Two-phase ultraviolet spectrophotometry of the pulsating white dwarf ZZ Piscium

NASA Technical Reports Server (NTRS)

Bond, H. E.; Kemper, E.; Grauer, A. D.; Holm, A. V.; Panek, R. J.; Schiffer, F. H., III

1985-01-01

Spectra of the pulsating white dwarf ZZ Psc (= G29-38) were obtained using the International Ultraviolet Explorer. By using a multiple-exposure technique in conjunction with simultaneous ground-based exposure-metering photometry, it was possible to obtain mean on-pulse and off-pulse spectra in the 1950-1310 A wavelength range. The ratio of the time-averaged on-pulse to off-pulse spectra is best fitted by a temperature variation that is in phase with the optical light variation. This result is consistent with the hypothesis that the observed variation is due to a high-order nonradial pulsation. Conventional ultraviolet spectra of ZZ Psc showed broad absorption features at 1390 and 1600 A. These features are also found in the spectra of the cool DA-type white dwarfs G226-29 and G67-23, and appear to increase in strength with decreasing temperature. A possible explanation for the 1600 A feature is absorption by the satellite band of resonance-broadened hydrogen Ly-alpha. Such absorption would also help explain a discrepancy between the observed pulsation amplitude shortward of 1650 A and the predicted amplitudes based on model atmospheres.

Spectroscopy as a tool for geochemical modeling

NASA Astrophysics Data System (ADS)

Kopacková, Veronika; Chevrel, Stephane; Bourguignon, Anna

2011-11-01

This study focused on testing the feasibility of up-scaling ground-spectra-derived parameters to HyMap spectral and spatial resolution and whether they could be further used for a quantitative determination of the following geochemical parameters: As, pH and Clignite content. The study was carried on the Sokolov lignite mine as it represents a site with extreme material heterogeneity and high heavy-metal gradients. A new segmentation method based on the unique spectral properties of acid materials was developed and applied to the multi-line HyMap image data corrected for BRDF and atmospheric effects. The quantitative parameters were calculated for multiple absorption features identified within the VIS/VNIR/SWIR regions (simple band ratios, absorption band depth and quantitative spectral feature parameters calculated dynamically for each spectral measurement (centre of the absorption band (λ), depth of the absorption band (D), width of the absorption band (Width), and asymmetry of the absorption band (S)). The degree of spectral similarity between the ground and image spectra was assessed. The linear models for pH, As and the Clignite content of the whole and segmented images were cross-validated on the selected homogenous areas defined in the HS images using ground truth. For the segmented images, reliable results were achieved as follows: As: R2=0.84, Clignite: R2=0.88 and R2 pH: R2= 0.57.

Observations of circumstellar carbon monoxide and evidence for multiple ejections in red giants

NASA Technical Reports Server (NTRS)

Bernat, A. P.

1981-01-01

Observations of the fundamental 4.6 micron band of CO in nine red giants are presented. A common feature is multiple absorption lines which are identified as products of separate components or shells. Column densities are derived; the relative values should be free of the uncertainties inherent in determining the absolute scale. These column densities are well fitted by single excitation temperatures for each absorption component; these excitation temperatures are identified with the local kinetic temperatures. There is no correlation of CO column density with either gas or dust column density nor of the expansion velocity of the component with its distance from the star. The evidence is reviewed, and it is concluded that mass loss from red giants is most likely episodic in nature.

Si K EDGE STRUCTURE AND VARIABILITY IN GALACTIC X-RAY BINARIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schulz, Norbert S.; Corrales, Lia; Canizares, Claude R.

2016-08-10

We survey the Si K edge structure in various absorbed Galactic low-mass X-ray binaries (LMXBs) to study states of silicon in the inter- and circum-stellar medium. The bulk of these LMXBs lie toward the Galactic bulge region and all have column densities above 10{sup 22} cm{sup −2}. The observations were performed using the Chandra High Energy Transmission Grating Spectrometer. The Si K edge in all sources appears at an energy value of 1844 ± 0.001 eV. The edge exhibits significant substructure that can be described by a near edge absorption feature at 1849 ± 0.002 eV and a far edgemore » absorption feature at 1865 ± 0.002 eV. Both of these absorption features appear variable with equivalent widths up to several mÅ. We can describe the edge structure using several components: multiple edge functions, near edge absorption excesses from silicates in dust form, signatures from X-ray scattering optical depths, and a variable warm absorber from ionized atomic silicon. The measured optical depths of the edges indicate much higher values than expected from atomic silicon cross sections and interstellar medium abundances, and they appear consistent with predictions from silicate X-ray absorption and scattering. A comparison with models also indicates a preference for larger dust grain sizes. In many cases, we identify Si xiii resonance absorption and determine ionization parameters between log ξ = 1.8 and 2.8 and turbulent velocities between 300 and 1000 km s{sup −1}. This places the warm absorber in close vicinity of the X-ray binaries. In some data, we observe a weak edge at 1.840 keV, potentially from a lesser contribution of neutral atomic silicon.« less

Laser absorption spectroscopy of oxygen confined in highly porous hollow sphere xerogel.

PubMed

Yang, Lin; Somesfalean, Gabriel; He, Sailing

2014-02-10

An Al2O3 xerogel with a distinctive microstructure is studied for the application of laser absorption spectroscopy of oxygen. The xerogel has an exceptionally high porosity (up to 88%) and a large pore size (up to 3.6 µm). Using the method of gas-in-scattering media absorption spectroscopy (GASMAS), a long optical path length (about 3.5m) and high enhancement factor (over 300 times) are achieved as the result of extremely strong multiple-scattering when the light is transmitted through the air-filled, hollow-sphere alumina xerogel. We investigate how the micro-physical feature influences the optical property. As part of the optical sensing system, the material's gas exchange dynamics are also experimentally studied.

Effect of absorption recovery in bismuth-doped silica glass at 1450 nm on soliton grouping in fiber laser

PubMed Central

Gumenyuk, R.; Melkumov, M. A.; Khopin, V. F.; Dianov, E. M.; Okhotnikov, O. G.

2014-01-01

Saturable absorption in bismuth-doped glasses was found to have a noticeable influence on soliton interaction and group formation. This phenomenon, observed in 1450 nm mode-locked bismuth-doped fiber laser, shows the distinct feature of the multiple pulse regime, which appears as a stationary pulse group whose length can be spread over the whole cavity length by variation of the pump power and polarization. Pulse positioning within the ensemble depends on the saturation fluence and the relatively fast recovery dynamics of bismuth fiber. PMID:25391808

Polar Expansion Dynamics in the Plant Kingdom: A Diverse and Multifunctional Journey on the Path to Pollen Tubes

PubMed Central

Domozych, David S.; Fujimoto, Chelsea; LaRue, Therese

2013-01-01

Polar expansion is a widespread phenomenon in plants spanning all taxonomic groups from the Charophycean Green Algae to pollen tubes in Angiosperms and Gymnosperms. Current data strongly suggests that many common features are shared amongst cells displaying polar growth mechanics including changes to the structural features of localized regions of the cell wall, mobilization of targeted secretion mechanisms, employment of the actin cytoskeleton for directing secretion and in many cases, endocytosis and coordinated interaction of multiple signal transduction mechanisms prompted by external biotic and abiotic cues. The products of polar expansion perform diverse functions including delivery of male gametes to the egg, absorption, anchorage, adhesion and photo-absorption efficacy. A comparative analysis of polar expansion dynamics is provided with special emphasis on those found in early divergent plants. PMID:27137370

Changes in the Far UV Spectrum of Eta Carinae Near the 2003 Minimum

NASA Technical Reports Server (NTRS)

Iping, R. C.; Gull, T. R.; Sonneborn, G.; Massa, D.; Vieira, G. L.; Nielsen, K. E.

2004-01-01

High resolution 905-1180 spectra of \\eta Carinae have been obtained with the Far Ultraviolet Spectroscopic Explorer (FUSE) satellite at nine epochs between February 2000 and June 2003 . This period of time extends from the broad maximum up to the very beginning of the minimum of the 5.52-year period initially discovered by A. Damineli. The flux levels were unchanged between February 2000 through February 2003 with minor spectral differences. The X-Ray minimum started on June 29, 2003 . Three observations were accomplished on June 10, June 17 and June 27 leading up to the minimum. Substantial changes were present in the June 10 and June 17 spectra, but a very significant change occurred by June 27, 2003. Longward of 1100A, the overall flux dropped 10 to 30 %. Shortward of 1100A, there are spectral intervals with NO decrease in flux even down to the shortest wavelengths (920--950 ). This indicates that dust absorption has a negligible role in the observed spectral changes and that line absorptions play a major role. Throughout the spectrum there are intervals ranging in width of 3-10A with strong increased absorption. Significant absorptions may be associated with the red portion of the following stellar wind lines: C III 977, O VI 1031,1037, P V 1117, while other absorption features are much broader, more extended and not clearly associated with well-known spectral transitions. Given the complexity of the STIS echelle spectra taken in this period of time, many of these absorption features are likely due to multiple absorption lines

Sub-diffraction limit laser ablation via multiple exposures using a digital micromirror device.

PubMed

Heath, Daniel J; Grant-Jacob, James A; Feinaeugle, Matthias; Mills, Ben; Eason, Robert W

2017-08-01

We present the use of digital micromirror devices as variable illumination masks for pitch-splitting multiple exposures to laser machine the surfaces of materials. Ultrafast laser pulses of length 150 fs and 800 nm central wavelength were used for the sequential machining of contiguous patterns on the surface of samples in order to build up complex structures with sub-diffraction limit features. Machined patterns of tens to hundreds of micrometers in lateral dimensions with feature separations as low as 270 nm were produced in electroless nickel on an optical setup diffraction limited to 727 nm, showing a reduction factor below the Abbe diffraction limit of ∼2.7×. This was compared to similar patterns in a photoresist optimized for two-photon absorption, which showed a reduction factor of only 2×, demonstrating that multiple exposures via ablation can produce a greater resolution enhancement than via two-photon polymerization.

Local structural effects in Sr 3NiRhO 6 across magnetic transitions

DOE PAGES

Singh, Navneet; Khalid, S.; Bindu, R.

2016-04-06

Here, we investigate the temperature dependence of the structural parameters of quasi-one-dimensional Sr 3NiRhO 6 across the region of magnetic phase transitions using Ni K-edge and Sr K-edge x-ray absorption spectroscopy (XAS). The features in the x-ray absorption near-edge region are identified using multiple scattering calculations. The temperature-dependent extended x-ray absorption fine structure (EXAFS) studies show that the setting of the intra-chain super exchange interaction starts at ~200 K, which is well above the first transition temperature (45 K) revealed by magnetic susceptibility studies. The onset of the inter-chain super–super exchange interaction appears to be at ~125 K. Interestingly, themore » role played by direct exchange interaction between the Ni 3d and Rh 4d states in stabilising the magnetic interaction is less significant. The present results shed light on the generic features exhibited by isostructural compounds and may help in identifying the magnetic exchange pathways useful for understanding the unusual properties exhibited by such compounds.« less

Mapping the mineralogy and lithology of Canyonlands, Utah with imaging spectrometer data and the multiple spectral feature mapping algorithm

NASA Technical Reports Server (NTRS)

Clark, Roger N.; Swayze, Gregg A.; Gallagher, Andrea

1992-01-01

The sedimentary sections exposed in the Canyonlands and Arches National Parks region of Utah (generally referred to as 'Canyonlands') consist of sandstones, shales, limestones, and conglomerates. Reflectance spectra of weathered surfaces of rocks from these areas show two components: (1) variations in spectrally detectable mineralogy, and (2) variations in the relative ratios of the absorption bands between minerals. Both types of information can be used together to map each major lithology and the Clark spectral features mapping algorithm is applied to do the job.

High-resolution optical measurements of atmospheric winds from space. I - Lower atmosphere molecular absorption

NASA Technical Reports Server (NTRS)

Hays, P. B.

1982-01-01

A high-resolution spectroscopic technique, analogous to that used in the thermosphere to measure the vector wind fields in the upper troposphere and stratosphere, is described which uses narrow features in the spectrum of light scattered from the earth's lower atmosphere to provide Doppler information on atmospheric scattering and absorption. It is demonstrated that vector winds can be measured from a satellite throughout the lower atmosphere, using a multiple-etalon Fabry-Perot interferometer of modest aperture. It is found that molecular oxygen and water vapor absorption lines in the spectrum of sunlight scattered by the atmosphere are Doppler-shifted by the line of sight wind, so that they may be used to monitor the global wind systems in the upper troposphere and stratosphere.

X-ray absorption spectroscopic studies of mononuclear non-heme iron enzymes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westre, Tami E.

Fe-K-edge X-ray absorption spectroscopy (XAS) has been used to investigate the electronic and geometric structure of the iron active site in non-heme iron enzymes. A new theoretical extended X-ray absorption fine structure (EXAFS) analysis approach, called GNXAS, has been tested on data for iron model complexes to evaluate the utility and reliability of this new technique, especially with respect to the effects of multiple-scattering. In addition, a detailed analysis of the 1s→3d pre-edge feature has been developed as a tool for investigating the oxidation state, spin state, and geometry of iron sites. Edge and EXAFS analyses have then been appliedmore » to the study of non-heme iron enzyme active sites.« less

Titan solar occultation observations reveal transit spectra of a hazy world.

PubMed

Robinson, Tyler D; Maltagliati, Luca; Marley, Mark S; Fortney, Jonathan J

2014-06-24

High-altitude clouds and hazes are integral to understanding exoplanet observations, and are proposed to explain observed featureless transit spectra. However, it is difficult to make inferences from these data because of the need to disentangle effects of gas absorption from haze extinction. Here, we turn to the quintessential hazy world, Titan, to clarify how high-altitude hazes influence transit spectra. We use solar occultation observations of Titan's atmosphere from the Visual and Infrared Mapping Spectrometer aboard National Aeronautics and Space Administration's (NASA) Cassini spacecraft to generate transit spectra. Data span 0.88-5 μm at a resolution of 12-18 nm, with uncertainties typically smaller than 1%. Our approach exploits symmetry between occultations and transits, producing transit radius spectra that inherently include the effects of haze multiple scattering, refraction, and gas absorption. We use a simple model of haze extinction to explore how Titan's haze affects its transit spectrum. Our spectra show strong methane-absorption features, and weaker features due to other gases. Most importantly, the data demonstrate that high-altitude hazes can severely limit the atmospheric depths probed by transit spectra, bounding observations to pressures smaller than 0.1-10 mbar, depending on wavelength. Unlike the usual assumption made when modeling and interpreting transit observations of potentially hazy worlds, the slope set by haze in our spectra is not flat, and creates a variation in transit height whose magnitude is comparable to those from the strongest gaseous-absorption features. These findings have important consequences for interpreting future exoplanet observations, including those from NASA's James Webb Space Telescope.

Dynamical scattering in coherent hard x-ray nanobeam Bragg diffraction

NASA Astrophysics Data System (ADS)

Pateras, A.; Park, J.; Ahn, Y.; Tilka, J. A.; Holt, M. V.; Kim, H.; Mawst, L. J.; Evans, P. G.

2018-06-01

Unique intensity features arising from dynamical diffraction arise in coherent x-ray nanobeam diffraction patterns of crystals having thicknesses larger than the x-ray extinction depth or exhibiting combinations of nanoscale and mesoscale features. We demonstrate that dynamical scattering effects can be accurately predicted using an optical model combined with the Darwin theory of dynamical x-ray diffraction. The model includes the highly divergent coherent x-ray nanobeams produced by Fresnel zone plate focusing optics and accounts for primary extinction, multiple scattering, and absorption. The simulation accurately reproduces the dynamical scattering features of experimental diffraction patterns acquired from a GaAs/AlGaAs epitaxial heterostructure on a GaAs (001) substrate.

Imaging-based molecular barcoding with pixelated dielectric metasurfaces

NASA Astrophysics Data System (ADS)

Tittl, Andreas; Leitis, Aleksandrs; Liu, Mingkai; Yesilkoy, Filiz; Choi, Duk-Yong; Neshev, Dragomir N.; Kivshar, Yuri S.; Altug, Hatice

2018-06-01

Metasurfaces provide opportunities for wavefront control, flat optics, and subwavelength light focusing. We developed an imaging-based nanophotonic method for detecting mid-infrared molecular fingerprints and implemented it for the chemical identification and compositional analysis of surface-bound analytes. Our technique features a two-dimensional pixelated dielectric metasurface with a range of ultrasharp resonances, each tuned to a discrete frequency; this enables molecular absorption signatures to be read out at multiple spectral points, and the resulting information is then translated into a barcode-like spatial absorption map for imaging. The signatures of biological, polymer, and pesticide molecules can be detected with high sensitivity, covering applications such as biosensing and environmental monitoring. Our chemically specific technique can resolve absorption fingerprints without the need for spectrometry, frequency scanning, or moving mechanical parts, thereby paving the way toward sensitive and versatile miniaturized mid-infrared spectroscopy devices.

A Hubble Space Telescope Survey of Intrinsic Absorption in Nearby AGN

NASA Astrophysics Data System (ADS)

Dashtamirova, Dzhuliya; Dunn, Jay P.; Crenshaw, D. Michael

2017-01-01

We present a survey of the intrinsic UV absorption lines in active galactic nuclei (AGN). We limit our study to the ultraviolet spectra of type 1 AGN with a redshift of z < 0.15 as a continuation of the Dunn et al. (2007, 2008) and Crenshaw et al. (1999) studies of smaller samples. We identify approximately 90 AGN fit our redshift specifications in the Mikulski Archive for Space Telescopes (MAST) database with Cosmic Origin Spectrograph (COS) observations. We download and co-add all of the COS spectra. We find that about 80 of these are type 1 AGN. We normalize the COS spectra and identify all of the intrinsic Lyman-alpha, N V, Si IV, and C IV intrinsic absorption features. From these data, we determine the fraction of type 1 AGN with intrinsic absorption in this redshift range and find the global covering factors of the absorbers. We also identify low ionization species as well as excited state lines. A number of objects have multiple epoch COS and/or Space Telescope Imaging Spectrograph (STIS) observations, which we use to investigate the absorption variability.

X-ray Absorption and Emission Spectroscopy of CrIII (Hydr)Oxides: Analysis of the K-Pre-Edge Region

NASA Astrophysics Data System (ADS)

Frommer, Jakob; Nachtegaal, Maarten; Czekaj, Izabela; Weng, Tsu-Chien; Kretzschmar, Ruben

2009-10-01

Pre-edge spectral features below the main X-ray absorption K-edge of transition metals show a pronounced chemical sensitivity and are promising sources of structural information. Nevertheless, the use of pre-edge analysis in applied research is limited because of the lack of definite theoretical peak-assignments. The aim of this study was to determine the factors affecting the chromium K-pre-edge features in trivalent chromium-bearing oxides and oxyhydroxides. The selected phases varied in the degree of octahedral polymerization and the degree of iron-for-chromium substitution in the crystal structure. We investigated the pre-edge fine structure by means of high-energy-resolution fluorescence detected X-ray absorption spectroscopy and by 1s2p resonant X-ray emission spectroscopy. Multiplet theory and full multiple-scattering calculations were used to analyze the experimental data. We show that the chromium K-pre-edge contains localized and nonlocalized transitions. Contributions arising from nonlocalized metal-metal transitions are sensitive to the nearest metal type and to the linkage mode between neighboring metal octahedra. Analyzing these transitions opens up new opportunities for investigating the local coordination environment of chromium in poorly ordered solids of environmental relevance.

Seismic signatures of carbonate caves affected by near-surface absorptions

NASA Astrophysics Data System (ADS)

Rao, Ying; Wang, Yanghua

2015-12-01

The near-surface absorption within a low-velocity zone generally has an exponential attenuation effect on seismic waves. But how does this absorption affect seismic signatures of karstic caves in deep carbonate reservoirs? Seismic simulation and analysis reveals that, although this near-surface absorption attenuates the wave energy of a continuous reflection, it does not alter the basic kinematic shape of bead-string reflections, a special seismic characteristic associated with carbonate caves in the Tarim Basin, China. Therefore, the bead-strings in seismic profiles can be utilized, with a great certainty, for interpreting the existence of caves within the deep carbonate reservoirs and for evaluating their pore spaces. Nevertheless, the difference between the central frequency and the peak frequency is increased along with the increment in the absorption. While the wave energy of bead-string reflections remains strong, due to the interference of seismic multiples generated by big impedance contrast between the infill materials of a cave and the surrounding carbonate rocks, the central frequency is shifted linearly with respect to the near-surface absorption. These two features can be exploited simultaneously, for a stable attenuation analysis of field seismic data.

The correlated k-distribution technique as applied to the AVHRR channels

NASA Technical Reports Server (NTRS)

Kratz, David P.

1995-01-01

Correlated k-distributions have been created to account for the molecular absorption found in the spectral ranges of the five Advanced Very High Resolution Radiometer (AVHRR) satellite channels. The production of the k-distributions was based upon an exponential-sum fitting of transmissions (ESFT) technique which was applied to reference line-by-line absorptance calculations. To account for the overlap of spectral features from different molecular species, the present routines made use of the multiplication transmissivity property which allows for considerable flexibility, especially when altering relative mixing ratios of the various molecular species. To determine the accuracy of the correlated k-distribution technique as compared to the line-by-line procedure, atmospheric flux and heating rate calculations were run for a wide variety of atmospheric conditions. For the atmospheric conditions taken into consideration, the correlated k-distribution technique has yielded results within about 0.5% for both the cases where the satellite spectral response functions were applied and where they were not. The correlated k-distribution's principal advantages is that it can be incorporated directly into multiple scattering routines that consider scattering as well as absorption by clouds and aerosol particles.

Photonic crystal geometry for organic solar cells.

PubMed

Ko, Doo-Hyun; Tumbleston, John R; Zhang, Lei; Williams, Stuart; DeSimone, Joseph M; Lopez, Rene; Samulski, Edward T

2009-07-01

We report organic solar cells with a photonic crystal nanostructure embossed in the photoactive bulk heterojunction layer, a topography that exhibits a 3-fold enhancement of the absorption in specific regions of the solar spectrum in part through multiple excitation resonances. The photonic crystal geometry is fabricated using a materials-agnostic process called PRINT wherein highly ordered arrays of nanoscale features are readily made in a single processing step over wide areas (approximately 4 cm(2)) that is scalable. We show efficiency improvements of approximately 70% that result not only from greater absorption, but also from electrical enhancements. The methodology is generally applicable to organic solar cells and the experimental findings reported in our manuscript corroborate theoretical expectations.

Using high spectral resolution spectrophotometry to study broad mineral absorption features on Mars

NASA Technical Reports Server (NTRS)

Blaney, D. L.; Crisp, D.

1993-01-01

Traditionally telescopic measurements of mineralogic absorption features have been made using relatively low to moderate (R=30-300) spectral resolution. Mineralogic absorption features tend to be broad so high resolution spectroscopy (R greater than 10,000) does not provide significant additional compositional information. Low to moderate resolution spectroscopy allows an observer to obtain data over a wide wavelength range (hundreds to thousands of wavenumbers) compared to the several wavenumber intervals that are collected using high resolution spectrometers. However, spectrophotometry at high resolution has major advantages over lower resolution spectroscopy in situations that are applicable to studies of the Martian surface, i.e., at wavelengths where relatively weak surface absorption features and atmospheric gas absorption features both occur.

Scramjet Performance Assessment Using Water Absorption Diagnostics (U)

NASA Technical Reports Server (NTRS)

Cavolowsky, John A.; Loomis, Mark P.; Deiwert, George

1995-01-01

Simultaneous multiple path measurements of temperature and H2O concentration will be presented for the AIMHYE test entries in the NASA Ames 16-Inch Shock Tunnel. Monitoring the progress of high temperature chemical reactions that define scramjet combustor efficiencies is a task uniquely suited to nonintrusive optical diagnostics. One application strategy to overcome the many challenges and limitations of nonintrusive measurements is to use laser absorption spectroscopy coupled with optical fibers. Absorption spectroscopic techniques with rapidly tunable lasers are capable of making simultaneous measurements of mole fraction, temperature, pressure, and velocity. The scramjet water absorption diagnostic was used to measure combustor efficiency and was compared to thrust measurements using a nozzle force balance and integrated nozzle pressures to develop a direct technique for evaluating integrated scramjet performance. Tests were initially performed with a diode laser tuning over a water absorption feature at 1391.7 nm. A second diode laser later became available at a wavelength near 1343.3 nm covering an additional water absorption feature and was incorporated in the system for a two-wavelength technique. Both temperature and mole fraction can be inferred from the lineshape analysis using this approach. Additional high temperature spectroscopy research was conducted to reduce uncertainties in the scramjet application. The lasers are optical fiber coupled to ports at the combustor exit and in the nozzle region. The output from the two diode lasers were combined in a single fiber, and the resultant two-wavelength beam was subsequently split into four legs. Each leg was directed through 60 meters of optical fiber to four combustor exit locations for measurement of beam intensity after absorption by the water within the flow. Absorption results will be compared to 1D combustor analysis using RJPA and nozzle CFD computations as well as to data from a nozzle metric balance measuring thrust and integrated pressure measurements along the length of the nozzle. Assessment of its value as a combustor performance evaluation tool will be conducted.

The Mean Metal-line Absorption Spectrum of Damped Ly α Systems in BOSS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mas-Ribas, Lluís; Miralda-Escudé, Jordi; Pérez-Ràfols, Ignasi

We study the mean absorption spectrum of the Damped Ly α (DLA) population at z ∼ 2.6 by stacking normalized, rest-frame-shifted spectra of ∼27,000 DLA systems from the DR12 of the Baryon Oscillation Spectroscopic Survey (BOSS)/SDSS-III. We measure the equivalent widths of 50 individual metal absorption lines in five intervals of DLA hydrogen column density, five intervals of DLA redshift, and overall mean equivalent widths for an additional 13 absorption features from groups of strongly blended lines. The mean equivalent width of low-ionization lines increases with N {sub H} {sub i}, whereas for high-ionization lines the increase is much weaker.more » The mean metal line equivalent widths decrease by a factor ∼1.1–1.5 from z ∼ 2.1 to z ∼ 3.5, with small or no differences between low- and high-ionization species. We develop a theoretical model, inspired by the presence of multiple absorption components observed in high-resolution spectra, to infer mean metal column densities from the equivalent widths of partially saturated metal lines. We apply this model to 14 low-ionization species and to Al iii, S iii, Si iii, C iv, Si iv, N v, and O vi. We use an approximate derivation for separating the equivalent width contributions of several lines to blended absorption features, and infer mean equivalent widths and column densities from lines of the additional species N i, Zn ii, C ii*, Fe iii, and S iv. Several of these mean column densities of metal lines in DLAs are obtained for the first time; their values generally agree with measurements of individual DLAs from high-resolution, high signal-to-noise ratio spectra when they are available.« less

Configuration of Pluto's Volatile Ices

NASA Astrophysics Data System (ADS)

Grundy, William M.; Binzel, R. P.; Cook, J. C.; Cruikshank, D. P.; Dalle Ore, C. M.; Earle, A. M.; Ennico, K.; Jennings, D. E.; Howett, C. J. A.; Linscott, I. R.; Lunsford, A. W.; Olkin, C. B.; Parker, A. H.; Parker, J. Wm; Protopapa, S.; Reuter, D. C.; Singer, K. N.; Spencer, J. R.; Stern, S. A.; Tsang, C. C. C.; Verbiscer, A. J.; Weaver, H. A.; Young, L. A.; Berry, K.; Buie, M. W.; Stansberry, J. A.

2015-11-01

We report on near-infrared remote sensing by New Horizons' Ralph instrument (Reuter et al. 2008, Space Sci. Rev. 140, 129-154) of Pluto's N2, CO, and CH4 ices. These especially volatile ices are mobile even at Pluto's cryogenic surface temperatures. Sunlight reflected from these ices becomes imprinted with their characteristic spectral absorption bands. The detailed appearance of these absorption features depends on many aspects of local composition, thermodynamic state, and texture. Multiple-scattering radiative transfer models are used to retrieve quantitative information about these properties and to map how they vary across Pluto's surface. Using parameter maps derived from New Horizons observations, we investigate the striking regional differences in the abundances and scattering properties of Pluto's volatile ices. Comparing these spatial patterns with the underlying geology provides valuable constraints on processes actively modifying the planet's surface, over a variety of spatial scales ranging from global latitudinal patterns to more regional and local processes within and around the feature informally known as Sputnik Planum. This work was supported by the NASA New Horizons Project.

Titan solar occultation observations reveal transit spectra of a hazy world

PubMed Central

Robinson, Tyler D.; Maltagliati, Luca; Marley, Mark S.; Fortney, Jonathan J.

2014-01-01

High-altitude clouds and hazes are integral to understanding exoplanet observations, and are proposed to explain observed featureless transit spectra. However, it is difficult to make inferences from these data because of the need to disentangle effects of gas absorption from haze extinction. Here, we turn to the quintessential hazy world, Titan, to clarify how high-altitude hazes influence transit spectra. We use solar occultation observations of Titan’s atmosphere from the Visual and Infrared Mapping Spectrometer aboard National Aeronautics and Space Administration’s (NASA) Cassini spacecraft to generate transit spectra. Data span 0.88–5 μm at a resolution of 12–18 nm, with uncertainties typically smaller than 1%. Our approach exploits symmetry between occultations and transits, producing transit radius spectra that inherently include the effects of haze multiple scattering, refraction, and gas absorption. We use a simple model of haze extinction to explore how Titan’s haze affects its transit spectrum. Our spectra show strong methane-absorption features, and weaker features due to other gases. Most importantly, the data demonstrate that high-altitude hazes can severely limit the atmospheric depths probed by transit spectra, bounding observations to pressures smaller than 0.1–10 mbar, depending on wavelength. Unlike the usual assumption made when modeling and interpreting transit observations of potentially hazy worlds, the slope set by haze in our spectra is not flat, and creates a variation in transit height whose magnitude is comparable to those from the strongest gaseous-absorption features. These findings have important consequences for interpreting future exoplanet observations, including those from NASA’s James Webb Space Telescope. PMID:24876272

Red and near-infrared fluorophores inspired by chlorophylls: consideration of practical brightness in multicolor flow cytometry and biomedical sciences

NASA Astrophysics Data System (ADS)

Taniguchi, Masahiko; Hu, Gongfang; Liu, Rui; Du, Hai; Lindsey, Jonathan S.

2018-02-01

Demands in flow cytometry for increased multiplexing (for detection of multiple antigens) and brightness (for detection of rare entities) require new fluorophores (i.e., "colors") with spectrally distinct fluorescence outside the relatively congested visible spectral region. Flow cytometry fluorophores typically must function in aqueous solution upon bioconjugation and ideally should exhibit a host of photophysical features: (i) strong absorption, (ii) sizable Stokes shift, (iii) modest if not strong fluorescence, and (iv) narrow fluorescence band. Tandem dyes have long been pursued to achieve a large effective Stokes shift, increased brightness, and better control over the excitation and emission wavelengths. Here, the attractive photophysical features of chlorophylls and bacteriochlorophylls - Nature's chosen photoactive pigments for photosynthesis - are described with regards to use in flow cytometry. A chlorophyll (or bacteriochlorophyll) constitutes an intrinsic tandem dye given the red (or near-infrared) fluorescence upon excitation in the higher energy ultraviolet (UV) or visible absorption bands (due to rapid internal conversion to the lowest energy state). Synthetic (bacterio)chlorins are available with strong absorption (near-UV molar absorption coefficient ɛ(λexc) 105 M-1cm-1), modest fluorescence quantum yield (Φf = 0.05-0.30), and narrow fluorescence band (10-25 nm) tunable from 600-900 nm depending on synthetic design. The "relative practical brightness" is given by intrinsic brightness [ɛ(λexc) x Φf] times ηf, the fraction of the fluorescence band that is captured by an emission filter in a multicolor experiment. The spectroscopic features of (bacterio)chlorins are evaluated quantitatively to illustrate practical brightness for this novel class of fluorophores in a prospective 8-color panel.

Attosecond transient absorption probing of electronic superpositions of bound states in neon. Detection of quantum beats

DOE PAGES

Beck, Annelise R; Bernhardt, Birgitta; Warrick, Erika R.; ...

2014-11-07

Electronic wavepackets composed of multiple bound excited states of atomic neon lying between 19.6 and 21.5 eV are launched using an isolated attosecond pulse. Individual quantum beats of the wavepacket are detected by perturbing the induced polarization of the medium with a time-delayed few-femtosecond near-infrared (NIR) pulse via coupling the individual states to multiple neighboring levels. All of the initially excited states are monitored simultaneously in the attosecond transient absorption spectrum, revealing Lorentzian to Fano lineshape spectral changes as well as quantum beats. The most prominent beating of the several that were observed was in the spin–orbit split 3d absorptionmore » features, which has a 40 femtosecond period that corresponds to the spin–orbit splitting of 0.1 eV. The few-level models and multilevel calculations confirm that the observed magnitude of oscillation depends strongly on the spectral bandwidth and tuning of the NIR pulse and on the location of possible coupling states.« less

MODTRAN cloud and multiple scattering upgrades with application to AVIRIS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berk, A.; Bernstein, L.S.; Acharya, P.K.

1998-09-01

Recent upgrades to the MODTRAN atmospheric radiation code improve the accuracy of its radiance predictions, especially in the presence of clouds and thick aerosols, and for multiple scattering in regions of strong molecular line absorption. The current public-released version of MODTRAN (MODTRAN3.7) features a generalized specification of cloud properties, while the current research version of MODTRAN (MODTRAN4) implements a correlated-k (CK) approach for more accurate calculation of multiple scattered radiance. Comparisons to cloud measurements demonstrate the viability of the CK approach. The impact of these upgrades on predictions for AVIRIS viewing scenarios is discussed for both clear and clouded skies;more » the CK approach provides refined predictions for AVIRIS nadir and near-nadir viewing.« less

A multiple technique approach to the analysis of urinary calculi.

PubMed

Rodgers, A L; Nassimbeni, L R; Mulder, K J

1982-01-01

10 urinary calculi have been qualitatively and quantitatively analysed using X-ray diffraction, infra-red, scanning electron microscopy, X-ray fluorescence, atomic absorption and density gradient procedures. Constituents and compositional features which often go undetected due to limitations in the particular analytical procedure being used, have been identified and a detailed picture of each stone's composition and structure has been obtained. In all cases at least two components were detected suggesting that the multiple technique approach might cast some doubt as to the existence of "pure" stones. Evidence for a continuous, non-sequential deposition mechanism has been detected. In addition, the usefulness of each technique in the analysis of urinary stones has been assessed and the multiple technique approach has been evaluated as a whole.

Using the Properties of Broad Absorption Line Quasars to Illuminate Quasar Structure

NASA Astrophysics Data System (ADS)

Yong, Suk Yee; King, Anthea L.; Webster, Rachel L.; Bate, Nicholas F.; O'Dowd, Matthew J.; Labrie, Kathleen

2018-06-01

A key to understanding quasar unification paradigms is the emission properties of broad absorption line quasars (BALQs). The fact that only a small fraction of quasar spectra exhibit deep absorption troughs blueward of the broad permitted emission lines provides a crucial clue to the structure of quasar emitting regions. To learn whether it is possible to discriminate between the BALQ and non-BALQ populations given the observed spectral properties of a quasar, we employ two approaches: one based on statistical methods and the other supervised machine learning classification, applied to quasar samples from the Sloan Digital Sky Survey. The features explored include continuum and emission line properties, in particular the absolute magnitude, redshift, spectral index, line width, asymmetry, strength, and relative velocity offsets of high-ionisation C IV λ1549 and low-ionisation Mg II λ2798 lines. We consider a complete population of quasars, and assume that the statistical distributions of properties represent all angles where the quasar is viewed without obscuration. The distributions of the BALQ and non-BALQ sample properties show few significant differences. None of the observed continuum and emission line features are capable of differentiating between the two samples. Most published narrow disk-wind models are inconsistent with these observations, and an alternative disk-wind model is proposed. The key feature of the proposed model is a disk-wind filling a wide opening angle with multiple radial streams of dense clumps.

Pastes: what do they contain? How do they work?

PubMed

Juch, R D; Rufli, T; Surber, C

1994-01-01

Pastes are semisolid stiff preparations containing a high proportion of finely powdered material. Powders such as zinc oxide, titanium dioxide, starch, kaolin or talc are incorporated in high concentrations into a preferably lipophilic, greasy vehicle. A clinically distinctive feature which is generally attributed to pastes is the quality to absorb exudates by nature of the powder or other absorptive components. Reviewing the various pharmacopoeias serious doubts arise from the various formulas of pastes and their absorptive features. The zinc oxide pastes of the USP XXII, the DAB 10 and BP 88 (US, German and British pharmacopoeias). are composed of petrolatum, zinc oxide and starch. Petrolatum, a highly lipophilic, water-immiscible vehicle surrounds the powder particles preventing any absorption of water or exudates. The goal of our investigation was to test a simple experimental setting to characterize the clinically important absorptive feature of powders and pastes. The absorptive features of the powders were determined by the method of Enslin. The absorptive features of the paste preparations were calculated from the weight difference between the paste preparation before and after incubation with water using a simple standardized procedure. The absorptive features of titanium dioxide, zinc oxide, kaolin, corn starch and methylcellulose powder in pharmacopoeia quality were determined. Zinc oxide and kaolin powder showed the highest absorption of 1,000 mg water/g powder (100%). The water absorption of corn starch and titanium dioxide was 700 and 450 mg/g powder, respectively. The absorptive features of a series of paste preparations were studied in a simple experimental setting. The data show that two-phase pastes consisting of two immiscible components, one (the dispersed or inner phase; powder) being suspended in the other (the continuous or outer phase; lipophilic vehicle), have no absorptive features. In contrast, three-phase pastes consisting of a hydrophilic two-phase emulsion with high concentrations of incorporated powder (cream pastes) show considerable water uptake. We conclude that the classical two-phase pastes such as the zinc oxide pastes have no absorptive features. On the contrary, these formulations are highly occlusive. Therefore lipophilic pastes are only indicated when protection of intact skin against aggressive body exudates and humidity is required. The hydrophilic three-phase pastes or cream pastes show considerable water uptake and fulfil common expectations of pastes to dry the skin.

Hyperspectral imaging using novel LWIR OPO for hazardous material detection and identification

NASA Astrophysics Data System (ADS)

Ruxton, Keith; Robertson, Gordon; Miller, Bill; Malcolm, Graeme P. A.; Maker, Gareth T.

2014-05-01

Current stand-off hyperspectral imaging detection solutions that operate in the mid-wave infrared (MWIR), nominally 2.5 - 5 μm spectral region, are limited by the number of absorption bands that can be addressed. This issue is most apparent when evaluating a scene with multiple absorbers with overlapping spectral features making accurate material identification challenging. This limitation can be overcome by moving to the long wave IR (LWIR) region, which is rich in characteristic absorption features, which can provide ample molecular information in order to perform presumptive identification relative to a spectral library. This work utilises an instrument platform to perform negative contrast imaging using a novel LWIR optical parametric oscillator (OPO) as the source. The OPO offers continuous tuning in the region 5.5 - 9.5 μm, which includes a number of molecular vibrations associated with the target material compositions. Scanning the scene of interest whilst sweeping the wavelength of the OPO emission will highlight the presence of a suspect material and by analysing the resulting absorption spectrum, presumptive identification is possible. This work presents a selection of initial results using the LWIR hyperspectral imaging platform on a range of white powder materials to highlight the benefit operating in the LWIR region compared to the MWIR.

The Mysterious 6565 Å Absorption Feature of the Galactic Halo

NASA Astrophysics Data System (ADS)

Sethi, Shiv K.; Shchekinov, Yuri; Nath, Biman B.

2017-12-01

We consider various possible scenarios to explain the recent observation of what has been called a broad Hα absorption in our Galactic halo, with peak optical depth τ ≃ 0.01 and equivalent width W≃ 0.17 \\mathringA . We show that the absorbed feature cannot arise from the circumgalactic and ISM Hα absorption. As the observed absorption feature is quite broad ({{Δ }}λ ≃ 30 \\mathringA ), we also consider CNO lines that lie close to Hα as possible alternatives to explain the feature. We show that such lines could also not account for the observed feature. Instead, we suggest that it could arise from diffuse interstellar bands (DIBs) carriers or polyaromatic hydrocarbons (PAHs) absorption. While we identify several such lines close to the Hα transition, we are unable to determine the molecule responsible for the observed feature, partly because of selection effects that prevent us from identifying DIBs/PAHs features close to Hα using local observations. Deep integration of a few extragalactic sources with high spectral resolution might allow us to distinguish between different possible explanations.

A Noninvasive In Vivo Glucose Sensor Based on Mid-Infrared Quantum Cascade Laser Spectroscopy

NASA Astrophysics Data System (ADS)

Werth, Alexandra; Liakat, Sabbir; Xu, Laura; Gmachl, Claire

Diabetes affects over 387 million people worldwide; a number which grows every year. The most common method of measuring blood glucose concentration involves a finger prick which for some can be a harrowing process. Therefore, a portable, accurate, noninvasive glucose sensor can significantly improve the quality of life for many of these diabetics who draw blood multiple times a day to monitor their glucose levels. We have implemented a noninvasive, mobile glucose sensor using a mid-infrared (MIR) quantum cascade laser (QCL), integrating sphere, and thermal electrically (TE) cooled detector. The QCL is scanned from 8 - 10 microns wavelength over which are distinct absorption features of glucose molecules with little competition of absorption from other molecules found in the blood and interstitial fluid. The obtained absorption spectra are analyzed using a neural network algorithm which relates the small changes in absorption to the changing glucose concentration. The integrating sphere has increased the signal-to-noise ratio from a previous design, allowing us to use the TE-cooled detector which increases mobility without loss of accuracy.

Inherited Fe and Ti electron transition spectroscopic features in altered ultramafic-carbonatite intrusives

NASA Astrophysics Data System (ADS)

Shavers, E. J.; Ghulam, A.; Encarnacion, J. P.

2016-12-01

Spectroscopic reflectance in the visible to short-wave infrared region is an important tool for remote geologic mapping and is applied at scales from satellite to field measurements. Remote geologic mapping is challenging in regions subject to significant surficial weathering. Here we identify absorption features found in altered volcanic pipes and dikes in the Avon Volcanic District, Missouri, that are inherited from the original ultramafic and carbonatite lithology. Alteration ranges from small degree hydrothermal alteration to extensive laterization. The absorption features are three broad minima centered near 690, 890, and 1100 nm. Features in this region are recognized to be caused by ferric and ferrous Fe minerals including olivine, carbonates, chlorite, and goethite all of which are found among the Avon pipes and dikes that are in various stages of alteration. Iron-related intervalence charge transfer and crystal field perturbations of ions are the principal causes of the spectroscopic features in the visible to near-infrared region yet spectra are also distorted by factors like texture and the presence of opaque minerals known to reduce overall reflectance. In the Avon samples, Fe oxide content can reach >15 wt% leading to prominent absorption features even in the less altered ultramafics with reflectance curve maxima as low as 5%. The exaggerated minima allow the altered intrusive rocks to stand out among other weathered lithologies that will often have clay features in the region yet have lower iron concentration. The absorption feature centered near 690 nm is particularly noteworthy. Broad mineral-related absorption features centered at this wavelength are rare but have been linked to Ti3+ in octahedral coordination. The reduced form of Ti is not common in surface lithologies. Titanium-rich andradite has Ti3+ in the octahedral position, is resistant to weathering, is found among the Avon lithologies including ultramafic, carbonatite, and carbonated breccia, and is identified here as the cause of the 690 nm absorption feature. The Ti3+ absorption feature centered near 690 nm and strong Fe absorption features at 890 and 1100 nm may be useful indicators of rare intrusive lithologies in remote geologic mapping.

Fabry-Perot Based Radiometers for Precise Measurement of Greenhouse Gases

NASA Technical Reports Server (NTRS)

Heaps, William S.; Wilson, Emily L.; Georgieva, Elena

2007-01-01

Differential radiometers based upon the Fabry-Perot interferometer have been developed and demonstrated that exhibit very great sensitivity to changes in the atmospheric column of carbon dioxide, oxygen, and water vapor. These instruments employ a solid Fabry-Perot etalon that is tuned to the proper wavelength by changing the temperature. By choosing the thickness of the etalon its multiple pass bands can be made to align with regularly space absorption features of the molecule under investigation. Use of multiple absorption features improves the optical throughput of the instrument and improves the stability of the instrument response with respect to environmental changes. Efforts are underway at Goddard to extend this technique to the carbon 13 isotope of carbon dioxide and to methane. These instruments are intrinsically rugged and can be made rather small and inexpensively. They therefore hold promise for widespread use in ground based networks for calibration of satellite instruments such as OCO and GOSAT. Results will be presented for ground based and airborne operations for these systems. The effects of atmospheric scattering, pointing errors, pressure broadening and temperature effects will be discussed with regard to achieving precision better than .5% required for validation of carbon dioxide column measured from space. Designs permitting the extension of the technique to an even larger number of atmospheric species will be discussed along with theoretical analysis of potential system performance.

Anomalous photoluminescence in InP1−xBix

PubMed Central

Wu, Xiaoyan; Chen, Xiren; Pan, Wenwu; Wang, Peng; Zhang, Liyao; Li, Yaoyao; Wang, Hailong; Wang, Kai; Shao, Jun; Wang, Shumin

2016-01-01

Low temperature photoluminescence (PL) from InP1−xBix thin films with Bi concentrations in the 0–2.49% range reveals anomalous spectral features with strong and very broad (linewidth of 700 nm) PL signals compared to other bismide alloys. Multiple transitions are observed and their energy levels are found much smaller than the band-gap measured from absorption measurements. These transitions are related to deep levels confirmed by deep level transient spectroscopy, which effectively trap free holes and enhance radiative recombination. The broad luminescence feature is beneficial for making super-luminescence diodes, which can theoretically enhance spatial resolution beyond 1 μm in optical coherent tomography (OCT). PMID:27291823

Optical devices featuring textured semiconductor layers

DOEpatents

Moustakas, Theodore D [Dover, MA; Cabalu, Jasper S [Cary, NC

2011-10-11

A semiconductor sensor, solar cell or emitter, or a precursor therefor, has a substrate and one or more textured semiconductor layers deposited onto the substrate. The textured layers enhance light extraction or absorption. Texturing in the region of multiple quantum wells greatly enhances internal quantum efficiency if the semiconductor is polar and the quantum wells are grown along the polar direction. Electroluminescence of LEDs of the invention is dichromatic, and results in variable color LEDs, including white LEDs, without the use of phosphor.

Optical devices featuring textured semiconductor layers

DOEpatents

Moustakas, Theodore D [Dover, MA; Cabalu, Jasper S [Cary, NC

2012-08-07

A semiconductor sensor, solar cell or emitter, or a precursor therefor, has a substrate and one or more textured semiconductor layers deposited onto the substrate. The textured layers enhance light extraction or absorption. Texturing in the region of multiple quantum wells greatly enhances internal quantum efficiency if the semiconductor is polar and the quantum wells are grown along the polar direction. Electroluminescence of LEDs of the invention is dichromatic, and results in variable color LEDs, including white LEDs, without the use of phosphor.

Frequency-domain method for measuring spectral properties in multiple-scattering media: methemoglobin absorption spectrum in a tissuelike phantom

NASA Astrophysics Data System (ADS)

Fishkin, Joshua B.; So, Peter T. C.; Cerussi, Albert E.; Gratton, Enrico; Fantini, Sergio; Franceschini, Maria Angela

1995-03-01

We have measured the optical absorption and scattering coefficient spectra of a multiple-scattering medium (i.e., a biological tissue-simulating phantom comprising a lipid colloid) containing methemoglobin by using frequency-domain techniques. The methemoglobin absorption spectrum determined in the multiple-scattering medium is in excellent agreement with a corrected methemoglobin absorption spectrum obtained from a steady-state spectrophotometer measurement of the optical density of a minimally scattering medium. The determination of the corrected methemoglobin absorption spectrum takes into account the scattering from impurities in the methemoglobin solution containing no lipid colloid. Frequency-domain techniques allow for the separation of the absorbing from the scattering properties of multiple-scattering media, and these techniques thus provide an absolute

Imaging-based molecular barcoding with pixelated dielectric metasurfaces.

PubMed

Tittl, Andreas; Leitis, Aleksandrs; Liu, Mingkai; Yesilkoy, Filiz; Choi, Duk-Yong; Neshev, Dragomir N; Kivshar, Yuri S; Altug, Hatice

2018-06-08

Metasurfaces provide opportunities for wavefront control, flat optics, and subwavelength light focusing. We developed an imaging-based nanophotonic method for detecting mid-infrared molecular fingerprints and implemented it for the chemical identification and compositional analysis of surface-bound analytes. Our technique features a two-dimensional pixelated dielectric metasurface with a range of ultrasharp resonances, each tuned to a discrete frequency; this enables molecular absorption signatures to be read out at multiple spectral points, and the resulting information is then translated into a barcode-like spatial absorption map for imaging. The signatures of biological, polymer, and pesticide molecules can be detected with high sensitivity, covering applications such as biosensing and environmental monitoring. Our chemically specific technique can resolve absorption fingerprints without the need for spectrometry, frequency scanning, or moving mechanical parts, thereby paving the way toward sensitive and versatile miniaturized mid-infrared spectroscopy devices. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

Constraints on the Compositions of Phobos and Deimos from Mineral Absorptions

NASA Technical Reports Server (NTRS)

Fraeman, A. A.; Murchie, S. L.; Arvidson, R. E.; Rivkin, A. S.; Morris, R. V.

2013-01-01

The compositions of Phobos and Deimos have remained controversial despite multiple Earth- and space-based observations acquired during the last 40 years. Phobos is composed of at least two spectral units that are both dark yet distinct at visible to near infrared wavelenghts; a spectrally red-sloped "red" unit covers most of the moon and a less red-sloped "blue" unit is present in the ejecta of the approximately 9-km diameter impact crater Stickney [1,2]. Deimos is similar spectrally to Phobos' "red" unit [2]. Here we report results from mapping mineral absorptions on Phobos and Deimos using visible/near infrared observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). We find evidence for an absorption feature at 0.65 m in the Phobos red unit and Deimos that is reproducible in observations from other instruments. The phase responsible is uncertain but may be a Fe-bearing phyllosilicate and/or graphite, consistent with the notion that Phobos and Deimos have compositions similar to CM carbonaceous chondrites [3].

HST/STIS Observations of the Local Interstellar Medium toward Very Nearby Stars: A Detailed Analysis of the a Centuari Sight Line

NASA Astrophysics Data System (ADS)

Dann, Julian; Redfield, Seth; Ayres, Thomas R.

2017-01-01

The Local Interstellar Medium (LISM), a region extending about 100 parsecs and in which the Sun is currently immersed, can only be studied using UV/optical absorption features against bright background stars. Perhaps in the future in-situ measurements will be possible (e.g., the Voyager spacecraft or Breakthrough Starshot-style missions). Using high-resolution observations with the Space Telescope Imaging Spectrograph (STIS) on-board the Hubble Space Telescope (HST), we have analyzed several very nearby sight lines to measure physical properties of the LISM. The data used in this study is a part of the Advanced Spectral Library (ASTRAL) Project, an HST Large Treasury Project, in which we have analyzed the spectra of fourteen nearby stars. LISM absorption features in these stellar spectra reveal key information about the abundances, temperature, and turbulence in the intervening gas. We have fit ion transitions in the near-UV for MgII, FeII, CII, DI, SiII, and OII. These absorption features provide direct measurements of the radial velocity, Doppler broadening parameter, and the column density along the line of sight. The presence of multiple local minima in the deep and narrow ISM profile is evidence of multiple clouds moving at different radial velocities.Included in our data set is the a Centauri sight line. We provide a detailed analysis of these new observations and a comparison with previous HST observations that were observed more than 20 years ago. A discussion of the physical properties along this line of sight is provided within the context of a Breakthrough Starshot mission. These high resolution and high signal-to-noise spectra will be important for making accurate estimations of the interstellar environment to help inform such an interstellar mission.We would like to acknowledge NASA HST Grant GO-12278 and GO-13346 awarded by the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., for NASA, under contract NAS 5-26555, and a student fellowship from the Connecticut Space Grant Consortium for their support of this research.

Phyllosilicate absorption features in main-belt and outer-belt asteroid reflectance spectra.

PubMed

Vilas, F; Gaffey, M J

1989-11-10

Absorption features having depths up to 5% are identified in high-quality, high-resolution reflectance spectra of 16 dark asteroids in the main belt and in the Cybele and Hilda groups. Analogs among the CM2 carbonaceous chondrite meteorites exist for some of these asteroids, suggesting that these absorptions are due to iron oxides in phyllosilicates formed on the asteroidal surfaces by aqueous alteration processes. Spectra of ten additional asteroids, located beyond the outer edge of the main belt, show no discernible absorption features, suggesting that aqueous alteration did not always operate at these heliocentric distances.

Phyllosilicate absorption features in main-belt and outer-belt asteroid reflectance spectra

NASA Technical Reports Server (NTRS)

Vilas, Faith; Gaffey, Michael J.

1989-01-01

Absorption features having depths up to 5 percent are identified in high-quality, high-resolution reflectance spectra of 16 dark asteroids in the main belt and in the Cybele and Hilda groups. Analogs among the CM2 carbonaceous chondrite meteorites exist for some of these asteroids, suggesting that these absorptions are due to iron oxides in phyllosilicates formed on the asteroidal surfaces by aqueous alteration processes. Spectra of ten additional asteroids, located beyond the outer edge of the main belt, show no discernible absorption features, suggesting that aqueous alteration did not always operate at these heliocentric distances.

Location of γ -ray emission and magnetic field strengths in OJ 287

DOE PAGES

Hodgson, J. A.; Krichbaum, T. P.; Marscher, A. P.; ...

2017-01-06

We report the γ-ray BL Lac object OJ 287 is known to exhibit inner-parsec “jet-wobbling”, high degrees of variability at all wavelengths and quasi-stationary features, including an apparent (≈100°) position-angle change in projection on the sky plane. Sub-50 micro-arcsecond resolution 86 GHz observations with the global mm-VLBI array (GMVA) supplement ongoing multi-frequency VLBI blazar monitoring at lower frequencies. Using these maps, together with cm/mm total intensity and γ-ray observations from Fermi-LAT from 2008-2014, we aim to Observations with the GMVA offer approximately double the angular resolution compared with 43 GHz VLBA observations and enable us to observe above the synchrotronmore » self-absorption peak frequency. Fermi-LAT γ-ray data were reduced and analysed. The jet was spectrally decomposed at multiple locations along the jet. From this, we could derive estimates of the magnetic field using equipartition and synchrotron self-absorption arguments. How the field decreases down the jet provided an estimate of the distance to the jet apex and an estimate of the magnetic field strength at the jet apex and in the broad line region. Combined with accurate kinematics, we attempt to locate the site of γ-ray activity, radio flares, and spectral changes. Strong γ-ray flares appeared to originate from either the so-called core region, a downstream stationary feature, or both, with γ-ray activity significantly correlated with radio flaring in the downstream quasi-stationary feature. Magnetic field estimates were determined at multiple locations along the jet, with the magnetic field found to be ≥1.6 G in the core and ≤0.4 G in the downstream quasi-stationary feature. Finally, we therefore found upper limits on the location of the VLBI core as ≲6.0 pc from the jet apex and determined an upper limit on the magnetic field near the jet base of the order of thousands of Gauss.« less

Location of γ -ray emission and magnetic field strengths in OJ 287

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hodgson, J. A.; Krichbaum, T. P.; Marscher, A. P.

We report the γ-ray BL Lac object OJ 287 is known to exhibit inner-parsec “jet-wobbling”, high degrees of variability at all wavelengths and quasi-stationary features, including an apparent (≈100°) position-angle change in projection on the sky plane. Sub-50 micro-arcsecond resolution 86 GHz observations with the global mm-VLBI array (GMVA) supplement ongoing multi-frequency VLBI blazar monitoring at lower frequencies. Using these maps, together with cm/mm total intensity and γ-ray observations from Fermi-LAT from 2008-2014, we aim to Observations with the GMVA offer approximately double the angular resolution compared with 43 GHz VLBA observations and enable us to observe above the synchrotronmore » self-absorption peak frequency. Fermi-LAT γ-ray data were reduced and analysed. The jet was spectrally decomposed at multiple locations along the jet. From this, we could derive estimates of the magnetic field using equipartition and synchrotron self-absorption arguments. How the field decreases down the jet provided an estimate of the distance to the jet apex and an estimate of the magnetic field strength at the jet apex and in the broad line region. Combined with accurate kinematics, we attempt to locate the site of γ-ray activity, radio flares, and spectral changes. Strong γ-ray flares appeared to originate from either the so-called core region, a downstream stationary feature, or both, with γ-ray activity significantly correlated with radio flaring in the downstream quasi-stationary feature. Magnetic field estimates were determined at multiple locations along the jet, with the magnetic field found to be ≥1.6 G in the core and ≤0.4 G in the downstream quasi-stationary feature. Finally, we therefore found upper limits on the location of the VLBI core as ≲6.0 pc from the jet apex and determined an upper limit on the magnetic field near the jet base of the order of thousands of Gauss.« less

Super-resolution atomic force photoactivated microscopy of biological samples (Conference Presentation)

NASA Astrophysics Data System (ADS)

Lee, Seunghyun; Kim, Hyemin; Shin, Seungjun; Doh, Junsang; Kim, Chulhong

2017-03-01

Optical microscopy (OM) and photoacoustic microscopy (PAM) have previously been used to image the optical absorption of intercellular features of biological cells. However, the optical diffraction limit ( 200 nm) makes it difficult for these modalities to image nanoscale inner cell structures and the distribution of internal cell components. Although super-resolution fluorescence microscopy, such as stimulated emission depletion microscopy (STED) and stochastic optical reconstruction microscopy (STORM), has successfully performed nanoscale biological imaging, these modalities require the use of exogenous fluorescence agents, which are unfavorable for biological samples. Our newly developed atomic force photoactivated microscopy (AFPM) can provide optical absorption images with nanoscale lateral resolution without any exogenous contrast agents. AFPM combines conventional atomic force microscopy (AFM) and an optical excitation system, and simultaneously provides multiple contrasts, such as the topography and magnitude of optical absorption. AFPM can detect the intrinsic optical absorption of samples with 8 nm lateral resolution, easily overcoming the diffraction limit. Using the label-free AFPM system, we have successfully imaged the optical absorption properties of a single melanoma cell (B16F10) and a rosette leaf epidermal cell of Arabidopsis (ecotype Columbia (Col-0)) with nanoscale lateral resolution. The remarkable images show the melanosome distribution of a melanoma cell and the biological structures of a plant cell. AFPM provides superior imaging of optical absorption with a nanoscale lateral resolution, and it promises to become widely used in biological and chemical research.

Spectroscopic determination of leaf biochemistry using band-depth analysis of absorption features and stepwise multiple linear regression

USGS Publications Warehouse

Kokaly, R.F.; Clark, R.N.

1999-01-01

We develop a new method for estimating the biochemistry of plant material using spectroscopy. Normalized band depths calculated from the continuum-removed reflectance spectra of dried and ground leaves were used to estimate their concentrations of nitrogen, lignin, and cellulose. Stepwise multiple linear regression was used to select wavelengths in the broad absorption features centered at 1.73 ??m, 2.10 ??m, and 2.30 ??m that were highly correlated with the chemistry of samples from eastern U.S. forests. Band depths of absorption features at these wavelengths were found to also be highly correlated with the chemistry of four other sites. A subset of data from the eastern U.S. forest sites was used to derive linear equations that were applied to the remaining data to successfully estimate their nitrogen, lignin, and cellulose concentrations. Correlations were highest for nitrogen (R2 from 0.75 to 0.94). The consistent results indicate the possibility of establishing a single equation capable of estimating the chemical concentrations in a wide variety of species from the reflectance spectra of dried leaves. The extension of this method to remote sensing was investigated. The effects of leaf water content, sensor signal-to-noise and bandpass, atmospheric effects, and background soil exposure were examined. Leaf water was found to be the greatest challenge to extending this empirical method to the analysis of fresh whole leaves and complete vegetation canopies. The influence of leaf water on reflectance spectra must be removed to within 10%. Other effects were reduced by continuum removal and normalization of band depths. If the effects of leaf water can be compensated for, it might be possible to extend this method to remote sensing data acquired by imaging spectrometers to give estimates of nitrogen, lignin, and cellulose concentrations over large areas for use in ecosystem studies.We develop a new method for estimating the biochemistry of plant material using spectroscopy. Normalized band depths calculated from the continuum-removed reflectance spectra of dried and ground leaves were used to estimate their concentrations of nitrogen, lignin, and cellulose. Stepwise multiple linear regression was used to select wavelengths in the broad absorption features centered at 1.73 ??m, 2.10 ??m, and 2.301 ??m that were highly correlated with the chemistry of samples from eastern U.S. forests. Band depths of absorption features at these wavelengths were found to also be highly correlated with the chemistry of four other sites. A subset of data from the eastern U.S. forest sites was used to derive linear equations that were applied to the remaining data to successfully estimate their nitrogen, lignin, and cellulose concentrations. Correlations were highest for nitrogen (R2 from 0.75 to 0.94). The consistent results indicate the possibility of establishing a single equation capable of estimating the chemical concentrations in a wide variety of species from the reflectance spectra of dried leaves. The extension of this method to remote sensing was investigated. The effects of leaf water content, sensor signal-to-noise and bandpass, atmospheric effects, and background soil exposure were examined. Leaf water was found to be the greatest challenge to extending this empirical method to the analysis of fresh whole leaves and complete vegetation canopies. The influence of leaf water on reflectance spectra must be removed to within 10%. Other effects were reduced by continuum removal and normalization of band depths. If the effects of leaf water can be compensated for, it might be possible to extend this method to remote sensing data acquired by imaging spectrometers to give estimates of nitrogen, lignin, and cellulose concentrations over large areas for use in ecosystem studies.

Grouping normal type Ia supernovae by UV to optical color differences

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milne, Peter A.; Brown, Peter J.; Roming, Peter W. A.

2013-12-10

Observations of many Type Ia supernovae (SNe Ia) for multiple epochs per object with the Swift Ultraviolet Optical Telescope instrument have revealed that there exists order to the differences in the UV-optical colors of optically normal supernovae (SNe). We examine UV-optical color curves for 23 SNe Ia, dividing the SNe into four groups, and find that roughly one-third of 'NUV-blue' SNe Ia have bluer UV-optical colors than the larger 'NUV-red' group. Two minor groups are recognized, 'MUV-blue' and 'irregular' SNe Ia. While we conclude that the latter group is a subset of the NUV-red group, containing the SNe with themore » broadest optical peaks, we conclude that the 'MUV-blue' group is a distinct group. Separating into the groups and accounting for the time evolution of the UV-optical colors lowers the scatter in two NUV-optical colors (e.g., u – v and uvw1 – v) to the level of the scatter in b – v. This finding is promising for extending the cosmological utilization of SNe Ia into the NUV. We generate spectrophotometry of 33 SNe Ia and determine the correct grouping for each. We argue that there is a fundamental spectral difference in the 2900-3500 Å wavelength range, a region suggested to be dominated by absorption from iron-peak elements. The NUV-blue SNe Ia feature less absorption than the NUV-red SNe Ia. We show that all NUV-blue SNe Ia in this sample also show evidence of unburned carbon in optical spectra, whereas only one NUV-red SN Ia features that absorption line. Every NUV-blue event also exhibits a low gradient of the Si II λ6355 absorption feature. Many NUV-red events also exhibit a low gradient, perhaps suggestive that NUV-blue events are a subset of the larger low-velocity gradient group.« less

Interstellar silicate dust in the z = 0.685 absorber toward TXS 0218+357

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aller, Monique C.; Kulkarni, Varsha P.; Liger, Nicholas

2014-04-10

We report the detection of interstellar silicate dust in the z {sub abs} = 0.685 absorber along the sightline toward the gravitationally lensed blazar TXS 0218+357. Using Spitzer Space Telescope Infrared Spectrograph data, we detect the 10 μm silicate absorption feature with a detection significance of 10.7σ. We fit laboratory-derived silicate dust profile templates obtained from the literature to the observed 10 μm absorption feature and find that the best single-mineral fit is obtained using an amorphous olivine template with a measured peak optical depth of τ{sub 10} = 0.49 ± 0.02, which rises to τ{sub 10} ∼ 0.67 ±more » 0.04 if the covering factor is taken into account. We also detected the 18 μm silicate absorption feature in our data with a >3σ significance. Due to the proximity of the 18 μm absorption feature to the edge of our covered spectral range, and associated uncertainty about the shape of the quasar continuum normalization near 18 μm, we do not independently fit this feature. We find, however, that the shape and depth of the 18 μm silicate absorption are well matched to the amorphous olivine template prediction, given the optical depth inferred for the 10 μm feature. The measured 10 μm peak optical depth in this absorber is significantly higher than those found in previously studied quasar absorption systems. However, the reddening, 21 cm absorption, and velocity spread of Mg II are not outliers relative to other studied absorption systems. This high optical depth may be evidence for variations in dust grain properties in the interstellar medium between this and the previously studied high redshift galaxies.« less

THE 3–4  μ m SPECTRA OF JUPITER TROJAN ASTEROIDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, M. E., E-mail: mbrown@caltech.edu

To date, reflectance spectra of Jupiter Trojan asteroids have revealed no distinctive absorption features. For this reason, the surface composition of these objects remains a subject of speculation. Spectra have revealed, however, that the Jupiter Trojan asteroids consist of two distinct sub-populations that differ in the optical to near-infrared colors. The origins and compositional differences between the two sub-populations remain unclear. Here, we report the results from a 2.2–3.8 μ m spectral survey of a collection of 16 Jupiter Trojan asteroids, divided equally between the two sub-populations. We find clear spectral absorption features centered around 3.1 μ m in themore » less-red population. Additional absorption consistent with that expected from organic materials might also be present. No such features are see in the red population. A strong correlation exists between the strength of the 3.1 μ m absorption feature and the optical to near-infrared color of the objects. While, traditionally, absorptions such as these in dark asteroids are modeled as being due to fine-grain water frost, we find it physically implausible that the special circumstances required to create such fine-grained frost would exist on a substantial fraction of the Jupiter Trojan asteroids. We suggest, instead, that the 3.1 μ m absorption on Trojans and other dark asteroids could be due to N–H stretch features. Additionally, we point out that reflectivities derived from WISE observations show a strong absorption beyond 4 μ m for both populations. The continuum of 3.1 μ m features and the common absorption beyond 4 μ m might suggest that both sub-populations of Jupiter Trojan asteroids formed in the same general region of the early solar system.« less

Contrastive Study on the Structure and the Ultraviolet Absorption Property of Multiple-Doped and Element-Doped ZnO Thin Films

NASA Astrophysics Data System (ADS)

Xu, Yunyun; Zhang, Tao; Lin, Zhenrong; Tian, Yanfeng; Zhou, Shandan

Sb2O3- and CeO2-doped ZnO thin films were prepared by RF magnetron sputtering technique. The influence of Sb2O3 and CeO2 on the structure and ultraviolet (UV) absorption properties was studied by X-ray diffraction and UV-Vis spectrophotometry. Results show that multiple doping of films had a prominent effect on the development of crystal grains and the UV absorption property. Ce and Sb exist in many forms in the ZnO film. The multiple-doped films also show enhanced UVA absorption, and the UV absorption peak widens and the absorption intensity increases. Sb plays a dominant role on the structure and UV absorption of ZnO thin films, which are enhanced by Ce.

Hexaphyrin as a Potential Theranostic Dye for Photothermal Therapy and 19 F Magnetic Resonance Imaging.

PubMed

Higashino, Tomohiro; Nakatsuji, Hirotaka; Fukuda, Ryosuke; Okamoto, Haruki; Imai, Hirohiko; Matsuda, Tetsuya; Tochio, Hidehito; Shirakawa, Masahiro; Tkachenko, Nikolai V; Hashida, Mitsuru; Murakami, Tatsuya; Imahori, Hiroshi

2017-05-18

Two features of meso-Aryl-substituted expanded porphyrins suggest suitability as theranostic agents. They have excellent absorption in near infrared (NIR) region, and they offer the possibility of introduction of multiple fluorine atoms at structurally equivalent positions. Here, hexaphyrin (hexa) was synthesized from 2,6-bis(trifluoromethyl)-4-formyl benzoate and pyrrole and evaluated as a novel expanded porphyrin with the above features. Under NIR illumination hexa showed intense photothermal and weak photodynamic effects, which were most likely due to its low excited states, close to singlet oxygen. The sustained photothermal effect caused ablation of cancer cells more effectively than the photodynamic effect of indocyanine green (a clinical dye). In addition, hexa showed potential for use in the visualization of tumors by 19 F magnetic resonance imaging (MRI), because of the multiple fluorine atoms. Our results strongly support the utility of expanded porphyrins as theranostic agents in both photothermal therapy and 19 F MRI. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

LARGE SOIL ABSORPTION SYSTEMS FOR WASTEWATERS FROM MULTIPLE-HOME DEVELOPMENTS

EPA Science Inventory

An investigation was conducted to provide insight into the design and performance of large soil absorption systems for treatment and disposal of wastewaters from multiple-home developments. The objectives were to investigate absorption system performance and identify potential de...

Spatially Resolved HCN Absorption Features in the Circumnuclear Region of NGC 1052

NASA Astrophysics Data System (ADS)

Sawada-Satoh, Satoko; Roh, Duk-Gyoo; Oh, Se-Jin; Lee, Sang-Sung; Byun, Do-Young; Kameno, Seiji; Yeom, Jae-Hwan; Jung, Dong-Kyu; Kim, Hyo-Ryoung; Hwang, Ju-Yeon

2016-10-01

We present the first VLBI detection of HCN molecular absorption in the nearby active galactic nucleus NGC 1052. Utilizing the 1 mas resolution achieved by the Korean VLBI Network, we have spatially resolved the HCN absorption against a double-sided nuclear jet structure. Two velocity features of HCN absorption are detected significantly at the radial velocity of 1656 and 1719 km s-1, redshifted by 149 and 212 km s-1 with respect to the systemic velocity of the galaxy. The column density of the HCN molecule is estimated to be 1015-1016 cm-2, assuming an excitation temperature of 100-230 K. The absorption features show high optical depth localized on the receding jet side, where the free-free absorption occurred due to the circumnuclear torus. The size of the foreground absorbing molecular gas is estimated to be on approximately one-parsec scales, which agrees well with the approximate size of the circumnuclear torus. HCN absorbing gas is likely to be several clumps smaller than 0.1 pc inside the circumnuclear torus. The redshifted velocities of the HCN absorption features imply that HCN absorbing gas traces ongoing infall motion inside the circumnuclear torus onto the central engine.

The origin of blueshifted absorption features in the X-ray spectrum of PG 1211+143: outflow or disc

NASA Astrophysics Data System (ADS)

Gallo, L. C.; Fabian, A. C.

2013-07-01

In some radio-quiet active galactic nuclei (AGN), high-energy absorption features in the X-ray spectra have been interpreted as ultrafast outflows (UFOs) - highly ionized material (e.g. Fe XXV and Fe XXVI) ejected at mildly relativistic velocities. In some cases, these outflows can carry energy in excess of the binding energy of the host galaxy. Needless to say, these features demand our attention as they are strong signatures of AGN feedback and will influence galaxy evolution. For the same reason, alternative models need to be discussed and refuted or confirmed. Gallo and Fabian proposed that some of these features could arise from resonance absorption of the reflected spectrum in a layer of ionized material located above and corotating with the accretion disc. Therefore, the absorbing medium would be subjected to similar blurring effects as seen in the disc. A priori, the existence of such plasma above the disc is as plausible as a fast wind. In this work, we highlight the ambiguity by demonstrating that the absorption model can describe the ˜7.6 keV absorption feature (and possibly other features) in the quasar PG 1211+143, an AGN that is often described as a classic example of a UFO. In this model, the 2-10 keV spectrum would be largely reflection dominated (as opposed to power law dominated in the wind models) and the resonance absorption would be originating in a layer between about 6 and 60 gravitational radii. The studies of such features constitute a cornerstone for future X-ray observatories like Astro-H and Athena+. Should our model prove correct, or at least important in some cases, then absorption will provide another diagnostic tool with which to probe the inner accretion flow with future missions.

A Statistical Study of the Southern Fermi Bubble in UV Absorption Spectra

NASA Astrophysics Data System (ADS)

Karim, Md. Tanveer; Fox, Andrew; Jenkins, Edward; Bordoloi, Rongmon; Wakker, Bart; Savage, Blair D.; Lockman, Felix; Crawford, Steve; Bland-Hawthorn, Joss; Jorgenson, Regina A.

2018-01-01

The Fermi Bubbles are two giant lobes of plasma situated at the center of the Milky Way, extending 55° above and below the Galactic Midplane. Although the Bubbles have been widely studied in multiple wavelengths, few studies have been done in UV absorption. Here we present a statistical study of the Southern Fermi Bubble using 17 QSO sightlines — 6 inside the Bubble, 11 outside — using UV absorption spectra from the Hubble Space Telescope Cosmic Origins Spectrograph (HST/COS). We searched for high-velocity clouds (HVCs) in 11 metal lines from ions of Aluminium, Carbon and Silicon. We detected HVCs in 83% of the sightlines inside the Bubble and 64% outside the Bubble, showing an enhancement in the covering fraction of HVCs in the Southern Bubble region. We also observed a decrease in vLSR of the HVCs as a function of the galactic latitude, consistent with a scenario where the identified HVCs trace the Galactic nuclear outflow, as sightlines closer to the central engine are expected to show a higher velocity. Combined with previous studies, our analysis indicates that the Southern Fermi Bubble is a dynamic environment giving rise to complex absorption features.

Findings on rings and inner satellites of Saturn of Pioneer 11

NASA Astrophysics Data System (ADS)

van Allen, J. A.

1982-09-01

The introductory part of this paper gives a short account of the theory of absorption by planetary rings and satellites of energetic charged particles that are trapped in a planet's magnetic field and describes the observable consequences of such absorption processes. The previously published University of Iowa observations of absorption features during Pioneer 11's passage through Saturn's inner radiation belt on 1 September 1979 are critically reanalyzed and related to other evidence on rings and satellites inside 2.9 Saturn radii, especially that from the imaging system on Voyagers 1 and 2. It is found (a) that satellites 1979 S1, 1979 S2, and 1980 S3 are almost certainly identical; (b) that the evidence for 1979 S4 is weak to nonexistent; (c) that 1979 S5 and two other nearby absorption features and 1979 S6 and one other nearby absorption feature are probably caused by longitudinal and radial structure of Ring F and not by satellites; and (d) that absorption feature 1979 S3 at 169,200 + or - 600 km is identified with the optically observed Ring G.

Near-infrared tunable multiple broadband perfect absorber base on VO2 semi-shell arrays photonic microstructure and gold reflector

NASA Astrophysics Data System (ADS)

Liang, Jiran; Li, Peng; Zhou, Liwei; Guo, Jinbang; Zhao, Yirui

2018-01-01

We proposed a metamaterial absorber which is aimed to achieve a multiple broadband absorption and tunable absorption peak in the near-infrared region. The absorber is based on VO2 semi-shell coated on the top of silica nano-particle array supported on the gold-reflective layer. Measured results show that the absorber has the multiple broadband with the absorption magnitudes more than 95% in the near infrared region. The absorption peaks can be tuned through the VO2 phase transition from metallic phase to insulator phase in the short wavelength (before λ = 1500 nm), when VO2 is at the metallic state, an absorption band appears in the long wavelength (after λ = 1500 nm). The simulation results closely match those of measured. The absorption intensity becomes stronger and absorption peaks have red shift with the increase of thickness of VO2 semi-shell. Thus, this designed tunable absorption intensity and position absorber based on VO2 can be a good choice for enhancing the performance of multiple band, this would be beneficial to the field of photo detectors, sensor and solar cell.

Differential Radiometers Using Fabry-Perot Interferometric Technique for Remote Sensing Determination of Various Atmospheric Trace Gases

NASA Technical Reports Server (NTRS)

Georgieva, E. M.; Heaps, W. S.; Wilson, E. L.

2007-01-01

New type of remote sensing instrument based upon the Fabry-Perot inte rferometric technique has been developed at NASA's Goddard Space Flight Center. Fabry-Perot interferometry (FPI) is a well known, powerful spectroscopic technique and one of its many applications is to be use d to measure greenhouse gases and also some harmful species in the at mosphere. With this technique, absorption of particular species is me asured and related to its concentration. A solid Fabry-Perot etalon is used as a frequency filter to restrict the measurement to particular absorption bands of the gas of interest. With adjusting the thicknes s of the etalon that separation (in frequency) of the transmitted fri nges can be made equal to the almost constant separation of the gas a bsorption lines. By adjusting the temperature of the etalon, which changes the index of refi-action of its material, the transmission fring es can be brought into nearly exact correspondence with absorption li nes of the particular species. With this alignment between absorption lines and fringes, changes in the amount of a species in the atmosph ere strongly affect the amount of light transmitted by the etalon and can be related to gas concentration. The instrument that we have dev eloped detects the absorption of various atmospheric trace gases in d irect or reflected sunlight. Our instrument employing Fabry-Perot interferometer makes use of two features to achieve high sensitivity. The first is high spectral resolution enabling one to match the width of an atmospheric absorption feature by the instrumental band pass. The second is high optical throughput enabled by using multiple spectral lines simultaneously. For any species that one wishes to measure, thi s first feature is available while the use of multiple spectral features can be employed only for species with suitable spectra and freedom from interfering species in the same wavelength region. We have deve loped an instrument for use as ground based, airborne and satellite s ensor for gases such as carbon dioxide (1570 nm), oxygen (762 nm and 768 nm lines sensitive to changes in oxygen pressure and oxygen temper ature) and water vapor (940 nm). Our current goal is to develop an ul tra precise, inexpensive, ground based device suitable for wide deplo yment as a validation instrument for the Orbiting Carbon Observatory (OCO) satellite. We show sensitivity measurements for CO2, 02, and H2 O, compare our measurements to those obtained using other types of sensors and discuss some of the peculiarities that must be addressed in order to provide the very high quality column detection required for solving problems about global distribution of greenhouse gases and cl imatological models. In another area of research we are interested in developing a small-size channel for CO2 capable of doing simultaneous measurements with the AERONET (Aerosol Robotic Network) at NASA, God dard to study the hypothesis that atmospheric aerosols affect the reg ional terrestrial carbon cycle. We present recent data from our groun d based measurements of O2, CO2, H2O and (13)CO2 and discuss extensio n of the technique to new species and applications.

Resonantly enhanced multiple exciton generation through below-band-gap multi-photon absorption in perovskite nanocrystals.

PubMed

Manzi, Aurora; Tong, Yu; Feucht, Julius; Yao, En-Ping; Polavarapu, Lakshminarayana; Urban, Alexander S; Feldmann, Jochen

2018-04-17

Multi-photon absorption and multiple exciton generation represent two separate strategies for enhancing the conversion efficiency of light into usable electric power. Targeting below-band-gap and above-band-gap energies, respectively, to date these processes have only been demonstrated independently. Here we report the combined interaction of both nonlinear processes in CsPbBr 3 perovskite nanocrystals. We demonstrate nonlinear absorption over a wide range of below-band-gap excitation energies (0.5-0.8 E g ). Interestingly, we discover high-order absorption processes, deviating from the typical two-photon absorption, at specific energetic positions. These energies are associated with a strong enhancement of the photoluminescence intensity by up to 10 5 . The analysis of the corresponding energy levels reveals that the observed phenomena can be ascribed to the resonant creation of multiple excitons via the absorption of multiple below-band-gap photons. This effect may open new pathways for the efficient conversion of optical energy, potentially also in other semiconducting materials.

Method of analyzing multiple sample simultaneously by detecting absorption and systems for use in such a method

DOEpatents

Yeung, Edward S.; Gong, Xiaoyi

2004-09-07

The present invention provides a method of analyzing multiple samples simultaneously by absorption detection. The method comprises: (i) providing a planar array of multiple containers, each of which contains a sample comprising at least one absorbing species, (ii) irradiating the planar array of multiple containers with a light source and (iii) detecting absorption of light with a detetion means that is in line with the light source at a distance of at leaat about 10 times a cross-sectional distance of a container in the planar array of multiple containers. The absorption of light by a sample indicates the presence of an absorbing species in it. The method can further comprise: (iv) measuring the amount of absorption of light detected in (iii) indicating the amount of the absorbing species in the sample. Also provided by the present invention is a system for use in the abov metho.The system comprises; (i) a light source comrnpising or consisting essentially of at leaat one wavelength of light, the absorption of which is to be detected, (ii) a planar array of multiple containers, and (iii) a detection means that is in line with the light source and is positioned in line with and parallel to the planar array of multiple contiainers at a distance of at least about 10 times a cross-sectional distance of a container.

Photophysical studies of chromium sensitizers designed for excited state hole transfer to semiconductors and sequential hole/electron transfers from photoexcited cadmium sulfide nanorods to mononuclear ruthenium water-oxidation catalysts

NASA Astrophysics Data System (ADS)

Tseng, Huan-Wei

This dissertation describes three research projects related to solar cells and solar water splitting with a goal of utilizing solar energy, a renewable energy source. The first project is focused on photophysical studies of four newly-synthesized Cr(III) tris-bipyridyl complexes featuring the 4-dmcbpy (dimethyl 2,2'-bipyridine-4,4'-dicarboxylate) ligand. Static and time-resolved emission results suggest that the complexes store ˜1.7 eV of energy for multiple microseconds. Using cyclic voltammetry, it is found that the inclusion of 4-dmcbpy shifts the E1/2 of CrIII/II by +0.2 V from the homoleptic parent complexes without 4-dmcbpy. All four complexes have excited state potentials of CrIII*/II between +1.8 and +2.0 V vs. NHE, placing them among the most powerful photooxidants reported and making them candidates for hole-injection sensitizers. The second project continues with Cr(III) complexes, but using iminopyridine Schiff base ligands. Two complexes feature hexadentate ligands and the other two are their tris-bidentate analogues. One of each pair contains methyl ester groups for attachment to semiconductors. Cyclic voltammograms show that the hexadentate and tris-bidentate analogues have almost identical reduction potentials, but the addition of ester substituents shifts the reduction potentials by +0.2 V. The absorption spectra of the hexadentate complexes show improved absorption of visible light compared to the tris-bidentate analogues. For freshly prepared sample solutions in CH3CN, time-resolved emission and transient absorption measurements for the Cr(III) tris-bidentate ester complex show a doublet excited state with a 17-19 microsecond lifetime at room temperature, while no emission or transient absorption signals from the doublet states are observed for the hexadentate analogue under the same conditions. The dramatic difference is due to the presence of a nonligated bridgehead nitrogen atom. The third project features charge transfer interactions between a photoexcited cadmium sulfide nanorod and [Ru(diethyl 2,2'-bipyridine-4,4'-dicarboxylate)(2,2':6',2"-terpyridine)Cl] +, a mononuclear water-oxidation catalyst. Upon photoexcitation, hole transfer from the cadmium sulfide nanorod oxidizes the catalyst (Ru 2+ → Ru3+) on a 100 ps to 1 ns timescale. This is followed by electron transfer (10-100 ns) from the nanorod to reduce the Ru3+ center. The relatively slow electron transfer dynamics may provide opportunities for the accumulation of multiple holes at the catalyst, which is required for water oxidation.

Low-Latitude Ethane Rain on Titan

NASA Technical Reports Server (NTRS)

Dalba, Paul A.; Buratti, Bonnie J.; Brown, R. H.; Barnes, J. W.; Baines, K. H.; Sotin, C.; Clark, R. N.; Lawrence, K. J.; Nicholson, P. D.

2012-01-01

Cassini ISS observed multiple widespread changes in surface brightness in Titan's equatorial regions over the past three years. These brightness variations are attributed to rainfall from cloud systems that appear to form seasonally. Determining the composition of this rainfall is an important step in understanding the "methanological" cycle on Titan. I use data from Cassini VIMS to complete a spectroscopic investigation of multiple rain-wetted areas. I compute "before-and-after" spectral ratios of any areas that show either deposition or evaporation of rain. By comparing these spectral ratios to a model of liquid ethane, I find that the rain is most likely composed of liquid ethane. The spectrum of liquid ethane contains multiple absorption features that fall within the 2-micron and 5-micron spectral windows in Titan's atmosphere. I show that these features are visible in the spectra taken of Titan's surface and that they are characteristically different than those in the spectrum of liquid methane. Furthermore, just as ISS saw the surface brightness reverting to its original state after a period of time, I show that VIMS observations of later flybys show the surface composition in different stages of returning to its initial form.

EXTINCTION AND POLYCYCLIC AROMATIC HYDROCARBON INTENSITY VARIATIONS ACROSS THE H II REGION IRAS 12063-6259

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stock, D. J.; Peeters, E.; Otaguro, J. N.

The spatial variations in polycyclic aromatic hydrocarbon (PAH) band intensities are normally attributed to the physical conditions of the emitting PAHs, however in recent years it has been suggested that such variations are caused mainly by extinction. To resolve this question, we have obtained near-infrared (NIR), mid-infrared (MIR), and radio observations of the compact H II region IRAS 12063-6259. We use these data to construct multiple independent extinction maps and also to measure the main PAH features (6.2, 7.7, 8.6, and 11.2 {mu}m) in the MIR. Three extinction maps are derived: the first using the NIR hydrogen lines and casemore » B recombination theory; the second combining the NIR data with radio data; and the third making use of the Spitzer/IRS MIR observations to measure the 9.8 {mu}m silicate absorption feature using the Spoon method and PAHFIT (as the depth of this feature can be related to overall extinction). The silicate absorption over the bright, southern component of IRAS 12063-6259 is almost absent while the other methods find significant extinction. While such breakdowns of the relationship between the NIR extinction and the 9.8 {mu}m absorption have been observed in molecular clouds, they have never been observed for H II regions. We then compare the PAH intensity variations in the Spitzer/IRS data after dereddening to those found in the original data. It was found that in most cases, the PAH band intensity variations persist even after dereddening, implying that extinction is not the main cause of the PAH band intensity variations.« less

Harnessing Multiple Internal Reflections to Design Highly Absorptive Acoustic Metasurfaces

NASA Astrophysics Data System (ADS)

Shen, Chen; Cummer, Steven A.

2018-05-01

The rapid development of metasurfaces has enabled numerous intriguing applications with acoustically thin sheets. Here we report the theory and experimental realization of a nonresonant sound-absorbing strategy using metasurfaces by harnessing multiple internal reflections. We theoretically and numerically show that the higher-order diffraction of thin gradient-index metasurfaces is tied to multiple internal reflections inside the unit cells. Highly absorbing acoustic metasurfaces can be realized by enforcing multiple internal reflections together with a small amount of loss. A reflective gradient-index acoustic metasurface is designed based on the theory, and we further experimentally verify the performance using a three-dimensional printed prototype. Measurements show over 99% energy absorption at the peak frequency and a 95% energy absorption bandwidth of around 600 Hz. The proposed mechanism provides an alternative route for sound absorption without the necessity of high absorption of the individual unit cells.

SPATIALLY RESOLVED HCN ABSORPTION FEATURES IN THE CIRCUMNUCLEAR REGION OF NGC 1052

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sawada-Satoh, Satoko; Roh, Duk-Gyoo; Oh, Se-Jin

We present the first VLBI detection of HCN molecular absorption in the nearby active galactic nucleus NGC 1052. Utilizing the 1 mas resolution achieved by the Korean VLBI Network, we have spatially resolved the HCN absorption against a double-sided nuclear jet structure. Two velocity features of HCN absorption are detected significantly at the radial velocity of 1656 and 1719 km s{sup −1}, redshifted by 149 and 212 km s{sup −1} with respect to the systemic velocity of the galaxy. The column density of the HCN molecule is estimated to be 10{sup 15}–10{sup 16} cm{sup −2}, assuming an excitation temperature ofmore » 100–230 K. The absorption features show high optical depth localized on the receding jet side, where the free–free absorption occurred due to the circumnuclear torus. The size of the foreground absorbing molecular gas is estimated to be on approximately one-parsec scales, which agrees well with the approximate size of the circumnuclear torus. HCN absorbing gas is likely to be several clumps smaller than 0.1 pc inside the circumnuclear torus. The redshifted velocities of the HCN absorption features imply that HCN absorbing gas traces ongoing infall motion inside the circumnuclear torus onto the central engine.« less

Multielectron transitions in x-ray absorption of krypton

NASA Astrophysics Data System (ADS)

Ito, Yoshiaki; Nakamatsu, Hirohide; Mukoyama, Takeshi; Omote, Kazuhiko; Yoshikado, Shinzo; Takahashi, Masao; Emura, Shuichi

1992-11-01

The photoabsorption cross section near the K edge in krypton gas has been measured using synchro- tron radiation. Several features for simultaneous multielectron excitations were detected and analyzed by the use of the shakeup and shakeoff probabilities and their dependence on the photon energy. Previous observations of the [1s3p], [1s3d], and [1s4p] transitions have been confirmed. A transition is found between [1s3p] and [1s3d] multiple excitations and identified as a three-electron excitation [1s3d4p].

Dual-wavelength quantum cascade laser for trace gas spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jágerská, J.; Tuzson, B.; Mangold, M.

2014-10-20

We demonstrate a sequentially operating dual-wavelength quantum cascade laser with electrically separated laser sections, emitting single-mode at 5.25 and 6.25 μm. Based on a single waveguide ridge, this laser represents a considerable asset to optical sensing and trace gas spectroscopy, as it allows probing multiple gas species with spectrally distant absorption features using conventional optical setups without any beam combining optics. The laser capability was demonstrated in simultaneous NO and NO{sub 2} detection, reaching sub-ppb detection limits and selectivity comparable to conventional high-end spectroscopic systems.

Water and solute absorption from carbohydrate-electrolyte solutions in the human proximal small intestine: a review and statistical analysis.

PubMed

Shi, Xiaocai; Passe, Dennis H

2010-10-01

The purpose of this study is to summarize water, carbohydrate (CHO), and electrolyte absorption from carbohydrate-electrolyte (CHO-E) solutions based on all of the triple-lumen-perfusion studies in humans since the early 1960s. The current statistical analysis included 30 reports from which were obtained information on water absorption, CHO absorption, total solute absorption, CHO concentration, CHO type, osmolality, sodium concentration, and sodium absorption in the different gut segments during exercise and at rest. Mean differences were assessed using independent-samples t tests. Exploratory multiple-regression analyses were conducted to create prediction models for intestinal water absorption. The factors influencing water and solute absorption are carefully evaluated and extensively discussed. The authors suggest that in the human proximal small intestine, water absorption is related to both total solute and CHO absorption; osmolality exerts various impacts on water absorption in the different segments; the multiple types of CHO in the ingested CHO-E solutions play a critical role in stimulating CHO, sodium, total solute, and water absorption; CHO concentration is negatively related to water absorption; and exercise may result in greater water absorption than rest. A potential regression model for predicting water absorption is also proposed for future research and practical application. In conclusion, water absorption in the human small intestine is influenced by osmolality, solute absorption, and the anatomical structures of gut segments. Multiple types of CHO in a CHO-E solution facilitate water absorption by stimulating CHO and solute absorption and lowering osmolality in the intestinal lumen.

Iron oxide bands in the visible and near-infrared reflectance spectra of primitive asteroids

NASA Technical Reports Server (NTRS)

Jarvis, Kandy S.; Vilas, Faith; Gaffey, Michael J.

1993-01-01

High resolution reflectance spectra of primitive asteroids (C, P, and D class and associated subclasses) have commonly revealed an absorption feature centered at 0.7 microns attributed to an Fe(2+)-Fe(3+) charge transfer transition in iron oxides and/or oxidized iron in phyllosilicates. A smaller feature identified at 0.43 microns has been attributed to an Fe(3+) spin-forbidden transition in iron oxides. In the spectra of the two main-belt primitive asteroids 368 Haidea (D) and 877 Walkure (F), weak absorption features which were centered near the location of 0.60-0.65 microns and 0.80-0.90 microns prompted a search for features at these wavelengths and an attempt to identify their origin(s). The CCD reflectance spectra obtained between 1982-1992 were reviewed for similar absorption features located near these wavelengths. The spectra of asteroids in which these absorption features have been identified are shown. These spectra are plotted in order of increasing heliocentric distance. No division of the asteroids by class has been attempted here (although the absence of these features in the anhydrous S-class asteroids, many of which have presumably undergone full heating and differentiation should be noted). For this study, each spectrum was treated as a continuum with discrete absorption features superimposed on it. For each object, a linear least squares fit to the data points defined a simple linear continuum. The linear continuum was then divided into each spectrum, thus removing the sloped continuum and permitting the intercomparison of residual spectral features.

Spectral features of biogenic calcium carbonates and implications for astrobiology

NASA Astrophysics Data System (ADS)

Berg, B. L.; Ronholm, J.; Applin, D. M.; Mann, P.; Izawa, M.; Cloutis, E. A.; Whyte, L. G.

2014-09-01

The ability to discriminate biogenic from abiogenic calcium carbonate (CaCO3) would be useful in the search for extant or extinct life, since CaCO3 can be produced by both biotic and abiotic processes on Earth. Bioprecipitated CaCO3 material was produced during the growth of heterotrophic microbial isolates on medium enriched with calcium acetate or calcium citrate. These biologically produced CaCO3, along with natural and synthetic non-biologically produced CaCO3 samples, were analysed by reflectance spectroscopy (0.35-2.5 μm), Raman spectroscopy (532 and 785 nm), and laser-induced fluorescence spectroscopy (365 and 405 nm excitation). Optimal instruments for the discrimination of biogenic from abiogenic CaCO3 were determined to be reflectance spectroscopy, and laser-induced fluorescence spectroscopy. Multiple absorption features in the visible light region occurred in reflectance spectra for most biogenic CaCO3 samples, which are likely due to organic pigments. Multiple fluorescence peaks occurred in emission spectra (405 nm excitation) of biogenic CaCO3 samples, which also are best attributed to the presence of organic compounds; however, further analyses must be performed in order to better determine the cause of these features to establish criteria for confirming the origin of a given CaCO3 sample. Raman spectroscopy was not useful for discrimination since any potential Raman peaks in spectra of biogenic carbonates collected by both the 532 and 785 nm lasers were overwhelmed by fluorescence. However, this also suggests that biogenic carbonates may be identified by the presence of this organic-associated fluorescence. No reliable spectroscopic differences in terms of parameters such as positions or widths of carbonate-associated absorption bands were found between the biogenic and abiogenic carbonate samples. These results indicate that the presence or absence of organic matter intimately associated with carbonate minerals is the only potentially useful spectral discriminator for the techniques that were examined, and that multiple spectroscopic techniques are capable of detecting the presence of associated organic materials. However, the presence or absence of intimately associated organic matter is not, in itself, an indicator of biogenicity.

The origin of absorptive features in the two-dimensional electronic spectra of rhodopsin.

PubMed

Farag, Marwa H; Jansen, Thomas L C; Knoester, Jasper

2018-05-09

In rhodopsin, the absorption of a photon causes the isomerization of the 11-cis isomer of the retinal chromophore to its all-trans isomer. This isomerization is known to occur through a conical intersection (CI) and the internal conversion through the CI is known to be vibrationally coherent. Recently measured two-dimensional electronic spectra (2DES) showed dramatic absorptive spectral features at early waiting times associated with the transition through the CI. The common two-state two-mode model Hamiltonian was unable to elucidate the origin of these features. To rationalize the source of these features, we employ a three-state three-mode model Hamiltonian where the hydrogen out-of plane (HOOP) mode and a higher-lying electronic state are included. The 2DES of the retinal chromophore in rhodopsin are calculated and compared with the experiment. Our analysis shows that the source of the observed features in the measured 2DES is the excited state absorption to a higher-lying electronic state and not the HOOP mode.

UV absorption investigation of ferromagnetically filled ultra-thick carbon onions, carriers of the 217.5 nm Interstellar Absorption Feature

NASA Astrophysics Data System (ADS)

Boi, Filippo S.; Zhang, Xiaotian; Ivaturi, Sameera; Liu, Qianyang; Wen, Jiqiu; Wang, Shanling

2017-12-01

Carbon nano-onions (CNOs) are fullerene-like structures which consist of quasi-spherical closed carbon shells. These structures have become a subject of great interest thanks to their characteristic absorption feature of interstellar origin (at 217.5 nm, 4.6 μm-1). An additional extinction peak at 3.8 μm-1 has also been reported and attributed to absorption by graphitic residues between the as-grown CNOs. Here, we report the ultraviolet absorption properties of ultra-thick CNOs filled with FePt3 crystals, which also exhibit two main absorption peaks—features located at 4.58 μm-1 and 3.44 μm-1. The presence of this additional feature is surprising and is attributed to nonmagnetic graphite flakes produced as a by-product in the pyrolysis experiment (as confirmed by magnetic separation methods). Instead, the feature at 4.58 μm-1 is associated with the π-plasmonic resonance of the CNOs structures. The FePt3 filled CNOs were fabricated in situ by an advanced one-step fast process consisting in the direct sublimation and pyrolysis of two molecular precursors, namely, ferrocene and dichloro-cyclooctadiene-platinum in a chemical vapour deposition system. The morphological, structural, and magnetic properties of the as-grown filled CNOs were characterized by a means of scanning and transmission electron microscopy, X-ray diffraction, and magnetometry.

Measurements of multiple gas parameters in a pulsed-detonation combustor using time-division-multiplexed Fourier-domain mode-locked lasers.

PubMed

Caswell, Andrew W; Roy, Sukesh; An, Xinliang; Sanders, Scott T; Schauer, Frederick R; Gord, James R

2013-04-20

Hyperspectral absorption spectroscopy is being used to monitor gas temperature, velocity, pressure, and H(2)O mole fraction in a research-grade pulsed-detonation combustor (PDC) at the Air Force Research Laboratory. The hyperspectral source employed is termed the TDM 3-FDML because it consists of three time-division-multiplexed (TDM) Fourier-domain mode-locked (FDML) lasers. This optical-fiber-based source monitors sufficient spectral information in the H(2)O absorption spectrum near 1350 nm to permit measurements over the wide range of conditions encountered throughout the PDC cycle. Doppler velocimetry based on absorption features is accomplished using a counterpropagating beam approach that is designed to minimize common-mode flow noise. The PDC in this study is operated in two configurations: one in which the combustion tube exhausts directly to the ambient environment and another in which it feeds an automotive-style turbocharger to assess the performance of a detonation-driven turbine. Because the enthalpy flow [kilojoule/second] is important in assessing the performance of the PDC in various configurations, it is calculated from the measured gas properties.

Absorption and scattering by fractal aggregates and by their equivalent coated spheres

NASA Astrophysics Data System (ADS)

Kandilian, Razmig; Heng, Ri-Liang; Pilon, Laurent

2015-01-01

This paper demonstrates that the absorption and scattering cross-sections and the asymmetry factor of randomly oriented fractal aggregates of spherical monomers can be rapidly estimated as those of coated spheres with equivalent volume and average projected area. This was established for fractal aggregates with fractal dimension ranging from 2.0 to 3.0 and composed of up to 1000 monodisperse or polydisperse monomers with a wide range of size parameter and relative complex index of refraction. This equivalent coated sphere approximation was able to capture the effects of both multiple scattering and shading among constituent monomers on the integral radiation characteristics of the aggregates. It was shown to be superior to the Rayleigh-Debye-Gans approximation and to the equivalent coated sphere approximation proposed by Latimer. However, the scattering matrix element ratios of equivalent coated spheres featured large angular oscillations caused by internal reflection in the coating which were not observed in those of the corresponding fractal aggregates. Finally, the scattering phase function and the scattering matrix elements of aggregates with large monomer size parameter were found to have unique features that could be used in remote sensing applications.

The hot DOA1 degenerate HZ 21 - A search for circumstellar/photospheric metals and peculiar absorption at He II

NASA Technical Reports Server (NTRS)

Fritz, M. L.; Leckenby, H.; Sion, E. M.; Vauclair, G.; Liebert, J.

1990-01-01

A high-resolution IUE spectrum of the hot DO1 degenerate HZ 21 was obtained by combining US1 + European 2 low-background observing shifts. The SWP image reveals a rich spectrum of interstellar absorption lines with an average velocity in the line of sight to HZ 21 of -30 km/s. However, there is no clear evidence of any highly or lowly ionized metal features which could be attributed to circumstellar, wind, or photospheric absorption. There is, however, a broad absorption trough at He II (1640) which was not unexpected, given the clear presence of He II (4686) absorption in this star's optical spectrum. The velocity width of He II (1640) appears consistent with photospheric absorption wings which appear to flank the geocoronal Ly-alpha emission feature. The He II (1640) feature reveals what appears to be a broad (310 km/s) emission reversal. Evidence is provided that the emission reversal is probably real.

Terahertz sensing of highly absorptive water-methanol mixtures with multiple resonances in metamaterials.

PubMed

Chen, Min; Singh, Leena; Xu, Ningning; Singh, Ranjan; Zhang, Weili; Xie, Lijuan

2017-06-26

Terahertz sensing of highly absorptive aqueous solutions remains challenging due to strong absorption of water in the terahertz regime. Here, we experimentally demonstrate a cost-effective metamaterial-based sensor integrated with terahertz time-domain spectroscopy for highly absorptive water-methanol mixture sensing. This metamaterial has simple asymmetric wire structures that support multiple resonances including a fundamental Fano resonance and higher order dipolar resonance in the terahertz regime. Both the resonance modes have strong intensity in the transmission spectra which we exploit for detection of the highly absorptive water-methanol mixtures. The experimentally characterized sensitivities of the Fano and dipole resonances for the water-methanol mixtures are found to be 160 and 305 GHz/RIU, respectively. This method provides a robust route for metamaterial-assisted terahertz sensing of highly absorptive chemical and biochemical materials with multiple resonances and high accuracy.

IUE's View of Callisto: Detection of an SO2 Absorption Correlated to Possible Torus Neutral Wind Alterations

NASA Technical Reports Server (NTRS)

Lane, Arthur L.; Domingue, Deborah L.

1997-01-01

Observations taken with the International Ultraviolet Explorer (IUE) detected a 0.28 micron absorption feature on Callisto's leading and Jupiter-facing hemispheres. This feature is similar to Europa's 0.28 micron feature, however it shows no correlation with magnetospheric ion bombardment. The strongest 0.28 micron signature is seen in the region containing the Valhalla impact. This absorption feature also shows some spatial correlation to possible neutral wind interactions, suggestive of S implantation (rather than S(sub x)) into Callisto's water ice surface, Indications of possible temporal variations (on the 10% level) are seen at other wavelengths between the 1984-1986 and the 1996 observations.

Evaluation of Fourier transform coefficients for the diagnosis of rheumatoid arthritis from diffuse optical tomography images

NASA Astrophysics Data System (ADS)

Montejo, Ludguier D.; Jia, Jingfei; Kim, Hyun K.; Hielscher, Andreas H.

2013-03-01

We apply the Fourier Transform to absorption and scattering coefficient images of proximal interphalangeal (PIP) joints and evaluate the performance of these coefficients as classifiers using receiver operator characteristic (ROC) curve analysis. We find 25 features that yield a Youden index over 0.7, 3 features that yield a Youden index over 0.8, and 1 feature that yields a Youden index over 0.9 (90.0% sensitivity and 100% specificity). In general, scattering coefficient images yield better one-dimensional classifiers compared to absorption coefficient images. Using features derived from scattering coefficient images we obtain an average Youden index of 0.58 +/- 0.16, and an average Youden index of 0.45 +/- 0.15 when using features from absorption coefficient images.

Evidence for mass loss at polar latitudes in the Be stars Omega Orionis and 66 Ophiuchi

NASA Technical Reports Server (NTRS)

Peters, G. J.

1982-01-01

IUE observations of the pole-on Be stars Omega Ori and 66 Oph have revealed the unexpected presence of high velocity (-250 to -850 km/sec), relatively narrow (about 1 A) absorption components to the resonance lines of C IV, Si IV, and Si III. The C IV features show structure indicative of multiple shells or clouds. If Omega Ori and 66 Oph are indeed viewed pole-on, then these observations suggest that substantial matter is being ejected from the polar regions of these stars. The nature of these unusual high velocity features, which were not observed in other pole-on Be stars considered in the program, and the column densities and mass loss rates implied by them are discussed in this Letter.

[Analysis of UV-visible absorption spectrum on the decolorization of industrial wastewater by disinfection].

PubMed

Huang, Xin; Wang, Long-Yong; Gao, Nai-Yun; Li, Wei-Guo

2012-10-01

The UV-Visible absorption spectrum of industrial wastewater was explored to introduce a substituting method determining the color of water, and to compare the decolorization efficacy of different disinfectants. The results show that the visible absorption spectrum(350-600 nm), instead of ultraviolet absorption spectrum, should be applied to characterize the color of wastewater. There is a good correlation between the features of visible absorption spectrum and the true color of wastewater. Both ozone and chlorine dioxide has a better decolorization performance than chlorine. However, the color of chlorine dioxide itself has a negative effect on decolorization. The changes in the features of visible absorption spectrum effectively reflect the variations in the color of wastewater after disinfection.

Detection of absorption lines in the spectra of X-ray bursts from X1608-52

NASA Astrophysics Data System (ADS)

Nakamura, Norio; Inoue, Hajime; Tanaka, Yasuo

X-ray bursts from X 1608-52 were observed with the gas scintillation proportional counters on the Tenma satellite. Absorption features were detected in the spectra of three bursts among 17 bursts observed. These absorption features are consistent with a common absorption line at 4.1 keV. The energy and the properties of the absorption lines of the X 1608-52 bursts are very similar to those observed from the X 1636-53 bursts by Waki et al. (1984). Near equality of the absorption-line energies for X 1636-53 and X 1608-52 would imply that mass and radius of the neutron stars in these two systems are very similar to each other.

A honeycomb-like three-dimensional metamaterial absorber via super-wideband and wide-angle performances at millimeter wave and low THz frequencies

NASA Astrophysics Data System (ADS)

Vahidi, Alireza; Rajabalipanah, Hamid; Abdolali, Ali; Cheldavi, Ahmad

2018-04-01

Achieving wideband absorption via three-dimensional (3D) metamaterials has revealed as a new emerging innovative field of research, especially in recent years. Here, a novel 3D metamaterial absorber (MA) having a sixfold symmetry is designed which consists of periodic resistive honeycomb-like units. The proposed 3D MA exhibits a strong absorptivity above 90% in the widest bandwidth ever reported to the authors' knowledge from 50 to 460 GHz (the bandwidth ratio larger than 1:9), covering both millimeter wave and low -terahertz spectra. To understand the physical mechanism of absorption, the electric field and surface current distributions, the power loss density as well as the deteriorating effects of the high-order Floquet modes are monitored and discussed. As a distinctive feature in comparison to the similar 3D MAs, our engineered absorber provides multiple resonances, contributing to further broadening of the operating bandwidth. In addition, it is shown that the honeycomb-like MA retains its polarization-insensitive absorption in a wide range of incident wave angles and polarization angles. Due to flexibility of the design, these superior performances can be simply extended to terahertz, infrared and visible frequencies, potentially leading to many promising applications in imaging, sensing, and camouflage technology.

Combined infrared and ultraviolet-visible spectroscopy matrix-isolated carbon vapor

NASA Technical Reports Server (NTRS)

Kurtz, Joe; Huffman, Donald R.

1990-01-01

Infrared and UV-visible absorption spectra have been measured on the same sample of matrix-isolated carbon vapor in order to establish correlations between absorption intensities of vibrational and electronic transitions as a function of sample annealing. A high degree of correlation has been found between the IR feature at 1998/cm recently assigned to C8 and a UV absorption feature at about 3100 A. Thus, for the first time, direct evidence is given for the assignment of one of the unknown UV-visible features of the long-studied matrix-isolated carbon vapor spectrum.

Near-infrared spectra of the Martian surface: Reading between the lines

NASA Technical Reports Server (NTRS)

Crisp, D.; Bell, J. F., III

1993-01-01

Moderate-resolution near-infrared (NIR) spectra of Mars have been widely used in studies of the Martian surface because many candidate surface materials have distinctive absorption features at these wavelengths. Recent advances in NIR detector technology and instrumentation have also encouraged studies in this spectral region. The use of moderate spectral resolution has often been justified for NIR surface observations because the spectral features produced by most surface materials are relatively broad, and easily discriminated at this resolution. In spite of this, NIR spectra of Mars are usually very difficult to interpret quantitatively. One problem is that NIR surface absorption features are often only a few percent deep, requiring observations with great signal-to-noise ratios. A more significant problem is that gases in the Martian atmosphere contribute numerous absorption features at these wavelengths. Ground-based observers must also contend with variable absorption by several gases in the Earth's atmosphere (H2O, CO2, O3, N2O, CH4, O2). The strong CO2 bands near 1.4, 1.6, 2.0, 2.7, 4.3, and 4.8 micrometers largely preclude the analysis of surface spectral features at these wavelengths. Martian atmospheric water vapor also contributes significant absorption near 1.33, 1.88, and 2.7 micrometers, but water vapor in the Earth's atmosphere poses a much larger problem to ground-based studies of these spectral regions. The third most important NIR absorber in the Martian atmosphere is CO. This gas absorbs most strongly in the relatively-transparent spectral windows near 4.6 and 2.3 micrometers. It also produces 1-10 percent absorption in the solar spectrum at these NIR wavelengths. This solar CO absorption cannot be adequately removed by dividing the Martian spectrum by that of a star, as is commonly done to calibrate ground-based spectroscopic observations, because most stars do not have identical amounts of CO absorption in their spectra. Here, we describe tow effective methods for eliminating contamination of Martian surface spectra by absorption in the solar, terrestrial, and Martian atmospheres. Both methods involve the use of very-high-resolution spectra that completely resolve the narrow atmospheric absorption lines.

Simultaneous infrared and UV-visible absorption spectra of matrix-isolated carbon vapor

NASA Technical Reports Server (NTRS)

Kurtz, Joe; Huffman, Donald R.

1989-01-01

Carbon molecules were suggested as possible carriers of the diffuse interstellar bands. In particular, it was proposed that the 443 nm diffuse interstellar band is due to the same molecule which gives rise to the 447 nm absorption feature in argon matrix-isolated carbon vapor. If so, then an associated C-C stretching mode should be seen in the IR. By doing spectroscopy in both the IR and UV-visible regions on the same sample, the present work provides evidence for correlating UV-visible absorption features with those found in the IR. Early data indicates no correlation between the strongest IR feature (1997/cm) and the 447 nm band. Correlation with weaker IR features is being investigated.

Investigation of black and brown carbon multiple-wavelength-dependent light absorption from biomass and fossil fuel combustion source emissions

Treesearch

Michael R. Olson; Mercedes Victoria Garcia; Michael A. Robinson; Paul Van Rooy; Mark A. Dietenberger; Michael Bergin; James Jay Schauer

2015-01-01

Quantification of the black carbon (BC) and brown carbon (BrC) components of source emissions is critical to understanding the impact combustion aerosols have on atmospheric light absorption. Multiple-wavelength absorption was measured from fuels including wood, agricultural biomass, coals, plant matter, and petroleum distillates in controlled combustion settings....

Thermophysics Characterization of Multiply Ionized Air Plasma Absorption of Laser Radiation

NASA Technical Reports Server (NTRS)

Wang, Ten-See; Rhodes, Robert; Turner, Jim (Technical Monitor)

2002-01-01

The impact of multiple ionization of air plasma on the inverse Bremsstrahlung absorption of laser radiation is investigated for air breathing laser propulsion. Thermochemical properties of multiply ionized air plasma species are computed for temperatures up to 200,000 deg K, using hydrogenic approximation of the electronic partition function; And those for neutral air molecules are also updated for temperatures up to 50,000 deg K, using available literature data. Three formulas for absorption are calculated and a general formula is recommended for multiple ionization absorption calculation. The plasma composition required for absorption calculation is obtained by increasing the degree of ionization sequentially, up to quadruple ionization, with a series of thermal equilibrium computations. The calculated second ionization absorption coefficient agrees reasonably well with that of available data. The importance of multiple ionization modeling is demonstrated with the finding that area under the quadruple ionization curve of absorption is found to be twice that of single ionization. The effort of this work is beneficial to the computational plasma aerodynamics modeling of laser lightcraft performance.

Exploring the Time Evolution of Cool Metallic Absorption Features in UV Burst Spectra

NASA Astrophysics Data System (ADS)

Belmes, K.; Madsen, C. A.; DeLuca, E.

2017-12-01

UV bursts are compact brightenings in active regions that appear in UV images. They are identified through three spectroscopic features: (1) broadening and intensification of NUV/FUV emission lines, (2) the presence of optically thin Si IV emission, and (3) the presence of absorption features from cool metallic ions. Properties (2) and (3) imply that bursts exist at transition region temperatures (≥ 80,000 K) but are located in the cooler lower chromosphere ( 5,000 K). Their energetic and dynamical properties remain poorly constrained. Improving our understanding of this phenomena could help us further constrain the energetic and dynamical properties of the chromosphere, as well as give us insight into whether or not UV bursts contribute to chromospheric and/or coronal heating. We analyzed the time evolution of UV bursts using spectral data from the Interface Region Imaging Spectrograph (IRIS). We inspected Si IV 1393.8 Å line profiles for Ni II 1393.3 Å absorption features to look for signs of heating. Weakening of absorption features over time could indicate heating of the cool ions above the burst, implying that thermal energy from the burst could rapidly conduct upward through the chromosphere. To detect the spectral profiles corresponding to bursts, we applied a four-parameter Gaussian fit to every profile in each observation and took cuts in parameter space to isolate the bursts. We then manually reviewed the remaining profiles by looking for a statistically significant appearance of Ni II 1393.3 Å absorption. We quantified these absorption features by normalizing the Si IV 1393.8 Å emission profiles and measuring the maximum fractional extinction in each. Our preliminary results indicate that Ni II 1393.3 Å absorption may undergo a cycle of strengthening and weakening throughout a burst's lifetime. However, further investigation is needed for confirmation. This work is supported by the NSF-REU solar physics program at SAO, grant number AGS-1560313.

Crystalline sulfur dioxide: Crystal field splittings, absolute band intensities and complex refractive indices derived from infrared spectra

NASA Technical Reports Server (NTRS)

Khanna, R. K.; Zhao, Guizhi

1986-01-01

The infrared absorption spectra of thin crystalline films of sulfur dioxide at 90 K are reported in the 2700 to 450/cm region. The observed multiplicity of the spectral features in the regions of fundamentals is attributed to factor group splittings of the modes in a biaxial crystal lattice and the naturally present minor S-34, S-36, and O-18 isotopic species. Complex refractive indices determined by an iterative Kramers-Kronig analysis of the extinction data, and absolute band strengths derived from them, are also reported in this region.

Syndrome of normal pressure hydrocephalus: possible relation to hypertensive and arteriosclerotic vasculopathy.

PubMed Central

Koto, A; Rosenberg, G; Zingesser, L H; Horoupian, D; Katzman, R

1977-01-01

A patient with clinical features of idiopathic normal pressure hydrocephalus, who responded dramatically to shunting, was found a necropsy to have a severe hypertensive and arteriosclerotic vasculopathy with multiple lacunar infarcts. There was no pathological evidence of thickened leptomeninges, fibrosis of the arachnoid villi, or Alzheimer's disease. An abnormal absorption mechanism was demonstrated with cisternography and by an increase in the concentration of homovanillic acid in the cerebrospinal fluid. It is suggested that vascular changes may play an important role in the pathophysiology in some cases of normal pressure hydrocephalus. Images PMID:845610

Multiple-Nozzle Spray Head Applies Foam Insulation

NASA Technical Reports Server (NTRS)

Walls, Joe T.

1993-01-01

Spray head equipped with four-nozzle turret mixes two reactive components of polyurethane and polyisocyanurate foam insulating material and sprays reacting mixture onto surface to be insulated. If nozzle in use becomes clogged, fresh one automatically rotated into position, with minimal interruption of spraying process. Incorporates features recirculating and controlling pressures of reactive components to maintain quality of foam by ensuring proper blend at outset. Also used to spray protective coats on or in ships, aircraft, and pipelines. Sprays such reactive adhesives as epoxy/polyurethane mixtures. Components of spray contain solid-particle fillers for strength, fire retardance, toughness, resistance to abrasion, or radar absorption.

Multi-wavelength differential absorption measurements of chemical species

NASA Astrophysics Data System (ADS)

Brown, David M.

The probability of accurate detection and quantification of airborne species is enhanced when several optical wavelengths are used to measure the differential absorption of molecular spectral features. Characterization of minor atmospheric constituents, biological hazards, and chemical plumes containing multiple species is difficult when using current approaches because of weak signatures and the use of a limited number of wavelengths used for identification. Current broadband systems such as Differential Optical Absorption Spectroscopy (DOAS) have either limitations for long-range propagation, or require transmitter power levels that are unsafe for operation in urban environments. Passive hyperspectral imaging systems that utilize absorption of solar scatter at visible and infrared wavelengths, or use absorption of background thermal emission, have been employed routinely for detection of airborne chemical species. Passive approaches have operational limitations at various ranges, or under adverse atmospheric conditions because the source intensity and spectrum is often an unknown variable. The work presented here describes a measurement approach that uses a known source of a low transmitted power level for an active system, while retaining the benefits of broadband and extremely long-path absorption operations. An optimized passive imaging system also is described that operates in the 3 to 4 mum window of the mid-infrared. Such active and passive instruments can be configured to optimize the detection of several hydrocarbon gases, as well as many other species of interest. Measurements have provided the incentive to develop algorithms for the calculations of atmospheric species concentrations using multiple wavelengths. These algorithms are used to prepare simulations and make comparisons with experimental results from absorption data of a supercontinuum laser source. The MODTRAN model is used in preparing the simulations, and also in developing additional algorithms to select filters for use with a MWIR (midwave infrared) imager for detection of plumes of methane, propane, gasoline vapor, and diesel vapor. These simulations were prepared for system designs operating on a down-looking airborne platform. A data analysis algorithm for use with a hydrocarbon imaging system extracts regions of interest from the field-of-view for further analysis. An error analysis is presented for a scanning DAS (Differential Absorption Spectroscopy) lidar system operating from an airborne platform that uses signals scattered from topographical targets. The analysis is built into a simulation program for testing real-time data processing approaches, and to gauge the effects on measurements of path column concentration due to ground reflectivity variations. An example simulation provides a description of the data expected for methane. Several accomplishments of this research include: (1) A new lidar technique for detection and measurement of concentrations of atmospheric species is demonstrated that uses a low-power supercontinuum source. (2) A new multi-wavelength algorithm, which demonstrates excellent performance, is applied to processing spectroscopic data collected by a longpath supercontinuum laser absorption instrument. (3) A simulation program for topographical scattering of a scanning DAS system is developed, and it is validated with aircraft data from the ITT Industries ANGEL (Airborne Natural Gas Emission Lidar) 3-lambda lidar system. (4) An error analysis procedure for DAS is developed, and is applied to measurements and simulations for an airborne platform. (5) A method for filter selection is developed and tested for use with an infrared imager that optimizes the detection for various hydrocarbons that absorb in the midwave infrared. (6) The development of a Fourier analysis algorithm is described that allows a user to rapidly separate hydrocarbon plumes from the background features in the field of view of an imaging system.

The 4.5 micron Sulfate Absorption Feature on Mars and Its Relationship to Formation Environment

NASA Technical Reports Server (NTRS)

Blaney, D. L.

2001-01-01

The 4.5 micron sulfate absorption feature on Mars is spatially variable. It is a sensitive composition and hydration state and can be used to identify different types of aqueous environments. Additional information is contained in the original extended abstract.

The UV to Near-IR Optical Properties of PAHs: A Semi-Empirical Model

NASA Technical Reports Server (NTRS)

Mattioda, A. L.; Allamandola, L. J.; Hudgins, D. M.

2005-01-01

Interstellar Polycyclic Aromatic Hydrocarbon (PAH) infrared emission features represent an important and unique diagnostic tool of the chemical and physical conditions throughout the universe. However, one challenge facing the widely accepted PAH emission model has been the detection of infrared features in regions of low UV flux. Utilizing recently published laboratory Near Infrared VIR) PAH ion absorption data measured in our laboratory, we build upon previous models for PAH ion absorption in the UV-Vis to extrapolate a new model which incorporates PAH ion absorption in the NIR. This model provides a basis for comparing the relative energy absorption of PAH ions in the UV-Vis and NIR regions for a wide variety of stellar types. This model demonstrates that the radiation from late-type stars can pump the mid-IR PAH features.

Metal-core/semiconductor-shell nanocones for broadband solar absorption enhancement.

PubMed

Zhou, Lin; Yu, Xiaoqiang; Zhu, Jia

2014-02-12

Nanostructure-based photovoltaic devices have exhibited several advantages, such as reduced reflection, extraordinary light trapping, and so forth. In particular, semiconductor nanostructures provide optical modes that have strong dependence on the size and geometry. Metallic nanostructures also attract a lot of attention because of the appealing plasmonic effect on the near-field enhancement. In this study, we propose a novel design, the metal-core/semiconductor-shell nanocones with the core radius varying in a linearly gradient style. With a thin layer of semiconductor absorber coated on a metallic cone, such a design can lead to significant and broadband absorption enhancement across the entire visible and near-infrared solar spectrum. As an example of demonstration, a layer of 16 nm thick crystalline silicon (c-Si) coated on a silver nanocone can absorb 27% of standard solar radiation across a broad spectral range of 300-1100 nm, which is equivalent to a 700 nm thick flat c-Si film. Therefore, the absorption enhancement factor approaching the Yablonovitch limit is achieved with this design. The significant absorption enhancement can be ascribed to three types of optical modes, that is, Fabry-Perot modes, plasmonic modes, and hybrid modes that combine the features of the previous two. In addition, the unique nanocone geometry enables the linearly gradient radius of the semiconductor shell, which can support multiple optical resonances, critical for the broadband absorption. Our design may find general usage as elements for the low cost, high efficiency solar conversion and water-splitting devices.

Fractal-Like Materials Design with Optimized Radiative Properties for High-Efficiency Solar Energy Conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ho, Clifford K.; Ortega, Jesus D.; Christian, Joshua Mark

Novel designs to increase light trapping and thermal efficiency of concentrating solar receivers at multiple length scales have been conceived, designed, and tested. The fractal-like geometries and features are introduced at both macro (meters) and meso (millimeters to centimeters) scales. Advantages include increased solar absorptance, reduced thermal emittance, and increased thermal efficiency. Radial and linear structures at the meso (tube shape and geometry) and macro (total receiver geometry and configuration) scales redirect reflected solar radiation toward the interior of the receiver for increased absorptance. Hotter regions within the interior of the receiver can reduce thermal emittance due to reduced localmore » view factors to the environment, and higher concentration ratios can be employed with similar surface irradiances to reduce the effective optical aperture, footprint, and thermal losses. Coupled optical/fluid/thermal models have been developed to evaluate the performance of these designs relative to conventional designs. Modeling results showed that fractal-like structures and geometries can increase the effective solar absorptance by 5 – 20% and the thermal efficiency by several percentage points at both the meso and macro scales, depending on factors such as intrinsic absorptance. Meso-scale prototypes were fabricated using additive manufacturing techniques, and a macro-scale bladed receiver design was fabricated using Inconel 625 tubes. On-sun tests were performed using the solar furnace and solar tower at the National Solar Thermal Test facility. The test results demonstrated enhanced solar absorptance and thermal efficiency of the fractal-like designs.« less

O2 on ganymede: Spectral characteristics and plasma formation mechanisms

USGS Publications Warehouse

Calvin, W.M.; Johnson, R.E.; Spencer, J.R.

1996-01-01

Weak absorption features in the visible reflectance spectrum of Jupiter's satellite Ganymede have been correlated to those observed in the spectrum of molecular oxygen. We examine the spectral characteristics of these absorption features in all phases of O2 and conclude that the molecular oxygen is most likely present at densities similar to the liquid or solid ??-phase. The contribution of O2 to spectral features observed on Ganymede in the near-infrared wavelength region affects the previous estimates of photon pathlength in ice. The concentration of the visible absorption features on the trailing hemisphere of Ganymede suggests an origin due to bombardment by magneto-spheric ions. We derive an approximate O2 formation rate from this mechanism and consider the state of O2 within the surface.

Copernicus observational searches for OH and H2O in diffuse clouds

NASA Technical Reports Server (NTRS)

Smith, W. H.; Snow, T. P., Jr.

1983-01-01

An intensive search for OH and H2O in the directions of sigma Sco, alpha Cam, and micron Per was undertaken with the Copernicus satellite. Multiple scans were carried out over the wavelength region for the expected absorption features due to the OH D-X and H2O C-X transitions. The feature due to OH was detected marginally towards sigma Sco, and only an upper limit can be given towards alpha Cam. H2O was not detected in any of the stars at the signal level accumulated. The OH abundance towards sigma Sco and the respective lower limits for the OH/H2O ratios are discussed with regard to the extant models for the steady state abundances of OH and H2O, and shown not to be inconsistent with ion-molecule schemes.

Copernicus observational searches for OH and H2O in diffuse clouds

NASA Technical Reports Server (NTRS)

Smith, W. H.; Snow, T. P., Jr.

1979-01-01

An intensive search for OH and H2O in the directions of Sigma Sco, Alpha Cam, and Omicron Per was undertaken with the Copernicus satellite. Multiple scans were carried out over the wavelength region for the expected absorption features due to the OH D-X and H2O C-X transitions. The feature due to OH was possibly detected toward Sigma Sco, and only an upper limit can be given toward Alpha Cam. H2O was not detected in any of the stars at the signal level accumulated. The OH abundance toward Sigma Sco and the respective lower limits for the OH/H2O ratios are discussed with regard to the extant models for the steady-state abundances of OH and H2O, and shown not to be inconsistent with ion-molecule schemes.

Use of airborne imaging spectrometer data to map minerals associated with hydrothermally altered rocks in the northern grapevine mountains, Nevada, and California

USGS Publications Warehouse

Kruse, F.A.

1988-01-01

Three flightlines of Airborne Imaging Spectrometer (AIS) data, acquired over the northern Grapevine Mountains, Nevada, and California, were used to map minerals associated with hydrothermally altered rocks. The data were processed to remove vertical striping, normalized using an equal area normalization, and reduced to reflectance relative to an average spectrum derived from the data. An algorithm was developed to automatically calculate the absorption band parameters band position, band depth, and band width for the strongest absorption feature in each pixel. These parameters were mapped into an intensity, hue, saturation (IHS) color system to produce a single color image that summarized the absorption band information, This image was used to map areas of potential alteration based upon the predicted relationships between the color image and mineral absorption band. Individual AIS spectra for these areas were then examined to identify specific minerals. Two types of alteration were mapped with the AIS data. Areas of quartz-sericite-pyrite alteration were identified based upon a strong absorption feature near 2.21 ??m, a weak shoulder near 2.25 ??m, and a weak absorption band near 2.35 ??m caused by sericite (fine-grained muscovite). Areas of argillic alteration were defined based on the presence of montmorillonite, identified by a weak to moderate absorption feature near 2.21 ??m and the absence of the 2.35 ??m band. Montmorillonite could not be identified in mineral mixtures. Calcite and dolomite were identified based on sharp absorption features near 2.34 and 2.32 ??m, respectively. Areas of alteration identified using the AIS data corresponded well with areas mapped using field mapping, field reflectance spectra, and laboratory spectral measurements. ?? 1988.

Derivative Analysis of Absorption Features in Hyperspectral Remote Sensing Data of Carbonate Sediments

DTIC Science & Technology

2002-12-30

reflectance of carbonate sediments and application to shallow water benthic habitat classification,” Doctoral Dissertation, University of Miami. Chap.3...resolve overlapping features. A primary application has been to analyze pigment and chemical composition of leaves in order to track physiological...final absorption feature was observed at 630 nm, in a region associated with the biliprotein, phycocyanin [16,17]. As biliproteins are water soluble

Characterizing the thermal distributions of warm molecular hydrogen in protoplanetary disks

NASA Astrophysics Data System (ADS)

Hoadley, Keri; France, Kevin

2016-01-01

Probing the surviving molecular gas within the inner regions of protoplanetary disks (PPDs) around T Tauri stars (1 - 10 Myr) provides insight into the conditions in which planet formation and migration occurs while the gas disk is still present. Recent studies done by Hoadley et al. 2015 and Banzatti & Pontipoddan 2015 suggest that gas in the inner disks of PPDs appear to "respond" to the loss of small dust grains with evolving PPD stage, and IR-CO emission may either be thermally or photo-excited by stellar UV radiation, depending on PPD evolutionary stage. Because far-UV H2 emission lines are dominantly photo-excited by stellar HI-Lyman alpha photons, we observe H2 absorption features against the stellar Lyman alpha wings in a large sample of PPDs at various evolutionary stages. We aim to characterize whether the inner disk H2 environment is in thermal equilibrium at various stages of PPD evolution. We use a sophisticated first-principles approach to fitting multiple absorption features along the red- and blue-wings of the observed stellar Lyman alpha profiles to extract column density estimates of H2 along the line of sight to the target. We find that the high kinetic energy H2 observed in absorption against the LyA wing may be described as a part of the thermal distribution with high kinetic temperature - a potential indication of an inner disk molecular hazy "envelope" around the cooler bulk disk. Ongoing research may help determine the state of the gas and whether it evolves with disk evolutionary stage.

Plant phenolics and absorption features in vegetation reflectance spectra near 1.66 μm

NASA Astrophysics Data System (ADS)

Kokaly, Raymond F.; Skidmore, Andrew K.

2015-12-01

Past laboratory and field studies have quantified phenolic substances in vegetative matter from reflectance measurements for understanding plant response to herbivores and insect predation. Past remote sensing studies on phenolics have evaluated crop quality and vegetation patterns caused by bedrock geology and associated variations in soil geochemistry. We examined spectra of pure phenolic compounds, common plant biochemical constituents, dry leaves, fresh leaves, and plant canopies for direct evidence of absorption features attributable to plant phenolics. Using spectral feature analysis with continuum removal, we observed that a narrow feature at 1.66 μm is persistent in spectra of manzanita, sumac, red maple, sugar maple, tea, and other species. This feature was consistent with absorption caused by aromatic Csbnd H bonds in the chemical structure of phenolic compounds and non-hydroxylated aromatics. Because of overlapping absorption by water, the feature was weaker in fresh leaf and canopy spectra compared to dry leaf measurements. Simple linear regressions of feature depth and feature area with polyphenol concentration in tea resulted in high correlations and low errors (% phenol by dry weight) at the dry leaf (r2 = 0.95, RMSE = 1.0%, n = 56), fresh leaf (r2 = 0.79, RMSE = 2.1%, n = 56), and canopy (r2 = 0.78, RMSE = 1.0%, n = 13) levels of measurement. Spectra of leaves, needles, and canopies of big sagebrush and evergreens exhibited a weak absorption feature centered near 1.63 μm, short ward of the phenolic compounds, possibly consistent with terpenes. This study demonstrates that subtle variation in vegetation spectra in the shortwave infrared can directly indicate biochemical constituents and be used to quantify them. Phenolics are of lesser abundance compared to the major plant constituents but, nonetheless, have important plant functions and ecological significance. Additional research is needed to advance our understanding of the spectral influences of plant phenolics and terpenes relative to dominant leaf biochemistry (water, chlorophyll, protein/nitrogen, cellulose, and lignin).

Laser isotope separation by multiple photon absorption

DOEpatents

Robinson, C. Paul; Rockwood, Stephen D.; Jensen, Reed J.; Lyman, John L.; Aldridge, III, Jack P.

1987-01-01

Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

Laser isotope separation by multiple photon absorption

DOEpatents

Robinson, C. Paul; Rockwood, Stephen D.; Jensen, Reed J.; Lyman, John L.; Aldridge, III, Jack P.

1977-01-01

Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, in the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

Soft X-ray absorption spectroscopy investigation of the surface chemistry and treatments of copper indium gallium diselenide (CIGS)

DOE PAGES

Schwartz, Craig; Nordlund, Dennis; Sokaras, Dimosthenis; ...

2017-02-01

The surface and near surface structure of copper-indium-gallium-selenide (CIGS) absorber layers is integral to the producing a high-quality photovoltaic junction. By using X-ray absorption spectroscopy (XAS) and monitoring multiple elemental absorption edges with both theory and experiment, we are able to identify several features of the surface of CIGS as a function of composition and surface treatments. The XAS data shows trends in the near surface region of oxygen, copper, indium and gallium species as the copper content is varied in the films. The oxygen surface species are also monitored through a series of experiments that systematically investigates the effectsmore » of water and various solutions of: ammonium hydroxide, cadmium sulfate, and thiourea. These being components of cadmium sulfide chemical bath deposition (CBD). Characteristics of the CBD are correlated with a restorative effect that produces as normalized, uniform surface chemistry as measured by XAS. This surface chemistry is found in CIGS solar cells with excellent power conversion efficiency (<19%). The results provide new insight for CIGS processing strategies that seek to replace CBD and/or cadmium sulfide.« less

Soft X-ray absorption spectroscopy investigation of the surface chemistry and treatments of copper indium gallium diselenide (CIGS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwartz, Craig; Nordlund, Dennis; Sokaras, Dimosthenis

The surface and near surface structure of copper-indium-gallium-selenide (CIGS) absorber layers is integral to the producing a high-quality photovoltaic junction. By using X-ray absorption spectroscopy (XAS) and monitoring multiple elemental absorption edges with both theory and experiment, we are able to identify several features of the surface of CIGS as a function of composition and surface treatments. The XAS data shows trends in the near surface region of oxygen, copper, indium and gallium species as the copper content is varied in the films. The oxygen surface species are also monitored through a series of experiments that systematically investigates the effectsmore » of water and various solutions of: ammonium hydroxide, cadmium sulfate, and thiourea. These being components of cadmium sulfide chemical bath deposition (CBD). Characteristics of the CBD are correlated with a restorative effect that produces as normalized, uniform surface chemistry as measured by XAS. This surface chemistry is found in CIGS solar cells with excellent power conversion efficiency (<19%). The results provide new insight for CIGS processing strategies that seek to replace CBD and/or cadmium sulfide.« less

Trapping proton transfer intermediates in the disordered hydrogen-bonded network of cryogenic hydrofluoric acid solutions.

PubMed

Ayotte, Patrick; Plessis, Sylvain; Marchand, Patrick

2008-08-28

A molecular-level description of the structural and dynamical aspects that are responsible for the weak acid behaviour of dilute hydrofluoric acid solutions and their unusual increased acidity at near equimolar concentrations continues to elude us. We address this problem by reporting reflection-absorption infrared spectra (RAIRS) of cryogenic HF-H(2)O binary mixtures at various compositions prepared as nanoscopic films using molecular beam techniques. Optical constants for these cryogenic solutions [n(omega) and k(omega)] are obtained by iteratively solving Fresnel equations for stratified media. Modeling of the experimental RAIRS spectra allow for a quantitative interpretation of the complex interplay between multiple reflections, optical interference and absorption effects. The evolution of the strong absorption features in the intermediate 1000-3000 cm(-1) range with increasing HF concentration reveals the presence of various ionic dissociation intermediates that are trapped in the disordered H-bonded network of cryogenic hydrofluoric acid solutions. Our findings are discussed in light of the conventional interpretation of why hydrofluoric acid is a weak acid revealing molecular-level details of the mechanism for HF ionization that may be relevant to analogous elementary processes involved in the ionization of weak acids in aqueous solutions.

Solid methane on Triton and Pluto - 3- to 4-micron spectrophotometry

NASA Technical Reports Server (NTRS)

Spencer, John R.; Buie, Marc W.; Bjoraker, Gordon L.

1990-01-01

Methane has been identified in the Pluto/Charon system on the basis of absorption features in the reflectance spectrum at 1.5 and 2.3 microns; attention is presently given to observations of a 3.25 micron-centered deep absorption feature in Triton and Pluto/Charon system reflectance spectra. This absorption may indicate the presence of solid methane, constituting either the dominant surface species or a mixture with a highly transparent substance, such as N2 frost.

Optical detection of tracer species in strongly scattering media.

PubMed

Brauser, Eric M; Rose, Peter E; McLennan, John D; Bartl, Michael H

2015-03-01

A combination of optical absorption and scattering is used to detect tracer species in a strongly scattering medium. An optical setup was developed, consisting of a dual-beam scattering detection scheme in which sample scattering beam overlaps with the characteristic absorption feature of quantum dot tracer species, while the reference scattering beam is outside any absorption features of the tracer. This scheme was successfully tested in engineered breakthrough tests typical of wastewater and subsurface fluid analysis, as well as in batch analysis of oil and gas reservoir fluids and biological samples. Tracers were detected even under highly scattering conditions, conditions in which conventional absorption or fluorescence methods failed.

Multiplexed absorption tomography with calibration-free wavelength modulation spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cai, Weiwei; Kaminski, Clemens F., E-mail: cfk23@cam.ac.uk

2014-04-14

We propose a multiplexed absorption tomography technique, which uses calibration-free wavelength modulation spectroscopy with tunable semiconductor lasers for the simultaneous imaging of temperature and species concentration in harsh combustion environments. Compared with the commonly used direct absorption spectroscopy (DAS) counterpart, the present variant enjoys better signal-to-noise ratios and requires no baseline fitting, a particularly desirable feature for high-pressure applications, where adjacent absorption features overlap and interfere severely. We present proof-of-concept numerical demonstrations of the technique using realistic phantom models of harsh combustion environments and prove that the proposed techniques outperform currently available tomography techniques based on DAS.

Fourier Transform Infrared Absorption Spectroscopy of Gas-Phase and Surface Reaction Products during Si Etching in Inductively Coupled Cl2 Plasmas

NASA Astrophysics Data System (ADS)

Miyata, Hiroki; Tsuda, Hirotaka; Fukushima, Daisuke; Takao, Yoshinori; Eriguchi, Koji; Ono, Kouichi

2011-10-01

A better understanding of plasma-surface interactions is indispensable during etching, including the behavior of reaction or etch products, because the products on surfaces and in the plasma are important in passivation layer formation through their redeposition on surfaces. In practice, the nanometer-scale control of plasma etching would still rely largely on such passivation layer formation as well as ion-enhanced etching on feature surfaces. This paper presents in situ Fourier transform infrared (FTIR) absorption spectroscopy of gas-phase and surface reaction products during inductively coupled plasma (ICP) etching of Si in Cl2. The observation was made in the gas phase by transmission absorption spectroscopy (TAS), and also on the substrate surface by reflection absorption spectroscopy (RAS). The quantum chemical calculation was also made of the vibrational frequency of silicon chloride molecules. The deconvolution of the TAS spectrum revealed absorption features of Si2Cl6 and SiClx (x = 1-3) as well as SiCl4, while that of the RAS spectrum revealed relatively increased absorption features of unsaturated silicon chlorides. A different behavior was also observed in bias power dependence between the TAS and RAS spectra.

Near-infrared diode laser absorption diagnostic for temperature and water vapor in a scramjet combustor

NASA Astrophysics Data System (ADS)

Liu, Jonathan T. C.; Rieker, Gregory B.; Jeffries, Jay B.; Gruber, Mark R.; Carter, Campbell D.; Mathur, Tarun; Hanson, Ronald K.

2005-11-01

Tunable diode laser absorption measurements of gas temperature and water concentration were made at the exit of a model scramjet combustor fueled on JP-7. Multiplexed, fiber-coupled, near-infrared distributed feedback lasers were used to probe three water vapor absorption features in the 1.34 1.47 μm spectral region (2v1 and v1+v3 overtone bands). Ratio thermometry was performed using direct-absorption wavelength scans of isolated features at a 4-kHz repetition rate, as well as 2f wavelength modulation scans at a 2-kHz scan rate. Large signal-to-noise ratios demonstrate the ability of the optimally engineered optical hardware to reject beam steering and vibration noise. Successful measurements were made at full combustion conditions for a variety of fuel/air equivalence ratios and at eight vertical positions in the duct to investigate spatial uniformity. The use of three water vapor absorption features allowed for preliminary estimates of temperature distributions along the line of sight. The improved signal quality afforded by 2f measurements, in the case of weak absorption, demonstrates the utility of a scanned wavelength modulation strategy in such situations.

A light-trapping strategy for nanocrystalline silicon thin-film solar cells using three-dimensionally assembled nanoparticle structures.

PubMed

Ha, Kyungyeon; Jang, Eunseok; Jang, Segeun; Lee, Jong-Kwon; Jang, Min Seok; Choi, Hoseop; Cho, Jun-Sik; Choi, Mansoo

2016-02-05

We report three-dimensionally assembled nanoparticle structures inducing multiple plasmon resonances for broadband light harvesting in nanocrystalline silicon (nc-Si:H) thin-film solar cells. A three-dimensional multiscale (3DM) assembly of nanoparticles generated using a multi-pin spark discharge method has been accomplished over a large area under atmospheric conditions via ion-assisted aerosol lithography. The multiscale features of the sophisticated 3DM structures exhibit surface plasmon resonances at multiple frequencies, which increase light scattering and absorption efficiency over a wide spectral range from 350-1100 nm. The multiple plasmon resonances, together with the antireflection functionality arising from the conformally deposited top surface of the 3D solar cell, lead to a 22% and an 11% improvement in power conversion efficiency of the nc-Si:H thin-film solar cells compared to flat cells and cells employing nanoparticle clusters, respectively. Finite-difference time-domain simulations were also carried out to confirm that the improved device performance mainly originates from the multiple plasmon resonances generated from three-dimensionally assembled nanoparticle structures.

Spectra of Particulate Backscattering in Natural Waters

NASA Technical Reports Server (NTRS)

Gordon, Howard, R.; Lewis, Marlon R.; McLean, Scott D.; Twardowski, Michael S.; Freeman, Scott A.; Voss, Kenneth J.; Boynton, Chris G.

2009-01-01

Hyperspectral profiles of downwelling irradiance and upwelling radiance in natural waters (oligotrophic and mesotrophic) are combined with inverse radiative transfer to obtain high resolution spectra of the absorption coefficient (a) and the backscattering coefficient (bb) of the water and its constituents. The absorption coefficient at the mesotrophic station clearly shows spectral absorption features attributable to several phytoplankton pigments (Chlorophyll a, b, c, and Carotenoids). The backscattering shows only weak spectral features and can be well represented by a power-law variation with wavelength (lambda): b(sub b) approx. Lambda(sup -n), where n is a constant between 0.4 and 1.0. However, the weak spectral features in b(sub b), suggest that it is depressed in spectral regions of strong particle absorption. The applicability of the present inverse radiative transfer algorithm, which omits the influence of Raman scattering, is limited to lambda < 490 nm in oligotrophic waters and lambda < 575 nm in mesotrophic waters.

The nature of pulsar radio emission

NASA Astrophysics Data System (ADS)

Dyks, J.; Rudak, B.; Demorest, P.

2010-01-01

High-quality averaged radio profiles of some pulsars exhibit double, highly symmetric features both in emission and in absorption. It is shown that both types of feature are produced by a split fan beam of extraordinary-mode curvature radiation that is emitted/absorbed by radially extended streams of magnetospheric plasma. With no emissivity in the plane of the stream, such a beam produces bifurcated emission components (BFCs) when our line of sight passes through the plane. An example of a double component created in this way is present in the averaged profile of the 5-ms pulsar J1012+5307. We show that the component can indeed be very well fitted by the textbook formula for the non-coherent beam of curvature radiation in the polarization state that is orthogonal to the plane of electron trajectory. The observed width of the BFC decreases with increasing frequency at a rate that confirms the curvature origin. Likewise, the double absorption features (double notches) are produced by the same beam of the extraordinary-mode curvature radiation, when it is eclipsed by thin plasma streams. The intrinsic property of curvature radiation to create bifurcated fan beams explains the double features in terms of a very natural geometry and implies the curvature origin of pulsar radio emission. Similarly, the `double conal' profiles of class D result from a cut through a wider stream with finite extent in magnetic azimuth. Therefore, their width reacts very slowly to changes of viewing geometry resulting from geodetic precession. The stream-cut interpretation implies a highly non-orthodox origin of both the famous S-swing of polarization angle and the low-frequency pulse broadening in D profiles. The azimuthal structure of polarization modes in the curvature radiation beam provides an explanation for the polarized `multiple imaging' and the edge depolarization of pulsar profiles.

A search for ultraviolet circumstellar gas absorption features in alpha Piscis Austrinus (Fomalhaut), a possible Beta Pictoris-like system

NASA Technical Reports Server (NTRS)

Cheng, K.-P.; Bruhweiler, Fred C.; Kondo, Yoji

1994-01-01

Archival high-dispersion International Ultraviolet Explorer (IUE) spectra have been used to search for circumstellar gas absorption features in alpha PsA (A3 V), a nearby (6.7 pc) proto-planetary system candidate. Recent sub-millimeter mapping observations around the region of alpha PsA indicate a spatially resolved dust disk like the one seen around Beta Pic. To determine how closely this putative disk resembles that of Beta Pic, we have searched for signatures of circumstellar gaseous absorption in all the available IUE high-dispersion data of alpha PsA. Examination of co-added IUE spectra shows weak circumstellar absorptions from excited levels in the resonance multiplet of Fe II near 2600 A. We also conclude that the sharp C I feature near 1657 A, previously identified as interstellar absorption toward alpha PsA, likely has a circumstellar origin. However, because the weakness of these absorption features, we will consider the presence of circumstellar gas as tentative and should be verified by using the Goddard High-Resolution Spectrograph aboard the Hubble Space Telescope. No corresponding circumstellar absorption is detected in higher ionization Fe III and Al III. Since the collisionally ionized nonphotospheric Al III resonance absorption seen in Beta Pic is likely formed close to the stellar surface, its absence in the UV spectra of alpha PsA could imply that, in contrast with Beta Pic, there is no active gaseous disk infall onto the central star. In the alpha PsA gaseous disk, if we assume a solar abundance for iron and all the iron is in the form of Fe II, plus a disk temperature of 5000 K, the Fe II UV1 absorption at 2611.8743 A infers a total hydrogen column density along the line of sight through the circumstellar disk of N(H) approximately equals 3.8 x 10(exp 17)/cm.

Magnetized Disk Winds in NGC 3783

NASA Technical Reports Server (NTRS)

Fukumura, Keigo; Kazanas, Demosthenes; Shrader, Chris; Behar, Ehud; Tombesi, Francesco; Contopoulos, Ioannis

2018-01-01

We analyze a 900 kilosecond stacked Chandra/HETG (High-Energy Transmission Grating) spectrum of NGC 3783 in the context of magnetically driven accretion-disk wind models in an effort to provide tight constraints on the global conditions of the underlying absorbers. Motivated by the earlier measurements of its absorption measure distribution (AMD) indicating X-ray-absorbing ionic columns that decrease slowly with decreasing ionization parameter, we employ 2-dimension (2-D) magnetohydrodynamic (MHD) disk wind models to describe the global outflow. We compute its photoionization structure along with the wind kinematic properties, allowing us to further calculate in a self-consistent fashion the shapes of the major X-ray absorption lines. With the wind radial density profile determined by the AMD, the profiles of the ensemble of the observed absorption features are determined by the two global parameters of the MHD wind; i.e., disk inclination theta (sub obs) and wind density normalization n (sub o). Considering the most significant absorption features in the approximately 1.8-20 angstrom range, we show that the MHD wind is best described by n(r) approximately equal to 6.9 times 10 (sup 11) (r/r (sub o)) (sup - 1.15) cubic centimeters and theta (sub obs). We argue that winds launched by X-ray heating or radiation pressure, or even MHD winds but with steeper radial density profiles, are strongly disfavored by data. Considering the properties of Fe K-band absorption features (i.e., Fe XXV and Fe XXVI), while typically prominent in the active galactic nucleus X-ray spectra, they appear to be weak in NGC 3783. For the specific parameters of our model obtained by fitting the AMD and the rest of the absorption features, these features are found to be weak, in agreement with observations.

Magnetized Disk Winds in NGC 3783

NASA Astrophysics Data System (ADS)

Fukumura, Keigo; Kazanas, Demosthenes; Shrader, Chris; Behar, Ehud; Tombesi, Francesco; Contopoulos, Ioannis

2018-01-01

We analyze a 900 ks stacked Chandra/HETG spectrum of NGC 3783 in the context of magnetically driven accretion-disk wind models in an effort to provide tight constraints on the global conditions of the underlying absorbers. Motivated by the earlier measurements of its absorption measure distribution (AMD) indicating X-ray-absorbing ionic columns that decrease slowly with decreasing ionization parameter, we employ 2D magnetohydrodynamic (MHD) disk wind models to describe the global outflow. We compute its photoionization structure along with the wind kinematic properties, allowing us to further calculate in a self-consistent fashion the shapes of the major X-ray absorption lines. With the wind radial density profile determined by the AMD, the profiles of the ensemble of the observed absorption features are determined by the two global parameters of the MHD wind; i.e., disk inclination {θ }{obs} and wind density normalization n o . Considering the most significant absorption features in the ∼1.8–20 Å range, we show that the MHD wind is best described by n{(r)∼ 6.9× {10}11(r/{r}o)}-1.15 cm‑3 and {θ }{obs}=44^\\circ . We argue that winds launched by X-ray heating or radiation pressure, or even MHD winds but with steeper radial density profiles, are strongly disfavored by data. Considering the properties of Fe K-band absorption features (i.e., Fe XXV and Fe XXVI), while typically prominent in the active galactic nucleus X-ray spectra, they appear to be weak in NGC 3783. For the specific parameters of our model obtained by fitting the AMD and the rest of the absorption features, these features are found to be weak, in agreement with observations.

Mid-infrared interferometric variability of DG Tauri: Implications for the inner-disk structure

NASA Astrophysics Data System (ADS)

Varga, J.; Gabányi, K. É.; Ábrahám, P.; Chen, L.; Kóspál, Á.; Menu, J.; Ratzka, Th.; van Boekel, R.; Dullemond, C. P.; Henning, Th.; Jaffe, W.; Juhász, A.; Moór, A.; Mosoni, L.; Sipos, N.

2017-08-01

Context. DG Tau is a low-mass pre-main sequence star, whose strongly accreting protoplanetary disk exhibits a so-far enigmatic behavior: its mid-infrared thermal emission is strongly time-variable, even turning the 10 μm silicate feature from emission to absorption temporarily. Aims: We look for the reason for the spectral variability at high spatial resolution and at multiple epochs. Methods: Infrared interferometry can spatially resolve the thermal emission of the circumstellar disk, also giving information about dust processing. We study the temporal variability of the mid-infrared interferometric signal, observed with the VLTI/MIDI instrument at six epochs between 2011 and 2014. We fit a geometric disk model to the observed interferometric signal to obtain spatial information about the disk. We also model the mid-infrared spectra by template fitting to characterize the profile and time dependence of the silicate emission. We use physically motivated radiative transfer modeling to interpret the mid-infrared interferometric spectra. Results: The inner disk (r < 1-3 au) spectra exhibit a 10 μm absorption feature related to amorphous silicate grains. The outer disk (r > 1-3 au) spectra show a crystalline silicate feature in emission, similar to the spectra of comet Hale-Bopp. The striking difference between the inner and outer disk spectral feature is highly unusual among T Tauri stars. The mid-infrared variability is dominated by the outer disk. The strength of the silicate feature changed by more than a factor of two. Between 2011 and 2014 the half-light radius of the mid-infrared-emitting region decreased from 1.15 to 0.7 au. Conclusions: For the origin of the absorption we discuss four possible explanations: a cold obscuring envelope, an accretion heated inner disk, a temperature inversion on the disk surface and a misaligned inner geometry. The silicate emission in the outer disk can be explained by dusty material high above the disk plane, whose mass can change with time, possibly due to turbulence in the disk. Based on observations made with the ESO Very Large Telescope Interferometer at Paranal Observatory (Chile) under the programs 088.C-1007 (PI: L. Mosoni), 090.C-0040 (PI: Th. Ratzka), and 092.C-0086 (PI: Th. Ratzka).

Production of Ti-C presolar carbide grain analogies and its infrared spectra

NASA Astrophysics Data System (ADS)

Kimura, Y.; Ikegami, A.; Tanigaki, T.; Ishikawa, M.; Sato, T.; Suzuki, H.; Kido, O.; Kaito, C.

The infrared emission of the circumstellar environment of carbon-rich stars and dense molecular cloud cores is believed to be dominated by the emissivity of carbon dust. The origins of absorption peaks will be identified on the basis of laboratory studies. Important factors in the determination of absorption features are size, shape and structure of the grain (Bohren and Huffman, 1983). Therefore, the production of presolar grain analogy is important for the identification of the observation spectra. Recently, we succeeded in the formation of Si-, Ti- and Zr-C grains of the order of 50 nm by advanced gas evaporation method. We have started to obtain characteristic data of carbide grains in laboratory experiments. The spectra from ultraviolet to infrared of samples embedded in KBr pellets are presented. In the present study, we will elucidate the correlation between the size of TiC grain or thickness of the carbon mantle layer and spectra of TiC core-carbon mantle grains. Because TiC is one of the candidates of 21 micron feature. The absorption peaks of TiC core (50 nm)-carbon mantle (2 nm) grains were found to be at 9.5 and 12.5 microns. When the thickness of the mantle layer increased to 15 nm, the peak at 12.5 microns disappeared and the peak at 9.5 microns was significantly weakened. These results are similar to the calculated result for SiC core-carbon mantle grains, i.e., increased thickness of the mantle layer weakens the spectrum intensity (Kozasa et al., 1996). The 20.1 micron absorption feature never appeared, even if the same size grains seen in meteorites were produced. Moreover, the infrared spectra were observed when the size of TiC grains was smaller than presolar grain. Carbon was deposited on the surface of Ti grains. Then, TiC nanocrystallites with the size of 2-3 nm were produced by the diffusion of Ti and/or carbon. The new absorption feature was appeared at 14 microns. The 12.5 micron absorption was hardly seen. If the samples are heated at 700circC for 1h, crystallites size of TiC was increased to about 5 nm. The absorption feature at 14 microns was weaken. It was concluded that the infrared absorption feature was depend on the crystallites size.

Analysis of Shuttle Multispecral Infrared Radiometer measurements of the western Saudi Arabian shield.

USGS Publications Warehouse

Rowan, Lawrence C.; Goetz, Alexander F.H.; Abbott, Elsa

1987-01-01

During the November 12–14, 1981, mission of the space shuttle Columbia, the Shuttle Multispectral Infrared Radiometer (SMIRR) recorded radiances in ten channels along a 100 m wide groundtrack across the western Saudi Arabian shield. The ten channels are located in the 0.5 to 2.4 μm region, with five positioned between 2.0 and 2.40 μm for measuring absorption features that are diagnostic of OH‐bearing and CO3‐bearing">CO3‐bearing minerals. This exceptionally well exposed area consists of late Proterozoic metamorphic, intermediate to silicic intrusive, and interlayered clastic sedimentary and intermediate silicic volcanic rocks that have not been studied previously using SMIRR data. Plots or traces of unnormalized SMIRR channel ratios were examined before field studies to locate areas with high spectral contrast, especially in the 2.0 μm to 2.40 μm channels. Reflectance spectra were measured in the laboratory for rock and soil samples collected in these areas, and the mineralogic causes of the main absorption features were determined using X‐ray diffraction. Laboratory SMIRR spectra were produced by convolving the ten SMIRR filters with the laboratory spectra. Then, normalized SMIRR reflectance spectra were generated along the groundtrack using normalization coefficients calculated for a field sample representing a uniform, low‐spectral contrast area. Field evaluation shows that unnormalized SMIRR ratio traces are useful, even without specific mineralogic information, for distinguishing rocks that are characterized by Al‐OH, Mg‐OH, and/or CO3">CO3">CO3, Fe3+">Fe3+, and Fe2+ absorption features. Analysis of field samples permits suites of minerals causing absorption features to be identified. However, specific mineral identification cannot be achieved consistently using the SMIRR ratio traces or normalized SMIRR spectra, because the Al‐OH and Mg‐OH absorption features can be caused by more than one of the minerals commonly present. The normalized SMIRR spectra are especially useful for identifying subtle Al‐OH and Mg‐OH absorption features that are difficult to identify in the unnormalized ratio traces and for comparing the relative intensities of absorption features. Al‐OH absorption is related to muscovite, smectite, illite, and kaolinite, whereas Mg‐OH absorption is caused by chlorite, amphibole, and biotite. The principal sources of error in using SMIRR spectral measurements for identifying mineral groups along the orbit 27 groundtrack are inaccuracies in field location and lithologic heterogeneity that is not represented adequately by field samples. Calibration errors may account for systematic albedo and absorption intensity differences between calculated laboratory SMIRR spectra and normalized SMIRR spectra. SMIRR instrument noise and atmospheric factors appear to be less important sources of error. However, as higher spectral and spatial resolution systems are developed for mineral identification, radiometric precision and atmospheric factors will become more important.

Hyperspectral analysis of the ultramafic complex and adjacent lithologies at Mordor, NT, Australia

USGS Publications Warehouse

Rowan, L.C.; Simpson, C.J.; Mars, J.C.

2004-01-01

The Mordor Complex consists of a series of potassic ultramafic rocks which were intruded into Proterozoic felsic gneisses and amphibolite and are overlain by quartzite and unconsolidated deposits. In situ and laboratory 0.4 to 2.5 ??m reflectance spectra show Al-OH absorption features caused by absorption in muscovite, kaolinite, and illite/smectite in syenite, granitic gneiss, quartzite and unconsolidated sedimentary deposits, and Fe,Mg-OH features due to phlogopite, biotite, epidote, and hornblende in the mafic and ultramafic rocks. Ferrous-iron absorption positioned near 1.05 ??m is most intense in peridotite reflectance spectra. Ferric-iron absorption is intense in most of the felsic lithologies. HyMap data were recorded in 126 narrow bands from 0.43 to 2.5 ??m along a 7-km-wide swath with approximately 6-m spatial resolution. Correction of the data to spectral reflectance was accomplished by reference to in situ measurements of an extensive, alluvial plain. Spectral classes for matched filter processing were selected by using the pixel purity index procedure and analysis of in situ and laboratory spectra. Considering the spatial distribution of the resulting 14 classes, some classes were combined, which produced eight classes characterized by Al-OH absorption features, and three Fe,Mg-OH absorption-feature classes. Comparison of the distribution of these 11 spectral classes to a generalized lithologic map of the study area shows that the spectral distinction among the eight Al-OH classes is related to variations in primary lithology, weathering products, and vegetation density. Quartzite is represented in three classes, syenite corresponds to a single scattered class, quartz-muscovite-biotite schist defines a single very coherent class, and unconsolidated sediments are portrayed in four classes. The three mafic-ultramafic classes are distinguished on the basis of generally intense Fe,Mg-OH and ferrous-iron absorption features. A single class represents the main Mordor ultramafic mass. Epidote-bearing rocks define another class, which corresponds to biotite gneiss and, in the southern part of the area, to fracture zones. The third class, which exhibits Al-OH, as well as Fe,Mg-OH features, represents hornblende gneiss and other mafic gneisses. These results indicate the importance of analyzing the VNIR and SWIR spectral shape and albedo, as well as analyzing specific spectral features, for mapping lithologic units in this weathered terrain. ?? 2004 Elsevier Inc. All rights reserved.

Laser isotope separation by multiple photon absorption

DOEpatents

Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

1987-04-07

Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

On the Non-Metallicity of 2.2 nm Au 246 (SR) 80 Nanoclusters

DOE PAGES

Zhou, Meng; Zeng, Chenjie; Song, Yongbo; ...

2017-11-22

The transition from molecular to plasmonic behaviour in metal nanoparticles with increasing size remains a central question in nanoscience. Here, we report that the giant 246-gold-atom nanocluster (2.2 nm in gold core diameter) protected by 80 thiolate ligands is surprisingly non-metallic based on UV/Vis and femtosecond transient absorption spectroscopy as well as electrochemical measurements. Specifically, the Au246 nanocluster exhibits multiple excitonic peaks in transient absorption spectra and electron dynamics independent of the pump power, which are in contrast to the behaviour of metallic gold nanoparticles. Moreover, a prominent oscillatory feature with frequency of 0.5 THz can be observed in almostmore » all the probe wavelengths. The phase and amplitude analysis of the oscillation suggests that it arises from the wavepacket motion on the ground state potential energy surface, which also indicates the presence of a small band-gap and thus non-metallic or molecular-like behaviour.« less

Band-edge absorption coefficients from photoluminescence in semiconductor multiple quantum wells

NASA Technical Reports Server (NTRS)

Kost, Alan; Zou, Yao; Dapkus, P. D.; Garmire, Elsa; Lee, H. C.

1989-01-01

A novel approach to determining absorption coefficients in thin films using luminescence is described. The technique avoids many of the difficulties typically encountered in measurements of thin samples, Fabry-Perot effects, for example, and can be applied to a variety of materials. The absorption edge for GaAs/AlGaAs multiple quantum well structures, with quantum well widths ranging from 54 to 193 A is examined. Urbach (1953) parameters and excitonic linewidths are tabulated.

Correlations between Crystallite Size, Shape, Surface, and Infrared Spectra Using the Ti-C System

NASA Astrophysics Data System (ADS)

Kimura, Y.; Ikegami, A.; Kurumada, M.; Kamitsuji, K.; Kaito, C.

2004-06-01

TiC crystallites less than 10 nm in size showed an absorption feature at 14.3 μm. This 14.3 μm absorption was rarely seen in specimens ranging from bulk material to grains of 50 nm in size. The 14.3 μm feature was weakened as a result of the growth of TiC crystallites by heat treatment. When the carbide grains were covered with a carbon layer, the absorption peaks were considerably weakened, i.e., the absorption intensity depended on the grain surface state. A possible explanation is that the effects of size and shape on the spectra depend on the surface anisotropy.

Composition and structure of fresh ammonia clouds on Jupiter based on quantitative analysis of Galileo/NIMS and New Horizons/LEISA spectra

NASA Astrophysics Data System (ADS)

Sromovsky, L. A.; Fry, P. M.

2018-06-01

Ammonia gas has long been assumed to be the main source of condensables for the upper cloud layer on Jupiter, but distinctive spectral features associated with ammonia have been seen only rarely. Since both ammonia and NH4SH absorb in the 3 μm region, and widespread absorption in the 3 μm region was present (Sromovsky and Fry, 2010), identification of the 2 μm absorption feature of NH3 provided an opportunity to clearly establish its presence in Jovian clouds. Baines et al. (2002) succeeded in finding in Near Infrared Mapping Spectrometer (NIMS) observations one feature that had both 2 μm and 3 μm absorption, and many which were known to have absorption at 2.73 μm. They named these Spectrally Identifiable Ammonia Clouds (SIACs). They also argued that these were fresh ammonia clouds that would eventually succumb to some process that would obscure their absorption features. Detection of many more of the 2 μm features was later achieved by New Horizon's Linear Etalon Imaging Spectral Array (LEISA) instrument, which provided both the spatial and spectral resolution needed to identify these features. Here we report on the first quantitative modeling that uses NIMS spectra over a broad (1-5.2 μm) spectral range and LEISA spectra over a much narrower (1.25-2.5 μm) spectral range to constrain the cloud structure and composition of these rare cloud features and compare them to background clouds. We find that the absorption signature at 2 μm, which is well characterized in LEISA spectra, is relatively subtle and easily matched by model clouds containing spherical particles of ammonia ice with radii of 2-4 μm. The NIMS spectra, which cover both reflected sunlight as well as thermal emission regions are more difficult to model with cloud materials plausibly present in Jupiter's atmosphere. The best signal/noise spectra obtained from NIMS provide a relatively sparse sampling of the spectrum, which does not establish the detailed shape of the 3 μm absorption region. NIMS SIAC spectra with much denser spectral sampling are limited by much higher noise levels that degrade the features that are key to identifying cloud composition. The structure which best matches the wide range NIMS SIAC spectra contains two overlapping NH3 clouds with a bi-modal size distribution over an optically thick NH4SH cloud. The bi-modal distribution may be a result of modeling non-spherical, possibly fractal aggregate, particles with spheres.

Investigating Hydroxyl at Asteroid 951 Gaspra

NASA Astrophysics Data System (ADS)

Granahan, James C.

2015-11-01

Recent investigations [Granahan, 2011; 2014] of Galileo Near Infrared Mapping Spectrometer (NIMS) observations of asteroid 951 Gaspra have detected an infrared absorption feature near 2.8 micrometers. These were detected in NIMS data acquired by the Galileo spacecraft on October 29, 1991 at wavelengths ranging from 0.7 - 5.2 micrometers [Carlson et al., 1992]. This abstract presents a summary of the investigation to identify the material creating the 2.8 micrometer spectral absorption feature. The current best match for the observed 951 Gaspra feature is the phyllosilicate bound hydroxyl signature present in a thermally desiccated QUE 99038 carbonaceous chondrite as measured by Takir et al. [2013].The 951 Gaspra absorption feature has been compared to a variety of hydroxyl bearing signatures. Many phyllosilicates, hydroxyl bearing minerals, have absorption minima at different positions (2.7 or 2.85 micrometers). It also differs from similar absorptions in a potential R chondrite analog, LAP 04840. The spectra LAP 04840 has a 2.7 micrometer feature due to biotite and a 2.9 micrometer feature due to adsorbed water [Klima et al., 2007]. 2.8 micrometer absorption minima have been found for adsorbed hydroxyl on the Moon [McCord et al., 2011] and various carbonaceous chondrites [Calvin and King, 1997; Takir et al., 2013]. The best match, with a minimum Euclidean distance difference to the 951 Gaspra feature, is found in the spectrum of QUE 99038 [Takir et al., 2013]. This spectrum is the product of an infrared measurement of a sample that had its adsorbed water baked off and removed in a vacuum chamber. The remaining hydroxyl in the sample belongs to a mixture of phyllosilicates dominated by the presence of cronstedtite.References: Calvin, W. M., and T. V. King (1997), Met. Planet. Sci., 32, 693-702. Carlson, R. W., et al. (1992), Bull. American Astro. Soc., 24, 932. Granahan, J. C. (2011), Icarus, 213, 265-272. Granahan, J. C. (2014), 45th LPSC, #1092. Klima, R., C. et al. (2007), 38th LPSC, #1710. McCord, T. B., et al. (2011), JGR, 116, E00G05. Takir, D., et al. (2013), Met. Planet. Sci., 48, 1618-1637.

IUE detector saturation and the new 2800 A absorption feature 'discovered' by Karim, Hoyle, and Wickramasinghe

NASA Astrophysics Data System (ADS)

Savage, B. D.; Sitko, M. L.

1984-03-01

The 2800 A feature of Karim et al. (1983) is shown to be the result of IUE detector saturation effects in overexposed spectra. A properly exposed spectrum and an overexposed one are shown. The latter shows a broad absorption peak at 2800 A while the former does not.

Cell classification using big data analytics plus time stretch imaging (Conference Presentation)

NASA Astrophysics Data System (ADS)

Jalali, Bahram; Chen, Claire L.; Mahjoubfar, Ata

2016-09-01

We show that blood cells can be classified with high accuracy and high throughput by combining machine learning with time stretch quantitative phase imaging. Our diagnostic system captures quantitative phase images in a flow microscope at millions of frames per second and extracts multiple biophysical features from individual cells including morphological characteristics, light absorption and scattering parameters, and protein concentration. These parameters form a hyperdimensional feature space in which supervised learning and cell classification is performed. We show binary classification of T-cells against colon cancer cells, as well classification of algae cell strains with high and low lipid content. The label-free screening averts the negative impact of staining reagents on cellular viability or cell signaling. The combination of time stretch machine vision and learning offers unprecedented cell analysis capabilities for cancer diagnostics, drug development and liquid biopsy for personalized genomics.

Copernicus observational searches for OH and H/sub 2/O in diffuse clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, W.H.; Snow, T.P. Jr.

1979-03-01

An intensive search for OH and H/sub 2/O in the directions of sigma Sco, ..cap alpha.. Cam, and omicron Per was undertaken with the Copernicus satellite. Multiple scans were carried out over the wavelength region for the expected absorption features due to the OH D--X and H/sub 2/O C--X transitions. The feature due to OH was possibly detected toward sigma Sco, and only an upper limit can be given toward ..cap alpha.. Cam. H/sub 2/O was not detected in any of the stars at the signal level accumulated. The OH abundance toward sigma Sco and the respective lower limits formore » the OH/H/sub 2/O ratios are discussed with regard to the extant models for the steady-state abundances of OH and H/sub 2/O, and shown not to be inconsistent with ion-molecule schemes.« less

Investigations on the 1.7 micron residual absorption feature in the vegetation reflection spectrum

NASA Technical Reports Server (NTRS)

Verdebout, J.; Jacquemoud, S.; Andreoli, G.; Hosgood, B.; Sieber, A.

1993-01-01

The detection and interpretation of the weak absorption features associated with the biochemical components of vegetation is of great potential interest to a variety of applications ranging from classification to global change studies. This recent subject is also challenging because the spectral signature of the biochemicals is only detectable as a small distortion of the infrared spectrum which is mainly governed by water. Furthermore, the interpretation is complicated by complexity of the molecules (lignin, cellulose, starch, proteins) which contain a large number of different and common chemical bonds. In this paper, we present investigations on the absorption feature centered at 1.7 micron; these were conducted both on AVIRIS data and laboratory reflectance spectra of leaves.

Split-flow regeneration in absorptive air separation

DOEpatents

Weimer, Robert F.

1987-01-01

A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

Near-Infrared Band Strengths of Molecules Diluted in N2 and H20 Ice Mixtures Relevant to Interstellar and Planetary Ices

NASA Technical Reports Server (NTRS)

Richey, C. R.; Richey, Christina R.

2012-01-01

In order to determine the column density of a component of an ice from its infrared absorption features, the strengths of these features must be known. The peak positions, widths, profiles, and strengths of a certain ice component's infrared absorption features are affected be the overall composition of the ice. Many satellites within the solar system have surfaces that are dominated by H2O or N2 and ices in the interstellar medium (ISM) are primarily composed of H2O. The experiments presented here focus on the near-infrared absorption features of CO, CO2, CH4, and NH3 (nu=10,000-4,000/cm, lambda=1-2.5 microns) and the effects of diluting these molecules in N2 or H2O ice (mixture ratio of 5:1). This is a continuation of previous results published by our research group.

Split-flow regeneration in absorptive air separation

DOEpatents

Weimer, R.F.

1987-11-24

A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs. 4 figs.

Aluminium X-ray absorption Near Edge Structure in model compounds and Earth's surface minerals

NASA Astrophysics Data System (ADS)

Ildefonse, P.; Cabaret, D.; Sainctavit, P.; Calas, G.; Flank, A.-M.; Lagarde, P.

Aluminium K-edge X-ray absorption near edge spectra (XANES) of a suite of silicate and oxides minerals consist of electronic excitations occurring in the edge region, and multiple scattering resonances at higher energies. The main XANES feature for four-fold Al is at around 2 eV lower energy than the main XANES feature for six-fold Al. This provides a useful probe for coordination numbers in clay minerals, gels, glasses or material with unknown Al-coordination number. Six-fold aluminium yields a large variety of XANES features which can be correlated with octahedral point symmetry, number of aluminium sites and distribution of Al-O distances. These three parameters may act together, and the quantitative interpretation of XANES spectra is difficult. For a low point symmetry (1), variations are mainly related to the number of Al sites and distribution of Al-O distances: pyrophyllite, one Al site, is clearly distinguished from kaolinite and gibbsite presenting two Al sites. For a given number of Al-site (1), variations are controlled by changes in point symmetry, the number of XANES features being increased as point symmetry decreases. For a given point symmetry (1) and a given number of Al site (1), variations are related to second nearest neighbours (gibbsite versus kaolinite). The amplitude of the XANES feature at about 1566 eV is a useful probe for the assessment of AlIV/Altotal ratios in 2/1 phyllosilicates. Al-K XANES has been performed on synthetic Al-bearing goethites which cannot be studied by 27Al NMR. At low Al content, Al-K XANES is very different from that of α-AlOOH but at the highest level, XANES spectrum tends to that of diaspore. Al-K XAS is thus a promising tool for the structural study of poorly ordered materials such as clay minerals and natural alumino-silicate gels together with Al-subsituted Fe-oxyhydroxides.

Plant phenolics and absorption features in vegetation reflectance spectra near 1.66 μm

USGS Publications Warehouse

Kokaly, Raymond F.; Skidmore, Andrew K

2015-01-01

Past laboratory and field studies have quantified phenolic substances in vegetative matter from reflectance measurements for understanding plant response to herbivores and insect predation. Past remote sensing studies on phenolics have evaluated crop quality and vegetation patterns caused by bedrock geology and associated variations in soil geochemistry. We examined spectra of pure phenolic compounds, common plant biochemical constituents, dry leaves, fresh leaves, and plant canopies for direct evidence of absorption features attributable to plant phenolics. Using spectral feature analysis with continuum removal, we observed that a narrow feature at 1.66 μm is persistent in spectra of manzanita, sumac, red maple, sugar maple, tea, and other species. This feature was consistent with absorption caused by aromatic C-H bonds in the chemical structure of phenolic compounds and non-hydroxylated aromatics. Because of overlapping absorption by water, the feature was weaker in fresh leaf and canopy spectra compared to dry leaf measurements. Simple linear regressions of feature depth and feature area with polyphenol concentration in tea resulted in high correlations and low errors (% phenol by dry weight) at the dry leaf (r2 = 0.95, RMSE = 1.0%, n = 56), fresh leaf (r2 = 0.79, RMSE = 2.1%, n = 56), and canopy (r2 = 0.78, RMSE = 1.0%, n = 13) levels of measurement. Spectra of leaves, needles, and canopies of big sagebrush and evergreens exhibited a weak absorption feature centered near 1.63 μm, short ward of the phenolic compounds, possibly consistent with terpenes. This study demonstrates that subtle variation in vegetation spectra in the shortwave infrared can directly indicate biochemical constituents and be used to quantify them. Phenolics are of lesser abundance compared to the major plant constituents but, nonetheless, have important plant functions and ecological significance. Additional research is needed to advance our understanding of the spectral influences of plant phenolics and terpenes relative to dominant leaf biochemistry (water, chlorophyll, protein/nitrogen, cellulose, and lignin).

Wavelength feature mapping as a proxy to mineral chemistry for investigating geologic systems: An example from the Rodalquilar epithermal system

NASA Astrophysics Data System (ADS)

van der Meer, Freek; Kopačková, Veronika; Koucká, Lucie; van der Werff, Harald M. A.; van Ruitenbeek, Frank J. A.; Bakker, Wim H.

2018-02-01

The final product of a geologic remote sensing data analysis using multi spectral and hyperspectral images is a mineral (abundance) map. Multispectral data, such as ASTER, Landsat, SPOT, Sentinel-2, typically allow to determine qualitative estimates of what minerals are in a pixel, while hyperspectral data allow to quantify this. As input to most image classification or spectral processing approach, endmembers are required. An alternative approach to classification is to derive absorption feature characteristics such as the wavelength position of the deepest absorption, depth of the absorption and symmetry of the absorption feature from hyperspectral data. Two approaches are presented, tested and compared in this paper: the 'Wavelength Mapper' and the 'QuanTools'. Although these algorithms use a different mathematical solution to derive absorption feature wavelength and depth, and use different image post-processing, the results are consistent, comparable and reproducible. The wavelength images can be directly linked to mineral type and abundance, but more importantly also to mineral chemical composition and subtle changes thereof. This in turn allows to interpret hyperspectral data in terms of mineral chemistry changes which is a proxy to pressure-temperature of formation of minerals. We show the case of the Rodalquilar epithermal system of the southern Spanish Gabo de Gata volcanic area using HyMAP airborne hyperspectral images.

Optical properties of an inhomogeneously broadened ΛV-system with multiple excited states

NASA Astrophysics Data System (ADS)

Kaur, Paramjit; Bharti, Vineet; Wasan, Ajay

2014-09-01

We present a theoretical model using a density matrix approach to show the influence of multiple excited states on the optical properties of an inhomogeneously broadened ?V-system of the ?Rb D2 line. These closely spaced multiple excited states cause asymmetry in absorption and dispersion profiles. We observe the reduced absorption profiles, due to dressed state interactions of the applied electromagnetic fields, which results the Mollow sideband-like transparency windows. In a room temperature vapor, we obtain a narrow enhanced absorption and steep positive dispersion at the line center when the strengths of control and pump fields are equal. Here, we show how the probe transmittance varies when it passes through the atomic medium. We also discuss the transient behavior of our system which agrees well with the corresponding absorption and dispersion profiles. This study has potential applications in controllability of group velocity, and for optical and quantum information processing.

Optimal design of sound absorbing systems with microperforated panels

NASA Astrophysics Data System (ADS)

Kim, Nicholas Nakjoo

As the development of technology makes economic prosperity and life more convenient, people now desire a higher quality of life. This quality of life is based not only on the convenience in their life but also on clean and eco-friendly environments. To meet that requirement, much research is being performed in many areas of eco-friendly technology, such as renewable energy, biodegradable content, and batteries for electronic vehicles. This tendency is also obvious in the acoustics area, where there are continuing attempts to replace fiber-glass sound absorbers with fiber-free materials. The combination of microperfoated panels (MPP) (one of the fiber-free sound absorbing materials), usually in the form of a thin panel with small holes, and an air backing may be one of the preferred solutions. These panels can be designed in many ways, and usually feature many small (sub-millimeter) holes and typically surface porosities on the order of 1 percent. The detailed acoustical properties of MPPs depend on their hole shape, the hole diameter, the thickness of the panel, the overall porosity of the perforated film, the film's mass per unit area, and the depth of the backing air cavity. Together, these parameters control the absorption peak location and the magnitude of the absorption coefficient (and the magnitude of the transmission loss in barrier applications). By an appropriate choice of these parameters good absorption performance can be achieved in a frequency range one or two octaves wide. That kind of solution may be adequate when it is necessary to control sound only in a specified frequency range (in the speech interference range, for example). However, in order to provide appropriate noise control solutions over a broader range of frequencies, it is necessary to design systems featuring multiple-layers of MPPs, thus creating what amounts to a multi-degree-of-freedom system and so expanding the range over which good absorption can be obtained. In this research, three different situations were considered: one was studying the combination of microperforated panels with tapered holes and a specific depth of air backing space with a view to finding the trade-off between hole angle and surface porosity. Secondly, it was of interest to study the use of multiple-layer MPPs as functional absorbers. Finally, there is a study of the optimization of a multi-layer cylindrical duct liner that gives maximum axial attenuation. Note that "Functional Absorber" is the name given to a system that can be hung, in an industrial space, for example, to provide acoustic absorption. The duct applications of interest would be in HVAC systems, whether in buildings, automotive systems or personal ventilators. In both applications, the focus was on obtaining the best possible performance in the full speech interference range, which spans the range from 500 Hz to 4000 kHz. In each case, a transfer matrix method has been developed to calculate the transmission loss and absorption coefficients provided by the systems. Note finally that the design of an N multiple-layer MPP system depends on 5N-1 parameters, and so a general optimization becomes difficult in realistic cases when as many as ten layers might be used. Thus, the use of a genetic algorithm to optimize the system parameters has been adopted, since an algorithm of that sort can efficiently identify good solutions from a very large design space. The results, as presented in this thesis, show that it is possible to identify the best combination of MPP properties that improve the desired acoustic performance, whether absorption or transmission loss, in a prescribed frequency range.

Classification by diagnosing all absorption features (CDAF) for the most abundant minerals in airborne hyperspectral images

NASA Astrophysics Data System (ADS)

Mobasheri, Mohammad Reza; Ghamary-Asl, Mohsen

2011-12-01

Imaging through hyperspectral technology is a powerful tool that can be used to spectrally identify and spatially map materials based on their specific absorption characteristics in electromagnetic spectrum. A robust method called Tetracorder has shown its effectiveness at material identification and mapping, using a set of algorithms within an expert system decision-making framework. In this study, using some stages of Tetracorder, a technique called classification by diagnosing all absorption features (CDAF) is introduced. This technique enables one to assign a class to the most abundant mineral in each pixel with high accuracy. The technique is based on the derivation of information from reflectance spectra of the image. This can be done through extraction of spectral absorption features of any minerals from their respected laboratory-measured reflectance spectra, and comparing it with those extracted from the pixels in the image. The CDAF technique has been executed on the AVIRIS image where the results show an overall accuracy of better than 96%.

Enhancement of broadband optical absorption in photovoltaic devices by band-edge effect of photonic crystals.

PubMed

Tanaka, Yoshinori; Kawamoto, Yosuke; Fujita, Masayuki; Noda, Susumu

2013-08-26

We numerically investigate broadband optical absorption enhancement in thin, 400-nm thick microcrystalline silicon (µc-Si) photovoltaic devices by photonic crystals (PCs). We realize absorption enhancement by coupling the light from the free space to the large area resonant modes at the photonic band-edge induced by the photonic crystals. We show that multiple photonic band-edge modes can be produced by higher order modes in the vertical direction of the Si photovoltaic layer, which can enhance the absorption on multiple wavelengths. Moreover, we reveal that the photonic superlattice structure can produce more photonic band-edge modes that lead to further optical absorption. The absorption average in wavelengths of 500-1000 nm weighted to the solar spectrum (AM 1.5) increases almost twice: from 33% without photonic crystal to 58% with a 4 × 4 period superlattice photonic crystal; our result outperforms the Lambertian textured structure.

Hydrothermal alteration mapping using ASTER data in Baogutu porphyry deposit, China

NASA Astrophysics Data System (ADS)

Li, Q.; Zhang, B.; Lu, L.; Lin, Q.

2014-03-01

Remote sensing plays an important role in mineral exploration. One of its proven applications is extracting host-rock lithology and alteration zones that are related to porphyry copper deposits. An Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) was used to map the Baogutu porphyry deposit alteration area. A circular alteration mineral zoning pattern was clearly observed in the classification result of potassic, phyllic, argillic, propylitic zones. The potassic is characterized by biotite and anhydrite with an absorption feature centered at 1.94 and 2.1um. The phyllic zone is characterized by illite and sericite that indicates an intense Al-OH absorption feature centered at 2.20um. The narrower argillic zone including kaolinite and alunite displays a secondary Al-OH absorption feature at 2.17 um. The mineral assemblages of the outer propylitic zone are epidote, chlorite and calcite that exhibit absorption features at 2.335um.The performance of Principal Component Analysis(PCA), Minimum Noise Fraction (MNF), band ratio(BR) and Constrained Energy Minimization(CEM) has been evaluated. These techniques identified new prospects of porphyry copper mineralization in the study areas. These results indicate that ASTER is a powerful tool in the initial steps of mineral exploration.

Negative Searches for Evidence of Aqueous Alteration on Asteroid Surfaces

NASA Technical Reports Server (NTRS)

Vilas, F.

2005-01-01

Small bodies in the Solar System preserve evidence of the processes occurring during early Solar System formation, unlike the larger planets that undergo continuous churning of their surfaces. We study these bodies to understand what processes affected different stages of Solar System formation. The action of aqueous alteration (the alteration of material by the interaction of that material with liquid formed by the melting of incorporated ice) of near-subsurface material has been inferred to occur on many asteroids based on the spectrophotometric evidence of phyllosilicates and iron alteration minerals. The definitive indication of aqueous alteration is the 3.0- micron absorption feature attributed to structural hydroxyl (OH) and interlayer and adsorbed water (H2O) in phyllosilicates (clays) (hereafter water of hydration). A weak absorption feature centered near 0.7 microns attributed to an Fe (2+) right arrow Fe (3+) charge transfer transition in oxidized iron in phyllosilicates has been observed in the reflectance spectra and photometry of approximately 50% of the main-belt C-class asteroids. An approximately 85% correlation between this 0.7- micron feature and the 3.0- micron water of hydration absorption feature was found among the low-albedo asteroids. The feature is usually centered near 0.68 microns in asteroid spectra, and ranges in wavelength from approximately 0.57 to 0.83 microns. Serendipitously, three of the Eight Color Asteroid Survey filters the v (0.550 microns), w (0.701 microns), and x (0.853 microns)-bracket this feature well, and can be used to determine the presence of this feature in the reflectance properties of an asteroid, and probe the aqueous alteration history of larger samples of asteroid data. Two efforts to search for evidence of aqueous alteration based on the presence of this 0.7- micron absorption feature are presented here.

Location of γ-ray emission and magnetic field strengths in OJ 287

NASA Astrophysics Data System (ADS)

Hodgson, J. A.; Krichbaum, T. P.; Marscher, A. P.; Jorstad, S. G.; Rani, B.; Marti-Vidal, I.; Bach, U.; Sanchez, S.; Bremer, M.; Lindqvist, M.; Uunila, M.; Kallunki, J.; Vicente, P.; Fuhrmann, L.; Angelakis, E.; Karamanavis, V.; Myserlis, I.; Nestoras, I.; Chidiac, C.; Sievers, A.; Gurwell, M.; Zensus, J. A.

2017-01-01

Context. The γ-ray BL Lac object OJ 287 is known to exhibit inner-parsec "jet-wobbling", high degrees of variability at all wavelengths and quasi-stationary features, including an apparent (≈100°) position-angle change in projection on the sky plane. Aims: Sub-50 micro-arcsecond resolution 86 GHz observations with the global mm-VLBI array (GMVA) supplement ongoing multi-frequency VLBI blazar monitoring at lower frequencies. Using these maps, together with cm/mm total intensity and γ-ray observations from Fermi-LAT from 2008-2014, we aim to determine the location of γ-ray emission and to explain the inner-mas structural changes. Methods: Observations with the GMVA offer approximately double the angular resolution compared with 43 GHz VLBA observations and enable us to observe above the synchrotron self-absorption peak frequency. Fermi-LAT γ-ray data were reduced and analysed. The jet was spectrally decomposed at multiple locations along the jet. From this, we could derive estimates of the magnetic field using equipartition and synchrotron self-absorption arguments. How the field decreases down the jet provided an estimate of the distance to the jet apex and an estimate of the magnetic field strength at the jet apex and in the broad line region. Combined with accurate kinematics, we attempt to locate the site of γ-ray activity, radio flares, and spectral changes. Results: Strong γ-ray flares appeared to originate from either the so-called core region, a downstream stationary feature, or both, with γ-ray activity significantly correlated with radio flaring in the downstream quasi-stationary feature. Magnetic field estimates were determined at multiple locations along the jet, with the magnetic field found to be ≥1.6 G in the core and ≤0.4 G in the downstream quasi-stationary feature. We therefore found upper limits on the location of the VLBI core as ≲6.0 pc from the jet apex and determined an upper limit on the magnetic field near the jet base of the order of thousands of Gauss. The 3 mm GMVA data are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/597/A80

Complex Resonance Absorption Structure in the X-Ray Spectrum of IRAS 13349+2438

NASA Technical Reports Server (NTRS)

Sako, M.; Kahn, S. M.; Behar, E.; Kaastra, J. S.; Brinkman, A. C.; Boller, Th.; Puchnarewicz, E. M.; Starling, R.; Liedahl, D. A.; Clavel, J.

2000-01-01

The luminous infrared-loud quasar IRAS 13349+2438 was observed with the XMM - Newton Observatory as part of the Performance Verification program. The spectrum obtained by the Reflection Grating Spectrometer (RGS) exhibits broad (FWHM - 1400 km/s) absorption lines from highly ionized elements including hydrogen- and helium-like carbon, nitrogen, oxygen, and neon, and several iron L - shell ions (Fe XVII - XX). Also shown in the spectrum is the first astrophysical detection of a broad absorption feature around lambda = 16 - 17 A identified as an unresolved transition array (UTA) of 2p - 3d inner-shell absorption by iron M-shell ions in a much cooler medium; a feature that might be misidentified as an O VII edge when observed with moderate resolution spectrometers. No absorption edges are clearly detected in the spectrum. We demonstrate that the RGS spectrum of IRAS 13349+2438 exhibits absorption lines from two distinct regions, one of which is tentatively associated with the medium that produces the optical/UV reddening.

AlInAsSb separate absorption, charge, and multiplication avalanche photodiodes

NASA Astrophysics Data System (ADS)

Ren, Min; Maddox, Scott J.; Woodson, Madison E.; Chen, Yaojia; Bank, Seth R.; Campbell, Joe C.

2016-05-01

We report AlxIn1-xAsySb1-y separate absorption, charge, and multiplication avalanche photodiodes (APDs) that operate in the short-wavelength infrared spectrum. They exhibit excess noise factor less or equal to that of Si and the low dark currents typical of III-V compound APDs.

[Experimental research of turbidity influence on water quality monitoring of COD in UV-visible spectroscopy].

PubMed

Tang, Bin; Wei, Biao; Wu, De-Cao; Mi, De-Ling; Zhao, Jing-Xiao; Feng, Peng; Jiang, Shang-Hai; Mao, Ben-Jiang

2014-11-01

Eliminating turbidity is a direct effect spectroscopy detection of COD key technical problems. This stems from the UV-visible spectroscopy detected key quality parameters depend on an accurate and effective analysis of water quality parameters analytical model, and turbidity is an important parameter that affects the modeling. In this paper, we selected formazine turbidity solution and standard solution of potassium hydrogen phthalate to study the turbidity affect of UV--visible absorption spectroscopy detection of COD, at the characteristics wavelength of 245, 300, 360 and 560 nm wavelength point several characteristics with the turbidity change in absorbance method of least squares curve fitting, thus analyzes the variation of absorbance with turbidity. The results show, In the ultraviolet range of 240 to 380 nm, as the turbidity caused by particle produces compounds to the organics, it is relatively complicated to test the turbidity affections on the water Ultraviolet spectra; in the visible region of 380 to 780 nm, the turbidity of the spectrum weakens with wavelength increases. Based on this, this paper we study the multiplicative scatter correction method affected by the turbidity of the water sample spectra calibration test, this method can correct water samples spectral affected by turbidity. After treatment, by comparing the spectra before, the results showed that the turbidity caused by wavelength baseline shift points have been effectively corrected, and features in the ultraviolet region has not diminished. Then we make multiplicative scatter correction for the three selected UV liquid-visible absorption spectroscopy, experimental results shows that on the premise of saving the characteristic of the Ultraviolet-Visible absorption spectrum of water samples, which not only improve the quality of COD spectroscopy detection SNR, but also for providing an efficient data conditioning regimen for establishing an accurate of the chemical measurement methods.

Chemometric analysis of correlations between electronic absorption characteristics and structural and/or physicochemical parameters for ampholytic substances of biological and pharmaceutical relevance.

PubMed

Judycka-Proma, U; Bober, L; Gajewicz, A; Puzyn, T; Błażejowski, J

2015-03-05

Forty ampholytic compounds of biological and pharmaceutical relevance were subjected to chemometric analysis based on unsupervised and supervised learning algorithms. This enabled relations to be found between empirical spectral characteristics derived from electronic absorption data and structural and physicochemical parameters predicted by quantum chemistry methods or phenomenological relationships based on additivity rules. It was found that the energies of long wavelength absorption bands are correlated through multiparametric linear relationships with parameters reflecting the bulkiness features of the absorbing molecules as well as their nucleophilicity and electrophilicity. These dependences enable the quantitative analysis of spectral features of the compounds, as well as a comparison of their similarities and certain pharmaceutical and biological features. Three QSPR models to predict the energies of long-wavelength absorption in buffers with pH=2.5 and pH=7.0, as well as in methanol, were developed and validated in this study. These models can be further used to predict the long-wavelength absorption energies of untested substances (if they are structurally similar to the training compounds). Copyright © 2014 Elsevier B.V. All rights reserved.

Detection of H I absorption in the dwarf galaxy Haro 11

NASA Astrophysics Data System (ADS)

MacHattie, Jeremy A.; Irwin, Judith A.; Madden, Suzanne C.; Cormier, Diane; Rémy-Ruyer, Aurélie

2014-02-01

We present the results of an analysis of archival 21 cm (H I) data of the blue compact dwarf galaxy Haro 11 (ESO 350-IG038). Observations were obtained at the Very Large Array, and the presence of a compact absorption feature near the optical centre of the galaxy has been detected. The central location of the absorption feature coincides with the centre of the continuum background of the galaxy, as well as with the location of knot B. The absorption feature yields an H I mass in the range of 3-10 × 108 M⊙, corresponding to spin temperatures from 91 K to 200 K, respectively. The absence of H I seen in emission places an upper limit of 1.7 × 109 M⊙ on the mass. To our knowledge this is the first example of a dwarf galaxy that shows H I absorption from its own background continuum. The continuum emission from the galaxy is also used to determine star formation rates, namely 6.85 ± 0.05 M⊙ yr-1 (for a stellar mass range of 5 M⊙ < M < 100 M⊙), or 32.8 ± 0.2 M⊙ yr-1 (for an extended range of 0.1 M⊙ < M < 100 M⊙).

Multiple-Path-Length Optical Absorbance Cell

NASA Technical Reports Server (NTRS)

2001-01-01

An optical absorbance cell that offers a selection of multiple optical path lengths has been developed as part of a portable spectrometric instrument that measures absorption spectra of small samples of water and that costs less than does a conventional, non-portable laboratory spectrometer. The instrument is intended, more specifically, for use in studying colored dissolved organic matter (CDOM) in seawater, especially in coastal regions. Accurate characterization of CDOM is necessary for building bio-optical mathematical models of seawater. The multiple path lengths of the absorption cell afford a wide range of sensitivity needed for measuring the optical absorbances associated with the wide range of concentrations of CDOM observed in nature. The instrument operates in the wavelength range of 370 to 725 nm. The major subsystems of the instrument (see figure) include a color-balanced light source; the absorption cell; a peristaltic pump; a high-precision, low-noise fiber optic spectrometer; and a laptop or other personal computer. A fiber-optic cable transmits light from the source to the absorption cell. Other optical fibers transmit light from the absorption cell to the spectrometer,

Computed a multiple band metamaterial absorber and its application based on the figure of merit value

NASA Astrophysics Data System (ADS)

Chen, Chao; Sheng, Yuping; Jun, Wang

2018-01-01

A high performed multiple band metamaterial absorber is designed and computed through the software Ansofts HFSS 10.0, which is constituted with two kinds of separated metal particles sub-structures. The multiple band absorption property of the metamaterial absorber is based on the resonance of localized surface plasmon (LSP) modes excited near edges of metal particles. The damping constant of gold layer is optimized to obtain a near-perfect absorption rate. Four kinds of dielectric layers is computed to achieve the perfect absorption perform. The perfect absorption perform of the metamaterial absorber is enhanced through optimizing the structural parameters (R = 75 nm, w = 80 nm). Moreover, a perfect absorption band is achieved because of the plasmonic hybridization phenomenon between LSP modes. The designed metamaterial absorber shows high sensitive in the changed of the refractive index of the liquid. A liquid refractive index sensor strategy is proposed based on the computed figure of merit (FOM) value of the metamaterial absorber. High FOM values (116, 111, and 108) are achieved with three liquid (Methanol, Carbon tetrachloride, and Carbon disulfide).

The widetilde{A}←widetilde{X} ABSORPTION SPECTRUM OF 2-NITROOXYBUTYL PEROXY RADICAL

NASA Astrophysics Data System (ADS)

Eddingsaas, Nathan; Takematsu, Kana; Okumura, Mitchio

2009-06-01

The nitrate radical is an important atmospheric oxidant in the nighttime sky. Nitrate radicals react by addition to alkenes, and in the presence of oxygen form nitrooxyalkyl peroxy radicals. The peroxy radical formed from the reaction of 2-butene, nitrate radical, and oxygen was detected by cavity ringdown spectroscopy (CRDS) via its widetilde{A}←widetilde{X} electronic absorption spectrum. The widetilde{A}←widetilde{X} electronic transition is a bound-bound transition with enough structure to distinguish between different peroxy radicals as well as different conformers of the same peroxy radical. Two conformers of the nitrooxybutyl peroxy radical have been observed; the absorption features are red shifted from the same absorption features of sec-butyl peroxy radical. Calculations on the structure of nitrooxyalkyl peroxy radicals and general trends of the position of the widetilde{A}←widetilde{X} absorption transitions have also been performed and compared to those of unsubstituted peroxy radicals.

Interstellar proteins and the discovery of a new absorption feature at lambda = 2800 A

NASA Astrophysics Data System (ADS)

Karim, L. M.; Hoyle, F.; Wickramasinghe, N. C.

1983-07-01

In order to check the presence of biogenic materials in interstellar grains, the spectra of three early-type, heavily reddened stars recorded by the IUE were examined. These stars showed comparatively weak absorption at 2200 A, minimizing the effect of graphite grains. A broad absorption feature centered on 2800 A is discovered in HD 14250 and interpreted to be due to the amino acid tryptophan. Comparison of the spectrum with that of the calculated extinction behavior of graphite spheres of radii 0.02 microns suggests that the latter are not responsible for the observed spectrum.

Sub-250nm room temperature optical gain from AlGaN materials with strong compositional fluctuations

NASA Astrophysics Data System (ADS)

Pecora, Emanuele; Zhang, Wei; Sun, Haiding; Nikiforov, A.; Yin, Jian; Paiella, Roberto; Moustakas, Theodore; Dal Negro, Luca

2013-03-01

Compact and portable deep-UV LEDs and laser sources are needed for a number of engineering applications including optical communications, gas sensing, biochemical agent detection, disinfection, biotechnology and medical diagnostics. We investigate the deep-UV optical emission and gain properties of AlxGa1-xN/AlyGa1-yN multiple quantum wells structure. These structures were grown by molecular-beam epitaxy on 6H-SiC substrates resulting in either homogeneous wells or various degrees of band-structure compositional fluctuations in the form of cluster-like features within the wells. We measured the TE-polarized amplified spontaneous emission in the sample with cluster-like features and quantified the optical absorption/gain coefficients and gain spectra by the Variable Stripe Length (VSL) technique under ultrafast optical pumping. We report blue-shift and narrowing of the emission, VSL traces, gain spectra, polarization studies, and the validity of the Schalow-Townes relation to demonstrate a maximum net modal gain of 120 cm-1 at 250 nm in the sample with strong compositional fluctuations. Moreover, we measure a very low gain threshold (15 μJ/cm2) . On the other hand, we found that samples with homogeneous quantum wells lead to absorption only. In addition, we report gain measurements in graded-index-separate-confined heterostructure (GRINSCH) designed to increase the device optical confinement factor.

Lightweight NiFe2O4 with controllable 3D network structure and enhanced microwave absorbing properties

NASA Astrophysics Data System (ADS)

Wang, Fen; Wang, Xing; Zhu, Jianfeng; Yang, Haibo; Kong, Xingang; Liu, Xiao

2016-11-01

3D network structure NiFe2O4 was successfully synthesized by a templated salt precipitation method using PMMA colloid crystal as templates. The morphology, phase composition and microwave absorbing properties of as-prepared samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), vector network analyzer (VNA), and so on. The results revealed that the 3D network structure was configurated with smooth spherical walls composed of NiFe2O4 nanocrystals and their pore diameters being in the range of 80-250 nm. The microwave absorption properties of the 3D network structure NiFe2O4 were crucially determined by the special structure. The synergy of intrinsic magnetic loss of magnetic NiFe2O4 and the interfacial polarization enhanced by 3D network structure and the interaction of multiple mechanisms endowed the sample with the feature of strong absorption, broad bandwidth and lightweight. There is more than one valley in the reflection loss curves and the maximum reflection loss is 27.5 dB with a bandwidth of 4 GHz. Moreover, the 3D network structure NiFe2O4 show a greater reflection loss with the same thickness comparing to the ordinary NiFe2O4 nanoparticles, which could achieve the feature of lightweight of the microwave absorbing materials.

Lightweight NiFe2O4 with controllable 3D network structure and enhanced microwave absorbing properties

PubMed Central

Wang, Fen; Wang, Xing; Zhu, Jianfeng; Yang, Haibo; Kong, Xingang; Liu, Xiao

2016-01-01

3D network structure NiFe2O4 was successfully synthesized by a templated salt precipitation method using PMMA colloid crystal as templates. The morphology, phase composition and microwave absorbing properties of as-prepared samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), vector network analyzer (VNA), and so on. The results revealed that the 3D network structure was configurated with smooth spherical walls composed of NiFe2O4 nanocrystals and their pore diameters being in the range of 80–250 nm. The microwave absorption properties of the 3D network structure NiFe2O4 were crucially determined by the special structure. The synergy of intrinsic magnetic loss of magnetic NiFe2O4 and the interfacial polarization enhanced by 3D network structure and the interaction of multiple mechanisms endowed the sample with the feature of strong absorption, broad bandwidth and lightweight. There is more than one valley in the reflection loss curves and the maximum reflection loss is 27.5 dB with a bandwidth of 4 GHz. Moreover, the 3D network structure NiFe2O4 show a greater reflection loss with the same thickness comparing to the ordinary NiFe2O4 nanoparticles, which could achieve the feature of lightweight of the microwave absorbing materials. PMID:27897209

Spectroscopic Confirmation of Five Galaxy Clusters at z > 1.25 in the 2500 deg^2 SPT-SZ Survey

NASA Astrophysics Data System (ADS)

Khullar, Gourav; Bleem, Lindsey; Bayliss, Matthew; Gladders, Michael; South Pole Telescope (SPT) Collaboration

2018-06-01

We present spectroscopic confirmation of 5 galaxy clusters at 1.25 < z < 1.5, discovered in the 2500 deg2 South Pole Telescope Sunyaev-Zel’dovich (SPT-SZ) survey. These clusters, taken from a nearly redshift-independent mass-limited sample of clusters, have multi-wavelength follow-up imaging data from the X-ray to the near-IR, and currently form the most homogenous massive high-redshift cluster sample in existence. We briefly describe the analysis pipeline used on the low S/N spectra of these faint galaxies, and describing the multiple techniques used to extract robust redshifts from a combination of absorption-line (Ca II H&K doublet - λλ3934,3968Å) and emission-line ([OII] λλ3727,3729Å) spectral features. We present several ensemble analyses of cluster member galaxies that demonstrate the reliability of the measured redshifts. We also identify modest [OII] emission and pronounced CN and Hδ absorption in a composite stacked spectrum of 28 low S/N passive galaxy spectra with redshifts derived primarily from Ca II H&K features. This work increases the number of spectroscopically-confirmed SPT-SZ galaxy clusters at z > 1.25 from 2 to 7, further demonstrating the efficacy of SZ selection for the highest redshift massive clusters, and enabling further detailed study of these confirmed systems.

Correlation-driven charge migration following double ionization and attosecond transient absorption spectroscopy

NASA Astrophysics Data System (ADS)

Hollstein, Maximilian; Santra, Robin; Pfannkuche, Daniela

2017-05-01

We theoretically investigate charge migration following prompt double ionization. Thereby, we extend the concept of correlation-driven charge migration, which was introduced by Cederbaum and coworkers for single ionization [Chem. Phys. Lett. 307, 205 (1999), 10.1016/S0009-2614(99)00508-4], to doubly ionized molecules. This allows us to demonstrate that compared to singly ionized molecules, in multiply ionized molecules, electron dynamics originating from electronic relaxation and correlation are particularly prominent. In addition, we also discuss how these correlation-driven electron dynamics might be evidenced and traced experimentally using attosecond transient absorption spectroscopy. For this purpose, we determine the time-resolved absorption cross section and find that the correlated electron dynamics discussed are reflected in it with exceptionally great detail. Strikingly, we find that features in the cross section can be traced back to electron hole populations and time-dependent partial charges and hence, can be interpreted with surprising ease. By taking advantage of element-specific core-to-valence transitions even atomic spatial resolution can be achieved. Thus, with the theoretical considerations presented, not only do we predict particularly diverse and correlated electron dynamics in molecules to follow prompt multiple ionization but we also identify a promising route towards their experimental investigation.

Uncovering the Terahertz Spectrum of Copper Sulfate Pentahydrate.

PubMed

Ruggiero, Michael T; Korter, Timothy M

2016-01-21

Terahertz vibrational spectroscopy has evolved into a powerful tool for the detection and characterization of transition metal sulfate compounds, specifically for its ability to differentiate between various hydrated forms with high specificity. Copper(II) sulfate is one such system where multiple crystalline hydrates have had their terahertz spectra fully assigned, and the unique spectral fingerprints of the forms allows for characterization of multicomponent systems with relative ease. Yet the most commonly occurring form, copper(II) sulfate pentahydrate (CuSO4·5H2O), has proven elusive due to the presence of a broad absorption across much of the terahertz region, making the unambiguous identification of its spectral signature difficult. Here, it is shown that the sub-100 cm(-1) spectrum of CuSO4·5H2O is obscured by absorption from adsorbed water and that controlled drying reveals sharp underlying features. The crystalline composition of the samples was monitored in parallel by X-ray diffraction as a function of drying time, supporting the spectroscopic results. Finally, the terahertz spectrum of CuSO4·5H2O was fully assigned using solid-state density functional theory simulations, helping attribute the additional absorptions that appear after excessive drying to formation of CuSO4·3H2O.

Ferric iron in primitive asteroids - A 0.43-micron absorption feature

NASA Technical Reports Server (NTRS)

Vilas, Faith; Hatch, Erin C.; Larson, Stephen M.; Sawyer, Scott R.; Gaffey, Michael J.

1993-01-01

A search of reflectance spectra of C- P-, D- and S-class asteroids to hunt for the Soret band near 0.4 micron that is indicative of porphyrins yielded an identification of an 0.43 micron absorption feature in 11 primitive asteroids of the C, P, and G classes and in one S-class asteroid. It is proposed that the feature is an Fe(3+) spin-forbidden transition in aqueously altered material, possibly located near 0.43 micron due to an enhancement effect similar to the mechanism operating in jarosite. The significance of the feature for the aqueous alteration history of these asteroids is addressed.

Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite: II. XANES analysis and simulation

USGS Publications Warehouse

Waychunas, G.A.; Fuller, C.C.; Davis, J.A.; Rehr, J.J.

2003-01-01

X-ray absorption near-edge spectroscopy (XANES) analysis of sorption complexes has the advantages of high sensitivity (10- to 20-fold greater than extended X-ray absorption fine structure [EXAFS] analysis) and relative ease and speed of data collection (because of the short k-space range). It is thus a potentially powerful tool for characterization of environmentally significant surface complexes and precipitates at very low surface coverages. However, quantitative analysis has been limited largely to "fingerprint" comparison with model spectra because of the difficulty of obtaining accurate multiple-scattering amplitudes for small clusters with high confidence. In the present work, calculations of the XANES for 50- to 200-atom clusters of structure from Zn model compounds using the full multiple-scattering code Feff 8.0 accurately replicate experimental spectra and display features characteristic of specific first-neighbor anion coordination geometry and second-neighbor cation geometry and number. Analogous calculations of the XANES for small molecular clusters indicative of precipitation and sorption geometries for aqueous Zn on ferrihydrite, and suggested by EXAFS analysis, are in good agreement with observed spectral trends with sample composition, with Zn-oxygen coordination and with changes in second-neighbor cation coordination as a function of sorption coverage. Empirical analysis of experimental XANES features further verifies the validity of the calculations. The findings agree well with a complete EXAFS analysis previously reported for the same sample set, namely, that octahedrally coordinated aqueous Zn2+ species sorb as a tetrahedral complex on ferrihydrite with varying local geometry depending on sorption density. At significantly higher densities but below those at which Zn hydroxide is expected to precipitate, a mainly octahedral coordinated Zn2+ precipitate is observed. An analysis of the multiple scattering paths contributing to the XANES demonstrates the importance of scattering paths involving the anion sublattice. We also describe the specific advantages of complementary quantitative XANES and EXAFS analysis and estimate limits on the extent of structural information obtainable from XANES analysis. ?? 2003 Elsevier Science Ltd.

Preliminary results from an investigation of AIS-1 data over an area of epithermal alteration: Plateau, Northern Queensland, Australia

NASA Technical Reports Server (NTRS)

Mackin, Steve; Munday, Tim; Hook, Simon

1987-01-01

Airborne Imaging Spectrometer-1 (AIS-1) data were flown over undifferentiated sequences of acid to intermediate volcanics and intrusives; meta-sediments; and a series of partially lateritized sedimentary rocks. The area exhibits a considerable spectral variability, after the suppression of striping effects. Log residual, and Internal Average Relative Reflectance (IARR) analytical techniques were used to enhance mineralogically related spectral features. Both methods produce similar results, but did not visually highlight mineral absorption features due to processing artifacts in areas of significant vegetation cover. The enhancement of mineral related absorption features was achieved using a hybrid processing approach based on the relative reflectance differences between vegetated and non-vegetated surfaces at 1.2 and 2.1 micron. The result is an image with little overall contrast, but which enhances the more subtle spectral features believed to be associated with clays and epidote. The AIS data was subject to interactive analysis using SPAM. Clear separation of clay and epidote related absorption features was apparent, and the identification of kaolinite was possible despite detrimental spectral effects.

Line Identifications in the Far Ultraviolet Spectrum of the Eclipsing Binary System 31 Cygni

NASA Astrophysics Data System (ADS)

Hagen Bauer, Wendy; Bennett, P. D.

2011-05-01

The eclipsing binary system 31 Cygni (K4 Ib + B3 V) was observed at several phases with the Far Ultraviolet Spectrosocopic Explorer (FUSE) satellite. During total eclipse, a rich emission spectrum was observed, produced by scattering of hot star photons in the extended wind of the K supergiant. The system was observed during deep chromospheric eclipse, and 2.5 months after total eclipse ended. We present an atlas of line identifications in these spectra. During total eclipse, emission features from C II , C III, N I, N II, N III, O I, Si II, P II, P III, S II, S III, Ar I, Cr III, Fe II, Fe III, and Ni II were detected. The strongest emission features arise from N II. These lines appear strongly in absorption during chromospheric eclipse, and even 2.5 months after total eclipse, the absorption bottoms out on the underlying emission seen during total eclipse. The second strongest features in the emission spectrum arise from Fe III. Any chromospheric Fe III absorption is buried within strong chromospheric absorption from other species, mainly Fe II. The emission profiles of most of the doubly-ionized species are red-shifted relative to the systemic velocity, with asymmetric profiles with a steeper long-wavelength edge. Emission profiles from singly-ionized species tend to be more symmetric and centered near the systemic velocity. In deep chromospheric eclipse, absorption features are seen from neutral and singly-ionized species, arising from lower levels up to 3 eV. Many strong chromospheric features are doubled in the observation obtained during egress from eclipse. The 31 Cygni spectrum taken 2.5 months after total eclipse ended ws compared to single-star B spectra from the FUSE archives. There was still some additional chromospheric absorption from strong low-excitation Fe II, O I and Ar I.

Aliphatic Hydrocarbon Content of Interstellar Dust

NASA Astrophysics Data System (ADS)

Günay, B.; Schmidt, T. W.; Burton, M. G.; Afşar, M.; Krechkivska, O.; Nauta, K.; Kable, S. H.; Rawal, A.

2018-06-01

There is considerable uncertainty as to the amount of carbon incorporated in interstellar dust. The aliphatic component of the carbonaceous dust is of particular interest because it produces a significant 3.4 μm absorption feature when viewed against a background radiation source. The optical depth of the 3.4 μm absorption feature is related to the number of aliphatic carbon C-H bonds along the line of sight. It is possible to estimate the column density of carbon locked up in the aliphatic hydrocarbon component of interstellar dust from quantitative analysis of the 3.4 μm interstellar absorption feature providing that the absorption coefficient of aliphatic hydrocarbons incorporated in the interstellar dust is known. We report laboratory analogues of interstellar dust by experimentally mimicking interstellar/circumstellar conditions. The resultant spectra of these dust analogues closely match those from astronomical observations. Measurements of the absorption coefficient of aliphatic hydrocarbons incorporated in the analogues were carried out by a procedure combining FTIR and 13C NMR spectroscopies. The absorption coefficients obtained for both interstellar analogues were found to be in close agreement (4.76(8) × 10-18 cm group-1 and 4.69(14) × 10-18 cm group-1), less than half those obtained in studies using small aliphatic molecules. The results thus obtained permit direct calibration of the astronomical observations, providing rigorous estimates of the amount of aliphatic carbon in the interstellar medium.

Multiple-scattering coefficients and absorption controlled diffusive processes

NASA Astrophysics Data System (ADS)

Godoy, Salvador; García-Colín, L. S.; Micenmacher, Victor

1999-11-01

Multiple-scattering transmission and reflection coefficients (T,R) are introduced in addition to the diffusion coefficient D for the description of ballistic diffusion in the presence of absorption. For 1D (one-dimensional) systems, the measurement of only one between T and D imposes restrictions on the possible values of the other. If D is measured, then T is bounded between the Landauer and Lambert-Beer equations. Measurements of both (T,D) imply the theoretical knowledge of the microscopic absorption Σa and scattering rΣs cross sections.

"CHON" particles: The interstellar component of cometary dust

NASA Technical Reports Server (NTRS)

Lien, David J.

1998-01-01

Interstellar dust is characterized by strong absorption in the ultraviolet and the mid-IR. Current models of interstellar dust are based on three chemically distinct components: a form of carbon (usually graphite), a silicate, and a blend of polycyclic aromatic hydrocarbons or other carbonaceous material. Previous work using effective medium theories to understand the optical properties of cometary dust suggested that an amalgam of materials could reproduce the observed interstellar and cometary dust features. Recently, Lawler and Brownlee (1992) re-analyzed the PIA and PUMA-1 data sets from the Giotto flyby of P/Halley and discovered that the so-called "CHON" particles were actually composed of a blend of carbon-bearing and silicon-bearing materials. Based on effective medium theories, the absorption spectrum of such a material would display the spectral features of each of the components - strong UV absorption from the carbonaceous component and strong absorption in the IR from the silicate component. To test this idea, vapor-deposited samples were created using two different deposition techniques: sputtering with an argon RF magnetron and deposition from an argon plasma torch. Two different compositions were tested: a blend of graphite and silica in a 7:1 ratio and an amalgam of materials whose approximate composition matches the "CHON"-silicate abundances for the uncompressed PIA data set of Lawler and Brownlee: graphite, iron oxide, magnesium oxide, ammonium sulfate, calcium carbonate, and silica in mass ratios of 6:4.3:4:2.2:1:9. The samples were finely ground and pressed into 2" diameter disks using a 40 ton press. In all, four different experiments were performed: one with each of the compositions (C:SiO and "CHON") in both the RF magnetron and the plasma torch chambers. The RF magnetron created a uniform dark thin film on the substrate surface, and the plasma torch created a coating of small (<100 micron) diameter grey particles. The spectra of all four samples show a strong, broad absorption feature at around 220 nm as well as a strong but narrower absorption peak near 10 microns. The RF magnetron sputtered samples showed some sub-structure in the UV, and the peak of the absorption was shifted toward longer wavelengths. The UV absorption in the plasma torch deposited samples have no sub-structure, and the peak absorption is very near 220 nm. Strong absorption near 9 microns is seen in the spectra from both sample preparation techniques, and is consistent with the IR spectra of some terrestrial silicates. Other features, particularly at 6.2 and 8.6 microns, are seen in the interstellar medium. A strong feature near 2 microns is due to absorbed water in the sample. Based on the results of these experiments, there is evidence that a material with a composition similar to that detected in "CHON" particles in the coma of P/Halley have a spectral signature which reproduces the main absorption features of interstellar dust. This suggests that the "CHON" particles could be the interstellar component of cometary dust.

Imaging multi-scale dynamics in vivo with spiral volumetric optoacoustic tomography

NASA Astrophysics Data System (ADS)

Deán-Ben, X. Luís.; Fehm, Thomas F.; Ford, Steven J.; Gottschalk, Sven; Razansky, Daniel

2017-03-01

Imaging dynamics in living organisms is essential for the understanding of biological complexity. While multiple imaging modalities are often required to cover both microscopic and macroscopic spatial scales, dynamic phenomena may also extend over different temporal scales, necessitating the use of different imaging technologies based on the trade-off between temporal resolution and effective field of view. Optoacoustic (photoacoustic) imaging has been shown to offer the exclusive capability to link multiple spatial scales ranging from organelles to entire organs of small animals. Yet, efficient visualization of multi-scale dynamics remained difficult with state-of-the-art systems due to inefficient trade-offs between image acquisition and effective field of view. Herein, we introduce a spiral volumetric optoacoustic tomography (SVOT) technique that provides spectrally-enriched high-resolution optical absorption contrast across multiple spatio-temporal scales. We demonstrate that SVOT can be used to monitor various in vivo dynamics, from video-rate volumetric visualization of cardiac-associated motion in whole organs to high-resolution imaging of pharmacokinetics in larger regions. The multi-scale dynamic imaging capability thus emerges as a powerful and unique feature of the optoacoustic technology that adds to the multiple advantages of this technology for structural, functional and molecular imaging.

Airborne imaging spectrometer data of the Ruby Mountains, Montana: Mineral discrimination using relative absorption band-depth images

USGS Publications Warehouse

Crowley, J.K.; Brickey, D.W.; Rowan, L.C.

1989-01-01

Airborne imaging spectrometer data collected in the near-infrared (1.2-2.4 ??m) wavelength range were used to study the spectral expression of metamorphic minerals and rocks in the Ruby Mountains of southwestern Montana. The data were analyzed by using a new data enhancement procedure-the construction of relative absorption band-depth (RBD) images. RBD images, like bandratio images, are designed to detect diagnostic mineral absorption features, while minimizing reflectance variations related to topographic slope and albedo differences. To produce an RBD image, several data channels near an absorption band shoulder are summed and then divided by the sum of several channels located near the band minimum. RBD images are both highly specific and sensitive to the presence of particular mineral absorption features. Further, the technique does not distort or subdue spectral features as sometimes occurs when using other data normalization methods. By using RBD images, a number of rock and soil units were distinguished in the Ruby Mountains including weathered quartz - feldspar pegmatites, marbles of several compositions, and soils developed over poorly exposed mica schists. The RBD technique is especially well suited for detecting weak near-infrared spectral features produced by soils, which may permit improved mapping of subtle lithologic and structural details in semiarid terrains. The observation of soils rich in talc, an important industrial commodity in the study area, also indicates that RBD images may be useful for mineral exploration. ?? 1989.

Exocomet Orbit Fitting: Accelerating Coma Absorption During Transits of β Pictoris

NASA Astrophysics Data System (ADS)

Kennedy, Grant M.

2018-06-01

Comets are a remarkable feature in our night sky, visible on their passage through the inner Solar system as the Sun's energy sublimates ices and liberates surface material, generating beautiful comae, dust, and ion tails. Comets are also thought to orbit other stars, and are the most promising interpretation of sporadic absorption features (i.e. transits) seen in spectra of stars such as β Pictoris and 49 Ceti. These "exocomets" are thought to form and evolve in the same way as in the Solar system, and as in the Solar system we may gain insight into their origins by deriving their orbits. In the case of β Pictoris, orbits have been estimated indirectly, using the radial velocity of the absorption features coupled with a physical evaporation model to estimate the stellocentric distance at transit dtr. Here, we note that the inferred dtr imply that some absorption signatures should accelerate over several hours, and show that this acceleration is indeed seen in HARPS spectra. This new constraint means that orbital characteristics can be obtained directly, and the pericentre distance and longitude constrained when parabolic orbits are assumed. The results from fitting orbits to 12 accelerating features, and a handful of non-accelerating ones, are in broad agreement with previous estimates based on an evaporation model, thereby providing some validation of the exocomet hypothesis. A prediction of the evaporation model, that coma absorption is deeper for more distant transits, is also seen here.

Drug Delivery and Transport into the Central Circulation: An Example of Zero-Order In vivo Absorption of Rotigotine from a Transdermal Patch Formulation.

PubMed

Cawello, Willi; Braun, Marina; Andreas, Jens-Otto

2018-01-13

Pharmacokinetic studies using deconvolution methods and non-compartmental analysis to model clinical absorption of drugs are not well represented in the literature. The purpose of this research was (1) to define the system of equations for description of rotigotine (a dopamine receptor agonist delivered via a transdermal patch) absorption based on a pharmacokinetic model and (2) to describe the kinetics of rotigotine disposition after single and multiple dosing. The kinetics of drug disposition was evaluated based on rotigotine plasma concentration data from three phase 1 trials. In two trials, rotigotine was administered via a single patch over 24 h in healthy subjects. In a third trial, rotigotine was administered once daily over 1 month in subjects with early-stage Parkinson's disease (PD). A pharmacokinetic model utilizing deconvolution methods was developed to describe the relationship between drug release from the patch and plasma concentrations. Plasma-concentration over time profiles were modeled based on a one-compartment model with a time lag, a zero-order input (describing a constant absorption via skin into central circulation) and first-order elimination. Corresponding mathematical models for single- and multiple-dose administration were developed. After single-dose administration of rotigotine patches (using 2, 4 or 8 mg/day) in healthy subjects, a constant in vivo absorption was present after a minor time lag (2-3 h). On days 27 and 30 of the multiple-dose study in patients with PD, absorption was constant during patch-on periods and resembled zero-order kinetics. Deconvolution based on rotigotine pharmacokinetic profiles after single- or multiple-dose administration of the once-daily patch demonstrated that in vivo absorption of rotigotine showed constant input through the skin into the central circulation (resembling zero-order kinetics). Continuous absorption through the skin is a basis for stable drug exposure.

Multiple-wavelength neutron holography with pulsed neutrons

PubMed Central

Hayashi, Kouichi; Ohoyama, Kenji; Happo, Naohisa; Matsushita, Tomohiro; Hosokawa, Shinya; Harada, Masahide; Inamura, Yasuhiro; Nitani, Hiroaki; Shishido, Toetsu; Yubuta, Kunio

2017-01-01

Local structures around impurities in solids provide important information for understanding the mechanisms of material functions, because most of them are controlled by dopants. For this purpose, the x-ray absorption fine structure method, which provides radial distribution functions around specific elements, is most widely used. However, a similar method using neutron techniques has not yet been developed. If one can establish a method of local structural analysis with neutrons, then a new frontier of materials science can be explored owing to the specific nature of neutron scattering—that is, its high sensitivity to light elements and magnetic moments. Multiple-wavelength neutron holography using the time-of-flight technique with pulsed neutrons has great potential to realize this. We demonstrated multiple-wavelength neutron holography using a Eu-doped CaF2 single crystal and obtained a clear three-dimensional atomic image around trivalent Eu substituted for divalent Ca, revealing an interesting feature of the local structure that allows it to maintain charge neutrality. The new holography technique is expected to provide new information on local structures using the neutron technique. PMID:28835917

Multiple-wavelength neutron holography with pulsed neutrons.

PubMed

Hayashi, Kouichi; Ohoyama, Kenji; Happo, Naohisa; Matsushita, Tomohiro; Hosokawa, Shinya; Harada, Masahide; Inamura, Yasuhiro; Nitani, Hiroaki; Shishido, Toetsu; Yubuta, Kunio

2017-08-01

Local structures around impurities in solids provide important information for understanding the mechanisms of material functions, because most of them are controlled by dopants. For this purpose, the x-ray absorption fine structure method, which provides radial distribution functions around specific elements, is most widely used. However, a similar method using neutron techniques has not yet been developed. If one can establish a method of local structural analysis with neutrons, then a new frontier of materials science can be explored owing to the specific nature of neutron scattering-that is, its high sensitivity to light elements and magnetic moments. Multiple-wavelength neutron holography using the time-of-flight technique with pulsed neutrons has great potential to realize this. We demonstrated multiple-wavelength neutron holography using a Eu-doped CaF 2 single crystal and obtained a clear three-dimensional atomic image around trivalent Eu substituted for divalent Ca, revealing an interesting feature of the local structure that allows it to maintain charge neutrality. The new holography technique is expected to provide new information on local structures using the neutron technique.

Electrowetting retroreflectors: Scalable and wide-spectrum modulation between corner cube and scattering reflection

NASA Astrophysics Data System (ADS)

Kilaru, M. K.; Cumby, B.; Heikenfeld, J.

2009-01-01

Corner cube and spherical retroreflectors are ubiquitous in conspicuity and range-finding applications since they reflect light back to the illumination source with unmatched efficiency. We report here a switchable electrowetting retroreflector platform that provides multiple novel features, including (a) using <0.5 μJ/cm2 electrical energy to switch from a light scattering state, (b) low loss and wide spectrum as limited only by the absorption spectrum of water, (c) use of ultrasimple self-assembly of 103-105 liquid lenslets/in.2 on a polymer/Al corner-cube substrate, and (d) change in retroreflected irradiance of >10:1 over a ±30° field of view.

Feature-based and statistical methods for analyzing the Deepwater Horizon oil spill with AVIRIS imagery

USGS Publications Warehouse

Rand, R.S.; Clark, R.N.; Livo, K.E.

2011-01-01

The Deepwater Horizon oil spill covered a very large geographical area in the Gulf of Mexico creating potentially serious environmental impacts on both marine life and the coastal shorelines. Knowing the oil's areal extent and thickness as well as denoting different categories of the oil's physical state is important for assessing these impacts. High spectral resolution data in hyperspectral imagery (HSI) sensors such as Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) provide a valuable source of information that can be used for analysis by semi-automatic methods for tracking an oil spill's areal extent, oil thickness, and oil categories. However, the spectral behavior of oil in water is inherently a highly non-linear and variable phenomenon that changes depending on oil thickness and oil/water ratios. For certain oil thicknesses there are well-defined absorption features, whereas for very thin films sometimes there are almost no observable features. Feature-based imaging spectroscopy methods are particularly effective at classifying materials that exhibit specific well-defined spectral absorption features. Statistical methods are effective at classifying materials with spectra that exhibit a considerable amount of variability and that do not necessarily exhibit well-defined spectral absorption features. This study investigates feature-based and statistical methods for analyzing oil spills using hyperspectral imagery. The appropriate use of each approach is investigated and a combined feature-based and statistical method is proposed.

Interplay of Collective Excitations in Quantum Well Intersubband Resonances

NASA Technical Reports Server (NTRS)

Li, Jian-Zhong; Ning, C. Z.

2003-01-01

Intersubband resonances in a semiconductor quantum well (QW) display some of the most fascinating features involving various collective excitations such as Fermi-edge singularity (FES) and intersubband plasmon (ISP). Using a density matrix approach, we treated many-body effects such as depolarization, vertex correction, and self-energy consistently for a two-subband system. We found a systematic change in resonance spectra from FES-dominated to ISP-dominated features, as QW- width or electron density is varied. Such an interplay between FES and ISP significantly changes both line shape and peak position of the absorption spectrum. In particular, we found that a cancellation of FES and ISP undresses the resonant responses and recovers the single-particle features of absorption for semiconductors with a strong nonparabolicity such as InAs, leading to a dramatic broadening of the absorption spectrum.

On Local Ionization Equilibrium and Disk Winds in QSOs

NASA Astrophysics Data System (ADS)

Pereyra, Nicolas A.

2014-11-01

We present theoretical C IV λλ1548,1550 absorption line profiles for QSOs calculated assuming the accretion disk wind (ADW) scenario. The results suggest that the multiple absorption troughs seen in many QSOs may be due to the discontinuities in the ion balance of the wind (caused by X-rays), rather than discontinuities in the density/velocity structure. The profiles are calculated from a 2.5-dimensional time-dependent hydrodynamic simulation of a line-driven disk wind for a typical QSO black hole mass, a typical QSO luminosity, and for a standard Shakura-Sunyaev disk. We include the effects of ionizing X-rays originating from within the inner disk radius by assuming that the wind is shielded from the X-rays from a certain viewing angle up to 90° ("edge on"). In the shielded region, we assume constant ionization equilibrium, and thus constant line-force parameters. In the non-shielded region, we assume that both the line-force and the C IV populations are nonexistent. The model can account for P-Cygni absorption troughs (produced at edge on viewing angles), multiple absorption troughs (produced at viewing angles close to the angle that separates the shielded region and the non-shielded region), and for detached absorption troughs (produced at an angle in between the first two absorption line types); that is, the model can account for the general types of broad absorption lines seen in QSOs as a viewing angle effect. The steady nature of ADWs, in turn, may account for the steady nature of the absorption structure observed in multiple-trough broad absorption line QSOs. The model parameters are M bh = 109 M ⊙ and L disk = 1047 erg s-1.

X-Ray Absorption Near Edge Structure And Extended X-Ray Absorption Fine Structure Analysis of Standards And Biological Samples Containing Mixed Oxidation States of Chromium(III) And Chromium(VI)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parsons, J.G.; Dokken, K.; Peralta-Videa, J.R.

For the first time a method has been developed for the extended X-ray absorption fine structure (EXAFS) data analyses of biological samples containing multiple oxidation states of chromium. In this study, the first shell coordination and interatomic distances based on the data analysis of known standards of potassium chromate (Cr(VI)) and chromium nitrate hexahydrate (Cr(III)) were investigated. The standards examined were mixtures of the following molar ratios of Cr(VI):Cr(III), 0:1, 0.25:0.75, 0.5:0.5, 0.75:0.25, and 1:0. It was determined from the calibration data that the fitting error associated with linear combination X-ray absorption near edge structure (LC-XANES) fittings was approximately {+-}10%more » of the total fitting. The peak height of the Cr(VI) pre-edge feature after normalization of the X-ray absorption (XAS) spectra was used to prepare a calibration curve. The EXAFS fittings of the standards were also investigated and fittings to lechuguilla biomass samples laden with different ratios of Cr(III) and Cr(VI) were performed as well. An excellent agreement between the XANES data and the data presented in the EXAFS spectra was observed. The EXFAS data also presented mean coordination numbers directly related to the ratios of the different chromium oxidation states in the sample. The chromium oxygen interactions had two different bond lengths at approximately 1.68 and 1.98 {angstrom} for the Cr(VI) and Cr(III) in the sample, respectively.« less

Electronic and nuclear contributions to time-resolved optical and X-ray absorption spectra of hematite and insights into photoelectrochemical performance

DOE PAGES

Hayes, Dugan; Hadt, Ryan G.; Emery, Jonathan D.; ...

2016-11-02

Ultrafast time-resolved studies of photocatalytic thin films can provide a wealth of information crucial for understanding and thereby improving the performance of these materials by directly probing electronic structure, reaction intermediates, and charge carrier dynamics. The interpretation of transient spectra, however, can be complicated by thermally induced structural distortions, which appear within the first few picoseconds following excitation due to carrier–phonon scattering. Here we present a comparison of ex situ steady-state thermal difference spectra and transient absorption spectra spanning from NIR to hard X-ray energies of hematite thin films grown by atomic layer deposition. We find that beyond the firstmore » 100 picoseconds, the transient spectra measured for all excitation wavelengths and probe energies are almost entirely due to thermal effects as the lattice expands in response to the ultrafast temperature jump and then cools to room temperature on the microsecond timescale. At earlier times, a broad excited state absorption band that is assigned to free carriers appears at 675 nm, and the lifetime and shape of this feature also appear to be mostly independent of excitation wavelength. The combined spectroscopic data, which are modeled with density functional theory and full multiple scattering calculations, support an assignment of the optical absorption spectrum of hematite that involves two LMCT bands that nearly span the visible spectrum. Lastly, our results also suggest a framework for shifting the ligand-to-metal charge transfer absorption bands of ferric oxide films from the near-UV further into the visible part of the solar spectrum to improve solar conversion efficiency.« less

Thermal infrared spectroscopy and modeling of experimentally shocked plagioclase feldspars

USGS Publications Warehouse

Johnson, J. R.; Horz, F.; Staid, M.I.

2003-01-01

Thermal infrared emission and reflectance spectra (250-1400 cm-1; ???7???40 ??m) of experimentally shocked albite- and anorthite-rich rocks (17-56 GPa) demonstrate that plagioclase feldspars exhibit characteristic degradations in spectral features with increasing pressure. New measurements of albite (Ab98) presented here display major spectral absorptions between 1000-1250 cm-1 (8-10 ??m) (due to Si-O antisymmetric stretch motions of the silica tetrahedra) and weaker absorptions between 350-700 cm-1 (14-29 ??m) (due to Si-O-Si octahedral bending vibrations). Many of these features persist to higher pressures compared to similar features in measurements of shocked anorthite, consistent with previous thermal infrared absorption studies of shocked feldspars. A transparency feature at 855 cm-1 (11.7 ??m) observed in powdered albite spectra also degrades with increasing pressure, similar to the 830 cm-1 (12.0 ??m) transparency feature in spectra of powders of shocked anorthite. Linear deconvolution models demonstrate that combinations of common mineral and glass spectra can replicate the spectra of shocked anorthite relatively well until shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation. Albite deconvolutions exhibit higher errors overall but do not change significantly with pressure, likely because certain clay minerals selected by the model exhibit absorption features similar to those in highly shocked albite. The implication for deconvolution of thermal infrared spectra of planetary surfaces (or laboratory spectra of samples) is that the use of highly shocked anorthite spectra in end-member libraries could be helpful in identifying highly shocked calcic plagioclase feldspars.

Iron alteration minerals in the visible and near-infrared spectra of low-albedo asteroids

NASA Technical Reports Server (NTRS)

Vilas, Faith; Jarvis, Kandy S.; Gaffey, Michael J.

1994-01-01

Absorption features centered near 0.60-0.65 and 0.80-0.90 micrometers have been identified in the spectra of five low-albedo main-belt and outer-belt asteroids. These absorption features are attributed respectively to the (6)A(sub 1) goes to (4)T(sub 2)(G) and (6)A(sub 1) goes to (4)T(sub 1)(G) charge transfer transitions in minerals such as goethite, hematite, and jarosite that are products of the aqueous alteration of anhydrous silicates. A shoulder near 0.63 micrometers has also been identified in the absorption feature centered near 0.7 micrometers attributed to oxidized iron in phyllosilicates found predominantly in C- and G-class asteroids reflectance spectra. The coexistence of iron oxides with phyllosilicates in asteroids believed to have undergone aqueous alteration would be expected based upon analogy with terrestrial aqueous alteration and the observed mineralogy of carbonaceous chondrites. The number of low-albedo asteroids having only iron alteration absorption features compared to the number of low-albedo asteroids having spectral characteristics indicative of phyllosilicates is small. Either the conditions under which these asteroids formed are rare, or the iron alteration minerals could be formed in the interiors of objects where phyllosilicates dominate the surface mineralogy.

GHRS observations of cool, low-gravity star. 2: Flow and turbulent velocities in the outer atmosphere of gamma CRU CIS (M3.4 III)

NASA Technical Reports Server (NTRS)

Carpenter, Kenneth G.; Robinson, Richard D.; Judge, Philip G.

1995-01-01

The Goddard High Resoulution Spectrograph (GHRS) on the Hubble Space Telescope (HST) has been used to obtain medium (R = 20,000) and high (R = 85,000) resoultion UV spectra of chromosphere emission features for the M3.4 III star gamma Cru. Small Science Aperture (SSA) G270M and Echelle-B spectra of selected regions in the 2300-2850 A range were obtained to determine the kinematics of the chromosphere using lines of C2), Fe2, Co2, Si1/2), Ni2, Mn2, and Mg2. Profiles of C2) (UV 0.01) lines and fluorescently excited lines of low optical depth indicate average turbulent velocities (Doppler FWHM) of 30.2 +/- 1.3 and 28.8 +/- 1.3 km/s, respectively. The fluorescent emission lines (mean RV = 21.3 +/- 0.9 km/s) and the wings of the emission components of Fe2 lines (mean RV = 22.8 +/- 0.4 km/s) are approximately at rest relative to the radial velocity of the star (21 km/s), while the C2) lines show a modest inflow (mean RV = 23.1 +/- 0.9 km/s). The more opaque lines of Fe2 and Mg2 exhibit complex profiles resulting from line formation in an optically thick, extended expanding atmosphere. The emission wings of these lines are broadened by multiple scattering, and they are centered near the photospheric radial velocity. Closer to line center, these strong lines show a strong blueshifted self-absorption feature (already seen in IUE data), indicative of formation in an expanding chromosphere, and a previously unseen dip in the profiles on the red side of line center. The absorption components, when extracted using simple Gaussian fits, show strong correlations with the relative optical depths of the lines. The derived absorption flow velocities converge to the photospheric velocity as one examines spectra features formed deeper in the atmosphere. The blueward abosrption velocity increases in magnitude from about 7 to 14 km/s with increasing line optical depth - the strong absorptions directly map the acceleration of the outflowing stellar wind, while the interpretation of the weaker redshifted abosrptions is more ambiguous, indicating either an inflow of material or formation in an extended, spherically expanding outflow. The Mg2 and Fe2 profiles, taken together, imply that the wind speed decreases between the atmospheric layers where the Mg2 and Fe2 self-absorption components are formed. Interstellar absorptions are seen in the resonance lines of Mg2 (UV 1) and Fe2 (UV1) with zero-volt lower levels, at about -3 km/s, consistent with models of the interstellar medium in the direction of gamma Cru. Finally, we have detected the Mg2 'satellite lines' seen in solar spectra obtained above the limb. In gamma Cru these lines are probably fluorescently excited by H Ly beta.

Measurements of reflectance spectra of ion-bombarded ice and application to surfaces in the outer solar system

NASA Technical Reports Server (NTRS)

O'Shaughnessy, D. J.; Boring, J. W.; Johnson, R. E.

1988-01-01

The first results of laboratory measurements of the wavelength dependence of the alternation of the visible reflectance of H2O ice irradiated by keV ions are presented. When the implanted species is chemically neutral, absorption is slightly enhanced below 0.55 micron. For an incident species containing sulfur, a strong absorption feature is produced at 0.4 micron, probably corresponding to S3. This occurs at too large a wavelength to account for the absorption feature observed at Europa by Voyager and therefore casts doubt on the recent interpretation of the reflectance data of Europa.

Using principal component analysis to understand the variability of PDS 456

NASA Astrophysics Data System (ADS)

Parker, M. L.; Reeves, J. N.; Matzeu, G. A.; Buisson, D. J. K.; Fabian, A. C.

2018-02-01

We present a spectral-variability analysis of the low-redshift quasar PDS 456 using principal component analysis. In the XMM-Newton data, we find a strong peak in the first principal component at the energy of the Fe absorption line from the highly blueshifted outflow. This indicates that the absorption feature is more variable than the continuum, and that it is responding to the continuum. We find qualitatively different behaviour in the Suzaku data, which is dominated by changes in the column density of neutral absorption. In this case, we find no evidence of the absorption produced by the highly ionized gas being correlated with this variability. Additionally, we perform simulations of the source variability, and demonstrate that PCA can trivially distinguish between outflow variability correlated, anticorrelated and un-correlated with the continuum flux. Here, the observed anticorrelation between the absorption line equivalent width and the continuum flux may be due to the ionization of the wind responding to the continuum. Finally, we compare our results with those found in the narrow-line Seyfert 1 IRAS 13224-3809. We find that the Fe K UFO feature is sharper and more prominent in PDS 456, but that it lacks the lower energy features from lighter elements found in IRAS 13224-3809, presumably due to differences in ionization.

Ionized absorbers, ionized emitters, and the X-ray spectrum of active galactic nuclei

NASA Technical Reports Server (NTRS)

Netzer, Hagai

1993-01-01

Broad absorption features are common in the X-ray spectrum of low-luminosity AGNs. The features have been modeled by leaky neutral absorbers or by highly ionized gas that completely occult the continuum source. Such models are incomplete since they do not take into account all the physical processes in the gas. In particular, no previous model included the X-ray emission by the ionized absorbing gas and the reflection of the continuum source radiation. The present work discusses the emission, absorption, and reflection properties of photoionized gases with emphasis on conditions thought to prevail in AGNs. It shows that such gas is likely to produce intense X-ray line and continuum radiation and to reflect a sizable fraction of the nonstellar continuum at all energies. If such gas is indeed responsible for the observed X-ray absorption, then absorption edges are much weaker than commonly assumed, and some residual X-ray continuum is likely to be observed even if the line of sight is completely blocked. Moreover, X-ray emission features may show up in sources not showing X-ray absorption. This has immense consequences for medium-resolution X-ray missions, such as BBXRT and Astro-D, and for the planned high-resolution experiments on board XMM and AXAF.

Laser scanning cytometry for automation of the micronucleus assay

PubMed Central

Darzynkiewicz, Zbigniew; Smolewski, Piotr; Holden, Elena; Luther, Ed; Henriksen, Mel; François, Maxime; Leifert, Wayne; Fenech, Michael

2011-01-01

Laser scanning cytometry (LSC) provides a novel approach for automated scoring of micronuclei (MN) in different types of mammalian cells, serving as a biomarker of genotoxicity and mutagenicity. In this review, we discuss the advances to date in measuring MN in cell lines, buccal cells and erythrocytes, describe the advantages and outline potential challenges of this distinctive approach of analysis of nuclear anomalies. The use of multiple laser wavelengths in LSC and the high dynamic range of fluorescence and absorption detection allow simultaneous measurement of multiple cellular and nuclear features such as cytoplasmic area, nuclear area, DNA content and density of nuclei and MN, protein content and density of cytoplasm as well as other features using molecular probes. This high-content analysis approach allows the cells of interest to be identified (e.g. binucleated cells in cytokinesis-blocked cultures) and MN scored specifically in them. MN assays in cell lines (e.g. the CHO cell MN assay) using LSC are increasingly used in routine toxicology screening. More high-content MN assays and the expansion of MN analysis by LSC to other models (i.e. exfoliated cells, dermal cell models, etc.) hold great promise for robust and exciting developments in MN assay automation as a high-content high-throughput analysis procedure. PMID:21164197

Wavelength-selective mid-infrared metamaterial absorbers with multiple tungsten cross resonators.

PubMed

Li, Zhigang; Stan, Liliana; Czaplewski, David A; Yang, Xiaodong; Gao, Jie

2018-03-05

Wavelength-selective metamaterial absorbers in the mid-infrared range are demonstrated by using multiple tungsten cross resonators. By adjusting the geometrical parameters of cross resonators in single-sized unit cells, near-perfect absorption with single absorption peak tunable from 3.5 µm to 5.5 µm is realized. The combination of two, three, or four cross resonators of different sizes in one unit cell enables broadband near-perfect absorption at mid-infrared range. The obtained absorption spectra exhibit omnidirectionality and weak dependence on incident polarization. The underlying mechanism of near-perfect absorption with cross resonators is further explained by the optical mode analysis, dispersion relation and equivalent RLC circuit model. Moreover, thermal analysis is performed to study the heat generation and temperature increase in the cross resonator absorbers, while the energy conversion efficiency is calculated for the thermophotovoltaic system made of the cross resonator thermal emitters and low-bandgap semiconductors.

Estimating Water Ice Abundance from Short-Wave Infrared Spectra of Drill Cuttings at Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Roush, Ted L.; Colaprete, Anthony; Kleinhenz, Julie; Cook, Amanda

2017-01-01

NASA's Resource Prospector (RP) mission intends to visit a lunar polar region to characterize the volatile distribution. Part of the RP payload, the Near-infrared Volatile Spectrometer System (NIRVSS) is a spectrometer operating from 1600-3400 nm that provides sensitivity to water ice, and other volatiles. For multiple years, the NIRVSS system has been incorporated into on-going RP payload testing in a cryogenic vacuum facility at Glenn Research Center. Soil tubes of lunar simulants, prepared with known amounts of water, are placed in the vacuum chamber and cooled to cryogenic temperatures (soil temperatures of 110-170 K) and placed under low vacuum (a few x 10(exp -6) Torr). During these tests NIRVSS continuously measures spectra of soil cuttings emplaced onto the surface by a drill. Real time processing of NIRVSS spectra produces two spectral parameters associated with water ice absorption features near 2000 and 3000 nm that can be used to inform decision making activities such as delivery of the soil to a sealable container. Post-test collection and analyses of the soils permit characterization the water content as a function of depth. These water content profiles exhibit the characteristics of a vacuum desiccation zone to depths of about 40 cm. Subsequent to completion of the tests, NIRVSS spectra are processed to produce two spectral parameters associated with water ice absorption features near 2000 and 3000 nm. These features can be evaluated as a function of time, and correlated with drill depth, and other measurements, throughout the drilling activities. Until now no effort was attempted to quantitatively relate these parameters to water abundance. This is the focus of our efforts to be presented.

Estimating Water Ice Abundance from Short-wave Infrared Spectra of Drill Cuttings at Cryogenic Temperatures

NASA Astrophysics Data System (ADS)

Roush, T. L.; Colaprete, A.; Kleinhenz, J.; Cook, A.

2017-12-01

NASA's Resource Prospector (RP) mission intends to visit a lunar polar region to characterize the volatile distribution. Part of the RP payload, the Near-infrared Volatile Spectrometer System (NIRVSS) is a spectrometer operating from 1600-3400 nm that provides sensitivity to water ice, and other volatiles. For multiple years, the NIRVSS system has been incorporated into on-going RP payload testing in a cryogenic vacuum facility at Glenn Research Center. Soil tubes of lunar simulants, prepared with known amounts of water, are placed in the vacuum chamber and cooled to cryogenic temperatures (soil temperatures of 110-170° K) and placed under low vacuum (a few x 10-6 Torr). During these tests NIRVSS continuously measures spectra of soil cuttings emplaced onto the surface by a drill. Real time processing of NIRVSS spectra produces two spectral parameters associated with water ice absorption features near 2000 and 3000 nm that can be used to inform decision-making activities such as delivery of the soil to a sealable container. Post-test collection and analyses of the soils permit characterization the water content as a function of depth. These water content profiles exhibit the characteristics of a vacuum desiccation zone to depths of about 40 cm. Subsequent to completion of the tests, NIRVSS spectra are processed to produce two spectral parameters associated with water ice absorption features near 2000 and 3000 nm. These features can be evaluated as a function of time, and correlated with drill depth, and other measurements, throughout the drilling activities. Until now no effort was attempted to quantitatively relate these parameters to water abundance. This is the focus of our efforts to be presented.

Airborne spectroradiometry: The application of AIS data to detecting subtle mineral absorption features

NASA Technical Reports Server (NTRS)

Cocks, T. D.; Green, A. A.

1986-01-01

Analysis of Airborne Imaging Spectrometer (AIS) data acquired in Australia has revealed a number of operational problems. Horizontal striping in AIS imagery and spectral distortions due to order overlap were investigated. Horizontal striping, caused by grating position errors can be removed with little or no effect on spectral details. Order overlap remains a problem that seriously compromises identification of subtle mineral absorption features within AIS spectra. A spectrometric model of the AIS was developed to assist in identifying spurious spectral features, and will be used in efforts to restore the spectral integrity of the data.

Iron K Features in the Quasar E 1821+643: Evidence for Gravitationally Redshifted Absorption?

NASA Technical Reports Server (NTRS)

Yaqoob, Tahir; Serlemitsos, Peter

2005-01-01

We report a Chandra high-energy grating detection of a narrow, redshifted absorption line superimposed on the red wing of a broad Fe K line in the z = 0.297 quasar E 1821+643. The absorption line is detected at a confidence level, estimated by two different methods, in the range approx. 2 - 3 sigma. Although the detection significance is not high enough to exclude a non-astrophysical origin, accounting for the absorption feature when modeling the X-ray spectrum implies that the Fe-K emission line is broad, and consistent with an origin in a relativistic accretion disk. Ignoring the apparent absorption feature leads to the conclusion that the Fe-K emission line is narrower, and also affects the inferred peak energy of the line (and hence the inferred ionization state of Fe). If the absorption line (at approx. 6.2 keV in the quasar frame) is real, we argue that it could be due to gravitationally redshifted Fe XXV or Fe XXVI resonance absorption within approx. 10 - 20 gravitational radii of the putative central black hole. The absorption line is not detected in earlier ASCA and Chandra low-energy grating observations, but the absorption line is not unequivocally ruled out by these data. The Chandra high-energy grating Fe-K emission line is consistent with an origin predominantly in Fe I-XVII or so. In an ASCA observation eight years earlier, the Fe-K line peaked at approx. 6.6 keV, closer to the energies of He-like Fe triplet lines. Further, in a Chandra low-energy grating observation the Fe-K line profile was double-peaked, one peak corresponding to Fe I-XVII or so, the other peak to Fe XXVI Ly alpha. Such a wide range in ionization state of Fe is not ruled out by the HEG and ASCA data either, and is suggestive of a complex structure for the line-emitter.

Evaluation of wavelet spectral features in pathological detection and discrimination of yellow rust and powdery mildew in winter wheat with hyperspectral reflectance data

NASA Astrophysics Data System (ADS)

Shi, Yue; Huang, Wenjiang; Zhou, Xianfeng

2017-04-01

Hyperspectral absorption features are important indicators of characterizing plant biophysical variables for the automatic diagnosis of crop diseases. Continuous wavelet analysis has proven to be an advanced hyperspectral analysis technique for extracting absorption features; however, specific wavelet features (WFs) and their relationship with pathological characteristics induced by different infestations have rarely been summarized. The aim of this research is to determine the most sensitive WFs for identifying specific pathological lesions from yellow rust and powdery mildew in winter wheat, based on 314 hyperspectral samples measured in field experiments in China in 2002, 2003, 2005, and 2012. The resultant WFs could be used as proxies to capture the major spectral absorption features caused by infestation of yellow rust or powdery mildew. Multivariate regression analysis based on these WFs outperformed conventional spectral features in disease detection; meanwhile, a Fisher discrimination model exhibited considerable potential for generating separable clusters for each infestation. Optimal classification returned an overall accuracy of 91.9% with a Kappa of 0.89. This paper also emphasizes the WFs and their relationship with pathological characteristics in order to provide a foundation for the further application of this approach in monitoring winter wheat diseases at the regional scale.

Flow Property Measurement Using Laser-Induced Fluorescence in the NASA Ames Interaction Heating Facility

NASA Technical Reports Server (NTRS)

Grinstead, Jay Henderson; Porter, Barry J.; Carballo, Julio Enrique

2011-01-01

The spectroscopic diagnostic technique of two photon absorption laser-induced fluorescence (TALIF) of atomic species has been applied to single-point measurements of velocity and static temperature in the NASA Ames Interaction Heating Facility (IHF) arc jet. Excitation spectra of atomic oxygen and nitrogen were recorded while scanning a tunable dye laser over the absorption feature. Thirty excitation spectra were acquired during 8 arc jet runs at two facility operating conditions; the number of scans per run varied between 2 and 6. Curve fits to the spectra were analyzed to recover their Doppler shifts and widths, from which the flow velocities and static temperatures, respectively, were determined. An increase in the number of independent flow property pairs from each as-measured scan was obtained by extracting multiple lower-resolution scans. The larger population sample size enabled the mean property values and their uncertainties for each run to be characterized with greater confidence. The average plus or minus 2 sigma uncertainties in the mean velocities and temperatures for all 8 runs were plus or minus 1.4% and plus or minus 11%, respectively.

Absorption and Reflection Contributions to the High Performance of Electromagnetic Waves Shielding Materials Fabricated by Compositing Leather Matrix with Metal Nanoparticles.

PubMed

Liu, Chang; Wang, Xiaoling; Huang, Xin; Liao, Xuepin; Shi, Bi

2018-04-25

Leather matrix (LM), a natural dielectric material, features a hierarchically suprafibrillar structure and abundant dipoles, which provides the possibility to dissipate electromagnetic waves (EW) energy via dipole relaxation combined with multiple diffuse reflections. Conventionally, metal-based materials are used as EW shielding materials due to that their high conductivity can reflect EW effectively. Herein, a lightweight and high-performance EW shielding composite with both absorption and reflection ability to EW was developed by coating metal nanoparticles (MNPs) onto LM. The as-prepared metal/LM membrane with only 4.58 wt % of coated MNPs showed excellent EW shielding effectiveness of ∼76.0 dB and specific shielding effectiveness of ∼200.0 dB cm 3 g -1 in the frequency range of 0.01-3.0 GHz, implying that more than 99.98% of EW was shielded. Further investigations indicated that the high shielding performances of the metal/LM membrane were attributed to the cooperative shielding mechanism between LM and the coating of MNPs.

Io: Near-Infrared Absorptions Not Attributable to SO2

NASA Astrophysics Data System (ADS)

Shirley, J. H.; Clark, R. N.; Soderblom, L. A.; Carlson, R. W.; Kamp, L. W.; Galileo NIMS Team

2001-11-01

The Near-Infrared Mapping Spectrometer (NIMS) onboard the Galileo spacecraft imaged the leading side of Jupiter's satellite Io at full spectral resolution and with triple Nyquist spatial sampling during the fifteenth orbital encounter (E15). New despiking and "dejittering" algorithms have been applied to this high S/N observation (15INHRSPEC01A). Spectral absorption features not attributable to SO2 are found between 3.0-3.4 microns and near 4.65 microns. The patterns of the spatial distributions of both absorbers differ from that of the omnipresent SO2. The broad 3.0-3.4 micron absorption is most pronounced in polar regions. Preliminary work suggests that the 4.65 micron feature may be associated with an unidentified sulfate mineral, while the 3.0-3.4 micron feature may result from the presence of more than one absorbing material. Hydrogen-bearing species are likely candidates. For example, H2O ice provides a good match for the absorption near 3.2 microns, but the absorption is shifted to wavelengths longer than that in pure H2O ice. If only one absorber is present, then hydrogen bonding of small numbers of H2O molecules could perhaps account for the shift. The absorption is weak; if H20 related, optical path lengths of a fraction of a micron are indicated. Portions of this research were carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration.

Ca II and Na I absorption in the QSO S4 0248 + 430 due to an intervening galaxy

NASA Technical Reports Server (NTRS)

Womble, Donna S.; Junkkarinen, Vesa T.; Cohen, Ross D.; Burbidge, E. Margaret

1990-01-01

Observations of the QSO S4 0248 + 430 and a nearby anonymous galaxy are presented. Two absorption components are found in both Ca II H and K and Na I D1 and D2 at z(a) = 0.0515, 0.0523. Column densities of log N(Ca II) = 13.29, 13.50, and log N(Na I) = 13.79, 14.18 are found for z(a) = 0.0515, 0.0523 absorption systems, respectively. The column density ratios imply considerable calcium depletion and disk-type absorbing gas. At least one and possibly both absorption components are produced by high-velocity gas. A broadband image of the field shows an asymmetrical armlike feature or possible tidal tail covering and extending past the position of the QSO. The presence of this extended feature and the apparent difference between the absorption velocities and galaxy rotation velocity suggest that the absorbing gas is not ordinary disk gas, but rather is a result of tidal disruption.

Excited state absorption spectra of dissolved and aggregated distyrylbenzene: A TD-DFT state and vibronic analysis

NASA Astrophysics Data System (ADS)

Oliveira, Eliezer Fernando; Shi, Junqing; Lavarda, Francisco Carlos; Lüer, Larry; Milián-Medina, Begoña; Gierschner, Johannes

2017-07-01

A time-dependent density functional theory study is performed to reveal the excited state absorption (ESA) features of distyrylbenzene (DSB), a prototype π-conjugated organic oligomer. Starting with a didactic insight to ESA based on simple molecular orbital and configuration considerations, the performance of various density functional theory functionals is tested to reveal the full vibronic ESA features of DSB at short and long probe delay times.

Fiber and fabric solar cells by directly weaving carbon nanotube yarns with CdSe nanowire-based electrodes

NASA Astrophysics Data System (ADS)

Zhang, Luhui; Shi, Enzheng; Ji, Chunyan; Li, Zhen; Li, Peixu; Shang, Yuanyuan; Li, Yibin; Wei, Jinquan; Wang, Kunlin; Zhu, Hongwei; Wu, Dehai; Cao, Anyuan

2012-07-01

Electrode materials are key components for fiber solar cells, and when combined with active layers (for light absorption and charge generation) in appropriate ways, they enable design and fabrication of efficient and innovative device structures. Here, we apply carbon nanotube yarns as counter electrodes in combination with CdSe nanowire-grafted primary electrodes (Ti wire) for making fiber and fabric-shaped photoelectrochemical cells with power conversion efficiencies in the range 1% to 2.9%. The spun-twist long nanotube yarns possess both good electrical conductivity and mechanical flexibility compared to conventional metal wires or carbon fibers, which facilitate fabrication of solar cells with versatile configurations. A unique feature of our process is that instead of making individual fiber cells, we directly weave single or multiple nanotube yarns with primary electrodes into a functional fabric. Our results demonstrate promising applications of semiconducting nanowires and carbon nanotubes in woven photovoltaics.Electrode materials are key components for fiber solar cells, and when combined with active layers (for light absorption and charge generation) in appropriate ways, they enable design and fabrication of efficient and innovative device structures. Here, we apply carbon nanotube yarns as counter electrodes in combination with CdSe nanowire-grafted primary electrodes (Ti wire) for making fiber and fabric-shaped photoelectrochemical cells with power conversion efficiencies in the range 1% to 2.9%. The spun-twist long nanotube yarns possess both good electrical conductivity and mechanical flexibility compared to conventional metal wires or carbon fibers, which facilitate fabrication of solar cells with versatile configurations. A unique feature of our process is that instead of making individual fiber cells, we directly weave single or multiple nanotube yarns with primary electrodes into a functional fabric. Our results demonstrate promising applications of semiconducting nanowires and carbon nanotubes in woven photovoltaics. Electronic supplementary information (ESI) available. See DOI: 10.1039/c2nr31440a

An absorptive single-pole four-throw switch using multiple-contact MEMS switches and its application to a monolithic millimeter-wave beam-forming network

NASA Astrophysics Data System (ADS)

Lee, Sanghyo; Kim, Jong-Man; Kim, Yong-Kweon; Kwon, Youngwoo

2009-01-01

In this paper, a new absorptive single-pole four-throw (SP4T) switch based on multiple-contact switching is proposed and integrated with a Butler matrix to demonstrate a monolithic beam-forming network at millimeter waves (mm waves). In order to simplify the switching driving circuit and reduce the number of unit switches in an absorptive SP4T switch, the individual switches were replaced with long-span multiple-contact switches using stress-free single-crystalline-silicon MEMS technology. This approach improves the mechanical stability as well as the manufacturing yield, thereby allowing successful integration into a monolithic beam former. The fabricated absorptive SP4T MEMS switch shows insertion loss less than 1.3 dB, return losses better than 11 dB at 30 GHz and wideband isolation performance higher than 39 dB from 20 to 40 GHz. The absorptive SP4T MEMS switch is integrated with a 4 × 4 Butler matrix on a single chip to implement a monolithic beam-forming network, directing beam into four distinct angles. Array factors from the measured data show that the proposed absorptive SPnT MEMS switch can be effectively used for high-performance mm-wave beam-switching systems. This work corresponds to the first demonstration of a monolithic beam-forming network using switched beams.

Compositional Analyses and Implications of Visible/Near-Infrared Spectra of Outer Irregular Jovian Satellites

NASA Astrophysics Data System (ADS)

Vilas, Faith; Hendrix, Amanda

2017-10-01

The existence of a visible-near infrared absorption feature attributed to aqueous alteration products has been suggested in both grey and reddened broadband photometry of some outer irregular jovian satellites. Moderate resolution VNIR narrowband spectroscopy was obtained of the jovian irregular satellites JVI Himalia, JVII Elara, JVIII Pasiphae, JIX Sinope, JX Lysithea, JXI Carme, JXII Ananke and JXVII Callirrhoe in 2006, 2008, 2009, and 2010 using the MMT Observatory facility Red Channel spectrograph to confirm the presence of this feature. The spectra are centered near 0.64 μm in order to cover the 0.7-μm feature entirely (generally ranging from 0.57 to 0.83 μm). The spectra generally have a dispersion/element of ~0.6 nm (6Å) some spectra are smoothed. These spectra sample three prograde (i = 28o), four retrograde (i = 149o, 165o) and one independent satellite.We observe these findings among the spectra:- An absorption feature centered near 0.7 µm exists in the spectra of the three prograde (i = 28o) satellites. This feature is spectrally broader than the 0.7-µm feature observed in C-complex asteroids. None appears spectrally reddened. This suggests that these prograde satellites have a common parent body.- A different absorption feature appears in the spectra of the three retrograde (i = 149o) satellites, also suggesting a common parent body. Varying reddening is observed. This feature is similar in spectral location and width to the 0.7-µm feature.- Reddening is observed in the individual observation of JXI Carme (i = 165o), and independent satellite JIX Sinope, similar to the D-class asteroid spectra dominating the Trojan population. A suggested absorption feature is being investigated.Mixing modeling of combinations of both expected and proposed compositions including carbonaceous materials, phyllosilicates, mafic silicates, and other opaque materials, is currently underway. Results will be reported and discussed at the meeting.Acknowledgments: The MMT Observatory is a joint facility of the University of Arizona and the Smithsonian Institution. This research has been supported by SSERVI CLASS.

Multiple infrared bands absorber based on multilayer gratings

NASA Astrophysics Data System (ADS)

Liu, Xiaoyi; Gao, Jinsong; Yang, Haigui; Wang, Xiaoyi; Guo, Chengli

2018-03-01

The present study offers an Ag/Si multilayer-grating microstructure based on an Si substrate. The microstructure exhibits designable narrowband absorption in multiple infrared wavebands, especially in mid- and long-wave infrared atmospheric windows. We investigate its resonance mode mechanism, and calculate the resonance wavelengths by the Fabry-Perot and metal-insulator-metal theories for comparison with the simulation results. Furthermore, we summarize the controlling rules of the absorption peak wavelength of the microstructure to provide a new method for generating a Si-based device with multiple working bands in infrared.

Comparing the VIRTIS Spectrum of 67P/Churyumov-Gerasimenko to Wild 2 and in Primitive Interplanetary Dust Particles

NASA Astrophysics Data System (ADS)

Flynn, George

2016-04-01

The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) instrument, a point spectrometer with high spectral resolution covering the range from 2 to 5 microns, on the ESA Rosetta spacecraft obtained spectra of the surface of Comet 67P/Churyumov-Gerasimenko. The spectral region covered by VIRTIS has been well studied in meteorites, interplanetary dust particles (IDPs) collected by NASA from the Earth's stratosphere, and the samples of Comet 81P/Wild 2 that were delivered to Earth by the NASA Stardust spacecraft. Infrared spectra of the nucleus of Comet 67P/Churyumov-Gerasimenko acquired by VIRTIS show a broad absorption band observed at ~3.3 μm, a region of the spectrum where C-H, O-H, and N-H stretching features occur (Capaccioni et al., 2015). This broad feature is similar to the O-H feature exhibited by hydrous minerals, but shifted to a significantly longer wavelength. Capaccioni et al. (2015) compared the VIRTIS spectra to laboratory spectra of carbonaceous chondrite meteorites of the CI, CM, and CR types and concluded that none of the typical features of these meteorite spectra are compatible with the spectra of the surface of 67P/Churyumov-Gerasimenko. Comparison of VIRTIS spectra of 67P/ Churyumov-Gerasimenko to the laboratory spectra of well-characterized extraterrestrial materials including the Wild 2 dust and the IDPs, a significant fraction of which are believed to be cometary, could aid in the interpretation of the 67P/Churyumov-Gerasimenko spectra. None of the Wild 2 particles examined by infrared spectroscopy exhibit an O-H feature, but this may be due to the high temperature reached during their capture in the aerogel collection medium. The O-H feature is also absent in all anhydrous IDPs. The hydrous IDPs exhibit varying strengths of both aliphatic C-H absorption features and the O-H absorption feature, but, as with the meteorites, the O-H feature occurs at a significantly shorter wavelength than the broad feature detected in 67P/Churyumov-Gerasimenko. Only one of the more than 50 IDPs analyzed by infrared spectroscopy has an infrared spectrum similar to that of 67P/Churyumov-Gerasimenko. This large, hydrous IDP, L2021 C10, has a broad absorption feature centered at the same position as the feature observed in 67P/Churyumov-Gerasimenko. In the case of L2021 C10 this feature is attributed to an O-H absorption feature in the position normally seen in hydrous minerals as well as a broad aromatic C-H feature, rarely detected in IDPs, and the aliphatic C-H feature seen in all IDPs examined thus far (Flynn et al., 2004). In the case of the VIRTIS spectrum of 67P/Churyumov-Gerasimenko the apparent shift of the broad O-H feature may actually result from the superposition of O-H and aromatic C-H features, both at their normal wavelengths. References: Capaccioni, F. et al. (2015) Science, 347 no. 6220, DOI: 10.1126/science.aaa0628. Flynn, G. J. et al. (2004) Advances in Space Research, 33, 57-66.

Pioneer 11 observations of trapped particle absorption by the Jovian ring and the satellites 1979, J1, J2, and J3

NASA Technical Reports Server (NTRS)

Pyle, K. R.; Mckibben, R. B.; Simpson, J. A.

1983-01-01

Pioneer 11 low energy telescope observation of charged particles around the Jovian satellites Amalthea, 1979 J1, J2, and J3, and the Jupiter ring are examined in the light of Voyager optical data from the same region. Good agreement was found in the absorption features of 0.5-8.7 MeV protons, electrons with energies of 3.4 MeV or more, and medium-Z nuclei. The heavier nuclei are suggested to be oxygen and sulfur particles with energies exceeding 70 MeV/nucleon. The observed intensity features in the regularly spaced radiation bands are interpreted as ring and satellite absorption.

Two-Photon Absorption in Pentacene Dimers: The Importance of the Spacer Using Upconversion as an Indirect Route to Singlet Fission.

PubMed

Garoni, Eleonora; Zirzlmeier, Johannes; Basel, Bettina S; Hetzer, Constantin; Kamada, Kenji; Guldi, Dirk M; Tykwinski, Rik R

2017-10-11

In this proof of concept study, we show that intramolecular singlet fission (iSF) can be initiated from a singlet excited state accessed by two-photon absorption, rather than through a traditional route of direct one-photon excitation (OPE). Thus, iSF in pentacene dimers 2 and 3 is enabled through NIR irradiation at 775 nm, a wavelength where neither dimer exhibits linear absorption of light. The adamantyl and meta-phenylene spacers 2 and 3, respectively, are designed to feature superimposable geometries, which establishes that the electronic coupling between the two pentacenes is the significant structural feature that dictates iSF efficiency.

Universal ultrafast signatures of photoexcitations in conjugated polymers: excitons and charge-transfer polarons

NASA Astrophysics Data System (ADS)

McBranch, Duncan W.; Kraabel, Brett; Xu, Su; Wang, Hsing-Lin; Klimov, Victor I.

1999-12-01

Using subpicosecond transient absorption spectroscopy, we have investigated the primary photoexcitations in thin films and solution of several phenylene-based conjugated polymers and an oligomer. We identify two features in the transient absorption spectra and dynamics that are common to all of the materials which we have studied from this family. The first spectral feature is a photoinduced absorption (PA) band peaking near 1 eV which has intensity-dependent dynamics which match the stimulated emission dynamics exactly over two orders of magnitude in excitation density. This band is associated with singlet intrachain excitons. The second spectral feature (observed only in thin films and aggregated solutions) is a PA band peaking near 1.8 eV, which is longer-lived than the 1 eV exciton PA band, and which has dynamics that are independent (or weakly-dependent) on excitation density. This feature is attributed to charge separated (interchain) excitations. These excitations are generated through a bimolecular process. By comparing to samples in which charged excitations are created deliberately by doping with C6O, we assign these secondary species as bound polarons.

Spectral Characteristics of Hayabusa 2 Near-Earth Asteroid Targets 162173 1999 JU3 and 2001 QC34

NASA Astrophysics Data System (ADS)

Vilas, Faith

2008-04-01

Reflectance spectra of C-type near-Earth asteroid 162173 1999 JU3 were acquired on UT 2007 July 11, September 10 and 11. An absorption feature centered near 0.7 μm, and associated with the presence of iron-bearing phyllosilicates, is seen in the 2007 July 11 spectrum. The 2007 September spectrum shows a shallow absorption feature centered near 0.6 μm. In contrast, the reflectance spectrum of 162173 1999 JU3 obtained during its discovery apparition has no absorption feature, suggesting that the asteroid's surface covers the conjunction of two different geological units. The variation in the presence and absence of these features in reflectance spectra of the surface material of C-type asteroids is observed among main-belt asteroids. As the target for the planned Japanese mission Hayabusa 2, 162173 1999 JU3 could represent a sample of aqueously altered early solar system material. An alternative target for Hayabusa 2, 2001 QC34, was observed spectrally for the first time. Its reflectance spectrum has characteristics of a Q-class or O-class asteroid.

Search for Feo and Pyroxene on MERCURY?S Surface

NASA Astrophysics Data System (ADS)

Sprague, Ann L.; Emery, Joshua P.

Results from spectral observations of Mercury's surface in the wavelength range 0.8 to 5.5 micrometers will be reported. The data were obtained at the NASA Infrared Telescope Facility on Mauna Kea Hawaii. We used SpeX a long slit imaging system developed at the IRTF for high resolving power spatially resolved spectroscopy throughout the solar system. We aligned the spectral slit with Mercury's geographic longitude and systematically moved it across the Earth-facing disk to obtain multiple disk-resolved spectral images. The entire data set provides spatial coverage of the Earth-facing disk limited only by atmospheric turbulence and the diffraction limit for each wavelength. We used SpeX in two spectral regions in the R 2000 mode. In the first case between 0.8 and 2.5 micrometer to search for the 0.9 to 1.0 micrometer reflectance absorption feature caused by the Fe2+ electronic transfer in FeO. We also measured the 4.5 to 5.5 micrometer flux from Mercury. This is a region of diagnostic features caused by the presence of volume scattering in pyroxene and olivine. These data will be compared to previous observations that showed an anomalous emission feature at 5.5 micrometer and to others that exhibited a feature closely resembling that from pyroxene.

Identify super quality markers from prototype-based pharmacokinetic markers of Tangzhiqing tablet (TZQ) based on in vitro dissolution/ permeation and in vivo absorption correlations.

PubMed

Li, Ziqiang; Liu, Jia; Li, Yazhuo; Du, Xi; Li, Yanfen; Wang, Ruihua; Lv, Chunxiao; He, Xin; Wang, Baohe; Huang, Yuhong; Zhang, Deqin

2018-06-01

A quality marker (Q-marker) is defined as an inherent chemical compound that is used for the quality control of a drug. Its biological activities are closely related to safety and therapeutic effects. Generally, a multiple-component herbal medicine may have many Q-markers. We therefore proposed a concept of "super Q-marker" satisfying both the criterion of Q-markers and PK-markers to be used in more effective quality control of herbal medicine. The first aim was to find suitable prototype-based PK-markers from Tangzhiqing tablets (TZQ), a Chinese patent medicine. Then super Q-markers were expected to be identified from the prototype-based PK-markers based on an in vitro-in vivo correlation study. Potentially eligible prototype-based PK-markers were identified in a single- and multiple-dose pharmacokinetic study on TZQ in 30 healthy volunteers. The in vitro dissolution and permeation profiles of the prototype-based PK-markers of TZQ were evaluated by the physiologically-based drug dissolution/absorption simulating system (DDASS). An in vitro-in vivo correlation analysis was conducted between the dissolution/permeation behaviors in DDASS and the actual absorption profiles in human to test the transferability and traceability of the promising super Q-markers for TZQ. In human, plasma paeoniflorin and nuciferine as prototype-based PK-markers exhibited the appropriate pharmacokinetic properties, including dose-dependent systemic exposure (AUC, C max ) and a proper elimination half-life (1∼3h). In DDASS, it was predicted that paeoniflorin and nuciferine are highly permeable but the absorption rates are primarily limited by the dissolution rates. Moreover, the established in vitro-in vivo correlations of paeoniflorin and nuciferine were in support of the super Q-markers features. Paeoniflorin and nuciferine are identified as the super Q-markers from the prototype-based PK-markers of TZQ based on findings from a combination of in vitro, in vivo, and in vitro-in vivo correlation studies. This method is practical for optimal identification of qualified Q-markers, thus helping improve the quality control of herbal medicines. Copyright © 2018 Elsevier GmbH. All rights reserved.

Hyperspectral Features of Oil-Polluted Sea Ice and the Response to the Contamination Area Fraction

PubMed Central

Li, Ying; Liu, Chengyu; Xie, Feng

2018-01-01

Researchers have studied oil spills in open waters using remote sensors, but few have focused on extracting reflectance features of oil pollution on sea ice. An experiment was conducted on natural sea ice in Bohai Bay, China, to obtain the spectral reflectance of oil-contaminated sea ice. The spectral absorption index (SAI), spectral peak height (SPH), and wavelet detail coefficient (DWT d5) were calculated using stepwise multiple linear regression. The reflectances of some false targets were measured and analysed. The simulated false targets were sediment, iron ore fines, coal dust, and the melt pool. The measured reflectances were resampled using five common sensors (GF-2, Landsat8-OLI, Sentinel3-OLCI, MODIS, and AVIRIS). Some significant spectral features could discriminate between oil-polluted and clean sea ice. The indices correlated well with the oil area fractions. All of the adjusted R2 values exceeded 0.9. The SPH model1, based on spectral features at 507–670 and 1627–1746 nm, displayed the best fitting. The resampled data indicated that these multi-spectral and hyper-spectral sensors could be used to detect crude oil on the sea ice if the effect of noise and spatial resolution are neglected. The spectral features and their identified changes may provide reference on sensor design and band selection. PMID:29342945

A novel design for maskless direct laser writing nanolithography: Combination of diffractive optical element and nonlinear absorption inorganic resists

NASA Astrophysics Data System (ADS)

Zha, Yikun; Wei, Jingsong; Gan, Fuxi

2013-09-01

Maskless laser direct writing lithography has been applied in the fabrication of optical elements and electric-optical devices. With the development of technology, the feature size of the elements and devices is required to reduce down to nanoscale. Increasing the numerical aperture of converging lens and shortening the laser wavelength are good methods to obtain the small spot and reduce the feature size to nanoscale, while this will cause the reduction of the depth of focus. The reduction of depth of focus will lead to some difficulties in the focusing and tracking servo controlling during the high speed laser direct writing lithography. In this work, the combination of the diffractive optical elements and the nonlinear absorption inorganic resist thin films cannot only extend the depth of focus, but also reduce the feature size of the lithographic marks down to nanoscale. By using the five-zone annular phase-only binary pupil filter as the diffractive optical elements and AgInSbTe as the nonlinear absorption inorganic resist thin film, the depth of focus cannot only extend to 7.39 times that of the focused spot, but also reduce the lithographic feature size down to 54.6 nm. The ill-effect of sidelobe on the lithography is also eliminated by the nonlinear reverse saturable absorption and the phase change threshold lithographic characteristics.

Leveraging multi-channel x-ray detector technology to improve quality metrics for industrial and security applications

NASA Astrophysics Data System (ADS)

Jimenez, Edward S.; Thompson, Kyle R.; Stohn, Adriana; Goodner, Ryan N.

2017-09-01

Sandia National Laboratories has recently developed the capability to acquire multi-channel radio- graphs for multiple research and development applications in industry and security. This capability allows for the acquisition of x-ray radiographs or sinogram data to be acquired at up to 300 keV with up to 128 channels per pixel. This work will investigate whether multiple quality metrics for computed tomography can actually benefit from binned projection data compared to traditionally acquired grayscale sinogram data. Features and metrics to be evaluated include the ability to dis- tinguish between two different materials with similar absorption properties, artifact reduction, and signal-to-noise for both raw data and reconstructed volumetric data. The impact of this technology to non-destructive evaluation, national security, and industry is wide-ranging and has to potential to improve upon many inspection methods such as dual-energy methods, material identification, object segmentation, and computer vision on radiographs.

Similarities in STXM-NEXAFS Spectra of Atmospheric Particles and Secondary Organic Aerosol Generated from Glyoxal, α-Pinene, Isoprene, 1,2,4-Trimethylbenzene, and d-Limonene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shakya, Kabindra M.; Liu, Shang; Takahama, Satoshi

2013-02-06

Functional group composition of particles produced in smog chambers are examined using scanning transmission X-ray microscopy (STXM) with near-edge X-ray absorption fine structure (NEXAFS) spectroscopy in order to identify characteristic spectral signatures for secondary organic aerosol (SOA). Glyoxal uptake studies showed absorption for mainly alkyl, carbon-nitrogen (C-N), and carboxylic carbonyl groups. The SOA formed from the photooxidation of α-pinene (with and without isoprene) showed stronger absorptions for alkyl and carbonyl groups than the glyoxal studies. The mass ratio of carbonyl to acid group was larger in α-pinene-only experiments relative to the mixed α-pinene-isoprene experiments. The chamber particle spectra were comparedmore » with the ambient particle spectra from multiple field campaigns to understand the potential SOA sources. One hundred nineteen particles from six field campaigns had spectral features that were considered similar to the chamber-SOA particles: MILAGRO-2006 (9 particles), VOCALS-2008 (42 particles), Whistler-2008 (22 particles), Scripps Pier-2009 (9 particles), Bakersfield-2010 (25 particles), and Whistler-2010 (12 particles). These similarities with SOA formed from glyoxal, α-pinene (with and without isoprene), 1,2,4-trimethylbenzene, and limonene provide spectroscopic evidence of SOA products from these precursors in ambient particles.« less

Geometry of Pt(IV) in H 2PtCl 6 aqueous solution: An X-ray absorption spectroscopic investigation

NASA Astrophysics Data System (ADS)

Chen, Xing; Chu, Wangsheng; Wang, Lei; Wu, Ziyu

2009-02-01

The noble metal ions play an important role in many chemical reactions, but at the present time they represent also potentially new environmental contaminants. There is relatively little information available to adequately assess the potential health hazards, so that to evaluate the potential hazards and identify the necessary actions to reduce the risks associated with exposure to these metals and their compounds it is important to understand the local structure around noble metal ions. In this contribution, the local coordination around platinum (IV) ions e.g., Pt 4+ in aqueous solution, has been investigated by using X-ray absorption spectroscopy (XAS). X-ray absorption near-edge spectra (XANES) of both [PtCl 6] 2- and [PtCl 4(OH) 2] 2- in an aqueous solution have been calculated using FEFF8.2 and both are characterized by an octahedral geometry. From these calculations, we may also assign a characteristic post-edge feature to a contribution of Cl d-states. From the EXAFS analysis we also determined the corresponding Pt bond distances, e.g., 2.33 Å for the Pt-Cl distance and 2.03 Å for the Pt-O distance in these aqueous solutions. The same analysis provides evidence that the peaks in the Fourier transform at about 4.0 Å are due to multiple scattering collinear Cl-Pt-Cl contributions.

The influence of local electric fields on photoinduced absorption in dye-sensitized solar cells.

PubMed

Cappel, Ute B; Feldt, Sandra M; Schöneboom, Jan; Hagfeldt, Anders; Boschloo, Gerrit

2010-07-07

The dye-sensitized solar cell (DSC) challenges conventional photovoltaics with its potential for low-cost production and its flexibility in terms of color and design. Transient absorption spectroscopy is widely used to unravel the working mechanism of DSCs. A surprising, unexplained feature observed in these studies is an apparent bleach of the ground-state absorption of the dye, under conditions where the dye is in the ground state. Here, we demonstrate that this feature can be attributed to a change of the local electric field affecting the absorption spectrum of the dye, an effect related to the Stark effect first reported in 1913. We present a method for measuring the effect of an externally applied electric field on the absorption of dye monolayers adsorbed on flat TiO(2) substrates. The measured signal has the shape of the first derivative of the absorption spectra of the dyes and reverses sign along with the reversion of the direction of the change in dipole moment upon excitation relative to the TiO(2) surface. A very similar signal is observed in photoinduced absorption spectra of dye-sensitized TiO(2) electrodes under solar cell conditions, demonstrating that the electric field across the dye molecules changes upon illumination. This result has important implications for the analysis of transient absorption spectra of DSCs and other molecular optoelectronic devices and challenges the interpretation of many previously published results.

Statistical Fine Structure in Inhomogeneously Broadened Absorption Lines in Solids.

DTIC Science & Technology

1987-12-22

the inhomogeneously broadened zero-phonon SijSo (0-0) absorption of pentacene molecules in crystals of p-terphenyl at liquid helium temperatures. SFS...structure (SFS) in the inhomogeneously broadened zero-phonon S, +- So (0-0) absorption of pentacene molecules in crystals of p-terphenyl at liquid helium...tile large multiplicity of local environments. Inhomogeneously broadened absorption lines are usually treated as smooth, Gaussian profiles. In recent

Understanding the features in the ultrafast transient absorption spectra of CdSe quantum dots

NASA Astrophysics Data System (ADS)

Zhang, Cheng; Do, Thanh Nhut; Ong, Xuanwei; Chan, Yinthai; Tan, Howe-Siang

2016-12-01

We describe a model to explain the features of the ultrafast transient absorption (TA) spectra of CdSe core type quantum dots (QDs). The measured TA spectrum consists of contributions by the ground state bleach (GSB), stimulated emission (SE) and excited state absorption (ESA) processes associated with the three lowest energy transition of the QDs. We model the shapes of the GSB, SE and ESA spectral components after fits to the linear absorption. The spectral positions of the ESA components take into account the biexcitonic binding energy. In order to obtain the correct weightage of the GSB, SE and ESA components to the TA spectrum, we enumerate the set of coherence transfer pathways associated with these processes. From our fits of the experimental TA spectra of 65 Å diameter QDs, biexcitonic binding energies for the three lowest energy transitions are obtained.

First Spectroscopic Identification of Massive Young Stellar Objects in the Galactic Center

NASA Technical Reports Server (NTRS)

An, Deokkeun; Ramirez, V.; Sellgren, Kris; Arendt, Richard G.; Boogert, A. C.; Schultheis, Mathias; Stolovy, Susan R.; Cotera, Angela S.; Robitaille, Thomas P.; Smith, Howard A.

2009-01-01

We report the detection of several molecular gas-phase and ice absorption features in three photometrically-selected young stellar object (YSO) candidates in the central 280 pc of the Milky Way. Our spectra, obtained with the Infrared Spectrograph (IRS) onboard the Spitzer Space Telescope, reveal gas-phase absorption from CO2 (15.0 microns), C2H2 (13.7 microns) and HCN (14.0 microns). We attribute this absorption to warm, dense gas in massive YSOs. We also detect strong and broad 15 microns CO2 ice absorption features, with a remarkable double-peaked structure. The prominent long-wavelength peak is due to CH3OH-rich ice grains, and is similar to those found in other known massive YSOs. Our IRS observa.tions demonstra.te the youth of these objects, and provide the first spectroscopic identification of massive YSOs in the Galactic Center.

Absorption by Spinning Dust: A Contaminant for High-redshift 21 cm Observations

NASA Astrophysics Data System (ADS)

Draine, B. T.; Miralda-Escudé, Jordi

2018-05-01

Spinning dust grains in front of the bright Galactic synchrotron background can produce a weak absorption signal that could affect measurements of high-redshift 21 cm absorption. At frequencies near 80 MHz where the Experiment to Detect the Global EoR Signature (EDGES) has reported 21 cm absorption at z≈ 17, absorption could be produced by interstellar nanoparticles with radii a≈ 50 \\mathringA in the cold interstellar medium (ISM), with rotational temperature T ≈ 50 K. Atmospheric aerosols could contribute additional absorption. The strength of the absorption depends on the abundance of such grains and on their dipole moments, which are uncertain. The breadth of the absorption spectrum of spinning dust limits its possible impact on measurement of a relatively narrow 21 cm absorption feature.

Are Hyperion and Phoebe Linked to Iapetus?

NASA Technical Reports Server (NTRS)

Jarvis, Kandy S.; Vilas, Faith; Larson, Stephen M.; Gaffey, Michael J.

1999-01-01

Narrowband reflectance spectra of the Saturnian satellites S VII Hyperion and S IX Phoebe were obtained across the 0.4 - 0.8 micron spectral region. The spectrum of Phoebe is similar to the spectrum of a C-class asteroid, with an absorption feature centered near 0.43 micron superimposed on the UV/blue intervalence charge transfer transition present in the spectrum. The spectrum of Hyperion shows the strong spectral slope apparent in spectra of many outer Solar System materials and attributed to organics. We use a linear mixing model to separate the reflectance spectrum of the dark material on Hyperion from the icy material. A distinct absorption feature centered at 0.67 micron is present. A slight inflection near 0.4 - 0.6 micron and change in slope near 0.73 micron suggesting the lower wavelength edge of an absorption are also present. These absorptions are very similar to those identified in the spectrum of the dark material on the surface of Iapetus, suggesting that the dark material on these two satellites is compositionally similar and has a similar origin. These absorption features are attributed to the (6)A(sub 1) yields (4)T(sub 2)(G) and (6)A(sub 1) yields (4)T(sub 1)(G) ferric charge transfer transitions in iron alteration minerals such as goethite and hematite that are products of the aqueous alteration of anhydrous silicates.

Could G Asteroids be the Parent Bodies of the CM Chondrites?

NASA Astrophysics Data System (ADS)

Burbine, T. H.; Binzel, R. P.

1995-09-01

Since almost all meteorites are believed to be derived from asteroidal source bodies, the comparison of asteroid and meteorite spectra should allow for possible meteorite parent bodies to be identified. However only two asteroids with unique spectral characteristics, 4 Vesta with the basaltic achondrites [1] and near-Earth asteroid 3103 Eger with the aubrites [2], have been convincingly linked with any meteorite type. Farinella et al. [3] has done a study of 2355 numbered main-belt asteroids to determine which asteroids have the highest probability of having their fragments injected into the 3:1 mean motion and the nu6 secular resonance regions. Interestingly, asteroids with the third (19 Fortuna), tenth (1 Ceres) and eleventh (13 Egeria) highest theoretical total fragment delivery efficiencies are G-asteroids, a moderately rare type of asteroid with approximately ten known members. (Vesta has the fifth highest theoretical total fragment delivery efficiency.) G-asteroids tend to have the strongest ultraviolet, 0.7 micrometers and 3 micrometers absorption features of all C-type (B, C, F and G) asteroids, appearing to indicate that G-asteroids are at the upper range of the aqueous alteration sequence in the asteroid population. (The 0.7 micrometers feature is apparently due to iron oxides in hydrated silicates and the 3 micrometers feature is apparently due to hydrated minerals.) Meteorites that have reflectance spectra with a 3 micrometers feature of comparable intensity to those of the G-asteroids are the CI, CM and CR chondrites. However, G-asteroids (like all C-types) have ultraviolet absorption features that are weaker than previously measured meteorite spectra. Comparisons of reflectance spectra between Ceres and meteorite samples appear to indicate that Ceres is compositionally different from almost all known carbonaceous chondrites. Both Fortuna and Egeria have an absorption feature centered around 0.7 micrometers [4] that is similar in structure and strength to those found in many CM chondrites. The visible and near-infrared spectrum of Fortuna [5] matches very well the spectra of CM chondrites Murchison (bulk powder) [6] and LEW90500 (particle sizes less than 100 micrometers) [7]. However, the ultraviolet absorption feature is still weaker in Fortuna's spectrum. A spectrum of a bulk powder of LEW90500 does have an ultraviolet feature that matches Fortuna's feature, but this spectrum is substantially bluer than Fortuna in the near-infrared. Egeria's ultraviolet absorption feature also matches very well the ultraviolet feature in LEW90500Us (bulk powder) spectrum, but this spectrum is slightly redder than Egeria [5] in the near-infrared. The question is how unique is any postulated linkage between the CM chondrites and the G-asteroids. The problem is that approximately two-thirds of all C-type asteroids have 3 micrometers absorption features [8] and approximately three-fourths have 0.7 micrometers absorption features [4]. However of all observed C-type asteroids, Fortuna and Egeria appear to be two of the best spectral matches for the CM chondrites. Coupled with the high probability that these two asteroids are injecting large numbers of fragments into meteorite-supplying resonances, G-asteroids Fortuna and Egeria appear to be possible CM chondrite parent bodies. Acknowledgments: This research is supported by NASA Grant Number NAGW-2049. References: [1] Binzel R. P. and Xu S. (1993) Science, 260, 186-191. [2] Gaffey M. J. et al. (1992) Icarus, 100, 95-109. [3] Farinella P. et al. (1993) Icarus, 101, 174-187. [4] Sawyer S. R. (1991) Ph.D. thesis, Univ. of Texas, Austin. [5] Bell J. F. et al. (1988) LPS XIX, 57-58. [6] Gaffey M. J. (1976) JGR, 81, 905-920. [7] Hiroi T. et al. (1993) Science, 261, 1016-1018. [8] Jones T. D. et al. (1990) Icarus, 88,172-192.

VNIR spectral features observed by the Mars Exploration Rover Opportunity in hematite-bearing materials at Meridiani Planum

NASA Astrophysics Data System (ADS)

Farrand, W. H.; Bell, J. F.; Morris, R. V.; Joliff, B. L.; Squyres, S. W.; Souza, P. A.

2004-12-01

The Mars Exploration Rover Opportunity was sent to Meridiani Planum based largely on MGS TES spectroscopic evidence of a large surface exposure of coarse grained gray hematite. The presence of hematite at Meridiani Planum has been confirmed through thermal infrared spectroscopy by the rover's Mini-TES instrument and by in-situ measurements by its Moessbauer (MB) spectrometer. Several types of hematite, as expressed by differences in MB spectral parameters, have been associated with various rocks and soils examined in Eagle crater and on the surrounding plains. The host materials include the small spherules (informally known as "blueberries") littering the floor of Eagle crater and the plains of Meridiani, the outcrop rock itself, specific types of soils, and two measurements on unique rocks in the Shoemaker's Patio area of Eagle crater. At the visible to near infrared (VNIR) wavelengths covered by the rover's multispectral Panoramic camera (Pancam), gray hematite is spectrally neutral. However, multispectral observations by Pancam of some of these hematite-bearing materials show discernable spectral features. Specifically, portions of the outcrop visible in the walls of Eagle crater display a strong 535 nm absorption feature. This feature resembles a similar feature in laboratory spectra of red hematite, but the characteristic 860 nm absorption of red hematite is either absent or is instead replaced by a longer wavelength absorption centered on Pancam's 900 nm channel. The blueberries display a deep and broad absorption centered on 900 nm and as well as an increase in reflectance in the 1009 nm band. The shape of the absorption feature in the blueberries is consistent with that seen in red hematite, but again the band minimum is displaced to a longer wavelength than would be expected for red hematite. The blueberries also lack the prominent absorption at the shortest wavelengths that would be expected of red hematite. The unique hematite-bearing (or coated) rocks at Shoemaker's Patio lack the very strong 535 nm band depth of other portions of the outcrop but still have a stronger 535 nm feature than most of the outcrop. Interestingly, VNIR spectra more consistent with that expected for red hematite have been found in cuttings released by grinding into outcrop by the rover's Rock Abrasion Tool. The cause of the observed spectral features in the portions of outcrop with strong 535 nm band depths and of the reddish rocks in the Shoemaker's Patio area is believed to be attributable either to red hematite mixed with other Fe3+ - bearing phases (such as jarosite and/or schwertmannite) or, at the longer wavelengths, with Fe2+ - bearing phases (such as pyroxenes). Determination of the nature of these iron-bearing materials will further elucidate the geologic, aqueous and diagenetic history of the rocks at Meridiani Planum.

Monte Carlo Analysis of Molecule Absorption Probabilities in Diffusion-Based Nanoscale Communication Systems with Multiple Receivers.

PubMed

Arifler, Dogu; Arifler, Dizem

2017-04-01

For biomedical applications of nanonetworks, employing molecular communication for information transport is advantageous over nano-electromagnetic communication: molecular communication is potentially biocompatible and inherently energy-efficient. Recently, several studies have modeled receivers in diffusion-based molecular communication systems as "perfectly monitoring" or "perfectly absorbing" spheres based on idealized descriptions of chemoreception. In this paper, we focus on perfectly absorbing receivers and present methods to improve the accuracy of simulation procedures that are used to analyze these receivers. We employ schemes available from the chemical physics and biophysics literature and outline a Monte Carlo simulation algorithm that accounts for the possibility of molecule absorption during discrete time steps, leading to a more accurate analysis of absorption probabilities. Unlike most existing studies that consider a single receiver, this paper analyzes absorption probabilities for multiple receivers deterministically or randomly deployed in a region. For random deployments, the ultimate absorption probabilities as a function of transmitter-receiver distance are shown to fit well to power laws; the exponents derived become more negative as the number of receivers increases up to a limit beyond which no additional receivers can be "packed" in the deployment region. This paper is expected to impact the design of molecular nanonetworks with multiple absorbing receivers.

Nonlinear photothermal mid-infrared spectroscopy

NASA Astrophysics Data System (ADS)

Totachawattana, Atcha; Erramilli, Shyamsunder; Sander, Michelle Y.

2016-10-01

Mid-infrared photothermal spectroscopy is a pump-probe technique for label-free and non-destructive sample characterization by targeting intrinsic vibrational modes. In this method, the mid-infrared pump beam excites a temperature-induced change in the refractive index of the sample. This laser-induced change in the refractive index is measured by a near-infrared probe laser using lock-in detection. At increased pump powers, emerging nonlinear phenomena not previously demonstrated in other mid-infrared techniques are observed. Nonlinear study of a 6 μm-thick 4-Octyl-4'-Cyanobiphenyl (8CB) liquid crystal sample is conducted by targeting the C=C stretching band at 1606 cm-1. At high pump powers, nonlinear signal enhancement and multiple pitchfork bifurcations of the spectral features are observed. An explanation of the nonlinear peak splitting is provided by the formation of bubbles in the sample at high pump powers. The discontinuous refractive index across the bubble interface results in a decrease in the forward scatter of the probe beam. This effect can be recorded as a bifurcation of the absorption peak in the photothermal spectrum. These nonlinear effects are not present in direct measurements of the mid-infrared beam. Evolution of the nonlinear photothermal spectrum of 8CB liquid crystal with increasing pump power shows enhancement of the absorption peak at 1606 cm-1. Multiple pitchfork bifurcations and spectral narrowing of the photothermal spectrum are demonstrated. This novel nonlinear regime presents potential for improved spectral resolution as well as a new regime for sample characterization in mid-infrared photothermal spectroscopy.

The application of feature selection to the development of Gaussian process models for percutaneous absorption.

PubMed

Lam, Lun Tak; Sun, Yi; Davey, Neil; Adams, Rod; Prapopoulou, Maria; Brown, Marc B; Moss, Gary P

2010-06-01

The aim was to employ Gaussian processes to assess mathematically the nature of a skin permeability dataset and to employ these methods, particularly feature selection, to determine the key physicochemical descriptors which exert the most significant influence on percutaneous absorption, and to compare such models with established existing models. Gaussian processes, including automatic relevance detection (GPRARD) methods, were employed to develop models of percutaneous absorption that identified key physicochemical descriptors of percutaneous absorption. Using MatLab software, the statistical performance of these models was compared with single linear networks (SLN) and quantitative structure-permeability relationships (QSPRs). Feature selection methods were used to examine in more detail the physicochemical parameters used in this study. A range of statistical measures to determine model quality were used. The inherently nonlinear nature of the skin data set was confirmed. The Gaussian process regression (GPR) methods yielded predictive models that offered statistically significant improvements over SLN and QSPR models with regard to predictivity (where the rank order was: GPR > SLN > QSPR). Feature selection analysis determined that the best GPR models were those that contained log P, melting point and the number of hydrogen bond donor groups as significant descriptors. Further statistical analysis also found that great synergy existed between certain parameters. It suggested that a number of the descriptors employed were effectively interchangeable, thus questioning the use of models where discrete variables are output, usually in the form of an equation. The use of a nonlinear GPR method produced models with significantly improved predictivity, compared with SLN or QSPR models. Feature selection methods were able to provide important mechanistic information. However, it was also shown that significant synergy existed between certain parameters, and as such it was possible to interchange certain descriptors (i.e. molecular weight and melting point) without incurring a loss of model quality. Such synergy suggested that a model constructed from discrete terms in an equation may not be the most appropriate way of representing mechanistic understandings of skin absorption.

Distribution of hydrothermally altered rocks in the Reko Diq, Pakistan mineralized area based on spectral analysis of ASTER data

USGS Publications Warehouse

Rowan, L.C.; Schmidt, R.G.; Mars, J.C.

2006-01-01

The Reko Diq, Pakistan mineralized study area, approximately 10??km in diameter, is underlain by a central zone of hydrothermally altered rocks associated with Cu-Au mineralization. The surrounding country rocks are a variable mixture of unaltered volcanic rocks, fluvial deposits, and eolian quartz sand. Analysis of 15-band Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data of the study area, aided by laboratory spectral reflectance and spectral emittance measurements of field samples, shows that phyllically altered rocks are laterally extensive, and contain localized areas of argillically altered rocks. In the visible through shortwave-infrared (VNIR + SWIR) phyllically altered rocks are characterized by Al-OH absorption in ASTER band 6 because of molecular vibrations in muscovite, whereas argillically altered rocks have an absorption feature in band 5 resulting from alunite. Propylitically altered rocks form a peripheral zone and are present in scattered exposures within the main altered area. Chlorite and muscovite cause distinctive absorption features at 2.33 and 2.20????m, respectively, although less intense 2.33????m absorption is also present in image spectra of country rocks. Important complementary lithologic information was derived by analysis of the spectral emittance data in the 5 thermal-infrared (TIR) bands. Silicified rocks were not distinguished in the 9 VNIR + SWIR bands because of the lack of diagnostic spectral absorption features in quartz in this wavelength region. Quartz-bearing surficial deposits, as well as hydrothermally silicified rocks, were mapped in the TIR bands by using a band 13/band 12 ratio image, which is sensitive to the intensity of the quartz reststrahlen feature. Improved distinction between the quartzose surficial deposits and silicified bedrock was achieved by using matched-filter processing with TIR image spectra for reference. ?? 2006 Elsevier Inc. All rights reserved.

Characterization of Yb{sup 3+}:Sr{sub 5{minus}x}Ba{sub x}(PO{sub 4}){sub 3}F crystals for diode pumped lasers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bayramian, A.J.; Marshall, C.D.; Schaffers, K.I.

Ytterbium-doped Sr{sub 5}(PO{sub 4}){sub 3}F (S-FAP) has been shown to be a useful material for diode pumping, since it displays high gain, low loss, and a long radiative lifetime. One of the issues with S-FAP is that it has a relatively narrow absorption bandwidth ({approximately}5 nm) at 900 nm, the diode-pumping wavelength, while the diode`s output bandwidth can be large ({approximately}10 nm). By changing the host slightly, the absorption feature can be broadened to better match the pump bandwidth. Four mixed crystal boules of Yb{sup 3+}:Sr{sub 5{minus}x}Ba{sub x}(PO{sub 4}){sub 3}F were grown by the Czochralski method with x = 0.25,more » 0.5, 1, and 2. The bandwidth of the 900-nm absorption feature was found to grow with increasing barium concentration from 4.7 nm to a maximum of 15.9 nm. Emission spectra showed a similar bandwidth increase with barium content from 4.9 nm to a maximum of 10 nm. Emission cross sections for these materials were deduced by the methods of reciprocity, the Einstein method, and small-signal gain. The absorption feature`s homogeneity was probed using a tunable pump source which qualitatively showed that the barium-broadened lines were at least partly inhomogeneous. Each of these materials lased with a variety of output couplers. This family of materials was found to provide suitable laser hosts where a broader absorption and/or emission bandwidth is desired.« less

Light-induced radical formation and isomerization of an aromatic thiol in solution followed by time-resolved x-ray absorption spectroscopy at the sulfur K-edge

DOE PAGES

Ochmann, Miguel; von Ahnen, Inga; Cordones, Amy A.; ...

2017-02-20

Here, we applied time-resolved sulfur-1s absorption spectroscopy to a model aromatic thiol system as a promising method for tracking chemical reactions in solution. Sulfur-1s absorption spectroscopy allows tracking multiple sulfur species with a time resolution of ~70 ps at synchrotron radiation facilities. Experimental transient spectra combined with high-level electronic structure theory allow identification of a radical and two thione isomers, which are generated upon illumination with 267 nm radiation. Moreover, the regioselectivity of the thione isomerization is explained by the resulting radical frontier orbitals. This work demonstrates the usefulness and potential of time-resolved sulfur-1s absorption spectroscopy for tracking multiple chemicalmore » reaction pathways and transient products of sulfur-containing molecules in solution.« less

Light-induced radical formation and isomerization of an aromatic thiol in solution followed by time-resolved x-ray absorption spectroscopy at the sulfur K-edge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ochmann, Miguel; von Ahnen, Inga; Cordones, Amy A.

Here, we applied time-resolved sulfur-1s absorption spectroscopy to a model aromatic thiol system as a promising method for tracking chemical reactions in solution. Sulfur-1s absorption spectroscopy allows tracking multiple sulfur species with a time resolution of ~70 ps at synchrotron radiation facilities. Experimental transient spectra combined with high-level electronic structure theory allow identification of a radical and two thione isomers, which are generated upon illumination with 267 nm radiation. Moreover, the regioselectivity of the thione isomerization is explained by the resulting radical frontier orbitals. This work demonstrates the usefulness and potential of time-resolved sulfur-1s absorption spectroscopy for tracking multiple chemicalmore » reaction pathways and transient products of sulfur-containing molecules in solution.« less

On the nature of the nova-like variable CD-42 deg 14462

NASA Technical Reports Server (NTRS)

Guinan, E. F.; Sion, E. M.

1981-01-01

Low dispersion long and short wavelength IUE spectra of the nova like system CD-42 deg 14462 were obtained on August 24 U.T. The short wave spectrum exhibits absorption features due to C III (lambda 1175), Lalpha 1216), NV (lambda1240), HeII (lambda 1640), SiIV (lambda1394), NIV (lambda1875) with CIV (lambda1550) as a P Cygni feature with blue shifted absorption suggesting the presence of material leaving the system. Possible interpretations of this object are discussed.

Effects of absorption on multiple scattering by random particulate media: exact results.

PubMed

Mishchenko, Michael I; Liu, Li; Hovenier, Joop W

2007-10-01

We employ the numerically exact superposition T-matrix method to perform extensive computations of elec nottromagnetic scattering by a volume of discrete random medium densely filled with increasingly absorbing as well as non-absorbing particles. Our numerical data demonstrate that increasing absorption diminishes and nearly extinguishes certain optical effects such as depolarization and coherent backscattering and increases the angular width of coherent backscattering patterns. This result corroborates the multiple-scattering origin of such effects and further demonstrates the heuristic value of the concept of multiple scattering even in application to densely packed particulate media.

Doppler-free satellites of resonances of electromagnetically induced transparency and absorption on the D 2 lines of alkali metals

NASA Astrophysics Data System (ADS)

Sargsyan, A.; Sarkisyan, D.; Staedter, D.; Akulshin, A. M.

2006-11-01

The peculiarities of intra-Doppler structures that are observed in the atomic absorption spectrum of alkali metals with the help of two independent lasers have been studied. These structures accompany ultranarrow coherent resonances of electromagnetically induced transparency and absorption. With the D 2 line of rubidium taken as an example, it is shown that, in the scheme of unidirectional waves, the maximum number of satellite resonances caused by optical pumping selective with respect to the atomic velocity is equal to seven, while only six resonances are observed in the traditional scheme of saturated absorption with counterpropagating waves of the same frequency. The spectral position of the resonances and their polarity depend on the frequency of the saturating radiation, while their number and relative amplitude depend also on the experimental geometry. These features are of general character and should show themselves in the absorption spectrum on the D 2 lines of all alkali metals. An explanation of these features is given. The calculated spectral separations between the resonances are compared to the experimental ones, and their possible application is discussed.

Laser Absorption by Over-Critical Plasmas

NASA Astrophysics Data System (ADS)

May, J.; Tonge, J.; Fiuza, F.; Fonseca, R. A.; Silva, L. O.; Mori, W. B.

2015-11-01

Absorption of high intensity laser light by matter has important applications to emerging sciences and technology, such as Fast Ignition ICF and ion acceleration. As such, understanding the underlying mechanisms of this absorption is key to developing these technologies. Critical features which distinguish the interaction of high intensity light - defined here as a laser field having a normalized vector potential greater than unity - are that the reaction of the material to the fields results in sharp high-density interfaces; and that the movement of the electrons is in general relativistic, both in a fluid and a thermal sense. The results of these features are that the absorption mechanisms are qualitatively distinct from those at lower intensities. We will review previous work, by our group and others, on the absorption mechanisms, and highlight current research. We will show that the standing wave structure of the reflected laser light is key to particle dynamics for normally incident lasers. The authors acknowledge the support of the Department of Energy under contract DE-NA 0001833 and the National Science Foundation under contract ACI 1339893.

Numerical indicators of absorption spectra of green leaf extract obtained from plants of different life forms.

PubMed

Koldaev, Vladimir M; Manyakhin, Artem Yu

2018-06-05

The study was carried out using 58 species of terrestrial plants of different life forms at the start of their fruiting stage. Photoreceptive systems of the leaves were assessed by means of unconventional numerical indicators of absorption spectra, relative photoabsorption coefficient, photosynthetic pigments' integral absorption intensity and relative absorption intensity coefficient. As the study showed, the leaves of all trees and light-demanding grasses favoring open spaces, which were subjected to the study were featured by the lowest values of numerical indicators of absorption spectra (NIAS). Shade-demanding grasses, which grow beneath the canopy, by contrast, were featured by the highest NIAS values. These values of the shrub leaves were in between those of light-demanding plants and shade-demanding ones. The results obtained are consistent with modern visions concerning the biochemistry and the physiology of plants' photoreceptive system. It is appropriate to apply the NIAS, which were used in this study and reflect a leaf's photoreceptive properties, as spectrophotometric criteria for monitoring and environmental management of natural plant resources and agricultural plants. Copyright © 2018 Elsevier B.V. All rights reserved.

On the state of the emitter of the 3.3 micron unidentified infrared band - Absorption spectroscopy of polycyclic aromatic hydrocarbon species

NASA Technical Reports Server (NTRS)

Flickinger, Gregory C.; Wdowiak, Thomas J.; Gomez, Percy L.

1991-01-01

Results of absorption measurements indicate that the PAH species responsible for the UIR (unidentified infrared) emission probably exist in a condensed form rather than as isolated molecules. It is shown that the peak absorption of the C-H stretch feature of vapor-phase PAHs occurs at a higher frequency than that of the condensed-phase PAHs and does not match the 3.289-micron interstellar feature. The vapor-phase experiments duplicate the phenomenon of the 3.3-micron profile simplification of PAH in KBr at elevated temperature. This confirms that the change of the profile with temperature is an intrinsic molecular effect, and is not a consequence of matrix (KBr) or condensed state interactions.

The relative importance of aerosol scattering and absorption in remote sensing

NASA Technical Reports Server (NTRS)

Fraser, R. S.; Kaufman, Y. J.

1985-01-01

Previous attempts to explain the effect of aerosols on satellite measurements of surface properties for the visible and near-infrared spectrum have emphasized the amount of aerosols without consideration of their absorption properties. In order to estimate the importance of absorption, the radiances of the sunlight scattered from models of the earth-atmosphere system are computed as functions of the aerosol optical thickness and absorption. The absorption effect is small where the surface reflectance is weak, but is important for strong reflectance. These effects on classification of surface features, measuring vegetation index, and measuring surface reflectance are presented.

Three-dimensionally patterned energy absorptive material and method of fabrication

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duoss, Eric; Frank, James M.; Kuntz, Joshua

A three-dimensionally patterned energy absorptive material and fabrication method having multiple layers of patterned filaments extrusion-formed from a curable pre-cursor material and stacked and cured in a three-dimensionally patterned architecture so that the energy absorptive material produced thereby has an engineered bulk property associated with the three-dimensionally patterned architecture.

Spectral decomposition of AVIRIS data

NASA Technical Reports Server (NTRS)

Gaddis, Lisa; Soderblom, Laurence; Kieffer, Hugh; Becker, Kris; Torson, Jim; Mullins, Kevin

1993-01-01

A set of techniques is presented that uses only information contained within a raw Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) scene to estimate and to remove additive components such as multiple scattering and instrument dark current. Multiplicative components (instrument gain, topographic modulation of brightness, atmospheric transmission) can then be normalized, permitting enhancement, extraction, and identification of relative reflectance information related to surface composition and mineralogy. The technique for derivation of additive-component spectra from a raw AVIRIS scene is an adaption of the 'regression intersection method' of Crippen. This method uses two surface units that are spatially extensive, and located in rugged terrain. For a given wavelength pair, subtraction of the derived additive component from individual band values will remove topography in both regions in a band/band ratio image. Normalization of all spectra in the scene to the average scene spectrum then results in cancellation of multiplicative components and production of a relative-reflectance scene. The resulting AVIRIS product contains relative-reflectance features due to mineral absorption that depart from the average spectrum. These features commonly are extremely weak and difficult to recognize, but they can be enhanced by using two simple 3-D image-processing tools. The validity of these techniques will be demonstrated by comparisons between relative-reflectance AVIRIS spectra and those derived by using JPL standard calibrations. The AVIRIS data used in this analysis were acquired over the Kelso Dunes area (34 deg 55' N, 115 deg 43' W) of the eastern Mojave Desert, CA (in 1987) and the Upheaval Dome area (38 deg 27' N, 109 deg 55' W) of the Canyonlands National Park, UT (in 1991).

Detection of water and/or hydroxyl on asteroid (16) Psyche

USGS Publications Warehouse

Takir, Driss; Reddy, Vishnu; Sanchez, Juan A.; Shepard, Michael K.; Emery, Joshua P.

2016-01-01

In order to search for evidence of hydration on M-type asteroid (16) Psyche, we observed this object in the 3 μm spectral region using the long-wavelength cross-dispersed (LXD: 1.9–4.2 μm) mode of the SpeX spectrograph/imager at the NASA Infrared Telescope Facility. Our observations show that Psyche exhibits a 3 μm absorption feature, attributed to water or hydroxyl. The 3 μm absorption feature is consistent with the hydration features found on the surfaces of water-rich asteroids, attributed to OH- and/or H2O-bearing phases (phyllosilicates). The detection of a 3 μm hydration absorption band on Psyche suggests that this asteroid may not be a metallic core, or it could be a metallic core that has been impacted by carbonaceous material over the past 4.5 Gyr. Our results also indicate rotational spectral variations, which we suggest reflect heterogeneity in the metal/silicate ratio on the surface of Psyche.

Detection of Water and/or Hydroxyl on Asteroid (16) Psyche

NASA Astrophysics Data System (ADS)

Takir, Driss; Reddy, Vishnu; Sanchez, Juan A.; Shepard, Michael K.; Emery, Joshua P.

2017-01-01

In order to search for evidence of hydration on M-type asteroid (16) Psyche, we observed this object in the 3 μm spectral region using the long-wavelength cross-dispersed (LXD: 1.9-4.2 μm) mode of the SpeX spectrograph/imager at the NASA Infrared Telescope Facility. Our observations show that Psyche exhibits a 3 μm absorption feature, attributed to water or hydroxyl. The 3 μm absorption feature is consistent with the hydration features found on the surfaces of water-rich asteroids, attributed to OH- and/or H2O-bearing phases (phyllosilicates). The detection of a 3 μm hydration absorption band on Psyche suggests that this asteroid may not be a metallic core, or it could be a metallic core that has been impacted by carbonaceous material over the past 4.5 Gyr. Our results also indicate rotational spectral variations, which we suggest reflect heterogeneity in the metal/silicate ratio on the surface of Psyche.

DETECTION OF WATER AND/OR HYDROXYL ON ASTEROID (16) Psyche

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takir, Driss; Reddy, Vishnu; Sanchez, Juan A.

In order to search for evidence of hydration on M-type asteroid (16) Psyche, we observed this object in the 3 μ m spectral region using the long-wavelength cross-dispersed (LXD: 1.9–4.2 μ m) mode of the SpeX spectrograph/imager at the NASA Infrared Telescope Facility. Our observations show that Psyche exhibits a 3 μ m absorption feature, attributed to water or hydroxyl. The 3 μ m absorption feature is consistent with the hydration features found on the surfaces of water-rich asteroids, attributed to OH- and/or H{sub 2}O-bearing phases (phyllosilicates). The detection of a 3 μ m hydration absorption band on Psyche suggestsmore » that this asteroid may not be a metallic core, or it could be a metallic core that has been impacted by carbonaceous material over the past 4.5 Gyr. Our results also indicate rotational spectral variations, which we suggest reflect heterogeneity in the metal/silicate ratio on the surface of Psyche.« less

Stochastic parameterization for light absorption by internally mixed BC/dust in snow grains for application to climate models

NASA Astrophysics Data System (ADS)

Liou, K. N.; Takano, Y.; He, C.; Yang, P.; Leung, L. R.; Gu, Y.; Lee, W. L.

2014-06-01

A stochastic approach has been developed to model the positions of BC (black carbon)/dust internally mixed with two snow grain types: hexagonal plate/column (convex) and Koch snowflake (concave). Subsequently, light absorption and scattering analysis can be followed by means of an improved geometric-optics approach coupled with Monte Carlo photon tracing to determine BC/dust single-scattering properties. For a given shape (plate, Koch snowflake, spheroid, or sphere), the action of internal mixing absorbs substantially more light than external mixing. The snow grain shape effect on absorption is relatively small, but its effect on asymmetry factor is substantial. Due to a greater probability of intercepting photons, multiple inclusions of BC/dust exhibit a larger absorption than an equal-volume single inclusion. The spectral absorption (0.2-5 µm) for snow grains internally mixed with BC/dust is confined to wavelengths shorter than about 1.4 µm, beyond which ice absorption predominates. Based on the single-scattering properties determined from stochastic and light absorption parameterizations and using the adding/doubling method for spectral radiative transfer, we find that internal mixing reduces snow albedo substantially more than external mixing and that the snow grain shape plays a critical role in snow albedo calculations through its forward scattering strength. Also, multiple inclusion of BC/dust significantly reduces snow albedo as compared to an equal-volume single sphere. For application to land/snow models, we propose a two-layer spectral snow parameterization involving contaminated fresh snow on top of old snow for investigating and understanding the climatic impact of multiple BC/dust internal mixing associated with snow grain metamorphism, particularly over mountain/snow topography.

Determining CDOM Absorption Spectra in Diverse Coastal Environments Using a Multiple Pathlength, Liquid Core Waveguide System. Measuring the Absorption of CDOM in the Field Using a Multiple Pathlength Liquid Waveguide System

NASA Technical Reports Server (NTRS)

Miller, Richard L.; Belz, Mathias; DelCastillo, Carlos; Trzaska, Rick

2000-01-01

We evaluated the accuracy, sensitivity and precision of a multiple pathlength, liquid core waveguide (MPLCW) system for measuring colored dissolved organic matter (CDOM) absorption in the UV-visible spectral range (370-700 nm). The MPLCW has four optical paths (2.0, 9.8, 49.3, and 204 cm) coupled to a single Teflon AF sample cell. Water samples were obtained from inland, coastal and ocean waters ranging in salinity from 0 to 36 PSU. Reference solutions for the MPLCW were made having a refractive index of the sample. CDOM absorption coefficients, a(sub CDOM), and the slope of the log-linearized absorption spectra, S, were compared with values obtained using a dual-beam spectrophotometer. Absorption of phenol red secondary standards measured by the MPLCW at 558 nm were highly correlated with spectrophotometer values (r > 0.99) and showed a linear response across all four pathlengths. Values of a(sub CDOM) measured using the MPLCW were virtually identical to spectrophotometer values over a wide range of concentrations. The dynamic range of a(sub CDOM) for MPLCW measurements was 0.002 - 231.5/m. At low CDOM concentrations (a(sub 370) < 0.1/m) spectrophotometric a(sub CDOM) were slightly greater than MPLCW values and showed larger fluctuations at longer wavelengths due to limitations in instrument precision. In contrast, MPLCW spectra followed an exponential to 600 nm for all samples. The maximum deviation in replicate MPLCW spectra was less than 0.001 absorbance units. The portability, sampling, and optical characteristics of a MPLCW system provide significant enhancements for routine CDOM absorption measurements in a broad range of natural waters.

Stochastic Parameterization for Light Absorption by Internally Mixed BC/dust in Snow Grains for Application to Climate Models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liou, K. N.; Takano, Y.; He, Cenlin

2014-06-27

A stochastic approach to model the positions of BC/dust internally mixed with two snow-grain types has been developed, including hexagonal plate/column (convex) and Koch snowflake (concave). Subsequently, light absorption and scattering analysis can be followed by means of an improved geometric-optics approach coupled with Monte Carlo photon tracing to determine their single-scattering properties. For a given shape (plate, Koch snowflake, spheroid, or sphere), internal mixing absorbs more light than external mixing. The snow-grain shape effect on absorption is relatively small, but its effect on the asymmetry factor is substantial. Due to a greater probability of intercepting photons, multiple inclusions ofmore » BC/dust exhibit a larger absorption than an equal-volume single inclusion. The spectral absorption (0.2 – 5 um) for snow grains internally mixed with BC/dust is confined to wavelengths shorter than about 1.4 um, beyond which ice absorption predominates. Based on the single-scattering properties determined from stochastic and light absorption parameterizations and using the adding/doubling method for spectral radiative transfer, we find that internal mixing reduces snow albedo more than external mixing and that the snow-grain shape plays a critical role in snow albedo calculations through the asymmetry factor. Also, snow albedo reduces more in the case of multiple inclusion of BC/dust compared to that of an equal-volume single sphere. For application to land/snow models, we propose a two-layer spectral snow parameterization containing contaminated fresh snow on top of old snow for investigating and understanding the climatic impact of multiple BC/dust internal mixing associated with snow grain metamorphism, particularly over mountains/snow topography.« less

Multiple origins for the DLA at zabs = 0.313 toward PKS 1127-145 indicated by a complex dust depletion pattern of Ca, Ti, and Mn

NASA Astrophysics Data System (ADS)

Guber, C. R.; Richter, P.; Wendt, M.

2018-01-01

Aims: We aim to investigate the dust depletion properties of optically thick gas in and around galaxies and its origin we study in detail the dust depletion patterns of Ti, Mn, and Ca in the multi-component damped Lymanα (DLA) absorber at zabs = 0.313 toward the quasar PKS 1127-145. Methods: We performed a detailed spectral analysis of the absorption profiles of Ca II, Mn II, Ti II, and Na I associated with the DLA toward PKS 1127-145, based on optical high-resolution data obtained with the UVES instrument at the Very Large Telescope. We obtained column densities and Doppler-parameters for the ions listed above and determine their gas-phase abundances, from which we conclude on their dust depletion properties. We compared the Ca and Ti depletion properties of this DLA with that of other DLAs. Results: One of the six analyzed absorption components (component 3) shows a striking underabundance of Ti and Mn in the gas-phase, indicating the effect of dust depletion for these elements and a locally enhanced dust-to-gas ratio. In this DLA and in other similar absorbers, the Mn II abundance follows that of Ti II very closely, implying that both ions are equally sensitive to the dust depletion effects. Conclusions: Our analysis indicates that the DLA toward PKS 1127-145 has multiple origins. With its narrow line width and its strong dust depletion, component 3 points toward the presence of a neutral gas disk from a faint LSB galaxy in front of PKS 1127-145, while the other, more diffuse and dust-poor, absorption components possibly are related to tidal gas features from the interaction between the various, optically confirmed galaxy-group members. In general, the Mn/Ca II ratio in sub-DLAs and DLAs possibly serves as an important indicator to discriminate between dust-rich and dust-poor in neutral gas in and around galaxies.

H I absorption in nearby compact radio galaxies

NASA Astrophysics Data System (ADS)

Glowacki, M.; Allison, J. R.; Sadler, E. M.; Moss, V. A.; Curran, S. J.; Musaeva, A.; Deng, C.; Parry, R.; Sligo, M. C.

2017-05-01

H I absorption studies yield information on both active galactic nucleus (AGN) feeding and feedback processes. This AGN activity interacts with the neutral gas in compact radio sources, which are believed to represent the young or recently re-triggered AGN population. We present the results of a survey for H I absorption in a sample of 66 compact radio sources at 0.040 < z < 0.096 with the Australia Telescope Compact Array. In total, we obtained seven detections, five of which are new, with a large range of peak optical depths (3-87 per cent). Of the detections, 71 per cent exhibit asymmetric, broad (ΔvFWHM > 100 km s-1) features, indicative of disturbed gas kinematics. Such broad, shallow and offset features are also found within low-excitation radio galaxies which is attributed to disturbed circumnuclear gas, consistent with early-type galaxies typically devoid of a gas-rich disc. Comparing mid-infrared colours of our galaxies with H I detections indicates that narrow and deep absorption features are preferentially found in late-type and high-excitation radio galaxies in our sample. These features are attributed to gas in galactic discs. By combining XMM-Newton archival data with 21-cm data, we find support that absorbed X-ray sources may be good tracers of H I content within the host galaxy. This sample extends previous H I surveys in compact radio galaxies to lower radio luminosities and provides a basis for future work exploring the higher redshift universe.

Precise Modelling of Telluric Features in Astronomical Spectra

NASA Astrophysics Data System (ADS)

Seifahrt, A.; Käufl, H. U.; Zängl, G.; Bean, J.; Richter, M.; Siebenmorgen, R.

2010-12-01

Ground-based astronomical observations suffer from the disturbing effects of the Earth's atmosphere. Oxygen, water vapour and a number of atmospheric trace gases absorb and emit light at discrete frequencies, shaping observing bands in the near- and mid-infrared and leaving their fingerprints - telluric absorption and emission lines - in astronomical spectra. The standard approach of removing the absorption lines is to observe a telluric standard star: a time-consuming and often imperfect solution. Alternatively, the spectral features of the Earth's atmosphere can be modelled using a radiative transfer code, often delivering a satisfying solution that removes these features without additional observations. In addition the model also provides a precise wavelength solution and an instrumental profile.

Mid-infrared interferometric variability of DG Tau: implications for the inner-disk structure .

NASA Astrophysics Data System (ADS)

Ábrahám, P.; Varga, J.; Gabányi, K. É.; Chen, L.; Kóspál, Á.; Ratzka, Th.; van Boekel, R.; Mosoni, L.; Henning, Th.

DG Tau is a low-mass young star whose strongly accreting disk shows a variable 10 mu m silicate feature, that may even turn temporarily from emission to absorption. Aiming to find the physical reason of this variability, we analysed multiepoch VLTI/MIDI interferometric observations. We found that the inner disk within 3 au radius exhibits a 10 mu m absorption feature related to amorphous silicate grains, while the outer disk displays a variable crystalline feature in emission, similar in shape to the spectrum of comet Hale-Bopp. The variability may be related to a fluctuating amount of dusty material above the disk surface, possibly due to turbulence.

Correlation between high-resolution remote-sensing imagery and detailed field mapping in Cordilleran Miogeocline

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feldman, S.C.; Taranik, J.V.

1986-05-01

Selected areas were mapped at a scale of 1:6000 in the southern hot Creek Range (south-central Nevada), which is underlain by Paleozoic autochthonous limestone, shale, and sandstone, Paleozoic allochthonous chert and siltstone, and Tertiary rhyolitic to dactitic ash flow tuff. The mapping was compared with computer-processed Airborne Imaging Spectrometer (AIS) data and Landsat Thematic Mapper (TM) imagery. The AIS imagery of the Hot Creek Range was acquired in 1984 by a NASA C-130 aircraft; it has a spatial resolution of 12 m, and swath width of 380 m. The sensor was developed by the Jet Propulsion Laboratory and is themore » first in a series of NASA imaging spectrometers. The AIS collects 128 spectral bands, having a bandwidth of approximately 9 nm, in the short-wave infrared between 1.2 and 2.4 ..mu..m. This part of the spectrum contains important narrow spectral absorption features for the carbonate ion, hydroxyl ion, and water of hydration. Using computer-processed AIS imagery, therefore, the authors can separate calcite from dolomite, and kaolinite from illite and montmorillonite as well as differentiate geologic units containing these minerals. On the AIS imagery, the Upper Mississippian Tripon Pass Limestone shows a distinctive calcite absorption feature at 2.34 ..mu..m; this feature is not as pronounced in Cambrian and Ordovician limestones. The dolomitized Nevada Formation exhibits the dolomite absorption feature at 2.32 ..mu..m. Clay mineral absorption features near 2.2 ..mu..m can be distinguished in altered volcanics. Mineralogic identification was confirmed with field and laboratory spectroradiometer measurements, thin-section examination, and x-ray analysis. AIS results and field mapping were also compared to computer-processed Landsat TM imagery, the highest spectral and spatial resolution worldwide data set currently available.« less

Observational Evidence Linking Interstellar UV Absorption to PAH Molecules

NASA Astrophysics Data System (ADS)

Blasberger, Avi; Behar, Ehud; Perets, Hagai B.; Brosch, Noah; Tielens, Alexander G. G. M.

2017-02-01

The 2175 Å UV extinction feature was discovered in the mid-1960s, yet its physical origin remains poorly understood. One suggestion is absorption by polycyclic aromatic hydrocarbon (PAH) molecules, which is supported by theoretical molecular structure computations and by laboratory experiments. PAHs are positively detected by their 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μm IR emission bands, which are specified by their modes of vibration. A definitive empirical link between the 2175 Å UV extinction and the IR PAH emission bands, however, is still missing. We present a new sample of hot stars that have both 2175 Å absorption and IR PAH emission. We find significant shifts of the central wavelength of the UV absorption feature, up to 2350 Å, but predominantly in stars that also have IR PAH emission. These UV shifts depend on stellar temperature in a fashion that is similar to the shifts of the 6.2 and 7.7 μm IR PAH bands, that is, the features are increasingly more redshifted as the stellar temperature decreases, but only below ˜15 kK. Above 15 kK both UV and IR features retain their nominal values. Moreover, we find a suggestive correlation between the UV and IR shifts. We hypothesize that these similar dependences of both the UV and IR features on stellar temperature hint at a common origin of the two in PAH molecules and may establish the missing link between the UV and IR observations. We further suggest that the shifts depend on molecular size, and that the critical temperature of ˜15 kK above which no shifts are observed is related to the onset of UV-driven hot-star winds and their associated shocks.

Detections and Sensitive Upper Limits for Methane and Related Trace Gases on Mars during 2003-2014, and planned extensions in 2016

NASA Astrophysics Data System (ADS)

Mumma, Michael J.; Villanueva, Geronimo L.; Novak, Robert E.

2015-11-01

Five groups report methane detections on Mars; all results suggest local release and high temporal variability [1-7]. Our team searched for CH4 on many dates and seasons and detected it on several dates [1, 9, 10]. TLS (Curiosity rover) reported methane upper limits [6], and then detections [7] that were consistent in size with earlier reports and that also showed rapid modulation of CH4 abundance.[8] argued that absorption features assigned to Mars 12CH4 by [1] might instead be weak lines of terrestrial 13CH4. If not properly removed, terrestrial 13CH4 signatures would appear on the blue wing of terrestrial 12CH4 even when Mars is red-shifted - but they do not (Fig. S6 of [1]), demonstrating that terrestrial signatures were correctly removed. [9] demonstrated that including the dependence of δ13CH4 with altitude did not affect the residual features, nor did taking δ13CH4 as zero. Were δ13CH4 important, its omission would have overemphasized the depth of 13CH4 terrestrial absorption, introducing emission features in the residual spectra [1]. However, the residual features are seen in absorption, establishing their origin as non-terrestrial - [8] now agrees with this view.We later reported results for multiple organic gases (CH4, CH3OH, H2CO, C2H6, C2H2, C2H4), hydroperoxyl (HO2), three nitriles (N2O, NH3, HCN) and two chlorinated species (HCl, CH3Cl) [9]. Most of these species cannot be detected with current space assets, owing to instrumental limitations (e.g., spectral resolving power). However, the high resolution infrared spectrometers (NOMAD, ACS) on ExoMars 2016 (Trace Gas Orbiter) will begin measurements in late 2016. In solar occultation, TGO sensitivities will far exceed prior capabilities.We published detailed hemispheric maps of H2O and HDO on Mars, inferring the size of a lost early ocean [10]. In 2016, we plan to acquire 3-D spatial maps of HDO and H2O with ALMA, and improved maps of organics with iSHELL/NASA-IRTF.References: [1] Mumma et al. Sci09; [2] Formisano et al. Sci04; [3] Krasnopolsky et al. Icar04; [4] Fonti and Marzo A&A10 [5] Krasnopolsky, Icar12; [6] Webster et al. Sci13; [7] Webster et al. Sci15; [8] Zahnle et al. Icar11; [9] Villanueva et al. Icar13; [10] Villanueva et al. Sci15.

UV laser long-path absorption spectroscopy

NASA Technical Reports Server (NTRS)

Dorn, Hans-Peter; Brauers, Theo; Neuroth, Rudolf

1994-01-01

Long path Differential Optical Absorption Spectroscopy (DOAS) using a picosecond UV laser as a light source was developed in our institute. Tropospheric OH radicals are measured by their rotational absorption lines around 308 nm. The spectra are obtained using a high resolution spectrograph. The detection system has been improved over the formerly used optomechanical scanning device by application of a photodiode array which increased the observed spectral range by a factor of 6 and which utilizes the light much more effectively leading to a considerable reduction of the measurement time. This technique provides direct measurements of OH because the signal is given by the product of the absorption coefficient and the OH concentration along the light path according to Lambert-Beers law. No calibration is needed. Since the integrated absorption coefficient is well known the accuracy of the measurement essentially depends on the extent to which the OH absorption pattern can be detected in the spectra. No interference by self generated OH radicals in the detection lightpath has been observed. The large bandwidth (greater than 0.15 nm) and the high spectral resolution (1.5 pm) allows absolute determination of interferences by other trace gas absorptions. The measurement error is directly accessible from the absorption-signal to baseline-noise ratio in the spectra. The applicability of the method strongly depends on visibility. Elevated concentrations of aerosols lead to considerable attenuation of the laser light which reduces the S/N-ratio. In the moderately polluted air of Julich, where we performed a number of OH measurement spectra. In addition absorption features of unidentified species were frequently detected. A quantitative deconvolution even of the known species is not easy to achieve and can leave residual structures in the spectra. Thus interferences usually increase the noise and deteriorate the OH detection sensitivity. Using diode arrays for sensitive absorption measurements some specific problems of those detectors have to be solved experimentally (i.e. fixed pattern noise, dark signal noise, nonuniform efficiency of individual elements, spatial sensitivity variations). In order to improve the low spatial resolution we performed laboratory studies using a multiple reflection cell to convert the long path technique to a real in situ point measurement. Under the conditions of field experiments in Julich residual absorbance signals at present are about 1.5x10(exp -4) corresponding to an OH detection sensitivity of 2x10(exp 6) OH/cm(exp 3) using a light path of 5.8 km. Total integration times for one measurement point vary between a few minutes and an hour.

Search for volatiles on icy satellites. I. Europa

USGS Publications Warehouse

Brown, R.H.; Cruikshank, D.P.; Tokunaga, A.T.; Smith, R.G.; Clark, R.N.

1988-01-01

New reflectance spectra have been obtained for both the leading and trailing sides of Europa, using the Cooled Grating Array Spectrometer (CGAS) of the NASA Infrared Telescope Facility (IRTF). The spectra are of higher precision than any yet obtained. Spectra of Europa's trailing side (central meridian longitude ???300??) obtained in 1985 show two weak absorptions near 2.2 and 2.3 ??m. Both of these features as well as others are seen in spectra obtained by R. N. Clark, R. B. Singer, P. D. Owensby, and F.P. Fanale (1980a, Bull. Amer. Astron. Soc. 12, 713-714) at similar central meridian longitude. Data obtained with an improved detector array in 1986, however, do not show the absorptions seen in the 1980 and 1985 spectra. It is not clear why the newest data do not show the apparent absorptions seen in previous years, but the suggestion is that either the 1980 and 1985 data are spurious or that the material responsible for the weak absorptions is no longer detectable. Analysis of the 1980 and 1985 data did not reveal any obvious source of systematic error capable of introducing spurious features, but we are skeptical of any explanation that cites transient deposition, movement, and/or destruction of material on Europa's trailing side to account for the nondetection of the features in the 1986 data. If the weak absorptions seen in the 1980 and 1985 data are real, they can be interpreted as indicating the transient spectroscopic presence of a molecular component on Europa's trailing side different from the water ice that is known to be the dominant surface constituent. Further monitoring is required to determine if the apparent absorptions are real. ?? 1988.

Influence of multiple scattering and absorption on the full scattering profile and the isobaric point in tissue

NASA Astrophysics Data System (ADS)

Duadi, Hamootal; Fixler, Dror

2015-05-01

Light reflectance and transmission from soft tissue has been utilized in noninvasive clinical measurement devices such as the photoplethysmograph (PPG) and reflectance pulse oximeter. Incident light on the skin travels into the underlying layers and is in part reflected back to the surface, in part transferred and in part absorbed. Most methods of near infrared (NIR) spectroscopy focus on the volume reflectance from a semi-infinite sample, while very few measure transmission. We have previously shown that examining the full scattering profile (angular distribution of exiting photons) provides more comprehensive information when measuring from a cylindrical tissue. Furthermore, an isobaric point was found which is not dependent on changes in the reduced scattering coefficient. The angle corresponding to this isobaric point depends on the tissue diameter. We investigated the role of multiple scattering and absorption on the full scattering profile of a cylindrical tissue. First, we define the range in which multiple scattering occurs for different tissue diameters. Next, we examine the role of the absorption coefficient in the attenuation of the full scattering profile. We demonstrate that the absorption linearly influences the intensity at each angle of the full scattering profile and, more importantly, the absorption does not change the position of the isobaric point. The findings of this work demonstrate a realistic model for optical tissue measurements such as NIR spectroscopy, PPG, and pulse oximetery.

Lipid-associated Oral Delivery: Mechanisms and Analysis of Oral Absorption Enhancement

PubMed Central

Rezhdo, Oljora; Speciner, Lauren; Carrier, Rebecca L.

2016-01-01

The majority of newly discovered oral drugs are poorly water soluble, and co-administration with lipids has proven effective in significantly enhancing bioavailability of some compounds with low aqueous solubility. Yet, lipid-based delivery technologies have not been widely employed in commercial oral products. Lipids can impact drug transport and fate in the gastrointestinal (GI) tract through multiple mechanisms including enhancement of solubility and dissolution kinetics, enhancement of permeation through the intestinal mucosa, and triggering drug precipitation upon lipid emulsion depletion (e.g., by digestion). The effect of lipids on drug absorption is currently not quantitatively predictable, in part due to the multiple complex dynamic processes that can be impacted by lipids. Quantitative mechanistic analysis of the processes significant to lipid system function and overall impact on drug absorption can aid understanding of drug-lipid interactions in the GI tract and exploitation of such interactions to achieve optimal lipid-based drug delivery. In this review, we discuss the impact of co-delivered lipids and lipid digestion on drug dissolution, partitioning, and absorption in the context of the experimental tools and associated kinetic expressions used to study and model these processes. The potential benefit of a systems-based consideration of the concurrent multiple dynamic processes occurring upon co-dosing lipids and drugs to predict the impact of lipids on drug absorption and enable rational design of lipid-based delivery systems is presented. PMID:27520734

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

DOEpatents

Cassano, Anthony A.

1985-01-01

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

Multiband and Broadband Absorption Enhancement of Monolayer Graphene at Optical Frequencies from Multiple Magnetic Dipole Resonances in Metamaterials

NASA Astrophysics Data System (ADS)

Liu, Bo; Tang, Chaojun; Chen, Jing; Xie, Ningyan; Tang, Huang; Zhu, Xiaoqin; Park, Gun-sik

2018-05-01

It is well known that a suspended monolayer graphene has a weak light absorption efficiency of about 2.3% at normal incidence, which is disadvantageous to some applications in optoelectronic devices. In this work, we will numerically study multiband and broadband absorption enhancement of monolayer graphene over the whole visible spectrum, due to multiple magnetic dipole resonances in metamaterials. The unit cell of the metamaterials is composed of a graphene monolayer sandwiched between four Ag nanodisks with different diameters and a SiO2 spacer on an Ag substrate. The near-field plasmon hybridizations between individual Ag nanodisks and the Ag substrate form four independent magnetic dipole modes, which result into multiband absorption enhancement of monolayer graphene at optical frequencies. When the resonance wavelengths of the magnetic dipole modes are tuned to approach one another by changing the diameters of the Ag nanodisks, a broadband absorption enhancement can be achieved. The position of the absorption band in monolayer graphene can be also controlled by varying the thickness of the SiO2 spacer or the distance between the Ag nanodisks. Our designed graphene light absorber may find some potential applications in optoelectronic devices, such as photodetectors.

Near UV-Visible electronic absorption originating from charged amino acids in a monomeric protein† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00880e

PubMed Central

Prasad, Saumya; Mandal, Imon; Singh, Shubham; Paul, Ashim; Mandal, Bhubaneswar

2017-01-01

Electronic absorption spectra of proteins are primarily characterized over the ultraviolet region (185–320 nm) of the electromagnetic spectrum. While recent studies on peptide aggregates have revealed absorption beyond 350 nm, monomeric proteins lacking aromatic amino acids, disulphide bonds, and active site prosthetic groups are expected to remain optically silent beyond 250 nm. Here, in a joint theoretical and experimental investigation, we report the distinctive UV-Vis absorption spectrum between 250 nm [ε = 7338 M–1 cm–1] and 800 nm [ε = 501 M–1 cm–1] in a synthetic 67 residue protein (α3C), in monomeric form, devoid of aromatic amino acids. Systematic control studies with high concentration non-aromatic amino acid solutions revealed significant absorption beyond 250 nm for charged amino acids which constitute over 50% of the sequence composition in α3C. Classical atomistic molecular dynamics (MD) simulations of α3C reveal dynamic interactions between multiple charged sidechains of Lys and Glu residues present in α3C. Time-dependent density functional theory calculations on charged amino acid residues sampled from the MD trajectories of α3C reveal that the distinctive absorption features of α3C may arise from two different types of charge transfer (CT) transitions involving spatially proximal Lys/Glu amino acids. Specifically, we show that the charged amino (NH3+)/carboxylate (COO–) groups of Lys/Glu sidechains act as electronic charge acceptors/donors for photoinduced electron transfer either from/to the polypeptide backbone or to each other. Further, the sensitivity of the CT spectra to close/far/intermediate range of encounters between sidechains of Lys/Glu owing to the three dimensional protein fold can create the long tail in the α3C absorption profile between 300 and 800 nm. Finally, we experimentally demonstrate the sensitivity of α3C absorption spectrum to temperature and pH-induced changes in protein structure. Taken together, our investigation significantly expands the pool of spectroscopically active biomolecular chromophores and adds an optical 250–800 nm spectral window, which we term ProCharTS (Protein Charge Transfer Spectra), for label free probes of biomolecular structure and dynamics. PMID:28970921

Intraband magneto-optical absorption in InAs/GaAs quantum dots: Orbital Zeeman splitting and the Thomas-Reiche-Kuhn sum rule

NASA Astrophysics Data System (ADS)

Zhang, J.-Z.; Galbraith, I.

2008-05-01

Using perturbation theory, intraband magneto-optical absorption is calculated for InAs/GaAs truncated pyramidal quantum dots in a magnetic field applied parallel to the growth direction z . The effects of the magnetic field on the electronic states as well as the intraband transitions are systematically studied. Selection rules governing the intraband transitions are discussed based on the symmetry properties of the electronic states. While the broadband z -polarized absorption is almost insensitive to the magnetic field, the orbital Zeeman splitting is the dominant feature in the in-plane polarized spectrum. Strong in-plane polarized magneto-absorption features are located in the far-infrared region, while z -polarized absorption occurs at higher frequencies. This is due to the dot geometry (the base length is much larger than the height) yielding different quantum confinement in the vertical and lateral directions. The Thomas-Reiche-Kuhn sum rule, including the magnetic field effect, is applied together with the selection rules to the absorption spectra. The orbital Zeeman splitting depends on both the dot size and the confining potential—the splitting decreases as the dot size or the confining potential decreases. Our calculated Zeeman splittings are in agreement with experimental data.

Broadband ultrafast transient absorption of multiple exciton dynamics in lead sulfide nanocrystals

NASA Astrophysics Data System (ADS)

Gesuele, Felice; Wong, Chee Wei; Sfeir, Matthew; Misewich, James; Koh, Weonkyu; Murray, Christopher

2011-03-01

Multiple exciton generation (MEG) is under intense investigation as potential third-generation solar photovoltaics with efficiencies beyond the Shockley-Queisser limit. We examine PbS nanocrystals, dispersed and vigorously stirred in TCE solution, by means of supercontinuum femtosecond transient absorption (TA). TA spectra show the presence of first and second order bleaches for the 1Sh-Se and 1Ph-Pe excitonic transition while photoinduced absorption for the 1Sh,e-Ph,e transitions. We found evidence of carrier multiplication (MEG for single absorbed photon) from the analysis of the first and second order bleaches, in the limit of low number of absorbed photons (Nabs ~ 0.01), for energy three times and four times the Energy gap. The MEG efficiency, derived from the ratio between early-time to long-time TA signal, presents a strongly dispersive behavior with maximum red shifted respect the first absorption peak. Analysis of population dynamics shows that in presence of biexciton, the 1Sh-Se bleach peak is red-shifted indicating a positive binding energy. MEG efficiency estimation will be discussed with regards to spectral integration, correlated higher-order and first excitonic transitions, as well as the nanocrystal morphologies.

Matched-filtering line search methods applied to Suzaku data

NASA Astrophysics Data System (ADS)

Miyazaki, Naoto; Yamada, Shin'ya; Enoto, Teruaki; Axelsson, Magnus; Ohashi, Takaya

2016-12-01

A detailed search for emission and absorption lines and an assessment of their upper limits are performed for Suzaku data. The method utilizes a matched-filtering approach to maximize the signal-to-noise ratio for a given energy resolution, which could be applicable to many types of line search. We first applied it to well-known active galactic nuclei spectra that have been reported to have ultra-fast outflows, and find that our results are consistent with previous findings at the ˜3σ level. We proceeded to search for emission and absorption features in two bright magnetars 4U 0142+61 and 1RXS J1708-4009, applying the filtering method to Suzaku data. We found that neither source showed any significant indication of line features, even using long-term Suzaku observations or dividing their spectra into spin phases. The upper limits on the equivalent width of emission/absorption lines are constrained to be a few eV at ˜1 keV and a few hundreds of eV at ˜10 keV. This strengthens previous reports that persistently bright magnetars do not show proton cyclotron absorption features in soft X-rays and, even if they exist, they would be broadened or much weaker than below the detection limit of X-ray CCD.

The influence of coordination geometry and valency on the K-edge absorption near edge spectra of selected chromium compounds

NASA Astrophysics Data System (ADS)

Pantelouris, A.; Modrow, H.; Pantelouris, M.; Hormes, J.; Reinen, D.

2004-05-01

X-ray absorption spectra at the chromium K-edge are reported for a number of selected chromium compounds of known chemical structure. The spectra were obtained with use of synchrotron radiation available at the ELectron Stretcher Accelerator ELSA in Bonn. The compounds studied include the tetrahedrally coordinated compounds Ca 2Ge 0.8Cr 0.2O 4, Ba 2Ge 0.1Cr 0.9O 4, Sr 2CrO 4, Ca 2(PO 4) x(CrO 4) 1- xCl ( x=0.25,0.5), Ca 5(CrO 4) 3Cl, CrO 3, the octahedrally coordinated compounds Cr(II)-acetate, CrCl 3, CrF 3, Cr 2O 3, KCr(SO 4) 2 · 12H 2O, CrO 2 and cubic coordinated metallic chromium. In these compounds chromium exhibits a wide range of formal oxidation states (0 to VI). The absorption features in the near edge region are shown to be characteristic of the spatial environment of the absorbing atom. The occurrence of a single pre-edge line easily allows one to distinguish between tetrahedral and octahedral coordination geometry, whereas the energy position of the absorption edge is found to be very sensitive to the valency of the excited chromium atom. Calculations of the ionisation potential of Cr in different oxidation states using the non-relativistic Hartree-Fock method (Froese-Fischer) confirm that the ionisation limit shifts to higher energy with increasing Cr valency. More detailed information on the electronic structure of the different compounds is gained by real-space full multiple scattering calculations using the FEFF8 code.

Mineral Physicochemistry based Geoscience Products for Mapping the Earth's Surface and Subsurface

NASA Astrophysics Data System (ADS)

Laukamp, C.; Cudahy, T.; Caccetta, M.; Haest, M.; Rodger, A.; Western Australian Centre of Excellence3D Mineral Mapping

2011-12-01

Mineral maps derived from remotes sensing data can be used to address geological questions about mineral systems important for exploration and mining. This paper focuses on the application of geoscience-tuned multi- and hyperspectral sensors (e.g. ASTER, HyMap) and the methods to routinely create meaningful higher level geoscience products from these data sets. The vision is a 3D mineral map of the earth's surface and subsurface. Understanding the physicochemistry of rock forming minerals and the related diagnostic absorption features in the visible, near, mid and far infrared is a key for mineral mapping. For this, reflectance spectra obtained with lab based visible and infrared spectroscopic (VIRS) instruments (e.g. Bruker Hemisphere Vertex 70) are compared to various remote and proximal sensing techniques. Calibration of the various sensor types is a major challenge with any such comparisons. The spectral resolution of the respective instruments and the band positions are two of the main factors governing the ability to identify mineral groups or mineral species and compositions of those. The routine processing method employed by the Western Australian Centre of Excellence for 3D Mineral Mapping (http://c3dmm.csiro.au) is a multiple feature extraction method (MFEM). This method targets mineral specific absorption features rather than relying on spectral libraries or the need to find pure endmembers. The principle behind MFEM allows us to easily compare hyperspectral surface and subsurface data, laying the foundation for a seamless and accurate 3-dimensional mineral map. The advantage of VIRS techniques for geoscientific applications is the ability to deliver quantitative mineral information over multiple scales. For example, C3DMM is working towards a suite of ASTER-derived maps covering the Australian continent, scheduled for publication in 2012. A suite of higher level geoscience products of Western Australia (e.g. AlOH group abundance and composition) are now available. The multispectral satellite data can be integrated with hyperspectral airborne and drill core data (e.g. HyLogging), which is demonstrated by various case studies ranging from Channel Iron Deposits in the Hamersley Basin (WA) to various Australian orogenic Au deposits. Comparison with airborne and field hyperspectral or lab-based VIRS, as well as independent analyses such as XRD and geochemistry, enables us to deliver cross-calibrated geoscience products derived from the whole suite of geoscience tuned multi- and hyperspectral technologies. Kaolin crystallinity and hematite-goethite ratio for characterization of regolith, and Tschermak substitution in white micas for mapping of chemical gradients associated with hydrothermal ore deposits are a few of the multiple examples where 3D mineral maps can help to resolve geological questions.

Testing the Prediction of Iron Alteration Minerals on Low Albedo Asteroids

NASA Technical Reports Server (NTRS)

Jarvis, K. S.; Vilas, Faith; Howell, E.; Kelley, M.; Cochran, A.

1999-01-01

Absorption features centered near 0.60 - 0.65 and 0.80 - 0.90 micron were identified in the spectra of three low-albedo main-belt (165, 368, 877) and two low-albedo outer-belt (225, 334) asteroids (Vilas et al., Icarus, v. 109,274,1994). The absorption features were attributed to charge transfer transitions in iron alteration minerals such as goethite, hematite, and jarosite, all products of aqueous alteration. Concurrently, Jarvis et al. (LPSC XXIV, 715, 1993) presented additional spectra of low-albedo asteroids that had absorption features centered near 0.60 - 0.65 micron without the longer wavelength feature. Since these two features in iron oxides originate from the same ground state, and the longer wavelength feature requires less energy to exist, the single shorter wavelength feature cannot be caused by the iron alteration minerals. In addition, spectra of minerals such as hematite and goethite show a rapid increase in reflectance beginning near 0.5 micron absent in the low-albedo asteroid spectra. The absence of this rise has been attributed to its suppresion from opaques in the surface material. Spectra on more than one night were available for only one of these five asteroids, 225 Henrietta, and showed good repeatability of the 0.65-micron feature. We have acquired additional spectra of all five asteroids in order to test the repeatability of the 0.65-micron feature, and the presence and repeatability of the features centered near 0.8 - 0.9 micron. We specifically will test the possibility that longer wavelength features could be caused by incomplete removal of telluric water. Asteroid 877 Walkure is a member of the Nysa-Hertha family, and will be compared to spectra of other members of that family. Data were acquired in 1996 and 1999 on the 2.1-m telescope with a facility cassegrain spectrograph, McDonald Observatory, Univ. Of Texas, and the 1.5-m telescope with facility cassegrain spectrograph at CTIO. This research is supported by the NASA Planetary Astronomy Program.

Near-infrared spectroscopy of the proto-planetary nebula CRL 618 and the origin of the hydrocarbon dust component in the interstellar medium.

PubMed

Chiar, J E; Pendleton, Y J; Geballe, T R; Tielens, A G

1998-11-01

A new 2.8-3.8 micrometers spectrum of the carbon-rich protoplanetary nebula CRL 618 confirms the previous detection of a circumstellar 3.4 micrometers absorption feature in this object (Lequeux & Jourdain de Muizon). The high resolution and high signal-to-noise ratio of our spectrum allow us to derive the detailed profile of this absorption feature, which is very similar to that observed in the spectrum of the Galactic center and also resembles the strong 3.4 micrometers emission feature in some post-asymptotic giant branch stars. A weak 3.3 micrometers unidentified infrared band, marginally detected in the CRL 618 spectrum of Lequeux & Jourdain de Muizon, is present in our spectrum. The existence of the 3.4 micrometers feature implies the presence of relatively short-chained, aliphatic hydrocarbon materials (-CH2-/-CH3 approximately = 2-2.5) in the circumstellar environment around CRL 618. It also implies that the carriers of the interstellar 3.4 micrometers feature are produced at least in part in circumstellar material, and it calls into question whether any are produced by the processing of interstellar ices in dense interstellar clouds, as has been previously proposed. Other features in the spectrum are recombination lines of hydrogen, rotational and vibration-rotation lines of molecular hydrogen, and a broad absorption probably due to a blend of HCN and C2H2 bands.

Near-infrared spectroscopy of the proto-planetary nebula CRL 618 and the origin of the hydrocarbon dust component in the interstellar medium

NASA Technical Reports Server (NTRS)

Chiar, J. E.; Pendleton, Y. J.; Geballe, T. R.; Tielens, A. G.

1998-01-01

A new 2.8-3.8 micrometers spectrum of the carbon-rich protoplanetary nebula CRL 618 confirms the previous detection of a circumstellar 3.4 micrometers absorption feature in this object (Lequeux & Jourdain de Muizon). The high resolution and high signal-to-noise ratio of our spectrum allow us to derive the detailed profile of this absorption feature, which is very similar to that observed in the spectrum of the Galactic center and also resembles the strong 3.4 micrometers emission feature in some post-asymptotic giant branch stars. A weak 3.3 micrometers unidentified infrared band, marginally detected in the CRL 618 spectrum of Lequeux & Jourdain de Muizon, is present in our spectrum. The existence of the 3.4 micrometers feature implies the presence of relatively short-chained, aliphatic hydrocarbon materials (-CH2-/-CH3 approximately = 2-2.5) in the circumstellar environment around CRL 618. It also implies that the carriers of the interstellar 3.4 micrometers feature are produced at least in part in circumstellar material, and it calls into question whether any are produced by the processing of interstellar ices in dense interstellar clouds, as has been previously proposed. Other features in the spectrum are recombination lines of hydrogen, rotational and vibration-rotation lines of molecular hydrogen, and a broad absorption probably due to a blend of HCN and C2H2 bands.

Unified analysis of optical absorption spectra of carotenoids based on a stochastic model.

PubMed

Uragami, Chiasa; Saito, Keisuke; Yoshizawa, Masayuki; Molnár, Péter; Hashimoto, Hideki

2018-05-03

The chemical structures of the carotenoid molecules are very simple and one might think that the electronic feature of it is easily predicted. However, it still has so much unknown information except the correlation between the electronic energy state and the length of effective conjugation chain of carotenoids. To investigate the electronic feature of the carotenoids, the most essential method is measuring the optical absorption spectra, but simulating it from the resonance Raman spectra is also the effective way. From this reason, we studied the optical absorption spectra as well as resonance Raman spectra of 15 different kinds of cyclic carotenoid molecules, recorded in tetrahydrofuran (THF) solutions at room temperature. The whole band shapes of the absorption spectra of all these carotenoid molecules were successfully simulated based on a stochastic model using Brownian oscillators. The parameters obtained from the simulation made it possible to discuss the intermolecular interaction between carotenoids and solvent THF molecules quantitatively. Copyright © 2018. Published by Elsevier Inc.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Honda, M.; Kudo, T.; Terada, H.

We made near-infrared multicolor imaging observations of a disk around Herbig Be star HD 100546 using Gemini/NICI. K (2.2 μm), H{sub 2}O ice (3.06 μm), and L′ (3.8 μm) disk images were obtained and we found a 3.1 μm absorption feature in the scattered light spectrum, likely due to water ice grains at the disk surface. We compared the observed depth of the ice absorption feature with the disk model based on Oka et al., including the water ice photodesorption effect by stellar UV photons. The observed absorption depth can be explained by both the disk models with and without themore » photodesorption effect within the measurement accuracy, but the model with photodesorption effects is slightly more favored, implying that the UV photons play an important role in the survival/destruction of ice grains at the Herbig Ae/Be disk surface. Further improvement to the accuracy of the observations of the water ice absorption depth is needed to constrain the disk models.« less

FIRST ULTRAVIOLET REFLECTANCE SPECTRA OF PLUTO AND CHARON BY THE HUBBLE SPACE TELESCOPE COSMIC ORIGINS SPECTROGRAPH: DETECTION OF ABSORPTION FEATURES AND EVIDENCE FOR TEMPORAL CHANGE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stern, S. A.; Spencer, J. R.; Shinn, A.

We have observed the mid-UV spectra of both Pluto and its large satellite, Charon, at two rotational epochs using the Hubble Space Telescope (HST) Cosmic Origins Spectrograph (COS) in 2010. These are the first HST/COS measurements of Pluto and Charon. Here we describe the observations and our reduction of them, and present the albedo spectra, average mid-UV albedos, and albedo slopes we derive from these data. These data reveal evidence for a strong absorption feature in the mid-UV spectrum of Pluto; evidence for temporal change in Pluto's spectrum since the 1990s is reported, and indirect evidence for a near-UV spectralmore » absorption on Charon is also reported.« less

The Detection of Water Ice in Comet Hale-Bopp

NASA Technical Reports Server (NTRS)

Davies, John K.; Roush, Ted L.; Cruikshank, Dale P.; Bartholomew, Mary Jane; Geballe, Thomas R.; Owen, Tobias

1996-01-01

We present spectra of Comet Hale-Bopp (C/1995 01) covering the range 1.4-2.5 micron that were recorded when the comet was 7 AU from the Sun. These show I)road absorption features at 1.5 and 2.05 micron. We show that some, but not all, of this absorption could be matched by an intimate mixture of water ice and a low albedo material such as carbon on the nucleus. However, we recognize that it is more likely that the ice features are produced by scattering from icy grains in the coma. The absence of absorption at 1.65 micron suggests that this ice is probably in the amorphous state. An unidentified additional component may be required to account for the downward slope at the longwavelength end of the spectrum.

Rapidly variable relatvistic absorption

NASA Astrophysics Data System (ADS)

Parker, M.; Pinto, C.; Fabian, A.; Lohfink, A.; Buisson, D.; Alston, W.; Jiang, J.

2017-10-01

I will present results from the 1.5Ms XMM-Newton observing campaign on the most X-ray variable AGN, IRAS 13224-3809. We find a series of nine absorption lines with a velocity of 0.24c from an ultra-fast outflow. For the first time, we are able to see extremely rapid variability of the UFO features, and can link this to the X-ray variability from the inner accretion disk. We find a clear flux dependence of the outflow features, suggesting that the wind is ionized by increasing X-ray emission.

Long-range, noncoherent laser Doppler velocimeter.

PubMed

Bloom, S H; Kremer, R; Searcy, P A; Rivers, M; Menders, J; Korevaar, E

1991-11-15

An experimental demonstration of a long-range, noncoherent laser Doppler velocimeter (LDV) is presented. The LDV detects incoming Doppler-shifted signal photons by using the sharp spectral absorption features in atomic or molecular vapors. The edge of the absorption feature is used to convert changes in frequency to large changes in transmission. Preliminary measurements of wind velocity using seeded aerosols showed that the LDV results agreed with mechanical anemometer measurements to within the accuracy of the LDV measurements. With optimization the LDV will provide accurate range-resolved and vibration-tolerant wind-speed measurements at large distances.

Assessing the Utility of Uav-Borne Hyperspectral Image and Photogrammetry Derived 3d Data for Wetland Species Distribution Quick Mapping

NASA Astrophysics Data System (ADS)

Li, Q. S.; Wong, F. K. K.; Fung, T.

2017-08-01

Lightweight unmanned aerial vehicle (UAV) loaded with novel sensors offers a low cost and minimum risk solution for data acquisition in complex environment. This study assessed the performance of UAV-based hyperspectral image and digital surface model (DSM) derived from photogrammetric point clouds for 13 species classification in wetland area of Hong Kong. Multiple feature reduction methods and different classifiers were compared. The best result was obtained when transformed components from minimum noise fraction (MNF) and DSM were combined in support vector machine (SVM) classifier. Wavelength regions at chlorophyll absorption green peak, red, red edge and Oxygen absorption at near infrared were identified for better species discrimination. In addition, input of DSM data reduces overestimation of low plant species and misclassification due to the shadow effect and inter-species morphological variation. This study establishes a framework for quick survey and update on wetland environment using UAV system. The findings indicate that the utility of UAV-borne hyperspectral and derived tree height information provides a solid foundation for further researches such as biological invasion monitoring and bio-parameters modelling in wetland.

Physical properties of erupting plasma associated with coronal mass ejections

NASA Astrophysics Data System (ADS)

Lee, J.; Raymond, J. C.; Reeves, K. K.; Moon, Y.; Kim, K.

2013-12-01

We investigate the physical properties (temperature, density, and mass) of erupting plasma observed in X-rays and EUV, which are all associated with coronal mass ejections observed by SOHO/LASCO. The erupting plasmas are observed as absorption or emission features in the low corona. The absorption feature provides a lower limit to the cold mass while the emission feature provides an upper limit to the mass of observed plasma in X-ray and EUV. We compare the mass constraints for each temperature response and find that the mass estimates in EUV and XRT are smaller than the total mass in the coronagraph. Several events were observed by a few passbands in the X-rays, which allows us to determine the temperature of the eruptive plasma using a filter ratio method. The temperature of one event is estimated at about 8.6 MK near the top of the erupting plasma. This measurement is possibly an average temperature for higher temperature plasma because the XRT is more sensitive at higher temperatures. In addition, a few events show that the absorption features of a prominence or a loop change to emission features with the beginning of their eruptions in all EUV wavelengths of SDO/AIA, which indicates the heating of the plasma. By estimating the physical properties of the erupting plasmas, we discuss the heating of the plasmas associated with coronal mass ejections in the low corona.

Dry contact transfer printing of aligned carbon nanotube patterns and characterization of their optical properties for diameter distribution and alignment.

PubMed

Pint, Cary L; Xu, Ya-Qiong; Moghazy, Sharief; Cherukuri, Tonya; Alvarez, Noe T; Haroz, Erik H; Mahzooni, Salma; Doorn, Stephen K; Kono, Junichiro; Pasquali, Matteo; Hauge, Robert H

2010-02-23

A scalable and facile approach is demonstrated where as-grown patterns of well-aligned structures composed of single-walled carbon nanotubes (SWNT) synthesized via water-assisted chemical vapor deposition (CVD) can be transferred, or printed, to any host surface in a single dry, room-temperature step using the growth substrate as a stamp. We demonstrate compatibility of this process with multiple transfers for large-scale device and specifically tailored pattern fabrication. Utilizing this transfer approach, anisotropic optical properties of the SWNT films are probed via polarized absorption, Raman, and photoluminescence spectroscopies. Using a simple model to describe optical transitions in the large SWNT species present in the aligned samples, polarized absorption data are demonstrated as an effective tool for accurate assignment of the diameter distribution from broad absorption features located in the infrared. This can be performed on either well-aligned samples or unaligned doped samples, allowing simple and rapid feedback of the SWNT diameter distribution that can be challenging and time-consuming to obtain in other optical methods. Furthermore, we discuss challenges in accurately characterizing alignment in structures of long versus short carbon nanotubes through optical techniques, where SWNT length makes a difference in the information obtained in such measurements. This work provides new insight to the efficient transfer and optical properties of an emerging class of long, large diameter SWNT species typically produced in the CVD process.

Photoacoustic characterization of ovarian tissue

NASA Astrophysics Data System (ADS)

Aguirre, Andres; Gamelin, John; Guo, Puyun; Yan, Shikui; Sanders, Mary; Brewer, Molly; Zhu, Quing

2009-02-01

Ovarian cancer has the highest mortality of all gynecologic cancers with a five-year survival rate of only 30%. Because current imaging techniques (ultrasound, CT, MRI, PET) are not capable of detecting ovarian cancer early, most diagnoses occur in later stages (III/IV). Thus many women are not correctly diagnosed until the cancer becomes widely metastatic. On the other hand, while the majority of women with a detectable ultrasound abnormality do not harbor a cancer, they all undergo unnecessary oophorectomy. Hence, new imaging techniques that can provide functional and molecular contrasts are needed for improving the specificity of ovarian cancer detection and characterization. One such technique is photoacoustic imaging, which has great potential to reveal early tumor angiogenesis through intrinsic optical absorption contrast from hemoglobin or extrinsic contrast from conjugated agents binding to appropriate molecular receptors. To better understand the cancer disease process of ovarian tissue using photoacoustic imaging, it is necessary to first characterize the properties of normal ovarian tissue. We have imaged ex-vivo ovarian tissue using a 3D co-registered ultrasound and photoacoustic imaging system. The system is capable of volumetric imaging by means of electronic focusing. Detecting and visualizing small features from multiple viewing angles is possible without the need for any mechanical movement. The results show strong optical absorption from vasculature, especially highly vascularized corpora lutea, and low absorption from follicles. We will present correlation of photoacoustic images from animals with histology. Potential application of this technology would be the noninvasive imaging of the ovaries for screening or diagnostic purposes.

Search for correlated UV and x ray absorption of NGC 3516

NASA Technical Reports Server (NTRS)

Martin, Christopher; Halpern, Jules P.; Kolman, Michiel

1991-01-01

NGC 3516, a low-luminosity Seyfert galaxy, is one of a small fraction of Seyfert galaxies that exhibit broad absorption in a resonance line. In order to determine whether the UV and x ray absorption in NGC 3516 are related, 5 IUE observations were obtained, quasi-simultaneously with 4 Ginga observations. The results are presented and discussed. The following subject areas are covered: short-term UV variability; emission lines; galactic absorption lines; the C IV, N V, and Si IV absorption features; lower limit on the carbon column density; estimate of the distance from the absorber to the continuum source; variability in the continuum and absorption; a comparison with BAL QSO's; and the x ray-UV connection.

A novel biasing dependent circuit model of resonant cavity enhanced avalanche photodetectors (RCE-APDs)

NASA Astrophysics Data System (ADS)

Abdelhamid, Mostafa R.; El-Batawy, Yasser M.; Deen, M. Jamal

2018-02-01

In Resonant Cavity Enhanced Photodetectors (RCE-PDs), the trade-off between the bandwidth and the quantum efficiency in the conventional photodetectors is overcome. In RCE-PDs, large bandwidth can be achieved using a thin absorption layer while the use of a resonant cavity allows for multiple passes of light in the absorption which boosts the quantum efficiency. In this paper, a complete bias-dependent model for the Resonant Cavity Enhanced-Separated Absorption Graded Charge Multiplication-Avalanche Photodetector (RCE-SAGCM-APD) is presented. The proposed model takes into account the case of drift velocities other than the saturation velocity, thus modeling this effect on the photodetector different design parameters such as Gain, Bandwidth and Gain-Bandwidth product.

The active site structure of tetanus neurotoxin resolved by multiple scattering analysis in X-Ray absorption spectroscopy.

PubMed Central

Meneghini, C; Morante, S

1998-01-01

A detailed study of the x-ray absorption spectrum of tetanus neurotoxin in the K-edge EXAFS region of the zinc absorber is presented that allows the complete identification of the amino acid residues coordinated to the zinc active site. A very satisfactory interpretation of the experimental data can be given if multiple scattering contributions are included in the analysis. Comparing the absorption spectrum of tetanus neurotoxin to that of two other structurally similar zinc-endopeptidases, thermolysin and astacin, in which the zinc coordination mode is known from crystallographic data, we conclude that in tetanus neurotoxin, besides a water molecule, zinc is coordinated to two histidines and a tyrosine. PMID:9746536

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

DOEpatents

Cassano, A.A.

1985-07-02

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

Time-varying sodium absorption in the Type Ia supernova 2013gh

DOE PAGES

Ferretti, Raphael; Amanullah, R.; Goobar, A.; ...

2016-07-18

Context. Temporal variability of narrow absorption lines in high-resolution spectra of Type Ia supernovae (SNe Ia) is studied to search for circumstellar matter. Time series which resolve the profiles of absorption lines such as Na I D or Ca II H&K are expected to reveal variations due to photoionisation and subsequent recombination of the gases. The presence, composition, and geometry of circumstellar matter may hint at the elusive progenitor system of SNe Ia and could also affect the observed reddening law. Aims. To date, there are few known cases of time-varying Na I D absorption in SNe Ia, all ofmore » which occurred during relatively late phases of the supernova (SN) evolution. Photoionisation, however, is predicted to occur during the early phases of SNe Ia, when the supernovae peak in the ultraviolet. We attempt, therefore, to observe early-time absorption-line variations by obtaining high-resolution spectra of SNe before maximum light. Methods. In this paper, we have obtained photometry and high-resolution spectroscopy of SNe Ia 2013gh and iPTF 13dge, to search for absorption-line variations. Furthermore, we study interstellar absorption features in relation to the observed photometric colours of the SNe. Results. Both SNe display deep Na I D and Ca II H&K absorption features. Furthermore, small but significant variations are detected in a feature of the Na I D profile of SN 2013gh. The variations are consistent with either geometric effects of rapidly moving or patchy gas clouds or photoionisation of Na I gas at R ≈ 10 19 cm from the explosion. Conclusions. Our analysis indicates that it is necessary to focus on early phases to detect photoionisation effects of gases in the circumstellar medium of SNe Ia. Different absorbers such as Na I and Ca II can be used to probe for matter at different distances from the SNe. Finally, the nondetection of variations during early phases makes it possible to put limits on the abundance of the species at those distances.« less

Avalanche diode having reduced dark current and method for its manufacture

DOEpatents

Davids, Paul; Starbuck, Andrew Lee; Pomerene, Andrew T. S.

2017-08-29

An avalanche diode includes an absorption region in a germanium body epitaxially grown on a silicon body including a multiplication region. Aspect-ratio trapping is used to suppress dislocation growth in the vicinity of the absorption region.

Development of a Near-Ir Cavity Enhanced Absorption Spectrometer for the Detection of Atmospheric Oxidation Products and Organoamines

NASA Astrophysics Data System (ADS)

Eddingsaas, Nathan C.; Jewell, Breanna; Thurnherr, Emily

2014-06-01

An estimated 10,000 to 100,000 different compounds have been measured in the atmosphere, each one undergoes many oxidation reactions that may or may not degrade air quality. To date, the fate of even some of the most abundant hydrocarbons in the atmosphere is poorly understood. One difficulty is the detection of atmospheric oxidation products that are very labile and decompose during analysis. To study labile species under atmospheric conditions, a highly sensitive, non-destructive technique is needed. Here we describe a near-IR incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) setup that we are developing to meet this end. We have chosen to utilize the near-IR, where vibrational overtone absorptions are observed, due to the clean spectral windows and better spectral separation of absorption features. In one spectral window we can simultaneously and continuously monitor the composition of alcohols, hydroperoxides, and carboxylic acids in an air mass. In addition, we have used our CEAS setup to detect organoamines. The long effective path length of CEAS allows for low detection limits, even of the overtone absorption features, at ppb and ppt levels.

Hydrothermally-altered dacite terrains in the Methana peninsula Greece: Relevance to Mars

NASA Astrophysics Data System (ADS)

Cloutis, Edward A.; Jonatanson, Victoria; Bandfield, Joshua L.; Amador, Elena S.; Rivera-Hernández, Frances; Mann, P.; Mertzman, Stanley A.

2017-04-01

Dacitic rocks, often indicative of crustal recycling on Earth, have been identified in some regions on Mars, as have possible hydrothermally/aqueously-altered dacites. To enable more robust identification of unaltered and altered dacites on Mars and other planetary bodies, we undertook a spectroscopic-structural-compositional study of altered and unaltered dacites from a dacitic volcanic region in Methana, Greece. Dacites erupted in this region range from fresh to pervasively hydrothermally altered, resulting in friable, Si-enriched products, as well as fumarolic deposition of Si and S-rich precipitates. Spectrally, fresh dacites are unremarkable in the 0.35-2.5 μm region with low, generally flat, reflectance and few, if any, absorption bands. Dacite infrared spectra exhibit Si-O absorption features in the 8-10 μm region (which are characteristic of Si-bearing rocks, in general). With increasing alteration, reflectance over the 0.35-2.5 μm range increases, absorption bands in the 1.4 and 1.9 μm region, associated with H2O/OH, and in the 2.2-2.3 μm region, associated with SiOH, become deeper, Fe3+-associated absorption bands in the 0.43 and 0.9 μm region appear, and the Christiansen feature near 8 μm moves to shorter wavelengths. Silica-rich coatings appear to be spectrally indistinguishable from Si-rich alteration. Alteration-formed sulfates may be detectable by the presence of diagnostic absorption features in the 0.35-2.5 μm region. Spectral similarities between different poorly crystalline high-Si phases make it difficult to uniquely determine the processes that formed high-Si surfaces that have been identified on Mars. However, the samples described here show a variety of spectral features that correspond to variable amounts of alteration. We find a similar range of spectral features, likely due to similar phases, on Mars, perhaps indicating a similar range of alteration environments. Comparison of laboratory spectra to Mars observational data also suggests that the major Si-rich regions likely consist of assemblages that more mineralogically complex than those included in this study.

Dust around Mira variables: An analysis of IRAS LRS spectra

NASA Technical Reports Server (NTRS)

Slijkhuis, S.

1989-01-01

The spatial extent and spectral appearance of the thin dust shell around Mira variables is determined largely by the dust absorptivity, Q(sub abs)(lambda), and the dust condensation temperature T(sub cond). Both Q(sub abs)(lambda) and T(sub cond) are extracted from IRAS low-resolution spectra (LRS) spectra. In order to do this, the assumption that the ratio of total power in the 10 micron feature to that in the 20 micron feature should be equal to that measured in other amorphous silicates (e.g., synthesized amorphous Mg2SiO4). It was found that T(sub cond) decreases with decreasing strength of the 10 micron feature, from T(sub cond) = 1000 K to 500 K (estimated error 20 percent). A value for the near-infrared dust absorptivity could not be determined. Although this parameter strongly affects the condensation radius, it hardly affects the shape of the LRS spectrum (as long as the optically thin approximation is valid), because it scales the spatial distribution of the dust. Information on the magnitude of the near-infrared dust absorptivity may be deduced from the unique carbon star BM Gem. This star has a LRS spectrum with silicate features indication an inner dust shell temperature of at least 1000 K. However, on the basis of observations in the 1920s-30s one may infer an inner dust shell radius of at least 6x10(exp 12)m. To have this high temperature at such a large distance, the near-infrared absorptivity of the dust must be high.

Plasmonic field confinement for separate absorption-multiplication in InGaAs nanopillar avalanche photodiodes

PubMed Central

Farrell, Alan C.; Senanayake, Pradeep; Hung, Chung-Hong; El-Howayek, Georges; Rajagopal, Abhejit; Currie, Marc; Hayat, Majeed M.; Huffaker, Diana L.

2015-01-01

Avalanche photodiodes (APDs) are essential components in quantum key distribution systems and active imaging systems requiring both ultrafast response time to measure photon time of flight and high gain to detect low photon flux. The internal gain of an APD can improve system signal-to-noise ratio (SNR). Excess noise is typically kept low through the selection of material with intrinsically low excess noise, using separate-absorption-multiplication (SAM) heterostructures, or taking advantage of the dead-space effect using thin multiplication regions. In this work we demonstrate the first measurement of excess noise and gain-bandwidth product in III–V nanopillars exhibiting substantially lower excess noise factors compared to bulk and gain-bandwidth products greater than 200 GHz. The nanopillar optical antenna avalanche detector (NOAAD) architecture is utilized for spatially separating the absorption region from the avalanche region via the NOA resulting in single carrier injection without the use of a traditional SAM heterostructure. PMID:26627932

Soft Lithographic Procedure for Producing Plastic Microfluidic Devices with View-ports Transparent to Visible and Infrared Light.

PubMed

Suryana, Mona; Shanmugarajah, Jegan V; Maniam, Sivakumar M; Grenci, Gianluca

2017-08-17

Infrared (IR) spectro-microscopy of living biological samples is hampered by the absorption of water in the mid-IR range and by the lack of suitable microfluidic devices. Here, a protocol for the fabrication of plastic microfluidic devices is demonstrated, where soft lithographic techniques are used to embed transparent Calcium Fluoride (CaF2) view-ports in connection with observation chamber(s). The method is based on a replica casting approach, where a polydimethylsiloxane (PDMS) mold is produced through standard lithographic procedures and then used as the template to produce a plastic device. The plastic device features ultraviolet/visible/infrared (UV/Vis/IR) -transparent windows made of CaF2 to allow for direct observation with visible and IR light. The advantages of the proposed method include: a reduced need for accessing a clean room micro-fabrication facility, multiple view-ports, an easy and versatile connection to an external pumping system through the plastic body, flexibility of the design, e.g., open/closed channels configuration, and the possibility to add sophisticated features such as nanoporous membranes.

Wide-angle, polarization-insensitive and broadband absorber based on eight-fold symmetric SRRs metamaterial

NASA Astrophysics Data System (ADS)

Wu, Dong; Liu, Yumin; Yu, Zhongyuan; Chen, Lei; Ma, Rui; Li, Yutong; Li, Ruifang; Ye, Han

2016-12-01

In this paper, we propose a novel three dimensional metamaterial design with eight-fold rotational symmetry that shows a polarization-insensitive, wide-angle and broadband perfect absorption in the microwave band. By simulation, the polarization-insensitive absorption is over 90% between 26.9 GHz to 32.9 GHz, and the broadband absorption remains a good absorption performance to a wide incident angles for both TE and TM polarizations. The magnetic field distribution are investigated to interpret the physical mechanism of broadband absorption. The broadband absorption is based on overlapping the multiple magnetic resonances at the neighboring frequencies by coupling effects of multiple metallic split-ring resonators (SRRs). Moreover, it is demonstrate that the designed structure can be extended to other frequencies by scale down the size of the unit cell, such as the visible frequencies. The simulated results show that the absorption of the smaller absorber is above 90% in the frequency range from 467 THz to 765 THz(392-642 nm), which include orange to purple light in visible region(400-760nm). The wide-angle and polarization-insensitive stabilities of the smaller absorber is also demonstrated at visible region. The proposed work provides a new design of realization of a polarization-insensitive, wide-angle and broadband absorber ranging different frequency bands, and such a structure has potential application in the fields of solar cell, imaging and detection.

Statistical Analysis of Hubble /WFC3 Transit Spectroscopy of Extrasolar Planets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fu, Guangwei; Deming, Drake; Knutson, Heather

2017-10-01

Transmission spectroscopy provides a window to study exoplanetary atmospheres, but that window is fogged by clouds and hazes. Clouds and haze introduce a degeneracy between the strength of gaseous absorption features and planetary physical parameters such as abundances. One way to break that degeneracy is via statistical studies. We collect all published HST /WFC3 transit spectra for 1.1–1.65 μ m water vapor absorption and perform a statistical study on potential correlations between the water absorption feature and planetary parameters. We fit the observed spectra with a template calculated for each planet using the Exo-transmit code. We express the magnitude ofmore » the water absorption in scale heights, thereby removing the known dependence on temperature, surface gravity, and mean molecular weight. We find that the absorption in scale heights has a positive baseline correlation with planetary equilibrium temperature; our hypothesis is that decreasing cloud condensation with increasing temperature is responsible for this baseline slope. However, the observed sample is also intrinsically degenerate in the sense that equilibrium temperature correlates with planetary mass. We compile the distribution of absorption in scale heights, and we find that this distribution is closer to log-normal than Gaussian. However, we also find that the distribution of equilibrium temperatures for the observed planets is similarly log-normal. This indicates that the absorption values are affected by observational bias, whereby observers have not yet targeted a sufficient sample of the hottest planets.« less

Statistical Analysis of Hubble/WFC3 Transit Spectroscopy of Extrasolar Planets

NASA Astrophysics Data System (ADS)

Fu, Guangwei; Deming, Drake; Knutson, Heather; Madhusudhan, Nikku; Mandell, Avi; Fraine, Jonathan

2018-01-01

Transmission spectroscopy provides a window to study exoplanetary atmospheres, but that window is fogged by clouds and hazes. Clouds and haze introduce a degeneracy between the strength of gaseous absorption features and planetary physical parameters such as abundances. One way to break that degeneracy is via statistical studies. We collect all published HST/WFC3 transit spectra for 1.1-1.65 micron water vapor absorption, and perform a statistical study on potential correlations between the water absorption feature and planetary parameters. We fit the observed spectra with a template calculated for each planet using the Exo-Transmit code. We express the magnitude of the water absorption in scale heights, thereby removing the known dependence on temperature, surface gravity, and mean molecular weight. We find that the absorption in scale heights has a positive baseline correlation with planetary equilibrium temperature; our hypothesis is that decreasing cloud condensation with increasing temperature is responsible for this baseline slope. However, the observed sample is also intrinsically degenerate in the sense that equilibrium temperature correlates with planetary mass. We compile the distribution of absorption in scale heights, and we find that this distribution is closer to log-normal than Gaussian. However, we also find that the distribution of equilibrium temperatures for the observed planets is similarly log-normal. This indicates that the absorption values are affected by observational bias, whereby observers have not yet targeted a sufficient sample of the hottest planets.

Statistical Analysis of Hubble/WFC3 Transit Spectroscopy of Extrasolar Planets

NASA Astrophysics Data System (ADS)

Fu, Guangwei; Deming, Drake; Knutson, Heather; Madhusudhan, Nikku; Mandell, Avi; Fraine, Jonathan

2017-10-01

Transmission spectroscopy provides a window to study exoplanetary atmospheres, but that window is fogged by clouds and hazes. Clouds and haze introduce a degeneracy between the strength of gaseous absorption features and planetary physical parameters such as abundances. One way to break that degeneracy is via statistical studies. We collect all published HST/WFC3 transit spectra for 1.1-1.65 μm water vapor absorption and perform a statistical study on potential correlations between the water absorption feature and planetary parameters. We fit the observed spectra with a template calculated for each planet using the Exo-transmit code. We express the magnitude of the water absorption in scale heights, thereby removing the known dependence on temperature, surface gravity, and mean molecular weight. We find that the absorption in scale heights has a positive baseline correlation with planetary equilibrium temperature; our hypothesis is that decreasing cloud condensation with increasing temperature is responsible for this baseline slope. However, the observed sample is also intrinsically degenerate in the sense that equilibrium temperature correlates with planetary mass. We compile the distribution of absorption in scale heights, and we find that this distribution is closer to log-normal than Gaussian. However, we also find that the distribution of equilibrium temperatures for the observed planets is similarly log-normal. This indicates that the absorption values are affected by observational bias, whereby observers have not yet targeted a sufficient sample of the hottest planets.

Suzaku Observations Of Near-relativistic Outflows In The Bal Quasar APM 08279+5255.

NASA Astrophysics Data System (ADS)

Saez, Cristian; Chartas, G.; Brandt, N.

2009-12-01

We present results from three Suzaku observations of the z =3.91 gravitationally lensed broad absorption line quasar APM 08279+5255. We detect strong and broad absorption at rest-frame energies of <2 keV (low-energy) and 7-12 keV (high-energy). The detection of these features confirms the results of previous long-exposure (80-90 ks) Chandra and XMM-Newton observations. The low and high-energy absorption is detected in both the back-illuminated (BI) and front-illuminated (FI) Suzaku XIS spectra (with an F-test significance of <99%). We interpret the low-energy absorption as arising from a low ionization absorber with logNH 23 and the high-energy absorption as due to lines arising from highly ionized iron in a near-relativistic outflowing wind. Assuming this interpretation we find that the velocities in the outflow range between 0.1c and 0.6c. We constrain the angle between the outflow direction of the X-ray absorber and our line of sight to be <36 degrees. We also detect possible variability of the absorption lines (at the <99.9% and <98% significance levels in the FI and BI spectra, respectively) with a rest-frame time scale of 1 month. Assuming that the detected high-energy absorption features arise from FeXXV, we estimate that the fraction of the total bolometric energy injected over the quasar's lifetime into the intergalactic medium in the form of kinetic energy to be >10%.

Influence of δ p-doping on the behaviour of GaAs/AlGaAs SAM-APDs for synchrotron radiation

NASA Astrophysics Data System (ADS)

Steinhartova, T.; Nichetti, C.; Antonelli, M.; Cautero, G.; Menk, R. H.; Pilotto, A.; Driussi, F.; Palestri, P.; Selmi, L.; Koshmak, K.; Nannarone, S.; Arfelli, F.; Dal Zilio, S.; Biasiol, G.

2017-11-01

This work focuses on the development and the characterization of avalanche photodiodes with separated absorption and multiplication regions grown by molecular beam epitaxy. The i-GaAs absorption region is separated from the multiplication region by a δ p-doped layer of carbon atoms, which ensures that after applying a reverse bias, the vast majority of the potential drops in the multiplication region. Therein, thin layers of AlGaAs and GaAs alternate periodically in a so-called staircase structure to create a periodic modulation of the band gap, which under bias enables a well-defined charge multiplication and results in a low multiplication noise. The influence of the concentration of carbon atoms in the δ p-doped layer on the device characteristics was investigated and experimental data are presented together with simulation results.

4.6 micron absorption features due to solid phase CO and cyano group molecules toward compact infrared sources

NASA Technical Reports Server (NTRS)

Lacy, J. H.; Baas, F.; Allamandola, L. J.; Van De Bult, C. E. P.; Persson, S. E.; Mcgregor, P. J.; Lonsdale, C. J.; Geballe, T. R.

1984-01-01

Spectra obtained at a resolving power of 840, for seven protostellar sources in the region of the 4.67-micron fundamental vibrational band of CO, indicate that the deep absorption feature in W33A near 4.61 microns consists of three features which are seen in other sources, but with varying relative strength. UV-irradiation laboratory experiments with 'dirty ice' temperature cycling allow the identification of two of the features cited with solid CO and CO complexed to other molecules. Cyano group-containing molecules have a lower vapor pressure than CO, and can therefore survive in much warmer environments. The formation and location of the CO- and CN-bearing grain mantles and sources of UV irradiation in cold molecular clouds are discussed. Plausible UV light sources can produce the observed cyano group features, but only under conditions in which local heat sources do not cause evaporation of the CO molecules prior to their photoprocessing.

Imperfectly geometric shapes of nanograting structures as solar absorbers with superior performance for solar cells.

PubMed

Nguyen-Huu, Nghia; Cada, Michael; Pištora, Jaromír

2014-03-10

The expectation of perfectly geometric shapes of subwavelength grating (SWG) structures such as smoothness of sidewalls and sharp corners and nonexistence of grating defects is not realistic due to micro/nanofabrication processes. This work numerically investigates optical properties of an optimal solar absorber comprising a single-layered silicon (Si) SWG deposited on a finite Si substrate, with a careful consideration given to effects of various types of its imperfect geometry. The absorptance spectra of the solar absorber with different geometric shapes, namely, the grating with attached nanometer-sized features at the top and bottom of sidewalls and periodic defects within four and ten grating periods are investigated comprehensively. It is found that the grating with attached features at the bottom absorbs more energy than both the one at the top and the perfect grating. In addition, it is shown that the grating with defects in each fourth period exhibits the highest average absorptance (91%) compared with that of the grating having defects in each tenth period (89%), the grating with attached features (89%), and the perfect one (86%). Moreover, the results indicate that the absorptance spectrum of the imperfect structures is insensitive to angles of incidence. Furthermore, the absorptance enhancement is clearly demonstrated by computing magnetic field, energy density, and Poynting vector distributions. The results presented in this study prove that imperfect geometries of the nanograting structure display a higher absorptance than the perfect one, and provide such a practical guideline for nanofabrication capabilities necessary to be considered by structure designers.

Line identifications, line strengths, and continuum flux measurements in the ultraviolet spectrum of Arcturus

NASA Technical Reports Server (NTRS)

Carpenter, K. G.; Wing, R. F.; Stencel, R. E.

1985-01-01

The ultraviolet spectrum of Arcturus has been observed at high resolution with the IUE satellite. Line identifications, mean absolute 'continuum' flux measurements, integrated absolute emission-line fluxes, and measurements of selected absorption line strengths are presented for the 2250-2930 A region. In the 1150-2000 A region, identifications are given primarily on the basis of low-resolution spectra. Chromospheric emission lines have been identified with low-excitation species including H I, C I, C II, O I, Mg I, Mg II, Al II, Si I, Si II, S I, and Fe II; there is no evidence for lines of C IV, N V, or other species requiring high temperatures. A search for molecular absorption features in the 2500-2930 A interval has led to several tentative identifications, but only OH could be established as definitely present. Iron lines strongly dominate the identifications in the 2250-2930 A region, Fe II accounting for about 86 percent of the emission features and Fe I for 43 percent of the identified absorption features.

Character and spatial distribution of OH/H2O on the surface of the Moon seen by M3 on Chandrayaan-1.

PubMed

Pieters, C M; Goswami, J N; Clark, R N; Annadurai, M; Boardman, J; Buratti, B; Combe, J-P; Dyar, M D; Green, R; Head, J W; Hibbitts, C; Hicks, M; Isaacson, P; Klima, R; Kramer, G; Kumar, S; Livo, E; Lundeen, S; Malaret, E; McCord, T; Mustard, J; Nettles, J; Petro, N; Runyon, C; Staid, M; Sunshine, J; Taylor, L A; Tompkins, S; Varanasi, P

2009-10-23

The search for water on the surface of the anhydrous Moon had remained an unfulfilled quest for 40 years. However, the Moon Mineralogy Mapper (M3) on Chandrayaan-1 has recently detected absorption features near 2.8 to 3.0 micrometers on the surface of the Moon. For silicate bodies, such features are typically attributed to hydroxyl- and/or water-bearing materials. On the Moon, the feature is seen as a widely distributed absorption that appears strongest at cooler high latitudes and at several fresh feldspathic craters. The general lack of correlation of this feature in sunlit M3 data with neutron spectrometer hydrogen abundance data suggests that the formation and retention of hydroxyl and water are ongoing surficial processes. Hydroxyl/water production processes may feed polar cold traps and make the lunar regolith a candidate source of volatiles for human exploration.

Character and spatial distribution of OH/H2O on the surface of the moon seen by M3 on chandrayaan-1

USGS Publications Warehouse

Pieters, C.M.; Goswami, J.N.; Clark, R.N.; Annadurai, M.; Boardman, J.; Buratti, B.; Combe, J.-P.; Dyar, M.D.; Green, R.; Head, J.W.; Hibbitts, C.; Hicks, M.; Isaacson, P.; Klima, R.; Kramer, G.; Kumar, S.; Livo, E.; Lundeen, S.; Malaret, E.; McCord, T.; Mustard, J.; Nettles, J.; Petro, N.; Runyon, C.; Staid, M.; Sunshine, J.; Taylor, L.A.; Tompkins, S.; Varanasi, P.

2009-01-01

The search for water on the surface of the anhydrous Moon had remained an unfulfilled quest for 40 years. However, the Moon Mineralogy Mapper (M 3) on Chandrayaan-1 has recently detected absorption features near 2.8 to 3.0 micrometers on the surface of the Moon. For silicate bodies, such features are typically attributed to hydroxyl- and/or water-bearing materials. On the Moon, the feature is seen as a widely distributed absorption that appears strongest at cooler high latitudes and at several fresh feldspathic craters. The general lack of correlation of this feature in sunlit M3 data with neutron spectrometer hydrogen abundance data suggests that the formation and retention of hydroxyl and water are ongoing surficial processes. Hydroxyl/water production processes may feed polar cold traps and make the lunar regolith a candidate source of volatiles for human exploration.

Coupling between absorption and scattering in disordered colloids

NASA Astrophysics Data System (ADS)

Stephenson, Anna; Hwang, Victoria; Park, Jin-Gyu; Manoharan, Vinothan N.

We aim to understand how scattering and absorption are coupled in disordered colloidal suspensions containing absorbing molecules (dyes). When the absorption length is shorter than the transport length, absorption dominates, and absorption and scattering can be seen as two additive effects. However, when the transport length is shorter than the absorption length, the scattering and absorption become coupled, as multiple scattering increases the path length of the light in the sample, leading to a higher probability of absorption. To quantify this synergistic effect, we measure the diffuse reflectance spectra of colloidal samples of varying dye concentrations, thicknesses, and particle concentrations, and we calculate the transport length and absorption length from our measurements, using a radiative transfer model. At particle concentrations so high that the particles form disordered packings, we find a minimum in the transport length. We show that selecting a dye where the absorption peak matches the location of the minimum in the transport length allows for enhanced absorption. Kraft-Heinz Corporation, NSF GRFP 2015200426.

Lipid-associated oral delivery: Mechanisms and analysis of oral absorption enhancement.

PubMed

Rezhdo, Oljora; Speciner, Lauren; Carrier, Rebecca

2016-10-28

The majority of newly discovered oral drugs are poorly water soluble, and co-administration with lipids has proven effective in significantly enhancing bioavailability of some compounds with low aqueous solubility. Yet, lipid-based delivery technologies have not been widely employed in commercial oral products. Lipids can impact drug transport and fate in the gastrointestinal (GI) tract through multiple mechanisms including enhancement of solubility and dissolution kinetics, enhancement of permeation through the intestinal mucosa, and triggering drug precipitation upon lipid emulsion depletion (e.g., by digestion). The effect of lipids on drug absorption is currently not quantitatively predictable, in part due to the multiple complex dynamic processes that can be impacted by lipids. Quantitative mechanistic analysis of the processes significant to lipid system function and overall impact on drug absorption can aid in the understanding of drug-lipid interactions in the GI tract and exploitation of such interactions to achieve optimal lipid-based drug delivery. In this review, we discuss the impact of co-delivered lipids and lipid digestion on drug dissolution, partitioning, and absorption in the context of the experimental tools and associated kinetic expressions used to study and model these processes. The potential benefit of a systems-based consideration of the concurrent multiple dynamic processes occurring upon co-dosing lipids and drugs to predict the impact of lipids on drug absorption and enable rational design of lipid-based delivery systems is presented. Copyright © 2016 Elsevier B.V. All rights reserved.

Evidence for sulphur implantation in Europa's UV absorption band

NASA Technical Reports Server (NTRS)

Lane, A. L.; Nelson, R. M.; Matson, D. L.

1981-01-01

The UV spectral characteristics of the Galilean satellites are investigated (using data from the International Ultraviolet Explorer (IUE) spacecraft) as a function of the orbital position, large-scale areal variability, and temporal dynamics. The discovery of an absorption feature at 280 nm in Europa's reflection spectrum is reported and observations show that the absorption is strongest on the trailing hemisphere (central longitude 270 degrees). The feature resembles SO2 and seems to result from S-O bond formation between deeply implanted sulphur atoms and the adjacent damaged water-ice-lattice. The sulphur supposedly comes from energetic (hundreds of keV) sulphur ions that are present in the Jovian magnetosphere. An appropriate equilibrium condition can be found to match the observed spectral data if sputtering erosion occurs at no greater than approximately 20 meters per one billion years.

Transition-metal-substituted indium thiospinels as novel intermediate-band materials: prediction and understanding of their electronic properties.

PubMed

Palacios, P; Aguilera, I; Sánchez, K; Conesa, J C; Wahnón, P

2008-07-25

Results of density-functional calculations for indium thiospinel semiconductors substituted at octahedral sites with isolated transition metals (M=Ti,V) show an isolated partially filled narrow band containing three t2g-type states per M atom inside the usual semiconductor band gap. Thanks to this electronic structure feature, these materials will allow the absorption of photons with energy below the band gap, in addition to the normal light absorption of a semiconductor. To our knowledge, we demonstrate for the first time the formation of an isolated intermediate electronic band structure through M substitution at octahedral sites in a semiconductor, leading to an enhancement of the absorption coefficient in both infrared and visible ranges of the solar spectrum. This electronic structure feature could be applied for developing a new third-generation photovoltaic cell.

Phase-dependent absorption features in X-ray spectra of X-ray Dim Isolated Neutron Stars

NASA Astrophysics Data System (ADS)

Borghese, A.; Rea, N.; Coti Zelati, F.; Turolla, R.; Tiengo, A.; Zane, S.

2017-12-01

A detailed phase-resolved spectroscopy of archival XMM-Newton observations of X-ray Dim Isolated Neutron Stars (XDINSs) led to the discovery of narrow and strongly phase-dependent absorption features in two of these sources. The first was discovered in the X-ray spectrum of RX J0720.4-3125, followed by a new possible candidate in RX J1308.6+2127. Both spectral lines have similar properties: they are detected for only ˜ 20% of the rotational cycle and appear to be stable over the timespan covered by the observations. We performed Monte Carlo simulations to test the significance of these phase-variable features and in both cases the outcome has confirmed the detection with a confidence level > 4.6σ. Because of the narrow width and the strong dependence on the pulsar rotational phase, the most likely interpretation for these spectral features is in terms of resonant proton cyclotron absorption scattering in a confined high-B structure close to the stellar surface. Within the framework of this interpretation, our results provide evidence for deviations from a pure dipole magnetic field on small scales for highly magnetized neutron stars and support the proposed scenario of XDINSs being aged magnetars, with a strong non-dipolar crustal B-field component.

Automated simultaneous multiple feature classification of MTI data

NASA Astrophysics Data System (ADS)

Harvey, Neal R.; Theiler, James P.; Balick, Lee K.; Pope, Paul A.; Szymanski, John J.; Perkins, Simon J.; Porter, Reid B.; Brumby, Steven P.; Bloch, Jeffrey J.; David, Nancy A.; Galassi, Mark C.

2002-08-01

Los Alamos National Laboratory has developed and demonstrated a highly capable system, GENIE, for the two-class problem of detecting a single feature against a background of non-feature. In addition to the two-class case, however, a commonly encountered remote sensing task is the segmentation of multispectral image data into a larger number of distinct feature classes or land cover types. To this end we have extended our existing system to allow the simultaneous classification of multiple features/classes from multispectral data. The technique builds on previous work and its core continues to utilize a hybrid evolutionary-algorithm-based system capable of searching for image processing pipelines optimized for specific image feature extraction tasks. We describe the improvements made to the GENIE software to allow multiple-feature classification and describe the application of this system to the automatic simultaneous classification of multiple features from MTI image data. We show the application of the multiple-feature classification technique to the problem of classifying lava flows on Mauna Loa volcano, Hawaii, using MTI image data and compare the classification results with standard supervised multiple-feature classification techniques.

Plasma concentrations of remoxipride and the gastrointestinal transit of 111In-marked extended-release coated spheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Graffner, C.; Wagner, Z.; Nilsson, M.I.

1990-01-01

To explore the oral absorption of remoxipride, spheres of remoxipride were labeled with indium-111 colloid before coating with a release-controlling ethylcellulose membrane. Since the labeling remained inside the coating, it was suitable as a marker. Eight healthy volunteers were given a single dose of 100 mg remoxipride in 111In-marked spheres as a multiple-unit capsule. The radioactivity and the position of the spheres (microcapsules) were followed externally for 30 hr by gamma scintigraphy. Parallel to this, plasma concentrations were drawn for 48 hr to confirm the extended dissolution and absorption of remoxipride. The hard gelatin, multiple-unit capsule released the microcapsules withinmore » the stomach. These were then rapidly emptied into the small intestine, within 0.5-1 hr. There was then an immediate distribution in the upper small intestine before collection in the lower portion, within 2-5 hr. After passing into the large intestine, there was again extended distribution of the microcapsules. A mean Cmax of 2.7 microM remoxipride was achieved 4 hr after drug administration and a mean AUC of 26.1 mumol.L-1.hr was achieved. Judging from the absorption versus time profile, calculated according to the Wagner-Nelson method, and the scintigraphic images, it is concluded that the main absorption occurs from the small intestine. Data from four volunteers, however, indicated a comparatively good absorption also from the large intestine. Due to the good absorption properties, it is reasonable to expect a low variation in the extent of bioavailability of remoxipride after administration in an extended-release, multiple-unit capsule formulation.« less

Hydrolysis Batteries: Generating Electrical Energy during Hydrogen Absorption.

PubMed

Xiao, Rui; Chen, Jun; Fu, Kai; Zheng, Xinyao; Wang, Teng; Zheng, Jie; Li, Xingguo

2018-02-19

The hydrolysis reaction of aluminum can be decoupled into a battery by pairing an Al foil with a Pd-capped yttrium dihydride (YH 2 -Pd) electrode. This hydrolysis battery generates a voltage around 0.45 V and leads to hydrogen absorption into the YH 2 layer. This represents a new hydrogen absorption mechanism featuring electrical energy generation during hydrogen absorption. The hydrolysis battery converts 8-15 % of the thermal energy of the hydrolysis reaction into usable electrical energy, leading to much higher energy efficiency compared to that of direct hydrolysis. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Special Features of Light Absorption by the Dimer of Bilayer Microparticles

NASA Astrophysics Data System (ADS)

Geints, Yu. É.; Panina, E. K.; Zemlyanov, A. A.

2018-05-01

Results of numerical simulation of light absorption by the dimer of bilayer spherical particles consisting of a water core and a polymer shell absorbing radiation are presented. The spatial distribution and the amplitude characteristics of the volume density of the absorbed power are investigated. It is shown that for a certain spatial dimer configuration, the maximal achievable density of the absorbed power is realized. It is also established that for closely spaced microcapsules with high shell absorption indices, the total power absorbed in the dimer volume can increase in comparison with the radiation absorption by two insulated microparticles.

Numerical simulation of infrared radiation absorption for diagnostics of gas-aerosol medium by remote sensing data

NASA Astrophysics Data System (ADS)

Voitsekhovskaya, O. K.; Egorov, O. V.; Kashirskii, D. E.; Shefer, O. V.

2015-11-01

Calculated absorption spectra of the mixture of gases (H2O, CO, CO2, NO, NO2, and SO2) and aerosol (soot and Al2O3), contained in the exhausts of aircraft and rocket engines are demonstrated. Based on the model of gas-aerosol medium, a numerical study of the spectral dependence of the absorptance for different ratios of gas and aerosol components was carried out. The influence of microphysical and optical properties of the components of the mixture on the spectral features of absorption of gas-aerosol medium was established.

Molecular dynamics simulations of collision-induced absorption: Implementation in LAMMPS

NASA Astrophysics Data System (ADS)

Fakhardji, W.; Gustafsson, M.

2017-02-01

We pursue simulations of collision-induced absorption in a mixture of argon and xenon gas at room temperature by means of classical molecular dynamics. The established theoretical approach (Hartmann et al. 2011 J. Chem. Phys. 134 094316) is implemented with the molecular dynamics package LAMMPS. The bound state features in the absorption spectrum are well reproduced with the molecular dynamics simulation in comparison with a laboratory measurement. The magnitude of the computed absorption, however, is underestimated in a large part of the spectrum. We suggest some aspects of the simulation that could be improved.

Christiansen effect in disperse systems with resonant absorption

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zimnyakov, D A; Isaeva, Elmira A; Isaeva, A A

We discuss the results of experimental studies of competition of absorption and scattering of laser radiation propagating in dispersive media with resonant absorption. As media under study, use is made of a suspension of polystyrene particles in solutions of rhodamine 6G in ethylene glycol probed by laser light with a wavelength of 532 nm. It is found that an increase in the dye concentration leads to an increase in optical transmittance of suspensions and an increase in speckle modulation of the forward-scattered radiation. We interpret these features as a manifestation of Christiansen effect in disperse systems with resonance absorption.

Spectrum of Transient ASASSN-13at

NASA Astrophysics Data System (ADS)

Garnavich, Peter; Deal, Shanel

2013-06-01

We observed the transient ASASSN-13at (ATEL 5168) on June 28.3 (UT) with the Vatican Advanced Technology Telescope (VATT) and VATTSPEC instrument. The resulting spectrum covers the wavelength range between 365 nm and 750 nm with a resolution of 1100. The spectrum of ASASSN-13at shows a blue continuum with strong Balmer absorption lines. Helium absorption at 447 nm and 588 nm is also seen. Blue-shifted emission lines are visible within the Halpha and Hbeta absorption features.

Extreme Variability in a Broad Absorption Line Quasar

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stern, Daniel; Jun, Hyunsung D.; Graham, Matthew J.

CRTS J084133.15+200525.8 is an optically bright quasar at z = 2.345 that has shown extreme spectral variability over the past decade. Photometrically, the source had a visual magnitude of V ∼ 17.3 between 2002 and 2008. Then, over the following five years, the source slowly brightened by approximately one magnitude, to V ∼ 16.2. Only ∼1 in 10,000 quasars show such extreme variability, as quantified by the extreme parameters derived for this quasar assuming a damped random walk model. A combination of archival and newly acquired spectra reveal the source to be an iron low-ionization broad absorption line quasar withmore » extreme changes in its absorption spectrum. Some absorption features completely disappear over the 9 years of optical spectra, while other features remain essentially unchanged. We report the first definitive redshift for this source, based on the detection of broad H α in a Keck/MOSFIRE spectrum. Absorption systems separated by several 1000 km s{sup −1} in velocity show coordinated weakening in the depths of their troughs as the continuum flux increases. We interpret the broad absorption line variability to be due to changes in photoionization, rather than due to motion of material along our line of sight. This source highlights one sort of rare transition object that astronomy will now be finding through dedicated time-domain surveys.« less

Surface materials map of Afghanistan: carbonates, phyllosilicates, sulfates, altered minerals, and other materials

USGS Publications Warehouse

Kokaly, Raymond F.; King, Trude V.V.; Hoefen, Todd M.; Dudek, Kathleen B.; Livo, Keith E.

2012-01-01

This map shows the distribution of selected carbonates, phyllosilicates, sulfates, altered minerals, and other materials derived from analysis of HyMap imaging spectrometer data of Afghanistan. Using a NASA (National Aeronautics and Space Administration) WB-57 aircraft flown at an altitude of ~15,240 meters or ~50,000 feet, 218 flight lines of data were collected over Afghanistan between August 22 and October 2, 2007. The HyMap data were converted to apparent surface reflectance, then further empirically adjusted using ground-based reflectance measurements. The reflectance spectrum of each pixel of HyMap data was compared to the spectral features of reference entries in a spectral library of minerals, vegetation, water, ice, and snow. This map shows the spatial distribution of minerals that have diagnostic absorption features in the shortwave infrared wavelengths. These absorption features result primarily from characteristic chemical bonds and mineralogical vibrations. Several criteria, including (1) the reliability of detection and discrimination of minerals using the HyMap spectrometer data, (2) the relative abundance of minerals, and (3) the importance of particular minerals to studies of Afghanistan's natural resources, guided the selection of entries in the reference spectral library and, therefore, guided the selection of mineral classes shown on this map. Minerals occurring abundantly at the surface and those having unique spectral features were easily detected and discriminated. Minerals having similar spectral features were less easily discriminated, especially where the minerals were not particularly abundant and (or) where vegetation cover reduced the absorption strength of mineral features. Complications in reflectance calibration also affected the detection and identification of minerals.

Stream-Field Interactions in the Magnetic Accretor AO Piscium

NASA Astrophysics Data System (ADS)

Hellier, Coel; van Zyl, Liza

2005-06-01

UV spectra of the magnetic accretor AO Psc show absorption features for half the binary orbit. The absorption is unlike the wind-formed features often seen in similar stars. Instead, we attribute it to a fraction of the stream that overflows the impact with the accretion disk. Rapid velocity variations can be explained by changes in the trajectory of the stream depending on the orientation of the white dwarf's magnetic field. Hence, we are directly observing the interaction of an accretion stream with a rotating field. We compare this behavior to that seen in other intermediate polars and in SW Sex stars.

More on the lambda 2800 A 'interstellar extinction' feature

NASA Astrophysics Data System (ADS)

McLachlan, A.; Nandy, K.

1985-02-01

In a response made to a recent letter by Karim et al. (1984), it is shown that the examples of interstellar absorption at 2800 A that they attribute to proteinaceous material can all be attributed to overexposure of IUE detectors. It is pointed out that stars in the Large Magellanic Cloud show pronounced absorption at 2800 A which cannot be due to interstellar protein since there is no associated absorption at 2200 A; this lack of absorption cannot be due to presence of graphite, whose absorption is weak in the Cloud. The claim by Karim et al. that the spectra of eight stars show 2800 A absorption and that these spectra are saturation-free is considered, and it is shown that data processing problems at IUE ground stations make these spectra unreliable.

Six-band terahertz metamaterial absorber based on the combination of multiple-order responses of metallic patches in a dual-layer stacked resonance structure.

PubMed

Wang, Ben-Xin; Wang, Gui-Zhen; Sang, Tian; Wang, Ling-Ling

2017-01-25

This paper reports on a numerical study of the six-band metamaterial absorber composed of two alternating stack of metallic-dielectric layers on top of a continuous metallic plane. Six obvious resonance peaks with high absorption performance (average larger than 99.37%) are realized. The first, third, fifth, and the second, fourth, sixth resonance absorption bands are attributed to the multiple-order responses (i.e., the 1-, 3- and 5-order responses) of the bottom- and top-layer of the structure, respectively, and thus the absorption mechanism of six-band absorber is due to the combination of two sets of the multiple-order resonances of these two layers. Besides, the size changes of the metallic layers have the ability to tune the frequencies of the six-band absorber. Employing the results, we also present a six-band polarization tunable absorber through varying the sizes of the structure in two orthogonal polarization directions. Moreover, nine-band terahertz absorber can be achieved by using a three-layer stacked structure. Simulation results indicate that the absorber possesses nine distinct resonance bands, and average absorptivities of them are larger than 94.03%. The six-band or nine-band absorbers obtained here have potential applications in many optoelectronic and engineering technology areas.

Progress in thin-film silicon solar cells based on photonic-crystal structures

NASA Astrophysics Data System (ADS)

Ishizaki, Kenji; De Zoysa, Menaka; Tanaka, Yoshinori; Jeon, Seung-Woo; Noda, Susumu

2018-06-01

We review the recent progress in thin-film silicon solar cells with photonic crystals, where absorption enhancement is achieved by using large-area resonant effects in photonic crystals. First, a definitive guideline for enhancing light absorption in a wide wavelength range (600–1100 nm) is introduced, showing that the formation of multiple band edges utilizing higher-order modes confined in the thickness direction and the introduction of photonic superlattice structures enable significant absorption enhancement, exceeding that observed for conventional random scatterers. Subsequently, experimental evidence of this enhancement is demonstrated for a variety of thin-film Si solar cells: ∼500-nm-thick ultrathin microcrystalline silicon cells, few-µm-thick microcrystalline silicon cells, and ∼20-µm-thick thin single-crystalline silicon cells. The high short-circuit current densities and/or efficiencies observed for each cell structure confirm the effectiveness of using multiple band-edge resonant modes of photonic crystals for enhancing broadband absorption in actual solar cells.

Flower-like BiOI microsphere/Ni@C nanocapsule hybrid composites and their efficient microwave absorbing activity

NASA Astrophysics Data System (ADS)

Liu, Xianguo; Yu, Jieyi; Cui, Caiyun; Sun, Yuping; Li, Xiaolong; Li, Zhenxing

2018-07-01

At present, microwave absorbers are prepared by dispersing absorbing nanomaterials in a binder, which can lead to the aggregation of nanomaterials in the binder and further affect the optimization of the absorption performances. Hybrid micro/nano-scale structures are beneficial for buffering agglomeration phenomena and the construction of multiple interfaces. Here, Ni@C nanocapsules are conjugated onto flower-like BiOI microspheres, forming micro/nano-scale hybrid composites. The multiple interfaces between BiOI microspheres and Ni@C nanocapsules can bring enhanced dielectric loss and increased attenuation constant, resulting in the enhancement of absorption capacity (the optimal reflection loss reaches  ‑61.35 dB), increased width of the effective absorption band (the maximum effective bandwidth, f Emax , is 5.86 GHz) and the reduction of absorption thickness (the thickness corresponding to f Emax is 1.7 mm). This study highlights a simple idea for the optimization of electromagnetic absorbing performance, which is of great significance in the development of microwave absorbers.

PAHFIT: Properties of PAH Emission

NASA Astrophysics Data System (ADS)

Smith, J. D.; Draine, Bruce

2012-10-01

PAHFIT is an IDL tool for decomposing Spitzer IRS spectra of PAH emission sources, with a special emphasis on the careful recovery of ambiguous silicate absorption, and weak, blended dust emission features. PAHFIT is primarily designed for use with full 5-35 micron Spitzer low-resolution IRS spectra. PAHFIT is a flexible tool for fitting spectra, and you can add or disable features, compute combined flux bands, change fitting limits, etc., without changing the code. PAHFIT uses a simple, physically-motivated model, consisting of starlight, thermal dust continuum in a small number of fixed temperature bins, resolved dust features and feature blends, prominent emission lines (which themselves can be blended with dust features), as well as simple fully-mixed or screen dust extinction, dominated by the silicate absorption bands at 9.7 and 18 microns. Most model components are held fixed or are tightly constrained. PAHFIT uses Drude profiles to recover the full strength of dust emission features and blends, including the significant power in the wings of the broad emission profiles. This means the resulting feature strengths are larger (by factors of 2-4) than are recovered by methods which estimate the underlying continuum using line segments or spline curves fit through fiducial wavelength anchors.

Optically induced excitonic electroabsorption in a periodically delta-doped InGaAs/GaAs multiple quantum well structure

NASA Technical Reports Server (NTRS)

Larsson, A.; Maserjian, J.

1991-01-01

Large optically induced Stark shifts have been observed in a periodically delta-doped InGaAs/GaAs multiple quantum well structure. With an excitation intensity of 10 mW/sq cm, an absolute quantum well absorption change of 7000/cm was measured with a corresponding differential absorption change as high as 80 percent. The associated maximum change in the quantum well refractive index is 0.04. This material is promising for device development for all-optical computing and signal processing.

Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework

DOE PAGES

Demir, Selvan; Brune, Nicholas K.; Van Humbeck, Jeffrey F.; ...

2016-04-08

Porous aromatic frameworks (PAFs) incorporating a high concentration of acid functional groups possess characteristics that are promising for use in separating lanthanide and actinide metal ions, as required in the treatment of radioactive waste. These materials have been shown to be indefinitely stable to concentrated acids and bases, potentially allowing for multiple adsorption/stripping cycles. Additionally, the PAFs combine exceptional features from MOFs and inorganic/ activated carbons giving rise to tunable pore surfaces and maximum chemical stability. Herein, we present a study of the adsorption of selected metal ions, Sr 2+, Fe 3+, Nd 3+, and Am 3+, from aqueous solutionsmore » employing a carbon-based porous aromatic framework, BPP-7 (Berkeley Porous Polymer-7). This material displays high metal loading capacities together with excellent adsorption selectivity for neodymium over strontium based on Langmuir adsorption isotherms and ideal adsorbed solution theory (IAST) calculations. Based in part upon X-ray absorption spectroscopy studies, the stronger adsorption of neodymium is attributed to multiple metal ion and binding site interactions resulting from the densely functionalized and highly interpenetrated structure of BPP-7. Finally, recyclability and combustibility experiments demonstrate that multiple adsorption/stripping cycles can be completed with minimal degradation of the polymer adsorption capacity.« less

Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework

PubMed Central

2016-01-01

Porous aromatic frameworks (PAFs) incorporating a high concentration of acid functional groups possess characteristics that are promising for use in separating lanthanide and actinide metal ions, as required in the treatment of radioactive waste. These materials have been shown to be indefinitely stable to concentrated acids and bases, potentially allowing for multiple adsorption/stripping cycles. Additionally, the PAFs combine exceptional features from MOFs and inorganic/activated carbons giving rise to tunable pore surfaces and maximum chemical stability. Herein, we present a study of the adsorption of selected metal ions, Sr2+, Fe3+, Nd3+, and Am3+, from aqueous solutions employing a carbon-based porous aromatic framework, BPP-7 (Berkeley Porous Polymer-7). This material displays high metal loading capacities together with excellent adsorption selectivity for neodymium over strontium based on Langmuir adsorption isotherms and ideal adsorbed solution theory (IAST) calculations. Based in part upon X-ray absorption spectroscopy studies, the stronger adsorption of neodymium is attributed to multiple metal ion and binding site interactions resulting from the densely functionalized and highly interpenetrated structure of BPP-7. Recyclability and combustibility experiments demonstrate that multiple adsorption/stripping cycles can be completed with minimal degradation of the polymer adsorption capacity. PMID:27163056

Visible and near-IR spectral reflectance of geologically important materials: A short review

NASA Technical Reports Server (NTRS)

Singer, R. B.

1982-01-01

Examples of reflectance spectra are presented and discussed for various mineral groups including pyroxenes, olivene, phylosilicates, amphiboles, feldspars, oxides and hydroxides, carbonates, and mixtures of minerals. The physical sources of some spectral features are also reviewed such as charge transfer and conduction bands, crystal field absorptions, and vibrational absorptions.

Superenhancers: novel opportunities for nanowire optoelectronics.

PubMed

Khudiyev, Tural; Bayindir, Mehmet

2014-12-16

Nanowires play a crucial role in the development of new generation optoelectronic devices ranging from photovoltaics to photodetectors, as these designs capitalize on the low material usage, utilize leaky-mode optical resonances and possess high conversion efficiencies associated with nanowire geometry. However, their current schemes lack sufficient absorption capacity demanded for their practical applicability, and more efficient materials cannot find widespread usage in these designs due to their rarity and cost. Here we suggest a novel and versatile nanoconcentrator scheme utilizing unique optical features of non-resonant Mie (NRM) scattering regime associated with low-index structures. The scattering regime is highly compatible with resonant Mie absorption effect taking place in nanowire absorbers. This technique in its optimized forms can provide up to 1500% total absorption enhancement, 400-fold material save and is suitable for large-area applications with significant area preservation compared to thin-film of same materials. Proposed superenhancer concept with its exceptional features such as broadband absorption enhancement, polarization immunity and material-independent manner paves the way for development of efficient nanowire photosensors or solar thermophotovoltaic devices and presents novel design opportunities for self-powered nanosystems.

High-resolution, vacuum-ultraviolet absorption spectrum of boron trifluoride

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hughes, Patrick P.; Thompson, Alan K.; Vest, Robert E.

2014-11-21

In the course of investigations of thermal neutron detection based on mixtures of {sup 10}BF{sub 3} with other gases, knowledge was required of the photoabsorption cross sections of {sup 10}BF{sub 3} for wavelengths between 135 and 205 nm. Large discrepancies in the values reported in existing literature led to the absolute measurements reported in this communication. The measurements were made at the SURF III Synchrotron Ultraviolet Radiation Facility at the National Institute of Standards and Technology. The measured absorption cross sections vary from 10{sup −20} cm{sup 2} at 135 nm to less than 10{sup −21} cm{sup 2} in the regionmore » from 165 to 205 nm. Three previously unreported absorption features with resolvable structure were found in the regions 135–145 nm, 150–165 nm, and 190–205 nm. Quantum mechanical calculations, using the TD-B3LYP/aug-cc-pVDZ variant of time-dependent density functional theory implemented in Gaussian 09, suggest that the observed absorption features arise from symmetry-changing adiabatic transitions.« less

Scientific issues and potential remote-sensing requirements for plant biochemical content

NASA Technical Reports Server (NTRS)

Peterson, David L.; Hubbard, G. S.

1992-01-01

Application of developments in imaging spectrometry to the study of terrestrial ecosystems, which began in 1983, demonstrate the potential to estimate lignin and nitrogen concentrations of plant canopies by remote-sensing techniques. Estimation of these parameters from the first principles of radiative transfer and the interactions of light with plant materials is not presently possible, principally because of lack of knowledge about internal leaf scattering and specific absorption involving biochemical compounds. From the perspective of remote-sensing instrumentation, sensors are needed to support derivative imaging spectroscopy. Biochemical absorption features tend to occur in functional groupings throughout the 1100- to 2500-nm region. Derivative spectroscopy improves the information associated with the weaker, narrower absorption features of biochemical absorption that are superimposed on the strong absolute variations due to foliar biomass, pigments, and leaf water content of plant canopies. Preliminary sensor specifications call for 8-nm bandwidths at 2-nm centers in four spectral regions (about 400 bands total) and a signal-to-noise performance of at least 1000:1 for 20 percent albedo targets in the 2000-nm region.

Improvements to Shortwave Absorption in the GFDL General Circulation Model Radiation Code

NASA Astrophysics Data System (ADS)

Freidenreich, S.

2015-12-01

The multiple-band shortwave radiation parameterization used in the GFDL general circulation models is being revised to better simulate the disposition of the solar flux in comparison with line-by-line+doubling-adding reference calculations based on the HITRAN 2012 catalog. For clear skies, a notable deficiency in the older formulation is an underestimate of atmospheric absorption. The two main reasons for this is the neglecting of both H2O absorption for wavenumbers < 2500 cm-1 and the O2 continuum. Further contributions to this underestimate are due to neglecting the effects of CH4, N2O and stratospheric H2O absorption. These issues are addressed in the revised formulation and result in globally average shortwave absorption increasing from 74 to 78 Wm-2. The number of spectral bands considered remains the same (18), but the number of pseudomonochromatic intervals (based mainly on the exponential-sum-fit technique) for the determination of H2O absorption is increased from 38 to 74, allowing for more accuracy in its simulation. Also, CO2 absorption is now determined by the exponential-sum-fit technique, replacing an algebraic absorptivity expression in the older parameterization; this improves the simulation of the heating in the stratosphere. Improvements to the treatment of multiple scattering are currently being tested. This involves replacing the current algorithm, which consists of the two stream delta-Eddington, with a four stream algorithm. Initial results show that in most, but not all cases these produce better agreement with the reference doubling-adding results.

Extrinsic extinction cross-section in the multiple acoustic scattering by fluid particles

NASA Astrophysics Data System (ADS)

Mitri, F. G.

2017-04-01

Cross-sections (and their related energy efficiency factors) are physical parameters used in the quantitative analysis of different phenomena arising from the interaction of waves with a particle (or multiple particles). Earlier works with the acoustic scattering theory considered such quadratic (i.e., nonlinear) quantities for a single scatterer, although a few extended the formalism for a pair of scatterers but were limited to the scattering cross-section only. Therefore, the standard formalism applied to viscous particles is not suitable for the complete description of the cross-sections and energy balance of the multiple-particle system because both absorption and extinction phenomena arise during the multiple scattering process. Based upon the law of the conservation of energy, this work provides a complete comprehensive analysis for the extrinsic scattering, absorption, and extinction cross-sections (i.e., in the far-field) of a pair of viscous scatterers of arbitrary shape, immersed in a nonviscous isotropic fluid. A law of acoustic extinction taking into consideration interparticle effects in wave propagation is established, which constitutes a generalized form of the optical theorem in multiple scattering. Analytical expressions for the scattering, absorption, and extinction cross-sections are derived for plane progressive waves with arbitrary incidence. The mathematical expressions are formulated in partial-wave series expansions in cylindrical coordinates involving the angle of incidence, the addition theorem for the cylindrical wave functions, and the expansion coefficients of the scatterers. The analysis shows that the multiple scattering cross-section depends upon the expansion coefficients of both scatterers in addition to an interference factor that depends on the interparticle distance. However, the extinction cross-section depends on the expansion coefficients of the scatterer located in a particular system of coordinates, in addition to the interference term. Numerical examples illustrate the analysis for two viscous fluid circular cylindrical cross-sections immersed in a non-viscous fluid. Computations for the (non-dimensional) scattering, absorption, and extinction cross-section factors are performed with particular emphasis on varying the angle of incidence, the interparticle distance, and the sizes, and the physical properties of the particles. A symmetric behavior is observed for the dimensionless multiple scattering cross-section, while asymmetries arise for both the dimensionless absorption and extinction cross-sections with respect to the angle of incidence. The present analysis provides a complete analytical and computational method for the prediction of cross-section and energy efficiency factors in multiple acoustic scattering of plane waves of arbitrary incidence by a pair of scatterers. The results can be used as a priori information in the direct or inverse characterization of multiple scattering systems such as acoustically engineered fluid metamaterials with reconfigurable periodicities, cloaking devices, liquid crystals, and other applications.

Tunable UV-visible absorption of SnS2 layered quantum dots produced by liquid phase exfoliation.

PubMed

Fu, Xiao; Ilanchezhiyan, P; Mohan Kumar, G; Cho, Hak Dong; Zhang, Lei; Chan, A Sattar; Lee, Dong J; Panin, Gennady N; Kang, Tae Won

2017-02-02

4H-SnS 2 layered crystals synthesized by a hydrothermal method were used to obtain via liquid phase exfoliation quantum dots (QDs), consisting of a single layer (SLQDs) or multiple layers (MLQDs). Systematic downshift of the peaks in the Raman spectra of crystals with a decrease in size was observed. The bandgap of layered QDs, estimated by UV-visible absorption spectroscopy and the tunneling current measurements using graphene probes, increases from 2.25 eV to 3.50 eV with decreasing size. 2-4 nm SLQDs, which are transparent in the visible region, show selective absorption and photosensitivity at wavelengths in the ultraviolet region of the spectrum while larger MLQDs (5-90 nm) exhibit a broad band absorption in the visible spectral region and the photoresponse under white light. The results show that the layered quantum dots obtained by liquid phase exfoliation exhibit well-controlled and regulated bandgap absorption in a wide tunable wavelength range. These novel layered quantum dots prepared using an inexpensive method of exfoliation and deposition from solution onto various substrates at room temperature can be used to create highly efficient visible-blind ultraviolet photodetectors and multiple bandgap solar cells.

DISCOVERY OF THE TRANSITION OF A MINI-BROAD ABSORPTION LINE INTO A BROAD ABSORPTION LINE IN THE SDSS QUASAR J115122.14+020426.3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hidalgo, Paola Rodriguez; Eracleous, Michael; Charlton, Jane

We present the detection of a rare case of dramatic strengthening in the UV absorption profiles in the spectrum of the quasar J115122.14+020426.3 between observations {approx}2.86 yr apart in the quasar rest frame. A spectrum obtained in 2001 by the Sloan Digital Sky Survey shows a C IV ''mini-broad'' absorption line (FWHM = 1220 km s{sup -1}) with a maximum blueshift velocity of {approx}9520 km s{sup -1}, while a later spectrum from the Very Large Telescope shows a significantly broader and stronger absorption line, with a maximum blueshift velocity of {approx}12, 240 km s{sup -1} that qualifies as a broadmore » absorption line. A similar variability pattern is observed in two additional systems at lower blueshifted velocities and in the Ly{alpha} and N V transitions as well. One of the absorption systems appears to be resolved and shows evidence for partial covering of the quasar continuum source (C{sub f} {approx} 0.65), indicating a transverse absorber size of, at least, {approx}6 Multiplication-Sign 10{sup 16} cm. In contrast, a cluster of narrower C IV lines appears to originate in gas that fully covers the continuum and broad emission line sources. There is no evidence for changes in the centroid velocity of the absorption troughs. This case suggests that at least some of the absorbers that produce ''mini-broad'' and broad absorption lines in quasar spectra do not belong to intrinsically separate classes. Here, the ''mini-broad'' absorption line is most likely interpreted as an intermediate phase before the appearance of a broad absorption line due to their similar velocities. While the current observations do not provide enough constraints to discern among the possible causes for this variability, future monitoring of multiple transitions at high resolution will help achieve this goal.« less

Dark matter in the outer solar system

NASA Technical Reports Server (NTRS)

Owen, T.; Cruikshank, D.; De Bergh, C.; Geballe, T.

1994-01-01

There are now a large number of small bodies in the outer solar system that are known to be covered with dark material. Attempts to identify that material have been thwarted by the absence of discrete absorption features in the reflection spectra of these planetesimals. An absorption at 2.2 micrometers that appeared to be present in several objects has not been confirmed by new observations. Three absorptions in the spectrum of the unusually red planetesimal 5145 Pholus are well-established, but their identity remains a mystery.

On the Formation of Interstellar Water Ice: Constraints from a Search for Hydrogen Peroxide Ice in Molecular Clouds

NASA Technical Reports Server (NTRS)

Smith, R. G.; Charnely, S. B.; Pendleton, Y. J.; Wright, C. M.; Maldoni, M. M.; Robinson, G.

2011-01-01

Recent surface chemistry experiments have shown that the hydrogenation of molecular oxygen on interstellar dust grains is a plausible formation mechanism, via hydrogen peroxide (H2O2), for the production of water (H2O) ice mantles in the dense interstellar medium. Theoretical chemistry models also predict the formation of a significant abundance of H2O2 ice in grain mantles by this route. At their upper limits, the predicted and experimental abundances are sufficiently high that H2O2 should be detectable in molecular cloud ice spectra. To investigate this further, laboratory spectra have been obtained for H2O2/H2O ice films between 2.5 and 200 micron, from 10 to 180 K, containing 3%, 30%, and 97% H2O2 ice. Integrated absorbances for all the absorption features in low-temperature H2O2 ice have been derived from these spectra. For identifying H2O2 ice, the key results are the presence of unique features near 3.5, 7.0, and 11.3 micron. Comparing the laboratory spectra with the spectra of a group of 24 protostars and field stars, all of which have strong H2O ice absorption bands, no absorption features are found that can definitely be identified with H2O2 ice. In the absence of definite H2O2 features, the H2O2 abundance is constrained by its possible contribution to the weak absorption feature near 3.47 micron found on the long-wavelength wing of the 3 micron H2O ice band. This gives an average upper limit for H2O2, as a percentage of H2O, of 9% +/- 4%. This is a strong constraint on parameters for surface chemistry experiments and dense cloud chemistry models.

Layers in the Central Orion nebula

NASA Astrophysics Data System (ADS)

O'Dell, C. R.

2018-07-01

The existence of multiple layers in the inner Orion nebula has been revealed using data from an Atlas of spectra at 2 arcsec and 12 km s-1 resolution. These data were sometimes grouped over Samples of 10 arcsec×10 arcsecto produce high signal-to-noise spectra and sometimes grouped into sequences of pseudo-slit Spectra of 12^''.8-39 arcsec width for high spatial resolution studies. Multiple velocity systems were found: V_{MIF} traces the Main Ionization Front (MIF), V_{scat} arises from back-scattering of V_{MIF} emission by particles in the background Photon Dissociation Region (PDR), V_{low} is an ionized layer in front of the MIF and if it is the source of the stellar absorption lines seen in the Trapezium stars, it must lie between the foreground Veil and those stars, V_{new,[O III] may represent ionized gas evaporating from the Veil away from the observer. There are features such as the Bright Bar where variations of velocities are due to changing tilts of the MIF, but velocity changes above about 25 arcsec arise from variations in velocity of the background PDR. In a region 25 arcsec ENE of the Orion-S Cloud one finds dramatic changes in the [OIII] components, including the signals from the V_{low,[O III] and V_{MIF,[O III] becoming equal, indicating shadowing of gas from stellar photons of >24.6 eV. This feature is also seen in areas to the west and south of the Orion-S Cloud.

Layers in the Central Orion Nebula

NASA Astrophysics Data System (ADS)

O'Dell, C. R.

2018-04-01

The existence of multiple layers in the inner Orion Nebula has been revealed using data from an Atlas of spectra at 2″ and 12 km s-1 resolution. These data were sometimes grouped over Samples of 10″×10″ to produce high Signal to Noise spectra and sometimes grouped into sequences of pseudo-slit Spectra of 12{^''.}8 - 39″width for high spatial resolution studies. Multiple velocity systems were found: V_{MIF} traces the Main Ionization Front (MIF), V_{scat} arises from back-scattering of V_{MIF} emission by particles in the background Photon Dissociation Region (PDR), V_{low} is an ionized layer in front of the MIF and if it is the source of the stellar absorption lines seen in the Trapezium stars, it must lie between the foreground Veil and those stars, V_{new,[O III]} may represent ionized gas evaporating from the Veil away from the observer. There are features such as the Bright Bar where variations of velocities are due to changing tilts of the MIF, but velocity changes above about 25″ arise from variations in velocity of the background PDR. In a region 25″ ENE of the Orion-S Cloud one finds dramatic changes in the [O III] components, including the signals from the V_{low,[O III]} and V_{MIF,[O III]} becoming equal, indicating shadowing of gas from stellar photons of >24.6 eV. This feature is also seen in areas to the west and south of the Orion-S Cloud.

12 years of Phobos observations by Omega and Spicam on board MEX

NASA Astrophysics Data System (ADS)

Gondet, Brigitte; Bertaux, Jean-Loup; Omega Team, Spicam Team

2016-10-01

Mars Express made several encounters with Phobos and a few with Deimos since 2004. Observations with SPICAM and OMEGA imaging spectrometers on board Mars Express covers the range from UV (110-312 nm) to visible and mid IR up to 5 µm. In the following we consider the ultraviolet (UV) channel of SPICAM and only the visible channel of OMEGA and its small UV extension down to 390 nm, in order to compare with SPICAM. Preliminary results were presented already in the past [1]. Since then, a more detailed analysis was carried out, subtracting some internally scattered light affecting the SPICAM UV retrieved reflectance.The combined spectrum of Radiance Factor from SPICAM and OMEGA suggests the presence of a deep absorption feature. Both instruments, taken separately, support also this absorption feature.In the visible part of CRISM [2] on board MRO and recently confirmed by Omega, one feature is centered at 0.65 µm, with an absorption depth varying from 0 to 4%, an other one is centered at 2.8µm. These two Visible IR features were interpreted [2] either to highly desiccated Fe-phyllosilicate minerals indigenous to the bodies, or to a surface process involving Rayleigh scattering and absorption of small iron particles formed by exogenic space weathering processing.In this rather uncertain situation, the UV band detected by SPICAM and OMEGA on board Mars Express is of great importance to attempt discriminating between the two scenarios proposed above to explain the Visible-IR reflectance spectra of Phobos.[1] Bertaux J.L. et al. (2011) EPSC/DPS conference abstract, Nantes, November 2011. [[2] Freaman A.A. et al. (2014) Icarus, 229 , 196-205.

UV-Visible reflectance of Phobos from SPICAM and OMEGA and comparison with Deimos

NASA Astrophysics Data System (ADS)

Gondet, Brigitte; Bertaux, Jean-Loup; Montmessin, Franck; Reberarc, Aurelie

2016-04-01

Mars Express made several encounters with Phobos and a few with Deimos since 2004. Observations with SPICAM and OMEGA imaging spectrometers on board Mars Express covers the range from UV (110-312 nm) to visible and mid IR up to 5 μm. In the following we consider the ultraviolet (UV) channel of SPICAM and only the visible channel of OMEGA and its small UV extension down to 390 nm, in order to compare with SPICAM. Preliminary results were presented already in the past [1]. Since then, a more detailed analysis was carried out, subtracting some internally scattered light affecting the SPICAM UV retrieved reflectance. The combined spectrum of Radiance Factor from SPICAM and OMEGA suggests the presence of a deep absorption feature. Both instruments, taken separately, support also this absorption feature. In the visible part of CRISM [2] on board MRO, one feature is centered at 0.65 μm, with an absorption depth varying from 0 to 4%, an other one is centered at 2.8μm. These two Visible IR features were interpreted [2] either to highly desiccated Fe-phyllosilicate minerals indigenous to the bodies, or to a surface process involving Rayleigh scattering and absorption of small iron particles formed by exogenic space weathering processing. In this rather uncertain situation, the UV band detected by SPICAM and OMEGA on board Mars Express is of great importance to attempt discriminating between the two scenarios proposed above to explain the Visible-IR reflectance spectra of Phobos. [1] Bertaux J.L. et al. (2011) EPSC/DPS conference abstract, Nantes, November 2011, [5] Freaman A.A. et al. (2014) Icarus, 229 , 196-205.

TIME-VARIABLE ALUMINUM ABSORPTION IN THE POLAR AR URSAE MAJORIS, AND AN UPDATED ESTIMATE FOR THE MASS OF THE WHITE DWARF

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bai, Yu; Justham, Stephen; Liu, JiFeng

2016-09-01

We present spectra of the extreme polar AR Ursae Majoris (AR UMa), which display a clear Al i absorption doublet, alongside spectra taken less than a year earlier in which that feature is not present. Re-examination of earlier SDSS spectra indicates that the Al i absorption doublet was also present ≈8 years before our first non-detection. We conclude that this absorbing material is unlikely to be on the surface of either the white dwarf (WD) or the donor star. We suggest that this Al i absorption feature arises in circumstellar material, perhaps produced by the evaporation of asteroids as theymore » approach the hot WD. The presence of any remaining reservoir of rocky material in AR UMa might help to constrain the prior evolution of this unusual binary system. We also apply spectral decomposition to find the stellar parameters of the M dwarf companion, and attempt to dynamically measure the mass of the WD in AR UMa by considering both the radial velocity curves of the H {sub β} emission line and the Na i absorption line. Thereby we infer a mass range for the WD in AR UMa of 0.91 M {sub ⊙} < M {sub WD} < 1.24 M {sub ⊙}.« less

Time-variable Aluminum Absorption in the Polar AR Ursae Majoris, and an Updated Estimate for the Mass of the White Dwarf

NASA Astrophysics Data System (ADS)

Bai, Yu; Justham, Stephen; Liu, JiFeng; Guo, JinCheng; Gao, Qing; Gong, Hang

2016-09-01

We present spectra of the extreme polar AR Ursae Majoris (AR UMa), which display a clear Al I absorption doublet, alongside spectra taken less than a year earlier in which that feature is not present. Re-examination of earlier SDSS spectra indicates that the Al I absorption doublet was also present ≈8 years before our first non-detection. We conclude that this absorbing material is unlikely to be on the surface of either the white dwarf (WD) or the donor star. We suggest that this Al I absorption feature arises in circumstellar material, perhaps produced by the evaporation of asteroids as they approach the hot WD. The presence of any remaining reservoir of rocky material in AR UMa might help to constrain the prior evolution of this unusual binary system. We also apply spectral decomposition to find the stellar parameters of the M dwarf companion, and attempt to dynamically measure the mass of the WD in AR UMa by considering both the radial velocity curves of the H β emission line and the Na I absorption line. Thereby we infer a mass range for the WD in AR UMa of 0.91 M ⊙ < M WD < 1.24 M ⊙.

Optical Hydrogen Absorption Consistent with a Thin Bow Shock Leading the Hot Jupiter HD 189733b

NASA Astrophysics Data System (ADS)

Cauley, P. Wilson; Redfield, Seth; Jensen, Adam G.; Barman, Travis; Endl, Michael; Cochran, William D.

2015-09-01

Bow shocks are ubiquitous astrophysical phenomena resulting from the supersonic passage of an object through a gas. Recently, pre-transit absorption in UV metal transitions of the hot Jupiter (HJ) exoplanets HD 189733b and WASP12-b have been interpreted as being caused by material compressed in a planetary bow shock. Here we present a robust detection of a time-resolved pre-transit, as well as in-transit absorption signature around the HJ exoplanet HD 189733b using high spectral resolution observations of several hydrogen Balmer lines. The line shape of the pre-transit feature and the shape of the timeseries absorption provide the strongest constraints on the morphology and physical characteristics of extended structures around an exoplanet. The in-transit measurements confirm the previous exospheric Hα detection, although the absorption depth measured here is ∼50% lower. The pre-transit absorption feature occurs 125 minutes before the predicted optical transit, a projected linear distance from the planet to the stellar disk of 7.2 Rp. The absorption strength observed in the Balmer lines indicates an optically thick, but physically small, geometry. We model this signal as the early ingress of a planetary bow shock. If the bow shock is mediated by a planetary magnetosphere, the large standoff distance derived from the model suggests a large planetary magnetic field strength of Beq = 28 G. Better knowledge of exoplanet magnetic field strengths is crucial to understanding the role these fields play in planetary evolution and the potential development of life on planets in the habitable zone.

Mg I absorption features in the solar spectrum near 9 and 12 microns

NASA Technical Reports Server (NTRS)

Glenar, David A.; Reuter, Dennis C.; Deming, Drake; Chang, Edward S.

1988-01-01

High-resolution FTS observations from the Kitt Peak National Solar Observatory and the Spacelab 3 ATMOS experiment have revealed additional infrared transitions due to Mg I in the spectra of both quiet sun and sunspot penumbra. In contrast to previous observations, these transitions are seen in absorption, not emission. Absorption intensities range from 1 to 7 percent of the continuum in the quiet sun. In the penumbra, the same features appear to show Zeeman splitting. Modeling of the line profiles in the photospheric spectrum shows evidence for a factor of three overabundance in the n = 5 or more levels of Mg I in the upper photosphere, but with no deviations from a Planck source function. It is concluded that whatever the process that produces the emission (including the Lemke and Holweger mechanism), it must occur well above the tau(5000) = 0.01 level.

Tunable evolutions of shock absorption and energy partitioning in magnetic granular chains

NASA Astrophysics Data System (ADS)

Leng, Dingxin; Liu, Guijie; Sun, Lingyu

2018-01-01

In this paper, we investigate the tunable characteristics of shock waves propagating in one-dimensional magnetic granular chains at various chain lengths and magnetic flux densities. According to the Hertz contact theory and Maxwell principle, a discrete element model with coupling elastic and field-induced interaction potentials of adjacent magnetic grains is proposed. We also present hard-sphere approximation analysis to describe the energy partitioning features of magnetic granular chains. The results demonstrate that, for a fixed magnetic field strength, when the chain length is greater than two times of the wave width of the solitary wave, the chain length has little effect on the output energy of the system; for a fixed chain length, the shock absorption and energy partitioning features of magnetic granular chains are remarkably influenced by varying magnetic flux densities. This study implies that the magnetic granular chain is potential to construct adaptive shock absorption components for impulse mitigation.

Differential absorption lidar observation on small-time-scale features of water vapor in the atmospheric boundary layer

NASA Astrophysics Data System (ADS)

Kong, Wei; Li, Jiatang; Liu, Hao; Chen, Tao; Hong, Guanglie; Shu, Rong

2017-11-01

Observation on small-time-scale features of water vapor density is essential for turbulence, convection and many other fast atmospheric processes study. For the high signal-to-noise signal of elastic signal acquired by differential absorption lidar, it has great potential for all-day water vapor turbulence observation. This paper presents a set of differential absorption lidar at 935nm developed by Shanghai Institute of Technical Physics of the Chinese Academy of Science for water vapor turbulence observation. A case at the midday is presented to demonstrate the daytime observation ability of this system. "Autocovariance method" is used to separate the contribution of water vapor fluctuation from random error. The results show that the relative error is less than 10% at temporal and spatial resolution of 10 seconds and 60 meters in the ABL. This indicate that the system has excellent performance for daytime water vapor turbulence observation.

Discovery of very high velocity outflow in V Hydra - Wind from an accretion disk in a binary?

NASA Technical Reports Server (NTRS)

Sahai, R.; Wannier, P. G.

1988-01-01

High-resolution observations of lines from the CO v = 1-0 vibration-rotation band at 4.6 microns, taken with the FTS/KPNO 4-m telescope, are reported for the carbon-rich red giant V Hydra, which is surrounded by an extended expanding molecular envelope resulting from extensive mass loss. The spectrum shows, in addition to the expected absorption at the outflow velocity of the envelope, absorption extending up to 120 km/s bluewards of the stellar velocity. A comparison of the spectrum observed at two epochs shows that the high-velocity absorption features change with time. It is suggested that the observed high-velocity features in V Hydra arise in a high-velocity polar outflow from an accretion disk in a binary system, as proposed in the mass-loss model for bipolar envelopes by Morris (1988).

Fine-scale structure in the -185 kilometers per second absorption by HCO(+) in the Galactic center

NASA Technical Reports Server (NTRS)

Marr, Jonathan M.; Rudolph, Alexander L.; Pauls, Thomas A.; Wright, Melvyn C. H.; Backer, Donald C.

1992-01-01

We present a high-resolution study of the HCO(+) (J = 1-0) absorption by the 'high-velocity gas' at velocities between -170 and -200 km/s in Sgr A West. The absorption against the continuum radiation from the ionized gas features in Sgr A West (in particular the 'bar') is stronger than it is against Sgr A which is separated from the ionized gas by a few arcseconds. The positions of peak HCO(+) opacity coincide with the positions of Ne II emission at these velocities. These observations suggest that, even though emission is detected from gas at these high velocities over several arcminutes, some of the absorbing molecular gas may be mixed in with the ionized gas close to Sgr A. Simple calculations show that sufficient shielding can exist in the ionized features to allow molecules to survive very close to the ionizing source.

Cold atomic hydrogen in the inner galaxy

NASA Technical Reports Server (NTRS)

Dickey, J. M.; Garwood, R. W.

1986-01-01

The VLA is used to measure 21 cm absorption in directions with the absolute value of b less than 1 deg., the absolute value of 1 less than 25 deg. to probe the cool atomic gas in the inner galaxy. Abundant H I absorption is detected; typical lines are deep and narrow, sometimes blending in velocity with adjacent features. Unlike 21 cm emission not all allowed velocities are covered: large portions of the l-v diagram are optically thin. Although not similar to H I emission, the absorption shows a striking correspondence with CO emission in the inner galaxy: essentially every strong feature detected in one survey is seen in the other. The provisional conclusion is that in the inner galaxy most cool atomic gas is associated with molecular cloud complexes. There are few or no cold atomic clouds devoid of molecules in the inner galaxy, although these are common in the outer galaxy.

A Statistical Approach to Exoplanetary Molecular Spectroscopy Using Spitzer Eclipses

NASA Astrophysics Data System (ADS)

Deming, Drake; Garhart, Emily; Burrows, Adam; Fortney, Jonathan; Knutson, Heather; Todorov, Kamen

2018-01-01

Secondary eclipses of exoplanets observed using the Spitzer Space Telescope measure the total emission emergent from exoplanetary atmospheres integrated over broad photometric bands. Spitzer photometry is excellent for measuring day side temperatures, but is less well suited to the detection of molecular absorption or emission features. Even for very hot exoplanets, it can be difficult to attain the accuracy on eclipse depth that is needed to unambiguously interpret the Spitzer results in terms of molecular absorption or emission. However, a statistical approach, wherein we seek deviations from a simple blackbody planet as a function of the planet's equilibrium temperature, shows promise for defining the nature and strength of molecular absorption in ensembles of planets. In this paper, we explore such an approach using secondary eclipses observed for tens of hot exoplanets during Spitzer's Cycles 10, 12, and 13. We focus on the possibility that the hottest planets exhibit molecular features in emission, due to temperature inversions.

Tailored Algorithm for Sensitivity Enhancement of Gas Concentration Sensors Based on Tunable Laser Absorption Spectroscopy.

PubMed

Vargas-Rodriguez, Everardo; Guzman-Chavez, Ana Dinora; Baeza-Serrato, Roberto

2018-06-04

In this work, a novel tailored algorithm to enhance the overall sensitivity of gas concentration sensors based on the Direct Absorption Tunable Laser Absorption Spectroscopy (DA-ATLAS) method is presented. By using this algorithm, the sensor sensitivity can be custom-designed to be quasi constant over a much larger dynamic range compared with that obtained by typical methods based on a single statistics feature of the sensor signal output (peak amplitude, area under the curve, mean or RMS). Additionally, it is shown that with our algorithm, an optimal function can be tailored to get a quasi linear relationship between the concentration and some specific statistics features over a wider dynamic range. In order to test the viability of our algorithm, a basic C 2 H 2 sensor based on DA-ATLAS was implemented, and its experimental measurements support the simulated results provided by our algorithm.

Egg structure and ultrastructure of Paterdecolyus yanbarensis (Insecta, Orthoptera, Anostostomatidae, Anabropsinae).

PubMed

Mashimo, Yuta; Fukui, Makiko; Machida, Ryuichiro

2016-11-01

The egg structure of Paterdecolyus yanbarensis was examined using light, scanning electron and transmission electron microscopy. The egg surface shows a distinct honeycomb pattern formed by exochorionic ridges. Several micropyles are clustered on the ventral side of the egg. The egg membrane is composed of an exochorion penetrated with numerous aeropyles, an endochorion, and an extremely thin vitelline membrane. The endochorion is thickened at the posterior egg pole, probably associated with water absorption. A comparison of egg structure among Orthoptera revealed that the micropylar distribution pattern is conserved in Ensifera and Caelifera and might be regarded as a groundplan feature for each group; in Ensifera, multiple micropyles are clustered on the ventral side of the egg, whereas in Caelifera, micropyles are arranged circularly around the posterior pole of the egg. Copyright © 2016 Elsevier Ltd. All rights reserved.

Feasibility study on a short-pulsed IR wavelength for effective calculus fragmentation

NASA Astrophysics Data System (ADS)

Kang, Hyun Wook

2015-05-01

Laser-induced lithotripsy has been used for a minimally-invasive surgery to treat kidney-stone disease associated with urinary obstruction. A short-pulsed Tm:YAG laser (λ = 2.01 µm) was developed to improve fragmentation efficiency and was evaluated with a Ho:YAG laser (λ = 2.12 μm) as to its ablation feature and mass removal rate. Application of a train of sub-microsecond pulses with a lower energy at a frequency of 500 Hz created multiple events of cavitation that accompanied strong acoustic transients. During Tm:YAG irradiation, both high light absorption and secondary photomechanical impacts readily fragmented the calculus into small pieces (< 3 mm) and removed them 130 times faster than photothermal Ho:YAG lithotripsy. The proposed short-pulsed Tm:YAG approach may be an effective lithotripter for treating calculus disease.

Drill hole logging with infrared spectroscopy

USGS Publications Warehouse

Calvin, W.M.; Solum, J.G.

2005-01-01

Infrared spectroscopy has been used to identify rocks and minerals for over 40 years. The technique is sensitive to primary silicates as well as alteration products. Minerals can be uniquely identified based on multiple absorption features at wavelengths from the visible to the thermal infrared. We are currently establishing methods and protocols in order to use the technique for rapid assessment of downhole lithology on samples obtained during drilling operations. Initial work performed includes spectral analysis of chip cuttings and core sections from drill sites around Desert Peak, NV. In this paper, we report on a survey of 10,000 feet of drill cuttings, at 100 foot intervals, from the San Andreas Fault Observatory at Depth (SAFOD). Data from Blue Mountain geothermal wells will also be acquired. We will describe the utility of the technique for rapid assessment of lithologic and mineralogic discrimination.

Labview Interface Concepts Used in NASA Scientific Investigations and Virtual Instruments

NASA Technical Reports Server (NTRS)

Roth, Don J.; Parker, Bradford H.; Rapchun, David A.; Jones, Hollis H.; Cao, Wei

2001-01-01

This article provides an overview of several software control applications developed for NASA using LabVIEW. The applications covered here include (1) an Ultrasonic Measurement System for nondestructive evaluation of advanced structural materials, an Xray Spectral Mapping System for characterizing the quality and uniformity of developing photon detector materials, (2) a Life Testing System for these same materials, (3) and the instrument panel for an aircraft mounted Cloud Absorption Radiometer that measures the light scattered by clouds in multiple spectral bands. Many of the software interface concepts employed are explained. Panel layout and block diagram (code) strategies for each application are described. In particular, some of the more unique features of the applications' interfaces and source code are highlighted. This article assumes that the reader has a beginner-to-intermediate understanding of LabVIEW methods.

Io's Thermal Regions and Non-SO2 Spectral Features

NASA Technical Reports Server (NTRS)

Smythe, W. D.; Soderblom, L. A.; Lopes, R. M. C.

2003-01-01

Several absorptions have been identified in the Galileo NIMS spectra of Io that are not related to SO2. [1,2]. These absorptions have band centers at 2.97, 3.15, 3.85, and 3.91 microns. There are also broad absorptions in the regions 1-1.3 and 3- 3.4 microns. Patterning noise in wavelength registration, arising from the pushbroom imaging and grating motion of the NIMS instrument have previously inhibited reliable mapping of weak absorptions. Recent improvements in techniques to remove the coherent pattern noise from the NIMS dataset have been made by Soderblom. This greatly improves the signal to noise ratio and enables mapping of weak spectral signatures such as the 3.15 micron absorption on Io.

Charge transfer effects, thermo and photochromism in single crystal CVD synthetic diamond.

PubMed

Khan, R U A; Martineau, P M; Cann, B L; Newton, M E; Twitchen, D J

2009-09-09

We report on the effects of thermal treatment and ultraviolet irradiation on the point defect concentrations and optical absorption profiles of single crystal CVD synthetic diamond. All thermal treatments were below 850 K, which is lower than the growth temperature and unlikely to result in any structural change. UV-visible absorption spectroscopy measurements showed that upon thermal treatment (823 K), various broad absorption features diminished: an absorption band at 270 nm (used to deduce neutral single substitutional nitrogen (N(S)(0)) concentrations) and also two broad features centred at approximately 360 and 520 nm. Point defect centre concentrations as a function of temperature were also deduced using electron paramagnetic resonance (EPR) spectroscopy. Above ∼500 K, we observed a decrease in the concentration of N(S)(0) centres and a concomitant increase in the negatively charged nitrogen-vacancy-hydrogen (NVH) complex (NVH(-)) concentration. Both transitions exhibited an activation energy between 0.6 and 1.2 eV, which is lower than that for the N(S)(0) donor (∼1.7 eV). Finally, it was found that illuminating samples with intense short-wave ultraviolet light recovered the N(S)(0) concentration and also the 270, 360 and 520 nm absorption features. From these results, we postulate a valence band mediated charge transfer process between NVH and single nitrogen centres with an acceptor trap depth for NVH of 0.6-1.2 eV. Because the loss of N(S)(0) concentration is greater than the increase in NVH(-) concentration we also suggest the presence of another unknown acceptor existing at a similar energy to NVH. The extent to which the colour in CVD synthetic diamond is dependent on prior history is discussed.

Far Ultraviolet Spectroscopy of Saturn's Icy Moon Rhea

NASA Astrophysics Data System (ADS)

Elowitz, Mark; Hendrix, Amanda; Mason, Nigel J.; Sivaraman, Bhalamurugan

2018-01-01

We present an analysis of spatially resolved, far-UV reflectance spectra of Saturn’s icy satellite Rhea, collected by the Cassini Ultraviolet Imaging Spectrograph (UVIS). In recent years ultraviolet spectroscopy has become an important tool for analysing the icy satellites of the outer solar system (1Hendrix & Hansen, 2008). Far-UV spectroscopy provides unique information about the molecular structure and electronic transitions of chemical species. Many molecules that are suspected to be present in the icy surfaces of moons in the outer solar system have broad absorption features due to electronic transitions that occur in the far-UV portion of the spectrum. The studies show that Rhea, like the other icy satellites of the Saturnian system are dominated by water-ice as evident by the 165-nm absorption edge, with minor UV absorbing contaminants. Far-UV spectra of several Saturnian icy satellites, including Rhea and Dione, show an unexplained weak absorption feature centered near 184 nm. To carry out the geochemical survey of Rhea’s surface, the UVIS observations are compared with vacuum-UV spectra of thin-ice samples measured in laboratory experiments. Thin film laboratory spectra of water-ice and other molecular compounds in the solid phase were collected at near-vacuum conditions and temperatures identical to those at the surface of Rhea. Comparison between the observed far-UV spectra of Rhea’s surface ice and modelled spectra based on laboratory absorption measurements of different non-water-ice compounds show that two possible chemical compounds could explain the 184-nm absorption feature. The two molecular compounds include simple chlorine molecules and hydrazine monohydrate. Attempts to explain the source(s) of these compounds on Rhea and the scientific implications of their possible discovery will be summarized.[1] Hendrix, A. R. & Hansen, C. J. (2008). Icarus, 193, pp. 323-333.

Water in primitive solar system bodies

NASA Astrophysics Data System (ADS)

Yang, Bin

This is a dissertation on the physical properties, particularly, the water distribution in three small body populations of the solar system: (1) the Jovian Trojans, (2) the main-belt B-type asteroids and (3) the comets. Using near-infrared (NIR) spectroscopy, I have sought diagnostic (especially water) features in the Trojans. My sample is focused on objects identified in previous measurements as being of special interest. I found that the high albedo Trojan (4709) Ennomos has a featureless spectrum and that its surface contains no more than 10% water ice. In addition, the organic-like features reported earlier for Trojans (617) Patroclus, (911) Agamemnon, (1143) Odysseus and (2797) Teucer were not confirmed. Furthermore, my observations of seven Trojan asteroids that have been formerly reported to show silicate-like absorption features did not confirm the features in their spectra. My broadband photometric observations of two Trojan families (the Eurybates and the 1986WD family) showed that five Eurybates Trojans and one 1986WD Trojan exhibit UV drop-offs, indicating the presence of hydrated minerals on these objects. B-type asteroids are rare, blue asteroids, of which 2 Pallas is the largest and most famous example. In a focused, spectroscopic study of 20 B-type asteroids, I found that optically similar B-type asteroids are spectrally diverse in the near infrared. The negative optical spectral slope is due to the presence of a broad absorption band centered near 1.0 mm, which can often be modeled using magnetite. The best meteorite analogs for B-types are the unusual CI and CM carbonaceous chondrites. In the NIR spectra of the outburst comet 17P/Holmes, I found two broad absorption bands with centers (at 2mm and 3mm, respectively) and overall shapes consistent with the presence of micron-sized water ice grains in the coma. These features together with the discovery of excess 3mm thermal emission, suggests that the coma of 17P/Holmes has two components (hot, refractory dust and cold ice grains) which are not in thermal contact. I also detected the 1.5- and 2-mm water ice absorption features in the two bright Oort cloud comets, C/ 2005L3 and C/2006W3.

Speciation analysis of arsenic in biological matrices by automated hydride generation-cryotrapping-atomic absorption spectrometry with multiple microflame quartz tube atomizer (multiatomizer).

EPA Science Inventory

This paper describes an automated system for the oxidation state specific speciation of inorganic and methylated arsenicals by selective hydride generation - cryotrapping- gas chromatography - atomic absorption spectrometry with the multiatomizer. The corresponding arsines are ge...

Optical spectroscopy of interplanetary dust collected in the earth's stratosphere

NASA Technical Reports Server (NTRS)

Fraundorf, P.; Patel, R. I.; Shirck, J.; Walker, R. M.; Freeman, J. J.

1980-01-01

Optical absorption spectra of interplanetary dust particles 2-30 microns in size collected in the atmosphere at an altitude of 20 km by inertial impactors mounted on NASA U-2 aircraft are reported. Fourier transform absorption spectroscopy of crushed samples of the particles reveals a broad feature in the region 1300-800 kaysers which has also been found in meteorite and cometary dust spectra, and a weak iron crystal field absorption band at approximately 9800 kaysers, as is observed in meteorites. Work is currently in progress to separate the various components of the interplanetary dust particles in order to evaluate separately their contributions to the absorption.

Semiconductor meta-surface based perfect light absorber

NASA Astrophysics Data System (ADS)

Liu, Guiqiang; Nie, Yiyou; Fu, Guolan; Liu, Xiaoshan; Liu, Yi; Tang, Li; Liu, Zhengqi

2017-04-01

We numerically proposed and demonstrated a semiconductor meta-surface light absorber, which consists of a silicon patches array on a silicon thin-film and an opaque silver substrate. The Mie resonances of the silicon patches and the fundamental cavity mode of the ultra-thin silicon film couple strongly to the incident optical field, leading to a multi-band perfect absorption. The maximal absorption is above 99.5% and the absorption is polarization-independent. Moreover, the absorption behavior is scalable in the frequency region via tuning the structural parameters. These features hold the absorber platform with wide applications in optoelectronics such as hot-electron excitation and photo-detection.

A search for formic acid in the upper troposphere - A tentative identification of the 1105-per cm nu-6 band Q branch in high-resolution balloon-borne solar absorption spectra

NASA Technical Reports Server (NTRS)

Goldman, A.; Murcray, F. H.; Murcray, D. G.; Rinsland, C. P.

1984-01-01

Infrared solar absorption spectra recorded at 0.02-per cm resolution during a balloon flight from Alamogordo, NM (33 deg N), on March 23, 1981, have been analyzed for the possible presence of absorption by formic acid (HCOOH). An absorption feature at 1105 per cm has been tentatively identified in upper tropospheric spectra as due to the nu-6 band Q branch. A preliminary analysis indicates a concentration of about 0.6 ppbv and 0.4 ppbv near 8 and 10 km, respectively.

Automatic plankton image classification combining multiple view features via multiple kernel learning.

PubMed

Zheng, Haiyong; Wang, Ruchen; Yu, Zhibin; Wang, Nan; Gu, Zhaorui; Zheng, Bing

2017-12-28

Plankton, including phytoplankton and zooplankton, are the main source of food for organisms in the ocean and form the base of marine food chain. As the fundamental components of marine ecosystems, plankton is very sensitive to environment changes, and the study of plankton abundance and distribution is crucial, in order to understand environment changes and protect marine ecosystems. This study was carried out to develop an extensive applicable plankton classification system with high accuracy for the increasing number of various imaging devices. Literature shows that most plankton image classification systems were limited to only one specific imaging device and a relatively narrow taxonomic scope. The real practical system for automatic plankton classification is even non-existent and this study is partly to fill this gap. Inspired by the analysis of literature and development of technology, we focused on the requirements of practical application and proposed an automatic system for plankton image classification combining multiple view features via multiple kernel learning (MKL). For one thing, in order to describe the biomorphic characteristics of plankton more completely and comprehensively, we combined general features with robust features, especially by adding features like Inner-Distance Shape Context for morphological representation. For another, we divided all the features into different types from multiple views and feed them to multiple classifiers instead of only one by combining different kernel matrices computed from different types of features optimally via multiple kernel learning. Moreover, we also applied feature selection method to choose the optimal feature subsets from redundant features for satisfying different datasets from different imaging devices. We implemented our proposed classification system on three different datasets across more than 20 categories from phytoplankton to zooplankton. The experimental results validated that our system outperforms state-of-the-art plankton image classification systems in terms of accuracy and robustness. This study demonstrated automatic plankton image classification system combining multiple view features using multiple kernel learning. The results indicated that multiple view features combined by NLMKL using three kernel functions (linear, polynomial and Gaussian kernel functions) can describe and use information of features better so that achieve a higher classification accuracy.

Time-varying sodium absorption in the Type Ia supernova 2013gh

NASA Astrophysics Data System (ADS)

Ferretti, R.; Amanullah, R.; Goobar, A.; Johansson, J.; Vreeswijk, P. M.; Butler, R. P.; Cao, Y.; Cenko, S. B.; Doran, G.; Filippenko, A. V.; Freeland, E.; Hosseinzadeh, G.; Howell, D. A.; Lundqvist, P.; Mattila, S.; Nordin, J.; Nugent, P. E.; Petrushevska, T.; Valenti, S.; Vogt, S.; Wozniak, P.

2016-07-01

Context. Temporal variability of narrow absorption lines in high-resolution spectra of Type Ia supernovae (SNe Ia) is studied to search for circumstellar matter. Time series which resolve the profiles of absorption lines such as Na I D or Ca II H&K are expected to reveal variations due to photoionisation and subsequent recombination of the gases. The presence, composition, and geometry of circumstellar matter may hint at the elusive progenitor system of SNe Ia and could also affect the observed reddening law. Aims: To date, there are few known cases of time-varying Na I D absorption in SNe Ia, all of which occurred during relatively late phases of the supernova (SN) evolution. Photoionisation, however, is predicted to occur during the early phases of SNe Ia, when the supernovae peak in the ultraviolet. We attempt, therefore, to observe early-time absorption-line variations by obtaining high-resolution spectra of SNe before maximum light. Methods: We have obtained photometry and high-resolution spectroscopy of SNe Ia 2013gh and iPTF 13dge, to search for absorption-line variations. Furthermore, we study interstellar absorption features in relation to the observed photometric colours of the SNe. Results: Both SNe display deep Na I D and Ca II H&K absorption features. Furthermore, small but significant variations are detected in a feature of the Na I D profile of SN 2013gh. The variations are consistent with either geometric effects of rapidly moving or patchy gas clouds or photoionisation of Na I gas at R ≈ 1019 cm from the explosion. Conclusions: Our analysis indicates that it is necessary to focus on early phases to detect photoionisation effects of gases in the circumstellar medium of SNe Ia. Different absorbers such as Na I and Ca II can be used to probe for matter at different distances from the SNe. The nondetection of variations during early phases makes it possible to put limits on the abundance of the species at those distances. Full Tables 2 and 3 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/592/A40

Important Considerations When Using Hydroxyl Airglow Measurements to Determine Climate Trends of the Mesopause Region.

NASA Astrophysics Data System (ADS)

Burns, G.; French, J.

2007-05-01

Spectral calibrations, airglow and possibly auroral contaminations, solar and telluric absorption features and the selection of transition probabilities can all influence rotational temperatures derived from measurements of hydroxyl airglow intensities. Consideration and examples are given of these influences. Measurements and analyses are outlined for data checking that should be undertaken if a hydroxyl airglow data set is to be used to determine climate trends. Multiple spectral calibrations should be conducted throughout the observing period, with regular inter- comparisons to other calibration sources also required. Uncertainties in spectral calibrations should be expressed as a temperature equivalent. Sufficient spectral scans at maximum resolution should be obtained under all extreme observing conditions (at the lowest solar depression angle operated both morning and night, moon and cloud both separately and combined, aurora and under conditions of enhanced atomic oxygen airglow, and under clear sky conditions but with high atmospheric water vapour content) so that an uncertainty for the derived rotational temperatures can be determined for the established data selection criteria. Once the varying emission and absorption features for the hydroxyl region of interest at your site are understood for the observing site, then the spectral resolution of the observing instrument can be reduced to increase temporal resolution with reasonable confidence. This confidence should be tested by investigating the average rotational temperatures derived from all possible line intensity ratios under the extreme observing conditions noted. If a spectral-fitting rotational temperature determination is used, the residuals from the fit should be summed and similarly examined. Hydroxyl measurements provide a cost effective means of monitoring the temperature of the climate-sensitive mesopause region on an almost nightly basis. If care is taken, they provide a valuable data set for investigating climate change.

Characterization of Artifacts Introduced by the Empirical Volcano-Scan Atmospheric Correction Commonly Applied to CRISM and OMEGA Near-Infrared Spectra

NASA Technical Reports Server (NTRS)

Wiseman, S.M.; Arvidson, R.E.; Wolff, M. J.; Smith, M. D.; Seelos, F. P.; Morgan, F.; Murchie, S. L.; Mustard, J. F.; Morris, R. V.; Humm, D.;

Characterization of artifacts introduced by the empirical volcano-scan atmospheric correction commonly applied to CRISM and OMEGA near-infrared spectra

NASA Astrophysics Data System (ADS)

Wiseman, S. M.; Arvidson, R. E.; Wolff, M. J.; Smith, M. D.; Seelos, F. P.; Morgan, F.; Murchie, S. L.; Mustard, J. F.; Morris, R. V.; Humm, D.; McGuire, P. C.

2016-05-01

The empirical 'volcano-scan' atmospheric correction is widely applied to martian near infrared CRISM and OMEGA spectra between ∼1000 and ∼2600 nm to remove prominent atmospheric gas absorptions with minimal computational investment. This correction method employs division by a scaled empirically-derived atmospheric transmission spectrum that is generated from observations of the martian surface in which different path lengths through the atmosphere were measured and transmission calculated using the Beer-Lambert Law. Identifying and characterizing both artifacts and residual atmospheric features left by the volcano-scan correction is important for robust interpretation of CRISM and OMEGA volcano-scan corrected spectra. In order to identify and determine the cause of spectral artifacts introduced by the volcano-scan correction, we simulated this correction using a multiple scattering radiative transfer algorithm (DISORT). Simulated transmission spectra that are similar to actual CRISM- and OMEGA-derived transmission spectra were generated from modeled Olympus Mons base and summit spectra. Results from the simulations were used to investigate the validity of assumptions inherent in the volcano-scan correction and to identify artifacts introduced by this method of atmospheric correction. We found that the most prominent artifact, a bowl-shaped feature centered near 2000 nm, is caused by the inaccurate assumption that absorption coefficients of CO2 in the martian atmosphere are independent of column density. In addition, spectral albedo and slope are modified by atmospheric aerosols. Residual atmospheric contributions that are caused by variable amounts of dust aerosols, ice aerosols, and water vapor are characterized by the analysis of CRISM volcano-scan corrected spectra from the same location acquired at different times under variable atmospheric conditions.

Detailed Spectral Analysis of the 260 ks XMM-Newton Data of 1E 1207.4-5209 and Significance of a 2.1 keV Absorption Feature

NASA Astrophysics Data System (ADS)

Mori, Kaya; Chonko, James C.; Hailey, Charles J.

2005-10-01

We have reanalyzed the 260 ks XMM-Newton observation of 1E 1207.4-5209. There are several significant improvements over previous work. First, a much broader range of physically plausible spectral models was used. Second, we have used a more rigorous statistical analysis. The standard F-distribution was not employed, but rather the exact finite statistics F-distribution was determined by Monte Carlo simulations. This approach was motivated by the recent work of Protassov and coworkers and Freeman and coworkers. They demonstrated that the standard F-distribution is not even asymptotically correct when applied to assess the significance of additional absorption features in a spectrum. With our improved analysis we do not find a third and fourth spectral feature in 1E 1207.4-5209 but only the two broad absorption features previously reported. Two additional statistical tests, one line model dependent and the other line model independent, confirmed our modified F-test analysis. For all physically plausible continuum models in which the weak residuals are strong enough to fit, the residuals occur at the instrument Au M edge. As a sanity check we confirmed that the residuals are consistent in strength and position with the instrument Au M residuals observed in 3C 273.

The librational band of water ice in AFGL 961: revisited

NASA Astrophysics Data System (ADS)

Smith, R. G.; Wright, C. M.

2011-07-01

Of all the water ice absorption bands seen in the laboratory, the librational band near 12-13 μ m has proven the most difficult to conclusively identify in observational spectra. Cox reported the detection of this band in the IRAS spectrum of the massive protostar AFGL 961 near 13.6 μ m; however, the details of the structure of the band were limited by the quality of the IRAS spectrum and the accuracy of the subtracted silicate absorption. AFGL 961 is also a double system comprising two point-like components separated by ˜6 arcsec (AFGL 961E and AFGL 961W) so the IRAS aperture included both components - it is unclear how the combination of the intrinsic spectra of these two sources may have affected the resultant IRAS spectrum. In this paper we report Spitzer and European Southern Observatory (ESO) 3.6-m mid-infrared spectroscopic observations of each component of AFGL 961. We find a broad absorption feature near 13.1 μ m common to both AFGL 961E and W. The profile and peak wavelength of this feature are well matched by the laboratory spectrum of the librational band of amorphous H2O ice in the temperature range 10-30 K, in agreement with the Cox result. Both AFGL 961E and W also have strong CO2 ice absorption near 15.2 μ m, indistinguishable in profile between the two. However, AFGL 961E shows silicates in absorption near 9.7 μ m, while AFGL 961W shows polycyclic aromatic hydrocarbons in emission and, in a small aperture, also silicates in emission. Uncertainty in where the true continuum lies in the 8-13 μ m spectral region for both AFGL 961E and W means we cannot rule out the possibility that a combination of silicate emission and absorption could be responsible for at least some of the features we see in this region. In this case, a much weaker librational band could still be present, but not as a distinct feature. In either case, the ice must be located in a cool, outer envelope surrounding both stars or a cool foreground cloud, far enough away that the ice is not appreciably modified by the local environment of either one.

Surface Material Analysis of the S-type Asteroids: Removing the Space Weathering Effect from Reflectance Spectrum

NASA Technical Reports Server (NTRS)

Ueda, Y.; Miyamoto, M.; Mikouchi, T.; Hiroi, T.

2003-01-01

Recent years, many researchers have been observing a lot of asteroid reflectance spectra in the UV, visible to NIR at wavelength region. Reflectance spectroscopy of asteroid at this range should bring us a lot of information about its surface materials. Pyroxene and olivine have characteristic absorption bands in this wavelength range. Low-Ca pyroxene has two absorption bands around 0.9 microns and 1.9 microns. The more Ca and Fe content, the longer both absorption band centers. On the other hand, reflectance spectrum of olivine has three complicated absorption bands around 1 m, and no absorption feature around 2 microns. In general, reflectance spectra of many asteroids that are considered to be silicate rich (i.e., S- and A type asteroids) show redder slope and more subdued absorption bands than those of terrestrial minerals and meteorites. These features are now believed to be caused by the space weathering effect, which is probably caused by micrometeorite bombardment and/or solar wind. This process causes nanophase reduced iron (npFe(sup 0)) particles near the surface of mineral grains, which leads the optical change. Therefore, the space weathering effect should be removed from asteroid reflectance spectra to compare with those of meteorite and terrestrial minerals. In this report, we will apply the expanded modified Gaussian model (MGM) to the reflectance spectra of S-type asteroids 7 Iris and 532 Herculina and compare them with those of meteorites.

Ultra-violet and visible absorption characterization of explosives by differential reflectometry.

PubMed

Dubroca, Thierry; Moyant, Kyle; Hummel, Rolf E

2013-03-15

This study presents some optical properties of TNT (2,4,6-trinitrotoluene), RDX, HMX and tetryl, specifically their absorption spectra as a function of concentration in various solvents in the ultraviolet and visible portion of the electromagnetic spectrum. We utilize a standoff explosives detection method, called differential reflectometry (DR). TNT was diluted in six different solvents (acetone, acetonitrile, ethanol, ethyl acetate, methanol, and toluene), which allowed for a direct comparison of absorption features over a wide range of concentrations. A line-shape analysis was adopted with great accuracy (R(2)>0.99) to model the absorption features of TNT in differential reflectivity spectra. We observed a blue shift in the pertinent absorption band with decreasing TNT concentration for all solvents. Moreover, using this technique, it was found that for all utilized solvents the concentration of TNT as well as of RDX, HMX, and tetryl, measured as a function of the transition wavelength of the ultra-violet absorption edge in differential reflectivity spectra shows three distinct regions. A model is presented to explain this behavior which is based on intermolecular hydrogen bonding of explosives molecules with themselves (or lack thereof) at different concentrations. Other intermolecular forces such as dipole-dipole interactions, London dispersion forces and π-stacking contribute to slight variations in the resulting spectra, which were determined to be rather insignificant in comparison to hydrogen bonding. The results are aimed towards a better understanding of the DR spectra of explosives energetic materials. Copyright © 2012 Elsevier B.V. All rights reserved.

Spectroscopic and Density Functional Theory Studies of the Blue–Copper Site in M121SeM and C112SeC Azurin: Cu–Se Versus Cu–S Bonding

PubMed Central

Sarangi, Ritimukta; Gorelsky, Serge I.; Basumallick, Lipika; Hwang, Hee Jung; Pratt, Russell C.; Stack, T. Daniel P.; Lu, Yi; Hodgson, Keith O.; Hedman, Britt; Solomon, Edward I.

2009-01-01

S K-edge X-ray absorption, UV–vis absorption, magnetic circular dichroism (MCD), and resonance Raman spectroscopies are used to investigate the electronic structure differences among WT, M121SeM, and C112SeC Pseudomonas aeruginosa (P.a) azurin. A comparison of S K-edge XAS of WT and M121SeM azurin and a CuII–thioether model complex shows that the 38% S character in the ground state wave function of the blue–copper (BC) sites solely reflects the Cu–SCys bond. Resonance Raman (rR) data on WT and C112SeC azurin give direct evidence for the kinematic coupling between the Cu–SCys stretch and the cysteine deformation modes in WT azurin, which leads to multiple features in the rR spectrum of the BC site. The UV–vis absorption and MCD data on WT, M121SeM, and C112SeC give very similar C0/D0 ratios, indicating that the C-term MCD intensity mechanism involves Cu-centered spin–orbit coupling (SOC). The spectroscopic data combined with density functional theory (DFT) calculations indicate that SCys and SeCys have similar covalent interactions with Cu at their respective bond lengths of 2.1 and 2.3 Å. This reflects the similar electronegativites of S and Se in the thiolate/selenolate ligand fragment and explains the strong spectroscopic similarities between WT and C112SeC azurin. PMID:18314977

M3 spectral analysis of lunar swirls and the link between optical maturation and surface hydroxyl formation at magnetic anomalies

USGS Publications Warehouse

Kramer, G.Y.; Besse, S.; Dhingra, D.; Nettles, J.; Klima, R.; Garrick-Bethell, I.; Clark, Roger N.; Combe, J.-P.; Head, J. W.; Taylor, L.A.; Pieters, C.M.; Boardman, J.; McCord, T.B.

2011-01-01

We examined the lunar swirls using data from the Moon Mineralogy Mapper (M3). The improved spectral and spatial resolution of M3 over previous spectral imaging data facilitates distinction of subtle spectral differences, and provides new information about the nature of these enigmatic features. We characterized spectral features of the swirls, interswirl regions (dark lanes), and surrounding terrain for each of three focus regions: Reiner Gamma, Gerasimovich, and Mare Ingenii. We used Principle Component Analysis to identify spectrally distinct surfaces at each focus region, and characterize the spectral features that distinguish them. We compared spectra from small, recent impact craters with the mature soils into which they penetrated to examine differences in maturation trends on- and off-swirl. Fresh, on-swirl crater spectra are higher albedo, exhibit a wider range in albedos and have well-preserved mafic absorption features compared with fresh off-swirl craters. Albedoand mafic absorptions are still evident in undisturbed, on-swirl surface soils, suggesting the maturation process is retarded. The spectral continuum is more concave compared with off-swirl spectra; a result of the limited spectral reddening being mostly constrained to wavelengths less than ∼1500 nm. Off-swirl spectra show very little reddening or change in continuum shape across the entire M3 spectral range. Off-swirl spectra are dark, have attenuated absorption features, and the narrow range in off-swirl albedos suggests off-swirl regions mature rapidly. Spectral parameter maps depicting the relative OH surface abundance for each of our three swirl focus regions were created using the depth of the hydroxyl absorption feature at 2.82 μm. For each of the studied regions, the 2.82 μm absorption feature is significantly weaker on-swirl than off-swirl, indicating the swirls are depleted in OH relative to their surroundings. The spectral characteristics of the swirls and adjacent terrains from all three focus regions support the hypothesis that the magnetic anomalies deflect solar wind ions away from the swirls and onto off-swirl surfaces. Nanophase iron (npFe0) is largely responsible for the spectral characteristics we attribute to space weathering and maturation, and is created by vaporization/deposition by micrometeorite impacts and sputtering/reduction by solar wind ions. On the swirls, the decreased proton flux slows the spectral effects of space weathering (relative to nonswirl regions) by limiting the npFe0 production mechanism almost exclusively to micrometeoroid impact vaporization/deposition. Immediately adjacent to the swirls, maturation is accelerated by the increased flux of protons deflected from the swirls.

Nonequilibrium iron oxide formation in some low-mass post-asymptotic giant branch stars

NASA Technical Reports Server (NTRS)

Rietmeijer, Frans J. M.

1992-01-01

Using experimental evidence that under highly oxidizing conditions gamma-Fe2O3 (maghemite) and Fe3O4 display refractory behavior, it is proposed that very low C/O ratios, that could be unique to evolving AGB stars, induce nonequilibrium formation of ferromagnetic iron oxide grains along with chondritic dust. The oxides are preferentially fractionated from chondritic dust in the stellar magnetic field which could account for the observed extreme iron underabundance in their photosphere. A search for the 1-2.5-micron IR absorption feature, or for diagnostic magnetite and maghemite IR absorption features, could show the validity of the model proposed.

Optical observations of nearby interstellar gas

NASA Astrophysics Data System (ADS)

Frisch, P. C.; York, D. G.

1984-11-01

Observations indicated that a cloud with a heliocentric velocity of approximately -28 km/s and a hydrogen column density that possibly could be on the order of, or greater than, 5 x 10 to the 19 power/square cm is located within the nearest 50 to 80 parsecs in the direction of Ophiuchus. This is a surprisingly large column density of material for this distance range. The patchy nature of the absorption from the cloud indicates that it may not be a feature with uniform properties, but rather one with small scale structure which includes local enhancements in the column density. This cloud is probably associated with the interstellar cloud at about the same velocity in front of the 20 parsec distant star alpha Oph (Frisch 1981, Crutcher 1982), and the weak interstellar polarization found in stars as near as 35 parsecs in this general region (Tinbergen 1982). These data also indicate that some portion of the -14 km/s cloud also must lie within the 100 parsec region. Similar observations of both Na1 and Ca2 interstellar absorption features were performed in other lines of sight. Similar interstellar absorption features were found in a dozen stars between 20 and 100 parsecs of the Sun.

Optical Observations of Nearby Interstellar Gas

NASA Technical Reports Server (NTRS)

Frisch, P. C.; York, D. G.

1984-01-01

Observations indicated that a cloud with a heliocentric velocity of approximately -28 km/s and a hydrogen column density that possibly could be on the order of, or greater than, 5 x 10 to the 19 power/square cm is located within the nearest 50 to 80 parsecs in the direction of Ophiuchus. This is a surprisingly large column density of material for this distance range. The patchy nature of the absorption from the cloud indicates that it may not be a feature with uniform properties, but rather one with small scale structure which includes local enhancements in the column density. This cloud is probably associated with the interstellar cloud at about the same velocity in front of the 20 parsec distant star alpha Oph (Frisch 1981, Crutcher 1982), and the weak interstellar polarization found in stars as near as 35 parsecs in this general region (Tinbergen 1982). These data also indicate that some portion of the -14 km/s cloud also must lie within the 100 parsec region. Similar observations of both Na1 and Ca2 interstellar absorption features were performed in other lines of sight. Similar interstellar absorption features were found in a dozen stars between 20 and 100 parsecs of the Sun.

A Time-dependant atmospheric model of HD209458b

NASA Astrophysics Data System (ADS)

Iro, N.; Bézard, B.; Guillot, T.

2004-11-01

Charbonneau et al. (2002) conducted HST spectroscopic observations of HD209458 centered on the sodium doublet at 589.3 nm. An absorption feature was found, interpreted as an absorption from the sodium in the planet's atmosphere. However, this feature is weaker than predicted by static radiative equilibrium atmospheric models of HD209458b. We present a time-dependent radiative model of the atmosphere of HD209458b and investigate its thermal structure and chemical composition. Time-dependent temperature profiles are calculated, assuming a constant-with-height zonal wind, modelled as a solid body rotation. We predict day-night variations of the effective temperature of ˜600 K, for an equatorial rotation rate of 1 km s-1, in good agreement with the predictions by Showman & Guillot, 2002. At high altitudes (mbar pressures or less), the night temperatures are low enough to allow sodium to condense into Na2S. Synthetic transit spectra of the visible Na doublet show a much weaker sodium absorption on the morning limb than on the evening limb. The calculated dimming of the sodium feature during a planetary transit agrees with the value reported by Charbonneau et al. (2002).

Detection of Organic Matter in Sediments with Near-Infrared Reflectance Spectroscopy: Effects of Mineralogy, Albedo and Hydration

NASA Astrophysics Data System (ADS)

Kaplan, H. H.; Milliken, R.

2014-12-01

Laboratory, field-, and satellite-based visible-near infrared reflectance spectroscopy allows for rapid, remote, and non-destructive analysis of geologic materials to identify mineralogy as well as organic compounds. This type of analysis has potential to aid the search for organics on Mars as a means of first detection of reduced carbon, or to study organic matter nondestructively in valuable samples such as meteorites. In order to assess potential applications of this method we aim to answer fundamental questions about detection limits and quantification of organic matter using reflectance spectroscopy. Laboratory mixtures and natural samples are measured for total organic carbon (TOC in wt.%) with standard methods and reflectance spectroscopy. Absorption features due to C-H2 and C-H3 bonds are observed in the 3.3 to 3.5μm (3000 to 2850 cm-1) wavelength region. A strong H2O feature near 3μm, as well as carbonate-related absorptions near 3.4µm, are also found in this spectral region and can complicate detection of organic material, particularly at low TOC values. In natural samples without carbonate there appears to be a linear trend between TOC and the band depth of organic absorptions; samples that have low albedo, or strong 3μm water features deviate from this trend line. Spectra of samples with carbonate may be modeled with Gaussians to remove the influence of the carbonate features and better match the organic absorption trend. Early results indicate that quantification of organic matter in natural fine-grained samples using reflectance spectroscopy will need to take low-albedo components and water content into account. Detection limits may also depend on these properties; organic absorption features are clearly seen in the lowest TOC sample measured so far (0.08wt% or 800ppm), which is a relatively bright, carbonate-free, quartz- and clay-dominated outcrop sample. A series of laboratory experiments have been undertaken in which known amounts of organic compounds are mixed with smectitic clay in order to understand detection limits and the effects of albedo and hydration in a controlled setting. These laboratory results are compared with findings from natural samples that represent a wide range of ages and depositional settings.

Effect of in-material losses on terahertz absorption, transmission, and reflection in photonic crystals made of polar dielectrics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serebryannikov, Andriy E., E-mail: andser@amu.edu.pl; Nanotechnology Research Center—NANOTAM, Bilkent University, 06800 Ankara; Nojima, S.

2015-10-07

The effect of the material absorption factor on terahertz absorption (A), transmittance (T), and reflectance (R) for slabs of PhC that comprise rods made of GaAs, a polar dielectric, is studied. The main goal was to illustrate how critical a choice of the absorption factor for simulations is and to indicate the importance of the possible modification of the absorption ability by using either active or lossy impurities. The spectra of A, T, and R are strongly sensitive to the location of the polaritonic gap with respect to the photonic pass and stop bands connected with periodicity that enables themore » efficient combination of the effects of material and structural parameters. It will be shown that the spectra can strongly depend on the utilized value of the material absorption factor. In particular, both narrow and wide absorption bands may appear owing to a variation of the material parameters with a frequency in the vicinity of the polaritonic gap. The latter are often achieved at wideband suppression of transmission, so that an ultra-wide stop band can appear as a result of adjustment of the stop bands having different origin. The results obtained at simultaneous variation of the absorption factor and frequency, and angle of incidence and frequency, indicate the possibility of the existence of wide ranges of tolerance, in which the basic features do remain. This allows for mitigating the accuracy requirements for the absorption factor in simulations and promises the efficient absorption of nonmonochromatic waves and beams with a wide angular spectrum. Suppression of narrowband effects in transmission is demonstrated at rather large values of the absorption factor, when they appear due to either the defect modes related to structural defects or dispersion inspired variations of the material parameters in the vicinity of the polaritonic gap. Comparison with auxiliary structures helps one to detect the common features and differences of homogeneous slabs and slabs of a PhC, which are made of GaAs.« less

Analysis of aircraft spectrometer data with logarithmic residuals

NASA Technical Reports Server (NTRS)

Green, A. A.; Craig, M. D.

1985-01-01

Spectra from airborne systems must be analyzed in terms of their mineral-related absorption features. Methods for removing backgrounds and extracting these features one at a time from reflectance spectra are discussed. Methods for converting radiance spectra into a form similar to reflectance spectra so that the feature extraction procedures can be implemented on aircraft spectrometer data are also discussed.

Functionalization of carbon dioxide and carbon disulfide using a stable uranium(III) alkyl complex.

PubMed

Matson, Ellen M; Forrest, William P; Fanwick, Phillip E; Bart, Suzanne C

2011-04-06

A rare uranium(III) alkyl complex, Tp*(2)U(CH(2)Ph) (2) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate), was synthesized by salt metathesis from Tp*(2)UI (1) and KCH(2)Ph and fully characterized using (1)H NMR, infrared, and electronic absorption spectroscopies as well as X-ray crystallography. This complex has a uranium-carbon distance of 2.57(2) Å, which is comparable to other uranium alkyls reported. Treating this compound with either carbon dioxide or carbon disulfide results in insertion into the uranium-carbon bond to generate Tp*(2)U(κ(2)-O(2)CCH(2)Ph) (3) and Tp*(2)U(SC(S)CH(2)Ph) (4), respectively. These species, characterized spectroscopically and by X-ray crystallography, feature new carboxylate and dithiocarboxylate ligands. Analysis by electronic absorption spectroscopy supports the trivalent oxidation state of the uranium center in both of these derivatives. Addition of trimethylsilylhalides (Me(3)SiX; X = Cl, I) to 3 results in the release of the free silyl ester, Me(3)SiOC(O)CH(2)Ph, forming the initial uranium monohalide species, Tp*(2)UX, which can then be used over multiple cycles for the functionalization of carbon dioxide. © 2011 American Chemical Society

Computer-aided interpretation approach for optical tomographic images

NASA Astrophysics Data System (ADS)

Klose, Christian D.; Klose, Alexander D.; Netz, Uwe J.; Scheel, Alexander K.; Beuthan, Jürgen; Hielscher, Andreas H.

2010-11-01

A computer-aided interpretation approach is proposed to detect rheumatic arthritis (RA) in human finger joints using optical tomographic images. The image interpretation method employs a classification algorithm that makes use of a so-called self-organizing mapping scheme to classify fingers as either affected or unaffected by RA. Unlike in previous studies, this allows for combining multiple image features, such as minimum and maximum values of the absorption coefficient for identifying affected and not affected joints. Classification performances obtained by the proposed method were evaluated in terms of sensitivity, specificity, Youden index, and mutual information. Different methods (i.e., clinical diagnostics, ultrasound imaging, magnet resonance imaging, and inspection of optical tomographic images), were used to produce ground truth benchmarks to determine the performance of image interpretations. Using data from 100 finger joints, findings suggest that some parameter combinations lead to higher sensitivities, while others to higher specificities when compared to single parameter classifications employed in previous studies. Maximum performances are reached when combining the minimum/maximum ratio of the absorption coefficient and image variance. In this case, sensitivities and specificities over 0.9 can be achieved. These values are much higher than values obtained when only single parameter classifications were used, where sensitivities and specificities remained well below 0.8.

The Composition of the Iapetus Dark Material, Hyperion and Phoebe

NASA Astrophysics Data System (ADS)

Stockstill, K. R.; Larson, S. M.; Vilas, F.; Gaffey, M. J.

1996-09-01

A linear mixing model has been used to separate the high-resolution visible/near-infrared reflectance spectrum of the Iapetus dark material from spectra of the leading and trailing sides of Iapetus. A distinct absorption feature centered at 0.67 mu m is apparent in the spectrum. A slight inflection covering 0.4 to 0.6 mu m and a change in slope near 0.73 mu m suggesting the lower wavelength edge of an absorption are also present. These absorption features are attributed to (6) A1 -> (4) T2(G) and (6) A1 -> (4) T1(G) charge transfer transitions in minerals such as goethite and hematite that are products of the aqueous alteration of anhydrous silicates. We confirm the strong, positive spectral slope attributed to organic material. Broadband photometry of Phoebe using ECAS filters was acquired on four nights in 1982 (Tholen and Zellner, Icarus, 1983). On two nights covering the same side of Phoebe, the photometry tested positively for an absorption feature centered at 0.7 mu m due to oxidized iron in phyllosilicates. The opposite side of Phoebe was covered by the other two observations. The spectral difference between two opposite sides of Phoebe suggests that an impact fragmented Phoebe's parent body, producing Phoebe at the junction of two different compositional units. High resolution reflectance spectra have been obtained of the Saturnian satellites Phoebe and Hyperion, the main candidates for a circumsaturnian origin of the Iapetus dark material. These will be discussed.

PROBING FOR EVIDENCE OF PLUMES ON EUROPA WITH HST /STIS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sparks, W. B.; Bergeron, E.; Cracraft, M.

2016-10-01

Roth et al. (2014a) reported evidence for plumes of water venting from a southern high latitude region on Europa: spectroscopic detection of off-limb line emission from the dissociation products of water. Here, we present Hubble Space Telescope direct images of Europa in the far-ultraviolet (FUV) as it transited the smooth face of Jupiter to measure absorption from gas or aerosols beyond the Europa limb. Out of 10 observations, we found 3 in which plume activity could be implicated. Two observations showed statistically significant features at latitudes similar to Roth et al., and the third at a more equatorial location. Wemore » consider potential systematic effects that might influence the statistical analysis and create artifacts, and are unable to find any that can definitively explain the features, although there are reasons to be cautious. If the apparent absorption features are real, the magnitude of implied outgassing is similar to that of the Roth et al. feature; however, the apparent activity appears more frequently in our data.« less

Excitation of phonons in medium-energy electron diffraction

NASA Astrophysics Data System (ADS)

Alvarez, M. A. Vicente; Ascolani, H.; Zampieri, G.

1996-03-01

The ``elastic'' backscattering of electrons from crystalline surfaces presents two regimes: a low-energy regime, in which the characteristic low-energy electron diffraction (LEED) pattern is observed, and a medium-energy regime, in which the diffraction pattern is similar to those observed in x-ray photoemission diffraction (XPD) and Auger electron diffraction (AED) experiments. We present a model for the electron scattering which, including the vibrational degrees of freedom of the crystal, contains both regimes and explains the passage from one regime to the other. Our model is based on a separation of the electron and atomic motions (adiabatic approximation) and on a cluster-type formulation of the multiple scattering of the electron. The inelastic scattering events (excitation and/or absorption of phonons) are treated as coherent processes and no break of the phase relation between the incident and the exit paths of the electron is assumed. The LEED and the medium-energy electron diffraction regimes appear naturally in this model as the limit cases of completely elastic scattering and of inelastic scattering with excitation and/or absorption of multiple phonons. Intensity patterns calculated with this model are in very good agreement with recent experiments of electron scattering on Cu(001) at low and medium energies. We show that there is a correspondence between the type of intensity pattern and the mean number of phonons excited and/or absorbed during the scattering: a LEED-like pattern is observed when this mean number is less than 2, LEED-like and XPD/AED-like features coexist when this number is 3-4, and a XPD/AED-like pattern is observed when this number is greater than 5-6.

Efficient optical analysis of surface texture combinations for silicon solar cells

NASA Astrophysics Data System (ADS)

Tucher, Nico; Eisenlohr, Johannes; Kiefel, Peter; Gebrewold, Habtamu; Höhn, Oliver; Hauser, Hubert; Müller, Claas; Goldschmidt, Jan Christoph; Bläsi, Benedikt

2016-04-01

Surface textures can significantly improve anti-reflective and light trapping properties of silicon solar cells. Combining standard pyramidal front side textures with scattering or diffractive rear side textures has the potential to further increase the light path length inside the silicon and thereby increase the solar cell efficiency. In this work we introduce the OPTOS (Optical Properties of Textured Optical Sheets) simulation formalism and apply it to the modelling of silicon solar cells with different surface textures at front and rear side. OPTOS is a matrix-based method that allows for the computationally-efficient calculation of non-coherent light propagation within textured solar cells, featuring multiple textures that may operate in different optical regimes. After calculating redistribution matrices for each individual surface texture with the most appropriate technique, optical properties like angle dependent reflectance, transmittance or absorptance can be determined via matrix multiplications. Using OPTOS, we demonstrate for example that the integration of a diffractive grating at the rear side of solar cells with random pyramids at the front results in an absorptance gain that corresponds to a photocurrent density enhancement of 0.73 mA/cm2 for a 250 μm thick cell. The re-usability of matrices enables the investigation of different solar cell thicknesses within minutes. For thicknesses down to 50 μm the simulated gain increases up to 1.22 mA/cm2. The OPTOS formalism is furthermore not restricted with respect to the number of textured interfaces. By combining two or more textured sheets to effective interfaces, it is possible to optically model a complete photovoltaic module including EVA and potentially textured glass layers with one calculation tool.

Quantum-enhanced spectroscopy with entangled multiphoton states

NASA Astrophysics Data System (ADS)

Dinani, Hossein T.; Gupta, Manish K.; Dowling, Jonathan P.; Berry, Dominic W.

2016-06-01

Traditionally, spectroscopy is performed by examining the position of absorption lines. However, at frequencies near the transition frequency, additional information can be obtained from the phase shift. In this work we consider the information about the transition frequency obtained from both the absorption and the phase shift, as quantified by the Fisher information in an interferometric measurement. We examine the use of multiple single-photon states, NOON states, and numerically optimized states that are entangled and have multiple photons. We find the optimized states that improve over the standard quantum limit set by independent single photons for some atom number densities.

Chemoselectivity-induced multiple interfaces in MWCNT/Fe3O4@ZnO heterotrimers for whole X-band microwave absorption.

PubMed

Wang, Zhijiang; Wu, Lina; Zhou, Jigang; Jiang, Zhaohua; Shen, Baozhong

2014-11-07

A chemoselective route to induce Fe3O4@ZnO core-shell nanoparticles decorating carbon nanotubes to form MWCNT/Fe3O4@ZnO heterotrimers has been developed. Charges are redistributed in the heterotrimers through C-O-Zn, C-O-Fe and Fe-O-Zn bondings, giving rise to multiple electronic phases. The generated significant interfacial polarization and synergetic interaction between dielectric and magnetic absorbers result in the MWCNT/Fe3O4@ZnO heterotrimers with high-performance microwave absorption in an entire X band.

Ge/graded-SiGe multiplication layers for low-voltage and low-noise Ge avalanche photodiodes on Si

NASA Astrophysics Data System (ADS)

Miyasaka, Yuji; Hiraki, Tatsurou; Okazaki, Kota; Takeda, Kotaro; Tsuchizawa, Tai; Yamada, Koji; Wada, Kazumi; Ishikawa, Yasuhiko

2016-04-01

A new structure is examined for low-voltage and low-noise Ge-based avalanche photodiodes (APDs) on Si, where a Ge/graded-SiGe heterostructure is used as the multiplication layer of a separate-absorption-carrier-multiplication structure. The Ge/SiGe heterojunction multiplication layer is theoretically shown to be useful for preferentially enhancing impact ionization for photogenerated holes injected from the Ge optical-absorption layer via the graded SiGe, reflecting the valence band discontinuity at the Ge/SiGe interface. This property is effective not only for the reduction of operation voltage/electric field strength in Ge-based APDs but also for the reduction of excess noise resulting from the ratio of the ionization coefficients between electrons and holes being far from unity. Such Ge/graded-SiGe heterostructures are successfully fabricated by ultrahigh-vacuum chemical vapor deposition. Preliminary pin diodes having a Ge/graded-SiGe multiplication layer act reasonably as photodetectors, showing a multiplication gain larger than those for diodes without the Ge/SiGe heterojunction.

The energy loss and nuclear absorption effects in semi-inclusive deep inelastic scattering on nucleus

NASA Astrophysics Data System (ADS)

Song, Li-Hua; Xin, Shang-Fei; Liu, Na

2018-02-01

Semi-inclusive deep inelastic lepton-nucleus scattering provides a good opportunity to investigate the cold nuclear effects on quark propagation and hadronization. Considering the nuclear modification of the quark energy loss and nuclear absorption effects in final state, the leading-order computations on hadron multiplicity ratios for both hadronization occurring outside and inside the medium are performed with the nuclear geometry effect of the path length L of the struck quark in the medium. By fitting the HERMES two-dimensional data on the multiplicity ratios for positively and negatively charged pions and kaons produced on neon, the hadron-nucleon inelastic cross section {σ }h for different identified hadrons is determined, respectively. It is found that our predictions obtained with the analytic parameterizations of quenching weights based on BDMPS formalism and the nuclear absorption factor {N}A(z,ν ) are in good agreement with the experimental measurements. This indicates that the energy loss and nuclear absorption are the main nuclear effects inducing a reduction of the hadron yield for quark hadronization occurring outside and inside the nucleus, respectively.

Exciton absorption of entangled photons in semiconductor quantum wells

NASA Astrophysics Data System (ADS)

Rodriguez, Ferney; Guzman, David; Salazar, Luis; Quiroga, Luis; Condensed Matter Physics Group Team

2013-03-01

The dependence of the excitonic two-photon absorption on the quantum correlations (entanglement) of exciting biphotons by a semiconductor quantum well is studied. We show that entangled photon absorption can display very unusual features depending on space-time-polarization biphoton parameters and absorber density of states for both bound exciton states as well as for unbound electron-hole pairs. We report on the connection between biphoton entanglement, as quantified by the Schmidt number, and absorption by a semiconductor quantum well. Comparison between frequency-anti-correlated, unentangled and frequency-correlated biphoton absorption is addressed. We found that exciton oscillator strengths are highly increased when photons arrive almost simultaneously in an entangled state. Two-photon-absorption becomes a highly sensitive probe of photon quantum correlations when narrow semiconductor quantum wells are used as two-photon absorbers. Research funds from Facultad de Ciencias, Universidad de los Andes

Structural parameter effect of porous material on sound absorption performance of double-resonance material

NASA Astrophysics Data System (ADS)

Fan, C.; Tian, Y.; Wang, Z. Q.; Nie, J. K.; Wang, G. K.; Liu, X. S.

2017-06-01

In view of the noise feature and service environment of urban power substations, this paper explores the idea of compound impedance, fills some porous sound-absorption material in the first resonance cavity of the double-resonance sound-absorption material, and designs a new-type of composite acoustic board. We conduct some acoustic characterizations according to the standard test of impedance tube, and research on the influence of assembly order, the thickness and area density of the filling material, and back cavity on material sound-absorption performance. The results show that the new-type of acoustic board consisting of aluminum fibrous material as inner structure, micro-porous board as outer structure, and polyester-filled space between them, has good sound-absorption performance for low frequency and full frequency noise. When the thickness, area density of filling material and thickness of back cavity increase, the sound absorption coefficient curve peak will move toward low frequency.

Indications of the Mineralogy of Callisto and Mars from Reflectance Spectroscopy.

NASA Astrophysics Data System (ADS)

Calvin, Wendy Marie

1991-02-01

Remotely sensed reflectance spectra contain information on mineral identities, grain sizes, and abundances. This thesis consists of analysis of such spectra for two planetary objects, Callisto and Mars. Theoretical modeling of telescopic spectra of Callisto indicates that the surface consists of 20 to 45 wt% water ice at large grain sizes. In the spectral region beyond 3 μm absorption by hydrated mineral phases is dominant. The non-ice material is spectrally similar to hydrous alteration minerals that are commonly found in certain petrologic types of meteorites. New high-resolution data of Callisto are consistent with the findings of the modeling study. In addition, these new data have identified the presence of a small amount of fine-grained water ice on the leading hemisphere, through a characteristic absorption near 3.4 mum. Variations in the depth of this absorption feature indicate dynamic competition between processes which create and erode fine -grained water ice. Calibration and analysis of spectrometer data from the Mariner 6 and 7 space-craft has provided new information regarding the mineralogy of Mars. Laboratory measurements and theoretical calculations of CO_2 frosts have allowed an analysis of spectra taken over the martian south polar cap. The grain sizes in the seasonal cap are quite large and there may be evidence of contamination by water frost or dust. Analysis of Mariner spectra in non-polar regions have tentatively identified absorption features near 2.76 μm and 5.4 mum. The location of these features, and other absorptions identified from terrestrial observations, are consistent with the spectra of hydrous magnesium carbonates. The hydrous carbonates do not have strong spectral features typically associated with carbonates. Theoretical calculations of mixtures indicates that 10-30wt% of these minerals can be included and still be consistent with spectral observations. These minerals form on earth through weathering of mafic minerals with the production of amorphous iron oxides as byproducts, consistent with both present and inferred past martian environments. The presence of hydrous carbonates can provide a mechanism for having abundant carbonates on Mars while spectral searches for (anhydrous) carbonates will not find any evidence for them.

Effect of X-ray irradiation on the optical absorption of СdSe1-xTex nanocrystals embedded in borosilicate glass

NASA Astrophysics Data System (ADS)

Prymak, M. V.; Azhniuk, Yu. M.; Solomon, A. M.; Krasilinets, V. M.; Lopushansky, V. V.; Bodnar, I. V.; Gomonnai, A. V.; Zahn, D. R. T.

2012-07-01

The effect of X-ray irradiation on the optical absorption spectra of CdSe1-xTex nanocrystals embedded in a borosilicate matrix is studied. The observed blue shift of the absorption edge and bleaching of the confinement-related features in the spectra are related to X-ray induced negative ionization of the nanocrystals with charge transfer across the nanocrystal/matrix interface. The radiation-induced changes are observed to recover after longer post-irradiation storage at room temperature.

Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

NASA Technical Reports Server (NTRS)

Goldman, A.; Williams, W. J.; Murcray, D. G.

1974-01-01

The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

Cloud Effects in Hyperspectral Imagery from First-Principles Scene Simulations

DTIC Science & Technology

2009-01-01

SPIE. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, or distribution to multiple locations...scattering and absorption, scattering events, surface scattering with material-dependent bidirectional reflectances, multiple surface adjacency...aerosols or clouds, they may be absorbed, or they may reflect off the ground or an object. A given photon may undergo multiple scattering events

OPTICAL HYDROGEN ABSORPTION CONSISTENT WITH A THIN BOW SHOCK LEADING THE HOT JUPITER HD 189733B

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cauley, P. Wilson; Redfield, Seth; Jensen, Adam G.

Bow shocks are ubiquitous astrophysical phenomena resulting from the supersonic passage of an object through a gas. Recently, pre-transit absorption in UV metal transitions of the hot Jupiter (HJ) exoplanets HD 189733b and WASP12-b have been interpreted as being caused by material compressed in a planetary bow shock. Here we present a robust detection of a time-resolved pre-transit, as well as in-transit absorption signature around the HJ exoplanet HD 189733b using high spectral resolution observations of several hydrogen Balmer lines. The line shape of the pre-transit feature and the shape of the timeseries absorption provide the strongest constraints on themore » morphology and physical characteristics of extended structures around an exoplanet. The in-transit measurements confirm the previous exospheric Hα detection, although the absorption depth measured here is ∼50% lower. The pre-transit absorption feature occurs 125 minutes before the predicted optical transit, a projected linear distance from the planet to the stellar disk of 7.2 R{sub p}. The absorption strength observed in the Balmer lines indicates an optically thick, but physically small, geometry. We model this signal as the early ingress of a planetary bow shock. If the bow shock is mediated by a planetary magnetosphere, the large standoff distance derived from the model suggests a large planetary magnetic field strength of B{sub eq} = 28 G. Better knowledge of exoplanet magnetic field strengths is crucial to understanding the role these fields play in planetary evolution and the potential development of life on planets in the habitable zone.« less

The Magellan Evolution of Galaxies Spectroscopic and Ultraviolet Reference Atlas (MegaSaura). II. Stacked Spectra

NASA Astrophysics Data System (ADS)

Rigby, J. R.; Bayliss, M. B.; Chisholm, J.; Bordoloi, R.; Sharon, K.; Gladders, M. D.; Johnson, T.; Paterno-Mahler, R.; Wuyts, E.; Dahle, H.; Acharyya, A.

2018-01-01

We stack the rest-frame ultraviolet spectra of N = 14 highly magnified gravitationally lensed galaxies at redshifts 1.6< z< 3.6. The resulting new composite spans 900< {λ }{rest}< 3000 Å, with a peak signal-to-noise ratio (S/N) of 103 per spectral resolution element (∼100 km s‑1). It is the highest S/N, highest spectral resolution composite spectrum of z ∼ 2–3 galaxies yet published. The composite reveals numerous weak nebular emission lines and stellar photospheric absorption lines that can serve as new physical diagnostics, particularly at high redshift with the James Webb Space Telescope (JWST). We report equivalent widths to aid in proposing for and interpreting JWST spectra. We examine the velocity profiles of strong absorption features in the composite, and in a matched composite of z∼ 0 COS/HST galaxy spectra. We find remarkable similarity in the velocity profiles at z∼ 0 and z∼ 2, suggesting that similar physical processes control the outflows across cosmic time. While the maximum outflow velocity depends strongly on ionization potential, the absorption-weighted mean velocity does not. As such, the bulk of the high-ionization absorption traces the low-ionization gas, with an additional blueshifted absorption tail extending to at least ‑2000 km s‑1. We interpret this tail as arising from the stellar wind and photospheres of massive stars. Starburst99 models are able to replicate this high-velocity absorption tail. However, these theoretical models poorly reproduce several of the photospheric absorption features, indicating that improvements are needed to match observational constraints on the massive stellar content of star-forming galaxies at z∼ 2. We publicly release our composite spectra.

Suzaku Observations of Near-Relativistic Outflows in the BAL Quasar APM 08279+5255

NASA Astrophysics Data System (ADS)

Saez, C.; Chartas, G.; Brandt, W. N.

2009-05-01

We present results from three Suzaku observations of the z = 3.91 gravitationally lensed broad absorption line quasar APM 08279+5255. We detect strong and broad absorption at rest-frame energies of lsim2 keV (low energy) and 7-12 keV (high energy). The detection of these features confirms the results of previous long-exposure (80-90 ks) Chandra and XMM-Newton observations. The low- and high-energy absorption is detected in both the back-illuminated (BI) and front-illuminated (FI) Suzaku X-ray Imaging Spectrometer spectra (with an F-test significance of gsim99%). We interpret the low-energy absorption as arising from a low-ionization absorber with log N H ~ 23 and the high-energy absorption as due to lines arising from highly ionized (2.75 lsim logξ lsim 4.0, where ξ is the ionization parameter) iron in a near-relativistic outflowing wind. Assuming this interpretation we find that the velocities in the outflow range between 0.1c and 0.6c. We constrain the angle between the outflow direction of the X-ray absorber and our line of sight to be lsim36°. We also detect likely variability of the absorption lines (at the gsim99.9% and gsim98% significance levels in the FI and BI spectra, respectively) with a rest-frame timescale of ~1 month. Assuming that the detected high-energy absorption features arise from Fe XXV, we estimate that the fraction of the total bolometric energy injected over the quasar's lifetime into the intergalactic medium in the form of kinetic energy to be gsim10%.

A multiple-feature and multiple-kernel scene segmentation algorithm for humanoid robot.

PubMed

Liu, Zhi; Xu, Shuqiong; Zhang, Yun; Chen, Chun Lung Philip

2014-11-01

This technical correspondence presents a multiple-feature and multiple-kernel support vector machine (MFMK-SVM) methodology to achieve a more reliable and robust segmentation performance for humanoid robot. The pixel wise intensity, gradient, and C1 SMF features are extracted via the local homogeneity model and Gabor filter, which would be used as inputs of MFMK-SVM model. It may provide multiple features of the samples for easier implementation and efficient computation of MFMK-SVM model. A new clustering method, which is called feature validity-interval type-2 fuzzy C-means (FV-IT2FCM) clustering algorithm, is proposed by integrating a type-2 fuzzy criterion in the clustering optimization process to improve the robustness and reliability of clustering results by the iterative optimization. Furthermore, the clustering validity is employed to select the training samples for the learning of the MFMK-SVM model. The MFMK-SVM scene segmentation method is able to fully take advantage of the multiple features of scene image and the ability of multiple kernels. Experiments on the BSDS dataset and real natural scene images demonstrate the superior performance of our proposed method.

On the limitations of statistical absorption studies with the Sloan Digital Sky Surveys I-III

NASA Astrophysics Data System (ADS)

Lan, Ting-Wen; Ménard, Brice; Baron, Dalya; Johnson, Sean; Poznanski, Dovi; Prochaska, J. Xavier; O'Meara, John M.

2018-07-01

We investigate the limitations of statistical absorption measurements with the Sloan Digital Sky Survey (SDSS) optical spectroscopic surveys. We show that changes in the data reduction strategy throughout different data releases have led to a better accuracy at long wavelengths, in particular for sky line subtraction, but a degradation at short wavelengths with the emergence of systematic spectral features with an amplitude of about 1 per cent. We show that these features originate from inaccuracy in the fitting of modelled F-star spectra used for flux calibration. The best-fitting models for those stars are found to systematically overestimate the strength of metal lines and underestimate that of Lithium. We also identify the existence of artefacts due to masking and interpolation procedures at the wavelengths of the hydrogen Balmer series leading to the existence of artificial Balmer α absorption in all SDSS optical spectra. All these effects occur in the rest frame of the standard stars and therefore present Galactic longitude variations due to the rotation of the Galaxy. We demonstrate that the detection of certain weak absorption lines reported in the literature is solely due to calibration effects. Finally, we discuss new strategies to mitigate these issues.

Effect of the solvent environment on the spectroscopic properties and dynamics of the lowest excited states of carotenoids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frank, H.A.; Bautista, J.A.; Josue, J.

2000-05-11

The spectroscopic properties and dynamics of the lowest excited singlet states of peridinin, fucoxanthin, neoxanthin, uriolide acetate, spheroidene, and spheroidenone in several different solvents have been studied by steady-state absorption and fast-transient optical spectroscopic techniques. Peridinin, fucoxanthin, uriolide acetate, and spheroidenone, which contain carbonyl functional groups in conjugation with the carbon-carbon {pi}-electron system, display broader absorption spectral features and are affected more by the solvent environment than neoxanthin and spheroidene, which do not contain carbonyl functional groups. The possible sources of the spectral broadening are explored by examining the absorption spectra at 77 K in glassy solvents. Also, carotenoids whichmore » contain carbonyls have complex transient absorption spectra and show a pronounced dependence of the excited singlet state lifetime on the solvent environment. It is postulated that these effects are related to the presence of an intramolecular charge transfer state strongly coupled to the S{sub 1} (2{sup 1}A{sub g}) excited singlet state. Structural variations in the series of carotenoids studied here make it possible to focus on the general molecular features that control the spectroscopic and dynamic properties of carotenoids.« less

Gas-phase Absorption of {{\\rm{C}}}_{70}^{2+} below 10 K: Astronomical Implications

NASA Astrophysics Data System (ADS)

Campbell, E. K.; Holz, M.; Maier, J. P.

2017-02-01

The electronic spectrum of the fullerene dication {{{C}}}702+ has been measured in the gas phase at low temperature in a cryogenic radiofrequency ion trap. The spectrum consists of a strong origin band at 7030 Å and two weaker features to higher energy. The bands have FWHMs of 35 Å indicating an excited state lifetime on the order of one-tenth of a picosecond. Absorption cross-section measurements yield (2 ± 1) × 10-15 cm2 at 7030 Å. These results are used to predict the depth of diffuse interstellar bands (DIBs) due to the absorption by {{{C}}}702+. At an assumed column density of 2 × 1012 cm-2 the attenuation of starlight at 7030 Å is around 0.4% and thus the detection of such a shallow and broad interstellar band would be difficult. The electronic spectrum of {{{C}}}602+ shows no absorptions in the visible. Below 4000 Å the spectra of C60, {{{C}}}60+ and {{{C}}}602+ are similar. The large intrinsic FWHM of the features in this region, ˜200 Å for the band near 3250 Å, make them unsuitable for DIB detection.

On the limitations of statistical absorption studies with the Sloan Digital Sky Surveys I-III

NASA Astrophysics Data System (ADS)

Lan, Ting-Wen; Ménard, Brice; Baron, Dalya; Johnson, Sean; Poznanski, Dovi; Prochaska, J. Xavier; O'Meara, John M.

2018-04-01

We investigate the limitations of statistical absorption measurements with the SDSS optical spectroscopic surveys. We show that changes in the data reduction strategy throughout different data releases have led to a better accuracy at long wavelengths, in particular for sky line subtraction, but a degradation at short wavelengths with the emergence of systematic spectral features with an amplitude of about one percent. We show that these features originate from inaccuracy in the fitting of modeled F-star spectra used for flux calibration. The best-fit models for those stars are found to systematically over-estimate the strength of metal lines and under-estimate that of Lithium. We also identify the existence of artifacts due to masking and interpolation procedures at the wavelengths of the hydrogen Balmer series leading to the existence of artificial Balmer α absorption in all SDSS optical spectra. All these effects occur in the rest-frame of the standard stars and therefore present Galactic longitude variations due to the rotation of the Galaxy. We demonstrate that the detection of certain weak absorption lines reported in the literature are solely due to calibration effects. Finally, we discuss new strategies to mitigate these issues.

Absorption spectroscopy of microalgae, cyanobacteria, and dissolved organic matter: Measurements in an integrating sphere cavity

NASA Astrophysics Data System (ADS)

Pogosyan, S. I.; Durgaryan, A. M.; Konyukhov, I. V.; Chivkunova, O. B.; Merzlyak, M. N.

2009-12-01

A device for integrating cavity absorption measurements (ICAM) with an internal diameter of 80 mm suitable for field research is described. The spectral features of the light absorption by some cyanobacteria, green algae, and diatoms in the integrating sphere were studied and the dependences of the absorption on the cell concentration were determined in comparison with the conventional measurements in a 1-cm cuvette. The sensitivity of the chlorophyll estimation with the ICAM reached 0.2-0.5 mg m-3. The results of the ICAM application for the direct analysis of the natural phytoplankton and dissolved organic (“yellow“) matter in the Black Sea and the Sea of Japan are described.

Stellar wind variations in HD 45166: The continuing story. [Wolf-Rayet star

NASA Technical Reports Server (NTRS)

Willis, Allan J.; Stickland, David J.; Heap, Sara R.

1988-01-01

High resolution SWP IUE spectra of HD 45166 (qWR+B8V) obtained over a 36 hr continuous run, together with earlier observations, reveal 2 distinct modes of UV variability in this object. Gross, epoch-linked changes are seen in the strengths of the qWR emission lines, accompanied by large changes in its highly ionized photospheric absorption spectrum. Rapid (hours) variability in strong, multiple, high velocity, wind discrete absorption components (DAC), in the CIV lambda 1550 resonance lines, which superpose to give the appearance of a broad P Cygni absorption profile at many epochs is also observed. These multiple DAC's (often at least 3 are seen) propagate in velocity, from 0.6 to 1.0 v inf, on a timescale of 1 day, implying an acceleration of 180 cm/s comparable to that seen in O-type stars.

On the evaluation of air mass factors for atmospheric near-ultraviolet and visible absorption spectroscopy

NASA Technical Reports Server (NTRS)

Perliski, Lori M.; Solomon, Susan

1993-01-01

The interpretation of UV-visible twilight absorption measurements of atmospheric chemical constituents is dependent on how well the optical path, or air mass factor, of light collected by the spectrometer is understood. A simple single scattering model and a Monte Carlo radiative transfer scheme have been developed to study the effects of multiple scattering, aerosol scattering, surface albedo and refraction on air mass factors for scattered light observations. At fairly short visible wavelengths (less than about 450 nm), stratospheric air mass factors are found to be relatively insensitive to multiple scattering, surface albedo and refraction, as well as aerosol scattering by background aerosols. Longer wavelengths display greater sensitivity to refraction and aerosol scattering. Tropospheric air mass factors are found to be highly dependent on aerosol scattering, surface albedo and, at long visible wavelengths (about 650 nm), refraction. Absorption measurements of NO2 and O4 are shown to support these conclusions.

Microwave absorption properties of carbon nanocoils coated with highly controlled magnetic materials by atomic layer deposition.

PubMed

Wang, Guizhen; Gao, Zhe; Tang, Shiwei; Chen, Chaoqiu; Duan, Feifei; Zhao, Shichao; Lin, Shiwei; Feng, Yuhong; Zhou, Lei; Qin, Yong

2012-12-21

In this work, atomic layer deposition is applied to coat carbon nanocoils with magnetic Fe(3)O(4) or Ni. The coatings have a uniform and highly controlled thickness. The coated nanocoils with coaxial multilayer nanostructures exhibit remarkably improved microwave absorption properties compared to the pristine carbon nanocoils. The enhanced absorption ability arises from the efficient complementarity between complex permittivity and permeability, chiral morphology, and multilayer structure of the products. This method can be extended to exploit other composite materials benefiting from its convenient control of the impedance matching and combination of dielectric-magnetic multiple loss mechanisms for microwave absorption applications.

Using dimers to measure biosignatures and atmospheric pressure for terrestrial exoplanets.

PubMed

Misra, Amit; Meadows, Victoria; Claire, Mark; Crisp, Dave

2014-02-01

We present a new method to probe atmospheric pressure on Earth-like planets using (O2-O2) dimers in the near-infrared. We also show that dimer features could be the most readily detectable biosignatures for Earth-like atmospheres and may even be detectable in transit transmission with the James Webb Space Telescope (JWST). The absorption by dimers changes more rapidly with pressure and density than that of monomers and can therefore provide additional information about atmospheric pressures. By comparing the absorption strengths of rotational and vibrational features to the absorption strengths of dimer features, we show that in some cases it may be possible to estimate the pressure at the reflecting surface of a planet. This method is demonstrated by using the O2 A band and the 1.06 μm dimer feature, either in transmission or reflected spectra. It works best for planets around M dwarfs with atmospheric pressures between 0.1 and 10 bar and for O2 volume mixing ratios above 50% of Earth's present-day level. Furthermore, unlike observations of Rayleigh scattering, this method can be used at wavelengths longer than 0.6 μm and is therefore potentially applicable, although challenging, to near-term planet characterization missions such as JWST. We also performed detectability studies for JWST transit transmission spectroscopy and found that the 1.06 and 1.27 μm dimer features could be detectable (SNR>3) for an Earth analogue orbiting an M5V star at a distance of 5 pc. The detection of these features could provide a constraint on the atmospheric pressure of an exoplanet and serve as biosignatures for oxygenic photosynthesis. We calculated the required signal-to-noise ratios to detect and characterize O2 monomer and dimer features in direct imaging-reflected spectra and found that signal-to-noise ratios greater than 10 at a spectral resolving power of R=100 would be required.

Colors and Compositional Characteristics of Kuiper Belt Objects and Centaurs

NASA Astrophysics Data System (ADS)

Lederer, S. M.; Vilas, F.; Jarvis, K. S.; French, L.

2001-11-01

We present a study designed by Painter et al. (DPS 2000) to search for evidence of aqueous alteration in the surface material of solar system objects. Using VRI broadband photometry, we will search for the presence of the 0.7 um absorption feature (indicative of Fe-bearing hydrated silicates) in KBOs and Centaurs. Vilas (Icarus 111, 1994) found a strong correlation between the presence of the 0.7-um feature in low-albedo asteroids with solar-like colors and the 3-um water of hydration feature, indicative of phyllosilicates. Recent work by Howell et al. (LPSC, 2001) confirms that the presence of the 0.7 um feature in low-albedo asteroids definitely indicates the presence of the 3.0-um water of hydration absorption feature, suggesting the action of aqueous alteration in asteroids. In addition, Feierberg et al. (Icarus 63, 1985) showed that when the U - B color difference is > 0.12 in ECAS photometry, the 3.0-um absorption feature is often present in low albedo asteroids. Therefore, if the U-B color difference is > 0.12 and the 0.7-um feature is present in UBVRI reflectance photometry, water of hydration is implied in KBOs and Centaurs. We pursue these studies based on the mixed flat or steeply reddened photometry of these objects: Water ice has been identified in near-IR dark, flat spectra of some Centaurs, providing a source for the action of aqueous alteration. The complex collisional history proposed for these objects suggests a potential source of heating that would melt water ice, providing a mechanism for aqueous alteration to occur. Finally, we will use BVR photometry to determine the B-V and V-R colors, as has been done by Tegler and Romanishin (Nature, 407). We will compare our results with colors of KBOs and Centaurs published in the literature. This research was supported by the National Research Council and the NASA Planetary Astronomy Program.

Dynamic conductivity modified by impurity resonant states in doping three-dimensional Dirac semimetals

NASA Astrophysics Data System (ADS)

Li, Shuai; Wang, Chen; Zheng, Shi-Han; Wang, Rui-Qiang; Li, Jun; Yang, Mou

2018-04-01

The impurity effect is studied in three-dimensional Dirac semimetals in the framework of a T-matrix method to consider the multiple scattering events of Dirac electrons off impurities. It has been found that a strong impurity potential can significantly restructure the energy dispersion and the density of states of Dirac electrons. An impurity-induced resonant state emerges and significantly modifies the pristine optical response. It is shown that the impurity state disturbs the common longitudinal optical conductivity by creating either an optical conductivity peak or double absorption jumps, depending on the relative position of the impurity band and the Fermi level. More importantly, these conductivity features appear in the forbidden region between the Drude and interband transition, completely or partially filling the Pauli block region of optical response. The underlying physics is that the appearance of resonance states as well as the broadening of the bands leads to a more complicated selection rule for the optical transitions, making it possible to excite new electron-hole pairs in the forbidden region. These features in optical conductivity provide valuable information to understand the impurity behaviors in 3D Dirac materials.

[Study on intestinal absorption features of oligosaccharides in Morinda officinalis How. with sigle-pass perfusion].

PubMed

Deng, Shao-Dong; Zhang, Peng; Lin, Li; Xiao, Feng-Xia; Lin, Jing-Ran

2015-01-01

To study the in situ intestinal absorption of five oligosaccharides contained in Morinda officinalis How. (sucrose, kestose, nystose, 1F-Fructofuranosyinystose and Bajijiasu). The absorption of the five oligosaccharides in small intestine (duodenum, jejunum and ileum) and colon of rats and their contents were investigated by using in situ single-pass perfusion model and HPLC-ELSD. The effects of drug concentration, pH in perfusate and P-glycoprotein inhibitor on the intestinal absorption were investigated to define the intestinal absorption mechanism of the five oligosaccharides in rats. According to the results, all of the five oligosaccharides were absorbed in the whole intestine, and their absorption rates were affected by the pH of the perfusion solution, drug concentration and intestinal segments. Verapamil Hydrochloride could significantly increase the absorptive amount of sucrose and Bajijiasu, suggesting sucrose and Bajijiasu are P-gp's substrate. The five oligosaccharides are absorbed mainly through passive diffusion in the intestinal segments, without saturated absorption. They are absorbed well in all intestines and mainly in duodenum and jejunum.

Reflectance characteristics of dry plant materials

NASA Technical Reports Server (NTRS)

Elvidge, Christopher D.

1987-01-01

Chlorophyll and water obscure the absorption features of all other leaf constituents in the spectra of green leaves. The predominant near-IR and thermal IR spectral features of dry plant materials originate from lignin, cellulose, and hemicellulose. These compounds account for 80 to 98 percent of the dry weight in most plant materials.

Examination of the Measurement of Absorption Using the Reverberant Room Method for Highly Absorptive Acoustic Foam

NASA Technical Reports Server (NTRS)

Hughes, William O.; McNelis, Anne M.; Chris Nottoli; Eric Wolfram

2015-01-01

The absorption coefficient for material specimens are needed to quantify the expected acoustic performance of that material in its actual usage and environment. The ASTM C423-09a standard, "Standard Test Method for Sound Absorption and Sound Absorption Coefficients by the Reverberant Room Method" is often used to measure the absorption coefficient of material test specimens. This method has its basics in the Sabine formula. Although widely used, the interpretation of these measurements are a topic of interest. For example, in certain cases the measured Sabine absorption coefficients are greater than 1.0 for highly absorptive materials. This is often attributed to the diffraction edge effect phenomenon. An investigative test program to measure the absorption properties of highly absorbent melamine foam has been performed at the Riverbank Acoustical Laboratories. This paper will present and discuss the test results relating to the effect of the test materials' surface area, thickness and edge sealing conditions. A follow-on paper is envisioned that will present and discuss the results relating to the spacing between multiple piece specimens, and the mounting condition of the test specimen.

Theoretical studies of the infrared emission from circumstellar dust shells: the infrared characteristics of circumstellar silicates and the mass-loss rate of oxygen-rich late-type giants

NASA Technical Reports Server (NTRS)

Schutte, W. A.; Tielens, A. G.; Allamandola, L. J. (Principal Investigator)

1989-01-01

We have modeled the infrared emission of spherically symmetric, circumstellar dust shells with the aim of deriving the infrared absorption properties of circumstellar silicate grains and the mass-loss rates of the central stars. As a basis for our numerical studies, a simple semianalytical formula has been derived that illustrates the essential characteristics of the infrared emission of such dust shells. A numerical radiative transfer program has been developed and applied to dust shells around oxygen-rich late-type giants. Free parameters in such models include the absorption properties and density distribution of the dust. An approximate, analytical expression is derived for the density distribution of circumstellar dust driven outward by radiation pressure from a central source. A large grid of models has been calculated to study the influence of the free parameters on the emergent spectrum. These results form the basis for a comparison with near-infrared observations. Observational studies have revealed a correlation between the near-infrared color temperature, Tc, and the strength of the 10 micrometers emission or absorption feature, A10. This relationship, which essentially measures the near-infrared optical depth in terms of the 10 micrometers optical depth, is discussed. Theoretical A10-Tc relations have been calculated and compared to the observations. The results show that this relation is a sensitive way to determine the ratio of the near-infrared to 10 micrometers absorption efficiency of circumstellar silicates. These results as well as previous studies show that the near-infrared absorption efficiency of circumstellar silicate grains is much higher than expected from terrestrial minerals. We suggest that this enhanced absorption is due to the presence of ferrous iron (Fe2+) color centers dissolved in the circumstellar silicates. By using the derived value for the ratio of the near-infrared to 10 micrometers absorption efficiency, the observed A10-Tc relation can be calibrated in terms of the total dust column density of the circumstellar shell and thus the mass-loss rate of late-type giants can easily be derived. Detailed models have been made of the infrared emission of three well-studied Miras: R Cas, IRC 10011, and OH 26.5+0.6, with the emphasis on the shape of the 10 micrometers emission or absorption feature. The results show that the intrinsic shape of the 10 micrometers resonance varies from a very broad feature in R Cas to a relatively narrower feature in OH 26.5+0.6, with IRC 10011 somewhere in between. Possible origins of this variation are discussed. The mass-loss rates from these objects are calculated to be 3 x 10(-7), 2 x 10(-5), and 2 x 10(-4) M Sun yr-1 for R Cas, IRC 10011, and OH 26.5+0.6, respectively. These results are compared to other determinations in the literature.

The Colorado Ultraviolet Transit Experiment (CUTE): Observing Mass Loss on Short-Period Exoplanets

NASA Astrophysics Data System (ADS)

Egan, Arika; Fleming, Brian; France, Kevin

2018-06-01

The Colorado Ultraviolet Transit Experiment (CUTE) is an NUV spectrograph packaged into a 6U CubeSat, designed to characterize the interaction between exoplanetary atmospheres and their host stars. CUTE will conduct a transit spectroscopy survey, gathering data over multiple transits on more than 12 short-period exoplanets with a range of masses and radii. The instrument will characterize the spectral properties of the transit light curves to < 1% depth sensitivity. The NUV is host to several high oscillator strength atomic and molecular absorption features predicted to exist in the upper atmospheres of these planets, including Mg I, Mg II, Fe II, and OH. The shape and evolution of these spectral light curves will be used to quantify mass loss rates, the stellar drives of that mass loss, and the possible existence of exoplanetary magnetic fiends. This poster presents the science motivation for CUTE, planned observation and data analysis methods, and expected results.

Thermally activated decomposition of (Ga,Mn)As thin layer at medium temperature post growth annealing

NASA Astrophysics Data System (ADS)

Melikhov, Y.; Konstantynov, P.; Domagala, J.; Sadowski, J.; Chernyshova, M.; Wojciechowski, T.; Syryanyy, Y.; Demchenko, I. N.

2016-05-01

The redistribution of Mn atoms in Ga1-xMnxAs layer during medium-temperature annealing, 250-450 oC, by Mn K-edge X-ray absorption fine structure (XAFS) recorded at ALBA facility, was studied. For this purpose Ga1-xMnxAs thin layer with x=0.01 was grown on AlAs buffer layer deposited on GaAs(100) substrate by molecular beam epitaxy (MBE) followed by annealing. The examined layer was detached from the substrate using a “lift-off” procedure in order to eliminate elastic scattering in XAFS spectra. Fourier transform analysis of experimentally obtained EXAFS spectra allowed to propose a model which describes a redistribution/diffusion of Mn atoms in the host matrix. Theoretical XANES spectra, simulated using multiple scattering formalism (FEFF code) with the support of density functional theory (WIEN2k code), qualitatively describe the features observed in the experimental fine structure.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Applegate, Matthew B.; Alonzo, Carlo; Georgakoudi, Irene

High resolution three-dimensional voids can be directly written into transparent silk fibroin hydrogels using ultrashort pulses of near-infrared (NIR) light. Here, we propose a simple finite-element model that can be used to predict the size and shape of individual features under various exposure conditions. We compare predicted and measured feature volumes for a wide range of parameters and use the model to determine optimum conditions for maximum material removal. The simplicity of the model implies that the mechanism of multiphoton induced void creation in silk is due to direct absorption of light energy rather than diffusion of heat or othermore » photoproducts, and confirms that multiphoton absorption of NIR light in silk is purely a 3-photon process.« less

BATSE Gamma-Ray Burst Line Search. IV. Line Candidates from the Visual Search

NASA Astrophysics Data System (ADS)

Band, D. L.; Ryder, S.; Ford, L. A.; Matteson, J. L.; Palmer, D. M.; Teegarden, B. J.; Briggs, M. S.; Paciesas, W. S.; Pendleton, G. N.; Preece, R. D.

1996-02-01

We evaluate the significance of the line candidates identified by a visual search of burst spectra from BATSE's Spectroscopy Detectors. None of the candidates satisfy our detection criteria: an F-test probability less than 10-4 for a feature in one detector and consistency among the detectors that viewed the burst. Most of the candidates are not very significant and are likely to be fluctuations. Because of the expectation of finding absorption lines, the search was biased toward absorption features. We do not have a quantitative measure of the completeness of the search, which would enable a comparison with previous missions. Therefore, a more objective computerized search has begun.

Detection of a deep 3-microm absorption feature in the spectrum of Amalthea (JV).

PubMed

Takato, Naruhisa; Bus, Schelte J; Terada, Hiroshi; Pyo, Tae-Soo; Kobayashi, Naoto

2004-12-24

Near-infrared spectra of Jupiter's small inner satellites Amalthea and Thebe are similar to those of D-type asteroids in the 0.8- to 2.5-micrometer wavelength range. A deep absorption feature is detected at 3 micrometers in the spectra of the trailing side of Amalthea, which is similar to that of the non-ice components of Callisto and can be attributed to hydrous minerals. These surface materials cannot be explained if the satellite formed at its present orbit by accreting from a circumjovian nebula. Amalthea and Thebe may be the remnants of Jupiter's inflowing building blocks that formed in the outer part or outside of the circumjovian nebula.

Mof-Tree: A Spatial Access Method To Manipulate Multiple Overlapping Features.

ERIC Educational Resources Information Center

Manolopoulos, Yannis; Nardelli, Enrico; Papadopoulos, Apostolos; Proietti, Guido

1997-01-01

Investigates the manipulation of large sets of two-dimensional data representing multiple overlapping features, and presents a new access method, the MOF-tree. Analyzes storage requirements and time with respect to window query operations involving multiple features. Examines both the pointer-based and pointerless MOF-tree representations.…

Overcoming Matrix Effects in a Complex Sample: Analysis of Multiple Elements in Multivitamins by Atomic Absorption Spectroscopy

ERIC Educational Resources Information Center

Arnold, Randy J.; Arndt, Brett; Blaser, Emilia; Blosser, Chris; Caulton, Dana; Chung, Won Sog; Fiorenza, Garrett; Heath, Wyatt; Jacobs, Alex; Kahng, Eunice; Koh, Eun; Le, Thao; Mandla, Kyle; McCory, Chelsey; Newman, Laura; Pithadia, Amit; Reckelhoff, Anna; Rheinhardt, Joseph; Skljarevski, Sonja; Stuart, Jordyn; Taylor, Cassie; Thomas, Scott; Tse, Kyle; Wall, Rachel; Warkentien, Chad

2011-01-01

A multivitamin tablet and liquid are analyzed for the elements calcium, magnesium, iron, zinc, copper, and manganese using atomic absorption spectrometry. Linear calibration and standard addition are used for all elements except calcium, allowing for an estimate of the matrix effects encountered for this complex sample. Sample preparation using…

Cation distribution in NiZn-ferrite films via extended x-ray absorption fine structure

NASA Astrophysics Data System (ADS)

Harris, V. G.; Koon, N. C.; Williams, C. M.; Zhang, Q.; Abe, M.; Kirkland, J. P.

1996-04-01

We have applied extended x-ray absorption fine structure (EXAFS) spectroscopy to study the cation distribution in a series of spin-sprayed NiZn-ferrite films. A least-squares fitting of experimental EXAFS data with theoretical, multiple-scattering, EXAFS data allowed the quantitative determination of site distributions for all transition metal cations.

Estimation of Snow Particle Model Suitable for a Complex and Forested Terrain: Lessons from SnowEx

NASA Astrophysics Data System (ADS)

Gatebe, C. K.; Li, W.; Stamnes, K. H.; Poudyal, R.; Fan, Y.; Chen, N.

2017-12-01

SnowEx 2017 obtained consistent and coordinated ground and airborne remote sensing measurements over Grand Mesa in Colorado, which feature sufficient forested stands to have a range of density and height (and other forest conditions); a range of snow depth/snow water equivalent (SWE) conditions; sufficiently flat snow-covered terrain of a size comparable to airborne instrument swath widths. The Cloud Absorption Radiometer (CAR) data from SnowEx are unique and can be used to assess the accuracy of Bidirectional Reflectance-Distribution Functions (BRDFs) calculated by different snow models. These measurements provide multiple angle and multiple wavelength data needed for accurate surface BRDF characterization. Such data cannot easily be obtained by current satellite remote sensors. Compared to ground-based snow field measurements, CAR measurements minimize the effect of self-shading, and are adaptable to a wide variety of field conditions. We plan to use the CAR measurements as the validation data source for our snow modeling effort. By comparing calculated BRDF results from different snow models to CAR measurements, we can determine which model best explains the snow BRDFs, and is therefore most suitable for application to satellite remote sensing of snow parameters and surface energy budget calculations.

Infrared Multiple-Photon Dissociation spectroscopy of group II metal complexes with salicylate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryan P. Dain; Gary Gresham; Gary S. Groenewold

2011-07-01

Ion-trap tandem mass spectrometry with collision-induced dissociation, and the combination of infrared multiple-photon dissociation (IRMPD) spectroscopy and density functional theory (DFT) calculations were used to characterize singly-charged, 1:1 complexes of Ca2+, Sr2+ and Ba2+ with salicylate. For each metal-salicylate complex, the CID pathways are: (a) elimination of CO2 and (b) formation of [MOH]+ where M=Ca2+, Sr2+ or Ba2+. DFT calculations predict three minima for the cation-salicylate complexes which differ in the mode of metal binding. In the first, the metal ion is coordinated by O atoms of the (neutral) phenol and carboxylate groups of salicylate. In the second, the cationmore » is coordinated by phenoxide and (neutral) carboxylic acid groups. The third mode involves coordination by the carboxylate group alone. The infrared spectrum for the metal-salicylate complexes contains a number of absorptions between 1000 – 1650 cm-1, and the best correlation between theoretical and experimental spectra for the structure that features coordination of the metal ion by phenoxide and the carbonyl group of the carboxylic acid group, consistent with calculated energies for the respective species.« less

Infrared multiple-photon dissociation spectroscopy of group II metal complexes with salicylate.

PubMed

Dain, Ryan P; Gresham, Gary; Groenewold, Gary S; Steill, Jeffrey D; Oomens, Jos; van Stipdonk, Michael J

2011-07-15

Ion trap tandem mass spectrometry with collision-induced dissociation, and the combination of infrared multiple-photon dissociation (IRMPD) spectroscopy and density functional theory (DFT) calculations, were used to characterize singly charged, 1:1 complexes of Ca(2+), Sr(2+) and Ba(2+) with salicylate. For each metal-salicylate complex, the CID pathways are: (a) elimination of CO(2) and (b) formation of [MOH](+) where M = Ca(2+), Sr(2+) or Ba(2+). DFT calculations predict three minima for the cation-salicylate complexes which differ in the mode of metal binding. In the first, the metal ion is coordinated by O atoms of the (neutral) phenol and carboxylate groups of salicylate. In the second, the cation is coordinated by phenoxide and (neutral) carboxylic acid groups. The third mode involves coordination by the carboxylate group alone. The infrared spectrum for the metal-salicylate complexes contains a number of absorptions between 1000 and 1650 cm(-1), and the best correlation between theoretical and experimental spectra is found for the structure that features coordination of the metal ion by phenoxide and the carbonyl O of the carboxylic acid group, consistent with the calculated energies for the respective species. Copyright © 2011 John Wiley & Sons, Ltd.

Infrared spectroscopy of Jupiter and Saturn

NASA Technical Reports Server (NTRS)

Knacke, Roger F.

1993-01-01

Infrared spectroscopy provides unique insights into the chemistry and dynamics of the atmospheres of Jupiter, Saturn, and Titan. In 1991 we obtained data at J, H, K, and M and made repeated observations of Titan's albedo as the satellite orbited Saturn. The J albedo is 12% +/- 3% greater than the albedo measured in 1979; the H and K albedos are the same. There was no evidence for variations at any wavelength over the eastern half of Titan's orbit. We also obtained low resolution (R=50) spectra of Titan between 3.1 and 5.1 microns. The spectra contain evidence for CO and CH3D absorptions. Spectra of Callisto and Ganymede in the 4.5 micron spectral region are featureless and give albedos of 0.08 and 0.04 respectively. If Titan's atmosphere is transparent near 5 microns, its surface albedo there is similar to Callisto's. In 1992 and 1993 we obtained further spectroscopic data of Titan with the UKIRT CGS4 spectrometer. We discovered two unexpected and unexplained spectral features in the 3-4 micron spectrum of Titan. An apparent emission feature near the 3 micron (nu sub 3) band of methane indicated temperatures higher than known to be present in Titan's upper stratosphere and may be caused by unexpected non-LTE emission. An absorption feature near 3.47 microns may be caused by absorption in solid grains or aerosols in Titan's clouds. The feature is similar but not identical to organics in the interstellar matter and in comets.

In-plane crashworthiness of bio-inspired hierarchical honeycombs

DOE PAGES

Yin, Hanfeng; Huang, Xiaofei; Scarpa, Fabrizio; ...

2018-03-13

Biological tissues like bone, wood, and sponge possess hierarchical cellular topologies, which are lightweight and feature an excellent energy absorption capability. Here we present a system of bio-inspired hierarchical honeycomb structures based on hexagonal, Kagome, and triangular tessellations. The hierarchical designs and a reference regular honeycomb configuration are subjected to simulated in-plane impact using the nonlinear finite element code LS-DYNA. The numerical simulation results show that the triangular hierarchical honeycomb provides the best performance compared to the other two hierarchical honeycombs, and features more than twice the energy absorbed by the regular honeycomb under similar loading conditions. We also proposemore » a parametric study correlating the microstructure parameters (hierarchical length ratio r and the number of sub cells N) to the energy absorption capacity of these hierarchical honeycombs. The triangular hierarchical honeycomb with N = 2 and r = 1/8 shows the highest energy absorption capacity among all the investigated cases, and this configuration could be employed as a benchmark for the design of future safety protective systems.« less

Near-infrared spectral reflectance of mineral mixtures - Systematic combinations of pyroxenes, olivine, and iron oxides

NASA Technical Reports Server (NTRS)

Singer, R. B.

1981-01-01

Near-infrared spectral reflectance data are presented for systematic variations in weight percent of two component mixtures of ferromagnesium and iron oxide minerals used to study the dark materials on Mars. Olivine spectral features are greatly reduced in contrast by admixture of other phases but remain distinctive even for low olivine contents. Clinopyroxene and orthopyroxene mixtures show resolved pyroxene absorptions near 2 microns. Limonite greatly modifies pyroxene and olivine reflectance, but does not fully eliminate distinctive spectral characteristics. Using only spectral data in the 1 micron region, it is difficult to differentiate orthopyroxene and limonite in a mixture. All composite mineral absorptions were either weaker than or intermediate in strength to the end-member absorptions and have bandwidths greater than or equal to those for the end members. In general, spectral properties in an intimate mixture combine in a complex, nonadditive manner, with features demonstrating a regular but usually nonlinear variation as a function of end-member phase proportions.

Photoluminescence and gain/absorption spectra of a driven-dissipative electron-hole-photon condensate

NASA Astrophysics Data System (ADS)

Hanai, Ryo; Littlewood, Peter B.; Ohashi, Yoji

2018-06-01

We investigate theoretically nonequilibrium effects on photoluminescence and gain/absorption spectra of a driven-dissipative exciton-polariton condensate, by employing the combined Hartree-Fock-Bogoliubov theory with the generalized random phase approximation extended to the Keldysh formalism. Our calculated photoluminescence spectra is in semiquantitative agreement with experiments, where features such as a blue shift of the emission from the condensate, the appearance of the dispersionless feature of a diffusive Goldstone mode, and the suppression of the dispersive profile of the mode are obtained. We show that the nonequilibrium nature of the exciton-polariton condensate strongly suppresses the visibility of the Bogoliubov dispersion in the negative energy branch (ghost branch) in photoluminescence spectra. We also show that the trace of this branch can be captured as a hole burning effect in gain/absorption spectra. Our results indicate that the nonequilibrium nature of the exciton-polariton condensate strongly reduces quantum depletion, while a scattering channel to the ghost branch is still present.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang Bin; Jewitt, David, E-mail: yangbin@ifa.hawaii.ed, E-mail: jewitt@ucla.ed

Spectrally blue (B-type) asteroids are rare, with the second discovered asteroid, Pallas, being the largest and most famous example. We conducted a focused, infrared spectroscopic survey of B-type asteroids to search for water-related features in these objects. Our results show that the negative optical spectral slope of some B-type asteroids is due to the presence of a broad absorption band centered near 1.0 {mu}m. The 1 {mu}m band can be matched in position and shape using magnetite (Fe{sub 3}O{sub 4}), which is an important indicator of past aqueous alteration in the parent body. Furthermore, our observations of B-type asteroid (335)more » Roberta in the 3 {mu}m region reveal an absorption feature centered at 2.9 {mu}m, which is consistent with the absorption due to phyllosilicates (another hydration product) observed in CI chondrites. The new observations suggest that at least some B-type asteroids are likely to have incorporated significant amounts of water ice and to have experienced intensive aqueous alteration.« less

In-plane crashworthiness of bio-inspired hierarchical honeycombs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yin, Hanfeng; Huang, Xiaofei; Scarpa, Fabrizio

Biological tissues like bone, wood, and sponge possess hierarchical cellular topologies, which are lightweight and feature an excellent energy absorption capability. Here we present a system of bio-inspired hierarchical honeycomb structures based on hexagonal, Kagome, and triangular tessellations. The hierarchical designs and a reference regular honeycomb configuration are subjected to simulated in-plane impact using the nonlinear finite element code LS-DYNA. The numerical simulation results show that the triangular hierarchical honeycomb provides the best performance compared to the other two hierarchical honeycombs, and features more than twice the energy absorbed by the regular honeycomb under similar loading conditions. We also proposemore » a parametric study correlating the microstructure parameters (hierarchical length ratio r and the number of sub cells N) to the energy absorption capacity of these hierarchical honeycombs. The triangular hierarchical honeycomb with N = 2 and r = 1/8 shows the highest energy absorption capacity among all the investigated cases, and this configuration could be employed as a benchmark for the design of future safety protective systems.« less

Measurement of Electronic States of PbS Nanocrystal Quantum Dots Using Scanning Tunneling Spectroscopy: The Role of Parity Selection Rules in Optical Absorption

NASA Astrophysics Data System (ADS)

Diaconescu, Bogdan; Padilha, Lazaro A.; Nagpal, Prashant; Swartzentruber, Brian S.; Klimov, Victor I.

2013-03-01

We study the structure of electronic states in individual PbS nanocrystal quantum dots by scanning tunneling spectroscopy (STS) using one-to-two monolayer nanocrystal films treated with 1, 2-ethanedithiols (EDT). Up to six individual valence and conduction band states are resolved for a range of quantum dot sizes. The measured states’ energies are in good agreement with calculations using the k·p four-band envelope function formalism. A comparison of STS and optical absorption spectra indicates that some of the absorption features can only be explained by asymmetric transitions involving the states of different symmetries (e.g., S and P or P and D), which points towards the relaxation of the parity selection rules in these nanostructures. STS measurements also reveal a midgap feature, which is likely similar to one observed in previous charge transport studies of EDT-treated quantum dot films.

Outbursts by low-mass white dwarfs in symbiotic variables

NASA Technical Reports Server (NTRS)

Sion, Edward M.; Ready, Christian J.

1992-01-01

The high-resolution IUE spectra of the symbiotic variables BF Cygni and EG Andromedae are studied in order to describe the P Cygni-like features of these objects. The 10 high-dispersion IUE spectra are examined for orbital phase-dependent variations in the C IV resonance doublet in terms of velocity and/or structure. One image is found to have a strong He-II absorption feature that coincides in velocity with the C-IV absorption component in P Cygni. The absorbing material for both lines is related to outflow and P Cygni self-absorption near the hot component. The P Cygni profiles do not appear to be related to a red-giant wind nor an expanding circumbinary shell in the in both BF Cyg and EG And. Quasi-static evolutionary model calculations demonstrate an unexpected outburst behavior in response to the assumed accretion. These data are shown to be important for the study of symbiotic systems that contain low-mass white dwarfs.

An x-ray absorption study of the iron site in bacterial photosynthetic reaction centers.

PubMed Central

Bunker, G; Stern, E A; Blankenship, R E; Parson, W W

1982-01-01

Measurements were made of the extended x-ray absorption fine structure (EXAFS) of the iron site in photosynthetic reaction centers from the bacterium Rhodopseudomonas sphaeroides. Forms with two quinones, two quinones with added o-phenanthroline, and one quinone were studied. Only the two forms containing two quinones maintained their integrity and were analyzed. The spectra show directly that the added o-phenanthroline does not chelate the iron atom. Further analysis indicates that the iron is octahedrally coordinated by nitrogen and/or oxygen atoms located at various distances, with the average value of about 2.14 A. The analysis suggests that most of the ligands are nitrogens and that three of the nitrogen ligands belong to histidine rings. This interpretation accounts for several unusual features of the EXAFS spectrum. We speculate that the quinones are bound to the histidine rings in some manner. Qualitative features of the absorption edge spectra also are discussed and are related to the Fe-ligand distance. PMID:6977382

Quantum-correlated two-photon transitions to excitons in semiconductor quantum wells.

PubMed

Salazar, L J; Guzmán, D A; Rodríguez, F J; Quiroga, L

2012-02-13

The dependence of the excitonic two-photon absorption on the quantum correlations (entanglement) of exciting biphotons by a semiconductor quantum well is studied. We show that entangled photon absorption can display very unusual features depending on space-time-polarization biphoton parameters and absorber density of states for both bound exciton states as well as for unbound electron-hole pairs. We report on the connection between biphoton entanglement, as quantified by the Schmidt number, and absorption by a semiconductor quantum well. Comparison between frequency-anti-correlated, unentangled and frequency-correlated biphoton absorption is addressed. We found that exciton oscillator strengths are highly increased when photons arrive almost simultaneously in an entangled state. Two-photon-absorption becomes a highly sensitive probe of photon quantum correlations when narrow semiconductor quantum wells are used as two-photon absorbers.

High enthalpy arc-heated plasma flow diagnostics by tunable diode laser absorption spectroscopy

NASA Astrophysics Data System (ADS)

Lin, Xin; Chen, Lianzhong; Zeng, Hui; Ou, Dongbin; Dong, Yonghui

2017-05-01

This paper reports the laser absorption measurements of atomic oxygen in the FD04 arc-heater at China Academy of Aerospace Aerodynamics (CAAA). An atomic oxygen absorption line at 777.19 nm is utilizied for detecting the population of electronically excited oxygen atom in an air plasma flow. A scanned-wavelength direct absorption mode is used in this study. The laser is scanned in wavelength across the absorption feature at a rate of 200 Hz. Under the assumption of thermal equilibrium, time-resolved temperature measurements are obtained on one line-of-sight in the arc-heater. The good agreement of the temperature inferred from the sonic throat method suggests the equilibrium assumption is valid. These results illustrate the feasibility of the diode laser sensors for flow parameters in high enthalpy arc-heated facilities.

Computer Based Behavioral Biometric Authentication via Multi-Modal Fusion

DTIC Science & Technology

2013-03-01

the decisions made by each individual modality. Fusion of features is the simple concatenation of feature vectors from multiple modalities to be...of Features BayesNet MDL 330 LibSVM PCA 80 J48 Wrapper Evaluator 11 3.5.3 Ensemble Based Decision Level Fusion. In ensemble learning multiple ...The high fusion percentages validate our hypothesis that by combining features from multiple modalities, classification accuracy can be improved. As

No Evidence for Multiple Stellar Populations in the Low-mass Galactic Globular Cluster E 3

NASA Astrophysics Data System (ADS)

Salinas, Ricardo; Strader, Jay

2015-08-01

Multiple stellar populations are a widespread phenomenon among Galactic globular clusters. Even though the origin of the enriched material from which new generations of stars are produced remains unclear, it is likely that self-enrichment will be feasible only in clusters massive enough to retain this enriched material. We searched for multiple populations in the low mass (M˜ 1.4× {10}4 {M}⊙ ) globular cluster E3, analyzing SOAR/Goodman multi-object spectroscopy centered on the blue cyanogen (CN) absorption features of 23 red giant branch stars. We find that the CN abundance does not present the typical bimodal behavior seen in clusters hosting multistellar populations, but rather a unimodal distribution that indicates the presence of a genuine single stellar population, or a level of enrichment much lower than in clusters that show evidence for two populations from high-resolution spectroscopy. E3 would be the first bona fide Galactic old globular cluster where no sign of self-enrichment is found. Based on observations obtained at the Southern Astrophysical Research (SOAR) Telescope, which is a joint project of the Ministério da Ciência, Tecnologia, e Inovação (MCTI) da República Federativa do Brasil, the US National Optical Astronomy Observatory (NOAO), the University of North Carolina at Chapel Hill (UNC), and Michigan State University (MSU).

Atmospheric aerosols: Their Optical Properties and Effects (supplement)

NASA Technical Reports Server (NTRS)

1976-01-01

A digest of technical papers is presented. Topics include aerosol size distribution from spectral attenuation with scattering measurements; comparison of extinction and backscattering coefficients for measured and analytic stratospheric aerosol size distributions; using hybrid methods to solve problems in radiative transfer and in multiple scattering; blue moon phenomena; absorption refractive index of aerosols in the Denver pollution cloud; a two dimensional stratospheric model of the dispersion of aerosols from the Fuego volcanic eruption; the variation of the aerosol volume to light scattering coefficient; spectrophone in situ measurements of the absorption of visible light by aerosols; a reassessment of the Krakatoa volcanic turbidity, and multiple scattering in the sky radiance.

Multi-species detection using multi-mode absorption spectroscopy (MUMAS)

NASA Astrophysics Data System (ADS)

Northern, J. H.; Thompson, A. W. J.; Hamilton, M. L.; Ewart, P.

2013-06-01

The detection of multiple species using a single laser and single detector employing multi-mode absorption spectroscopy (MUMAS) is reported. An in-house constructed, diode-pumped, Er:Yb:glass micro-laser operating at 1,565 nm with 10 modes separated by 18 GHz was used to record MUMAS signals in a gas mixture containing C2H2, N2O and CO. The components of the mixture were detected simultaneously by identifying multiple transitions in each of the species. By using temperature- and pressure-dependent modelled spectral fits to the data, partial pressures of each species in the mixture were determined with an uncertainty of ±2 %.

Can Infrared Spectroscopy Be Used to Measure Change in Potassium Nitrate Concentration as a Proxy for Soil Particle Movement?

PubMed Central

Luleva, Mila Ivanova; van der Werff, Harald; Jetten, Victor; van der Meer, Freek

2011-01-01

Displacement of soil particles caused by erosion influences soil condition and fertility. To date, the cesium 137 isotope (137Cs) technique is most commonly used for soil particle tracing. However when large areas are considered, the expensive soil sampling and analysis present an obstacle. Infrared spectral measurements would provide a solution, however the small concentrations of the isotope do not influence the spectral signal sufficiently. Potassium (K) has similar electrical, chemical and physical properties as Cs. Our hypothesis is that it can be used as possible replacement in soil particle tracing. Soils differing in texture were sampled for the study. Laboratory soil chemical analyses and spectral sensitivity analyses were carried out to identify the wavelength range related to K concentration. Different concentrations of K fertilizer were added to soils with varying texture properties in order to establish spectral characteristics of the absorption feature associated with the element. Changes in position of absorption feature center were observed at wavelengths between 2,450 and 2,470 nm, depending on the amount of fertilizer applied. Other absorption feature parameters (absorption band depth, width and area) were also found to change with K concentration with coefficient of determination between 0.85 and 0.99. Tracing soil particles using K fertilizer and infrared spectral response is considered suitable for soils with sandy and sandy silt texture. It is a new approach that can potentially grow to a technique for rapid monitoring of soil particle movement over large areas. PMID:22163843

Absorption spectrum of a two-level atom in a bad cavity with injected squeezed vacuum

NASA Astrophysics Data System (ADS)

Zhou, Peng; Swain, S.

1996-02-01

We study the absorption spectrum of a coherently driven two-level atom interacting with a resonant cavity mode which is coupled to a broadband squeezed vacuum through its input-output mirror in the bad cavity limit. We study the modification of the two-photon correlation strength of the injected squeezed vacuum inside the cavity, and show that the equations describing probe absorption in the cavity environment are formally identical to these in free space, but with modified parameters describing the squeezed vacuum. The two photon correlations induced by the squeezed vacuum are always weaker than in free space. We pay particular attention to the spectral behaviour at line centre in the region of intermediate trength driving intensities, where anomalous spectral features such as hole-burning and dispersive profiles are displayed. These unusual spectral features are very sensitive to the squeezing phase and the Rabi frequency of the driving field. We also derive the threshold value of the Rabi frequency which gives rise to the transparency of the probe beam at the driving frequency. When the Rabi frequency is less than the threshold value, the probe beam is absorbed, whilst the probe beam is amplified (without population inversion under certain conditions) when the Rabi frequency is larger than this threshold. The anomalous spectral features all take place in the vicinity of the critical point dividing the different dynamical regimes, probe absorption and amplification, of the atomic radiation. The physical origin of the strong amplification without population inversion, and the feasibility of observing it, are discussed.

The Role of Exotic Molecules In Model Exoplanet Spectra

NASA Astrophysics Data System (ADS)

Chang, Caroline; Iyer, Nandini; Morley, Caroline; Fortney, Jonathan J.

2016-01-01

We present the absorption signatures of 21 elemental and molecular species normally found in observed planetary spectra. Fifty model exoplanet spectra that span temperatures from 400 to 2000 K, gravities from 100 to 1000 m/s2, and are 0.3-3 times solar metallicity composition are obtained by converting the pressure-temperature profiles through publicly available radiative transfer code (DISORT), assuming chemical equilibrium conditions. We explore the dependency of an individual specie's effect on a spectrum in the near-IR by removing its equilibrium abundance or enriching the specie's abundance. While testing for the individual effect of each species, it is found that the temperature is a key property for identifying absorption features in this diverse set of model spectra. Strong and abundant absorbers such as CO and CH4 are not as prevalent in high temperature models over 1200 K as H2O at 0.9-2.2 and 2.3-4.1 microns. In addition, we investigate the vertical mixing and disequilibrium of CO and CH4 and find features of these carbon species at 3.3-4.2 and 4.3-5.0 microns across all models. Trace species such as NH3 and Na exhibit prevalent signatures in cold planets (~400-800 K) at the 1-1.1, 1.3-1.5, and 1.6-1.8 micron ranges. A consistent PH3 feature is identified for 400 K spectra at 4-4.8 microns. In our hot model spectra with temperatures greater than 1400 K, TiO shows more significant absorption features than VO, suggesting that these molecules potentially play separate roles in determining thermal inversions. Hydrocarbons such as C2H2 with abundances higher than 10-4 exhibit prevalent absorption features at ~4.2-4.5 microns, indicating that photochemical reactions may be needed to further enrich these abundances. A table of these signatures at their respective temperatures, gravities, and metallicities is presented here. This research presented here was conducted by high-school students under the auspices of the University of California Santa Cruz's Science Internship Program.

Comparative analysis of high-performance infrared avalanche InxGa1-xAsyP1-y and Hg1-xCdxTe heterophotodiodes

NASA Astrophysics Data System (ADS)

Kholodnov, Viacheslav; Drugova, Albina; Nikitin, Mikhail; Chekanova, Galina

2012-10-01

Technology of infrared (IR) avalanche photodiodes (APDs) gradually moves from simple single element APD to 2D focal plane arrays (FPA). Spectral covering of APDs is expanded continuously from classic 1.3 μm to longer wavelengths due to using of narrow-gap semiconductor materials like Hg1-xCdxTe. APDs are of great interest to developers and manufacturers of different optical communication, measuring and 3D reconstruction thermal imaging systems. Major IR detector materials for manufacturing of high-performance APDs became heteroepitaxial structures InxGa1-xAsyP1-y and Hg1-xCdxTe. Progress in IR APD technology was achieved through serious improvement in material growing techniques enabling forming of multilayer heterostuctures with separate absorption and multiplication regions (SAM). Today SAM-APD design can be implemented both on InxGa1-xAsyP1-y and Hg1-xCdxTe multilayer heteroepitaxial structures. To create the best performance optimal design avalanche heterophotodiode (AHPD) it is necessary to carry out a detailed theoretical analysis of basic features of generation, avalanche breakdown and multiplication of charge carriers in proper heterostructure. Optimization of AHPD properties requires comprehensive estimation of AHPD's pixel performance depending on pixel's multi-layer structure design, layers doping, distribution of electric field in the structure and operating temperature. Objective of the present article is to compare some features of 1.55 μm SAM-AHPDs based on InxGa1-xAsyP1-y and Hg1-xCdxTe.

Estimating Achievable Accuracy for Global Imaging Spectroscopy Measurement of Non-Photosynthetic Vegetation Cover

NASA Astrophysics Data System (ADS)

Dennison, P. E.; Kokaly, R. F.; Daughtry, C. S. T.; Roberts, D. A.; Thompson, D. R.; Chambers, J. Q.; Nagler, P. L.; Okin, G. S.; Scarth, P.

2016-12-01

Terrestrial vegetation is dynamic, expressing seasonal, annual, and long-term changes in response to climate and disturbance. Phenology and disturbance (e.g. drought, insect attack, and wildfire) can result in a transition from photosynthesizing "green" vegetation to non-photosynthetic vegetation (NPV). NPV cover can include dead and senescent vegetation, plant litter, agricultural residues, and non-photosynthesizing stem tissue. NPV cover is poorly captured by conventional remote sensing vegetation indices, but it is readily separable from substrate cover based on spectral absorption features in the shortwave infrared. We will present past research motivating the need for global NPV measurements, establishing that mapping seasonal NPV cover is critical for improving our understanding of ecosystem function and carbon dynamics. We will also present new research that helps determine a best achievable accuracy for NPV cover estimation. To test the sensitivity of different NPV cover estimation methods, we simulated satellite imaging spectrometer data using field spectra collected over mixtures of NPV, green vegetation, and soil substrate. We incorporated atmospheric transmittance and modeled sensor noise to create simulated spectra with spectral resolutions ranging from 10 to 30 nm. We applied multiple methods of NPV estimation to the simulated spectra, including spectral indices, spectral feature analysis, multiple endmember spectral mixture analysis, and partial least squares regression, and compared the accuracy and bias of each method. These results prescribe sensor characteristics for an imaging spectrometer mission with NPV measurement capabilities, as well as a "Quantified Earth Science Objective" for global measurement of NPV cover. Copyright 2016, all rights reserved.

Laser absorption of carbon fiber reinforced polymer with randomly distributed carbon fibers

NASA Astrophysics Data System (ADS)

Hu, Jun; Xu, Hebing; Li, Chao

2018-03-01

Laser processing of carbon fiber reinforced polymer (CFRP) is a non-traditional machining method which has many prospective applications. The laser absorption characteristics of CFRP are analyzed in this paper. A ray tracing model describing the interaction of the laser spot with CFRP is established. The material model contains randomly distributed carbon fibers which are generated using an improved carbon fiber placement method. It was found that CFRP has good laser absorption due to multiple reflections of the light rays in the material’s microstructure. The randomly distributed carbon fibers make the absorptivity of the light rays change randomly in the laser spot. Meanwhile, the average absorptivity fluctuation is obvious during movement of the laser. The experimental measurements agree well with the values predicted by the ray tracing model.

Design of Quad-Band Terahertz Metamaterial Absorber Using a Perforated Rectangular Resonator for Sensing Applications.

PubMed

Xie, Qin; Dong, Guangxi; Wang, Ben-Xin; Huang, Wei-Qing

2018-05-08

Quad-band terahertz absorber with single-sized metamaterial design formed by a perforated rectangular resonator on a gold substrate with a dielectric gap in between is investigated. The designed metamaterial structure enables four absorption peaks, of which the first three peaks have large absorption coefficient while the last peak possesses a high Q (quality factor) value of 98.33. The underlying physical mechanisms of these peaks are explored; it is found that their near-field distributions are different. Moreover, the figure of merit (FOM) of the last absorption peak can reach 101.67, which is much higher than that of the first three absorption modes and even absorption bands of other works operated in the terahertz frequency. The designed device with multiple-band absorption and high FOM could provide numerous potential applications in terahertz technology-related fields.

Design of Quad-Band Terahertz Metamaterial Absorber Using a Perforated Rectangular Resonator for Sensing Applications

NASA Astrophysics Data System (ADS)

Xie, Qin; Dong, Guangxi; Wang, Ben-Xin; Huang, Wei-Qing

2018-05-01

Quad-band terahertz absorber with single-sized metamaterial design formed by a perforated rectangular resonator on a gold substrate with a dielectric gap in between is investigated. The designed metamaterial structure enables four absorption peaks, of which the first three peaks have large absorption coefficient while the last peak possesses a high Q (quality factor) value of 98.33. The underlying physical mechanisms of these peaks are explored; it is found that their near-field distributions are different. Moreover, the figure of merit (FOM) of the last absorption peak can reach 101.67, which is much higher than that of the first three absorption modes and even absorption bands of other works operated in the terahertz frequency. The designed device with multiple-band absorption and high FOM could provide numerous potential applications in terahertz technology-related fields.

Implication of Spectral Characteristic of Chlorite Based on Spectrums SWIR in Nuri Deposit of Tibet

NASA Astrophysics Data System (ADS)

Huang, Z.

2017-12-01

This contribution reports the spectral characterization of chlorite in Nuri deposit of Tibet. Nuri Cu polymetallic deposit locates in south rim of Eastern of Gangdise in Tibet. It is presented for large metallogenic scale and special mineralized combination. The study area is underlain extensively by lower Cretaceous rocks of Bima Formation, upper Cretaceous to Paleogene Danshiting Formation and the Quaternary Aeolian Sand. Intrusive bodies, which mainly are quartz diorite, granodiorite, monzonitic granitite, moyite, granite porphyry and so on, feature growth gigantic composite granitic batholith. Distribution of Chlorite is very significant for range and degree of influence of hydrothermal alteration in magmatic hydrothermal deposit. From measuring the spectral of rock and mineral using SVC portable spectrograph, it derived consequence of exists some main altered mineral chlorite. The spectra of chlorite show the absorption features at 1390, 2000, 2250, 2340nm which reflect either O-H stretching vibrations and/or Fe-OH and Mg-OH bending vibrations. Chlorite with Mg-rich shows a strong band at 2324 with a shoulder at 2245nm. The iron-rich chlorite has two absorption features which occur at 2356 and 2256nm. From 110 samples containing chlorite which measured in situ using SVC portable spectrometer, the secondary characteristic absorption wavelengths of chlorite were extracted using TSG software and the diagnosis absorption characteristic of chlorite near 2250nm wavelength is from 2232 to 2266nm. According to the absorption characteristics wavelength position near 2250nm, the samples containing chlorite divided into four categories, i.e. Mg-chlorite whose wavelength less than 2245nm, MgFe-chlorite whose wavelength between 2245 and 2250nm, FeMg-chlorite whose wavelength between 2250 and 2258nm, and Fe-chlorite whose wavelength greater than 2258nm. And then chemical composition of chlorite is analyzed by electron probe with JXA-8230 device which shows that the Fe and AlVI content of chlorite increase or Mg ion content decrease should cause the absorption wavelength of chlorite to shift to long wavelength. The result is very important meaning for mineral prospecting.

Dimensionality-varied deep convolutional neural network for spectral-spatial classification of hyperspectral data

NASA Astrophysics Data System (ADS)

Qu, Haicheng; Liang, Xuejian; Liang, Shichao; Liu, Wanjun

2018-01-01

Many methods of hyperspectral image classification have been proposed recently, and the convolutional neural network (CNN) achieves outstanding performance. However, spectral-spatial classification of CNN requires an excessively large model, tremendous computations, and complex network, and CNN is generally unable to use the noisy bands caused by water-vapor absorption. A dimensionality-varied CNN (DV-CNN) is proposed to address these issues. There are four stages in DV-CNN and the dimensionalities of spectral-spatial feature maps vary with the stages. DV-CNN can reduce the computation and simplify the structure of the network. All feature maps are processed by more kernels in higher stages to extract more precise features. DV-CNN also improves the classification accuracy and enhances the robustness to water-vapor absorption bands. The experiments are performed on data sets of Indian Pines and Pavia University scene. The classification performance of DV-CNN is compared with state-of-the-art methods, which contain the variations of CNN, traditional, and other deep learning methods. The experiment of performance analysis about DV-CNN itself is also carried out. The experimental results demonstrate that DV-CNN outperforms state-of-the-art methods for spectral-spatial classification and it is also robust to water-vapor absorption bands. Moreover, reasonable parameters selection is effective to improve classification accuracy.

Spectral characteristics of the iron oxides with application to the Martian bright region mineralogy

NASA Technical Reports Server (NTRS)

Sherman, D. M.; Burns, R. G.; Mee Burns, V.

1982-01-01

Reflectance spectra of eight polymorphs of FeOOH and Fe2O3 are determined in order to clarify the nature and significance of the iron oxide mineralogy on Mars. The effect of other components that might interfere with iron oxide absorption features is qualitatively constrained through the use of the Kebulka-Munk theory. It is found that the effect of temperature complicates the identification of a given Fe(3+) phase based on the position of the 6A1-4T1 absorption feature. While the Fe(3+) crystal field transitions are spin forbidden, most of the iron oxide polymorphs exhibit anomalously intense crystal field absorption features due to magnetic coupling between adjacent FeO6 octahedra. It is suggested that the resulting deviations from observed remotely sensed reflectance spectra of Mars may provide a basis for the exclusion of many iron oxide phases as significant components of the Martian Fe(3+) mineralogy. A comparison of these results with the visible region spectra of Martian bright regions indicates that the predominant Fe(3+)-bearing phase may be a magnetically disordered material, such as amorphous gels, some ferric sulphates, and other minerals in which Fe(3+) ions in the crystal structure are not magnetically coupled.

Near-infrared absorption spectroscopy of interstellar hydrocarbon grains

NASA Astrophysics Data System (ADS)

Pendleton, Y. J.; Sandford, S. A.; Allamandola, L. J.; Tielens, A. G. G. M.; Sellgren, K.

1994-12-01

We present new 3600 - 2700/cm (2.8 - 3.7 micrometer) spectra of objects whose extinction is dominated by dust in the diffuse interstellar medium. The observations presented here augment an ongoing study of the organic component of the diffuse interstellar medium. These spectra contain a broad feature centered near 3300/cm (3.0 micrometers) and/or a feature with a more complex profile near 2950/cm (3.4 micrometers), the latter of which is attributed to saturated aliphatic hydrocarbons in interstellar grains and is the primary interest of this paper. As in our earlier work, the similarity of the absorption bands near 2950/cm (3.4 micrometers) along different lines of sight and the correlation of these features with interstellar extinction reveal that the carrier of this band lies in the dust in the diffuse interstellar medium (DISM). At least 2.5% of the cosmic carbon in the local interstellar medium and 4% toward the Galactic center is tied up in the carrier of the 2950/cm (3.4 micrometer) band. The spectral structure of the diffuse dust hydrocarbon C-H stretch absorption features is reasonably similar to UV photolyzed laboratory ice residues and is quite similar to the carbonaceous component of the Murchison meteorite. The similarity between the DISM and the meteoritic spectrum suggests that some of the interstellar material originally incorporated into the solar nebula may have survived relatively untouched in primitive solar system bodies. Comparisons of the DISM spectrum to hydrogenated amorphous carbon and quenched carbonaceous composite are also presented. The AV/tau ratio for the 2950/cm (3.4 micrometer) feature is lower toward the Galactic center than toward sources in the local solar neighborhood (approximately 150 for the Galactic center sources vs. approximately 250 for the local ISM sources). A similar trend has been observed previously for silicates in the diffuse medium by Roche & Aitken, suggesting that (1) the silicate and carbonaceous materials in the DISM may be physically correlated and (2) there is either dust compositional variation in the galaxy or galactic variation in the grain population density distribution. We also note a possible absorption feature near 3050/cm (3.28 micrometers), a wavelength position that is characteristic of polycyclic aromatic hydrocarbons (PAHs).

Near-infrared absorption spectroscopy of interstellar hydrocarbon grains

NASA Technical Reports Server (NTRS)

Pendleton, Y. J.; Sandford, S. A.; Allamandola, L. J.; Tielens, A. G. G. M.; Sellgren, K.

1994-01-01

We present new 3600 - 2700/cm (2.8 - 3.7 micrometer) spectra of objects whose extinction is dominated by dust in the diffuse interstellar medium. The observations presented here augment an ongoing study of the organic component of the diffuse interstellar medium. These spectra contain a broad feature centered near 3300/cm (3.0 micrometers) and/or a feature with a more complex profile near 2950/cm (3.4 micrometers), the latter of which is attributed to saturated aliphatic hydrocarbons in interstellar grains and is the primary interest of this paper. As in our earlier work, the similarity of the absorption bands near 2950/cm (3.4 micrometers) along different lines of sight and the correlation of these features with interstellar extinction reveal that the carrier of this band lies in the dust in the diffuse interstellar medium (DISM). At least 2.5% of the cosmic carbon in the local interstellar medium and 4% toward the Galactic center is tied up in the carrier of the 2950/cm (3.4 micrometer) band. The spectral structure of the diffuse dust hydrocarbon C-H stretch absorption features is reasonably similar to UV photolyzed laboratory ice residues and is quite similar to the carbonaceous component of the Murchison meteorite. The similarity between the DISM and the meteoritic spectrum suggests that some of the interstellar material originally incorporated into the solar nebula may have survived relatively untouched in primitive solar system bodies. Comparisons of the DISM spectrum to hydrogenated amorphous carbon and quenched carbonaceous composite are also presented. The A(sub V)/tau ratio for the 2950/cm (3.4 micrometer) feature is lower toward the Galactic center than toward sources in the local solar neighborhood (approximately 150 for the Galactic center sources vs. approximately 250 for the local ISM sources). A similar trend has been observed previously for silicates in the diffuse medium by Roche & Aitken, suggesting that (1) the silicate and carbonaceous materials in the DISM may be physically correlated and (2) there is either dust compositional variation in the galaxy or galactic variation in the grain population density distribution. We also note a possible absorption feature near 3050/cm (3.28 micrometers), a wavelength position that is characteristic of polycyclic aromatic hydrocarbons (PAHs).

Mapping vegetation in Yellowstone National Park using spectral feature analysis of AVIRIS data

USGS Publications Warehouse

Kokaly, Raymond F.; Despain, Don G.; Clark, Roger N.; Livo, K. Eric

2003-01-01

Knowledge of the distribution of vegetation on the landscape can be used to investigate ecosystem functioning. The sizes and movements of animal populations can be linked to resources provided by different plant species. This paper demonstrates the application of imaging spectroscopy to the study of vegetation in Yellowstone National Park (Yellowstone) using spectral feature analysis of data from the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). AVIRIS data, acquired on August 7, 1996, were calibrated to surface reflectance using a radiative transfer model and field reflectance measurements of a ground calibration site. A spectral library of canopy reflectance signatures was created by averaging pixels of the calibrated AVIRIS data over areas of known forest and nonforest vegetation cover types in Yellowstone. Using continuum removal and least squares fitting algorithms in the US Geological Survey's Tetracorder expert system, the distributions of these vegetation types were determined by comparing the absorption features of vegetation in the spectral library with the spectra from the AVIRIS data. The 0.68 μm chlorophyll absorption feature and leaf water absorption features, centered near 0.98 and 1.20 μm, were analyzed. Nonforest cover types of sagebrush, grasslands, willows, sedges, and other wetland vegetation were mapped in the Lamar Valley of Yellowstone. Conifer cover types of lodgepole pine, whitebark pine, Douglas fir, and mixed Engelmann spruce/subalpine fir forests were spectrally discriminated and their distributions mapped in the AVIRIS images. In the Mount Washburn area of Yellowstone, a comparison of the AVIRIS map of forest cover types to a map derived from air photos resulted in an overall agreement of 74.1% (kappa statistic=0.62).

Observational Evidence Linking Interstellar UV Absorption to PAH Molecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blasberger, Avi; Behar, Ehud; Perets, Hagai B.

The 2175 Å UV extinction feature was discovered in the mid-1960s, yet its physical origin remains poorly understood. One suggestion is absorption by polycyclic aromatic hydrocarbon (PAH) molecules, which is supported by theoretical molecular structure computations and by laboratory experiments. PAHs are positively detected by their 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 μ m IR emission bands, which are specified by their modes of vibration. A definitive empirical link between the 2175 Å UV extinction and the IR PAH emission bands, however, is still missing. We present a new sample of hot stars that have both 2175 Å absorptionmore » and IR PAH emission. We find significant shifts of the central wavelength of the UV absorption feature, up to 2350 Å, but predominantly in stars that also have IR PAH emission. These UV shifts depend on stellar temperature in a fashion that is similar to the shifts of the 6.2 and 7.7 μ m IR PAH bands, that is, the features are increasingly more redshifted as the stellar temperature decreases, but only below ∼15 kK. Above 15 kK both UV and IR features retain their nominal values. Moreover, we find a suggestive correlation between the UV and IR shifts. We hypothesize that these similar dependences of both the UV and IR features on stellar temperature hint at a common origin of the two in PAH molecules and may establish the missing link between the UV and IR observations. We further suggest that the shifts depend on molecular size, and that the critical temperature of ∼15 kK above which no shifts are observed is related to the onset of UV-driven hot-star winds and their associated shocks.« less

EXhype: A tool for mineral classification using hyperspectral data

NASA Astrophysics Data System (ADS)

Adep, Ramesh Nityanand; shetty, Amba; Ramesh, H.

2017-02-01

Various supervised classification algorithms have been developed to classify earth surface features using hyperspectral data. Each algorithm is modelled based on different human expertises. However, the performance of conventional algorithms is not satisfactory to map especially the minerals in view of their typical spectral responses. This study introduces a new expert system named 'EXhype (Expert system for hyperspectral data classification)' to map minerals. The system incorporates human expertise at several stages of it's implementation: (i) to deal with intra-class variation; (ii) to identify absorption features; (iii) to discriminate spectra by considering absorption features, non-absorption features and by full spectra comparison; and (iv) finally takes a decision based on learning and by emphasizing most important features. It is developed using a knowledge base consisting of an Optimal Spectral Library, Segmented Upper Hull method, Spectral Angle Mapper (SAM) and Artificial Neural Network. The performance of the EXhype is compared with a traditional, most commonly used SAM algorithm using Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data acquired over Cuprite, Nevada, USA. A virtual verification method is used to collect samples information for accuracy assessment. Further, a modified accuracy assessment method is used to get a real users accuracies in cases where only limited or desired classes are considered for classification. With the modified accuracy assessment method, SAM and EXhype yields an overall accuracy of 60.35% and 90.75% and the kappa coefficient of 0.51 and 0.89 respectively. It was also found that the virtual verification method allows to use most desired stratified random sampling method and eliminates all the difficulties associated with it. The experimental results show that EXhype is not only producing better accuracy compared to traditional SAM but, can also rightly classify the minerals. It is proficient in avoiding misclassification between target classes when applied on minerals.

Light absorption and morphological properties of soot-containing aerosols observed at an East Asian outflow site, Noto Peninsula, Japan

NASA Astrophysics Data System (ADS)

Ueda, Sayako; Nakayama, Tomoki; Taketani, Fumikazu; Adachi, Kouji; Matsuki, Atsushi; Iwamoto, Yoko; Sadanaga, Yasuhiro; Matsumi, Yutaka

2016-03-01

The coating of black carbon (BC) with inorganic salts and organic compounds can enhance the magnitude of light absorption by BC. To elucidate the enhancement of light absorption of aged BC particles and its relation to the mixing state and morphology of individual particles, we conducted observations of particles at an Asian outflow site in Noto Peninsula, Japan, in the spring of 2013. Absorption and scattering coefficients at 405, 532, and 781 nm and mass concentrations/mixing states of refractory BC in PM2.5 were measured using a three-wavelength photoacoustic soot spectrometer and a single-particle soot photometer (SP2), respectively, after passage through a thermodenuder (TD) maintained at 300 or 400 °C or a bypass line maintained at room temperature (25 °C). The average enhancement factor of BC light absorption due to coating was estimated by comparing absorption coefficients at 781 nm for particles that with and without passing through the TD at 300 °C and was found to be 1.22. The largest enhancements (> 1.30) were observed under high absorption coefficient periods when the air mass was long-range transported from urban areas in China. Aerosol samples were also analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer. The morphological features and mixing states of soot-containing particles of four samples collected during the high absorption events were analyzed by comparing microphotographs before and after the evaporation of beam-sensitive materials by irradiation with a high-density electron beam. The majority of the soot in all samples was found as mixed particles with sulfate-containing spherules or as clusters of such spherules. For samples showing high enhancement (> 1.30) of BC light absorption, the TEM showed that the internally mixed soot-containing particles tended to have a more spherical shape and to be thickly coated. The SP2 measurements also suggested that the proportion of thickly coated soot was greater. Thus, the observed enhancement of BC light absorption was found to differ according to the mixing states and morphology of soot-containing particles. The enhancement of BC light absorption in our in situ measurements and its relation with individual features of soot-containing particles will be useful to evaluate direct radiative forcing in the downwind areas of large emission sources of BC.

Light absorption and morphological properties of soot-containing aerosols observed at an East Asian outflow site, Noto Peninsula, Japan

NASA Astrophysics Data System (ADS)

Ueda, S.; Nakayama, T.; Taketani, F.; Adachi, K.; Matsuki, A.; Iwamoto, Y.; Sadanaga, Y.; Matsumi, Y.

2015-09-01

The coating of black carbon (BC) with inorganic salts and organic compounds can enhance the magnitude of light absorption by BC. To elucidate the enhancement of light absorption of aged BC particles and its relation to the mixing state and morphology of individual particles, we conducted observations of particles at an Asian outflow site in Noto Peninsula, Japan, in the spring of 2013. Absorption and scattering coefficients at 405, 532, and 781 nm and mass concentrations/mixing states of refractory-BC in PM2.5 were measured using a three-wavelength photoacoustic soot spectrometer and a single-particle soot photometer (SP2), respectively, after passage through a heater maintained at 300 or 400 °C or a bypass line maintained at room temperature (25 °C). The average enhancement of BC light absorption due to coating was estimated by comparing absorption coefficients at 781 nm for particles that with and without passing through the heater and was found to be 22-23 %. The largest enhancements (> 30 %) were observed under high absorption coefficient conditions when the air mass was long-range transported from urban areas in China. Aerosol samples were also analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer. The morphological features and mixing states of soot-containing particles of four samples collected during the high absorption coefficient events were analyzed by comparing microphotographs before and after the evaporation of beam-sensitive materials by irradiation with a high density electron beam. The majority of the soot in all samples was found as mixed particles with spherical sulfate or as clusters of sulfate spherules. For samples showing high enhancement (> 30 %) of BC light absorption, TEM showed that the internally mixed soot-containing particles tended to have a more spherical shape and to be embedded into the sulfate. The SP2 measurements also suggested that the proportion of thickly-coated soot was greater. Thus, the observed enhancement of BC light absorption was found to differ according to the mixing states and morphology of soot-containing particles. The enhancement of BC light absorption in our in situ measurements and its relation with individual features of soot-containing particles will be useful to evaluate direct radiative forcing in the leeward areas of large emission sources of BC.

Accurate spectroscopic redshift of the multiply lensed quasar PSOJ0147 from the Pan-STARRS survey

NASA Astrophysics Data System (ADS)

Lee, C.-H.

2017-09-01

Context. The gravitational lensing time delay method provides a one-step determination of the Hubble constant (H0) with an uncertainty level on par with the cosmic distance ladder method. However, to further investigate the nature of the dark energy, a H0 estimate down to 1% level is greatly needed. This requires dozens of strongly lensed quasars that are yet to be delivered by ongoing and forthcoming all-sky surveys. Aims: In this work we aim to determine the spectroscopic redshift of PSOJ0147, the first strongly lensed quasar candidate found in the Pan-STARRS survey. The main goal of our work is to derive an accurate redshift estimate of the background quasar for cosmography. Methods: To obtain timely spectroscopically follow-up, we took advantage of the fast-track service programme that is carried out by the Nordic Optical Telescope. Using a grism covering 3200-9600 Å, we identified prominent emission line features, such as Lyα, N V, O I, C II, Si IV, C IV, and [C III] in the spectra of the background quasar of the PSOJ0147 lens system. This enables us to determine accurately the redshift of the background quasar. Results: The spectrum of the background quasar exhibits prominent absorption features bluewards of the strong emission lines, such as Lyα, N V, and C IV. These blue absorption lines indicate that the background source is a broad absorption line (BAL) quasar. Unfortunately, the BAL features hamper an accurate determination of redshift using the above-mentioned strong emission lines. Nevertheless, we are able to determine a redshift of 2.341 ± 0.001 from three of the four lensed quasar images with the clean forbidden line [C III]. In addition, we also derive a maximum outflow velocity of 9800 km s-1 with the broad absorption features bluewards of the C IV emission line. This value of maximum outflow velocity is in good agreement with other BAL quasars.

High Resolution Spectroscopy of X-ray Quasars: Searching for the X-ray Absorption from the Warm-Hot Intergalactic Medium

NASA Technical Reports Server (NTRS)

Fang, Taotao; Canizares, Claude R.; Marshall, Herman L.

2004-01-01

We present a survey of six low to moderate redshift quasars with Chandra and XMM-Newton. The primary goal is to search for the narrow X-ray absorption lines produced by highly ionized metals in the Warm-Hot Intergalactic Medium. All the X-ray spectra can be well fitted by a power law with neutral hydrogen absorption. Only one feature is detected at above 3-sigma level in all the spectra, which is consistent with statistic fluctuation. We discuss the implications in our understanding of the baryon content of the universe. We also discuss the implication of the non-detection of the local (z approx. 0) X-ray absorption.

Radiative transitions involving the (2p2)(3 Pe) metastable autodetaching of H(-)

NASA Technical Reports Server (NTRS)

Jacobs, V. L.; Bhatia, A. K.; Temkin, A.

1974-01-01

The absorption coefficient for the free-bound transition H (ls) + e(-)+ h omega yields H(-)(2 sq p,(3)P(e)) is calculated (together with the differential emission rate for the inverse process) using ls - 2s - 2p close coupling continuum wave functions and a Hylleraas bound state wave function. A maximum in the absorption and emission spectra is found to occur at a photon wavelength of 1219.5 A, which is 2 A closer to the Lyman alpha line than predicted by the calculations of Drake, and is in closer agreement with the stellar absorption feature identified by Heap and Stecher. The free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.

Models of filter-based particle light absorption measurements

NASA Astrophysics Data System (ADS)

Hamasha, Khadeejeh M.

Light absorption by aerosol is very important in the visible, near UN, and near I.R region of the electromagnetic spectrum. Aerosol particles in the atmosphere have a great influence on the flux of solar energy, and also impact health in a negative sense when they are breathed into lungs. Aerosol absorption measurements are usually performed by filter-based methods that are derived from the change in light transmission through a filter where particles have been deposited. These methods suffer from interference between light-absorbing and light-scattering aerosol components. The Aethalometer is the most commonly used filter-based instrument for aerosol light absorption measurement. This dissertation describes new understanding of aerosol light absorption obtained by the filter method. The theory uses a multiple scattering model for the combination of filter and particle optics. The theory is evaluated using Aethalometer data from laboratory and ambient measurements in comparison with photoacoustic measurements of aerosol light absorption. Two models were developed to calculate aerosol light absorption coefficients from the Aethalometer data, and were compared to the in-situ aerosol light absorption coefficients. The first is an approximate model and the second is a "full" model. In the approximate model two extreme cases of aerosol optics were used to develop a model-based calibration scheme for the 7-wavelength Aethalometer. These cases include those of very strong scattering aerosols (Ammonium sulfate sample) and very absorbing aerosols (kerosene soot sample). The exponential behavior of light absorption in the strong multiple scattering limit is shown to be the square root of the total absorption optical depth rather than linear with optical depth as is commonly assumed with Beer's law. 2-stream radiative transfer theory was used to develop the full model to calculate the aerosol light absorption coefficients from the Aethalometer data. This comprehensive model allows for studying very general cases of particles of various sizes embedded on arbitrary filter media. Application of this model to the Reno Aerosol Optics Study (Laboratory data) shows that the aerosol light absorption coefficients are about half of the Aethalometer attenuation coefficients, and there is a reasonable agreement between the model calculated absorption coefficients at 521 nm and the measured photoacoustic absorption coefficients at 532 nm. For ambient data obtained during the Las Vegas study, it shows that the model absorption coefficients at 521 nm are larger than the photoacoustic coefficients at 532 nm. Use of the 2-stream model shows that particle penetration depth into the filter has a strong influence on the interpretation of filter-based aerosol light absorption measurements. This is likely explanation for the difference found between model results for filter-based aerosol light absorption and those from photoacoustic measurements for ambient and laboratory aerosol.

Ultralight Fe@C Nanocapsules/Sponge Composite with Reversibly Tunable Microwave Absorption Performances.

PubMed

Li, Yixing; Mao, Zhe; Liu, Rongge; Zhao, Xiaoning; Zhang, Yanhui; Qin, Gaowu; Zhang, Xuefeng

2017-08-11

Microwave absorbers are usually designed to solve electromagnetic interferences at a specific frequency, while the requirements may be dynamic during service life. Therefore, a recoverable tuning for microwave absorption properties in response to an external stimulus would be highly desirable. We herein present a micro/nano-scale hybrid absorber, in which high-performance Fe@C nanocapsule absorbents are integrated with a porous melamine sponge skeleton, exhibiting multiple merits of light weight, strong absorption and high elasticity. By mechanically compressing and decompressing the absorber, microwave absorption performances can be effectively shifted between 18 GHz and 26.5 GHz. The present study thus provides a new strategy for the design of a 'dynamic' microwave absorber.

Ultralight Fe@C Nanocapsules/Sponge Composite with Reversibly Tunable Microwave Absorption Performances

NASA Astrophysics Data System (ADS)

Li, Yixing; Mao, Zhe; Liu, Rongge; Zhao, Xiaoning; Zhang, Yanhui; Qin, Gaowu; Zhang, Xuefeng

2017-08-01

Microwave absorbers are usually designed to solve electromagnetic interferences at a specific frequency, while the requirements may be dynamic during service life. Therefore, a recoverable tuning for microwave absorption properties in response to an external stimulus would be highly desirable. We herein present a micro/nano-scale hybrid absorber, in which high-performance Fe@C nanocapsule absorbents are integrated with a porous melamine sponge skeleton, exhibiting multiple merits of light weight, strong absorption and high elasticity. By mechanically compressing and decompressing the absorber, microwave absorption performances can be effectively shifted between 18 GHz and 26.5 GHz. The present study thus provides a new strategy for the design of a ‘dynamic’ microwave absorber.

VARIATIONS OF THE 10 mum SILICATE FEATURES IN THE ACTIVELY ACCRETING T TAURI STARS: DG Tau AND XZ Tau

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bary, Jeffrey S.; Leisenring, Jarron M.; Skrutskie, Michael F., E-mail: jbary@colgate.ed, E-mail: jml2u@virginia.ed, E-mail: mfs4n@virginia.ed

2009-11-20

Using the Infrared Spectrograph aboard the Spitzer Space Telescope, we observed multiple epochs of 11 actively accreting T Tauri stars in the nearby Taurus-Auriga star-forming region. In total, 88 low-resolution mid-infrared spectra were collected over 1.5 years in Cycles 2 and 3. The results of this multi-epoch survey show that the 10 mum silicate complex in the spectra of two sources-DG Tau and XZ Tau-undergoes significant variations with the silicate feature growing both weaker and stronger over month- and year-long timescales. Shorter timescale variations on day- to week-long timescales were not detected within the measured flux errors. The time resolutionmore » coverage of this data set is inadequate for determining if the variations are periodic. Pure emission compositional models of the silicate complex in each epoch of the DG Tau and XZ Tau spectra provide poor fits to the observed silicate features. These results agree with those of previous groups that attempted to fit only single-epoch observations of these sources. Simple two-temperature, two-slab models with similar compositions successfully reproduce the observed variations in the silicate features. These models hint at a self-absorption origin of the diminution of the silicate complex instead of a compositional change in the population of emitting dust grains. We discuss several scenarios for producing such variability including disk shadowing, vertical mixing, variations in disk heating, and disk wind events associated with accretion outbursts.« less

Ultraviolet Changes of the Central Source and the Very Nearby Ejecta

NASA Technical Reports Server (NTRS)

Gull, Theodore R.; Nielsen, Krister; Vierira, Gladys; Hillier, John; Walborn, Nolan; Davidson, Kris

2004-01-01

We utilized the high spatial and high spectral resolution of the HST/STIS MAMA echelle modes in the ultraviolet (0.025 inch spatial resolution and 30,000 to 120,000 spectral resolving power) to view changes in and around Eta Carinae before and after the X-Ray drop which occurred on June 29, 2003 (M. Corcoran, IAUC 8160). Major changes in the spectra of the Central Source and nearby nebulosities occurred between June 22 and July 5. Visibility of the Central Source dropped, especially between 1175 and 1350 Angstroms, but not uniformly throughout the ultraviolet. This fading is likely due to multiple line absorptions both in the source and in the intervening ejecta. Nebular emission of Si III] and Fe III, located 0.09 sec. to the west, disappeared. By July 29, a bright feature extending up to 0.071 sec. east of the Central Source became prominent in broad emission lines near 2500 Angstroms, but was not noticeable longward of 2900 Angstroms. ACS/HRC imagery and STIS CCD spectra taken concurrently are being examined for larger scale changes. Numerous narrow velocity components between -146 and -585 kilometers per second were identified in spectra before the minimum. New components appeared primarily in Fe II absorption lines with velocities between -170 and -380 kilometers per second. While the lines of the -513 kilometers per second component did not change, most lines of the -146 kilometers per second component changed considerably. Lines originating from high energy levels diminished or disappeared, while lines originating from lower energy levels strengthened. Strong absorption lines of Ti II, not present before the X-Ray drop, appeared within seven days, but disappeared by July 29. Further analysis of these unprecedented data will provide significant new information about the structure of Eta Carinae and its periodic variations.

Estimating mineral abundances of clay and gypsum mixtures using radiative transfer models applied to visible-near infrared reflectance spectra

NASA Astrophysics Data System (ADS)

Robertson, K. M.; Milliken, R. E.; Li, S.

2016-10-01

Quantitative mineral abundances of lab derived clay-gypsum mixtures were estimated using a revised Hapke VIS-NIR and Shkuratov radiative transfer model. Montmorillonite-gypsum mixtures were used to test the effectiveness of the model in distinguishing between subtle differences in minor absorption features that are diagnostic of mineralogy in the presence of strong H2O absorptions that are not always diagnostic of distinct phases or mineral abundance. The optical constants (k-values) for both endmembers were determined from bi-directional reflectance spectra measured in RELAB as well as on an ASD FieldSpec3 in a controlled laboratory setting. Multiple size fractions were measured in order to derive a single k-value from optimization of the optical path length in the radiative transfer models. It is shown that with careful experimental conditions, optical constants can be accurately determined from powdered samples using a field spectrometer, consistent with previous studies. Variability in the montmorillonite hydration level increased the uncertainties in the derived k-values, but estimated modal abundances for the mixtures were still within 5% of the measured values. Results suggest that the Hapke model works well in distinguishing between hydrated phases that have overlapping H2O absorptions and it is able to detect gypsum and montmorillonite in these simple mixtures where they are present at levels of ∼10%. Care must be taken however to derive k-values from a sample with appropriate H2O content relative to the modeled spectra. These initial results are promising for the potential quantitative analysis of orbital remote sensing data of hydrated minerals, including more complex clay and sulfate assemblages such as mudstones examined by the Curiosity rover in Gale crater.

Light absorption properties of colored dissolved organic matter (CDOM) in adjacent waters of the Changjiang Estuary during a flood season: implication for DOC estimation

NASA Astrophysics Data System (ADS)

Liu, Yangyang; Shen, Fang; Li, Xiuzhen

2014-11-01

Light absorption properties of colored dissolved organic matter (CDOM) in adjacent waters of the Changjiang Estuary were investigated during the summer of 2013. CDOM absorption showed a substantial portion of the total absorption and clearly dominant among most investigation stations. It generally decreased from the northwest to the southeast, which controlled by physical mixing of fresh water and seawater as was indicated by a conservative behaviour of CDOM. CDOM absorption sharply increased during phytoplankton blooms. Similarly, dissolved organic carbon (DOC) also peaked during blooms period. However, DOC exhibited a more complex behavior relative to a simple conservative mixing, possibly attributed to multiple origins of DOC. CDOM absorption and DOC co-varied to some degree, implying a potential way of DOC estimation from CDOM absorption. However, more detailed information such as CDOM and DOC composition and more validation data were required to obtain a stable CDOM - DOC pattern. Lastly, empirical algorithms with limited data were developed to retrieve CDOM absorption. Further validation of the algorithms were needed when they were to be commonly applied.

Hybrid acoustic metamaterial as super absorber for broadband low-frequency sound

PubMed Central

Tang, Yufan; Ren, Shuwei; Meng, Han; Xin, Fengxian; Huang, Lixi; Chen, Tianning; Zhang, Chuanzeng; Lu, Tian Jain

2017-01-01

A hybrid acoustic metamaterial is proposed as a new class of sound absorber, which exhibits superior broadband low-frequency sound absorption as well as excellent mechanical stiffness/strength. Based on the honeycomb-corrugation hybrid core (H-C hybrid core), we introduce perforations on both top facesheet and corrugation, forming perforated honeycomb-corrugation hybrid (PHCH) to gain super broadband low-frequency sound absorption. Applying the theory of micro-perforated panel (MPP), we establish a theoretical method to calculate the sound absorption coefficient of this new kind of metamaterial. Perfect sound absorption is found at just a few hundreds hertz with two-octave 0.5 absorption bandwidth. To verify this model, a finite element model is developed to calculate the absorption coefficient and analyze the viscous-thermal energy dissipation. It is found that viscous energy dissipation at perforation regions dominates the total energy consumed. This new kind of acoustic metamaterials show promising engineering applications, which can serve as multiple functional materials with extraordinary low-frequency sound absorption, excellent stiffness/strength and impact energy absorption. PMID:28240239

Novel ratio difference at coabsorptive point spectrophotometric method for determination of components with wide variation in their absorptivities.

PubMed

Saad, Ahmed S; Abo-Talib, Nisreen F; El-Ghobashy, Mohamed R

2016-01-05

Different methods have been introduced to enhance selectivity of UV-spectrophotometry thus enabling accurate determination of co-formulated components, however mixtures whose components exhibit wide variation in absorptivities has been an obstacle against application of UV-spectrophotometry. The developed ratio difference at coabsorptive point method (RDC) represents a simple effective solution for the mentioned problem, where the additive property of light absorbance enabled the consideration of the two components as multiples of the lower absorptivity component at certain wavelength (coabsorptive point), at which their total concentration multiples could be determined, whereas the other component was selectively determined by applying the ratio difference method in a single step. Mixture of perindopril arginine (PA) and amlodipine besylate (AM) figures that problem, where the low absorptivity of PA relative to AM hinders selective spectrophotometric determination of PA. The developed method successfully determined both components in the overlapped region of their spectra with accuracy 99.39±1.60 and 100.51±1.21, for PA and AM, respectively. The method was validated as per the USP guidelines and showed no significant difference upon statistical comparison with reported chromatographic method. Copyright © 2015 Elsevier B.V. All rights reserved.

Near-ideal optical metamaterial absorbers with super-octave bandwidth.

PubMed

Bossard, Jeremy A; Lin, Lan; Yun, Seokho; Liu, Liu; Werner, Douglas H; Mayer, Theresa S

2014-02-25

Nanostructured optical coatings with tailored spectral absorption properties are of interest for a wide range of applications such as spectroscopy, emissivity control, and solar energy harvesting. Optical metamaterial absorbers have been demonstrated with a variety of customized single band, multiple band, polarization, and angular configurations. However, metamaterials that provide near unity absorptivity with super-octave bandwidth over a specified optical wavelength range have not yet been demonstrated experimentally. Here, we show a broadband, polarization-insensitive metamaterial with greater than 98% measured average absorptivity that is maintained over a wide ± 45° field-of-view for mid-infrared wavelengths between 1.77 and 4.81 μm. The nearly ideal absorption is realized by using a genetic algorithm to identify the geometry of a single-layer metal nanostructure array that excites multiple overlapping electric resonances with high optical loss across greater than an octave bandwidth. The response is optimized by substituting palladium for gold to increase the infrared metallic loss and by introducing a dielectric superstrate to suppress reflection over the entire band. This demonstration advances the state-of-the-art in high-performance broadband metamaterial absorbers that can be reliably fabricated using a single patterned layer of metal nanostructures.

Determining CDOM Absorption Spectra in Diverse Aquatic Environments Using a Multiple Pathlength, Liquid Core Waveguide System

NASA Technical Reports Server (NTRS)

Miller, Richard L.; Belz, Mathias; DelCastillo, Carlos; Trzaska, Rick

2001-01-01

We evaluated the accuracy, sensitivity and precision of a multiple pathlength, liquid core waveguide (MPLCW) system for measuring colored dissolved organic matter (CDOM) absorption in the UV-visible spectral range (370-700 nm). The MPLCW has four optical paths (2.0, 9.8, 49.3, and 204 cm) coupled to a single Teflon AF sample cell. Water samples were obtained from inland, coastal and ocean waters ranging in salinity from 0 to 36 PSU. Reference solutions for the MPLCW were made having a refractive index of the sample. CDOM absorption coefficients, aCDOM, and the slope of the log-linearized absorption spectra, S, were compared with values obtained using a dual-beam spectrophotometer. Absorption of phenol red secondary standards measured by the MPLCW at 558 nm were highly correlated with spectrophotometer values and showed a linear response across all four pathlengths. Values of aCDOM measured using the MPLCW were virtually identical to spectrophotometer values over a wide range of concentrations. The dynamic range of aCDOM for MPLCW measurements was 0.002 - 231.5 m-1. At low CDOM concentrations spectrophotometric aCDOM were slightly greater than MPLCW values and showed larger fluctuations at longer wavelengths due to limitations in instrument precision. In contrast, MPLCW spectra followed an exponential to 600 nm for all samples.

Real-time trace gas sensor using a multimode diode laser and multiple-line integrated cavity enhanced absorption spectroscopy.

PubMed

Karpf, Andreas; Rao, Gottipaty N

2015-07-01

We describe and demonstrate a highly sensitive trace gas sensor based on a simplified design that is capable of measuring sub-ppb concentrations of NO2 in tens of milliseconds. The sensor makes use of a relatively inexpensive Fabry-Perot diode laser to conduct off-axis cavity enhanced spectroscopy. The broad frequency range of a multimode Fabry-Perot diode laser spans a large number of absorption lines, thereby removing the need for a single-frequency tunable laser source. The use of cavity enhanced absorption spectroscopy enhances the sensitivity of the sensor by providing a pathlength on the order of 1 km in a small volume. Off-axis alignment excites a large number of cavity modes simultaneously, thereby reducing the sensor's susceptibility to vibration. Multiple-line integrated absorption spectroscopy (where one integrates the absorption spectra over a large number of rovibronic transitions of the molecular species) further improves the sensitivity of detection. Relatively high laser power (∼400  mW) is used to compensate for the low coupling efficiency of a broad linewidth laser to the optical cavity. The approach was demonstrated using a 407 nm diode laser to detect trace quantities of NO2 in zero air. Sensitivities of 750 ppt, 110 ppt, and 65 ppt were achieved using integration times of 50 ms, 5 s, and 20 s respectively.

Strong anisotropic optical conductivity in two-dimensional puckered structures: The role of the Rashba effect

NASA Astrophysics Data System (ADS)

Saberi-Pouya, S.; Vazifehshenas, T.; Salavati-fard, T.; Farmanbar, M.; Peeters, F. M.

2017-08-01

We calculate the optical conductivity of an anisotropic two-dimensional system with Rashba spin-flip excitation within the Kubo formalism. We show that the anisotropic Rashba effect caused by an external field significantly changes the magnitude of the spin splitting. Furthermore, we obtain an analytical expression for the longitudinal optical conductivity associated with interband transitions as a function of the frequency for arbitrary polarization angle. We find that the diagonal components of the optical conductivity tensor are direction dependent and the optical absorption spectrum exhibits a strongly anisotropic absorption window. The height and width of this absorption window are very sensitive to the anisotropy of the system. While the height of absorption peak increases with increasing effective mass anisotropy ratio, the peak intensity is larger when the light polarization is along the armchair direction. Moreover, the absorption peak width becomes broader as the density-of-states mass or Rashba interaction is enhanced. These features in the optical absorption spectrum can be used to determine parameters relevant for spintronics.

Nitrogen dioxide sensing using a novel gas correlation detector

NASA Astrophysics Data System (ADS)

Kebabian, Paul L.; Annen, Kurt D.; Berkoff, Timothy A.; Freedman, Andrew

2000-05-01

A nitrogen dioxide point sensor, based on a novel nondispersive gas filter spectroscopic scheme, is described. The detection scheme relies on the fact that the absorption spectrum of nitrogen dioxide in the 400-550 nm region consists of a complicated line structure superimposed on an average broadband absorption. A compensating filter is used to remove the effect of the broadband absorption, making the sensor insensitive both to small particles in the optical path and to potentially interfering gases with broadband absorption features in the relevant wavelength region. Measurements are obtained using a remote optical absorption cell that is linked via multimode fibre optics to the source and detection optics. The incorporation of blue light emitting diodes which spectrally match the nitrogen dioxide absorption allows the employment of electronic (instead of mechanical) switching between optical paths. A sensitivity of better than 1.0 ppm m column density (1 s integration time) has been observed; improvements in electronics and thermal stabilization should increase this sensitivity.

The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/Vims

USGS Publications Warehouse

Baines, K.H.; Momary, T.W.; Buratti, B.J.; Matson, D.L.; Nelson, R.M.; Drossart, P.; Sicardy, B.; Formisano, V.; Bellucci, G.; Coradini, A.; Griffith, C.; Brown, R.H.; Bibring, J.-P.; Langevin, Y.; Capaccioni, F.; Cerroni, P.; Clark, R.N.; Combes, M.; Cruikshank, D.P.; Jaumann, R.; McCordt, T.B.; Mennella, V.; Nicholson, P.D.; Sotin, Christophe

2006-01-01

The wide spectral coverage and extensive spatial, temporal, and phase-angle mapping capabilities of the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini-Huygens Orbiter are producing fundamental new insights into the nature of the atmospheres of Saturn and Titan. For both bodies, VIMS maps over time and solar phase angles provide information for a multitude of atmospheric constituents and aerosol layers, providing new insights into atmospheric structure and dynamical and chemical processes. For Saturn, salient early results include evidence for phosphine depletion in relatively dark and less cloudy belts at temperate and mid-latitudes compared to the relatively bright and cloudier Equatorial Region, consistent with traditional theories of belts being regions of relative downwelling. Additional Saturn results include (1) the mapping of enhanced trace gas absorptions at the south pole, and (2) the first high phase-angle, high-spatial-resolution imagery of CH4 fluorescence. An additional fundamental new result is the first nighttime near-infrared mapping of Saturn, clearly showing discrete meteorological features relatively deep in the atmosphere beneath the planet's sunlit haze and cloud layers, thus revealing a new dynamical regime at depth where vertical dynamics is relatively more important than zonal dynamics in determining cloud morphology. Zonal wind measurements at deeper levels than previously available are achieved by tracking these features over multiple days, thereby providing measurements of zonal wind shears within Saturn's troposphere when compared to cloudtop movements measured in reflected sunlight. For Titan, initial results include (1) the first detection and mapping of thermal emission spectra of CO, CO2, and CH3D on Titan's nightside limb, (2) the mapping of CH4 fluorescence over the dayside bright limb, extending to ??? 750 km altitude, (3) wind measurements of ???0.5 ms-1, favoring prograde, from the movement of a persistent (multiple months) south polar cloud near 88??S latitude, and (4) the imaging of two transient mid-southern-latitude cloud features. ?? Springer Science+Business Media, Inc. 2006.

Fast spectroscopic variations on rapidly-rotating, cool dwarfs. 3: Masses of circumstellar absorbing clouds on AB Doradus

NASA Technical Reports Server (NTRS)

Cameron, A. Collier; Duncan, D. K.; Ehrenfreund, P.; Foing, B. H.; Kuntz, K. D.; Penston, M. V.; Robinson, R. D.; Soderblom, D. R.

1989-01-01

New time-resolved H alpha, Ca II H and K and Mg II h and k spectra of the rapidly-rotating K0 dwarf star AB Doradus (= HD 36705). The transient absorption features seen in the H alpha line are also present in the Ca II and Mg II resonance lines. New techniques are developed for measuring the average strength of the line absorption along lines of sight intersecting the cloud. These techniques also give a measure of the projected cloud area. The strength of the resonance line absorption provides useful new constraints on the column densities, projected surface areas, temperatures and internal turbulent velocity dispersions of the circumstellar clouds producing the absorption features. At any given time the star appears to be surrounded by at least 6 to 10 clouds with masses in the range 2 to 6 x 10(exp 17) g. The clouds appear to have turbulent internal velocity dispersions of order 3 to 20 km/s, comparable with the random velocities of discrete filamentary structures in solar quiescent prominences. Night-to-night changes in the amount of Ca II resonance line absorption can be explained by changes in the amplitude of turbulent motions in the clouds. The corresponding changes in the total energy of the internal motions are of order 10(exp 29) erg per cloud. Changes of this magnitude could easily be activated by the frequent energetic (approximately 10(exp 34) erg) x ray flares seen on this star.

Triplet exciton dissociation and electron extraction in graphene-templated pentacene observed with ultrafast spectroscopy.

PubMed

McDonough, Thomas J; Zhang, Lushuai; Roy, Susmit Singha; Kearns, Nicholas M; Arnold, Michael S; Zanni, Martin T; Andrew, Trisha L

2017-02-08

We compare the ultrafast dynamics of singlet fission and charge generation in pentacene films grown on glass and graphene. Pentacene grown on graphene is interesting because it forms large crystals with the long axis of the molecules "lying-down" (parallel to the surface). At low excitation fluence, spectra for pentacene on graphene contain triplet absorptions at 507 and 545 nm and no bleaching at 630 nm, which we show is due to the orientation of the pentacene molecules. We perform the first transient absorption anisotropy measurements on pentacene, observing negative anisotropy of the 507 and 545 nm peaks, consistent with triplet absorption. A broad feature at 853 nm, observed on both glass and graphene, is isotropic, suggesting hole absorption. At high fluence, there are additional features, whose kinetics and anisotropies are not explained by heating, that we assign to charge generation; we propose a polaron pair absorption at 614 nm. The lifetimes are shorter at high fluence for both pentacene on glass and graphene, indicative of triplet-triplet annihilation that likely enhances charge generation. The anisotropy decays more slowly for pentacene on graphene than on glass, in keeping with the smaller domain size observed via atomic force microscopy. Coherent acoustic phonons are observed for pentacene on graphene, which is a consequence of more homogeneous domains. Measuring the ultrafast dynamics of pentacene as a function of molecular orientation, fluence, and polarization provides new insight to previous spectral assignments.