Molecular size and molecular size distribution affecting traditional balsamic vinegar aging.
Falcone, Pasquale Massimiliano; Giudici, Paolo
2008-08-27
A first attempt at a semiquantitative study of molecular weight (MW) and molecular weight distribution (MWD) in cooked grape must and traditional balsamic vinegar (TBV) with increasing well-defined age was performed by high-performance liquid size exclusion chromatography (SEC) using dual detection, that is, differential refractive index (DRI) and absorbance (UV-vis) based detectors. With this aim, MW and MWD, including number- and weight-average MW and polydispersity, were determined with respect to a secondary standard and then analyzed. All investigated vinegar samples were recognized as compositionally and structurally heterogeneous blends of copolymers (melanoidins) spreading over a wide range of molecular sizes: the relative MW ranged from 2 to >2000 kDa. The extent of the polymerization reactions was in agreement with the TBV browning kinetics. MWD parameters varied asymptotically toward either upper or lower limits during aging, reflecting a nonequilibrium status of the balance between polymerization and depolymerization reactions in TBV. MWD parameters were proposed as potential aging markers of TBV.
Transport of dissolved organic matter in Boom Clay: Size effects
NASA Astrophysics Data System (ADS)
Durce, D.; Aertsens, M.; Jacques, D.; Maes, N.; Van Gompel, M.
2018-01-01
A coupled experimental-modelling approach was developed to evaluate the effects of molecular weight (MW) of dissolved organic matter (DOM) on its transport through intact Boom Clay (BC) samples. Natural DOM was sampled in-situ in the BC layer. Transport was investigated with percolation experiments on 1.5 cm BC samples by measuring the outflow MW distribution (MWD) by size exclusion chromatography (SEC). A one-dimensional reactive transport model was developed to account for retardation, diffusion and entrapment (attachment and/or straining) of DOM. These parameters were determined along the MWD by implementing a discretisation of DOM into several MW points and modelling the breakthrough of each point. The pore throat diameter of BC was determined as 6.6-7.6 nm. Below this critical size, transport of DOM is MW dependent and two major types of transport were identified. Below MW of 2 kDa, DOM was neither strongly trapped nor strongly retarded. This fraction had an averaged capacity factor of 1.19 ± 0.24 and an apparent dispersion coefficient ranging from 7.5 × 10- 11 to 1.7 × 10- 11 m2/s with increasing MW. DOM with MW > 2 kDa was affected by both retardation and straining that increased significantly with increasing MW while apparent dispersion coefficients decreased. Values ranging from 1.36 to 19.6 were determined for the capacity factor and 3.2 × 10- 11 to 1.0 × 10- 11 m2/s for the apparent dispersion coefficient for species with 2.2 kDa < MW < 9.3 kDa. Straining resulted in an immobilisation of in average 49 ± 6% of the injected 9.3 kDa species. Our findings show that an accurate description of DOM transport requires the consideration of the size effects.
Offshore Wind Plant Balance-of-Station Cost Drivers and Sensitivities (Poster)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Saur, G.; Maples, B.; Meadows, B.
2012-09-01
With Balance of System (BOS) costs contributing up to 70% of the installed capital cost, it is fundamental to understanding the BOS costs for offshore wind projects as well as potential cost trends for larger offshore turbines. NREL developed a BOS model using project cost estimates developed by GL Garrad Hassan. Aspects of BOS covered include engineering and permitting, ports and staging, transportation and installation, vessels, foundations, and electrical. The data introduce new scaling relationships for each BOS component to estimate cost as a function of turbine parameters and size, project parameters and size, and soil type. Based on themore » new BOS model, an analysis to understand the non-turbine costs associated with offshore turbine sizes ranging from 3 MW to 6 MW and offshore wind plant sizes ranging from 100 MW to 1000 MW has been conducted. This analysis establishes a more robust baseline cost estimate, identifies the largest cost components of offshore wind project BOS, and explores the sensitivity of the levelized cost of energy to permutations in each BOS cost element. This presentation shows results from the model that illustrates the potential impact of turbine size and project size on the cost of energy from US offshore wind plants.« less
Lee, Yun-Kyung; Hur, Jin
2017-08-01
Knowledge of the heterogeneous distribution of humic substances (HS) reactivities along a continuum of molecular weight (MW) is crucial for the systems where the HS MW is subject to change. In this study, two dimensional correlation spectroscopy combined with size exclusion chromatography (2D-CoSEC) was first utilized to obtain a continuous and heterogeneous presence of copper binding characteristics within bulk HS with respect to MW. HS solutions with varying copper concentrations were directly injected into a size exclusion chromatography (SEC) system with Tris-HCl buffer as a mobile phase. Several validation tests confirmed neither structural disruption of HS nor competition effect of the mobile phase used. Similar to batch systems, fluorescence quenching was observed in the chromatograms over a wide range of HS MW. 2D-CoSEC maps of a soil-derived HS (Elliot soil humic acid) showed the greater fluorescence quenching degrees with respect to the apparent MW on the order of 12500 Da > 10600 Da > 7000 Da > 15800 Da. The binding constants calculated based on modified Stern-Volmer equation were consistent with the 2D-CoSEC results. More heterogeneity of copper binding affinities within bulk HS was found for the soil-derived HS versus an aquatic HS. The traditional fluorescence quenching titration method using ultrafiltered HS size fractions failed to delineate detailed distribution of the copper binding characteristics, exhibiting a much shorter range of the binding constants than those obtained from the 2D-CoSEC. Our proposed technique demonstrated a great potential to describe metal binding characteristics of HS at high MW resolution, providing a clear picture of the size-dependent metal-HS interactions. Copyright © 2017 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Trocki, L.K.
1989-09-01
The expected economic benefits from development of a geothermal power plant at Platanares in the Department of Copan, Honduras are evaluated in this report. The economic benefits of geothermal plants ranging in size from a 10-MW plant in the shallow reservoir to a 20-, 30-, 55-, or 110-MW plant in the assumed deeper reservoir were measured by computing optimal expansion plans for each size of geothermal plant. Savings are computed as the difference in present value cost between a plan that contains no geothermal plant and one that does. Present value savings in millions of 1987 dollars range from $25more » million for the 10-MW plant to $110 million for the 110-MW plant -- savings of 6% to 25% over the time period 1988 through 2008. 8 refs., 9 figs., 6 tabs.« less
Size distribution of absorbing and fluorescing DOM in Beaufort Sea, Canada Basin
NASA Astrophysics Data System (ADS)
Gao, Zhiyuan; Guéguen, Céline
2017-03-01
The molecular weight (MW) of dissolved organic matter (DOM) is considered as an important factor affecting the bioavailability of organic matter and associated chemical species. Colored DOM (CDOM) MW distribution was determined, for the first time, in the Beaufort Sea (Canada Basin) by asymmetrical flow field-flow fractionation (AF4) coupled with online diode array ultra violet-visible photometer and offline fluorescence detectors. The apparent MW ranged from 1.07 to 1.45 kDa, congruent with previous studies using high performance size exclusion chromatography and tangential flow filtration. Interestingly, a minimum in MW was associated with the Pacific Summer Waters (PSW), while higher MW was associated with the Pacific Winter Waters (PWW). The Arctic Intermediate Waters (AIW) did not show any significant change in MW and fluorescence intensities distribution between stations, suggesting homogeneous DOM composition in deep waters. Three fluorescence components including two humic-like components and one protein-like component were PARAFAC-validated. With the increase of MW, protein-like fluorescence component became more dominant while the majority remained as marine/microbially derived humic-like components. Overall, it is concluded that water mass origin influenced DOM MW distribution in the Arctic Ocean.
THE MASSIVE SATELLITE POPULATION OF MILKY-WAY-SIZED GALAXIES
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rodriguez-Puebla, Aldo; Avila-Reese, Vladimir; Drory, Niv, E-mail: apuebla@astro.unam.mx
2013-08-20
Several occupational distributions for satellite galaxies more massive than m{sub *} Almost-Equal-To 4 Multiplication-Sign 10{sup 7} M{sub Sun} around Milky-Way (MW)-sized hosts are presented and used to predict the internal dynamics of these satellites as a function of m{sub *}. For the analysis, a large galaxy group mock catalog is constructed on the basis of (sub)halo-to-stellar mass relations fully constrained with currently available observations, namely the galaxy stellar mass function decomposed into centrals and satellites, and the two-point correlation functions at different masses. We find that 6.6% of MW-sized galaxies host two satellites in the mass range of the Smallmore » and Large Magellanic Clouds (SMC and LMC, respectively). The probabilities of the MW-sized galaxies having one satellite equal to or larger than the LMC, two satellites equal to or larger than the SMC, or three satellites equal to or larger than Sagittarius (Sgr) are Almost-Equal-To 0.26, 0.14, and 0.14, respectively. The cumulative satellite mass function of the MW, N{sub s} ({>=}m{sub *}) , down to the mass of the Fornax dwarf is within the 1{sigma} distribution of all the MW-sized galaxies. We find that MW-sized hosts with three satellites more massive than Sgr (as the MW) are among the most common cases. However, the most and second most massive satellites in these systems are smaller than the LMC and SMC by roughly 0.7 and 0.8 dex, respectively. We conclude that the distribution N{sub s} ({>=}m{sub *}) for MW-sized galaxies is quite broad, the particular case of the MW being of low frequency but not an outlier. The halo mass of MW-sized galaxies correlates only weakly with N{sub s} ({>=}m{sub *}). Then, it is not possible to accurately determine the MW halo mass by means of its N{sub s} ({>=}m{sub *}); from our catalog, we constrain a lower limit of 1.38 Multiplication-Sign 10{sup 12} M{sub Sun} at the 1{sigma} level. Our analysis strongly suggests that the abundance of massive subhalos should agree with the abundance of massive satellites in all MW-sized hosts, i.e., there is not a missing (massive) satellite problem for the {Lambda}CDM cosmology. However, we confirm that the maximum circular velocity, v{sub max}, of the subhalos of satellites smaller than m{sub *} {approx} 10{sup 8} M{sub Sun} is systematically larger than the v{sub max} inferred from current observational studies of the MW bright dwarf satellites; different from previous works, this conclusion is based on an analysis of the overall population of MW-sized galaxies. Some pieces of evidence suggest that the issue could refer only to satellite dwarfs but not to central dwarfs, then environmental processes associated with dwarfs inside host halos combined with supernova-driven core expansion should be on the basis of the lowering of v{sub max}.« less
Pectin characterisation using size exclusion chromatography: A comparison of ELS and RI detection.
Muñoz-Almagro, Nerea; Rico-Rodriguez, Fabián; Villamiel, Mar; Montilla, Antonia
2018-06-30
A high-performance size-exclusion chromatography (HPSEC) method coupled to Evaporative Light Scattering (ELS) and Refractive Index (RI) detectors were evaluated and compared for the molecular mass (Mw) estimation of pectin in a wide range (0.342-805 kDa). Instrumental parameters of the ELSD were optimised by Response Surface Methodology (RSM) being 73 °C the evaporator temperature and 0.9 mL/min the air flow rate. The linear range for the ELSD concentration response was wider (10-2250 mg/L) and better (R 2 = 0.985) than RID (10-1500 mg/L; R 2 = 0.875). The limits of detection (LOD) and quantitation (LOQ) for all pullulans hardly changed in ELSD (LOD: 1.22-1.99 mg/L; LOQ: 4.07-6.63 mg/L); however, RID showed huge variations (LOD: 0.49-10.41 mg/L; LOQ: 1.64-34.70 mg/L), which increased with the Mw. In general, responses of both detectors were similar for the Mw estimation, although pectin characterisation with HPSEC-ELSD exhibited better results in the lowest Mw compounds. Copyright © 2018 Elsevier Ltd. All rights reserved.
Sheth, Saumil; Lanzetta, Paolo; Veritti, Daniele; Zucchiatti, Ilaria; Savorgnani, Carola; Bandello, Francesco
2011-01-01
Aim: To systematically refine and recommend parameter settings of spot size, power, and treatment duration using the Pascal® photocoagulator, a multi-spot, semi-automated, short-duration laser system. Materials and Methods: A retrospective consecutive series with 752 Caucasian eyes and 1242 laser procedures over two years were grouped into, (1) 374 macular focal / grid photocoagulation (FP), (2), 666 panretinal photocoagulation (PRP), and (3) 202 barrage photocoagulation (BP). Parameters for power, duration, spot number, and spot size were recorded for every group. Results: Power parameters for all groups showed a non-gaussian distribution; FP group, median 190 mW, range 100 – 950 mW, and PRP group, median 800 mW, range 100 – 2000 mW. On subgroup comparison, for similar spot size, as treatment duration decreased, the power required increased, albeit in a much lesser proportion than that given by energy = power × time. Most frequently used patterns were single spot (89% of cases) in FP, 5 × 5 box (72%) in PRP, and 2 × 2 box (78%) in BP. Spot diameters as high as ≈ 700 μm on retina were given in the PRP group. Single session PRP was attempted in six eyes with a median spot count of 3500. Conclusion: Overall, due to the small duration of its pulse, the Pascal® photocoagulator tends to use higher powers, although much lower cumulative energies, than those used in a conventional laser. The consequent lesser heat dissipation, especially lateral, can allow one to use relatively larger spot sizes and give more closely spaced burns, without incurring significant side effects. PMID:21350276
NASA Astrophysics Data System (ADS)
Horikoshi, Satoshi; Abe, Hideki; Torigoe, Kanjiro; Abe, Masahiko; Serpone, Nick
2010-08-01
This article examines the effect(s) of the 2.45-GHz microwave (MW) radiation in the synthesis of silver nanoparticles in aqueous media by reduction of the diaminesilver(i) complex, [Ag(NH3)2]+, with carboxymethylcellulose (CMC) in both batch-type and continuous-flow reactor systems with a particular emphasis on the characteristics of the microwaves in this process and the size distributions. This microwave thermally-assisted synthesis is compared to a conventional heating (CH) method, both requiring a reaction temperature of 100 °C to produce the nanoparticles, in both cases leading to the formation of silver colloids with different size distributions. Reduction of the diaminesilver(i) precursor complex, [Ag(NH3)2]+, by CMC depended on the solution temperature. Cooling the reactor during the heating process driven with 390-Watt microwaves (MW-390W/Cool protocol) yielded silver nanoparticles with sizes spanning the range 1-2 nm. By contrast, the size distribution of Ag nanoparticles with 170-Watt microwaves (no cooling; MW-170W protocol) was in the range 1.4-3.6 nm (average size ~3 nm). The overall results suggest the potential for a scale-up process in the microwave-assisted synthesis of nanoparticles. Based on the present data, a flow-through microwave reactor system is herein proposed for the continuous production of silver nanoparticles. The novel flow reactor system (flow rate, 600 mL min-1) coupled to 1200-Watt microwave radiation generated silver nanoparticles with a size distribution 0.7-2.8 nm (average size ca. 1.5 nm).
NASA Astrophysics Data System (ADS)
Ichinose, Gene Aaron
The source parameters for eastern California and western Nevada earthquakes are estimated from regionally recorded seismograms using a moment tensor inversion. We use the point source approximation and fit the seismograms, at long periods. We generated a moment tensor catalog for Mw > 4.0 since 1997 and Mw > 5.0 since 1990. The catalog includes centroid depths, seismic moments, and focal mechanisms. The regions with the most moderate sized earthquakes in the last decade were in aftershock zones located in Eureka Valley, Double Spring Flat, Coso, Ridgecrest, Fish Lake Valley, and Scotty's Junction. The remaining moderate size earthquakes were distributed across the region. The 1993 (Mw 6.0) Eureka Valley earthquake occurred in the Eastern California Shear Zone. Careful aftershock relocations were used to resolve structure from aftershock clusters. The mainshock appears to rupture along the western side of the Last Change Range along a 30° to 60° west dipping fault plane, consistent with previous geodetic modeling. We estimate the source parameters for aftershocks at source-receiver distances less than 20 km using waveform modeling. The relocated aftershocks and waveform modeling results do not indicate any significant evidence of low angle faulting (dips > 30°. The results did reveal deformation along vertical faults within the hanging-wall block, consistent with observed surface rupture along the Saline Range above the dipping fault plane. The 1994 (Mw 5.8) Double Spring Flat earthquake occurred along the eastern Sierra Nevada between overlapping normal faults. Aftershock migration and cross fault triggering occurred in the following two years, producing seventeen Mw > 4 aftershocks The source parameters for the largest aftershocks were estimated from regionally recorded seismograms using moment tensor inversion. We estimate the source parameters for two moderate sized earthquakes which occurred near Reno, Nevada, the 1995 (Mw 4.4) Border Town, and the 1998 (Mw 4.7) Incline Village Earthquakes. We test to see how such stress interactions affected a cluster of six large earthquakes (Mw 6.6 to 7.5) between 1915 to 1954 within the Central Nevada Seismic Belt. We compute the static stress changes for these earthquake using dislocation models based on the location and amount of surface rupture. (Abstract shortened by UMI.)
Duarte, Regina M B O; Barros, Ana C; Duarte, Armando C
2012-08-03
For the purpose of resolving the chemical heterogeneity of natural organic matter (NOM), comprehensive two-dimensional liquid chromatography (LC×LC) was employed for the first time to map the hydrophobicity versus molecular weight (MW) distribution of two well-known complex organic mixtures: Suwannee River Fulvic Acids (SR-FA) and Pony Lake Fulvic Acids (PL-FA). Two methods have been developed using either a conventional reversed-phase (RP) silica column or a mixed-mode hydrophilic interaction column operating under aqueous RP mode in the first dimension, and a size-exclusion column in the second dimension. The LC×LC fractions were screened on-line by UV at 254 nm, molecular fluorescence at excitation/emission wavelengths (λ(Exc)/λ(Em)) of 240/450 nm, and by evaporative light scattering. The MW distributions of these two NOM samples were further characterized by number (Mn) and weight (Mw) average MW, and by polydispersity (Mw/Mn). Findings suggest that the combination of two independent separation mechanisms is promising in extend the range of NOM separation. For the cases where NOM separation was accomplished, smaller Mw group fractions seem to be related to a more hydrophobic nature. Regardless of the detection method, the complete range of MW distribution provided by both comprehensive LC×LC methods was found to be lower than those reported in the literature. Copyright © 2012 Elsevier B.V. All rights reserved.
Determination of Love- and Rayleigh-Wave Magnitudes for Earthquakes and Explosions and Other Studies
2012-12-30
the dip- slip or oblique mechanisms . Figure 30. Comparison of Mw (a) and depth (b) computed using srfgrd96 program (Herrmann, 2004...example it follows from Equations A5 and A7 that the Love wave amplitudes for the strike- slip focal mechanism are greater than those for a dip- slip ...These events ranged in size between 3.2 < Mw < 5.1 with the focal mechanisms (Herrmann, pers. comm. 2010) being predominantly strike- slip
NASA Astrophysics Data System (ADS)
Askar, Shadid; Wei, Tong; Tan, Anthony W.; Torkelson, John M.
2017-05-01
Many studies have established a major effect of nanoscale confinement on the glass transition temperature (Tg) of polystyrene (PS), most commonly in thin films with one or two free surfaces. Here, we characterize smaller yet significant intrinsic size effects (in the absence of free surfaces or significant attractive polymer-substrate interactions) on the Tg and fragility of PS. Melt infiltration of various molecular weights (MWs) of PS into anodic aluminum oxide (AAO) templates is used to create nanorods supported on AAO with rod diameter (d) ranging from 24 to 210 nm. The Tg (both as Tg,onset and fictive temperature) and fragility values are characterized by differential scanning calorimetry. No intrinsic size effect is observed for 30 kg/mol PS in template-supported nanorods with d = 24 nm. However, effects on Tg are present for PS nanorods with Mn and Mw ≥ ˜175 kg/mol, with effects increasing in magnitude with increasing MW. For example, in 24-nm-diameter template-supported nanorods, Tg, rod - Tg, bulk = -2.0 to -2.5 °C for PS with Mn = 175 kg/mol and Mw = 182 kg/mol, and Tg, rod - Tg, bulk = ˜-8 °C for PS with Mn = 929 kg/mol and Mw = 1420 kg/mol. In general, reductions in Tg occur when d ≤ ˜2Rg, where Rg is the bulk polymer radius of gyration. Thus, intrinsic size effects are significant when the rod diameter is smaller than the diameter (2Rg) associated with the spherical volume pervaded by coils in bulk. We hypothesize that the Tg reduction occurs when chain segment packing frustration is sufficiently perturbed by confinement in the nanorods. This explanation is supported by observed reductions in fragility with the increasing extent of confinement. We also explain why these small intrinsic size effects do not contradict reports that the Tg-confinement effect in supported PS films with one free surface exhibits little or no MW dependence.
Thermal Fatigue Study of W/cu Joint
NASA Astrophysics Data System (ADS)
Zhang, Fu; Wu, Jihong; Xu, Zengyu; Xu, Ying
2003-06-01
HHFC mock-ups with a structure of W/Cu/SS were developed by hot isostatic pressing (HIP). The performance of the W/Cu joint under high heat loads was tested using an electron beam. The size of specimens for heat load tests was 25×25 mm and the size of beam spot on the specimen surface was 22 mm in diameter. During heat load test, the specimens were water-cooled. Thermal fatigue test were conducted at power density of 8.7 MW/m2 with pulse duration of 20 seconds and interval of 20 seconds. After 1000 cycles of tests, no cracks and failure were found in the W/Cu joint. The thermal performance was also investigated in the range of 1 ~ 9 MW/m2.
The report gives results of measurements of nitrous oxide (N2O) emissions from coal-fired utility boilers at three electric power generating stations. Six units were tested, two at each site, including sizes ranging from 165 to 700 MW. Several manufacturers and boiler firing type...
Dynamic conversion of solar generated heat to electricity
NASA Technical Reports Server (NTRS)
Powell, J. C.; Fourakis, E.; Hammer, J. M.; Smith, G. A.; Grosskreutz, J. C.; Mcbride, E.
1974-01-01
The effort undertaken during this program led to the selection of the water-superheated steam (850 psig/900 F) crescent central receiver as the preferred concept from among 11 candidate systems across the technological spectrum of the dynamic conversion of solar generated heat to electricity. The solar power plant designs were investigated in the range of plant capacities from 100 to 1000 Mw(e). The investigations considered the impacts of plant size, collector design, feed-water temperature ratio, heat rejection equipment, ground cover, and location on solar power technical and economic feasibility. For the distributed receiver systems, the optimization studies showed that plant capacities less than 100 Mw(e) may be best. Although the size of central receiver concepts was not parametrically investigated, all indications are that the optimal plant capacity for central receiver systems will be in the range from 50 to 200 Mw(e). Solar thermal power plant site selection criteria and methodology were also established and used to evaluate potentially suitable sites. The result of this effort was to identify a site south of Inyokern, California, as typically suitable for a solar thermal power plant. The criteria used in the selection process included insolation and climatological characteristics, topography, and seismic history as well as water availability.
Oregon | Midmarket Solar Policies in the United States | Solar Research |
Utilities Commission. System size limit: PGE and PacifiCorp customers: 2 MW for non-residential, 25 kW for residential; municipal, electric cooperative, and public utility district customers: 25 kW for non-residential , >25 kW and â¤2MW, non-exporting systems â¤10 MW, and all systems. System size limit: 10 MW
Microscopic Structure of Metal Whiskers
NASA Astrophysics Data System (ADS)
Borra, Vamsi; Georgiev, Daniel G.; Karpov, V. G.; Shvydka, Diana
2018-05-01
We present TEM images of the interior of metal whiskers (MWs) grown on electroplated Sn films. Along with earlier published information, our observations focus on a number of questions, such as, why MWs' diameters are in the micron range (significantly exceeding the typical nanosizes of nuclei in solids), why the diameters remain practically unchanged in the course of MW growth, what the nature of MW diameter stochasticity is, and what the origin of the well-known striation structure of MW side surfaces is. In an attempt to address such questions, we perform an in-depth study of MW structure at the nanoscale by detaching a MW from its original film, reducing its size to a thin slice by cutting its sides by a focused ion beam, and performing TEM on that structure. Also, we examine the root of the MW and Cu-Sn interface for the intermetallic compounds. Our TEM observations reveal a rich nontrivial morphology suggesting that MWs may consist of many side-by-side grown filaments. This structure appears to extend to the outside whisker surface and be the reason for the striation. In addition, we put forward a theory where nucleation of multiple thin metal needles results in micron-scale and larger MW diameters. This theory is developed in the average field approximation similar to the roughening transitions of metal surfaces. The theory also predicts MW nucleation barriers and other observed features.
Guéguen, Céline; Cuss, Chad W
2011-07-08
Flow field-flow fractionation (FlFFF) with on-line UV/Visible diode array detector (DAD) and excitation emission matrix (EEM) fluorescence detector has been developed for the characterization of optical properties of aquatic dissolved organic matter (DOM) collected in the Otonabee River (Ontario, Canada) and Athabasca River (Alberta, Canada). The molecular weight (MW) distribution of DOM was estimated using a series of organic macromolecules ranging from 479 to 66,000 Da. Both the number-average (M(n)) and weight-average (M(w)) molecular weights of Suwannee River fulvic acid (SRFA) and Suwannee River humic acid (SRHA) determined using these macromolecular standards were comparable to those obtained using polystyrenesulfonate (PSS) standards, suggesting that organic macromolecules can be used to estimate MW of natural organic colloids. The MW of eight river DOM samples determined by this method was found to have an M(n) range of 0.8-1.1 kDa, which agrees with available literature estimates. The FlFFF-DAD-EEM system provided insight into the MW components of river DOM including the optical properties by on-line absorbance and fluorescence measurement. A red-shift in emission and excitation wavelength maxima associated with lower spectral slope ratios (S(R)=S₂₇₅₋₂₉₅:S₃₅₀₋₄₀₀) was related to higher MW DOM. However, DOM of different origins at similar MW also showed significant difference in optical properties. A difference of 47 and 40 nm in excitation and emission peak C maxima was found. This supports the hypothesis that river DOM is not uniform in size and optical composition. Copyright © 2010 Elsevier B.V. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hatayama, Ariyoshi; Ogasawara, Masatada; Yamauchi, Michinori
1994-08-01
Plasma size and other basic performance parameters for 1000-MW(electric) power production are calculated with the blanket energy multiplication factor, the M value, as a parameter. The calculational model is base don the International Thermonuclear Experimental Reactor (ITER) physics design guidelines and includes overall plant power flow. Plasma size decreases as the M value increases. However, the improvement in the plasma compactness and other basic performance parameters, such as the total plant power efficiency, becomes saturated above the M = 5 to 7 range. THus, a value in the M = 5 to 7 range is a reasonable choice for 1000-MW(electric)more » hybrids. Typical plasma parameters for 1000-MW(electric) hybrids with a value of M = 7 are a major radius of R = 5.2 m, minor radius of a = 1.7 m, plasma current of I{sub p} = 15 MA, and toroidal field on the axis of B{sub o} = 5 T. The concept of a thermal fission blanket that uses light water as a coolant is selected as an attractive candidate for electricity-producing hybrids. An optimization study is carried out for this blanket concept. The result shows that a compact, simple structure with a uniform fuel composition for the fissile region is sufficient to obtain optimal conditions for suppressing the thermal power increase caused by fuel burnup. The maximum increase in the thermal power is +3.2%. The M value estimated from the neutronics calculations is {approximately}7.0, which is confirmed to be compatible with the plasma requirement. These studies show that it is possible to use a tokamak fusion core with design requirements similar to those of ITER for a 1000-MW(electric) power reactor that uses existing thermal reactor technology for the blanket. 30 refs., 22 figs., 4 tabs.« less
Percutaneous Microwave Ablation of Renal Angiomyolipomas.
Cristescu, Mircea; Abel, E Jason; Wells, Shane; Ziemlewicz, Timothy J; Hedican, Sean P; Lubner, Megan G; Hinshaw, J Louis; Brace, Christopher L; Lee, Fred T
2016-03-01
To evaluate the safety and efficacy of US-guided percutaneous microwave (MW) ablation in the treatment of renal angiomyolipoma (AML). From January 2011 to April 2014, seven patients (5 females and 2 males; mean age 51.4) with 11 renal AMLs (9 sporadic type and 2 tuberous sclerosis associated) with a mean size of 3.4 ± 0.7 cm (range 2.4-4.9 cm) were treated with high-powered, gas-cooled percutaneous MW ablation under US guidance. Tumoral diameter, volume, and CT/MR enhancement were measured on pre-treatment, immediate post-ablation, and delayed post-ablation imaging. Clinical symptoms and creatinine were assessed on follow-up visits. All ablations were technically successful and no major complications were encountered. Mean ablation parameters were ablation power of 65 W (range 60-70 W), using 456 mL of hydrodissection fluid per patient, over 4.7 min (range 3-8 min). Immediate post-ablation imaging demonstrated mean tumor diameter and volume decreases of 1.8% (3.4-3.3 cm) and 1.7% (27.5-26.3 cm(3)), respectively. Delayed imaging follow-up obtained at a mean interval of 23.1 months (median 17.6; range 9-47) demonstrated mean tumor diameter and volume decreases of 29% (3.4-2.4 cm) and 47% (27.5-12.1 cm(3)), respectively. Tumoral enhancement decreased on immediate post-procedure and delayed imaging by CT/MR parameters, indicating decreased tumor vascularity. No patients required additional intervention and no patients experienced spontaneous bleeding post-ablation. Our early experience with high-powered, gas-cooled percutaneous MW ablation demonstrates it to be a safe and effective modality to devascularize and decrease the size of renal AMLs.
NASA Astrophysics Data System (ADS)
Gonschior, C. P.; Klein, K.-F.; Sun, T.; Grattan, K. T. V.
2012-04-01
As the demand for high power fiber-coupled violet laser systems increases existing problems remain. The typical power of commercially available diode lasers around 400 nm is in the order of 100 to 300 mW, depending on the type of laser. But in combination with the small core of single-mode fibers reduced spot sizes are needed for good coupling efficiencies, leading to power densities in the MW/cm2 range. We investigated the influence of 405 nm laser light irradiation on different fused silica fibers and differently treated end-faces. The effect of glued-and-polished, cleaved-and-clamped and of cleaved-and-fusion-arc-treated fiber end-faces on the damage rate and behavior are presented. In addition, effects in the deep ultra-violet were determined spectrally using newest spectrometer technology, allowing the measurement of color centers around 200 nm in small core fibers. Periodic surface structures were found on the proximal end-faces and were investigated concerning generation control parameters and composition. The used fiber types range from low-mode fiber to single-mode and polarization-maintaining fiber. For this investigation 405 nm single-mode or multi-mode diode lasers with 150 mW or 300 mW, respectively, were employed.
Resonant tunnelling diode terahertz sources for broadband wireless communications
NASA Astrophysics Data System (ADS)
Wasige, Edward; Alharbi, Khalid H.; Al-Khalidi, Abdullah; Wang, Jue; Khalid, Ata; Rodrigues, Gil C.; Figueiredo, José
2017-02-01
This paper will discuss resonant tunnelling diode (RTD) sources being developed on a European project iBROW (ibrow.project.eu) to enable short-range multi-gigabit wireless links and microwave-photonic interfaces for seamless links to the optical fibre backbone network. The practically relevant output powers are at least 10 mW at 90 GHz, 5 mW at 160 GHz and 1 mW at 300 GHz and simulation and some experimental results show that these are feasible in RTD technology. To date, 75 - 315 GHz indium phosphide (InP) based RTD oscillators with relatively high output powers in the 0.5 - 1.1 mW range have been demonstrated on the project. They are realised in various circuit topologies including those that use a single RTD device, 2 RTD devices and up to 4 RTD devices for increasingly higher output power. The oscillators are realised using only photolithography by taking advantage of the large micron-sized but broadband RTD devices. The paper will also describe properties of RTD devices as photo-detectors which makes this a unified technology that can be integrated into both ends of a wireless link, namely consumer portable devices and fibre-optic supported base-stations (since integration with laser diodes is also possible).
Composition and molecular weight distribution of carob germ protein fractions.
Smith, Brennan M; Bean, Scott R; Schober, Tilman J; Tilley, Michael; Herald, Thomas J; Aramouni, Fadi
2010-07-14
Biochemical properties of carob germ proteins were analyzed using a combination of selective extraction, reversed-phase high-performance liquid chromatography (RP-HPLC), size exclusion chromatography (SEC) coupled with multiangle laser light scattering (SEC-MALS), and electrophoretic analysis. Using a modified Osborne extraction procedure, carob germ flour proteins were found to contain approximately 32% albumin and globulin and approximately 68% glutelin with no prolamins detected. The albumin and globulin fraction was found to contain low amounts of disulfide-bonded polymers with relatively low M(w) ranging up to 5 x 10(6) Da. The glutelin fraction, however, was found to contain large amounts of high molecular weight disulfide-bonded polymers with M(w) up to 8 x 10(7) Da. When extracted under nonreducing conditions and divided into soluble and insoluble proteins as typically done for wheat gluten, carob germ proteins were found to be almost entirely ( approximately 95%) in the soluble fraction with only ( approximately 5%) in the insoluble fraction. As in wheat, SEC-MALS analysis showed that the insoluble proteins had a greater M(w) than the soluble proteins and ranged up to 8 x 10(7) Da. The lower M(w) distribution of the polymeric proteins of carob germ flour may account for differences in functionality between wheat and carob germ flour.
Boligon, A A; Carvalheiro, R; Ayres, D R; Albuquerque, L G
2013-02-01
Body size is directly related to the productive and reproductive performance of beef cattle raised under free-range conditions. In an attempt to better plan selection criteria, avoiding extremes in body size, this study estimated the heritabilities and genetic correlations of yearling hip height (YH) and mature hip height (MH) with selection indices obtained at weaning (WI) and yearling (YI) and mature weight (MW). Data from 102,373 Nelore animals born between 1984 and 2010, which belong to 263 farms that participate in genetic evaluation programmes of beef cattle conducted in Brazil and Paraguay, were used. The (co)variance components and genetic parameters were estimated by Bayesian inference in multi-trait analysis using an animal model. The mean heritabilities for YH, MH and MW were 0.56 ± 0.06, 0.47 ± 0.02 and 0.42 ± 0.02, respectively. The genetic correlation of YH with WI (0.13 ± 0.01) and YI (0.11 ± 0.01) was practically zero, whereas a higher correlation was observed with MW (0.22 ± 0.03). Positive genetic correlations of medium magnitude were estimated between MH and WI and YI (0.23 ± 0.01 and 0.43 ± 0.02, respectively). On the other hand, a high genetic correlation (0.68 ± 0.03) was observed between the indicator traits of mature body size (MH and MW). Considering the top 20 % of sire (896 sires) in terms of breeding values for the yearling index, the rank sire correlations between breeding values for MH and MW was 0.62. In general, the results indicate that selection based on WI and YI should not lead to important changes in YH. However, an undesired correlated response in mature cow height is expected, particularly when selection is performed using YI. Therefore, changes in the body structure of Nelore females can be obtained when MH and MW is used as a selection criterion for cows.
Construction of a Full-size Component of the ICRH System
NASA Astrophysics Data System (ADS)
Mantovani, S.; Sassi, M.; Coppi, B.
2012-10-01
The ICRH system is an important component of the Ignitor project and all efforts have been made to ensure that its design takes into account the construction experience gained in the most advanced laboratories. The system is designed to operate over a frequency range 80-120 MHz, which is consistent with the use of magnetic fields in the range 9-13 T. The maximum delivered power ranges from 8 MW (at 80 MHz) to 6 MW (at 120 MHz) distributed over 4 ports. Since the transition from a detailed design to the actual construction is not without surprises we have constructed a full size prototype of the VTL between the port flange and the antenna straps, with the external support and precise guiding system. The innovative quick latching system located at the end of the coaxial cable was successfully tested, providing perfect interference with the spring Be-Cu electrical contacts. Special care was given to the finishing of the inox surfaces, and to the TIG welds. Vacuum levels of 10-6, compatible with the limit of material degassing, and electrical tests up to 12 kV without discharges have been obtained. A revision of the other key components of the Ignitor machine has been undertaken, taking into account the experience gained in the fabrication of the corresponding prototypes.
Blade system design studies volume II : preliminary blade designs and recommended test matrix.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Griffin, Dayton A.
2004-06-01
As part of the U.S. Department of Energy's Wind Partnerships for Advanced Component Technologies (WindPACT) program, Global Energy Concepts, LLC is performing a Blade System Design Study (BSDS) concerning innovations in materials, processes and structural configurations for application to wind turbine blades in the multi-megawatt range. The BSDS Volume I project report addresses issues and constraints identified to scaling conventional blade designs to the megawatt size range, and evaluated candidate materials, manufacturing and design innovations for overcoming and improving large blade economics. The current report (Volume II), presents additional discussion of materials and manufacturing issues for large blades, including amore » summary of current trends in commercial blade manufacturing. Specifications are then developed to guide the preliminary design of MW-scale blades. Using preliminary design calculations for a 3.0 MW blade, parametric analyses are performed to quantify the potential benefits in stiffness and decreased gravity loading by replacement of a baseline fiberglass spar with carbon-fiberglass hybrid material. Complete preliminary designs are then presented for 3.0 MW and 5.0 MW blades that incorporate fiberglass-to-carbon transitions at mid-span. Based on analysis of these designs, technical issues are identified and discussed. Finally, recommendations are made for composites testing under Part I1 of the BSDS, and the initial planned test matrix for that program is presented.« less
Implications of grain size variation in magnetic field alignment of block copolymer blends
Rokhlenko, Yekaterina; Majewski, Pawel W.; Larson, Steven R.; ...
2017-03-28
Recent experiments have highlighted the intrinsic magnetic anisotropy in coil–coil diblock copolymers, specifically in poly(styrene- block-4-vinylpyridine) (PS- b-P4VP), that enables magnetic field alignment at field strengths of a few tesla. We consider here the alignment response of two low molecular weight (MW) lamallae-forming PS- b-P4VP systems. Cooling across the disorder–order transition temperature (T odt) results in strong alignment for the higher MW sample (5.5K), whereas little alignment is discernible for the lower MW system (3.6K). This disparity under otherwise identical conditions of field strength and cooling rate suggests that different average grain sizes are produced during slow cooling of thesemore » materials, with larger grains formed in the higher MW material. Blending the block copolymers results in homogeneous samples which display T odt, d-spacings, and grain sizes that are intermediate between the two neat diblocks. Similarly, the alignment quality displays a smooth variation with the concentration of the higher MW diblock in the blends, and the size of grains likewise interpolates between limits set by the neat diblocks, with a factor of 3.5× difference in the grain size observed in high vs low MW neat diblocks. Finally, these results highlight the importance of grain growth kinetics in dictating the field response in block copolymers and suggests an unconventional route for the manipulation of such kinetics.« less
Implications of grain size variation in magnetic field alignment of block copolymer blends
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rokhlenko, Yekaterina; Majewski, Pawel W.; Larson, Steven R.
Recent experiments have highlighted the intrinsic magnetic anisotropy in coil–coil diblock copolymers, specifically in poly(styrene- block-4-vinylpyridine) (PS- b-P4VP), that enables magnetic field alignment at field strengths of a few tesla. We consider here the alignment response of two low molecular weight (MW) lamallae-forming PS- b-P4VP systems. Cooling across the disorder–order transition temperature (T odt) results in strong alignment for the higher MW sample (5.5K), whereas little alignment is discernible for the lower MW system (3.6K). This disparity under otherwise identical conditions of field strength and cooling rate suggests that different average grain sizes are produced during slow cooling of thesemore » materials, with larger grains formed in the higher MW material. Blending the block copolymers results in homogeneous samples which display T odt, d-spacings, and grain sizes that are intermediate between the two neat diblocks. Similarly, the alignment quality displays a smooth variation with the concentration of the higher MW diblock in the blends, and the size of grains likewise interpolates between limits set by the neat diblocks, with a factor of 3.5× difference in the grain size observed in high vs low MW neat diblocks. Finally, these results highlight the importance of grain growth kinetics in dictating the field response in block copolymers and suggests an unconventional route for the manipulation of such kinetics.« less
Developments for the ICRH System of the Ignitor Machine
NASA Astrophysics Data System (ADS)
Sassi, M.; Mantovani, S.; Coppi, B.
2014-10-01
The ICRH system that is suitable for the high-density plasmas to be produced by the Ignitor machine has been designed and components of it have been tested. This system will operate over the range 80-120 MHz, consistently with magnetic fields in the range 9-13 T. The maximum delivered power is in the interval 8 MW (at 80 MHz) to 6 MW (at 120 MHz) distributed over 4 ports. A full size prototype of the VTL between the port flange and the antenna straps, with the external support and precise guiding system has been constructed. The innovative quick latching system located at the end of the coaxial cable has been successfully tested, providing perfect interference with the spring Be-Cu electrical contacts. Vacuum levels of 10-6, compatible with the limit of material degassing, and electrical tests up to 12 kV without discharges have been obtained. Sponsored in part by the US DOE.
Bhure, U N; Lardinois, D; Kalff, V; Hany, T F; Soltermann, A; Seifert, B; Steinert, H C
2010-10-01
Accurate determination of tumour size in lung adenocarcinoma with bronchoalveolar features (BAC) is important for the determination of TNM (tumour, nodes, metastasis) scores used in staging, prognosis and therapy response assessment. However, tumour sizes derived using lung window (LW) CT or soft-tissue/mediastinal window (MW) CT often give different results. This study examines which measurement correlates best with actual tumour size and which best identifies advanced disease. This retrospective study included 43 BAC patients who underwent surgical resection with mediastinal lymphadenectomy <4 weeks post CT scan. The largest unidimensional tumour diameter on each CT window was compared with actual histopathological tumour size (HP). LW, MW and HP size measurements and a recently described CT parameter - the modified tumour shadow disappearance rate (mTDR) = (1 - [MW/LW]) - were then used to determine which parameter best discriminated between the presence or absence of advanced disease. There was no difference between HP and LW sizes, but MW significantly underestimated HP size (p<0.0001). Unlike MW (p = 0.01) and mTDR (p = 0.001), neither HP (p = 0.14) nor LW (p = 0.10) distinguished between patients with or without advanced disease. On receiver operating characteristic (ROC) analysis at a cut-off of ≤0.13, the sensitivity and specificity of mTDR for detecting advanced disease were 69% and 89%, respectively. In patients with tumours ≤3 cm, only mTDR remained a significant predictor of advanced disease (p = 0.017), with best cut-off at ≤0.20, giving a sensitivity and specificity of 71% and 94%, respectively. MW better predicts advanced disease than LW and might also need to be recorded for RECIST (response evaluation criteria in solid tumours) assessment for T staging of BAC; however, mTDR appears to be an even better predictor and should also be used.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cristescu, Mircea, E-mail: mcristescu@uwhealth.org; Abel, E. Jason, E-mail: abel@urology.wisc.edu; Wells, Shane, E-mail: swells@uwhealth.org
PurposeTo evaluate the safety and efficacy of US-guided percutaneous microwave (MW) ablation in the treatment of renal angiomyolipoma (AML).Materials and MethodsFrom January 2011 to April 2014, seven patients (5 females and 2 males; mean age 51.4) with 11 renal AMLs (9 sporadic type and 2 tuberous sclerosis associated) with a mean size of 3.4 ± 0.7 cm (range 2.4–4.9 cm) were treated with high-powered, gas-cooled percutaneous MW ablation under US guidance. Tumoral diameter, volume, and CT/MR enhancement were measured on pre-treatment, immediate post-ablation, and delayed post-ablation imaging. Clinical symptoms and creatinine were assessed on follow-up visits.ResultsAll ablations were technically successful and no major complicationsmore » were encountered. Mean ablation parameters were ablation power of 65 W (range 60–70 W), using 456 mL of hydrodissection fluid per patient, over 4.7 min (range 3–8 min). Immediate post-ablation imaging demonstrated mean tumor diameter and volume decreases of 1.8 % (3.4–3.3 cm) and 1.7 % (27.5–26.3 cm{sup 3}), respectively. Delayed imaging follow-up obtained at a mean interval of 23.1 months (median 17.6; range 9–47) demonstrated mean tumor diameter and volume decreases of 29 % (3.4–2.4 cm) and 47 % (27.5–12.1 cm{sup 3}), respectively. Tumoral enhancement decreased on immediate post-procedure and delayed imaging by CT/MR parameters, indicating decreased tumor vascularity. No patients required additional intervention and no patients experienced spontaneous bleeding post-ablation.ConclusionOur early experience with high-powered, gas-cooled percutaneous MW ablation demonstrates it to be a safe and effective modality to devascularize and decrease the size of renal AMLs.« less
Zhou, Zhengzhen; Guo, Laodong
2015-06-19
Colloidal retention characteristics, recovery and size distribution of model macromolecules and natural dissolved organic matter (DOM) were systematically examined using an asymmetrical flow field-flow fractionation (AFlFFF) system under various membrane size cutoffs and carrier solutions. Polystyrene sulfonate (PSS) standards with known molecular weights (MW) were used to determine their permeation and recovery rates by membranes with different nominal MW cutoffs (NMWCO) within the AFlFFF system. Based on a ≥90% recovery rate for PSS standards by the AFlFFF system, the actual NMWCOs were determined to be 1.9 kDa for the 0.3 kDa membrane, 2.7 kDa for the 1 kDa membrane, and 33 kDa for the 10 kDa membrane, respectively. After membrane calibration, natural DOM samples were analyzed with the AFlFFF system to determine their colloidal size distribution and the influence from membrane NMWCOs and carrier solutions. Size partitioning of DOM samples showed a predominant colloidal size fraction in the <5 nm or <10 kDa size range, consistent with the size characteristics of humic substances as the main terrestrial DOM component. Recovery of DOM by the AFlFFF system, as determined by UV-absorbance at 254 nm, decreased significantly with increasing membrane NMWCO, from 45% by the 0.3 kDa membrane to 2-3% by the 10 kDa membrane. Since natural DOM is mostly composed of lower MW substances (<10 kDa) and the actual membrane cutoffs are normally larger than their manufacturer ratings, a 0.3 kDa membrane (with an actual NMWCO of 1.9 kDa) is highly recommended for colloidal size characterization of natural DOM. Among the three carrier solutions, borate buffer seemed to provide the highest recovery and optimal separation of DOM. Rigorous calibration with macromolecular standards and optimization of system conditions are a prerequisite for quantifying colloidal size distribution using the flow field-flow fractionation technique. In addition, the coupling of AFlFFF with fluorescence EEMs could provide new insights into DOM heterogeneity in different colloidal size fractions. Copyright © 2015 Elsevier B.V. All rights reserved.
Formulation and Characterization of Echogenic Lipid–Pluronic Nanobubbles
Krupka, Tianyi M.; Solorio, Luis; Wilson, Robin E.; Wu, Hanping; Azar, Nami; Exner, Agata A.
2012-01-01
The advent of microbubble contrast agents has enhanced the capabilities of ultrasound as a medical imaging modality and stimulated innovative strategies for ultrasound-mediated drug and gene delivery. While the utilization of microbubbles as carrier vehicles has shown encouraging results in cancer therapy, their applicability has been limited by a large size which typically confines them to the vasculature. To enhance their multifunctional contrast and delivery capacity, it is critical to reduce bubble size to the nanometer range without reducing echogenicity. In this work, we present a novel strategy for formulation of nanosized, echogenic lipid bubbles by incorporating the surfactant Pluronic, a triblock copolymer of ethylene oxide copropylene oxide coethylene oxide into the formulation. Five Pluronics (L31, L61, L81, L64 and P85) with a range of molecular weights (Mw: 1100 to 4600 Da) were incorporated into the lipid shell either before or after lipid film hydration and before addition of perfluorocarbon gas. Results demonstrate that Pluronic–lipid interactions lead to a significantly reduced bubble size. Among the tested formulations, bubbles made with Pluronic L61 were the smallest with a mean hydrodynamic diameter of 207.9 ± 74.7 nm compared to the 880.9 ± 127.6 nm control bubbles. Pluronic L81 also significantly reduced bubble size to 406.8 ± 21.0 nm. We conclude that Pluronic is effective in lipid bubble size control, and Pluronic Mw, hydrophilic–lipophilic balance (HLB), and Pluronic/ lipid ratio are critical determinants of the bubble size. Most importantly, our results have shown that although the bubbles are nanosized, their stability and in vitro and in vivo echogenicity are not compromised. The resulting nanobubbles may be better suited for contrast enhanced tumor imaging and subsequent therapeutic delivery. PMID:19957968
Hydrothermal heat discharge in the Cascade Range, northwestern United States
Ingebritsen, S.E.; Mariner, R.H.
2010-01-01
Hydrothermal heat discharge in the Cascade Range includes the heat discharged by thermal springs, by "slightly thermal" springs that are only a few degrees warmer than ambient temperature, and by fumaroles. Thermal-spring heat discharge is calculated on the basis of chloride-flux measurements and geothermometer temperatures and totals ~ 240 MW in the U.S. part of the Cascade Range, excluding the transient post-1980 discharge at Mount St. Helens (~80 MW as of 2004-5). Heat discharge from "slightly thermal" springs is based on the degree of geothermal warming (after correction for gravitational potential energy effects) and totals ~. 660. MW. Fumarolic heat discharge is calculated by a variety of indirect and direct methods and totals ~160 MW, excluding the transient mid-1970s discharge at Mount Baker (~80 MW) and transient post-1980 discharge at Mount St. Helens (>. 230. MW as of 2005). Other than the pronounced transients at Mount St. Helens and Mount Baker, hydrothermal heat discharge in the Cascade Range appears to be fairly steady over a ~25-year period of measurement. Of the total of ~. 1050. MW of "steady" hydrothermal heat discharge identified in the U.S. part of the Cascade Range, less than 50. MW occurs north of latitude 45??15' N (~0.1 MW per km arc length from 45??15' to 49??N). Much greater rates of hydrothermal heat discharge south of 45??15'N (~1.7 MW per km arc length from 40?? to 45??15'N) may reflect the influence of Basin and Range-style extensional tectonics (faulting) that impinges on the Cascades as far north as Mount Jefferson but is not evident farther north. ?? 2010.
Mecozzi, Mauro; Pietrantonio, Eva; Pietroletti, Marco
2009-01-01
In this paper the marine organic matter soluble in an alkaline medium called extractable humic substance (EHS), was extracted from three sediment samples of Tyrrhenian Sea and separated by precipitation at pH 2 in the two fractions of fulvic acids (FAs) and humic acids (HAs). FAs were further fractionated in seven sub-samples of different molecular weight (mw) by means of seven different ultrafiltration membranes operating in the range between mw<1 kDa and mw>100 kDa. Then the qualitative composition of each sample of fractionated FAs and HAs was studied by means of one-dimensional Fourier transform infrared spectroscopy in reflectance mode (FTIR-DRIFT) and by two-dimensional (2D) correlation spectroscopy both in wavelength-wavelength (WW) and in sample-sample (SS) mode. The application of 2D correlation WW spectroscopy allows to elucidate the different roles played by carbohydrates and proteins with respect to some lipid compounds such as fatty acids and ester fatty acids during the process of aggregate formations from mw approximately 1 kDa to higher size aggregates. In addition, 2D correlation WW spectroscopy allows to observe some peculiar interactions between carbohydrates and proteins in the formation of EHS aggregates, interactions which vary from a sample to another sample. The results of 2D correlation SS spectroscopy confirm the general evidences obtained by 2D WW spectroscopy and moreover, they also describe the formation of EHS aggregates as a complex process where evolutionary links and connectivity between aggregates of neighbour molecular size ranges are not evident. Two-dimensional correlation spectroscopy applied to FTIR spectroscopy shows to be a powerful tool for the investigation of the mechanisms involved in EHS aggregation because it supports the acquisition of structural information which sometimes can be hardly obtained by one-dimensional FTIR spectroscopy.
Li, Fusheng; Yuasa, Akira; Muraki, Yuzo; Matsui, Yoshihiko
2005-06-01
The impacts of a heavy storm of rain upon the dissolved and particulate organic matter (OM), nitrogen (N) and phosphorus (P) in the main river of the vegetation-rich Nagara River basin were investigated using water samples collected along the river line during a critical typhoon-induced heavy rain storm event. Besides, based on a high performance size-exclusion chromatography (HPSEC) system, the variance of dissolved OM (DOM) in its molecular weight (MW) characteristics was also assessed. From the MW standpoint, DOM components merged into the river along the river line resembled those present in its headwater. The MW range changed only slightly from 1010 to 5900 at the upstream (US), to 1130-5900 and 1200-5900 Da at the midstream (MS) and downstream (DS), respectively, while the corresponding weight-averaged MW (M(w)) decreased from 3669 to 3330 and 2962 Da. The heavy storm of rain enhanced the content of DOM; however, apart from a small larger-MW fraction (about 5900-6800 Da), the newly emerged DOM constituents exhibited an MW range similar to those existed before the storm. Due also to the storm of rain, total P and N (TP and TN) changed markedly in the ranges of 6.6-11.9, 8.3-40.6 and 48.4-231.3 microg/l for TP, and 145.4-296.0, 502.2-1168.7 and 1342.7-1927.3 microg/l for TN at the US, MS and DS, respectively. The larger values of TP and TN generally appeared for samples at elevated river water levels. The enhanced presence of P was found largely attributed to its particulate form; while, for N, the contribution from its dissolved form was significant. The newly emerged suspended particles via the storm-water contained lower content of OM, N and P, and a general decreasing trend of the particulate OM, N and P along the river line was also confirmed. The C/N ratio in the dissolved form varied in 0.7-6.7 and decreased downstream, while, that in the particulate form 2.3-17.3. Suspended particles that emerged in the river water during the storm exhibited larger C/N values. N/P in both dissolved and particulate forms varied in the ranges of 2.2-17.1 and 12.9-444.9, respectively, and a general trend of either increasing or decreasing in relation to the storm of rain was not revealed.
A UHF RFID system with on-chip-antenna tag for short range communication
NASA Astrophysics Data System (ADS)
Qi, Peng; Chun, Zhang; Xijin, Zhao; Zhihua, Wang
2015-05-01
A UHF RF identification system based on the 0.18 μm CMOS process has been developed for short range and harsh size requirement applications, which is composed of a fully integrated tag and a special reader. The whole tag chip with the antenna takes up an area of 0.36 mm2, which is smaller than other reported tags with an on-chip antenna (OCA) using the standard CMOS process. A self-defined protocol is proposed to reduce the power consumption, and minimize the size of the tag. The specialized SOC reader system consists of the RF transceiver, digital baseband, MCU and host interface. Its power consumption is about 500 mW. Measurement results show that the system's reading range is 2 mm with 20 dBm reader output power. With an inductive antenna printed on a paper substrate around the OCA tag, the reading range can be extended from several centimeters to meters, depending on the shape and size of the inductive antenna.
Chaturvedi, Shalini; Siegel, Derick; Wagner, Carrie L; Park, Jaehong; van de Velde, Helgi; Vermeulen, Jessica; Fung, Man-Cheong; Reddy, Manjula; Hall, Brett; Sasser, Kate
2015-01-01
Aim Interleukin-6 (IL-6), a multifunctional cytokine, exists in several forms ranging from a low molecular weight (MW 20–30 kDa) non-complexed form to high MW (200–450 kDa), complexes. Accurate baseline IL-6 assessment is pivotal to understand clinical responses to IL-6-targeted treatments. Existing assays measure only the low MW, non-complexed IL-6 form. The present work aimed to develop a validated assay to measure accurately total IL-6 (complexed and non-complexed) in serum or plasma as matrix in a high throughput and easily standardized format for clinical testing. Methods Commercial capture and detection antibodies were screened against humanized IL-6 and evaluated in an enzyme-linked immunosorbent assay format. The best antibody combinations were screened to identify an antibody pair that gave minimum background and maximum recovery of IL-6 in the presence of 100% serum matrix. A plate-based total IL-6 assay was developed and transferred to the Meso Scale Discovery (MSD) platform for large scale clinical testing. Results The top-performing antibody pair from 36 capture and four detection candidates was validated on the MSD platform. The lower limit of quantification in human serum samples (n = 6) was 9.77 pg l–1, recovery ranged from 93.13–113.27%, the overall pooled coefficients of variation were 20.12% (inter-assay) and 8.67% (intra-assay). High MW forms of IL-6, in size fractionated serum samples from myelodysplastic syndrome and rheumatoid arthritis patients, were detected by the assay but not by a commercial kit. Conclusion This novel panoptic (sees all forms) IL-6 MSD assay that measures both high and low MW forms may have clinical utility. PMID:25847183
Size-dependent interaction of silica nanoparticles with lysozyme and bovine serum albumin proteins
NASA Astrophysics Data System (ADS)
Yadav, Indresh; Aswal, Vinod K.; Kohlbrecher, Joachim
2016-05-01
The interaction of three different sized (diameter 10, 18, and 28 nm) anionic silica nanoparticles with two model proteins—cationic lysozyme [molecular weight (MW) 14.7 kDa)] and anionic bovine serum albumin (BSA) (MW 66.4 kDa) has been studied by UV-vis spectroscopy, dynamic light scattering (DLS), and small-angle neutron scattering (SANS). The adsorption behavior of proteins on the nanoparticles, measured by UV-vis spectroscopy, is found to be very different for lysozyme and BSA. Lysozyme adsorbs strongly on the nanoparticles and shows exponential behavior as a function of lysozyme concentration irrespective of the nanoparticle size. The total amount of adsorbed lysozyme, as governed by the surface-to-volume ratio, increases on lowering the size of the nanoparticles for a fixed volume fraction of the nanoparticles. On the other hand, BSA does not show any adsorption for all the different sizes of the nanoparticles. Despite having different interactions, both proteins induce similar phase behavior where the nanoparticle-protein system transforms from one phase (clear) to two phase (turbid) as a function of protein concentration. The phase behavior is modified towards the lower concentrations for both proteins with increasing the nanoparticle size. DLS suggests that the phase behavior arises as a result of the nanoparticles' aggregation on the addition of proteins. The size-dependent modifications in the interaction potential, responsible for the phase behavior, have been determined by SANS data as modeled using the two-Yukawa potential accounting for the repulsive and attractive interactions in the systems. The protein-induced interaction between the nanoparticles is found to be short-range attraction for lysozyme and long-range attraction for BSA. The magnitude of attractive interaction irrespective of protein type is enhanced with increase in the size of the nanoparticles. The total (attractive+repulsive) potential leading to two-phase formation is found to be more attractive for larger sized nanoparticles. The nanoparticle aggregates are characterized by mass fractal.
Impact of Low Molecular Weight Poly(3-hexylthiophene)s as Additives in Organic Photovoltaic Devices.
Seibers, Zach D; Le, Thinh P; Lee, Youngmin; Gomez, Enrique D; Kilbey, S Michael
2018-01-24
Despite tremendous progress in using additives to enhance the power conversion efficiency of organic photovoltaic devices, significant challenges remain in controlling the microstructure of the active layer, such as at internal donor-acceptor interfaces. Here, we demonstrate that the addition of low molecular weight poly(3-hexylthiophene)s (low-MW P3HT) to the P3HT/fullerene active layer increases device performance up to 36% over an unmodified control device. Low MW P3HT chains ranging in size from 1.6 to 8.0 kg/mol are blended with 77.5 kg/mol P3HT chains and [6,6]-phenyl C 61 butyric acid methyl ester (PCBM) fullerenes while keeping P3HT/PCBM ratio constant. Optimal photovoltaic device performance increases are obtained for each additive when incorporated into the bulk heterojunction blend at loading levels that are dependent upon additive MW. Small-angle X-ray scattering and energy-filtered transmission electron microscopy imaging reveal that domain sizes are approximately invariant at low loading levels of the low-MW P3HT additive, and wide-angle X-ray scattering suggests that P3HT crystallinity is unaffected by these additives. These results suggest that oligomeric P3HTs compatibilize donor-acceptor interfaces at low loading levels but coarsen domain structures at higher loading levels and they are consistent with recent simulations results. Although results are specific to the P3HT/PCBM system, the notion that low molecular weight additives can enhance photovoltaic device performance generally provides a new opportunity for improving device performance and operating lifetimes.
2012 Market Report on U.S. Wind Technologies in Distributed Applications
DOE Office of Scientific and Technical Information (OSTI.GOV)
Orrell, Alice C.; Flowers, L. T.; Gagne, M. N.
2013-08-06
At the end of 2012, U.S. wind turbines in distributed applications reached a 10-year cumulative installed capacity of more than 812 MW from more than 69,000 units across all 50 states. In 2012 alone, nearly 3,800 wind turbines totaling 175 MW of distributed wind capacity were documented in 40 states and in the U.S. Virgin Islands, with 138 MW using utility-scale turbines (i.e., greater than 1 MW in size), 19 MW using mid-size turbines (i.e., 101 kW to 1 MW in size), and 18.4 MW using small turbines (i.e., up to 100 kW in size). Distributed wind is defined inmore » terms of technology application based on a wind project’s location relative to end-use and power-distribution infrastructure, rather than on technology size or project size. Distributed wind systems are either connected on the customer side of the meter (to meet the onsite load) or directly to distribution or micro grids (to support grid operations or offset large loads nearby). Estimated capacity-weighted average costs for 2012 U.S. distributed wind installations was $2,540/kW for utility-scale wind turbines, $2,810/kW for mid-sized wind turbines, and $6,960/kW for newly manufactured (domestic and imported) small wind turbines. An emerging trend observed in 2012 was an increased use of refurbished turbines. The estimated capacity-weighted average cost of refurbished small wind turbines installed in 2012 was $4,080/kW. As a result of multiple projects using utility-scale turbines, Iowa deployed the most new overall distributed wind capacity, 37 MW, in 2012. Nevada deployed the most small wind capacity in 2012, with nearly 8 MW of small wind turbines installed in distributed applications. In the case of mid-size turbines, Ohio led all states in 2012 with 4.9 MW installed in distributed applications. State and federal policies and incentives continued to play a substantial role in the development of distributed wind projects. In 2012, U.S. Treasury Section 1603 payments and grants and loans from the U.S. Department of Agriculture’s Rural Energy for America Program were the main sources of federal funding for distributed wind projects. State and local funding varied across the country, from rebates to loans, tax credits, and other incentives. Reducing utility bills and hedging against potentially rising electricity rates remain drivers of distributed wind installations. In 2012, other drivers included taking advantage of the expiring U.S. Treasury Section 1603 program and a prosperous year for farmers. While 2012 saw a large addition of distributed wind capacity, considerable barriers and challenges remain, such as a weak domestic economy, inconsistent state incentives, and very competitive solar photovoltaic and natural gas prices. The industry remains committed to improving the distributed wind marketplace by advancing the third-party certification process and introducing alternative financing models, such as third-party power purchase agreements and lease-to-own agreements more typical in the solar photovoltaic market. Continued growth is expected in 2013.« less
Chan, W I; Liao, P H; Lo, K V
2010-11-01
Using the microwave-enhanced advanced oxidation process (MW/H2O2-AOP), the pH and irradiation intensity on waste activated sludge samples were investigated to provide insight to the athermal effects on nutrients release, solids destruction, particle size distribution and dewaterability, and to demonstrate their interrelationships. Carbonaceous matters and nutrients released into solution depended on the irradiation intensity and time. Higher irradiation levels tended to be more effective in the solubilization of nutrients and had more pronounced effects in the dewaterability of sludge. In terms of particle size distribution, detectable particles increased in size for treatments in acidic conditions, while the dewaterability of treated sludge was improved. In treatments under neutral and alkaline conditions, the particle size range increased, with more small particles formed, thereby significantly deteriorating the dewaterability of sludge treated in alkaline conditions. The best results for the solubilization of nutrients were in alkaline conditions with high irradiation power, but dewaterability of the sludge was compromised. Sludge treatment with the MW/H2O2-AOP in acidic conditions with high irradiation power yielded the best dewaterable sludge and significant nutrient solubilization; therefore, it is the recommended treatment condition for activated sludge.
Wang, Ruijun; Sprengel, Stephan; Boehm, Gerhard; Muneeb, Muhammad; Baets, Roel; Amann, Markus-Christian; Roelkens, Gunther
2016-09-05
Heterogeneously integrated InP-based type-II quantum well Fabry-Perot lasers on a silicon waveguide circuit emitting in the 2.3 µm wavelength range are demonstrated. The devices consist of a "W"-shaped InGaAs/GaAsSb multi-quantum-well gain section, III-V/silicon spot size converters and two silicon Bragg grating reflectors to form the laser cavity. In continuous-wave (CW) operation, we obtain a threshold current density of 2.7 kA/cm2 and output power of 1.3 mW at 5 °C for 2.35 μm lasers. The lasers emit over 3.7 mW of peak power with a threshold current density of 1.6 kA/cm2 in pulsed regime at room temperature. This demonstration of heterogeneously integrated lasers indicates that the material system and heterogeneous integration method are promising to realize fully integrated III-V/silicon photonics spectroscopic sensors in the 2 µm wavelength range.
Parliman, D.J.
2000-01-01
In February and March 2000, the U.S. Geological Survey Western Regional Research Drilling Operation constructed replacement monitoring wells MW 3–2, MW 6–2, MW 7–2, and MW 11–2 as part of a regional ground-water monitor- ing network for the Mountain Home Air Force Base, Elmore County, Idaho. Total well depths ranged from 435.5 to 456.5 feet, and initial depth-to-water measurements ranged from about 350 to 375 feet below land surface. After completion, wells were pumped and onsite measurements were made of water temperature, specific conductance, pH, and dissolved oxygen. At each well, natural gamma, spontaneous potential, resistivity, caliper, and temperature logs were obtained from instruments placed in open boreholes. A three- dimensional borehole flow analysis was completed for MW 3–2 and MW 11–2, and a video log was obtained for MW 11–2 to annotate lithology and note wet zones in the borehole above saturated rock.
Lightweight MgB2 superconducting 10 MW wind generator
NASA Astrophysics Data System (ADS)
Marino, I.; Pujana, A.; Sarmiento, G.; Sanz, S.; Merino, J. M.; Tropeano, M.; Sun, J.; Canosa, T.
2016-02-01
The offshore wind market demands a higher power rate and more reliable turbines in order to optimize capital and operational costs. The state-of-the-art shows that both geared and direct-drive conventional generators are difficult to scale up to 10 MW and beyond due to their huge size and weight. Superconducting direct-drive wind generators are considered a promising solution to achieve lighter weight machines. This work presents an innovative 10 MW 8.1 rpm direct-drive partial superconducting generator using MgB2 wire for the field coils. It has a warm iron rotor configuration with the superconducting coils working at 20 K while the rotor core and the armature are at ambient temperature. A cooling system based on cryocoolers installed in the rotor extracts the heat from the superconducting coils by conduction. The generator's main parameters are compared against a permanent magnet reference machine, showing a significant weight and size reduction. The 10 MW superconducting generator concept will be experimentally validated with a small-scale magnetic machine, which has innovative components such as superconducting coils, modular cryostats and cooling systems, and will have similar size and characteristics as the 10 MW generator.
NASA Astrophysics Data System (ADS)
Lehtimäki, Esa; Väisänen, Ari
2017-01-01
The digestion methods for the determination of As, Cd, Cr, Pb, Sb, Sn and Zn concentrations in plastic samples using microwave-assisted digestion (MW-AD) and small-size autoclave digestion was developed. The certified polyethylene, polypropylene, polyvinyl chloride and acrylonitrile butadiene styrene certified reference materials were used in order to find digestion method working properly for several sample matrices. Efficiency of the digestion methods was evaluated by analyzing the residual carbon in digests by TOC analyzer. MW-AD using a mixture of 7 mL of HNO3 and 3 mL of H2O2 as a digestion solution resulted in excellent recoveries for As, Cd, Pb, Sb and Zn, and were in the range of 92-107% for all the analytes except Pb in polyethylene material. Autoclave digestion using 5 mL of concentrated HNO3 as a digestion solution resulted in similar recoveries with the exception of a higher As recovery (98%). Tin recovery resulted in low level after both MW-AD and autoclave digestion. Autoclave digestion was further developed resulting in a partially open two-step digestion process especially for the determination of Sn and Cr. The method resulted in higher recoveries of Sn and Cr (87 and 76%) but with the lower concentration of easily volatile As, Cd and Sb.
NASA Astrophysics Data System (ADS)
Uchide, Takahiko; Imanishi, Kazutoshi
2018-01-01
Magnitude scales based on the amplitude of seismic waves, including the Japan Meteorological Agency magnitude scale (Mj), are commonly used in routine processes. The moment magnitude scale (Mw), however, is more physics based and is able to evaluate any type and size of earthquake. This paper addresses the relation between Mj and Mw for microearthquakes. The relative moment magnitudes among earthquakes are well constrained by multiple spectral ratio analyses. The results for the events in the Fukushima Hamadori and northern Ibaraki prefecture areas of Japan imply that Mj is significantly and systematically smaller than Mw for microearthquakes. The Mj-Mw curve has slopes of 1/2 and 1 for small and large values of Mj, respectively; for example, Mj = 1.0 corresponds to Mw = 2.0. A simple numerical simulation implies that this is due to anelastic attenuation and the recording using a finite sampling interval. The underestimation affects earthquake statistics. The completeness magnitude, Mc, for magnitudes lower than which the magnitude-frequency distribution deviates from the Gutenberg-Richter law, is effectively lower for Mw than that for Mj, by taking into account the systematic difference between Mj and Mw. The b values of the Gutenberg-Richter law are larger for Mw than for Mj. As the b values for Mj and Mw are well correlated, qualitative argument using b values is not affected. While the estimated b values for Mj are below 1.5, those for Mw often exceed 1.5. This may affect the physical implication of the seismicity.
Armenia-To Trans-Boundary Fault: AN Example of International Cooperation in the Caucasus
NASA Astrophysics Data System (ADS)
Karakhanyan, A.; Avagyan, A.; Avanesyan, M.; Elashvili, M.; Godoladze, T.; Javakishvili, Z.; Korzhenkov, A.; Philip, S.; Vergino, E. S.
2012-12-01
Studies of a trans-boundary active fault that cuts through the border of Armenia to Georgia in the area of the Javakheti volcanic highland have been conducted since 2007. The studies have been implemented based on the ISTC 1418 and NATO SfP 983284 Projects. The Javakheti Fault is oriented to the north-northwest and consists of individual segments displaying clear left-stepping trend. Fault mechanism is represented by right-lateral strike-slip with normal-fault component. The fault formed distinct scarps, deforming young volcanic and glacial sediments. The maximum-size displacements are recorded in the central part of the fault and range up to 150-200 m by normal fault and 700-900 m by right-lateral strike-slip fault. On both flanks, fault scarps have younger appearance, and displacement size there decreases to tens of meters. Fault length is 80 km, suggesting that maximum fault magnitude is estimated at 7.3 according to the Wells and Coppersmith (1994) relation. Many minor earthquakes and a few stronger events (1088, Mw=6.4, 1899 Mw=6.4, 1912, Mw=6.4 and 1925, Mw=5.6) are associated with the fault. In 2011/2012, we conducted paleoseismological and archeoseismological studies of the fault. By two paleoseismological trenches were excavated in the central part of the fault, and on its northern and southern flanks. The trenches enabled recording at least three strong ancient earthquakes. Presently, results of radiocarbon age estimations of those events are expected. The Javakheti Fault may pose considerable seismic hazard for trans-boundary areas of Armenia and Georgia as its northern flank is located at the distance of 15 km from the Baku-Ceyhan pipeline.
Clearance kinetics and tissue distribution of aggregated human serum IgA in rats.
Bogers, W M; Gorter, A; Stuurman, M E; Van Es, L A; Daha, M R
1989-01-01
In the present study the clearance kinetics and tissue distribution of human polyclonal heat-aggregated serum IgA (AIgA) of different sizes in rats was studied after intravenous administration of 125I-AIgA. The 125I-AIgA of different sizes disappeared from the circulation in a biphasic manner with an initial rapid half-life (T1/2) and a second slower T1/2. The first T1/2 was related to the size of the 125I-AIgA: high molecular weight (MW) 125I-AIgA was cleared much faster than 125I-AIgA with a low MW. Relatively more degradation products were observed in blood when high MW 125I-AIgA were injected as compared to low MW 125I-AIgA. The AIgA were mainly taken up by the liver. Eight minutes after injection of high MW 125I-AIgA, 90% of the injected dose was found in the liver, whereas less than 2% was detected in the spleen. Very little activity was detectable in other organs, such as lungs, heart and kidneys. In the present study 1-3% of the injected 125I-AIgA were found in the bile. Analysis of this material revealed that low MW 125I-AIgA were transported more efficiently to the bile than high MW 125I-AIgA. To obtain more insight into the receptors involved in the clearance of 125I-AIgA, rats were pretreated with ovalbumin or asialofetuin. The clearance of 125I-AIgA of different sizes was inhibited when rats were pretreated with asialofetuin. Pretreatment with ovalbumin had no effect on the clearance rates of 125I-AIgA. These results suggest a role for carbohydrate receptors, which recognize glycoprotein-containing galactose terminal residues on Kupffer cells, in the clearance of 125I-AIgA. PMID:2473956
Low-frequency noise from large wind turbines.
Møller, Henrik; Pedersen, Christian Sejer
2011-06-01
As wind turbines get larger, worries have emerged that the turbine noise would move down in frequency and that the low-frequency noise would cause annoyance for the neighbors. The noise emission from 48 wind turbines with nominal electric power up to 3.6 MW is analyzed and discussed. The relative amount of low-frequency noise is higher for large turbines (2.3-3.6 MW) than for small turbines (≤ 2 MW), and the difference is statistically significant. The difference can also be expressed as a downward shift of the spectrum of approximately one-third of an octave. A further shift of similar size is suggested for future turbines in the 10-MW range. Due to the air absorption, the higher low-frequency content becomes even more pronounced, when sound pressure levels in relevant neighbor distances are considered. Even when A-weighted levels are considered, a substantial part of the noise is at low frequencies, and for several of the investigated large turbines, the one-third-octave band with the highest level is at or below 250 Hz. It is thus beyond any doubt that the low-frequency part of the spectrum plays an important role in the noise at the neighbors. © 2011 Acoustical Society of America
Molecular weight profiles of proanthocyanidin polymers
Vincent M. Williams; Lawrence J. Porter; Richard W. Hemingway
1983-01-01
The MW profiles of proanthocyanidin polymers (condensed tannins) from 32 samples representing a wide range of plant tissues of many different species have been obtained by gel permeation chromatography of the peracetate derivatives. The tannins vary widely in MW, with M values for the peracetates in the range 1600-5500. The MW profiles vary greatly from those with...
Generation of 320 mW at 10.20 μm based on CdSe long-wave infrared crystal
NASA Astrophysics Data System (ADS)
Wang, Jian; Yuan, Ligang; Zhang, Yingwu; Chen, Guo; Cheng, Hongjuan; Gao, Yanzhao
2018-06-01
CdSe single crystal, with the sizes of ∼54 mm in diameter and ∼25 mm in length, was grown by a high pressure vertical gradient freeze (HPVGF) technique using (0 0 1)-oriented seed. The CdSe crystal was characterized with transmission spectrophotometer. The transmission spectra showed that the infrared transmission was above 68% and the mean absorption coefficient was 0.041 cm-1 in the range of 2.5-20 μm. Using fabricated CdSe crystal with the dimensions of 6 mm × 10 mm × 44 mm, we demonstrated an optical parametric oscillator (OPO) pumped by a 2.05 μm Ho:YLF laser at a pulse repetition frequency of 5 kHz. Up to 320 mW output was obtained at the idler wavelength of 10.20 μm with a pump power of 18.06 W. 320 mW at 10.20 μm, to our knowledge, was the highest power obtained with a 2.05 μm laser-pumped CdSe OPO.
Towards spatially constrained gust models
NASA Astrophysics Data System (ADS)
Bos, René; Bierbooms, Wim; van Bussel, Gerard
2014-06-01
With the trend of moving towards 10-20 MW turbines, rotor diameters are growing beyond the size of the largest turbulent structures in the atmospheric boundary layer. As a consequence, the fully uniform transients that are commonly used to predict extreme gust loads are losing their connection to reality and may lead to gross overdimensioning. More suiting would be to represent gusts by advecting air parcels and posing certain physical constraints on size and position. However, this would introduce several new degrees of freedom that significantly increase the computational burden of extreme load prediction. In an attempt to elaborate on the costs and benefits of such an approach, load calculations were done on the DTU 10 MW reference turbine where a single uniform gust shape was given various spatial dimensions with the transverse wavelength ranging up to twice the rotor diameter (357 m). The resulting loads displayed a very high spread, but remained well under the level of a uniform gust. Moving towards spatially constrained gust models would therefore yield far less conservative, though more realistic predictions at the cost of higher computation time.
Knoth de Zarruk, K; Scholer, G; Dudal, Y
2007-09-01
Land spreading of organic materials introduces large amounts of dissolved organic matter (DOM) into the soil. DOM has the ability to form stable complexes with heavy metals and can facilitate their transport towards the groundwater. The effects on soil processes are difficult to assess, because different DOM components might react differently towards metal ions. The objective of this study was to investigate the fluorescence signature and the Cu2+-binding capacity of individual molecular size fractions of DOM from various sources. DOM extracted from leaf compost, chicken manure, sugar cane vinasse and a fulvic hypercalcaric cambisol was fractionated by the means of dialysis into four molecular size classes: MW<500, 500
Zhang, Xiangru; Minear, Roger A
2006-03-01
High-molecular weight (MW) halogenated disinfection byproducts (DBPs) may cause adverse health effects. In this work several issues related to the better separation and characterization of the high MW halogenated DBPs (MW>500Da) were studied. Ultra-filtration (UF) coupled with a nominal 500-Da membrane was employed to flush out low MW DBPs and inorganic ions. Two procedures, intermittent UF and continuous UF, were used and compared. The results demonstrate that haloacetic acids, chloride and sodium ions could be effectively flushed out, and most of phosphate ions could be flushed out for a given dilution number or sufficient Milli-Q water. The size exclusion chromatograms indicate that haloacetic acids and trihalomethanes were not bound to Suwannee River fulvic acid (SRFA); 2,4,6-trichlorophenol might form some binding with SRFA, but it appeared to be very weak and readily broken up when passing along the size exclusion column. The octanol-water partition coefficients of low MW DBPs and the properties of humic substances seem to play key roles in determining the formation of possible bindings between low MW DBPs and humic substances.
The Direct FuelCell™ stack engineering
NASA Astrophysics Data System (ADS)
Doyon, J.; Farooque, M.; Maru, H.
FuelCell Energy (FCE) has developed power plants in the size range of 300 kW to 3 MW for distributed power generation. Field-testing of the sub-megawatt plants is underway. The FCE power plants are based on its Direct FuelCell™ (DFC) technology. This is so named because of its ability to generate electricity directly from a hydrocarbon fuel, such as natural gas, by reforming it inside the fuel cell stack itself. All FCE products use identical 8000 cm 2 cell design, approximately 350-400 cells per stack, external gas manifolds, and similar stack compression systems. The difference lies in the packaging of the stacks inside the stack module. The sub-megawatt system stack module contains a single horizontal stack whereas the MW-class stack module houses four identical vertical stacks. The commonality of the design, internal reforming features, and atmospheric operation simplify the system design, reduce cost, improve efficiency, increase reliability and maintainability. The product building-block stack design has been advanced through three full-size stack operations at company's headquarters in Danbury, CT. The initial proof-of-concept of the full-size stack design was verified in 1999, followed by a 1.5 year of endurance verification in 2000-2001, and currently a value-engineered stack version is in operation. This paper discusses the design features, important engineering solutions implemented, and test results of FCE's full-size DFC stacks.
NASA Astrophysics Data System (ADS)
Heidarzadeh, Mohammad; Harada, Tomoya; Satake, Kenji; Ishibe, Takeo; Takagawa, Tomohiro
2017-12-01
The Wharton Basin, off southwest Sumatra, ruptured to a large intraplate left-lateral strike-slip Mw 7.8 earthquake on 2016 March 2. The epicentre was located ∼800 km to the south of another similar-mechanism intraplate Mw 8.6 earthquake in the same basin on 2012 April 11. Small tsunamis from these strike-slip earthquakes were registered with maximum amplitudes of 0.5-1.5 cm on DARTs and 1-19 cm on tide gauges for the 2016 event, and the respective values of 0.5-6 and 6-40 cm for the 2012 event. By using both teleseismic body waves and tsunami observations of the 2016 event, we obtained optimum slip models with rupture velocity (Vr) in the range of 2.8-3.6 km s-1 belonging to both EW and NS faults. While the EW fault plane cannot be fully ruled out, we chose the best model as the NS fault plane with a Vr of 3.6 km s-1, a maximum slip of 7.7 m and source duration of 33 s. The tsunami energy period bands were 4-15 and 7-24 min for the 2016 and 2012 tsunamis, respectively, reflecting the difference in source sizes. Seismicity in the Wharton Basin is dominated by large strike-slip events including the 2012 (Mw 8.6 and 8.2) and 2016 (Mw 7.8) events, indicating that these events are possible tsunami sources in the Wharton Basin. Cumulative number and cumulative seismic-moment curves revealed that most earthquakes are of strike-slip mechanisms and the largest seismic-moment is provided by the strike-slip earthquakes in this basin.
Earthquake Records of North Anatolian Fault from Sapanca Lake Sediments, NW Anatolia
NASA Astrophysics Data System (ADS)
Yalamaz, Burak; Cagatay, Namık; Acar, Dursun; Demirbag, Emin; Gungor, Emin; Gungor, Nurdan; Gulen, Levent
2014-05-01
We determined earthquake records in sediment cores of Sapanca Lake which is a pull-apart basin located along the North Anatolian Fault zone in NW Anatolia. The lake has a maximum depth of 55 m, and a surface area of 46.8 km2, measuring 16 km in E-W and 5 km in N-S directions. A systematic study of the sedimentological, physical and geochemical properties of three water-sediment interface cores, up to 75.7 cm long, located along depth transects ranging from 43 to 51.5 m water depths. The cores were analyzed using Geotek Multi Sensor Core Logger (MSCL) for physical properties, laser particle size analyzer for granulometry, TOC Analyzer for Total Organic Content (TOC) and Total Inorganic Carbon (TIC) analysis, Itrax-XRF Core Scanner for elemental analysis and digital X-RAY Radiography. The geochronology was determined using AMS radiocarbon and radionuclide methods. The Sapanca Lake earthquake records are characterized by mass flow units consisting of grey or dark grey coarse to fine sand and silty mud with sharp basal and transional upper boundaries. The units commonly show normal size grading with their basal parts showing high density, and high magnetic susceptibility and enrichment in one or more elements, such as Si, Ca, Tİ, K, Rb, Zr and Fe, indicative of coarse detrial input. Based on radionuclide and radiocarbon analyses the mass flow units are correlated with 1999 İzmit and Düzce earthquakes (Mw=7.4 and 7.2, respectively) , 1967 Mudurnu earthquake (Mw= 6,8), and 1957 Abant (Mw= 7.1) earthquake. Keywords: Sapanca Lake, North Anatolian Fault, Earthquake, Grain size, Itrax-XRF, MSCL
Tidal Power Exploitation in Korea
NASA Astrophysics Data System (ADS)
Choi, Byung Ho; Kim, Kyeong Ok; Choi, Jae Cheon
The highest tides in South Korea are found along the northwest coast between latitudes 36-38 degrees and the number of possible sites for tidal range power barrages to create tidal basins is great due to irregular coastlines with numerous bays. At present Lake Sihwa tidal power plant is completed. The plant is consisted of 10 bulb type turbines with 8 sluice gates. The installed capacity of turbines and generators is 254MW and annual energy output expected is about 552.7 GWh taking flood flow generation scheme. Three other TPP projects are being progressed at Garolim Bay (20 turbines with 25.4MW capacity), Kangwha (28 turbines with 25.4MW capacity), Incheon (44 or 48 turbines with 30 MW capacity) and project features will be outlined here. The introduction of tidal barrages into four major TPP projects along the Kyeonggi bay will render wide range of potential impacts. Preliminary attempts were performed to quantify these impacts using 2 D hydrodynamic model demonstrating the changes in tidal amplitude and phase under mean tidal condition, associated changes in residual circulation (indicator for SPM and pollutant dispersion), bottom stress (indicator for bedload movement), and tidal front (positional indicator for bio-productivity) in both shelf scale and local context. Tidal regime modeling system for ocean tides in the seas bordering the Korean Peninsula is designed to cover an area that is broad in scope and size, yet provide a high degree of resolution in strong tidal current region including off southwestern tip of the Peninsula (Uldolmok , Jangjuk, Wando-Hoenggan), Daebang Sudo (Channel) and Kyeonggi Bay. With this simulation system, real tidal time simulation of extended springneap cycles was performed to estimate spatial distribution of tidal current power potentials in terms of power density, energy density and then extrapolated annual energy density.
Venkatesan, Arjun K; Gan, Wenhui; Ashani, Harsh; Herckes, Pierre; Westerhoff, Paul
2018-04-15
Phosphorus (P) is an important and often limiting element in terrestrial and aquatic ecosystem. A lack of understanding of its distribution and structures in the environment limits the design of effective P mitigation and recovery approaches. Here we developed a robust method employing size exclusion chromatography (SEC) coupled to an ICP-MS to determine the molecular weight (MW) distribution of P in environmental samples. The most abundant fraction of P varied widely in different environmental samples: (i) orthophosphate was the dominant fraction (93-100%) in one lake, two aerosols and DOC isolate samples, (ii) species of 400-600 Da range were abundant (74-100%) in two surface waters, and (iii) species of 150-350 Da range were abundant in wastewater effluents. SEC-DOC of the aqueous samples using a similar SEC column showed overlapping peaks for the 400-600 Da species in two surface waters, and for >20 kDa species in the effluents, suggesting that these fractions are likely associated with organic matter. The MW resolution and performance of SEC-ICP-MS agreed well with the time integrated results obtained using conventional ultrafiltration method. Results show that SEC in combination with ICP-MS and DOC has the potential to be a powerful and easy-to-use method in identifying unknown fractions of P in the environment. Copyright © 2018 Elsevier Ltd. All rights reserved.
Infrared/microwave (IR/MW) micromirror array beam combiner design and analysis.
Tian, Yi; Lv, Lijun; Jiang, Liwei; Wang, Xin; Li, Yanhong; Yu, Haiming; Feng, Xiaochen; Li, Qi; Zhang, Li; Li, Zhuo
2013-08-01
We investigated the design method of an infrared (IR)/microwave (MW) micromirror array type of beam combiner. The size of micromirror is in microscopic levels and comparable to MW wavelengths, so that the MW will not react in these dimensions, whereas the much shorter optical wavelengths will be reflected by them. Hence, the MW multilayered substrate was simplified and designed using transmission line theory. The beam combiner used an IR wavefront-division imaging technique to reflect the IR radiation image to the unit under test (UUT)'s pupil in a parallel light path. In addition, the boresight error detected by phase monopulse radar was analyzed using a moment-of method (MoM) and multilevel fast multipole method (MLFMM) acceleration technique. The boresight error introduced by the finite size of the beam combiner was less than 1°. Finally, in order to verify the wavefront-division imaging technique, a prototype of a micromirror array was fabricated, and IR images were tested. The IR images obtained by the thermal imager verified the correctness of the wavefront-division imaging technique.
Heat flow from the Liberian precambrian shield
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sass, J.H.; Behrendt, J.C.
1980-06-10
Uncorrected heat flow in iron formation rocks from three areas within the Liberian part of the West African Shield ranges from 50 to more than 80 mW m/sup -2/. When corrections are applied for topography and refraction, the range of heat flow is narrowed to between 38 and 42 mW m/sup -2/. In comparison with heat flows from other parts of the West African Craton, these values are consistent with preliminary results from Ghana (42 +- 8 mW m/sup -2/) and Nigeria (38 +- 2 mW /sup -2/) but are somewhat higher than values from Niger (20 mW m/sup -2/)more » and neighboring Sierra Leone (26 mW m/sup -2/). The Liberian values are significantly lower than the heat flow offshore in the equatorial Atlantic Ocean (58 +- 8 mW m/sup -2/), suggesting large lateral temperature gradients within the lithosphere near the coast. Values of heat production from outcrops of crystalline basement rocks near the holes are between 2 and 2.3 ..mu..W m/sup -3/. A heat-flow/heat-production relation cannot be established because of the small range of values; however, assuming a 'characteristic depth' of 8 km (similar to the North American Craton) the reduced heat flow of from 20 to 25 mW m/sup -2/ is consistent with that from other Precambrian shields.« less
Sundh, Ingvar
1992-01-01
The molecular size distribution and biochemical composition of the dissolved organic carbon released from natural communities of lake phytoplankton (photosynthetically produced dissolved organic carbon [PDOC]) and subsequently used by heterotrophic bacteria were determined in three lakes differing in trophic status and concentration of humic substances. After incubation of epilimnetic lake water samples with H14CO3- over one diel cycle, the phytoplankton were removed by size-selective filtration. The filtrates, still containing most of the heterotrophic bacteria, were reincubated in darkness (heterotrophic incubation). Differences in the amount and composition of PDO14C between samples collected before the heterotrophic incubation and samples collected afterwards were considered to be a result of bacterial utilization. The PDO14C collected at the start of the heterotrophic incubations always contained both high (>10,000)- and low (<1,000)-molecular-weight (MW) components and sometimes contained intermediate-MW components as well. In general, bacterial turnover rates of the low-MW components were fairly rapid, whereas the high-MW components were utilized slowly or not at all. In the humic lake, the intermediate-MW components accounted for a large proportion of the net PDO14C and were subject to rapid bacterial utilization. This fraction probably consisted almost entirely of polysaccharides of ca. 6,000 MW. Amino acids and peptides, other organic acids, and carbohydrates could all be quantitatively important parts of the low-MW PDO14C that was utilized by the heterotrophic bacteria, but the relative contributions of these fractions differed widely. It was concluded that, generally, low-MW components of PDOC are quantitatively much more important to the bacteria than are high-MW components, that PDOC released from phytoplankton does not contain substances of quantitative importance as bacterial substrates in all situations, and that high-MW components of PDOC probably contribute to the buildup of refractory, high-MW dissolved organic carbon in pelagic environments. PMID:16348767
Highly sensitive atomic based MW interferometry.
Shylla, Dangka; Nyakang'o, Elijah Ogaro; Pandey, Kanhaiya
2018-06-06
We theoretically study a scheme to develop an atomic based micro-wave (MW) interferometry using the Rydberg states in Rb. Unlike the traditional MW interferometry, this scheme is not based upon the electrical circuits, hence the sensitivity of the phase and the amplitude/strength of the MW field is not limited by the Nyquist thermal noise. Further, this system has great advantage due to its much higher frequency range in comparision to the electrical circuit, ranging from radio frequency (RF), MW to terahertz regime. In addition, this is two orders of magnitude more sensitive to field strength as compared to the prior demonstrations on the MW electrometry using the Rydberg atomic states. Further, previously studied atomic systems are only sensitive to the field strength but not to the phase and hence this scheme provides a great opportunity to characterize the MW completely including the propagation direction and the wavefront. The atomic based MW interferometry is based upon a six-level loopy ladder system involving the Rydberg states in which two sub-systems interfere constructively or destructively depending upon the phase between the MW electric fields closing the loop. This work opens up a new field i.e. atomic based MW interferometry replacing the conventional electrical circuit in much superior fashion.
Ultra Clean 1.1MW High Efficiency Natural Gas Engine Powered System
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zurlo, James; Lueck, Steve
Dresser, Inc. (GE Energy, Waukesha gas engines) will develop, test, demonstrate, and commercialize a 1.1 Megawatt (MW) natural gas fueled combined heat and power reciprocating engine powered package. This package will feature a total efficiency > 75% and ultra low CARB permitting emissions. Our modular design will cover the 1 – 6 MW size range, and this scalable technology can be used in both smaller and larger engine powered CHP packages. To further advance one of the key advantages of reciprocating engines, the engine, generator and CHP package will be optimized for low initial and operating costs. Dresser, Inc. willmore » leverage the knowledge gained in the DOE - ARES program. Dresser, Inc. will work with commercial, regulatory, and government entities to help break down barriers to wider deployment of CHP. The outcome of this project will be a commercially successful 1.1 MW CHP package with high electrical and total efficiency that will significantly reduce emissions compared to the current central power plant paradigm. Principal objectives by phases for Budget Period 1 include: • Phase 1 – market study to determine optimum system performance, target first cost, lifecycle cost, and creation of a detailed product specification. • Phase 2 – Refinement of the Waukesha CHP system design concepts, identification of critical characteristics, initial evaluation of technical solutions, and risk mitigation plans. Background« less
Heat flow from the Liberian Precambrian Shield
NASA Astrophysics Data System (ADS)
Sass, J. H.; Behrendt, J. C.
1980-06-01
Uncorrected heat flow in iron formation rocks from three areas within the Liberian part of the West African Shield ranges from 50 to more than 80 mW m-2. When corrections are applied for topography and refraction, the range of heat flow is narrowed to between 38 and 42 mW m-2. In comparison with heat flows from other parts of the West African Craton, these values are consistent with preliminary results from Ghana (42±8 mW m-2) and Nigeria (38±2 mW m-2) but are somewhat higher than values from Niger (20 mW m-2) and neighboring Sierra Leone (26 mW m-2). The Liberian values are significantly lower than the heat flow offshore in the equatorial Atlantic Ocean (58±8 m W m-2), suggesting large lateral temperature gradients within the lithosphere near the coast. Values of heat production from outcrops of crystalline basement rocks near the holes are between 2 and 2.3 /μW m-3. A heat-flow/heat-production relation cannot be established because of the small range of values; however, assuming a `characteristic depth' of 8 km (similar to the North American Craton) the reduced heat flow of from 20 to 25 mW m-2 is consistent with that from other Precambrian shields.
NASA Astrophysics Data System (ADS)
Wong, N. Z.; Feng, L.; Hill, E.
2017-12-01
The Sumatran plate boundary has experienced five Mw > 8 great earthquakes, a handful of Mw 7-8 earthquakes and numerous small to moderate events since the 2004 Mw 9.2 Sumatra-Andaman earthquake. The geodetic studies of these moderate earthquakes have mostly been passed over in favour of larger events. We therefore in this study present a catalog of coseismic uniform-slip models of one Mw 7.2 earthquake and 17 Mw 5.9-6.9 events that have mostly gone geodetically unstudied. These events occurred close to various continuous stations within the Sumatran GPS Array (SuGAr), allowing the network to record their surface deformation. However, due to their relatively small magnitudes, most of these moderate earthquakes were recorded by only 1-4 GPS stations. With the limited observations per event, we first constrain most of the model parameters (e.g. location, slip, patch size, strike, dip, rake) using various external sources (e.g., the ANSS catalog, gCMT, Slab1.0, and empirical relationships). We then use grid-search forward models to explore a range of some of these parameters (geographic position for all events and additionally depth for some events). Our results indicate the gCMT centroid locations in the Sumatran subduction zone might be biased towards the west for smaller events, while ANSS epicentres might be biased towards the east. The more accurate locations of these events are potentially useful in understanding the nature of various structures along the megathrust, particularly the persistent rupture barriers.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Seeley, R.S.
1994-04-01
The wind power industry blows strongly in Holland these days. The Netherlands topped 100 MW capacity at the beginning of this year. Most of this capacity consists of utility-run wind power plants, and a lesser number of small turbines, mainly operated by farmers. An ambitious government program pushes for 1,000 MW installed capacity by the year 2000. By then, 30 to 40 windpower plants, with more than 700 wind turbines, will crank out electricity along the coastal areas and dikes. With limited land space and dense population, planners see maximum room for 1,000 MW, of large turbines, to conserve space.more » For this reason, the market does not favor a wide range of turbine sizes. Currently, the 10 largest wind power plants in the Netherlands turn out 71.5 MW. The largest wind farm, in Noordoostpolder, southwest of Groningen, whips out 15 MW. To bolster wind power development, government subsidies shorten paybacks. Any many Dutch utilities apparently pay a good rate for wind-generated electricity. The rates are said to be better than those in the United States. Under the government plan, utilities will stimulate further development of technology to improve quality, lower costs, and introduce larger turbines. As this progresses, the government subsidy is expected to decrease. The second oil crisis of the late 1970s fanned Holland's wind energy surge. Since then, wind-electricity costs have fallen by half. The current government push is driven by the desire to reduce dependence on gas and oil, and reduce CO[sub 2] and coal emissions by increasing clean energy sources.« less
Intermediate load-center photovoltaic application experiments
DOE Office of Scientific and Technical Information (OSTI.GOV)
Burgess, E. L.
1980-01-01
A total of nine intermediate load-center photovoltaic systems were carried into the construction phase this year. These nine systems range in size from 20 to 225 kW/sub p/ electrical output and total almost 1 MW/sub p/. They are being installed in a diverse set of applications and locations and represent the bulk of the photovoltaic initial system evaluation experiments (ISEE) for the intermediate load-center sector. Each of these experiments are briefly described and the status of the construction phase is given for each project.
NASA Astrophysics Data System (ADS)
Cheng, Li-Chen; Bai, Wubin; Fernandez Martin, Eduardo; Tu, Kun-Hua; Ntetsikas, Konstantinos; Liontos, George; Avgeropoulos, Apostolos; Ross, C. A.
2017-04-01
The self-assembly of block copolymers with large feature sizes is inherently challenging as the large kinetic barrier arising from chain entanglement of high molecular weight (MW) polymers limits the extent over which long-range ordered microdomains can be achieved. Here, we illustrate the evolution of thin film morphology from a diblock copolymer of polystyrene-block-poly(dimethylsiloxane) exhibiting total number average MW of 123 kg mol-1, and demonstrate the formation of layers of well-ordered cylindrical microdomains under appropriate conditions of binary solvent mix ratio, commensurate film thickness, and solvent vapor annealing time. Directed self-assembly of the block copolymer within lithographically patterned trenches occurs with alignment of cylinders parallel to the sidewalls. Fabrication of ordered cobalt nanowire arrays by pattern transfer was also implemented, and their magnetic properties and domain wall behavior were characterized.
Brush Seals for Improved Steam Turbine Performance
NASA Technical Reports Server (NTRS)
Turnquist, Norman; Chupp, Ray; Baily, Fred; Burnett, Mark; Rivas, Flor; Bowsher, Aaron; Crudgington, Peter
2006-01-01
GE Energy has retrofitted brush seals into more than 19 operating steam turbines. Brush seals offer superior leakage control compared to labyrinth seals, owing to their compliant nature and ability to maintain very tight clearances to the rotating shaft. Seal designs have been established for steam turbines ranging in size from 12 MW to over 1200 MW, including fossil, nuclear, combined-cycle and industrial applications. Steam turbines present unique design challenges that must be addressed to ensure that the potential performance benefits of brush seals are realized. Brush seals can have important effects on the overall turbine system that must be taken into account to assure reliable operation. Subscale rig tests are instrumental to understanding seal behavior under simulated steam-turbine operating conditions, prior to installing brush seals in the field. This presentation discusses the technical challenges of designing brush seals for steam turbines; subscale testing; performance benefits of brush seals; overall system effects; and field applications.
Selective tuning of high-Q silicon photonic crystal nanocavities via laser-assisted local oxidation.
Chen, Charlton J; Zheng, Jiangjun; Gu, Tingyi; McMillan, James F; Yu, Mingbin; Lo, Guo-Qiang; Kwong, Dim-Lee; Wong, Chee Wei
2011-06-20
We examine the cavity resonance tuning of high-Q silicon photonic crystal heterostructures by localized laser-assisted thermal oxidation using a 532 nm continuous wave laser focused to a 2.5 μm radius spot-size. The total shift is consistent with the parabolic rate law. A tuning range of up to 8.7 nm is achieved with ∼ 30 mW laser powers. Over this tuning range, the cavity Qs decreases from 3.2×10(5) to 1.2×10(5). Numerical simulations model the temperature distributions in the silicon photonic crystal membrane and the cavity resonance shift from oxidation.
Green laser pointers for visual astronomy: how much power is enough?
Bará, Salvador; Robles, Marisol; Tejelo, Isabel; Marzoa, Ramón I; González, Héctor
2010-02-01
Green laser pointers with output powers in the tens to hundreds of milliwatt (mW) range, clearly exceeding the limiting 5 mW of American National Standards Institute class 3a (International Electrotechnical Commission class 3R), are now easily available in the global market. They are increasingly being used in public sky observations and other nighttime outreach activities by educators and science communicators in countries where their use is not well regulated, despite the fact that such high power levels may represent a potential threat to visual health. The purpose of this study was to determine the output power reasonably required to perform satisfactorily this kind of activities. Twenty-three observers were asked to vary continuously the output power of a green laser source (wavelength 532 nm) until clearly seeing the laser beam propagating skyward through the atmosphere in a heavily light-polluted urban setting. Measurements were conducted with observers of a wide range of ages (9 to 56 years), refractions (spherical equivalents -8.50 to +1.50 diopters), and previous expertise in using lasers as pointing devices outdoors (from no experience to professional astronomers). Two measurement runs were made in different nights under different meteorological conditions. The output power chosen by observers in the first run (11 observers) averaged to 1.84 mW (+/-0.68 mW, 1 SD). The second run (17 observers) averaged to 2.91 mW (+/-1.54 mW). The global average was 2.38 mW (+/-1.30 mW). Only one observer scored 5.6 mW, just above the class 3a limit. The power chosen by the remaining 22 observers ranged from 1.37 to 3.53 mW. Green laser pointers with output powers below 5 mW (laser classes American National Standards Institute 3a or International Electrotechnical Commission 3R) appear to be sufficient for use in educational nighttime outdoors activities, providing enough bright beams at reasonable safety levels.
NASA Astrophysics Data System (ADS)
Wongkrongsak, Soraya; Tangthong, Theeranan; Pasanphan, Wanvimol
2016-01-01
The research proposes a novel water-soluble silk fibroin nanoparticles (WSSF-NPs) created by electron beam irradiation. In this report, we demonstrate the effects of electron beam irradiation doses ranging from 1 to 30 kGy on the molecular weight (MW), nanostructure formation, antioxidant activity and reducing power of the WSSF-NPs. Electron beam-induced degradation of SF causing MW reduction from 250 to 37 kDa. Chemical characteristic functions of SF still remained after exposing to electron beam. The WSSF-NPs with the MW of 37 kDa exhibited spherical morphology with a nanoscaled size of 40 nm. Antioxidant activities and reducing powers were investigated using 2,2-diphenyl-1-picrylhryl free radical (DPPH•) scavenging activity and ferric reducing antioxidant power (FRAP) assays, respectively. The WSSF-NPs showed greater antioxidant activity and reducing power than non-irradiated SF. By increasing their antioxidant and reducing power efficiencies, WSSF-NPs potentially created gold nanocolloid. WSSF-NPs produced by electron beam irradiation would be a great merit for the uses as a natural antioxidant additive and a green reducing agent in biomedical, cosmetic and food applications.
915MHz microwave ablation with high output power in in vivo porcine spleens.
Gao, Yongyan; Wang, Yang; Duan, Yaqi; Li, Chunling; Sun, Yuanyuan; Zhang, Dakun; Lu, Tong; Liang, Ping
2010-07-01
The purpose of this study was to evaluate the efficacy of 915 MHz microwave (MW) ablation with high output power in in vivo porcine spleens. MW ablations were performed in 9 porcine spleens with an internally cooled 915 MHz antenna. Thermocouples were placed at 5, 10, 15, 20 mm away from the antenna to measure temperatures in real-time during MW emission. The energy was applied for 10 min at high output power of 60 W, 70 W or 80 W. Gross specimens were sectioned and measured to determine ablation size. Representative areas were examined by light microscopy and electron microscopy. Coagulation sizes and temperatures were compared among the three power groups. Hematoxylin-eosin staining showed irreversible necrosis in the splenic coagulation area after MW ablation. As the power was increased, long-axis diameter enlarged significantly (p<.05). Short-axis diameter also tended to increase, but there were no statistical difference (p>.05). The coagulation size of long-axis and short-axis diameter with 80 W in vivo spleen ablation was 6.43+/-0.52 and 4.95+/-0.30 cm, respectively. With the increase of output power, maximum temperatures at 5, 10, 15, 20 mm from the antenna were increased accordingly (p<.05). The maximum temperature with 80 W at 5 and 20 mm from the antenna reached 146.17+/-6.65 and 72.38+/-4.23 degrees C respectively. With internally cooled antenna and high output power, 915 MHz MW ablation in the spleen could produce irreversible tissue necrosis of clinical significance. MW ablation may be used as a promising minimally invasive method for the treatment of splenic diseases. Copyright 2009 Elsevier Ireland Ltd. All rights reserved.
Fast Computation of Ground Motion Shaking Map base on the Modified Stochastic Finite Fault Modeling
NASA Astrophysics Data System (ADS)
Shen, W.; Zhong, Q.; Shi, B.
2012-12-01
Rapidly regional MMI mapping soon after a moderate-large earthquake is crucial to loss estimation, emergency services and planning of emergency action by the government. In fact, many countries show different degrees of attention on the technology of rapid estimation of MMI , and this technology has made significant progress in earthquake-prone countries. In recent years, numerical modeling of strong ground motion has been well developed with the advances of computation technology and earthquake science. The computational simulation of strong ground motion caused by earthquake faulting has become an efficient way to estimate the regional MMI distribution soon after earthquake. In China, due to the lack of strong motion observation in network sparse or even completely missing areas, the development of strong ground motion simulation method has become an important means of quantitative estimation of strong motion intensity. In many of the simulation models, stochastic finite fault model is preferred to rapid MMI estimating for its time-effectiveness and accuracy. In finite fault model, a large fault is divided into N subfaults, and each subfault is considered as a small point source. The ground motions contributed by each subfault are calculated by the stochastic point source method which is developed by Boore, and then summed at the observation point to obtain the ground motion from the entire fault with a proper time delay. Further, Motazedian and Atkinson proposed the concept of Dynamic Corner Frequency, with the new approach, the total radiated energy from the fault and the total seismic moment are conserved independent of subfault size over a wide range of subfault sizes. In current study, the program EXSIM developed by Motazedian and Atkinson has been modified for local or regional computations of strong motion parameters such as PGA, PGV and PGD, which are essential for MMI estimating. To make the results more reasonable, we consider the impact of V30 for the ground shaking intensity, and the results of the comparisons between the simulated and observed MMI for the 2004 Mw 6.0 Parkfield earthquake, the 2008 Mw 7.9Wenchuan earthquake and the 1976 Mw 7.6Tangshan earthquake is fairly well. Take Parkfield earthquake as example, the simulative result reflect the directivity effect and the influence of the shallow velocity structure well. On the other hand, the simulative data is in good agreement with the network data and NGA (Next Generation Attenuation). The consumed time depends on the number of the subfaults and the number of the grid point. For the 2004 Mw 6.0 Parkfield earthquake, the grid size we calculated is 2.5° × 2.5°, the grid space is 0.025°, and the total time consumed is about 1.3hours. For the 2008 Mw 7.9 Wenchuan earthquake, the grid size calculated is 10° × 10°, the grid space is 0.05°, the total number of grid point is more than 40,000, and the total time consumed is about 7.5 hours. For t the 1976 Mw 7.6 Tangshan earthquake, the grid size we calculated is 4° × 6°, the grid space is 0.05°, and the total time consumed is about 2.1 hours. The CPU we used is 3.40GHz, and such computational time could further reduce by using GPU computing technique and other parallel computing technique. This is also our next focus.
Changes on aggregation in mine waste amended with biochar and marble mud
NASA Astrophysics Data System (ADS)
Ángeles Muñoz, María; Guzmán, Jose; Zornoza, Raúl; Moreno-Barriga, Fabián; Faz, Ángel; Lal, Rattan
2016-04-01
Mining activities have produced large amounts of wastes over centuries accumulated in tailing ponds in Southeast Spain. Applications of biochar may have a high potential for reclamation of degraded soils. Distribution, size and stability of aggregates are important indices of soil physical quality. However, research data on aggregation processes at amended mining tailings with biochar are scanty. Therefore, the aim of this study was to determine the effects of seven different treatments involving biochar and marble mud (MM) on the aggregation in mine waste (MW). Seven different treatments were tested after 90 days of incubation in the laboratory. These treatments were the mix of MW and: biochar from solid pig manure (PM), biochar from cotton crop residues (CR), biochar from municipal solid waste (MSW), marble mud (MM), PM+MM, CR+MM, MSW+MM and control without amendment. High sand percentages were identified in the MW. The biochars made from wastes (PM, CR, MSW) were obtained through pyrolysis of feedstocks. The water stability of soil aggregates was studied. The data on total aggregation were corrected for the primary particles considering the sandy texture of the MW. Moreover, partial aggregation was determined for each fraction and the mean weight diameter (MWD) of aggregates was computed. Soil bulk density and total porosity were also determined. No significant differences were observed in total aggregation and MWD among treatments including the control. For the size range of >4.75 mm, there were significant differences in aggregates > 4.75 mm between CR+MM in comparison with that for CT. There were also significant differences between MSW and PM+MM for the 1-0.425 mm fraction, and between CT and MM and CR for 0.425-0.162 mm aggregate size fractions. Therefore, CR-derived biochar applied with MM enhanced stability of macro-aggregates. Furthermore, soil bulk density was also the lowest bulk density and total porosity the highest for the CR-derived biochar treatment because macro aggregate stability is largely responsible for macro-porosity. The decrease in bulk density may be an indication of a positive effect for mine waste reclamation. Conversely, no differences were observed among treatments in micro-aggregate stability. Apparently, low organic matter contents in MW needed to be co-amended with labile organic amendments to effectively increase soil aggregation. Furthermore, the presence of Fe hydroxides could also increase the micro-aggregation. Additional research is needed to understand the mechanisms of mine soil reclamation. Acknowledgement : This work has been funded by Fundación Séneca (Agency of Science and Technology of the Region of Murcia, Spain
Qhattal, Hussaini Syed Sha; Liu, Xinli
2011-01-01
Hyaluronan (HA) is a biocompatible and biodegradable linear polysaccharide which is of interest for tumor targeting through cell surface CD44 receptors. HA binds with high affinity to CD44 receptors, which are overexpressed in many tumors and involved in cancer metastasis. In the present study, we investigated the impact of HA molecular weight (MW), grafting density, and CD44 receptor density on endocytosis of HA-grafted liposomes (HA-liposomes) by cancer cells. Additionally, the intracellular localization of the HA-liposomes was determined. HAs of different MWs (5-8, 10-12, 175-350, and 1600 kDa) were conjugated to liposomes with varying degrees of grafting density. HA surface density was quantified using the hexadecyltrimethylammonium bromide turbidimetric method. Cellular uptake and subcellular localization of HA-liposomes were evaluated by flow cytometry and fluorescence microscopy. Mean particle sizes of HA-liposomes ranged from 120 to 180 nm and increased with the bigger size of HA. HA-liposome uptake correlated with HA MW (5-8 < 10-12 < 175-350 kDa), grafting density, and CD44 receptor density and exceeded that obtained with unconjugated plain liposomes. HA-liposomes were taken up into cells via lipid raft-mediated endocytosis, which is both energy- and cholesterol-dependent. Once within cells, HA-liposomes localized primarily to endosomes and lysosomes. The results demonstrate that cellular targeting efficiency of HA-liposomes depends strongly upon HA MW, grafting density, and cell surface receptor CD44 density. The results support a role of HA-liposomes for targeted drug delivery. PMID:21696190
PEGylated PEI-based biodegradable polymers as non-viral gene vectors.
Huang, Fu-Wei; Wang, Hui-Yuan; Li, Cao; Wang, Hua-Fen; Sun, Yun-Xia; Feng, Jun; Zhang, Xian-Zheng; Zhuo, Ren-Xi
2010-11-01
Novel functional biodegradable gene vectors, poly(L-succinimide)-g-polyethylenimines-g-poly(ethylene glycol) (PSI-g-PEI-g-PEGs) were synthesized by conjugating methoxy poly(ethylene glycol) (mPEG, M(w)=750 Da) to PEI segments (M(w)=800 Da) of PSI-g-PEI. The physicochemical properties of PSI-g-PEI-g-PEGs, including buffering capability, pDNA binding ability, cytotoxicity, zeta potential and the particle size of polymer/pDNA complexes, were explored. The influence of PEGylation was discussed based on a comparative study of PSI-g-PEI-g-PEGs, PSI-g-PEI and PEI25k (M(w)=25 kDa). SEM images revealed that PSI-g-PEI-g-PEG/pDNA particles have a regular shape with the diameter ranging from 70 to 170 nm. PEGylation could suppress the aggregation occurrence between complexes, resulting in a reduction of the polymer/pDNA complex size. PSI-g-PEI-g-PEGs exhibited remarkably lower cytotoxicity compared to PSI-g-PEI and PEI25k. In 293T and HeLa cells, the obtained PSI-g-PEI-g-PEGs showed very high transfection efficiency compared to PEI25k. Fluorescent confocal microscopy demonstrated that PSI-g-PEI-g-PEGs could effectively transport pGL-3 plasmids into the nuclei of HeLa cells. Taking into account the continued high transfection efficacy and decreased toxicity after PEG modification, PSI-g-PEI-g-PEGs show great potential as the non-viral vectors for gene transfection. Copyright © 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bill Major
The use of stationary gas turbines for power generation has been growing rapidly with continuing trends predicted well into the future. Factors that are contributing to this growth include advances in turbine technology, operating and siting flexibility and low capital cost. Restructuring of the electric utility industry will provide new opportunities for on-site generation. In a competitive market, it maybe more cost effective to install small distributed generation units (like gas turbines) within the grid rather than constructing large power plants in remote locations with extensive transmission and distribution systems. For the customer, on-site generation will provide added reliability andmore » leverage over the cost of purchased power One of the key issues that is addressed in virtually every gas turbine application is emissions, particularly NO{sub x} emissions. Decades of research and development have significantly reduced the NO{sub x} levels emitted from gas turbines from uncontrolled levels. Emission control technologies are continuing to evolve with older technologies being gradually phased-out while new technologies are being developed and commercialized. The objective of this study is to determine and compare the cost of NO{sub x} control technologies for three size ranges of stationary gas turbines: 5 MW, 25 MW and 150 MW. The purpose of the comparison is to evaluate the cost effectiveness and impact of each control technology as a function of turbine size. The NO{sub x} control technologies evaluated in this study include: Lean premix combustion, also known as dry low NO{sub x} (DLN) combustion; Catalytic combustion; Water/steam injection; Selective catalytic reduction (SCR)--low temperature, conventional, high temperature; and SCONO{sub x}{trademark}.« less
NASA Astrophysics Data System (ADS)
Mögelin, H.; Yao, G.; Zhong, H.; dos Santos, A. R.; Barascu, A.; Meyer, R.; Krenkel, S.; Wassersleben, S.; Hickmann, T.; Enke, D.; Turek, T.; Kunz, U.
2018-02-01
The improvement of redox-flow batteries requires the development of chemically stable and highly conductive separators. Porous glass membranes can be an attractive alternative to the nowadays most common polymeric membranes. Flat porous glass membranes with a pore size in the range from 2 to 50 nm and a thickness of 300 and 500 μm have been used for that purpose. Maximum values for voltage efficiency of 85.1%, coulombic efficiency of 97.9% and energy efficiency of 76.3% at current densities in the range from 20 to 60 mA cm-2 have been achieved. Furthermore, a maximum power density of 95.2 mW cm-2 at a current density of 140 mA cm-2 was gained. These results can be related to small vanadium crossover, high conductivity and chemical stability, confirming the great potential of porous glass membranes for vanadium redox-flow applications.
Varao-Sousa, Trish L; Kingstone, Alan
2018-06-26
Mind wandering (MW) reports often rely on individuals responding to specific external thought probes. Researchers have used this probe-caught method almost exclusively, due to its reliability across a wide range of testing situations. However, it remains an open question whether the probe-caught MW rates in more complex settings converge with those for simpler tasks, because of the rather artificial and controlled nature of the probe-caught methodology itself, which is shared across the different settings. To address this issue, we measured MW in a real-world lecture, during which students indicated whether they were mind wandering by simply catching themselves (as one would normally do in real life) or by catching themselves and responding to thought probes. Across three separate lectures, self-caught MW reports were stable and unaffected by the inclusion of MW probes. That the probe rates were similar to those found in prior classroom research and did not affect the self-caught MW rates strongly suggests that the past consistency of probe-caught MW rates across a range of different settings is not an artifact of the thought-probe method. Our study also indicates that the self-caught MW methodology is a reliable way to acquire MW data. The extension of measurement techniques to include students' self-caught reports provides valuable information about how to successfully and naturalistically monitor MW in lecture settings, outside the laboratory.
Repeated Earthquakes in the Vrancea Subcrustal Source and Source Scaling
NASA Astrophysics Data System (ADS)
Popescu, Emilia; Otilia Placinta, Anica; Borleasnu, Felix; Radulian, Mircea
2017-12-01
The Vrancea seismic nest, located at the South-Eastern Carpathians Arc bend, in Romania, is a well-confined cluster of seismicity at intermediate depth (60 - 180 km). During the last 100 years four major shocks were recorded in the lithosphere body descending almost vertically beneath the Vrancea region: 10 November 1940 (Mw 7.7, depth 150 km), 4 March 1977 (Mw 7.4, depth 94 km), 30 August 1986 (Mw 7.1, depth 131 km) and a double shock on 30 and 31 May 1990 (Mw 6.9, depth 91 km and Mw 6.4, depth 87 km, respectively). The probability of repeated earthquakes in the Vrancea seismogenic volume is relatively large taking into account the high density of foci. The purpose of the present paper is to investigate source parameters and clustering properties for the repetitive earthquakes (located close each other) recorded in the Vrancea seismogenic subcrustal region. To this aim, we selected a set of earthquakes as templates for different co-located groups of events covering the entire depth range of active seismicity. For the identified clusters of repetitive earthquakes, we applied spectral ratios technique and empirical Green’s function deconvolution, in order to constrain as much as possible source parameters. Seismicity patterns of repeated earthquakes in space, time and size are investigated in order to detect potential interconnections with larger events. Specific scaling properties are analyzed as well. The present analysis represents a first attempt to provide a strategy for detecting and monitoring possible interconnections between different nodes of seismic activity and their role in modelling tectonic processes responsible for generating the major earthquakes in the Vrancea subcrustal seismogenic source.
MW-assisted synthesis of SVO for ICD primary batteries
NASA Astrophysics Data System (ADS)
Beninati, Sabina; Fantuzzi, Matteo; Mastragostino, Marina; Soavi, Francesca
An Ag 2V 4O 11 (SVO) cathode material prepared by microwave (MW)-assisted solid-state synthesis (MW-SVO) was developed for lithium primary batteries for implantable cardioverter/defibrillators (ICDs). This paper presents the results of physical-chemical and electrochemical characterizations of MW-SVO as well as those of SVO prepared by conventional thermal route (T-SVO). A specific effect of MWs which accelerates the synthesis reaction and contributes to yield a material of different morphology and degree of crystallinity compared with those of T-SVO was observed. The results of pulsed electrochemical tests carried out at 37 °C in operative conditions of ICDs on Li/MW-SVO batteries with cathode mass loading sized for practical use are also reported. These tests demonstrated that MW-SVO can be used for high performing lithium primary battery delivering in few seconds the specific energy values required by ICD application.
Yu, Hong; Nguyen, Minh-Hiep; Hadinoto, Kunn
2018-01-01
To investigate the effects of varying molecular weight (MW) of chitosan (CHI) used in the complexation with curcumin (CUR) on the physical and dissolution characteristics of the amorphous CUR-CHI nanoparticle complex produced. Amorphous CUR-CHI nanoparticle complex (or CUR nanoplex in short) recently emerged as a promising bioavailability enhancement strategy of CUR attributed to its fast dissolution, supersaturation generation capability, and simple preparation. Existing CUR nanoplex prepared using low MW CHI, however, exhibited poor colloidal stability during storage. Herein we hypothesized that the colloidal stability could be improved by using CHI of higher MW. The effects of this approach on the nanoplex's other characteristics were simultaneously investigated. The CUR nanoplex was prepared by electrostatically driven self-assembled complexation between CUR and oppositely charged CHI of three different MWs (i.e. low, medium, and high). Besides colloidal stability, the effects of MW variation were investigated for the nanoplex's (1) other physical characteristics (i.e. size, zeta potential, CUR payload, amorphous state stability), (2) preparation efficiency (i.e. CUR utilization rate, yield), and (3) dissolutions under sink condition and supersaturation generation. CUR nanoplex prepared using CHI of high MW exhibited improved colloidal stability, larger size, superior morphology, and prolonged supersaturation generation. On the other hand, the effects of MW variation on the payload, amorphous state stability, preparation efficiency, and dissolution under sink condition were found to be insignificant. Varying MW of CHI used was an effective means to improve certain aspects of the CUR nanoplex characteristics with minimal adverse effects on the others.
A 0.7 V 6.66-9.36 GHz wide tuning range CMOS LC VCO with small chip size
NASA Astrophysics Data System (ADS)
Chen, Jun-Da; Zhang, Jie
2017-10-01
The circuit designs are based on TSMC 0.18 μm CMOS standard technology model. The designed circuit uses transformer coupling technology in order to decrease chip area and increase the Q value. The switched-capacitor topology array enables the voltage-controlled oscillator (VCO) to be tuned between 6.66 and 9.36 GHz with 4.9 mW power consumption at supply voltage of 0.7 V, and the tuning range of the circuit can reach 33.7%. The measured phase noise is -110.5 dBc/Hz at 1 MHz offset from the carrier frequency of 7.113 GHz. The output power level is about -1.22 dBm. The figure-of-merit and figure-of-merit-with-tuning range of the VCO are about -180.7 and -191.25 dBc/Hz, respectively. The chip area is 0.429 mm2 excluding the pads. The presented ultra-wideband VCO leads to a better performance in terms of power consumption, tuning range, chip size and output power level for low supply voltage.
Characterization, origin and aggregation behavior of colloids in eutrophic shallow lake.
Xu, Huacheng; Xu, Mengwen; Li, Yani; Liu, Xin; Guo, Laodong; Jiang, Helong
2018-05-31
Stability of colloidal particles contributes to the turbidity in the water column, which significantly influences water quality and ecological functions in aquatic environments especially shallow lakes. Here we report characterization, origin and aggregation behavior of aquatic colloids, including natural colloidal particles (NCPs) and total inorganic colloidal particles (TICPs), in a highly turbid shallow lake, via field observations, simulation experiments, ultrafiltration, spectral and microscopic, and light scattering techniques. The colloidal particles were characterized with various shapes (spherical, polygonal and elliptical) and aluminum-, silicon-, and ferric-containing mineralogical structures, with a size range of 20-200 nm. The process of sediment re-suspension under environmentally relevant conditions contributed 78-80% of TICPs and 54-55% of NCPs in Lake Taihu, representing an important source of colloids in the water column. Both mono- and divalent electrolytes enhanced colloidal aggregation, while a reverse trend was observed in the presence of natural organic matter (NOM). The influence of NOM on colloidal stability was highly related to molecular weight (MW) properties with the high MW fraction exhibiting higher stability efficiency than the low MW counterparts. However, the MW-dependent aggregation behavior for NCPs was less significant than that for TICPs, implying that previous results on colloidal behavior using model inorganic colloids alone should be reevaluated. Further studies are needed to better understand the mobility/stability and transformation of aquatic colloids and their role in governing the fate and transport of pollutants in natural waters. Copyright © 2018. Published by Elsevier Ltd.
NASA Astrophysics Data System (ADS)
Arora, Shreya; Malik, Javed N.
2017-12-01
The Himalaya is one of the most seismically active regions of the world. The occurrence of several large magnitude earthquakes viz. 1905 Kangra earthquake (Mw 7.8), 1934 Bihar-Nepal earthquake (Mw 8.2), 1950 Assam earthquake (Mw 8.4), 2005 Kashmir (Mw 7.6), and 2015 Gorkha (Mw 7.8) are the testimony to ongoing tectonic activity. In the last few decades, tremendous efforts have been made along the Himalayan arc to understand the patterns of earthquake occurrences, size, extent, and return periods. Some of the large magnitude earthquakes produced surface rupture, while some remained blind. Furthermore, due to the incompleteness of the earthquake catalogue, a very few events can be correlated with medieval earthquakes. Based on the existing paleoseismic data certainly, there exists a complexity to precisely determine the extent of surface rupture of these earthquakes and also for those events, which occurred during historic times. In this paper, we have compiled the paleo-seismological data and recalibrated the radiocarbon ages from the trenches excavated by previous workers along the entire Himalaya and compared earthquake scenario with the past. Our studies suggest that there were multiple earthquake events with overlapping surface ruptures in small patches with an average rupture length of 300 km limiting Mw 7.8-8.0 for the Himalayan arc, rather than two or three giant earthquakes rupturing the whole front. It has been identified that the large magnitude Himalayan earthquakes, such as 1905 Kangra, 1934 Bihar-Nepal, and 1950 Assam, that have occurred within a time frame of 45 years. Now, if these events are dated, there is a high possibility that within the range of ±50 years, they may be considered as the remnant of one giant earthquake rupturing the entire Himalayan arc. Therefore, leading to an overestimation of seismic hazard scenario in Himalaya.
Feasibility Study for the Ivano-Frankivsk District Heating Repowering: Analysis of Options
DOE Office of Scientific and Technical Information (OSTI.GOV)
Markel, L.; Popelka, A.; Laskarevsky, V.
2002-03-20
Part of the U.S. Initiative on Joint Implementation with the Ukraine Inter-Ministerial Commission on Climate Change, financed by the US Department of Energy. The project was implemented by a team consisting of the US company SenTech, Inc. and the Ukrainian company Esco-West. The main objective of the effort was to assess available alternatives of Ivano-Frankivsk (I-F) District Heating repowering and provide information for I-F's investment decision process. This study provides information on positive and negative technical and economic aspects of available options. Three options were analyzed for technical merit and economic performance: 1. Installation of cogeneration system based on Gasmore » Turbine (GT) and Heat Recovery Heat Exchanger with thermal capacity of 30 MW and electrical capacity of 13.5 MW. This Option assumes utilization of five existing boilers with total capacity of 221 MW. Existing boilers will be equipped with modern controls. Equipment in this Option was sized for longest operating hours, about 8000 based on the available summer baseload. 2. Installation of Gas Turbine Combined Cycle (GTCC) and Heat Recovery Steam Generator (HRSG) with thermal capacity 45 MW and electrical capacity of 58.7 MW. This Option assumes utilization of five existing boilers with total capacity of 221 MW. Existing boilers will be equipped with modern controls. The equipment was sized for medium, shoulder season thermal load, and some cooling was assumed during the summer operation for extension of operating hours for electricity production. 3. Retrofit of six existing boilers (NGB) with total thermal capacity of 255.9 MW by installation of modern control system and minor upgrades. This option assumes only heat production with minimum investment. The best economic performance and the largest investment cost would result from alternative GTCC. This alternative has positive Net Present Value (NPV) with discount rate lower than about 12%, and has IRR slightly above 12%. The lowest economic results, and the lowest required investment, would result from alternative NGB. This Option's NPV is negative even at 0% discount rate, and would not become positive even by improving some parameters within a reasonable range. The Option with Gas Turbine displays relatively modest results and the NPV is positive for low discount rate, higher price of sold electricity and lower cost of natural gas. The IRR of this alternative is 9.75%, which is not very attractive. The largest influences on the investment are from the cost of electricity sold to the grid, the heat tariff, and the cost of natural gas. Assuming the implementation of the GTCC alternative, the benefit of the project is also reflected in lower Green House Emissions.« less
Recent advancements in photorefractive holographic imaging
NASA Astrophysics Data System (ADS)
Lynn, B.; Blanche, P.-A.; Bablumian, A.; Rankin, R.; Voorakaranam, R.; St. Hilaire, P.; LaComb, L., Jr.; Yamamoto, M.; Peyghambarian, N.
2013-02-01
We have recently demonstrated several improvements in material properties and optical design to increase the resolution, size, brightness, and color range of updatable holograms using photorefractive materials. A compact system has been developed that is capable of producing holograms with brightness in excess of 2,500 cd/m2 using less than 20mW of CW laser power. The size of the hologram has been increased to 300mm × 150mm with a writing time of less than 8 seconds using a 50 Hz pulse laser. Optical improvements have been implemented to reduce the hogel size to less than 200 μm. We have optimized the color gamut to extend beyond the NTSC CIE color space through a combination of spatial and polarization multiplexing. Further improvements could bring applications in telemedicine, prototyping, advertising, updatable 3D maps and entertainment.
ABB's advanced steam turbine program
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chellini, R.
Demand for industrial steam turbines for combined-cycle applications and cogeneration plants has influenced turbine manufacturers to standardize their machines to reduce delivery time and cost. ABB, also a supplier of turnkey plants, manufactures steam turbines in Finspong, Sweden, at the former ASEA Stal facilities and in Nuernberg, Germany, at the former AEG facilities. The companies have joined forces, setting up the advanced Steam Turbine Program (ATP) that, once completed, will cover a power range from two to 100 MW. The company decided to use two criteria as a starting point, the high efficiency design of the Swedish turbines and themore » high reliability of the German machines. Thus, the main task was combining the two designs in standard machines that could be assembled quickly into predefined packages to meet specific needs of combined-cycle and cogeneration plants specified by customers. In carrying out this project, emphasis was put on cost reduction as one of the main goals. The first results of the ATP program, presented by ABB Turbinen Nuernberg, is the range of 2-30 MW turbines covered by two frame sizes comprising standard components supporting the thermodynamic module. An important feature is the standardization of the speed reduction gearbox.« less
NASA Astrophysics Data System (ADS)
Rezaei, Farzaneh; Richard, Tom L.; Logan, Bruce E.
Microbial fuel cells (MFCs) produce bioelectricity from a wide variety of organic and inorganic substrates. Chitin can be used as a slowly degrading substrate in MFCs and thus as a long-term fuel to sustain power by these devices in remote locations. However, little is known about the effects of particle size on power density and length of the power cycle (longevity). We therefore examined power generation from chitin particles sieved to produce three average particle sizes (0.28, 0.46 and 0.78 mm). The longevity increased from 9 to 33 days with an increase in the particle diameter from 0.28 to 0.78 mm. Coulombic efficiency also increased with particle size from 18% to 56%. The maximum power density was lower for the largest (0.78 mm) particles (176 mW m -2), with higher power densities for the 0.28 mm (272 mW m -2) and 0.46 mm (252 mW m -2) particle sizes. The measured lifetimes of these particles scaled with particle diameter to the 1.3 power. Application of a fractal dissolution model indicates chitin particles had a three-dimensional fractal dimension between 2 and 2.3. These results demonstrate particles can be used as a sustainable fuel in MFCs, but that particle sizes will need to be controlled to achieve desired power levels.
Higher Signal-to-Noise Measurements of Alpha-element Abundances in the M31 System
NASA Astrophysics Data System (ADS)
Escala, Ivanna; Kirby, Evan N.
2018-06-01
The stellar halo and tidal streams of M31 provide an essential counterpoint to the same structures around the Milky Way (MW). While measurements of [Fe/H] and [$\\alpha$/Fe] have been made in the MW, little is known about the detailed chemical abundances of the M31 system. To make progress with existing telescopes, we expand upon the technique first presented by Kirby et al., applying spectral synthesis to medium-resolution spectroscopy at lower spectral resolution (R $\\sim$ 1800) across an optical range (4100~\\AA \\ $<$ $\\lambda$ $<$ 9100~\\AA) that extends down the blue. We have obtained deep spectra of red giants in the tidal streams, smooth halo, and disk of M31 using the DEIMOS 600ZD grating, resulting in higher signal-to-noise per spectral resolution element (S/N $\\sim$ 30 \\AA$^{-1}$). By applying our technique to red giant stars in MW globular clusters with higher-resolution ($R$ $\\sim$ 6000) spectra in the blue (4100 - 6300 \\AA), we demonstrate that our technique reproduces previous measurements derived from the red side of the optical (6300 - 9100 \\AA). For the first time, we present measurements of [Fe/H] and [$\\alpha$/Fe] of sufficient quality and sample size to construct quantitative models of galactic chemical evolution in the M31 system.
Focal Mechanisms and Stress Environment of the 12 May 2008 Wenchuan, China, Earthquake Sequence
NASA Astrophysics Data System (ADS)
Zhao, L.; Luo, Y.; Ni, S.
2012-12-01
The 12 May 2008 Wenchuan earthquake (Mw=7.9) was the largest earthquake in China ever recorded by modern seismic instruments. It generated numerous moderate sized aftershocks that were well recorded by both permanent stations as well as portable instruments deployed after the mainshock. These waveform records yield high-quality data for the determination of focal mechanisms of aftershocks, which in turn provide important information for the investigation of regional stress field and the seismogenic environment in the Wenchuan earthquake source region. In this study, we determine the focal mechanisms, depths and moment magnitudes of moderate-sized (Mw ≥ 4.0) Wenchuan aftershocks using broadband waveform records. The focal mechanism results are then used to obtain the orientation and ratio of the principle stresses by the damped linear stress inversion method of Hardebeck & Michael (2006). Our results show that the majority of the moderate aftershocks occur at a depth range of 10-20 km and outside of the major rupture zones of the mainshock. The Wenchuan source region remains under a nearly horizontal compression with mostly thrust and occasional strike-slip faulting, especially towards the two ends of the rupture of the main shock. There is also clearly local variations in the orientation of the principle stresses.
Low-temperature positron annihilation study of B+-ion implanted PMMA
NASA Astrophysics Data System (ADS)
Kavetskyy, T. S.; Tsmots, V. M.; Voloshanska, S. Ya.; Šauša, O.; Nuzhdin, V. I.; Valeev, V. F.; Osin, Y. N.; Stepanov, A. L.
2014-08-01
Temperature dependent positron annihilation lifetime spectroscopy (PALS) measurements in the range of 50-300 K are carried out to study positronium formation in 40 KeV B+-ion implanted polymethylmethacrylate (B:PMMA) with two ion doses of 3.13 × 1015 and 3.75 × 1016 ions/cm2. The investigated samples show the various temperature trends of ortho-positronium (o-Ps) lifetime τ3 and intensity I3 in PMMA before and after ion implantation. Two transitions in the vicinity of ˜150 and ˜250 K, ascribed to γ and β transitions, respectively, are observed in the PMMA and B:PMMA samples in consistent with reference data for pristine sample. The obtained results are compared with room temperature PALS study of PMMA with different molecular weight (Mw) which known from literature. It is found that B+-ion implantation leads to decreasing Mw in PMMA at lower ion dose. At higher ion dose the local destruction of polymeric structure follows to broadening of lifetime distribution (hole size distribution).
NASA Astrophysics Data System (ADS)
Kimura, H.; Asano, Y.; Matsumoto, T.
2012-12-01
The rapid determination of hypocentral parameters and their transmission to the public are valuable components of disaster mitigation. We have operated an automatic system for this purpose—termed the Accurate and QUick Analysis system for source parameters (AQUA)—since 2005 (Matsumura et al., 2006). In this system, the initial hypocenter, the moment tensor (MT), and the centroid moment tensor (CMT) solutions are automatically determined and posted on the NIED Hi-net Web site (www.hinet.bosai.go.jp). This paper describes improvements made to the AQUA to overcome limitations that became apparent after the 2011 Tohoku Earthquake (05:46:17, March 11, 2011 in UTC). The improvements included the processing of NIED F-net velocity-type strong motion records, because NIED F-net broadband seismographs are saturated for great earthquakes such as the 2011 Tohoku Earthquake. These velocity-type strong motion seismographs provide unsaturated records not only for the 2011 Tohoku Earthquake, but also for recording stations located close to the epicenters of M>7 earthquakes. We used 0.005-0.020 Hz records for M>7.5 earthquakes, in contrast to the 0.01-0.05 Hz records employed in the original system. The initial hypocenters determined based on arrival times picked by using seismograms recorded by NIED Hi-net stations can have large errors in terms of magnitude and hypocenter location, especially for great earthquakes or earthquakes located far from the onland Hi-net network. The size of the 2011 Tohoku Earthquake was initially underestimated in the AQUA to be around M5 at the initial stage of rupture. Numerous aftershocks occurred at the outer rise east of the Japan trench, where a great earthquake is anticipated to occur. Hence, we modified the system to repeat the MT analyses assuming a larger size, for all earthquakes for which the magnitude was initially underestimated. We also broadened the search range of centroid depth for earthquakes located far from the onland Hi-net network. After implementing the above improvements, the CMT solution for the 2011 Tohoku Earthquake was successfully determined with a moment magnitude (Mw) of 8.6 (9.04 × 10^21 Nm). The focal mechanisms and centroid depths of the 2011 Tohoku Earthquake and M>7 aftershocks, as obtained using the improved system, are in agreement with those from the GlobalCMT. The sizes of these earthquakes are also consistent with those of GlobalCMT, with differences of less than Mw 0.1 except for the mainshock (Mw9.1, 5.31 × 10^22 Nm, GlobalCMT). This discrepancy may indicate that the bandwidth used in the analysis is insufficient for an earthquake of this size. To address this shortcoming, we used 0.0025-0.0100 Hz records and obtained a magnitude of Mw8.9 (3.35 × 10^22 Nm). This result is consistent with the GlobalCMT and other results (e.g., Mw 9.0, 3.43 × 10^22 Nm reported by Ozawa et al., 2011; Mw9.0, 4.42 × 10^22 Nm reported by Suzuki et al., 2011). Using the improved system, the CMT analysis for the 2011 Tohoku Earthquake is estimated to be completed within 12 minutes of the origin time.
Intermediate-sized natural gas fueled carbonate fuel cell power plants
NASA Astrophysics Data System (ADS)
Sudhoff, Frederick A.; Fleming, Donald K.
1994-04-01
This executive summary of the report describes the accomplishments of the joint US Department of Energy's (DOE) Morgantown Energy Technology Center (METC) and M-C POWER Corporation's Cooperative Research and Development Agreement (CRADA) No. 93-013. This study addresses the intermediate power plant size between 2 megawatt (MW) and 200 MW. A 25 MW natural-gas, fueled-carbonate fuel cell power plant was chosen for this purpose. In keeping with recent designs, the fuel cell will operate under approximately three atmospheres of pressure. An expander/alternator is utilized to expand exhaust gas to atmospheric conditions and generate additional power. A steam-bottoming cycle is not included in this study because it is not believed to be cost effective for this system size. This study also addresses the simplicity and accuracy of a spreadsheet-based simulation with that of a full Advanced System for Process Engineering (ASPEN) simulation. The personal computer can fully utilize the simple spreadsheet model simulation. This model can be made available to all users and is particularly advantageous to the small business user.
A versatile electrophoresis system for the analysis of high- and low-molecular-weight proteins
Tastet, Christophe; Lescuyer, Pierre; Diemer, Hélène; Luche, Sylvie; van Dorsselaer, Alain; Rabilloud, Thierry
2003-01-01
A new, versatile, multiphasic buffer system for high resolution sodium dodecyl sulfatepolyacrylamide gel electrophoresis of proteins in the relative molecular weight Mw range of 300,000-3000 Da is described. The system, based on the theory of multiphasic zone electrophoresis, allows complete stacking and destacking of proteins in the above Mw range. The buffer system uses taurine and chloride as trailing and leading ion, respectively, and Tris, at a pH close to its pKa, as the buffering counter ion. Coupled with limited variation in the acrylamide concentration, this electrophoresis system allows to tailor the resolution in the 6–200 kDa Mw range, with minimal difficulties in the post electrophoretic identification processes. PMID:12783456
State Models to Incentivize and Streamline Small Hydropower Development
DOE Office of Scientific and Technical Information (OSTI.GOV)
Curtis, Taylor; Levine, Aaron; Johnson, Kurt
In 2016, the hydropower fleet in the United States produced more than 6 percent (approximately 265,829 gigawatt-hours [GWh]) of the total net electricity generation. The median-size hydroelectric facility in the United States is 1.6 MW and 75 percent of total facilities have a nameplate capacity of 10 MW or less. Moreover, the U.S. Department of Energy's Hydropower Vision study identified approximately 79 GW hydroelectric potential beyond what is already developed. Much of the potential identified is at low-impact new stream-reaches, existing conduits, and non-powered dams with a median project size of 10 MW or less. To optimize the potential andmore » value of small hydropower development, state governments are crafting policies that provide financial assistance and expedite state and federal review processes for small hydroelectric projects. This report analyzes state-led initiatives and programs that incentivize and streamline small hydroelectric development.« less
All-polarization maintaining erbium fiber laser based on carbon nanowalls saturable absorber
NASA Astrophysics Data System (ADS)
Kurata, Shintaro; Izawa, Jun; Kawaguchi, Norihito
2018-02-01
We report a soliton mode locked femtosecond oscillation with all-polarization maintaining erbuim doped fiber laser based on Carbon Nanowalls saturable absorber (CNWs SA). To improve the stability and the capability of the oscillator, the all-polarization maintaining(all-PM) fiber is generally used since PM fiber is tolerant of stretches and bends. The saturable absorber is an optical device that placed in a laser cavity to suppress continuous wave operation to promote cooperation between many modes to sustain ultrashort pulse operation. We apply CNWs for the material of SAs in our oscillator. CNWs are one of the nanocarbon materials, which are a high-aspect-ratio structure in the cross-section, where, although their width and height range in a few micrometers, the thickness is as small as ten nanometers or so. A sheet of CNWs is made up of nano-size graphite grain aggregates. Then CNWs structure is expected to have a high absorption to the incident light and large modulation depth due to a small number of carbon layers as well as CNT and Graphene. With this all-PM fiber laser oscillator based on CNWs SA, the soliton mode-locked laser oscillated with 66.3MHz repetition frequency and its spectrum width is 5.6nm in FWHM. Average output power is 8.1mW with 122.5mW laser diode pump power. In addition, the laser amplification system with erbium-doped fiber is constructed and amplifies the femtosecond pulse laser into 268.2mW and 3000mW pumping power.
UAV-borne lidar with MEMS mirror-based scanning capability
NASA Astrophysics Data System (ADS)
Kasturi, Abhishek; Milanovic, Veljko; Atwood, Bryan H.; Yang, James
2016-05-01
Firstly, we demonstrated a wirelessly controlled MEMS scan module with imaging and laser tracking capability which can be mounted and flown on a small UAV quadcopter. The MEMS scan module was reduced down to a small volume of <90mm x 60mm x 40mm, weighing less than 40g and consuming less than 750mW of power using a ~5mW laser. This MEMS scan module was controlled by a smartphone via Bluetooth while flying on a drone, and could project vector content, text, and perform laser based tracking. Also, a "point-and-range" LiDAR module was developed for UAV applications based on low SWaP (Size, Weight and Power) gimbal-less MEMS mirror beam-steering technology and off-the-shelf OEM LRF modules. For demonstration purposes of an integrated laser range finder module, we used a simple off-the-shelf OEM laser range finder (LRF) with a 100m range, +/-1.5mm accuracy, and 4Hz ranging capability. The LRFs receiver optics were modified to accept 20° of angle, matching the transmitter's FoR. A relatively large (5.0mm) diameter MEMS mirror with +/-10° optical scanning angle was utilized in the demonstration to maintain the small beam divergence of the module. The complete LiDAR prototype can fit into a small volume of <70mm x 60mm x 60mm, and weigh <50g when powered by the UAV's battery. The MEMS mirror based LiDAR system allows for ondemand ranging of points or areas within the FoR without altering the UAV's position. Increasing the LRF ranging frequency and stabilizing the pointing of the laser beam by utilizing the onboard inertial sensors and the camera are additional goals of the next design.
Cella, Monica Angela; Akgul, Deniz; Eskicioglu, Cigdem
2016-03-01
A range of ultrasonication (US) and microwave irradiation (MW) sludge pretreatments were compared to determine the extent of cellular destruction in micro-organisms within secondary sludge and how this cellular destruction translated to anaerobic digestion (AD). Cellular lysis/inactivation was measured using two microbial viability assays, (1) Syto 16® Green and Sytox® Orange counter-assay to discern the integrity of cellular membranes and (2) a fluorescein diacetate assay to understand relative enzymatic activity. A range of MW intensities (2.17-6.48 kJ/g total solids or TS, coinciding temperatures of 60-160 °C) were selected for comparison via viability assays; a range of corresponding US intensities (2.37-27.71 kJ/g TS, coinciding sonication times of 10-60 min at different amplitudes) were also compared to this MW range. The MW pretreatment of thickened waste activated sludge (tWAS) caused fourfold to fivefold greater cell death than non-pretreated and US-pretreated tWAS. The greatest microbial destruction occurred at MW intensities greater than 2.62 kJ/g TS of sludge, after which increased energy input via MW did not appear to cause greater microbial death. In addition, the optimal MW pretreatment (80 °C, 2.62 kJ/g TS) and corresponding US pretreatment (10 min, 60 % amplitude, 2.37 kJ/g TS) were administered to the tWAS of a mixed sludge and fed to anaerobic digesters over sludge retention times (SRTs) of 20, 14, and 7 days to compare effects of feed pretreatment on AD efficiency. The digester utilizing MW-pretreated tWAS (80 °C, 2.62 kJ/g TS) had the greatest fecal coliform removal (73.4 and 69.8 % reduction, respectively), greatest solids removal (44.2 % TS reduction), and highest overall methane production (248.2 L CH4/kg volatile solids) at 14- and 7-day SRTs. However, despite the fourfold to fivefold increases in cell death upon pretreatment, improvements from the digester fed MW-pretreated sludge were marginal (i.e., increases in efficiency of less than 3-10 %) and likely due to a smaller proportion of cells (10-20 %) in the polymeric network and mixed sludge fed to digesters.
2016-10-28
constraints and wire routing issues. • Outside sites have more space, but require outdoor rated equipment (NEMA outdoor rated.. ) and more maintenance...sustainable power, in many different types, sizes and capacities, as follows: • Cogen Plant #1 B1579: 7.2MW gas-fired turbine at Substation “AA...Cogen Plant #2 B1991: (2) 4.6MW gas-fired turbines at “Gillespie” Substation • 300kW fuel cell at Substation “AA” • PPA: 1.015MW solar photovoltaic
Grivas, Christos; Corbari, Costantino; Brambilla, Gilberto; Lagoudakis, Pavlos G
2012-11-15
Fabrication and cw lasing at 798.25 nm is reported for femtosecond (fs) and picosecond (ps) laser-inscribed channel waveguides in Ti:sapphire crystals. Lasing in channels written by fs (ps) pulses was obtained above a threshold of 84 mW (189 mW) with a maximum output power and a slope efficiency of 143 mW (45 mW) and 23.5% (7.1%), respectively. The emission wavelength was tuned over a 170 nm range by using a birefringent filter in an external cavity.
A systems engineering analysis of three-point and four-point wind turbine drivetrain configurations
Guo, Yi; Parsons, Tyler; Dykes, Katherine; ...
2016-08-24
This study compares the impact of drivetrain configuration on the mass and capital cost of a series of wind turbines ranging from 1.5 MW to 5.0 MW power ratings for both land-based and offshore applications. The analysis is performed with a new physics-based drivetrain analysis and sizing tool, Drive Systems Engineering (DriveSE), which is part of the Wind-Plant Integrated System Design & Engineering Model. DriveSE uses physics-based relationships to size all major drivetrain components according to given rotor loads simulated based on International Electrotechnical Commission design load cases. The model's sensitivity to input loads that contain a high degree ofmore » variability was analyzed. Aeroelastic simulations are used to calculate the rotor forces and moments imposed on the drivetrain for each turbine design. DriveSE is then used to size all of the major drivetrain components for each turbine for both three-point and four-point configurations. The simulation results quantify the trade-offs in mass and component costs for the different configurations. On average, a 16.7% decrease in total nacelle mass can be achieved when using a three-point drivetrain configuration, resulting in a 3.5% reduction in turbine capital cost. This analysis is driven by extreme loads and does not consider fatigue. Thus, the effects of configuration choices on reliability and serviceability are not captured. Furthermore, a first order estimate of the sizing, dimensioning and costing of major drivetrain components are made which can be used in larger system studies which consider trade-offs between subsystems such as the rotor, drivetrain and tower.« less
A systems engineering analysis of three-point and four-point wind turbine drivetrain configurations
DOE Office of Scientific and Technical Information (OSTI.GOV)
Guo, Yi; Parsons, Tyler; Dykes, Katherine
This study compares the impact of drivetrain configuration on the mass and capital cost of a series of wind turbines ranging from 1.5 MW to 5.0 MW power ratings for both land-based and offshore applications. The analysis is performed with a new physics-based drivetrain analysis and sizing tool, Drive Systems Engineering (DriveSE), which is part of the Wind-Plant Integrated System Design & Engineering Model. DriveSE uses physics-based relationships to size all major drivetrain components according to given rotor loads simulated based on International Electrotechnical Commission design load cases. The model's sensitivity to input loads that contain a high degree ofmore » variability was analyzed. Aeroelastic simulations are used to calculate the rotor forces and moments imposed on the drivetrain for each turbine design. DriveSE is then used to size all of the major drivetrain components for each turbine for both three-point and four-point configurations. The simulation results quantify the trade-offs in mass and component costs for the different configurations. On average, a 16.7% decrease in total nacelle mass can be achieved when using a three-point drivetrain configuration, resulting in a 3.5% reduction in turbine capital cost. This analysis is driven by extreme loads and does not consider fatigue. Thus, the effects of configuration choices on reliability and serviceability are not captured. Furthermore, a first order estimate of the sizing, dimensioning and costing of major drivetrain components are made which can be used in larger system studies which consider trade-offs between subsystems such as the rotor, drivetrain and tower.« less
Choi, J; Horne, D S; Lucey, J A
2011-07-01
Colloidal calcium phosphate (CCP) plays a key role in the formation and integrity of casein (CN) micelles. However, limited information is available on the molecular weight (M(w)) of CCP. Recently, we theoretically derived the M(w) of CCP and the objectives of this study were to experimentally determine the M(w) of CCP. We used 2 methods to prepare CCP fractions: skim milk was enzymatically digested with either trypsin or a combination of papain and proteinase enzymes to remove most CN. The CN phosphopeptides are resistant to trypsin hydrolysis. Digestion was carried out in a membrane tube that was dialyzed against the same bulk milk used in sample preparation to remove small peptides and to minimize perturbation of CCP. After digestion, the protein contents of the enzyme-treated milks were 0.92 and 0.36% for the trypsin and papain-proteinase treatments, respectively. Size-exclusion chromatography, coupled with multi-angle laser light scattering, was used to separate the CCP-phosphopeptide fraction from the digested mixture. Simulated milk ultrafiltrate was used as a mobile phase during size-exclusion chromatography separation to try to preserve the integrity of CCP. Size-exclusion chromatography peaks, which had higher Ca and P contents than the baseline, were identified as the likely fractions containing the phosphopeptide-stabilized CCP; this peak eluted with retention times of 100 to approximately 110 min for trypsinated samples. The papain-proteinase treatment caused excessive loss of CN that were needed to stabilize CCP, which resulted in no obvious peak that had elevated Ca and P contents. Debye plots at these retention times indicated that the weight-average M(w) for the fraction prepared by trypsin was 17,450 g/mol. Attempts to estimate the M(w) of the phosphopeptides associated with CCP using sodium dodecyl sulfate-PAGE were not successful, as we did not observe any peptide bands in these gels, presumably because of their low concentration in the isolated, unconcentrated fraction. Assuming that 4 CN phosphopeptides stabilized each CCP and if the M(w) of each of these phosphopeptides was about 2,500 g/mol, then the M(w) of CCP would be around 7,450 g/mol. This experimental value was close to the theoretically-derived M(w) of 4,897 and 9,757 g/mol for tetrahedron and bi-pyramid shaped objects, respectively, when using the brushite form of calcium phosphate. Copyright © 2011 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
Sato, Tomohiro O.; Sato, Takao M.; Sagawa, Hideo; Noguchi, Katsuyuki; Saitoh, Naoko; Irie, Hitoshi; Kita, Kazuyuki; Mahani, Mona E.; Zettsu, Koji; Imasu, Ryoichi; Hayashida, Sachiko; Kasai, Yasuko
2018-03-01
We performed a feasibility study of constraining the vertical profile of the tropospheric ozone by using a synergetic retrieval method on multiple spectra, i.e., ultraviolet (UV), thermal infrared (TIR), and microwave (MW) ranges, measured from space. This work provides, for the first time, a quantitative evaluation of the retrieval sensitivity of the tropospheric ozone by adding the MW measurement to the UV and TIR measurements. Two observation points in East Asia (one in an urban area and one in an ocean area) and two observation times (one during summer and one during winter) were assumed. Geometry of line of sight was nadir down-looking for the UV and TIR measurements, and limb sounding for the MW measurement. The retrieval sensitivities of the ozone profiles in the upper troposphere (UT), middle troposphere (MT), and lowermost troposphere (LMT) were estimated using the degree of freedom for signal (DFS), the pressure of maximum sensitivity, reduction rate of error from the a priori error, and the averaging kernel matrix, derived based on the optimal estimation method. The measurement noise levels were assumed to be the same as those for currently available instruments. The weighting functions for the UV, TIR, and MW ranges were calculated using the SCIATRAN radiative transfer model, the Line-By-Line Radiative Transfer Model (LBLRTM), and the Advanced Model for Atmospheric Terahertz Radiation Analysis and Simulation (AMATERASU), respectively. The DFS value was increased by approximately 96, 23, and 30 % by adding the MW measurements to the combination of UV and TIR measurements in the UT, MT, and LMT regions, respectively. The MW measurement increased the DFS value of the LMT ozone; nevertheless, the MW measurement alone has no sensitivity to the LMT ozone. The pressure of maximum sensitivity value for the LMT ozone was also increased by adding the MW measurement. These findings indicate that better information on LMT ozone can be obtained by adding constraints on the UT and MT ozone from the MW measurement. The results of this study are applicable to the upcoming air-quality monitoring missions, APOLLO, GMAP-Asia, and uvSCOPE.
Gómez-Ordóñez, Eva; Jiménez-Escrig, Antonio; Rupérez, Pilar
2012-05-15
Biological properties of polysaccharides from seaweeds are related to their composition and structure. Many factors such as the kind of sugar, type of linkage or sulfate content of algal biopolymers exert an influence in the relationship between structure and function. Besides, the molecular weight (MW) also plays an important role. Thus, a simple, reliable and fast HPSEC method with refractive index detection was developed and optimized for the MW estimation of soluble algal polysaccharides. Chromatogram shape and repeatability of retention time was considerably improved when sodium nitrate was used instead of ultrapure water as mobile phase. Pullulan and dextran standards of different MW were used for method calibration and validation. Also, main polysaccharide standards from brown (alginate, fucoidan, laminaran) and red seaweeds (kappa- and iota-carrageenan) were used for quantification and method precision and accuracy. Relative standard deviation (RSD) of repeatability for retention time, peak areas and inter-day precision was below 0.7%, 2.5% and 2.6%, respectively, which indicated good repeatability and precision. Recoveries (96.3-109.8%) also showed its fairly good accuracy. Regarding linearity, main polysaccharide standards from brown or red seaweeds showed a highly satisfactory correlation coefficient (r>0.999). Moreover, a good sensitivity was shown, with corresponding limits of detection and quantitation in mg/mL of 0.05-0.21 and 0.16-0.31, respectively. The method was applied to the MW estimation of standard algal polysaccharides, as well as to the soluble polysaccharide fractions from the brown seaweed Saccharina latissima and the red Mastocarpus stellatus, respectively. Although distribution of molecular weight was broad, the good repeatability for retention time provided a good precision in MW estimation of polysaccharides. Water- and alkali-soluble fractions from S. latissima ranged from very high (>2400 kDa) to low MW compounds (<6 kDa); this high heterogeneity could be attributable to the complex polysaccharide composition of brown algae. Regarding M. stellatus, sulfated galactans followed a descending order of MW (>1400 kDa to <10 kDa), related to the different solubility of carrageenans in red seaweeds. In summary, the method developed allows for the molecular weight analysis of seaweed polysaccharides with very good precision, accuracy, linearity and sensitivity within a short time. Copyright © 2012 Elsevier B.V. All rights reserved.
Lubner, Meghan G; Hinshaw, J Louis; Andreano, Anita; Sampson, Lisa; Lee, Fred T; Brace, Christopher L
2012-03-01
To evaluate the performance of a gas-cooled, high-powered microwave system. Investigators performed 54 ablations in ex vivo bovine livers using three devices-a single 17-gauge cooled radiofrequency(RF) electrode; a cluster RF electrode; and a single 17-gauge, gas-cooled microwave (MW) antenna-at three time points (n = 6 at 4 minutes, 12 minutes, and 16 minutes). RF power was applied using impedance-based pulsing with maximum 200 W generator output. MW power of 135 W at 2.45 GHz was delivered continuously. An approved in vivo study was performed using 13 domestic pigs. Hepatic ablations were performed using single applicators and the above-mentioned MW and RF generator systems at treatment times of 2 minutes (n = 7 MW, n = 6 RF), 5 minutes (n = 23 MW, n = 8 RF), 7 minutes (n = 11 MW, n = 6 RF), and 10 minutes (n = 7 MW, n = 9 RF). Mean transverse diameter and length of the ablation zones were compared using analysis of variance (ANOVA) with post-hoc t tests and Wilcoxon rank-sum tests. Single ex vivo MW ablations were larger than single RF ablations at all time points (MW mean diameter range 3.5-4.8 cm 4-16 minutes; RF mean diameter range 2.6-3.1 cm 4-16 minutes) (P < .05). There was no difference in mean diameter between cluster RF and MW ablations (RF 3.3-4.4 cm 4-16 minutes; P = .4-.9). In vivo lesion diameters for MW (and RF) were as follows: 2.6 cm ± 0.72 (RF 1.5 cm ± 0.14), 3.6 cm ± 0.89 (RF 2.0 cm ± 0.4), 3.4 cm ± 0.87 (RF 1.8 cm ± 0.23), and 3.8 cm ± 0.74 (RF 2.1 cm ± 0.3) at 2 minutes, 5 minutes, 7 minutes, and 10 minutes (P < .05 all time points). Gas-cooled, high-powered MW ablation allows the generation of large ablation zones in short times. Copyright © 2012 SIR. Published by Elsevier Inc. All rights reserved.
Pan, Chengyi
2014-01-01
The effects of the molecular weight (MW) and charge density (CD) of cationic polyacrylamide (CPAM) on sludge dewatering and moisture evaporation were investigated in this study. Results indicated that in sludge conditioning, the optimum dosages were 10, 6, 6, 4, and 4 mg g−1 CPAM with 5 million MW and 20% CD, 5 million MW and 40% CD, 3 million MW and 40% CD, 8 million MW and 40% CD, and 5 million MW and 60% CD, respectively. The optimum dosage of CPAM was negatively correlated with its CD or MW if the CD or MW of CPAM was above 20% or 5 million. In the centrifugal dewatering of sludge, the moisture content in the conditioned sludge gradually decreased with the extension of centrifugation time, and the economical centrifugal force was 400×g. The moisture evaporation rates of the conditioned sludge were closely related to sludge dewaterability, which was in turn significantly correlated either positively with the solid content of sludge particles that were >2 mm in size or negatively with that of particles measuring 1 mm to 2 mm in diameter. During treatment, sludge moisture content was reduced from 80% to 20% by evaporation, and the moisture evaporation rates were 1.35, 1.49, 1.62, and 2.24 times faster in the sludge conditioned using 4 mg g−1 CPAM with 5 million MW and 60% CD than in the sludge conditioned using 4 mg g−1 CPAM with 8 million MW and 40% CD, 6 mg g−1 CPAM with 5 million MW and 40% CD, 6 mg g−1 CPAM with 3 million MW and 40% CD, and 10 mg g−1 CPAM with 5 million MW and 20% CD, respectively. Hence, the CPAM with 5 million MW and 60% CD was ideal for sludge dewatering. PMID:24878582
Zhou, Jun; Liu, Fenwu; Pan, Chengyi
2014-01-01
The effects of the molecular weight (MW) and charge density (CD) of cationic polyacrylamide (CPAM) on sludge dewatering and moisture evaporation were investigated in this study. Results indicated that in sludge conditioning, the optimum dosages were 10, 6, 6, 4, and 4 mg g(-1) CPAM with 5 million MW and 20% CD, 5 million MW and 40% CD, 3 million MW and 40% CD, 8 million MW and 40% CD, and 5 million MW and 60% CD, respectively. The optimum dosage of CPAM was negatively correlated with its CD or MW if the CD or MW of CPAM was above 20% or 5 million. In the centrifugal dewatering of sludge, the moisture content in the conditioned sludge gradually decreased with the extension of centrifugation time, and the economical centrifugal force was 400×g. The moisture evaporation rates of the conditioned sludge were closely related to sludge dewaterability, which was in turn significantly correlated either positively with the solid content of sludge particles that were >2 mm in size or negatively with that of particles measuring 1 mm to 2 mm in diameter. During treatment, sludge moisture content was reduced from 80% to 20% by evaporation, and the moisture evaporation rates were 1.35, 1.49, 1.62, and 2.24 times faster in the sludge conditioned using 4 mg g(-1) CPAM with 5 million MW and 60% CD than in the sludge conditioned using 4 mg g(-1) CPAM with 8 million MW and 40% CD, 6 mg g(-1) CPAM with 5 million MW and 40% CD, 6 mg g(-1) CPAM with 3 million MW and 40% CD, and 10 mg g(-1) CPAM with 5 million MW and 20% CD, respectively. Hence, the CPAM with 5 million MW and 60% CD was ideal for sludge dewatering.
The benefits of grid-scale storage on Oahu
Ellison, James F.; Rashkin, Lee J.; Serio, Joseph; ...
2017-12-23
The Hawaiian Electric Company intends to procure grid-scale Battery Energy Storage System (“BESS”) capacity. The purpose of this study is to determine whether providing contingency reserve or time-of-day shifting is of more benefit to the Oahu grid, and to better understand the relationship between BESS size and level of benefit. This is an independent study by Sandia, and is not being used to support the regulatory case for BESS capacity by Hawaiian Electric. The study team created a production cost model of the Oahu grid using data primarily from the Hawaiian Electric Company. The proposed BESS supplied contingency reserve inmore » one set of runs and time-of-day shifting in another. Supplying contingency reserve led to larger savings than time-of-day energy shifting. Assuming a renewable reserve and a quick-start reserve, and $15/MMBtu for Low-Sulphur Fuel Oil, the 50-MW/25-MWh, 100-MW/50-MWh, and 150-MW/75-MWh systems supplying contingency reserve provided, respectively, savings of 9.6, 15.6, and 18.3 million USD over system year 2018. Over the range of fuel prices tested, these cost savings were found to be directly proportional to the cost of fuel. Lastly, as the focus is the operational benefit of BESS capacity, the capacity value of the BESS was not included in benefit calculations.« less
The benefits of grid-scale storage on Oahu
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ellison, James F.; Rashkin, Lee J.; Serio, Joseph
The Hawaiian Electric Company intends to procure grid-scale Battery Energy Storage System (“BESS”) capacity. The purpose of this study is to determine whether providing contingency reserve or time-of-day shifting is of more benefit to the Oahu grid, and to better understand the relationship between BESS size and level of benefit. This is an independent study by Sandia, and is not being used to support the regulatory case for BESS capacity by Hawaiian Electric. The study team created a production cost model of the Oahu grid using data primarily from the Hawaiian Electric Company. The proposed BESS supplied contingency reserve inmore » one set of runs and time-of-day shifting in another. Supplying contingency reserve led to larger savings than time-of-day energy shifting. Assuming a renewable reserve and a quick-start reserve, and $15/MMBtu for Low-Sulphur Fuel Oil, the 50-MW/25-MWh, 100-MW/50-MWh, and 150-MW/75-MWh systems supplying contingency reserve provided, respectively, savings of 9.6, 15.6, and 18.3 million USD over system year 2018. Over the range of fuel prices tested, these cost savings were found to be directly proportional to the cost of fuel. Lastly, as the focus is the operational benefit of BESS capacity, the capacity value of the BESS was not included in benefit calculations.« less
THE SPLASH SURVEY: SPECTROSCOPY OF 15 M31 DWARF SPHEROIDAL SATELLITE GALAXIES
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tollerud, Erik J.; Bullock, James S.; Yniguez, Basilio
2012-06-10
We present a resolved star spectroscopic survey of 15 dwarf spheroidal (dSph) satellites of the Andromeda galaxy (M31). We filter foreground contamination from Milky Way (MW) stars, noting that MW substructure is evident in this contaminant sample. We also filter M31 halo field giant stars and identify the remainder as probable dSph members. We then use these members to determine the kinematical properties of the dSphs. For the first time, we confirm that And XVIII, XXI, and XXII show kinematics consistent with bound, dark-matter-dominated galaxies. From the velocity dispersions for the full sample of dSphs we determine masses, which wemore » combine with the size and luminosity of the galaxies to produce mass-size-luminosity scaling relations. With these scalings we determine that the M31 dSphs are fully consistent with the MW dSphs, suggesting that the well-studied MW satellite population provides a fair sample for broader conclusions. We also estimate dark matter halo masses of the satellites and find that there is no sign that the luminosity of these galaxies depends on their dark halo mass, a result consistent with what is seen for MW dwarfs. Two of the M31 dSphs (And XV, XVI) have estimated maximum circular velocities smaller than 12 km s{sup -1} (to 1{sigma}), which likely places them within the lowest-mass dark matter halos known to host stars (along with Booetes I of the MW). Finally, we use the systemic velocities of the M31 satellites to estimate the mass of the M31 halo, obtaining a virial mass consistent with previous results.« less
Woo, Sohee; Lee, Ju Yong; Choi, Woonjin; Moon, Myeong Hee
2016-01-15
In this study, frit inlet asymmetrical flow field-flow fractionation (FlFFF) with multi-angle light scattering (MALS) and differential refractive index (DRI) detection is utilized for size separation, determination of molecular weight (MW), and conformation of ultrahigh-MW (10(7)-10(9) g/mol) cationic polyacrylamides (C-PAMs), a class of water-soluble copolymers based on acrylamide and vinyl-type comonomers with quaternary ammonium cations that are widely used in wastewater treatment and in paper industries. Linear and branched C-PAM copolymers prepared in two different polymerization methods (solution and emulsion) from varying amounts of crosslinking agent and initiator were size fractionated by FlFFF with field-programming. It was found experimentally that the linear copolymers from both polymerization methods were less than 10(8) g/mol in MW with compact, nearly spherical structures, while the branched C-PAM copolymers from the emulsion polymerization showed a significant increase in average MW up to ∼ 10(9)g/mol, which was about 20-fold greater than those from the solution method, and the branched copolymers had more compact or shrunken conformations. While both linear and branched copolymers less than 10(8) g/mol MW were well resolved in an increasing order of MW (normal mode), it was noted that branched copolymers prepared through emulsion polymerization exhibited significantly larger MWs of 10(8-)10(9) g/mol and eluted in the steric/hyperlayer mode, in which the elution order is reversed in an extreme run condition (strong initial field strength followed by a fast field decay during programming). Copyright © 2015 Elsevier B.V. All rights reserved.
Lin, J.; Stein, R.S.
2004-01-01
We argue that key features of thrust earthquake triggering, inhibition, and clustering can be explained by Coulomb stress changes, which we illustrate by a suite of representative models and by detailed examples. Whereas slip on surface-cutting thrust faults drops the stress in most of the adjacent crust, slip on blind thrust faults increases the stress on some nearby zones, particularly above the source fault. Blind thrusts can thus trigger slip on secondary faults at shallow depth and typically produce broadly distributed aftershocks. Short thrust ruptures are particularly efficient at triggering earthquakes of similar size on adjacent thrust faults. We calculate that during a progressive thrust sequence in central California the 1983 Mw = 6.7 Coalinga earthquake brought the subsequent 1983 Mw = 6.0 Nunez and 1985 Mw = 6.0 Kettleman Hills ruptures 10 bars and 1 bar closer to Coulomb failure. The idealized stress change calculations also reconcile the distribution of seismicity accompanying large subduction events, in agreement with findings of prior investigations. Subduction zone ruptures are calculated to promote normal faulting events in the outer rise and to promote thrust-faulting events on the periphery of the seismic rupture and its downdip extension. These features are evident in aftershocks of the 1957 Mw = 9.1 Aleutian and other large subduction earthquakes. We further examine stress changes on the rupture surface imparted by the 1960 Mw = 9.5 and 1995 Mw = 8.1 Chile earthquakes, for which detailed slip models are available. Calculated Coulomb stress increases of 2-20 bars correspond closely to sites of aftershocks and postseismic slip, whereas aftershocks are absent where the stress drops by more than 10 bars. We also argue that slip on major strike-slip systems modulates the stress acting on nearby thrust and strike-slip faults. We calculate that the 1857 Mw = 7.9 Fort Tejon earthquake on the San Andreas fault and subsequent interseismic slip brought the Coalinga fault ???1 bar closer to failure but inhibited failure elsewhere on the Coast Ranges thrust faults. The 1857 earthquake also promoted failure on the White Wolf reverse fault by 8 bars, which ruptured in the 1952 Mw = 7.3 Kern County shock but inhibited slip on the left-lateral Garlock fault, which has not ruptured since 1857. We thus contend that stress transfer exerts a control on the seismicity of thrust faults across a broad spectrum of spatial and temporal scales. Copyright 2004 by the American Geophysical Union.
New York | Midmarket Solar Policies in the United States | Solar Research |
solar within the state. The statewide solar incentives program, NY-Sun, offers loans and grants for non viability. System size limit: Solar: 25 kW for residential; 100 kW for farms; 2 MW for non-residential. PSEG Long Island: 25 kW for residential solar, 2 MW for non-residential solar Aggregate cap: None PSEG Long
Microwave-assisted green synthesis of silver nanostructures.
Nadagouda, Mallikarjuna N; Speth, Thomas F; Varma, Rajender S
2011-07-19
Over the past 25 years, microwave (MW) chemistry has moved from a laboratory curiosity to a well-established synthetic technique used in many academic and industrial laboratories around the world. Although the overwhelming number of MW-assisted applications today are still performed on a laboratory (mL) scale, we expect that this enabling technology may be used on a larger, perhaps even production, scale in conjunction with radio frequency or conventional heating. Microwave chemistry is based on two main principles, the dipolar mechanism and the electrical conductor mechanism. The dipolar mechanism occurs when, under a very high frequency electric field, a polar molecule attempts to follow the field in the same alignment. When this happens, the molecules release enough heat to drive the reaction forward. In the second mechanism, the irradiated sample is an electrical conductor and the charge carriers, ions and electrons, move through the material under the influence of the electric field and lead to polarization within the sample. These induced currents and any electrical resistance will heat the sample. This Account summarizes a microwave (MW)-assisted synthetic approach for producing silver nanostructures. MW heating has received considerable attention as a promising new method for the one-pot synthesis of metallic nanostructures in solutions. Researchers have successfully demonstrated the application of this method in the preparation of silver (Ag), gold (Au), platinum (Pt), and gold-palladium (Au-Pd) nanostructures. MW heating conditions allow not only for the preparation of spherical nanoparticles within a few minutes but also for the formation of single crystalline polygonal plates, sheets, rods, wires, tubes, and dendrites. The morphologies and sizes of the nanostructures can be controlled by changing various experimental parameters, such as the concentration of metallic salt precursors, the surfactant polymers, the chain length of the surfactant polymers, the solvents, and the operation reaction temperature. In general, nanostructures with smaller sizes, narrower size distributions, and a higher degree of crystallization have been obtained more consistently via MW heating than by heating with a conventional oil-bath. The use of microwaves to heat samples is a viable avenue for the greener synthesis of nanomaterials and provides several desirable features such as shorter reaction times, reduced energy consumption, and better product yields.
Bisio, Antonella; Mantegazza, Alessandra; Vecchietti, Davide; Bensi, Donata; Coppa, Alessia; Torri, Giangiacomo; Bertini, Sabrina
2015-03-19
The evaluation of weight average molecular weight (Mw) and molecular weight distribution represents one of the most controversial aspects concerning the characterization of low molecular weight heparins (LMWHs). As the most commonly used method for the measurement of such parameters is high performance size exclusion chromatography (HP-SEC), the soundness of results mainly depends on the appropriate calibration of the chromatographic columns used. With the aim of meeting the requirement of proper Mw standards for LMWHs, in the present work the determination of molecular weight parameters (Mw and Mn) by HP-SEC combined with a triple detector array (TDA) was performed. The HP-SEC/TDA technique permits the evaluation of polymeric samples by exploiting the combined and simultaneous action of three on-line detectors: light scattering detectors (LALLS/RALLS); refractometer and viscometer. Three commercial LMWH samples, enoxaparin, tinzaparin and dalteparin, a γ-ray depolymerized heparin (γ-Hep) and its chromatographic fractions, and a synthetic pentasaccharide were analysed by HP-SEC/TDA. The same samples were analysed also with a conventional HP-SEC method employing refractive index (RI) and UV detectors and two different chromatographic column set, silica gel and polymeric gel columns. In both chromatographic systems, two different calibration curves were built up by using (i) γ-Hep chromatographic fractions and the corresponding Mw parameters obtained via HP-SEC/TDA; (ii) the whole γ-Hep preparation with broad Mw dispersion and the corresponding cumulative distribution function calculated via HP-SEC/TDA. In addition, also a chromatographic column calibration according to European Pharmacopoeia indication was built up. By comparing all the obtained results, some important differences among Mw and size distribution values of the three LMWHs were found with the five different calibration methods and with HP-SEC/TDA method. In particular, the detection of the lower molecular weight components turned out to be the most critical aspect. Whereas HP-SEC/TDA may underestimate species under 2 KDa when present in low concentration, other methods appeared to emphasize their content.
Li, Jianlin; Armstrong, Beth L; Daniel, Claus; Kiggans, Jim; Wood, David L
2013-09-01
Addition of polyethyleneimine (PEI) to aqueous LiFePO4 nanoparticle suspensions improves stability and reduces agglomerate size, which is beneficial to lithium-ion battery cathode manufacturing. This research examines the effect of both PEI concentration and molecular weight (MW) on dispersing LiFePO4 and Super P C45 in multicomponent aqueous suspensions. It is demonstrated that the optimal conditions for obtaining stable suspensions with minimal agglomerate size are 1.5 wt% PEI with MW=2000 g mol(-1) and 5.0 wt% PEI with MW=10,000 g mol(-1) for LiFePO4 and Super P C45, respectively. The mixing sequence also affects rheological properties of these suspensions. It is found that dispersing the LiFePO4 and Super P C45 separately yielded suspensions with superior properties (Newtonian rheological behavior, smaller agglomerate size, improved settling, etc.). In particular, dispersing the LiFePO4 prior to the Super P C45 when making the final multicomponent suspension is found to be beneficial, which was evidenced by higher half-cell discharge capacity. Copyright © 2013 Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
Hara, T.
2012-12-01
Hara (2007. EPS, 59, 227 - 231) developed a method to determine earthquake magnitudes using durations of high frequency energy radiation and displacement amplitudes of tele-seismic events, and showed that it was applicable to huge events such as the 2004 Sumatra earthquake (Mw 9.0 after the Global CMT catalog. In the following the moment magnitude are from their estimates). Since Hara (2007) developed this method, we have been applying it to large shallow events, and confirmed its effectiveness. The results for several events are available at the web site of our institute (http://iisee.kenken.go.jp/quakes.htm). Also, Hara (2011. EPS, 63, 525-528) applied this method to the 2011 Off the Pacific Coast of Tohoku Earthquake (Mw 9.1), and showed that it worked well. In these applications, we used only waveform data recorded in the tele-seismic distance range (30 - 85 degrees). In order to have a magnitude estimate faster, it is necessary to analyze regional distance range data. In this study, we applied the method of Hara (2007) to waveform data recorded in the regional distance range (8 - 30 degrees) to investigate its applicability. We slightly modified the method by changing durations of times series used for analysis considering arrivals of high amplitude Rayleigh waves. We selected the six recent huge (their moment magnitude are equal to or greater than 8.5) earthquakes; they are the December 26, 2004 Sumatra (Mw 9.0), the March 28, 2005 Northern Sumatra (Mw 8,6), the September 12, 2007 Southern Sumatra (Mw 8.5), the February 27, 2010 Chile (Mw 8.8), the March 11, 2011 off the Pacific Coast of Tohoku (Mw 9.1), the April 11, 2012 off West Coast of Northern Sumatra (Mw 8.6). We retrieved BHZ channel waveform data from IRIS DMC. For the 2004 Sumatra and 2010 Chile earthquakes, only a few waveform data are available. The estimated magnitudes are 9.16, 8.66, 8.53, 8.83, 9.15, and 8.70, respectively. Also, the estimated high frequency energy radiation durations are consistent with the centroid time shifts of the Global CMT catalog. These preliminary results suggest that the method of Hara (2007) is applicable to waveform data recorded in the regional distance range. We plan to apply this method to smaller events to investigate a possible systematic deviation from analyses of tele-seismic records.
Fractionation of aquatic natural organic matter upon sorption to goethite and kaolinite
Meier, M.; Namjesnik-Dejanovic, K.; Maurice, P.A.; Chin, Y.-P.; Aiken, G.R.
1999-01-01
Natural organic matter (NOM) consists of a complex mixture of organic molecules; previous studies have suggested that preferential sorption of higher molecular weight, more hydrophobic, and more aromatic components may lead to fractionation of the NOM pool upon passage through porous media. Our work expands upon previous studies by quantifying the change in solution-phase weight average molecular weight (M(w)) upon sorption of bulk (rather than isolated) surface water NOM from the Suwannee River (SR) and the Great Dismal Swamp (GDS) to goethite and kaolinite at different sorption densities and at pH 4, 22??C. High pressure size exclusion chromatography (HPSEC) was used to quantify changes in M(w) upon sorption, and molar absorptivities at ?? = 280 nm were used to approximate changes in solution NOM aromaticity. Two SR water samples were used, with M(w) = 2320 and 2200 Da; a single GDS sample was used, with M(w) = 1890 Da. The SR NOM was slightly more hydrophobic and aromatic. These differences were reflected in greater sorption of SR NOM than GDS NOM. Both surface water NOMs showed a much greater affinity for goethite than for kaolinite. HPSEC analysis of the NOM remaining in solution after 24 h reaction time with geothite revealed that the largest changes in solution phase M(w)s (decreases by 900-1700 Da) occurred at relatively low equilibrium sorbate concentrations (approximately 5-20 mg C 1-1); the decrease in solution M(w) suggested that reactive surface sites were occupied disproportionately by large and intermediate size NOM moieties. At higher equilibrium NOM concentrations (>20 mg C 1-1), as percent adsorption decreased, M(w) in solution was similar to original samples. A smaller decrease in solution NOM M(w) (300-500 Da at 10-20 mg C 1-1 ~ 100 Da at > 20 mg) also occurred upon sorption to kaolinite. Overall, our results showed that factors (as related to NOM composition, clay mineral surface properties, and position along the sorption isotherm) which promote a higher percent sorption lead to the most pronounced decreases in solution M(w).
Repeating Earthquakes Following an Mw 4.4 Earthquake Near Luther, Oklahoma
NASA Astrophysics Data System (ADS)
Clements, T.; Keranen, K. M.; Savage, H. M.
2015-12-01
An Mw 4.4 earthquake on April 16, 2013 near Luther, OK was one of the earliest M4+ earthquakes in central Oklahoma, following the Prague sequence in 2011. A network of four local broadband seismometers deployed within a day of the Mw 4.4 event, along with six Oklahoma netquake stations, recorded more than 500 aftershocks in the two weeks following the Luther earthquake. Here we use HypoDD (Waldhauser & Ellsworth, 2000) and waveform cross-correlation to obtain precise aftershock locations. The location uncertainty, calculated using the SVD method in HypoDD, is ~15 m horizontally and ~ 35 m vertically. The earthquakes define a near vertical, NE-SW striking fault plane. Events occur at depths from 2 km to 3.5 km within the granitic basement, with a small fraction of events shallower, near the sediment-basement interface. Earthquakes occur within a zone of ~200 meters thickness on either side of the best-fitting fault surface. We use an equivalency class algorithm to identity clusters of repeating events, defined as event pairs with median three-component correlation > 0.97 across common stations (Aster & Scott, 1993). Repeating events occur as doublets of only two events in over 50% of cases; overall, 41% of earthquakes recorded occur as repeating events. The recurrence intervals for the repeating events range from minutes to days, with common recurrence intervals of less than two minutes. While clusters occur in tight dimensions, commonly of 80 m x 200 m, aftershocks occur in 3 distinct ~2km x 2km-sized patches along the fault. Our analysis suggests that with rapidly deployed local arrays, the plethora of ~Mw 4 earthquakes occurring in Oklahoma and Southern Kansas can be used to investigate the earthquake rupture process and the role of damage zones.
Diffusion of macromolecules through sclera.
Miao, Heng; Wu, Bi-Dong; Tao, Yong; Li, Xiao-Xin
2013-02-01
To quantify the in vitro permeability coefficient over different topographical locations of porcine sclera to macromolecules with different molecular weight. Fresh equatorial and posterior superotemporal porcine sclera was mounted in a two-chamber diffusion apparatus, and its permeability to fluorescein isothiocyanate (FITC)-conjugated dextrans ranging in molecular weight from 40 kDa to 150 kDa was determined by fluorescence spectrophotometry. The sclera was processed as frozen sections and viewed with a fluorescence microscope. The thickness of the area and the thickness that macromolecules enriched in the surface of sclera were measured. The permeability coefficient (Pc) of porcine sclera to macromolecules was significantly higher (40 kDa, p = 0.028; 70 kDa, p = 0.033; 150 kDa, p = 0.007) in equatorial region than posterior, which could be attributed to the significant difference of thickness (p < 0.001, Kruskal-Wallis) between them. Moreover, linear regression indicated a significant negative relationship (40 kDa, p < 0.001; 70 kDa, p = 0.015; 150 kDa, p < 0.001) between scleral permeability coefficient and thickness. Also, Pc declined significantly with increasing molecular weight (MW, p < 0.001, Kruskal-Wallis). The area that the macromolecules enriched in the scleral surface was thicker for those with larger MW (p < 0.001, Kruskal-Wallis). The maximum MW and size for equatorial and posterior superotemporal scleral tissue were 185.01 KDa and 180.42 KDa, 9.92 nm and 9.67 nm, respectively. The permeability coefficient of porcine sclera has a significant negative relationship with scleral thickness and MW of macromolecules. Larger macromolecules are more likely to accumulate in scleral surface. The difference between topographical locations may have pharmacokinetic implications when considering transscleral diffusion of macromolecules. © 2012 The Authors. Acta Ophthalmologica © 2012 Acta Ophthalmologica Scandinavica Foundation.
DUST COAGULATION IN THE VICINITY OF A GAP-OPENING JUPITER-MASS PLANET
DOE Office of Scientific and Technical Information (OSTI.GOV)
Carballido, Augusto; Matthews, Lorin S.; Hyde, Truell W., E-mail: Augusto_Carballido@baylor.edu
We analyze the coagulation of dust in and around a gap opened by a Jupiter-mass planet. To this end, we carry out a high-resolution magnetohydrodynamic (MHD) simulation of the gap environment, which is turbulent due to the magnetorotational instability. From the MHD simulation, we obtain values of the gas velocities, densities, and turbulent stresses (a) close to the gap edge, (b) in one of the two gas streams that accrete onto the planet, (c) inside the low-density gap, and (d) outside the gap. The MHD values are then input into a Monte Carlo dust-coagulation algorithm which models grain sticking andmore » compaction. We also introduce a simple implementation for bouncing, for comparison purposes. We consider two dust populations for each region: one whose initial size distribution is monodisperse, with monomer radius equal to 1 μ m, and another one whose initial size distribution follows the Mathis–Rumpl–Nordsieck distribution for interstellar dust grains, with an initial range of monomer radii between 0.5 and 10 μ m. Without bouncing, our Monte Carlo calculations show steady growth of dust aggregates in all regions, and the mass-weighted (m-w) average porosity of the initially monodisperse population reaches extremely high final values of 98%. The final m-w porosities in all other cases without bouncing range between 30% and 82%. The efficiency of compaction is due to high turbulent relative speeds between dust particles. When bouncing is introduced, growth is slowed down in the planetary wake and inside the gap. Future studies will need to explore the effect of different planet masses and electric charge on grains.« less
Energetic and entropic components of the Tolman length for mW and TIP4P/2005 water nanodroplets
NASA Astrophysics Data System (ADS)
Joswiak, Mark N.; Do, Ryan; Doherty, Michael F.; Peters, Baron
2016-11-01
The surface free energy of a droplet is approximately γ ( R ) = γ ( ∞ ) ( 1 - 2 δ / R ) , with R being the droplet radius and δ being the Tolman length. Here we use the mitosis method to compute δ = - 0.56 ± 0.1 Å at 300 K for mW water, indicating that γ ( R ) increases as the droplet size decreases. The computed Tolman length agrees quite well with a previous study of TIP4P/2005 water. We also decompose the size-dependent surface free energy into energetic and entropic contributions for the mW and TIP4P/2005 force fields. Despite having similar Tolman lengths, the energy-entropy decompositions are very different for the two force fields. We discuss critical assumptions which lead to these findings and their relation to experiments on the nucleation of water droplets. We also discuss surface broken bonds and structural correlations as possible explanations for the energetic and entropic contributions.
MOND simulation suggests an origin for some peculiarities in the Local Group
NASA Astrophysics Data System (ADS)
Bílek, M.; Thies, I.; Kroupa, P.; Famaey, B.
2018-06-01
Context. The Milky Way (MW) and Andromeda (M 31) galaxies possess rotating planes of satellites. The formation of these planes has not been explained satisfactorily so far. It has been suggested that the MW and M 31 satellites are ancient tidal dwarf galaxies; this might explain their configuration. This suggestion gained support by an analytic backward-calculation of the relative MW-M 31 orbit in the MOND modified dynamics paradigm. The result implied that the galaxies experienced a close flyby 7-11 Gyr ago. Aims: Here we explore the Local Group history in MOND in more detail using a simplified first-ever self-consistent simulation. We describe the features induced by the encounter in the simulation and identify possible real counterparts of these features. Methods: The initial conditions were set to eventually roughly reproduce the observed MW and M 31 masses, effective radii, separation, relative velocity, and disk inclinations. We used the publicly available adaptive-mesh-refinement code Phantom of RAMSES. Results: Matter was transferred from the MW to M 31 along a tidal tail in the simulation. The encounter induced the formation of several structures resembling the peculiarities of the Local Group. Most notably are that 1) a rotating planar structure formed around M 31 from the transferred material. It had a size similar to the observed satellite plane and was oriented edge-on to the simulated MW, just as the real plane. 2) The same structure also resembled the tidal features observed around M 31 by its size and morphology. 3) A warp in the MW developed with an amplitude and orientation similar to that observed. 4) A cloud of particles formed around the simulated MW, with the extent of the actual MW satellite system. The encounter did not end by merging in a Hubble time. The simulated stellar disks also thickened as a result of the encounter. Conclusions: The simulation demonstrated that MOND might explain many peculiarities of the Local Group; this needs to be verified with additional simulations. The simulation moreover showed that tidal features observed in galaxies, usually interpreted as merger remnants, could have been formed by matter exchange during non-merging galactic flybys in some cases. Three movies are available at http://www.aanda.org
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fox, Elise B.; Edwards, Thomas B.
In 2015, a program was initiated to carefully track and monitor the growth of the solar industry in SC. Prior to then, little information was available on the costs associated with distributed photovoltaic (PV) installations in the Southeastern US. For this report, data were collected from businesses on the number of hires they had at the end of 2014 and compared with data for 2015 and June 2016. It was found that the percentage of installers within the state who serve the residential sector increased to 82% from 67%. During the same time period, the average size of initiated installationsmore » for residential, commercial, and utility scale installations all trended upwards. Where residential installations were typically 5 kW-DC in 2014, they were typically 10 kW-DC by late 2015 and in mid-2016. For commercial installations, the average size grew from 84 kW-DC in 2014 to between 136-236 kW-DC in 2015 and then 188-248 kWDC in mid-2016. An exception was seen in utility scale installations where a 2.3 MW-DC system was common in 2014, the size grew to be 5-15 MW-DC in late 2015. The average size dropped 3.1-4.4 MWDC in mid-June 2016, though individual averages up to 20 MW-DC were reported.« less
Probing the size of proteins with glass nanopores
NASA Astrophysics Data System (ADS)
Steinbock, L. J.; Krishnan, S.; Bulushev, R. D.; Borgeaud, S.; Blokesch, M.; Feletti, L.; Radenovic, A.
2014-11-01
Single molecule studies using nanopores have gained attention due to the ability to sense single molecules in aqueous solution without the need to label them. In this study, short DNA molecules and proteins were detected with glass nanopores, whose sensitivity was enhanced by electron reshaping which decreased the nanopore diameter and created geometries with a reduced sensing length. Further, proteins having molecular weights (MW) ranging from 12 kDa to 480 kDa were detected, which showed that their corresponding current peak amplitude changes according to their MW. In the case of the 12 kDa ComEA protein, its DNA-binding properties to an 800 bp long DNA molecule was investigated. Moreover, the influence of the pH on the charge of the protein was demonstrated by showing a change in the translocation direction. This work emphasizes the wide spectrum of detectable molecules using nanopores from glass nanocapillaries, which stand out because of their inexpensive, lithography-free, and rapid manufacturing process.Single molecule studies using nanopores have gained attention due to the ability to sense single molecules in aqueous solution without the need to label them. In this study, short DNA molecules and proteins were detected with glass nanopores, whose sensitivity was enhanced by electron reshaping which decreased the nanopore diameter and created geometries with a reduced sensing length. Further, proteins having molecular weights (MW) ranging from 12 kDa to 480 kDa were detected, which showed that their corresponding current peak amplitude changes according to their MW. In the case of the 12 kDa ComEA protein, its DNA-binding properties to an 800 bp long DNA molecule was investigated. Moreover, the influence of the pH on the charge of the protein was demonstrated by showing a change in the translocation direction. This work emphasizes the wide spectrum of detectable molecules using nanopores from glass nanocapillaries, which stand out because of their inexpensive, lithography-free, and rapid manufacturing process. Electronic supplementary information (ESI) available. See DOI: 10.1039/c4nr05001k
Chiesa, E; Dorati, R; Modena, T; Conti, B; Genta, I
2018-01-30
Design of Experiment-assisted evaluation of critical process (total flow rate, TFR, flow rate ratio, FRR) and formulation (polymer concentration and structure, drug:polymer ratio) variables in a novel microfluidics-based device, a staggered herringbone micromixer (SHM), for poly(lactic-co-glycolic acid) copolymer (PLGA) nanoparticles (NPs) manufacturing was performed in order to systematically evaluate and mathematically describe their effects on NPs sizes and drug encapsulation; a small hydrophilic moiety, N-acetylcysteine, was chosen as challenging model drug. SHM-assisted nanoprecipitation method consistently yielded NPs with tailor made sizes (in the range of 100-900 nm) and polydispersity index range from 0.061 to 0.286. Significant effects on NPs sizes were highlighted for TFR and FRR: increasing TFR (from 5 to 15 mL/min) and decreasing FRR (from 1:1 to 1:5 v/v, acetonitrile: buffer) NPs with mean diameter <200 nm were obtained. SHM technique allowed for flexible, application-specific tuning of PLGA NPs size using organic solvents with relatively low toxicity (acetone, acetonitrile), varying aqueous phase composition (Tris buffer vs PVA aqueous solution) and PLGA characteristics (Mw ranging from 25-90 kDa, capped or un-capped PLGA, different lactide:glycolide molar ratio). A very satisfactory N-Ac encapsulation efficiency (more than 67%) and a prolonged release (by 168 h) were achieved. Copyright © 2017 Elsevier B.V. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Liese, Eric; Zitney, Stephen E.
A multi-stage centrifugal compressor model is presented with emphasis on analyzing use of an exit flow coefficient vs. an inlet flow coefficient performance parameter to predict off-design conditions in the critical region of a supercritical carbon dioxide (CO 2) power cycle. A description of the performance parameters is given along with their implementation in a design model (number of stages, basic sizing, etc.) and a dynamic model (for use in transient studies). A design case is shown for two compressors, a bypass compressor and a main compressor, as defined in a process simulation of a 10 megawatt (MW) supercritical COmore » 2 recompression Brayton cycle. Simulation results are presented for a simple open cycle and closed cycle process with changes to the inlet temperature of the main compressor which operates near the CO 2 critical point. Results showed some difference in results using the exit vs. inlet flow coefficient correction, however, it was not significant for the range of conditions examined. Here, this paper also serves as a reference for future works, including a full process simulation of the 10 MW recompression Brayton cycle.« less
Re-Evaluating Geothermal Potential with GIS Methods and New Data: Williston Basin, North Dakota
NASA Astrophysics Data System (ADS)
Crowell, A. M.; Gosnold, W. D.; UND Geothermal Laboratory
2011-12-01
The University of North Dakota Geothermal Laboratory is working on the National Geothermal Data Aggregation project in conjunction with Southern Methodist University (SMU) and other partners, and funded by the Department of Energy to collect data for exploration and utilization of resources for geothermal power production. We have examined 10,951 wells in the Williston Basin to determine accurate methods for estimating power extraction potential in a sedimentary basin. The calculations we used involved defining the area of wells within designated ranges and calculating the geothermal fluid reservoir volume using porosity data from the North Dakota Geological Survey Wilson M. Laird Core Library. We defined the parameters for our calculations as: bottom-hole temperature (BHT), formation thickness data, surface area of the polygon around wells within the temperature range, and porosity data. The wells in each formation with a BHT over 90°C were imported into ArcGIS, buffered to 1.6 kilometers from centroid, and outlined with a polygon feature to define the surface area. We then included average formation thickness to determine an approximate volume for ten water and rock reservoirs. In calculating this available energy the following three assumptions were made; that 1/1000 of the water volume is available to use per year, that the temperature is lowered to 50°C during electrical power production, and that the efficiency of the binary power plant utilized is 14%. The estimated recoverable energy in the volume of rock containing geothermal fluids by temperature range is as follows: 1.32 x 108 MW for 90°-100° C, 1.92 x 108 MW for 100°-110° C, 2.15 x 108 MW for 110°-120° C, 2.4 x 108 MW for 120°-130° C, 1.4 x 108 MW for 130°-140° C, 4.95 x 107 MW for 140°-150° C, and 3.67 x 107 MW for 150° C and up.
Development and Production of a 201 MHz, 5.0 MW Peak Power Klystron
DOE Office of Scientific and Technical Information (OSTI.GOV)
Aymar, Galen; Eisen, Edward; Stockwell, Brad
2016-01-01
Communications & Power Industries LLC has designed and manufactured the VKP-8201A, a high peak power, high gain, VHF band klystron. The klystron operates at 201.25 MHz, with 5.0 MW peak output power, 34 kW average output power, and a gain of 36 dB. The klystron is designed to operate between 1.0 MW and 4.5 MW in the linear range of the transfer curve. The klystron utilizes a unique magnetic field which enables the use of a proven electron gun design with a larger electron beam requirement. Experimental and predicted performance data are compared.
Green high-power tunable external-cavity GaN diode laser at 515 nm.
Chi, Mingjun; Jensen, Ole Bjarlin; Petersen, Paul Michael
2016-09-15
A 480 mW green tunable diode laser system is demonstrated for the first time to our knowledge. The laser system is based on a GaN broad-area diode laser and Littrow external-cavity feedback. The green laser system is operated in two modes by switching the polarization direction of the laser beam incident on the grating. When the laser beam is p-polarized, an output power of 50 mW with a tunable range of 9.2 nm is achieved. When the laser beam is s-polarized, an output power of 480 mW with a tunable range of 2.1 nm is obtained. This constitutes the highest output power from a tunable green diode laser system.
Trontz, Adam; Cheng, Baokai; Zeng, Shixuan; Xiao, Hai; Dong, Junhang
2015-01-01
Metal-ceramic coaxial cable Fabry-Pérot interferometric (MCCC-FPI) sensors have been developed using a stainless steel tube and a stainless steel wire as the outer and inner conductors, respectively; a tubular α-alumina insulator; and a pair of air gaps created in the insulator along the cable to serve as weak reflectors for the transmitting microwave (MW) signal. The MCCC-FPI sensors have been demonstrated for high temperature measurements using MW signals in a frequency range of 2–8 GHz. The temperature measurement is achieved by monitoring the frequency shift (Δƒ) of the MW interferogram reflected from the pair of weak reflectors. The MW sensor exhibited excellent linear dependence of Δƒ on temperature; small measurement deviations (±2.7%); and fast response in a tested range of 200–500 °C. The MCCC has the potential for further developing multipoint FPI sensors in a single-cable to achieve in situ and continuous measurement of spatially distributed temperature in harsh environments. PMID:26404280
Trontz, Adam; Cheng, Baokai; Zeng, Shixuan; Xiao, Hai; Dong, Junhang
2015-09-25
Metal-ceramic coaxial cable Fabry-Pérot interferometric (MCCC-FPI) sensors have been developed using a stainless steel tube and a stainless steel wire as the outer and inner conductors, respectively; a tubular α-alumina insulator; and a pair of air gaps created in the insulator along the cable to serve as weak reflectors for the transmitting microwave (MW) signal. The MCCC-FPI sensors have been demonstrated for high temperature measurements using MW signals in a frequency range of 2-8 GHz. The temperature measurement is achieved by monitoring the frequency shift (Δƒ) of the MW interferogram reflected from the pair of weak reflectors. The MW sensor exhibited excellent linear dependence of Δƒ on temperature; small measurement deviations (±2.7%); and fast response in a tested range of 200-500 °C. The MCCC has the potential for further developing multipoint FPI sensors in a single-cable to achieve in situ and continuous measurement of spatially distributed temperature in harsh environments.
NASA Astrophysics Data System (ADS)
Gulen, L.; Demirbağ, E.; Cagatay, M. N.; Yıldırım, E.; Yalamaz, B.
2015-12-01
Seismic reflection studies have been carried out in the Sapanca Lake to delineate the geometry of the North Anatolian Fault. A total of 28 N-S and 2 E-W trending seismic profiles were obtained. The interpretation of seismic reflection profiles have revealed that the North Anatolian Fault Zone exhibits a pull-apart fault geometry within the Sapanca Lake and the active fault segments have been mapped. A bathymetry map of the Sapanca Lake is also generated and the maximum depth is determined to be 54 m. A systematic study of the sedimentological, physical and geochemical properties of three up to 75.7 cm long water-sediment interface cores located along depth transects ranging from 43 to 5.1.5 m water depth. The cores were analyzed using Geotek Multi Sensor Core Logger (MSCL) for physical properties, laser particle size analyzer for granulometry, TOC Analyzer for Total Organic Organic (TOC) and Total Inorganic carbon (TIC) analysis and Itrax-XRF Core Scanner for elemental analysis and digital X-RAY Radiography. The Sapanca Lake earthquake records are characterized by seismo-turbidites consisting of grey or dark grey coarse to fine sand and silty mud with a sharp basal and transitional upper boundaries. The units commonly show normal size grading with their basal parts showing high density and magnetic susceptibility and enrichment in one or more of elements, such as Si, Ca, Tİ, K, Rb, Zr and Fe, indicative of coarse detrial input. Based on radionuclide and radiocarbon analyses the seismo-turbidites are correlated with the 1999 İzmit and Düzce (Mw=7.4 and 7.2), 1967 Mudurnu (Mw= 6.8), and 1957 Abant (Mw= 7.1) Earthquakes. Additionally a prominent Cs137 peak was found in the Sapanca Lake sediment cores at a depth of 12 cm. indicating that a radioactive fallout occurred in the region as a result of the 1986 Chernobyl Nuclear Power Plant accident in Ukraine.
Chilean megathrust earthquake recurrence linked to frictional contrast at depth
NASA Astrophysics Data System (ADS)
Moreno, M.; Li, S.; Melnick, D.; Bedford, J. R.; Baez, J. C.; Motagh, M.; Metzger, S.; Vajedian, S.; Sippl, C.; Gutknecht, B. D.; Contreras-Reyes, E.; Deng, Z.; Tassara, A.; Oncken, O.
2018-04-01
Fundamental processes of the seismic cycle in subduction zones, including those controlling the recurrence and size of great earthquakes, are still poorly understood. Here, by studying the 2016 earthquake in southern Chile—the first large event within the rupture zone of the 1960 earthquake (moment magnitude (Mw) = 9.5)—we show that the frictional zonation of the plate interface fault at depth mechanically controls the timing of more frequent, moderate-size deep events (Mw < 8) and less frequent, tsunamigenic great shallow earthquakes (Mw > 8.5). We model the evolution of stress build-up for a seismogenic zone with heterogeneous friction to examine the link between the 2016 and 1960 earthquakes. Our results suggest that the deeper segments of the seismogenic megathrust are weaker and interseismically loaded by a more strongly coupled, shallower asperity. Deeper segments fail earlier ( 60 yr recurrence), producing moderate-size events that precede the failure of the shallower region, which fails in a great earthquake (recurrence >110 yr). We interpret the contrasting frictional strength and lag time between deeper and shallower earthquakes to be controlled by variations in pore fluid pressure. Our integrated analysis strengthens understanding of the mechanics and timing of great megathrust earthquakes, and therefore could aid in the seismic hazard assessment of other subduction zones.
Eswari, Parvathy; Kavitha, S; Kaliappan, S; Yeom, Ick-Tae; Banu, J Rajesh
2016-07-01
The aim of this study was to increase the sludge disintegration and reduce the cost of microwave (MW) pretreatment. Thermodynamic analysis of MW hydrolysis revealed the best fit with a first-order kinetic model at a specific energy of 18,600 kJ/kg total solids (TS). Combining H2O2 with MW resulted in a significant increment in solubilization from 30 to 50 % at 18,600 kJ/kg TS. The pH of H2O2-assisted MW-pretreated sludge (MW + H2O2) was in the alkaline range (pH 9-10), and it made the sludge unfavorable for subsequent anaerobic digestion and inhibits methane production. In order to nullify the alkaline effect caused by the MW + H2O2 combination, the addition of acid was considered for pH adjustment. H2O2-assisted MW-pretreated sludge in acidic conditions (MW + H2O2 + acid) showed a maximum methane production of 323 mL/g volatile solids (VS) than others during anaerobic biodegradability. A cost analysis of this study reveals that MW + H2O2 + acid was the most economical method with a net profit of 59.90 €/t of sludge.
McKenzie, Erica R; Young, Thomas M
2013-01-01
Size exclusion chromatography (SEC), which separates molecules based on molecular volume, can be coupled with online inductively coupled plasma mass spectrometry (ICP-MS) to explore size-dependent metal-natural organic matter (NOM) complexation. To make effective use of this analytical dual detector system, the operator should be mindful of quality control measures. Al, Cr, Fe, Se, and Sn all exhibited columnless attenuation, which indicated unintended interactions with system components. Based on signal-to-noise ratio and peak reproducibility between duplicate analyses of environmental samples, consistent peak time and height were observed for Mg, Cl, Mn, Cu, Br, and Pb. Al, V, Fe, Co, Ni, Zn, Se, Cd, Sn, and Sb were less consistent overall, but produced consistent measurements in select samples. Ultrafiltering and centrifuging produced similar peak distributions, but glass fiber filtration produced more high molecular weight (MW) peaks. Storage in glass also produced more high MW peaks than did plastic bottles.
Mucoadhesive nanoparticles made of thiolated quaternary chitosan crosslinked with hyaluronan.
Zambito, Ylenia; Felice, Francesca; Fabiano, Angela; Di Stefano, Rossella; Di Colo, Giacomo
2013-01-30
Mucoadhesive polymeric nanoparticles intended for drug transport across the gastrointestinal mucosa were prepared from quaternary ammonium-chitosan conjugates synthesised from reduced-MW chitosan (32 kDa). Conjugates contained pendant moieties of 2-4 adjacent diethyl-dimethylene-ammonium groups substituted on repeating units (26-55%). Conjugates were thiolated via amide bonds with thioglycolic acid to yield products with thiol content in the 35-87 μmol/g range. Nanoparticles with mean size in the 270-370 nm range and positive zeta-potential (+3.7 to +12.5 mV) resulted from ionotropic gelation of the thiolated conjugates with de-polymerised hyaluronic acid (470 kDa). The nanoparticles were fairly stable in size and thiol content and showed a significant mucoadhesivity, matching and even exceeding that of the constituent polymers. Nanoparticles were internalised by endothelial progenitor cells in direct relation to their surface charge intensity. Nanoparticle uptake significantly improved cell viability and resistance to oxidation. The lyophilised nanoparticles were re-dispersible and could make a manageable formulation for oral use. Copyright © 2012 Elsevier Ltd. All rights reserved.
Microwave Enhancement of Autocatalytic Growth of Nanometals.
Ashley, Bridgett; Vakil, Parth N; Lynch, Brian B; Dyer, Christopher M; Tracy, Joseph B; Owens, Jeffery; Strouse, Geoffrey F
2017-10-24
The desire for designing efficient synthetic methods that lead to industrially important nanomaterials has led a desire to more fully understand the mechanism of growth and how modern synthetic techniques can be employed. Microwave (MW) synthesis is one such technique that has attracted attention as a green, sustainable method. The reports of enhancement of formation rates and improved quality for MW driven reactions are intriguing, but the lack of understanding of the reaction mechanism and how coupling to the MW field leads to these observations is concerning. In this manuscript, the growth of a metal nanoparticles (NPs) in a microwave cavity is spectroscopically analyzed and compared with the classical autocatalytic method of NP growth to elucidate the underpinnings for the observed enhanced growth behavior for metal NPs prepared in a MW field. The study illustrates that microwave synthesis of nickel and gold NPs below saturation conditions follows the Finke-Watzky mechanism of nucleation and growth. The enhancement of the reaction arises from the size-dependent increase in MW absorption cross section for the metal NPs. For Ni, the presence of oxides is considered via theoretical computations and compared to dielectric measurements of isolated nickel NPs. The study definitively shows that MW growth can be modeled by an autocatalytic mechanism that directly leads to the observed enhanced rates and improved quality widely reported in the nanomaterial community when MW irradiation is employed.
Variable-period surface-wave magnitudes: A rapid and robust estimator of seismic moments
Bonner, J.; Herrmann, R.; Benz, H.
2010-01-01
We demonstrate that surface-wave magnitudes (Ms), measured at local, regional, and teleseismic distances, can be used as a rapid and robust estimator of seismic moment magnitude (Mw). We used the Russell (2006) variable-period surface-wave magnitude formula, henceforth called Ms(VMAX), to estimate the Ms for 165 North American events with 3.2
PROPERTIES OF DUST GRAINS PROBED WITH EXTINCTION CURVES
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nozawa, Takaya; Fukugita, Masataka
Modern data of the extinction curve from the ultraviolet to the near-infrared are revisited to study properties of dust grains in the Milky Way (MW) and the Small Magellanic Cloud (SMC). We confirm that the graphite-silicate mixture of grains yields the observed extinction curve with the simple power-law distribution of the grain size but with a cutoff at some maximal size: the parameters are tightly constrained to be q = 3.5 {+-} 0.2 for the size distribution a {sup -q} and the maximum radius a{sub max} = 0.24 {+-} 0.05 {mu}m, for both MW and SMC. The abundance of grains,more » and hence the elemental abundance, is constrained from the reddening versus hydrogen column density, E(B - V)/N{sub H}. If we take the solar elemental abundance as the standard for the MW, >56% of carbon should be in graphite dust, while it is <40% in the SMC using its available abundance estimate. This disparity and the relative abundance of C to Si explain the difference of the two curves. We find that 50%-60% of carbon may not necessarily be in graphite but in the amorphous or glassy phase. Iron may also be in the metallic phase or up to {approx}80% in magnetite rather than in silicates, so that the Mg/Fe ratio in astronomical olivine is arbitrary. With these substitutions, the parameters of the grain size remain unchanged. The mass density of dust grains relative to hydrogen is {rho}{sub dust}/{rho}{sub H}= 1 / (120{sup +10}{sub -16}) for the MW and 1 / (760{sup +70}{sub -90}) for the SMC under the elemental abundance constraints. We underline the importance of the wavelength dependence of the extinction curve in the near-infrared in constructing the dust model: if A{sub {lambda}}{proportional_to}{lambda}{sup -{gamma}} with {gamma} {approx_equal} 1.6, the power-law grain-size model fails, whereas it works if {gamma} {approx_equal} 1.8-2.0.« less
Hornok, Sándor; Sugár, László; Fernández de Mera, Isabel G; de la Fuente, José; Horváth, Gábor; Kovács, Tibor; Micsutka, Attila; Gönczi, Enikő; Flaisz, Barbara; Takács, Nóra; Farkas, Róbert; Meli, Marina L; Hofmann-Lehmann, Regina
2018-03-20
Hunting constitutes an important industry in Europe. However, data on the prevalence of vector-borne bacteria in large game animal species are lacking from several countries. Blood or spleen samples (239 and 270, respectively) were taken from red, fallow and roe deer, as well as from water buffaloes, mouflons and wild boars in Hungary, followed by DNA extraction and molecular analyses for Anaplasma phagocytophilum, haemoplasmas and rickettsiae. Based on blood samples, the prevalence rate of A. phagocytophilum infection was significantly higher in red deer (97.9%) than in fallow deer (72.7%) and roe deer (60%), and in all these compared to mouflons (6.3%). In addition, 39.2% of the spleen samples from wild boars were PCR positive for A. phagocytophilum, but none of the buffalos. Based on blood samples, the prevalence rates of both Mycoplasma wenyonii (Mw) and 'Candidatus M. haemobos' (CMh) infections were significantly higher in buffaloes (Mw: 91.2%; CMh: 73.3%) than in red deer (Mw: 64.6%; CMh: 45.8%), and in both of them compared to fallow deer (Mw: 30.3%; CMh: 9.1%) and roe deer (Mw: 20%; CMh: 1.5%). The prevalence of Mw and CMh infection significantly correlated with the body sizes of these hosts. Furthermore, Mw was significantly more prevalent than CMh in buffaloes, red and roe deer. Mycoplasma ovis was detected in mouflons, M. suis in wild boars, R. helvetica in one fallow deer and one mouflon, and an unidentified Rickettsia sp. in a fallow deer. Forest-dwelling game animal species were found to be important carriers of A. phagocytophilum. In contrast, animals grazing grassland (i.e. buffaloes) were less likely to get infected with this Ixodes ricinus-borne pathogen. Water buffaloes, deer species, mouflons and wild boars harbored haemoplasmas that may affect domestic ungulates. Evaluated animals with larger body size had significantly higher prevalence of infection with haemoplasmas compared to smaller deer species. The above host species rarely carried rickettsiae.
Chen, Xue-shuang; Jiang, Tao; Lu, Song; Wei, Shi-qiang; Wang, Ding-yong; Yan, Jin-long
2016-03-15
The study of the molecular weight (MW) fractions of dissolved organic matter (DOM) in aquatic environment is of interests because the size plays an important role in deciding the biogeochemical characteristics of DOM. Thus, using ultrafiltration ( UF) technique combined with three-dimensional fluorescence spectroscopy, DOM samples from four sampling sites in typical water-level fluctuation zones of Three Gorge Reservoir areas were selected to investigate the differences of properties and sources of different DOM MW fractions. The results showed that in these areas, the distribution of MW fractions was highly dispersive, but the approximately equal contributions from colloidal (Mr 1 x 10³-0.22 µm) and true dissolved fraction (Mr < 1 x 10³) to the total DOC concentration were found. Four fluorescence signals (humic-like A and C; protein-like B and T) were observed in all MW fractions including bulk DOM, which showed the same distribution trend: true dissolved > low MW (Mr 1 x 10³-10 x 10³) > medium MW (Mr 10 x 10³-30 x 10³) > high MW (Mr 30 x 10³-0.22 µm). Additionally, with decreasing MW fraction, fluorescence index (FI) and freshness index (BIX) increased suggesting enhanced signals of autochthonous inputs, whereas humification index ( HIX) decreased indicating lowe humification degree. It strongly suggested that terrestrial input mainly affected the composition and property of higher MW fractions of DOM, as compared to lower MW and true dissolved fractions that were controlled by autochthonous sources such as microbial and alga activities, instead of allochthonous sources. Meanwhile, the riparian different land-use types also affected obviously on the characteristics of DOM. Therefore, higher diversity of land-use types, and also higher complexity of ecosystem and landscapes, induced higher heterogeneity of fluorescence components in different MW fraction of DOM.
A home health agency's pandemic preparedness and experience with the 2009 H1N1 pandemic.
Rebmann, Terri; Citarella, Barbara; Subramaniam, Divya S; Subramaniam, Dipti P
2011-11-01
Adequate pandemic preparedness is imperative for home health agencies. A 23-item pandemic preparedness survey was administered to home health agencies in the spring of 2010. The Kruskal-Wallis (KW) test was used to evaluate the relationships between agency size and preparedness indicators. Significant findings were further analyzed by the Mann-Whitney (MW) U post hoc test. The response rate was 25% (526/2,119). Approximately one-third of respondents (30.4%; n = 131) reported experiencing trouble obtaining supplies during the 2009 H1N1 pandemic. Small agencies were significantly more likely (Krusal-Wallis [KW] = 9.2; P < .01) to report having trouble obtaining supplies than larger-sized agencies (Mann-Whitney [MW] = 14,080; P < .01). Most home health agencies (87.3%; n = 459) reported having a pandemic influenza plan. One-third (33.5%; n = 176) reported having no surge capacity; only 27.0% (n = 142) reported having at least a 20% surge capacity. The largest agencies were significantly more likely (KW = 138; P < .001) to report having at least 20% surge capacity than medium-sized agencies (MW = 7,812; P = .001) or small agencies (MW = 8,306; P < .001). Approximately 80% (n = 414) reported stockpiling personal protective equipment. Three-quarters (71.3%; n = 375) reported fit-testing staff, and half (49.2%; n = 259) reported participating in disaster drills. The majority of home health professionals (75.1%; n = 395) reported having a personal/family disaster plan in place. There are gaps in US home health agency pandemic preparedness, including surge capacity and participation in disaster drills, that need to be addressed. Copyright © 2011 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Mosby, Inc. All rights reserved.
Hirata, K.; Takahashi, H.; Geist, E.; Satake, K.; Tanioka, Y.; Sugioka, H.; Mikada, H.
2003-01-01
Micro-tsunami waves with a maximum amplitude of 4-6 mm were detected with the ocean-bottom pressure gauges on a cabled deep seafloor observatory south of Hokkaido, Japan, following the January 28, 2000 earthquake (Mw 6.8) in the southern Kuril subduction zone. We model the observed micro-tsunami and estimate the focal depth and other source parameters such as fault length and amount of slip using grid searching with the least-squares method. The source depth and stress drop for the January 2000 earthquake are estimated to be 50 km and 7 MPa, respectively, with possible ranges of 45-55 km and 4-13 MPa. Focal depth of typical inter-plate earthquakes in this region ranges from 10 to 20 km and stress drop of inter-plate earthquakes generally is around 3 MPa. The source depth and stress drop estimates suggest that the earthquake was an intra-slab event in the subducting Pacific plate, rather than an inter-plate event. In addition, for a prescribed fault width of 30 km, the fault length is estimated to be 15 km, with possible ranges of 10-20 km, which is the same as the previously determined aftershock distribution. The corresponding estimate for seismic moment is 2.7x1019 Nm with possible ranges of 2.3x1019-3.2x1019Nm. Standard tide gauges along the nearby coast did not record any tsunami signal. High-precision ocean-bottom pressure measurements offshore thus make it possible to determine fault parameters of moderate-sized earthquakes in subduction zones using open-ocean tsunami waveforms. Published by Elsevier Science B. V.
The SPLASH Survey: Spectroscopy of 15 M31 Dwarf Spheroidal Satellite Galaxies
NASA Astrophysics Data System (ADS)
Tollerud, Erik J.; Beaton, Rachael L.; Geha, Marla C.; Bullock, James S.; Guhathakurta, Puragra; Kalirai, Jason S.; Majewski, Steve R.; Kirby, Evan N.; Gilbert, Karoline M.; Yniguez, Basilio; Patterson, Richard J.; Ostheimer, James C.; Cooke, Jeff; Dorman, Claire E.; Choudhury, Abrar; Cooper, Michael C.
2012-06-01
We present a resolved star spectroscopic survey of 15 dwarf spheroidal (dSph) satellites of the Andromeda galaxy (M31). We filter foreground contamination from Milky Way (MW) stars, noting that MW substructure is evident in this contaminant sample. We also filter M31 halo field giant stars and identify the remainder as probable dSph members. We then use these members to determine the kinematical properties of the dSphs. For the first time, we confirm that And XVIII, XXI, and XXII show kinematics consistent with bound, dark-matter-dominated galaxies. From the velocity dispersions for the full sample of dSphs we determine masses, which we combine with the size and luminosity of the galaxies to produce mass-size-luminosity scaling relations. With these scalings we determine that the M31 dSphs are fully consistent with the MW dSphs, suggesting that the well-studied MW satellite population provides a fair sample for broader conclusions. We also estimate dark matter halo masses of the satellites and find that there is no sign that the luminosity of these galaxies depends on their dark halo mass, a result consistent with what is seen for MW dwarfs. Two of the M31 dSphs (And XV, XVI) have estimated maximum circular velocities smaller than 12 km s-1 (to 1σ), which likely places them within the lowest-mass dark matter halos known to host stars (along with Boötes I of the MW). Finally, we use the systemic velocities of the M31 satellites to estimate the mass of the M31 halo, obtaining a virial mass consistent with previous results. The data presented herein were obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration. The Observatory was made possible by the generous financial support of the W. M. Keck Foundation.
NASA Astrophysics Data System (ADS)
Ikuta, R.; Mitsui, Y.; Ando, M.
2014-12-01
We studied inter-plate slip history for about 100 years using earthquake catalogs. On assumption that each earthquake has stick-slip patch centered in its centroid, we regard cumulative seismic slips around the centroid as representing the inter-plate dislocation. We evaluated the slips on the stick-slip patches of over-M5-class earthquakes prior to three recent mega-thrust earthquakes, the 2004 Sumatra (Mw9.2), the 2010 Chile (Mw8.8), and the 2011 Tohoku (Mw9.0) around them. Comparing the cumulative seismic slips with the plate convergence, the slips before the mega-thrust events are significantly short in large area corresponding to the size of the mega-thrust events. We also researched cumulative seismic slips after other three mega-thrust earthquakes occurred in this 100 years, the 1952 Kamchatka (Mw9.0), the 1960 Chile (Mw9.5), the 1964 Alaska (Mw9.2). The cumulative slips have been significantly short in and around the focal area after their occurrence. The result should reflect persistency of the strong or/and large inter-plate coupled area capable of mega-thrust earthquakes. We applied the same procedure to global subduction zones to find that 21 regions including the focal area of above mega-thrust earthquakes show slip deficit over large area corresponding to the size of M9-class earthquakes. Considering that at least six M9-class earthquakes occurred in this 100 years and each recurrence interval should be 500-1000 years, it would not be surprised that from five to ten times of the already known regions (30 to 60 regions) are capable of M9 class earthquakes. The 21 regions as expected M9 class focal areas in our study is less than 5 to 10 times of the known 6, some of these regions may be divided into a few M9 class focal area because they extend to much larger area than typical M9 class focal area.
Utility interconnection experience with an operating central station MW-sized photovoltaic plant
NASA Astrophysics Data System (ADS)
Patapoff, N. W., Jr.; Mattijetz, D. R.
1985-08-01
Utility experience to date with photovoltaic systems has been with small dispersed systems designed primarily as demonstration projects. The 1 MW photovoltaic plant at Lugo Substation in Hesperia, California, has been designed and is operated as a central station power plant. The performance of the system has been monitored since first coming on line in November 1982. The potential impact of this and similar systems upon the operation of the utility is discussed.
A Mw 6.3 earthquake scenario in the city of Nice (southeast France): ground motion simulations
NASA Astrophysics Data System (ADS)
Salichon, Jérome; Kohrs-Sansorny, Carine; Bertrand, Etienne; Courboulex, Françoise
2010-07-01
The southern Alps-Ligurian basin junction is one of the most seismically active zone of the western Europe. A constant microseismicity and moderate size events (3.5 < M < 5) are regularly recorded. The last reported historical event took place in February 1887 and reached an estimated magnitude between 6 and 6.5, causing human losses and extensive damages (intensity X, Medvedev-Sponheuer-Karnik). Such an event, occurring nowadays, could have critical consequences given the high density of population living on the French and Italian Riviera. We study the case of an offshore Mw 6.3 earthquake located at the place where two moderate size events (Mw 4.5) occurred recently and where a morphotectonic feature has been detected by a bathymetric survey. We used a stochastic empirical Green’s functions (EGFs) summation method to produce a population of realistic accelerograms on rock and soil sites in the city of Nice. The ground motion simulations are calibrated on a rock site with a set of ground motion prediction equations (GMPEs) in order to estimate a reasonable stress-drop ratio between the February 25th, 2001, Mw 4.5, event taken as an EGF and the target earthquake. Our results show that the combination of the GMPEs and EGF techniques is an interesting tool for site-specific strong ground motion estimation.
WindPACT Reference Wind Turbines
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dykes, Katherine L; Rinker, Jennifer
To fully understand how loads and turbine cost scale with turbine size, it is necessary to have identical turbine models that have been scaled to different rated powers. The report presents the WindPACT baseline models, which are a series of four baseline models that were designed to facilitate investigations into the scalings of loads and turbine cost with size. The models have four different rated powers (750 kW, 1.5 MW, 3.0 MW, and 5.0 MW), and each model was designed to its specified rated power using the same design methodology. The models were originally implemented in FAST_AD, the predecessor tomore » NREL's open-source wind turbine simulator FAST, but have yet to be implemented in FAST. This report contains the specifications for all four WindPACT baseline models - including structural, aerodynamic, and control specifications - along with the inherent assumptions and equations that were used to calculate the model parameters. It is hoped that these baseline models will serve as extremely useful resources for investigations into the scalings of costs, loads, or optimization routines.« less
Li, Yongfu; Meunier, David M; Partain, Emmett M
2014-09-12
Size-exclusion chromatography (SEC) of hydrophobe-modified hydroxyethyl cellulose (HmHEC) is challenging because polymer chains are not isolated in solution due to association of hydrophobic groups and hydrophobic interaction with column packing materials. An approach to neutralize these hydrophobic interactions was developed by adding β-cyclodextrin (β-CD) to the aqueous eluent. SEC mass recovery, especially for the higher molecular weight chains, increased with increasing concentration of β-CD in the eluent. A β-CD concentration of 0.75wt% in the eluent was determined to be optimal for the HmHEC polymers studied. These conditions enabled precise determinations of apparent molecular weight distributions exhibiting less than 2% relative standard deviation in the measured weight-average molecular weight (MW) for five injections on three studied samples and showed no significant differences in MW determined on two different days. The developed technology was shown to be very robust for characterizing HmHEC having MW from 500kg/mol to 2000kg/mol, and it can be potentially applied to other hydrophobe-modified polymers. Copyright © 2014 Elsevier B.V. All rights reserved.
Estimating the Mass of the Milky Way Using the Ensemble of Classical Satellite Galaxies
NASA Astrophysics Data System (ADS)
Patel, Ekta; Besla, Gurtina; Sohn, Sangmo Tony; Mandel, Kaisey
2018-06-01
High precision proper motions are currently available for approximately 20% of the Milky Way's known satellite galaxies. Often, the 6D phase space information of each satellite is used separately to constrain the mass of the MW. In this talk, I will discuss the Bayesian framework outlined in Patel et al. 2017b to make inferences of the MW's mass using satellite properties such as specific orbital angular momentum, rather than just position and velocity. By extending this framework from one satellite to a population of satellites, we can now form simultaneous MW mass estimates using the Illustris-Dark cosmological simulation that are unbiased by high speed satellites such as Leo I (Patel et al., submitted). Our resulting MW mass estimates reduce the current factor of two uncertainty in the mass range of the MW and show promising signs for improvement as upcoming ground- and space-based observatories obtain proper motions for additional MW satellite galaxies.
NASA Astrophysics Data System (ADS)
Fondriest, M.; Smith, S. A.; Di Toro, G.; Nielsen, S. B.
2012-12-01
The lack of clear geological markers of seismic faulting represents a major limitation in our current comprehension of earthquake physics. At present pseudotachylytes (i.e. friction-induced melts) are the only unambiguously identified indicator of ancient seismicity in exhumed fault zones, but pseudotachylytes are not found in many rock types, including carbonates. We report the occurrence of small-displacement, mirror-like slip surfaces from a fault zone cutting dolostones. A combination of field observations and rotary shear friction experiments suggests that such slip surfaces: 1) are formed only at seismic slip rates, and 2) could potentially be used to estimate power dissipation during individual slip events. The Foiana Line (FL) is a major NNE-SSW-trending sinistral transpressive fault in the Italian Southern Alps. The outcropping fault zone consists of a <300 m wide zone of heavily fractured ("pulverized") dolostones cut by a network of mirror-like slip surfaces. The slip surfaces have displacements ranging between 0.04 m and 0.5 m and their mirror-like appearance indicates that the wavelength of surface roughness is <1 μm. The slip surfaces have mainly dip-slip reverse kinematics and were exhumed from ~2 km depth. Resolved normal stress on the slip surfaces is estimated in the range 30-50 MPa. To understand how the mirror-like slip surfaces may have developed, slow- to high-velocity rotary-shear experiments using SHIVA (INGV, Rome) were performed on 3 mm thick layers of dolomite gouge (grain size <250 μm) collected from the FL. Tests were conducted using a purpose-built gouge sample holder at slip rates of 0.0001-1.13 m/s, normal stresses up to 26 MPa and displacements in the range 0.02-3.5 m. At seismic slip rates of 1.13 m/s the dolomite gouge shows a dramatic reduction of the friction coefficient (μ) from a peak value of ~0.7 to a steady-state value of ~0.25. The gouge starts to weaken above a threshold velocity in the range 0.19-0.49 m/s following a transient phase of strengthening. During the tests the instantaneous power density (shear stress*slip rate) dissipated on the sample reaches values of 6-10 MW/m2 over distances of 0.02-1 m, comparable to those of natural earthquakes. At 26 MPa normal stress a mirror-like slip surface is formed after only 0.03 m of slip. At intermediate slip rates (0.113 m/s) only moderate reductions in μ are observed. Instantaneous power density is ~1 MW/m2 and the mirror-like slip surface starts to develop after 0.1 m of slip. At sub-seismic slip rates (0.0001-0.0013 m/s) μ remains ~0.7, instantaneous power density is ~0.02 MW/m2, and no mirror-like slip surface develops. Microstructural observations suggest that the natural and experimental slip zones are comparable: both have a compacted layer up to 20 μm thick immediately below the mirror-like slip surface in which deformation is strongly localized. The layer consists of partially-welded dolomite clasts 0.1-10 μm in size. In the experimental samples, chemical analyses recognized small (<100 μm long), discontinuous patches of periclase and Mg-calcite nanoparticles formed by dolomite decomposition. Field, experimental and microstructural data suggest that mirror-like slip surfaces in dolostone develop at seismic conditions, when instantaneous power density is of the order of 1-10 MW/m2.
Adsorption and fractionation of a muck fulvic acid on kaolinite and goethite at pH 3.7,6, and 8
Namjesnik-Dejanovic, K.; Maurice, P.A.; Aiken, G.R.; Cabaniss, S.; Chin, Y.-P.; Pullin, M.J.
2000-01-01
Molecular weight (MW) of humic materials is a key factor controlling proton and metal binding and organic pollutant partitioning. Several studies have suggested preferential adsorption of higher MW, more aromatic moieties to mineral surfaces; quantification of such processes is fundamental to development of predictive models. We used high pressure size exclusion chromatography (HPSEC) to quantify MW changes upon adsorption of a muck fulvic acid (MFA) extracted from a peat deposit to kaolinite and goethite, at pH 3.7,6, and 8 at 22 ??C, I = 0.01 (NaC1), 24-h reaction time. MFA adsorption affinity was greater for goethite than for kaolinite. At concentrations less than the adsorption maximum (A(max)) for both adsorbents, the weight-average MW (M(w)) of MFA remaining in solution decreased by as much as several hundred Daltons relative to control samples, indicating preferential adsorption of the higher MW components. At concentrations more than A(max), M(w) of MFA in solution did not change appreciably. Although total adsorption decreased significantly as pH increased, fractionation as measured by change in M(w) remained similar, perhaps indicating greater selectivity for higher MW components at higher pH. Absorptivities at ?? = 280 nm normalized to mg C L-1 (??) suggested preferential adsorption of more aromatic moieties to kaolinite. ?? could not be used for goethite-reacted samples because high Fe concentrations in the aqueous phase brought about by goethite dissolution interfered with the spectroscopic analysis. Preliminary kinetic experiments suggested that smaller molecules adsorbed first and were replaced by larger molecules whose adsorption was thermodynamically favored.
Molecular rotation and dynamics in superfluid helium-4 nanodroplets
NASA Astrophysics Data System (ADS)
Callegari, Carlo
2000-11-01
Cavity-enhanced laser radiation, coupled to molecular- beam bolometric detection has been used to study the spectroscopy of acetylenic molecules embedded in helium nanodroplets. The 2ν1 transition (CH stretch overtone) of HCN, DCCH, NCCCH, CH3CCH, CF3CCH, (CH 3)3CCCH, (CH3)3SiCCH, has been investigated in the 1.5 μm spectral region by means of a color center laser coupled to a resonant build-up cavity, which enhances the laser power experienced by the molecules in the beam by up to a factor of 400, thus overcoming the weakness of the (dipole forbidden) transitions. All molecules are observed to rotate freely in the liquid cluster environment, with strongly enhanced moments of inertia, but with negligible matrix induced shifts (less than 1 cm-1). We show that this enhancement is largely accounted for by hydrodynamic effects, which we have modeled and numerically calculated. While in the gas phase the rotational lines have instrument-limited widths (a few MHZ), in the droplets we have observed linewidths ranging from 600 MHz for (CH3)3SiCCH to 2.8GHz for (CH3) 3CCCH. To investigate the nature of the broadening (which was widely believed to be homogeneous), we have performed a series of infrared (IR) saturation experiments on the 2ν1 transition. We have also thoroughly investigated NCCCH by means of microwave (MW) single-resonance experiments (on rotational transitions) and double-resonance (MW-MW and MW-IR) experiments. The results demonstrate that the spectral features of molecules in He droplets are inhomogeneously broadened, and allow an estimate of the importance of the different broadening contributions. In particular, MW-IR measurements show that the size of the cluster greatly affects the way rotational energy is relaxed. Large clusters seem to follow a ``strong collision model'' where memory of the initial rotational state is completely lost after each ``relaxation'' event, while for smaller clusters relaxation rates are probably affected by the lower density of states available for the dissipation of energy.
Molecular rotation and dynamics in superfluid ^4He nanodroplets
NASA Astrophysics Data System (ADS)
Callegari, Carlo
2001-05-01
Cavity-enhanced laser radiation, coupled to molecular-beam bolometric detection has been used to study the spectroscopy of acetylenic molecules embedded in helium nanodroplets. The 2ν1 transition (CH stretch overtone) of HCN, DCCH, NCCCH, CH_3CCH, CF_3CCH, (CH_3)_3CCCH, (CH_3)_3SiCCH, has been investigated in the 1.5 μm spectral region by means of a color center laser coupled to a resonant buildup cavity, which enhances the laser power experienced by the molecules in the beam by up to a factor of 400, thus overcoming the weakness of the (harmonically forbidden) transitions. All molecules are observed to rotate freely in the liquid cluster environment, with strongly enhanced moments of inertia, but with negligible matrix induced shifts (less than 1 cm-1). We show that this enhancement is largely accounted for by hydrodynamic effects, which we have modeled and numerically calculated. While in the gas phase the rotational lines have instrument-limited widths (a few MHz), in the droplets we have observed linewidths ranging from 600 MHz for (CH_3)_3SiCCH to 2.8 GHz for (CH_3)_3CCCH. To investigate the nature of the broadening (which was widely believed to be homogeneous), we have performed a series of infrared (IR) saturation experiments on the 2ν1 transition. We have also thoroughly investigated NCCCH by means of microwave (MW) single-resonance experiments (on rotational transitions) and double-resonance (MW-MW and MW-IR) experiments. The results demonstrate that the spectral features of molecules in He droplets are inhomogeneously broadened, and allow an estimate of the importance of the different broadening contributions. In particular, MW-IR measurements show that the size of the cluster greatly affects the way rotational energy is relaxed. Large clusters seem to follow a ``strong collision model'' where memory of the initial rotational state is completely lost after each ``relaxation'' event, while for smaller clusters relaxation rates are probably affected by the lower density of states available for the dissipation of energy.
Diagnosis of the "large medial meniscus" of the knee on MR imaging.
Samoto, Nobuhiko; Kozuma, Masakazu; Tokuhisa, Toshio; Kobayashi, Kunio
2006-11-01
Although several quantitative magnetic resonance (MR) diagnostic criteria for discoid lateral meniscus (DLM) have been described, there are no criteria by which to estimate the size of the medial meniscus. We define a medial meniscus that exceeds the normal size as a "large medial meniscus" (LMM), and the purpose of this study is to establish the quantitative MR diagnostic criteria for LMM. The MR imaging findings of 96 knees with arthroscopically confirmed intact semilunar lateral meniscus (SLM), 18 knees with intact DLM, 105 knees with intact semilunar medial meniscus (SMM) and 4 knees with torn LMM were analyzed. The following three quantitative parameters were measured: (a) meniscal width (MW): the minimum MW on the coronal slice; (b) ratio of the meniscus to the tibia (RMT): the ratio of minimum MW to maximum tibial width on the coronal slice; (c) continuity of the anterior and posterior horns (CAPH): the number of consecutive 5-mm-thick sagittal slices showing continuity between the anterior horn and the posterior horn of the meniscus on sagittal slices. Using logistic discriminant analysis between intact SLM and DLM groups and using descriptive statistics of intact SLM and SMM groups, the cutoff values used to discriminate LMM from SMM were calculated by MW and RMT. Moreover, the efficacy of these cutoff values and three slices of the cutoff values for CAPH were estimated in the medial meniscus group. "MW> or =11 mm" and "RMT> or =15%" were determined to be effective diagnostic criteria for LMM, while three of four cases in the torn LMM group were true positives and specificity was 99% in both criteria. When "CAPH> or =3 slices" was used as a criterion, three of four torn LMM cases were true positives and specificity was 93%.
Finite-fault slip model of the 2011 Mw 5.6 Prague, Oklahoma earthquake from regional waveforms
Sun, Xiaodan; Hartzell, Stephen
2014-01-01
The slip model for the 2011 Mw 5.6 Prague, Oklahoma, earthquake is inferred using a linear least squares methodology. Waveforms of six aftershocks recorded at 21 regional stations are used as empirical Green's functions (EGFs). The solution indicates two large slip patches: one located around the hypocenter with a depth range of 3–5.5 km; the other located to the southwest of the epicenter with a depth range from 7.5 to 9.5 km. The total moment of the solution is estimated at 3.37 × 1024 dyne cm (Mw 5.65). The peak slip and average stress drop for the source at the hypocenter are 70 cm and 90 bars, respectively, approximately one half the values for the Mw 5.8 2011 Mineral, Virginia, earthquake. The stress drop averaged over all areas of slip is 16 bars. The relatively low peak slip and stress drop may indicate an induced component in the origin of the Prague earthquake from deep fluid injection.
Trontz, Adam; Cheng, Baokai; Zeng, Shixuan; ...
2015-09-25
Metal-ceramic coaxial cable Fabry-Pérot interferometric (MCCC-FPI) sensors have been developed using a stainless steel tube and a stainless steel wire as the outer and inner conductors, respectively; a tubular α-alumina insulator; and a pair of air gaps created in the insulator along the cable to serve as weak reflectors for the transmitting microwave (MW) signal. The MCCC-FPI sensors have been demonstrated for high temperature measurements using MW signals in a frequency range of 2–8 GHz. The temperature measurement is achieved by monitoring the frequency shift (Δƒ) of the MW interferogram reflected from the pair of weak reflectors. The MW sensormore » exhibited excellent linear dependence of Δƒ on temperature; small measurement deviations (±2.7%); and fast response in a tested range of 200–500 °C. The MCCC has the potential for further developing multipoint FPI sensors in a single-cable to achieve in situ and continuous measurement of spatially distributed temperature in harsh environments.« less
Land Use by System Technology | Energy Analysis | NREL
compares the combination of capital costs, O&M, performance, and fuel costs. If you are seeking utility 5.5 0.7 Photovoltaics 1 10 MW 6.1 1.7 Wind <10 kW 30 n/a Wind 10 100 kW 30 n/a Wind 100- 1000 kW 30 n/a Wind 1 10 MW 44.7 25.0 Biomass Combustion Combined Heat & Power 3.5 1.9 Technology Type Size
New control center for EPM in Medellin, Columbia
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gomez, H.C.; Zadeh, K.N.; Meyer, R.C.
1989-07-01
The municipal electric utility of Empresas Publicas de Medellin (EPM) in Medellin, Colombia, has completed the installation and testing of their new control center. These facilities, which include all the functions expected from a modern control center, were implemented through carefully monitored and executed project stages, which are described in this article. EPM generates and transmits 1400 MW of exclusively hydroelectric energy to their service territory of the city of Medellin and nine neighboring cities and 77 smaller cities. The EPM system load ranges from 400 MW to 1200 MW.
The ARIES Advanced and Conservative Tokamak Power Plant Study
Kessel, C. E; Tillak, M. S; Najmabadi, F.; ...
2015-12-22
Tokamak power plants are studied with advanced and conservative design philosophies to identify the impacts on the resulting designs and to provide guidance to critical research needs. Incorporating updated physics understanding and using more sophisticated engineering and physics analysis, the tokamak configurations have developed a more credible basis compared with older studies. The advanced configuration assumes a self-cooled lead lithium blanket concept with SiC composite structural material with 58% thermal conversion efficiency. This plasma has a major radius of 6.25 m, a toroidal field of 6.0 T, a q₉₅ of 4.5, aᵦ total N of 5.75, an H98 of 1.65,more » an n/n Gr of 1.0, and a peak divertor heat flux of 13.7 MW/m² . The conservative configuration assumes a dual-coolant lead lithium blanket concept with reduced activation ferritic martensitic steel structural material and helium coolant, achieving a thermal conversion efficiency of 45%. The plasma has a major radius of 9.75 m, a toroidal field of 8.75 T, a q₉₅ of 8.0, aᵦ total N of 2.5, an H₉₈ of 1.25, an n/n Gr of 1.3, and a peak divertor heat flux of 10 MW/m² . The divertor heat flux treatment with a narrow power scrape off width has driven the plasmas to larger major radius. Edge and divertor plasma simulations are targeting a basis for high radiated power fraction in the divertor, which is necessary for solutions to keep the peak heat flux in the range 10 to 15 MW/m² . Combinations of the advanced and conservative approaches show intermediate sizes. A new systems code using a database approach has been used and shows that the operating point is really an operating zone with some range of plasma and engineering parameters and very similar costs of electricity. Other papers in this issue provide more detailed discussion of the work summarized here.« less
The ARIES Advanced And Conservative Tokamak (ACT) Power Plant Study
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kessel, C. E.; Poli, F. M.; Ghantous, K.
2014-03-05
Tokamak power plants are studied with advanced and conservative design philosophies in order to identify the impacts on the resulting designs and to provide guidance to critical research needs. Incorporating updated physics understanding, and using more sophisticated engineering and physics analysis, the tokamak configurations have developed a more credible basis compared to older studies. The advanced configuration assumes a self-cooled lead lithium (SCLL) blanket concept with SiC composite structural material with 58% thermal conversion efficiency. This plasma has a major radius of 6.25 m, a toroidal field of 6.0 T, a q95 of 4.5, a βN total of 5.75, Hmore » 98 of 1.65, n/nGr of 1.0, and peak divertor heat flux of 13.7 MW/m 2. The conservative configuration assumes a dual coolant lead lithium (DCLL) blanket concept with ferritic steel structural material and helium coolant, achieving a thermal conversion efficiency of 45%. The plasma major radius is 9.75 m, a toroidal field of 8.75 T, a q95 of 8.0, a βN total of 2.5, H 98 of 1.25, n/n Gr of 1.3, and peak divertor heat flux of 10 MW/m 2. The divertor heat flux treatment with a narrow power scrape-off width has driven the plasmas to larger major radius. Edge and divertor plasma simulations are targeting a basis for high radiated power fraction in the divertor, which is necessary for solutions to keep the peak heat flux in the range of 10-15 MW/m 2. Combinations of the advanced and conservative approaches show intermediate sizes. A new systems code using a database approach has been used and shows that the operating point is really an operating zone with some range of plasma and engineering parameters and very similar costs of electricity. Papers in this issue provide more detailed discussion of the work summarized here.« less
Superconducting wind turbine generators
NASA Astrophysics Data System (ADS)
Abrahamsen, A. B.; Mijatovic, N.; Seiler, E.; Zirngibl, T.; Træholt, C.; Nørgård, P. B.; Pedersen, N. F.; Andersen, N. H.; Østergård, J.
2010-03-01
We have examined the potential of 10 MW superconducting direct drive generators to enter the European offshore wind power market and estimated that the production of about 1200 superconducting turbines until 2030 would correspond to 10% of the EU offshore market. The expected properties of future offshore turbines of 8 and 10 MW have been determined from an up-scaling of an existing 5 MW turbine and the necessary properties of the superconducting drive train are discussed. We have found that the absence of the gear box is the main benefit and the reduced weight and size is secondary. However, the main challenge of the superconducting direct drive technology is to prove that the reliability is superior to the alternative drive trains based on gearboxes or permanent magnets. A strategy of successive testing of superconducting direct drive trains in real wind turbines of 10 kW, 100 kW, 1 MW and 10 MW is suggested to secure the accumulation of reliability experience. Finally, the quantities of high temperature superconducting tape needed for a 10 kW and an extreme high field 10 MW generator are found to be 7.5 km and 1500 km, respectively. A more realistic estimate is 200-300 km of tape per 10 MW generator and it is concluded that the present production capacity of coated conductors must be increased by a factor of 36 by 2020, resulting in a ten times lower price of the tape in order to reach a realistic price level for the superconducting drive train.
Liese, Eric; Zitney, Stephen E.
2017-06-26
A multi-stage centrifugal compressor model is presented with emphasis on analyzing use of an exit flow coefficient vs. an inlet flow coefficient performance parameter to predict off-design conditions in the critical region of a supercritical carbon dioxide (CO 2) power cycle. A description of the performance parameters is given along with their implementation in a design model (number of stages, basic sizing, etc.) and a dynamic model (for use in transient studies). A design case is shown for two compressors, a bypass compressor and a main compressor, as defined in a process simulation of a 10 megawatt (MW) supercritical COmore » 2 recompression Brayton cycle. Simulation results are presented for a simple open cycle and closed cycle process with changes to the inlet temperature of the main compressor which operates near the CO 2 critical point. Results showed some difference in results using the exit vs. inlet flow coefficient correction, however, it was not significant for the range of conditions examined. Here, this paper also serves as a reference for future works, including a full process simulation of the 10 MW recompression Brayton cycle.« less
NASA Astrophysics Data System (ADS)
Sorbom, Brandon; Ball, Justin; Palmer, Timothy; Mangiarotti, Franco; Sierchio, Jennifer; Bonoli, Paul; Kasten, Cale; Sutherland, Derek; Barnard, Harold; Haakonsen, Christian; Goh, Jon; Sung, Choongki; Whyte, Dennis
2014-10-01
The Affordable, Robust, Compact (ARC) reactor conceptual design aims to reduce the size, cost, and complexity of a combined Fusion Nuclear Science Facility (FNSF) and demonstration fusion pilot power plant. ARC is a 270 MWe tokamak reactor with a major radius of 3.3 m, a minor radius of 1.1 m, and an on-axis magnetic field of 9.2 T. ARC has Rare Earth Barium Copper Oxide (REBCO) superconducting toroidal field coils with joints to allow disassembly, allowing for removal and replacement of the vacuum vessel as a single component. Inboard-launched current drive of 25 MW LHRF power and 13.6 MW ICRF power is used to provide a robust, steady state core plasma far from disruptive limits. ARC uses an all-liquid blanket, consisting of low pressure, slowly flowing Fluorine Lithium Beryllium (FLiBe) molten salt. The liquid blanket acts as a working fluid, coolant, and tritium breeder, and minimizes the solid material that can become activated. The large temperature range over which FLiBe is liquid permits blanket operation at 800-900 K with single phase fluid cooling and allows use of a high-efficiency Brayton cycle for electricity production in the secondary coolant loop.
Earthquake source properties of a shallow induced seismic sequence in SE Brazil
NASA Astrophysics Data System (ADS)
Agurto-Detzel, Hans; Bianchi, Marcelo; Prieto, Germán. A.; Assumpção, Marcelo
2017-04-01
We study source parameters of a cluster of 21 very shallow (<1 km depth) small-magnitude (Mw < 2) earthquakes induced by percolation of water by gravity in SE Brazil. Using a multiple empirical Green's functions (meGf) approach, we estimate seismic moments, corner frequencies, and static stress drops of these events by inversion of their spectral ratios. For the studied magnitude range (-0.3 < Mw < 1.9), we found an increase of stress drop with seismic moment. We assess associated uncertainties by considering different signal time windows and by performing a jackknife resampling of the spectral ratios. We also calculate seismic moments by full waveform inversion to independently validate our moments from spectral analysis. We propose repeated rupture on a fault patch at shallow depth, following continuous inflow of water, as the cause for the observed low absolute stress drop values (<1 MPa) and earthquake size dependency. To our knowledge, no other study on earthquake source properties of shallow events induced by water injection with no added pressure is available in the literature. Our study suggests that source parameter characterization may provide additional information of induced seismicity by hydraulic stimulation.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Liese, Eric; Zitney, Stephen E.
A multi-stage centrifugal compressor model is presented with emphasis on analyzing use of an exit flow coefficient vs. an inlet flow coefficient performance parameter to predict off-design conditions in the critical region of a supercritical carbon dioxide (CO 2) power cycle. A description of the performance parameters is given along with their implementation in a design model (number of stages, basic sizing, etc.) and a dynamic model (for use in transient studies). A design case is shown for two compressors, a bypass compressor and a main compressor, as defined in a process simulation of a 10 megawatt (MW) supercritical COmore » 2 recompression Brayton cycle. Simulation results are presented for a simple open cycle and closed cycle process with changes to the inlet temperature of the main compressor which operates near the CO 2 critical point. Results showed some difference in results using the exit vs. inlet flow coefficient correction, however, it was not significant for the range of conditions examined. Here, this paper also serves as a reference for future works, including a full process simulation of the 10 MW recompression Brayton cycle.« less
Phase behaviour of oat β-glucan/sodium caseinate mixtures varying in molecular weight.
Agbenorhevi, Jacob K; Kontogiorgos, Vassilis; Kasapis, Stefan
2013-05-01
The isothermal phase behaviour at 5 °C of mixtures of sodium caseinate and oat β-glucan isolates varying in molecular weight (MW) was investigated by means of phase diagram construction, rheometry, fluorescence microscopy and electrophoresis. Phase diagrams indicated that the compatibility of the β-glucan/sodium caseinate system increases as β-glucan MW decreases. Images of mixtures taken at various biopolymer concentrations revealed phase separated domains. Results also revealed that at the state of thermodynamic equilibrium, lower MW samples yielded considerable viscosity in the mixture. At equivalent hydrodynamic volume of β-glucan in the mixtures, samples varying in molecular weight exhibited similar flow behaviour. A deviation dependent on the protein concentration was observed for the high MW sample in the concentrated regime due to the size of β-glucan aggregates formed. Results demonstrate that by controlling the structural features of β-glucan in mixtures with sodium caseinate, informed manipulation of rheological properties in these systems can be achieved. Copyright © 2012 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Alberti, Stefano; Genoud, Jérémy; Goodman, Timothy; Hogge, Jean-Philippe; Porte, Laurie; Silva, Miguel; Tran, Trach-Minh; Tran, Minh-Quang; Avramidis, Konstantinos; Pagonakis, Ioannis; Jin, Jianbo; Illy, Stefan; Gantenbein, Gerd; Jelonnek, John; Thumm, Manfred; Bin, William; Bruschi, Alex; Garavaglia, Saul; Moro, Alessandro; Kasparek, Walter; Legrand, François; Perial, Etienne; Rozier, Yoan; Cismondi, Fabio; Doelman, Niek
2017-10-01
The upgrade of the EC-system of the TCV tokamak has entered in its realization phase and is part of a broader upgrade of TCV. The MW-class dual-frequency gyrotrons (84 or 126GHz/2s/1MW) are presently being manufactured by Thales Electron Devices with the first gyrotron foreseen to be delivered at SPC by the end of 2017. In parallel to the gyrotron development, for extending the level of operational flexibility of the TCV EC-system the integration of the dual-frequency gyrotrons adds a significant complexity in the evacuated 63.5mm-diameter HE11 transmission line system connected to the various TCV low-field side and top launchers. As discussed in [1], an important part of the present TCV-upgrade consists in inserting a modular closed divertor chamber. This will have an impact on the X3 top-launcher which will have to be reduced in size. For using the new compact launcher we are considering employing a Fast Directional Switch (FADIS), combining the two 1MW/126GHz/2s rf-beams into a single 2MW rf-beam.
Origin of the Local Group satellite planes
NASA Astrophysics Data System (ADS)
Banik, Indranil; O'Ryan, David; Zhao, Hongsheng
2018-04-01
We attempt to understand the planes of satellite galaxies orbiting the Milky Way (MW) and M31 in the context of Modified Newtonian Dynamics (MOND), which implies a close MW-M31 flyby occurred ≈8 Gyr ago. Using the timing argument, we obtain MW-M31 trajectories consistent with cosmological initial conditions and present observations. We adjust the present M31 proper motion within its uncertainty in order to simulate a range of orbital geometries and closest approach distances. Treating the MW and M31 as point masses, we follow the trajectories of surrounding test particle disks, thereby mapping out the tidal debris distribution. Around each galaxy, the resulting tidal debris tends to cluster around a particular orbital pole. We find some models in which these preferred spin vectors align fairly well with those of the corresponding observed satellite planes. The radial distributions of material in the simulated satellite planes are similar to what we observe. Around the MW, our best-fitting model yields a significant fraction (0.22) of counter-rotating material, perhaps explaining why Sculptor counter-rotates within the MW satellite plane. In contrast, our model yields no counter-rotating material around M31. This is testable with proper motions of M31 satellites. In our best model, the MW disk is thickened by the flyby 7.65 Gyr ago to a root mean square height of 0.75 kpc. This is similar to the observed age and thickness of the Galactic thick disk. Thus, the MW thick disk may have formed together with the MW and M31 satellite planes during a past MW-M31 flyby.
Origin of the Local Group satellite planes
NASA Astrophysics Data System (ADS)
Banik, Indranil; O'Ryan, David; Zhao, Hongsheng
2018-07-01
We attempt to understand the planes of satellite galaxies orbiting the Milky Way (MW) and M31 in the context of Modified Newtonian Dynamics, which implies a close MW-M31 flyby occurred ≈8 Gyr ago. Using the timing argument, we obtain MW-M31 trajectories consistent with cosmological initial conditions and present observations. We adjust the present M31 proper motion within its uncertainty in order to simulate a range of orbital geometries and closest approach distances. Treating the MW and M31 as point masses, we follow the trajectories of surrounding test particle discs, thereby mapping out the tidal debris distribution. Around each galaxy, the resulting tidal debris tends to cluster around a particular orbital pole. We find some models in which these preferred spin vectors align fairly well with those of the corresponding observed satellite planes. The radial distributions of material in the simulated satellite planes are similar to what we observe. Around the MW, our best-fitting model yields a significant fraction (0.22) of counter-rotating material, perhaps explaining why Sculptor counter-rotates within the MW satellite plane. In contrast, our model yields no counter-rotating material around M31. This is testable with proper motions of M31 satellites. In our best model, the MW disc is thickened by the flyby 7.65 Gyr ago to a root mean square height of 0.75 kpc. This is similar to the observed age and thickness of the Galactic thick disc. Thus, the MW thick disc may have formed together with the MW and M31 satellite planes during a past MW-M31 flyby.
Early commercial demonstration of space solar power using ultra-lightweight arrays
NASA Astrophysics Data System (ADS)
Reed, Kevin; Willenberg, Harvey J.
2009-11-01
Space solar power shows great promise for future energy sources worldwide. Most central power stations operate with power capacity of 1000 MW or greater. Due to launch size limitations and specific power of current, rigid solar arrays, the largest solar arrays that have flown in space are around 50 kW. Thin-film arrays offer the promise of much higher specific power and deployment of array sizes up to several MW with current launch vehicles. An approach to early commercial applications for space solar power to distribute power to charge hand-held, mobile battery systems by wireless power transmission (WPT) from thin-film solar arrays in quasi-stationary orbits will be presented. Four key elements to this prototype will be discussed: (1) Space and near-space testing of prototype wireless power transmission by laser and microwave components including WPT space to space and WPT space to near-space HAA transmission demonstrations; (2) distributed power source for recharging hand-held batteries by wireless power transmission from MW space solar power systems; (3) use of quasi-geostationary satellites to generate electricity and distribute it to targeted areas; and (4) architecture and technology for ultra-lightweight thin-film solar arrays with specific energy exceeding 1 kW/kg. This approach would yield flight demonstration of space solar power and wireless power transmission of 1.2 MW. This prototype system will be described, and a roadmap will be presented that will lead to still higher power levels.
Spherical, rolling magnet generators for passive energy harvesting from human motion
NASA Astrophysics Data System (ADS)
Bowers, Benjamin J.; Arnold, David P.
2009-09-01
In this work, non-resonant, vibrational energy harvester architectures intended for human-motion energy scavenging are researched. The basic design employs a spherical, unidirectionally magnetized permanent magnet (NdFeB) ball that is allowed to move arbitrarily in a spherical cavity wrapped with copper coil windings. As the ball rotates and translates within the cage, the time-varying magnetic flux induces a voltage in the coil according to Faraday's Law. Devices ranging from 1.5 cm3 to 4 cm3 in size were tested under human activity scenarios—held in the user's hand or placed in the user's pocket while walking (4 km h-1) and running (14.5 km h-1). These harvesters have demonstrated rms voltages ranging from ~80 mV to 700 mV and time-averaged power densities up to 0.5 mW cm-3.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Amano, Sho
2014-06-15
To generate continuously repetitive EUV and soft X-ray pulses with various wavelengths from laser-produced plasmas, a one-dimensionally translating substrate system with a closed He gas cryostat that can continuously supply various cryogenic targets for ∼10 Hz laser pulses has been developed. The system was successfully operated at a lowest temperature of 15 K and at a maximum up-down speed of 12 mm/s. Solid Ar, Kr, and Xe layers were formed, and their growth rates and the laser crater sizes on them were studied. By optimization of the operational parameters in accordance with our design rule, it was shown that stablemore » output power was achieved continuously from the plasma emission at frequencies of 1–10 Hz. The average soft X-ray and EUV powers obtained were 19 mW at 3.2 nm, 33 mW at 10.0 nm, and 66 mW at 10.8 nm, with 10% bandwidths, from the Ar, Kr, and Xe solid targets, respectively, with a laser power of 1 W. We will be able to achieve higher frequencies using a high beam quality laser that produces smaller craters, and can expect higher powers. Although only Ar, Kr, and Xe gases were tested in this study, the target system achieved a temperature of 15 K and can thus solidify almost all target gases, apart from H and He, and can continuously supply the solid target. The use of various target materials will enable expansion of the EUV and soft X-ray emission wavelength range.« less
Characterization of Bioderived Polyhydroxyalkanoates by Size Exclusion Chromatography
NASA Astrophysics Data System (ADS)
Negulescu, Ioan; Cueto, Rafael; Rusch, Kelly; Gutierrez-Wing, Teresa; Stevens, Benjamin
2008-03-01
The plant derived polyesters, better known as polyhydroxyalkanoates, PHAs, are renewable and sustainable: [-O-CH(CH3)-(CH2)x-CO-]n. If x = 0 PHA is Poly(lactic acid), PLA; if x = 1 or 2 it is Poly(hydroxy butyrate), PHB, or Poly(hydroxy valerate), PHV. SEC and light scattering have been used before for determination of the absolute molecular mass of PLA dissolved in CHCl3 (Malmgren et al., J. Thermal Anal. Calorim., 2006, 83, 35-40). To our best knowledge there is no publication on the determination of the absolute MW of other PHAs. The bioderived polymers analyzed in this work were four catalog PHA samples: PHB Fluka 81329, PHB Natural Aldrich 363502, 95PHB/5PHV Aldrich 403105, and 92PHB/8PHV Aldrich 403113. SEC/LS instrumentation used: three Phenogel (1K-10000K) columns + a guard column, an Agilent pump and Wyatt Heleos MALS, QUELS (DLS), ViscoStar and rEX DRI detectors, all in series. The experimental dn/dc of PHB in CHCl3 (0.0336 ml/g at 658nm) allowed the determination of absolute MW of all PHA samples: PHB Fluka Mw 345,100 Mn 218,400; PHB Aldrich Mw 335,700 Mn 185,000; 92PHB/8PHV Mw 144,700 Mn 91,970; 95PHB/5PHV Mw 253,000 Mn 193,800.
Qu, Pengfei; Zhou, Jingran; Chen, Weiyou; Li, Fumin; Li, Haibin; Liu, Caixia; Ruan, Shengping; Dong, Wei
2010-04-20
We designed a microwave (MW) photonics phase shifter, consisting of a Fabry-Perot filter, a phase modulation region (PMR), and distributed Bragg reflectors, in a silicon-on-insulator rib waveguide. The thermo-optics effect was employed to tune the PMR. It was theoretically demonstrated that the linear MW phase shift of 0-2pi could be achieved by a refractive index variation of 0-9.68x10(-3) in an ultrawideband (about 38?GHz-1.9?THz), and the corresponding tuning resolution was about 6.92 degrees / degrees C. The device had a very compact size. It could be easily integrated in silicon optoelectronic chips and expected to be widely used in the high-frequency MW photonics field.
Tran, Ngoc Han; Ngo, Huu Hao; Urase, Taro; Gin, Karina Yew-Hoong
2015-10-01
The presence of organic matter (OM) in raw wastewater, treated wastewater effluents, and natural water samples has been known to cause many problems in wastewater treatment and water reclamation processes, such as treatability, membrane fouling, and the formation of potentially toxic by-products during wastewater treatment. This paper summarizes the current knowledge on the methods for characterization and quantification of OM in water samples in relation to wastewater and water treatment processes including: (i) characterization based on the biodegradability; (ii) characterization based on particle size distribution; (iii) fractionation based on the hydrophilic/hydrophobic properties; (iv) characterization based on the molecular weight (MW) size distribution; and (v) characterization based on fluorescence excitation emission matrix. In addition, the advantages, disadvantages and applications of these methods are discussed in detail. The establishment of correlations among biodegradability, hydrophobic/hydrophilic fractions, MW size distribution of OM, membrane fouling and formation of toxic by-products potential is highly recommended for further studies. Copyright © 2015 Elsevier Ltd. All rights reserved.
Global Value Chain and Manufacturing Analysis on Geothermal Power Plant Turbines
DOE Office of Scientific and Technical Information (OSTI.GOV)
Akar, Sertac; Augustine, Chad; Kurup, Parthiv
In this study, we have undertaken a robust analysis of the global supply chain and manufacturing costs for components of Organic Rankine Cycle (ORC) Turboexpander and steam turbines used in geothermal power plants. We collected a range of market data influencing manufacturing from various data sources and determined the main international manufacturers in the industry. The data includes the manufacturing cost model to identify requirements for equipment, facilities, raw materials, and labor. We analyzed three different cases; 1) 1 MW geothermal ORC Turboexpander 2) 5 MW ORC Turboexpander 3) 20 MW geothermal Steam Turbine
Bragg gratings inscription in step-index PMMA optical fiber by femtosecond laser pulses at 400 nm
NASA Astrophysics Data System (ADS)
Hu, X.; Kinet, D.; Chah, K.; Mégret, P.; Caucheteur, C.
2016-05-01
In this paper, we report photo-inscription of uniform Bragg gratings in trans-4-stilbenemethanol-doped photosensitive step-index polymer optical fiber. Gratings were produced at ~1575 nm by the phase mask technique with a femtosecond laser emitting at 400 nm with different average optical powers (8 mW, 13 mW and 20 mW). The grating growth dynamics in transmission were monitored during the manufacturing process, showing that the grating grows faster with higher power. Using 20 mW laser beam power, the reflectivity reaches 94 % (8 dB transmission loss) in 70 seconds. Finally, the gratings were characterized in temperature in the range 20 - 45 °C. The thermal sensitivity has been computed equal to - 86.6 pm/°C.
NASA Astrophysics Data System (ADS)
Mohammed, D. Z.; Khaleel, Wurood Abdulkhaleq; Al-Janabi, A. H.
2017-12-01
Ferro-oxide (Fe3O4) nanoparticles were used as a saturable absorber (SA) for a passively Q-switched erbium doped fiber laser (EDFL) with ring cavity. The Q-switching operation was achieved at a pump threshold of 80 mW. The proposed fiber laser produces stable pulses train of repetition rate ranging from 25 kHz to 80 kHz as the pump power increases from threshold to 342 mW. The minimum recorded pulse width was 2.7 μs at 342 mW. The C-band tunability operation was performed using single mode-multimode-single mode fiber (SM-MM-SM) structure. The laser exhibited a total tuning range of 7 nm, maximum sensitivity of 106.9 nm, optical signal to noise ratio (OSNR) of 38 dB and 3-dB linewidth of 0.06 nm.
Williams, J L; Garrick, D J; Speidel, S E
2009-05-01
Maintenance energy requirements of cattle can be predicted from published equations utilizing metabolic BW and milk production potential. Metabolic BW is a function of BW at a constant fat percentage or BCS. Pedigree and performance records can be used in random regression models to predict genetic merit for metabolic BW and milk production potentials. The purpose of this study was to present a methodology for predicting mature cow maintenance energy EPD using mature cow BW and BCS and accounting for prior selection of replacement females at weaning and yearling ages. Variance components were obtained for direct and maternal effects on weaning weight, direct effects on postweaning BW gain, and direct coefficients for random regression on mature weights (MW) adjusted for BCS. These BW were transformed into metabolic BW by taking BW to the power of 0.75, variance components were estimated for metabolic BW, and were then used to predict breeding values from which cow maintenance energy EPD could be derived. Data used in this analysis were obtained from the Red Angus Association of America and limited to herds with MW and corresponding BCS observations. The data set included 52,338 BW records on 21,103 individuals. Weaning and yearling contemporaries to those with MW observations, but with no MW records themselves, were included to account for selection occurring before maturity. Heritability estimates for weaning weight direct, weaning weight maternal, and postweaning BW gain were 0.18 +/- 0.02, 0.16 +/- 0.02, and 0.18 +/- 0.02, respectively. Mature BW observed at 2, 3, 4, 5, and 6 yr of age had heritability estimates of 0.45 +/- 0.03, 0.44 +/- 0.03, 0.49 +/- 0.03, 0.66 +/- 0.04, and 0.62 +/- 0.05, respectively. Correlations between weaning weight direct and MW ranged from 0.65 +/- 0.07 to 0.82 +/- 0.04, and correlations between MW at different ages ranged from 0.95 +/- 0.03 to 0.99 +/- 0.01. The genetic correlations between postweaning BW gain and MW ranged from 0.48 +/- 0.06 to 0.59 +/- 0.06. The 15-yr genetic increase in metabolic BW was 3.6 kg(0.75), greater than the value of 0.23 kg(0.75) obtained from the same data ignoring weaning and yearling contemporaries with unobserved MW, the approach currently used in the derivation of cow maintenance EPD published by the Red Angus Association of America.
Kastler, Adrian; Krainik, Alexandre; Sakhri, Linda; Mousseau, Mireille; Kastler, Bruno
2017-03-01
To evaluate feasibility of using a thermocouple for temperature monitoring during microwave (MW) ablation of metastatic bone disease. This retrospective study comprised 16 patients (8 men with mean age 63 y and 8 women with mean age 59 y) with 18 bone metastases treated with MW ablation using a thermocouple between March 2012 and October 2015. The mean maximum tumor size was 29.5 mm. MW ablation power was set between 15 W and 40 W and applied for 1-6 minutes. Thermocouple placements were as follows: epidural space (n = 7 cases), nerve roots (n = 9 cases), pleura (n = 1), and pericardium (n = 1). The procedure was considered technically successful when the MW and the thermocouple probes were accurately placed and thermoablation was initiated. Clinical success was defined as a 50% visual analog scale score decrease at 1 month as assessed by the operators. Mean MW ablation time was 4.3 minutes with a mean energy of 30 W. Procedural success was 100%. In 16 cases with neural structure monitoring, temperature did not increase > 43°C. In 8 cases, MW ablation had to be discontinued because of temperature reaching 42°C. Efficacy of the procedure in regard to pain was achieved in 17 of 18 ablation sessions at 1 month. Use of a thermocouple during bone MW ablation is a feasible technique and may be a potentially useful tool to help avoid nontarget ablation surrounding tumors. Copyright © 2016 SIR. Published by Elsevier Inc. All rights reserved.
Wang, Huaxin; Jiao, Ruyuan; Wang, Fang; Zhang, Lu; Yan, Weijin
2016-12-01
Dissolved organic carbon (DOC) plays diverse roles in carbon biogeochemical cycles. Here, we explored the link between DOC and pCO 2 using high-performance size-exclusion chromatography (HPSEC) with UV 254 detection and excitation emission matrix (EEM) fluorescence spectroscopy to determine the molecular weight distribution (MW) and the spectral characteristics of DOC, respectively. The relationship between DOC and pCO 2 was investigated in the Poyang Lake wetlands and their adjacent aquatic systems. The results indicated significant spatial variation in the DOC concentrations, MW distributions, and pCO 2 . The DOC concentration was higher in the wetlands than in the rivers and lakes. pCO 2 was high in wetlands in which the dominant vegetation was Phragmites australis, whereas it was low in wetlands in which Carex tristachya was the dominant species. DOC was divided into five fractions according to MW, as follows: super-low MW (SLMW, <1 kDa); low MW (LMW, 1-2.5 kDa); intermediate MW (IMW, 2.5-3.5 kDa); high MW (HMW, 3.5-6 kDa); and super-high MW (SMW, > 40 kDa). Rivers contained high proportions of HMW and extremely low amounts of SLMW, whereas wetlands had relatively high proportions of SLMW. The proportion of SMW (SMW p ) was particularly high in wetlands. We found that pCO 2 significantly positively correlated with the proportion of IMW, and significantly negatively correlated with SMW p . These data improve our understanding of the MW of bioavailable DOC and its conversion to CO 2 . The present results demonstrate that both the content and characteristics of DOC significantly affect pCO 2 . pCO 2 and DOC must be studied further to help understanding the role of the wetland on the regional CO 2 budget. Copyright © 2016 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fillos, J.; Khanbilvardi, R.
1993-09-01
The Fresh Kills Landfill is a 2400-acre site located on the western shore of Staten Island. The landfill is divided into several geographical sections, two of which, sections 1/9 and 6/7, will remain active for the near future. These sections will continue to produce leachate which will be collected and treated in an on-site facility. This volume presents the results of a series of leachate analyses and batch- and continuous-flow experiments designed to characterize the leachate and to develop loading criteria for a biological nitrogen removal process. The analyses showed that 57 percent of the organic matter in the leachatemore » falls below the 1,000 MW size while 14 percent is higher than 30,000 MW. Most of the organic matter is nonbiodegradable. Procedures applied to improve biodegradability, such as thermal and pH conditioning, and attempts to chemically oxidize the organic matter with ozone and hydrogen peroxide were not effective, demonstrating that the organic matter is stable and should persist indefinitely when released to the environment. However, biological nitrogen removal was extremely effective. Ammonia nitrification in excess of 99 percent was achieved in a sequencing batch reactor, using process loading rates in the range of 0.23 to 0.44 lb NH{sub 3}/lb MLVSS/day. Subsequent denitrification of the nitrites and nitrates required an external source of carbon. Methanol was used as the carbon source achieving complete denitrification in an anaerobic upflow reactor. Denitrification rates were measured in the range 62 to 125 lb NO{sub x}/1000 cu ft/day, with methanol to nitrogen ratio dosages in the rang 1.9 to 2.2 and retention time of approximately 10 hours.« less
Mansilla, Alberto V; Bivins, Eugene E; Contreras, Francisco; Hernandez, Manuel A; Kohler, Nathan; Pepe, Julie W
2017-02-01
To develop a scoring system that stratifies complexity of percutaneous ablation of renal tumors. Analysis was performed of 36 consecutive patients (mean age, 64 y; range, 30-89 y) who underwent CT-guided microwave (MW) ablation of 45 renal tumors (mean tumor diameter, 2.4 cm; range, 1.2-4.0 cm). Technical success and effectiveness were determined based on intraprocedural and follow-up imaging studies. The RENAL score and the proposed percutaneous renal ablation complexity (P-RAC) score were calculated for each tumor. Technical success was 93.3% (n = 42). Biopsy of 38 of 45 renal tumors revealed 23 renal cell carcinomas. Median follow-up period was 9.7 months (range, 2.9-46.8 months). There were no tumor recurrences. One major complication, ureteropelvic junction stricture, occurred (2.6%). The P-RAC score was found to differ statistically from the RENAL score (t = 3.754, df = 44, P = .001). A positive correlation was found between the P-RAC score and number of antenna insertions (r = .378, n = 45, P = .011) and procedure duration (r = .328, n = 45, P = .028). No correlation was found between the RENAL score and number of MW antenna insertions (r = .110, n = 45, P = .472) or procedure duration (r = .263, n = 45, P = .081). Hydrodissection was significantly more common in the P-RAC high-complexity category than in low-complexity category (χ 2 = 12.073, df = 2, P = .002). The P-RAC score may be useful in stratifying percutaneous renal ablation complexity. Further studies with larger sample sizes are necessary to validate the P-RAC score and to determine if it can predict risk of complications. Copyright © 2016 SIR. Published by Elsevier Inc. All rights reserved.
The paper describesd a direct thermal desorption (TDS) approach to determine the PAH composition (MW = 202-302 amu) in size-segregated aerosols from residential wood combustion (RWC). Six combustion tests are performed with two highly available wood fuel varieties, Douglas-fir (P...
The Formation of a Milky Way-sized Disk Galaxy. I. A Comparison of Numerical Methods
NASA Astrophysics Data System (ADS)
Zhu, Qirong; Li, Yuexing
2016-11-01
The long-standing challenge of creating a Milky Way- (MW-) like disk galaxy from cosmological simulations has motivated significant developments in both numerical methods and physical models. We investigate these two fundamental aspects in a new comparison project using a set of cosmological hydrodynamic simulations of an MW-sized galaxy. In this study, we focus on the comparison of two particle-based hydrodynamics methods: an improved smoothed particle hydrodynamics (SPH) code Gadget, and a Lagrangian Meshless Finite-Mass (MFM) code Gizmo. All the simulations in this paper use the same initial conditions and physical models, which include star formation, “energy-driven” outflows, metal-dependent cooling, stellar evolution, and metal enrichment. We find that both numerical schemes produce a late-type galaxy with extended gaseous and stellar disks. However, notable differences are present in a wide range of galaxy properties and their evolution, including star-formation history, gas content, disk structure, and kinematics. Compared to Gizmo, the Gadget simulation produced a larger fraction of cold, dense gas at high redshift which fuels rapid star formation and results in a higher stellar mass by 20% and a lower gas fraction by 10% at z = 0, and the resulting gas disk is smoother and more coherent in rotation due to damping of turbulent motion by the numerical viscosity in SPH, in contrast to the Gizmo simulation, which shows a more prominent spiral structure. Given its better convergence properties and lower computational cost, we argue that the MFM method is a promising alternative to SPH in cosmological hydrodynamic simulations.
THE FORMATION OF A MILKY WAY-SIZED DISK GALAXY. I. A COMPARISON OF NUMERICAL METHODS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhu, Qirong; Li, Yuexing, E-mail: qxz125@psu.edu
The long-standing challenge of creating a Milky Way- (MW-) like disk galaxy from cosmological simulations has motivated significant developments in both numerical methods and physical models. We investigate these two fundamental aspects in a new comparison project using a set of cosmological hydrodynamic simulations of an MW-sized galaxy. In this study, we focus on the comparison of two particle-based hydrodynamics methods: an improved smoothed particle hydrodynamics (SPH) code Gadget, and a Lagrangian Meshless Finite-Mass (MFM) code Gizmo. All the simulations in this paper use the same initial conditions and physical models, which include star formation, “energy-driven” outflows, metal-dependent cooling, stellarmore » evolution, and metal enrichment. We find that both numerical schemes produce a late-type galaxy with extended gaseous and stellar disks. However, notable differences are present in a wide range of galaxy properties and their evolution, including star-formation history, gas content, disk structure, and kinematics. Compared to Gizmo, the Gadget simulation produced a larger fraction of cold, dense gas at high redshift which fuels rapid star formation and results in a higher stellar mass by 20% and a lower gas fraction by 10% at z = 0, and the resulting gas disk is smoother and more coherent in rotation due to damping of turbulent motion by the numerical viscosity in SPH, in contrast to the Gizmo simulation, which shows a more prominent spiral structure. Given its better convergence properties and lower computational cost, we argue that the MFM method is a promising alternative to SPH in cosmological hydrodynamic simulations.« less
Streamflow responses in Chile to megathrust earthquakes in the 20th and 21st centuries
NASA Astrophysics Data System (ADS)
Mohr, Christian; Manga, Michael; Wang, Chi-yuen; Korup, Oliver
2016-04-01
Both coseismic static stress and dynamic stresses associated with seismic waves may cause responses in hydrological systems. Such responses include changes in the water level, hydrochemistry and streamflow discharge. Earthquake effects on hydrological systems provide a means to study the interaction between stress changes and regional hydrology, which is otherwise rarely possible. Chile is a country of frequent and large earthquakes and thus provides abundant opportunities to study such interactions and processes. We analyze streamflow responses in Chile to several megathrust earthquakes, including the 1943 Mw 8.1 Coquimbo, 1950 Mw 8.2 Antofagasta, 1960 Mw 9.5 Valdivia, 1985 Mw 8.0 Valparaiso, 1995 Mw 8.0 Antofagasta, 2010 Mw 8.8 Maule, and the 2014 Mw 8.2 Iquique earthquakes. We use data from 716 stream gauges distributed from the Altiplano in the North to Tierra del Fuego in the South. This network covers the Andes mountain ranges, the central valley, the Coastal Mountain ranges and (mainly in the more southern parts) the Coastal flats. We combine empirical magnitude-distance relationships, machine learning tools, and process-based modeling to characterize responses. We first assess the streamflow anomalies and relate these to topographical, hydro-climatic, geological and earthquake-related (volumetric and dynamic strain) factors using various classifiers. We then apply 1D-groundwater flow modeling to selected catchments in order to test competing hypotheses for the origin of streamflow changes. We show that the co-seismic responses of streamflow mostly involved increasing discharges. We conclude that enhanced vertical permeability can explain most streamflow responses at the regional scale. The total excess water released by a single earthquake, i.e. the Maule earthquake, yielded up to 1 km3. Against the background of megathrust earthquakes frequently hitting Chile, the amount of water released by earthquakes is substantial, particularly for the arid northern areas that depend exclusively on groundwater resources.
Estimating Seismic Moment From Broadband P-Waves for Tsunami Warnings.
NASA Astrophysics Data System (ADS)
Hirshorn, B. F.
2006-12-01
The Richard H. Hagemeyer Pacific Tsunami Warning Center (PTWC), located in Ewa Beach, Oahu, Hawaii, is responsible for issuing local, regional, and distant tsunami warnings to Hawaii, and for issuing regional and distant tsunami warnings to the rest of the Pacific Basin, exclusive of the US West Coast. The PTWC must provide these tsunami warnings as soon as technologically possible, based entirely on estimates of a potentially tsunamigenic earthquake's source parameters. We calculate the broadband P-wave moment magnitude, Mwp, from the P or pP wave velocity seismograms [Tsuboi et al., 1995, 1999]. This method appears to work well for regional and teleseismic events [ Tsuboi et al (1999], Whitmore et al (2002), Hirshorn et al (2004) ]. Following Tsuboi, [1995], we consider the displacement record of the P-wave portion of the broadband seismograms as an approximate source time function and integrate this record to obtain the moment rate function, Mo(t), and the moment magnitude [Hanks and Kanamori, 1972] as a function of time, Mw(t). We present results for Mwp for local, regional, and teleseismic broad band recordings for earthquakes in the Mw 5 to 9.3 range. As large Hawaii events are rare, we tested this local case using other Pacific events in the magnitude 5.0 to 7.5 range recorded by nearby stations. Signals were excluded, however, if the epicentral distance was so small (generally less than 1 degree) that there was contamination by the S-wave too closely following the P-waves. Scatter plots of Mwp against the Harvard Mw for these events shows that Mwp does predict Mw well from seismograms recorded at local, regional, and teleseismic distances. For some complex earthquakes, eg. the Mw 8.4(HRV) Peru earthquake of June 21, 2001, Mwp underestimates Mw if the first moment release is not the largest. Our estimates of Mwp for the Mw 9.3 Summatra-Andaman Island's earthquake of December 26, 2004 and for the Mw 8.7 (HRV) Summatra event of March 28, 2005, were Mwp 8.1, Mwp 8.7 respectively, from p-waves recorded at 15 - 90 degrees from each hypocenter.
Generation and composition of medical wastes from private medical microbiology laboratories.
Komilis, Dimitrios; Makroleivaditis, Nikolaos; Nikolakopoulou, Eftychia
2017-03-01
A study on the generation rate and the composition of solid medical wastes (MW) produced by private medical microbiology laboratories (PMML) was conducted in Greece. The novelty of the work is that no such information exists in the literature for this type of laboratories worldwide. Seven laboratories were selected with capacities that ranged from 8 to 88 examinees per day. The study lasted 6months and daily recording of MW weights was done over 30days during that period. The rates were correlated to the number of examinees, examinations and personnel. Results indicated that on average 35% of the total MW was hazardous (infectious) medical wastes (IFMW). The IFMW generation rates ranged from 11.5 to 32.5g examinee -1 d -1 while an average value from all 7 labs was 19.6±9.6g examinee -1 d -1 or 2.27±1.11g examination -1 d -1 . The average urban type medical waste generation rate was 44.2±32.5g examinee -1 d -1 . Using basic regression modeling, it was shown that the number of examinees and examinations can be predictors of the IFMW generation, but not of the urban type MW generation. The number of examinations was a better predictor of the MW amounts than the number of examinees. Statistical comparison of the means of the 7PMML was done with standard ANOVA techniques after checking the normality of the data and after doing the appropriate transformations. Based on the results of this work, it is approximated that 580 tonnes of infectious MW are generated annually by the PMML in Greece. Copyright © 2017 Elsevier Ltd. All rights reserved.
Partyla, Tomasz; Hacker, Henriette; Edinger, Hardy; Leutzow, Bianca; Lange, Joern; Usichenko, Taras
2017-03-01
The hypoalgesic effect of electromagnetic millimeter waves (MW) is well studied in animal model; however, the results of human research are controversial. The aim of this study was to evaluate the effects of various frequency ranges of MW on hypoalgesia using the cold pressor test (CPT). Experimental pain was induced using standardized CPT protocols in 20 healthy male volunteers. The skin of the lower part of sternum was exposed to MW with a frequency of 42.25 GHz (active generator); MW within 50-75 GHz frequency range (noise generator); or an inactive MW device (placebo generator) in a random crossover double-blinded manner. Pain threshold, measured using the CPT, was the primary outcome. Other CPT parameters, heart rate, blood pressure, incidence of subjective sensations (paresthesia) during exposure, as well as quality of volunteers' blinding were also recorded. The end points of the condition with exposure to 42.25 GHz, were compared with baseline; exposure to noise 50-75 GHz; and placebo generators. Pain threshold increased during exposure to the 42.25 GHz generator when compared with baseline: median difference (MD), 1.97 seconds (95% confidence interval [CI], 0.35-3.73) and noise generator: MD, 1.27 seconds (95% CI, 0.05-2.33) but not compared with the placebo generator. Time to onset of cold and increasing pain sensations as well as diastolic blood pressure increased under the exposure to the 42.25 GHz generator when compared with baseline and noise generator. Other outcome measures were comparable among the study conditions. We were able to partially confirm the previously suggested hypoalgesic effects of low-intensity electromagnetic MW. However, the effect was indistinguishable from the placebo condition in our investigation.
Quantitative Research on the Minimum Wage
ERIC Educational Resources Information Center
Goldfarb, Robert S.
1975-01-01
The article reviews recent research examining the impact of minimum wage requirements on the size and distribution of teenage employment and earnings. The studies measure income distribution, employment levels and effect on unemployment. (MW)
NASA Technical Reports Server (NTRS)
Ichoku, Charles; Giglio, Louis; Wooster, Martin J.; Remer, Lorraine A.
2008-01-01
Remote sensing is the most practical means of measuring energy release from large open-air biomass burning. Satellite measurement of fire radiative energy (FRE) release rate or power (FRP) enables distinction between fires of different strengths. Based on a 1-km resolution fire data acquired globally by the MODerate-resolution Imaging Spectro-radiometer (MODIS) sensor aboard the Terra and Aqua satellites from 2000 to 2006, instanteaneous FRP values ranged between 0.02 MW and 1866 MW, with global daily means ranging between 20 and 40 MW. Regionally, at the Aqua-MODIS afternoon overpass, the mean FRP values for Alaska, Western US, Western Australia, Quebec and the rest of Canada are significantly higher than these global means, with Quebec having the overall highest value of 85 MW. Analysis of regional mean FRP per unit area of land (FRP flux) shows that a peak fire season in certain regions, fires can be responsible for up to 0.2 W/m(sup 2) at peak time of day. Zambia has the highest regional monthly mean FRP flux of approximately 0.045 W/m(sup 2) at peak time of day and season, while the Middle East has the lowest value of approximately 0.0005 W/m(sup 2). A simple scheme based on FRP has been devised to classify fires into five categories, to facilitate fire rating by strength, similar to earthquakes and hurricanes. The scheme uses MODIS measurements of FRP at 1-km resolution as follows: catagory 1 (less than 100 MW), category 2 (100 to less than 500 MW), category 3 (500 to less than 1000 MW), category 4 (1000 to less than 1500 MW), catagory 5 (greater than or equal to 1500 MW). In most regions of the world, over 90% of fires fall into category 1, while only less than 1% fall into each of categories 3 to 5, although these proportions may differ significantly from day to day and by season. The frequency of occurence of the larger fires is region specific, and could not be explained by ecosystem type alone. Time-series analysis of the propertions of higher category fires based on MODIS measured FRP from 2002 to 2006 does not show any moticeable trend because of the short time period.
Size-Dependent Particle Dynamics in Entangled Polymer Nanocomposites
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mangal, Rahul; Srivastava, Samanvaya; Narayanan, Suresh
Polymer-grafted nanoparticles with diameter d homogeneously dispersed in entangled polymer melts with varying random coil radius R0, but fixed entanglement mesh size ae, are used to study particle motions in entangled polymers. We focus on materials in the transition region between the continuum regime (d > R0), where the classical Stokes-Einstein (S-E) equation is known to describe polymer drag on particles, and the non-continuum regime (d < ae), in which several recent studies report faster diffusion of particles than expected from continuum S-E analysis, based on the bulk polymer viscosity. Specifically, we consider dynamics of particles with sizes d ≥more » ae in entangled polymers with varying molecular weight Mw in order to investigate how the transition from non-continuum to continuum dynamics occur. We take advantage of favorable enthalpic interactions between SiO2 nanoparticles tethered with PEO molecules and entangled PMMA host polymers to create model nanoparticle-polymer composites, in which spherical nanoparticles are uniformly dispersed in entangled polymers. Investigation of the particle dynamics via X-ray photon correlation spectroscopy measurements reveal a transition from fast to slow particle motion as the PMMA molecular weight is increased beyond the entanglement threshold, with a much weaker Mw dependence for Mw>Me than expected from S-E analysis based on bulk viscosity of entangled PMMA melts. We rationalize these observations using a simple force balance analysis around particles and find that nanoparticle motion in entangled melts can be described using a variant of the S-E analysis in which motion of particles is assumed to only disturb sub-chain entangled host segments with sizes comparable to the particle diameter.« less
Size-Dependent Particle Dynamics in Entangled Polymer Nanocomposites.
Mangal, Rahul; Srivastava, Samanvaya; Narayanan, Suresh; Archer, Lynden A
2016-01-19
Polymer-grafted nanoparticles with diameter d homogeneously dispersed in entangled polymer melts with varying random coil radius R0, but fixed entanglement mesh size a(e), are used to study particle motions in entangled polymers. We focus on materials in the transition region between the continuum regime (d > R0), where the classical Stokes-Einstein (S-E) equation is known to describe polymer drag on particles, and the noncontinuum regime (d < a(e)), in which several recent studies report faster diffusion of particles than expected from continuum S-E analysis, based on the bulk polymer viscosity. Specifically, we consider dynamics of particles with sizes d ≥ a(e) in entangled polymers with varying molecular weight M(w) in order to investigate how the transition from noncontinuum to continuum dynamics occur. We take advantage of favorable enthalpic interactions between SiO2 nanoparticles tethered with PEO molecules and entangled PMMA host polymers to create model nanoparticle-polymer composites, in which spherical nanoparticles are uniformly dispersed in entangled polymers. Investigation of the particle dynamics via X-ray photon correlation spectroscopy measurements reveals a transition from fast to slow particle motion as the PMMA molecular weight is increased beyond the entanglement threshold, with a much weaker M(w) dependence for M(w) > M(e) than expected from S-E analysis based on bulk viscosity of entangled PMMA melts. We rationalize these observations using a simple force balance analysis around particles and find that nanoparticle motion in entangled melts can be described using a variant of the S-E analysis in which motion of particles is assumed to only disturb subchain entangled host segments with sizes comparable to the particle diameter.
NASA Astrophysics Data System (ADS)
Men, Shaojie; Liu, Zhaojun; Cong, Zhenhua; Rao, Han; Zhang, Sasa; Liu, Yang; Zverev, Petr G.; Konyushkin, Vasily A.; Zhang, Xingyu
2016-02-01
High-repetition-rate tunable LiF:\\text{F}2- color center lasers pumped by quasi-continuous-wave diode-side-pumped acousto-optically Q-switched Nd:YAG laser are demonstrated. Littrow-grating and Littman-grating tuning schemes are studied respectively. In the Littrow-grating scheme, the tuning range was 1085 nm to 1275 nm, and the maximal average output power was 275 mW. In the Littman-grating scheme, the tuning range was 1105.5 nm to 1215.5 nm, and the maximal average output power was 135 mW.
Feasibility of ultra-wideband SAW RFID tags meeting FCC rules.
Härmä, Sanna; Plessky, Victor P; Li, Xianyi; Hartogh, Paul
2009-04-01
We discuss the feasibility of surface acoustic wave (SAW) radio-frequency identification (RFID) tags that rely on ultra-wideband (UWB) technology. We propose a design of a UWB SAW tag, carry out numerical experiments on the device performance, and study signal processing in the system. We also present experimental results for the proposed device and estimate the potentially achievable reading distance. UWB SAW tags will have an extremely small chip size (<0.5 x 1 mm(2)) and a low cost. They also can provide a large number of different codes. The estimated read range for UWB SAW tags is about 2 m with a reader radiating as low as <0.1 mW power levels with an extremely low duty factor.
Dong, Bingzhi; Gui, Bo; Liu, Junxia; Wang, Zhihong; Tan, Kaiting
2018-06-01
This paper analysed organic foulants in the coagulation-microfiltration process for Taihu Lake treatment. High-performance size-exclusion chromatography (HPSEC) and fluorescence excitation-emission matrices (EEM) were applied to elucidate the influence of characteristics of organics on microfiltration (MF) membrane fouling. Results showed that coagulation pretreatment could extend the operation duration of MF based on the fact that pretreatment could effectively remove macromolecular substances as well as a portion of small molecular weight (MW) organics. The analysis of foulants indicated that organics of strong hydrophobic acids (SHA) and neutral hydrophilic (Neut) fractions (based on hydrophobicity) and medium and small MW components (based on MW distribution) contributed greatly to irreversible fouling. EEM fluorescence analysis of chemical solutions exhibited that aromatic proteins and soluble microbial products were mainly a response to irreversible fouling.
Yu, Minda; He, Xiaosong; Liu, Jiaomei; Wang, Yuefeng; Xi, Beidou; Li, Dan; Zhang, Hui; Yang, Chao
2018-04-14
Understanding the heterogeneous evolution characteristics of dissolved organic matter fractions derived from compost is crucial to exploring the composting biodegradation process and the possible applications of compost products. Herein, two-dimensional correlation spectroscopy integrated with reversed-phase high performance liquid chromatography and size exclusion chromatography were utilized to obtain the molecular weight (MW) and polarity evolution characteristics of humic acid (HA), fulvic acid (FA), and the hydrophilic (HyI) fractions during composting. The high-MW humic substances and building blocks in the HA fraction degraded faster during composting than polymers, proteins, and organic colloids. Similarly, the low MW acid FA factions transformed faster than the low weight neutral fractions, followed by building blocks, and finally polymers, proteins, and organic colloids. The evolutions of HyI fractions during composting occurred first for building blocks, followed by low MW acids, and finally low weight neutrals. With the progress of composting, the hydrophobic properties of the HA and FA fractions were enhanced. The degradation/humification process of the hydrophilic and transphilic components was faster than that of the hydrophobic component. Compared with the FA and HyI fractions, the HA fraction exhibited a higher MW and increased hydrophobicity. Copyright © 2018 Elsevier B.V. All rights reserved.
Matsuyama, K; Mishima, K; Umemoto, H; Yamaguchi, S
2001-10-15
A novel method is reported for forming polymer microparticles, which reduce atmospheric emissions of environmentally harmful volatile organic compounds such as toluene and xylene used as paint solvent in paint industry. The polymer microparticles have formed through rapid expansion from supercritical solution with a nonsolvent (RESS-N). Solubilization of poly(styrene)-b-(poly(methyl methacrylate)-co-poly (glycidyl methacrylate)) copolymer(PS-b-(PMMA-co-PGMA), MW = 5000, PS/PMMA/PGMA = 2/5/3), poly(ethylene glycol) (PEG, M. W = 4000), bisphenol A type epoxy resin (EP, MW = 3000), poly(methyl methacrylate) (PMMA; MW = 15000, 75000, 120000), and poly(oxyalkylene) alkylphenyl ether (MW = 4000) in carbon dioxide (CO2) was achieved with the use of small alcohols as cosolvents. The solubility of the PS-b-(PMMA-co-PGMA) is extremely low in either CO2 or ethanol but becomes 20 wt % in a mixture of the two. Because ethanol is a nonsolvent for the polymer, it can be used as a cosolvent in rapid expansion from supercritical solution to produce 1-3 microm particles that do not agglomerate. Obtained polymer particles by RESS-N were applied as powder coatings. The resulting coatings have a smooth and coherent film. The particle size distribution of microspheres was controlled by changing the polymer concentration, preexpansion pressure, temperature, and injection distance. The feed compositions were more effective than the other factors in controlling the particle size. The polymeric microparticles formed by RESS-N method can be utilized to make the thin coating film without anytoxic organic solvents and/or surfactants.
Dong, Ban Xuan; Smith, Mitchell; Strzalka, Joseph; ...
2018-02-06
In this work, poly(3-hexylthiophene) (P3HT) films prepared using the matrix-assisted pulsed laser evaporation (MAPLE) technique are shown to possess morphological structures that are dependent on molecular weight (MW). Specifically, the structures of low MW samples of MAPLE-deposited film are composed of crystallites/aggregates embedded within highly disordered environments, whereas those of high MW samples are composed of aggregated domains connected by long polymer chains. Additionally, the crystallite size along the side-chain (100) direction decreases, whereas the conjugation length increases with increasing molecular weight. This is qualitatively similar to the structure of spin-cast films, though the MAPLE-deposited films are more disordered. In-planemore » carrier mobilities in the MAPLE-deposited samples increase with MW, consistent with the notion that longer chains bridge adjacent aggregated domains thereby facilitating more effective charge transport. The carrier mobilities in the MAPLE-deposited simples are consistently lower than those in the solvent-cast samples for all molecular weights, consistent with the shorter conjugation length in samples prepared by this deposition technique.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dong, Ban Xuan; Smith, Mitchell; Strzalka, Joseph
In this work, poly(3-hexylthiophene) (P3HT) films prepared using the matrix-assisted pulsed laser evaporation (MAPLE) technique are shown to possess morphological structures that are dependent on molecular weight (MW). Specifically, the structures of low MW samples of MAPLE-deposited film are composed of crystallites/aggregates embedded within highly disordered environments, whereas those of high MW samples are composed of aggregated domains connected by long polymer chains. Additionally, the crystallite size along the side-chain (100) direction decreases, whereas the conjugation length increases with increasing molecular weight. This is qualitatively similar to the structure of spin-cast films, though the MAPLE-deposited films are more disordered. In-planemore » carrier mobilities in the MAPLE-deposited samples increase with MW, consistent with the notion that longer chains bridge adjacent aggregated domains thereby facilitating more effective charge transport. The carrier mobilities in the MAPLE-deposited simples are consistently lower than those in the solvent-cast samples for all molecular weights, consistent with the shorter conjugation length in samples prepared by this deposition technique.« less
Regeneration of acid orange 7-exhausted granular activated carbons with microwave irradiation.
Quan, Xie; Liu, Xitao; Bo, Longli; Chen, Shuo; Zhao, Yazhi; Cui, Xinyi
2004-12-01
An investigation was performed for the regeneration of three granular activated carbons (GACs) exhausted with acid orange 7 (AO7). The three GACs were made from different materials, i.e. coconut shells, almond nucleus and coal. The AO7 adsorption process was carried out in a continuous-flow adsorption column. After adsorption, the AO7-saturated GAC was dried at 120 degrees C, then regenerated in a quartz reactor by 2450 MHz microwave (MW) irradiation at 850 W for 5 min. The efficacy of this procedure was analyzed by determining the rates and amounts of AO7 adsorbed in successive adsorption-MW regeneration cycles. Effects of this regeneration on the structural properties, surface chemistry and the AO7 adsorption capacities of GAC samples were examined. It was found that after several adsorption-MW regeneration cycles, the adsorption rates and capacities of GACs could maintain relatively high levels, even higher than those of virgin GACs, as indicated by AO7 breakthrough curves and adsorption isotherms. The improvement of GAC adsorption properties resulted from the modification of pore size distribution and surface chemistry by MW irradiation.
Failure of self-similarity for large (Mw > 81/4) earthquakes.
Hartzell, S.H.; Heaton, T.H.
1988-01-01
Compares teleseismic P-wave records for earthquakes in the magnitude range from 6.0-9.5 with synthetics for a self-similar, omega 2 source model and conclude that the energy radiated by very large earthquakes (Mw > 81/4) is not self-similar to that radiated from smaller earthquakes (Mw < 81/4). Furthermore, in the period band from 2 sec to several tens of seconds, it is concluded that large subduction earthquakes have an average spectral decay rate of omega -1.5. This spectral decay rate is consistent with a previously noted tendency of the omega 2 model to overestimate Ms for large earthquakes.-Authors
NASA Technical Reports Server (NTRS)
Wu, Dongliang L.
2017-01-01
Clouds, ice clouds in particular, are a major source of uncertainty in climate models. Submm-wave sensors fill the sensitivity gap between MW and IR.Cloud microphysical properties (particle size and shape) account for large (200 and 40) measurement uncertainty.
McRae, Jacqui M; Kirby, Nigel; Mertens, Haydyn D T; Kassara, Stella; Smith, Paul A
2014-07-23
The molecular size of wine tannins can influence astringency, and yet it has been unclear as to whether the standard methods for determining average tannin molecular weight (MW), including gel-permeation chromatography (GPC) and depolymerization reactions, are actually related to the size of the tannin in wine-like conditions. Small-angle X-ray scattering (SAXS) was therefore used to determine the molecular sizes and corresponding MWs of wine tannin samples from 3 and 7 year old Cabernet Sauvignon wine in a variety of wine-like matrixes: 5-15% and 100% ethanol; 0-200 mM NaCl and pH 3.0-4.0, and compared to those measured using the standard methods. The SAXS results indicated that the tannin samples from the older wine were larger than those of the younger wine and that wine composition did not greatly impact on tannin molecular size. The average tannin MWs as determined by GPC correlated strongly with the SAXS results, suggesting that this method does give a good indication of tannin molecular size in wine-like conditions. The MW as determined from the depolymerization reactions did not correlate as strongly with the SAXS results. To our knowledge, SAXS measurements have not previously been attempted for wine tannins.
Yu, Wenzheng; Liu, Teng; Crawshaw, John; Liu, Ting; Graham, Nigel
2018-08-01
The fouling of ultrafiltration (UF) and nanofiltration (NF) membranes during the treatment of surface waters continues to be of concern and the particular role of natural organic matter (NOM) requires further investigation. In this study the effect of pH and surface charge on membrane fouling during the treatment of samples of a representative surface water (Hyde Park recreational lake) were evaluated, together with the impact of pre-ozonation. While biopolymers in the surface water could be removed by the UF membrane, smaller molecular weight (MW) fractions of NOM were poorly removed, confirming the importance of membrane pore size. For NF membranes the removal of smaller MW fractions (800 Da-10 kDa) was less than expected from their pore size; however, nearly all of the hydrophobic, humic-type substances could be removed by the hydrophilic NF membranes for all MW distributions (greater than 90%). The results indicated the importance of the charge and hydrophilic nature of the NOM. Thus, the hydrophilic NF membrane could remove the hydrophobic organic matter, but not the hydrophilic substances. Increasing charge effects (more negative zeta potentials) with increasing solution pH were found to enhance organics removal and reduce fouling (flux decline), most likely through greater membrane surface repulsion. Pre-ozonation of the surface water increased the hydrophilic fraction and anionic charge of NOM and altered their size distributions. This resulted in a decreased fouling (less flux decline) for the UF and smaller pore NF, but a slight increase in fouling for the larger pore NF. The differences in the NF behavior are believed to relate to the relative sizes of ozonated organic fractions and the NF pores; a similar size of ozonated organic fractions and the NF pores causes significant membrane fouling. Copyright © 2018 The Authors. Published by Elsevier Ltd.. All rights reserved.
2013-01-01
Introduction Inflammation of the synovial membrane plays an important role in the pathophysiology of osteoarthritis (OA). The synovial tissue of patients with initial OA is characterized by infiltration of mononuclear cells and production of proinflammatory cytokines and other mediators of joint injury. The objective was to evaluate the effect of low-level laser therapy (LLLT) operating at 50 mW and 100 mW on joint inflammation in rats induced by papain, through histopathological analysis, differential counts of inflammatory cells (macrophages and neutrophils), as well as gene expression of interleukin 1-beta and 6 (IL-1β and IL-6), and protein expression of tumor necrosis factor alpha (TNFα). Methods Male Wistar rats (n = 60) were randomly divided into four groups of 15 animals, namely: a negative control group; an inflammation injury positive control group; a 50 mW LLLT group, subjected to injury and treated with 50 mW LLLT; and a 100 mW LLLT group, subjected to injury and treated with 100 mW LLLT. The animals were subject to joint inflammation (papain solution, 4%) and then treated with LLLT (808 nm, 4 J, 142.4 J/cm2, spot size 0.028 for both groups). On the day of euthanasia, articular lavage was collected and immediately centrifuged; the supernatant was saved for analysis of expression of TNFα protein by enzyme-linked immunosorbent assay and expression of IL-1β and IL-6 mRNA by real-time polymerase chain reaction. A histologic examination of joint tissue was also performed. For the statistical analysis, analysis of variance with Tukey's post-hoc test was used for comparisons between each group. All data are expressed as mean values and standard deviation, with P < 0.05. Results Laser treatment with 50 mW was more efficient than 100 mW in reducing cellular inflammation, and decreased the expression of IL-1β and IL-6. However, the 100 mW treatment led to a higher reduction of TNFα compared with the 50 mW treatment. Conclusions LLLT with 50 mW was more efficient in modulating inflammatory mediators (IL-1β, IL-6) and inflammatory cells (macrophages and neutrophils), which correlated with the histology that showed a reduction in the inflammatory process. PMID:24028507
NASA Astrophysics Data System (ADS)
Rhodes, N.; Hurtado, J. M.
2013-05-01
Features such as the Home Plate plateau on Mars, a suspected remnant of a phreatomagmatic eruption, can reveal important information about paleohydrologic conditions. The types and sizes of pyroclastic rocks produced by a phreatomagmatic eruption are indicative of the behavior of the explosion and the characteristics of the groundwater reservoir. Analysis of the pyroclast size distribution can be used to determine magma volatile content. We conduct an analysis of pyroclast size distribution using Ground Penetrating Radar (GPR) to make a quantitative estimate of the presence of past groundwater at Kilbourne Hole, a well-known phreatomagmatic crater located in southern Dona Ana County, New Mexico. As basaltic magma intruded the groundwater reservoir in the mid-Pleistocene, the water vaporized and caused a phreatomagmatic explosion that excavated the 2-km wide and 200-m deep depression. The pyroclastic units produced during a phreatomagmatic explosion are proportional to the size and the duration of the explosion and the size of the groundwater reservoir such that the wetter the eruption, the stronger the explosion. In a violent volcanic eruption, magma changes from a liquid into solid fragments and the explosion releases kinetic energy (Ek) by ejecting liquid water, vapor water (with mass Mw) and solid fragments (with mass Mf) at an ejection velocity (Ve). In order to determine Mw, we must know Ve. The relationship between Ve and the distance from center of the eruption (R) is such that Ve exponentially decreases with time (t) and R. A numerical model relating pyroclast size and Ve for material ejected in Hawaiian and Plinian eruptions shows that clast size also exponentially decreases with decreasing Ve. Based on these relationships, we use GPR to map the ejected clast size distribution as a function of distance from the edge of Kilbourne Hole in an effort to determine Ve and Mw. GPR surveys were performed in January 2012 and January 2013 using a Noggins 250 MHz radar system. We designed the surveys to detect volcanic bombs in the shallow subsurface and to map radial variations in their sizes. Six GPR lines were extended radially in each cardinal direction from the rim of Kilbourne Hole, and, as a control, fifteen short GPR lines were performed along an accessible cliff where visible volcanic bombs and blocks are exposed. We are able to visualize 58 bombs and blocks along one of the six GPR lines within the maximum penetration depth of 2.4-3.2 m. From the resulting GPR profiles, we measured the width and the length of the bombs. The largest dimension of each bomb was plotted against distance from crater rim, and the obtained exponential relationship between bomb size and distance will be applied to a numerical model of ejecta dispersal from transient volcanic explosions to solve for Ve and Mw. This case study at Kilbourne Hole serves as a planetary analog for similar surveys that could be done on Mars and on the Moon.
NASA Astrophysics Data System (ADS)
Hoffacker, M. K.; Hernandez, R. R.; Field, C. B.
2013-12-01
Solar energy is an archetype renewable energy technology with great potential to reduce greenhouse gas emissions when substituted for carbon-intensive energy. Utility-scale solar energy (USSE; i.e., > 1 MW) necessitates large quantities of space making the efficient use of land for USSE development critical to realizing its full potential. However, studies elucidating the interaction between land-use and utility-scale solar energy (USSE) are limited. In this study, we assessed 1) the theoretical and technical potential of terrestrial-based USSE systems, and 2) land-use and land-cover change impacts from actual USSE installations (> 20 MW; planned, under construction, operating), using California as a case study due to its early adoption of renewable energy systems, unique constraints on land availability, immense energy demand, and vast natural resources. We used topo-climatic (e.g., slope, irradiance), infrastructural (e.g., proximity to transmission lines), and ecological constraints (e.g., threatened and endangered species) to determine highly favorable, favorable, and unfavorable locations for USSE and to assess its technical potential. We found that the theoretical potential of photovoltaic (PV) and concentrating solar power (CSP) in California is 26,097 and 29,422 kWh/m2/day, respectively. We identified over 150 planned, under construction, and operating USSE installations in California, ranging in size from 20 to 1,000 MW. Currently, 29% are located on shrub- and scrublands, 23% on cultivated crop land, 13% on pasture/hay areas, 11% on grassland/herbaceous and developed open space, and 7% in the built environment. Understanding current land-use decisions of USSE systems and assessing its future potential can be instructive for achieving land, energy, and environmental compatibility, especially for other global regions that share similar resource demands and limitations.
NASA Astrophysics Data System (ADS)
Rappolee, E.; Burk, D. R.; Mackey, K. G.; Fujita, K.; Shibaev, S. V.; Koz'min, B. M.
2016-12-01
The details of the seismotectonics along the boundary between the Eurasian, North American, and Okhotsk plates are poorly understood. Infrequent earthquakes of moderate size (Mw > 4) in this remote region make it difficult to characterize its tectonic activity. On February 14, 2013, an Mw 6.7 earthquake along this boundary in Northern Yakutia, Russia, resulted in a long sequence of aftershocks that provide an opportunity to better understand the region's geology. A temporary deployment of four seismic stations was installed around the main shock to supplement regional station coverage. During the ten day deployment, several thousand aftershocks were recorded. We have located 112 events using both first-arriving Pn and Sn and secondary arriving Pg and Sg phase time picks. The located aftershocks define a SSE striking zone approximately 30 km long and 10 km wide, east of the Illin'-Tas fault and northwest of the Indigirka River. Location depths range from 0 to 20 km. In conjunction with locating aftershocks, a local three-layer best-fit velocity was determined consisting of an upper crust (14 km thick, VPg = 6.06 km/s and VSg = 3.53 km/s), a lower crust (21 km thick, VP* = 6.45 km/s and VS* = 3.65 km/s), and a Moho (35 km deep, VPn = 7.98 km/s and VSn = 4.53 km/s). The mainshock epicenter falls in the northwestern corner of the aftershock zone, however its focal depth is not well established. Aftershock analysis is ongoing and will possibly provide a better understanding of the earthquake rupture zone. Nonetheless, results of this study support active thrusting and mountain building as a mechanism to accommodate compression along the North America-Eurasia boundary.
NASA Astrophysics Data System (ADS)
Dixon, Keri L.; Iliev, Ilian T.; Gottlöber, Stefan; Yepes, Gustavo; Knebe, Alexander; Libeskind, Noam; Hoffman, Yehuda
2018-06-01
Observations of the Milky Way (MW), M31, and their vicinity, known as the Local Group (LG), can provide clues about the sources of reionization. We present a suite of radiative transfer simulations based on initial conditions provided by the Constrained Local UniversE Simulations (CLUES) project that are designed to recreate the Local Universe, including a realistic MW-M31 pair and a nearby Virgo. Our box size (91 Mpc) is large enough to incorporate the relevant sources of ionizing photons for the LG. We employ a range of source models, mimicking the potential effects of radiative feedback for dark matter haloes between {˜ }10^8 and 10^9 M_{⊙}. Although the LG mostly reionizes in an inside-out fashion, the final 40 per cent of its ionization shows some outside influence. For the LG satellites, we find no evidence that their redshift of reionization is related to the present-day mass of the satellite or the distance from the central galaxy. We find that fewer than 20 per cent of present-day satellites for MW and M31 have undergone any star formation prior to the end of global reionization. Approximately 5 per cent of these satellites could be classified as fossils, meaning the majority of star formation occurred at these early times. The more massive satellites have more cumulative star formation prior to the end of global reionization, but the scatter is significant, especially at the low-mass end. Present-day mass and distance from the central galaxy are poor predictors for the presence of ancient stellar populations in satellite galaxies.
NASA Astrophysics Data System (ADS)
Wallace, L. M.; Araki, E.; Saffer, D.; Wang, X.; Roesner, A.; Kopf, A.; Nakanishi, A.; Power, W.; Kobayashi, R.; Kinoshita, C.; Toczko, S.; Kimura, T.; Machida, Y.; Carr, S.
2016-11-01
An Mw 6.0 earthquake struck 50 km offshore the Kii Peninsula of southwest Honshu, Japan on 1 April 2016. This earthquake occurred directly beneath a cabled offshore monitoring network at the Nankai Trough subduction zone and within 25-35 km of two borehole observatories installed as part of the International Ocean Discovery Program's NanTroSEIZE project. The earthquake's location close to the seafloor and subseafloor network offers a unique opportunity to evaluate dense seafloor geodetic and seismological data in the near field of a moderate-sized offshore earthquake. We use the offshore seismic network to locate the main shock and aftershocks, seafloor pressure sensors, and borehole observatory data to determine the detailed distribution of seafloor and subseafloor deformation, and seafloor pressure observations to model the resulting tsunami. Contractional strain estimated from formation pore pressure records in the borehole observatories (equivalent to 0.37 to 0.15 μstrain) provides a key to narrowing the possible range of fault plane solutions. Together, these data show that the rupture occurred on a landward dipping thrust fault at 9-10 km below the seafloor, most likely on the plate interface. Pore pressure changes recorded in one of the observatories also provide evidence for significant afterslip for at least a few days following the main shock. The earthquake and its aftershocks are located within the coseismic slip region of the 1944 Tonankai earthquake (Mw 8.0), and immediately downdip of swarms of very low frequency earthquakes in this region, illustrating the complex distribution of megathrust slip behavior at a dominantly locked seismogenic zone.
NASA Astrophysics Data System (ADS)
Rogozea, Maria; Radulian, Mircea; Placinta, Anica; Toma-Danila, Dragos
2017-04-01
A pair of moderate earthquakes of similar magnitude (Mw = 5.6) occurred in the Vrancea seismic source, a well-defined seismicity nest located in the mantle, beneath the South-Eastern Carpathians Arc in Romania. The two events are separated in time by two months (September 23, 2016 at 23:11:20 GMT and December 27, 2016 at 23:20:55 GMT). They are located close each other (45.7140N, 26.6180E, h = 92 km, and 45.7090N, 26.6030E, h = 99 km, respectively) and could be considered as belonging to an earthquake doublet. Similar doublets generated in the same depth range were recorded in 01 August 1985 (Mw = 5.2 and 5.8) and in 30-31 May 1990 (Mw = 6.9 and 6.4). The main purpose of this paper is to investigate comparatively the macroseismic effects associated to the earthquake doublet of 2016 and to analyze possible correlations with source characteristics, acceleration distribution and focal mechanism. Macroseismic information is collected using the on-line questionnaires from the website of the National Institute for Earth Physics (NIEP) and of the European Mediterranean Seismological Center (EMSC). The two earthquakes were felt over an extended area covering most of the Romania, north of Bulgaria, Republic of Moldova and south of Ukraine. We estimate the maximum observed intensity at V (MSK-64 scale). Although the two events have similar locations, time of occurrence and focal mechanism, significant differences were reported in the way that they were felt: on September 2017 the effects were stronger toward NE (Moldova) and SE (Dobrogea), while on December 2017 they were stronger toward NW (Transylvania) and SW (Romanian Plain). Possible source effects (complexity, rupture size) are investigated in this respect.
Dalal, Madhumita; Greneche, Jean-Marc; Satpati, Biswarup; Ghzaiel, Tayssir B; Mazaleyrat, Frédric; Ningthoujam, Raghumani S; Chakrabarti, Pabitra K
2017-11-22
Nanoparticles of Li 0.3 Zn 0.3 Co 0.1 Fe 2.3 O 4 (LZC) were prepared by the sol-gel method and dried in a furnace at ∼200 °C. The dried sample was annealed at 500, 600, 700, and 800 °C for 5 h each. Rietveld analysis of X-ray diffraction patterns confirms the cubic Fd3̅m phase formation with lattice parameters ranged from 8.376 up to 8.390 Å and allows the crystallite sizes (d cryst ) to be estimated. To enhance microwave (MW) absorption as well as the effectiveness for hyperthermia treatment, nanoparticles are taken in the matrix of multiwalled carbon nanotubes (MWCNTs) and the morphology of the so-prepared samples (LZC@MWCNT) was studied by scanning electron microscopy and transmission electron microscopy analyses. Both static and dynamic magnetic properties were investigated on the samples of LZC nanoparticles and compared to those of the samples of LZC@MWCNT. The samples annealed at 500, 600, and 800 °C are excellent candidates in cancer treatment as ac magnetic heating analysis shows that the hyperthermia temperature (42 °C) was successfully achieved for an applied ac magnetic field of 420 Oe and 300 kHz frequency. MW absorption study also reveals that the samples of LZC@MWCNT could be used as a potential MW absorbing material for which a maximum reflection loss (R L ) of ∼-21 dB was achieved at a frequency of 15.27 GHz for only 1 mm layer thickness.
Choi, Dongkil; Lee, Woojin; Park, Jinwon; Koh, Wongun
2008-01-01
In this study, poly(ethylene glycol) (PEG)-based hydrogels having different network structures were synthesized by UV-initiated photopolymerization and used for the enzyme immobilization. PEGs with different molecular weight were acrylated by derivatizing both ends with acryloyl chloride and photopolymerization of PEG-diacrylate (PEG-DA) yielded crosslinked hydrogel network within 5 seconds. Attachment of acrylate groups and gelation were confirmed by ATR/FT-IR and FT-Raman spectroscopy. Network structures of hydrogels could be easily controlled by changing the molecular weight (MW) of PEG-DA and characterized by calculating molecular weight between crosslinks and mesh size from the swelling measurement. Synthesis of hydrogels with higher MW of PEG produced less crosslinked hydrogels having higher water content, larger value of Mc and mesh size, which resulted in enhanced mass transfer but loss of mechanical properties. For the enzyme immobilization, glucose oxidase (GOX) was immobilized inside PEG hydrogels by means of physical entrapment and covalent immobilization. Encapsulated GOX were covalently bound to PEG backbone using acryloyl-PEG-N-hydroxysuccinimide and maintained their activity over a week period without leakage. Kinetic study indicated that immobilized enzyme inside hydrogel prepared from higher MW of PEG possessed lower apparent Km (Michaelis-Menten constant) and higher activity.
Ouyang, Yilan; Zeng, Yangyang; Yi, Lin; Tang, Hong; Li, Duxin; Linhardt, Robert J; Zhang, Zhenqing
2017-11-03
Heparin, a highly sulfated glycosaminoglycan, has been used as a clinical anticoagulant over 80 years. Low molecular weight heparins (LMWHs), heparins partially depolymerized using different processes, are widely used as clinical anticoagulants. Qualitative molecular weight (MW) and quantitative mass content analysis are two important factors that contribute to LMWH quality control. Size exclusion chromatography (SEC), relying on multiple angle laser scattering (MALS)/refractive index (RI) detectors, has been developed for accurate analysis of heparin MW in the absence of standards. However, the cations, which ion-pair with the anionic polysaccharide chains of heparin and LMWHs, had not been considered in previous reports. In this study, SEC with MALS/RI and inductively coupled plasma/mass spectrometry detectors were used in a comprehensive analytical approach taking both anionic polysaccharide and ion-paired cations heparin products. This approach was also applied to quantitative analysis of heparin and LMWHs. Full profiles of MWs and mass recoveries for three commercial heparin/LMWH products, heparin sodium, enoxaparin sodium and nadroparin calcium, were obtained and all showed higher MWs than previously reported. This important improvement more precisely characterized the MW properties of heparin/LMWHs and potentially many other anionic polysaccharides. Copyright © 2017 Elsevier B.V. All rights reserved.
Cost efficient PMMA/NG nanocomposites for electromagnetic interference shielding applications
NASA Astrophysics Data System (ADS)
Yadav, Prachi; Rattan, Sunita; Tripathi, Ambuj; Kumar, Sandeep
2017-06-01
Cost-efficient polymethylmethacrylate/exfoliated nanographite (PMMA/NG) nanocomposites were prepared through the melt blending technique. The crystalline size of NG in nanocomposites was estimated using Scherrer’s formula and was found to be in the range of 42.4-50.6 nm. Scanning electron micrographs showed the homogeneous dispersion of NG in the PMMA matrix. The thermal degradation temperature (T d) of nanocomposites was found to rise monotonically with increase in the loading of NG. Differential scanning calorimetry measurement showed a significant improvement in glass transition temperature (T g) from 97.2 °C for neat PMMA to 106.4 °C for 4.0 wt% PMMA/NG nanocomposites. DC electrical conductivity measurement revealed that the prepared nanocomposites exhibited a low percolation threshold of 0.45 vol%. The s-parameters (S 11 and S 21) were measured through vector network analyser and were explored in the estimation of electromagnetic interference (EMI) shielding effectiveness (SE). The EMI SE of 19.2 dB (~ 99% attenuation of incoming microwave (MW) power) was attained in the 4.0 wt% PMMA/NG nanocomposite at 12.7 GHz MW frequency. Moreover, the observed broadband EMI SE spectra indicate that the prepared nanocomposites can be employed in lightweight and low-cost commercial EMI shielding applications.
NASA Astrophysics Data System (ADS)
Jannoo, Kanokwan; Teerapatsakul, Churapa; Punyanut, Adisak; Pasanphan, Wanvimol
2015-07-01
Silver nanoparticles (AgNPs) in chitosan (CS) stabilizer were successfully synthesized using electron beam irradiation. The effects of irradiation dose, molecular weight (MW) of CS stabilizer, concentration of AgNO3 precursor and addition of tert-butanol on AgNPs production were studied. The stability of the AgNPs under different temperatures and storage times were also investigated. The AgNPs formation in CS was observed using UV-vis, FT-IR and XRD. The characteristic surface plasmon resonance (SPR) of the obtained AgNPs was around 418 nm. The CS stabilizer and its MW, AgNO3 precursor and irradiation doses are important parameters for the synthesis of AgNPs. The optimum addition of 20% v/v tert-butanol could assist the formation of AgNPs. The AgNPs in CS stabilizer were stable over a period of one year when the samples were kept at 5 °C. The AgNPs observed from TEM images were spherical with an average particle size in the range of 5-20 nm depending on the irradiation doses. The AgNPs in CS solution effectively inhibited the growth of several fungi, i.e., Curvularia lunata, Trichoderma sp., Penicillium sp. and Aspergillus niger, which commonly found on the building surface.
Observation of Alpha-Driven TAEs in TFTR
NASA Astrophysics Data System (ADS)
Nazikian, R.; Chang, Z.; Fu, G. Y.; Majeski, R.; Batha, S.; Bell, M.; Budny, R.; Cheng, C. Z.; Darrow, D. S.; Duong, H.; Efthimion, P. C.; Fredrickson, E.; Levinton, F.; Mazzucato, E.; Medley, S.; Taylor, S.; Zweben, G.
1996-11-01
Transient mode activity in the TAE range of frequencies (150-170 kHz) with toroidal mode numbers n=2,3 is observed in reduced magnetic shear DT discharges on TFTR with a fusion power threshold of ~1.5 MW. Mode activity appears 50-100 msec after NBI in discharges with the following machine parameter: B=5.3 T, I=1.6MA, R=260cm, P_NBI=25-28 MW, q(0)>2.0 from MSE and toroidal beta β_T<1%. The elevated q(0) and reduced central shear |s|<0.2 is achieved using a full size plasma startup with delayed NBI. Theoretical calculations using NOVA-K indicate that the combined effect of low shear, low beta and elevated q(0) leads to a very low instability threshold for the alpha-driven TAE with β_α (0) ~ 10-4. This appears to be consistent with experimental observations of mode activity in DT plasmas with β_α ~ 10-4 (determined from TRANSP analysis). Thus far the modes have only been observed on Mirnov coils with fluctuation levels tildeB ~ 1mG. Efforts to determine mode location by perturbing the edge density and inducing strong toroidal velocity shear will be reported, as will efforts to affect mode stability by systematically varying the central safety factor.
Initial experiments with a laser driven Stirling engine
NASA Technical Reports Server (NTRS)
Byer, R. L.
1976-01-01
Operation of a Beale free piston Stirling engine with a 40-W CO2 laser is described. Advantages of such a system include: closed-cycle operation, long life, inexpensive construction, and size scalability to 100 MW.
Topkara, Veli K; Williams, Mathew R; Barili, Fabio; Bastos, Renata; Liu, Judy F; Liberman, Elyse A; Russo, Mark J; Oz, Mehmet C; Argenziano, Michael
2006-01-01
Due to its complexity and risk of bleeding, the Maze III procedure has been largely replaced by surgical ablation for atrial fibrillation (AF) using alternative energy sources. Radiofrequency (RF) and microwave (MW) are the most commonly used energy forms. In this study, we sought to compare these energy modalities in terms of clinical outcomes. Two hundred five patients underwent surgical ablation of AF, from October 1999 to May 2004 at our institution via an endocardial approach. Patients were categorized into 2 groups: RF and MW. Baseline characteristics, operative details, and clinical outcomes were compared between the 2 groups. Rhythm success was defined as freedom from AF and atrial flutter as determined by postoperative electrocardiograms. One hundred twenty patients (58.5%) were ablated using RF, whereas 85 (41.5%) were ablated with MW. Most of the patients had persistent AF in both the RF and MW groups (85.7% versus 80.0%, respectively; P = .363). Intraoperative left atrial size was 6.4 +/- 1.7 cm for the RF group and 6.4 +/- 1.7 cm for the MW group (P = .820). Postoperative rhythm success at 6 and 12 months was 72.4% versus 71.4% (P +/- .611) and 75.0% versus 66.7% (P = .909) for the RF and MW groups, respectively. Hospital length of stay was comparable for both groups (15.4 +/- 14.0 versus 13.3 +/- 13.9 days; P = .307). Postoperative survival at 6 months, 1 year, and 3 years was 90.4%, 89.5%, and 86.1% for RF patients compared to 87.9%, 86.5%, and 84.4% for MW patients, respectively (log rank P = .490). RF and MW energy forms yield comparable postoperative rhythm success, hospital length of stay, and postoperative survival. Both sources are rapid, safe, and effective alternatives to "cut and sew" techniques for surgical treatment of AF.
Multimode harmonic power measurement of 40 MW pulsed S-band klystrons
NASA Astrophysics Data System (ADS)
Fowkes, W. R.; Wu, E. S.
1984-08-01
An array of 12 calibrated RF electric field probes on the waveguide walls are used to sample the complex field profile at the second and third harmonics where the fundamental power is in the 40 MW range at 2856 MHz. The measured amplitude and phase signals from these are Fourier analyzed to determine with good accuracy the power in each of the many possible propagating modes.
Scalable Method to Produce Biodegradable Nanoparticles that Rapidly Penetrate Human Mucus
Xu, Qingguo; Boylan, Nicholas J.; Cai, Shutian; Miao, Bolong; Patel, Himatkumar; Hanes, Justin
2013-01-01
Mucus typically traps and rapidly removes foreign particles from the airways, gastrointestinal tract, nasopharynx, female reproductive tract and the surface of the eye. Nanoparticles capable of rapid penetration through mucus can potentially avoid rapid clearance, and open significant opportunities for controlled drug delivery at mucosal surfaces. Here, we report an industrially scalable emulsification method to produce biodegradable mucus-penetrating particles (MPP). The emulsification of diblock copolymers of poly(lactic-co-glycolic acid) and polyethylene glycol (PLGA-PEG) using low molecular weight (MW) emulsifiers forms dense brush PEG coatings on nanoparticles that allow rapid nanoparticle penetration through fresh undiluted human mucus. In comparison, conventional high MW emulsifiers, such as polyvinyl alcohol (PVA), interrupts the PEG coating on nanoparticles, resulting in their immobilization in mucus owing to adhesive interactions with mucus mesh elements. PLGA-PEG nanoparticles with a wide range of PEG MW (1, 2, 5, and 10 kDa), prepared by the emulsification method using low MW emulsifiers, all rapidly penetrated mucus. A range of drugs, from hydrophobic small molecules to hydrohilic large biologics, can be efficiently loaded into biodegradable MPP using the method described. This readily scalable method should facilitate the production of MPP products for mucosal drug delivery, as well as potentially longer-circulating particles following intravenous administration. PMID:23751567
Earthquake hazards on the cascadia subduction zone.
Heaton, T H; Hartzell, S H
1987-04-10
Large subduction earthquakes on the Cascadia subduction zone pose a potential seismic hazard. Very young oceanic lithosphere (10 million years old) is being subducted beneath North America at a rate of approximately 4 centimeters per year. The Cascadia subduction zone shares many characteristics with subduction zones in southern Chile, southwestern Japan, and Colombia, where comparably young oceanic lithosphere is also subducting. Very large subduction earthquakes, ranging in energy magnitude (M(w)) between 8 and 9.5, have occurred along these other subduction zones. If the Cascadia subduction zone is also storing elastic energy, a sequence of several great earthquakes (M(w) 8) or a giant earthquake (M(w) 9) would be necessary to fill this 1200-kilometer gap. The nature of strong ground motions recorded during subduction earthquakes of M(w) less than 8.2 is discussed. Strong ground motions from even larger earthquakes (M(w) up to 9.5) are estimated by simple simulations. If large subduction earthquakes occur in the Pacific Northwest, relatively strong shaking can be expected over a large region. Such earthquakes may also be accompanied by large local tsunamis.
MW 08-multi-beam air and surface surveillance radar
NASA Astrophysics Data System (ADS)
1989-09-01
Signal of the Netherlands has developed and is marketing the MW 08, a 3-D radar to be used for short to medium range surveillance, target acquisition, and tracking. MW 08 is a fully automated detecting and tracking radar. It is designed to counter threats from aircraft and low flying antiship missiles. It can also deal with the high level missile threat. MW 08 operates in the 5 cm band using one antenna for both transmitting and receiving. The antenna is an array, consisting of 8 stripline antennas. The received radar energy is processed by 8 receiver channels. These channels come together in the beam forming network, in which 8 virtual beams are formed. From this beam pattern, 6 beams are used for the elevation coverage of 0-70 degrees. MW 08's output signals of the beam former are further handled by FFT and plot processors for target speed information, clutter rejection, and jamming suppression. A general purpose computer handles target track initiation, and tracking. Tracking data are transferred to the command and control systems with 3-D target information for fastest possible lockon.
Molecular weight dependence of carrier mobility and recombination rate in neat P3HT films
Dixon, Alex G.; Visvanathan, Rayshan; Clark, Noel A.; ...
2017-11-02
The microstructure dependence of carrier mobility and recombination rates of neat films of poly 3-hexylthyophene (P3HT) were determined for a range of materials of weight-average molecular weights, Mw, ranging from 14 to 331 kDa. This variation has previously been shown to modify the polymer microstructure, with low molecular weights forming a one-phase, paraffinic-like structure comprised of chain-extended crystallites, and higher molecular weights forming a semicrystalline structure with crystalline domains being embedded in an amorphous matrix. Using Charge Extraction by Linearly Increasing Voltage (CELIV), we show here that the carrier mobility in P3HT devices peaks for materials of Mw = 48more » kDa, and that the recombination rate decreases monotonically with increasing molecular weight. This trend is likely due to the development of a semicrystalline, two-phase structure with increasing Mw, which allows for the spatial separation of holes and electrons into the amorphous and crystalline regions, respectively. This separation leads to decreased recombination.« less
Molecular weight dependence of carrier mobility and recombination rate in neat P3HT films
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dixon, Alex G.; Visvanathan, Rayshan; Clark, Noel A.
The microstructure dependence of carrier mobility and recombination rates of neat films of poly 3-hexylthyophene (P3HT) were determined for a range of materials of weight-average molecular weights, Mw, ranging from 14 to 331 kDa. This variation has previously been shown to modify the polymer microstructure, with low molecular weights forming a one-phase, paraffinic-like structure comprised of chain-extended crystallites, and higher molecular weights forming a semicrystalline structure with crystalline domains being embedded in an amorphous matrix. Using Charge Extraction by Linearly Increasing Voltage (CELIV), we show here that the carrier mobility in P3HT devices peaks for materials of Mw = 48more » kDa, and that the recombination rate decreases monotonically with increasing molecular weight. This trend is likely due to the development of a semicrystalline, two-phase structure with increasing Mw, which allows for the spatial separation of holes and electrons into the amorphous and crystalline regions, respectively. This separation leads to decreased recombination.« less
A target development program for beamhole spallation neutron sources in the megawatt range
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bauer, G.S.; Atchison, F.
1995-10-01
Spallation sources as an alternative to fission neutron sources have been operating successfully up to 160 kW of beam power. With the next generation of these facilities aiming at the medium power range between 0.5 and 5 MW, loads on the targets will be high enough to make present experience of little relevance. With the 0.6 MW continuous facility SINQ under construction, and a 5 MW pulsed facility (ESS) under study in Europe, a research and development program is about to be started which aimes at assessing the limits of stationary and moving solid targets and the feasibility and potentialmore » benefits of flowing liquid metal targets. Apart from theoretical work and examination of existing irradiated material, including used targets from ISIS, it is intended to take advantage of the SINQ solid rod target design to improve the relevant data base by building the target in such a way that individual rods can be equipped as irradiation capsules.« less
Quantum pump effect induced by a linearly polarized microwave in a two-dimensional electron gas.
Song, Juntao; Liu, Haiwen; Jiang, Hua
2012-05-30
A quantum pump effect is predicted in an ideal homogeneous two-dimensional electron gas (2DEG) that is normally irradiated by linearly polarized microwaves (MW). Without considering effects from spin-orbital coupling or the magnetic field, it is found that a polarized MW can continuously pump electrons from the longitudinal to the transverse direction, or from the transverse to the longitudinal direction, in the central irradiated region. The large pump current is obtained for both the low frequency limit and the high frequency case. Its magnitude depends on sample properties such as the size of the radiated region, the power and frequency of the MW, etc. Through the calculated results, the pump current should be attributed to the dominant photon-assisted tunneling processes as well as the asymmetry of the electron density of states with respect to the Fermi energy.
Precursory slow-slip loaded the 2009 L'Aquila earthquake sequence
NASA Astrophysics Data System (ADS)
Borghi, A.; Aoudia, A.; Javed, F.; Barzaghi, R.
2016-05-01
Slow-slip events (SSEs) are common at subduction zone faults where large mega earthquakes occur. We report here that one of the best-recorded moderate size continental earthquake, the 2009 April 6 moment magnitude (Mw) 6.3 L'Aquila (Italy) earthquake, was preceded by a 5.9 Mw SSE that originated from the decollement beneath the reactivated normal faulting system. The SSE is identified from a rigorous analysis of continuous GPS stations and occurred on the 12 February and lasted for almost two weeks. It coincided with a burst in the foreshock activity with small repeating earthquakes migrating towards the main-shock hypocentre as well as with a change in the elastic properties of rocks in the fault region. The SSE has caused substantial stress loading at seismogenic depths where the magnitude 4.0 foreshock and Mw 6.3 main shock nucleated. This stress loading is also spatially correlated with the lateral extent of the aftershock sequence.
Engdahl, E.R.; Billington, S.; Kisslinger, C.
1989-01-01
The Andreanof Islands earthquake (Mw 8.0) is the largest event to have occurred in that section of the Aleutian arc since the March 9, 1957, Aleutian Islands earthquake (Mw 8.6). Teleseismically well-recorded earthquakes in the region of the 1986 earthquake are relocated with a plate model and with careful attention to the focal depths. The data set is nearly complete for mb???4.7 between longitudes 172??W and 179??W for the period 1964 through April 1987 and provides a detailed description of the space-time history of moderate-size earthquakes in the region for that period. Additional insight is provided by source parameters which have been systematically determined for Mw???5 earthquakes that occurred in the region since 1977 and by a modeling study of the spatial distribution of moment release on the mainshock fault plane. -from Authors
Desilication of ZSM-5 zeolites for mesoporosity development using microwave irradiation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hasan, Zubair; Jun, Jong Won; Kim, Chul-Ung
2015-01-15
Highlights: • Microwaves have beneficial effects on desilication of zeolites. • Produced mesopores with microwaves have narrow pore-size distribution. • Advantages and disadvantages of various desilicating agents were also reported. - Abstract: Mesoporous ZSM-5 zeolite was obtained by desilication in alkaline solutions with microwave (MW) and conventional electric (CE) heating under hydrothermal conditions. Both methods were effective in the production of mesoporous zeolites; however, MW was more efficient than CE as it led to well-defined mesopores with relatively small sizes and a narrow size distribution within a short treatment time. Moreover, the mesoporous ZSM-5 obtained through this method was effectivemore » in producing less bulky products from an acid-catalyzed reaction, specifically the butylation of phenol. Finally, various bases were found to have advantages and disadvantages in desilication. NaOH was the most reactive; however, macroporosity could develop easily under a severe condition. Ammonia water was weakly reactive; however, it could be used to precisely control the pore architecture, and no ion exchange is needed for acid catalysis. Organic amines such as ethylenediamine can also be used in desilication.« less
InP MMIC Chip Set for Power Sources Covering 80-170 GHz
NASA Technical Reports Server (NTRS)
Ngo, Catherine
2001-01-01
We will present a Monolithic Millimeter-wave Integrated Circuit (MMIC) chip set which provides high output-power sources for driving diode frequency multipliers into the terahertz range. The chip set was fabricated at HRL Laboratories using a 0.1-micrometer gate-length InAlAs/InGaAs/InP high electron mobility transistor (HEMT) process, and features transistors with an f(sub max) above 600 GHz. The HRL InP HEMT process has already demonstrated amplifiers in the 60-200 GHz range. In this paper, these high frequency HEMTs form the basis for power sources up to 170 GHz. A number of state-of-the-art InP HEMT MMICs will be presented. These include voltage-controlled and fixed-tuned oscillators, power amplifiers, and an active doubler. We will first discuss an 80 GHz voltage-controlled oscillator with 5 GHz of tunability and at least 17 mW of output power, as well as a 120 GHz oscillator providing 7 mW of output power. In addition, we will present results of a power amplifier which covers the full WRIO waveguide band (75-110 GHz), and provides 40-50 mW of output power. Furthermore, we will present an active doubler at 164 GHz providing 8% bandwidth, 3 mW of output power, and an unprecedented 2 dB of conversion loss for an InP HEMT MMIC at this frequency. Finally, we will demonstrate a power amplifier to cover 140-170 GHz with 15-25 mW of output power and 8 dB gain. These components can form a power source in the 155-165 GHz range by cascading the 80 GHz oscillator, W-band power amplifier, 164 GHz active doubler and final 140-170 GHz power amplifier for a stable, compact local oscillator subsystem, which could be used for atmospheric science or astrophysics radiometers.
LN2 spray droplet size measurement via ensemble diffraction technique
NASA Technical Reports Server (NTRS)
Saiyed, N. H.; Jurns, J.; Chato, David J.
1991-01-01
The size of subcooled liquified nitrogen droplets are measured with a 5 mW He-Ne laser as a function of pressure difference (delta P) across flat spray and full cone pressure atomizing nozzles. For delta P's of 3 to 30 psid, the spray sauter mean diameter (SMD) ranged between 250 to 50 microns. The pressure range tested is representative of those expected during cryogenic fluid transfer operations in space. The droplet sizes from the flat spray nozzles were greater than those from the full cone nozzle. A power function of the form, SMD varies as delta P(exp a), describes the spray SMD as a function of the delta P very well. The values of a were -0.36 for the flat spray and -0.87 for the full cone. The reduced dependence of the flat spray SMD on the delta P was probably because of: (1) the absence of a swirler that generates turbulence within the nozzle to enhance atomization, and (2) a possible increase in shearing stress resulting from the delayed atomization due to the absence of turbulence. The nitrogen quality, up to 1.5 percent is based on isenthalpic expansion, did not have a distinct and measurable effect on the spray SMD. Both bimodal and monomodal droplet size population distributions were measured. In the bimodal distribution, the frequency of the first mode was much greater than the frequency of the second mode. Also, the frequency of the second mode was low enough such that a monomodal approximation probably would give reasonable results.
Profile of medical waste management in two healthcare facilities in Lagos, Nigeria: a case study.
Idowu, Ibijoke; Alo, Babajide; Atherton, William; Al Khaddar, Rafid
2013-05-01
Proper management and safe disposal of medical waste (MW) is vital in the reduction of infection or illness through contact with discarded material and in the prevention of environmental contamination in hospital facilities. The management practices for MW in selected healthcare facilities in Lagos, Nigeria were assessed. The cross-sectional study involved the use of questionnaires, in-depth interviews, focused group discussions and participant observation strategies. It also involved the collection, segregation, identification and weighing of waste types from wards and units in the representative facilities in Lagos, Nigeria, for qualitative and quantitative analysis of the MW streams. The findings indicated that the selected Nigerian healthcare facilities were lacking in the adoption of sound MW management (MWM) practices. The average MW ranged from 0.01 kg/bed/day to 3.98 kg/bed/day. Moreover, about 30% of the domestic waste from the healthcare facilities consisted of MW due to inappropriate co-disposal practices. Multiple linear regression was applied to predict the volume of waste generated giving a correlation coefficient (R(2)) value of 0.99 confirming a good fit of the data. This study revealed that the current MWM practices and strategies in Lagos are weak, and suggests an urgent need for review to achieve vital reversals in the current trends.
NASA Astrophysics Data System (ADS)
Chen, K. P.; Chang, W. Y.; Tsai, Y. B.
2016-12-01
The main purpose of this study is to apply an innovative approach to assess the median annual seismicity rates and their dispersions for Taiwan earthquakes in different depth ranges. This approach explicitly represents the Gutenberg-Richter (G-R) relation in terms of both the logarithmic mean annual seismicity rate and its standard deviation, instead of just the arithmetic mean. We use the high-quality seismicity data obtained by the Institute of Earth Sciences (IES) and the Central Weather Bureau (CWB) in an earthquake catalog with homogenized moment magnitudes from 1975 to 2014 for our study. The selected data set is shown to be complete for Mw>3.0. We first use it to illustrate the merits of our new approach for dampening the influence of spuriously large or small event numbers in individual years on the determination of median annual seismicity rate and its standard deviation. We further show that the logarithmic annual seismicity rates indeed possess a well-behaved lognormal distribution. The final results are summarized as follows: log10N=5.75-0.90Mw+/-(0.245-0.01Mw) for focal depth 0 300 km; log10N=5.78-0.94Mw+/-(0.195+0.01Mw) for focal depth 0-35 km; log10N=4.72-0.89Mw+/-(-0.075+0.075Mw) for focal depth 35-70 km; and log10N=4.69-0.88Mw+/-(-0.47+0.16Mw) for focal depth 70-300 km. Above results show distinctly different values for the parameters a and b in the G-R relations for Taiwan earthquakes in different depth ranges. These analytical equations can be readily used for comprehensive probabilistic seismic hazard assessment. Furthermore, a numerical table on the corresponding median annual seismicity rates and their upper and lower bounds at median +/- one standard deviation levels, as calculated from above analytical equations, is presented at the end. This table offers an overall glance of the estimated median annual seismicity rates and their dispersions for Taiwan earthquakes of various magnitudes and focal depths. It is interesting to point out that the seismicity rate of crustal earthquakes, which tend to contribute most hazards, accounts for only about 74% of the overall seismicity rate in Taiwan. Accordingly, direct use of the entire earthquake catalog without differentiating the focal depth may result in substantial overestimates of potential seismic hazards.
The Maupin, Oregon Earthquake Swarm
NASA Astrophysics Data System (ADS)
Braunmiller, J.; Williams, M.; Trehu, A. M.; Nabelek, J.
2008-12-01
The area near Maupin, Oregon has experienced over 300 earthquakes since December 2006. The events, located by the Pacific Northwest Seismic Network (PNSN), occurred ~10 km SE of the town in central Oregon and ~50 km E-SE of Mount Hood. The temporal event pattern and lack of a distinct main shock are characteristic of an earthquake swarm with the event-size distribution indicating a low b-value similar to other non-volcanic swarms. Locations show a NW-SE trending, ~4x3 km cluster at apparent depths of 12-24 km. The largest events (Mw=3.8 and 3.9) on March 1, 2007 and July 14, 2008 occurred more than one year apart; 11 other events had a magnitude of 3 or greater. The larger events were felt locally. During the first 14 months EarthScope USArray seismic stations surrounded the swarm, providing a unique high-quality dataset. Waveform similarity at the closest USArray site G06A indicates hypocenters are much tighter than suggested by the PNSN distribution. Moment tensor inversion reveals nearly identical double- couple strike-slip mechanisms on a plane striking ~15° NW for the three largest 2007 events and the July 2008 event. The April 2008 Mw=3.3 event is rotated ~10° clockwise consistent with slight changes of G06A three-component waveforms relative to the other events. Preferred centroid depths are in the 15-20 km range. Historically, seismicity in the Pacific Northwest east of the Cascades is characterized by sporadic bursts of clustered seismicity with occasional M=6 earthquakes. The largest instrumentally recorded earthquake near Maupin (Mw=4.6) occurred 1976. An earlier swarm was observed 1987, but since then only ~2 events/yr occurred until the current swarm. In spite of recurrent seismicity, exposed surface rocks near Maupin are undeformed lava flows of the Columbia River Basalt Group and older John Day volcanics. The geologic map of Oregon shows a NW-trending dip slip fault near the epicenter area, inconsistent with moment tensor solutions. The cause for the swarm is currently unknown with hypotheses ranging from magmatic or fluid motion in the crust to tectonic activity along a weakly coupled microplate boundary.
Kinetic Assembly of Near-IR Active Gold Nanoclusters using Weakly Adsorbing Polymers to Control Size
Tam, Jasmine M.; Murthy, Avinash K.; Ingram, Davis R.; Nguyen, Robin; Sokolov, Konstantin V.; Johnston, Keith P.
2013-01-01
Clusters of metal nanoparticles with an overall size less than 100 nm and high metal loadings for strong optical functionality, are of interest in various fields including microelectronics, sensors, optoelectronics and biomedical imaging and therapeutics. Herein we assemble ~5 nm gold particles into clusters with controlled size, as small as 30 nm and up to 100 nm, which contain only small amounts of polymeric stabilizers. The assembly is kinetically controlled with weakly adsorbing polymers, PLA(2K)-b-PEG(10K)-b-PLA(2K) or PEG (MW = 3350), by manipulating electrostatic, van der Waals (VDW), steric, and depletion forces. The cluster size and optical properties are tuned as a function of particle volume fractions and polymer/gold ratios to modulate the interparticle interactions. The close spacing between the constituent gold nanoparticles and high gold loadings (80–85% w/w gold) produce a strong absorbance cross section of ~9×10−15 m2 in the NIR at 700 nm. This morphology results from VDW and depletion attractive interactions that exclude the weakly adsorbed polymeric stabilizer from the cluster interior. The generality of this kinetic assembly platform is demonstrated for gold nanoparticles with a range of surface charges from highly negative to neutral, with the two different polymers. PMID:20361735
Viscous Energy Loss in the Presence of Abnormal Aortic Flow
Barker, A.J.; van Ooij, P.; Bandi, K.; Garcia, J.; Albaghdadi, M.; McCarthy, P.; Bonow, R. O.; Carr, J.; Collins, J.; Malaisrie, C.; Markl, M.
2014-01-01
Purpose To present a theoretical basis for noninvasively characterizing in vivo fluid-mechanical energy losses, and to apply it in a pilot study of patients known to express abnormal aortic flow patterns. Methods 4D flow MRI was used to characterize laminar viscous energy losses in the aorta of normal controls (n=12, age=37±10), patients with aortic dilation (n=16, age=52±8), and patients with aortic valve stenosis matched for age and aortic size (n=14, age=46±15), using a relationship between the 3D velocity field and viscous energy dissipation. Results Viscous energy loss was significantly elevated in the thoracic aorta for patients with dilated aorta (3.6±1.3 mW, p=0.024) and patients with aortic stenosis (14.3±8.2 mW, p<0.001) compared to healthy volunteers (2.3±0.9 mW). The same pattern of significant differences were seen in the ascending aorta, where viscous energy losses in patients with dilated aortas (2.2±1.1 mW, p=0.021) and patients with aortic stenosis (10.9±6.8 mW, p<0.001) were elevated compared to healthy volunteers (1.2±0.6 mW). Conclusion This technique provides a capability to quantify the contribution of abnormal laminar blood flow to increased ventricular afterload. In this pilot study, viscous energy loss in patient cohorts was significantly elevated and indicates that cardiac afterload is increased due to abnormal flow. PMID:24122967
Cocurrent scrubber evaluation: TVA's Colbert lime-limestone wet-scrubbing pilot plant
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hollinden, G.A.; Robards, R.F.; Moore, N.D.
1979-01-01
The Tennessee Valley Authority (TVA) is actively engaged in a pilot plant program to develop and/or evaluate wet-scrubbing processes for removing sulfur dioxide (SO/sub 2/) from boiler flue gas. The physical size and general arrangement of flue gas scrubbing systems have a major impact on capital investment and operating cost, as do potential operating and maintenance advantages inherent to some systems. The equipment configuration for a cocurrent scrubber reflects some of these advantages. EPRI funded TVA to perform preliminary screening tests at TVA's 1 MW pilot plant (Colbert Steam Plant) to develop operating data on the cocurrent design for usemore » in designing and operating a 10 MW prototype cocurrent scrubber at TVA's Shawnee Scrubber Test Facility. Results of Colbert tests showed excellent sulfur dioxide removal efficiencies, generally greater than 85%, low pressure drop, and high particulate removal efficiencies. This report covers these screening tests. The results indicate that commercial application of the cocurrent scrubber concept may save substantial capital investment by reducing the number of scrubber modules and auxiliary equipment. These evaluation tests provided the basis for the design and construction of the 10 MW cocurrent scrubber at the Shawnee Facility. Operation of this scrubber began in August 1978 to develop the scale-up similarities and differences between the Colbert test program (1 MW) and the Shawnee test program (10 MW). It also demonstrated the practicality and reliability of the 10 MW prototype. Detailed results of the prototype test series will be available in late 1979.« less
NASA Astrophysics Data System (ADS)
Lanas, Vanessa; Ahn, Yongtae; Logan, Bruce E.
2014-02-01
Larger scale microbial fuel cells (MFCs) require compact architectures to efficiently treat wastewater. We examined how anode-brush diameter, number of anodes, and electrode spacing affected the performance of the MFCs operated in fed-batch and continuous flow mode. All anodes were initially tested with the brush core set at the same distance from the cathode. In fed-batch mode, the configuration with three larger brushes (25 mm diameter) produced 80% more power (1240 mW m-2) than reactors with eight smaller brushes (8 mm) (690 mW m-2). The higher power production by the larger brushes was due to more negative and stable anode potentials than the smaller brushes. The same general result was obtained in continuous flow operation, although power densities were reduced. However, by moving the center of the smaller brushes closer to the cathode (from 16.5 to 8 mm), power substantially increased from 690 to 1030 mW m-2 in fed batch mode. In continuous flow mode, power increased from 280 to 1020 mW m-2, resulting in more power production from the smaller brushes than the larger brushes (540 mW m-2). These results show that multi-electrode MFCs can be optimized by selecting smaller anodes, placed as close as possible to the cathode.
NASA Astrophysics Data System (ADS)
Bernhardi, E. H.; de Ridder, R. M.; Wörhoff, K.; Pollnau, M.
2013-03-01
We report on diode-pumped distributed-feedback (DFB) and distributed-Bragg-reflector (DBR) channel waveguide lasers in Er-doped and Yb-doped Al2O3 on standard thermally oxidized silicon substrates. Uniform surface-relief Bragg gratings were patterned by laser-interference lithography and etched into the SiO2 top cladding. The maximum grating reflectivity exceeded 99%. Monolithic DFB and DBR cavities with Q-factors of up to 1.35×106 were realized. The Erdoped DFB laser delivered 3 mW of output power with a slope efficiency of 41% versus absorbed pump power. Singlelongitudinal- mode operation at a wavelength of 1545.2 nm was achieved with an emission line width of 1.70 0.58 kHz, corresponding to a laser Q-factor of 1.14×1011. Yb-doped DFB and DBR lasers were demonstrated at wavelengths near 1020 nm with output powers of 55 mW and a slope efficiency of 67% versus launched pump power. An Yb-doped dualwavelength laser was achieved based on the optical resonances induced by two local phase shifts in the DFB structure. A stable microwave signal at ~15 GHz with a -3-dB width of 9 kHz and a long-term frequency stability of +/- 2.5 MHz was created via the heterodyne photo-detection of the two laser wavelengths. By measuring changes in the microwave beat signal as the intra-cavity evanescent laser field interacts with micro-particles on the waveguide surface, we achieved real-time detection and accurate size measurement of single micro-particles with diameters ranging between 1 μm and 20 μm, which represents the typical size of many fungal and bacterial pathogens. A limit of detection of ~500 nm was deduced.
NASA Technical Reports Server (NTRS)
Hubbard, Harvey H.; Shepherd, Kevin P.
2009-01-01
Wind turbine generators, ranging in size from a few kilowatts to several megawatts, are producing electricity both singly and in wind power stations that encompass hundreds of machines. Many installations are in uninhabited areas far from established residences, and therefore there are no apparent environmental impacts in terms of noise. There is, however, the potential for situations in which the radiated noise can be heard by residents of adjacent neighborhoods, particularly those neighborhoods with low ambient noise levels. A widely publicized incident of this nature occurred with the operation of the experimental Mod-1 2-MW wind turbine, which is described in detail elsewhere. Pioneering studies which were conducted at the Mod-1 site on the causes and remedies of noise from wind turbines form the foundation of much of the technology described in this chapter.
Experimental investigation on flow in diffuser of 1090 MW steam turbine
NASA Astrophysics Data System (ADS)
Hoznedl, Michal; Sedlák, Kamil; Mrózek, Lukáš; Bednář, Lukáš; Kalista, Robert
2016-06-01
The paper deals with flow of wet water steam in diffuser of turbine engine 1090 MW on saturated water steam. Experimental measurements were done while the turbine was in operation for a wide range of outputs. Defining the outlet velocity from the last stage and with knowledge of static pressures on the diffuser outlet, it is possible to define the contribution of the diffuser to the whole low pressure part efficiency.
JPRS Report, Science & Technology USSR: Physics & Mathematics
1991-03-07
field B < mw 2 / e (mw - mass of gauge W- boson ) does not invalidate this approximation inasmuch as the respective momentum integrals remain...model (sin29w = Vi where 0W - angle of W- boson momentum) indicate that, in an ultras- trong magnetic field, photon fusion produces more elec- tron... boson field throughout the 8^8* range. This study was made within the scope of Project N 344 in the Government Program "High-Temperature
DOE Office of Scientific and Technical Information (OSTI.GOV)
Akulov, V A; Kablukov, S I; Babin, Sergei A
2012-02-28
This paper presents an experimental study of frequency doubling of a tunable ytterbium-doped fibre laser in KTP crystals phase-matched in the XY and YZ planes. In the XY plane, we obtained continuous tuning in the range 528 - 540 nm through intracavity frequency doubling. The second-harmonic power reached 450 mW for 18 W of multimode diode pump power, which was five times higher in comparison with single-pass frequency doubling. In a single-pass configuration in the YZ plane, we obtained a wide tuning range (527 - 551 nm) in the green spectral region and a second-harmonic power of {approx}10 mW. Themore » tuning range was only limited by the mechanical performance of the fibre Bragg grating and can potentially be extended to the entire lasing range of the ytterbium-doped fibre laser.« less
Time-to-digital converter card for multichannel time-resolved single-photon counting applications
NASA Astrophysics Data System (ADS)
Tamborini, Davide; Portaluppi, Davide; Tisa, Simone; Tosi, Alberto
2015-03-01
We present a high performance Time-to-Digital Converter (TDC) card that provides 10 ps timing resolution and 20 ps (rms) timing precision with a programmable full-scale-range from 160 ns to 10 μs. Differential Non-Linearity (DNL) is better than 1.3% LSB (rms) and Integral Non-Linearity (INL) is 5 ps rms. Thanks to the low power consumption (400 mW) and the compact size (78 mm x 28 mm x 10 mm), this card is the building block for developing compact multichannel time-resolved instrumentation for Time-Correlated Single-Photon Counting (TCSPC). The TDC-card outputs the time measurement results together with the rates of START and STOP signals and the number of valid TDC conversions. These additional information are needed by many TCSPC-based applications, such as: Fluorescence Lifetime Imaging (FLIM), Time-of-Flight (TOF) ranging measurements, time-resolved Positron Emission Tomography (PET), single-molecule spectroscopy, Fluorescence Correlation Spectroscopy (FCS), Diffuse Optical Tomography (DOT), Optical Time-Domain Reflectometry (OTDR), quantum optics, etc.
Areas of slip of recent earthquakes in the Mexican subduction zone
NASA Astrophysics Data System (ADS)
Hjorleifsdottir, V.; Sánchez-Reyes, H. S.; Singh, S.; Ji, C.; Iglesias, A.; Perez-Campos, X.
2012-12-01
The Mexican subduction zone is unusual: the width of the seismogenic zone is relatively narrow and a large portion of the co-seismic slip generally occurs below the coast, ~ 45 to 80 km from the trench. The earthquake recurrence interval is relatively short and almost the entire length of the zone has experienced a large (Mw≥7.4) earthquake in the last 100 years (Singh et al., 1981). In this study we present detailed analysis of the areas of significant slip during several recent (last 20 years) large earthquakes in the Mexican subduction zone. The most recent earthquake of 20 March 2012 (Mw7.4) occurred near the Guerrero/Oaxaca border. The slip was concentrated on the plate interface below land and the epicentral PGAs ranged between 0.2 and 0.7g. The updip portion of the plate interface had previously broken during the 25 Feb 1996 earthquake (Mw7.1), which was a slow earthquake and produced anomalously low PGAs (Iglesias et al., 2003). This indicates that in this region the area close to the trench is at least partially locked, with some earthquakes breaking the down-dip portion of the interface and others rupturing the up-dip portion. The Jalisco/Colima segment of the subduction zone seems to behave in a similar fashion. The 9 October 1995 (Mw 8.0) earthquake generated small accelerations relative to its size. The energy to moment ratio, E0/M0, is 4.2e-6 (Pérez-Campos, Singh and Beroza, 2003), a value similar to the Feb, 1996 earthquake. This value is low compared to other thrust events in the region. The earthquake also had the largest (Ms-Mw) disparity along the Mexican subduction zone, 7.4 vs 8.0. The event produced relatively large tsunami. On the contrary, the 3 June 1932 earthquake (Ms8.2, Mw8.0), that is believed to have broken the same segment of the subduction zone, appears to be "normal." Based on the available evidence, it may be concluded that the 1932 event broke a deeper patch of the plate interface relative to the 1995 event. The mode of rupture in the subduction zone between the two areas mentioned above is not known. This part of the subduction zone includes the rupture area of the 1985 Michoacán earthquake (Mw8.0) and the "Guerrero Gap" which is a section of the subduction zone that has not had a large earthquake in the last 100 years. The downdip and updip patches on the plate interface, which, generally, rupture independently may slip during one great earthquake. This possibility must be accounted for in the estimation of maximum-magnitude earthquake along the subduction zone.
NASA Astrophysics Data System (ADS)
Bijukchhen, Subeg M.; Takai, Nobuo; Shigefuji, Michiko; Ichiyanagi, Masayoshi; Sasatani, Tsutomu; Sugimura, Yokito
2017-07-01
The Himalayan collision zone experiences many seismic activities with large earthquakes occurring at certain time intervals. The damming of the proto-Bagmati River as a result of rapid mountain-building processes created a lake in the Kathmandu Valley that eventually dried out, leaving thick unconsolidated lacustrine deposits. Previous studies have shown that the sediments are 600 m thick in the center. A location in a seismically active region, and the possible amplification of seismic waves due to thick sediments, have made Kathmandu Valley seismically vulnerable. It has suffered devastation due to earthquakes several times in the past. The development of the Kathmandu Valley into the largest urban agglomerate in Nepal has exposed a large population to seismic hazards. This vulnerability was apparent during the Gorkha Earthquake (Mw7.8) on April 25, 2015, when the main shock and ensuing aftershocks claimed more than 1700 lives and nearly 13% of buildings inside the valley were completely damaged. Preparing safe and up-to-date building codes to reduce seismic risk requires a thorough study of ground motion amplification. Characterizing subsurface velocity structure is a step toward achieving that goal. We used the records from an array of strong-motion accelerometers installed by Hokkaido University and Tribhuvan University to construct 1-D velocity models of station sites by forward modeling of low-frequency S-waves. Filtered records (0.1-0.5 Hz) from one of the accelerometers installed at a rock site during a moderate-sized (mb4.9) earthquake on August 30, 2013, and three moderate-sized (Mw5.1, Mw5.1, and Mw5.5) aftershocks of the 2015 Gorkha Earthquake were used as input motion for modeling of low-frequency S-waves. We consulted available geological maps, cross-sections, and borehole data as the basis for initial models for the sediment sites. This study shows that the basin has an undulating topography and sediment sites have deposits of varying thicknesses, from 155 to 440 m. These models also show high velocity contrast at the bedrock depth which results in significant wave amplification.[Figure not available: see fulltext.
NASA Technical Reports Server (NTRS)
Botez, D.; Connolly, J. C.
1982-01-01
A new terraced lateral wave confining structure is obtained by liquid phase epitaxy over channeled substrates misoriented perpendicular to the channels' direction. Single spatial and longitudinal mode CW operation is achieved to 50 mW from one facet, in large spot sizes (2 x 7.5 micron, 1/e squared points in intensity) and narrow beams (6 deg x 23 deg), full width half-power). At 70 C ambient temperature CW lasing is obtained to 15 mW from one facet. Weak mode confinement in an asymmetric lateral waveguides provides discrimination against high-order mode oscillation.
Wijting, W K; Laven, J; van Benthem, R A T M; de With, G
2008-11-01
The adsorption of two polymeric surfactants on an organic pigment was investigated. As surfactants the anionic polyacrylic acid sodium salt (PANa, M(W)=15,000) and a non-ionic block copolymer surfactant based on styrene oxide (SO) and ethylene oxide (EO) (M(W)=1500) were used. The adsorption behavior was analyzed by size exclusion chromatography of the supernatant after centrifugation of the pigment dispersions. It was found that PANa has no affinity to the pigment, whereas SO-EO has a strong affinity to the pigment surface. Competitive adsorption of PANa and SO-EO was not observed. Addition of SO-EO yields stable dispersions.
Jechow, Andreas; Schedel, Marco; Stry, Sandra; Sacher, Joachim; Menzel, Ralf
2007-10-15
A continuous-wave distributed feedback diode laser emitting at 976 nm was frequency doubled by the use of a periodically poled lithium niobate waveguide crystal with a channel size of 3 microm x 5 microm and an interaction length of 10 mm. A laser to waveguide coupling efficiency of 75% could be achieved resulting in 304 mW of incident infrared light inside the waveguide. Blue laser light emission of 159 mW at 488 nm has been generated, which equals to a conversion efficiency of 52%. The resulting wall plug efficiency was 7.4%.
Calce, Enrica; Mercurio, Flavia Anna; Leone, Marilisa; Saviano, Michele; De Luca, Stefania
2016-06-05
An environmentally sustainable and energy-efficient synthetic process has been developed to prepare hyaluronan-based nano-sized material. It consists in a microwave-promoted acylation of the hydroxyl function of the polysaccharide with natural fatty acids, performed under solvent-free conditions. The efficient interaction of the solid reagents with the MW radiation accounts for the obtained high yielded products. The self-assembly process of the obtained compounds very fast occurred in an aqueous medium under MW-radiation, thus allowing the development of a green protocol for the nano-particles preparation. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Rai, Padmnabh; Mohapatra, Dipti R.; Hazra, K. S.; Misra, D. S.; Ghatak, Jay; Satyam, P. V.
2008-03-01
The Raman spectra of the multi-walled carbon nanotubes are studied with the laser power of 5-20 mW. We observe the Raman bands at ˜1352, 1581, 1607, and 2700 cm -1 with 5 mW laser power. As the laser power is increased to 10, 15 and 20 mW, the radial breathing modes (RBMs) of the single wall carbon nanotubes (SWNTs) appear in the range 200-610 cm -1. The diameter corresponding to the highest RBM is ˜0.37 nm, the lowest reported so far. The RBMs are attributed to the local synthesis of the SWNTs at the top surface of the samples at higher laser power.
Effective flocculation of Chlorella vulgaris using chitosan with zeta potential measurement
NASA Astrophysics Data System (ADS)
Low, Y. J.; Lau, S. W.
2017-06-01
Microalgae are considered as one promising source of third-generation biofuels due to their fast growth rates, potentially higher yield rates and wide ranges of growth conditions. However, the extremely low biomass concentration in microalgae cultures presents a great challenge to the harvesting of microalgae because a large volume of water needs to be removed to obtain dry microalgal cells for the subsequent oil extraction process. In this study, the fresh water microalgae Chlorella vulgaris (C. vulgaris) was effectively harvested using both low molecular weight (MW) and high MW chitosan flocculants. The flocculation efficiency was evaluated by physical appearance, supernatant absorbance, zeta potential and solids content after centrifugal dewatering. High flocculation efficiency of 98.0-99.0% was achieved at the optimal dosage of 30-40 mg/g with formation of large microalgae flocs. This study suggests that the polymer bridging mechanism was governing the flocculation behaviour of C. vulgaris using high MW chitosan. Besides, charge patch neutralisation mechanism prevailed at low MW chitosan where lower dosage was sufficient to reach near-zero zeta potential compared with the high MW chitosan. The amount of chitosan polymer present in the culture may also affect the mechanism of flocculation.
NASA Astrophysics Data System (ADS)
Takayama, Toru; Mochida, Atsunori; Orita, Kenji; Tamura, Satoshi; Ohnishi, Toshikazu; Yuri, Masaaki; Shimizu, Hirokazu
2002-05-01
High-power (>100mW) 820 nm-band distributed Bragg reflector (DBR) laser diodes (LDs) with stable fundamental transverse mode operation and continuous wavelength tuning characteristics have been developed. To obtain high-power LDs with a stable fundamental transverse mode in 820 nm wavelength range, an AlGaAs narrow stripe (2.0 micrometers ) real refractive-index-guided self-aligned (RISA) structure is utilized. In the RISA structure, the index step between inside and outside the stripe region ((Delta) n) can be precisely controlled in the order of 10-3). To maintain a stable fundamental transverse mode up to an output power over 100 mW, (Delta) n is designed to be 4x10-3. Higher-order transverse modes are effectively suppressed by a narrow stripe geometry. Further, to achieve continuous wavelength tuning capability, the three-section LD structure, which consists of the active (700micrometers ), phase control (300micrometers ), and DBR(500micrometers ) sections, is incorporated. Our DBR LDs show a maximum output power over 200mW with a stable fundamental transverse mode, and wavelength tuning characteristics ((Delta) (lambda) ~2nm) under 100 mW CW operation.
Regatieri, I C; Boligon, A A; Baldi, F; Albuquerque, L G
2012-08-29
We investigated genetic associations between mature cow weight (MW) and weaning weight (WW), yearling weight (YW), weight gain from birth to weaning (GBW), weight gain from weaning to yearling (GWY), weaning hip height (WHH), yearling hip height (YHH), scrotal circumference (SC), and age at first calving (AFC). Data from 127,104 Nellore animals born between 1993 and 2006, belonging to Agropecuária Jacarezinho Ltda., were analyzed. (Co)variance components were obtained by the restricted maximum likelihood method, applying an animal model in a multi-traits analysis. The model included direct genetic and residual effects as random effects, the fixed effects of contemporary group, and the linear and quadratic effects of animal age at recording (except for AFC, GBW, and GWY) and age of cow at calving as covariates (except for MW). The numbers of days from birth to weaning and from weaning to yearling were included as covariates for GBW and GWY, respectively. Estimated direct heritabilities were 0.43 ± 0.02 (MW), 0.33 ± 0.01 (WW), 0.36 ± 0.01 (YW), 0.28 ± 0.02 (GBW), 0.31 ± 0.01 (GWY), 0.44 ± 0.02 (WHH), 0.48 ± 0.02 (YHH), 0.44 ± 0.01 (SC), and 0.16 ± 0.03 (AFC). Genetic correlations between MW and productive traits were positive and of medium to high magnitude (ranging from 0.47 ± 0.03 to 0.71 ± 0.01). A positive and low genetic correlation was observed between MW and SC (0.24 ± 0.04). A negative genetic correlation (-0.19 ± 0.03) was estimated between MW and AFC. Selection to increase weight or weight gains at any age, as well as hip height, will change MW in the same direction. Selection for higher SC may lead to a long-term increase in MW. The AFC can be included in selection indices to improve the reproductive performance of beef cattle without significant changes in MW.
Dust coagulation and magnetic field strength in a planet-induced gap subject to MRI turbulence
NASA Astrophysics Data System (ADS)
Carballido, Augusto; Matthews, Lorin; Hyde, Truell
2017-01-01
We investigate the coagulation of dust particles in and around a gap opened by a Jupiter-mass planet. To this end, we carry out a high-resolution magnetohydrodynamic (MHD) simulation of the gap environment, which is turbulent due to the magneto rotational instability. From the MHD simulation, we obtain values of the gas velocities, densities and turbulent stresses close to the gap edge, in one of the two gas streams that accrete onto the planet, and inside the low-density gap. The MHD values are then supplied to a Monte Carlo dust coagulation algorithm, which models grain sticking, compaction and bouncing. We consider two dust populations for each region: one whose initial size distribution is monodisperse, with monomer radius equal to 1 micron, and another one whose initial size distribution follows the Mathis-Rumpl-Nordsieck distribution for interstellar dust grains, with an initial range of monomer radii between 0.5 and 10 microns. Without bouncing, our Monte Carlo calculations show steady growth of dust aggregates in all regions, and the mass-weighted (MW) average porosity of the initially mono disperse population reaches extremely high final values of 98%. The final MW porosities in all other cases without bouncing range from 30% to 82%. The efficiency of compaction is due to high turbulent relative speeds between dust particles. When bouncing is introduced, growth is slowed down in the planetary wake and inside the gap.We also analyze the strength of the magnetic field threading the gaps opened by planets of different sub-Jovian masses. Preliminary results show that, in a gap opened by a large-mass planet (~ 1 MJ), the time-averaged radial profile of the vertical component of the field (Bz) increases sharply inside the gap, and less sharply in the case of less massive planets. In gaps opened by intermediate-mass planets (~ 0.5 — 0.75 MJ), the radial profile of Bz exhibits local maxima in the vicinity of the planet, but not at the gap center.
Estimating the Mass of the Milky Way Using the Ensemble of Classical Satellite Galaxies
NASA Astrophysics Data System (ADS)
Patel, Ekta; Besla, Gurtina; Mandel, Kaisey; Sohn, Sangmo Tony
2018-04-01
High precision proper motion (PM) measurements are available for approximately 20% of all known dwarf satellite galaxies of the Milky Way (MW). Here we extend the Bayesian framework of Patel et al. to include all MW satellites with measured 6D phase-space information and apply it with the Illustris-Dark simulation to constrain the MW’s mass. Using the properties of each MW satellite individually, we find that the scatter among mass estimates is reduced when the magnitude of specific orbital angular momentum (j) is adopted, rather than their combined instantaneous positions and velocities. We also find that high j satellites (i.e., Leo II) constrain the upper limits for the MW’s mass and low j satellites, rather than the highest speed satellites (i.e., Leo I and Large Magellanic Cloud), set the lower mass limits. When j of all classical satellites is used to simultaneously estimate the MW’s mass, we conclude the halo mass is 0.85+0.23 ‑0.26 × 1012 {M}ȯ (including Sagittarius dSph) and 0.96+0.29 ‑0.28 × 1012 {M}ȯ (excluding Sagittarius dSph), cautioning that low j satellites on decaying orbits like Sagittarius dSph may bias the distribution. These estimates markedly reduce the current factor of two spread in the mass range of the MW. We also find a well-defined relationship between host halo mass and satellite j distribution, which yields the prediction that upcoming PMs for ultra-faint dwarfs should reveal j within 5 × 103–104 kpc km s‑1. This is a promising method to significantly constrain the cosmologically expected mass range for the MW and eventually M31 as more satellite PMs become available.
North American tidal power prospects
NASA Astrophysics Data System (ADS)
Wayne, W. W., Jr.
1981-07-01
Prospects for North American tidal power electrical generation are reviewed. Studies by the US Army Corps of Engineers of 90 possible generation schemes in Cobscook Bay, ME, indicated that maximum power generation rather than dependable capacity was the most economic method. Construction cost estimates for 15 MW bulb units in a single effect mode from basin to the sea are provided; five projects were considered ranging from 110-160 MW. Additional tidal power installations are examined for: Half-Moon Cove, ME (12 MW, 18 ft tide); Cook Inlet, AK, which is shown to pose severe environmental and engineering problems due to fish migration, earthquake hazards, and 300 ft deep silt deposits; and the Bay of Fundy, Canada. This last has a 17.8 MW plant under construction in a 29 ft maximum tide area. Other tidal projects of the Maritime Provinces are reviewed, and it is noted that previous economic evaluations based on an oil price of $16/barrel are in need of revision.
Conceptual design of ocean thermal energy conversion (OTEC) power plants in the Philippines
DOE Office of Scientific and Technical Information (OSTI.GOV)
Haruo Uehara; Dilao, C.O.; Tsutomu Nakaoka
1988-01-01
Extensive temperature readings were obtained to determine suitable OTEC power plant sites in the Philippines. An analysis of temperature profiles reveals that surface seawater is in the range of 25 to 29{degree}C throughout the year while seawater at 500 to 700 m depth remains at a low temperature of 8 to 4{degree}C, respectively. In this article, 14 suitable sites within the Philippine seas are suggested. Conceptual designs for a 5-MW onland-type and a 25-MW floating-type OTEC power plant are proposed. Optimum conditions are determined and plant specifications are computed. Cost estimates show that a floating-type 25-MW OTEC power plant canmore » generate electricity at a busbar power cost of 5.33 to 7.57 cents/kW {times} h while an onshore type 5-MW plant can generate electricity at a busbar cost of 14.71 to 18.09 cents/kW {times} h.« less
Transmission Reinforcements in the Central American Regional Power System
DOE Office of Scientific and Technical Information (OSTI.GOV)
Elizondo, Marcelo A.; Vallem, Mallikarjuna R.; Samaan, Nader A.
The Central American regional interconnected power system (SER) connects the countries members of the Central American regional electricity market (MER): Guatemala, El Salvador, Honduras, Nicaragua, Costa Rica, and Panama. The SER was a result of a long term regional effort, and was initially conceived to transfer 300 MW between countries. However, the current transfer limits between countries range from 70 MW to 300 MW. Regional entities, like CRIE (Regional Commission of Electrical Interconnection), EOR (Central American Regional System Operator), and CDMER (Board of Directors of the Central American Market) are working on coordinating the national transmission expansion plans with regionalmore » transmission planning efforts. This paper presents experience in Central America region to recommend transmission reinforcements to achieve 300 MW transfer capacity between any pair of member countries of the Central American regional electricity market (MER). This paper also provides a methodology for technical analysis and for coordination among the regional and national entities. This methodology is unique for transmission systems of these characteristics.« less
Sun, Lijun; Li, Jin; Cai, Jun; Zhong, Lian; Ren, Guohui; Ma, Qimin
2017-12-15
Gold nanoparticles (AuNPs) were synthesized in one-step by reducing gold salt using nontoxic and biodegradable chitosan as dual roles of reducing agent and stabilizer. The obtained AuNPs were characterized with UV-vis spectroscopy and transmission electron microscopy. The results indicated that control over the size and shape of AuNPs is achieved through the careful selection of experimental conditions, such as reaction temperature, reaction time, concentration of gold salt and chitosan, and chitosan molecular parameters, i.e., degree of deacetylation (DD) and molecular weight (MW). At low chitosan concentration (0.005% and 0.01% (w/v)), individual spherical AuNPs with average particle size around 10nm were obtained regardless of chitosan DD and MW, while anisotropic AuNPs were obtained at concentration above 0.05% (w/v) for all investigated chitosan at the optimum condition (1mL of 1mmol/L HAuCl 4 added to 3mL of chitosan solution reacted for 120min at 70°C). The growth of larger polygonal AuNPs was promoted as the higher concentration and lower DD chitosan was used as reducing agent and stabilizer. Au nanoplate was synthesized by water-soluble chitosan (M v 566kDa, DD 53%) at concentration above 0.15% (w/v). Chitooligomers (M v 2.4kDa, DD 94%) showed the highest reduction ability for Au 3+ and the synthesized AuNPs exhibited aggregation on morphology. It was considered that chitosan DD and concentration played a more important role than MW in the size and shape of AuNPs. Copyright © 2017 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Iwata, T.; Asano, K.; Kubo, H.
2014-12-01
The source model of the 2014 South Napa earthquake (Mw6.0) is estimated using broad band strong ground motion simulation by the empirical Green's function method (Irikura, 1986, Irikura et al., 1997). We used the CESMD strong motion data. Aftershock ground motion records of Mw3.6 which occurred at 05:33 on 24th August (PDT), are used as an empirical Green's function. We refer to the finite source model by Dreger et al. (2014) for setting the geometry of the source fault plane and the rupture velocity. We assume a single rectangular strong motion generation area (e.g. Miyake et al., 2003; Asano and Iwata, 2012). The seismic moment ratio between the target and EGF events is fixed from the moment magnitudes. As only five station data are available for the aftershock records, the size of SMGA area, rupture starting point, and the rise time on the SMGA are determined by the trial and error. Preliminary SMGA model is 6x6km2 and the rupture mainly propagates WNW and shallower directions. The SMGA size we obtained follows the empirical relationship of Mw and SMGA size for the inland crustal events (Irikura and Miyake, 2011). Waveform fittings are fairly well at the near source station NHC (Huichica creek) and 68150 (Napa Collage), where as the fitting is not good at the south-side stations, 68206 (Crockett - Carquinez Br. Geotech Array) and 68310 (Vallejo - Hwy 37/Napa River E Geo. Array). Particularly, we did not succeed in explaining the high PGA at the 68206 surface station. We will try to improve our SMGA model and will discuss the origin of the high PGA observed at that station.
Wilson Corners SWMU 001 2015 Annual Long Term Monitoring Report Kennedy Space Center, Florida
NASA Technical Reports Server (NTRS)
Lawson, Emily M.
2016-01-01
This document presents the findings of the 2015 Long Term Monitoring (LTM) that was completed at the Wilson Corners site, located at the National Aeronautics and Space Administration John F. Kennedy Space Center, Florida. The objectives of the 2015 LTM event were to evaluate the groundwater flow direction and gradient, to monitor the vertical and horizontal extent of the volatile organic compounds (VOCs; including the upgradient and sidegradient extents, which are monitored every five years), and to monitor select locations internal to the dissolved groundwater plume. The 2015 LTM event included several upgradient and sidegradient monitoring wells that are not sampled annually to verify the extent of VOCs in this portion of the site. The December 2015 LTM groundwater sampling event included, depth to groundwater measurements, 40 VOC samples collected using passive diffusion bags, and one VOC sample collected using low-flow techniques. Additionally, monitoring well MW0052DD was overdrilled and abandoned using rotasonic drilling techniques. The following conclusions can be made based on the 2015 LTM results: groundwater flow is generally to the west with northwest and southwest flow components from the water table to approximately 55 feet below land surface (ft BLS); peripheral monitoring wells generally delineate VOCs to groundwater cleanup target levels (GCTLs) except for monitoring wells MW0088, MW0090, MW0095, and NPSHMW0039, which had vinyl chloride (VC) concentrations near the GCTL and MW0062, which had trichloroethene (TCE), cis-1,2-dichloroethenen (cDCE), and VC concentrations above natural attenuation default concentrations (NADCs); VOCs in interior downgradient wells generally fluctuate within historic ranges except for monitoring wells in the north-northwest portion of the site, which have increasing VC concentrations indicating potential plume migration and expansion; Historically, the vertical extents of the VOCs were delineated by monitoring wells screened greater than 60 ft BLS (MW0083 through MW0086, and MW0078). The 2015 LTM results indicate that concentrations of daughter product cDCE is greater than the NADC in MW0078 and that cDCE and VC are greater than NADCs in MW0130. TCE was greater than the GCTL in monitoring well MW130 and not detected above method detection limits (9 micrograms per Liter) in monitoring well MW0078. No GCTL exceedances were identified in monitoring wells MW0083 or MW0086; the dissolved plume footprint appears generally stable, though not fully delineated by monitoring well data in the northeast portion of the site; and 2015 LTM results generally support the existing Conceptual Site Model. Geosyntec recommends modifying the LTM program, collecting a verification sample from monitoring well MW0062, and performing a direct push technology instigation in the northnortheastern portion of the site. A cluster of monitoring wells (MW0132 [2 to 12 ft BLS], MW0133 [15 to 25 ft BLS], and MW0134 [29 to 34 ft BLS]) is proposed to delineate impacts in the northnortheast portion of the site. Geosyntec recommends installation of a vertical extent well in the center of the site (Hot Spot 2 area) post-remediation implementation.
Gawande, Manoj B; Shelke, Sharad N; Zboril, Radek; Varma, Rajender S
2014-04-15
The magic of microwave (MW) heating technique, termed the Bunsen burner of the 21st century, has emerged as a valuable alternative in the synthesis of organic compounds, polymers, inorganic materials, and nanomaterials. Important innovations in MW-assisted chemistry now enable chemists to prepare catalytic materials or nanomaterials and desired organic molecules, selectively, in almost quantitative yields and with greater precision than using conventional heating. By controlling the specific MW parameters (temperature, pressure, and ramping of temperature) and choice of solvents, researchers can now move into the next generation of advanced nanomaterial design and development. Microwave-assisted chemical reactions are now well-established practices in the laboratory setting although some controversy lingers as to how MW irradiation is able to enhance or influence the outcome of chemical reactions. Much of the discussion has focused on whether the observed effects can, in all instances, be rationalized by purely thermal Arrhenius-based phenomena (thermal microwave effects), that is, the importance of the rapid heating and high bulk reaction temperatures that are achievable using MW dielectric heating in sealed reaction vessels, or whether these observations can be explained by so-called "nonthermal" or "specific microwave" effects. In recent years, innovative and significant advances have occurred in MW hardware development to help delineate MW effects, especially the use of silicon carbide (SiC) reaction vessels and the accurate measurement of temperature using fiber optic (FO) temperature probes. SiC reactors appear to be good alternatives to MW transparent borosilicate glass, because of their high microwave absorptivity, and as such they serve as valuable tools to demystify the claimed magical MW effects. This enables one to evaluate the influence of the electromagnetic field on the specific chemical reactions, under truly identical conventional heating conditions, wherein temperature is measured accurately by fiber optic (FO) probe. This Account describes the current status of MW-assisted synthesis highlighting the introduction of various prototypes of equipment, classes of organic reactions pursued using nanomaterials, and the synthesis of unique and multifunctional nanomaterials; the ensuing nanomaterials possess zero-dimensional to three-dimensional shapes, such as spherical, hexagonal, nanoprisms, star shapes, and nanorods. The synthesis of well-defined nanomaterials and nanocatalysts is an integral part of nanotechnology and catalysis science, because it is imperative to control their size, shape, and compositional engineering for unique deployment in the field of nanocatalysis and organic synthesis. MW-assisted methods have been employed for the convenient and reproducible synthesis of well-defined noble and transition core-shell metallic nanoparticles with tunable shell thicknesses. Some of the distinctive attributes of MW-selective heating in the synthesis and applications of magnetic nanocatalysts in organic synthesis under benign reaction conditions are highlighted. Sustainable nanomaterials and their applications in benign media are an ideal blend for the development of greener methodologies in organic synthesis; MW heating provides superb value to the overall sustainable process development via process intensification including the flow systems.
Gibson, Larry H; Coughlin, Robert W
2002-01-01
Of five strains of Aureobasidium pullulans studied, NRRL Y-2311-1 yielded the highest titer (26.2 g/L) of pullulan and formed the lowest amount of melanin-like pigment. Sucrose was superior to glucose as the carbon and energy source on the basis of yield and titer of pullulan produced. Pullulan titer was higher (26.2 vs 5.1 g/L), biomass concentration was lower (6.9 vs 12.7 g/L), and DO was lower (0 vs 60% of saturation) when the fermenter was agitated by a marine propeller compared to Rushton impellers. Pullulan produced by strain NRRL Y-2311-1 ranged in weight-average molar mass (M(w)) from 486 KDa and number-average molar mass (M(n)) from 220 Da on day 1 of growth to 390 KDa and 690 Da on day 6; M(w) declined by about 35% from day 1 to day 3, the day of maximum pullulan titer. For the other strains, the ranges of molar mass on the day of maximum pullulan titer were 338-614 KDa (M(w)) and 100-6820 Da (M(n)).
Hattori, Hidemi; Ishihara, Masayuki
2015-01-22
Because the molecular weight (Mw) and degree of deacetylation (DDA) of chitosan can vary depending on the purification method, the identification of appropriate chitosan structures is important for developing more effective hemostatic agents. In this study, the influence of varying Mw and DDA of chitosan on blood aggregation was characterized by 10 types of chitosan with different Mw and DDA, including oligomers. The highest aggregation of whole blood, washed erythrocytes and platelets in platelet-rich plasma (PRP) were observed in chitosan with Mw of 8.6 kDa or more and with DDA of 75 to 88%. However, chitosan with too high Mw (247 kDa) inhibited the aggregation of whole blood, washed erythrocytes and PRP at high chitosan concentration. At certain concentrations, chitosan with 75-85% DDA and 50-190 kDa and chitosan with 87.6% DDA and 247 kDa both aggregated proteins in PRP. Chitosan oligomer did not affect blood aggregation. The results suggested that the aggregation by chitosan depended on the interaction of positively charged chitosan with negatively charged erythrocytes, platelets and plasma protein. It seemed that a suitable balance of positive charge in chitosan and negative charge in hemocytes and some kinds of proteins was important. To develop a hemostatic with effective blood aggregation, the chitosan should not be limited to a single Mw and a single DDA but may be a mixed chitosan with wide range of Mw (8.6-247 kDa) and DDA of 75 to 88%.
NASA Astrophysics Data System (ADS)
Sips, A. C. C.; Giruzzi, G.; Ide, S.; Kessel, C.; Luce, T. C.; Snipes, J. A.; Stober, J. K.
2015-02-01
The development of operating scenarios is one of the key issues in the research for ITER which aims to achieve a fusion gain (Q) of ˜10, while producing 500 MW of fusion power for ≥300 s. The ITER Research plan proposes a success oriented schedule starting in hydrogen and helium, to be followed by a nuclear operation phase with a rapid development towards Q ˜ 10 in deuterium/tritium. The Integrated Operation Scenarios Topical Group of the International Tokamak Physics Activity initiates joint activities among worldwide institutions and experiments to prepare ITER operation. Plasma formation studies report robust plasma breakdown in devices with metal walls over a wide range of conditions, while other experiments use an inclined EC launch angle at plasma formation to mimic the conditions in ITER. Simulations of the plasma burn-through predict that at least 4 MW of Electron Cyclotron heating (EC) assist would be required in ITER. For H-modes at q95 ˜ 3, many experiments have demonstrated operation with scaled parameters for the ITER baseline scenario at ne/nGW ˜ 0.85. Most experiments, however, obtain stable discharges at H98(y,2) ˜ 1.0 only for βN = 2.0-2.2. For the rampup in ITER, early X-point formation is recommended, allowing auxiliary heating to reduce the flux consumption. A range of plasma inductance (li(3)) can be obtained from 0.65 to 1.0, with the lowest values obtained in H-mode operation. For the rampdown, the plasma should stay diverted maintaining H-mode together with a reduction of the elongation from 1.85 to 1.4. Simulations show that the proposed rampup and rampdown schemes developed since 2007 are compatible with the present ITER design for the poloidal field coils. At 13-15 MA and densities down to ne/nGW ˜ 0.5, long pulse operation (>1000 s) in ITER is possible at Q ˜ 5, useful to provide neutron fluence for Test Blanket Module assessments. ITER scenario preparation in hydrogen and helium requires high input power (>50 MW). H-mode operation in helium may be possible at input powers above 35 MW at a toroidal field of 2.65 T, for studying H-modes and ELM mitigation. In hydrogen, H-mode operation is expected to be marginal, even at 2.65 T with 60 MW of input power. Simulation code benchmark studies using hybrid and steady state scenario parameters have proved to be a very challenging and lengthy task of testing suites of codes, consisting of tens of sophisticated modules. Nevertheless, the general basis of the modelling appears sound, with substantial consistency among codes developed by different groups. For a hybrid scenario at 12 MA, the code simulations give a range for Q = 6.5-8.3, using 30 MW neutral beam injection and 20 MW ICRH. For non-inductive operation at 7-9 MA, the simulation results show more variation. At high edge pedestal pressure (Tped ˜ 7 keV), the codes predict Q = 3.3-3.8 using 33 MW NB, 20 MW EC, and 20 MW ion cyclotron to demonstrate the feasibility of steady-state operation with the day-1 heating systems in ITER. Simulations using a lower edge pedestal temperature (˜3 keV) but improved core confinement obtain Q = 5-6.5, when ECCD is concentrated at mid-radius and ˜20 MW off-axis current drive (ECCD or LHCD) is added. Several issues remain to be studied, including plasmas with dominant electron heating, mitigation of transient heat loads integrated in scenario demonstrations and (burn) control simulations in ITER scenarios.
Understanding the Milky Way Halo through Large Surveys
NASA Astrophysics Data System (ADS)
Koposov, Sergey
This thesis presents an extensive study of stellar substructure in the outskirts of the Milky Way(MW), combining data mining of SDSS with theoretical modeling. Such substructure, either bound star clusters and satellite galaxies, or tidally disrupted objects forming stellar streams are powerful diagnostics of the Milky Way's dynamics and formation history. I have developed an algorithmic technique of searching for stellar overdensities in the MW halo, based on SDSS catalogs. This led to the discovery of unusual ultra-faint ~ (1000Lsun) globular clusters with very compact sizes and relaxation times << t_Hubble. The detailed analysis of a known stellar stream (GD-1), allowed me to make the first 6-D phase space map for such an object along 60 degrees on the sky. By modeling the stream's orbit I could place strong constraints on the Galactic potential, e.g. Vcirc(R0)= 224+/-13 km/s. The application of the algorithmic search for stellar overdensities to the SDSS dataset and to mock datasets allowed me to quantify SDSS's severe radial incompleteness in its search for ultra-faint dwarf galaxies and to determine the luminosity function of MW satellites down to luminosities of M_V ~ -3. I used the semi-analytical model in order to compare the CDM model predictions for the MW satellite population with the observations; this comparison has shown that the recently increased census of MW satellites, better understanding of the radial incompleteness and the suppression of star formation after the reionization can fully solve the "Missing satellite problem".
Xiao, Fanrong; Nicholson, Charles; Hrabe, Jan; Hrabetová, Sabina
2008-08-01
There are a limited number of methods available to quantify the extracellular diffusion of macromolecules in an anisotropic brain region, e.g., an area containing numerous aligned fibers where diffusion is faster along the fibers than across. We applied the integrative optical imaging method to measure diffusion of the fluorophore Alexa Fluor 488 (molecular weight (MW) 547) and fluorophore-labeled flexible random-coil dextran polymers (dex3, MW 3000; dex75, MW 75,000; dex282, MW 282,000; dex525, MW 525,000) in the extracellular space (ECS) of the anisotropic molecular layer of the isolated turtle cerebellum. For all molecules, two-dimensional images acquired an elliptical shape with major and minor axes oriented along and across, respectively, the unmyelinated parallel fibers. The effective diffusion coefficients, D*(major) and D*(minor), decreased with molecular size. The diffusion anisotropy ratio (DAR = D*(major)/D*(minor)) increased for Alexa Fluor 488 through dex75 but then unexpectedly reached a plateau. We argue that dex282 and dex525 approach the ECS width and deform to diffuse. In support of this concept, scaling theory shows the diffusion behavior of dex282 and dex525 to be consistent with transition to a reptation regime, and estimates the average ECS width at approximately 31 nm. These findings have implications for the interstitial transport of molecules and drugs, and for modeling neurotransmitter diffusion during ectopic release and spillover.
Yin, Jiefu; Brady, Alexander B.; Takeuchi, Esther S.; ...
2017-03-06
MgMn 2O 4 nanoparticles with crystallite sizes of 11 (MMO-1) and 31 nm (MMO-2) were synthesized and their magnesium-ion battery-relevant electrochemistry was investigated. Here, MMO-1 delivered an initial capacity of 220 mA h g –1 (678 mW h g –1). Electrolyte water content had a profound effect on cycle retention.
Virginia | Midmarket Solar Policies in the United States | Solar Research |
rates. System size limit: Residential 20 kW, non-residential 1 MW, agricultural 500 kW. New agricultural : Agricultural customers can aggregate electric meters into a single account up to 500 kW; not addressed for
NASA Astrophysics Data System (ADS)
Pei, Kai; Li, Hongdong; Zou, Guangtian; Yu, Richeng; Zhao, Haofei; Shen, Xi; Wang, Liying; Song, Yanpeng; Qiu, Dongchao
2017-02-01
A novel electrolyte materials of introducing detonation nanodiamond (DNDs) into samarium doped ceria (SDC) is reported here. 1%wt. DNDs doping SDC (named SDC/ND) can enlarge the electrotyle grain size and change the valence of partial ceria. DNDs provide the widen channel to accelerate the mobility of oxygen ions in electrolyte. Larger grain size means that oxygen ions move easier in electrolyte, it can also reduce the alternating current (AC) impedance spectra of internal grains. The lower valence of partial Ce provides more oxygen vacancies to enhance mobility rate of oxygen ions. Hence all of them enhance the transportation of oxygen ions in SDC/ND electrolyte and the OCV. Ultimately the power density of SOFC can reach 762 mw cm-2 at 800 °C (twice higher than pure SDC, which is 319 mw cm-2 at 800 °C), and it remains high power density in the intermediate temperature (600-800 °C). It is relatively high for the electrolyte supported (300 μm) cells.
High-pressure microhydraulic actuator
Mosier, Bruce P [San Francisco, CA; Crocker, Robert W [Fremont, CA; Patel, Kamlesh D [Dublin, CA
2008-06-10
Electrokinetic ("EK") pumps convert electric to mechanical work when an electric field exerts a body force on ions in the Debye layer of a fluid in a packed bed, which then viscously drags the fluid. Porous silica and polymer monoliths (2.5-mm O.D., and 6-mm to 10-mm length) having a narrow pore size distribution have been developed that are capable of large pressure gradients (250-500 psi/mm) when large electric fields (1000-1500 V/cm) are applied. Flowrates up to 200 .mu.L/min and delivery pressures up to 1200 psi have been demonstrated. Forces up to 5 lb-force at 0.5 mm/s (12 mW) have been demonstrated with a battery-powered DC-DC converter. Hydraulic power of 17 mW (900 psi@ 180 uL/min) has been demonstrated with wall-powered high voltage supplies. The force and stroke delivered by an actuator utilizing an EK pump are shown to exceed the output of solenoids, stepper motors, and DC motors of similar size, despite the low thermodynamic efficiency.
Le Feunteun, Steven; Mariette, François
2007-12-26
The translational dynamics of poly(ethylene glycol) (PEG) polymers with molecular weights (Mw) varying from 6x10(2) to 5x10(5) were investigated by pulsed field gradient NMR in casein suspensions and in gels induced by acidification, enzyme action, and a combination of both. For molecules with Mw
2011-03-18
efficiency of the OPO, but ranges from up to 15 mW on target in the UV to 50 mW in the visible. This ability to illuminate a target with a broad...been back illuminated and coated for enhanced UV response. The run file which automates the collection process uses several input parameters to...analyzed by a Agilent spectrophotometer to determine absorbance characteristics of the liquid. The remaining mixture was then placed into a standard UV
Enhanced gene expression promoted by hybrid magnetic/cationic block copolymer micelles.
Haladjova, E; Rangelov, S; Tsvetanov, Ch B; Posheva, V; Peycheva, E; Maximova, V; Momekova, D; Mountrichas, G; Pispas, S; Bakandritsos, A
2014-07-15
We report on novel gene delivery vector systems based on hybrid polymer-magnetic micelles. The hybrid micelles were prepared by codissolution of hydrophobically surface modified iron oxide and amphiphilic polystyrene-b-poly(quaternized 2-vinylpyridine) block copolymer (PS-b-P2QVP) in organic solvent. After extensive dialysis against water, micelles with positively charged hydrophilic corona of PQVP and hydrophobic PS core were prepared, in which magnetic nanoparticles were randomly distributed. The hybrid micelles were used to form complexes with linear (salmon sperm, 2000 bp, corresponding to M(w) of 1.32 × 10(6) Da) and plasmid (pEGFP-N1, 4730 bp, corresponding to M(w) of 3.12 × 10(6) Da) DNA. The resulting magnetopolyplexes of phosphate:amine (P/N) ratios in the 0.05-20 range were characterized by light scattering, ζ-potential measurements, and transmission electron microscopy as well as cytotoxicity and gel retardation assays. The investigated systems displayed a narrow size distribution, particle dimensions below 360 nm, whereas their ζ-potential values varied from positive to negative depending of the P/N ratio. The resulting vector nanosystems exhibited low toxicity. They were able to introduce pEGFP-N1 molecules into the cells. The application of a magnetic field markedly boosted the transgene expression efficiency of the magnetopolyplexes, which was even superior to those of commercial transfectants such as Lipofectamine and dendritic polyethylenimine.
NASA Astrophysics Data System (ADS)
Huang, Mong-Han; Fielding, Eric J.; Dickinson, Haylee; Sun, Jianbao; Gonzalez-Ortega, J. Alejandro; Freed, Andrew M.; Bürgmann, Roland
2017-01-01
The 4 April 2010 Mw 7.2 El Mayor-Cucapah (EMC) earthquake in Baja, California, and Sonora, Mexico, had primarily right-lateral strike-slip motion and a minor normal-slip component. The surface rupture extended about 120 km in a NW-SE direction, west of the Cerro Prieto fault. Here we use geodetic measurements including near- to far-field GPS, interferometric synthetic aperture radar (InSAR), and subpixel offset measurements of radar and optical images to characterize the fault slip during the EMC event. We use dislocation inversion methods and determine an optimal nine-segment fault geometry, as well as a subfault slip distribution from the geodetic measurements. With systematic perturbation of the fault dip angles, randomly removing one geodetic data constraint, or different data combinations, we are able to explore the robustness of the inferred slip distribution along fault strike and depth. The model fitting residuals imply contributions of early postseismic deformation to the InSAR measurements as well as lateral heterogeneity in the crustal elastic structure between the Peninsular Ranges and the Salton Trough. We also find that with incorporation of near-field geodetic data and finer fault patch size, the shallow slip deficit is reduced in the EMC event by reductions in the level of smoothing. These results show that the outcomes of coseismic inversions can vary greatly depending on model parameterization and methodology.
On-Chip Power-Combining for High-Power Schottky Diode-Based Frequency Multipliers
NASA Technical Reports Server (NTRS)
Chattopadhyay, Goutam; Mehdi, Imran; Schlecht, Erich T.; Lee, Choonsup; Siles, Jose V.; Maestrini, Alain E.; Thomas, Bertrand; Jung, Cecile D.
2013-01-01
A 1.6-THz power-combined Schottky frequency tripler was designed to handle approximately 30 mW input power. The design of Schottky-based triplers at this frequency range is mainly constrained by the shrinkage of the waveguide dimensions with frequency and the minimum diode mesa sizes, which limits the maximum number of diodes that can be placed on the chip to no more than two. Hence, multiple-chip power-combined schemes become necessary to increase the power-handling capabilities of high-frequency multipliers. The design presented here overcomes difficulties by performing the power-combining directly on-chip. Four E-probes are located at a single input waveguide in order to equally pump four multiplying structures (featuring two diodes each). The produced output power is then recombined at the output using the same concept.
Apollo - An advanced fuel fusion power reactor for the 21st century
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kulcinski, G.L.; Emmert, G.A.; Blanchard, J.P.
1989-03-01
A preconceptual design of a tokamak reactor fueled by a D-He-3 plasma is presented. A low aspect ratio (A=2-4) device is studied here but high aspect ratio devices (A > 6) may also be quite attractive. The Apollo D-He-3 tokamak capitalizes on recent advances in high field magnets (20 T) and utilizes rectennas to convert the synchrotron radiation directly to electricity. The overall efficiency ranges from 37 to 52% depending on whether the bremsstrahlung energy is utilized. The low neutron wall loading (0.1 MW/m/sup 2/) allows a permanent first wall to be designed and the low nuclear decay heat enablesmore » the reactor to be classed as inherently safe. The cost of electricity from Apollo is > 40% lower than electricity from a similar sized DT reactor.« less
Performance evaluation of tubular fuel cells fuelled by pulverized graphite
NASA Astrophysics Data System (ADS)
Kim, Jong-Pil; Lim, Ho; Jeon, Chung-Hwan; Chang, Young-June; Koh, Kwang-Nak; Choi, Soon-Mok; Song, Ju-Hun
A fuel cell fuelled by carbonaceous graphite is proposed. The tubular fuel cell, with the carbon in a fixed-bed form on the anode side, is employed to convert directly the chemical energy of carbon into electricity. Surface platinum electrodes are coated on the cell electrolyte, which is a yttria-stabilized zirconia (YSZ) tube of 1.5 mm thickness. The effect of using different sizes of graphite powder (in the range 0-180 μm) as fuel is analyzed. Power density and actual open-circuit voltage (OCV) values are measured as the temperature is varied from 0 to 950 °C. The cell provides a maximum power density of 16.8 mW cm -2 and an OCV of 1.115 V at the highest temperature condition (950 °C) tested in this study.
Examination of the Entry to Burn and Burn Control for the ITER 15 MA Baseline and Other Scenarios
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kesse, Charles E.; Kim, S-H.; Koechl, F.
2014-09-01
The entry to burn and flattop burn control in ITER will be a critical need from the first DT experiments. Simulations are used to address time-dependent behavior under a range of possible conditions that include injected power level, impurity content (W, Ar, Be), density evolution, H-mode regimes, controlled parameter (Wth, Pnet, Pfusion), and actuator (Paux, fueling, fAr), with a range of transport models. A number of physics issues at the L-H transition require better understanding to project to ITER, however, simulations indicate viable control with sufficient auxiliary power (up to 73 MW), while lower powers become marginal (as low asmore » 43 MW).« less
NASA Astrophysics Data System (ADS)
Cho, Hyoup Je; Choi, Gyeong Man
A Ni-YSZ (Y 2O 3-stabilized ZrO 2) composite is commonly used as a solid oxide fuel cell anode. The composite powders are usually synthesized by mixing NiO and YSZ powders. The particle size and distribution of the two phases generally determine the performance of the anode. Two different milling methods are used to prepare the composite anode powders, namely, high-energy milling and ball-milling that reduce the particle size. The particle size and the Ni distribution of the two composite powders are examined. The effects of milling on the performance are evaluated by using both an electrolyte-supported, symmetric Ni-YSZ/YSZ/Ni-YSZ cell and an anode-supported, asymmetric cell. The performance is examined at 800 °C by impedance analysis and current-voltage measurements. Pellets made by using high-energy milled NiO-YSZ powders have much smaller particle sizes and a more uniform distribution of Ni particles than pellets made from ball-milled powder, and thus the polarization resistance of the electrode is also smaller. The maximum power density of the anode-supported cell prepared by using the high-energy milled powder is ∼850 mW cm -2 at 800 °C compared with ∼500 mW cm -2 for the cell with ball-milled powder. Thus, high-energy milling is found to be more effective in reducing particle size and obtaining a uniform distribution of Ni particles.
Energy density of anchovy Engraulis encrasicolus in the Bay of Biscay.
Dubreuil, J; Petitgas, P
2009-02-01
The energy density (E(D)) of anchovy Engraulis encrasicolus in the Bay of Biscay was determined by direct calorimetry and its evolution with size, age and season was investigated. The water content and energy density varied seasonally following opposite trends. The E(D) g(-1) of wet mass (M(W)) was highest at the end of the feeding season (autumn: c. 8 kJ g(-1)M(W)) and lowest in late winter (c. 6 kJ g(-1)M(W)). In winter, the fish lost mass, which was partially replaced by water, and the energy density decreased. These variations in water content and organic matter content may have implications on the buoyancy of the fish. The water content was the major driver of the energy density variations for a M(W) basis. A significant linear relationship was established between E(D) g(-1) (y) and the per cent dry mass (M(D); x): y =-4.937 + 0.411x. In the light of the current literature, this relationship seemed to be not only species specific but also ecosystem specific. Calibration and validation of fish bioenergetics models require energy content measurements on fish samples collected at sea. The present study provides a first reference for the energetics of E. encrasicolus in the Bay of Biscay.
A Pragmatic Approach to Sales Training
ERIC Educational Resources Information Center
Buzzotta, V. R.; And Others
1974-01-01
A systematic ten-step approach to behavioral sales training is offered: (1) sales-behavior training goals, (2) cognitive maps, (3) sizing-up of skills, (4) selling techniques, (5) realistic practice, (6) feedback, (7) individual business goals, (8) plan of action, (9) review of results, and (10) research results. (MW)
NASA Astrophysics Data System (ADS)
Zhao, J. F.; Liao, T. Q.; Zhang, C.; Zhang, R. X.; Miao, C. Y.; Tong, Z. R.
2012-09-01
A 50 nm tuning range multiwavelength Brillouin-erbium fiber laser (MWBEFL) with double Brillouin frequency spacing is presented. Two separated gain blocks with symmetrical architecture, consisted by erbium-doped fiber amplifiers (EDFAs) and Brillouin gain media, are used to generate double Brillouin frequency spacing. The wider tuning range is realized by eliminating the self-lasing cavity modes existing in conventional MWBEFLs because of the absence of the physical mirrors at the ends of the linear cavity. The Brillouin pump (BP) is preamplified by the EDFA before entering the single-mode fiber (SMF), which leads to the reduction of threshold power and the generation enhancement of Brillouin Stokes (BS) signals. Four channels with 0.176 nm spacing are achieved at 2 mW BP power and 280 mW 980 nm pump power which can be tuned from 1525 to 1575 nm.
NASA Astrophysics Data System (ADS)
Ahmed, M. H. M.; Ali, N. M.; Salleh, Z. S.; Rahman, A. A.; Harun, S. W.; Manaf, M.; Arof, H.
2015-01-01
A passive, stable and low cost Q-switched Erbium-doped fiber laser (EDFL) is demonstrated using both single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs), which are embedded in polyethylene oxide (PEO) film as a saturable absorber (SA). The film is sandwiched between two FC/PC fiber connectors and integrated into the laser cavity for Q-switching pulse generation operating at wavelength of 1533.6 nm. With SWCNTs, the laser produces a stable pulse train with repetition rate and pulse width ranging from 9.52 to 33.33 kHz and 16.8 to 8.0 μs while varying the 980 nm pump power from 48.5 mW to 100.4 mW. On the other hand, with MWCNTs, the repetition rate and pulse width can be tuned in a wider range of 6.12-33.62 kHz and 9.5- 4.2 μs, respectively as the pump power increases from 37.9 to 120.6 mW. The MWCNTs produce the pulse train at a lower threshold and attain a higher repetition rate compared to the SWCNTs. This is due to thicker carbon nanotubes layer of the MWCNTs which provides more absorption and consequently higher damage threshold. The Q-switched EDFL produces the highest pulse energy of 531 nJ at pump power of 37.9 mW with the use of MWCNTs-PEO SA.
Efficient arsenate removal by magnetite-modified water hyacinth biochar.
Zhang, Feng; Wang, Xin; Xionghui, Ji; Ma, Lijuan
2016-09-01
Magnetic biochars (MW) prepared by chemical co-precipitation of Fe(2+)/Fe(3+) on water hyacinth biomass followed by pyrolysis exhibited important potential in aqueous As(V) elimination. In comparison, MW2501 outperformed other MWs and exhibited the highest As(V) sorption capacity which was estimated to be 7.4 mg g(-1) based on Langmuir-Freundlic model. With solution pH ranging from 3 to 10, As(V) removal efficiency by MW2501 kept stable and consistently higher than 90%. Besides, ∼100% removal of 0.5 mM As(V) can be obtained in the presence of P ≤ 0.1 mM or Cr/Sb ≤ 0.5 mM, indicating a wide applicability of MW2501 for treatment of As-containing water. The predominance of Fe3O4 on MW2501 surface was evidenced by XRD. Ligand exchange between As(V) anion and the hydroxylated surface of Fe3O4 as well as H bond was largely responsible for As(V) sorption as suggested by FTIR. XPS analysis further revealed the dominance of As(V) in the sorbed As on MW2501 surface with co-occurrence of a minor proportion of As(III) (11.45%). In parallel, oxidative transformation of Fe3O4 to Fe2O3 was also suggested by XPS. By a lab-scale column test, the potential and suitability of MW2501 in As-containing water treatment was further confirmed, which could also provide an alternative way to manage and utilize this highly problematic invasive species. Copyright © 2016 Elsevier Ltd. All rights reserved.
Lai, Jui-Yang; Lu, Pei-Lin; Chen, Ko-Hua; Tabata, Yasuhiko; Hsiue, Ging-Ho
2006-06-01
Cell transplantation strategies usually involve the use of supporting carrier materials because of the soft and fragile nature of these grafts. In this work, a cell-adhesive gelatin hydrogel carrier was fabricated to deliver cultivated human corneal endothelial cell (HCEC) sheets, which were harvested from thermo-responsive poly(N-isopropylacrylamide) (PNIPAAm)-grafted culture surfaces. The carrier disks, consisting of gelatins with a different isoelectric point (IEP = 5.0 and 9.0) and a molecular weight (MW) ranging from 3 to 100 kDa, were subjected to 16.6 kGy gamma irradiation for sterilization. The effect of IEP and MW of the raw gelatins (i.e., before irradiation) on the functionality of sterilized disks was studied by determinations of mechanical property, water content, dissolution degree, and cytocompatibility. Irrespective of the IEP of raw gelatin, hydrogel disks prepared with high MW (100 kDa) exhibited a greater tensile strength, lower water content, and slower dissolution rate than those made of low MW gelatin (8 and 3 kDa). From the investigation of cellular responses to the disks, the negatively charged gelatin (IEP = 5.0) groups were more cytocompatible when compared with their positively charged counterparts (IEP = 9.0) at the same MW (100 kDa). Additionally, in the negatively charged gelatin groups, only a slight increase in pro-inflammatory cytokine expression was observed with increasing MW of gelatin from 3 to 100 kDa. It is concluded that the gamma-sterilized hydrogel disks made from raw gelatins (IEP = 5.0, MW = 100 kDa) with appropriate dissolution degree and acceptable cytocompatibility are capable of providing stable mechanical support, making these carriers promising candidates for intraocular delivery of cultivated HCEC sheets.
I, Satish Kumar; C, Vijaya Kumar; G, Gangaraju; Nath, Sapna; A K, Thiruvenkadan
2017-10-01
In the present study, (co)variance components and genetic parameters in Nellore sheep were obtained by restricted maximum likelihood (REML) method using six different animal models with various combinations of direct and maternal genetic effects for birth weight (BW), weaning weight (WW), 6-month weight (6MW), 9-month weight (9MW) and 12-month weight (YW). Evaluated records of 2075 lambs descended from 69 sires and 478 dams over a period of 8 years (2007-2014) were collected from the Livestock Research Station, Palamaner, India. Lambing year, sex of lamb, season of lambing and parity of dam were the fixed effects in the model, and ewe weight was used as a covariate. Best model for each trait was determined by log-likelihood ratio test. Direct heritability for BW, WW, 6MW, 9MW and YW were 0.08, 0.03, 0.12, 0.16 and 0.10, respectively, and their corresponding maternal heritabilities were 0.07, 0.10, 0.09, 0.08 and 0.11. The proportions of maternal permanent environment variance to phenotypic variance (Pe 2 ) were 0.07, 0.10, 0.07, 0.06 and 0.10 for BW, WW, 6MW, 9MW and YW, respectively. The estimates of direct genetic correlations among the growth traits were positive and ranged from 0.44(BW-WW) to 0.96(YW-9MW), and the estimates of phenotypic and environmental correlations were found to be lower than those of genetic correlations. Exclusion of maternal effects in the model resulted in biased estimates of genetic parameters in Nellore sheep. Hence, to implement optimum breeding strategies for improvement of traits in Nellore sheep, maternal effects should be considered.
Interaction mechanisms of condensed tannins (proanthocyanidins) with wheat gluten proteins
USDA-ARS?s Scientific Manuscript database
Proanthocyanidins (PA) crosslink wheat gluten, increasing its polymer size and strength. However, precise mechanisms behind these interactions are unknown. This study used PA of different MW profiles (mDP 8.3 and 19.5) to investigate the interactions involved in PA polymerization of gluten. The high...
Solar thermal electricity generation
NASA Astrophysics Data System (ADS)
Gasemagha, Khairy Ramadan
1993-01-01
This report presents the results of modeling the thermal performance and economic feasibility of large (utility scale) and small solar thermal power plants for electricity generation. A number of solar concepts for power systems applications have been investigated. Each concept has been analyzed over a range of plant power ratings from 1 MW(sub e) to 300 MW(sub e) and over a range of capacity factors from a no-storage case (capacity factor of about 0.25 to 0.30) up to intermediate load capacity factors in the range of 0.46 to 0.60. The solar plant's economic viability is investigated by examining the effect of various parameters on the plant costs (both capital and O & M) and the levelized energy costs (LEC). The cost components are reported in six categories: collectors, energy transport, energy storage, energy conversion, balance of plant, and indirect/contingency costs. Concentrator and receiver costs are included in the collector category. Thermal and electric energy transport costs are included in the energy transport category. Costs for the thermal or electric storage are included in the energy storage category; energy conversion costs are included in the energy conversion category. The balance of plant cost category comprises the structures, land, service facilities, power conditioning, instrumentation and controls, and spare part costs. The indirect/contingency category consists of the indirect construction and the contingency costs. The concepts included in the study are (1) molten salt cavity central receiver with salt storage (PFCR/R-C-Salt); (2) molten salt external central receiver with salt storage (PFCR/R-E-Salt); (3) sodium external central receiver with sodium storage (PFCR/RE-Na); (4) sodium external central receiver with salt storage (PFCR/R-E-Na/Salt); (5) water/steam external central receiver with oil/rock storage (PFCR/R-E-W/S); (6) parabolic dish with stirling engine conversion and lead acid battery storage (PFDR/SLAB); (7) parabolic dish with stirling engine conversion and redox advanced battery storage (PFDR/S-RAB); and (8) parabolic trough with oil/rock storage (LFDR/R-HT-45). Key annual efficiency and economic results of the study are highlighted in tabular format for plant sizes and capacity factor that resulted in the lowest LEC over the analysis range.
NASA Astrophysics Data System (ADS)
Darwiesh, M.; El-Sherif, Ashraf F.; El-Ghandour, Hatem; Aly, Hussein A.; Mokhtar, A. M.
2011-03-01
Optical imaging systems are widely used in different applications include tracking for portable scanners; input pointing devices for laptop computers, cell phones, and cameras, fingerprint-identification scanners, optical navigation for target tracking, and in optical computer mouse. We presented an experimental work to measure and analyze the laser speckle pattern (LSP) produced from different optical sources (i.e. various color LEDs, 3 mW diode laser, and 10mW He-Ne laser) with different produced operating surfaces (Gabor hologram diffusers), and how they affects the performance of the optical imaging systems; speckle size and signal-to-noise ratio (signal is represented by the patches of the speckles that contain or carry information, and noise is represented by the whole remaining part of the selected image). The theoretical and experimental studies of the colorimetry (color correction is done in the color images captured by the optical imaging system to produce realistic color images which contains most of the information in the image by selecting suitable gray scale which contains most of the informative data in the image, this is done by calculating the accurate Red-Green-Blue (RGB) color components making use of the measured spectrum for light sources, and color matching functions of International Telecommunication Organization (ITU-R709) for CRT phosphorus, Tirinton-SONY Model ) for the used optical sources are investigated and introduced to present the relations between the signal-to-noise ratios with different diffusers for each light source. The source surface coupling has been discussed and concludes that the performance of the optical imaging system for certain source varies from worst to best based on the operating surface. The sensor /surface coupling has been studied and discussed for the case of He-Ne laser and concludes the speckle size is ranged from 4.59 to 4.62 μm, which are slightly different or approximately the same for all produced diffusers (which satisfies the fact that the speckle size is independent on the illuminating surface). But, the calculated value of signal-tonoise ratio takes different values ranged from 0.71 to 0.92 for different diffuser. This means that the surface texture affects the performance of the optical sensor because, all images captured for all diffusers under the same conditions [same source (He-Ne laser), same distances of the experimental set-up, and the same sensor (CCD camera)].
Zeuthen*, Thomas; Belhage, Bo; Zeuthen, Emil
2006-01-01
The relation between substrate and water transport was studied in Na+-coupled cotransporters of glucose (SGLT1) and of iodide (NIS) expressed in Xenopus oocytes. The water transport was monitored from changes in oocyte volume at a resolution of 20 pl, more than one order of magnitude better than previous investigations. The rate of cotransport was monitored as the clamp current obtained from two-electrode voltage clamp. The high resolution data demonstrated a fixed ratio between the turn-over of the cotransporter and the rate of water transport. This applied to experiments in which the rate of cotransport was changed by isosmotic application of substrate, by rapid changes in clamp voltage, or by poisoning. Transport of larger substrates gave rise to less water transport. For the rabbit SGLT1, 378 ± 20 (n = 18 oocytes) water molecules were cotransported along with the 2 Na+ ions and the glucose-analogue α-MDG (MW 194); using the larger sugar arbutin (MW 272) this number was reduced by a factor of at least 0.86 ± 0.03 (15). For the human SGLT1 the respective numbers were 234 ± 12 (18) and 0.85 ± 0.8 (7). For NIS, 253 ± 16 (12) water molecules were cotransported for each 2 Na+ and 1 thiocyanate (SCN−, MW 58), with I− as anion (MW 127) only 162 ± 11 (19) water molecules were cotransported. The effect of substrate size suggests a molecular mechanism for water cotransport and is opposite to what would be expected from unstirred layer effects. Data were analysed by a model which combined cotransport and osmosis at the membrane with diffusion in the cytoplasm. The combination of high resolution measurements and precise modelling showed that water transport across the membrane can be explained by cotransport of water in the membrane proteins and that intracellular unstirred layers effects are minute. PMID:16322051
Shyn, Paul B; Bird, Jeffery R; Koch, R Marie; Tatli, Servet; Levesque, Vincent M; Catalano, Paul J; Silverman, Stuart G
2016-09-01
To determine whether total energy (TE) reaching the microwave (MW) applicator or net energy (NE) exiting the applicator (after correcting for reflectivity) correlates better with hepatic MW ablation zone dimensions than manufacturer-provided chart predictions. Single-applicator, nonoverlapping ablations of 93 liver tumors (0.7-5.9 cm) were performed in 52 adult patients. TE and NE were recorded for each ablation. Long axis diameter (LAD), short axis diameter (SAD), and volume (V) of each ablation zone were measured on magnetic resonance imaging or computed tomography after the procedure and retrospectively compared with TE; NE; and manufacturer-provided chart predictions of LAD, SAD, and V using correlation and regression analyses. For treated tumors, mean (± SD) TE and NE were 49.8 kJ (± 22.7) and 36.4 kJ (± 19.4). Mean LAD, SAD, and V were 5.8 cm (± 1.3), 3.7 cm (± 0.8), and 44.1 cm(3) (± 25.4). Correlation coefficients (95% confidence interval) with LAD, SAD, and V were 0.46 (0.28, 0.61), 0.52 (0.36, 0.66), and 0.52 (0.36, 0.66) for TE; 0.42 (0.24, 0.58), 0.55 (0.39, 0.68), and 0.53 (0.36, 0.66) for NE; and 0.51 (0.34, 0.65), 0.63 (0.49, 0.74), and 0.60 (0.45, 0.73) for chart predictions. Using regression analysis and controlling for TE, SAD was 0.34 cm larger in patients with cirrhosis than in patients without cirrhosis. Correcting for reflectivity did not substantially improve correlation of energy values with MW ablation zone size parameters and did not outperform manufacturer-provided chart predictions. Correlations were moderate and variable using all methods. The results suggest a disproportionate influence of tissue factors on MW ablation results. Copyright © 2016 SIR. Published by Elsevier Inc. All rights reserved.
Zhang, Ying; Zhang, Ning; Zhao, Peng; Niu, Zhiguang
2018-03-01
The characteristics of dissolved organic matter (DOM) and bromide ion concentration have a significant influence on the formation of disinfection by-products (DBPs). In order to identify the main DBP precursors, DOM was divided into five fractions based on molecular weight (MW), trihalomethane formation potential and haloacetic acid formation potential were determined for fractions, and the change in contents of different fractions and total DBPs during treatment processes (pre-chlorination, coagulation, sand filtration, disinfection) were studied. Moreover, the relationship between bromide concentration and DBP generation characteristics in processes was also analyzed. The results showed that the main DBP precursors were the fraction with MW <1kDa and fraction with MW 3-10kDa, and the DBP's generation ability of lower molecular weight DOM (<10kDa) was higher than that of higher molecular weight DOM. During different processes, pre-chlorination and disinfection had limited effect on removing organics but could alter the MW distribution, and coagulation and filtration could effectively remove organics with higher MW. For DBPs, trihalomethanes (THMs) were mainly generated in pre-chlorination and disinfection, while haloacetic acids (HAAs) were mostly generated during pre-chlorination; coagulation and sand filtration had little effect on THMs but resulted in a slight removal of HAAs. In addition, the results of ANOVA tests suggested that molecular sizes and treatment processes have significant influence on DBP formation. With increasing bromide concentration, the brominated DBPs significantly increased, but the bromine incorporation factor in the processes was basically consistent at each concentration. Copyright © 2017. Published by Elsevier B.V.
Farm-level feasibility of bioenergy depends on variations across multiple sectors
NASA Astrophysics Data System (ADS)
Myhre, Mitchell; Barford, Carol
2013-03-01
The potential supply of bioenergy from farm-grown biomass is uncertain due to several poorly understood or volatile factors, including land availability, yield variability, and energy prices. Although biomass production for liquid fuel has received more attention, here we present a case study of biomass production for renewable heat and power in the state of Wisconsin (US), where heating constitutes at least 30% of total energy demand. Using three bioenergy systems (50 kW, 8.8 MW and 50 MW) and Wisconsin farm-level data, we determined the net farm income effect of producing switchgrass (Panicum virgatum) as a feedstock, either for on-farm use (50 kW system) or for sale to an off-farm energy system operator (8.8 and 50 MW systems). In southern counties, where switchgrass yields approach 10 Mg ha-1 yr-1, the main determinants of economic feasibility were the available land area per farm, the ability to utilize bioheat, and opportunity cost assumptions. Switchgrass yield temporal variability was less important. For the state median farm size and switchgrass yield, at least 25% (50 kW system) or 50% (8.8 MW system) bioheat utilization was required to economically offset propane or natural gas heat, respectively, and purchased electricity. Offsetting electricity only (50 MW system) did not generate enough revenue to meet switchgrass production expenses. Although the opportunity cost of small-scale (50 kW) on-farm bioenergy generation was higher, it also held greater opportunity for increasing farm net income, especially by replacing propane-based heat.
Characterization of soluble microbial products in a drinking water biological aerated filter.
Kang, Jia; Ma, Teng-Fei; Zhang, Peng; Gao, Xu; Chen, You-Peng
2016-05-01
Utilization-associated products (UAPs) and biomass-associated products (BAPs) were quantified separately in this study to characterize soluble microbial products (SMPs) in a drinking water lab-scale biological aerated filter (BAF), and their basic characteristics were explored using gel filtration chromatography and three-dimensional excitation-emission matrix (3D-EEM) spectrophotometry with fluorescence regional integration analysis and parallel factor model. UAPs were observed increased with the increase of filter media depth and accumulated after BAF treatment, whereas BAPs were basically constant. 3D-EEM spectroscopy analysis result showed that tryptophan and protein-like compounds were the main components of UAPs and BAPs, and fulvic-acid-like substance was a major component of BAPs, rather than UAPs. In terms of molecular weight (MW) distribution, UAP MW presented a bimodal distribution in the range of 1-5 and >10 kDa, while BAP MW exhibited unimodal distribution with MW >20 kDa fraction accounting for more than 90 %. The macromolecules of UAPs accumulated after BAF treatment. This study provides theoretical support for in-depth study of SMP characteristics.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
Twenty-eight geothermal areas in Kenya were evaluated and prioritized for development. The prioritization was based on the potential size, resource temperature, level of exploration risk, location, and exploration/development costs for each geothermal area. Suswa, Eburru and Arus are found to offer the best short-term prospects for successful private power development. It was found that cost per kill developed are significantly lower for the larger (50MW) than for smaller-sized (10 or 20 NW) projects. In addition to plant size, the cost per kill developed is seen to be a function of resource temperature, generation mode (binary or flash cycle) and transmissionmore » distance.« less
Cost and size estimates for an electrochemical bulk energy storage concept
NASA Technical Reports Server (NTRS)
Warshay, M.; Wright, L. O.
1975-01-01
Preliminary capital cost and size estimates were made for a titanium trichloride, titanium tetrachloride, ferric chloride, ferrous chloride redox-flow-cell electric power system. On the basis of these preliminary estimates plus other important considerations, this electrochemical system emerged as having great promise as a bulk energy storage system for power load leveling. The size of this system is less than two per cent of that of a comparable pumped hydroelectric plant. The estimated capital cost of a 10 MW, 60- and 85-MWh redox-flow system compared well with that of competing systems.
A novel in situ permeation system and its utility in cancer tissue ablation
WATANABE, MASAMI
2015-01-01
Focal ablation therapy is an emerging treatment modality for localized cancer lesions. It is an attractive strategy for inhibiting tumor progression and preventing morbidity associated with open surgery. As for intratissue drug delivery systems for use in local therapy, the convection-enhanced delivery (CED) of liquid drugs has been utilized, particularly for the treatment of malignant brain tumors. Although the conventional CED system is useful for providing drug/vehicle-based local therapy, there are several reported disadvantages in terms of the ability to control the extent of drug diffusion. We herein developed and validated a novel in situ permeation (ISP)-MW-1 system for achieving intratissue drug diffusion. The ISP system includes a perfusion catheter connected to an injector and aspirator, which enables intratissue perfusion of the solute diluted in the vehicle in the tip-inserted cavity. We subsequently evaluated the utility of the ISP-MW-1 system for in situ permeation in a subcutaneous tumor model in hamsters. Dehydrated ethanol, saline and 50% acetic acid were evaluated as the vehicle, and methylene blue was used as a dissolved substance for evaluating the diffusion of the agent. As a result, almost all of the tumor tissue within the capsule (tumor size: ~3 cm) was permeated with the dehydrated ethanol and 50% acetic acid and partially with the saline. We further demonstrated that ISP treatment with 50% acetic acid completely ablated the subcutaneous tumors in all of the treated hamsters (n=3). Therefore, the ISP-MW-1 system is a promising approach for controlling the intratissue diffusion of therapeutic agents and for providing local ablation therapy for cancer lesions. We believe that this system may be applicable to a broad range of medicinal and industrial fields, such as regenerative medicine, drug delivery systems, biochemistry and material technologies as well as cancer therapy. PMID:26134633
Solar perspectives - Israel, solar pond innovator
NASA Astrophysics Data System (ADS)
Winsberg, S.
1981-07-01
Existing and planned solar pond electricity producing power plants in Israel and California are discussed. Salt ponds, with salinity increasing with depth, are coupled with low temperature, organic working fluid Rankine cycle engines to form self-storage, nonpolluting, electric plants. Average pond thermal gradients range from 25 C surface to 90 C at the bottom; 160 GW of potential power have been projected as currently available from existing natural solar ponds from a partial survey of 14 countries. The largest installation to date has a 220 kW output, and a 5 MW plant is scheduled for completion in 1983. Efficiencies of 10% and a cost of $2,000/kW for a 40 MW plant are projected, a cost which is comparable to that of conventional plants. The 40 MW plant is an optimized design, allowing for modular plant additions to increase capacity.
Discharge formation in a XеCl laser pumped by high specific power
NASA Astrophysics Data System (ADS)
Panchenko, Yu. N.; Losev, V. F.
2013-02-01
Stable glow of the discharge of various types in the gas mixture of a XeCl laser is investigated for specific pumping power in the range 1.2-4.6 MW/cm3 and pulse duration of 40 ns. It is demonstrated that formation of partially homogeneous plasma with many intensive cathode spots on the electrode allows the maximum energy and duration of the lasing pulse to be obtained with laser efficiency of 2.4%. It is revealed that for the specific pumping powers up to 1.5 MW/cm3, a very homogeneous volume discharge with a small number of lowintensive cathode spots is formed in the discharge gap. With further increase in the specific pumping power exceeding 4.5 MW/cm3, current microinhomogeneities are formed in the volume discharge of this type leading to lasing breakdown.
Deformations and Rotational Ground Motions Inferred from Downhole Vertical Array Observations
NASA Astrophysics Data System (ADS)
Graizer, V.
2017-12-01
Only few direct reliable measurements of rotational component of strong earthquake ground motions are obtained so far. In the meantime, high quality data recorded at downhole vertical arrays during a number of earthquakes provide an opportunity to calculate deformations based on the differences in ground motions recorded simultaneously at different depths. More than twenty high resolution strong motion downhole vertical arrays were installed in California with primary goal to study site response of different geologic structures to strong motion. Deformation or simple shear strain with the rate γ is the combination of pure shear strain with the rate γ/2 and rotation with the rate of α=γ/2. Deformations and rotations were inferred from downhole array records of the Mw 6.0 Parkfield 2004, the Mw 7.2 Sierra El Mayor (Mexico) 2010, the Mw 6.5 Ferndale area in N. California 2010 and the two smaller earthquakes in California. Highest amplitude of rotation of 0.60E-03 rad was observed at the Eureka array corresponding to ground velocity of 35 cm/s, and highest rotation rate of 0.55E-02 rad/s associated with the S-wave was observed at a close epicentral distance of 4.3 km from the ML 4.2 event in Southern California at the La Cienega array. Large magnitude Sierra El Mayor earthquake produced long duration rotational motions of up to 1.5E-04 rad and 2.05E-03 rad/s associated with shear and surface waves at the El Centro array at closest fault distance of 33.4km. Rotational motions of such levels, especially tilting can have significant effect on structures. High dynamic range well synchronized and properly oriented instrumentation is necessary for reliable calculation of rotations from vertical array data. Data from the dense Treasure Island array near San Francisco demonstrate consistent change of shape of rotational motion with depth and material. In the frequency range of 1-15 Hz Fourier amplitude spectrum of vertical ground velocity is similar to the scaled tilt spectrum. Amplitudes of rotations at the site depend upon the size of the base and usually decrease with depth. They are also amplified by soft material. Earthquake data used in this study were downloaded from the Center for Engineering Strong Motion Data at http://www.strongmotioncenter.org/.
Narrow-band double-pass superluminescent diodes emitting at 1060 nm
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lobintsov, A A; Perevozchikov, M V; Shramenko, M V
2009-09-30
Experimental data are presented which show that double-pass superluminescent diodes (SLDs) with fibre Bragg grating (FBG) based spectrally selective external reflectors offer emission linewidths in the range 0.1-1.0 nm, i.e., one to two orders of magnitude narrower in comparison with conventional SLDs and considerably broader in comparison with single-frequency semiconductor lasers. Their optical power at the single-mode fibre output reaches 5.0-8.0 mW, and can be raised to 50 mW using a semiconductor optical amplifier. (lasers)
Submillimeter sources for radiometry using high power Indium Phosphide Gunn diode oscillators
NASA Technical Reports Server (NTRS)
Deo, Naresh C.
1990-01-01
A study aimed at developing high frequency millimeter wave and submillimeter wave local oscillator sources in the 60-600 GHz range was conducted. Sources involved both fundamental and harmonic-extraction type Indium Phosphide Gunn diode oscillators as well as varactor multipliers. In particular, a high power balanced-doubler using varactor diodes was developed for 166 GHz. It is capable of handling 100 mW input power, and typically produced 25 mW output power. A high frequency tripler operating at 500 GHz output frequency was also developed and cascaded with the balanced-doubler. A dual-diode InP Gunn diode combiner was used to pump this cascaded multiplier to produce on the order of 0.5 mW at 500 GHz. In addition, considerable development and characterization work on InP Gunn diode oscillators was carried out. Design data and operating characteristics were documented for a very wide range of oscillators. The reliability of InP devices was examined, and packaging techniques to enhance the performance were analyzed. A theoretical study of a new class of high power multipliers was conducted for future applications. The sources developed here find many commercial applications for radio astronomy and remote sensing.
NASA Astrophysics Data System (ADS)
Kuroda, Natsuha; Wang, Haimin; Gary, Dale E.
2017-08-01
It is well known that the time profiles of the hard X-ray (HXR) emission and the microwave (MW) emission during the impulsive phase of the solar flare are well correlated, and that their analysis can lead to the understandings of the flare-accelerated electrons. In this work, we first studied the source locations of seven distinct temporal peaks observed in HXR and MW lightcurves of the 2011-02-15 X2.2 flare using the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) and Nobeyama Radioheliograph. We found that the seven emission peaks did not come from seven spatially distinct sites in HXR and MW, but rather in HXR we observed a sudden change in location only between the second and the third peak, with the same pattern occurring, but evolving more slowly in MW, which is consistent with the tether-cutting model of solar flares. Next, we closely examine the widely-used notion of a "common population" of the accelerated electrons producing the HXR and the MW, which has been challenged by some studies suggesting the differences in the inferred energy spectral index and emitting energies of the HXR- and MW- producing electrons. We use the Non-linear Force Free Field model extrapolated from the observed photospheric magnetogram in the three-dimensional, multi-wavelength modeling platform GX Simulator, and attempt to create a unified electron population model that can simultaneously reproduce the observed X-ray and MW observations of the 2015-06-22 M6.5 flare. We constrain the model parameters by the observations made by the highest-resolving instruments currently available in two wavelengths, the RHESSI for X-ray and the Expanded Owens Valley Solar Array for MW. The results suggest that the X-ray emitting electron population model fits to the standard flare model with the broken, hardening power-law spectrum at ~300 keV that simultaneously produces the HXR footpoint emission and the MW high frequency emission, and also reveals that there could be a “X-ray invisible” population of nonthermal electrons that are trapped in a large magnetic field volume above the X-ray emitting loops, that emits gyrosynchrotron radiation mainly in MW low frequency range.
Multiwavelength L-band fiber laser with bismuth-oxide EDF and photonic crystal fiber
NASA Astrophysics Data System (ADS)
Ramzia Salem, A. M.; Al-Mansoori, M. H.; Hizam, H.; Mohd Noor, S. B.; Abu Bakar, M. H.; Mahdi, M. A.
2011-05-01
A multiwavelength laser comb using a bismuth-based erbium-doped fiber and 50 m photonic crystal fiber is demonstrated in a ring cavity configuration. The fiber laser is solely pumped by a single 1455 nm Raman pump laser to exploit its higher power delivery compared to that of a single-mode laser diode pump. At 264 mW Raman pump power and 1 mW Brillouin pump power, 38 output channels in the L-band have been realized with an optical signal-to-noise ratio above 15 dB and a Stokes line spacing of 0.08 nm. The laser exhibits a tuning range of 12 nm and produces stable Stokes lines across the tuning range between Brillouin pump wavelengths of 1603 nm and 1615 nm.
Position-insensitive long range inductive power transfer
NASA Astrophysics Data System (ADS)
Kwan, Christopher H.; Lawson, James; Yates, David C.; Mitcheson, Paul D.
2014-11-01
This paper presents results of an improved inductive wireless power transfer system for reliable long range powering of sensors with milliwatt-level consumption. An ultra-low power flyback impedance emulator operating in open loop is used to present the optimal load to the receiver's resonant tank. Transmitter power modulation is implemented in order to maintain constant receiver power and to prevent damage to the receiver electronics caused by excessive received voltage. Received power is steady up to 3 m at around 30 mW. The receiver electronics and feedback system consumes 3.1 mW and so with a transmitter input power of 163.3 W the receiver becomes power neutral at 4.75 m. Such an IPT system can provide a reliable alternative to energy harvesters for supplying power concurrently to multiple remote sensors.
High-damage-threshold antireflection coatings on diamond for CW and pulsed CO2 lasers
NASA Astrophysics Data System (ADS)
Komlenok, M. S.; Pivovarov, P. A.; Volodkin, B. O.; Pavelyev, V. S.; Anisimov, V. I.; Butuzov, V. V.; Sorochenko, V. R.; Nefedov, S. M.; Mineev, A. P.; Soifer, V. A.; Konov, V. I.
2018-03-01
A multilayer antireflection coating for diamond optics that allows work in the infrared spectral range of 8 -12 µm with minimal optical losses is developed. The optical transmittance of a chemical vapour deposition diamond plate coated with this film on both sides exceeds 94% over the whole specified wavelength range. The coatings deposited on the diamond plate were damage-tested by coherent-wave and pulsed (τ = 90 ns) CO2 lasers. Results of the tests demonstrated that the coating can withstand prolonged radiation loads with intensity above 3 MW cm-2 in a continuous-mode laser exposure. In the case of a nanosecond pulsed action, destruction of the coating begins at intensities greater than 50 MW cm-2.
Rotor instability due to a gear coupling connected to a bearingless sun wheel of a planetary gear
NASA Technical Reports Server (NTRS)
Buehlmann, E. T.; Luzi, A.
1989-01-01
A 21 MW electric power generating unit comprises a gas turbine, a planetary gear, and a generator connected together by gear couplings. For simplicity of the design and high performance the pinion of the gear has no bearing. It is centered by the planet wheels only. The original design showed a strong instability and a natural frequency increasing with the load between 2 and 6.5 MW. In this operating range the natural frequency was below the operating speed of the gas turbine, n sub PT = 7729 RPM. By shortening the pinion shaft and reduction of its moment of inertia the unstable natural frequency was shifted well above the operating speed. With that measure the unit now operates with stability in the entire load range.
Macro-spin modeling and experimental study of spin-orbit torque biased magnetic sensors
NASA Astrophysics Data System (ADS)
Xu, Yanjun; Yang, Yumeng; Luo, Ziyan; Xu, Baoxi; Wu, Yihong
2017-11-01
We reported a systematic study of spin-orbit torque biased magnetic sensors based on NiFe/Pt bilayers through both macro-spin modeling and experiments. The simulation results show that it is possible to achieve a linear sensor with a dynamic range of 0.1-10 Oe, power consumption of 1 μW-1mW, and sensitivity of 0.1-0.5 Ω/Oe. These characteristics can be controlled by varying the sensor dimension and current density in the Pt layer. The latter is in the range of 1 × 105-107 A/cm2. Experimental results of fabricated sensors with selected sizes agree well with the simulation results. For a Wheatstone bridge sensor comprising of four sensing elements, a sensitivity up to 0.548 Ω/Oe, linearity error below 6%, and detectivity of about 2.8 nT/√Hz were obtained. The simple structure and ultrathin thickness greatly facilitate the integration of these sensors for on-chip applications. As a proof-of-concept experiment, we demonstrate its application in detection of current flowing in an on-chip Cu wire.
Active heat exchange system development for latent heat thermal energy storage
NASA Technical Reports Server (NTRS)
Lefrois, R. T.; Knowles, G. R.; Mathur, A. K.; Budimir, J.
1979-01-01
Active heat exchange concepts for use with thermal energy storage systems in the temperature range of 250 C to 350 C, using the heat of fusion of molten salts for storing thermal energy are described. Salt mixtures that freeze and melt in appropriate ranges are identified and are evaluated for physico-chemical, economic, corrosive and safety characteristics. Eight active heat exchange concepts for heat transfer during solidification are conceived and conceptually designed for use with selected storage media. The concepts are analyzed for their scalability, maintenance, safety, technological development and costs. A model for estimating and scaling storage system costs is developed and is used for economic evaluation of salt mixtures and heat exchange concepts for a large scale application. The importance of comparing salts and heat exchange concepts on a total system cost basis, rather than the component cost basis alone, is pointed out. The heat exchange concepts were sized and compared for 6.5 MPa/281 C steam conditions and a 1000 MW(t) heat rate for six hours. A cost sensitivity analysis for other design conditions is also carried out.
Eckert, Kristen A; Carter, Marissa J; Lansingh, Van C; Wilson, David A; Furtado, João M; Frick, Kevin D; Resnikoff, Serge
2015-01-01
To estimate the annual loss of productivity from blindness and moderate to severe visual impairment (MSVI) using simple models (analogous to how a rapid assessment model relates to a comprehensive model) based on minimum wage (MW) and gross national income (GNI) per capita (US$, 2011). Cost of blindness (COB) was calculated for the age group ≥50 years in nine sample countries by assuming the loss of current MW and loss of GNI per capita. It was assumed that all individuals work until 65 years old and that half of visual impairment prevalent in the ≥50 years age group is prevalent in the 50-64 years age group. For cost of MSVI (COMSVI), individual wage and GNI loss of 30% was assumed. Results were compared with the values of the uncorrected refractive error (URE) model of productivity loss. COB (MW method) ranged from $0.1 billion in Honduras to $2.5 billion in the United States, and COMSVI ranged from $0.1 billion in Honduras to $5.3 billion in the US. COB (GNI method) ranged from $0.1 million in Honduras to $7.8 billion in the US, and COMSVI ranged from $0.1 billion in Honduras to $16.5 billion in the US. Most GNI method values were near equivalent to those of the URE model. Although most people with blindness and MSVI live in developing countries, the highest productivity losses are in high income countries. The global economy could improve if eye care were made more accessible and more affordable to all.
Rapid determination of the energy magnitude Me
NASA Astrophysics Data System (ADS)
di Giacomo, D.; Parolai, S.; Bormann, P.; Grosser, H.; Saul, J.; Wang, R.; Zschau, J.
2009-12-01
The magnitude of an earthquake is one of the most used parameters to evaluate the earthquake’s damage potential. Among the non-saturating magnitude scales, the energy magnitude Me is related to a well defined physical parameter of the seismic source, that is the radiated seismic energy Es (e.g. Bormann et al., 2002): Me = 2/3(log10 Es - 4.4). Me is more suitable than the moment magnitude Mw in describing an earthquake's shaking potential (Choy and Kirby, 2004). Indeed, Me is calculated over a wide frequency range of the source spectrum and represents a better measure of the shaking potential, whereas Mw is related to the low-frequency asymptote of the source spectrum and is a good measure of the fault size and hence of the static (tectonic) effect of an earthquake. We analyse teleseismic broadband P-waves signals in the distance range 20°-98° to calculate Es. To correct the frequency-dependent energy loss experienced by the P-waves during the propagation path, we use pre-calculated spectral amplitude decay functions for different frequencies obtained from numerical simulations of Green’s functions (Wang, 1999) given the reference Earth model AK135Q (Kennett et al., 1995; Montagner and Kennett, 1996). By means of these functions the correction for the various propagation effects of the recorded P-wave velocity spectra is performed in a rapid and robust way, and the calculation of ES, and hence of Me, can be computed at the single station. We show that our procedure is suitable for implementation in rapid response systems since it could provide stable Me determinations within 10-15 minutes after the earthquake’s origin time, even in case of great earthquakes. We tested our procedure for a large dataset composed by about 770 earthquakes globally distributed in the Mw range 5.5-9.3 recorded at the broadband stations managed by the IRIS, GEOFON, and GEOSCOPE global networks, as well as other regional seismic networks. Me and Mw express two different aspects of the seismic source, and a combined use of these two magnitude scales would allow a better assessment of the tsunami and shaking potential of an earthquake. Representative case studies will be also shown and discussed. References Bormann, P., Baumbach, M., Bock, G., Grosser, H., Choy, G. L., and Boatwright, J. (2002). Seismic sources and source parameters, in IASPEI New Manual of Seismological Observatory Practice, P. Bormann (Editor), Vol. 1, GeoForschungsZentrum, Potsdam, Chapter 3, 1-94. Choy, G. L., and Kirby, S. (2004). Apparent stress, fault maturity and seismic hazard for normal-fault earthquakes at subduction zones. Geophys. J. Int., 159, 991-1012. Kennett, B. L. N., Engdahl, E. R., and Buland, R. (1995). Constraints on seismic velocities in the Earth from traveltimes. Geophys. J. Int., 122, 108-124. Montagner, J.-P., and Kennett, B. L. N. (1996). How to reconcile body-wave and normal-mode reference Earth models?. Geophys. J. Int., 125, 229-248. Wang, R. (1999). A simple orthonormalization method for stable and efficient computation of Green’s functions. Bull. Seism. Soc. Am., 89(3), 733-741.
Rapidly dissolving polymeric microneedles for minimally invasive intraocular drug delivery.
Thakur, Raghu Raj Singh; Tekko, Ismaiel A; Al-Shammari, Farhan; Ali, Ahlam A; McCarthy, Helen; Donnelly, Ryan F
2016-12-01
In this study, dissolving microneedles (MNs) were used to enhance ocular drug delivery of macromolecules. MNs were fabricated using polyvinylpyrrolidone (PVP) polymer of various molecular weights (MWs) containing three model molecules of increasing MW, namely fluorescein sodium and fluorescein isothiocyanate-dextrans (with MW of 70 k and 150 k Da). Arrays (3 × 3) of PVP MNs with conical shape measuring about 800 μm in height with a 300 μm base diameter, containing the model drugs, were fabricated and characterized for their fracture forces, insertion forces (in the sclera and cornea), depth of penetration (using OCT and confocal imaging), dissolution time and in vitro permeation. The average drug content of the MNs (only in MN shafts) ranged from 0.96 to 9.91 μg, and the average moisture content was below 11 %. High MW PVP produced MNs that can withstand higher forces with minimal reduction in needle height. PVP MNs showed rapid dissolution that ranged from 10 to 180 s, which was dependent upon PVP's MW. In vitro studies showed significant enhancement of macromolecule permeation when MNs were used, across both the corneal and scleral tissues, in comparison to topically applied aqueous solutions. Confocal images showed that the macromolecules formed depots within the tissues, which led to sustained permeation. However, use of MNs did not significantly benefit the permeation of small molecules; nevertheless, MN application has the potential for drug retention within the selected ocular tissues unlike topical application for small molecules. The material used in the fabrication of the MNs was found to be biocompatible with retinal cells (i.e. ARPE-19). Overall, this study reported the design and fabrication of minimally invasive rapidly dissolving polymeric MN arrays which were able to deliver high MW molecules to the eye via the intrastromal or intrascleral route. Thus, dissolving MNs have potential applications in enhancing ocular delivery of both small and macromolecules.
METALLICITY EVOLUTION OF THE SIX MOST LUMINOUS M31 DWARF SATELLITES
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ho, Nhung; Geha, Marla; Tollerud, Erik J.
We present global metallicity properties, metallicity distribution functions (MDFs), and radial metallicity profiles for the six most luminous M31 dwarf galaxy satellites: M32, NGC 205, NGC 185, NGC 147, Andromeda VII, and Andromeda II. The results presented are the first spectroscopic MDFs for dwarf systems surrounding a host galaxy other than the Milky Way (MW). Our sample consists of individual metallicity measurements for 1243 red giant branch member stars spread across these six systems. We determine metallicities based on the strength of the Ca II triplet lines using the empirical calibration of Carrera et al., which is calibrated over the metallicity range –4 < [Fe/H] <+0.5. We findmore » that these M31 satellites lie on the same luminosity-metallicity relationship as the MW dwarf satellites. We do not find a trend between the internal metallicity spread and galaxy luminosity, contrary to previous studies. The MDF widths of And II and And VII are similar to the MW dwarf spheroidal (dSph) satellites of comparable luminosity; however, our four brightest M31 dwarf satellites are more luminous than any of the MW dSphs and have broader MDFs. The MDFs of our six M31 dwarf satellites are consistent with the leaky box model of chemical evolution, although our metallicity errors allow a wide range of evolution models. We find a significant radial gradient in metallicity in only two of our six systems, NGC 185 and Andromeda II, and flat radial metallicity gradients in the rest of our sample with no observed correlation between rotational support and radial metallicity gradients. Although the average properties and radial trends of the M31 dwarf galaxies agree with their MW counterparts at similar luminosity, the detailed MDFs are different, particularly at the metal-rich end.« less
Luco, N.; Bazzurro, P.
2007-01-01
Limitations of the existing earthquake ground motion database lead to scaling of records to obtain seismograms consistent with a ground motion target for structural design and evaluation. In the engineering seismology community, acceptable limits for 'legitimate' scaling vary from one (no scaling allowed) to 10 or more. The concerns expressed by detractors of scaling are mostly based on the knowledge of, for example, differences in ground motion characteristics for different earthquake magnitude-distance (Mw-Rclose) scenarios, and much less on their effects on structures. At the other end of the spectrum, proponents have demonstrated that scaling is not only legitimate but also useful for assessing structural response statistics for Mw-Rclose scenarios. Their studies, however, have not investigated more recent purposes of scaling and have not always drawn conclusions for a wide spectrum of structural vibration periods and strengths. This article investigates whether scaling of records randomly selected from an Mw-Rclose bin (or range) to a target fundamental-mode spectral acceleration (Sa) level introduces bias in the expected nonlinear structural drift response of both single-degree-of-freedom oscillators and one multi-degree-of-freedom building. The bias is quantified relative to unscaled records from the target Mw-Rclose bin that are 'naturally' at the target Sa level. We consider scaling of records from the target Mw-Rclose bin and from other Mw-Rclose bins. The results demonstrate that scaling can indeed introduce a bias that, for the most part, ca be explained by differences between the elastic response spectra of the scaled versus unscaled records. Copyright ?? 2007 John Wiley & Sons, Ltd.
Cloud Tolerance of Remote-Sensing Technologies to Measure Land Surface Temperature
NASA Technical Reports Server (NTRS)
Holmes, Thomas R. H.; Hain, Christopher R.; Anderson, Martha C.; Crow, Wade T.
2016-01-01
Conventional methods to estimate land surface temperature (LST) from space rely on the thermal infrared(TIR) spectral window and is limited to cloud-free scenes. To also provide LST estimates during periods with clouds, a new method was developed to estimate LST based on passive microwave(MW) observations. The MW-LST product is informed by six polar-orbiting satellites to create a global record with up to eight observations per day for each 0.25resolution grid box. For days with sufficient observations, a continuous diurnal temperature cycle (DTC) was fitted. The main characteristics of the DTC were scaled to match those of a geostationary TIR-LST product. This paper tests the cloud tolerance of the MW-LST product. In particular, we demonstrate its stable performance with respect to flux tower observation sites (four in Europe and nine in the United States), over a range of cloudiness conditions up to heavily overcast skies. The results show that TIR based LST has slightly better performance than MW-LST for clear-sky observations but suffers an increasing negative bias as cloud cover increases. This negative bias is caused by incomplete masking of cloud-covered areas within the TIR scene that affects many applications of TIR-LST. In contrast, for MW-LST we find no direct impact of clouds on its accuracy and bias. MW-LST can therefore be used to improve TIR cloud screening. Moreover, the ability to provide LST estimates for cloud-covered surfaces can help expand current clear-sky-only satellite retrieval products to all-weather applications.
Liu, Xianwen; Sun, Changzheng; Xiong, Bing; Wang, Jian; Wang, Lai; Han, Yanjun; Hao, Zhibiao; Li, Hongtao; Luo, Yi; Yan, Jianchang; Wei, Tong Bo; Zhang, Yun; Wang, Junxi
2016-08-01
An all-optically tunable microwave photonic phase shifter is demonstrated based on an epitaxial aluminum nitride (AlN) microring with an intrinsic quality factor of 3.2×106. The microring adopts a pedestal structure, which allows overcoupling with 700 nm gap size and facilitates the fabrication process. A phase shift for broadband signals from 4 to 25 GHz is demonstrated by employing the thermo-optic effect and the separate carrier tuning technique. A phase tuning range of 0°-332° is recorded with a 3 dB radio frequency (RF) power variation and 48 mW optical power consumption. In addition, AlN exhibits intrinsic second-order optical nonlinearity. Thus, our work presents a novel platform with a low propagation loss and the capability of electro-optic modulation for applications in integrated microwave photonics.
Miniaturized multiple Fourier-horn ultrasonic droplet generators for biomedical applications.
Tsai, Chen S; Mao, Rong W; Lin, Shih K; Wang, Ning; Tsai, Shirley C
2010-10-21
Here we report micro-electro-mechanical system (MEMS)-based miniaturized silicon ultrasonic droplet generators of a new and simple nozzle architecture with multiple Fourier horns in resonance but without a central channel. The centimetre-sized nozzles operate at one to two MHz and a single vibration mode which readily facilitates temporal instability of Faraday waves to produce monodisperse droplets. Droplets with diameter range 2.2-4.6 μm are produced at high throughput of 420 μl min(-1) and very low electrical drive power of 80 mW. We also report the first theoretical prediction of the droplet diameter. The resulting MHz ultrasonic devices possess important advantages and demonstrate superior performance over earlier devices with a central channel and thus have high potential for biomedical applications such as efficient and effective delivery of inhaled medications and encapsulated therapy to the lung.
Berenbaum, Francis; Grifka, Joachim; Cazzaniga, Sara; D'Amato, Massimo; Giacovelli, Giampaolo; Chevalier, Xavier; Rannou, Francois; Rovati, Lucio C; Maheu, Emmanuel
2012-01-01
Objectives To compare the effects of an intermediate molecular weight (MW) intra-articular hyaluronic acid (HA) with a low MW product on knee osteoarthritis (OA) symptoms. Methods Patients with symptomatic knee OA were enrolled inarandomised, controlled, double-blind, parallel-group, non-inferiority trial with the possibility to shift to superiority. Patients were randomised to GO-ON(MW 800–1500 kD, 25 mg/2.5 ml) or Hyalgan(MW 500–730 kD, 20 mg/2 ml) injected at 3-weekly intervals. The primary outcome was 6-month change in the WOMAC pain subscale (0–100 mm). Sample size was calculated on a non-inferiority margin of 9 mm, lower than the minimum perceptible clinical improvement. Secondary endpoints included OARSI-OMERACT responder rates Results The intention-to-treat (ITT) and per-protocol (PP) populations consisted of 217 and 209 patients and 171 and 172 patients in the GO-ON and Hyalgan groups, respectively. ITT WOMAC pain of 47.5±1.0(SE) and 48.8±1.0 mm decreased by 22.9±1.4 mm with GO-ON and 18.4±1.5 mm with Hyalgan after 6 months. The primary analysis was conducted in the PP population followed by the ITT population.Mean (95% CI) differences in WOMAC pain change were 5.2 (0.9 to 9.6)mm and 4.5 (0.5 to 8.5)mm, respectively,favouring GO-ON, satisfying the claim for non-inferiority (lower limit>−9 mm) and for statistical superiority (95% CI all>0, p=0.021). Ahigher proportion of OARSI/OMERACT responders was observed with GO-ONthan with Hyalgan (73.3% vs58.4%, p=0.001). Both preparations were well tolerated. Conclusions Treatment with 3-weekly injections of intermediate MW HA may be superior to low MW HA on knee OA symptoms over 6 months, with similar safety. PMID:22294639
WTS-4 system verification unit for wind/hydroelectric integration study
NASA Technical Reports Server (NTRS)
Watts, A. W.
1982-01-01
The Bureau of Reclamation (Reclamation) initiated a study to investigate the concept of integrating 100 MW of wind energy from megawatt-size wind turbines with the Federal hydroelectric system. As a part of the study, one large wind turbine was purchased through the competitive bid process and is now being installed to serve as a system verification unit (SVU). Reclamation negotiated an agreement with NASA to provide technical management of the project for the design, fabrication, installation, testing, and initial operation. Hamilton Standard was awarded a contract to furnish and install its WTS-4 wind turbine rated at 4 MW at a site near Medicine Bow, Wyoming. The purposes for installing the SVU are to fully evaluate the wind/hydro integration concept, make technical evaluation of the hardware design, train personnel in the technology, evaluate operation and maintenance aspects, and evaluate associated environmental impacts. The SVU will be operational in June 1982. Data from the WTS-4 and from a second SVU, Boeing's MOD-2, will be used to prepare a final design for a 100-MW farm if Congress authorizes the project.
Partial detachment of high power discharges in ASDEX Upgrade
NASA Astrophysics Data System (ADS)
Kallenbach, A.; Bernert, M.; Beurskens, M.; Casali, L.; Dunne, M.; Eich, T.; Giannone, L.; Herrmann, A.; Maraschek, M.; Potzel, S.; Reimold, F.; Rohde, V.; Schweinzer, J.; Viezzer, E.; Wischmeier, M.; the ASDEX Upgrade Team
2015-05-01
Detachment of high power discharges is obtained in ASDEX Upgrade by simultaneous feedback control of core radiation and divertor radiation or thermoelectric currents by the injection of radiating impurities. So far 2/3 of the ITER normalized heat flux Psep/R = 15 MW m-1 has been obtained in ASDEX Upgrade under partially detached conditions with a peak target heat flux well below 10 MW m-2. When the detachment is further pronounced towards lower peak heat flux at the target, substantial changes in edge localized mode (ELM) behaviour, density and radiation distribution occur. The time-averaged peak heat flux at both divertor targets can be reduced below 2 MW m-2, which offers an attractive DEMO divertor scenario with potential for simpler and cheaper technical solutions. Generally, pronounced detachment leads to a pedestal and core density rise by about 20-40%, moderate (<20%) confinement degradation and a reduction of ELM size. For AUG conditions, some operational challenges occur, like the density cut-off limit for X-2 electron cyclotron resonance heating, which is used for central tungsten control.
Bulk syntheses of silver (Ag) and iron (Fe) nanorods using poly (ethylene glycol), PEG, under microwave irradiation (MW) conditions are reported. Favorable conditions to make Ag nanorods were established and can be extended to make Fe nanorods with uniform size and shape. The nan...
The 2013 Mw 6.2 Khaki-Shonbe (Iran) Earthquake: Seismic Shortening of the Zagros Sedimentary Cover
NASA Astrophysics Data System (ADS)
Elliott, J. R.; Bergman, E.; Copley, A.; Ghods, A.; Nissen, E.; Oveisi, B.; Walters, R. J.
2014-12-01
The 2013 Mw 6.2 Khaki-Shonbe earthquake occurred in the Simply Folded Belt of the Zagros Mountains, Iran. This is the largest earthquake in the Zagros since the November 1990 Mw 6.4 Furg (Hormozgan) thrust faulting event, and therefore the largest in the period for which dense InSAR ground displacements are available. It is also the biggest seismic event to have occurred in the Simply Folded Belt since the March 1977 Mw 6.7 Khurgu earthquake. This earthquake therefore potentially provides valuable insights into a range of controversies: (1) the preponderance of earthquake faulting in the crystalline basement versus the sedimentary cover and the potential importance of lithology in controlling and limiting seismic rupture; (2) the nature of surface folding and whether or not there is a one-to-one relationship between buried reverse faults and surface anticlines; and (3) the presence or absence of large pulses of aseismic slip triggered by mainshock rupture. We combine seismological solutions and aftershock relocations with satellite interferometric ground displacements and observations from the field to determine the geometry of faulting and its relationship with the structure, stratigraphy and tectonics of the Central Zagros. The earthquake rupture involved reverse slip on two along-strike southwest dipping fault segments, the rupture initiating at the northern and bottom end of the larger north-west segment. These faults verge away from the foreland and towards the high range interior, contrary to the fault geometries depicted in many structural cross-sections of the Zagros. The slip measured on the reverse segments occurred over two mutually exclusive depth ranges, 10-5 km and 4-2 km, resulting in long (16 km), narrow (7 km) rupture segments. Conversely, aftershocks are found to cluster in the depth range 8-16 km, beneath the main rupture segment. This indicates only significant reverse slip and coseismic shortening in the sedimentary cover, with the slip distribution likely to be lithologically controlled in depth by the Hormuz salt at the base of the sedimentary cover, and the Kazhdumi Formation mudrocks at upper-levels (5 km), and aftershocks constrained largely beneath the main coseismic rupture planes.
Molecular Features of Wheat Endosperm Arabinoxylan Inclusion in Functional Bread
Li, Weili; Hu, Hui; Wang, Qi; Brennan, Charles J.
2013-01-01
Arabinoxylan (AX) is a major dietary fibre component found in a variety of cereals. Numerous health benefits of arabinoxylans have been reported to be associated with their solubility and molecular features. The current study reports the development of a functional bread using a combination of AX-enriched material (AEM) and optimal commercial endoxylanase. The total AX content of bread was increased to 8.2 g per 100 g available carbohydrates. The extractability of AX in breads with and without endoxylanase was determined. The results demonstrate that water-extractable AX (WE-AX) increased progressively through the bread making process. The application of endoxylanase also increased WE-AX content. The presence of 360 ppm of endoxylanase had positive effects on the bread characteristics in terms of bread volume and firmness by converting the water unextractable (WU)-AX to WE-AX. In addition, the molecular weight (Mw) distribution of the WE-AX of bread with and without endoxylanase was characterized by size-exclusion chromatography. The results show that as the portion of WE-AX increased, the amount of high Mw WE-AX (higher than 100 kDa) decreased, whereas the amount of low Mw WE-AX (lower than 100 kDa) increased from 33.2% to 44.2% through the baking process. The low Mw WE-AX further increased to 75.5% with the application of the optimal endoxylanase (360 ppm). PMID:28239111
Airborne megawatt class free-electron laser for defense and security
DOE Office of Scientific and Technical Information (OSTI.GOV)
Roy Whitney; David Douglas; George Neil
2005-03-01
An airborne megawatt (MW) average power Free-Electron Laser (FEL) is now a possibility. In the process of shrinking the FEL parameters to fit on ship, a surprisingly lightweight and compact design has been achieved. There are multiple motivations for using a FEL for a high-power airborne system for Defense and Security: Diverse mission requirements can be met by a single system. The MW of light can be made available with any time structure for time periods from microseconds to hours, i.e. there is a nearly unlimited magazine. The wavelength of the light can be chosen to be from the farmore » infrared (IR) to the near ultraviolet (UV) thereby best meeting mission requirements. The FEL light can be modulated for detecting the same pattern in the small fraction of light reflected from the target resulting in greatly enhanced targeting control. The entire MW class FEL including all of its subsystems can be carried by large commercial size airplanes or on an airship. Adequate electrical power can be generated on the plane or airship to run the FEL as long as the plane or airship has fuel to fly. The light from the FEL will work well with relay mirror systems. The required R&D to achieve the MW level is well understood. The coupling of the capabilities of an airborne FEL to diverse mission requirements provides unique opportunities.« less
NASA Astrophysics Data System (ADS)
Almeida, T. S.; Palma, L. M.; Leonello, P. H.; Morais, C.; Kokoh, K. B.; De Andrade, A. R.
2012-10-01
The aim of this work was to perform a systematic study of the parameters that can influence the composition, morphology, and catalytic activity of PtSn/C nanoparticles and compare two different methods of nanocatalyst preparation, namely microwave-assisted heating (MW) and thermal decomposition of polymeric precursors (DPP). An investigation of the effects of the reducing and stabilizing agents on the catalytic activity and morphology of Pt75Sn25/C catalysts prepared by microwave-assisted heating was undertaken for optimization purposes. The effect of short-chain alcohols such as ethanol, ethylene glycol, and propylene glycol as reducing agents was evaluated, and the use of sodium acetate and citric acid as stabilizing agents for the MW procedure was examined. Catalysts obtained from propylene glycol displayed higher catalytic activity compared with catalysts prepared in ethylene glycol. Introduction of sodium acetate enhanced the catalytic activity, but this beneficial effect was observed until a critical acetate concentration was reached. Optimization of the MW synthesis allowed for the preparation of highly dispersed catalysts with average sizes lying between 2.0 and 5.0 nm. Comparison of the best catalyst prepared by MW with a catalyst of similar composition prepared by the polymeric precursors method showed that the catalytic activity of the material can be improved when a proper condition for catalyst preparation is achieved.
Transscleral thermotherapy with laser-induced and conductive heating in hamster Greene melanoma.
Rem, Alex I; Oosterhuis, Jendo A; Keunen, Jan E E; Journée-De Korver, Hanneke G
2004-10-01
The purpose of this study was to investigate the cytotoxic effect of heat as induced by transscleral thermotherapy (TSTT), which may be of interest in the treatment of patients with choroidal melanoma. The aim of TSTT is to heat both the sclera and the tumor up to a cytotoxic temperature of about 60 degrees C. TSTT was performed in hamsters with subcutaneously implanted Greene melanoma covered by a specimen of human donor sclera of thickness 0.5, 0.7 or 0.9 mm. A newly developed applicator, which combines conductive episcleral heating at 60 degrees C with laser-induced heating, was used at laser powers ranging from 500 to 1500 mW delivered by an 810 nm diode laser, beam diameter 3 mm, and exposure time 1 min. Temperatures were measured at the scleral surface and at the sclera-tumor interface. The extent of tumor necrosis was examined by light microscopy and the sclera was examined by polarized light microscopy. Maximal depth of tumor necrosis without scleral damage was 4.4 (SD 1.5) mm. The temperature at the scleral surface after TSTT was 58.8 (SD 2.4) degrees C. The temperature at the sclera-tumor interface ranged from 56.4 (SD 3.7) degrees C at 500 mW to 65.3 (SD 4.4) degrees C at 1250 mW laser power. Structural changes to the scleral collagen started to develop at 1250 mW. TSTT with combined laser-induced and conductive heating caused cytotoxic temperatures in the tumor and the sclera, which were well tolerated by the scleral collagen.
Peyman, A; Khalid, M; Calderon, C; Addison, D; Mee, T; Maslanyj, M; Mann, S
2011-06-01
Laboratory measurements have been carried out with examples of Wi-Fi devices used in UK schools to evaluate the radiofrequency power densities around them and the total emitted powers. Unlike previous studies, a 20 MHz bandwidth signal analyzer was used, enabling the whole Wi-Fi signal to be captured and monitored. The radiation patterns of the laptops had certain similarities, including a minimum toward the torso of the user and two maxima symmetrically opposed across a vertical plane bisecting the screen and keyboard. The maxima would have resulted from separate antennas mounted behind the top left and right corners of the laptop screens. The patterns for access points were more symmetrical with generally higher power densities at a given distance. The spherically-integrated radiated power (IRP) ranged from 5 to 17 mW for 15 laptops in the 2.45 GHz band and from 1 to 16 mW for eight laptops in the 5 GHz band. For practical reasons and because access points are generally wall-mounted with beams directed into the rooms, their powers were integrated over a hemisphere. These ranged from 3 to 28 mW for 12 access points at 2.4 GHz and from 3 to 29 mW for six access points at 5 GHz. In addition to the spherical measurements of IRP, power densities were measured at distances of 0.5 m and greater from the devices, and consistent with the low radiated powers, these were all much lower than the ICNIRP reference level.
Pan, Pengju; Han, Lili; Bao, Jianna; Xie, Qing; Shan, Guorong; Bao, Yongzhong
2015-05-28
Competitive crystallization kinetics, polymorphic crystalline structure, and transition of poly(l-lactic acid)/poly(d-lactic acid) (PLLA/PDLA) racemic blends with a wide range of molecular weights (MWs) were symmetrically investigated. Stereocomplex (sc) crystallites are exclusively formed in the low-MW racemic blends. However, stereocomplexation is remarkably depressed, and homocrystallization becomes prevailing with increasing MWs of PLLA and PDLA. Suppressed stereocomplexation in high-MW (HMW) racemic blends is proposed to be due to the low chain diffusion ability and restricted intermolecular crystal nucleation/growth. Equilibrium melting point of sc crystallites first increases and then decreases as MW increases. Crystallinity and relative fraction of sc crystallites in racemic blends enhance with crystallization temperature (Tc), and the sc crystallites are merely formed at Tc > 170 °C because of their higher thermodynamic stability. In situ wide-angle X-ray diffraction (WAXD) analysis reveals that the stereocomplexation and homocrystallization are successive rather than completely simultaneous, and the stereocomplexation is preceding homocrystallization in isothermal crystallization of HMW racemic blends. Both initial crystalline structure of homocrystallites (hc) and MW influence the heating-induced hc-to-sc transition of HMW racemic blend drastically; the hc-to-sc transition becomes easier with decreasing Tc and MW. After crystallization at the same temperature, sc crystallites show smaller long period than their hc counterparts.
Capping of Aβ42 Oligomers by Small Molecule Inhibitors
2015-01-01
Aβ42 peptides associate into soluble oligomers and protofibrils in the process of forming the amyloid fibrils associated with Alzheimer’s disease. The oligomers have been reported to be more toxic to neurons than fibrils, and have been targeted by a wide range of small molecule and peptide inhibitors. With single touch atomic force microscopy (AFM), we show that monomeric Aβ42 forms two distinct types of oligomers, low molecular weight (MW) oligomers with heights of 1–2 nm and high MW oligomers with heights of 3–5 nm. In both cases, the oligomers are disc-shaped with diameters of ∼10–15 nm. The similar diameters suggest that the low MW species stack to form the high MW oligomers. The ability of Aβ42 inhibitors to interact with these oligomers is probed using atomic force microscopy and NMR spectroscopy. We show that curcumin and resveratrol bind to the N-terminus (residues 5–20) of Aβ42 monomers and cap the height of the oligomers that are formed at 1–2 nm. A second class of inhibitors, which includes sulindac sulfide and indomethacin, exhibit very weak interactions across the Aβ42 sequence and do not block the formation of the high MW oligomers. The correlation between N-terminal interactions and capping of the height of the Aβ oligomers provides insights into the mechanism of inhibition and the pathway of Aβ aggregation. PMID:25422864
NASA Astrophysics Data System (ADS)
Scholl, D. W.; Kirby, S. H.; Keranen, K. M.; Wells, R. E.; Blakely, R. J.; Michael, F.; von Huene, R.
2007-12-01
HABITATS OF GREAT OFFSHORE EARTHQUAKES: High-magnitude earthquakes (Mw = or >8.5) and trans- oceanic tsunamis commonly nucleate along subduction zones (SZ) bordered by laterally continuous, sediment- flooded trenches. Examples include: south-central Chile (1960 Mw=9.5), eastern Alaska (1964 Mw=9.2), Sumatra (2004, Mw=9.1), Cascadia (historic 1700 Mw=9.0), Colombia (1906 Mw=8.8), Sumatra (historic 1883, Mw=8.8), west-central Aleutian (1965 Mw=8.7), central Aleutian (1986, Mw=8.7), Sumatra (2005 Mw=8.6), and Nankai (historic 1707, Mw=8.5). In thickness, sediment entering these SZ ranges from 2 to 3 km and the column is axially continuous for more than 800 km. The depositional pile is typically the clastic beds of a trench-axis turbidite wedge and underlying fan and abyssal plain deposits that accrued seaward of the trench axis. Great rupture events also occur at subduction zones receiving little sediment, for example the Kamchatka (1952, Mw=9.0) and the north Chile SZs (historic 1868 Mw=8.9). Both SZs are areas of rapid upper plate thinning, subsidence, and truncation effected by subduction erosion. WORKINGS OF THE SUBDUCTION CHANNEL (SC): Beneath the submerged forearc, the SC functions to transport subducted ocean floor sediment and tectonically eroded forearc debris toward and into the mantle. The SC is the lowest structural unit containing upper plate crustal material. It hosts the seismogenic zone, which probably runs along the SC's upper boundary commonly referred to as the interplate decollement. A thick, laterally continuous SC structurally smoothes or simplifies the surface of the interplate decollement and sets up conditions for lengthy, high moment-release ruptures. Maximum slip is commonly concentrated beneath the thinned crust underlying forearc basins. These structures, in positive feed-back, are likely deepened co- seismically by high-slip-rate enhanced basal subduction erosion. The detached material lowers the effective stress on the decollement and further evens this interface. The channel also works tectonically to underplate the base of the inner margin and induce uplift and co-seismic activation of high-angle reverse faults. CONSEQUENCES OF WHAT IS FED SUBDUCTION ZONES: Ridges and high relief entering the SZ can act to arrest lateral rupturing. Supplying sedimentary and erosional debris to the subduction channel appears to act differently and favors the continuation of rupture, rapid slip beneath crustally thinned areas that can be translated upward at forearc splay faults to generate trans-oceanic tsunamis, and nearshore reverse-fault can spawn near- field tsunamis. The potential for great earthquake nucleation along thickly sediment SZs must be set high. Similarly, seismogenic risk for highly erosional SZ little perturbed by subducting relief must also be set high. Margins undergoing rapid tectonic erosion produce regional tsunamis but perhaps not trans-oceanic waves of great destructiveness.
Wieser, Herbert
2007-04-01
Gluten proteins play a key role in determining the unique baking quality of wheat by conferring water absorption capacity, cohesivity, viscosity and elasticity on dough. Gluten proteins can be divided into two main fractions according to their solubility in aqueous alcohols: the soluble gliadins and the insoluble glutenins. Both fractions consist of numerous, partially closely related protein components characterized by high glutamine and proline contents. Gliadins are mainly monomeric proteins with molecular weights (MWs) around 28,000-55,000 and can be classified according to their different primary structures into the alpha/beta-, gamma- and omega-type. Disulphide bonds are either absent or present as intrachain crosslinks. The glutenin fraction comprises aggregated proteins linked by interchain disulphide bonds; they have a varying size ranging from about 500,000 to more than 10 million. After reduction of disulphide bonds, the resulting glutenin subunits show a solubility in aqueous alcohols similar to gliadins. Based on primary structure, glutenin subunits have been divided into the high-molecular-weight (HMW) subunits (MW=67,000-88,000) and low-molecular-weight (LMW) subunits (MW=32,000-35,000). Each gluten protein type consists or two or three different structural domains; one of them contains unique repetitive sequences rich in glutamine and proline. Native glutenins are composed of a backbone formed by HMW subunit polymers and of LMW subunit polymers branched off from HMW subunits. Non-covalent bonds such as hydrogen bonds, ionic bonds and hydrophobic bonds are important for the aggregation of gliadins and glutenins and implicate structure and physical properties of dough.
NASA Technical Reports Server (NTRS)
Juhasz, Albert J.; Tew, Roy C.; Schwarze, Gene E.
1998-01-01
The effect of silicon carbide (SiC) electronics operating temperatures on Power Management and Distribution (PMAD), or Power Conditioning (PC), subsystem radiator size and mass requirements was evaluated for three power output levels (100 kW(e) , 1 MW(e), and 10 MW(e)) for near term technology ( i.e. 1500 K turbine inlet temperature) Closed Cycle Gas Turbine (CCGT) power systems with a High Temperature Gas Reactor (HTGR) heat source. The study was conducted for assumed PC radiator temperatures ranging from 370 to 845 K and for three scenarios of electrical energy to heat conversion levels which needed to be rejected to space by means of the PC radiator. In addition, during part of the study the radiation hardness of the PC electronics was varied at a fixed separation distance to estimate its effect on the mass of the instrument rated reactor shadow shield. With both the PC radiator and the conical shadow shield representing major components of the overall power system the influence of the above on total power system mass was also determined. As expected, results show that the greatest actual mass savings achieved by the use of SiC electronics occur with high capacity power systems. Moreover, raising the PC radiator temperature above 600 K yields only small additional system mass savings. The effect of increased radiation hardness on total system mass is to reduce system mass by virtue of lowering the shield mass.
Boiler house modernization through shared savings program
DOE Office of Scientific and Technical Information (OSTI.GOV)
Breault, R.W.
1995-12-31
Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question thatmore » arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.« less
Broadband Sources in the 1-3 THz Range
NASA Technical Reports Server (NTRS)
Mehdi, Imran; Ward, John; Maestrini, Alain; Chattopadhyay, Goutam; Schlecht, Erich; Thomas, Bertrand; Lin, Robert; Lee, Choonsup; Gill, John
2009-01-01
Broadband electronically tunable sources in the terahertz range are a critical technology for enabling space-borne as well as ground-based applications. By power-combining MMIC amplifier and frequency tripler chips, we have recently demonstrated >1 mW of output power at 900 GHz. This source provides a stepping stone to enable sources in the 2-3 THz range than can sufficiently pump multi-pixel imaging arrays.
Picot, Laurent; Ravallec, Rozenn; Fouchereau-Péron, Martine; Vandanjon, Laurent; Jaouen, Pascal; Chaplain-Derouiniot, Maryse; Guérard, Fabienne; Chabeaud, Aurélie; Legal, Yves; Alvarez, Oscar Martinez; Bergé, Jean-Pascal; Piot, Jean-Marie; Batista, Irineu; Pires, Carla; Thorkelsson, Gudjon; Delannoy, Charles; Jakobsen, Greta; Johansson, Inez; Bourseau, Patrick
2010-08-30
Numerous studies have demonstrated that in vitro controlled enzymatic hydrolysis of fish and shellfish proteins leads to bioactive peptides. Ultrafiltration (UF) and/or nanofiltration (NF) can be used to refine hydrolysates and also to fractionate them in order to obtain a peptide population enriched in selected sizes. This study was designed to highlight the impact of controlled UF and NF on the stability of biological activities of an industrial fish protein hydrolysate (FPH) and to understand whether fractionation could improve its content in bioactive peptides. The starting fish protein hydrolysate exhibited a balanced amino acid composition, a reproducible molecular weight (MW) profile, and a low sodium chloride content, allowing the study of its biological activity. Successive fractionation on UF and NF membranes allowed concentration of peptides of selected sizes, without, however, carrying out sharp separations, some MW classes being found in several fractions. Peptides containing Pro, Hyp, Asp and Glu were concentrated in the UF and NF retentates compared to the unfractionated hydrolysate and UF permeate, respectively. Gastrin/cholecystokinin-like peptides were present in the starting FPH, UF and NF fractions, but fractionation did not increase their concentration. In contrast, quantification of calcitonin gene-related peptide (CGRP)-like peptides demonstrated an increase in CGRP-like activities in the UF permeate, relative to the starting FPH. The starting hydrolysate also showed a potent antioxidant and radical scavenging activity, and a moderate angiotensin-converting enzyme (ACE)-1 inhibitory activity, which were not increased by UF and NF fractionation. Fractionation of an FPH using membrane separation, with a molecular weight cut-off adapted to the peptide composition, may provide an effective means to concentrate CGRP-like peptides and peptides enriched in selected amino acids. The peptide size distribution observed after UF and NF fractionation demonstrates that it is misleading to characterize the fractions obtained by membrane filtration according to the MW cut-off of the membrane only, as is currently done in the literature. Copyright (c) 2010 Society of Chemical Industry.
Personius, Stephen; Crone, Anthony J.; Burns, Patricia A.; Reitman, Nadine G.
2017-01-01
We conducted a trench investigation and analyzed pre‐ and postearthquake topography to determine the timing and size of prehistoric surface ruptures on the Susitna Glacier fault (SGF), the thrust fault that initiated the 2002 Mw 7.9 Denali fault earthquake sequence in central Alaska. In two of our three hand‐excavated trenches, we found clear evidence for a single pre‐2002 earthquake (penultimate earthquake [PE]) and determined an age of 2210±420 cal. B.P. (2σ) for this event. We used structure‐from‐motion software to create a pre‐2002‐earthquake digital surface model (DSM) from 1:62,800‐scale aerial photography taken in 1980 and compared this DSM with postearthquake 5‐m/pixel Interferometric Synthetic Aperature Radar topography taken in 2010. Topographic profiles measured from the pre‐earthquake DSM show features that we interpret as fault and fold scarps. These landforms were about the same size as those formed in 2002, so we infer that the PE was similar in size to the initial (Mw 7.2) subevent of the 2002 sequence. A recurrence interval of 2270 yrs and dip slip of ∼4.8 m yield a single‐interval slip rate of ∼1.8 mm/yr. The lack of evidence for pre‐PE deformation indicates probable episodic (clustering) behavior on the SGF that may be related to strain migration among other similarly oriented thrust faults that together accommodate shortening south of the Denali fault. We suspect that slip‐partitioned thrust‐triggered earthquakes may be a common occurrence on the Denali fault system, but documenting the frequency of such events will be very difficult, given the lack of long‐term paleoseismic records, the number of potential thrust‐earthquake sources, and the pervasive glacial erosion in the region.
On the evolution of the geothermal regime of the North China Basin
NASA Astrophysics Data System (ADS)
Wang, Ji-yang; Chen, Mo-xiang; Wang, Ji-an; Deng, Xiao
1985-12-01
Recent heat flow and regional geothermal studies indicate that the North China Basin is characterized by relatively high heat flow compared with most stable areas in other parts of the world, but lower heat flow than most active tectonic areas. Measured heat flow values range from 61 to 74 mW m -2. The temperature at a depth of 2000 m is generally in the range 75 to 85°C, but sometimes is 90°C or higher. The geothermal gradient in Cenozoic sediments is in the range 30 to 40°C/km for most of the area. The calculated temperature at the Moho is 560 and 640°C for surface heat flow values of 63 and 71 mW m -2, respectively. These thermal data are consistent with other geophysical observations for the North China Basin. Relatively high heat flow in this area is related to Late Cretaceous-Paleogene rifting as described in this paper.
The Space Motion of Leo I: The Mass of the Milky Way's Dark Matter Halo
NASA Astrophysics Data System (ADS)
Boylan-Kolchin, Michael; Bullock, James S.; Sohn, Sangmo Tony; Besla, Gurtina; van der Marel, Roeland P.
2013-05-01
We combine our Hubble Space Telescope measurement of the proper motion of the Leo I dwarf spheroidal galaxy (presented in a companion paper) with the highest resolution numerical simulations of Galaxy-size dark matter halos in existence to constrain the mass of the Milky Way's dark matter halo (M vir, MW). Despite Leo I's large Galactocentric space velocity (200 km s-1) and distance (261 kpc), we show that it is extremely unlikely to be unbound if Galactic satellites are associated with dark matter substructure, as 99.9% of subhalos in the simulations are bound to their host. The observed position and velocity of Leo I strongly disfavor a low-mass Milky Way: if we assume that Leo I is the least bound of the Milky Way's classical satellites, then we find that M vir, MW > 1012 M ⊙ at 95% confidence for a variety of Bayesian priors on M vir, MW. In lower mass halos, it is vanishingly rare to find subhalos at 261 kpc moving as fast as Leo I. Should an additional classical satellite be found to be less bound than Leo I, this lower limit on M vir, MW would increase by 30%. Imposing a mass-weighted ΛCDM prior, we find a median Milky Way virial mass of M vir, MW = 1.6 × 1012 M ⊙, with a 90% confidence interval of [1.0-2.4] × 1012 M ⊙. We also confirm a strong correlation between subhalo infall time and orbital energy in the simulations and show that proper motions can aid significantly in interpreting the infall times and orbital histories of satellites.
Kenya geothermal private power project: A prefeasibility study
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1992-10-01
Twenty-eight geothermal areas in Kenya were evaluated and prioritized for development. The prioritization was based on the potential size, resource temperature, level of exploration risk, location, and exploration/development costs for each geothermal area. Suswa, Eburru and Arus are found to offer the best short-term prospects for successful private power development. It was found that cost per kill developed are significantly lower for the larger (50MW) than for smaller-sized (10 or 20 NW) projects. In addition to plant size, the cost per kill developed is seen to be a function of resource temperature, generation mode (binary or flash cycle) and transmissionmore » distance.« less
Fatigue response of perforated titanium for application in laminar flow control
NASA Technical Reports Server (NTRS)
Johnson, W. Steven; Miller, Jennifer L.; Newman, Jr., James
1996-01-01
The room temperature tensile and fatigue response of non-perforated and perforated titanium for laminar flow control application was investigated both experimentally and analytically. Results showed that multiple perforations did not affect the tensile response, but did reduce the fatigue life. A two dimensional finite element stress analysis was used to determine that the stress fields from adjacent perforations did not influence one another. The stress fields around the holes did not overlap one another, allowing the materials to be modeled as a plate with a center hole. Fatigue life was predicted using an equivalent MW flow size approach to relate the experimental results to microstructural features of the titanium. Predictions using flaw sizes ranging from 1 to 15 microns correlated within a factor of 2 with the experimental results by using a flow stress of 260 MPa. By using two different flow stresses in the crack closure model and correcting for plasticity, the experimental results were bounded by the predictions for high applied stresses. Further analysis of the complex geometry of the perforations and the local material chemistry is needed to further understand the fatigue behavior of the perforated titanium.
Yan, Wei-qiang; Zhang, Min; Huang, Lue-lue; Tang, Juming; Mujumdar, Arun S; Sun, Jin-cai
2010-06-01
In commercial deep-fat frying of potato chips, the oil content of the final products ranges from 35 to 45 g 100 g(-1) (wet basis). High-temperature frying may cause the formation of acrylamide, making the products unhealthy to the consumer. The aim of this research was to explore a new method, spouted bed microwave drying, to produce healthier puffed snack potato cubes as possible alternatives to oil-fried potato chips. The influence of drying conditions of the spouted bed microwave drying on puffing characteristics of potato cubes were studied and compared with the direct microwave and hot air drying method. Tandem combination drying of microwave-enhanced spouted bed drying (MWSB) could achieve a good expansion ratio, breaking force and rehydration ratio. The puffing characteristics of potato cubes were significantly affected (P < 0.05) by moisture content before starting microwave power in spouted bed microwave drying, by microwave (MW) power, and by the original size of potato cubes. The optimum processing parameters were the moisture content at the start of microwave power (60%), the size of potato cubes (10-12 mm), and microwave power (2-2.5 W g(-1)) Copyright (c) 2010 Society of Chemical Industry.
NASA Technical Reports Server (NTRS)
1976-01-01
A long-lived space-based system that converts on-orbit solar and/or nuclear energy to a suitable form for distribution to using space systems is described. Mission applications, requirements, issues, problems, benefits, and technology thrusts are identified for the multipurpose power platform. Power levels of at least 10-100Kw are required for space manufacturing, satellites, and space station operations. Two Mw are needed for a proposed passive radar system. Propulsion system requirements are in the 100Kw-100Mw range.
NASA Astrophysics Data System (ADS)
Imakubo, Keiichi
1994-10-01
Ar ion laser-induced photoacoustic spectroscopy has been performed on 0.01 mu M flavin adenine dinucleotide in H2O and 0.01 mu M beta-carotene in n-hexane where the optical absorption spectroscopy is not applicable. On the basis of the linear relationships between laser powers and photoacoustic signal intensities up to 500 mW, it may be concluded that laser power ranging from 10 to 50 mW is required for the successful observation of photoacoustic signals without any photochemical or photobiological effects.
ICRH system performance during ITER-Like Wall operations at JET and the outlook for DT campaign
NASA Astrophysics Data System (ADS)
Monakhov, Igor; Blackman, Trevor; Dumortier, Pierre; Durodié, Frederic; Jacquet, Philippe; Lerche, Ernesto; Noble, Craig
2017-10-01
Performance of JET ICRH system since installation of the metal ITER-Like Wall (ILW) has been assessed statistically. The data demonstrate steady increase of the RF power coupled to plasmas over recent years with the maximum pulse-average and peak values exceeding respectively 6MW and 8MW in 2016. Analysis and extrapolation of power capabilities of conventional JET ICRH antennas is provided and key performance-limiting factors are discussed. The RF plant operational frequency options are presented highlighting the issues of efficient ICRH application within a foreseeable range of DT plasma scenarios.
NASA Astrophysics Data System (ADS)
Brett, Gareth; Barnett, Matthew
2014-12-01
Liquid Air Energy Storage (LAES) provides large scale, long duration energy storage at the point of demand in the 5 MW/20 MWh to 100 MW/1,000 MWh range. LAES combines mature components from the industrial gas and electricity industries assembled in a novel process and is one of the few storage technologies that can be delivered at large scale, with no geographical constraints. The system uses no exotic materials or scarce resources and all major components have a proven lifetime of 25+ years. The system can also integrate low grade waste heat to increase power output. Founded in 2005, Highview Power Storage, is a UK based developer of LAES. The company has taken the concept from academic analysis, through laboratory testing, and in 2011 commissioned the world's first fully integrated system at pilot plant scale (300 kW/2.5 MWh) hosted at SSE's (Scottish & Southern Energy) 80 MW Biomass Plant in Greater London which was partly funded by a Department of Energy and Climate Change (DECC) grant. Highview is now working with commercial customers to deploy multi MW commercial reference plants in the UK and abroad.
Isolation of a thermophilic bacterium capable of low-molecular-weight polyethylene degradation.
Jeon, Hyun Jeong; Kim, Mal Nam
2013-02-01
A thermophilic bacterium capable of low-molecular-weight polyethylene (LMWPE) degradation was isolated from a compost sample, and was identified as Chelatococcus sp. E1, through sequencing of the 16S rRNA gene. LMWPE was prepared by thermal degradation of commercial PE in a strict nitrogen atmosphere. LMWPE with a weight-average-molecular-weight (Mw) in the range of 1,700-23,700 was noticeably mineralized into CO(2) by the bacterium. The biodegradability of LMWPE decreased as the Mw increased. The low molecular weight fraction of LMWPE decreased significantly as a result of the degradation process, and thereby both the number-average-molecular-weight and Mw increased after biodegradation. The polydispersity of LMWPE was either narrowed or widened, depending on the initial Mw of LMWPE, due to the preferential elimination of the low molecular weight fraction, in comparison to the high molecular weight portion. LMWPE free from an extremely low molecular weight fraction was also mineralized by the strain at a remarkable rate, and FTIR peaks assignable to C-O stretching appeared as a result of microbial action. The FTIR peaks corresponding to alkenes also became more intense, indicating that dehydrogenations occurred concomitantly with microbial induced oxidation.
Characterization of gold kiwifruit pectin from fruit of different maturities and extraction methods.
Yuliarti, Oni; Matia-Merino, Lara; Goh, Kelvin K T; Mawson, John; Williams, Martin A K; Brennan, Charles
2015-01-01
Studies on gold kiwifruit pectins are limited. In this work, the characterization of pectin isolated from two different stages of maturity of gold kiwifruit, namely early harvested fruit (EHF) and main harvested fruit (MHF) isolated by three methods (acid, water, enzymatic) was carried out. Pectins isolated from MHF were higher in galacturonic acid content (52-59% w/w) and weight-average molecular weights (Mw, 1.7-3.8 × 10(6)g/mol) compared with EHF pectins (29-49% w/w and 0.2-1.7 × 10(6)g/mol respectively). Enzymatic treatment gave the highest yield but lowest in Mw, viscosity and mechanical spectra for both maturities. The pectin of both maturities was classified as high-methoxyl pectin with the degree of esterification ranged from 82% to 90%. Water-extracted MHF pectin molecules had the highest RMS radius (182.7 nm) and Mw (3.75 × 10(6)g/mol). The water extraction method appeared to retain the native state of pectin molecules compared with acid and enzymatic extraction methods based on the Mw and viscosity data. Copyright © 2014 Elsevier Ltd. All rights reserved.
Flow reversal power limit for the HFBR
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cheng, L.Y.; Tichler, P.R.
The High Flux Beam Reactor (HFBR) is a pressurized heavy water moderated and cooled research reactor that began operation at 40 MW. The reactor was subsequently upgraded to 60 MW and operated at that level for several years. The reactor undergoes a buoyancy-driven reversal of flow in the reactor core following certain postulated accidents. Questions which were raised about the afterheat removal capability during the flow reversal transition led to a reactor shutdown and subsequent resumption of operation at a reduced power of 30 MW. An experimental and analytical program to address these questions is described in this report. Themore » experiments were single channel flow reversal tests under a range of conditions. The analytical phase involved simulations of the tests to benchmark the physical models and development of a criterion for dryout. The criterion is then used in simulations of reactor accidents to determine a safe operating power level. It is concluded that the limit on the HFBR operating power with respect to the issue of flow reversal is in excess of 60 MW. Direct use of the experimental results and an understanding of the governing phenomenology supports this conclusion.« less
On the physical nature of globular cluster candidates in the Milky Way bulge
NASA Astrophysics Data System (ADS)
Piatti, Andrés E.
2018-06-01
We present results from 2MASS JKs photometry on the physical reality of recently reported globular cluster (GC) candidates in the Milky Way (MW) bulge. We relied our analysis on photometric membership probabilities that allowed us to distinguish real stellar aggregates from the composite field star population. When building colour-magnitude diagrams and stellar density maps for stars at different membership probability levels, the genuine GC candidate populations are clearly highlighted. We then used the tip of the red giant branch (RGB) as distance estimator, resulting in heliocentric distances that place many of the objects in regions near the MW bulge, where no GC had been previously recognized. Some few GC candidates resulted to be MW halo/disc objects. Metallicities estimated from the standard RGB method are in agreement with the values expected according to the position of the GC candidates in the Galaxy. Finally, we derived, for the first time, their structural parameters. We found that the studied objects have core, half-light, and tidal radii in the ranges spanned by the population of known MW GCs. Their internal dynamical evolutionary stages will be described properly when their masses are estimated.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tavoulareas, E.S.; Hardman, R.; Eskinazi, D.
This report provides the key findings of the Innovative Clean Coal Technology (ICCT) demonstration project at Gulf Power`s Lansing Smith Unit No. 2 and the implications for other tangentially-fired boilers. L. Smith Unit No. 2 is a 180 MW tangentially-fired boiler burning Eastern Bituminous coal, which was retrofitted with Asea Brown Boveri/Combustion Engineering Services` (ABB/CE) LNCFS I, II, and III technologies. An extensive test program was carried-out with US Department of Energy, Southern Company and Electric Power Research Institute (EPRI) funding. The LNCFS I, II, and III achieved 37 percent, 37 percent, and 45 percent average long-term NO{sub x} emissionmore » reduction at full load, respectively (see following table). Similar NO{sub x} reduction was achieved within the control range (100--200 MW). However, below the control point (100 MW), NO{sub x} emissions with the LNCFS technologies increased significantly, reaching pre-retrofit levels at 70 MW. Short-term testing proved that low load NO{sub x} emissions could be reduced further by using lower excess O{sub 2} and burner tilt, but with adversed impacts on unit performance, such as lower steam outlet temperatures and, potentially, higher CO emissions and LOI.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gómez, Facundo A.; O’Shea, Brian W.; Besla, Gurtina
2015-04-01
Motivated by recent studies suggesting that the Large Magellanic Cloud (LMC) could be significantly more massive than previously thought, we explore whether the approximation of an inertial Galactocentric reference frame is still valid in the presence of such a massive LMC. We find that previous estimates of the LMC’s orbital period and apocentric distance derived assuming a fixed Milky Way (MW) are significantly shortened for models where the MW is allowed to move freely in response to the gravitational pull of the LMC. Holding other parameters fixed, the fraction of models favoring first infall is reduced. Due to this interaction,more » the MW center of mass within the inner 50 kpc can be significantly displaced in phase-space in a very short period of time that ranges from 0.3 to 0.5 Gyr by as much as 30 kpc and 75 km s{sup −1}. Furthermore, we show that the gravitational pull of the LMC and response of the MW are likely to significantly affect the orbit and phase space distribution of tidal debris from the Sagittarius dwarf galaxy (Sgr). Such effects are larger than previous estimates based on the torque of the LMC alone. As a result, Sgr deposits debris in regions of the sky that are not aligned with the present-day Sgr orbital plane. In addition, we find that properly accounting for the movement of the MW around its common center of mass with the LMC significantly modifies the angular distance between apocenters and tilts its orbital pole, alleviating tensions between previous models and observations. While these models are preliminary in nature, they highlight the central importance of accounting for the mutual gravitational interaction between the MW and LMC when modeling the kinematics of objects in the MW and Local Group.« less
Shahriari, Haleh; Warith, Mostafa; Hamoda, Mohamed; Kennedy, Kevin J
2012-01-01
In order to enhance anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW), pretreatment combining two modalities, microwave (MW) heating in presence or absence of hydrogen peroxide (H(2)O(2)) were investigated. The main pretreatment variables affecting the characteristics of the OFMSW were temperature (T) via MW irradiation and supplemental water additions of 20% and 30% (SWA20 and SW30). Subsequently, the focus of this study was to evaluate mesophilic batch AD performance in terms of biogas production, as well as changes in the characteristics of the OFMSW post digestion. A high MW induced temperature range (115-175°C) was applied, using sealed vessels and a bench scale MW unit equipped with temperature and pressure controls. Biochemical methane potential (BMP) tests were conducted on the whole OFMSW as well as the liquid fractions. The whole OFMSW pretreated at 115°C and 145°C showed 4-7% improvement in biogas production over untreated OFMSW (control). When pretreated at 175°C, biogas production decreased due to formation of refractory compounds, inhibiting the digestion. For the liquid fraction of OFMSW, the effect of pretreatment on the cumulative biogas production (CBP) was more pronounced for SWA20 at 145°C, with a 26% increase in biogas production after 8days of digestion, compared to the control. When considering the increased substrate availability in the liquid fraction after MW pretreatment, a 78% improvement in biogas production vs. the control was achieved. Combining MW and H(2)O(2) modalities did not have a positive impact on OFMSW stabilization and enhanced biogas production. In general, all samples pretreated with H(2)O(2) displayed a long lag phase and the CBP was usually lower than MW irradiated only samples. First order rate constant was calculated. Copyright © 2011 Elsevier Ltd. All rights reserved.
Health implications of exposure to radiofrequency/microwave energies
Michaelson, S M
1982-01-01
ABSTRACT The rapid development of and the increase in the number and variety of devices that emit microwave/radiofrequency (MW/RF) energies has resulted in a growing interest regarding the potential effects on health of these energies. The frequency ranges considered in this review are: 300 kHz to 300 MHz (radiofrequency) and 300 MHz to 300 GHz (microwaves). Investigations have shown that exposure to certain power densities for several minutes or hours can result in pathophysiological manifestations in laboratory animals. Such effects may or may not be characterised by a measurable rise in temperature, which is a function of thermal regulatory processes and active adaptation by the animal. The end result is either a reversible or irreversible change, depending on the irradiation conditions and the physiological state of the animal. At lower power densities, evidence of pathological changes or physiological alteration is non-existent or equivocal. Much discussion, nevertheless, has taken place on the relative importance of thermal or non-thermal effects of radiofrequency and microwave radiation. Several retrospective studies have been done on human populations exposed or believed to have been exposed to MW/RF energies. Those performed in the US have not shown any relationship of altered morbidity or mortality to MW/RF exposure. Reactions referrable to the central nervous system and cardiovascular effects from exposure of man to microwave energy have been reported mostly in Eastern European publications. Individuals suffering from various ailments or psychological factors may exhibit the same dysfunctions of the central nervous and cardiovascular systems as those reported to result from exposure to MW/RF; thus it is extremely difficult, if not impossible, to rule out other factors in attempting to relate MW/RF exposure to clinical conditions. There is a need to set limits on the amount of exposure to MW/RF energies that individuals can accept with safety. Operative protection standards have apparently provided adequate safety to workers and the general population to permit the use of MW/RF energies without harm or detriment. PMID:7039662
Variations and controls on crustal thermal regimes in Southeastern Australia
NASA Astrophysics Data System (ADS)
Mather, Ben; McLaren, Sandra; Taylor, David; Roy, Sukanta; Moresi, Louis
2018-01-01
The surface heat flow field in Australia has for many years been poorly constrained compared to continental regions elsewhere. 182 recent heat flow determinations and 66 new heat production measurements for Southeastern Australia significantly increase our understanding of local and regional lithospheric thermal regimes and allow for detailed thermal modelling. The new data give a mean surface heat flow for Victoria of 71 ± 15 mW m- 2 which fits within the 61-77 mW m- 2 range reported for Phanerozoic-aged crust globally. These data reveal three new thermally and compositionally distinct heat flow sub-provinces within the previously defined Eastern Heat Flow Province: the Delamerian heat flow sub-province (average surface heat flow 60 ± 9 mW m- 2); the Lachlan heat flow sub-province (average surface heat flow 74 ± 13 mW m- 2); and the Newer Volcanics heat flow sub-province (average surface heat flow 72 ± 16 mW m- 2) which includes extreme values that locally exceed 100 mW m- 2. Inversions of reduced heat flow and crustal differentiation find that the Delamerian sub-province has experienced significant crustal reworking compared to the Lachlan and Newer Volcanics sub-provinces. The latter has experienced volcanism within the last 8 Ma and the degree of variability observed in surface heat flow points (up to 8 mW m- 2 per kilometre laterally) cannot be replicated with steady-state thermal models through this sub-province. In the absence of a strong palaeoclimate signal, aquifer disturbances, or highly enriched granites, we suggest that this high variability arises from localised transient perturbations to the upper crust associated with recent intraplate volcanism. This is supported by a strong spatial correlation of high surface heat flow and known eruption points within the Newer Volcanics heat flow sub-province.
NASA Astrophysics Data System (ADS)
Munafo, I.; Malagnini, L.; Chiaraluce, L.; Valoroso, L.
2015-12-01
The relation between moment magnitude (MW) and local magnitude (ML) is still a debated issue (Bath, 1966, 1981; Ristau et al., 2003, 2005). Theoretical considerations and empirical observations show that, in the magnitude range between 3 and 5, MW and ML scale 1∶1. Whilst for smaller magnitudes this 1∶1 scaling breaks down (Bethmann et al. 2011). For accomplishing this task we analyzed the source parameters of about 1500 (30.000 waveforms) well-located small earthquakes occurred in the Upper Tiber Valley (Northern Apennines) in the range of -1.5≤ML≤3.8. In between these earthquakes there are 300 events repeatedly rupturing the same fault patch generally twice within a short time interval (less than 24 hours; Chiaraluce et al., 2007). We use high-resolution short period and broadband recordings acquired between 2010 and 2014 by 50 permanent seismic stations deployed to monitor the activity of a regional low angle normal fault (named Alto Tiberina fault, ATF) in the framework of The Alto Tiberina Near Fault Observatory project (TABOO; Chiaraluce et al., 2014). For this study the direct determination of MW for small earthquakes is essential but unfortunately the computation of MW for small earthquakes (MW < 3) is not a routine procedure in seismology. We apply the contributions of source, site, and crustal attenuation computed for this area in order to obtain precise spectral corrections to be used in the calculation of small earthquakes spectral plateaus. The aim of this analysis is to achieve moment magnitudes of small events through a procedure that uses our previously calibrated crustal attenuation parameters (geometrical spreading g(r), quality factor Q(f), and the residual parameter k) to correct for path effects. We determine the MW-ML relationships in two selected fault zones (on-fault and fault-hanging-wall) of the ATF by an orthogonal regression analysis providing a semi-automatic and robust procedure for moment magnitude determination within a region characterized by small to moderate seismicity. Finally, we present for a subset of data, corner frequency values computed by spectral analysis of S-waves, using data from three nearby shallow borehole stations sampled at 500 sps.
Effect of gold nanoparticle size and coating on labeling monocytes for CT tracking
Chhour, Peter; Kim, Johoon; Benardo, Barbara; Tovar, Alfredo; Mian, Shaameen; Litt, Harold I.; Ferrari, Victor A.; Cormode, David P.
2017-01-01
With advances in cell therapies, interest in cell tracking techniques to monitor the migration, localization and viability of these cells continues to grow. X-ray computed tomography (CT) is a cornerstone of medical imaging but has been limited in cell tracking applications due to its low sensitivity towards contrast media. In this study, we investigate the role of size and surface functionality of gold nanoparticles for monocyte uptake to optimize the labeling of these cells for tracking in CT. We synthesized gold nanoparticles (AuNP) that range from 15 to 150 nm in diameter and examined several capping ligands, generating 44 distinct AuNP formulations. In vitro cytotoxicity and uptake experiments were performed with the RAW 264.7 monocyte cell line. The majority of formulations at each size were found to be biocompatible, with only certain 150 nm PEG functionalized particles reducing viability at high concentrations. High uptake of AuNP was found using small capping ligands with distal carboxylic acids (11-MUA and 16-MHA). Similar uptake values were found with intermediate sizes (50 and 75 nm) of AuNP when coated with 2000 MW poly(ethylene-glycol) carboxylic acid ligands (PCOOH). Low uptake values were observed with 15, 25, 100, and 150 nm PCOOH AuNP, revealing interplay between size and surface functionality. TEM and CT performed on cells revealed similar patterns of high gold uptake for 50 nm PCOOH and 75 nm PCOOH AuNP. These results demonstrate that highly negatively charged carboxylic acid coatings for AuNP provide the greatest internalization of AuNP in monocytes, with a complex dependency on size. PMID:28095688
NASA Astrophysics Data System (ADS)
Gomez-Gonzalez, J. M.; Mellors, R.
2007-05-01
We investigate the kinematics of the rupture process for the September 27, 2003, Mw7.3, Altai earthquake and its associated large aftershocks. This is the largest earthquake striking the Altai mountains within the last 50 years, which provides important constraints on the ongoing tectonics. The fault plane solution obtained by teleseismic body waveform modeling indicated a predominantly strike-slip event (strike=130, dip=75, rake 170), Scalar moment for the main shock ranges from 0.688 to 1.196E+20 N m, a source duration of about 20 to 42 s, and an average centroid depth of 10 km. Source duration would indicate a fault length of about 130 - 270 km. The main shock was followed closely by two aftershocks (Mw5.7, Mw6.4) occurred the same day, another aftershock (Mw6.7) occurred on 1 October , 2003. We also modeled the second aftershock (Mw6.4) to asses geometric similarities during their respective rupture process. This aftershock occurred spatially very close to the mainshock and possesses a similar fault plane solution (strike=128, dip=71, rake=154), and centroid depth (13 km). Several local conditions, such as the crustal model and fault geometry, affect the correct estimation of some source parameters. We perfume a sensitivity evaluation of several parameters, including centroid depth, scalar moment and source duration, based on a point and finite source modeling. The point source approximation results are the departure parameters for the finite source exploration. We evaluate the different reported parameters to discard poor constrained models. In addition, deformation data acquired by InSAR are also included in the analysis.
Low stress drops observed for aftershocks of the 2011 Mw 5.7 Prague, Oklahoma, earthquake
NASA Astrophysics Data System (ADS)
Sumy, Danielle F.; Neighbors, Corrie J.; Cochran, Elizabeth S.; Keranen, Katie M.
2017-05-01
In November 2011, three Mw ≥ 4.8 earthquakes and thousands of aftershocks occurred along the structurally complex Wilzetta fault system near Prague, Oklahoma. Previous studies suggest that wastewater injection induced a Mw 4.8 foreshock, which subsequently triggered a Mw 5.7 mainshock. We examine source properties of aftershocks with a standard Brune-type spectral model and jointly solve for seismic moment (M0), corner frequency (f0), and kappa (κ) with an iterative Gauss-Newton global downhill optimization method. We examine 934 earthquakes with initial moment magnitudes (Mw) between 0.33 and 4.99 based on the pseudospectral acceleration and recover reasonable M0, f0, and κ for 87 earthquakes with Mw 1.83-3.51 determined by spectral fit. We use M0 and f0 to estimate the Brune-type stress drop, assuming a circular fault and shear-wave velocity at the hypocentral depth of the event. Our observations suggest that stress drops range between 0.005 and 4.8 MPa with a median of 0.2 MPa (0.03-26.4 MPa with a median of 1.1 MPa for Madariaga-type), which is significantly lower than typical eastern United States intraplate events (>10 MPa). We find that stress drops correlate weakly with hypocentral depth and magnitude. Additionally, we find the stress drops increase with time after the mainshock, although temporal variation in stress drop is difficult to separate from spatial heterogeneity and changing event locations. The overall low median stress drop suggests that the fault segments may have been primed to fail as a result of high pore fluid pressures, likely related to nearby wastewater injection.
NASA Astrophysics Data System (ADS)
Kuroda, N.; Gary, D. E.; Wang, H.; Fleishman, G. D.; Nita, G. M.; Jing, J.
2017-12-01
The well-established notion of a "common population" of the accelerated electrons simultaneously producing the hard X-ray (HXR) and the microwave (MW) emission during the flare impulsive phase has been challenged by some studies reporting the discrepancies between the HXR-inferred and the MW-inferred electron energy spectra. The traditional methods of their spectral inversion have some problems that can be mainly attributed to the unrealistic and the oversimplified treatment of the flare emission. To properly address this problem, we use a Non-linear Force Free Field (NLFFF) model extrapolated from an observed photospheric magnetogram as input to the threedimensional, multi-wavelength modeling platform GX Simulator, and create a unified electron population model that can simultaneously reproduce the observed HXR and MW observations. We model the end of the impulsive phase of the 2015-06-22 M6.5 flare, and constrain the modeled electron spatial and energy parameters using observations made by the highest-resolving instruments currently available in two wavelengths, the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) for HXR and the Expanded Owens Valley Solar Array (EOVSA) for MW. Our results suggest that the HXR-emitting electron population model fits the standard flare model with a broken power-law spectrum that simultaneously produces the HXR footpoint emission and the MW high frequency emission. The model also includes an "HXR invisible" population of nonthermal electrons that are trapped in a large volume of magnetic field above the HXR-emitting loops, which is observable by its gyrosynchrotron (GS) radiation emitting mainly in MW low frequency range.
NASA Astrophysics Data System (ADS)
Kuroda, Natsuha; Gary, Dale E.; Wang, Haimin; Fleishman, Gregory D.; Nita, Gelu M.; Jing, Ju
2018-01-01
The well-established notion of a “common population” of the accelerated electrons simultaneously producing the hard X-ray (HXR) and microwave (MW) emission during the flare impulsive phase has been challenged by some studies reporting the discrepancies between the HXR-inferred and MW-inferred electron energy spectra. The traditional methods of spectral inversion have some problems that can be mainly attributed to the unrealistic and oversimplified treatment of the flare emission. To properly address this problem, we use a nonlinear force-free field (NLFFF) model extrapolated from an observed photospheric magnetogram as input to the three-dimensional, multiwavelength modeling platform GX Simulator and create a unified electron population model that can simultaneously reproduce the observed HXR and MW observations. We model the end of the impulsive phase of the 2015 June 22 M6.5 flare and constrain the modeled electron spatial and energy parameters using observations made by the highest-resolving instruments currently available in two wavelengths, the Reuven Ramaty High Energy Solar Spectroscopic Imager for HXR and the Expanded Owens Valley Solar Array for MW. Our results suggest that the HXR-emitting electron population model fits the standard flare model with a broken power-law spectrum ({E}{break}∼ 200 keV) that simultaneously produces the HXR footpoint emission and the MW high-frequency emission. The model also includes an “HXR-invisible” population of nonthermal electrons that are trapped in a large volume of magnetic field above the HXR-emitting loops, which is observable by its gyrosynchrotron radiation emitting mainly in the MW low-frequency range.
2013-01-01
A gold nanoparticle (AuNP)-based colorimetric method was developed for the molecular weight (MW) determination of polyethylene glycol (PEG), a commonly used hydrophilic polymer. Addition of a salt solution to PEG-coated AuNP solutions helps in screening the electrostatic repulsion between nanoparticles and generating a color change of the solutions from wine red to blue in 10 min in accordance with the MW of PEG, which illustrates the different stability degrees (SDs) of the AuNPs. The SDs are calculated by the absorbance ratios of the stable to the aggregated AuNPs in the solution. The root mean square end-to-end length (〈h2〉1/2) of PEG molecules shows a linear fit to the SDs of the PEG-coated AuNPs in a range of 1.938 ± 0.156 to 10.151 ± 0.176 nm. According to the Derjaguin-Landau-Verwey-Overbeek theory, the reason for this linear relationship is that the thickness of the PEG adlayer is roughly equivalent to the 〈h2〉1/2 of the PEG molecules in solution, which determines the SDs of the AuNPs. Subsequently, the MW of the PEG can be obtained from its 〈h2〉1/2 using a mathematical relationship between 〈h2〉1/2 and MW of PEG molecule. Applying this approach, we determined the 〈h2〉1/2 and the MW of four PEG samples according to their absorbance values from the ordinary ultraviolet–visible spectrophotometric measurements. Therefore, the MW of PEG can be distinguished straightforwardly by visual inspection and determined by spectrophotometry. This novel approach is simple, rapid, and sensitive. PMID:24359120
The 2017 Maple Creek Seismic Swarm in Yellowstone National Park
NASA Astrophysics Data System (ADS)
Pang, G.; Hale, J. M.; Farrell, J.; Burlacu, R.; Koper, K. D.; Smith, R. B.
2017-12-01
The University of Utah Seismograph Stations (UUSS) performs near-real-time monitoring of seismicity in the region around Yellowstone National Park in partnership with the United States Geological Survey and the National Park Service. UUSS operates and maintains 29 seismic stations with network code WY (short-period, strong-motion, and broadband) and records data from five other seismic networks—IW, MB, PB, TA, and US—to enhance the location capabilities in the Yellowstone region. A seismic catalog is produced using a conventional STA/LTA detector and single-event location techniques (Hypoinverse). On June 12, 2017, a seismic swarm began in Yellowstone National Park about 5 km east of Hebgen Lake. The swarm is adjacent to the source region of the 1959 MW 7.3 Hebgen Lake earthquake, in an area corresponding to positive Coulumb stress change from that event. As of Aug. 1, 2017, the swarm consists of 1481 earthquakes with 1 earthquake above magnitude 4, 8 earthquakes in the magnitude 3 range, 115 earthquakes in the magnitude 2 range, 469 earthquakes in the magnitude 1 range, 856 earthquakes in the magnitude 0 range, 22 earthquakes with negative magnitudes, and 10 earthquakes with no magnitude. Earthquake depths are mostly between 3 and 10 km and earthquake depth increases toward the northwest. Moment tensors for the 2 largest events (3.6 MW and 4.4. MW) show strike-slip faulting with T axes oriented NE-SW, consistent with the regional stress field. We are currently using waveform cross-correlation methods to measure differential travel times that are being used with the GrowClust program to generate high-accuracy relative relocations. Those locations will be used to identify structures in the seismicity and make inferences about the tectonic and magmatic processes causing the swarm.
A compact frequency stabilized telecom laser diode for space applications
NASA Astrophysics Data System (ADS)
Philippe, C.; Holleville, D.; Le Targat, R.; Wolf, P.; Leveque, T.; Le Goff, R.; Martaud, E.; Acef, O.
2017-09-01
We report on a Telecom laser diode (LD) frequency stabilization to a narrow iodine hyperfine line in the green range, after frequency tripling process using fibered nonlinear waveguide PPLN crystals. We have generated up to 300 mW optical power in the green range ( 514 nm) from 800 mW of infrared power ( 1542 nm), corresponding to a nonlinear conversion efficiency h = P3?/P? 36%. Less than 10 mW of the generated green power are used for Doppler-free spectroscopy of 127I2 molecular iodine, and -therefore- for the frequency stabilization purpose. The frequency tripling optical setup is very compact (< 5 l), fully fibered, and could operate over the full C-band of the Telecom range (1530 nm - 1565 nm). Several thousands of hyperfine iodine lines may thus be interrogated in the 510 nm - 521 nm range. We build up an optical bench used at first in free space configuration, using the well-known modulation transfer spectroscopy technique (MTS), in order to test the potential of this new frequency standard based on the couple "1.5 ?m laser / iodine molecule". We have already demonstrated a preliminary frequency stability of 4.8 x 10-14 ? -1/2 with a minimum value of 6 x 10-15 reached after 50 s of integration time, conferred to a laser diode operating at 1542.1 nm. We focus now our efforts to expand the frequency stability to a longer integration time in order to meet requirements of many space experiments, such earth gravity missions, inters satellites links or space to ground communications. Furthermore, we investigate the potential of a new approach based on frequency modulation technique (FM), associated to a 3rd harmonic detection of iodine lines to increase the compactness of the optical setup.
Electricity generation of single-chamber microbial fuel cells at low temperatures.
Cheng, Shaoan; Xing, Defeng; Logan, Bruce E
2011-01-15
Practical applications of microbial fuel cells (MFCs) for wastewater treatment will require operation of these systems over a wide range of wastewater temperatures. MFCs at room or higher temperatures (20-35°C) are relatively well studied compared those at lower temperatures. MFC performance was examined here over a temperature range of 4-30°C in terms of startup time needed for reproducible power cycles, and performance. MFCs initially operated at 15°C or higher all attained a reproducible cycles of power generation, but the startup time to reach stable operation increased from 50 h at 30°C to 210 h at 15°C. At temperatures below 15°C, MFCs did not produce appreciable power even after one month of operation. If an MFC was first started up at temperature of 30°C, however, reproducible cycles of power generation could then be achieved at even the two lowest temperatures of 4°C and 10°C. Power production increased linearly with temperature at a rate of 33±4 mW °C(-1), from 425±2 mW m(-2) at 4°C to 1260±10 mW m(-2) at 30°C. Coulombic efficiency decreased by 45% over this same temperature range, or from CE=31% at 4°C to CE=17% at 30°C. These results demonstrate that MFCs can effectively be operated over a wide range of temperatures, but our findings have important implications for the startup of larger scale reactors where low wastewater temperatures could delay or prevent adequate startup of the system. Copyright © 2010 Elsevier B.V. All rights reserved.
Brocher, Thomas M.; Blakely, Richard J.; Sherrod, Brian
2017-01-01
We investigate spatial and temporal relations between an ongoing and prolific seismicity cluster in central Washington, near Entiat, and the 14 December 1872 Entiat earthquake, the largest historic crustal earthquake in Washington. A fault scarp produced by the 1872 earthquake lies within the Entiat cluster; the locations and areas of both the cluster and the estimated 1872 rupture surface are comparable. Seismic intensities and the 1–2 m of coseismic displacement suggest a magnitude range between 6.5 and 7.0 for the 1872 earthquake. Aftershock forecast models for (1) the first several hours following the 1872 earthquake, (2) the largest felt earthquakes from 1900 to 1974, and (3) the seismicity within the Entiat cluster from 1976 through 2016 are also consistent with this magnitude range. Based on this aftershock modeling, most of the current seismicity in the Entiat cluster could represent aftershocks of the 1872 earthquake. Other earthquakes, especially those with long recurrence intervals, have long‐lived aftershock sequences, including the Mw">MwMw 7.5 1891 Nobi earthquake in Japan, with aftershocks continuing 100 yrs after the mainshock. Although we do not rule out ongoing tectonic deformation in this region, a long‐lived aftershock sequence can account for these observations.
1170 MW/sub t/ HTGR steamer cogeneration plant: design and cost study
DOE Office of Scientific and Technical Information (OSTI.GOV)
None
A conceptual design and cost study is presented for intermediate size high temperature gas-cooled reactor (HTGR) for industrial energy applications performed by United Engineers and Constructors Inc., (UE and C) and The General Atomic Company (GAC). The study is part of a program at ORNL and has the objective to provide support in the evaluation of the technical and economic feasibility of a single unit 1170 MW/sub t/ HTGR steam cycle cogeneration plant (referred to as the Steamer plant) for the production of industrial process energy. Inherent in the achievement of this objective, it was essential to perform a numbermore » of basic tasks such as the development of plant concept, capital cost estimate, project schedule and annual operation and maintenance (O and M) cost.« less
Engineering aspects of the HT-6M Tokamak
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1986-05-01
The HT-6M is a medium-sized tokamak being built in China. The principal aim of the project is to study high-power auxiliary heating (1-MW neutral beam injection, 1-MW ion cyclotron resonance heating, and 100-kW electron cyclotron resonance heating), high-..beta.. experiments, the transport process, and the formation and diffusion process of impurities. The main device parameters are: major plasma radius R = 65 cm, minor plasma radius a = 20 cm, plasma current I/subP/ = 150 kA, discharge time tau = 150 ms, toroidal field B/subT/ = 15 kG. Simplicity of construction, accessibility to the plasma, reliability in operation, and convenience formore » maintenance were particularly emphasized in the design. The important design features of the device and power supply system are described.« less
Suitability of rapid energy magnitude determinations for emergency response purposes
NASA Astrophysics Data System (ADS)
Di Giacomo, Domenico; Parolai, Stefano; Bormann, Peter; Grosser, Helmut; Saul, Joachim; Wang, Rongjiang; Zschau, Jochen
2010-01-01
It is common practice in the seismological community to use, especially for large earthquakes, the moment magnitude Mw as a unique magnitude parameter to evaluate the earthquake's damage potential. However, as a static measure of earthquake size, Mw does not provide direct information about the released seismic wave energy and its high frequency content, which is the more interesting information both for engineering purposes and for a rapid assessment of the earthquake's shaking potential. Therefore, we recommend to provide to disaster management organizations besides Mw also sufficiently accurate energy magnitude determinations as soon as possible after large earthquakes. We developed and extensively tested a rapid method for calculating the energy magnitude Me within about 10-15 min after an earthquake's occurrence. The method is based on pre-calculated spectral amplitude decay functions obtained from numerical simulations of Green's functions. After empirical validation, the procedure has been applied offline to a large data set of 767 shallow earthquakes that have been grouped according to their type of mechanism (strike-slip, normal faulting, thrust faulting, etc.). The suitability of the proposed approach is discussed by comparing our rapid Me estimates with Mw published by GCMT as well as with Mw and Me reported by the USGS. Mw is on average slightly larger than our Me for all types of mechanisms. No clear dependence on source mechanism is observed for our Me estimates. In contrast, Me from the USGS is generally larger than Mw for strike-slip earthquakes and generally smaller for the other source types. For ~67 per cent of the event data set our Me differs <= +/-0.3 magnitude units (m.u.) from the respective Me values published by the USGS. However, larger discrepancies (up to 0.8 m.u.) may occur for strike-slip events. A reason of that may be the overcorrection of the energy flux applied by the USGS for this type of earthquakes. We follow the original definition of magnitude scales, which does not apply a priori mechanism corrections to measured amplitudes, also since reliable fault-plane solutions are hardly available within 10-15 min after the earthquake origin time. Notable is that our uncorrected Me data show a better linear correlation and less scatter with respect to Mw than Me of the USGS. Finally, by analysing the recordings of representative recent pairs of strong and great earthquakes, we emphasize the importance of combining Mw and Me in the rapid characterization of the seismic source. They are related to different aspects of the source and may differ occasionally even more than 1 m.u. This highlights the usefulness and importance of providing these two magnitude estimates together for a better assessment of an earthquake's shaking potential and/or tsunamigenic potential.
Cryan, P.M.; Wolf, B. O.
2003-01-01
This study quantifies sex differences in thermoregulation and water loss of a small (20-35 g) insectivorous heterothermic mammal, the hoary bat Lasiurus cinereus, during its spring migration. We measured body temperature, metabolic rate and evaporative water loss, and calculated wet thermal conductance, for bats exposed to air temperatures ranging from 0 to 40°C for periods of 2-5 h. Pregnant females maintained normothermic body temperatures (35.7±0.7°C; mean ± s.e.m.) independent of air temperature. In contrast, males became torpid during the majority (68%) of exposures to air temperatures <25°C. The thermal neutral zone (TNZ) ranged between approximately 30°C and 34°C in both sexes and, within the TNZ, females had lower mass-specific metabolic rates (6.1±0.2 mW g-1) than males (9.0±0.9 mW g-1). Wet thermal conductance values in torpid bats (0.7±0.5 mW g-1 deg.-1) were lower than those of normothermic individuals (1.1±0.3 mW g-1 deg.-1). Mass-specific rates of evaporative water loss in males were consistently higher than in females at most air temperatures and rates of water loss in torpid bats were 63±6% of normothermic values. These results suggest that male and pregnant female L. cinereus employ different thermoregulatory strategies during their spring migration. Females defend normothermic body temperatures, presumably to expedite embryonic growth, while males use torpor, presumably to minimize energy and water deficits. These variable thermoregulatory strategies may reflect continental differences in the summer distribution of the sexes.
NASA Astrophysics Data System (ADS)
Zhu, S.; Chai, Y.; Forrest, J. A.
2017-07-01
We demonstrate the use of selective thermal evaporation to separate and purify small molecular weight polymers into highly monodisperse polymers over an extended range of polymerization index. By exploiting the calculated dependence of polymer vapor pressure on polymerization index N and temperature T , we can isolate individual components (N -mers) of an initially polydisperse mixture. To demonstrate this ability, we consider polystyrene samples of Mw=600 g/mol and Mw=890 g/mol with narrow molecular weight distributions, as well as a Mw=1200 g/mol sample with a broader distribution. In each case we are able to separate the sample into milligram quantities of many different components. Using this technique, we have been able to isolate N -mers from 3 to 13. We use differential scanning calorimetry to measure the Tg values of these components, and find that the components have the same Tg values independent of the Mw or polydispersity of the sample they originate from. We find that even initially narrow molecular weight distributions have many different components whose Tg values can differ by more than 50 K. Calculations suggest the isolated components have Mw/Mn values less than 1.001 and through a second iteration of the process could become as low as 1.000 003. The measured Tg values for the N -mers as well as large N polymers are well described by a simple relation derived from the Fox equation for the Tg of mixtures.
Liboni, William; Molinari, Filippo; Allais, Giovanni Battista; Mana, Ornella; Negri, Emanuela; D'Andrea, Giovanni; Bussone, Gennaro; Benedetto, Chiara
2008-05-01
There is an increased prevalence of patent foramen ovale (PFO) in women with migraine with aura (MwA) compared to controls, but the role of PFO in triggering aura is still debated. The aim of this study was to test a group of women suffering from MwA with near-infrared spectroscopy (NIRS), to assess the NIRS capability of discriminating between subjects with and without PFO. Eighty-eight MwA patients (mean age 37.4+/-10.7 years, range 16-62 years) underwent NIRS measurement of the cerebral variations of the oxygenated (O2Hb) and reduced haemoglobin (HHb) during breath-holding. The prevalence of O2Hb vs. HHb was used to assess the presence of PFO. As a gold standard, the presence of PFO was assessed by transcranial Doppler sonography (TCD). At the TCD analysis 48 patients (55%) showed PFOs, 32 of which were permanent. NIRS correctly detected 36 subjects out of 40 without PFO, and 38 subjects out of 48 having PFO: sensitivity was 79%; specificity was 90%. All the false negatives were permanent shunts. MwA patients with PFO showed a delayed increase in the O2Hb concentration and a reduced oxygenation with respect to subjects without PFO. NIRS is effective in identifying the presence of PFO in a MwA population, but TCD achieves better diagnostic performances. The NIRS provides additional information about the cerebral vasoreactivity and highlights substantial differences between patients with latent and permanent shunts that warrant further studies.
NASA Astrophysics Data System (ADS)
Chow, Raymond
The aerodynamic characteristics of the NREL 5-MW rotor have been examined using a Reynolds-averaged Navier-Stokes method, OVERFLOW2. A comprehensive off-body grid independence study has been performed. A strong dependence on the size of the near-body wake grid has been found. Rapid diffusion of the wake appears to generate an overprediction of power and thrust. A large, continuous near-wake grid at minimum of two rotor diameters downstream of the rotor appears to be necessary for accurate predictions of near-body forces. The NREL 5-MW rotor demonstrates significant inboard flow separation up to 30% of span. This separation appears to be highly three-dimensional, with a significant amount of radial flow increasing the size of the separated region outboard. Both integrated aerodynamic coefficients and detailed wake structures for the baseline NREL 5-MW rotor are in excellent agreement with results by Riso at Uinfinity = 8 and 11 m/s. A simple, continuous full-chord fence was applied at the maximum chord location of the blade, within the region of separation. This non-optimized device reduced the boundary-layer cross-flow and resulting separation, and increased rotor power capture by 0.9% and 0.6% at U infinity = 8 and 11 m/s, respectively. Suction side only fences perform similarly in terms of power capture but reduce the increase in rotor thrust. Fence heights from 0.5% to 17.5% of the maximum chord all demonstrate some level of effectiveness, with fences (1-2.5%cmax) showing similar performance gains to taller fences with smaller penalties in thrust. Performance in terms of power capture is not very sensitive to spanwise location when placed within the separation region. Blunt trailing edge modifications to the inboard region of the blade showed a relatively significant effect on rotor power. Over a large range of trailing edge thicknesses from hTE = 10 to 25%c, power was found to increase by 1.4%. Thrust increased proportionally with the thicknesses examined, reaching a comparable increase of 1.4% by a trailing edge thickness of 15%c. Decreasing inboard twist only acted to increase thrust without increasing power capture any further at U infinity = 11 m/s. While increasing inboard blade twist decreased power, but decreased thrust at even a higher rate. Vortex generators were not successively configured to significantly improve power capture in this study. Two of the three configurations examined actually decreased power capture and increased the separation region. The results found in this study are not believed to be representative of a properly sized and located array of VGs. The presence of the nose cone and nacelle body at the hub of the rotor is found to have a minimal effect on the power and thrust of the overall rotor. The downstream wake structure however is changed by the nacelle, potentially useful for wake tailoring when turbines are closely spaced together.
New VCSEL technology with scalability for single mode operation and densely integrated arrays
NASA Astrophysics Data System (ADS)
Zhao, Guowei; Demir, Abdullah; Freisem, Sabine; Zhang, Yu; Liu, Xiaohang; Deppe, Dennis G.
2011-06-01
Data are presented demonstrating a new lithographic vertical-cavity surface-emitting laser (VCSEL) technology, which produces simultaneous mode- and current-confinement only by lithography and epitaxial crystal growth. The devices are grown by solid source molecular beam epitaxy, and have lithographically defined sizes that vary from 3 μm to 20 μm. The lithographic process allows the devices to have high uniformity throughout the wafer and scalability to very small size. The 3 μm device shows a threshold current of 310 μA, the slope efficiency of 0.81 W/A, and the maximum output power of more than 5 mW. The 3 μm device also shows single-mode single-polarization operation without the use of surface grating, and has over 25 dB side-mode-suppression-ratio up to 1 mW of output power. The devices have low thermal resistance due to the elimination of oxide aperture. High reliability is achieved by removal of internal strain caused by the oxide, stress test shows no degradation for the 3 μm device operating at very high injection current level of 142 kA/cm2 for 1000 hours, while at this dive level commercial VCSELs fail rapidly. The lithographic VCSEL technology can lead to manufacture of reliable small size laser diode, which will have application in large area 2-D arrays and low power sensors.
Correction methods of medicinal properties of mineral waters in Pyatigorsk resort
NASA Astrophysics Data System (ADS)
Reps, Valentina; Potapov, Evgeniy; Abramtsova, Anna; Kotova, Margarita
2016-04-01
Mineral Water (MW) of Pyatigorsk deposit (PD) is united in five genetic groups (operational stocks of 2809,8 m3/day): carbonic and hydrosulphuric, carbonic, carbonic chloride-hydrocarbonate sodium (salt and alkaline), radonic low carbonate, nitrogen-carbonic terms. A variety of MW types is explained by peculiarities of geological structure and hydrogeological conditions of PD. Here on the sites of the development of deep semi-ring splits there are overflows and a mixture of various complexes. Unloading of deep water strikes happens not only on the earth surface in the form of springs but also at the depth in its edging crumbling rocks of Palaeocene and quarternary deposits. As a result of mixture processes of water and its subsequent metamorphization, various types of mineral water of this deposit are formed. Pyatigorsk resort is in a special protected ecologo-resort region which mode allows to keep stability of structure and ecological purity of MW. Nevertheless, MW variability, compositional differences and MW mineralization determining the level of its biological effect demand studying of action mechanisms of both natural MW, and possibility of its modification for range expansion of rehabilitation action. There have been examined biological effects of the course drinking reception In experiment on 80 rats males of the Wistar line biological effects of the course drinking reception of two MW types: "Krasnoarmeyskaya new" (MW1) of sulphate-hydrocarbonate-chloride calcium-sodium structure with the raised contents of iron (3-5 mg/dm3), mineralization of 5,0-5,2 g/dm3, CO2 of 1,3-2,2 g/dm3, daily flow of 10-86 m3/day, temperature from 14 to 370C on the mouth of the well and spring №2 (MW2) low sulphate, low carbonate sulphate-hydrocarbonate-chloride calcium-sodium, mineralization of 5,0 g/l, CO2 of 0,7 g/dm3, H2 of S 0,01 g/dm3. There has been shown an ability of the drinking course MW1 to influence on endocrine and metabolic continium - cortisol level increased by 1,86 times at simultaneous decrease in ACTH in 47% in comparison with the control. The decrease in lipid peroxidation intensity in 21,7% due to the change of antioxidant system capacity (ASC) - level glutathione peroxidases (GPO) with 50% of animals higher than 7 ng/l, in control group 0,7 ng/l-6,9ng/l was also noted. Modification of MW1 by selenium nanoparticles in a dosage of 20 and 40 mkg/kg led to the increase of GPO level with 75% of animals. The preventive course of MW1 with oil extract from Tambukan mud before the reproduction of the sharp model of toxic liver involvement CCL4 promoted the decrease in blood serum of the level of damage markers of plasmatic membranes of an alaninaminotransferaza (ALT) and alkaline phosphatase for 9% and 19,6% respectively. So at simultaneous decrease in cholesterol level (for 13,5%) and triglycerides (for 57,1%) in comparison with the control (pathological model). Medical courses of drinking reception of MW1 and MW2 promoted the increase of stability of cellular membranes - ALT level was noted at 17-22% below control (pathological model). Conclusions: The course reception of natural and modified drinking mineral waters of Pyatigorsk resort increases nonspecific resistance of an organism to the action of toxic factors.
Degradation of chitosan by gamma ray with presence of hydrogen peroxide
NASA Astrophysics Data System (ADS)
Mahmud, Maznah; Naziri, Muhammad Ihsan; Yacob, Norzita; Talip, Norhashidah; Abdullah, Zahid
2014-02-01
The radiation degraded chitosan samples were prepared by swelling the chitosan powder in water and exposed for gamma irradiation. The ratio chitosan to water was 1:6 with the presence of hydrogen peroxide (H2O2), 1%-5%. These chitosan-water mixtures were irradiated at 6kGy, which is the lowest irradiation dose that facility can offered. All samples were purified and proceed with characterization. The molecular weight (MW) study was monitored by size exclusion chromatography-multi angle laser light scattering (SEC-MALLS). Results showed that MW of chitosan reduced as the dose increased. Application of H2O2 enhanced the degradation rate of chitosan even at very low irradiation dose. Homogenous degradation also occurred during treatment with H2O2based on the polydispersity index (PDI) derived from the calculation of weight average molecular weight over number average molecular weight (Mw/Mn). Mechanism of chitosan radiation degradation with and without hydrogen peroxide was also discussed in this paper. Structure of degraded products was characterized with Fourier-transform infrared spectra. The degree of deacetylation (DDA) values of the samples was determined by acid-base titration. Solubility test results showed that, chitosan powder even at low Mw was insoluble in water even at low pH water. Chitosan as well as irradiated chitosan powder are soluble in strong and weak acid solution. Further discussion on behaviours of radiation degraded chitosan will be elaborated more in this paper.
Tolosa, Angel; de Fez, Dolores; Caballero, María T.; Miret, Juan J.
2017-01-01
Purpose To analyze the “in vitro” aberrometric pattern of a refractive IOL and two extended depth of focus IOLs. Methods A special optical bench with a Shack-Hartmann wavefront sensor (SH) was designed for the measurement. Three presbyopia correction IOLs were analyzed: Mini WELL (MW), TECNIS Symfony ZXR00 (SYM), and Lentis Mplus X LS-313 MF30 (MP). Three different pupil sizes were used for the comparison: 3, 4, and 4.7 mm. Results MW generated negative primary and positive secondary spherical aberrations (SA) for the apertures of 3 mm (−0.13 and +0.12 μm), 4 mm (−0.12 and +0.08 μm), and 4.7 mm (−0.11 and +0.08 μm), while the SYM only generated negative primary SA for 4 and 4.7 mm apertures (−0.12 μm and −0.20 μm, resp.). The MP induced coma and trefoil for all pupils and showed significant HOAs for apertures of 4 and 4.7 mm. Conclusions In an optical bench, the MW induces negative primary and positive secondary SA for all pupils. The SYM aberrations seem to be pupil dependent; it does not produce negative primary SA for 3 mm but increases for higher pupils. Meanwhile, the HOAs for the MW and SYM were not significant. The MP showed in all cases the highest HOAs. PMID:29318040
Camps, Vicente J; Tolosa, Angel; Piñero, David P; de Fez, Dolores; Caballero, María T; Miret, Juan J
2017-01-01
To analyze the "in vitro" aberrometric pattern of a refractive IOL and two extended depth of focus IOLs. A special optical bench with a Shack-Hartmann wavefront sensor (SH) was designed for the measurement. Three presbyopia correction IOLs were analyzed: Mini WELL (MW), TECNIS Symfony ZXR00 (SYM), and Lentis Mplus X LS-313 MF30 (MP). Three different pupil sizes were used for the comparison: 3, 4, and 4.7 mm. MW generated negative primary and positive secondary spherical aberrations (SA) for the apertures of 3 mm (-0.13 and +0.12 μ m), 4 mm (-0.12 and +0.08 μ m), and 4.7 mm (-0.11 and +0.08 μ m), while the SYM only generated negative primary SA for 4 and 4.7 mm apertures (-0.12 μ m and -0.20 μ m, resp.). The MP induced coma and trefoil for all pupils and showed significant HOAs for apertures of 4 and 4.7 mm. In an optical bench, the MW induces negative primary and positive secondary SA for all pupils. The SYM aberrations seem to be pupil dependent; it does not produce negative primary SA for 3 mm but increases for higher pupils. Meanwhile, the HOAs for the MW and SYM were not significant. The MP showed in all cases the highest HOAs.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mahmud, Maznah; Yacob, Norzita; Talip, Norhashidah
The radiation degraded chitosan samples were prepared by swelling the chitosan powder in water and exposed for gamma irradiation. The ratio chitosan to water was 1:6 with the presence of hydrogen peroxide (H{sub 2}O{sub 2}), 1%–5%. These chitosan-water mixtures were irradiated at 6kGy, which is the lowest irradiation dose that facility can offered. All samples were purified and proceed with characterization. The molecular weight (MW) study was monitored by size exclusion chromatography-multi angle laser light scattering (SEC-MALLS). Results showed that MW of chitosan reduced as the dose increased. Application of H{sub 2}O{sub 2} enhanced the degradation rate of chitosan evenmore » at very low irradiation dose. Homogenous degradation also occurred during treatment with H{sub 2}O{sub 2}based on the polydispersity index (PDI) derived from the calculation of weight average molecular weight over number average molecular weight (Mw/Mn). Mechanism of chitosan radiation degradation with and without hydrogen peroxide was also discussed in this paper. Structure of degraded products was characterized with Fourier-transform infrared spectra. The degree of deacetylation (DDA) values of the samples was determined by acid-base titration. Solubility test results showed that, chitosan powder even at low Mw was insoluble in water even at low pH water. Chitosan as well as irradiated chitosan powder are soluble in strong and weak acid solution. Further discussion on behaviours of radiation degraded chitosan will be elaborated more in this paper.« less
Countability of Planck Boxes in Quantum Branching Models
NASA Astrophysics Data System (ADS)
Berezin, Alexander A.
2002-04-01
Two popular paradigms of cosmological quantum branching are Many World (MW) model of parallel universes (Everett, Deutsch) and inflationary quantum foam (IQF) model (Guth, Linde). Taking Planck L,T units as physically smallest, our Big Bang miniverse with size 10E28 cm and duration 10E18 sec has some 10E244 (N) elementary 4D Planck Boxes (PB) in its entire spacetime history. Using combinatorics, N! (about 10E10E247) is upper estimate for number of all possible 4D states, i.e. scale of "eternal return" (ER; Nietzsche, Eliade) for such miniverses. To count all states in full Megaverse (all up and down branches of infinite tree of all MW and/or IQF miniverses) we recall that all countable infinities have same (aleph-naught) cardinality (Cantor). Using Godel-type numbering, count PB in our miniverse by primes. This uses first N primes. Both MW and IQF models presume splitting of miniverses as springing (potentially) from each PB, making each PB infinitely rich, inexhaustible and unique. Next branching level is counted by integers p1Ep2, third level by p1Ep2Ep3 integers, etc, ad infinitum. To count in up and down directions from "our" miniverse, different branching subsets of powers of primes can be used at all levels of tower exponentiation. Thus, all PB in all infinitude of MW and/or IQF branches can be uniquely counted by never repeating integers (tower exponents of primes), offering escape from grim ER scenarios.
Demonstration of a Dual-Band Mid-Wavelength HgCdTe Detector Operating at Room Temperature
NASA Astrophysics Data System (ADS)
Martyniuk, P.; Madejczyk, P.; Gawron, W.; Rutkowski, J.
2018-03-01
In this paper, the performance of sequential dual-band mid-wavelength N+-n-p-p-P+-p-p-n-n+ back-to-back HgCdTe photodiode grown by metal-organic chemical vapor deposition (MOCVD) operating at room temperature is presented. The details of the MOCVD growth procedure are given. The influence of p-type separating-barrier layer on dark current, photocurrent and response time was analyzed. Detectivity without immersion D * higher than 1 × 108 cmHz1/2/W was estimated for λ Peak = 3.2 μm and 4.2 μm, respectively. A response time of τ s ˜ 1 ns could be reached in both MW1 and MW2 ranges for the optimal P+ barrier Cd composition at the range 0.38-0.42, and extra series resistance related to the processing R Series equal to 500 Ω.
Assessment Study of Small Space Debris Removal by Laser Satellites
NASA Technical Reports Server (NTRS)
Choi, Sang H.; Papa, Richard S.
2011-01-01
Space debris in Earth orbit poses significant danger to satellites, humans in space, and future space exploration activities. In particular, the increasing number of unidentifiable objects, smaller than 10 cm, presents a serious hazard. Numerous technologies have been studied for removing unwanted objects in space. Our approach uses a short wavelength laser stationed in orbit to vaporize these small objects. This paper discusses the power requirements for space debris removal using lasers. A short wavelength laser pumped directly or indirectly by solar energy can scan, identify, position, and illuminate the target, which will then be vaporized or slow down the orbital speed of debris by laser detonation until it re-enters the atmosphere. The laser-induced plasma plume has a dispersive motion of approximately 105 m/sec with a Lambertian profile in the direction of the incoming beam [1-2]. The resulting fast ejecting jet plume of vaporized material should prevent matter recombination and condensation. If it allows any condensation of vaporized material, the size of condensed material will be no more than a nanoscale level [3]. Lasers for this purpose can be indirectly pumped by power from an array of solar cells or directly pumped by the solar spectrum [4]. The energy required for vaporization and ionization of a 10 cm cube ( 2700 gm) of aluminum is 87,160 kJ. To remove this amount of aluminum in 3 minutes requires a continuous laser beam power of at least 5.38 MW under the consideration of 9% laser absorption by aluminum [5] and 5% laser pumping efficiency. The power needed for pumping 5.38 MW laser is approximately 108 MW, which can be obtained from a large solar array with 40% efficiency solar cells and a minimal area of 450 meters by 450 meters. This solar array would collect approximately 108 MW. The power required for system operation and maneuvering can be obtained by increasing solar panel size. This feasibility assessment covers roughly the power requirement, laser system, and a potential operational scenario.
Use of Different Proteases to Obtain Flaxseed Protein Hydrolysates with Antioxidant Activity.
Karamać, Magdalena; Kosińska-Cagnazzo, Agnieszka; Kulczyk, Anna
2016-06-29
The antioxidant activity of flaxseed protein hydrolysates obtained using five different enzymes was evaluated. Proteins were isolated from flaxseed cake and were separately treated with papain, trypsin, pancreatin, Alcalase and Flavourzyme. The degree of hydrolysis (DH) was determined as the percentage of cleaved peptide bonds using a spectrophotometric method with o-phthaldialdehyde. The distribution of the molecular weights (MW) of the hydrolysis products was profiled using Tricine-sodium dodecyl sulfate-polyacrylamide gel electrophoresis (Tricine-SDS-PAGE) and size exclusion-high performance liquid chromatography (SE-HPLC) separations. The antioxidant activities of the protein isolate and hydrolysates were probed for their radical scavenging activity using 2,2'-azino-bis-(3-ethylbenzothiazoline-6-sulfonate) radical cation (ABTS(•+)) and photochemiluminescence (PCL-ACL) assays, and for their ferric reducing antioxidant power (FRAP) and ability to bind Fe(2+). The hydrolysates were more effective as antioxidants than the protein isolate in all systems. The PCL-ACL values of the hydrolysates ranged from 7.2 to 35.7 μmol Trolox/g. Both the FRAP and ABTS(•+) scavenging activity differed among the hydrolysates to a lower extent, with the ranges of 0.20-0.24 mmol Fe(2+)/g and 0.17-0.22 mmol Trolox/g, respectively. The highest chelating activity (71.5%) was noted for the pancreatin hydrolysate. In general, the hydrolysates obtained using Alcalase and pancreatin had the highest antioxidant activity, even though their DH (15.4% and 29.3%, respectively) and the MW profiles of the peptides varied substantially. The O₂(•-) scavenging activity and the ability to chelate Fe(2+) of the Flavourzyme hydrolysate were lower than those of the Alcalase and pancreatin hydrolysates. Papain was the least effective in releasing the peptides with antioxidant activity. The study showed that the type of enzyme used for flaxseed protein hydrolysis determines the antioxidant activity of the hydrolysates.
The Near-Earth Encounter of Asteroid 308635 (2005 YU55): Thermal IR Observations
NASA Astrophysics Data System (ADS)
Lim, Lucy F.; Emery, J. P.; Moskovitz, N. A.; Busch, M. W.; Yang, B.; Granvik, M.
2012-10-01
The near-Earth approach (0.00217 AU, or 0.845 lunar distances) of the C-type asteroid 308635 (2005 YU55) in November 2011 presented a rare opportunity for detailed observations of a low-albedo NEA in this size range. As part of a multi-telescope campaign to measure visible and infrared spectra and photometry, we obtained mid-infrared ( 8 to 22 micron) photometry and spectroscopy of 2005 YU55 using Michelle [1] on the Gemini North telescope on UT November 9 and 10, 2011. An extensive radar campaign [2] together with optical lightcurves [3,4] established the rotation state of YU55. In addition, the radar imaging resulted in a shape model for the asteroid, detection of numerous boulders on its surface, and a preliminary estimate of its equatorial diameter at 380 +/- 20 m. In a preliminary analysis, applying the radar and lightcurve-derived parameters to a rough-surface thermophysical model fit to the Gemini/Michelle thermal emission photometry results in a thermal inertia range of approximately 500 to 1500 J m-2 s-1/2 K-1, with the low-thermal-inertia solution corresponding to the small end of the radar size range and vice versa. Updates to these results will be presented and modeling of the thermal contribution to the measured near-infrared spectra from Palomar/Triplespec and IRTF/SpeX will also be discussed. The authors gratefully acknowledge the assistance of observatory staff and the support of the NASA NEOO program (LFL and JPE), the Carnegie fellowship (NAM), and NASA AES, NSF, and the NRAO Jansky Fellowship (MWB). [1] De Buizer, J. and R. Fisher, Proc. Hris (2005), pp. 84-87. [2] Busch, M.W. et al., ACM (2012), abstract #6179. [3] Warner, B., MPBull 39 (2), 84 [4] Pravec, P.
Laser comminution of submerged samples
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mariella, R. Jr.; Rubenchik, A.; Norton, M.
With the long-term goal in mind of investigating possible designs for a 'universal, solid-sample comminution technique' for elemental analysis of debris and rubble, we have studied pulsed-laser ablation of solid samples that were submerged in water. Using 351-nm, 15-ns laser pulses with energy between 1 J and 0.35 J, intensities between 500 MW/cm{sup 2} and 30 MW/cm{sup 2}, and samples of broken rock [quartzite] and concrete debris, we have observed conditions in which the laser-driven process can remove material from the solid target substrate, dissolving it and/or converting it into ultrafine particles in a controlled manner. Our study used impure,more » non-metallic substrates and investigated both the rate of material removal as well as the size distribution of particles that were ablated from the process. We studied ablation at lower regimes of intensity and fluence [below 100 MW/cm{sup 2} and 0.4 J/cm{sup 2}, respectively] than has previously attracted attention and discovered that there appears to be a new regime for energy-efficient material removal [Q* < 4000 J/g, for quartzite and <2000 J/g for concrete] and for the generation of ultrafine particles.« less
Lin, Chia-Wei; Haeuptle, Micha A; Aebi, Markus
2016-09-06
Recent developments in proteomic techniques have led to the development of mass spectrometry (MS)-based methods to characterize site-specific glycosylation of proteins. However, appropriate analytical tools to characterize acidic and high-molecular-weight (hMW) glycopeptides are still lacking. In this study, we demonstrate that the addition of supercharging reagent, m-nitrobenzyl alcohol (m-NBA), into mobile phases greatly facilitates the analysis of acidic and hMW glycopeptides. Using commercial glycoproteins, we demonstrated that in the presence of m-NBA the charge state of sialylated glycopeptides increased and the chromatographic separation of neutral and acidic glycopeptides revealed a remarkable improvement. Next, we applied this system to the characterization of a glycoconjugate vaccine candidate consisting of a genetically detoxified exotoxin A of Pseudomonas aeruginosa covalently linked to Shigella flexneri type 2a O-antigen (Sf2E) produced by engineered Escherichia coli. The addition of m-NBA, allowed us to identify peptides with glycan chains of unprecedented size, up to 20 repeat units (98 monosaccharides). Our results indicated that incorporation of m-NBA into reversed-phase liquid chromatography (LC) solvents improves sensitivity, charging, and chromatographic resolution for acidic and hMW glycopeptides.
Final Technical Report - Modernization of the Boulder Canyon Hydroelectric Project
DOE Office of Scientific and Technical Information (OSTI.GOV)
Taddeucci, Joe
2013-03-29
The Boulder Canyon Hydroelectric Project (BCH) was purchased by the City of Boulder, CO (the city) in 2001. Project facilities were originally constructed in 1910 and upgraded in the 1930s and 1940s. By 2009, the two 10 MW turbine/generators had reached or were nearing the end of their useful lives. One generator had grounded out and was beyond repair, reducing plant capacity to 10 MW. The remaining 10 MW unit was expected to fail at any time. When the BCH power plant was originally constructed, a sizeable water supply was available for the sole purpose of hydroelectric power generation. Betweenmore » 1950 and 2001, that water supply had gradually been converted to municipal water supply by the city. By 2001, the water available for hydroelectric power generation at BCH could not support even one 10 MW unit. Boulder lacked the financial resources to modernize the facilities, and Boulder anticipated that when the single, operational historical unit failed, the project would cease operation. In 2009, the City of Boulder applied for and received a U.S. Department of Energy (DOE) grant for $1.18 million toward a total estimated project cost of $5.155 million to modernize BCH. The federal funding allowed Boulder to move forward with plant modifications that would ensure BCH would continue operation. Federal funding was made available through the American Recovery and Reinvestment Act (ARRA) of 2009. Boulder determined that a single 5 MW turbine/generator would be the most appropriate capacity, given the reduced water supply to the plant. Average annual BCH generation with the old 10 MW unit had been about 8,500 MW-hr, whereas annual generation with a new, efficient turbine could average 11,000 to 12,000 MW-hr. The incremental change in annual generation represents a 30% increase in generation over pre-project conditions. The old turbine/generator was a single nozzle Pelton turbine with a 5-to-1 flow turndown and a maximum turbine/generator efficiency of 82%. The new unit is a double nozzle Pelton turbine with a 10-to-1 flow turndown and a maximum turbine/generator efficiency of 88%. This alone represents a 6% increase in overall efficiency. The old turbine operated at low efficiencies due to age and non-optimal sizing of the turbine for the water flow available to the unit. It was shut down whenever water flow dropped to less than 4-5 cfs, and at that flow, efficiency was 55 to 60%. The new turbine will operate in the range of 70 to 88% efficiency through a large portion of the existing flow range and would only have to be shut down at flow rates less than 3.7 cfs. Efficiency is expected to increase by 15-30%, depending on flow. In addition to the installation of new equipment, other goals for the project included: Increasing safety at Boulder Canyon Hydro Increasing protection of the Boulder Creek environment Modernizing and integrating control equipment into Boulder's municipal water supply system, and Preserving significant historical engineering information prior to power plant modernization. From January 1, 2010 through December 31, 2012, combined consultant and contractor personnel hours paid for by both the city and the federal government have totaled approximately 40,000. This equates roughly to seven people working full time on the project from January 2010 through December 2012. This project also involved considerable material expense (steel pipe, a variety of valves, electrical equipment, and the various components of the turbine and generator), which were not accounted for in terms of hours spent on the project. However, the material expense related to this project did help to create or preserve manufacturing/industrial jobs throughout the United States. As required by ARRA, the various components of the hydroelectric project were manufactured or substantially transformed in the U.S. BCH is eligible for nomination to the National Register of Historic Places due in part to its unique engineering features and innovative construction techniques. Special efforts were directed toward documenting the (largely original) interior of the plant and installing new equipment without modifying the power plant exterior in order to preserve the historical significance of the facility. In addition, a significant portion of the historical equipment within the power plant was preserved in place. The modernization project began with DOE grant award on January 1, 2010, and the project was completed on December 31, 2012. In addition to city engineering and hydroelectric staff, major project participants included AECOM (design/engineering) Canyon Industries (turbine/generator manufacture), Gracon Corporation (general construction contractor), Exponential Engineering Company (electrical engineering) and URS Corporation (historical documentation), as well as numerous other subcontractors and consultants.« less
Testing stress shadowing effects at the South American subduction zone
NASA Astrophysics Data System (ADS)
Roth, F.; Dahm, T.; Hainzl, S.
2017-11-01
The seismic gap hypothesis assumes that a characteristic earthquake is followed by a long period with a reduced occurrence probability for the next large event on the same fault segment, as a consequence of the induced stress shadow. The gap model is commonly accepted by geologists and is often used for time-dependent seismic hazard estimations. However, systematic and rigorous tests to verify the seismic gap model have often failed so far, which might be partially related to limited data and too tight model assumptions. In this study, we relax the assumption of a characteristic size and location of repeating earthquakes and analyse one of the best available data sets, namely the historical record of major earthquakes along a 3000 km long linear segment of the South American subduction zone. To test whether a stress shadow effect is observable, we compiled a comprehensive catalogue of mega-thrust earthquakes along this plate boundary from 1520 to 2015 containing 174 earthquakes with Mw > 6.5. In our new testing approach, we analyse the time span between an earthquake and the last event that ruptured the epicentre location, where we consider the impact of the uncertainties of epicentres and rupture extensions. Assuming uniform boundary conditions along the trench, we compare the distribution of these recurrence times with simple recurrence models. We find that the distribution is in all cases almost exponentially distributed corresponding to a random (Poissonian) process; despite some tendencies for clustering of the Mw ≥ 7 events and a weak quasi-periodicity of the Mw ≥ 8 earthquakes, respectively. To verify whether the absence of a clear stress shadow signal is related to physical assumptions or data uncertainties, we perform simulations of a physics-based stochastic earthquake model considering rate and state-dependent earthquake nucleation, which are adapted to the observations with regard to the number of events, spatial extend, size distribution and involved uncertainties. Our simulations show that the catalogue uncertainties lead to a significant blurring of the theoretically peaked distribution, but the distribution would be still distinguishable from the observed one for Mw ≥ 7 events. However, considering the stress transfer to adjacent fault segments and heterogeneous instead of constant stress drop within the rupture zone can explain the observed recurrence time distribution. We conclude that simplified recurrence models, ignoring the complexity of the underlying physical process, cannot be applied for forecasting the Mw ≥ 7 earthquake occurrence at this plate boundary.
A log-normal distribution model for the molecular weight of aquatic fulvic acids
Cabaniss, S.E.; Zhou, Q.; Maurice, P.A.; Chin, Y.-P.; Aiken, G.R.
2000-01-01
The molecular weight of humic substances influences their proton and metal binding, organic pollutant partitioning, adsorption onto minerals and activated carbon, and behavior during water treatment. We propose a lognormal model for the molecular weight distribution in aquatic fulvic acids to provide a conceptual framework for studying these size effects. The normal curve mean and standard deviation are readily calculated from measured M(n) and M(w) and vary from 2.7 to 3 for the means and from 0.28 to 0.37 for the standard deviations for typical aquatic fulvic acids. The model is consistent with several types of molecular weight data, including the shapes of high- pressure size-exclusion chromatography (HP-SEC) peaks. Applications of the model to electrostatic interactions, pollutant solubilization, and adsorption are explored in illustrative calculations.The molecular weight of humic substances influences their proton and metal binding, organic pollutant partitioning, adsorption onto minerals and activated carbon, and behavior during water treatment. We propose a log-normal model for the molecular weight distribution in aquatic fulvic acids to provide a conceptual framework for studying these size effects. The normal curve mean and standard deviation are readily calculated from measured Mn and Mw and vary from 2.7 to 3 for the means and from 0.28 to 0.37 for the standard deviations for typical aquatic fulvic acids. The model is consistent with several type's of molecular weight data, including the shapes of high-pressure size-exclusion chromatography (HP-SEC) peaks. Applications of the model to electrostatic interactions, pollutant solubilization, and adsorption are explored in illustrative calculations.
NASA Astrophysics Data System (ADS)
Panther, Chad C.
Vertical Axis Wind Turbines (VAWTs) have experienced a renewed interest in development for urban, remote, and offshore applications. Past research has shown that VAWTs cannot compete with Horizontals Axis Wind Turbines (HAWTs) in terms of energy capture efficiency. VAWT performance is plagued by dynamic stall (DS) effects at low tip-speed ratios (lambda), where each blade pitches beyond static stall multiple times per revolution. Furthermore, for lambda<2, blades operate outside of stall during over 70% of rotation. However, VAWTs offer many advantages such as omnidirectional operation, ground proximity of generator, lower sound emission, and non-cantilevered blades with longer life. Thus, mitigating dynamic stall and improving VAWT blade aerodynamics for competitive power efficiency has been a popular research topic in recent years and the directive of this study. Past research at WVU focused on the addition of circulation control (CC) technology to improve VAWT aerodynamics and expand the operational envelope. A novel blade design was generated from the augmentation of a NACA0018 airfoil to include CC capabilities. Static wind tunnel data was collected for a range of steady jet momentum coefficients (0.01≤ Cmu≤0.10) for analytical vortex model performance projections. Control strategies were developed to optimize CC jet conditions throughout rotation, resulting in improved power output for 2≤lambda≤5. However, the pumping power required to produce steady CC jets reduced net power gains of the augmented turbine by approximately 15%. The goal of this work was to investigate pulsed CC jet actuation to match steady jet performance with reduced mass flow requirements. To date, no experimental studies have been completed to analyze pulsed CC performance on a pitching airfoil. The research described herein details the first study on the impact of steady and pulsed jet CC on pitching VAWT blade aerodynamics. Both numerical and experimental studies were implemented, varying Re, k, and +/-alpha to match a typical VAWT operating environment. A range of reduced jet frequencies (0.25≤St≤4) were analyzed with varying Cmu, based on effective ranges from prior flow control airfoil studies. Airfoil pitch was found to increase the baseline lift-to-drag ratio (L/D) by up to 50% due to dynamic stall effects. The influence of dynamic stall on steady CC airfoil performance was greater for Cmu=0.05, increasing L/D by 115% for positive angle-of-attack. Pulsed actuation was shown to match, or improve, steady jet lift performance while reducing required mass flow by up to 35%. From numerical flow visualization, pulsed actuation was shown to reduce the size and strength of wake vorticity during DS, resulting in lower profile drag relative to baseline and steady actuation cases. A database of pitching airfoil test data, including overshoot and hysteresis of aerodynamic coefficients (Cl, Cd), was compiled for improved analytical model inputs to update CCVAWT performance predictions, where the aforementioned L/D improvements will be directly reflected. Relative to a conventional VAWT with annual power output of 1 MW, previous work at WVU proved that the addition of steady jet CC could improve total output to 1.25 MW. However, the pumping cost to generate the continuous jet reduced yearly CCVAWT net gains to 1.15 MW. The current study has shown that pulsed CC jets can recover 4% of the pumping demands due to reduced mass flow requirements, increasing annual CCVAWT net power production to 1.19 MW, a 19% improvement relative to the conventional turbine.
Rapid determination of the energy magnitude Me
NASA Astrophysics Data System (ADS)
di Giacomo, D.; Parolai, S.; Bormann, P.; Saul, J.; Grosser, H.; Wang, R.; Zschau, J.
2009-04-01
The magnitude of an earthquake is one of the most used parameters to evaluate the earthquake's damage potential. However, many magnitude scales developed over the past years have different meanings. Among the non-saturating magnitude scales, the energy magnitude Me is related to a well defined physical parameter of the seismic source, that is the radiated seismic energy ES (e.g. Bormann et al., 2002): Me = 2/3(log10 ES - 4.4). Me is more suitable than the moment magnitude Mw in describing an earthquake's shaking potential (Choy and Kirby, 2004). Indeed, Me is calculated over a wide frequency range of the source spectrum and represents a better measure of the shaking potential, whereas Mw is related to the low-frequency asymptote of the source spectrum and is a good measure of the fault size and hence of the static (tectonic) effect of an earthquake. The calculation of ES requires the integration over frequency of the squared P-waves velocity spectrum corrected for the energy loss experienced by the seismic waves along the path from the source to the receivers. To accout for the frequency-dependent energy loss, we computed spectral amplitude decay functions for different frequenciesby using synthetic Green's functions (Wang, 1999) based on the reference Earth model AK135Q (Kennett et al., 1995; Montagner and Kennett, 1996). By means of these functions the correction for the various propagation effects of the recorded P-wave velocity spectra is performed in a rapid and robust way, and the calculation of ES, and hence of Me, can be computed at the single station. We analyse teleseismic broadband P-waves signals in the distance range 20°-98°. We show that our procedure is suitable for implementation in rapid response systems since it could provide stable Me determinations within 10-15 minutes after the earthquake's origin time. Indeed, we use time variable cumulative energy windows starting 4 s after the first P-wave arrival in order to include the earthquake rupture duration, which is calculated according to Bormann and Saul (2008). We tested our procedure for a large dataset composed by about 750 earthquakes globally distributed in the Mw range 5.5-9.3 recorded at the broadband stations managed by the IRIS, GEOFON, and GEOSCOPE global networks, as well as other regional seismic networks. Me and Mw express two different aspects of the seismic source, and a combined use of these two magnitude scales would allow a better assessment of the tsunami and shaking potential of an earthquake.. References Bormann, P., Baumbach, M., Bock, G., Grosser, H., Choy, G. L., and Boatwright, J. (2002). Seismic sources and source parameters, in IASPEI New Manual of Seismological Observatory Practice, P. Bormann (Editor), Vol. 1, GeoForschungsZentrum, Potsdam, Chapter 3, 1-94. Bormann, P., and Saul, J. (2008). The new IASPEI standard broadband magnitude mB. Seism. Res. Lett., 79(5), 699-705. Choy, G. L., and Kirby, S. (2004). Apparent stress, fault maturity and seismic hazard for normal-fault earthquakes at subduction zones. Geophys. J. Int., 159, 991-1012. Kennett, B. L. N., Engdahl, E. R., and Buland, R. (1995). Constraints on seismic velocities in the Earth from traveltimes. Geophys. J. Int., 122, 108-124. Montagner, J.-P., and Kennett, B. L. N. (1996). How to reconcile body-wave and normal-mode reference Earth models?. Geophys. J. Int., 125, 229-248. Wang, R. (1999). A simple orthonormalization method for stable and efficient computation of Green's functions. Bull. Seism. Soc. Am., 89(3), 733-741.
Blue laser system for photo-dynamic therapy
NASA Astrophysics Data System (ADS)
Dabu, R.; Carstocea, B.; Blanaru, C.; Pacala, O.; Stratan, A.; Ursu, D.; Stegaru, F.
2007-03-01
A blue laser system for eye diseases (age related macular degeneration, sub-retinal neo-vascularisation in myopia and presumed ocular histoplasmosis syndrome - POHS) photo-dynamic therapy, based on riboflavin as photosensitive substance, has been developed. A CW diode laser at 445 nm wavelength was coupled through an opto-mechanical system to the viewing path of a bio-microscope. The laser beam power in the irradiated area is adjustable between 1 mW and 40 mW, in a spot of 3-5 mm diameter. The irradiation time can be programmed in the range of 1-19 minutes. Currently, the laser system is under clinic tests.
Single-frequency diode-pumped lasers for free-space optical communication
NASA Technical Reports Server (NTRS)
Kane, Thomas J.; Cheng, Emily A. P.; Gerstenberger, David C.; Wallace, Richard W.
1990-01-01
Recent advances in laser technology for intersatellite optical communication systems are reviewed and illustrated with graphs and diagrams. Topics addressed include (1) single-frequency diode-pumped Nd:YAG lasers of monolithic ring configuration (yielding 368-384 mW output power with 1-W pumping), (2) injection chaining of up to 10 monolithic resonators to achieve redundancy and/or higher output power, (3) 2-kHz-linewidth 5-mW versions of (1) which are tunable over a 30-MHz range for use as local oscillators in coherent communication, (4) resonant external modulation and doubling or resonant phase modulation of diode-pumped lasers, and (5) wavelength multiplexing.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chiang, Cheng Ching K.; Barkakaty, Balaka; Puskas, Judit E.
The superior properties of natural rubber (cis-1,4-polyisoprene [NR]) are a function of its structure and composition, properties that still remain a mystery and that are irreplaceable by any synthetic rubber. NR from guayule (Parthenium argentatum) has been gaining special interest for its hypoallergenic properties while maintaining superior mechanical properties that are commonly associated with the Brazilian rubber tree (Hevea brasiliensis), the most common source of NR. Techniques exist to isolate washed rubber particles (WRPs) that contain enzymatically active rubber transferase, to study NR biosynthesis, and previous work on the in vitroNRgrowth in Hevea has demonstrated the presence of around 50wt%ofmore » a low molecular weight ([MW], Mn <10 000 g/mol) fraction. Structural and compositional analyses of this low MW fraction in Hevea are challenging due to the high protein content. Here, we discuss the analysis and composition of guayule latex and WRPs using high-resolution Size Exclusion Chromatography. We also discuss the composition of the soluble fraction of inactive guayule latex using matrix-assisted laser desorption ionization/time of flight mass spectrometry.« less
Happonen, Matti; Mylläri, Fanni; Karjalainen, Panu; Frey, Anna; Saarikoski, Sanna; Carbone, Samara; Hillamo, Risto; Pirjola, Liisa; Häyrinen, Anna; Kytömäki, Jorma; Niemi, Jarkko V; Keskinen, Jorma; Rönkkö, Topi
2013-12-17
Heavy fuel oil (HFO) is a commonly used fuel in industrial heating and power generation and for large marine vessels. In this study, the fine particle emissions of a 47 MW oil-fired boiler were studied at 30 MW power and with three different fuels. The studied fuels were HFO, water emulsion of HFO, and water emulsion of HFO mixed with light fuel oil (LFO). With all the fuels, the boiler emitted considerable amounts of particles smaller than 200 nm in diameter. Further, these small particles were quite hygroscopic even as fresh and, in the case of HFO+LFO emulsion, the hygroscopic growth of the particles was dependent on particle size. The use of emulsions and the addition of LFO to the fuel had a reducing effect on the hygroscopic growth of particles. The use of emulsions lowered the sulfate content of the smallest particles but did not affect significantly the sulfate content of particles larger than 42 nm and, further, the addition of LFO considerably increased the black carbon content of particulate matter. The results indicate that even the fine particles emitted from HFO based combustion can have a significant effect on cloud formation, visibility, and air quality.
Morphology and phase evolution in microwave synthesized Al/FeO4 system.
Chuan, Lee Chang; Yoshikawaa, Noboru; Taniguchia, Shoji
2011-01-01
Thermite reaction between Al/Fe3O4 raised by microwave (MW) heating under N2 atmosphere has been investigated, and compared with that by the electric furnace. In addition to the stoichiometric ratio for the production of metallic iron and alumina, mixture with slightly Lower in Al content is also studied. As thermite reaction is highly exothermic, melting of reaction product and destruction of microstructure may occur, which corresponds to the enthalpy and adiabatic temperature of the reaction. Hence, to avoid this problem, reaction coupled with a smaller driving force by controlling the MW ignition condition at low temperature exotherm has been investigated. The phase and microstructure evolution during the reaction were analyzed by differential thermal analysis (DTA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). Thermogram of the DTA analysis, irrespective of their mole ratio, recorded two exothermic peaks, one at - 1310 degrees C and another one at - 1370 degrees C. When heated by microwave at 955 degrees C, the main products were identified as Al, FeO and Fe, minor amount of Fe3O4 and some Fe and alumina were detected. When heating to 1155 degrees C, Al and Fe3O4 peaks disappeared, formation of Fe-Al alloy was observed. For sample heated at 1265 degrees C, a porous body was obtained. Micron sized metal particles with complex morphology, irregular in size and shapes were formed, uniformly distributed within the spinel hercynite and/or alumina matrix. In contrast, conventional heating produced no porous products. Formation of alumina is also observed around the metal particles. Controlling of the reaction progress was possible while heating the sample by MW around the low temperature exotherm region, whereas the combustion wave could not be self-propagated.
NASA Astrophysics Data System (ADS)
Fachinger, Friederike; Drewnick, Frank; Gieré, Reto; Borrmann, Stephan
2018-05-01
Particulate and gaseous emissions of two medium-sized district heating facilities (400 kW, fueled with miscanthus, and 1.5 MW, fueled with wood chips) were characterized for different operational conditions, and compared to previously obtained results for household wood and pellet stoves. SO2 and NOx emission factors (reported in mg MJFuel-1) were found to not only depend on fuel sulfur/nitrogen content, but also on combustion appliance type and efficiency. Emission factors of SO2, NOx, and PM (particulate matter) increased with increasing load. Particle chemical composition did not primarily depend on operational conditions, but varied mostly with combustion appliances, fuel types, and flue gas cleaning technologies. Black carbon content was decreasing with increasing combustion efficiency; chloride content was strongly enhanced when burning miscanthus. Flue gas cleaning using an electrostatic precipitator caused strong reduction not only in total PM, but also in the fraction of refractory and semi-refractory material within emitted PM1. For the impact of facilities on their surroundings (immissions) not only their total emissions are decisive, but also their stack heights. In immission measurements downwind of the two facilities, a plume could only be observed for the 400 kW facility with low (11 m) stack height (1.5 MW facility: 30 m), and measured immissions agreed reasonably well with predicted ones. The impact of these immissions is non-negligible: At a distance of 50 m from the facility, apart from CO2, also plume contributions of NOx, ultrafine particles, PM1, PM10, poly-aromatic hydrocarbons, and sulfate were detected, with enhancements above background values of 2-130%.
Lienkaemper, James J.; McFarland, Forrest S.; Simpson, Robert W.; Bilham, Roger; Ponce, David A.; Boatwright, John; Caskey, S. John
2012-01-01
The Hayward fault (HF) in California exhibits large (Mw 6.5–7.1) earthquakes with short recurrence times (161±65 yr), probably kept short by a 26%–78% aseismic release rate (including postseismic). Its interseismic release rate varies locally over time, as we infer from many decades of surface creep data. Earliest estimates of creep rate, primarily from infrequent surveys of offset cultural features, revealed distinct spatial variation in rates along the fault, but no detectable temporal variation. Since the 1989 Mw 6.9 Loma Prieta earthquake (LPE), monitoring on 32 alinement arrays and 5 creepmeters has greatly improved the spatial and temporal resolution of creep rate. We now identify significant temporal variations, mostly associated with local and regional earthquakes. The largest rate change was a 6‐yr cessation of creep along a 5‐km length near the south end of the HF, attributed to a regional stress drop from the LPE, ending in 1996 with a 2‐cm creep event. North of there near Union City starting in 1991, rates apparently increased by 25% above pre‐LPE levels on a 16‐km‐long reach of the fault. Near Oakland in 2007 an Mw 4.2 earthquake initiated a 1–2 cm creep event extending 10–15 km along the fault. Using new better‐constrained long‐term creep rates, we updated earlier estimates of depth to locking along the HF. The locking depths outline a single, ∼50‐km‐long locked or retarded patch with the potential for an Mw∼6.8 event equaling the 1868 HF earthquake. We propose that this inferred patch regulates the size and frequency of large earthquakes on HF.
Enforcing Job Safety: A Managerial View
ERIC Educational Resources Information Center
Barnako, Frank R.
1975-01-01
The views of management or of employees regarding enforcement of the job safety law range from general satisfaction to calls for repeal of the act. The complexity of standards, statistics and recordkeeping, and enforcement procedures are major areas of concern. (MW)
GREENER CHEMICAL SYNTHESES USING MICROWAVE IRRADIATION
Greener solvent-free protocols involve microwave (MW) exposure of neat reactants catalyzed by the surfaces of recyclable mineral supports such as alumina, silica and clay which are applicable to a wide range of cleavage, condensation, cyclization, oxidation and reduction reaction...
GREENER CHEMICAL SYNTHESIS USING MICROWAVES
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or "doped" surfaces is presented which is applicable to a wide range of cleavage, condensation, cyc...
Elucidating Adsorptive Fractions of Natural Organic Matter on Carbon Nanotubes.
Ateia, Mohamed; Apul, Onur G; Shimizu, Yuta; Muflihah, Astri; Yoshimura, Chihiro; Karanfil, Tanju
2017-06-20
Natural organic matter (NOM) is a heterogeneous mixture of organic compounds that is omnipresent in natural waters. To date, the understanding of the adsorption of NOM components by carbon nanotubes (CNTs) is limited because of the limited number of comprehensive studies in the literature examining the adsorption of NOM by CNTs. In this study, 11 standard NOM samples from various sources were characterized, and their adsorption behaviors on four different CNTs were examined side-by-side using total organic carbon, fluorescence, UV-visible spectroscopy, and high-performance size-exclusion chromatography (HPSEC) analysis. Adsorption was influenced by the chemical properties of the NOM, including aromaticity, degree of oxidation, and carboxylic acidity. Fluorescence excitation-emission matrix (EEM) analysis showed preferential adsorption of decomposed and terrestrial-derived NOM compared to freshly produced and microbial-derived NOM. HPSEC analysis revealed preferential adsorption of fractions in the molecular weight range of 0.5-2 kDa for humic acids but in the molecular weight range of 1-3 kDa for all fulvic acids and reverse-osmosis isolates. However, the smallest characterized fraction (MW < 0.4 kDa) in all samples did not adsorb on the CNTs.
Preliminary tests of silicon carbide based concretes for hybrid rocket nozzles in a solar furnace
NASA Astrophysics Data System (ADS)
D'Elia, Raffaele; Bernhart, Gérard; Cutard, Thierry; Peraudeau, Gilles; Balat-Pichelin, Marianne
2014-06-01
This research is part of the PERSEUS project, a space program concerning hybrid propulsion and supported by CNES. The main goal of this study is to characterise silicon carbide based micro-concrete with a maximum aggregates size of 800 μm, in a hybrid propulsion environment. The nozzle throat has to resist to a highly oxidising polyethylene (PE)/N2O hybrid environment, under temperatures ranging up to 2980 K. The study is divided into two main parts: the first one deals with the thermo-mechanical characterisation of the material up to 1500 K and the second one with an investigation on the oxidation behaviour in a standard atmosphere, under a solar flux up to 13.5 MW/m2. Young's modulus was determined by resonant frequency method: results show an increase with the stabilisation temperature. Four point bending tests have shown a rupture tensile strength increasing with stabilisation temperature, up to 1473 K. Sintering and densification processes are primary causes of this phenomenon. Visco-plastic behaviour appears at 1373 K, due to the formation of liquid phases in cement ternary system. High-temperature oxidation in ambient air was carried out at PROMES-CNRS laboratory, on a 2 kW solar furnace, with a concentration factor of 15,000. A maximum 13.5 MW/m2 incident solar flux and a 7-90 s exposure times have been chosen. Optical microscopy, SEM, EDS analyses were used to determine the microstructure evolution and the mass loss kinetics. During these tests, silicon carbide undergoes active oxidation with production of SiO and CO smokes and ablation. A linear relation between mass loss and time is found. Oxidation tests performed at 13.5 MW/m2 solar flux have shown a mass loss of 10 mg/cm2 after 15 s. After 90 s, the mass loss reaches 60 mg/cm2. Surface temperature measurement is a main point in this study, because of necessity of a thermo-mechanical-ablative model for the material. Smokes appear at around 5.9 MW/m2, leading to the impossibility of useful temperature measurements by optical pyrometry. Micro-concrete is really interesting for the nozzle realisation, thanks to its workability, and its thermo-mechanical properties. After 30 s, mass loss in micro-concrete is one half of pure α-SiC. This result is really interesting to study SiC-based concretes in oxidising environments, instead of sintered α-SiC.
Vector MO magnetometry for mapping microwave currents
NASA Astrophysics Data System (ADS)
Višňovský, Š.; Lišková-Jakubisová, E.; Harward, I.; Celinski, Z.
2018-05-01
Magneto-optic (MO) effects in magnetic multilayers (MML) can be employed in non-invasive 2D mapping of microwave (mw) radiation on the surface of semiconductor chips. A typical sensor configuration consists of Fe nanolayers sandwiched with dielectrics on a thin Si substrate transparent to mw radiation. To extend the observation bandwidth, Δf, up to 100 GHz range the sensor works at ferromagnetic resonance (FMR) frequency in applied magnetic flux density, Bappl. The mw currents excite the precession of magnetization, M, in magnetic nanolayers proportional to their amplitude. The MO component reflected on the sensor surface is proportional to the amplitude of M component, M⊥. The laser source operates at the wavelength of 410 nm. Its plane of incidence is oriented perpendicular to the M⊥ plane. M⊥ oscillates between polar and transverse configurations. A substantial improvement of MO figure of merit takes place in aperiodic MML. More favorable Δf vs. Bappl dependence and MO response can potentially be achieved in MML imbedding hexagonal ferrite or Co nanolayers with in-plane magnetic anisotropy.
CHARACTERISTIC QUALITIES OF SOME ATOMIC POWER STATIONS (in Hungarian)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ligeti, G.
1962-04-01
Mostly as the result of economic factors, the current rate of construction of public atomic power stations has slowed down. The use of atomic energy is considered economical only in a few special cases, such as ship propulsion or supplying power to remote regions. For this reason, many reactors were designed especially for the construction of such midget'' power stations, operating at power levels ranging from 10 to 70 Mw. Technical details are given of such already-built or proposed systems, including the following: pressurized- water reactors such as the Babcock and Wilcox 60-Mw reactor, using 2.4% U/sup 235/ fuel; themore » Humphrey-Glasow Company's 20 Mw reactor; the gascooled system of the de Havilland Company; the organicmoderated reactor of the English Electric Company; the organic-moderated system of the Hawker-Siddeley Nuclear Power Company; the boiling-water reactor of the Mitchell Engineering Company and the steam-cooled, heavy-water reactor of the Rolls-Royce & Vickers Company. (TTT)« less
NASA Astrophysics Data System (ADS)
Shani-Kadmiel, Shahar; Assink, Jelle D.; Smets, Pieter S. M.; Evers, Läslo G.
2018-01-01
In this study we analyze infrasound signals from three earthquakes in central Italy. The Mw 6.0 Amatrice, Mw 5.9 Visso, and Mw 6.5 Norcia earthquakes generated significant epicentral ground motions that couple to the atmosphere and produce infrasonic waves. Epicentral seismic and infrasonic signals are detected at I26DE; however, a third type of signal, which arrives after the seismic wave train and before the epicentral infrasound signal, is also detected. This peculiar signal propagates across the array at acoustic wave speeds, but the celerity associated with it is 3 times the speed of sound. Atmosphere-independent backprojections and full 3-D ray tracing using atmospheric conditions of the European Centre for Medium-Range Weather Forecasts are used to demonstrate that this apparently fast-arriving infrasound signal originates from ground motions more than 400 km away from the epicenter. The location of the secondary infrasound patch coincides with the closest bounce point to I26DE as depicted by ray tracing backprojections.
Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids
Fan, Fei; Wang, Weiyu; Holt, Adam P.; ...
2016-06-07
The unique properties of ionic liquids (ILs) have made them promising candidates for electrochemical applications. Polymerization of the corresponding ILs results in a new class of materials called polymerized ionic liquids (PolyILs). Though PolyILs offer the possibility to combine the high conductivity of ILs and the high mechanical strength of polymers, their conductivities are typically much lower than that of the corresponding small molecule ILs. In this study, seven PolyILs were synthesized having degrees of polymerization ranging from 1 to 333, corresponding to molecular weights (MW) from 482 to 160 400 g/mol. Depolarized dynamic light scattering, broadband dielectric spectroscopy, rheology,more » and differential scanning calorimetry were employed to systematically study the influence of MW on the mechanism of ionic transport and segmental dynamics in these materials. Finally, the modified Walden plot analysis reveals that the ion conductivity transforms from being closely coupled with structural relaxation to being strongly decoupled from it as MW increases.« less
Duputel, Zacharie; Jiang, Junle; Jolivet, Romain; Simons, Mark; Rivera, Luis; Ampuero, Jean-Paul; Riel, Bryan; Owen, Susan E; Moore, Angelyn W; Samsonov, Sergey V; Ortega Culaciati, Francisco; Minson, Sarah E.
2016-01-01
The subduction zone in northern Chile is a well-identified seismic gap that last ruptured in 1877. On 1 April 2014, this region was struck by a large earthquake following a two week long series of foreshocks. This study combines a wide range of observations, including geodetic, tsunami, and seismic data, to produce a reliable kinematic slip model of the Mw=8.1 main shock and a static slip model of the Mw=7.7 aftershock. We use a novel Bayesian modeling approach that accounts for uncertainty in the Green's functions, both static and dynamic, while avoiding nonphysical regularization. The results reveal a sharp slip zone, more compact than previously thought, located downdip of the foreshock sequence and updip of high-frequency sources inferred by back-projection analysis. Both the main shock and the Mw=7.7 aftershock did not rupture to the trench and left most of the seismic gap unbroken, leaving the possibility of a future large earthquake in the region.
Effect of Molecular Weight on the Ion Transport Mechanism in Polymerized Ionic Liquids
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fan, Fei; Wang, Weiyu; Holt, Adam P.
The unique properties of ionic liquids (ILs) have made them promising candidates for electrochemical applications. Polymerization of the corresponding ILs results in a new class of materials called polymerized ionic liquids (PolyILs). Though PolyILs offer the possibility to combine the high conductivity of ILs and the high mechanical strength of polymers, their conductivities are typically much lower than that of the corresponding small molecule ILs. In this study, seven PolyILs were synthesized having degrees of polymerization ranging from 1 to 333, corresponding to molecular weights (MW) from 482 to 160 400 g/mol. Depolarized dynamic light scattering, broadband dielectric spectroscopy, rheology,more » and differential scanning calorimetry were employed to systematically study the influence of MW on the mechanism of ionic transport and segmental dynamics in these materials. Finally, the modified Walden plot analysis reveals that the ion conductivity transforms from being closely coupled with structural relaxation to being strongly decoupled from it as MW increases.« less
Broadly tunable terahertz generation in mid-infrared quantum cascade lasers.
Vijayraghavan, Karun; Jiang, Yifan; Jang, Min; Jiang, Aiting; Choutagunta, Karthik; Vizbaras, Augustinas; Demmerle, Frederic; Boehm, Gerhard; Amann, Markus C; Belkin, Mikhail A
2013-01-01
Room temperature, broadly tunable, electrically pumped semiconductor sources in the terahertz spectral range, similar in operation simplicity to diode lasers, are highly desired for applications. An emerging technology in this area are sources based on intracavity difference-frequency generation in dual-wavelength mid-infrared quantum cascade lasers. Here we report terahertz quantum cascade laser sources based on an optimized non-collinear Cherenkov difference-frequency generation scheme that demonstrates dramatic improvements in performance. Devices emitting at 4 THz display a mid-infrared-to-terahertz conversion efficiency in excess of 0.6 mW W(-2) and provide nearly 0.12 mW of peak power output. Devices emitting at 2 and 3 THz fabricated on the same chip display 0.09 and 0.4 mW W(-2) conversion efficiencies at room temperature, respectively. High terahertz-generation efficiency and relaxed phase-matching conditions offered by the Cherenkov scheme allowed us to demonstrate, for the first time, an external-cavity terahertz quantum cascade laser source tunable between 1.70 and 5.25 THz.
Overview of ASDEX Upgrade results
NASA Astrophysics Data System (ADS)
Stroth, U.; Adamek, J.; Aho-Mantila, L.; Äkäslompolo, S.; Amdor, C.; Angioni, C.; Balden, M.; Bardin, S.; Barrera Orte, L.; Behler, K.; Belonohy, E.; Bergmann, A.; Bernert, M.; Bilato, R.; Birkenmeier, G.; Bobkov, V.; Boom, J.; Bottereau, C.; Bottino, A.; Braun, F.; Brezinsek, S.; Brochard, T.; Brüdgam, M.; Buhler, A.; Burckhart, A.; Casson, F. J.; Chankin, A.; Chapman, I.; Clairet, F.; Classen, I. G. J.; Coenen, J. W.; Conway, G. D.; Coster, D. P.; Curran, D.; da Silva, F.; de Marné, P.; D'Inca, R.; Douai, D.; Drube, R.; Dunne, M.; Dux, R.; Eich, T.; Eixenberger, H.; Endstrasser, N.; Engelhardt, K.; Esposito, B.; Fable, E.; Fischer, R.; Fünfgelder, H.; Fuchs, J. C.; Gál, K.; García Muñoz, M.; Geiger, B.; Giannone, L.; Görler, T.; da Graca, S.; Greuner, H.; Gruber, O.; Gude, A.; Guimarais, L.; Günter, S.; Haas, G.; Hakola, A. H.; Hangan, D.; Happel, T.; Härtl, T.; Hauff, T.; Heinemann, B.; Herrmann, A.; Hobirk, J.; Höhnle, H.; Hölzl, M.; Hopf, C.; Houben, A.; Igochine, V.; Ionita, C.; Janzer, A.; Jenko, F.; Kantor, M.; Käsemann, C.-P.; Kallenbach, A.; Kálvin, S.; Kantor, M.; Kappatou, A.; Kardaun, O.; Kasparek, W.; Kaufmann, M.; Kirk, A.; Klingshirn, H.-J.; Kocan, M.; Kocsis, G.; Konz, C.; Koslowski, R.; Krieger, K.; Kubic, M.; Kurki-Suonio, T.; Kurzan, B.; Lackner, K.; Lang, P. T.; Lauber, P.; Laux, M.; Lazaros, A.; Leipold, F.; Leuterer, F.; Lindig, S.; Lisgo, S.; Lohs, A.; Lunt, T.; Maier, H.; Makkonen, T.; Mank, K.; Manso, M.-E.; Maraschek, M.; Mayer, M.; McCarthy, P. J.; McDermott, R.; Mehlmann, F.; Meister, H.; Menchero, L.; Meo, F.; Merkel, P.; Merkel, R.; Mertens, V.; Merz, F.; Mlynek, A.; Monaco, F.; Müller, S.; Müller, H. W.; Münich, M.; Neu, G.; Neu, R.; Neuwirth, D.; Nocente, M.; Nold, B.; Noterdaeme, J.-M.; Pautasso, G.; Pereverzev, G.; Plöckl, B.; Podoba, Y.; Pompon, F.; Poli, E.; Polozhiy, K.; Potzel, S.; Püschel, M. J.; Pütterich, T.; Rathgeber, S. K.; Raupp, G.; Reich, M.; Reimold, F.; Ribeiro, T.; Riedl, R.; Rohde, V.; Rooij, G. v.; Roth, J.; Rott, M.; Ryter, F.; Salewski, M.; Santos, J.; Sauter, P.; Scarabosio, A.; Schall, G.; Schmid, K.; Schneider, P. A.; Schneider, W.; Schrittwieser, R.; Schubert, M.; Schweinzer, J.; Scott, B.; Sempf, M.; Sertoli, M.; Siccinio, M.; Sieglin, B.; Sigalov, A.; Silva, A.; Sommer, F.; Stäbler, A.; Stober, J.; Streibl, B.; Strumberger, E.; Sugiyama, K.; Suttrop, W.; Tala, T.; Tardini, G.; Teschke, M.; Tichmann, C.; Told, D.; Treutterer, W.; Tsalas, M.; Van Zeeland, M. A.; Varela, P.; Veres, G.; Vicente, J.; Vianello, N.; Vierle, T.; Viezzer, E.; Viola, B.; Vorpahl, C.; Wachowski, M.; Wagner, D.; Wauters, T.; Weller, A.; Wenninger, R.; Wieland, B.; Willensdorfer, M.; Wischmeier, M.; Wolfrum, E.; Würsching, E.; Yu, Q.; Zammuto, I.; Zasche, D.; Zehetbauer, T.; Zhang, Y.; Zilker, M.; Zohm, H.
2013-10-01
The medium size divertor tokamak ASDEX Upgrade (major and minor radii 1.65 m and 0.5 m, respectively, magnetic-field strength 2.5 T) possesses flexible shaping and versatile heating and current drive systems. Recently the technical capabilities were extended by increasing the electron cyclotron resonance heating (ECRH) power, by installing 2 × 8 internal magnetic perturbation coils, and by improving the ion cyclotron range of frequency compatibility with the tungsten wall. With the perturbation coils, reliable suppression of large type-I edge localized modes (ELMs) could be demonstrated in a wide operational window, which opens up above a critical plasma pedestal density. The pellet fuelling efficiency was observed to increase which gives access to H-mode discharges with peaked density profiles at line densities clearly exceeding the empirical Greenwald limit. Owing to the increased ECRH power of 4 MW, H-mode discharges could be studied in regimes with dominant electron heating and low plasma rotation velocities, i.e. under conditions particularly relevant for ITER. The ion-pressure gradient and the neoclassical radial electric field emerge as key parameters for the transition. Using the total simultaneously available heating power of 23 MW, high performance discharges have been carried out where feed-back controlled radiative cooling in the core and the divertor allowed the divertor peak power loads to be maintained below 5 MW m-2. Under attached divertor conditions, a multi-device scaling expression for the power-decay length was obtained which is independent of major radius and decreases with magnetic field resulting in a decay length of 1 mm for ITER. At higher densities and under partially detached conditions, however, a broadening of the decay length is observed. In discharges with density ramps up to the density limit, the divertor plasma shows a complex behaviour with a localized high-density region in the inner divertor before the outer divertor detaches. Turbulent transport is studied in the core and the scrape-off layer (SOL). Discharges over a wide parameter range exhibit a close link between core momentum and density transport. Consistent with gyro-kinetic calculations, the density gradient at half plasma radius determines the momentum transport through residual stress and thus the central toroidal rotation. In the SOL a close comparison of probe data with a gyro-fluid code showed excellent agreement and points to the dominance of drift waves. Intermittent structures from ELMs and from turbulence are shown to have high ion temperatures even at large distances outside the separatrix.
NASA Astrophysics Data System (ADS)
Xu, Wenbin
2017-05-01
Subduction earthquakes have been widely studied in the Chilean subduction zone, but earthquakes occurring in its southern part have attracted less research interest primarily due to its lower rate of seismic activity. Here I use Sentinel-1 interferometric synthetic aperture radar (InSAR) data and range offset measurements to generate coseismic crustal deformation maps of the 2016 Mw 7.5 Chiloé earthquake in southern Chile. I find a concentrated crustal deformation with ground displacement of approximately 50 cm in the southern part of the Chiloé island. The best fitting fault model shows a pure thrust-fault motion on a shallow dipping plane orienting 4° NNE. The InSAR-determined moment is 2.4 × 1020 Nm with a shear modulus of 30 GPa, equivalent to Mw 7.56, which is slightly lower than the seismic moment. The model shows that the slip did not reach the trench, and it reruptured part of the fault that ruptured in the 1960 Mw 9.5 earthquake. The 2016 event has only released a small portion of the accumulated strain energy on the 1960 rupture zone, suggesting that the seismic hazard of future great earthquakes in southern Chile is high.
NASA Astrophysics Data System (ADS)
Zhang, Huaijin; Meng, Xianlin; Wang, Changqing; Wang, Pu; Zhu, Li; Liu, Xuesong; Dong, Chunming; Yang, Yuyong; Cheng, Ruiping; Dawes, Judith; Piper, Jim; Zhang, Shaojun; Sun, Lianke
2000-09-01
In this paper, Er : Ca 4YO(BO 3) 3 (Er : YCOB) and Er : Yb : Ca 4YO(BO 3) 3 (Er : Yb : YCOB) crystals with large size and excellent quality have been grown by the Czochralski method. The absorption and emission spectra of Er : YCOB and Er : Yb : YCOB crystals have been measured; the emission spectrum of Er : Yb : YCOB crystal shows that the strongest emission peak is located at 1537 nm. An output power of about 2 mW at the wavelength of 1553 nm has been obtained under the pumping power of a fiber-coupled laser diode (LD) of 1600 mW at 976 nm, using a Y direction cut 2.5 mm thick Er : Yb : YCOB crystal sample.
Thermal power systems small power systems applications project. Volume 2: Detailed report
NASA Technical Reports Server (NTRS)
Marriott, A. T.
1979-01-01
Small power system technology as applied to power plants up to 10 MW in size was considered. Markets for small power systems were characterized and cost goals were established for the project. Candidate power plant system design concepts were selected for evaluation and preliminary performance and cost assessments were made. Breakeven capital costs were determined for leading contenders among the candidate systems. The potential use of small power systems in providing part of the demand for pumping power by the extensive aqueduct system of California, was studied. Criteria and methodologies were developed for the ranking of candidate power plant system design concepts. Experimental power plant concepts of 1 MW rating were studied to define a power plant configuration for subsequent detail design construction, testing and evaluation. Site selection criteria and ground rules were developed.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jeong, Junseok; Choi, Ji Eun; Hong, Young Joon, E-mail: yjhong@sejong.ac.kr
Position-controlled n-ZnO microwire (MW) and nanowire-bundle (NW-B) arrays were fabricated using hydrothermal growth of ZnO on a patterned p-GaN film. Both the wire/film p–n heterojunctions showed electrical rectification features at reverse-bias (rb) voltages, analogous to backward diodes. Dichromatic electroluminescence (EL) emissions with 445- and 560-nm-wavelength peaks displayed whitish-blue and greenish-yellow light from MW- and NW-B-based heterojunctions at rb voltages, respectively. The different dichromatic EL emission colors were studied based on photoluminescence spectra and the dichromatic EL peak intensity ratios as a function of the rb voltage. The different EL colors are discussed with respect to depletion thickness and electron tunnelingmore » probability determined by wire/film junction geometry and size.« less
NASA Astrophysics Data System (ADS)
Jeong, Junseok; Choi, Ji Eun; Kim, Yong-Jin; Hwang, Sunyong; Kim, Sung Kyu; Kim, Jong Kyu; Jeong, Hu Young; Hong, Young Joon
2016-09-01
Position-controlled n-ZnO microwire (MW) and nanowire-bundle (NW-B) arrays were fabricated using hydrothermal growth of ZnO on a patterned p-GaN film. Both the wire/film p-n heterojunctions showed electrical rectification features at reverse-bias (rb) voltages, analogous to backward diodes. Dichromatic electroluminescence (EL) emissions with 445- and 560-nm-wavelength peaks displayed whitish-blue and greenish-yellow light from MW- and NW-B-based heterojunctions at rb voltages, respectively. The different dichromatic EL emission colors were studied based on photoluminescence spectra and the dichromatic EL peak intensity ratios as a function of the rb voltage. The different EL colors are discussed with respect to depletion thickness and electron tunneling probability determined by wire/film junction geometry and size.
Nuclear powered Mars cargo transport mission utilizing advanced ion propulsion
NASA Technical Reports Server (NTRS)
Galecki, Diane L.; Patterson, Michael J.
1987-01-01
Nuclear-powered ion propulsion technology was combined with detailed trajectory analysis to determine propulsion system and trajectory options for an unmanned cargo mission to Mars in support of manned Mars missions. A total of 96 mission scenarios were identified by combining two power levels, two propellants, four values of specific impulse per propellant, three starting altitudes, and two starting velocities. Sixty of these scenarios were selected for a detailed trajectory analysis; a complete propulsion system study was then conducted for 20 of these trajectories. Trip times ranged from 344 days for a xenon propulsion system operating at 300 kW total power and starting from lunar orbit with escape velocity, to 770 days for an argon propulsion system operating at 300 kW total power and starting from nuclear start orbit with circular velocity. Trip times for the 3 MW cases studied ranged from 356 to 413 days. Payload masses ranged from 5700 to 12,300 kg for the 300 kW power level, and from 72,200 to 81,500 kg for the 3 MW power level.
Source Mechanisms of Destructive Tsunamigenic Earthquakes occurred along the Major Subduction Zones
NASA Astrophysics Data System (ADS)
Yolsal-Çevikbilen, Seda; Taymaz, Tuncay; Ulutaş, Ergin
2016-04-01
Subduction zones, where an oceanic plate is subducted down into the mantle by tectonic forces, are potential tsunami locations. Many big, destructive and tsunamigenic earthquakes (Mw > 7.5) and high amplitude tsunami waves are observed along the major subduction zones particularly near Indonesia, Japan, Kuril and Aleutan Islands, Gulf of Alaska, Southern America. Not all earthquakes are tsunamigenic; in order to generate a tsunami, the earthquake must occur under or near the ocean, be large, and create significant vertical movements of the seafloor. It is also known that tsunamigenic earthquakes release their energy over a couple of minutes, have long source time functions and slow-smooth ruptures. In this study, we performed point-source inversions by using teleseismic long-period P- and SH- and broad-band P-waveforms recorded by the Federation of Digital Seismograph Networks (FDSN) and the Global Digital Seismograph Network (GDSN) stations. We obtained source mechanism parameters and finite-fault slip distributions of recent destructive ten earthquakes (Mw ≥ 7.5) by comparing the shapes and amplitudes of long period P- and SH-waveforms, recorded in the distance range of 30° - 90°, with synthetic waveforms. We further obtained finite-fault rupture histories of those earthquakes to determine the faulting area (fault length and width), maximum displacement, rupture duration and stress drop. We applied a new back-projection method that uses teleseismic P-waveforms to integrate the direct P-phase with reflected phases from structural discontinuities near the source, and customized it to estimate the spatio-temporal distribution of the seismic energy release of earthquakes. Inversion results exhibit that recent tsunamigenic earthquakes show dominantly thrust faulting mechanisms with small amount of strike-slip components. Their focal depths are also relatively shallow (h < 40 km). As an example, the September 16, 2015 Illapel (Chile) earthquake (Mw: 8.3; h: 26 km) reflects the major characteristics of the Peru-Chile subduction zone between the Nazca and South America Plates. The size, location, depth and focal mechanism of this earthquake are consistent with its occurrence on the megathrust interface in this region. This study is supported by the Scientific and Technological Research Council of Turkey (TUBITAK, Project No: CAYDAG - 114Y066).
NASA Astrophysics Data System (ADS)
Dahm, Torsten; Cesca, Simone; Hainzl, Sebastian; Braun, Thomas; Krüger, Frank
2015-04-01
Earthquakes occurring close to hydrocarbon fields under production are often under critical view of being induced or triggered. However, clear and testable rules to discriminate the different events have rarely been developed and tested. The unresolved scientific problem may lead to lengthy public disputes with unpredictable impact on the local acceptance of the exploitation and field operations. We propose a quantitative approach to discriminate induced, triggered, and natural earthquakes, which is based on testable input parameters. Maxima of occurrence probabilities are compared for the cases under question, and a single probability of being triggered or induced is reported. The uncertainties of earthquake location and other input parameters are considered in terms of the integration over probability density functions. The probability that events have been human triggered/induced is derived from the modeling of Coulomb stress changes and a rate and state-dependent seismicity model. In our case a 3-D boundary element method has been adapted for the nuclei of strain approach to estimate the stress changes outside the reservoir, which are related to pore pressure changes in the field formation. The predicted rate of natural earthquakes is either derived from the background seismicity or, in case of rare events, from an estimate of the tectonic stress rate. Instrumentally derived seismological information on the event location, source mechanism, and the size of the rupture plane is of advantage for the method. If the rupture plane has been estimated, the discrimination between induced or only triggered events is theoretically possible if probability functions are convolved with a rupture fault filter. We apply the approach to three recent main shock events: (1) the Mw 4.3 Ekofisk 2001, North Sea, earthquake close to the Ekofisk oil field; (2) the Mw 4.4 Rotenburg 2004, Northern Germany, earthquake in the vicinity of the Söhlingen gas field; and (3) the Mw 6.1 Emilia 2012, Northern Italy, earthquake in the vicinity of a hydrocarbon reservoir. The three test cases cover the complete range of possible causes: clearly "human induced," "not even human triggered," and a third case in between both extremes.
NASA Astrophysics Data System (ADS)
Yamada, T.; Matsuoka, H.; Sun, J.; Yoshikawa, S.; Tsuji, H.; Hiraishi, A.
2013-04-01
The large amount of waste that is discharged along with the diffusion of poly(L-lactic acid) (PLLA) articles in use is persistent concern. Previously, we studied solid-phase denitrification (SPD) processes using PLLA to establish an effective re-use of PLLA waste. We found that PLLA with a weight-average molecular weight (Mw) of approximately 10,000 was suitable for SPD processes; however, the recycling of PLLA waste consumes a high energy. A new PLLA plastic including 5% poly(ethylene oxalate) (PEOxPLLA) as a blend material has attracted attention because recycling of PEOxPLLA consumes less electricity than that of PLLA. In this study, our main objectives were to evaluate whether PEOxPLLA can be used for SPD processes by changing its Mw and to investigate the bioavailability for denitrification of hydrolysates released from PEOxPLLA. The predicted hydrolysates, including oxalic acid, ethylene glycol, and lactate, are abiotically released, leading to different biological nitrate removal rates. Consequently, the nitrate removal rate of PEOxPLLA ranged from 0.9-4.1 mg-NO3--N·g-MLSS·h-1 by changing the Mw in the range of 8,500-238,000. In culture-dependent approaches, denitrifying bacteria using each substrate as an electron donor are found in activated sludge, suggesting that all hydrolysates functioned in the SPD processes using PEOxPLLA.
‘GREENER’ CHEMICAL SYNTHESES USING MICROWAVE IRRADIATION (PRAGUE)
'Greener' solvent-free protocols involve microwave (MW) exposure of neat reactants catalyzed by the surfaces of recyclable mineral supports such as alumina, silica and clay which are applicable to a wide range of cleavage, condensation, cyclization, oxidation and reduction reacti...
ORGANIC SYNTHESES UNDER NON-TRADITIONAL CONDITIONS
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
'GREENER' CHEMICAL SYNTHESIS USING MICROWAVE IRRADIATION
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
A 16K-bit static IIL RAM with 25-ns access time
NASA Astrophysics Data System (ADS)
Inabe, Y.; Hayashi, T.; Kawarada, K.; Miwa, H.; Ogiue, K.
1982-04-01
A 16,384 x 1-bit RAM with 25-ns access time, 600-mW power dissipation, and 33 sq mm chip size has been developed. Excellent speed-power performance with high packing density has been achieved by an oxide isolation technology in conjunction with novel ECL circuit techniques and IIL flip-flop memory cells, 980 sq microns (35 x 28 microns) in cell size. Development results have shown that IIL flip-flop memory cell is a trump card for assuring achievement of a high-performance large-capacity bipolar RAM, in the above 16K-bit/chip area.
A geodetic matched filter search for slow slip with application to the Mexico subduction zone
NASA Astrophysics Data System (ADS)
Rousset, B.; Campillo, M.; Lasserre, C.; Frank, W. B.; Cotte, N.; Walpersdorf, A.; Socquet, A.; Kostoglodov, V.
2017-12-01
Since the discovery of slow slip events, many methods have been successfully applied to model obvious transient events in geodetic time series, such as the widely used network strain filter. Independent seismological observations of tremors or low-frequency earthquakes and repeating earthquakes provide evidence of low-amplitude slow deformation but do not always coincide with clear occurrences of transient signals in geodetic time series. Here we aim to extract the signal corresponding to slow slips hidden in the noise of GPS time series, without using information from independent data sets. We first build a library of synthetic slow slip event templates by assembling a source function with Green's functions for a discretized fault. We then correlate the templates with postprocessed GPS time series. Once the events have been detected in time, we estimate their duration T and magnitude Mw by modeling a weighted stack of GPS time series. An analysis of synthetic time series shows that this method is able to resolve the correct timing, location, T, and Mw of events larger than Mw 6 in the context of the Mexico subduction zone. Applied on a real data set of 29 GPS time series in the Guerrero area from 2005 to 2014, this technique allows us to detect 28 transient events from Mw 6.3 to 7.2 with durations that range from 3 to 39 days. These events have a dominant recurrence time of 40 days and are mainly located at the downdip edges of the Mw>7.5 slow slip events.
A geodetic matched-filter search for slow slip with application to the Mexico subduction zone
NASA Astrophysics Data System (ADS)
Rousset, B.; Campillo, M.; Lasserre, C.; Frank, W.; Cotte, N.; Walpersdorf, A.; Socquet, A.; Kostoglodov, V.
2017-12-01
Since the discovery of slow slip events, many methods have been successfully applied to model obvious transient events in geodetic time series, such as the widely used network strain filter. Independent seismological observations of tremors or low frequency earthquakes and repeating earthquakes provide evidence of low amplitude slow deformation but do not always coincide with clear occurrences of transient signals in geodetic time series. Here, we aim to extract the signal corresponding to slow slips hidden in the noise of GPS time series, without using information from independent datasets. We first build a library of synthetic slow slip event templates by assembling a source function with Green's functions for a discretized fault. We then correlate the templates with post-processed GPS time series. Once the events have been detected in time, we estimate their duration T and magnitude Mw by modelling a weighted stack of GPS time series. An analysis of synthetic time series shows that this method is able to resolve the correct timing, location, T and Mw of events larger than Mw 6.0 in the context of the Mexico subduction zone. Applied on a real data set of 29 GPS time series in the Guerrero area from 2005 to 2014, this technique allows us to detect 28 transient events from Mw 6.3 to 7.2 with durations that range from 3 to 39 days. These events have a dominant recurrence time of 40 days and are mainly located at the down dip edges of the Mw > 7.5 SSEs.
Redefining the properties of an osmotic agent in an intestinal-specific preservation solution
Schlachter, Kimberly; Kokotilo, Matthew S; Carter, Jodi; Thiesen, Aducio; Ochs, Angela; Khadaroo, Rachel G; Churchill, Thomas A
2010-01-01
AIM: To investigate the effects of dextrans of various molecular weights (Mw) during a 12 h cold storage time-course on energetics, histology and mucosal infiltration of fluorescein isothiocyanate (FITC)-dextran. METHODS: Rodent intestines were isolated and received a standard University of Wisconsin vascular flush followed by intraluminal administration of a nutrient-rich preservation solution containing dextrans of varying Mw: Group D1, 73 kdal; Group D2, 276 kdal; Group D3, 534 kdal; Group D4, 1185 kdal; Group D5, 2400 kdal. RESULTS: Using FITC-labeled dextrans, fluorescent micrographs demonstrated varying degrees of mucosal infiltration; lower Mw (groups D1-D3: 73-534 kdal) dextrans penetrated the mucosa as early as 2 h, whereas the largest dextran (D5: 2400 kdal) remained captive within the lumen and exhibited no permeability even after 12 h. After 12 h, median injury grades ranged from 6.5 to 7.5 in groups D1-D4 (73-1185 kdal) representing injury of the regenerative cryptal regions and submucosa; this was in contrast to group D5 (2400 kdal) which exhibited villus denudation (with intact crypts) corresponding to a median injury grade of 4 (P < 0.05). Analysis of tissue energetics reflected a strong positive correlation between Mw and adenosine triphosphate (r2 = 0.809), total adenylates (r2 = 0.865) and energy charge (r2 = 0.667). CONCLUSION: Our data indicate that dextrans of Mw > 2400 kdal act as true impermeant agents during 12 h ischemic storage when incorporated into an intraluminal preservation solution. PMID:21128319
Rapid degradation of azo dye Direct Black BN by magnetic MgFe2O4-SiC under microwave radiation
NASA Astrophysics Data System (ADS)
Gao, Jia; Yang, Shaogui; Li, Na; Meng, Lingjun; Wang, Fei; He, Huan; Sun, Cheng
2016-08-01
A novel microwave (MW) catalyst, MgFe2O4 loaded on SiC (MgFe2O4-SiC), was successfully synthesized by sol-gel method, and pure MgFe2O4 was used as reference. The MgFe2O4 and MgFe2O4-SiC catalysts were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), N2 adsorption analyzer (BET specific surface area), X-ray photoelectron spectroscopy (XPS). The electromagnetic parameters of the prepared catalysts were measured by vector network analyzer. The reflection loss (RL) based on the electromagnetic parameters calculated in Matlab showed MgFe2O4-SiC attained the maximum absorbing value of 13.32 dB at 2.57 GHz, which reached extremely high RL value at low frequency range, revealing the excellent MW absorption property of MgFe2O4-SiC. MW-induced degradation of Direct Black BN (DB BN) over as-synthesized MgFe2O4-SiC indicated that degradation efficiency of DB BN (20 mg L-1) in 5 min reached 96.5%, the corresponding TOC removal was 65%, and the toxicity of DB BN after degradation by MgFe2O4-SiC obviously decreased. The good stability and applicability of MgFe2O4-SiC on the degradation process were also discovered. Moreover, the ionic chromatogram during degradation of DB BN demonstrated that the C-S, C-N and azo bonds in the DB BN molecule were destroyed gradually. MW-induced rad OH and holes could be responsible for the efficient removal involved in the system. These findings make MgFe2O4-SiC become an excellent MW absorbent as well as an effective MW catalyst with rapid degradation of DB BN. Therefore, it may be promising for MgFe2O4-SiC under MW radiation to deal with various dyestuffs and other toxic organic pollutants.
Concentrating Solar Power Projects in China | Concentrating Solar Power |
Delingha 50MW Thermal Oil Parabolic Trough project Gansu Akesai 50MW Molten Salt Trough project Golden Tower 100MW Molten Salt project Golmud Gulang 100MW Thermal Oil Parabolic Trough project Hami 50 MW CSP Yumen 50MW Thermal Oil Trough project Shangyi 50MW DSG Tower CSP project SunCan Dunhuang 10 MW Phase I
NASA Astrophysics Data System (ADS)
Schwenk, Arne
2016-04-01
Since 1997 K.U.M. GmbH designs and manufactures Ocean Bottom Seismometer. During the last three years we designed a new instrument which is presented here. Higher resolution, higher accuracy and less power consumption led to an unique instrument, the worlds smallest broadband longterm OBS. Key data are: 32 bit, 143dB, 300mW, 120 sec, 200kg deployment weight, size of half a palette.
Hypocenter relocation along the Sunda arc in Indonesia, using a 3D seismic velocity model
Nugraha, Andri Dian; Shiddiqi, Hasbi A.; Widiyantoro, Sri; Thurber, Clifford H.; Pesicek, Jeremy D.; Zhang, Haijiang; Wiyono, Samsul H.; Ramadhan, Mohamad; Wandano,; Irsyam, Mahsyur
2018-01-01
The tectonics of the Sunda arc region is characterized by the junction of the Eurasian and Indo‐Australian tectonic plates, causing complex dynamics to take place. High‐seismicity rates in the Indonesian region occur due to the interaction between these tectonic plates. The availability of a denser network of seismometers after the earthquakes of Mw">Mw 9.1 in 2004 and Mw">Mw 8.6 in 2005 supports various seismic studies, one of which regards the precise relocation of the hypocenters. In this study, hypocenter relocation was performed using a teleseismic double‐difference (DD) relocation method (teletomoDD) combining arrival times of P and S waves from stations at local, regional, and teleseismic distances. The catalog data were taken from the Agency of Meteorology, Climatology, and Geophysics (BMKG) of Indonesia, and the International Seismological Centre (ISC) for the time period of April 2009 to May 2015. The 3D seismic‐wave velocity model with a grid size 1°×1°">1°×1° was used in the travel‐time calculations. Relocation results show a reduction in travel‐time residuals compared with the initial locations. The relocation results better illuminate subducted slabs and active faults in the region such as the Mentawai back thrust and the outer rise in the subduction zone south of Java. Focal mechanisms from the Global Centroid Moment Tensor catalog are analyzed in conjunction with the relocation results, and our synthesis of the results provides further insight into seismogenesis in the region.
NASA Technical Reports Server (NTRS)
Chambon, Philippe; Zhang, Sara Q.; Hou, Arthur Y.; Zupanski, Milija; Cheung, Samson
2013-01-01
The forthcoming Global Precipitation Measurement (GPM) Mission will provide next generation precipitation observations from a constellation of satellites. Since precipitation by nature has large variability and low predictability at cloud-resolving scales, the impact of precipitation data on the skills of mesoscale numerical weather prediction (NWP) is largely affected by the characterization of background and observation errors and the representation of nonlinear cloud/precipitation physics in an NWP data assimilation system. We present a data impact study on the assimilation of precipitation-affected microwave (MW) radiances from a pre-GPM satellite constellation using the Goddard WRF Ensemble Data Assimilation System (Goddard WRF-EDAS). A series of assimilation experiments are carried out in a Weather Research Forecast (WRF) model domain of 9 km resolution in western Europe. Sensitivities to observation error specifications, background error covariance estimated from ensemble forecasts with different ensemble sizes, and MW channel selections are examined through single-observation assimilation experiments. An empirical bias correction for precipitation-affected MW radiances is developed based on the statistics of radiance innovations in rainy areas. The data impact is assessed by full data assimilation cycling experiments for a storm event that occurred in France in September 2010. Results show that the assimilation of MW precipitation observations from a satellite constellation mimicking GPM has a positive impact on the accumulated rain forecasts verified with surface radar rain estimates. The case-study on a convective storm also reveals that the accuracy of ensemble-based background error covariance is limited by sampling errors and model errors such as precipitation displacement and unresolved convective scale instability.
NASA Astrophysics Data System (ADS)
Elnoby, Rasha M.; Mourad, M. Hussein; Elnaby, Salah L. Hassab; Abou Kana, Maram T. H.
2018-05-01
Solar based cells coated by nanoparticles (NPs) acknowledge potential utilizing as a part of photovoltaic innovation. The acquired silicon solar cells (Si-SCs) coated with different sizes of silver nanoparticles (Ag NPs) as well as uncoated were fabricated in our lab. The sizes and optical properties of prepared NPs were characterized by spectroscopic techniques and Mie theory respectively. The reflectivity of Si-SCs showed reduction of this property as the size of NPs increased. Electrical properties as open circuit current, fill factor and output power density were assessed and discussed depending on point of view of Mie theory for the optical properties of NPs. Also, photostabilities of SCs were assessed using diode laser of wavelength 450 nm and power 300 mW. Coated SCs with the largest Ag NPs size showed the highest Photostability due to its highest scattering efficiency according to Mie theory concept.
Illuminating the star clusters and satellite galaxies with multi-scale baryonic simulations
NASA Astrophysics Data System (ADS)
Maji, Moupiya; Zhu, Qirong; Li, Yuexing; Marinacci, Federico; Charlton, Jane; Hernquist, Lars; Knebe, Alexander
2018-01-01
Over the past decade, advances in computational architecture have made it possible for the first time to investigate some of the fundamental questions around the formation, evolution and assembly of the building blocks of the universe; star clusters and galaxies. In this talk, I will focus on two major questions: What is the origin of the observed universal lognormal mass function in globular clusters? What is the statistical distribution of the properties of satellite planes in a large sample of satellite systems?Observations of globular clusters show that they have universal lognormal mass functions with a characteristic peak at 2X105 MSun, although the origin of this peaked distribution is unclear. We investigate the formation of star clusters in interacting galaxies using baryonic simulations and found that massive clusters preferentially form in extremely high pressure gas clouds which reside in highly shocked regions produced by galaxy interactions. These massive clusters have quasi-lognormal initial mass functions with a peak around ~106MSun which may survive dynamical evolution and slowly evolve into the universal lognormal profiles observed today.The classical Milky Way (MW) satellites are observed to be distributed in a highly-flattened plane, called Disk of Satellites (DoS). However the significance, coherence and origin of DoS is highly debated. To understand this, we first analyze all MW satellites and find that a small sample size can artificially produce a highly anisotropic spatial distribution and a strong clustering of their angular momentum. Comparing a baryonic simulation of a MW-sized galaxy with its N-body counterpart we find that an anisotropic DoS can originate from baryonic processes. Furthermore, we explore the statistical distribution of DoS properties by analyzing 2591 satellite systems in the cosmological hydrodynamic simulation Illustris. We find that the DoS becomes more isotropic with increasing sample sizes and most (~90%) satellite systems have no clear coherent rotation. Their overall evolution indicate that the DoS may be part of large scale filamentary structure. Our results show that baryonic processes may be the key to solve many long standing theoretical problems.
On the efficiency of small air coil motors
NASA Astrophysics Data System (ADS)
Horowitz, P.
1981-05-01
The efficiency of two types of small ironless motors in the output range of 5 to 500 mW was investigated for use in driving a miniature roller pump for a portable infusion system. One motor has a continuous rotating coil (commutator motor) and one has an oscillating coil. In this case a ratchet and ratchet wheel is needed to generate a rotating motion (ratchet wheel motor). The electromechanical transducer and a mechanical transformation and support system are discussed as well as frictional losses. The influence of the size of the motor is discussed. An expression for the total efficiency is obtained which enables the calculation of the speed of rotation of a certain motor at maximum efficiency for a certain required output. This optimal speed of rotation is hardly influenced by the required speed of rotation at the output shaft of the driving. The transmission, if required, has only a small effect on the optimum speed of rotation of the motor.
Two Instruments for Measuring Distributions of Low-Energy Charged Particles in Space
NASA Technical Reports Server (NTRS)
Bader, Michel; Fryer, Thomas B.; Witteborn, Fred C.
1961-01-01
Current estimates indicate that the bulk of interplanetary gas consists of protons with energies between 0 and 20 kev and concentrations of 1 to 105 particles/cu cm. Methods and instrumentation for measuring the energy and density distribution of such a gas are considered from the standpoint of suitability for space vehicle payloads. It is concluded that electrostatic analysis of the energy distribution can provide sufficient information in initial experiments. Both magnetic and electrostatic analyzers should eventually be used. Several instruments designed and constructed at the Ames Research Center for space plasma measurements, and the methods of calibration and data reduction are described. In particular, the instrument designed for operation on solar cell power has the following characteristics: weight, 1.1 pounds; size, 2 by 3 by 4 inches; and power consumption, 145 mw. The instrument is designed to yield information on the concentration, energy distribution, and the anisotropy of ion trajectories in the 0.2 to 20 kev range.
Moon, Ji-Hong; Lee, Jeung-Woo; Lee, Uen-Do
2011-10-01
An economic analysis of biomass power generation was conducted. Two key technologies--direct combustion with a steam turbine and gasification with a syngas engine--were mainly examined. In view of the present domestic biomass infrastructure of Korea, a small and distributed power generation system ranging from 0.5 to 5 MW(e) was considered. It was found that gasification with a syngas engine becomes more economically feasible as the plant size decreases. Changes in the economic feasibilities with and without RPS or heat sales were also investigated. A sensitivity analysis of each system was conducted for representative parameters. Regarding the cost of electricity generation, electrical efficiency and fuel cost significantly affect both direct combustion and gasification systems. Regarding the internal rate of return (IRR), the heat sales price becomes important for obtaining a higher IRR, followed by power generation capacity and electrical efficiency. Copyright © 2011 Elsevier Ltd. All rights reserved.
Study of ceria-carbonate nanocomposite electrolytes for low-temperature solid oxide fuel cells.
Fan, L; Wang, C; Di, J; Chen, M; Zheng, J; Zhu, B
2012-06-01
Composite and nanocomposite samarium doped ceria-carbonates powders were prepared by solid-state reaction, citric acid-nitrate combustion and modified nanocomposite approaches and used as electrolytes for low temperature solid oxide fuel cells. X-ray Diffraction, Scanning Electron Microscope, low-temperature Nitrogen Adsorption/desorption Experiments, Electrochemical Impedance Spectroscopy and fuel cell performance test were employed in characterization of these materials. All powders are nano-size particles with slight aggregation and carbonates are amorphous in composites. Nanocomposite electrolyte exhibits much lower impedance resistance and higher ionic conductivity than those of the other electrolytes at lower temperature. Fuel cell using the electrolyte prepared by modified nanocomposite approach exhibits the best performance in the whole operation temperature range and achieves a maximum power density of 839 mW cm(-2) at 600 degrees C with H2 as fuel. The excellent physical and electrochemical performances of nanocomposite electrolyte make it a promising candidate for low-temperature solid oxide fuel cells.
Source analysis using regional empirical Green's functions: The 2008 Wells, Nevada, earthquake
Mendoza, C.; Hartzell, S.
2009-01-01
We invert three-component, regional broadband waveforms recorded for the 21 February 2008 Wells, Nevada, earthquake using a finite-fault methodology that prescribes subfault responses using eight MW∼4 aftershocks as empirical Green's functions (EGFs) distributed within a 20-km by 21.6-km fault area. The inversion identifies a seismic moment of 6.2 x 1024 dyne-cm (5.8 MW) with slip concentrated in a compact 6.5-km by 4-km region updip from the hypocenter. The peak slip within this localized area is 88 cm and the stress drop is 72 bars, which is higher than expected for Basin and Range normal faults in the western United States. The EGF approach yields excellent fits to the complex regional waveforms, accounting for strong variations in wave propagation and site effects. This suggests that the procedure is useful for studying moderate-size earthquakes with limited teleseismic or strong-motion data and for examining uncertainties in slip models obtained using theoretical Green's functions.
Performance calculations for 200-1000 MWe MHD/steam power plants
NASA Technical Reports Server (NTRS)
Staiger, P. J.
1981-01-01
The effects of MHD generator length, level of oxygen enrichment, and oxygen production power on the performance of MHD/steam power plants ranging from 200 to 1000 MW in electrical output are investigated. The plants considered use oxygen enriched combustion air preheated to 1100 F. Both plants in which the MHD generator is cooled with low temperature and pressure boiler feedwater and plants in which the generator is cooled with high temperature and pressure boiler feedwater are considered. For plants using low temperature boiler feedwater for generator cooling the maximum thermodynamic efficiency is obtained with shorter generators and a lower level of oxygen enrichment compared to plants using high temperature boiler feedwater for generator cooling. The generator length at which the maximum plant efficiency occurs increases with power plant size for plants with a generator cooled by low temperature feedwater. Also shown is the relationship of the magnet stored energy requirement of the generator length and the power plant performance. Possible cost/performance tradeoffs between magnet cost and plant performance are indicated.
AC Coupled Interconnect for Low Power Spaceborne Electronics
2012-01-18
Apad = 175x175µm2 (200µm pitch and 25µm spacing on package), CC,row,min = 500fF (from preliminary simulation with TRX in 0.13µm standard CMOS and 80cm...the TRX performance with state-of-the-art designs. It is demonstrated that the TRX , benefitting from the CT-FSE scheme combined with use of the...8.9Gb/s TX Power 5.2mW 6.5mW 7.6mW 4.9mW - 11.6mW RX Power 1.1mW 1.1mW 1.1mW 8mW 10.9mW 5.4mW TRX Total Area .007mm 2 .307mm 2 .054mm 2 .023mm 2
Low stress drops observed for aftershocks of the 2011 Mw 5.7 Prague, Oklahoma, earthquake
Sumy, Danielle F.; Neighbors, Corrie J.; Cochran, Elizabeth S.; Keranen, Katie M.
2017-01-01
In November 2011, three Mw ≥ 4.8 earthquakes and thousands of aftershocks occurred along the structurally complex Wilzetta fault system near Prague, Oklahoma. Previous studies suggest that wastewater injection induced a Mw 4.8 foreshock, which subsequently triggered a Mw 5.7 mainshock. We examine source properties of aftershocks with a standard Brune-type spectral model and jointly solve for seismic moment (M0), corner frequency (f0), and kappa (κ) with an iterative Gauss-Newton global downhill optimization method. We examine 934 earthquakes with initial moment magnitudes (Mw) between 0.33 and 4.99 based on the pseudospectral acceleration and recover reasonable M0, f0, and κ for 87 earthquakes with Mw 1.83–3.51 determined by spectral fit. We use M0 and f0 to estimate the Brune-type stress drop, assuming a circular fault and shear-wave velocity at the hypocentral depth of the event. Our observations suggest that stress drops range between 0.005 and 4.8 MPa with a median of 0.2 MPa (0.03–26.4 MPa with a median of 1.1 MPa for Madariaga-type), which is significantly lower than typical eastern United States intraplate events (>10 MPa). We find that stress drops correlate weakly with hypocentral depth and magnitude. Additionally, we find the stress drops increase with time after the mainshock, although temporal variation in stress drop is difficult to separate from spatial heterogeneity and changing event locations. The overall low median stress drop suggests that the fault segments may have been primed to fail as a result of high pore fluid pressures, likely related to nearby wastewater injection.
Regional Moment Tensor Analysis of Earthquakes in Iran for 2010 to 2017 Using In-Country Data
NASA Astrophysics Data System (ADS)
Graybeal, D.; Braunmiller, J.
2017-12-01
Located in the middle of the Arabia-Eurasia continental collision, Iran is one of the most tectonically diverse and seismically active countries in the world. Until recently, however, seismic source parameter studies had to rely on teleseismic data or on data from temporary local arrays, which limited the scope of investigations. Relatively new broadband seismic networks operated by the Iranian Institute of Engineering Seismology (IIEES) and the Iranian Seismological Center (IRSC) currently consist of more than 100 stations and allow, for the first time, routine three-component full-waveform regional moment tensor analysis of the numerous M≥4.0 earthquakes that occur throughout the country. We use openly available, in-country data and include data from nearby permanent broadband stations available through IRIS and EIDA to improve azimuthal coverage for events in border regions. For the period from 2010 to 2017, we have obtained about 500 moment tensors for earthquakes ranging from Mw=3.6 to 7.8. The resulting database provides a unique, detailed view of deformation styles and earthquake depths in Iran. Overall, we find mainly thrust and strike-slip mechanisms as expected considering the convergent tectonic setting. Our magnitudes (Mw) are slightly smaller than ML and mb but comparable to Mw as reported in global catalogs (USGS ANSS). Event depths average about 3 km shallower than in global catalogs and are well constrained considering the capability of regional waveforms to resolve earthquake depth. Our dataset also contains several large magnitude main shock-aftershock sequences from different tectonic provinces, including the 2012 Ahar-Varzeghan (Mw=6.4), 2013 Kaki (Mw=6.5), and 2014 Murmuri (Mw=6.2) earthquakes. The most significant result in terms of seismogenesis and seismic hazard is that the vast majority of earthquakes occur at shallow depth, not in deeper basement. Our findings indicate that more than 80% of crustal seismicity in Iran likely occurs at depths of 12 km or less.
The 2008 Mw 6.0 Wells, Nevada Earthquake Sequence
NASA Astrophysics Data System (ADS)
Smith, K.; Depolo, D.; Torrisi, J.; Edwards, N.; Biasi, G.; Slater, D.
2008-12-01
The Mw 6.0 February 21, 2008 (06:16 AM PDT) Wells, Nevada normal faulting earthquake occurred in Town Creek Flat about 8 km northeast of the small community of Wells. A preliminary set of about 1000 aftershock relocations clearly defines a 55-60 degree southeast dipping fault plane. The structure projects to the surface along the southern end of the Snake Range, although no surface offsets have been identified. The earthquake occurred east of the Ruby Mountains and Snake Range west dipping range front faults, possibly on a northern extension of an east dipping normal fault system on the eastern side of the East Humbolt Range. The depth of the mainshock is estimated to be 10.5 km with the aftershock sequence extending to about 15 km. Typical of moderate sized Basin and Range earthquakes, the early aftershock period included several earthquakes of M > 4 and these were felt strongly by the residents of Wells. From the preliminary relocations, the source radius of the mainshock is estimated to be about 4 km, resulting in an estimated displacement of 55 to 83 cm and static stress drop of 72 to 86 bars, depending on the seismic moment estimate used. Aftershock relocations suggest a radial rupture mechanism. Fortunately, the EarthScope USArray network was operating in Nevada at the time of the event and provided unique controls on the mainshock and early aftershock locations. The earthquake occurred in an area of relatively low seismic hazard and the only permanent seismograph in the region was the U.S. National Network broadband station east of the Ruby Mountains south of Wells. The University of Utah and University of Nevada deployed locally recorded strong motion instruments in the Wells area. Also, an 8 station IP telemetered strong motion network, jointly deployed by the U.S. Geological Survey and University of Nevada Reno, provided real-time data for quick high-quality aftershock relocations and ground motion estimates. In addition, the University of Utah established several telemetered analog stations for improved aftershock locations. IP data communications was routed through the Nevada Department of Information Technology microwave communications site north of Wells. The aftershock deployment was not possible without the considerable support of a number of public and private agencies in the Wells area and the Wells community itself. Many unreinforced masonry structures in old-town Wells, dating to the early 1900's, experienced significant damage. There was also damage to homes and businesses within the community, including the local High School, but fortunately there were no serious injuries associated with the earthquake.
'GREENER' SOLVENT-FREE CHEMICAL SYNTHESIS USING MICROWAVE IRRADIATION
Solvent-free approach that involves microwave (MW) irradiation of neat reactants (undiluted) catalyzed by the surfaces of less-expensive and recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage...
GREENER CHEMICAL SYNTHESES USING ALTERNATIVE REACTION CONDITIONS AND MEDIA
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
Federal Register 2010, 2011, 2012, 2013, 2014
2011-09-29
... efficiency; (7) optimization of generation and energy storage ranging from a 4 unit, 500 megawatts (MW) (4... brief comments up to 6,000 characters, without prior registration, using the eComment system at http...
CHEMICAL SYNTHESES AND TRANSFORMATIONS UNDER NON-TRADITIONAL CONDITIONS
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
Heat flow from the West African Shield
NASA Astrophysics Data System (ADS)
Brigaud, Frédéric; Lucazeau, Francis; Ly, Saidou; Sauvage, Jean François
1985-09-01
The heat flow over Precambrian shields is generally lower than over other continental provinces. Previous observations at 9 sites of the West African shield have shown that heat flow ranges from 20 mW m -2 in Niger to 38-42 mW m -2 in Liberia, Ghana and Nigeria. Since some of these values are lower than expected for Precambrian shields, it is important to find out whether or not they are representative of the entire shield before trying to derive its thermal structure. In this paper, we present new heat flow determinations from seven sites of the West African shield. These indicate that the surface heat flow is comparable with that of other Precambrian shields in the world.
Radiation-hardened-by-design clocking circuits in 0.13-μm CMOS technology
NASA Astrophysics Data System (ADS)
You, Y.; Huang, D.; Chen, J.; Gong, D.; Liu, T.; Ye, J.
2014-01-01
We present a single-event-hardened phase-locked loop for frequency generation applications and a digital delay-locked loop for DDR2 memory interface applications. The PLL covers a 12.5 MHz to 500 MHz frequency range with an RMS Jitter (RJ) of 4.70-pS. The DLL operates at 267 MHz and has a phase resolution of 60-pS. Designed in 0.13-μm CMOS technology, the PLL and the DLL are hardened against SEE for charge injection of 250 fC. The PLL and the DLL consume 17 mW and 22 mW of power under a 1.5 V power supply, respectively.
NASA Astrophysics Data System (ADS)
Song, Huaqing; Wang, Qi; Wang, Dongdong; Li, Li
2018-03-01
In this paper, we demonstrated passively Q-switched wavelength-tunable 1-μm fiber lasers utilizing few-layer black phosphorus saturable absorbers. The few-layer BP was deposited onto the tapered fibers by an optically driven process. The wavelength tunability was achieved with a fiber Sagnac loop comprised of a piece of polarization maintaining fiber and a polarization controller. Stable Q-switching laser operations were observed at wavelengths ranging from 1040.5 to 1044.6 nm at threshold pump power of 220 mW. Maximal pulse energy of 141.27 nJ at a repetition rate of 63 kHz was recorded under pump power of 445 mW.
Continuous wave room temperature external ring cavity quantum cascade laser
DOE Office of Scientific and Technical Information (OSTI.GOV)
Revin, D. G., E-mail: d.revin@sheffield.ac.uk; Hemingway, M.; Vaitiekus, D.
2015-06-29
An external ring cavity quantum cascade laser operating at ∼5.2 μm wavelength in a continuous-wave regime at the temperature of 15 °C is demonstrated. Out-coupled continuous-wave optical powers of up to 23 mW are observed for light of one propagation direction with an estimated total intra-cavity optical power flux in excess of 340 mW. The uni-directional regime characterized by the intensity ratio of more than 60 for the light propagating in the opposite directions was achieved. A single emission peak wavelength tuning range of 90 cm{sup −1} is realized by the incorporation of a diffraction grating into the cavity.
NASA Astrophysics Data System (ADS)
Simonelli, A.; Belfi, J.; Beverini, N.; Di Virgilio, A.; Giacomelli, U.; De Luca, G.; Igel, H.
2017-12-01
We report the observation and analysis of the MW 8.1 Tehuantepec earthquake-induced rotational ground motion as observed by the Gingerino ring laser gyroscope (RLG).This instrument is located inside the National laboratory of the "Istituto Nazionale di Fisica Nucleare" in Gran Sasso (Italy) in a deep underground environment.We compare the vertical rotation rate with the horizontal acceleration measured by a co-located broadband seismometer. This analysis, performed by means of a wavelet-based correlation method, permits to identify the G1,G2,G3,G4 onsets of the surface Love waves in the 120 to 280 seconds period range.
Evaluating galactic habitability using high-resolution cosmological simulations of galaxy formation
NASA Astrophysics Data System (ADS)
Forgan, Duncan; Dayal, Pratika; Cockell, Charles; Libeskind, Noam
2017-01-01
We present the first model that couples high-resolution simulations of the formation of local group galaxies with calculations of the galactic habitable zone (GHZ), a region of space which has sufficient metallicity to form terrestrial planets without being subject to hazardous radiation. These simulations allow us to make substantial progress in mapping out the asymmetric three-dimensional GHZ and its time evolution for the Milky Way (MW) and Triangulum (M33) galaxies, as opposed to works that generally assume an azimuthally symmetric GHZ. Applying typical habitability metrics to MW and M33, we find that while a large number of habitable planets exist as close as a few kiloparsecs from the galactic centre, the probability of individual planetary systems being habitable rises as one approaches the edge of the stellar disc. Tidal streams and satellite galaxies also appear to be fertile grounds for habitable planet formation. In short, we find that both galaxies arrive at similar GHZs by different evolutionary paths, as measured by the first and third quartiles of surviving biospheres. For the MW, this interquartile range begins as a narrow band at large radii, expanding to encompass much of the Galaxy at intermediate times before settling at a range of 2-13 kpc. In the case of M33, the opposite behaviour occurs - the initial and final interquartile ranges are quite similar, showing gradual evolution. This suggests that Galaxy assembly history strongly influences the time evolution of the GHZ, which will affect the relative time lag between biospheres in different galactic locations. We end by noting the caveats involved in such studies and demonstrate that high-resolution cosmological simulations will play a vital role in understanding habitability on galactic scales, provided that these simulations accurately resolve chemical evolution.
The 1999 Mw 7.1 Hector Mine, California, earthquake: A test of the stress shadow hypothesis?
Harris, R.A.; Simpson, R.W.
2002-01-01
We test the stress shadow hypothesis for large earthquake interactions by examining the relationship between two large earthquakes that occurred in the Mojave Desert of southern California, the 1992 Mw 7.3 Landers and 1999 Mw 7.1 Hector Mine earthquakes. We want to determine if the 1999 Hector Mine earthquake occurred at a location where the Coulomb stress was increased (earthquake advance, stress trigger) or decreased (earthquake delay, stress shadow) by the previous large earthquake. Using four models of the Landers rupture and a range of possible hypocentral planes for the Hector Mine earthquake, we discover that most scenarios yield a Landers-induced relaxation (stress shadow) on the Hector Mine hypocentral plane. Although this result would seem to weigh against the stress shadow hypothesis, the results become considerably more uncertain when the effects of a nearby Landers aftershock, the 1992 ML 5.4 Pisgah earthquake, are taken into account. We calculate the combined static Coulomb stress changes due to the Landers and Pisgah earthquakes to range from -0.3 to +0.3 MPa (- 3 to +3 bars) at the possible Hector Mine hypocenters, depending on choice of rupture model and hypocenter. These varied results imply that the Hector Mine earthquake does not provide a good test of the stress shadow hypothesis for large earthquake interactions. We use a simple approach, that of static dislocations in an elastic half-space, yet we still obtain a wide range of both negative and positive Coulomb stress changes. Our findings serve as a caution that more complex models purporting to explain the triggering or shadowing relationship between the 1992 Landers and 1999 Hector Mine earthquakes need to also consider the parametric and geometric uncertainties raised here.
All-periodically poled, high-power, continuous-wave, single-frequency tunable UV source.
Aadhi, A; Chaitanya N, Apurv; Jabir, M V; Singh, R P; Samanta, G K
2015-01-01
We report on experimental demonstration of an all-periodically poled, continuous-wave (CW), high-power, single-frequency, ultra-violet (UV) source. Based on internal second-harmonic-generation (SHG) of a CW singly resonant optical parametric oscillator (OPO) pumped in the green, the UV source provides tunable radiation across 398.94-417.08 nm. The compact source comprising of a 25-mm-long MgO-doped periodically poled stoichiometric lithium tantalate (MgO:sPPLT) crystal of period Λ(SLT)=8.5 μm for OPO and a 5-mm-long, multi-grating (Λ(KTP)=3.3, 3.4, 3.6 and 3.8 μm), periodically poled potassium titanium phosphate (PPKTP) for intra-cavity SHG, provides as much as 336 mW of UV power at 398.94 nm, corresponding to a green-to-UV conversion efficiency of ∼6.7%. In addition, the singly resonant OPO (SRO) provides 840 mW of idler at 1541.61 nm and substantial signal power of 108 mW at 812.33 nm transmitted through the high reflective cavity mirrors. UV source provides single-frequency radiation with instantaneous line-width of ∼18.3 MHz and power >100 mW in Gaussian beam profile (ellipticity >92%) across the entire tuning range. Access to lower UV wavelengths requires smaller grating periods to compensate high phase-mismatch resulting from high material dispersion in the UV wavelength range. Additionally, we have measured the normalized temperature and spectral acceptance bandwidth of PPKTP crystal in the UV wavelength range to be ∼2.25°C·cm and ∼0.15 nm·cm, respectively.
A Search for Laser Emission with Megawatt Thresholds from 5600 FGKM Stars
NASA Astrophysics Data System (ADS)
Tellis, Nathaniel K.; Marcy, Geoffrey W.
2017-06-01
We searched high-resolution spectra of 5600 nearby stars for emission lines that are both inconsistent with a natural origin and unresolved spatially, as would be expected from extraterrestrial optical lasers. The spectra were obtained with the Keck 10 m telescope, including light coming from within 0.5 arcsec of the star, corresponding typically to within a few to tens of astronomical units of the star, and covering nearly the entire visible wavelength range from 3640 to 7890 Å. We establish detection thresholds by injecting synthetic laser emission lines into our spectra and blindly analyzing them for detections. We compute flux density detection thresholds for all wavelengths and spectral types sampled. Our detection thresholds for the power of the lasers themselves range from 3 kW to 13 MW, independent of distance to the star but dependent on the competing “glare” of the spectral energy distribution of the star and on the wavelength of the laser light, launched from a benchmark, diffraction-limited 10 m class telescope. We found no such laser emission coming from the planetary region around any of the 5600 stars. Because they contain roughly 2000 lukewarm, Earth-size planets, we rule out models of the Milky Way in which over 0.1% of warm, Earth-size planets harbor technological civilizations that, intentionally or not, are beaming optical lasers toward us. A next-generation spectroscopic laser search will be done by the Breakthrough Listen initiative, targeting more stars, especially stellar types overlooked here including spectral types O, B, A, early F, late M, and brown dwarfs, and astrophysical exotica.
Effect of particle size and laser power on the Raman spectra of CuAlO2 delafossite nanoparticles
NASA Astrophysics Data System (ADS)
Yassin, O. A.; Alamri, S. N.; Joraid, A. A.
2013-06-01
A transparent conductive oxide CuAlO2 delafossite is studied using x-ray powder diffraction (XRD) and micro-Raman spectroscopy measurements as a function of the particle size and laser power from 2 to 20 mW. The XRD results indicate that the lattice parameters and the cell volume expand as the particle size reduces. Large red shifts (˜60 cm-1) and line broadening (˜50 cm-1) are observed as the particle size becomes of the order of 13 nm. These huge values can only be justified if collective effects on the Raman spectra created by the lattice expansion, confinement of phonons and enhanced phonon-phonon interactions are included in the interpretations of the Raman spectra of the CuAlO2 nanoparticles.
Choy, George; Rubinstein, Justin L.; Yeck, William; McNamara, Daniel E.; Mueller, Charles; Boyd, Oliver
2016-01-01
The largest recorded earthquake in Kansas occurred northeast of Milan on 12 November 2014 (Mw 4.9) in a region previously devoid of significant seismic activity. Applying multistation processing to data from local stations, we are able to detail the rupture process and rupture geometry of the mainshock, identify the causative fault plane, and delineate the expansion and extent of the subsequent seismic activity. The earthquake followed rapid increases of fluid injection by multiple wastewater injection wells in the vicinity of the fault. The source parameters and behavior of the Milan earthquake and foreshock–aftershock sequence are similar to characteristics of other earthquakes induced by wastewater injection into permeable formations overlying crystalline basement. This earthquake also provides an opportunity to test the empirical relation that uses felt area to estimate moment magnitude for historical earthquakes for Kansas.
Cocurrent scrubber evaluation TVA's Colbert Lime--Limestone Wet-Scrubbing Pilot Plant. Final report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Robards, R.F.; Moore, N.D.; Kelso, T.M.
1979-01-01
The Tennessee Valley Authority (TVA) is actively engaged in a pilot plant program to develop and/or evaluate wet-scrubbing processes for removing sulfur dioxide (SO/sub 2/) from boiler flue gas. The physical size and general arrangement of flue gas scrubbing systems have a major impact on capital investment and operating cost, as do potential operating and maintenance advantages inherent to some systems. The equipment configuration for a cocurrent scrubber reflects some of these advantages. EPRI funded TVA to perform preliminary screening tests of TVA's 1 MW pilot plant (Colbert Steam Plant) to develop operating data on the cocurrent design for usemore » in designing and operating a 10 MW prototype cocurrent scrubber at TVA's Shawnee Scrubber Test Facility. Results of the Colbert tests showed excellent sulfur dioxide removal efficiencies, generally greater than 85%, low pressure drop, and high particulate removal efficiencies. This report covers these screening tests.« less
Oxidative polymerization of lignins by laccase in water-acetone mixture.
Fiţigău, Ionița Firuța; Peter, Francisc; Boeriu, Carmen Gabriela
2013-01-01
The enzymatic oxidative polymerization of five technical lignins with different molecular properties, i.e. Soda Grass/Wheat straw Lignin, Organosolv Hardwood Lignin, Soda Wheat straw Lignin, Alkali pretreated Wheat straw Lignin, and Kraft Softwood was studied. All lignins were previously fractionated by acetone/water 50:50 (v/v) and the laccase-catalyzed polymerization of the low molecular weight fractions (Mw < 4000 g/mol) was carried out in the same solvent system. Reactivity of lignin substrates in laccase-catalyzed reactions was determined by monitoring the oxygen consumption. The oxidation reactions in 50% acetone in water mixture proceed with high rate for all tested lignins. Polymerization products were analyzed by size exclusion chromatography, FT-IR, and (31)P-NMR and evidence of important lignin modifications after incubation with laccase. Lignin polymers with higher molecular weight (Mw up to 17500 g/mol) were obtained. The obtained polymers have potential for applications in bioplastics, adhesives and as polymeric dispersants.
A low-power high-speed ultra-wideband pulse radio transmission system.
Wei Tang; Culurciello, E
2009-10-01
We present a low-power high-speed ultra-wideband (UWB) transmitter with a wireless transmission test platform. The system is specifically designed for low-power high-speed wireless implantable biosensors. The integrated transmitter consists of a compact pulse generator and a modulator. The circuit is fabricated in the 0.5-mum silicon-on-sapphire process and occupies 420 mum times 420 mum silicon area. The transmitter is capable of generating pulses with 1-ns width and the pulse rate can be controlled between 90 MHz and 270 MHz. We built a demonstration/testing system for the transmitter. The transmitter achieves a 14-Mb/s data rate. With 50% duty cycle data, the power consumption of the chip is between 10 mW and 21 mW when the transmission distance is from 3.2 to 4 m. The core circuit size is 70 mum times 130 mum.
Small solar thermal electric power plants with early commercial potential
NASA Technical Reports Server (NTRS)
Jones, H. E.; Bisantz, D. J.; Clayton, R. N.; Heiges, H. H.; Ku, A. C.
1979-01-01
Cost-effective small solar thermal electric power plants (1- to 10-MW nominal size) offer an attractive way of helping the world meet its future energy needs. The paper describes the characteristics of a conceptual near-term plant (about 1 MW) and a potential 1990 commercial version. The basic system concept is one in which steam is generated using two-axis tracking, parabolic dish, and point-focusing collectors. The steam is transported through low-loss piping to a central steam turbine generator unit where it is converted to electricity. The plants have no energy storage and their output power level varies with the solar insolation level. This system concept, which is firmly based on state-of-the-art technology, is projected to offer one of the fastest paths for U.S. commercialization of solar thermal electric power plants through moderate technology advances and mass production.
More mind wandering, fewer original ideas: be not distracted during creative idea generation.
Hao, Ning; Wu, Mengxia; Runco, Mark A; Pina, Jeremy
2015-10-01
Several studies suggest that mind wandering (MW) benefits creativity when the MW occurs in the incubation period of creative problem solving. The aim of present study was to examine the effects of MW that occurs in the course of creative idea generation. Participants received an Alternative Uses Task (AUT) and were asked to generate ideas for 20min. Their MW frequencies as time passed were measured by means of probe-caught MW. Comparisons of the AUT performances of high and low MW groups revealed that greater MW was associated with lower fluency and originality scores on the AUT. Furthermore, the high MW group showed greater MW as time passed, while the low MW group's MW was steady during the course of idea generation. Accordingly, the originality of idea generation decreased with time passing for the high MW group but was steady for the low MW group. The findings suggest that the MW during the course of creative idea generation is negatively related to creativity, perhaps because the control processes involved in idea generation are impaired by the mind wandering. Copyright © 2015 Elsevier B.V. All rights reserved.
Analysis of UV-excited fluorochromes by flow cytometry using near-ultraviolet laser diodes.
Telford, William G
2004-09-01
Violet laser diodes have become common and reliable laser sources for benchtop flow cytometers. While these lasers are very useful for a variety of violet and some ultraviolet-excited fluorochromes (e.g., DAPI), they do not efficiently excite most UV-stimulated probes. In this study, the next generation of InGaN near-UV laser diodes (NUVLDs) emitting in the 370-375-nm range have been evaluated as laser sources for cuvette-based flow cytometers. Several NUVLDs, ranging in wavelength from 370 to 374 nm and in power level from 1.5 to 10 mW, were mounted on a BD Biosciences LSR II and evaluated for their ability to excite cells labeled with the UV DNA binding dye DAPI, several UV phenotyping fluorochromes (including Alexa Fluor 350, Marina Blue, and quantum dots), and the fluorescent calcium chelator indo-1. NUVLDs at the 8-10-mW power range gave detection sensitivity levels comparable to more powerful solid-state and ion laser sources, using low-fluorescence microsphere beads as measurement standards. NUVLDs at all tested power levels allowed extremely high-resolution DAPI cell cycle analysis, and sources in the 8-10-mW power range excited Alexa Fluor 350, Marina Blue, and a variety of quantum dots at virtually the same signal-to-noise ratios as more powerful UV sources. These evaluations indicate that near-UV laser diodes installed on a cuvette-based flow cytometer performed nearly as well as more powerful solid-state UV lasers on the same instrumentation, and comparably to more powerful ion lasers on a jet-in-air system, and. Despite their limited power, integration of these small and inexpensive lasers into benchtop flow cytometers should allow the use of flow cytometric applications requiring UV excitation on a wide variety of instruments. Copyright 2004 Wiley-Liss, Inc.
Indoor noise annoyance due to 3-5 megawatt wind turbines-An exposure-response relationship.
Hongisto, Valtteri; Oliva, David; Keränen, Jukka
2017-10-01
The existing exposure-response relationships describing the association between wind turbine sound level and noise annoyance concern turbine sizes of 0.15-3.0 MW. The main purpose of this study was to determine a relationship concerning turbines with nominal power of 3-5 MW. A cross-sectional survey was conducted around three wind power areas in Finland. The survey involved all households within a 2 km distance from the nearest turbine. Altogether, 429 households out of 753 participated. The households were exposed to wind turbine noise having sound levels within 26.7-44.2 dB L Aeq . Standard prediction methods were applied to determine the sound level, L Aeq , in each participant's yard. The measured sound level agreed well with the predicted sound level. The exposure-response relationship was derived between L Aeq outdoors and the indoor noise annoyance. The relationship was in rather good agreement with two previous studies involving much smaller turbines (0.15-1.5 MW) under 40 dB L Aeq . The Community Tolerance Level (CTL), CTL 20 = 50 dB, was 3 dB lower than for two previous studies. Above 40 dB, a small number of participants prevented a reliable comparison to previous studies.
Ken, Yukawa; Noriko, Tachikawa; Furuichi, Akiko; Shohei, Kasugai
2016-12-01
This study investigated the biological reaction to porous poly-DL-lactic acid (PDLLA) scaffolds with holes for soft tissue augmentation. The control group was porous PDLLA with a diameter of 5.0 mm and a height of 2.0 mm. For the 2 test groups, 7 holes were drilled from the upper to the lower base of the scaffolds; the holes had diameters of 0.5 and 1.0 mm. A scaffold was placed in the periosteum of the cranium. The height and molecular weight (Mw) of the scaffolds were measured at 4 and 8 weeks. Hematoxylin and eosin staining was used to measure the connective tissue and blood vessel areas. All groups had similar scaffold heights, but the Mw decreased significantly over time. There were significant differences in the connective tissue and blood vessel areas among the control, 0.5-mm, and 1.0-mm groups at the same time point. The soft tissue was increased by drilling holes in the scaffolds. Porous poly-DL-lactic acid (PDLLA) contributed favorable prognosis for soft tissue. A wider hole was associated with increased connective tissue and blood vessel areas. The scaffold height and Mw were not impacted by size of the holes.
A robust operational model for predicting where tropical cyclone waves damage coral reefs
NASA Astrophysics Data System (ADS)
Puotinen, Marji; Maynard, Jeffrey A.; Beeden, Roger; Radford, Ben; Williams, Gareth J.
2016-05-01
Tropical cyclone (TC) waves can severely damage coral reefs. Models that predict where to find such damage (the ‘damage zone’) enable reef managers to: 1) target management responses after major TCs in near-real time to promote recovery at severely damaged sites; and 2) identify spatial patterns in historic TC exposure to explain habitat condition trajectories. For damage models to meet these needs, they must be valid for TCs of varying intensity, circulation size and duration. Here, we map damage zones for 46 TCs that crossed Australia’s Great Barrier Reef from 1985-2015 using three models - including one we develop which extends the capability of the others. We ground truth model performance with field data of wave damage from seven TCs of varying characteristics. The model we develop (4MW) out-performed the other models at capturing all incidences of known damage. The next best performing model (AHF) both under-predicted and over-predicted damage for TCs of various types. 4MW and AHF produce strikingly different spatial and temporal patterns of damage potential when used to reconstruct past TCs from 1985-2015. The 4MW model greatly enhances both of the main capabilities TC damage models provide to managers, and is useful wherever TCs and coral reefs co-occur.
A robust operational model for predicting where tropical cyclone waves damage coral reefs.
Puotinen, Marji; Maynard, Jeffrey A; Beeden, Roger; Radford, Ben; Williams, Gareth J
2016-05-17
Tropical cyclone (TC) waves can severely damage coral reefs. Models that predict where to find such damage (the 'damage zone') enable reef managers to: 1) target management responses after major TCs in near-real time to promote recovery at severely damaged sites; and 2) identify spatial patterns in historic TC exposure to explain habitat condition trajectories. For damage models to meet these needs, they must be valid for TCs of varying intensity, circulation size and duration. Here, we map damage zones for 46 TCs that crossed Australia's Great Barrier Reef from 1985-2015 using three models - including one we develop which extends the capability of the others. We ground truth model performance with field data of wave damage from seven TCs of varying characteristics. The model we develop (4MW) out-performed the other models at capturing all incidences of known damage. The next best performing model (AHF) both under-predicted and over-predicted damage for TCs of various types. 4MW and AHF produce strikingly different spatial and temporal patterns of damage potential when used to reconstruct past TCs from 1985-2015. The 4MW model greatly enhances both of the main capabilities TC damage models provide to managers, and is useful wherever TCs and coral reefs co-occur.
Hnatukova, Petra; Kopecka, Ivana; Pivokonsky, Martin
2011-05-01
In this research, the adsorption of two herbicides, alachlor (ALA) and terbuthylazine (TBA), on granular activated carbon (GAC) in the presence of well-characterized peptide fraction of cellular organic matter (COM) produced by cyanobacterium Microcystis aeruginosa was studied. Two commercially available GACs were characterized using nitrogen gas adsorption and surface charge titrations. The COM peptides of molecular weight (MW) < 10 kDa were isolated and characterized using MW fractionation technique and high-performance size exclusion chromatography (HPSEC). The effect of surface charge on the adsorption of COM peptides was studied by means of equilibrium adsorption experiments at pH 5 and pH 8.5. Electrostatic interactions and hydrogen bonding proved to be important mechanisms of COM peptides adsorption. The adsorption of ALA and TBA on granular activated carbon preloaded with COM peptides was influenced by solution pH. The reduction in adsorption was significantly greater at pH 5 compared to pH 8.5, which corresponded to the increased adsorption of COM peptides at pH 5. The majority of the competition between COM peptides and both herbicides was attributed to low molecular weight COM peptides with MW of 700, 900, 1300 and 1700 Da. Copyright © 2011 Elsevier Ltd. All rights reserved.
The Absence of Remotely Triggered Seismicity in Japan from 1997 to 2002
NASA Astrophysics Data System (ADS)
Wakefield, R. H.; Brodsky, E. E.
2003-12-01
Observations of increased seismicity following the Landers, Hector Mine, Izmit, and the Denali, earthquakes suggests remote seismic triggering occurs in geothermal locations as far as 3150 km. This study attempts to determine if the same effects occur in Japan, a geothermal region of high seismicity. For the period of 1997 to 2002, we searched for significant increases in the seismicity levels following earthquakes with Mw >= 6.5 at distances larger than conventionally associated with aftershocks. Additionally, we examined available waveform data in order to detect uncataloged events hidden by the coda of the mainshock. Five events had associated waveform data: March 24, 2001 Geiyo, Mw = 6.8; March 28, 2000 Volcano Islands, Mw = 7.6; July 30, 2000 Honshu, Mw = 6.5; October 6, 2000 Tottori, Mw = 6.7; and the January 28, 1999 Kuril Islands, Mw = 6.8 earthquake. Located 260 km from the Geiyo epicenter, station TKO recorded one possible triggered event within 65 km during the hour following the mainshock. However, the TKO data contains many anomalous spikes, and we are not confident the record is clear enough to differentiate small local events from noise. An ambiguous, two-day, regional seismicity increase followed the Volcano Islands event. We interpret the swarm associated with the signal as coincidental because no similar swarms occurred at the same location following Tottori or Geiyo, both of which had an order of magnitude larger shaking. Both waveforms and cataloged events indicate no triggering occurred following the Honshu, Tottori and Kuril Islands mainshocks. We do not interpret the one indefinite local event recorded by TKO as evidence for mid range dynamic triggering, implying that the 2.5 cm/s shaking at TKO did not exceed the local triggering threshold. Additionally, the lack of triggering following Honshu, Tottori, and Kuril Islands suggests that the 1, 2.5 and 2.6 cm/s shaking at distances of 182, 238, and 267 km, respectively, creates lower bounds for the dynamic triggering thresholds at the respective locations. This assumes the bound is frequency independent. In none of the cases were thresholds exceeded over a large enough region or by large enough amplitude to produce a statistically significant increase in the cataloged rate of seismicity during the period from 1997 to 2002. All previously documented examples of triggering have occurred following shallow earthquakes with Mw > 7. With the exception of Volcano Islands, all of the events of this study have Mw < 7, and have no triggering associated with them. This suggests two possibilities: either events with Mw > 7 are required to produce sufficient shaking to trigger seismicity, or Japan is less susceptible to triggering than the western US or Greece. We assume that the depth of the Volcano Islands earthquake prohibits any substantial surface shaking. We conclude that more data is required associated with shallow, crustal events with Mw > 7 in order to determine whether or not Japan is susceptible to regional triggering.
GREENER CHEMICAL SYNTHESES USING ALTERNATIVE REACTION CONDITIONS AND MEDIA (MARCH 2006)
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or ‘doped’ surfaces is presented which is applicable to a wide range of cleavage, conden...
CHEMISTRY UNDER 'GREENER' CONDITIONS: SOLVENT-FREE SYNTHESIS USING MICROWAVE IRRADIATION
Solvent-free approach is emphasized that involves microwave (MW) irradiation of neat reactants (undiluted) catalyzed by the surfaces of less-expensive and recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces which is applicable to a wide range of cleavag...
"GREENER" CHEMICAL SYNTHESES USING AN ALTERNATE REACTION CONDITIONS OR AQUEOUS MEDIA
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
GREENER CHEMICAL SYNTHESES USING ALTERNATIVE REACTION CONDITIONS AND MEDIA (BRAZIL 2006)
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
ENVIRONMENTALLY FRIENDLIER SYNTHESES USING MICROWAVES AND ALTERNATIVE REACTION MEDIA
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of less-expensive and recyclable mineral supports such as alumina, silica, clay, or "doped" surfaces is presented which is applicable to a wide range of cleavage,...
ENVIRONMENTALLY FRIENDLIER SYNTHESES USING MICROWAVES AND ALTERNATIVE REACTION CONDITIONS
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of less-expensive and recyclable mineral supports such as alumina, silica, clay, or doped surfaces is presented which is applicable to a wide range of cleavage, c...
ORGANIC SYNTHESES IN SOLVENT-FREE AND AQUEOUS MEDIA USING MICROWAVES
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of recyclable mineral supports such as alumina, silica, clay, or 'doped' surfaces is presented which is applicable to a wide range of cleavage, condensation, cycl...
‘GREENER’ ORGANIC SYNTHESES UNDER NON-TRADITIONAL CONDITIONS
A solvent-free approach that involves microwave (MW) exposure of neat reactants (undiluted) catalyzed by the surfaces of less-expensive and recyclable mineral supports such as alumina, silica, clay, or ‘doped’ surfaces is presented which is applicable to a wide range of cleavage,...
Studies of charge transport in DNA films using the time-of-flight (TOF) technique
NASA Astrophysics Data System (ADS)
Yaney, Perry P.; Gorman, Timothy; Ouchen, Fahima; Grote, James G.
2011-09-01
Measurements were carried out on salmon DNA-based films, including as-received DNA (molecular weight, MW>2000 kDa) without and with hexacetyltrimethl-ammonium chloride (CTMA) surfactant, and sonicated DNA of MW~200 kDa with CTMA. The test specimens were spin-coated or drop-cast films on ITO-coated quartz slides with a gold charge-collecting electrode. To protect the films from atmospheric influences, the TOF devices were coated with a 200-400 nm polyurethane passivation layer. A quadrupled 20 ns, pulsed Nd:YAG laser with output at 266 nm was used for charge injection. The room temperature photoconductive transients were dispersive to varying degrees with hole mobilities in DNA materials films ranging between 2E-5 to 6E-3 cm2/Vs for fields ranging from 8 to 58 kV/cm. Only hole response was observed in DNA. The dispersive data were analyzed using a simple, quasi-empirical equation for the photocurrent transient data.
Low threshold optical bistability in one-dimensional gratings based on graphene plasmonics.
Guo, Jun; Jiang, Leyong; Jia, Yue; Dai, Xiaoyu; Xiang, Yuanjiang; Fan, Dianyuan
2017-03-20
Optical bistability of graphene surface plasmon is investigated numerically, using grating coupling method at normal light incidence. The linear surface plasmon resonance is strongly dependent on Femi-level of graphene, hence it can be tuned in a large wavelength range. Due to the field enhancement of graphene surface plasmon resonance and large third-order nonlinear response of graphene, a low-threshold optical hysteresis has been observed. The threshold value with 20MW/cm2 and response time with 1.7ps have been verified. Especially, it is found that this optical bistability phenomenon is angular insensitivity for near 15° incident angle. The threshold of optical bistability can be further lowered to 0.5MW/cm2 by using graphene nanoribbons, and the response time is also shorten to 800fs. We believe that our results will find potential applications in bistable devices and all-optical switching from mid-IR to THz range.
NASA Astrophysics Data System (ADS)
Redpath, David; Ward, Michael J.
2017-07-01
The maximum exploitable potential for low head hydroelectric sites (gross head≤10 m) in Northern Ireland (NI) was determined as 12.07 MW using a simple payback analysis for 304 potential sites investigated to derive a classification scheme in terms of economic viability. A techno-economic analysis with validated numerical models from previous research estimated the capital investment required for the development of a hydroelectric plant, using the low head Michell-Banki cross flow turbine, for the 304 sites investigated. The number of potentially viable sites in NI for low head hydro ranged from 198 to 286 with an estimated installed capacity ranging from 11.95 to 12.05 MW. Sites with a limited installed capacity were not economically viable unless increased government support in the form of longer term (25-50 years) low interest loans as well as the current (Renewables Obligations Certificates) Renewables Obligation Certificates scheme is provided and sustained.
All-fiber, ultra-wideband tunable laser at 2 μm.
Li, Z; Alam, S U; Jung, Y; Heidt, A M; Richardson, D J
2013-11-15
We report a direct diode-pumped all-fiber tunable laser source at 2 μm with a tuning range of more than 250 nm. A 3 dB power flatness of 200 nm with a maximum output power of 30 mW at 1930 nm was achieved. The laser has a high optical signal-to-noise ratio (OSNR) of more than 40 dB across the whole tuning range.
NASA Astrophysics Data System (ADS)
Ghosh, Rikhia; Banerjee, Saikat; Hazra, Milan; Roy, Susmita; Bagchi, Biman
2014-12-01
Since the time of Kirkwood, observed deviations in magnitude of the dielectric constant of aqueous protein solution from that of neat water (˜80) and slower decay of polarization have been subjects of enormous interest, controversy, and debate. Most of the common proteins have large permanent dipole moments (often more than 100 D) that can influence structure and dynamics of even distant water molecules, thereby affecting collective polarization fluctuation of the solution, which in turn can significantly alter solution's dielectric constant. Therefore, distance dependence of polarization fluctuation can provide important insight into the nature of biological water. We explore these aspects by studying aqueous solutions of four different proteins of different characteristics and varying sizes, chicken villin headpiece subdomain (HP-36), immunoglobulin binding domain protein G (GB1), hen-egg white lysozyme (LYS), and Myoglobin (MYO). We simulate fairly large systems consisting of single protein molecule and 20000-30000 water molecules (varied according to the protein size), providing a concentration in the range of ˜2-3 mM. We find that the calculated dielectric constant of the system shows a noticeable increment in all the cases compared to that of neat water. Total dipole moment auto time correlation function of water ⟨δMW(0)δMW(t)⟩ is found to be sensitive to the nature of the protein. Surprisingly, dipole moment of the protein and total dipole moment of the water molecules are found to be only weakly coupled. Shellwise decomposition of water molecules around protein reveals higher density of first layer compared to the succeeding ones. We also calculate heuristic effective dielectric constant of successive layers and find that the layer adjacent to protein has much lower value (˜50). However, progressive layers exhibit successive increment of dielectric constant, finally reaching a value close to that of bulk 4-5 layers away. We also calculate shellwise orientational correlation function and tetrahedral order parameter to understand the local dynamics and structural re-arrangement of water. Theoretical analysis providing simple method for calculation of shellwise local dielectric constant and implication of these findings are elaborately discussed in the present work.
Grand Canonical Investigation of the Quasi Liquid Layer of Ice: Is It Liquid?
Pickering, Ignacio; Paleico, Martin; Sirkin, Yamila A Perez; Scherlis, Damian A; Factorovich, Matías H
2018-05-10
In this study, the solid-vapor equilibrium and the quasi liquid layer (QLL) of ice Ih exposing the basal and primary prismatic faces were explored by means of grand canonical molecular dynamics simulations with the monatomic mW potential. For this model, the solid-vapor equilibrium was found to follow the Clausius-Clapeyron relation in the range examined, from 250 to 270 K, with a Δ H sub of 50 kJ/mol in excellent agreement with the experimental value. The phase diagram of the mW model was constructed for the low pressure region around the triple point. The analysis of the crystallization dynamics during condensation and evaporation revealed that, for the basal face, both processes are highly activated, and in particular cubic ice is formed during condensation, producing stacking-disordered ice. The basal and primary prismatic surfaces of ice Ih were investigated at different temperatures and at their corresponding equilibrium vapor pressures. Our results show that the region known as QLL can be interpreted as the outermost layers of the solid where a partial melting takes place. Solid islands in the nanometer length scale are surrounded by interconnected liquid areas, generating a bidimensional nanophase segregation that spans throughout the entire width of the outermost layer even at 250 K. Two approaches were adopted to quantify the QLL and discussed in light of their ability to reflect this nanophase segregation phenomena. Our results in the μVT ensemble were compared with NPT and NVT simulations for two system sizes. No significant differences were found between the results as a consequence of model system size or of the working ensemble. Nevertheless, certain advantages of performing μVT simulations in order to reproduce the experimental situation are highlighted. On the one hand, the QLL thickness measured out of equilibrium might be affected because of crystallization being slower than condensation. On the other, preliminary simulations of AFM indentation experiments show that the tip can induce capillary condensation over the ice surface, enlarging the apparent QLL.
Characterization of allergoids.
Himly, Martin; Carnés, Jerónimo; Fernández-Caldas, Enrique; Briza, Peter; Ferreira, Fatima
2009-01-01
So far it has not been possible to measure the amount of major allergens in the complexes after chemical modification. Furthermore, the presence of minor allergens remained obscure, unless antibodies were successfully generated by animal immunization with allergoids and shown to be reactive with purified natural or recombinant allergens in immunological assays. Thus, we adapted and employed a set of physicochemical methods with the aim of elucidating the molecular size and allergen composition of allergoids. Using online-HPSEC light scattering and DLS, it was shown that two thirds of depigmented allergoid prepared from birch pollen extracts adopted a MW between 1000 and 2000 kDa. The question of reproducibility of the polymerization reaction was addressed by investigating four batches of P. pratense allergoid. Three out of the four batches contained 73 to 77% of polymerized molecules in the above-mentioned range of molecular sizes. One batch showed a significantly higher content of molecules with a MW exceeding 2 MDa. Analysis of allergen composition in B. alba allergoids revealed the presence of all relevant Bet v 1 isoforms and minor allergens except for Bet v 3 and Bet v 4, which was in good agreement with the allergens detected in the native extracts. It should be noted that Bet v 3 has not been detected at the protein level before. Similarly, good agreement in allergen composition between allergoid and native extract was also found for D. pteronyssinus. Presently, the European Directorate for Quality of Medicines and Healthcare (EDQM) is committed to the application of the 3R principles (i. e. replace, reduce, refine the use of animals) for the quality control of medicines wherever possible. This is reflected by the regular review of the monographs of the European Pharmacopoeia and the introduction of alternative tests. For instance, recently it was decided to replace the rabbit pyrogen test by an in vitro test. Furthermore, through the Biological Standardisation Programme the EDQM develops, validates, and establishes alternative test methods in the field of quality control of biologicals (personal communication with Karl-Heinz Buchheit, EDQM). Therefore, the approach presented here for the characterization of allergoids relying on physicochemical methods shall also serve the growing needs for alternative methods to animal testing.
A 11 mW 2.4 GHz 0.18 µm CMOS Transceivers for Wireless Sensor Networks.
Hou, Bing; Chen, Hua; Wang, Zhiyu; Mo, Jiongjiong; Chen, Junli; Yu, Faxin; Wang, Wenbo
2017-01-24
In this paper, a low power transceiver for wireless sensor networks (WSN) is proposed. The system is designed with fully functional blocks including a receiver, a fractional-N frequency synthesizer, and a class-E transmitter, and it is optimized with a good balance among output power, sensitivity, power consumption, and silicon area. A transmitter and receiver (TX-RX) shared input-output matching network is used so that only one off-chip inductor is needed in the system. The power and area efficiency-oriented, fully-integrated frequency synthesizer is able to provide programmable output frequencies in the 2.4 GHz range while occupying a small silicon area. Implemented in a standard 0.18 μm RF Complementary Metal Oxide Semiconductor (CMOS) technology, the whole transceiver occupies a chip area of 0.5 mm² (1.2 mm² including bonding pads for a QFN package). Measurement results suggest that the design is able to work at amplitude shift keying (ASK)/on-off-keying (OOK) and FSK modes with up to 500 kbps data rate. With an input sensitivity of -60 dBm and an output power of 3 dBm, the receiver, transmitter and frequency synthesizer consumes 2.3 mW, 4.8 mW, and 3.9 mW from a 1.8 V supply voltage, respectively.