A New Multielement Method for LA-ICP-MS Data Acquisition from Glacier Ice Cores.

PubMed

Spaulding, Nicole E; Sneed, Sharon B; Handley, Michael J; Bohleber, Pascal; Kurbatov, Andrei V; Pearce, Nicholas J; Erhardt, Tobias; Mayewski, Paul A

2017-11-21

To answer pressing new research questions about the rate and timing of abrupt climate transitions, a robust system for ultrahigh-resolution sampling of glacier ice is needed. Here, we present a multielement method of LA-ICP-MS analysis wherein an array of chemical elements is simultaneously measured from the same ablation area. Although multielement techniques are commonplace for high-concentration materials, prior to the development of this method, all LA-ICP-MS analyses of glacier ice involved a single element per ablation pass or spot. This new method, developed using the LA-ICP-MS system at the W. M. Keck Laser Ice Facility at the University of Maine Climate Change Institute, has already been used to shed light on our flawed understanding of natural levels of Pb in Earth's atmosphere.

Designs and Algorithms to Map Eye Tracking Data with Dynamic Multielement Moving Objects.

PubMed

Kang, Ziho; Mandal, Saptarshi; Crutchfield, Jerry; Millan, Angel; McClung, Sarah N

2016-01-01

Design concepts and algorithms were developed to address the eye tracking analysis issues that arise when (1) participants interrogate dynamic multielement objects that can overlap on the display and (2) visual angle error of the eye trackers is incapable of providing exact eye fixation coordinates. These issues were addressed by (1) developing dynamic areas of interests (AOIs) in the form of either convex or rectangular shapes to represent the moving and shape-changing multielement objects, (2) introducing the concept of AOI gap tolerance (AGT) that controls the size of the AOIs to address the overlapping and visual angle error issues, and (3) finding a near optimal AGT value. The approach was tested in the context of air traffic control (ATC) operations where air traffic controller specialists (ATCSs) interrogated multiple moving aircraft on a radar display to detect and control the aircraft for the purpose of maintaining safe and expeditious air transportation. In addition, we show how eye tracking analysis results can differ based on how we define dynamic AOIs to determine eye fixations on moving objects. The results serve as a framework to more accurately analyze eye tracking data and to better support the analysis of human performance.

Designs and Algorithms to Map Eye Tracking Data with Dynamic Multielement Moving Objects

PubMed Central

Mandal, Saptarshi

2016-01-01

Design concepts and algorithms were developed to address the eye tracking analysis issues that arise when (1) participants interrogate dynamic multielement objects that can overlap on the display and (2) visual angle error of the eye trackers is incapable of providing exact eye fixation coordinates. These issues were addressed by (1) developing dynamic areas of interests (AOIs) in the form of either convex or rectangular shapes to represent the moving and shape-changing multielement objects, (2) introducing the concept of AOI gap tolerance (AGT) that controls the size of the AOIs to address the overlapping and visual angle error issues, and (3) finding a near optimal AGT value. The approach was tested in the context of air traffic control (ATC) operations where air traffic controller specialists (ATCSs) interrogated multiple moving aircraft on a radar display to detect and control the aircraft for the purpose of maintaining safe and expeditious air transportation. In addition, we show how eye tracking analysis results can differ based on how we define dynamic AOIs to determine eye fixations on moving objects. The results serve as a framework to more accurately analyze eye tracking data and to better support the analysis of human performance. PMID:27725830

The use of a single multielement standard for trace analysis in biological materials by external beam PIXE

NASA Astrophysics Data System (ADS)

Biswas, S. K.; Khaliquzzaman, M.; Islam, M. M.; Khan, A. H.

1984-04-01

The validity of the use of a single multielement standard for mass calibration in thick-target external beam PIXE analysis of biological materials has been investigated. In this study, the NBS orchard leaf, SRM 1571, was used as the basic standard for trace element analysis in other biological materials. Using the present procedure, the concentrations of K, Ca, Mn, Fe, Ni, Cu, Zn, Br, Rb and Sr were determined in several NBS reference materials such as bovine liver, spinach, rice flour, etc., generally in 20 μC irradiations with 2.0 MeV protons. The analytical results are compared with certified values of the NBS as well as with other measurements and the sources of errors are discussed.

An experimental investigation of multi-element airfoil ice accretion and resulting performance degradation

NASA Technical Reports Server (NTRS)

Potapczuk, Mark G.; Berkowitz, Brian M.

1989-01-01

An investigation of the ice accretion pattern and performance characteristics of a multi-element airfoil was undertaken in the NASA Lewis 6- by 9-Foot Icing Research Tunnel. Several configurations of main airfoil, slat, and flaps were employed to examine the effects of ice accretion and provide further experimental information for code validation purposes. The text matrix consisted of glaze, rime, and mixed icing conditions. Airflow and icing cloud conditions were set to correspond to those typical of the operating environment anticipated tor a commercial transport vehicle. Results obtained included ice profile tracings, photographs of the ice accretions, and force balance measurements obtained both during the accretion process and in a post-accretion evaluation over a range of angles of attack. The tracings and photographs indicated significant accretions on the slat leading edge, in gaps between slat or flaps and the main wing, on the flap leading-edge surfaces, and on flap lower surfaces. Force measurments indicate the possibility of severe performance degradation, especially near C sub Lmax, for both light and heavy ice accretion and performance analysis codes presently in use. The LEWICE code was used to evaluate the ice accretion shape developed during one of the rime ice tests. The actual ice shape was then evaluated, using a Navier-Strokes code, for changes in performance characteristics. These predicted results were compared to the measured results and indicate very good agreement.

Flow prediction over a transport multi-element high-lift system and comparison with flight measurements

NASA Technical Reports Server (NTRS)

Vijgen, P. M. H. W.; Hardin, J. D.; Yip, L. P.

1992-01-01

Accurate prediction of surface-pressure distributions, merging boundary-layers, and separated-flow regions over multi-element high-lift airfoils is required to design advanced high-lift systems for efficient subsonic transport aircraft. The availability of detailed measurements of pressure distributions and both averaged and time-dependent boundary-layer flow parameters at flight Reynolds numbers is critical to evaluate computational methods and to model the turbulence structure for closure of the flow equations. Several detailed wind-tunnel measurements at subscale Reynolds numbers were conducted to obtain detailed flow information including the Reynolds-stress component. As part of a subsonic-transport high-lift research program, flight experiments are conducted using the NASA-Langley B737-100 research aircraft to obtain detailed flow characteristics for support of computational and wind-tunnel efforts. Planned flight measurements include pressure distributions at several spanwise locations, boundary-layer transition and separation locations, surface skin friction, as well as boundary-layer profiles and Reynolds stresses in adverse pressure-gradient flow.

Multielement mapping of alpha-SiC by scanning Auger microscopy

NASA Technical Reports Server (NTRS)

Browning, Ray; Smialek, James L.; Jacobson, Nathan S.

1987-01-01

Fine second-phase particles, numerous in sintered alpha-SiC, were analyzed by scanning Auger microscopy and conventional techniques. The Auger analysis utilized computer-controlled data acquisition, multielement correlation diagrams, and a high spatial resolution of 100 nm. This procedure enabled construction of false color maps and the detection of fine compositional details within these particles. Carbon, silicon oxide, and boron-rich particles (qualitatively as BN or B4C) predominated. The BN particles, sometimes having a carbon core, are believed to result from reaction between B4C additives and nitrogen sintering atmospheres.

Evolution of Elemental Composition and Morphology in Fusion Reactor's First Wall

NASA Astrophysics Data System (ADS)

Kim, Yong W.

2007-11-01

Forcing of a multi-element alloy by a gradient field can modify the spatial profile of its elemental composition. The gradient field may be in the imposed temperature or the flux of impinging particles. In a fusion device, both scenarios apply. The consequences must be well understood because they change the thermal transport properties as well as the strength, corrosion and wear characteristics of the first wall materials. Given the large number of directions material evolution can take, new robust methods of near-surface composition analyses are needed. This paper presents a new measurement methodology and requisite instrumentation, which can provide measures of local elemental composition and transport properties simultaneously by time-resolved spectroscopy of laser-produced plasma (LPP) plume emissions from the specimen surfaces. The studies to date show that the composition profiles can be modified thermally in a reproducible manner; disparate thermal transport of constituent atoms can incur modifications of near-surface composition profiles.[Y.W. Kim, Int. J. Thermophysics 28, 732 (2007)] Also, disparate fluxes of fuel particles, fusion products and impurities force the first walls in myriad ways. Repetitive application of the LPP analysis can resolve the near-surface composition profile as well as transport properties over several microns with depth resolutions to 20 nm. Work supported in part by NSF-DMR.

Detecting False Positives in Multielement Designs: Implications for Brief Assessments

ERIC Educational Resources Information Center

Bartlett, Sara M.; Rapp, John T.; Henrickson, Marissa L.

2011-01-01

The authors assessed the extent to which multielement designs produced false positives using continuous duration recording (CDR) and interval recording with 10-s and 1-min interval sizes. Specifically, they created 6,000 graphs with multielement designs that varied in the number of data paths, and the number of data points per data path, using a…

Position-specific isotope modeling of organic micropollutants transformations through different reaction pathways

NASA Astrophysics Data System (ADS)

Jin, Biao; Rolle, Massimo

2016-04-01

Organic compounds are produced in vast quantities for industrial and agricultural use, as well as for human and animal healthcare [1]. These chemicals and their metabolites are frequently detected at trace levels in fresh water environments where they undergo degradation via different reaction pathways. Compound specific stable isotope analysis (CSIA) is a valuable tool to identify such degradation pathways in different environmental systems. Recent advances in analytical techniques have promoted the fast development and implementation of multi-element CSIA. However, quantitative frameworks to evaluate multi-element stable isotope data and incorporating mechanistic information on the degradation processes [2,3] are still lacking. In this study we propose a mechanism-based modeling approach to simultaneously evaluate concentration as well as bulk and position-specific multi-element isotope evolution during the transformation of organic micropollutants. The model explicitly simulates position-specific isotopologues for those atoms that experience isotope effects and, thereby, provides a mechanistic description of isotope fractionation occurring at different molecular positions. We validate the proposed approach with the concentration and multi-element isotope data of three selected organic micropollutants: dichlorobenzamide (BAM), isoproturon (IPU) and diclofenac (DCF). The model precisely captures the dual element isotope trends characteristic of different reaction pathways and their range of variation consistent with observed multi-element (C, N) bulk isotope fractionation. The proposed approach can also be used as a tool to explore transformation pathways in scenarios for which position-specific isotope data are not yet available. [1] Schwarzenbach, R.P., Egli, T., Hofstetter, T.B., von Gunten, U., Wehrli, B., 2010. Global Water Pollution and Human Health. Annu. Rev. Environ. Resour. doi:10.1146/annurev-environ-100809-125342. [2] Jin, B., Haderlein, S.B., Rolle, M., 2013. Integrated carbon and chlorine isotope modeling: Applications to chlorinated aliphatic hydrocarbons dechlorination. Environ. Sci. Technol. 47, 1443-1451. doi:10.1021/es304053h. [3] Jin, B., Rolle, M., 2014. Mechanistic approach to multi-element isotope modeling of organic contaminant degradation. Chemosphere 95, 131-139. doi:10.1016/j.chemosphere.2013.08.050.

Optimisation of flame parameters for simultaneous multi-element atomic absorption spectrometric determination of trace elements in rocks

USGS Publications Warehouse

Kane, J.S.

1988-01-01

A study is described that identifies the optimum operating conditions for the accurate determination of Co, Cu, Mn, Ni, Pb, Zn, Ag, Bi and Cd using simultaneous multi-element atomic absorption spectrometry. Accuracy was measured in terms of the percentage recoveries of the analytes based on certified values in nine standard reference materials. In addition to identifying optimum operating conditions for accurate analysis, conditions resulting in serious matrix interferences and the magnitude of the interferences were determined. The listed elements can be measured with acceptable accuracy in a lean to stoicheiometric flame at measurement heights ???5-10 mm above the burner.

Multi-element compound specific stable isotope analysis of chlorinated aliphatic contaminants derived from chlorinated pitches.

PubMed

Filippini, Maria; Nijenhuis, Ivonne; Kümmel, Steffen; Chiarini, Veronica; Crosta, Giovanni; Richnow, Hans H; Gargini, Alessandro

2018-05-30

Tetrachloroethene and trichloroethene are typical by-products of the industrial production of chloromethanes. These by-products are known as "chlorinated pitches" and were often dumped in un-contained waste disposal sites causing groundwater contaminations. Previous research showed that a strongly depleted stable carbon isotope signature characterizes chlorinated compounds associated with chlorinated pitches whereas manufactured commercial compounds have more enriched carbon isotope ratios. The findings were restricted to a single case study and one element (i.e. carbon). This paper presents a multi-element Compound-Specific Stable Isotope Analysis (CSIA, including carbon, chlorine and hydrogen) of chlorinated aliphatic contaminants originated from chlorinated pitches at two sites with different hydrogeology and different producers of chloromethanes. The results show strongly depleted carbon signatures at both sites whereas the chlorine and the hydrogen signatures are comparable to those presented in the literature for manufactured commercial compounds. Multi-element CSIA allowed the identification of sources and site-specific processes affecting chloroethene transformation in groundwater as a result of emergency remediation measures. CSIA turned out to be an effective forensic tool to address the liability for the contamination, leading to a conviction for the crimes of unintentional aggravated public water supply poisoning and environmental disaster. Copyright © 2018 Elsevier B.V. All rights reserved.

Theory study on the bandgap of antimonide-based multi-element alloys

NASA Astrophysics Data System (ADS)

An, Ning; Liu, Cheng-Zhi; Fan, Cun-Bo; Dong, Xue; Song, Qing-Li

2017-05-01

In order to meet the design requirements of the high-performance antimonide-based optoelectronic devices, the spin-orbit splitting correction method for bandgaps of Sb-based multi-element alloys is proposed. Based on the analysis of band structure, a correction factor is introduced in the InxGa1-xAsySb1-y bandgaps calculation with taking into account the spin-orbit coupling sufficiently. In addition, the InxGa1-xAsySb1-y films with different compositions are grown on GaSb substrates by molecular beam epitaxy (MBE), and the corresponding bandgaps are obtained by photoluminescence (PL) to test the accuracy and reliability of this new method. The results show that the calculated values agree fairly well with the experimental results. To further verify this new method, the bandgaps of a series of experimental samples reported before are calculated. The error rate analysis reveals that the α of spin-orbit splitting correction method is decreased to 2%, almost one order of magnitude smaller than the common method. It means this new method can calculate the antimonide multi-element more accurately and has the merit of wide applicability. This work can give a reasonable interpretation for the reported results and beneficial to tailor the antimonides properties and optoelectronic devices.

Status of the Combustion Devices Injector Technology Program at the NASA MSFC

NASA Technical Reports Server (NTRS)

Jones, Gregg; Protz, Christopher; Trinh, Huu; Tucker, Kevin; Nesman, Tomas; Hulka, James

2005-01-01

To support the NASA Space Exploration Mission, an in-house program called Combustion Devices Injector Technology (CDIT) is being conducted at the NASA Marshall Space Flight Center (MSFC) for the fiscal year 2005. CDIT is focused on developing combustor technology and analysis tools to improve reliability and durability of upper-stage and in-space liquid propellant rocket engines. The three areas of focus include injector/chamber thermal compatibility, ignition, and combustion stability. In the compatibility and ignition areas, small-scale single- and multi-element hardware experiments will be conducted to demonstrate advanced technological concepts as well as to provide experimental data for validation of computational analysis tools. In addition, advanced analysis tools will be developed to eventually include 3-dimensional and multi- element effects and improve capability and validity to analyze heat transfer and ignition in large, multi-element injectors.

Delineation of geochemical anomalies based on stream sediment data utilizing fractal modeling and staged factor analysis

NASA Astrophysics Data System (ADS)

Afzal, Peyman; Mirzaei, Misagh; Yousefi, Mahyar; Adib, Ahmad; Khalajmasoumi, Masoumeh; Zarifi, Afshar Zia; Foster, Patrick; Yasrebi, Amir Bijan

2016-07-01

Recognition of significant geochemical signatures and separation of geochemical anomalies from background are critical issues in interpretation of stream sediment data to define exploration targets. In this paper, we used staged factor analysis in conjunction with the concentration-number (C-N) fractal model to generate exploration targets for prospecting Cr and Fe mineralization in Balvard area, SE Iran. The results show coexistence of derived multi-element geochemical signatures of the deposit-type sought and ultramafic-mafic rocks in the NE and northern parts of the study area indicating significant chromite and iron ore prospects. In this regard, application of staged factor analysis and fractal modeling resulted in recognition of significant multi-element signatures that have a high spatial association with host lithological units of the deposit-type sought, and therefore, the generated targets are reliable for further prospecting of the deposit in the study area.

Mesogondolella and Jinogondolella (Conodonta): Multielement definition of the taxa that bracket the basal Guadalupian (Middle Permian Series) GSSP

USGS Publications Warehouse

Lambert, L.L.; Wardlaw, B.R.; Henderson, C.M.

2007-01-01

Multielement definitions are presented here for Mesogondolella and Jinogondolella based on species that bracket the basal Guadalupian (Middle Permian Series) GSSP. Distinctive apparatus characters that appear with the first Jinogondolella include several details of P2 element dimorphism and process bifurcation in S3 elements. The sequential expression of these multielement characters is traced through M. idahoensis, M. lamberti, and J. nankingensis. The resulting multielement definition of Jinogondolella serves to distinguish it from all other closely related genera. Mesogondolella lamberti is recognized as a distinct species, and J. serrata is formally designated a junior synonym of J. nankingensis. ?? 2007 Nanjing Institute of Geology and Palaeontology, CAS.

Multi-Element Behaviour Support as a Model for the Delivery of a Human Rights Based Approach for Working with People with Intellectual Disabilities and Behaviours that Challenge

ERIC Educational Resources Information Center

Doody, Christina

2009-01-01

This paper demonstrates the effectiveness of the multi-element behaviour support (MEBS) model in meeting the rights of persons with intellectual disabilities and behaviours that challenge. It does this through explicitly linking the multi-element model to the guiding principles of a human rights based approach (HRBA) using a vignette to…

Aerodynamics Characteristics of Multi-Element Airfoils at -90 Degrees Incidence

NASA Technical Reports Server (NTRS)

Stremel, Paul M.; Schmitz, Fredric H. (Technical Monitor)

1994-01-01

A developed method has been applied to calculate accurately the viscous flow about airfoils normal to the free-stream flow. This method has special application to the analysis of tilt rotor aircraft in the evaluation of download. In particular, the flow about an XV-15 airfoil with and without deflected leading and trailing edge flaps at -90 degrees incidence is evaluated. The multi-element aspect of the method provides for the evaluation of slotted flap configurations which may lead to decreased drag. The method solves for turbulent flow at flight Reynolds numbers. The flow about the XV-15 airfoil with and without flap deflections has been calculated and compared with experimental data at a Reynolds number of one million. The comparison between the calculated and measured pressure distributions are very good, thereby, verifying the method. The aerodynamic evaluation of multielement airfoils will be conducted to determine airfoil/flap configurations for reduced airfoil drag. Comparisons between the calculated lift, drag and pitching moment on the airfoil and the airfoil surface pressure will also be presented.

Quality and Trace Element Profile of Tunisian Olive Oils Obtained from Plants Irrigated with Treated Wastewater

PubMed Central

Benincasa, Cinzia; Gharsallaoui, Mariem; Perri, Enzo; Briccoli Bati, Caterina; Ayadi, Mohamed; Khlif, Moncen; Gabsi, Slimane

2012-01-01

In the present work the use of treated wastewater (TWW) to irrigate olive plants was monitored. This type of water is characterized by high salinity and retains a substantial amount of trace elements, organic and metallic compounds that can be transferred into the soil and into the plants and fruits. In order to evaluate the impact of TWW on the overall quality of the oils, the time of contact of the olives with the soil has been taken into account. Multi-element data were obtained using ICP-MS. Nineteen elements (Li, B, Na, Mg, Al, K, Ca, Sc, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Mo, Ba and La) were submitted for statistical analysis. Using analysis of variance, linear discriminant analysis and principal component analysis it was possible to differentiate between oils produced from different batches of olives whose plants received different types of water. Also, the results showed that there was correlation between the elemental and mineral composition of the water used to irrigate the olive plots and the elemental and mineral composition of the oils. PMID:22654625

Energy dispersive X-ray fluorescence (EDXRF) equipment calibration for multielement analysis of soil and rock samples

NASA Astrophysics Data System (ADS)

de Moraes, Alex Silva; Tech, Lohane; Melquíades, Fábio Luiz; Bastos, Rodrigo Oliveira

2014-11-01

Considering the importance to understand the behavior of the elements on different natural and/or anthropic processes, this study had as objective to verify the accuracy of a multielement analysis method for rocks characterization by using soil standards as calibration reference. An EDXRF equipment was used. The analyses were made on samples doped with known concentration of Mn, Zn, Rb, Sr and Zr, for the obtainment of the calibration curves, and on a certified rock sample to check the accuracy of the analytical curves. Then, a set of rock samples from Rio Bonito, located in Figueira city, Paraná State, Brazil, were analyzed. The concentration values obtained, in ppm, for Mn, Rb, Sr and Zr varied, respectively, from 175 to 1084, 7.4 to 268, 28 to 2247 and 15 to 761.

An Assessment of the Icing Blade and the SEA Multi-Element Sensor for Liquid Water Content Calibration of the NASA GRC Icing Research Tunnel

NASA Technical Reports Server (NTRS)

Steen, Laura E.; Ide, Robert F.; Van Zante, Judith Foss

2017-01-01

The Icing Research Tunnel at NASA Glenn has recently switched to from using the Icing Blade to using the SEA Multi-Element Sensor (also known as the multi-wire) for its calibration of cloud liquid water content. In order to perform this transition, tests were completed to compare the Multi-Element Sensor to the Icing Blade, particularly with respect to liquid water content, airspeed, and drop size. The two instruments were found to compare well for the majority of Appendix C conditions. However, it was discovered that the Icing Blade under-measures when the conditions approach the Ludlam Limit. This paper also describes data processing procedures for the Multi-Element Sensor in the IRT, including collection efficiency corrections, mounting underneath a splitter plate, and correcting for a jump in the compensation wire power. Further data is presented to describe the repeatability of the IRT with the Multi-Element sensor, health-monitoring checks for the instrument, and a sensing-element configuration comparison.

SmaggIce 2.0: Additional Capabilities for Interactive Grid Generation of Iced Airfoils

NASA Technical Reports Server (NTRS)

Kreeger, Richard E.; Baez, Marivell; Braun, Donald C.; Schilling, Herbert W.; Vickerman, Mary B.

2008-01-01

The Surface Modeling and Grid Generation for Iced Airfoils (SmaggIce) software toolkit has been extended to allow interactive grid generation for multi-element iced airfoils. The essential phases of an icing effects study include geometry preparation, block creation and grid generation. SmaggIce Version 2.0 now includes these main capabilities for both single and multi-element airfoils, plus an improved flow solver interface and a variety of additional tools to enhance the efficiency and accuracy of icing effects studies. An overview of these features is given, especially the new multi-element blocking strategy using the multiple wakes method. Examples are given which illustrate the capabilities of SmaggIce for conducting an icing effects study for both single and multi-element airfoils.

Method for Extraction and Multielement Analysis of Hypogymnia Physodes Samples from the Athabasca Oil Sands Region

EPA Science Inventory

A microwave-assisted digestion technique followed by ICPMS (inductively coupled plasma-mass spectrometry) analysis was used to measure concentrations of 43 elements in Hypogymnia physodes samples collected in the Athabasca Oil Sands Region (AOSR) of northern Alberta, Canad...

Performance and Stability Analyses of Rocket Thrust Chambers with Oxygen/Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, James R.; Jones, Gregg W.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for future in-space vehicles. This propellant combination has not been previously used in flight-qualified engine systems developed by NASA, so limited test data and analysis results are available at this stage of early development. As part of activities for the Propulsion and Cryogenic Advanced Development (PCAD) project funded under the Exploration Technology Development Program, the NASA Marshall Space Flight Center (MSFC) has been evaluating capability to model combustion performance and stability for oxygen and methane propellants. This activity has been proceeding for about two years and this paper is a summary of results to date. Hot-fire test results of oxygen/methane propellant rocket engine combustion devices for the modeling investigations have come from several sources, including multi-element injector tests with gaseous methane from the 1980s, single element tests with gaseous methane funded through the Constellation University Institutes Program, and multi-element injector tests with both gaseous and liquid methane conducted at the NASA MSFC funded by PCAD. For the latter, test results of both impinging and coaxial element injectors using liquid oxygen and liquid methane propellants are included. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interactive Design and Analysis code and the Coaxial Injector Combustion Model. Special effort was focused on how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied, improved or developed in the future. Low frequency combustion instability (chug) occurred, with frequencies ranging from 150 to 250 Hz, with several multi-element injectors with liquid/liquid propellants, and was modeled using techniques from Wenzel and Szuch. High-frequency combustion instability also occurred at the first tangential (1T) mode, at about 4500 Hz, with several multi-element injectors with liquid/liquid propellants. Analyses of the transverse mode instability were conducted by evaluating injector resonances and empirical methods developed by Hewitt.

Automation system for measurement of gamma-ray spectra of induced activity for multi-element high volume neutron activation analysis at the reactor IBR-2 of Frank Laboratory of Neutron Physics at the joint institute for nuclear research

NASA Astrophysics Data System (ADS)

Pavlov, S. S.; Dmitriev, A. Yu.; Chepurchenko, I. A.; Frontasyeva, M. V.

2014-11-01

The automation system for measurement of induced activity of gamma-ray spectra for multi-element high volume neutron activation analysis (NAA) was designed, developed and implemented at the reactor IBR-2 at the Frank Laboratory of Neutron Physics. The system consists of three devices of automatic sample changers for three Canberra HPGe detector-based gamma spectrometry systems. Each sample changer consists of two-axis of linear positioning module M202A by DriveSet company and disk with 45 slots for containers with samples. Control of automatic sample changer is performed by the Xemo S360U controller by Systec company. Positioning accuracy can reach 0.1 mm. Special software performs automatic changing of samples and measurement of gamma spectra at constant interaction with the NAA database.

A Mars orbiter/rover/penetrator mission for the 1984 opportunity

NASA Technical Reports Server (NTRS)

Hastrup, R.; Driver, J.; Nagorski, R.

1977-01-01

A point design mission is described that utilizes the 1984 opportunity to extend the exploration of Mars after the successful Viking operations and provide the additional scientific information needed before conducting a sample return mission. Two identical multi-element spacecraft are employed, each consisting of (1) an orbiter, (2) a Viking-derived landing system that delivers a heavily instrumented, semi-autonomous rover, and (3) three penetrators deployed from the approach trajectory. Selection of the orbit profiles requires consideration of several important factors in order to satisfy all of the mission goals.

Optimization of multi-element airfoils for maximum lift

NASA Technical Reports Server (NTRS)

Olsen, L. E.

1979-01-01

Two theoretical methods are presented for optimizing multi-element airfoils to obtain maximum lift. The analyses assume that the shapes of the various high lift elements are fixed. The objective of the design procedures is then to determine the optimum location and/or deflection of the leading and trailing edge devices. The first analysis determines the optimum horizontal and vertical location and the deflection of a leading edge slat. The structure of the flow field is calculated by iteratively coupling potential flow and boundary layer analysis. This design procedure does not require that flow separation effects be modeled. The second analysis determines the slat and flap deflection required to maximize the lift of a three element airfoil. This approach requires that the effects of flow separation from one or more of the airfoil elements be taken into account. The theoretical results are in good agreement with results of a wind tunnel test used to corroborate the predicted optimum slat and flap positions.

Energy-Dispersive X-Ray Fluorescence Spectrometry: A Long Overdue Addition to the Chemistry Curriculum

ERIC Educational Resources Information Center

Palmer, Peter T.

2011-01-01

Portable Energy-Dispersive X-Ray Fluorescence (XRF) analyzers have undergone significant improvements over the past decade. Salient advantages of XRF for elemental analysis include minimal sample preparation, multielement analysis capabilities, detection limits in the low parts per million (ppm) range, and analysis times on the order of 1 min.…

[Determination of multi-element contents in gypsum by ICP-AES].

PubMed

Guo, Zhong-bao; Bai, Yong-zhi; Cui, Jin-hua; Mei, Yi-fei; Ma, Zhen-zhu

2014-08-01

The content of multi-element in gypsum was determined by ICP-AES. The sample was pretreated by acid-soluble method or alkali-fusion method. Acid-soluble method is suitable for the determination of CaO, SOs, Al2O3, Fe2O3, MgO, K2O, Na2O, TiO2, P2O5, MnO, SrO and BaO. Alkali-fusion method is suitable for the determination of CaO, SO3, SiO2, Al2O3, Fe2O3, MgO, TiO2, P2O5, MnO, SrO, BaO and B2O3. Different series standard solutions were prepared considering the properties and content of elements and solution matrix. The limit of detection and quantification were confirmed for each element under their best analysis spectral lines. The recoveries of the two pretreatment methods were from 93% to 110%, besides that for TiO2 was 81%-87% as pretreated by acid-soluble method. All RSDs (n=6) of tests were from 0.70%-3.42%. The accuracies of CaO and SO3 with ICP-AES method were less than the chemical analysis method. The determination of CaO and SO3 with ICP-AES method is only suitable for the case of low accuracy requirement. The results showed that the method can be used for the determination of multi-element contents in gypsum, with simple operation, fast analysis and reliable results. Total elements can be analysed with both acid-soluble method and alkali-fusion method.

An Assessment of the Icing Blade and the SEA Multi-Element Sensor for Liquid Water Content Calibration of the NASA GRC Icing Research Tunnel

NASA Technical Reports Server (NTRS)

Steen, Laura E.; Ide, Robert F.; Van Zante, Judith F.

2016-01-01

The Icing Research Tunnel at NASA Glenn has recently switched from using the Icing Blade to using the SEA Multi-Element Sensor (also known as the multi-wire) for its calibration of cloud liquid water content. In order to peform this transition, tests were completed to compare the Multi-Element Sensor to the Icing Blade, particularly with respect to liquid water content, airspeed, and drop size. The two instruments were found to compare well for the majority of Appendix C conditions. However, it was discovered that the Icing Blade under-measures when the conditions approach the Ludlam Limit. This paper also describes data processing procedures for the Multi-Element Sensor in the IRT, including collision efficiency corrections, mounting underneath a splitter plate, and correcting for a jump in the compensation wire power. Further data is presented to describe the repeatability of the IRT with the Multi-Element Sensor, health-monitoring checks for the instrument, and a sensing-element configuration comparison. Ultimately these tests showed that in the IRT, the multi-wire is a better instrument for measuring cloud liquid water content than the blade.

Airfoil Dynamic Stall and Rotorcraft Maneuverability

NASA Technical Reports Server (NTRS)

Bousman, William G.

2000-01-01

The loading of an airfoil during dynamic stall is examined in terms of the augmented lift and the associated penalties in pitching moment and drag. It is shown that once stall occurs and a leading-edge vortex is shed from the airfoil there is a unique relationship between the augmented lift, the negative pitching moment, and the increase in drag. This relationship, referred to here as the dynamic stall function, shows limited sensitivity to effects such as the airfoil section profile and Mach number, and appears to be independent of such parameters as Reynolds number, reduced frequency, and blade sweep. For single-element airfoils there is little that can be done to improve rotorcraft maneuverability except to provide good static C(l(max)) characteristics and the chord or blade number that is required to provide the necessary rotor thrust. However, multi-element airfoils or airfoils with variable geometry features can provide augmented lift in some cases that exceeds that available from a single-element airfoil. The dynamic stall function is shown to be a useful tool for the evaluation of both measured and calculated dynamic stall characteristics of single element, multi-element, and variable geometry airfoils.

An Assessment of the SEA Multi-Element Sensor for Liquid Water Content Calibration of the NASA GRC Icing Research Tunnel

NASA Technical Reports Server (NTRS)

Steen, Laura E.; Ide, Robert F.; Van Zante, Judith F.

2015-01-01

The NASA Glenn Icing Research tunnel has been using an Icing Blade technique to measure cloud liquid water content (LWC) since 1980. The IRT conducted tests with SEA Multi-Element sensors from 2009 to 2011 to assess their performance in measuring LWC. These tests revealed that the Multi-Element sensors showed some significant advantages over the Icing Blade, particularly at higher water contents, higher impingement rates, and large drop sizes. Results of these and other tests are presented here.

Examination of an Antecedent Communication Intervention to Reduce Tangibly Maintained Challenging Behavior: A Controlled Analog Analysis

ERIC Educational Resources Information Center

O'Reilly, Mark; Fragale, Christina; Gainey, Summer; Kang, Soyeon; Koch, Heather; Shubert, Jennifer; El Zein, Farah; Longino, Deanna; Chung, Moon; Xu, Ziwei; White, Pamela; Lang, Russell; Davis, Tonya; Rispoli, Mandy; Lancioni, Giulio; Didden, Robert; Healy, Olive; Kagohara, Deborah; van der Meer, Larah; Sigafoos, Jeff

2012-01-01

We examined the influence of an antecedent communication intervention on challenging behavior for three students with developmental disorders. Students were taught to request tangible items that were identified as reinforcers for challenging behavior in a prior functional analysis. Individual participant multielement and reversal designs were used…

Multi-element least square HDMR methods and their applications for stochastic multiscale model reduction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, Lijian, E-mail: ljjiang@hnu.edu.cn; Li, Xinping, E-mail: exping@126.com

Stochastic multiscale modeling has become a necessary approach to quantify uncertainty and characterize multiscale phenomena for many practical problems such as flows in stochastic porous media. The numerical treatment of the stochastic multiscale models can be very challengeable as the existence of complex uncertainty and multiple physical scales in the models. To efficiently take care of the difficulty, we construct a computational reduced model. To this end, we propose a multi-element least square high-dimensional model representation (HDMR) method, through which the random domain is adaptively decomposed into a few subdomains, and a local least square HDMR is constructed in eachmore » subdomain. These local HDMRs are represented by a finite number of orthogonal basis functions defined in low-dimensional random spaces. The coefficients in the local HDMRs are determined using least square methods. We paste all the local HDMR approximations together to form a global HDMR approximation. To further reduce computational cost, we present a multi-element reduced least-square HDMR, which improves both efficiency and approximation accuracy in certain conditions. To effectively treat heterogeneity properties and multiscale features in the models, we integrate multiscale finite element methods with multi-element least-square HDMR for stochastic multiscale model reduction. This approach significantly reduces the original model's complexity in both the resolution of the physical space and the high-dimensional stochastic space. We analyze the proposed approach, and provide a set of numerical experiments to demonstrate the performance of the presented model reduction techniques. - Highlights: • Multi-element least square HDMR is proposed to treat stochastic models. • Random domain is adaptively decomposed into some subdomains to obtain adaptive multi-element HDMR. • Least-square reduced HDMR is proposed to enhance computation efficiency and approximation accuracy in certain conditions. • Integrating MsFEM and multi-element least square HDMR can significantly reduce computation complexity.« less

Multielement suppressor nozzles for thrust augmentation systems.

NASA Technical Reports Server (NTRS)

Lawrence, R. L.; O'Keefe, J. V.; Tate, R. B.

1972-01-01

The noise reduction and nozzle performance characteristics of large-scale, high-aspect-ratio multielement nozzle arrays operated at low velocities were determined by test. The nozzles are selected for application to high-aspect-ratio augmentor suppressors to be used for augmentor wing airplanes. Significant improvements in noise characteristics for multielement nozzles over those of round or high-aspect-ratio slot nozzles are obtained. Elliptical noise patterns typical of slot nozzles are presented for high-aspect-ratio multielement nozzle arrays. Additional advantages are available in OASPL noise reduction from the element size and spacing. Augmentor-suppressor systems can be designed for maximum beam pattern directivity and frequency spectrum shaping advantages. Measurements of the nozzle wakes show a correlation with noise level data and frequency spectrum peaks. The noise and jet wake results are compared with existing prediction procedures based on empirical jet flow equations, Lighthill relationships, Strouhal number, and empirical shock-induced screech noise effects.

Multielement geochemistry identifies the spatial pattern of soil and sediment contamination in an urban parkland, Western Australia.

PubMed

Rate, Andrew W

2018-06-15

Urban environments are dynamic and highly heterogeneous, and multiple additions of potential contaminants are likely on timescales which are short relative to natural processes. The likely sources and location of soil or sediment contamination in urban environment should therefore be detectable using multielement geochemical composition combined with rigorously applied multivariate statistical techniques. Soil, wetland sediment, and street dust was sampled along intersecting transects in Robertson Park in metropolitan Perth, Western Australia. Samples were analysed for near-total concentrations of multiple elements (including Cd, Ce, Co, Cr, Cu, Fe, Gd, La, Mn, Nd, Ni, Pb, Y, and Zn), as well as pH, and electrical conductivity. Samples at some locations within Robertson Park had high concentrations of potentially toxic elements (Pb above Health Investigation Limits; As, Ba, Cu, Mn, Ni, Pb, V, and Zn above Ecological Investigation Limits). However, these concentrations carry low risk due to the main land use as recreational open space, the low proportion of samples exceeding guideline values, and a tendency for the highest concentrations to be located within the less accessible wetland basin. The different spatial distributions of different groups of contaminants was consistent with different inputs of contaminants related to changes in land use and technology over the history of the site. Multivariate statistical analyses reinforced the spatial information, with principal component analysis identifying geochemical associations of elements which were also spatially related. A multivariate linear discriminant model was able to discriminate samples into a-priori types, and could predict sample type with 84% accuracy based on multielement composition. The findings suggest substantial advantages of characterising a site using multielement and multivariate analyses, an approach which could benefit investigations of other sites of concern. Copyright © 2018 Elsevier B.V. All rights reserved.

Multielement analysis and antioxidant capacity of Merlot wine clones developed in Montenegro.

PubMed

Đorđević, Neda O; Pejin, Boris; Novaković, Miroslav M; Stanković, Dalibor M; Mutić, Jelena J; Pajović, Snežana B; Tešević, Vele V

2018-02-01

The overall aim of this paper was to compare the multielement composition and antioxidant capacity of two Montenegrin Merlot wines obtained from specific vine clones (VCR1 and VCR 101) along with commercial Merlot wine throughout the consecutive vintages in 2010 and 2011. Elemental composition was analysed using inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS). Additionally, antioxidant capacity was assessed by cyclic voltammetry. VCR 1 wine from 2011 stood out for its elemental composition. On the other hand, antioxidant capacity of VCR 101 wines was the highest one for the both vintages. According to the experimental data obtained, all three wines are good source of essential elements and products with a significant antioxidant activity and specific geographical origin.

Analysis of a High-Lift Multi-Element Airfoil using a Navier-Stokes Code

NASA Technical Reports Server (NTRS)

Whitlock, Mark E.

1995-01-01

A thin-layer Navier-Stokes code, CFL3D, was utilized to compute the flow over a high-lift multi-element airfoil. This study was conducted to improve the prediction of high-lift flowfields using various turbulence models and improved glidding techniques. An overset Chimera grid system is used to model the three element airfoil geometry. The effects of wind tunnel wall modeling, changes to the grid density and distribution, and embedded grids are discussed. Computed pressure and lift coefficients using Spalart-Allmaras, Baldwin-Barth, and Menter's kappa-omega - Shear Stress Transport (SST) turbulence models are compared with experimental data. The ability of CFL3D to predict the effects on lift coefficient due to changes in Reynolds number changes is also discussed.

Hydrogeochemical and stream sediment reconnaissance basic data for Las Cruces quadrangle, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-08-31

Field and laboratory data are presented for 501 water samples and 1817 sediment samples from the Las Cruces Quadrangle, New Mexico. The samples were collected and uranium analysis performed by Los Alamos National Laboratory; multielement analysis and data reporting were performed by the Uranium Resource Evaluation Project at Oak Ridge, Tennessee.

A multi-element screening method to identify metal targets for blood biomonitoring in green sea turtles (Chelonia mydas).

PubMed

Villa, C A; Finlayson, S; Limpus, C; Gaus, C

2015-04-15

Biomonitoring of blood is commonly used to identify and quantify occupational or environmental exposure to chemical contaminants. Increasingly, this technique has been applied to wildlife contaminant monitoring, including for green turtles, allowing for the non-lethal evaluation of chemical exposure in their nearshore environment. The sources, composition, bioavailability and toxicity of metals in the marine environment are, however, often unknown and influenced by numerous biotic and abiotic factors. These factors can vary considerably across time and space making the selection of the most informative elements for biomonitoring challenging. This study aimed to validate an ICP-MS multi-element screening method for green turtle blood in order to identify and facilitate prioritisation of target metals for subsequent fully quantitative analysis. Multi-element screening provided semiquantitative results for 70 elements, 28 of which were also determined through fully quantitative analysis. Of the 28 comparable elements, 23 of the semiquantitative results had an accuracy between 67% and 112% relative to the fully quantified values. In lieu of any available turtle certified reference materials (CRMs), we evaluated the use of human blood CRMs as a matrix surrogate for quality control, and compared two commonly used sample preparation methods for matrix related effects. The results demonstrate that human blood provides an appropriate matrix for use as a quality control material in the fully quantitative analysis of metals in turtle blood. An example for the application of this screening method is provided by comparing screening results from blood of green turtles foraging in an urban and rural region in Queensland, Australia. Potential targets for future metal biomonitoring in these regions were identified by this approach. Copyright © 2014 Elsevier B.V. All rights reserved.

Multi-scaling allometric analysis for urban and regional development

NASA Astrophysics Data System (ADS)

Chen, Yanguang

2017-01-01

The concept of allometric growth is based on scaling relations, and it has been applied to urban and regional analysis for a long time. However, most allometric analyses were devoted to the single proportional relation between two elements of a geographical system. Few researches focus on the allometric scaling of multielements. In this paper, a process of multiscaling allometric analysis is developed for the studies on spatio-temporal evolution of complex systems. By means of linear algebra, general system theory, and by analogy with the analytical hierarchy process, the concepts of allometric growth can be integrated with the ideas from fractal dimension. Thus a new methodology of geo-spatial analysis and the related theoretical models emerge. Based on the least squares regression and matrix operations, a simple algorithm is proposed to solve the multiscaling allometric equation. Applying the analytical method of multielement allometry to Chinese cities and regions yields satisfying results. A conclusion is reached that the multiscaling allometric analysis can be employed to make a comprehensive evaluation for the relative levels of urban and regional development, and explain spatial heterogeneity. The notion of multiscaling allometry may enrich the current theory and methodology of spatial analyses of urban and regional evolution.

Status of jet noise

NASA Technical Reports Server (NTRS)

Banerian, G.

1977-01-01

The fundamentals of jet noise generation and suppression have been studied in great detail over the past twenty-five years. Considerable progress has been made recently in our understanding of this subject, though some aspects of it remain perplexing. The importance of accounting for the influence of the jets mean flow in shrouding acoustic sources is now recognized and the large amount of information obtained on jet noise reduction schemes, e.g., the internal mixer nozzle, the inverted profile nozzle and multi-element suppressors, has helped clarify trends and identify remaining issues. Current understanding of inflight effects is limited and in need of much more attention.

Detailed Modeling and Irreversible Transfer Process Analysis of a Multi-Element Thermoelectric Generator System

NASA Astrophysics Data System (ADS)

Xiao, Heng; Gou, Xiaolong; Yang, Suwen

2011-05-01

Thermoelectric (TE) power generation technology, due to its several advantages, is becoming a noteworthy research direction. Many researchers conduct their performance analysis and optimization of TE devices and related applications based on the generalized thermoelectric energy balance equations. These generalized TE equations involve the internal irreversibility of Joule heating inside the thermoelectric device and heat leakage through the thermoelectric couple leg. However, it is assumed that the thermoelectric generator (TEG) is thermally isolated from the surroundings except for the heat flows at the cold and hot junctions. Since the thermoelectric generator is a multi-element device in practice, being composed of many fundamental TE couple legs, the effect of heat transfer between the TE couple leg and the ambient environment is not negligible. In this paper, based on basic theories of thermoelectric power generation and thermal science, detailed modeling of a thermoelectric generator taking account of the phenomenon of energy loss from the TE couple leg is reported. The revised generalized thermoelectric energy balance equations considering the effect of heat transfer between the TE couple leg and the ambient environment have been derived. Furthermore, characteristics of a multi-element thermoelectric generator with irreversibility have been investigated on the basis of the new derived TE equations. In the present investigation, second-law-based thermodynamic analysis (exergy analysis) has been applied to the irreversible heat transfer process in particular. It is found that the existence of the irreversible heat convection process causes a large loss of heat exergy in the TEG system, and using thermoelectric generators for low-grade waste heat recovery has promising potential. The results of irreversibility analysis, especially irreversible effects on generator system performance, based on the system model established in detail have guiding significance for the development and application of thermoelectric generators, particularly for the design and optimization of TE modules.

Radiological and multi-element analysis of sediments from the Proserpina reservoir (Spain) dating from Roman times.

PubMed

Baeza, A; Guillén, J; Ontalba Salamanca, M A; Rodríguez, A; Ager, F J

2009-10-01

The Proserpina dam was built in Roman times to provide drinking water to Emerita Augusta (today's Mérida in SW Spain). During maintenance work, a sediment core was extracted, offering an excellent opportunity to analyze the historical environmental impacts of the dam and its reservoir over the 2000 years since Roman times. In order to establish an accurate chronology, (14)C ages were determined by accelerator mass spectrometry (AMS). Core samples were assayed for their content in uranium and thorium series isotopes, (40)K, and the anthropogenic radionuclides (137)Cs, (90)Sr, and (239+240)Pu. Potassium-40 presented the highest activity level and was not constant with depth. The uranium and thorium series were generally in equilibrium, suggesting there had been no additional input of natural radionuclides. The presence of (137)Cs was only found in relation with the global fallout in the early 1960s. Multi-element assays were performed using the PIXE and PIGE techniques. Some variations in the multi-element concentrations were observed with depth, but the sediment core could be considered as clean, and no presumptive anthropogenic pollutants were found. Nevertheless, an unusually high Zn content was detected at depths corresponding to pre-Roman times, due to geological anomalies in the area.

Statistical Methods in Assembly Quality Management of Multi-Element Products on Automatic Rotor Lines

NASA Astrophysics Data System (ADS)

Pries, V. V.; Proskuriakov, N. E.

2018-04-01

To control the assembly quality of multi-element mass-produced products on automatic rotor lines, control methods with operational feedback are required. However, due to possible failures in the operation of the devices and systems of automatic rotor line, there is always a real probability of getting defective (incomplete) products into the output process stream. Therefore, a continuous sampling control of the products completeness, based on the use of statistical methods, remains an important element in managing the quality of assembly of multi-element mass products on automatic rotor lines. The feature of continuous sampling control of the multi-element products completeness in the assembly process is its breaking sort, which excludes the possibility of returning component parts after sampling control to the process stream and leads to a decrease in the actual productivity of the assembly equipment. Therefore, the use of statistical procedures for continuous sampling control of the multi-element products completeness when assembled on automatic rotor lines requires the use of such sampling plans that ensure a minimum size of control samples. Comparison of the values of the limit of the average output defect level for the continuous sampling plan (CSP) and for the automated continuous sampling plan (ACSP) shows the possibility of providing lower limit values for the average output defects level using the ACSP-1. Also, the average sample size when using the ACSP-1 plan is less than when using the CSP-1 plan. Thus, the application of statistical methods in the assembly quality management of multi-element products on automatic rotor lines, involving the use of proposed plans and methods for continuous selective control, will allow to automating sampling control procedures and the required level of quality of assembled products while minimizing sample size.

Coupling Meteorology, Metal Concentrations, and Pb Isotopes for Source Attribution in Archived Precipitation Samples

EPA Science Inventory

A technique that couples lead (Pb) isotopes and multi-element concentrations with meteorological analysis was used to assess source contributions to precipitation samples at the Bondville, Illinois USA National Trends Network (NTN) site. Precipitation samples collected over a 16 ...

Multi-element analysis of wines by ICP-MS and ICP-OES and their classification according to geographical origin in Slovenia.

PubMed

Selih, Vid S; Sala, Martin; Drgan, Viktor

2014-06-15

Inductively coupled plasma mass spectrometry and optical emission were used to determine the multi-element composition of 272 bottled Slovenian wines. To achieve geographical classification of the wines by their elemental composition, principal component analysis (PCA) and counter-propagation artificial neural networks (CPANN) have been used. From 49 elements measured, 19 were used to build the final classification models. CPANN was used for the final predictions because of its superior results. The best model gave 82% correct predictions for external set of the white wine samples. Taking into account the small size of whole Slovenian wine growing regions, we consider the classification results were very good. For the red wines, which were mostly represented from one region, even-sub region classification was possible with great precision. From the level maps of the CPANN model, some of the most important elements for classification were identified. Copyright © 2013 Elsevier Ltd. All rights reserved.

Application of the vortex-lattice technique to the analysis of thin wings with vortex separation and thick multi-element wings

NASA Technical Reports Server (NTRS)

Smith, C. W.; Bhateley, I. C.

1976-01-01

Two techniques for extending the range of applicability of the basic vortex-lattice method are discussed. The first improves the computation of aerodynamic forces on thin, low-aspect-ratio wings of arbitrary planforms at subsonic Mach numbers by including the effects of leading-edge and tip vortex separation, characteristic of this type wing, through use of the well-known suction-analogy method of E. C. Polhamus. Comparisons with experimental data for a variety of planforms are presented. The second consists of the use of the vortex-lattice method to predict pressure distributions over thick multi-element wings (wings with leading- and trailing-edge devices). A method of laying out the lattice is described which gives accurate pressures on the top and part of the bottom surface of the wing. Limited comparisons between the result predicted by this method, the conventional lattice arrangement method, experimental data, and 2-D potential flow analysis techniques are presented.

Development of a multi-element microdosimetric detector based on a thick gas electron multiplier

NASA Astrophysics Data System (ADS)

Anjomani, Z.; Hanu, A. R.; Prestwich, W. V.; Byun, S. H.

2017-03-01

A prototype multi-element gaseous microdosimetric detector was developed using the Thick Gas Electron Multiplier (THGEM) technique. The detector aims at measuring neutron and gamma-ray dose rates for weak neutron-gamma radiation fields. The multi-element design was employed to increase the neutron detection efficiency. The prototype THGEM multi-element detector consists of three layers of tissue equivalent plastic hexagons and each layer houses a hexagonal array of seven cylindrical gas cavity elements with equal heights and diameters of 17 mm. The final detector structure incorporates 21 gaseous volumes. Owing to the absence of wire electrodes, the THGEM multi-element detector offers flexible and convenient fabrication. The detector responses to neutron and gamma-ray were investigated using the McMaster Tandetron 7Li(p,n) neutron source. The dosimetric performance of the detector is presented in contrast to the response of a commercial tissue equivalent proportional counter. Compared to the standard TEPC response, the detector gave a consistent microdosimetric response with an average discrepancy of 8 % in measured neutron absorbed dose. An improvement of a factor of 3.0 in neutron detection efficiency has been accomplished with only a small degradation in energy resolution. However, its low energy cut off is about 6 keV/μm, which is not sufficient to measure the gamma-ray dose. This problem will be addressed by increasing the electron multiplication gain using double THGEM layers.

Simulation of multi-element multispectral UV radiation source for optical-electronic system of minerals luminescence analysis

NASA Astrophysics Data System (ADS)

Peretyagin, Vladimir S.; Korolev, Timofey K.; Chertov, Aleksandr N.

2017-02-01

The problems of dressability the solid minerals are attracted attention of specialists, where the extraction of mineral raw materials is a significant sector of the economy. There are a significant amount of mineral ore dressability methods. At the moment the radiometric dressability methods are considered the most promising. One of radiometric methods is method photoluminescence. This method is based on the spectral analysis, amplitude and kinetic parameters luminescence of minerals (under UV radiation), as well as color parameters of radiation. The absence of developed scientific and methodological approaches of analysis irradiation area to UV radiation as well as absence the relevant radiation sources are the factors which hinder development and use of photoluminescence method. The present work is devoted to the development of multi-element UV radiation source designed for the solution problem of analysis and sorting minerals by their selective luminescence. This article is presented a method of theoretical modeling of the radiation devices based on UV LEDs. The models consider such factors as spectral component, the spatial and energy parameters of the LEDs. Also, this article is presented the results of experimental studies of the some samples minerals.

Multi-element isotope fractionation concepts to characterize the biodegradation of hydrocarbons - from enzymes to the environment.

PubMed

Vogt, Carsten; Dorer, Conrad; Musat, Florin; Richnow, Hans-Hermann

2016-10-01

Multi-element compound-specific isotope fractionation (ME-CSIA) has become a state-of-the-art approach for identifying biotransformation reactions. In the last decade, several studies focused on the combined analysis of carbon and hydrogen stable isotopes upon biodegradation of hydrocarbons due to its widespread environmental occurrence as contaminants, often in high concentrations. Most known initial transformation reactions of hydrocarbons have been isotopically characterized in laboratory experiments using model cultures. The data suggest that several of these reactions - especially those occurring under anoxic conditions - can be identified by ME-CSIA, although a number of constraints have been realized which may lead to wrong ME-CSIA data interpretations in field studies. Generally, the applicability of ME-CSIA regarding hydrocarbon biodegradation needs to be corroborated in future field studies. Copyright © 2016 Elsevier Ltd. All rights reserved.

The 1 MV multi-element AMS system for biomedical applications at the Netherlands Organization for Applied Scientific Research (TNO)

NASA Astrophysics Data System (ADS)

Klein, Matthias; Vaes, W. H. J.; Fabriek, B.; Sandman, H.; Mous, D. J. W.; Gottdang, A.

2013-01-01

The Netherlands Organization for Applied Scientific Research (TNO) has installed a compact 1 MV multi-element AMS system manufactured by High Voltage Engineering Europa B.V., The Netherlands. TNO performs clinical research programs for pharmaceutical and innovative foods industry to obtain early pharmacokinetic data and to provide anti-osteoporotic efficacy data of new treatments. The AMS system will analyze carbon, iodine and calcium samples for this purpose. The first measurements on blank samples indicate background levels in the low 10-12 for calcium and iodine, making the system well suited for these biomedical applications. Carbon blanks have been measured at low 10-16. For unattended, around-the-clock analysis, the system features the 200 sample version of the SO110 hybrid ion source and user friendly control software.

Certification of elements in and use of standard reference material 3280 multivitamin/multielement tablets

USDA-ARS?s Scientific Manuscript database

Standard Reference Material (SRM) 3280 Multivitamin/Multielement Tablets was issued by the National Institute of Standards and Technology (NIST) in 2009 and has certified and reference mass fraction values for 13 vitamins, 26 elements, and 2 carotenoids. Elements were measured using two or more ana...

Icing Test Results on an Advanced Two-Dimensional High-Lift Multi-Element Airfoil

NASA Technical Reports Server (NTRS)

Shin, Jaiwon; Wilcox, Peter; Chin, Vincent; Sheldon, David

1994-01-01

An experimental study has been conducted to investigate ice accretions on a high-lift, multi-element airfoil in the Icing Research Tunnel at the NASA Lewis Research Center. The airfoil is representative of an advanced transport wing design. The experimental work was conducted as part of a cooperative program between McDonnell Douglas Aerospace and the NASA Lewis Research Center to improve current understanding of ice accretion characteristics on the multi-element airfoil. The experimental effort also provided ice shapes for future aerodynamic tests at flight Reynolds numbers to ascertain high-lift performance effects. Ice shapes documented for a landing configuration over a variety of icing conditions are presented along with analyses.

Multi-element screening by ICP-MS of two specimens of Napoleon's hair.

PubMed

Kintz, Pascal; Ginet, Morgane; Cirimele, Vincent

2006-10-01

Since 1960, it has been demonstrated by various analytical procedures that high concentrations of arsenic were present in Napoleon's hair. Various authors, indicating that the detected arsenic levels are a consequence of external contamination, have challenged the results of these examinations. In order to shed more light on this historical controversy, we have tested two samples of Napoleon's hair by inductively coupled plasma-mass spectrometry (ICP-MS). The samples of hair were decontaminated with acetone and were cut into small segments. For multi-element screening, hair samples were mineralized in concentrated nitric acid for 1 h at 70 degrees C, diluted 1:40 in specific solution with rhodium as an internal standard, and finally analyzed by ICP-MS on a Thermo Electron ICP/MS X7. Multi-element analysis of Napoleon's hair samples revealed massive amounts of arsenic (42.1 and 37.4 ng/mg), antimony (2.1 and 1.8 ng/mg) and elevated levels of mercury (3.3 and 4.7 ng/mg) and lead (229 and 112 ng/mg). In the case of arsenic, these concentrations, 40 times higher than the normal values, confirm the hypothesis of a significant exposure to arsenic. The concentrations of the other elements, in particular antimony and mercury, are in agreement with the data already known about the therapeutic treatments given to Napoleon, which were based on calomel (salt of mercury) and tartar emetic (antimony).

Masking technique for coating thickness control on large and strongly curved aspherical optics.

PubMed

Sassolas, B; Flaminio, R; Franc, J; Michel, C; Montorio, J-L; Morgado, N; Pinard, L

2009-07-01

We discuss a method to control the coating thickness deposited onto large and strongly curved optics by ion beam sputtering. The technique uses an original design of the mask used to screen part of the sputtered materials. A first multielement mask is calculated from the measured two-dimensional coating thickness distribution. Then, by means of an iterative process, the final mask is designed. By using such a technique, it has been possible to deposit layers of tantalum pentoxide having a high thickness gradient onto a curved substrate 500 mm in diameter. Residual errors in the coating thickness profile are below 0.7%.

An Empirical Analysis of the Effects of a Possible Sinus Infection and Weighted Vest on Functional Analysis Outcomes of Self-Injury Exhibited by a Child with Autism

ERIC Educational Resources Information Center

Carter, Stacy L.

2005-01-01

Analogue functional analysis methodology was used to assess potential maintaining contingencies of episodic self-injurious behavior (SIB) of a 4-year-old child diagnosed with autism. Analogue conditions were presented within a multielement design when the child did, and did not exhibit signs of a possible sinus infection, and when the participant,…

Application of a Navier-Stokes Solver to the Analysis of Multielement Airfoils and Wings Using Multizonal Grid Techniques

NASA Technical Reports Server (NTRS)

Jones, Kenneth M.; Biedron, Robert T.; Whitlock, Mark

1995-01-01

A computational study was performed to determine the predictive capability of a Reynolds averaged Navier-Stokes code (CFL3D) for two-dimensional and three-dimensional multielement high-lift systems. Three configurations were analyzed: a three-element airfoil, a wing with a full span flap and a wing with a partial span flap. In order to accurately model these complex geometries, two different multizonal structured grid techniques were employed. For the airfoil and full span wing configurations, a chimera or overset grid technique was used. The results of the airfoil analysis illustrated that although the absolute values of lift were somewhat in error, the code was able to predict reasonably well the variation with Reynolds number and flap position. The full span flap analysis demonstrated good agreement with experimental surface pressure data over the wing and flap. Multiblock patched grids were used to model the partial span flap wing. A modification to an existing patched- grid algorithm was required to analyze the configuration as modeled. Comparisons with experimental data were very good, indicating the applicability of the patched-grid technique to analyses of these complex geometries.

[Simultaneous determination of multiple elements in airborne particulate samples by X-ray fluorescence spectrometry].

PubMed

Takada, T; Hitosugi, M; Kadowaki, T; Kudo, M

1983-07-01

An energy dispersive X-ray fluorescence spectrometer (EDX) has been applied to determine multielements in the workplace air. The standards for X-ray fluorescence analysis were prepared by the chelate precipitation method on polyvinyl chloride (PVC) membrane filter. And, the specimens were prepared to deposit various metal compounds of different chemical forms by the suspension method on PVC membrane filter, and they were determined with EDX and atomic absorption spectrometer (AAS). The results obtained were as follows. Though there is a difference by each element, an amount less than 3 microgram/cm2 per unit area makes it possible to undergo multielement analysis, that is, is has no influence on fine particle effect (particle size; under 5 microns). Then, effects of the X-ray intensity by different chemical forms are negligible. At the presence the neighboring element and other elements this technique showed greater precision by carrying out on corrective treatment, etc. The coefficient of variation of this technique was in the range of 2.5-6.5% at DDTC-Cu of 0.5-5.0 micrograms/cm2, with the limit of detection for As : 0.002 microgram/cm2, Zn : 0.003 microgram/cm2, Pb : 0.003 microgram/cm2, Cu : 0.004 microgram/cm2, Ni : 0.003 microgram/cm2, Fe : 0.005 microgram/cm2, Mn : 0.008 microgram/cm2, Cr : 0.013 microgram/cm2, respectively. Aerosols collected at the workplace were analyzed with EDX and AAS, and the obtained results showed good agreement with such regression line as y = 1.04 chi + 0.04, the coefficient of correlation being r = 0.995. From these results, this technique was found to be a very excellent method for monitoring of multielements in the workplace air.

Do Multielement Visual Tracking and Visual Search Draw Continuously on the Same Visual Attention Resources?

ERIC Educational Resources Information Center

Alvarez, George A.; Horowitz, Todd S.; Arsenio, Helga C.; DiMase, Jennifer S.; Wolfe, Jeremy M.

2005-01-01

Multielement visual tracking and visual search are 2 tasks that are held to require visual-spatial attention. The authors used the attentional operating characteristic (AOC) method to determine whether both tasks draw continuously on the same attentional resource (i.e., whether the 2 tasks are mutually exclusive). The authors found that observers…

Active control of multi-element rotor blade airfoils

NASA Technical Reports Server (NTRS)

Torok, Michael S. (Inventor); Moffitt, Robert C. (Inventor); Bagai, Ashish (Inventor)

2005-01-01

A multi-element rotor blade includes an individually controllable main element and fixed aerodynamic surface in an aerodynamically efficient location relative to the main element. The main element is controlled to locate the fixed aerodynamic surface in a position to increase lift and/or reduce drag upon the main element at various azimuthal positions during rotation.

COMPARISON OF METALS IN HUMAN MILK AND URINE USING TRACE MULTIELEMENT ANALYSES

EPA Science Inventory

Healthy, nonsmoking women from 18-38 years old twice donated milk and urine (2-7 weeks and 3-4 months postpartum) as part of the EPA's Methods Advancement for Milk Analysis study, a pilot for the National Children's Study (NCS). Our goals were to determine 1) if routine high thro...

Recent progress in the analysis of iced airfoils and wings

NASA Technical Reports Server (NTRS)

Cebeci, Tuncer; Chen, Hsun H.; Kaups, Kalle; Schimke, Sue

1992-01-01

Recent work on the analysis of iced airfoils and wings is described. Ice shapes for multielement airfoils and wings are computed using an extension of the LEWICE code that was developed for single airfoils. The aerodynamic properties of the iced wing are determined with an interactive scheme in which the solutions of the inviscid flow equations are obtained from a panel method and the solutions of the viscous flow equations are obtained from an inverse three-dimensional finite-difference boundary-layer method. A new interaction law is used to couple the inviscid and viscous flow solutions. The newly developed LEWICE multielement code is amplified to a high-lift configuration to calculate the ice shapes on the slat and on the main airfoil and on a four-element airfoil. The application of the LEWICE wing code to the calculation of ice shapes on a MS-317 swept wing shows good agreement with measurements. The interactive boundary-layer method is applied to a tapered iced wing in order to study the effect of icing on the aerodynamic properties of the wing at several angles of attack.

Characterization Of Nuclear Materials Using Time-Of-Flight ICP-MS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buerger, Stefan; Riciputi, Lee R; Bostick, Debra A

2006-01-01

The investigation of illicit trafficking of nuclear materials, nuclear safeguards analysis, and non-proliferation control requires sensitive and isotope-selective detection methods to gain crucial nuclear forensic information like isotope 'fingerprints' and multi-element signatures. The advantage of time-of-flight (TOF) mass spectrometry - quasi-simultaneous multi-mass analysis - combined with an inductively coupled plasma (ICP) ion source provides an analytical instrument with multi-element and multi-isotope capability and good detection limits. A TOF-ICP-MS system thus appears to be an advantageous choice for the investigation and characterization of nuclear materials. We present here results using a GBC OptiMass 8000 time-of-flight ICP-MS for the isotope screening ofmore » solid samples by laser ablation and the multi-element determination of impurities in uranium ore concentrates using matrix matched standards. A laser ablation system (New Wave Research, UP 213) coupled to the TOF-ICP-MS instrument has been used to optimize the system for analysis of non-radioactive metal samples of natural isotopic composition for a variety of elements including Cu, Sr, Zr, Mo, Cd, In, Ba, Ta, W, Re, Pt, and Pb in pure metals, alloys, and glasses to explore precision, accuracy, and detection limits. Similar methods were then applied to measure uranium. When the laser system is optimized, no mass bias correction is required. Precision and accuracy for the determination of the isotopic composition is typically 1 - 3% for elemental concentrations of as little as 50 ppm in the matrix, with no requirement for sample preparation. The laser ablation precision and accuracy are within ~10x of the instrumental limits for liquid analysis (0.1%). We have investigated the capabilities of the TOF-ICP-MS for the analysis of impurities in uranium matrices. Matrix matching has been used to develop calibration curves for a range of impurities (alkaline, earth-alkaline, transition metals, and rare earth elements). These calibration curves have been used to measure impurities in a number of uranium samples. The results from the TOF-ICP-MS will be compared with other mass spectrometric methods.« less

Underlying role of mechanical rigidity and topological constraints in physical sputtering and reactive ion etching of amorphous materials

NASA Astrophysics Data System (ADS)

Bhattarai, Gyanendra; Dhungana, Shailesh; Nordell, Bradley J.; Caruso, Anthony N.; Paquette, Michelle M.; Lanford, William A.; King, Sean W.

2018-05-01

Analytical expressions describing ion-induced sputter or etch processes generally relate the sputter yield to the surface atomic binding energy (Usb) for the target material. While straightforward to measure for the crystalline elemental solids, Usb is more complicated to establish for amorphous and multielement materials due to composition-driven variations and incongruent sublimation. In this regard, we show that for amorphous multielement materials, the ion-driven yield can instead be better understood via a consideration of mechanical rigidity and network topology. We first demonstrate a direct relationship between Usb, bulk modulus, and ion sputter yield for the elements, and then subsequently prove our hypothesis for amorphous multielement compounds by demonstrating that the same relationships exist between the reactive ion etch (RIE) rate and nanoindentation Young's modulus for a series of a -Si Nx :H and a -Si OxCy :H thin films. The impact of network topology is further revealed via application of the Phillips-Thorpe theory of topological constraints, which directly relates the Young's modulus to the mean atomic coordination () for an amorphous solid. The combined analysis allows the trends and plateaus in the RIE rate to be ultimately reinterpreted in terms of the atomic structure of the target material through a consideration of . These findings establish the important underlying role of mechanical rigidity and network topology in ion-solid interactions and provide additional considerations for the design and optimization of radiation-hard materials in nuclear and outer space environments.

Inorganic elemental compositions of commercial multivitamin/mineral dietary supplements: application of collision/reaction cell inductively coupled-mass spectroscopy

USDA-ARS?s Scientific Manuscript database

Microwave digestion followed by analysis using ICP-MS has been shown to be a simple, fast reliable method for the multi-element determination in multivitamin/mineral dietary supplements (MVM). A study of 35 popular MVM dietary supplements revealed that composition and levels varied among products, a...

Laser ablation inductively coupled plasma dynamic reaction cell mass spectrometry for the multi-element analysis of polymers

NASA Astrophysics Data System (ADS)

Resano, M.; García-Ruiz, E.; Vanhaecke, F.

2005-11-01

In this work, the potential of laser ablation-inductively coupled plasma-mass spectrometry for the fast analysis of polymers has been explored. Different real-life samples (polyethylene shopping bags, an acrylonitrile butadiene styrene material and various plastic bricks) as well as several reference materials (VDA 001 to 004, Cd in polyethylene) have been selected for the study. Two polyethylene reference materials (ERM-EC 680 and 681), for which a reference or indicative value for the most relevant metals is available, have proved their suitability as standards for calibration. Special attention has been paid to the difficulties expected for the determination of Cr at the μg g - 1 level in this kind of materials, due to the interference of ArC + ions on the most abundant isotopes of Cr. The use of ammonia as a reaction gas in a dynamic reaction cell is shown to alleviate this problem, resulting in a limit of detection of 0.15 μg g - 1 for this element, while limiting only modestly the possibilities of the technique for simultaneous multi-element analysis. In this regard, As is the analyte most seriously affected by the use of ammonia, and its determination has to be carried out in vented mode, at the expense of measuring time. In all cases studied, accurate results could be obtained for elements ranging in content from the sub-μg g - 1 level to tens of thousands of μg g - 1 . However, the use of an element of known concentration as internal standard may be needed for materials with a matrix significantly different from that of the standard (polyethylene in this work). Precision ranged between 5% and 10% RSD for elements found at the 10 μg g - 1 level or higher, while this value could deteriorate to 20% for analytes found at the sub-μg g - 1 level. Overall, the technique evaluated presents many advantages for the fast and accurate multi-element analysis of these materials, avoiding laborious digestion procedures and minimizing the risk of analyte losses due to the formation of volatile compounds.

Effect of catalyst calcination temperature in the visible light photocatalytic oxidation of gaseous formaldehyde by multi-element doped titanium dioxide.

PubMed

de Luna, Mark Daniel G; Laciste, Maricris T; Tolosa, Nolan C; Lu, Ming-Chun

2018-03-20

The present study investigates the influence of calcination temperature on the properties and photoactivity of multi-element doped TiO 2 . The photocatalysts were prepared by incorporating silver (Ag), fluorine (F), nitrogen (N), and tungsten (W) into the TiO 2 structure via the sol-gel method. Spectroscopic techniques were used to elucidate the correlation between the structural and optical properties of the doped photocatalyst and its photoactivity. XRD results showed that the mean crystallite size increased for undoped photocatalysts and decreased for the doped photocatalysts when calcination was done at higher temperatures. UV-Vis spectra showed that the absorption cut-off wavelength shifted towards the visible light region for the as-synthesized photocatalysts and band gap narrowing was attributed to multi-element doping and calcination. FTIR spectra results showed the shifting of OH-bending absorption bands towards increasing wave numbers. The activity of the photocatalysts was evaluated in terms of gaseous formaldehyde removal under visible light irradiation. The highest photocatalytic removal of gaseous formaldehyde was found at 88%. The study confirms the effectiveness of multi-element doped TiO 2 to remove gaseous formaldehyde in air by visible light photocatalysis and the results have a lot of potential to extend the application to other organic air contaminants.

Evaluation of Graduated vs All-or-None Contingencies on Rate Tasks for Individuals Diagnosed with Autism

ERIC Educational Resources Information Center

Kassardjian, Alyne; Leaf, Jeremy A.; Leaf, Justin B.; Townley-Cochran, Donna; Alcalay, Aditt; Milne, Christine; Dale, Stephanie; Tsuji, Kathleen; Leaf, Ronald; Taubman, Mitchell; McEachin, John

2016-01-01

The graduated reinforcement procedure (also known as differential reinforcement) is an often-used procedure in the field of Applied Behavior Analysis to teach new skills and increase pro-social behaviors. In this study, the researchers used a multi-element design to evaluated the graduated reinforcement procedure for six children with a diagnosis…

Analysis of Indium Tin Oxide Film Using Argon Fluroide (ArF) Laser-Excited Atomic Fluorescence of Ablated Plumes.

PubMed

Ho, Sut Kam; Garcia, Dario Machado

2017-04-01

A two-pulse laser-excited atomic fluorescence (LEAF) technique at 193 nm wavelength was applied to the analysis of indium tin oxide (ITO) layer on polyethylene terephthalate (PET) film. Fluorescence emissions from analytes were induced from plumes generated by first laser pulse. Using this approach, non-selective LEAF can be accomplished for simultaneous multi-element analysis and it overcomes the handicap of strict requirement for laser excitation wavelength. In this study, experimental conditions including laser fluences, times for gating and time delay between pulses were optimized to reveal high sensitivity with minimal sample destruction and penetration. With weak laser fluences of 100 and 125 mJ/cm 2 for 355 and 193 nm pulses, detection limits were estimated to be 0.10% and 0.43% for Sn and In, respectively. In addition, the relation between fluorescence emissions and number of laser shots was investigated; reproducible results were obtained for Sn and In. It shows the feasibility of depth profiling by this technique. Morphologies of samples were characterized at various laser fluences and number of shots to examine the accurate penetration. Images of craters were also investigated using scanning electron microscopy (SEM). The results demonstrate the imperceptible destructiveness of film after laser shot. With such weak laser fluences and minimal destructiveness, this LEAF technique is suitable for thin-film analysis.

Excitation of the three principal spin waves in yttrium iron garnet using a wavelength-specific multi-element antenna

NASA Astrophysics Data System (ADS)

Bang, Wonbae; Jungfleisch, Matthias B.; Lim, Jinho; Trossman, Jonathan; Tsai, C. C.; Hoffmann, Axel; Ketterson, John B.

2018-05-01

We report systematic measurements of the dispersion of long wavelength spin waves for the magnetic field along the three principal directions (supporting the forward volume, backward volume and Damon-Eshbach modes) of a 3.05 μm thick yttrium iron garnet film on a lattice-matched (111) gadolinium gallium garnet substrate obtained using a lithographically patterned, multi-element, 50 μm spatially-resonant, antenna.

Excitation of the three principal spin waves in yttrium iron garnet using a wavelength-specific multi-element antenna

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bang, Wonbae; Jungfleisch, Matthias B.; Lim, Jinho

We report systematic measurements of the dispersion of long wavelength spin waves for the magnetic field along the three principal directions (supporting the forward volume, backward volume and Damon-Eshbach modes) of a 3.05 um thick yttrium iron garnet film on a lattice-matched (111) gadolinium gallium garnet substrate obtained using a lithographically patterned, multi-element, 50 um spatially-resonant, antenna.

Excitation of the three principal spin waves in yttrium iron garnet using a wavelength-specific multi-element antenna

DOE PAGES

Bang, Wonbae; Jungfleisch, Matthias B.; Lim, Jinho; ...

2017-12-22

We report systematic measurements of the dispersion of long wavelength spin waves for the magnetic field along the three principal directions (supporting the forward volume, backward volume and Damon-Eshbach modes) of a 3.05 um thick yttrium iron garnet film on a lattice-matched (111) gadolinium gallium garnet substrate obtained using a lithographically patterned, multi-element, 50 um spatially-resonant, antenna.

Coupling meteorology, metal concentrations, and Pb isotopes for source attribution in archived precipitation samples.

PubMed

Graney, Joseph R; Landis, Matthew S

2013-03-15

A technique that couples lead (Pb) isotopes and multi-element concentrations with meteorological analysis was used to assess source contributions to precipitation samples at the Bondville, Illinois USA National Trends Network (NTN) site. Precipitation samples collected over a 16month period (July 1994-October 1995) at Bondville were parsed into six unique meteorological flow regimes using a minimum variance clustering technique on back trajectory endpoints. Pb isotope ratios and multi-element concentrations were measured using high resolution inductively coupled plasma-sector field mass spectrometry (ICP-SFMS) on the archived precipitation samples. Bondville is located in central Illinois, ~250km downwind from smelters in southeast Missouri. The Mississippi Valley Type ore deposits in Missouri provided a unique multi-element and Pb isotope fingerprint for smelter emissions which could be contrasted to industrial emissions from the Chicago and Indianapolis urban areas (~125km north and east, of Bondville respectively) and regional emissions from electric utility facilities. Differences in Pb isotopes and element concentrations in precipitation corresponded to flow regime. Industrial sources from urban areas, and thorogenic Pb from coal use, could be differentiated from smelter emissions from Missouri by coupling Pb isotopes with variations in element ratios and relative mass factors. Using a three endmember mixing model based on Pb isotope ratio differences, industrial processes in urban airsheds contributed 56±19%, smelters in southeast Missouri 26±13%, and coal combustion 18±7%, of the Pb in precipitation collected in Bondville in the mid-1990s. Copyright © 2012 Elsevier B.V. All rights reserved.

Theoretical study of the effect of an AlGaAs double heterostructure on metal-semiconductor-metal photodetector performance

NASA Technical Reports Server (NTRS)

Salem, Ali F.; Smith, Arlynn W.; Brennan, Kevin F.

1994-01-01

The sizing and efficiency of an aircraft is largely determined by the performance of its high-lift system. Subsonic civil transports most often use deployable multi-element airfoils to achieve the maximum-lift requirements for landing, as well as the high lift-to-drag ratios for take-off. However, these systems produce very complex flow fields which are not fully understood by the scientific community. In order to compete in today's market place, aircraft manufacturers will have to design better high-lift systems. Therefore, a more thorough understanding of the flows associated with these systems is desired. Flight and wind-tunnel experiments have been conducted on NASA Langley's B737-100 research aircraft to obtain detailed full-scale flow measurements on a multi-element high-lift system at various flight conditions. As part of this effort, computational aerodynamic tools are being used to provide preliminary flow-field information for instrumentation development, and to provide additional insight during the data analysis and interpretation process. The purpose of this paper is to demonstrate the ability and usefulness of a three-dimensional low-order potentialflow solver, PMARC, by comparing computational results with data obtained from 1/8 scale wind-tunnel tests. Overall, correlation of experimental and computational data reveals that the panel method is able to predict reasonably well the pressures of the aircraft's multi-element wing at several spanwise stations. PMARC's versatility and usefulness is also demonstrated by accurately predicting inviscid threedimensional flow features for several intricate geometrical regions.

An Analysis of Initial Acquisition and Maintenance of Sight Words Following Picture Matching and Copy, Cover, and Compare Teaching Methods

ERIC Educational Resources Information Center

Conley, Colleen M.; Derby, K. Mark; Roberts-Gwinn, Michelle; Weber, Kimberly P.; McLaughlin, T.F.

2004-01-01

This study compared the copy, cover, and compare method to a picture-word matching method for teaching sight word recognition. Participants were 5 kindergarten students with less than preprimer sight word vocabularies who were enrolled in a public school in the Pacific Northwest. A multielement design was used to evaluate the effects of the two…

Determination of fat-soluble vitamins and carotenoids in standard reference material 3280 multivitamin/multielement tablets by liquid chromatography with absorbance detection.

PubMed

Thomas, Jeanice B; Sharpless, Katherine E; Yen, James H; Rimmer, Catherine A

2011-01-01

The concentrations of selected fat-soluble vitamins and carotenoids in Standard Reference Material (SRM) 3280 Multivitamin/Multielement Tablets have been determined by two independent LC methods, with measurements performed by the National Institute of Standards and Technology (NIST). This SRM has been prepared as part of a collaborative effort between NIST and the National Institutes of Health Office of Dietary Supplements. The SRM is also intended to support the Dietary Supplement Ingredient Database that is being established by the U.S. Department of Agriculture. The methods used at NIST to determine the concentration levels of vitamins A and E, and beta-carotene in the SRM used RPLC with absorbance detection. The relative precision of these methods ranged from 2 to 8% for the analytes measured. SRM 3280 is primarily intended for use in validating analytical methods for the determination of selected vitamins, carotenoids, and elements in multivitamin/multielement tablets and similar matrixes.

Chemical elements in the environment: multi-element geochemical datasets from continental to national scale surveys on four continents

USGS Publications Warehouse

Caritat, Patrice de; Reimann, Clemens; Smith, David; Wang, Xueqiu

2017-01-01

During the last 10-20 years, Geological Surveys around the world have undertaken a major effort towards delivering fully harmonized and tightly quality-controlled low-density multi-element soil geochemical maps and datasets of vast regions including up to whole continents. Concentrations of between 45 and 60 elements commonly have been determined in a variety of different regolith types (e.g., sediment, soil). The multi-element datasets are published as complete geochemical atlases and made available to the general public. Several other geochemical datasets covering smaller areas but generally at a higher spatial density are also available. These datasets may, however, not be found by superficial internet-based searches because the elements are not mentioned individually either in the title or in the keyword lists of the original references. This publication attempts to increase the visibility and discoverability of these fundamental background datasets covering large areas up to whole continents.

Investigation of optical/infrared sensor techniques for application satellites

NASA Technical Reports Server (NTRS)

Kaufman, I.

1972-01-01

A method of scanning an optical sensor array by acoustic surface waves is discussed. Data cover detailed computer based analysis of the operation of a multielement acoustic surface-wave-scanned optical sensor, the development of design and operation techniques that were used to show the feasibility of an integrated array to design several such arrays, and experimental verification of a number of the calculations with discrete sensor devices.

Multivariate class modeling techniques applied to multielement analysis for the verification of the geographical origin of chili pepper.

PubMed

Naccarato, Attilio; Furia, Emilia; Sindona, Giovanni; Tagarelli, Antonio

2016-09-01

Four class-modeling techniques (soft independent modeling of class analogy (SIMCA), unequal dispersed classes (UNEQ), potential functions (PF), and multivariate range modeling (MRM)) were applied to multielement distribution to build chemometric models able to authenticate chili pepper samples grown in Calabria respect to those grown outside of Calabria. The multivariate techniques were applied by considering both all the variables (32 elements, Al, As, Ba, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Fe, Ga, La, Li, Mg, Mn, Na, Nd, Ni, Pb, Pr, Rb, Sc, Se, Sr, Tl, Tm, V, Y, Yb, Zn) and variables selected by means of stepwise linear discriminant analysis (S-LDA). In the first case, satisfactory and comparable results in terms of CV efficiency are obtained with the use of SIMCA and MRM (82.3 and 83.2% respectively), whereas MRM performs better than SIMCA in terms of forced model efficiency (96.5%). The selection of variables by S-LDA permitted to build models characterized, in general, by a higher efficiency. MRM provided again the best results for CV efficiency (87.7% with an effective balance of sensitivity and specificity) as well as forced model efficiency (96.5%). Copyright © 2016 Elsevier Ltd. All rights reserved.

Investigation of production method, geographical origin and species authentication in commercially relevant shrimps using stable isotope ratio and/or multi-element analyses combined with chemometrics: an exploratory analysis.

PubMed

Ortea, Ignacio; Gallardo, José M

2015-03-01

Three factors defining the traceability of a food product are production method (wild or farmed), geographical origin and biological species, which have to be checked and guaranteed, not only in order to avoid mislabelling and commercial fraud, but also to address food safety issues and to comply with legal regulations. The aim of this study was to determine whether these three factors could be differentiated in shrimps using stable isotope ratio analysis of carbon and nitrogen and/or multi-element composition. Different multivariate statistics methods were applied to different data subsets in order to evaluate their performance in terms of classification or predictive ability. Although the success rates varied depending on the dataset used, the combination of both techniques allowed the correct classification of 100% of the samples according to their actual origin and method of production, and 93.5% according to biological species. Even though further studies including a larger number of samples in each group are needed in order to validate these findings, we can conclude that these methodologies should be considered for studies regarding seafood product authenticity. Copyright © 2014 Elsevier Ltd. All rights reserved.

Modeling and Grid Generation of Iced Airfoils

NASA Technical Reports Server (NTRS)

Vickerman, Mary B.; Baez, Marivell; Braun, Donald C.; Hackenberg, Anthony W.; Pennline, James A.; Schilling, Herbert W.

2007-01-01

SmaggIce Version 2.0 is a software toolkit for geometric modeling and grid generation for two-dimensional, singleand multi-element, clean and iced airfoils. A previous version of SmaggIce was described in Preparing and Analyzing Iced Airfoils, NASA Tech Briefs, Vol. 28, No. 8 (August 2004), page 32. To recapitulate: Ice shapes make it difficult to generate quality grids around airfoils, yet these grids are essential for predicting ice-induced complex flow. This software efficiently creates high-quality structured grids with tools that are uniquely tailored for various ice shapes. SmaggIce Version 2.0 significantly enhances the previous version primarily by adding the capability to generate grids for multi-element airfoils. This version of the software is an important step in streamlining the aeronautical analysis of ice airfoils using computational fluid dynamics (CFD) tools. The user may prepare the ice shape, define the flow domain, decompose it into blocks, generate grids, modify/divide/merge blocks, and control grid density and smoothness. All these steps may be performed efficiently even for the difficult glaze and rime ice shapes. Providing the means to generate highly controlled grids near rough ice, the software includes the creation of a wrap-around block (called the "viscous sublayer block"), which is a thin, C-type block around the wake line and iced airfoil. For multi-element airfoils, the software makes use of grids that wrap around and fill in the areas between the viscous sub-layer blocks for all elements that make up the airfoil. A scripting feature records the history of interactive steps, which can be edited and replayed later to produce other grids. Using this version of SmaggIce, ice shape handling and grid generation can become a practical engineering process, rather than a laborious research effort.

Simultaneous trace multielement determination by ICP-OES after solid phase extraction with modified octadecyl silica gel.

PubMed

Karbasi, Mohamad-Hadi; Jahanparast, Babak; Shamsipur, Mojtaba; Hassan, Jalal

2009-10-15

Multielement simultaneous determination of 35 trace elements in environmental samples was carried out by inductively coupled plasma emission spectrometry (ICP-OES) after preconcentration with octadecyl silicagel, modified with aurin tricarboxylic acid (Aluminon). Optimal experimental conditions including pH of sample solution, sample volume, sample and eluent flow rate, type, concentration and volume of eluent and foreign ions effect were investigated and established. Trace element ions in aqueous solution were quantitatively adsorbed onto octadecyl silicagel modified with aurin tricarboxylic acid at pH 8.0 with a flow rate of 11.0 mL min(-1). The adsorbed element ions were eluted with 3-5 mL of 0.5 mol L(-1) HNO(3) at a flow rate of 10.0 mL min(-1) and analyzed by ICP-OES simultaneously. The proposed method has at least preconcentration factor of 100 in water samples, which results high sensitive detection of ultra-trace and trace analysis. The present methodology gave recoveries better than 70% and RSD less than 16%.

Experiments on Lunar Core Composition: Phase Equilibrium Analysis of A Multi-Element (Fe-Ni-S-C) System

NASA Technical Reports Server (NTRS)

Go, B. M.; Righter, K.; Danielson, L.; Pando, K.

2015-01-01

Previous geochemical and geophysical experiments have proposed the presence of a small, metallic lunar core, but its composition is still being investigated. Knowledge of core composition can have a significant effect on understanding the thermal history of the Moon, the conditions surrounding the liquid-solid or liquid-liquid field, and siderophile element partitioning between mantle and core. However, experiments on complex bulk core compositions are very limited. One limitation comes from numerous studies that have only considered two or three element systems such as Fe-S or Fe-C, which do not supply a comprehensive understanding for complex systems such as Fe-Ni-S-Si-C. Recent geophysical data suggests the presence of up to 6% lighter elements. Reassessments of Apollo seismological analyses and samples have also shown the need to acquire more data for a broader range of pressures, temperatures, and compositions. This study considers a complex multi-element system (Fe-Ni-S-C) for a relevant pressure and temperature range to the Moon's core conditions.

Quantitative simultaneous multi-element microprobe analysis using combined wavelength and energy dispersive systems

NASA Technical Reports Server (NTRS)

Walter, L. S.; Doan, A. S., Jr.; Wood, F. M., Jr.; Bredekamp, J. H.

1972-01-01

A combined WDS-EDS system obviates the severe X-ray peak overlap problems encountered with Na, Mg, Al and Si common to pure EDS systems. By application of easily measured empirical correction factors for pulse pile-up and peak overlaps which are normally observed in the analysis of silicate minerals, the accuracy of analysis is comparable with that expected for WDS electron microprobe analyses. The continuum backgrounds are subtracted for the spectra by a spline fitting technique based on integrated intensities between the peaks. The preprocessed data are then reduced to chemical analyses by existing data reduction programs.

The effect of pre-evaporation on ion distributions in inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Liu, Shulan; Beauchemin, Diane

2006-02-01

The connecting tube (2 or 5-mm i. d., 11-cm long) between the spray chamber and the torch was heated (to 400 °C) to investigate the effect of pre-evaporation on the distribution of ions in inductively coupled plasma mass spectrometry (ICP-MS). Axial and radial profiles of analyte ions (Al +, V +, Cr +, Ni +, Zn +, Mn +, Zn +, As +, Se +, Mo +, Cd +, Sb +, La +, Pb +) in 1% HNO 3 as well as some polyatomic ions (LaO +, ArO +, ArN +, CO 2+) were simultaneously obtained on a time-of-flight ICP-MS instrument. Upon heating the connecting tube, the optimal axial position of all elements shifted closer to the load coil. Without the heated tube, 3.5 mm was the compromise axial position for multielemental analysis, which was optimal for 6 analytes. With the heated tube, this position became 1.5 mm, which was then optimal for 9 of the 14 analytes. Furthermore, the radial profiles, which were wide with a plateau in their middle without heating, became significantly narrower and Gaussian-like with a heated tube. This narrowing, which was most important for the 5-mm tube, slightly (by a factor of two at the most) yet significantly (at the 95% confidence level) improved the sensitivity of all elements but Mn upon optimisation of the axial position for compromise multi-element analysis. Furthermore, a concurrent decrease in the standard deviation of the blank was significant at the 95% confidence level for 9 of the 14 analytes. For most of the analytes, this translated into a two-fold to up to an order of magnitude improvement in detection limit, which is commensurate with a reduction of noise resulting from the smaller droplets entering the plasma after traversing the pre-evaporation tube.

X-ray fluorescence analysis of alloy and stainless steels using a mercuric iodide detector

NASA Technical Reports Server (NTRS)

Kelliher, Warren C.; Maddox, W. Gene

1988-01-01

A mercuric iodide detector was used for the XRF analysis of a number of NBS standard steels, applying a specially developed correction method for interelemental effects. It is shown that, using this method and a good peak-deconvolution technique, the HgI2 detector is capable of achieving resolutions and count rates needed in the XRF anlysis of multielement samples. The freedom from cryogenic cooling and from power supplies necessary for an electrically cooled device makes this detector a very good candidate for a portable instrument.

Competitive adsorption of copper(II), cadmium(II), lead(II) and zinc(II) onto basic oxygen furnace slag.

PubMed

Xue, Yongjie; Hou, Haobo; Zhu, Shujing

2009-02-15

Polluted and contaminated water can often contain more than one heavy metal species. It is possible that the behavior of a particular metal species in a solution system will be affected by the presence of other metals. In this study, we have investigated the adsorption of Cd(II), Cu(II), Pb(II), and Zn(II) onto basic oxygen furnace slag (BOF slag) in single- and multi-element solution systems as a function of pH and concentration, in a background solution of 0.01M NaNO(3). In adsorption edge experiments, the pH was varied from 2.0 to 13.0 with total metal concentration 0.84mM in the single element system and 0.21mM each of Cd(II), Cu(II), Pb(II), and Zn(II) in the multi-element system. The value of pH(50) (the pH at which 50% adsorption occurs) was found to follow the sequence Zn>Cu>Pb>Cd in single-element systems, but Pb>Cu>Zn>Cd in the multi-element system. Adsorption isotherms at pH 6.0 in the multi-element systems showed that there is competition among various metals for adsorption sites on BOF slag. The adsorption and potentiometric titrations data for various slag-metal systems were modeled using an extended constant-capacitance surface complexation model that assumed an ion-exchange process below pH 6.5 and the formation of inner-sphere surface complexes at higher pH. Inner-sphere complexation was more dominant for the Cu(II), Pb(II) and Zn(II) systems.

Multi-element stochastic spectral projection for high quantile estimation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ko, Jordan, E-mail: jordan.ko@mac.com; Garnier, Josselin

2013-06-15

We investigate quantile estimation by multi-element generalized Polynomial Chaos (gPC) metamodel where the exact numerical model is approximated by complementary metamodels in overlapping domains that mimic the model’s exact response. The gPC metamodel is constructed by the non-intrusive stochastic spectral projection approach and function evaluation on the gPC metamodel can be considered as essentially free. Thus, large number of Monte Carlo samples from the metamodel can be used to estimate α-quantile, for moderate values of α. As the gPC metamodel is an expansion about the means of the inputs, its accuracy may worsen away from these mean values where themore » extreme events may occur. By increasing the approximation accuracy of the metamodel, we may eventually improve accuracy of quantile estimation but it is very expensive. A multi-element approach is therefore proposed by combining a global metamodel in the standard normal space with supplementary local metamodels constructed in bounded domains about the design points corresponding to the extreme events. To improve the accuracy and to minimize the sampling cost, sparse-tensor and anisotropic-tensor quadratures are tested in addition to the full-tensor Gauss quadrature in the construction of local metamodels; different bounds of the gPC expansion are also examined. The global and local metamodels are combined in the multi-element gPC (MEgPC) approach and it is shown that MEgPC can be more accurate than Monte Carlo or importance sampling methods for high quantile estimations for input dimensions roughly below N=8, a limit that is very much case- and α-dependent.« less

Decomposition techniques

USGS Publications Warehouse

Chao, T.T.; Sanzolone, R.F.

1992-01-01

Sample decomposition is a fundamental and integral step in the procedure of geochemical analysis. It is often the limiting factor to sample throughput, especially with the recent application of the fast and modern multi-element measurement instrumentation. The complexity of geological materials makes it necessary to choose the sample decomposition technique that is compatible with the specific objective of the analysis. When selecting a decomposition technique, consideration should be given to the chemical and mineralogical characteristics of the sample, elements to be determined, precision and accuracy requirements, sample throughput, technical capability of personnel, and time constraints. This paper addresses these concerns and discusses the attributes and limitations of many techniques of sample decomposition along with examples of their application to geochemical analysis. The chemical properties of reagents as to their function as decomposition agents are also reviewed. The section on acid dissolution techniques addresses the various inorganic acids that are used individually or in combination in both open and closed systems. Fluxes used in sample fusion are discussed. The promising microwave-oven technology and the emerging field of automation are also examined. A section on applications highlights the use of decomposition techniques for the determination of Au, platinum group elements (PGEs), Hg, U, hydride-forming elements, rare earth elements (REEs), and multi-elements in geological materials. Partial dissolution techniques used for geochemical exploration which have been treated in detail elsewhere are not discussed here; nor are fire-assaying for noble metals and decomposition techniques for X-ray fluorescence or nuclear methods be discussed. ?? 1992.

A comparison of turbulence models in computing multi-element airfoil flows

NASA Technical Reports Server (NTRS)

Rogers, Stuart E.; Menter, Florian; Durbin, Paul A.; Mansour, Nagi N.

1994-01-01

Four different turbulence models are used to compute the flow over a three-element airfoil configuration. These models are the one-equation Baldwin-Barth model, the one-equation Spalart-Allmaras model, a two-equation k-omega model, and a new one-equation Durbin-Mansour model. The flow is computed using the INS2D two-dimensional incompressible Navier-Stokes solver. An overset Chimera grid approach is utilized. Grid resolution tests are presented, and manual solution-adaptation of the grid was performed. The performance of each of the models is evaluated for test cases involving different angles-of-attack, Reynolds numbers, and flap riggings. The resulting surface pressure coefficients, skin friction, velocity profiles, and lift, drag, and moment coefficients are compared with experimental data. The models produce very similar results in most cases. Excellent agreement between computational and experimental surface pressures was observed, but only moderately good agreement was seen in the velocity profile data. In general, the difference between the predictions of the different models was less than the difference between the computational and experimental data.

Development of a personal dosimetry system based on optically stimulated luminescence of alpha-Al2O3:C for mixed radiation fields.

PubMed

Lee, S Y; Lee, K J

2001-04-01

To develop a personal optically stimulated luminescence (OSL) dosimetry system for mixed radiation fields using alpha-Al2O3:C, a discriminating badge filter system was designed by taking advantage of its optically stimulable properties and energy dependencies. This was done by designing a multi-element badge system for powder layered alpha-Al2O3:C material and an optical reader system based on high-intensity blue light-emitting diode (LED). The design of the multielement OSL dosimeter badge system developed allows the measurement of a personal dose equivalent value Hp(d) in mixed radiation fields of beta and gamma. Dosimetric properties of the personal OSL dosimeter badge system investigated here were the dose response, energy response and multi-readability. Based on the computational simulations and experiments of the proposed dosimeter design, it was demonstrated that a multi-element dosimeter system with an OSL technology based on alpha-Al2O3:C is suitable to obtain personal dose equivalent information in mixed radiation fields.

Rapid Quantitation of Ascorbic and Folic Acids in SRM 3280 Multivitamin/Multielement Tablets using Flow-Injection Tandem Mass Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhandari, Deepak; Kertesz, Vilmos; Van Berkel, Gary J

RATIONALE: Ascorbic acid (AA) and folic acid (FA) are water-soluble vitamins and are usually fortified in food and dietary supplements. For the safety of human health, proper intake of these vitamins is recommended. Improvement in the analysis time required for the quantitative determination of these vitamins in food and nutritional formulations is desired. METHODS: A simple and fast (~5 min) in-tube sample preparation was performed, independently for FA and AA, by mixing extraction solvent with a powdered sample aliquot followed by agitation, centrifugation, and filtration to recover an extract for analysis. Quantitative detection was achieved by flow-injection (1 L injectionmore » volume) electrospray ionization tandem mass spectrometry (ESI-MS/MS) in negative ion mode using the method of standard addition. RESULTS: Method of standard addition was employed for the quantitative estimation of each vitamin in a sample extract. At least 2 spiked and 1 non-spiked sample extract were injected in triplicate for each quantitative analysis. Given an injection-to-injection interval of approximately 2 min, about 18 min was required to complete the quantitative estimation of each vitamin. The concentration values obtained for the respective vitamins in the standard reference material (SRM) 3280 using this approach were within the statistical range of the certified values provided in the NIST Certificate of Analysis. The estimated limit of detections of FA and AA were 13 and 5.9 ng/g, respectively. CONCLUSIONS: Flow-injection ESI-MS/MS was successfully applied for the rapid quantitation of FA and AA in SRM 3280 multivitamin/multielement tablets.« less

Device structure for OLED light device having multi element light extraction and luminescence conversion layer

DOEpatents

Antoniadis,; Homer, Krummacher [Mountain View, CA; Claus, Benjamin [Regensburg, DE

2008-01-22

An apparatus such as a light source has a multi-element light extraction and luminescence conversion layer disposed over a transparent layer of the light source and on the exterior of said light source. The multi-element light extraction and luminescence conversion layer includes a plurality of light extraction elements and a plurality of luminescence conversion elements. The light extraction elements diffuses the light from the light source while luminescence conversion elements absorbs a first spectrum of light from said light source and emits a second spectrum of light.

Computational Modeling for the Flow Over a Multi-Element Airfoil

NASA Technical Reports Server (NTRS)

Liou, William W.; Liu, Feng-Jun

1999-01-01

The flow over a multi-element airfoil is computed using two two-equation turbulence models. The computations are performed using the INS2D) Navier-Stokes code for two angles of attack. Overset grids are used for the three-element airfoil. The computed results are compared with experimental data for the surface pressure, skin friction coefficient, and velocity magnitude. The computed surface quantities generally agree well with the measurement. The computed results reveal the possible existence of a mixing-layer-like region of flow next to the suction surface of the slat for both angles of attack.

A multi-element cosmological model with a complex space-time topology

NASA Astrophysics Data System (ADS)

Kardashev, N. S.; Lipatova, L. N.; Novikov, I. D.; Shatskiy, A. A.

2015-02-01

Wormhole models with a complex topology having one entrance and two exits into the same space-time of another universe are considered, as well as models with two entrances from the same space-time and one exit to another universe. These models are used to build a model of a multi-sheeted universe (a multi-element model of the "Multiverse") with a complex topology. Spherical symmetry is assumed in all the models. A Reissner-Norström black-hole model having no singularity beyond the horizon is constructed. The strength of the central singularity of the black hole is analyzed.

Church Anchor Explosive Sources (SUS) Propagation Measurements

DTIC Science & Technology

1974-12-01

execution of the exercise were carried out by an even larger group . Contributors from ARL/UT Analysis and Interpretation A. L. Anderson S. K. Mitchell T. D...ACODACs) located at sites A, C, :id. D, and a Multielement Super -direc.-tive Array (MESA) located at site E. The primary source track for the data, as shown...estimates, the narrowband spectra for the swot signai dztected in those ranges are inspected to determine the quality cf thb- data. Presumed signals

Preparation for Scaling Studies of Ice-Crystal Icing at the NRC Research Altitude Test Facility

NASA Technical Reports Server (NTRS)

Struk, Peter M.; Bencic, Timothy J.; Tsao, Jen-Ching; Fuleki, Dan; Knezevici, Daniel C.

2013-01-01

This paper describes experiments conducted at the National Research Council (NRC) of Canadas Research Altitiude Test Facility between March 26 and April 11, 2012. The tests, conducted collaboratively between NASA and NRC, focus on three key aspects in preparation for later scaling work to be conducted with a NACA 0012 airfoil model in the NRC Cascade rig: (1) cloud characterization, (2) scaling model development, and (3) ice-shape profile measurements. Regarding cloud characterization, the experiments focus on particle spectra measurements using two shadowgraphy methods, cloud uniformity via particle scattering from a laser sheet, and characterization of the SEA Multi-Element probe. Overviews of each aspect as well as detailed information on the diagnostic method are presented. Select results from the measurements and interpretation are presented which will help guide future work.

Characterization of NIES CRM No. 23 Tea Leaves II for the determination of multielements.

PubMed

Mori, Ikuko; Ukachi, Miyuki; Nagano, Kimiyo; Ito, Hiroyasu; Yoshinaga, Jun; Nishikawa, Masataka

2010-05-01

A candidate environmental certified reference material (CRM) for the determination of multielements in tea leaves and materials of similar matrix, NIES CRM No. 23 Tea Leaves II, has been developed and characterized by the National Institute for Environmental Studies (NIES), Japan. The origin of the material was tea leaves, which were ground, sieved through a 106-microm mesh, homogenized, and then subdivided into amber glass bottles. The results of homogeneity and stability tests indicated that the material was sufficiently homogeneous and stable for use as a reference material. The property values of the material were statistically determined based on chemical analyses by a network of laboratories using a wide range of methods. Sixteen laboratories participated in the characterization, and nine certified values and five reference values were obtained. These property values of the candidate CRM, which are expressed as mass fractions, were close to the median and/or mean values of the mass fractions of elements in various tea products. The candidate CRM is appropriate for use in analytical quality control and in the evaluation of methods used in the analysis of tea and materials of similar matrix.

Design and development of ultra-wideband 3 dB hybrid coupler for Ion cyclotron resonance frequency heating in tokamak.

PubMed

Yadav, Rana Pratap; Kumar, Sunil; Kulkarni, S V

2014-04-01

Design and development of a high power ultra-wideband, 3 dB tandem hybrid coupler is presented and its application in ICRF heating of the tokamak is discussed. In order to achieve the desired frequency band of 38-112 MHz and 200 kW power handling capability, the 3 dB hybrid coupler is developed using two 3-element 8.34 ± 0.2 dB coupled lines sections in tandem. In multi-element coupled lines, junctions are employed for the joining of coupled elements that produce the undesirable reactance called junction discontinuity effect. The effect becomes prominent in the high power multi-element coupled lines for high frequency (HF) and very high frequency(VHF) applications because of larger structural dimensions. Junction discontinuity effect significantly deteriorates coupling and output performance from the theoretical predictions. For the analysis of junction discontinuity effect and its compensation, a theoretical approach has been developed and generalized for n-element coupled lines section. The theory has been applied in the development of the 3 dB hybrid coupler. The fabricated hybrid coupler has been experimentally characterized using vector network analyzer and obtained results are found in good agreement with developed theory.

First-Order Model Management With Variable-Fidelity Physics Applied to Multi-Element Airfoil Optimization

NASA Technical Reports Server (NTRS)

Alexandrov, N. M.; Nielsen, E. J.; Lewis, R. M.; Anderson, W. K.

2000-01-01

First-order approximation and model management is a methodology for a systematic use of variable-fidelity models or approximations in optimization. The intent of model management is to attain convergence to high-fidelity solutions with minimal expense in high-fidelity computations. The savings in terms of computationally intensive evaluations depends on the ability of the available lower-fidelity model or a suite of models to predict the improvement trends for the high-fidelity problem, Variable-fidelity models can be represented by data-fitting approximations, variable-resolution models. variable-convergence models. or variable physical fidelity models. The present work considers the use of variable-fidelity physics models. We demonstrate the performance of model management on an aerodynamic optimization of a multi-element airfoil designed to operate in the transonic regime. Reynolds-averaged Navier-Stokes equations represent the high-fidelity model, while the Euler equations represent the low-fidelity model. An unstructured mesh-based analysis code FUN2D evaluates functions and sensitivity derivatives for both models. Model management for the present demonstration problem yields fivefold savings in terms of high-fidelity evaluations compared to optimization done with high-fidelity computations alone.

Geology and surface geochemistry of the Roosevelt Springs Known Geothermal Resource Area, Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lovell, J.S.; Meyer, W.T.; Atkinson, D.J.

1980-01-01

Available data on the Roosevelt area were synthesized to determine the spatial arrangement of the rocks, and the patterns of mass and energy flow within them. The resulting model lead to a new interpretation of the geothermal system, and provided ground truth for evaluating the application of soil geochemistry to exploration for concealed geothermal fields. Preliminary geochemical studies comparing the surface microlayer to conventional soil sampling methods indicated both practical and chemical advantages for the surface microlayer technique, which was particularly evident in the case of As, Sb and Cs. Subsequent multi-element analyses of surface microlayer samples collected over anmore » area of 100 square miles were processed to produce single element contour maps for 41 chemical parameters. Computer manipulation of the multi-element data using R-mode factor analysis provided the optimum method of interpretation of the surface microlayer data. A trace element association of As, Sb and Cs in the surface microlayer provided the best indication of the leakage of geothermal solutions to the surface, while regional mercury trends may reflect the presence of a mercury vapour anomaly above a concealed heat source.« less

Stray-light analyses of the multielement telescope for imaging and spectroscopy coronagraph on Solar Orbiter

NASA Astrophysics Data System (ADS)

Sandri, Paolo; Fineschi, Silvano; Romoli, Marco; Taccola, Matteo; Landini, Federico; Da Deppo, Vania; Naletto, Giampiero; Morea, Danilo; Naughton, Denis; Antonucci, Ester

2018-01-01

The modeling of the scattering phenomena for the multielement telescope for imaging and spectroscopy (METIS) coronagraph on board the European Space Agency Solar Orbiter is reported. METIS is an inverted occultation coronagraph including two optical paths: the broadband imaging of the full corona in linearly polarized visible-light (580 to 640 nm) and the narrow-band imaging of the full corona in the ultraviolet Lyman-α (121.6 nm). METIS will have the unique opportunity of observing the solar outer atmosphere as close to the Sun as 0.28 AU and from up to 35 deg out-of-ecliptic. The stray-light simulations performed on the UV and VL channels of the METIS analyzing the contributors of surface microroughness, particulate contamination, cosmetic defects, and diffraction are reported. The results obtained with the nonsequential modality of Zemax OpticStudio are compared with two different approaches: the Monte Carlo ray trace with Advanced Systems Analysis Program (ASAP®) and a semianalytical model. The results obtained with the three independently developed approaches are in considerable agreement and show compliance to the requirement of stray-light level for both the UV and VL channels.

Method for measuring integrated sensitivity of solar cells and multielement photoconverters using an X-Y scanner

NASA Astrophysics Data System (ADS)

Naumov, V. V.; Grebenshchikov, O. A.; Zalesskii, V. B.

2006-09-01

We describe a method for automated measurement of the integrated sensitivity of solar cells (SCs) and multielement photoconverters (MPCs) using an experimental apparatus including a Pentium III personal computer (PC), an HP-34401A digital multimeter (DM), a stabilized radiation source (SRS), a controllable focusing system, an X-Y positioning device based on CD-RW optical disk storage devices. The method provides high accuracy in measuring the size of photosensitive areas of the solar cells and multielement photoconverters and inhomogeneities in their active regions, which makes it possible to correct the production process in the development stage and during fabrication of test prototypes for the solar cells and multielement photoconverters. The radiation power from the stabilized radiation source was ≤1 W; the ranges of the scanning steps along the X, Y coordinates were 10 100 µm, the range of the transverse cross sectional diameters of the focused radiation beam was 10 100 µm, the measurable photocurrents were 10-9 A to 2 A; scanning rate along the X, Y coordinates, ≤100 mm/sec; relative mean-square error (RMSE) for measurement of the integrated sensitivity of the solar cells, 0.2 ≤ γS int ≤ 0.9% in the ranges of measurable photocurrents 1 mA ≤ Iph ≤ 750 mA and areas 0.1 ≤ A ≤ 25 cm2 for number of measurements equal to ≤ 2· 105; instability of the radiation power (luminosity) ≤ 0.08% for 1 h or ≤ 0.4% for 8 h continuous operation; stabilized power range for the stabilized radiation source, 10-2 102 W. The software was written in Delphi 7.0.

Comparison of jet Mach number decay data with a correlation and jet spreading contours for a large variety of nozzles

NASA Technical Reports Server (NTRS)

Groesbeck, D. E.; Huff, R. G.; Vonglahn, U. H.

1977-01-01

Small-scale circular, noncircular, single- and multi-element nozzles with flow areas as large as 122 sq cm were tested with cold airflow at exit Mach numbers from 0.28 to 1.15. The effects of multi-element nozzle shape and element spacing on jet Mach number decay were studied in an effort to reduce the noise caused by jet impingement on externally blown flap (EBF) STOL aircraft. The jet Mach number decay data are well represented by empirical relations. Jet spreading and Mach number decay contours are presented for all configurations tested.

Multi-element germanium detectors for synchrotron applications

NASA Astrophysics Data System (ADS)

Rumaiz, A. K.; Kuczewski, A. J.; Mead, J.; Vernon, E.; Pinelli, D.; Dooryhee, E.; Ghose, S.; Caswell, T.; Siddons, D. P.; Miceli, A.; Baldwin, J.; Almer, J.; Okasinski, J.; Quaranta, O.; Woods, R.; Krings, T.; Stock, S.

2018-04-01

We have developed a series of monolithic multi-element germanium detectors, based on sensor arrays produced by the Forschungzentrum Julich, and on Application-specific integrated circuits (ASICs) developed at Brookhaven. Devices have been made with element counts ranging from 64 to 384. These detectors are being used at NSLS-II and APS for a range of diffraction experiments, both monochromatic and energy-dispersive. Compact and powerful readout systems have been developed, based on the new generation of FPGA system-on-chip devices, which provide closely coupled multi-core processors embedded in large gate arrays. We will discuss the technical details of the systems, and present some of the results from them.

Certification of elements in and use of standard reference material 3280 multivitamin/multielement tablets.

PubMed

Turk, Gregory C; Sharpless, Katherine E; Cleveland, Danielle; Jongsma, Candice; Mackey, Elizabeth A; Marlow, Anthony F; Oflaz, Rabia; Paul, Rick L; Sieber, John R; Thompson, Robert Q; Wood, Laura J; Yu, Lee L; Zeisler, Rolf; Wise, Stephen A; Yen, James H; Christopher, Steven J; Day, Russell D; Long, Stephen E; Greene, Ella; Harnly, James; Ho, I-Pin; Betz, Joseph M

2013-01-01

Standard Reference Material 3280 Multivitamin/ Multielement Tablets was issued by the National Institute of Standards and Technology in 2009, and has certified and reference mass fraction values for 13 vitamins, 26 elements, and two carotenoids. Elements were measured using two or more analytical methods at NIST with additional data contributed by collaborating laboratories. This reference material is expected to serve a dual purpose: to provide quality assurance in support of a database of dietary supplement products and to provide a means for analysts, dietary supplement manufacturers, and researchers to assess the appropriateness and validity of their analytical methods and the accuracy of their results.

Transverse-structure electrostatic charged particle beam lens

DOEpatents

Moran, M.J.

1998-10-13

Electrostatic particle-beam lenses using a concentric co-planar array of independently biased rings can be advantageous for some applications. Traditional electrostatic lenses often consist of axial series of biased rings, apertures, or tubes. The science of lens design has devoted much attention to finding axial arrangements that compensate for the substantial optical aberrations of the individual elements. Thus, as with multi-element lenses for light, a multi-element charged-particle lens can have optical behavior that is far superior to that of the individual elements. Transverse multiple-concentric-ring lenses achieve high performance, while also having advantages in terms of compactness and optical versatility. 7 figs.

Transverse-structure electrostatic charged particle beam lens

DOEpatents

Moran, Michael J.

1998-01-01

Electrostatic particle-beam lenses using a concentric co-planar array of independently biased rings can be advantageous for some applications. Traditional electrostatic lenses often consist of axial series of biased rings, apertures, or tubes. The science of lens design has devoted much attention to finding axial arrangements that compensate for the substantial optical aberrations of the individual elements. Thus, as with multi-element lenses for light, a multi-element charged-particle lens can have optical behavior that is far superior to that of the individual elements. Transverse multiple-concentric-ring lenses achieve high performance, while also having advantages in terms of compactness and optical versatility.

Detecting false positives in multielement designs: implications for brief assessments.

PubMed

Bartlett, Sara M; Rapp, John T; Henrickson, Marissa L

2011-11-01

The authors assessed the extent to which multielement designs produced false positives using continuous duration recording (CDR) and interval recording with 10-s and 1-min interval sizes. Specifically, they created 6,000 graphs with multielement designs that varied in the number of data paths, and the number of data points per data path, using a random number generator. In Experiment 1, the authors visually analyzed the graphs for the occurrence of false positives. Results indicated that graphs depicting only two sessions for each condition (e.g., a control condition plotted with multiple test conditions) produced the highest percentage of false positives for CDR and interval recording with 10-s and 1-min intervals. Conversely, graphs with four or five sessions for each condition produced the lowest percentage of false positives for each method. In Experiment 2, they applied two new rules, which were intended to decrease false positives, to each graph that depicted a false positive in Experiment 1. Results showed that application of new rules decreased false positives to less than 5% for all of the graphs except for those with two data paths and two data points per data path. Implications for brief assessments are discussed.

Efficient simulation of incompressible viscous flow over multi-element airfoils

NASA Technical Reports Server (NTRS)

Rogers, Stuart E.; Wiltberger, N. Lyn; Kwak, Dochan

1992-01-01

The incompressible, viscous, turbulent flow over single and multi-element airfoils is numerically simulated in an efficient manner by solving the incompressible Navier-Stokes equations. The computer code uses the method of pseudo-compressibility with an upwind-differencing scheme for the convective fluxes and an implicit line-relaxation solution algorithm. The motivation for this work includes interest in studying the high-lift take-off and landing configurations of various aircraft. In particular, accurate computation of lift and drag at various angles of attack, up to stall, is desired. Two different turbulence models are tested in computing the flow over an NACA 4412 airfoil; an accurate prediction of stall is obtained. The approach used for multi-element airfoils involves the use of multiple zones of structured grids fitted to each element. Two different approaches are compared: a patched system of grids, and an overlaid Chimera system of grids. Computational results are presented for two-element, three-element, and four-element airfoil configurations. Excellent agreement with experimental surface pressure coefficients is seen. The code converges in less than 200 iterations, requiring on the order of one minute of CPU time (on a CRAY YMP) per element in the airfoil configuration.

Efficient simulation of incompressible viscous flow over multi-element airfoils

NASA Technical Reports Server (NTRS)

Rogers, Stuart E.; Wiltberger, N. Lyn; Kwak, Dochan

1993-01-01

The incompressible, viscous, turbulent flow over single and multi-element airfoils is numerically simulated in an efficient manner by solving the incompressible Navier-Stokes equations. The solution algorithm employs the method of pseudo compressibility and utilizes an upwind differencing scheme for the convective fluxes, and an implicit line-relaxation scheme. The motivation for this work includes interest in studying high-lift take-off and landing configurations of various aircraft. In particular, accurate computation of lift and drag at various angles of attack up to stall is desired. Two different turbulence models are tested in computing the flow over an NACA 4412 airfoil; an accurate prediction of stall is obtained. The approach used for multi-element airfoils involves the use of multiple zones of structured grids fitted to each element. Two different approaches are compared; a patched system of grids, and an overlaid Chimera system of grids. Computational results are presented for two-element, three-element, and four-element airfoil configurations. Excellent agreement with experimental surface pressure coefficients is seen. The code converges in less than 200 iterations, requiring on the order of one minute of CPU time on a CRAY YMP per element in the airfoil configuration.

Differential maneuvering simulator data reduction and analysis software

NASA Technical Reports Server (NTRS)

Beasley, G. P.; Sigman, R. S.

1972-01-01

A multielement data reduction and analysis software package has been developed for use with the Langley differential maneuvering simulator (DMS). This package, which has several independent elements, was developed to support all phases of DMS aircraft simulation studies with a variety of both graphical and tabular information. The overall software package is considered unique because of the number, diversity, and sophistication of the element programs available for use in a single study. The purpose of this paper is to discuss the overall DMS data reduction and analysis package by reviewing the development of the various elements of the software, showing typical results that can be obtained, and discussing how each element can be used.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newhouse, P. F.; Guevarra, D.; Umehara, M.

Energy technologies are enabled by materials innovations, requiring efficient methods to search high dimensional parameter spaces, such as multi-element alloying for enhancing solar fuels photoanodes.

High-lift flow-physics flight experiments on a subsonic civil transport aircraft (B737-100)

NASA Technical Reports Server (NTRS)

Vandam, Cornelis P.

1994-01-01

As part of the subsonic transport high-lift program, flight experiments are being conducted using NASA Langley's B737-100 to measure the flow characteristics of the multi-element high-lift system at full-scale high-Reynolds-number conditions. The instrumentation consists of hot-film anemometers to measure boundary-layer states, an infra-red camera to detect transition from laminar to turbulent flow, Preston tubes to measure wall shear stress, boundary-layer rakes to measure off-surface velocity profiles, and pressure orifices to measure surface pressure distributions. The initial phase of this research project was recently concluded with two flights on July 14. This phase consisted of a total of twenty flights over a period of about ten weeks. In the coming months the data obtained in this initial set of flight experiments will be analyzed and the results will be used to finalize the instrumentation layout for the next set of flight experiments scheduled for Winter and Spring of 1995. The main goal of these upcoming flights will be: (1) to measure more detailed surface pressure distributions across the wing for a range of flight conditions and flap settings; (2) to visualize the surface flows across the multi-element wing at high-lift conditions using fluorescent mini tufts; and (3) to measure in more detail the changes in boundary-layer state on the various flap elements as a result of changes in flight condition and flap deflection. These flight measured results are being correlated with experimental data measured in ground-based facilities as well as with computational data calculated with methods based on the Navier-Stokes equations or a reduced set of these equations. Also these results provide insight into the extent of laminar flow that exists on actual multi-element lifting surfaces at full-scale high-life conditions. Preliminary results indicate that depending on the deflection angle, the slat and flap elements have significant regions of laminar flow over a wide range of angles of attack. Boundary-layer transition mechanisms that were observed include attachment-line contamination on the slat and inflectional instability on the slat and fore flap. Also, the results agree fairly well with the predictions reported in a paper presented at last year's AIAA Fluid Dynamics Conference. The fact that extended regions of laminar flow are shown to exist on the various elements of the high-lift system raises the question what the effect is of loss of laminar flow as a result of insect contamiantion, rain or ice accumulation on high-life performance.

Improvements in surface singularity analysis and design methods. [applicable to airfoils

NASA Technical Reports Server (NTRS)

Bristow, D. R.

1979-01-01

The coupling of the combined source vortex distribution of Green's potential flow function with contemporary numerical techniques is shown to provide accurate, efficient, and stable solutions to subsonic inviscid analysis and design problems for multi-element airfoils. The analysis problem is solved by direct calculation of the surface singularity distribution required to satisfy the flow tangency boundary condition. The design or inverse problem is solved by an iteration process. In this process, the geometry and the associated pressure distribution are iterated until the pressure distribution most nearly corresponding to the prescribed design distribution is obtained. Typically, five iteration cycles are required for convergence. A description of the analysis and design method is presented, along with supporting examples.

Stable isotope dilution analysis of hydrologic samples by inductively coupled plasma mass spectrometry

USGS Publications Warehouse

Garbarino, John R.; Taylor, Howard E.

1987-01-01

Inductively coupled plasma mass spectrometry is employed in the determination of Ni, Cu, Sr, Cd, Ba, Ti, and Pb in nonsaline, natural water samples by stable isotope dilution analysis. Hydrologic samples were directly analyzed without any unusual pretreatment. Interference effects related to overlapping isobars, formation of metal oxide and multiply charged ions, and matrix composition were identified and suitable methods of correction evaluated. A comparability study snowed that single-element isotope dilution analysis was only marginally better than sequential multielement isotope dilution analysis. Accuracy and precision of the single-element method were determined on the basis of results obtained for standard reference materials. The instrumental technique was shown to be ideally suited for programs associated with certification of standard reference materials.

Combination of complementary data mining methods for geographical characterization of extra virgin olive oils based on mineral composition.

PubMed

Sayago, Ana; González-Domínguez, Raúl; Beltrán, Rafael; Fernández-Recamales, Ángeles

2018-09-30

This work explores the potential of multi-element fingerprinting in combination with advanced data mining strategies to assess the geographical origin of extra virgin olive oil samples. For this purpose, the concentrations of 55 elements were determined in 125 oil samples from multiple Spanish geographic areas. Several unsupervised and supervised multivariate statistical techniques were used to build classification models and investigate the relationship between mineral composition of olive oils and their provenance. Results showed that Spanish extra virgin olive oils exhibit characteristic element profiles, which can be differentiated on the basis of their origin in accordance with three geographical areas: Atlantic coast (Huelva province), Mediterranean coast and inland regions. Furthermore, statistical modelling yielded high sensitivity and specificity, principally when random forest and support vector machines were employed, thus demonstrating the utility of these techniques in food traceability and authenticity research. Copyright © 2018 Elsevier Ltd. All rights reserved.

Environmentally induced amplitude death and firing provocation in large-scale networks of neuronal systems

NASA Astrophysics Data System (ADS)

Pankratova, Evgeniya V.; Kalyakulina, Alena I.

2016-12-01

We study the dynamics of multielement neuronal systems taking into account both the direct interaction between the cells via linear coupling and nondiffusive cell-to-cell communication via common environment. For the cells exhibiting individual bursting behavior, we have revealed the dependence of the network activity on its scale. Particularly, we show that small-scale networks demonstrate the inability to maintain complicated oscillations: for a small number of elements in an ensemble, the phenomenon of amplitude death is observed. The existence of threshold network scales and mechanisms causing firing in artificial and real multielement neural networks, as well as their significance for biological applications, are discussed.

Detection of foreign body using fast thermoacoustic tomography with a multielement linear transducer array

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nie Liming; Xing Da; Yang Diwu

2007-04-23

Current imaging modalities face challenges in clinical applications due to limitations in resolution or contrast. Microwave-induced thermoacoustic imaging may provide a complementary modality for medical imaging, particularly for detecting foreign objects due to their different absorption of electromagnetic radiation at specific frequencies. A thermoacoustic tomography system with a multielement linear transducer array was developed and used to detect foreign objects in tissue. Radiography and thermoacoustic images of objects with different electromagnetic properties, including glass, sand, and iron, were compared. The authors' results demonstrate that thermoacoustic imaging has the potential to become a fast method for surgical localization of occult foreignmore » objects.« less

Crosstalk-free operation of multielement superconducting nanowire single-photon detector array integrated with single-flux-quantum circuit in a 0.1 W Gifford-McMahon cryocooler.

PubMed

Yamashita, Taro; Miki, Shigehito; Terai, Hirotaka; Makise, Kazumasa; Wang, Zhen

2012-07-15

We demonstrate the successful operation of a multielement superconducting nanowire single-photon detector (SSPD) array integrated with a single-flux-quantum (SFQ) readout circuit in a compact 0.1 W Gifford-McMahon cryocooler. A time-resolved readout technique, where output signals from each element enter the SFQ readout circuit with finite time intervals, revealed crosstalk-free operation of the four-element SSPD array connected with the SFQ readout circuit. The timing jitter and the system detection efficiency were measured to be 50 ps and 11.4%, respectively, which were comparable to the performance of practical single-pixel SSPD systems.

Implications for Metallographic Cooling Rates, Derived from Fine-Scale Analytical Traverses Across Kamacite, Taenite, and Tetrataenite in the Butler Iron Meteorite

NASA Technical Reports Server (NTRS)

Jones, J. H.; Ross, D. K.; Chabot, N. L.; Keller, L. P.

2016-01-01

The "M-shaped" Ni concentrations across Widmanstatten patterns in iron meteorites, mesosiderites, and ordinary chondrites are commonly used to calculate cooling rates. As Ni-poor kamacite exolves from Ni-rich taenite, Ni concentrations build up at the kamacite-taenite interface because of the sluggish diffusivity of Ni. Quantitative knowledge of experimentally-determined Ni diffusivities, coupled with the shape of the M-profile, have been used to allow calculation of cooling rates that pertained at low temperatures, less than or equal to 500 C. However, determining Ni metallographic cooling rates are challenging, due to the sluggish diffusivity of Ni at low temperatures. There are three potential difficulties in using Ni cooling rates at low temperatures: (i) Ni diffusivities are typically extrapolated from higher-temperature measurements; (ii) Phase changes occur at low temperatures that may be difficult to take into account; and (iii) It appears that Ge in kamacite and taenite has continued to equilibrate (or attempted to equilibrate) at temperatures below those that formed the M-shaped Ni profile. Combining Ni measurements with those of other elements has the potential to provide a way to confirm or challenge Ni-determined cooling rates, as well as provide insight into the partitioning behaviors of elements during the cooling of iron meteorites. Despite these benefits, studies that examine elemental profiles of Ni along with other elements in iron meteorites are limited, often due to the low concentration levels of the other elements and associated analytical challenges. The Butler iron meteorite provides a good opportunity to conduct a multi-element analytical study, due to the higher concentration levels of key elements in addition to Fe and Ni. In this work, we perform combined analysis for six elements in the Butler iron to determine the relative behaviors of these elements during the evolution of iron meteorites, with implications for metallographic cooling rates.

[Study on microwave digestion of coal for the determination of multi-element by ICP-OES and ICP-MS].

PubMed

Wang, Hui; Song, Qiang; Yao, Qiang; Chen, Chang-He; Yu, Fei-Lu

2012-06-01

Effects of temperature and four acids (HNO3, HNO3/H2O2, HNO3/HF and HNO3/HF+H3BO3) on the coal decomposition by microwave digestion and the multi-element analysis were studied. SARM20 was used as a coal standard reference material. The contents of 10 mineral elements (Al, Ca, Fe, Mg, K, Na, S, Si, Sr and Ti) in the coal SARM20 were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES). And the contents of 20 heavy metals (Li, Be, Sc, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, As, Se, Zr, Sn, Cs, Ba, Ce, Eu and Pb) were determined by inductively coupled plasma-mass spectrometry (ICP-MS). The results showed that the coal was completely decomposed by microwave digestion with HNO3/HF+ H3BO3 at 210 degrees C. Good recoveries for all elements in the coal SARM20 were obtained by this two-step microwave digestion method. The recoveries of the 10 mineral elements were from 87.5% to 98.8%, and the recoveries of the 20 heavy metals were from 85% to 112.5%. All RSDs of tests were below 3%.

Multielement fingerprinting as a tool in origin authentication of PGI food products: Tropea red onion.

PubMed

Furia, Emilia; Naccarato, Attilio; Sindona, Giovanni; Stabile, Gaetano; Tagarelli, Antonio

2011-08-10

Tropea red onion ( Allium cepa L. var. Tropea) is among the most highly appreciated Italian products. It is cultivated in specific areas of Calabria and, due to its characteristics, was recently awarded with the protected geographical indications (PGI) certification from the European Union. A reliable classification of onion samples in groups corresponding to "Tropea" and "non-Tropea" categories is now available to the producers. This important goal has been achieved through the evaluation of three supervised chemometric approaches. Onion samples with PGI brand (120) and onion samples not cultivated following the production regulations (80) were digested by a closed-vessel microwave oven system. ICP-MS equipped with a dynamic reaction cell was used to determine the concentrations of 25 elements (Al, Ba, Ca, Cd, Ce, Cr, Dy, Eu, Fe, Ga, Gd, Ho, La, Mg, Mn, Na, Nd, Ni, Pr, Rb, Sm, Sr, Tl, Y, and Zn). The multielement fingerprint was processed using linear discriminant analysis (LDA) (standard and stepwise), soft independent modeling of class analogy (SIMCA), and back-propagation artificial neural network (BP-ANN). The cross-validation procedure has shown good results in terms of the prediction ability for all of the chemometric models: standard LDA, 94.0%; stepwise LDA, 94.5%; SIMCA, 95.5%; and BP-ANN, 91.5%.

Biosorption of metal ions using a low cost modified adsorbent (Mauritia flexuosa): experimental design and mathematical modeling.

PubMed

Melo, Diego de Quadros; Vidal, Carla Bastos; Medeiros, Thiago Coutinho; Raulino, Giselle Santiago Cabral; Dervanoski, Adriana; Pinheiro, Márcio do Carmo; Nascimento, Ronaldo Ferreira do

2016-09-01

Buriti fibers were subjected to an alkaline pre-treatment and tested as an adsorbent to investigate the adsorption of copper, cadmium, lead and nickel in mono- and multi-element aqueous solutions, the results showed an increase in the adsorption capacity compared to the unmodified Buriti fiber. The effects of pH, adsorbent mass, agitation rate and initial metal ions concentration on the efficiency of the adsorption process were studied using a fractional 2(4-1) factorial design, and the results showed that all four parameters influenced metal adsorption differently. Fourier transform infrared spectrometry and X-ray fluorescence analysis were used to identify the groups that participated in the adsorption process and suggest its mechanisms and they indicated the probable mechanisms involved in the adsorption process are mainly ion exchange. Kinetic and thermodynamic equilibrium parameters were determined. The adsorption kinetics were adjusted to the homogeneous diffusion model. The adsorption equilibrium was reached in 30 min for Cu(2+) and Pb(2+), 20 min for Ni(2+) and instantaneously for Cd(2+). The results showed a significant difference was found in the competitiveness for the adsorption sites. A mathematical model was used to simulate the breakthrough curves in multi-element column adsorption considering the influences of external mass transfer and intraparticle diffusion resistance.

Design and Fabrication of High Gain Multi-element Multi-segment Quarter-sector Cylindrical Dielectric Resonator Antenna

NASA Astrophysics Data System (ADS)

Ranjan, Pinku; Gangwar, Ravi Kumar

2017-12-01

A novel design and analysis of quarter cylindrical dielectric resonator antenna (q-CDRA) with multi-element and multi-segment (MEMS) approach has been presented. The MEMS q-CDRA has been designed by splitting four identical quarters from a solid cylinder and then multi-segmentation approach has been utilized to design q-CDRA. The proposed antenna has been designed for enhancement in bandwidth as well as for high gain. For bandwidth enhancement, multi-segmentation method has been explained for the selection of dielectric constant of materials. The performance of the proposed MEMS q-CDRA has been demonstrated with design guideline of MEMS approach. To validate the antenna performance, three segments q-CDRA has been fabricated and analyzed practically. The simulated results have been in good agreement with measured one. The MEMS q-CDRA has wide impedance bandwidth (|S11|≤-10 dB) of 133.8 % with monopole-like radiation pattern. The proposed MEMS q-CDRA has been operating at TM01δ mode with the measured gain of 6.65 dBi and minimum gain of 4.5 dBi in entire operating frequency band (5.1-13.7 GHz). The proposed MEMS q-CDRA may find appropriate applications in WiMAX and WLAN band.

Multi-element compound specific stable isotope analysis of volatile organic compounds at trace levels in groundwater samples

NASA Astrophysics Data System (ADS)

Herrero-Martín, Sara; Nijenhuis, Ivonne; Schmidt, Marie; Wolfram, Diana; Richnow, Hans. H.; Gehre, Matthias

2013-04-01

Groundwater pollution remains one of the major environmental and health concerns. A thorough understanding of sources, sinks and transformation processes of groundwater contaminants is needed to improve risk management evaluation, and to design efficient remediation and water treatment strategies. Isotopic tools provide unique information for an in-depth understanding of the fate of organic chemicals in the environment. During the last decades compound specific isotope analysis (CSIA) of complex mixtures, using gas chromatography-isotope ratio mass spectrometry (GC-IRMS), has gained popularity for the characterization and risk assessment of hazardous waste sites and for isotope forensics of organic contaminants. Multi-element isotope fingerprinting of organic substances provides a more robust framework for interpretation than the isotope analysis of only one element. One major challenge for application of CSIA is the analysis of trace levels of organic compounds in environmental matrices. It is necessary to inject 1 nmol carbon or 8 nmol hydrogen on column, to obtain an accurate and precise measurement of the isotope ratios, which is between two and three orders of magnitude larger than the amount of compound needed for conventional analysis of compound concentrations. Therefore, efficient extraction and pre-concentration techniques have to be integrated with GC-IRMS. Further research is urgently needed in this field, to evaluate the potential of novel and environmental-friendly sample pre-treatment techniques for CSIA to lower the detection limits and extending environmental applications. In this study, the novel coupling of a headspace autosampler (HS) with a programmed temperature vaporizer (PTV), allowing large volume injection of headspace samples, is proposed to improve the sensitivity of CSIA. This automatic, fast and solvent free strategy provides a significant increase on the sensitivity of GC-based methods maintaining the simple headspace instrumentation. The method was developed for the multi-element isotope analysis (carbon and hydrogen) of priority volatile organic groundwater pollutants (methyl tert-butyl ether (MTBE), benzene, toluene, ethylbenzene and o-xylene (BTEX)), and for carbon isotope analysis of chlorinated benzenes and ethenes. The extraction and injection conditions were optimized in terms of maximum sensitivity and minimum isotope effects. During the injection of the headspace sample, the liner is maintained at a low temperature, such that the compounds are retained in a hydrophobic insert packing while the water vapor is eliminated through the split line. With the optimized conditions, it was possible to inject up to 5mL headspace sample with no significant carbon or hydrogen isotopic effects except for the most hydrophobic substance (MTBE), which was subject to a small and reproducible isotope fractionation for hydrogen. The increment on method sensitivity was at least 20 fold in comparison with conventional static headspace analysis. The environmental applicability of the HS-PTV-GC-IRMS method was evaluated by the analysis of groundwater samples from different contaminated field sites, containing BTEX and chlorinated volatile organic contaminants in the low µg/L range. The results obtained demonstrate that this pre-concentration technique is highly promising to enhance the limits of detection of current CSIA methods and broaden its possibilities.

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions

PubMed Central

Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia

2018-01-01

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents’ efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements’ removal efficiency which resulted to be in correlation with the specific adsorbents’ chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements. PMID:29495363

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions.

PubMed

Massimi, Lorenzo; Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia

2018-02-26

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents' efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements' removal efficiency which resulted to be in correlation with the specific adsorbents' chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements.

Multi-Element Integrated Project Planning at Kennedy Space Center

NASA Technical Reports Server (NTRS)

Mullon, Robert

2008-01-01

This presentation demonstrates how the ASRC Scheduling team developed working practices to support multiple NASA and ASRC Project Managers using the enterprise capabilities of Primavera P6 and P6 Web Access. This work has proceeded as part of Kennedy Ground Systems' preparation for its transition from the Shuttle Program to the Constellation Program. The presenters will cover Primavera's enterprise-class capabilities for schedule development, integrated critical path analysis, and reporting, as well as advanced Primavera P6 Web Access tools and techniques for communicating project status.

Sensitive determination of Hg together with Mn, Fe, Cu by combined photochemical vapor generation and pneumatic nebulization in the programmable temperature spray chamber and inductively coupled plasma optical emission spectrometry.

PubMed

Giersz, Jacek; Bartosiak, Magdalena; Jankowski, Krzysztof

2017-05-15

Continuous photo-induced generation of mercury cold vapor has been successfully coupled with conventional pneumatic nebulization in programmable temperature spray chamber (PCVG-PN-PTSC) allowing fast, sensitive and easy multi-element analysis. The applied technique enabled simultaneous determination of non-volatile forming elements (Fe, Cu, Mn) and volatile Hg, while 15% v/v formic acid is present in the sample. PTSC elevated temperature (40°C) causes partial conversion of sample matrix into vapor form, thus improving plasma robustness. The efficiency of Hg vapor generation and its transport to the plasma is close to 100%. Moreover, spray chamber temperature stabilization improved the precision of the measurements (Hg signal RSD below 0.5%). The achieved limit of detection for Hg (90pgmL -1 ) at 194.23nm with no monochromator purge is better by almost two orders of magnitude than that obtained by conventional PN-ICP-OES. On the other hand, LODs for non-vapor forming elements are comparable to those obtained with pneumatic nebulization. The linear dynamic ranges for all examined elements are at least three orders of magnitude up to 1000ngmL -1 . None mutual interference between examined analytes (Hg, Fe, Cu, Mn) has been observed. The method was validated by the analysis of two CRM materials of different matrix composition (waste water ERM CA713 and estuarine sediment ERM CC580) giving satisfactory results. As low as 2 ppb of Hg can he directly determined in waste water. The proposed procedure uses mild reagents and allows for fast multi-element analysis, and matches green chemistry requirements. Copyright © 2017 Elsevier B.V. All rights reserved.

Multielement analysis of interplanetary dust particles using TOF-SIMS

NASA Technical Reports Server (NTRS)

Stephan, T.; Kloeck, W.; Jessberger, E. K.; Rulle, H.; Zehnpfenning, J.

1993-01-01

Sections of three stratospheric particles (U2015G1, W7029*A27, and L2005P9) were analyzed with TOF-SIMS (Time Of Flight-Secondary Ion Mass Spectrometry) continuing our efforts to investigate the element distribution in interplanetary dust particles (IDP's) with high lateral resolution (approximately 0.2 micron), to examine possible atmospheric contamination effects, and to further explore the abilities of this technique for element analysis of small samples. The samples, previously investigated with SXRF (synchrotron X-ray fluorescence analysis), are highly enriched in Br (Br/Fe: 59 x CI, 9.2 x CI, and 116 x CI, respectively). U2015G1 is the IDP with the by far highest Zn/Fe-ratio (81 x CI) ever reported in chondritic particles.

Applications of laser-induced breakdown spectrometry (LIBS) in surface analysis.

PubMed

Vadillo, J M; Palanco, S; Romero, M D; Laserna, J J

1996-07-01

The applicability of laser-induced breakdown spectrometry (LIBS) for surface analysis is presented in terms of its lateral and depth resolution. A pulsed N(2) laser at 337.1 nm (3.65 J/cm(2)) was used to irradiate solar cells employed for photovoltaic energy production. Laser produced plasmas were collected and detected using a charge-coupled device. An experimental device developed in the laboratory permits an exact synchronization of sample positioning using an XY motorized system with laser pulses. Multielement analysis with lateral resolution of up to 30 microm is feasible with the present system. Three-dimensional capabilities of the system are used for studies on the distribution of carbon impurities at the surface of the solar cells.

Metric-wave and decimetric-wave aperture synthesis systems (review)

NASA Astrophysics Data System (ADS)

Ilyasov, Y. P.

1984-09-01

Aperture synthesis systems using metric or decimetric waves are adequate and promising for astrophysical study of extragalactic radioemission sources, operation with metric waves being characterized by destabilizing effects of the ionosphere and thus requiring special methods of data processing. Methods of closure phase and closure amplitude were proposed and then successfully implemented in very-large-baseline radiotelescope and multi-element interferometers, respectively. Several radiotelescopes were developed which operate in the supersynthesis mode, with rotation of the Earth used for filling the space-frequency plane. Further achievements include the Swarup system (Uti/INDIA) with phase-stable interferometer, the Jodrell Bank system (Manchester/UK), the Palmer Merlin multielement system (UK) with CLEAN procedure and CORTEL telescope correction algorithm, the VLA system (USA), and the international giant equatorial radiotelescope.

Multi-element germanium detectors for synchrotron applications

DOE PAGES

Rumaiz, A. K.; Kuczewski, A. J.; Mead, J.; ...

2018-04-27

In this paper, we have developed a series of monolithic multi-element germanium detectors, based on sensor arrays produced by the Forschungzentrum Julich, and on Application-specific integrated circuits (ASICs) developed at Brookhaven. Devices have been made with element counts ranging from 64 to 384. These detectors are being used at NSLS-II and APS for a range of diffraction experiments, both monochromatic and energy-dispersive. Compact and powerful readout systems have been developed, based on the new generation of FPGA system-on-chip devices, which provide closely coupled multi-core processors embedded in large gate arrays. Finally, we will discuss the technical details of the systems,more » and present some of the results from them.« less

Cross-flow vortex structure and transition measurements using multi-element hot films

NASA Technical Reports Server (NTRS)

Agarwal, Naval K.; Mangalam, Siva M.; Maddalon, Dal V.; Collier, Fayette S., Jr.

1991-01-01

An experiment on a 45-degree swept wing was conducted to study three-dimensional boundary-layer characteristics using surface-mounted, micro-thin, multi-element hot-film sensors. Cross-flow vortex structure and boundary-layer transition were measured from the simultaneously acquired signals of the hot films. Spanwise variation of the root-mean-square (RMS) hot-film signal show a local minima and maxima. The distance between two minima corresponds to the stationary cross-flow vortex wavelength and agrees with naphthalene flow-visualization results. The chordwise and spanwise variation of amplified traveling (nonstationary) cross-flow disturbance characteristics were measured as Reynolds number was varied. The frequency of the most amplified cross-flow disturbances agrees with linear stability theory.

Multi-element germanium detectors for synchrotron applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rumaiz, A. K.; Kuczewski, A. J.; Mead, J.

In this paper, we have developed a series of monolithic multi-element germanium detectors, based on sensor arrays produced by the Forschungzentrum Julich, and on Application-specific integrated circuits (ASICs) developed at Brookhaven. Devices have been made with element counts ranging from 64 to 384. These detectors are being used at NSLS-II and APS for a range of diffraction experiments, both monochromatic and energy-dispersive. Compact and powerful readout systems have been developed, based on the new generation of FPGA system-on-chip devices, which provide closely coupled multi-core processors embedded in large gate arrays. Finally, we will discuss the technical details of the systems,more » and present some of the results from them.« less

Overview of Marshall Space Flight Center Activities for the Combustion Stability Tool Development Program

NASA Technical Reports Server (NTRS)

Kenny, R. J.; Greene, W. D.

2016-01-01

This presentation covers the overall scope, schedule, and activities associated with the NASA - Marshall Space Flight Center (MSFC) involvement with the Combustion Stability Tool Development (CSTD) program. The CSTD program is funded by the Air Force Space & Missile Systems Center; it is approximately two years in duration and; and it is sponsoring MSFC to: design, fabricate, & execute multi-element hardware testing, support Air Force Research Laboratory (AFRL) single element testing, and execute testing of a small-scale, multi-element combustion chamber. Specific MSFC Engineering Directorate involvement, per CSTD-sponsored task, will be outlined. This presentation serves a primer for the corresponding works that provide details of the technical work performed by individual groups within MSFC.

MULTIELEMENT SOLID PHASE PRECONCENTRATION USING A CHELATING RESIN OF STYRENE DIVINYLBENZENE COPOLYMER AND APPLICATION TO ANALYSIS OF SEAWATER AND FISH OTOLITHS BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY (ICP�MS)

PubMed Central

Zereen, Fahmida; Yilmaz, Vedat; Arslan, Zikri

2013-01-01

A new chelating resin has been synthesized by immobilizing 4–(2–thiazolylazo) resorcinol (TAR) onto styrene divinlybenzene copolymer and examined for on-line solid phase extraction/preconcentration of Cd, Co, Cu, Ni, Pb and Zn in seawater and fish otoliths for determination by inductively plasma mass spectrometry (ICP-MS). A volume of 5.0 mL sample solution was loaded onto the mini column of TAR immobilized resin at 2.0 mL min−1 via a sequential injection system. The optimum pH for multielement preconcentration was around pH 5.5. Recoveries were better than 96% in artificial seawater. Elution was achieved with 1.0 mL of 0.75 mol L−1 HNO3. The resin possesses large sorption capacity ranging from 82.0 µmol g−1 for Pb to 319 µmol g−1 for Cu. The detection limits (3s) varied between 0.0016 µg L−1 (Cd) and to 0.015 µg L−1 (Zn) for preconcentration of 5.0 mL blank solutions (pH 5.5). Relative standard deviation (RSD)for three replicate runs was between 0.3% (Cd) and 6% (Zn) at 1.0 µg L−1 level. The procedure was validated by analysis of Nearshore Seawater certified reference material (CASS–4), and then successfully applied to the determination of the trace elements in fish otoliths (CRM 22) and in coastal seawater and estuarine water samples. PMID:24976635

Combinatorial alloying improves bismuth vanadate photoanodes via reduced monoclinic distortion

DOE PAGES

Newhouse, P. F.; Guevarra, D.; Umehara, M.; ...

2018-01-01

Energy technologies are enabled by materials innovations, requiring efficient methods to search high dimensional parameter spaces, such as multi-element alloying for enhancing solar fuels photoanodes.

Multi-element fiber technology for space-division multiplexing applications.

PubMed

Jain, S; Rancaño, V J F; May-Smith, T C; Petropoulos, P; Sahu, J K; Richardson, D J

2014-02-24

A novel technological approach to space division multiplexing (SDM) based on the use of multiple individual fibers embedded in a common polymer coating material is presented, which is referred to as Multi-Element Fiber (MEF). The approach ensures ultralow crosstalk between spatial channels and allows for cost-effective ways of realizing multi-spatial channel amplification and signal multiplexing/demultiplexing. Both the fabrication and characterization of a passive 3-element MEF for data transmission, and an active 5-element erbium/ytterbium doped MEF for cladding-pumped optical amplification that uses one of the elements as an integrated pump delivery fiber is reported. Finally, both components were combined to emulate an optical fiber network comprising SDM transmission lines and amplifiers, and illustrate the compatibility of the approach with existing installed single-mode WDM fiber systems.

Computational Modeling For The Transitional Flow Over A Multi-Element Airfoil

NASA Technical Reports Server (NTRS)

Liou, William W.; Liu, Feng-Jun; Rumsey, Chris L. (Technical Monitor)

2000-01-01

The transitional flow over a multi-element airfoil in a landing configuration are computed using a two equation transition model. The transition model is predictive in the sense that the transition onset is a result of the calculation and no prior knowledge of the transition location is required. The computations were performed using the INS2D) Navier-Stokes code. Overset grids are used for the three-element airfoil. The airfoil operating conditions are varied for a range of angle of attack and for two different Reynolds numbers of 5 million and 9 million. The computed results are compared with experimental data for the surface pressure, skin friction, transition onset location, and velocity magnitude. In general, the comparison shows a good agreement with the experimental data.

Measurement of crossflow vortices, attachment-line flow, and transition using microthin hot films

NASA Technical Reports Server (NTRS)

Mangalam, S. M.; Agarwal, N. K.; Maddalon, D. V.; Saric, W. S.

1990-01-01

A flow diagnostic experiment was conducted on a 45-deg swept-wing model using surface-mounted, multielement, microthin, hot-film sensors. The cross-flow vortex spacing, the attachment-line flow characteristics, and the transition region were all determined using an advanced data acquisition and instrumentation system. In addition to the frequencies of traveling waves predicted by linear stability theory, amplified disturbances at much higher frequencies were observed. Simultaneous measurements from sensors located at a number of chord and span locations highlighted the strong three-dimensionality of the boundary-layer flow in the presence of cross-flow vortices. The state of the attachment-line boundary layer was determined using a multielement sensor wrapped around the wing leading edge. The transition region flow characteristics were also identified.

Modeling 3D-CSIA data: Carbon, chlorine, and hydrogen isotope fractionation during reductive dechlorination of TCE to ethene.

PubMed

Van Breukelen, Boris M; Thouement, Héloïse A A; Stack, Philip E; Vanderford, Mindy; Philp, Paul; Kuder, Tomasz

2017-09-01

Reactive transport modeling of multi-element, compound-specific isotope analysis (CSIA) data has great potential to quantify sequential microbial reductive dechlorination (SRD) and alternative pathways such as oxidation, in support of remediation of chlorinated solvents in groundwater. As a key step towards this goal, a model was developed that simulates simultaneous carbon, chlorine, and hydrogen isotope fractionation during SRD of trichloroethene, via cis-1,2-dichloroethene (and trans-DCE as minor pathway), and vinyl chloride to ethene, following Monod kinetics. A simple correction term for individual isotope/isotopologue rates avoided multi-element isotopologue modeling. The model was successfully validated with data from a mixed culture Dehalococcoides microcosm. Simulation of Cl-CSIA required incorporation of secondary kinetic isotope effects (SKIEs). Assuming a limited degree of intramolecular heterogeneity of δ 37 Cl in TCE decreased the magnitudes of SKIEs required at the non-reacting Cl positions, without compromising the goodness of model fit, whereas a good fit of a model involving intramolecular CCl bond competition required an unlikely degree of intramolecular heterogeneity. Simulation of H-CSIA required SKIEs in H atoms originally present in the reacting compounds, especially for TCE, together with imprints of strongly depleted δ 2 H during protonation in the products. Scenario modeling illustrates the potential of H-CSIA for source apportionment. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

Element concentrations in growth rings of trees near an abandoned wood-preserving plant site at Jackson, Tennessee

USGS Publications Warehouse

Yanosky, T.M.; Carmichael, J.K.

1993-01-01

Multielement analysis was performed on individual annual rings of trees growing at and near an abandoned wood-preserving plant site in Jackson, Tennessee, that operated from the early 1930's until 1981. Numerous organic compounds associated with the wood-preserving process have been detected in soils, ground water, and surface water within much of the site. Tree-ring investigations were conducted prior to investigations of ground water downgradient from the site to determine if trees preserved an areal and temporal record of contaminant movement into offsite areas. Increment cores were collected from trees on the abandoned plant site, in downgradient areas west and south of the site, and at two locations presumably unaffected by contamination from the site. Multielement analysis by proton-induced X-ray emission was performed on 5 to 15 individual growth rings from each of 34 trees that ranged in age from about 5 to 50 years. Concentrations of 16 elements were evaluated by analyzing average concentrations within the 1987, 1989, and 1990 rings of all trees; analyzing element-concentration trends along entire core radii; and analyzing element correlations between and among trees. Concentrations of some nutrients and trace metals were elevated in the outermost sapwood rings of some trees that grow south and southwest of the most contaminated part of the site; small trees on the main part of the site and larger trees to the west generally contained fewer rings with elevated concentrations, particularly of trace metals. Concentrations of several elements elevated in tree rings also were elevated in water samples collected from the reach of a stream that flows near the southwestern part of the site. Multielement analysis of each ring of a willow growing along the southern boundary of the site detected extremely large concentrations of chromium, nickel, and iron in rings that formed in 1986 and thereafter. Relative increases in the concentrations of these elements also were detected in a silver maple growing next to the willow, but not in another silver maple growing 150 meters farther to the west. An oak growing in the southwestern part of the study area contained large concentrations of calcium and several trace elements, and some trees south of the abandoned site contained large concentrations of phosphorus or potassium. Concentrations of trace metals and nutrients in some trees may be related to wood-preserving activities at the site and possibly to remedial efforts conducted during the early to mid 1980's.However, the possibility cannot be discounted that large concentrations of some elements are from sources other than the wood-preserving facility, or in part from flooding of the South Fork Forked Deer River.

[Progress in the application of laser ablation ICP-MS to surface microanalysis in material science].

PubMed

Zhang, Yong; Jia, Yun-hai; Chen, Ji-wen; Shen, Xue-jing; Liu, Ying; Zhao, Leiz; Li, Dong-ling; Hang, Peng-cheng; Zhao, Zhen; Fan, Wan-lun; Wang, Hai-zhou

2014-08-01

In the present paper, apparatus and theory of surface analysis is introduced, and the progress in the application of laser ablation ICP-MS to microanalysis in ferrous, nonferrous and semiconductor field is reviewed in detail. Compared with traditional surface analytical tools, such as SEM/EDS (scanning electron microscopy/energy dispersive spectrum), EPMA (electron probe microanalysis analysis), AES (auger energy spectrum), etc. the advantage is little or no sample preparation, adjustable spatial resolution according to analytical demand, multi-element analysis and high sensitivity. It is now a powerful complementary method to traditional surface analytical tool. With the development of LA-ICP-MS technology maturing, more and more analytical workers will use this powerful tool in the future, and LA-ICP-MS will be a super star in elemental analysis field just like LIBS (Laser-induced breakdown spectroscopy).

Optimization of x-ray capillary optics for mammography

NASA Astrophysics Data System (ADS)

Ross, Richard E.; Bradford, Carla D.; Peppler, Walter W.

2002-05-01

The purpose of this study is to develop a full-field digital mammography system utilizing capillary optics. Specific aims are to identify optic properties that affect image quality and to optimize those properties in the design of a multi-element capillary array. It has been shown that polycapillary optics significantly improve mammographic image quality through increased resolution and reduced x-ray scatter. For practical clinical application much larger multi-element optics will be required. This study quantified the contributing factors to the multi-element optic MTF and investigated methods to determine optimal parameters for a practical design. Individual and a prototype multi-element array of linearly tapered optics with a common focal point were investigated. A conventional (MO/MO) mammography tube and computed radiography system were used. The system and optic MTF were measured using the angled slit method with a slit camera (10 micron slit). MTF measurements were performed with both stationary and scanned optics. Contributions to MTF included: distortion within individual optics, misalignment between optics, capillary channel size, and vibration. Measurement techniques used to identify and quantify the contributions to optic MTF included a phantom chosen specifically for polycapillary optics. This phantom provided a method for assessing the coherence among capillaries within an optic as well as the relative alignment of the optics within the array. In addition, modifications to the scanning procedure allowed for the isolation and quantification of several contributors to the system MTF. Specifically, measurements were made using a stationary optic, a scanning optic, and an optic placed at multiple locations within the imaged field of view. These techniques yielded the optic MTF, the degradation of MTF due to loss of coherence within the optic, and the degradation of MTF due to vibration of the scanning mechanism. Distortion within individual optics was, typically, quite small. However, MTF degradation resulting from twist was significant in some optics. MTF degradation due to misalignment was relatively large in the prototype triad. Modeling found that misalignment up to 50 microns reduced MTF by less than 10 percent up to 3 cycles/mm. Channel diameters of 52 microns and 85 microns reduced MTF by 9 percent to 20 percent at 5 cycles/mm and provided an optimal tradeoff between transmission and MTF. Vibration was identified as a significant degradation to MTF but can easily reduced with simple modifications. In spite of some reduced optic MTF values, system MTF has always been significantly improved - in some cases almost by the magnification ratio. These results allow for accurate modeling of optic performance and optimization of design parameters. This study demonstrates that a multi-element array can be produced with nearly optimal properties. A large area array suitable for clinical trial is feasible and is the next step in this program.

Total mass difference statistics algorithm: a new approach to identification of high-mass building blocks in electrospray ionization Fourier transform ion cyclotron mass spectrometry data of natural organic matter.

PubMed

Kunenkov, Erast V; Kononikhin, Alexey S; Perminova, Irina V; Hertkorn, Norbert; Gaspar, Andras; Schmitt-Kopplin, Philippe; Popov, Igor A; Garmash, Andrew V; Nikolaev, Evgeniy N

2009-12-15

The ultrahigh-resolution Fourier transform ion cyclotron resonance (FTICR) mass spectrum of natural organic matter (NOM) contains several thousand peaks with dozens of molecules matching the same nominal mass. Such a complexity poses a significant challenge for automatic data interpretation, in which the most difficult task is molecular formula assignment, especially in the case of heavy and/or multielement ions. In this study, a new universal algorithm for automatic treatment of FTICR mass spectra of NOM and humic substances based on total mass difference statistics (TMDS) has been developed and implemented. The algorithm enables a blind search for unknown building blocks (instead of a priori known ones) by revealing repetitive patterns present in spectra. In this respect, it differs from all previously developed approaches. This algorithm was implemented in designing FIRAN-software for fully automated analysis of mass data with high peak density. The specific feature of FIRAN is its ability to assign formulas to heavy and/or multielement molecules using "virtual elements" approach. To verify the approach, it was used for processing mass spectra of sodium polystyrene sulfonate (PSS, M(w) = 2200 Da) and polymethacrylate (PMA, M(w) = 3290 Da) which produce heavy multielement and multiply-charged ions. Application of TMDS identified unambiguously monomers present in the polymers consistent with their structure: C(8)H(7)SO(3)Na for PSS and C(4)H(6)O(2) for PMA. It also allowed unambiguous formula assignment to all multiply-charged peaks including the heaviest peak in PMA spectrum at mass 4025.6625 with charge state 6- (mass bias -0.33 ppm). Application of the TMDS-algorithm to processing data on the Suwannee River FA has proven its unique capacities in analysis of spectra with high peak density: it has not only identified the known small building blocks in the structure of FA such as CH(2), H(2), C(2)H(2)O, O but the heavier unit at 154.027 amu. The latter was identified for the first time and assigned a formula C(7)H(6)O(4) consistent with the structure of dihydroxyl-benzoic acids. The presence of these compounds in the structure of FA has so far been numerically suggested but never proven directly. It was concluded that application of the TMDS-algorithm opens new horizons in unfolding molecular complexity of NOM and other natural products.

Otolith edge fingerprints as approach for stock identification of Genidens barbus

NASA Astrophysics Data System (ADS)

Avigliano, Esteban; Maichak de Carvalho, Barbara; Leisen, Mathieu; Romero, Rurik; Velasco, Gonzalo; Vianna, Marcelo; Barra, Fernando; Volpedo, Alejandra Vanina

2017-07-01

The purpose of this paper is to assess the use of multi-elemental otolith fingerprints as a tool to delimit catfish Genidens barbus fish stocks in four estuaries from the southwestern Atlantic Ocean. Barium:Calcium (Ca), Magnesium:Ca, Manganese:Ca, Sodium:Ca and Strontium:Ca ratios in the otolith edge were determined by LA-ICPMS. PERMANOVA analysis reveal significant differences in the multi-element signatures among estuaries (p = 0.0001-0.002). Reclassification rates of quadratic discriminant analysis are high, averaging 89.9% (78-100%). The new data presented here show that the otolith chemistry is a potential tool for stock identification, and indicates the presence of at least four stocks which should probably be handled independently.

SRXRF determination of the multielement composition of the hair and blood of the children of Tundra Nenetz population

NASA Astrophysics Data System (ADS)

Chankina, O. V.; Kovalskaya, G. A.; Koutzenogii, K. P.; Osipova, L. P.; Savchenko, T. I.

2001-09-01

SRXRF has been used to determine the multielement composition of the hair and blood of Tundra Nenetz children. The method allows one to simultaneously determine 21 elements in the blood and 22 elements in the hair. Individual differences have been revealed in the element composition of the hair and blood. Sexual and age changes have been revealed in the content of some elements in the hair. A technique has been developed to prepare blood and hair samples for measuring the element composition by the SRXRF method. The blood samples were prepared by spreading 20 μl over the 1 cm 2 Whatman filter. The hair samples were obtained by pressing in the form of tablets of 1 cm in diameter and a mass of 10-40 mg.

Recent Turbulence Model Advances Applied to Multielement Airfoil Computations

NASA Technical Reports Server (NTRS)

Rumsey, Christopher L.; Gatski, Thomas B.

2000-01-01

A one-equation linear turbulence model and a two-equation nonlinear explicit algebraic stress model (EASM) are applied to the flow over a multielement airfoil. The effect of the K-epsilon and K-omega forms of the two-equation model are explored, and the K-epsilon form is shown to be deficient in the wall-bounded regions of adverse pressure gradient flows. A new K-omega form of EASM is introduced. Nonlinear terms present in EASM are shown to improve predictions of turbulent shear stress behind the trailing edge of the main element and near midflap. Curvature corrections are applied to both the one- and two-equation turbulence models and yield only relatively small local differences in the flap region, where the flow field undergoes the greatest curvature. Predictions of maximum lift are essentially unaffected by the turbulence model variations studied.

A new large solid angle multi-element silicon drift detector system for low energy X-ray fluorescence spectroscopy

NASA Astrophysics Data System (ADS)

Bufon, J.; Schillani, S.; Altissimo, M.; Bellutti, P.; Bertuccio, G.; Billè, F.; Borghes, R.; Borghi, G.; Cautero, G.; Cirrincione, D.; Fabiani, S.; Ficorella, F.; Gandola, M.; Gianoncelli, A.; Giuressi, D.; Kourousias, G.; Mele, F.; Menk, R. H.; Picciotto, A.; Rachevski, A.; Rashevskaya, I.; Sammartini, M.; Stolfa, A.; Zampa, G.; Zampa, N.; Zorzi, N.; Vacchi, A.

2018-03-01

Low-energy X-ray fluorescence (LEXRF) is an essential tool for bio-related research of organic samples, whose composition is dominated by light elements. Working at energies below 2 keV and being able to detect fluorescence photons of lightweight elements such as carbon (277 eV) is still a challenge, since it requires in-vacuum operations to avoid in-air photon absorption. Moreover, the detectors must have a thin entrance window and collect photons at an angle of incidence near 90 degrees to minimize the absorption by the protective coating. Considering the low fluorescence yield of light elements, it is important to cover a substantial part of the solid angle detecting ideally all emitted X-ray fluorescence (XRF) photons. Furthermore, the energy resolution of the detection system should be close to the Fano limit in order to discriminate elements whose XRF emission lines are often very close within the energy spectra. To ensure all these features, a system consisting of four monolithic multi-element silicon drift detectors was developed. The use of four separate detector units allows optimizing the incidence angle on all the sensor elements. The multi-element approach in turn provides a lower leakage current on each anode, which, in combination with ultra-low noise preamplifiers, is necessary to achieve an energy resolution close to the Fano limit. The potential of the new detection system and its applicability for typical LEXRF applications has been proved on the Elettra TwinMic beamline.

A New Clinical HIFU System (Teleson II)

NASA Astrophysics Data System (ADS)

Ma, Yixin; Symonds-Tayler, Richard; Rivens, Ian H.; ter Haar, Gail R.

2007-05-01

Previous clinical trials with our first prototype HIFU system (Teleson I) for the treatment of liver tumors, demonstrated a major challenge to be treatment of those tumors located behind the ribs. We have designed a new multi-element transducer for rib sparing. Initial simulation and experimental results (using a single channel power amplifier) are very encouraging. A new clinical HIFU system which can drive the multi-element transducer and control each channel independently is being designed and constructed. This second version of a clinical prototype HIFU system consists of a 3D motorised gantry, a multi-channel signal generator, a multi-channel power amplifier, a user interface PC, an embedded controller and auxiliary circuits for real-time interleaving/synchronization control and a to-be-implemented safety monitoring and data logging unit. For multi-element transducers, each element can be individually switched on and off for rib sparing, and phase and amplitude modulated for potential phased array applications. The multi-channel power amplifier can be switched on/off very rapidly at required intervals to interleave with ultrasound B-Scan imaging for HIFU monitoring or radiation force elastography imaging via a dedicated interleaving/timing module. The gantry movement can also be synchronised with power amplifier on/off and phase/amplitude updating for lesion generation under a wide variety of conditions including single lesions, lesion arrays and lesions "tracks" created whilst translating the active transducer. Results from testing the system using excised tissue will be presented.

Nanostructured multielement (TiHfZrNbVTa)N coatings before and after implantation of N+ ions (1018 cm-2): Their structure and mechanical properties

NASA Astrophysics Data System (ADS)

Pogrebnjak, A. D.; Bondar, O. V.; Borba, S. O.; Abadias, G.; Konarski, P.; Plotnikov, S. V.; Beresnev, V. M.; Kassenova, L. G.; Drodziel, P.

2016-10-01

Multielement high entropy alloy (HEA) nitride (TiHfZrNbVTa)N coatings were deposited by vacuum arc and their structural and mechanical stability after implantation of high doses of N+ ions, 1018 cm-2, were investigated. The crystal structure and phase composition were characterized by X-ray diffraction (XRD) and Transmission Electron Microscopy, while depth-resolved nanoindentation tests were used to determine the evolution of hardness and elastic modulus along the implantation depth. XRD patterns show that coatings exhibit a main phase with fcc structure, which preferred orientation varies from (1 1 1) to (2 0 0), depending on the deposition conditions. First-principles calculations reveal that the presence of Nb atoms could favor the formation of solid solution with fcc structure in multielement HEA nitride. TEM results showed that amorphous and nanostructured phases were formed in the implanted coating sub-surface layer (∼100 nm depth). Concentration of nitrogen reached 90 at% in the near-surface layer after implantation, and decreased at higher depth. Nanohardness of the as-deposited coatings varied from 27 to 38 GPa depending on the deposition conditions. Ion implantation led to a significant decrease of the nanohardness to 12 GPa in the implanted region, while it reaches 24 GPa at larger depths. However, the H/E ratio is ⩾0.1 in the sub-surface layer due to N+ implantation, which is expected to have beneficial effect on the wear properties.

An analysis of initial acquisition and maintenance of sight words following picture matching and copy cover, and compare teaching methods.

PubMed

Conley, Colleen M; Derby, K Mark; Roberts-Gwinn, Michelle; Weber, Kimberly P; McLaughlin, T E

2004-01-01

This study compared the copy, cover, and compare method to a picture-word matching method for teaching sight word recognition. Participants were 5 kindergarten students with less than preprimer sight word vocabularies who were enrolled in a public school in the Pacific Northwest. A multielement design was used to evaluate the effects of the two interventions. Outcomes suggested that sight words taught using the copy, cover, and compare method resulted in better maintenance of word recognition when compared to the picture-matching intervention. Benefits to students and the practicality of employing the word-level teaching methods are discussed.

Time-resolved ion energy and charge state distributions in pulsed cathodic arc plasmas of Nb‑Al cathodes in high vacuum

NASA Astrophysics Data System (ADS)

Zöhrer, Siegfried; Anders, André; Franz, Robert

2018-05-01

Cathodic arcs have been utilized in various applications including the deposition of thin films and coatings, ion implantation, and high current switching. Despite substantial progress in recent decades, the physical mechanisms responsible for the observed plasma properties are still a matter of dispute, particularly for multi-element cathodes, which can play an essential role in applications. The analysis of plasma properties is complicated by the generally occurring neutral background of metal atoms, which perturbs initial ion properties. By using a time-resolved method in combination with pulsed arcs and a comprehensive Nb‑Al cathode model system, we investigate the influence of cathode composition on the plasma, while making the influence of neutrals visible for the observed time frame. The results visualize ion detections of 600 μs plasma pulses, extracted 0.27 m from the cathode, resolved in mass-per-charge, energy-per-charge and time. Ion properties are found to be strongly dependent on the cathode material in a way that cannot be deduced by simple linear extrapolation. Subsequently, current hypotheses in cathodic arc physics applying to multi-element cathodes, like the so-called ‘velocity rule’ or the ‘cohesive energy rule’, are tested for early and late stages of the pulse. Apart from their fundamental character, the findings could be useful in optimizing or designing plasma properties for applications, by actively utilizing effects on ion distributions caused by composite cathode materials and charge exchange with neutrals.

Calcium-based multi-element chemistry for grid-scale electrochemical energy storage

NASA Astrophysics Data System (ADS)

Ouchi, Takanari; Kim, Hojong; Spatocco, Brian L.; Sadoway, Donald R.

2016-03-01

Calcium is an attractive material for the negative electrode in a rechargeable battery due to its low electronegativity (high cell voltage), double valence, earth abundance and low cost; however, the use of calcium has historically eluded researchers due to its high melting temperature, high reactivity and unfavorably high solubility in molten salts. Here we demonstrate a long-cycle-life calcium-metal-based rechargeable battery for grid-scale energy storage. By deploying a multi-cation binary electrolyte in concert with an alloyed negative electrode, calcium solubility in the electrolyte is suppressed and operating temperature is reduced. These chemical mitigation strategies also engage another element in energy storage reactions resulting in a multi-element battery. These initial results demonstrate how the synergistic effects of deploying multiple chemical mitigation strategies coupled with the relaxation of the requirement of a single itinerant ion can unlock calcium-based chemistries and produce a battery with enhanced performance.

Calcium-based multi-element chemistry for grid-scale electrochemical energy storage

PubMed Central

Ouchi, Takanari; Kim, Hojong; Spatocco, Brian L.; Sadoway, Donald R.

2016-01-01

Calcium is an attractive material for the negative electrode in a rechargeable battery due to its low electronegativity (high cell voltage), double valence, earth abundance and low cost; however, the use of calcium has historically eluded researchers due to its high melting temperature, high reactivity and unfavorably high solubility in molten salts. Here we demonstrate a long-cycle-life calcium-metal-based rechargeable battery for grid-scale energy storage. By deploying a multi-cation binary electrolyte in concert with an alloyed negative electrode, calcium solubility in the electrolyte is suppressed and operating temperature is reduced. These chemical mitigation strategies also engage another element in energy storage reactions resulting in a multi-element battery. These initial results demonstrate how the synergistic effects of deploying multiple chemical mitigation strategies coupled with the relaxation of the requirement of a single itinerant ion can unlock calcium-based chemistries and produce a battery with enhanced performance. PMID:27001915

Calcium-based multi-element chemistry for grid-scale electrochemical energy storage.

PubMed

Ouchi, Takanari; Kim, Hojong; Spatocco, Brian L; Sadoway, Donald R

2016-03-22

Calcium is an attractive material for the negative electrode in a rechargeable battery due to its low electronegativity (high cell voltage), double valence, earth abundance and low cost; however, the use of calcium has historically eluded researchers due to its high melting temperature, high reactivity and unfavorably high solubility in molten salts. Here we demonstrate a long-cycle-life calcium-metal-based rechargeable battery for grid-scale energy storage. By deploying a multi-cation binary electrolyte in concert with an alloyed negative electrode, calcium solubility in the electrolyte is suppressed and operating temperature is reduced. These chemical mitigation strategies also engage another element in energy storage reactions resulting in a multi-element battery. These initial results demonstrate how the synergistic effects of deploying multiple chemical mitigation strategies coupled with the relaxation of the requirement of a single itinerant ion can unlock calcium-based chemistries and produce a battery with enhanced performance.

Determination of Electron Optical Properties for Aperture Zoom Lenses Using an Artificial Neural Network Method.

PubMed

Isik, Nimet

2016-04-01

Multi-element electrostatic aperture lens systems are widely used to control electron or charged particle beams in many scientific instruments. By means of applied voltages, these lens systems can be operated for different purposes. In this context, numerous methods have been performed to calculate focal properties of these lenses. In this study, an artificial neural network (ANN) classification method is utilized to determine the focused/unfocused charged particle beam in the image point as a function of lens voltages for multi-element electrostatic aperture lenses. A data set for training and testing of ANN is taken from the SIMION 8.1 simulation program, which is a well known and proven accuracy program in charged particle optics. Mean squared error results of this study indicate that the ANN classification method provides notable performance characteristics for electrostatic aperture zoom lenses.

Generic simulation of multi-element ladar scanner kinematics in USU LadarSIM

NASA Astrophysics Data System (ADS)

Omer, David; Call, Benjamin; Pack, Robert; Fullmer, Rees

2006-05-01

This paper presents a generic simulation model for a ladar scanner with up to three scan elements, each having a steering, stabilization and/or pattern-scanning role. Of interest is the development of algorithms that automatically generate commands to the scan elements given beam-steering objectives out of the ladar aperture, and the base motion of the sensor platform. First, a straight-forward single-element body-fixed beam-steering methodology is presented. Then a unique multi-element redirective and reflective space-fixed beam-steering methodology is explained. It is shown that standard direction cosine matrix decomposition methods fail when using two orthogonal, space-fixed rotations, thus demanding the development of a new algorithm for beam steering. Finally, a related steering control methodology is presented that uses two separate optical elements mathematically combined to determine the necessary scan element commands. Limits, restrictions, and results on this methodology are presented.

On the possibility of using multi-element phased arrays for shock-wave action on deep brain structures

NASA Astrophysics Data System (ADS)

Rosnitskiy, P. B.; Gavrilov, L. R.; Yuldashev, P. V.; Sapozhnikov, O. A.; Khokhlova, V. A.

2017-09-01

A noninvasive ultrasound surgery method that relies on using multi-element focused phased arrays is being successfully used to destroy tumors and perform neurosurgical operations in deep structures of the human brain. However, several drawbacks that limit the possibilities of the existing systems in their clinical use have been revealed: a large size of the hemispherical array, impossibility of its mechanical movement relative to the patient's head, limited volume of dynamic focusing around the center of curvature of the array, and side effect of overheating skull. Here we evaluate the possibility of using arrays of smaller size and aperture angles to achieve shock-wave formation at the focus for thermal and mechanical ablation (histotripsy) of brain tissue taking into account current intensity limitations at the array elements. The proposed approach has potential advantages to mitigate the existing limitations and expand the possibilities of transcranial ultrasound surgery.

Gaseous film cooling investigation in a multi-element splash platelet injector

NASA Astrophysics Data System (ADS)

Yin, Liang; Liu, Weiqiang

2018-03-01

Film cooling is an effective technique that protects chamber walls in rocket combustion against chemical attacks and heat fluxes. This study discusses cooling effect in a multi-element GO2/CH4 splash platelet injector. Influence parameters, such as slot height, slot number, percentage of coolant, and injection position on cooling effect, were investigated. GCH4 with 298.15 K was applied as film coolant. In the first step, slot heights of 0.2 and 0.4 mm were compared by applying a constant film mass flow rate. Temperature, CH4 mole fraction distribution, and flow field structure were obtained. The effects of slot number, percentage of coolant, and injection position on wall temperature distribution were then determined. Finally, the reasons for the low cooling efficiency were analyzed. Improvement in the method is proposed to achieve improved cooling effect for splash platelet injectors.

Multi-Element Airfoil System

NASA Technical Reports Server (NTRS)

Turner, Travis L. (Inventor); Khorrami, Mehdi R. (Inventor); Lockard, David P. (Inventor); McKenney, Martin J. (Inventor); Atherley, Raymond D. (Inventor); Kidd, Reggie T. (Inventor)

2014-01-01

A multi-element airfoil system includes an airfoil element having a leading edge region and a skin element coupled to the airfoil element. A slat deployment system is coupled to the slat and the skin element, and is capable of deploying and retracting the slat and the skin element. The skin element substantially fills the lateral gap formed between the slat and the airfoil element when the slat is deployed. The system further includes an uncoupling device and a sensor to remove the skin element from the gap based on a critical angle-of-attack of the airfoil element. The system can alternatively comprise a trailing edge flap, where a skin element substantially fills the lateral gap between the flap and the trailing edge region of the airfoil element. In each case, the skin element fills a gap between the airfoil element and the deployed flap or slat to reduce airframe noise.

Viscous/potential flow about multi-element two-dimensional and infinite-span swept wings: Theory and experiment

NASA Technical Reports Server (NTRS)

Olson, L. E.; Dvorak, F. A.

1975-01-01

The viscous subsonic flow past two-dimensional and infinite-span swept multi-component airfoils is studied theoretically and experimentally. The computerized analysis is based on iteratively coupled boundary layer and potential flow analysis. The method, which is restricted to flows with only slight separation, gives surface pressure distribution, chordwise and spanwise boundary layer characteristics, lift, drag, and pitching moment for airfoil configurations with up to four elements. Merging confluent boundary layers are treated. Theoretical predictions are compared with an exact theoretical potential flow solution and with experimental measures made in the Ames 40- by 80-Foot Wind Tunnel for both two-dimensional and infinite-span swept wing configurations. Section lift characteristics are accurately predicted for zero and moderate sweep angles where flow separation effects are negligible.

Application of epithermal neutron activation in multielement analysis of silicate rocks employing both coaxial Ge(Li) and low energy photon detector systems

USGS Publications Warehouse

Baedecker, P.A.; Rowe, J.J.; Steinnes, E.

1977-01-01

The instrumental activation analysis of silicate rocks using epithermal neutrons has been studied using both high resolution coaxial Ge(Li) detectors and low energy photon detectors, and applied to the determination of 23 elements in eight new U.S.G.S. standard rocks. The analytical use X-ray peaks associated with electron capture or internal conversion processes has been evaluated. Of 28 elements which can be considered to be determinable by instrumental means, the epithermal activation approach is capable of giving improved sensitivity and precision in 16 cases, over the normal INAA procedure. In eleven cases the use of the low energy photon detector is thought to show advantages over convertional coaxial Ge(Li) spectroscopy. ?? 1977 Akade??miai Kiado??.

Development of a compact underwater laser-induced breakdown spectroscopy (LIBS) system and preliminary results in sea trials.

PubMed

Guo, Jinjia; Lu, Yuan; Cheng, Kai; Song, Jiaojian; Ye, Wangquan; Li, Nan; Zheng, Ronger

2017-10-10

The exploitation and research of deep-sea hydrothermal vent has been an issue of great interest in ocean research in recent years. Laser-induced breakdown spectroscopy (LIBS) has great potential for ocean application due to the capabilities of stand-off, multiphase, and multielement analysis. In this work, a newly developed compact 4000 m rated LIBS system (LIBSea) is introduced with preliminary results of sea trials. The underwater system consists of an Nd:YAG single-pulsed laser operating at 1064 nm, an optical fiber spectrometer, an optics module, and an electronic controller module. The whole system is housed in an L800  mm×ϕ258  mm pressure housing with an optical window on the end cap. It was deployed on the remote operated vehicle Faxian on the research vessel Kexue, and in June 2015 was successfully applied for hydrothermal field measurements at the Manus area. The obtained results are shown that the LIBS system is capable of detecting elements Li, Na, K, Ca, and Mg in the hydrothermal area. Profiles of LIBS signals of elements K and Ca have also been obtained during the sea trial. The results show that the K emission line is gradually broadened with depth from sea surface to sea floor (1800 m or so); the K intensity shows a hump shape with maximum value at about 1050 m. The Ca emission line is rapidly broadened below 400 m and slowly narrowed to the sea floor; the Ca intensity shows no obvious change below 400 m and increases continuously to sea floor. A very interesting finding is that the small fluctuations of intensity profile curve of Ca show a degree of correlation with seawater temperature change. The sea trial results prove the performance of LIBSea. After further optimization, it is hoped to apply the LIBS system to the in situ mineral deposits and hydrothermal vent fluid detection in deep sea.

Use of polarized radiation for increasing the sensitivity of multielement x-ray fluorescence analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ter-Saakov, A.A.; Glebov, M.V.

1985-10-01

An experimental x-ray fluorescence analysis facility has been developed using polarized radiation. A modernized small-sized REIS-I emitter is used as the x-ray genertor. Its characteristics are: a straight-through drift tube with a copper, molybdenum, or silver anode; and a controlled working voltage from 0 to 45 kV. The thickness of the inlet beryllium window is 100 um. Experiments were carried out on the facility on the optimization of fluorescence excitation conditions of biological samples. The investigations conducted of the dosimetric and spectral characteristics of the BS-1, BS-3, and BKh-7 x-ray tubes with copper, silver, and molybdenum anodes have shown thatmore » for the analysis in samples of biogenic elements, it is most efficient to use the BKh-7 and BS-1 tubes with a copper anode.« less

Nuclear analytical techniques in medicine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cesareo, R.

1988-01-01

This book acquaints one with the fundamental principles and the instrumentation relevant to analytical technique based on atomic and nuclear physics, as well as present and future biomedical applications. Besides providing a theoretical description of the physical phenomena, a large part of the book is devoted to applications in the medical and biological field, particularly in hematology, forensic medicine and environmental science. This volume reviews methods such as the possibility of carrying out rapid multi-element analysis of trace elements on biomedical samples, in vitro and in vivo, by XRF-analysis; the ability of the PIXE-microprobe to analyze in detail and tomore » map trace elements in fragments of biomedical samples or inside the cells; the potentiality of in vivo nuclear activation analysis for diagnostic purposes. Finally, techniques are described such as radiation scattering (elastic and inelastic scattering) and attenuation measurements which will undoubtedly see great development in the immediate future.« less

Multi-element fingerprinting as a tool in origin authentication of four east China marine species.

PubMed

Guo, Lipan; Gong, Like; Yu, Yanlei; Zhang, Hong

2013-12-01

The contents of 25 elements in 4 types of commercial marine species from the East China Sea were determined by inductively coupled plasma mass spectrometry and atomic absorption spectrometry. The elemental composition was used to differentiate marine species according to geographical origin by multivariate statistical analysis. The results showed that principal component analysis could distinguish samples from different areas and reveal the elements which played the most important role in origin diversity. The established models by partial least squares discriminant analysis (PLS-DA) and by probabilistic neural network (PNN) can both precisely predict the origin of the marine species. Further study indicated that PLS-DA and PNN were efficacious in regional discrimination. The models from these 2 statistical methods, with an accuracy of 97.92% and 100%, respectively, could both distinguish samples from different areas without the need for species differentiation. © 2013 Institute of Food Technologists®

Development of nine-channel 10-micrometer (Hg, Cd)Te pushbroom IR/CCD system

NASA Technical Reports Server (NTRS)

White, W. J.; Wasa, S.

1977-01-01

The engineering development of the 9-channel detector array is documented. The development of the array demonstrates the feasibility of a self scanned multi-element infrared detector focal plane. Procedures for operating the array are outlined.

A comparative study of neutron activation analysis and proton-induced X-ray emission analysis for the determination of heavy metals in estuarine sediments

NASA Astrophysics Data System (ADS)

Randle, K.; Al-Jundi, J.; Mamas, C. J. V.; Sokhi, R. S.; Earwaker, L. G.

1993-06-01

Our work on heavy metals in the estuarine environment has involved the use of two multielement techniques: neutron activation analysis (NAA) and proton-induced X-ray emission (PIXE) analysis. As PIXE is essentially a surface analytical technique problems may arise due to sample inhomogeneity and surface roughness. In order to assess the contribution of these effects we have compared the results from PIXE analysis with those from a technique which analyzes a larger bulk sample rather than just the surface. An obvious method was NAA. A series of sediment samples containing particles of variable diameter were compared. Pellets containing a few mg of sediment were prepared from each sample and analyzed by the PIXE technique using both an absolute and a comparitive method. For INAA the rest of the sample was then irradiated with thermal neutrons and element concentrations determined from analyses of the subsequent gamma-ray spectrum. Results from the two methods are discussed.

Practical and quality-control aspects of multi-element analysis with quadrupole ICP-MS with special attention to urine and whole blood.

PubMed

De Boer, Jan L M; Ritsema, Rob; Piso, Sjoerd; Van Staden, Hans; Van Den Beld, Wilbert

2004-07-01

Two screening methods were developed for rapid analysis of a great number of urine and blood samples within the framework of an exposure check of the population after a firework explosion. A total of 56 elements was measured including major elements. Sample preparation consisted of simple dilution. Extensive quality controls were applied including element addition and the use of certified reference materials. Relevant results at levels similar to those found in the literature were obtained for Co, Ni, Cu, Zn, Sr, Cd, Sn, Sb, Ba, Tl, and Pb in urine and for the same elements except Ni, Sn, Sb, and Ba in blood. However, quadrupole ICP-MS has limitations, mainly related to spectral interferences, for the analysis of urine and blood, and these cause higher detection limits. The general aspects discussed in the paper give it wider applicability than just for analysis of blood and urine-it can for example be used in environmental analysis.

Using of Synchrotron radiation for study of multielement composition of the small mammals diet and tissues

NASA Astrophysics Data System (ADS)

Bezel, V. S.; Koutzenogii, K. P.; Mukhacheva, S. V.; Chankina, O. V.; Savchenko, T. I.

2007-05-01

The Synchrotron radiation X-ray Fluorescence analysis (SRXRF) was used for estimation of "geochemical selection" of elements by small mammals, which belong to different trophic groups and inhabit polluted and background areas (the Middle Ural). The concentrations of K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Br, Rb, Sr, Y, Cd, Pb in the diet and into hepar of a herbivorous ( bank vole) and carnivorous ( Laxmann's shrew) small mammals were compared. Herbivores play a particular role in chemical elements translocation between trophic levels, limiting element transition to consumers of the consequent levels. Whereas, insectivores concentrate most elements in their tissues under the same conditions.

Multi-elemental analysis of aqueous geological samples by inductively coupled plasma-optical emission spectrometry

USGS Publications Warehouse

Todorov, Todor I.; Wolf, Ruth E.; Adams, Monique

2014-01-01

Typically, 27 major, minor, and trace elements are determined in natural waters, acid mine drainage, extraction fluids, and leachates of geological and environmental samples by inductively coupled plasma-optical emission spectrometry (ICP-OES). At the discretion of the analyst, additional elements may be determined after suitable method modifications and performance data are established. Samples are preserved in 1–2 percent nitric acid (HNO3) at sample collection or as soon as possible after collection. The aqueous samples are aspirated into the ICP-OES discharge, where the elemental emission signals are measured simultaneously for 27 elements. Calibration is performed with a series of matrix-matched, multi-element solution standards.

Performance characteristics of LOX-H2, tangential-entry, swirl-coaxial, rocket injectors

NASA Technical Reports Server (NTRS)

Howell, Doug; Petersen, Eric; Clark, Jim

1993-01-01

Development of a high performing swirl-coaxial injector requires an understanding of fundamental performance characteristics. This paper addresses the findings of studies on cold flow atomic characterizations which provided information on the influence of fluid properties and element operating conditions on the produced droplet sprays. These findings are applied to actual rocket conditions. The performance characteristics of swirl-coaxial injection elements under multi-element hot-fire conditions were obtained by analysis of combustion performance data from three separate test series. The injection elements are described and test results are analyzed using multi-variable linear regression. A direct comparison of test results indicated that reduced fuel injection velocity improved injection element performance through improved propellant mixing.

Recent modifications and calibration of the Langley low-turbulence pressure tunnel

NASA Technical Reports Server (NTRS)

Mcghee, R. J.; Beasley, W. D.; Foster, J. M.

1984-01-01

Modifications to the Langley Low-Turbulence Pressure Tunnel are presented and a calibration of the mean flow parameters in the test section is provided. Also included are the operational capability of the tunnel and typical test results for both single-element and multi-element airfoils. Modifications to the facility consisted of the following: replacement of the original cooling coils and antiturbulence screens and addition of a tunnel-shell heating system, a two dimensional model-support and force-balance system, a sidewall boundary layer control system, a remote-controlled survey apparatus, and a new data acquisition system. A calibration of the mean flow parameters in the test section was conducted over the complete operational range of the tunnel. The calibration included dynamic-pressure measurements, Mach number distributions, flow-angularity measurements, boundary-layer characteristics, and total-pressure profiles. In addition, test-section turbulence measurements made after the tunnel modifications have been included with these calibration data to show a comparison of existing turbulence levels with data obtained for the facility in 1941 with the original screen installation.

X-ray Fluorescence Tomography of Aged Fluid-Catalytic-Cracking Catalyst Particles Reveals Insight into Metal Deposition Processes.

PubMed

Kalirai, Sam; Boesenberg, Ulrike; Falkenberg, Gerald; Meirer, Florian; Weckhuysen, Bert M

2015-11-01

Microprobe X-ray fluorescence tomography was used to investigate metal poison deposition in individual, intact and industrially deactivated fluid catalytic cracking (FCC) particles at two differing catalytic life-stages. 3 D multi-element imaging, at submicron resolution was achieved by using a large-array Maia fluorescence detector. Our results show that Fe, Ni and Ca have significant concentration at the exterior of the FCC catalyst particle and are highly co-localized. As concentrations increase as a function of catalytic life-stage, the deposition profiles of Fe, Ni, and Ca do not change significantly. V has been shown to penetrate deeper into the particle with increasing catalytic age. Although it has been previously suggested that V is responsible for damaging the zeolite components of FCC particles, no spatial correlation was found for V and La, which was used as a marker for the embedded zeolite domains. This suggests that although V is known to be detrimental to zeolites in FCC particles, a preferential interaction does not exist between the two.

Effects of bamboo biochar on soybean root nodulation in multi-elements contaminated soils.

PubMed

Wang, Chunyan; Alidoust, Darioush; Yang, Xueling; Isoda, Akihiro

2018-04-15

Improvements in plant physiological performance by means of biochar application in soils contaminated by multi-elements are determinants of agroecosystem functioning. This study analyzed the effects of bamboo-derived biochar on root nodulation and plant growth in a moderately acidic Andosol (pH = 5.56) contaminated with multi-elements during a 70-day investigation of soybean growth. Bamboo biochar that had been pyrolyzed at a temperature below 500°C was applied to soils at three different and moderately high rates (5%, 10%, and 15%, w/w). Biochar amendment beyond 5% stimulated root nodulation as well as soybean growth. The nodule weight per root system was significantly enhanced by 186% and 243% over the control at the 10% and 15% addition rates, respectively. The primary explanation for these stimulatory effects was attributed to an increase in the K and Mo supplies for plant uptake that was induced by the biochar application, whereas the increased availability of P contributed to a lesser extent. Leaf CO 2 assimilation rate was slightly enhanced at the highest application rate, but this enhancement was not associated with an increase in biomass. The incorporation of biochar into the soil reduced extractable-NH 4 NO 3 Cd, Cu, Mn, Ni, and Zn, but not Pb, regardless of the application dose. This change was accompanied by a significant (P < 0.05) suppression of the uptake od trace elements in soybean shoots at the optimum application rate (10%); the degree of reduction followed this order: Pb>Mn>Cd>Zn>Cu>Ni. The increase in soil pH and the diffusion/adsorption of trace elements onto the biochar may have contributed to the lowering of the concentration of trace elements in the soil as well as in soybean shoots. Copyright © 2017 Elsevier Inc. All rights reserved.

Aeroacoustic Characteristics of a Rectangular Multi-Element Supersonic Jet Mixer-Ejector Nozzle

NASA Technical Reports Server (NTRS)

Raman, Ganesh; Taghavi, Ray

1996-01-01

This paper provides a unique, detailed evaluation of the acoustics and aerodynamics of a rectangular multi-element supersonic jet mixer-ejector noise suppressor. The performance of such mixer-ejectors is important in aircraft engine application for noise suppression and thrust augmentation. In contrast to most prior experimental studies on ejectors that reported either aerodynamic or acoustic data, our work documents both types of data. We present information on the mixing, pumping, ejector wall pressure distribution, thrust augmentation and noise suppression characteristics of four simple, multi-element, jet mixer-ejector configurations. The four configurations included the effect of ejector area ratio (AR = ejector area/primary jet area) and the effect of non-parallel ejector walls. We also studied in detail the configuration that produced the best noise suppression characteristics. Our results show that ejector configurations that produced the maximum maximum pumping (entrained flow per secondary inlet area) also exhibited the lowest wall pressures in the inlet region, and the maximum thrust augmentation. When cases having the same total mass flow were compared, we found that noise suppression trends corresponded with those for pumping. Surprisingly, the mixing (quantified by the peak Mach number, and flow uniformity) at the ejector exit exhibited no relationship to the noise suppression at moderate primary jet fully expanded Mach numbers (Mj is less than 1.4). However, the noise suppression dependence on the mixing was apparent at higher Mj. The above observations are justified by noting that the mixing at the ejector exit is ot a strong factor in determining the radiated noise when noise produced internal to the ejector dominates the noise field outside the ejector.

Deformation behaviour of a new magnesium ternary alloy

NASA Astrophysics Data System (ADS)

Guglielmi, P.; Kaya, A. Arslan; Sorgente, D.; Palumbo, G.

2018-05-01

Magnesium based alloys are yet to fill a greater niche especially in the automotive and aeronautical industry. In fact, such alloys have a big weight saving potential, together with good damping characteristics. However, nowadays about 90% of Magnesium products are produced by casting, mainly using two alloy systems, namely Mg-Al-Zn (AZ91D) and Mg-Al (AM50, AM60). Now the emphasis, especially after having achieved considerable success in creep resistance and understanding of the deformation behaviour of Magnesium, has been shifted towards wrought alloys; AZ31, in this case, is the most popular. In this work a multi-element Magnesium alloy, developed to improve the deformation capacity of such a lightweight material, has been investigated and compared to a commercial AZ31B. The possibility of adopting such a multi-element Magnesium alloy for manufacturing components via unconventional sheet forming (such as superplastic forming, warm hydroforming, incremental forming) has been proved in the present work focusing the attention on the superplastic field. Free inflation tests were thus conducted at 450°C setting constant pressure to investigate the superplastic behaviour (in terms of dome height and strain rate sensitivity index) of both the multi-element Magnesium alloy (Mg-2Zn-Ce) and the commercial one (AZ31B). To enhance information on the thickness distribution and investigate the microstructure evolution, metallographic analyses on the samples used to carry out free inflation tests were also performed. The developed ternary alloy manifested quite a good deformation behaviour (high strain rate sensitivity index), even being tested in the as cast condition; in addition a limited grain coarsening was observed in the specimens after deformation.

Experimental and Computational Investigation of Lift-Enhancing Tabs on a Multi-Element Airfoil

NASA Technical Reports Server (NTRS)

Ashby, Dale L.

1996-01-01

An experimental and computational investigation of the effect of lift-enhancing tabs on a two-element airfoil has been conducted. The objective of the study was to develop an understanding of the flow physics associated with lift-enhancing tabs on a multi-element airfoil. An NACA 63(2)-215 ModB airfoil with a 30% chord fowler flap was tested in the NASA Ames 7- by 10-Foot Wind Tunnel. Lift-enhancing tabs of various heights were tested on both the main element and the flap for a variety of flap riggings. A combination of tabs located at the main element and flap trailing edges increased the airfoil lift coefficient by 11% relative to the highest lift coefficient achieved by any baseline configuration at an angle of attack of 0 deg, and C(sub 1max) was increased by 3%. Computations of the flow over the two-element airfoil were performed using the two-dimensional incompressible Navier-Stokes code INS2D-UP. The computed results predicted all of the trends observed in the experimental data quite well. In addition, a simple analytic model based on potential flow was developed to provide a more detailed understanding of how lift-enhancing tabs work. The tabs were modeled by a point vortex at the air-foil or flap trailing edge. Sensitivity relationships were derived which provide a mathematical basis for explaining the effects of lift-enhancing tabs on a multi-element airfoil. Results of the modeling effort indicate that the dominant effects of the tabs on the pressure distribution of each element of the airfoil can be captured with a potential flow model for cases with no flow separation.

Scaling study of the combustion performance of gas—gas rocket injectors

NASA Astrophysics Data System (ADS)

Wang, Xiao-Wei; Cai, Guo-Biao; Jin, Ping

2011-10-01

To obtain the key subelements that may influence the scaling of gas—gas injector combustor performance, the combustion performance subelements in a liquid propellant rocket engine combustor are initially analysed based on the results of a previous study on the scaling of a gas—gas combustion flowfield. Analysis indicates that inner wall friction loss and heat-flux loss are two key issues in gaining the scaling criterion of the combustion performance. The similarity conditions of the inner wall friction loss and heat-flux loss in a gas—gas combustion chamber are obtained by theoretical analyses. Then the theoretical scaling criterion was obtained for the combustion performance, but it proved to be impractical. The criterion conditions, the wall friction and the heat flux are further analysed in detail to obtain the specific engineering scaling criterion of the combustion performance. The results indicate that when the inner flowfields in the combustors are similar, the combustor wall shear stress will have similar distributions qualitatively and will be directly proportional to pc0.8dt-0.2 quantitatively. In addition, the combustion peformance will remain unchanged. Furthermore, multi-element injector chambers with different geometric sizes and at different pressures are numerically simulated and the wall shear stress and combustion efficiencies are solved and compared with each other. A multielement injector chamber is designed and hot-fire tested at several chamber pressures and the combustion performances are measured in a total of nine hot-fire tests. The numerical and experimental results verified the similarities among combustor wall shear stress and combustion performances at different chamber pressures and geometries, with the criterion applied.

Intra-regional classification of grape seeds produced in Mendoza province (Argentina) by multi-elemental analysis and chemometrics tools.

PubMed

Canizo, Brenda V; Escudero, Leticia B; Pérez, María B; Pellerano, Roberto G; Wuilloud, Rodolfo G

2018-03-01

The feasibility of the application of chemometric techniques associated with multi-element analysis for the classification of grape seeds according to their provenance vineyard soil was investigated. Grape seed samples from different localities of Mendoza province (Argentina) were evaluated. Inductively coupled plasma mass spectrometry (ICP-MS) was used for the determination of twenty-nine elements (Ag, As, Ce, Co, Cs, Cu, Eu, Fe, Ga, Gd, La, Lu, Mn, Mo, Nb, Nd, Ni, Pr, Rb, Sm, Te, Ti, Tl, Tm, U, V, Y, Zn and Zr). Once the analytical data were collected, supervised pattern recognition techniques such as linear discriminant analysis (LDA), partial least square discriminant analysis (PLS-DA), k-nearest neighbors (k-NN), support vector machine (SVM) and Random Forest (RF) were applied to construct classification/discrimination rules. The results indicated that nonlinear methods, RF and SVM, perform best with up to 98% and 93% accuracy rate, respectively, and therefore are excellent tools for classification of grapes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Characterization of Hatay honeys according to their multi-element analysis using ICP-OES combined with chemometrics.

PubMed

Yücel, Yasin; Sultanoğlu, Pınar

2013-09-01

Chemical characterisation has been carried out on 45 honey samples collected from Hatay region of Turkey. The concentrations of 17 elements were determined by inductively coupled plasma optical emission spectrometry (ICP-OES). Ca, K, Mg and Na were the most abundant elements, with mean contents of 219.38, 446.93, 49.06 and 95.91 mg kg(-1) respectively. The trace element mean contents ranged between 0.03 and 15.07 mg kg(-1). Chemometric methods such as principal component analysis (PCA) and cluster analysis (CA) techniques were applied to classify honey according to mineral content. The first most important principal component (PC) was strongly associated with the value of Al, B, Cd and Co. CA showed eight clusters corresponding to the eight botanical origins of honey. PCA explained 75.69% of the variance with the first six PC variables. Chemometric analysis of the analytical data allowed the accurate classification of the honey samples according to origin. Copyright © 2013 Elsevier Ltd. All rights reserved.

Increasing Social Engagement in an Inclusive Environment

ERIC Educational Resources Information Center

Hartzell, Rebecca; Liaupsin, Carl; Gann, Candace; Clem, Sarah

2015-01-01

This study examined the effectiveness, generalization, and maintenance of a multi-element intervention consisting of brief direct instruction social skill lessons, a prompting procedure, and a fading procedure to promote social engagement in an integrated lunchroom and playground setting for three elementary age students with developmental…

Experimental Investigation of Shock-Cell Noise Reduction for Single Stream Nozzles in Simulated Flight

NASA Technical Reports Server (NTRS)

Yamamoto, K.; Brausch, J. F.; Balsa, T. F.; Janardan, B. A.; Knott, P. R.

1984-01-01

Seven single stream model nozzles were tested in the Anechoic Free-Jet Acoustic Test Facility to evaluate the effectiveness of convergent divergent (C-D) flowpaths in the reduction of shock-cell noise under both static and mulated flight conditions. The test nozzles included a baseline convergent circular nozzle, a C-D circular nozzle, a convergent annular plug nozzle, a C-D annular plug nozzle, a convergent multi-element suppressor plug nozzle, and a C-D multi-element suppressor plug nozzle. Diagnostic flow visualization with a shadowgraph and aerodynamic plume measurements with a laser velocimeter were performed with the test nozzles. A theory of shock-cell noise for annular plug nozzles with shock-cells in the vicinity of the plug was developed. The benefit of these C-D nozzles was observed over a broad range of pressure ratiosin the vicinity of their design conditions. At the C-D design condition, the C-D annual nozzle was found to be free of shock-cells on the plug.

KENNEDY SPACE CENTER, FLA. - The U.S. Node 2 is undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS.

NASA Image and Video Library

2003-08-27

KENNEDY SPACE CENTER, FLA. - The U.S. Node 2 is undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS.

Measurement Of Crossflow Vortex Structure

NASA Technical Reports Server (NTRS)

Maddalon, Dal V.; Agarwal, Navel K.

1994-01-01

Method developed for measuring wavelengths of crossflow vortices by using surface-mounted, microthin, multielement hot-film sensors. Provides direct and true value of wavelength of crossflow vortices at various spanwise locations without localized flow disturbances. Attainment of laminar airflow on aircraft wings has significant potential for reducing drag and increasing fuel efficiency.

Word Reading Fluency as a Serial Naming Task

ERIC Educational Resources Information Center

Protopapas, Athanassios; Katopodi, Katerina; Altani, Angeliki; Georgiou, George K.

2018-01-01

Word list reading fluency is theoretically expected to depend on single word reading speed. Yet the correlation between the two diminishes with increasing fluency, while fluency remains strongly correlated to serial digit naming. We hypothesized that multi-element sequence processing is an important component of fluency. We used confirmatory…

Local Structure and Short-Range Order in a NiCoCr Solid Solution Alloy

DOE PAGES

Zhang, F. X.; Zhao, Shijun; Jin, Ke; ...

2017-05-19

Multi-element solid solution alloys are intrinsically disordered on the atomic scale, and many of their advanced properties originate from the unique local structural characteristics. We measured the local structure of a NiCoCr solid solution alloy with X-ray/neutron total scattering and extended X-ray absorption fine structure (EXAFS) techniques. The atomic pair distribution function analysis (PDF) did not exhibit distinct structural distortion. But, EXAFS analysis suggested that the Cr atoms are favorably bonded with Ni and Co in the solid solution alloys. This short-range order (SRO) plays a role in the distinct low values of electrical and thermal conductivities in Ni-based solidmore » solution alloys when Cr is incorporated. Both the long-range and local structures of the NiCoCr alloy upon Ni ion irradiation were studied and an irradiation-induced enhancement of SRO was found.« less

The Open Cluster Chemical Abundances and Mapping (OCCAM) Survey: Current Status

NASA Astrophysics Data System (ADS)

Frinchaboy, Peter; O'Connell, Julia; Donor, John; Cunha, Katia; Thompson, Benjamin; Melendez, Matthew; Shetrone, Matthew; Zasowski, Gail; Majewski, Steven R.; APOGEE TEAM

2018-01-01

The Open Cluster Chemical Analysis and Mapping (OCCAM) survey aims to produce a comprehensive, uniform, infrared-based data set forhundreds of open clusters, and constrain key Galactic dynamical and chemical parameters using the SDSS/APOGEE survey and follow-up from the McDonald Observatory Otto Struve 2.1-m telescope and Sandiford Cass Echelle Spectrograph (R ~ 60,000). We report on multi-element radial abundance gradients obtained from a sample of over 30 disk open clusters. The APOGEE chemical abundances were derived automatically by the ASPCAP pipeline and these are part of the SDSS IV Data Release 14, optical follow-up were analyzed using equivalent width analysis and spectral synthesis. We present the current open cluster sample that spans a significant range in age allowing exploration of the evolution of the Galactic abundance gradients. This work is supported by an NSF AAG grants AST-1311835 & AST-1715662.

Determination of rare earth elements in geological materials by inductively coupled argon plasma/atomic emission spectrometry

USGS Publications Warehouse

Crock, J.G.; Lichte, F.E.

1982-01-01

Inductively coupled argon plasma/optical emission spectrometery (ICAP/OES) is useful as a simultaneous, multielement analytical technique for the determination of trace elements in geological materials. A method for the determination of trace-level rare earth elements (REE) in geological materials using an ICAP 63-channel emission spectrometer is described. Separation and preconcentration of the REE and yttrium from a sample digest are achieved by a nitric acid gradient cation exchange and hydrochloric acid anion exchange. Precision of 1-4% relative standard deviation and comparable accuracy are demonstrated by the triplicate analysis of three splits of BCR-1 and BHVO-1. Analyses of other geological materials including coals, soils, and rocks show comparable precision and accuracy.

Simplified multi-element analysis of ground and instant coffees by ICP-OES and FAAS.

PubMed

Szymczycha-Madeja, Anna; Welna, Maja; Pohl, Pawel

2015-01-01

A simplified alternative to the wet digestion sample preparation procedure for roasted ground and instant coffees has been developed and validated for the determination of different elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (Al, Ba, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sr, Zn) and flame atomic absorption spectrometry (FAAS) (Ca, Fe, K, Mg, Na). The proposed procedure, i.e. the ultrasound-assisted solubilisation in aqua regia, is quite fast and simple, requires minimal use of reagents, and demonstrated good analytical performance, i.e. accuracy from -4.7% to 1.9%, precision within 0.5-8.6% and recovery in the range 93.5-103%. Detection limits of elements were from 0.086 ng ml(-1) (Sr) to 40 ng ml(-1) (Fe). A preliminary classification of 18 samples of ground and instant coffees was successfully made based on concentrations of selected elements and using principal component analysis and hierarchic cluster analysis.

Multielement analysis of Canadian wines by inductively coupled plasma mass spectrometry (ICP-MS) and multivariate statistics.

PubMed

Taylor, Vivien F; Longerich, Henry P; Greenough, John D

2003-02-12

Trace element fingerprints were deciphered for wines from Canada's two major wine-producing regions, the Okanagan Valley and the Niagara Peninsula, for the purpose of examining differences in wine element composition with region of origin and identifying elements important to determining provenance. Analysis by ICP-MS allowed simultaneous determination of 34 trace elements in wine (Li, Be, Mg, Al, P, Cl, Ca, Ti, V, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Mo, Ag, Cd, Sb, I, Cs, Ba, La, Ce, Tl, Pb, Bi, Th, and U) at low levels of detection, and patterns in trace element concentrations were deciphered by multivariate statistical analysis. The two regions were discriminated with 100% accuracy using 10 of these elements. Differences in soil chemistry between the Niagara and Okanagan vineyards were evident, without a good correlation between soil and wine composition. The element Sr was found to be a good indicator of provenance and has been reported in fingerprinting studies of other regions.

Multielement extraction system for determining 19 trace elements in gold exploration samples

USGS Publications Warehouse

Clark, J. Robert; Viets, John G.; ,

1990-01-01

A multielement extraction system is being used successfully to provide essentially interference-free geochemical analyses to aid in gold exploration. The Methyl isobutyl ketone-Amine synerGistic Iodide Complex (MAGIC) extraction system separates Ag, As, Au, Bi, Cd, Cu, Ga, Hg, In, Mo, Pb, Pd, Pt, Sb, Se, Sn, Te, Tl, and Zn from interfering geological matrices. Quantitative extraction of these elements is accomplished over a broad range of acid normality making it possible to economically determine all 19 elements from a single digestion or leach solution. The resulting organic extracts are amenable to analysis by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and flame atomic absorption spectroscopy (FAAS). For many years the principal shortcoming of ICP-AES was the complex spectral and stray-light interferences that were caused by the extreme variability of components such as Fe, Na, and Ca in common geological matrices. The MAGIC extraction allows determination of the extracted elements with enhanced sensitivity, from a virtually uniform matrix, by ICP-AES and FAAS. Because of its simultaneous multichannel capabilities, ICP-AES is the ideal instrumental technique for determining these 19 extracted elements. Ultratrace (sub-part-per-billion) determinations of Au and many of the other extracted elements can be made by graphite furnace atomic absorption spectroscopy (GFAAS), following back stripping of the extracts. The combination of the extraction followed by stripping of the organic phase eliminates 99.999% of potential interferences for Au. Gold determination by GFAAS from these extracts under the specified conditions yields a fourfold improvement in sensitivity over conventional GFAAS methods. This sensitivity enhancement and the interference-free matrix allow highly reliable determinations well into the parts-per-trillion range.

Solid Phase Extraction of Trace Elements in Waterand Tissue Samples on a Mini Column with Diphenylcarbazone Impregnated Nano-TiO2 and Their Determination by Inductively Coupled Plasma Optical Emission Spectrometry

PubMed Central

Baytak, Sıtkı; Arslan, Zikri

2015-01-01

This study presents a simple, robust and environmentally friendly solid phase preconcentration procedure for multielement determination by inductively coupled plasma optical emission spectrometry (ICP-OES) using diphenylcarbazone (DPC) impregnated TiO2 nanopowder (n-TiO2). DPC was successfully impregnated onto n-TiO2 in colloidal solution. A number of elements, including Co(II), Cr(III), Cu(II), Fe(III), Mn(II) and Zn(II) were quantitatively preconcentrated from aqueous solutions between pH 8 and 8.5 at a flow rate of 2 mL min−1, and then eluted with 2 mL of 5% (v/v) HNO3. A mini-column packed with 0.12 g DPC impregnated n-TiO2 retained all elements quantitatively from up to 250 mL multielement solution (2.5 μg per analyte) affording an enrichment factor of 125. The limits of detection (LOD) for preconcentration of 50 mL blank solutions (n = 12) were 0.28, 0.15, 0.25, 0.22, 0.12, and 0.10 μg L−1 for Co, Cr, Cu, Fe, Mn, and Zn, respectively. The relative standard deviation (RSD) for five replicate determinations was 0.8, 3.4, 2.6, 2.2, 1.2 and 3.3% for Co, Cr, Cu, Fe, Mn and Zn, respectively, at 5 μg L−1 level. The method was validated with analysis of Freshwater (SRM 1643e) and Lobster hepatopancreas (TORT-2) certified reference materials, and then applied to the determination of the elements from tap water and lake water samples by ICP-OES. PMID:26236403

Developmental Dyslexia: The Visual Attention Span Deficit Hypothesis

ERIC Educational Resources Information Center

Bosse, Marie-Line; Tainturier, Marie Josephe; Valdois, Sylviane

2007-01-01

The visual attention (VA) span is defined as the amount of distinct visual elements which can be processed in parallel in a multi-element array. Both recent empirical data and theoretical accounts suggest that a VA span deficit might contribute to developmental dyslexia, independently of a phonological disorder. In this study, this hypothesis was…

Future Directions for Space Transportation and Propulsion at NASA

NASA Technical Reports Server (NTRS)

Sackheim, Robert L.

2005-01-01

Contents include the following: Oxygen Compatible Materials. Manufacturing Technology Demonstrations. Turbopump Inducer Waterflow Test. Turbine Damping "Whirligig" Test. Single Element Preburner and Main Injector Test. 40K Multi-Element Preburner and MI. Full-Scale Battleship Preburner. Prototype Preburner Test Article. Full-Scale Prototype TCA. Turbopump Hot-Fire Test Article. Prototype Engine. Validated Analytical Models.

Effects of Signaled Positive Reinforcement on Problem Behavior Maintained by Negative Reinforcement

ERIC Educational Resources Information Center

Schieltz, Kelly M.; Wacker, David P.; Romani, Patrick W.

2017-01-01

We evaluated the effects of providing positive reinforcement for task completion, signaled via the presence of a tangible item, on escape-maintained problem behavior displayed by three typically developing children during one-time 90-min outpatient evaluations. Brief functional analyses of problem behavior, conducted within a multielement design,…

Assessing Cardiovascular Responses to Stressors in Individuals with Autism Spectrum Disorders

ERIC Educational Resources Information Center

Groden, June; Goodwin, Matthew S.; Baron, M. Grace; Groden, Gerald; Velicer, Wayne F.; Lipsitt, Lewis P.; Hofmann, Stefan G.; Plummer, Brett

2005-01-01

Characteristics of persons with autism and other developmental disabilities may make this population especially vulnerable to the effects of stress. Prior research on stress and its measurement in this population is reviewed. Using a single-case multi-element design, this study explores the feasibility of measuring cardiovascular responses to four…

Simultaneous Atomic Absorption Spectrometry for Cadmium and Lead Determination in Wastewater: A Laboratory Exercise

ERIC Educational Resources Information Center

Correia, Paulo R. M.; Oliveira, Pedro V.

2004-01-01

The simultaneous determination of cadmium and lead by multi-element atomic absorption spectrometry with electrochemical atomization is proposed by employing a problem-based approach. The reports indicate that the students assimilated the principles of the simultaneous atomic absorption spectrometry (SIMAAS), the role of the chemical modifier, the…

Brief Report: Teaching Situation-Based Emotions to Children with Autistic Spectrum Disorder

ERIC Educational Resources Information Center

McHugh, Louise; Bobarnac, Alina; Reed, Phil

2011-01-01

Many individuals with autism spectrum disorders (ASD) have difficulty recognizing emotions in themselves and others. Three children (all males) participated in the study. In a multi-element design children with ASD were trained to tact situation-based emotions (i.e., "happy", "sad", "angry", and "afraid") using novel video based scenarios. To…

Studying as Fun and Games: Effects on College Students' Quiz Performance

ERIC Educational Resources Information Center

Neef, Nancy A.; Perrin, Christopher J.; Haberlin, Alayna T.; Rodrigues, Lilian C.

2011-01-01

We examined college students' participation in a game activity for studying course material on their subsequent quiz performance. Game conditions were alternated with another activity counterbalanced across two groups of students in a multielement design. Overall, the mean percentage correct on quizzes was higher during the game condition than…

Simulation of Fluid Flow and Collection Efficiency for an SEA Multi-element Probe

NASA Technical Reports Server (NTRS)

Rigby, David L.; Struk, Peter M.; Bidwell, Colin

2014-01-01

Numerical simulations of fluid flow and collection efficiency for a Science Engineering Associates (SEA) multi-element probe are presented. Simulation of the flow field was produced using the Glenn-HT Navier-Stokes solver. Three dimensional unsteady results were produced and then time averaged for the collection efficiency results. Three grid densities were investigated to enable an assessment of grid dependence. Collection efficiencies were generated for three spherical particle sizes, 100, 20, and 5 micron in diameter, using the codes LEWICE3D and LEWICE2D. The free stream Mach number was 0.27, representing a velocity of approximately 86 ms. It was observed that a reduction in velocity of about 15-20 occurred as the flow entered the shroud of the probe.Collection efficiency results indicate a reduction in collection efficiency as particle size is reduced. The reduction with particle size is expected, however, the results tended to be lower than previous results generated for isolated two-dimensional elements. The deviation from the two-dimensional results is more pronounced for the smaller particles and is likely due to the effect of the protective shroud.

Capacitively readout multi-element sensor array with common-mode cancellation

DOEpatents

Britton, Jr., Charles L.; Warmack, Robert J.; Bryan, William L.; Jones, Robert L.; Oden, Patrick Ian; Thundat, Thomas

2001-01-01

An improved multi-element apparatus for detecting the presence of at least one chemical, biological or physical component in a monitored area comprising an array or single set of the following elements: a capacitive transducer having at least one cantilever spring element secured thereto, the cantilever element having an area thereof coated with a chemical having an affinity for the component to be detected; a pick-up plate positioned adjacent to the cantilever element at a distance such that a capacitance between the cantilever element and the pick-up plate changes as the distance between the cantilever element and the pick-up plate varies, the change in capacitance being a measurable variation; a detection means for measuring the measurable variation in the capacitance between the cantilever element and the pick-up plate that forms a measurement channel signal; and at least one feedback cantilever spring element positioned apart from the coated cantilever element, the cantilever element substantially unaffected by the component being monitored and providing a reference channel signal to the detection means that achieves a common mode cancellation between the measurement channel signal and reference channel signal.

Multi-element microelectropolishing method

DOEpatents

Lee, Peter J.

1994-01-01

A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle.

Experimental Combustion Dynamics Behavior of a Multi-Element Lean Direct Injection (LDI) Gas Turbine Combustor

NASA Technical Reports Server (NTRS)

Acosta, Waldo A.; Chang, Clarence T.

2016-01-01

An experimental investigation of the combustion dynamic characteristics of a research multi-element lean direct injection (LDI) combustor under simulated gas turbine conditions was conducted. The objective was to gain a better understanding of the physical phenomena inside a pressurized flametube combustion chamber under acoustically isolated conditions. A nine-point swirl venturi lean direct injection (SV-LDI) geometry was evaluated at inlet pressures up to 2,413 kPa and non-vitiated air temperatures up to 867 K. The equivalence ratio was varied to obtain adiabatic flame temperatures between 1388 K and 1905 K. Dynamic pressure measurements were taken upstream of the SV-LDI, in the combustion zone and downstream of the exit nozzle. The measurements showed that combustion dynamics were fairly small when the fuel was distributed uniformly and mostly due to fluid dynamics effects. Dynamic pressure fluctuations larger than 40 kPa at low frequencies were measured at 653 K inlet temperature and 1117 kPa inlet pressure when fuel was shifted and the pilot fuel injector equivalence ratio was increased to 0.72.

New sonic shockwave multi-element sensors mounted on a small airfoil flown on F-15B testbed aircraft

NASA Technical Reports Server (NTRS)

1996-01-01

An experimental device to pinpoint the location of a shockwave that develops in an aircraft flying at transonic and supersonic speeds was recently flight-tested at NASA's Dryden Flight Research Center, Edwards, California. The shock location sensor, developed by TAO Systems, Hampton, Va., utilizes a multi-element hot-film sensor array along with a constant-voltage anemometer and special diagnostic software to pinpoint the exact location of the shockwave and its characteristics as it develops on an aircraft surface. For this experiment, the 45-element sensor was mounted on the small Dryden-designed airfoil shown in this illustration. The airfoil was attached to the Flight Test Fixture mounted underneath the fuselage of Dryden's F-15B testbed aircraft. Tests were flown at transonic speeds of Mach 0.7 to 0.9, and the device isolated the location of the shock wave to within a half-inch. Application of this technology could assist designers of future supersonic aircraft in improving the efficiency of engine air inlets by controlling the shockwave, with a related improvement in aircraft performance and fuel economy.

Extreme pollution of soils by emissions of the copper-nickel industrial complex in the Kola Peninsula

NASA Astrophysics Data System (ADS)

Kashulina, G. M.

2017-07-01

The distribution of the total Ni, Cu, Co, Cd, Pb, and Zn contents was studied in the soil profiles of six catenas in the zone subjected to emissions of the copper-nickel industrial complex, which is the largest source of SO2 and heavy metals in northern Europe. The results show that, at present, the concentrations of Ni and Cu in the upper organic soil horizons in the impact zone reach extreme levels of 9000 and 6000 mg/kg, respectively. Under conditions of the long-term intense multi-element industrial emissions, the modern levels of the accumulation of polluting substances in soils greatly depend on the indirect factors, such as the degree of the technogenic degradation of soils with the loss of a significant part of soil organic matter, the reaching of threshold saturation of the topsoil with polluting metals, and competitive relationships between chemical elements. The state of the ecosystems in the impact zone varied greatly and did not always agree with the contents of the main metals-pollutants in the soils. The moisture conditions determined by the landscape position affected significantly the resistance of the ecosystems to emissions.

Development of acoustically lined ejector technology for multitube jet noise suppressor nozzles by model and engine tests over a wide range of jet pressure ratios and temperatures

NASA Technical Reports Server (NTRS)

Atvars, J.; Paynter, G. C.; Walker, D. Q.; Wintermeyer, C. F.

1974-01-01

An experimental program comprising model nozzle and full-scale engine tests was undertaken to acquire parametric data for acoustically lined ejectors applied to primary jet noise suppression. Ejector lining design technology and acoustical scaling of lined ejector configurations were the major objectives. Ground static tests were run with a J-75 turbojet engine fitted with a 37-tube, area ratio 3.3 suppressor nozzle and two lengths of ejector shroud (L/D = 1 and 2). Seven ejector lining configurations were tested over the engine pressure ratio range of 1.40 to 2.40 with corresponding jet velocities between 305 and 610 M/sec. One-fourth scale model nozzles were tested over a pressure ratio range of 1.40 to 4.0 with jet total temperatures between ambient and 1088 K. Scaling of multielement nozzle ejector configurations was also studied using a single element of the nozzle array with identical ejector lengths and lining materials. Acoustic far field and near field data together with nozzle thrust performance and jet aerodynamic flow profiles are presented.

Process recognition in multi-element soil and stream-sediment geochemical data

USGS Publications Warehouse

Grunsky, E.C.; Drew, L.J.; Sutphin, D.M.

2009-01-01

Stream-sediment and soil geochemical data from the Upper and Lower Coastal Plains of South Carolina (USA) were studied to determine relationships between soils and stream sediments. From multi-element associations, characteristic compositions were determined for both media. Primary associations of elements reflect mineralogy, including heavy minerals, carbonates and clays, and the effects of groundwater. The effects of groundwater on element concentrations are more evident in soils than stream sediments. A "winnowing index" was created using ratios of Th to Al that revealed differing erosional and depositional environments. Both soils and stream sediments from the Upper and Lower Coastal Plains show derivation from similar materials and subsequent similar multi-element relationships, but have some distinct differences. In the Lower Coastal Plain, soils have high values of elements concentrated in heavy minerals (Ce, Y, Th) that grade into high values of elements concentrated into finer-grain-size, lower-density materials, primarily comprised of carbonates and feldspar minerals (Mg, Ca, Na, K, Al). These gradational trends in mineralogy and geochemistry are inferred to reflect reworking of materials during marine transgressions and regressions. Upper Coastal Plain stream-sediment geochemistry shows a higher winnowing index relative to soil geochemistry. A comparison of the 4 media (Upper Coastal Plain soils and stream sediments and Lower Coastal Plain soils and stream sediments) shows that Upper Coastal Plain stream sediments have a higher winnowing index and a higher concentration of elements contained within heavy minerals, whereas Lower Coastal Plain stream sediments show a strong correlation between elements typically contained within clays. It is not possible to calculate a functional relationship between stream sediment-soil compositions for all elements due to the complex history of weathering, deposition, reworking and re-deposition. However, depending on the spatial separation of the stream-sediment and soil samples, some elements are more highly correlated than others. Crown Copyright ?? 2009.

Design considerations regarding an atomizer for multi-element electrothermal atomic absorption spectrometry

NASA Astrophysics Data System (ADS)

Katskov, Dmitri A.; Sadagov, Yuri M.

2011-06-01

The methodology of simultaneous multi-element electrothermal atomic absorption spectrometry (ETAAS-Electrothermal Atomic Absorption Spectrometry) stipulates rigid requirements to the design and operation of the atomizer. It must provide high degree of atomization for the group of analytes, invariant respective to the vaporization kinetics and heating ramp residence time of atoms in the absorption volume and absence of memory effects from major sample components. For the low resolution spectrometer with a continuum radiation source the reduced compared to traditional ETAAS (Electrothermal Atomic Absorption Spectrometry) sensitivity should be, at least partially, compensated by creating high density of atomic vapor in the absorption pulse. The sought-for characteristics were obtained for the 18 mm in length and 2.5 mm in internal diameter longitudinally heated graphite tube atomizer furnished with 2-4.5 mg of ring shaped carbon fiber yarn collector. The collector located next to the sampling port provides large substrate area that helps to keep the sample and its residue in the central part of the tube after drying. The collector also provides a "platform" effect that delays the vaporization and stipulates vapor release into absorption volume having already stabilized gas temperature. Due to the shape of external surface of the tube, presence of collector and rapid (about 10 °C/ms) heating, an inverse temperature distribution along the tube is attained at the beginnings of the atomization and cleaning steps. The effect is employed for cleaning of the atomizer using the set of short maximum power heating pulses. Preparation, optimal maintenance of the atomizer and its compliance to the multi-element determination requirements are evaluated and discussed. The experimental setup provides direct simultaneous determination of large group of element within 3-4 order concentration range. Limits of detection are close to those for sequential single element determination in Flame AAS with primary line source that is 50-1000 times higher than the limits obtainable with common ETAAS (Electrothermal Atomic Absorption Spectrometry) instrumentation.

HIFU scattering by the ribs: constrained optimisation with a complex surface impedance boundary condition

NASA Astrophysics Data System (ADS)

Gélat, P.; ter Haar, G.; Saffari, N.

2014-04-01

High intensity focused ultrasound (HIFU) enables highly localised, non-invasive tissue ablation and its efficacy has been demonstrated in the treatment of a range of cancers, including those of the kidney, prostate and breast. HIFU offers the ability to treat deep-seated tumours locally, and potentially bears fewer side effects than more established treatment modalities such as resection, chemotherapy and ionising radiation. There remains however a number of significant challenges which currently hinder its widespread clinical application. One of these challenges is the need to transmit sufficient energy through the ribcage to ablate tissue at the required foci whilst minimising the formation of side lobes and sparing healthy tissue. Ribs both absorb and reflect ultrasound strongly. This sometimes results in overheating of bone and overlying tissue during treatment, leading to skin burns. Successful treatment of a patient with tumours in the upper abdomen therefore requires a thorough understanding of the way acoustic and thermal energy is deposited. Previously, a boundary element (BE) approach based on a Generalised Minimal Residual (GMRES) implementation of the Burton-Miller formulation was developed to predict the field of a multi-element HIFU array scattered by human ribs, the topology of which was obtained from CT scan data [1]. Dissipative mechanisms inside the propagating medium have since been implemented, together with a complex surface impedance condition at the surface of the ribs. A reformulation of the boundary element equations as a constrained optimisation problem was carried out to determine the complex surface velocities of a multi-element HIFU array which generated the acoustic pressure field that best fitted a required acoustic pressure distribution in a least-squares sense. This was done whilst ensuring that an acoustic dose rate parameter at the surface of the ribs was kept below a specified threshold. The methodology was tested at an excitation frequency of 1 MHz on a spherical multi-element array in the presence of anatomical ribs.

SIMS chemical analysis of extended impacts on the leading and trailing edges of LDEF experiment AO187-2

NASA Technical Reports Server (NTRS)

Amari, S.; Foote, J.; Simon, Charles G.; Swan, P.; Walker, R. M.; Zinner, E.; Jessberger, E. K.; Lange, G.; Stadermann, F.

1992-01-01

The Long Duration Exposure Facility (LDEF) Experiment AO187-2 consisted of 237 capture cells, 120 on the leading edge and 117 on the trailing edge. Each cell was made of polished Ge plates covered with 2.5 micron thick mylar foil at 200 microns from the Ge. Although all leading edge cells and 105 trailing edge cells had lost their plastic covers during flight, optical and electron microscope examination revealed extended impacts in bare cells from either edge that apparently were produced by high velocity projectiles while the plastic foils were still in place. Detailed optical scanning yielded 53 extended impacts on 100 bare cells from the trailing edge that were selected for SIMS chemical analysis. Lateral multi-element ion probe profiles were obtained on 40 of these impacts. Material that can be attributed to the incoming projectiles was found in all analyzed extended compact features and most seem to be associated with cosmic dust particles. However, LDEF deposits are systematically enriched in the refractory elements Al, Ca, and Ti relative to Mg and Fe when compared to IDP's collected in the stratosphere and to chondritic compositions. These differences are most likely due to elemental fractionation effects during the high velocity impact but real differences between interplanetary particles captured on LDEF and stratospheric IDP's cannot be excluded. Recently we extended our studies to cells from the leading edge and the covered cells from the trailing edge. The 12 covered cells contain 20 extended impact candidates. Ion probe analysis of 3 yielded results similar to those obtained for impacts on the bare cells from the trailing edge. Optical scanning of the bare leading edge cell also reveals many extended impacts (42 on 22 cells scanned to date), demonstrating that the cover foils remained intact at least for some time. However, SIMS analysis showed elements that can reasonably be attributed to micrometeoroids in only 2 out of 11 impacts. Eight impacts have residues dominated by Al and one dominated by Ti, indicating a preponderance of orbital debris in leading edge impacts.

Air pollution source identification

NASA Technical Reports Server (NTRS)

Fordyce, J. S.

1975-01-01

The techniques available for source identification are reviewed: remote sensing, injected tracers, and pollutants themselves as tracers. The use of the large number of trace elements in the ambient airborne particulate matter as a practical means of identifying sources is discussed. Trace constituents are determined by sensitive, inexpensive, nondestructive, multielement analytical methods such as instrumental neutron activation and charged particle X-ray fluorescence. The application to a large data set of pairwise correlation, the more advanced pattern recognition-cluster analysis approach with and without training sets, enrichment factors, and pollutant concentration rose displays for each element is described. It is shown that elemental constituents are related to specific source types: earth crustal, automotive, metallurgical, and more specific industries. A field-ready source identification system based on time and wind direction resolved sampling is described.

Assessment of the analytical capabilities of inductively coupled plasma-mass spectrometry

USGS Publications Warehouse

Taylor, Howard E.; Garbarino, John R.

1988-01-01

A thorough assessment of the analytical capabilities of inductively coupled plasma-mass spectrometry was conducted for selected analytes of importance in water quality applications and hydrologic research. A multielement calibration curve technique was designed to produce accurate and precise results in analysis times of approximately one minute. The suite of elements included Al, As, B, Ba, Be, Cd, Co, Cr, Cu, Hg, Li, Mn, Mo, Ni, Pb, Se, Sr, V, and Zn. The effects of sample matrix composition on the accuracy of the determinations showed that matrix elements (such as Na, Ca, Mg, and K) that may be present in natural water samples at concentration levels greater than 50 mg/L resulted in as much as a 10% suppression in ion current for analyte elements. Operational detection limits are presented.

Simulations of a Liquid Hydrogen Inducer at Low-Flow Off-Design Flow Conditions

NASA Technical Reports Server (NTRS)

Hosangadi, A.; Ahuja, V.; Ungewitter, R. J.

2005-01-01

The ability to accurately model details of inlet back flow for inducers operating a t low-flow, off-design conditions is evaluated. A sub-scale version of a three-bladed liquid hydrogen inducer tested in water with detailed velocity and pressure measurements is used as a numerical test bed. Under low-flow, off-design conditions the length of the separation zone as well as the swirl velocity magnitude was under predicted with a standard k-E model. When the turbulent viscosity coefficient was reduced good comparison was obtained a t all the flow conditions examined with both the magnitude and shape of the profile matching well with the experimental data taken half a diameter upstream of the leading edge. The velocity profiles and incidence angles a t the leading edge itself were less sensitive to the back flow length predictions indicating that single-phase performance predictions may be well predicted even if the details of flow separation modeled are incorrect. However, for cavitating flow situations the prediction of the correct swirl in the back flow and the pressure depression in the core becomes critical since it leads to vapor formation. The simulations have been performed using the CRUNCH CFD(Registered Trademark) code that has a generalized multi-element unstructured framework and a n advanced multi-phase formulation for cryogenic fluids. The framework has been validated rigorously for predictions of temperature and pressure depression in cryogenic fluid cavities and has also been shown to predict the cavitation breakdown point for inducers a t design conditions.

The Effects of Priming on Spontaneous Verbal Language in Children with Autism Spectrum Disorders

ERIC Educational Resources Information Center

Ivey, Michelle L.

2008-01-01

A multi-element design was used to investigate the effect of priming on spontaneous verbal communication in children with Autism Spectrum Disorders (ASD). Three children with ASD engaged in 20-minute thematic activity sessions (ACT) with the investigator. Prior to the ACTs, they met with another trained researcher for 10-minute presessions. Half…

A Comparison of Prompting Strategies to Teach Intraverbals to an Adolescent with Down Syndrome

ERIC Educational Resources Information Center

Wallace, Abigail M.; Bechtel, D. Reed; Heatter, Sue; Barry, Leasha M.

2016-01-01

Ingvarsson and Hollobaugh (2011) investigated tact- or echoic-to-intraverbal transfer of stimulus control to "wh" questions for three preschool-aged boys with autism. The current study was a systematic replication of this study with an adolescent girl with Down syndrome. A multi-element design was used to compare the effectiveness and…

Selecting Effective Interventions to Increase Math Computation Fluency via Brief Experimental Analyses

ERIC Educational Resources Information Center

Reisener, Carmen D.; Dufrene, Brad A.; Clark, Chelsi R.; Olmi, D. Joe; Tingstrom, Daniel H.

2016-01-01

In a response to intervention RtI paradigm, the use of brief experimental analyses (BEAs) for identifying effective interventions for elementary and middle school students struggling with math is a relatively new area of research. This investigation includes two studies, both of which employed a brief multielement design and an extended analysis…

Effects of a Group Contingency Strategy on Middle School Physical Education Students' Heart Rates

ERIC Educational Resources Information Center

Vidoni, Carla; Azevedo, Liane; Eberline, Andrew

2012-01-01

The purpose of this study was to assess the effects of a dependent group contingency on eighth-grade students' heart rates. Participants were 18 male and female students. A multielement research design was used to examine the intervention effects. The intervention consisted of: (a) teacher explanation about effort; (b) students' suggestions to…

Special Educators and Data Recording: What's Delayed Recording Got to Do With It?

ERIC Educational Resources Information Center

Jasper, Andrea D.; Taber Doughty, Teresa

2015-01-01

This study examined the effects of delayed recording on the accuracy of data recorded by special educators serving students with high- or low-incidence disabilities. A multi-element design was used to compare the accuracy of data recorded across three conditions: (a) immediately after a student's target behavior occurred, (b) immediately after the…

Studying as fun and games: effects on college students' quiz performance.

PubMed

Neef, Nancy A; Perrin, Christopher J; Haberlin, Alayna T; Rodrigues, Lilian C

2011-01-01

We examined college students' participation in a game activity for studying course material on their subsequent quiz performance. Game conditions were alternated with another activity counterbalanced across two groups of students in a multielement design. Overall, the mean percentage correct on quizzes was higher during the game condition than in the no-game condition.

Near-reef elemental signals in the otoliths of settling Pomacentrus amboinensis (Pomacentridae)

NASA Astrophysics Data System (ADS)

Sih, Tiffany L.; Kingsford, Michael J.

2016-03-01

Settlement is a key life history transition for coral reef fishes, and how long a fish spends close to a reef prior to settlement is poorly understood. We used laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and otolith microstructure analysis (daily increments and settlement marks) to determine the length of time larval fish spend near a reef prior to settlement. The otoliths of Pomacentrus amboinensis collected from four neighbouring reefs in the southern Great Barrier Reef showed clear and consistent differences in their elemental signatures prior to and following settlement. Elevated Ba:Ca near settlement and post-settlement was found in fish from all four reefs. However, there was individual variation in elemental profiles, with an increased otolith Ba-to-Ca ratio (near-reef signature) at settlement in 33 % of fish, and up to 8 d prior to settlement in others. Increment widths, often used as a proxy for growth, decreased approaching the settlement mark for all fish, providing further evidence for a "search phase" in larvae. We demonstrated experimentally that otoliths of fish kept in reefal or inter-reefal waters had different elemental chemistry. There were differences in the elemental composition of water samples within the study area, but no consistent trends with distance from reefs. There was poor discrimination of multi-element signatures among fish from different reefs during their pre-settlement phases. However, discrimination improved in the settlement and post-settlement phases of otoliths, indicating that reef waters and perhaps stage of ontogeny affected otolith chemistry. This study demonstrated clear near-reef elemental signatures in fish around settlement. We suggest these differences are due to a combination of water chemistry and physiological influences (e.g., growth). Combining LA-ICP-MS with otolith microstructure analysis can provide high-resolution information on the early life history of reef fishes. Further, a near-reef "search phase" prior to settlement may be common in reef fishes.

High hair selenium mother to fetus transfer after the Brazil nuts consumption.

PubMed

Momčilović, B; Prejac, J; Višnjević, V; Brundić, S; Skalny, A A; Mimica, N

2016-01-01

Lactating mother and her two month old healthy daughter (APGAR 10) gave their scalp hair for a multielement profile analysis; 25 elements were analyzed with the ICP MS. Mother's hair was divided into 5cm long segment proximal to the scull (Young), and the distal segment further up to the hair tip (Old). One centimeter of hair records one month of the metabolic activity of the bioelements in the body. Mother's Young hair and daughters hair have 2.70 and 9.74μgg(-1)Se, a distinctly higher Se concentrations than the Old hair of 0.87μgg(-1). The adequate hair Se concentrations in Croatia women population vary from 0.08 to 0.63μgg(-1); values below or above that range indicate deficiency or excess, respectively. Dietary recall revealed that during the last trimester of pregnancy and over a period of a week, the mother has consumed 135g of Brazil nuts (Bertholletia excelsa) (BN); BN is an exceptionally rich Se dietary source. The amount of Se in BN varies and one week consumption of 135g of BN may result in Se daily intake of 367 to 492μgg(-1)day(-1) over a period of seven consecutive days, and what is about or exceeds the Upper Limit of daily selenium intake of 400μg(-1)g(-1). The excessively high infant hair Se mirrored a natural high mother to fetus transplacental transfer of bio elements in the last trimester of pregnancy. The potential toxicological risks of such a high Se transfer remains to be elucidated. Copyright © 2015 Elsevier GmbH. All rights reserved.

UV-sensitive scientific CCD image sensors

NASA Astrophysics Data System (ADS)

Vishnevsky, Grigory I.; Kossov, Vladimir G.; Iblyaminova, A. F.; Lazovsky, Leonid Y.; Vydrevitch, Michail G.

1997-06-01

An investigation of probe laser irradiation interaction with substances containing in an environment has long since become a recognized technique for contamination detection and identification. For this purpose, a near and midrange-IR laser irradiation is traditionally used. However, as many works presented on last ecology monitoring conferences show, in addition to traditional systems, rapidly growing are systems with laser irradiation from near-UV range (250 - 500 nm). Use of CCD imagers is one of the prerequisites for this allowing the development of a multi-channel computer-based spectral research system. To identify and analyze contaminating impurities on an environment, such methods as laser fluorescence analysis, UV absorption and differential spectroscopy, Raman scattering are commonly used. These methods are used to identify a large number of impurities (petrol, toluene, Xylene isomers, SO2, acetone, methanol), to detect and identify food pathogens in real time, to measure a concentration of NH3, SO2 and NO in combustion outbursts, to detect oil products in a water, to analyze contaminations in ground waters, to define ozone distribution in the atmosphere profile, to monitor various chemical processes including radioactive materials manufacturing, heterogeneous catalytic reactions, polymers production etc. Multi-element image sensor with enhanced UV sensitivity, low optical non-uniformity, low intrinsic noise and high dynamic range is a key element of all above systems. Thus, so called Virtual Phase (VP) CCDs possessing all these features, seems promising for ecology monitoring spectral measuring systems. Presently, a family of VP CCDs with different architecture and number of pixels is developed and being manufactured. All CCDs from this family are supported with a precise slow-scan digital image acquisition system that can be used in various image processing systems in astronomy, biology, medicine, ecology etc. An image is displayed directly on a PC monitor through a software support.

Laser Amplifier Development for the Remote Sensing of CO2 from Space

NASA Technical Reports Server (NTRS)

Yu, Anthony W.; Abshire, James B.; Storm, Mark; Betin, Alexander

2015-01-01

Accurate global measurements of tropospheric CO2 mixing ratios are needed to study CO2 emissions and CO2 exchange with the land and oceans. NASA Goddard Space Flight Center (GSFC) is developing a pulsed lidar approach for an integrated path differential absorption (IPDA) lidar to allow global measurements of atmospheric CO2 column densities from space. Our group has developed, and successfully flown, an airborne pulsed lidar instrument that uses two tunable pulsed laser transmitters allowing simultaneous measurement of a single CO2 absorption line in the 1570 nm band, absorption of an O2 line pair in the oxygen A-band (765 nm), range, and atmospheric backscatter profiles in the same path. Both lasers are pulsed at 10 kHz, and the two absorption line regions are sampled at typically a 300 Hz rate. A space-based version of this lidar must have a much larger lidar power-area product due to the approximately x40 longer range and faster along track velocity compared to airborne instrument. Initial link budget analysis indicated that for a 400 km orbit, a 1.5 m diameter telescope and a 10 second integration time, a approximately 2 mJ laser energy is required to attain the precision needed for each measurement. To meet this energy requirement, we have pursued parallel power scaling efforts to enable space-based lidar measurement of CO2 concentrations. These included a multiple aperture approach consists of multi-element large mode area fiber amplifiers and a single-aperture approach consists of a multi-pass Er:Yb:Phosphate glass based planar waveguide amplifier (PWA). In this paper we will present our laser amplifier design approaches and preliminary results.

High Energy, Narrow Linewidth 1572nm Eryb-Fiber Based MOPA for a Multi-Aperture CO2 Trace-Gas Laser Space Transmitter

NASA Technical Reports Server (NTRS)

Engin, Doruk; Mathason, Brian; Stephen, Mark; Yu, Anthony; Cao, He; Fouron, Jean-Luc; Storm, Mark

2016-01-01

Accurate global measurements of tropospheric CO2 mixing ratios are needed to study CO2 emissions and CO2 exchange with the land and oceans. NASA Goddard Space Flight Center (GSFC) is developing a pulsed lidar approach for an integrated path differential absorption (IPDA) lidar to allow global measurements of atmospheric CO2 column densities from space. Our group has developed, and successfully flown, an airborne pulsed lidar instrument that uses two tunable pulsed laser transmitters allowing simultaneous measurement of a single CO2 absorption line in the 1570 nm band, absorption of an O2 line pair in the oxygen A-band (765 nm), range, and atmospheric backscatter profiles in the same path. Both lasers are pulsed at 10 kHz, and the two absorption line regions are sampled at typically a 300 Hz rate. A space-based version of this lidar must have a much larger lidar power-area product due to the x40 longer range and faster along track velocity compared to airborne instrument. Initial link budget analysis indicated that for a 400 km orbit, a 1.5 m diameter telescope and a 10 second integration time, a 2 mJ laser energy is required to attain the precision needed for each measurement. To meet this energy requirement, we have pursued parallel power scaling efforts to enable space-based lidar measurement of CO2 concentrations. These included a multiple aperture approach consists of multi-element large mode area fiber amplifiers and a single-aperture approach consists of a multi-pass Er:Yb:Phosphate glass based planar waveguide amplifier (PWA). In this paper we will present our laser amplifier design approaches and preliminary results.

Descriptive and experimental analyses of variables maintaining self-injurious behavior.

PubMed Central

Lerman, D C; Iwata, B A

1993-01-01

Independent descriptive (correlational) and functional (experimental) analyses were conducted to determine the extent to which the two methods would yield data supporting similar conclusions about variables maintaining the self-injurious behavior (SIB) of 6 subjects. For the descriptive analyses, subjects were observed in their residences and at training sites at various times each day while observers recorded naturally occurring sequences of specified subject and staff behaviors. The subjects also participated in a day program for the assessment and treatment of SIB, in which they were exposed to functional analyses that manipulated potential maintaining variables in multielement designs. Both sets of data were analyzed via conditional probabilities to identify relevant antecedent and consequent events for subjects' SIB. Using outcomes of the experimental analysis as the standard for comparison, results indicated that the descriptive analysis was useful in identifying the extent to which SIB was related to social versus nonsocial contingencies, but was limited in its ability to distinguish between positive and negative reinforcement (i.e., attention versus escape). PMID:8407680

Genetic and geochemical signatures to prevent frauds and counterfeit of high-quality asparagus and pistachio.

PubMed

Zannella, Carmela; Carucci, Francesca; Aversano, Riccardo; Prohaska, Thomas; Vingiani, Simona; Carputo, Domenico; Adamo, Paola

2017-12-15

A fingerprinting strategy based on genetic (simple sequence repeat) and geochemical (multielement and 87 Sr/ 86 Sr ratio) analysis was tested to prove the geographical origin of high-quality Italian products "White Asparagus from Bassano del Grappa" and "Green Pistachio from Bronte". Genetic analysis generated many polymorphic alleles and different specific amplified fragments in both agriproducts. In addition, a core set of markers was defined. According to variability within production soils and products, potential candidate elements linking asparagus (Zn, P, Cr, Mg, B, K) and pistachio (Mn, P, Cr, Mg, Ti, B, K, Sc, S) to the production areas were identified. The Sr isotopic signature was an excellent marker when Italian asparagus was compared with literature data for Hungarian and Peruvian asparagus. This work reinforces the use of Sr isotope composition in the soil bioavailable fraction, as assessed by 1mol/L NH 4 NO 3 , to distinguish white asparagus and pistachio originating from different geographical areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

An in Situ Technique for Elemental Analysis of Lunar Surfaces

NASA Technical Reports Server (NTRS)

Kane, K. Y.; Cremers, D. A.

1992-01-01

An in situ analytical technique that can remotely determine the elemental constituents of solids has been demonstrated. Laser-Induced Breakdown Spectroscopy (LIBS) is a form of atomic emission spectroscopy in which a powerful laser pulse is focused on a solid to generate a laser spark, or microplasma. Material in the plasma is vaporized, and the resulting atoms are excited to emit light. The light is spectrally resolved to identify the emitting species. LIBS is a simple technique that can be automated for inclusion aboard a remotely operated vehicle. Since only optical access to a sample is required, areas inaccessible to a rover can be analyzed remotely. A single laser spark both vaporizes and excites the sample so that near real-time analysis (a few minutes) is possible. This technique provides simultaneous multielement detection and has good sensitivity for many elements. LIBS also eliminates the need for sample retrieval and preparation preventing possible sample contamination. These qualities make the LIBS technique uniquely suited for use in the lunar environment.

Further evaluation of a functional analysis of moderate-to-vigorous physical activity in young children.

PubMed

Larson, Tracy A; Normand, Matthew P; Morley, Allison J; Miller, Bryon G

2014-01-01

Inadequate physical activity increases the risks related to several health problems in children; however, increasing physical activity mitigates these risks. In this study, we examined the relations between moderate-to-vigorous physical activity (MVPA) and several environmental conditions (attention, interactive play, alone, escape) with 4 preschool children. We compared the experimental conditions to a control condition and a naturalistic baseline according to a combined multielement and reversal design. Results indicated that all participants were most active in the interactive play condition and that the percentage of MVPA varied across experimental and control conditions. In addition, the frequency and duration of bouts of MVPA were greatest in the interactive play condition. The current study presents a methodology for the identification of environmental contingencies that support increased levels of MVPA in young children, and it holds promise for improving our understanding of the variables related to physical activity. © Society for the Experimental Analysis of Behavior.

Embedded Prompting May Function as Embedded Punishment: Detection of Unexpected Behavioral Processes within a Typical Preschool Teaching Strategy

ERIC Educational Resources Information Center

Heal, Nicole A.; Hanley, Gregory P.

2011-01-01

This study describes an unexpected behavioral process that influenced behavior during the teaching of concepts to a 4-year-old girl. The efficacy of and preference for three strategies that varied in teacher directedness were assessed in a multielement design and concurrent-chains arrangement, respectively. The strategy that involved the most…

Awell-preserved conodont fauna from the Pennsylvanian Excello Shale of Iowa, U. S. A.

USGS Publications Warehouse

Merlynd K. Nestell,; Wardlaw, Bruce R.; John P. Pope,

2016-01-01

A superbly preserved discrete element conodont fauna has been recovered from carbonate concretions from the upper Desmoinesian (Pennsylvanian) Excello Shale at two localities in south-central Iowa. The multielement apparatuses for Gondolella wardlawi (new species), Idiognathodus acutus, Idioprioniodus conjunctus, and Neognathodus roundyi are reconstructed. Rare specimens of Idiognathodus tuberis (new species) also occur in the fauna.

Multi-channel electronically scanned cryogenic pressure sensor

NASA Technical Reports Server (NTRS)

Chapman, John J. (Inventor); Hopson, Purnell, Jr. (Inventor); Kruse, Nancy M. H. (Inventor)

1995-01-01

A miniature, multi-channel, electronically scanned pressure measuring device uses electrostatically bonded silicon dies in a multielement array. These dies are bonded at specific sites on a glass, prepatterned substrate. Thermal data is multiplexed and recorded on each individual pressure measuring diaphragm. The device functions in a cryogenic environment without the need of heaters to keep the sensor at constant temperatures.

Initiatives (Part 1): Keystone; Cycle Time Puzzle, A Full-Scale Challenge; Foot to Foot, Face to Face; Change Management; Multi-Element Team Challenge.

ERIC Educational Resources Information Center

Schoel, Jim; Butler, Steve; Murray, Mark; Gass, Mike; Carrick, Moe

2001-01-01

Presents five group problem-solving initiatives for use in adventure and experiential settings, focusing on conflict resolution, corporate workplace issues, or adjustment to change. Includes target group, group size, time and space needs, activity level, overview, goals, props, instructions, and suggestions for framing and debriefing the…

Increasing Seat Belt Use on a College Campus: An Evaluation of Two Prompting Procedures

ERIC Educational Resources Information Center

Clayton, Michael C.; Helms, Bridgett P.

2009-01-01

Seat belt use is an important factor in the prevention of automobile accidents involving injuries and fatalities. The current study used a multielement design to compare the "Click It or Ticket" and "Please Buckle Up--I Care" procedures. Results indicate that the Click It or Ticket prompt resulted in a 20-percentage-point increase in seat belt…

Effects of Social Stimuli on Laughing and Smiling in Young Children with Angelman Syndrome

ERIC Educational Resources Information Center

Richman, David M.; Gernat, Eric; Teichman, Heather

2006-01-01

The effects of social stimuli present and absent on laughing and smiling in 2 young children with Angelman syndrome were assessed via a multielement design. Results indicated that laughing and smiling for either child was unaffected by the social stimuli assessed in the social interaction condition. Results are discussed in terms of the effects of…

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dmitriev, Alexander S.; Yemelyanov, Ruslan Yu.; Moscow Institute of Physics and Technology

The paper deals with a new multi-element processor platform assigned for modelling the behaviour of interacting dynamical systems, i.e., active wireless network. Experimentally, this ensemble is implemented in an active network, the active nodes of which include direct chaotic transceivers and special actuator boards containing microcontrollers for modelling the dynamical systems and an information display unit (colored LEDs). The modelling technique and experimental results are described and analyzed.

Multielement surface plasmon resonance immunosensor for monitoring of blood circulation system

NASA Astrophysics Data System (ADS)

Kostyukevych, Sergey A.; Kostyukevych, Kateryna V.; Khristosenko, Roman V.; Lysiuk, Viktor O.; Koptyukh, Anastasiya A.; Moscalenko, Nadiya L.

2017-12-01

The problems related to the development of a multielement immunosensor device with the prism type of excitation of a surface plasmon resonance in the Kretschmann configuration and with the scanning of the incidence angle of monochromatic light aimed at the reliable determination of the levels of three molecular markers of the system of hemostasis (fibrinogen, soluble fibrin, and D-dimer) are considered. We have analyzed the influence of a technology for the production of a gold coating, modification of its surface, and noise effects on the enhancement of sensitivity and stability of the operation of devices. A means of oriented immobilization of monoclonal antibodies on the surface of gold using a multilayer film of copper aminopentacyanoferrate is developed. For the model proteins of studied markers, the calibrating curves (maximum sensitivity of 0.5 μg/ml) are obtained, and the level of fibrinogen in blood plasma of donors is determined. A four-channel modification of the device with an application of a reference channel for comparing the elimination of the noise of temperature fluctuations has been constructed. This device allows one to execute the express-diagnostics of prethrombotic states and the monitoring of the therapy of diseases of the blood circulation system.

A distributed transmit beamforming synchronization strategy for multi-element radar systems

NASA Astrophysics Data System (ADS)

Xiao, Manlin; Li, Xingwen; Xu, Jikang

2017-02-01

The distributed transmit beamforming has recently been discussed as an energy-effective technique in wireless communication systems. A common ground of various techniques is that the destination node transmits a beacon signal or feedback to assist source nodes to synchronize signals. However, this approach is not appropriate for a radar system since the destination is a non-cooperative target of an unknown location. In our paper, we propose a novel synchronization strategy for a distributed multiple-element beamfoming radar system. Source nodes estimate parameters of beacon signals transmitted from others to get their local synchronization information. The channel information of the phase propagation delay is transmitted to nodes via the reflected beacon signals as well. Next, each node generates appropriate parameters to form a beamforming signal at the target. Transmit beamforming signals of all nodes will combine coherently at the target compensating for different propagation delay. We analyse the influence of the local oscillation accuracy and the parameter estimation errors on the performance of the proposed synchronization scheme. The results of numerical simulations illustrate that this synchronization scheme is effective to enable the transmit beamforming in a distributed multi-element radar system.

Single element injector testing for STME injector technology

NASA Technical Reports Server (NTRS)

Hulka, J.; Schneider, J. A.; Davis, J.

1992-01-01

An oxidizer-swirled coaxial element injector is being developed for application in the liquid oxygen/gaseous hydrogen Space Transportation Main Engine (STME) for the National Launch System (NLS) vehicle. This paper reports on the first two parts of a four part single injector element study for optimization of the STME injector design. Measurements of Rupe mixing efficiency and atomization characteristics are reported for single element versions of injection elements from two multielement injectors that have been recently hot fire tested. Rather than attempting to measure a definitive mixing efficiency or droplet size parameters of these injector elements, the purpose of these experiments was to provide a baseline comparison for evaluating future injector element design modifications. Hence, all the experiments reported here were conducted with cold flow simulants to nonflowing, ambient conditions. Mixing experiments were conducted with liquid/liquid simulants to provide economical trend data. Atomization experiments were conducted with liquid/gas simulants without backpressure. The results, despite significant differences from hot fire conditions, were found to relate to mixing and atomization parameters deduced from the hot fire testing, suggesting that these experiments are valid for trend analyses. Single element and subscale multielement hot fire testing will verify optimized designs before committing to fullscale fabrication.

Analytical possibilities of different X-ray fluorescence systems for determination of trace elements in aqueous samples pre-concentrated with carbon nanotubes

NASA Astrophysics Data System (ADS)

Marguí, E.; Zawisza, B.; Skorek, R.; Theato, T.; Queralt, I.; Hidalgo, M.; Sitko, R.

2013-10-01

This study was aimed to achieve improved instrumental sensitivity and detection limits for multielement determination of V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Se, Pb and Cd in liquid samples by using different X-ray fluorescence (XRF) configurations (a benchtop energy-dispersive X-ray fluorescence spectrometer, a benchtop polarised energy-dispersive X-ray fluorescence spectrometer and a wavelength-dispersive X-ray fluorescence spectrometer). The preconcentration of metals from liquid solutions consisted on a solid-phase extraction using carbon nanotubes (CNTs) as solid sorbents. After the extraction step, the aqueous sample was filtered and CNTs with the absorbed elements were collected onto a filter paper which was directly analyzed by XRF. The calculated detection limits in all cases were in the low ng mL- 1 range. Nevertheless, results obtained indicate the benefits, in terms of sensitivity, of using polarized X-ray sources using different secondary targets in comparison to conventional XRF systems, above all if Cd determination is required. The developed methodologies, using the aforementioned equipments, have been applied for multielement determination in water samples from an industrial area of Poland.

A MULTI-ELEMENT THICK GAS ELECTRON MULTIPLIER-BASED MICRODOSEMETER FOR MEASUREMENT OF NEUTRONS DOSE-EQUIVALENT: A MONTE CARLO STUDY.

PubMed

Moslehi, A; Raisali, G

2017-11-01

To determine the dose-equivalent of neutrons in an extended energy range, in the present work a multi-element thick gas electron multiplier-based microdosemeter made of PMMA (Perspex) walls of 10 mm in thickness is designed. Each cavity is filled with the propane-based tissue-equivalent (TE) gas simulating 1 µm of tissue. Also, a few weight fractions of 3He are assumed to be added to the TE gas. The dose-equivalents are determined for 11 neutron energies between thermal and 14 MeV using the lineal energy distributions calculated by Geant4 simulation toolkit and also the lineal energy-based quality factors. The results show that by adding 0.04% of 3He to the TE gas in each cavity, an energy-independent dose-equivalent response within 30% uncertainty around a median value of 0.91 in the above energy range is achieved. It is concluded that after its construction, the studied microdosemeter can be used to measure the dose-equivalent of neutrons, favorably. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Numerical investigation of multi-element airfoils

NASA Technical Reports Server (NTRS)

Cummings, Russell M.

1993-01-01

The flow over multi-element airfoils with flat-plate lift-enhancing tabs was numerically investigated. Tabs ranging in height from 0.25 percent to 1.25 percent of the reference airfoil chord were studied near the trailing edge of the main-element. This two-dimensional numerical simulation employed an incompressible Navier-Stokes solver on a structured, embedded grid topology. New grid refinements were used to improve the accuracy of the solution near the overlapping grid boundaries. The effects of various tabs were studied at a constant Reynolds number on a two-element airfoil with a slotted flap. Both computed and measured results indicated that a tab in the main-element cove improved the maximum lift and lift-to-drag ratio relative to the baseline airfoil without a tab. Computed streamlines revealed that the additional turning caused by the tab may reduce the amount of separated flow on the flap. A three-element airfoil was also studied over a range of Reynolds numbers. For the optimized flap rigging, the computed and measured Reynolds number effects were similar. When the flap was moved from the optimum position, numerical results indicated that a tab may help to reoptimize the airfoil to within 1 percent of the optimum flap case.

Lift-Enhancing Tabs on Multielement Airfoils

NASA Technical Reports Server (NTRS)

Ross, James C.; Storms, Bruce L.; Carrannanto, Paul G.

1995-01-01

The use of flat-plate tabs (similar to Gurney flaps) to enhance the lift of multielement airfoils is extended here by placing them on the pressure side and near the trailing edge of the main element rather than just on the furthest downstream wing element. The tabs studied range in height from 0.125 to 1.25% of the airfoil reference chord. In practice, such tabs would be retracted when the high-lift system is stowed. The effectiveness of the concept was demonstrated experimentally and computationally on a two-dimensional NACA 63(sub 2)-215 Mod B airfoil with a single-slotted, 30%-chord flap. Both the experiments and computations showed that the tabs significantly increase the lift at a given angle of attack and the maximum lift coefficient of the airfoil. The computational results showed that the increased lift was a result of additional turning of the flow by the tab that reduced or eliminated now separation on the flap. The best configuration tested, a 0.5%-chord tab placed 0.5% chord upstream of the trailing edge of the main element, increased the maximum lift coefficient of the airfoil by 12% and the maximum lift-to-drag ratio by 40%.

Multi-element microelectropolishing method

DOEpatents

Lee, P.J.

1994-10-11

A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle. 10 figs.

Computational Plume Modeling of COnceptual ARES Vehicle Stage Tests

NASA Technical Reports Server (NTRS)

Allgood, Daniel C.; Ahuja, Vineet

2007-01-01

The plume-induced environment of a conceptual ARES V vehicle stage test at the NASA Stennis Space Center (NASA-SSC) was modeled using computational fluid dynamics (CFD). A full-scale multi-element grid was generated for the NASA-SSC B-2 test stand with the ARES V stage being located in a proposed off-center forward position. The plume produced by the ARES V main power plant (cluster of five RS-68 LOX/LH2 engines) was simulated using a multi-element flow solver - CRUNCH. The primary objective of this work was to obtain a fundamental understanding of the ARES V plume and its impingement characteristics on the B-2 flame-deflector. The location, size and shape of the impingement region were quantified along with the un-cooled deflector wall pressures, temperatures and incident heating rates. Issues with the proposed tests were identified and several of these addressed using the CFD methodology. The final results of this modeling effort will provide useful data and boundary conditions in upcoming engineering studies that are directed towards determining the required facility modifications for ensuring safe and reliable stage testing in support of the Constellation Program.

Correction factors for on-line microprobe analysis of multielement alloy systems

NASA Technical Reports Server (NTRS)

Unnam, J.; Tenney, D. R.; Brewer, W. D.

1977-01-01

An on-line correction technique was developed for the conversion of electron probe X-ray intensities into concentrations of emitting elements. This technique consisted of off-line calculation and representation of binary interaction data which were read into an on-line minicomputer to calculate variable correction coefficients. These coefficients were used to correct the X-ray data without significantly increasing computer core requirements. The binary interaction data were obtained by running Colby's MAGIC 4 program in the reverse mode. The data for each binary interaction were represented by polynomial coefficients obtained by least-squares fitting a third-order polynomial. Polynomial coefficients were generated for most of the common binary interactions at different accelerating potentials and are included. Results are presented for the analyses of several alloy standards to demonstrate the applicability of this correction procedure.

Game meat authentication through rare earth elements fingerprinting.

PubMed

Danezis, G P; Pappas, A C; Zoidis, E; Papadomichelakis, G; Hadjigeorgiou, I; Zhang, P; Brusic, V; Georgiou, C A

2017-10-23

Accurate labelling of meat (e.g. wild versus farmed, geographical and genetic origin, organic versus conventional, processing treatment) is important to inform the consumers about the products they buy. Meat and meat products declared as game have higher commercial value making them target to fraudulent labelling practices and replacement with non-game meat. We have developed and validated a new method for authentication of wild rabbit meat using elemental metabolomics approach. Elemental analysis was performed using rapid ultra-trace multi-element measurement by inductively coupled plasma mass spectrometry (ICP-MS). Elemental signatures showed excellent ability to discriminate the wild rabbit from non-wild rabbit meat. Our results demonstrate the usefulness of metabolic markers -rare earth signatures, as well as other trace element signatures for game meat authentication. Copyright © 2017 Elsevier B.V. All rights reserved.

A Guided Wave Sensor Enabling Simultaneous Wavenumber-Frequency Analysis for Both Lamb and Shear-Horizontal Waves.

PubMed

Ren, Baiyang; Cho, Hwanjeong; Lissenden, Cliff J

2017-03-01

Guided waves in plate-like structures have been widely investigated for structural health monitoring. Lamb waves and shear horizontal (SH) waves, two commonly used types of waves in plates, provide different benefits for the detection of various types of defects and material degradation. However, there are few sensors that can detect both Lamb and SH waves and also resolve their modal content, namely the wavenumber-frequency spectrum. A sensor that can detect both waves is desirable to take full advantage of both types of waves in order to improve sensitivity to different discontinuity geometries. We demonstrate that polyvinylidene difluoride (PVDF) film provides the basis for a multi-element array sensor that detects both Lamb and SH waves and also measures their modal content, i.e., the wavenumber-frequency spectrum.

[Principal component analysis and cluster analysis of inorganic elements in sea cucumber Apostichopus japonicus].

PubMed

Liu, Xiao-Fang; Xue, Chang-Hu; Wang, Yu-Ming; Li, Zhao-Jie; Xue, Yong; Xu, Jie

2011-11-01

The present study is to investigate the feasibility of multi-elements analysis in determination of the geographical origin of sea cucumber Apostichopus japonicus, and to make choice of the effective tracers in sea cucumber Apostichopus japonicus geographical origin assessment. The content of the elements such as Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Cd, Hg and Pb in sea cucumber Apostichopus japonicus samples from seven places of geographical origin were determined by means of ICP-MS. The results were used for the development of elements database. Cluster analysis(CA) and principal component analysis (PCA) were applied to differentiate the sea cucumber Apostichopus japonicus geographical origin. Three principal components which accounted for over 89% of the total variance were extracted from the standardized data. The results of Q-type cluster analysis showed that the 26 samples could be clustered reasonably into five groups, the classification results were significantly associated with the marine distribution of the sea cucumber Apostichopus japonicus samples. The CA and PCA were the effective methods for elements analysis of sea cucumber Apostichopus japonicus samples. The content of the mineral elements in sea cucumber Apostichopus japonicus samples was good chemical descriptors for differentiating their geographical origins.

[Rapid multi-elemental analysis on four precious Tibetan medicines based on LIBS technique].

PubMed

Liu, Xiao-na; Shi, Xin-yuan; Jia, Shuai-yun; Zhao, Na; Wu, Zhi-sheng; Qiao, Yan-jiang

2015-06-01

The laser-induced breakdown spectroscopy (LIBS) was applied to perform a qualitative elementary analysis on four precious Tibetan medicines, i. e. Renqing Mangjue, Renqing Changjue, 25-herb coral pills and 25-herb pearl pills. The specific spectra of the four Tibetan medicines were established. In the experiment, Nd: YAG and 1 064 nm-baseband pulse laser were adopted to collect the spectra. A laser beam focused on the surface of the samples to generate plasma. Its spectral signal was detected by using spectrograph. Based on the National Institute of Standard and Technology (NIST) database, LIBS spectral lines were indentified. The four Tibetan medicines mainly included Ca, Na, K, Mg and other elements and C-N molecular band. Specifically, Fe was detected in Renqing Changjue and 25-herb pearl pills; heavy mental elements Hg and Cu were shown in Renqing Mangjue and Renqing Changjue; Ag was found in Renqing Changjue. The results demonstrated that LIBS is a reliable and rapid multi-element analysis on the four Tibetan medicines. With Real-time, rapid and nondestructive advantages, LIBS has a wide application prospect in the element analysis on ethnic medicines.

Multiple-element semiquantitative analysis of one-milligram geochemical samples by D.C. arc emission spectrography

USGS Publications Warehouse

Rait, N.

1981-01-01

A modified method is described for a 1-mg sample multi-element semiquantitative spectrographic analysis. This method uses a direct-current arc source, carbon instead of graphite electrodes, and an 80% argon-20% oxygen atmosphere instead of air. Although this is a destructive method, an analysis can be made for 68 elements in all mineral and geochemical samples. Carbon electrodes have been an aid in improving the detection limits of many elements. The carbon has a greater resistance to heat conductance and develops a better tip, facilitating sample volatilization and counter balancing the cooling effect of a flow of the argon-oxygen mixture around the anode. Where such an argon-oxygen atmosphere is used instead of air, the cyanogen band lines are greatly diminished in intensity, and thus more spectral lines of analysis elements are available for use; the spectral background is also lower. The main advantage of using the carbon electrode and the 80% argon-20% oxygen atmosphere is the improved detection limits of 36 out of 68 elements. The detection limits remain the same for 23 elements, and are not as good for only nine elements. ?? 1981.

Evaluating the Effects of Traffic on Driver Stopping and Turn Signal Use at a Stop Sign: A Systematic Replication

ERIC Educational Resources Information Center

Lebbon, Angela R.; Austin, John; Van Houten, Ron; Malenfant, Louis E.

2007-01-01

The current analyses of observational data found that oncoming traffic substantially affected driver stopping patterns and turn signal use at the target stop sign. The percentage of legal stops and turn signal use by drivers in the presence and absence of traffic was analyzed using a multi-element design. The results showed that legal stops were…

Multi-Channel Electronically Scanned Cryogenic Pressure Sensor And Method For Making Same

NASA Technical Reports Server (NTRS)

Chapman, John J. (Inventor); Hopson, Purnell, Jr. (Inventor); Holloway, Nancy M. (Inventor)

2001-01-01

A miniature, multi-channel, electronically scanned pressure measuring device uses electrostatically bonded silicon dies in a multi-element array. These dies are bonded at specific sites on a glass, pre-patterned substrate. Thermal data is multiplexed and recorded on each individual pressure measuring diaphragm. The device functions in a cryogenic environment without the need of heaters to keep the sensor at constant temperatures.

The Use of an Academic Discipline Model in Budgeting the State University of New York. New York Case Studies in Public Management, No. 2.

ERIC Educational Resources Information Center

Cockey, Caroline

This report examines New York State's experience with multi-element formulas in budgeting for the State University of New York, and considers some of the obstacles confronting scientific budgeting in a political environment. A specific budgeting formula (the Academic Discipline Model) is examined, its evolution and application discussed, and the…

Selection and Storage of Perceptual Groups Is Constrained by a Discrete Resource in Working Memory

ERIC Educational Resources Information Center

Anderson, David E.; Vogel, Edward K.; Awh, Edward

2013-01-01

Perceptual grouping can lead observers to perceive a multielement scene as a smaller number of hierarchical units. Past work has shown that grouping enables more elements to be stored in visual working memory (WM). Although this may appear to contradict so-called discrete resource models that argue for fixed item limits in WM storage, it is also…

Electrochemical sensor/detector system and method

DOEpatents

Glass, Robert S.; Perone, Sam P.; Ciarlo, Dino R.; Kimmons, James F.

1992-01-01

An electrochemical detection system is described comprising in combination: (a) a multielement, microelectrode array detector containing means for acquiring a plurality of signals; (b) electronic means for receiving said signals and converting said signals into a readout or display providing information with respect to the nature and concentration of elements present in a solution being tested. Also described is the means of making the above described microelectrode detector.

Electrochemical sensor/detector system and method

DOEpatents

Glass, Robert S.; Perone, Sam P.; Ciarlo, Dino R.; Kimmons, James F.

1994-01-01

An electrochemical detection system is described comprising in combination: (a) a multielement, microelectrode array detector containing means for acquiring a plurality of signals; (b) electronic means for receiving said signals and converting said signals into a readout or display providing information with respect to the nature and concentration of elements present in a solution being tested. Also described is the means of making the above described microelectrode detector.

Results from a Prototype Multi-Element CdZnTe Gamma-Ray Detector for Planetary Missions

NASA Technical Reports Server (NTRS)

Moss, C. E.; Browne, M. C.; Ianakiev, K. D.; Prettyman, T. H.; Reedy, R. C.

2001-01-01

We present high energy results for a 2 x 2 x 2 array of eight 10 mm x 10 mm x 5 mm coplanar grid CdZnTe detectors. We conclude that such an array can provide a room-temperature detector with good resolution and efficiency for planetary missions. Additional information is contained in the original extended abstract.

Acoustic tests of augmentor wing model

NASA Technical Reports Server (NTRS)

Goodykoontz, J. H.

1977-01-01

Acoustic and aerodynamic data were obtained for a full-scale section of an augmentor wing. Features of the design included a single-row, multielement nozzle array and acoustically tuned panels placed on the interior surfaces of the augmentor. When the data were extrapolated to a 91,000-kilogram aircraft, the calculated sideline perceived noise levels were approximately the same for either the takeoff or approach condition.

Development of an accurate, sensitive, and robust isotope dilution laser ablation ICP-MS method for simultaneous multi-element analysis (chlorine, sulfur, and heavy metals) in coal samples.

PubMed

Boulyga, Sergei F; Heilmann, Jens; Prohaska, Thomas; Heumann, Klaus G

2007-10-01

A method for the direct multi-element determination of Cl, S, Hg, Pb, Cd, U, Br, Cr, Cu, Fe, and Zn in powdered coal samples has been developed by applying inductively coupled plasma isotope dilution mass spectrometry (ICP-IDMS) with laser-assisted introduction into the plasma. A sector-field ICP-MS with a mass resolution of 4,000 and a high-ablation rate laser ablation system provided significantly better sensitivity, detection limits, and accuracy compared to a conventional laser ablation system coupled with a quadrupole ICP-MS. The sensitivity ranges from about 590 cps for (35)Cl+ to more than 6 x 10(5) cps for (238)U+ for 1 microg of trace element per gram of coal sample. Detection limits vary from 450 ng g(-1) for chlorine and 18 ng g(-1) for sulfur to 9.5 pg g(-1) for mercury and 0.3 pg g(-1) for uranium. Analyses of minor and trace elements in four certified reference materials (BCR-180 Gas Coal, BCR-331 Steam Coal, SRM 1632c Trace Elements in Coal, SRM 1635 Trace Elements in Coal) yielded good agreement of usually not more than 5% deviation from the certified values and precisions of less than 10% relative standard deviation for most elements. Higher relative standard deviations were found for particular elements such as Hg and Cd caused by inhomogeneities due to associations of these elements within micro-inclusions in coal which was demonstrated for Hg in SRM 1635, SRM 1632c, and another standard reference material (SRM 2682b, Sulfur and Mercury in Coal). The developed LA-ICP-IDMS method with its simple sample pretreatment opens the possibility for accurate, fast, and highly sensitive determinations of environmentally critical contaminants in coal as well as of trace impurities in similar sample materials like graphite powder and activated charcoal on a routine basis.

Flow velocity profiling using acoustic time of flight flow metering based on wide band signals and adaptive beam-forming techniques

NASA Astrophysics Data System (ADS)

Murgan, I.; Candel, I.; Ioana, C.; Digulescu, A.; Bunea, F.; Ciocan, G. D.; Anghel, A.; Vasile, G.

2016-11-01

In this paper, we present a novel approach to non-intrusive flow velocity profiling technique using multi-element sensor array and wide-band signal's processing methods. Conventional techniques for the measurements of the flow velocity profiles are usually based on intrusive instruments (current meters, acoustic Doppler profilers, Pitot tubes, etc.) that take punctual velocity readings. Although very efficient, these choices are limited in terms of practical cases of applications especially when non-intrusive measurements techniques are required and/or a spatial accuracy of the velocity profiling is required This is due to factors related to hydraulic machinery down time, the often long time duration needed to explore the entire section area, the frequent cumbersome number of devices that needs to be handled simultaneously, or the impossibility to perform intrusive tests. In the case of non-intrusive flow profiling methods based on acoustic techniques, previous methods concentrated on using a large number of acoustic transducers placed around the measured section. Although feasible, this approach presents several major drawbacks such as a complicated signal timing, transmission, acquisition and recording system, resulting in a relative high cost of operation. In addition, because of the geometrical constraints, a desired number of sensors may not be installed. Recent results in acoustic flow metering based on wide band signals and adaptive beamforming proved that it is possible to achieve flow velocity profiles using less acoustic transducers. In a normal acoustic time of flight path the transducers are both emitters and receivers, sequentially changing their roles. In the new configuration, proposed in this paper, two new receivers are added on each side. Since the beam angles of each acoustic transducer are wide enough the newly added transducers can receive the transmitted signals and additional time of flight estimation can be done. Thus, several flow velocities are possible to be computed. Analytically defined emitted wide band signals makes possible the identification of signals coming from each transducer. Using the adaptive beam-forming algorithm the receiving transducers can record different signals from the receiver, equivalent to different propagation paths. Therefore, different measurements of time of flight are possible, leading to additional flow velocity measurements. Results carried out in an experiment facility belonging to ICPE-CA, Bucharest - Romania allowed to the validation of the flow velocities computed using this new technique, in symmetric, asymmetric and uneven flow conditions. The acoustic derived values were referenced with those provided from a Pitot tube probe installed in the test channel and the results obtained by the method proposed in this paper are relatively close to this reference.

Frequency control using a complex effective reflectivity in laterally coupled semiconductor laser arrays.

PubMed

Griffel, G; Marshall, W K; Gravé, I; Yariv, A; Nabiev, R

1991-08-01

Frequency selectivity of a novel type of multielement, multisection laterally coupled semiconductor laser array is studied using the round-trip method. It is found that such a structure should lead to a strong frequency selectivity owing to a periodic dependency of the threshold gain on the frequency. A gain-guided two-coupledcavity device was fabricated. The experimental results show excellent agreement with the theoretical prediction.

The Influence of Viscous Effects on Ice Accretion Prediction and Airfoil Performance Predictions

NASA Technical Reports Server (NTRS)

Kreeger, Richard E.; Wright, William B.

2005-01-01

A computational study was conducted to evaluate the effectiveness of using a viscous flow solution in an ice accretion code and the resulting accuracy of aerodynamic performance prediction. Ice shapes were obtained for one single-element and one multi-element airfoil using both potential flow and Navier-Stokes flowfields in the LEWICE ice accretion code. Aerodynamics were then calculated using a Navier-Stokes flow solver.

Multi-Element Free-Space Optical (FSO) Modules for Mobile-Opportunistic Networking

DTIC Science & Technology

2016-11-14

will enable us to improve our existing FSO prototype modules to low power consuming, miniature devices with high data transfer rates. Particularly, we... wireless spectrum bands in both military and civilian settings. Recent research has shown that free- space-optical (FSO), a.k.a. optical wireless ...communications is a promising complementary approach to address the exploding mobile wireless traffic demand. The major impediment for using FSO in a

Methodology Plan for Minimum Resolvable Temperature Difference (MRTD) Testing of Aircraft Installed Sensors

DTIC Science & Technology

2011-03-23

sensors (e.g., sensor fusion) or use different detector materials to increase spectral bands into the Near IR (NIR). 3. Holst2provides an...a. Detector type: Multi-element MCT SPRITE b. Wavelength: Long wave, 8-12 um c. Cooling system: Integrated Sterling cooler d. Cooldown...A-1 B. COLLIMATOR SYSTEM DESIGN AND EO/ IR TOPICS ................ B-1 C. ATTC FACILITIES AND INSTRUMENTATION

Comparing Acquisition of AAC-Based Mands in Three Young Children with Autism Spectrum Disorder Using iPad® Applications with Different Display and Design Elements

ERIC Educational Resources Information Center

Gevarter, Cindy; O'Reilly, Mark F.; Rojeski, Laura; Sammarco, Nicolette; Sigafoos, Jeff; Lancioni, Giulio E.; Lang, Russell

2014-01-01

Augmentative and alternative communication (AAC) applications may differ in their use of display and design elements. Using a multielement design, this study compared mand acquisition in three preschool-aged males with autism spectrum disorder, across three different displays in two iPad® AAC applications. Displays included a Widgit symbol button…

A Multi-Element Ultrasonic Ranging Array

DTIC Science & Technology

1985-01-01

of local tehiperature, in degrees Rankine (degrees Farenheit + 460 degrees). At 70 degrees F: c = 49.018 V ^60 + 70 = 1128 ft/sec At 30 degrees F...the RS-232. When acknowledged, the ranges sre sequentially dumped out the serial interface and placed by the Scheduler in Page Zero indexed storage...served, such as collision avoidance or object tracking, where absolute accuracies are not as important as is relative information

The Effect of Orthographic Depth on Letter String Processing: The Case of Visual Attention Span and Rapid Automatized Naming

ERIC Educational Resources Information Center

Antzaka, Alexia; Martin, Clara; Caffarra, Sendy; Schlöffel, Sophie; Carreiras, Manuel; Lallier, Marie

2018-01-01

The present study investigated whether orthographic depth can increase the bias towards multi-letter processing in two reading-related skills: visual attention span (VAS) and rapid automatized naming (RAN). VAS (i.e., the number of visual elements that can be processed at once in a multi-element array) was tested with a visual 1-back task and RAN…

Large Eddy Simulations of Transverse Combustion Instability in a Multi-Element Injector

DTIC Science & Technology

2016-07-27

plagued the development of liquid rocket engines and remains a large riskin the development and acquisition of new liquid rocket engines. Combustion...simulations to better understand the physics that can lead combustion instability in liquid rocket engines. Simulations of this type are able to...instabilities found in liquid rocket engines are transverse. The motivating of the experiment behind the current work is to subject the CVRC injector

A guided wave sensor enabling simultaneous wavenumber-frequency analysis for both lamb and shear-horizontal waves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ren, Baiyang; Cho, Hwanjeong; Lissenden, Cliff J.

Guided waves in plate-like structures have been widely investigated for structural health monitoring. Lamb waves and shear horizontal (SH) waves, two commonly used types of waves in plates, provide different benefits for the detection of various types of defects and material degradation. However, there are few sensors that can detect both Lamb and SH waves and also resolve their modal content, namely the wavenumber-frequency spectrum. A sensor that can detect both waves is desirable to take full advantage of both types of waves in order to improve sensitivity to different discontinuity geometries. As a result, we demonstrate that polyvinylidene difluoridemore » (PVDF) film provides the basis for a multi-element array sensor that detects both Lamb and SH waves and also measures their modal content, i.e., the wavenumber-frequency spectrum.« less

A unique measurement technique to study laminar-separation bubble characteristics on an airfoil

NASA Technical Reports Server (NTRS)

Stack, J. P.; Mangalam, S. M.; Berry, S. A.

1987-01-01

A 'nonintrusive', multielement heat-transfer sensor was designed to study laminar-separation bubble characteristics on a NASA LRN (1)-1010 low-Reynolds number airfoil. The sensor consists of 30 individual nickel films, vacuum-deposited on a thin substrate (0.05 mm) that was bonded to the airfoil model with the sensor array placed streamwise on the airfoil upper surface. Experiments were conducted on a 15-cm chord model in the 50,000-300,000 chord Reynolds number range. Time history as well as spectral analysis of signals from surface film gauges were simultaneously obtained to determine the location of laminar separation and the subsequent behavior of the separated shear layer. In addition to the successful determination of laminar separation, a new phenomenon involving a large phase shift in dynamic shear stresses across the separation and reattachment points was observed.

A guided wave sensor enabling simultaneous wavenumber-frequency analysis for both lamb and shear-horizontal waves

DOE PAGES

Ren, Baiyang; Cho, Hwanjeong; Lissenden, Cliff J.

2017-03-01

Guided waves in plate-like structures have been widely investigated for structural health monitoring. Lamb waves and shear horizontal (SH) waves, two commonly used types of waves in plates, provide different benefits for the detection of various types of defects and material degradation. However, there are few sensors that can detect both Lamb and SH waves and also resolve their modal content, namely the wavenumber-frequency spectrum. A sensor that can detect both waves is desirable to take full advantage of both types of waves in order to improve sensitivity to different discontinuity geometries. As a result, we demonstrate that polyvinylidene difluoridemore » (PVDF) film provides the basis for a multi-element array sensor that detects both Lamb and SH waves and also measures their modal content, i.e., the wavenumber-frequency spectrum.« less

The computation of induced drag with nonplanar and deformed wakes

NASA Technical Reports Server (NTRS)

Kroo, Ilan; Smith, Stephen

1991-01-01

The classical calculation of inviscid drag, based on far field flow properties, is reexamined with particular attention to the nonlinear effects of wake roll-up. Based on a detailed look at nonlinear, inviscid flow theory, it is concluded that many of the classical, linear results are more general than might have been expected. Departures from the linear theory are identified and design implications are discussed. Results include the following: Wake deformation has little effect on the induced drag of a single element wing, but introduces first order corrections to the induced drag of a multi-element lifting system. Far field Trefftz-plane analysis may be used to estimate the induced drag of lifting systems, even when wake roll-up is considered, but numerical difficulties arise. The implications of several other approximations made in lifting line theory are evaluated by comparison with more refined analyses.

Compact electrostatic beam optics for multi-element focused ion beams: simulation and experiments.

PubMed

Mathew, Jose V; Bhattacharjee, Sudeep

2011-01-01

Electrostatic beam optics for a multi-element focused ion beam (MEFIB) system comprising of a microwave multicusp plasma (ion) source is designed with the help of two widely known and commercially available beam simulation codes: AXCEL-INP and SIMION. The input parameters to the simulations are obtained from experiments carried out in the system. A single and a double Einzel lens system (ELS) with and without beam limiting apertures (S) have been investigated. For a 1 mm beam at the plasma electrode aperture, the rms emittance of the focused ion beam is found to reduce from ∼0.9 mm mrad for single ELS to ∼0.5 mm mrad for a double ELS, when S of 0.5 mm aperture size is employed. The emittance can be further improved to ∼0.1 mm mrad by maintaining S at ground potential, leading to reduction in beam spot size (∼10 μm). The double ELS design is optimized for different electrode geometrical parameters with tolerances of ±1 mm in electrode thickness, electrode aperture, inter electrode distance, and ±1° in electrode angle, providing a robust design. Experimental results obtained with the double ELS for the focused beam current and spot size, agree reasonably well with the simulations.

Design Methodology for Multi-Element High-Lift Systems on Subsonic Civil Transport Aircraft

NASA Technical Reports Server (NTRS)

Pepper, R. S.; vanDam, C. P.

1996-01-01

The choice of a high-lift system is crucial in the preliminary design process of a subsonic civil transport aircraft. Its purpose is to increase the allowable aircraft weight or decrease the aircraft's wing area for a given takeoff and landing performance. However, the implementation of a high-lift system into a design must be done carefully, for it can improve the aerodynamic performance of an aircraft but may also drastically increase the aircraft empty weight. If designed properly, a high-lift system can improve the cost effectiveness of an aircraft by increasing the payload weight for a given takeoff and landing performance. This is why the design methodology for a high-lift system should incorporate aerodynamic performance, weight, and cost. The airframe industry has experienced rapid technological growth in recent years which has led to significant advances in high-lift systems. For this reason many existing design methodologies have become obsolete since they are based on outdated low Reynolds number wind-tunnel data and can no longer accurately predict the aerodynamic characteristics or weight of current multi-element wings. Therefore, a new design methodology has been created that reflects current aerodynamic, weight, and cost data and provides enough flexibility to allow incorporation of new data when it becomes available.

Almost equivalence of combinatorial and distance processes for discrimination in multielement images.

PubMed

Ferraro, M; Foster, D H

1991-01-01

Under certain experimental conditions, visual discrimination performance in multielement images is closely related to visual identification performance: elements of the image are distinguished only insofar as they appear to have distinct, discrete, internal characterizations. This report is concerned with the detailed relationship between such internal characterizations and observable discrimination performance. Two types of general processes that might underline discrimination are considered. The first is based on computing all possible internal image characterizations that could allow a correct decision, each characterization weighted by the probability of its occurrence and of a correct decision being made. The second process is based on computing the difference between the probabilities associated with the internal characterizations of the individual image elements, the difference quantified naturally with an l(p) norm. The relationship between the two processes was investigated analytically and by Monte Carlo simulations over a plausible range of numbers n of the internal characterizations of each of the m elements in the image. The predictions of the two processes were found to be closely similar. The relationship was precisely one-to-one, however, only for n = 2, m = 3, 4, 6, and for n greater than 2, m = 3, 4, p = 2. For all other cases tested, a one-to-one relationship was shown to be impossible.

A competitive interaction theory of attentional selection and decision making in brief, multielement displays.

PubMed

Smith, Philip L; Sewell, David K

2013-07-01

We generalize the integrated system model of Smith and Ratcliff (2009) to obtain a new theory of attentional selection in brief, multielement visual displays. The theory proposes that attentional selection occurs via competitive interactions among detectors that signal the presence of task-relevant features at particular display locations. The outcome of the competition, together with attention, determines which stimuli are selected into visual short-term memory (VSTM). Decisions about the contents of VSTM are made by a diffusion-process decision stage. The selection process is modeled by coupled systems of shunting equations, which perform gated where-on-what pathway VSTM selection. The theory provides a computational account of key findings from attention tasks with near-threshold stimuli. These are (a) the success of the MAX model of visual search and spatial cuing, (b) the distractor homogeneity effect, (c) the double-target detection deficit, (d) redundancy costs in the post-stimulus probe task, (e) the joint item and information capacity limits of VSTM, and (f) the object-based nature of attentional selection. We argue that these phenomena are all manifestations of an underlying competitive VSTM selection process, which arise as a natural consequence of our theory. PsycINFO Database Record (c) 2013 APA, all rights reserved.

High-Lift Optimization Design Using Neural Networks on a Multi-Element Airfoil

NASA Technical Reports Server (NTRS)

Greenman, Roxana M.; Roth, Karlin R.; Smith, Charles A. (Technical Monitor)

1998-01-01

The high-lift performance of a multi-element airfoil was optimized by using neural-net predictions that were trained using a computational data set. The numerical data was generated using a two-dimensional, incompressible, Navier-Stokes algorithm with the Spalart-Allmaras turbulence model. Because it is difficult to predict maximum lift for high-lift systems, an empirically-based maximum lift criteria was used in this study to determine both the maximum lift and the angle at which it occurs. Multiple input, single output networks were trained using the NASA Ames variation of the Levenberg-Marquardt algorithm for each of the aerodynamic coefficients (lift, drag, and moment). The artificial neural networks were integrated with a gradient-based optimizer. Using independent numerical simulations and experimental data for this high-lift configuration, it was shown that this design process successfully optimized flap deflection, gap, overlap, and angle of attack to maximize lift. Once the neural networks were trained and integrated with the optimizer, minimal additional computer resources were required to perform optimization runs with different initial conditions and parameters. Applying the neural networks within the high-lift rigging optimization process reduced the amount of computational time and resources by 83% compared with traditional gradient-based optimization procedures for multiple optimization runs.

Numerical study to assess sulfur hexafluoride as a medium for testing multielement airfoils

NASA Technical Reports Server (NTRS)

Bonhaus, Daryl L.; Anderson, W. Kyle; Mavriplis, Dimitri J.

1995-01-01

A methodology is described for computing viscous flows of air and sulfur hexafluoride (SF6). The basis is an existing flow solver that calculates turbulent flows in two dimensions on unstructured triangular meshes. The solver has been modified to incorporate the thermodynamic model for SF6 and used to calculate the viscous flow over two multielement airfoils that have been tested in a wind tunnel with air as the test medium. Flows of both air and SF6 at a free-stream Mach number of 0.2 and a Reynolds number of 9 x 10(exp 6) are computed for a range of angles of attack corresponding to the wind-tunnel test. The computations are used to investigate the suitability of SF6 as a test medium in wind tunnels and are a follow-on to previous computations for single-element airfoils. Surface-pressure, lift, and drag coefficients are compared with experimental data. The effects of heavy gas on the details of the flow are investigated based on computed boundary-layer and skin-friction data. In general, the predictions in SF6 vary little from those in air. Within the limitations of the computational method, the results presented are sufficiently encouraging to warrant further experiments.

Trace-element characterization of evidential cannabis sative samples using k{sub 0}-standardization methodology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henderson, D.P. Jr.; Vernetson, W.G.; Ratner, R.T.

The University of Florida Training Reactor (UFTR) facilities including the analytical laboratory are used for a wide range of educational, research, training, and service functions. The UFTR is a 100-kW light-water-cooled, graphite-and-water-moderated modified Argonaut-type reactor. The UFTR utilizes high enriched plate-type fuel in a two-slab arrangement and operates at a 100-kW power level. Since first licensed to operate at 10 kW in 1959, this nonpower reactor facility has had an active but evolving record of continuous service to a wide range of academic, utility, and community users. The services of the UFTR have also been used by various state authoritiesmore » in criminal investigations. Because of its relatively low power and careful laboratory analyses, the UFTR neutron flux characteristics in several ports are not only well characterized but they are also quite invariant with time. As a result, such a facility is well-suited to the application of the multielement analysis using the k{sub o}-standardization method of neutron activation analysis. The analysis of untreated evidential botanical samples presented a unique opportunity to demonstrate implementation of this method at the UFTR facilities.« less

Analysis of the effect of mobile phone base station antenna loading on localized SAR and its consequences for measurements.

PubMed

Hansson, Björn; Thors, Björn; Törnevik, Christer

2011-12-01

In this work, the effect of antenna element loading on the localized specific absorption rate (SAR) has been analyzed for base station antennas. The analysis was conducted in order to determine whether localized SAR measurements of large multi-element base station antennas can be conducted using standardized procedures and commercially available equipment. More specifically, it was investigated if the antenna shifting measurement procedure, specified in the European base station exposure assessment standard EN 50383, will produce accurate localized SAR results for base station antennas larger than the specified measurement phantom. The obtained results show that SAR accuracy is affected by the presence of lossy material within distances of one wavelength from the tested antennas as a consequence of coupling and redistribution of transmitted power among the antenna elements. It was also found that the existing standardized phantom is not optimal for SAR measurements of large base station antennas. A new methodology is instead proposed based on a larger, box-shaped, whole-body phantom. Copyright © 2011 Wiley Periodicals, Inc.

Characterization and Analyses of Valves, Feed Lines and Tanks used in Propellant Delivery Systems at NASA SSC

NASA Technical Reports Server (NTRS)

Ryan, Harry M.; Coote, David J.; Ahuja, Vineet; Hosangadi, Ashvin

2006-01-01

Accurate modeling of liquid rocket engine test processes involves assessing critical fluid mechanic and heat and mass transfer mechanisms within a cryogenic environment, and accurately modeling fluid properties such as vapor pressure and liquid and gas densities as a function of pressure and temperature. The Engineering and Science Directorate at the NASA John C. Stennis Space Center has developed and implemented such analytic models and analysis processes that have been used over a broad range of thermodynamic systems and resulted in substantial improvements in rocket propulsion testing services. In this paper, we offer an overview of the analyses techniques used to simulate pressurization and propellant fluid systems associated with the test stands at the NASA John C. Stennis Space Center. More specifically, examples of the global performance (one-dimensional) of a propellant system are provided as predicted using the Rocket Propulsion Test Analysis (RPTA) model. Computational fluid dynamic (CFD) analyses utilizing multi-element, unstructured, moving grid capability of complex cryogenic feed ducts, transient valve operation, and pressurization and mixing in propellant tanks are provided as well.

A comparison of a modified sequential oral sensory approach to an applied behavior-analytic approach in the treatment of food selectivity in children with autism spectrum disorder.

PubMed

Peterson, Kathryn M; Piazza, Cathleen C; Volkert, Valerie M

2016-09-01

Treatments of pediatric feeding disorders based on applied behavior analysis (ABA) have the most empirical support in the research literature (Volkert & Piazza, 2012); however, professionals often recommend, and caregivers often use, treatments that have limited empirical support. In the current investigation, we compared a modified sequential oral sensory approach (M-SOS; Benson, Parke, Gannon, & Muñoz, 2013) to an ABA approach for the treatment of the food selectivity of 6 children with autism. We randomly assigned 3 children to ABA and 3 children to M-SOS and compared the effects of treatment in a multiple baseline design across novel, healthy target foods. We used a multielement design to assess treatment generalization. Consumption of target foods increased for children who received ABA, but not for children who received M-SOS. We subsequently implemented ABA with the children for whom M-SOS was not effective and observed a potential treatment generalization effect during ABA when M-SOS preceded ABA. © 2016 Society for the Experimental Analysis of Behavior.

Analysis of SMELS and reference materials for validation of the k0-based internal monostandard NAA method using in-situ detection efficiency

NASA Astrophysics Data System (ADS)

Acharya, R.; Swain, K. K.; Reddy, A. V. R.

2010-10-01

Three synthetic multielement standards (SMELS I, II and III) and two reference materials (RMs), SL-3 and Soil-7 of IAEA were analyzed for validation of the k0-based internal monostandard neutron activation analysis (IM-NAA) method utilizing in-situ relative detection efficiency. The internal monostandards used in SMELS and RMs were Au and Sc, respectively. The samples were irradiated in Apsara and Dhruva reactors, BARC and radioactive assay was carried out using a 40% relative efficiency HPGe detector coupled to an 8 k MCA. Concentrations of 23 elements were determined in both SMELS and RMs. In the case of RMs, concentrations of a few elements, whose certified values are not available, could also be determined. The % deviations for the elements determined in SMELS with respect to the assigned values and RMs with respect to certified values were within ±8%. The Z-score values at 95% confidence level for most of the elements in both the materials were within ±1.

Multi-element analysis of water decoction of medicine food homology plants using inductively coupled plasma-tandem mass spectrometry

NASA Astrophysics Data System (ADS)

Fu, Liang; Shi, Shu-Yun; Chen, Xiao-Qing

2017-07-01

The concentration of twelve trace elements in the water decoction of medicine food homology plants (MFHP) was determined by inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS). Water decoctions of MFHP were analyzed directly using the MS/MS mode after acidification by 1% (v/v) nitric acid. The polyatomic interferences were eliminated by oxygen mass shift, oxygen on-mass, and ammonia mass shift. The accuracy of the method was verified by analysis of standard reference materials. This method was utilized to investigate the water decoction composition of 16 common Chinese MFHPs. The trace elements in the water decoctions of different MFHPs presented significantly different dissolution ratios. The dissolution ratio of V was the lowest (4.21%-14.86%), whereas Zn showed the highest dissolution ratio (24.87%-86.80%). In addition, the dissolution ratio of heavy metallic elements in most MFHP was equal to or was lower than 30%. Therefore, consumption of MHFP decoction could decrease the heavy metal intake associated with MFHP use and reduce the risk of heavy metal poisoning.

Reconnaissance exploration geochemistry in the central Brooks Range, northern Alaska: Implications for exploration of sediment-hosted zinc-lead-silver deposits

USGS Publications Warehouse

Kelley, K.D.; Kelley, D.L.

1992-01-01

A reconnaissance geochemical survey was conducted in the southern Killik River quadrangle, central Brooks Range, northern Alaska. The Brooks Range lies within the zone of continuous permafrost which may partially inhibit chemical weathering and oxidation. The minus 30-mesh and nonmagnetic heavy-mineral concentrate fractions of sediment samples were chosen as the sample media for the survey so that mechanical rather than chemical dispersion patterns would be enhanced. A total of 263 sites were sampled within the southern half of the Killik River quadrangle at an average sample density of approximately one sample per 12 km2. All samples were submitted for multi-element analyses. In the western and central Brooks Range, several known sediment-hosted Zn-Pb-Ag(-Ba) deposits occur within a belt of Paleozoic rocks of the Endicott Mountains allochthon. Exploration for this type of deposit in the Brook Range is difficult, due to the inherently high background values for Ba, Zn and Pb in shale and the common occurrence of metamorphic quartz-calcite veins, many of which contain traces of sulfide minerals. Stream sediments derived from these sources produce numerous geochemical anomalies which are not necessarily associated with significant mineralization. R-mode factor analysis provides a means of distinguishing between element associations related to lithology and those related to possible mineralization. Factor analysis applied to the multi-element data from the southern Killik River quadrangle resulted in the discovery of two additional Zn-Pb-Ag mineral occurrences of considerable areal extent which are 80-100 km east of any previously known deposit. These have been informally named the Kady and Vidlee. Several lithogeochemical element associations, or factors, and three factors which represent sulfide mineralization were identified: Ag-Pb-Zn (galena and sphalerite) and Fe-Ni-Co-Cu (pyrite ?? chalcopyrite) in the concentrate samples and Cd-Zn-Pb-As-Mn in the sediment samples. The distribution of high scores for each individual mineralization factor outlined several relatively large (200-250 km2) geochemically favorable areas. When the distribution of high scores for all three factors were superimposed, samples characterized by high scores for one or both of the concentrate mineralization factors and the mineralization factor in sediments define basin areas of approximately 48 and 64 km2 surrounding Kady and Vidlee, respectively. ?? 1992.

Blind-type optical configuration for the high heat solar collectors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vasilyev, V.P.

1996-12-31

Blind approach in constructing high heat solar collectors with the one-stage light flux concentration is presented. Shown are diverse multielement optical configurations that can be built on the basis of a blind-type concept. Their two main versions using the set of concave parabolic reflecting elements are described. A preliminary estimation of the flux concentration level for a circle-blind collector shows it reaching up to half of the thermodynamic limit.

Minimum accommodation for aerobrake assembly, phase 2

NASA Technical Reports Server (NTRS)

Katzberg, Stephen J.; Haynes, Davy A.; Tutterow, Robin D.; Watson, Judith J.; Russell, James W.

1994-01-01

A multi-element study was done to assess the practicality of a Space Station Freedom-based aerobrake system for the Space Exploration Initiative. The study was organized into six parts related to structure, aerodynamics, robotics and assembly, thermal protection system, inspection, and verification, all tied together by an integration study. The integration activity managed the broad issues related to meeting mission requirements. This report is a summary of the issues addressed by the integration team.

PYTi-NiCr Signatures in the Columbia Hills are Present in Certain Martian Meteorites

NASA Technical Reports Server (NTRS)

Clark, B. C.; Gellert, R.; Ming, D. W.; Morris, R. V.; Mittlefehldt, D. W.; Squyres, S. W.

2006-01-01

Uniquely high levels of phosphorus and titanium were observed in several samples [1-3] by the APXS x-ray fluorescence measurements as the MER Spirit rover climbed Husband Hill (Columbia Hills, Gusev crater, Mars). A careful study of many such samples and their geochemical variability has revealed additional elements in this pattern, and that the derived multi-element signature is also unambiguously manifested in several martian meteorites.

Military Curricula for Vocational & Technical Education. Basic Electricity and Electronics. CANTRAC A-100-0010. Module 21: Basic Transistor Theory; Module 21T: Multi-Element Vacuum Tubes. Study Booklet.

ERIC Educational Resources Information Center

Chief of Naval Education and Training Support, Pensacola, FL.

This set of individualized learning modules on transistor theory is one in a series of modules for a course in basic electricity and electronics. The course is one of a number of military-developed curriculum packages selected for adaptation to vocational instructional and curriculum development in a civilian setting. Two modules are included in…

Supercritical Quasi-Conduction States in Stochastic Rayleigh-Benard Convection

DTIC Science & Technology

2011-09-15

is 10 (see table 1). The sensitivity (in the sense of Sobol [39]) of the integrated Nusselt number with respect to the amplitude of the boundary...using a multi-element quadrature formula [32]. Following Sobol [39], we shall define global sensitivity indices as the ratio between the variance of...39] I. M. Sobol , Global sensitivity indices for nonlinear mathematical models and their monte carlo estimates, Math. Comput. Simul. 55 (2001) 271

Summer Research Program (1992). Summer Faculty Research Program (SFRP) Reports. Volume 2. Armstrong Laboratory

DTIC Science & Technology

1992-12-01

desirable. In this study, the proposed model consists of a thick-walled, highly deformable elastic tube in which the blood flow is described by linearized ...presented a mechanical model consisting of linearized Navier-Stokes and finite elasticity equations to predict blood pooling under acceleration stress... linear multielement model of the cardiovascular system which can calculate blood pressures and flows at any point in the cardio- vascular system. It

Detection and quantitative determination of heavy metals in electronic cigarette refill liquids using Total Reflection X-ray Fluorescence Spectrometry.

PubMed

Kamilari, Eleni; Farsalinos, Konstantinos; Poulas, Konstantinos; Kontoyannis, Christos G; Orkoula, Malvina G

2018-06-01

Electronic cigarettes are considered healthier alternatives to conventional cigarettes containing tobacco. They produce vapor through heating of the refill liquids (e-liquids) which consist of propylene glycol, vegetable glycerin, nicotine (in various concentrations), water and flavoring agents. Heavy metals may enter the refill liquid during the production, posing a risk for consumer's health due to their toxicity. The objective of the present study was the development of a methodology for the detection and quantitative analysis of cadmium (Cd), lead (Pb), nickel (Ni), copper (Cu), arsenic (As) and chromium (Cr), employing Total Reflection X-Ray Fluorescence Spectroscopy (TXRF) as an alternative technique to ICP-MS or ICP-OES commonly used for this type of analysis. TXRF was chosen due to its advantages, which include short analysis time, promptness, simultaneous multi-element analysis capability and minimum sample preparation, low purchase and operational cost. The proposed methodology was applied to a large number of electronic cigarette liquids commercially available, as well as their constituents, in order to evaluate their safety. TXRF may be a valuable tool for probing heavy metals in electronic cigarette refill liquids to serve for the protection of human health. Copyright © 2018 Elsevier Ltd. All rights reserved.

Experimental and computational investigation of lift-enhancing tabs on a multi-element airfoil

NASA Technical Reports Server (NTRS)

Ashby, Dale

1996-01-01

An experimental and computational investigation of the effect of lift enhancing tabs on a two-element airfoil was conducted. The objective of the study was to develop an understanding of the flow physics associated with lift enhancing tabs on a multi-element airfoil. A NACA 63(sub 2)-215 ModB airfoil with a 30 percent chord Fowler flap was tested in the NASA Ames 7 by 10 foot wind tunnel. Lift enhancing tabs of various heights were tested on both the main element and the flap for a variety of flap riggings. Computations of the flow over the two-element airfoil were performed using the two-dimensional incompressible Navier-Stokes code INS2D-UP. The computer results predict all of the trends in the experimental data quite well. When the flow over the flap upper surface is attached, tabs mounted at the main element trailing edge (cove tabs) produce very little change in lift. At high flap deflections. however, the flow over the flap is separated and cove tabs produce large increases in lift and corresponding reductions in drag by eliminating the separated flow. Cove tabs permit high flap deflection angles to be achieved and reduce the sensitivity of the airfoil lift to the size of the flap gap. Tabs attached to the flap training edge (flap tabs) are effective at increasing lift without significantly increasing drag. A combination of a cove tab and a flap tab increased the airfoil lift coefficient by 11 percent relative to the highest lift tab coefficient achieved by any baseline configuration at an angle of attack of zero percent and the maximum lift coefficient was increased by more than 3 percent. A simple analytic model based on potential flow was developed to provide a more detailed understanding of how lift enhancing tabs work. The tabs were modeled by a point vortex at the training edge. Sensitivity relationships were derived which provide a mathematical basis for explaining the effects of lift enhancing tabs on a multi-element airfoil. Results of the modeling effort indicate that the dominant effects of the tabs on the pressure distribution of each element of the airfoil can be captured with a potential flow model for cases with no flow separation.

A new analytical approach to understanding nanoscale lead-iron interactions in drinking water distribution systems.

PubMed

Trueman, Benjamin F; Gagnon, Graham A

2016-07-05

High levels of iron in distributed drinking water often accompany elevated lead release from lead service lines and other plumbing. Lead-iron interactions in drinking water distribution systems are hypothesized to be the result of adsorption and transport of lead by iron oxide particles. This mechanism was explored using point-of-use drinking water samples characterized by size exclusion chromatography with UV and multi-element (ICP-MS) detection. In separations on two different stationary phases, high apparent molecular weight (>669 kDa) elution profiles for (56)Fe and (208)Pb were strongly correlated (average R(2)=0.96, N=73 samples representing 23 single-unit residences). Moreover, (56)Fe and (208)Pb peak areas exhibited an apparent linear dependence (R(2)=0.82), consistent with mobilization of lead via adsorption to colloidal particles rich in iron. A UV254 absorbance peak, coincident with high molecular weight (56)Fe and (208)Pb, implied that natural organic matter was interacting with the hypothesized colloidal species. High molecular weight UV254 peak areas were correlated with both (56)Fe and (208)Pb peak areas (R(2)=0.87 and 0.58, respectively). On average, 45% (std. dev. 10%) of total lead occurred in the size range 0.05-0.45 μm. Copyright © 2016 Elsevier B.V. All rights reserved.

Three-dimensional printed sample load/inject valves enabling online monitoring of extracellular calcium and zinc ions in living rat brains.

PubMed

Su, Cheng-Kuan; Hsia, Sheng-Chieh; Sun, Yuh-Chang

2014-08-01

We have developed a simple and low-cost flow injection system coupled to a quadruple ICP-MS for the direct and continuous determination of multi-element in microdialysates. To interface microdialysis sampling to an inductively coupled plasma mass spectrometer (ICP-MS), we employed 3D printing to manufacture an as-designed sample load/inject valve featuring an in-valve sample loop for precise handling of microliter samples with a dissolved solids content of 0.9% NaCl (w/v). To demonstrate the practicality of our developed on-line system, we applied the 3D printed valve equipped a 5-μL sample loop to minimize the occurrence of salt matrix effects and facilitate an online dynamic monitoring of extracellular calcium and zinc ions in living rat brains. Under the practical condition (temporal resolution: 10h(-1)), dynamic profiling of these two metal ions in living rat brain extracellular fluid after probe implantation (the basal values for Ca and Zn were 12.11±0.10mg L(-1) and 1.87±0.05μg L(-1), respectively) and real-time monitoring of the physiological response to excitotoxic stress elicited upon perfusing a solution of 2.5mM N-methyl-d-aspartate were performed. Copyright © 2014 Elsevier B.V. All rights reserved.

Quantifying Acoustic Uncertainty Due to Marine Mammals and Fish Near the Shelfbreak Front off Cape Hatteras

DTIC Science & Technology

2015-09-30

an AUV mounted acoustic source, 2) moored multi-element SHRU acoustic receiver arrays, 3) a shipboard acoustic resonator, 4) fish-attraction...devices (FAD’s), 5) a three- AUV fish-field mapping effort (employing sidescan sonar plus optics) and 6) ScanFish, ADCP, and moored sensor oceanographic...The acoustic model has been further refined. To obtain a better estimate of source positions, the navigation data of the source AUV (Snoopy) was

Reduced Basis and Stochastic Modeling of Liquid Propellant Rocket Engine as a Complex System

DTIC Science & Technology

2015-07-02

additions, the approach will be extended to a real- gas system so that it can be used to investigate model multi-element liquid rocket combustors in a...Sirignano (2010). In the following discussion, we examine the various conservation principles for the gas and liquid phases. The hyperbolic nature of the...conservation equations for the gas and liquid phases. Mass conservation of individual chemical species or of individual classes of liquid droplets will

Modular multi-element high energy particle detector

DOEpatents

Coon, D.D.; Elliott, J.P.

1990-01-02

Multi-element high energy particle detector modules comprise a planar heavy metal carrier of tungsten alloy with planar detector units uniformly distributed over one planar surface. The detector units are secured to the heavy metal carrier by electrically conductive adhesive so that the carrier serves as a common ground. The other surface of each planar detector unit is electrically connected to a feedthrough electrical terminal extending through the carrier for front or rear readout. The feedthrough electrical terminals comprise sockets at one face of the carrier and mating pins projecting from the other face, so that any number of modules may be plugged together to create a stack of modules of any desired number of radiation lengths. The detector units each comprise four, preferably rectangular, p-i-n diode chips arranged around the associated feedthrough terminal to form a square detector unit providing at least 90% detector element coverage of the carrier. Integral spacers projecting from the carriers extend at least partially along the boundaries between detector units to space the p-i-n diode chips from adjacent carriers in a stack. The spacers along the perimeters of the modules are one-half the width of the interior spacers so that when stacks of modules are arranged side by side to form a large array of any size or shape, distribution of the detector units is uniform over the entire array. 5 figs.

Modular multi-element high energy particle detector

DOEpatents

Coon, Darryl D.; Elliott, John P.

1990-01-02

Multi-element high energy particle detector modules comprise a planar heavy metal carrier of tungsten alloy with planar detector units uniformly distributed over one planar surface. The detector units are secured to the heavy metal carrier by electrically conductive adhesive so that the carrier serves as a common ground. The other surface of each planar detector unit is electrically connected to a feedthrough electrical terminal extending through the carrier for front or rear readout. The feedthrough electrical terminals comprise sockets at one face of the carrier and mating pins porjecting from the other face, so that any number of modules may be plugged together to create a stack of modules of any desired number of radiation lengths. The detector units each comprise four, preferably rectangular, p-i-n diode chips arranged around the associated feedthrough terminal to form a square detector unit providing at least 90% detector element coverage of the carrier. Integral spacers projecting from the carriers extend at least partially along the boundaries between detector units to space the p-i-n diode chips from adjacent carriers in a stack. The spacers along the perimeters of the modules are one-half the width of the interior spacers so that when stacks of modules are arranged side by side to form a large array of any size or shape, distribution of the detector units is uniform over the entire array.

Multi-Element Unstructured Analyses of Complex Valve Systems

NASA Technical Reports Server (NTRS)

Sulyma, Peter (Technical Monitor); Ahuja, Vineet; Hosangadi, Ashvin; Shipman, Jeremy

2004-01-01

The safe and reliable operation of high pressure test stands for rocket engine and component testing places an increased emphasis on the performance of control valves and flow metering devices. In this paper, we will present a series of high fidelity computational analyses of systems ranging from cryogenic control valves and pressure regulator systems to cavitating venturis that are used to support rocket engine and component testing at NASA Stennis Space Center. A generalized multi-element framework with sub-models for grid adaption, grid movement and multi-phase flow dynamics has been used to carry out the simulations. Such a framework provides the flexibility of resolving the structural and functional complexities that are typically associated with valve-based high pressure feed systems and have been difficult to deal with traditional CFD methods. Our simulations revealed a rich variety of flow phenomena such as secondary flow patterns, hydrodynamic instabilities, fluctuating vapor pockets etc. In the paper, we will discuss performance losses related to cryogenic control valves, and provide insight into the physics of the dominant multi-phase fluid transport phenomena that are responsible for the choking like behavior in cryogenic control elements. Additionally, we will provide detailed analyses of the modal instability that is observed in the operation of the dome pressure regulator valve. Such instabilities are usually not localized and manifest themselves as a system wide phenomena leading to an undesirable chatter at high flow conditions.

Effect of multi-element addition of Alnico alloying elements on structure and magnetic properties of SmCo5-based ribbons

NASA Astrophysics Data System (ADS)

Bian, Lu-peng; Li, Ying; Han, Xu-hao; Cheng, Jin-yun; Qin, Xiao-ning; Zhao, Yan-qiu; Sun, Ji-bing

2018-02-01

New SmCo5 + x wt% Alnico composite ribbons melt-spun at 40 m/s are designed by multi-element addition of Alnico alloy into SmCo5 matrix, and their structure and magnetic properties are investigated. The results show that the main phase in x ≤ 2.5 ribbons is Sm(Co,M)5, whereas the main phase changes into Sm(Co,M)7 at x = 4.0-8.5, and simultaneously that the content of Al-rich and amorphous phases increases with increasing x. The hard magnetic properties of the ribbons are found to improve with an increase in Alnico content, and particularly the average magnetic properties reach maximum, i.e., Hc = 19.6 ± 1.2 kOe, Mr = 47.7 ± 3.4 emu/g and M2T = 59.1 ± 5.6 emu/g, at x = 4.0. The main reasons for such improvement are that the finer grains divided by three grain boundaries exist in main phase, the dispersed Al-Ni and Al-Co-rich phases distribute in grains and grain boundaries, and the Fe-rich Alnico alloying elements dissolve into Sm(Co,M)7 matrix phase. However, when x > 4.0, the gradually increasing Al-Co and amorphous phases lead to the reduction of hard magnetic properties.

The relationship between structural stability and electrochemical performance of multi-element doped alpha nickel hydroxide

NASA Astrophysics Data System (ADS)

Miao, Chengcheng; Zhu, Yanjuan; Huang, Liangguo; Zhao, Tengqi

2015-01-01

The multi-element doped alpha nickel hydroxide has been prepared by supersonic co-precipitation method. Three kinds of samples A, B and C are prepared by chemically coprecipitating Ni/Al, Ni/Al/Mn and Ni/Al/Mn/Yb, respectively. Inductively coupled plasma atomic emission spectroscopy (ICP-AES), Particle size distribution (PSD) measurement, X-ray diffraction (XRD), scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR) are used to characterize the physical properties of the synthesized α-Ni(OH)2 samples, such as chemical composition, morphology, structural stability of the crystal. The results show that all samples are nano-sized materials and the interlayer spacing becomes larger and the structural stability becomes better with the increase of doped elements and doped ratio. The prepared alpha nickel hydroxide samples are added into micro-sized beta nickel hydroxide to form biphase electrode materials for Ni-MH battery. The electrochemical characterization of the biphase electrodes, including cyclic voltammetry (CV) and charge/discharge test, are also performed. The results demonstrate that the biphase electrode with sample C exhibits better electrochemical reversibility and cyclic stability, higher charge efficient and discharge potential, larger proton diffusion coefficient (5.81 × 10-12 cm2 s-1) and discharge capacity (309.0 mAh g-1). Hence, it indicates that all doped elements can produce the synergic effect and further improve the electrochemical properties of the alpha nickel hydroxide.

Wind Tunnel Results of the Aerodynamic Performance of a 1/8-Scale Model of a Twin-Engine Transport with Multi-Element Wing

NASA Technical Reports Server (NTRS)

Laflin, Brenda E. Gile; Applin, Zachary T.; Jones, Kenneth M.

1997-01-01

A wind tunnel investigation was performed in the 14- by 22-Foot Subsonic Tunnel on a pressure instrumented 1/8-scale twin-engine subsonic transport to better understand the flow physics on a multi-element wing section. The wing consisted of a part-span, triple-slotted trailing edge flap, inboard leading-edge Krueger flap and an outboard leading-edge slat. The model was instrumented with flush pressure ports at the fuselage centerline and seven spanwise wing locations. The model was tested in cruise, take-off and landing configurations at dynamic pressures and Mach numbers from 10 lbf/ft(exp 2) to 50 lbf/ft(exp 2) and 0.08 to 0.17, respectively. This resulted in corresponding Reynolds numbers of 0.8 x 10(exp 5) to 1.8 x 10(exp 6). Pressure data were collected using electronically scanned pressure devices and force and moment data were collected with a six component strain gauge balance. Results are presented for various control surface deflections over an angle-of-attack range from -4 degrees to 16 degrees and sideslip angle range from -10 degrees to 10 degrees. Longitudinal and lateral directional aerodynamic data are presented as well as chordwise pressure distributions at the seven spanwise wing locations and the fuselage centerline.

A comparison of simultaneous plasma, atomic absorption, and iron colorimetric determinations of major and trace constituents in acid mine waters

USGS Publications Warehouse

Ball, J.W.; Nordstrom, D. Kirk

1994-01-01

Sixty-three water samples collected during June to October 1982 from the Leviathan/Bryant Creek drainage basin were originally analyzed by simultaneous multielement direct-current plasma (DCP) atomic-emission spectrometry, flame atomic-absorption spectrometry, graphite-furnace atomic-absorption spectrometry (GFAAS) (thallium only), ultraviolet-visible spectrometry, and hydride-generation atomic-absorption spectrometry.Determinations were made for the following metallic and semi-metallic constituents: AI, As, B, Ba, Be, Bi, Cd, Ca, Cr, Co, Cu, Fe(11), Fe(total), Li, Pb, Mg, Mn, Mo, Ni, K, Sb, Se, Si, Na, Sr, TI, V, and Zn. These samples were re-analyzed later by simultaneous multielement inductively coupled plasma (ICP) atomic-emission spectrometry and Zeeman-corrected GFAAS to determine the concentrations of many of the same constituents with improved accuracy, precision, and sensitivity. The result of this analysis has been the generation of comparative concentration values for a significant subset of the solute constituents. Many of the more recently determined values replace less-than-detection values for the trace metals; others constitute duplicate analyses for the major constituents. The multiple determinations have yielded a more complete, accurate, and precise set of analytical data. They also have resulted in an opportunity to compare the performance of the plasma-emission instruments operated in their respective simultaneous multielement modes. Flame atomic-absorption spectrometry was judged best for Na and K and hydride-generation atomic-absorption spectrometry was judged best for As because of their lower detection limit and relative freedom from interelement spectral effects. Colorimetric determination using ferrozine as the color agent was judged most accurate, precise, and sensitive for Fe. Cadmium, lead, and vanadium concentrations were too low in this set of samples to enable a determination of whether ICP or DCP is a more suitable technique. Of the remaining elements, Ba, Be, Ca, Cr, Mg, Mn, Sr, and Zn have roughly equivalent accuracy, precision, and detection limit by ICP and DCP. Cobalt and Ni were determined to be better analyzed by ICP, because of lower detection limits; B, Cu, Mo, and Si were determined to be better analyzed by DCP, because of relative freedom from interferences. The determination oral by DCP was far more sensitive, owing to the use of a more sensitive wavelength, compared with the ICP. However, there is a very serious potential interference from a strong Ca emission line near the 396.15 nanometer DCP wavelength. Thus, there is no clear choice between the plasma techniques tested, for the determination oral. The ICP and DCP detection limits are typically between 0.001 and 0.5 milligrams per liter in acid mine waters. For those metals best analyzed by ICP and/or DCP, but below these limits, GFAAS is the method of choice because of its relatively greater sensitivity and specificity. Six of the elements were not determined by DCP, ICP or Zeeman-corrected GFAAS, and are not discussed in this report. These elements are: Bi, Fe(11), Li, Sb, Se, and TI.

Recent Advances in the Measurement of Arsenic, Cadmium, and Mercury in Rice and Other Foods

PubMed Central

Punshon, Tracy

2015-01-01

Trace element analysis of foods is of increasing importance because of raised consumer awareness and the need to evaluate and establish regulatory guidelines for toxic trace metals and metalloids. This paper reviews recent advances in the analysis of trace elements in food, including challenges, state-of-the art methods, and use of spatially resolved techniques for localizing the distribution of As and Hg within rice grains. Total elemental analysis of foods is relatively well-established but the push for ever lower detection limits requires that methods be robust from potential matrix interferences which can be particularly severe for food. Inductively coupled plasma mass spectrometry (ICP-MS) is the method of choice, allowing for multi-element and highly sensitive analyses. For arsenic, speciation analysis is necessary because the inorganic forms are more likely to be subject to regulatory limits. Chromatographic techniques coupled to ICP-MS are most often used for arsenic speciation and a range of methods now exist for a variety of different arsenic species in different food matrices. Speciation and spatial analysis of foods, especially rice, can also be achieved with synchrotron techniques. Sensitive analytical techniques and methodological advances provide robust methods for the assessment of several metals in animal and plant-based foods, in particular for arsenic, cadmium and mercury in rice and arsenic speciation in foodstuffs. PMID:25938012

Evaluation of Flow-Injection Tandem Mass Spectrometry for Rapid and High-Throughput Quantitative Determination of B-Vitamins in Nutritional Supplements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhandari, Deepak; Van Berkel, Gary J

2012-01-01

The use of flow-injection electrospray ionization tandem mass spectrometry for rapid and high-throughput mass spectral analysis of selected B-vitamins, viz. B1, B2, B3, B5, and B6, in nutritional formulations was demonstrated. A simple and rapid (~5 min) in-tube sample preparation was performed by adding extraction solvent to a powdered sample aliquot followed by agitation, centrifugation, and filtration to recover an extract for analysis. Automated flow injection introduced 1 L of the extracts directly into the mass spectrometer ion source without chromatographic separation. Sample-to-sample analysis time was 60 s representing significant improvement over conventional liquid chromatography approaches which typically require 25-45more » min, and often require more significant sample preparation procedures. Quantitative capabilities of the flow-injection analysis were tested using the method of standard additions and NIST standard reference material (SRM 3280) multivitamin/multielement tablets. The quantity determined for each B-vitamin in SRM 3280 was within the statistical range provided for the respective certified values. The same sample preparation and analysis approach was also applied to two different commercial vitamin supplement tablets and proved to be successful in the quantification of the selected B-vitamins as evidenced by an agreement with the labels values and the results obtained using isotope dilution liquid chromatography/mass spectrometry.« less

Recognizing and overcoming analytical error in the use of ICP-MS for the determination of cadmium in breakfast cereal and dietary supplements.

PubMed

Murphy, Karen E; Vetter, Thomas W

2013-05-01

The potential effect of spectral interference on the accurate measurement of the cadmium (Cd) mass fraction in fortified breakfast cereal and a variety of dietary supplement materials using inductively coupled plasma quadrupole mass spectrometry was studied. The materials were two new standard reference materials (SRMs)--SRM 3233 Fortified Breakfast Cereal and SRM 3532 Calcium Dietary Supplement--as well as several existing materials--SRM 3258 Bitter Orange Fruit, SRM 3259 Bitter Orange Extract, SRM 3260 Bitter Orange-containing Solid Oral Dosage Form, and SRM 3280 Multivitamin/Multielement Tablets. Samples were prepared for analysis using the method of isotope dilution and measured using various operating and sample introduction configurations including standard mode, collision cell with kinetic energy discrimination mode, and standard mode with sample introduction via a desolvating nebulizer system. Three isotope pairs, (112)Cd/(111)Cd, (113)Cd/(111)Cd, and (114)Cd/(111)Cd, were measured. Cadmium mass fraction results for the unseparated samples of each material, measured using the three instrument configurations and isotope pairs, were compared to the results obtained after the matrix was removed via chemical separation using anion exchange chromatography. In four of the six materials studied, measurements using the standard mode with sample introduction via the desolvating nebulizer gave results for the unseparated samples quantified with the (112)Cd/(111)Cd isotope pair that showed a positive bias relative to the matrix-separated samples, which indicated a persistent inference at m/z112 with this configuration. Use of the standard mode, without the desolvating nebulizer, also gave results that showed a positive bias for the unseparated samples quantified with the (112)Cd/(111)Cd isotope pair in three of the materials studied. Collision cell/kinetic energy discrimination mode, however, was very effective for reducing spectral interference for Cd in all of the materials and isotope pairs studied, except in the multivitamin/multielement matrix (SRM 3280) where the large corrections for known isobaric interferences or unidentified interferences compromised the accuracy. For SRM 3280, matrix separation provided the best method to achieve accurate measurement of Cd.

Computation of subsonic flow around airfoil systems with multiple separation

NASA Technical Reports Server (NTRS)

Jacob, K.

1982-01-01

A numerical method for computing the subsonic flow around multi-element airfoil systems was developed, allowing for flow separation at one or more elements. Besides multiple rear separation also sort bubbles on the upper surface and cove bubbles can approximately be taken into account. Also, compressibility effects for pure subsonic flow are approximately accounted for. After presentation the method is applied to several examples and improved in some details. Finally, the present limitations and desirable extensions are discussed.

Abrupt Climate Change in the Atlantic Ocean During the Last 20,000 Years: Insights from Multi-Element Analyses of Benthic and Planktic Foraminifera and a Coupled OA-GCM

DTIC Science & Technology

2005-09-01

paleoceanographic and terrestrial climate proxies . Greenland ice cores, in particular, provide evidence of large amplitude, very rapid climate change during...received the most attention because it is the largest Holocene excursion in the GISP2 810 record [Alley et al., 1997]. Multiple proxies in Greenland ice...latitude North Atlantic foraminiferal-based proxies such as modem analogue technique [Marchal et al., 2002; Risebrobakken et al., 2003], but

CFD validation experiments at the Lockheed-Georgia Company

NASA Technical Reports Server (NTRS)

Malone, John B.; Thomas, Andrew S. W.

1987-01-01

Information is given in viewgraph form on computational fluid dynamics (CFD) validation experiments at the Lockheed-Georgia Company. Topics covered include validation experiments on a generic fighter configuration, a transport configuration, and a generic hypersonic vehicle configuration; computational procedures; surface and pressure measurements on wings; laser velocimeter measurements of a multi-element airfoil system; the flowfield around a stiffened airfoil; laser velocimeter surveys of a circulation control wing; circulation control for high lift; and high angle of attack aerodynamic evaluations.

Single-Sided Noinvasive Inspection of Multielement Sample Using Fan-Beam Multiplexed Compton Scatter Tomography

DTIC Science & Technology

2000-05-01

a vector , ρ "# represents the set of voxel densities sorted into a vector , and ( )A ρ $# "# represents a 8 mapping of the voxel densities to...density vector in equation (4) suggests that solving for ρ "# by direct inversion is not possible, calling for an iterative technique beginning with...the vector of measured spectra, and D is the diagonal matrix of the inverse of the variances. The diagonal matrix provides weighting terms, which

Increasing Seat Belt Use on a College Campus: An Evaluation of Two Prompting Procedures

PubMed Central

Clayton, Michael C; Helms, Bridgett P

2009-01-01

Seat belt use is an important factor in the prevention of automobile accidents involving injuries and fatalities. The current study used a multielement design to compare the “Click It or Ticket” and “Please Buckle Up—I Care” procedures. Results indicate that the Click It or Ticket prompt resulted in a 20-percentage-point increase in seat belt use, and Please Buckle Up—I Care resulted in a 14-percentage-point increase. PMID:19721736

KSC-99pp0659

NASA Image and Video Library

1999-05-25

In The Space Station Processing Facility, a Multi-Element Integration Test (MEIT) is underway to ensure components of the International Space Station work together before they are launched into orbit. Within the framework at right is the U.S. Lab, called Destiny; at left is the Z-1 truss. The current MEIT combines the P-6 photovoltaic module, the Z-1 truss and the Pressurized Mating Adapter 3. Electrical and fluid connections are being hooked up to verify how the ISS elements operate together

Development of solid tunable optics for ultra-miniature imaging systems

NASA Astrophysics Data System (ADS)

Yongchao, Zou

This thesis focuses on the optimal design, fabrication and testing of solid tunable optics and exploring their applications in miniature imaging systems. It starts with the numerical modelling of such lenses, followed by the optimum design method and alignment tolerance analysis. A miniature solid tunable lens driven by a piezo actuator is then developed. To solve the problem of limited maximum optical power and tuning range in conventional lens designs, a novel multi-element solid tunable lens is proposed and developed. Inspired by the Alvarez principle, a novel miniature solid tunable dual-focus lens, which is designed using freeform surfaces and driven by one micro-electro-mechanical-systems (MEMS) rotary actuator, is demonstrated. To explore the applications of these miniature solid tunable lenses, a miniature adjustable-focus endoscope and one compact adjustable-focus camera module are developed. The adjustable-focus capability of these two miniature imaging systems is fully proved by electrically focusing targets placed at different positions.

A retail market study of organic and conventional potatoes (Solanum tuberosum): mineral content and nutritional implications.

PubMed

Griffiths, Andrea M; Cook, David M; Eggett, Dennis L; Christensen, Merrill J

2012-06-01

Whether or not all foods marketed to consumers as organic meet specified standards for use of that descriptor, or are nutritionally different from conventional foods, is uncertain. In a retail market study in a Western US metropolitan area, differences in mineral composition between conventional potatoes and those marketed as organic were analysed. Potatoes marketed as organic had more copper and magnesium (p < 0.0001), less iron (p < 0.0001) and sodium (p < 0.02), and the same concentration of calcium, potassium and zinc as conventional potatoes. Comparison of individual mineral concentrations between foodstuffs sold as organic or conventional is unlikely to establish a chemical fingerprint to objectively distinguish between organic and conventional produce, but more sophisticated chemometric analysis of multi-element fingerprints holds promise of doing so. Although statistically significant, these differences would only minimally affect total dietary intake of these minerals and be unlikely to result in measurable health benefits.

The effects of presession manipulations on automatically maintained challenging behavior and task responding.

PubMed

Chung, Yi-Chieh; Cannella-Malone, Helen I

2010-11-01

This study examined the effects of presession exposure to attention, response blocking, attention with response blocking, and noninteraction conditions on subsequent engagement in automatically maintained challenging behavior and correct responding in four individuals with significant intellectual disabilities. Following a functional analysis, the effects of the four presession conditions were examined using multielement designs. Results varied across the 4 participants (e.g., presession noninteraction acted as an abolishing operation for 2 participants, but as an establishing operation for the other 2 participants). As such, both the results replicated and contradicted previous research examining the effects of motivating operations on automatically maintained challenging behavior. Although the results varied across participants, at least one condition resulting in a decrease in challenging behavior and an increase in correct responding were identified for each participant. These findings suggested that presession manipulations resulted in decreases in subsequent automatically maintained challenging behavior and simultaneous increases in correct responding might need to be individually identified when the maintaining contingencies cannot be identified.

Use of High-Resolution Continuum Source Flame Atomic Absorption Spectrometry (HR-CS FAAS) for Sequential Multi-Element Determination of Metals in Seawater and Wastewater Samples

NASA Astrophysics Data System (ADS)

Peña-Vázquez, E.; Barciela-Alonso, M. C.; Pita-Calvo, C.; Domínguez-González, R.; Bermejo-Barrera, P.

2015-09-01

The objective of this work is to develop a method for the determination of metals in saline matrices using high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS). Module SFS 6 for sample injection was used in the manual mode, and flame operating conditions were selected. The main absorption lines were used for all the elements, and the number of selected analytical pixels were 5 (CP±2) for Cd, Cu, Fe, Ni, Pb and Zn, and 3 pixels for Mn (CP±1). Samples were acidified (0.5% (v/v) nitric acid), and the standard addition method was used for the sequential determination of the analytes in diluted samples (1:2). The method showed good precision (RSD(%) < 4%, except for Pb (6.5%)) and good recoveries. Accuracy was checked after the analysis of an SPS-WW2 wastewater reference material diluted with synthetic seawater (dilution 1:2), showing a good agreement between certified and experimental results.

Mineral content of Chinese medicinal herbs used as diuretic treatments for Taiwanese children.

PubMed

Chen, Chien-Yi

2005-01-01

Eighteen major, minor and trace elements in 12 Chinese medicinal herbs commonly consumed by Taiwanese Children as diuretics were determined by instrumental neutron activation analysis (INAA). Dried and powdered herb samples were irradiated in a neutron flux of ca. 2 x 10(12) n/cm2 s under separate short and long irradiation schemes. Lichen (IAEA-336) was used as the reference standard, and tomato leaves (NIST-SRM 1570a) were employed for cross-checking the accuracy of the results. INAA was shown to be a reliable multi-element analytical method for determining the content of both toxicologically and nutritionally important minerals in Chinese medicinal herbs. Determined elements were present in the dried herbs in concentrations ranging from 10(4) to 10(-3) microg/g. The mineral contents and the maximum daily intake values of the tested herbs were compared with published values and with the recommended daily intakes for Taiwanese children as specified by the World Health Organization.

The effects of a weighted vest on aggressive and self-injurious behavior in a child with autism.

PubMed

Davis, Tonya N; Dacus, Sharon; Strickland, Erica; Copeland, Daelynn; Chan, Jeffrey Michael; Blenden, Kara; Scalzo, Rachel; Osborn, Staci; Wells, Kellsye; Christian, Krisann

2013-06-01

Analyse the effects of a weighted vest on the aggressive and self-injurious behavior of a young boy with autism. The effects of the weighted vest were examined during a functional analysis utilizing an ABAB design with an embedded multielement design, in which the participant wore a five pound weighted vest or no vest. The results do not suggest the existence of a functional relationship between the use of a weighted vest and challenging behavior, as the weighted vest had no marked effect on levels of aggression and self-injurious behavior. Weighted vests are a commonly implemented form of sensory integration therapy, frequently used as a treatment for disruptive behaviors associated with autism spectrum disorder [Stephenson J, Carter M. The use of weighted vests with children with autism spectrum disorders and other disabilities. Journal of Autism and Developmental Disabilities 2009;39:105-114]. However, the current findings support previous literature which states that the use of weighted vests does not appear to decrease challenging behavior.

A three-dimensional viscous/potential flow interaction analysis method for multi-element wings: Modifications to the potential flow code to allow part-span, high-lift devices and close-interference calculations

NASA Technical Reports Server (NTRS)

Maskew, B.

1979-01-01

The description of the modified code includes details of a doublet subpanel technique in which panels that are close to a velocity calculation point are replaced by a subpanel set. This treatment gives the effect of a higher panel density without increasing the number of unknowns. In particular, the technique removes the close approach problem of the earlier singularity model in which distortions occur in the detailed pressure calculation near panel corners. Removal of this problem allowed a complete wake relaxation and roll-up iterative procedure to be installed in the code. The geometry package developed for the new technique and also for the more general configurations is based on a multiple patch scheme. Each patch has a regular array of panels, but arbitrary relationships are allowed between neighboring panels at the edges of adjacent patches. This provides great versatility for treating general configurations.

Cause of the chalcophile trace element enrichments marking the Holocene to Anthropocene transition in northern Chesapeake Bay sediments

NASA Astrophysics Data System (ADS)

Dolor, Marvourneen K.; Helz, George R.; McDonough, William F.

2012-04-01

In Chesapeake Bay sediments, concentrations of 15 chalcophile trace elements, half rarely determined in estuaries, display historical profiles having remarkably similar features. All element concentrations rose more or less simultaneously in the 1920-1940 interval, creating a chemostratigraphic marker of the Holocene to Anthropocene transition. Subsequently, concentration maxima occurred at ˜20-year intervals, suggesting a link to a documented climate cycle of similar period. These elements' correlated profiles suggest that sediments approximate binary mixtures of one lithogenic and one multi-element anthropogenic component. The latter component is characterized by these mass ratios (±standard error): Co/Zn 0.071 ± 0.003 Cu/Zn 0.147 ± 0.007 Ag/Zn 0.0030 ± 0.0002 Cd/Zn 0.0050 ± 0.0004 In/Zn 0.00031 ± 0.00004 Sn/Zn 0.019 ± 0.002 Sb/Zn 0.0040 ± 0.0002 Te/Zn 0.00059 ± 0.00003 Tl/Zn 0.0016 ± 0.0002 Pb/Zn 0.242 ± 0.013 Bi/Zn 0.00087 ± 0.00005 Where comparisons are possible, these ratios differ from those of contaminants in the harbor of the region's principal industrial city, Baltimore, but are surprisingly similar to those in sediment contaminants from the Susquehanna River, the Bay's chief tributary. Thus both the anthropogenic and the lithogenic components in the Bay's central channel appear to originate in the river basin. Many chalcophile element ratios in the anthropogenic component are similar to those in regional aerosols. If cumulative aerosol deposition on soils in the river basin is the source of the anthropogenic component, then the above ratios could be a regional anthropogenic signature that should be looked for more widely. Unlike Mo, the enrichment of these chalcophile elements in the Bay's sediments is not controlled by seasonal anoxia; Mo apparently possesses a unique capacity to record past redox information about estuaries owing to its high seawater concentration.

Preliminary study on multi-element profile mapping of crustal and mantle zircons by using Synchrotron Radiation X-ray Fluorescence (SR-XRF)

NASA Astrophysics Data System (ADS)

Hasözbek, Altug; Shyam, Badri; Siebel, Wolfgang; Schmitt, Axel; Akay, Erhan; Skinner, Lawrie

2013-04-01

Zircon (ZrSiO4) is a mineral of singular importance in the geosciences. Zircon microanalysis has greatly contributed to our understanding of key events in earth's history as certain radioactive heavy elements and their daughter products are well-preserved within the exceptionally stable inorganic matrix of the mineral. A prevailing notion in this field is that zircon, as a mineral, is predominantly a crustal mineral; this has been contested in the last few years with more reports of mantle-derived zircons (Siebel et al., 2009). Zircons enriched from different parts of the upper mantle to lower crust from Turkey (Hasozbek et al. 2010) and Germany (Siebel et al., 2009) will be presented in this study using SR-XRF mapping carried out at beamline 2-IDE at the Advanced Photon Source synchrotron facility (Argonne National Laboratory, USA). The high-resolution (5-10 µm) elemental maps were obtained with collimated and linearly polarized synchrotron radiation (10 to 17 keV) and possess the advantage of being a completely non-destructive technique. Elemental maps of various trace and rare-earth elements along the cross-section of the zircons reveal a zonation-related distribution, which may be used to reveal factors affecting the growth history and dynamics of the crystal formation. Further, abrupt changes in elemental distribution or concentration were found to correspond to faults or inclusions within the zircon crystal. If such observations are found to be applicable for a wide range of samples, elemental mapping with this technique may serve as an important qualitative diagnostic to locating µ-meter inclusions that may be challenging to identify using other techniques (ICP-MS LA, SHRIMP,…) Through these preliminary elemental profile mapping studies of crustal and mantle zircons using SR-XRF methods, we aim to highlight a relatively quick and promising analytical method that may be used to study various geological problems.

I'll take that to go: Big data bags and minimal identifiers for exchange of large, complex datasets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chard, Kyle; D'Arcy, Mike; Heavner, Benjamin D.

Big data workflows often require the assembly and exchange of complex, multi-element datasets. For example, in biomedical applications, the input to an analytic pipeline can be a dataset consisting thousands of images and genome sequences assembled from diverse repositories, requiring a description of the contents of the dataset in a concise and unambiguous form. Typical approaches to creating datasets for big data workflows assume that all data reside in a single location, requiring costly data marshaling and permitting errors of omission and commission because dataset members are not explicitly specified. We address these issues by proposing simple methods and toolsmore » for assembling, sharing, and analyzing large and complex datasets that scientists can easily integrate into their daily workflows. These tools combine a simple and robust method for describing data collections (BDBags), data descriptions (Research Objects), and simple persistent identifiers (Minids) to create a powerful ecosystem of tools and services for big data analysis and sharing. We present these tools and use biomedical case studies to illustrate their use for the rapid assembly, sharing, and analysis of large datasets.« less

GIS-based multielement source analysis of dustfall in Beijing: A study of 40 major and trace elements.

PubMed

Luo, Nana; An, Li; Nara, Atsushi; Yan, Xing; Zhao, Wenji

2016-06-01

Dust, as an important carrier of inorganic and organic pollutants, daily exposes to human without any protection. It affects our health adversely, especially its chemical elements and ions. In this research, we investigated the chemical characteristics of dustfall in Beijing, specifically in terms of 40 major and trace elements, and presented semi-quantitative evaluations of the relative local and remote contributions. In total, 58 samples were collected in Beijing and nearby cities during 2013-2014 "the winter heating period". Using multiple statistical methods and GIS techniques, we obtained the relative similarities among certain elements and identified their pollution sources (from local or nearby cities). And more interestingly, the relative contributions of nearby cities can be calculated by the Hysplit4 backward-trajectory model. In addition, the correlation analysis for the 40 elements in dust and soil indicated that traffic restricted interchange between them; the city center, with the heaviest traffic, had the most significant influence. Finally, the resulting source apportionment was examined and modified using land use data and terrain information. We hope it can provide a strong basis for the environmental protection and risk assessment. Copyright © 2016 Elsevier Ltd. All rights reserved.

Novorossiysk agglomeration landscapes and cement production: geochemical impact assessment

NASA Astrophysics Data System (ADS)

Alekseenko, A. V.; Pashkevich, M. A.

2016-09-01

The article deals with assessing the environmental impact of marl mining and cement production in Novorossiysk city (Krasnodar krai, Russia). The existing methods of studying the environmental effects caused by the cement industry have been reviewed. Soil and aquatic vegetation sampling has been carried out and the gross concentration of metals in the samples has been defined. The research has been conducted in the certified and accredited laboratory using emission spectral analysis. The external control has been carried out via X-ray fluorescence analysis. Based on the collected data, main chemical pollutants in soil cover and water area near the cement plant have been identified. The contaminants released by urban enterprises and motor vehicle emissions, as well as fugitive dust from dumps and the cement factory, lead to multi-element lithogeochemical anomaly at geochemical barriers in soils. Accumulation of pollutants in soil depends on the type of land use and the area relief. The most contaminated aquatic landscapes have been identified in the inner bay. According to this information, the technical proposals can be prepared for environmental safety management in strongly polluted city areas, as well as for the reclamation design in the areas currently experiencing the negative impact of cement production.

Dual wing, swept forward swept rearward wing, and single wing design optimization for high performance business airplanes

NASA Technical Reports Server (NTRS)

Rhodes, M. D.; Selberg, B. P.

1982-01-01

An investigation was performed to compare closely coupled dual wing and swept forward swept rearward wing aircraft to corresponding single wing 'baseline' designs to judge the advantages offered by aircraft designed with multiple wing systems. The optimum multiple wing geometry used on the multiple wing designs was determined in an analytic study which investigated the two- and three-dimensional aerodynamic behavior of a wide range of multiple wing configurations in order to find the wing geometry that created the minimum cruise drag. This analysis used a multi-element inviscid vortex panel program coupled to a momentum integral boundary layer analysis program to account for the aerodynamic coupling between the wings and to provide the two-dimensional aerodynamic data, which was then used as input for a three-dimensional vortex lattice program, which calculated the three-dimensional aerodynamic data. The low drag of the multiple wing configurations is due to a combination of two dimensional drag reductions, tailoring the three dimensional drag for the swept forward swept rearward design, and the structural advantages of the two wings that because of the structural connections permitted higher aspect ratios.

Determination of Stark parameters by cross-calibration in a multi-element laser-induced plasma

NASA Astrophysics Data System (ADS)

Liu, Hao; Truscott, Benjamin S.; Ashfold, Michael N. R.

2016-05-01

We illustrate a Stark broadening analysis of the electron density Ne and temperature Te in a laser-induced plasma (LIP), using a model free of assumptions regarding local thermodynamic equilibrium (LTE). The method relies on Stark parameters determined also without assuming LTE, which are often unknown and unavailable in the literature. Here, we demonstrate that the necessary values can be obtained in situ by cross-calibration between the spectral lines of different charge states, and even different elements, given determinations of Ne and Te based on appropriate parameters for at least one observed transition. This approach enables essentially free choice between species on which to base the analysis, extending the range over which these properties can be measured and giving improved access to low-density plasmas out of LTE. Because of the availability of suitable tabulated values for several charge states of both Si and C, the example of a SiC LIP is taken to illustrate the consistency and accuracy of the procedure. The cross-calibrated Stark parameters are at least as reliable as values obtained by other means, offering a straightforward route to extending the literature in this area.

Analysis of Inorganic Nanoparticles by Single-particle Inductively Coupled Plasma Time-of-Flight Mass Spectrometry.

PubMed

Hendriks, Lyndsey; Gundlach-Graham, Alexander; Günther, Detlef

2018-04-25

Due to the rapid development of nanotechnologies, engineered nanomaterials (ENMs) and nanoparticles (ENPs) are becoming a part of everyday life: nanotechnologies are quickly migrating from laboratory benches to store shelves and industrial processes. As the use of ENPs continues to expand, their release into the environment is unavoidable; however, understanding the mechanisms and degree of ENP release is only possible through direct detection of these nanospecies in relevant matrices and at realistic concentrations. Key analytical requirements for quantitative detection of ENPs include high sensitivity to detect small particles at low total mass concentrations and the need to separate signals of ENPs from a background of dissolved elemental species and natural nanoparticles (NNPs). To this end, an emerging method called single-particle inductively coupled plasma mass spectrometry (sp-ICPMS) has demonstrated great potential for the characterization of inorganic nanoparticles (NPs) at environmentally relevant concentrations. Here, we comment on the capabilities of modern sp-ICPMS analysis with particular focus on the measurement possibilities offered by ICP-time-of-flight mass spectrometry (ICP-TOFMS). ICP-TOFMS delivers complete elemental mass spectra for individual NPs, which allows for high-throughput, untargeted quantitative analysis of dispersed NPs in natural matrices. Moreover, the multi-element detection capabilities of ICP-TOFMS enable new NP-analysis strategies, including online calibration via microdroplets for accurate NP mass quantification and matrix compensation.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi (left), with the National Space Development Agency of Japan (NASDA), points to data on the console during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM) in the Space Station Processing Facility. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 provides attach locations for the Japanese laboratory, as well as European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. Installation of the module will complete the U.S. Core of the ISS.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi (left), with the National Space Development Agency of Japan (NASDA), points to data on the console during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM) in the Space Station Processing Facility. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 provides attach locations for the Japanese laboratory, as well as European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. Installation of the module will complete the U.S. Core of the ISS.

KENNEDY SPACE CENTER, FLA. - In the Space Station Processing Facility, astronaut Soichi Noguchi (right), with the National Space Development Agency of Japan (NASDA), stands inside the Japanese Experiment Module (JEM) that is undergoing a Multi-Element Integrated Test (MEIT) with the U.S. Node 2. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 provides attach locations for the Japanese laboratory, as well as European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. Installation of the module will complete the U.S. Core of the ISS.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - In the Space Station Processing Facility, astronaut Soichi Noguchi (right), with the National Space Development Agency of Japan (NASDA), stands inside the Japanese Experiment Module (JEM) that is undergoing a Multi-Element Integrated Test (MEIT) with the U.S. Node 2. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 provides attach locations for the Japanese laboratory, as well as European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. Installation of the module will complete the U.S. Core of the ISS.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi (left), with the National Space Development Agency of Japan (NASDA), works at a console during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM) in the Space Station Processing Facility. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 provides attach locations for the Japanese laboratory, as well as European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. Installation of the module will complete the U.S. Core of the ISS.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi (left), with the National Space Development Agency of Japan (NASDA), works at a console during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM) in the Space Station Processing Facility. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 provides attach locations for the Japanese laboratory, as well as European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. Installation of the module will complete the U.S. Core of the ISS.

Scattering of the field of a multi-element phased array by human ribs

NASA Astrophysics Data System (ADS)

Gélat, P.; ter Haar, G.; Saffari, N.

2012-03-01

The efficacy of high intensity focused ultrasound (HIFU) for the non-invasive treatment of cancer has been demonstrated for a range of different cancers including those of the liver, kidney, prostate and breast. As a non-invasive focused therapy, HIFU offers considerable advantages over other techniques such as chemotherapy and surgical resection, in terms of invasiveness and risk of harmful side effects. Despite its advantages, however, there are a number of significant challenges currently hindering its widespread clinical application. One of these challenges is the need to transmit sufficient energy through the ribcage to induce tissue necrosis at the required foci whilst minimising the formation of side lobes. Multielement random arrays are currently showing great promise in overcoming the limitations of single-element transducers. Nevertheless, successfully treating a patient for liver tumours requires a thorough understanding of the way in which the ultrasonic pressure field from a HIFU array is scattered by the ribcage. A mesh of quadratic pressure patches was generated using CT scan data for ribs nine to twelve on the right side. A boundary element approach based on a Generalised Minimal Residual (GMRES) implementation of the Burton-Miller formulation was used, in conjunction with phase conjugation techniques to focus the field of a 256-element random HIFU array past the ribs at both intercostal and transcostal treatment locations. This method has the advantage of accounting for full effects of scattering and diffraction in three dimensions under continuous wave excitation.

Database of natural matrix reference materials (NMRM) for organic constituents.

PubMed

Iyengar, G V; Bleise, A R

2001-06-01

The International Atomic Energy Agency maintains a database of internationally available certified reference materials (CRM) of natural matrices. This database is periodically updated, and presently documents nearly 25,000 measurands in 1,700 materials. The organic constituents are classified in five major groups of analytes aliphatic and aromatic hydrocarbons (A), chlorinated hydrocarbons (B), pesticides (C), organometallic compounds (D) and other organic constituents (nutrients, etc.) (E). The matrices include natural materials such as body fluids, food products, soils, and sediments, terrestrial (e.g. plants), and anthropogenic products (e.g. dust, fly ash). These five organic groups of analytes encompass more than 2000 measurands for 420 different analytes in 230 materials. Of these measurands, 1,682 (68%) are certified, and 768 (32%) are provided as informational values. Within each major group of analytes, measurands reported as informational values accounted for: A (35%); B (35%); C (26%); D (10%), and E (22%). The high proportion of informational values (i.e. non-certified values) for A, B, and C, compares well with a similar but undesirable situation faced in the nineteen-seventies in the inorganic area when simultaneous multielement techniques became available. In the case of D and E, it appears that mostly targeted analytes are measured, leading to a cohesive certification profile. Although the IAEA database is not equally comprehensive for all groups of analytes cited above, it can still serve as an useful indicator of the status of organic constituents in RMs.

Oversampling of digitized images. [effects on interpolation in signal processing

NASA Technical Reports Server (NTRS)

Fischel, D.

1976-01-01

Oversampling is defined as sampling with a device whose characteristic width is greater than the interval between samples. This paper shows why oversampling should be avoided and discusses the limitations in data processing if circumstances dictate that oversampling cannot be circumvented. Principally, oversampling should not be used to provide interpolating data points. Rather, the time spent oversampling should be used to obtain more signal with less relative error, and the Sampling Theorem should be employed to provide any desired interpolated values. The concepts are applicable to single-element and multielement detectors.

Experimental Optimization Methods for Multi-Element Airfoils

NASA Technical Reports Server (NTRS)

Landman, Drew; Britcher, Colin P.

1996-01-01

A modern three element airfoil model with a remotely activated flap was used to investigate optimum flap testing position using an automated optimization algorithm in wind tunnel tests. Detailed results for lift coefficient versus flap vertical and horizontal position are presented for two angles of attack: 8 and 14 degrees. An on-line first order optimizer is demonstrated which automatically seeks the optimum lift as a function of flap position. Future work with off-line optimization techniques is introduced and aerodynamic hysteresis effects due to flap movement with flow on are discussed.

High Tc superconducting IR detectors from Y-Ba-Cu-O thin films

NASA Technical Reports Server (NTRS)

Lindgren, M.; Ahlberg, H.; Danerud, M.; Larsson, A.; Eng, M.

1990-01-01

A thin-film high-Tc superconducting multielement optical detector made of Y-Ba-Cu-O has been designed and evaluated using optical pulses from a diode laser (830 nm) and a Q-switched CO2-laser (10.6 microns). Different thin films have been tested. A laser deposited film showed the strongest response amplitude for short pulses and responded to an ultrafast, 50 ps wide pulse. Comparisons between dR/dT and response as a function of temperature indicated, however, a bolometric response.

OLED lighting devices having multi element light extraction and luminescence conversion layer

DOEpatents

Krummacher, Benjamin Claus; Antoniadis, Homer

2010-11-16

An apparatus such as a light source has a multi element light extraction and luminescence conversion layer disposed over a transparent layer of the light source and on the exterior of said light source. The multi-element light extraction and luminescence conversion layer includes a plurality of light extraction elements and a plurality of luminescence conversion elements. The light extraction elements diffuses the light from the light source while luminescence conversion elements absorbs a first spectrum of light from said light source and emits a second spectrum of light.

Chemistry of Stream Sediments and Surface Waters in New England

USGS Publications Warehouse

Robinson, Gilpin R.; Kapo, Katherine E.; Grossman, Jeffrey N.

2004-01-01

Summary -- This online publication portrays regional data for pH, alkalinity, and specific conductance for stream waters and a multi-element geochemical dataset for stream sediments collected in the New England states of Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island, and Vermont. A series of interpolation grid maps portray the chemistry of the stream waters and sediments in relation to bedrock geology, lithology, drainage basins, and urban areas. A series of box plots portray the statistical variation of the chemical data grouped by lithology and other features.

Large Eddy Simulations of Transverse Combustion Instability in a Multi-Element Injector

DTIC Science & Technology

2016-07-27

Instability in a Multi- Element Injector 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Matthew Harvazinski, Yogin...Simulations of Transverse  Combustion Instability in a Multi‐ Element  Injector 2 History Damaged engine injector  faceplate caused by combustion...Clearance #16346 3 Single  Element  Studies Short Post Marginally Stable Intermediate Post Unstable Long Post Stable Long Post Unstable CVRC Experiment

The Constellation-X Focal Plane Microcalorimeter Array: An NTD-Germanium Solution

NASA Technical Reports Server (NTRS)

Beeman, J.; Silver, E.; Bandler, S.; Schnopper, H.; Murray, S.; Madden, N.; Landis, D.; Haller, E. E.; Barbera, M.

2001-01-01

The hallmarks of Neutron Transmutation Doped (NTD) germanium cryogenic thermistors include high reliability, reproducibility, and long term stability of bulk carrier transport properties. Using micro-machined NTD Ge thermistors with integral 'flying' leads, we can now fabricate two-dimensional arrays that are built up from a series of stacked linear arrays. We believe that this modular approach of building, assembling, and perhaps replacing individual modules of detectors is essential to the successful fabrication and testing of large multi-element instruments. Details of construction are presented.

Nuclear forward scattering for high energy mössbauer transitions.

PubMed

Sergueev, I; Chumakov, A I; Beaume-Dang, T H Deschaux; Rüffer, R; Strohm, C; van Bürck, U

2007-08-31

We have studied nuclear forward scattering of synchrotron radiation for the 67.41 keV resonance of 61Ni using a silicon crystal monochromator with low-index reflections and a multielement detector. This approach can be extended to other high-energy Mössbauer transitions and does not pose any restrictions on the sample environment. Under conditions of large sample thickness and short nuclear lifetime, typical for work with high-energy nuclear resonances, the nuclear decay follows a universal dependence where both thickness effects and hyperfine interactions are taken into account by time scaling.

Multi-Element X-Ray Shields for Spacecraft

DTIC Science & Technology

1983-12-30

34 Theoretical Photoionization Crcss Sections from I to 1500 keV", UCRL-51326 (1973). Values are given for shells and subshells as well as the atomic...effect data are from Hubbell, et al.1 The photoeffect data are from Scofield 2 at 1.0 keV and greater; values at 0.5 to 1.0 keV are from Veigele.3 An...example (not requiring interpolation) is given in Table I, the case of a 100 keV x-ray on lead. Each step in the process of filling the photoionization

The utility of assessing musical preference before implementation of noncontingent music to reduce vocal stereotypy.

PubMed

Lanovaz, Marc J; Rapp, John T; Ferguson, Stéphanie

2012-01-01

We conducted a modified paired-choice preference assessment and used a multielement design to examine the effects of noncontingent access to high- and low-preference music on vocal stereotypy exhibited by children with autism. For 3 of the 4 participants, high-preference music (a) produced lower levels of vocal stereotypy than low-preference music and (b) reduced vocal stereotypy when compared to a no-interaction condition. Results underscore the potential importance of assessing musical preference prior to using noncontingent music to reduce vocal stereotypy.

Inductively Coupled Plasma Optical Emission Spectrometry for Rare Earth Elements Analysis

NASA Astrophysics Data System (ADS)

He, Man; Hu, Bin; Chen, Beibei; Jiang, Zucheng

2017-01-01

Inductively coupled plasma optical emission spectrometry (ICP-OES) merits multielements capability, high sensitivity, good reproducibility, low matrix effect and wide dynamic linear range for rare earth elements (REEs) analysis. But the spectral interference in trace REEs analysis by ICP-OES is a serious problem due to the complicated emission spectra of REEs, which demands some correction technology including interference factor method, derivative spectrum, Kalman filtering algorithm and partial least-squares (PLS) method. Matrix-matching calibration, internal standard, correction factor and sample dilution are usually employed to overcome or decrease the matrix effect. Coupled with various sample introduction techniques, the analytical performance of ICP-OES for REEs analysis would be improved. Compared with conventional pneumatic nebulization (PN), acid effect and matrix effect are decreased to some extent in flow injection ICP-OES, with higher tolerable matrix concentration and better reproducibility. By using electrothermal vaporization as sample introduction system, direct analysis of solid samples by ICP-OES is achieved and the vaporization behavior of refractory REEs with high boiling point, which can easily form involatile carbides in the graphite tube, could be improved by using chemical modifier, such as polytetrafluoroethylene and 1-phenyl-3-methyl-4-benzoyl-5-pyrazone. Laser ablation-ICP-OES is suitable for the analysis of both conductive and nonconductive solid samples, with the absolute detection limit of ng-pg level and extremely low sample consumption (0.2 % of that in conventional PN introduction). ICP-OES has been extensively employed for trace REEs analysis in high-purity materials, and environmental and biological samples.

Comparison of a portable micro-X-ray fluorescence spectrometry with inductively coupled plasma atomic emission spectrometry for the ancient ceramics analysis

NASA Astrophysics Data System (ADS)

Papadopoulou, D. N.; Zachariadis, G. A.; Anthemidis, A. N.; Tsirliganis, N. C.; Stratis, J. A.

2004-12-01

Two multielement instrumental methods of analysis, micro X-ray fluorescence spectrometry (micro-XRF) and inductively coupled plasma atomic emission spectrometry (ICP-AES) were applied for the analysis of 7th and 5th century B.C. ancient ceramic sherds in order to evaluate the above two methods and to assess the potential to use the current compact and portable micro-XRF instrument for the in situ analysis of ancient ceramics. The distinguishing factor of interest is that micro-XRF spectrometry offers the possibility of a nondestructive analysis, an aspect of primary importance in the compositional analysis of cultural objects. Micro-XRF measurements were performed firstly directly on the ceramic sherds with no special pretreatment apart from surface cleaning (micro-XRF on sherds) and secondly on pressed pellet disks which were prepared for each ceramic sherd (micro-XRF on pellet). For the ICP-AES determination of elements, test solutions were prepared by the application of a microwave-assisted decomposition procedure in closed high-pressure PFA vessels. Also, the standard reference material SARM 69 was used for the efficiency calibration of the micro-XRF instrument and was analysed by both methods. In order to verify the calibration, the standard reference materials NCS DC 73332 and SRM620 as well as the reference materials AWI-1 and PRI-1 were analysed by micro-XRF. Elemental concentrations determined by the three analytical procedures (ICP-AES, micro-XRF on sherds and micro-XRF on pellets) were statistically treated by correlation analysis and Student's t-test (at the 95% confidence level).

A Coordinated Research Project on the Implementation of Nuclear Techniques to Improve Food Traceability

NASA Astrophysics Data System (ADS)

Frew, Russell; Cannavan, Andrew; Zandric, Zora; Maestroni, Britt; Abrahim, Aiman

2013-04-01

Traceability systems play a key role in assuring a safe and reliable food supply. Analytical techniques harnessing the spatial patterns in distribution of stable isotope and trace element ratios can be used for the determination of the provenance of food. Such techniques offer the potential to enhance global trade by providing an independent means of verifying "paper" traceability systems and can also help to prove authenticity, to combat fraudulent practices, and to control adulteration, which are important issues for economic, religious or cultural reasons. To address some of the challenges that developing countries face in attempting to implement effective food traceability systems, the IAEA, through its Joint FAO/IAEA Division on Nuclear Techniques in Food and Agriculture, has initiated a 5-year coordinated research project involving institutes in 15 developing and developed countries (Austria, Botswana, Chile, China, France, India, Lebanon, Morocco, Portugal, Singapore, Sweden, Thailand, Uganda, UK, USA). The objective is to help in member state laboratories to establish robust analytical techniques and databases, validated to international standards, to determine the provenance of food. Nuclear techniques such as stable isotope and multi-element analysis, along with complementary methods, will be applied for the verification of food traceability systems and claims related to food origin, production, and authenticity. This integrated and multidisciplinary approach to strengthening capacity in food traceability will contribute to the effective implementation of holistic systems for food safety and control. The project focuses mainly on the development of techniques to confirm product authenticity, with several research partners also considering food safety issues. Research topics encompass determination of the geographical origin of a variety of commodities, including seed oils, rice, wine, olive oil, wheat, orange juice, fish, groundnuts, tea, pork, honey and coffee, the adulteration of milk with soy protein, chemical contamination of food products, and inhomogeneity in isotopic ratios in poultry and eggs as a means to determine production history. Analytical techniques include stable isotope ratio measurements (2H/1H, 13C/12C, 15N/14N, 18O/16O, 34S/32S, 87Sr/86Sr, 208Pb/207Pb/206Pb), elemental analysis, DNA fingerprinting, fatty acid and other biomolecule profiling, chromatography-mass spectrometry and near infra-red spectroscopy.

Uncertainty Measurement for Trace Element Analysis of Uranium and Plutonium Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gallimore, David L.

2012-06-13

The measurement uncertainty estimatino associated with trace element analysis of impurities in U and Pu was evaluated using the Guide to the Expression of Uncertainty Measurement (GUM). I this evalution the uncertainty sources were identified and standard uncertainties for the components were categorized as either Type A or B. The combined standard uncertainty was calculated and a coverage factor k = 2 was applied to obtain the expanded uncertainty, U. The ICP-AES and ICP-MS methods used were deveoped for the multi-element analysis of U and Pu samples. A typical analytical run consists of standards, process blanks, samples, matrix spiked samples,more » post digestion spiked samples and independent calibration verification standards. The uncertainty estimation was performed on U and Pu samples that have been analyzed previously as part of the U and Pu Sample Exchange Programs. Control chart results and data from the U and Pu metal exchange programs were combined with the GUM into a concentration dependent estimate of the expanded uncertainty. Comparison of trace element uncertainties obtained using this model was compared to those obtained for trace element results as part of the Exchange programs. This process was completed for all trace elements that were determined to be above the detection limit for the U and Pu samples.« less

NCC: A Multidisciplinary Design/Analysis Tool for Combustion Systems

NASA Technical Reports Server (NTRS)

Liu, Nan-Suey; Quealy, Angela

1999-01-01

A multi-disciplinary design/analysis tool for combustion systems is critical for optimizing the low-emission, high-performance combustor design process. Based on discussions between NASA Lewis Research Center and the jet engine companies, an industry-government team was formed in early 1995 to develop the National Combustion Code (NCC), which is an integrated system of computer codes for the design and analysis of combustion systems. NCC has advanced features that address the need to meet designer's requirements such as "assured accuracy", "fast turnaround", and "acceptable cost". The NCC development team is comprised of Allison Engine Company (Allison), CFD Research Corporation (CFDRC), GE Aircraft Engines (GEAE), NASA Lewis Research Center (LeRC), and Pratt & Whitney (P&W). This development team operates under the guidance of the NCC steering committee. The "unstructured mesh" capability and "parallel computing" are fundamental features of NCC from its inception. The NCC system is composed of a set of "elements" which includes grid generator, main flow solver, turbulence module, turbulence and chemistry interaction module, chemistry module, spray module, radiation heat transfer module, data visualization module, and a post-processor for evaluating engine performance parameters. Each element may have contributions from several team members. Such a multi-source multi-element system needs to be integrated in a way that facilitates inter-module data communication, flexibility in module selection, and ease of integration.

KENNEDY SPACE CENTER, FLA. - Workers in the Space Station Processing Facility observe consoles during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by the National Space Development Agency of Japan (NASDA), is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Workers in the Space Station Processing Facility observe consoles during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by the National Space Development Agency of Japan (NASDA), is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Technicians in the Space Station Processing Facility work on a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by the National Space Development Agency of Japan (NASDA), is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Technicians in the Space Station Processing Facility work on a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by the National Space Development Agency of Japan (NASDA), is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

Simultaneous multielement atomic absorption spectrometry with graphite furnace atomization

NASA Astrophysics Data System (ADS)

Harnly, James M.; Miller-Ihli, Nancy J.; O'Haver, Thomas C.

The extended analytical range capability of a simultaneous multielement atomic absorption continuum source spectrometer (SIMAAC) was tested for furnace atomization with respect to the signal measurement mode (peak height and area), the atomization mode (from the wall or from a platform), and the temperature program mode (stepped or ramped atomization). These parameters were evaluated with respect to the shapes of the analytical curves, the detection limits, carry-over contamination and accuracy. Peak area measurements gave more linear calibration curves. Methods for slowing the atomization step heating rate, the use of a ramped temperature program or a platform, produced similar calibration curves and longer linear ranges than atomization with a stepped temperature program. Peak height detection limits were best using stepped atomization from the wall. Peak area detection limits for all atomization modes were similar. Carry-over contamination was worse for peak area than peak height, worse for ramped atomization than stepped atomization, and worse for atomization from a platform than from the wall. Accurate determinations (100 ± 12% for Ca, Cu, Fe, Mn, and Zn in National Bureau of Standards' Standard Reference Materials Bovine Liver 1577 and Rice Flour 1568 were obtained using peak area measurements with ramped atomization from the wall and stepped atomization from a platform. Only stepped atomization from a platform gave accurate recoveries for K. Accurate recoveries, 100 ± 10%, with precisions ranging from 1 to 36 % (standard deviation), were obtained for the determination of Al, Co, Cr, Fe, Mn, Mo, Ni. Pb, V and Zn in Acidified Waters (NBS SRM 1643 and 1643a) using stepped atomization from a platform.

Multi-Element Bioimaging of Arabidopsis thaliana Roots.

PubMed

Persson, Daniel Pergament; Chen, Anle; Aarts, Mark G M; Salt, David E; Schjoerring, Jan K; Husted, Søren

2016-10-01

Better understanding of root function is central for the development of plants with more efficient nutrient uptake and translocation. We here present a method for multielement bioimaging at the cellular level in roots of the genetic model system Arabidopsis (Arabidopsis thaliana). Using conventional protocols for microscopy, we observed that diffusible ions such as potassium and sodium were lost during sample dehydration. Thus, we developed a protocol that preserves ions in their native, cellular environment. Briefly, fresh roots are encapsulated in paraffin, cryo-sectioned, and freeze dried. Samples are finally analyzed by laser ablation-inductively coupled plasma-mass spectrometry, utilizing a specially designed internal standard procedure. The method can be further developed to maintain the native composition of proteins, enzymes, RNA, and DNA, making it attractive in combination with other omics techniques. To demonstrate the potential of the method, we analyzed a mutant of Arabidopsis unable to synthesize the metal chelator nicotianamine. The mutant accumulated substantially more zinc and manganese than the wild type in the tissues surrounding the vascular cylinder. For iron, the images looked completely different, with iron bound mainly in the epidermis of the wild-type plants but confined to the cortical cell walls of the mutant. The method offers the power of inductively coupled plasma-mass spectrometry to be fully employed, thereby providing a basis for detailed studies of ion transport in roots. Being applicable to Arabidopsis, the molecular and genetic approaches available in this system can now be fully exploited in order to gain a better mechanistic understanding of these processes. © 2016 American Society of Plant Biologists. All Rights Reserved.

Multi-Element Bioimaging of Arabidopsis thaliana Roots1[OPEN

PubMed Central

Salt, David E.

2016-01-01

Better understanding of root function is central for the development of plants with more efficient nutrient uptake and translocation. We here present a method for multielement bioimaging at the cellular level in roots of the genetic model system Arabidopsis (Arabidopsis thaliana). Using conventional protocols for microscopy, we observed that diffusible ions such as potassium and sodium were lost during sample dehydration. Thus, we developed a protocol that preserves ions in their native, cellular environment. Briefly, fresh roots are encapsulated in paraffin, cryo-sectioned, and freeze dried. Samples are finally analyzed by laser ablation-inductively coupled plasma-mass spectrometry, utilizing a specially designed internal standard procedure. The method can be further developed to maintain the native composition of proteins, enzymes, RNA, and DNA, making it attractive in combination with other omics techniques. To demonstrate the potential of the method, we analyzed a mutant of Arabidopsis unable to synthesize the metal chelator nicotianamine. The mutant accumulated substantially more zinc and manganese than the wild type in the tissues surrounding the vascular cylinder. For iron, the images looked completely different, with iron bound mainly in the epidermis of the wild-type plants but confined to the cortical cell walls of the mutant. The method offers the power of inductively coupled plasma-mass spectrometry to be fully employed, thereby providing a basis for detailed studies of ion transport in roots. Being applicable to Arabidopsis, the molecular and genetic approaches available in this system can now be fully exploited in order to gain a better mechanistic understanding of these processes. PMID:27566167

[Ultra-Fine Pressed Powder Pellet Sample Preparation XRF Determination of Multi-Elements and Carbon Dioxide in Carbonate].

PubMed

Li, Xiao-li; An, Shu-qing; Xu, Tie-min; Liu, Yi-bo; Zhang, Li-juan; Zeng, Jiang-ping; Wang, Na

2015-06-01

The main analysis error of pressed powder pellet of carbonate comes from particle-size effect and mineral effect. So in the article in order to eliminate the particle-size effect, the ultrafine pressed powder pellet sample preparation is used to the determination of multi-elements and carbon-dioxide in carbonate. To prepare the ultrafine powder the FRITSCH planetary Micro Mill machine and tungsten carbide media is utilized. To conquer the conglomeration during the process of grinding, the wet grinding is preferred. The surface morphology of the pellet is more smooth and neat, the Compton scatter effect is reduced with the decrease in particle size. The intensity of the spectral line is varied with the change of the particle size, generally the intensity of the spectral line is increased with the decrease in the particle size. But when the particle size of more than one component of the material is decreased, the intensity of the spectral line may increase for S, Si, Mg, or decrease for Ca, Al, Ti, K, which depend on the respective mass absorption coefficient . The change of the composition of the phase with milling is also researched. The incident depth of respective element is given from theoretical calculation. When the sample is grounded to the particle size of less than the penetration depth of all the analyte, the effect of the particle size on the intensity of the spectral line is much reduced. In the experiment, when grounded the sample to less than 8 μm(d95), the particle-size effect is much eliminated, with the correction method of theoretical α coefficient and the empirical coefficient, 14 major, minor and trace element in the carbonate can be determined accurately. And the precision of the method is much improved with RSD < 2%, except Na2O. Carbon is ultra-light element, the fluorescence yield is low and the interference is serious. With the manual multi-layer crystal PX4, coarse collimator, empirical correction, X-ray spectrometer can be used to determine the carbon dioxide in the carbonate quantitatively. The intensity of the carbon is increase with the times of the measurement and the time delay even the pellet is stored in the dessicator. So employing the latest pressed powder pellet is suggested.

Multi-element atmospheric deposition in Macedonia studied by the moss biomonitoring technique.

PubMed

Barandovski, Lambe; Frontasyeva, Marina V; Stafilov, Trajče; Šajn, Robert; Ostrovnaya, Tatyana M

2015-10-01

Moss biomonitoring technique using moss species Homolothecium lutescens (Hedw.) Robins and Hypnum cupressiforme (Hedw.) was applied to air pollution studies in the Republic of Macedonia. The study was performed in the framework of the International Cooperative Programme on Effects of Air Pollution on Natural Vegetation and Crops under the auspices of the United Nations Economic Commission for Europe (UNECE) Convention on Long-Range Transboundary Air Pollution (LRTAP). The presence of 47 elements was determined by instrumental epithermal neutron activation analysis, atomic absorption spectrometry and atomic emission spectrometry with inductively coupled plasma. Normality of the datasets of elements was investigated, and Box-Cox transformation was used in order to achieve normal distributions of the data. Different pollution sources were identified and characterized using principal component analysis (PCA). Distribution maps were prepared to point out the regions most affected by pollution and to relate this to the known sources of contamination. The cities of Veles, Skopje, Tetovo, Radoviš and Kavadarci were determined to experience particular environmental stress. Moreover, three reactivated lead-zinc mines were also shown to contribute to a high content of lead and zinc in the eastern part of the country. However, a comparison with the previous moss survey conducted in 2005 showed a decreasing trend of pollution elements that are usually associated with emission from industrial activities.

The application of the Wigner Distribution to wave type identification in finite length beams

NASA Technical Reports Server (NTRS)

Wahl, T. J.; Bolton, J. Stuart

1994-01-01

The object of the research described in this paper was to develop a means of identifying the wave-types propagating between two points in a finite length beam. It is known that different structural wave-types possess different dispersion relations: i.e., that their group speeds and the frequency dependence of their group speeds differ. As a result of those distinct dispersion relationships, different wave-types may be associated with characteristic features when structural responses are examined in the time frequency domain. Previously, the time-frequency character of analytically generated structural responses of both single element and multi-element structures were examined by using the Wigner Distribution (WD) along with filtering techniques that were designed to detect the wave-types present in the responses. In the work to be described here, the measure time-frequency response of finite length beam is examined using the WD and filtering procedures. This paper is organized as follows. First the concept of time-frequency analysis of structural responses is explained. The WD is then introduced along with a description of the implementation of a discrete version. The time-frequency filtering techniques are then presented and explained. The results of applying the WD and the filtering techniques to the analysis of a transient response is then presented.

Unsteady characteristics of a slat-cove flow field

NASA Astrophysics Data System (ADS)

Pascioni, Kyle A.; Cattafesta, Louis N.

2018-03-01

The leading-edge slat of a multielement wing is a significant contributor to the acoustic signature of an aircraft during the approach phase of the flight path. An experimental study of the two-dimensional 30P30N geometry is undertaken to further understand the flow physics and specific noise source mechanisms. The mean statistics from particle image velocimetry (PIV) shows the differences in the flow field with angle of attack, including the interaction between the cove and trailing-edge flow. Phase-locked PIV successfully links narrow-band peaks found in the surface pressure spectrum to shear layer instabilities and also reveals that a bulk cove oscillation at a Strouhal number based on a slat chord of 0.15 exists, indicative of shear layer flapping. Unsteady surface pressure measurements are documented and used to estimate spanwise coherence length scales. A narrow-band frequency prediction scheme is also tested and found to agree well with the data. Furthermore, higher-order spectral analysis suggests that nonlinear effects cause additional peaks to arise in the power spectrum, particularly at low angles of attack.

Contrast discrimination, non-uniform patterns and change blindness.

PubMed Central

Scott-Brown, K C; Orbach, H S

1998-01-01

Change blindness--our inability to detect large changes in natural scenes when saccades, blinks and other transients interrupt visual input--seems to contradict psychophysical evidence for our exquisite sensitivity to contrast changes. Can the type of effects described as 'change blindness' be observed with simple, multi-element stimuli, amenable to psychophysical analysis? Such stimuli, composed of five mixed contrast elements, elicited a striking increase in contrast increment thresholds compared to those for an isolated element. Cue presentation prior to the stimulus substantially reduced thresholds, as for change blindness with natural scenes. On one hand, explanations for change blindness based on abstract and sketchy representations in short-term visual memory seem inappropriate for this low-level image property of contrast where there is ample evidence for exquisite performance on memory tasks. On the other hand, the highly increased thresholds for mixed contrast elements, and the decreased thresholds when a cue is present, argue against any simple early attentional or sensory explanation for change blindness. Thus, psychophysical results for very simple patterns cannot straightforwardly predict results even for the slightly more complicated patterns studied here. PMID:9872004

[Study on microwave digestion of gypsum for the determination of multielement by ICP-OES and ICP-MS].

PubMed

Wang, Hui; Song, Qiang; Yang, Rui-ming; Yao, Qiang; Chen, Chang-he

2010-09-01

Three acids (HNO3, HNO3/HF and HNO3 /HF+ H3BO3) were used to decompose gypsum with microwave digestion system. The contents of 10 mineral elements (Al, Ca, Mg, Fe, K, Na, S, Ti, Si and Sr) in gypsum were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES) while 6 heavy metals (V, Cr, Mn, Zn, Se and Ce) were determined by inductively coupled plasma-mass spectrometry (ICP-MS). GBW03109a, GBW03110 and FGD-2 were used as gypsum standard reference materials. The results showed that two-step microwave digestion with HNO3/HF at 210 degrees C and then adding H3BO3 for the removal of HF and fluorides completely decomposed the gypsums, while this method achieved good recoveries for all elements in the three gypsum standard reference materials. The recovery was from 88% to 112% and the RSD of tests was below 3%. The method was applied to the elemental analysis for flue gas desulfurization gypsums from three coal-fired power plants.

Time-Accurate Simulations and Acoustic Analysis of Slat Free-Shear-Layer. Part 2

NASA Technical Reports Server (NTRS)

Khorrami, Mehdi R.; Singer, Bart A.; Lockard, David P.

2002-01-01

Unsteady computational simulations of a multi-element, high-lift configuration are performed. Emphasis is placed on accurate spatiotemporal resolution of the free shear layer in the slat-cove region. The excessive dissipative effects of the turbulence model, so prevalent in previous simulations, are circumvented by switching off the turbulence-production term in the slat cove region. The justifications and physical arguments for taking such a step are explained in detail. The removal of this excess damping allows the shear layer to amplify large-scale structures, to achieve a proper non-linear saturation state, and to permit vortex merging. The large-scale disturbances are self-excited, and unlike our prior fully turbulent simulations, no external forcing of the shear layer is required. To obtain the farfield acoustics, the Ffowcs Williams and Hawkings equation is evaluated numerically using the simulated time-accurate flow data. The present comparison between the computed and measured farfield acoustic spectra shows much better agreement for the amplitude and frequency content than past calculations. The effect of the angle-of-attack on the slat's flow features radiated acoustic field are also simulated presented.

Seasonal determination of trace and ultra-trace content in Macrocystis pyrifera from San Jorge Gulf (Patagonia) by Total Reflection X-ray Fluorescence

NASA Astrophysics Data System (ADS)

Salomone, Vanesa N.; Riera, Marina; Cerchietti, Luciana; Custo, Graciela; Muniain, Claudia

2017-05-01

Seaweed have a great capacity to accumulate heavy metals in their tissues. The chemical characterization of seaweed is important due to their use in environmental monitoring and human or animal food. The aim of the present study was to evaluate the multi-elemental composition of seaweed from San Jorge Gulf (Patagonia, Argentina) by Total Reflection X-ray Fluorescence (TXRF). The elements As, Br, Cu, Cr, Fe, Mn, Ni, Pb, Rb, Sr, V and Zn were seasonally analyzed and quantified in blades of Macrocystis pyrifera. TXRF showed to be a suitable technique for simultaneous multi-element analysis in this kind of samples. The results revealed seasonal variations in the chemical content for some elements; arsenic content was maximum in summer and autumn, iron concentration increased to the winter and zinc concentration was maximum in autumn. The sum of principal micronutrients (Fe + Zn + Mn + Cu) varied between 114 and 171 mg k- 1 g dw. The total As concentration ranged between 36 and 66 mg kg- 1. Lead, nickel and copper were not detected.

Analysis of the performance of a wireless optical multi-input to multi-output communication system.

PubMed

Bushuev, Denis; Arnon, Shlomi

2006-07-01

We investigate robust optical wireless communication in a highly scattering propagation medium using multielement optical detector arrays. The communication setup consists of synchronized multiple transmitters that send information to a receiver array and an atmospheric propagation channel. The mathematical model that best describes this scenario is multi-input to multi-output communication through stochastic slow changing channels. In this model, signals from m transmitters are received by n receiver-detectors. The channel transfer function matrix is G, and its size is n x m. G(i,j) is the transfer function from transmitter i to detector j, and m > or = n. We adopt a quasi-stationary approach in which the channel time variation has a negligible effect on communication performance over a burst. The G matrix is calculated on the basis of the optical transfer function of the atmospheric channel (composed of aerosol and turbulence elements) and the receiver's optics. In this work we derive a performance model using environmental data, such as documented turbulence and aerosol models and noise statistics. We also present the results of simulations conducted for the proposed detection algorithm.

Split Flow Online Solid-Phase Extraction Coupled with Inductively Coupled Plasma Mass Spectrometry System for One-Shot Data Acquisition of Quantification and Recovery Efficiency.

PubMed

Furukawa, Makoto; Takagai, Yoshitaka

2016-10-04

Online solid-phase extraction (SPE) coupled with inductively coupled plasma mass spectrometry (ICPMS) is a useful tool in automatic sequential analysis. However, it cannot simultaneously quantify the analytical targets and their recovery percentages (R%) in one-shot samples. We propose a system that simultaneously acquires both data in a single sample injection. The main flowline of the online solid-phase extraction is divided into main and split flows. The split flow line (i.e., bypass line), which circumvents the SPE column, was placed on the main flow line. Under program-controlled switching of the automatic valve, the ICPMS sequentially measures the targets in a sample before and after column preconcentration and determines the target concentrations and the R% on the SPE column. This paper describes the system development and two demonstrations to exhibit the analytical significance, i.e., the ultratrace amounts of radioactive strontium ( 90 Sr) using commercial Sr-trap resin and multielement adsorbability on the SPE column. This system is applicable to other flow analyses and detectors in online solid phase extraction.

Unsteady Analyses of Valve Systems in Rocket Engine Testing Environments

NASA Technical Reports Server (NTRS)

Shipman, Jeremy; Hosangadi, Ashvin; Ahuja, Vineet

2004-01-01

This paper discusses simulation technology used to support the testing of rocket propulsion systems by performing high fidelity analyses of feed system components. A generalized multi-element framework has been used to perform simulations of control valve systems. This framework provides the flexibility to resolve the structural and functional complexities typically associated with valve-based high pressure feed systems that are difficult to deal with using traditional Computational Fluid Dynamics (CFD) methods. In order to validate this framework for control valve systems, results are presented for simulations of a cryogenic control valve at various plug settings and compared to both experimental data and simulation results obtained at NASA Stennis Space Center. A detailed unsteady analysis has also been performed for a pressure regulator type control valve used to support rocket engine and component testing at Stennis Space Center. The transient simulation captures the onset of a modal instability that has been observed in the operation of the valve. A discussion of the flow physics responsible for the instability and a prediction of the dominant modes associated with the fluctuations is presented.

Study on the influence of X-ray tube spectral distribution on the analysis of bulk samples and thin films: Fundamental parameters method and theoretical coefficient algorithms

NASA Astrophysics Data System (ADS)

Sitko, Rafał

2008-11-01

Knowledge of X-ray tube spectral distribution is necessary in theoretical methods of matrix correction, i.e. in both fundamental parameter (FP) methods and theoretical influence coefficient algorithms. Thus, the influence of X-ray tube distribution on the accuracy of the analysis of thin films and bulk samples is presented. The calculations are performed using experimental X-ray tube spectra taken from the literature and theoretical X-ray tube spectra evaluated by three different algorithms proposed by Pella et al. (X-Ray Spectrom. 14 (1985) 125-135), Ebel (X-Ray Spectrom. 28 (1999) 255-266), and Finkelshtein and Pavlova (X-Ray Spectrom. 28 (1999) 27-32). In this study, Fe-Cr-Ni system is selected as an example and the calculations are performed for X-ray tubes commonly applied in X-ray fluorescence analysis (XRF), i.e., Cr, Mo, Rh and W. The influence of X-ray tube spectra on FP analysis is evaluated when quantification is performed using various types of calibration samples. FP analysis of bulk samples is performed using pure-element bulk standards and multielement bulk standards similar to the analyzed material, whereas for FP analysis of thin films, the bulk and thin pure-element standards are used. For the evaluation of the influence of X-ray tube spectra on XRF analysis performed by theoretical influence coefficient methods, two algorithms for bulk samples are selected, i.e. Claisse-Quintin (Can. Spectrosc. 12 (1967) 129-134) and COLA algorithms (G.R. Lachance, Paper Presented at the International Conference on Industrial Inorganic Elemental Analysis, Metz, France, June 3, 1981) and two algorithms (constant and linear coefficients) for thin films recently proposed by Sitko (X-Ray Spectrom. 37 (2008) 265-272).

Crossflow vorticity sensor

NASA Technical Reports Server (NTRS)

Holmes, Bruce J. (Inventor); Carraway, Debra L. (Inventor); Holmes, Harlan K. (Inventor); Moore, Thomas C. (Inventor)

1988-01-01

A crossflow vorticity sensor for the detection of crossflow vorticity characteristics is described. The sensor is comprised of crossflow sensors which are noninvasively adhered to a swept wing laminar surface either singularly, in multi-element strips, in polar patterns, or in orthogonal patterns. These crossflow sensors are comprised of hot-film sensor elements which operate as a constant temperature anemometer circuit to detect heat transfer rate changes. Accordingly, crossflow vorticity characteristics are determined via cross-correlation. In addition, the crossflow sensors have a thickness which does not exceed a maximum value h in order to avoid contamination of downstream crossflow sensors.

Diode amplifier of modulated optical beam power

DOE Office of Scientific and Technical Information (OSTI.GOV)

D'yachkov, N V; Bogatov, A P; Gushchik, T I

2014-11-30

Analytical relations are obtained between characteristics of modulated light at the output and input of an optical diode power amplifier operating in the highly saturated gain regime. It is shown that a diode amplifier may act as an amplitude-to-phase modulation converter with a rather large bandwidth (∼10 GHz). The low sensitivity of the output power of the amplifier to the input beam power and its high energy efficiency allow it to be used as a building block of a high-power multielement laser system with coherent summation of a large number of optical beams. (lasers)

A linear photodiode array employed in a short range laser triangulation obstacle avoidance sensor. M.S. Thesis; [Martian roving vehicle sensor

NASA Technical Reports Server (NTRS)

Odenthal, J. P.

1980-01-01

An opto-electronic receiver incorporating a multi-element linear photodiode array as a component of a laser-triangulation rangefinder was developed as an obstacle avoidance sensor for a Martian roving vehicle. The detector can resolve the angle of laser return in 1.5 deg increments within a field of view of 30 deg and a range of five meters. A second receiver with a 1024 elements over 60 deg and a 3 meter range is also documented. Design criteria, circuit operation, schematics, experimental results and calibration procedures are discussed.

Wall-modeled large eddy simulation of high-lift devices from low to post-stall angle of attacks

NASA Astrophysics Data System (ADS)

Bodart, Julien; Larsson, Johan; Moin, Parviz

2013-11-01

The flow around a McDonnell-Douglas 30P/30N multi-element airfoil at the flight Reynolds number of 9 million (based on chord) is computed using LES with an equilibrium wall-model with special treatment for transitional flows. Several different angles of attack are considered, up to and including stall, challenging the wall-model in several flow regimes. The maximum lift coefficient, which is generally difficult to predict with RANS approaches, is accurately predicted, as compared to experiments performed in the NASA LPT wind-tunnel. NASA grant: NNX11AI60A.

Algorithm Sorts Groups Of Data

NASA Technical Reports Server (NTRS)

Evans, J. D.

1987-01-01

For efficient sorting, algorithm finds set containing minimum or maximum most significant data. Sets of data sorted as desired. Sorting process simplified by reduction of each multielement set of data to single representative number. First, each set of data expressed as polynomial with suitably chosen base, using elements of set as coefficients. Most significant element placed in term containing largest exponent. Base selected by examining range in value of data elements. Resulting series summed to yield single representative number. Numbers easily sorted, and each such number converted back to original set of data by successive division. Program written in BASIC.

Micromechanical Switches on GaAs for Microwave Applications

NASA Technical Reports Server (NTRS)

Randall, John N.; Goldsmith, Chuck; Denniston, David; Lin, Tsen-Hwang

1995-01-01

In this presentation, we describe the fabrication of micro-electro-mechanical system (MEMS) devices, in particular, of low-frequency multi-element electrical switches using SiO2 cantilevers. The switches discussed are related to micromechanical membrane structures used to perform switching of optical signals on silicon substrates. These switches use a thin metal membrane which is actuated by an electrostatic potential, causing the switch to make or break contact. The advantages include: superior isolation, high power handling capabilities, high radiation hardening, very low power operations, and the ability to integrate onto GaAs monolithic microwave integrated circuit (MMIC) chips.

Radiation detector having a multiplicity of individual detecting elements

DOEpatents

Whetten, Nathan R.; Kelley, John E.

1985-01-01

A radiation detector has a plurality of detector collection element arrays immersed in a radiation-to-electron conversion medium. Each array contains a multiplicity of coplanar detector elements radially disposed with respect to one of a plurality of positions which at least one radiation source can assume. Each detector collector array is utilized only when a source is operative at the associated source position, negating the necessity for a multi-element detector to be moved with respect to an object to be examined. A novel housing provides the required containment of a high-pressure gas conversion medium.

32 bit digital optical computer - A hardware update

NASA Technical Reports Server (NTRS)

Guilfoyle, Peter S.; Carter, James A., III; Stone, Richard V.; Pape, Dennis R.

1990-01-01

Such state-of-the-art devices as multielement linear laser diode arrays, multichannel acoustooptic modulators, optical relays, and avalanche photodiode arrays, are presently applied to the implementation of a 32-bit supercomputer's general-purpose optical central processing architecture. Shannon's theorem, Morozov's control operator method (in conjunction with combinatorial arithmetic), and DeMorgan's law have been used to design an architecture whose 100 MHz clock renders it fully competitive with emerging planar-semiconductor technology. Attention is given to the architecture's multichannel Bragg cells, thermal design and RF crosstalk considerations, and the first and second anamorphic relay legs.

Multi-element array signal reconstruction with adaptive least-squares algorithms

NASA Technical Reports Server (NTRS)

Kumar, R.

1992-01-01

Two versions of the adaptive least-squares algorithm are presented for combining signals from multiple feeds placed in the focal plane of a mechanical antenna whose reflector surface is distorted due to various deformations. Coherent signal combining techniques based on the adaptive least-squares algorithm are examined for nearly optimally and adaptively combining the outputs of the feeds. The performance of the two versions is evaluated by simulations. It is demonstrated for the example considered that both of the adaptive least-squares algorithms are capable of offsetting most of the loss in the antenna gain incurred due to reflector surface deformations.

Ultrafast IR detector response in high Tc superconducting thin films

NASA Technical Reports Server (NTRS)

Lindgren, Mikael; Ahlberg, Henrik; Danerud, Martin; Larsson, Anders; Eng, Sverre T.

1991-01-01

The response from a high Tc superconducting multielement optical detector made of a laser deposited Y-Ba-Cu-O thin film has been evaluated. Several microscopic and spectroscopic techniques were used to establish the presence of the correct phase of the thin film. Optical pulses from a laser diode at 830 nm and from a Q-switched CO2-laser at 10.6 microns were used. The detector responded to 50 ps (FWHM) pulses. A comparison between dR/dT of the film and the response amplitude as a function of temperature indicated a bolometric response.

Selective conversion of {Mo132} Keplerate ion into 4-electron reduced crown-capped Keggin derivative [Te5Mo15O57](8-). A key intermediate to single-phase M1 multielement MoVTeO light-alkanes oxidation catalyst.

PubMed

Canioni, Romain; Marchal-Roch, Catherine; Leclerc-Laronze, Nathalie; Haouas, Mohamed; Taulèlle, Francis; Marrot, Jérôme; Paul, Sebastien; Lamonier, Carole; Paul, Jean-François; Loridant, Stéphane; Millet, Jean-Marc M; Cadot, Emmanuel

2011-06-14

{Mo(132)} Keplerate anion reacts with tellurites to give a soluble precursor to produce in hydrothermal conditions single-phase M1 MoVTeO light-alkanes oxidation catalyst. Characterization of this Te-containing intermediate by single-crystal X-ray diffraction, (125)Te NMR, UV-visible and redox titration reveals a molybdotellurite anion as a crown-capped Keggin derivative. This journal is © The Royal Society of Chemistry 2011

Integration Testing of Space Flight Systems

NASA Technical Reports Server (NTRS)

Honeycutt, Timothy; Sowards, Stephanie

2008-01-01

Based on the previous success' of Multi-Element Integration Testing (MEITs) for the International Space Station Program, these type of integrated tests have also been planned for the Constellation Program: MEIT (1) CEV to ISS (emulated) (2) CEV to Lunar Lander/EDS (emulated) (3) Future: Lunar Surface Systems and Mars Missions Finite Element Integration Test (FEIT) (1) CEV/CLV (2) Lunar Lander/EDS/CaL V Integrated Verification Tests (IVT) (1) Performed as a subset of the FEITs during the flight tests and then performed for every flight after Full Operational Capability (FOC) has been obtained with the flight and ground Systems.

A Smart Eddy Current Sensor Dedicated to the Nondestructive Evaluation of Carbon Fibers Reinforced Polymers.

PubMed

Naidjate, Mohammed; Helifa, Bachir; Feliachi, Mouloud; Lefkaier, Iben-Khaldoun; Heuer, Henning; Schulze, Martin

2017-08-31

This paper propose a new concept of an eddy current (EC) multi-element sensor for the characterization of carbon fiber-reinforced polymers (CFRP) to evaluate the orientations of plies in CFRP and the order of their stacking. The main advantage of the new sensors is the flexible parametrization by electronical switching that reduces the effort for mechanical manipulation. The sensor response was calculated and proved by 3D finite element (FE) modeling. This sensor is dedicated to nondestructive testing (NDT) and can be an alternative for conventional mechanical rotating and rectangular sensors.

A Surrogate Approach to the Experimental Optimization of Multielement Airfoils

NASA Technical Reports Server (NTRS)

Otto, John C.; Landman, Drew; Patera, Anthony T.

1996-01-01

The incorporation of experimental test data into the optimization process is accomplished through the use of Bayesian-validated surrogates. In the surrogate approach, a surrogate for the experiment (e.g., a response surface) serves in the optimization process. The validation step of the framework provides a qualitative assessment of the surrogate quality, and bounds the surrogate-for-experiment error on designs "near" surrogate-predicted optimal designs. The utility of the framework is demonstrated through its application to the experimental selection of the trailing edge ap position to achieve a design lift coefficient for a three-element airfoil.

High-voltage R-F feedthrough bushing

DOEpatents

Grotz, G.F.

1982-09-03

Described is a multi-element, high voltage radio frequency bushing for transmitting rf energy to an antenna located in a vacuum container. The bushing includes a center conductor of complex geometrical shape, an outer coaxial shield conductor, and a thin-walled hollow truncated cone insulator disposed between central and outer conductors. The shape of the center conductor, which includes a reverse curvature portion formed of a radially inwardly directed shoulder and a convex portion, controls the uniformity of the axial surface gradient on the insulator cone. The outer shield has a first substantially cylindrical portion and a second radially inwardly extending truncated cone portion.

High voltage RF feedthrough bushing

DOEpatents

Grotz, Glenn F.

1984-01-01

Described is a multi-element, high voltage radio frequency bushing for trmitting RF energy to an antenna located in a vacuum container. The bushing includes a center conductor of complex geometrical shape, an outer coaxial shield conductor, and a thin-walled hollow truncated cone insulator disposed between central and outer conductors. The shape of the center conductor, which includes a reverse curvature portion formed of a radially inwardly directed shoulder and a convex portion, controls the uniformity of the axial surface gradient on the insulator cone. The outer shield has a first substantially cylindrical portion and a second radially inwardly extending truncated cone portion.

Soil properties, strontium isotopic signatures and multi-element profiles to authenticate the origin of vegetables from small-scale regions: illustration with early potatoes from southern Italy.

PubMed

Zampella, Mariavittoria; Quétel, Christophe R; Paredes, Eduardo; Goitom Asfaha, Daniel; Vingiani, Simona; Adamo, Paola

2011-10-15

We propose a method for the authentication of the origin of vegetables grown under similar weather conditions, in sites less than 10 km distance from the sea and distributed over a rather small scale area (58651 km(2)). We studied how the strontium (Sr) isotopic signature and selected elemental concentrations ([Mn], [Cu], [Zn], [Rb], [Sr] and [Cd]) in early potatoes from three neighbouring administrative regions in the south of Italy were related to the geological substrate (alluvial sediments, volcanic substrates and carbonate rocks) and to selected soil chemical properties influencing the bioavailability of elements in soils (pH, cation exchange capacity and total carbonate content). Through multiple-step multivariate statistics (PLS-DA) we could assign 26 potatoes (including two already commercialised samples) to their respective eight sites of production, corresponding to the first two types of geological substrates. The other 12 potatoes from four sites of production had similar characteristics in terms of the geological substrate (third type) and these soil properties could be grouped together. In this case, more discriminative parameters would be required to allow the differentiation between sites. The validation of our models included external prediction tests with data of potatoes harvested the year before and a study on the robustness of the uncertainties of the measurement results. Annual variations between multi-elemental and Sr isotopic fingerprints were observed in potatoes harvested from soils overlying carbonate rocks, stressing the importance of testing long term variations in authentication studies. Copyright © 2011 John Wiley & Sons, Ltd. and European Union [2011].

Friction Stir Weld Inspection Through Conductivity Imaging Using Shaped Field MWM(Registered Trademark) - Arrays

NASA Technical Reports Server (NTRS)

Goldfine, Neil; Grundy, David; Zilberstein, Vladimir; Kinchen, David G.; McCool, Alex (Technical Monitor)

2002-01-01

Friction Stir Welds (FSW) of Al 2195-T8 and Al 2219-T8, provided by Lockheed Martin Michoud Operations, were inspected for lack-of-penetration (LOP) defects using a custom designed MWM-Array, a multi-element eddy-current sensor. MWM (registered trademark) electrical conductivity mapping demonstrated high sensitivity to LOP as small as 0.75 mm (0.03 in.), as confirmed by metallographic data that characterized the extent of LOP defects. High sensitivity and high spatial resolution was achieved via a 37-element custom designed MWM-Array allowing LOP detection using the normalized longitudinal component of the MWM measured conductivity. This permitted both LOP detection and correlation of MWM conductivity features with the LOP defect size, as changes in conductivity were apparently associated with metallurgical features within the near-surface layer of the LOP defect zone. MWM conductivity mapping reveals information similar to macro-etching as the MWM-Array is sensitive to small changes in conductivity due to changes in microstructure associated with material thermal processing, in this case welding. The electrical conductivity measured on the root side of FSWs varies across the weld due to microstructural differences introduced by the FSW process, as well as those caused by planar flaws. Weld metal, i.e., dynamically recrystallized zone (DXZ), thermomechanically affected zone (TMZ), heat-affected zone (HAZ), and parent metal (PM) are all evident in the conductivity maps. While prior efforts had met with limited success for NDE (Nondestructive Evaluation) of dissimilar alloy, Al2219 to Al2195 FSW, the new custom designed multi-element MWM-Array achieved detection of all LOP defects even in dissimilar metal welds.

KENNEDY SPACE CENTER, FLA. - Workers in the Space Station Processing Facility look over paperwork during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by the National Space Development Agency of Japan (NASDA), is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Workers in the Space Station Processing Facility look over paperwork during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by the National Space Development Agency of Japan (NASDA), is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), works at a console during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), works at a console during a Multi-Element Integrated Test (MEIT) of the U.S. Node 2 and the Japanese Experiment Module (JEM). Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), is inside the Japanese Experiment Module (JEM), undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), is inside the Japanese Experiment Module (JEM), undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), rests inside the Japanese Experiment Module (JEM), undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), rests inside the Japanese Experiment Module (JEM), undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi (right), with the National Space Development Agency of Japan (NASDA), is inside the Japanese Experiment Module (JEM), undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi (right), with the National Space Development Agency of Japan (NASDA), is inside the Japanese Experiment Module (JEM), undergoing a Multi-Element Integrated Test (MEIT) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), signals success during a Multi-Element Integrated Test (MEIT ) of the Japanese Experiment Module (JEM) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Astronaut Soichi Noguchi, with the National Space Development Agency of Japan (NASDA), signals success during a Multi-Element Integrated Test (MEIT ) of the Japanese Experiment Module (JEM) in the Space Station Processing Facility. Noguchi is assigned to mission STS-114 as a mission specialist. Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The JEM, developed by NASDA, is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

Airborne ultrasonic phased arrays using ferroelectrets: a new fabrication approach.

PubMed

Ealo, Joao L; Camacho, Jorge J; Fritsch, Carlos

2009-04-01

In this work, a novel procedure that considerably simplifies the fabrication process of ferroelectret-based multielement array transducers is proposed and evaluated. Also, the potential of ferroelectrets being used as active material for air-coupled ultrasonic transducer design is demonstrated. The new construction method of multi-element transducers introduces 2 distinctive improvements. First, active ferroelectret material is not discretized into elements, and second, the need of structuring upper and/or lower electrodes in advance of the permanent polarization of the film is removed. The aperture discretization and the mechanical connection are achieved in one step using a through-thickness conductive tape. To validate the procedure, 2 linear array prototypes of 32 elements, with a pitch of 3.43 mm and a wide usable frequency range from 30 to 300 kHz, were built and evaluated using a commercial phased-array system. A low crosstalk among elements, below -30 dB, was measured by interferometry. Likewise, a homogeneous response of the array elements, with a maximum deviation of +/-1.8 dB, was obtained. Acoustic beam steering measurements were accomplished at different deflection angles using a calibrated microphone. The ultrasonic beam parameters, namely, lateral resolution, side lobe level, grating lobes, and focus depth, were congruent with theory. Acoustic images of a single reflector were obtained using one of the array elements as the receiver. Resulting images are also in accordance with numerical simulation, demonstrating the feasibility of using these arrays in pulse-echo mode. The proposed procedure simplifies the manufacturing of multidimensional arrays with arbitrary shape elements and not uniformly distributed. Furthermore, this concept can be extended to nonflat arrays as long as the transducer substrate conforms to a developable surface.

Hydrogen Isotope Fractionation during the Biodegradation of 1,2-Dichloroethane: Potential for Pathway Identification Using a Multi-element (C, Cl, and H) Isotope Approach.

PubMed

Palau, Jordi; Shouakar-Stash, Orfan; Hatijah Mortan, Siti; Yu, Rong; Rosell, Monica; Marco-Urrea, Ernest; Freedman, David L; Aravena, Ramon; Soler, Albert; Hunkeler, Daniel

2017-09-19

Even though multi-element isotope fractionation patterns provide crucial information with which to identify contaminant degradation pathways in the field, those involving hydrogen are still lacking for many halogenated groundwater contaminants and degradation pathways. This study investigates for the first time hydrogen isotope fractionation during both aerobic and anaerobic biodegradation of 1,2-dichloroethane (1,2-DCA) using five microbial cultures. Transformation-associated isotope fractionation values (ε bulk H ) were -115 ± 18‰ (aerobic C-H bond oxidation), -34 ± 4‰ and -38 ± 4‰ (aerobic C-Cl bond cleavage via hydrolytic dehalogenation), and -57 ± 3‰ and -77 ± 9‰ (anaerobic C-Cl bond cleavage via reductive dihaloelimination). The dual-element C-H isotope approach (Λ C-H = Δδ 2 H/Δδ 13 C ≈ ε bulk H /ε bulk C , where Δδ 2 H and Δδ 13 C are changes in isotope ratios during degradation) resulted in clearly different Λ C-H values: 28 ± 4 (oxidation), 0.7 ± 0.1 and 0.9 ± 0.1 (hydrolytic dehalogenation), and 1.76 ± 0.05 and 3.5 ± 0.1 (dihaloelimination). This result highlights the potential of this approach to identify 1,2-DCA degradation pathways in the field. In addition, distinct trends were also observed in a multi- (i.e., Δδ 2 H versus Δδ 37 Cl versus Δδ 13 C) isotope plot, which opens further possibilities for pathway identification in future field studies. This is crucial information to understand the mechanisms controlling natural attenuation of 1,2-DCA and to design appropriate strategies to enhance biodegradation.

Scoresum - A technique for displaying and evaluating multi-element geochemical information, with examples of its use in regional mineral assessment programs

USGS Publications Warehouse

Chaffee, M.A.

1983-01-01

A technique called SCORESUM was developed to display a maximum of multi-element geochemical information on a minimum number of maps for mineral assessment purposes. The technique can be done manually for a small analytical data set or can be done with a computer for a large data set. SCORESUM can be used with highly censored data and can also weight samples so as to minimize the chemical differences of diverse lithologies in different parts of a given study area. The full range of reported analyses for each element of interest in a data set is divided into four categories. Anomaly scores - values of O (background), 1 (weakly anomalous), 2 (moderately anomalous), and 3 (strongly anomalous) - are substituted for all of the analyses falling into each of the four categories. A group of elements based on known or suspected association in altered or mineralized areas is selected for study and the anomaly scores for these elements are summed for each sample site and then plotted on a map. Some of the results of geochemical studies conducted for mineral assessments in two areas are briefly described. The first area, the Mokelumne Wilderness and vicinity, is a relatively small and geologically simple one. The second, the Walker Lake 1?? ?? 2?? quadrangle, is a large area that has extremely complex geology and that contains a number of different mineral deposit environments. These two studies provide examples of how the SCORESUM technique has been used (1) to enhance relatively small but anomalous areas and (2) to delineate and rank areas containing geochemical signatures for specific suites of elements related to certain types of alteration or mineralization. ?? 1983.

Modelling of the acoustic field of a multi-element HIFU array scattered by human ribs

NASA Astrophysics Data System (ADS)

Gélat, Pierre; ter Haar, Gail; Saffari, Nader

2011-09-01

The efficacy of high-intensity focused ultrasound (HIFU) for the treatment of a range of different cancers, including those of the liver, prostate and breast, has been demonstrated. As a non-invasive focused therapy, HIFU offers considerable advantages over techniques such as chemotherapy and surgical resection in terms of reduced risk of harmful side effects. Despite this, there are a number of significant challenges which currently hinder its widespread clinical application. One of these challenges is the need to transmit sufficient energy through the rib cage to induce tissue necrosis in the required volume whilst minimizing the formation of side lobes. Multi-element random-phased arrays are currently showing great promise in overcoming the limitations of single-element transducers. Nevertheless, successful treatment of a patient with liver tumours requires a thorough understanding of the way in which the ultrasonic pressure field from a HIFU array is scattered by the rib cage. In order to address this, a boundary element approach based on a generalized minimal residual (GMRES) implementation of the Burton-Miller formulation was used in conjunction with phase conjugation techniques to focus the field of a 256-element random HIFU array behind human ribs at locations requiring intercostal and transcostal treatment. Simulations were carried out on a 3D mesh of quadratic pressure patches generated using CT scan anatomical data for adult ribs 9-12 on the right side. The methodology was validated on spherical and cylindrical scatterers. Field calculations were also carried out for idealized ribs, consisting of arrays of strip-like scatterers, demonstrating effects of splitting at the focus. This method has the advantage of fully accounting for the effect of scattering and diffraction in 3D under continuous wave excitation.

Hot-Fire Test Results of Liquid Oxygen/RP-2 Multi-Element Oxidizer-Rich Preburners

NASA Technical Reports Server (NTRS)

Protz, C. S.; Garcia, C. P.; Casiano, M. J.; Parton, J. A.; Hulka, J. R.

2016-01-01

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. To supply the oxidizer-rich combustion products to the main injector of the integrated test article, existing subscale preburner injectors from a previous NASA-funded oxidizer-rich staged combustion engine development program were utilized. For the integrated test article, existing and newly designed and fabricated inter-connecting hot gas duct hardware were used to supply the oxidizer-rich combustion products to the oxidizer circuit of the main injector of the thrust chamber. However, before one of the preburners was used in the integrated test article, it was first hot-fire tested at length to prove it could provide the hot exhaust gas mean temperature, thermal uniformity and combustion stability necessary to perform in the integrated test article experiment. This paper presents results from hot-fire testing of several preburner injectors in a representative combustion chamber with a sonic throat. Hydraulic, combustion performance, exhaust gas thermal uniformity, and combustion stability data are presented. Results from combustion stability modeling of these test results are described in a companion paper at this JANNAF conference, while hot-fire test results of the preburner injector in the integrated test article are described in another companion paper.

Recombinant Escherichia coli as a biofactory for various single- and multi-element nanomaterials.

PubMed

Choi, Yoojin; Park, Tae Jung; Lee, Doh C; Lee, Sang Yup

2018-06-05

Nanomaterials (NMs) are mostly synthesized by chemical and physical methods, but biological synthesis is also receiving great attention. However, the mechanisms for biological producibility of NMs, crystalline versus amorphous, are not yet understood. Here we report biosynthesis of 60 different NMs by employing a recombinant Escherichia coli strain coexpressing metallothionein, a metal-binding protein, and phytochelatin synthase that synthesizes a metal-binding peptide phytochelatin. Both an in vivo method employing live cells and an in vitro method employing the cell extract are used to synthesize NMs. The periodic table is scanned to select 35 suitable elements, followed by biosynthesis of their NMs. Nine crystalline single-elements of Mn 3 O 4 , Fe 3 O 4 , Cu 2 O, Mo, Ag, In(OH) 3 , SnO 2 , Te, and Au are synthesized, while the other 16 elements result in biosynthesis of amorphous NMs or no NM synthesis. Producibility and crystallinity of the NMs are analyzed using a Pourbaix diagram that predicts the stable chemical species of each element for NM biosynthesis by varying reduction potential and pH. Based on the analyses, the initial pH of reactions is changed from 6.5 to 7.5, resulting in biosynthesis of various crystalline NMs of those previously amorphous or not-synthesized ones. This strategy is extended to biosynthesize multi-element NMs including CoFe 2 O 4 , NiFe 2 O 4 , ZnMn 2 O 4 , ZnFe 2 O 4 , Ag 2 S, Ag 2 TeO 3 , Ag 2 WO 4 , Hg 3 TeO 6 , PbMoO 4, PbWO 4 , and Pb 5 (VO 4 ) 3 OH NMs. The strategy described here allows biosynthesis of NMs with various properties, providing a platform for manufacturing various NMs in an environmentally friendly manner.

Plume magmatism and crustal growth at 2.9 to 3.0 Ga in the Steep Rock and Lumby Lake area, Western Superior Province

NASA Astrophysics Data System (ADS)

Tomlinson, K. Y.; Hughes, D. J.; Thurston, P. C.; Hall, R. P.

1999-01-01

The greenstone belts of the western Superior Province are predominantly 2.78 to 2.69 Ga and provide evidence of oceanic and arc volcanism during the accretionary phase of development of the Superior Province. There is also scattered evidence of Meso-Archean crust (predominantly 2.9 to 3.0 Ga) within the western Superior Province. The Meso-Archean greenstone belts commonly contain platformal sediments and unconformably overlie granitoid basement. The platformal sediments occur associated with komatiitic and tholeiitic volcanic rocks that suggest a history of magmatism associated with rifting during the Meso-Archean. The central Wabigoon Subprovince is a key area of Meso-Archean crust and in its southern portion comprises the Steep Rock, Finlayson and Lumby Lake greenstone belts. The Steep Rock greenstone belt unconformably overlies 3 Ga continental basement and contains platformal sediments succeeded by komatiitic and tholeiitic volcanic rocks. The Lumby Lake greenstone belt contains thick sequences of mafic volcanics, a number of komatiite horizons, and thin platformal sedimentary units. The two belts are joined by the predominantly mafic volcanic Finlayson greenstone belt. The volcanics throughout these three greenstone belts may be correlated to some extent and a range of basaltic and komatiite types is present. Al-undepleted komatiites present in the Lumby Lake greenstone belt have an Al 2O 3/TiO 2 ratio ranging from 14 to 27 and (Gd/Yb) N from 0.7 to 1.3. These are divided into basaltic komatiites with generally unfractionated mantle-normalised multi-element profiles, and spinifex-textured high-Mg basalts with slightly light REE enriched multi-element profiles and small negative Nb and Ta anomalies. The unfractionated basaltic komatiites represent high degree partial melts of the upper mantle whereas the spinifex-textured high-Mg basalts represent evolutionary products of the komatiite liquids following olivine and chromite fractionation and crustal contamination. Al-depleted komatiites are present in both the Lumby Lake and Steep Rock belts and have Al 2O 3/TiO 2 ratio ranges from 2.5 to 5. These display strong enrichment in the light REE and Nb and strong depletion in the heavy REE and Y ((Gd/Yb) N=2-4). They represent a deep mantle plume source generated from a high degree of partial melting in the majorite garnet stability field. The basaltic flows in all three greenstone belts are predominantly slightly light REE depleted and represent a slightly depleted upper mantle source. Basalts spatially associated with the unfractionated basaltic komatiites and the slightly light REE enriched spinifex-textured high-Mg basalts are also slightly enriched in light REE and have negative Nb and Ta anomalies. These basalts represent evolved products of the primitive basaltic komatiites and enriched spinifex-textured high-Mg basalts after further crustal contamination and olivine and clinopyroxene fractionation. The geochemical stratigraphy in the Lumby Lake belt is consistent with an ascending mantle plume model. The light REE depleted basalts were derived from upper mantle melted by an ascending mantle plume. These are overlain by the unfractionated basaltic komatiites and their evolutionary products which represent hotter plume head material derived from a mixture of plume mantle and entrained depleted upper mantle. In turn, these are overlain by strongly light REE and HFSE enriched komatiites that represent a deep plume source that has not been mixed with depleted mantle and are, therefore, likely to have been derived from a plume core or tail. Volcanism was protracted in these three greenstone belts lasting ca. 70 Ma and combined stratigraphic evidence from the Lumby Lake and Steep Rock belts suggests that more than one plume may have ascended and tapped the same mantle sources, over time, within the area. Plume magmatism and rifting of continental platforms thus appears to have been an important feature of crustal development in the Meso-Archean.

A multi-instrumental geochemical study of anomalous uranium enrichment in coal.

PubMed

Havelcová, Martina; Machovič, Vladimír; Mizera, Jiří; Sýkorová, Ivana; Borecká, Lenka; Kopecký, Lubomír

2014-11-01

Contents of uranium in coals from Odeř in the northernmost part of the Sokolov Basin, Czech Republic, in the vicinity of the well known St. Joachimsthal uranium ore deposits, reach extremely high values. In the present work, coal samples with contents of uranium ranging from 0.02 to 6 wt.% were studied. The study employing a whole complex of analytical techniques has been aimed at identification of changes in the structure of coal organic matter, which are associated with the high contents of uranium in coal. The study includes proximate and ultimate analyses, multielement analysis by instrumental neutron and photon activation analyses, micropetrographic analysis by optical microscopy, ESEM/EDX analysis of mineral matter, infrared and Raman spectroscopies, solvent extraction followed by gas chromatography with mass spectroscopy (GC/MS), and analytical pyrolysis (Py-GC/MS). The study has confirmed previously proposed explanation of uraniferous mineralization in sedimentary carboniferous substances by the mechanism of reduction and fixation of soluble U(VI) (uranyl, UO2(2+)) species (e.g., humic, carbonate/hydroxo/phosphate complexes) by sedimentary organic matter under diagenetic or hydrothermal conditions, and formation of insoluble U(IV) species as phosphate minerals and uraninite. The process is accompanied with alteration and destruction of the coal organic matter. The changes in the structure of coal organic matter involve dehydrogenation and oxidation mainly in the aliphatic, aromatic and hydroxyl structures, and an increase in aromaticity, content of ether bonds, and the degree of coalification. Copyright © 2014 Elsevier Ltd. All rights reserved.

Simulation of multicomponent light source for optical-electronic system of color analysis objects

NASA Astrophysics Data System (ADS)

Peretiagin, Vladimir S.; Alekhin, Artem A.; Korotaev, Valery V.

2016-04-01

Development of lighting technology has led to possibility of using LEDs in the specialized devices for outdoor, industrial (decorative and accent) and domestic lighting. In addition, LEDs and devices based on them are widely used for solving particular problems. For example, the LED devices are widely used for lighting of vegetables and fruit (for their sorting or growing), textile products (for the control of its quality), minerals (for their sorting), etc. Causes of active introduction LED technology in different systems, including optical-electronic devices and systems, are a large choice of emission color and LED structure, that defines the spatial, power, thermal and other parameters. Furthermore, multi-element and color devices of lighting with adjustable illumination properties can be designed and implemented by using LEDs. However, devices based on LEDs require more attention if you want to provide a certain nature of the energy or color distribution at all the work area (area of analysis or observation) or surface of the object. This paper is proposed a method of theoretical modeling of the lighting devices. The authors present the models of RGB multicomponent light source applied to optical-electronic system for the color analysis of mineral objects. The possibility of formation the uniform and homogeneous on energy and color illumination of the work area for this system is presented. Also authors showed how parameters and characteristics of optical radiation receiver (by optical-electronic system) affect on the energy, spatial, spectral and colorimetric properties of a multicomponent light source.

Single-Walled Carbon Nanotubes, Carbon Nanofibers and Laser-Induced Incandescence

NASA Technical Reports Server (NTRS)

Schubert, Kathy (Technical Monitor); VanderWal, Randy L.; Ticich, Thomas M.; Berger, Gordon M.; Patel, Premal D.

2004-01-01

Laser induced incandescence applied to a heterogeneous, multi-element reacting flows is characterized by a) temporally resolved emission spectra, time-resolved emission at selected detection wavelengths and fluence dependence. Laser fluences above 0.6 Joules per square centimeter at 1064 nm initiate laser-induced vaporization, yielding a lower incandescence intensity, as found through fluence dependence measurements. Spectrally derived temperatures show that values of excitation laser fluence beyond this value lead to a super-heated plasma, well above the vaporization of temperature of carbon. The temporal evolution of the emission signal at these fluences is consistent with plasma dissipation processes, not incandescence from solid-like structures.

SRXFA in the studies of the correlation between the element composition of human blood and environment objects

NASA Astrophysics Data System (ADS)

Koutzenogii, K. P.; Savchenko, T. I.; Chankina, O. V.; Popova, S. A.

2009-05-01

High correlation has been revealed both between the content of chemical elements in human blood and atmospheric aerosols and between blood elements and food components. The element compositions of blood and hair have been established to be strongly related to each other. These biosubstrates can be used to estimate the health of the population of the northern hemisphere. Variability of the multielement composition of the blood and hair of the inhabitants of Novosibirsk, the Tundra Nenetz, Yakuts, Chukchi and the Eskimos, food components and aerosols in the regions where they live was determined by the SRXFA method.

Implicit solvers for unstructured meshes

NASA Technical Reports Server (NTRS)

Venkatakrishnan, V.; Mavriplis, Dimitri J.

1991-01-01

Implicit methods for unstructured mesh computations are developed and tested. The approximate system which arises from the Newton-linearization of the nonlinear evolution operator is solved by using the preconditioned generalized minimum residual technique. These different preconditioners are investigated: the incomplete LU factorization (ILU), block diagonal factorization, and the symmetric successive over-relaxation (SSOR). The preconditioners have been optimized to have good vectorization properties. The various methods are compared over a wide range of problems. Ordering of the unknowns, which affects the convergence of these sparse matrix iterative methods, is also investigated. Results are presented for inviscid and turbulent viscous calculations on single and multielement airfoil configurations using globally and adaptively generated meshes.

Radio frequency surface resistance of Tl-Ba-Ca-Cu-O films on metal and single-crystal substrates

NASA Astrophysics Data System (ADS)

Arendt, P. N.; Reeves, G. A.; Elliott, N. E.; Cooke, D. W.; Gray, E. R.; Houlton, R. J.; Brown, D. R.

1990-01-01

Films of Tl-Ba-Ca-Cu were dc magnetron sputtered from a single multielement target. The films were deposited onto substrates of: (1) magnesium oxide, (2) a silver based alloy (Consil 995), (3) a nickel based alloy (Haynes 230), and (4) buffer layers of barium fluoride or copper oxide on Consil. To form superconducting phases, post-deposition anneals were made on these films using an alumina crucible with an over pressure of thallium and flowing oxygen. After annealing, the film phases were determined using x-ray diffraction. The film surface resistances (Rs) were measured at 22 GHz in a TE011 cavity.

Imaging the small animal cardiovascular system in real-time with multispectral optoacoustic tomography

NASA Astrophysics Data System (ADS)

Taruttis, Adrian; Herzog, Eva; Razansky, Daniel; Ntziachristos, Vasilis

2011-03-01

Multispectral Optoacoustic Tomography (MSOT) is an emerging technique for high resolution macroscopic imaging with optical and molecular contrast. We present cardiovascular imaging results from a multi-element real-time MSOT system recently developed for studies on small animals. Anatomical features relevant to cardiovascular disease, such as the carotid arteries, the aorta and the heart, are imaged in mice. The system's fast acquisition time, in tens of microseconds, allows images free of motion artifacts from heartbeat and respiration. Additionally, we present in-vivo detection of optical imaging agents, gold nanorods, at high spatial and temporal resolution, paving the way for molecular imaging applications.

Sensitive and selective spectrochemical analysis of metallic samples: the combination of laser-induced breakdown spectroscopy and laser-induced fluorescence spectroscopy

NASA Astrophysics Data System (ADS)

Telle, H. H.; Beddows, D. C. S.; Morris, G. W.; Samek, O.

2001-06-01

In order to improve on analytical selectivity and sensitivity, the technique of laser-induced fluorescence spectroscopy (LIFS) was combined with laser-induced breakdown spectroscopy (LIBS). The main thrust of this investigation was to address analytical scenarios in which the measurement site may be difficult to access. Hence, a remote LIBS+LIFS arrangement was set up, and the experiments were carried out on samples surrounded by air at atmospheric pressure, rather than in a controlled buffer gas environment at reduced pressure. Representative for proof of principle, the detection of aluminium, chromium, iron and silicon at trace level concentrations was pursued. These elements are of importance in numerous chemical, medical and industrial applications, and they exhibit suitable resonance transitions, accessible by radiation from a pulsed Ti:sapphire laser system (its 2nd and 3rd harmonic outputs). All investigated elements have an energy level structure in which the laser-excited level is a member of a group of closely-spaced energy levels; thus, this allowed for easy off-resonant fluorescence detection (collisional energy transfer processes). Since numerous of the relevant transition wavelengths are within a narrow spectral interval, this opens the possibility for multi-element analysis; this was demonstrated here for Cr and Fe which were accessed by rapidly changing the tuneable laser wavelength.

Relationships between soil and leaf mineral composition are element-specific, environment-dependent and geographically structured in the emerging model Arabidopsis halleri.

PubMed

Stein, Ricardo J; Höreth, Stephan; de Melo, J Romário F; Syllwasschy, Lara; Lee, Gwonjin; Garbin, Mário L; Clemens, Stephan; Krämer, Ute

2017-02-01

Leaf mineral composition, the leaf ionome, reflects the complex interaction between a plant and its environment including local soil composition, an influential factor that can limit species distribution and plant productivity. Here we addressed within-species variation in plant-soil interactions and edaphic adaptation using Arabidopsis halleri, a well-suited model species as a facultative metallophyte and metal hyperaccumulator. We conducted multi-element analysis of 1972 paired leaf and soil samples from 165 European populations of A. halleri, at individual resolution to accommodate soil heterogeneity. Results were further confirmed under standardized conditions upon cultivation of 105 field-collected genotypes on an artificially metal-contaminated soil in growth chamber experiments. Soil-independent between- and within-population variation set apart leaf accumulation of zinc, cadmium and lead from all other nutrient and nonessential elements, concurring with differential hypothesized ecological roles in either biotic interaction or nutrition. For these metals, soil-leaf relationships were element-specific, differed between metalliferous and nonmetalliferous soils and were geographically structured both in the field and under standardized growth conditions, implicating complex scenarios of recent ecological adaptation. Our study provides an example and a reference for future related work and will serve as a basis for the molecular-genetic dissection and ecological analysis of the observed phenotypic variation. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

Viscous-flow analysis of a subsonic transport aircraft high-lift system and correlation with flight data

NASA Technical Reports Server (NTRS)

Potter, R. C.; Vandam, C. P.

1995-01-01

High-lift system aerodynamics has been gaining attention in recent years. In an effort to improve aircraft performance, comprehensive studies of multi-element airfoil systems are being undertaken in wind-tunnel and flight experiments. Recent developments in Computational Fluid Dynamics (CFD) offer a relatively inexpensive alternative for studying complex viscous flows by numerically solving the Navier-Stokes (N-S) equations. Current limitations in computer resources restrict practical high-lift N-S computations to two dimensions, but CFD predictions can yield tremendous insight into flow structure, interactions between airfoil elements, and effects of changes in airfoil geometry or free-stream conditions. These codes are very accurate when compared to strictly 2D data provided by wind-tunnel testing, as will be shown here. Yet, additional challenges must be faced in the analysis of a production aircraft wing section, such as that of the NASA Langley Transport Systems Research Vehicle (TSRV). A primary issue is the sweep theory used to correlate 2D predictions with 3D flight results, accounting for sweep, taper, and finite wing effects. Other computational issues addressed here include the effects of surface roughness of the geometry, cove shape modeling, grid topology, and transition specification. The sensitivity of the flow to changing free-stream conditions is investigated. In addition, the effects of Gurney flaps on the aerodynamic characteristics of the airfoil system are predicted.

Elemental analysis of forensic glasses by inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Almirall, Jose R.; Duckworth, Douglas C.; Bayne, Charles K.; Morton, Sherman A.; Smith, David H.; Koons, Robert D.; Furton, Kenneth G.

1999-02-01

Flat glass is a common type of evidence collected from the scenes of crimes such as burglaries, vandalism, and hit-and- run accidents. The usefulness of such evidence lies in the ability to associate the glass from the scene (or a suspect) to the original source. Physical and chemical analysis of the glass can be used for discrimination between the possible sources of glass. If the sample is large enough, physical attributes such as fracture matches, density, color, and thickness can be employed for comparison between a recovered fragment(s) to the suspect source. More commonly, refractive index (RI) comparisons are employed. Due to the improved control over glass manufacturing processes, RI values often cannot differentiate glasses where approximately 6 - 9% of casework samples are not expected to be distinguished by RI alone even if they originated from different sources. Employing methods such as NAA, XRF, ICP-AES, and ICP-MS for the comparison of trace elemental compositions has been shown to be more discriminating than RI comparisons. The multielement capability and the sensitivity of ICP-AES and ICP-MS provide for excellent discrimination power. In this work, the sources of variability in ICP-MS of glass analysis are investigated to determine possible sources of variation. The sources of variation examined include errors due to sample preparation, instrument accuracy and precision, and interlaboratory reproducibility. Other sources of variation include inhomogeneity across a sheet of glass from the same source. Analysis of variance has been applied to our ICP-MS analysis of NIST standards and to the interlaboratory comparisons of float glass samples collected across a sheet in a production facility. The results of these experiments allows for a more accurate interpretation of forensic glass data and a better understanding of the discriminating power (absolute and practical) of ICP-MS.

Shape-Independent Model of Monitor Neutron Activation Analysis

NASA Astrophysics Data System (ADS)

Yusuf, Siaka Ojo

The technique of monitor neutron activation analysis has been improved by developing a shape-independent model to solve the problem of the treatment of the epithermal reaction contribution to the reaction rate in reactor neutron activation analysis. It is a form of facility characterization in which differential approximations to neither the neutron flux distribution as a function of energy nor the reaction cross section as a function of energy are necessary. The model predicts a linear relationship when the k-factors (ratios of reaction rates of two nuclides at a given irradiation position) for element x, k _{c} (x), is plotted against the k-factor for the monitor, k_{c} (m). The slope of this line, B(x,c,m) is measured for each element x to provide the calibration of the irradiation facility for monitor activation analysis. In this thesis, scandium was chosen as the comparator and antimony as the epithermal monitor. B(x, Sc, Sb) has been accurately measured for a number of nuclides in three different reactors. The measurement was done by irradiating filter papers containing binary mixture of the elements x and the flux monitor Sc at the various irradiation positions in these three reactors. The experiment was designed in such a way that systematic errors due to mass ratios and efficiency ratios cancel out. Also, rate related errors and backgrounds were kept at negligible values. The results show that B(x,c,m) depends not only on x, c, and m, but also on the type of moderator used for the reactor. We want this new approach to be adopted at all laboratories where routine analysis of multi-element samples are done with the monitor method since the choices of c and m are flexible.

The preparation of <100 particles per trial having the same mole fraction of 12 inorganic compounds at diameters of 6.8, 3.8, or 2.6 [mu]m followed by their deposition onto human lung cells (A549) with measurement of the relative downstream differential expression of ICAM-1

NASA Astrophysics Data System (ADS)

Eleghasim, Ndukauba M.; Haddrell, Allen E.; van Eeden, Stephen; Agnes, George R.

2006-12-01

The characterization of particulate matter suspended in the troposphere (PM10) based on size is an important basis for assessing the extent of their adverse effects on human health. The relevance of such assessments is anticipated to be significantly improved through the continued development of tools that can identify the chemical components within individual ambient particles, and the injury that they cause. We use recently reported methodology to create mimics of ambient particle types of known size and chemical composition that are levitated within an ac trap. The ac trap uses electric fields to levitate the particles that have a given mass and net elementary charge, and as such the ac trap is a mass-to-charge filter. The ac trap was used to levitate populations of particles where the size of particles in any given population could be altered. The levitated particles are delivered direct from the ac trap to human lung cells (A549), in vitro, with downstream measurement of differential expression of intercellular adhesion molecule (ICAM)-1 and counting of the number of particles actually delivered to the culture using an optical microscope. In this study, the chemical composition of the ambient particle mimics was restricted to inorganic compounds whose relative abundance was purposely designed to mimic the average abundance in Environmental Health Center-93 (EHC-93) particles. The sizes of the multilelement particle types prepared were 6.8 +/- 0.5, 3.8 +/- 0.3, 2.6 +/- 0.2 (mean +/- S.D.). Particles of either elemental carbon, or elemental carbon containing glycerol were used as control particle types. In any given experiment, a known number of particles, but always <100, of a given size, were deposited onto a small region of an A549 cell culture. Following an 18-h incubation period and anti-body labeling of ICAM-1, the fluorescence emission from a 1.07 mm2 area of the cell culture centered at the site of particle deposition was acquired. The relative differential expression of ICAM-1 was greatest for multielement particle types having diameters of 2.6 +/- 0.2 [mu]m for which as few as ~15 particles deposited onto the culture resulted in maximal ICAM-1 expression, whereas with multielement particle types having diameters of 6.8 +/- 0.5 [mu]m, it was necessary to deposit >50 particles in order to effect comparable ICAM-1 expression. This data set indicates that for multi-element particle types comprised of the same mole fraction of inorganic compounds and of sizes within the course fraction of PM10, the 2.6 [mu]m particle type was the most potent with respect to effecting differential expression of ICAM-1.

[Determination of 27 elements in Maca nationality's medicine by microwave digestion ICP-MS].

PubMed

Yu, Gui-fang; Zhong, Hai-jie; Hu, Jun-hua; Wang, Jing; Huang, Wen-zhe; Wang, Zhen-zhong; Xiao, Wei

2015-12-01

An analysis method has been established to test 27 elements (Li, Be, B, Mg, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Sr, Mo, Cd, Sn, Sb, Ba, La, Hg, Pb, Bi) in Maca nationality's medicine with microwave digestion-ICP-MS. Sample solutions were analyzed by ICP-MS after microwave digestion, and the contents of elements were calculated according to their calibration curves, and internal standard method was adopted to reduce matrix effect and other interference effects. The experimental results showed that the linear relations of all the elements were very good; the correlation coefficient (r) was 0.9994-1.0000 (Hg was 0.9982) ; the limits of detection were 0.003-2.662 microg x L(-1); the relative standard deviations for all elements of reproducibility were lower than 5% (except the individual elements); the recovery rate were 78.5%-123.7% with RSD lower than 5% ( except the individual elements). The analytical results of standard material showed acceptable agreement with the certified values. This method was applicable to determinate the contents of multi-elements in Maca which had a high sensitivity, good specificity and good repeatability, and provide basis for the quality control of Maca.

Multi-Elements in Waters and Sediments of Shallow Lakes: Relationships with Water, Sediment, and Watershed Characteristics.

PubMed

Kissoon, La Toya T; Jacob, Donna L; Hanson, Mark A; Herwig, Brian R; Bowe, Shane E; Otte, Marinus L

2015-06-01

We measured concentrations of multiple elements, including rare earth elements, in waters and sediments of 38 shallow lakes of varying turbidity and macrophyte cover in the Prairie Parkland (PP) and Laurentian Mixed Forest (LMF) provinces of Minnesota. PP shallow lakes had higher element concentrations in waters and sediments compared to LMF sites. Redundancy analysis indicated that a combination of site- and watershed-scale features explained a large proportion of among-lake variability in element concentrations in lake water and sediments. Percent woodland cover in watersheds, turbidity, open water area, and macrophyte cover collectively explained 65.2 % of variation in element concentrations in lake waters. Sediment fraction smaller than 63 µm, percent woodland in watersheds, open water area, and sediment organic matter collectively explained 64.2 % of variation in element concentrations in lake sediments. In contrast to earlier work on shallow lakes, our results showed the extent to which multiple elements in shallow lake waters and sediments were influenced by a combination of variables including sediment characteristics, lake morphology, and percent land cover in watersheds. These results are informative because they help illustrate the extent of functional connectivity between shallow lakes and adjacent lands within these lake watersheds.

Parallel kinematic mechanisms for distributed actuation of future structures

NASA Astrophysics Data System (ADS)

Lai, G.; Plummer, A. R.; Cleaver, D. J.; Zhou, H.

2016-09-01

Future machines will require distributed actuation integrated with load-bearing structures, so that they are lighter, move faster, use less energy, and are more adaptable. Good examples are shape-changing aircraft wings which can adapt precisely to the ideal aerodynamic form for current flying conditions, and light but powerful robotic manipulators which can interact safely with human co-workers. A 'tensegrity structure' is a good candidate for this application due to its potentially excellent stiffness and strength-to-weight ratio and a multi-element structure into which actuators could be embedded. This paper presents results of an analysis of an example practical actuated tensegrity structure consisting of 3 ‘unit cells’. A numerical method is used to determine the stability of the structure with varying actuator length, showing how four actuators can be used to control movement in three degrees of freedom as well as simultaneously maintaining the structural pre-load. An experimental prototype has been built, in which 4 pneumatic artificial muscles (PAMs) are embedded in one unit cell. The PAMs are controlled antagonistically, by high speed switching of on-off valves, to achieve control of position and structure pre-load. Experimental and simulation results are presented, and future prospects for the approach are discussed.

Single element injector cold flow testing for STME swirl coaxial injector element design

NASA Technical Reports Server (NTRS)

Hulka, J.; Schneider, J. A.

1993-01-01

An oxidizer-swirled coaxial element injector is being investigated for application in the Space Transportation Main Engine (STME). Single element cold flow experiments were conducted to provide characterization of the STME injector element for future analysis, design, and optimization. All tests were conducted to quiescent, ambient backpressure conditions. Spray angle, circumferential spray uniformity, dropsize, and dropsize distribution were measured in water-only and water/nitrogen flows. Rupe mixing efficiency was measured using water/sucrose solution flows with a large grid patternator for simple comparative evaluation of mixing. Factorial designs of experiment were used for statistical evaluation of injector geometrical design features and propellant flow conditions on mixing and atomization. Increasing the free swirl angle of the liquid oxidizer had the greatest influence on increasing the mixing efficiency. The addition of gas assistance had the most significant effect on reducing oxidizer droplet size parameters and increasing droplet size distribution. Increasing the oxidizer injection velocity had the greatest influence for reducing oxidizer droplet size parameters and increasing size distribution for non-gas assisted flows. Single element and multi-element subscale hot fire testing are recommended to verify optimized designs before committing to the STME design.

Effect of organic and conventional rearing system on the mineral content of pork.

PubMed

Zhao, Yan; Wang, Donghua; Yang, Shuming

2016-08-01

Dietary composition and rearing regime largely determine the trace elemental composition of pigs, and consequently their concentration in animal products. The present study evaluates thirteen macro- and trace element concentrations in pork from organic and conventional farms. Conventional pigs were given a commercial feed with added minerals; organic pigs were given a feed based on organic feedstuffs. The content of macro-elements (Na, K, Mg and Ca) and some trace elements (Ni, Fe, Zn and Sr) in organic and conventional meat samples showed no significant differences (P>0.05). Several trace element concentrations in organic pork were significantly higher (P<0.05) compared to conventional pork: Cr (808 and 500μg/kg in organic and conventional pork, respectively), Mn (695 and 473μg/kg) and Cu (1.80 and 1.49mg/kg). The results showed considerable differences in mineral content between samples from pigs reared in organic and conventional systems. Our results also indicate that authentication of organic pork can be realized by applying multivariate chemometric methods such as discriminant analysis to this multi-element data. Copyright © 2016 Elsevier Ltd. All rights reserved.

Modelling of loading, stress relaxation and stress recovery in a shape memory polymer.

PubMed

Sweeney, J; Bonner, M; Ward, I M

2014-09-01

A multi-element constitutive model for a lactide-based shape memory polymer has been developed that represents loading to large tensile deformations, stress relaxation and stress recovery at 60, 65 and 70°C. The model consists of parallel Maxwell arms each comprising neo-Hookean and Eyring elements. Guiu-Pratt analysis of the stress relaxation curves yields Eyring parameters. When these parameters are used to define the Eyring process in a single Maxwell arm, the resulting model yields at too low a stress, but gives good predictions for longer times. Stress dip tests show a very stiff response on unloading by a small strain decrement. This would create an unrealistically high stress on loading to large strain if it were modelled by an elastic element. Instead it is modelled by an Eyring process operating via a flow rule that introduces strain hardening after yield. When this process is incorporated into a second parallel Maxwell arm, there results a model that fully represents both stress relaxation and stress dip tests at 60°C. At higher temperatures a third arm is required for valid predictions. Crown Copyright © 2014. Published by Elsevier Ltd. All rights reserved.

Development, validation and application of an ICP-MS/MS method to quantify minerals and (ultra-)trace elements in human serum.

PubMed

Meyer, Sören; Markova, Mariya; Pohl, Gabriele; Marschall, Talke A; Pivovarova, Olga; Pfeiffer, Andreas F H; Schwerdtle, Tanja

2018-09-01

Multi-element determination in human samples is very challenging. Especially in human intervention studies sample volumes are often limited to a few microliters and due to the high number of samples a high-throughput is indispensable. Here, we present a state-of-the-art ICP-MS/MS-based method for the analysis of essential (trace) elements, namely Mg, Ca, Fe, Cu, Zn, Mo, Se and I, as well as food-relevant toxic elements such as As and Cd. The developed method was validated regarding linearity of the calibration curves, method LODs and LOQs, selectivity and trueness as well as precision. The established reliable method was applied to quantify the element serum concentrations of participants of a human intervention study (LeguAN). The participants received isocaloric diets, either rich in plant protein or in animal protein. While the serum concentrations of Mg and Mo increased in participants receiving the plant protein-based diet (above all legumes), the Se concentration in serum decreased. In contrast, the animal protein-based diet, rich in meat and dairy products, resulted in an increased Se concentration in serum. Copyright © 2018 Elsevier GmbH. All rights reserved.

Influence of soil characteristics on rare earth fingerprints in mosses and mushrooms: Example of a pristine temperate rainforest (Slavonia, Croatia).

PubMed

Fiket, Željka; Medunić, Gordana; Furdek Turk, Martina; Ivanić, Maja; Kniewald, Goran

2017-07-01

The present study aims to investigate levels and distribution of rare earth elements (REE) in soils, mosses and mushrooms of a pristine temperate rainforest, a non-polluted natural system, in order to characterise their environmental availability and mobility. The multielement analysis of digested soil, moss and mushroom samples was performed by High Resolution Inductively Coupled Plasma Mass Spectrometry. The distribution of rare earths in mosses and mushrooms was found primarily affected by local pedological setting. Mosses displayed a consistent lithological signature with an almost insignificant REE fractionation compared to soils. Mushrooms showed differences in REE concentrations in certain parts of the fruiting body with regard to their main physiological function and indicated a significant impact of soil organic content on the overall REEs uptake. Results of our work highlight the importance of substrate characteristics on the initial levels of REEs in mosses and mushrooms. Moreover, this study provides baseline data on the rare earth element levels in mosses and mushrooms growing in a pristine forest area characterised by naturally elevated REE levels in the soil. Copyright © 2017 Elsevier Ltd. All rights reserved.

Determination of essential elements in beverages, herbal infusions and dietary supplements using a new straightforward sequential approach based on flame atomic absorption spectrometry.

PubMed

Gómez-Nieto, Beatriz; Gismera, Mª Jesús; Sevilla, Mª Teresa; Procopio, Jesús R

2017-03-15

A simple method based on FAAS was developed for the sequential multi-element determination of Cu, Zn, Mn, Mg and Si in beverages and food supplements with successful results. The main absorption lines for Cu, Zn and Si and secondary lines for Mn and Mg were selected to carry out the measurements. The sample introduction was performed using a flow injection system. Using the choice of the absorption line wings, the upper limit of the linear range increased up to 110mgL -1 for Mg, 200mgL -1 for Si and 13mgL -1 for Zn. The determination of the five elements was carried out, in triplicate, without the need of additional sample dilutions and/or re-measurements, using less than 3.5mL of sample to perform the complete analysis. The LODs were 0.008mgL -1 for Cu, 0.017mgL -1 for Zn, 0.011mgL -1 for Mn, 0.16mgL -1 for Si and 0.11mgL -1 for Mg. Copyright © 2016 Elsevier Ltd. All rights reserved.

Pulsed—Laser Deposition Of Oxide Thin Films And Laser—Induced Breakdown Spectroscopy Of Multi—Element Materials

NASA Astrophysics Data System (ADS)

Pedarnig, Johannes D.

2010-10-01

New results of the Linz group on pulsed—laser deposition (PLD) of oxide thin films and on laser—induced breakdown spectroscopy (LIBS) of multi-element materials are reported. High-Tc superconducting (HTS) films with enhanced critical current density Jc are produced by laser ablation of novel nano-composite ceramic targets. The targets contain insulating nano-particles that are embedded into the YBa2Cu3O7 matrix. Epitaxial double-layers of lithium-doped and aluminum-doped ZnO are deposited on r-cut sapphire substrates. Acoustic over-modes in the GHz range are excited by piezoelectric actuation of layers. Smooth films of rare-earth doped glass are produced by F2—laser ablation. The transport properties of HTS thin films are modified by light—ion irradiation. Thin film nano—patterning is achieved by masked ion beam irradiation. LIBS is employed to analyze trace elements in industrial iron oxide powder and reference polymer materials. Various trace elements of ppm concentration are measured in the UV/VIS and vacuum-UV spectral range. Quantitative LIBS analysis of major components in oxide materials is performed by calibration-free methods.

Perogenesis of granites, Sharm El-Sheikh area, South Sinai, Egypt: petrological constrains and tectonic evolution

NASA Astrophysics Data System (ADS)

Sherif, Mahmoud I.; Ghoneim, Mohamed F.; Heikal, Mohamed Th. S.; El Dosuky, Bothina T.

2013-10-01

Precambrian granites of the Sharm El-Sheikh area in south Sinai, Egypt belong to collisional and post-collisional Magmatism (610-580 Ma). The granites are widely distributed in the northern part of the Neoproterozoic Arabian-Nubian Shield. South Sinai includes important components of successive multiple stages of upper crust granitic rocks. The earliest stages include monzogranite and syenogranites while the later stages produced alkali feldspar granites and riebeckite-bearing granites. Numerous felsic, mafic dikes and quartz veins traverse the study granites. Petrographically, the granitic rocks consist mainly of perthite, plagioclase, quartz, biotite and riebeckite. Analysis results portray monzogranites displaying calc-alkaline characteristics and emplaced in island-arc tectonic settings, whereas the syenogranites, alkali-feldspar granites and the riebeckite bearing-granites exhibit an alkaline nature and are enriched in HFSEs similar to granites within an extensional regime. Multi-element variation diagrams and geochemical characteristics reinforce a post-collision tectonic setting. REEs geochemical modeling reveals that the rocks were generated as a result of partial melting and fractionation of lower crust basaltic magma giving rise to A1 and A2 subtype granites. They were subsequently emplaced within an intraplate environment at the end of the Pan-African Orogeny.

Multi-Elements in Waters and Sediments of Shallow Lakes: Relationships with Water, Sediment, and Watershed Characteristics

PubMed Central

Jacob, Donna L.; Hanson, Mark A.; Herwig, Brian R.; Bowe, Shane E.; Otte, Marinus L.

2015-01-01

We measured concentrations of multiple elements, including rare earth elements, in waters and sediments of 38 shallow lakes of varying turbidity and macrophyte cover in the Prairie Parkland (PP) and Laurentian Mixed Forest (LMF) provinces of Minnesota. PP shallow lakes had higher element concentrations in waters and sediments compared to LMF sites. Redundancy analysis indicated that a combination of site- and watershed-scale features explained a large proportion of among-lake variability in element concentrations in lake water and sediments. Percent woodland cover in watersheds, turbidity, open water area, and macrophyte cover collectively explained 65.2 % of variation in element concentrations in lake waters. Sediment fraction smaller than 63 µm, percent woodland in watersheds, open water area, and sediment organic matter collectively explained 64.2 % of variation in element concentrations in lake sediments. In contrast to earlier work on shallow lakes, our results showed the extent to which multiple elements in shallow lake waters and sediments were influenced by a combination of variables including sediment characteristics, lake morphology, and percent land cover in watersheds. These results are informative because they help illustrate the extent of functional connectivity between shallow lakes and adjacent lands within these lake watersheds. PMID:26074657

Does heavy metal exposure affect the condition of Whitethroat (Sylvia communis) nestlings?

PubMed

Turzańska-Pietras, Katarzyna; Chachulska, Justyna; Polechońska, Ludmiła; Borowiec, Marta

2018-03-01

Anthropogenic pollution results in high concentrations of heavy metals in the environment. Due to their persistence and a high potential for bioaccumulation, metals are a real threat for birds breeding in industrial areas. The aim of the present study has been to explore the contents of heavy metals (arsenic As, cadmium Cd, chromium Cr, copper Cu, iron Fe, nickel Ni, lead Pb and zinc Zn) in the excreta of Whitethroat (Sylvia communis) nestlings living in polluted environment and to investigate the relationship between these contents and the nestlings' condition. Excrement samples contained all the studied elements. The contents of arsenic, cadmium, copper and zinc in the excreta of nestlings from nests located close to a slag dump were several times higher than in the soil near the dump, which suggested accumulation in food consumed by the birds. Condition parameters (body mass and haemoglobin concentration) were not related to heavy metal concentrations in the nestlings' excreta, except of Zn. It is possible that Whitethroats are able to detoxicate heavy metals to a certain extent. Detailed, multi-element analysis of the environment, food and bird tissues or excreta should be performed to explore relations between different chemicals and bird condition.

Effects of antecedent exercise on academic engagement and stereotypy during instruction.

PubMed

Neely, Leslie; Rispoli, Mandy; Gerow, Stephanie; Ninci, Jennifer

2015-01-01

Antecedent physical exercise has emerged as a potentially promising treatment for reducing challenging behavior and increasing academic behavior in individuals with autism spectrum disorder (ASD). The purpose of this study was to evaluate the effects of physical exercise conducted prior to instructional sessions (antecedent physical exercise) on academic engagement and stereotypy during instructional sessions for two children diagnosed with ASD. Functional analysis results suggested stereotypy was maintained by automatic reinforcement for both participants. A multielement design was employed to evaluate academic engagement and stereotypy during instructional sessions following randomly sequenced conditions involving either (a) no antecedent exercise, (b) brief durations of antecedent exercise, or (c) antecedent exercise that continued until the participant engaged in a systematically determined behavioral indicator of satiation. Both participants demonstrated higher levels of academic engagement and reduced levels of stereotypy during the instructional sessions which followed antecedent physical exercise that continued until behavioral indicators of satiation occurred. This study replicates previous research suggesting that individuals with ASD may benefit from physical exercise prior to academic instruction and further suggests that the duration of antecedent exercise may be optimally individualized based on behavioral indicators of satiation. © The Author(s) 2014.

Petrology and Geochemistry of Tethyan Mélange and Flysch Units Adjacent to the Yarlung Zangbo Suture Zone (YZSZ), Southern Tibet

NASA Astrophysics Data System (ADS)

Dupuis, C.; Hebert, R.; Wang, C.; Li, Y.; Li, Z.

2004-05-01

Located north of the Himalayas, the E-W trending YZSZ is mainly composed of remnants of the Neo-Tethys ocean-floor and marks the suture between Indian and Eurasian plates. This project aims to define geological units immediately South of the YZSZ ophiolites : the serpentinized ophiolitic mélange, the Jurassic-Cretaceous wildflysch and the Triassic flysch. The ophiolitic mélange is characterized by ultramafic rocks, which can be divided into 3 groups. Cpx-harzburgites contain brownish aluminous spinels with Mg# of 0.7-0.75 and Cr# of 0.15-0.27. They resemble fertile abyssal peridotites with generally smooth LREE-depleted and fairly flat MREE-HREE profiles. Transitional harzburgites contain reddish spinels with Mg# of 0.57-0.66 and Cr# of 0.35-0.46. They resemble depleted abyssal or supra-subduction zone peridotites in that MREE-HREE profiles have positive slopes indicative of high degrees of partial melting. LREE profiles vary from depleted to slightly enriched, consistent with some trapped or interacting melt or aqueous fluids. Harzburgites and dunites contain dark reddish spinels with Mg# of 0.47-0.68 and Cr# of 0.40-0.63. They have U-shaped profiles characteristics of interaction between LREE-enriched melt and REE-depleted mantle residues. Spinel compositions and fractional melting modelling indicate that Cpx-harburgites may be the residues from 5-15% melting, transitional harzburgites from 15-23% melting, and harzburgites and dunites from 22-29% melting. The South Sandwich arc-basin system is considered a modern analog of initial geodynamic setting. Mafic rocks (gabbros, diabases and basalts) are ubiquitous and can be geochemically subdivided according to their source unit. LREE-depleted profiles with average (La/Yb)N of 0.5 and slight negative Nb-Ta and Ti anomalies indicate that rocks from the ophiolitic mélange formed in a back-arc basin, such as back-arc-basin mafic rocks of the Izu-Bonin Arc. REE patterns of rocks from the wildflysch are LREE-enriched with average (La/Yb)N of 5.3. These rocks are of intraplate affinity and are geochemically similar to volcanic rocks of the South Tethyan suture zone of Pakistan, which are interpreted to represent an early expression of the Réunion hotspot. Rocks from the flysch show the most LREE-enriched profiles with average (La/Yb)N of 6.9 and slight negative Nb-Ta and Ti anomalies, which suggest continental lithospheric assimilation. Similarly to volcanic rocks of the Deccan Traps, these rocks are thus interpreted to derive from an enriched mantle source of intraplate type (Réunion hotspot?), with additional contamination from the Indian continental crust (ICC). The geochemical signature of greywackes, red and black shales from the wildflysch and flysch units are all concordant with a continental passive margin setting. Despite fairly important chemical weathering, the signature was not affected by significant sedimentary recycling nor heavy-mineral accumulation. REE patterns show a LREE enrichment typical of shales and indicate an old upper CC provenance for the turbidites. Multi-element patterns indicate both mafic and felsic contributions to the source. The mafic contribution (slight positive Ti anomalies) could originate from mafic blocks of enriched intraplate geochemical affinity found in the sedimentary units, whereas the felsic contribution (slight LREE enrichment and negative NB-Ta anomalies) probably derives from remnants of evolved migmatitic batholith of the ICC.

Further Examining Berry's Model: The Applicability of Latent Profile Analysis to Acculturation

ERIC Educational Resources Information Center

Fox, Rina S.; Merz, Erin L.; Solórzano, Martha T.; Roesch, Scott C.

2013-01-01

This study used latent profile analysis (LPA) to identify acculturation profiles. A three-profile solution fit the data best, and comparisons on demographic and psychosocial outcomes as a function of profile yielded expected results. The findings support using LPA as a parsimonious way to model acculturation without anticipating profiles in…

Hot-Fire Test Results of an Oxygen/RP-2 Multi-Element Oxidizer-Rich Staged-Combustion Integrated Test Article

NASA Technical Reports Server (NTRS)

Hulka, J. R.; Protz, C. S.; Garcia, C. P.; Casiano, M. J.; Parton, J. A.

2016-01-01

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. For the thrust chamber assembly of the test article, several configurations of new main injectors, using relatively conventional gas-centered swirl coaxial injector elements, were designed and fabricated. The design and fabrication of these main injectors are described in a companion paper at this JANNAF meeting. New ablative combustion chambers were fabricated based on hardware previously used at NASA for testing at similar size and pressure. An existing oxygen/RP-1 oxidizer-rich subscale preburner injector from a previous NASA-funded program, along with existing and new inter-connecting hot gas duct hardware, were used to supply the oxidizer-rich combustion products to the oxidizer circuit of the main injector of the thrust chamber. Results from independent hot-fire tests of the preburner injector in a combustion chamber with a sonic throat are described in companion papers at this JANNAF conference. The resulting integrated test article - which includes the preburner, inter-connecting hot gas duct, main injector, and ablative combustion chamber - was assembled at Test Stand 116 at the East Test Area of the NASA Marshall Space Flight Center. The test article was well instrumented with static and dynamic pressure, temperature, and acceleration sensors to allow the collected data to be used for combustion analysis model development. Hot-fire testing was conducted with main combustion chamber pressures ranging from 1400 to 2100 psia, and main combustion chamber mixture ratios ranging from 2.4 to 2.9. Different levels of fuel film cooling injected from the injector face were examined ranging from none to about 12% of the total fuel flow. This paper presents the hot-fire test results of the integrated test article. Combustion performance, stability, thermal, and compatibility characteristics of both the preburner and the thrust chamber are described. Another companion paper at this JANNAF meeting includes additional and more detailed test data regarding the combustion dynamics and stability characteristics.

Utility of palmatolepids and icriodontids in recognizing Upper Devonian Series, Stage, and possible substage boundaries

USGS Publications Warehouse

Ziegler, W.; Sandberg, C.A.

2000-01-01

Conodonts are accepted internationally to define Devonian Series and Stage boundaries. Hence, the evolution and taxonomy of pelagic palmatolepids, primarily Palmatolepis and its direct ancestor Mesotaxis, and shallow-water icriodontids, Icriodus, Pelekysgnathus, and "Icriodus", are the major tools for recognizing subdivisions of the Upper Devonian. Palmatolepids are the basis for the Late Devonian Standard Conodont Zonation (ZIEGLER & SANDBERG 1990), whereas icriodontids are the basis for the alternative, integrated shallow-water zonation (SANDBERG & DREESEN 1984). However, an alternative palmatolepid taxonomy for some Frasnian species has been employed recently by some conodont workers using the Montagne Noire (M.N.) zonation, shape analyses of Pa elements, and multielement reconstructions of KLAPPER (1989), KLAPPER & FOSTER (1993); and KLAPPER et al. (1996). Herein, the evolution of palmatolepids and icriodontids is summarized in terms of our zonation and some of the taxonomic differences with the alternative M.N. zonation are exemplified. One of the problems in relating the Standard and M.N. zonations arises from previous errors of interpretation and drafting of the Martenberg section in Germany. This section was designated the reference section for the Frasnian transitans through jamieae Zones by ZIEGLER & SANDBERG (1990). Herein, the early and middle Frasnian zonal boundaries at Martenberg are improved by re-study of our old and recent collections from three profiles, spaced only 4 m apart. Serious problems exist with the Global Stratotype Sections and Points (GSSP's), selected by the Subcommission on Devonian Stratigraphy, following the paleontologic definition of the bases of the Frasnian, Famennian, and Tournaisian Stages, because of the difficulty in making global correlations from these GSSP's. Our summary of these problems should be helpful if future workers decide to relocate these GSSP's.

Mineralogy, geochemistry, and palynology of modern and late Tertiary mangrove deposits in the Barreiras Formation of Mosqueiro Island, northeastern Pará state, eastern Amazonia

NASA Astrophysics Data System (ADS)

Behling, Hermann; da Costa, Marcondes Lima

2004-12-01

A coastal environment has been interpreted from 110 cm thick mudstone deposits found at the base of a 10 m immature laterite profile, which forms the modern coastal cliff on Mosqueiro Island in northeastern Pará state, northern Brazil. The late Tertiary sediment deposits of the Barreiras Formation are studied by multi-element geochemistry and pollen analyses. The mineralogical and geochemical results show that the gray, organic-rich deposits are composed of kaolinite, quartz, and illite/muscovite, as well as pyrite and anatase. They are rich in SiO 2, Al 2O 3, and some FeO. The composition is homogenous, indicating that the detritus source area is formed of lateritic soils derived from acid rock composition. Their chemical composition, including trace elements, is somewhat comparable to continental shale, and the values are below the upper continental Earth crust composition. The pollen analytical data document that the mudstone deposits were formed by an ancient mangrove ecosystem. Mineralogical, geochemical, and pollen analytical data obtained from late Tertiary mangrove deposits are compared with modern mangrove deposits from the Bragança Peninsula of the northeastern coast of Pará state. Although the pollen composition of the deposits is very similar to the modern one, the geochemical and mineralogical composition is different. Smectite was only found in the modern deposit; illite/mica occurs in the ancient deposit, along with Mg, K, and Na. The pollen signature and detrital minerals (kaolinite, quartz and anatase) found in both mangrove deposits show that during the Miocene, a humid tropical climate condition prevailed, similar to modern conditions.

Estimation and Psychometric Analysis of Component Profile Scores via Multivariate Generalizability Theory

ERIC Educational Resources Information Center

Grochowalski, Joseph H.

2015-01-01

Component Universe Score Profile analysis (CUSP) is introduced in this paper as a psychometric alternative to multivariate profile analysis. The theoretical foundations of CUSP analysis are reviewed, which include multivariate generalizability theory and constrained principal components analysis. Because CUSP is a combination of generalizability…

Evaluating the Invariance of Cognitive Profile Patterns Derived from Profile Analysis via Multidimensional Scaling (PAMS): A Bootstrapping Approach

ERIC Educational Resources Information Center

Kim, Se-Kang

2010-01-01

The aim of the current study is to validate the invariance of major profile patterns derived from multidimensional scaling (MDS) by bootstrapping. Profile Analysis via Multidimensional Scaling (PAMS) was employed to obtain profiles and bootstrapping was used to construct the sampling distributions of the profile coordinates and the empirical…

Assimilation of NUCAPS Retrieved Profiles in GSI for Unique Forecasting Applications

NASA Technical Reports Server (NTRS)

Berndt, Emily Beth; Zavodsky, Bradley; Srikishen, Jayanthi; Blankenship, Clay

2015-01-01

Hyperspectral IR profiles can be assimilated in GSI as a separate observation other than radiosondes with only changes to tables in the fix directory. Assimilation of profiles does produce changes to analysis fields and evidenced by: Innovations larger than +/-2.0 K are present and represent where individual profiles impact the final temperature analysis.The updated temperature analysis is colder behind the cold front and warmer in the warm sector. The updated moisture analysis is modified more in the low levels and tends to be drier than the original model background Analysis of model output shows: Differences relative to 13-km RAP analyses are smaller when profiles are assimilated with NUCAPS errors. CAPE is under-forecasted when assimilating NUCAPS profiles, which could be problematic for severe weather forecasting Refining the assimilation technique to incorporate an error covariance matrix and creating a separate GSI module to assimilate satellite profiles may improve results.

Parameter assessment for virtual Stackelberg game in aerodynamic shape optimization

NASA Astrophysics Data System (ADS)

Wang, Jing; Xie, Fangfang; Zheng, Yao; Zhang, Jifa

2018-05-01

In this paper, parametric studies of virtual Stackelberg game (VSG) are conducted to assess the impact of critical parameters on aerodynamic shape optimization, including design cycle, split of design variables and role assignment. Typical numerical cases, including the inverse design and drag reduction design of airfoil, have been carried out. The numerical results confirm the effectiveness and efficiency of VSG. Furthermore, the most significant parameters are identified, e.g. the increase of design cycle can improve the optimization results but it will also add computational burden. These studies will maximize the productivity of the effort in aerodynamic optimization for more complicated engineering problems, such as the multi-element airfoil and wing-body configurations.

Additional Improvements to the NASA Lewis Ice Accretion Code LEWICE

NASA Technical Reports Server (NTRS)

Wright, William B.; Bidwell, Colin S.

1995-01-01

Due to the feedback of the user community, three major features have been added to the NASA Lewis ice accretion code LEWICE. These features include: first, further improvements to the numerics of the code so that more time steps can be run and so that the code is more stable; second, inclusion and refinement of the roughness prediction model described in an earlier paper; third, inclusion of multi-element trajectory and ice accretion capabilities to LEWICE. This paper will describe each of these advancements in full and make comparisons with the experimental data available. Further refinement of these features and inclusion of additional features will be performed as more feedback is received.

Velocity visualization in gaseous flows

NASA Technical Reports Server (NTRS)

Hanson, R. K.; Hiller, B.; Hassa, C.; Booman, R. A.

1984-01-01

Techniques yielding simultaneous, multiple-point measurements of velocity in reacting or nonreacting flow fields have the potential to significantly impact basic and applied studies of fluid mechanics. This research program is aimed at investigating several candidate schemes which could provide such measurement capability. The concepts under study have in common the use of a laser source (to illuminate a column, a grid, a plane or a volume in the flow) and the collection of light at right angles (from Mie scattering, fluorescence, phosphorescence or chemiluminescence) using a multi-element solid-state camera (100 x 100 array of photodiodes). The work will include an overview and a status report of work in progress with particular emphasis on the method of Doppler-modulated absorption.

Driving Circuitry for Focused Ultrasound Noninvasive Surgery and Drug Delivery Applications

PubMed Central

El-Desouki, Munir M.; Hynynen, Kullervo

2011-01-01

Recent works on focused ultrasound (FUS) have shown great promise for cancer therapy. Researchers are continuously trying to improve system performance, which is resulting in an increased complexity that is more apparent when using multi-element phased array systems. This has led to significant efforts to reduce system size and cost by relying on system integration. Although ideas from other fields such as microwave antenna phased arrays can be adopted in FUS, the application requirements differ significantly since the frequency range used in FUS is much lower. In this paper, we review recent efforts to design efficient power monitoring, phase shifting and output driving techniques used specifically for high intensity focused ultrasound (HIFU). PMID:22346589

A nickel metal hydride battery for electric vehicles

NASA Astrophysics Data System (ADS)

Ovshinsky, S. R.; Fetcenko, M. A.; Ross, J.

1993-04-01

An efficient battery is the key technological element to the development of practical electric vehicles. The science and technology of a nickel metal hydride battery, which stores hydrogen in the solid hydride phase and has high energy density, high power, long life, tolerance to abuse, a wide range of operating temperature, quick-charge capability, and totally sealed maintenance-free operation, is described. A broad range of multi-element metal hydride materials that use structural and compositional disorder on several scales of length has been engineered for use as the negative electrode in this battery. The battery operates at ambient temperature, is made of nontoxic materials, and is recyclable. Demonstration of the manufacturing technology has been achieved.

Strategies for Ground Based Testing of Manned Lunar Surface Systems

NASA Technical Reports Server (NTRS)

Beyer, Jeff; Peacock, Mike; Gill, Tracy

2009-01-01

Integrated testing (such as Multi-Element Integrated Test (MEIT)) is critical to reducing risks and minimizing problems encountered during assembly, activation, and on-orbit operation of large, complex manned spacecraft. Provides the best implementation of "Test Like You Fly:. Planning for integrated testing needs to begin at the earliest stages of Program definition. Program leadership needs to fully understand and buy in to what integrated testing is and why it needs to be performed. As Program evolves and design and schedules mature, continually look for suitable opportunities to perform testing where enough components are together in one place at one time. The benefits to be gained are well worth the costs.

A comparison of peer video modeling and self video modeling to teach textual responses in children with autism.

PubMed

Marcus, Alonna; Wilder, David A

2009-01-01

Peer video modeling was compared to self video modeling to teach 3 children with autism to respond appropriately to (i.e., identify or label) novel letters. A combination multiple baseline and multielement design was used to compare the two procedures. Results showed that all 3 participants met the mastery criterion in the self-modeling condition, whereas only 1 of the participants met the mastery criterion in the peer-modeling condition. In addition, the participant who met the mastery criterion in both conditions reached the criterion more quickly in the self-modeling condition. Results are discussed in terms of their implications for teaching new skills to children with autism.

All-optical photochromic spatial light modulators based on photoinduced electron transfer in rigid matrices

NASA Technical Reports Server (NTRS)

Beratan, David N. (Inventor); Perry, Joseph W. (Inventor)

1991-01-01

A single material (not a multi-element structure) spatial light modulator may be written to, as well as read out from, using light. The device has tailorable rise and hold times dependent on the composition and concentration of the molecular species used as the active components. The spatial resolution of this device is limited only by light diffraction as in volume holograms. The device may function as a two-dimensional mask (transmission or reflection) or as a three-dimensional volume holographic medium. This device, based on optically-induced electron transfer, is able to perform incoherent to coherent image conversion or wavelength conversion over a wide spectral range (ultraviolet, visible, or near-infrared regions).

A comparison of forward and concurrent chaining strategies in teaching laundromat skills to students with severe handicaps.

PubMed

McDonnell, J; McFarland, S

1988-01-01

This study compared the relative efficiency of forward and concurrent chaining strategies in teaching the use of a commercial washing machine and laundry soap dispenser to four high school students with severe handicaps. Acquisition and maintenance of the laundromat skills were assessed through a multielement, alternating treatment within subject design. Results indicated that the concurrent chaining strategy was more efficient than forward chaining in facilitating acquisition of the activities. Four week and eight week follow-up probes indicated that concurrent chaining resulted in better maintenance of the activities. The implications of these results for teaching community activities and future research in building complex chains are discussed.

Driving circuitry for focused ultrasound noninvasive surgery and drug delivery applications.

PubMed

El-Desouki, Munir M; Hynynen, Kullervo

2011-01-01

Recent works on focused ultrasound (FUS) have shown great promise for cancer therapy. Researchers are continuously trying to improve system performance, which is resulting in an increased complexity that is more apparent when using multi-element phased array systems. This has led to significant efforts to reduce system size and cost by relying on system integration. Although ideas from other fields such as microwave antenna phased arrays can be adopted in FUS, the application requirements differ significantly since the frequency range used in FUS is much lower. In this paper, we review recent efforts to design efficient power monitoring, phase shifting and output driving techniques used specifically for high intensity focused ultrasound (HIFU).

Use of sol-gels as solid matrixes for simultaneous multielement determination by radio frequency glow discharge optical emission spectrometry: determinations of suspended particulate matter.

PubMed

Davis, W Clay; Knippel, Brad C; Cooper, Julia E; Spraul, Bryan K; Rice, Jeanette K; Smith, Dennis W; Marcus, R Kenneth

2003-05-15

A new approach for the analysis of particulate matter by radio frequency glow discharge optical emission spectrometry (rf-GD-OES) is described. Dispersion of the particles in a sol-gel sample matrix provides a convenient means of generating a thin film suitable for sputter-sampling into the discharge. Acid-catalyzed sol-gel glasses synthesized from tetramethyl orthosilicate were prepared and spun-cast on glass substrates. The resultant thin films on glass substrates were analyzed to determine the discharge operating conditions and resultant sputtering characteristics while a number of optical emission lines of the film components were monitored. Slurries of powdered standard reference materials NIST SRM 1884a (Portland Cement) and NIST SRM 2690 (Coal Fly Ash) dispersed in the sols were cast into films in the same manner. Use of the sol-gels as sample matrixes allows for background subtraction through the use of analytical blanks and may facilitate the generation of calibration curves via readily synthesized, matrix-matched analytical standards in solids analysis. Detection limits were determined for minor elements via the RSDB method to be in the range of 1-10 microg/g in Portland Cement and Coal Fly Ash samples for the elements Al, Fe, Mg, S, and Si. Values for Ca were in the range of 15-35 microg/g. This preliminary study demonstrates the possibility of incorporating various insoluble species, including ceramics and geological specimens in powder form, into a solid matrix for further analysis by either rf-GD-OES or MS.

Aerodynamic Shape Sensitivity Analysis and Design Optimization of Complex Configurations Using Unstructured Grids

NASA Technical Reports Server (NTRS)

Taylor, Arthur C., III; Newman, James C., III; Barnwell, Richard W.

1997-01-01

A three-dimensional unstructured grid approach to aerodynamic shape sensitivity analysis and design optimization has been developed and is extended to model geometrically complex configurations. The advantage of unstructured grids (when compared with a structured-grid approach) is their inherent ability to discretize irregularly shaped domains with greater efficiency and less effort. Hence, this approach is ideally suited for geometrically complex configurations of practical interest. In this work the nonlinear Euler equations are solved using an upwind, cell-centered, finite-volume scheme. The discrete, linearized systems which result from this scheme are solved iteratively by a preconditioned conjugate-gradient-like algorithm known as GMRES for the two-dimensional geometry and a Gauss-Seidel algorithm for the three-dimensional; similar procedures are used to solve the accompanying linear aerodynamic sensitivity equations in incremental iterative form. As shown, this particular form of the sensitivity equation makes large-scale gradient-based aerodynamic optimization possible by taking advantage of memory efficient methods to construct exact Jacobian matrix-vector products. Simple parameterization techniques are utilized for demonstrative purposes. Once the surface has been deformed, the unstructured grid is adapted by considering the mesh as a system of interconnected springs. Grid sensitivities are obtained by differentiating the surface parameterization and the grid adaptation algorithms with ADIFOR (which is an advanced automatic-differentiation software tool). To demonstrate the ability of this procedure to analyze and design complex configurations of practical interest, the sensitivity analysis and shape optimization has been performed for a two-dimensional high-lift multielement airfoil and for a three-dimensional Boeing 747-200 aircraft.

Evaluation of methods for trace-element determination with emphasis on their usability in the clinical routine laboratory.

PubMed

Bolann, B J; Rahil-Khazen, R; Henriksen, H; Isrenn, R; Ulvik, R J

2007-01-01

Commonly used techniques for trace-element analysis in human biological material are flame atomic absorption spectrometry (FAAS), graphite furnace atomic absorption spectrometry (GFAAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). Elements that form volatile hydrides, first of all mercury, are analysed by hydride generation techniques. In the absorption techniques the samples are vaporized into free, neutral atoms and illuminated by a light source that emits the atomic spectrum of the element under analysis. The absorbance gives a quantitative measure of the concentration of the element. ICP-AES and ICP-MS are multi-element techniques. In ICP-AES the atoms of the sample are excited by, for example, argon plasma at very high temperatures. The emitted light is directed to a detector, and the optical signals are processed to values for the concentrations of the elements. In ICP-MS a mass spectrometer separates and detects ions produced by the ICP, according to their mass-to-charge ratio. Dilution of biological fluids is commonly needed to reduce the effect of the matrix. Digestion using acids and microwave energy in closed vessels at elevated pressure is often used. Matrix and spectral interferences may cause problems. Precautions should be taken against trace-element contamination during collection, storage and processing of samples. For clinical problems requiring the analysis of only one or a few elements, the use of FAAS may be sufficient, unless the higher sensitivity of GFAAS is required. For screening of multiple elements, however, the ICP techniques are preferable.

[Rapid determination of major and trace elements in the salt lake clay minerals by X-ray fluorescence spectrometry].

PubMed

Wang, Xiao-Huan; Meng, Qing-Fen; Dong, Ya-Ping; Chen, Mei-Da; Li, Wu

2010-03-01

A rapid multi-element analysis method for clay mineral samples was described. This method utilized a polarized wave-length dispersive X-ray fluorescence spectrometer--Axios PW4400, which had a maximum tube power of 4 000 watts. The method was developed for the determination of As, Mn, Co, Cu, Cr, Dy, Ga, Mo, P, Pb, Rb, S, Sr, Ni, ,Cs, Ta, Th, Ti, U, V, Y, Zn, Zr, MgO, K2O, Na2O, CaO, Fe2O3, Al2O3, SiO2 and so on. Thirty elements in clay mineral species were measured by X-ray fluorescence spectrometry with pressed powder pellets. Spectral interferences, in particular the indirect interferences of each element, were studied. A method to distinguish the interference between each other periodic elements in element periodic table was put forward. The measuring conditions and existence were mainly investigated, and the selected background position as well as corrected spectral overlap for the trace elements were also discussed. It was found that the indirect spectral overlap line was the same important as direct spectral overlap line. Due to inducing the effect of indirect spectral overlap, some elements jlike Bi, Sn, W which do not need analysis were also added to the elements channel. The relative standard deviation (RSD) was in the range of 0.01% to 5.45% except three elements Mo, Cs and Ta. The detection limits, precisions and accuracies for most elements using this method can meet the requirements of sample analysis in clay mineral species.

EDXRF as an alternative method for multielement analysis of tropical soils and sediments.

PubMed

Fernández, Zahily Herrero; Dos Santos Júnior, José Araújo; Dos Santos Amaral, Romilton; Alvarez, Juan Reinaldo Estevez; da Silva, Edvane Borges; De França, Elvis Joacir; Menezes, Rômulo Simões Cezar; de Farias, Emerson Emiliano Gualberto; do Nascimento Santos, Josineide Marques

2017-08-10

The quality assessment of tropical soils and sediments is still under discussion, with efforts being made on the part of governmental agencies to establish reference values. Energy dispersive X-ray fluorescence (EDXRF) is a potential analytical technique for quantifying diverse chemical elements in geological material without chemical treatment, primarily when it is performed at an appropriate metrological level. In this work, analytical curves were obtained by means of the analysis of geological reference materials (RMs), which allowed for the researchers to draw a comparison among the sources of analytical uncertainty. After having determined the quality assurance of the analytical procedure, the EDXRF method was applied to determine chemical elements in soils from the state of Pernambuco, Brazil. The regression coefficients of the analytical curves used to determine Al, Ca, Fe, K, Mg, Mn, Ni, Pb, Si, Sr, Ti, and Zn were higher than 0.99. The quality of the analytical procedure was demonstrated at a 95% confidence level, in which the estimated analytical uncertainties agreed with those from the RM's certificates of analysis. The analysis of diverse geological samples from Pernambuco indicated higher concentrations of Ni and Zn in sugarcane, with maximum values of 41 mg kg - 1 and 118 mg kg - 1 , respectively, and agricultural areas (41 mg kg - 1 and 127 mg kg - 1 , respectively). The trace element Sr was mainly enriched in urban soils with values of 400 mg kg - 1 . According to the results, the EDXRF method was successfully implemented, providing some chemical tracers for the quality assessment of tropical soils and sediments.

Performance and Stability Analyses of Rocket Combustion Devices Using Liquid Oxygen/Liquid Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, James R.; Jones, G. W.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in flight-qualified engine systems, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented programs with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations on these programs. This paper summarizes these analyses. Test and analysis results of impinging and coaxial element injectors using liquid oxygen and liquid methane propellants are included. Several cases with gaseous methane are included for reference. Several different thrust chamber configurations have been modeled, including thrust chambers with multi-element like-on-like and swirl coax element injectors tested at NASA MSFC, and a unielement chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods.

Combustion and Performance Analyses of Coaxial Element Injectors with Liquid Oxygen/Liquid Methane Propellants

NASA Technical Reports Server (NTRS)

Hulka, J. R.; Jones, G. W.

2010-01-01

Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in a flight-qualified engine system, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented activities with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, the NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations. This paper summarizes the analyses of combustion and performance as a follow-up to a paper published in the 2008 JANNAF/LPS meeting. Combustion stability analyses are presented in a separate paper. The current paper includes test and analysis results of coaxial element injectors using liquid oxygen and liquid methane or gaseous methane propellants. Several thrust chamber configurations have been modeled, including thrust chambers with multi-element swirl coax element injectors tested at the NASA MSFC, and a uni-element chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods

Analysis of Complex Valve and Feed Systems

NASA Technical Reports Server (NTRS)

Ahuja, Vineet; Hosangadi, Ashvin; Shipman, Jeremy; Cavallo, Peter; Dash, Sanford

2007-01-01

A numerical framework for analysis of complex valve systems supports testing of propulsive systems by simulating key valve and control system components in the test loop. In particular, it is designed to enhance the analysis capability in terms of identifying system transients and quantifying the valve response to these transients. This system has analysis capability for simulating valve motion in complex systems operating in diverse flow regimes ranging from compressible gases to cryogenic liquids. A key feature is the hybrid, unstructured framework with sub-models for grid movement and phase change including cryogenic cavitations. The multi-element unstructured framework offers improved predictions of valve performance characteristics under steady conditions for structurally complex valves such as pressure regulator valve. Unsteady simulations of valve motion using this computational approach have been carried out for various valves in operation at Stennis Space Center such as the split-body valve and the 10-in. (approx.25.4-cm) LOX (liquid oxygen) valve and the 4-in. (approx.10 cm) Y-pattern valve (liquid nitrogen). Such simulations make use of variable grid topologies, thereby permitting solution accuracy and resolving important flow physics in the seat region of the moving valve. An advantage to this software includes possible reduction in testing costs incurred due to disruptions relating to unexpected flow transients or functioning of valve/flow control systems. Prediction of the flow anomalies leading to system vibrations, flow resonance, and valve stall can help in valve scheduling and significantly reduce the need for activation tests. This framework has been evaluated for its ability to predict performance metrics like flow coefficient for cavitating venturis and valve coefficient curves, and could be a valuable tool in predicting and understanding anomalous behavior of system components at rocket propulsion testing and design sites.

Association of glass fragments by their trace elemental content using ICP-MS and LA-ICP-MS in the analysis scheme

NASA Astrophysics Data System (ADS)

Almirall, Jose R.; Montero, Shirly; Furton, Kenneth G.

2002-08-01

The importance of glass as evidence of association between a crime event and a suspect has been recognized for some time. Glass is a fragile material that is often found at the scenes of crimes such as burglaries, hit-and-run accidents and violent crime offenses. The physical and chemical properties of glass can be used to differentiate between possible sources and as evidence of association between two fragments of glass thought to originate from the same source. Refractive index (RI) comparisons have been used for this purpose but due to the improved control over glass manufacturing processes, RI values often cannot differentiate glasses, even if the glass originates from different sources. Elemental analysis methods such as NAA, XRF, ICP-AES, and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) have also been used for the comparison of trace elemental compositions and these techniques have been shown to provide an improvement in the discrimination of glass fragments over RI comparisons alone. The multi-element capability and the sensitivity of ICP-MS combined with the simplified sample introduction of laser ablation prior to ion detection provides for an excellent and relatively non-destructive technique for elemental analysis of glass fragments. The methodology for solution analysis (digestion procedure) and solid sample analysis (laser ablation) of glass is reported and the analytical results are compared. An isotope dilution method is also reported as a high precision technique for elemental analysis of glass fragments. The optimum sampling parameters for laser ablation, for semi-quantitative analysis and element ratio comparisons are also presented. Finally, the results of a case involving the breaking of 15 vehicle windows in an airport parking lot and the association of a suspect to the breakings by the glass fragments found on his person are also presented.

KENNEDY SPACE CENTER, FLA. - Various elements intended for the International Space Station are lined up in the Space Station Processing Facility. The newest to arrive at KSC are in the rear: at left, the U.S. Node 2, and at right, the Japanese Experiment Module (JEM). The two elements are undergoing a Multi-Element Integrated Test (MEIT). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. Developed by the National Space Development Agency of Japan (NASDA), the JEM is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-08-27

KENNEDY SPACE CENTER, FLA. - Various elements intended for the International Space Station are lined up in the Space Station Processing Facility. The newest to arrive at KSC are in the rear: at left, the U.S. Node 2, and at right, the Japanese Experiment Module (JEM). The two elements are undergoing a Multi-Element Integrated Test (MEIT). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. Developed by the National Space Development Agency of Japan (NASDA), the JEM is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

KENNEDY SPACE CENTER, FLA. - Various elements intended for the International Space Station are lined up in the Space Station Processing Facility. The newest to arrive at KSC are in the rear: at left, the U.S. Node 2, and next to it at right, the Japanese Experiment Module (JEM). The two elements are undergoing a Multi-Element Integrated Test (MEIT). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. Developed by the National Space Development Agency of Japan (NASDA), the JEM is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-09-03

KENNEDY SPACE CENTER, FLA. - Various elements intended for the International Space Station are lined up in the Space Station Processing Facility. The newest to arrive at KSC are in the rear: at left, the U.S. Node 2, and next to it at right, the Japanese Experiment Module (JEM). The two elements are undergoing a Multi-Element Integrated Test (MEIT). Node 2 attaches to the end of the U.S. Lab on the ISS and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. Developed by the National Space Development Agency of Japan (NASDA), the JEM is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

Rayleigh-based, multi-element coral thermometry: A biomineralization approach to developing climate proxies

USGS Publications Warehouse

Gaetani, G.A.; Cohen, A.L.; Wang, Z.; Crusius, John

2011-01-01

This study presents a new approach to coral thermometry that deconvolves the influence of water temperature on skeleton composition from that of “vital effects”, and has the potential to provide estimates of growth temperatures that are accurate to within a few tenths of a degree Celsius from both tropical and cold-water corals. Our results provide support for a physico-chemical model of coral biomineralization, and imply that Mg2+ substitutes directly for Ca2+ in biogenic aragonite. Recent studies have identified Rayleigh fractionation as an important influence on the elemental composition of coral skeletons. Daily, seasonal and interannual variations in the amount of aragonite precipitated by corals from each “batch” of calcifying fluid can explain why the temperature dependencies of elemental ratios in coral skeleton differ from those of abiogenic aragonites, and are highly variable among individual corals. On the basis of this new insight into the origin of “vital effects” in coral skeleton, we developed a Rayleigh-based, multi-element approach to coral thermometry. Temperature is resolved from the Rayleigh fractionation signal by combining information from multiple element ratios (e.g., Mg/Ca, Sr/Ca, Ba/Ca) to produce a mathematically over-constrained system of Rayleigh equations. Unlike conventional coral thermometers, this approach does not rely on an initial calibration of coral skeletal composition to an instrumental temperature record. Rather, considering coral skeletogenesis as a biologically mediated, physico-chemical process provides a means to extract temperature information from the skeleton composition using the Rayleigh equation and a set of experimentally determined partition coefficients. Because this approach is based on a quantitative understanding of the mechanism that produces the “vital effect” it should be possible to apply it both across scleractinian species and to corals growing in vastly different environments. Where instrumental temperature records are available, a Rayleigh-based framework allows the effects of stress on coral calcification to be identified on the basis of anomalies in the skeletal composition.

KENNEDY SPACE CENTER, FLA. - In the Space Station Processing Facility, the U.S. Node 2 (center) and the Japanese Experiment Module (JEM), background right, await a Multi-Element Integrated Test (MEIT). Node 2 attaches to the end of the U.S. Lab on the International Space Station and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The National Space Development Agency of Japan (NASDA) developed their laboratory at the Tsukuba Space Center near Tokyo. It is the first element, named "Kibo" (Hope), to be delivered to KSC. The JEM is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

NASA Image and Video Library

2003-08-27

KENNEDY SPACE CENTER, FLA. - In the Space Station Processing Facility, the U.S. Node 2 (center) and the Japanese Experiment Module (JEM), background right, await a Multi-Element Integrated Test (MEIT). Node 2 attaches to the end of the U.S. Lab on the International Space Station and provides attach locations for the Japanese laboratory, European laboratory, the Centrifuge Accommodation Module and, eventually, Multipurpose Logistics Modules. It will provide the primary docking location for the Shuttle when a pressurized mating adapter is attached to Node 2. Installation of the module will complete the U.S. Core of the ISS. The National Space Development Agency of Japan (NASDA) developed their laboratory at the Tsukuba Space Center near Tokyo. It is the first element, named "Kibo" (Hope), to be delivered to KSC. The JEM is Japan's primary contribution to the Station. It will enhance the unique research capabilities of the orbiting complex by providing an additional environment for astronauts to conduct science experiments.

Examining the degree of pain reduction using a multielement exercise model with a conventional training shoe versus an ultraflexible training shoe for treating plantar fasciitis.

PubMed

Ryan, Michael; Fraser, Scott; McDonald, Kymberly; Taunton, Jack

2009-12-01

Plantar fasciitis is a common injury to the plantar aponeurosis, manifesting as pain surrounding its proximal insertion at the medial calcaneal tubercle. Pain is typically worse in the morning when getting out of bed, and may subside after the tissue is sufficiently warmed up. For running-based athletes and individuals who spend prolonged periods of time on their feet at work, plantar fasciitis may become recalcitrant to conservative treatments such as ice, rest, and anti-inflammatory medication. Exercise-based therapies have received only limited attention in the literature for this common problem, yet they are becoming increasingly validated for pain relief and positive tissue remodeling at other sites of similar soft-tissue overuse injury. This study reports on pain outcomes in individuals experiencing chronic plantar fasciitis while wearing a shoe with an ultraflexible midsole (Nike Free 5.0) (FREE) versus a conventional training (CON) shoe in a 12-week multielement exercise regimen, and after a 6-month follow-up. Adults with >or= 6-month history of painful heel pain were recruited and randomly assigned to wear 1 of the 2 shoes. All subjects completed the same exercise protocol. A visual analogue scale item tracked peak pain in the preceding 24 hours taken at baseline, 6- and 12-week points, and at the 6-month follow-up. Twenty-one subjects completed the program (9 FREE; 12 CON). Both groups reported significant improvements in pain by the 6-month follow-up, and the FREE group reported an overall reduced level of pain throughout the study as a result of lower mean pain scores at the midpoint and post-test compared with the CON group. The exercise regimen employed in this study appears to reduce pain associated with chronic plantar fasciitis, and in doing so, the Nike 5.0 shoe may result in reductions in pain earlier than conventional running shoes.

Determination of trace metals in drinking water using solid-phase extraction disks and X-ray fluorescence spectrometry.

PubMed

Hou, Xiandeng; Peters, Heather L; Yang, Zheng; Wagner, Karl A; Batchelor, James D; Daniel, Meredith M; Jones, Bradley T

2003-03-01

A convenient method is described for monitoring Cd, Ni, Cu, and Pb at trace levels in drinking water samples. These metals are preconcentrated on a chelating solid-phase extraction disk and then determined by X-ray fluorescence spectrometry. The method tolerates a wide pH range (pH 6-14) and a large amount of alkaline and alkaline earth elements. The preconcentration factor is well over 1600, assuming a 1 L water sample volume. The limits of detection for Cd, Ni, Cu, and Pb are 3.8, 0.6, 0.4, and 0.3 ng/mL, respectively. These are well below the federal maximum contaminant level values, which are 5, 100, 1300, and 15 ng/mL, respectively. The proposed method has many advantages including ease of operation, multielement capability, nondestructiveness, high sensitivity, and relative cost efficiency. The solid-phase extraction step can be conducted in the field and then the disks can be mailed to a laboratory for the analysis, eliminating the cost of transporting large volumes of water samples. Furthermore, the color of the used extraction disk provides an initial estimate of the degree of contamination for some transition metals (for example, Ni and Cu). Thus, the overall cost for analysis of metals in drinking water can be minimized by implementing the method, and small water supply companies with limited budgets will be better able to comply with the Safe Drinking Water Act.

Solution of multi-element LED light sources development automation problem

NASA Astrophysics Data System (ADS)

Chertov, Aleksandr N.; Gorbunova, Elena V.; Korotaev, Valery V.; Peretyagin, Vladimir S.

2014-09-01

The intensive development of LED technologies resulted in the creation of multicomponent light sources in the form of controlled illumination devices based on usage of mentioned LED technologies. These light sources are used in different areas of production (for example, in the food industry for sorting products or in the textile industry for quality control, etc.). The use of LED lighting products in the devices used in specialized lighting, became possible due to wide range of colors of light, LED structures (which determines the direction of radiation, the spatial distribution and intensity of the radiation, electrical, heat, power and other characteristics), and of course, the possibility of obtaining any shade in a wide dynamic range of brightness values. LED-based lighting devices are notable for the diversity of parameters and characteristics, such as color radiation, location and number of emitters, etc. Although LED technologies have several advantages, however, they require more attention if you need to ensure a certain character of illumination distribution and/or distribution of the color picture at a predetermined distance (for example, at flat surface, work zone, area of analysis or observation). This paper presents software designed for the development of the multicomponent LED light sources. The possibility of obtaining the desired color and energy distribution at the zone of analysis by specifying the spatial parameters of the created multicomponent light source and using of real power, spectral and color parameters and characteristics of the LEDs is shown as well.

Forensic analysis of laser printed ink by X-ray fluorescence and laser-excited plume fluorescence.

PubMed

Chu, Po-Chun; Cai, Bruno Yue; Tsoi, Yeuk Ki; Yuen, Ronald; Leung, Kelvin S Y; Cheung, Nai-Ho

2013-05-07

We demonstrated a minimally destructive two-tier approach for multielement forensic analysis of laser-printed ink. The printed document was first screened using a portable-X-ray fluorescence (XRF) probe. If the results were not conclusive, a laser microprobe was then deployed. The laser probe was based on a two-pulse scheme: the first laser pulse ablated a thin layer of the printed ink; the second laser pulse at 193 nm induced multianalytes in the desorbed ink to fluoresce. We analyzed four brands of black toners. The toners were printed on paper in the form of patches or letters or overprinted on another ink. The XRF probe could sort the four brands if the printed letters were larger than font 20. It could not tell the printing sequence in the case of overprints. The laser probe was more discriminatory; it could sort the toner brands and reveal the overprint sequence regardless of font size while the sampled area was not visibly different from neighboring areas even under the microscope. In terms of general analytical performance, the laser probe featured tens of micrometer lateral resolution and tens to hundreds of nm depth resolution and atto-mole mass detection limits. It could handle samples of arbitrary size and shape and was air compatible, and no sample pretreatment was necessary. It will prove useful whenever high-resolution and high sensitivity 3D elemental mapping is required.

Design and Fabrication of Large Diameter Gradient-Index Lenses for Dual-Band Visible to Short-Wave Infrared Imaging Applications

NASA Astrophysics Data System (ADS)

Visconti, Anthony Joseph

The fabrication of gradient-index (GRIN) optical elements is quite challenging, which has traditionally restricted their use in many imaging systems; consequently, commercial-level GRIN components usually exist in one particular market or niche application space. One such fabrication technique, ion exchange, is a well-known process used in the chemical strengthening of glass, the fabrication of waveguide devices, and the production of small diameter GRIN optical relay systems. However, the manufacturing of large diameter ion-exchanged GRIN elements has historically been limited by long diffusion times. For example, the diffusion time for a 20 mm diameter radial GRIN lens in commercially available ion exchange glass for small diameter relays, is on the order of a year. The diffusion time can be dramatically reduced by addressing three key ion exchange process parameters; the composition of the glass, the diffusion temperature, and the composition of the salt bath. Experimental work throughout this thesis aims to (1) scale up the ion exchange diffusion process to 20 mm diameters for a fast-diffusing titania silicate glass family in both (2) sodium ion for lithium ion (Na+ for Li+) and lithium ion for sodium ion (Li+ for Na+) exchange directions, while (3) utilizing manufacturing friendly salt bath compositions. In addition, optical design studies have demonstrated that an important benefit of gradient-index elements in imaging systems is the added degree of freedom introduced with a gradient's optical power. However, these studies have not investigated the potential usefulness of GRIN materials in dual-band visible to short-wave infrared (vis-SWIR) imaging systems. The unique chromatic properties of the titania silicate ion exchange glass become a significant degree of freedom in the design process for these color-limited, broadband imaging applications. A single GRIN element can replace a cemented doublet or even a cemented triplet, without loss in overall system performance. In this work, a polychromatic vis-SWIR gradient-index design model is constructed based on the homogeneous material properties of the titania silicate ion exchange glass. This model is verified by measuring the dispersion of fabricated GRIN profiles across the vis-SWIR spectrum. Finally, the polychromatic GRIN design model is implemented into commercial design software and several design studies are presented which validate the beneficial chromatic properties of the titania silicate GRIN material. In addition, system-level tolerancing with gradient-index elements is a largely unexplored area. This work introduces new methods and techniques for incorporating GRIN manufacturing errors directly into the design and tolerancing analysis of a multi-element optical system. These methods allow for the optical engineer to utilize manufacturable GRIN profiles throughout the design process and to better predict the final performance of an as-built system. Based on these techniques, a true design-for-manufacture high-performance eyepiece, utilizing a spherical gradient-index element, is designed, toleranced, and commissioned for build.

Flash Study Analysis and the Music Learning Pro-Files Project

ERIC Educational Resources Information Center

Cremata, Radio; Pignato, Joseph; Powell, Bryan; Smith, Gareth Dylan

2016-01-01

This paper introduces the Music Learning Profiles Project, and its methodological approach, flash study analysis. Flash study analysis is a method that draws heavily on extant qualitative approaches to education research, to develop broad understandings of music learning in diverse contexts. The Music Learning Profiles Project (MLPP) is an…

Analysis of BSRT Profiles in the LHC at Injection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fitterer, M.; Stancari, G.; Papadopoulou, S.

The beam synchrotron radiation telescope (BSRT) at the LHC allows to take profiles of the transverse beam distribution, which can provide useful additional insight in the evolution of the transverse beam distribution. A python class has been developed [1], which allows to read in the BSRT profiles, usually stored in binary format, run different analysis tools and generate plots of the statistical parameters and profiles as well as videos of the the profiles. The detailed analysis will be described in this note. The analysis is based on the data obtained at injection energy (450 GeV) during MD1217 [2] and MD1415more » [3] which will be also used as illustrative example. A similar approach is also taken with a MATLAB based analysis described in [4].« less

Modeling of U-series Radionuclide Transport Through Soil at Pena Blanca, Chihuahua, Mexico

NASA Astrophysics Data System (ADS)

Pekar, K. E.; Goodell, P. C.; Walton, J. C.; Anthony, E. Y.; Ren, M.

2007-05-01

The Nopal I uranium deposit is located at Pena Blanca in Chihuahua, Mexico. Mining of high-grade uranium ore occurred in the early 1980s, with the ore stockpiled nearby. The stockpile was mostly cleared in the 1990s; however, some of the high-grade boulders have remained there, creating localized sources of radioactivity for a period of 25-30 years. This provides a unique opportunity to study radionuclide transport, because the study area did not have any uranium contamination predating the stockpile in the 1980s. One high-grade boulder was selected for study based upon its shape, location, and high activity. The presumed drip-line off of the boulder was marked, samples from the boulder surface were taken, and then the boulder was moved several feet away. Soil samples were taken from directly beneath the boulder, around the drip-line, and down slope. Eight of these samples were collected in a vertical profile directly beneath the boulder. Visible flakes of boulder material were removed from the surficial soil samples, because they would have higher concentrations of U-series radionuclides and cause the activities in the soil samples to be excessively high. The vertical sampling profile used 2-inch thicknesses for each sample. The soil samples were packaged into thin plastic containers to minimize the attenuation and to standardize sample geometry, and then they were analyzed by gamma-ray spectroscopy with a Ge(Li) detector for Th-234, Pa-234, U-234, Th-230, Ra-226, Pb-214, Bi-214, and Pb-210. The raw counts were corrected for self-attenuation and normalized using BL-5, a uranium standard from Beaverlodge, Saskatchewan. BL-5 allowed the counts obtained on the Ge(Li) to be referenced to a known concentration or activity, which was then applied to the soil unknowns for a reliable calculation of their concentrations. Gamma ray spectra of five soil samples from the vertical profile exhibit decreasing activities with increasing depth for the selected radionuclides. Independent multi-element analyses of three samples by ICP-MS show decreasing uranium concentration with depth as well. The transport of the radionuclides is evaluated using STANMOD, a Windows-based software package for evaluating solute transport in porous media using analytical solutions of the advection-dispersion solute transport equation. The package allows various one-dimensional, advection-dispersion parameters to be determined by fitting mathematical solutions of theoretical transport models to observed data. The results are promising for future work on the release rate of radionuclides from the boulder, the dominant mode of transport (e.g., particulate or dissolution), and the movement of radionuclides through porous media. The measured subsurface transport rates provide modelers with a model validation dataset.

Multi-element sewer slime impact pattern--a quantitative characteristic enabling identification of the source of heavy metal discharges into sewer systems.

PubMed

Kintrup, J; Wünsch, G

2001-11-01

The capability of sewer slime to accumulate heavy metals from municipal wastewater can be exploited to identify the sources of sewage sludge pollution. Former investigations of sewer slime looked for a few elements only and could, therefore, not account for deviations of the enrichment efficiency of the slime or for irregularities from sampling. Results of ICP-MS multi element determinations were analyzed by multivariate statistical methods. A new dimensionless characteristic "sewer slime impact" is proposed, which is zero for unloaded samples. Patterns expressed in this data format specifically extract the information required to identify the type of pollution and polluter quicker and with less effort and cost than hitherto.

The geochemical landscape of northwestern Wisconsin and adjacent parts of northern Michigan and Minnesota (geochemical data files)

USGS Publications Warehouse

Cannon, William F.; Woodruff, Laurel G.

2003-01-01

This data set consists of nine files of geochemical information on various types of surficial deposits in northwestern Wisconsin and immediately adjacent parts of Michigan and Minnesota. The files are presented in two formats: as dbase files in dbaseIV form and Microsoft Excel form. The data present multi-element chemical analyses of soils, stream sediments, and lake sediments. Latitude and longitude values are provided in each file so that the dbf files can be readily imported to GIS applications. Metadata files are provided in outline form, question and answer form and text form. The metadata includes information on procedures for sample collection, sample preparation, and chemical analyses including sensitivity and precision.

Optimized multisectioned acoustic liners

NASA Technical Reports Server (NTRS)

Baumeister, K. J.

1979-01-01

New calculations show that segmenting is most efficient at high frequencies with relatively long duct lengths where the attenuation is low for both uniform and segmented liners. Statistical considerations indicate little advantage in using optimized liners with more than two segments while the bandwidth of an optimized two-segment liner is shown to be nearly equal to that of a uniform liner. Multielement liner calculations show a large degradation in performance due to changes in assumed input modal structure. Computer programs are used to generate theoretical attenuations for a number of liner configurations for liners in a rectangular duct with no mean flow. Overall, the use of optimized multisectioned liners fails to offer sufficient advantage over a uniform liner to warrant their use except in low frequency single mode application.

Rapid calculation of acoustic fields from arbitrary continuous-wave sources.

PubMed

Treeby, Bradley E; Budisky, Jakub; Wise, Elliott S; Jaros, Jiri; Cox, B T

2018-01-01

A Green's function solution is derived for calculating the acoustic field generated by phased array transducers of arbitrary shape when driven by a single frequency continuous wave excitation with spatially varying amplitude and phase. The solution is based on the Green's function for the homogeneous wave equation expressed in the spatial frequency domain or k-space. The temporal convolution integral is solved analytically, and the remaining integrals are expressed in the form of the spatial Fourier transform. This allows the acoustic pressure for all spatial positions to be calculated in a single step using two fast Fourier transforms. The model is demonstrated through several numerical examples, including single element rectangular and spherically focused bowl transducers, and multi-element linear and hemispherical arrays.

Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Fuxiang; Tong, Yang; Jin, Ke

In order to study chemical complexity-induced lattice distortion in high-entropy alloys, the static Debye–Waller (D-W) factor of NiCoFeMnCr solid solution alloy is measured with low temperature neutron diffraction, ambient X-ray diffraction, and total scattering methods. Here, the static atomic displacement parameter of the multi-element component alloy at 0 K is 0.035–0.041 Å, which is obvious larger than that of element Ni (~0 Å). The atomic pair distance between individual atoms in the alloy investigated with extended X-ray absorption fine structure (EXAFS) measurements indicates that Mn has a slightly larger bond distance (~0.4%) with neighbor atoms than that of others.

A new AMS facility based on a Cockcroft-Walton type 1 MV tandetron at IFIN-HH Magurele, Romania

NASA Astrophysics Data System (ADS)

Stan-Sion, C.; Enachescu, M.; Ghita, D. G.; Calinescu, C. I.; Petre, A.; Mosu, D. V.; Klein, M.

2014-01-01

A 1 MV AMS machine was recently installed in the National Institute for Physics and Nuclear Engineering IFIN-HH, Bucharest Romania. It is the second AMS facility at IFIN-HH having the goal not only to continue but mainly to enlarge the research area of this highly sensitive analyzing method. The multi-element AMS was developed by HVEE to measure 14C, 10Be, and 26Al, and 129I. The results of an acceptance test are presented and demonstrate that this machine is capable of routine 14C age dating and of measurements of other radioisotopes in terms of accuracy and precision as well as a low background level.

A COMPARISON OF PEER VIDEO MODELING AND SELF VIDEO MODELING TO TEACH TEXTUAL RESPONSES IN CHILDREN WITH AUTISM

PubMed Central

Marcus, Alonna; Wilder, David A

2009-01-01

Peer video modeling was compared to self video modeling to teach 3 children with autism to respond appropriately to (i.e., identify or label) novel letters. A combination multiple baseline and multielement design was used to compare the two procedures. Results showed that all 3 participants met the mastery criterion in the self-modeling condition, whereas only 1 of the participants met the mastery criterion in the peer-modeling condition. In addition, the participant who met the mastery criterion in both conditions reached the criterion more quickly in the self-modeling condition. Results are discussed in terms of their implications for teaching new skills to children with autism. PMID:19949521

Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy

DOE PAGES

Zhang, Fuxiang; Tong, Yang; Jin, Ke; ...

2018-06-16

In order to study chemical complexity-induced lattice distortion in high-entropy alloys, the static Debye–Waller (D-W) factor of NiCoFeMnCr solid solution alloy is measured with low temperature neutron diffraction, ambient X-ray diffraction, and total scattering methods. Here, the static atomic displacement parameter of the multi-element component alloy at 0 K is 0.035–0.041 Å, which is obvious larger than that of element Ni (~0 Å). The atomic pair distance between individual atoms in the alloy investigated with extended X-ray absorption fine structure (EXAFS) measurements indicates that Mn has a slightly larger bond distance (~0.4%) with neighbor atoms than that of others.

Implicit solvers for unstructured meshes

NASA Technical Reports Server (NTRS)

Venkatakrishnan, V.; Mavriplis, Dimitri J.

1991-01-01

Implicit methods were developed and tested for unstructured mesh computations. The approximate system which arises from the Newton linearization of the nonlinear evolution operator is solved by using the preconditioned GMRES (Generalized Minimum Residual) technique. Three different preconditioners were studied, namely, the incomplete LU factorization (ILU), block diagonal factorization, and the symmetric successive over relaxation (SSOR). The preconditioners were optimized to have good vectorization properties. SSOR and ILU were also studied as iterative schemes. The various methods are compared over a wide range of problems. Ordering of the unknowns, which affects the convergence of these sparse matrix iterative methods, is also studied. Results are presented for inviscid and turbulent viscous calculations on single and multielement airfoil configurations using globally and adaptively generated meshes.

The Effect of Cross Flow on Slat Noise

NASA Technical Reports Server (NTRS)

Lockard, David P.; Choudhari, Meelan M.

2010-01-01

This paper continues the computational examination (AIAA Journal, Vol. 45, No. 9, 2007, pp. 2174-2186) of the unsteady flow within the slat cove region of a multi-element high-lift airfoil configuration. Two simulations have been performed to examine the effect of cross flow on the near-field fluctuations and far-field acoustics. The cross flow was imposed by changing the free-stream velocity vector and modifying the Reynolds number. The cross flow does appear to alter the dynamics in the cove region, but the impact on the noise seems to be more dependent on the flow conditions. However, separating out the true effects of the cross flow from those of the Mach and Reynolds number would require additional calculations to isolate those effects.

A modular solid state detector for measuring high energy heavy ion fragmentation near the beam axis

NASA Technical Reports Server (NTRS)

Zeitlin, C. J.; Frankel, K. A.; Gong, W.; Heilbronn, L.; Lampo, E. J.; Leres, R.; Miller, J.; Schimmerling, W.

1994-01-01

A multi-element solid state detector has been designed to measure fluences of fragments produced near the beam axis by high energy heavy ion beams in thick targets. The detector is compact and modular, so as to be readily reconfigured according to the range of fragment charges and energies to be measured. Preamplifier gain settings and detector calibrations are adjustable remotely under computer control. We describe the central detector, its associated detectors and electronics, triggering scheme, data acquisition and particle identification techniques, illustrated by data taken with 600 MeV/u 56Fe beams and thick polyethylene targets at the LBL Bevalac. The applications of this work to space radiation protection are discussed.

Review of advanced radiator technologies for spacecraft power systems and space thermal control

NASA Technical Reports Server (NTRS)

Juhasz, Albert J.; Peterson, George P.

1994-01-01

A two-part overview of progress in space radiator technologies is presented. The first part reviews and compares the innovative heat-rejection system concepts proposed during the past decade, some of which have been developed to the breadboard demonstration stage. Included are space-constructable radiators with heat pipes, variable-surface-area radiators, rotating solid radiators, moving-belt radiators, rotating film radiators, liquid droplet radiators, Curie point radiators, and rotating bubble-membrane radiators. The second part summarizes a multielement project including focused hardware development under the Civil Space Technology Initiative (CSTI) High Capacity Power program carried out by the NASA Lewis Research Center and its contractors to develop lightweight space radiators in support of Space Exploration Initiative (SEI) power systems technology.

Gene integrated set profile analysis: a context-based approach for inferring biological endpoints

PubMed Central

Kowalski, Jeanne; Dwivedi, Bhakti; Newman, Scott; Switchenko, Jeffery M.; Pauly, Rini; Gutman, David A.; Arora, Jyoti; Gandhi, Khanjan; Ainslie, Kylie; Doho, Gregory; Qin, Zhaohui; Moreno, Carlos S.; Rossi, Michael R.; Vertino, Paula M.; Lonial, Sagar; Bernal-Mizrachi, Leon; Boise, Lawrence H.

2016-01-01

The identification of genes with specific patterns of change (e.g. down-regulated and methylated) as phenotype drivers or samples with similar profiles for a given gene set as drivers of clinical outcome, requires the integration of several genomic data types for which an ‘integrate by intersection’ (IBI) approach is often applied. In this approach, results from separate analyses of each data type are intersected, which has the limitation of a smaller intersection with more data types. We introduce a new method, GISPA (Gene Integrated Set Profile Analysis) for integrated genomic analysis and its variation, SISPA (Sample Integrated Set Profile Analysis) for defining respective genes and samples with the context of similar, a priori specified molecular profiles. With GISPA, the user defines a molecular profile that is compared among several classes and obtains ranked gene sets that satisfy the profile as drivers of each class. With SISPA, the user defines a gene set that satisfies a profile and obtains sample groups of profile activity. Our results from applying GISPA to human multiple myeloma (MM) cell lines contained genes of known profiles and importance, along with several novel targets, and their further SISPA application to MM coMMpass trial data showed clinical relevance. PMID:26826710