice-distal, poorly agitated shelf environment by material supplied from meltwater buoyant plumes and rain-out from ice-rafted debris. Remobilization by mass-flow processes (cohesive debris flows and slumps) was an important mechanism particularly for the formation of massive diamictites. The glaciomarine deposits represent a typical deglaciation sequence reflecting retreat of the ice front (grounded or floating ice sheet), relative sea-level rise and gradually reduced sedimentation rate with increasing contribution from suspension fallout. This sequence was deposited on the non-glaciated shelf of the intracratonic North Gondwana platform along the southern margin of the Rheic Ocean. The Hirnantian strata of the Balkan Terrane can be correlated with similar glaciomarine deposits known from peri-Gondwana terranes elsewhere in Europe showing clear 'Armorican affinity'. Several lines of evidence suggest that the provenance of siliciclastic material was associated mainly with sedimentary recycling of mature sands which had been deposited across North Gondwana in Cambrian and pre-glacial Ordovician times.

Characterization and quantification of suspended sediment sources to the Manawatu River, New Zealand.

PubMed

Vale, S S; Fuller, I C; Procter, J N; Basher, L R; Smith, I E

2016-02-01

Knowledge of sediment movement throughout a catchment environment is essential due to its influence on the character and form of our landscape relating to agricultural productivity and ecological health. Sediment fingerprinting is a well-used tool for evaluating sediment sources within a fluvial catchment but still faces areas of uncertainty for applications to large catchments that have a complex arrangement of sources. Sediment fingerprinting was applied to the Manawatu River Catchment to differentiate 8 geological and geomorphological sources. The source categories were Mudstone, Hill Subsurface, Hill Surface, Channel Bank, Mountain Range, Gravel Terrace, Loess and Limestone. Geochemical analysis was conducted using XRF and LA-ICP-MS. Geochemical concentrations were analysed using Discriminant Function Analysis and sediment un-mixing models. Two mixing models were used in conjunction with GRG non-linear and Evolutionary optimization methods for comparison. Discriminant Function Analysis required 16 variables to correctly classify 92.6% of sediment sources. Geological explanations were achieved for some of the variables selected, although there is a need for mineralogical information to confirm causes for the geochemical signatures. Consistent source estimates were achieved between models with optimization techniques providing globally optimal solutions for sediment quantification. Sediment sources was attributed primarily to Mudstone, ≈38-46%; followed by the Mountain Range, ≈15-18%; Hill Surface, ≈12-16%; Hill Subsurface, ≈9-11%; Loess, ≈9-15%; Gravel Terrace, ≈0-4%; Channel Bank, ≈0-5%; and Limestone, ≈0%. Sediment source apportionment fits with the conceptual understanding of the catchment which has recognized soft sedimentary mudstone to be highly susceptible to erosion. Inference of the processes responsible for sediment generation can be made for processes where there is a clear relationship with the geomorphology, but is problematic for processes which occur within multiple terrains. Copyright © 2015 Elsevier B.V. All rights reserved.

Silicic volcanism on Mars evidenced by tridymite in high-SiO2 sedimentary rock at Gale crater

PubMed Central

Morris, Richard V.; Vaniman, David T.; Blake, David F.; Gellert, Ralf; Chipera, Steve J.; Rampe, Elizabeth B.; Ming, Douglas W.; Morrison, Shaunna M.; Downs, Robert T.; Treiman, Allan H.; Yen, Albert S.; Grotzinger, John P.; Achilles, Cherie N.; Bristow, Thomas F.; Crisp, Joy A.; Des Marais, David J.; Farmer, Jack D.; Fendrich, Kim V.; Graff, Trevor G.; Morookian, John-Michael; Stolper, Edward M.; Schwenzer, Susanne P.

2016-01-01

Tridymite, a low-pressure, high-temperature (>870 °C) SiO2 polymorph, was detected in a drill sample of laminated mudstone (Buckskin) at Marias Pass in Gale crater, Mars, by the Chemistry and Mineralogy X-ray diffraction instrument onboard the Mars Science Laboratory rover Curiosity. The tridymitic mudstone has ∼40 wt.% crystalline and ∼60 wt.% X-ray amorphous material and a bulk composition with ∼74 wt.% SiO2 (Alpha Particle X-Ray Spectrometer analysis). Plagioclase (∼17 wt.% of bulk sample), tridymite (∼14 wt.%), sanidine (∼3 wt.%), cation-deficient magnetite (∼3 wt.%), cristobalite (∼2 wt.%), and anhydrite (∼1 wt.%) are the mudstone crystalline minerals. Amorphous material is silica-rich (∼39 wt.% opal-A and/or high-SiO2 glass and opal-CT), volatile-bearing (16 wt.% mixed cation sulfates, phosphates, and chlorides−perchlorates−chlorates), and has minor TiO2 and Fe2O3T oxides (∼5 wt.%). Rietveld refinement yielded a monoclinic structural model for a well-crystalline tridymite, consistent with high formation temperatures. Terrestrial tridymite is commonly associated with silicic volcanism, and detritus from such volcanism in a “Lake Gale” catchment environment can account for Buckskin’s tridymite, cristobalite, feldspar, and any residual high-SiO2 glass. These cogenetic detrital phases are possibly sourced from the Gale crater wall/rim/central peak. Opaline silica could form during diagenesis from high-SiO2 glass, as amorphous precipitated silica, or as a residue of acidic leaching in the sediment source region or at Marias Pass. The amorphous mixed-cation salts and oxides and possibly the crystalline magnetite (otherwise detrital) are primary precipitates and/or their diagenesis products derived from multiple infiltrations of aqueous solutions having variable compositions, temperatures, and acidities. Anhydrite is post lithification fracture/vein fill. PMID:27298370

A lithology identification method for continental shale oil reservoir based on BP neural network

NASA Astrophysics Data System (ADS)

Han, Luo; Fuqiang, Lai; Zheng, Dong; Weixu, Xia

2018-06-01

The Dongying Depression and Jiyang Depression of the Bohai Bay Basin consist of continental sedimentary facies with a variable sedimentary environment and the shale layer system has a variety of lithologies and strong heterogeneity. It is difficult to accurately identify the lithologies with traditional lithology identification methods. The back propagation (BP) neural network was used to predict the lithology of continental shale oil reservoirs. Based on the rock slice identification, x-ray diffraction bulk rock mineral analysis, scanning electron microscope analysis, and the data of well logging and logging, the lithology was divided with carbonate, clay and felsic as end-member minerals. According to the core-electrical relationship, the frequency histogram was then used to calculate the logging response range of each lithology. The lithology-sensitive curves selected from 23 logging curves (GR, AC, CNL, DEN, etc) were chosen as the input variables. Finally, the BP neural network training model was established to predict the lithology. The lithology in the study area can be divided into four types: mudstone, lime mudstone, lime oil-mudstone, and lime argillaceous oil-shale. The logging responses of lithology were complicated and characterized by the low values of four indicators and medium values of two indicators. By comparing the number of hidden nodes and the number of training times, we found that the number of 15 hidden nodes and 1000 times of training yielded the best training results. The optimal neural network training model was established based on the above results. The lithology prediction results of BP neural network of well XX-1 showed that the accuracy rate was over 80%, indicating that the method was suitable for lithology identification of continental shale stratigraphy. The study provided the basis for the reservoir quality and oily evaluation of continental shale reservoirs and was of great significance to shale oil and gas exploration.

Late Devonian glacigenic and associated facies from the central Appalachian Basin, eastern United States

USGS Publications Warehouse

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.

2010-01-01

Late Devonian strata in the eastern United States are generally considered as having been deposited under warm tropical conditions. However, a stratigraphically restricted Late Devonian succession of diamictite- mudstonesandstone within the Spechty Kopf and Rockwell Formations that extends for more than 400 km along depositional strike within the central Appalachian Basin may indicate other wise. This lithologic association unconformably overlies the Catskill Formation, where a 3- to 5-m-thick interval of deformed strata occurs immediately below the diamictite strata. The diamictite facies consists of several subfacies that are interpreted to be subglacial, englacial, supraglacial meltout, and resedimented deposits. The mudstone facies that overlies the diamictite consists of subfacies of chaotically bedded, clast-poor mudstone, and laminated mudstone sub facies that represent subaqueous proximal debris flows and distal glaciolacustrine rhythmites or varvites, respectively. The pebbly sandstone facies is interpreted as proglacial braided outwash deposits that both preceded glacial advance and followed glacial retreat. Both the tectonic and depositional frameworks suggest that the facies were deposited in a terrestrial setting within the Appalachian foreland basin during a single glacial advance and retreat. Regionally, areas that were not covered by ice were subject to increased rainfall as indicated by wet-climate paleosols. River systems eroded deeper channels in response to sea-level drop during glacial advance. Marine facies to the west contain iceborne dropstone boulders preserved within contemporaneous units of the Cleveland Shale Member of the Ohio Shale.The stratigraphic interval correlative with sea-level drop, climate change, and glacigenic succession represents one of the Appalachian Basin's most prolific oil-and gas-producing intervals and is contemporaneous with a global episode of sea-level drop responsible for the deposition of the Hangenberg Shale/Sandstone of Europe. This interval records the Hangenberg biotic crisis near the Devonian-Carboniferous boundary. ?? 2009 Geological Society of America.

Detailed anatomy of a deep-water carbonate breccia lobe (Upper Jurassic, French subalpine basin)

NASA Astrophysics Data System (ADS)

Courjault, Thomas; Grosheny, Danièle; Ferry, Serge; Sausse, Judith

2011-06-01

Detailed correlations across Tithonian carbonate breccia deposits in the Drôme River area (northern part of the so-called "Vocontian Through") suggest the depositional system was that of an elongated deep-water lobe, up to 70 km long and 20 to 30 km wide, for a thickness reaching 200 m. The Drôme lobe, as it is now called, is mainly made of slope to basinal mudstones breccias with minor platform components, interpreted as debris flow and mud flow deposits, associated with slump deposits. It is basically a base-of-slope system, whose elongated depositional area implies it was a "point-sourced" gravity system, thus perhaps connected to a small canyon cut onto the western slope of the basin. But the mostly mudstone material of the breccias also suggests that the walls of this inferred canyon were the main supplier of the lobe, not the carbonate platform proper. The updip part of the lobe has a complex internal geometry as the deposition of breccia bed packages is interrupted by scourings locally 50 m-deep, indicating maybe a canyon mouth environment. The middle part of the lobe is dominated by pure vertical aggradation of breccia beds with minor intervening erosion. In the downdip part of the system a morphological compensation mechanism occurs as breccia beds tend to spread laterally. A huge slump carrying large mudstone olistoliths ends the breccia deposition at the beginning of the Berriasian. This megaslump deposit was mostly emplaced on the right side of the breccia lobe supporting the idea of a depositional relief. Our observations thus show that previous interpretations as a submarine canyon infilling or as shallow-water breccias formed in-situ by cyclic loading under attenuating hurricane waves approaching the platform are not consistent with our observations. The internal geometry of the system studied brings new data about a poorly-studied kind of "turbidite" systems that of deep-water carbonate breccias.

Sedimentology of the fluvial and fluvio-marine facies of the Bahariya Formation (Early Cenomanian), Bahariya Oasis, Western Desert, Egypt

NASA Astrophysics Data System (ADS)

Khalifa, M. A.; Catuneanu, O.

2008-05-01

The Lower Cenomanian Bahariya Formation in the Bahariya Oasis, Western Desert, Egypt, was deposited under two coeval environmental conditions. A fully fluvial system occurs in the southern portion of the Bahariya Oasis, including depositional products of meandering and braided streams, and a coeval fluvio-marine setting is dominant to the north. These deposits are organized into four unconformity-bounded depositional sequences, whose architecture is shaped by a complex system of incised valleys. The fluvial portion of the lower two depositional sequences is dominated by low-energy, meandering systems with a tabular geometry, dominated by overbank facies. The fluvial deposits of the upper two sequences represent the product of sedimentation within braided streams, and consist mainly of amalgamated channel-fills. The braided fluvial systems form the fill of incised valleys whose orientation follows a southeast-northwest trending direction, and which truncate the underlying sequences. Four sedimentary facies have been identified within the braided-channel systems, namely thin-laminated sandstones (Sh), cross-bedded sandstones (Sp, St), massive ferruginous sandstones (Sm) and variegated mudstones (Fm). The exposed off-channel overbank facies of the meandering systems include floodplain (Fm) and crevasse splay (Sl) facies. The fluvio-marine depositional systems consist of interbedded floodplain, coastal and shallow-marine deposits. The floodplain facies include fine-grained sandstones (Sf), laminated siltstones (Stf) and mudstones (Mf) that show fining-upward cycles. The coastal to shallow-marine facies consist primarily of mudstones (Mc) and glauconitic sandstones (Gc) organized vertically in coarsening-upward prograding cyclothems topped by thin crusts of ferricrete (Fc). The four depositional sequences are present across the Bahariya Oasis, albeit with varying degrees of preservation related to post-depositional erosion associated with the formation of sequence boundaries. These unconformities may be overlain by braided-stream channel sandstones at the base of incised valleys, or marked by ferricrete paleosols (lithofacies Fc) in the interfluve areas.

Shallow lacustrine system of the Permian Pedra de Fogo Formation, Western Gondwana, Parnaíba Basin, Brazil

NASA Astrophysics Data System (ADS)

Araújo, Raphael Neto; Nogueira, Afonso César Rodrigues; Bandeira, José; Angélica, Rômulo Simões

2016-04-01

The Permian Period of the Parnaíba Basin, northern Brazil, represented here by deposits from the Pedra de Fogo Formation, records important events that occurred in Western Gondwana near its boundary with the Mesozoic Era. The analysis of outcrop based facies from the Permian Pedra de Fogo Formation, which is 100 m thick, carried out along the eastern and western borders of the Parnaiba Basin, allowed the identification of eleven sedimentary facies, which were grouped into three distinct facies associations (FA), representative of a shallow lacustrine system associated with mudflats and ephemeral rivers. Bioturbation, desiccation cracks, silcretes and various siliceous concretions characterize the Pedra de Fogo deposits. The FA1 mudflat deposits occur predominantly at the base of the Pedra de Fogo Formation and consist of laminated claystone/mudstone, mudcrack-bearing sandstones/mudstones and sandstones exhibiting cross-lamination, massive and megaripple bedding. Popcorn-like silicified nodules and casts indicate evaporite deposits. Other common features are silica concretions, silicified tepees and silcretes. FA2 represents nearshore deposits and consists of fine-grained sandstones with evenly parallel lamination, climbing ripple cross-lamination, massive and megaripple bedding and mudstone/siltstone showing evenly parallel lamination. FA3 refers to wadi/inundite deposits, generally organized as fining-upward cycles of metric size, composed of conglomerates and medium-grained pebbly sandstones showing massive bedding and cross-stratification, as well as claystone/siltstone showing evenly parallel to undulate lamination. Scour-and-fill features are isolated in predominantly tabular deposits composed of mudstones interbedded with fine to medium-grained sandstones showing planar to slightly undulate lamination. Silicified plant remains previously classified as belonging to the Psaronius genus found in the uppermost levels of the Pedra de Fogo Formation, near the contact with the Motuca Formation, are considered here as excellent biostratigraphic markers. Fish remains, ostracods, bryozoans and scolecodonts represent other fossils that are present in the succession. Mudflat deposits developed in an arid and hot climate probably in the Early Permian. Semi-arid conditions prevailed in the Middle Permian allowing the proliferation of fauna and flora in adjacent humid regions and onto the lake margin. The climate variation was responsible for the contraction and expansion phases of the lake, fed by sporadic sheet floods carrying plant remains. The reestablishment of the arid climate, at the end of Permian, marks the final sedimentation of the Pedra de Fogo Formation, linked to the consolidation of the Pangaea Supercontinent. This last event was concomitant with the deposition of the Motuca Formation red beds and the development of extensive ergs related to the Triassic Sambaíba Formation in Western Gondwana.

Re-Os systematics and age of pyrite associated with stratiform Zn-Pb mineralization in the Howards Pass district, Yukon and Northwest Territories, Canada

NASA Astrophysics Data System (ADS)

Kelley, Karen D.; Selby, David; Falck, Hendrik; Slack, John F.

2017-03-01

Stratiform Zn-Pb deposits hosted in unmetamorphosed carbonaceous and siliceous mudstones of the Ordovician to Silurian Duo Lake Formation define the Howards Pass district in Yukon Territory and Northwest Territories, western Canada. Collectively, the deposits are amongst the largest in the world, containing drill-indicated and inferred resources of 423 Mt at 4.84 % Zn and 1.59 % Pb. Sulphide textures include (a) fine-scale laminations of sphalerite, galena, and pyrite from <0.05 mm to 1 cm thick, interbedded with carbonaceous sedimentary rock; (b) layers of coarse sulphide that are structurally controlled by microfolds; and (c) veins that cut bedding and sulphide laminations. The finely interlaminated nature of sulphides with mudstone has been used as evidence for syngenetic mineralizing processes, whereas paleomagnetic data determined on coarse layered sulphides suggest a Middle Jurassic age of mineralization. Here, we present new rhenium-osmium (Re-Os) isotopic data for 12 pyrite separates obtained from 4 laminated sulphide-rich samples from the XY Central (XYC) and Don (DON) deposits and for 1 unmineralized organic-rich mudstone ˜20 m stratigraphically below the sulphide-bearing zone. Pyrite separates that lack mudstone inclusions ("pure") from the XYC deposit contain 2.2 to 4.0 ppb Re and 93.4 to 123.4 ppt Os; pure pyrite from the DON deposit is significantly more enriched in Re and Os (34-37 ppb Re; 636.8-694.9 ppt Os). The 187Re/188Os values of pure pyrite separates from the XYC and DON deposits range from 137.6 to 197 and 182.1 to 201.4, respectively. Regression of all pure pyrite Re-Os data from both deposits yields an isochron age of 442 ± 14 Ma (MSWD = 7.4) and an initial 187Os/188Os (Osi) value of 0.71 ± 0.07. The Re-Os age indicates that the early phase of pyrite precipitation (and by inference, sphalerite and galena) occurred during the early Silurian, consistent with biostratigraphic ages of the host rocks. The Osi value of ˜0.8 for earliest Silurian seawater recorded from organic-rich shale in the basal Silurian Global Stratotype Section and Point (GSSP) at Dobs Linn, Scotland is very similar to that provided by the Howards Pass pyrite regression and hence suggests a hydrogenous (seawater) source of Os for the pyrite. Therefore, two possible sources of Os are (1) the Zn- and Pb-bearing hydrothermal fluid that leached Os from footwall sedimentary rocks, which were deposited in seawater, or (2) directly from seawater during precipitation of the pyrite, which suggests that the Os content of the hydrothermal fluid was minor relative to that of seawater.

Paleoenvironmental Implications of Clay Minerals at Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Bristow, Thomas F.; Blake, David F.

2014-01-01

The Mars Science Laboratory (MSL) Rover, Curiosity spent approx 150 sols at Yellowknife Bay (YKB) studying a section of fluvio-lacustrine sedimentary rocks (with potential indications of volcanic influence), informally known as the Yellowknife Bay formation. YKB lies in a distal region of the Peace Vallis alluvial fan, which extends from the northern rim of Gale Crater toward the dune field at the base of Mt Sharp. Sedimentological and stratigraphic observations are consistent with the Yellowknife Bay formation being part of a distal fan deposit, which could be as young as middle Hesperian to even early Amazonian in age (approx. 3.5 to 2.5 Ga). The Yellowknife Bay formation hosts a unit of mudstone called the Sheepbed member. Curiosity obtained powdered rock samples from two drill holes in the Sheepbed Member, named John Klein and Cumberland, and delivered them to instruments in Curiosity. Data from CheMin, a combined X-ray diffraction (XRD)/X-ray fluorescence instrument (XRF), has allowed detailed mineralogical analysis of mudstone powders revealing a clay mineral component of approx. 20 wt.% in each sample. The clay minerals are important indicators of paleoenvironmental conditions and sensitive recorders of post-depositional alteration processes. The XRD pattern of John Klein reveals a 02l band consistent with a trioctahedral phyllosilicate. A broad peak at approx. 10A with a slight inflexion at approx. 12A indicates the presence of 2:1 type clay minerals in the John Klein sample. The trioctahedral nature of the clay minerals, breadth of the basal reflection, and presence of a minor component with larger basal spacing suggests that John Klein contains a trioctahedral smectite (probably saponite), whose interlayer is largely collapsed because of the low-humidity conditions. The XRD patterns show no evidence of corrensite (mixed-layer chlorite/smectite) or chlorite, which are typical diagenetic products of trioctahedral smectites when subjected to burial and heating >60 C in the presence of water. Given estimated geothermal gradients on Mars temperatures <60 C might still be consistent with (but do not require) moderate burial. However, our ability to identify interstratified minerals is greatly limited by the lack of access to traditional treatments methods used in the lab (e.g., ethylene glycol solvation). Our preferred explanation for the origin of trioctahedral smectites in Sheepbed mudstone is in situ production via reaction of olivine, water and Si-bearing amorphous material, an important mudstone component detected by XRD. Elevated levels of magnetite in the Sheepbed and the trioctahedral monomineralic nature of the clay minerals support this model. These observations, combined with previous studies of olivine stability, support the persistence of circum-neutral hydrous conditions for thousands of years at YKB.

The First X-ray Diffraction Patterns of Clay Minerals from Gale Crater

NASA Astrophysics Data System (ADS)

Bristow, T.; Blake, D.; Bish, D. L.; Vaniman, D.; Ming, D. W.; Morris, R. V.; Chipera, S.; Rampe, E. B.; Farmer, J. D.; Treiman, A. H.; Downs, R.; Morrison, S.; Achilles, C.; Des Marais, D. J.; Crisp, J. A.; Sarrazin, P.; Morookian, J.; Grotzinger, J. P.; Team, M.

2013-12-01

The Mars Science Laboratory (MSL) Rover, Curiosity spent ~150 sols at Yellowknife Bay (YKB) studying a section of fluvio-lacustrine sedimentary rocks (with potential indications of volcanic influence), informally known as the Yellowknife Bay formation. YKB lies in a distal region of the Peace Vallis alluvial fan, which extends from the northern rim of Gale Crater toward the dune field at the base of Mt Sharp. Sedimentological and stratigraphic observations are consistent with the Yellowknife Bay formation being part of a distal fan deposit, which could be as young as middle Hesperian to even early Amazonian in age (~3.5 to 2.5 Ga). The Yellowknife Bay formation hosts a unit of mudstone called the Sheepbed member. Curiosity obtained powdered rock samples from two drill holes in the Sheepbed Member, named John Klein and Cumberland, and delivered them to instruments in Curiosity. Data from CheMin, a combined X-ray diffraction (XRD)/X-ray fluorescence instrument (XRF), has allowed detailed mineralogical analysis of mudstone powders revealing a clay mineral component of ~20 wt.% in each sample. The clay minerals are important indicators of paleoenvironmental conditions and sensitive recorders of post-depositional alteration processes. The XRD pattern of John Klein reveals a 02l band consistent with a trioctahedral phyllosilicate. A broad peak at ~10A with a slight inflexion at ~12A indicates the presence of 2:1 type clay minerals in the John Klein sample. The trioctahedral nature of the clay minerals, breadth of the basal reflection, and presence of a minor component with larger basal spacing suggests that John Klein contains a trioctahedral smectite (probably saponite), whose interlayer is largely collapsed because of the low-humidity conditions. The XRD patterns show no evidence of corrensite (mixed-layer chlorite/smectite) or chlorite, which are typical diagenetic products of trioctahedral smectites when subjected to burial and heating >60°C in the presence of water. Given estimated geothermal gradients on Mars temperatures <60 °C might still be consistent with (but do not require) moderate burial. However, our ability to identify interstratified minerals is greatly limited by the lack of access to traditional treatments methods used in the lab (e.g., ethylene glycol solvation). Our preferred explanation for the origin of trioctahedral smectites in Sheepbed mudstone is in situ production via reaction of olivine, water and Si-bearing amorphous material, an important mudstone component detected by XRD. Elevated levels of magnetite in the Sheepbed and the trioctahedral monomineralic nature of the clay minerals support this model. These observations, combined with previous studies of olivine stability, support the persistence of circum-neutral hydrous conditions for thousands of years at YKB.

The First X-ray Diffraction Patterns of Clay Minerals from Gale Crater

NASA Technical Reports Server (NTRS)

Bristow, Thomas; Blake, David; Bish, David L.; Vaniman, David; Ming, Douglas W.; Morris, Richard V.; Chipera, Steve; Rampe, Elizabeth B.; Farmer, Jack, D.; Treiman, Allan H;

Configuration of the mudstones, gray- and coffee-colored shale lithologic units, zones of silica and epidote, and their relation to the tectonics of the Cerro Prieto geothermal field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cobo R, J.M.

1981-01-01

Based on well cuttings, five lithological units have been recognized within the area of what is now the Cerro Prieto geothermal field. These five units are described. Differences in origin, mineralogy, grading, color, compaction, etc., are shown.

Mars Rover Mastcam View of Possible Mud Cracks

NASA Image and Video Library

2017-01-17

This view of a Martian rock slab called "Old Soaker," which has a network of cracks that may have originated in drying mud, comes from the Mast Camera (Mastcam) on NASA's Curiosity Mars rover. The location is within an exposure of Murray formation mudstone on lower Mount Sharp inside Gale Crater. Mud cracks would be evidence of a time more than 3 billion years ago when dry intervals interrupted wetter periods that supported lakes in the area. Curiosity has found evidence of ancient lakes in older, lower-lying rock layers and also in younger mudstone that is above Old Soaker. Several images from Mastcam's left-eye camera are combined into this mosaic view. They were taken on Dec. 20, 2016, during the 1,555th Martian day, or sol, of Curiosity's work on Mars. The Old Soaker slab is about 4 feet (1.2 meters) long. Figure 1 includes a scale bar of 30 centimeters (12 inches). The scene is presented with a color adjustment that approximates white balancing, to resemble how the rocks and sand would appear under daytime lighting conditions on Earth. http://photojournal.jpl.nasa.gov/catalog/PIA21262

Evidence for indigenous nitrogen in sedimentary and aeolian deposits from the Curiosity rover investigations at Gale crater, Mars

PubMed Central

Stern, Jennifer C.; Sutter, Brad; Freissinet, Caroline; Navarro-González, Rafael; McKay, Christopher P.; Archer, P. Douglas; Buch, Arnaud; Brunner, Anna E.; Coll, Patrice; Eigenbrode, Jennifer L.; Fairen, Alberto G.; Franz, Heather B.; Glavin, Daniel P.; Kashyap, Srishti; McAdam, Amy C.; Ming, Douglas W.; Steele, Andrew; Szopa, Cyril; Wray, James J.; Martín-Torres, F. Javier; Zorzano, Maria-Paz; Conrad, Pamela G.; Mahaffy, Paul R.; Kemppinen, Osku; Bridges, Nathan; Johnson, Jeffrey R.; Minitti, Michelle; Cremers, David; Bell, James F.; Edgar, Lauren; Farmer, Jack; Godber, Austin; Wadhwa, Meenakshi; Wellington, Danika; McEwan, Ian; Newman, Claire; Richardson, Mark; Charpentier, Antoine; Peret, Laurent; King, Penelope; Blank, Jennifer; Weigle, Gerald; Schmidt, Mariek; Li, Shuai; Milliken, Ralph; Robertson, Kevin; Sun, Vivian; Baker, Michael; Edwards, Christopher; Ehlmann, Bethany; Farley, Kenneth; Griffes, Jennifer; Grotzinger, John; Miller, Hayden; Newcombe, Megan; Pilorget, Cedric; Rice, Melissa; Siebach, Kirsten; Stack, Katie; Stolper, Edward; Brunet, Claude; Hipkin, Victoria; Léveillé, Richard; Marchand, Geneviève; Sánchez, Pablo Sobrón; Favot, Laurent; Cody, George; Steele, Andrew; Flückiger, Lorenzo; Lees, David; Nefian, Ara; Martin, Mildred; Gailhanou, Marc; Westall, Frances; Israël, Guy; Agard, Christophe; Baroukh, Julien; Donny, Christophe; Gaboriaud, Alain; Guillemot, Philippe; Lafaille, Vivian; Lorigny, Eric; Paillet, Alexis; Pérez, René; Saccoccio, Muriel; Yana, Charles; Armiens-Aparicio, Carlos; Rodríguez, Javier Caride; Blázquez, Isaías Carrasco; Gómez, Felipe Gómez; Gómez-Elvira, Javier; Hettrich, Sebastian; Malvitte, Alain Lepinette; Jiménez, Mercedes Marín; Martínez-Frías, Jesús; Martín-Soler, Javier; - Torres, F. Javier Martín; Jurado, Antonio Molina; Mora-Sotomayor, Luis; Caro, Guillermo Muñoz; López, Sara Navarro; Peinado-González, Verónica; Pla-García, Jorge; Manfredi, José Antonio Rodriguez; Romeral-Planelló, Julio José; Fuentes, Sara Alejandra Sans; Martinez, Eduardo Sebastian; Redondo, Josefina Torres; Urqui-O'Callaghan, Roser; Mier, María-Paz Zorzano; Chipera, Steve; Lacour, Jean-Luc; Mauchien, Patrick; Sirven, Jean-Baptiste; Manning, Heidi; Fairén, Alberto; Hayes, Alexander; Joseph, Jonathan; Squyres, Steven; Sullivan, Robert; Thomas, Peter; Dupont, Audrey; Lundberg, Angela; Melikechi, Noureddine; Mezzacappa, Alissa; DeMarines, Julia; Grinspoon, David; Reitz, Günther; Prats, Benito; Atlaskin, Evgeny; Genzer, Maria; Harri, Ari-Matti; Haukka, Harri; Kahanpää, Henrik; Kauhanen, Janne; Kemppinen, Osku; Paton, Mark; Polkko, Jouni; Schmidt, Walter; Siili, Tero; Fabre, Cécile; Wray, James; Wilhelm, Mary Beth; Poitrasson, Franck; Patel, Kiran; Gorevan, Stephen; Indyk, Stephen; Paulsen, Gale; Gupta, Sanjeev; Bish, David; Schieber, Juergen; Gondet, Brigitte; Langevin, Yves; Geffroy, Claude; Baratoux, David; Berger, Gilles; Cros, Alain; d’Uston, Claude; Forni, Olivier; Gasnault, Olivier; Lasue, Jérémie; Lee, Qiu-Mei; Maurice, Sylvestre; Meslin, Pierre-Yves; Pallier, Etienne; Parot, Yann; Pinet, Patrick; Schröder, Susanne; Toplis, Mike; Lewin, Éric; Brunner, Will; Heydari, Ezat; Achilles, Cherie; Oehler, Dorothy; Sutter, Brad; Cabane, Michel; Coscia, David; Israël, Guy; Szopa, Cyril; Dromart, Gilles; Robert, François; Sautter, Violaine; Le Mouélic, Stéphane; Mangold, Nicolas; Nachon, Marion; Buch, Arnaud; Stalport, Fabien; Coll, Patrice; François, Pascaline; Raulin, François; Teinturier, Samuel; Cameron, James; Clegg, Sam; Cousin, Agnès; DeLapp, Dorothea; Dingler, Robert; Jackson, Ryan Steele; Johnstone, Stephen; Lanza, Nina; Little, Cynthia; Nelson, Tony; Wiens, Roger C.; Williams, Richard B.; Jones, Andrea; Kirkland, Laurel; Treiman, Allan; Baker, Burt; Cantor, Bruce; Caplinger, Michael; Davis, Scott; Duston, Brian; Edgett, Kenneth; Fay, Donald; Hardgrove, Craig; Harker, David; Herrera, Paul; Jensen, Elsa; Kennedy, Megan R.; Krezoski, Gillian; Krysak, Daniel; Lipkaman, Leslie; Malin, Michael; McCartney, Elaina; McNair, Sean; Nixon, Brian; Posiolova, Liliya; Ravine, Michael; Salamon, Andrew; Saper, Lee; Stoiber, Kevin; Supulver, Kimberley; Van Beek, Jason; Van Beek, Tessa; Zimdar, Robert; French, Katherine Louise; Iagnemma, Karl; Miller, Kristen; Summons, Roger; Goesmann, Fred; Goetz, Walter; Hviid, Stubbe; Johnson, Micah; Lefavor, Matthew; Lyness, Eric; Breves, Elly; Dyar, M. Darby; Fassett, Caleb; Blake, David F.; Bristow, Thomas; DesMarais, David; Edwards, Laurence; Haberle, Robert; Hoehler, Tori; Hollingsworth, Jeff; Kahre, Melinda; Keely, Leslie; McKay, Christopher; Wilhelm, Mary Beth; Bleacher, Lora; Brinckerhoff, William; Choi, David; Conrad, Pamela; Dworkin, Jason P.; Eigenbrode, Jennifer; Floyd, Melissa; Freissinet, Caroline; Garvin, James; Glavin, Daniel; Harpold, Daniel; Jones, Andrea; Mahaffy, Paul; Martin, David K.; McAdam, Amy; Pavlov, Alexander; Raaen, Eric; Smith, Michael D.; Stern, Jennifer; Tan, Florence; Trainer, Melissa; Meyer, Michael; Posner, Arik; Voytek, Mary; Anderson, Robert C; Aubrey, Andrew; Beegle, Luther W.; Behar, Alberto; Blaney, Diana; Brinza, David; Calef, Fred; Christensen, Lance; Crisp, Joy A.; DeFlores, Lauren; Ehlmann, Bethany; Feldman, Jason; Feldman, Sabrina; Flesch, Gregory; Hurowitz, Joel; Jun, Insoo; Keymeulen, Didier; Maki, Justin; Mischna, Michael; Morookian, John Michael; Parker, Timothy; Pavri, Betina; Schoppers, Marcel; Sengstacken, Aaron; Simmonds, John J.; Spanovich, Nicole; Juarez, Manuel de la Torre; Vasavada, Ashwin R.; Webster, Christopher R.; Yen, Albert; Archer, Paul Douglas; Cucinotta, Francis; Jones, John H.; Ming, Douglas; Morris, Richard V.; Niles, Paul; Rampe, Elizabeth; Nolan, Thomas; Fisk, Martin; Radziemski, Leon; Barraclough, Bruce; Bender, Steve; Berman, Daniel; Dobrea, Eldar Noe; Tokar, Robert; Vaniman, David; Williams, Rebecca M. E.; Yingst, Aileen; Lewis, Kevin; Leshin, Laurie; Cleghorn, Timothy; Huntress, Wesley; Manhès, Gérard; Hudgins, Judy; Olson, Timothy; Stewart, Noel; Sarrazin, Philippe; Grant, John; Vicenzi, Edward; Wilson, Sharon A.; Bullock, Mark; Ehresmann, Bent; Hamilton, Victoria; Hassler, Donald; Peterson, Joseph; Rafkin, Scot; Zeitlin, Cary; Fedosov, Fedor; Golovin, Dmitry; Karpushkina, Natalya; Kozyrev, Alexander; Litvak, Maxim; Malakhov, Alexey; Mitrofanov, Igor; Mokrousov, Maxim; Nikiforov, Sergey; Prokhorov, Vasily; Sanin, Anton; Tretyakov, Vladislav; Varenikov, Alexey; Vostrukhin, Andrey; Kuzmin, Ruslan; Clark, Benton; Wolff, Michael; McLennan, Scott; Botta, Oliver; Drake, Darrell; Bean, Keri; Lemmon, Mark; Schwenzer, Susanne P.; Anderson, Ryan B.; Herkenhoff, Kenneth; Lee, Ella Mae; Sucharski, Robert; Hernández, Miguel Ángel de Pablo; Ávalos, Juan José Blanco; Ramos, Miguel; Kim, Myung-Hee; Malespin, Charles; Plante, Ianik; Muller, Jan-Peter; Navarro-González, Rafael; Ewing, Ryan; Boynton, William; Downs, Robert; Fitzgibbon, Mike; Harshman, Karl; Morrison, Shaunna; Dietrich, William; Kortmann, Onno; Palucis, Marisa; Sumner, Dawn Y.; Williams, Amy; Lugmair, Günter; Wilson, Michael A.; Rubin, David; Jakosky, Bruce; Balic-Zunic, Tonci; Frydenvang, Jens; Jensen, Jaqueline Kløvgaard; Kinch, Kjartan; Koefoed, Asmus; Madsen, Morten Bo; Stipp, Susan Louise Svane; Boyd, Nick; Campbell, John L.; Gellert, Ralf; Perrett, Glynis; Pradler, Irina; VanBommel, Scott; Jacob, Samantha; Owen, Tobias; Rowland, Scott; Atlaskin, Evgeny; Savijärvi, Hannu; Boehm, Eckart; Böttcher, Stephan; Burmeister, Sönke; Guo, Jingnan; Köhler, Jan; García, César Martín; Mueller-Mellin, Reinhold; Wimmer-Schweingruber, Robert; Bridges, John C.; McConnochie, Timothy; Benna, Mehdi; Franz, Heather; Bower, Hannah; Brunner, Anna; Blau, Hannah; Boucher, Thomas; Carmosino, Marco; Atreya, Sushil; Elliott, Harvey; Halleaux, Douglas; Rennó, Nilton; Wong, Michael; Pepin, Robert; Elliott, Beverley; Spray, John; Thompson, Lucy; Gordon, Suzanne; Newsom, Horton; Ollila, Ann; Williams, Joshua; Vasconcelos, Paulo; Bentz, Jennifer; Nealson, Kenneth; Popa, Radu; Kah, Linda C.; Moersch, Jeffrey; Tate, Christopher; Day, Mackenzie; Kocurek, Gary; Hallet, Bernard; Sletten, Ronald; Francis, Raymond; McCullough, Emily; Cloutis, Ed; ten Kate, Inge Loes; Kuzmin, Ruslan; Arvidson, Raymond; Fraeman, Abigail; Scholes, Daniel; Slavney, Susan; Stein, Thomas; Ward, Jennifer; Berger, Jeffrey; Moores, John E.

2015-01-01

The Sample Analysis at Mars (SAM) investigation on the Mars Science Laboratory (MSL) Curiosity rover has detected oxidized nitrogen-bearing compounds during pyrolysis of scooped aeolian sediments and drilled sedimentary deposits within Gale crater. Total N concentrations ranged from 20 to 250 nmol N per sample. After subtraction of known N sources in SAM, our results support the equivalent of 110–300 ppm of nitrate in the Rocknest (RN) aeolian samples, and 70–260 and 330–1,100 ppm nitrate in John Klein (JK) and Cumberland (CB) mudstone deposits, respectively. Discovery of indigenous martian nitrogen in Mars surface materials has important implications for habitability and, specifically, for the potential evolution of a nitrogen cycle at some point in martian history. The detection of nitrate in both wind-drifted fines (RN) and in mudstone (JK, CB) is likely a result of N2 fixation to nitrate generated by thermal shock from impact or volcanic plume lightning on ancient Mars. Fixed nitrogen could have facilitated the development of a primitive nitrogen cycle on the surface of ancient Mars, potentially providing a biochemically accessible source of nitrogen. PMID:25831544

Evidence for indigenous nitrogen in sedimentary and aeolian deposits from the Curiosity rover investigations at Gale crater, Mars.

PubMed

Stern, Jennifer C; Sutter, Brad; Freissinet, Caroline; Navarro-González, Rafael; McKay, Christopher P; Archer, P Douglas; Buch, Arnaud; Brunner, Anna E; Coll, Patrice; Eigenbrode, Jennifer L; Fairen, Alberto G; Franz, Heather B; Glavin, Daniel P; Kashyap, Srishti; McAdam, Amy C; Ming, Douglas W; Steele, Andrew; Szopa, Cyril; Wray, James J; Martín-Torres, F Javier; Zorzano, Maria-Paz; Conrad, Pamela G; Mahaffy, Paul R

2015-04-07

The Sample Analysis at Mars (SAM) investigation on the Mars Science Laboratory (MSL) Curiosity rover has detected oxidized nitrogen-bearing compounds during pyrolysis of scooped aeolian sediments and drilled sedimentary deposits within Gale crater. Total N concentrations ranged from 20 to 250 nmol N per sample. After subtraction of known N sources in SAM, our results support the equivalent of 110-300 ppm of nitrate in the Rocknest (RN) aeolian samples, and 70-260 and 330-1,100 ppm nitrate in John Klein (JK) and Cumberland (CB) mudstone deposits, respectively. Discovery of indigenous martian nitrogen in Mars surface materials has important implications for habitability and, specifically, for the potential evolution of a nitrogen cycle at some point in martian history. The detection of nitrate in both wind-drifted fines (RN) and in mudstone (JK, CB) is likely a result of N2 fixation to nitrate generated by thermal shock from impact or volcanic plume lightning on ancient Mars. Fixed nitrogen could have facilitated the development of a primitive nitrogen cycle on the surface of ancient Mars, potentially providing a biochemically accessible source of nitrogen.

Silurian pinnacle reefs of the Canadian Arctic

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Freitas, T.A.; Dixon, O.A.; Mayr, U.

1993-04-01

Pinnacle reefs are commonly an attractive target for oil exploration because they are usually porous carbonate bodies entombed in impervious, deep-water shales that provide both the source and the seal for hydrocarbons. Silurian pinnacle reefs, the first described in the Canadian Arctic Archipelago, are exposed on Ellesmere and Devon Islands. Two main reef trends occur, one of early middle Llandovery to middle Ludlow age and a second of middle Ludlow to Late Silurian or Early Devonian age. Reefs of both phases contain lime mudstone cores: some are stromatactoid-rich and others consist predominantly of microbialite-rich lime mudstone or microbial boundstone. Faciesmore » sequences of both reef phases show evidence of upward-shallowing overall, but, in the older reefs, isochronous capping facies are dominated either by coral-mirian or by stromatoporoid boundstone and floatstone. This difference perhaps reflects variation in wave stress and apparent ability of a few corals,thickly encrusted by or associated with microbial boundstone and skeletal algae, to withstand greater wave energy than a stromatoporoid-coral-rich reef community. These reefs constitute one of the bright prospects of hydrocarbon exploration in rocks of the Franklinian succession. 43 refs., 9 figs.« less

Sedimentary and petrofacies analyses of the Amasiri Sandstone, southern Benue Trough, Nigeria: Implications for depositional environment and tectonic provenance

NASA Astrophysics Data System (ADS)

Okoro, A. U.; Igwe, E. O.; Nwajide, C. S.

2016-11-01

This study was undertaken to determine the depositional environment, provenance and tectonic setting for the Turonian Amasiri Sandstone, southern Benue Trough, Nigeria, using lithofacies analysis and re-appraisal of petrography of the sandstones. Local stratigraphy and field relationships show a thick succession of shales alternating with elongate/parallel sandstone ridges extending eastwards from Akpoha to Amasiri through Itigidi and Ugep to Apiapum areas. Lithofacies analysis reveals 9 lithofacies suggestive of storm (mass flow) and tidal shelf processes. These include dark grey to black laminated shale/silty mudstones, bioturbated mudstones, coquinoid limestones, very fine-grained bioturbated sandstones with shell hash/debris in places and limestone rip-up clasts, massive and chaotic sandy conglomerate with rip - up clasts, fine to medium-grained, parallel laminated sandstone, hummocky cross-stratified, massive, medium to coarse-grained sandstones, medium to very coarse-grained, planar cross-bedded sandstone, with clay-draped foresets and Ophiomorpha burrows, and coarse-grained trough cross-bedded sandstone. Petrofacies analysis identifies the sandstones as feldspathic and arkosic arenites. Ternary plot of framework mineralogy indicates derivation from an uplifted continental block related to the nearby Oban Massif and Cameroon Basement Complex.

The volcano-sedimentary succession of Upper Permian in Wuli area, central Qinghai-Tibetan Plateau: Sedimentology, geochemistry and paleogeography

NASA Astrophysics Data System (ADS)

Liu, Shengqian; Jiang, Zaixing; Gao, Yi

2017-04-01

Detailed observations on cores and thin sections well documented a volcano-sedimentary succession from Well TK2, which is located in Wuli area, central Qinghai-Tibetan Plateau. The TK2 volcano-sedimentary succession reflects an active sedimentary-tectonic setting in the north margin of North Qiangtang-Chamdo terrane in the late Permian epoch. Based on the observation and recognition on lithology and mineralogy, the components of TK2 succession are mainly volcanic and volcaniclastic rocks and four main lithofacies are recognized, including massive volcanic lithofacies (LF1), pyroclastic tuff lithofacies (LF2), tuffaceous sandstone lithofacies (LF3) and mudstone lithofacies (LF4). LF1 is characterized by felsic components, massive structure and porphyrotopic structure with local flow structure, which indicates submarine intrusive domes or extrusion-fed lavas that formed by magma ascents via faults or dykes. Meanwhile, its eruption style may reflect a relative high pressure compensation level (PCL) that mainly determined by water depth, which implies a deep-water environment. LF2 is composed of volcanic lapilli or ash and featured with massive structure, parallel bedding and various deformed laminations including convolve structure, slide deformation, ball-and-pillow structure, etc.. LF2 indicates the sedimentation of initial or reworked explosive products not far away from volcano centers, reflecting the proximal accumulation of volcano eruption-fed clasts or their resedimentation as debris flows. In addition, the submarine volcano eruptions may induced earthquakes that facilitate the resedimentation of unconsolidated sediments. LF3 contains abundant pyroclastic components and is commonly massive with rip-up mudstone clasts or usually interbedded with LF4. In addition, typical flute casts, scour structures and graded beddings in thin-interbedded layers of sandstone and mudstone are commonly observed, which also represents the sedimentation of debris flows or turbidity flows in a relative deep-water environment. LF4 indicates suspension deposits of distal turbidity sediments in deeper-water setting, which is mainly tuffaceous and ordinary mudstone, commonly interbedded with thin pyroclastic layers. Geochemically, the felsic volcanic rocks belong to tholeiitic to calc-alkaline series, exhibiting characteristics of right-leaning rare earth element (REE) patterns with conspicuous Eu negative anomalies, enrichments in large ion lithophile elements (LILEs) and depletions in high field-strength elements (HFSEs), which reflect an island arc environment that corresponds to the late-Permian subduction of slabs. The TK2 volcanic-sedimentary succession reveals a submarine volcano-dominated depositional model and proves the existence of a deeper water environment, at least in a restricted zone of Wuli area. However, the traditional sedimentary and paleogeographic knowledges are mostly about coal-forming transitional facies in stable environment. Therefore, the proposing of a deep-water volcano-sedimentary model will provide a further comprehension of paleogeography in southern Qinghai at late-Permian, which will also supplement the previous cognition of stable ocean-land transitional environments and provide a new sight to the paleogeographic framework of late-Permian in North Qiangtang-Chamdo terrane.

Mineralogy of Mudstone at Gale Crater, Mars: Evidence for Dynamic Lacustrine Environments

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Ming, D. W.; Grotzinger, J. P.; Morris, R. V.; Blake, D. F.; Vaniman, D. T.; Bristow, T. F.; Yen, A. S.; Chipera, S. J.; Morrison, S. M.;

Possible effects of two-phase flow pattern on the mechanical behavior of mudstones

NASA Astrophysics Data System (ADS)

Goto, H.; Tokunaga, T.; Aichi, M.

2016-12-01

To investigate the influence of two-phase flow pattern on the mechanical behavior of mudstones, laboratory experiments were conducted. In the experiment, air was injected from the bottom of the water-saturated Quaternary Umegase mudstone sample under hydrostatic external stress condition. Both axial and circumferential strains at half the height of the sample and volumetric discharge of water at the outlet were monitored during the experiment. Numerical simulation of the experiment was tried by using a simulator which can solve coupled two-phase flow and poroelastic deformation assuming the extended-Darcian flow with relative permeability and capillary pressure as functions of the wetting-phase fluid saturation. In the numerical simulation, the volumetric discharge of water was reproduced well while both strains were not. Three dimensionless numbers, i.e., the viscosity ratio, the Capillary number, and the Bond number, which characterize the two-phase flow pattern (Lenormand et al., 1988; Ewing and Berkowitz, 1998) were calculated to be 2×10-2, 2×10-11, and 7×10-11, respectively, in the experiment. Because the Bond number was quite small, it was possible to apply Lenormand et al. (1988)'s diagram to evaluate the flow regime, and the flow regime was considered to be capillary fingering. While, in the numerical simulation, air moved uniformly upward with quite low non-wetting phase saturation conditions because the fluid flow obeyed the two-phase Darcy's law. These different displacement patterns developed in the experiment and assumed in the numerical simulation were considered to be the reason why the deformation behavior observed in the experiment could not be reproduced by numerical simulation, suggesting that the two-phase flow pattern could affect the changes of internal fluid pressure patterns during displacement processes. For further studies, quantitative analysis of the experimental results by using a numerical simulator which can solve the coupled processes of two-phase flow through preferential flow paths and deformation of porous media is needed. References: Ewing R. P., and B. Berkowitz (1998), Water Resour. Res., 34, 611-622. Lenormand, R., E. Touboul, and C. Zarcone (1988), J. Fluid Mech., 189, 165-187.

Sedimentation in a Submarine Seamount Apron at Site U1431, International Ocean Discovery Program Expedition 349, South China Sea

NASA Astrophysics Data System (ADS)

Dadd, K. A.; Clift, P. D.; Hyun, S.; Jiang, T.; Liu, Z.

2014-12-01

International Ocean Discovery Program (IODP) Expedition 349 Site U1431 is located near the relict spreading ridge in the East Subbasin of the South China Sea. Holes at this site were drilled close to seamounts and intersected the volcaniclastic apron. Volcaniclastic breccia and sandstone at Site U1431 are dated as late middle Miocene to early late Miocene (~8-13 Ma), suggesting a 5 m.y. duration of seamount volcanism. The apron is approximately 200 m thick and is sandwiched between non-volcaniclastic units that represent the background sedimentation. These comprise dark greenish gray clay, silt, and nannofossil ooze interpreted as turbidite and hemipelagic deposits that accumulated at abyssal water depths. At its base, the seamount sequence begins with dark greenish gray sandstone, siltstone, and claystone in upward fining sequences interpreted as turbidites intercalated with minor intervals of volcaniclastic breccia. Upsection the number and thickness of breccia layers increases with some beds up to 4.8 m and possibly 14.5 m thick. The breccia is typically massive, ungraded, and poorly sorted with angular to subangular basaltic clasts, as well as minor reworked subrounded calcareous mudstone, mudstone, and sandstone clasts. Basaltic clasts include nonvesicular aphyric basalt, sparsely vesicular aphyric basalt, highly vesicular aphyric basalt, and nonvesicular glassy basalt. Mudstone clasts are clay rich and contain foraminifer fossils. The matrix comprises up to 40% of the breccia beds and is a mix of clay, finer grained altered basalt clasts, and mafic vitroclasts with rare foraminifer fossils. Some layers have calcite cement between clasts. Volcaniclastic sandstone and claystone cycles interbedded with the breccia layers have current ripples and parallel laminations indicative of high-energy flow conditions during sedimentation. The breccia beds were most likely deposited as a series of debris flows or grain flows. This interpretation is supported by their massive structure, poor sorting, and reverse-graded bases. The upper part of the apron grades back into the background clay, silt and nannofossil ooze sedimentation with minor volcaniclastic sand and silt.

The origin and implications of clay minerals from Yellowknife Bay, Gale crater, Mars†

PubMed Central

Bristow, Thomas F.; Bish, David L.; Vaniman, David T.; Morris, Richard V.; Blake, David F.; Grotzinger, John P.; Rampe, Elizabeth B.; Crisp, Joy A.; Achilles, Cherie N.; Ming, Doug W.; Ehlmann, Bethany L.; King, Penelope L.; Bridges, John C.; Eigenbrode, Jennifer L.; Sumner, Dawn Y.; Chipera, Steve J.; Moorokian, John Michael; Treiman, Allan H.; Morrison, Shaunna M.; Downs, Robert T.; Farmer, Jack D.; Marais, David Des; Sarrazin, Philippe; Floyd, Melissa M.; Mischna, Michael A.; McAdam, Amy C.

2016-01-01

The Mars Science Laboratory (MSL) rover Curiosity has documented a section of fluvio-lacustrine strata at Yellowknife Bay (YKB), an embayment on the floor of Gale crater, approximately 500 m east of the Bradbury landing site. X-ray diffraction (XRD) data and evolved gas analysis (EGA) data from the CheMin and SAM instruments show that two powdered mudstone samples (named John Klein and Cumberland) drilled from the Sheepbed member of this succession contain up to ~20 wt% clay minerals. A trioctahedral smectite, likely a ferrian saponite, is the only clay mineral phase detected in these samples. Smectites of the two samples exhibit different 001 spacing under the low partial pressures of H2O inside the CheMin instrument (relative humidity <1%). Smectite interlayers in John Klein collapsed sometime between clay mineral formation and the time of analysis to a basal spacing of 10 Å, but largely remain open in the Cumberland sample with a basal spacing of ~13.2 Å. Partial intercalation of Cumberland smectites by metal-hydroxyl groups, a common process in certain pedogenic and lacustrine settings on Earth, is our favored explanation for these differences. The relatively low abundances of olivine and enriched levels of magnetite in the Sheepbed mudstone, when compared with regional basalt compositions derived from orbital data, suggest that clay minerals formed with magnetite in situ via aqueous alteration of olivine. Mass-balance calculations are permissive of such a reaction. Moreover, the Sheepbed mudstone mineral assemblage is consistent with minimal inputs of detrital clay minerals from the crater walls and rim. Early diagenetic fabrics suggest clay mineral formation prior to lithification. Thermodynamic modeling indicates that the production of authigenic magnetite and saponite at surficial temperatures requires a moderate supply of oxidants, allowing circum-neutral pH. The kinetics of olivine alteration suggest the presence of fluids for thousands to hundreds of thousands of years. Mineralogical evidence of the persistence of benign aqueous conditions at YKB for extended periods indicates a potentially habitable environment where life could establish itself. Mediated oxidation of Fe2+ in olivine to Fe3+ in magnetite, and perhaps in smectites provided a potential energy source for organisms. PMID:28798492

Magnetite Authigenesis and the Ancient Martian Atmosphere

NASA Astrophysics Data System (ADS)

Tosca, N. J.; Ahmed, I. A.; Ashpitel, A.; Hurowitz, J.

2017-12-01

Although the Curiosity rover has documented lacustrine sediments at Gale Crater, how liquid water became physically stable is unknown. The early Martian atmosphere is thought to have been dominated by CO2 [1], but the Curiosity rover has provided only ambiguous detections of carbonate minerals at abundances significantly less than 1 wt. % [2, 3], and climate models indicate that in the absence of additional components, multi-bar CO2 atmospheres could not have maintained surface temperatures above freezing. To constrain the composition of the ancient Martian atmosphere, we experimentally investigated the nucleation and growth kinetics of authigenic Fe(II)-minerals in Gale Crater mudstones. Experiments show that as basaltic waters experience pH increases above 8.0, a series of anoxic mineral transformations generates magnetite in days. Electrochemical and dissolved gas analyses show that one stage of this process, the conversion of Fe(OH)2 to green rust, generates H2(g). Experiments including dissolved CO2 show that, despite magnetite formation, Fe(II)-carbonate does not nucleate until significant supersaturation is reached, at PCO2 levels far above previous estimates. Our experimental observations imply that Gale Crater lakes could have been in contact with a CO2-rich atmosphere. In addition, geochemical calculations show that groundwater infiltration into lacustrine sediments triggered magnetite and H2(g) generation at Gale Crater (instead of Fe(II)-carbonate cementation). Groundwater infiltration is consistent with data from the Sheepbed member mudstones, and deep-water mudstones of the Murray formation, both of which contain abundant authigenic magnetite [2, 4]. Low temperature H2 production may have provided a globally significant but transient feedback for stabilizing liquid water on early Mars. Data collected to date by the Curiosity rover are consistent with both estimated timescales and climatic shifts associated with H2-induced warming. Low temperature H2 production also implies that a wide range of biologically relevant chemical reactions may have been operative on the early Martian surface. [1] J. Pollack, et al. (1987) Icarus 71, 203-24. [2] D. Vaniman et al., (2014) Science 343, 8. [3] D. Ming, et al., (2014) Science 343, 1245267. [4] J. Hurowitz, et al. (2017) Science 356, 922.

The origin and implications of clay minerals from Yellowknife Bay, Gale crater, Mars.

PubMed

Bristow, Thomas F; Bish, David L; Vaniman, David T; Morris, Richard V; Blake, David F; Grotzinger, John P; Rampe, Elizabeth B; Crisp, Joy A; Achilles, Cherie N; Ming, Doug W; Ehlmann, Bethany L; King, Penelope L; Bridges, John C; Eigenbrode, Jennifer L; Sumner, Dawn Y; Chipera, Steve J; Moorokian, John Michael; Treiman, Allan H; Morrison, Shaunna M; Downs, Robert T; Farmer, Jack D; Marais, David Des; Sarrazin, Philippe; Floyd, Melissa M; Mischna, Michael A; McAdam, Amy C

2015-04-01

The Mars Science Laboratory (MSL) rover Curiosity has documented a section of fluvio-lacustrine strata at Yellowknife Bay (YKB), an embayment on the floor of Gale crater, approximately 500 m east of the Bradbury landing site. X-ray diffraction (XRD) data and evolved gas analysis (EGA) data from the CheMin and SAM instruments show that two powdered mudstone samples (named John Klein and Cumberland) drilled from the Sheepbed member of this succession contain up to ~20 wt% clay minerals. A trioctahedral smectite, likely a ferrian saponite, is the only clay mineral phase detected in these samples. Smectites of the two samples exhibit different 001 spacing under the low partial pressures of H 2 O inside the CheMin instrument (relative humidity <1%). Smectite interlayers in John Klein collapsed sometime between clay mineral formation and the time of analysis to a basal spacing of 10 Å, but largely remain open in the Cumberland sample with a basal spacing of ~13.2 Å. Partial intercalation of Cumberland smectites by metal-hydroxyl groups, a common process in certain pedogenic and lacustrine settings on Earth, is our favored explanation for these differences. The relatively low abundances of olivine and enriched levels of magnetite in the Sheepbed mudstone, when compared with regional basalt compositions derived from orbital data, suggest that clay minerals formed with magnetite in situ via aqueous alteration of olivine. Mass-balance calculations are permissive of such a reaction. Moreover, the Sheepbed mudstone mineral assemblage is consistent with minimal inputs of detrital clay minerals from the crater walls and rim. Early diagenetic fabrics suggest clay mineral formation prior to lithification. Thermodynamic modeling indicates that the production of authigenic magnetite and saponite at surficial temperatures requires a moderate supply of oxidants, allowing circum-neutral pH. The kinetics of olivine alteration suggest the presence of fluids for thousands to hundreds of thousands of years. Mineralogical evidence of the persistence of benign aqueous conditions at YKB for extended periods indicates a potentially habitable environment where life could establish itself. Mediated oxidation of Fe 2+ in olivine to Fe 3+ in magnetite, and perhaps in smectites provided a potential energy source for organisms.

The Role of Microfossils in the Compression of Marine Sediments: Implications for Submarine Slope Failure

NASA Astrophysics Data System (ADS)

Reece, J. S.; Shackleton, T.

2016-12-01

The influence of microfossils on engineering properties has long been recognized. However, most experimental studies have been conducted on diatomites, which are almost exclusively composed of diatom fossils. Here, instead, we analyze the impact of varying amounts of microfossils in natural marine sediments on the macro-scale mechanical behavior. We use foraminifera as an example for microfossils, which, in contrast to diatoms, have been understudied. We uniformly mix foraminifera with natural mudstone from Site C0011 in the Nankai Trough, offshore Japan, obtained during Integrated Ocean Drilling Program (IODP) Expedition 322, at three different microfossil concentrations: 0 wt%, 5 wt%, and 10 wt%. The foraminifera, extracted by washing and sieving, originated from IODP Site U1338 in the Equatorial Pacific. We use resedimentation to prepare the homogeneous microfossil-rich mudstone samples and uniaxially compress them to 100 kPa. Additionally, we use scanning electron microscopy to investigate microstructural changes during compression as a function of microfossil content. Microfossil-rich sediments are known to initially not consolidate to as low porosities as other marine clays owing to microfossil shells acting as structural components. But they show a delayed compressibility when the yield stress is overcome and microfossil shells collapse resulting in an increase in porosity and compressibility. Here, we investigate the 1) threshold microfossil content at which the microfabric significantly changes during compression and 2) stress at which foraminifera chambers start to break. We anticipate to observe an increase in compressibility and microstructural changes in the vicinity of the yield stress with increasing microfossil content attributed to the crushing of foraminifera and particle rearrangement. But the total axial stress of 100 kPa at the end of the resedimentation experiments may not be large enough to have a significant effect on the macroscopic mudstone properties. This study has large implications for submarine slope failure due to the possible sudden expulsion of water causing a pore pressure increase, which may destabilize continental slopes, and cause a hazard for coastal communities and offshore infrastructure.

Lower Eocene alluvial paleosols (Willwood Formation, Northwest Wyoming, U.S.A.) and their significance for paleoecology, paleoclimatology, and basin analysis

USGS Publications Warehouse

Bown, Thomas M.; Kraus, M.J.

1981-01-01

The lower Eocene Willwood Formation of northwest Wyoming is a 700 m thick accumulation of alluvial floodplain and channel mudstones and sandstones, nearly all of which show paleopedogenic modifications. Pedogenesis of Willwood sandstones is indicated by taproot and vertebrate and invertebrate bioturbation, early local cementation by calcium carbonate, and thin illuviation cutans on clastic grains. Pedogenesis in Willwood mudstones is indicated by plant bioturbation, insect and other invertebrate burrow casts and lebensspuren; free iron, aluminum, and manganese mobilization, including hydromorphic gleying; sesquioxide and calcareous glaebule formation in lower parts of the solum; presence of clay-rich and organic carbon-rich zones; and well differentiated epipedons and albic and spodic horizons. Probable A horizons are also locally well developed.Occurrence of variegated paleosol units in thick floodplain mudstone deposits and their association with thin, lenticular, and unconnected fluvial sandstones in the Willwood Formation of the central and southeast Bighorn Basin suggest that these soils formed during times of rapid sediment accumulation. The tabular geometry and lateral persistence of soil units as well as the absence of catenization indicate that Willwood floodplains were broad and essentially featureless.All Willwood paleosols were developed on alluvial parent materials and are complex in that B horizons of younger paleosols were commonly superimposed upon and mask properties of suspected A and B horizons of the next older paleosols. The soils appear to be wet varieties of the Spodosol and Entisol groups (aquods and ferrods, and aquents, respectively), though thick, superposed and less mottled red, purple, and yellow paleosols resemble some ultisols. Most Willwood paleosols resemble warm temperate to subtropical alluvial soils that form today under alternating wet and dry conditions and (or) fluctuating water tables. The up-section decrease in frequency of gley mottles, increase in numerical proportion and thickness of red versus orange coloration, and increase in abundance of calcrete glaebules indicate better drained soils and probably drier climate in late Willwood time. This drying is believed to be related to creation of rain shadows and spacing of rainfall (but not necessarily decrease in absolute rainfall) due to progressive tectonic structural elevation of the mountainous margins of the Bighorn Basin.

Regional Surface Waves from Mesabi Range Mine Blasts (Northern Minnesota)

DTIC Science & Technology

1991-10-29

rocks within the Archean basement which underlies the Animikie basin near the source areas. The final analysis was two dimensional raytracing which...overlying the Archean basement. Overlying the Pokegama Quartzite is the Biwabik Iron Formation and the Virginia Formation (Morey, 1983, Southwick and others...composed of intercalated mudstone and siltstone turbidite deposits which thicken and coarsen progressively from north to south across the basin (Morey and

In-situ stresses in low-permeability, nonmarine rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warpinski, N.R.; Teufel, L.W.

In-situ stress measurements have been performed over a 2,500-ft (760-m) interval in the nonmarine section of the Cretaceous Mesaverde in the Piceance basin in Colorado. These measurements included 52 hydraulic fracture measurements of the minimum in-situ stress and 22 anelastic strain recovery (ASR) measurements. Stress data obtained in sandstones, shales, mudstones, siltstones, and coals show the effect of lithology on the magnitudes of the stresses.

Spatial niche partitioning in dinosaurs from the latest cretaceous (Maastrichtian) of North America.

PubMed

Lyson, Tyler R; Longrich, Nicholas R

2011-04-22

We examine patterns of occurrence of associated dinosaur specimens (n = 343) from the North American Upper Cretaceous Hell Creek Formation and equivalent beds, by comparing their relative abundance in sandstone and mudstone. Ceratopsians preferentially occur in mudstone, whereas hadrosaurs and the small ornithopod Thescelosaurus show a strong association with sandstone. By contrast, the giant carnivore Tyrannosaurus rex shows no preferred association with either lithology. These lithologies are used as an indicator of environment of deposition, with sandstone generally representing river environments, and finer grained sediments typically representing floodplain environments. Given these patterns of occurrence, we argue that spatial niche partitioning helped reduce competition for resources between the herbivorous dinosaurs. Within coastal lowlands ceratopsians preferred habitats farther away from rivers, whereas hadrosaurs and Thescelosaurus preferred habitats in close proximity to rivers, and T. rex, the ecosystem's sole large carnivore, inhabited both palaeoenvironments. Spatial partitioning of the environment helps explain how several species of large herbivorous dinosaurs coexisted. This study emphasizes that different lithologies can preserve dramatically dissimilar vertebrate assemblages, even when deposited in close proximity and within a narrow window of time. The lithology in which fossils are preserved should be recorded as these data can provide unique insights into the palaeoecology of the animals they preserve.

Spatial niche partitioning in dinosaurs from the latest cretaceous (Maastrichtian) of North America

PubMed Central

Lyson, Tyler R.; Longrich, Nicholas R.

2011-01-01

We examine patterns of occurrence of associated dinosaur specimens (n = 343) from the North American Upper Cretaceous Hell Creek Formation and equivalent beds, by comparing their relative abundance in sandstone and mudstone. Ceratopsians preferentially occur in mudstone, whereas hadrosaurs and the small ornithopod Thescelosaurus show a strong association with sandstone. By contrast, the giant carnivore Tyrannosaurus rex shows no preferred association with either lithology. These lithologies are used as an indicator of environment of deposition, with sandstone generally representing river environments, and finer grained sediments typically representing floodplain environments. Given these patterns of occurrence, we argue that spatial niche partitioning helped reduce competition for resources between the herbivorous dinosaurs. Within coastal lowlands ceratopsians preferred habitats farther away from rivers, whereas hadrosaurs and Thescelosaurus preferred habitats in close proximity to rivers, and T. rex, the ecosystem's sole large carnivore, inhabited both palaeoenvironments. Spatial partitioning of the environment helps explain how several species of large herbivorous dinosaurs coexisted. This study emphasizes that different lithologies can preserve dramatically dissimilar vertebrate assemblages, even when deposited in close proximity and within a narrow window of time. The lithology in which fossils are preserved should be recorded as these data can provide unique insights into the palaeoecology of the animals they preserve. PMID:20943689

Fluids during diagenesis and sulfate vein formation in sediments at Gale crater, Mars

NASA Astrophysics Data System (ADS)

Schwenzer, S. P.; Bridges, J. C.; Wiens, R. C.; Conrad, P. G.; Kelley, S. P.; Leveille, R.; Mangold, N.; Martín-Torres, J.; McAdam, A.; Newsom, H.; Zorzano, M. P.; Rapin, W.; Spray, J.; Treiman, A. H.; Westall, F.; Fairén, A. G.; Meslin, P.-Y.

2016-11-01

We model the fluids involved in the alteration processes recorded in the Sheepbed Member mudstones of Yellowknife Bay (YKB), Gale crater, Mars, as revealed by the Mars Science Laboratory Curiosity rover investigations. We compare the Gale crater waters with fluids modeled for shergottites, nakhlites, and the ancient meteorite ALH 84001, as well as rocks analyzed by the Mars Exploration rovers, and with terrestrial ground and surface waters. The aqueous solution present during sediment alteration associated with phyllosilicate formation at Gale was high in Na, K, and Si; had low Mg, Fe, and Al concentrations—relative to terrestrial groundwaters such as the Deccan Traps and other modeled Mars fluids; and had near neutral to alkaline pH. Ca and S species were present in the 10-3 to 10-2 concentration range. A fluid local to Gale crater strata produced the alteration products observed by Curiosity and subsequent evaporation of this groundwater-type fluid formed impure sulfate- and silica-rich deposits—veins or horizons. In a second, separate stage of alteration, partial dissolution of this sulfate-rich layer in Yellowknife Bay, or beyond, led to the pure sulfate veins observed in YKB. This scenario is analogous to similar processes identified at a terrestrial site in Triassic sediments with gypsum veins of the Mercia Mudstone Group in Watchet Bay, UK.

Carbon and Sulfur Isotopic Composition of Yellowknife Bay Sediments: Measurements by the Sample Analysis at Mars (SAM) Quadrupole Mass Spectrometer

NASA Technical Reports Server (NTRS)

Franz, H. B.; Mahaffy, P. R.; Stern, J. C.; Eigenbrode, J. L.; Steele, A.; Ming, D. W.; McAdam, A. C.; Freissinet, C.; Glavin, D. P.; Archer, P. D.;

Anatomy of biocalcarenitic units in the Plio-Pleistocene record of the Northern Apennines (Italy)

NASA Astrophysics Data System (ADS)

Cau, Simone; Roveri, Marco; Taviani, Marco

2017-04-01

The Castell'Arquato Basin (CAB) in the foothills of the thrust-belt Northern Apennines is a foreland basin infilled by Plio-Quaternary sediments and a reference area for Plio-Pleistocene biostratigraphy. The CAB exposes plurimetric biodetrital carbonate units at discrete temporal intervals. Such shell-rich units are at places lithified, turning into conspicuous biodetritral carbonate rocks (biocalcarenites) that display a cyclical stacking motif highlighted by the regular alternation with finer-grained marine deposits. The cyclical nature of thick biocalcarenites has been hypothesized to be orbitally-controlled by obliquity and/or precession cyclicity. Furthermore, biocalcarenite-mudstone couplets form distinct clusters governed by 100-400 ka eccentricity maxima starting from 3.1 Ma at the inception of the Northern Hemisphere glaciation. They correlate with sapropels cycles formed at times of maximum insolation (precession minima). The CAB calcarenites are poorly known with respect to their environmental genetic context what motivated a detailed paleoecological analysis to unravel at best their formative context. Five distinct biofacies arranged in stacking patterns are identified through two-way cluster analysis based on the macrofossil content. Our quantitative and qualitative results suggest that these polytaxic shell concentrations and their bracketing marine mudstones developed in middle shelf settings being sensitive to climatically-driven changes.

The first X-ray diffraction measurements on Mars.

PubMed

Bish, David; Blake, David; Vaniman, David; Sarrazin, Philippe; Bristow, Thomas; Achilles, Cherie; Dera, Przemyslaw; Chipera, Steve; Crisp, Joy; Downs, R T; Farmer, Jack; Gailhanou, Marc; Ming, Doug; Morookian, John Michael; Morris, Richard; Morrison, Shaunna; Rampe, Elizabeth; Treiman, Allan; Yen, Albert

2014-11-01

The Mars Science Laboratory landed in Gale crater on Mars in August 2012, and the Curiosity rover then began field studies on its drive toward Mount Sharp, a central peak made of ancient sediments. CheMin is one of ten instruments on or inside the rover, all designed to provide detailed information on the rocks, soils and atmosphere in this region. CheMin is a miniaturized X-ray diffraction/X-ray fluorescence (XRD/XRF) instrument that uses transmission geometry with an energy-discriminating CCD detector. CheMin uses onboard standards for XRD and XRF calibration, and beryl:quartz mixtures constitute the primary XRD standards. Four samples have been analysed by CheMin, namely a soil sample, two samples drilled from mudstones and a sample drilled from a sandstone. Rietveld and full-pattern analysis of the XRD data reveal a complex mineralogy, with contributions from parent igneous rocks, amorphous components and several minerals relating to aqueous alteration. In particular, the mudstone samples all contain one or more phyllosilicates consistent with alteration in liquid water. In addition to quantitative mineralogy, Rietveld refinements also provide unit-cell parameters for the major phases, which can be used to infer the chemical compositions of individual minerals and, by difference, the composition of the amorphous component.

Shallow marine event sedimentation in a volcanic arc-related setting: The Ordovician Suri Formation, Famatina range, northwest Argentina

USGS Publications Warehouse

Mangano, M.G.; Buatois, L.A.

1996-01-01

The Loma del Kilome??tro Member of the Lower Ordovician Suri Formation records arc-related shelf sedimentation in the Famatina Basin of northwest Argentina. Nine facies, grouped into three facies assemblages, are recognized. Facies assemblage 1 [massive and parallel-laminated mudstones (facies A) locally punctuated by normally graded or parallel-laminated silty sandstones (facies B] records deposition from suspension fall-out and episodic storm-induced turbidity currents in an outer shelf setting. Facies assemblage 2 [massive and parallel-laminated mudstones (facies A) interbedded with rippled-top very fine-grained sandstones (facies D)] is interpreted as the product of background sedimentation alternating with distal storm events in a middle shelf environment. Facies assemblage 3 [normally graded coarse to fine-grained sandstones (facies C); parallel-laminated to low angle cross-stratified sandstones (facies E); hummocky cross-stratified sandstones and siltstones (facies F); interstratified fine-grained sandstones and mudstones (facies G); massive muddy siltstones and sandstones (facies H); tuffaceous sandstones (facies I); and interbedded thin units of massive and parallel-laminated mudstones (facies A)] is thought to represent volcaniclastic mass flow and storm deposition coupled with subordinated suspension fall-out in an inner-shelf to lower-shoreface setting. The Loma del Kilo??metro Member records regressive-transgressive sedimentation in a storm- and mass flow-dominated high-gradient shelf. Volcano-tectonic activity was the important control on shelf morphology, while relative sea-level change influenced sedimentation. The lower part of the succession is attributed to mud blanketing during high stand and volcanic quiescence. Progradation of the inner shelf to lower shoreface facies assemblage in the middle part represents an abrupt basinward shoreline migration. An erosive-based, non-volcaniclastic, turbidite unit at the base of this package suggests a sea level fall. Pyroclastic detritus, andesites, and a non-volcanic terrain were eroded and their detritus was transported basinward and redeposited by sediment gravity flows during the low stand. The local coexistence of juvenile pyroclastic detritus and fossils suggests reworking of rare ash-falls. The upper part of the Loma del Kilo??metre Member records a transgression with no evidence of contemporaneous volcanism. Biostratinomic, paleoecologic, and ichnologic analyses support this paleoenvironmental interpretations and provide independent evidence for the dominance of episodic sedimentation in an arc-related shallow marine setting. Fossil concentrations were mainly formed by event processes, such as storms and volcaniclastic mass flows. High depositional rates inhibited formation of sediment-starved biogenic concentrations. Collectively, trace fossils belong to the Cruziana ichnofacies. Low diversity, scarcity, and presence of relatively simple forms indicate benthic activity under stressful conditions, most probably linked to high sedimentation rates. Contrasting sedimentary dynamics between 'normal shelves' and their volcaniclastic counterparts produce distinct and particular signatures in the stratigraphic record. Arc-related shelves are typified by event deposition with significant participation of sediment gravity flows, relatively high sedimentation rates, textural and mineralogical immaturity of sediments, scarcity and low diversity of trace fossils, and dominance of transported and reworked faunal assemblages genetically related to episodic processes.

Regional paleohydrologic and paleoclimatic settings of wetland/lacustrine depositional systems in the Morrison Formation (Upper Jurassic), Western Interior, USA

USGS Publications Warehouse

Dunagan, S.P.; Turner, C.E.

2004-01-01

During deposition of the Upper Jurassic Morrison Formation, water that originated as precipitation in uplands to the west of the Western Interior depositional basin infiltrated regional aquifers that underlay the basin. This regional groundwater system delivered water into the otherwise dry continental interior basin where it discharged to form two major wetland/lacustrine successions. A freshwater carbonate wetland/lacustrine succession formed in the distal reaches of the basin, where regional groundwater discharged into the Denver-Julesburg Basin, which was a smaller structural basin within the more extensive Western Interior depositional basin. An alkaline-saline wetland/lacustrine complex (Lake T'oo'dichi') formed farther upstream, where shallower aquifers discharged into the San Juan/Paradox Basin, which was another small structural basin in the Western Interior depositional basin. These were both wetlands in the sense that groundwater was the major source of water. Input from surface and meteoric water was limited. In both basins, lacustrine conditions developed during episodes of increased input of surface water. Inclusion of wetlands in our interpretation of what had previously been considered largely lacustrine systems has important implications for paleohydrology and paleoclimatology. The distal carbonate wetland/lacustrine deposits are well developed in the Morrison Formation of east-central Colorado, occupying a stratigraphic interval that is equivalent to the "lower" Morrison but extends into the "upper" Morrison Formation. Sedimentologic, paleontologic, and isotopic evidence indicate that regional groundwater discharge maintained shallow, hydrologically open, well oxygenated, perennial carbonate wetlands and lakes despite the semi-arid climate. Wetland deposits include charophyte-rich wackestone and green mudstone. Lacustrine episodes, in which surface water input was significant, were times of carbonate and siliciclastic deposition in scarce deltaic and shoreline deposits. Marginal lacustrine deposits include ooid and skeletal packstone-grainstone, siltstone, and sandstone. Distal lacustrine units are skeletal mudstone-wackestone, microbialites, and laminated (siliciclastic) mudstone. Differentiation between wetlands and distal lacustrine units is not always possible. Palustrine features, Magadi-type chert (MTC), and evaporites record episodes of increased aridity and exposure. Farther upstream, during deposition of the upper part of the Brushy Basin Member, the ancestral Uncompahgre Uplift imposed a barrier to shallow, eastward-flowing groundwater that discharged into the San Juan/Paradox Basin on the upstream side of the uplift. This created the closed hydrologic setting necessary for development of an alkaline-saline wetland/lacustrine complex ("Lake" T'oo'dichi'). Silicic volcanic ash, delivered by prevailing winds from calderas west and southwest of the basin, contributed to the pore-water evolution in the sediments. A distinctive lateral hydrogeochemical gradient, reflecting increasing salinity and alkalinity in the pore waters, altered the ash to a variety of authigenic minerals that define concentric zones within the basin. The basinward progression of diagenetic mineral zones is smectite???clinoptilolite???analcime ??potassium feldspar???albite. The groundwater-fed wetlands were shallow and frequently evaporated to dryness. Scarce laminated gray mudstone beds record distinct episodes of freshwater lacustrine deposition that resulted from intermittent streams that carried detritus well out into the basin. ?? 2004 Elsevier B.V. All rights reserved.

Organic Molecules in the Sheepbed Mudstone, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Freissinet, C.; Glavin, D. P.; Mahaffy, P. R.; Miller, K. E.; Eigenbrode, J. L.; Summons, R. E.; Brunner, A. E.; Buch, A.; Szopa, C.; Archer, P. D.;

ACEX: A First Look at Arctic Ocean Cenozoic History

NASA Astrophysics Data System (ADS)

Moran, K.; Backman, J.

2004-12-01

The first Integrated Ocean Drilling Program mission specificplatform expedition (ACEX - Arctic Coring Expedition) drilled and recovered core from five holes at four sites through Cenozoic sediments draping the crest of the Lomonosov Ridge in the central Arctic Ocean. Coring continued into the underlying Cretaceous sedimentary bedrock. Sites are located only a few nautical miles apart along a single seismic line (AWI-91090), showing an identical and coherent Cenozoic seismostratigraphy. Preliminary results from shipboard investigations of core-catcher-based bio- and lithostratigraphy, pore water analyses and core logger data describe a thick (~160 m) middle Miocene through Pleistocene sequence that shows large amplitude, cyclic variability in the density, magnetic susceptibility and acoustic velocity of the sediments. Sediments are largely carbonate free. Pleistocene sedimentation rates are close to 3 cm/ka, whereas Pliocene sediments are by-and-large missing. A sharp change in physical properties at ~200 m defines the transition into a 200+ m thick Paleogene sequence that is initially dominated by large numbers of dinoflagellate cysts. The early Miocene, Oligocene and late Eocene appear to be largely missing in a hiatus. However, a 32 m thick interval separates the overlying middle Miocene from the underlying middle Eocene and presumably preserves some of the early Neogene and late Paleogene sections. Dinoflagellate cysts, diatoms, ebridians and silicoflagellates are common to abundant in the middle Eocene section, which bottoms in a spectacular layer showing massive occurrences of glochidia and massulae (megaspores) of the freshwater hydropterid fern Azolla (duckweed) at the early/middle Eocene boundary (~306 m), suggesting strongly reduced surface water salinity or perhaps even a brief episode of fresh water conditions at the surface. Biosilica is not present prior to the late early Eocene (~320 m). The (sub-) tropical dinoflagellate species Apectodinium augustum occurs abundantly at around 380m in pyrite-rich mudstones, indicating that the Paleocene/Eocene boundary and the associated Carbon Isotope Excursion (CIE) interval were recovered, and that the Arctic Ocean experienced surface temperatures on the order of 20°C during the Paleocene Eocene Thermal Maximum (PETM). Benthic foraminifers indicate that the early Eocene through latest Paleocene sediments were deposited in shallow-marine, neritic to inner neritic, environments. The mudstone of late Paleocene age rests unconformably on Campanian marine sands, sandstone and mudstone.

Mélange versus forearc contributions to sedimentation and uplift, during rapid denudation of a young Banda forearc-continent collisional belt

NASA Astrophysics Data System (ADS)

Duffy, Brendan; Kalansky, Julie; Bassett, Kari; Harris, Ron; Quigley, Mark; van Hinsbergen, Douwe J. J.; Strachan, Lorna J.; Rosenthal, Yair

2017-05-01

New sedimentary geochemistry and petrographic analyses provide the most extensive sedimentary documentation yet of the rapid denudation of the young Timor orogen. The data from three basins including two widely-separated, well-dated sections of the Synorogenic Megasequence of Timor-Leste, and a re-dated DSDP 262, constrain the source and timing of detrital sediment flux during forearc-continent collision along the Timor sector of the Banda Arc. The exhumed synorogenic piggy-back basins formed above a mélange unit that developed at the expense of a weak stratigraphic horizon in the Mesozoic stratigraphy, and was exhumed to the sea floor in latest Messinian time. Following an interval of deep marine chalky marl sedimentation, an increasingly muddy sediment flux indicates that the island of Timor became emergent and shed sediment by 4.5 Ma. Comparison of exhumed sections with similar patterns in the DSDP262 chemistry suggests that the sediment source was probably located some 50-60 km distant from the basin, which is consistent with the Aileu region of Timor-Leste that shows an appropriate exhumation history. All sedimentation between 4.5 and 3.2 Ma was probably derived from a low-relief, rapidly eroding, and mudstone-dominated landscape with geochemical affinities to the Triassic-mudstone-derived synorogenic mélange. The mélange unit overlies and surrounds the Banda Terrane, and was presumably structurally emplaced by propagation of a decollement through the Triassic rocks during the collision. After 3.2 Ma, sedimentation was dominated by hard rock lithologies of the Banda Terrane, consisting of forearc cover and basement, the latter including elements of metamafic rocks and metapelites. This phase of sedimentation was accompanied by rapid uplift, which may have been partly driven by a transient imbalance between rock uplift and denudation as resistant lithologies emerged from below mélange-like mudstone. Previous work has suggested that the timing of collision in Timor-Leste and West Timor was substantially different. Our reevaluation of DSDP 262 facies migration history in the context of the re-dating presented here, favours a relatively synchronous onset of uplift in both halves of the island, but with different partitioning of strain between the foreland and hinterland in each half of the island.

Textural evidence for jamming and dewatering of a sub-surface, fluid-saturated granular flow

NASA Astrophysics Data System (ADS)

Sherry, T. J.; Rowe, C. D.; Kirkpatrick, J. D.; Brodsky, E. E.

2011-12-01

Sand injectites are spectacular examples of large-scale granular flows involving migration of hundreds of cubic meters of sand slurry over hundreds of meters to kilometers in the sub-surface. By studying the macro- and microstructural textures of a kilometer-scale sand injectite, we interpret the fluid flow regimes during emplacement and define the timing of formation of specific textures in the injected material. Fluidized sand sourced from the Santa Margarita Fm., was injected upward into the Santa Cruz Mudstone, Santa Cruz County, California. The sand injectite exposed at Yellow Bank Beach records emplacement of both hydrocarbon and aqueous sand slurries. Elongate, angular mudstone clasts were ripped from the wall rock during sand migration, providing evidence for high velocity, turbid flow. However, clast long axis orientations are consistently sub-horizontal suggesting the slurry transitioned to a laminar flow as the flow velocity decreased in the sill-like intrusion. Millimeter to centimeter scale laminations are ubiquitous throughout the sand body and are locally parallel to the mudstone clast long axes. The laminations are distinct in exposure because alternating layers are preferentially cemented with limonite sourced from later groundwater infiltration. Quantitative microstructural analyses show that the laminations are defined by subtle oscillations in grain alignment between limonite and non-limonite stained layers. Grain packing, size and shape distributions do not vary. The presence of limonite in alternating layers results from differential infiltration of groundwater, indicating permeability changes between the layers despite minimal grain scale differences. Convolute dewatering structures deform the laminations. Dolomite-cemented sand, a signature of hydrocarbon saturation, forms irregular bodies that cross-cut the laminations and dewatering structures. Laminations are not formed in the dolomite-cemented sand. The relative viscosity difference between the hydrocarbon and aqueous sand slurries controls the the critical radius of the contacts between dolomite cemented and limonite cemented sand bodies. The cross-cutting relationships established in the field show that the laminations formed at the jamming transition in the aqueous sand slurry. We interpret the laminations as preserving evidence for dynamic permeability instabilities in the dewatering slurry. Relatively high permeability channels formed as pore fluid flow rearranged grains during initial dewatering. Once initiated, the flow localized further into the higher permeability channels resulting in a feedback that caused the permeability in the channels to increase.

Lower Eocene alluvial paleosols (Willwood Formation, Northwest Wyoming, U.S.A.) and their significance for paleoecology, paleoclimatology, and basin analysis

USGS Publications Warehouse

Bown, T.M.; Kraus, M.J.

1981-01-01

The lower Eocene Willwood Formation of northwest Wyoming is a 700 m thick accumulation of alluvial floodplain and channel mudstones and sandstones, nearly all of which show paleopedogenic modifications. Pedogenesis of Willwood sandstones is indicated by taproot and vertebrate and invertebrate bioturbation, early local cementation by calcium carbonate, and thin illuviation cutans on clastic grains. Pedogenesis in Willwood mudstones is indicated by plant bioturbation, insect and other invertebrate burrow casts and lebensspuren; free iron, aluminum, and manganese mobilization, including hydromorphic gleying; sesquioxide and calcareous glaebule formation in lower parts of the solum; presence of clay-rich and organic carbon-rich zones; and well differentiated epipedons and albic and spodic horizons. Probable A horizons are also locally well developed. Occurrence of variegated paleosol units in thick floodplain mudstone deposits and their association with thin, lenticular, and unconnected fluvial sandstones in the Willwood Formation of the central and southeast Bighorn Basin suggest that these soils formed during times of rapid sediment accumulation. The tabular geometry and lateral persistence of soil units as well as the absence of catenization indicate that Willwood floodplains were broad and essentially featureless. All Willwood paleosols were developed on alluvial parent materials and are complex in that B horizons of younger paleosols were commonly superimposed upon and mask properties of suspected A and B horizons of the next older paleosols. The soils appear to be wet varieties of the Spodosol and Entisol groups (aquods and ferrods, and aquents, respectively), though thick, superposed and less mottled red, purple, and yellow paleosols resemble some ultisols. Most Willwood paleosols resemble warm temperate to subtropical alluvial soils that form today under alternating wet and dry conditions and (or) fluctuating water tables. The up-section decrease in frequency of gley mottles, increase in numerical proportion and thickness of red versus orange coloration, and increase in abundance of calcrete glaebules indicate better drained soils and probably drier climate in late Willwood time. This drying is believed to be related to creation of rain shadows and spacing of rainfall (but not necessarily decrease in absolute rainfall) due to progressive tectonic structural elevation of the mountainous margins of the Bighorn Basin. ?? 1981.

Five Years of Analyses of Volatiles, Isotopes and Organics in Gale Crater Materials

NASA Astrophysics Data System (ADS)

McAdam, A.; Mahaffy, P. R.; Andrejkovicova, S. C.; Archer, P. D., Jr.; Atreya, S. K.; Buch, A.; Coll, P. J.; Conrad, P. G.; Eigenbrode, J. L.; Farley, K. A.; Flesch, G.; Franz, H. B.; Freissinet, C.; Glavin, D. P.; Hogancamp, J. V.; House, C. H.; Knudson, C. A.; Lewis, J. M.; Malespin, C.; Martin, P. M.; Millan, M.; Ming, D. W.; Morris, R. V.; Navarro-Gonzalez, R.; Steele, A.; Stern, J. C.; Summons, R. E.; Sutter, B.; Szopa, C.; Teinturier, S.; Trainer, M. G.; Webster, C. R.; Wong, G. M.

2017-12-01

Over the last five years, the Curiosity rover has explored a variety of fluvial, lacustrine and aeolian sedimentary rocks, and soils. The Sample Analysis at Mars (SAM) instrument has analysed 3 soil and 12 rock samples, which exhibit significant chemical and mineralogical diversity in over 200 meters of vertical section. Here we will highlight several key insights enabled by recent measurements of the chemical and isotopic composition of inorganic volatiles and organic compounds detected in Gale Crater materials. Until recently samples have evolved O2 during SAM evolved gas analyses (EGA), attributed to the thermal decomposition of oxychlorine phases. A lack of O2 evolution from recent mudstone samples may indicate a difference in the composition of depositional or diagenetic fluids, and can also have implications for the detection of organic compounds since O2 can combust organics to CO2 in the SAM ovens. Recent mudstone samples have also shown little or no evolution of NO attributable to nitrate salts, possibly also as a result of changes in the chemical composition of fluids [1]. Measurements of the isotopic composition of sulfur, hydrogen, nitrogen, chlorine, and carbon in methane evolved during SAM pyrolysis are providing constraints on the conditions of possible paleoenvironments [e.g., 2, 3]. There is evidence of organic C from both EGA and GCMS measurements of Gale samples [e.g., 4, 5]. Organic sulfur volatiles have been detected in several samples, and the first opportunistic derivatization experiment produced a rich dataset indicating the presence of several organic compounds [6, 7]. A K-Ar age has been obtained from the Mojave mudstone, and the age of secondary materials formed by aqueous alteration is likely <3 Ga [8]. This relatively young formation age suggests fluid interactions after the end of most fluvial activity on the surface of Mars. As these highlights show, SAM measurements of solid samples have made diverse and important contributions to the exploration of Gale's rock records of martian environmental history and habitability. [1] Sutter et al. (2017) LPSC 3009. [2] Franz et al., this mtg. [3] Stern et al., this mtg. [4] Ming et al. (2014) Science 343. [5] Freissinet et al. (2015) JGR 120. [6] Eigenbrode et al. (2016) AGU P21D-08. [7] Freissinet et al. (2017) LPSC 2687. [8] Martin et al. (2017) LPSC 1531.

SERDP and ESTCP Expert Panel Workshop on Reducing the Uncertainty of DNAPL Source Zone Remediation

DTIC Science & Technology

2006-09-01

Conventional – Wells – Geoprobe • Pneumatic Fracturing • Hydraulic Fracturing • Pressure Pulse Success is achieved when enough Oxidant/Reductant is...al, 2003; Parker et al, 2004). In fractured aquitards (i.e., silts/clays and shales/mudstones), where the bulk hydraulic conductivity is...relatively low, DNAPL can readily migrate into these units via the fractures and, after a few years to decades, nearly all the mass resides in the low

Fluids During Diagenesis and Sulfate Vein Formation in Sediments at Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Schwenzer, S. P.; Bridges, J. C.; Weins, R. C.; Conrad, P. G.; Kelley, S. P.; Leveille, R.; Mangold, N.; Martin-Torres, J.; McAdam, A.; Newsom, H.;

Depositional environment of the downdip Queen City (Eocene) Sandstone, Mestena Grande Field Area, Jim Hogg and Duval Counties, Texas

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCormack, J.

1994-09-01

The downdip Queen City sandstone interval in the Mestena Grande field area of the south Texas Gulf Coast basin comprises two sandstone depositional units, referred to in this paper as A Lobe and B Lobe. A total of 583 ft (179 m) of conventional core from 11 wells containing predominantly B Lobe deposits were examined macroscopically. The A Lobe is a thin (6-34 ft; 1.8-10.4 m) fine- to very fine-grained, mostly bioturbated, well-sorted sandstone. The B Lobe is composed of fine to very fine, well-sorted sandstone interbedded with siltstone and mudstone. The trace fossil assemblage of the B Lobe indicatesmore » that sediments were deposited in the cruziana ichnofacies. Trace fossils and authigenic minerals also suggest oxygen stratification during deposition. B Lobe contains five subunits, each up to 13.5 ft (4 m) net sand thickness. These units were deposited as part of a highstands systems tract during the early Lutetian Stage (lower middle Eocene). B Lobe is a primarily aggradational unit composed of storm-generated sandstone and heterolithic deposits of the lower shoreface to inner shelf environment. A Lobe is a coarsening upward unit and represents progradation of the shoreface during late highstand systems tract development. An interlobal mudstone, which separates the units, marks the transition from early to late highstand systems tract development.« less

Removing the effects of metamorphism from the Neoproterozoic carbon isotope record: a case study on Islay, western Scotland

NASA Astrophysics Data System (ADS)

Skelton, Alasdair

2016-04-01

The Port Askaig Formation on Islay, western Scotland is the first discovered tillite (glacial sediment) of Neoproterozoic age. This formation is sandwiched between carbonate rocks which preserve an extreme negative carbon isotope excursion. This so called "Islay anomaly" has been correlated with other such anomalies worldwide and together with the tillites has been cited as evidence of major (worldwide) glaciation events. During subsequent mountain building, this carbonate-tillite- carbonate sequence has been folded, producing a major en-echelon anticlinal fold system. Folding was accompanied by metamorphism at greenschist facies conditions which was, in turn, accompanied by metamorphic fluid flow. Mapping of the δ18O and δ13C values of these carbonate rocks reveals that metamorphic fluids were channelled through the axial region of the anticlinal fold. The metamorphic fluid was found to have a highly negative δ13C value, which was found to be in equilibrium with metamorphosed graphitic mudstones beneath the carbonate-tillite-carbonate sequence. Devolatilisation of these mudstones is therefore a likely source of this metamorphic fluid. Removal of the effects of metamorphic fluid flow on δ13C values recorded by metamorphosed carbonate rocks on Islay allows us to re-evaluate the isotopic evidence used to reconstruct Neoproterozoic climate. We are able to show that extreme negative δ13C values can partly be attributed to metamorphic fluid flow.

Eustatic and tectonic controls on development and demise of Waulsortian carbonate buildups, Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Precht, W.F.; Shepard, W.

1989-03-01

Deeper water Waulsortian carbonate buildups of Kinderhookian age are known from four localities in Montana. These buildups are situated within rhythmically bedded carbonate mudstones in the Paine Member of the Lodgepole formation. These buildups are mud-rich, byrozoan-crinoid mounds which contain abundant stromatactoid-like spar-filled cavities. The buildups are located along downdropped blocks on bounding faults of the Central Montana trough related to reactivation of a middle Proterozoic intracratonic rift margin (aulacogen). Sequence stratigraphic analyses of the Lodgepole throughout central Montana forms the basis for interpretation of buildup development and demise. Opening of the trough coupled with sea level rise formed threemore » distinct members of the Lodgepole, including (1) a transgressive surface marked by shallow-water deposits of the Cottonwood Canyon Member, (2) a transgressive systems tract of the Paine Member which can be separated into two distinct facies - a condensed section of deeper water carbonate mudstones to wackestones and the Waulsortian buildup facies which are encased within these rhythmically bedded deposits, and (3) a high-stand systems tract characterized by high-energy, cyclic, shoaling-upward crinoidal grainstones and oolites of the Woodhurst Member. Rapid eustatic rise and syntectonic subsidence during the transgressive systems tract outpassed buildup development and led to subsequent drowning. The lack of rapid reef building metazoans during the Mississippian is also suspect in explaining Waulsortian buildup demise.« less

Stratigraphy and depositional environment of early Mississippian Joana limestone of east-central Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilmore, T.

1987-08-01

The Early Mississippian Joana Limestone in the southern Schell Creek and Egan Ranges of east-central Nevada is divided into nine rock types: mudstone, fossiliferous mudstone, wackestone, peloidal wackestone, pelmatozoan wackestone, pelmatozoan packstone, pelmatozoan grainstone, and ooid packstone. From the combined rock type and larger scale outcrop information, three depositional facies were identified: (1) unbedded subtidal, (2) bedded subtidal, and (3) restricted subtidal, each containing a unique set of diagnostic microfacies. Facies thicknesses, lithologies, and contacts with adjacent stratigraphic units indicate a highly varied paleotopography of localized highs and basins during Joana deposition. It is suggested that Waulsortian-type buildups occur downslopemore » of some paleohighs in the unbedded subtidal facies. An age of upper Kinderhookian to lowest Osagean within the Mississippian Period was determined for the Joana, based primarily on conodonts and foraminifera. In the middle beds of the Joana, the previously unreported upper Siphonodella crenulata conodont zone occurs and relates the timing of the Joana to regional geologic events. Color alteration indices of these conodonts are 1.5 to 2, and occur in the oil generation window. Additionally, oil staining was noted in numerous samples primarily from the lower half of the formation, represented by the unbedded subtidal facies. Porosities of the formation are varied, ranging from no visible porosity to over 20% interparticle porosity in some pelmatozoan grainstones.« less

Impacts of Biochar on Physical Properties and Erosion Potential of a Mudstone Slopeland Soil

PubMed Central

Chien, Wei-Hsin; Liou, Ruei-Cheng

2014-01-01

Food demand and soil sustainability have become urgent issues recently because of the global climate changes. This study aims to evaluate the application of a biochar produced by rice hull, on changes of physiochemical characteristics and erosion potential of a degraded slopeland soil. Rice hull biochar pyrolized at 400°C was incorporated into the soil at rates of 2.5%, 5%, and 10% (w/w) and was incubated for 168 d in this study. The results indicated that biochar application reduced the Bd by 12% to 25% and the PR by 57% to 92% after incubation, compared with the control. Besides, porosity and aggregate size increased by 16% to 22% and by 0.59 to 0.94 mm, respectively. The results presented that available water contents significantly increased in the amended soils by 18% to 89% because of the obvious increase of micropores. The water conductivity of the biochar-amended soils was only found in 10% biochar treatment, which might result from significant increase of macropores and reduction of soil strength (Bd and PR). During a simulated rainfall event, soil loss contents significantly decreased by 35% to 90% in the biochar-amended soils. In conclusion, biochar application could availably raise soil quality and physical properties for tilth increasing in the degraded mudstone soil. PMID:25548787

Temporal changes in Quaternary paleoenvironment and ostracode fauna in the eastern Indian Sea off Western Australia (IODP, Exp. 356, site U1461)

NASA Astrophysics Data System (ADS)

Iwatani, H.; Yasuhara, M.; Angue Minto'O, C. M.; Bassetti, M. A.; Expedition 356 Scientists, I.

2016-12-01

The International Ocean Discovery Program Expedition 356 drilled on seven sites off Western Australia to reveal the history of the Indonesian throughflow, the effects of the Australian monsoon, and the subsidence of the northwest shelf of Australia. To achieve these objectives, we investigated paleoenvironmental evolutions in this region during the Quaternary period using high-resolution statistical analyses of the fossil Ostracoda (Crustacea) as an effective environmental indicator. For the investigation, we used a sediment core obtained from an area off Western Australia in the eastern Indian Sea (site: U1461; water depth: 128 m; latitude: 20°, 12.85' S; longitude: 115°, 03.94' E). The upper part of the core mainly comprises alternating beds of darker-colored packstone/wackestone and light-colored wackestone/mudstone. The light-colored wackestone/mudstone beds often contain fecal pellets and well-preserved molluscan fossils. We investigated fossil ostracode faunal composition and species diversity changes during the deposition of the study site. Many well-preserved ostracodes were recorded in the studied cores. Many of collected species are extant taxa that inhabit the upper sublittoral regions as reported from around the recent Indian Ocean off northwestern Australia. Ostracode assemblages, abundance, and diversity drastically changed during the deposition, and they are concordant with sedimentary facies. Here we will discuss the relationships between these paleo-communities changes and paleoenvironmental conditions.

Fluvial sandstone reservoirs of Travis Peak (Hosston) Formation, east Texas basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tye, R.S.

1989-03-01

Gas production (7.2 billion ft/sup 3/) from low-permeability sandstones in the Travis Peak Formation, North Appleby field, Nacogdoches County, Texas, is enhanced through massive hydraulic fracturing of stacked sandstones that occur at depths between 8000 and 10,000 ft. stratigraphic reservoirs were formed in multilateral tabular sandstones owing to impermeable mudstone interbeds that encase blocky to upward-fining sandstones. Pervasive quartz cement in the sandstones decreases porosity and permeability and augments the reservoir seal. Subsurface data indicate that much of this 2000-ft thick section represents aggradation of alluvial-valley deposits. Multiple channel belts form a network of overlapping, broad, tabular sandstones having thickness-to-widthmore » ratios of 1:850 (8-44 ft thick; widths exceed 4-5 mi). Six to eight channel belts, each containing 80-90% medium to fine-grained sandstone, can occupy a 200-ft thick interval. In a vertical sequence through one channel belt sandstone, basal planar cross-bedding grades upward into thinly interbedded sets of planar cross-beds and ripple cross-lamination. Clay-clast conglomerates line scoured channel bases. Adjacent to the channels, interbedded mudstones accumulated in well-drained swamps and lakes. Poorly sorted sandstones represent overbank deposition (crevasse splays and lacustrine deltas). During Travis Peak deposition, fluvial styles evolved from dominantly braided systems near the base of the formation to more mud-rich, meandering systems at the top.« less

Untold muddy tales: Paleoenvironmental dynamics of a ``barren'' mudrock succession from a shallow Permian epeiric sea

NASA Astrophysics Data System (ADS)

Simões, M. G.; Matos, S. A.; Warren, L. V.; Assine, M. L.; Riccomini, C.; Bondioli, J. G.

2016-11-01

During the late Paleozoic, the intracratonic Paraná Basin, Brazil, in central Gondwanaland, was covered by a huge (>1.600.000 km2), shallow and isolated epeiric sea. Within the Permian succession, oxygen-deficient facies are commonly recorded in the Mesosaurus-bearing Irati Formation (Cisuralian, Artinskian/Kungurian) and the overlaying Serra Alta Formation (Guadalupian, Wordian/Capitanian). Barren, dark-grey mudstones are the main facies preserved in this last unit, which has usually discouraged extensive and detailed stratigraphical and paleontological investigations. However, exhaustive sedimentological, taphonomic and paleontological surveys in those deposits reveal a dynamic and complex depositonal history. Based on sedimentary fabric, autochthonous to parautochthonous occurrences of shelly benthic invertebrates (bivalves) and the presence/absence of concretion-bearing and phosphate-rich layers, we report variations in the oxygen levels of bottom and pore waters, in bathymetry, sedimentation rates, and changes in benthic colonization. Our data indicate that the deposition of this "apparently barren" mudstone-dominated succession was driven by a complex interplay of variations in sedimentation rate and oxygen pulses tied to tectonic and climate changes. Three distinct populations or invertebrate paleocommunities were recorded, which were adapted to (a) normal background low-oxygen (dysoxic) conditions (i.e., minute infaunal suspension-feeding bivalves associated with the trace fossil Planolites), (b) chemically toxic (anoxic/extreme dysoxic) substrates, including gigantic burrowing bivalves (probable chemosymbiotic taxa), and (c) oxic/dysoxic substrates following short-term bottom disruptions.

Marine Jurassic lithostratigraphy of Thailand

NASA Astrophysics Data System (ADS)

Meesook, A.; Grant-Mackie, J. A.

Marine Jurassic rocks of Thailand are well-exposed in the Mae Sot and Umphang areas and less extensively near Mae Hong Son, Kanchanaburi, Chumphon and Nakhon Si Thammarat, in the north, west, and south respectively. They are generally underlain unconformably by Triassic and overlain by Quaternary strata. Based mainly on five measured sections, fourteen new lithostratigraphic units are established: (in ascending order) Pa Lan, Mai Hung and Kong Mu Formations of the Huai Pong Group in the Mae Hong Son area; Khun Huai, Doi Yot and Pha De Formations of the Hua Fai Group in the Mae Sot area; Klo Tho, Ta Sue Kho, Pu Khloe Khi and Lu Kloc Tu Formations of the Umphang Group in the Umphang area; and the Khao Lak Formation in the Chumphon area. Mudstone, siltstone, sandstone, limestone and marl are the dominant lithologies. Mudstones, siltstones and sandstones are widespread; limestones are confined to the Mae Sot, Umphang, Kanchanaburi and Mae Hong Son areas; marls are found only in Mae Sot. The sequences are approximately 900 m thick in Mae Sot and 450 m thick in Umphang and are rather thinner in the other areas, particularly in the south. Based on ammonites, with additional data from bivalves and foraminifera, the marine Jurassic is largely Toarcian-Aalenian plus some Bajocian. Late Jurassic ages given previously for strata in the Mae Sot and Umphang areas have not been confirmed.

Undiscovered hydrocarbon resources in the U.S. Gulf Coast Jurassic Norphlet and Smackover Formations

USGS Publications Warehouse

Pearson, Ofori N.

2011-01-01

The U.S. Geological Survey has completed assessments of undiscovered technically recoverable oil and gas resources in the Jurassic Norphlet and Smackover formations of the onshore coastal plain and State waters of the U.S. Gulf Coast. The Norphlet Formation consists of sandstones and interbedded shales and siltstones deposited during a marine transgression. Along its northeast margin, deposition of the Norphlet was in alluvial fans, fluvial systems, and dune and clastic sabkha environments. Mudstones of the underlying Smackover Formation act as source rocks for Norphlet reservoirs. The Norphlet was divided into the following three assessment units (AUs): the Norphlet Salt Basins and Updip AU, the Norphlet Mobile Bay Deep Gas AU, and the Norphlet South Texas Gas AU. The lower part of the Smackover consists primarily of dark carbonate mudstone and argillaceous limestone deposited in low-energy environments, and is one of the Gulf of Mexico Basin’s major source rocks. The upper part of the Smackover is comprised primarily of grain-supported carbonates deposited in high-energy environments. The Smackover was divided into the following four AUs: the Smackover Updip and Peripheral Fault Zone AU, the Smackover Salt Basin AU, the Smackover South Texas AU, and the Smackover Downdip Continuous Gas AU. Although the Norphlet and Smackover formations have been the focus of extensive exploration and production, they probably still contain significant undiscovered oil and gas resources.

Long-term migration of iodine in sedimentary rocks based on iodine speciation and 129I/127I ratio

NASA Astrophysics Data System (ADS)

Togo, Y.; Takahashi, Y.; Amano, Y.; Matsuzaki, H.; Suzuki, Y.; Muramatsu, Y.; Iwatsuki, T.

2012-12-01

[Introduction] 129I is one of the available indexes of long-term migration of groundwater solutes, because of its long half-life (15.7 million years) and low sorption characteristics. The Horonobe underground research center (Japan Atomic Energy Agency), at which are conducted research and development of fundamental techniques on geological disposal of high-level radioactive waste, is an appropriate site for natural analogue studies, because iodine concentration in groundwater is high in this area. To predict iodine behavior in natural systems, speciation of iodine is essential because of different mobility among each species. In this study, we determined iodine speciation and129I/127I isotope ratios of rock and groundwater samples to investigate long term migration of iodine. [Methods] All rock and groundwater samples were collected at Horonobe underground research center. The region is underlain mainly by Neogene to Quaternary marine sedimentary rocks, the Wakkanai Formation (Wk Fm, siliceous mudstones), and the overlying Koetoi Formation (Kt Fm, diatomaceous mudstones). Iodine species in rock samples were determined by iodine K-edge X-ray absorption near edge structure (SPring-8 BL01B1). Thin sections of rock samples were prepared, and iodine mapping were obtained by micro-XRF analysis (SPring-8 BL37XU). Iodine species (IO3-, I-, and organic I) in groundwater were separately detected by high performance liquid chromatography connected to ICP-MS. The 129I/127I ratios in groundwater and rock samples were measured by accelerator mass spectrometry (MALT, Univ. of Tokyo). Iodine in rock samples were separated by pyrohydrolysis and water extraction. [Results and discussion] Concentration of iodine in groundwater varied widely and was much higher than that of seawater showing a high correlation with that of chlorine (R2 = 0.90). Species of iodine in groundwater was mainly I-. Iodine in rock samples decreased near the boundary between Wk and Kt Fms. Iodine K-edge XANES showed that iodine in rock was a mixture of organic and inorganic iodine. According to iodine and carbon mapping in micrometer scale, iodine was accumulated locally and correlated with carbon, suggesting that iodine existed as organic iodine. The 129I/127I isotope ratios in groundwater were lower than those in rocks and almost constant at various depths, demonstrating that iodine in groundwater was released from layers deeper than co-existing rocks. According to these results, migration of iodine in this area can be expected as follows. (i) During sedimentation of Wk and Kt Fms, iodine was accumulated as organic iodine in siliceous sediments. (ii) Iodine was released as I- from the layers deeper than Wk Fm during diagenetic processes. Subsequently, iodine rich groundwater was distributed to Wk and Kt Fms due to the compaction of the layers. (iii) During uplift and denudation processes, both iodine and chlorine were diluted by meteoric water from the surface. Iodine distribution coefficient (Kd = [I concentration in rock]/[I concentration in groundwater]) of Kt Fm is higher than that in Wk Fm. Diatomaceous mudstones might be more effective than siliceous mudstones as natural barrier for 129I released from deep underground radioactive waste repository. This suggestion should be reinforced by laboratory experiments in future studies.

Construction Foundation Report for Seepage Control Adits Abiquiu Dam and Reservoir, New Mexico

DTIC Science & Technology

1990-02-02

by broad folds and gentle regional dips to the north and west. Steeply dipping normal faults with a general north to northeast trend are common and...often exhibit throws in excess of 200 feet. Jointing is generally north-west to north-east and are nearly vertical to vertical. [1] The close of the...numerous minor joints. Joints faces in the mudstone are commonly striated and slickensided in random orientations. [1] The Agua Zarca Sandstone member of

Geology and mineral deposits of the Carlile quadrangle, Crook County, Wyoming

USGS Publications Warehouse

Bergendahl, M.H.; Davis, R.E.; Izett, G.A.

1961-01-01

The Carlile quadrangle-is along the northwestern flank of the Black Hills uplift in Crook County, Wyo. The area-is primarily one of canyons and divides that are a result of downcutting by the Belle Fourche River and its tributaries through an alternating succession of sandstone, siltstone, and mudstone or shale beds. The present topography is also influenced by the regional structure, as reflected by the beds that dip gently westward and by the local structural features such as anticlines, domes, synclines, basins, and terraces, which are superimposed upon the regional setting. Rocks exposed include shale and thin limestone and sandstone beds belonging to the Redwater shale member of the Sundance formation and to the Morrison formation, both of Late Jurassic age; sandstone, siltstone, and mudstone of the Lakota and Fall River formations of Early Cretaceous age; and shale and sandstone of the Skull Creek shale, Newcastle sandstone, and Mowry shale, also of Early Cretaceous age. In the southwestern part of the quadrangle rocks of the Upper Cretaceous series are exposed. These include the Belle Fourche shale, Greenhorn formation, and Carlile shale. Gravel terraces, landslide debris, and stream alluvium comprise the surficial deposits. The Lakota and Fall River formations, which make up the Iriyan Kara group, contain uranium deposits locally in the northern Black Hills. These formations were informally subdivided in order to show clearly the vertical and lateral distribution of the sandstone, siltstone, and mudstone facies within them.The Lakota was subdivided into a sandstone unit and an overlying mudstone unit; the Fall River was subdivided, in ascending order, into a siltstone unit, a mudstone unit, a sandstone unit, and an upper unit. The lithologic character of the Lakota changes abruptly locally, and the units are quite inconsistent with respect to composition, thickness, and extent. This is in contrast to a notable consistency in the lithologic character and thickness among all the Fall River units, with the exception of the upper unit. Petrographic studies on selected samples of units from both formations show differences in composition between Lakota and Fall River rocks.The Carlile quadrangle lies immediately east of the monocline that marks the outer limit of the Black Hills uplift, and the rocks in this area have a regional dip of less than 2° outward from the center of the uplift. Superimposed upon the regional uplift are many subordinate structural features anticlines, synclines, domes, basins, and terraces which locally modify the regional features. The most pronounced of these subordinate structural features are the doubly-plunging Pine Ridge, Oil Butte, and Dakota Divide anticlines, and the Eggie Creek syncline. Stress throughout the area was relieved almost entirely through folding; only a few small nearly vertical normal faults were found within the quadrangle.Uranium has been mined from the Carlile deposit, owned by the Homestake Mining Co. The ore minerals, carnotite and tyuyamnuite occur in a sandstone lens that is enclosed within relatively impermeable clayey beds in the mudstone unit of the Lakota formation. The ore also includes unidentified black vanadium minerals and possibly coffinite. Uranium minerals are more abundant in and adjacent to thicker carbonaceous and silty seams in the sandstone lens. A mixture of fine-grained calcium carbonate and calcium sulfate fills the interstices between detrital quartz grains in mineralized sandstone. Selenium and arsenic are more abundant in samples that are high in uranium. Drilling on Thorn Divide about 1 mile west of the Carlile mine has roughly outlined concentrations of a sooty black uranium mineral associated with pyrite In two stratigraphic intervals of the Lakota formation. One is in the same sandstone lens that contains the ore at the Carlile mine; the other is in conglomeratic sandstone near the base of the Lakota. These deposits are relatively deep, and no mining has been attempted. The mineralogy of the Carlile deposits and the lithologic features of the sandstone host rock suggest that uranium and vanadium were transported in the high-valent state by carbonate or sulfate solutions, were extracted from solution by organic material, and were reduced to low-valent states to form an original assemblage of oxides and silicates. These primary minerals were oxidized in place, and the present carnotite-tyuyamunite assemblage was formed. In general, radioactivity analyses correspond fairly closely with chemical analyses of uranium, thus it is believed that only minor solution and migration of uranium has occurred since the present suite of oxidized minerals was formed. The factors responsible for ore localization are not clear, but probably a combination of three lithologic and structural elements contributed to provide a favorable environment for precipitating uranium from aqueous solutions: abundant carbonaceous material or pyrite in a thin, permeable sandstone enclosed within relatively thick impermeable clays; local structural basins; and a regional structural setting involving a broad syncline between two anticlines. The structural features controlled the regional flow of ground water and the lithologic features controlled the local rate of flow and provided the proper chemical environment for uranium deposition. Bentonite has been mined from an opencut in the Mowry shale in the southwest part of the quadrangle. A bentonite bed in the Newcastle sandstone also seems to be of minable thickness and quality. Exploration for petroleum has been unsuccessful within the quadrangle; however, some wells that yielded oil were recently drilled on small anticlines to the west and southeast. It is possible that similar structural features in the Carlile area, that were previously overlooked, may be equally productive.

Storm and tide influenced depositional architecture of the Pliocene-Pleistocene Chad Formation, Chad Basin (Bornu Sub-basin) NE Nigeria: A mixed fluvial, deltaic, shoreface and lacustrine complex

NASA Astrophysics Data System (ADS)

Shettima, Bukar; Kyari, Aji Maina; Aji, Mallam Musa; Adams, Fatimoh Dupe

2018-07-01

Lithofacies analyses of the upper part of the Chad Formation (Bama Ridge Complex) in the Bornu Sub-basin of the Chad Basin indicated four facies associations; fluvial, deltaic, shoreface and lacustrine sequences. The fluvial sequences are composed of fining upward cycles with successive occurrence of planar crossbedded sandstone facies displaying unimodal paleocurrent system and rare mudstone facies typical of braided river system. The deltaic succession consists of both fining and coarsening upwards cycles with the former depicting fluvial setting of an upper delta plain while the later suggestive of mouth-bar sequences. The setting displays a polymodal current system of fluvial, waves, storms and tides that were primarily induced by complex interactions of seiches and lunar tides. Similar current systems devoid of fluvial patterns were reflected in the coarsening upward packages of the shoreface sequences. Lacustrine succession composed of thick bioturbated mudstone facies generally defines the base of these coarsening upward profiles, giving a fluvio-lacustrine geomorphic relief where complex interaction developed the deltaic and shoreface facies along its shorelines. Clay mineral fractions of the formation are dominantly kaolinitic, indicating a predominantly humid tropical-subtropical climatic condition during their deposition. This climatic regime falls within the African humid period of the early-mid Holocene that led to the third lacustrine transgression of the Lake Mega-Chad, whereas the subordinate smectite mineralization points to aridification that characterizes most of the post humid period to recent.

Growth, Failure, and Erosion of Submarine Channel Levees on the Upper Mississippi Fan, Gulf of Mexico

NASA Astrophysics Data System (ADS)

Sawyer, D. E.; Flemings, P. B.; Nikolinakou, M. A.

2011-12-01

Late Pleistocene channel levees on the Mississippi Fan failed repeatedly along deep-seated listric faults. These growth faults begin at the top of the levee, as much as a kilometer away from the channel axis. They plunge 150-200 meters downward reaching their deepest point halfway towards the channel axis (0.5 km) along the base of a regional sand unit. They then rise toward the channel axis where they emerge. The erosion of toe-thrust material coupled with levee growth, promoted a dynamic equilibrium: turbidity currents flushed the channel axis and deposited new levee on the margins, which induced further displacement into the channel. With a geomechanical model we show that deep-seated failure occurred by undrained loading of an underlying low permeability mudstone. Excess pore pressure formed a low-strength layer that localized the detachment at the base of a regional sand. Our results show that deep-seated failure is expected when levee systems form above regional sand bodies that were deposited rapidly above low permeability mudstone. Furthermore, the presence of this failure style in channel-levee systems is a strong indicator that overpressures and low effective stresses were present during formation and thus record paleo-pressures. Understanding these systems is critical for the design of safe well penetrations, predicting hydraulic connectivity of deepwater channel sands, and the growth of submarine channel-levee systems. This study illuminates the linkages between sedimentation, erosion, and the mechanical stability of levees in submarine channel systems.

Lithofacies of Spencer Formation, western Tualatin Valley, Oregon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Atta, R.O.

The Spencer Formation crops out in a narrow band that trends north-northwest on the western edge of the Willamette and Tualatin Valleys, Oregon. It apparently conformably overlies mud rocks of either the Yamhill or the Nestucca Formation and is conformably overlain by the Pittsburgh Bluff Formation. The Spencer Formation consists of two members (informal): a lower highly micaceous sandstone (800-1000 ft) and an upper member that is micaceous siltstone and mudstone (1000-1300 ft). The lower member includes an upper part that is light-gray to creamy-gray, silty to muddy, pebbly lithic arkose to feldspathic litharenite, with minor arkose. Sorting is poormore » and beds may be laminated to ripple cross-laminated or massive and bioturbated with abundant mollusk shells, carbonized wood, and burrows. The lower part of the lower member is medium-gray to greenish-gray, silty, pumiceous lithic arkose to feldspathic litharenite. The texture tends to be more uniform and better sorted than that of the upper part of the member. Bedding is commonly massive due to bioturbation. The upper member is medium to dark-gray mudstone with thin pebble-conglomerate lenses. It intertongues with the lower member. Bioturbation, burrows, and carbonized wood are common. The trend in depositional environments appears to be from outer to mid-neritic (lower part, lower member) to shallow neritic, nearshore, and lagoonal (upper part, lower member, and upper member). The provenance of the Spencer Formation includes both proximal volcanics and distant plutonic and high-grade metamorphics.« less

Terrestrial paleoclimatic changes in northeast Asia during OAE 3 in the Late Cretaceous: Organic geochemical evidences from the Songliao paleo-lake Basin, northeast China

NASA Astrophysics Data System (ADS)

Gao, Y.; Wang, C.; Huang, H.

2016-12-01

Oceanic anoxic events (OAEs) in the Cretaceous greenhouse world record significant paleoclimatic changes and represent major disturbances in the global carbon cycle. The Coniacian-Santonian oceanic anoxic event (OAE 3), the last of the Cretaceous OAEs, is characterized by restricted black shale deposits in equatorial to mid-latitude Atlantic and adjacent basins. Continental hydroclimate on tropical Africa and South America was proved have a strong effect on carbon burial in ocean basins during OAE 3, although terrestrial paleoclimatic changes on the other continents were not well understood. The Continental Scientific Drilling Project of the Songliao paleo-lake Basin (northeast China) recovered 500m thick, continuous, dark-colored, deep lacustrine mudstone of the Qingshankou Formation, with the age of 92.0-86.2Ma tightly constrained by radiometric dating on volcanic ashes, magnetostratigraphy and cyclostratigraphy. These sediments thus provide an opportunity to study terrestrial paleoclimate changes in northeast Asia during OAE 3. Our high-resolution ( 1m interval) TOC and δ13Corg data of the Qingshankou Formation in the Songliao Basin show several positive δ13Corg excursions over the OAE 3 time period. Spectrum analysis shows remarkable Milankovich cycles including eccentricity cycles ( 400kyr) and precession cycles ( 20 kyr). These data suggest that dark-colored mudstone deposition in the Songliao paleo-lake was probably controlled by regional hydroclimatic changes which were influenced by orbital forcing.

Surveying Clay Mineral Diversity in the Murray Formation, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Bristow, T. F.; Blake, D. F.; Vaniman, D. T.; Chipera, S. J.; Rampe, E. B.; Grotzinger, J. P.; McAdam, A. C.; Ming, D. W.; Morrison, S. M.; Yen, A. S.;

Cyclicity in Silurian island-arc carbonates, Alexander terrane, Alaska

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kittredge, L.E.; Soja, C.M.

1993-03-01

Silurian carbonates from Alaska (Alexander terrane) record the evolution of a submarine platform during waning volcanism in an island arc. A detailed stratigraphic analysis of a 47 meter-thick sequence revealed the existence of cyclically repeated limestones: coral-stromatoporoid wackestones alternate with oncoid packstones and bioturbated, silty lime mudstones. The coral-stromatoporoid deposits are characterized by a low-diversity assemblage of dendroid corals, massive stromatoporoids, Atrypoidea brachiopods, and rare occurrences of biostromes associated with Solenopora, high-spired gastropods, and crinoids. Oncoids typically are 2-6 mm in diameter and form massive, meter-thick units. Coated grains are symmetrically developed, have a shell or algal nucleus, and aremore » also a minor component of coral-stromatoporoid beds. These lithologic units form seven, shallowing-upwards cycles (parasequences) that range in thickness from 3-9 meters. Coral-stomatoporoid wackestones form the base of each cycle and grade upwards into oncoid packstones with silty, lime mudstones at the top. This succession of lithofacies within each cycle reflects an increase in energy levels from relatively deeper water environments to relatively shallower ones. The lack of abrasion in the corals and stromatoporoids suggests predominantly quiet-water conditions in shallow subtidal areas affected by periodic turbulence. Comparison with correlative sections in Alaska and lack of correspondence with global sea level curves suggest that the primary cause of cyclicity was tectonic perturbations with secondary eustatic effects. Cyclic deposition in peri/subtidal sites was terminated by rapid drowning of the carbonate platform during late Silurian orogenesis.« less

Imaging pathways in fractured rock using three-dimensional electrical resistivity tomography

USGS Publications Warehouse

Robinson, Judith; Slater, Lee; Johnson, Timothy B.; Shapiro, Allen M.; Tiedeman, Claire; Ntlargiannis, Dimitrios; Johnson, Carole D.; Day-Lewis, Frederick D.; Lacombe, Pierre; Imbrigiotta, Thomas; Lane, John W.

2016-01-01

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three-dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high-resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time-lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone.

High frequency peritidal cycles in the lower member of the Late Cretaceous (Turonian, Coniasian-Santonian) El Hefhuf Formation, Bahariya Oases, Western Desert, Egypt

NASA Astrophysics Data System (ADS)

Khalifa, M. A.; Tanner, Lawrence H.

2017-06-01

Carbonate lithofacies of the lower member of the El Hefhuf Formation (Turonian, Coniasian-Santonian) in the Bahariya Oases, Western Desert of Egypt comprise dolostone, burrowed dolostone, cherty dolostone, calcareous dedolostone, dolomitic quartzose lime-mudstone, and caliche. The dolostone and cherty dolostone formed in intertidal to supratidal environments, while dedolostone and caliche were formed during subaerial exposure. The dolomitic quartzose lime-mudstone was deposited in a restricted subtidal environment. Stable isotope analyses of the dolostone lithofacies are consistent with dolomitization by normal marine to evaporatively enriched dolomitizing fluids with only slight mixing of meteoric water. Therefore, dolomitization occurred in the intertidal and supratidal environments immediately following deposition. The dolostone and cherty dolostone lithofacies display pronounced cyclicity at the sub-meter scale, with individual cycles consisting of one (monolithic), two (diad) or at most three (triad) lithofacies. Most of all cycles show evidence of subaerial exposure at the top, such as brecciations, and many cycles are capped by calcareous palaeosol layers (caliche). In the absence of evidence for cycle periods at Milankovitch-scale frequencies, we reject orbital forcing as the cause of the cyclicity and suggest instead autocyclic depositional processes in the peritidal environment as the primary control on cyclicity, possibly modified by eustatic fluctuations at periods longer than the cycles recorded here. The significance of this study is to suggest formation of dolomite cycles due to high-frequency in sea level with intermittent subaerial exposure.

Exploration for uranium deposits in the Atkinson Mesa area, Montrose County, Colorado

USGS Publications Warehouse

Brew, Daniel Allen

1954-01-01

The U.S. Geological Survey explored the Atkinson Mesa area for uranium- and vanadium-bearing deposits from July 2, 1951, to June 18, 1953, with 397 diamond-drill holes that totaled 261,251 feet. Sedimentary rocks of Mesozoic age are exposed in the Atkinson Mesa area. They are: the Brushy Basin member of the Upper Jurassic Morrison formation, the Lower Cretaceous Burro Canyon formation, and the Upper and Lower Cretaceous Dakota sandstone. All of the large uranium-vanadium deposits discovered by Geological Survey drilling are in a series of sandstone lenses in the upper part of the Salt Wash member of the Jurassic Morrison formation. The deposits are mainly tabular and blanket-like, but some elongate pod-shaped masses, locally called "rolls" may be present. The mineralized material consists of sandstone impregnated with a uranium mineral which is probably coffinite, spme carnotite, and vanadium minerals, thought to be mainly corvusite and montroseite. In addition,, some mudstone and carbonaceous material is similarly impregnated. Near masses of mineralized material the sandstone is light gray or light brown, is generally over 40 feet thick, and usually contains some carbonaceous material and abundant disseminated pyrite or limonite stain. Similarly, the mudstone in contact with the ore-bearing sandstone near bodies of mineralized rock is commonly blue gray, as compared to its dominant red color away from ore deposits. Presence and degree of these features are useful guides in exploring for new deposits.

Hydrocarbon source rock potential of the Karoo in Zimbabwe

NASA Astrophysics Data System (ADS)

Hiller, K.; Shoko, U.

1996-07-01

The hydrocarbon potential of Zimbabwe is tied to the Karoo rifts which fringe the Zimbabwe Craton, i.e. the Mid-Zambezi basin/rift and the Mana Pools basin in the northwest, the Cabora Bassa basin in the north and the Tuli-Bubye and Sabi-Runde basins in the south. Based on the geochemical investigation of almost one thousand samples of fine clastic Karoo sediments, a concise source rock inventory has been established showing the following features. No marine source rocks have been identified. In the Mid-Zambezi area and Cabora Bassa basin, the source rocks are gas-prone, carbonaceous to coaly mudstones and coal of Lower Karoo age. In the Cabora Bassa basin, similar gas-prone source rocks occur in the Upper Karoo (Angwa Alternations Member). These kerogen type III source rocks are widespread and predominantly immature to moderately mature. In the southern basins, the Lower Karoo source rocks are gas-prone; in addition some have a small condensate potential. Most of the samples are, however, overmature due to numerous dolerite intrusions. Samples with a mixed gas, condensate and oil potential (mainly kerogen types II and III) were identified in the Lower Karoo (Coal Measure and Lower Madumabisa Mudstone Formations) of the Mid-Zambezi basin, and in the Louver Karoo (Mkanga Formation) and Upper Karoo (Upper Angwa Alternations Member Formation) of the Cabora Bassa basin. The source rocks, with a liquid potential, are also immature to moderately mature and were deposited in swamp, paludal and lacustrine environments of limited extent.

Integrated Ground-based Hyperspectral Imaging and Geochemical Study of the Eagle Ford Group in West Texas

NASA Astrophysics Data System (ADS)

Sun, L.; Khan, S.; Godet, A.

2017-12-01

This study used ground-based hyperspectral imaging to map an outcrop of the Eagle Ford Group in west Texas. The Eagle Ford Group consists of alternating layers of mudstone - wackestone, grainstone - packstone facies and volcanic ash deposits with high total organic carbon content deposited during the Late Cenomanian - Turonian time period. It is one of the few unconventional source rock and reservoirs that have surface representations. Ground-based hyperspectral imaging scanned an outcrop and hand samples at close ranges with very fine spatial resolution (centimeter to sub-millimeter). Spectral absorption modeling of clay minerals and calcite with the modified Gaussian model (MGM) allowed quantification of variations of mineral abundances. Petrographic analysis confirmed mineral identifications and shed light on sedimentary textures. Major element geochemistry confirmed the mineral quantification. Enrichment of molybdenum (Mo) and uranium (U) indicated "unrestricted marine" paleo-hydrogeology and anoxic to euxinic paleo-redox bottom water conditions. Mineral quantification resulted in mapping of mudstone - wackestone, grainstone - packstone facies and claystones (volcanic ash beds). The lack of spatial associations between the grainstones and claystones on the outcrop calls into question the hypothesis that the primary productivity is controlled by iron availability from volcanic ash beds. Hyperspectral remote sensing data also helped in creating a virtual outcrop model with detailed mineralogical compositions, and provided reservoir analog to extract compositional and geo-mechanical characteristics and variations. The utilization of these new techniques in geo-statistical analysis provides a workflow for employing remote sensing in resource exploration and exploitation.

Integrated ground-based hyperspectral imaging and geochemical study of the Eagle Ford Group in West Texas

NASA Astrophysics Data System (ADS)

Sun, Lei; Khan, Shuhab; Godet, Alexis

2018-01-01

This study used ground-based hyperspectral imaging to map an outcrop of the Eagle Ford Group in west Texas. The Eagle Ford Group consists of alternating layers of mudstone - wackestone, grainstone - packstone facies and volcanic ash deposits with high total organic content deposited during the Cenomanian - Turonian time period. It is one of the few unconventional source rock and reservoirs that have surface representations. Ground-based hyperspectral imaging scanned an outcrop and hand samples at close ranges with very fine spatial resolution (centimeter to sub-millimeter). Spectral absorption modeling of clay minerals and calcite with the modified Gaussian model (MGM) allowed quantification of variations of mineral abundances. Petrographic analysis confirmed mineral identifications and shed light on sedimentary textures, and major element geochemistry supported the mineral quantification. Mineral quantification resulted in mapping of mudstone - wackestone, grainstone - packstone facies and bentonites (volcanic ash beds). The lack of spatial associations between the grainstones and bentonites on the outcrop calls into question the hypothesis that the primary productivity is controlled by iron availability from volcanic ash beds. Enrichment of molybdenum (Mo) and uranium (U) indicated "unrestricted marine" paleo-hydrogeology and anoxic to euxinic paleo-redox bottom water conditions. Hyperspectral remote sensing data also helped in creating a virtual outcrop model with detailed mineralogical compositions, and provided reservoir analog to extract compositional and geo-mechanical characteristics and variations. The utilization of these new techniques in geo-statistical analysis provides a workflow for employing remote sensing in resource exploration and exploitation.

Lower Cretaceous paleo-Vertisols and sedimentary interrelationships in stacked alluvial sequences, Utah, USA

NASA Astrophysics Data System (ADS)

Joeckel, R. M.; Ludvigson, G. A.; Kirkland, J. I.

2017-11-01

The Yellow Cat Member of the Cedar Mountain Formation in Poison Strip, Utah, USA, consists of stacked, erosionally bounded alluvial sequences dominated by massive mudstones (lithofacies Fm) with paleo-Vertisols. Sediment bodies within these sequences grade vertically and laterally into each other at pedogenic boundaries, across which color, texture, and structures (sedimentary vs. pedogenic) change. Slickensides, unfilled (sealed) cracks, carbonate-filled cracks, and deeper cracks filled with sandstone; the latter features suggest thorough desiccation during aridification. Thin sandstones (Sms) in some sequences, typically as well as laminated to massive mudstones (Flm) with which they are interbedded in some cases, are interpreted as avulsion deposits. The termini of many beds of these lithofacies curve upward, parallel to nearby pedogenic slickensides, as the features we call ;turnups.; Turnups are overlain or surrounded by paleosols, but strata sheltered underneath beds with turnups retain primary sedimentary fabrics. Turnups were produced by movement along slickensides during pedogenesis, by differential compaction alongside pre-existing gilgai microhighs, or by a combination of both. Palustrine carbonates (lithofacies C) appear only in the highest or next-highest alluvial sequences, along with a deep paleo-Vertisol that exhibits partially preserved microrelief at the base of the overlying Poison Strip Member. The attributes of the Yellow Cat Member suggest comparatively low accommodation, slow accumulation, long hiatuses in clastic sedimentation, and substantial time intervals of subaerial exposure and pedogenesis; it appears to be distinct among the members of the Cedar Mountain Formation in these respects.

Sequence stratigraphy and hydrocarbon habitat of the Natih formation in Oman

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sikkema, W.; Borgomano, J.

1993-09-01

The Natih Formation is part of the Mesozoic platform carbonate succession deposited on the southeastern Arabian peninsula and one of the main hydrocarbon producing reservoirs in Oman. It is separated from the underlying carbonates of the Shuaiba Formation by the Nahr Umr Formation and is overlain by the Fiqa Formation, both acting as regional seals. The age of the Natih Formation is late Albian to early Turonian, and its deposition was terminated by early Turonian uplift. Various lithofacies are present in the Natih Formation. The Natih Formation is cyclic, with a succession of coarsening-upward cycles of deeper marine shales andmore » mudstones grading to shallow marine rudistid packstones and grainstones, each terminated by an emergence surface. The cyclicity is the result of eustatic sea level changes. Two deeper marine shales rich in planktonic foraminifera and organic material are intercalated within the sequence. The cycles have been used to subdivide the Natih into members labeled a to g. A sequence stratigraphic model has been applied to the observed cyclicity, which helps to understand (1) the distribution of shallow marine grainstones (reservoir) and deeper marine shales and mudstones (seal, source rock), and (2) where the reservoir quality may have been enhanced by emergence and leaching. The model has been tested both on a regional scale and on a field scale, e.g., on seismic lines over the Sirat Prospect area in central north Oman and the Marmul area of south Oman.« less

Relationship Between Faults Oriented Parallel and Oblique to Bedding in Neogene Massive Siliceous Mudstones at The Horonobe Underground Research Laboratory, Japan

NASA Astrophysics Data System (ADS)

Hayano, Akira; Ishii, Eiichi

2016-10-01

This study investigates the mechanical relationship between bedding-parallel and bedding-oblique faults in a Neogene massive siliceous mudstone at the site of the Horonobe Underground Research Laboratory (URL) in Hokkaido, Japan, on the basis of observations of drill-core recovered from pilot boreholes and fracture mapping on shaft and gallery walls. Four bedding-parallel faults with visible fault gouge, named respectively the MM Fault, the Last MM Fault, the S1 Fault, and the S2 Fault (stratigraphically, from the highest to the lowest), were observed in two pilot boreholes (PB-V01 and SAB-1). The distribution of the bedding-parallel faults at 350 m depth in the Horonobe URL indicates that these faults are spread over at least several tens of meters in parallel along a bedding plane. The observation that the bedding-oblique fault displaces the Last MM fault is consistent with the previous interpretation that the bedding- oblique faults formed after the bedding-parallel faults. In addition, the bedding-parallel faults terminate near the MM and S1 faults, indicating that the bedding-parallel faults with visible fault gouge act to terminate the propagation of younger bedding-oblique faults. In particular, the MM and S1 faults, which have a relatively thick fault gouge, appear to have had a stronger control on the propagation of bedding-oblique faults than did the Last MM fault, which has a relatively thin fault gouge.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cornaggia, F.; Congo, S.A.; Agostino, M.

Kitina field is located in Marine VII permit, offshore Congo. The field was discovered in 1991 by a joint venture composed of Agip Recherches Congo (operator), Hydrocongo and Chevron International Limited. The field is a structural four-way dip closure trap shaped as turtle-back. Halokinetic movements are responsible for the structuring. The seismic imaging of the reservoir is affected by strong lateral velocity variations caused by different sedimentation across the paleo-shelf edge in the post-Albian sequence. One pass 3D poststack depth migration, performed with a velocity field obtained by means of geostatistical integration of 2D seismic and wellbore velocities, achieved amore » good compromise between high dip reflector imaging and depths at well location. Three main reservoirs of lower Albian age exist between -2100 and -3100m. They are separated by tight mudstones which act as intraformational seal. Seismic trace inversion improved the resolution of petrophysical variations in some of the field reservoirs, which have the following characteristics (from top to bottom): reservoir 2A is composed of bioclastic and oolitic packstone-grainstone laid down during regional regressive phase in insulated offshore bars on the crest of structural high. Early diagenetic phenomena lead to the development of world class permeability framework. Reservoir 1A-1B are composed of sandstone bodies which were deposited as shoreface to offshore bars during short-term regressive pulse. The 1A-1B reservoir, are embedded in mudstones deposited during long lasting phases of relative high stand in relatively deep offshore setting characterised by high, halokinetic driven subsidence.« less

Evolution of the east-central San Jose del Cabo basin, Baja California Sur, Mexico

NASA Astrophysics Data System (ADS)

McTeague, M. S.; Umhoefer, P. J.; Schwennicke, T.; Ingle, J. C.; Cortes Martinez, M.

2006-12-01

The San Jose del Cabo basin at the southern tip of the Baja California peninsula records the early tectonic evolution of the west side of the Gulf of California. This study focused on the east central margin of the basin. The basal La Calera Formation unconformably overlies Cretaceous granite and consists of conglomerate, pebbly sandstone and conglomerate, and sandstone deposited in alluvial fans and fan-deltas. Deposition of the La Calera Formation was from ca. 9-14 Ma. The lower member of the Trinidad Formation was deposited beginning ca. 9-13 Ma and consists of sandstone, mudstone, and shelly mudstone deposited in nearshore and estuarine environments. These age estimates are based on sedimentation rates and foraminifera and coccoliths from the NN 11A nannozone (7.4 8.6 Ma, GTS 2004). The middle member of the Trinidad Formation consists of deeper water mudstones deposited by turbidity currents and suspension settling in a shelf to slope and conglomerates deposited by submarine debris flows on the shelf. The basin began earlier than previously thought. The oldest marine rocks are ca.9-13 Ma, while sedimentation on the east side began at ca. 9-14 Ma, synchronous with estimates of initiation of offset on the San Jose del Cabo fault. The Zapote fault is a down-to-the-east normal and sinistral-oblique fault that exposes a wedge of granite and older strata in the footwall to the west. The fault was active during sedimentation in the late Miocene and possibly later. The fault divides the study area into an eastern hanging wall subbasin and western footwall subbasin. The eastern subbasin formed an embayment in the eastern margin of the Cabo basin. A regional flooding surface (ca. 8 Ma) can be correlated across the fault that marks a major marine incursion. Depositional systems evolved rapidly from coarse-grained terrestrial systems to fine-grained marine and estuarine systems. The Cabo basin provides an excellent analogue for comparison with offshore basins, which are broadly similar with more faulting in lower strata and fewer or no faulting in upper strata. Offshore seismic data show older, deformed syn-rift strata in half graben overlain by younger, undeformed post-rift strata. The normal faults with 1-5 km spacing cut the basement rock and oldest sedimentary units. The eastern margin of the Cabo basin has older, growth strata cut by the Zapote fault that are overlain by simpler strata. Smaller scale normal faults in the Cabo basin are no longer active while the Cabo fault remains active.

Sedimentary processes and depositional environments of the Horn River Shale in British Columbia, Canada

NASA Astrophysics Data System (ADS)

Yoon, Seok-Hoon; Koh, Chang-Seong; Joe, Young-Jin; Woo, Ju-Hwan; Lee, Hyun-Suk

2017-04-01

The Horn River Basin in the northeastern British Columbia, Canada, is one of the largest unconventional gas accumulations in North America. It consists mainly of Devonian shales (Horn River Formation) and is stratigraphically divided into three members, the Muskwa, Otterpark and Evie in descending order. This study focuses on sedimentary processes and depositional environments of the Horn River shale based on sedimentary facies analysis aided by well-log mineralogy (ECS) and total organic carbon (TOC) data. The shale formation consists dominantly of siliceous minerals (quartz, feldspar and mica) and subordinate clay mineral and carbonate materials, and TOC ranging from 1.0 to 7.6%. Based on sedimentary structures and micro texture, three sedimentary facies were classified: homogeneous mudstone (HM), indistinctly laminated mudstone (ILM), and planar laminated mudstone (PLM). Integrated interpretation of the sedimentary facies, lithology and TOC suggests that depositional environment of the Horn River shale was an anoxic quiescent basin plain and base-of-slope off carbonate platform or reef. In this deeper marine setting, organic-rich facies HM and ILM, dominant in the Muskwa (the upper part of the Horn River Formation) and Evie (the lower part of the Horn River Formation) members, may have been emplaced by pelagic to hemipelagic sedimentation on the anoxic sea floor with infrequent effects of low-density gravity flows (turbidity currents or nepheloid flows). In the other hand, facies PLM typifying the Otterpark Member (the middle part of the Horn River Formation) suggests more frequent inflow of bottom-hugging turbidity currents punctuating the hemipelagic settling of the background sedimentation process. The stratigraphic change of sedimentary facies and TOC content in the Horn River Formation is most appropriately interpreted to have been caused by the relative sea-level change, that is, lower TOC and frequent signal of turbidity current during the sea-level lowstand and vice versa. Therefore, the Horn River Formation represents an earlier upward shallowing environmental change from a deep basin (Evie) to shallower marginal slope (middle Otterpark), then turning back to the deeper marine environment (Muskwa) in association with overall regression-lowstand-transgression of the sea level. (This study is supported by "Research on Exploration Technologies and an Onsite Verification to Enhance the Fracturing Efficiency of a Shale Gas Formation" of the Korea Institute of Energy Technology Evaluation and Planning (KETEP), granted financial resource from the Ministry of Trade, Industry & Energy, Republic of Korea.)

Slope-apron deposition in an ordovician arc-related setting: The Vuelta de Las Tolas Member (Suri Formation), Famatina Basin, northwest Argentina

USGS Publications Warehouse

Mangano, M.G.; Buatois, L.A.

1997-01-01

The Ordovician Suri Formation is part of the infill of the Famatina Basin of northwest Argentina, which formed in an active setting along the western margin of early Paleozoic Gondwana. The lower part of this formation, the Vuelta de Las Tolas Member, records sedimentation on a slope apron formed in an intra-arc basin situated on a flooded continental arc platform. The coincidence of a thick Arenig-Llanvirn sedimentary succession and volcanic-plutonic arc rocks suggests an extensional or transtensional arc setting, and is consistent with evidence of an extensional regime within the volcanic arc in the northern Puna region. The studied stratigraphic sections consist of volcanic rocks and six sedimentary facies. The facies can be clustered into four facies associations. Association 1, composed of facies A (laminated siltstones and mudstones) and B (massive mudstones and siltstones), is interpreted to have accumulated from silty-muddy high-and low-density turbidity currents and highly fluid, silty debris flows, with subsequent reworking by bottom currents, and to a lesser extent, hemipelagic suspension in an open-slope setting. Facies association 2 is dominated by facies C (current-rippled siltstones) strata. These deposits are interpreted to record overbank sedimentation from fine-grained turbidity currents. Facies E (matrix-supported volcanic breccias) interbedded with andesitic lava units comprises facies association 3. Deposition was contemporaneous with subaqueous volcanic activity, and accumulated from cohesive debris flows in a coarse-grained wedge at the base of slope. Facies association 4 is typified by facies D (vitric fine-grained sandstones and siltstones) and F (channelized and graded volcanic conglomerates and breccias) deposits. These strata commonly display thinning-and fining-upward trends, indicating sedimentation from highly-concentrated volcaniclastic turbidity currents in a channelized system. The general characteristics of these deposits of fresh pyroclastic detritus suggest that their accumulation was contemporaneous with, or post-dated shallow-water or subaereal explosive volcanism. The Vuelta de Las Tolas Member tends to show an overall random facies patterns reflecting the strong influence of non-cyclical episodic processes related to arc volcanism and slope sedimentation. The scarcity of resident ichnofaunas and the presence of thick packages of uniform mudstones suggest deposition under oxygen-depleted conditions in a topographically confined, ponded sub-basin. Interbasinal correlations favor comparison with Middle Arenig slope-apron successions formed in the northern Puna Basin and suggest a southward prolongation of the Arenig volcanic arc.

Authigenesis/Diagenesis of the Murray Formation Mudstone in Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Ming, D. W.; Rampe, E. B.; Grotzinger, J. P.; Hurowitz, J. A.; Morris, R. V.; Yen, A. S.; Blake, D. B.; Geller, R.; Sutter, B.

2016-01-01

The Mars Science Laboratory rover Curiosity has been exploring sedimentary deposits in Gale crater since August, 2012. The rover has traversed up section through approximately 150 m of sedimentary rocks deposited in fluvial, deltaic, and lacustrine environments (Bradbury group and overlying Mount Sharp group). The Murray formation lies at the base of the Mt. Sharp group and has been interpreted to be a finely laminated mudstone likely deposited in a subaqueous lacustrine environment. Four drill samples from several elevations in the Murray fm have been acquired by the rover's sampling system and delivered to the CheMin XRD instrument. The lower section of the Murray fm contains 2:1 phyllosilicate(s), hematite, jarosite, XRD amorphous materials, and primary basaltic minerals. Further up section, the Murray fm contains magnetite, cristobalite, tridymite, abundant Si-rich XRD amorphous materials along with plagioclase and K-feldspars. Murray formation materials appear to have been altered under an open hydrologic system based on the bulk chemistry of these materials measured by the Alpha Particle X-ray Spectrometer (APXS). The 2:1 phyllosilicate only occurs in the lowermost section of the Murray fm and may be detrital or formed during authigenesis of Murray fm materials, similar to the Fe-saponite and magnetite detected in a mudstone in the Yellowknife Bay fm near Curiosity's landing site (stratigraphically at the base of the Bradbury group). The occurrence of jarosite and hematite in the lower section indicates an acidic diagenetic event. These phases may have formed via several acidic alteration mechanisms, including (1) oxidative weathering of mafic igneous rocks containing sulfides; (2) sulfuric acid weathering of Fe-bearing phases; and (3) near-neutral pH subsurface solutions rich in Fe2(+) that were rapidly oxidized to Fe3(+), which produced excess acidity. The transition from abundant hematite in the lowermost Murray fm to magnetite moving up section may indicate changes in lake chemistry, i.e., variable redox conditions, possibly during authigenesis or subsequent diagenetic events. Tridymite, a high temperature mineral, (and possibly cristobalite) is detrital, potentially deposited in a lake from a distal silicic volcanic rock source or from crustal materials present prior to the Gale Crater impact event. Abundant Si-rich XRD amorphous materials in the upper sections of the Murray fm may be detrital or an aqueous alteration product of primary igneous phases and phyllosilicates. Curiosity's science team is still deciphering the authigenesis and diagenetic events that formed the Murray fm. The mineralogy and geochemistry of the formation suggest a complicated history with several (many?) episodes of aqueous alteration under a variety of environmental conditions.

The XRD Amorphous Component in John Klein Drill Fines at Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Morris, Richard V.; Ming,, Douglas W.; Blake, David; Vaniman, David; Bish, David L; Chipera, Steve; Downs, Robert; Morrison, Shaunna; Gellert, Ralf; Campbell, Iain;

Depositional controls on coal distribution and quality in the Eocene Brunner Coal Measures, Buller Coalfield, South Island, New Zealand

USGS Publications Warehouse

Flores, R.M.; Sykes, R.

1996-01-01

The Buller Coalfield on the West Coast of the South Island, New Zealand, contains the Eocene Brunner Coal Measures. The coal measures unconformably overlie Paleozoic-Cretaceous basement rocks and are conformably overlain by, and laterally interfinger with, the Eocene marine Kaiata Formation. This study examines the lithofacies frameworks of the coal measures in order to interpret their depositional environments. The lower part of the coal measures is dominated by conglomeratic lithofacies that rest on a basal erosional surface and thicken in paleovalleys incised into an undulating peneplain surface. These lithofacies are overlain by sandstone, mudstone and organic-rich lithofacies of the upper part of the coal measures. The main coal seam of the organic-rich lithofacies is thick (10-20 m), extensive, locally split, and locally absent. This seam and associated coal seams in the Buller Coalfield are of low- to high-volatile bituminous rank (vitrinite reflectance between 0.65% and 1.75%). The main seam contains a variable percentage of ash and sulphur. These values are related to the thickening and areal distribution of the seam, which in turn, were controlled by the nature of clastic deposition and peat-forming mire systems, marine transgression and local tidal incursion. The conglomeratic lithofacies represent deposits of trunk and tributary braided streams that rapidly aggraded incised paleovalleys during sea-level stillstands. The main seam represents a deposit of raised mires that initially developed as topogenous mires on abandoned margins of inactive braidbelts. Peat accumulated in mires as a response to a rise in the water table, probably initially due to gradual sea-level rise and climate, and the resulting raised topography served as protection from floods. The upper part of the coal measures consists of sandstone lithofacies of flu vial origin and bioturbated sandstone, mudstone and organic-rich lithofacies, which represent deposits of paralic (deltaic, barrier shoreface, tidal and mire) and marine environments. The fluvial sandstone lithofacies accumulated in channels during a sea-level stillstand. The channels were infilled by coeval braided and meandering streams prior to transgression. Continued transgression, ranging from tidal channel-estuarine incursions to widespread but uneven paleoshoreline encroachment, accompanied by moderate basin subsidence, is marked by a stacked, back-stepping geometry of bioturbated sandstone and marine mudstone lithofacies. Final retrogradation (sea-level highstand) is marked by backfilling of estuaries and by rapid landward deposition of the marine Kaiata Formation in the late Eocene.

The Investigation of Chlorate/Iron-Phase Mixtures as a Possible Source of Oxygen and Chlorine Detected by the Sample Analysis at Mars (SAM) Instrument in Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Clark, J.; Sutter, B.; Morris, R. V.; Archer, P. D.; Ming, D. W.; Niles, P.; Mahaffy, P.; Navarro-Gonzalez, R.

2016-01-01

The Sample Analysis at Mars (SAM) instrument on board the Curiosity Rover has detected oxygen and HCl gas releases from all analyzed Gale Crater sediments. The presence of perchlorate ClO4(sup-) and/or chlorates ClO3(sup-) are potential sources of the aforementioned O2 releases. The detections of O2 and HCl gas releases and chlorinated hydrocarbons by SAM coupled with the detection of perchlorates by Phoenix Lander's 2008 Wet Chemistry Laboratory all suggest that perchlorates, and possibly chorates, may be present in the Gale Crater sediments. Previous laboratory studies have attempted to replicate these O2 releases by heating perchlorates and chlorates in instruments operated similarly to those in the SAM instrument. Early studies found that pure perchlorates release O2 at temperatures higher than those observed in SAM data. Subsequently, studies were done to test the effects of mixing iron-phase minerals, analogous to those detected on Mars by ChemMin, with perchlorates. The iron in these minerals acts as a catalyst and causes O2 to be released from the perchlorate at a lower temperature. These studies found that perchlorate solutions mixed with either Hawaii palagonite or ferrihydrite produce O2 releases at temperatures similar to the Rocknest (RN) windblown deposit and the John Klein (JK) drill sample from the Sheepbed mudstone. The study also determined that perchlorate mixtures with magnetite, hematite, fayalite-magnetite, ilmentite, and pyrrhotite produce O2 releases at temperatures similar to the Confidence Hills (CH) drill sample from the Murray mudstone. Oxygen re-leases from pure chlorates were recently compared with the SAM data. Laboratory analyses determined that Ca-chlorate produces O2 and HCl peaks that are similar to those detected in RN and JK materials. Currently, no perchlorate/chlorate mixture with iron-phase minerals can explain the O2 releases from either the Cumberland (CB) drill sample from the Sheepbed mudstone or Windjana (WJ) drill sample from the Kimberly sandstone. Mixtures of chlorate solutions with iron-phase minerals may produce O2 peaks at temperatures that match those from CB and WJ materials. The goal of this work is to determine if heating chlorate solutions mixed with iron-phase minerals will produce O2 and HCl peak temperatures similar to O2 and HCl peak temperatures of sediments analyzed by SAM, particularly the WJ and CB materials.

Neogene stratigraphy, foraminifera, diatoms, and depositional history of Maria Madre Island, Mexico: Evidence of early Neogene marine conditions in the southern Gulf of California

USGS Publications Warehouse

McCloy, C.; Ingle, J.C.; Barron, J.A.

1988-01-01

Foraminifera and diatoms have been analyzed from an upper Miocene through Pleistocene(?) sequence of marine sediments exposed on Maria Madre Island, largest of the Tre??s Marias Islands off the Pacific coast of Mexico. The Neogene stratigraphic sequence exposed on Maria Madre Island includes a mid-Miocene(?) non-marine and/or shallow marine sandstone unconformably overlain by a lower upper Miocene to uppermost Miocene upper to middle bathyal laminated and massive diatomite, mudstone, and siltstone unit. This unit is unconformably overlain by lower Pliocene middle to lower bathyal sandstones and siltstones which, in turn, are unconformably overlain by upper Pliocene through Pleistocene(?) upper bathyal to upper middle bathyal foraminiferal limestones and siltstones. These beds are unconformably capped by Pleistocene terrace deposits. Basement rocks on the island include Cretaceous granite and granodiorite, and Tertiary(?) andesites and rhyolites. The upper Miocene diatomaceous unit contains a low diversity foraminiferal fauna dominated by species of Bolivina indicating low oxygen conditions in the proto-Gulf Maria Madre basin. The diatomaceous unit grades into a mudstone that contains a latest Miocene upper to middle bathyal biofacies characterized by Baggina californica and Uvigerina hootsi along with displaced neritic taxa. An angular unconformity separates the upper Miocene middle bathyal sediments from overlying lower Pliocene siltstones and mudstones that contain a middle to lower bathyal biofacies and abundant planktonic species including Neogloboquadrina acostaensis and Pulleniatina primalis indicating an early Pliocene age. Significantly, this Pliocene unit contains common occurrences of benthic species restricted to Miocene sediments in California including Bulimina uvigerinaformis. Pliocene to Pleistocene(?) foraminiferal limestones and siltstones characterize submarine bank accumulations formed during uplift of the Tre??s Marias Island area, and include abundant planktonic foraminifera such as Pulleniatina obliquiloculata and Neogloboquadrina duterteri. Common benthic foraminifera in this unit are indicative of upper bathyal water depths. The Neogene depositional history recorded on Maria Madre Island involves an early late Miocene subsidence event marking formation of the Tre??s Marias Basin with relatively undiluted diatomaceous sediment deposited in a low oxygen setting. Subsidence and deepening of the basin continued into the early Pliocene along with rapid deposition of terrigenous clastics. Uplift of the basinal sequence began in late Pliocene time accompanied by deposition of upper Pliocene-Pleistocene foraminiferal limestones on a rising submarine bank. Continued episodic uplift of the Neogene deposits brought the island above sea level by late Pleistocene time. ?? 1988.

Eocene bituminous coal deposits of the Claiborne group, Webb County, Texas

USGS Publications Warehouse

Hook, Robert W.; Warwick, Peter D.; Warwick, Peter D.; Karlsen, Alexander K.; Merrill, Matthew D.; Valentine, Brett J.

2011-01-01

Two bituminous coal zones, the San Pedro and the Santo Tomas, in the middle Eocene Claiborne Group of Webb County, south Texas (Figure 1), are among the coal resources that are not evaluated quantitatively as part of the current Gulf Coastal Plain coal resource assessment. Coal beds within these zones were mined by underground methods northwest of Laredo until 1939 and have been intermittently mined at the surface since 1979. These coals have long been regarded as unique within the Gulf Coast Tertiary coal-bearing section because they are high-volatile C bituminous in rank and because their physical characteristics resemble upper Carboniferous cannel coals of the Appalachians and Europe.Discontinuous exposures of the Santo Tomas and the underlying San Pedro coal zone extend northwestward from Dolores for approximately 15 to 21 mi along the breaks of the Rio Grande and its tributaries in Webb County (Figure 1). This part of south Texas lies along the southwestern flank of the Rio Grande Embayment, which extends south and southeastwardly through the Mexican States of Coahuila, Nuevo León, and Tamaulipas (Figure 1). Within the embayment, the lower to middle part of the Claiborne Group consists of marine mudstones (Reklaw Formation) in the east and northeast and sandstones and mudstones (Bigford Formation) in the south and southwest (Figure 2). The marine mudstones coarsen upward into fluvial-deltaic sandstones (Queen City Sand) that prograded gulfward across eastern and central Texas (Guevara and Garcia, 1972). To the west and southwest, the interval overlying the Bigford Formation becomes less sandy, and claystones (El Pico Clay) predominate. Although the San Pedro coal zone has been placed traditionally near the top of the Bigford Formation and the Santo Tomas coal zone near the base of the El Pico Clay, recent work has failed to validate a mappable contact between these formations (Warwick and Hook, 1995). The coal beds dip northeast at less than 2 degrees towards the synclinal axis of the basin.The following summary is based upon published and unpublished reports; drillhole records (geophysical logs, descriptions of cores and cuttings); coal-quality data obtained from the permit files of the Railroad Commission of Texas and recent sampling by the U.S. Geological Survey (USGS); a preliminary review of proprietary data acquired recently by the USGS; and field work conducted by the USGS since 1994. A total of approximately 200 drillhole records was examined.

Evidence for Acid-Sulfate Alteration in the Pahrump Hills Region, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Ming, D. W.; Blake, D. F.; Morris, R. V.; Bish, D. L.; Bristow, T. F.; Crisp, J. A.; Morookian, J. M.; Vaniman. D. T.; Chipera, S. J.;

The determination of substrate conditions from the orientations of solitary rugose corals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bolton, J.C.; Driese, S.G.

1990-10-01

The substrate conditions of mudstone strata formed in ancient epicontinental settings may be determined from taphonomic assemblages of solitary rugose corals. Equal-area plots on the orientations of preserved corals can be used to infer whether subsequent hydrodynamic conditions affected any post-mortem reworking of the corals. Mechanically stable positions for curved corals can be determined. Curved corals preserved in mechanically stable positions are interpreted to have been deposited on firm or hard substrates. Curved corals preserved in mechanically unstable positions were probably embedded in soft or soupy substrates.

Tuffaceous Mud is a Volumetrically Important Volcaniclastic Facies of Reararc Submarine Volcanism

NASA Astrophysics Data System (ADS)

Gill, J. B.; Bongiolo, E.; Miyazaki, T.; Hamelin, C.; Jutzeler, M.

2016-12-01

Unexpectedly, about 2/3 of the 1806 m of rock drilled during IODP Exp 350 on the flank of an Upper Miocene andesitic seamount in the Izu reararc was tuffaceous mud and tuffaceous mudstone that accumulated at high carbonate-free sedimentation rates (60-120 m/MY). This rate is several times faster than at adjacent sites in the forearc or incoming plate. Most tuffaceous muds contain <1% <2 mm-sized fragments of glass shards and plag±cpx crystals. Most muds are dacitic in bulk composition on an anhydrous, carbonate-free basis. They are intercalated with thin ash or tuff beds. The trace element and Sr-Nd-Hf-Pb isotope geochemistry of carbonate-free tuffaceous mud and mudstone indicates that >70% and often >90% of them consist of local volcanic materials that range from basalt to rhyolite. Most exceptions were deposited during Pleistocene glacial intervals. Consequently, tuffaceous mud is an important submarine volcaniclastic facies destined to become shale or slate in the geological record while retaining geochemical information about its provenance. Even though the drill site was <10 km from the summit of a 2-km-high and at times subaerially exposed seamount, and the sedimentation rate exceeded that in the adjacent forearc, tuffaceous mud was the principal reararc volcaniclastic facies. To explain this fine grain size, we infer that much of the submarine volcanism was explosive despite water depths approaching 2 km. The resulting very fine glass quickly becomes clay or is too small to be recognized in thin section or smear slides, and can be sampled only in sediment cores.

Rapid sea-level change in the Late Guadalupian (Permian) on the Tethyan side of South China: litho- and biostratigraphy of the Chaotian section in Sichuan

PubMed Central

Isozaki, Yukio; Yao, Jianxin; Ji, Zhangshen; Saitoh, Masafumi; Kobayashi, Noritada; Sakai, Harutaka

2008-01-01

The Capitanian (Late Guadalupian) Maokou Formation at Chaotian in northern Sichuan, South China, is composed mainly of shallow marine shelf carbonates deposited on the Tethyan side of South China. By detailed field mapping and scientific drilling, we newly found out unique fossil assemblages and a sharp lithologic change in the upper part of the Maokou Formation. The main part of the Maokou Formation (over 130 m thick) is composed of algal packstone with Wordian-Capitanian large-tested fusulines, rugose corals and other sessile benthos, whereas the Uppermost Member (13 m thick) is composed of black limy mudstone/chert with Capitanian offshore biota (ammonoids, radiolarians, and conodonts). The topmost Capitanian conodont zones are missing; however, the Maokou Formation is disconformably overlain by 260 ± 4 Ma volcanic ash (Wangpo bed) and the Early Lopingian Wujiaping Formation with plant-bearing coaly mudstone and shallow marine carbonates (packstone). The newly identified facies change indicates that northern Sichuan has experienced rapid sea-level changes in the late Guadalupian, i.e., first a transgression in the mid-Capitanian and then a regression across the Guadalupian-Lopingian boundary. As the end-Guadalupian is characterized by a global regression, such a volatile sea-level fluctuation, in particular the sea-level rise, is unique to the Tethyan side of South China. The newly recognized relatively deep-water late Guadalupian sequence adds new paleo-environmental information and further provides a paleotectonic interpretation of the low-latitude eastern Tethyan margin immediately before the end-Guadalupian mass extinction. PMID:18941307

IODP Expedition 351 Lithostratigraphy: Volcaniclastic Record of Izu-Bonin-Mariana (IBM) Arc Initiation

NASA Astrophysics Data System (ADS)

Barth, A. P.; Brandl, P. A.; Li, H.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Tepley, F. J., III; Yogodzinski, G. M.

2014-12-01

The destruction of lithospheric plates by subduction is a fundamentally important process leading to arc magmatism and the creation of continental crust, yet subduction initiation and early magmatic arc evolution remain poorly understood. For many arc systems, onset of arc volcanism and early evolution are obscured by metamorphism or the record is deeply buried; however, initial products of arc systems may be preserved in forearc and backarc sedimentary records. IODP Expedition 351 recovered this history from the dispersed ash and pyroclast record in the proximal rear-arc of the northern IBM system west of the Kyushu-Palau Ridge. Drilling at Site U1438 in the Amami Sankaku Basin recovered a thick volcaniclastic record of subduction initiation and the early evolution of the Izu-Bonin Arc. A 160-m thick section of Neogene sediment overlies 1.3 kilometers of Paleogene volcaniclastic rocks with andesitic average composition; this volcaniclastic section was deposited on mafic volcanic basement rocks. The thin upper sediment layer is primarily terrigenous, biogenic and volcaniclastic mud and ooze with interspersed ash layers. The underlying Eocene to Oligocene volcaniclastic rocks are 33% tuffaceous mudstone, 61% tuffaceous sandstone, and 6% conglomerate with volcanic and rare sedimentary clasts commonly up to pebble and rarely to cobble size. The clastic section is characterized by repetitive conglomerate and sandstone-dominated intervals with intervening mudstone-dominated intervals, reflecting waxing and waning of coarse arc-derived sediment inputs through time. Volcanic lithic clasts in sandstones and conglomerates range from basalt to rhyolite in composition and include well-preserved pumice, reflecting a lithologically diverse and compositionally variable arc volcanic source.

Magneto- and litho-stratigraphic records of the Oligocene-Early Miocene climatic changes from deep drilling in the Linxia Basin, Northeast Tibetan Plateau

NASA Astrophysics Data System (ADS)

Wu, Fuli; Fang, Xiaomin; Meng, Qingquan; Zhao, Yan; Tang, Fenjun; Zhang, Tao; Zhang, Weilin; Zan, Jinbo

2017-11-01

The East Asian monsoon is generally regarded to have initiated at the transition from the Late Oligocene to the Early Miocene. However, little is known about this process because of a lack of continuous strata across the boundary between the Late Oligocene and the Early Miocene in Asia. Based on previous drilling (core HZ-1) in the Miocene sediments in the southern Linxia Basin in NW China, we drilled a new 620 m core (HZ-2) into the Late Oligocene strata and obtained 206 m of continuous new core. The detailed paleomagnetism of the new core reveals eleven pairs of normal and reversed polarity zones that can be readily correlated with chrons 6Bn-9n of the geomagnetic polarity time scale (GPTS), define an age interval of 21.6-26.5 Ma and indicate continuity from the Late Oligocene to Early Miocene. The core is characterized by the remarkable occurrence of brownish-red paleosols of luvic cambisols (brown to luvic drab soils) above reddish-brown floodplain siltstones and mudstones, which suggest that the East Asian monsoon likely began by 26.5 Ma. In contrast to the siltstone and mudstone of the Late Oligocene strata, the Miocene strata begin with a thick fine sandstone bed, which marks sudden increases in erosion and loading that most likely reflect a response to tectonic uplift. The hematite content and redness index records of the core further demonstrate that the monsoonal climate in the Late Oligocene to Early Miocene in this area was mainly controlled by global temperature trends and events.

Rapid sea-level change in the Late Guadalupian (Permian) on the Tethyan side of South China: litho- and biostratigraphy of the Chaotian section in Sichuan.

PubMed

Isozaki, Yukio; Yao, Jianxin; Ji, Zhangshen; Saitoh, Masafumi; Kobayashi, Noritada; Sakai, Harutaka

2008-01-01

The Capitanian (Late Guadalupian) Maokou Formation at Chaotian in northern Sichuan, South China, is composed mainly of shallow marine shelf carbonates deposited on the Tethyan side of South China. By detailed field mapping and scientific drilling, we newly found out unique fossil assemblages and a sharp lithologic change in the upper part of the Maokou Formation. The main part of the Maokou Formation (over 130 m thick) is composed of algal packstone with Wordian-Capitanian large-tested fusulines, rugose corals and other sessile benthos, whereas the Uppermost Member (13 m thick) is composed of black limy mudstone/chert with Capitanian offshore biota (ammonoids, radiolarians, and conodonts). The topmost Capitanian conodont zones are missing; however, the Maokou Formation is disconformably overlain by 260+/-4 Ma volcanic ash (Wangpo bed) and the Early Lopingian Wujiaping Formation with plant-bearing coaly mudstone and shallow marine carbonates (packstone). The newly identified facies change indicates that northern Sichuan has experienced rapid sea-level changes in the late Guadalupian, i.e., first a transgression in the mid-Capitanian and then a regression across the Guadalupian-Lopingian boundary. As the end-Guadalupian is characterized by a global regression, such a volatile sea-level fluctuation, in particular the sea-level rise, is unique to the Tethyan side of South China. The newly recognized relatively deep-water late Guadalupian sequence adds new paleo-environmental information and further provides a paleotectonic interpretation of the low-latitude eastern Tethyan margin immediately before the end-Guadalupian mass extinction.

Imaging Pathways in Fractured Rock Using Three-Dimensional Electrical Resistivity Tomography.

PubMed

Robinson, Judith; Slater, Lee; Johnson, Timothy; Shapiro, Allen; Tiedeman, Claire; Ntarlagiannis, Dimitrios; Johnson, Carole; Day-Lewis, Frederick; Lacombe, Pierre; Imbrigiotta, Thomas; Lane, John

2016-03-01

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three-dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high-resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time-lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone. © 2015, National Ground Water Association.

Shallow and marginal marine Triassic trace fossils and ichnofabric from northwest Australia (ocean drilling program leg 122)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Droser, M.L.; O'Connell, S.

The ichnofabric index method of ranking amount of bioturbation was used for the first time in conjunction with discrete trace fossils to examine shallow-water marine cores. Previous ichnological studies on cores have focused primarily on outer shelf and deep-sea discrete trace fossils. Upper Triassic cores examined in this study were recovered off northwest Australia during ODP Leg 122. These sediments were deposited in a shallow-water and continental shelf setting, which included swamp and prodelta environments. The most common lithology is siltstone with interbedded mudstone and sandstone. Sediments deposited in a swamp setting have rootlets and coal beds with an ichnologicalmore » record consisting primarily of mottled bedding rather than discrete trace fossils. Ichnofabric indices 1 through 5 were recorded. Marginal marine/lagoonal facies have a low trace fossil diversity with common Chondrites, Planolites, and Teichichnus. Recorded ichnofabric indices include 1, 2, and 3. Laminated mudstones and siltstones (ii1) are most common. Fully marine open shelf strata are thoroughly bioturbated (ii5 and ii6) with Thalassinoides, Zoophycos, Teichichnus, and Planolites. Wackestone and packstone occur in discrete uppermost Triassic intervals and have ii1 through ii6 represented. In part due to the drilling process, sandstones and reefal limestones were poorly recovered and ichnofabric is not well preserved. Physical sedimentary structures and lateral facies relationships can be difficult to discern in core. In shallow marine deposits, the distribution of ichnofabric indices and discrete trace fossils within these strata provide an additional important data base to evaluate depositional environments.« less

Stratigraphy and sedimentation of Mississippian Ste. Genevieve-Cedar Bluff interval, Southwestern Indiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Breedon, D.; Droste, J.B.; Murray, H.H.

1983-09-01

The Ste. Genevieve Limestone and Cedar Bluff Group of Mississippian age, both important sources of hydrocarbons in the Illinois basin, were traced from a subsurface stratigraphic section in White County, Illinois (described by Swan in 1963, across Gibson and Daviess Counties, Indiana, using electric logs and sample descriptions from 84 wells. The Ste. Genevieve Limestone is subdivided into four members and the Cedar Bluff Group into three formations. Six cross sections and nine isopach maps based on 300 wells show that these units comprise a succession of alternating fine- and coarse-grained carbonate rocks with only minor interruptions of sandstone andmore » shale. Two complete coarsening-upward cycles are apparent, and a third cycle is incomplete. Each cycle consists of a lower sequence of lime mudstones and wackestones, and an upper sequence of oolitic and skeletal grainstones. These cycles are the record of successive shoaling-upward cycles of sedimentation on a shallow marine platform. The lower mudstone-wackestone sequence represents deposition in a shallow subtidal environment, and the upper oolitic-skeletal grainstone unit represents development of oolite shoals and tidal channels in very shallow waters. Terrigenous clastic sediments brought into the basin by the Michigan river periodically encroached into the marine environment. Dolomitization of the fine-grained carbonate sediments is largely restricted to areas which are overlain by oolitic grainstones. In eastern Daviess County, indentification of the individual stratigraphic units in this interval is somewhat tenuous, but tracing the units from eastern Illinois into Indiana made correlation and identification of the individual stratigraphic units possible by using electric logs and sample descriptions.« less

Stratigraphy and depositional environment of upper Cambrian Red Lion Formation, southwestern Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hayden, L.L.; Bush, J.H.

1987-08-01

The Red Lion Formation was examined along a northwest-southeast transect from Missoula to Bozeman, Montana. Lateral equivalents are the Snowy Range Formation east of Bozeman and the upper Fishtrap Dolomite in northwest Montana. The basal Dry Creek Member (0-5 m) consists of shale interbedded with quartz siltstones and sandstones. The overlying Sage Member, up to 115 meters in thickness, is characterized by ribbon carbonate beds containing lime mudstone and quartzose calcisiltite couplets arranged in fining-upward sequences 1-5 cm thick. Couplets are interlayered in places with thin (1-5 cm) to medium bedded (6-70 cm) units of laminated and non-laminated calcareous siltstones,more » flat-pebble conglomerates, trilobite packstones, cryptalgal boundstones, bioturbated lime mudstones and shales. In places, the upper Sage contains columnar and domal algal features. The Red Lion Formation is considered to be one Grand Cycle with the Dry Creek representing a lower inner detrital half-cycle and the Sage an upper carbonate half-cycle. The Dry Creek formed as the result of a westward clastic pulse from the inner detrital belt across an intrashelf basin onto outer middle carbonate peritidal complexes of the underlying Pilgrim Formation. Lower Sage ribbon rocks were deposited in storm-crossed, below wave-base areas. During deposition of the upper Sage, shallowing formed discontinuous algal-peritidal complexes over much of western and central Montana. These complexes were less extensive than earlier Cambrian buildups owing to slower rates of basin subsidence and clastic input suppressing carbonate production.« less

A new petroleum system in offshore Campeche, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Limon, M.

1996-08-01

A new petroleum system in the Sonda de Campeche of Mexico has been recently defined. This system is entirely Oxfordian in age, comprising eolian and beach sandstone reservoirs overlain by evaporates, which provide the seal, and in turn, overlain by organically rich, low energy carbonate mudstones, which are source rocks. This petroleum system was created during the late stages of opening of the Gulf of Mexico. The source rocks are composed of an algal mudstone overlying the evaporite sequence. Geochemistry, isotopic and biomarkers analyses allowed us to identify the Oxfordian source rock and also to obtain an excellent correlation withmore » the Oxfordian oils reservoired in the discoveries. Oxfordian sandstones in the Sonda de Campeche exhibit excellent reservoir quality, ranging from 6 to 26% porosity and 2 to 2730 md permeability. The porosity is principally secondary due to the dissolution of dolomite, anhydrite and cement, but intergranular porosity can also be observed. The tectonic evolution of the Gulf of Mexico in the Sonda de Campeche produced three types of traps (1) faulted blocks of {open_quotes}domino{close_quotes} style, developed during the extensional stage; (2) faulted anticlines formed during the Middle Miocene compressive event; and (3) traps related to diapirism of salt of the Middle Miocene-Pleistocene. The seal rocks are mainly composed by Oxfordian evaporates. Oil generation was initiated in the Middle Miocene following the compressional stage. The potential source rocks reached maturity beneath a thick Tertiary overburden in downthrown fault blocks and expelled hydrocarbons which migrated in a predominantly vertical direction. The oils do not show any diagnostic evidence of bacterial alteration.« less

A new petroleum system in offshore Campeche, Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gonzalez, R.; Cruz, P.; Limon, M.

1995-08-01

A new petroleum system in the Sonda de Campeche of Mexico has been recently defined. This system is entirely Oxfordian in age, comprising eolian and beach sandstone reservoirs overlain by evaporites, which provide the seal, and in turn, overlain by organically rich, low energy carbonate mudstones, which are source rocks. This petroleum system was created during the late stages of opening of the Gulf of Mexico. The source rocks are composed of an algal mudstone overlying the evaporite sequence. Geochemistry, isotopic and biomarkers analyses allowed us to identify the Oxfordian source rock and also to obtain an excellent correlation withmore » the oils Oxfordian reservoired in the discoveries. Oxfordian sandstones in the Sonda de Campeche exhibit excellent reservoir quality, ranging from 6 to 26% porosity and 2 to 2730 md permeability. The porosity is principally secondary due to the dissolution of dolomite anhydrite and cement but intergranular porosity can also be observed. The tectonic evolution of the Gulf of Mexico, in the Sonda de Campeche produced three types of traps (1) faulted blocks of {open_quotes}domino{close_quotes} style, developed during the extensional stage; (2) faulted anticlines formed during the Middle Miocene compressive event; and (3) traps related to diapirism of salt of the Middle Miocene-Pleistocene. The seal rocks are mainly composed by Oxfordian evaporates. Oil generation was initiated in the Middle Miocene following the compressional stage. The potential source rocks reached maturity beneath a thick Tertiary overburden in downthrown fault blocks and expelled hydrocarbons which migrated in a predominantly vertical direction. The oils do not show any diagnostic evidence of bacterial alteration.« less

Petroleum geology of the Cusiana Field, Llanos Basin Foothills, Colombia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cazier, E.C.; Hayward, A.B.; Espinosa, G.

1995-10-01

Cusiana field is located in the Llanos Foothills, 150 mi (240km) northeast of Bogota, Colombia. Light oil, gas, and condensate in Cusiana occur at drilling depths that average 15,000 ft (4575 m) in an asymmetric, hanging-wall anticlinal trap 15 mi (25 km) long and 3-4 mi (5-6 km) across, formed during the Miocene-Holocene deformation of the Eastern Cordillera. Top and lateral seals are provided by marine mudstones of the Oligocene Carbonera Group, and support a hydrocarbon column of over 1500 ft (460 m). Biomarker data from the hydrocarbons indicate a marine mudstone source interpreted to be the Turonian-Coniacian Gacheta Formation.more » Over 50% of the reserves occur in upper Eocene Mirador Formation sandstones, which were deposited predominantly in estuarine environments. Additional, deeper reservoirs include estuarine sandstones of the Paleocene Barco Formation and the shallow-marine Santonian-Campanian Upper Guadalupe Sandstone. Porosity in Cusiana is relatively low. Good permeability is retained, however, because the reservoirs are pure quartz-cemented quartzarenites that lack permeability-reducing authigenic clays and carbonate cements. Core and well test analyses indicate matrix permeability, not fracture permeability, provides the high deliverability of Cusiana wells. Cusiana hydrocarbon phases exist in a near-miscible, critical-point state. Reservoir simulation indicates very high liquid hydrocarbon recoveries should be possible from all reservoirs by using the reinjection of produced gas to maintain reservoir pressure and to vaporize residual liquids. The field contains up to 1.5 MSTB of hydrocarbon liquid reserves and 3.4 Tcf of gas.« less

Permanganate diffusion and reaction in sedimentary rocks.

PubMed

Huang, Qiuyuan; Dong, Hailiang; Towne, Rachael M; Fischer, Timothy B; Schaefer, Charles E

2014-04-01

In situ chemical oxidation using permanganate has frequently been used to treat chlorinated solvents in fractured bedrock aquifers. However, in systems where matrix back-diffusion is an important process, the ability of the oxidant to migrate and treat target contaminants within the rock matrix will likely determine the overall effectiveness of this remedial approach. In this study, a series of diffusion experiments were performed to measure the permanganate diffusion and reaction in four different types of sedimentary rocks (dark gray mudstone, light gray mudstone, red sandstone, and tan sandstone). Results showed that, within the experimental time frame (~2 months), oxidant migration into the rock was limited to distances less than 500 μm. The observed diffusivities for permanganate into the rock matrices ranged from 5.3 × 10(-13) to 1.3 × 10(-11) cm(2)/s. These values were reasonably predicted by accounting for both the rock oxidant demand and the effective diffusivity of the rock. Various Mn minerals formed as surface coatings from reduction of permanganate coupled with oxidation of total organic carbon (TOC), and the nature of the formed Mn minerals was dependent upon the rock type. Post-treatment tracer testing showed that these Mn mineral coatings had a negligible impact on diffusion through the rock. Overall, our results showed that the extent of permanganate diffusion and reaction depended on rock properties, including porosity, mineralogy, and organic carbon. These results have important implications for our understanding of long-term organic contaminant remediation in sedimentary rocks using permanganate. Copyright © 2014 Elsevier B.V. All rights reserved.

Two Possible Ways Boron Got into Veins on Mount Sharp

NASA Image and Video Library

2016-12-13

This graphic portrays two hypotheses about how the element boron ended up in calcium sulfate veins found within mudstone layers of the Murray formation on Mars' lower Mount Sharp. Hypothesis A is presented left-to-right in the upper four panels; hypothesis B in the lower four. Note that the two final panels are identical, depicting conditions found by NASA's Curiosity Mars rover. Calcium sulfate is the veins' main ingredient. The mudstone matrix around the veins resulted from deposition of sediments in a lake environment in Mars' Gale Crater billions of years ago. In hypothesis A: (1) Boron dissolved in the lake and was incorporated into the lake bottom clays that became the Murray formation. (2) The lake then dried and the bedrock fractured. (3) Later groundwater interacted with the clays under conditions that released the boron into the groundwater. (4) Then, the boron was deposited along with the calcium sulfate that makes up the bulk of these veins. In hypothesis B: (1) Boron was not incorporated into the clays as the lake was active. (2) Instead, when the lake dried out, it left a layer of boron-containing salts, and likely other types of salts, such as sodium chloride (table salt) and calcium sulfates, in an overlying layer that Curiosity has not yet visited. The bedrock fractured. (3) Groundwater later dissolved this layer of evaporite salts and moved the salts down into the older layers the rover has investigated. (4) The groundwater deposited the evaporite salts with the calcium sulfate that makes up the bulk of these veins. http://photojournal.jpl.nasa.gov/catalog/PIA21253

Deep-water lithofacies and conodont faunas of the Lisburne Group, western Brooks Range, Alaska: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1992

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Anita G.; Schmidt, Jeanine M.

1993-01-01

Deep-water lithofacies of the Lisburne Group occur in thrust sheets in the western part of the foreland fold and thrust belt of the Brooks Range and represent at least three discrete units. The Kuna Formation (Brooks Range allochthon) consists mostly of spiculitic mudstone and lesser shale; subordinate carbonate layers are chiefly diagenetic dolomite. Predominantly shale sections of the Kuna that contain few sponge spicules occur in the western part of the study area. The Akmalik Chert (Picnic Creek allochthon) is mostly radiolarian-spiculitic chert; rare limy beds are calcitized radiolarite. The Rim Butte unit (Ipnavik River allochthon) consists chiefly of calcareous turbidites, derived from both shallow- and deep-water sources, interbedded with spiculitic mudstone. Much of the material in the turbidites came from a contemporaneous carbonate platform and margin, but some fossils and lithic clasts were eroded from older, already lithified carbonate-platform rocks. All three units appear to be roughly coeval and are chiefly Osagean (late Early Mississippian) in age in the study area.Shallow-water lithofacies of the Lisburne Group exposed in the Howard Pass area (Brooks Range allochthon) are mostly of Meramecian (early Late Mississippian) age. Thus, these carbonate-platform rocks were not the source of the calcareous turbidites in the Rim Butte unit. Rim Butte turbidites could have been derived from older platform carbonate rocks such as those of the Utukok Formation (Kelly River allochthon) exposed mainly to the west of the Howard Pass quadrangle.

A combined geomorphological and geophysical approach to characterising relict landslide hazard on the Jurassic Escarpments of Great Britain

NASA Astrophysics Data System (ADS)

Boon, David P.; Chambers, Jonathan E.; Hobbs, Peter R. N.; Kirkham, Mathew; Merritt, Andrew J.; Dashwood, Claire; Pennington, Catherine; Wilby, Philip R.

2015-11-01

The Jurassic Escarpment in the North York Moors in Northern Britain has a high density of deep-seated relict landslides but their regional hazard is poorly understood due to a lack of detailed case studies. Investigation of a typical relict landslide at Great Fryup Dale suggests that the crop of the Whitby Mudstone Formation is highly susceptible to landslide hazards. The mudstone lithologies along the Escarpment form large multiple rotational failures which break down at an accelerated rate during wetter climates and degrade into extensive frontal mudflows. Geomorphological mapping, high resolution LiDAR imagery, boreholes, and geophysical ERT surveys are deployed in a combined approach to delimit internal architecture of the landslide. Cross-sections developed from these data indicate that the main movement displaced a bedrock volume of c. 1 × 107 m3 with a maximum depth of rupture of c. 50 m. The mode of failure is strongly controlled by lithology, bedding, joint pattern, and rate of lateral unloading. Dating of buried peats using the AMS method suggests that the 10 m thick frontal mudflow complex was last active in the Late Holocene, after c. 2270 ± 30 calendar years BP. Geomorphic mapping and dating work indicates that the landslide is dormant, but slope stability modelling suggests that the slope is less stable than previously assumed; implying that this and other similar landslides in Britain may become more susceptible to reactivation or extension during future wetter climatic phases. This study shows the value of a multi-technique approach for landslide hazard assessment and to enhance national landslide inventories.

Block Slides on Extremely Weak Tectonic Clay Seams in Openly Folded Tertiary Mud-Rocks at Auckland and the Rangitikei Valley, North Island, New Zealand

NASA Astrophysics Data System (ADS)

Prebble, Warwick M.; Williams, Ann L.

2016-06-01

Block slides have developed on extremely weak, thin clay seams of tectonic origin, parallel to bedding in gently dipping sandstones and mudstones of Tertiary age. Two areas of noted instability are investigated at Auckland and the Rangitikei valley. Dimensions range from 100 m across × 100 m long for short displacement block slides up to 4 km across × 3 km long for large landslide complexes in which block slides are a major component. Displacements of blocks range from incipient (cm) through short (30 m) to 2 or 3 km for large slides. Many of the Auckland slides are dormant but likely to move in a 2000 year return period earthquake or 100 year high intensity rain storm. At Rangitikei there are many active, younger slides. Sliding rates for active failures vary from a few cm/year to 50 m in 30 min. Host rocks are weak to very weak clayey sandstones and sandy mudstones. The seams are rich in smectite. They have polished and crushed walls, may have slickensides and some contain rounded rock fragments. Laboratory shear strength of the seams is 13 kPa cohesion and 13° friction, with a lower bound of 8° at zero cohesion. Strength is increased at the field scale by waviness, steps and splays. Continuity can be demonstrated over distances of hundreds of metres. Key investigation methods were mapping, shafts and trenches. Tectonic uplift, folding and faulting of the weak Tertiary strata and river down-cutting are perpetuating block slide development.

Thermophysical properties along Curiosity's traverse in Gale crater, Mars, derived from the REMS Ground Temperature Sensor

NASA Astrophysics Data System (ADS)

Vasavada, A. R.; Piqueux, S.

2016-12-01

The REMS instrument onboard the Mars Science Laboratory rover, Curiosity, has measured ground temperature nearly continuously at hourly intervals for two Mars years. Coverage of the entire diurnal cycle at 1 Hz is achieved every few martian days. We compare these measurements with predictions of surface-atmosphere thermal models to derive the apparent thermal inertia and thermally derived albedo along the rover's traverse, after accounting for the radiative effects of dust as well as atmospheric water ice during fall and winter, as is necessary to match the measured seasonal trend. The REMS measurements can distinguish between active sand, other loose materials, mudstone, and sandstone based on their thermophysical properties. However, the thermal inertias of bedrock-dominated surfaces ( 350-550 J m-2 K-1 s-½) are lower than expected. We use the detailed shape of the diurnal ground temperature curve to infer the effects of lateral mixing of different materials within the sensor footprint, as well as vertical heterogeneity. While results of this forward modeling approach are non-unique, we find surface configurations capable of creating the observed thermal responses that also are consistent with rover imagery. Bedrock thermal inertias isolated by this modeling are 1000-1900 J m-2 K-1 s-½ for mudstone and 700 J m-2 K-1 s-½ for sandstone. This methodology provides a better basis for inferring properties such as rock porosity, cement composition, and degree of cementation from the thermal inertia. These results highlight the advantages of deriving thermophysical properties from ground temperature records well-sampled in local time.

Thermophysical Properties Along Curiosity's Traverse in Gale Crater, Mars, Derived from the REMS Ground Temperature Sensor

NASA Technical Reports Server (NTRS)

Vasavada, Ashwin R.; Piqueux, Sylvain; Lewis, Kevin W.; Lemmon, Mark T.; Smith, Michael Doyle

2016-01-01

The REMS instrument onboard the Mars Science Laboratory rover, Curiosity, has measured ground temperature nearly continuously at hourly intervals for two Mars years. Coverage of the entire diurnal cycle at 1 Hz is available every few martian days. We compare these measurements with predictions of surface atmosphere thermal models to derive the apparent thermal inertia and thermally derived albedo along the rovers traverse after accounting for the radiative effects of atmospheric water ice during fall and winter, as is necessary to match the measured seasonal trend. The REMS measurements can distinguish between active sand, other loose materials, mudstone, and sandstone based on their thermophysical properties. However, the apparent thermal inertias of bedrock dominated surfaces [approx. 350-550 J m(exp. -2) K(exp. -1 s(exp. -1/2 )] are lower than expected. We use rover imagery and the detailed shape of the diurnal ground temperature curve to explore whether lateral or vertical heterogeneity in the surface materials within the sensor footprint might explain the low inertias. We find that the bedrock component of the surface can have a thermal inertia as high as 650-1700 J m(exp. -2) K(exp. -1) s(exp. -1/2) for mudstone sites and approx. 700 J m(exp. -2) K(exp. -1) s(exp. - 1/2) for sandstone sites in models runs that include lateral and vertical mixing. Although the results of our forward modeling approach may be non-unique, they demonstrate the potential to extract information about lateral and vertical variations in thermophysical properties from temporally resolved measurements of ground temperature.

Sedimentology of paleochannels on foreland coastal plain, Judith River Formation (upper Cretaceous), southeast Alberta

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koster, E.H.

1984-04-01

The upper 90 m (295 ft) of the sub-Bearpaw Judith River Formation, continuously exposed in the badlands along the Red Deer River 185 km (115 mi) east of Calgary, is famous for the unrivaled assemblage of dinosaur fossils. Dinosaur Provincial Park presents are a rare opportunity to view the architecture of a foreland coastal-plain sequence as well as to clarify the origin and distribution of subbituminous coal zones and gas reservoirs associated with this formation across southeast Alberta. The distal reaches of paleodrainage from the developing Cordillera to the Western Interior seaway are being examined by north-south traversed across themore » badlands. Sharp-based paleochannel units, enclosed by rooted, olive-gray mudstone sequences that are commonly 4-6 m (13-20 ft) thick, vary between 2 end members. The first contains laterally accreted sand-mud couplets with abundant macrofloral debris, and represents cyclical, low-energy growth of point bars, possible with an estuarine influence. The second, mainly comprising cosets of large trough cross-beds with mudstone intraclasts, was formed by episodic aggradation of high-energy systems. An intermediate composite type displays evidence for an energy increase as channel sinuosity decreased. This variation in paleochannel type is attributed to alternating alluviation/rejuvenation associated with an unstable base level. Coal zones and potential reservoirs appear to be associated with the transgressive and regressive phases, respectively, of the Bearpaw coast. Amalgamation of paleochannels - marked by laterally extensive horizons of bone fragments, lithic and intraclastic gravel - is more common seaward over the axial region of the Sweetgrass arch.« less

Paleogeographic evolution of carbonate reservoirs: geological and geophysical analysis at the Albian Campos Basin, Brazil

NASA Astrophysics Data System (ADS)

Castillo Vincentelli, Maria Gabriela; Favoreto, Julia; Roemers-Oliveira, Eduardo

2018-02-01

An integrated geophysical and geological analysis of a carbonate reservoir can offer an effective method to better understand the paleogeographical evolution and distribution of a geological reservoir and non-reservoir facies. Therefore, we propose a better method for obtaining geological facies from geophysical facies, helping to characterize the permo-porous system of this kind of play. The goal is to determine the main geological phases from a specific hydrocarbon producer (Albian Campos Basin, Brazil). The applied method includes the use of a petrographic and qualitative description from the integrated reservoir with seismic interpretation of an attribute map (energy, root mean square, mean amplitude, maximum negative amplitude, etc), all calculated at the Albian level for each of the five identified phases. The studied carbonate reservoir is approximately 6 km long with a main direction of NE-SW, and it was sub-divided as follows (from bottom to top): (1) the first depositional sequence of the bank was composed mainly of packstone, indicating that the local structure adjacent to the main bank is protected from environmental conditions; (2) characterized by the presence of grainstone developed at the higher structure; (3) the main sequence of the peloidal packstone with mudstones oncoids; (4) corresponds to the oil production of carbonate reservoirs formed by oolitic grainstone deposited at the top of the carbonate bank; at this phase, rising sea levels formed channels that connected the open sea shelf with the restricted circulation shelf; and (5) mudstone and wackestone represent the system’s flooding phase.

Facies transition and depositional architecture of the Late Eocene tide-dominated delta in northern coast of Birket Qarun, Fayum, Egypt

NASA Astrophysics Data System (ADS)

Abdel-Fattah, Zaki A.

2016-07-01

Late Eocene successions in the Fayum Depression display notable facies transition from open-marine to brackish-marine realms. Stratigraphic and sedimentologic characteristics of the depositional facies are integrated with ichnological data for the recognition of four facies associations (FA1 to FA4). The transition from open-marine sandstones (FA1) to the brackish-marine deposits (FA2) heralds a transgressive - regressive dislocation. The shallowing- and coarsening-upward progradation from the basal prodelta mudstone-dominated facies (FA2a) to deltafront heterolithics (FA2b) and sandstone facies (FA2c) are overlain by finning-upward delta plain deposits which are expressed by the delta plain mudstone (FA2d) and erosive-based distributary channel fills (FA4). Prodelta/deltfront deposits of FA2 are arranged in thinning- and coarsening-upward parasequences which are stacked in a shallowing-upward progressive cycle. Shallow-marine fossiliferous sandstones (FA3) mark the basal part of each parasequence. Stratigraphic and depositional architectures reflect a tide-dominated delta rather than an estuarine and incised valley (IV) model. This can be evinced by the progressive facies architecture, absence of basal regional incision or a subaerial unconformity and the stratigraphic position above a maximum flooding surface (MFS), in addition to the presence of multiple tidally-influenced distributary channels. Stratigraphic and depositional characteristics of the suggested model resemble those of modern tide-dominated deltaic systems. Accordingly, this model contributes to our understanding of the depositional models for analogous brackish-marine environments, particularly tide-dominated deltas in the rock record.

Helium measurements of pore fluids obtained from the San Andreas Fault Observatory at Depth (SAFOD, USA) drill cores

NASA Astrophysics Data System (ADS)

Ali, S.; Stute, M.; Torgersen, T.; Winckler, G.; Kennedy, B. M.

2011-02-01

4He accumulated in fluids is a well established geochemical tracer used to study crustal fluid dynamics. Direct fluid samples are not always collectable; therefore, a method to extract rare gases from matrix fluids of whole rocks by diffusion has been adapted. Helium was measured on matrix fluids extracted from sandstones and mudstones recovered during the San Andreas Fault Observatory at Depth (SAFOD) drilling in California, USA. Samples were typically collected as subcores or from drillcore fragments. Helium concentration and isotope ratios were measured 4-6 times on each sample, and indicate a bulk 4He diffusion coefficient of 3.5 ± 1.3 × 10-8 cm2 s-1 at 21°C, compared to previously published diffusion coefficients of 1.2 × 10-18 cm2 s-1 (21°C) to 3.0 × 10-15 cm2 s-1 (150°C) in the sands and clays. Correcting the diffusion coefficient of 4Hewater for matrix porosity (˜3%) and tortuosity (˜6-13) produces effective diffusion coefficients of 1 × 10-8 cm2 s-1 (21°C) and 1 × 10-7 (120°C), effectively isolating pore fluid 4He from the 4He contained in the rock matrix. Model calculations indicate that <6% of helium initially dissolved in pore fluids was lost during the sampling process. Complete and quantitative extraction of the pore fluids provide minimum in situ porosity values for sandstones 2.8 ± 0.4% (SD, n = 4) and mudstones 3.1 ± 0.8% (SD, n = 4).

Lithofacies, Age, and Sequence Stratigraphy of the Carboniferous Lisburne Group in the Skimo Creek Area, Central Brooks Range

USGS Publications Warehouse

Dumoulin, Julie A.; Whalen, Michael T.; Harris, Anita G.

2008-01-01

The Lisburne Group, a mainly Carboniferous carbonate succession that is widely distributed across northern Alaska, contains notable amounts of oil and gas at Prudhoe Bay. Detailed studies of the Lisburne in the Skimo Creek area, central Brooks Range, delineate its lithofacies, age, conodont biofacies, depositional environments, and sequence stratigraphy and provide new data on its hydrocarbon source-rock and reservoir potential, as well as its thermal history, in this area. We have studied the Lisburne Group in two thrust sheets of the Endicott Mountains allochthon, herein called the Skimo and Tiglukpuk thrust sheets. The southern, Skimo Creek section, which is >900 m thick, is composed largely of even-bedded to nodular lime mudstone and wackestone intercalated with intervals of thin- to thick-bedded bioclastic packstone and grainstone. Some parts of the section are partially to completely dolomitized and (or) replaced by chert. A distinctive, 30-m-thick zone of black, organic-rich shale, lime mudstone, and phosphorite is exposed 170 m below the top of the Lisburne. The uppermost 40 m of section is also distinctive and made up of dark shale, lime mudstone, spiculite, and glauconitic grainstone. The northern, Tiglukpuk Creek section, which is similar to the Skimo Creek section but only ~760 m thick, includes more packstone and grainstone and less organic-rich shale. Analyses of conodonts and foraminifers indicate that both sections range in age from late Early Mississippian (Osagean) through Early Pennsylvanian (early Morrowan) and document a hiatus of at least 15 m.y. at the contact between the Lisburne and the overlying Siksikpuk Formation. No evidence of subaerial exposure was observed along this contact, which may represent a submarine erosional surface. Lithofacies and biofacies imply that the Lisburne Group in the study area was deposited mainly in midramp to outer-ramp settings. Deepest water strata are mud rich and formed below storm or fair-weather wave base on the outer ramp to outer midramp; shallowest facies are storm, sand-wave, and shoal deposits of the inner midramp to inner ramp. A relatively diverse, open-marine fauna occurs throughout much of the Lisburne in the study area, but some beds also contain clasts typical of more restricted, shallow-water environments that were likely transported seaward by storms and currents. Radiolarians are abundant in the shale and phosphorite unit at Skimo Creek and also occur in equivalent strata at Tiglukpuk Creek; high gamma-ray response and elevated total organic-carbon contents (max 5?8 weight percent) also characterize this unit at Skimo Creek. Lithologic, faunal, and geochemical data all suggest that these rocks formed mainly in an outer-ramp to basinal setting with low sedimentation rates, high productivity, and poorly oxygenated bottom water. Shale and mudstone at the top of the Lisburne Group accumulated in a similarly sediment starved, mainly outer ramp environment but lack comparable evidence for high nutrient and low oxygen levels during deposition. Vertical shifts in rock types and faunas delineate numerous parasequences and six probable third-order sequences in the study area; the same sequences are also recognized in the Lisburne Group to the east. Transgressive-system tracts in these sequences generally fine upward, whereas highstand-system tracts coarsen upward. Sequences in the Tiglukpuk Creek section are mostly thinner, contain thinner and more numerous parasequences, and accumulated in somewhat shallower settings than those in the Skimo Creek section. These differences reflect the more seaward position and, thus, increased accommodation space of the Skimo Creek section relative to the Tiglukpuk Creek section during deposition. Organic-rich calcareous shale in the shale and phosphorite unit has a cumulative thickness of at least 15 m and a lateral extent of >50 km; this lithology is the best potential hydrocarbon source rock in the Lisburne Group

Grainstones and cementstone mounds: The Trogkofel summit section (Lower Permian, Carnic Alps, Austria).

NASA Astrophysics Data System (ADS)

Schaffhauser, M.; Sanders, D.; Krainer, K.

2009-04-01

In the Carnic Alps, Austria, an Artinskian succession 400 m thick of shallow-water bioclastic limestones and of mounds composed of ?Archaeolithophyllum, Archaeolithoporella and abundant fibrous cementstone (after former aragonite) records deposition along a "grainstone-dominated" platform margin. The section was taken along the route through the east-facing cliff of Trogkofel. The Trogkofel Limestone (Artinskian pro parte) is excellently exposed and preserved the most complete along this route, but no section has hitherto been logged. The total thickness of the Trogkofel Limestone probably is about 550 meters; the summit section comprises its upper 400 meters. The section consists mainly of shallow-water bioclastic limestones (grainstones, packstones, rudstones) intercalated with cementstone mounds. Both the bioclastic limestones and the mounds typically are thick-bedded to, more commonly, unbedded. Throughout the section, intervals a few tens of meters in thickness dominated by bioclastic limestones change vertically with intervals dominated by cementstone mounds. Up-section, no clear-cut trend with respect to prevalent facies, mean depositional water depth, and energy index is obvious. Furthermore, no lime-muddy, meter-scale peritidal cycles, and no teepee structures and no pisolite levels were identified; thin intervals of fenestral lime mudstones and/or of cryptmicrobially-laminated limestones are very rare. The bioclastic limestones commonly weather out unstratified, or show subhorizontal stratification or, more rarely, low-angle cross-stratification. In the upper 100 meters of section, grainstones to fine-grained rudstones rich in keystone vugs are prevalent. The cementstone mounds comprise intervals up to a few meters in thickness; the biogenic component is characterized by foliose crusts pertaining to ?Archaeolithophyllum hidensis and Archaeolithoporella, overgrown by Tubiphytes and fenestrate bryozoans. The ?Archaeolithophyllum-Archaeolithoporella crusts are overgrown by abundant, thick fringes and botryoids of fibrous cement that is interpreted as calcitized aragonite cement. In addition, brachiopods, crustose red algae, and a few solitary and colonial rugose corals are typical. By volume, the former aragonite cement comprises the majority of the mounds. Intrinsic pores within the cementstone fabrics typically are filled by micropeloidal grainstone and/or by lime mudstone. The Trogkofel Limestone is locally dolomitized. Replacement dolomites show a wide range of crystal shapes and textures, but overall comprise (a) finely-crystalline, limpid dolostone of xenotopic or hypidiotopic fabrics that broadly mimick the texture of replaced sediment and cements, (b) coarse-crystalline fabrics of hypidiotopic to idiotopic, limpid or optically zoned dolomite, and (c) replacement saddle dolomite. The Trogkofel Limestone is riddled by karstic dykes and caverns that are mainly filled by, both or either of, geopetally-laminated red lime mudstone, terrigenous red sandstones, or thick fringes of fibrous cement. In the karstic cavity fills, packages of convolute geopetal lamination and brecciated internal sediments (internal seismites) overlain by infills with non-convolute lamination, fracture of fibrous cements, and dykes filled by multi-phase fracture breccias record tectonism during or after deposition of the Trogkofel Limestone. The Trogkofel Limestone is capped by a truncation surface which, in turn, is overlain by an interval of extremely poorly sorted, thick-bedded breccias with a former matrix of lime mudstone ("Trogkofel Breccia"). Both the components and the matrix of the Trogkofel Breccia are dolomitized. We interpret the facies and facies architecture of the eastern cliff section of Trogkofel as succession from the seaward side of a "grainstone-dominated" platform margin with cementstone mounds. The lack of clear-cut vertical trends in prevalent facies suggests that the platform margin developed mainly by aggradation. The timing and processes of replacement dolomitization(s) to date are poorly constrained. The presence of saddle dolomite nevertheless indicates passage of dolomitizing fluids of more than 90-100°C.

The volcanic-sedimentary sequence of the Lousal deposit, Iberian Pyrite Belt (Portugal)

NASA Astrophysics Data System (ADS)

Rosa, Carlos; Rosa, Diogo; Matos, Joao; Relvas, Jorge

2010-05-01

The Iberian Pyrite Belt (IPB) is a massive sulfide province that is located in the south of Portugal and Spain, and hosts more than 90 massive sulfide deposits that amount to more than 1850 million metric tonnes of sulfide ore (Tornos, 2006). The ore deposits size, vary from ~1Mt to >100Mt (e.g. Neves Corvo and Aljustrel in Portugal, and Rio Tinto and Tharsis in Spain). The ore deposits are hosted by a submarine sedimentary and volcanic, felsic dominated, succession that constitutes the Upper Devonian to Lower Carboniferous Volcanic and Sedimentary Complex (VSC). The VSC ranges in thickness from approximately 600 to 1300 m (Tornos 2006). The VSC overlies the Phyllite-Quartzite Group (PQ) (Upper Devonian, base unknown) and is overlain by the Baixo Alentejo Flysch Group (Lower to Upper Carboniferous). The Lousal massive sulfide deposit is located in the western part of the IPB and occurs mostly interbedded with black mudstone. The VSC sequence at Lousal mine consists of a mudstone and quartzite sequence (PQ Group) in the lower part of the succession, over which a thick sequence of rhyolitic lavas (>300 m) occurs. Above the rhyolitic lavas there is a thick sequence of black and grey mudstone that hosts the massive sulfide ore bodies, and a rhyolitic sill. The upper part of the VSC sequence consists of a thick mudstone interval that hosts two thick basaltic units, locally with pillows. The rhyolites have small coherent cores, locally with flow bands, that grade to surrounding massive clastic intervals, with large lateral extent. The clasts show jigsaw-fit arrangement in many places and have planar or curviplanar margins and locally are perlitic at the margin. The top contact of these units is in most locations not exposed, which makes difficult to interpret the mode of emplacement. However, the thick clastic intervals, above described, are in accordance with quenching of volcanic glass with abundant water and therefore indicate that quenching of the rhyolites was the dominant fragmentation mechanism. Unlike many locations of the IPB, fiamme-rich pyroclastic units were not identified at Lousal. The ore deposits occur in close proximity with this volcanic centre that may have driven hydrothermal circulation that led to ore formation. The volcanic rocks show intense chloritic alteration, indicating that the mineralizing event occurred after most of the rhyolitic units have emplaced. The massive sulfides show abundant sedimentary structures which is not typical in the massive sulfide deposits of the IPB. The Lousal 50 Mt massive sulfide deposit consists of at least 11 ore bodies and was exploited until 1988 mainly for pyrite. The ores mined averaged 0.7% Cu, 0.8%Pb e 1.4%Zn (Strauss, 1971). These relatively low base metal grades led to an evaluation of the contents and distribution of high-tech element in the ore bodies, which would improve the economic viability of mining the deposit. This evaluation is currently focusing on the distribution and mineralogy of selenium, as ores mined in the past were known to be rich in this element. This work benefits from research projects INCA (PTDC/CTE-GIN/67027/2006; Characterization of crucial mineral resources for the development of renewable energy technologies: The Iberian Pyrite Belt ores as a source of indium and other high-technology elements) and project ARCHYMEDES II (POCTI/CTA/45873/2002), both funded by the Fundação para a Ciência e Tecnologia. REFERENCES Strauss, G.K., 1970. Sobre la geologia de la provincia piritifera del Suroeste de la Peninsula Iberica y sus yacimientos, en especial sobre la mina de pirita de Lousal (Portugal): Memoria del IGME 77, 1-266. Tornos, F., 2006. Environment of formation and styles of volcanogenic massive sulfides: The Iberian Pyrite Belt. Ore Geology Reviews 28, 259-307.

Petrology and sedimentology of the Horlick Formation (Lower Devonian), Ohio Range, Transantarctic Mountains

USGS Publications Warehouse

McCartan, Lucy; Bradshaw, Margaret A.

1987-01-01

The Horlick Formation of Early Devonian age is as thick as 50 m and consists of subhorizontal, interbedded subarkosic sandstone and chloritic shale and mudstone. The Horlick overlies an erosion surface cut into Ordovician granitic rocks and is, in turn, overlain by Carboniferous and Permian glacial and periglacial deposits. Textures, sedimentary structures, and ubiquitous marine body fossils and animal traces suggest that the Horlick was deposited on a shallow shelf having moderate wave energy and a moderate tidal range. The source terrane probably lay to the north, and longshore transport was toward the west.

Making a black shale shine: the interaction of hydrothermal fluids and diagenetic processes

NASA Astrophysics Data System (ADS)

Gleeson, Sarah; Magnall, Joe; Reynolds, Merilie

2016-04-01

Hydrothermal fluids are important agents of mass and thermal transfer in the upper crust. This is exemplified by shale-hosted massive sulphide deposits (SHMS), which are anomalous accumulations of Zn and Pb sulphides (± barite) in sedimentary basins created by hydrothermal fluids. These deposits occur in passive margin settings and, typically, there is no direct evidence of magmatic input. Recent studies of Paleozoic deposits in the North American Cordillera (MacMillan Pass and Red Dog Districts) have shown that the deposits are formed in a sub-seafloor setting, where the potential for thermal and chemical gradients is high. Mineralization is characterized by the replacement and displacement of unconsolidated, partially lithified and lithified biosiliceous mudstones (± carbonates), and commonly the sulphide mineralization post-dates, and replaces, bedded barite units in the sediments. The Red Dog District (Alaska, USA) contain some of the largest Zn-Pb deposits ever discovered. The host-rocks are dominantly carbonaceous mudstones, with carbonate units and some radiolarites. The ore forms massive sulphide bodies that replace pyritized mudstones, barite and carbonate units. Lithological and textural relationships provide evidence that much of the ore formed in bioturbated, biosiliceous zones that may have had high primary porosity and/or permeability. Sediment permeability may have been further modified by aging of the silica rich sediments and the dissolution/replacement of carbonate and barite beds. At the Tom and Jason deposits (MacMillan Pass, Yukon) the fault-controlled hydrothermal upflow zone is uniquely preserved as an unequivocal vent complex. Here, the metal bearing fluids are hot (300°C), low salinity (6 wt% NaCl equiv.) and acidic (pH < 4.5). These fluids were initially in thermal and chemical disequilibrium with a partially lithified organic rich host-rock but cooled rapidly during fluid rock interaction and the input of diagenetic pore fluids. Paragenetically-constrained sulphur isotope analyses provide evidence that at MacMillan Pass and in the Red Dog deposits, reduced sulphur was generated during open system diagenesis and euxinic conditions were not present at the time of mineralization. Furthermore, the formation of diagenetic barite provided an important mechanism of sulphur concentration into the host rock. Both features combined to produce an effective metal trap in the sub-surface. Ultimately, interactions between hydrothermal and diagenetic fluids within a permeable, chemically reactive medium contribute to the formation of SHMS deposits. Where these factors align, it is possible to produce world-class ore deposits (e.g. in the Red Dog district). The complex textures that are commonly encountered in these systems are the result of hydrothermal fluids interacting with their host-rocks in a heterogeneous and dynamic physical and chemical environment.

Fractures system within Qusaiba shale outcrop and its relationship to the lithological properties, Qasim area, Central Saudi Arabia

NASA Astrophysics Data System (ADS)

Ibrahim, Mohamed I. M.; Hariri, Mustafa M.; Abdullatif, Osman M.; Makkawi, Mohammad H.; Elzain, Hussam

2017-09-01

The basal Qusaiba hot shale member of Qalibah Formation is considered to be an important source rock in the Paleozoic petroleum system of Saudi Arabia and an exploration target for tight shale as one of the Unconventional resources of petroleum. This work has been carried out to understand the fractures network of Qusaiba shale member in outcrops located to the west of Qusayba' village in Al-Qasim area, Central Saudi Arabia. The main objective of this study is to understand the distribution of natural fractures over different lithological units. Description data sheets were used for the detailed lithological description of Qusaiba shale member on two outcrops. Spot-7 and Landsat ETM+ satellite images were used for lineament mapping and analyses on a regional scale in a GIS environment. Fractures characterization in outcrop-scale was conducted by using linear scanline method. Qusaiba shale member in the study area consists of 5 main lithofacies, divided based on their sedimentary structures and petrographical properties, from base to top in the outcrops, the lithofacies are; fissile shale, very fine-grained micaceous siltstone, bioturbated mudstone, very fine to fine-grained hummocky cross-stratified sandstone, and fine to medium-grained low/high angle cross-stratified sandstone lithofacies. Lineaments interpretation of the Spot-7 and Landsat ETM+ satellite images showed two major directions in the study area; 320° that could be related to Najd fault system and 20° that could be related to the extensional activities which took place after Amar collision. Fractures are much denser in the fissile shale and mudstone lithofacies than sandstones lithofacies, and average spacing is smaller in the fissile shale and mudstone lithofacies than sandstones lithofacies. Lineaments and large-scale fractures are Non-Stratabound fractures and they deal with the area as one big mechanical unit, but small-scale fractures are Stratabound fractures that propose different mechanical units within Qusaiba shale member in the study area. The fractures network in the study area has a wide range of properties related to fractures density, length, spacing, height, and termination degree. The conceptual multi-scale model divides the fractures in the study area into 4 orders depending on the available data that have been observed from satellite images and field. The multi-scale fractures model that was generated in this study could help to understand the distribution of stratigraphically controlled fractures when integrated with flow simulation models. Overall, this work could have a significant contribution to tight shale exploration plans in the subsurface by providing some knowledge about the fractures mechanical behavior of the lower part of Qusaiba shale member of Qalibah Formation.

Brookian structural plays in the National Petroleum Reserve, Alaska

USGS Publications Warehouse

Potter, Christopher J.; Moore, Thomas E.

2003-01-01

As part of the U.S. Geological Survey assessment of undiscovered oil and gas resources in the National Petroleum Reserve-Alaska (NPRA), two structural plays were assessed in thrust-faulted and folded Upper Cretaceous rocks of the Brookian megasequence. These are the Brookian Topset Structural Play and the Torok Structural Play, located in the Brooks Range foothills and the southern part of the coastal plain, within the Tertiary-age frontal part of the Jurassic to Tertiary Brooks Range orogenic belt. A new regional structural interpretation, developed through regional seismic analyses, reconnaissance field investigations, and new thermal constraints, guided the geologic evaluation and risking of these plays. Volumetric parameters were derived from seismic reflection data, well data and oil and gas field analogs. The fundamental elements of the Brookian Topset Structural Play, exemplified by the undeveloped Umiat oil field, include: (1) reservoirs in Nanushuk Group and uppermost Torok Formation shallow-marine to nonmarine sandstones draped over anticlines caused by structural thickening in underlying Torok mudstones; (2) seals provided by overlying shale drapes in the Nanushuk, and locally by thrust faults; (3) Torok, gamma-ray-zone (GRZ) or pebble shale source rocks; (4) remigration of hydrocarbons from early formed (Late Cretaceous) stratigraphic traps disrupted by 60 Ma thrusting, into newly formed structural traps. The 60 Ma thrusting was probably accompanied by new generation and migration of natural gas resulting from late structural thickening and tectonic loading. Subsurface data from the Umiat field and other seismic reflection data within the play area indicate that the structural traps are commonly compartmentalized by thrust faults. The fundamental elements of the Torok Structural Play, exemplified by the undeveloped East Kurupa gas accumulation just south of NPRA, include: (1) reservoirs in lower Torok Formation basin-floor sandstones, and perhaps in small sandstone bodies intercalated with middle to upper Torok mudstones; (2) structural traps provided by folded sandstone bodies above thrust faults within a pervasively deformed passive-roof duplex beneath the foothills and a less-strongly deformed domain to the north; (3) seals provided by Torok mudstone, both stratigraphically above the sandstone bodies and smeared along bounding thrust faults; (4) Torok, GRZ, pebble shale, or Kingak Shale source rocks; (5) a migration and charging scenario similar to that of the Brookian Topset Structural Play. According to our estimates, the Brookian Topset Structural Play contains 137 million barrels of technically recoverable oil and 10.6 trillion cubic feet (TCF) of technically recoverable, non-associated natural gas, with both values representing the mean estimate (expected value). The Torok Structural Play contains about 35 million barrels of technically recoverable oil and 17.9 TCF of technically recoverable, nonassociated natural gas.

Recent sedimentological studies of the Murray and Stimson formations and their implications for Gale crater evolution, Mars

NASA Astrophysics Data System (ADS)

Gupta, Sanjeev; Fedo, Chris; Grotzinger, John; Edgett, Ken; Vasavada, Ashwin

2017-04-01

The Mars Science Laboratory (MSL) Curiosity rover has been exploring sedimentary rocks on the lower north slope of Aeolis Mons since August 2014. Previous work has demonstrated a succession of sedimentary rock types deposited dominantly in river-delta settings (Bradbury group), and interfingering/overlying contemporaneous/younger lake settings (Murray formation, Mt. Sharp group). The Murray formation is unconformably overlain by the Stimson formation, an ancient aeolian sand lithology. Here, we describe the MSL team's most recent sedimentological findings regarding the Murray and Stimson formations. The Murray formation is of the order of 200 meters thick and formed dominantly of mudstones. The mudstone facies, originally identified at the Pahrump Hills field site, show abundant fine-scale planar laminations throughout the Murray formation succession and is interpreted to record deposition in an ancient lake system in Gale crater. Since leaving the Naukluft Plateau (Stimson formation rocks) and driving south-southeastwards and progressive stratigraphically upwards through the Murray succession, we have recognised a variety of additional facies have been recognized that indicate variability in the overall palaeoenvironmental setting. These facies include (1) cross-bedded siltstones to very fine-grained sandstones with metre-scale troughs that might represent aeolian sedimentation; (2) a heterolithic mudstone-sandstone facies with laminated fine-grained strata, cm-scale ripple cross-laminations in siltstone or very fine sandstone, and dm-scale cross-stratified siltstone and very fine grained sandstone. The palaeoenvironmental setting for the second facies remains under discussion. Our results show that Gale crater hosted lakes systems for millions to tens of millions of years, perhaps punctuated by drier intervals. Murray strata are unconformably overlain by the Stimson formation. Stimson outcrops are typically characterized by cross-bedded sandstones with cross-sets ranging between 40-80 cm thick (Fig. 2). Within the sets, cross-strata comprise repetitive laminations that are a few millimeters thick and typically sub-parallel. Cross-laminations downlap onto the underlying bounding surface with an asymptotic profile and are truncated at their top by an overlying bounding surface. Palaeocurrent analysis based on measurements of 117 foreset azimuths indicate a wind regime that drove dune migration towards the northeast. Cross sets are separated by erosional bounding surfaces, which are interpreted to represent interdune surfaces, which were formed by migrating dunes as they climbed over the stoss slope of a preceding dune, eroding its stoss and upper part of the lee slope. From analysis of the sedimentary architecture, and comparison with terrestrial aeolian strata, we interpret the Stimson formation to represent sands deposited in a dry-aeolian dune system. In summary, sedimentary observations by the Curiosity rover record a diverse range of palaeoenvironments and a rich geological history in strata preserved in lower Aeolis Mons.

Lithofacies, age, depositional setting, and geochemistry of the Otuk Formation in the Red Dog District, northwestern Alaska

USGS Publications Warehouse

Dumoulin, Julie A.; Burruss, Robert A.; Blome, Charles D.

2013-01-01

Complete penetration of the Otuk Formation in a continuous drill core (diamond-drill hole, DDH 927) from the Red Dog District illuminates the facies, age, depositional environment, source rock potential, and isotope stratigraphy of this unit in northwestern Alaska. The section, in the Wolverine Creek plate of the Endicott Mountains Allochthon (EMA), is ~82 meters (m) thick and appears structurally uncomplicated. Bedding dips are generally low and thicknesses recorded are close to true thicknesses. Preliminary synthesis of sedimentologic, paleontologic, and isotopic data suggests that the Otuk succession in DDH 927 is a largely complete, albeit condensed, marine Triassic section in conformable contact with marine Permian and Jurassic strata. The Otuk Formation in DDH 927 gradationally overlies gray siliceous mudstone of the Siksikpuk Formation (Permian, based on regional correlations) and underlies black organic-rich mudstone of the Kingak(?) Shale (Jurassic?, based on regional correlations). The informal shale, chert, and limestone members of the Otuk are recognized in DDH 927, but the Jurassic Blankenship Member is absent. The lower (shale) member consists of 28 m of black to light gray, silty shale with as much as 6.9 weight percent total organic carbon (TOC). Thin limy layers near the base of this member contain bivalve fragments (Claraia sp.?) consistent with an Early Triassic (Griesbachian-early Smithian) age. Gray radiolarian chert dominates the middle member (25 m thick) and yields radiolarians of Middle Triassic (Anisian and Ladinian) and Late Triassic (Carnian-late middle Norian) ages. Black to light gray silty shale, like that in the lower member, forms interbeds that range from a few millimeters to 7 centimeters in thickness through much of the middle member. A distinctive, 2.4-m-thick interval of black shale and calcareous radiolarite ~17 m above the base of the member has as much as 9.8 weight percent TOC, and a 1.9-m-thick interval of limy to cherty mudstone immediately above this contains radiolarians, foraminifers, conodonts, and halobiid bivalve fragments. The upper (limestone) member (29 m thick) is lime mudstone with monotid bivalves and late Norian radiolarians, overlain by gray chert that contains Rhaetian (latest Triassic) radiolarians; Rhaetian strata have not previously been documented in the Otuk. Rare gray to black shale interbeds in the upper member have as much as 3.4 weight percent TOC. At least 35 m of black mudstone overlies the limestone member; these strata lack interbeds of oil shale and chert that are characteristic of the Blankenship, and instead they resemble the Kingak Shale. Vitrinite reflectance values (2.45 and 2.47 percent Ro) from two samples of black shale in the chert member indicate that these rocks reached a high level of thermal maturity within the dry gas window. Regional correlations indicate that lithofacies in the Otuk Formation vary with both structural and geographic position. For example, the shale member of the Otuk in the Wolverine Creek plate includes more limy layers and less barite (as blades, nodules, and lenses) than equivalent strata in the structurally higher Red Dog plate of the EMA, but it has fewer limy layers than the shale member in the EMA ~450 kilometers (km) to the east at Tiglukpuk Creek. The limestone member of the Otuk is thicker in the Wolverine Creek plate than in the Red Dog plate and differs from this member in EMA sections to the east in containing an upper cherty interval that lacks monotids; a similar interval is seen at the top of the Otuk Formation ~125 km to the west (Lisburne Peninsula). Our observations are consistent with the interpretations of previous researchers that Otuk facies become more distal in higher structural positions and that within a given structural level more distal facies occur to the west. Recent paleogeographic reconstructions indicate that the Otuk accumulated at a relatively high paleolatitude with a bivalve fauna typical of the Boreal realm. A suite of δ13Corg (carbon isotopic composition of carbon) data (n=38) from the upper Siksikpuk Formation through the Otuk Formation and into the Kingak(?) Shale in DDH 927 shows a pattern of positive and negative excursions similar to those reported elsewhere in Triassic strata. In particular, a distinct negative excursion at the base of the Otuk (from ‒23.8 to ‒31.3‰ (permil, or parts per thousand)) likely correlates with a pronounced excursion that marks the Permian-Triassic boundary at many localities worldwide. Another feature of the Otuk δ13Corg record that may correlate globally is a series of negative and positive excursions in the lower member. At the top of the Otuk in DDH 927, the δ13Corg values are extremely low and may correlate with a negative excursion that is widely observed at the Triassic-Jurassic boundary.

Petrology and dolomitization of the C' zone, Red River Formation (Ordovician), in a deep core, Williston basin, Richland County, eastern Montana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zenger, D.H.

Unocal's Superior [number sign]1 Vanderhoof 97-foot (29.6 m) core consists of 63 feet (19.2 m) of the upper part of the C' burrowed member (BM) overlain by 34 feet (10.4 m) of the C' laminated member (LM) of the productive Red River Formation. The LM is mainly laminated, anhydritic, stylolitic, essentially unfossiliferous dolomudstone to calcareous dolomudstone with more minor dolomitic lime mudstone. The unit represents a restricted, hypersaline, inner shelf environment. The BM is burrow-mottled (Thalassinoides ), skeletal, dolomitic wackestone to grainstone matrix to calcareous dolowackestone (burrow fills) and represents near-normal salinity, inner shelf conditions. Dolomite is primarily replacive andmore » in the LM occurs as 25--50 [mu]m rhombs floating in mudstone or associated with stylolites, and as nonplanar, polymodal (5--50 [mu]m) crystals in totally dolomitized intervals. Most BM dolomite consists of 20--160 [mu]m, primarily nonplanar crystals in the largely replaced burrow fills; it also occurs as crystals that are disseminated or focused along stylolites (as in LM), as large crystals selectively and pseudomorphically replacing echinoderm fragments, and more rarely as late-stage, void-filling saddle dolomite. Previous theories of dolomitization have invoked descending brines. Geochemical data, in particular depleted [delta][sup 18]O and relatively low amounts of trace elements Sr and Na, but high Fe and Mn content, reveal that if brines were responsible for early diagenetic replacement, the dolomite has not retained such geochemical memory; rather it has undergone modification, acquiring later diagenetic, burial signatures. Possibly more of the replacement itself was later and deeper than previously thought.« less

Interaction Behavior between Thrust Faulting and the National Highway No. 3 - Tianliao III bridge as Determined using Numerical Simulation

NASA Astrophysics Data System (ADS)

Li, C. H.; Wu, L. C.; Chan, P. C.; Lin, M. L.

2016-12-01

The National Highway No. 3 - Tianliao III Bridge is located in the southwestern Taiwan mudstone area and crosses the Chekualin fault. Since the bridge was opened to traffic, it has been repaired 11 times. To understand the interaction behavior between thrust faulting and the bridge, a discrete element method-based software program, PFC, was applied to conduct a numerical analysis. A 3D model for simulating the thrust faulting and bridge was established, as shown in Fig. 1. In this conceptual model, the length and width were 50 and 10 m, respectively. Part of the box bottom was moveable, simulating the displacement of the thrust fault. The overburden stratum had a height of 5 m with fault dip angles of 20° (Fig. 2). The bottom-up strata were mudstone, clay, and sand, separately. The uplift was 1 m, which was 20% of the stratum thickness. In accordance with the investigation, the position of the fault tip was set, depending on the fault zone, and the bridge deformation was observed (Fig. 3). By setting "Monitoring Balls" in the numerical model to analyzes bridge displacement, we determined that the bridge deck deflection increased as the uplift distance increased. Furthermore, the force caused by the loading of the bridge deck and fault dislocation was determined to cause a down deflection of the P1 and P2 bridge piers. Finally, the fault deflection trajectory of the P4 pier displayed the maximum displacement (Fig. 4). Similar behavior has been observed through numerical simulation as well as field monitoring data. Usage of the discrete element model (PFC3D) to simulate the deformation behavior between thrust faulting and the bridge provided feedback for the design and improved planning of the bridge.

Effects of smectite to illite transformation on the frictional strength and sliding stability of intact marine mudstones

USGS Publications Warehouse

Saffer, Demian M.; Lockner, David A.; McKiernan, Alex

2012-01-01

At subduction zones, earthquake nucleation and coseismic slip occur only within a limited depth range, known as the “seismogenic zone”. One leading hypothesis for the upper aseismic-seismic transition is that transformation of smectite to illite at ∼100–150°C triggers a change from rate-strengthening frictional behavior that allows only stable sliding, to rate weakening behavior considered a prerequisite for unstable slip. Previous studies on powdered gouges have shown that changes in clay mineralogy alone are unlikely to control this transition, but associated fabric and cementation developed during diagenesis remain possible candidates. We conducted shearing experiments designed specifically to evaluate this hypothesis, by using intact wafers of mudstone from Ocean Drilling Program Site 1174, offshore SW Japan, which have undergone progressive smectite transformation in situ. We sheared specimens along a sawcut in a triaxial configuration, oriented parallel to bedding, at normal stresses of ∼20–150 MPa and a pore pressure of 1 MPa. During shearing, we conducted velocity-stepping tests to measure the friction rate parameter (a-b). Friction coefficient ranges from 0.28–0.40 and values of (a-b) are uniformly positive; both are independent of clay transformation progress. Our work represents the most direct and comprehensive test of the clay transformation hypothesis to date, and suggests that neither illitization, nor accompanying fabric development and cementation, trigger a transition to unstable frictional behavior. We suggest that strain localization, in combination with precipitation of calcite and quartz, is a viable alternative that is consistent with both field observations and recent conceptual models of a heterogeneous seismogenic zone.

Transgressive reef sequences of the Devonian Devils Gate Limestone, Red Hill, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shapiro, R.; Dehler, C.; Flynn, J.

The Devils Gate Limestone at Red Hill, Simpson Park Range, Eureka Co., Nevada is composed of several conformable transgressive sequences cropping out in a series of step-like cliffs 1--5 m high. The general sequence is as follows: (1) a 1--4 m thick in situ boundstone dominated by large, period rugosans, domical and stratiform stromatoporids and rare, 1--3 cm diameter oncolites. Most of the boundstone is composed of small, cylindrical fossils. Petrographic observation revealed them to be mostly Amphipora and Cladopora. The upper portions of these units are packstones composed of Amphipora/Cladopora and, to a lesser degree, small favositids, round stromatoporoidsmore » (3--4 cm diameter), and rip-up clasts. (2) These beds grade upward into a thinly laminated and/or cross-bedded unfossiliferous mudstone. (3) Stratigraphically above the mudstone or in contact with the packstone, is a cross-bedded and/or bioturbated wackestone containing fossils no greater than 2 mm. In thin section, the mottled reddish-grey wackestone is pelletal, with rare lenses of small crinoid columnals. Disarticulated brachiopod shells of low diversity are found near the tops of some of these layers. Community dominance in the reefal units alternates between Amphipora/Cladopora, colonial rugose, and stromatoporoids. Oncolite mounds are common in the uppermost unit. The typical reef succession consists of domical and digitate stromatoporoids growing on the upper surfaces of in place or disturbed, large rugosans, though the reverse has been noted. Tabulate corals encrusted by stromatoporoids are often found in the packstone. It is important to note that often these successions' can be attributed to juxtaposition along styolites.« less

Stratigraphy and structure of the Miners Mountain area, Wayne County, Utah

USGS Publications Warehouse

Luedke, Robert G.

1953-01-01

The Miners Mountain area includes about 85 square miles in Wayne County, south-central Utah. The area is semiarid and characterized by cliffs and deep canyons. Formations range in age from Permian to Upper Jurassic and have an aggregate thickness of about 3,500 feet. Permian formations are the buff Coconino sandstone and the overlying white, limy, shert-containing Kaibab limestone. Unconformably overlying the Kaihab is the lower Triassic Moenkopi formation of reddish-brown and yellow mudstone, siltstone, and sandstone; it contains the Sinbad limestone member (?) in the lower part. Thin, lenticular Shinarump conglomerate unconformably overlies the Moenkopi, but grades upward into the Upper Triassic Chinle formation of variegated mudstone with some interbedded sandstone and limestone lenses. Uncomformably overlying the Chinle are the Wingate sandstone, Kayenta formation, and Navajo sandstone of the Jurassic (?) Glen Canyon group, which consist of red to white sandstone. Only the lower part of the Carmel formation of the Upper Jurassic San Rafael group is exposed in the area; it consists of variegated siltstone, sandstone, limestone, and gypsum. The conspicuous structural feature in the area is the Teasdale anticline which trends northwest, is about 14 miles long, and is asymmetric with a steeper west flank. Bounding the anticline on the northeast and east is the Capitol Reef monocline, the northern part of the Waterpocket Fold. Strata in the area are broken by steeply-dipping normal faults with small displacements, except for the Teasdale fault which has a maximum displacement of over 1,000 feet. Jointing is prominent in some formations. The major orogenic movement in the area is believed to be late Upper Cretaceous to early Tertiary. Epeirogenic uplift occurred intermittently throughout Tertiary and perhaps Quaternary time.

Paleovalley fills: Trunk vs. tributary

USGS Publications Warehouse

Kvale, E.P.; Archer, A.W.

2007-01-01

A late Mississippian-early Pennsylvanian eustatic sea level drop resulted in a complex lowstand drainage network being eroded across the Illinois Basin in the eastern United States. This drainage system was filled during the early part of the Pennsylvanian. Distinct differences can be recognized between the trunk and tributary paleovalley fills. Fills preserved within the trunk systems tend to be fluvially dominated and consist of bed-load deposits of coarse- to medium-grained sandstone and conglomerate. Conversely, the incised valleys of tributary systems tend to be filled with dark mudstone, thinly interbedded sandstones, and mudstones and siltstones. These finer grained facies exhibit marine influences manifested by tidal rhythmites, certain traces fossils, and macro- and microfauna. Examples of tributary and trunk systems, separated by no more than 7 km (4.3 mi) along strike, exhibit these styles of highly contrasting fills. Useful analogs for understanding this Pennsylvanian system include the Quaternary glacial sluiceways present in the lower Ohio, White, and Wabash river valleys of Indiana (United States) and the modern Amazon River (Brazil). Both the Amazon River and the Quaternary rivers of Indiana have (or had) trunk rivers that are (were) dominated by large quantities of bed load relative to their tributaries. The trunk valley systems of these analogs aggraded much more rapidly than their tributary valleys, which evolved into lakes because depositional rates along the trunk are (were) so high that the mouths of the tributaries have been dammed by bed-load deposits. These Holocene systems illustrate that sediment yields can significantly influence the nature of fill successions within incised valleys independent of rates of sea level changes or proximity to highstand coastlines. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

Petroleum source potential of the Lower Cretaceous mudstone succession of the NPRA and Colville Delta area, North Slope Alaska, based on sonic and resistivity logs

USGS Publications Warehouse

Keller, Margaret A.; Bird, Kenneth J.

2003-01-01

Resource assessment of the North Slope of Alaska by the U. S. Geological Survey includes evaluation of the petroleum source potential of Mesozoic and Cenozoic rocks using the delta log R technique (Passey and others, 1990). Porosity and resistivity logs are used in combination with thermal maturity data to produce a continuous profile of total organic carbon content in weight % (TOC). From the pattern and amount of TOC in the profile produced, the depositional setting and thus the petroleum source-rock potential (kerogen type) of the organic matter can be inferred and compared to interpretations from other data such as Rock-Eval pyrolysis. TOC profiles determined by this technique for the contiguous interval of pebble shale unit, Hue Shale (including the Gamma Ray Zone or GRZ), and lower part of the Torok Formation indicate important potential for petroleum generation in the Tunalik 1, Inigok 1, N. Inigok 1, Kuyanak 1, Texaco Colville Delta 1, Nechelik 1, and Bergschrund 1 wells of the western North Slope region. TOC profiles suggest that this interval contains both type II and III kerogens – consistent with proposed depositional models -- and is predominantly greater than 2 wt. % TOC (cut-off used for effective source potential). Average TOC for the total effective section of the pebble shale unit + Hue Shale ranges from 2.6 to 4.1 wt % TOC (values predominantly 2-8% TOC) over 192-352 ft. Source potential for the lower Torok Formation, which also has interbedded sandstone and lean mudstone, is good to negligible in these 7 wells.

Stratigraphic and structural data for the Conasauga Group and the Rome Formation on the Copper Creek fault block near Oak Ridge, Tennessee: preliminary results from test borehole ORNL-JOY No. 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haase, C.S.; Walls, E.C.; Farmer, C.D.

1985-06-01

To resolve long-standing problems with the stratigraphy of the Conasauga Group and the Rome Formation on the Copper Creek fault block near Oak Ridge National Laboratory (ORNL), an 828.5-m-deep test borehole was drilled. Continuous rock core was recovered from the 17.7- to 828.5-m-deep interval; temperature, caliper, neutron, gamma-ray, and acoustic (velocity and televiewer) logs were obtained. The Conasauga Group at the study site is 572.4 m thick and comprises six formations that are - in descending stratigraphic order - Maynardville Limestone (98.8 m), Nolichucky Shale (167.9 m), Maryville Limestone (141.1 m), Rogersville Shale (39.6 m), Rutledge Limestone (30.8 m), andmore » Pumpkin Valley Shale (94.2 m). The formations are lithologically complex, ranging from clastics that consist of shales, mudstones, and siltstones to carbonates that consist of micrites, wackestones, packstones, and conglomerates. The Rome Formation is 188.1 m thick and consists of variably bedded mudstones, siltstones, and sandstones. The Rome Formation thickness represents 88.1 m of relatively undeformed section and 100.0 m of highly deformed, jumbled, and partially repeated section. The bottom of the Rome Formation is marked by a tectonic disconformity that occurs within a 46-m-thick, intensely deformed interval caused by motion along the Copper Creek fault. Results from this study establish the stratigraphy and the lithology of the Conasauga Group and the Rome Formation near ORNL and, for the first time, allow for the unambiguous correlation of cores and geophysical logs from boreholes elsewhere in the ORNL vicinity. 45 refs., 26 figs., 2 tabs.« less

Characterizing the Phyllosilicate Component of the Sheepbed Mudstone in Gale Crater, Mars Using Laboratory XRD and EGA

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Morris, R. V.; Ming, D. W.; Archer, P. D.; Bish, D. L.; Chipera, S. J.; Vaniman, D. T.; Blake, D. F.; Bristow, T. F.; Sutter, B.;

The Hydrological Evolution of Mars as Recorded at Gale Crater

NASA Astrophysics Data System (ADS)

Andrews-Hanna, J. C.; Horvath, D. G.

2017-12-01

The sedimentary deposits making up the Aeolis Mons sedimentary mound within Gale Crater preserve a record of the evolving hydrology and climate of Mars during the Late Noachian and Hesperian epochs. Aqueous sedimentary deposits including mudstones, deltaic deposits, and sulfate-cemented sediments indicate the past presence of liquid water on the surface. However, these observations alone do not strictly constrain the nature of the hydrology and climate at the time of deposition. We use models of the subsurface and surface hydrology to shed light on the conditions required to reproduce the observed deposits. Changes in the nature and composition of the deposits reflect changes in the balance between the surface and subsurface components of the hydrological cycle, driven by climate changes. Mudstones observed by the MSL rover at the base of the crater reflect lacustrine deposition under semi-arid conditions, with substantial fluid supply from both the surface (overland flow and direct precipitation) and subsurface. A transition at higher stratigraphic levels to sulfate-cemented sandstones required a change to a more arid climate, with the hydrology dominated by long-distance subsurface transport. Near the top of the mound, unaltered deposits indicate deposition under dry conditions, though this transition coincides with the natural limit on the rise of the water table imposed by the surrounding topography and does not require a change in climate. Erosion of the crater-filling sedimentary deposits to their present mound shape required a dramatic drop in the water table under hyper-arid conditions. Evidence for later lake stands in the Hesperian indicates transient returns to semi-arid conditions similar to those that prevailed during the Late Noachian. By coupling surface and orbital observations with hydrological modeling, we are able to make more specific constraints on the evolving climate and aridity of early Mars.

3D-Mapping of Dolomitized Structures in Lower Cambrian Phosphorites

NASA Astrophysics Data System (ADS)

Hippler, Dorothee; Stammeier, Jessica A.; Brunner, Roland; Rosc, Jördis; Franz, Gerhard; Dietzel, Martin

2016-04-01

Dolomitization is a widespread phenomenon in ancient sedimentary rocks, particularly close to the Precambrian-Cambrian boundary. Dolomite can form in synsedimentary or hydrothermal environments, preferentially via the replacement of solid carbonate precursor phases. Synsedimentary dolomite formation is often associated with microbial activity, such as bacterial sulfate reduction or methanogenesis. In this study, we investigate dolomitic phosphorites from the Lowermost Cambrian Tal Group, Mussoori Syncline, Lesser Himalaya, India, using micro-CT 3D-mapping, in order to unravel the complex diagenetic history of the rocks. The selected sample shows alternating layering of phosphatic mudstones and sparitic dolostone, in which brecciated layers of phosphorite or phosphatic mudstones are immersed in a dolomite-rich matrix. Lamination occurs on a sub-millimetre scale, with lamination sometimes wavy to crinkly. This fabric is interpreted as former microbial mats, providing the environment for early diagenetic phosphatization. Preliminary electron backscatter imaging with scanning microscopy revealed that dolomite crystals often occur in spherical to ellipsoidal structures, typically with a high porosity. This dolomite is associated with botryoidal apatite, organic matter and small amounts of calcite. Micro-CT 3D-mappings reveal that dolomite structures are cigar-shaped, elongated and up to 600 μm long. They are further arranged in a Mikado-like oriented framework spanning a layer thickness of a few millimetres. Analyses of ambient pore space, with similar elongated outlines and filled with organic matter, suggest a potential coherence of ambient pore space and shape of the dolomite structures. Allowing for other associated mineral phases, such as pyrite and silicates, and their spatial distribution, the present approach can be used to unravel distinct diagenetic reaction pathways, and might thus constrain the proxy potential of these Lower Cambrian dolomitic phosphorites to reconstruct ambient environmental at the time of deposition.

Geology and lithogeochemistry of the Ren gold prospect, Elko County, Nevada - the role of rock sampling in exploration for deep Carlin-type deposits

USGS Publications Warehouse

Albino, G.V.

1994-01-01

The Ren gold prospect, Elko County, Nevada, is in the northern part of the Carlin trend, two kilometers northwest of the recently-discovered, high-grade Purple Vein deposit. The Ren area is underlain mainly by Paleozoic sedimentary rocks, consisting of limestone, calcareous siltstone, and mudstone of the eastern (carbonate) assemblage, overlain in thrust contact by chert, quartzite, and mudstone of the western (siliceous) assemblage. Cretaceous(?) granodiorite porphyry and hornblende porphyry dikes have intruded the sedimentary rocks along north-striking faults. Three stages of mineralization include a pre- or syntectonic base metal-barite assemblage, a middle stage of Ag- and Sb-rich jasperoid, and a late Au-rich stage responsible for the potentially economic mineralization at the prospect. The latter two stages of alteration and mineralization were focused along steep east-dipping faults and dikes, and the nearly flat-lying contact between lower massive limestone and laminated calcareous siltstone. Mineralization is present between 380 and 500 m below the surface. Alteration includes decalcification and weak silicification in siltstone, and formation of massive jasperoid in the upper part of the limestone unit. Alteration of dikes is mainly sericite-quartz-pyrite, with late pyrite-quartz-kaolinite. The element suite characteristic of Au-stage mineralization includes Au, As, and Hg with minor Ag and Hg; Ag and Sb are most enriched in the earlier jasperoid event. Haloes of As and Hg extend at least 80 m above the Au mineralization, but no anomalies are present at the surface. Gold anomalies are more widespread, and extend to shallower depths, but are less coherent. ?? 1994.

Detection of Frictional Heating on Faults Using Raman Spectra of Carbonaceous Material

NASA Astrophysics Data System (ADS)

Ito, K.; Ujiie, K.; Kagi, H.

2017-12-01

Raman spectra of carbonaceous material (RSCM) have been used as geothermometer in sedimentary and metamorphic rocks. However, it remains poorly understood whether RSCM are useful for detecting past frictional heating on faults. To detect increased heating during seismic slip, we examine the thrust fault in the Jurassic accretionary complex, central Japan. The thrust fault zone includes 10 cm-thick cataclasite and a few mm-thick dark layer. The cataclasite is characterized by fragments of black and gray chert in the black carbonaceous mudstone matrix. The dark layer is marked by intensely cracked gray chert fragments in the dark matrix of carbonaceous mudstone composition, which bounds the fractured gray chert above from the cataclasite below. The RSCM are analyzed for carbonaceous material in the cataclasite, dark layer, and host rock <10 mm from cataclasite and dark layer boundaries. The result indicates that there is no increased carbonization in the cataclasite. In contrast, the dark layer and part of host rocks <2 mm from the dark layer boundaries show prominent increase in carbonization. The absent of increased carbonization in the cataclasite could be attributed to insufficient frictional heating associated with distributed shear and/or faulting at low slip rates. The dark layer exhibits the appearance of fault and injection veins, and the dark layer boundaries are irregularly embayed or intensely cracked; these features have been characteristically observed in pseudotachylytes. Therefore, the increased carbonization in the dark layer is likely resulted from increased heating during earthquake faulting. The intensely cracked fragments in the dark layer and cracked wall rocks may reflect thermal fracturing in chert, which is caused by heat conduction from the molten zone. We suggest that RSCM are useful for the detection of increased heating on faults, particularly when the temperature is high enough for frictional melting and thermal fracturing.

Late Diagenetic Cements in the Murray Formation, Gale Crater, Mars: Implications for Postdepositional Fluid Flow

NASA Astrophysics Data System (ADS)

Kah, L. C.; Kronyak, R. E.; Van Beek, J.; Nachon, M.; Mangold, N.; Thompson, L. M.; Wiens, R. C.; Grotzinger, J. P.; Schieber, J.

2015-12-01

The Murray formation in its type section at Pahrump Hills, consists of approximately 14 meters of recessive-weathering mudstone interbedded with decimeter-scale cross-bedded sandstone in the upper portions of the exposed section. Mudstone textures vary from massive, to poorly laminated, to well laminated. Unusual 3-dimensional crystal clusters and dendrites occur in the lowermost part of the section and are erosionally resistant with respect to the host rock. Crystal clusters consist of elongate lathes that occur within individual blocks of the fractured substrate. Individual lathes show tabular morphologies with a pseudo-rectangular cross-section and the three dimensional morphology of the crystal clusters cross-cut host rock lamination with little or no deformation. Dendritic structures are typically larger and show predominantly planar growth aligned with bedding planes. Individual lathes within the dendrites are elongate and pseudo-rectangular in cross-section. Unlike crystal clusters, dendritic morphologies appear to nucleate at bedrock fractures and near mineralized veins. Here we show evidence that crystal clusters and dendrites are post-depositional, potentially burial diagenetic features. Association of features with through-going fractures suggests that fractures may have been a primary transport pathway for ions responsible for dendrite growth. Even where dendrites do not occur, enhanced cementation suggests that fluids permeated the rock matrix. We suggest that growth of clusters proceeded as inter-particle crystal growth, wherein mineral growth within inter-particle spaces resulted in cementation and porosity loss, with little further effect on the rock matrix. Crystal clusters and dendrites are most likely to form when mineral saturation states are highest, for instance with initial intrusion of fracture-borne fluids and mixing with ambient pore fluids, and thus emphasize the importance of fractures in ion transport during late diagenesis.

Depositional settings, correlation, and age carboniferous rocks in the western Brooks Range, Alaska

USGS Publications Warehouse

Dumoulin, Julie A.; Harris, Anita G.; Blome, Charles D.; Young, Lorne E.

2004-01-01

The Kuna Formation (Lisburne Group) in northwest Alaska hosts the Red Dog and other Zn-Pb-Ag massive sulfide deposits in the Red Dog district. New studies of the sedimentology and paleontology of the Lisburne Group constrain the setting, age, and thermal history of these deposits. In the western and west-central Brooks Range, the Lisburne Group includes both deep- and shallow-water sedimentary facies and local volcanic rocks that are exposed in a series of thrust sheets or allochthons. Deep-water facies in the Red Dog area (i.e., the Kuna Formation and related rocks) are found chiefly in the Endicott Mountains and structurally higher Picnic Creek allochthons. In the Red Dog plate of the Endicott Mountains allochthon, the Kuna consists of at least 122 m of thinly interbedded calcareous shale, calcareous spiculite, and bioclastic supportstone (Kivalina unit) overlain by 30 to 240 m of siliceous shale, mudstone, calcareous radiolarite, and calcareous lithic turbidite (Ikalukrok unit). The Ikalukrok unit in the Red Dog plate hosts all massive sulfide deposits in the area. It is notably carbonaceous, is generally finely laminated, and contains siliceous sponge spicules and radiolarians. The Kuna Formation in the Key Creek plate of the Endicott Mountains allochthon (60–110 m) resembles the Ikalukrok unit but is unmineralized and has thinner carbonate layers that are mainly organic-rich dolostone. Correlative strata in the Picnic Creek allochthon include less shale and mudstone and more carbonate (mostly calcareous spiculite). Conodonts and radiolarians indicate an age range of Osagean to early Chesterian (late Early to Late Mississippian) for the Kuna in the Red Dog area. Sedimentologic, faunal, and geochemical data imply that most of the Kuna formed in slope and basin settings characterized by anoxic or dysoxic bottom water and by local high productivity.

Diagenesis and porosity preservation in Eocene microporous limestones, South Florida, USA

NASA Astrophysics Data System (ADS)

Maliva, Robert G.; Missimer, Thomas M.; Clayton, Edward A.; Dickson, J. A. D.

2009-05-01

Microporous limestones may contain immobile, capillary-bound (irreducible) water that is only in diffusional contact with mobile pore waters or in some reservoirs may contain producible hydrocarbons. The preservation and distribution of microporosity impact both subsurface fluid flow and solute transport. The diagenesis of microporous limestones has received relatively little attention because their very fine grains and cements are not amenable to standard analytical methods. The Ocala Limestone (Upper Eocene) and upper Avon Park Formation (Middle Eocene) in South Florida contain microporous micritic limestones (mudstones to packstones) that are at an intermediate stage of diagenesis. The limestones have been exposed to the active near-surface environment, but have not yet reached a burial depth sufficient for intense chemical compaction and associated porosity reduction. Nuclear magnetic resonance (NMR) logging allowed for the quantification of total porosity, pore-size distribution, and permeability. The Ocala Limestone and Avon Park Formation have different predominant microfacies and porosity size distributions, but yet both retain total porosities predominantly between 35% and 37%. Estimated microporosities range mostly between 12% and 45%. The mudstones and wackestones of the Ocala Limestone have significantly lower permeabilities (mostly 3 to 12 md) than the wackestones to grainstones of the Avon Park Formation (commonly in the 100 to 3000 md range), which have more mixed and overall coarser pore sizes. Computer modeling using carbon and oxygen stable data indicates that the studied microporous limestones underwent only a low degree of chemical diagenetic alteration, despite likely experiencing episodes of freshwater flushing associated with post-depositional sea-level lowstands. The Ocala Limestone and Avon Park Formation limestones illustrate the general concept that total porosity is often largely preserved through early diagenesis (although may undergo intra-formational redistribution) and that confined aquifers are diagenetic quiescent environments.

Early Cretaceous Shallow-Water Platform Carbonates of the Bolkar Mountains, Central Taurides - South Turkey: Facies Analysis and Depositional Environments

NASA Astrophysics Data System (ADS)

Solak, Cemile; Taslı, Kemal; Koç, Hayati

2016-10-01

The study area comprises southern non-metamorphic part of the Bolkar Mountains which are situated in southern Turkey, eastern part of the Central Taurides. The studied five outcrops form geologically parts of the tectonostratigraphic units called as allochthonous Aladag Unit and autochthonous Geyikdagi Unit. The aim of this study is to describe microfacies and depositional environments of the Bolkar Mountains Early Cretaceous shallow- water platform carbonates. The Lower Cretaceous is represented by continuous thick- bedded to massive dolomite sequence ranging from 100 to 150 meters thick, which only contains locally laminated limestone intercalations in the Yüğlük section and thick to very thick-bedded uniform limestones ranging from approximately 50 to 120 meters, consist of mainly laminated- fenestral mudstone, peloidal-intraclastic grainstone-packstone, bioclastic packstone- wackestone, benthic foraminiferal-intraclastic grainstone-packstone, ostracod-fenestral wackestone-mudstone, dasycladacean algal packstone-wackestone and ooidal grainstone microfacies. Based on a combination sedimantological data, facies/microfacies and micropaleontological (predominantly dasycladacean algae and diverse benthic foraminifera) analysis, it is concluded that Early Cretaceous platform carbonates of the Bolkar Mountains reflect a tidally affected tidal-flat and restricted lagoon settings. During the Berriasian- Valanginian unfavourable facies for benthic foraminifera and dolomitization were predominate. In the Hauterivian-early Aptian, the effect of dolomitization largely disappeared and inner platform conditions still prevailed showing alternations of peritidal and lagoon facies, going from peritidal plains (representing various sub-environments including supratidal, intertidal area, tidal-intertidal ponds and ooid bars) dominated by ostracod and miliolids, to dasycladacean algae-rich restricted lagoons-subtidal. These environments show a transition in the vertical and lateral directions in all studied stratigraphic sections.

Structure, stratigraphy, and hydrocarbons offshore southern Kalimantan, Indonesia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bishop, W.F.

1980-01-01

Offshore southern Kalimantan (Borneo), Indonesia, the Sunda Shelf is bounded on the south by the east-west-trending Java-Madura foreland basin and on the north by outcrops of the granitic core of Kalimantan. Major northeast-southwest-trending faults created a basin and ridge province which controlled sedimentation at least until early Miocene time. Just above the unconformity, the oldest pre-CD Limestone clastic strata are fluviatile and lacustrine, the remainder consisting largely of shallow-marine, calcareous shale with interbeds of fine-grained, quartzose sandstone. A flood of terrigenous detritus - Kudjung unit 3 - resulted from post-CD Limestone uplift, and is more widely distributed. Unit 3 consistsmore » largely of fluviatile sandstone interbedded with shale and mudstone, grading upward to marine clastics with a few thin limestones near the top. The resulting Kudjing unit 2 is largely a shallow-basinal deposit, comprising thin, micritic limestones interbedded with calcareous shale and mudstone. Infilling of the basins was nearly complete by the end of Kudjing unit 1 deposition. Eastern equivalents of Kudjing units 1 and 2 are known as the Berai limestone interval (comprising bank, reefal, basinal, and open-marine limestones, and marl). Of the three oil fields in the area, two are shut in, but one has produced nearly 100 million bbl. Gas shows were recorded in most wells of the area, but the maximum flow was 1.8 MMcf methane/day, although larger flows with high percentages of carbon dioxide and nitrogen were reported. Fine-grained clastic strata of unit 3 are continuous with those farther south, where geochemical data indicate good source and hydrocarbon-generating potential. Sandstones with reservoir capability are present in the clastic intervals, and several carbonate facies have sporadically developed porosity. A variety of structural and stratigraphic traps is present. 20 figures, 1 table.« less

Petroleum systems of Zhu III depression in Pearl River Mouth Basin, South China Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weilin, Zhu; Li Mingbi; Wu Peikang

Zhu III depression is located in the west part of Pearl River Mouth Basin, and covers an area of 11,000 sq km. Until now more than twenty wells have been drilled in the depression and its surrounding area, and all oil-gas fields and oil-gas discoveries are concentrated inside the depression. Integrated study indicates that there are two petroleum systems in Zhu III depression. One is Wenchang - Zhuhai, Zhujiang oil system which is mainly distributed in Wenchang B sag in the southwest part of the depression. Its source rock, the Wenchang formation is mainly composed of dark mudstone of lacustrinemore » facies, with thicknesses up to more than 1000 m. Its reservoir includes tidal sandstone of transitional facies of Zhuhai formation and neritic sandstone of the lower part of Zhujiang formation. Through bounding faults and margin coarse sediment zone, oil generated from the Wenchang formation migrated into overlying sandstone of Zhuhai formation, which was overlaid by mudstone beds of bay facies of Zhuhai formation or neritic facies of Zhujiang formation, and formed oil accumulations. The other system is Enping - Zhuhai gas system, distributed in Wenchang A sag in the northeast part of the depression, whose source rock in the Enping formation deposited in the contracting stage of the lake, dominated by swamp coal measure in lithology and terrestrial plant clastics in kerogen components. The gas generated from Enping formation directly migrated into overlying tidal sandstone of Zhuhai formation and formed gas accumulations. Therefore, exploration in Wenchang A sag in the northeast part of the depression is for gas accumulations, and oil accumulations in Wenchang B sag in the southwest part of the depression, while oil-gas mixed accumulations are likely to be found in the transitional area of two systems.« less

Paleosol sequences within Lower Permian cyclothems of Kansas: Evidence of climatic cyclicity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, K.B.; McCahon, T.J.

The Lower Permian (Wolfcampian) cycles of Kansas are broadly similar to the better known Upper Pennsylvanian (Missourian) cyclothems of the midcontinent. The morphological features of paleosols within five successive variegated mudstone units of the Council Grove and Chase Groups have been described in detail. A consistent pattern has emerged with aridic paleosols near the bases of the mudstones intervals and vertic paleosols toward the tops. The lower paleosol profiles are typically calcareous with well-developed carbonate accumulation (Bk) horizons. These may contain carbonate nodules, rhizocretions, or less commonly calcretes (K-horizons). Drab haloed root races are a common feature of these grayishmore » reddish brown B horizons. The reddish color records oxidation under fairly well drained conditions, the underlying greenish gray horizons probably indicating the average position of the water table. Thin greenish gray to gray elluvial (E) horizons are preserved at the tops of many profiles. The upper paleosols within each variegated interval are characterized by well-developed vertic structures. Pedogenic slickensides, pseudoanticlines, and occasional gilgai result from the expansion and contraction of the soil such as occurs in a seasonal wet/dry environment. These paleosols are greenish gray to olive gray and often have abundant concertina root traces. The absence of a red oxidized horizon suggests more poorly drained conditions. The upward trend from drier, better drained soils to vertic, poorly drained soils could have been generated by short-term climate change toward increasing, though still seasonal, precipitation. If so, this observation suggests that cyclic climatic change may have been an important factor in generating Lower Permian cyclothems. Such a conclusion is consistent with other evidence that the limestone and shale facies of these cyclothems were deposited in consistently shallow depositional environments.« less

Semipermeability Evolution of Wakkanai Mudstones During Isotropic Compression

NASA Astrophysics Data System (ADS)

Takeda, M.; Manaka, M.

2015-12-01

Precise identification of major processes that influence groundwater flow system is of fundamental importance for the performance assessment of waste disposal in subsurface. In the characterization of groundwater flow system, gravity- and pressure-driven flows have been conventionally assumed as dominant processes. However, recent studies have suggested that argillites can act as semipermeable membranes and they can cause chemically driven flow, i.e., chemical osmosis, under salinity gradients, which may generate erratic pore pressures in argillaceous formations. In order to identify the possibility that chemical osmosis is involved in erratic pore pressure generations in argillaceous formations, it is essential to measure the semipermeability of formation media; however, in the measurements of semipermeability, little consideration has been given to the stresses that the formation media would have experienced in past geologic processes. This study investigates the influence of stress history on the semipermeability of an argillite by an experimental approach. A series of chemical osmosis experiments were performed on Wakkanai mudstones to measure the evolution of semipermeability during loading and unloading confining pressure cycles. The osmotic efficiency, which represents the semipermeability, was estimated at each confining pressure. The results show that the osmotic efficiency increases almost linearly with increasing confining pressure; however, the increased osmotic efficiency does not recover during unloading unless the confining pressure is almost relieved. The observed unrecoverable change in osmotic efficiency may have an important implication on the evaluation of chemical osmosis in argillaceous formations that have been exposed to large stresses in past geologic processes. If the osmotic efficiency increased by the past stress can remain unchanged to date, the osmotic efficiency should be measured at the past highest stress rather than the current in-situ stress. Otherwise, the effect of chemical osmosis on the pore pressure generation would be underestimated.

Paleogeographic insights based on new U-Pb dates for altered tuffs in the Miocene Barstow Formation, California

USGS Publications Warehouse

Miller, David; Rosario, Jose E.; Leslie, Shannon R.; Vazquez, Jorge A.

2013-01-01

The type section of the Barstow Formation in the Mud Hills, north of Barstow, is a reference section for early to middle Miocene paleontology, magnetostratigraphy, and dated volcanic episodes. Thanks to this robust chronologic framework, much of the interpretation of the paleogeography of the region from about 18 Ma to 13 Ma is based on study of the rocks in the Mud Hills. Eastward from the type section, the Barstow Formation typically is altered and structurally complex, and therefore it is hard to fit into the patterns inferred for sedimentation at the type section. We have studied ten tuff beds in five locations, extracting zircons that are partly eruptive components of the volcanic ash and partly detrital. Ion microprobe dating of the zircons associated with the ashes allows us to improve stratigraphic correlations. Dated tuffs range from 19.3 Ma to ~14.8 Ma. In several of the sections, we dated tuffs in the range 16.2-16.5 Ma, about the same age as the ~16.3 Ma Rak Tuff in the type section. The beginning of lacustrine limestone, shale, and siltstone deposition varies significantly, from ~16.3 Ma in the type section to ~18.5 Ma in hills to the east and the Calico Mountains, and greater than 19.3 Ma at Harvard Hill. At ~16.3 Ma, the sedimentary rocks ranged (west to east) from silty sandstone and limestone, to mudstone with gypsum, to massive mudstone, and then to sandstone. If the sections have not been greatly shuffled by subsequent faulting, the picture that emerges is one of a broad basin whose center near the Yermo Hills was occupied by a lake that was much longer lived and deeper than to the east and west.

Mineralogy, geochemistry, and palynology of modern and late Tertiary mangrove deposits in the Barreiras Formation of Mosqueiro Island, northeastern Pará state, eastern Amazonia

NASA Astrophysics Data System (ADS)

Behling, Hermann; da Costa, Marcondes Lima

2004-12-01

A coastal environment has been interpreted from 110 cm thick mudstone deposits found at the base of a 10 m immature laterite profile, which forms the modern coastal cliff on Mosqueiro Island in northeastern Pará state, northern Brazil. The late Tertiary sediment deposits of the Barreiras Formation are studied by multi-element geochemistry and pollen analyses. The mineralogical and geochemical results show that the gray, organic-rich deposits are composed of kaolinite, quartz, and illite/muscovite, as well as pyrite and anatase. They are rich in SiO 2, Al 2O 3, and some FeO. The composition is homogenous, indicating that the detritus source area is formed of lateritic soils derived from acid rock composition. Their chemical composition, including trace elements, is somewhat comparable to continental shale, and the values are below the upper continental Earth crust composition. The pollen analytical data document that the mudstone deposits were formed by an ancient mangrove ecosystem. Mineralogical, geochemical, and pollen analytical data obtained from late Tertiary mangrove deposits are compared with modern mangrove deposits from the Bragança Peninsula of the northeastern coast of Pará state. Although the pollen composition of the deposits is very similar to the modern one, the geochemical and mineralogical composition is different. Smectite was only found in the modern deposit; illite/mica occurs in the ancient deposit, along with Mg, K, and Na. The pollen signature and detrital minerals (kaolinite, quartz and anatase) found in both mangrove deposits show that during the Miocene, a humid tropical climate condition prevailed, similar to modern conditions.

Stratigraphy and depositional history of the West Franklin Limestone (Pennsylvanian) in the southernmost part of the Illinois Basin, western Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, N.R.

1994-04-01

The West Franklin Limestone in the subsurface of Webster and Union Counties, Kentucky includes 7.5--18m of strata deposited during portions of four depositional cycles in the latest Desmoinesian and earliest Missourian (Pennsylvanian). These cycles began with marine flooding and deposition of limestone, followed by progradation of siliciclastics in three of the four cycles, and ended with emergence. The basal West Franklin is micritic limestone (0.5--3m) that rests on rooted mudstone. Overlying the limestone are siliciclastics (1.5--7m) dominated by red and green claystone that is rooted at the top. Next is a middle limestone zone that includes either a paleokarsted micriticmore » limestone, or a thin bioclastic micritic limestone bed associated with phosphatic shale and locally a second bioclastic micritic limestone. Above that is another siliciclastic interval (4--9m) capped by rooted mudstone and locally a thin coal. The overlying micritic limestone (1.5--2.5m) marks the top of the West Franklin. Depositional events included: (1) marine flooding of an emergent shelf producing the basal limestone; (2) progradation of siliciclastics followed by emergence and paleosol development; (3) marine flooding producing a second limestone; (4) emergence and karstification of erosional remnants of the second limestone; (5) renewed marine flooding depositing shell hash'' limestones and phosphatic shale; (6) progradation of siliciclastics culminating in emergency; and (7) marine flooding producing the upper limestone. Thus, two flooding-emergence cycles are represented by the middle limestone zone. The second, locally-developed shell-hash'' limestone in the middle zone was deposited during the regressive phase of a depositional cycle. All of the other limestones were deposited during transgression.« less

Hydrogeology of an ancient arid closed basin: implications for tabular sandstone-hosted uranium deposits

USGS Publications Warehouse

Sanford, R.F.

1990-01-01

Hydrogeologic modeling shows that tabular-type uranium deposits in the Grants uranium region of the San Juan basin, New Mexico, formed in zones of ascending and discharging regional ground-water flow. The association of either lacustrine mudstone or actively subsiding structures and uranium deposits can best be explained by the occurrence of lakes at topographic depressions where ground water having different sources and compositions is likely to converge, mix, and discharge. Ascending and discharging flow also explains the association of uranium deposits with underlying evaporites and suggests a brine interface. The simulations contradict previous suggestions that ground water moved downward in the mudflat. -Author

The geology of Burnsville Cove, Bath and Highland Counties, Virginia

USGS Publications Warehouse

Swezey, Christopher; Haynes, John T.; Lambert, Richard A.; White, William B.; Lucas, Philip C.; Garrity, Christopher P.

2015-01-01

Burnsville Cove is a karst region in Bath and Highland Counties of Virginia. A new geologic map of the area reveals various units of limestone, sandstone, and siliciclastic mudstone (shale) of Silurian through Devonian age, as well as structural features such as northeast-trending anticlines and synclines, minor thrust faults, and prominent joints. Quaternary features include erosional (strath) terraces and accumulations of mud, sand, and gravel. The caves of Burnsville Cove are located within predominantly carbonate strata above the Silurian Williamsport Sandstone and below the Devonian Oriskany Sandstone. Most of the caves are located within the Silurian Tonoloway Limestone, rather than the Silurian-Devonian Keyser Limestone as reported previously.

Isopach and structure contour maps of the Burro Canyon(?) Formation in the Chama-El Vado Area, Chama Basin, New Mexico

USGS Publications Warehouse

Ridgley, Jennie L.

1983-01-01

In the Chama Basin a wequence of conglomerate, sandstone, and red, gray-green, and pale-purple mudstone occurs stratigraphically between the Upper Jurassic Morrison Formation and Upper Cretaceous Dakota Sandstone. This stratigraphic interval has been called the Burro Canyon Formation by several workers (Craig and others, 1959; Smith and others, 1961; Saucier, 1974). Although similarities in lithology and stratigraphic position exist between this unit and the Burro Canyon Formation in Colorado, no direct correlation has been made between the two. For this reason the unit in the Chama Basin is called the Burro Canyon(?) Formation. 

Revised stratigraphy and reinterpretation of the Miocene Pohang basinfill, SE Korea: sequence development in response to tectonism and eustasy in a back-arc basin margin

NASA Astrophysics Data System (ADS)

Sohn, Y. K.; Rhee, C. W.; Shon, H.

2001-09-01

The Miocene Pohang Basin is a pull-apart basin formed along the eastern continental margin of Korea (ECMK) during the back-arc opening of the East Sea (Sea of Japan). The basin is filled by more than 1 km thick, nonmarine to deep-marine strata. These strata show extreme vertical and lateral lithofacies changes and have caused decades-long controversies on their nature and stratigraphy. Previous sedimentological studies suggest that the basinfill was deposited by a series of contemporaneously developed depositional systems, including fan delta, prodelta, slope apron, and basin plain. Detailed mapping and magnetotelluric surveying show, however, that the basinfill is composed of several packages of strata (sequences) that are bounded by distinct and laterally persistent stratigraphic discontinuities (sequence boundaries). This suggests that the depositional systems in the Pohang Basin developed sequentially rather than contemporaneously. Six packages of strata are identified in the basin: a nonmarine to shallow marine (transgressive) sequence (Sequence 1), a Gilbert-type-delta conglomerate (Sequence 2), and alternations of submarine conglomerates and hemipelagic mudstones (Sequences 3-6). The conglomerates and hemipelagic mudstones of the latter four sequences are interpreted to represent lowstand depositional systems (slope apron, submarine fan, and high-gradient delta) and condensed intervals, respectively. Compilation of geochronologic, paleomagnetic, and biostratigraphic data suggests that Sequence 1 formed during the gradual subsidence of the ECMK prior to 17 Ma, whereas Sequence 2 formed in response to abrupt downfaulting of the Pohang Basin at about 17 Ma. Both sequences are interpreted to have developed in response to the early Miocene back-arc-opening tectonism of the East Sea. On the other hand, Sequences 3-6 formed between 17 and about 10.5 Ma. The Pohang Basin was subject to only minor tectonism during this period and could record global sea-level fluctuations. We suggest that the four alternations of conglomerates (lowstand systems) and hemipelagic mudstones (condensed intervals) resulted most probably from the 3rd-order glacioeustatic cycles during the middle Miocene. This finding implies that the signatures of global sea-level fluctuations can be deciphered from a tectonically active sedimentary basin if the timing of regional tectonic development is well constrained, and the global sea-level chart of Haq et al. ( Haq, B.W., Hardenbol, J., Vail, P.R., 1987, Chronology of fluctuating sea levels since the Triassic. Science 235, 1156-1167; Haq, B.U., Hardenbol, J., Vail, P.R., 1988. Mesozoic and Cenozoic chronostratigraphy and eustatic cycles. In: Wilgus, C.K., Hastings, B.S., Posamentier, H., Van Wagoner, J., Ross, C.A., Kendall, C.G.S.C. (Eds.), Sea-Level Changes: an Integrated Approach: Soc. Econ. Paleont. Mineral. Spec. Publ. 42, pp. 71-108) may serve as a guide to basinfill interpretation even in tectonically active sedimentary basins.

Storms in the deep: tempestite- and beach-like deposits in pelagic sequences (Middle-Upper Jurassic, Subbetic, South of Spain)

NASA Astrophysics Data System (ADS)

Pomar, Luis; Molina, Jose M.; Ruiz-Ortiz, Pedro A.; Vera, Juan A.

2017-04-01

Fine-peloidal- to coarse oolitic-bioclastic grainstones with hummocky cross stratification (HCS) occur interbedded in Middle-Upper Jurassic pelagic lime-mudstone successions (Betic ranges, Southern Spain). These strata were deposited in pelagic troughs and swells, away from continental areas, in the Southern Iberian Continental Margin of the Western Tethys. Previously interpreted as tempestites, mainly due to the attribution of the HCS to surface storm waves, they are now reinterpreted as the product of turbulence in deeper conditions. Among many, some selected examples are here presented. All of them share: 1) Grainstone beds are interbedded with pelagic mudstones and marls 2) Grainstone components were reworked by oscillatory flows superimposed to unidirectional tractive flows (unidirectional ripple lamination and HCS). 3) Components were either derived from shallow-water environments (e.g., ooids), or produced in pelagic conditions (e.g., radiolarians, Saccocoma, peloids, etc). 4) Although surface-storm tempestite flows can be required to bring downslope components from shallow-water settings, the grainstone beds reflect sediment reworking at a depth dominated by fine pelagic sedimentation. 5) Internal waves propagating along a pycnocline and breaking against a sloping surface are the best candidate to induce the sedimentary structures and sediment organization that characterize these grainstone beds. The examples here presented (Middle-Upper Jurassic of the Subbetic) include: a) Peloid grainstones interbedded with radiolarite marls deposited on the flanks of volcanic guyots. The interbedded lime muds and marls contain 'filaments', sponge spicules and radiolarians. b) Peloid-bioclastic (radiolarians, Saccocoma, etc.) grainstone beds with HCS, interbedded with pelagic lime muds. c) Coarse oolitic grainstone unit, encased in pelagic marls, with wedge-shaped crossbed-sets with gently seaward-dipping parallel lamination, and sets of low-angle up-slope dipping parallel lamination. These oolitic grainstones hold characteristics similar to the ridge-berm-swash zone of modern beaches and are here interpreted to represent an "internal beach". d) Crossbedded peloidal-skeletal (Saccocoma) grainstones with HCS and wave ripples on top, interbedded with pelagic mudstones and wackestones with abundant bioturbation and ammonites (Ammonitico Rosso facies). All these grainstones are reinterpreted as the product of breaking internal waves. This breaking produces episodic high-turbulence events and remobilizes sediments at the depth where the pycnocline intersects the sea floor. The swash run-up produces erosion and the backwash return flow can bypass the breaker and travel downdip where the oscillatory-flow component of the IWs become dominant and form the characteristic HCS bedforms. Coarser sediments "trapped" at the breaker zone form sediment accumulations similar to the sediments caught by the "littoral fence" in the surface beach. This scenario evidences the HCS not to be necessarily linked to the surface storms but to the bathymetry of the pycnocline, solving the problem of having HCS in pelagic zones where the storm and hurricanes wave action can be considered "out-of-context". Acknowledgments: fundings from projet CGL2014-52096-P and Research Group RNM-200 (PAIDI-JA)

Orbital- to Sub-Orbital-Scale Cyclicity in Seismic Reflections and Sediment Character in Early to Middle Pleistocene Mudstone, Santa Barbara Basin, California

NASA Astrophysics Data System (ADS)

Peterson, C. D.; Behl, R. J.; Nicholson, C.; Lisiecki, L. E.; Sorlien, C. C.

2009-12-01

High-resolution seismic reflection records and well logs from the Santa Barbara Channel suggest that large parts of the Pleistocene succession records climate variability on orbital to sub-orbital scales with remarkable sensitivity, much like the well-studied sediments of the last glacial cycle (ODP Site 893). Spectral analysis of seismic reflection data and gamma ray logs from stratigraphically similar Pleistocene sections finds similar cyclic character and shifts through the section. This correlation suggests that acoustic impedance and physical properties of sediment are linked by basin-scale, likely climatically-driven, oscillations in lithologic composition and fabric during deposition, and that seismic profiling can provide a method for remote identification and correlation of orbital- and sub-orbital-scale sedimentary cyclicity. Where it crops out along the northern shelf of the central Santa Barbara Channel, the early to middle Pleistocene succession (~1.8-1.2 Ma) is a bathyal hemipelagic mudstone with remarkably rhythmic planar bedding, finely laminated fabric, and well-preserved foraminifera, none of which have been significantly altered, or obscured by post-depositional diagenesis or tectonic deformation. Unlike the coarser, turbiditic successions in the central Ventura and Los Angeles basins, this sequence has the potential to record Quaternary global climate change at high resolution. Seismic reflection data (towed chirp) collected on the R/V Melville 2008 Cruise (MV08) penetrate 10's of meters below seafloor into a ~1 km-long sequence of south-dipping seismic reflectors. Sampling parallel to the seafloor permits acquisition of consistent signal amplitude for similar reflectors without spreading loss. Based on established age ranges for this section, sedimentation rates may range from 0.4 to 1.4 meters/kyr, therefore suggesting that the most powerful cycles are orbital- to sub-orbital-scale. Discrete sets of cycles with high power show an abrupt shift to shorter wavelengths midway through the section. Deep in the section, the strongest cycles indicated by spectral analysis are 50 and 16 meters thick, whereas up section, the strongest cycles are 20 and 12 meters thick. Nearby industry boreholes that penetrate a stratigraphically similar, 1500-meter-thick mudstone section, provide logs of natural gamma ray intensity with a higher sample interval (15 cm), allowing resolution and analysis of even higher frequency lithologic cycles. The strongest cycle deep in the section is 100 meters thick, and up section, the strongest cycle is 12 meters thick. This abrupt decrease in dominant cycle thickness midway through both the seismic and gamma ray records perhaps indicates a basin-wide shift in sedimentation. With improved chronostratigraphy based on Sr-isotope ratios and biostratigraphy, and comparison with paleoclimate proxy data, we will test if seismically resolved lithologic oscillations can be reliably interpreted as representing climatically driven Milankovitch cycles. This method may be used to evaluate the age and paleoceanographic potential of sedimentary strata before a coring vessel is deployed.

Drilling the Messinian Salinity Crisis as a Model Analogue for Dolomite Deposition at the End of Massive Salt Deposition Events

NASA Astrophysics Data System (ADS)

McKenzie, Judith A.; Aloisi, Giovanni; Anjos, Sylvia; Latgé, Ricardo; Matsuda, Nilo; Bontognali, Tomaso; Vasconcelos, Crisogono

2015-04-01

Sedimentologic and stratigraphic studies of the Lower Cretaceous sequence, deposited in the economically important Campos Basin, southeast Brazil, document the occurrence of ~20-m-thick dolomite intervals overlying the "massive salt" megasequences of the Lagoa Feia Formation. This stratigaphic succession marks the Aptian/Albian transition from extreme evaporitic conditions of the Lagoa Feia Formation to shallow marine conditions of the Macaé Formation, related to the early opening of the South Atlantic. The facies change from evaporites to dolomite is interpreted as a product of dolomitization resulting from the refuxing of hypersaline fluids from shallow embayments with intense evaporation (Latgé, 2001). Although the reflux model provides a mechanism to produce fluids with geochemical composition favorable for dolomite precipitation, it cannot account for all of the factors required to promote dolomite precipitation. In this study, we propose a different model to explain the post-evaporite deposition of massive dolomite based on the study of sequences deposited at the end Messinian Salinity Crisis, which were recovered from the deep basins of the Mediterranean Sea during DSDP/ODP drilling campaigns. At most of these deep-water sites, the cored interval contained unusual dolomite deposits overlying the uppermost evaporite sections. For example, the upper Messinian sedimentary sequence at DSDP Site 374 comprises non-fossiliferous dolomitic mudstone overlying dolomitic mudstone/gypsum cycles, which in turn overlie anhydrite and halite (Hsü, Montadert et al., 1978). We postulate that the end Messinian dolomite is a product of microbial activity under extreme hypersaline conditions. In the last 20 years, research into the factors controlling dolomite precipitation under Earth surface conditions has led to the development of new models involving the metabolism of microorganisms and associated biofilms to overcome the kinetic inhibitions associated with primary dolomite precipitation. Furthermore, based on the limited pore-water geochemical data obtained during drilling at DSDP Site 374: Messina Abyssal Plain, the dolomitic mudstones of the uppermost Messinian evaporite complex represent an ideal candidate for such an extensive study in a "natural laboratory". In fact, the data suggest that microbial diagenesis and perhaps dolomite precipitation may still be occurring. Thus, to increase our understanding of the biogeochemical processes associated with ancient massive dolomite formation, a major new drilling campaign to study the sub-seafloor Messinian evaporite complex in the deep Mediterranean basins, using greatly enhanced drilling technology currently available within the new International Ocean Discovery Program (IODP), would be timely. Hsü, K., Montadert, L. et al., 1978. Initial Reports of the Deep Sea Drilling Project, Volume 42, Part 1: Washington (U.S. Government Printing Office). Latgé, M. A. R., 2001. O Albiano no Atlântico Sul: estratigrafia, Paleoceanografia e Relações Globais. PhD thesis, Universidade Federal do Rio Grande do Sul, pp. 257.

The Middle Jurassic basinal deposits of the Surmeh Formation in the Central Zagros Mountains, southwest Iran: Facies, sequence stratigraphy, and controls

USGS Publications Warehouse

Lasemi, Y.; Jalilian, A.H.

2010-01-01

The lower part of the Lower to Upper Jurassic Surmeh Formation consists of a succession of shallow marine carbonates (Toarcian-Aalenian) overlain by a deep marine basinal succession (Aalenian-Bajocian) that grades upward to Middle to Upper Jurassic platform carbonates. The termination of shallow marine carbonate deposition of the lower part of the Surmeh Formation and the establishment of deep marine sedimentation indicate a change in the style of sedimentation in the Neotethys passive margin of southwest Iran during the Middle Jurassic. To evaluate the reasons for this change and to assess the basin configuration during the Middle Jurassic, this study focuses on facies analysis and sequence stratigraphy of the basinal deposits (pelagic and calciturbidite facies) of the Surmeh Formation, referred here as 'lower shaley unit' in the Central Zagros region. The upper Aalenian-Bajocian 'lower shaley unit' overlies, with an abrupt contact, the Toarcian-lower Aalenian platform carbonates. It consists of pelagic (calcareous shale and limestone) and calciturbidite facies grading to upper Bajocian-Bathonian platform carbonates. Calciturbidite deposits in the 'lower shaley unit' consist of various graded grainstone to lime mudstone facies containing mixed deep marine fauna and platform-derived material. These facies include quartz-bearing lithoclast/intraclast grainstone to lime mudstone, bioclast/ooid/peloid intraclast grainstone, ooid grainstone to packstone, and lime wackestone to mudstone. The calciturbidite layers are erosive-based and commonly exhibit graded bedding, incomplete Bouma turbidite sequence, flute casts, and load casts. They consist chiefly of platform-derived materials including ooids, intraclasts/lithoclasts, peloids, echinoderms, brachiopods, bivalves, and open-ocean biota, such as planktonic bivalves, crinoids, coccoliths, foraminifers, and sponge spicules. The 'lower shaley unit' constitutes the late transgressive and the main part of the highstand systems tract of a depositional sequence and grades upward to platform margin and platform interior facies as a result of late highstand basinward progradation. The sedimentary record of the 'lower shaley unit' in the Central Zagros region reveals the existence of a northwest-southeast trending platform margin during the Middle Jurassic that faced a deep basin, the 'Pars intrashelf basin' in the northeast. The thinning of calciturbidite layers towards the northeast and the widespread Middle Jurassic platform carbonates in the southern Persian Gulf states and in the Persian Gulf area support the existence of a southwest platform margin and platform interior source area. The platform margin was formed as a result of tectonic activity along the preexisting Mountain Front fault associated with Cimmerian continental rifting in northeast Gondwana. Flooding of the southwest platform margin during early to middle Bajocian resulted in the reestablishment of the carbonate sediment factory and overproduction of shallow marine carbonates associated with sea-level highstand, which led to vertical and lateral expansion of the platform and gradual infilling of the Pars intrashelf basin by late Bajocian time. ?? 2010 Springer-Verlag.

A Search for Impact Debris in the Pliocene Age Sirius Group, Transantarctic Mountains

NASA Technical Reports Server (NTRS)

Harvey, Ralph P.; Boyd, Hiram

2003-01-01

The Sirius Group is a mixed sequence of interbedded diamictite and mudstone of Pliocene age found at scattered locations along the length of the Transantarctic Mountains. Sirius Group rocks are usually considered tillites, but contain some very "un-tillite" elements. Within section and from site to site, Sirius Group rocks vary considerably in terms of texture and relative abundance of clast lithologies, recording a history that includes shifting influences of glacial, lacustrine, fluvial and wetland processes. The colorful heritage of the Sirius Group has generated a lot of interest due to its potential as a record of changes in the behavior of the East Antarctic icesheet during a climatologically interesting period.

The Nitrate/Perchlorate Ratio on Mars as an Indicator for Habitability

NASA Technical Reports Server (NTRS)

Stern, J. C.; Sutter, B.; McKay, C. P.; Navarro-Gonzalex, R.; Freissinet, C.; Conrad, P. G.; Mahaffy, P. R.; Archer, P. D., Jr.; Ming, D. W.; Niles, P. B.;

Isopach and structure contour maps of the Burro Canyon(?) Formation in the Mesa Golondrina and Mesa de los Viejos areas, Chama Basin, New Mexico

USGS Publications Warehouse

Ridgley, Jennie L.

1983-01-01

In the Chama Basin a wequence of conglomerate, sandstone, and red, gray-green, and pale-purple mudstone occurs stratigraphically between the Upper Jurassic Morrison Formation and Upper Cretaceous Dakota Sandstone. This stratigraphic interval has been called the Burro Canyon Formation by several workers (Craig and others, 1959; Smith and others, 1961; Saucier, 1974). Although similarities in lithology and stratigraphic position exist between this unit and the Burro Canyon Formation in Colorado, no direct correlation has been made between the two. For this reason the unit in the Chama Basin is called the Burro Canyon(?) Formation. 

Soft-sediment deformation structures from an ice-marginal storm-tide interactive system, Permo-Carboniferous Talchir Formation, Talchir Coalbasin, India

NASA Astrophysics Data System (ADS)

Bhattacharya, H. N.; Bhattacharya, Biplab

2010-01-01

Permo-Carboniferous Talchir Formation, Talchir Coalbasin, India, records sedimentation during a phase of climatic amelioration in an ice-marginal storm-affected shelf. Evidences of subtidal processes are preserved only under thick mud drapes deposited during waning storm phases. Various soft-sediment deformation structures in some sandstone/siltstone-mudstone interbeds, like syn-sedimentary faults, deformed laminations, sand-silt flows, convolute laminations and various flame structures, suggest liquefaction and fluidization of the beds due to passage of syn-depositional seismic shocks. In the Late Paleozoic ice-marginal shelf, such earthquake tremors could be generated by crustal movements in response to glacioisostatic adjustments of the basin floor.

Preliminary report on the use of LANDSAT-1 (ERTS-1) reflectance data in locating alteration zones associated with uranium mineralization near Cameron, Arizona

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spirakis, C.S.; Condit, C.D.

1975-01-01

LANDSAT-1 (ERTS-1) multispectral reflectance data were used to enhance the detection of alteration around uranium deposits near Cameron, Ariz. The technique involved stretching and ratioing computer-enhanced data from which electronic noise and atmospheric haze had been removed. Using present techniques, the work proves that LANDSAT-1 data are useful in detecting alteration around uranium deposits, but the method may still be improved. Bluish-gray mudstone in the target area could not be differentiated from the altered zones on the ratioed images. Further experiments involving combinations of ratioed and nonratioed data will be required to uniquely define the altered zones.

Humic acid provenance influence to the adsorption capacity in uranium and thorium removal

NASA Astrophysics Data System (ADS)

Prasetyo, E.

2018-01-01

It is common knowledge that humic acid is organic compound without certain chemical composition since it is derived from different organic materials. Further this raises question whether the different humic acid sample used could lead to different adsorbent properties e.g. adsorption capacity. To address the problem, this paper is aimed to clarify the relation between the provenances of humic acid and synthesized adsorbent properties especially adsorption capacities by quantitative and qualitative functional groups determination including discussion on their effect to the metal ion adsorption mechanism using three humic acid samples. Two commercial samples were derived from recent compost while the other extracted from tertiary carbonaceous mudstone strata.

Physical data of soil profiles formed on late Quaternary marine terraces near Santa Cruz, California

USGS Publications Warehouse

Munster, Jennie; Harden, Jennifer W.

2002-01-01

The marine terraces in and around Santa Cruz, California, represent a set of well-preserved terraces formed as a product of geology, sea level, and climate. A marine terrace begins as a wave cut platform. Eustatic sea level changes, seacliff erosion, and tectonic uplift work together to generate marine terraces. "When a wave-cut platform is raised (due to tectonic activity) above sea level and cliffed by wave action it becomes a marine terrace" (Bradley, 1957, p. 424). During glacial periods, eustatic sea level is estimated to have dropped by 150 meters (Fairbanks, 1989). Cliff retreat measured from aerial photographs between 1930 and 1980 vary from 0.0 to 0.2 m yr–1 (Best and Griggs, 1991). Estimates of uplift rates along the Santa Cruz coastline vary from 0.10 to 0.48 m kyr–1 (Bradley and Griggs, 1976; Weber and others, 1999). Uplift mechanisms include coseismic uplift associated both with a reverse component of slip on the steeply SW dipping Loma Prieta fault in the restraining bend of the San Andreas Fault and a small component of reverse slip on the steeply SE dipping San Gregorio fault (Anderson and Menking 1994). Previous work studying physical properties on these terraces include Pinney and others (in press) and Aniku (1986) and Bowman and Estrada (1980). Sedimentary deposits of the marine terraces are a mixture of terrestrial and marine sediments but generally consist of a sheet of marine deposits overlying the old platform and a wedge of nonmarine deposits banked against the old sea cliff (Bradley, 1957). Bedrock underlying the terraces in the Santa Cruz area is generally either Santa Margarita Sandstone or Santa Cruz Mudstone. The Santa Margarita Sandstone represents an upper Miocene, transgressive, tidally dominated marine-shelf deposit with crossbedded sets of sand and gravel and horizontally stratified and bioturbated invertebrate-fossils beds (Phillips, 1990). The siliceous Santa Cruz Mudstone, of late Miocene age, conformably overlies the Santa Margarita Sandstone. The Santa Cruz Mudstone is a thin to medium-bedded siliceous mudstone with nonsiliceous mudstone and siltstone and minor amounts of sandstone. The siliceous nature implies organic deposition in a quiescent, deep-water environment. Bedrock is mantled by 1–4 meters of medium to coarse-grained regressive beach sediment and fluvial deposits from the Ben Lomond Mountains. Terrace age increases with elevation above sea level, and weathering of primary minerals increases with age. The suite of soils formed on the terraces is referred to as a soil chronosequence. Soil chronosequences, important tools in characterizing natural weathering rates, are defined as a group of soils that differ in age and therefore in duration of weathering but have similar climatic conditions, vegetation, geomorphic position, and parent material (Jenny, 1941; Birkland, 1999). Soils are frequently useful indicators of geomorphic age (Muhs, 1982; Switzer and others, 1988) and are a function of pedogenic and/or eolian processes. Some aspects of soil development can be episodic but when viewed on large time scales can be perceived as continuous (Switzer and others, 1988). The age of the soil may be constrained by the age of the deposit, since soil formation generally commences when deposition has ceased (Birkland, 1999). Dating of the terraces provides an unprecedented opportunity to study weathering and soil-formation rates (Perg and others, 2001; Hanks and others, 1984; Bradley and Griggs, 1976; Bradley and Addicott, 1968; Bradley, 1956). Ages of the terraces recently dated by cosmogenic radionuclide are, starting with the youngest, 65, 92, 137, 139, and 226 k.y. (Perg and others, 2001). However, these ages are much younger than recent radiometric dates on mollusk shells (Muhs, U.S. Geological Survey, personal communication, 2002; Bradley and Addicott, 1968). For this study, soils were sampled on five terraces. Terrace one in the Lighthouse Field along Westcliff in Santa Cruz was the last site selected, and this report contains minimal data on this terrace. Sites on the second, third, and fourth terraces are located in Wilder Ranch, Santa Cruz, California. Site five is on private property north of Wilder Ranch. Careful consideration was taken in selecting field sites, choosing locations in a topographically flat area to avoid effects of erosion, and trying to keep parent material similar. This report contains physical properties of the soil profiles on four of the five marine terraces near Santa Cruz, California, excluding the youngest terrace in all tables except 6 and 7. Data includes field descriptions, bulk density, grain size analyses, weight percent magnetic fraction, and the soil development index. Soil properties are important when trying to understand the chemistry of a given profile or when comparing profiles. Grain size constrains the movement of water in a profile, thus controlling movement of chemicals and weathering rates. Bulk density is a useful property to calculate chemical inventory. Quantifying the magnetic fraction aids in understanding the Fe inventory for these soils. The soil development index is a semi-quantitative way to define the degree of development of a soil profile. This is a useful way to compare development of profiles for this chronosequence or compare the Santa Cruz terraces to a suit of other terraces or another chronosequence.

Stratigraphy and paleontology of Lower Permian rocks north of Cananea, northern Sonora, Mexico

USGS Publications Warehouse

Blodgett, R.B.; Moore, Thomas E.; Gray, F.

2002-01-01

Lower Permian carbonate and overlying red bed clastic rocks are present in a 2 km2 stratigraphic window in the vicinity of Rancho La Cueva, Santa Cruz sheet (scale 1:50,000), northern Sonora, Mexico. This exposure lies unconformably beneath predominantly intermediate Upper Cretaceous volcanics yielding 40Ar/39Ar ages of 73.4?? 0.18 and 71.1 ?? 0.35 Ma. The lower part of the Permian succession consists of light- to medium-gray colored limestones of the Colina Limestone, with a minimum thickness of 235 m. Sedimentary features suggest shallow water, slightly restricted depositional environments. Although lacking observable fossils for the most part, two intervals of richly fossiliferous, silicified shell beds are present near the base and top of the Colina Limestone. The lower fauna consist mostly of gastropods and bivalves. The presence of a new microdomatid gastropod species. Glyptospira sonorensis n. sp., close to Glytospira arelela Plas, suggests a late Wolfcampian age for this horizon. The upper fauna are predominantly molluscan dominated (gastropods and bivalves), but some brachiopods (productids and the rhynchonellid genus Pontisia) are also present. Gastropod genera include Bellerophon, Warthia, Euomphalus (represented by the species, Euomphalus kaibabensis Chronic), Baylea, Worthenia, Naticopsis, Goniasma, Kinishbia, Cibecuia, and Glyptospira. The gastropods suggest a Leonardian (late Early Permian) age for this horizon, and many of the species have previously been recorded from the Supai Group and Kaibab Formation of northern and central Arizona. The Colina Limestone is conformably overlain by 11.2 m of light-gray lime mudstone and dolostone, assigned here to the Epitaph Dolomite, which in turn is succeeded by 58.8 m of red-colored sandstone and gray lime mudstone, assigned here to the Scherrer Formation. This Lower Permian succession is significant because it further strengthens the stratigraphic ties of southeastern Arizona rocks with those of northern Sonora and confirms the presence of North American cratonal stratigraphy in the northern part of the state of Sonora, Mexico. Published by Elsevier Science Ltd.

Bioerosion by pit-forming, temperate-reef sea urchins: History, rates and broader implications.

PubMed

Russell, Michael P; Gibbs, Victoria K; Duwan, Emily

2018-01-01

Sea urchins are dominant members of rocky temperate reefs around the world. They often occur in cavities within the rock, and fit so tightly, it is natural to assume they sculpted these "pits." However, there are no experimental data demonstrating they bore pits. If they do, what are the rates and consequences of bioerosion to nearshore systems? We sampled purple sea urchins, Strongylocentrotus purpuratus, from sites with four rock types, three sedimentary (two sandstones and one mudstone) and one metamorphic (granite). A year-long experiment showed urchins excavated depressions on sedimentary rocks in just months. The rate of pit formation varied with rock type and ranged from <5 yr for medium-grain sandstone to >100 yr for granite. In the field, there were differences in pit size and shapes of the urchins (height:diameter ratio). The pits were shallow and urchins flatter at the granite site, and the pits were deeper and urchins taller at the sedimentary sites. Although overall pit sizes were larger on mudstone than on sandstone, urchin size accounted for this difference. A second, short-term experiment, showed the primary mechanism for bioerosion was ingestion of the substratum. This experiment eliminated potential confounding factors of the year-long experiment and yielded higher bioerosion rates. Given the high densities of urchins, large amounts of rock can be converted to sediment over short time periods. Urchins on sandstone can excavate as much as 11.4 kg m-2 yr-1. On a broader geographic scale, sediment production can exceed 100 t ha-1 yr-1, and across their range, their combined bioerosion is comparable to the sediment load of many rivers. The phase shift between urchin barrens and kelp bed habitats in the North Pacific is controlled by the trophic cascade of sea otters. By limiting urchin populations, these apex predators also may indirectly control a substantial component of coastal rates of bioerosion.

Mapping Electrical Structures in the Jarud Basin, Northeast China through Magnetotelluric Sounding

NASA Astrophysics Data System (ADS)

Zhao, W.

2015-12-01

In recent years, China Geological Survey (CGS) has launched 3D geological mapping programs from regional to local scales. The project Deep geological survey at the periphery of the Songliao Basin funded by CGS was implemented from 2012 to 2014. Its main goals are to reveal the tectonic framework of the Jarud Basin (JB) as well as to identify the strata distribution of Permian Linxi Formation by integrating new electromagnetic data with existing geophysical and geological data since black mudstones in the Linxi Formation have shown the potential of shale gas. The study area covered dominantly with Cretaceous-Jurassic igneous rocks with exception of the southeast part is situated in Jarud Banner and Ar Horqin Banner, Inner Mongolia, China. It tectonically lies in the southern Great Khingan Range, western margin of the Songliao Basin, and north of Xar Moron Fault. Over the period of 2012 to 2014, a magnetotelluric survey was carried out at the JB. A total of 926 MT sites with nominal spacing 1 km was acquired in the effective frequency range of 0.01 Hz ~ 300 Hz on six NW and five NE profiles, covering area that exceeds 10, 000 km2. After dimensionality analysis and static shift removal, the nonlinear conjugate algorithm was used to conduct 2D inversion for TM and TE modes. The resistivity models underwent examination using sensitivity tests. The optimal resistivity models revealed numerous large faults, some of which constitute the boundaries of the JB, and modified the tectonic framework. Integrated with well logging and geological mapping data, the strata of Linxi Formation were identified and classified into three depressions: Depressions Arituguri, Gadasu and Wufen. Attention should be paid to Depression Gadasu with area of around 500 km2 since it contains reasonably thick conductive sediments exceeding 4 km in depth which are inferred to be black mudstones pertaining to shale gas.

High-velocity frictional strength across the Tohoku-Oki megathrust determined from surface drilling torque

NASA Astrophysics Data System (ADS)

Ujiie, K.; Inoue, T.; Ishiwata, J.

2015-12-01

Frictional strength at seismic slip rates is a key to evaluate fault weakening and rupture propagation during earthquakes. The Japan Trench First Drilling Project (JFAST) drilled through the shallow plate-boundary thrust, where huge displacements of ~50 m occurred during the 2011 Tohoku-Oki earthquake. To determine the downhole frictional strength at drilled site (Site C0019), we analyzed surface drilling data. The equivalent slip rate estimated from the rotation rate and inner and outer radiuses of the drill bit ranges from 0.8 to 1.3 m/s. The measured torque includes the frictional torque between the drilling string and borehole wall, the viscous torque between the drilling string and seawater/drilling fluid, and the drilling torque between the drill bit and sediments. We subtracted the former two from the measured torque using the torque data during bottom-up rotating operations at several depths. Then, the shear stress was calculated from the drilling torque taking the configuration of the drill bit into consideration. The normal stress was estimated from the weight on bit data and the projected area of the drill bit. Assuming negligible cohesion, the frictional strength was obtained by dividing shear stress by normal stress. The results show a clear contrast in high-velocity frictional strength across the plate-boundary thrust: the friction coefficient of frontal prism sediments (hemipelagic mudstones) in hanging wall is 0.1-0.2, while that in subducting sediments (hemipelagic to pelagic mudstones and chert) in footwall increases to 0.2-0.4. The friction coefficient of smectite-rich pelagic clay in the plate-boundary thrust is ~0.1, which is consistent with that obtained from high-velocity (1.3 m/s) friction experiments and temperature measurements. We conclude that surface drilling torque provides useful data to obtain a continuous downhole frictional strength.

Upper Campanian calciclastic turbidite sequences from the Hacımehmet area (eastern Pontides, NE Turkey): integrated biostratigraphy and microfacies analysis

NASA Astrophysics Data System (ADS)

Sari, Bilal; Kandemir, Raif; Özer, Sacit; Walaszczyk, Ireneusz; Görmüş, Muhittin; Demircan, Huriye; Yilmaz, Cemil

2014-12-01

The upper Campanian (Cretaceous) of the Hacımehmet area (south of the city of Trabzon; Eastern Pontides) is mainly composed of calciclastic turbidites. The basinal unit of the 119 m thick succession includes thin red pelagic limestone interlayers and conglomerates dominated by volcanic clasts. The overlying upper slope and lower slope units of the sequence consist of an alternation of allochthonous calcarenite/calcirudite beds and pelagic marls and mudstones. Calcarenite/calcirudite beds dominate the upper slope unit of the succession and are composed of transported material, including benthic foraminifers, red algae, bryozoan, crinoid and rudist fragments, inoceramid bivalve prisms and neritic and pelagic carbonate lithoclasts. The occurrence of Helicorbitoides boluensis (Sirel) extracted from the calcarenite/calcirudite beds indicates a Campanian age. Identifiable rudists such as Joufia reticulata Boehm, Bournonia cf. anatolica Ozer, Biradiolites cf. bulgaricus Pamouktchiev and ?Biradiolites sp. from the upper slope unit of the succession indicate a late Campanian- Maastrichtian age. The planktonic foraminifers within the red pelagic limestone beds, marls and mudstones throughout the succession consist mainly of Campanian-Maastrichtian forms and suggest mainly basinal depositional conditions. The presence of Radotruncana cf. calcarata (Cushman) accompanied by Globotruncanita elevata (Brotzen) in the basinal unit of the succession indicates an early late Campanian age for the lower part of the succession. Inoceramid bivalves have been collected from the upper part of the succession. The fauna is dominated by `Inoceramus' tenuilineatus Hall and Meek, 1854 and Cataceramus haldemensis (Giers, 1964); other taxa recognised are: `Inoceramus' algeriensis Heinz, 1932, Platyceramus vanuxemi (Meek and Hayden, 1860), `Inoceramus' cf. nebrascensis Owen, 1852, Cataceramus aff. barabini (Morton, 1834), Cataceramus gandjaensis (Aliev, 1956), and `Inoceramus' sp.; the assemblage indicates the `Inoceramus' tenuilineatus Zone; corresponding to the middle-late Campanian boundary interval. The uppermost part of the succession is characterized by the presence of the trace fossils Scolicia strozzii and Scolicia isp., indicating a mixed Skolithos-Cruziana ichnofacies. This ichnofacies suggests a well-oxygenated environment.

Mineral Fractionation during Sediment Comminution and Transport in Fluvio-Deltaic and Lacustrine Rocks of the Bradbury Group, Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Siebach, K. L.; Baker, M. B.; Grotzinger, J. P.; McLennan, S. M.; Gellert, R.; Thompson, L. M.; Hurowitz, J.

2017-12-01

Mineral distribution patterns in sediments of the Bradbury group in Gale crater, interpreted from observations by the Mars Science Laboratory rover Curiosity, show the importance of transport mechanics in source-to-sink processes on Mars. The Bradbury group is comprised of basalt-derived mudstones to conglomerates exposed along the modern floor of Gale crater and analyzed along a 9-km traverse of the Curiosity rover. Over 110 bulk chemistry analyses of the rocks were acquired, along with two XRD mineralogical analyses of the mudstone. These rocks are uniquely suited for analysis of source-to-sink processes because they exhibit a wide range of compositions, but (based on multiple chemical weathering proxies) they appear to have experienced negligible cation-loss during weathering and erosion. Chemical variations between analyses correlate with sediment grain sizes, with coarser-grained rocks enriched in plagioclase components SiO2, Al2O3, and Na2O, and finer-grained rocks enriched in components of mafic minerals, consistent with grain-size sorting of mineral fractions during sediment transport. Further geochemical and mineralogical modeling supports the importance of mineral fractionation: even though the limited XRD data suggests that some fraction (if not all) of the rocks contain clays and an amorphous component, models show that 90% of the compositions measured are consistent with sorting of primary igneous minerals from a plagioclase-phyric subalkaline basalt (i.e., no corrections for cation-loss are required). The distribution of K2O, modeled as a potassium feldspar component, is an exception to the major-element trends because it does not correlate with grain size, but has an elevation-dependent signal likely correlated with the introduction of a second source material. However, the dominant compositional trends within the Bradbury group sedimentary rocks are correlated with grain size and consistent with mineral fractionation of minimally-weathered plagioclase-phyric basalts; the plagioclase phenocrysts settle into coarser deposits and the finer deposits are dominated by mafic minerals.

Electrical Conductive Mechanism of Gas Hydrate-Bearing Reservoirs in the Permafrost Region of Qilian Mountain

NASA Astrophysics Data System (ADS)

Peng, C.; Zou, C.; Tang, Y.; Liu, A.; Hu, X.

2017-12-01

In the Qilian Mountain, gas hydrates not only occur in pore spaces of sandstones, but also fill in fractures of mudstones. This leads to the difficulty in identification and evaluation of gas hydrate reservoir from resistivity and velocity logs. Understanding electrical conductive mechanism is the basis for log interpretation. However, the research is insufficient in this area. We have collected well logs from 30 wells in this area. Well logs and rock samples from DK-9, DK-11 and DK-12 wells were used in this study. The experiments including SEM, thin section, NMR, XRD, synthesis of gas hydrate in consolidated rock cores under low temperature and measurement of their resistivity and others were performed for understanding the effects of pore structure, rock composition, temperature and gas hydrate on conductivity. The results show that the porosity of reservoir of pore filling type is less than 10% and its clay mineral content is high. As good conductive passages, fractures can reduce resistivity of water-saturated rock. If fractures in the mudstone are filled by calcite, resistivity increases significantly. The resistivity of water-saturated rock at 2°C is twice of that at 18°C. The gas hydrate formation process in the sandstone was studied by resistivity recorded in real time. In the early stage of gas hydrate formation, the increase of residual water salinity may lead to the decrease of resistivity. In the late stage of gas hydrate formation, the continuity decrease of water leads to continuity increase of resistivity. In summary, fractures, rock composition, temperature and gas hydrate are important factors influencing resistivity of formation. This study is helpful for more accurate evaluation of gas hydrate from resistivity log. Acknowledgment: We acknowledge the financial support of the National Special Program for Gas Hydrate Exploration and Test-production (GZH201400302).

Magnetostratigraphic Dating of Paleogene Sediments in the Seymour Island (Antarctic Peninsula): A Preliminary Chronostratigraphy

NASA Astrophysics Data System (ADS)

Beamud, E.; Montes, M. J.; Santillana, S.; Nozal, F.; Marenssi, S.

2015-12-01

Seymour Island is located at 64 º S, close to the northeastern tip of the Antarctic Peninsula. This glacier-free island contains the southernmost exposures of the K/Pg boundary and it has the most complete record of the Paleogene in Antarctica. The base of the Paleogene is represented by the Early Paleocene shallow marine shelf deposits of the Marambio Group; which are unconformably overlain by the Late Paleocene to Late Eocene Seymour Island Group. The Marambio Group is divided into the quartz-rich silty sandstones and mudstones of the López de Bertodano Fm and the mudstones to quartz-rich sandstones of the Sobral Fm. The overlaying Seymour Island Group records the erosion and filling of incised valleys. This group is made up by the Cross Valley-Wiman, La Meseta and the uppermost new Submeseta Formations. Main regressive periods are evidenced by the erosional unconformities and their related time gaps at the base of these three Formations. The La Meseta and Submeseta Formations are composed by poorly consolidated marine sandstones and siltstones deposited in a shallow coastal (possibly estuarine) environment. Several biostratigraphic and isotopic studies have been conducted in the Seymour Island due to its extremely rich fossil record, and the age of the López de Bertodano Fm has been recently refined by magnetostratigraphy. However, the overlying Paleogene formations lack a reliable absolute continuous dating. To solve this problem, a composite magnetostratigraphic section spanning more than 1300 m from the K/Pg boundary up to the top of the Submeseta Fm was conducted, with an average sampling resolution of 3 m per site. Although many samples yielded weak results, a local magnetostratigraphy was obtained which has been correlated to the GPTS. The new derived ages range from Danian (~ 66 Ma) up to Priabonian (~ 34 Ma). These results have been integrated with previous litho-, bio- and isotopic data to build a new Paleogene chronostratigraphy for the Seymour Island.

Evidence of orbital forcing in lake-level fluctuations in the Middle Eocene oil shale-bearing lacustrine successions in the Mudurnu-Göynük Basin, NW Anatolia (Turkey)

NASA Astrophysics Data System (ADS)

Ocakoğlu, F.; Açıkalın, S.; Yılmaz, İ. Ö.; Şafak, Ü.; Gökçeoğlu, C.

2012-08-01

Mudurnu-Göynük basin of the Sakarya Zone in NW Anatolia comprises ca. 1500 m thick Paleocene-Eocene terrestrial to shallow marine succession overlying the Late Cretaceous deeper marine progradational fore-arc sediments. Formed in a foreland setting in relation to southerly situated İzmir-Ankara suture zone, this terrestrial succession (regionally known as Kızılçay group) comprises a thin (<200 m) oil shale-bearing lacustrine section with very good cyclic patterns that potentially serves the quantification of stratigraphy and enlightening the origin of cyclicities of various hierarchy. Our detailed facies analysis on three correlative measured sections showed that mudstone, oil shale and thinner limestone alternations characterize the relatively deeper part of the Eocene lake with probable marine intervention, while thicker limestone, coal, marl and occasional oil shale alternations typify the southern relatively freshwater shoal areas. These facies are frequently organized as meter-scale symmetric to asymmetric transgressive-regressive cycles. Spectral analysis of the mudstone beds and the cycles within the lacustrine succession strongly indicates the occurrence of full bands of Milankovitch with the shortest precession cycle (19 ka) at ca. 2.30 m. Our observations further revealed quite rhythmic thin couplets with estimated durations of 365-730 yr that might represent abrupt climatic changes during deposition. On the other hand, longer duration (ca. 1 Ma) of shoaling and deepening trends in the studied sections were attributed basically to varying subsidence due to tectonic loading in the southerly suture zone. Lastly, regarding the distribution of depositional environments we propose that the oil shale exploration activities should be carried out within a 20 km wide E-W running belt while the southern limits of this belt is more prolific for coal resources.

Clay Mineralogy, Authigenic Smectite Concentration, and Fault Weakening of the San Gregorio Fault; Moss Beach, California

NASA Astrophysics Data System (ADS)

Mazzoni, S.; Moore, J.; Bish, D. L.

2002-12-01

The apparently weak nature of the San Andreas fault system poses a fundamental geophysical question. The San Gregorio fault at Moss Beach, CA is an active splay of the right-lateral San Andreas fault zone and has a total offset of about 150 km. At Moss Beach, the San Gregorio fault offsets Pliocene sedimentary rocks and consists of a clay-rich gouge zone, eastern sandstone block, and western mudstone block. In the presence of fluids, smectite clays can swell and become very weak to shearing. We studied a profile of samples across the fault zone and wall rocks to determine if there is a concentration of smectite in the gouge zone and propose a possible formation mechanism. Samples were analyzed using standard quantitative X-ray diffraction methods and software recently developed at Los Alamos National Lab. XRD results show a high smectite/illite (weak clay/strong clay) ratio in the gouge (S/I ratio=2-4), lower in the mudstone (S/I ratio=2), and very low in the sandstone (S/I ratio=1). The variability of smectite/illite ratio in the gouge zone may be evidence of preferential alteration where developed shear planes undergo progressive smectite enrichment. The amount of illite layers in illite/smectites is 5-30%, indicating little illitization; therefore, these fault rocks have not undergone significant diagenesis above 100 degrees C and illite present must be largely detrital. Bulk mineralogy shows significant anti-correlation of smectite with feldspar, especially in the gouge, suggesting authigenic smectite generation from feldspar. Under scanning-electron microscope inspection, smectites have fibrous, grain coating growth fabrics, also suggesting smectite authigenesis. If in situ production of smectite via chemical alteration is possible in active faults, it could have significant implications for self-generated weakening of faults above the smectite-to-illite transition (<150 degrees C, or 5-7km).

Stress-sensitivity of The Hydraulic Properties of A Fault Gouge

NASA Astrophysics Data System (ADS)

Harrington, J. F.; Horseman, S. T.; Hama, K.; Metcalfe, R.

Tono Mine is located about 350 km southwest of Tokyo and is the site of the most extensive uranium deposits in Japan. The geological setting comprises Tertiary (Mizu- nami Group) sedimentary rocks overlying Cretaceous granitic basement rocks. In as- cending order, the sedimentary rocks are the Toki Lignite-bearing Formation (con- glomerate, interbedded sandstone and mudstone), the Akeyo Formation (tuffaceous sandstone) and the Oidawara Formation (siltstone and mudstone). The Tsukiyoshi Fault cuts through this sequence and is a reverse fault, dipping to the south at 60- 70 degrees, with a throw of about 30 metres. As part of its hydrogeological studies, JNC is evaluating the impact of the fault on groundwater flow in the Tertiary sedi- ments. A sample was taken from a borehole in the NATM Drift, where the fault zone contains gouge material with two clay-bearing layers around 2 to 3 cm thick, separated by a 10 to 20 cm thick layer of unconsolidated fine sandy material. The sample was obtained using a triple-tube core barrel fitted with a split sample tube and a diamond bit. A specimen was prepared and consolidated at successive effective stress levels of 2, 6 and 12 MPa. The plot of void ratio against the logarithm of effective stress was found to be sensibly linear with a negative slope, kappa, of 0.036 rising to 0.044 at higher stress levels. The evidence suggests that the gouge is overconsolidated. Hy- draulic conductivity and specific storage were also measured at each stress level using the constant flow rate method. Hydraulic conductivity was found to be strongly stress sensitive, falling from 1.84 x 10-12 m.s-1 at 2 MPa to 7.9 x 10-14 m.s-1 at 12 MPa. Specific storage values were analysed using the critical state soil mechanics approach assuming a stress-dependent pore compressibility. Reasonable agreement was found between the theoretical curve with kappa = 0.036 and the measured values.

BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

2005-05-10

The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structuremore » and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon expulsion commenced during the Early Cretaceous and continued into the Tertiary with peak expulsion occurring mainly during the Late Cretaceous.« less

Rock Formation and Cosmic Radiation Exposure Ages in Gale Crater Mudstones from the Mars Science Laboratory

NASA Astrophysics Data System (ADS)

Mahaffy, Paul; Farley, Ken; Malespin, Charles; Gellert, Ralph; Grotzinger, John

2014-05-01

The quadrupole mass spectrometer (QMS) in the Sample Analysis at Mars (SAM) suite of the Mars Science Laboratory (MSL) has been utilized to secure abundances of 3He, 21Ne, 36Ar, and 40Ar thermally evolved from the mudstone in the stratified Yellowknife Bay formation in Gale Crater. As reported by Farley et al. [1] these measurements of cosmogenic and radiogenic noble gases together with Cl and K abundances measured by MSL's alpha particle X-ray spectrometer enable a K-Ar rock formation age of 4.21+0.35 Ga to be established as well as a surface exposure age to cosmic radiation of 78+30 Ma. Understanding surface exposures to cosmic radiation is relevant to the MSL search for organic compounds since even the limited set of studies carried out, to date, indicate that even 10's to 100's of millions of years of near surface (1-3 meter) exposure may transform a significant fraction of the organic compounds exposed to this radiation [2,3,4]. Transformation of potential biosignatures and even loss of molecular structural information in compounds that could point to exogenous or endogenous sources suggests a new paradigm in the search for near surface organics that incorporates a search for the most recently exposed outcrops through erosional processes. The K-Ar rock formation age determination shows promise for more precise in situ measurements that may help calibrate the martian cratering record that currently relies on extrapolation from the lunar record with its ground truth chronology with returned samples. We will discuss the protocol for the in situ noble gas measurements secured with SAM and ongoing studies to optimize these measurements using the SAM testbed. References: [1] Farley, K.A.M Science Magazine, 342, (2013). [2] G. Kminek et al., Earth Planet Sc Lett 245, 1 (2006). [3] Dartnell, L.R., Biogeosciences 4, 545 (2007). [4] Pavlov, A. A., et al. Geophys Res Lett 39, 13202 (2012).

Preferred-rupture propagation to the hangingwall of the shallow part of the out-of-sequence thrust: Ishido Fault in Boso Peninsula, central Japan

NASA Astrophysics Data System (ADS)

Yamamoto, Y.; Fukuyama, M.; Ujiie, K.; Hirose, T.; Hamada, Y.; Kitamura, M.; Kamiya, N.

2016-12-01

Although earthquake ruptures in shallow portion of plate boundary have recently been identified (e.g. Tohoku, Nankai, etc.), their mechanisms why the shallow portion of plate boundary composed mainly of clay minerals can accumulate strain and make seismic slip are under controversial. An ancient out-of-sequence thrust which divided the early and late Miocene accretionary complexes in the Boso Peninsula, central Japan records rupture propagation to the shallow portion of accretionary prism (< 2 km). The fault core is composed of black-colored thin (<1 mm) pseudotachylite and fluidized fault gouge. The former is characterized by homogeneous glassy matrix including fragments of quartz/feldspar, submicron-sized Fe-rich spherules, and vesicles. Based on the mineralogy of the host rock and EDS analyses of matrices, origin of the pseudotachylite was apparently frictional melting of smectite containing Fe. Fe-rich spherules formed by rapid cooling of pseudotachylite. On the other hand, overturned fault-related drag fold developed in the footwall, within about 30 m. Although some Riedel sheared normal faults developed in the overturned footwall, no other brittle deformations were identified. These occurrences imply coexistence of low- and high-speed slips along the same thrust fault. The whole-rock major and trace elemental analyses using XRF and ICP-MS show that mudstone in the hangingwall has similar chemical composition to those of pseudotachylite and fluidized fault gouge with REE enriched patterns, whereas the footwall has different chemical characteristics with relatively flat REE pattern and low LOI. Therefore, the protolith of pseudotachylite and fluidized fault gouge is mudstone in the hangingwall. These data imply that rupture propagation preferably occurred in the hangingwall along the fault zone. The footwall was also deformed apparently during slow-slip deformation leading to formation of the overturn, whereas only the hangingwall, just side of the fault zone, slipped under high-speed shear.

Experimental Investigation on Dilation Mechanisms of Land-Facies Karamay Oil Sand Reservoirs under Water Injection

NASA Astrophysics Data System (ADS)

Lin, Botao; Jin, Yan; Pang, Huiwen; Cerato, Amy B.

2016-04-01

The success of steam-assisted gravity drainage (SAGD) is strongly dependent on the formation of a homogeneous and highly permeable zone in the land-facies Karamay oil sand reservoirs. To accomplish this, hydraulic fracturing is applied through controlled water injection to a pair of horizontal wells to create a dilation zone between the dual wells. The mechanical response of the reservoirs during this injection process, however, has remained unclear for the land-facies oil sand that has a loosely packed structure. This research conducted triaxial, permeability and scanning electron microscopy (SEM) tests on the field-collected oil sand samples. The tests evaluated the influences of the field temperature, confining stress and injection pressure on the dilation mechanisms as shear dilation and tensile parting during injection. To account for petrophysical heterogeneity, five reservoir rocks including regular oil sand, mud-rich oil sand, bitumen-rich oil sand, mudstone and sandstone were investigated. It was found that the permeability evolution in the oil sand samples subjected to shear dilation closely followed the porosity and microcrack evolutions in the shear bands. In contrast, the mudstone and sandstone samples developed distinct shear planes, which formed preferred permeation paths. Tensile parting expanded the pore space and increased the permeability of all the samples in various degrees. Based on this analysis, it is concluded that the range of injection propagation in the pay zone determines the overall quality of hydraulic fracturing, while the injection pressure must be carefully controlled. A region in a reservoir has little dilation upon injection if it remains unsaturated. Moreover, a cooling of the injected water can strengthen the dilation potential of a reservoir. Finally, it is suggested that the numerical modeling of water injection in the Karamay oil sand reservoirs must take into account the volumetric plastic strain in hydrostatic loading.

Fracture propagation during fluid injection experiments in shale at elevated confining pressures.

NASA Astrophysics Data System (ADS)

Chandler, Mike; Mecklenburgh, Julian; Rutter, Ernest; Fauchille, Anne-Laure; Taylor, Rochelle; Lee, Peter

2017-04-01

The use of hydraulic fracturing to recover shale-gas has focused attention upon the fundamental fracture properties of gas-bearing shales. Fracture propagation trajectories in these materials depend on the interaction between the anisotropic mechanical properties of the shale and the anisotropic in-situ stress field. However, there is a general paucity of available experimental data on their anisotropic mechanical, physical and fluid-flow properties, especially at elevated confining pressures. Here we report the results of laboratory-scale fluid injection experiments, for Whitby mudstone and Mancos shale (an interbedded silt and mudstone), as well as Pennant sandstone (a tight sandstone with permeability similar to shales), which is used an isotropic baseline and tight-gas sandstone analogue. Our injection experiments involved the pressurisation of a blind-ending central hole in an initially dry cylindrical sample. Pressurisation was conducted under constant volume-rate control, using silicone oils of various viscosities. The dependence of breakdown pressure on confining pressure was seen to be dependent on the rock strength, with the significantly stronger Pennant sandstone exhibiting much lower confining-pressure dependence of breakdown pressure than the weaker shales. In most experiments, a small drop in the injection pressure record was observed at what is taken to be fracture initiation, and in the Pennant sandstone this was accompanied by a small burst of acoustic energy. Breakdown was found to be rapid and uncontrollable after initiation if injection is continued, but can be limited to a slower (but still uncontrolled) rate by ceasing the injection of fluid after the breakdown initiation in experiments where it could be identified. A simplified 2-dimensional model for explaining these observations is presented in terms of the stress intensities at the tip of a pressurised crack. Additionally, we present a suite of supporting mechanical, flow and elastic measurements. Mechanical experiments include standard triaxial tests, pressure-dependent permeability experiments and fracture toughness determined using the double-torsion test. Elastic characterisation was determined through ultrasonic velocities determined using a cross-correlation method.

Reser­voir anisotropy and facies stratigraphic framework in the Pale­ocene Fort Union Formation, western Wind River basin

USGS Publications Warehouse

Flores, R.M.; Keighin, C.W.

1993-01-01

Investigation of reservoir anisotropy and lithofacies stratigraphic framework in the Fort Union Formation in western Wind River Basin, Wyoming focused on excellent surface exposures in the Shotgun Butte, Eagle Point, and Shotgun Bench synclines, and in the Merriam anticline area of the Wind River Reservation (Fig. 1). A complementary study was made of the formation in the Muddy Ridge and Pavillion gas fields, 8-10 mi to the southeast (Fig. 2). The Fort Union Formation is as much as 4000 ft thick in these areas, but thins to approximately 1800 ft toward the northern flank of the Little Dome anticline 3 mi south of Merriam anticline (Keefer and Troyer, 1964). The Fort Union Formation includes interbedded conglomerates, sandstones, siltstones, mudstones, coals, and carbonaceous shales (Fig. 3). The lower member of the Fort Union Formation is dominated by conglomerates and sandstones. The overlying Shotgun Member of the Fort Union Formation mainly consists of siltstones, mudstones, and carbonaceous shales, and coals, and subordinate sandstones. Contact between the lower member and Shotgun Member is gradational and marked by a topographic change from the resistant conglomerates and sandstones of the lower member to less resistant fine-grained strata of the Shotgun Member. In addition, the Shotgun Member commonly contains coal and carbonaceous shale beds, both in the surface and subsurface (Fig. 4). About 15-20 mi east of the study area the Waltman Shale Member of the Fort Union Formation pinches out at the contact between the lower member and Shotgun Member (Keefer and Johnson, this volume). The Waltman Shale Member, which consists of brown to gray silty and shaly claystones interbedded with sandstones, increases in thickness to as much as 3000 ft eastward into the basin center (Keefer, 1961; 1965). Thus, eastward, the Paleocene Fort Union Formation in ascending order, contains the lower member, Waltman Shale Member, and Shotgun Member. The Shotgun Member generally thins and interfingers with the Waltman Member.

Cenozoic Methane-Seep Faunas of the Caribbean Region

PubMed Central

Kiel, Steffen; Hansen, Bent T.

2015-01-01

We report new examples of Cenozoic cold-seep communities from Colombia, Cuba, the Dominican Republic, Trinidad, and Venezuela, and attempt to improve the stratigraphic dating of Cenozoic Caribbean seep communities using strontium isotope stratigraphy. Two seep faunas are distinguished in Barbados: the late Eocene mudstone-hosted ‘Joes River fauna’ consists mainly of large lucinid bivalves and tall abyssochrysoid gastropods, and the early Miocene carbonate-hosted ‘Bath Cliffs fauna’ containing the vesicomyid Pleurophopsis, the mytilid Bathymodiolus and small gastropods. Two new Oligocene seep communities from the Sinú River basin in Colombia consist of lucinid bivalves including Elongatolucina, thyasirid and solemyid bivalves, and Pleurophopsis. A new early Miocene seep community from Cuba includes Pleurophopsis and the large lucinid Meganodontia. Strontium isotope stratigraphy suggests an Eocene age for the Cuban Elmira asphalt mine seep community, making it the oldest in the Caribbean region. A new basal Pliocene seep fauna from the Dominican Republic is characterized by the large lucinid Anodontia (Pegophysema). In Trinidad we distinguish two types of seep faunas: the mudstone-hosted Godineau River fauna consisting mainly of lucinid bivalves, and the limestone-hosted Freeman’s Bay fauna consisting chiefly of Pleurophopsis, Bathymodiolus, and small gastropods; they are all dated as late Miocene. Four new seep communities of Oligocene to Miocene age are reported from Venezuela. They consist mainly of large globular lucinid bivalves including Meganodontia, and moderately sized vesicomyid bivalves. After the late Miocene many large and typical ‘Cenozoic’ lucinid genera disappeared from the Caribbean seeps and are today known only from the central Indo-Pacific Ocean. We speculate that the increasingly oligotrophic conditions in the Caribbean Sea after the closure of the Isthmus of Panama in the Pliocene may have been unfavorable for such large lucinids because they are only facultative chemosymbiotic and need to derive a significant proportion of their nutrition from suspended organic matter. PMID:26468887

Broadening the interpretive framework of deepwater deposits: 3D characterization of outcrop scale bedforms within supercritical dominated slope deposits of the Fish Creek-Vallecito Basin, Late-Miocene Gulf of California

NASA Astrophysics Data System (ADS)

West, L. M.; Steel, R.; Olariu, C.

2017-12-01

Study of seafloor bathymetry, numerical and physical modeling, and direct observation of turbidity currents increasingly suggests that sediment gravity flows over moderately steep basin slopes commonly reach Froude supercritical states. However, interpretation of supercritical features in deepwater outcrops remains limited in both quantity and scope, leaving stratigraphic qualities of supercritical deposits poorly understood. Slope turbidites on along steep margins of the early Gulf of California are exposed in seismic scale outcrops of the Late Miocene Lycium Member in the Fish Creek-Vallecito Basin of south-central California where they build 100s m-thick slopes. Measured sections, bedding orientation, and facies descriptions collected both for strike- and dip-oriented sections are combined with photogrammetric to characterize selected bedforms in three-dimensions. Analysis shows upflow accreting stacks of 10s of beds into a variety of bedforms with wavelengths and widths tens to hundreds of meters in scale and heights of 5-15 m. Beds have low-angle sinusoidal to sigmoidal down dip geometries and lens or lobate strike geometries. Bedding facies are dominated by 5-50 cm thick, normally graded, laminated sandstones capped by 1-3 cm bioturbated muds. Sandstones transition into interbedded sandstones and silty mudstones or 1-2 m thick silty mudstones. In places, Present also are incisional, steeply dipping backsets of 0.5-3 m-thick boulder-rich, amalgamated, structureless sandtones with abundant soft sediment deformation. that can transition downflow into arching, thinning, normally-graded sandstones. These bedforms are interpreted here as large-scale, long-lived supercritical deposits that represent preserved antidune and possibly cyclic steps bedforms or as-yet undefined bedforms incorporating by not bound by hydraulic jumps. This characterization provides new understanding of the nature of supercritical deposits and an important framework criteria for recognizing similar deposits elsewhere.

Cranial osteology of the ankylosaurian dinosaur formerly known as Minmi sp. (Ornithischia: Thyreophora) from the Lower Cretaceous Allaru Mudstone of Richmond, Queensland, Australia

PubMed Central

Molnar, Ralph E.; Carpenter, Kenneth; Witmer, Lawrence M.; Salisbury, Steven W.

2015-01-01

Minmi is the only known genus of ankylosaurian dinosaur from Australia. Seven specimens are known, all from the Lower Cretaceous of Queensland. Only two of these have been described in any detail: the holotype specimen Minmi paravertebra from the Bungil Formation near Roma, and a near complete skeleton from the Allaru Mudstone on Marathon Station near Richmond, preliminarily referred to a possible new species of Minmi. The Marathon specimen represents one of the world’s most complete ankylosaurian skeletons and the best-preserved dinosaurian fossil from eastern Gondwana. Moreover, among ankylosaurians, its skull is one of only a few in which the majority of sutures have not been obliterated by dermal ossifications or surface remodelling. Recent preparation of the Marathon specimen has revealed new details of the palate and narial regions, permitting a comprehensive description and thus providing new insights cranial osteology of a basal ankylosaurian. The skull has also undergone computed tomography, digital segmentation and 3D computer visualisation enabling the reconstruction of its nasal cavity and endocranium. The airways of the Marathon specimen are more complicated than non-ankylosaurian dinosaurs but less so than derived ankylosaurians. The cranial (brain) endocast is superficially similar to those of other ankylosaurians but is strongly divergent in many important respects. The inner ear is extremely large and unlike that of any dinosaur yet known. Based on a high number of diagnostic differences between the skull of the Marathon specimen and other ankylosaurians, we consider it prudent to assign this specimen to a new genus and species of ankylosaurian. Kunbarrasaurus ieversi gen. et sp. nov. represents the second genus of ankylosaurian from Australia and is characterised by an unusual melange of both primitive and derived characters, shedding new light on the evolution of the ankylosaurian skull. PMID:26664806

Three-dimensional characterization of microporosity and permeability in fault zones hosted in heterolithic succession

NASA Astrophysics Data System (ADS)

Riegel, H. B.; Zambrano, M.; Jablonska, D.; Emanuele, T.; Agosta, F.; Mattioni, L.; Rustichelli, A.

2017-12-01

The hydraulic properties of fault zones depend upon the individual contributions of the damage zone and the fault core. In the case of the damage zone, it is generally characterized by means of fracture analysis and modelling implementing multiple approaches, for instance the discrete fracture network model, the continuum model, and the channel network model. Conversely, the fault core is more difficult to characterize because it is normally composed of fine grain material generated by friction and wear. If the dimensions of the fault core allows it, the porosity and permeability are normally studied by means of laboratory analysis or in the other case by two dimensional microporosity analysis and in situ measurements of permeability (e.g. micro-permeameter). In this study, a combined approach consisting of fracture modeling, three-dimensional microporosity analysis, and computational fluid dynamics was applied to characterize the hydraulic properties of fault zones. The studied fault zones crosscut a well-cemented heterolithic succession (sandstone and mudstones) and may vary in terms of fault core thickness and composition, fracture properties, kinematics (normal or strike-slip), and displacement. These characteristics produce various splay and fault core behavior. The alternation of sandstone and mudstone layers is responsible for the concurrent occurrence of brittle (fractures) and ductile (clay smearing) deformation. When these alternating layers are faulted, they produce corresponding fault cores which act as conduits or barriers for fluid migration. When analyzing damage zones, accurate field and data acquisition and stochastic modeling was used to determine the hydraulic properties of the rock volume, in relation to the surrounding, undamaged host rock. In the fault cores, the three-dimensional pore network quantitative analysis based on X-ray microtomography images includes porosity, pore connectivity, and specific surface area. In addition, images were used to perform computational fluid simulation (Lattice-Boltzmann multi relaxation time method) and estimate the permeability. These results will be useful for understanding the deformation process and hydraulic properties across meter-scale damage zones.

Shoreface to estuarine sedimentation in the late Paleocene Matanomadh Formation, Kachchh, western India

NASA Astrophysics Data System (ADS)

Srivastava, V. K.; Singh, B. P.

2017-04-01

Late Paleocene sedimentation in the pericratonic Kachchh Basin marks the initial marine transgression during the Cenozoic era. A 17 m thick sandstone-dominated succession, known as the clastic member (CM) of the Matanomadh Formation (MF), is exposed sporadically in the basin. Three facies associations are reconstructed in the succession in three different sections. Facies association-1 contains matrix-supported pebbly conglomerate facies, horizontally-laminated sandstone-mudstone alternation facies, hummocky- and swaley cross-bedded sandstone facies, wave-rippled sandstone facies and climbing ripple cross-laminated sandstone facies. This facies association developed between shoreface and foreshore zone under the influence of storms on a barrier ridge. Facies association-2 contains sigmoidal cross-bedded sandstone facies, sandstone-mudstone alternation facies, flaser-bedded sandstone facies, herringbone cross-bedded sandstone facies and tangential cross-bedded sandstone facies. This facies association possessing tidal bundles and herringbone cross-beds developed on a tidal flat with strong tidal influence. Facies association-3 comprises pebbly sandstone facies, horizontally-bedded sandstone facies, tangential cross-bedded sandstone facies exhibiting reactivation surfaces and tabular cross-bedded sandstone facies. This facies association represents sedimentation in a river-dominated estuary and reactivation surfaces and herringbone cross-beds indicating tidal influence. The bipolar paleocurrent pattern changes to unipolar up-section because of the change in the depositional currents from tidal to fluvial. The sedimentation took place in an open coast similar to the Korean coast. The presence of neap-spring tidal rhythmites further suggests that a semidiurnal system similar to the modern day Indian Ocean was responsible for the sedimentation. Here, the overall sequence developed during the transgressive phase where barrier ridge succession is succeeded by the tidal flat succession and the latter, in turn, is succeeded by the estuarine succession. This study resolves the most debated issue of initial marine transgression in the Kachchh Basin during the Cenozoic.

Bioerosion by pit-forming, temperate-reef sea urchins: History, rates and broader implications

PubMed Central

Gibbs, Victoria K.; Duwan, Emily

2018-01-01

Sea urchins are dominant members of rocky temperate reefs around the world. They often occur in cavities within the rock, and fit so tightly, it is natural to assume they sculpted these “pits.” However, there are no experimental data demonstrating they bore pits. If they do, what are the rates and consequences of bioerosion to nearshore systems? We sampled purple sea urchins, Strongylocentrotus purpuratus, from sites with four rock types, three sedimentary (two sandstones and one mudstone) and one metamorphic (granite). A year-long experiment showed urchins excavated depressions on sedimentary rocks in just months. The rate of pit formation varied with rock type and ranged from <5 yr for medium-grain sandstone to >100 yr for granite. In the field, there were differences in pit size and shapes of the urchins (height:diameter ratio). The pits were shallow and urchins flatter at the granite site, and the pits were deeper and urchins taller at the sedimentary sites. Although overall pit sizes were larger on mudstone than on sandstone, urchin size accounted for this difference. A second, short-term experiment, showed the primary mechanism for bioerosion was ingestion of the substratum. This experiment eliminated potential confounding factors of the year-long experiment and yielded higher bioerosion rates. Given the high densities of urchins, large amounts of rock can be converted to sediment over short time periods. Urchins on sandstone can excavate as much as 11.4 kg m-2 yr-1. On a broader geographic scale, sediment production can exceed 100 t ha-1 yr-1, and across their range, their combined bioerosion is comparable to the sediment load of many rivers. The phase shift between urchin barrens and kelp bed habitats in the North Pacific is controlled by the trophic cascade of sea otters. By limiting urchin populations, these apex predators also may indirectly control a substantial component of coastal rates of bioerosion. PMID:29466357

Cenozoic Methane-Seep Faunas of the Caribbean Region.

PubMed

Kiel, Steffen; Hansen, Bent T

2015-01-01

We report new examples of Cenozoic cold-seep communities from Colombia, Cuba, the Dominican Republic, Trinidad, and Venezuela, and attempt to improve the stratigraphic dating of Cenozoic Caribbean seep communities using strontium isotope stratigraphy. Two seep faunas are distinguished in Barbados: the late Eocene mudstone-hosted 'Joes River fauna' consists mainly of large lucinid bivalves and tall abyssochrysoid gastropods, and the early Miocene carbonate-hosted 'Bath Cliffs fauna' containing the vesicomyid Pleurophopsis, the mytilid Bathymodiolus and small gastropods. Two new Oligocene seep communities from the Sinú River basin in Colombia consist of lucinid bivalves including Elongatolucina, thyasirid and solemyid bivalves, and Pleurophopsis. A new early Miocene seep community from Cuba includes Pleurophopsis and the large lucinid Meganodontia. Strontium isotope stratigraphy suggests an Eocene age for the Cuban Elmira asphalt mine seep community, making it the oldest in the Caribbean region. A new basal Pliocene seep fauna from the Dominican Republic is characterized by the large lucinid Anodontia (Pegophysema). In Trinidad we distinguish two types of seep faunas: the mudstone-hosted Godineau River fauna consisting mainly of lucinid bivalves, and the limestone-hosted Freeman's Bay fauna consisting chiefly of Pleurophopsis, Bathymodiolus, and small gastropods; they are all dated as late Miocene. Four new seep communities of Oligocene to Miocene age are reported from Venezuela. They consist mainly of large globular lucinid bivalves including Meganodontia, and moderately sized vesicomyid bivalves. After the late Miocene many large and typical 'Cenozoic' lucinid genera disappeared from the Caribbean seeps and are today known only from the central Indo-Pacific Ocean. We speculate that the increasingly oligotrophic conditions in the Caribbean Sea after the closure of the Isthmus of Panama in the Pliocene may have been unfavorable for such large lucinids because they are only facultative chemosymbiotic and need to derive a significant proportion of their nutrition from suspended organic matter.

Searching for Ancient Lakebeds in Ladon Basin, Mars and Implications for Future Exploration

NASA Astrophysics Data System (ADS)

Colón, A. M.; Miranda, C.; Milliken, R.

2017-12-01

It is well known from terrestrial studies that clay-rich rocks, and lacustrine mudstones in particular, are efficient at trapping, binding, and preserving organic matter through geologic time. This has also been demonstrated on Mars, where the Curiosity rover has detected organics in ancient mudstones in Gale crater. A number of other potential ancient lake sites have been proposed as landing sties for the Mars 2020 rover, including regions within the Ladon Basin and Valles system. In this study we map of the distribution of clay deposits in the Uzboi-Morava-Ladon (ULM) System, a system thought to have been a series of lakes interconnected by channels, and assess how these hydrous minerals relate to topography, adjacent fluvial networks, and the overall stratigraphy of basin deposits. We use CTX images and near-IR spectral reflectance data from the Mars Reconnaissance Orbiter CRISM instrument to independently map morphological and mineralogical features within Ladon. We find a number of occurrences of stratified, light-toned outcrops within the basin, but individual outcrops are small even at the scale of CTX images and are concentrated in several locations in the basin. Some light-toned outcrops are associated with clay minerals, but in general the light-toned appearance appears to be a poor proxy for clay distribution. CRISM data reveal that some clay-bearing regions are visually indistinct from adjacent clay-poor terrains. Some of the best examples of stratified, clay-bearing rocks are found in Ladon Valles, where they occur in terraces. In general, the stratigraphic, topographic, and morphologic evidence do not preclude a lacustrine origin, but there is no diagnostic evidence to support this interpretation either. The clay-bearing and light-toned deposits within Ladon basin may instead reflect deposition in an alluvial/fluvial system that post-dates the peak period of inferred lacustrine activity in the ULM system.

Stratigraphic analysis of the Paleocene Beaufort Formation, Lenoir and Craven Counties, North Carolina

DOE Office of Scientific and Technical Information (OSTI.GOV)

McLaurin, B.T.

The Beaufort Formation (BF) occurs in the inner coastal plain in a fault-bounded basin associated with the Graingers wrench zone. The unit disconformably overlies the Cretaceous Peedee Fm., and is overlain disconformably by either the Eocene Castle Hayne Limestone or younger units. Although the BF is only known to crop out along the western margin of the basin, approximately 36 core-holes penetrate the unit in the basin. Core-hole analysis indicates that the BF rapidly varies in thickness from 0--85 feet over a distance of several hundred feet. The BF is divided into the lower Jericho Run Member of Danian agemore » and an upper unnamed member of Thanetian age. The Jericho Run Member (JRM) is principally a light-gray to gray siliceous mudstone which in some places contains interbeds of very fine to coarse glauconitic quartz sand. The mudstone is often burrowed and can contain as much as 40% quartz and 15% glauconite usually concentrated in thin laminae or burrows. The JRM is the most widespread member of the BF obtaining a maximum thickness of 53 feet. Where present, it always lies disconformably on the Peedee Formation and is either overlain disconformably by the unnamed member or younger sediments. Planktic foraminifera assigned to the P1 zone indicate that the JRM is Danian in age. The unnamed member is characterized by a gray-green to dark green glauconitic sand with minor thin sandy carbonates. When the JRM is absent, the unnamed member disconformably overlies the Peedee Formation with the contact marked by a thin phosphate-pebble conglomerate. The unnamed member is not as widely distributed as the Danian member, but its thickness in some areas exceeds 78 feet. The unnamed member contains up to 10% more glauconite and larger amounts of phosphatic material than the JRM. Planktic foraminifera (P4) and calcareous nannofossils (NP6) indicate that the unnamed member is Thanetian in age.« less

Cranial osteology of the ankylosaurian dinosaur formerly known as Minmi sp. (Ornithischia: Thyreophora) from the Lower Cretaceous Allaru Mudstone of Richmond, Queensland, Australia.

PubMed

Leahey, Lucy G; Molnar, Ralph E; Carpenter, Kenneth; Witmer, Lawrence M; Salisbury, Steven W

2015-01-01

Minmi is the only known genus of ankylosaurian dinosaur from Australia. Seven specimens are known, all from the Lower Cretaceous of Queensland. Only two of these have been described in any detail: the holotype specimen Minmi paravertebra from the Bungil Formation near Roma, and a near complete skeleton from the Allaru Mudstone on Marathon Station near Richmond, preliminarily referred to a possible new species of Minmi. The Marathon specimen represents one of the world's most complete ankylosaurian skeletons and the best-preserved dinosaurian fossil from eastern Gondwana. Moreover, among ankylosaurians, its skull is one of only a few in which the majority of sutures have not been obliterated by dermal ossifications or surface remodelling. Recent preparation of the Marathon specimen has revealed new details of the palate and narial regions, permitting a comprehensive description and thus providing new insights cranial osteology of a basal ankylosaurian. The skull has also undergone computed tomography, digital segmentation and 3D computer visualisation enabling the reconstruction of its nasal cavity and endocranium. The airways of the Marathon specimen are more complicated than non-ankylosaurian dinosaurs but less so than derived ankylosaurians. The cranial (brain) endocast is superficially similar to those of other ankylosaurians but is strongly divergent in many important respects. The inner ear is extremely large and unlike that of any dinosaur yet known. Based on a high number of diagnostic differences between the skull of the Marathon specimen and other ankylosaurians, we consider it prudent to assign this specimen to a new genus and species of ankylosaurian. Kunbarrasaurus ieversi gen. et sp. nov. represents the second genus of ankylosaurian from Australia and is characterised by an unusual melange of both primitive and derived characters, shedding new light on the evolution of the ankylosaurian skull.

Cover sequences at the northern margin of the Antongil Craton, NE Madagascar

USGS Publications Warehouse

Bauer, W.; Walsh, G.J.; De Waele, B.; Thomas, Ronald J.; Horstwood, M.S.A.; Bracciali, L.; Schofield, D.I.; Wollenberg, U.; Lidke, D.J.; Rasaona, I.T.; Rabarimanana, M.H.

2011-01-01

The island of Madagascar is a collage of Precambrian, generally high-grade metamorphic basement domains, that are locally overlain by unmetamorphosed sedimentary rocks and poorly understood low-grade metasediments. In the Antalaha area of NE Madagascar, two distinct cover sequences rest on high-grade metamorphic and igneous basement rocks of the Archaean Antongil craton and the Neoproterozoic Bemarivo belt. The older of these two cover sequences, the Andrarona Group, consists of low-grade metasedimentary rocks. The younger sequence, the newly defined Ampohafana Formation, consists of unmetamorphosed sedimentary rocks. The Andrarona Group rests on Neoarchaean granites and monzogranites of the Antongil craton and consists of a basal metagreywacke, thick quartzites and an upper sequence of sericite-chlorite meta-mudstones, meta-sandstones and a volcaniclastic meta-sandstone. The depositional age of the volcaniclastic meta-sandstone is constrained in age by U–Pb laser-ablation ICP-MS analyses of euhedral zircons to 1875 ± 8 Ma (2σ). Detrital zircons of Archaean and Palaeoproterozoic age represent an input from the Antongil craton and a newly defined Palaeoproterozoic igneous unit, the Masindray tonalite, which underlies the Andrarona Group, and yielded a U–Pb zircon age of 2355 ± 11 Ma (2σ), thus constraining the maximum age of deposition of the basal part of the Andrarona Group. The Andrarona Group shows a low-grade metamorphic overprint in the area near Antalaha; illite crystallinity values scatter around 0.17°Δ2Θ CuKα, which is within the epizone. The Ampohafana Formation consists of undeformed, polymict conglomerate, cross-bedded sandstone, and red mudstone. An illite crystallinity value of >0.25°Δ2Θ CuKα obtained from the rocks is typical of the diagenetic zone. Occurrences of rhyodacite pebbles in the Ampohafana Formation and the intrusion of a basaltic dyke suggest a deposition in a WSW-ENE-trending graben system during the opening of the Indian Ocean in the Upper Cretaceous, that was characterized by extensive rhyolitic to basaltic magmatism along Madagascar's eastern coast.

The thermal and chemical evolution of hydrothermal vent fluids in shale hosted massive sulphide (SHMS) systems from the MacMillan Pass district (Yukon, Canada)

NASA Astrophysics Data System (ADS)

Magnall, J. M.; Gleeson, S. A.; Blamey, N. J. F.; Paradis, S.; Luo, Y.

2016-11-01

At Macmillan Pass (YT, Canada), the hydrothermal vent complexes beneath two shale-hosted massive sulphide (SHMS) deposits (Tom, Jason) are well preserved within Late Devonian strata. These deposits provide a unique opportunity to constrain key geochemical parameters (temperature, salinity, pH, fO2, ΣS) that are critical for metal transport and deposition in SHMS systems, and to evaluate the interaction between hydrothermal fluids and the mudstone host rock. This has been achieved using a combination of detailed petrography, isotopic techniques (δ34S, δ13C and δ18O values), carbonate rare earth element analysis (LA-ICP-MS), fluid inclusion analysis (microthermometry, gas analysis via incremental crush fast scan mass spectrometry), and thermodynamic modelling. Two main paragenetic stages are preserved in both vent complexes: Stage 1 comprises pervasive ankerite alteration of the organic-rich mudstone host rock and crosscutting stockwork ankerite veining (±pyrobitumen, pyrite and quartz) and; Stage 2 consists of main stage massive sulphide (galena-pyrrhotite-pyrite ± chalcopyrite-sphalerite) and siderite (±quartz and barytocalcite) mineralisation. Co-variation of δ18O and δ13C values in ankerite can be described by temperature dependent fractionation and fluid rock interaction. Together with fluid inclusion microthermometry, this provides evidence of a steep thermal gradient (from 300 to ∼100 °C) over approximately 15 m stratigraphic depth, temporally and spatially constrained within the paragenesis of both vent complexes and developed under shallow lithostatic (<1 km; 250 bars) to hydrostatic (<400 m; 40 bars) conditions. There is evidence of mixing between diagenetic and hydrothermal fluids recorded in chondrite-normalised rare earth element (REE) profiles of ankerite and siderite. Middle REE enrichments and superchondritic Y/Ho ratios (>28), characteristic of diagenetic fluids, are coupled with positive europium anomalies and variable light REE depletion, which are more consistent with chloride complexation in hot (>250 °C) hydrothermal fluids. In this shallow sub-seafloor setting, thermal alteration of organic carbon in the immature, chemically reactive mudstones also had an important role in the evolution of fluid chemistry. Reduced sulphur generation via thermochemical reduction of Late Devonian seawater sulphate produced positive δ34S values in sulphide minerals (+7.5‰ to +19.5‰), coupled with a suite of volatile components (CO2, CH4, C1-C4 hydrocarbons, N2) trapped in Stage 2 quartz. Many of these geochemical features developed during the final stages of fluid ascent, in a system where the fluid cooled close to the site of mineralisation. Using this information, we have modelled the metal transporting capacity of the deep hydrothermal fluid, which even at modest salinities (6 wt.% NaCl) was high (≫100 ppm Pb, Zn), owing to the combined effects of high temperature and low pH (⩽4.5). Therefore in SHMS systems, enhanced geothermal gradients and rapid fluid ascent (with minimal fluid cooling) are considered to be the most important factors for transporting high concentrations of base metals to the site of mineralisation.

Quantification of in situ pore pressure and stress in regions of low frequency earthquakes and anomalously low seismic velocity at the Nankai Trough

NASA Astrophysics Data System (ADS)

Kitajima, H.; Saffer, D. M.

2012-12-01

Recent seismic reflection and ocean bottom seismometer (OBS) studies reveal broad regions of low seismic velocity along the megathrust plate boundary of the Nankai subduction zone offshore SW Japan. These low velocity zones (LVZ's) extend to ~55 km from the trench, corresponding to depths of >~10 km below sea floor. Elevated pore pressure has been invoked as one potential cause of both the LVZ's and very low frequency earthquakes (VLFE) in the outer forearc. Here, we estimate the in-situ pore fluid pressure and stress state within these LVZ's by combining P-wave velocities (Vp) obtained from seismic reflection and OBS data with well-constrained empirical relations between (1) P-wave velocity and porosity; and (2) porosity and effective mean and differential stresses, defined by triaxial deformation tests on drill core samples of the incoming oceanic sediment. We used cores of Lower Shikoku Basin (LSB) hemipelagic mudstone (322-C0011B-19R-5, initial porosity of 43%), and Middle Shikoku Basin (MSB) tuffaceous sandstone (333-C0011D-51X-2, initial porosity of 46%) that have been recovered from IODP Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) Site C0011 (~20 km seaward from the deformation front). Samples were loaded under a range of different stress paths including isotropic loading, triaxial compression, and triaxial extension. During the tests, all pressures, axial displacement, and pore volume change were continuously monitored; and ultrasonic velocity and permeability were measured at regular intervals. The relationship between Vp and porosity for LSB mudstone is independent of stress path, and is well fit by an empirical function derived by Hoffman and Tobin [2004] for LSB sediments sampled by drilling along Muroto transect, located ~150 km southwest of the NanTroSEIZE study area. The MSB sandstone exhibits slightly higher P-wave velocity than LSB mudstone at a given porosity. Based on our experimental results, and assuming that the sediments in the LVZ's are at shear failure defined by a critical state stress condition, we estimate that effective vertical stress in the LVZ ranges from 15 MPa at 13 km landward of the trench, to 41 MPa at a distance of 55 km. The maximum horizontal effective stress ranges from 41-124 MPa over this region. Excess pore fluid pressure ranges from 15-81 MPa, corresponding to modified pore pressure ratios, λ* of 0.44-0.73. If LVZ is composed dominantly of sandstones, both the effective vertical and horizontal stresses would be lower, and the excess pore pressure would be higher, with pore pressure ratios λ* = 0.31-0.90. Our results suggest that the sediments have been loaded under poorly drained conditions, and that pore fluids support ≥~53-91 % of the overburden stress along the base of the accretionary wedge across the outer forearc. The low effective stress should lead to a mechanically weak plate boundary, and is spatially correlated with well-located low-frequency earthquakes in the outer accretionary wedge. The heterogeneous distribution of inferred pore pressure also suggests that fluid sources and drainage are localized and possibly transient.

Diagenetic evolution and stable isotopes of Lower Permian platform marginal carbonates (Trogkofel Limestone, Carnic Alps, Austria)

NASA Astrophysics Data System (ADS)

Schaffhauser, Maria; Krainer, Karl; Sanders, Diethard Gerald; Spötl, Christoph

2010-05-01

The Trogkofel massif in the Carnic Alps, Austria/Italy, consists of a succession up to 400 m thick of limestones deposited along a platform margin (Trogkofel Limestone; Artinskian). The top of the Trogkofel Limestone is erosively overlain by the Tarvis Breccia. Up-section, the Trogkofel Limestone consists of well-bedded shallow-water bioclastic limestones with intercalated mud mounds, overlain by thick-bedded to unbedded limestones (bioclastic grainstones, packstones, rudstones) and cementstone mounds rich in phylloid algae, Tubiphytes, bryozoans and Archaeolithoporella. In the cementstone mounds, bioclasts are coated by thick fringes and botryoids of fibrous calcite, and of calcite spar that probably represents calcitized aragonite. Primary and intrinsic pores are filled by microbialite, and/or by mudstone to bioclastic wackestone. Shallow-water bioclastic grainstones are cemented by isopachous fringes of fibrous calcite, or by sparry calcite. Throughout the succession, evidence for meteoric-vadose dissolution is present. The Trogkofel Limestone is riddled by palaeokarstic dykes and caverns filled by (a) isopachous cement fringes up to a few decimetres thick, and/or (b) by red, geopetally-laminated lime mudstone to bio-lithoclastic wackestone; geopetal laminasets locally display convolute bedding. Small dissolution cavities are filled by grey internal sediment, or by crystal silt. Brecciated internal sediments overlain by unbrecciated, geopetally-laminated infillings record deformation during or after deposition of the Trogkofel Limestone. Polyphase fractures cemented by calcite may cross-cut both internal sediments and host rock. In the Trogkofel Limestone, local dolomitization is common. Replacement dolomites show a wide range of shapes and fabrics, including: (a) fine-crystalline anhedral xenotopic fabric, (b) coarse-crystalline subhedral to euhedral, hypidiotopic to idiotopic fabric of turbid or optically zoned crystals, and (c) saddle dolomite as replacement and filling of fractures. Closely below the erosional surface at the top of the Trogkofel Limestone, the dolomite is characterized by vuggy porosity. The Tarvis Breccia, which represents coarse alluvial fan deposits, in turn, is thick-bedded, poorly sorted, typically clast-supported, and consists of angular lithoclasts embedded in a matrix of former lime mudstone. Both, matrix as well as lithoclasts, are dolomitized. Various types of cement (isopachous, botryoidal, microbialite, calcite spar), karstic cavity fills (isopachous cements, internal sediments), and replacement dolomites of the Trogkofel section, as well as of the Tarvis Breccia were analysed for their stable isotopic composition. δ18O and δ13C data produced so far allow to differentiate between replacement dolomites and saddle dolomite of the Trogkofel Limestone and the Tarvis Breccia. Saddle dolomite shows the most depleted oxygen isotope values, suggesting formation during relatively high temperatures. Carbon isotope values are invariably positive in all dolomite types indicating lacking influence of organic diagenesis on the alkalinity of the deep-burial pore water. Matrix dolomite from the Tarvis Breccia shows slightly positive δ18O values. Calcite cements show a wide range in δ18O values (ca. -1 to -7 permil VPDB), which overlaps the composition of unaltered brachiopod shells (ca. -3 permil VPDB). Oxygen isotope values of calcite cements reveal a trend towards depleted δ18O values. This trend is reflecting most likely increasing temperature.

Surveying Clay Mineral Diversity in the Murray Formation, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Bristow, T.F.; Blake, D. F..; Vaniman, D. T.; Chipera, S. J.; Rampe, E. B.; Grotzinger, J. P.; McAdam, A. C.; Ming, D. W..; Morrison, S. M.; Yen, A. S.;

Microstructure and permeability of the Whitby Mudstone (UK) as an analogue for the Posidonia shale (NL)

NASA Astrophysics Data System (ADS)

Houben, Maartje; Barnhoorn, Auke; Drury, Martyn; Peach, Colin; Spiers, Christopher

2015-04-01

In order to make gas productivity from a shale economically interesting we should find ways to better connect the in-situ pore network to the natural occurring and mechanical induced fractures in the rock. When trying to improve gas productivity a first aim is to understand gas storage and gas flow potential through the rock by investigating the microstructure and measure the matrix porosity and permeability of the unfractured shales. Using a combination of methods we have characterized the porosity and permeability of the Jet Dogger section of the Whitby Mudstone Formation (UK), which we use as an analogue for the Posidonia Shale (NL). The Posidonia shale is a possible unconventional source for gas in Northern Europe. A combination of Precision Ion Polishing (PIPS) and Scanning Electron Microscopy (SEM) has been used to investigate the microstructure and the pores. Microstructurally the circa 8 meter thick Jet section of the Whitby Mudstone Formation can be subdivided into a fossil rich (>15 %) top half with an organic matter content of 7-10% and a sub-mm laminated (alternating clay-rich, carbonate-rich, not necessarily fossils, layers) lower half were the organic matter content varies from 0.3-16%. In addition, any possible flow in the rock has to go through the fine-grained clay matrix (all grains < 2 μm) due to the fact that all larger grains are completely surround by this matrix. Visible PIPS-SEM porosity (pore diameter > 100 nm) is in the order of 0.5-2.5% and is not connected in 2D. Furthermore, overall more than 40% of the visible porosity is present within the clay matrix (sometimes even up to 80%). Porosity and pore size distributions for pores with smaller diameters (2 < diameter < 100 nm) were determined using Ar and N2 gas adsorption. The adsorption porosity was in the order of 1-5%, were we found 1-2.5% porosity for the top half of the section and 2-5% porosity for the bottom half. Ar gas permeability of the samples was measured on 1-inch diameter cores using Ar-gas-permeametry with a pressure step of 0.2 MPa. The permeability measured was in the order of 2•10-19 - 1•10-17 m2 at a confining pressure of 0.8 MPa. The top half of the section (less porous) showed a slightly lower permeability (2•10-19 -3•10-18 m2) than the lower half of the Jet Dogger section (1•10-18 - 1•10-17m2). The PIPS-SEM porosity is apparently unconnected on the scale used for imaging and any flow through these rocks has to go through the clay matrix. A connected network of nano-scale pores connected to the micro-scale (PIPS-SEM) pores should be present because of the fact that we measured a through flow of gas. Relationships between the permeability and Ar-porosity and permeability and microstructure were, however, not systematic.

Acidic Fluids Across Mars: Detections of Magnesium-Nickel Sulfates

NASA Technical Reports Server (NTRS)

Yen, A. S.; Ming, D. W.; Gellert, R.; Mittlefehldt, D. W.; Rampe, E. B.; Vaniman, D. T.; Thompson, L. M.; Morris, R. V.; Clark, B. C.; VanBommel, S. J.

2017-01-01

Calcium, magnesium and ferric iron sulfates have been detected by the instrument suites on the Mars rovers. A subset of the magnesium sulfates show clear associations with nickel. These associations indicate Ni(2+) co-precipitation with or substitution for Mg(2+) from sulfate-saturated solutions. Nickel is ex-tracted from primary rocks almost exclusively at pH values less than 6, constraining the formation of these Mg-Ni sulfates to mildly to strongly acidic conditions. There is clear evidence for aqueous alteration at the rim of Endeavour Crater (Meridiani Planum), in the Murray formation mudstone (Gale Crater), and near Home Plate (Gusev Crater). The discovery of Mg-Ni sulfates at these locations indicates a history of fluid-rock interactions at low pH.

Stable isotopic evidence for fluid flow and fluid/rock interaction during thrust faulting in Pumpkin Valley shale and Rome Formation, east Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Butler, B.K.; Haase, C.S.

1989-08-01

The Pumpkin Valley Shale and the underlying Rome Formation form the lower portions of the Copper Creek and White Oak Mountain thrust sheets in east Tennessee. The Pumpkin Valley Shale consists of shale and mudstone with subordinate amounts of interbedded siltstone. The Rome Formation is composed predominantly of sandstone with interbedded shale and siltstone toward the base of the formation. The percentage of illite increases from 20% to over 80% of the bulk clay mineralogy toward the base of the section. Porosity is occluded by quartz, phyllosilicate, and calcite cements. Both formations contain calcite-filled and, less commonly, quartz-filled Alleghenian fracturesmore » and joints.« less

Evolved Gas Analyses of the Murray Formation in Gale Crater, Mars: Results of the Curiosity Rover's Sample Analysis at Mars (SAM) Instrument

NASA Technical Reports Server (NTRS)

Sutter, B.; McAdam, A. C.; Rampe, E. B.; Thompson, L. M.; Ming, D. W.; Mahaffy, P. R.; Navarro-Gonzalez, R.; Stern, J. C.; Eigenbrode, J. L.; Archer, P. D.

2017-01-01

The Sample Analysis at Mars (SAM) instrument aboard the Mars Science Laboratory rover has analyzed 13 samples from Gale Crater. All SAM-evolved gas analyses have yielded a multitude of volatiles (e.g., H2O, SO2, H2S, CO2, CO, NO, O2, HCl) [1- 6]. The objectives of this work are to 1) Characterize recent evolved SO2, CO2, O2, and NO gas traces of the Murray formation mudstone, 2) Constrain sediment mineralogy/composition based on SAM evolved gas analysis (SAM-EGA), and 3) Discuss the implications of these results relative to understanding the geological history of Gale Crater.

Chondrites isp. Indicating Late Paleozoic Atmospheric Anoxia in Eastern Peninsular India

PubMed Central

Bhattacharya, Biplab; Banerjee, Sudipto

2014-01-01

Rhythmic sandstone-mudstone-coal succession of the Barakar Formation (early Permian) manifests a transition from lower braided-fluvial to upper tide-wave influenced, estuarine setting. Monospecific assemblage of marine trace fossil Chondrites isp. in contemporaneous claystone beds in the upper Barakar succession from two Gondwana basins (namely, the Raniganj Basin and the Talchir Basin) in eastern peninsular India signifies predominant marine incursion during end early Permian. Monospecific Chondrites ichnoassemblage in different sedimentary horizons in geographically wide apart (~400 km) areas demarcates multiple short-spanned phases of anoxia in eastern India. Such anoxia is interpreted as intermittent falls in oxygen level in an overall decreasing atmospheric oxygenation within the late Paleozoic global oxygen-carbon dioxide fluctuations. PMID:24616628

The Imprint of Atmospheric Evolution in the D/H of Hesperian Clay Minerals on Mars

NASA Technical Reports Server (NTRS)

Mahaffy, P. R.; Webster, C. R.; Stern, J. C.; Brunner, A. E.; Atreya, S. K.; Conrad, P. G.; Domagal-Goldman, S.; Eigenbrode, J. L.; Flesch, G. J.; Christensen, L. E.;

Redox stratification of an ancient lake in Gale crater, Mars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hurowitz, Joel A.; Grotzinger, John P.; Fischer, Woodward W.

In 2012, NASA’s Curiosity rover landed on Mars to assess its potential as a habitat for past life and investigate the paleoclimate record preserved by sedimentary rocks inside the ~150-kilometer-diameter Gale impact crater. Geological reconstructions from Curiosity rover data have revealed an ancient, habitable lake environment fed by rivers draining into the crater. We synthesize geochemical and mineralogical data from lake-bed mudstones collected during the first 1300 martian solar days of rover operations in Gale. We present evidence for lake redox stratification, established by depth-dependent variations in atmospheric oxidant and dissolved-solute concentrations. Paleoclimate proxy data indicate that a transition frommore » colder to warmer climate conditions is preserved in the stratigraphy. Lastly, a late phase of geochemical modification by saline fluids is recognized.« less

Redox stratification of an ancient lake in Gale crater, Mars

DOE PAGES

Hurowitz, Joel A.; Grotzinger, John P.; Fischer, Woodward W.; ...

2017-06-02

In 2012, NASA’s Curiosity rover landed on Mars to assess its potential as a habitat for past life and investigate the paleoclimate record preserved by sedimentary rocks inside the ~150-kilometer-diameter Gale impact crater. Geological reconstructions from Curiosity rover data have revealed an ancient, habitable lake environment fed by rivers draining into the crater. We synthesize geochemical and mineralogical data from lake-bed mudstones collected during the first 1300 martian solar days of rover operations in Gale. We present evidence for lake redox stratification, established by depth-dependent variations in atmospheric oxidant and dissolved-solute concentrations. Paleoclimate proxy data indicate that a transition frommore » colder to warmer climate conditions is preserved in the stratigraphy. Lastly, a late phase of geochemical modification by saline fluids is recognized.« less

Marias Pass, Contact Zone of Two Martian Rock Units

NASA Image and Video Library

2015-12-17

This view from the Mast Camera (Mastcam) in NASA's Curiosity Mars rover shows the "Marias Pass" area where a lower and older geological unit of mudstone -- the pale zone in the center of the image -- lies in contact with an overlying geological unit of sandstone. Just before Curiosity reached Marias Pass, the rover's laser-firing Chemistry and Camera (ChemCam) instrument examined a rock found to be rich in silica, a mineral-forming chemical. This scene combines several images taken on May 22, 2015, during the 992nd Martian day, or sol, of Curiosity's work on Mars. The scene is presented with a color adjustment that approximates white balancing, to resemble how the rocks and sand would appear under daytime lighting conditions on Earth. http://photojournal.jpl.nasa.gov/catalog/?IDNumber=pia20174

Terahertz lens made out of natural stone.

PubMed

Han, Daehoon; Lee, Kanghee; Lim, Jongseok; Hong, Sei Sun; Kim, Young Kie; Ahn, Jaewook

2013-12-20

Terahertz (THz) time-domain spectroscopy probes the optical properties of naturally occurring solid aggregates of minerals, or stones, in the THz frequency range. Refractive index and extinction coefficient measurement reveals that most natural stones, including mudstone, sandstone, granite, tuff, gneiss, diorite, slate, marble, and dolomite, are fairly transparent for THz frequency waves. Dolomite in particular exhibits a nearly uniform refractive index of 2.7 over the broad frequency range from 0.1 to 1 THz. The high index of refraction allows flexibility in lens designing with a shorter accessible focal length or a thinner lens with a given focal length. Good agreement between the experiment and calculation for the THz beam profile confirms that dolomite has high homogeneity as a lens material, suggesting the possibility of using natural stones for THz optical elements.

A model for Cryogenian iron formation

NASA Astrophysics Data System (ADS)

Cox, Grant M.; Halverson, Galen P.; Poirier, André; Le Heron, Daniel; Strauss, Justin V.; Stevenson, Ross

2016-01-01

The Neoproterozoic Tatonduk (Alaska) and Holowilena (South Australia) iron formations share many characteristics including their broadly coeval (Sturtian) ages, intimate association with glaciogenic sediments, and mineralogy. We show that these shared characteristics extend to their neodymium (εNd) and iron isotope (δ56Fe) systematics. In both regions δ56Fe values display a distinct up-section trend to isotopically heavier values, while εNd values are primitive and similar to non-ferruginous mudstones within these successions. The δ56Fe profiles are consistent with oxidation of ferruginous waters during marine transgression, and the εNd values imply that much of this iron was sourced from the leaching of continental margin sediments largely derived from continental flood basalts. Rare earth element data indicate a secondary hydrothermal source for this iron.

Geology and ground water in north-central Santa Cruz County, California

USGS Publications Warehouse

Johnson, Michael J.

1980-01-01

North-central Santa Cruz County is underlain mainly by folded sedimentary rocks of Tertiary and Cretaceous age that have been highly fractured by movements in the San Andreas fault system. Ground water is stored in fractures within shale and mudstone formations and in intergranular pore spaces within fine- to very fine-grained sandstone and siltstone formations. Fewer than 10% of the wells yield more than 15 gallons of water per minute. The water in most wells is moderately hard to very hard, is generally of a sodium bicarbonate or calcium bicarbonate type, and commonly has excessive concentrations of iron or manganese. Of the many geologic units in the study area, only the Purisima Formation of Pliocene age has the potential to sustain well yields greater than 100 gallons per minute. (USGS)

The Jeanie Point complex revisited

USGS Publications Warehouse

Dumoulin, Julie A.; Miller, Martha L.

1984-01-01

The so-called Jeanie Point complex is a distinctive package of rocks within the Orca Group, a Tertiary turbidite sequence. The rocks crop out on the southeast coast of Montague Island, Prince William Sound, approximately 3 km northeast of Jeanie Point (loc. 7, fig. 44). These rocks consist dominantly of fine-grained limestone and lesser amounts of siliceous limestone, chert, tuff, mudstone, argillite, and sandstone (fig. 47). The Jeanie Point rocks also differ from those typical of the Orca Group in their fold style. Thus, the Orca Group of the area is isoclinally folded on a large scale (tens to hundreds of meters), whereas the Jeanie Point rocks are tightly folded on a 1- to 3- m-wavelength scale (differences in rock competency may be responsible for this variation in fold style).

Paleogene Vertebrate Paleontology, Geology and Remote Sensing in the Wind River Basin

NASA Technical Reports Server (NTRS)

Stucky, R. K.; Krishtalka, L.

1985-01-01

Biostratigraphic and lithostratigraphic studies were used to correlate different events in the geologic evolution of the northeastern part of the Wind River Basin and have suggested several conclusions. Laterally equivalent exposures of the Lysite member from Cedar Ridge to Bridger Creek show a gradation in lithology from interbedded boulder conglomerates and sandstones to interbedded lenticular sandstones and mudstones to interbedded carbonaceous shales, coals and tabular sandstones. This gradation suggests a shift from alluvial fan to braided stream to paludal or lacustrine sedimentary environments during the late early Eocene. The Lysite and Lost Cabin members of the Wind River Formation are in fault contact in the Bridger Creek area and may intertongue to the east along Cedar Ridge. Ways in which remote sensing could be used in these studies are discussed.

Permeability anisotropy in marine mudstones in the Nankai Trough, SW Japan: Implications for hypothesized lateral fluid flow and chemical transport outboard of the trench

NASA Astrophysics Data System (ADS)

Saffer, D. M.; McKiernan, A. W.; Skarbek, R. M.

2008-12-01

Characterizing dewatering pathways and chemical fluxes near and outboard of subduction trenches is important toward understanding early sediment dewatering and devolatilization. Quantifying fluid flow rates also constrains the hydraulic gradients driving flow, and thus ultimately hold implications for pore pressure distribution and fault mechanical strength. We focus on the well-studied Nankai Trough offshore SW Japan, where drilling has sampled the sedimentary section at several boreholes from ~11 km outboard of the trench to 3 km landward. At these drillsites, &δ37Cl data and correlation of distinct extrema in downhole chloride profiles have been interpreted to reflect substantial horizontal fluid flow to >10 km outboard of the trench within the ~400 m-thick, homogeneous Lower Shikoku Basin (LSB) facies mudstone. The estimated horizontal velocities are 13 ± 5 cm yr-1; the flow is presumably driven by loading during subduction, and mediated by either permeable conduits or strong anisotropy in permeability. However, the pressure gradients and sediment permeabilities necessary for such flow have not been quantified. Here, we address this problem by combining (1) laboratory measurement of horizontal and vertical sediment permeability from a combination of constant rate of strain (CRS) consolidation tests and flow-through measurements on core samples; and (2) numerical models of fluid flow within a cross section perpendicular to the trench. In our models, we assign hydrostatic pressure at the top and seaward edges, a no-flow condition at the base of the sediments, and pore pressures ranging from 40%-100% of lithostatic at the arcward model boundary. We assign sediment permeability on the basis of our laboratory measurements, and evaluate the possible role of thin permeable conduits as well as strong anisotropy in the incoming section. Our laboratory results define a systematic log-linear relationship between sediment permeability and porosity within the LSB mudstones. The overall variation in permeability for our suite of samples is ~1 order of magnitude. Notably, horizontal permeabilities fall within the range of measured vertical permeabilities, and indicate no significant anisotropy. Using laboratory-derived permeability values, simulated horizontal flow rates range from 10-4 to 10-1 cm yr-1, and decrease dramatically with distance seaward of the trench. With permeability anisotropy of 1000x (i.e. kh = 1000kv), simulated flow rates peak at 3 cm yr-1 at the trench, and decrease to 3x10-1 cm yr-1 by 10 km seaward. These flow rates are substantially lower than those inferred from the geochemical data and also lower than the plate convergence rate of 4 cm yr-1, such that net transport of fluids out of the subduction zone is not likely. If discrete conduits are included in our models, permeabilities of ~10-114m2 are required to sustain the inferred flow rates. However, no potential conduits in the LSB were observed by coring or logging- while-drilling. In contrast, net egress of fluids - and associated chemical transport and pressure translation - are plausible at margins where continuous permeable strata are subducting. Overall, our results highlight a major discrepancy between constraints on fluid flow derived from physical hydrogeology and inferences from geochemical data. In this case, we suggest that the chemical signals may be affected by other processes such as in situ clay dehydration and down-section chemical variations.

Collision of the Tacheng block with the Mayile-Barleik-Tangbale accretionary complex in Western Junggar, NW China: Implication for Early-Middle Paleozoic architecture of the western Altaids

NASA Astrophysics Data System (ADS)

Zhang, Ji'en; Xiao, Wenjiao; Luo, Jun; Chen, Yichao; Windley, Brian F.; Song, Dongfang; Han, Chunming; Safonova, Inna

2018-06-01

Western Junggar in NW China, located to the southeast of the Boshchekul-Chingiz (BC) Range and to the north of the Chu-Balkhash-Yili microcontinent (CBY), played a key role in the architectural development of the western Altaids. However, the mutual tectonic relationships have been poorly constrained. In this paper, we present detailed mapping, field structural geology, and geochemical data from the Barleik-Mayile-Tangbale Complex (BMTC) in Western Junggar. The Complex is divisible into Zones I, II and III, which are mainly composed of Cambrian-Silurian rocks. Zone I contains pillow lava, siliceous shale, chert, coral-bearing limestone, sandstone and purple mudstone. Zone II consists of basaltic lava, siliceous shale, chert, sandstone and mudstone. Zone III is characterized by basalt, chert, sandstone and mudstone. These rocks represent imbricated ocean plate stratigraphy, which have been either tectonically juxtaposed by thrusting or form a mélange with a block-in-matrix structure. All these relationships suggest that the BMTC is an Early-Middle Paleozoic accretionary complex in the eastern extension of the BC Range. These Early Paleozoic oceanic rocks were thrust onto Silurian sediments forming imbricate thrust stacks that are unconformably overlain by Devonian limestone, conglomerate and sandstone containing fossils of brachiopoda, crinoidea, bryozoa, and plant stems and leaves. The tectonic vergence of overturned folds in cherts, drag-related curved cleavages and σ-type structures on the main thrust surface suggests top-to-the-NW transport. Moreover, the positive εNd(t) values of volcanic rocks from the Tacan-1 drill-core, and the positive εHf(t) values and post-Cambrian ages of detrital zircons from Silurian and Devonian strata to the south of the Tacheng block indicate that its basement is a depleted and juvenile lithosphere. And there was a radial outward transition from coral-bearing shallow marine (shelf) to deep ocean (pelagic) environments, and from OIB/E-MORB to N-MORB lava geochemistry away from the Tacheng block. Comparisons with published data suggest that these positive isotopic values, stratigraphic, structural and geochemical relationships can be best understood as an analogue of the relationships between the Ontong Java oceanic plateau and the Pacific oceanic crust. Therefore we propose that the basement of the Tacheng block was an Early Paleozoic oceanic plateau. The southern part of the Tacheng block was an accretionary complex and the northern part was an oceanic basin in the Early Paleozoic, the configuration of which is similar to that of the present Ontong Java oceanic plateau situated on the Pacific oceanic crust, and its accretion into the Solomon accretionary complex. The presence of Ordovician SSZ-type ophiolites, early Paleozoic blueschist and Silurian SSZ-type intrusions in the BMTC, and Early-Middle Paleozoic continental arc-related intrusive rocks in the northern margin of the CBY provide further corroboration of a former subduction zone between the southern West Junggar and the northern margin of the CBY. Furthermore, consideration of the fact that the Kokchetav-North Tianshan range was collaged to the southern margin of the CBY in the Ordovician-Devonian indicates that both ranges were amalgamated synchronously with the CBY constructing the Early-Middle Paleozoic architecture of western Altaids.

Geologic map of the Pinedale quadrangle, McKinley County, New Mexico

USGS Publications Warehouse

Robertson, Jacques F.

2005-01-01

The 1:24,000-scale geologic map of the Pinedale 7.5' quadrangle lies in the western part of the Grants uranium mineral belt, which was mapped and studied under a cooperative agreement between the USGS and the U.S. Department of Energy. A spectacular panoramic view of the southern half of the Pinedale quadrangle is obtained looking northward from Interstate Highway 40, particularly from the New Mexico State travelers' rest stop near the Shell Oil Company's Ciniza Refinery, 28.5 kilometers (17.8 miles) east of Gallup. A west-trending escarpment, 200 meters high, of massive red sandstone, rises above a broad valley, its continuity broken only by a few deep and picturesque canyons in the western half of the quadrangle. The escarpment is formed by the eolian Entrada Sandstone of Late Jurassic age. The Entrada unconformably overlies the Chinle Formation of Late Triassic age, which occupies the valley below. The Chinle Formation consists of cherty mottled limestone and mudstone of the Owl Rock Member and underlying, poorly consolidated, red to purple fluvial siltstone, mudstone, and sandstone beds of the Petrified Forest Member. The pinyon- and juniper-covered bench that tops the escarpment is underlain by the Todilto Limestone. A quarry operation, located just north of the Indian community of Iyanbito in the southwestern part of the quadrangle, produces crushed limestone aggregate for highway construction and railroad ballast. Beyond the escarpment to the north and rising prominently above it, is the northwest-trending Fallen Timber Ridge. Near the west side of the quadrangle lie the peaks of Midget Mesa, and Mesa Butte, the latter of which has the highest altitude in the area at 2,635 meters (8,030 feet) above sea level. The prominences are capped by buff-colored resistant beds of the Dakota Sandstone of Late Cretaceous age, containing some interbedded coal. These beds unconformably overlie the uranium-bearing Morrison Formation, which consists of red, green, and gray shale, orange feldspathic sandstone, and green tuffaceous mudstone, deposited in ancient lakes, alluvial fans, and rivers during the Upper Jurassic Period. Thick, crossbedded, white beds of the Cow Springs Sandstone, derived from ancient windblown desert sands, underlie the Morrison. In the northern part of the quadrangle, the Dakota Sandstone is overlain by gray Mancos Shale and yellowish-gray Two Wells and Gallup Sandstones that were deposited in Late Cretaceous seas. Unconsolidated deposits of Quaternary age are found throughout the quadrangle in talus, slope wash, fans, valley alluviums, pediments, and as windblown sands in dunes and blanket deposits. The strata conform to the regional dip of about three degrees to north, except where they are down-folded some 200 meters along the Pinedale monocline, whose limbs follow a sinuous west-northwest trend across the northern half of the quadrangle. The monocline is beautifully exposed at Pinedale, where it shows as much as 20 degrees dip on the pine-studded bare rock slope of the Two Wells Sandstone. A north-plunging broad anticline and accompanying syncline is developed in the east-central part of the quadrangle but dies out against the monocline. A minor fault, with barely 3 meters of vertical displacement, extends several kilometers westward across the Todilto Limestone bench. A large landslide mass, 1.5 kilometers long by 0.7 kilometers wide occurs in the Mancos Shale west of Pinedale. Exploration drilling for uranium in the Morrison Formation has been extensive in the quadrangle, particularly north of the monocline, which adjoins the Old Church Rock mine area, west northwest of the quadrangle.

Ductile and Brittle Neogene Deformation of Late Permian Orthogneiss in the Northern Ailao Shan-Red River Shear Zone: View from the Xuelong Shan Block

NASA Astrophysics Data System (ADS)

Wintsch, R. P.; Yi, D.; Yi, K.; Wang, Q. F.; Wang, G. H.

2014-12-01

The orthogneisses in the core of the Xuelong Shan block are surrounded by ductile and then brittle fault rocks. This lens-shape block is in fault contact with Triassic marbles on the eastern margin and Jurassic-Cretaceous mudstones on the western margin. The rocks in the core of the Xuelong Shan block contain multiply foliated feldspathic orthogneisses with local amphibolites, largely overprinted by protomylonitic deformation. Foliation strengthens to the east to become mylonites and ultramylonites, with a 30 m wide zone of loosely cemented fault breccia adjacent to brittlely faulted Triassic marbles. In contrast, the rocks to the west are dominated by brittle deformation, with mylonites becoming cataclasites and then breccias facing the mudstones to the east. Well-foliated phyllonites are locally present within the cataclasites. Early S1 gneissosity striking ENE are recognized only in the interior protomylonite. In the east, the dominate mylonitic S2 foliation strikes 340° with a moderate dip to the east, and an L2 mineral stretching lineation plunges gently north. However, in the west S2 cleavage is transposed into a NNW trending schistosity that dips steeply to the ENE, with down-dip mineral stretching lineations. Whole rock chemistry indicates a granitic to granodioritic protolith for all the rocks including the ultramylonites, but also suggests the progressive loss of alkalis with increasing deformation. Trace element compositions show these rocks lie in the volcanic arc/syn-collisional granite field. U-Pb SHRIMP ages show an Early Triassic age for these granite, with possible Middle Permian inheritance in some cores. These ages are consistent with the period of the closure of the northern Paleo-Tethys ocean. Metamorphic rim ages of ~ 30 Ma record a small amount of zircon dissolution/precipitation probably associated with the Oligocene ductile deformation that produced the upper greenschist facies mylonites. These results support the geologic history of the ASRRSZ based on data obtained in the southern Diancang Shan block. Permian granitoids were intruded and ductily deformed in the Early Triassic. The left lateral shearing that brought these blocks to the surface was delayed until the Neogene extrusion of the Indochina block.

Distribution and tectonic implications of Cretaceous-Quaternary sedimentary facies in Solomon Islands

NASA Astrophysics Data System (ADS)

Turner, C. C.; Hughes, G. W.

1982-08-01

Sedimentary rocks of the Solomon Islands-Bougainville Arc are described in terms of nine widespread facies. Four facies associations are recognised by grouping facies which developed in broadly similar sedimentary environments. A marine pelagic association of Early Cretaceous to Miocene rocks comprises three facies. Facies Al: Early Cretaceous siliceous mudstone, found only on Malaita, is interpreted as deep marine siliceous ooze. Facies A2: Early Cretaceous to Eocene limestone with chert, overlies the siliceous mudstone facies, and is widespread in the central and eastern Solomons. It represents lithified calcareous ooze. Facies A3: Oligocene to Miocene calcisiltite with thin tuffaceous beds, overlies Facies A2 in most areas, and also occurs in the western Solomons. This represents similar, but less lithified calcareous ooze, and the deposits of periodic andesitic volcanism. An open marine detrital association of Oligocene to Recent age occurs throughout the Solomons. This comprises two facies. Facies B1 is variably calcareous siltstone, of hemipelagic origin; and Facies B2 consists of volcanogenic clastic deposits, laid down from submarine mass flows. A third association, of shallow marine carbonates, ranges in age from Late Oligocene to Recent. Facies C1 is biohermal limestone, and Facies C2 is biostromal calcarenite. The fourth association comprises areally restricted Pliocene to Recent paralic detrital deposits. Facies D1 includes nearshore clastic sediments, and Facies D2 comprises alluvial sands and gravels. Pre-Oligocene pelagic sediments were deposited contemporaneously with, and subsequent to, the extrusion of oceanic tholeiite. Island arc volcanism commenced along the length of the Solomons during the Oligocene, and greatly influenced sedimentation. Thick volcaniclastic sequences were deposited from submarine mass flows, and shallow marine carbonates accumulated locally. Fine grained graded tuffaceous beds within the marine pelagic association are interpreted as products of this volcanism, suggesting that the Santa Isabel-Malaita-Ulawa area, where these beds are prevalent, was relatively close to the main Solomons chain at this time. A subduction zone may have dipped towards the northeast beneath this volcanic chain. Pliocene to Pleistocene calcalkaline volcanism and tectonism resulted in the emergence of all large islands and led to deposition of clastic and carbonate facies in paralic, shallow and deep marine environments.

Provenance of Conglomerates within a Late Cretaceous Turbidite Channel System on the North American Margin: the Rosario Formation, Baja California, Mexico

NASA Astrophysics Data System (ADS)

Dos Santos, Thisiane; Kneller, Benjamin; Morton, Andrew; Armelenti, Garibaldi; Pantopoulos, George; De Ros, Luiz Fernando

2017-04-01

The Rosario Formation forms part of the Peninsular Ranges forearc basin complex, which crops out discontinuously along the Pacific coast of the Baja California Peninsula, Mexico. This study concerns the upper, deep marine part of the Rosario Formation , which includes several slope channel systems, one of these, the San Fernando channel systems consists of five channel complex sets (CCS1 to CCS5), each characterized by three filling stages. Stage I consists of predominantly clast­ and matrix-supported conglomerates, with subordinate medium to coarse grained sandstones. Stage II consists of units of clast-supported conglomerates with subordinate medium to coarse-grained sandstones, separated by mainly thinly-bedded turbidites (intercalation of thin beds of fine-grained sandstones and mudstones). Stage III consists mainly of hemipelagic mudstones. The main objective of this research is to determine source area and to compare the coarse fraction and finer fraction (fragments <2 cm) from conglomerates of each channel set, combining provenance methodology such as heavy minerals, clast counting, geochemistry, bulk petrography and U/Pb in detrital zircons by LA-ICPMS and SHRIMP. The heavy minerals assembly identified were Ca amphibole, epidote, clinozoisite, titanite, garnet, tourmaline, apatite, rutile and zircon, among them amphiboles are by far the most abundant detrital mineral. Clast counting and petrographic characterization showed that the pebble fraction of the conglomerates is constituted at least 18 different, and the majority being composed by pyroclastic, porphyritic volcanic and sandstone rocks. Bulk quantification indicates that the main provenance tectonic mode of the fine fraction of the conglomerates can be interpreted as dissected magmatic arc, with subordinate uplifted basement and recycled orogenic contributions. The preliminary conclusion is that the sedimentary supply to the Rosario Formation was mostly derived from volcanic and plutonic rocks of the Upper Peninsular Ranges Arc complex known as the Alisitos Arc, which follows the western margin of the Peninsular Ranges batholith, as well as from older magmatic arc, and from recycling of sedimentary/metasedimentary terrains.

A Hydraulic Tomography Experiment in Fractured Sedimentary Rocks, Newark Basin, New Jersey, USA

NASA Astrophysics Data System (ADS)

Tiedeman, C. R.; Barrash, W.; Thrash, C. J.; Johnson, C. D.

2015-12-01

Hydraulic tomography was performed in July 2015 in contaminated fractured mudstone beds at the former Naval Air Warfare Center (NAWC) in the Newark Basin near Trenton, NJ using seven existing wells. The spatial arrangement of wells (in a circle of 9 m radius with one central well), the use of packers to divide the wells into multiple monitoring intervals, and the deployment of fiber optic pressure transducers enabled collection of a hydraulic tomography dataset comprising high-resolution drawdown observations at an unprecedented level of spatial detail for fractured rocks. The experiment involved 45-minute cross-hole aquifer tests, conducted by pumping from a given packer-isolated well interval and continuously monitoring drawdowns in all other well intervals. The collective set of drawdown data from all tests and intervals displays a wide range of behavior suggestive of highly heterogeneous hydraulic conductivity (K) within the tested volume, such as: drawdown curves for different well intervals crossing one another on drawdown-time plots; variable drawdown curve shapes, including linear segments on log-log plots; variable order and magnitude of time-lag and/or drawdown for intervals of a given well in response to pumping from similar fractures or stratigraphic units in different wells; and variable groupings of wells and intervals showing similar responses for different pumping tests. The observed behavior is consistent with previous testing at the NAWC indicating that K within and across individual mudstone beds can vary by orders of magnitude over scales of meters. Preliminary assessment of the drawdown data together with a rich set of geophysical logs suggests an initial conceptual model that includes densely distributed fractures of moderate K at the shallowest depths of the tested volume, connected high-K bedding-plane-parting fractures at intermediate depths, and sparse low-K fractures in the deeper rocks. Future work will involve tomographic inversion of the data to estimate the K distribution at a scale of ~1 m3 in the upper two-thirds of the investigated volume where observation density is greatest.

Uranium potential of the Burro Canyon Formation in western Colorado

USGS Publications Warehouse

Craig, L.C.

1982-01-01

The Burro Canyon Formation of Early Cretaceous age overlies the Morrison Formation (Late Jurassic) and underlies the Dakota Sandstone (Late Cretaceous) over most of southeastern Utah and southwestern Colorado. It consists mainly of alternating beds of fluvial sandstone and overbank mudstone with sandstone dominating in the lower part of the formation and mudstone in the upper part. At the outcrop, the sandstones in the formation exhibit almost all the characteristics that are considered favorable for the occurrence of sandstone-type uranium deposits, but only a few small deposits have been discovered in the Colorado-Utah area. The major deficiency of the Burro Canyon in these outcrop areas is the absence of a reductant such as carbonaceous debris, humic or humate materials, or pyrite. Reductants were probably removed during a period of extensive oxidation at the time of deposition and during a subsequent erosional episode prior to deposition of the Dakota Sandstone. The formation reaches a lobate, inexactly located eastern margin that extends from near Meeker, Colorado, southward through the Piceance basin to near Aztec, New Mexico, in the northwestern part of the San Juan Basin. Along much of this distance, the formation is in the subsurface and has been penetrated by only a few drill holes. Along this eastern margin, the lobes project eastward where fluvial distributary streams built minor alluvial fans of relatively high-energy deposits out from the main axis of Burro Canyon stream deposition. The lower and distal reaches of these lobes may have survived the period of post depositional erosion and oxidation in a reduced condition because of low relief and the protection of a high water table. If so, the peripheral and distal parts of these lobes may have retained the precipitants necessary to form a uranium deposit. Two of the lobes extend into the southwest margin of the Piceance Basin and are considered the possible location of uranium deposits. Two additional lobes extend into the northwestern part of the San Juan Basin but have not been evaluated in this study.

Early Permian post-glacial bivalve faunas of the Itararé Group, Paraná Basin, Brazil: Paleoecology and biocorrelations with South American intraplate basins

NASA Astrophysics Data System (ADS)

Neves, Jacqueline Peixoto; Anelli, Luiz Eduardo; Simões, Marcello Guimarães

2014-07-01

The uppermost portion of the Taciba Formation, Itararé Group, Paraná Basin, Brazil, records a succession of depositional environments tied to the demise of late Paleozoic glaciation. In the study area, Teixeira Soares county, state of Paraná, the unit is dominated by massive to laminated diamictites with inclusions of sandstones and other coarse-grained lithotypes, representing re-sedimented material in proximal areas. These are succeeded by fine to medium-grained sandstones with tabular cross-stratification and pectinid-rich shell pavements, interpreted as nearshore deposits. Above this, laminated and intensely bioturbated siltstones with closed articulated bivalve shells are recorded, probably deposited in inner shelf settings. Fine to very fine sandstones/siltstones with hummocky cross-stratification and intercalated mudstones, including infaunal in situ shells, are interpreted as stacked storm deposits, generated in distal shoreface environments. These are succeeded by fossil-poor, massive to laminated siltstones/mudstones or gray shales (=Passinho shale) that are inferred to be outer shelf deposits, generated in organic-rich, oxygen-deficient muddy bottoms. In this sedimentary succession dropstones or ice-rafted debris are missing and locally the Passinho shale marks the maximum flooding surface of the Itararé succession. These are capped by the fluvio-deltaic deposits of the Rio Bonito Formation (Sakmarian-Artinskian). Six facies-controlled, bivalve-dominated assemblages are recognized, representing faunal associations that thrived in aerobic to extreme dysaerobic bottoms along a nearshore-offshore trend. Within these assemblages, nineteen bivalve species (three of them new) were recorded and described in detail. The presence of Myonia argentinensis (Harrington), Atomodesma (Aphanaia) orbirugata (Harrington) and Heteropecten paranaensis Neves et al. suggests correlation with bivalve assemblages of the Eurydesma-bearing Bonete Formation, Pillahuincó Group, Sauce Grande-Colorado Basin (Buenos Aires Province), Argentina, indicating a possible Asselian age for this diverse post-glacial bivalve fauna. Despite that, typical members of the icehouse-style Eurydesma-Trigonotreta biota (stricto sensu) have not yet been found in the studied bivalve assemblages.

Possible Signs of Ancient Drying in Martian Rock

NASA Image and Video Library

2017-01-17

A grid of small polygons on the Martian rock surface near the right edge of this view may have originated as cracks in drying mud more than 3 billion years ago. Multiple images from the Mast Camera (Mastcam) on NASA's Curiosity Mars rover were combined for this mosaic of a block called "Squid Cove" and its immediate surroundings. The location is within an exposure of Murray formation mudstone on lower Mount Sharp inside Gale Crater. Mastcam's right-eye camera, which has a telephoto lens, took the component images of this view on Dec. 20, 2016, during the 1,555th Martian day, or sol, of Curiosity's work on Mars. The rover drove farther uphill on Gale Crater before the possible mud cracks were detected in the Mastcam images. This possible evidence about the area's ancient environment prompted the rover mission to backtrack for closer inspection of Squid Cove and nearby target rocks. This scene is presented with a color adjustment that approximates white balancing, to resemble how the rocks and sand would appear under daytime lighting conditions on Earth. The polygons are about half an inch to 1 inch (about 1 to 2 centimeters) across. Figure 1 includes a scale bar of 30 centimeters (12 inches). The polygons are outlined by ridges. This could result from a three-step process after cracks form due to drying: Wind-blown sediments accumulate in the open cracks. Later, these sediments and the dried mud become rock under the pressure of multiple younger layers that accumulate on top of them. Most recently, after the overlying layers were eroded away by wind, the vein-filling material resists erosion better than the once-muddy material, so the pattern that began as cracks appears as ridges. Mud cracks would be evidence of a drying interval between wetter periods that supported lakes in the area. Curiosity has found evidence of ancient lakes in older, lower-lying rock layers and also in younger mudstone that is above Squid Cove. http://photojournal.jpl.nasa.gov/catalog/PIA21263

Stratigraphic distribution, taphonomy and paleoenvironments of Spinicaudata in the Triassic and Jurassic of the Paraná Basin

NASA Astrophysics Data System (ADS)

Jenisch, Alan Gregory; Lehn, Ilana; Gallego, Oscar Florencio; Monferran, Mateo Daniel; Horodyski, Rodrigo Scalise; Faccini, Ubiratan Ferrucio

2017-12-01

Due to the chitino-phosphatic nature of Spinicaudata conchostracan exoskeletons, their carapaces exhibit a low preservational potential compared to other bivalve groups. However, the recent studies point towards the increased tolerance of the carapace against the physical processes. Due to this peculiar characteristic, conchostracan carapace have been utilized as precise temporal markers in estimating stratigraphic and taphonomic parameters. The same characteristic also makes the spinicaudatans useful in evaluating the depositional processes and environments. The present work aims at providing a paleoenvironmental and stratigraphic analysis of conchostracans (Spinicaudata) from the Triassic-Jurassic of the Paraná Basin (Santa Maria and Caturrita formations) in terms of the sedimentary facies analysis, depositional system characterization, and analysis of the taphonomic signatures of the fossiliferous horizons within these formations. The results from the taphonomic study delineates the presence of 4 distinct fossil assemblages based on the causative mechanism and fundamental characteristics of the fossil concentrations: two taphonomic assemblages in the laminated mudstone beds deposited from the decanting fine-grained sediments in floodplains; the sandstone beds with plane parallel laminations and dune- and ripple-cross-stratifications deposited from the flooding-related overflow in the floodplains; and the association of laminated mudstone and massive sandstone beds deposited as the river mouth bars. The results show that the taphonomic signatures, e.g., closed valves, may indicate the various patterns of autochthony and allochthony. In the fine-grained floodplain assemblages, the high degree of preservation can be attributed to autochthony in the conchostracans, whereas the preservational condition of floodplain sandstone sheet and mouth bar assemblages point toward parautochthony and even allochthony. Therefore, the preservational quality of conchostracan exoskeletons is likely a function of parameters, e.g., the transport duration, the distance from life position, and the magnitude of events causing their final burial. Within the observed species, the recognition of Eustheria minuta in the stratigraphic level of the Passo das Tropas creek corroborates an age for these deposits between the late Middle Triassic and early Upper Triassic. The presence of a new form, likely related to the family Fushunograptidae in sediments from the Caturrita Formation, suggests a Jurassic age for these deposits.

Geomorphic Drainage Capture Recorded by Oxygen Isotopes of Green River Formation Lacustrine Mudstone, Eocene, Wyoming

NASA Astrophysics Data System (ADS)

Doebbert, A. C.; Booth, A. L.; Carroll, A.; Chamberlain, C.; Rhodes, M.

2005-12-01

The isotopic composition of cement and other meteoric precipitates are increasingly being used to interpret orogenic uplift histories, based on the relationship between altitude and rainwater δ18O. However, other variables such as changing regional drainage patterns may also affect the downstream composition of surface waters, especially when multiple drainages commingle in a lake. The Green River Formation contains some of the best documented lacustrine deposits in the world, making it ideal for examining such issues. Carbonate mudstone in balanced-fill facies of the lower LaClede Bed averages 3.41‰ (PDB), and records a deep, saline to brackish lake that fluctuated near its sill. In contrast, overfilled facies of the upper LaClede Bed record a freshwater lake, and δ18O reaches values as low as -9.72‰. This transition occurred shortly after deposition of the Analcite Tuff at 48.94 ± 0.12 Ma (Smith et al., 2003), and was geologically abrupt. Based on 40Ar/39Ar-calibrated sediment accumulation rates it required no more than 200-300 ky. An almost identical transition occurs in two cores separated by about 30 km, making local diagenesis an unlikely cause. The magnitude of δ18O change is similar to that in some uplift studies, but its rapidity virtually excludes uplift as a controlling mechanism. Instead, we propose that both the change in sedimentation and the sharp decrease in δ18O are the result of a drainage capture event. The addition of a new drainage to the basin may have adjusted isotopic values in two ways: by introducing runoff with relatively low δ18O, and by decreasing residence time (and therefore evaporation) of lake water. Decreasing 87Sr/86Sr across the same transition suggests that the newly added waters may have been sourced from rising volcanic topography to the north in the Absaroka province. Although this rising topography allows for the possibility of some uplift component, the rate of change in lacustrine δ18O is consistent with geomorphic processes rather than uplift. These results indicate the need for considerable caution when examining uplift records from other ancient lake deposits.

Hydrothermal Signatures at Gale Crater, Mars, and Possible In-Situ Formation of Tridymite

NASA Astrophysics Data System (ADS)

Yen, A. S.; Morris, R. V.; Gellert, R.; Berger, J. A.; Sutter, B.; Downs, R. T.; Bristow, T.; Treiman, A. H.; Ming, D. W.; Achilles, C.; Blake, D. F.; Chipera, S.; Clark, B. C.; Craig, P.; Morrison, S. M.; Rampe, E. B.; Schmidt, M. E.; Schwenzer, S. P.; Thompson, L. M.; Vaniman, D.

2017-12-01

The occurrence of tridymite, a high temperature SiO2 polymorph definitively identified by the Curiosity rover in the Buckskin mudstone sample at Gale crater, Mars, has been attributed to detrital accumulation of rhyolitic material. This interpretation of a detrital origin is revisited in light of the observation that the tridymite-hosting sediments appear to have interacted with the same fluids that produced alteration halos in the overlying sandstone. The alteration halos in the Stimson sandstone are light-toned, elevated silica zones within 50 cm of a central fracture. They have likely experienced chemical leaching under acidic conditions resulting in depletion of metals (including Al), retention of Ti, formation of amorphous iron sulfates, 50% reduction of the pyroxene:plagioclase ratio, a factor of two increase in the Fe/Mn ratio, and passive enrichment of Si. This alteration is not constrained (nor precluded) to have occurred at elevated temperatures, but there are abundant indicators of hydrothermal activity within Gale crater. High concentrations of Ge, Zn, Ni, Pb, Cu, Se and Ga in a variety of samples analyzed by the Alpha Particle X-ray Spectrometer are indicative of mobility in hydrothermal solutions. Mineralogy of Gale crater samples determined by the CheMin X-ray diffraction instrument includes phases which may be associated with hydrothermal activity (smectites, anhydrite, hematite), but definitive detections of mineral assemblages that are necessarily hydrothermal in origin remain absent. The nearly identical patterns of enriched and depleted elements of the Stimson alteration halos (relative to parent rocks) and the tridymite-bearing unit (relative to typical mudstone samples) require the consideration of co-genetic origins. Cristobalite, a SiO2 polymorph stable above 1470°C found in the Buckskin sample, is known to form in hydrothermal solutions at temperatures well below its stability field (Henderson et al., 1971). Formation of well-crystalline tridymite at temperatures below its thermodynamic stability range (870-1470°C) has not been established, but cannot be excluded. Thus, the possibility that the fluids responsible for the passive enrichment of silica in the Stimson alteration halos also resulted in the in-situ formation of tridymite deserves further consideration.

Quantifying rock mass strength degradation in coastal rock cliffs

NASA Astrophysics Data System (ADS)

Brain, Matthew; Lim, Michael; Rosser, Nick; Petley, David; Norman, Emma; Barlow, John

2010-05-01

Although rock cliffs are generally perceived to evolve through undercutting and cantilever collapse of material, the recent application of high-resolution three-dimensional monitoring techniques has suggested that the volumetric losses recorded from layers above the intertidal zone produce an equally significant contribution to cliff behaviour. It is therefore important to understand the controls on rockfalls in such layers. Here we investigate the progressive influence of subaerial exposure and weathering on the geotechnical properties of the rocks encountered within the geologically complex coastal cliffs of the northeast coast of England, UK. Through a program of continuous in situ monitoring of local environmental and tidal conditions and laboratory rock strength testing, we aim to better quantify the relationships between environmental processes and the geotechnical response of the cliff materials. We have cut fresh (not previously exposed) samples from the three main rock types (sandstone, mudstone and shale) found within the cliff to uniform size, shape and volume, thus minimizing variability and removing previous surface weathering effects. In order to characterise the intact strength of the rocks, we have undertaken unconfined compressive strength and triaxial strength tests using high pressure (400 kN maximum axial load; 64 MPa maximum cell pressure) triaxial testing apparatus. The results outline the peak strength characteristics of the unweathered materials. We then divided the samples of each lithology into different experimental groups. The first set of samples remained in the laboratory at constant temperature and humidity; this group provides our control. Samples from each of the three rock types were located at heights on the cliff face corresponding with the different lithologies: at the base (mudstone), in the mid cliff (shale) and at the top of the cliff (sandstone). This subjected them to the same conditions experienced by the in situ cliff forming materials, which were also monitored using an array of environmental sensors. This experiment forms the basis of a long term investigation into the effects of varying environmental conditions on rock mass strength degradation over time. Ultimately, we aim to develop rock mass strength degradation curves to build a quantitative understanding of the interaction between coastal rock cliff behaviour and environmental processes.

Aqueous Alteration on Mars: Evidence from Landed Missions

NASA Technical Reports Server (NTRS)

Ming, Douglas W.; Morris, Richard V.; Clark, Benton C., III; Yen, Albert S.; Gellert, Ralf

2015-01-01

Mineralogical and geochemical data returned by orbiters and landers over the past 15 years have substantially enhanced our understanding of the history of aqueous alteration on Mars. Here, we summarize aqueous processes that have been implied from data collected by landed missions. Mars is a basaltic planet. The geochemistry of most materials has not been “extensively” altered by open-system aqueous processes and have average Mars crustal compositions. There are few examples of open-system alteration, such as Gale crater’s Pahrump Hills mudstone. Types of aqueous alteration include (1) acid-sulfate and (2) hydrolytic (circum-neutral/alkaline pH) with varying water-to-rock ratios. Several hypotheses have been suggested for acid-sulfate alteration including (1) oxidative weathering of ultramafic igneous rocks containing sulfides; (2) sulfuric acid weathering of basaltic materials; (3) acid fog weathering of basaltic materials; and (4) near-neutral pH subsurface solutions rich in Fe (sup 2 plus) that rapidly oxidized to Fe (sup 3 plus) producing excess acidity. Meridiani Planum’s sulfate-rich sedimentary deposit containing jarosite is the most “famous” acid-sulfate environment visited on Mars, although ferric sulfate-rich soils are common in Gusev crater’s Columbia Hills and jarosite was recently discovered in the Pahrump Hills. An example of aqueous alteration under circum-neutral pH conditions is the formation of Fe-saponite with magnetite in situ via aqueous alteration of olivine in Gale crater’s Sheepbed mudstone. Circum-neutral pH, hydrothermal conditions were likely required for the formation of Mg-Fe carbonate in the Columbia Hills. Diagenetic features (e.g., spherules, fracture filled veins) indicate multiple episodes of aqueous alteration/diagenesis in most sedimentary deposits. However, low water-to-rock ratios are prominent at most sites visited by landed missions (e.g., limited water for reaction to form crystalline phases possibly resulting in large amounts of short-range ordered materials and little physical separation of primary and secondary materials). Most of the aqueous alteration appears to have occurred early in the planet’s history; however, minor aqueous alteration may be occurring at the surface today (e.g., thin films of water forming carbonates akin to those discovered by Phoenix).

Stratigraphy and Folding in the Cenozoic Cover of a Fold-Thrust Belt in the Nallıhan Region (Ankara, Central Turkey)

NASA Astrophysics Data System (ADS)

Karaaǧaç, Serdal; Koral, Hayrettin

2017-04-01

This study investigates stratigraphy and structural features in the Cenozoic sedimentary sequence of the fold-thrust belt of the Nallıhan-Ankara region, located to the north of the İzmir-Ankara-Erzincan Suture Zone. Permian-Triassic age marble intercalated with schist-phyllites, the upper Jurassic-lower Cretaceous age limestone and the upper Cretaceous age sandstone-shale alternation compose the basement in the study area. These rocks are unconformably overlain by the Cenozoic age terrestrial sedimentary and volcanic units. The Cenozoic stratigraphy begins with the Paleocene-Eocene age coal-bearing, at times, volcanic intercalated conglomerate-sandstone-mudstone alternation of alluvial-fluvial origins (Aksaklar Formation) and the tuff intercalated with lacustrine limestone, bituminous limestone (Kabalar Formation). These units are conformably overlain by the Eocene age basalt-andesite and pyroclastic rocks (Meyildere volcanics). The Paleocene-Eocene aged units are unconformably overlain by the conglomerate-sandstone-mudstone-marl of a lower-middle Miocene lacustrine environment (Hançili Formation). The terrestrial conglomerate-sandstone alternation (Örencik Formation) is the youngest unit in the Cenozoic stratigraphy, and is assumed to be of Pliocene age based its stratigraphic position on older units. Field study shows existence of both folds and faults in the sedimentary cover. Stereographic projections of bedding measured in the field shows N25W/45NW and N60W/4SE-oriented fold axes in the Paleocene-Eocene age units. There are also N76W/12SE and N88E/8NE-oriented folds. The difference in fold-axis orientations suggests that some folds may have been rotated in blocks bound by faults during the post-Paleocene/Eocene period. Whereas, the lower-middle Miocene units manifest N88W/13SE-oriented fold axes. It is thus proposed that the observed difference in the azimuth of fold axes represent two different folding phases, one with NE-SW and the other with N-S directed axis of compression. Open folds with E-W orientation seem to be structural elements developed during the last phase of the deformation.

Sedimentology and paleoenvironments of the Las Chacritas carbonate paleolake, Cañadón Asfalto Formation (Jurassic), Patagonia, Argentina

NASA Astrophysics Data System (ADS)

Cabaleri, Nora G.; Benavente, Cecilia A.

2013-02-01

The Las Chacritas Member is the lower part of the Cañadón Asfalto Formation (Jurassic). The unit is a completely continental limestone succession with volcanic contributions that were deposited during the development of the Cañadón Asfalto Rift Basin (Chubut province, Patagonia, Argentina). A detailed sedimentological analysis was performed in the Fossati depocenter to determine the paleoenvironments that developed in the context of this rift. The Las Chacritas Member represents a carbonate paleolake system with ramp-shaped margins associated with wetlands that were eventually affected by subaerial exposure and pedogenesis. This process is represented by three main subenvironments: a) a lacustrine setting sensu stricto (lacustrine limestone facies association), represented by Mudstones/Wackestones containing porifera spicules (F1), Intraclastic packstones (F6) and Tabular stromatolites (F10) in which deposition and diagenesis were entirely subaqueous; b) a palustrine setting (palustrine limestone facies association) containing Microbial Mudstones (F2), Intraclastic sandy packstone with ostracode remains (F3), Oncolitic packstone (F5), Brecciated limestone (F7) and Nodular-Mottled limestone (F8) representing shallow marginal areas affected by groundwater fluctuations and minor subaerial exposure; and c) a pedogenic paleoenvironment (pedogenic limestone facies association) including Intraclastic limestone (F4) and Packstones containing Microcodium (F9) facies displaying the major features of subaerial exposure, pedogenic diagenesis and the development of paleosols. The fluvial-palustrine-lacustrine succession shows a general shallow upward trend in which contraction-expansion cycles are represented (delimited by exposure and surface erosion). The variations in the successive formations reflect the responses to fluctuations in a combination of two major controls, the tectonic and local climatic variables. The predominance of the palustrine facies associations was determined by its accommodation space as well as the local climate conditions. The variations in the lacustrine limestone facies associations reflect differential patterns of subsidence within the sub-basin. The diagnostic features of the palustrine limestone facies associations (organic matter (OM) content, microinvertebrate fauna, abundant mud cracks, brecciation, presence of evaporitic minerals) frame the sub-basin in a climatic context intermediate between arid and subhumid conditions.

The Anarraaq Zn-Pb-Ag and barite deposit, northern Alaska: Evidence for replacement of carbonate by barite and sulfides

USGS Publications Warehouse

Kelley, K.D.; Dumoulin, Julie A.; Jennings, S.

2004-01-01

The Anarraaq deposit in northern Alaska consists of a barite body, estimated to be as much as 1 billion metric tons, and a Zn-Pb-Ag massive sulfide zone with an estimated resource of about 18 Mt at 18 percent Zn, 5.4 percent Pb, and 85 g/t Ag. The barite and sulfide minerals are hosted by the uppermost part of the Mississippian Kuna Formation (Ikalukrok unit) that consists of carbonaceous and siliceous mudstone or shale interbedded with carbonate. The amount of interbedded carbonate in the Anarraaq deposit is atypical of the district as a whole, comprising as much as one third of the section. The total thickness of the Ikalukrok unit is considerably greater in the area of the deposit (210 to almost 350 m) than to the north and south (maximum of 164 m). The mineralized zone at Anarraaq is lens shaped and has a relatively flat top and a convex base. It also ranges greatly in thickness, from a few meters to more than 100 m. Textures of some of the carbonate layers are distinctive, consisting of nodules within siliceous mudstone or layers interbedded with shale. Many of the layers contain calcitized sponge spicules or radiolarians in a carbonate matrix. Textures of barite and sulfide minerals mimic those of carbonate and provide unequivocal evidence that replacement of precursor carbonate was an important process. Barite and sulfide textures include either nodular, bladed grains of various sizes that resemble spicules (observed only with iron sulfides) or well-rounded forms that are replaced radiolarians. Mineralization at Anarraaq probably occurred in a fault-bounded Carboniferous basin during early diagenesis in the shallow subsurface. The shape and size of the mineralized body suggest that barite and sulfides replaced calcareous mass flow deposits in a submarine channel. The distribution of biogenic and/or early diagenetic silica may have served as impermeable barriers to the fluids, thereby focusing and controlling fluid flow through unreplaced carbonate layers. ?? 2004 by Economic Geology.

Facies analysis of Lofer cycles (Upper Triassic), in the Argolis Peninsula (Greece)

NASA Astrophysics Data System (ADS)

Pomoni-Papaioannou, F.

The Upper Triassic carbonate sediments of Argolis Peninsula are part of the Upper Triassic-Lower Jurassic extensive and thick neritic carbonate formations (Pantokrator facies) that formed at the passive Pelagonian margin and are considered as Dachstein-type platform carbonates. Facies analysis of the Upper Triassic "Lofer-type" lagoonal-peritidal cycles in the Dhidimi area, proved that cycles, although mostly incomplete, were regressive shallowing-upward. The ideal elementary cyclothems are meter-scale in thickness and begin with a subtidal bed (Member C), represented by a peloidal dolostone with megalodonts (wackestone or packstone), being followed by a stromatolitic intertidal dolomitic mudstone and/or fenestral intertidal dolomitic mudstone (Member B) that is overlain by dolocrete (terrestrial stromatolites or pisoidic dolomite) or a supratidal "soil conglomerate" in red micritic matrix (Member A). Lofer-cycle boundaries are defined at the erosional surfaces and accordingly the Lofer cyclothems are unconformity-bounded units. Due to common post-depositional truncation of the subtidal and intertidal facies, the supratidal members prevail, being developed, in places, directly upon subaerial exposure surfaces (erosionally reduced cyclothems). Peritidal layers are characterized by a well-expressed lamination, sheet cracks, tepee structures, fenestral pores and karst dissolution cavities. The studied lagoonal-peritidal cycles are considered to have been deposited in a tidal-flat setting (inner platform), repeatedly exposed under subaerial conditions, in the context of a broader tropical rimmed platform. Although the studied area was tectonically active due to rift-activity and the autocyclic processes should also be taken in consideration, the great lateral correlatability of cycles, the facies shifting and the widespread erosion that resulted in superposition of supratidal-pedogenic facies directly upon subtidal members (subaerial erosional unconformity), indicating a sea-level drop, reflect allocyclic control via high-frequency eustatic sea-level oscillation (orbital forcing). Sediment deposition occurred during low-stand system tract (LST), that probably continued also in the transgressive system tract (TST) and reflects an overall sea-level fall. Under these conditions dissolution and cement precipitation episodes, as well development of paleosols and karsts, were triggered, during a relatively less arid interval.

Deposition of Boron in Possible Evaporite Deposits in Gale Crate

NASA Astrophysics Data System (ADS)

Gasda, P. J.; Peets, E.; Lamm, S. N.; Rapin, W.; Lanza, N.; Frydenvang, J.; Clark, B. C.; Herkenhoff, K. E.; Bridges, J.; Schwenzer, S. P.; Haldeman, E. B.; Wiens, R. C.; Maurice, S.; Clegg, S. M.; Delapp, D.; Sanford, V.; Bodine, M. R.; McInroy, R.

2017-12-01

Boron has been previously detected in Gale crater using the ChemCam instrument on board the NASA Curiosity rover within calcium sulfate fracture fill hosted by lacustrine mudstone and eolian sandstone units. Recent results show that up to 300 ppm B is present in the upper sections of the lacustrine unit. Boron has been detected in both the groundwater-emplaced calcium sulfate fracture fill materials and bedding-parallel calcium sulfate layers. The widespread bedding-parallel calcium sulfate layers within the upper strata of the lacustrine bedrock that Curiosity has encountered recently could be interpreted as primary evaporite deposits. We have two hypotheses for the history of boron in Gale crater. In both hypotheses, borates were first deposited as lake water evaporated, depositing primary evaporates that were later re-dissolved by groundwater, which redistributed the boron into secondary evaporitic calcium sulfate fracture fill deposits. In the first scenario, Gale crater may have undergone a period of perennial lake formation during a drier period of martian history, depositing layers of evaporitic minerals (including borates) among lacustrine mudstone layers. In the second scenario, lake margins could have become periodically exposed during cyclic drops in lake level and subsequently desiccated. Evaporites were deposited and desiccation features were formed in lowstand deposits. Either hypothetical scenario of evaporite deposition would promote prebiotic chemical reactions via wet-dry cycles. Boron may be an important prebiotic element, and as such, its presence in ancient martian surface and groundwater provides evidence that important prebiotic chemical reactions could occur on Mars if organics were present. The presence of boron in ancient Gale crater groundwater also provides additional evidence that a habitable environment existed in the martian subsurface well after the expected disappearance of liquid water on the surface of Mars. We will report on the most recent results for boron in relation to these bedding-parallel calcium sulfate layers and lowstand deposits. If a connection between observations of boron and lowstand lake features is found, this would suggest the existence of boron-bearing lake-deposited evaporites in Gale.

Shale Gas Petrophysical Models: an evaluation of contrasting approaches and assumptions

NASA Astrophysics Data System (ADS)

Inwood, Jennifer; Lovell, Mike; Davies, Sarah; Fishwick, Stewart; Taylor, Kevin

2015-04-01

Shale gas refers to fine-grained formations, or mudstones, where organic matter has matured sufficiently to produce predominantly gas, but that gas has not migrated any significant distance and hence the source rock is effectively the reservoir. Due to the success of shale gas extraction in the USA, many European countries are assessing their potential resources. A key uncertainty in evaluating the resource is the estimation of gas in place and most models are based on North American plays. However, it would seem that no single model to date can confidently predict the gas in place for a 'new' shale formation. Shale gas is frequently characterized by two distinct gas components: free gas is able to move and occupies the pores, while adsorbed gas is fixed onto organic surfaces and held in place by pressure. There are a number of different published methodologies that attempt to take account for this complicated distribution of gas within the rock ranging from models where the importance of the adsorbed gas is assumed to be negligible to those where all gas is assumed to exist within the organic pores and none within the mineral pore spaces. Models that assume both components are important and occupy adjacent volumes need to consider how to separate out the two to avoid double counting. Due to the heterogeneity of mudstones the most appropriate model may vary downhole as well as across adjacent wells. In this pilot study we consider the underlying assumptions and categorize models dependent on the deterministic or probabilistic approach used. We use an initial dataset from North America to test and compare a number of different approaches before expanding the analysis to further formations that span a range of geological and petrophysical characteristics. We then review and evaluate the models, identifying key variables and, where possible, determining their importance through sensitivity analysis. This work aims to establish guidelines for selecting the most appropriate petrophysical model for evaluating the gas in place in a shale gas play, and as such provides a more informed understanding of this petrophysical maze for both specialists and non-specialists.

Tracking Changes in Iron Mineralogy Through Time in Gale Crater and Terrestrial Analogues

NASA Astrophysics Data System (ADS)

Sheppard, R.; Milliken, R.; Russell, J. M.

2017-12-01

Iron and other redox-sensitive elements measured in ancient mudstones of Gale Crater, Mars by the Curiosity rover can provide information on past climate and interactions between water and the early atmosphere. Preserved ferrous mineralogy can constrain lake bottom water conditions and potentially the relative position of the oxycline and/or shoreline through the stratigraphic section. Multiple oxidation states in a given assemblage may also indicate a potential energy source for microbes. The X-ray amorphous fraction of all rocks measured in Gale Crater to date is also enigmatic: it can constitute up to 50 wt% of the sediment but the precise composition and formation conditions are unknown. Features similar to those in the martian mudstones are seen in sediments from the terrestrial redox-stratified Lake Towuti, including alternating ferrous and ferric mineralogy and an abundant Fe-rich X-ray amorphous phase. To constrain conditions in the water column and early diagenetic processes, we present trends in chemistry and mineralogy for sediment acquired from soils in the mafic/ultramafic catchment and lake bottom/core samples. The soils contain high abundances of crystalline Fe-oxides (e.g. magnetite, goethite, hematite), whereas sediment from the very surface of the lake bottom maintain high Fe but not in crystalline form based on XRD. This suggests Fe is being rapidly cycled to form amorphous phases after entering the lake. Sequential extractions to isolate highly reactive iron (e.g. ferrihydrite) will be used to confirm the relative abundance of poorly crystalline phases in catchment versus lake sediment. Sediments from a 150 m core representing 1 Myr lake history also maintain high Fe content and distinct alternating bands of red and green sediment, but there are no crystalline Fe-oxides discernible in XRD data. The process(es) and timescale for this switching is not yet known, but understanding the conditions that allow ferrous vs. ferric iron to form, and what other changes happen concurrently with silicates such as clay minerals, may help constrain how to interpret lake sediment chemistry and mineralogy in terms of climate on Earth and Mars.

Overview of the Mars Science Laboratory mission: Bradbury Landing to Yellowknife Bay and beyond

NASA Astrophysics Data System (ADS)

Vasavada, A. R.; Grotzinger, J. P.; Arvidson, R. E.; Calef, F. J.; Crisp, J. A.; Gupta, S.; Hurowitz, J.; Mangold, N.; Maurice, S.; Schmidt, M. E.; Wiens, R. C.; Williams, R. M. E.; Yingst, R. A.

2014-06-01

The Mars Science Laboratory mission reached Bradbury Landing in August 2012. In its first 500 sols, the rover Curiosity was commissioned and began its investigation of the habitability of past and present environments within Gale Crater. Curiosity traversed eastward toward Glenelg, investigating a boulder with a highly alkaline basaltic composition, encountering numerous exposures of outcropping pebble conglomerate, and sampling aeolian sediment at Rocknest and lacustrine mudstones at Yellowknife Bay. On sol 324, the mission turned its focus southwest, beginning a year-long journey to the lower reaches of Mt. Sharp, with brief stops at the Darwin and Cooperstown waypoints. The unprecedented complexity of the rover and payload systems posed challenges to science operations, as did a number of anomalies. Operational processes were revised to include additional opportunities for advance planning by the science and engineering teams.

Comment on "Evaluation of X-ray diffraction methods for determining the crystal growth mechanisms of clay minerals in mudstones, shales and slates," by L. N. Warr and D. R. Peacor

USGS Publications Warehouse

Eberl, D.D.; Srodon, J.; Drits, V.A.

2003-01-01

A recent paper by Warr and Peacor (2002) suggested that our use of the Bertaut-Warren-Averbach technique (MudMaster computer program) for studying changes in crystallite thickness distributions (CTDs) of clay minerals during diagenesis and very low-grade metamorphism is not reliable because it is dependent on many variables which can not be fully controlled. Furthermore, the authors implied that the measured shapes of CTDs cannot be used with confidence to deduce crystal growth mechanisms and histories for clays, based on our CTD simulation approach (using the Galoper computer program). We disagree with both points, and show that the techniques are powerful, reliable and useful for studying clay mineral alteration in rocks. ?? 2003 Schweiz. Mineral. Petrogr. Ges.

Mars atmosphere. The imprint of atmospheric evolution in the D/H of Hesperian clay minerals on Mars.

PubMed

Mahaffy, P R; Webster, C R; Stern, J C; Brunner, A E; Atreya, S K; Conrad, P G; Domagal-Goldman, S; Eigenbrode, J L; Flesch, G J; Christensen, L E; Franz, H B; Freissinet, C; Glavin, D P; Grotzinger, J P; Jones, J H; Leshin, L A; Malespin, C; McAdam, A C; Ming, D W; Navarro-Gonzalez, R; Niles, P B; Owen, T; Pavlov, A A; Steele, A; Trainer, M G; Williford, K H; Wray, J J

2015-01-23

The deuterium-to-hydrogen (D/H) ratio in strongly bound water or hydroxyl groups in ancient martian clays retains the imprint of the water of formation of these minerals. Curiosity's Sample Analysis at Mars (SAM) experiment measured thermally evolved water and hydrogen gas released between 550° and 950°C from samples of Hesperian-era Gale crater smectite to determine this isotope ratio. The D/H value is 3.0 (±0.2) times the ratio in standard mean ocean water. The D/H ratio in this ~3-billion-year-old mudstone, which is half that of the present martian atmosphere but substantially higher than that expected in very early Mars, indicates an extended history of hydrogen escape and desiccation of the planet. Copyright © 2015, American Association for the Advancement of Science.

Redox stratification of an ancient lake in Gale crater, Mars.

PubMed

Hurowitz, J A; Grotzinger, J P; Fischer, W W; McLennan, S M; Milliken, R E; Stein, N; Vasavada, A R; Blake, D F; Dehouck, E; Eigenbrode, J L; Fairén, A G; Frydenvang, J; Gellert, R; Grant, J A; Gupta, S; Herkenhoff, K E; Ming, D W; Rampe, E B; Schmidt, M E; Siebach, K L; Stack-Morgan, K; Sumner, D Y; Wiens, R C

2017-06-02

In 2012, NASA's Curiosity rover landed on Mars to assess its potential as a habitat for past life and investigate the paleoclimate record preserved by sedimentary rocks inside the ~150-kilometer-diameter Gale impact crater. Geological reconstructions from Curiosity rover data have revealed an ancient, habitable lake environment fed by rivers draining into the crater. We synthesize geochemical and mineralogical data from lake-bed mudstones collected during the first 1300 martian solar days of rover operations in Gale. We present evidence for lake redox stratification, established by depth-dependent variations in atmospheric oxidant and dissolved-solute concentrations. Paleoclimate proxy data indicate that a transition from colder to warmer climate conditions is preserved in the stratigraphy. Finally, a late phase of geochemical modification by saline fluids is recognized. Copyright © 2017, American Association for the Advancement of Science.

Secrets of Hidden Valley on Mars

NASA Image and Video Library

2015-10-08

An image taken at the Hidden Valley site, en-route to Mount Sharp, by NASA Curiosity rover. A variety of mudstone strata in the area indicate a lakebed deposit, with river- and stream-related deposits nearby. Decoding the history of how these sedimentary rocks were formed, and during what period of time, was a key component in the confirming of the role of water and sedimentation in the formation of the floor of Gale Crater and Mount Sharp. This image was taken by the Mast Camera (Mastcam) on Curiosity on the 703rd Martian day, or sol, of the mission. Malin Space Science Systems, San Diego, built and operates Curiosity's Mastcam. NASA's Jet Propulsion Laboratory, a division of the California Institute of Technology, Pasadena, built the rover and manages the project for NASA's Science Mission Directorate, Washington. http://photojournal.jpl.nasa.gov/catalog/PIA19840

Detecting a Difference in Clay Minerals at Two Gale Crater Sites

NASA Image and Video Library

2016-12-13

Data graphed here from the Chemistry and Camera (CheMin) instrument on NASA's Mars Curiosity rover show a difference between clay minerals in powder drilled from mudstone outcrops at two locations in Mars' Gale Crater: "Yellowknife Bay" and "Murray Buttes." CheMin's X-ray diffraction analysis reveals information about the crystalline structure of minerals in the rock. The intensity peaks marked with dotted vertical lines in this chart indicate that the crystalline structure of the two sites' clay minerals differs. The difference can be tied to a compositional difference in the clay minerals, as depicted in a diagram at PIA21148. The Yellowknife Bay site is on the floor of Gale Crater. The Murray Buttes site is on lower Mount Sharp, the layered mound in the center of the crater. http://photojournal.jpl.nasa.gov/catalog/PIA21147

Siliceous spicules in a vauxiid sponge (Demospongia) from the Kaili Biota(Cambrian Stage 5), Guizhou, South China

NASA Astrophysics Data System (ADS)

Yang, X.-L.; Zhao, Y.-L.; Babcock, L. E.; Peng, J.

2017-02-01

Fossils of the sponge Angulosuspongia sinensis from calcareous mudstones of the middle and upper part of the Kaili Formation (Cambrian Stage 5) in the Jianhe area of Guizhou province, South China, exhibit an apparently reticulate pattern, characteristic of the Vauxiidae. Energy Dispersive X-Ray Spectrometry (EDS) and Raman spectroscopy analysis indicate the presence of silica in the skeletal elements of these fossils, suggesting that this taxon possessed a skeleton comprised of spicules. This is the first confirmation of siliceous skeletal elements in fossils of the family Vauxiidae, and it lends support to the hypothesis that some early demosponges possessed biomineralized siliceous skeletons, which were subsequently lost and replaced by spongin later in the evolutionary history of this lineage. The new materials provide critical insight into the phylogeny and evolution of biomineralization in the Demosopongiae.

Mechanical development of folded chert beds in Monterey Formation, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crowther, D.; Snyder, W.S.

1988-03-01

Small-scale folds in the upper siliceous facies of the Miocene Monterey Formation, at Lions Head, California (Santa Maria basin) are of tectonic origin. Folding is well developed in the chert-dominated zones and dies out rapidly in the adjacent siliceous mudstones. A tectonic origin is evidenced by the dominantly brittle deformation of the competent chert layers. Mechanically, the folds formed through a complex interrelationship between fracture and flexural slip. Opal-CT and quartz-chert layers display brittle fractures and rotated fracture blocks that responded to shortening. Thrusting of the chert layers is common in folds where fold propagation was impeded. Dilation breccia andmore » void space occur in the hinges and reflect room problems during development of these disharmonic folds. Subsequent diagenesis has partially healed the fractures and slip surfaces, creating the erroneous appearance that ductile deformation was an important factor in the formation of the folds.« less

Organic geochemistry and petrology of oil source rocks, Carpathian Overthrust region, southeastern Poland - Implications for petroleum generation

USGS Publications Warehouse

Kruge, M.A.; Mastalerz, Maria; Solecki, A.; Stankiewicz, B.A.

1996-01-01

The organic mailer rich Oligocene Menilite black shales and mudstones are widely distributed in the Carpathian Overthrust region of southeastern Poland and have excellent hydrocarbon generation potential, according to TOC, Rock-Eval, and petrographic data. Extractable organic matter was characterized by an equable distribution of steranes by carbon number, by varying amounts of 28,30-dinor-hopane, 18??(H)-oleanane and by a distinctive group of C24 ring-A degraded triterpanes. The Menilite samples ranged in maturity from pre-generative to mid-oil window levels, with the most mature in the southeastern portion of the study area. Carpathian petroleum samples from Campanian Oligocene sandstone reservoirs were similar in biomarker composition to the Menilite rock extracts. Similarities in aliphatic and aromatic hydrocarbon distributions between petroleum asphaltene and source rock pyrolyzates provided further evidence genetically linking Menilite kerogens with Carpathian oils.

Silurian K-bentonites of the Dnestr Basin, Podolia, Ukraine

USGS Publications Warehouse

Huff, W.D.; Bergstrom, Stig M.; Kolata, Dennis R.

2000-01-01

The Dnestr Basin of Podolia, Ukraine, is an epicratonic basin consisting of neritic carbonate and calcareous mudstone facies including a nearly complete Silurian sequence ranging from late Llandovery to late Pridoli in age. The Silurian section has served as a standard for regional and interregional studies as a consequence of its well-documented macro- and microfaunal assemblages. Approximately 24 mid- to Late Silurian K-bentonites are present in this succession, and their lateral persistence has aided in establishing regional correlations. The K-bentonites range from 1 to 40 cm in thickness and occur in the Bagovitsa (late Wenlock), Malinovtsy (Ludlow) and Skala (Pridoli) Formations. Discrimination diagrams based on immobile trace elements together with rare earth element data suggest the K-bentonites had a volcanic origin in a collision margin setting related to subduction. Thickness and stratigraphic distribution considerations are consistent with a source area in the Rheic Ocean.

DEPOSITIONAL RELATIONS OF UMPQUA AND TYEE FORMATIONS (EOCENE), SOUTHWESTERN OREGON.

USGS Publications Warehouse

Molenaar, C.M.

1985-01-01

The Umpqua Formation (as herein restricted) consists of as much as 10,000 ft of mudstone, sandstone, and conglomerate of nonmarine to deep marine origin. A basaltic basement that underlies the sedimentary rocks in most of the area and was formerly included in the Umpqua is herein considered a separate unit and assigned to the Siletz River Volcanics. A proposal to subdivide the Umpqua into three unconformity-bounded formations in the area west of Roseburg, Oregon, is not recognized in this report because of questionable correlations and limited extent of some units. The Tyee Formation, which conformably overlies the Umpqua, is a predominantly sandstone unit about 6,000 ft thick, deposited in environments ranging from shallow marine and nonmarine deltaic on the south, to slope and deep marine basinal to the north. Deposition across the Umpqua-Tyee boundary contact represents a change in tectonic setting. Refs.

Underwater noise from geotechnical drilling and standard penetration testing.

PubMed

Erbe, Christine; McPherson, Craig

2017-09-01

Geotechnical site investigations prior to marine construction typically involve shallow, small-core drilling and standard penetration testing (SPT), during which a small tube is hammered into the ground at the bottom of the borehole. Drilling (120 kW, 83 mm diameter drillbit, 1500 rpm, 16-17 m drill depth in sand and mudstone) and SPT (50 mm diameter test tube, 15 mm wall thickness, 100 kg hammer, 1 m drop height) by a jack-up rig in 7-13 m of water were recorded with a drifting hydrophone at 10-50 m range. Source levels were 142-145 dB re 1 μPa rms @ 1 m (30-2000 Hz) for drilling and 151-160 dB re 1 μPa 2 s @ 1 m (20-24 000 Hz) for SPT.

Anomalous Iridium Enrichment at the Triassic-Jurassic Boundary, Blomidon Formation, Fundy Basin, Canada

NASA Technical Reports Server (NTRS)

Kyte, Frank T.

2005-01-01

We present new analyses that confirm Ir enrichment (up to 0.31 ng/g) in close proximity to the palynological Triassic-Jurassic boundary in strata near the top of the Blomidon Formation at Partridge Island, Nova Scotia. High Ir concentrations have been found in at least two samples within the uppermost 70 cm of the formation. Ratios of other PGEs and Au to Ir are generally higher by an order of magnitude than in ordinary chondrites. No impact-related materials have been identified at #is horizon in the Blomidon Formation, therefore we cannot confirm an extraterrestrial source for the anomalous Ir levels. We consider, however, the possibility that regional basaltic volcanism is a potential source for the Ir in these sediments. The elevated Ir concentrations are found in reduced, grey colored mudstones, so redox concentration is a possible explanation for the distribution of Ir in these strata.

Sedimentary Facies of the West Crocker Formation North Kota Kinabalu-Tuaran Area, Sabah, Malaysia

NASA Astrophysics Data System (ADS)

Mohamed, Azfar; Hadi Abd Rahman, Abdul; Suhaili Ismail, Mohd

2016-02-01

Newly outcrops exposed in the West Crocker Formation have led to the detail sedimentolgical analysis of the formation. Eight sedimentary facies have been recognised in which it was divided into three main groups: (1) sand-dominated facies (F1-F2), (2) poorly- sorted unit mixed sand and mud-dominated facies (F3), and (3) mud-dominated facies (F4-F5). These are: F1- graded sandstone (massive to planar laminated), F2-ripple-cross laminated, wavy and convolute lamination sandstone, F3-chaotic beds of mixed sandstone and mudstone blocks and clasts, F4-lenticular bedded of sandstone, and F5-shale. The studies of the formation has come out that it was deposited in a sand-rich submarine fan with specific location located at (1) inner fan channel-levee complex; (2) mid-fan channelised lobes, and (3) outer fan.

Exceptionally preserved Cambrian loriciferans and the early animal invasion of the meiobenthos.

PubMed

Harvey, Thomas H P; Butterfield, Nicholas J

2017-01-30

Microscopic animals that live among and between sediment grains (meiobenthic metazoans) are key constituents of modern aquatic ecosystems, but are effectively absent from the fossil record. We describe an assemblage of microscopic fossil loriciferans (Ecdysozoa, Loricifera) from the late Cambrian Deadwood Formation of western Canada. The fossils share a characteristic head structure and minute adult body size (~300 μm) with modern loriciferans, indicating the early evolution and subsequent conservation of an obligate, permanently meiobenthic lifestyle. The unsuspected fossilization potential of such small animals in marine mudstones offers a new search image for the earliest ecdysozoans and other animals, although the anatomical complexity of loriciferans points to their evolutionary miniaturization from a larger-bodied ancestor. The invasion of animals into ecospace that was previously monopolized by protists will have contributed considerably to the revolutionary geobiological feedbacks of the Proterozoic/Phanerozoic transition.

Geophysical Logs of Selected Wells at the Diaz Chemical Superfund Site in the Village of Holley, New York, 2009

USGS Publications Warehouse

Eckhardt, David A.V.; Anderson, J. Alton

2010-01-01

Geophysical logs were collected and analyzed to define the bedrock fracture patterns and flow zones penetrated by three wells at the Diaz Chemical Superfund Site in the Village of Holley in Orleans County, New York. The work was conducted in December 2009 as part of the investigation of contamination by organic compounds in the shale, mudstone, and sandstone bedrock at the Site. The geophysical logs include natural-gamma, caliper, borehole image, fluid properties, and flowmeter data. The orientation of fractures in the boreholes was inferred from the log data and summarized in stereo and tadpole plots; when possible, the transmissivity and hydraulic head was also determined for fracture zones that were observed to be hydraulically active through the flowmeter logs. The data are intended, in part, for use in the remediation of the site.

A giant Late Triassic ichthyosaur from the UK and a reinterpretation of the Aust Cliff ‘dinosaurian’ bones

PubMed Central

De la Salle, Paul; Massare, Judy A.; Gallois, Ramues

2018-01-01

The largest reported ichthyosaurs lived during the Late Triassic (~235–200 million years ago), and isolated, fragmentary bones could be easily mistaken for those of dinosaurs because of their size. We report the discovery of an isolated bone from the lower jaw of a giant ichthyosaur from the latest Triassic of Lilstock, Somerset, UK. It documents that giant ichthyosaurs persisted well into the Rhaetian Stage, and close to the time of the Late Triassic extinction event. This specimen has prompted the reinterpretation of several large, roughly cylindrical bones from the latest Triassic (Rhaetian Stage) Westbury Mudstone Formation from Aust Cliff, Gloucestershire, UK. We argue here that the Aust bones, previously identified as those of dinosaurs or large terrestrial archosaurs, are jaw fragments from giant ichthyosaurs. The Lilstock and Aust specimens might represent the largest ichthyosaurs currently known. PMID:29630618

Siliceous spicules in a vauxiid sponge (Demospongia) from the Kaili Biota(Cambrian Stage 5), Guizhou, South China

PubMed Central

Yang, X.-L.; Zhao, Y.-L.; Babcock, L. E.; Peng, J.

2017-01-01

Fossils of the sponge Angulosuspongia sinensis from calcareous mudstones of the middle and upper part of the Kaili Formation (Cambrian Stage 5) in the Jianhe area of Guizhou province, South China, exhibit an apparently reticulate pattern, characteristic of the Vauxiidae. Energy Dispersive X-Ray Spectrometry (EDS) and Raman spectroscopy analysis indicate the presence of silica in the skeletal elements of these fossils, suggesting that this taxon possessed a skeleton comprised of spicules. This is the first confirmation of siliceous skeletal elements in fossils of the family Vauxiidae, and it lends support to the hypothesis that some early demosponges possessed biomineralized siliceous skeletons, which were subsequently lost and replaced by spongin later in the evolutionary history of this lineage. The new materials provide critical insight into the phylogeny and evolution of biomineralization in the Demosopongiae. PMID:28220860

Geophysical Logs of Selected Test Wells at the Diaz Chemical Superfund Site in Holley, New York

USGS Publications Warehouse

Eckhardt, David A.V.; Anderson, J. Alton

2007-01-01

In June and July 2006, geophysical logs were collected and analyzed along with rock-core samples to define the bedrock stratigraphy and flow zones penetrated by four test wells at the Diaz Chemical Superfund site at Holley in eastern Orleans County, New York. The work was completed as a preliminary part of the investigation of contamination by organic compounds in the shale, mudstone, and sandstone bedrock. The geophysical logs included natural-gamma, caliper, borehole image, fluid properties, and flowmeter data. The orientation of fractures in the boreholes was inferred from the log data and summarized in stereo and tadpole plots; the transmissivity and hydraulic head was also determined for fracture zones that were observed to be hydraulically active through the flowmeter logs. The data are intended in part for use in the remediation of the site.

First record of Ginkgo-related fertile organs (Hamshawvia, Stachyopitys) and leaves (Baiera, Sphenobaiera) in the Triassic of Brazil, Santa Maria formation

NASA Astrophysics Data System (ADS)

Barboni, Ronaldo; Dutra, Tânia Lindner

2015-11-01

This paper describes new ginkgophytes recently discovered in a new exposure of the original type section of the Passo das Tropas Member, Santa Maria Formation, linked to Paraná Basin succession. The well-preserved fossils come from a very fine red laminated mudstone representing a lacustrine interval, within a broader low-sinuosity fluvial succession. The material occurs in a Dicroidium-dominated assemblage and is represented by the leaves Baiera and Sphenobaiera, accompanied by the fertile structures Hamshawvia and Stachyopytis. Cuticle fragments preserved on leaf impressions of Sphenobaiera schenkii show xeromorphic features. The geology, paleogeography and paleoclimate of the Passo das Tropas Member (PTM), Santa Maria Formation, is discussed. By comparing these ginkgophytes with those from other Gondwanan assemblages, the Brazilian deposits earlier assigned to Anisian-Ladinian age can now be extended to the Carnian age.

Microfacies and diagenesis of the Middle Jurassic Dhruma carbonates, southwest Riyadh, Saudi Arabia

NASA Astrophysics Data System (ADS)

El-Sorogy, Abdelbaset S.; Galmed, Mahmoud A.; Al-Kahtany, Khaled; Al-Zahrani, Ali

2017-06-01

In order to document the microfacies analysis and diagenetic alterations of the Middle Jurassic Dhruma Formation at southwest Riyadh City of central Saudi Arabia, a stratigraphic section was studied in detail at Khashm adh Dhi'bi area. Mudstones, wackstones, packstones, grainstones and boundstones are the main microfacies types in the studied area. These microfacies types with field investigations and fossil content indicated an environment ranging from deep shelf to organic buildup on platform margins for the studied carbonates. Cementation and recrystallization, dissolution, fragmentation and compaction, silicification, dolomitization, and bioerosion were the main diagenetic alterations affected the carbonate rocks of the Dhruma Formation. Cementation and recrystallization are represented by equant calcite crystals, Dog-tooth fringes of thin isopachous calcites and blocky low Mg-calcites. Gastrochaenolites, Trypanites and Meandropolydora spp. were the most bioeroders in coral heads and large bivalves and hardgrounds. These bioeroders indicated a long post-mortem period during the early diagenetic stage.

Merged digital aeromagnetic data for the middle Rio Grande and southern Espanola basins, New Mexico

USGS Publications Warehouse

Sweeney, Ronald E.; Grauch, V.J.S.; Phillips, Jeffrey D.

2002-01-01

The U. S. Geological Survey (USGS) recently conducted a multi-disciplinary study of the Middle Rio Grande basin (Bartolino and Cole, 2002; Fig. 1). The main purpose of this study was to gain a better multi-dimensional understanding of the basin's hydrogeologic framework and use this new understanding to construct an improved regional ground-water flow model. The Middle Rio Grande basin fill serves as the primary water resource for Albuquerque and surrounding communities (Thorn and others, 1993). It is composed of poorly consolidated, Tertiary to Quaternary sediments, collectively called the Santa Fe Group. These sediments were deposited during the Tertiary to Quaternary development of the Rio Grande rift (Fig. 1, inset). The strata vary in thickness from 1,000 to more than 4,000 m and range from mudstone to conglomerate (Kelley, 1977; May and Russell, 1994).

High Stress Consolidation, Ultrasonic, and Permeability Measurements: Constraints on Physical Properties and In Situ Stress along the Costa Rica Subduction Plate Interface

NASA Astrophysics Data System (ADS)

Winner, A.; Saffer, D. M.; Valdez, R. D.

2014-12-01

Sediment permeability and consolidation behavior are key parameters in governing the drainage state and thus potential for excess pore fluid pressure in subduction zones. Elevated pore pressure, in turn, is one important control on the strength and sliding behavior of faults. Along many subduction margins, evidence of elevated, near-lithostatic, in situ pore pressure comes from high seismic reflectivity, low P-wave velocity (Vp), and high Vp/Vs ratios. This inference is broadly supported by numerical modeling studies that indicate elevated pore pressures are likely given high rates of burial and tectonic loading, combined with the low permeability of marine mudstones. Here, we report on a series of high-stress consolidation experiments on sediment core samples from the incoming Cocos plate obtained as part of Integrated Ocean Drilling Program (IODP) Expedition 344. Our experiments were designed to measure the consolidation behavior, permeability, and P-wave velocity of the incoming sediments over a range of confining stresses from .5 to 90 MPa. We explore a range of paths,including isostatic loading (σ1=σ2=σ3), K0 consolidation, in which the ratio of σ3/σ1 is maintained at ~0.6, and the trixial loading paths designed to maintain a near critical-state failure condition. In our tests, load is increased in a series of steps. After equilibration at each step, we conduct constant head permeability tests, and measure P-wave velocities in a "time of flight" mode. Initial results from isostatic loading tests on hemipelagic mudstone samples from 34 mbsf document consolidation and permeability-porosity trends, in which porosity decreases from 69% to 54% as stress in increased from .5 MPa to 15 MPa, and permeability decreases from 8.1 X 10-18 m2 at 1 MPa to 1.1 X 10-19 m2 at 15 MPa. P-wave velocity increases by 486-568 km/s over this effective stress range. Ultimately, data from our experiments will provide a robust basis for quantifying fluid content and pressure from seismic velocity and fault plane reflectivity at this margin, and provide data to parameterize forward models of fluid flow and consolidation.

Bedrock cores from 89° North: Implications for the geologic framework and Neogene paleoceanography of Lomonosov Ridge and a tie to the Barents shelf

USGS Publications Warehouse

Grantz, Arthur; Pease, Victoria L.; Willard, Debra A.; Phillips, R.L.; Clark, David L.

2001-01-01

Two piston cores from the Eurasian flank of Lomonosov Ridge near lat 88.9°N, long 140°E provide the first samples of bedrock from this high-standing trans-Arctic ridge. Core 94-PC27 sampled nonmarine siltstone similar in facies and age to uppermost Triassic to lower Lower Jurassic and mid– Lower Cretaceous beds in the 4 to > 5 km Mesozoic section on Franz Josef Land, on the outer Barents shelf. A ca. 250 Ma peak in the cumulative frequency curve of detrital zircons from the siltstone, dated by U- Th-Pb analysis, suggests a source in the post-tectonic syenites of northern Taymyr and nearby islands in the Kara Sea. Textural trends reported in the literature indicate that the Lower Jurassic nonmarine strata of Franz Josef Land coarsen to the southeast; this suggests the existence of a sedimentary system in which detrital zircons could be transported from the northern Taymyr Peninsula to the outer Barents shelf near the position of core 94-PC27 prior to opening of the Eurasia Basin. Correlation of the coaly siltstone in core 94-PC27 with part of the Mesozoic section on Franz Josef Land is compatible with the strong evidence from seafloor magnetic anomalies and bathymetry that Lomonosov Ridge is a continental fragment rifted from the Barents shelf during the Cenozoic. It also suggests that Lomonosov Ridge near the North Pole is underlain by a substantial section of unmetamorphosed Mesozoic marine and nonmarine sedimentary strata. Core 94-PC29 sampled cyclical deposits containing ice-rafted debris (IRD) overlying weakly consolidated laminated olive-black anoxic Neogene siltstone and mudstone with an average total organic carbon (TOC) of 4.1 wt%. The high TOC content of the mudstone indicates that during the Neogene, prior to the introduction of IRD into the Arctic seas about 3.3 Ma (early late Pliocene), the shallow waters of the central Arctic Ocean supported significant primary photosynthetic organic production near the North Pole. These deposits also contain fine grains of siltstone that resemble the breccia-clast siltstone of core 94-PC27 and reworked Carboniferous, Cretaceous, and Tertiary palynomorphs that may have also originated in the bedrock of Lomonosov Ridge.

Sedimentary provenance of Trinity Peninsula Group, Antarctic Peninsula: petrography, geochemistry and SHRIMP U-Pb zircon age constraints.

NASA Astrophysics Data System (ADS)

Castillo, P.; Lacassie, J. P.; Hervé, F.; Fanning, C. M.

2009-04-01

The Trinity Peninsula Group (TPG) crops out in northern Graham Land and consists of a mostly non-fossiliferous metasedimentary succession of Permo-Triassic(?) age, which was accreted prior to the initiation of the Gondwana breakup. This succession has been sub-divided, from north to south, into five formations, namely: Hope Bay (HBF), View Point (VPF), Legoupil (LgF), Charlotte Bay (ChBF) and Paradise Harbour (PHF) formations. However, there are still large areas with unknown stratigraphic allocation, age and extension. Twenty TPG samples (12 sandstones and 8 mudstones) were collected from four localities in the Antarctic Peninsula, including Hope Bay; Paradise Harbour, Cape Legoupil and Charlotte Bay. Twelve sandstones were selected for modal analysis and 15 samples (7 sandstones and 8 mudstones) for whole rock chemical analysis. The geochemical data of the TPG samples was compared with the geochemical data of other sedimentary successions of different provenance and tectonic setting, by using unsupervised artificial neural networks. The modal composition of the sandstones is dominated by quartz and, in similar but smaller proportions by feldspar, and according to the discrimination scheme of Dickinson et al. (1983) is consistent with the product of erosion of the plutonic roots of a magmatic arc. The chemical data suggest a relatively evolved source, with a composition similar to a typical granodioritic continental magmatic arc. The deposition of the detritus is most likely to have occurred within an active continental margin. Three sandstone samples from the HBF, LgF and PHF were selected for U-Pb dating of detrital zircons by SHRIMP. For the HBF and PHF samples, the major age component is Permian (270-280 Ma). Only the sample from LgF has two important peaks at ~270 and ~470 Ma. In all cases, the youngest dated zircon is Permian (~257 Ma). These results show that there are strong chemical and chronological similarities between the TPG, the Duque de York Complex (DYC, Patagonia), the Rakaia Terrane (New Zealand) and the LeMay Group (Alexander Island, Antarctic Peninsula). These similarities suggest that these successions derive from the same active continental margin. Into this context, the subtle petrographical differences between TPG and DYC could possibly indicate that both units correspond to different petrofacies of a common source, as has been proposed for the Rakaia Terrane in New Zealand.

Hydrology and water-quality monitoring considerations, Jackpile uranium mine, northwestern New Mexico

USGS Publications Warehouse

Zehner, H.H.

1985-01-01

The Jackpile Uranium Mine, which is on the Pueblo of Laguna in northwestern New Mexico, was operated from 1953 to 1980. The mine and facilities have affected 3,141 acres of land, and about 2,656 acres were yet to be reclaimed by late 1980. The intended use of the restored land is stock grazing. Fractured Dakota Sandstone and Mancos Shale of Cretaceous age overlie the Jackpile sandstone and a 200-ft-thick tight mudstone unit of the Brushy Basin Member underlies the Jackpile. The hydraulic conductivity of the Jackpile sandstone probably is about 0.3 ft/day. The small storage coefficients determined from three aquifer tests indicate that the Jackpile sandstone is a confined hydrologic system throughout much of the mine area. Sediment from the Rio Paguate has nearly filled the Paguate Reservoir near Laguna since its construction in 1940. The mean concentrations of uranium, Ra-226, and other trace elements generally were less than permissible limits established in national drinking water regulations or New Mexico State groundwater regulations. No individual surface water samples collected upstream from the mine contained concentrations of Ra-226 in excess of the permissible limits. Ra-226 concentrations in many individual samples collected from the Rio Paguate from near the mouth of the Rio Moquino to the sampling sites along the downstream reach of the Rio Paguate, however, exceeded the recommended permissible concentration of Ra-226 for public drinking water supplies. Concentrations in surface water apparently are changed by groundwater inflow near the confluence of the two streams. The altitude of the water tables in the backfill of the pits will be controlled partly by the water level in the Rio Paguate. Other factors controlling the altitudes of the water tables are the recharge rate to the backfill and the hydraulic conductivities of the backfill, alluvium, Jackpile sandstone, and mudstone unit of the Brushy Basin Member. After reclamation, most of the shallow groundwater probably will discharge to the natural stream channels draining the mine area. Groundwater quality may be monitored as: (1) ' Limited monitoring, ' in which only the change in water quality is determined as the groundwater flows from the mine; or (2) ' thorough monitoring, ' in which specific sources of possible contaminants are described. (Author 's Abstract)

Evidence of the coupled geology system and its impact on the evolution of South China during the transformation from Sinian to Cambrian

NASA Astrophysics Data System (ADS)

Yang, C.; Wang, T.; Chen, Z.

2016-12-01

Separate interpretation of the evidence on tectonic, sedimentology or climate is insufficient to reappear the dynamic process of the evolution of the Earth surface, thus, tectonic, sedimentology and climate should be considered as a coupled system. Thick carbonate succession is overlaying on the paleo-uplift which is divided into two parts by a fluted belt in the center of Sichuan Basin. Sinian carbonate rocks is commonly composed by algae dolomite, while at the top of the Sinian succession the rocks had experienced meteoric karstification. Grain dolostones, fine-grained siliciclastic sandstones with mudstone appeare as the regional sediment of Cambrian. However, extraordinary thick mudstone had settled in the fluted belt, and the succession could be divided in to siliciclastic mud of the lower and clay-carbonate mud of the upper. The geochemistry and well log synthesized profile of Z4 well indicate that the chemical condition of siliciclastic mud and clay-carbonate mud had changed from oxidation to reduction, however the siliciclastic mud only appeared within the fluted belt. The fluted belt does not exist on the map of the gravity anomaly, but it had been convinced by the seismic data. The precursor of the fluted belt might be a sag within the platform basement, while with the sea level gradually raising up, the growth of algal mound exacerbated the geomorphology difference. Then a regression had happened at the end of the Sinian, starved all the algae and caused weather crust. Meanwhile, the fluted belt became a closed lagoon, received the sediment including algal mound fragment and biosilic crystals. Afterwards, rapidly increasing of the sea level deposited thick cay-carbonate mud that could be recognized as the sediment of maximum flooding surface. Then with the sea level decreasing, siliciclastic sandstones and inorganic grain carbonate became the main petrology of the Cambrian strata. Fine-grained eolian siliciclastic sandstones within the Cambrian carbonate indicate the influence of the continent, but this terrigenous clastics not exist in Sinian carbonate because the location of the platform moved closer to the continent in Cambrian. Meanwhile, there is no algal within Cambrian carbonate, it means the platform might drift to inhospitable place for the algal during the period.

The Sedimentology and Origins of a Giant Mass Transport Deposit: The Nataraja Slide, Arabian Sea

NASA Astrophysics Data System (ADS)

Dailey, S. K.; Clift, P. D.; Kulhanek, D. K.; Calves, G.

2017-12-01

The Nataraja Slide was recently discovered by seismic mapping off the west coast of India in the Arabian Sea. Volumetrically estimated to be 19,000 km3, it is the second largest mass transport deposit known on a passive margin. Understanding how this deposit was emplaced is important to constrain how mass wasting affects the bathymetry of sedimentary basins, as well as the effects triggered by such a large event, including tsunamis. The Nataraja Slide was emplaced at 10.8 Ma as a result of collapse of the western India margin, which traveled 550 km into the basin. The deposit has been cored in two locations by the International Ocean Discovery Program (IODP) Expedition 355, where it is 330 m (Site U1456) and 190 m thick (Site U1457). The presence of various deformation structures and the occurrence of a predominantly reworked calcareous nannofossil assemblages are used to define the top of the deposit. The deposit appears to consist of two units at Site U1456 with 22 m of upper Miocene hemipelagic sediment separating them, suggesting emplacement in two large pulses. At both sites, the mass transport deposit has a coarse carbonate-dominated base, composed of clast-supported breccia overlain by massive calcarenite associated with high-energy current transport, and calcilutite. These strata are overlain by steeply inclined, slumped but otherwise coherent pyritized, siliciclastic mudstones and minor volumes of matrix-supported conglomerates, interpreted as debris flows. Emplacement appears to have eroded significant thicknesses of Indus Fan turbidites at Site U1456, as there is a hiatus that is a minimum of 2.5 m.y. at the base. At Site U1457, the slide directly overlies Paleocene reddish mudstones on the eastern flank of the Laxmi Ridge, which likely diverted the sediment to the south in the Laxmi Basin and away from the main Arabian Sea basin. Bulk sediment Nd and Sr isotope geochemistry show a provenance, similar to those of the Tapti and Narmada rivers in western India, and include entrainment of Indus Fan material particularly in the top of the deposit, and drape. Our study aims to further evaluate the depositional mechanisms and original trigger for the mass wasting event by using petrography to understand the sediment in this upper Miocene mass transport deposit.

Porosity-depth trends of carbonate deposits along the northwest shelf of Australia (IODP Expedition 356)

NASA Astrophysics Data System (ADS)

Lee, Eun Young; Kominz, Michelle; Reuning, Lars; Takayanagi, Hideko; Knierzinger, Wolfgang; Wagreich, Michael; Expedition 356 shipboard scientists, IODP

2017-04-01

The northwest shelf (NWS) of Australia extends from northern tropical to southern temperate latitudes situated offshore from the low-moderate-relief and semi-arid Australian continent. The shelf environment is dominated throughout by carbonate sedimentation with warm-water and tropical carbonate deposits, connected to the long-term northward drift of Australia bringing the NWS into tropical latitudes. IODP expedition 356 cored seven sites (U1458-U1464) covering a latitudinal range of 29°S-18°S off the NWS. This study focuses on porosity-depth trends of the Miocene - Pleistocene carbonate sediment on the NWS. The NWS is an ideal area to study regional (and furthermore general) carbonate porosity-depth relationships, because it contains a nearly continuous sequence of carbonate sediment ranging in depth from the surface to about 1,100m and in age from Pleistocene to Miocene. Porosity-depth trends of sedimentary rocks are generally controlled by a variety of factors which govern the rates of porosity loss due to mechanical compaction and of porosity loss (or gain) due to chemical processes during diagenesis. This study derives porosity data from Moisture and Density (MAD) technique conducted during IODP Expedition 356. MAD samples were collected from packstone (44%), wackestone (27%), mudstone (15%) and grainstone (7%), with the rest from floatstone, rudstone, dolostone, sandstone and other subordinate lithologies. To understand porosity-depth trends, the porosity data are arranged both exponentially and linearly, and correlated with age models and lithologic descriptions provided by IODP shipboard scientists. Porosity(%)-depth(m) trends of all the porosity data are Porosity=52e-0.0008/Depth (exponential) and Porosity=-0.03Depth+52 (linear). Porosities near surface and in the deepest parts of each well are least well represented by these trend lines. Porosity values of Pleistocene sediment are generally higher than those of Miocene - Pliocene sediment. The initial porosity in porosity-depth trends increases from 52% to 57% with increasing mud content from grainstone to packstone, wackestone, and mudstone. Carbonate sediment that includes non-skeletal grains usually has lower porosity values than the trend lines. *This research was a part of the project titled 'International Ocean Discovery Program', funded by the Ministry of Oceans and Fisheries, Korea.

Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ernest A. Mancini; Paul Aharon; Donald A. Goddard

2006-05-26

The principal research effort for Phase 1 (Concept Development) of the project has been data compilation; determination of the tectonic, depositional, burial, and thermal maturation histories of the North Louisiana Salt Basin; basin modeling (geohistory, thermal maturation, hydrocarbon expulsion); petroleum system identification; comparative basin evaluation; and resource assessment. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, and regional cross sections have been prepared. Structure, isopach and formation lithology maps have been constructed, and burial history, thermal maturation history, and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface mapsmore » and burial history, thermal maturation history, and hydrocarbon expulsion profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs include Upper Jurassic and Cretaceous fluvial-deltaic sandstone facies; shoreline, marine bar and shallow shelf sandstone facies; and carbonate shoal, shelf and reef facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon expulsion commenced during the Early Cretaceous and continued into the Tertiary with peak expulsion occurring during the Early to Late Cretaceous. The geohistory of the North Louisiana Salt Basin is comparable to the Mississippi Interior Salt Basin with the major difference being the elevated heat flow the strata in the North Louisiana Salt Basin experienced in the Cretaceous due primarily to reactivation of upward movement, igneous activity, and erosion associated with the Monroe and Sabine Uplifts. Potential undiscovered reservoirs in the North Louisiana Salt Basin are Triassic Eagle Mills sandstone and deeply buried Upper Jurassic sandstone and limestone. Potential underdeveloped reservoirs include Lower Cretaceous sandstone and limestone and Upper Cretaceous sandstone.« less

Elastic Properties of Subduction Zone Materials in the Large Shallow Slip Environment for the Tohoku 2011 Earthquake: Laboratory data from JFAST Core Samples

NASA Astrophysics Data System (ADS)

Jeppson, T.; Tobin, H. J.

2014-12-01

The 11 March 2011 Tohoku-Oki earthquake (Mw=9.0) produced large displacements of ~50 meters near the Japan Trench. In order to understand earthquake propagation and slip stabilization in this environment, quantitative values of the real elastic properties of fault zones and their surrounding wall rock material is crucial. Because elastic and mechanical properties of faults and wallrocks are controlling factors in fault strength, earthquake generation and propagation, and slip stabilization, an understanding of these properties and their depth dependence is essential to understanding and accurately modeling earthquake rupture. In particular, quantitatively measured S-wave speeds, needed for estimation of elastic properties, are scarce in the literature. We report laboratory ultrasonic velocity measurements performed at elevated pressures, as well as the calculated dynamic elastic moduli, for samples of the rock surrounding the Tohoku earthquake principal fault zone recovered by drilling during IODP Expedition 343, Japan Trench Fast Drilling Project (JFAST). We performed measurements on five samples of gray mudstone from the hanging wall and one sample of underthrust brown mudstone from the footwall. We find P- and S-wave velocities of 2.0 to 2.4 km/s and 0.7 to 1.0 km/s, respectively, at 5 MPa effective pressure. At the same effective pressure, the hanging wall samples have shear moduli ranging from 1.4 to 2.2 GPa and the footwall sample has a shear modulus of 1.0 GPa. While these values are perhaps not surprising for shallow, clay-rich subduction zone sediments, they are substantially lower than the 30 GPa commonly assumed for rigidity in earthquake rupture and propagation models [e.g., Ide et al., 1993; Liu and Rice, 2005; Loveless and Meade, 2011]. In order to better understand the elastic properties of shallow subduction zone sediments, our measurements from the Japan Trench are compared to similar shallow drill core samples from the Nankai Trough, Costa Rica, Cascadia, and Barbados ridge subduction zones. We find that shallow subduction zone sediments in general have similarly low rigidity. These data provide important ground-truth values that can be used to parameterize fault slip models addressing the problem of shallow, tsunamigenic propagation of megathrust earthquakes.

Detrital Zircon U-Pb Analysis of the Liuqu Conglomerate Along the Yarlung-Zangbo Suture Zone, and Implications for the Mode and Timing of Collision Tectonics in Southern Tibet

NASA Astrophysics Data System (ADS)

Xie, Y.; Dilek, Y.

2016-12-01

The Liuqu Conglomerate (LQC) along the Yarlung-Zangbo suture zone (YZSZ) in Southern Tibet is a terrestrial deposit that provides significant spatial and temporal constraints for the timing and nature of collisional events in the tectonic evolution of the Tibetan-Himalayan orogenic belt. The 10-km-wide (N-S) LQC is exposed discontinuously for more than 1000 km in an E-W direction, and is tectonically overlain to the north by the Cretaceous Neotethyan oceanic lithosphere along a S-vergent thrust fault system and to the south by Triassic-Jurassic metamorphosed sedimentary-volcanic rocks of the Tethyan Himalaya along N-vergent reverse-thrust faults. The major facies of the LQC are the matrix-supported to clast-supported conglomerates. The matrix is poorly to moderate sorted red quartz sandstone, mudstone and sub-rounded pebble to cobble-sized clasts. The clast lithology present in central and southern parts includes dark red sandstone, siltstone and mudstone greyish-green shale, grey phyllite and slate with their provenance in the Triassic Tethyan Himalaya to the south. The clastic material making up its stratigraphy in the northern part of the LQC includes quartz sandstone, radiolarian chert, minor dolerite, gabbro and peridotite derived from the Cretaceous ophiolite. Here we report in-situ detrital zircon U-Pb age analysis of sandstone from the LQC near Liuqu area. 163 concordant U-Pb ages obtained from sample 22-LQ-15, 27-LQ-15 and 35-LQ-15 show the youngest age is 307±13 Ma with discordance of -17.02%, and the oldest zircon grain is 3362 ±51 Ma with discordance of 2.63%. Statistically, the age spectrum of these zircons from the three sandstone samples display a prominent peak centred in 935 Ma, a large peak around 516 Ma, and two small clusters around 2429 Ma and 2772 Ma. The zircon U-Pb results provide evidence of age clusters of the sandstone in LQC are consistent with the detrital U-Pb age signature of the sandstone in Tethyan Himalaya. Thus, the sediments in the LQC could be derived from the northern edge of the Indian margin and a late Jurassic-Cretaceous intra-oceanic island arc that lay within Thethys and developed prior to the final collision between India and Eurasia plates.

Sedimentology and High Resolution Sequence Stratigraphy of the Middle Jurassic Dhruma Formation Carbonates Outcrops in the Central Saudi Arabia

NASA Astrophysics Data System (ADS)

Yousif, Ibrahim; Abdullatif, Osman; Makkawi, Mohammed; Abdulghani, Waleed

2017-04-01

This study investigates the microfacies and sequence stratigraphic frame work of the Middle Jurassic Dhruma Formation in outcrops in central Saudi Arabia. The study contributes to the efforts to understand and enhance local and regional stratigraphic relationship and correlation of the Jurassic carbonate sequences and their significance to reservoir description and prediction in the subsurcae. The study describes and characterizes the sedimentology, microfacies and the stratigraphy of Dhruma Formation from outcrop sections having a total thickness of 70 m. Detailed microfacies and high-resolution stratigraphical analysis were carried out to determine microfacies, cyclicity, sequences and staking pattern. The study revealed ten lithofacies namely: oolitic grainstone,bioclastic oolitic grainstone, oolitic grapestone, bioclastic grainstone,foraminiferal packstone, echinoderm packstone, peloidal packstone to grainstone,skeletal wackestone to packstone, mudstone, and marlstone.These lithofacies were grouped into five lithofacies associations that deposited on a carbonate ramp setting. The depositional environment ranging from low energy lagoonal setting to high-energy shoals and banks to low energy outer ramp setting. Five high-resolution composite sequences have been defined and each sequence is composed at the bottom of intercalated mudstone/wackestone that passing up into grainstone lithofacies.The composite sequences range in thickness from 7 to 15 m, while the parasequences range from 0.5 to 1.5 m. The composite sequences extend laterally for a distance of more than 350 m. The overall composite section shows a shallowing upward succession of the 4th to the 5th order high-resolution sequences.The dominant lithofacies are the grainy ones, which constitute 30%, 50% and 80% of the studied sections. Furthermore, the parasequences thickness and their bio-components are increasing towards the top. The muddy lithofacies intensively affected the vertical continuity of the lower reservoir interval compared to the upper interval. Detailed examination of thin-sections reflects a clear and well-developed reservoir interval in the uppermost part of the section, which is dominated by peloidal packstone and grainstone.The findings of this high-resolution outcrop analog might help to understand and predict lithofacies, stratigraphic heirachies and correlations of Dhruma Formation within the interwell spacing. Moreover, this study might also contribute to better reservoir description and assessment of its quality and architecture in subsurface equivalent reservoirs.

The Investigation of Chlorate and Perchlorate/Saponite Mixtures as a Possible Source of Oxygen and Chlorine Detected by the Sample Analysis at Mars (SAM) Instrument in Gale Crater

NASA Technical Reports Server (NTRS)

Clark, J.; Sutter, B.; Min, D. W.; Mahaffy, P.

2016-01-01

The Sample Analysis at Mars (SAM) instrument on board the Curiosity Rover has detected O2 and HCl gas releases from all analyzed Gale Crater sediments, which are attributed to the presence of perchlorates and/or chlorates in martian sediment. Previous SAM analog laboratory analyses found that most pure perchlorates and chlorates release O2 and HCl at different temperatures than those observed in the SAM data. Subsequent studies examined the effects of perchlorate and chlorate mixtures with Gale Crater analog iron phases, which are known to catalyze oxychlorine decomposition. Several mixtures produced O2 releases at similar temperatures as Gale Crater materials, but most of these mixtures did not produce significant HCl releases comparable to those detected by the SAM instrument. In order to better explain the Gale Crater HCl releases, perchlorates and chlorates were mixed with Gale Crater analog saponite, which is found at abundances from 8 to 20 wt % in the John Klein and Cumberland drill samples. Mixtures of chlorates or perchlorates with calcium-saponite or ferrian-saponite were heated to 1000 deg C in a Labsys EVO differential scanning calorimeter/mass spectrometer configured to operate similarly to the SAM oven/quadrupole mass spectrometer system. Our results demonstrate that all chlorate and perchlorate mixtures produce significant HCl releases below 1000 deg C as well as depressed oxygen peak release temperatures when mixed with saponite. The type of saponite (calcium or ferrian saponite) did not affect the evolved gas results significantly. Saponite/Mg-perchlorate mixtures produced two HCl releases similar to the Cumberland drilled sample. Mg-chlorate mixed with saponite produced HCl releases similar to the Big Sky drilled sample in an eolian sandstone. A mixture of Ca-perchlorate and saponite produced HCl and oxygen releases similar to the Buckskin mudstone drilled sample and the Gobabeb 2 eolian dune material. Ca-chlorate mixed with saponite produced both HCl and oxygen releases within the same range as the Rock-nest windblown deposit, the Greenhorn eolian sandstone, and the John Klein drilled mudstone. Overall, mixtures of perchlorates or chlorates with saponite provide the first explanation for the high temperature HCl releases in addition to the oxygen releases observed in Gale Crater materials.

Acid Sulfate Alteration on Mars

NASA Technical Reports Server (NTRS)

Ming, D. W.; Morris, R. V.

2016-01-01

A variety of mineralogical and geochemical indicators for aqueous alteration on Mars have been identified by a combination of surface and orbital robotic missions, telescopic observations, characterization of Martian meteorites, and laboratory and terrestrial analog studies. Acid sulfate alteration has been identified at all three landing sites visited by NASA rover missions (Spirit, Opportunity, and Curiosity). Spirit landed in Gusev crater in 2004 and discovered Fe-sulfates and materials that have been extensively leached by acid sulfate solutions. Opportunity landing on the plains of Meridiani Planum also in 2004 where the rover encountered large abundances of jarosite and hematite in sedimentary rocks. Curiosity landed in Gale crater in 2012 and has characterized fluvial, deltaic, and lacustrine sediments. Jarosite and hematite were discovered in some of the lacustrine sediments. The high elemental abundance of sulfur in surface materials is obvious evidence that sulfate has played a major role in aqueous processes at all landing sites on Mars. The sulfate-rich outcrop at Meridiani Planum has an SO3 content of up to 25 wt.%. The interiors of rocks and outcrops on the Columbia Hills within Gusev crater have up to 8 wt.% SO3. Soils at both sites generally have between 5 to 14 wt.% SO3, and several soils in Gusev crater contain around 30 wt.% SO3. After normalization of major element compositions to a SO3-free basis, the bulk compositions of these materials are basaltic, with a few exceptions in Gusev crater and in lacustrine mudstones in Gale crater. These observations suggest that materials encountered by the rovers were derived from basaltic precursors by acid sulfate alteration under nearly isochemical conditions (i.e., minimal leaching). There are several cases, however, where acid sulfate alteration minerals (jarosite and hematite) formed in open hydrologic systems, e.g., in Gale crater lacustrine mudstones. Several hypotheses have been suggested for the aqueous formation of sulfate-bearing phases under acidic conditions on the surface of Mars including (1) sulfuric acid weathering of basaltic materials; (2) oxidative weathering of ultramafic igneous rocks containing sulfides; (3) acid fog weathering of basaltic materials, and (4) near-neutral pH subsurface solutions rich in Fe2(+) that were rapidly oxidized to Fe3(+), which produced excess acidity as iron was oxidized on exposure to O2 or photo-oxidized by ultraviolet radiation at the martian surface. Next, we briefly describe evidence for these hypothesis.

Age and speciation of iodine in groundwater and mudstones of the Horonobe area, Hokkaido, Japan: Implications for the origin and migration of iodine during basin evolution

NASA Astrophysics Data System (ADS)

Togo, Yoko S.; Takahashi, Yoshio; Amano, Yuki; Matsuzaki, Hiroyuki; Suzuki, Yohey; Terada, Yasuko; Muramatsu, Yasuyuki; Ito, Kazumasa; Iwatsuki, Teruki

2016-10-01

This paper reports the concentration, speciation and isotope ratio (129I/127I) of iodine from both groundwater and host rocks in the Horonobe area, northern Hokkaido, Japan, to clarify the origin and migration of iodine in sedimentary rocks. Cretaceous to Quaternary sedimentary rocks deposited nearly horizontally in Tenpoku Basin and in the Horonobe area were uplifted above sea level during active tectonics to form folds and faults in the Quaternary. Samples were collected from the Pliocene Koetoi and late Miocene Wakkanai formations (Fms), which include diatomaceous and siliceous mudstones. The iodine concentration in groundwater, up to 270 μmol/L, is significantly higher than that of seawater, with the iodine enrichment factor relative to seawater reaching 800-1500. The iodine concentration in the rocks decreases from the Koetoi to Wakkanai Fms, suggesting that iodine was released into the water from the rocks of deeper formations. The iodine concentration in the rocks is sufficiently high for forming iodine-rich groundwater as found in this area. X-ray absorption near edge structure (XANES) analysis shows that iodine exists as organic iodine and iodide (I-) in host rocks, whereas it exists mainly as I- in groundwater. The isotope ratio is nearly constant for iodine in the groundwater, at [0.11-0.23] × 10-12, and it is higher for iodine in rocks, at [0.29-1.1] × 10-12, giving iodine ages of 42-60 Ma and 7-38 Ma, respectively. Some iodine in groundwater must have originated from Paleogene and even late Cretaceous Fms, which are also considered as possible sources of oil and gas, in view of the old iodine ages of the groundwater. The iodine ages of the rocks are older than the depositional ages, implying that the rocks adsorbed some iodine from groundwater, which was sourced from greater depths. The iodine concentration in groundwater decreases with decreasing chlorine concentration due to mixing of iodine-rich connate water and meteoric water. A likely scenario is that iodine-rich brine formed during the long-term basin evolution from the Cretaceous to Quaternary and that this brine was diluted by mixing with meteoric water during uplifting and denudation of the area.

Magnetic Polarity Stratigraphy and Rock Magnetic Data From the Continuous Cored Record of Triassic Continental Environmental Change, the Colorado Plateau Coring Project

NASA Astrophysics Data System (ADS)

Geissman, J. W.; McIntosh, J.; Buhedma, H. M. A.

2017-12-01

Despite the fact that the Triassic Period (ca. 251.9-201.3 Ma) is bound by two of Earth's largest mass extinctions, experienced giant bolide impacts and eruption of three large igneous provinces, and witnessed evolution of the main components of modern tetrapod communities, the time interval has sparse geochronologic calibration. The US NSF- and ICDP-funded coring of Phase 1 of the CPCP was completed in 2013, with the recovery of two major cores (6.35 cm diameter: 1A, 518m length and 2B, 253m; 31km apart) from the Petrified Forest National Park spanning the Chinle and Moenkopi fms. Core 1A has been fully sampled, with specimens obtained either by drilling or by extraction of core fragments and packing in ceramic boxes. Specimens are subjected to progressive thermal demagnetization or a combination of alternating field (AF) followed by thermal treatment. In several cases, specimens were extracted from each core segment to test for internal consistency. Chinle hematitic mudstones and siltstones have NRM intensities between 130 to 0.5 mA/m, with bulk susceptibilities from 2 x 10-2 to 5 x 10-5 SI units. More indurated hematitic siltstones/ medium sandstones of the Moenkopi Fm have NRM intensities and bulk susceptibilities that are far less variable (NRM: 9.0 to 1.2 mA/m, MS: 3.0 X 10-4 and 0.5 x 10-5 SI vol). Thermal demagnetization typically isolates magnetizations of N declination and shallow inclination (interpreted as normal polarity) and antipodes (reverse) (image), a polarity stratigraphy is being compiled for much of the section. Response is typically more interpretable for very hematitic Chinle mudstone sections and most Moenkopi rocks. Coarser grained, less hematitic Chinle strata rarely yield interpretable results, likely due to coarse-grained detrital magnetite, and it is likely that these intervals will not yield robust polarity information. Some core segments yield well-resolved magnetizations that are inconsistent with a Triassic field and we suspect occasional core reorientation inaccuracies. For core segments yielding magnetizations resembling a Triassic magnetic field, anisotropy of magnetic susceptibility data show a well-developed depositional fabric. IRM acquisition and backfield demagnetization data demonstrate both hematite and magnetite as magnetic phases.

Environmental radioactivity in the UK: the airborne geophysical view of dose rate estimates.

PubMed

Beamish, David

2014-12-01

This study considers UK airborne gamma-ray data obtained through a series of high spatial resolution, low altitude surveys over the past decade. The ground concentrations of the naturally occurring radionuclides Potassium, Thorium and Uranium are converted to air absorbed dose rates and these are used to assess terrestrial exposure levels from both natural and technologically enhanced sources. The high resolution airborne information is also assessed alongside existing knowledge from soil sampling and ground-based measurements of exposure levels. The surveys have sampled an extensive number of the UK lithological bedrock formations and the statistical information provides examples of low dose rate lithologies (the formations that characterise much of southern England) to the highest sustained values associated with granitic terrains. The maximum dose rates (e.g. >300 nGy h(-1)) encountered across the sampled granitic terrains are found to vary by a factor of 2. Excluding granitic terrains, the most spatially extensive dose rates (>50 nGy h(-1)) are found in association with the Mercia Mudstone Group (Triassic argillaceous mudstones) of eastern England. Geological associations between high dose rate and high radon values are also noted. Recent studies of the datasets have revealed the extent of source rock (i.e. bedrock) flux attenuation by soil moisture in conjunction with the density and porosity of the temperate latitude soils found in the UK. The presence or absence of soil cover (and associated presence or absence of attenuation) appears to account for a range of localised variations in the exposure levels encountered. The hypothesis is supported by a study of an extensive combined data set of dose rates obtained from soil sampling and by airborne geophysical survey. With no attenuation factors applied, except those intrinsic to the airborne estimates, a bias to high values of between 10 and 15 nGy h(-1) is observed in the soil data. A wide range of technologically enhanced, localised contributions to dose rate values are also apparent in the data sets. Two detailed examples are provided that reveal the detectability of site-scale environmental impacts due to former industrial activities and the high dose values (>500 nGy h(-1)) that are associated with former, small-scale Uranium mining operations. Copyright © 2014. Published by Elsevier Ltd.

Preliminary Magnetic Polarity Stratigraphy and Rock Magnetic Data From the Continuous Cored Record of Triassic Continental Environmental Change, the Colorado Plateau Coring Project

NASA Astrophysics Data System (ADS)

Geissman, J. W.; Buhedma, H. M. A.; McIntosh, J.; Olsen, P. E.; Kent, D. V.

2016-12-01

The Triassic Period (251.9-201.3 Ma) is bound by two of Earth's largest mass extinctions, suffered giant bolide impacts and eruption of 3 large igneous provinces, and saw evolution of the main components of modern tetrapod communities, and yet has sparse geochronologic calibration. To bridge this gap, the US NSF- and ICDP-funded coring of Phase 1 of the CPCP was completed in late 2013, with the recovery of two major cores (1A, 518m length and 2B, 253m; 31km apart) from the north and south ends of Petrified Forest National Park spanning most of the Chinle and all of the Moenkopi fms. Core 1A has been fully sampled, with specimens obtained either by drilling or by careful extraction of core fragments and packing in ceramic boxes. Several specimens were extracted from each core segment to test for internal consistency and subjected to progressive thermal demagnetization or a combination of alternating field (AF) followed by thermal treatment. Chinle hematitic mudstones and siltstones have NRM intensities that range from 130 to 0.5 mA/m, with bulk susceptibilities from 2 x 10-2 to 5 x 10-5 SI units. More indurated hematitic siltstones and sandstones of the Moenkopi Fm have NRM intensities that range from 9.0 to 1.2 mA/m and bulk susceptibilities are far less variable, between 3.0 X 10-4 and 0.5 x 10-5 SI units. Thermal demagnetization typically isolates magnetizations of N declination and shallow inclination (interpreted as normal polarity) and antipodes (reverse). Some core segments yield well-resolved magnetizations that are inconsistent with a Triassic field and we suspect correctable core orientation errors. Demagnetization response is typically more interpretable for hematitic Chinle mudstone intervals and most Moenkopi rocks. Coarser grained, less hematitic Chinle rocks rarely yield interpretable results, likely due to coarse-grained detrital magnetite. For core segments yielding magnetizations resembling a Triassic magnetic field, anisotropy of magnetic susceptibility data show a well-developed depositional fabric. IRM acquisition and backfield demagnetization data demonstrate both hematite and magnetite as magnetic phases. Given results thus far, a polarity stratigraphy should be obtainable for the section, allowing global export of the numerous zircon U-Pb dates from core and local outcrop.

Sedimentology and paleoenvironments of a new fossiliferous late Miocene-Pliocene sedimentary succession in the Rukwa Rift Basin, Tanzania

NASA Astrophysics Data System (ADS)

Mtelela, Cassy; Roberts, Eric M.; Hilbert-Wolf, Hannah L.; Downie, Robert; Hendrix, Marc S.; O'Connor, Patrick M.; Stevens, Nancy J.

2017-05-01

This paper presents a detailed sedimentologic investigation of a newly identified, fossiliferous Late Neogene sedimentary succession in the Rukwa Rift Basin, southwestern Tanzania. This synrift deposit is a rare and significant new example of a fossiliferous succession of this age in the Western Branch of East Africa Rift System. The unit, informally termed the lower Lake Beds succession, is late Miocene to Pliocene in age based on cross-cutting relationships, preliminary biostratigraphy, and U-Pb geochronology. An angular unconformity separates the lower Lake Beds from underlying Cretaceous and Oligocene strata. Deposition was controlled by rapid generation of accommodation space and increased sediment supply associated with late Cenozoic tectonic reactivation of the Rukwa Rift and synchronous initiation of the Rungwe Volcanic Centre. The lower Lake Beds, which have thus far only been identified in three localities throughout the Rukwa Rift Basin, are characterized by two discrete lithologic members (herein A and B). The lower Member A is a volcanic-rich succession composed mostly of devitrified volcanic tuffs, and volcaniclastic mudstones and sandstones with minor conglomerates. The upper Member B is a siliciclastic-dominated succession of conglomerates, sandstones, mudstones and minor volcanic tuffs. Detailed facies analysis of the lower Lake Beds reveals various distinctive depositional environments that can be grouped into three categories: 1) alluvial fan; 2) fluvial channel; and 3) flood basin environments, characterized by volcanoclastic-filled lakes and ponds, abandoned channel-fills and pedogenically modified floodplains. Member A represents a shallow lacustrine setting filled by tuffaceous sediments, which grade up into a system of alluvial fans and high-energy, proximal gravel-bed braided rivers. An unconformity marks the contact between the two members. Member B shows an upward transition from a high-energy, gravel-bed braided river system to a sandy braided river system with increasingly abundant floodplain deposits and well-developed paleosols. Vertebrate fossils are sparse in member A, but common in member B, preserved both within pedogenic soil horizons and as isolated elements and microsites within fluvial channel facies associations. Faunal remains include fishes, turtles and crocodylians, along with well-preserved mammal cranial and post-cranial remains. In addition, freshwater gastropod shells are locally present in member A and continental trace fossils, including abundant fossilized termite nests, are present in both members.

Early neogene history of the central American arc from Bocas del Toro, western Panama

USGS Publications Warehouse

Coates, Anthony G.; Aubry, Marie-Pierre; Berggren, William A.; Collins, Laurel S.; Kunk, Michael J.

2003-01-01

A newly discovered sequence of lower to middle Miocene rocks from the eastern Bocas del Toro archipelago, western Panama, reveals the timing and environment of the earliest stages in the rise of the Isthmus of Panama in this region. Two new formations, the Punta Alegre Formation (lower Miocene, Aquitanian to Burdigalian) and the Valiente Formation (middle Miocene, Langhian to Serravallian), are here named and formally described. The Punta Alegre Formation contains a diagnostic microfauna of benthic and planktic foraminifera and calcareous nannofossils that indicate deposition in a 2000-m-deep pre-isthmian neotropical ocean from as old as 21.5–18.3 Ma. Its lithology varies from silty mudstone to muddy foraminiferal ooze with rare thin microturbidite layers near the top. The Valiente Formation, which ranges in age from 16.4 to ca. 12.0 Ma, lies with slight angular unconformity on the Punta Alegre Formation and consists of five lithofacies: (1) columnar basalt and flow breccia, (2) pyroclastic deposits, (3) coarse-grained volcaniclastic deposits, (4) coral-reef limestone with diverse large coral colonies, and (5) marine debris-flow deposits and microturbidites. These lithofacies are interpreted to indicate that after ca. 16 Ma a volcanic arc developed in the region of Bocas del Toro and that by ca. 12 Ma an extensively emergent archipelago of volcanic islands had formed. 39Ar/40Ar dating of basalt flows associated with the fossiliferous sedimentary rocks in the upper part of the Valiente Formation strongly confirms the ages derived from planktic foraminifera and nannofossils. Paleobathymetric analysis of the two new formations in the Valiente Peninsula and Popa Island, in the Bocas del Toro archipelago, shows a general shallowing from lower- through upper-bathyal to upper-neritic and emergent laharic and fluviatile deposits from ca. 19 to 12 Ma. The overlying nonconformable Bocas del Toro Group contains a lower transgressive sequence ranging from basal nearshore sandstone to upper-bathyal mudstone (ca. 8.1–5.3 Ma) and an upper regressive sequence (5.3–3.5 Ma). A similar paleobathymetric pattern is observed from the Gatun to Chagres Formations (12–6 Ma) in the Panama Canal Basin area and in the Uscari, Rio Banana, Quebrada Chocolate, and Moin Formations (8–1.7 Ma) in the southern Limón Basin of Costa Rica.

Ocean Drilling Program Leg 178 (Antarctic Peninsula): Sedimentology of glacially influenced continental margin topsets and foresets

USGS Publications Warehouse

Eyles, N.; Daniels, J.; Osterman, L.E.; Januszczak, N.

2001-01-01

Ocean Drilling Program Leg 178 (February-April 1998) drilled two sites (Sites 1097 and 1103) on the outer Antarctic Peninsula Pacific continental shelf. Recovered strata are no older than late Miocene or early Pliocene (<4.6 Ma). Recovery at shallow depths in loosely consolidated and iceberg-turbated bouldery sediment was poor but improved with increasing depth and consolidation to allow description of lithofacies and biofacies and interpretation of depositional environment. Site 1097 lies on the outer shelf within Marguerite Trough which is a major outlet for ice expanding seaward from the Antarctic Peninsula and reached a maximum depth drilled of 436.6 m below the sea floor (mbsf). Seismic stratigraphic data show flat-lying upper strata resting on strata that dip gently seaward. Uppermost strata, to a depth of 150 mbsf, were poorly recovered, but data suggest they consist of diamictites containing reworked and abraded marine microfauna. This interval is interpreted as having been deposited largely as till produced by subglacial cannibalization of marine sediments (deformation till) recording ice sheet expansion across the shelf. Underlying gently dipping strata show massive, stratified and graded diamictite facies with common bioturbation and slump stuctures that are interbedded with laminated and massive mudstones with dropstones. The succession contains a well-preserved in situ marine microfauna typical of open marine and proglacial marine environments. The lower gently dipping succession at Site 1097 is interpreted as a complex of sediment gravity flows formed of poorly sorted glacial debris. Site 1103 was drilled in that part of the continental margin that shows uppermost flat-lying continental shelf topsets overlying steeper dipping slope foresets seaward of a structural mid-shelf high. Drilling reached a depth of 363 mbsf with good recovery in steeply dipping continental slope foreset strata. Foreset strata are dominated by massive and chaotically stratified diamictites interbedded with massive and graded sandstones and mudstones. The sedimentary record and seismic stratigraphy is consistent with deposition on a continental slope from debris flows and turbidity currents released from a glacial source. Data from Sites 1097 and 1103 suggest the importance of aggradation of the Antarctic Peninsula continental shelf by tilt deposition and progradation of the slope by mass flow. This may provide a model for the interpretation of Palaeozoic and Proterozoic glacial successions that accumulated on glacially influenced continental margins.

Trace fossils and sedimentary facies from a Late Cambrian‐Early Ordovician tide‐dominated shelf (Santa Rosita Formation, northwest Argentina): Implications for ichnofacies models of shallow marine successions

USGS Publications Warehouse

Mángano, M. Gabriela; Buatois, Luis A.; Aceñolaza, Guillermo F.

1996-01-01

The Santa Rosita Formation is one the most widely distributed lower Paleozoic units of northwest Argentina. At the Quebrada del Salto Alto section, east of Purmamarca, Jujuy Province, it is represented by four sedimentary facies: thick‐bedded planar cross‐stratified quartzose sandstones (A), thin‐bedded planar cross‐stratified quartzose sandstones and mudstones (B), wave‐rippled sandstones and bioturbated mudstones (C), and black and greenish gray shales (D). Paleocurrent data, sandstone architecture, and sedimentary structures from faciès A and B indicate bipolar/bimodal paleoflows, suggesting the action of tidal currents. The succession is interpreted as that of a tide‐dominated shelf, with only secondary influence of wave processes. Trace fossils are restricted to facies B and C.The Cruziana ichnocoenosis is preserved on the soles of thin‐bedded planar cross‐stratified quartzose sandstones (faciès B). This ichnocoenosis consists of Conostichus isp., Cruziana omanica, C. semiplicata, C. cf. tortworthi, Cruziana isp. Helminthopsis abeli, Monomorphichnus bilinearis, M. multilineatus, Palaeophycus tubularis, Rusophycus carbonarias, R. latus, and R. isp. The occurrence of Cruziana semiplicata, C. omanica, C. cf. tortworthi, and Rusophycus latus supports a Late Cambrian‐Tremadoc age. Slabbing of Cruziana shows complex interactions between biologic and sedimentologic processes, and suggests a predominance of exhumed traces, washed out and recast by tractive sand deposition. Sandstone soles are densely packed with biogenic structures and exhibit distinctive clusters of Rusophycus isp. that most likely represent trilobite nesting burrows. The Cruziana ichnocoenosis records the resident fauna of a protected, lower intertidal to subtidal interbar setting.The Skolithos ichnocoenosis is represented by high to low density vertical burrows of Skolithos linearis, which extend downwards to the quartzose sandstone soles of faciès B and cross the Cruziana ichnocoenosis. The Skolithos ichnocoenosis represents colonization by suspension‐feeding organisms following a major change in environmental conditions, related to the migration of lower intertidal to subtidal sandwaves.The Planolites ichnocoenosis consists exclusively of Planolites montanus within mudstones overlying wave‐rippled sandstones (facies C). The Planolites ichnocoenosis records opportunistic colonization by inf aunal deposit feeders that mined the organic‐rich fine‐grained sediment during the waning phase of storms that scoured organic detritus from the sea bottom.The section records, from base to top, a Cruziana‐Skolithos ichnofacies zone, a Skolithos ichnofacies zone and an unbioturbated zone typified by the thick‐bedded cross‐stratified quartzose sandstone (fades A). This trend reflects progressively higher energy conditions linked to the establishment of a large sand wave complex. The presence of a mixed Cruziana‐Skolithos ichnofacies in the lower interval reflects changes in substrate and energy levels, rather than water depth. Accordingly, contrasting ichnocoenoses from interbars (Cruziana) and sandwaves (Skolithos) must be considered an example of ichnofacies controlled by local parameters instead of general bathymétrie trends. Conversely, the vertical replacement of the Cruziana ichnofacies by the Skolithos ichnofacies towards the middle interval of the section reflects the environmental changes associated with the transition between the intertidal and subtidal zones. As overall tidal energy increases from supratidal to subtidal settings, the Skolithos ichnofacies tends to occur seaward of the Cruzianaichnofacies in tide‐dominated shallow marine environments. Therefore, onshore‐offshore ichnofacies replacement in tide‐dominated shallow seas is opposite to that in wave‐dominated marine settings.

Unusual occurrence of some sedimentary structures and their significance in Jurassic transgressive clastic successions of Northern Ethiopia

NASA Astrophysics Data System (ADS)

Dubey, N.; Bheemalingeswara, K.

2009-04-01

Mesozoic sedimentary successions produced by marine transgression and regression of sea in northeastern part of Africa are well preserved in Mekelle basin of Ethiopia. Here, a typical second order sequence is well developed and preserved overlying the Precambrian basement rocks or patchy Palaeozoic sedimentary successions. Initiation of Mesozoic sedimentation in Mekelle basin has started with deposition of Adigrat Sandstone Formation (ASF). It is a retrogradational succession of siliciclastics in coastline/beach environment due to transgression of sea from southeast. ASF is followed by Antallo Limestone Formation (ALF)- an aggradational succession of carbonates in tidal flat environment; Agula Shale/Mudstone Formation (AMF); and Upper/Ambaradom Sandstone Formation (USF)- a progradational succession formed during regression in ascending order (Dubey et al., 2007). AMF is deposited in a lagoonal evaporatic environment whereas USF in a fluvial coastal margin. ASF is an aggregate of cyclically stacked two lithologies ASF1 and ASF2 produced by sea-level rise and fall of a lower order mini-cycle. ASF1 is a thick, multistoried, pink to red, friable, medium to fine grained, cross-bedded sandstone deposited in a high energy environment. ASF2 is a thin, hard and maroon colored iron-rich mudstone (ironstones) deposited in a low energy environment. ASF1 has resulted during regressive phase of the mini-cycle when rate of sedimentation was extremely high due to abundant coarser clastic supply from land to the coastal area. On the other hand, ASF2 has resulted during transgressive phase of the mini-cycle which restricted the supply of the coarser clastic to the coastal area and deposited the muddy ferruginous sediments in low energy offshore part of the basin where sedimentation rate was very low. Apart from these two major lithologies, there are also few other minor lithologies like fine-grained white sandstone, carbonate (as bands), claystone and mudstone present in ASF. ASF is a well developed lithostratigraphic unit of northern Ethiopia and represents the Jurassic transgressive clastic succession of Mekelle basin. The physical and biogenic sedimentary structures reported in this paper are observed from the terminal part of ASF. Their occurrence is unusual, rare, unknown so far and unreported. It includes (i) mud cracks (including their casts filled with overlying lithology) representing subaerial exposure which is unusual during transgressive phase, (ii) vertical traces of Skolithos burrows in ASF2 produced by suspension feeders in high energy environment of deposition (Dubey et al., 2007), (iii) tiny bivalve moulds and casts (external- and internal-moulds) of body fossils, and (iv) elliptical negative epirelief (potato shaped empty depressions - external moulds of eggs or nodules?). Fifty two such randomly oriented external moulds are noticed within 2 m2 area on an upper bedding plane of thin, white and fine- grained sandstone. Their in- fills are missing/removed as they are present on a gently dipping bed. Therefore, it is difficult to ascertain their biogenic (egg) or abiogenic (nodule) origin. Their detail investigation is under progress. Since ASF developed during marine transgression, presence of mud cracks in its terminal part indicates subaerial exposure. This provides suitable sites for nesting eggs (reptile?) in wet sands. Removal of such preserved eggs can provide potato depressions. Though it is difficult to relate these moulds to the eggs because of the missing in-fills, their shape, size and restricted occurrence supports biogenic origin. Reference Dubey, N., Bheemalingeswara, K. and Tadesse, N. (2007). Sedimentology and lithostratigraphy of the Mesozoic successions of Mekelle Basin, Ethiopia, Norteastern Africa. Geophysical Research Abstracts, Vol.9, 11471. (SRef-ID: 1607-7962/gra/EGU2007-A-11471).

Sedimentary Rocks Associated with the Coal Seams of the Saddle Beds from the Chwałowice Trough - West Part of Upper Silesian Coal Basin / Skały Osadowe Towarzyszące Pokładom Węgla Warstw Siodłowych Niecki Chwałowickiej - Zachodnia Część Górnośląskiego Zagłębia Węglowego

NASA Astrophysics Data System (ADS)

Stanienda, Katarzyna

2015-03-01

The results of investigation of the associated rocks with the Saddle Beds Coals Seams from Chwałowice Trough were presented in this article. The results of researches show that sandstones and mudstones dominate in the investigating profile. Claystones are situated mainly in ceilings and floors of coal seams. Grains of sandstones include mainly quartz, feldspars, micas and also quartzite's and gneiss's fragments. It is also possible to observe small grains of heavy minerals. Some of sandstones present bad compactness and are destroyed during transportation. This feature is connected with presence of little quantity of cement, especially in medium grained sandstones, which include more matrix than typical cement. The cement is built mainly of clay minerals, kaolinite and illite, carbonates and chalcedony but X-ray diffraction confirmed also the presence of halite in the cement of investigated sandstones. Mudstones and claystones are composed mainly of clay minerals. It's also possible to find quartz and micas there. Higher amounts of quartz and micas are possible to find rather in mudstones. The associated rocks with the Saddle Beds Coal Seams from Chwałowice Trough include also organic matter. W artykule przedstawiono wyniki badań skał towarzyszących pokładom węgla warstw siodłowych Niecki Chwałowickiej. Wyniki badań wskazują, że w badanym profilu dominują piaskowce oraz mułowce. Iłowce natomiast występują głównie w stropach i spągach pokładów węgla. Okruchy piaskowców to głównie ziarna kwarcu, skaleni, mik oraz fragmenty kwarcytów i gnejsów. Można tu również zaobserwować drobne okruchy minerałów ciężkich. Niektóre piaskowce charakteryzują się obniżoną zwięzłością i podczas transportu ulegają rozpadowi. Cecha ta związana jest z niewielką ilością spoiwa, szczególnie w piaskowcach średnioziarnistych, w których matrix przeważa nad typowym cementem. Spoiwo zbudowane jest głównie z minerałów ilastych, takich jak kaolinit i illit, węglanów i chalcedonu, chociaż wyniki dyfraktometrii rentgenowskiej potwierdziły występowanie w spoiwie badanych piaskowców również halitu. Na podstawie składu mineralnego piaskowców, dokonano ich klasyfikacji, stosując podziały skał okruchowych Krynina (1948) i Pettijohn'a-Potter'a-Siever'a (1973). Według klasyfikacji Krynina badane piaskowce reprezentują szarogłazy (szarowaki). W klasyfikacji Pettijohn'a, próbki 6, 8 i 13 reprezentują arenity lityczne, natomiast próbki 3 i 10- waki. Mułowce i iłowce zbudowane SA głównie z minerałów ilastych. Można w nich również spotkać ziarna kwarcu oraz miki. Wyższy udział kwarcu i mik jest jednak charakterystyczny dla mułowców. Skały towarzyszące pokładom węgla warstw siodłowych Niecki Chwałowickiej zawierają również domieszki substancji organicznej.

Geohydrology and conceptual model of a ground-water-flow system near a Superfund site in Cheshire, Connecticut

USGS Publications Warehouse

Stone, J.R.; Barlow, P.M.; Starn, J.J.

1996-01-01

Degradation of ground-water quality has been identified in an area of the north-central part of the town of Cheshire, Connecticut. An investigation by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, was done during 1994-95 to characterize the unconsolidated glacial deposits and the sedimentary bedrock, integrate the local geohydrologic conditions with the regional geohydrologic system, and develop a conceptual understanding of ground-water flow in the study area. A regional ground-water-flow model developed for the region near the study area indicates that perennial streams, including Judd Brook and the Tenmile River, form hydrologic divides that separate the larger region into hydraulically independent flow systems. In the local study area, synoptic water-level measurements made in June 1995 indicate that ground water near the water table flows west and southwestward from the low hill on the eastern side of the area toward the pond and wetlands along Judd Brook. Water-level data indicate that there is good hydraulic connection between the unconsolidated materials and underlying fractured bedrock. Unconsolidated materials in the study area consist principally of glacial stratified deposits that are fine sand, silt, and clay of glaci- olacustrine origin; locally these overlie thin glacial till. The glacial sediments range in thickness from a few feet to about 25 ft in the eastern part of the study area and are as much as 100 ft thick in the western and southern part of the study area beneath the Judd Brook and Tenmile River valleys. Fluvial redbeds of the New Haven Arkose underlie the glacial deposits in the region; in the study area, the redbeds consist of (1) channel sandstone units, which are coarse sandstone to fine conglomerate, generally in 6- to 15-ft- thick sequences; and (2) overbank mudstone units, which are siltstone and silty sandstone with some fine sandstone, generally in 6- to 50-ft-thick sequences. Thin-bedded zones of siltstone that are particularly fissile are present locally within the mudstone units. Rock units strike northward and dip eastward at about 20. The eastward-dipping strata are cut by a consistent set of west to west-northwest dipping, high-angle fractures. These fractures are oriented perpendicular to bedding and are present mostly in the channel sandstone units, but locally extend into the mudstone units as well. Borehole-geophysical logging indicates that ground water flows along bedding planes in fissile zones and between fissile zones in high-angle fractures, which are perpendicular to bedding. The combined fracture types form an aquifer system in which ground water follows a stair-step flowpath, flowing horizontally through fissile zones and vertically through high-angle fractures. Heat-pulse flow meter measurements and borehole fluid-conductivity and temperature logs indicate that only a small subset of the fissile zones and some high-angle fractures are hydraulically significant. A generalized local-scale ground-water flow model based on a nonspecific, but realistic, rock and fracture geometry was developed for the study area. Simulations show that under nonpumping conditions at a hypothetical well located in the middle of the model, ground-water flow was separated into upper and lower zones in which flow paths differed but were generally from northeast to southwest. Several short-duration aquifer tests conducted in the study area indicate that there is good hydraulic connection in the fractures between the pumping well (CS-221) and two bedrock wells located approximately 100 ft to the north and south along bedding strike. During the short duration of the aquifer tests, there was no hydraulic connection in bedrock wells located to the east, perpendicular to the strike. A range of transmissivity of 27 to 46 ft2/d was calculated from the aquifer-test data for the fractured-bedrock aquifer at CS-221 and TH-2. Individual fracture zones identified by bo

Rainfall and Seasonal Movement of the Weeks Creek Landslide, San Mateo County, California

USGS Publications Warehouse

Wieczorek, Gerald F.; Reid, Mark E.; Jodicke, Walter; Pearson, Chris; Wilcox, Grant

2007-01-01

Introduction Many different types of landslide occur in the Santa Cruz Mountains of San Mateo County, Calif. (Brabb and Pampeyan, 1972); most slope movement is triggered by strong earthquakes, heavy rainfall, or shoreline erosion. In this area, shallow landslides of loose soil and rock, which may transform into debris flows, commonly occur during individual storms when rainfall exceeds a threshold of intensity and duration (Cannon and Ellen, 1985; Wieczorek and Sarmiento, 1988; Wilson and Wieczorek, 1995). In contrast, deeper rotational and translational slides (Varnes, 1978) typically begin to move only after days to weeks or months of heavy rain. Once started, they can continue to move for months during and after a heavy rainfall season, for example, the Scenic Drive landslide at La Honda, Calif. (Jayko and others, 1998; Wells and others, 2005, 2006). Although the rainfall characteristics triggering rapid, shallow landslides have been documented (Wieczorek, 1987; Cannon and Ellen, 1988), the rainfall conditions leading to repeated deeper-seated slope movements are less well known. The Weeks Creek landslide (Adam, 1975), near the western crest of the Santa Cruz Mountains north of La Honda in San Mateo County (fig. 1), consists of a large prehistoric section containing a historically active section; both sections have earthflow morphologies. The entire landslide mass, which extends about 1,000 m westward from an elevation of 220 m down to an elevation of 120 m, is about 300 to 370 m wide (Cole and others, 1994); The prehistoric section of the landslide is about 30 m deep and approximately 10 million m3 in volume (Cole and others, 1994). The smaller, historically active portion of the Weeks Creek landslide (fig. 1) is only approximately 500 m long, 200 m wide, and 13 m deep (Cole and others, 1994). Near the landslide, the Santa Cruz Mountains consist of tightly folded, Tertiary sedimentary bedrock materials of the Butano sandstone and San Lorenzo Formations (Eocene through Lower Oligocene). These sedimentary bedrock materials are locally intruded by Oligocene diabase and capped by Oligocene through Miocene basalt of the Mindego Formation (Brabb, 1980; Cole and others, 1994). Within the active landslide, as documented from multiple borings by Cole and others (1994), deeply weathered mudstone and sandstone of the San Lorenzo Formation extends to a depth of about 10 to 13 m, where the active shear zone is located. Beneath this, within the deeper prehistoric landslide, mudstone extends to a depth of about 24 to 32 m and is underlain by strong diabase bedrock. The basal rupture surface of the prehistoric landslide is located near the mudstone/diabase contact (Cole and others, 1994). The historically active section of the Weeks Creek landslide, which is crossed by the La Honda road (California Highway 84, fig. 1), was first noticed to partially move during the great 1906 San Francisco earthquake (Lawson, 1908). It has moved repeatedly over the ensuing years but generally only during wet rainy seasons. For some of these active years, ground cracks and lateral displacements were recorded by local residents Walter Jodicke and Chris Pearson, as well as by U.S. Geological Survey (USGS) personnel. In spring 2006, fresh ground cracks were noted in parts of the prehistoric, previously inactive section of the landslide. In this report, we present daily rainfall measurements from 1973 through 2006 obtained at the landslide site and summarize available observations of slope movement over that period. In addition, we present more detailed observations of rainfall, ground-water pressure, and slope movement for three water years spanning the period 1981-1984. We conclude with some preliminary observations about rainfall and slope movement at this site.

The sequence stratigraphy, sedimentology, and economic importance of evaporite carbonate transitions: a review

NASA Astrophysics Data System (ADS)

Sarg, J. F.

2001-04-01

World-class hydrocarbon accumulations occur in many ancient evaporite-related basins. Seals and traps of such accumulations are, in many cases, controlled by the stratigraphic distribution of carbonate-evaporite facies transitions. Evaporites may occur in each of the systems tracts within depositional sequences. Thick evaporite successions are best developed during sea level lowstands due to evaporative drawdown. Type 1 lowstand evaporite systems are characterized by thick wedges that fill basin centers, and onlap basin margins. Very thick successions (i.e. saline giants) represent 2nd-order supersequence set (20-50 m.y.) lowstand systems that cap basin fills, and provide the ultimate top seals for the hydrocarbons contained within such basins. Where slope carbonate buildups occur, lowstand evaporites that onlap and overlap these buildups show a lateral facies mosaic directly related to the paleo-relief of the buildups. This facies mosaic, as exemplified in the Silurian of the Michigan basin, ranges from nodular mosaic anhydrite of supratidal sabkha origin deposited over the crests of the buildups, to downslope subaqueous facies of bedded massive/mosaic anhydrite and allochthonous dolomite-anhydrite breccias. Facies transitions near the updip onlap edges of evaporite wedges can provide lateral seals to hydrocarbons. Porous dolomites at the updip edges of lowstand evaporites will trap hydrocarbons where they onlap nonporous platform slope deposits. The Desert Creek Member of the Paradox Formation illustrates this transition. On the margins of the giant Aneth oil field in southeastern Utah, separate downdip oil pools have accumulated where dolomudstones and dolowackestones with microcrystalline porosity onlap the underlying highstand platform slope. Where lowstand carbonate units exist in arid basins, the updip facies change from carbonates to evaporite-rich facies can also provide traps for hydrocarbons. The change from porous dolomites composed of high-energy, shallow water grainstones and packstones to nonporous evaporitic lagoonal dolomite and sabkha anhydrite occurs in the Upper Permian San Andres/Grayburg sequences of the Permian basin. This facies change provides the trap for secondary oil pools on the basinward flanks of fields that are productive from highstand facies identical to the lowstand dolograinstones. Type 2 lowstand systems, like the Smackover Limestone of the Gulf of Mexico, show a similar relationship. Commonly, these evaporite systems are a facies mosaic of salina and sabkha evaporites admixed with wadi siliciclastics. They overlie and seal highstand carbonate platforms containing reservoir facies of shoalwater nonskeletal and skeletal grainstones. Further basinward these evaporites change facies into similar porous platform facies, and contain separate hydrocarbon traps. Transgressions in arid settings over underfilled platforms (e.g. Zechstein (Permian) of Europe; Ferry Lake Anhydrite (Cretaceous), Gulf of Mexico) can result in deposition of alternating cyclic carbonates and evaporites in broad, shallow subaqueous hypersaline environments. Evaporites include bedded and palmate gypsum layers. Mudstones and wackestones are deposited in mesosaline, shallow subtidal to low intertidal environments during periodic flooding of the platform interior. Highstand systems tracts are characterized by thick successions of m-scale, brining upward parasequences in platform interior settings. The Seven Rivers Formation (Guadalupian) of the Permian basin typifies this transition. An intertonguing of carbonate and sulfates is interpreted to occur in a broad, shallow subaqueous hypersaline shelf lagoon behind the main restricting shelf-edge carbonate complex. Underlying paleodepositional highs appear to control the position of the initial facies transition. Periodic flooding of the shelf interior results in widespread carbonate deposition comprised of mesosaline, skeletal-poor peloid dolowackestones/mudstones. Progressive restriction due to active carbonate deposition and/or an environment of net evaporation causes brining upward and deposition of lagoonal gypsum. Condensed sections of organic-rich black lime mudstones occur in basinal areas seaward of the transgressive and highstand carbonate platforms and have sourced significant quantities of hydrocarbons.

Regional structural framework and petroleum assessment of the Brooks Range foothills and southern coastal plain, National Petroleum Reserve, Alaska

USGS Publications Warehouse

Potter, Christopher J.; Moore, Thomas E.; O'Sullivan, Paul B.; Miller, John J.

2002-01-01

The transects, along with other seismic-reflection examples, illustrate four play concepts being used in the deformed area for the 2002 U.S. Geological Survey oil and gas assessment of the National Petroleum Reserve-Alaska (NPRA). The Brookian topset structural play includes broad west-northwest-trending anticlines in the Cretaceous Nanushuk Group, developed above structurally thickened Torok mudstones in the incipiently-deformed, most northerly part of the thrust system. The Torok structural play includes prominent anticlines affecting deep-basin sandstones, many of which are detached from folds exposed at the surface. The Ellesmerian structural play includes closures developed in the clastic part of the Ellesmerian sequence, mainly above a detachment in the Shublik Formation. The thrust belt play includes antiformal stacks of allochthonous Endicott Group clastic rocks and Lisburne Group carbonates; these stacks were assembled at about 120 Ma, and were transported to their present positions in the foothills at about 60 Ma.

Stratigraphy and paleoenvironments of the Shell 410-1 well, Georges Bank Basin, US North Atlantic outer continental shelf

USGS Publications Warehouse

Poppe, L.J.; Poag, C.W.; Swift, B.A.

1995-01-01

The Shell 410-1 well is the most downdip (seaward) hydrocarbon exploratory well in the Georges Bank Basin. It was drilled to a total depth of 4745 m RKB, and penetrated a section composed of Middle Jurassic to Quaternary sedimentary rocks. The lithostratigraphy of the section is described. The strata penetrated by the Shell 410-1 well are more marine than rocks at the updip (landward) COST G-1, Exxon 975-1, COST G-2, and Conoco 145-1 well sites. Limestones and calcareous mudstones dominate at the Shell 410-1 site. Dolomite and anhydrite are much more abundant in the Bajocian-Callovian strata of the Shell 410-1 well, which is evidence that the carbonate-bank palaeoenvironments recorded in the Iroquois and Abenaki Formations were more restricted (less marine) here than 47 km to the west-northwest at the Mobil 312-1 well site near the edge of the Jurassic carbonate platform. -from Authors

Undiscovered oil and gas resources of Lower Silurian Qusaiba-Paleozoic total petroleum systems, Arabian Peninsula

USGS Publications Warehouse

Ahlbrandt, T.S.; Pollastro, R.M.; Schenk, C.J.

2002-01-01

The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered conventional oil and gas potential of 128 of the world’s petroleum provinces (U.S. Geological Survey World Energy Assessment Team, 2000). In each province, the USGS defined Total Petroleum Systems, and Assessment Units in each Total Petroleum System, and then quantitatively estimated the undiscovered conventional oil and gas resources. Of the eight global regions studied by the USGS, the Arabian Peninsula portion of the Middle East region was estimated to contain the greatest volumes of undiscovered oil and gas. The Lower Silurian Qusaiba Member of the Qalibah Formation is the source rock for some of the most important Total Petroleum Systems of the Middle East region. For example, the sources of the gas in the supergiant North field of Qatar and Iran and recent giant light oil discoveries in central Saudi Arabia were largely organic-rich, Qusaiba marine mudstones.

Total petroleum systems of the Illizi Province, Algeria and Libya; Tanezzuft-Illizi

USGS Publications Warehouse

Klett, T.R.

2000-01-01

Undiscovered conventional oil and gas resources were assessed within a total petroleum system of the Illizi Province (2056) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Illizi Province is in eastern Algeria and a small portion of western Libya. The province and its total petroleum system coincide with the Illizi Basin. Although several total petroleum systems may exist within the Illizi Province, only one “composite” total petroleum system is identified. This total petroleum system comprises a single assessment unit. The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. The total petroleum system was named after the oldest major source rock and the basin in which it resides. The estimated means of the undiscovered conventional petroleum volumes in the Tanezzuft-Illizi Total Petroleum System are 2,814 million barrels of oil (MMBO), 27,785 billion cubic feet of gas (BCFG), and 873 million barrels of natural gas liquids (MMBNGL).

Key Locations Studied at 'Pahrump Hills' on Mars

NASA Image and Video Library

2017-06-09

NASA's Curiosity Mars rover examined a mudstone outcrop area called "Pahrump Hills" on lower Mount Sharp, in 2014 and 2015. This view shows locations of some targets the rover studied there. The blue dots indicate where drilled samples of powdered rock were collected for analysis. The rover drilled a sample of rock powder at "Confidence Hills" in September 2014 and analyzed it with internal laboratory instruments. Then the mission conducted a walkabout survey up the slope, along the route indicated in yellow, stopping for close inspection at the red-dot locations. Observations from the walkabout were used to choose where to take additional drilled samples for analysis during a second pass up the slope. The "Mojave 2" sample was collected in January 2015 and the "Telegraph Peak" one in February 2015. This view of the outcrop and other portions of Mount Sharp beyond is a mosaic of images taken by the rover's Mast Camera (Mastcam) in September 2014. https://photojournal.jpl.nasa.gov/catalog/PIA21709

Genesis analysis of high-gamma ray sandstone reservoir and its log evaluation techniques: a case study from the Junggar basin, northwest China.

PubMed

Wang, Liang; Mao, Zhiqiang; Sun, Zhongchun; Luo, Xingping; Song, Yong; Liu, Zhen

2013-01-01

In the Junggar basin, northwest China, many high gamma-ray (GR) sandstone reservoirs are found and routinely interpreted as mudstone non-reservoirs, with negative implications for the exploration and exploitation of oil and gas. Then, the high GR sandstone reservoirs' recognition principles, genesis, and log evaluation techniques are systematically studied. Studies show that the sandstone reservoirs with apparent shale content greater than 50% and GR value higher than 110API can be regarded as high GR sandstone reservoir. The high GR sandstone reservoir is mainly and directly caused by abnormally high uranium enrichment, but not the tuff, feldspar or clay mineral. Affected by formation's high water sensitivity and poor borehole quality, the conventional logs can not recognize reservoir and evaluate the physical property of reservoirs. Then, the nuclear magnetic resonance (NMR) logs is proposed and proved to be useful in reservoir recognition and physical property evaluation.

Genesis Analysis of High-Gamma Ray Sandstone Reservoir and Its Log Evaluation Techniques: A Case Study from the Junggar Basin, Northwest China

PubMed Central

Wang, Liang; Mao, Zhiqiang; Sun, Zhongchun; Luo, Xingping; Song, Yong; Liu, Zhen

2013-01-01

In the Junggar basin, northwest China, many high gamma-ray (GR) sandstone reservoirs are found and routinely interpreted as mudstone non-reservoirs, with negative implications for the exploration and exploitation of oil and gas. Then, the high GR sandstone reservoirs' recognition principles, genesis, and log evaluation techniques are systematically studied. Studies show that the sandstone reservoirs with apparent shale content greater than 50% and GR value higher than 110API can be regarded as high GR sandstone reservoir. The high GR sandstone reservoir is mainly and directly caused by abnormally high uranium enrichment, but not the tuff, feldspar or clay mineral. Affected by formation's high water sensitivity and poor borehole quality, the conventional logs can not recognize reservoir and evaluate the physical property of reservoirs. Then, the nuclear magnetic resonance (NMR) logs is proposed and proved to be useful in reservoir recognition and physical property evaluation. PMID:24078797

Sulphur-bearing Compounds Detected by MSL SAM Evolved Gas Analysis of Materials from Yellowknife Bay, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

McAdam, A. C.; Franz, H. B.; Archer, P. D. Jr.; Sutter, B.; Eigenbrode, J. L.; Freissinet, C.; Atreya, S. K.; Bish, D. L.; Blake, D. F.; Brunner, A.;

Facies development and paleoenvironment of the Hajajah Limestone Member, Aruma Formation, central Saudi Arabia

NASA Astrophysics Data System (ADS)

El-Sorogy, Abdelbaset S.; Ismail, Abdelmoneim; Youssef, Mohamed; Nour, Hamdy

2016-12-01

The Campanian Hajajah Limestone Member of the Aruma Formation was formed during two regressive episodes. Each of them formed of three depositional facies, from base to top: 1) intra-shelf basin facies, made up of fossiliferous green shale and mudstone with ostracods and badly preserved foraminifers. 2) fore-reef facies, consists of hard, massive, marly coralline limestone. The upper part is rich with low divers, badly to moderate preserved, solitary and colonial corals, and, 3) back reef and near-shore facies, consists of fossiliferous sandy dolomitized, bioturbated limestone with abundant reworked corals, bivalves, gastropods, and aggregate grains. On the basis of field observations, micro-and macrofossils and microfacies analysis, the Hajajah Limestone Member was deposited in distal marine settings below storm wave base in a low-energy environment changed upward to fore-reef framework in an open marine environment with moderate to high energy conditions and terminated with shallow marine facies with accumulation of skeletal grains by storms during regression.

The magnetic fabrics of experimentally deformed artificial clay-water dispersions

NASA Astrophysics Data System (ADS)

Richter, Carl; Frisch, Wolfgang; Ratschbacher, Lothar; Schwarz, Hans-Ulrich

1991-12-01

The development of magnetic fabrics in artificial clay-water dispersions and natural, hematite-bearing mudstones is investigated in plane-strain pure shear laboratory experiments under strain rates of 1.6 × 10 -5 and 2 × 10 -4s-1. The mixtures contain 0,15, 30 and 45% chlorite in an illite matrix, and 0, 1, 3, 6 and 8% magnetite in a kaolin matrix. Shortening up to 40% is imposed. The resulting fabrics show the following characteristics: (1) In the clay mixtures, the principal susceptibility axes ( kmax ≥ kint ≥ kmin) rotate away from the well defined initial fabric orientations into the princip strain directions ( e1 ≥ e2 ≥ e3) at strains > 30%. (2) Both mineralogical composition and initial magnetic fabric, but not the applied strain, influence the magnitudes of the principal susceptibility axes. (3) The illite-chlorite mixture series show an almost linear correlation between mineral concentration and susceptibility magnitudes. (4) Magnetite dominates the fabric of the magnetite-kaolin mixtures; the fabric is independent of the magnetite concentration.

Study on fracture identification of shale reservoir based on electrical imaging logging

NASA Astrophysics Data System (ADS)

Yu, Zhou; Lai, Fuqiang; Xu, Lei; Liu, Lin; Yu, Tong; Chen, Junyu; Zhu, Yuantong

2017-05-01

In recent years, shale gas exploration has made important development, access to a major breakthrough, in which the study of mud shale fractures is extremely important. The development of fractures has an important role in the development of gas reservoirs. Based on the core observation and the analysis of laboratory flakes and laboratory materials, this paper divides the lithology of the shale reservoirs of the XX well in Zhanhua Depression. Based on the response of the mudstone fractures in the logging curve, the fracture development and logging Response to the relationship between the conventional logging and electrical imaging logging to identify the fractures in the work, the final completion of the type of fractures in the area to determine and quantify the calculation of fractures. It is concluded that the fracture type of the study area is high and the microstructures are developed from the analysis of the XX wells in Zhanhua Depression. The shape of the fractures can be clearly seen by imaging logging technology to determine its type.

An overview of the Permian (Karoo) coal deposits of southern Africa

NASA Astrophysics Data System (ADS)

Cairncross, B.

2001-08-01

The coal deposits of southern Africa (Botswana, Malawi, Mozambique, Namibia, South Africa, Swaziland, Tanzania, Zambia and Zimbabwe) are reviewed. The coal seams formed during two periods, the Early Permian (Artinskian-Kungurian) and the Late Permian (Ufimian-Kazanian). The coals are associated with non-marine terrestrial clastic sedimentary sequences, most commonly mudrock and sandstones, assigned to the Karoo Supergroup. The Early Permian coals are most commonly sandstone-hosted while the younger coals typically occur interbedded with mudstones. The sediments were deposited in varying tectono-sedimentary basins such as foreland, intracratonic rifts and intercratonic grabens and half-grabens. The depositional environments that produced the coal-bearing successions were primarily deltaic and fluvial, with some minor shoreline and lacustrine settings. Coals vary in rank from high-volatile bituminous to anthracite and characteristically have a relatively high inertinite component, and medium- to high-ash content. In countries where coal is mined, it is used for power generation, coking coal, synfuel generation, gasification and for (local) domestic household consumption.

Quasi-planer-laminated sandstone beds of the Lower Cretaceous Bootlegger Member, north-central Montana: Evidence of combined-flow sedimentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnott, R.W.C.

1993-05-01

Lower-shoreface to shallow-shelf strata of the Bootlegger Member of the Lower Cretaceous Blackleaf Formation are characterized by interbedded sandstone and mudstone. Sandstone beds are characterized by a peculiar planar lamination showing a subtle although perceptible undulation; spacing-to-height ratios of the undulation are generally 100 or more. Typically the undulation shows no evidence of lateral accretion but only vertical aggradation, and as a result most beds consist of a single laminaset. Aspects of quasi-planar-laminated beds indicate single-event storm sedimentation, and paleocurrent data indicate offshore sediment transport. By its sedimentary characteristics and its similarity with a bed configuration generated in an experimentalmore » wave duct, quasi-planar lamination is produced by high-energy combined flows. This style of stratification should be common in the shallow-marine stratigraphic record, and its recognition should aid in interpreting high-energy, combined-flow depositional events.« less

Modern and late Holocene dolomite formation: Manito Lake, Saskatchewan, Canada

NASA Astrophysics Data System (ADS)

Last, Fawn M.; Last, William M.; Halden, Norman M.

2012-12-01

Major advances have occurred in our understanding of modern dolomite formation and penecontemporaneous dolomitization over the past several decades. Manito Lake, located in west-central Saskatchewan, Canada, is a large (65 km2), deep (zmax: 22 m) perennial saline (~ 45 ppt TDS) lake in which modern and late Holocene dolomite coexists with other endogenic and authigenic carbonate precipitates, including aragonite, monohydrocalcite, calcite, and Mg-calcite. Like many other lacustrine dolomites, Manito Lake dolomite is microcrystalline (less than 1 μm to 5 μm), Ca-rich and poor to moderately ordered. It occurs as relatively pure hardgrounds and as a component of nearshore microbialites. It also forms isopachous cements in consolidated siliciclastic shoreline sediments. Manito Lake dolomite is most likely forming by mainly biomediated precipitation at or near the sediment-water interface (i) in pore spaces of coarse siliciclastic sediments (i.e., beachrock), (ii) as fine laminae associated with microbialites, and (iii) as a major component of mudstone hardgrounds and pavements.

Peritidal cyclic sedimentation from La Manga Formation (Oxfordian), Neuquén Basin, Mendoza, Argentina

NASA Astrophysics Data System (ADS)

Palma, Ricardo M.; Kietzmann, Diego A.; Bressan, Graciela S.; Martín-Chivelet, Javier; López-Gómez, José; Farias, María E.; Iglesias Llanos, María P.

2013-11-01

The La Manga Formation consists of marine carbonates and represents most of the sedimentary record of the Callovian-Oxfordian in the Neuquén Basin. Three localities in the southern Mendoza province were studied and their cyclicity was determined by means of facies analysis and their vertical arrangement. Facies of inner ramp, that were deposited in extremely shallow-water environments with intermittent subaerial exposures have been broken down into shallow subtidal, and intertidal-supratidal environments. Shallow subtidal facies are arranged into decimetre scale upward-shallowing cycles composed of marls, laminated or massive mudstones or bioclastic wackestones and intraclastic wackestone-packstones. Intertidal-supratidal centimetre-scale cycles consist of an upward-shallowing succession of restricted facies, overlaid by horizontal or crinkle microbial laminites, flat pebble conglomerates or breccias beds. The defined cycles show a shallowing upward trend in which the evidence of relative sea-level lowering is accepted. The interpretation of Fischer plots allowed the recognition of changes in accommodation space.

Nanophase Carbonates on Mars: Formation, Detection, and Implications

NASA Technical Reports Server (NTRS)

Archer, P. D.; Lauer, H. V.; Ming, D. W.; Niles, P. B.; Morris, R. V.; Rampe, E. B.; Sutter, B.

2014-01-01

Despite having an atmosphere composed primarily of CO2 and evidence for abundant water in the past, carbonate minerals have only been discovered on Mars in small amounts in martian dust, in soils in the Northern Plains, and in outcrops of limited spatial extent. Recently, carbonates have been identified as the possible source of CO2 released during thermal analysis of material from an aeolian deposit named Rocknest and drilled sample from the sheepbed mudstone, both samples analyzed by the Mars Science Laboratory (MSL) in Gale Crater. Both the Phoenix lander and MSL carry thermal analysis instruments, the Thermal and Evolved Gas Analyzer (TEGA) on Phoenix and the Sample Analysis at Mars (SAM) instrument on MSL. While thermal analysis does not provide definitive mineralogy, it can detect volatile-bearing minerals present at very low abundance and the temperature profiles of evolved gases can reveal physical properties of the sample. For example, the decomposition temperature of volatilebearing minerals depends heavily on the particle size of the mineral.

Lithology, reservoir properties, and burial history of portion of Gammon Shale ( Cretaceous), southwestern North Dakota.

USGS Publications Warehouse

Gautier, D.L.

1981-01-01

In the northern Great Plains, large quantities of biogenic methane are contained at shallow depths in Cretaceous marine mudstones. The Gammon Shale and equivalents of the Milk River Formation in Canada are typical. At Little Missouri field, Gammon reservoirs consist of discontinuous lenses and laminae of siltstone, enclosed by silty clay shale. Large amounts of allogenic clay, including highly expansible mixed-layer illite-smectite cause great water sensitivity and high water-saturation values. Studies show that the Gammon has not undergone thermal conditions sufficient for oil or thermal gas generation. The scarcity of authigenic silicates suggests that diagenesis has been inhibited by the presence of free methane. Shale layers are practically impermeable whereas siltstone microlenses are porous (30-40%) and have permeabilities on the order of 3-30 md. Organic matter in the low-permeability reservoirs served as the source of biogenic methane, and capillary forces acted as the trapping mechanism for gas accumulation. Much of the Gammon interval is potentially economic. -from Author

Factors that influence the extraction of polycyclic aromatic hydrocarbons from coal

USGS Publications Warehouse

Xue, J.; Liu, Gaisheng; Niu, Z.; Chou, C.-L.; Qi, C.; Zheng, Lingyun; Zhang, H.

2007-01-01

Coal samples and carbonaceous mudstone were collected from the Huaibei coalfield, China, and experiments investigating the factors influencing the extraction of the sixteen US EPA (Environmental Protection Agency) priority polycyclic aromatic hydrocarbons (PAHs) were carried out. Different extraction times, solvents, and methods were used. Major interest was focused on finding optimum conditions for extracting the PAHs from coal. We conclude that (1) coal composition, including the H/C and O/C ratios, is an important factor for the distribution of PAHs in coals; (2) the total amount of EPA priority PAHs increases with increasing extraction time, 30 min being suitable for ultrasonic-assisted extraction and 24 h for Soxhlet extraction; (3) CS2 is effective in extracting low molecular weight PAHs, while CH2Cl2 is better for extracting high molecular weight PAHs (both are excellent extraction solvents vs hexane); (4) both Soxhlet and ultrasonic extraction showed a similar PAH concentration profile, but the ultrasonic method is less efficient. ?? 2007 American Chemical Society.

Developing a shale heterogeneity index to predict fracture response in the Mancos Shale

NASA Astrophysics Data System (ADS)

DeReuil, Aubry; Birgenheier, Lauren; McLennan, John

2017-04-01

The interplay between sedimentary heterogeneity and fracture propagation in mudstone is crucial to assess the potential of low permeability rocks as unconventional reservoirs. Previous experimental research has demonstrated a relationship between heterogeneity and fracture of brittle rocks, as discontinuities in a rock mass influence micromechanical processes such as microcracking and strain localization, which evolve into macroscopic fractures. Though numerous studies have observed heterogeneity influencing fracture development, fundamental understanding of the entire fracture process and the physical controls on this process is still lacking. This is partly due to difficulties in quantifying heterogeneity in fine-grained rocks. Our study tests the hypothesis that there is a correlation between sedimentary heterogeneity and the manner in which mudstone is fractured. An extensive range of heterogeneity related to complex sedimentology is represented by various samples from cored intervals of the Mancos Shale. Samples were categorized via facies analysis consisting of: visual core description, XRF and XRD analysis, SEM and thin section microscopy, and reservoir quality analysis that tested porosity, permeability, water saturation, and TOC. Systematic indirect tensile testing on a broad variety of facies has been performed, and uniaxial and triaxial compression testing is underway. A novel tool based on analytically derived and statistically proven relationships between sedimentary geologic and geomechanical heterogeneity is the ultimate result, referred to as the shale heterogeneity index. Preliminary conclusions from development of the shale heterogeneity index reveal that samples with compositionally distinct bedding withstand loading at higher stress values, while texturally and compositionally homogeneous, bedded samples fail at lower stress values. The highest tensile strength results from cemented Ca-enriched samples, medial to high strength samples have approximately equivalent proportions of Al-Ca-Si compositions, while Al-rich samples have consistently low strength. Moisture preserved samples fail on average at approximately 5 MPa lower than dry samples of similar facies. Additionally, moisture preserved samples fail in a step-like pattern when tested perpendicular to bedding. Tensile fractures are halted at heterogeneities and propagate parallel to bedding planes before developing a through-going failure plane, as opposed to the discrete, continuous fractures that crosscut dry samples. This result suggests that sedimentary heterogeneity plays a greater role in fracture propagation in moisture preserved samples, which are more indicative of in-situ reservoir conditions. Stress-strain curves will be further analyzed, including estimation of an energy released term based on post-failure response, and an estimation of volume of cracking measure on the physical fracture surface.

Magnetostratigraphy of the Lower Cretaceous Hekou and Liupanshan Group in NW China and its Implications for the Composite of the Cretaceous Normal Superchron (cns)

NASA Astrophysics Data System (ADS)

Dai, S.; Yan, N.; Luo, L.; Jenkyns, H. C.; Mac Niocaill, C.; Tang, Y.; Peng, D.; Wang, W.

2015-12-01

Are the short reversed-polarity subzones of the Cretaceous Normal Superchron (CNS) recorded in non-marine deposits? And, if so, how long did they last? These questions have been a matter of debate for some time. Lower Cretaceous terrestrial deposits in NW China, provide an opportunity to examine this problem. Here we present high-resolution magnetostratigraphic results for two Lower Cretaceous successions, the Liupanshan Group (Liupanshan Basin) and the Hekou Group (Longzhong Basin), NW China, and propose a minor revision for the CNS. The Liupanshan Group is a ~1300-m thick succession and comprises the alluvial-fluvial- lacustrine clastic sediments and carbonate rocks and gypsiferous mudstones. Samples from 457 levels were measured on the 2G cryogenic magnetometer after demagnetization. Six normal-polarity and five reversed-polarity magnetozones were obtained, which are correlated with the M3n to the M-'2r' of the GPTS of Gradstein (2012). The paleomagnetic data allow us to assign the Liupanshan Group to the interval from 131 Ma to 106 Ma (Barremian to Late Albian). The Hekou Group is 3700-m thick and consists of fluvial, lacustrine and deltaic sandstones, mudstones, conglomerates. 28 normal-polarity and 27 reversed-polarity magnetozones were observed from the thermal demagnetization for ~ 800 samples, and they can be reasonably correlated to the M15 thorough M-"2r" of GPTS of Gradstein (2012). This correlation yields an age control for the Hekou Group of 139-106 Ma (Valanginian- Albian). The different basal age of these two basins indicates that the Hekou Basin was initially developed prior to the Liupanshan Basin, but they stopped to develop almost at the same time. We found a short minus magnetozone in the upper part of the two groups, lying between M-'1r' and M-'2r' of the C34 of GPTS, equivalent to the reversed-polarity subzone (G2003) reported by Gilder et al. (2003) in a basalt from the Tuoyun Basin, NW China. Finally, we propose an alternative version for the C34 (CNS), i.e., the CNS comprises five normal subchrons (labeled as C34n.1n to C34n.5n) which are separated by four minus subchrons (including M'-1r' (ISEA), G2003, M'-2r' and M'-3r'). We firstly and clearly confirm the duration of G2003 as 0.2 Myr and M'-2r' as 1.5 Myr. Acknowledgement: This study was supported by Chinese NSF (No. 41272127)

Using Geophysics to Define Hydrostratigraphic Units in the Edwards and Trinity Aquifers, Texas

NASA Astrophysics Data System (ADS)

Smith, B. D.; Blome, C. D.; Clark, A. K.; Kress, W.; Smith, D. V.

2007-05-01

Airborne and ground geophysical surveys conducted in Uvalde, Medina, and northern Bexar counties, Texas, can be used to define and characterize hydrostratigraphic units of the Edwards and Trinity aquifers. Airborne magnetic surveys have defined numerous Cretaceous intrusive stocks and laccoliths, mainly in Uvalde County, that influence local hydrology and perhaps regional ground-water flow paths. Depositional environments in the aquifers can be classified as shallow water platforms (San Marcos Platform, Edwards Group), shoal and reef facies (Devils River Trend, Devils River Formation), and deeper water basins (Maverick Basin, West Nueces, McKnight, and Salmon Peak Formations). Detailed airborne and ground electromagnetic surveys have been conducted over the Edwards aquifer catchment zone (exposed Trinity aquifer rocks), recharge zone (exposed Edwards aquifer rocks), and artesian zone (confined Edwards) in the Seco Creek area (northeast Uvalde and Medina Counties; Devils River Trend). These geophysical survey data have been used to divide the Edwards exposed within the Balcones fault zone into upper and lower hydrostratigraphic units. Although both units are high electrical resistivity, the upper unit has slightly lower resistivity than the lower unit. The Georgetown Formation, at the top of the Edwards Group has a moderate resistivity. The formations that comprise the upper confining units to the Edwards aquifer rocks have varying resistivities. The Eagleford and Del Rio Groups (mainly clays) have very low resistivities and are excellent electrical marker beds in the Seco Creek area. The Buda Limestone is characterized by high resistivities. Moderate resistivities characterize the Austin Group rocks (mainly chalk). The older Trinity aquifer, underlying the Edwards aquifer rocks, is characterized by less limestone (electrically resistive or low conductivity units) and greater quantities of mudstones (electrically conductive or low resistivity units). In the western area (Devils River Trend and Maverick Basin) of the Trinity aquifer system there are well-defined collapse units and features that are marked by moderate resistivities bracketed by resistive limestone and conductive mudstone of the Glen Rose Limestone. In the central part of the aquifer (San Marcos Platform) the Trinity's lithologies are divided into upper and lower units with further subdivisions into hydrostratigraphic units. These hydrostratigraphic units are well mapped by an airborne electromagnetic survey in Bexar County. Electrical properties of the Edwards aquifer also vary across the fresh-saline water interface where ground and borehole electrical surveys have been conducted. The saline- saturated Edwards is predictably more conductive than the fresh-water saturated rocks. Similar fresh-saline water interfaces exist within the upper confining units of the Edwards aquifer (Carrizo-Wilcox aquifer) and the Trinity aquifer rocks.

The stratigraphic distribution of large marine vertebrates and shell beds in the Pliocene of Tuscany

NASA Astrophysics Data System (ADS)

Dominici, Stefano; Benvenuti, Marco; Danise, Silvia

2015-04-01

The record of 337 shark fossils, 142 cetaceans and 10 sea cows from the Pliocene of Tuscany, mostly from historical museum collections, is revised. The majority of these fossils are concentrated at a few geographic sites from separated hinterland basins, on the South-Western side of the Northern Apennines. To better understand the meaning of these concentrations, the sequence stratigraphic distribution of more recent findings of large marine vertebrates is reconstructed against a high-resolution framework based on sedimentary facies analysis. These remains are usually covered by, or included in mudstones deposited far from the coast (N=12), skeletons being usually articulated, slightly displaced, and often bioeroded. A minor part of better preserved articulated skeletons is associated with sandstones from deltaic paleonenvironments (N=2). Marine mammal and shark remains may be associated with laterally-continuous shell accumulations, a type of concentration occurring at maximum flooding surfaces, separating relatively coarse-grained facies from open marine mudstones. Shell beds were bulk-sampled at 66 locations from six basins, covering a wide range of sedimentary facies, and spanning a chronologic interval of about 2.5 million years. A dataset of 62,655 mollusc specimens belonging to 496 species formed the basis of a statistical study to reconstruct the structure of the benthic communities, and to estimate paleodepths from intertidal to upper bathyal settings. Mollusc associations closely mirror the distribution of sedimentary facies, allowing for a fine tuning of the sequence stratigraphic architecture. Merging paleogeographic, stratigraphic and paleoecologic data, we conclude that the more abundant and diverse accumulations of large vertebrates took place in settings under the influence of coastal upwelling. A modern analogue occurs today in the Ligurian Sea, on the Tuscan offshore, where abundant nutrients carried by deep-marine currents of Western origin, within an otherwise oligotrophic Mediterranean Sea, sustain a rich and diverse cetacean and shark, epipelagic and mesopelagic community. The modern steep bathymetric gradient was displaced towards the East during the Pliocene, before the latest phases of uplift of the Northern Apennines. An open marine, nutrient-rich ecosystem influenced hinterland basins during major transgressive pulses, leading to a higher productivity and the formation of laterally-continuos accumulations of biogenic hard parts. A comparison with the few available studies on the sequence-stratigraphic distribution of large marine vertebrates and shell beds suggests that a model integrating high-productivity and sea level rise, favouring bone bed and shell bed formation, can be applied at other settings, and other geologic intervals.

Hydrocarbon potential evaluation of the source rocks from the Abu Gabra Formation in the Sufyan Sag, Muglad Basin, Sudan

NASA Astrophysics Data System (ADS)

Qiao, Jinqi; Liu, Luofu; An, Fuli; Xiao, Fei; Wang, Ying; Wu, Kangjun; Zhao, Yuanyuan

2016-06-01

The Sufyan Sag is one of the low-exploration areas in the Muglad Basin (Sudan), and hydrocarbon potential evaluation of source rocks is the basis for its further exploration. The Abu Gabra Formation consisting of three members (AG3, AG2 and AG1 from bottom to top) was thought to be the main source rock formation, but detailed studies on its petroleum geology and geochemical characteristics are still insufficient. Through systematic analysis on distribution, organic matter abundance, organic matter type, organic matter maturity and characteristics of hydrocarbon generation and expulsion of the source rocks from the Abu Gabra Formation, the main source rock members were determined and the petroleum resource extent was estimated in the study area. The results show that dark mudstones are the thickest in the AG2 member while the thinnest in the AG1 member, and the thickness of the AG3 dark mudstone is not small either. The AG3 member have developed good-excellent source rock mainly with Type I kerogen. In the Southern Sub-sag, the AG3 source rock began to generate hydrocarbons in the middle period of Bentiu. In the early period of Darfur, it reached the hydrocarbon generation and expulsion peak. It is in late mature stage currently. The AG2 member developed good-excellent source rock mainly with Types II1 and I kerogen, and has lower organic matter abundance than the AG3 member. In the Southern Sub-sag, the AG2 source rock began to generate hydrocarbons in the late period of Bentiu. In the late period of Darfur, it reached the peak of hydrocarbon generation and its expulsion. It is in middle mature stage currently. The AG1 member developed fair-good source rock mainly with Types II and III kerogen. Throughout the geological evolution history, the AG1 source rock has no effective hydrocarbon generation or expulsion processes. Combined with basin modeling results, we have concluded that the AG3 and AG2 members are the main source rock layers and the Southern Sub-sag is the main source kitchen in the study area. The AG3 and AG2 source rocks have supplied 58.1% and 41.9% of the total hydrocarbon generation, respectively, and 54.9% and 45.1% of the total hydrocarbon expulsion, respectively. Their hydrocarbon expulsion efficiency ratios are 71.0% and 62.3%, respectively. The Southern Sub-sag has supplied more than 90% of the total amounts of hydrocarbon generation and its expulsion.

Identification of the Paleocene-Eocene boundary in coastal strata in the Otway Basin, Victoria, Australia

NASA Astrophysics Data System (ADS)

Frieling, Joost; Huurdeman, Emiel P.; Rem, Charlotte C. M.; Donders, Timme H.; Pross, Jörg; Bohaty, Steven M.; Holdgate, Guy R.; Gallagher, Stephen J.; McGowran, Brian; Bijl, Peter K.

2018-02-01

Detailed, stratigraphically well-constrained environmental reconstructions are available for Paleocene and Eocene strata at a range of sites in the southwest Pacific Ocean (New Zealand and East Tasman Plateau; ETP) and Integrated Ocean Discovery Program (IODP) Site U1356 in the south of the Australo-Antarctic Gulf (AAG). These reconstructions have revealed a large discrepancy between temperature proxy data and climate models in this region, suggesting a crucial error in model, proxy data or both. To resolve the origin of this discrepancy, detailed reconstructions are needed from both sides of the Tasmanian Gateway. Paleocene-Eocene sedimentary archives from the west of the Tasmanian Gateway have unfortunately remained scarce (only IODP Site U1356), and no well-dated successions are available for the northern sector of the AAG. Here we present new stratigraphic data for upper Paleocene and lower Eocene strata from the Otway Basin, southeast Australia, on the (north)west side of the Tasmanian Gateway. We analyzed sediments recovered from exploration drilling (Latrobe-1 drill core) and outcrop sampling (Point Margaret) and performed high-resolution carbon isotope geochemistry of bulk organic matter and dinoflagellate cyst (dinocyst) and pollen biostratigraphy on sediments from the regional lithostratigraphic units, including the Pebble Point Formation, Pember Mudstone and Dilwyn Formation. Pollen and dinocyst assemblages are assigned to previously established Australian pollen and dinocyst zonations and tied to available zonations for the SW Pacific. Based on our dinocyst stratigraphy and previously published planktic foraminifer biostratigraphy, the Pebble Point Formation at Point Margaret is dated to the latest Paleocene. The globally synchronous negative carbon isotope excursion that marks the Paleocene-Eocene boundary is identified within the top part of the Pember Mudstone in the Latrobe-1 borehole and at Point Margaret. However, the high abundances of the dinocyst Apectodinium prior to this negative carbon isotope excursion prohibit a direct correlation of this regional bio-event with the quasi-global Apectodinium acme at the Paleocene-Eocene Thermal Maximum (PETM; 56 Ma). Therefore, the first occurrence of the pollen species Spinizonocolpites prominatus and the dinocyst species Florentinia reichartii are here designated as regional markers for the PETM. In the Latrobe-1 drill core, dinocyst biostratigraphy further indicates that the early Eocene ( ˜ 56-51 Ma) sediments are truncated by a ˜ 10 Myr long hiatus overlain by middle Eocene ( ˜ 40 Ma) strata. These sedimentary archives from southeast Australia may prove key in resolving the model-data discrepancy in this region, and the new stratigraphic data presented here allow for detailed comparisons between paleoclimate records on both sides of the Tasmanian Gateway.

Griffith Saponite as an Analog for Clay Minerals at Yellowknife Bay in Gale Crater, Mars: A Marker for Low-temperature Hydrothermal Processes

NASA Technical Reports Server (NTRS)

Morris, R.V.; Treiman, A. H.; Agresti, D. G.; Graff, T. G.; Achilles, C. N.; Rampe, E. B.; Bristow, T. F.; Ming, D. W.; Blake, D. F.; Vaniman, D. T.;

Provenance and tectonic setting of the Neoproterozoic clastic rocks hosting the Banana Zone Cu-Ag mineralisation, northwest Botswana

NASA Astrophysics Data System (ADS)

Kelepile, Tebogo; Bineli Betsi, Thierry; Franchi, Fulvio; Shemang, Elisha; Suh, Cheo Emmanuel

2017-05-01

Petrographic and geochemical data were combined in order to decipher the petrogenesis of the Neoproterozoic sedimentary succession associated with the Banana Zone Cu-Ag mineralisation (northwest Botswana), in the Kalahari Copperbelt. The investigated Neoproterozoic sedimentary succession is composed of two formations including the Ngwako Pan and the D'kar Formations. The Ngwako Pan Formation is made up of continental siliciclastic sediments, mainly sandstones interbedded with siltstones and mudstones, whereas the D'kar Formation is comprised of shallow marine laminated siltstones, sandstones and mudstones, with subordinate limestone. Copper-Ag mineralisation is essentially confined at the base of the D'kar Formation, which bears reduced organic components, likely to have controlled Cu-Ag precipitation. Sandstones of both the Ngwako Pan and the D'kar Formations are arkoses and subarkoses, composed of quartz (Q), feldspars (F) and lithic fragments (L). Moreover, geochemically the sandstones are considered as potassic and classified as arkoses. On the other hand, mudrocks of the D'kar Formation are finely laminated and are dominated by muscovite, sericite, chlorite and quartz. The modified chemical index of weathering (CIW‧) values indicated an intense chemical weathering of the source rock. The dominance of detrital quartz and feldspar grains coupled with Al2O3/TiO2 ratios (average 29.67 and 24.52 for Ngwako Pan and D'kar Formations, respectively) and Ni and Cr depletion in the sandstones, suggest a dominant felsic source. However, high concentrations of Ni and Cr and a low Al2O3/TiO2 ratio (<20) in the mudrocks of the D'kar Formation indicate a mixed source. Provenance of the investigated sandstones and mudrocks samples is further supported by the REE patterns, the size of Eu anomaly as well as La/Co, Th/Co, Th/Cr and Cr/Th ratios, which show a felsic source for the sandstones of both the Ngwako Pan and D'kar Formations and an intermediate source for the mudrocks of the D'kar Formation. Detrital modes (QFL diagrams) and geochemical characteristics of the sandstones of both the Ngwako Pan and D'kar Formations indicate that the detritus were probably supplied from a heavily weathered felsic continental block and deposited in a continental rift setting (passive margin) in a humid environment. The source rocks might have been the Palaeoproterozoic basement rocks (granitoids and granitic gneiss) and the Mesoproterozoic Kgwebe volcanic rocks exposed north of the study area.

Middle-Upper Permian carbon isotope stratigraphy at Chaotian, South China: Pre-extinction multiple upwelling of oxygen-depleted water onto continental shelf

NASA Astrophysics Data System (ADS)

Saitoh, Masafumi; Isozaki, Yukio; Ueno, Yuichiro; Yoshida, Naohiro; Yao, Jianxin; Ji, Zhansheng

2013-05-01

In order to examine the causal relationships between the carbon cycle in a shallow euphotic zone and the environmental changes in a relatively deep disphotic zone at the end-Guadalupian (Middle Permian), isotopic compositions of carbonate carbon (δ13Ccarb) of the Guadalupian-Lopingian (Upper Permian) rocks were analyzed in the Chaotian section in northern Sichuan, South China. By analyzing exceptionally fresh drill core samples, a continuous chemostratigraphic record was newly obtained. The ca. 65 m-thick analyzed carbonate rocks at Chaotian comprise three stratigraphic units, i.e., the Limestone Unit of the Guadalupian Maokou Formation, the Mudstone Unit of the Maokou Formation, and the lower part of the Wuchiapingian (Lower Lopingian) Wujiaping Formation, in ascending order. The Limestone Unit of the Maokou Formation is characterized by almost constant δ13Ccarb values of ca. +4‰ followed by an abrupt drop for 7‰ to -3‰ in the topmost part of the unit. In the Mudstone Unit of the Maokou Formation, the δ13Ccarb values are rather constant around +2‰, although distinct three isotopic negative excursions for 3‰ from ca. +2 to -1‰ occurred in the upper part of the unit. In the lower part of the Wujiaping Formation, the δ13Ccarb values monotonously increase for 5‰ from ca. 0 to +5‰. The present data newly demonstrated four isotopic negative excursions in the topmost part of the Maokou Formation in the Capitanian (Late Guadalupian) at Chaotian. It is noteworthy that these negative excursions are in accordance with the emergence of an oxygen-depleted condition on the relatively deep disphotic slope/basin on the basis of litho- and bio-facies characteristics. They suggest multiple upwelling of oxygen-depleted waters with dissolved inorganic carbon of relatively low carbon isotope values along the continental margin, from the deeper disphotic slope/basin to the shallower euphotic shelf, slightly before the end-Guadalupian extinction. Although the negative excursions at Chaotian are apparently correlated with the previously proposed large negative excursion in the middle Capitanian in South China, the age difference according to the biostratigraphic constraints clearly exclude this interpretation. The isotopic negative excursions at Chaotian are unique and no similar isotopic signal in the same period has been reported elsewhere. The multiple upwelling of oxygen-depleted waters onto the euphotic shelf may have represented local phenomena that occurred solely around northwestern South China.

Geothermal characteristics of deep wells using geophysical logs in Pohang area, Korea

NASA Astrophysics Data System (ADS)

LIM, W.; Hamm, S. Y.; Lee, C.; Song, Y.; Kim, H.

2016-12-01

Pohang area displays a larger potential of geothermal energy with the highest heat flow of 83 mWm-2 in South Korea. A geothermal binary power plant with a generation capacity of 1.5MW using enhanced geothermal system (EGS) is under construction in Pohang area and will be completed until 2017. This study aims to reveal geothermal characteristics of four wells (BH-1 to BH-4 wells) of 2,383 m in depth in Pohang area, using geophysical logs. The geology of the study area is composed of tertiary mudstone of 200 - 359.1 m, tuff of 73 - 240 m, sandstone/mudstone of 46 - 907 m, rhyolite of 259 - 375 m, and andesitic volcanic breccia of 834 m in thicknesses from the surface, with granodiorite at bottom. By the result of the study, temperature and maximum electrical conductivity (EC) are 69.5°C at 1,502.6 m and 1,162 μS/cm at BH-2 well, 44.4°C at 912.3 m and 1,105 μS/cm at BH-3 well, and 82.5°C at 1,981.3 m and 3,412 μS/cm at BH-4 well. Thermal conductivity values at saturated state are 2.14 - 3.95 W/m-K (average 3.47 W/m-K) at BH-1 well and 2.36 - 3.61 W/m-K (average 2.85 W/m-K) at BH-4 well. ß (determining heat flow rate and up/down direction) values were estimated by using 1-D steady-state heat transfer equation and were determined as -0.77 - 0.99 with the geothermal gradients (Ks) of 42.5 - 46.3°C/km at BH-1 well, -3.15 - 3.05 with the Ks of 25.0 - 29.1°C/km at BH-2, -1.80 - 2.09 with the Ks of 20.0 - 23.0°C/km at BH-3 well, and -4.10 - 5.18 with the Ks of 30.2 - 39.0°C/km at BH-4 well. Most depths of all the wells showed upward heat transfer. Based on the geophysical logs, the main aquifer is located between 200 and 300 meters. KEY WORDS: Geothermal gradient, thermal conductivity, geophysical logs, ß value, heat transfer equation, Pohang area Acknowledgement This work was supported by grants from the Principal Research Fund of Korea Institute of the Geoscience and Mineral Resources (KIGAM 16-3411).

Geological implications and controls on the determination of water saturation in shale gas reservoirs

NASA Astrophysics Data System (ADS)

Hartigan, David; Lovell, Mike; Davies, Sarah

2014-05-01

A significant challenge to the petrophysical evaluation of shale gas systems can be attributed to the conductivity behaviour of clay minerals and entrained clay bound waters. This is compounded by centimetre to sub-millimetre vertical and lateral heterogeneity in formation composition and structure. Where despite significant variation in formation geological and therefore petrophysical properties, we routinely rely on conventional resistivity methods for the determination of water saturation (Sw), and hence the free gas saturation (Sg) in gas bearing mudstones. The application of resistivity based methods is the subject of continuing debate, and there is often significant uncertainty in both how they are applied and the saturation estimates they produce. This is partly a consequence of the view that "the quantification of the behaviour of shale conductivity....has only limited geological significance" (Rider 1986). As a result, there is a separation between our geological understanding of shale gas systems and the petrophysical rational and methods employed to evaluate them. In response to this uncertainty, many petrophysicists are moving away from the use of more complex 'shaly-sand' based evaluation techniques and returning to traditional Archie methods for answers. The Archie equation requires various parameter inputs such as porosity and saturation exponents (m and n), as well as values for connate fluid resistivity (Rw). Many of these parameters are difficult to determine in shale gas systems, where obtaining a water sample, or carrying out laboratory experiments on recovered core is often technically impractical. Here we assess the geological implications and controls on variations in pseudo Archie parameters across two geological formations, using well data spanning multiple basinal settings for a prominent shale gas play in the northern Gulf of Mexico basin. The results, of numerical analysis and systematic modification of parameter values to minimise the error between core derived Sw (Dean Stark analysis) and computed Sw, links sample structure with composition, highlighting some unanticipated impacts of clay minerals on the effective bulk fluid resistivity (Rwe) and thus formation resistivity (Rt). In addition, it highlights simple corrective empirical adaptations that can significantly reduce the error in Sw estimation for some wells. Observed results hint at the possibility of developing a predictive capability in selecting Archie parameter values based on geological facies association and log composition indicators (i.e. V Clay), establishing a link between formation depositional systems and their petrophysical properties in gas bearing mudstones. Rider, M.H., 1986. The Geological Interpretation of Well Logs, Blackie.

Palaeogeographic, palaeoclimatic, palaeohydrological and chemical/biochemical controls on accumulation of late Eocene coastal lacustrine-palustrine limestones, Southern England

NASA Astrophysics Data System (ADS)

Armenteros, Ildefonso; Edwards, Nicholas

2012-12-01

The shallow-lacustrine to palustrine Hatherwood Limestone Member of the late Eocene Headon Hill Formation, Southern England, is in a succession of fluvio-estuarine and laguno-lacustrine siliciclastic sediments. It is up to 8.0 m thick and is subdivided by metric-scale palaeotopographic erosion surfaces, one of which underlies lenticular humic siliciclastic mudstones. The limestone lithologies are (1) biocalcilutites/biocalcisiltites, (2) biocalcarenites, (3) calcirudites, and (4) laterally-discontinuous laminar and fenestral crusts. Lithology (1) accumulated in a low-energy shallow-lacustrine depositional environment, indicated by the predominance of pulmonate pond-snails in the mollusc assemblage. In contrast, lithologies (2) and (3) are the coarse-grained fills of shallow palaeotopographic lows, and also form basal lags and palaeokarst-fills. Lithology (3) comprises remnant autochthonous lags that resulted from selective erosion during lacustrine transgressions. Brecciation and proto-intraclast to nodular differentiation in lithology (2) suggests derivation of the intraclasts from subaerially- and pedogenically-modified shallow-lacustrine muds. Laminar crusts (4), 0.5-6.0 cm in thickness, display irregularly undulose and anastamosing laminations 150-400 μm thick, that display differential staining by iron oxide. The abundance of rootlet traces and calcitised parenchymatic root tissues in the fenestral crusts suggests a palustrine depositional environment for these lithologies. The siliciclastic mudstone lithologies are (1) black humic muds and (2) blue-green silty muds and marls. The high C/N molar ratio of the black muds suggests derivation of the humic content mainly from vascular plants in local wetlands. The mollusc assemblage of the blue-green siliciclastic muds resembles floodplain lake assemblages from the regional Palaeogene succession. Mean stable isotopic values for limestone samples, of - 4.75 ± 1.53 for δ13C and - 2.77 ± 1.47 for δ18O, indicate a relatively heavy tendency within published spectra for Tertiary lacustrine carbonates. The δ18O isotope results agree with published subtropical surface-water palaeotemperatures for this succession. The total characteristics of the Member therefore suggest a shallow-lacustrine to palustrine depositional environment. Pedogenic overprinting and mechanical reworking displayed by the limestones are attributable to seasonal fluctuations of water level during lake highstands, but in this marine-influenced setting, major long-term lake lowstands, resulting in deep erosion and palaeokarsting of the limestones, may be attributable to falls in relative sea-level. The biocalcilutites and humic muds accumulated during the ensuing lake transgressions.

Schaben field, Kansas: Improving performance in a Mississippian shallow-shelf carbonate

USGS Publications Warehouse

Montgomery, S.L.; Franseen, E.K.; Bhattacharya, S.; Gerlach, P.; Byrnes, A.; Guy, W.; Carr, T.R.

2000-01-01

Schaben field (Kansas), located along the northeastern shelf of the Hugoton embayment, produces from Mississippian carbonates in erosional highs immediately beneath a regional unconformity. Production comes from depths of around 4400 ft (1342 m) in partially dolomitized shelf deposits. A detailed reservoir characterization/simulation study, recently performed as part of a Department of Energy Reservoir Class Oil Field Demonstration Project, has led to important revision in explanations for observed patterns of production. Cores recovered from three new data wells identify three main facies: Spicule-rich wackestone-packstone, echinoderm wackestone/packstone/grainstone, and dolomitic mudstone-wackestone. Reservoir quality is highest in spicule-rich wackestone/packstones but is subject to a very high degree of vertical heterogeneity due to facies interbedding, silification, and variable natural fracturing. The oil reservoir is underlain by an active aquifer, which helps maintain reservoir pressure but supports significant water production. Reservoir simulation, using public-domain, PC-based software, suggests that infill drilling is an efficient approach to enhanced recovery. Recent drilling directed by simulation results has shown considerable success in improving field production rates. Results from the Schaben field demonstration project are likely to have wide application for independent oil and exploration companies in western Kansas.Schaben field (Kansas), located along the northeastern shelf of the Hugoton embayment, produces from Mississippian carbonates in erosional highs immediately beneath a regional unconformity. Production comes from depths of around 4400 ft (1342 m) in partially dolomitized shelf deposits. A detailed reservoir characterization/simulation study, recently performed as part of a Department of Energy Reservoir Class Oil Field Demonstration Project, has led to important revision in explanations for observed patterns of production. Cores recovered from three new data wells identify three main facies: spicule-rich wackestone-packstone, echinoderm wackestone/packstone/grainstone, and dolomitic mudstone-wackestone. Reservoir quality is highest in spicule-rich wackestone/packstones but is subject to a very high degree of vertical heterogeneity due to facies interbedding, silification, and variable natural fracturing. The oil reservoir is underlain by an active aquifer, which helps maintain reservoir pressure but supports significant water production. Reservoir simulation, using public-domain, PC-based software, suggests that infill drilling is an efficient approach to enhanced recovery. Recent drilling directed by simulation results has shown considerable success in improving field production rates. Results from the Schaben field demonstration project are likely to have wide application for independent oil and exploration companies in western Kansas.

Hollow Nodules Gas Escape Sedimentary Structures in Lacustrine Deposits on Earth and Gale Crater

NASA Astrophysics Data System (ADS)

Bonaccorsi, R.; Willson, D.; Fairen, A. G.; Baker, L.; McKay, C.; Zent, A.; Mahaffy, P. R.

2015-12-01

Curiosity's Mastcam and MAHLI instruments in Gale Crater (GC) imaged mm-sized circular rimmed hollow nodules (HNs) (Figure 1A), pitting the Sheepbed mudstone of Yellowknife Bay Formation [1,2]. HNs are significantly smaller than the solid nodules within the outcrop, with an external mean diameter of 1.2 mm and an interior one of 0.7 mm [2] Several formation mechanisms of HNs have been discussed, such as: (1) Diagenetic dissolution of soluble mineral phases; or, (2) Gas bubbles released shortly after sediment deposition [1-3]. In an ephemeral pond in Ubehebe Crater (Death Valley, CA) we observed the formation of hollow nodule sedimentary structures produced by gas bubbles (Figure 1C) preserved in smectite-rich mud that are strikingly similar to those imaged in GC (Figure 1A). This finding supports the gas bubble hypothesis [2]. Ubehebe Crater (UC) surface sediment hollow nodules were sampled, imaged, and their internal diameter measured (200 hollow structures) showing similar shape, distribution, and composition to those imaged by Curiosity in GC. UC in-situ observations suggest the gas bubbles were generated within the slightly reducing ephemerally submerged mud. These intra-crater deposits remain otherwise extremely dry year round, i.e., Air_rH ~2-5%; ground H2O wt%: 1-2%; Summer air/ground T: 45-48ºC/67-70ºC [4-5]. Data from the Sample Analysis at Mars (SAM), CheMin, and ChemCam instruments onboard the rover revealed that HNs-bearing mudstone are rich in smectite clay e.g., ~18-20% [6,7] deposited in a neutral to mildly alkaline environment, capturing a period when the surface was potentially habitable [1]. The UC HNs-hosting deposits are also rich in smectite clays (~30%) and occur in an ephemeral shallow freshwater setting [4-5]. If present, surface hollow nodules are easy to find in dry clay-rich mud in lacustrine sediments, so they could represent a new indicator of ephemeral but habitable/inhabited environments on both Earth and early Mars. References: [1] Grotzinger J.P. et al. (2014), Science 343, 124277. [2] Stack et al. (2014) JGR,Planets 119343. [4] Bonaccorsi R. et al. (2012) AGU Fall Meeting, Abstract #P11B-1839. [5] Bonaccorsi, R. et al. (2014) AGU Fall Meeting, Paper #EP53A-3632. [6] McLennan, S.M. et al. (2014) Science 343, 1244734. [7] Ming D.W. et al. (2014) Science, 343, 1245267.

Mg Isotope variations of Marinoan Cap Carbonates: implications for the chemical evolution of Neoproterozoic Ocean after snowball earth

NASA Astrophysics Data System (ADS)

Liu, C.; Macdonald, F. A.; Raub, T.; Wang, Z.; Evans, D. A.

2012-12-01

We report Mg isotope profiles of two cap-carbonates: Nuccaleena formation from south Australia (mostly dolostones) and Tsagaan Oloom Formation from southwest Mongolia (including dolostones, aragonite crystal fans, and lime-mudstones). These data provide additional constraints on the chemical evolution of Neoproterozoic Oceans after the Marinoan deglaciation. An incremental leaching technique using ammonium acetate and various concentrations of acetic acid and hydrochloric acid was applied to separate metals in various forms from cap-carbonates (including surface adsorbed phases, calcite, dolomite and clay minerals). The leachates were then passed through chromatographic columns to extract pure Mg and Sr, which were then analyzed for their isotopic compositions by MC-ICP-MS (Neptune) at Yale University. Elemental ratios (Mg/Ca and Sr/Ca) in each leaching steps were also measured. Our results show that small variations of δ26MgDSM3 with leaching steps were observed in most dolostone samples when secondary calcite is absent. In contrast, large Mg isotope variations (up to 1.5 per mil) were shown in the leaching steps of limestone and crystal fans. The primary δ26MgDSM3 value of each sample was chosen from the leachate that has the lowest 87Sr/86Sr ratios. The δ26MgDSM3 value of Nuccaleena dolostone increases from -2.2‰ at the basal part of the section to -1.7‰ in the middle, and then turns back to -2.0‰ on the top, with a positive correlation between 26Mg/24Mg and 87Sr/86Sr ratios, implying that the high δ26MgDSM3 values may be caused by alteration or inherit from continental-derived fluids. In contrast, small δ26MgDSM3 variations in Tsagaan Oloom dolostones were exhibited in different leaching steps or cross the section (~-1.7‰), with high 87Sr/86Sr ratios (~0.7090), resembling cap dolostones from middle part of Nuccaleena dolostone, implying that they are formed in a similar environment. However, the δ26MgDSM3 value of upper lime-mudstones and crystal fans from Tsagaan Oloom Formation oscillate between -3.4‰ to -1.9‰ with a negative correlation between δ26MgDSM3 and Ca/Mg, and without any correlation with 87Sr/86Sr ratios, indicating mixing of co-precipitated multiple carbonate phases with different mineralogy.

Facies analysis, depositional environments and paleoclimate of the Cretaceous Bima Formation in the Gongola Sub - Basin, Northern Benue Trough, NE Nigeria

NASA Astrophysics Data System (ADS)

Shettima, B.; Abubakar, M. B.; Kuku, A.; Haruna, A. I.

2018-01-01

Facies analysis of the Cretaceous Bima Formation in the Gongola Sub -basin of the Northern Benue Trough northeastern Nigeria indicated that the Lower Bima Member is composed of alluvial fan and braided river facies associations. The alluvial fan depositional environment dominantly consists of debris flow facies that commonly occur as matrix supported conglomerate. This facies is locally associated with grain supported conglomerate and mudstone facies, representing sieve channel and mud flow deposits respectively, and these deposits may account for the proximal alluvial fan region of the Lower Bima Member. The distal fan facies were represented by gravel-bed braided river system of probably Scot - type model. This grade into sandy braided river systems with well developed floodplains facies, forming probably at the lowermost portion of the alluvial fan depositional gradient, where it inter-fingers with basinal facies. In the Middle Bima Member, the facies architecture is dominantly suggestive of deep perennial sand-bed braided river system with thickly developed amalgamated trough crossbedded sandstone facies fining to mudstone. Couplets of shallow channels are also locally common, attesting to the varying topography of the basin. The Upper Bima Member is characterized by shallow perennial sand-bed braided river system composed of successive succession of planar and trough crossbedded sandstone facies associations, and shallower channels of the flashy ephemeral sheetflood sand - bed river systems defined by interbedded succession of small scale trough crossbedded sandstone facies and parallel laminated sandstone facies. The overall stacking pattern of the facies succession of the Bima Formation in the Gongola Sub - basin is generally thinning and fining upwards cycles, indicating scarp retreat and deposition in a relatively passive margin setting. Dominance of kaolinite in the clay mineral fraction of the Bima Formation points to predominance of humid sub - tropical to tropical climatic conditions. This favors pedogenic activities which are manifested in the several occurrences of paleosols. Pronounced periods of arid climatic conditions are also notable from the subordinate smectite mineralization. Chlorite mineralization at some localities is indicative of elevation of the provenance area, and this is synonymous with deposition of the Bima Formation, because of its syn - depositional tectonics. The absences of lacustrine shales in the syn - rift stratigraphic architecture of the Bima Formation indicates that the lower Cretaceous petroleum system that are common in the West and Central African Rift basins are generally barren in the Gongola Sub - basin of the Northern Benue Trough.

3D Sedimentological and geophysical studies of clastic reservoir analogs: Facies architecture, reservoir properties, and flow behavior within delta front facies elements of the Cretaceous Wall Creek Member, Frontier Formation, Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Christopher D. White

2009-12-21

Significant volumes of oil and gas occur in reservoirs formed by ancient river deltas. This has implications for the spatial distribution of rock types and the variation of transport properties. A between mudstones and sandstones may form baffles that influence productivity and recovery efficiency. Diagenetic processes such as compaction, dissolution, and cementation can also alter flow properties. A better understanding of these properties and improved methods will allow improved reservoir development planning and increased recovery of oil and gas from deltaic reservoirs. Surface exposures of ancient deltaic rocks provide a high-resolution view of variability. Insights gleaned from these exposures canmore » be used to model analogous reservoirs, for which data is sparser. The Frontier Formation in central Wyoming provides an opportunity for high-resolution models. The same rocks exposed in the Tisdale anticline are productive in nearby oil fields. Kilometers of exposure are accessible, and bedding-plane exposures allow use of high-resolution ground-penetrating radar. This study combined geologic interpretations, maps, vertical sections, core data, and ground-penetrating radar to construct geostatistical and flow models. Strata-conforming grids were use to reproduce the observed geometries. A new Bayesian method integrates outcrop, core, and radar amplitude and phase data. The proposed method propagates measurement uncertainty and yields an ensemble of plausible models for calcite concretions. These concretions affect flow significantly. Models which integrate more have different flow responses from simpler models, as demonstrated an exhaustive two-dimensional reference image and in three dimensions. This method is simple to implement within widely available geostatistics packages. Significant volumes of oil and gas occur in reservoirs that are inferred to have been formed by ancient river deltas. This geologic setting has implications for the spatial distribution of rock types (\\Eg sandstones and mudstones) and the variation of transport properties (\\Eg permeability and porosity) within bodies of a particular rock type. Both basin-wide processes such as sea-level change and the autocyclicity of deltaic processes commonly cause deltaic reservoirs to have large variability in rock properties; in particular, alternations between mudstones and sandstones may form baffles and trends in rock body permeability can influence productivity and recovery efficiency. In addition, diagenetic processes such as compaction, dissolution, and cementation can alter the spatial pattern of flow properties. A better understanding of these properties, and improved methods to model the properties and their effects, will allow improved reservoir development planning and increased recovery of oil and gas from deltaic reservoirs. Surface exposures of ancient deltaic rocks provide a high resolution, low uncertainty view of subsurface variability. Patterns and insights gleaned from these exposures can be used to model analogous reservoirs, for which data is much sparser. This approach is particularly attractive when reservoir formations are exposed at the surface. The Frontier Formation in central Wyoming provides an opportunity for high resolution characterization. The same rocks exposed in the vicinity of the Tisdale anticline are productive in nearby oil fields, including Salt Creek. Many kilometers of good-quality exposure are accessible, and the common bedding-plane exposures allow use of shallow-penetration, high-resolution electromagnetic methods known as ground-penetrating radar. This study combined geologic interpretations, maps, vertical sections, core data, and ground-penetrating radar to construct high-resolution geostatistical and flow models for the Wall Creek Member of the Frontier Formation. Stratal-conforming grids were use to reproduce the progradational and aggradational geometries observed in outcrop and radar data. A new, Bayesian method integrates outcrop--derived statistics, core observations of concretions, and radar amplitude and phase data. The proposed method consistently propagates measurement uncertainty through the model-building process, and yields an ensemble of plausible models for diagenetic calcite concretions. These concretions have a statistically significant on flow. Furthermore, neither geostatistical data from the outcrops nor geophysical data from radar is sufficient: models which integrate these data have significantly different flow responses. This was demonstrated both for an exhaustive two-dimensional reference image and in three dimensions, using flow simulations. This project wholly supported one PhD student and part of the education of an additional MS and PhD student. It helped to sponsor 6 refereed articles and 8 conference or similar presentations.« less

DOE workshop: Sedimentary systems, aqueous and organic geochemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-07-01

A DOE workshop on sedimentary systems, aqueous and organic geochemistry was held July 15-16, 1993 at Lawrence Berkeley Laboratory. Papers were organized into several sections: Fundamental Properties, containing papers on the thermodynamics of brines, minerals and aqueous electrolyte solutions; Geochemical Transport, covering 3-D imaging of drill core samples, hydrothermal geochemistry, chemical interactions in hydrocarbon reservoirs, fluid flow model application, among others; Rock-Water Interactions, with presentations on stable isotope systematics of fluid/rock interaction, fluid flow and petotectonic evolution, grain boundary transport, sulfur incorporation, tracers in geologic reservoirs, geothermal controls on oil-reservoir evolution, and mineral hydrolysis kinetics; Organic Geochemistry covered new methodsmore » for constraining time of hydrocarbon migration, kinetic models of petroleum formation, mudstones in burial diagenesis, compound-specific carbon isotope analysis of petroleums, stability of natural gas, sulfur in sedimentary organic matter, organic geochemistry of deep ocean sediments, direct speciation of metal by optical spectroscopies; and lastly, Sedimentary Systems, covering sequence stratigraphy, seismic reflectors and diagenetic changes in carbonates, geochemistry and origin of regional dolomites, and evidence of large comet or asteroid impacts at extinction boundaries.« less

Massive sulfide metallogenesis at a late Mesozoic sediment-covered spreading axis: Evidence from the Franciscan complex and contemporary analogues

USGS Publications Warehouse

Koski, Randolph A.; Lamons, Roberta C.; Dumoulin, Julie A.; Bouse, Robin M.

1993-01-01

The Island Mountain deposit, an anomalous massive sulfide in the Central belt of the Franciscan subduction complex, northern California Coast Ranges, formed during hydrothermal activity in a sediment-dominated paleo-sea-floor environment. Although the base of the massive sulfide is juxtaposed against a 500-m-wide melange band, its gradational upper contact within a coherent sequence of sandstone, siltstone, and mudstone indicates that hydrothermal activity was concurrent with turbidite deposition. Accumulations of sulfide breccia and clastic sulfide were produced by mass wasting of the sulfide mound prior to burial by turbidites. The bulk composition of sulfide samples (pyrrhotite rich; high Cu, As, and Au contents; radiogenic Pb isotope ratios) is consistent with a hydrothermal system dominated by fluid-sediment interaction. On the basis of a comparison with possible contemporary tectonic analogues at the southern Gorda Ridge and the Chile margin triple junction, we propose that massive sulfide mineralization in the Central belt of the Franciscan complex resulted from hydrothermal activity at a late Mesozoic sediment-covered ridge axis prior to collision with the North American plate.

Permeability and compressibility of resedimented Gulf of Mexico mudrock

NASA Astrophysics Data System (ADS)

Betts, W. S.; Flemings, P. B.; Schneider, J.

2011-12-01

We use a constant-rate-of strain consolidation test on resedimented Gulf of Mexico mudrock to determine the compression index (Cc) to be 0.618 and the expansion index (Ce) to be 0.083. We used crushed, homogenized Pliocene and Pleistocene mudrock extracted from cored wells in the Eugene Island block 330 oil field. This powdered material has a liquid limit (LL) of 87, a plastic limit (PL) of 24, and a plasticity index (PI) of 63. The particle size distribution from hydrometer analyses is approximately 65% clay-sized particles (<2 μm) with the remainder being less than 70 microns in diameter. Resedimented specimens have been used to characterize the geotechnical and geophysical behavior of soils and mudstones independent of the variability of natural samples and without the effects of sampling disturbance. Previous investigations of resedimented offshore Gulf of Mexico sediments (e.g. Mazzei, 2008) have been limited in scope. This is the first test of the homogenized Eugene Island core material. These results will be compared to in situ measurements to determine the controls on consolidation over large stress ranges.

Paleogeographic implications of an erosional remnant of Paleogene rocks southwest of the Sur-Nacimiento Fault Zone, southern Coast Ranges, California

USGS Publications Warehouse

Vedder, J.G.; McLean, H.; Stanley, R.G.; Wiley, T.J.

1991-01-01

A small tract of heretofore-unrecognized Paleogene rocks lies about 30 km northeast of Santa Maria and 1 km southwest of the Sur-Nacimiento fault zone near upper Pine Creek. This poorly exposed assemblage of rocks is less than 50 m thick, lies unconformably on regionally distributed Upper Cretaceous submarine-fan deposits, and consists of three units: fossiliferous lower Eocene mudstone, Oligocene(?) conglomerate, and basaltic andesite that has a radiometric age of 26.6 ?? 0.5 Ma. Both the sedimentary and igneous constituents in the Paleogene sequence are unlike those of known sequences on either side of the Sur-Nacimiento fault zone. The Paleogene sedimentary rocks near upper Pine Creek presumably are remnants of formerly widespread early Eocene bathyal deposits and locally distributed Oligocene(?) fluvial deposits southwest of the fault zone. The 26.6 Ma basaltic andesite, however, may not have extended much beyond its present outcrops. An episode of Oligocene(?) displacement is required by the contrast in thicknesses, depositional patterns, and paleobathymetry of the juxtaposed rock sequences. -from Authors

Continuity of Permian Mengkareng formation through GPR interpretation in Merangin Geopark

NASA Astrophysics Data System (ADS)

Hanif, F.; Syahputra, R.; Kristyanto, T. H. W.; Tempessy, A. S.; Rokhmatuloh

2017-07-01

The Permian Mengkarang Formation was a part of the continental margin (Gondwana Land) which separated in the Devon Period. In this period, Gondwana Land experienced glaciation at the Paleo South Pole. However, the fossils found in Mengkarang Formation were tropical flora, had made the Merangin to be certified as one of the national geoparks. It also shows that the geological process (stratigraphy and tectonic) in the Merangin has occurred before the Indonesian archipelago was formed: namely the Permian to Triassic period. Ground Penetrating Radar (GPR) was chosen as an effective geophysical method to study shallow subsurface geology. GPR and seismic reflection method have the same common principle to identify the facies and sub-sequence stratigraphy but they are different in implementation. Therefore, this study aims to deliver the vertical continuity of the Permian Mengkarang Formation in high resolution unit. The GPR result showing the subsurface image is based on dielectric of the rock layers. The GPR sections show the absence of the unconformity delivered in the intercalation between mudstone, sandstone, and tuff. Thus, it can be concluded that the Permian Mengkareng Formation continues up to 20 m depth.

Bulk Hydrogen Content OF High-Silica Rocks in Gale Crater With the Active Dynamic Albedo of Neutrons Experiment

NASA Technical Reports Server (NTRS)

Gabriel, T. S. J.; Hardgrove, C.; Litvak, M.; Mitrofanov, I.; Boynton, W. V.; Fedosov, F.; Golovin, D.; Jun, I.; Mischna, M.; Tate, C. G.;

Geological and taphonomic context for the new hominin species Homo naledi from the Dinaledi Chamber, South Africa

PubMed Central

Dirks, Paul HGM; Berger, Lee R; Roberts, Eric M; Kramers, Jan D; Hawks, John; Randolph-Quinney, Patrick S; Elliott, Marina; Musiba, Charles M; Churchill, Steven E; de Ruiter, Darryl J; Schmid, Peter; Backwell, Lucinda R; Belyanin, Georgy A; Boshoff, Pedro; Hunter, K Lindsay; Feuerriegel, Elen M; Gurtov, Alia; Harrison, James du G; Hunter, Rick; Kruger, Ashley; Morris, Hannah; Makhubela, Tebogo V; Peixotto, Becca; Tucker, Steven

2015-01-01

We describe the physical context of the Dinaledi Chamber within the Rising Star cave, South Africa, which contains the fossils of Homo naledi. Approximately 1550 specimens of hominin remains have been recovered from at least 15 individuals, representing a small portion of the total fossil content. Macro-vertebrate fossils are exclusively H. naledi, and occur within clay-rich sediments derived from in situ weathering, and exogenous clay and silt, which entered the chamber through fractures that prevented passage of coarser-grained material. The chamber was always in the dark zone, and not accessible to non-hominins. Bone taphonomy indicates that hominin individuals reached the chamber complete, with disarticulation occurring during/after deposition. Hominins accumulated over time as older laminated mudstone units and sediment along the cave floor were eroded. Preliminary evidence is consistent with deliberate body disposal in a single location, by a hominin species other than Homo sapiens, at an as-yet unknown date. DOI: http://dx.doi.org/10.7554/eLife.09561.001 PMID:26354289

Integration of thermal digital 3D model and a MASW (Multichannel Analysis of Surface Wave) as a means of improving monitoring of spoil tip stability

NASA Astrophysics Data System (ADS)

Lewińska, Paulina; Matuła, Rafał; Dyczko, Artur

2018-01-01

Spoil tips are anthropogenic terrain structures built of leftover (coal) mining materials. They consist mostly of slate and sandstone or mudstone but also include coal and highly explosive coal dust. Coal soil tip fires cause an irreversible degradation to the environment. Government organizations notice the potential problem of spoil tip hazard and are looking for ways of fast monitoring of their temperature and inside structure. In order to test new monitoring methods an experimental was performed in the area of spoil tip of Lubelski Węgiel "Bogdanka" S.A. A survey consisted of creating a 3D discreet thermal model. This was done in order to look for potential fire areas. MASW (Multichannel analysis of surface wave) was done in order to find potential voids within the body of a tip. Existing data was digitalized and a 3D model of object's outside and inside was produced. This article provides results of this survey and informs about advantages of such an approach.

Diagenesis in the Murray Formation, Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Rampe, E. B.; Ming, D. W.; Morris, R. V.; Blake, D. F.; Bristow, T. F.; Chipera. S. J.; Vaniman, D. T.; Yen, A. S.; Grotzinger, J. P.; Downs, R. T.;

Petrography, geochemistry, and tectonics of a rifted fragment of Mainland Asia: evidence from the Lasala Formation, Mindoro Island, Philippines

NASA Astrophysics Data System (ADS)

Concepcion, R. A. B.; Dimalanta, C. B.; Yumul, G. P.; Faustino-Eslava, D. V.; Queaño, K. L.; Tamayo, R. A.; Imai, A.

2012-01-01

Petrological and geochemical investigations of the sedimentary Lasala formation in northwest Mindoro, Philippines, offer new insights into the origin of this geologically contentious region. Mindoro island's position at the boundary between Sundaland and the Philippine Mobile Belt has led to variable suggestions as to how much of it is continent derived or not. The Eocene Lasala formation overlies the Jurassic Halcon metamorphics, a regionally metamorphosed suite generally thought to have formed as a result of arc-continent collision processes. The sedimentary formation consists mainly of sandstones and shales interbedded with mudstones, basalt flows, and subordinate limestones and conglomerates. Petrographic information on the Lasala clastic rocks demonstrates a uniform framework composition that is predominantly quartzose. Major oxide, trace element abundances, and various elemental ratios similarly impart a strongly felsic signature. These characteristics are taken to indicate a chiefly continental, passive margin derivation and deposition of the Lasala sediments during the Eocene. The weak indication of active margin influence is suggested to be an inherited signature, supported by paleogeographic models of the southeastern Asian margin area during the pre-Cenozoic.

Sedimentary facies and depositional history of the Swan Islands, Honduras

NASA Astrophysics Data System (ADS)

Ivey, Marvin L.; Breyer, John A.; Britton, Joseph C.

1980-10-01

Swan Island is a Honduran possession in the western Caribbean, located on the southeastern side of the Cayman Trench. Two sedimentary assemblages are found on the island: an older bedded sequence of mid-Tertiary age (Aquitanian or Burdigalian) and a younger sedimentary sequence of Late Pleistocene age. The older sequence is composed of a series of calcarenites, calcilutites, and siliciclastic mudstones; capping these are cliff-forming reefal carbonates of the younger sequence. The rocks of the older bedded sequence accumulated in deep water. Sedimentation consisted of a constant rain of pyroclastic debris interrupted by the episodic introduction of upslope carbonate material by turbidity currents. Uplift and deformation of this sequence was initiated sometime after the Early Miocene. By the Late Pleistocene, uplift had brought the rocks into water depths conducive to coral growth. Pleistocene sedimentation on the island was controlled by the interaction between tectonic uplift and eustatic sea-level changes. The primary controlling force on the tectonic history of the island is its proximity to the boundary between the North American and Caribbean plates.

Tuffaceous Mud is a Volumetrically Important Volcaniclastic Facies of Submarine Arc Volcanism and Record of Climate Change

NASA Astrophysics Data System (ADS)

Gill, J. B.; Bongiolo, E. M.; Miyazaki, T.; Hamelin, C.; Jutzeler, M.; DeBari, S.; Jonas, A.-S.; Vaglarov, B. S.; Nascimento, L. S.; Yakavonis, M.

2018-04-01

The inorganic portion of tuffaceous mud and mudstone in an oceanic island arc can be mostly volcanic in origin. Consequently, a large volume of submarine volcaniclastic material is as extremely fine-grained as products of subaerial eruptions (<100 µm). Using results of IODP Expedition 350 in the Izu rear arc, we show that such material can accumulate at high rates (12-20 cm/k.y.) within 13 km of the nearest seamount summit and scores of km behind the volcanic front. The geochemistry of bulk, acid-leached mud, and its discrete vitriclasts, shows that >75% of the mud is volcanic, and that most of it was derived from proximal rear arc volcanic sources. It faithfully preserves integrated igneous geochemical information about arc evolution in much the same way that terrigenous shales track the evolution of continental crust. In addition, their high sedimentation rate enables high resolution study of climate cycles, including the effects of Pleistocene glaciation on the behavior of the Kuroshio Current in the Shikoku Basin south of Japan.

Update on the Chemical Composition Of Crystalline, Smectite, and Amorphous Components for Rocknest Soil and John Klein and Cumberland Mudstone Drill Fines at Gale Crater, Mars

NASA Technical Reports Server (NTRS)

Morris, R. V.; Ming, D. W.; Gellert, R.; Vaniman, D. T.; Bish, D. L.; Blake, D. F.; Chipera, S. J.; Morrison, S. M.; Downs, R. T.; Rampe, E. B.;