Stability of generic thin shells in conformally flat spacetimes

NASA Astrophysics Data System (ADS)

Amirabi, Z.

2017-07-01

Some important spacetimes are conformally flat; examples are the Robertson-Walker cosmological metric, the Einstein-de Sitter spacetime, and the Levi-Civita-Bertotti-Robinson and Mannheim metrics. In this paper we construct generic thin shells in conformally flat spacetime supported by a perfect fluid with a linear equation of state, i.e., p=ω σ . It is shown that, for the physical domain of ω , i.e., 0<ω ≤ 1, such thin shells are not dynamically stable. The stability of the timelike thin shells with the Mannheim spacetime as the outer region is also investigated.

Spline Approximation of Thin Shell Dynamics

NASA Technical Reports Server (NTRS)

delRosario, R. C. H.; Smith, R. C.

1996-01-01

A spline-based method for approximating thin shell dynamics is presented here. While the method is developed in the context of the Donnell-Mushtari thin shell equations, it can be easily extended to the Byrne-Flugge-Lur'ye equations or other models for shells of revolution as warranted by applications. The primary requirements for the method include accuracy, flexibility and efficiency in smart material applications. To accomplish this, the method was designed to be flexible with regard to boundary conditions, material nonhomogeneities due to sensors and actuators, and inputs from smart material actuators such as piezoceramic patches. The accuracy of the method was also of primary concern, both to guarantee full resolution of structural dynamics and to facilitate the development of PDE-based controllers which ultimately require real-time implementation. Several numerical examples provide initial evidence demonstrating the efficacy of the method.

Manufacturing of glassy thin shell for adaptive optics: results achieved

NASA Astrophysics Data System (ADS)

Poutriquet, F.; Rinchet, A.; Carel, J.-L.; Leplan, H.; Ruch, E.; Geyl, R.; Marque, G.

2012-07-01

Glassy thin shells are key components for the development of adaptive optics and are part of future & innovative projects such as ELT. However, manufacturing thin shells is a real challenge. Even though optical requirements for the front face - or optical face - are relaxed compared to conventional passive mirrors, requirements concerning thickness uniformity are difficult to achieve. In addition, process has to be completely re-defined as thin mirror generates new manufacturing issues. In particular, scratches and digs requirement is more difficult as this could weaken the shell, handling is also an important issue due to the fragility of the mirror. Sagem, through REOSC program, has recently manufactured different types of thin shells in the frame of European projects: E-ELT M4 prototypes and VLT Deformable Secondary Mirror (VLT DSM).

Experimental Observation of Thin-shell Instability in a Collisionless Plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahmed, H.; Doria, D.; Sarri, G.

We report on the experimental observation of the instability of a plasma shell, which formed during the expansion of a laser-ablated plasma into a rarefied ambient medium. By means of a proton radiography technique, the evolution of the instability is temporally and spatially resolved on a timescale much shorter than the hydrodynamic one. The density of the thin shell exceeds that of the surrounding plasma, which lets electrons diffuse outward. An ambipolar electric field grows on both sides of the thin shell that is antiparallel to the density gradient. Ripples in the thin shell result in a spatially varying balancemore » between the thermal pressure force mediated by this field and the ram pressure force that is exerted on it by the inflowing plasma. This mismatch amplifies the ripples by the same mechanism that drives the hydrodynamic nonlinear thin-shell instability (NTSI). Our results thus constitute the first experimental verification that the NTSI can develop in colliding flows.« less

Experimental Observation of Thin-shell Instability in a Collisionless Plasma

NASA Astrophysics Data System (ADS)

Ahmed, H.; Doria, D.; Dieckmann, M. E.; Sarri, G.; Romagnani, L.; Bret, A.; Cerchez, M.; Giesecke, A. L.; Ianni, E.; Kar, S.; Notley, M.; Prasad, R.; Quinn, K.; Willi, O.; Borghesi, M.

2017-01-01

We report on the experimental observation of the instability of a plasma shell, which formed during the expansion of a laser-ablated plasma into a rarefied ambient medium. By means of a proton radiography technique, the evolution of the instability is temporally and spatially resolved on a timescale much shorter than the hydrodynamic one. The density of the thin shell exceeds that of the surrounding plasma, which lets electrons diffuse outward. An ambipolar electric field grows on both sides of the thin shell that is antiparallel to the density gradient. Ripples in the thin shell result in a spatially varying balance between the thermal pressure force mediated by this field and the ram pressure force that is exerted on it by the inflowing plasma. This mismatch amplifies the ripples by the same mechanism that drives the hydrodynamic nonlinear thin-shell instability (NTSI). Our results thus constitute the first experimental verification that the NTSI can develop in colliding flows.

Structure and dynamics of shear bands in amorphous–crystalline nanolaminates

DOE PAGES

Guo, Wei; Gan, Bin; Molina-Aldareguia, Jon M.; ...

2015-08-03

In this paper, the velocities of shear bands in amorphous CuZr/crystalline Cu nanolaminates were quantified as a function of strain rate and crystalline volume fraction. A rate-dependent transition in flow response was found in a 100 nm CuZr/10 nm Cu nanolaminates. When increasing the Cu layer thickness from 10 nm to 100 nm, the instantaneous velocity of the shear band in these nanolaminates decreases from 11.2 μm/s to <~500 nm/s. Finally, atom probe tomography and transmission election microcopy observation revealed that in post-deformed pillars both grain rotation in the crystalline portion and non-diffusive crystallization in the amorphous layer affect themore » viscosity of shear bands.« less

Thin Shell Model for NIF capsule stagnation studies

NASA Astrophysics Data System (ADS)

Hammer, J. H.; Buchoff, M.; Brandon, S.; Field, J. E.; Gaffney, J.; Kritcher, A.; Nora, R. C.; Peterson, J. L.; Spears, B.; Springer, P. T.

2015-11-01

We adapt the thin shell model of Ott et al. to asymmetric ICF capsule implosions on NIF. Through much of an implosion, the shell aspect ratio is large so the thin shell approximation is well satisfied. Asymmetric pressure drive is applied using an analytic form for ablation pressure as a function of the x-ray flux, as well as time-dependent 3D drive asymmetry from hohlraum calculations. Since deviations from a sphere are small through peak velocity, we linearize the equations, decompose them by spherical harmonics and solve ODE's for the coefficients. The model gives the shell position, velocity and areal mass variations at the time of peak velocity, near 250 microns radius. The variables are used to initialize 3D rad-hydro calculations with the HYDRA and ARES codes. At link time the cold fuel shell and ablator are each characterized by a density, adiabat and mass. The thickness, position and velocity of each point are taken from the thin shell model. The interior of the shell is filled with a uniform gas density and temperature consistent with the 3/2PV energy found from 1D rad-hydro calculations. 3D linked simulations compare favorably with integrated simulations of the entire implosion. Through generating synthetic diagnostic data, the model offers a method for quickly testing hypothetical sources of asymmetry and comparing with experiment. Prepared by LLNL under Contract DE-AC52-07NA27344.

Properties-Adjustable Alumina-Zirconia Nanolaminate Dielectric Fabricated by Spin-Coating.

PubMed

Peng, Junbiao; Wei, Jinglin; Zhu, Zhennan; Ning, Honglong; Cai, Wei; Lu, Kuankuan; Yao, Rihui; Tao, Hong; Zheng, Yanqiong; Lu, Xubing

2017-11-29

In this paper, an alumina-zirconia (Al₂O₃-ZrO₂) nanolaminate dielectric was fabricated by spin-coating and the performance was investigated. It was found that the properties of the dielectric can be adjusted by changing the content of Al₂O₃/ZrO₂ in nanolaminates: when the content of Al₂O₃ was higher than 50%, the properties of nanolaminates, such as the optical energy gap, dielectric strength (V ds ), capacitance density, and relative permittivity were relatively stable, while the change of these properties became larger when the content of Al₂O₃ was less than 50%. With the content of ZrO₂ varying from 50% to 100%, the variation of these properties was up to 0.482 eV, 2.12 MV/cm, 135.35 nF/cm², and 11.64, respectively. Furthermore, it was demonstrated that the dielectric strength of nanolaminates were influenced significantly by the number (n) of bilayers. Every increment of one Al₂O₃-ZrO 2 bilayer will enhance the dielectric strength by around 0.39 MV/cm (V ds ≈ 0.86 + 0.39n). This could be contributed to the amorphous alumina which interrupted the grain boundaries of zirconia.

Mechanical properties of metal-ceramic nanolaminates: Effect of constraint and temperature

DOE PAGES

Yang, Ling Wei; Mayer, Carl; Li, Nan; ...

2017-09-21

Al/SiC nanolaminates with equal nominal thicknesses of the Al and SiC layers (10, 25, 50 and 100 nm) were manufactured by magnetron sputtering. The mechanical properties were measured at 25 °C and 100 °C by means of nanoindentation and micropillar compression tests and the deformation mechanisms were analyzed by in situ micropillar compression tests in the transmission electron microscope. In addition, finite element simulations of both tests were carried out to ascertain the role played by the strength of the Al layers and by the elastic constraint of the ceramic layers on the plastic flow of Al in the mechanicalmore » response. It was found that the mechanical response was mainly controlled by the constraint during nanoindentation or micropillar compression tests of very thin layered (≈10 nm) laminates, while the influence of the strength of Al layers was not as critical. This behavior was reversed, however, for thick layered laminates (100 nm). Here, these mechanisms point to the different effects of layer thickness during nanoindentation and micropillar compression, at both temperatures, and showed the critical role played by constraint on the mechanical response of nanolaminates made of materials with a very large difference in the elasto-plastic properties.« less

Nanolaminated Permalloy Core for High-Flux, High-Frequency Ultracompact Power Conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, J; Kim, M; Galle, P

2013-09-01

Metallic magnetic materials have desirable magnetic properties, including high permeability, and high saturation flux density, when compared with their ferrite counterparts. However, eddy-current losses preclude their use in many switching converter applications, due to the challenge of simultaneously achieving sufficiently thin laminations such that eddy currents are suppressed (e.g., 500 nm-1 mu m for megahertz frequencies), while simultaneously achieving overall core thicknesses such that substantial power can be handled. A CMOS-compatible fabrication process based on robot-assisted sequential electrodeposition followed by selective chemical etching has been developed for the realization of a core of substantial overall thickness (tens to hundreds ofmore » micrometers) comprised of multiple, stacked permalloy (Ni80Fe20) nanolaminations. Tests of toroidal inductors with nanolaminated cores showed negligible eddy-current loss relative to total core loss even at a peak flux density of 0.5 T in the megahertz frequency range. To illustrate the use of these cores, a buck power converter topology is implemented with switching frequencies of 1-2 MHz. Power conversion efficiency greater than 85% with peak operating flux density of 0.3-0.5 T in the core and converter output power level exceeding 5 W was achieved.« less

Enceladus's crust as a non-uniform thin shell: I tidal deformations

NASA Astrophysics Data System (ADS)

Beuthe, Mikael

2018-03-01

The geologic activity at Enceladus's south pole remains unexplained, though tidal deformations are probably the ultimate cause. Recent gravity and libration data indicate that Enceladus's icy crust floats on a global ocean, is rather thin, and has a strongly non-uniform thickness. Tidal effects are enhanced by crustal thinning at the south pole, so that realistic models of tidal tectonics and dissipation should take into account the lateral variations of shell structure. I construct here the theory of non-uniform viscoelastic thin shells, allowing for depth-dependent rheology and large lateral variations of shell thickness and rheology. Coupling to tides yields two 2D linear partial differential equations of the fourth order on the sphere which take into account self-gravity, density stratification below the shell, and core viscoelasticity. If the shell is laterally uniform, the solution agrees with analytical formulas for tidal Love numbers; errors on displacements and stresses are less than 5% and 15%, respectively, if the thickness is less than 10% of the radius. If the shell is non-uniform, the tidal thin shell equations are solved as a system of coupled linear equations in a spherical harmonic basis. Compared to finite element models, thin shell predictions are similar for the deformations due to Enceladus's pressurized ocean, but differ for the tides of Ganymede. If Enceladus's shell is conductive with isostatic thickness variations, surface stresses are approximately inversely proportional to the local shell thickness. The radial tide is only moderately enhanced at the south pole. The combination of crustal thinning and convection below the poles can amplify south polar stresses by a factor of 10, but it cannot explain the apparent time lag between the maximum plume brightness and the opening of tiger stripes. In a second paper, I will study the impact of a non-uniform crust on tidal dissipation.

Reactive sputter deposition of metal oxide nanolaminates

NASA Astrophysics Data System (ADS)

Rubin Aita, Carolyn

2008-07-01

We discuss the reactive sputter deposition of metal oxide nanolaminates on unheated substrates using four archetypical examples: ZrO2 Al2O3, HfO2 Al2O3, ZrO2 Y2O3, and ZrO2 TiO2. The pseudobinary bulk phase diagrams corresponding to these nanolaminates represent three types of interfaces. I. Complete immiscibility (ZrO2 Al2O3 and HfO2 Al2O3). II. Complete miscibility (ZrO2 Y2O3). III. Limited miscibility without a common end-member lattice (ZrO2 TiO2). We found that, although reactive sputter deposition is a far-from-equilibrium process, thermodynamic considerations strongly influence both phase formation within layers and at interfaces. We show that pseudobinary phase diagrams can be used to predict interfacial cation mixing in the nanolaminates. However, size effects must be considered to predict specific structures. In the absence of pseudoepitaxy, size effects play a significant role in determining the nanocrystalline phases that form within a layer (e.g. tetragonal ZrO2, tetragonal HfO2, and orthorhombic HfO2) and at interfaces (e.g. monoclinic (Zr,Ti)O2). These phases are not bulk standard temperature and pressure phases. Their formation is understood in terms of self-assembly into the lowest energy structure in individual critical nuclei.

The theory of spherically symmetric thin shells in conformal gravity

NASA Astrophysics Data System (ADS)

Berezin, Victor; Dokuchaev, Vyacheslav; Eroshenko, Yury

The spherically symmetric thin shells are the nearest generalizations of the point-like particles. Moreover, they serve as the simple sources of the gravitational fields both in General Relativity and much more complex quadratic gravity theories. We are interested in the special and physically important case when all the quadratic in curvature tensor (Riemann tensor) and its contractions (Ricci tensor and scalar curvature) terms are present in the form of the square of Weyl tensor. By definition, the energy-momentum tensor of the thin shell is proportional to Diracs delta-function. We constructed the theory of the spherically symmetric thin shells for three types of gravitational theories with the shell: (1) General Relativity; (2) Pure conformal (Weyl) gravity where the gravitational part of the total Lagrangian is just the square of the Weyl tensor; (3) Weyl-Einstein gravity. The results are compared with these in General Relativity (Israel equations). We considered in detail the shells immersed in the vacuum. Some peculiar properties of such shells are found. In particular, for the traceless ( = massless) shell, it is shown that their dynamics cannot be derived from the matching conditions and, thus, is completely arbitrary. On the contrary, in the case of the Weyl-Einstein gravity, the trajectory of the same type of shell is completely restored even without knowledge of the outside solution.

Thin-shell wormholes in rainbow gravity

NASA Astrophysics Data System (ADS)

Amirabi, Z.; Halilsoy, M.; Mazharimousavi, S. Habib

2018-03-01

At the Planck scale of length ˜10‑35 m where the energy is comparable with the Planck energy, the quantum gravity corrections to the classical background spacetime results in gravity’s rainbow or rainbow gravity. In this modified theory of gravity, geometry depends on the energy of the test particle used to probe the spacetime, such that in the low energy limit, it yields the standard general relativity. In this work, we study the thin-shell wormholes in the spherically symmetric rainbow gravity. We find the corresponding properties in terms of the rainbow functions which are essential in the rainbow gravity and the stability of such thin-shell wormholes are investigated. Particularly, it will be shown that there are exact solutions in which high energy particles crossing the throat will encounter less amount of total exotic matter. This may be used as an advantage over general relativity to reduce the amount of exotic matter.

Dynamics of thin-shell wormholes with different cosmological models

NASA Astrophysics Data System (ADS)

Sharif, Muhammad; Mumtaz, Saadia

This work is devoted to investigate the stability of thin-shell wormholes in Einstein-Hoffmann-Born-Infeld electrodynamics. We also study the attractive and repulsive characteristics of these configurations. A general equation-of-state is considered in the form of linear perturbation which explores the stability of the respective wormhole solutions. We assume Chaplygin, linear and logarithmic gas models to study exotic matter at thin-shell and evaluate stability regions for different values of the involved parameters. It is concluded that the Hoffmann-Born-Infeld parameter and electric charge enhance the stability regions.

Perturbative dynamics of thin-shell wormholes beyond general relativity: An alternative approach

NASA Astrophysics Data System (ADS)

Rubín de Celis, Emilio; Tomasini, Cecilia; Simeone, Claudio

Recent studies relating the approximations for the equations-of-state for thin shells and their consequent perturbative evolution are extended to thin-shell wormholes in theories beyond general relativity and more than four spacetime dimensions. The assumption of equations-of-state of the same form for static and slowly evolving shells appears as a strong restriction excluding the possibility of oscillatory evolutions. Then the new results considerably differ from previous ones obtained within the usual linearized approach.

Fabrication and characterization of optical sensors using metallic core-shell thin film nanoislands for ozone detection

NASA Astrophysics Data System (ADS)

Addanki, Satish; Nedumaran, D.

2017-07-01

Core-Shell nanostructures play a vital role in the sensor field owing to their performance improvements in sensing characteristics and well-established synthesis procedures. These nanostructures can be ingeniously tuned to achieve tailored properties for a particular application of interest. In this work, an Ag-Au core-shell thin film nanoislands with APTMS (3-Aminopropyl trimethoxysilane) and PVA (Polyvinyl alcohol) binding agents was modeled, synthesized and characterized. The simulation results were used to fabricate the sensor through chemical route. The results of this study confirmed that the APTMS based Ag-Au core-shell thin film nanoislands offered a better performance over the PVA based Ag-Au core-shell thin film nanoislands. Also, the APTMS based Ag-Au core-shell thin film nanoislands exhibited better sensitivity towards ozone sensing over the other types, viz., APTMS/PVA based Au-Ag core-shell and standalone Au/Ag thin film nanoislands.

Axisymmetric thermoviscoelastoplastic state of thin laminated shells made of a damageable material

NASA Astrophysics Data System (ADS)

Galishin, A. Z.

2008-04-01

A technique for the determination of the axisymmetric thermoviscoelastoplastic state of laminated thin shells made of a damageable material is developed. The technique is based on the kinematic equations of the theory of thin shells that account for transverse shear strains. The thermoviscoplastic equations, which describe the deformation of a shell element along paths of small curvature, are used as the constitutive equations. The equivalent stress that appears in the kinetic equations of damage and creep is determined from a failure criterion that accounts for the stress mode. The thermoviscoplastic deformation of a two-layer shell that models an element of a rocket engine nozzle is considered as an example

Repeated crossing of two concentric spherical thin-shells with charge

NASA Astrophysics Data System (ADS)

Mazharimousavi, S. Habib; Halilsoy, M.

Interaction/collision of two concentric spherical thin-shells of linear fluid resulting in collapse has been considered recently. We show that addition of finely tuned electric charges on the shells apart from the cosmological constant serves to delay the collapse indefinitely, yielding an ever colliding system of two concentric fluid shells. Given the finely tuned charges, this provides an example of a perpetual two-body motion in general relativity.

Rollable Thin Shell Composite-Material Paraboloidal Mirrors

NASA Technical Reports Server (NTRS)

Meinel, Aden; Meinel, Marjorie; Romeo, Robert

2003-01-01

An experiment and calculation have demonstrated the feasibility of a technique of compact storage of paraboloidal mirrors made of thin composite-material (multiple layers of carbon fiber mats in a polymeric matrix) shells coated with metal for reflectivity. Such mirrors are under consideration as simple, lightweight alternatives to the heavier, more complex mirrors now used in space telescopes. They could also be used on Earth in applications in which gravitational sag of the thin shells can be tolerated. The present technique is essentially the same as that used to store large maps, posters, tapestries, and similar objects: One simply rolls up the mirror to a radius small enough to enable the insertion of the mirror in a protective cylindrical case. Provided that the stress associated with rolling the mirror is not so large as to introduce an appreciable amount of hysteresis, the mirror can be expected to spring back to its original shape, with sufficient precision to perform its intended optical function, when unrolled from storage.

Stability of cylindrical thin shell wormholes supported by MGCG in f(R) gravity

NASA Astrophysics Data System (ADS)

Eid, A.

2018-02-01

In the framework of f(R) modified theory of gravity, the dynamical equations of motion of a cylindrical thin shell wormholes supported by a modified generalized Chaplygin gas are constructed, using the cut and paste scheme (Darmois Israel formalism). The mechanical stability analysis of a cylindrical thin shell wormhole is discussed using a linearized radial perturbation around static solutions at the wormhole throat. The presence of stable static solutions depends on the suitable values of some parameters of dynamical shell.

Some New Problems on Shells and Thin Structures

NASA Technical Reports Server (NTRS)

Vlasov, V. S.

1949-01-01

Cylindrical shells of arbitrary section, reinforced by longitudinal and transverse members (stringers and ribs) are considered by us, for a sufficiently close spacing of the ribs, as in our previously published papers (references 1 end 2), as thin-walled orthotropic spatial systems at the cross-sections of which only axial (normal and shearing) forces can arise. The longitudinal bending and twisting moments, due to their weak effect on the stress state of the shell, are taken equal to zero. Along the longitudinal sections of the shell there may arise transverse forces in addition to the normal d shearing forces. Under the so-called static assumptions there is taken for the computation model of the shell a thin-walled spatial system consisting along its length (along a generator) of an infinite number of elementary strips capable of bending. Each of these strips is likened to a curved rod operating in each of its sections not only in tension (compression)but also in transverse bending and shear. The interaction between two adjoining transverse strips in the shell expresses itself in the transmission from one strip to the other of only the normal and shearing stresses. The static structure of the computation model here described is shown in figure 1, where the connections through which the normal and shearing stresses transmitted from one transverse strip to smother are indicated schematically by the rods located in the middle surface of the shell. In addition to the static hypothesis we introduce also geometric hypotheses. According to the latter the elongational deformations of the shell along lines parallel to the generator of its middle surface and the shear deformations in the middle surface, as ma+gitudes having . little effect on the state of the fundamental internal forces of the shell, are taken equal to zero. The deformations of the shell in our computational model are such that in the first place the lines of this surface perpendicular to the generator are

Optical figuring specifications for thin shells to be used in adaptive telescope mirrors

NASA Astrophysics Data System (ADS)

Riccardi, A.

2006-06-01

The present work describes the guidelines to define the optical figuring specifications for optical manufacturing of thin shells in terms of figuring error power spectrum (and related rms vs scale distributon) to be used in adaptive optics correctors with force actuators like Deformable Secondary Mirrors (DSM). In particular the numerical example for a thin shell for a VLT DSM is considered.

Low-temperature remote plasma enhanced atomic layer deposition of ZrO2/zircone nanolaminate film for efficient encapsulation of flexible organic light-emitting diodes

PubMed Central

Chen, Zheng; Wang, Haoran; Wang, Xiao; Chen, Ping; Liu, Yunfei; Zhao, Hongyu; Zhao, Yi; Duan, Yu

2017-01-01

Encapsulation is essential to protect the air-sensitive components of organic light-emitting diodes (OLEDs) such as active layers and cathode electrodes. In this study, hybrid zirconium inorganic/organic nanolaminates were fabricated using remote plasma enhanced atomic layer deposition (PEALD) and molecular layer deposition at a low temperature. The nanolaminate serves as a thin-film encapsulation layer for OLEDs. The reaction mechanism of PEALD process was investigated using an in-situ quartz crystal microbalance (QCM) and in-situ quadrupole mass spectrometer (QMS). The bonds present in the films were determined by Fourier transform infrared spectroscopy. The primary reaction byproducts in PEALD, such as CO, CO2, NO, H2O, as well as the related fragments during the O2 plasma process were characterized using the QMS, indicating a combustion-like reaction process. The self-limiting nature and growth mechanisms of the ZrO2 during the complex surface chemical reaction of the ligand and O2 plasma were monitored using the QCM. The remote PEALD ZrO2/zircone nanolaminate structure prolonged the transmission path of water vapor and smooth surface morphology. Consequently, the water barrier properties were significantly improved (reaching 3.078 × 10−5 g/m2/day). This study also shows that flexible OLEDs can be successfully encapsulated to achieve a significantly longer lifetime. PMID:28059160

Low-temperature remote plasma enhanced atomic layer deposition of ZrO2/zircone nanolaminate film for efficient encapsulation of flexible organic light-emitting diodes.

PubMed

Chen, Zheng; Wang, Haoran; Wang, Xiao; Chen, Ping; Liu, Yunfei; Zhao, Hongyu; Zhao, Yi; Duan, Yu

2017-01-06

Encapsulation is essential to protect the air-sensitive components of organic light-emitting diodes (OLEDs) such as active layers and cathode electrodes. In this study, hybrid zirconium inorganic/organic nanolaminates were fabricated using remote plasma enhanced atomic layer deposition (PEALD) and molecular layer deposition at a low temperature. The nanolaminate serves as a thin-film encapsulation layer for OLEDs. The reaction mechanism of PEALD process was investigated using an in-situ quartz crystal microbalance (QCM) and in-situ quadrupole mass spectrometer (QMS). The bonds present in the films were determined by Fourier transform infrared spectroscopy. The primary reaction byproducts in PEALD, such as CO, CO 2 , NO, H 2 O, as well as the related fragments during the O 2 plasma process were characterized using the QMS, indicating a combustion-like reaction process. The self-limiting nature and growth mechanisms of the ZrO 2 during the complex surface chemical reaction of the ligand and O 2 plasma were monitored using the QCM. The remote PEALD ZrO 2 /zircone nanolaminate structure prolonged the transmission path of water vapor and smooth surface morphology. Consequently, the water barrier properties were significantly improved (reaching 3.078 × 10 -5  g/m 2 /day). This study also shows that flexible OLEDs can be successfully encapsulated to achieve a significantly longer lifetime.

Low-temperature remote plasma enhanced atomic layer deposition of ZrO2/zircone nanolaminate film for efficient encapsulation of flexible organic light-emitting diodes

NASA Astrophysics Data System (ADS)

Chen, Zheng; Wang, Haoran; Wang, Xiao; Chen, Ping; Liu, Yunfei; Zhao, Hongyu; Zhao, Yi; Duan, Yu

2017-01-01

Encapsulation is essential to protect the air-sensitive components of organic light-emitting diodes (OLEDs) such as active layers and cathode electrodes. In this study, hybrid zirconium inorganic/organic nanolaminates were fabricated using remote plasma enhanced atomic layer deposition (PEALD) and molecular layer deposition at a low temperature. The nanolaminate serves as a thin-film encapsulation layer for OLEDs. The reaction mechanism of PEALD process was investigated using an in-situ quartz crystal microbalance (QCM) and in-situ quadrupole mass spectrometer (QMS). The bonds present in the films were determined by Fourier transform infrared spectroscopy. The primary reaction byproducts in PEALD, such as CO, CO2, NO, H2O, as well as the related fragments during the O2 plasma process were characterized using the QMS, indicating a combustion-like reaction process. The self-limiting nature and growth mechanisms of the ZrO2 during the complex surface chemical reaction of the ligand and O2 plasma were monitored using the QCM. The remote PEALD ZrO2/zircone nanolaminate structure prolonged the transmission path of water vapor and smooth surface morphology. Consequently, the water barrier properties were significantly improved (reaching 3.078 × 10-5 g/m2/day). This study also shows that flexible OLEDs can be successfully encapsulated to achieve a significantly longer lifetime.

A thin-shelled reptile from the Late Triassic of North America and the origin of the turtle shell.

PubMed

Joyce, Walter G; Lucas, Spencer G; Scheyer, Torsten M; Heckert, Andrew B; Hunt, Adrian P

2009-02-07

A new, thin-shelled fossil from the Upper Triassic (Revueltian: Norian) Chinle Group of New Mexico, Chinlechelys tenertesta, is one of the most primitive known unambiguous members of the turtle stem lineage. The thin-shelled nature of the new turtle combined with its likely terrestrial habitat preference hint at taphonomic filters that basal turtles had to overcome before entering the fossil record. Chinlechelys tenertesta possesses neck spines formed by multiple osteoderms, indicating that the earliest known turtles were covered with rows of dermal armour. More importantly, the primitive, vertically oriented dorsal ribs of the new turtle are only poorly associated with the overlying costal bones, indicating that these two structures are independent ossifications in basal turtles. These novel observations lend support to the hypothesis that the turtle shell was originally a complex composite in which dermal armour fused with the endoskeletal ribs and vertebrae of an ancestral lineage instead of forming de novo. The critical shell elements (i.e. costals and neurals) are thus not simple outgrowths of the bone of the endoskeletal elements as has been hypothesized from some embryological observations.

Enhanced Mechanical Properties of Graphene (Reduced Graphene Oxide)/Aluminum Composites with a Bioinspired Nanolaminated Structure.

PubMed

Li, Zan; Guo, Qiang; Li, Zhiqiang; Fan, Genlian; Xiong, Ding-Bang; Su, Yishi; Zhang, Jie; Zhang, Di

2015-12-09

Bulk graphene (reduced graphene oxide)-reinforced Al matrix composites with a bioinspired nanolaminated microstructure were fabricated via a composite powder assembly approach. Compared with the unreinforced Al matrix, these composites were shown to possess significantly improved stiffness and tensile strength, and a similar or even slightly higher total elongation. These observations were interpreted by the facilitated load transfer between graphene and the Al matrix, and the extrinsic toughening effect as a result of the nanolaminated microstructure.

Electronic quantization in dielectric nanolaminates

NASA Astrophysics Data System (ADS)

Willemsen, T.; Geerke, P.; Jupé, M.; Gallais, L.; Ristau, D.

2016-12-01

The scientific background in the field of the laser induced damage processes in optical coatings has been significantly extended during the last decades. Especially for the ultra-short pulse regime a clear correlation between the electronic material parameters and the laser damage threshold could be demonstrated. In the present study, the quantization in nanolaminates is investigated to gain a deeper insight into the behavior of the blue shift of the bandgap in specific coating materials as well as to find approximations for the effective mass of the electrons. The theoretical predictions are correlated to the measurements.

Thick or Thin Ice Shell on Europa?

NASA Technical Reports Server (NTRS)

2007-01-01

Scientists are all but certain that Europa has an ocean underneath its icy surface, but they do not know how thick this ice might be. This artist concept illustrates two possible cut-away views through Europa's ice shell. In both, heat escapes, possibly volcanically, from Europa's rocky mantle and is carried upward by buoyant oceanic currents. If the heat from below is intense and the ice shell is thin enough (left), the ice shell can directly melt, causing what are called 'chaos' on Europa, regions of what appear to be broken, rotated and tilted ice blocks. On the other hand, if the ice shell is sufficiently thick (right), the less intense interior heat will be transferred to the warmer ice at the bottom of the shell, and additional heat is generated by tidal squeezing of the warmer ice. This warmer ice will slowly rise, flowing as glaciers do on Earth, and the slow but steady motion may also disrupt the extremely cold, brittle ice at the surface. Europa is no larger than Earth's moon, and its internal heating stems from its eccentric orbit about Jupiter, seen in the distance. As tides raised by Jupiter in Europa's ocean rise and fall, they may cause cracking, additional heating and even venting of water vapor into the airless sky above Europa's icy surface. (Artwork by Michael Carroll.)

Asymptotic approximations for pure bending of thin cylindrical shells

NASA Astrophysics Data System (ADS)

Coman, Ciprian D.

2017-08-01

A simplified partial wrinkling scenario for in-plane bending of thin cylindrical shells is explored by using several asymptotic strategies. The eighth-order boundary eigenvalue problem investigated here originates in the Donnel-Mushtari-Vlasov shallow shell theory coupled with a linear membrane pre-bifurcation state. It is shown that the corresponding neutral stability curve is amenable to a detailed asymptotic analysis based on the method of multiple scales. This is further complemented by an alternative WKB approximation that provides comparable information with significantly less effort.

Stability of thin shell wormholes with a modified Chaplygin gas in Einstein-Hoffman-Born-Infeld theory

NASA Astrophysics Data System (ADS)

Eid, A.

2017-11-01

In the framework of Darmois-Israel formalism, the dynamics of motion equations of spherically symmetric thin shell wormholes that are supported by a modified Chaplygin gas in Einstein-Hoffman-Born-Infeld theory are constructed. The stability analysis of a thin shell wormhole is also discussed using a linearized radial perturbation around static solutions at the wormhole throat. The existence of stable static solutions depends on the value of some parameters of dynamical shell.

A thin-shelled reptile from the Late Triassic of North America and the origin of the turtle shell

PubMed Central

Joyce, Walter G.; Lucas, Spencer G.; Scheyer, Torsten M.; Heckert, Andrew B.; Hunt, Adrian P.

2008-01-01

A new, thin-shelled fossil from the Upper Triassic (Revueltian: Norian) Chinle Group of New Mexico, Chinlechelys tenertesta, is one of the most primitive known unambiguous members of the turtle stem lineage. The thin-shelled nature of the new turtle combined with its likely terrestrial habitat preference hint at taphonomic filters that basal turtles had to overcome before entering the fossil record. Chinlechelys tenertesta possesses neck spines formed by multiple osteoderms, indicating that the earliest known turtles were covered with rows of dermal armour. More importantly, the primitive, vertically oriented dorsal ribs of the new turtle are only poorly associated with the overlying costal bones, indicating that these two structures are independent ossifications in basal turtles. These novel observations lend support to the hypothesis that the turtle shell was originally a complex composite in which dermal armour fused with the endoskeletal ribs and vertebrae of an ancestral lineage instead of forming de novo. The critical shell elements (i.e. costals and neurals) are thus not simple outgrowths of the bone of the endoskeletal elements as has been hypothesized from some embryological observations. PMID:18842543

Low-Temperature Fabrication of Robust, Transparent, and Flexible Thin-Film Transistors with a Nanolaminated Insulator.

PubMed

Kwon, Jeong Hyun; Park, Junhong; Lee, Myung Keun; Park, Jeong Woo; Jeon, Yongmin; Shin, Jeong Bin; Nam, Minwoo; Kim, Choong-Ki; Choi, Yang-Kyu; Choi, Kyung Cheol

2018-05-09

The lack of reliable, transparent, and flexible electrodes and insulators for applications in thin-film transistors (TFTs) makes it difficult to commercialize transparent, flexible TFTs (TF-TFTs). More specifically, conventional high process temperatures and the brittleness of these elements have been hurdles in developing flexible substrates vulnerable to heat. Here, we propose electrode and insulator fabrication techniques considering process temperature, transmittance, flexibility, and environmental stability. A transparent and flexible indium tin oxide (ITO)/Ag/ITO (IAI) electrode and an Al 2 O 3 /MgO (AM)-laminated insulator were optimized at the low temperature of 70 °C for the fabrication of TF-TFTs on a polyethylene terephthalate (PET) substrate. The optimized IAI electrode with a sheet resistance of 7 Ω/sq exhibited the luminous transmittance of 85.17% and maintained its electrical conductivity after exposure to damp heat conditions because of an environmentally stable ITO capping layer. In addition, the electrical conductivity of IAI was maintained after 10 000 bending cycles with a tensile strain of 3% because of the ductile Ag film. In the metal/insulator/metal structure, the insulating and mechanical properties of the optimized AM-laminated film deposited at 70 °C were significantly improved because of the highly dense nanolaminate system, compared to those of the Al 2 O 3 film deposited at 70 °C. In addition, the amorphous indium-gallium-zinc oxide (a-IGZO) was used as the active channel for TF-TFTs because of its excellent chemical stability. In the environmental stability test, the ITO, a-IGZO, and AM-laminated films showed the excellent environmental stability. Therefore, our IGZO-based TFT with IAI electrodes and the 70 °C AM-laminated insulator was fabricated to evaluate robustness, transparency, flexibility, and process temperature, resulting in transfer characteristics comparable to those of an IGZO-based TFT with a 150 °C Al 2 O 3

Scanning the parameter space of collapsing rotating thin shells

NASA Astrophysics Data System (ADS)

Rocha, Jorge V.; Santarelli, Raphael

2018-06-01

We present results of a comprehensive study of collapsing and bouncing thin shells with rotation, framing it in the context of the weak cosmic censorship conjecture. The analysis is based on a formalism developed specifically for higher odd dimensions that is able to describe the dynamics of collapsing rotating shells exactly. We analyse and classify a plethora of shell trajectories in asymptotically flat spacetimes. The parameters varied include the shell’s mass and angular momentum, its radial velocity at infinity, the (linear) equation-of-state parameter and the spacetime dimensionality. We find that plunges of rotating shells into black holes never produce naked singularities, as long as the matter shell obeys the weak energy condition, and so respects cosmic censorship. This applies to collapses of dust shells starting from rest or with a finite velocity at infinity. Not even shells with a negative isotropic pressure component (i.e. tension) lead to the formation of naked singularities, as long as the weak energy condition is satisfied. Endowing the shells with a positive isotropic pressure component allows for the existence of bouncing trajectories satisfying the dominant energy condition and fully contained outside rotating black holes. Otherwise any turning point occurs always inside the horizon. These results are based on strong numerical evidence from scans of numerous sections in the large parameter space available to these collapsing shells. The generalisation of the radial equation of motion to a polytropic equation-of-state for the matter shell is also included in an appendix.

Laminated Thin Shell Structures Subjected to Free Vibration in a Hygrothermal Environment

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Guptill, James D.

1994-01-01

Parametric studies were performed to assess the effects of various parameters on the free-vibration behavior (natural frequencies) of (+/- theta)(sub 2) angle-ply, fiber composite, thin shell structures in a hygrothermal environment. Knowledge of the natural frequencies of structures is important in considering their response to various kinds of excitation, especially when structures and force systems are complex and when excitations are not periodic. The three dimensional, finite element structural analysis computer code CSTEM was used in the Cray YMP computer environment. The fiber composite shell was assumed to be cylindrical and made from T300 graphite fibers embedded in an intermediate-modulus, high-strength matrix. The following parameters were investigated: the length and the laminate thickness of the shell, the fiber orientation, the fiber volume fraction, the temperature profile through the thickness of the laminate, and laminates with different ply thicknesses. The results indicate that the fiber orientation and the length of the laminated shell had significant effects on the natural frequencies. The fiber volume fraction, the laminate thickness, and the temperature profile through the shell thickness had weak effects on the natural frequencies. Finally, the laminates with different ply thicknesses had an insignificant influence on the behavior of the vibrated laminated shell. Also, a single through-the-thickness, eight-node, three dimensional composite finite element analysis appears to be sufficient for investigating the free-vibration behavior of thin, composite, angle-ply shell structures.

A Simplified Method of Elastic-Stability Analysis for Thin Cylindrical Shells

NASA Technical Reports Server (NTRS)

Batdorf, S B

1947-01-01

This paper develops a new method for determining the buckling stresses of cylindrical shells under various loading conditions. In part I, the equation for the equilibrium of cylindrical shells introduced by Donnell in NACA report no. 479 to find the critical stresses of cylinders in torsion is applied to find critical stresses for cylinders with simply supported edges under other loading conditions. In part II, a modified form of Donnell's equation for the equilibrium of thin cylindrical shells is derived which is equivalent to Donnell's equation but has certain advantages in physical interpretation and in ease of solution, particularly in the case of shells having clamped edges. The question of implicit boundary conditions is also considered.

Asymmetric thin-shell wormholes

NASA Astrophysics Data System (ADS)

Forghani, S. Danial; Mazharimousavi, S. Habib; Halilsoy, Mustafa

2018-06-01

Spacetime wormholes in isotropic spacetimes are represented traditionally by embedding diagrams which were symmetric paraboloids. This mirror symmetry, however, can be broken by considering different sources on different sides of the throat. This gives rise to an asymmetric thin-shell wormhole, whose stability is studied here in the framework of the linear stability analysis. Having constructed a general formulation, using a variable equation of state and related junction conditions, the results are tested for some examples of diverse geometries such as the cosmic string, Schwarzschild, Reissner-Nordström and Minkowski spacetimes. Based on our chosen spacetimes as examples, our finding suggests that symmetry is an important factor to make a wormhole more stable. Furthermore, the parameter γ , which corresponds to the radius dependency of the pressure on the wormholes's throat, can affect the stability in a great extent.

Relativistic Bose-Einstein condensates thin-shell wormholes

NASA Astrophysics Data System (ADS)

Richarte, M. G.; Salako, I. G.; Graça, J. P. Morais; Moradpour, H.; Övgün, Ali

2017-10-01

We construct traversable thin-shell wormholes which are asymptotically Ads/dS applying the cut and paste procedure for the case of an acoustic metric created by a relativistic Bose-Einstein condensate. We examine several definitions of the flare-out condition along with the violation or not of the energy conditions for such relativistic geometries. Under reasonable assumptions about the equation of state of the matter located at the shell, we concentrate on the mechanical stability of wormholes under radial perturbation preserving the original spherical symmetry. To do so, we consider linearized perturbations around static solutions. We obtain that dS acoustic wormholes remain stable under radial perturbations as long as they have small radius; such wormholes with finite radius do not violate the strong/null energy condition. Besides, we show that stable Ads wormhole satisfy some of the energy conditions whereas unstable Ads wormhole with large radii violate them.

Vibrations of a thin cylindrical shell stiffened by rings with various stiffness

NASA Astrophysics Data System (ADS)

Nesterchuk, G. A.

2018-05-01

The problem of vibrations of a thin-walled elastic cylindrical shell reinforced by frames of different rigidity is investigated. The solution for the case of the clamped shell edges was obtained by asymptotic methods and refined by the finite element method. Rings with zero eccentricity and stiffness varying along the generatrix of the shell cylinder are considered. Varying the optimal coefficients of the distribution functions of the rigidity of the frames and finding more precise parameters makes it possible to find correction factors for analytical formulas of approximate calculation.

Dynamics of test particles in thin-shell wormhole spacetimes

NASA Astrophysics Data System (ADS)

Diemer, Valeria; Smolarek, Elena

2013-09-01

Geodesic motion in traversable Schwarzschild and Kerr thin-shell wormholes constructed by the cut-and-paste method introduced by Visser (1989 Nucl. Phys. B 328 203; 1995 Wormholes: from Einstein to Hawking (Woodbury, MN: American Institute of Physics)) is studied. The orbits are calculated exactly in terms of elliptic functions and visualized with the help of embedding diagrams.

Requirements for Weatherproofing Thin Shell Concrete Roofs. Proceedings of the Conference of Building Research Institute, Division of Engineering and Industrial Research (Spring 1961).

ERIC Educational Resources Information Center

National Academy of Sciences - National Research Council, Washington, DC.

Topics discussed include--(1) requirements for weatherproofing and sealant materials for thin shell concrete roof, (2) effect of physical factors on weatherproofing of thin shell concrete roofs, (3) problems and limitations imposed by thin shell concrete roofs and their effect on weatherproofing and sealant materials, and (4) properties and uses…

Vibration of Shells

NASA Technical Reports Server (NTRS)

Leissa, A. W.

1973-01-01

The vibrational characteristics and mechanical properties of shell structures are discussed. The subjects presented are: (1) fundamental equations of thin shell theory, (2) characteristics of thin circular cylindrical shells, (3) complicating effects in circular cylindrical shells, (4) noncircular cylindrical shell properties, (5) characteristics of spherical shells, and (6) solution of three-dimensional equations of motion for cylinders.

Large amplitude flexural vibration of thin elastic flat plates and shells

NASA Technical Reports Server (NTRS)

Pandalia, K. A. V.

1972-01-01

The general equations governing the large amplitude flexural vibration of any thin elastic shell using curvilinear orthogonal coordinates are derived and consist of two coupled, nonlinear, partial differential equations in the normal displacement w and the stress function F. From these equations, the governing equations for the case of shells of revolution or flat plates can be readily obtained as special cases. The material of the shell or plate is isotropic and homogeneous and Hooke's law for the two-dimensional case is valid. It is suggested that the difference between the hardening type of nonlinearity in the case of flat plates and straight beams and the softening type of nonlinearity in the case of shells and rings can, in general, be traced to the amount of curvature present in the underformed median surface of the structure concerned.

Computational Simulation of Damage Progression of Composite Thin Shells Subjected to Mechanical Loads

NASA Technical Reports Server (NTRS)

Gotsis, P. K.; Chamis, C. C.; Minnetyan, L.

1996-01-01

Defect-free and defected composite thin shells with ply orientation (90/0/+/-75) made of graphite/epoxy are simulated for damage progression and fracture due to internal pressure and axial loading. The thin shells have a cylindrical geometry with one end fixed and the other free. The applied load consists of an internal pressure in conjunction with an axial load at the free end, the cure temperature was 177 C (350 F) and the operational temperature was 21 C (70 F). The residual stresses due to the processing are taken into account. Shells with defect and without defects were examined by using CODSTRAN an integrated computer code that couples composite mechanics, finite element and account for all possible failure modes inherent in composites. CODSTRAN traces damage initiation, growth, accumulation, damage propagation and the final fracture of the structure. The results show that damage initiation started with matrix failure while damage/fracture progression occurred due to additional matrix failure and fiber fracture. The burst pressure of the (90/0/+/- 75) defected shell was 0.092% of that of the free defect. Finally the results of the damage progression of the (90/0/+/- 75), defective composite shell was compared with the (90/0/+/- theta, where theta = 45 and 60, layup configurations. It was shown that the examined laminate (90/0/+/- 75) has the least damage tolerant of the two compared defective shells with the (90/0/+/- theta), theta = 45 and 60 laminates.

Strain fields induced by kink band propagation in Cu-Nb nanolaminate composites

DOE PAGES

Nizolek, T. J.; Begley, M. R.; McCabe, R. J.; ...

2017-07-01

Kink band formation is a common deformation mode for anisotropic materials and has been observed in polymer matrix fiber composites, single crystals, geological formations, and recently in metallic nanolaminates. While numerous studies have been devoted to kink band formation, the majority do not consider the often rapid and unstable process of kink band propagation. In this paper, we take advantage of stable kink band formation in Cu-Nb nanolaminates to quantitatively map the local strain fields surrounding a propagating kink band during uniaxial compression. Kink bands are observed to initiate at specimen edges, propagate across the sample during a rising globalmore » stress, and induce extended strain fields in the non-kinked material surrounding the propagating kink band. Finally, it is proposed that these stress/strain fields significantly contribute to the total energy dissipated during kinking and, analogous to crack tip stress/strain fields, influence the direction of kink propagation and therefore the kink band inclination angle.« less

Fabrication of Nanolaminates with Ultrathin Nanolayers Using Atomic Layer Deposition: Nucleation & Growth Issues

DTIC Science & Technology

2009-02-01

Tecnologia de Superficies y Materiales (SMCTSM), XXVII Congreso Nacional, Oaxaca, Oaxaca, Mexico, September 26, 2007. 26. "Atomic Layer Deposition of...Nanolaminates: Fabrication and Properties" (Plenary Lecture), Sociedad Mexicana de Ciencia y Tecnologia de Superficies y Materiales (SMCTSM), XXVII

Free Vibration of Fiber Composite Thin Shells in a Hot Environment

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Guptill, James D.

1995-01-01

Results are presented of parametric studies to assess the effects of various parameters on the free vibration behavior (natural frequencies) of (plus or minus theta)2, angle-ply fiber composite thin shells in a hot environment. These results were obtained by using a three-dimensional finite element structural analysis computer code. The fiber composite shell is assumed to be cylindrical and made from T-300 graphite fibers embedded in an intermediate-modulus high-strength matrix (IMHS). The residual stresses induced into the laminated structure during curing are taken into account. The following parameters are investigated: the length and the thickness of the shell, the fiber orientations, the fiber volume fraction, the temperature profile through the thickness of the laminate and the different ply thicknesses. Results obtained indicate that: the fiber orientations and the length of the laminated shell had significant effect on the natural frequencies. The fiber volume fraction, the laminate thickness and the temperature profile through the shell thickness had a weak effect on the natural frequencies. Finally, the laminates with different ply thicknesses had insignificant influence on the behavior of the vibrated laminated shell.

Spherical thin-shell wormholes and modified Chaplygin gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharif, M.; Azam, M., E-mail: msharif.math@pu.edu.pk, E-mail: azammath@gmail.com

2013-05-01

The purpose of this paper is to construct spherical thin-shell wormhole solutions through cut and paste technique and investigate the stability of these solutions in the vicinity of modified Chaplygin gas. The Darmois-Israel formalism is used to formulate the stresses of the surface concentrating the exotic matter. We explore the stability of the wormhole solutions by using the standard potential method. We conclude that there exist more stable as well as unstable solutions than the previous study with generalized Chaplygin gas [19].

Atomic layer deposited high-k nanolaminate capacitors

NASA Astrophysics Data System (ADS)

Smith, S. W.; McAuliffe, K. G.; Conley, J. F., Jr.

2010-10-01

Al 2O 3-Ta 2O 5 nanolaminate films were prepared via atomic layer deposition (ALD) on silicon with a single overall composition and thickness, but with a varying number of Al 2O 3/Ta 2O 5 bilayers. The composition of the films was roughly 57% Al 2O 3 and 43% Ta 2O 5 and the total film thickness was held at ˜58 nm, while the number of bilayers was varied from 3 to 192 by changing the target bilayer thickness from ˜19.2 nm to ˜0.3 nm. Varying the number of bilayers was found to impact electrical properties. Although, almost all laminate films exhibited leakage, breakdown, hysteresis, and overall dielectric constant intermediate between pure Al 2O 3 and Ta 2O 5 films, laminates with few bilayers exhibited leakage current density lower than Al 2O 3 over the range of ˜3.5-4.5 MV/cm. Select samples annealed at temperatures from 400 to 900 °C were compared with as-deposited laminates. Annealing the laminate films at low temperatures improved leakage and breakdown while higher temperature anneals degraded both leakage and breakdown but improved the effective dielectric constant. A figure of merit was used to evaluate the overall ability of the various films to store charge. It was found that the few bilayer laminates were ranked higher than the many bilayer laminates as well as above both the pure Ta 2O 5 and pure Al 2O 3 films. These results indicate that even for a fixed overall composition, the electrical properties of a nanolaminate can be adjusted by varying the number of bilayers.

Quantum corrected Schwarzschild thin-shell wormhole

NASA Astrophysics Data System (ADS)

Jusufi, Kimet

2016-11-01

Recently, Ali and Khalil (Nucl Phys B, 909, 173-185, 2016), based on Bohmian quantum mechanics, derived a quantum corrected version of the Schwarzschild metric. In this paper, we construct a quantum corrected Schwarzschild thin-shell wormhole (QSTSW) and investigate the stability of this wormhole. First we compute the surface stress at the wormhole throat by applying the Darmois-Israel formalism to the modified Schwarzschild metric and show that exotic matter is required at the throat to keep the wormhole stable. We then study the stability analysis of the wormhole by considering phantom-energy for the exotic matter, generalized Chaplygin gas (GCG), and the linearized stability analysis. It is argued that quantum corrections can affect the stability domain of the wormhole.

LQR Control of Thin Shell Dynamics: Formulation and Numerical Implementation

NASA Technical Reports Server (NTRS)

delRosario, R. C. H.; Smith, R. C.

1997-01-01

A PDE-based feedback control method for thin cylindrical shells with surface-mounted piezoceramic actuators is presented. Donnell-Mushtari equations modified to incorporate both passive and active piezoceramic patch contributions are used to model the system dynamics. The well-posedness of this model and the associated LQR problem with an unbounded input operator are established through analytic semigroup theory. The model is discretized using a Galerkin expansion with basis functions constructed from Fourier polynomials tensored with cubic splines, and convergence criteria for the associated approximate LQR problem are established. The effectiveness of the method for attenuating the coupled longitudinal, circumferential and transverse shell displacements is illustrated through a set of numerical examples.

Tidal deformability and I-Love-Q relations for gravastars with polytropic thin shells

NASA Astrophysics Data System (ADS)

Uchikata, Nami; Yoshida, Shijun; Pani, Paolo

2016-09-01

The moment of inertia, the spin-induced quadrupole moment, and the tidal Love number of neutron-star and quark-star models are related through some relations which depend only mildly on the stellar equation of state. These "I-Love-Q" relations have important implications for astrophysics and gravitational-wave astronomy. An interesting problem is whether similar relations hold for other compact objects and how they approach the black hole limit. To answer these questions, here we investigate the deformation properties of a large class of thin-shell gravastars, which are exotic compact objects that do not possess an event horizon nor a spacetime singularity. Working in a small-spin and small-tidal field expansion, we calculate the moment of inertia, the quadrupole moment, and the (quadrupolar electric) tidal Love number of gravastars with a polytropic thin shell. The I-Love-Q relations of a thin-shell gravastar are drastically different from those of an ordinary neutron star. The Love number and quadrupole moment for less compact models have the opposite sign relative to those of ordinary neutron stars, and the I-Love-Q relations continuously approach the black hole limit. We consider a variety of polytropic equations of state for the matter shell and find no universality in the I-Love-Q relations. However, we cannot deny the possibility that, similarly to the neutron-star case, an approximate universality might emerge for a limited class of equations of state. Finally, we discuss how a measurement of the tidal deformability from the gravitational-wave detection of a compact-binary inspiral can be used to constrain exotic compact objects like gravastars.

Geometric Nonlinear Computation of Thin Rods and Shells

NASA Astrophysics Data System (ADS)

Grinspun, Eitan

2011-03-01

We develop simple, fast numerical codes for the dynamics of thin elastic rods and shells, by exploiting the connection between physics, geometry, and computation. By building a discrete mechanical picture from the ground up, mimicking the axioms, structures, and symmetries of the smooth setting, we produce numerical codes that not only are consistent in a classical sense, but also reproduce qualitative, characteristic behavior of a physical system----such as exact preservation of conservation laws----even for very coarse discretizations. As two recent examples, we present discrete computational models of elastic rods and shells, with straightforward extensions to the viscous setting. Even at coarse discretizations, the resulting simulations capture characteristic geometric instabilities. The numerical codes we describe are used in experimental mechanics, cinema, and consumer software products. This is joint work with Miklós Bergou, Basile Audoly, Max Wardetzky, and Etienne Vouga. This research is supported in part by the Sloan Foundation, the NSF, Adobe, Autodesk, Intel, the Walt Disney Company, and Weta Digital.

Enzyme-assisted growth of nacreous CaCO3/polymer hybrid nanolaminates via the formation of mineral bridges

NASA Astrophysics Data System (ADS)

Yeom, Bongjun; Char, Kookheon

2016-06-01

Laminated nanostructures in nacre have been adopted as models in the fabrication of strong, tough synthetic nanocomposites. However, the utilization of CaCO3 biominerals in these composites is limited by the complexity of the synthesis method for nanosized biominerals. In this study, we use the enzymatic reaction of urease to generate a nanoscale CaCO3 thin film to prepare CaCO3/polymer hybrid nanolaminates. Additional layers of CaCO3 thin film are consecutively grown over the base CaCO3 layer with the intercalation of organic layers. The morphology and crystallinity of the added CaCO3 layers depend strongly on the thickness of the organic layer coated on the underlying CaCO3 layer. When the organic layer is less than 20 nm thick, the amorphous CaCO3 layer is spontaneously transformed into crystalline calcite layer during the growth process. We also observe crystalline continuity between adjacent CaCO3 layers through interconnecting mineral bridges. The formation of these mineral bridges is crucial to the epitaxial growth of CaCO3 layers, similar to the formation of natural nacre.

The chocolate-egg problem: Fabrication of thin elastic shells through coating

NASA Astrophysics Data System (ADS)

Lee, Anna; Marthelot, Joel; Brun, Pierre-Thomas; Reis, Pedro M.

2015-03-01

We study the fabrication of thin polymeric shells based on the coating of a curved surface by a viscous fluid. Upon polymerization of the resulting thin film, a slender solid structure is delivered after demolding. This technique is extensively used, empirically, in manufacturing, where it is known as rotational molding, as well as in the food industry, e.g. for chocolate-eggs. This problem is analogous to the Landau-Levich-Derjaguin coating of plates and fibers and Bretherton's problem of film deposition in cylindrical channels, albeit now on a double-curved geometry. Here, the balance between gravity, viscosity, surface tension and polymerization rate can yield a constant thickness film. We seek to identify the physical ingredients that govern the final film thickness and its profile. In our experiments using organosilicon, we systematically vary the properties of the fluid, as well as the curvature of the substrate onto which the film is coated, and characterize the final thickness profile of the shells. A reduced model is developed to rationalize the process.

A triangular thin shell finite element: Nonlinear analysis. [structural analysis

NASA Technical Reports Server (NTRS)

Thomas, G. R.; Gallagher, R. H.

1975-01-01

Aspects of the formulation of a triangular thin shell finite element which pertain to geometrically nonlinear (small strain, finite displacement) behavior are described. The procedure for solution of the resulting nonlinear algebraic equations combines a one-step incremental (tangent stiffness) approach with one iteration in the Newton-Raphson mode. A method is presented which permits a rational estimation of step size in this procedure. Limit points are calculated by means of a superposition scheme coupled to the incremental side of the solution procedure while bifurcation points are calculated through a process of interpolation of the determinants of the tangent-stiffness matrix. Numerical results are obtained for a flat plate and two curved shell problems and are compared with alternative solutions.

A parameter-free variational coupling approach for trimmed isogeometric thin shells

NASA Astrophysics Data System (ADS)

Guo, Yujie; Ruess, Martin; Schillinger, Dominik

2017-04-01

The non-symmetric variant of Nitsche's method was recently applied successfully for variationally enforcing boundary and interface conditions in non-boundary-fitted discretizations. In contrast to its symmetric variant, it does not require stabilization terms and therefore does not depend on the appropriate estimation of stabilization parameters. In this paper, we further consolidate the non-symmetric Nitsche approach by establishing its application in isogeometric thin shell analysis, where variational coupling techniques are of particular interest for enforcing interface conditions along trimming curves. To this end, we extend its variational formulation within Kirchhoff-Love shell theory, combine it with the finite cell method, and apply the resulting framework to a range of representative shell problems based on trimmed NURBS surfaces. We demonstrate that the non-symmetric variant applied in this context is stable and can lead to the same accuracy in terms of displacements and stresses as its symmetric counterpart. Based on our numerical evidence, the non-symmetric Nitsche method is a viable parameter-free alternative to the symmetric variant in elastostatic shell analysis.

Design and development by direct polishing of the WFXT thin polynomial mirror shells

NASA Astrophysics Data System (ADS)

Proserpio, L.; Campana, S.; Citterio, O.; Civitani, M.; Combrinck, H.; Conconi, P.; Cotroneo, V.; Freeman, R.; Mattini, E.; Langstrof, P.; Morton, R.; Motta, G.; Oberle, O.; Pareschi, G.; Parodi, G.; Pels, C.; Schenk, C.; Stock, R.; Tagliaferri, G.

2017-11-01

The Wide Field X-ray Telescope (WFXT) is a medium class mission proposed to address key questions about cosmic origins and physics of the cosmos through an unprecedented survey of the sky in the soft X-ray band (0.2-6 keV) [1], [2]. In order to get the desired angular resolution of 10 arcsec (5 arcsec goal) on the entire 1 degrees Field Of View (FOV), the design of the optical system is based on nested grazing-incidence polynomial profiles mirrors, and assumes a focal plane curvature and plate scale corrections among the shells. This design guarantees an increased angular resolution also at large off-axis positions with respect to the usually adopted Wolter I configuration. In order to meet the requirements in terms of mass and effective area (less than 1200 kg, 6000 cm2 @ 1 keV), the nested shells are thin and made of quartz glass. The telescope assembly is composed by three identical modules of 78 nested shells each, with diameter up to 1.1 m, length in the range of 200-440 mm and thickness of less than 2.2 mm. At this regard, a deterministic direct polishing method is under investigation to manufacture the WFXT thin grazing-incidence mirrors made of quartz. The direct polishing method has already been used for past missions (as Einstein, Rosat, Chandra) but based on much thicker shells (10 mm ore more). The technological challenge for WFXT is to apply the same approach but for 510 times thinner shells. The proposed approach is based on two main steps: first, quartz glass tubes available on the market are ground to conical profiles; second the pre-shaped shells are polished to the required polynomial profiles using a CNC polishing machine. In this paper, preliminary results on the direct grinding and polishing of prototypes shells made by quartz glass with low thickness, representative of the WFXT optical design, are presented.

Convergence of finite difference transient response computations for thin shells.

NASA Technical Reports Server (NTRS)

Sobel, L. H.; Geers, T. L.

1973-01-01

Numerical studies pertaining to the limits of applicability of the finite difference method in the solution of linear transient shell response problems are performed, and a computational procedure for the use of the method is recommended. It is found that the only inherent limitation of the finite difference method is its inability to reproduce accurately response discontinuities. This is not a serious limitation in view of natural constraints imposed by the extension of Saint Venant's principle to transient response problems. It is also found that the short wavelength limitations of thin shell (Bernoulli-Euler) theory create significant convergence difficulties in computed response to certain types of transverse excitations. These difficulties may be overcome, however, through proper selection of finite difference mesh dimensions and temporal smoothing of the excitation.

Buckling of Thin Cylindrical Shell Subject to Uniform External Pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Forasassi, G.; Lo Frano, R.

2006-07-01

The buckling of cylindrical shells under uniform external pressure loading has been widely investigated. In general, when tubes are subjected to external pressure, collapse is initiated by yielding, but interaction with instability is significant, in that imperfections associated with fabrication of shells reduce the load bearing capacity by a significant amount even when thickness is considerable. A specific buckling analysis is used to predict collapse failure of long pressure vessels and pipelines when they are subjected to external over-pressure. The problem of buckling for variable load conditions is relevant for the optimisation of several Nuclear Power Plant applications as, formore » instance, the IRIS (International Reactor Innovative and Secure) LWR integrated Steam Generator (SG) tubes. In this paper, we consider in addition to the usual assumptions of thin shell, homogeneous and isotropic material, also the tube geometric imperfections and plastic deformations that may affect the limit load. When all those conditions are considered at present, a complete theoretical analysis was not founding the literature. At Pisa University a research activity is being carried out on the buckling of thin walled metal specimen, with reference to several geometries and two different stainless steel materials. A test equipment (with the necessary data acquisition facility), suitable for carrying out many test on this issue, as well as numerical models implemented on the MARC FEM code, were set up. In this report, the results of the performed analyses of critical pressure load determination with different numerical and experimental approaches are presented. The numerical results obtained are compared with the experimental results, for the same geometry and loading conditions, showing a good agreement between these two approaches. (authors)« less

Nanocrystalline-to-amorphous transition in nanolaminates grown by low temperature atomic layer deposition and related mechanical properties

NASA Astrophysics Data System (ADS)

Raghavan, R.; Bechelany, M.; Parlinska, M.; Frey, D.; Mook, W. M.; Beyer, A.; Michler, J.; Utke, I.

2012-05-01

We report on a comprehensive structural and nanoindentation study of nanolaminates of Al2O3 and ZnO synthesized by atomic layer deposition (ALD). By reducing the bilayer thickness from 50 nm to below 1 nm, the nanocrystal size could be controlled in the nanolaminate structure. The softer and more compliant response of the multilayers as compared to the single layers of Al2O3 and ZnO is attributed to the structural change from nanocrystalline to amorphous at smaller bilayer thicknesses. It is also shown that ALD is a unique technique for studying the inverse Hall-Petch softening mechanism (E. Voce and D. Tabor, J. Inst. Metals 79(12), 465 (1951)) related to grain size effects in nanomaterials.

Progressive Fracture of Fiber Composite Thin Shell Structures Under Internal Pressure and Axial Loads

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Chamis, Christos C.; Minnetyan, Levon

1996-01-01

Graphite/epoxy composite thin shell structures were simulated to investigate damage and fracture progression due to internal pressure and axial loading. Defective and defect-free structures (thin cylinders) were examined. The three different laminates examined had fiber orientations of (90/0/+/-0)(sub s), where 0 is 45, 60, and 75 deg. CODSTRAN, an integrated computer code that scales up constituent level properties to the structural level and accounts for all possible failure modes, was used to simulate composite degradation under loading. Damage initiation, growth, accumulation, and propagation to fracture were included in the simulation. Burst pressures for defective and defect-free shells were compared to evaluate damage tolerance. The results showed that damage initiation began with matrix failure whereas damage and/or fracture progression occurred as a result of additional matrix failure and fiber fracture. In both thin cylinder cases examined (defective and defect-free), the optimum layup configuration was (90/0/+/-60)(sub s) because it had the best damage tolerance with respect to the burst pressure.

Vacuum thin shells in Einstein–Gauss–Bonnet brane-world cosmology

NASA Astrophysics Data System (ADS)

Ramirez, Marcos A.

2018-04-01

In this paper we construct new solutions of the Einstein–Gauss–Bonnet field equations in an isotropic Shiromizu–Maeda–Sasaki brane-world setting which represent a couple of Z 2-symmetric vacuum thin shells splitting from the central brane, and explore the main properties of the dynamics of the system. The matching of the separating vacuum shells with the brane-world is as smooth as possible and all matter fields are restricted to the brane. We prove the existence of these solutions, derive the criteria for their existence, analyse some fundamental aspects or their evolution and demonstrate the possibility of constructing cosmological examples that exhibit this feature at early times. We also comment on the possible implications for cosmology and the relation of this system with the thermodynamic instability of highly symmetric vacuum solutions of Lovelock theory.

Addendum to ''Thin-shell wormholes supported by ordinary matter in Einstein-Gauss-Bonnet gravity''

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simeone, Claudio

2011-04-15

Thin-shell wormholes are constructed starting from the exotic branch of the Wiltshire spherically symmetric solution of Einstein-Gauss-Bonnet gravity. The energy-momentum tensor of the shell is studied, and it is shown that configurations supported by matter satisfying the energy conditions exist for certain values of the parameters. Differing from the previous result associated with the normal branch of the Wiltshire solution, this is achieved for small positive values of the Gauss-Bonnet parameter and for vanishing charge.

Evolution of helical perturbations in a thin-shell model of an imploding liner

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryutov, D. D.; Dorf, M. A.

A thin-shell model of the liner stability has been revisited and applied to the stability of the helical perturbations. Several stages of the implosion have been identified, starting from a long initial “latent” phase of an almost resting liner, continuing to the second stage of a rapid contraction and significant perturbation growth, and then transitioning to the third stage where perturbations become ballistic and highly non-linear. The stage of stagnation and rebound is beyond the scope of this paper. An importance of vorticity conservation during the late stages is emphasized. Nonlinear evolution of perturbations is followed up to the pointmore » of the formation of cusp structures. Effects of in-surface flows and of their enhancement due to the vorticity conservation are discussed. It is shown that the pre-machined perturbations created only on the outer surface of the liner grow much slower than one could anticipate. The limitations on the thin-shell description are discussed.« less

(Zr,Ti)O2 interface structure in ZrO2-TiO2 nanolaminates with ultrathin periodicity

NASA Astrophysics Data System (ADS)

Aita, C. R.; DeLoach, J. D.; Yakovlev, V. V.

2002-07-01

A mixed cation interfacial structure in ZrO2-TiO2 nanolaminate films with ultrathin bilayer periodicity grown by sputter deposition at 297 K was identified by x-ray diffraction and nonresonant Raman spectroscopy. This structure consists of an amorphous phase at a ZrO2-on-TiO2 bilayer interface, followed by an extensive crystalline monoclinic (Zr,Ti)O2 solid solution predicted by Vegard's law. Monoclinic (Zr,Ti)O2 has previously been reported only once, in bulk powder of a single composition (ZrTiO4) at high pressure. Its stabilization in the nanolaminates is explained by the Gibbs-Thomson effect. This complex interfacial structure is shown to be a means of accommodating chemical mixing in the absence of a driving force for heteroepitaxy.

Static and free-vibration analyses of cracks in thin-shell structures based on an isogeometric-meshfree coupling approach

NASA Astrophysics Data System (ADS)

Nguyen-Thanh, Nhon; Li, Weidong; Zhou, Kun

2018-03-01

This paper develops a coupling approach which integrates the meshfree method and isogeometric analysis (IGA) for static and free-vibration analyses of cracks in thin-shell structures. In this approach, the domain surrounding the cracks is represented by the meshfree method while the rest domain is meshed by IGA. The present approach is capable of preserving geometry exactness and high continuity of IGA. The local refinement is achieved by adding the nodes along the background cells in the meshfree domain. Moreover, the equivalent domain integral technique for three-dimensional problems is derived from the additional Kirchhoff-Love theory to compute the J-integral for the thin-shell model. The proposed approach is able to address the problems involving through-the-thickness cracks without using additional rotational degrees of freedom, which facilitates the enrichment strategy for crack tips. The crack tip enrichment effects and the stress distribution and displacements around the crack tips are investigated. Free vibrations of cracks in thin shells are also analyzed. Numerical examples are presented to demonstrate the accuracy and computational efficiency of the coupling approach.

Simulations of heart valves by thin shells with non-linear material properties

NASA Astrophysics Data System (ADS)

Borazjani, Iman; Asgharzadeh, Hafez; Hedayat, Mohammadali

2016-11-01

The primary function of a heart valve is to allow blood to flow in only one direction through the heart. Triangular thin-shell finite element formulation is implemented, which considers only translational degrees of freedom, in three-dimensional domain to simulate heart valves undergoing large deformations. The formulation is based on the nonlinear Kirchhoff thin-shell theory. The developed method is intensively validated against numerical and analytical benchmarks. This method is added to previously developed membrane method to obtain more realistic results since ignoring bending forces can results in unrealistic wrinkling of heart valves. A nonlinear Fung-type constitutive relation, based on experimentally measured biaxial loading tests, is used to model the material properties for response of the in-plane motion in heart valves. Furthermore, the experimentally measured liner constitutive relation is used to model the material properties to capture the flexural motion of heart valves. The Fluid structure interaction solver adopts a strongly coupled partitioned approach that is stabilized with under-relaxation and the Aitken acceleration technique. This work was supported by American Heart Association (AHA) Grant 13SDG17220022 and the Center of Computational Research (CCR) of University at Buffalo.

Fluid-structure interaction simulations of deformable structures with non-linear thin shell elements

NASA Astrophysics Data System (ADS)

Asgharzadeh, Hafez; Hedayat, Mohammadali; Borazjani, Iman; Scientific Computing; Biofluids Laboratory Team

2017-11-01

Large deformation of structures in a fluid is simulated using a strongly coupled partitioned fluid-structure interaction (FSI) approach which is stabilized with under-relaxation and the Aitken acceleration technique. The fluid is simulated using a recently developed implicit Newton-Krylov method with a novel analytical Jacobian. Structures are simulated using a triangular thin-shell finite element formulation, which considers only translational degrees of freedom. The thin-shell method is developed on the top of a previously implemented membrane finite element formulation. A sharp interface immersed boundary method is used to handle structures in the fluid domain. The developed FSI framework is validated against two three-dimensional experiments: (1) a flexible aquatic vegetation in the fluid and (2) a heaving flexible panel in fluid. Furthermore, the developed FSI framework is used to simulate tissue heart valves, which involve large deformations and non-linear material properties. This work was supported by American Heart Association (AHA) Grant 13SDG17220022 and the Center of Computational Research (CCR) of University at Buffalo.

Thermodynamics of extremal rotating thin shells in an extremal BTZ spacetime and the extremal black hole entropy

NASA Astrophysics Data System (ADS)

Lemos, José P. S.; Minamitsuji, Masato; Zaslavskii, Oleg B.

2017-02-01

In a (2 +1 )-dimensional spacetime with a negative cosmological constant, the thermodynamics and the entropy of an extremal rotating thin shell, i.e., an extremal rotating ring, are investigated. The outer and inner regions with respect to the shell are taken to be the Bañados-Teitelbom-Zanelli (BTZ) spacetime and the vacuum ground state anti-de Sitter spacetime, respectively. By applying the first law of thermodynamics to the extremal thin shell, one shows that the entropy of the shell is an arbitrary well-behaved function of the gravitational area A+ alone, S =S (A+). When the thin shell approaches its own gravitational radius r+ and turns into an extremal rotating BTZ black hole, it is found that the entropy of the spacetime remains such a function of A+, both when the local temperature of the shell at the gravitational radius is zero and nonzero. It is thus vindicated by this analysis that extremal black holes, here extremal BTZ black holes, have different properties from the corresponding nonextremal black holes, which have a definite entropy, the Bekenstein-Hawking entropy S (A+)=A/+4G , where G is the gravitational constant. It is argued that for extremal black holes, in particular for extremal BTZ black holes, one should set 0 ≤S (A+)≤A/+4G;i.e., the extremal black hole entropy has values in between zero and the maximum Bekenstein-Hawking entropy A/+4 G . Thus, rather than having just two entropies for extremal black holes, as previous results have debated, namely, 0 and A/+4 G , it is shown here that extremal black holes, in particular extremal BTZ black holes, may have a continuous range of entropies, limited by precisely those two entropies. Surely, the entropy that a particular extremal black hole picks must depend on past processes, notably on how it was formed. A remarkable relation between the third law of thermodynamics and the impossibility for a massive body to reach the velocity of light is also found. In addition, in the procedure, it

Analytical Solution of the Radiative Transfer Equation in a Thin Dusty Circumstellar Shell

NASA Astrophysics Data System (ADS)

Cruzalèbes, P.; Sacuto, S.

The radiative transfer equation can be solved analytically for optically thin shells. The solution leads to a semi-analytical expression of the visibility function, which can be compared to the numerical solution given by the DUSTY code. Best-fit model parameters are given using real measurements of ISO fluxes, ISI and VLTI-MIDI visibilities for 3 late-type stars.

High-Precision Shape Control of In-Space Deployable Large Membrane/Thin-Shell Reflectors

NASA Technical Reports Server (NTRS)

Watkins, Ronald; Goebel, Dan; Hofer, Richard

2010-01-01

This innovation has been developed to improve the resolutions of future spacebased active and passive microwave antennas for earth-science remote sensing missions by maintaining surface figure precisions of large membrane/thin-shell reflectors during orbiting. The intention is for these sensing instruments to be deployable at orbit altitudes one or two orders of magnitude higher than Low Earth Orbit (LEO), but still being able to acquire measurements at spatial resolution and sensitivity similar to those of LEO. Because active and passive microwave remote sensors are able to penetrate through clouds to acquire vertical profile measurements of geophysical parameters, it is desirable to elevate them to the higher orbits to obtain orbital geometries that offer large spatial coverage and more frequent observations. This capability is essential for monitoring and for detailed understanding of the life cycles of natural hazards, such as hurricanes, tropical storms, flash floods, and tsunamis. Major components of this high-precision antenna-surface-control system include a membrane/thin shell reflector, a metrology sensor, a controller, actuators, and corresponding power amplifier and signal conditioning electronics (see figure). Actuators are attached to the back of the reflector to produce contraction/ expansion forces to adjust the shape of the thin-material reflector. The wavefront-sensing metrology system continuously measures the surface figure of the reflector, converts the surface figure to digital data and feeds the data to the controller. The controller determines the control parameters and generates commands to the actuator system. The flexible, piezoelectric polymer actuators are thus activated, providing the control forces needed to correct any distortions that exist in the reflector surface. Piezoelectric polymer actuators are very thin and flexible. They can be implemented on the back of the membrane/thin-shell reflector without introducing significant

Organochlorine pesticides, polychlorinated biphenyls, and mercury in osprey eggs--1970-79--and their relationships to shell thinning and productivity

USGS Publications Warehouse

Wiemeyer, Stanley N.; Bunck, C.M.; Krynitsky, A.J.

1988-01-01

Osprey (Pandion haliaetus) eggs were collected in 14 states in 1970-79 and analyzed for organochlorine pesticides, polychlorinated biphenyls (PCBs), and mercury. Moderate shell thinning occurred in eggs from several areas. DDE was detected in all eggs, PCBs in 99%, DDD in 96%, dieldrin in 52%, and other compounds less frequently. Concentrations of DDT and its metabolites declined in eggs from Cape May County, New Jersey between 1970-72 and 1978-79. Eggs .from New Jersey in the early 1970s contained the highest concentrations of DDE. Dieldrin concentrations declined in eggs from the Potomac River, Maryland during 1971-77. Five different contaminants were significantly negatively correlated with shell thickness; DDE was most closely correlated. Ten percent shell thinning was associated with 2.0 ppm DDE, 15% with 4.2 ppm, and 20% with 8.7 ppm in eggs collected from randomly selected nests before egg loss. Shell thickness could not be accurately predicted from DDE concentrations in eggs collected after failure to hatch, presumably because the eggs with the thinnest shells had been broken and were unavailable for sampling. DDE was also significantly negatively correlated with brood size. Other contaminants did not appear to adversely affect shell thickness or reproductive success.

Nonlinear Shell Modeling of Thin Membranes with Emphasis on Structural Wrinkling

NASA Technical Reports Server (NTRS)

Tessler, Alexander; Sleight, David W.; Wang, John T.

2003-01-01

Thin solar sail membranes of very large span are being envisioned for near-term space missions. One major design issue that is inherent to these very flexible structures is the formation of wrinkling patterns. Structural wrinkles may deteriorate a solar sail's performance and, in certain cases, structural integrity. In this paper, a geometrically nonlinear, updated Lagrangian shell formulation is employed using the ABAQUS finite element code to simulate the formation of wrinkled deformations in thin-film membranes. The restrictive assumptions of true membranes, i.e. Tension Field theory (TF), are not invoked. Two effective modeling strategies are introduced to facilitate convergent solutions of wrinkled equilibrium states. Several numerical studies are carried out, and the results are compared with recent experimental data. Good agreement is observed between the numerical simulations and experimental data.

The role of crystallographic texture in achieving low friction zinc oxide nanolaminate films

NASA Astrophysics Data System (ADS)

Mojekwu, Nneoma

Metal oxide nanolaminate films are potential high temperature solid lubricants due to their ability to exhibit significant plasticity when grain size is reduced to the nanometer scale, and defective growth structure is achieved by condensation of oxygen vacancies to form intrinsic stacking faults. This is in contrast to conventional microcrystalline and single crystal oxides that exhibit brittle fracture during loading in a sliding contact. This study emphasizes the additional effect of growth orientation, in particular crystallographic texture, on determining the sliding friction behavior in nanocolumnar grain zinc oxide films grown by atomic layer deposition. It was determined that zinc oxide low (0002) versus higher (101¯3) surface energy crystallographic planes influenced the sliding friction coefficient. Texturing of the (0002) grains resulted in a decreased adhesive component of friction thereby lowering the sliding friction coefficient to ˜0.25, while the friction coefficient doubled to ˜0.5 with increasing contribution of surface (101¯3) grains. In addition, the variation of the x-ray grazing incident angle from 0.5° to 5° was studied to better understand the surface grain orientation as a function of ZnO layer thickness in one versus four bilayer nanolaminates where the under layer (seed layer) was load-bearing Zn(Ti,Zr)O3.

Nondimensional Parameters and Equations for Nonlinear and Bifurcation Analyses of Thin Anisotropic Quasi-Shallow Shells

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.

2010-01-01

A comprehensive development of nondimensional parameters and equations for nonlinear and bifurcations analyses of quasi-shallow shells, based on the Donnell-Mushtari-Vlasov theory for thin anisotropic shells, is presented. A complete set of field equations for geometrically imperfect shells is presented in terms general of lines-of-curvature coordinates. A systematic nondimensionalization of these equations is developed, several new nondimensional parameters are defined, and a comprehensive stress-function formulation is presented that includes variational principles for equilibrium and compatibility. Bifurcation analysis is applied to the nondimensional nonlinear field equations and a comprehensive set of bifurcation equations are presented. An extensive collection of tables and figures are presented that show the effects of lamina material properties and stacking sequence on the nondimensional parameters.

Irradiation-induced creep in metallic nanolaminates characterized by In situ TEM pillar nanocompression

DOE PAGES

Dillon, Shen J.; Bufford, Daniel C.; Jawaharram, Gowtham S.; ...

2017-04-13

Our work reports on irradiation-induced creep (IIC) measured on nanolaminate (Cu-W and Ni-Ag) and nanocrystalline alloys (Cu-W) at room temperature using a combination of heavy ion irradiation and nanopillar compression performed concurrently in situ in a transmission electron microscope. Furthermore, we observed appreciable IIC in multilayers with 50 nm layer thicknesses at high stress, ≈½ the yield strength, but not in multilayers with only 5 nm layer thicknesses.

Performance of an anisotropic Allman/DKT 3-node thin triangular flat shell element

NASA Astrophysics Data System (ADS)

Ertas, A.; Krafcik, J. T.; Ekwaro-Osire, S.

1992-05-01

A simple, explicit formulation of the stiffness matrix for an anisotropic, 3-node, thin triangular flat shell element in global coordinates is presented. An Allman triangle (AT) is used for membrane stiffness. The membrane stiffness matrix is explicitly derived by applying an Allman transformation to a Felippa 6-node linear strain triangle (LST). Bending stiffness is incorporated by the use of a discrete Kirchhoff triangle (DKT) bending element. Stiffness terms resulting from anisotropic membrane-bending coupling are included by integrating, in area coordinates, the membrane and bending strain-displacement matrices. Using the aforementioned approach, the objective of this study is to develop and test the performance of a practical 3-node flat shell element that could be used in plate problems with unsymmetrically stacked composite laminates. The performance of the latter element is tested on plates of varying aspect ratios. The developed 3-node shell element should simplify the programming task and have the potential of reducing the computational time.

Nonlinear Response of Thin Cylindrical Shells with Longitudinal Cracks and Subjected to Internal Pressure and Axial compression Loads

NASA Technical Reports Server (NTRS)

Starnes, James H.; Rose, Cheryl A.

1998-01-01

The results of an analytical study of the nonlinear response of a thin unstiffened aluminum cylindrical shell with a longitudinal crack are presented. The shell is analyzed with a nonlinear shell analysis code that maintains the shell in a nonlinear equilibrium state while the crack is grown. The analysis accurately accounts for global and local structural response phenomena. Results are presented for internal pressure, axial compression, and combined internal pressure and axial compression loads. The effects of varying crack length on the nonlinear response of the shell subjected to internal pressure are described. The effects of varying crack length on the prebuckling, buckling and postbuckling responses of the shell subjected to axial compression, and subjected to combined internal pressure and axial compression are also described. The results indicate that the nonlinear interaction between the in-plane stress resultants and the out-of-plane displacements near a crack can significantly affect the structural response of the shell. The results also indicate that crack growth instabilities and shell buckling instabilities can both affect the response of the shell as the crack length is increased.

Analytical Investigation of Elastic Thin-Walled Cylinder and Truncated Cone Shell Intersection Under Internal Pressure.

PubMed

Zamani, J; Soltani, B; Aghaei, M

2014-10-01

An elastic solution of cylinder-truncated cone shell intersection under internal pressure is presented. The edge solution theory that has been used in this study takes bending moments and shearing forces into account in the thin-walled shell of revolution element. The general solution of the cone equations is based on power series method. The effect of cone apex angle on the stress distribution in conical and cylindrical parts of structure is investigated. In addition, the effect of the intersection and boundary locations on the circumferential and longitudinal stresses is evaluated and it is shown that how quantitatively they are essential.

Communication: Programmable self-assembly of thin-shell mesostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Halverson, Jonathan D.; Tkachenko, Alexei V.

For this article, we study numerically the possibility of programmable self-assembly of various thin-shell architectures. They include clusters isomorphic to fullerenes C 20 and C 60, finite and infinite sheets, tube-shaped and toroidal mesostructures. Our approach is based on the recently introduced directionally functionalized nanoparticle platform, for which we employ a hybrid technique of Brownian dynamics with stochastic bond formation. By combining a number of strategies, we were able to achieve a near-perfect yield of the desired structures with a reduced “alphabet” of building blocks. Among those strategies are the following: the use of bending rigidity of the interparticle bondmore » as a control parameter, programming the morphology with a seed architecture, use of chirality-preserving symmetries for reduction of the particle alphabet, and the hierarchic approach.« less

Communication: Programmable self-assembly of thin-shell mesostructures

DOE PAGES

Halverson, Jonathan D.; Tkachenko, Alexei V.

2017-10-13

For this article, we study numerically the possibility of programmable self-assembly of various thin-shell architectures. They include clusters isomorphic to fullerenes C 20 and C 60, finite and infinite sheets, tube-shaped and toroidal mesostructures. Our approach is based on the recently introduced directionally functionalized nanoparticle platform, for which we employ a hybrid technique of Brownian dynamics with stochastic bond formation. By combining a number of strategies, we were able to achieve a near-perfect yield of the desired structures with a reduced “alphabet” of building blocks. Among those strategies are the following: the use of bending rigidity of the interparticle bondmore » as a control parameter, programming the morphology with a seed architecture, use of chirality-preserving symmetries for reduction of the particle alphabet, and the hierarchic approach.« less

Faraday Wave Turbulence on a Spherical Liquid Shell

NASA Technical Reports Server (NTRS)

Holt, R. Glynn; Trinh, Eugene H.

1996-01-01

Millimeter-radius liquid shells are acoustically levitated in an ultrasonic field. Capillary waves are observed on the shells. At low energies (minimal acoustic amplitude, thick shell) a resonance is observed between the symmetric and antisymmetric thin film oscillation modes. At high energies (high acoustic pressure, thin shell) the shell becomes fully covered with high-amplitude waves. Temporal spectra of scattered light from the shell in this regime exhibit a power-law decay indicative of turbulence.

Design and modeling of an additive manufactured thin shell for x-ray astronomy

NASA Astrophysics Data System (ADS)

Feldman, Charlotte; Atkins, Carolyn; Brooks, David; Watson, Stephen; Cochrane, William; Roulet, Melanie; Willingale, Richard; Doel, Peter

2017-09-01

Future X-ray astronomy missions require light-weight thin shells to provide large collecting areas within the weight limits of launch vehicles, whilst still delivering angular resolutions close to that of Chandra (0.5 arc seconds). Additive manufacturing (AM), also known as 3D printing, is a well-established technology with the ability to construct or `print' intricate support structures, which can be both integral and light-weight, and is therefore a candidate technique for producing shells for space-based X-ray telescopes. The work described here is a feasibility study into this technology for precision X-ray optics for astronomy and has been sponsored by the UK Space Agency's National Space Technology Programme. The goal of the project is to use a series of test samples to trial different materials and processes with the aim of developing a viable path for the production of an X-ray reflecting prototype for astronomical applications. The initial design of an AM prototype X-ray shell is presented with ray-trace modelling and analysis of the X-ray performance. The polishing process may cause print-through from the light-weight support structure on to the reflecting surface. Investigations in to the effect of the print-through on the X-ray performance of the shell are also presented.

The equivalence of Darmois-Israel and distributional method for thin shells in general relativity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mansouri, R.; Khorrami, M.

1996-11-01

A distributional method to solve the Einstein{close_quote}s field equations for thin shells is formulated. The familiar field equations and jump conditions of Darmois-Israel formalism are derived. A careful analysis of the Bianchi identities shows that, for cases under consideration, they make sense as distributions and lead to jump conditions of Darmois-Israel formalism. {copyright} {ital 1996 American Institute of Physics.}

Nonsymmetric dynamical thin-shell wormhole in Robinson-Trautman class

NASA Astrophysics Data System (ADS)

Svítek, O.; Tahamtan, T.

2018-02-01

The thin-shell wormhole created using the Darmois-Israel formalism applied to Robinson-Trautman family of spacetimes is presented. The stress energy tensor created on the throat is interpreted in terms of two dust streams and it is shown that asymptotically this wormhole settles to the Schwarzschild wormhole with a throat located at the position of the horizon. This behavior shows a nonlinear stability (within the Robinson-Trautman class) of this spherically symmetric wormhole. The gravitational radiation emitted by the Robinson-Trautman wormhole during the transition to spherical symmetry is indistinguishable from that of the corresponding black hole Robinson-Trautman spacetime. Subsequently, we show that the higher-dimensional generalization of Robinson-Trautman geometry offers a possibility of constructing wormholes without the need to violate the energy conditions for matter induced on the throat.

Unified approach to the entropy of an extremal rotating BTZ black hole: Thin shells and horizon limits

NASA Astrophysics Data System (ADS)

Lemos, José P. S.; Minamitsuji, Masato; Zaslavskii, Oleg B.

2017-10-01

Using a thin shell, the first law of thermodynamics, and a unified approach, we study the thermodymanics and find the entropy of a (2 +1 )-dimensional extremal rotating Bañados-Teitelbom-Zanelli (BTZ) black hole. The shell in (2 +1 ) dimensions, i.e., a ring, is taken to be circularly symmetric and rotating, with the inner region being a ground state of the anti-de Sitter spacetime and the outer region being the rotating BTZ spacetime. The extremal BTZ rotating black hole can be obtained in three different ways depending on the way the shell approaches its own gravitational or horizon radius. These ways are explicitly worked out. The resulting three cases give that the BTZ black hole entropy is either the Bekenstein-Hawking entropy, S =A/+ 4 G , or an arbitrary function of A+, S =S (A+) , where A+=2 π r+ is the area, i.e., the perimeter, of the event horizon in (2 +1 ) dimensions. We speculate that the entropy of an extremal black hole should obey 0 ≤S (A+)≤A/+ 4 G . We also show that the contributions from the various thermodynamic quantities, namely, the mass, the circular velocity, and the temperature, for the entropy in all three cases are distinct. This study complements the previous studies in thin shell thermodynamics and entropy for BTZ black holes. It also corroborates the results found for a (3 +1 )-dimensional extremal electrically charged Reissner-Nordström black hole.

A Bottle-around-a-Ship Method To Generate Hollow Thin-Shelled Particles Containing Encapsulated Iron Species with Application to the Environmental Decontamination of Chlorinated Compounds.

PubMed

Su, Yang; Wang, Yingqing; Owoseni, Olasehinde; Zhang, Yueheng; Gamliel, David Pierce; Valla, Julia A; McPherson, Gary L; John, Vijay T

2018-04-25

Thin-shelled hollow silica particles are synthesized using an aerosol-based process where the concentration of a silica precursor tetraethyl orthosilicate (TEOS) determines the shell thickness. The synthesis involves a novel concept of the salt bridging of an iron salt, FeCl 3 , to a cationic surfactant, cetyltrimethylammonium bromide (CTAB), which modulates the templating effect of the surfactant on silica porosity. The salt bridging leads to a sequestration of the surfactant in the interior of the droplet with the formation of a dense silica shell around the organic material. Subsequent calcination consistently results in hollow particles with encapsulated iron oxides. Control of the TEOS levels leads to the generation of ultrathin-shelled (∼10 nm) particles which become susceptible to rupture upon exposure to ultrasound. The dense silica shell that is formed is impervious to entry of chemical species. Mesoporosity is restored to the shell through desilication and reassembly, again using CTAB as a template. The mesoporous-shelled hollow particles show good reactivity toward the reductive dichlorination of trichloroethylene (TCE), indicating access of TCE to the particle interior. The ordered mesoporous thin-shelled particles containing active iron species are viable systems for chemical reaction and catalysis.

Features of electronic and lattice mechanisms of transboundary heat transfer in multilayer nanolaminate TiAlN/Ag coatings.

PubMed

Kovalev, A I; Wainstein, D L; Vakhrushev, V O; Gago, R; Soldera, F; Endrino, J L; Fox-Rabinovich, G S; Veldhuis, S

2017-12-06

Plasmon resonance heterogeneities were identified and studied along Ag and TiAlN layers within a multilayer stack in nanolaminate TiAlN/Ag coatings. For this purpose, a high-resolution plasmon microscopy was used. The plasmons intensity, energy, and depth of interface plasmon-polariton penetration were studied by scanning reflected electron energy loss spectroscopy. The heat conductivity of such metal-insulator-metal (MIM) nanolaminate coatings was measured by laser reflectometry. Dependencies of thermal conductivity coefficient of coatings, MIM interfaces, and resistivity of Ag layers as a function of the Ag-TiAlN bilayer thickness were calculated on the basis of experimental data. The contribution of plasmon resonance confinement to the abnormal lower thermal conductivity in the MIM metamaterial with Ag layer thickness below 25 nm is discussed. In particular, the results highlight the relevant role of different heat transfer mechanisms between MI and IM interfaces: asymmetry of plasmon-polariton interactions on upper and lower boundaries of Ag layer and asymmetry of LA and TA phonons propagation through interfaces.

Rapid vapor deposition of highly conformal silica nanolaminates.

PubMed

Hausmann, Dennis; Becker, Jill; Wang, Shenglong; Gordon, Roy G

2002-10-11

Highly uniform and conformal coatings can be made by the alternating exposures of a surface to vapors of two reactants, in a process commonly called atomic layer deposition (ALD). The application of ALD has, however, been limited because of slow deposition rates, with a theoretical maximum of one monolayer per cycle. We show that alternating exposure of a surface to vapors of trimethylaluminum and tris(tert-butoxy)silanol deposits highly conformal layers of amorphous silicon dioxide and aluminum oxide nanolaminates at rates of 12 nanometers (more than 32 monolayers) per cycle. This process allows for the uniform lining or filling of long, narrow holes. We propose that these ALD layers grow by a previously unknown catalytic mechanism that also operates during the rapid ALD of many other metal silicates. This process should allow improved production of many devices, such as trench insulation between transistors in microelectronics, planar waveguides, microelectromechanical structures, multilayer optical filters, and protective layers against diffusion, oxidation, or corrosion.

The Integration Process of Very Thin Mirror Shells with a Particular Regard to Simbol-X

NASA Astrophysics Data System (ADS)

Basso, S.; Pareschi, G.; Tagliaferri, G.; Mazzoleni, F.; Valtolina, R.; Citterio, O.; Conconi, P.

2009-05-01

The optics of Simbol-X are very thin compared to previous X-ray missions (like XMM). Therefore their shells floppy and are unable to maintain the correct shape. To avoid the deformations of their very thin X-ray optics during the integration process we adopt two stiffening rings with a good roundness. In this article the procedure used for the first three prototypes of the Simbol-X optics is presented with a description of the problems involved and with an analysis of the degradation of the performances during the integration. This analysis has been performed with the UV vertical bench measurements at INAF-OAB.

Core-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films.

PubMed

Antoine, Ségolène; Aissou, Karim; Mumtaz, Muhammad; Telitel, Siham; Pécastaings, Gilles; Wirotius, Anne-Laure; Brochon, Cyril; Cloutet, Eric; Fleury, Guillaume; Hadziioannou, Georges

2018-05-01

The synthesis and self-assembly in thin-film configuration of linear ABC triblock terpolymer chains consisting of polystyrene (PS), poly(2-vinylpyridine) (P2VP), and polyisoprene (PI) are described. For that purpose, a hydroxyl-terminated PS-b-P2VP (45 kg mol -1 ) building block and a carboxyl-terminated PI (9 kg mol -1 ) are first separately prepared by anionic polymerization, and then are coupled via a Steglich esterification reaction. This quantitative and metal-free catalyst synthesis route reveals to be very interesting since functionalization and purification steps are straightforward, and well-defined terpolymers are produced. A solvent vapor annealing (SVA) process is used to promote the self-assembly of frustrated PS-b-P2VP-b-PI chains into a thin-film core-shell double gyroid (Q 230 , space group: Ia3¯d) structure. As terraces are formed within PS-b-P2VP-b-PI thin films during the SVA process under a CHCl 3 vapor, different plane orientations of the Q 230 structure ((211), (110), (111), and (100)) are observed at the polymer-air interface depending on the film thickness. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Axisymmetric bluff-body flow: A vortex solver for thin shells

NASA Astrophysics Data System (ADS)

Strickland, J. H.

1992-05-01

A method which is capable of solving the axisymmetric flow field over bluff bodies consisting of thin shells such as disks, partial spheres, rings, and other such shapes is presented in this report. The body may be made up of several shells whose edges are separated by gaps. The body may be moved axially according to arbitrary velocity time histories. In addition, the surfaces may possess axial and radial degrees of flexibility such that points on the surfaces may be allowed to move relative to each other according to some specified function of time. The surfaces may be either porous or impervious. The present solution technique is based on the axisymmetric vorticity transport equation. Physically, this technique simulates the generation of vorticity at body surfaces in the form of discrete ring vortices which are subsequently diffused and convected into the boundary layers and wake of the body. Relatively large numbers of vortices (1000 or more) are required to obtain good simulations. Since the direct calculation of perturbations from large numbers of ring vortices is computationally intensive, a fast multipole method was used to greatly reduce computer processing time. Several example calculations are presented for disks, disks with holes, hemispheres, and vented hemispheres. These results are compared with steady and unsteady experimental data.

Magnetic core/shell nanoparticle thin films deposited by MAPLE: Investigation by chemical, morphological and in vitro biological assays

NASA Astrophysics Data System (ADS)

Cristescu, R.; Popescu, C.; Socol, G.; Iordache, I.; Mihailescu, I. N.; Mihaiescu, D. E.; Grumezescu, A. M.; Balan, A.; Stamatin, I.; Chifiriuc, C.; Bleotu, C.; Saviuc, C.; Popa, M.; Chrisey, D. B.

2012-09-01

We report on thin film deposition of nanostructured Fe3O4/oleic acid/ceftriaxone and Fe3O4/oleic acid/cefepime nanoparticles (core/shell/adsorption-shell) were fabricated by matrix assisted pulsed laser evaporation (MAPLE) onto inert substrates. The thin films were characterized by profilometry, Fourier transform infrared spectroscopy, atomic force microscopy, and investigated by in vitro biological assays. The biological properties tested included the investigation of the microbial viability and the microbial adherence to the glass coverslip nanoparticle film, using Gram-negative and Gram-positive bacterial strains with known antibiotic susceptibility behavior, the microbial adherence to the HeLa cells monolayer grown on the nanoparticle pellicle, and the cytotoxicity on eukaryotic cells. The proposed system, based on MAPLE, could be used for the development of novel anti-microbial materials or strategies for fighting pathogenic biofilms frequently implicated in the etiology of biofilm associated chronic infections.

Fano-like resonance phenomena by flexural shell modes in sound transmission through two-dimensional periodic arrays of thin-walled hollow cylinders

NASA Astrophysics Data System (ADS)

Kosevich, Yuriy A.; Goffaux, Cecile; Sánchez-Dehesa, Jose

2006-07-01

It is shown that the n=2 and 3 flexural shell vibration modes of thin-walled hollow cylinders result in Fano-like resonant enhancement of sound wave transmission through or reflection from two-dimensional periodic arrays of these cylinders in air. The frequencies of the resonant modes are well described by the analytical theory of flexural (circumferential) modes of thin-walled hollow cylinders and are confirmed by finite-difference time-domain simulations. When the modes are located in the band gaps of the phononic crystal, an enhancement of the band-gap widths is produced by the additional restoring forces caused by the flexural shell deformations. Our conclusions provide an alternative method for the vibration control of airborne phononic crystals.

Temperature- and frequency-dependent dielectric behaviors of insulator/semiconductor (Al2O3/ZnO) nanolaminates with various ZnO thicknesses

NASA Astrophysics Data System (ADS)

Li, Jin; Bi, Xiaofang

2016-07-01

Al2O3/ZnO nanolaminates (NLs) with various ZnO sublayer thicknesses were prepared by atomic layer deposition. The Al2O3 sublayers are characterized as amorphous and the ZnO sublayers have an oriented polycrystalline structure. As the ZnO thickness decreases to a certain value, each NL exhibits a critical temperature at which its dielectric constant starts to rise quickly. Moreover, this temperature increases as the ZnO thickness is decreased further. On the other hand, the permittivity demonstrates a large value of several hundred at a frequency  ⩽1000 Hz, followed by a steplike decrease at a higher frequency. The change in the cut-off frequency with ZnO thickness is characterized by a hook function. It is revealed that the Coulomb confinement effect becomes predominant in the dielectric behaviors of the NLs with very thin ZnO. As the ZnO thickness decreases to about the same as or even smaller than the Bohr radius of ZnO, a great change in the carrier concentration and effective mass of ZnO is induced, which is shown to be responsible for the peculiar dielectric behaviors of Al2O3/ZnO with very thin ZnO. These findings provide insight into the prevailing mechanisms to optimize the dielectric properties of semiconductor/insulator laminates with nanoscale sublayer thickness.

Tearing of thin spherical shells adhered to equally curved rigid substrates

NASA Astrophysics Data System (ADS)

McMahan, Connor; Lee, Anna; Marthelot, Joel; Reis, Pedro

Lasik (Laser-Assisted in Situ Keratomileusis) eye surgery involves the tearing of the corneal epithelium to remodel the corneal stroma for corrections such as myopia, hyperopia and astigmatism. One issue with this procedure is that during the tearing of the corneal epithelium, if the two propagating cracks coalesce, a flap detaches which could cause significant complications in the recovery of the patient. We seek to gain a predictive physical understanding of this process by performing precision desktop experiments on an analogue model system. First, thin spherical shells of nearly uniform thickness are fabricated by the coating of hemispherical molds with a polymer solution, which upon curing yields an elastic and brittle structure. We then create two notches near the equator of the shell and tear a flap by pulling tangentially to the spherical substrate, towards its pole. The resulting fracture paths are characterized by high-resolution 3D digital scanning. Our primary focus is on establishing how the positive Gaussian curvature of the system affects the path of the crack tip. Our results are directly contrasted against previous studies on systems with zero Gaussian curvature, where films were torn from planar and cylindrical substrates.

Interface failure modes explain non-monotonic size-dependent mechanical properties in bioinspired nanolaminates.

PubMed

Song, Z Q; Ni, Y; Peng, L M; Liang, H Y; He, L H

2016-03-31

Bioinspired discontinuous nanolaminate design becomes an efficient way to mitigate the strength-ductility tradeoff in brittle materials via arresting the crack at the interface followed by controllable interface failure. The analytical solution and numerical simulation based on the nonlinear shear-lag model indicates that propagation of the interface failure can be unstable or stable when the interfacial shear stress between laminae is uniform or highly localized, respectively. A dimensionless key parameter defined by the ratio of two characteristic lengths governs the transition between the two interface-failure modes, which can explain the non-monotonic size-dependent mechanical properties observed in various laminate composites.

Thin fused silica shells for high-resolution and large collecting area x-ray telescopes (like Lynx/XRS)

NASA Astrophysics Data System (ADS)

Civitani, M. M.; Hołyszko, J.; Vecchi, G.; Basso, S.; Citterio, O.; Ghigo, M.; Pareschi, G.; Parodi, G.; Incorvaia, S.

2017-09-01

The implementation of an X-ray mission with high imaging capabilities, similar to those achieved with Chandra (< 1 arc second Half Energy Width, HEW), but with a much larger throughput (2.5 m2 effective area @1 keV), represents a compelling request by the scientific community. To this end the Lynx/XRS mission is being studied in USA, with the participation of international partners. In order to figure out the challenging technological task of the mirror fabrication, different approaches are considered, based on monolithic and segmented shells. Starting from the experience done on the glass prototypal shell realized in the past years, the direct polishing of thin (2 mm thick) fused silica monolithic shells is being investigated as a possible solution. A temporary stiffening structure is designed to support the shell during the figuring and polishing operations and to manage the handling up to its integration in the telescope structure. After the grinding and the polishing phases, in order to achieve the required surface accuracy, a final ion beam figuring correction is foreseen. In this paper, we present the technological process and the results achieved so far on a prototypal shell under development.

Development and applications of a flat triangular element for thin laminated shells

NASA Astrophysics Data System (ADS)

Mohan, P.

Finite element analysis of thin laminated shells using a three-noded flat triangular shell element is presented. The flat shell element is obtained by combining the Discrete Kirchhoff Theory (DKT) plate bending element and a membrane element similar to the Allman element, but derived from the Linear Strain Triangular (LST) element. The major drawback of the DKT plate bending element is that the transverse displacement is not explicitly defined within the interior of the element. In the present research, free vibration analysis is performed both by using a lumped mass matrix and a so called consistent mass matrix, obtained by borrowing shape functions from an existing element, in order to compare the performance of the two methods. Several numerical examples are solved to demonstrate the accuracy of the formulation for both small and large rotation analysis of laminated plates and shells. The results are compared with those available in the existing literature and those obtained using the commercial finite element package ABAQUS and are found to be in good agreement. The element is employed for two main applications involving large flexible structures. The first application is the control of thermal deformations of a spherical mirror segment, which is a segment of a multi-segmented primary mirror used in a space telescope. The feasibility of controlling the surface distortions of the mirror segment due to arbitrary thermal fields, using discrete and distributed actuators, is studied. The second application is the analysis of an inflatable structure, being considered by the US Army for housing vehicles and personnel. The updated Lagrangian formulation of the flat shell element has been developed primarily for the nonlinear analysis of the tent structure, since such a structure is expected to undergo large deformations and rotations under the action of environmental loads like the wind and snow loads. The follower effects of the pressure load have been included in the

-dimensional thin shell wormhole with deformed throat can be supported by normal matter

NASA Astrophysics Data System (ADS)

Mazharimousavi, S. Habib; Halilsoy, M.

2015-06-01

From the physics standpoint the exotic matter problem is a major difficulty in thin shell wormholes (TSWs) with spherical/cylindrical throat topologies. We aim to circumvent this handicap by considering angle dependent throats in dimensions. By considering the throat of the TSW to be deformed spherical, i.e., a function of and , we present general conditions which are to be satisfied by the shape of the throat in order to have the wormhole supported by matter with positive density in the static reference frame. We provide particular solutions/examples to the constraint conditions.

Analysis of thin-walled cylindrical composite shell structures subject to axial and bending loads: Concept development, analytical modeling and experimental verification

NASA Astrophysics Data System (ADS)

Mahadev, Sthanu

Continued research and development efforts devoted in recent years have generated novel avenues towards the advancement of efficient and effective, slender laminated fiber-reinforced composite members. Numerous studies have focused on the modeling and response characterization of composite structures with particular relevance to thin-walled cylindrical composite shells. This class of shell configurations is being actively explored to fully determine their mechanical efficacy as primary aerospace structural members. The proposed research is targeted towards formulating a composite shell theory based prognosis methodology that entails an elaborate analysis and investigation of thin-walled cylindrical shell type laminated composite configurations that are highly desirable in increasing number of mechanical and aerospace applications. The prime motivation to adopt this theory arises from its superior ability to generate simple yet viable closed-form analytical solution procedure to numerous geometrically intense, inherent curvature possessing composite structures. This analytical evaluative routine offers to acquire a first-hand insight on the primary mechanical characteristics that essentially govern the behavior of slender composite shells under typical static loading conditions. Current work exposes the robustness of this mathematical framework via demonstrating its potential towards the prediction of structural properties such as axial stiffness and bending stiffness respectively. Longitudinal ply-stress computations are investigated upon deriving the global stiffness matrix model for composite cylindrical tubes with circular cross-sections. Additionally, this work employs a finite element based numerical technique to substantiate the analytical results reported for cylindrically shaped circular composite tubes. Furthermore, this concept development is extended to the study of thin-walled, open cross-sectioned, curved laminated shells that are geometrically

Hollow Silicon Nanospheres Encapsulated with a Thin Carbon Shell: An Electrochemical Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ashuri, Maziar; He, Qianran; Liu, Yuzi

In this study we have investigated the electrochemical properties of hollow silicon nanospheres encapsulated with a thin carbon shell, HSi@C, as a potential candidate for lithium-ion battery anodes. Hollow Si nanospheres are formed using a templating method which is followed by carbon coating via carbonization of a pyrrole precursor to form HSi@C. The synthesis conditions and the resulting structure of HSi@C have been studied in detail to obtain the target design of hollow Si nanospheres encapsulated with a carbon shell. The HSi@C obtained exhibits much better electrochemical cycle stability than both micro-and nano-size silicon anodes and deliver a stable specificmore » capacity of 700 mA h g(-1) after 100 cycles at a current density of 2 A g(-1) and 800 mA h g(-1) after 120 cycles at a current density of 1 A g(-1). The superior performance of HSi@C is attributed to the synergistic combination of the nanostructured material, the enhanced conductivity, and the presence of the central void space for Si expansion with little or no change in the volume of the entire HSi@C particle. This study is the first detailed investigation of the synthesis conditions to attain the desired structure of a hollow Si core with a conductive carbon shell. This study also offers guidelines to further enhance the specific capacity of HSi@C anodes in the future.« less

Hollow Silicon Nanospheres Encapsulated with a Thin Carbon Shell: An Electrochemical Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ashuri, Maziar; He, Qianran; Liu, Yuzi

In this study we have investigated the electrochemical properties of hollow silicon nanospheres encapsulated with a thin carbon shell, HSi@C, as a potential candidate for lithium-ion battery anodes. Hollow Si nanospheres are formed using a templating method which is followed by carbon coating via carbonization of a pyrrole precursor to form HSi@C. The synthesis conditions and the resulting structure of HSi@C have been studied in detail to obtain the target design of hollow Si nanospheres encapsulated with a carbon shell. The HSi@C obtained exhibits much better electrochemical cycle stability than both micro-and nano-size silicon anodes and deliver a stable specificmore » capacity of 700 mA h g(-1) after 100 cycles at a current density of 2 A g(-1) and 800 mA h g(-1) after 120 cycles at a current density of 1 A g(-1). The superior performance of HSi@C is attributed to the synergistic combination of the nanostructured material, the enhanced conductivity, and the presence of the central void space for Si expansion with little or no change in the volume of the entire HSi@C particle. This study is the first detailed investigation of the synthesis conditions to attain the desired structure of a hollow Si core with a conductive carbon shell. This study also offers guidelines to further enhance the specific capacity of HSi@C anodes in the future. (C) 2016 Elsevier Ltd. All rights reserved.« less

Block copolymers from ionic liquids for the preparation of thin carbonaceous shells

PubMed Central

Hanif, Sadaf; Oschmann, Bernd; Spetter, Dmitri; Tahir, Muhammad Nawaz; Tremel, Wolfgang

2017-01-01

This paper describes the controlled radical polymerization of an ionic-liquid monomer by RAFT polymerization. This allows the control over the molecular weight of ionic liquid blocks in the range of 8000 and 22000 and of the block-copolymer synthesis. In this work we focus on block copolymers with an anchor block. They can be used to control the formation of TiO2 nanoparticles, which are functionalized thereafter with a block of ionic-liquid polymer. Pyrolysis of these polymer functionalized inorganic nanoparticles leads to TiO2 nanoparticles coated with a thin carbonaceous shell. Such materials may, e.g., be interesting as battery materials. PMID:28904612

Block copolymers from ionic liquids for the preparation of thin carbonaceous shells.

PubMed

Hanif, Sadaf; Oschmann, Bernd; Spetter, Dmitri; Tahir, Muhammad Nawaz; Tremel, Wolfgang; Zentel, Rudolf

2017-01-01

This paper describes the controlled radical polymerization of an ionic-liquid monomer by RAFT polymerization. This allows the control over the molecular weight of ionic liquid blocks in the range of 8000 and 22000 and of the block-copolymer synthesis. In this work we focus on block copolymers with an anchor block. They can be used to control the formation of TiO 2 nanoparticles, which are functionalized thereafter with a block of ionic-liquid polymer. Pyrolysis of these polymer functionalized inorganic nanoparticles leads to TiO 2 nanoparticles coated with a thin carbonaceous shell. Such materials may, e.g., be interesting as battery materials.

Application of various elastic thin shell theories to blood flow problems

NASA Technical Reports Server (NTRS)

1972-01-01

Some existing theories, on elastic thin shells, are reviewed to ascertain their influence on the computation of phase velocities in fluid filled cylinders representing certain aspects of the behavior of arteries and veins in vivo. For physiologically meaningful parameters, including moderately large in plane prestrain that occurs in mammals, the results suggest that with one exception, the small differences in the formulations exercise little influence on the phase velocities. However, it is demonstrated that inclusion of the forces induced by the rotation of the hydrostatic pressure is essential or significantly erroneous torsional wave speeds result. Also the introduction of moderate implane prestrains that are present in living mammals is shown to lead to nonselfadjoint differential equations of motion, whose biorthogonal eigenvectors differ slightly from each other.

Calcium phosphate nanocoatings and nanocomposites, part 2: thin films for slow drug delivery and osteomyelitis.

PubMed

Ben-Nissan, Besim; Macha, Innocent; Cazalbou, Sophie; Choi, Andy H

2016-01-01

During the last two decades although many calcium phosphate based nanomaterials have been proposed for both drug delivery, and bone regeneration, their coating applications have been somehow slow due to the problems related to their complicated synthesis methods. In order to control the efficiency of local drug delivery of a biomaterial the critical pore sizes as well as good control of the chemical composition is pertinent. A variety of calcium phosphate based nanocoated composite drug delivery systems are currently being investigated. This review aims to give an update into the advancements of calcium phosphate nanocoatings and thin film nanolaminates. In particular recent research on PLA/hydroxyapatite composite thin films and coatings into the slow drug delivery for the possible treatment of osteomyelitis is covered.

Toward Effective Shell Modeling of Wrinkled Thin-Film Membranes Exhibiting Stress Concentrations

NASA Technical Reports Server (NTRS)

Tessler, Alexander; Sleight, David W.

2004-01-01

Geometrically nonlinear shell finite element analysis has recently been applied to solar-sail membrane problems in order to model the out-of-plane deformations due to structural wrinkling. Whereas certain problems lend themselves to achieving converged nonlinear solutions that compare favorably with experimental observations, solutions to tensioned membranes exhibiting high stress concentrations have been difficult to obtain even with the best nonlinear finite element codes and advanced shell element technology. In this paper, two numerical studies are presented that pave the way to improving the modeling of this class of nonlinear problems. The studies address the issues of mesh refinement and stress-concentration alleviation, and the effects of these modeling strategies on the ability to attain converged nonlinear deformations due to wrinkling. The numerical studies demonstrate that excessive mesh refinement in the regions of stress concentration may be disadvantageous to achieving wrinkled equilibrium states, causing the nonlinear solution to lock in the membrane response mode, while totally discarding the very low-energy bending response that is necessary to cause wrinkling deformation patterns. An element-level, strain-energy density criterion is suggested for facilitating automated, adaptive mesh refinements specifically aimed at the modeling of thin-film membranes undergoing wrinkling deformations.

Global Curvature Buckling and Snapping of Spherical Shells.

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Steranka, Mark; Bade, Abdikhalaq; Trejo, Miguel; Holmes, Douglas

A spherical shell under external pressure will eventually buckle locally through the development of a dimple. However, when a free spherical shell is subject to variations in natural curvature, it will either buckle globally or snap towards a buckled configuration. We study the similarities and differences between pressure and curvature instabilities in spherical shells. We show how the critical buckling natural curvature is largely independent of the thinness and half-angle of the shell, while the critical snapping natural curvature grows linearly with the half-angle. As a result, we demonstrate how a critical half-angle, depending only on the thinness of the shell, sets the threshold between two different kinds of snapping: as a rule of thumb, shallow shells snap into everted shells, while deep shells snap into buckled shells. As the developed models are purely geometrical, the results are applicable to a large variety of stimuli and scales. NSF CAREER CMMI-1454153.

Explicit formulation of an anisotropic Allman/DKT 3-node thin triangular flat shell elements

NASA Astrophysics Data System (ADS)

Ertas, A.; Krafcik, J. T.; Ekwaro-Osire, S.

A simple, explicit formulation of the stiffness matrix for an anisotropic, 3-node, thin triangular, flat shell element in global coordinates is presented. An Allman triangle is used for membrane stiffness. The membrane stiffness matrix is explicitly derived by applying an Allman transformation to a Felippa 6-node linear strain triangle (LST). Bending stiffness is incorporated by the use of a discrete Kirchhoff triangle (DKT) bending triangle. Stiffness terms resulting from anisotropic membrane-bending coupling are included by integrating, in area coordinates, membrane and bending strain-displacement matrices.

Elementary surface chemistry during CuO/Al nanolaminate-thermite synthesis: copper and oxygen deposition on aluminum (111) surfaces.

PubMed

Lanthony, Cloé; Guiltat, Mathilde; Ducéré, Jean Marie; Verdier, Agnes; Hémeryck, Anne; Djafari-Rouhani, Mehdi; Rossi, Carole; Chabal, Yves J; Estève, Alain

2014-09-10

The surface chemistry associated with the synthesis of energetic nanolaminates controls the formation of the critical interfacial layers that dominate the performances of nanothermites. For instance, the interaction of Al with CuO films or CuO with Al films needs to be understood to optimize Al/CuO nanolaminates. To that end, the chemical mechanisms occurring during early stages of molecular CuO adsorption onto crystalline Al(111) surfaces are investigated using density functional theory (DFT) calculations, leading to the systematic determination of their reaction enthalpies and associated activation energies. We show that CuO undergoes dissociative chemisorption on Al(111) surfaces, whereby the Cu and O atoms tend to separate from each other. Both Cu and O atoms form islands with different properties. Copper islanding fosters Cu insertion (via surface site exchange mechanism) into the subsurface, while oxygen islands remain stable at the surface. Above a critical local oxygen coverage, aluminum atoms are extracted from the Al surface, leading to oxygen-aluminum intermixing and the formation of aluminum oxide (γ-alumina). For Cu and O co-deposition, copper promotes oxygen-aluminum interaction by oxygen segregation and separates the resulting oxide from the Al substrate by insertion into Al and stabilization below the oxide front, preventing full mixing of Al, Cu, and O species.

Platinum-coated non-noble metal-noble metal core-shell electrocatalysts

DOEpatents

Adzic, Radoslav; Zhang, Junliang; Mo, Yibo; Vukmirovic, Miomir

2015-04-14

Core-shell particles encapsulated by a thin film of a catalytically active metal are described. The particles are preferably nanoparticles comprising a non-noble core with a noble metal shell which preferably do not include Pt. The non-noble metal-noble metal core-shell nanoparticles are encapsulated by a catalytically active metal which is preferably Pt. The core-shell nanoparticles are preferably formed by prolonged elevated-temperature annealing of nanoparticle alloys in an inert environment. This causes the noble metal component to surface segregate and form an atomically thin shell. The Pt overlayer is formed by a process involving the underpotential deposition of a monolayer of a non-noble metal followed by immersion in a solution comprising a Pt salt. A thin Pt layer forms via the galvanic displacement of non-noble surface atoms by more noble Pt atoms in the salt. The overall process is a robust and cost-efficient method for forming Pt-coated non-noble metal-noble metal core-shell nanoparticles.

Monte Carlo simulations of nematic and chiral nematic shells

NASA Astrophysics Data System (ADS)

Wand, Charlie R.; Bates, Martin A.

2015-01-01

We present a systematic Monte Carlo simulation study of thin nematic and cholesteric shells with planar anchoring using an off-lattice model. The results obtained using the simple model correspond with previously published results for lattice-based systems, with the number, type, and position of defects observed dependent on the shell thickness with four half-strength defects in a tetrahedral arrangement found in very thin shells and a pair of defects in a bipolar (boojum) configuration observed in thicker shells. A third intermediate defect configuration is occasionally observed for intermediate thickness shells, which is stabilized in noncentrosymmetric shells of nonuniform thickness. Chiral nematic (cholesteric) shells are investigated by including a chiral term in the potential. Decreasing the pitch of the chiral nematic leads to a twisted bipolar (chiral boojum) configuration with the director twist increasing from the inner to the outer surface.

Computation of Thin-Walled Prismatic Shells

NASA Technical Reports Server (NTRS)

Vlasov, V. Z.

1949-01-01

We consider a prismatic shell consisting of a finite number of narrow rectangular plates and having in the cross-section a finite number of closed contours (fig. 1(a)). We shall assume that the rectangular plates composing the shell are rigidly joined so that there is no motion of any kind of one plate relative to the others meeting at a given connecting line. The position of a point on the middle prismatic surface is considered to be defined by the coordinate z, the distance to a certain initial cross-section z = O, end the coordinate s determining its position on the contour of the cross-section.

Comparisons of Backscattering from Cylindrical Shells Described by Thin Shell and Elasticity Theories.

DTIC Science & Technology

1991-03-04

term that describes inextensional motion. The first equation represents the normal stress at the midsurface of the shell, which is equal to the...that the normal velocity at the midsurface of the shell is proportional to the normal derivative of the total pressw e. The scattered pressure ps can

Enhance the photoluminescence and radioluminescence of La2Zr2O7:Eu3+ core nanoparticles by coating with a thin Y2O3 shell

NASA Astrophysics Data System (ADS)

Pokhrel, Madhab; Burger, Arnold; Groza, Michael; Mao, Yuanbing

2017-06-01

We report the generation of La2Zr2O7:5%Eu3+@Y2O3 (LZO5E@YO) core@shell crystalline inorganic-inorganic heterogeneous nanoparticles (NPs). The Y2O3 (YO) shell coating process based on a chemical sol-gel method led to the growth of a thin YO shell on the ordered pyrochlore La2Zr2O7:5%Eu3+ (LZO5E) core NPs. Photoluminescence (PL) analyses demonstrated a blue shift of 15 nm on charge transfer (CT) excitation band of the core@shell NPs from that of the core NPs. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) along x-ray diffraction (XRD), Fourier-transform Infrared spectroscopy (FTIR) and x-ray photoelectron spectroscopy (XPS) studies confirmed the formation of the thin YO layer over the LZO5E core NPs. The PL intensity of the LZO5E@YO core@shell NPs was enhanced by three fold compared to that of the LZO5E core NPs, and higher quantum yield (QY) was observed for the former compared to the original NPs by more than 70%. Higher radioluminescence (RL) emission was also observed for the core@shell NPs compared to the core NPs. Our ability of obtaining near-perfect core@shell heterostructure with enhanced luminescence performance opens the door for the development of efficient La2Zr2O7:5%Eu3+@Y2O3 NPs for both optical and x-ray scintillation applications.

On the mechanics of elastic lines in thin shells

NASA Astrophysics Data System (ADS)

Benet, Eduard; Vernerey, Franck

The deformation of soft shells in nature and engineering is often conditioned by the presence of lines whose mechanical properties are different from the shell. For instance, the deformation of tree leaves is conditioned by the presence of harder stems, and cell mitosis is driven by a stiffening line along its membrane. From an experimental standpoint, many groups have taken advantage of this feature to develop self-actuated shells with prescribed deformations. Examples include the polymerization of gels along certain lines, or the inclusion of stiffer lines via 3D printing. However, there is not yet a general continuum theory that accounts for this type of discontinuity within the membrane. Hence, we extend the general shell theory to account for the inclusion of a line that potentially induces jumps in stresses, couple stresses and moments, across its thickness. This is achieved via coupling the rod and the membrane deformations, and ensuring continuity of displacements. The model is then applied to three important problems: a constriction disc inside a shell of revolution, the induced twisting of a shell via the torsion of an embedded line, and the effect of an helicoidal line on the uni-axial deformation of a cylindrical shell. National Science Foundation CAREER award 1350090.

The Experimental Study of the Performance of Nano-Thin Polyelectrolyte Shell for Dental Pulp Stem Cells Immobilization.

PubMed

Grzeczkowicz, A; Granicka, L H; Maciejewska, I; Strawski, M; Szklarczyk, M; Borkowska, M

2015-12-01

Carious is the most frequent disease of mineralized dental tissues which might result in dental pulp inflammation and mortality. In such cases an endodontic treatment is the only option to prolong tooth functioning in the oral cavity; however, in the cases of severe pulpitis, especially when complicated with periodontal tissue inflammation, the endodontic treatment might not be enough to protect against tooth loss. Thus, keeping the dental pulp viable and/or possibility of the reconstruction of a viable dental pulp complex, appears to become a critical factor for carious and/or pulp inflammation treatment. The nowadays technologies, which allow handling dental pulp stem cells (DPSC), seem to bring us closer to the usage of dental stem cells for tooth tissues reconstruction. Thus, DPSC immobilized within nano-thin polymeric shells, allowing for a diffusion of produced factors and separation from bacteria, may be considered as a cover system supporting technology of dental pulp reconstruction. The DPSC were immobilized using a layer-by-layer technique within nano-thin polymeric shells constructed and modified by nanostructure involvement to ensure the layers stability and integrity as well as separation from bacterial cells. The cytotoxity of the material used for membrane production was assessed on the model of adherent cells. The performance of DPSC nano-coating was assessed in vitro. Membrane coatings showed no cytotoxicity on the immobilized cells. The presence of coating shell was confirmed with flow cytometry, atomic force microscopy and visualized with fluorescent microscopy. The transfer of immobilized DPSC within the membrane system ensuring cells integrity, viability and protection from bacteria should be considered as an alternative method for dental tissues transportation and regeneration.

Design and development of thin quartz glass WFXT polynomial mirror shells by direct polishing

NASA Astrophysics Data System (ADS)

Proserpio, L.; Campana, S.; Citterio, O.; Civitani, M.; Combrinck, H.; Conconi, P.; Cotroneo, V.; Freeman, R.; Langstrof, P.; Mattaini, E.; Morton, R.; Oberle, B.; Pareschi, G.; Parodi, G.; Pels, C.; Schenk, C.; Stock, R.; Tagliaferri, G.

2010-07-01

The Wide Field X-ray Telescope (WFXT) is a medium class mission for X-ray surveys of the sky with an unprecedented area and sensitivity. In order to meet the effective area requirement, the design of the optical system is based on very thin mirror shells, with thicknesses in the 1-2 mm range. In order to get the desired angular resolution (10 arcsec requirement, 5 arcsec goal) across the entire 1x1 degree FOV (Field Of View), the design of the optical system is based on nested modified grazing incidence Wolter-I mirrors realized with polynomial profiles, focal plane curvature and plate scale corrections. This design guarantees an increased angular resolution at large off-axis angle with respect to the normally used Wolter I configuration, making WFXT ideal for survey purposes. The WFXT X-ray Telescope Assembly is composed by three identical mirror modules of 78 nested shells each, with diameter up to 1.1 m. The epoxy replication process with SiC shells has already been proved to be a valuable technology to meet the angular resolution requirement of 10 arcsec. To further mature the telescope manufacturing technology and to achieve the goal of 5 arcsec, a deterministic direct polishing method is under investigation. The direct polishing method has already been used for past missions (as Einstein, Rosat, Chandra): the technological challenge now is to apply it for almost ten times thinner shells. Under investigation is quartz glass (fused silica), a well-known material with good thermo-mechanical and polishability characteristics that could meet our goal in terms of mass and stiffness, with significant cost and time saving with respect to SiC. Our approach is based on two main steps: first quartz glass tubes available on the market are grinded to conical profiles, and second the obtained shells are polished to the required polynomial profiles by CNC (Computer Numerical Control) polishing machine. In this paper, the first results of the direct grinding and polishing of

Tensile behavior and flow stress anisotropy of accumulative roll bonded Cu-Nb nanolaminates

DOE PAGES

Nizolek, Thomas; Beyerlein, Irene J.; Mara, Nathan A.; ...

2016-02-01

The flow stress, ductility, and in-plane anisotropy are evaluated for bulk accumulative roll bonded copper-niobium nanolaminates with layer thicknesses ranging from 1.8 μm to 15 nm. Uniaxial tensile tests conducted parallel to the rolling direction and transverse direction demonstrate that ductility generally decreases with decreasing layer thickness; however, at 30 nm, both high strengths (1200 MPa) and significant ductility (8%) are achieved. The yield strength increases monotonically with decreasing layer thickness, consistent with the Hall-Petch relationship, and significant in-plane flow stress anisotropy is observed. As a result, Taylor polycrystal modeling is used to demonstrate that crystallographic texture is responsible formore » the in-plane anisotropy and that the effects of texture dominate even at nanoscale layer thicknesses.« less

Excitation of epsilon-near-zero resonance in ultra-thin indium tin oxide shell embedded nanostructured optical fiber.

PubMed

Minn, Khant; Anopchenko, Aleksei; Yang, Jingyi; Lee, Ho Wai Howard

2018-02-05

We report a novel optical waveguide design of a hollow step index fiber modified with a thin layer of indium tin oxide (ITO). We show an excitation of highly confined waveguide mode in the proposed fiber near the wavelength where permittivity of ITO approaches zero. Due to the high field confinement within thin ITO shell inside the fiber, the epsilon-near-zero (ENZ) mode can be characterized by a peak in modal loss of the hybrid waveguide. Our results show that such in-fiber excitation of ENZ mode is due to the coupling of the guided core mode to the thin-film ENZ mode. We also show that the phase matching wavelength, where the coupling takes place, varies depending on the refractive index of the constituents inside the central bore of the fiber. These ENZ nanostructured optical fibers have many potential applications, for example, in ENZ nonlinear and magneto-optics, as in-fiber wavelength-dependent filters, and as subwavelength fluid channel for optical and bio-photonic sensing.

On the determination of χ(2) in thin films: a comparison of one-beam second-harmonic generation measurement methodologies

PubMed Central

Hermans, Artur; Kieninger, Clemens; Koskinen, Kalle; Wickberg, Andreas; Solano, Eduardo; Dendooven, Jolien; Kauranen, Martti; Clemmen, Stéphane; Wegener, Martin; Koos, Christian; Baets, Roel

2017-01-01

The determination of the second-order susceptibility (χ(2)) of thin film samples can be a delicate matter since well-established χ(2) measurement methodologies such as the Maker fringe technique are best suited for nonlinear materials with large thicknesses typically ranging from tens of microns to several millimeters. Here we compare two different second-harmonic generation setups and the corresponding measurement methodologies that are especially advantageous for thin film χ(2) characterization. This exercise allows for cross-checking the χ(2) obtained for identical samples and identifying the main sources of error for the respective techniques. The development of photonic integrated circuits makes nonlinear thin films of particular interest, since they can be processed into long waveguides to create efficient nonlinear devices. The investigated samples are ABC-type nanolaminates, which were reported recently by two different research groups. However, the subsequent analysis can be useful for all researchers active in the field of thin film χ(2) characterization. PMID:28317938

Design and characterization of terahertz-absorbing nano-laminates of dielectric and metal thin films.

PubMed

Bolakis, C; Grbovic, D; Lavrik, N V; Karunasiri, G

2010-07-05

A terahertz-absorbing thin-film stack, containing a dielectric Bragg reflector and a thin chromium metal film, was fabricated on a silicon substrate for applications in bi-material terahertz (THz) sensors. The Bragg reflector is to be used for optical readout of sensor deformation under THz illumination. The THz absorption characteristics of the thin-film composite were measured using Fourier transform infrared spectroscopy. The absorption of the structure was calculated both analytically and by finite element modeling and the two approaches agreed well. Finite element modeling provides a convenient way to extract the amount of power dissipation in each layer and is used to quantify the THz absorption in the multi-layer stack. The calculation and the model were verified by experimentally characterizing the multi-layer stack in the 3-5 THz range. The measured and simulated absorption characteristics show a reasonably good agreement. It was found that the composite film absorbed about 20% of the incident THz power. The model was used to optimize the thickness of the chromium film for achieving high THz absorption and found that about 50% absorption can be achieved when film thickness is around 9 nm.

Determining linear vibration frequencies of a ferromagnetic shell

NASA Astrophysics Data System (ADS)

Bagdoev, A. G.; Vardanyan, A. V.; Vardanyan, S. V.; Kukudzhanov, V. N.

2007-10-01

The problems of determining the roots of dispersion equations for free bending vibrations of thin magnetoelastic plates and shells are of both theoretical and practical interest, in particular, in studying vibrations of metallic structures used in controlled thermonuclear reactors. These problems were solved on the basis of the Kirchhoff hypothesis in [1-5]. In [6], an exact spatial approach to determining the vibration frequencies of thin plates was suggested, and it was shown that it completely agrees with the solution obtained according to the Kirchhoff hypothesis. In [7-9], this exact approach was used to solve the problem on vibrations of thin magnetoelastic plates, and it was shown by cumbersome calculations that the solutions obtained according to the exact theory and the Kirchhoff hypothesis differ substantially except in a single case. In [10], the equations of the dynamic theory of elasticity in the axisymmetric problem are given. In [11], the equations for the vibration frequencies of thin ferromagnetic plates with arbitrary conductivity were obtained in the exact statement. In [12], the Kirchhoff hypothesis was used to obtain dispersion relations for a magnetoelastic thin shell. In [5, 13-16], the relations for the Maxwell tensor and the ponderomotive force for magnetics were presented. In [17], the dispersion relations for thin ferromagnetic plates in the transverse field in the spatial statement were studied analytically and numerically. In the present paper, on the basis of the exact approach, we study free bending vibrations of a thin ferromagnetic cylindrical shell. We obtain the exact dispersion equation in the form of a sixth-order determinant, which can be solved numerically in the case of a magnetoelastic thin shell. The numerical results are presented in tables and compared with the results obtained by the Kirchhoff hypothesis. We show a large number of differences in the results, even for the least frequency.

Uniform thin films of CdSe and CdSe(ZnS) core(shell) quantum dots by sol-gel assembly: enabling photoelectrochemical characterization and electronic applications.

PubMed

Korala, Lasantha; Wang, Zhijie; Liu, Yi; Maldonado, Stephen; Brock, Stephanie L

2013-02-26

Optoelectronic properties of quantum dot (QD) films are limited by (1) poor interfacial chemistry and (2) nonradiative recombination due to surface traps. To address these performance issues, sol-gel methods are applied to fabricate thin films of CdSe and core(shell) CdSe(ZnS) QDs. High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) imaging with chemical analysis confirms that the surface of the QDs in the sol-gel thin films are chalcogen-rich, consistent with an oxidative-induced gelation mechanism in which connectivity is achieved by formation of dichalcogenide covalent linkages between particles. The ligand removal and assembly process is probed by thermogravimetric, spectroscopic, and microscopic studies. Further enhancement of interparticle coupling via mild thermal annealing, which removes residual ligands and reinforces QD connectivity, results in QD sol-gel thin films with superior charge transport properties, as shown by a dramatic enhancement of electrochemical photocurrent under white light illumination relative to thin films composed of ligand-capped QDs. A more than 2-fold enhancement in photocurrent, and a further increase in photovoltage can be achieved by passivation of surface defects via overcoating with a thin ZnS shell. The ability to tune interfacial and surface characteristics for the optimization of photophysical properties suggests that the sol-gel approach may enable formation of QD thin films suitable for a range of optoelectronic applications.

Uniform Thin Films of CdSe and CdSe(ZnS) Core(shell) Quantum Dots by Sol-Gel Assembly: Enabling Photoelectrochemical Characterization and Electronic Applications

PubMed Central

Korala, Lasantha; Wang, Zhijie; Liu, Yi; Maldonado, Stephen; Brock, Stephanie L.

2013-01-01

Optoelectronic properties of quantum dot (QD) films are limited by (1) poor interfacial chemistry and (2) non-radiative recombination due to surface traps. To address these performance issues, sol-gel methods are applied to fabricate thin films of CdSe and core(shell) CdSe(ZnS) QDs. High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) imaging with chemical analysis confirms that the surface of the QDs in the sol-gel thin films are chalcogen-rich, consistent with an oxidative-induced gelation mechanism in which connectivity is achieved by formation of dichalcogenide covalent linkages between particles. The ligand removal and assembly process is probed by thermogravimetric, spectroscopic and microscopic studies. Further enhancement of inter-particle coupling via mild thermal annealing, which removes residual ligands and reinforces QD connectivity, results in QD sol-gel thin films with superior charge transport properties, as shown by a dramatic enhancement of electrochemical photocurrent under white light illumination relative to thin films composed of ligand-capped QDs. A more than 2-fold enhancement in photocurrent, and a further increase in photovoltage can be achieved by passivation of surface defects via overcoating with a thin ZnS shell. The ability to tune interfacial and surface characteristics for the optimization of photophysical properties suggests that the sol-gel approach may enable formation of QD thin films suitable for a range of optoelectronic applications. PMID:23350924

Fabrication and Characterization of Thermite Reactive Nano-Laminates

NASA Astrophysics Data System (ADS)

Lee, Evyn; Maria, Jon-Paul; Matveev, Sergey; Dlott, Dana; Rost, Christina; Hopkins, Patrick

2017-06-01

Results of fabrication and characterization of thermite reactive nano-laminates (RNLs) via magnetron sputtering will be presented. The samples were created in a bilayer geometry of a metal and metal oxide at varied thicknesses to alter the amount of interfacial area readily available to participate in the reaction. Two systems were investigated to characterize the RNL system: Al/CuO and Zr/CuO. The Al/CuO system was fabricated at a constant overall stack thickness of nearly one micron with varied numbers of bilayers (one to seven). Thermal conductivity and interface conductance of the Al/CuO system were investigated via time-domain thermoreflectance (TDTR). The Zr/CuO system was also fabricated at varying bilayer thickness and was characterized via high throughput shock studies to characterize the oxygen transfer process at short time scales. Emissions were obtained via a flyer plate impact at velocities ranging 0.5- 2 km s-1 at durations of 4-16 ns. The reaction impact threshold was found to be at velocities lower than 0.7(+/-0.05) km s-1. At impact velocities above the threshold, the reaction onset is seen at approximately 1 μs. ARO MURI: Multimodal energy flow at atomically engineered interfaces.

Electrostatically assisted fabrication of silver-dielectric core/shell nanoparticles thin film capacitor with uniform metal nanoparticle distribution and controlled spacing.

PubMed

Li, Xue; Niitsoo, Olivia; Couzis, Alexander

2016-03-01

An electrostatically-assisted strategy for fabrication of thin film composite capacitors with controllable dielectric constant (k) has been developed. The capacitor is composed of metal-dielectric core/shell nanoparticle (silver/silica, Ag@SiO2) multilayer films, and a backfilling polymer. Compared with the simple metal particle-polymer mixtures where the metal nanoparticles (NP) are randomly dispersed in the polymer matrix, the metal volume fraction in our capacitor was significantly increased, owing to the densely packed NP multilayers formed by the electrostatically assisted assembly process. Moreover, the insulating layer of silica shell provides a potential barrier that reduces the tunneling current between neighboring Ag cores, endowing the core/shell nanocomposites with a stable and relatively high dielectric constant (k) and low dielectric loss (D). Our work also shows that the thickness of the SiO2 shell plays a dominant role in controlling the dielectric properties of the nanocomposites. Control over metal NP separation distance was realized not only by variation the shell thickness of the core/shell NPs but also by introducing a high k nanoparticle, barium strontium titanate (BST) of relatively smaller size (∼8nm) compared to 80-160nm of the core/shell Ag@SiO2 NPs. The BST assemble between the Ag@SiO2 and fill the void space between the closely packed core/shell NPs leading to significant enhancement of the dielectric constant. This electrostatically assisted assembly method is promising for generating multilayer films of a large variety of NPs over large areas at low cost. Copyright © 2015 Elsevier Inc. All rights reserved.

Three-dimensional flat shell-to-shell coupling: numerical challenges

NASA Astrophysics Data System (ADS)

Guo, Kuo; Haikal, Ghadir

2017-11-01

The node-to-surface formulation is widely used in contact simulations with finite elements because it is relatively easy to implement using different types of element discretizations. This approach, however, has a number of well-known drawbacks, including locking due to over-constraint when this formulation is used as a twopass method. Most studies on the node-to-surface contact formulation, however, have been conducted using solid elements and little has been done to investigate the effectiveness of this approach for beam or shell elements. In this paper we show that locking can also be observed with the node-to-surface contact formulation when applied to plate and flat shell elements even with a singlepass implementation with distinct master/slave designations, which is the standard solution to locking with solid elements. In our study, we use the quadrilateral four node flat shell element for thin (Kirchhoff-Love) plate and thick (Reissner-Mindlin) plate theory, both in their standard forms and with improved formulations such as the linked interpolation [1] and the Discrete Kirchhoff [2] elements for thick and thin plates, respectively. The Lagrange multiplier method is used to enforce the node-to-surface constraints for all elements. The results show clear locking when compared to those obtained using a conforming mesh configuration.

Redirection and Splitting of Sound Waves by a Periodic Chain of Thin Perforated Cylindrical Shells

NASA Astrophysics Data System (ADS)

Bozhko, Andrey; Sánchez-Dehesa, José; Cervera, Francisco; Krokhin, Arkadii

2017-06-01

The scattering of sound by finite and infinite chains of equally spaced perforated metallic cylindrical shells in an ideal (inviscid) and viscous fluid is theoretically studied using rigorous analytical and numerical approaches. Because of perforations, a chain of thin shells is practically transparent for sound within a wide range of frequencies. It is shown that strong scattering and redirection of sound by 90° may occur only for a discrete set of frequencies (Wood's anomalies) where the leaky eigenmodes are excited. The spectrum of eigenmodes consists of antisymmetric and symmetric branches with normal and anomalous dispersion, respectively. The antisymmetric eigenmode turns out to be a deaf mode, since it cannot be excited at normal incidence. However, at slightly oblique incidence, both modes can be resonantly excited at different but close frequencies. The symmetric mode, due to its anomalous dispersion, scatters sound in the "wrong" direction. This property may find an application for the splitting of the two resonant harmonics of the incoming signal into two beams propagating along the chain in the opposite directions. A chain of perforated cylinders may also be used as a passive antenna that detects the direction to the incoming signal by measuring the frequencies of the waves excited in the chain. Calculations are presented for aluminum shells in viscous air where the effects of anomalous scattering, redirection, and signal splitting are well manifested.

Isogeometric Kirchhoff-Love shell formulations for biological membranes

PubMed Central

Tepole, Adrián Buganza; Kabaria, Hardik; Bletzinger, Kai-Uwe; Kuhl, Ellen

2015-01-01

Computational modeling of thin biological membranes can aid the design of better medical devices. Remarkable biological membranes include skin, alveoli, blood vessels, and heart valves. Isogeometric analysis is ideally suited for biological membranes since it inherently satisfies the C1-requirement for Kirchhoff-Love kinematics. Yet, current isogeometric shell formulations are mainly focused on linear isotropic materials, while biological tissues are characterized by a nonlinear anisotropic stress-strain response. Here we present a thin shell formulation for thin biological membranes. We derive the equilibrium equations using curvilinear convective coordinates on NURBS tensor product surface patches. We linearize the weak form of the generic linear momentum balance without a particular choice of a constitutive law. We then incorporate the constitutive equations that have been designed specifically for collagenous tissues. We explore three common anisotropic material models: Mooney-Rivlin, May Newmann-Yin, and Gasser-Ogden-Holzapfel. Our work will allow scientists in biomechanics and mechanobiology to adopt the constitutive equations that have been developed for solid three-dimensional soft tissues within the framework of isogeometric thin shell analysis. PMID:26251556

High content reduced graphene oxide reinforced copper with a bioinspired nano-laminated structure and large recoverable deformation ability

PubMed Central

Xiong, Ding-Bang; Cao, Mu; Guo, Qiang; Tan, Zhanqiu; Fan, Genlian; Li, Zhiqiang; Zhang, Di

2016-01-01

By using CuO/graphene-oxide/CuO sandwich-like nanosheets as the building blocks, bulk nacre-inspired copper matrix nano-laminated composite reinforced by molecular-level dispersed and ordered reduced graphene oxide (rGO) with content as high as ∼45 vol% was fabricated via a combined process of assembly, reduction and consolidation. Thanks to nanoconfinement effect, reinforcing effect, as well as architecture effect, the nanocomposite shows increased specific strength and at least one order of magnitude greater recoverable deformation ability as compared with monolithic Cu matrix. PMID:27647264

Simulation of the stress computation in shells

NASA Technical Reports Server (NTRS)

Salama, M.; Utku, S.

1978-01-01

A self-teaching computer program is described, whereby the stresses in thin shells can be computed with good accuracy using the best fit approach. The program is designed for use in interactive game mode to allow the structural engineer to learn about (1) the major sources of difficulties and associated errors in the computation of stresses in thin shells, (2) possible ways to reduce the errors, and (3) trade-off between computational cost and accuracy. Included are derivation of the computational approach, program description, and several examples illustrating the program usage.

Long-term stable water vapor permeation barrier properties of SiN/SiCN/SiN nanolaminated multilayers grown by plasma-enhanced chemical vapor deposition at extremely low pressures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, Bum Ho, E-mail: bhchoi@kitech.re.kr; Lee, Jong Ho

2014-08-04

We investigated the water vapor permeation barrier properties of 30-nm-thick SiN/SiCN/SiN nanolaminated multilayer structures grown by plasma enhanced chemical vapor deposition at 7 mTorr. The derived water vapor transmission rate was 1.12 × 10{sup −6} g/(m{sup 2} day) at 85 °C and 85% relative humidity, and this value was maintained up to 15 000 h of aging time. The X-ray diffraction patterns revealed that the nanolaminated film was composed of an amorphous phase. A mixed phase was observed upon performing high resolution transmission electron microscope analysis, which indicated that a thermodynamically stable structure was formed. It was revealed amorphous SiN/SiCN/SiN multilayer structures that are freemore » from intermixed interface defects effectively block water vapor permeation into active layer.« less

Electroluminescent Yb2O3:Er and Yb2Si2O7:Er nanolaminate films fabricated by atomic layer deposition on silicon

NASA Astrophysics Data System (ADS)

Ouyang, Zhongtao; Yang, Yang; Sun, Jiaming

2018-06-01

Atomic layer doped Yb2O3:Er and Yb2Si2O7:Er nanolaminate films are fabricated on silicon by atomic layer deposition, and ∼1530 nm electroluminescence (EL) is obtained from the metal-oxide-semiconductor light-emitting devices (MOSLEDs) based on these films. The Yb2O3 films transfer to Yb2Si2O7 phase after annealing above 1000 °C. Intense photoluminescence from Yb2Si2O7 film confirms high efficiency and energy transfer under optical excitation, but the limited electron conduction restricts the EL performance. EL from the Yb2O3:Er MOSLED outperforms, presenting an external quantum efficiency up to 8.5% and the power efficiency of 1 × 10-3. The EL is derived to result from the impact excitation of Er3+ ions by hot electrons, which stem from Fowler-Nordheim tunneling mechanism under sufficient bias voltage. The critical distance for the cross relaxation of doped Er3+ ions in nanolaminate Yb2O3 matrix is experimentally determined to be ∼3 nm. Such devices manifest the technological potential of Er-doped Yb-oxides for applications in silicon-based optoelectronics.

Three dimensional (3D) microstructure-based finite element modeling of Al-SiC nanolaminates using focused ion beam (FIB) tomography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayer, Carl R.

Al-SiC nanolaminate composites show promise as high performance coating materials due to their combination of strength and toughness. Although a significant amount of modeling effort has been focused on materials with an idealized flat nanostructure, experimentally these materials exhibit complex undulating layer geometries. This work utilizes FIB tomography to characterize this nanostructure in 3D and finite element modeling to determine the effect that this complex structure has on the mechanical behavior of these materials. A sufficiently large volume was characterized such that a 1 × 2 μm micropillar could be generated from the dataset and compared directly to experimental results.more » The mechanical response from this nanostructure was then compared to pillar models using simplified structures with perfectly flat layers, layers with sinusoidal waviness, and layers with arc segment waviness. The arc segment based layer geometry showed the best agreement with the experimentally determined structure, indicating it would be the most appropriate geometry for future modeling efforts. - Highlights: •FIB tomography was used to determine the structure of an Al-SiC nanolaminate in 3D. •FEM was used to compare the deformation of the nanostructure to experimental results. •Idealized structures from literature were compared to the FIB determined structure. •Arc segment based structures approximated the FIB determined structure most closely.« less

Molecular dynamics study of strengthening mechanism of nanolaminated graphene/Cu composites under compression.

PubMed

Weng, Shayuan; Ning, Huiming; Fu, Tao; Hu, Ning; Zhao, Yinbo; Huang, Cheng; Peng, Xianghe

2018-02-15

Molecular dynamics simulations of nanolaminated graphene/Cu (NGCu) and pure Cu under compression are conducted to investigate the underlying strengthening mechanism of graphene and the effect of lamella thickness. It is found that the stress-strain curves of NGCu undergo 3 regimes i.e. the elastic regime I, plastic strengthening regime II and plastic flow regime III. Incorporating graphene monolayer is proved to simultaneously contribute to the strength and ductility of the composites and the lamella thickness has a great effect on the mechanical properties of NGCu composites. Different strengthening mechanisms play main role in different regimes, the transition of mechanisms is found to be related to the deformation behavior. Graphene affected zone is developed and integrated with rule of mixtures and confined layer slip model to describe the elastic properties of NGCu and the strengthening effect of the incorporated graphene.

Non-axisymmetric α2Ω-dynamo waves in thin stellar shells

NASA Astrophysics Data System (ADS)

Bassom, Andrew P.; Kuzanyan, Kirill M.; Sokoloff, Dmitry; Soward, Andrew M.

2005-04-01

Linear α2Ω-dynamo waves are investigated in a thin turbulent, differentially rotating convective stellar shell. A simplified one-dimensional model is considered and an asymptotic solution constructed based on the small aspect ratio of the shell. In a previous paper Griffiths et al. (Griffiths, G.L., Bassom, A.P., Soward, A.M. and Kuzanyan, K.M., Nonlinear α2Ω-dynamo waves in stellar shells, Geophys. Astrophys. Fluid Dynam., 2001, 94, 85-133) considered the modulation of dynamo waves, linked to a latitudinal-dependent local α-effect and radial gradient of the zonal shear flow. These effects are measured at latitude θ by the magnetic Reynolds numbers Rαf(θ) and RΩg(θ). The modulated Parker wave, which propagates towards the equator, is localised at some mid-latitude θp under a Gaussian envelope. In this article, we include the influence of a latitudinal-dependent zonal flow possessing angular velocity Ω*(θ) and consider the possibility of non-axisymmetric dynamo waves with azimuthal wave number m. We find that the critical dynamo number Dc = RαRΩ is minimised by axisymmetric modes in the αΩ-limit (Rα→0). On the other hand, when Rα ≠ 0 there may exist a band of wave numbers 0 < m < m† for which the non-axisymmetric modes have a smaller Dc than in the axisymmetric case. Here m† is regarded as a continuous function of Rα with the property m†→0 as Rα→0 and the band is only non-empty when m† >1, which happens for sufficiently large Rα. The preference for non-axisymmetric modes is possible because the wind-up of the non-axisymmetric structures can be compensated by phase mixing inherent to the α2Ω-dynamo. For parameter values resembling solar conditions, the Parker wave of maximum dynamo activity at latitude θp not only propagates equatorwards but also westwards relative to the local angular velocity Ω*(θp). Since the critical dynamo number Dc = RαRΩ is O (1) for small Rα, the condition m�

Finite Rotation Analysis of Highly Thin and Flexible Structures

NASA Technical Reports Server (NTRS)

Clarke, Greg V.; Lee, Keejoo; Lee, Sung W.; Broduer, Stephen J. (Technical Monitor)

2001-01-01

Deployable space structures such as sunshields and solar sails are extremely thin and highly flexible with limited bending rigidity. For analytical investigation of their responses during deployment and operation in space, these structures can be modeled as thin shells. The present work examines the applicability of the solid shell element formulation to modeling of deployable space structures. The solid shell element formulation that models a shell as a three-dimensional solid is convenient in that no rotational parameters are needed for the description of kinematics of deformation. However, shell elements may suffer from element locking as the thickness becomes smaller unless special care is taken. It is shown that, when combined with the assumed strain formulation, the solid shell element formulation results in finite element models that are free of locking even for extremely thin structures. Accordingly, they can be used for analysis of highly flexible space structures undergoing geometrically nonlinear finite rotations.

Microbubble-Triggered Spontaneous Separation of Transparent Thin Films from Substrates Using Evaporable Core-Shell Nanocapsules.

PubMed

Son, Intae; Lee, Byungsun; Kim, Jae Hong; Kim, Chunho; Yoo, Ji Yong; Ahn, Byung Wook; Hwang, Jeongho; Lee, Jonghyuk; Lee, Jun Hyup

2018-05-23

The spontaneous separation of a polymer thin film from a substrate is an innovative technology that will enable material recycling and reduce manufacturing cost in the film industry, and this can be applied in a wide range of applications, from optical films to wearable devices. Here, we present an unprecedented spontaneous strategy for separating transparent polymer films from substrates on the basis of microbubble generation using nanocapsules containing an evaporable material. The core-shell nanocapsules are prepared from poly(methyl methacrylate)-polyethyleneimine nanoparticles via the encapsulation of methylcyclohexane (MCH). A spherical nanostructure with a vaporizable core is obtained, with the heat-triggered gas release ability leading to the formation of microbubbles. Our separation method applied to transparent polymer films doped with a small amount of the nanocapsules encapsulating evaporable MCH enables spontaneous detachment of thin films from substrates via vacuum-assisted rapid vaporization of MCH over a short separation time, and clear detachment of the film is achieved with no deterioration of the inherent optical transparency and adhesive property compared to a pristine film.

Impact Crater Morphology and the Structure of Europa's Ice Shell

NASA Astrophysics Data System (ADS)

Silber, Elizabeth A.; Johnson, Brandon C.

2017-12-01

We performed numerical simulations of impact crater formation on Europa to infer the thickness and structure of its ice shell. The simulations were performed using iSALE to test both the conductive ice shell over ocean and the conductive lid over warm convective ice scenarios for a variety of conditions. The modeled crater depth-diameter is strongly dependent on the thermal gradient and temperature of the warm convective ice. Our results indicate that both a fully conductive (thin) shell and a conductive-convective (thick) shell can reproduce the observed crater depth-diameter and morphologies. For the conductive ice shell over ocean, the best fit is an approximately 8 km thick conductive ice shell. Depending on the temperature (255-265 K) and therefore strength of warm convective ice, the thickness of the conductive ice lid is estimated at 5-7 km. If central features within the crater, such as pits and domes, form during crater collapse, our simulations are in better agreement with the fully conductive shell (thin shell). If central features form well after the impact, however, our simulations suggest that a conductive-convective shell (thick shell) is more likely. Although our study does not provide a firm conclusion regarding the thickness of Europa's ice shell, our work indicates that Valhalla class multiring basins on Europa may provide robust constraints on the thickness of Europa's ice shell.

3D image display of fetal ultrasonic images by thin shell

NASA Astrophysics Data System (ADS)

Wang, Shyh-Roei; Sun, Yung-Nien; Chang, Fong-Ming; Jiang, Ching-Fen

1999-05-01

Due to the properties of convenience and non-invasion, ultrasound has become an essential tool for diagnosis of fetal abnormality during women pregnancy in obstetrics. However, the 'noisy and blurry' nature of ultrasound data makes the rendering of the data a challenge in comparison with MRI and CT images. In spite of the speckle noise, the unwanted objects usually occlude the target to be observed. In this paper, we proposed a new system that can effectively depress the speckle noise, extract the target object, and clearly render the 3D fetal image in almost real-time from 3D ultrasound image data. The system is based on a deformable model that detects contours of the object according to the local image feature of ultrasound. Besides, in order to accelerate rendering speed, a thin shell is defined to separate the observed organ from unrelated structures depending on those detected contours. In this way, we can support quick 3D display of ultrasound, and the efficient visualization of 3D fetal ultrasound thus becomes possible.

Preparation and characterization of WO3 nanoparticles, WO3/TiO2 core/shell nanocomposites and PEDOT:PSS/WO3 composite thin films for photocatalytic and electrochromic applications

NASA Astrophysics Data System (ADS)

Boyadjiev, Stefan I.; Santos, Gustavo dos Lopes; Szżcs, Júlia; Szilágyi, Imre M.

2016-03-01

In this study, monoclinic WO3 nanoparticles were obtained by thermal decomposition of (NH4)xWO3 in air at 600 °C. On them by atomic layer deposition (ALD) TiO2 films were deposited, and thus core/shell WO3/TiO2 nanocomposites were prepared. We prepared composites of WO3 nanoparticles with conductive polymer as PEDOT:PSS, and deposited thin films of them on glass and ITO substrates by spin coating. The formation, morphology, composition and structure of the as-prepared pure and composite nanoparticles, as well thin films, were studied by TEM, SEM-EDX and XRD. The photocatalytic activity of both the WO3 and core/shell WO3/TiO2 nanoparticles was studied by decomposing methyl orange in aqueous solution under UV light irradiation. Cyclic voltammetry measurements were performed on the composite PEDOT:PSS/WO3 thin films, and the coloring and bleaching states were studied.

Stable organic thin-film transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia, Xiaojia; Fuentes-Hernandez, Canek; Wang, Cheng-Yin

Organic thin-film transistors (OTFTs) can be fabricated at moderate temperatures and through cost-effective solution-based processes on a wide range of low-cost flexible and deformable substrates. Although the charge mobility of state-of-the-art OTFTs is superior to that of amorphous silicon and approaches that of amorphous oxide thin-film transistors (TFTs), their operational stability generally remains inferior and a point of concern for their commercial deployment. We report on an exhaustive characterization of OTFTs with an ultrathin bilayer gate dielectric comprising the amorphous fluoropolymer CYTOP and an Al2O3:HfO2 nanolaminate. Threshold voltage shifts measured at room temperatureovertimeperiods upto5.9×105 s do not vary monotonically andmore » remain below 0.2 V in microcrystalline OTFTs (mc-OTFTs) with field-effect carrier mobility values up to 1.6 cm2 V-1 s-1. Modeling of these shifts as a function of time with a double stretched-exponential (DSE) function suggests that two compensating aging mechanisms are at play and responsible for this high stability. The measured threshold voltage shifts at temperatures up to 75°C represent at least a one-order-of-magnitude improvement in the operational stability over previous reports, bringing OTFT technologies to a performance level comparable to that reported in the scientific literature for other commercial TFTs technologies.« less

Stable organic thin-film transistors

DOE PAGES

Jia, Xiaojia; Fuentes-Hernandez, Canek; Wang, Cheng-Yin; ...

2018-01-12

Organic thin-film transistors (OTFTs) can be fabricated at moderate temperatures and through cost-effective solution-based processes on a wide range of low-cost flexible and deformable substrates. Although the charge mobility of state-of-the-art OTFTs is superior to that of amorphous silicon and approaches that of amorphous oxide thin-film transistors (TFTs), their operational stability generally remains inferior and a point of concern for their commercial deployment. We report on an exhaustive characterization of OTFTs with an ultrathin bilayer gate dielectric comprising the amorphous fluoropolymer CYTOP and an Al2O3:HfO2 nanolaminate. Threshold voltage shifts measured at room temperatureovertimeperiods upto5.9×105 s do not vary monotonically andmore » remain below 0.2 V in microcrystalline OTFTs (mc-OTFTs) with field-effect carrier mobility values up to 1.6 cm2 V-1 s-1. Modeling of these shifts as a function of time with a double stretched-exponential (DSE) function suggests that two compensating aging mechanisms are at play and responsible for this high stability. The measured threshold voltage shifts at temperatures up to 75°C represent at least a one-order-of-magnitude improvement in the operational stability over previous reports, bringing OTFT technologies to a performance level comparable to that reported in the scientific literature for other commercial TFTs technologies.« less

Stable organic thin-film transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia, Xiaojia; Fuentes-Hernandez, Canek; Wang, Cheng-Yin

2018-01-01

Organic thin-film transistors (OTFTs) can be fabricated at moderate temperatures and through cost-effective solution-based processes on a wide range of low-cost flexible and deformable substrates. Although the charge mobility of state-of-the-art OTFTs is superior to that of amorphous silicon and approaches that of amorphous oxide thin-film transistors (TFTs), their operational stability generally remains inferior and a point of concern for their commercial deployment. We report on an exhaustive characterization of OTFTs with an ultrathin bilayer gate dielectric comprising the amorphous fluoropolymer CYTOP and an Al2O3:HfO2 nanolaminate. Threshold voltage shifts measured at room temperatureovertimeperiods upto5.9×105 s do not vary monotonically andmore » remain below 0.2 V in microcrystalline OTFTs (mc-OTFTs) with field-effect carrier mobility values up to 1.6 cm2 V−1 s−1. Modeling of these shifts as a function of time with a double stretched-exponential (DSE) function suggests that two compensating aging mechanisms are at play and responsible for this high stability. The measured threshold voltage shifts at temperatures up to 75°C represent at least a one-order-of-magnitude improvement in the operational stability over previous reports, bringing OTFT technologies to a performance level comparable to that reported in the scientific literature for other commercial TFTs technologies.« less

Stable organic thin-film transistors

PubMed Central

Jia, Xiaojia; Fuentes-Hernandez, Canek; Wang, Cheng-Yin; Park, Youngrak; Kippelen, Bernard

2018-01-01

Organic thin-film transistors (OTFTs) can be fabricated at moderate temperatures and through cost-effective solution-based processes on a wide range of low-cost flexible and deformable substrates. Although the charge mobility of state-of-the-art OTFTs is superior to that of amorphous silicon and approaches that of amorphous oxide thin-film transistors (TFTs), their operational stability generally remains inferior and a point of concern for their commercial deployment. We report on an exhaustive characterization of OTFTs with an ultrathin bilayer gate dielectric comprising the amorphous fluoropolymer CYTOP and an Al2O3:HfO2 nanolaminate. Threshold voltage shifts measured at room temperature over time periods up to 5.9 × 105 s do not vary monotonically and remain below 0.2 V in microcrystalline OTFTs (μc-OTFTs) with field-effect carrier mobility values up to 1.6 cm2 V−1 s−1. Modeling of these shifts as a function of time with a double stretched-exponential (DSE) function suggests that two compensating aging mechanisms are at play and responsible for this high stability. The measured threshold voltage shifts at temperatures up to 75°C represent at least a one-order-of-magnitude improvement in the operational stability over previous reports, bringing OTFT technologies to a performance level comparable to that reported in the scientific literature for other commercial TFTs technologies. PMID:29340301

Formation of nano-laminated structures in a dry sliding wear-induced layer under different wear mechanisms of 20CrNi2Mo steel

NASA Astrophysics Data System (ADS)

Yin, Cun-hong; Liang, Yi-long; Jiang, Yun; Yang, Ming; Long, Shao-lei

2017-11-01

The microstructures of 20CrNi2Mo steel underneath the contact surface were examined after dry sliding. Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), Electron Backscattered Diffraction (EBSD) and an ultra-micro-hardness tester were used to characterize the worn surface and dry sliding wear-induced layer. Martensite laths were ultra-refined due to cumulative strains and a large strain gradient that occurred during cyclic loading in wear near the surface. The microstructure evolution in dominant abrasive wear differs from that in adhesive wear. In dominant abrasive wear, only bent martensite laths with high-density deformation dislocations were observed. In contrast, in dominant adhesive wear, gradient structures were formed along the depth from the wear surface. Cross-sectional TEM foils were prepared in a focused ion beam (FIB) to observe the gradient structures in a dry sliding wear-induced layer at depths of approximately 1-5 μm and 5-20 μm. The gradient structures contained nano-laminated structures with an average thickness of 30-50 nm and bent martensite laths. We found that the original martensite laths coordinated with the strain energy and provided origin boundaries for the formation of gradient structures. Geometrically necessary boundaries (GNBs) and isolated dislocation boundaries (IDBs) play important roles in forming the nano-laminated structures.

Reactive nanolaminate pulsed-laser ignition mechanism: Modeling and experimental evidence of diffusion limited reactions

DOE PAGES

Yarrington, C. D.; Abere, M. J.; Adams, D. P.; ...

2017-04-03

We irradiated Al/Pt nanolaminates with a bilayer thickness (tb, width of an Al/Pt pair-layer) of 164 nm with single laser pulses with durations of 10 ms and 0.5 ms at 189 W/cm 2 and 1189 W/cm 2, respectively. The time to ignition was measured for each pulse, and shorter ignition times were observed for the higher power/shorter pulse width. While the shorter pulse shows uniform brightness, videographic images of the irradiated area shortly after ignition show a non-uniform radial brightness for the longer pulse. A diffusion-limited single step reaction mechanism was implemented in a finite element package to model themore » progress from reactants to products at both pulse widths. Finally, the model captures well both the observed ignition delay and qualitative observations regarding the non-uniform radial temperature.« less

Curvature-driven morphing of non-Euclidean shells

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Jiang, Xin; Holmes, D. P.

2017-05-01

We investigate how thin structures change their shape in response to non-mechanical stimuli that can be interpreted as variations in the structure's natural curvature. Starting from the theory of non-Euclidean plates and shells, we derive an effective model that reduces a three-dimensional stimulus to the natural fundamental forms of the mid-surface of the structure, incorporating expansion, or growth, in the thickness. Then, we apply the model to a variety of thin bodies, from flat plates to spherical shells, obtaining excellent agreement between theory and numerics. We show how cylinders and cones can either bend more or unroll, and eventually snap and rotate. We also study the nearly isometric deformations of a spherical shell and describe how this shape change is ruled by the geometry of a spindle. As the derived results stem from a purely geometrical model, they are general and scalable.

Fabrication of slender elastic shells by the coating of curved surfaces

NASA Astrophysics Data System (ADS)

Lee, A.; Brun, P.-T.; Marthelot, J.; Balestra, G.; Gallaire, F.; Reis, P. M.

2016-04-01

Various manufacturing techniques exist to produce double-curvature shells, including injection, rotational and blow molding, as well as dip coating. However, these industrial processes are typically geared for mass production and are not directly applicable to laboratory research settings, where adaptable, inexpensive and predictable prototyping tools are desirable. Here, we study the rapid fabrication of hemispherical elastic shells by coating a curved surface with a polymer solution that yields a nearly uniform shell, upon polymerization of the resulting thin film. We experimentally characterize how the curing of the polymer affects its drainage dynamics and eventually selects the shell thickness. The coating process is then rationalized through a theoretical analysis that predicts the final thickness, in quantitative agreement with experiments and numerical simulations of the lubrication flow field. This robust fabrication framework should be invaluable for future studies on the mechanics of thin elastic shells and their intrinsic geometric nonlinearities.

Spatial Signal Characteristics of Shallow Paraboloidal Shell Structronic Systems

NASA Astrophysics Data System (ADS)

Yue, H. H.; Deng, Z. Q.; Tzou, H. S.

Based on the smart material and structronics technology, distributed sensor and control of shell structures have been rapidly developed for the last twenty years. This emerging technology has been utilized in aerospace, telecommunication, micro-electromechanical systems and other engineering applications. However, distributed monitoring technique and its resulting global spatially distributed sensing signals of thin flexible membrane shells are not clearly understood. In this paper, modeling of free thin paraboloidal shell with spatially distributed sensor, micro-sensing signal characteristics, and location of distributed piezoelectric sensor patches are investigated based on a new set of assumed mode shape functions. Parametric analysis indicates that the signal generation depends on modal membrane strains in the meridional and circumferential directions in which the latter is more significant than the former, when all bending strains vanish in membrane shells. This study provides a modeling and analysis technique for distributed sensors laminated on lightweight paraboloidal flexible structures and identifies critical components and regions that generate significant signals.

Better Finite-Element Analysis of Composite Shell Structures

NASA Technical Reports Server (NTRS)

Clarke, Gregory

2007-01-01

A computer program implements a finite-element-based method of predicting the deformations of thin aerospace structures made of isotropic materials or anisotropic fiber-reinforced composite materials. The technique and corresponding software are applicable to thin shell structures in general and are particularly useful for analysis of thin beamlike members having open cross-sections (e.g. I-beams and C-channels) in which significant warping can occur.

Non-Deterministic Dynamic Instability of Composite Shells

NASA Technical Reports Server (NTRS)

Chamis, Christos C.; Abumeri, Galib H.

2004-01-01

A computationally effective method is described to evaluate the non-deterministic dynamic instability (probabilistic dynamic buckling) of thin composite shells. The method is a judicious combination of available computer codes for finite element, composite mechanics, and probabilistic structural analysis. The solution method is incrementally updated Lagrangian. It is illustrated by applying it to thin composite cylindrical shell subjected to dynamic loads. Both deterministic and probabilistic buckling loads are evaluated to demonstrate the effectiveness of the method. A universal plot is obtained for the specific shell that can be used to approximate buckling loads for different load rates and different probability levels. Results from this plot show that the faster the rate, the higher the buckling load and the shorter the time. The lower the probability, the lower is the buckling load for a specific time. Probabilistic sensitivity results show that the ply thickness, the fiber volume ratio and the fiber longitudinal modulus, dynamic load and loading rate are the dominant uncertainties, in that order.

Static black hole and vacuum energy: thin shell and incompressible fluid

NASA Astrophysics Data System (ADS)

Ho, Pei-Ming; Matsuo, Yoshinori

2018-03-01

With the back reaction of the vacuum energy-momentum tensor consistently taken into account, we study static spherically symmetric black-hole-like solutions to the semi-classical Einstein equation. The vacuum energy is assumed to be given by that of 2-dimensional massless scalar fields, as a widely used model in the literature for black holes. The solutions have no horizon. Instead, there is a local minimum in the radius. We consider thin shells as well as incompressible fluid as the matter content of the black-hole-like geometry. The geometry has several interesting features due to the back reaction of vacuum energy. In particular, Buchdahl's inequality can be violated without divergence in pressure, even if the surface is below the Schwarzschild radius. At the same time, the surface of the star can not be far below the Schwarzschild radius for a density not much higher than the Planck scale, and the proper distance from its surface to the origin can be very short even for very large Schwarzschild radius. The results also imply that, contrary to the folklore, in principle the Boulware vacuum can be physical for black holes.

Laminated anisotropic reinforced plastic plates and shells

NASA Technical Reports Server (NTRS)

Korolev, V. I.

1981-01-01

Basic technical theories and engineering calculation equations for anisotropic plates and shells made of rigid reinforced plastics, mainly laminated fiberglass, are presented and discussed. Solutions are given for many problems of design of structural plates and shells, including curved sections and tanks, as well as two chapters on selection of the optimum materials, are given. Accounting for interlayer shearing and transverse separation, which are new engineering properties, are discussed. Application of the results obtained to thin three ply plates and shells wth a light elastic filler is presented and discussed.

SAPNEW: Parallel finite element code for thin shell structures on the Alliant FX/80

NASA Astrophysics Data System (ADS)

Kamat, Manohar P.; Watson, Brian C.

1992-02-01

The results of a research activity aimed at providing a finite element capability for analyzing turbo-machinery bladed-disk assemblies in a vector/parallel processing environment are summarized. Analysis of aircraft turbofan engines is very computationally intensive. The performance limit of modern day computers with a single processing unit was estimated at 3 billions of floating point operations per second (3 gigaflops). In view of this limit of a sequential unit, performance rates higher than 3 gigaflops can be achieved only through vectorization and/or parallelization as on Alliant FX/80. Accordingly, the efforts of this critically needed research were geared towards developing and evaluating parallel finite element methods for static and vibration analysis. A special purpose code, named with the acronym SAPNEW, performs static and eigen analysis of multi-degree-of-freedom blade models built-up from flat thin shell elements.

SAPNEW: Parallel finite element code for thin shell structures on the Alliant FX/80

NASA Technical Reports Server (NTRS)

Kamat, Manohar P.; Watson, Brian C.

1992-01-01

The results of a research activity aimed at providing a finite element capability for analyzing turbo-machinery bladed-disk assemblies in a vector/parallel processing environment are summarized. Analysis of aircraft turbofan engines is very computationally intensive. The performance limit of modern day computers with a single processing unit was estimated at 3 billions of floating point operations per second (3 gigaflops). In view of this limit of a sequential unit, performance rates higher than 3 gigaflops can be achieved only through vectorization and/or parallelization as on Alliant FX/80. Accordingly, the efforts of this critically needed research were geared towards developing and evaluating parallel finite element methods for static and vibration analysis. A special purpose code, named with the acronym SAPNEW, performs static and eigen analysis of multi-degree-of-freedom blade models built-up from flat thin shell elements.

Resistive wall instabilities and tearing mode dynamics in the EXTRAP T2R thin shell reversed-field pinch

NASA Astrophysics Data System (ADS)

Malmberg, J.-A.; Brunsell, P. R.

2002-01-01

Observations of resistive wall instabilities and tearing mode dynamics in the EXTRAP T2R thin shell (τw=6 ms) reversed field pinch are described. A nonresonant mode (m=1,n=-10) with the same handedness as the internal field grows nearly exponentially with an average growth time of about 2.6 ms (less than 1/2 of the shell time) consistent with linear stability theory. The externally nonresonant unstable modes (m=1,n>0), predicted by linear stability theory, are observed to have only low amplitudes (in the normal low-Θ operation mode of the device). The radial field of the dominant internally resonant tearing modes (m=1,n=-15 to n=-12) remain low due to spontaneous fast mode rotation, corresponding to angular phase velocities up to 280 krad/s. Phase aligned mode structures are observed to rotate toroidally with an average angular velocity of 40 krad/s, in the opposite direction of the plasma current. Toward the end of the discharge, the radial field of the internally resonant modes grows as the modes slow down and become wall-locked, in agreement with nonlinear computations. Fast rotation of the internally resonant modes has been observed only recently and is attributed to a change of the front-end system (vacuum vessel, shell, and TF coil) of the device.

Whispering gallery modes in a spherical microcavity with a photoluminescent shell

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grudinkin, S. A., E-mail: grudink@gvg.ioffe.ru; Dontsov, A. A.; Feoktistov, N. A.

2015-10-15

Whispering-gallery mode spectra in optical microcavities based on spherical silica particles coated with a thin photoluminescent shell of hydrogenated amorphous silicon carbide are studied. The spectral positions of the whispering-gallery modes for spherical microcavities with a shell are calculated. The dependence of the spectral distance between the TE and TM modes on the shell thickness is examined.

Numerical analysis of stiffened shells of revolution. Volume 2: Users' manual for STAR-02S - shell theory automated for rotational structures - 2 (statics), digital computer program

NASA Technical Reports Server (NTRS)

Svalbonas, V.

1973-01-01

A procedure for the structural analysis of stiffened shells of revolution is presented. A digital computer program based on the Love-Reissner first order shell theory was developed. The computer program can analyze orthotropic thin shells of revolution, subjected to unsymmetric distributed loading or concentrated line loads, as well as thermal strains. The geometrical shapes of the shells which may be analyzed are described. The shell wall cross section can be a sheet, sandwich, or reinforced sheet or sandwich. General stiffness input options are also available.

The problems concerning the integration of very thin mirror shells

NASA Astrophysics Data System (ADS)

Basso, S.; Citterio, O.; Mazzoleni, F.; Pareschi, G.; Tagliaferri, G.; Valtolina, R.; Conconi, P.; Parodi, G.

2009-08-01

The necessity to reduce the mass and to increase the collecting area requires that the thickness of the optics becomes more and more thinner. Simbol-X was a typical example of this trend. Such thickness makes the shells floppy and therefore unable to maintain the correct shape. During the integration of the shells into the mechanical structure, only negligible deformation must be introduced. The low thickness means also that the shells must be glued on both sides to reach a good stiffness of the whole mirror module and this fact introduces a set of mounting problems. In INAF - Osservatorio Astronomico di Brera an integration process has been developed. The use of stiffening rings and of a temporary structure is the key to maintain the right shape of the shell. In this article the results of the integration of the first three prototypes of the Simbol-X optics are presented. The description of the process and the analysis of the degradation of the performances during the integration are shown in detail.

Thin Shell evolution of NIF capsule with asymmetric drive and the resulting neutron diagnostics

NASA Astrophysics Data System (ADS)

Buchoff, Michael; Hammer, Jim

2015-11-01

One of the major impediments to achieving ignition via ICF is the non-spherical implosion arising from small asymmetries in the drive forcing the collapse of the capsule. Likewise, an experimental diagnostic for quantifying the characteristics of the implosion asymmetry is the final state neutrons, whose number and velocity distributions are not experimentally consistent with the expectation of a spherical implosion. In principle, connecting these initial and final state asymmetries could be solved via hydrodynamic simulations, but due to the multiple scales traversed throughout this process, these calculations are difficult and expensive, leaving much of the potential drive asymmetry profiles unexplored. In this work, we solve the resulting analytic equations from the thin-shell model proposed by Ott et. al. to evolve the capsule over a range of different drive asymmetries from its initial state (when the shell aspect ratio is much greater than 1) to a radius of roughly 250 microns, consisting of a layer of dense CH, a cold layer of dense DT, and a warm core of sparsely distributed DT. At this stage, more tractable hydrodynamical simulations are performed in the ARES code suite, determining the distribution of neutron from thermonuclear yield. These and future results allow for a multitude of tests of asymmetric sources to compare with and potentially guide experiment. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Deformation of compound shells under action of internal shock wave loading

NASA Astrophysics Data System (ADS)

Chernobryvko, Marina; Kruszka, Leopold; Avramov, Konstantin

2015-09-01

The compound shells under the action of internal shock wave loading are considered. The compound shell consists of a thin cylindrical shell and two thin parabolic shells at the edges. The boundary conditions in the shells joints satisfy the equality of displacements. The internal shock wave loading is modelled as the surplus pressure surface. This pressure is a function of the shell coordinates and time. The strain rate deformation of compound shell takes place in both the elastic and in plastic stages. In the elastic stage the equations of the structure motions are obtained by the assumed-modes method, which uses the kinetic and potential energies of the cylindrical and two parabolic shells. The dynamic behaviour of compound shells is treated. In local plastic zones the 3-D thermo-elastic-plastic model is used. The deformations are described by nonlinear model. The stress tensor elements are determined using dynamic deformation theory. The deformation properties of materials are influenced by the strain rate behaviour, the influence of temperature parameters, and the elastic-plastic properties of materials. The dynamic yield point of materials and Pisarenko-Lebedev's criterion of destruction are used. The modified adaptive finite differences method of numerical analysis is suggested for those simulations. The accuracy of the numerical simulation is verified on each temporal step of calculation and in the case of large deformation gradients.

Interacting shells in AdS spacetime and chaos

NASA Astrophysics Data System (ADS)

Brito, Richard; Cardoso, Vitor; Rocha, Jorge V.

2016-07-01

We study the simplest two-body problem in asymptotically anti-de Sitter spacetime: two, infinitely thin, concentric spherical shells of matter. We include only gravitational interaction between the two shells, but we show that the dynamics of this system is highly nontrivial. We observe prompt collapse to a black hole, delayed collapse and even perpetual oscillatory motion, depending on the initial location of the shells (or their energy content). The system exhibits critical behavior, and we show strong hints that it is also chaotic.

A versatile approach to the study of the transient response of a submerged thin shell

NASA Astrophysics Data System (ADS)

Leblond, C.; Sigrist, J.-F.

2010-01-01

The transient response of submerged two-dimensional thin shell subjected to weak acoustical or mechanical excitations is addressed in this paper. The proposed approach is first exposed in a detailed manner: it is based on Laplace transform in time, in vacuo eigenvector expansion with time-dependent coefficients for the structural dynamics and boundary-integral formulation for the fluid. The projection of the fluid pressure on the in vacuo eigenvectors leads to a fully coupled system involving the modal time-dependent displacement coefficients, which are the problem unknowns. They are simply determined by matrix inversion in the Laplace domain. Application of the method to the response of a two-dimensional immersed shell to a weak acoustical excitation is then exposed: the proposed test-case corresponds to the design of immersed structures subjected to underwater explosions, which is of paramount importance in naval shipbuilding. Comparison of a numerical calculation based on the proposed approach with an analytical solution is exposed; versatility of the method is also highlighted by referring to "classical" FEM/FEM or FEM/BEM simulations. As a conspicuous feature of the method, calculation of the fluid response functions corresponding to a given geometry has to be performed once, allowing various simulations for different material properties of the structure, as well as for various excitations on the structure. This versatile approach can therefore be efficiently and extensively used for design purposes.

The NASA Monographs on Shell Stability Design Recommendations: A Review and Suggested Improvements

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.; Starnes, James H., Jr.

1998-01-01

A summary of existing NASA design criteria monographs for the design of buckling-resistant thin-shell structures is presented. Subsequent improvements in the analysis for nonlinear shell response are reviewed, and current issues in shell stability analysis are discussed. Examples of nonlinear shell responses that are not included in the existing shell design monographs are presented, and an approach for including reliability based analysis procedures in the shell design process is discussed. Suggestions for conducting future shell experiments are presented, and proposed improvements to the NASA shell design criteria monographs are discussed.

The NASA Monographs on Shell Stability Design Recommendations: A Review and Suggested Improvements

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.; Starnes, James H., Jr.

1998-01-01

A summary of the existing NASA design criteria monographs for the design of buckling-resistant thin-shell structures is presented. Subsequent improvements in the analysis for nonlinear shell response are reviewed, and current issues in shell stability analysis are discussed. Examples of nonlinear shell responses that are not included in the existing shell design monographs are presented, and an approach for including reliability-based analysis procedures in the shell design process is discussed. Suggestions for conducting future shell experiments are presented, and proposed improvements to the NASA shell design criteria monographs are discussed.

New Tooling System for Forming Aluminum Beverage Can End Shell

NASA Astrophysics Data System (ADS)

Yamazaki, Koetsu; Otsuka, Takayasu; Han, Jing; Hasegawa, Takashi; Shirasawa, Taketo

2011-08-01

This paper proposes a new tooling system for forming shells of aluminum beverage can ends. At first, forming process of a conversional tooling system has been simulated using three-dimensional finite element models. Simulation results have been confirmed to be consistent with those of axisymmetric models, so simulations for further study have been performed using axisymmetric models to save computational time. A comparison shows that thinning of the shell formed by the proposed tooling system has been improved about 3.6%. Influences of the tool upmost surface profiles and tool initial positions in the new tooling system have been investigated and the design optimization method based on the numerical simulations has been then applied to search optimum design points, in order to minimize thinning subjected to the constraints of the geometrical dimensions of the shell. At last, the performance of the shell subjected to internal pressure has been confirmed to meet design requirements.

Enceladus Plume Activity Consistent with Eruptions from Sources within a Thin Shell

NASA Astrophysics Data System (ADS)

Hurford, Terry; Spitale, Joseph N.; Rhoden, Alyssa R.; Henning, Wade

2017-10-01

Enceladus is a small (radius 250 km) moon that orbits Saturn between the moons Mimas and Tethys with a period of 1.37 days. A 2:1 mean motion resonance with the moon Dione, which orbits just beyond Tethys, excites its orbital eccentricity to the observed value of 0.0047, which in turn produces periodic tidal stress on the surface.In 2005, Cassini detected the eruption of material from warm regions, which correlated with the large Tiger Stripe fractures near the south pole of Enceladus. A 2007 analysis of tidal stress postulated that the eruptive activity might be linked to tidal tension across these fractures and predicted that activity should vary on the orbital timescale such that greatest activity should be observed near apocenter (Hurford et al., 2007). In 2013, results from analysis of Cassini’s Visual and Infrared Map- ping Spectrometer (VIMS) data detected variability of the erupting material in the orbital cycle and qualitatively confirmed the predictions of variable activity from 2007 (Hedman et al., 2013; Hurford et al. 2007).Since then, work has been done to refine models for tidal control of plume activity. Nimmo et al. (2014) found that the plume activity could track the fraction of fractures under tension, but required a ~5 hr lag in Enceladus’ tidal response. This lag seemed plausible in a 24km ice shell. Behounkova et al. (2105) confirmed this result with a slightly improved model that linked tidal activity to normalize average tensile stress on the fracture.In this work, we illustrate how reservoir depth combines with a lag in tidal response to mimic larger delays in tidal activity. Taking into account the depth of the volatile reservoir, we find that the response of Enceladus to tidal deformation needs only be ~3 hrs and is more consistent with eruptions from a thin ice shell (≤10 km). This result is more consistent with recent revisions in ice shell thickness (Iess et al., 2014; Thomas et al., 2016).Hurford et al., 2007, Nature 447, 292

Core-shell silicon nanowire solar cells

PubMed Central

Adachi, M. M.; Anantram, M. P.; Karim, K. S.

2013-01-01

Silicon nanowires can enhance broadband optical absorption and reduce radial carrier collection distances in solar cell devices. Arrays of disordered nanowires grown by vapor-liquid-solid method are attractive because they can be grown on low-cost substrates such as glass, and are large area compatible. Here, we experimentally demonstrate that an array of disordered silicon nanowires surrounded by a thin transparent conductive oxide has both low diffuse and specular reflection with total values as low as < 4% over a broad wavelength range of 400 nm < λ < 650 nm. These anti-reflective properties together with enhanced infrared absorption in the core-shell nanowire facilitates enhancement in external quantum efficiency using two different active shell materials: amorphous silicon and nanocrystalline silicon. As a result, the core-shell nanowire device exhibits a short-circuit current enhancement of 15% with an amorphous Si shell and 26% with a nanocrystalline Si shell compared to their corresponding planar devices. PMID:23529071

Calculation of load distribution in stiffened cylindrical shells

NASA Technical Reports Server (NTRS)

Ebner, H; Koller, H

1938-01-01

Thin-walled shells with strong longitudinal and transverse stiffening (for example, stressed-skin fuselages and wings) may, under certain simplifying assumptions, be treated as static systems with finite redundancies. In this report the underlying basis for this method of treatment of the problem is presented and a computation procedure for stiffened cylindrical shells with curved sheet panels indicated. A detailed discussion of the force distribution due to applied concentrated forces is given, and the discussion illustrated by numerical examples which refer to an experimentally determined circular cylindrical shell.

Detection of λ-cyhalothrin by a core-shell spherical SiO2-based surface thin fluorescent molecularly imprinted polymer film.

PubMed

Gao, Lin; Han, Wenjuan; Li, Xiuying; Wang, Jixiang; Yan, Yongsheng; Li, Chunxiang; Dai, Jiangdong

2015-12-01

A fluorescent core-shell molecularly imprinted polymer based on the surface of SiO2 beads was synthesized and its application in the fluorescence detection of ultra-trace λ-cyhalothrin (LC) was investigated. The shell was prepared by copolymerization of acrylamide with allyl fluorescein in the presence of LC to form recognition sites. The experimental results showed that the thin fluorescent molecularly imprinted polymer (FMIP) film exhibited better selective recognition ability than fluorescent molecularly non-imprinted polymer (FNIP). A new nonlinear relationship between quenching rate and concentration was found in this work. In addition, the nonlinear relationship allowed a lower concentration range of 0-5.0 nM to be described by the Stern-Volmer equation with a correlation coefficient of 0.9929. The experiment results revealed that the SiO2@FMIP was satisfactory as a recognition element for determination of LC in soda water samples. Therefore this study demonstrated the potential of MIP for the recognition and detection of LC in food.

Effects of multiple resistive shells and transient electromagnetic torque on the dynamics of mode locking in reversed field pinch plasmas

NASA Astrophysics Data System (ADS)

Guo, S. C.; Chu, M. S.

2002-11-01

The effects of multiple resistive shells and transient electromagnetic torque on the dynamics of mode locking in the reversed field pinch (RFP) plasmas are studied. Most RFP machines are equipped with one or more metal shells outside of the vacuum vessel. These shells have finite resistivities. The eddy currents induced in each of the shells contribute to the braking electromagnetic (EM) torque which slows down the plasma rotation. In this work we study the electromagnetic torque acting on the plasma (tearing) modes produced by a system of resistive shells. These shells may consist of several nested thin shells or several thin shells enclosed within a thick shell. The dynamics of the plasma mode is investigated by balancing the EM torque from the resistive shells with the plasma viscous torque. Both the steady state theory and the time-dependent theory are developed. The steady state theory is shown to provide an accurate account of the resultant EM torque if (dω/dt)ω-2≪1 and the time scale of interest is much longer than the response (L/R) time of the shell. Otherwise, the transient theory should be adopted. As applications, the steady state theory is used to evaluate the changes of the EM torque response from the resistive shells in two variants of two RFP machines: (1) modification from Reversed Field Experiment (RFX) [Gnesotto et al., Fusion Eng. Des. 25, 335 (1995)] to the modified RFX: both of them are equipped with one thin shell plus one thick shell; (2) modification from Extrap T2 to Extrap T2R [Brunsell et al., Plasma Phys. Controlled Fusion 43, 1457 (2001)]: both of them are equipped with two thin shells. The transient theory has been applied numerically to study the time evolution of the EM torque during the unlocking of a locked tearing mode in the modified RFX.

Geometry induced phase transitions in magnetic spherical shell

NASA Astrophysics Data System (ADS)

Sloika, Mykola I.; Sheka, Denis D.; Kravchuk, Volodymyr P.; Pylypovskyi, Oleksandr V.; Gaididei, Yuri

2017-12-01

Equilibrium magnetization states in spherical shells of a magnetically soft ferromagnet form two out-of-surface vortices with codirectionally magnetized vortex cores at the sphere poles: (i) a whirligig state with the in-surface magnetization oriented along parallels is typical for thick shells; (ii) a three dimensional onion state with the in-surface meridional direction of the magnetization is realized in thin shells. The geometry of spherical shell prohibits an existence of spatially homogeneous magnetization distribution, even in the case of small sample radii. By varying geometrical parameters a continuous phase transition between the whirligig and onion states takes place. The detailed analytical description of the phase diagram is well confirmed by micromagnetic simulations.

Dynamics of magnetic shells and information loss problem

NASA Astrophysics Data System (ADS)

Lee, Bum-Hoon; Lee, Wonwoo; Yeom, Dong-han

2015-07-01

We investigate dynamics of magnetic thin-shells in three dimensional anti-de Sitter background. Because of the magnetic field, an oscillatory solution is possible. This oscillating shell can tunnel to a collapsing shell or a bouncing shell, where both tunnelings induce an event horizon and a singularity. In the entire path integral, via the oscillating solution, there is a nonzero probability to maintain a trivial causal structure without a singularity. Therefore, due to the path integral, the entire wave function can conserve information. Since an oscillating shell can tunnel after a number of oscillations, in the end, it will allow an infinite number of different branchings to classical histories. This system can be a good model of the effective loss of information, where information is conserved by a solution that is originated from gauge fields.

Micromagnetic study of equilibrium states in nano hemispheroidal shells

NASA Astrophysics Data System (ADS)

Schultz, Keren; Schultz, Moty

2017-11-01

We present results of micromagnetic simulations of thin ferromagnetic nano hemispheroidal shells with sizes ranging from 5 to 50 nm (inside dimensions). Depending on the geometrical and magnetic parameters of the hemispheroidal shell, there exist three different magnetic phases: easy axis, onion and vortex. The profile for the vortex magnetization distribution is analyzed and the limitations and applicability of different vortex ansatzes are discussed. In addition, we investigate the total energy density for each of the magnetic distributions as a function of the hemispheroidal shell dimensions.

Transparent and flexible capacitors based on nanolaminate Al2O3/TiO2/Al2O3.

PubMed

Zhang, Guozhen; Wu, Hao; Chen, Chao; Wang, Ti; Yue, Jin; Liu, Chang

2015-01-01

Transparent and flexible capacitors based on nanolaminate Al2O3/TiO2/Al2O3 dielectrics have been fabricated on indium tin oxide-coated polyethylene naphthalate substrates by atomic layer deposition. A capacitance density of 7.8 fF/μm(2) at 10 KHz was obtained, corresponding to a dielectric constant of 26.3. Moreover, a low leakage current density of 3.9 × 10(-8) A/cm(2) at 1 V has been realized. Bending test shows that the capacitors have better performances in concave conditions than in convex conditions. The capacitors exhibit an average optical transmittance of about 70% in visible range and thus open the door for applications in transparent and flexible integrated circuits.

Sound Transmission through Two Concentric Cylindrical Sandwich Shells

NASA Technical Reports Server (NTRS)

Tang, Yvette Y.; Silcox, Richard J.; Robinson, Jay H.

1996-01-01

This paper solves the problem of sound transmission through a system of two infinite concentric cylindrical sandwich shells. The shells are surrounded by external and internal fluid media and there is fluid (air) in the annular space between them. An oblique plane sound wave is incident upon the surface of the outer shell. A uniform flow is moving with a constant velocity in the external fluid medium. Classical thin shell theory is applied to the inner shell and first-order shear deformation theory is applied to the outer shell. A closed form for transmission loss is derived based on modal analysis. Investigations have been made for the impedance of both shells and the transmission loss through the shells from the exterior into the interior. Results are compared for double sandwich shells and single sandwich shells. This study shows that: (1) the impedance of the inner shell is much smaller than that of the outer shell so that the transmission loss is almost the same in both the annular space and the interior cavity of the shells; (2) the two concentric sandwich shells can produce an appreciable increase of transmission loss over single sandwich shells especially in the high frequency range; and (3) design guidelines may be derived with respect to the noise reduction requirement and the pressure in the annular space at a mid-frequency range.

The initiation and persistence of cracks in Enceladus' ice shell

NASA Astrophysics Data System (ADS)

Rudolph, M. L.; Jordan, J.; Manga, M.; Hawkins, E. K.; Grannan, A. M.; Reinhard, A.; Farough, A.; Mittal, T.; Hernandez, J. A.

2016-12-01

The eruption of water from a global ocean underlying Enceladus' ice shell requires; i. a mechanism to create stresses sufficient to produce cracks that reach the ocean, ii. that the ascent of water through the crack must be fast enough to keep the crack from freezing. We develop models for the evolution of stresses in the ice shell and overpressure in the ocean, the propagation of cracks into the ice shell, and the melting of ice caused by the eruption of water through the cracks. We show that modest cooling of Enceladus' interior can produce extensional stresses in the ice shell sufficient to overcome the tensile strength of ice. We show that the resultant ice shell cracks can penetrate to depths greater than 10 km. Cracks of 10 km are required to reach the interior oceans of Enceladus in the polar regions. After crack formation, we show that the present eruption rate is sufficient to keep cracks from freezing below the water-table, at which water boils and subsequently erupts. The ascent of warm water from Enceladus' ocean widens the cracks and thins the ice shell in the South Polar Terrain (SPT). Model predictions show that a crack with the minimum, sufficient heat flow to persist without freezing, would thin the surrounding ice shell by about a factor of two. This calculation for heat flow is consistent with observed heat fluxes at the surface and recent inferences of the ice shell thickness in the SPT based on the shape and gravity of Enceladus.

A comparison of experimental and calculated thin-shell leading-edge buckling due to thermal stresses

NASA Technical Reports Server (NTRS)

Jenkins, Jerald M.

1988-01-01

High-temperature thin-shell leading-edge buckling test data are analyzed using NASA structural analysis (NASTRAN) as a finite element tool for predicting thermal buckling characteristics. Buckling points are predicted for several combinations of edge boundary conditions. The problem of relating the appropriate plate area to the edge stress distribution and the stress gradient is addressed in terms of analysis assumptions. Local plasticity was found to occur on the specimen analyzed, and this tended to simplify the basic problem since it effectively equalized the stress gradient from loaded edge to loaded edge. The initial loading was found to be difficult to select for the buckling analysis because of the transient nature of thermal stress. Multiple initial model loadings are likely required for complicated thermal stress time histories before a pertinent finite element buckling analysis can be achieved. The basic mode shapes determined from experimentation were correctly identified from computation.

NASA Tech Briefs, May 2003

NASA Technical Reports Server (NTRS)

2003-01-01

Topics covered include: Using Diffusion Bonding in Making Piezoelectric Actuators; Wireless Temperature-Monitoring System; Analog Binaural Circuits for Detecting and Locating Leaks; Mirrors Containing Biomimetic Shape-Control Actuators; Surface-Micromachined Planar Arrays of Thermopiles; Cascade Back-Propagation Learning in Neural Networks; Perovskite Superlattices as Tunable Microwave Devices; Rollable Thin-Shell Nanolaminate Mirrors; Flight Tests of a Ministick Controller in an F/A-18 Airplane; Piezoelectrically Actuated Shutter for High Vacuum; Bio-Inspired Engineering of Exploration Systems; Microscope Cells Containing Multiple Micromachined Wells; Electrophoretic Deposition for Fabricating Microbatteries; Integrated Arrays of Ion-Sensitive Electrodes; Model of Fluidized Bed Containing Reacting Solids and Gases; Membrane Mirrors With Bimorph Shape Actuators; Using Fractional Clock-Period Delays in Telemetry Arraying; Developing Generic Software for Spacecraft Avionics; Numerical Study of Pyrolysis of Biomass in Fluidized Beds; and Assessment of Models of Chemically Reacting Granular Flows.

Anisotropy, size, and aspect ratio effects on micropillar compression of Al-SiC nanolaminate composites

DOE PAGES

Mayer, C. R.; Yang, L. W.; Singh, S. S.; ...

2016-05-20

Metal-ceramic nanolaminate composites show promise as high strength and toughness materials. Micropillar compression was used to characterize the mechanical behavior of AlSiC multilayers in different orientations including loading at 0°, 45° and 90° with respect to the direction of the layers. The 0° orientation showed the highest strength while the 45° orientation showed the lowest strength. Each orientation showed unique deformation behavior. Effects of pillar size and aspect ratio were also studied. Higher compressive strengths were observed in smaller pillars for all orientations. This effect was shown to be due to a lower probability of flaws using Weibull statistics. Additionally,more » changes in the aspect ratio was shown to have no significant effect on the behavior except an increase in the strain to failure in the 0° orientation. In conclusion, finite element analysis (FEA) was used to simulate and understand the effect of these parameters on the deformation behavior.« less

Folding of non-Euclidean curved shells

NASA Astrophysics Data System (ADS)

Bende, Nakul; Evans, Arthur; Innes-Gold, Sarah; Marin, Luis; Cohen, Itai; Santangelo, Christian; Hayward, Ryan

2015-03-01

Origami-based folding of 2D sheets has been of recent interest for a variety of applications ranging from deployable structures to self-folding robots. Though folding of planar sheets follows well-established principles, folding of curved shells involves an added level of complexity due to the inherent influence of curvature on mechanics. In this study, we use principles from differential geometry and thin shell mechanics to establish fundamental rules that govern folding of prototypical creased shells. In particular, we show how the normal curvature of a crease line controls whether the deformation is smooth or discontinuous, and investigate the influence of shell thickness and boundary conditions. We show that snap-folding of shells provides a route to rapid actuation on time-scales dictated by the speed of sound. The simple geometric design principles developed can be applied at any length-scale, offering potential for bio-inspired soft actuators for tunable optics, microfluidics, and robotics. This work was funded by the National Science Foundation through EFRI ODISSEI-1240441 with additional support to S.I.-G. through the UMass MRSEC DMR-0820506 REU program.

Self-assembly of core-shell structure PtO2@Pt nanodots and their formation evolution

NASA Astrophysics Data System (ADS)

Yang, Weijia; Liu, Junjie; Liu, Mingquan; Zhao, Zhicheng; Song, Yapeng; Tang, Xiufeng; Luo, Jianyi; Zeng, Qingguang; He, Xin

2018-05-01

Core-shell structure PtO2@Pt nanodots have been self-assembly by vacuum sputtering and high temperature annealing. First, Pt thin films with a small amount of PtO2 are grown on the sapphire substrates by vacuum sputtering. And then high temperature annealing on the thin films is carried out at 800 °C for 2 min to form Pt nanodots. During the cooling process, the atmosphere is deployed to supplant the nitrogen. Finally, even distributed core-shell structure PtO2@Pt nanodots with a diameter from 100 to 300 nm are achieved. Furthermore, the formation evolution of core-shell structure PtO2@Pt nanodots is also proposed. This work open up a new approach for fabricating core-shell structure nanodots.

Small bending and stretching of sandwich-type shells

NASA Technical Reports Server (NTRS)

Reissner, Eric

1950-01-01

A theory has been developed for small bending and stretching of sandwich-type shells. This theory is an extension of the known theory of homogeneous thin elastic shells. It was found that two effects are important in the present problem, which are not normally of importance in the theory of curved shells: (1) the effect of transverse shear deformation and (2) the effect of transverse normal stress deformation. The first of these two effects has been known to be of importance in the theory of plates and beams. The second effect was found to occur in a manner which is typical for shells and has no counterpart in flat-plate theory. The general results of this report have been applied to the solution of problems concerning flat plates, circular rings, circular cylindrical shells, and spherical shells. In each case numerical examples have been given, illustrating the magnitude of the effects of transverse shear and normal stress deformation.

A Leonard-Sanders-Budiansky-Koiter-Type Nonlinear Shell Theory with a Hierarchy of Transverse-Shearing Deformations

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.

2013-01-01

A detailed exposition on a refined nonlinear shell theory suitable for nonlinear buckling analyses of laminated-composite shell structures is presented. This shell theory includes the classical nonlinear shell theory attributed to Leonard, Sanders, Koiter, and Budiansky as an explicit proper subset. This approach is used in order to leverage the exisiting experience base and to make the theory attractive to industry. In addition, the formalism of general tensors is avoided in order to expose the details needed to fully understand and use the theory. The shell theory is based on "small" strains and "moderate" rotations, and no shell-thinness approximations are used. As a result, the strain-displacement relations are exact within the presumptions of "small" strains and "moderate" rotations. The effects of transverse-shearing deformations are included in the theory by using analyst-defined functions to describe the through-the-thickness distributions of transverse-shearing strains. Constitutive equations for laminated-composite shells are derived without using any shell-thinness approximations, and simplified forms and special cases are presented.

Preparation and characterization of WO{sub 3} nanoparticles, WO{sub 3}/TiO{sub 2} core/shell nanocomposites and PEDOT:PSS/WO{sub 3} composite thin films for photocatalytic and electrochromic applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boyadjiev, Stefan I., E-mail: boiajiev@gmail.com; Santos, Gustavo dos Lopes; Szűcs, Júlia

2016-03-25

In this study, monoclinic WO{sub 3} nanoparticles were obtained by thermal decomposition of (NH{sub 4}){sub x}WO{sub 3} in air at 600 °C. On them by atomic layer deposition (ALD) TiO{sub 2} films were deposited, and thus core/shell WO{sub 3}/TiO{sub 2} nanocomposites were prepared. We prepared composites of WO{sub 3} nanoparticles with conductive polymer as PEDOT:PSS, and deposited thin films of them on glass and ITO substrates by spin coating. The formation, morphology, composition and structure of the as-prepared pure and composite nanoparticles, as well thin films, were studied by TEM, SEM-EDX and XRD. The photocatalytic activity of both the WO{submore » 3} and core/shell WO{sub 3}/TiO{sub 2} nanoparticles was studied by decomposing methyl orange in aqueous solution under UV light irradiation. Cyclic voltammetry measurements were performed on the composite PEDOT:PSS/WO{sub 3} thin films, and the coloring and bleaching states were studied.« less

An immersed-shell method for modelling fluid–structure interactions

PubMed Central

Viré, A.; Xiang, J.; Pain, C. C.

2015-01-01

The paper presents a novel method for numerically modelling fluid–structure interactions. The method consists of solving the fluid-dynamics equations on an extended domain, where the computational mesh covers both fluid and solid structures. The fluid and solid velocities are relaxed to one another through a penalty force. The latter acts on a thin shell surrounding the solid structures. Additionally, the shell is represented on the extended domain by a non-zero shell-concentration field, which is obtained by conservatively mapping the shell mesh onto the extended mesh. The paper outlines the theory underpinning this novel method, referred to as the immersed-shell approach. It also shows how the coupling between a fluid- and a structural-dynamics solver is achieved. At this stage, results are shown for cases of fundamental interest. PMID:25583857

MHD Waves in Coronal Loops with a Shell

NASA Astrophysics Data System (ADS)

Mikhalyaev, B. B.; Solov'ev, A. A.

2004-04-01

We consider a model of a coronal loop in the form of a cord surrounded by a coaxial shell. Two slow magnetosonic waves longitudinally propagate within a thin flux tube on the m = 0 cylindrical mode with velocities close to the tube velocities in the cord and the shell. One wave propagates inside the cord, while the other propagates inside the shell. A peculiar feature of the second wave is that the plasma in the cord and the shell oscillates with opposite phases. There are two fast magnetosonic waves on each of the cylindrical modes with m > 0. If the plasma density in the shell is lower than that in the surrounding corona, then one of the waves is radiated into the corona, which causes the loop oscillations to be damped, while the other wave is trapped by the cord, but can also be radiated out under certain conditions. If the plasma density in the shell is higher than that in the cord, then one of the waves is trapped by the shell, while the other wave can also be trapped by the shell under certain conditions. In the wave trapped by the shell and the wave radiated by the tube, the plasma in the cord and the shell oscillates with opposite phases.

Nonlinear Finite Element Analysis of Shells with Large Aspect Ratio

NASA Technical Reports Server (NTRS)

Chang, T. Y.; Sawamiphakdi, K.

1984-01-01

A higher order degenerated shell element with nine nodes was selected for large deformation and post-buckling analysis of thick or thin shells. Elastic-plastic material properties are also included. The post-buckling analysis algorithm is given. Using a square plate, it was demonstrated that the none-node element does not have shear locking effect even if its aspect ratio was increased to the order 10 to the 8th power. Two sample problems are given to illustrate the analysis capability of the shell element.

Elastic stability of cylindrical shells with soft elastic cores: Biomimicking natural tubular structures

NASA Astrophysics Data System (ADS)

Karam, Gebran Nizar

1994-01-01

Thin walled cylindrical shell structures are widespread in nature: examples include plant stems, porcupine quills, and hedgehog spines. All have an outer shell of almost fully dense material supported by a low density, cellular core. In nature, all are loaded in combination of axial compression and bending: failure is typically by buckling. Natural structures are often optimized. Here we have analyzed the elastic buckling of a thin cylindrical shell supported by an elastic core to show that this structural configuration achieves significant weight saving over a hollow cylinder. The results of the analysis are compared with data from an extensive experimental program on uniaxial compression and four point bending tests on silicone rubber shells with and without compliant foam cores. The analysis describes the results of the mechanical tests well. Characterization of the microstructures of several natural tubular structures with foamlike cores (plant stems, quills, and spines) revealed them to be close to the optimal configurations predicted by the analytical model. Biomimicking of natural cylindrical shell structures and evolutionary design processes may offer the potential to increase the mechanical efficiency of engineering cylindrical shells.

Dynamic Stiffness Modeling of Composite Plate and Shell Assemblies

DTIC Science & Technology

2013-12-09

FA8655-10-1-3084 Report 6 Dynamic Stiffness Modelling of Plate and Shell Assemblies 4 Introduction Aerospace structures are generally made up of thin ...Sound and Vibration, 294(1- 2):131–161, 2006. [23] Y. F. Xing and B. Liu. New exact solutions for free vibrations of thin orthotropic rectangular plates ...Structures, 89(5–6):467–475, 2011. [80] A.Y.T. Leung. Dynamic stiffness analysis of laminated composite plates . Thin - Walled Structures, 25:109–133, 1996

Effects of zonal flows on correlation between energy balance and energy conservation associated with nonlinear nonviscous atmospheric dynamics in a thin rotating spherical shell

NASA Astrophysics Data System (ADS)

Ibragimov, Ranis N.

2018-03-01

The nonlinear Euler equations are used to model two-dimensional atmosphere dynamics in a thin rotating spherical shell. The energy balance is deduced on the basis of two classes of functorially independent invariant solutions associated with the model. It it shown that the energy balance is exactly the conservation law for one class of the solutions whereas the second class of invariant solutions provides and asymptotic convergence of the energy balance to the conservation law.

Transient Temperature Analysis in a System of Thin Shells Combined with Convective and Radiative Cooling

NASA Astrophysics Data System (ADS)

Prasad, Ravindra; Samria, N. K.

1989-01-01

The problem considered has applications in the transient thermal analysis and time for attaining the steady state of the cylinder wall and cylinder head of an air-cooled internal-combustion engine. Numerical calculations based on finite difference approximations are carried out to assess the thermal response in a system of thin cylindrical and spherical shells having hot gases inside with convective boundary conditions. The outside surface is exposed to cooling medium where it looses heat by natural convection and radiation. As a special case, when radius is large, the surface may be considered to be a plane wall. The cylinder cover and cylinder wall of an internal-combustion engine are considered to be a plane wall for a comparatively higher ratio of cylinder diameter to the thickness of the wall, i.e., whend/δ varies from 80 to 100. A plot of temperature-time history and heat flow rates have been obtained.

SAPNEW: Parallel finite element code for thin shell structures on the Alliant FX-80

NASA Astrophysics Data System (ADS)

Kamat, Manohar P.; Watson, Brian C.

1992-11-01

The finite element method has proven to be an invaluable tool for analysis and design of complex, high performance systems, such as bladed-disk assemblies in aircraft turbofan engines. However, as the problem size increase, the computation time required by conventional computers can be prohibitively high. Parallel processing computers provide the means to overcome these computation time limits. This report summarizes the results of a research activity aimed at providing a finite element capability for analyzing turbomachinery bladed-disk assemblies in a vector/parallel processing environment. A special purpose code, named with the acronym SAPNEW, has been developed to perform static and eigen analysis of multi-degree-of-freedom blade models built-up from flat thin shell elements. SAPNEW provides a stand alone capability for static and eigen analysis on the Alliant FX/80, a parallel processing computer. A preprocessor, named with the acronym NTOS, has been developed to accept NASTRAN input decks and convert them to the SAPNEW format to make SAPNEW more readily used by researchers at NASA Lewis Research Center.

Multilayer active shell mirrors for space telescopes

NASA Astrophysics Data System (ADS)

Steeves, John; Jackson, Kathryn; Pellegrino, Sergio; Redding, David; Wallace, J. Kent; Bradford, Samuel Case; Barbee, Troy

2016-07-01

A novel active mirror technology based on carbon fiber reinforced polymer (CFRP) substrates and replication techniques has been developed. Multiple additional layers are implemented into the design serving various functions. Nanolaminate metal films are used to provide a high quality reflective front surface. A backing layer of thin active material is implemented to provide the surface-parallel actuation scheme. Printed electronics are used to create a custom electrode pattern and flexible routing layer. Mirrors of this design are thin (< 1.0 mm), lightweight (2.7 kg/m2), and have large actuation capabilities. These capabilities, along with the associated manufacturing processes, represent a significant change in design compared to traditional optics. Such mirrors could be used as lightweight primaries for small CubeSat-based telescopes or as meter-class segments for future large aperture observatories. Multiple mirrors can be produced under identical conditions enabling a substantial reduction in manufacturing cost and complexity. An overview of the mirror design and manufacturing processes is presented. Predictions on the actuation performance have been made through finite element simulations demonstrating correctabilities on the order of 250-300× for astigmatic modes with only 41 independent actuators. A description of the custom metrology system used to characterize the active mirrors is also presented. The system is based on a Reverse Hartmann test and can accommodate extremely large deviations in mirror figure (> 100 μm PV) down to sub-micron precision. The system has been validated against several traditional techniques including photogrammetry and interferometry. The mirror performance has been characterized using this system, as well as closed-loop figure correction experiments on 150 mm dia. prototypes. The mirrors have demonstrated post-correction figure accuracies of 200 nm RMS (two dead actuators limiting performance).

Historical baselines and the future of shell calcification for a foundation species in a changing ocean

PubMed Central

Pfister, Catherine A.; Roy, Kaustuv; Wootton, J. Timothy; McCoy, Sophie J.; Paine, Robert T.; Suchanek, Thomas H.; Sanford, Eric

2016-01-01

Seawater pH and the availability of carbonate ions are decreasing due to anthropogenic carbon dioxide emissions, posing challenges for calcifying marine species. Marine mussels are of particular concern given their role as foundation species worldwide. Here, we document shell growth and calcification patterns in Mytilus californianus, the California mussel, over millennial and decadal scales. By comparing shell thickness across the largest modern shells, the largest mussels collected in the 1960s–1970s and shells from two Native American midden sites (∼1000–2420 years BP), we found that modern shells are thinner overall, thinner per age category and thinner per unit length. Thus, the largest individuals of this species are calcifying less now than in the past. Comparisons of shell thickness in smaller individuals over the past 10–40 years, however, do not show significant shell thinning. Given our sampling strategy, these results are unlikely to simply reflect within-site variability or preservation effects. Review of environmental and biotic drivers known to affect shell calcification suggests declining ocean pH as a likely explanation for the observed shell thinning. Further future decreases in shell thickness could have significant negative impacts on M. californianus survival and, in turn, negatively impact the species-rich complex that occupies mussel beds. PMID:27306049

Historical baselines and the future of shell calcification for a foundation species in a changing ocean

USGS Publications Warehouse

Pfister, Catherine A.; Roy, Kaustuv; Wootton, Timothy J.; McCoy, Sophie J.; Paine, Robert T.; Suchanek, Tom; Sanford, Eric

2016-01-01

Seawater pH and the availability of carbonate ions are decreasing due to anthropogenic carbon dioxide emissions, posing challenges for calcifying marine species. Marine mussels are of particular concern given their role as foundation species worldwide. Here, we document shell growth and calcification patterns in Mytilus californianus, the California mussel, over millennial and decadal scales. By comparing shell thickness across the largest modern shells, the largest mussels collected in the 1960s–1970s and shells from two Native American midden sites (∼1000–2420 years BP), we found that modern shells are thinner overall, thinner per age category and thinner per unit length. Thus, the largest individuals of this species are calcifying less now than in the past. Comparisons of shell thickness in smaller individuals over the past 10–40 years, however, do not show significant shell thinning. Given our sampling strategy, these results are unlikely to simply reflect within-site variability or preservation effects. Review of environmental and biotic drivers known to affect shell calcification suggests declining ocean pH as a likely explanation for the observed shell thinning. Further future decreases in shell thickness could have significant negative impacts on M. californianus survival and, in turn, negatively impact the species-rich complex that occupies mussel beds..

Historical baselines and the future of shell calcification for a foundation species in a changing ocean.

PubMed

Pfister, Catherine A; Roy, Kaustuv; Wootton, J Timothy; McCoy, Sophie J; Paine, Robert T; Suchanek, Thomas H; Sanford, Eric

2016-06-15

Seawater pH and the availability of carbonate ions are decreasing due to anthropogenic carbon dioxide emissions, posing challenges for calcifying marine species. Marine mussels are of particular concern given their role as foundation species worldwide. Here, we document shell growth and calcification patterns in Mytilus californianus, the California mussel, over millennial and decadal scales. By comparing shell thickness across the largest modern shells, the largest mussels collected in the 1960s-1970s and shells from two Native American midden sites (∼1000-2420 years BP), we found that modern shells are thinner overall, thinner per age category and thinner per unit length. Thus, the largest individuals of this species are calcifying less now than in the past. Comparisons of shell thickness in smaller individuals over the past 10-40 years, however, do not show significant shell thinning. Given our sampling strategy, these results are unlikely to simply reflect within-site variability or preservation effects. Review of environmental and biotic drivers known to affect shell calcification suggests declining ocean pH as a likely explanation for the observed shell thinning. Further future decreases in shell thickness could have significant negative impacts on M. californianus survival and, in turn, negatively impact the species-rich complex that occupies mussel beds. © 2016 The Author(s).

Thick or Thin Ice Shell on Europa? Artist Concept

NASA Image and Video Library

2007-12-13

Scientists are all but certain that Europa has an ocean underneath its icy surface, but they do not know how thick this ice might be. This artist concept illustrates two possible cut-away views through Europa ice shell.

Future Directions and Challenges in Shell Stability Analysis

NASA Technical Reports Server (NTRS)

Arbocz, Johann

1998-01-01

An answer is sought to the question of today, in 1997, after so many years of concentrated research effort in designing buckling critical thin walled shells, why one cannot do any better than using the rather conservative Lower Bound Design Philosophy of the sixties. It will be shown that with the establishment of Initial Imperfection Data Banks and the introduction of Probabilistic Design Procedures one has a viable alternative, that when used judiciously, may lead to improved shell design recommendations.

Capsules made from prefabricated thin films

NASA Astrophysics Data System (ADS)

Amstad, Esther

2018-02-01

Capsules are composed of a core, typically a liquid containing active substances, and a surrounding shell. They are used to delay the degradation of active ingredients, protect them from reacting or interacting with substances contained in the surrounding shell, or to prevent premature consumption of encapsulants (1, 2). The performance of capsules is often determined by their permeability toward encapsulants and stability against rupture; these parameters can be adjusted with the composition, structure, and thickness of the shell (3, 4). Mechanically robust capsules with a minimal permeability even toward low molecular weight substances often have rather thick shells (5). On page 775 of this issue, Kumar et al. (6) report an elegant process to fabricate capsules with very thin, rigid shells that display a low permeability even toward small encapsulants.

DNA nanoparticles with core-shell morphology.

PubMed

Chandran, Preethi L; Dimitriadis, Emilios K; Lisziewicz, Julianna; Speransky, Vlad; Horkay, Ferenc

2014-10-14

Mannobiose-modified polyethylenimines (PEI) are used in gene therapy to generate nanoparticles of DNA that can be targeted to the antigen-presenting cells of the immune system. We report that the sugar modification alters the DNA organization within the nanoparticles from homogenous to shell-like packing. The depth-dependent packing of DNA within the nanoparticles was probed using AFM nano-indentation. Unmodified PEI-DNA nanoparticles display linear elastic properties and depth-independent mechanics, characteristic of homogenous materials. Mannobiose-modified nanoparticles, however, showed distinct force regimes that were dependent on indentation depth, with 'buckling'-like response that is reproducible and not due to particle failure. By comparison with theoretical studies of spherical shell mechanics, the structure of mannobiosylated particles was deduced to be a thin shell with wall thickness in the order of few nanometers, and a fluid-filled core. The shell-core structure is also consistent with observations of nanoparticle denting in altered solution conditions, with measurements of nanoparticle water content from AFM images, and with images of DNA distribution in Transmission Electron Microscopy.

Validation of annual growth rings in freshwater mussel shells using cross dating .Can

Treesearch

Andrew L. Rypel; Wendell R. Haag; Robert H. Findlay

2009-01-01

We examined the usefulness of dendrochronological cross-dating methods for studying long-term, interannual growth patterns in freshwater mussels, including validation of annual shell ring formation. Using 13 species from three rivers, we measured increment widths between putative annual rings on shell thin sections and then removed age-related variation by...

Thickness Constraints on the Icy Shells of the Galilean Satellites from a Comparison of Crater Shapes

NASA Technical Reports Server (NTRS)

Schenk, Paul M.

2002-01-01

A thin outer ice shell on Jupiter's large moon Europa would imply easy exchange between the surface and any organic or biotic material in its putative subsurface ocean. The thickness of the outer ice shell is poorly constrained, however, with model-dependent estimates ranging from a few kilometers of depths of impact craters on Europa, Ganymede and Callisto that reveal two anomalous transitions in crater shape with diameter. The first transition is probably related to temperature-dependent ductility of the crust at shallow depths (7-8 km on Europa). The second transition is attributed to the influence of subsurface oceans on all three satellites, which constrains Europa's icy shell to be at least 19 km thick. The icy lithospheres of Ganymede and Callisto are equally ice-rich, but Europa's icy shell has a thermal structure about 0.25-0.5 times the thickness of Ganymede's or Callisto's shells, depending on epoch. The appearances of the craters on Europa are inconsistent with thin-ice-shell models and indicate that exchange of oceanic and surface material could be difficult.

Shell thinning and reproductive impairment in black ducks after cessation of DDE dosage

USGS Publications Warehouse

Longcore, J.R.; Stendell, R.C.

1977-01-01

Captive black ducks (anas rubripes) were fed dietary DDE [1,1-dichloro-2,2-bis (p-chlorophenyl)ethylene] at 10 ppm (dry weight; about 2 ppm on a natural diet basis) for 2 breeding seasons, then untreated feed for 2 succeeding years. Residues of DDE in the carcasses of adults declined 90% during the 2-year clean-up period. Following 2 years of dietary DDE, mean residues in eggs reached 64.9 ppm. Even after 2 years on clean feed, DDE residues in the eggs averaged 6.2 ppm or 9.5% of the mean DDE level reached after 2 years on treated feed. Shells of eggs from treated hens were about 20% thinner than shells of eggs from controls. Stoppage of DDE dosage resulted in progressively thicker shells, yet even after 2 years on untreated feed hens laid eggs with shells about 10% thinner than control hens. After DDE was removed from the diet, DDE residues in the eggs decreased, shell thickness increased, and reproductive success improved. Hens previously exposed to DDE, but then fed clean feed for 2 years, still produced significantly fewer surviving ducklings than did control hens.

Modeling complicated rheological behaviors in encapsulating shells of lipid-coated microbubbles accounting for nonlinear changes of both shell viscosity and elasticity.

PubMed

Li, Qian; Matula, Thomas J; Tu, Juan; Guo, Xiasheng; Zhang, Dong

2013-02-21

It has been accepted that the dynamic responses of ultrasound contrast agent (UCA) microbubbles will be significantly affected by the encapsulating shell properties (e.g., shell elasticity and viscosity). In this work, a new model is proposed to describe the complicated rheological behaviors in an encapsulating shell of UCA microbubbles by applying the nonlinear 'Cross law' to the shell viscous term in the Marmottant model. The proposed new model was verified by fitting the dynamic responses of UCAs measured with either a high-speed optical imaging system or a light scattering system. The comparison results between the measured radius-time curves and the numerical simulations demonstrate that the 'compression-only' behavior of UCAs can be successfully simulated with the new model. Then, the shell elastic and viscous coefficients of SonoVue microbubbles were evaluated based on the new model simulations, and compared to the results obtained from some existing UCA models. The results confirm the capability of the current model for reducing the dependence of bubble shell parameters on the initial bubble radius, which indicates that the current model might be more comprehensive to describe the complex rheological nature (e.g., 'shear-thinning' and 'strain-softening') in encapsulating shells of UCA microbubbles by taking into account the nonlinear changes of both shell elasticity and shell viscosity.

Enhanced linear photonic nanojet generated by core-shell optical microfibers

NASA Astrophysics Data System (ADS)

Liu, Cheng-Yang; Yen, Tzu-Ping; Chen, Chien-Wen

2017-05-01

The generation of linear photonic nanojet using core-shell optical microfiber is demonstrated numerically and experimentally in the visible light region. The power flow patterns for the core-shell optical microfiber are calculated by using the finite-difference time-domain method. The focusing properties of linear photonic nanojet are evaluated in terms of length and width along propagation and transversal directions. In experiment, the silica optical fiber is etched chemically down to 6 μm diameter and coated with metallic thin film by using glancing angle deposition. We show that the linear photonic nanojet is enhanced clearly by metallic shell due to surface plasmon polaritons. The large-area superresolution imaging can be performed by using a core-shell optical microfiber in the far-field system. The potential applications of this core-shell optical microfiber include micro-fluidics and nano-structure measurements.

Future Directions and Challenges in Shell Stability Analysis

NASA Technical Reports Server (NTRS)

Arbocz, Johann

1997-01-01

An answer is sought to the question how comes that today, in 1997, after so many years of concentrated research effort, when it comes to designing buckling critical thin walled shells, one cannot do any better than using the rather conservative Lower Bound Design Philosophy of the sixties. It will be shown that with the establishment of Initial Imperfection Data Banks and the introduction of Probabilistic Design Procedures one has, what appears to be, a viable alternative that when used judiciously may lead step by step to improved shell design recommendations.

Neotectonics of Asia: Thin-shell finite-element models with faults

NASA Technical Reports Server (NTRS)

Kong, Xianghong; Bird, Peter

1994-01-01

As India pushed into and beneath the south margin of Asia in Cenozoic time, it added a great volume of crust, which may have been (1) emplaced locally beneath Tibet, (2) distributed as regional crustal thickening of Asia, (3) converted to mantle eclogite by high-pressure metamorphism, or (4) extruded eastward to increase the area of Asia. The amount of eastward extrusion is especially controversial: plane-stress computer models of finite strain in a continuum lithosphere show minimal escape, while laboratory and theoretical plane-strain models of finite strain in a faulted lithosphere show escape as the dominant mode. We suggest computing the present (or neo)tectonics by use of the known fault network and available data on fault activity, geodesy, and stress to select the best model. We apply a new thin-shell method which can represent a faulted lithosphere of realistic rheology on a sphere, and provided predictions of present velocities, fault slip rates, and stresses for various trial rheologies and boundary conditions. To minimize artificial boundaries, the models include all of Asia east of 40 deg E and span 100 deg on the globe. The primary unknowns are the friction coefficient of faults within Asia and the amounts of shear traction applied to Asia in the Himalayan and oceanic subduction zones at its margins. Data on Quaternary fault activity prove to be most useful in rating the models. Best results are obtained with a very low fault friction of 0.085. This major heterogeneity shows that unfaulted continum models cannot be expected to give accurate simulations of the orogeny. But, even with such weak faults, only a fraction of the internal deformation is expressed as fault slip; this means that rigid microplate models cannot represent the kinematics either. A universal feature of the better models is that eastern China and southeast Asia flow rapidly eastward with respect to Siberia. The rate of escape is very sensitive to the level of shear traction in the

Stress polishing of thin shells for adaptive secondary mirrors. Application to the Very Large Telescope deformable secondary

NASA Astrophysics Data System (ADS)

Hugot, E.; Ferrari, M.; Riccardi, A.; Xompero, M.; Lemaître, G. R.; Arsenault, R.; Hubin, N.

2011-03-01

Context. Adaptive secondary mirrors (ASM) are, or will be, key components on all modern telescopes, providing improved seeing conditions or diffraction limited images, thanks to the high-order atmospheric turbulence correction obtained by controlling the shape of a thin mirror. Their development is a key milestone towards future extremely large telescopes (ELT) where this technology is mandatory for successful observations. Aims: The key point of actual adaptive secondaries technology is the thin glass mirror that acts as a deformable membrane, often aspheric. On 6 m - 8 m class telescopes, these are typically 1 m-class with a 2 mm thickness. The optical quality of this shell must be sufficiently good not to degrade the correction, meaning that high spatial frequency errors must be avoided. The innovative method presented here aims at generating aspherical shapes by elastic bending to reach high optical qualities. Methods: This method is called stress polishing and allows generating aspherical optics of a large amplitude with a simple spherical polishing with a full sized lap applied on a warped blank. The main advantage of this technique is the smooth optical quality obtained, free of high spatial frequency ripples as they are classically caused by subaperture toolmarks. After describing the manufacturing process we developed, our analytical calculations lead to a preliminary definition of the geometry of the blank, which allows a precise bending of the substrate. The finite element analysis (FEA) can be performed to refine this geometry by using an iterative method with a criterion based on the power spectral density of the displacement map of the optical surface. Results: Considering the specific case of the Very Large Telescope (VLT) deformable secondary mirror (DSM), extensive FEA were performed for the optimisation of the geometry. Results are showing that the warping will not introduce surface errors higher than 0.3 nm rms on the minimal spatial scale

A rigid and weathered ice shell on Titan.

PubMed

Hemingway, D; Nimmo, F; Zebker, H; Iess, L

2013-08-29

Several lines of evidence suggest that Saturn's largest moon, Titan, has a global subsurface ocean beneath an outer ice shell 50 to 200 kilometres thick. If convection is occurring, the rigid portion of the shell is expected to be thin; similarly, a weak, isostatically compensated shell has been proposed to explain the observed topography. Here we report a strong inverse correlation between gravity and topography at long wavelengths that are not dominated by tides and rotation. We argue that negative gravity anomalies (mass deficits) produced by crustal thickening at the base of the ice shell overwhelm positive gravity anomalies (mass excesses) produced by the small surface topography, giving rise to this inverse correlation. We show that this situation requires a substantially rigid ice shell with an elastic thickness exceeding 40 kilometres, and hundreds of metres of surface erosion and deposition, consistent with recent estimates from local features. Our results are therefore not compatible with a geologically active, low-rigidity ice shell. After extrapolating to wavelengths that are controlled by tides and rotation, we suggest that Titan's moment of inertia may be even higher (that is, Titan may be even less centrally condensed) than is currently thought.

Imperfection sensitivity of pressured buckling of biopolymer spherical shells

NASA Astrophysics Data System (ADS)

Zhang, Lei; Ru, C. Q.

2016-06-01

Imperfection sensitivity is essential for mechanical behavior of biopolymer shells [such as ultrasound contrast agents (UCAs) and spherical viruses] characterized by high geometric heterogeneity. In this work, an imperfection sensitivity analysis is conducted based on a refined shell model recently developed for spherical biopolymer shells of high structural heterogeneity and thickness nonuniformity. The influence of related parameters (including the ratio of radius to average shell thickness, the ratio of transverse shear modulus to in-plane shear modulus, and the ratio of effective bending thickness to average shell thickness) on imperfection sensitivity is examined for pressured buckling. Our results show that the ratio of effective bending thickness to average shell thickness has a major effect on the imperfection sensitivity, while the effect of the ratio of transverse shear modulus to in-plane shear modulus is usually negligible. For example, with physically realistic parameters for typical imperfect spherical biopolymer shells, the present model predicts that actual maximum external pressure could be reduced to as low as 60% of that of a perfect UCA spherical shell or 55%-65% of that of a perfect spherical virus shell, respectively. The moderate imperfection sensitivity of spherical biopolymer shells with physically realistic imperfection is largely attributed to the fact that biopolymer shells are relatively thicker (defined by smaller radius-to-thickness ratio) and therefore practically realistic imperfection amplitude normalized by thickness is very small as compared to that of classical elastic thin shells which have much larger radius-to-thickness ratio.

Spherical shells buckling to the sound of music

NASA Astrophysics Data System (ADS)

Lee, Anna; Marthelot, Joel; Reis, Pedro

We study how the critical buckling load of spherical elastic shells can be modified by a fluctuating external pressure field. In our experiments, we employ thin elastomeric shells of nearly uniform thickness fabricated by the coating of a hemispherical mold with a polymer solution, which upon curing yields elastic structures. A shell is submerged in a water bath and loaded quasi-statically until buckling occurs by reducing its inner volume with a syringe pump. Simultaneously, a plunger connected to an electromagnetic shaker is placed above the shell and driven sinusoidally to create a fluctuating external pressure field that can excite dynamic vibration modes of the shell. These dynamic modes induce effective compressive stresses, in addition to those from the inner pressure loading, which can modify the critical conditions for the onset of buckling. We systematically quantify how the frequency and amplitude of the external driving affects the buckling strength of our shells. In specific regions of the parameter space, we find that pressure fluctuations can result in large reductions of the critical buckling pressure. This is analogous to the classic knock-down effect in shells due to intrinsic geometric imperfections, albeit now in a way that can be controlled externally.

Rapid Synthesis and Formation Mechanism of Core-Shell-Structured La-Doped SrTiO3 with a Nb-Doped Shell

PubMed Central

Park, Nam-Hee; Akamatsu, Takafumi; Itoh, Toshio; Izu, Noriya; Shin, Woosuck

2015-01-01

To provide a convenient and practical synthesis process for metal ion doping on the surface of nanoparticles in an assembled nanostructure, core-shell-structured La-doped SrTiO3 nanocubes with a Nb-doped surface layer were synthesized via a rapid synthesis combining a rapid sol-precipitation and hydrothermal process. The La-doped SrTiO3 nanocubes were formed at room temperature by a rapid dissolution of NaOH pellets during the rapid sol-precipitation process, and the Nb-doped surface (shell) along with Nb-rich edges formed on the core nanocubes via the hydrothermal process. The formation mechanism of the core-shell-structured nanocubes and their shape evolution as a function of the Nb doping level were investigated. The synthesized core-shell-structured nanocubes could be arranged face-to-face on a SiO2/Si substrate by a slow evaporation process, and this nanostructured 10 μm thick thin film showed a smooth surface. PMID:28793420

Quantum collapse of dust shells in 2 + 1 gravity

NASA Astrophysics Data System (ADS)

Ortíz, L.; Ryan, M. P.

2007-08-01

This paper considers the quantum collapse of infinitesimally thin dust shells in 2 + 1 gravity. In 2 + 1 gravity a shell is no longer a sphere, but a ring of matter. The classical equation of motion of such shells in terms of variables defined on the shell has been considered by Peleg and Steif (Phys Rev D 51:3992, 1995), using the 2 + 1 version of the original formulation of Israel (Nuovo Cimento B 44:1, 1966), and Crisóstomo and Olea (Phys Rev D 69:104023, 2004), using canonical methods. The minisuperspace quantum problem can be reduced to that of a harmonic oscillator in terms of the curvature radius of the shell, which allows us to use well-known methods to find the motion of coherent wave packets that give the quantum collapse of the shell. Classically, as the radius of the shell falls below a certain point, a horizon forms. In the quantum problem one can define various quantities that give “indications” of horizon formation. Without a proper definition of a “horizon” in quantum gravity, these can be nothing but indications.

Periodic buckling of constrained cylindrical elastic shells

NASA Astrophysics Data System (ADS)

Marthelot, Joel; Brun, Pierre-Thomas; Lopez Jimenez, Francisco; Reis, Pedro M.

We revisit the classic problem of buckling of a thin cylindrical elastic shell loaded either by pneumatic depressurization or axial compression. The control of the resulting dimpled pattern is achieved by using a concentric inner rigid mandrel that constrains and stabilizes the post-buckling response. Under axial compression, a regular lattice of diamond-like dimples appears sequentially on the surface of the shell to form a robust spatially extended periodic pattern. Under pressure loading, a periodic array of ridges facets the surface of the elastic cylindrical shell. The sharpness of these ridges can be readily varied and controlled through a single scalar parameter, the applied pressure. A combination of experiments, simulations and scaling analyses is used to rationalize the combined role of geometry and mechanics in the nucleation and evolution of the diamond-like dimples and ridges networks.

Engineered magnetic core shell nanoprobes: Synthesis and applications to cancer imaging and therapeutics.

PubMed

Mandal, Samir; Chaudhuri, Keya

2016-02-26

Magnetic core shell nanoparticles are composed of a highly magnetic core material surrounded by a thin shell of desired drug, polymer or metal oxide. These magnetic core shell nanoparticles have a wide range of applications in biomedical research, more specifically in tissue imaging, drug delivery and therapeutics. The present review discusses the up-to-date knowledge on the various procedures for synthesis of magnetic core shell nanoparticles along with their applications in cancer imaging, drug delivery and hyperthermia or cancer therapeutics. Literature in this area shows that magnetic core shell nanoparticle-based imaging, drug targeting and therapy through hyperthermia can potentially be a powerful tool for the advanced diagnosis and treatment of various cancers.

Thickness constraints on the icy shells of the galilean satellites from a comparison of crater shapes.

PubMed

Schenk, Paul M

2002-05-23

A thin outer ice shell on Jupiter's large moon Europa would imply easy exchange between the surface and any organic or biotic material in its putative subsurface ocean. The thickness of the outer ice shell is poorly constrained, however, with model-dependent estimates ranging from a few kilometres to ten or more kilometres. Here I present measurements of depths of impact craters on Europa, Ganymede and Callisto that reveal two anomalous transitions in crater shape with diameter. The first transition is probably related to temperature-dependent ductility of the crust at shallow depths (7 8 km on Europa). The second transition is attributed to the influence of subsurface oceans on all three satellites, which constrains Europa's icy shell to be at least 19 km thick. The icy lithospheres of Ganymede and Callisto are equally ice-rich, but Europa's icy shell has a thermal structure about 0.25 0.5 times the thicknesses of Ganymede's or Callisto's shells, depending on epoch. The appearances of the craters on Europa are inconsistent with thin-ice-shell models and indicate that exchange of oceanic and surface material could be difficult.

Optimisation of warpage on thin shell plastic part using response surface methodology (RSM) and glowworm swarm optimisation (GSO)

NASA Astrophysics Data System (ADS)

Asyirah, B. N.; Shayfull, Z.; Nasir, S. M.; Fathullah, M.; Hazwan, M. H. M.

2017-09-01

In manufacturing a variety of parts, plastic injection moulding is widely use. The injection moulding process parameters have played important role that affects the product's quality and productivity. There are many approaches in minimising the warpage ans shrinkage such as artificial neural network, genetic algorithm, glowworm swarm optimisation and hybrid approaches are addressed. In this paper, a systematic methodology for determining a warpage and shrinkage in injection moulding process especially in thin shell plastic parts are presented. To identify the effects of the machining parameters on the warpage and shrinkage value, response surface methodology is applied. In thos study, a part of electronic night lamp are chosen as the model. Firstly, experimental design were used to determine the injection parameters on warpage for different thickness value. The software used to analyse the warpage is Autodesk Moldflow Insight (AMI) 2012.

Effects of calcination temperature for rate capability of triple-shelled ZnFe2O4 hollow microspheres for lithium ion battery anodes

NASA Astrophysics Data System (ADS)

Hwang, Hojin; Shin, Haeun; Lee, Wan-Jin

2017-04-01

Triple-shelled ZnFe2O4 hollow microspheres (ZFO) as anode materials for lithium ion battery are prepared through a one-pot hydrothermal reaction using the composite solution consisting of sucrose in water and metal ions in ethylene glycol (EG), followed by different calcination processes. The architectures of ZFO micro spheres are differently synthesized through a mutual cooperation of inward and outward ripening with three different calcination temperatures. Thin triple-shelled ZnFe2O4 hollow microspheres calcined at 450 °C (ZFO-450) delivers a high reversible capacity of 932 mA h g-1 at a current density of 2 A g-1 even at the 200th cycle without obvious decay. Furthermore, ZFO-450 delivers 1235, 1005, 865, 834, and 845 mA h g-1 at high current densities of 0.5, 2, 5, 10, and 20 A g-1 after 100 cycles. Thin triple-shelled hollow microsphere prepared at an optimum calcination temperature provides exceptional rate capability and outstanding rate retention due to (i) the formation of nanoparticles leading to thin shell with morphological integrity, (ii) the facile mass transfer by thin shell with mesoporous structure, and (iii) the void space with macroporous structure alleviating volume change occurring during cycling.

Effects of calcination temperature for rate capability of triple-shelled ZnFe2O4 hollow microspheres for lithium ion battery anodes

PubMed Central

Hwang, Hojin; Shin, Haeun; Lee, Wan-Jin

2017-01-01

Triple-shelled ZnFe2O4 hollow microspheres (ZFO) as anode materials for lithium ion battery are prepared through a one-pot hydrothermal reaction using the composite solution consisting of sucrose in water and metal ions in ethylene glycol (EG), followed by different calcination processes. The architectures of ZFO micro spheres are differently synthesized through a mutual cooperation of inward and outward ripening with three different calcination temperatures. Thin triple-shelled ZnFe2O4 hollow microspheres calcined at 450 °C (ZFO-450) delivers a high reversible capacity of 932 mA h g−1 at a current density of 2 A g−1 even at the 200th cycle without obvious decay. Furthermore, ZFO-450 delivers 1235, 1005, 865, 834, and 845 mA h g−1 at high current densities of 0.5, 2, 5, 10, and 20 A g−1 after 100 cycles. Thin triple-shelled hollow microsphere prepared at an optimum calcination temperature provides exceptional rate capability and outstanding rate retention due to (i) the formation of nanoparticles leading to thin shell with morphological integrity, (ii) the facile mass transfer by thin shell with mesoporous structure, and (iii) the void space with macroporous structure alleviating volume change occurring during cycling. PMID:28418001

Static, free vibration and thermal analysis of composite plates and shells using a flat triangular shell element

NASA Astrophysics Data System (ADS)

Kapania, R. K.; Mohan, P.

1996-09-01

Finite element static, free vibration and thermal analysis of thin laminated plates and shells using a three noded triangular flat shell element is presented. The flat shell element is a combination of the Discrete Kirchhoff Theory (DKT) plate bending element and a membrane element derived from the Linear Strain Triangular (LST) element with a total of 18 degrees of freedom (3 translations and 3 rotations per node). Explicit formulations are used for the membrane, bending and membrane-bending coupling stiffness matrices and the thermal load vector. Due to a strong analogy between the induced strain caused by the thermal field and the strain induced in a structure due to an electric field the present formulation is readily applicable for the analysis of structures excited by surface bonded or embedded piezoelectric actuators. The results are presented for (i) static analysis of (a) simply supported square plates under doubly sinusoidal load and uniformly distributed load (b) simply supported spherical shells under a uniformly distributed load, (ii) free vibration analysis of (a) square cantilever plates, (b) skew cantilever plates and (c) simply supported spherical shells; (iii) Thermal deformation analysis of (a) simply supported square plates, (b) simply supported-clamped square plate and (c) simply supported spherical shells. A numerical example is also presented demonstrating the application of the present formulation to analyse a symmetrically laminated graphite/epoxy laminate excited by a layer of piezoelectric polyvinylidene flouride (PVDF). The results presented are in good agreement with those available in the literature.

Enhanced direct-drive implosions with thin high-Z ablation layers.

PubMed

Mostovych, Andrew N; Colombant, Denis G; Karasik, Max; Knauer, James P; Schmitt, Andrew J; Weaver, James L

2008-02-22

New direct-drive spherical implosion experiments with deuterium filled plastic shells have demonstrated significant and absolute (2x) improvements in neutron yield when the shells are coated with a very thin layer ( approximately 200-400 A) of high-Z material such as palladium. This improvement is interpreted as resulting from increased stability of the imploding shell. These results provide for a possible path to control laser imprint and stability in laser-fusion-energy target designs.

Buckling Behavior of Compression-Loaded Composite Cylindrical Shells With Reinforced Cutouts

NASA Technical Reports Server (NTRS)

Hilburger, Mark W.; Sarnes, James H., Jr.

2004-01-01

Results from a numerical study of the response of thin-walled compression-loaded quasi-isotropic laminated composite cylindrical shells with unreinforced and reinforced square cutouts are presented. The effects of cutout reinforcement orthotropy, size, and thickness on the nonlinear response of the shells are described. A nonlinear analysis procedure has been used to predict the nonlinear response of the shells. The results indicate that a local buckling response occurs in the shell near the cutout when subjected to load and is caused by a nonlinear coupling between local shell-wall deformations and in-plane destabilizing compression stresses near the cutout. In general, reinforcement around a cutout in a compression-loaded shell is shown to retard or eliminate the local buckling response near the cutout and increase the buckling load of the shell. However, some results show that certain reinforcement configurations can cause an unexpected increase in the magnitude of local deformations and stresses in the shell and cause a reduction in the buckling load. Specific cases are presented that suggest that the orthotropy, thickness, and size of a cutout reinforcement in a shell can be tailored to achieve improved buckling response characteristics.

The energy of a prolate spheroidal shell in a uniform magnetic field

NASA Astrophysics Data System (ADS)

Koksharov, Yu. A.

2017-04-01

The problem of the energy of a spheroidal magnetic shell, solved by methods of classical electrodynamics, arises, in particular, upon the study of thin-wall biocompatible microcapsules in connection with a pressing issue of targeted drug delivery. The drug inside a microcapsule should be released from the shell at a required instant of time by destroying the capsule's shell. The placement inside a shell of magnetic nanoparticles sensitive to an external magnetic field theoretically makes it possible to solve both problems: to transport a capsule to the required place and to destroy its shell. In particular, the shell can be destroyed under the action of internal stress when the shape of a capsule is changed. In this paper, the analysis of the model of a magnetic microcapsule in the form of a prolate spheroidal shell is performed and formulas for the magnetostatic and magnetic free energy when the magnetic field is directed along the major axis of the spheroid are derived.

Holographic measurement of wave propagation in axi-symmetric shells

NASA Technical Reports Server (NTRS)

Evensen, D. A.; Aprahamian, R.; Jacoby, J. L.

1972-01-01

The report deals with the use of pulsed, double-exposure holographic interferometry to record the propagation of transverse waves in thin-walled axi-symmetric shells. The report is subdivided into sections dealing with: (1) wave propagation in circular cylindrical shells, (2) wave propagation past cut-outs and stiffeners, and (3) wave propagation in conical shells. Several interferograms are presented herein which show the waves reflecting from the shell boundaries, from cut-outs, and from stiffening rings. The initial response of the shell was nearly axi-symmetric in all cases, but nonsymmetric modes soon appeared in the radial response. This result suggests that the axi-symmetric response of the shell may be dynamically unstable, and thus may preferentially excite certain circumferential harmonics through parametric excitation. Attempts were made throughout to correlate the experimental data with analysis. For the most part, good agreement between theory and experiment was obtained. Occasional differences were attributed primarily to simplifying assumptions used in the analysis. From the standpoint of engineering applications, it is clear that pulsed laser holography can be used to obtain quantitative engineering data. Areas of dynamic stress concentration, stress concentration factors, local anomalies, etc., can be readily determined by holography.

Thermoviscoelastoplastic Deformation of Compound Shells of Revolution Made of a Damageable Material

NASA Astrophysics Data System (ADS)

Shevchenko, Yu. N.; Galishin, A. Z.; Babeshko, M. E.

2015-11-01

A technique for numerical analysis of the thermoviscoelastoplastic deformation of thin compound shells made of a damageable material in which a fracture front propagates is described. A procedure for automatic variation in the step of integration of the kinetic damage equation is developed. A two-layer cylindrical shell cooling by convection and subjected to internal pressure and tensile force is analyzed as an example. The numerical data are presented and analyzed

Iridescence of a shell of mollusk Haliotis Glabra

NASA Astrophysics Data System (ADS)

Tan, T. L.; Wong, D.; Lee, Paul

2004-10-01

Pearls and shells of some mollusks are attractive inorganic materials primarily owing to the beauty of their natural lustrous and iridescent surface. The iridescent colors can be explained by diffraction or interference or both, depending on the microstructure of the surface. Strong iridescent colors are very evident on the polished shell of the mollusk Haliotis Glabra, commonly known as abalone. It would be interesting to study how these colors are produced on the surface of the shell. By using a scanning electron microscope (SEM), the surface of the shell is found to have a fine-scale diffraction grating structure, and stacks of thin crystalline nacreous layers or platelets are found below the surface. These observations suggest that the iridescent colors are caused by both diffraction and interference. From measurements done on the diffraction patterns that were obtained using a He-Ne laser illuminating the shell, the groove width of the grating structure was derived. Good agreement was found between the derived groove density by diffraction and that measured directly using the SEM. The crystalline structure of the nacreous layers of the shell is studied using Fourier transform infrared spectroscopy and SEM observations. The infrared absorption peaks of 700, 713, 862 and 1083 cm-1 confirmed that the nacre of the shell is basically aragonite. The strong iridescent colors of the shell are the result of high groove density on the surface which causes diffraction. The uniform stacking of layers of nacre below the surface of the shell also causes interference effects that contribute to the iridescent colors.

Vertically aligned P(VDF-TrFE) core-shell structures on flexible pillar arrays

DOE PAGES

Choi, Yoon-Young; Yun, Tae Gwang; Qaiser, Nadeem; ...

2015-06-04

PVDF and P(VDF-TrFE) nano- and micro- structures are widely used due to their potential applications in several fields, including sensors, actuators, vital sign transducers, and energy harvesters. In this study, we developed vertically aligned P(VDF-TrFE) core-shell structures using high modulus polyurethane acrylate (PUA) pillars as the support structure to maintain the structural integrity. In addition, we were able to improve the piezoelectric effect by 1.85 times from 40 ± 2 to 74 ± 2 pm/V when compared to the thin film counterpart, which contributes to the more efficient current generation under a given stress, by making an effective use ofmore » the P(VDF-TrFE) thin top layer as well as the side walls. We attribute the enhancement of piezoelectric effects to the contributions from the shell component and the strain confinement effect, which was supported by our modeling results. We envision that these organic-based P(VDF-TrFE) core-shell structures will be used widely as 3D sensors and power generators because they are optimized for current generations by utilizing all surface areas, including the side walls of core-shell structures.« less

Resistive switching of Sn-doped In2O3/HfO2 core-shell nanowire: geometry architecture engineering for nonvolatile memory.

PubMed

Huang, Chi-Hsin; Chang, Wen-Chih; Huang, Jian-Shiou; Lin, Shih-Ming; Chueh, Yu-Lun

2017-05-25

Core-shell NWs offer an innovative approach to achieve nanoscale metal-insulator-metal (MIM) heterostructures along the wire radial direction, realizing three-dimensional geometry architecture rather than planar type thin film devices. This work demonstrated the tunable resistive switching characteristics of ITO/HfO 2 core-shell nanowires with controllable shell thicknesses by the atomic layer deposition (ALD) process for the first time. Compared to planar HfO 2 thin film device configuration, ITO/HfO 2 core-shell nanowire shows a prominent resistive memory behavior, including lower power consumption with a smaller SET voltage of ∼0.6 V and better switching voltage uniformity with variations (standard deviation(σ)/mean value (μ)) of V SET and V RESET from 0.38 to 0.14 and from 0.33 to 0.05 for ITO/HfO 2 core-shell nanowire and planar HfO 2 thin film, respectively. In addition, endurance over 10 3 cycles resulting from the local electric field enhancement can be achieved, which is attributed to geometry architecture engineering. The concept of geometry architecture engineering provides a promising strategy to modify the electric-field distribution for solving the non-uniformity issue of future RRAM.

Bulk Nanolaminated Nickel: Preparation, Microstructure, Mechanical Property, and Thermal Stability

NASA Astrophysics Data System (ADS)

Liu, Fan; Yuan, Hao; Goel, Sunkulp; Liu, Ying; Wang, Jing Tao

2018-02-01

A bulk nanolaminated (NL) structure with distinctive fractions of low- and high-angle grain boundaries ( f LAGBs and f HAGBs) is produced in pure nickel, through a two-step process of primary grain refinement by equal-channel angular pressing (ECAP), followed by a secondary geometrical refinement via liquid nitrogen rolling (LNR). The lamellar boundary spacings of 2N and 4N nickel are refined to 40 and 70 nm, respectively, and the yield strength of the NL structure in 2N nickel reaches 1.5 GPa. The impacts of the deformation path, material purity, grain boundary (GB) misorientation, and energy on the microstructure, refinement ability, mechanical strength, and thermal stability are investigated to understand the inherent governing mechanisms. GB migration is the main restoration mechanism limiting the refinement of an NL structure in 4N nickel, while in 2N nickel, shear banding occurs and mediates one-fifth of the total true normal rolling strain at the mesoscale, restricting further refinement. Three typical structures [ultrafine grained (UFG), NL with low f LAGBs, and NL with high f LAGBs] obtained through three different combinations of ECAP and LNR were studied by isochronal annealing for 1 hour at temperatures ranging from 433 K to 973 K (160 °C to 700 °C). Higher thermal stability in the NL structure with high f LAGBs is shown by a 50 K (50 °C) delay in the initiation temperature of recrystallization. Based on calculations and analyses of the stored energies of deformed structures from strain distribution, as characterized by kernel average misorientation (KAM), and from GB misorientations, higher thermal stability is attributed to high f LAGBs in this type of NL structure. This is confirmed by a slower change in the microstructure, as revealed by characterizing its annealing kinetics using KAM maps.

Giant dielectric constant dominated by Maxwell-Wagner relaxation in Al{sub 2}O{sub 3}/TiO{sub 2} nanolaminates synthesized by atomic layer deposition.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, W.; Auciello, O.; Premnath, R. N.

2010-01-01

Nanolaminates consisting of Al{sub 2}O{sub 3} and TiO{sub 2} oxide sublayers were synthesized by using atomic layer deposition to produce individual layers with atomic scale thickness control. The sublayer thicknesses were kept constant for each multilayer structure, and were changed from 50 to 0.2 nm for a series of different samples. Giant dielectric constant ({approx}1000) was observed when the sublayer thickness is less than 0.5 nm, which is significantly larger than that of Al{sub 2}O{sub 3} and TiO{sub 2} dielectrics. Detailed investigation revealed that the observed giant dielectric constant is originated from the Maxwell-Wagner type dielectric relaxation.

Low-frequency vibrations of a cylindrical shell rotating on rollers

NASA Astrophysics Data System (ADS)

Filippov, S. B.

2018-05-01

Small free low-frequency vibrations of a rotating closed cylindrical shell which is in a contact with rigid cylindrical rollers are considered. Assumptions of semi-momentless shell theory are used. By means of the expansion of solutions in truncated Fourier series in circumference coordinate the system of the algebraic equations for the approximate calculation of the vibration frequencies and the mode shapes is obtained. The algorithm for the evaluation of frequencies and vibration modes based on analytical solution is developed. In particular, the lowest frequencies of thin cylindrical shell, representing greatest interest for applications, were found. Approximate results are compared with results of numerical calculations carried out by the Finite Elements Analysis. It is shown that the semi-momentless theory can be used for the evaluation of the low frequencies of a cylindrical shell rotating on rollers.

Organic and inorganic–organic thin film structures by molecular layer deposition: A review

PubMed Central

Sundberg, Pia

2014-01-01

Summary The possibility to deposit purely organic and hybrid inorganic–organic materials in a way parallel to the state-of-the-art gas-phase deposition method of inorganic thin films, i.e., atomic layer deposition (ALD), is currently experiencing a strongly growing interest. Like ALD in case of the inorganics, the emerging molecular layer deposition (MLD) technique for organic constituents can be employed to fabricate high-quality thin films and coatings with thickness and composition control on the molecular scale, even on complex three-dimensional structures. Moreover, by combining the two techniques, ALD and MLD, fundamentally new types of inorganic–organic hybrid materials can be produced. In this review article, we first describe the basic concepts regarding the MLD and ALD/MLD processes, followed by a comprehensive review of the various precursors and precursor pairs so far employed in these processes. Finally, we discuss the first proof-of-concept experiments in which the newly developed MLD and ALD/MLD processes are exploited to fabricate novel multilayer and nanostructure architectures by combining different inorganic, organic and hybrid material layers into on-demand designed mixtures, superlattices and nanolaminates, and employing new innovative nanotemplates or post-deposition treatments to, e.g., selectively decompose parts of the structure. Such layer-engineered and/or nanostructured hybrid materials with exciting combinations of functional properties hold great promise for high-end technological applications. PMID:25161845

Curvature-Induced Instabilities of Shells

NASA Astrophysics Data System (ADS)

Pezzulla, Matteo; Stoop, Norbert; Steranka, Mark P.; Bade, Abdikhalaq J.; Holmes, Douglas P.

2018-01-01

Induced by proteins within the cell membrane or by differential growth, heating, or swelling, spontaneous curvatures can drastically affect the morphology of thin bodies and induce mechanical instabilities. Yet, the interaction of spontaneous curvature and geometric frustration in curved shells remains poorly understood. Via a combination of precision experiments on elastomeric spherical shells, simulations, and theory, we show how a spontaneous curvature induces a rotational symmetry-breaking buckling as well as a snapping instability reminiscent of the Venus fly trap closure mechanism. The instabilities, and their dependence on geometry, are rationalized by reducing the spontaneous curvature to an effective mechanical load. This formulation reveals a combined pressurelike term in the bulk and a torquelike term in the boundary, allowing scaling predictions for the instabilities that are in excellent agreement with experiments and simulations. Moreover, the effective pressure analogy suggests a curvature-induced subcritical buckling in closed shells. We determine the critical buckling curvature via a linear stability analysis that accounts for the combination of residual membrane and bending stresses. The prominent role of geometry in our findings suggests the applicability of the results over a wide range of scales.

Contact interaction of thin-walled elements with an elastic layer and an infinite circular cylinder under torsion

NASA Astrophysics Data System (ADS)

Kanetsyan, E. G.; Mkrtchyan, M. S.; Mkhitaryan, S. M.

2018-04-01

We consider a class of contact torsion problems on interaction of thin-walled elements shaped as an elastic thin washer – a flat circular plate of small height – with an elastic layer, in particular, with a half-space, and on interaction of thin cylindrical shells with a solid elastic cylinder, infinite in both directions. The governing equations of the physical models of elastic thin washers and thin circular cylindrical shells under torsion are derived from the exact equations of mathematical theory of elasticity using the Hankel and Fourier transforms. Within the framework of the accepted physical models, the solution of the contact problem between an elastic washer and an elastic layer is reduced to solving the Fredholm integral equation of the first kind with a kernel representable as a sum of the Weber–Sonin integral and some integral regular kernel, while solving the contact problem between a cylindrical shell and solid cylinder is reduced to a singular integral equation (SIE). An effective method for solving the governing integral equations of these problems are specified.

Non-uniform thickness in Europa's icy shell: implications for astrobiology mission design

NASA Astrophysics Data System (ADS)

Fairén, A.; Amils, R.

The exploration of Europa's subsurface ocean is hardly constrained by the presence of an outer ice shell of unknown thickness: a somewhat thin crust would allow easier access to the ocean below. Current estimates for the thickness of Europa's icy surface range from a few km [1] to a few tens of km [2], the shell overlying a liquid water ocean up to 150 km thick [3,4,5]. The surface is believed to be young (mean age of 30-80 Myr [6]) and geologically active [7,8,9], as it is sparsely cratered. Here we report geological evidence indicating that the thickness of Europa's ice crust is actually a complex combination of thicker and thinner areas, highlighting the implications of such structure in the future exploration of the inner ocean. Detailed geologic mapping of impact craters, palimpsests and chaotic terrains distribution on Europa's surface, offers an initial approach to a comprehensive description of the thickness variation in the ice shell. Our analysis is based in: (1) Crater distribution, morphology, diameter and depth. Seminal work by Schenk [2] of transitions in crater shape/diameter suggested enhanced structural collapse of craters with diameter >27-33 km, that will consequently form multiring basins, due to weaker ice or a global ocean at depths >19-25 km. This being true, strictly can only be interpreted regionally: multiring basins indicate regions where the ice shell is thick; in those regions where the icy surface is thin, a bolide impact will breach the ice and leave neither crater nor multiring basin behind, but probably Ganymede's type palimpsests. (2) Palimpsest-type features distribution, indicating regions where the ice shell is too thin to support crater formation after big bolide impacts. In Ganymede, palimpsests are circular, low albedo and relief features formerly formed by impacts [10,11]. (3) Chaotic terrain distribution, considering features tens to hundreds of km across, that may be the evidence for very thin ice areas (from ˜ 2 km to

Propagation of flexural and membrane waves with fluid loaded NASTRAN plate and shell elements

NASA Technical Reports Server (NTRS)

Kalinowski, A. J.; Wagner, C. A.

1983-01-01

Modeling of flexural and membrane type waves existing in various submerged (or in vacuo) plate and/or shell finite element models that are excited with steady state type harmonic loadings proportioned to e(i omega t) is discussed. Only thin walled plates and shells are treated wherein rotary inertia and shear correction factors are not included. More specifically, the issue of determining the shell or plate mesh size needed to represent the spatial distribution of the plate or shell response is of prime importance towards successfully representing the solution to the problem at hand. To this end, a procedure is presented for establishing guide lines for determining the mesh size based on a simple test model that can be used for a variety of plate and shell configurations such as, cylindrical shells with water loading, cylindrical shells in vacuo, plates with water loading, and plates in vacuo. The procedure for doing these four cases is given, with specific numerical examples present only for the cylindrical shell case.

Finite indentation of highly curved elastic shells

NASA Astrophysics Data System (ADS)

Pearce, S. P.; King, J. R.; Steinbrecher, T.; Leubner-Metzger, G.; Everitt, N. M.; Holdsworth, M. J.

2018-01-01

Experimentally measuring the elastic properties of thin biological surfaces is non-trivial, particularly when they are curved. One technique that may be used is the indentation of a thin sheet of material by a rigid indenter, while measuring the applied force and displacement. This gives immediate information on the fracture strength of the material (from the force required to puncture), but it is also theoretically possible to determine the elastic properties by comparing the resulting force-displacement curves with a mathematical model. Existing mathematical studies generally assume that the elastic surface is initially flat, which is often not the case for biological membranes. We previously outlined a theory for the indentation of curved isotropic, incompressible, hyperelastic membranes (with no bending stiffness) which breaks down for highly curved surfaces, as the entire membrane becomes wrinkled. Here, we introduce the effect of bending stiffness, ensuring that energy is required to change the shell shape without stretching, and find that commonly neglected terms in the shell equilibrium equation must be included. The theory presented here allows for the estimation of shape- and size-independent elastic properties of highly curved surfaces via indentation experiments, and is particularly relevant for biological surfaces.

Finite indentation of highly curved elastic shells

PubMed Central

2018-01-01

Experimentally measuring the elastic properties of thin biological surfaces is non-trivial, particularly when they are curved. One technique that may be used is the indentation of a thin sheet of material by a rigid indenter, while measuring the applied force and displacement. This gives immediate information on the fracture strength of the material (from the force required to puncture), but it is also theoretically possible to determine the elastic properties by comparing the resulting force–displacement curves with a mathematical model. Existing mathematical studies generally assume that the elastic surface is initially flat, which is often not the case for biological membranes. We previously outlined a theory for the indentation of curved isotropic, incompressible, hyperelastic membranes (with no bending stiffness) which breaks down for highly curved surfaces, as the entire membrane becomes wrinkled. Here, we introduce the effect of bending stiffness, ensuring that energy is required to change the shell shape without stretching, and find that commonly neglected terms in the shell equilibrium equation must be included. The theory presented here allows for the estimation of shape- and size-independent elastic properties of highly curved surfaces via indentation experiments, and is particularly relevant for biological surfaces. PMID:29434505

Mounting and Alignment of Full-Shell Replicated X-Ray Optics

NASA Technical Reports Server (NTRS)

Gubarev, Mikhail; Arnold, William; Kester, Thomas; Ramsey, Brian; Smithers, Martin

2007-01-01

We are developing grazing-incidence x-ray optics for astronomy. The optics are full-cylinder mirror shells fabricated using electroformed-nickel replication off super-polished mandrels. For space-based applications where weight is at a premium, very-thin-walled, light-weight mirrors are required. Such shells have been fabricated at MSFC with greater than 15 arcsec resolution. The challenge, however, is to preserve this resolution during mounting and assembly. We present here a status report on a mounting and alignment system currently under development at Marshall Space Flight Center to meet this challenge.

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Velikovich, A. L.; Schmit, P. F.

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. In the limit of small shell thickness, exact thin-shell perturbation equations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

NASA Astrophysics Data System (ADS)

Velikovich, A. L.; Schmit, P. F.

2015-12-01

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining the "instantaneous growth rate" are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. In the limit of small shell thickness, exact thin-shell perturbation equations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].

Ballistic Simulation Method for Lithium Ion Batteries (BASIMLIB) Using Thick Shell Composites (TSC) in LS-DYNA

DTIC Science & Technology

2016-08-04

BAllistic SImulation Method for Lithium Ion Batteries (BASIMLIB) using Thick Shell Composites (TSC) in LS-DYNA Venkatesh Babu, Dr. Matt Castanier, Dr...Objective • Objective and focus of this work is to develop a – Robust simulation methodology to model lithium - ion based batteries in its module and full...unlimited  Lithium Ion Phosphate (LiFePO4) battery cell, module and pack was modeled in LS-DYNA using both Thin Shell Layer (TSL) and Thick Shell

Vertically aligned P(VDF-TrFE) core-shell structures on flexible pillar arrays

PubMed Central

Choi, Yoon-Young; Yun, Tae Gwang; Qaiser, Nadeem; Paik, Haemin; Roh, Hee Seok; Hong, Jongin; Hong, Seungbum; Han, Seung Min; No, Kwangsoo

2015-01-01

PVDF and P(VDF-TrFE) nano- and micro- structures have been widely used due to their potential applications in several fields, including sensors, actuators, vital sign transducers, and energy harvesters. In this study, we developed vertically aligned P(VDF-TrFE) core-shell structures using high modulus polyurethane acrylate (PUA) pillars as the support structure to maintain the structural integrity. In addition, we were able to improve the piezoelectric effect by 1.85 times from 40 ± 2 to 74 ± 2 pm/V when compared to the thin film counterpart, which contributes to the more efficient current generation under a given stress, by making an effective use of the P(VDF-TrFE) thin top layer as well as the side walls. We attribute the enhancement of piezoelectric effects to the contributions from the shell component and the strain confinement effect, which was supported by our modeling results. We envision that these organic-based P(VDF-TrFE) core-shell structures will be used widely as 3D sensors and power generators because they are optimized for current generations by utilizing all surface areas, including the side walls of core-shell structures. PMID:26040539

Buckling Behavior of Compression-Loaded Composite Cylindrical Shells with Reinforced Cutouts

NASA Technical Reports Server (NTRS)

Hilburger, Mark W.; Starnes, James H., Jr.

2002-01-01

Results from a numerical study of the response of thin-wall compression-loaded quasi-isotropic laminated composite cylindrical shells with reinforced and unreinforced square cutouts are presented. The effects of cutout reinforcement orthotropy, size, and thickness on the nonlinear response of the shells are described. A high-fidelity nonlinear analysis procedure has been used to predict the nonlinear response of the shells. The analysis procedure includes a nonlinear static analysis that predicts stable response characteristics of the shells and a nonlinear transient analysis that predicts unstable dynamic buckling response characteristics. The results illustrate how a compression-loaded shell with an unreinforced cutout can exhibit a complex nonlinear response. In particular, a local buckling response occurs in the shell near the cutout and is caused by a complex nonlinear coupling between local shell-wall deformations and in-plane destabilizing compression stresses near the cutout. In general, the addition of reinforcement around a cutout in a compression-loaded shell can retard or eliminate the local buckling response near the cutout and increase the buckling load of the shell, as expected. However, results are presented that show how certain reinforcement configurations can actually cause an unexpected increase in the magnitude of local deformations and stresses in the shell and cause a reduction in the buckling load. Specific cases are presented that suggest that the orthotropy, thickness, and size of a cutout reinforcement in a shell can be tailored to achieve improved response characteristics.

Greenhouse Effect: Temperature of a Metal Sphere Surrounded by a Glass Shell and Heated by Sunlight

ERIC Educational Resources Information Center

Nguyen, Phuc H.; Matzner, Richard A.

2012-01-01

We study the greenhouse effect on a model satellite consisting of a tungsten sphere surrounded by a thin spherical, concentric glass shell, with a small gap between the sphere and the shell. The system sits in vacuum and is heated by sunlight incident along the "z"-axis. This development is a generalization of the simple treatment of the…

Analysis of transient, linear wave propagation in shells by the finite difference method

NASA Technical Reports Server (NTRS)

Geers, T. L.; Sobel, L. H.

1971-01-01

The applicability of the finite difference method to propagation problems in shells, and the response of a cylindrical shell with cutouts to both longitudinal and radial transient excitations are investigated. It is found that the only inherent limitation of the finite difference method is its inability to reproduce accurately response discontinuities. The short wave length limitations of thin shell theory create significant convergence difficulties may often be overcome through proper selection of finite difference mesh dimensions and temporal or spatial smoothing of the excitation. Cutouts produce moderate changes in early and intermediate time response of a cylindrical shell to axisymmetric pulse loads applied at one end. The cutouts may facilitate the undesirable late-time transfer of load-injected extensional energy into nonaxisymmetric flexural response.

The Oscillations of Coronal Loops Including the Shell

NASA Astrophysics Data System (ADS)

Mikhalyaev, B. B.; Solov'ev, A. A.

2005-04-01

We investigate the MHD waves in a double magnetic flux tube embedded in a uniform external magnetic field. The tube consists of a dense hot cylindrical cord surrounded by a co-axial shell. The plasma and the magnetic field are taken to be uniform inside the cord and also inside the shell. Two slow and two fast magnetosonic modes can exist in the thin double tube. The first slow mode is trapped by the cord, the other is trapped by the shell. The oscillations of the second mode have opposite phases inside the cord and shell. The speeds of the slow modes propagating along the tube are close to the tube speeds inside the cord and the shell. The behavior of the fast modes depends on the magnitude of Alfvén speed inside the shell. If it is less than the Alfvén speed inside the cord and in the environment, then the fast mode is trapped by the shell and the other may be trapped under the certain conditions. In the opposite case when the Alfvén speed in the shell is greater than those inside the cord and in the environment, then the fast mode is radiated by the tube and the other may also be radiated under certain conditions. The oscillation of the cord and the shell with opposite phases is the distinctive feature of the process. The proposed model allows to explain the basic phenomena connected to the coronal oscillations: i) the damping of oscillations stipulated in the double tube model by the radiative loss, ii) the presence of two different modes of perturbations propagating along the loop with close speeds, iii) the opposite phases of oscillations of modulated radio emission, coming from the near coronal sources having sharply different densities.

A numerical approach for simulating fluid structure interaction of flexible thin shells undergoing arbitrarily large deformations in complex domains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gilmanov, Anvar, E-mail: agilmano@umn.edu; Le, Trung Bao, E-mail: lebao002@umn.edu; Sotiropoulos, Fotis, E-mail: fotis@umn.edu

We present a new numerical methodology for simulating fluid–structure interaction (FSI) problems involving thin flexible bodies in an incompressible fluid. The FSI algorithm uses the Dirichlet–Neumann partitioning technique. The curvilinear immersed boundary method (CURVIB) is coupled with a rotation-free finite element (FE) model for thin shells enabling the efficient simulation of FSI problems with arbitrarily large deformation. Turbulent flow problems are handled using large-eddy simulation with the dynamic Smagorinsky model in conjunction with a wall model to reconstruct boundary conditions near immersed boundaries. The CURVIB and FE solvers are coupled together on the flexible solid–fluid interfaces where the structural nodalmore » positions, displacements, velocities and loads are calculated and exchanged between the two solvers. Loose and strong coupling FSI schemes are employed enhanced by the Aitken acceleration technique to ensure robust coupling and fast convergence especially for low mass ratio problems. The coupled CURVIB-FE-FSI method is validated by applying it to simulate two FSI problems involving thin flexible structures: 1) vortex-induced vibrations of a cantilever mounted in the wake of a square cylinder at different mass ratios and at low Reynolds number; and 2) the more challenging high Reynolds number problem involving the oscillation of an inverted elastic flag. For both cases the computed results are in excellent agreement with previous numerical simulations and/or experiential measurements. Grid convergence tests/studies are carried out for both the cantilever and inverted flag problems, which show that the CURVIB-FE-FSI method provides their convergence. Finally, the capability of the new methodology in simulations of complex cardiovascular flows is demonstrated by applying it to simulate the FSI of a tri-leaflet, prosthetic heart valve in an anatomic aorta and under physiologic pulsatile conditions.« less

Absolute cross-section measurements of inner-shell ionization

NASA Astrophysics Data System (ADS)

Schneider, Hans; Tobehn, Ingo; Ebel, Frank; Hippler, Rainer

1994-12-01

Cross section ratios for K- and L-shell ionization of thin silver and gold targets by positron and electron impact have been determined at projectile energies of 30 70 keV. The experimental results are confirmed by calculations in plane wave Born approximation (PWBA) which include an electron exchange term and account for the deceleration or acceleration of the incident projectile in the nuclear field of the target atom. We report first absolute cross sections for K- and L-shell ionization of silver and gold targets by lepton impact in the threshold region. We have measured the corresponding cross sections for electron (e-) impact with an electron gun and the same experimental set-up.

Polarimetry of nacre in iridescent shells

NASA Astrophysics Data System (ADS)

Metzler, R. A.; Burgess, C.; Regan, B.; Spano, S.; Galvez, E. J.

2014-09-01

We investigate the light transmitted or reflected from nacre (mother of pearl) taken from the iridescent shell of the bivalve Pinctad a fucata. These nacre surfaces have a rich structure, composed of aragonite crystals arranged as tablets or bricks, 5 μm wide and 400-500 nm thick, surrounded by 30nm thick organic mortar. The light reflected from these shell surfaces, or transmitted through thin polished layers, is rich in its polarization content, exhibiting a space dependent variation in the state of polarization with a high density of polarization singularities. Our goal is to use the polarization information to infer the structure of the biominerals and the role of the organic layer in determining the orientation of the crystals. In the experiments we send the light from a laser with a uniform state of polarization onto the shell, and analyze the light that is either transmitted or reflected, depending on the type of experiment, imaging it after its passage through polarization filters. We use the images from distinct filters to obtain the Stokes parameters, and hence the state of polarization, of each image point. We also construct the Mueller matrix for each imaged point, via 36 measurements. We do this for distinct physical and chemical treatments of the shell sample. Preliminary data shows that the organic layer may be responsible for organizing a multi-crystalline arrangement of aragonite tablets.

Micromechanical and in situ shear testing of Al–SiC nanolaminate composites in a transmission electron microscope (TEM)

DOE PAGES

Mayer, Carl; Li, Nan; Mara, Nathan Allan; ...

2014-11-07

Nanolaminate composites show promise as high strength and toughness materials. Still, due to the limited volume of these materials, micron scale mechanical testing methods must be used to determine the properties of these films. To this end, a novel approach combining a double notch shear testing geometry and compression with a flat punch in a nanoindenter was developed to determine the mechanical properties of these films under shear loading. To further elucidate the failure mechanisms under shear loading, in situ TEM experiments were performed using a double notch geometry cut into the TEM foil. Aluminum layer thicknesses of 50nm andmore » 100nm were used to show the effect of constraint on the deformation. Higher shear strength was observed in the 50 nm sample (690±54 MPa) compared to the 100 nm sample (423±28.7 MPa). Additionally, failure occurred along the Al-SiC interface in the 50 nm sample as opposed to failure within the Al layer in the 100 nm sample.« less

Core-shell Au-Pd nanoparticles as cathode catalysts for microbial fuel cell applications

PubMed Central

Yang, Gaixiu; Chen, Dong; Lv, Pengmei; Kong, Xiaoying; Sun, Yongming; Wang, Zhongming; Yuan, Zhenhong; Liu, Hui; Yang, Jun

2016-01-01

Bimetallic nanoparticles with core-shell structures usually display enhanced catalytic properties due to the lattice strain created between the core and shell regions. In this study, we demonstrate the application of bimetallic Au-Pd nanoparticles with an Au core and a thin Pd shell as cathode catalysts in microbial fuel cells, which represent a promising technology for wastewater treatment, while directly generating electrical energy. In specific, in comparison with the hollow structured Pt nanoparticles, a benchmark for the electrocatalysis, the bimetallic core-shell Au-Pd nanoparticles are found to have superior activity and stability for oxygen reduction reaction in a neutral condition due to the strong electronic interaction and lattice strain effect between the Au core and the Pd shell domains. The maximum power density generated in a membraneless single-chamber microbial fuel cell running on wastewater with core-shell Au-Pd as cathode catalysts is ca. 16.0 W m−3 and remains stable over 150 days, clearly illustrating the potential of core-shell nanostructures in the applications of microbial fuel cells. PMID:27734945

Constituency and origins of cyclic growth layers in pelecypod shells, part 1

NASA Technical Reports Server (NTRS)

Berry, W. B. N.

1972-01-01

Growth layers occurring in shells of 98 species of pelecypods were examined microscopically in thin section and as natural and etched surfaces. Study began with shells of eleven species known from life history investigations to have annual cycles of growth. Internal microstructural features of the annual layers in these shells provided criteria for recognition of similar, apparently annual shell increments in eighty-six of eighty-seven other species. All of the specimens feature growth laminae, commonly on the order of 50 microns in thickness. The specimens from shallow marine environments show either a clustering of growth laminae related to the formation of concentric ridges or minor growth bands on the external shell surface. Based on observations of the number of growth laminae and clusters per annual-growth layer, it was hypothesised that the subannual increments may be related to daily and fortnightly (and in some cases monthly) cycles in the environment. Possible applications of the paleogrowth method in the fields of paleoecology and paleoclimatology are discussed.

Tidal deformation of Enceladus' ice shell with variable thickness and Maxwell rheology

NASA Astrophysics Data System (ADS)

Soucek, Ondrej; Behounkova, Marie; Cadek, Ondrej; Tobie, Gabriel; Choblet, Gael

2017-04-01

Tidal deformation of icy moons has been traditionally studied using the spectral approach which is very efficient for perfectly spherical bodies with radially dependent rheological structure. Measurements of Enceladus' topography (Nimmo et al., 2011) and low-degree gravity (Iess et al., 2014) indicate that the ice shell is significantly thinned in the southern hemisphere (Iess et al., 2014; McKinnon, 2015) and according to recent gravity, shape and libration inversion, it may be only a few kilometers thick at the south pole (Cadek et al., 2016). These variations may potentially have a significant effect on the amplitude and pattern of tidal deformation, stress and associated heating inside the shell, but cannot be straightforwardly incorporated into the existing spectral codes. In order to circumvent this difficulty and to quantify the effects of ice-shell thickness variations, we have developed a three-dimensional finite element code in the framework of FEniCS package (Alnaes et al., 2015). Using this numerical tool, we address the changes in tidally-induced deformation amplitude, stresses and tidal heating for structural models of Enceladus' ice shell of various complexity. Considering Maxwell viscoelastic rheology of the shell, we compare models with uniform thickness consistent with the libration data and with constant viscosity, synthetic models with analytically parameterized thinning in the south polar region and depth-dependent viscosity varying over several orders of magnitude, and finally, models with the shell topography and thickness based on the recent model of Cadek et al. (2016). We find that the thinning of the ice shell around the south pole may lead to amplification of the stress and displacement in this region region by a factor of up to 2 and 4, respectively, depending on the average ice shell thickness, the amplitude of thinning and the viscosity structure. Our results also suggest that lateral variations of ice thickness can induce significant

Bending Boundary Layers in Laminated-Composite Circular Cylindrical Shells

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.; Smeltzer, Stanley S., III

2000-01-01

An analytical, parametric study of the attenuation of bending boundary layers or edge effects in balanced and unbalanced, symmetrically and unsymmetrically laminated thin cylindrical shells is presented for nine contemporary material systems. The analysis is based on the linear Sanders-Koiter shell equations and specializations to the Love-Kirchhoff shell equations and Donnell's equations are included. Two nondimensional parameters are identified that characterize and quantify the effects of laminate orthotropy and laminate anisotropy on the bending boundary-layer decay length in a very general and encompassing manner. A substantial number of structural design technology results are presented for a wide range of laminated-composite cylinders. For all the laminate constructions considered, the results show that the differences between results that were obtained with the Sanders-Koiter shell equations, the Love-Kirchhoff shell equations, and Donnell's equations are negligible. The results also show that the effect of anisotropy in the form of coupling between pure bending and twisting has a negligible effect on the size of the bending boundary-layer decay length of the balanced, symmetrically laminated cylinders considered. Moreover, the results show that coupling between the various types of shell anisotropies has a negligible effect on the calculation of the bending boundary-layer decay length in most cases. The results also show that in some cases neglecting the shell anisotropy results in underestimating the bending boundary-layer decay length and in other cases it results in an overestimation.

Core-shell TiO2@ZnO nanorods for efficient ultraviolet photodetection.

PubMed

Panigrahi, Shrabani; Basak, Durga

2011-05-01

Core-shell TiO(2)@ZnO nanorods (NRs) have been fabricated by a simple two step method: growth of ZnO NRs' array by an aqueous chemical technique and then coating of the NRs with a solution of titanium isopropoxide [Ti(OC(3)H(7))(4)] followed by a heating step to form the shell. The core-shell nanocomposites are composed of single-crystalline ZnO NRs, coated with a thin TiO(2) shell layer obtained by varying the number of coatings (one, three and five times). The ultraviolet (UV) emission intensity of the nanocomposite is largely quenched due to an efficient electron-hole separation reducing the band-to-band recombinations. The UV photoconductivity of the core-shell structure with three times TiO(2) coating has been largely enhanced due to photoelectron transfer between the core and the shell. The UV photosensitivity of the nanocomposite becomes four times larger while the photocurrent decay during steady UV illumination has been decreased almost by 7 times compared to the as-grown ZnO NRs indicating high efficiency of these core-shell structures as UV sensors. © The Royal Society of Chemistry 2011

Core-shell TiO2@ZnO nanorods for efficient ultraviolet photodetection

NASA Astrophysics Data System (ADS)

Panigrahi, Shrabani; Basak, Durga

2011-05-01

Core-shell TiO2@ZnO nanorods (NRs) have been fabricated by a simple two step method: growth of ZnO NRs' array by an aqueous chemical technique and then coating of the NRs with a solution of titanium isopropoxide [Ti(OC3H7)4] followed by a heating step to form the shell. The core-shell nanocomposites are composed of single-crystalline ZnO NRs, coated with a thin TiO2 shell layer obtained by varying the number of coatings (one, three and five times). The ultraviolet (UV) emission intensity of the nanocomposite is largely quenched due to an efficient electron-hole separation reducing the band-to-band recombinations. The UV photoconductivity of the core-shell structure with three times TiO2 coating has been largely enhanced due to photoelectron transfer between the core and the shell. The UV photosensitivity of the nanocomposite becomes four times larger while the photocurrent decay during steady UV illumination has been decreased almost by 7 times compared to the as-grown ZnO NRs indicating high efficiency of these core-shell structures as UV sensors.

Sound Transmission through Cylindrical Shell Structures Excited by Boundary Layer Pressure Fluctuations

NASA Technical Reports Server (NTRS)

Tang, Yvette Y.; Silcox, Richard J.; Robinson, Jay H.

1996-01-01

This paper examines sound transmission into two concentric cylindrical sandwich shells subject to turbulent flow on the exterior surface of the outer shell. The interior of the shells is filled with fluid medium and there is an airgap between the shells in the annular space. The description of the pressure field is based on the cross-spectral density formulation of Corcos, Maestrello, and Efimtsov models of the turbulent boundary layer. The classical thin shell theory and the first-order shear deformation theory are applied for the inner and outer shells, respectively. Modal expansion and the Galerkin approach are used to obtain closed-form solutions for the shell displacements and the radiation and transmission pressures in the cavities including both the annular space and the interior. The average spectral density of the structural responses and the transmitted interior pressures are expressed explicitly in terms of the summation of the cross-spectral density of generalized force induced by the boundary layer turbulence. The effects of acoustic and hydrodynamic coincidences on the spectral density are observed. Numerical examples are presented to illustrate the method for both subsonic and supersonic flows.

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Velikovich, A. L.; Schmit, P. F.

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

DOE PAGES

Velikovich, A. L.; Schmit, P. F.

2015-12-28

Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

Large-area super-resolution optical imaging by using core-shell microfibers

NASA Astrophysics Data System (ADS)

Liu, Cheng-Yang; Lo, Wei-Chieh

2017-09-01

We first numerically and experimentally report large-area super-resolution optical imaging achieved by using core-shell microfibers. The particular spatial electromagnetic waves for different core-shell microfibers are studied by using finite-difference time-domain and ray tracing calculations. The focusing properties of photonic nanojets are evaluated in terms of intensity profile and full width at half-maximum along propagation and transversal directions. In experiment, the general optical fiber is chemically etched down to 6 μm diameter and coated with different metallic thin films by using glancing angle deposition. The direct imaging of photonic nanojets for different core-shell microfibers is performed with a scanning optical microscope system. We show that the intensity distribution of a photonic nanojet is highly related to the metallic shell due to the surface plasmon polaritons. Furthermore, large-area super-resolution optical imaging is performed by using different core-shell microfibers placed over the nano-scale grating with 150 nm line width. The core-shell microfiber-assisted imaging is achieved with super-resolution and hundreds of times the field-of-view in contrast to microspheres. The possible applications of these core-shell optical microfibers include real-time large-area micro-fluidics and nano-structure inspections.

Effect of Ice-Shell Thickness Variations on the Tidal Deformation of Enceladus

NASA Astrophysics Data System (ADS)

Choblet, G.; Cadek, O.; Behounkova, M.; Tobie, G.; Kozubek, T.

2015-12-01

Recent analysis of Enceladus's gravity and topography has suggested that the thickness of the ice shell significantly varies laterally - from 30-40 km in the south polar region to 60 km elsewhere. These variations may influence the activity of the geysers and increase the tidal heat production in regions where the ice shell is thinned. Using a model including a regional or global subsurface ocean and Maxwell viscoelasticity, we investigate the impact of these variations on the tidal deformation of the moon and its heat production. For that purpose, we use different numerical approaches - finite elements, local application of 1d spectral method, and a generalized spectral method. Results obtained with these three approaches for various models of ice-shell thickness variations are presented and compared. Implications of a reduced ice shell thickness for the south polar terrain activity are discussed.

On the origin of the extended infrared shell around NGC 6888

NASA Astrophysics Data System (ADS)

Lozinskaya, T. A.; Pravdikova, V. V.; Gosachinskij, I. V.; Trushkin, S. A.

1997-06-01

The results of a program of research on the extended infrared shell around the nebula NGC 6888 and the star WR 136 are presented. We performed H-alpha observations with a Fabry-Perot interferometer mounted at the focus of a 125-cm telescope and radio continuum (2.7 to 31 cm) and 21-cm HI observations with the RATAN-600 radio telescope. A thick expanding shell of neutral hydrogen 120 pc in diameter that immediately surrounds the extended infrared shell was detected. This suggests that the infrared shell is a single structure rather than a projection of physically unrelated objects. The radial velocity of the HI shell is 11 +/- 1 km/s, the expansion velocity is 10 +/- 3 km/s, and the mass of the neutral hydrogen in the shell is 10 exp 4 solar masses. The bright radio features that we detected in the region of the infrared shell all exhibit a flat spectmm typical of thermal emission from optically thin HII regions. The same inference is probably also true for the nebula Simeiz 55. Our observations are consistent with the assumption of Marston that the extended shell was formed by the stellar wind from the precursor of WR 136, but they do not rule out the identification with a very old supernova remnant proposed by Nichols-Bohlin and Fesen.

Non-tenera Contamination and the Economic Impact of SHELL Genetic Testing in the Malaysian Independent Oil Palm Industry.

PubMed

Ooi, Leslie C-L; Low, Eng-Ti L; Abdullah, Meilina O; Nookiah, Rajanaidu; Ting, Ngoot C; Nagappan, Jayanthi; Manaf, Mohamad A A; Chan, Kuang-Lim; Halim, Mohd A; Azizi, Norazah; Omar, Wahid; Murad, Abdul J; Lakey, Nathan; Ordway, Jared M; Favello, Anthony; Budiman, Muhammad A; Van Brunt, Andrew; Beil, Melissa; Leininger, Michael T; Jiang, Nan; Smith, Steven W; Brown, Clyde R; Kuek, Alex C S; Bahrain, Shabani; Hoynes-O'Connor, Allison; Nguyen, Amelia Y; Chaudhari, Hemangi G; Shah, Shivam A; Choo, Yuen-May; Sambanthamurthi, Ravigadevi; Singh, Rajinder

2016-01-01

Oil palm (Elaeis guineensis) is the most productive oil bearing crop worldwide. It has three fruit forms, namely dura (thick-shelled), pisifera (shell-less) and tenera (thin-shelled), which are controlled by the SHELL gene. The fruit forms exhibit monogenic co-dominant inheritance, where tenera is a hybrid obtained by crossing maternal dura and paternal pisifera palms. Commercial palm oil production is based on planting thin-shelled tenera palms, which typically yield 30% more oil than dura palms, while pisifera palms are female-sterile and have little to no palm oil yield. It is clear that tenera hybrids produce more oil than either parent due to single gene heterosis. The unintentional planting of dura or pisifera palms reduces overall yield and impacts land utilization that would otherwise be devoted to more productive tenera palms. Here, we identify three additional novel mutant alleles of the SHELL gene, which encode a type II MADS-box transcription factor, and determine oil yield via control of shell fruit form phenotype in a manner similar to two previously identified mutant SHELL alleles. Assays encompassing all five mutations account for all dura and pisifera palms analyzed. By assaying for these variants in 10,224 mature palms or seedlings, we report the first large scale accurate genotype-based determination of the fruit forms in independent oil palm planting sites and in the nurseries that supply them throughout Malaysia. The measured non-tenera contamination rate (10.9% overall on a weighted average basis) underscores the importance of SHELL genetic testing of seedlings prior to planting in production fields. By eliminating non-tenera contamination, comprehensive SHELL genetic testing can improve sustainability by increasing yield on existing planted lands. In addition, economic modeling demonstrates that SHELL gene testing will confer substantial annual economic gains to the oil palm industry, to Malaysian gross national income and to Malaysian

Sound radiation modes of cylindrical surfaces and their application to vibro-acoustics analysis of cylindrical shells

NASA Astrophysics Data System (ADS)

Sun, Yao; Yang, Tiejun; Chen, Yuehua

2018-06-01

In this paper, sound radiation modes of baffled cylinders have been derived by constructing the radiation resistance matrix analytically. By examining the characteristics of sound radiation modes, it is found that radiation coefficient of each radiation mode increases gradually with the increase of frequency while modal shapes of sound radiation modes of cylindrical shells show a weak dependence upon frequency. Based on understandings on sound radiation modes, vibro-acoustics behaviors of cylindrical shells have been analyzed. The vibration responses of cylindrical shells are described by modified Fourier series expansions and solved by Rayleigh-Ritz method involving Flügge shell theory. Then radiation efficiency of a resonance has been determined by examining whether the vibration pattern is in correspondence with a sound radiation mode possessing great radiation efficiency. Furthermore, effects of thickness and boundary conditions on sound radiation of cylindrical shells have been investigated. It is found that radiation efficiency of thicker shells is greater than thinner shells while shells with a clamped boundary constraint radiate sound more efficiently than simply supported shells under thin shell assumption.

Structure of Enceladus' Ice Shell

NASA Astrophysics Data System (ADS)

Hemingway, D.

2016-12-01

Constraining the internal structure of Enceladus is essential for understanding its evolution, its highly active south polar region, and its prospects for habitability. Of particular interest is the thickness of the icy shell, which has implications for the thermal structure, the effects of tidal stresses, and the conduits feeding the jets and plume. Since Enceladus' low order gravity field was first measured [1], several studies of shape and gravity have suggested the presence of an internal ocean beneath the icy shell [1-3]. These analyses, however, involve several assumptions and approximations and yield distinct shell thickness estimates (ranging from 18-60 km), only some of which are compatible with estimates from the measured physical librations (15-25 km [4,5]). Part of the challenge is that standard approaches to interior modeling (e.g., Radau-Darwin) are not well suited to Enceladus due to its fast rotation and relatively large non-hydrostatic topography [2,6]. Because of Enceladus' small radius, results are also sensitive to the details of the compensation model [7,8]. Here we apply an analytical compensation model that accommodates the spherical geometry in a manner that is distinct from previous studies, and employ a high fidelity numerical approach to modeling the hydrostatic equilibrium figure [6]. We show that the resulting shell thickness estimates are smaller than in previous models—in agreement with the libration observations—suggesting the possibility of an extremely thin ice crust at the south pole. While a range of mean shell thicknesses are permitted within the observational constraints, the amplitude of lateral shell thickness variations is well constrained. In particular, the shell is 10 km thicker at the north pole than at the south pole, potentially helping to explain the nature of the north-south polar asymmetry in endogenic activity. 1. Iess et al., Science. 344, 78-80 (2014). 2. McKinnon, Geophys. Res. Lett.42 (2015). 3. Cadek et al

Study of the effect of varying core diameter, shell thickness and strain velocity on the tensile properties of single crystals of Cu-Ag core-shell nanowire using molecular dynamics simulations

NASA Astrophysics Data System (ADS)

Sarkar, Jit; Das, D. K.

2018-01-01

Core-shell type nanostructures show exceptional properties due to their unique structure having a central solid core of one type and an outer thin shell of another type which draw immense attention among researchers. In this study, molecular dynamics simulations are carried out on single crystals of copper-silver core-shell nanowires having wire diameter ranging from 9 to 30 nm with varying core diameter, shell thickness, and strain velocity. The tensile properties like yield strength, ultimate tensile strength, and Young's modulus are studied and correlated by varying one parameter at a time and keeping the other two parameters constant. The results obtained for a fixed wire size and different strain velocities were extrapolated to calculate the tensile properties like yield strength and Young's modulus at standard strain rate of 1 mm/min. The results show ultra-high tensile properties of copper-silver core-shell nanowires, several times than that of bulk copper and silver. These copper-silver core-shell nanowires can be used as a reinforcing agent in bulk metal matrix for developing ultra-high strength nanocomposites.

Nonlinear theory for laminated and thick plates and shells including the effects of transverse shearing

NASA Technical Reports Server (NTRS)

Stein, M.

1985-01-01

Nonlinear strain displacement relations for three-dimensional elasticity are determined in orthogonal curvilinear coordinates. To develop a two-dimensional theory, the displacements are expressed by trigonometric series representation through-the-thickness. The nonlinear strain-displacement relations are expanded into series which contain all first and second degree terms. In the series for the displacements only the first few terms are retained. Insertion of the expansions into the three-dimensional virtual work expression leads to nonlinear equations of equilibrium for laminated and thick plates and shells that include the effects of transverse shearing. Equations of equilibrium and buckling equations are derived for flat plates and cylindrical shells. The shell equations reduce to conventional transverse shearing shell equations when the effects of the trigonometric terms are omitted and to classical shell equations when the trigonometric terms are omitted and the shell is assumed to be thin.

Mechanical Behavior of Al-SiC Nanolaminate Composites Using Micro-Scale Testing Methods

NASA Astrophysics Data System (ADS)

Mayer, Carl Randolph

Nanolaminate composite materials consist of alternating layers of materials at the nanoscale (≤100 nm). Due to the nanometer scale thickness of their layers, these materials display unique and tailorable properties. This enables us to alter both mechanical attributes such as strength and wear properties, as well as functional characteristics such as biocompatibility, optical, and electronic properties. This dissertation focuses on understanding the mechanical behavior of the Al-SiC system. From a practical perspective, these materials exhibit a combination of high toughness and strength which is attractive for many applications. Scientifically, these materials are interesting due to the large elastic modulus mismatch between the layers. This, paired with the small layer thickness, allows a unique opportunity for scientists to study the plastic deformation of metals under extreme amounts of constraint. Previous studies are limited in scope and a more diverse range of mechanical characterization is required to understand both the advantages and limitations of these materials. One of the major challenges with testing these materials is that they are only able to be made in thicknesses on the order of micrometers so the testing methods are limited to small volume techniques. This work makes use of both microscale testing techniques from the literature as well as novel methodologies. Using these techniques we are able to gain insight into aspects of the material's mechanical behavior such as the effects of layer orientation, flaw dependent fracture, tension-compression asymmetry, fracture toughness as a function of layer thickness, and shear behavior as a function of layer thickness.

Stress-strain state on non-thin plates and shells. Generalized theory (survey)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nemish, Yu.N.; Khoma, I.Yu.

1994-05-01

In the first part of this survey, we examined exact and approximate analytic solutions of specific problems for thick shells and plates obtained on the basis of three-dimensional equations of the mathematical theory of elasticity. The second part of the survey, presented here, is devoted to systematization and analysis of studies made in regard to a generalized theory of plates and shells based on expansion of the sought functions into Fourier series in Legendre polynomials of the thickness coordinate. Methods are described for constructing systems of differential equations in the coefficients of the expansions (as functions of two independent variablesmore » and time), along with the corresponding boundary and initial conditions. Matters relating to substantiation of the given approach and its generalizations are also discussed.« less

Nano-engineering of three-dimensional core/shell nanotube arrays for high performance supercapacitors

NASA Astrophysics Data System (ADS)

Grote, Fabian; Wen, Liaoyong; Lei, Yong

2014-06-01

Large-scale arrays of core/shell nanostructures are highly desirable to enhance the performance of supercapacitors. Here we demonstrate an innovative template-based fabrication technique with high structural controllability, which is capable of synthesizing well-ordered three-dimensional arrays of SnO2/MnO2 core/shell nanotubes for electrochemical energy storage in supercapacitor applications. The SnO2 core is fabricated by atomic layer deposition and provides a highly electrical conductive matrix. Subsequently a thin MnO2 shell is coated by electrochemical deposition onto the SnO2 core, which guarantees a short ion diffusion length within the shell. The core/shell structure shows an excellent electrochemical performance with a high specific capacitance of 910 F g-1 at 1 A g-1 and a good rate capability of remaining 217 F g-1 at 50 A g-1. These results shall pave the way to realize aqueous based asymmetric supercapacitors with high specific power and high specific energy.

Alignment System for Full-Shell Replicated X-Ray Mirrors

NASA Technical Reports Server (NTRS)

Gubarev, Mikhail; Arnold, William; Ramsey, Brian

2009-01-01

We are developing grazing-incidence x-ray optics for high-energy astrophysical applications using the electroformnickel replication process. For space-based applications these optics must be light-weight yet stable, which dictates the use of very-thin-walled full-shell mirrors. Such shells have been fabricated with resolution as good as 11 arcsec for hard x-rays, and technology enhancements under development at MSFC are aimed at producing mirrors with resolution better than 10 arcsec. The challenge, however, is to preserve this resolution during mounting and assembly. We present here a status report on a mounting and alignment system currently under development at Marshall Space Flight Center designed to meet this challenge.

Hierarchic plate and shell models based on p-extension

NASA Technical Reports Server (NTRS)

Szabo, Barna A.; Sahrmann, Glenn J.

1988-01-01

Formulations of finite element models for beams, arches, plates and shells based on the principle of virtual work was studied. The focus is on computer implementation of hierarchic sequences of finite element models suitable for numerical solution of a large variety of practical problems which may concurrently contain thin and thick plates and shells, stiffeners, and regions where three dimensional representation is required. The approximate solutions corresponding to the hierarchic sequence of models converge to the exact solution of the fully three dimensional model. The stopping criterion is based on: (1) estimation of the relative error in energy norm; (2) equilibrium tests, and (3) observation of the convergence of quantities of interest.

Non-isothermal buckling behavior of viscoplastic shell structures

NASA Technical Reports Server (NTRS)

Riff, Richard; Simitses, G. J.

1988-01-01

Described are the mathematical model and solution methodologies for analyzing the structural response of thin, metallic elasto-viscoplastic shell structures under large thermomechanical loads and their non-isothermal buckling behavior. Among the system responses associated with these loads and conditions are snap-through, buckling, thermal buckling, and creep buckling. This geometric and material nonlinearities (of high order) can be anticipated and are considered in the model and the numerical treatment.

Design and Fabrication of a Ring-Stiffened Graphite-Epoxy Corrugated Cylindrical Shell

NASA Technical Reports Server (NTRS)

Johnson, R., Jr.

1978-01-01

Design and fabrication of supplement test panels that represent key portions of the cylinder are described, as are supporting tests of coupons, sample joints, and stiffening ring elements. The cylindrical shell is a ring-stiffened, open corrugation design that uses T300/5208 graphite-epoxy tape as the basic material for the shell wall and stiffening rings. The test cylinder is designed to withstand bending loads producing the relatively low maximum load intensity in the shell wall of 1,576 N/cm. The resulting shell wall weight, including stiffening rings and fasteners, is 0.0156 kg/m. The shell weight achieved in the graphite-epoxy cylinder represents a weight saving of approximately 23 percent, compared to a comparable aluminum shell. A unique fabrication approach was used in which the cylinder wall was built in three flat segments, which were then wrapped to the cylindrical shape. Such an approach, made possible by the flexibility of the thin corrugated wall in a radial direction, proved to be a simple approach to building the test cylinder. Based on tooling and fabrication methods in this program, the projected costs of a production run of 100 units are reported.

Initial formation of calcite crystals in the thin prismatic layer with the periostracum of Pinctada fucata.

PubMed

Suzuki, Michio; Nakayama, Seiji; Nagasawa, Hiromichi; Kogure, Toshihiro

2013-02-01

Although the formation mechanism of calcite crystals in the prismatic layer has been studied well in many previous works, the initial state of calcite formation has not been observed in detail using electron microscopes. In this study, we report that the soft prismatic layer with transparent color (the thin prismatic layer) in the tip of the fresh shell of Pinctada fucata was picked up to observe the early calcification phase. A scanning electron microscope (SEM) image showed that the growth tip of the thin prismatic layer was covered by the periostracum, which was also where the initial formation of calcite crystals began. A cross-section containing the thin calcite crystals in the thin prismatic layer with the periostracum was made using a focused ion beam (FIB) system. In a transmission electron microscope (TEM) observation, the thin calcite crystal (thickness is about 1μm) on the periostracum was found to be a single crystal with the c-axis oriented perpendicular to the shell surface. On the other hand, many aggregated small particles consisting of bassanite crystals were observed in the periostracum suggesting the possibility that not only organic sulfate but also inorganic sulfates exist in the prismatic layer. These discoveries in the early calcification phase of the thin prismatic layer may help to clarify the mechanism of regulating the nucleation and orientation of the calcite crystal in the shell. Copyright © 2012 Elsevier Ltd. All rights reserved.

Lipids from the nacreous and prismatic layers of two Pteriomorpha Mollusc shells

NASA Astrophysics Data System (ADS)

Farre, B.; Dauphin, Y.

2009-04-01

, abundance and composition of these components in Mollusc shells. Goulletquer and Wolowicz (1989) have estimated that proteins represent 90% of the organic matrix of the shell, carbohydrates vary from 0.15 to 0.29%, while lipids vary from 0.8 to 2.9%. Fatty acids, cholesterol, phytadienes and ketones have been described in modern and fossil shells (Cobabe and Pratt, 1995). Using a procedure to extract intra- and intercrystalline organic matrices, Collins et al. (1995) have detected n-alkanes, n-alcohols, fatty acids and sterols in modern shells. It is suggested that the contents and ratios of these components are dependant on the environment and phylogeny. Lipids of the nacreous layer of Pinctada are diverse, with cholesterol, fatty acids, triglycerides and other unknown components (Rousseau et al., 2006). It has been established that the main part of the soluble organic matrices of the nacreous layer is composed of acidic proteins (Samata, 1988, 1990), whereas the prismatic layer of Pinna is mainly composed of acidic and sulphated polysaccharides (Dauphin, 2002; Dauphin et al., 2003). The amino acid compositions of the two layers are also different (Samata, 1990). Because the organic matrices extracted from the aragonite nacre and calcite prisms are the best known materials, the lipids extracted from the calcite prisms of Pinna nobilis and Pinctada margaritifera and the aragonite nacre of P. margaritifera have been chosen as test material for characterisation of the lipid fraction of molusk shells. The nacreous layer of Pinctada is thick,whereas its prismatic layer is thin, and the prisms display complex structures. On the opposite, the calcitic prismatic layer of Pinna is thick, with no intraprismatic membranes, and its nacreous layer is thin and present only in the oldest part of the shell. Moreover, these layers have a simple geometry so that some organic components (membranes, wall…) said to be insoluble, are clearly visible. Lipids were extracted from the calcite

A contact algorithm for shell problems via Delaunay-based meshing of the contact domain

NASA Astrophysics Data System (ADS)

Kamran, K.; Rossi, R.; Oñate, E.

2013-07-01

The simulation of the contact within shells, with all of its different facets, represents still an open challenge in Computational Mechanics. Despite the effort spent in the development of techniques for the simulation of general contact problems, an all-seasons algorithm applicable to complex shell contact problems is yet to be developed. This work focuses on the solution of the contact between thin shells by using a technique derived from the particle finite element method together with a rotation-free shell triangle. The key concept is to define a discretization of the contact domain (CD) by constructing a finite element mesh of four-noded tetrahedra that describes the potential contact volume. The problem is completed by using an assumed-strain approach to define an elastic contact strain over the CD.

Parametric instability analysis of truncated conical shells using the Haar wavelet method

NASA Astrophysics Data System (ADS)

Dai, Qiyi; Cao, Qingjie

2018-05-01

In this paper, the Haar wavelet method is employed to analyze the parametric instability of truncated conical shells under static and time dependent periodic axial loads. The present work is based on the Love first-approximation theory for classical thin shells. The displacement field is expressed as the Haar wavelet series in the axial direction and trigonometric functions in the circumferential direction. Then the partial differential equations are reduced into a system of coupled Mathieu-type ordinary differential equations describing dynamic instability behavior of the shell. Using Bolotin's method, the first-order and second-order approximations of principal instability regions are determined. The correctness of present method is examined by comparing the results with those in the literature and very good agreement is observed. The difference between the first-order and second-order approximations of principal instability regions for tensile and compressive loads is also investigated. Finally, numerical results are presented to bring out the influences of various parameters like static load factors, boundary conditions and shell geometrical characteristics on the domains of parametric instability of conical shells.

Thin Shell, Segmented X-Ray Mirrors

NASA Technical Reports Server (NTRS)

Petre, Robert

2010-01-01

Thin foil mirrors were introduced as a means of achieving high throughput in an X-ray astronomical imaging system in applications for which high angular resolution were not necessary. Since their introduction, their high filling factor, modest mass, relative ease of construction, and modest cost have led to their use in numerous X-ray observatories, including the Broad Band X-ray Telescope, ASCA, and Suzaku. The introduction of key innovations, including epoxy replicated surfaces, multilayer coatings, and glass mirror substrates, has led to performance improvements, and in their becoming widely used for X-ray astronomical imaging at energies above 10 keV. The use of glass substrates has also led to substantial improvement in angular resolution, and thus their incorporation into the NASA concept for the International X-ray Observatory with a planned 3 in diameter aperture. This paper traces the development of foil mirrors from their inception in the 1970's through their current and anticipated future applications.

NASTRAN implementation of an isoparametric doubly-curved quadrilateral shell element

NASA Technical Reports Server (NTRS)

Potvin, A. B.; Leick, R. D.

1978-01-01

A quadrilateral shell element, CQUAD4, was added to level 15.5 and subsequently to level 16.0 of NASTRAN. The element exhibited doubly curved surfaces and used biquadratic interpolation functions. Reduced integration techniques were used to improve the performance of the element in thin shell problems. The creation of several new bulk data items is discussed, along with a special module, GPNORM, to process SHLNORM bulk data cards. In addition to the theoretical basis for the element stiffness matrix, consistent mass and load matrices are presented. Several potential sources of degenerate behavior of the element were investigated. Guidelines for proper use of the element were suggested. Performance of the element on several widely published classical examples was demonstrated. The results showed a significant improvement over presently available NASTRAN shell elements for even the coarsest meshes. Potential applications to two classes of practical problems are discussed.

Ocean-driven heating of Europa's icy shell at low latitudes

NASA Astrophysics Data System (ADS)

Soderlund, K. M.; Schmidt, B. E.; Wicht, J.; Blankenship, D. D.

2014-01-01

The ice shell of Jupiter's moon Europa is marked by regions of disrupted ice known as chaos terrains that cover up to 40% of the satellite's surface, most commonly occurring within 40° of the equator. Concurrence with salt deposits implies a coupling between the geologically active ice shell and the underlying liquid water ocean at lower latitudes. Europa's ocean dynamics have been assumed to adopt a two-dimensional pattern, which channels the moon's internal heat to higher latitudes. Here we present a numerical model of thermal convection in a thin, rotating spherical shell where small-scale convection instead adopts a three-dimensional structure and is more vigorous at lower latitudes. Global-scale currents are organized into three zonal jets and two equatorial Hadley-like circulation cells. We find that these convective motions transmit Europa's internal heat towards the surface most effectively in equatorial regions, where they can directly influence the thermo-compositional state and structure of the ice shell. We suggest that such heterogeneous heating promotes the formation of chaos features through increased melting of the ice shell and subsequent deposition of marine ice at low latitudes. We conclude that Europa's ocean dynamics can modulate the exchange of heat and materials between the surface and interior and explain the observed distribution of chaos terrains.

Geometrically controlled snapping transitions in shells with curved creases.

PubMed

Bende, Nakul Prabhakar; Evans, Arthur A; Innes-Gold, Sarah; Marin, Luis A; Cohen, Itai; Hayward, Ryan C; Santangelo, Christian D

2015-09-08

Curvature and mechanics are intimately connected for thin materials, and this coupling between geometry and physical properties is readily seen in folded structures from intestinal villi and pollen grains to wrinkled membranes and programmable metamaterials. While the well-known rules and mechanisms behind folding a flat surface have been used to create deployable structures and shape transformable materials, folding of curved shells is still not fundamentally understood. Shells naturally deform by simultaneously bending and stretching, and while this coupling gives them great stability for engineering applications, it makes folding a surface of arbitrary curvature a nontrivial task. Here we discuss the geometry of folding a creased shell, and demonstrate theoretically the conditions under which it may fold smoothly. When these conditions are violated we show, using experiments and simulations, that shells undergo rapid snapping motion to fold from one stable configuration to another. Although material asymmetry is a proven mechanism for creating this bifurcation of stability, for the case of a creased shell, the inherent geometry itself serves as a barrier to folding. We discuss here how two fundamental geometric concepts, creases and curvature, combine to allow rapid transitions from one stable state to another. Independent of material system and length scale, the design rule that we introduce here explains how to generate snapping transitions in arbitrary surfaces, thus facilitating the creation of programmable multistable materials with fast actuation capabilities.

Applicability of the Continuum-Shell Theories to the Mechanics of Carbon Nanotubes

NASA Technical Reports Server (NTRS)

Harik, V. M.; Gates, T. S.; Nemeth, M. P.

2002-01-01

Validity of the assumptions relating the applicability of continuum shell theories to the global mechanical behavior of carbon nanotubes is examined. The present study focuses on providing a basis that can be used to qualitatively assess the appropriateness of continuum-shell models for nanotubes. To address the effect of nanotube structure on their deformation, all nanotube geometries are divided into four major classes that require distinct models. Criteria for the applicability of continuum models are presented. The key parameters that control the buckling strains and deformation modes of these classes of nanotubes are determined. In an analogy with continuum mechanics, mechanical laws of geometric similitude are presented. A parametric map is constructed for a variety of nanotube geometries as a guide for the applicability of different models. The continuum assumptions made in representing a nanotube as a homogeneous thin shell are analyzed to identify possible limitations of applying shell theories and using their bifurcation-buckling equations at the nano-scale.

NIF Double Shell outer/inner shell collision experiments

NASA Astrophysics Data System (ADS)

Merritt, E. C.; Loomis, E. N.; Wilson, D. C.; Cardenas, T.; Montgomery, D. S.; Daughton, W. S.; Dodd, E. S.; Desjardins, T.; Renner, D. B.; Palaniyappan, S.; Batha, S. H.; Khan, S. F.; Smalyuk, V.; Ping, Y.; Amendt, P.; Schoff, M.; Hoppe, M.

2017-10-01

Double shell capsules are a potential low convergence path to substantial alpha-heating and ignition on NIF, since they are predicted to ignite and burn at relatively low temperatures via volume ignition. Current LANL NIF double shell designs consist of a low-Z ablator, low-density foam cushion, and high-Z inner shell with liquid DT fill. Central to the Double Shell concept is kinetic energy transfer from the outer to inner shell via collision. The collision determines maximum energy available for compression and implosion shape of the fuel. We present results of a NIF shape-transfer study: two experiments comparing shape and trajectory of the outer and inner shells at post-collision times. An outer-shell-only target shot measured the no-impact shell conditions, while an `imaging' double shell shot measured shell conditions with impact. The `imaging' target uses a low-Z inner shell and is designed to perform in similar collision physics space to a high-Z double shell but can be radiographed at 16keV, near the viable 2DConA BL energy limit. Work conducted under the auspices of the U.S. DOE by LANL under contract DE-AC52-06NA25396.

Non-tenera Contamination and the Economic Impact of SHELL Genetic Testing in the Malaysian Independent Oil Palm Industry

PubMed Central

Ooi, Leslie C.-L.; Low, Eng-Ti L.; Abdullah, Meilina O.; Nookiah, Rajanaidu; Ting, Ngoot C.; Nagappan, Jayanthi; Manaf, Mohamad A. A.; Chan, Kuang-Lim; Halim, Mohd A.; Azizi, Norazah; Omar, Wahid; Murad, Abdul J.; Lakey, Nathan; Ordway, Jared M.; Favello, Anthony; Budiman, Muhammad A.; Van Brunt, Andrew; Beil, Melissa; Leininger, Michael T.; Jiang, Nan; Smith, Steven W.; Brown, Clyde R.; Kuek, Alex C. S.; Bahrain, Shabani; Hoynes-O’Connor, Allison; Nguyen, Amelia Y.; Chaudhari, Hemangi G.; Shah, Shivam A.; Choo, Yuen-May; Sambanthamurthi, Ravigadevi; Singh, Rajinder

2016-01-01

Oil palm (Elaeis guineensis) is the most productive oil bearing crop worldwide. It has three fruit forms, namely dura (thick-shelled), pisifera (shell-less) and tenera (thin-shelled), which are controlled by the SHELL gene. The fruit forms exhibit monogenic co-dominant inheritance, where tenera is a hybrid obtained by crossing maternal dura and paternal pisifera palms. Commercial palm oil production is based on planting thin-shelled tenera palms, which typically yield 30% more oil than dura palms, while pisifera palms are female-sterile and have little to no palm oil yield. It is clear that tenera hybrids produce more oil than either parent due to single gene heterosis. The unintentional planting of dura or pisifera palms reduces overall yield and impacts land utilization that would otherwise be devoted to more productive tenera palms. Here, we identify three additional novel mutant alleles of the SHELL gene, which encode a type II MADS-box transcription factor, and determine oil yield via control of shell fruit form phenotype in a manner similar to two previously identified mutant SHELL alleles. Assays encompassing all five mutations account for all dura and pisifera palms analyzed. By assaying for these variants in 10,224 mature palms or seedlings, we report the first large scale accurate genotype-based determination of the fruit forms in independent oil palm planting sites and in the nurseries that supply them throughout Malaysia. The measured non-tenera contamination rate (10.9% overall on a weighted average basis) underscores the importance of SHELL genetic testing of seedlings prior to planting in production fields. By eliminating non-tenera contamination, comprehensive SHELL genetic testing can improve sustainability by increasing yield on existing planted lands. In addition, economic modeling demonstrates that SHELL gene testing will confer substantial annual economic gains to the oil palm industry, to Malaysian gross national income and to Malaysian

A comparative study of heterostructured CuO/CuWO4 nanowires and thin films

NASA Astrophysics Data System (ADS)

Polyakov, Boris; Kuzmin, Alexei; Vlassov, Sergei; Butanovs, Edgars; Zideluns, Janis; Butikova, Jelena; Kalendarev, Robert; Zubkins, Martins

2017-12-01

A comparative study of heterostructured CuO/CuWO4 core/shell nanowires and double-layer thin films was performed through X-ray diffraction, confocal micro-Raman spectroscopy and electron (SEM and TEM) microscopies. The heterostructures were produced using a two-step process, starting from a deposition of amorphous WO3 layer on top of CuO nanowires and thin films by reactive DC magnetron sputtering and followed by annealing at 650 °C in air. The second step induced a solid-state reaction between CuO and WO3 oxides through a thermal diffusion process, revealed by SEM-EDX analysis. Morphology evolution of core/shell nanowires and double-layer thin films upon heating was studied by electron (SEM and TEM) microscopies. A formation of CuWO4 phase was confirmed by X-ray diffraction and confocal micro-Raman spectroscopy.

Shell thinning and pesticide residues in Texas aquatic bird eggs, 1970

USGS Publications Warehouse

King, K.A.; Flickinger, Edward L.; Hildebrand, H.H.

1978-01-01

Significant decreases in eggshell thickness were found in 15 of 22 species of aquatic birds in Texas in 1970. Shell thickness reductions of 9 to 15 percent were found in white pelicans (Pelecanus erythrorhynchos), brown pelicans (P .occidentalis), and great blue herons (Ardea herodias). DDT family compounds were found in all eggs, and mean residues ranged from 0.4 ppm in white ibis (Eudocimus albus) to 23.2 ppm in great egrets (Casmerodius albus). GDDT residues were negatively correlated with shell thickness in five species; PCBs were negatively correlated in two. Residues in marine birds were generally lower and more uniform than levels in birds feeding in fresh and brackish water. DDT and dieldrin residues were higher in eggs from colonies near agricultural areas where these insecticides were heavily used; higher PCB residues were consistently associated with urban and industrial areas. Populations of five species have declined and deserve continued study: brown pelican, reddish egret (Dichromanassa rufescens), white-faced ibis (Plegadis chihi), laughing gull (Larus atricilla), and Forster's tern (Sterna forsteri). Population trends of four other species were undetermined and should be followed closely in future years.

Analytical and experimental studies of natural vibrations modes of ring-stiffened truncated-cone shells with variable theoretical ring fixity

NASA Technical Reports Server (NTRS)

Naumann, E. C.; Catherines, D. S.; Walton, W. C., Jr.

1971-01-01

Experimental and analytical investigations of the vibratory behavior of ring-stiffened truncated-cone shells are described. Vibration tests were conducted on 60 deg conical shells having up to four ring stiffeners and for free-free and clamped-free edge constraints and 9 deg conical shells, for two thicknesses, each with two angle rings and for free-free, free-clamped, and clamped-clamped edge constraints. The analytical method is based on linear thin shell theory, employing the Rayleigh-Ritz method. Discrete rings are represented as composed of one or more segments, each of which is a short truncated-cone shell of uniform thickness. Equations of constraint are used to join a ring and shell along a circumferential line connection. Excellent agreement was obtained for comparisons of experimental and calculated frequencies.

Toward highly stable solid-state unconventional thin-film battery-supercapacitor hybrid devices: Interfacing vertical core-shell array electrodes with a gel polymer electrolyte

NASA Astrophysics Data System (ADS)

Pandey, Gaind P.; Klankowski, Steven A.; Liu, Tao; Wu, Judy; Li, Jun

2017-02-01

A novel solid-state battery-supercapacitor hybrid device is fabricated for high-performance electrical energy storage using a Si anode and a TiO2 cathode in conjunction with a flexible, solid-like gel polymer electrolyte film as the electrolyte and separator. The electrodes were fabricated as three-dimensional nanostructured vertical arrays by sputtering active materials as conformal shells on vertically aligned carbon nanofibers (VACNFs) which serve as the current collector and structural template. Such nanostructured vertical core-shell array-electrodes enable short Li-ion diffusion path and large pseudocapacitive contribution by fast surface reactions, leading to the hybrid features of batteries and supercapacitors that can provide high specific energy over a wide range of power rates. Due to the improved mechanical stability of the infiltrated composite structure, the hybrid cell shows excellent cycling stability and is able to retain more than 95% of the original capacity after 3500 cycles. More importantly, this solid-state device can stably operate in a temperature range from -20 to 60 °C with a very low self-discharge rate and an excellent shelf life. This solid-state architecture is promising for the development of highly stable thin-film hybrid energy storage devices for unconventional applications requiring largely varied power, wider operation temperature, long shelf-life and higher safety standards.

Modeling of nonlinear viscous stress in encapsulating shells of lipid-coated contrast agent microbubbles

PubMed Central

Doinikov, Alexander A.; Haac, Jillian F.; Dayton, Paul A.

2009-01-01

A general theoretical approach to the development of zero-thickness encapsulation models for contrast microbubbles is proposed. The approach describes a procedure that allows one to recast available rheological laws from the bulk form to a surface form which is used in a modified Rayleigh-Plesset equation governing the radial dynamics of a contrast microbubble. By the use of the proposed procedure, the testing of different rheological laws for encapsulation can be carried out. Challenges of existing shell models for lipid-encapsulated microbubbles, such as the dependence of shell parameters on the initial bubble radius and the “compression-only” behavior, are discussed. Analysis of the rheological behavior of lipid encapsulation is made by using experimental radius-time curves for lipid-coated microbubbles with radii in the range 1.2 – 2.5 μm. The curves were acquired for a research phospholipid-coated contrast agent insonified with a 20-cycle, 3.0 MHz, 100 kPa acoustic pulse. The fitting of the experimental data by a model which treats the shell as a viscoelastic solid gives the values of the shell surface viscosity increasing from 0.30×10-8 kg/s to 2.63×10-8 kg/s for the range of bubble radii indicated above. The shell surface elastic modulus increases from 0.054 N/m to 0.37 N/m. It is proposed that this increase may be a result of the lipid coating possessing the properties of both a shear-thinning and a strain-softening material. We hypothesize that these complicated rheological properties do not allow the existing shell models to satisfactorily describe the dynamics of lipid encapsulation. In the existing shell models, the viscous and the elastic shell terms have the linear form which assumes that the viscous and the elastic stresses acting inside the lipid shell are proportional to the shell shear rate and the shell strain, respectively, with constant coefficients of proportionality. The analysis performed in the present paper suggests that a more

Modeling of nonlinear viscous stress in encapsulating shells of lipid-coated contrast agent microbubbles.

PubMed

Doinikov, Alexander A; Haac, Jillian F; Dayton, Paul A

2009-02-01

A general theoretical approach to the development of zero-thickness encapsulation models for contrast microbubbles is proposed. The approach describes a procedure that allows one to recast available rheological laws from the bulk form to a surface form which is used in a modified Rayleigh-Plesset equation governing the radial dynamics of a contrast microbubble. By the use of the proposed procedure, the testing of different rheological laws for encapsulation can be carried out. Challenges of existing shell models for lipid-encapsulated microbubbles, such as the dependence of shell parameters on the initial bubble radius and the "compression-only" behavior, are discussed. Analysis of the rheological behavior of lipid encapsulation is made by using experimental radius-time curves for lipid-coated microbubbles with radii in the range 1.2-2.5 microm. The curves were acquired for a research phospholipid-coated contrast agent insonified with a 20 cycle, 3.0 MHz, 100 kPa acoustic pulse. The fitting of the experimental data by a model which treats the shell as a viscoelastic solid gives the values of the shell surface viscosity increasing from 0.30 x 10(-8) kg/s to 2.63 x 10(-8) kg/s for the range of bubble radii, indicated above. The shell surface elastic modulus increases from 0.054 N/m to 0.37 N/m. It is proposed that this increase may be a result of the lipid coating possessing the properties of both a shear-thinning and a strain-softening material. We hypothesize that these complicated rheological properties do not allow the existing shell models to satisfactorily describe the dynamics of lipid encapsulation. In the existing shell models, the viscous and the elastic shell terms have the linear form which assumes that the viscous and the elastic stresses acting inside the lipid shell are proportional to the shell shear rate and the shell strain, respectively, with constant coefficients of proportionality. The analysis performed in the present paper suggests that a more

Change in Stripes for Cholesteric Shells via Anchoring in Moderation

NASA Astrophysics Data System (ADS)

Tran, Lisa; Lavrentovich, Maxim O.; Durey, Guillaume; Darmon, Alexandre; Haase, Martin F.; Li, Ningwei; Lee, Daeyeon; Stebe, Kathleen J.; Kamien, Randall D.; Lopez-Leon, Teresa

2017-10-01

Chirality, ubiquitous in complex biological systems, can be controlled and quantified in synthetic materials such as cholesteric liquid crystal (CLC) systems. In this work, we study spherical shells of CLC under weak anchoring conditions. We induce anchoring transitions at the inner and outer boundaries using two independent methods: by changing the surfactant concentration or by raising the temperature close to the clearing point. The shell confinement leads to new states and associated surface structures: a state where large stripes on the shell can be filled with smaller, perpendicular substripes, and a focal conic domain (FCD) state, where thin stripes wrap into at least two, topologically required, double spirals. Focusing on the latter state, we use a Landau-de Gennes model of the CLC to simulate its detailed configurations as a function of anchoring strength. By abruptly changing the topological constraints on the shell, we are able to study the interconversion between director defects and pitch defects, a phenomenon usually restricted by the complexity of the cholesteric phase. This work extends the knowledge of cholesteric patterns, structures that not only have potential for use as intricate, self-assembly blueprints but are also pervasive in biological systems.

Stable Tearing and Buckling Responses of Unstiffened Aluminum Shells with Long Cracks

NASA Technical Reports Server (NTRS)

Starnes, James H., Jr.; Rose, Cheryl A.

1999-01-01

The results of an analytical and experimental study of the nonlinear response of thin, unstiffened, aluminum cylindrical shells with a long longitudinal crack are presented. The shells are analyzed with a nonlinear shell analysis code that accurately accounts for global and local structural response phenomena. Results are presented for internal pressure and for axial compression loads. The effect of initial crack length on the initiation of stable crack growth and unstable crack growth in typical shells subjected to internal pressure loads is predicted using geometrically nonlinear elastic-plastic finite element analyses and the crack-tip-opening angle (CTOA) fracture criterion. The results of these analyses and of the experiments indicate that the pressure required to initiate stable crack growth and unstable crack growth in a shell subjected to internal pressure loads decreases as the initial crack length increases. The effects of crack length on the prebuckling, buckling and postbuckling responses of typical shells subjected to axial compression loads are also described. For this loading condition, the crack length was not allowed to increase as the load was increased. The results of the analyses and of the experiments indicate that the initial buckling load and collapse load for a shell subjected to axial compression loads decrease as the initial crack length increases. Initial buckling causes general instability or collapse of a shell for shorter initial crack lengths. Initial buckling is a stable local response mode for longer initial crack lengths. This stable local buckling response is followed by a stable postbuckling response, which is followed by general or overall instability of the shell.

Stable Tearing and Buckling Responses of Unstiffened Aluminum Shells with Long Cracks

NASA Technical Reports Server (NTRS)

Starnes, James H., Jr.; Rose, Cheryl A.

1998-01-01

The results of an analytical and experimental study of the nonlinear response of thin, unstiffened, aluminum cylindrical shells with a long longitudinal crack are presented. The shells are analyzed with a nonlinear shell analysis code that accurately accounts for global and local structural response phenomena. Results are presented for internal pressure and for axial compression loads. The effect of initial crack length on the initiation of stable crack growth and unstable crack growth in typical shells subjected to internal pressure loads is predicted using geometrically nonlinear elastic-plastic finite element analyses and the crack-tip-opening angle (CTOA) fracture criterion. The results of these analyses and of the experiments indicate that the pressure required to initiate stable crack growth and unstable crack growth in a shell subjected to internal pressure loads decreases as the initial crack length increases. The effects of crack length on the prebuckling, buckling and postbuckling responses of typical shells subjected to axial compression loads are also described. For this loading condition, the crack length was not allowed to increase as the load was increased. The results of the analyses and of the experiments indicate that the initial buckling load and collapse load for a shell subjected to axial compression loads decrease as the initial crack length increases. Initial buckling causes general instability or collapse of a shell for shorter initial crack lengths. Initial buckling is a stable local response mode for longer initial crack lengths. This stable local buckling response is followed by a stable postbuckling response, which is followed by general or overall instability of the shell.

Multi-Shell Hollow Nanogels with Responsive Shell Permeability

PubMed Central

Schmid, Andreas J.; Dubbert, Janine; Rudov, Andrey A.; Pedersen, Jan Skov; Lindner, Peter; Karg, Matthias; Potemkin, Igor I.; Richtering, Walter

2016-01-01

We report on hollow shell-shell nanogels with two polymer shells that have different volume phase transition temperatures. By means of small angle neutron scattering (SANS) employing contrast variation and molecular dynamics (MD) simulations we show that hollow shell-shell nanocontainers are ideal systems for controlled drug delivery: The temperature responsive swelling of the inner shell controls the uptake and release, while the thermoresponsive swelling of the outer shell controls the size of the void and the colloidal stability. At temperatures between 32 °C < T < 42 °C, the hollow nanocontainers provide a significant void, which is even larger than the initial core size of the template, and they possess a high colloidal stability due to the steric stabilization of the swollen outer shell. Computer simulations showed, that temperature induced switching of the permeability of the inner shell allows for the encapsulation in and release of molecules from the cavity. PMID:26984478

Nonlinear Local Bending Response and Bulging Factors for Longitudinal and Circumferential Cracks in Pressurized Cylindrical Shells

NASA Technical Reports Server (NTRS)

Young, Richard D.; Rose, Cheryl A.; Starnes, James H., Jr.

2000-01-01

Results of a geometrically nonlinear finite element parametric study to determine curvature correction factors or bulging factors that account for increased stresses due to curvature for longitudinal and circumferential cracks in unstiffened pressurized cylindrical shells are presented. Geometric parameters varied in the study include the shell radius, the shell wall thickness, and the crack length. The major results are presented in the form of contour plots of the bulging factor as a function of two nondimensional parameters: the shell curvature parameter, lambda, which is a function of the shell geometry, Poisson's ratio, and the crack length; and a loading parameter, eta, which is a function of the shell geometry, material properties, and the applied internal pressure. These plots identify the ranges of the shell curvature and loading parameters for which the effects of geometric nonlinearity are significant. Simple empirical expressions for the bulging factor are then derived from the numerical results and shown to predict accurately the nonlinear response of shells with longitudinal and circumferential cracks. The numerical results are also compared with analytical solutions based on linear shallow shell theory for thin shells, and with some other semi-empirical solutions from the literature, and limitations on the use of these other expressions are suggested.

Sound transmission through double cylindrical shells lined with porous material under turbulent boundary layer excitation

NASA Astrophysics Data System (ADS)

Zhou, Jie; Bhaskar, Atul; Zhang, Xin

2015-11-01

This paper investigates sound transmission through double-walled cylindrical shell lined with poroelastic material in the core, excited by pressure fluctuations due to the exterior turbulent boundary layer (TBL). Biot's model is used to describe the sound wave propagating in the porous material. Three types of constructions, bonded-bonded, bonded-unbonded and unbonded-unbonded, are considered in this study. The power spectral density (PSD) of the inner shell kinetic energy is predicted for two turbulent boundary layer models, different air gap depths and three types of polyimide foams, respectively. The peaks of the inner shell kinetic energy due to shell resonance, hydrodynamic coincidence and acoustic coincidence are discussed. The results show that if the frequency band over the ring frequency is of interest, an air gap, even if very thin, should exist between the two elastic shells for better sound insulation. And if small density foam has a high flow resistance, a superior sound insulation can still be maintained.

Stress concentration factors for circular, reinforced penetrations in pressurized cylindrical shells. Ph.D. Thesis - Virginia Univ.

NASA Technical Reports Server (NTRS)

Ramsey, J. W., Jr.

1975-01-01

The effect on stresses in a cylindrical shell with a circular penetration subject to internal pressure was investigated in thin, shallow linearly, elastic cylindrical shells. Results provide numerical predictions of peak stress concentration factors around nonreinforced and reinforced penetrations in pressurized cylindrical shells. Analytical results were correlated with published formulas, as well as theoretical and experimental results. An accuracy study was made of the finite element program for each of the configurations considered important in pressure vessel technology. A formula is developed to predict the peak stress concentration factor for analysis and/or design in conjunction with the ASME Boiler and Pressure Vessel Code.

Phase field modeling of brittle fracture for enhanced assumed strain shells at large deformations: formulation and finite element implementation

NASA Astrophysics Data System (ADS)

Reinoso, J.; Paggi, M.; Linder, C.

2017-06-01

Fracture of technological thin-walled components can notably limit the performance of their corresponding engineering systems. With the aim of achieving reliable fracture predictions of thin structures, this work presents a new phase field model of brittle fracture for large deformation analysis of shells relying on a mixed enhanced assumed strain (EAS) formulation. The kinematic description of the shell body is constructed according to the solid shell concept. This enables the use of fully three-dimensional constitutive models for the material. The proposed phase field formulation integrates the use of the (EAS) method to alleviate locking pathologies, especially Poisson thickness and volumetric locking. This technique is further combined with the assumed natural strain method to efficiently derive a locking-free solid shell element. On the computational side, a fully coupled monolithic framework is consistently formulated. Specific details regarding the corresponding finite element formulation and the main aspects associated with its implementation in the general purpose packages FEAP and ABAQUS are addressed. Finally, the applicability of the current strategy is demonstrated through several numerical examples involving different loading conditions, and including linear and nonlinear hyperelastic constitutive models.

Comparison of thin-film resistance heat-transfer gages with thin-skin transient calorimeter gages in conventional hypersonic wind tunnels

NASA Technical Reports Server (NTRS)

Miller, C. G., III

1981-01-01

Thin film gages deposited at the stagnation region of small (8.1-mm-diameter) hemispheres and gages mounted flush with the surface of a sharp-leading-edge flat plate were tested in the Langley continuous-flow hypersonic tunnel and in the Langley hypersonic CF4 tunnel. Two substrate materials were tested, quartz and a machinable glass-ceramic. Small hemispheres were also tested utilizing the thin-skin transient calorimeter technique usually employed in conventional tunnels. One transient calorimeter model was a thin shell of stainless steel, and the other was a thin-skin insert of stainless steel mounted into a hemisphere fabricated from a machinable-glass-ceramic. Measured heat-transfer rates from the various hemispheres were compared with one another and with predicted rates. The results demonstrate the feasibility and advantages of using-film resistance heat-transfer gages in conventional hypersonic wind tunnels over a wide range of conditions.

The argonaut shell: gas-mediated buoyancy control in a pelagic octopus

PubMed Central

Finn, Julian K.; Norman, Mark D.

2010-01-01

Argonauts (Cephalopoda: Argonautidae) are a group of rarely encountered open-ocean pelagic octopuses with benthic ancestry. Female argonauts inhabit a brittle ‘paper nautilus’ shell, the role of which has puzzled naturalists for millennia. The primary role attributed to the shell has been as a receptacle for egg deposition and brooding. Our observations of wild argonauts have revealed that the thin calcareous shell also functions as a hydrostatic structure, employed by the female argonaut to precisely control buoyancy at varying depths. Female argonauts use the shell to ‘gulp’ a measured volume of air at the sea surface, seal off the captured gas using flanged arms and forcefully dive to a depth where the compressed gas buoyancy counteracts body weight. This process allows the female argonaut to attain neutral buoyancy at depth and potentially adjust buoyancy to counter the increased (and significant) weight of eggs during reproductive periods. Evolution of this air-capture strategy enables this negatively buoyant octopus to survive free of the sea floor. This major shift in life mode from benthic to pelagic shows strong evolutionary parallels with the origins of all cephalopods, which attained gas-mediated buoyancy via the closed-chambered shells of the true nautiluses and their relatives. PMID:20484241

The argonaut shell: gas-mediated buoyancy control in a pelagic octopus.

PubMed

Finn, Julian K; Norman, Mark D

2010-10-07

Argonauts (Cephalopoda: Argonautidae) are a group of rarely encountered open-ocean pelagic octopuses with benthic ancestry. Female argonauts inhabit a brittle 'paper nautilus' shell, the role of which has puzzled naturalists for millennia. The primary role attributed to the shell has been as a receptacle for egg deposition and brooding. Our observations of wild argonauts have revealed that the thin calcareous shell also functions as a hydrostatic structure, employed by the female argonaut to precisely control buoyancy at varying depths. Female argonauts use the shell to 'gulp' a measured volume of air at the sea surface, seal off the captured gas using flanged arms and forcefully dive to a depth where the compressed gas buoyancy counteracts body weight. This process allows the female argonaut to attain neutral buoyancy at depth and potentially adjust buoyancy to counter the increased (and significant) weight of eggs during reproductive periods. Evolution of this air-capture strategy enables this negatively buoyant octopus to survive free of the sea floor. This major shift in life mode from benthic to pelagic shows strong evolutionary parallels with the origins of all cephalopods, which attained gas-mediated buoyancy via the closed-chambered shells of the true nautiluses and their relatives.

A change in stripes for cholesteric shells via modulated anchoring

NASA Astrophysics Data System (ADS)

Tran, Lisa; Lavrentovich, Maxim; Durey, Guillaume; Darmon, Alexandre; Haase, Martin; Li, Ningwei; Lee, Daeyeon; Stebe, Kathleen; Kamien, Randall; Lopez-Leon, Teresa

Many of the patterns found in biological systems are also found to self-assemble into cholesteric liquid crystal (CLC) systems. In this work, we probe the effect of varying the perpendicular anchoring strength of a CLC that is confined to a spherical shell. The shell geometry gives the confinement and curvature conditions for the formation of a rich array of meta-stable states, revealing an unexplored region between degenerate parallel anchoring and strong perpendicular anchoring. We modulate the anchoring strength in experiments with two methods: by adjusting the surfactant concentration or, interestingly, by varying the temperature. We find two states not previously reported for CLC shells: a Bouligand arches state, where larger, lateral stripes on the shell can be filled with smaller, longitudinal substripes, and a focal conic domain (FCD) state, where thin stripes wrap into at least two, topologically required, double spirals. We use a Landau-de Gennes model of the CLC to simulate the director configurations of these states. This work identifies the Bouligand arches state in CLC shells and builds upon the existing knowledge of cholesteric FCDs, structures that not only have potential for use as intricate, self-assembly blueprints but are pervasive in biological systems. UPENN MRSEC NSF DMR11-20901; ANR Grant 13-JS08-0006-01; IPGG Program ANR-10-IDEX 0001-02 PSL and ANR-10-EQPX-31.

The oil palm Shell gene controls oil yield and encodes a homologue of SEEDSTICK

PubMed Central

Singh, Rajinder; Leslie Low, Eng-Ti; Ooi, Leslie Cheng-Li; Ong-Abdullah, Meilina; Chin, Ting Ngoot; Nagappan, Jayanthi; Nookiah, Rajanaidu; Amiruddin, Mohd Din; Rosli, Rozana; Abdul Manaf, Mohamad Arif; Chan, Kuang-Lim; Halim, Mohd Amin; Azizi, Norazah; Lakey, Nathan; Smith, Steven W; Budiman, Muhammad A; Hogan, Michael; Bacher, Blaire; Van Brunt, Andrew; Wang, Chunyan; Ordway, Jared M; Sambanthamurthi, Ravigadevi; Martienssen, Robert A

2014-01-01

A key event in the domestication and breeding of the oil palm, Elaeis guineensis, was loss of the thick coconut-like shell surrounding the kernel. Modern E. guineensis has three fruit forms, dura (thick-shelled), pisifera (shell-less) and tenera (thin-shelled), a hybrid between dura and pisifera1–4. The pisifera palm is usually female-sterile but the tenera yields far more oil than dura, and is the basis for commercial palm oil production in all of Southeast Asia5. Here, we describe the mapping and identification of the Shell gene responsible for the different fruit forms. Using homozygosity mapping by sequencing we found two independent mutations in the DNA binding domain of a homologue of the MADS-box gene SEEDSTICK (STK) which controls ovule identity and seed development in Arabidopsis. The Shell gene is responsible for the tenera phenotype in both cultivated and wild palms from sub-Saharan Africa, and our findings provide a genetic explanation for the single gene heterosis attributed to Shell, via heterodimerization. This gene mutation explains the single most important economic trait in oil palm, and has implications for the competing interests of global edible oil production, biofuels and rainforest conservation6. PMID:23883930

Numerical treatment of a geometrically nonlinear planar Cosserat shell model

NASA Astrophysics Data System (ADS)

Sander, Oliver; Neff, Patrizio; Bîrsan, Mircea

2016-05-01

We present a new way to discretize a geometrically nonlinear elastic planar Cosserat shell. The kinematical model is similar to the general six-parameter resultant shell model with drilling rotations. The discretization uses geodesic finite elements (GFEs), which leads to an objective discrete model which naturally allows arbitrarily large rotations. GFEs of any approximation order can be constructed. The resulting algebraic problem is a minimization problem posed on a nonlinear finite-dimensional Riemannian manifold. We solve this problem using a Riemannian trust-region method, which is a generalization of Newton's method that converges globally without intermediate loading steps. We present the continuous model and the discretization, discuss the properties of the discrete model, and show several numerical examples, including wrinkling of thin elastic sheets in shear.

Geometrically Nonlinear Shell Analysis of Wrinkled Thin-Film Membranes with Stress Concentrations

NASA Technical Reports Server (NTRS)

Tessler, Alexander; Sleight, David W.

2006-01-01

Geometrically nonlinear shell finite element analysis has recently been applied to solar-sail membrane problems in order to model the out-of-plane deformations due to structural wrinkling. Whereas certain problems lend themselves to achieving converged nonlinear solutions that compare favorably with experimental observations, solutions to tensioned membranes exhibiting high stress concentrations have been difficult to obtain even with the best nonlinear finite element codes and advanced shell element technology. In this paper, two numerical studies are presented that pave the way to improving the modeling of this class of nonlinear problems. The studies address the issues of mesh refinement and stress-concentration alleviation, and the effects of these modeling strategies on the ability to attain converged nonlinear deformations due to wrinkling. The numerical studies demonstrate that excessive mesh refinement in the regions of stress concentration may be disadvantageous to achieving wrinkled equilibrium states, causing the nonlinear solution to lock in the membrane response mode, while totally discarding the very low-energy bending response that is necessary to cause wrinkling deformation patterns.

Structure and photoluminescence properties of TeO2-core/TiO2-shell nanowires

NASA Astrophysics Data System (ADS)

Park, Sunghoon; An, Soyeon; Lee, Chongmu

2013-12-01

TeO2-core/TiO2-shell nanowires were fabricated by thermal evaporation of Te powders and MOCVD of TiO2. The as-synthesized TeO2 nanowires showed a weak broad violet band centered at approximately 430 nm. The emission peak was shifted to a bluish violet region (∼455 nm) by the encapsulation of the nanowires with a TiO2 thin film. The intensity of the major emission from the core-shell nanowires showed strong dependence on the shell layer thickness. The strongest emission was obtained for the shell layer thickness of ∼15 nm and its intensity was approximately 80 times higher than that of the violet emission from the as-synthesized TeO2 nanowires. This enhancement in emission intensity is attributed to the subwavelength optical resonant cavity formation in the shell layer. The major emission intensity was enhanced further and blue-shifted by annealing, which might be attributed to the increase in the Ti interstitial and O vacancy concentrations in the TeO2 cores during annealing.

Growth of InAs/InP core-shell nanowires with various pure crystal structures.

PubMed

Gorji Ghalamestani, Sepideh; Heurlin, Magnus; Wernersson, Lars-Erik; Lehmann, Sebastian; Dick, Kimberly A

2012-07-20

We have studied the epitaxial growth of an InP shell on various pure InAs core nanowire crystal structures by metal-organic vapor phase epitaxy. The InP shell is grown on wurtzite (WZ), zinc-blende (ZB), and {111}- and {110}-type faceted ZB twin-plane superlattice (TSL) structures by tuning the InP shell growth parameters and controlling the shell thickness. The growth results, particularly on the WZ nanowires, show that homogeneous InP shell growth is promoted at relatively high temperatures (∼500 °C), but that the InAs nanowires decompose under the applied conditions. In order to protect the InAs core nanowires from decomposition, a short protective InP segment is first grown axially at lower temperatures (420-460 °C), before commencing the radial growth at a higher temperature. Further studies revealed that the InP radial growth rate is significantly higher on the ZB and TSL nanowires compared to WZ counterparts, and shows a strong anisotropy in polar directions. As a result, thin shells were obtained during low temperature InP growth on ZB structures, while a higher temperature was used to obtain uniform thick shells. In addition, a schematic growth model is suggested to explain the basic processes occurring during the shell growth on the TSL crystal structures.

Electrospun Polyurethane-Core and Gelatin-Shell Coaxial Fibre Coatings for Miniature Implantable Biosensors

PubMed Central

Wang, Ning; Burugapalli, Krishna; Wijesuriya, Shavini; Far, Mahshid Yazdi; Song, Wenhui; Moussy, Francis; Zheng, Yudong; Ma, Yanxuan; Wu, Zhentao; Li, Kang

2014-01-01

The aim of this study was to introduce bioactivity to the electrospun coating for implantable glucose biosensors. Coaxial fibre membranes having polyurethane as the core and gelatin as the shell were produced using a range of polyurethane concentrations (2, 4, 6 & 8% wt/v) while keeping gelatin concentration (10% wt/v) constant in 2,2,2-trifluoroethanol. The gelatin shell was stabilized using glutaraldehyde vapour. The formation of core-shell structure was confirmed using TEM, SEM and FTIR. The coaxial fibre membranes showed uniaxial tensile properties intermediate to that of the pure polyurethane and the gelatin fibre membranes. The gelatin shell increased hydrophilicity and glucose transport flux across the coaxial fibre membranes. The coaxial fibre membranes having small fibre diameter (541 nm) and a thick gelatin shell (52%) did not affect the sensor sensitivity, but decreased sensor’s linearity in the long run. In contrast, thicker coaxial fibre membranes (1133 nm) having a thin gelatin shell (34%) maintained both sensitivity and linearity till 84 days of the study period. To conclude, polyurethane-gelatin co-axial fibre membranes, due to their faster permeability to glucose, tailorable mechanical properties and bioactivity are potential candidates for coatings to favourably modify the host responses to extend the reliable in vivo lifetime of implantable glucose biosensors. PMID:24346001

Separative analyses of a chromatographic column packed with a core-shell adsorbent for lithium isotope separation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sugiyama, T.; Sugura, K.; Enokida, Y.

2015-03-15

Lithium-6 is used as a blanket material for sufficient tritium production in DT fueled fusion reactors. A core-shell type adsorbent was proposed for lithium isotope separation by chromatography. The mass transfer model in a chromatographic column consisted of 4 steps, such as convection and dispersion in the column, transfer through liquid films, intra-particle diffusion and and adsorption or desorption at the local adsorption sites. A model was developed and concentration profiles and time variation in the column were numerically simulated. It became clear that core-shell type adsorbents with thin porous shell were saturated rapidly relatively to fully porous one andmore » established a sharp edge of adsorption band. This is very important feature because lithium isotope separation requires long-distance development of adsorption band. The values of HETP (Height Equivalent of a Theoretical Plate) for core-shell adsorbent packed column were estimated by statistical moments of the step response curve. The value of HETP decreased with the thickness of the porous shell. A core-shell type adsorbent is, then, useful for lithium isotope separation. (authors)« less

Multi-parameter actuation of a neutrally stable shell: a flexible gear-less motor.

PubMed

Hamouche, W; Maurini, C; Vidoli, S; Vincenti, A

2017-08-01

We have designed and tested experimentally a morphing structure consisting of a neutrally stable thin cylindrical shell driven by a multi-parameter piezoelectric actuation. The shell is obtained by plastically deforming an initially flat copper disc, so as to induce large isotropic and almost uniform inelastic curvatures. Following the plastic deformation, in a perfectly isotropic system, the shell is theoretically neutrally stable, having a continuous set of stable cylindrical shapes corresponding to the rotation of the axis of maximal curvature. Small imperfections render the actual structure bistable, giving preferred orientations. A three-parameter piezoelectric actuation, exerted through micro-fibre-composite actuators, allows us to add a small perturbation to the plastic inelastic curvature and to control the direction of maximal curvature. This actuation law is designed through a geometrical analogy based on a fully nonlinear inextensible uniform-curvature shell model. We report on the fabrication, identification and experimental testing of a prototype and demonstrate the effectiveness of the piezoelectric actuators in controlling its shape. The resulting motion is an apparent rotation of the shell, controlled by the voltages as in a 'gear-less motor', which is, in reality, a precession of the axis of principal curvature.

Multi-parameter actuation of a neutrally stable shell: a flexible gear-less motor

NASA Astrophysics Data System (ADS)

Hamouche, W.; Maurini, C.; Vidoli, S.; Vincenti, A.

2017-08-01

We have designed and tested experimentally a morphing structure consisting of a neutrally stable thin cylindrical shell driven by a multi-parameter piezoelectric actuation. The shell is obtained by plastically deforming an initially flat copper disc, so as to induce large isotropic and almost uniform inelastic curvatures. Following the plastic deformation, in a perfectly isotropic system, the shell is theoretically neutrally stable, having a continuous set of stable cylindrical shapes corresponding to the rotation of the axis of maximal curvature. Small imperfections render the actual structure bistable, giving preferred orientations. A three-parameter piezoelectric actuation, exerted through micro-fibre-composite actuators, allows us to add a small perturbation to the plastic inelastic curvature and to control the direction of maximal curvature. This actuation law is designed through a geometrical analogy based on a fully nonlinear inextensible uniform-curvature shell model. We report on the fabrication, identification and experimental testing of a prototype and demonstrate the effectiveness of the piezoelectric actuators in controlling its shape. The resulting motion is an apparent rotation of the shell, controlled by the voltages as in a `gear-less motor', which is, in reality, a precession of the axis of principal curvature.

X-ray optics made from thin plastic foils

NASA Astrophysics Data System (ADS)

Schnopper, H. W.; Barbera, M.; Ingram, R.; Silver, E.; Romaine, S.; Bandler, S.; Murray, S.; Christensen, F. E.; Hussain, A.; Collura, A.

2000-10-01

New design concepts and materials can be used to produce lightweight, thin foil approximations, to Wolter I and other X-ray optics. Structures are designed around a central hub and spacers that connect two (or three) spoked wheels. Figure defining, thin pins span the distance between the wheels. Thin, metal coated or multilayered, plastic foils can be formed into full cones, cylinders or spirals for X-ray telescopes or lenses. High resolution X-ray scattering data were obtained for single foils at Cu K (8 KeV). Multi-energy (0.28 - 8 KeV) data were obtained with a multichannel plate imager in a 17 m beam line with a point-to-point focusing, cylindrical X-ray lens with 14 shells. The largest shell has a diameter of 175 mm and a length of 100 mm. Typical images have a FWHM of 20 arcsec. The results indicate that a 60 cm diameter, 4.65 m focal length X-ray telescope can have an HPD of considerably less than 2 arcmin. This research is supported, in part by NASA Grant NAG5-5268, ONR Grant N00014-95-1-1248, and by institutional funding from the Smithsonian Astrophysical Observatory. The SAO multilayer facility receives support from NASA Grant NAG5-5095. This work made use of the MRSEC Shared Experimental Facilities at MIT supported by NSF Grant DMR94-00334.

A Designed ZnO@ZIF-8 Core-Shell Nanorod Film as a Gas Sensor with Excellent Selectivity for H2 over CO.

PubMed

Wu, Xiaonan; Xiong, Shunshun; Mao, Zhenghao; Hu, Sheng; Long, Xinggui

2017-06-12

The development of H 2 gas sensors is important for H 2 production as a fuel. In this work, a ZnO@ZIF-8 core-shell nanorod film is designed and synthesized as a gas sensor through a facile solution deposition process. This film shows an excellent selective response for H 2 over CO. By fine-tuning the reaction conditions, a ZnO@ZIF-8 core-shell structure with a thin, fine-grain, porous ZIF-8 shell is obtained. Owing to the facile H 2 penetration through the ZIF-8 thin shell (≈110 nm) and the increased oxygen vacancies for the complex film, the ZnO@ZIF-8 nanorod film shows a higher H 2 sensitivity than a raw ZnO nanorod film. More importantly, the ZnO@ZIF-8 nanorod film shows no response for CO at 200 °C. Because of the fine-grain confinement of the porous ZIF-8 shell (<140 nm), the molecular sieving effect is strengthened, which allows the effective separation of H 2 over CO. This work provides a promising strategy for the design of high-performance H 2 sensors. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Re-radiation of acoustic waves from the A0 wave on a submerged elastic shell

NASA Astrophysics Data System (ADS)

Ahyi, A. C.; Cao, Hui; Raju, P. K.; Überall, Herbert

2005-07-01

We consider evacuated thin semi-infinite shells immersed in a fluid, which may be either of cylindrical shape with a hemispherical shell endcap, or formed two-dimensionally by semi-infinite parallel plates joined together by a semi-cylinder. The connected shell portions are joined in a manner to satisfy continuity but with a discontinuous radius of curvature. Acoustic waves are considered incident along the axis of symmetry (say the z axis) onto the curved portion of the shell, where they, at the critical angle of coincidence, generate Lamb and Stoneley-type waves in the shell. Computations were carried out using a code developed by Cao et al. [Chinese J. Acoust. 14, 317 (1995)] and was used in order to computationally visualize the waves in the fluid that have been re-radiated by the shell waves a the critical angle. The frequency range was below that of the lowest Lamb wave, and only the A0 wave (and partly the S0 wave) was observed to re-radiate into the fluid under our assumptions. The results will be compared to experimental results in which the re-radiated waves are optically visualized by the Schardin-Cranz schlieren method. .

Portable tomographic PIV measurements of swimming shelled Antarctic pteropods

NASA Astrophysics Data System (ADS)

Adhikari, Deepak; Webster, Donald R.; Yen, Jeannette

2016-12-01

A portable tomographic particle image velocimetry (tomographic PIV) system is described. The system was successfully deployed in Antarctica to study shelled Antarctic pteropods ( Limacina helicina antarctica)—a delicate organism with an unusual propulsion mechanism. The experimental setup consists of a free-standing frame assembled with optical rails, thus avoiding the need for heavy and bulky equipment (e.g. an optical table). The cameras, lasers, optics, and tanks are all rigidly supported within the frame assembly. The results indicate that the pteropods flap their parapodia (or "wings") downward during both power and recovery strokes, which is facilitated by the pitching of their shell. Shell pitching significantly alters the flapping trajectory, allowing the pteropod to move vertically and/or horizontally. The pronation and supination of the parapodia, together with the figure-eight motion during flapping, suggest similarities with insect flight. The volumetric velocity field surrounding the freely swimming pteropod reveals the generation of an attached vortex ring connecting the leading-edge vortex to the trailing-edge vortex during power stroke and a presence of a leading-edge vortex during recovery stroke. These vortex structures play a major role in accelerating the organism vertically and indicate that forces generated on the parapodia during flapping constitute both lift and drag. After completing each stroke, two vortex rings are shed into the wake of the pteropod. The complex combination of body kinematics (parapodia flapping, shell pitch, sawtooth trajectory), flow structures, and resulting force balance may be significantly altered by thinning of the pteropod shell, thus making pteropods an indicator of the detrimental effects of ocean acidification.

MicroShell Minimalist Shell for Xilinx Microprocessors

NASA Technical Reports Server (NTRS)

Werne, Thomas A.

2011-01-01

MicroShell is a lightweight shell environment for engineers and software developers working with embedded microprocessors in Xilinx FPGAs. (MicroShell has also been successfully ported to run on ARM Cortex-M1 microprocessors in Actel ProASIC3 FPGAs, but without project-integration support.) Micro Shell decreases the time spent performing initial tests of field-programmable gate array (FPGA) designs, simplifies running customizable one-time-only experiments, and provides a familiar-feeling command-line interface. The program comes with a collection of useful functions and enables the designer to add an unlimited number of custom commands, which are callable from the command-line. The commands are parameterizable (using the C-based command-line parameter idiom), so the designer can use one function to exercise hardware with different values. Also, since many hardware peripherals instantiated in FPGAs have reasonably simple register-mapped I/O interfaces, the engineer can edit and view hardware parameter settings at any time without stopping the processor. MicroShell comes with a set of support scripts that interface seamlessly with Xilinx's EDK tool. Adding an instance of MicroShell to a project is as simple as marking a check box in a library configuration dialog box and specifying a software project directory. The support scripts then examine the hardware design, build design-specific functions, conditionally include processor-specific functions, and complete the compilation process. For code-size constrained designs, most of the stock functionality can be excluded from the compiled library. When all of the configurable options are removed from the binary, MicroShell has an unoptimized memory footprint of about 4.8 kB and a size-optimized footprint of about 2.3 kB. Since MicroShell allows unfettered access to all processor-accessible memory locations, it is possible to perform live patching on a running system. This can be useful, for instance, if a bug is

Dicofol (Kelthane?)-induced eggshell thinning in captive American kestrels

USGS Publications Warehouse

Clark, D.R.; Spann, J.W.; Bunck, C.M.

1990-01-01

Reproductive parameters of American kestrels (Falco sparverius) were measured through two breeding seasons. Exposure to Kelthane? (containing no DDT-related compounds) at dietary concentrations of 0 (contro!), 1, 3, 10 and 30 ug/g (wet weight) began in late November before, and continued through, the second season. Kelthane thinned eggshells and lowered the thickness index at dietary concentrations >3 ?g/g and it reduced shell weight at >10 ?g/g when comparisons were to concurrent controls. Kelthane reduced the thickness index at >3 ug/g and it reduced shell thickness and weight at >10 ug/g when comparisons were to the same birds during the previous season. All changes were dose-related. It was not previously known that as little as 3 ug/g dicofol could cause these effects. Kestrels resembled previously studied eastern screech-owls (Otus asio) in that 10 ug/ g reduced hatchability of eggs. Both these raptors showed eggshell changes without serious effects on production of young. Available data show dicofol only equal to or less effective than DDE as a shell-thinning agent. Also, DDE may have more impact than dicofol on such critical aspects of reproduction as egg hatchability and survivability of hatchlings. Field studies of dicofol residues in food chains and of residue concentrations in eggs vs. nesting success from areas of heavy dicofol use are needed to judge this chemical's ecological impact.

Characterizing haploinsufficiency of SHELL gene to improve fruit form prediction in introgressive hybrids of oil palm.

PubMed

Teh, Chee-Keng; Muaz, Siti Dalila; Tangaya, Praveena; Fong, Po-Yee; Ong, Ai-Ling; Mayes, Sean; Chew, Fook-Tim; Kulaveerasingam, Harikrishna; Appleton, David

2017-06-08

The fundamental trait in selective breeding of oil palm (Eleais guineensis Jacq.) is the shell thickness surrounding the kernel. The monogenic shell thickness is inversely correlated to mesocarp thickness, where the crude palm oil accumulates. Commercial thin-shelled tenera derived from thick-shelled dura × shell-less pisifera generally contain 30% higher oil per bunch. Two mutations, sh MPOB (M1) and sh AVROS (M2) in the SHELL gene - a type II MADS-box transcription factor mainly present in AVROS and Nigerian origins, were reported to be responsible for different fruit forms. In this study, we have tested 1,339 samples maintained in Sime Darby Plantation using both mutations. Five genotype-phenotype discrepancies and eight controls were then re-tested with all five reported mutations (sh AVROS , sh MPOB , sh MPOB2 , sh MPOB3 and sh MPOB4 ) within the same gene. The integration of genotypic data, pedigree records and shell formation model further explained the haploinsufficiency effect on the SHELL gene with different number of functional copies. Some rare mutations were also identified, suggesting a need to further confirm the existence of cis-compound mutations in the gene. With this, the prediction accuracy of fruit forms can be further improved, especially in introgressive hybrids of oil palm. Understanding causative variant segregation is extremely important, even for monogenic traits such as shell thickness in oil palm.

Cylindrical Shells Made of Stainless Steel - Investigation of Postbuckling

NASA Astrophysics Data System (ADS)

Stehr, Sebastian; Stranghöner, Natalie

2017-06-01

The relevant load case of open thin-walled shells is often wind loading during construction. Because of the missing stabilization effect of the roof they show a very high sensitivity to buckling which results into higher wall thicknesses. As part of the European RFCS research project BiogaSS the Institute for Metal and Lightweight Structures of the University of Duisburg-Essen carried out investigations on open thin-walled tanks made of austenitic and duplex stainless steels under wind load to study a possible economic advantage which might be gained from the consideration of the elastic postbuckling behaviour. This contribution presents not only experimental and numerical results but also first recommendations regarding the range of possible buckling reduction factors which might be incorporated in future revisions of EN 1993-1-6 and EN 1993-4-2.

One-pot synthesis of metal-organic framework@SiO2 core-shell nanoparticles with enhanced visible-light photoactivity.

PubMed

Li, Zong-Qun; Wang, Ai; Guo, Chun-Yan; Tai, Yan-Fang; Qiu, Ling-Guang

2013-10-14

This paper presents a novel strategy to prepare Cu3(BTC)2@SiO2 core-shell nanoparticles in the size range of 200-400 nm using a new one-pot strategy under ultrasonic irradiation at room temperature. In this approach, the silica shell thickness could be finely tuned in the size range of 12-60 nm for various reaction times. Nanocomposite thin films were fabricated on the glass substrates by Sol-Gel spin coating using the products for 1.5 h, 2 h and 2.5 h, respectively, and heat treated using an infrared lamp heating system in air. The photocatalytic degradation of phenol in aqueous solution using Cu2(BTC)3@SiO2 thin films was investigated under visible light irradiation at pH 4. After a 45 min reaction with phenol, the degradation rate was up to 93.1%. Moreover, the thin film photocatalysts could be reused 5 times without appreciable loss of photocatalytic activity for degradation of phenol. The present work clearly shows that the films as photocatalysts showed higher photocatalytic performance.

Optical properties of core-shell and multi-shell nanorods

NASA Astrophysics Data System (ADS)

Mokkath, Junais Habeeb; Shehata, Nader

2018-05-01

We report a first-principles time dependent density functional theory study of the optical response modulations in bimetallic core-shell (Na@Al and Al@Na) and multi-shell (Al@Na@Al@Na and Na@Al@Na@Al: concentric shells of Al and Na alternate) nanorods. All of the core-shell and multi-shell configurations display highly enhanced absorption intensity with respect to the pure Al and Na nanorods, showing sensitivity to both composition and chemical ordering. Remarkably large spectral intensity enhancements were found in a couple of core-shell configurations, indicative that optical response averaging based on the individual components can not be considered as true as always in the case of bimetallic core-shell nanorods. We believe that our theoretical results would be useful in promising applications depending on Aluminum-based plasmonic materials such as solar cells and sensors.

An analytical theory for a three-dimensional thick-disc thin-plate vibratory gyroscope

NASA Astrophysics Data System (ADS)

Sedebo, G. T.; Joubert, S. V.; Shatalov, M. Y.

2018-04-01

We consider a cylindrical vibratory gyroscope comprising a not necessarliy thin-shelled annular disc with small-plate thickness, vibrating in the m -th vibration mode in-plane and in the (m + 1)st vibration mode out-of-plane. We derive the equations of motion for this contrivance in the “force-to-rebalance regime” and show how a slow (three-dimensional) inertial rotation rate of the gyroscope can be calculated in terms of amplitudes of vibration and other constants, all of which can be measured experimentally or calculated when the eigenfunctions and eigenvalues of the system are known. By means of a concrete example, a numerical experiment demonstrates how varying the inner radius of the annulus as well as the thickness of the plate allows us to “tune” the vibration frequencies of the in-plane and out-of-plane vibrations so that they coincide (for all practical purposes), eliminating any frequency split. Conventionally, an array of at least three thin-shelled hemispherical (or thin-ring) vibratory (resonator) gyroscopes is used to measure any three-dimensional rotation of the craft to which the gyroscopes are fixed. With the design proposed here, the array can be reduced to a solitary, tuned, annular thick-disc thin-plate vibratory gyroscope, reducing both size and cost.

Buckling of thin walled composite cylindrical shell filled with solid propellant

NASA Astrophysics Data System (ADS)

Dash, A. P.; Velmurugan, R.; Prasad, M. S. R.

2017-12-01

This paper investigates the buckling of thin walled composite cylindrical tubes that are partially filled with solid propellant equivalent elastic filler. Experimental investigation is conducted on thin composite tubes made out of S2-glass epoxy, which is made by using filament winding technique. The composite tubes are filled with elastic filler having similar mechanical properties as that of a typical solid propellant used in rocket motors. The tubes are tested for their buckling strength against the external pressure in the presence of the filler. Experimental data confirms the enhancement of external pressure carrying capacity of the composite tubes by up to three times as that of empty tubes for a volumetric loading fraction (VLF) of 0.9. Furthermore, the finite element based geometric nonlinearity analysis predicts the buckling behaviour of the partially filled composite tubes close to the experimental results.

Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making

DOEpatents

Alivisatos, A Paul [Oakland, CA; Yin, Yadong [Moreno Valley, CA; Rioux, Robert M [Somerville, MA; Somorjai, Gabor A [Berkeley, CA

2011-01-25

Described herein are nanoreactors having various shapes that can be produced by a simple chemical process. The nanoreactors described herein may have a shell as thin as 0.5 nm and outside diameters that can be controlled by the process of making and have a nanoparticle enclosed therein. The nanoreactors have catalytic activity and may be used to catalyze a variety of chemical reactions.

Technical Note: Effect of explicit M and N-shell atomic transitions on a low-energy x-ray source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watson, Peter G. F., E-mail: peter.watson@mail.mcgill.ca; Seuntjens, Jan

Purpose: In EGSnrc, atomic transitions to and from the M and N-shells are treated in an average way by default. This approach is justified in which the energy difference between explicit and average M and N-shell binding energies is less than 1 keV, and for most applications can be considered negligible. However, for simulations of low energy x-ray sources on thin, high-Z targets, characteristic x-rays can make up a significant portion of the source spectra. As of release V4-2.4.0, EGSnrc has included an option to enable a more complete algorithm of all atomic transitions available in the EADL compilation. Inmore » this paper, the effect of M and N-shell averaging on the calculation of half-value layer (HVL) and relative depth dose (RDD) curve of a 50 kVp intraoperative x-ray tube with a thin gold target was investigated. Methods: A 50 kVp miniature x-ray source with a gold target (The INTRABEAM System, Carl Zeiss, Germany) was modeled with the EGSnrc user code cavity, both with and without M and N-shell averaging. From photon fluence spectra simulations, the source HVLs were determined analytically. The same source model was then used with egs-chamber to calculate RDD curves in water. Results: A 4% increase of HVL was reported when accounting for explicit M and N-shell transitions, and up to a 9% decrease in local relative dose for normalization at 3 mm depth in water. Conclusions: The EGSnrc default of using averaged M and N-shell binding energies has an observable effect on the HVL and RDD of a low energy x-ray source with high-Z target. For accurate modeling of this class of devices, explicit atomic transitions should be included.« less

Enhanced Corrosion Resistance of PVD-CrN Coatings by ALD Sealing Layers

NASA Astrophysics Data System (ADS)

Wan; Zhang, Teng Fei; Ding, Ji Cheng; Kim, Chang-Min; Park, So-Won; Yang, Yang; Kim, Kwang-Ho; Kwon, Se-Hun

2017-04-01

Multilayered hard coatings with a CrN matrix and an Al2O3, TiO2, or nanolaminate-Al2O3/TiO2 sealing layer were designed by a hybrid deposition process combined with physical vapor deposition (PVD) and atomic layer deposition (ALD). The strategy was to utilize ALD thin films as pinhole-free barriers to seal the intrinsic defects to protect the CrN matrix. The influences of the different sealing layers added in the coatings on the microstructure, surface roughness, and corrosion behaviors were investigated. The results indicated that the sealing layer added by ALD significantly decreased the average grain size and improved the corrosion resistance of the CrN coatings. The insertion of the nanolaminate-Al2O3/TiO2 sealing layers resulted in a further increase in corrosion resistance, which was attributed to the synergistic effect of Al2O3 and TiO2, both acting as excellent passivation barriers to the diffusion of corrosive substances.

Microscopic Shell Model Calculations for sd-Shell Nuclei

NASA Astrophysics Data System (ADS)

Barrett, Bruce R.; Dikmen, Erdal; Maris, Pieter; Shirokov, Andrey M.; Smirnova, Nadya A.; Vary, James P.

Several techniques now exist for performing detailed and accurate calculations of the structure of light nuclei, i.e., A ≤ 16. Going to heavier nuclei requires new techniques or extensions of old ones. One of these is the so-called No Core Shell Model (NCSM) with a Core approach, which involves an Okubo-Lee-Suzuki (OLS) transformation of a converged NCSM result into a single major shell, such as the sd-shell. The obtained effective two-body matrix elements can be separated into core and single-particle (s.p.) energies plus residual two-body interactions, which can be used for performing standard shell-model (SSM) calculations. As an example, an application of this procedure will be given for nuclei at the beginning ofthe sd-shell.

Ocean Tidal Dynamics and Dissipation in the Thick Shell Worlds

NASA Astrophysics Data System (ADS)

Hay, H.; Matsuyama, I.

2017-12-01

Tidal dissipation in the subsurface oceans of icy satellites has so far only been explored in the limit of a free-surface ocean or under the assumption of a thin ice shell. Here we consider ocean tides in the opposite limit, under the assumption of an infinitely rigid, immovable, ice shell. This assumption forces the surface displacement of the ocean to remain zero, and requires the solution of a pressure correction to ensure that the ocean is mass conserving (divergence-free) at all times. This work investigates the effect of an infinitely rigid lid on ocean dynamics and dissipation, focusing on implications for the thick shell worlds Ganymede and Callisto. We perform simulations using a modified version of the numerical model Ocean Dissipation in Icy Satellites (ODIS), solving the momentum equations for incompressible shallow water flow under a degree-2 tidal forcing. The velocity solution to the momentum equations is updated iteratively at each time-step using a pressure correction to guarantee mass conservation everywhere, following a standard solution procedure originally used in solving the incompressible Navier-Stokes equations. We reason that any model that investigates ocean dynamics beneath a global ice layer should be tested in the limit of an immovable ice shell and must yield solutions that exhibit divergence-free flow at all times.

A top-down approach for fabricating three-dimensional closed hollow nanostructures with permeable thin metal walls.

PubMed

Barrios, Carlos Angulo; Canalejas-Tejero, Víctor

2017-01-01

We report on a top-down method for the controlled fabrication of three-dimensional (3D), closed, thin-shelled, hollow nanostructures (nanocages) on planar supports. The presented approach is based on conventional microelectronic fabrication processes and exploits the permeability of thin metal films to hollow-out polymer-filled metal nanocages through an oxygen-plasma process. The technique is used for fabricating arrays of cylindrical nanocages made of thin Al shells on silicon substrates. This hollow metal configuration features optical resonance as revealed by spectral reflectance measurements and numerical simulations. The fabricated nanocages were demonstrated as a refractometric sensor with a measured bulk sensitivity of 327 nm/refractive index unit (RIU). The pattern design flexibility and controllability offered by top-down nanofabrication techniques opens the door to the possibility of massive integration of these hollow 3D nano-objects on a chip for applications such as nanocontainers, nanoreactors, nanofluidics, nano-biosensors and photonic devices.

Soil calcium availability influences shell ecophenotype formation in the sub-antarctic land snail, Notodiscus hookeri.

PubMed

Charrier, Maryvonne; Marie, Arul; Guillaume, Damien; Bédouet, Laurent; Le Lannic, Joseph; Roiland, Claire; Berland, Sophie; Pierre, Jean-Sébastien; Le Floch, Marie; Frenot, Yves; Lebouvier, Marc

2013-01-01

Ecophenotypes reflect local matches between organisms and their environment, and show plasticity across generations in response to current living conditions. Plastic responses in shell morphology and shell growth have been widely studied in gastropods and are often related to environmental calcium availability, which influences shell biomineralisation. To date, all of these studies have overlooked micro-scale structure of the shell, in addition to how it is related to species responses in the context of environmental pressure. This study is the first to demonstrate that environmental factors induce a bi-modal variation in the shell micro-scale structure of a land gastropod. Notodiscus hookeri is the only native land snail present in the Crozet Archipelago (sub-Antarctic region). The adults have evolved into two ecophenotypes, which are referred to here as MS (mineral shell) and OS (organic shell). The MS-ecophenotype is characterised by a thick mineralised shell. It is primarily distributed along the coastline, and could be associated to the presence of exchangeable calcium in the clay minerals of the soils. The Os-ecophenotype is characterised by a thin organic shell. It is primarily distributed at high altitudes in the mesic and xeric fell-fields in soils with large particles that lack clay and exchangeable calcium. Snails of the Os-ecophenotype are characterised by thinner and larger shell sizes compared to snails of the MS-ecophenotype, indicating a trade-off between mineral thickness and shell size. This pattern increased along a temporal scale; whereby, older adult snails were more clearly separated into two clusters compared to the younger adult snails. The prevalence of glycine-rich proteins in the organic shell layer of N. hookeri, along with the absence of chitin, differs to the organic scaffolds of molluscan biominerals. The present study provides new insights for testing the adaptive value of phenotypic plasticity in response to spatial and temporal

Photoelectrodes based on 2D opals assembled from Cu-delafossite double-shelled microspheres for an enhanced photoelectrochemical response.

PubMed

Oh, Yunjung; Yang, Wooseok; Tan, Jeiwan; Lee, Hyungsoo; Park, Jaemin; Moon, Jooho

2018-02-22

Although a unique light-harvesting property was recently demonstrated in a photocathode based on 2-dimensional (2D) opals of CuFeO 2 -shelled SiO 2 microspheres, the performance of a monolayer of ultra-thin CuFeO 2 -shelled microspheres is limited by ineffective charge separation. Herein, we propose an innovative design rule, in which an inner CuFeO 2 /outer CuAlO 2 double-shelled heterojunction is formed on each partially etched microsphere to obtain a hexagonally assembled 2D opal photoelectrode. Our Cu-delafossite double-shelled photocathode shows a dramatically improved charge separation capability, with a 9-fold increase in the photocurrent compared to that of the single-shelled counterpart. Electrochemical impedance spectroscopy clearly confirms the reduced charge transport/transfer resistance associated with the Cu-delafossite double-shelled photocathode, while surface photovoltage spectra reveal enhanced polarization of the photogenerated carrier, indicating improved charge separation capability with the aid of the heterojunction. Our finding sheds light on the importance of heterojunction interfaces in achieving optimal charge separation in opal architectures as well as the inner-shell/electrolyte interface to expedite charge separation/transport.

Highly efficient photocatalytic conversion of solar energy to hydrogen by WO3/BiVO4 core-shell heterojunction nanorods

NASA Astrophysics Data System (ADS)

Kosar, Sonya; Pihosh, Yuriy; Bekarevich, Raman; Mitsuishi, Kazutaka; Mawatari, Kazuma; Kazoe, Yutaka; Kitamori, Takehiko; Tosa, Masahiro; Tarasov, Alexey B.; Goodilin, Eugene A.; Struk, Yaroslav M.; Kondo, Michio; Turkevych, Ivan

2018-04-01

Photocatalytic splitting of water under solar light has proved itself to be a promising approach toward the utilization of solar energy and the generation of environmentally friendly fuel in a form of hydrogen. In this work, we demonstrate highly efficient solar-to-hydrogen conversion efficiency of 7.7% by photovoltaic-photoelectrochemical (PV-PEC) device based on hybrid MAPbI3 perovskite PV cell and WO3/BiVO4 core-shell nanorods PEC cell tandem that utilizes spectral splitting approach. Although BiVO4 is characterized by intrinsically high recombination rate of photogenerated carriers, this is not an issue for WO3/BiVO4 core-shell nanorods, where highly conductive WO3 cores are combined with extremely thin absorber BiVO4 shell layer. Since the BiVO4 layer is thinner than the characteristic carrier diffusion length, the photogenerated charge carriers are separated at the WO3/BiVO4 heterojunction before their recombination. Also, such architecture provides sufficient optical thickness even for extremely thin BiVO4 layer due to efficient light trapping in the core-shell WO3/BiVO4 nanorods with high aspect ratio. We also demonstrate that the concept of fill factor can be used to compare I-V characteristics of different photoanodes regarding their optimization for PV/PEC tandem devices.

The Twisting of Thin-walled, Stiffened Circular Cylinders

NASA Technical Reports Server (NTRS)

Schapitz, E

1938-01-01

On the basis of the present investigation of the twisting of thin-walled, stiffened cylinders the following conclusions can be reached: 1) there is as yet no generally applicable formula for the buckling moment of the skin; 2) the mathematical treatment of the condition of the shell after buckling of the skin is based on the tension-field theory, wherein the strain condition is considered homogenous.

Preparation and recognition of surface molecularly imprinted core-shell microbeads for protein in aqueous solutions

NASA Astrophysics Data System (ADS)

Lu, Yan; Yan, Chang-Ling; Gao, Shu-Yan

2009-04-01

In this paper, a surface molecular imprinting technique was reported for preparing core-shell microbeads of protein imprinting, and bovine hemoglobin or bovine serum albumin were used as model proteins for studying the imprinted core-shell microbeads. 3-Aminophenylboronic acid (APBA) was polymerized onto the surface of polystyrene microbead in the presence of the protein templates to create protein-imprinted core-shell microbeads. The various samples were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller (BET) methods. The effect of pH on rebinding of the template hemoglobin, the specific binding and selective recognition were studied for the imprinted microbeads. The results show that the bovine hemoglobin-imprinted core-shell microbeads were successfully created. The shell was a sort of imprinted thin films with porous structure and larger surface areas. The imprinted microbeads have good selectivity for templates and high stability. Due to the recognition sites locating at or closing to the surface, these imprinted microbeads have good property of mass-transport. Unfortunately, the imprint technology was not successfully applied to imprinting bovine serum albumin (BSA).

Fast-Response Single-Nanowire Photodetector Based on ZnO/WS2 Core/Shell Heterostructures.

PubMed

Butanovs, Edgars; Vlassov, Sergei; Kuzmin, Alexei; Piskunov, Sergei; Butikova, Jelena; Polyakov, Boris

2018-04-25

The surface plays an exceptionally important role in nanoscale materials, exerting a strong influence on their properties. Consequently, even a very thin coating can greatly improve the optoelectronic properties of nanostructures by modifying the light absorption and spatial distribution of charge carriers. To use these advantages, 1D/1D heterostructures of ZnO/WS 2 core/shell nanowires with a-few-layers-thick WS 2 shell were fabricated. These heterostructures were thoroughly characterized by scanning and transmission electron microscopy, X-ray diffraction, and Raman spectroscopy. Then, a single-nanowire photoresistive device was assembled by mechanically positioning ZnO/WS 2 core/shell nanowires onto gold electrodes inside a scanning electron microscope. The results show that a few layers of WS 2 significantly enhance the photosensitivity in the short wavelength range and drastically (almost 2 orders of magnitude) improve the photoresponse time of pure ZnO nanowires. The fast response time of ZnO/WS 2 core/shell nanowire was explained by electrons and holes sinking from ZnO nanowire into WS 2 shell, which serves as a charge carrier channel in the ZnO/WS 2 heterostructure. First-principles calculations suggest that the interface layer i-WS 2 , bridging ZnO nanowire surface and WS 2 shell, might play a role of energy barrier, preventing the backward diffusion of charge carriers into ZnO nanowire.

Vibrations of cantilevered circular cylindrical shells Shallow versus deep shell theory

NASA Technical Reports Server (NTRS)

Lee, J. K.; Leissa, A. W.; Wang, A. J.

1983-01-01

Free vibrations of cantilevered circular cylindrical shells having rectangular planforms are studied in this paper by means of the Ritz method. The deep shell theory of Novozhilov and Goldenveizer is used and compared with the usual shallow shell theory for a wide range of shell parameters. A thorough convergence study is presented along with comparisons to previously published finite element solutions and experimental results. Accurately computed frequency parameters and mode shapes for various shell configurations are presented. The present paper appears to be the first comprehensive study presenting rigorous comparisons between the two shell theories in dealing with free vibrations of cantilevered cylindrical shells.

Core-shell microspheres with porous nanostructured shells for liquid chromatography.

PubMed

Ahmed, Adham; Skinley, Kevin; Herodotou, Stephanie; Zhang, Haifei

2018-01-01

The development of new stationary phases has been the key aspect for fast and efficient high-performance liquid chromatography separation with relatively low backpressure. Core-shell particles, with a solid core and porous shell, have been extensively investigated and commercially manufactured in the last decade. The excellent performance of core-shell particles columns has been recorded for a wide range of analytes, covering small and large molecules, neutral and ionic (acidic and basic), biomolecules and metabolites. In this review, we first introduce the advance and advantages of core-shell particles (or more widely known as superficially porous particles) against non-porous particles and fully porous particles. This is followed by the detailed description of various methods used to fabricate core-shell particles. We then discuss the applications of common silica core-shell particles (mostly commercially manufactured), spheres-on-sphere particles and core-shell particles with a non-silica shell. This review concludes with a summary and perspective on the development of stationary phase materials for high-performance liquid chromatography applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Greenhouse effect: temperature of a metal sphere surrounded by a glass shell and heated by sunlight

NASA Astrophysics Data System (ADS)

Nguyen, Phuc H.; Matzner, Richard A.

2012-01-01

We study the greenhouse effect on a model satellite consisting of a tungsten sphere surrounded by a thin spherical, concentric glass shell, with a small gap between the sphere and the shell. The system sits in vacuum and is heated by sunlight incident along the z-axis. This development is a generalization of the simple treatment of the greenhouse effect given by Kittel and Kroemer (1980 Thermal Physics (San Francisco: Freeman)) and can serve as a very simple model demonstrating the much more complex Earth greenhouse effect. Solution of the model problem provides an excellent pedagogical tool at the Junior/Senior undergraduate level.

Preliminary analysis techniques for ring and stringer stiffened cylindrical shells

NASA Technical Reports Server (NTRS)

Graham, J.

1993-01-01

This report outlines methods of analysis for the buckling of thin-walled circumferentially and longitudinally stiffened cylindrical shells. Methods of analysis for the various failure modes are presented in one cohesive package. Where applicable, more than one method of analysis for a failure mode is presented along with standard practices. The results of this report are primarily intended for use in launch vehicle design in the elastic range. A Microsoft Excel worksheet with accompanying macros has been developed to automate the analysis procedures.

Structural design criteria for filament-wound composite shells

NASA Technical Reports Server (NTRS)

Hahn, H. T.; Jensen, D. W.; Claus, S. J.; Pai, S. P.; Hipp, P. A.

1994-01-01

Advanced composite cylinders, manufactured by filament winding, provide a cost effective solution to many present structural applications; however, the compressive performance of filament-wound cylinders is lower than comparable shells fabricated from unidirectional tape. The objective of this study was to determine the cause of this reduction in thin filament-wound cylinders by relating the manufacturing procedures to the quality of the cylinder and to its compressive performance. The experiments on cylinder buckling were complemented by eigenvalue buckling analysis using a detailed geometric model in a finite element analysis. The applicability of classical buckling analyses was also investigated as a design tool.

Nondimensional parameters and equations for buckling of symmetrically laminated thin elastic shallow shells

NASA Technical Reports Server (NTRS)

Nemeth, Michael P.

1991-01-01

A method of deriving nondimensional equations and identifying the fundamental parameters associated with bifurcation buckling of anisotropic shells subjected to combined loads is presented. The procedure and rationale used to obtain useful nondimensional forms of the transverse equilibrium and compatibility equations for buckling are presented. Fundamental parameters are identified that represent the importance of both membrane and bending orthotropy and anisotropy on the results.

Tandem Core–Shell Si–Ta 3N 5 Photoanodes for Photoelectrochemical Water Splitting

DOE PAGES

Narkeviciute, Ieva; Chakthranont, Pongkarn; Mackus, Adriaan J. M.; ...

2016-11-22

Here, nanostructured core–shell Si–Ta 3N 5 photoanodes were designed and synthesized to overcome charge transport limitations of Ta 3N 5 for photoelectrochemical water splitting. The core–shell devices were fabricated by atomic layer deposition of amorphous Ta 2O 5 onto nanostructured Si and subsequent nitridation to crystalline Ta 3N 5. Nanostructuring with a thin shell of Ta 3N 5 results in a 10-fold improvement in photocurrent compared to a planar device of the same thickness. In examining thickness dependence of the Ta 3N 5 shell from 10 to 70 nm, superior photocurrent and absorbed-photon-to-current efficiencies are obtained from the thinner Tamore » 3N 5 shells, indicating minority carrier diffusion lengths on the order of tens of nanometers. The fabrication of a heterostructure based on a semiconducting, n-type Si core produced a tandem photoanode with a photocurrent onset shifted to lower potentials by 200 mV. CoTiO x and NiO x water oxidation cocatalysts were deposited onto the Si–Ta 3N 5 to yield active photoanodes that with NiO x retained 50–60% of their maximum photocurrent after 24 h chronoamperometry experiments and are thus among the most stable Ta 3N 5 photoanodes reported to date.« less

One-Hundred-km-Scale Basins on Enceladus: Evidence for an Active Ice Shell

NASA Technical Reports Server (NTRS)

Schenk, Paul M.; McKinnon, William B.

2009-01-01

Stereo-derived topographic mapping of 50% of Enceladus reveals at least 6 large-scale, ovoid depressions (basins) 90-175 km across and 800-to-1500 m deep and uncorrelated with geologic boundaries. Their shape and scale are inconsistent with impact, geoid deflection, or with dynamically supported topography. Isostatic thinning of Enceladus ice shell associated with upwellings (and tidally-driven ice melting) can plausibly account for the basins. Thinning implies upwarping of the base of the shell of 10-20 km beneath the depressions, depending on total shell thickness; loss of near-surface porosity due to enhanced heat flow may also contribute to basin lows. Alternatively, the basins may overly cold, inactive, and hence denser ice, but thermal isostasy alone requires thermal expansion more consistent with clathrate hydrate than water ice. In contrast to the basins, the south polar depression (SPD) is larger (350 wide) and shallower (0.4-to-0.8 km deep) and correlates with the area of tectonic deformation and active resurfacing. The SPD also differs in that the floor is relatively flat (i.e., conforms roughly to the global triaxial shape, or geoid) with broad, gently sloping flanks. The relative flatness across the SPD suggests that it is in or near isostatic equilibrium, and underlain by denser material, supporting the polar sea hypothesis of Collins and Goodman. Near flatness is also predicted by a crustal spreading origin for the "tiger stripes (McKinnon and Barr 2007, Barr 2008); the extraordinary, high CIRS heat flows imply half-spreading rates in excess of 10 cm/yr, a very young surface age (250,000 yr), and a rather thin lithosphere (hence modest thermal topography). Topographic rises in places along the outer margin of the SPD correlate with parallel ridges and deformation along the edge of the resurfaced terrain, consistent with a compressional, imbricate thrust origin for these ridges, driven by the spreading.

Variational finite-difference methods in linear and nonlinear problems of the deformation of metallic and composite shells (review)

NASA Astrophysics Data System (ADS)

Maksimyuk, V. A.; Storozhuk, E. A.; Chernyshenko, I. S.

2012-11-01

Variational finite-difference methods of solving linear and nonlinear problems for thin and nonthin shells (plates) made of homogeneous isotropic (metallic) and orthotropic (composite) materials are analyzed and their classification principles and structure are discussed. Scalar and vector variational finite-difference methods that implement the Kirchhoff-Love hypotheses analytically or algorithmically using Lagrange multipliers are outlined. The Timoshenko hypotheses are implemented in a traditional way, i.e., analytically. The stress-strain state of metallic and composite shells of complex geometry is analyzed numerically. The numerical results are presented in the form of graphs and tables and used to assess the efficiency of using the variational finite-difference methods to solve linear and nonlinear problems of the statics of shells (plates)

Defined polymer shells on nanoparticles via a continuous aerosol-based process

NASA Astrophysics Data System (ADS)

Sigmund, Stephanie; Akgün, Ertan; Meyer, Jörg; Hubbuch, Jürgen; Wörner, Michael; Kasper, Gerhard

2014-08-01

A continuous aerosol-based process is described for the encapsulation of nanoparticles with a thin polymer shell. The process is essentially based on directed binary collisions between gas-borne core particles and liquid monomer droplets carrying opposite electrical charges, followed by photo-initiated polymerization. Once the two streams are mixed together, the process runs to completion on a time scale of about 2 min or less, required for coagulation and polymerization. Gold, silica, and sodium chloride nanoparticles were successfully coated by this technique with PHDDA [poly(hexanediol diacrylate)] and/or crosslinked PMMA [poly(methyl methacrylate)]. It was found that all core materials as well as agglomerates were wettable at room temperature and that the spreading kinetics of the monomer were fast enough to cover the core particles uniformly within the time scale provided for coagulation. The shell thickness depends on the volume ratio between core particles and monomer droplets. This was demonstrated for a combination of monodisperse silica spheres ( d = 241 nm) and polydisperse methyl methacrylate droplets, resulting in a theoretical shell thickness of 18 nm. There was very good agreement between measurements by TEM and electrical mobility spectroscopy. The results revealed that about 90 % or more of the core-shell structures were formed from 1:1 collisions between a core particle and a single monomer droplet.

Fully localized post-buckling states of cylindrical shells under axial compression

NASA Astrophysics Data System (ADS)

Kreilos, Tobias; Schneider, Tobias M.

2017-09-01

We compute nonlinear force equilibrium solutions for a clamped thin cylindrical shell under axial compression. The equilibrium solutions are dynamically unstable and located on the stability boundary of the unbuckled state. A fully localized single dimple deformation is identified as the edge state-the attractor for the dynamics restricted to the stability boundary. Under variation of the axial load, the single dimple undergoes homoclinic snaking in the azimuthal direction, creating states with multiple dimples arranged around the central circumference. Once the circumference is completely filled with a ring of dimples, snaking in the axial direction leads to further growth of the dimple pattern. These fully nonlinear solutions embedded in the stability boundary of the unbuckled state constitute critical shape deformations. The solutions may thus be a step towards explaining when the buckling and subsequent collapse of an axially loaded cylinder shell is triggered.

Triangular prismatic solid-shell element with generalised deformation description

NASA Astrophysics Data System (ADS)

Mataix, Vicente; Flores, Fernando G.; Rossi, Riccardo; Oñate, Eugenio

2018-01-01

The solid-shells are an attractive kind of element for the simulation of f orming processes, due to the fact that any kind of generic 3D constitutive law can be employed without any kind of additional modification, besides the thermomechanic problem is formulated without additional assumptions. Additionally, this type of element allows the three-dimensional description of the deformable body, thus contact on both sides of the element can be treated easily. The present work consists in the development of a triangular prism element as a solid-shell, for the analysis of thin/thick shell, undergoing large deformations. The element is formulated in total Lagrangian formulation, and employs the neighbour (adjacent) elements to perform a local patch to enrich the displacement field. In the original formulation by Flores, a modified right Cauchy-Green deformation tensor (?) is obtained; in the present work a modified deformation gradient (?) is obtained, which allows to generalise the methodology and allows to employ a wide range of constitutive laws. The element is based in three modifications: (a) a classical assumed strain approach for transverse shear strains (b) an assumed strain approach for the in-plane components using information from neighbour elements and (c) an averaging of the volumetric strain over the element. The objective is to use this type of elements for the simulation of shells avoiding transverse shear locking, improving the membrane behaviour of the in-plane triangle and to handle quasi-incompressible materials or materials with isochoric plastic flow. Some examples have been evaluated to show the good performance of the element and results.

A new multi-layer approach for progressive damage simulation in composite laminates based on isogeometric analysis and Kirchhoff-Love shells. Part II: impact modeling

NASA Astrophysics Data System (ADS)

Pigazzini, M. S.; Bazilevs, Y.; Ellison, A.; Kim, H.

2017-11-01

In this two-part paper we introduce a new formulation for modeling progressive damage in laminated composite structures. We adopt a multi-layer modeling approach, based on isogeometric analysis, where each ply or lamina is represented by a spline surface, and modeled as a Kirchhoff-Love thin shell. Continuum damage mechanics is used to model intralaminar damage, and a new zero-thickness cohesive-interface formulation is introduced to model delamination as well as permitting laminate-level transverse shear compliance. In Part I of this series we focus on the presentation of the modeling framework, validation of the framework using standard Mode I and Mode II delamination tests, and assessment of its suitability for modeling thick laminates. In Part II of this series we focus on the application of the proposed framework to modeling and simulation of damage in composite laminates resulting from impact. The proposed approach has significant accuracy and efficiency advantages over existing methods for modeling impact damage. These stem from the use of IGA-based Kirchhoff-Love shells to represent the individual plies of the composite laminate, while the compliant cohesive interfaces enable transverse shear deformation of the laminate. Kirchhoff-Love shells give a faithful representation of the ply deformation behavior, and, unlike solids or traditional shear-deformable shells, do not suffer from transverse-shear locking in the limit of vanishing thickness. This, in combination with higher-order accurate and smooth representation of the shell midsurface displacement field, allows us to adopt relatively coarse in-plane discretizations without sacrificing solution accuracy. Furthermore, the thin-shell formulation employed does not use rotational degrees of freedom, which gives additional efficiency benefits relative to more standard shell formulations.

Effect of the Semiconductor Quantum Dot Shell Structure on Fluorescence Quenching by Acridine Ligand

NASA Astrophysics Data System (ADS)

Linkov, P. A.; Vokhmintcev, K. V.; Samokhvalov, P. S.; Laronze-Cochard, M.; Sapi, J.; Nabiev, I. R.

2018-02-01

The main line of research in cancer treatment is the development of methods for early diagnosis and targeted drug delivery to cancer cells. Fluorescent semiconductor core/shell nanocrystals of quantum dots (e.g., CdSe/ZnS) conjugated with an anticancer drug, e.g., an acridine derivative, allow real-time tracking and control of the process of the drug delivery to tumors. However, linking of acridine derivatives to a quantum dot can be accompanied by quantum dot fluorescence quenching caused by electron transfer from the quantum dot to the organic molecule. In this work, it has been shown that the structure of the shell of the quantum dot plays the decisive role in the process of photoinduced charge transfer from the quantum dot to the acridine ligand, which is responsible for fluorescence quenching. It has been shown that multicomponent ZnS/CdS/ZnS shells of CdSe cores of quantum dots, which have a relatively small thickness, make it possible to significantly suppress a decrease in the quantum yield of fluorescence of quantum dots as compared to both the classical ZnS thin shell and superthick shells of the same composition. Thus, core/multicomponent shell CdSe/ZnS/CdS/ZnS quantum dots can be used as optimal fluorescent probes for the development of systems for diagnosis and treatment of cancer with the use of anticancer compounds based on acridine derivatives.

Reversed field pinch operation with intelligent shell feedback control in EXTRAP T2R

NASA Astrophysics Data System (ADS)

Brunsell, P. R.; Kuldkepp, M.; Menmuir, S.; Cecconello, M.; Hedqvist, A.; Yadikin, D.; Drake, J. R.; Rachlew, E.

2006-11-01

Discharges in the thin shell reversed field pinch (RFP) device EXTRAP T2R without active feedback control are characterized by growth of non-resonant m = 1 unstable resistive wall modes (RWMs) in agreement with linear MHD theory. Resonant m = 1 tearing modes (TMs) exhibit initially fast rotation and the associated perturbed radial fields at the shell are small, but eventually TMs wall-lock and give rise to a growing radial field. The increase in the radial field at the wall due to growing RWMs and wall-locked TMs is correlated with an increase in the toroidal loop voltage, which leads to discharge termination after 3-4 wall times. An active magnetic feedback control system has been installed in EXTRAP T2R. A two-dimensional array of 128 active saddle coils (pair-connected into 64 independent m = 1 coils) is used with intelligent shell feedback control to suppress the m = 1 radial field at the shell. With feedback control, active stabilization of the full toroidal spectrum of 16 unstable m = 1 non-resonant RWMs is achieved, and TM wall locking is avoided. A three-fold extension of the pulse length, up to the power supply limit, is observed. Intelligent shell feedback control is able to maintain the plasma equilibrium for 10 wall times, with plasma confinement parameters sustained at values comparable to those obtained in thick shell devices of similar size.

The Shell of the Invasive Bivalve Species Dreissena polymorpha: Biochemical, Elemental and Textural Investigations

PubMed Central

Broussard, Cédric; Catherinet, Bastien; Plasseraud, Laurent; Alcaraz, Gérard; Bundeleva, Irina; Marin, Frédéric

2016-01-01

The zebra mussel Dreissena polymorpha is a well-established invasive model organism. Although extensively used in environmental sciences, virtually nothing is known of the molecular process of its shell calcification. By describing the microstructure, geochemistry and biochemistry/proteomics of the shell, the present study aims at promoting this species as a model organism in biomineralization studies, in order to establish a bridge with ecotoxicology, while sketching evolutionary conclusions. The shell of D. polymorpha exhibits the classical crossed-lamellar/complex crossed lamellar combination found in several heterodont bivalves, in addition to an external thin layer, the characteristics of which differ from what was described in earlier publication. We show that the shell selectively concentrates some heavy metals, in particular uranium, which predisposes D. polymorpha to local bioremediation of this pollutant. We establish the biochemical signature of the shell matrix, demonstrating that it interacts with the in vitro precipitation of calcium carbonate and inhibits calcium carbonate crystal formation, but these two properties are not strongly expressed. This matrix, although overall weakly glycosylated, contains a set of putatively calcium-binding proteins and a set of acidic sulphated proteins. 2D-gels reveal more than fifty proteins, twenty of which we identify by MS-MS analysis. We tentatively link the shell protein profile of D. polymorpha and the peculiar recent evolution of this invasive species of Ponto-Caspian origin, which has spread all across Europe in the last three centuries. PMID:27213644

Variation in Orthologous Shell-Forming Proteins Contribute to Molluscan Shell Diversity

PubMed Central

Jackson, Daniel J.; Reim, Laurin; Randow, Clemens; Cerveau, Nicolas; Degnan, Bernard M.; Fleck, Claudia

2017-01-01

Abstract Despite the evolutionary success and ancient heritage of the molluscan shell, little is known about the molecular details of its formation, evolutionary origins, or the interactions between the material properties of the shell and its organic constituents. In contrast to this dearth of information, a growing collection of molluscan shell-forming proteomes and transcriptomes suggest they are comprised of both deeply conserved, and lineage specific elements. Analyses of these sequence data sets have suggested that mechanisms such as exon shuffling, gene co-option, and gene family expansion facilitated the rapid evolution of shell-forming proteomes and supported the diversification of this phylum specific structure. In order to further investigate and test these ideas we have examined the molecular features and spatial expression patterns of two shell-forming genes (Lustrin and ML1A2) and coupled these observations with materials properties measurements of shells from a group of closely related gastropods (abalone). We find that the prominent “GS” domain of Lustrin, a domain believed to confer elastomeric properties to the shell, varies significantly in length between the species we investigated. Furthermore, the spatial expression patterns of Lustrin and ML1A2 also vary significantly between species, suggesting that both protein architecture, and the regulation of spatial gene expression patterns, are important drivers of molluscan shell evolution. Variation in these molecular features might relate to certain materials properties of the shells of these species. These insights reveal an important and underappreciated source of variation within shell-forming proteomes that must contribute to the diversity of molluscan shell phenotypes. PMID:28961798

Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution

DOE PAGES

Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.

2017-09-25

Enhanced catalysis for electrochemical oxygen evolution is essential for the efficacy of many renewable energy technologies, including water electrolyzers and metal–air batteries. Recently, Au supports have been shown to enhance the activity of many 3d transition metal-oxide thin films for the oxygen evolution reaction (OER) in alkaline media. In this paper, we translate the beneficial impact of Au supports to high surface area, device-ready core–shell nanoparticles consisting of a Au-core and a metal-oxide shell (Au@M xO y where M = Ni, Co, Fe, and CoFe). Through a systematic evaluation, we establish trends in performance and illustrate the universal activity enhancementmore » when employing the Au-core in the 3d transition metal-oxide nanoparticles. Finally, the highest activity particles, Au@CoFeO x, demonstrate an overpotential of 328 ± 3 mV over a 2 h stability test at 10 mA cm –2, illustrating that strategically coupling Au support and mixed metal-oxide effects in a core–shell nanoparticle morphology is a promising avenue to achieve device-ready, high-performance OER catalysts.« less

Core–Shell Au@Metal-Oxide Nanoparticle Electrocatalysts for Enhanced Oxygen Evolution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strickler, Alaina L.; Escudero-Escribano, Marı́a; Jaramillo, Thomas F.

Enhanced catalysis for electrochemical oxygen evolution is essential for the efficacy of many renewable energy technologies, including water electrolyzers and metal–air batteries. Recently, Au supports have been shown to enhance the activity of many 3d transition metal-oxide thin films for the oxygen evolution reaction (OER) in alkaline media. In this paper, we translate the beneficial impact of Au supports to high surface area, device-ready core–shell nanoparticles consisting of a Au-core and a metal-oxide shell (Au@M xO y where M = Ni, Co, Fe, and CoFe). Through a systematic evaluation, we establish trends in performance and illustrate the universal activity enhancementmore » when employing the Au-core in the 3d transition metal-oxide nanoparticles. Finally, the highest activity particles, Au@CoFeO x, demonstrate an overpotential of 328 ± 3 mV over a 2 h stability test at 10 mA cm –2, illustrating that strategically coupling Au support and mixed metal-oxide effects in a core–shell nanoparticle morphology is a promising avenue to achieve device-ready, high-performance OER catalysts.« less

Soil Calcium Availability Influences Shell Ecophenotype Formation in the Sub-Antarctic Land Snail, Notodiscus hookeri

PubMed Central

Charrier, Maryvonne; Marie, Arul; Guillaume, Damien; Bédouet, Laurent; Le Lannic, Joseph; Roiland, Claire; Berland, Sophie; Pierre, Jean-Sébastien; Le Floch, Marie; Frenot, Yves; Lebouvier, Marc

2013-01-01

Ecophenotypes reflect local matches between organisms and their environment, and show plasticity across generations in response to current living conditions. Plastic responses in shell morphology and shell growth have been widely studied in gastropods and are often related to environmental calcium availability, which influences shell biomineralisation. To date, all of these studies have overlooked micro-scale structure of the shell, in addition to how it is related to species responses in the context of environmental pressure. This study is the first to demonstrate that environmental factors induce a bi-modal variation in the shell micro-scale structure of a land gastropod. Notodiscus hookeri is the only native land snail present in the Crozet Archipelago (sub-Antarctic region). The adults have evolved into two ecophenotypes, which are referred to here as MS (mineral shell) and OS (organic shell). The MS-ecophenotype is characterised by a thick mineralised shell. It is primarily distributed along the coastline, and could be associated to the presence of exchangeable calcium in the clay minerals of the soils. The Os-ecophenotype is characterised by a thin organic shell. It is primarily distributed at high altitudes in the mesic and xeric fell-fields in soils with large particles that lack clay and exchangeable calcium. Snails of the Os-ecophenotype are characterised by thinner and larger shell sizes compared to snails of the MS- ecophenotype, indicating a trade-off between mineral thickness and shell size. This pattern increased along a temporal scale; whereby, older adult snails were more clearly separated into two clusters compared to the younger adult snails. The prevalence of glycine-rich proteins in the organic shell layer of N. hookeri, along with the absence of chitin, differs to the organic scaffolds of molluscan biominerals. The present study provides new insights for testing the adaptive value of phenotypic plasticity in response to spatial and temporal

Micro-Raman investigations of InN-GaN core-shell nanowires on Si (111) substrate

NASA Astrophysics Data System (ADS)

Sangeetha, P.; Jeganathan, K.; Ramakrishnan, V.

2013-06-01

The electron-phonon interactions in InN-GaN core-shell nanowires grown by plasma assisted- molecular beam epitaxy (MBE) on Si (111) substrate have been analysed using micro-Raman spectroscopic technique with the excitation wavelength of 633, 488 and 325 nm. The Raman scattering at 633 nm reveals the characteristic E2 (high) and A1 (LO) phonon mode of InN core at 490 and 590 cm-1 respectively and E2 (high) phonon mode of GaN shell at 573 cm-1. The free carrier concentration of InN core is found to be low in the order ˜ 1016 cm-3 due to the screening of charge carriers by thin GaN shell. Diameter of InN core evaluated using the spatial correlation model is consistent with the transmission electron microscopic measurement of ˜15 nm. The phonon-life time of core-shell nanowire structure is estimated to be ˜0.4 ps. The micro-Raman mapping and its corresponding localised spectra for 325 nm excitation exhibit intense E2 (high) phonon mode of GaN shell at 573 cm-1 as the decrease of laser interaction length and the signal intensity is quenched at the voids due to high spacing of NWs.

Initial postbuckling analysis of elastoplastic thin-shear structures

NASA Technical Reports Server (NTRS)

Carnoy, E. G.; Panosyan, G.

1984-01-01

The design of thin shell structures with respect to elastoplastic buckling requires an extended analysis of the influence of initial imperfections. For conservative design, the most critical defect should be assumed with the maximum allowable magnitude. This defect is closely related to the initial postbuckling behavior. An algorithm is given for the quasi-static analysis of the postbuckling behavior of structures that exhibit multiple buckling points. the algorithm based upon an energy criterion allows the computation of the critical perturbation which will be employed for the definition of the critical defect. For computational efficiency, the algorithm uses the reduced basis technique with automatic update of the modal basis. The method is applied to the axisymmetric buckling of cylindrical shells under axial compression, and conclusions are given for future research.

Analysis of shell type structures subjected to time dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, G. J.; Carlson, R. L.; Riff, R.

1985-01-01

A general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic or static thermomechanical loads is considered. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling and ratchetting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model.

Composted oyster shell as lime fertilizer is more effective than fresh oyster shell.

PubMed

Lee, Young Han; Islam, Shah Md Asraful; Hong, Sun Joo; Cho, Kye Man; Math, Renukaradhya K; Heo, Jae Young; Kim, Hoon; Yun, Han Dae

2010-01-01

Physio-chemical changes in oyster shell were examined, and fresh and composted oyster shell meals were compared as lime fertilizers in soybean cultivation. Structural changes in oyster shell were observed by AFM and FE-SEM. We found that grains of the oyster shell surface became smoother and smaller over time. FT-IR analysis indicated the degradation of a chitin-like compound of oyster shell. In chemical analysis, pH (12.3+/-0.24), electrical conductivity (4.1+/-0.24 dS m(-1)), and alkaline powder (53.3+/-1.12%) were highest in commercial lime. Besides, pH was higher in composted oyster shell meal (9.9+/-0.53) than in fresh oyster shell meal (8.4+/-0.32). The highest organic matter (1.1+/-0.08%), NaCl (0.54+/-0.03%), and moisture (15.1+/-1.95%) contents were found in fresh oyster shell meal. A significant higher yield of soybean (1.33 t ha(-1)) was obtained by applying composted oyster shell meal (a 21% higher yield than with fresh oyster shell meal). Thus composting of oyster shell increases the utility of oyster shell as a liming material for crop cultivation.

Scattering of plane evanescent waves by cylindrical shells and wave vector coupling conditions for exciting flexural waves

NASA Astrophysics Data System (ADS)

Marston, Philip L.

2002-05-01

The coupling of sound to buried targets can be associated with acoustic evanescent waves when the sea bottom is smooth. To understand the excitation of flexural waves on buried shells by acoustic evanescent waves, the partial wave series for the scattering is found for cylindrical shells at normal incidence in an unbounded medium. The formulation uses the simplifications of thin-shell dynamics. In the case of ordinary waves incident on a shell, a ray formulation is available to describe the coupling to subsonic flexural waves [P. L. Marston and N. H. Sun, J. Acoust. Soc. Am. 97, 777-783 (1995)]. When the incident wave is evanescent, the distance between propagating plane wavefronts is smaller than the ordinary acoustical wavelength at the same frequency and the coupling condition for the excitation of flexural waves on shells or plates is modified. Instead of matching the flexural wave number with the propagating part of the acoustic wave number only at the coincidence frequency, a second low-frequency wave number matching condition is found for highly evanescent waves. Numerical evaluation of the modified partial-wave-series appropriate for an evanescent wave is used to investigate the low-frequency coupling of evanescent waves with flexural wave resonances of shells.

Manufacturing and testing a thin glass mirror shell with piezoelectric active control

NASA Astrophysics Data System (ADS)

Spiga, D.; Barbera, M.; Collura, A.; Basso, S.; Candia, R.; Civitani, M.; Di Bella, M.; Di Cicca, G.; Lo Cicero, U.; Lullo, G.; Pelliciari, C.; Riva, M.; Salmaso, B.; Sciortino, L.; Varisco, S.

2015-09-01

Optics for future X-ray telescopes will be characterized by very large aperture and focal length, and will be made of lightweight materials like glass or silicon in order to keep the total mass within acceptable limits. Optical modules based on thin slumped glass foils are being developed at various institutes, aiming at improving the angular resolution to a few arcsec HEW. Thin mirrors are prone to deform, so they require a careful integration to avoid deformations and even correct forming errors. On the other hand, this offers the opportunity to actively correct the residual deformation: a viable possibility to improve the mirror figure is the application of piezoelectric actuators onto the non-optical side of the mirrors, and several groups are already at work on this approach. The concept we are developing consists of actively integrating thin glass foils with piezoelectric patches, fed by voltages driven by the feedback provided by X-rays. The actuators are commercial components, while the tension signals are carried by a printed circuit obtained by photolithography, and the driving electronic is a multi-channel low power consumption voltage supply developed inhouse. Finally, the shape detection and the consequent voltage signal to be provided to the piezoelectric array are determined in X-rays, in intra-focal setup at the XACT facility at INAF/OAPA. In this work, we describe the manufacturing steps to obtain a first active mirror prototype and the very first test performed in X-rays.

Stable and High-Performance Flexible ZnO Thin-Film Transistors by Atomic Layer Deposition.

PubMed

Lin, Yuan-Yu; Hsu, Che-Chen; Tseng, Ming-Hung; Shyue, Jing-Jong; Tsai, Feng-Yu

2015-10-14

Passivation is a challenging issue for the oxide thin-film transistor (TFT) technologies because it requires prolonged high-temperature annealing treatments to remedy defects produced in the process, which greatly limits its manufacturability as well as its compatibility with temperature-sensitive materials such as flexible plastic substrates. This study investigates the defect-formation mechanisms incurred by atomic layer deposition (ALD) passivation processes on ZnO TFTs, based on which we demonstrate for the first time degradation-free passivation of ZnO TFTs by a TiO2/Al2O3 nanolaminated (TAO) film deposited by a low-temperature (110 °C) ALD process. By combining the TAO passivation film with ALD dielectric and channel layers into an integrated low-temperature ALD process, we successfully fabricate flexible ZnO TFTs on plastics. Thanks to the exceptional gas-barrier property of the TAO film (water vapor transmission rate (WVTR)<10(-6) g m(-2) day(-1)) as well as the defect-free nature of the ALD dielectric and ZnO channel layers, the TFTs exhibit excellent device performance with high stability and flexibility: field-effect mobility>20 cm2 V(-1) s(-1), subthreshold swing<0.4 V decade(-1) after extended bias-stressing (>10,000 s), air-storage (>1200 h), and bending (1.3 cm radius for 1000 times).

Variation in Orthologous Shell-Forming Proteins Contribute to Molluscan Shell Diversity.

PubMed

Jackson, Daniel J; Reim, Laurin; Randow, Clemens; Cerveau, Nicolas; Degnan, Bernard M; Fleck, Claudia

2017-11-01

Despite the evolutionary success and ancient heritage of the molluscan shell, little is known about the molecular details of its formation, evolutionary origins, or the interactions between the material properties of the shell and its organic constituents. In contrast to this dearth of information, a growing collection of molluscan shell-forming proteomes and transcriptomes suggest they are comprised of both deeply conserved, and lineage specific elements. Analyses of these sequence data sets have suggested that mechanisms such as exon shuffling, gene co-option, and gene family expansion facilitated the rapid evolution of shell-forming proteomes and supported the diversification of this phylum specific structure. In order to further investigate and test these ideas we have examined the molecular features and spatial expression patterns of two shell-forming genes (Lustrin and ML1A2) and coupled these observations with materials properties measurements of shells from a group of closely related gastropods (abalone). We find that the prominent "GS" domain of Lustrin, a domain believed to confer elastomeric properties to the shell, varies significantly in length between the species we investigated. Furthermore, the spatial expression patterns of Lustrin and ML1A2 also vary significantly between species, suggesting that both protein architecture, and the regulation of spatial gene expression patterns, are important drivers of molluscan shell evolution. Variation in these molecular features might relate to certain materials properties of the shells of these species. These insights reveal an important and underappreciated source of variation within shell-forming proteomes that must contribute to the diversity of molluscan shell phenotypes. © The Author 2017. Published by Oxford University Press on behalf of the Society for Molecular Biology and Evolution.

Growth of fullerene-like carbon nitride thin solid films consisting of cross-linked nano-onions

NASA Astrophysics Data System (ADS)

Czigány, Zs.; Brunell, I. F.; Neidhardt, J.; Hultman, L.; Suenaga, K.

2001-10-01

Fullerene-like CNx (x≈0.12) thin solid films were deposited by reactive magnetron sputtering of graphite in a nitrogen and argon discharge on cleaved NaCl and Si(001) substrates at 450 °C. As-deposited films consist of 5 nm diam CNx nano-onions with shell sizes corresponding to Goldberg polyhedra determined by high-resolution transmission electron microscopy. Electron energy loss spectroscopy revealed that N incorporation is higher in the core of the onions than at the perimeter. N incorporation promotes pentagon formation and provides reactive sites for interlinks between shells of the onions. A model is proposed for the formation of CNx nano-onions by continuous surface nucleation and growth of hemispherical shells.

A Complete Structural Inventory of the Mycobacterial Microcompartment Shell Proteins Constrains Models of Global Architecture and Transport*

PubMed Central

Mallette, Evan

2017-01-01

Bacterial microcompartments are bacterial analogs of eukaryotic organelles in that they spatially segregate aspects of cellular metabolism, but they do so by building not a lipid membrane but a thin polyhedral protein shell. Although multiple shell protein structures are known for several microcompartment types, additional uncharacterized components complicate systematic investigations of shell architecture. We report here the structures of all four proteins proposed to form the shell of an uncharacterized microcompartment designated the Rhodococcus and Mycobacterium microcompartment (RMM), which, along with crystal interactions and docking studies, suggests possible models for the particle's vertex and edge organization. MSM0272 is a typical hexameric β-sandwich shell protein thought to form the bulk of the facet. MSM0273 is a pentameric β-barrel shell protein that likely plugs the vertex of the particle. MSM0271 is an unusual double-ringed bacterial microcompartment shell protein whose rings are organized in an offset position relative to all known related proteins. MSM0275 is related to MSM0271 but self-organizes as linear strips that may line the facet edge; here, the presence of a novel extendable loop may help ameliorate poor packing geometry of the rigid main particle at the angled edges. In contrast to previously characterized homologs, both of these proteins show closed pores at both ends. This suggests a model where key interactions at the vertex and edges are mediated at the inner layer of the shell by MSM0271 (encircling MSM0273) and MSM0275, and the facet is built from MSM0272 hexamers tiling in the outer layer of the shell. PMID:27927988

Stress Analysis of Composite Cylindrical Shells with an Elliptical Cutout

NASA Technical Reports Server (NTRS)

Oterkus, E.; Madenci, E.; Nemeth, M. P.

2007-01-01

A special-purpose, semi-analytical solution method for determining the stress and deformation fields in a thin laminated-composite cylindrical shell with an elliptical cutout is presented. The analysis includes the effects of cutout size, shape, and orientation; non-uniform wall thickness; oval-cross-section eccentricity; and loading conditions. The loading conditions include uniform tension, uniform torsion, and pure bending. The analysis approach is based on the principle of stationary potential energy and uses Lagrange multipliers to relax the kinematic admissibility requirements on the displacement representations through the use of idealized elastic edge restraints. Specifying appropriate stiffness values for the elastic extensional and rotational edge restraints (springs) allows the imposition of the kinematic boundary conditions in an indirect manner, which enables the use of a broader set of functions for representing the displacement fields. Selected results of parametric studies are presented for several geometric parameters that demonstrate that analysis approach is a powerful means for developing design criteria for laminated-composite shells.

Stress Analysis of Composite Cylindrical Shells With an Elliptical Cutout

NASA Technical Reports Server (NTRS)

Nemeth, M. P.; Oterkus, E.; Madenci, E.

2005-01-01

A special-purpose, semi-analytical solution method for determining the stress and deformation fields in a thin laminated-composite cylindrical shell with an elliptical cutout is presented. The analysis includes the effects of cutout size, shape, and orientation; nonuniform wall thickness; oval-cross-section eccentricity; and loading conditions. The loading conditions include uniform tension, uniform torsion, and pure bending. The analysis approach is based on the principle of stationary potential energy and uses Lagrange multipliers to relax the kinematic admissibility requirements on the displacement representations through the use of idealized elastic edge restraints. Specifying appropriate stiffness values for the elastic extensional and rotational edge restraints (springs) allows the imposition of the kinematic boundary conditions in an indirect manner, which enables the use of a broader set of functions for representing the displacement fields. Selected results of parametric studies are presented for several geometric parameters that demonstrate that analysis approach is a powerful means for developing design criteria for laminated-composite shells.

High-Energy Electron Shell in ECR Ion Source:

NASA Astrophysics Data System (ADS)

Niimura, M. G.; Goto, A.; Yano, Y.

1997-05-01

As an injector of cyclotrons and RFQ linacs, ECR ion source (ECRIS) is expected to deliver highly charged ions (HCI) at high beam-current (HBC). Injections of light gases and supplementary electrons have been employed for enhancement of HCI and HBC, respectively. Further amelioration of the performance may be feasible by investigating the hot-electron ring inside an ECRIS. Its existence has been granted because of the MeV of Te observable via X-ray diagnostics. However, its location, acceleration mechanism, and effects on the performance are not well known.We found them by deriving the radially negative potential distribution for an ECRIS from measured endloss-current data. It was evidenced from a hole-burning on the parabolic potential profile (by uniformly distributed warm-electron space charges of 9.5x10^5cm-3) and from a local minimum of the electrostatically-trapped ion distribution. A high-energy electron shell (HEES) was located right on the ECR-radius of 6 cm with shell-halfwidth of 1 cm. Such a thin shell around core plasma can only be generated by the Sadeev-Shapiro or v_phxBz acceleration mechanism that can raise Te up to a relativistic value. Here, v_ph is the phase velocity of ES Bernstein waves propagating backwards against incident microwave and Bz the axial mirror magnetic field. The HEES carries diamagnetic current which reduces the core magnetic pressure, thereby stabilizing the ECR surface against driftwave instabilities similarly to gas-mixing.

Comment on Peck et al: Vulnerability of pteropod (Limacina helicina) to ocean acidification: shell dissolution occurs despite an intact organic layer

NASA Astrophysics Data System (ADS)

Bednaršek, N.; Johnson, J.; Feely, R. A.

2016-05-01

Pteropods have been recognized as one of the most sensitive marine organisms to ocean acidification (OA). Their susceptibility is mostly related to rapid shell dissolution, which is correlated with exposure to waters undersaturated with respect to aragonite (Ωar≤ 1) (e.g., Lischka et al., 2011; Bednaršek et al., 2012a,b, 2014a,b; Busch et al., 2014). Increased dissolution weakens the shell, increases vulnerability to predation and infection, and imposes an energetic cost. The rapidity of shell dissolution is attributed to the combination of metastable aragonitic crystal structure of shells that are among the thinnest known for calcifying organisms, and an extremely thin outer organic layer (i.e. periostracum <1 μm thick), suggesting insufficient protection against shell dissolution at Ωar≤1 (Bednaršek et al., 2014b). The periostracum generally consists of polysaccharide and proteinaceous components (Gaffey and Bronnimann, 1993) but varies significantly in its structure and composition amongst taxa.

Direct Polishing of Full-Shell, High-Resolution X-Ray Optics

NASA Technical Reports Server (NTRS)

Roche, Jacqueline M.; Gubarev, Mikhail V.; Smith, W. Scott; O'Dell, Stephen L.; Kolodziejczak, Jeffrey J.; Weisskopf, Martin C.; Ramsey, Brian D.; Elsner, Ronald F.

2014-01-01

Future x-ray telescopes will likely require lightweight mirrors to attain the large collecting areas needed to accomplish the science objectives. Understanding and demonstrating processes now is critical to achieving sub-arcsecond performance in the future. Consequently, designs not only of the mirrors but of fixtures for supporting them during fabrication, metrology, handling, assembly, and testing must be adequately modeled and verified. To this end, MSFC is using finite-element modeling to study the effects of mounting on thin, full-shell grazing-incidence mirrors, during all processes leading to a flight.

Architecture in outer space. [multilayer shell systems filled with gas

NASA Technical Reports Server (NTRS)

Pokrovskiy, G. I.

1974-01-01

Mulilayer thin film structures consisting of systems of shells filled with gas at some pressure are recommended for outer space structures: Large mirrors to collect light and radio waves, protection against meteoric impact and damage, and for connectors between state space stations in the form of orbital rings. It is projected that individual orbital rings will multiply and completely seal a star trapping its high temperature radiation and transforming it into low temperature infrared and short wave radio emission; this radiation energy could be utilized for technological and biological processes.

O-shell emission of heavy atoms in an optically thin tokamak plasma

NASA Astrophysics Data System (ADS)

Finkenthal, M.; Lippmann, S.; Huang, L. K.; Zwicker, A.; Moos, H. W.; Goldstein, W. H.; Osterheld, A. L.

1992-04-01

Heavy atoms Au (Z=79), Pb (Z=82), Bi (Z=83), and U (Z=92) have been introduced in the low-density (ne~1013 cm-3) high-temperature (Te>=1 keV) TEXT tokamak (Fusion Research Center, University of Texas at Austin) plasma. The emission has been measured in the 50-200-Å range using a photometrically calibrated, time-resolving grazing-incidence spectrometer. The O-shell ion emission has been identified by comparison with ab initio energy-level calculations and line-intensity predictions of collisional radiative models for various charge states with 5p65dk ground-state configurations.

Acetabular shell deformation as a function of shell stiffness and bone strength.

PubMed

Dold, Philipp; Pandorf, Thomas; Flohr, Markus; Preuss, Roman; Bone, Martin C; Joyce, Tom J; Holland, James; Deehan, David

2016-04-01

Press-fit acetabular shells used for hip replacement rely upon an interference fit with the bone to provide initial stability. This process may result in deformation of the shell. This study aimed to model shell deformation as a process of shell stiffness and bone strength. A cohort of 32 shells with two different wall thicknesses (3 and 4 mm) and 10 different shell sizes (44- to 62-mm outer diameter) were implanted into eight cadavers. Shell deformation was then measured in the cadavers using a previously validated ATOS Triple Scan III optical system. The shell-bone interface was then considered as a spring system according to Hooke's law and from this the force exerted on the shell by the bone was calculated using a combined stiffness consisting of the measured shell stiffness and a calculated bone stiffness. The median radial stiffness for the 3-mm wall thickness was 4192 N/mm (range, 2920-6257 N/mm), while for the 4-mm wall thickness the median was 9633 N/mm (range, 6875-14,341 N/mm). The median deformation was 48 µm (range, 3-187 µm), while the median force was 256 N (range, 26-916 N). No statistically significant correlation was found between shell stiffness and deformation. Deformation was also found to be not fully symmetric (centres 180° apart), with a median angle discrepancy of 11.5° between the two maximum positive points of deformation. Further work is still required to understand how the bone influences acetabular shell deformation. © IMechE 2016.

Shell-isolated nanoparticle-enhanced Raman spectroscopy: principle and applications (Presentation Recording)

NASA Astrophysics Data System (ADS)

Li, Jian-Feng; Tian, Zhong-Qun

2015-08-01

Surface-enhanced Raman spectroscopy (SERS) is a powerful technique that yields fingerprint vibrational information with ultra-high sensitivity. However, only roughened Ag, Au and Cu surfaces can generate strong SERS effect. The lack of materials and morphology generality has severely limited the breadth of SERS practical applications on surface science, electrochemistry and catalysis. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) was therefore invented to break the long-standing limitation of SERS. In SHINERS, Au@SiO2 core-shell nanoparticles were rationally designed. The gold core acts as plasmonic antenna and encapsulated by an ultra-thin, uniform and pinhole-free silica shell, can provide high electromagnetic field to enhance the Raman signals of probed molecules. The inert silica shell acts as tunneling barrier prevents the core from interacting with the environment. SHINERS has already been applied to a number of challenging systems, such as hydrogen and CO on Pt(hkl) and Rh(hkl), which can't be realized by traditional SERS. Combining with electrochemical methods, we has investigated the adsorption processes of pyridine at the Au(hkl) single crystal/solution interface, and in-situ monitored the surface electro-oxidation at Au(hkl) electrodes. These pioneering studies demonstrate convincingly the ability of SHINERS in exploring correlations between structure and reactivity as well as in monitoring intermediates at the interfaces. SHINERS was also explored from semiconductor surface for industry, to living bacteria for life science, and to pesticide residue detection for food safety. The concept of shell-isolated nanoparticle-enhancement is being applied to other spectroscopies such as infrared absorption, sum frequency generation and fluorescence. Jian-Feng Li et al., Nature, 2010, 464, 392-395.

Plume Activity and Tidal Deformation on Enceladus Influenced by Faults and Variable Ice Shell Thickness

NASA Astrophysics Data System (ADS)

Běhounková, Marie; Souček, Ondřej; Hron, Jaroslav; Čadek, Ondřej

2017-09-01

We investigated the effect of variations in ice shell thickness and of the tiger stripe fractures crossing Enceladus' south polar terrain on the moon's tidal deformation by performing finite element calculations in three-dimensional geometry. The combination of thinning in the polar region and the presence of faults has a synergistic effect that leads to an increase of both the displacement and stress in the south polar terrain by an order of magnitude compared to that of the traditional model with a uniform shell thickness and without faults. Assuming a simplified conductive heat transfer and neglecting the heat sources below the ice shell, we computed the global heat budget of the ice shell. For the inelastic properties of the shell described by a Maxwell viscoelastic model, we show that unrealistically low average viscosity of the order of 10^{13} Pa s is necessary for preserving the volume of the ocean, suggesting the important role of the heat sources in the deep interior. Similarly, low viscosity is required to predict the observed delay of the plume activity, which hints at other delaying mechanisms than just the viscoelasticity of the ice shell. The presence of faults results in large spatial and temporal heterogeneity of geysering activity compared to the traditional models without faults. Our model contributes to understanding the physical mechanisms that control the fault activity, and it provides potentially useful information for future missions that will sample the plume for evidence of life.

Free vibrations of thin-walled semicircular graphite-epoxy composite frames

NASA Technical Reports Server (NTRS)

Carden, Huey D.; Noor, Ahmed K.; Peters, Jeanne M.

1990-01-01

A detailed study is made of the effects of variations in lamination and material parameters of thin walled composite frames on their vibrational characteristics. The structures considered are semicircular thin walled frames with I and J sections. The flanges and webs of the frames are modeled by using 2-D shell and plate finite elements. A mixed formulation is used with the fundamental unknowns consisting of both the generalized displacements and stress resultants in the frame. The frequencies and modes predicted by the 2-D finite element model are compared with those obtained from experiments, as well as with the predictions of a non-dimensional thin walled beam finite element model. A detailed study is made of the sensitivity of the vibrational response to variations in the fiber orientation, material properties of the individual layers, and boundary conditions.

Free vibrations of thin-walled semicircular graphite-epoxy composite frames

NASA Technical Reports Server (NTRS)

Noor, Ahmed K.; Carden, Huey D.; Peters, Jeanne M.

1990-01-01

A detailed study is made of the effects of variations in lamination and material parameters of thin walled composite frames on their vibrational characteristics. The structures considered are semicircular thin walled frames with I and J sections. The flanges and webs of the frames are modelled by using 2-D shell and plate finite elements. A mixed formulation is used with the fundamental unknowns consisting of both the generalized displacements and stress resultants in the frames. The frequencies and modes predicted by the 2-D finite element model are compared with those obtained from experiments, as well as with the predictions of a 1-D thin walled beam finite element model. A detailed study is made of the sensitivity of the vibrational response to variations in the fiber orientation, material properties of the individual layers, and boundary conditions.

Shock Response and Dynamic Failure of Spatially Tailored Aero-Thermal Structures

DTIC Science & Technology

2012-09-15

Deformation Behavior of Nanolaminated Titanium Aluminum Carbide. 36th International Conference and Exposition on Advanced Ceramics and Composites ...Deformation Behavior of Nanolaminated Titanium Aluminum Carbide. Effect of Strain-rate and Temperature on Dynamic Deformation of Nanolaminated...conditions, we are unaware of any studies published in the open literature on the effect of high strain rate deformation behavior of Ti2AlC at room or

Limpets counteract ocean acidification induced shell corrosion by thickening of aragonitic shell layers

NASA Astrophysics Data System (ADS)

Langer, G.; Nehrke, G.; Baggini, C.; Rodolfo-Metalpa, R.; Hall-Spencer, J.; Bijma, J.

2014-08-01

Specimens of the patellogastropod limpet Patella caerulea were collected within (pHlow-shells) and outside (pHn-shells) a CO2 vent site at Ischia, Italy. Four pHlow-shells and four pHn-shells were sectioned transversally and scanned for polymorph distribution by means of confocal Raman microscopy. The pHlow-shells displayed a twofold increase in aragonite area fraction and size normalised aragonite area. Size normalised calcite area was halved in pHlow-shells. Taken together with the increased apical and the decreased flank size normalised thickness of the pHlow-shells, these data led us to conclude that low pH exposed P. caerulea specimens counteract shell dissolution by enhanced shell production. The latter is different from normal elongation growth and proceeds through addition of aragonitic layers only, while the production of calcitic layers is confined to elongation growth. Therefore aragonite cannot be regarded as a per se disadvantageous polymorph under ocean acidification conditions.

Limpets counteract ocean acidification induced shell corrosion by thickening of aragonitic shell layers

NASA Astrophysics Data System (ADS)

Langer, G.; Nehrke, G.; Baggini, C.; Rodolfo-Metalpa, R.; Hall-Spencer, J. M.; Bijma, J.

2014-12-01

Specimens of the patellogastropod limpet Patella caerulea were collected within (pHlow-shells) and outside (pHn-shells) a CO2 vent site at Ischia, Italy. Four pHlow-shells and four pHn-shells were sectioned transversally and scanned for polymorph distribution by means of confocal Raman microscopy. The pHlow-shells displayed a twofold increase in aragonite area fraction and size-normalised aragonite area. Size-normalised calcite area was halved in pHlow-shells. Taken together with the increased apical and the decreased flank size-normalised thickness of the pHlow-shells, these data led us to conclude that low-pH-exposed P. caerulea specimens counteract shell dissolution by enhanced shell production. This is different from normal elongation growth and proceeds through addition of aragonitic parts only, while the production of calcitic parts is confined to elongation growth. Therefore, aragonite cannot be regarded as a disadvantageous polymorph per se under ocean acidification conditions.

Electronic and Optical Properties of Core/Shell Pb16X16/Cd52X52 (X =S, Se, Te) Quantum Dots

NASA Astrophysics Data System (ADS)

Tamukong, Patrick; Mayo, Michael; Kilina, Svetlana

2015-03-01

The electronic and optoelectronic properties of semiconductor quantum dots (QDs) are mediated by surface defects due to the presence of dangling bonds producing trap states within the HOMO-LUMO energy gap, and contributing to fluorescence quenching. Surface capping ligands are generally used to alleviate this problem and increase the quantum yields of QDs. An alternative way is to synthesize core-shell QD structures; i.e., a QD core with a shell of another semiconductor material. We have investigated the effects of Cd52X52 shells on the photoexcited dynamics of Pb16X16 (X =S, Se, Te) QDs. The thin (~ 0.50 nm) shells were found to result largely in type I core/shell structures and a blue shift of the absorption spectra. Our studies revealed fairly strong core-shell hybridization in the electronic states close to the conduction band (CB) edge for Pb16S16andPb16Se16 cores, whereas for the Pb16Te16 core, such CB states were largely shell-like in nature. Nonadiabatic DFT-based dynamics, coupled with the surface hopping method, was used to study the effects of the core and shell compositions on energy relaxation rates in these systems.

Shell concrete pavement.

DOT National Transportation Integrated Search

1966-10-01

This report describes the testing performed with reef shell, clam shell and a combination of reef and clam shell used as coarse aggregate to determine if a low modulus concrete could be developed for use as a base material as an alternate to the pres...

M-shell electron capture and direct ionization of gold by 25-MeV carbon and 32-MeV oxygen ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andrews, M.C.; McDaniel, F.D.; Duggan, J.L.

1984-01-01

M-shell x-ray production cross sections have been measured for thin solid targets of Au for 25 MeV /sup 12/C/sup q+/ (q = 4, 5, 6) and for 32 MeV /sup 16/O/sup q+/ (q = 5, 7, 8). The microscopic cross sections were determined from measurements made with targets ranging in thickness from 0.5 to 100 ..mu..g/cm/sup 2/. For projectiles with one or two K-shell vacancies, the M-shell x-ray production cross sections are found to be enhanced over those by projectiles without a K-shell vacancy. The sum of direct ionization to the continuum (DI) and electron capture (EC) to the L,more » M, N ... shells and EC to the K-shell of the projectile have been extracted from the data. The results are compared to the predictions of first Born theories i.e. PWBA for DI and OBK of Nikolaev for EC and the ECPSSR approach that accounts for energy loss, Coulomb deflection and relativistic effects in the perturbed stationary state theory. 25 references, 3 figures, 1 table.« less

Asymptotic analysis of the shear strain effect on the wave characteristics of a multilayered cylindrical shell filled with fluid

NASA Astrophysics Data System (ADS)

Amenzade, R. Yu.; Kiiko, I. A.

2007-06-01

It is commonly assumed that the theory based on the Kirchhoff hypotheses describes the properties inherent in the wave processes occurring in shells filled with fluids. But there are several new effects that cannot be described by this theory (in particular, the appearance of new types of waves). In this paper, we present a linearized description of axisymmetric wave motion of a perfect incompressible fluid in a multilayered cylindrical shell with allowance for shear strain; the shell is assumed to be infinite and simply supported. This description is aimed at finding new mechanical effects and hence at estimating the influence of the multiple layers and the shear strain on the wave characteristics. In a sense, it generalizes and develops well-known studies of this type. Practice necessitates deriving equations constructed under the assumption that the physical and mechanical properties of the shell material are inhomogeneous along the thickness direction or the shell is multilayered; the development of refined theories (compared with the classical theory based on the Kirchhoff—Love straight normal hypothesis) is also inspired by practice. This is primarily related to the fact that multilayered thin-walled shells made of composite materials are used in various fields of technology. It is of interest to note that, as a result of long evolution, the phenomenon of being multilayered also predominates in living organisms. For example, this is typical of big blood vessels [1] (arteries and veins). In [2], on the basis of a three-dimensional variational principle of mixed type, the equations of motion and physical relations for elastic anisotropic shells rigidly inhomogeneous in the thickness direction are derived under the assumptions of the theory of thin shells and with shear strains taken into account. It is also noted that the case of multilayered shells can be modeled by introducing functions with integrable singularities. When studying wave propagation in

Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

DOE PAGES

Zhang, Sen; Hao, Yizhou; Su, Dong; ...

2014-10-28

We report a size-controllable synthesis of monodisperse core/shell Ni/FePt nanoparticles (NPs) via a seed-mediated growth and their subsequent conversion to Ni/Pt NPs. Preventing surface oxidation of the Ni seeds is essential for the growth of uniform FePt shells. These Ni/FePt NPs have a thin (≈ 1 nm) FePt shell, and can be converted to Ni/Pt by acetic acid wash to yield active catalysts for oxygen reduction reaction (ORR). Tuning the core size allow for optimization of their electrocatalytic activity. The specific activity and mass activity of 4.2 nm/0.8 nm core/shell Ni/FePt reach 1.95 mA/cm² and 490 mA/mg Pt at 0.9more » V ( vs. reversible hydrogen electrode, RHE), which are much higher than those of benchmark commercial Pt catalyst (0.34 mA/cm² and 92 mA/mg Pt at 0.9 V). Our studies provide a robust approach to monodisperse core/shell NPs with non-precious metal core, making it possible to develop advanced NP catalysts with ultralow Pt content for ORR and many other heterogeneous reactions.« less

A Complete Structural Inventory of the Mycobacterial Microcompartment Shell Proteins Constrains Models of Global Architecture and Transport.

PubMed

Mallette, Evan; Kimber, Matthew S

2017-01-27

Bacterial microcompartments are bacterial analogs of eukaryotic organelles in that they spatially segregate aspects of cellular metabolism, but they do so by building not a lipid membrane but a thin polyhedral protein shell. Although multiple shell protein structures are known for several microcompartment types, additional uncharacterized components complicate systematic investigations of shell architecture. We report here the structures of all four proteins proposed to form the shell of an uncharacterized microcompartment designated the Rhodococcus and Mycobacterium microcompartment (RMM), which, along with crystal interactions and docking studies, suggests possible models for the particle's vertex and edge organization. MSM0272 is a typical hexameric β-sandwich shell protein thought to form the bulk of the facet. MSM0273 is a pentameric β-barrel shell protein that likely plugs the vertex of the particle. MSM0271 is an unusual double-ringed bacterial microcompartment shell protein whose rings are organized in an offset position relative to all known related proteins. MSM0275 is related to MSM0271 but self-organizes as linear strips that may line the facet edge; here, the presence of a novel extendable loop may help ameliorate poor packing geometry of the rigid main particle at the angled edges. In contrast to previously characterized homologs, both of these proteins show closed pores at both ends. This suggests a model where key interactions at the vertex and edges are mediated at the inner layer of the shell by MSM0271 (encircling MSM0273) and MSM0275, and the facet is built from MSM0272 hexamers tiling in the outer layer of the shell. © 2017 by The American Society for Biochemistry and Molecular Biology, Inc.

A compact proton spectrometer for measurement of the absolute DD proton spectrum from which yield and ρR are determined in thin-shell inertial-confinement-fusion implosions.

PubMed

Rosenberg, M J; Zylstra, A B; Frenje, J A; Rinderknecht, H G; Johnson, M Gatu; Waugh, C J; Séguin, F H; Sio, H; Sinenian, N; Li, C K; Petrasso, R D; Glebov, V Yu; Hohenberger, M; Stoeckl, C; Sangster, T C; Yeamans, C B; LePape, S; Mackinnon, A J; Bionta, R M; Talison, B; Casey, D T; Landen, O L; Moran, M J; Zacharias, R A; Kilkenny, J D; Nikroo, A

2014-10-01

A compact, step range filter proton spectrometer has been developed for the measurement of the absolute DD proton spectrum, from which yield and areal density (ρR) are inferred for deuterium-filled thin-shell inertial confinement fusion implosions. This spectrometer, which is based on tantalum step-range filters, is sensitive to protons in the energy range 1-9 MeV and can be used to measure proton spectra at mean energies of ∼1-3 MeV. It has been developed and implemented using a linear accelerator and applied to experiments at the OMEGA laser facility and the National Ignition Facility (NIF). Modeling of the proton slowing in the filters is necessary to construct the spectrum, and the yield and energy uncertainties are ±<10% in yield and ±120 keV, respectively. This spectrometer can be used for in situ calibration of DD-neutron yield diagnostics at the NIF.

Plume Activity and Tidal Deformation on Enceladus Influenced by Faults and Variable Ice Shell Thickness

PubMed Central

Souček, Ondřej; Hron, Jaroslav; Čadek, Ondřej

2017-01-01

Abstract We investigated the effect of variations in ice shell thickness and of the tiger stripe fractures crossing Enceladus' south polar terrain on the moon's tidal deformation by performing finite element calculations in three-dimensional geometry. The combination of thinning in the polar region and the presence of faults has a synergistic effect that leads to an increase of both the displacement and stress in the south polar terrain by an order of magnitude compared to that of the traditional model with a uniform shell thickness and without faults. Assuming a simplified conductive heat transfer and neglecting the heat sources below the ice shell, we computed the global heat budget of the ice shell. For the inelastic properties of the shell described by a Maxwell viscoelastic model, we show that unrealistically low average viscosity of the order of 1013 Pa s is necessary for preserving the volume of the ocean, suggesting the important role of the heat sources in the deep interior. Similarly, low viscosity is required to predict the observed delay of the plume activity, which hints at other delaying mechanisms than just the viscoelasticity of the ice shell. The presence of faults results in large spatial and temporal heterogeneity of geysering activity compared to the traditional models without faults. Our model contributes to understanding the physical mechanisms that control the fault activity, and it provides potentially useful information for future missions that will sample the plume for evidence of life. Key Words: Enceladus—Tidal deformation—Faults—Variable ice shell thickness—Tidal heating—Plume activity and timing. Astrobiology 17, 941–954. PMID:28816521

A non-LTE kinetic model for quick analysis of K-shell spectra from Z-pinch plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, J., E-mail: s.duan@163.com; Huang, X. B., E-mail: s.duan@163.com; Cai, H. C., E-mail: s.duan@163.com

Analyzing and modeling K-shell spectra emitted by low-to moderate-atomic number plasma is a useful and effective way to retrieve temperature density of z-pinch plasmas. In this paper, a non-LTE population kinetic model for quick analysis of K-shell spectra was proposed. The model contains ionization stages from bare nucleus to neutral atoms and includes all the important atomic processes. In the present form of the model, the plasma is assumed to be both optically thin and homogeneous with constant temperature and density, and only steady-state situation is considered. According to the detailed calculations for aluminum plasmas, contours of ratios of certainmore » K-shell lines in electron temperature and density plane as well as typical synthesized spectra were presented and discussed. The usefulness of the model is demonstrated by analyzing the spectrum from a neon gas-puff Z-pinch experiment performed on a 1 MA pulsed-power accelerator.« less

A Variational Principle for Reconstruction of Elastic Deformations in Shear Deformable Plates and Shells

NASA Technical Reports Server (NTRS)

Tessler, Alexander; Spangler, Jan L.

2003-01-01

A variational principle is formulated for the inverse problem of full-field reconstruction of three-dimensional plate/shell deformations from experimentally measured surface strains. The formulation is based upon the minimization of a least squares functional that uses the complete set of strain measures consistent with linear, first-order shear-deformation theory. The formulation, which accommodates for transverse shear deformation, is applicable for the analysis of thin and moderately thick plate and shell structures. The main benefit of the variational principle is that it is well suited for C(sup 0)-continuous displacement finite element discretizations, thus enabling the development of robust algorithms for application to complex civil and aeronautical structures. The methodology is especially aimed at the next generation of aerospace vehicles for use in real-time structural health monitoring systems.

The effect of ring distortions on buckling of blunt conical shells. [Viking mission aeroshell

NASA Technical Reports Server (NTRS)

Heard, W. L., Jr.; Anderson, M. S.; Stephens, W. B.

1975-01-01

A rigorous analytical study of cones stiffened by many thin-gage, open-section rings is presented. The results are compared with data previously obtained from uniform pressure tests of the Viking mission flight aeroshell and of the Viking structural prototype aeroshells. A conventional analysis, in which the rings are modeled as discrete rigid cross sections, is shown to lead to large, unconservative strength predictions. A more sophisticated technique of modeling the rings as shell branches leads to much more realistic strength predictions and more accurately predicts the failure modes. It is also shown that if a small initial imperfection proportional to the shape of the buckling mode is assumed, the critical buckling modes from analysis and test are in agreement. However, the reduction in buckling strength from the perfect-shell predictions is small.

Time-frequency analysis of the bistatic acoustic scattering from a spherical elastic shell.

PubMed

Anderson, Shaun D; Sabra, Karim G; Zakharia, Manell E; Sessarego, Jean-Pierre

2012-01-01

The development of low-frequency sonar systems, using, for instance, a network of autonomous systems in unmanned vehicles, provides a practical means for bistatic measurements (i.e., when the source and receiver are widely separated) allowing for multiple viewpoints of the target of interest. Time-frequency analysis, in particular, Wigner-Ville analysis, takes advantage of the evolution time dependent aspect of the echo spectrum to differentiate a man-made target, such as an elastic spherical shell, from a natural object of the similar shape. A key energetic feature of fluid-loaded and thin spherical shell is the coincidence pattern, also referred to as the mid-frequency enhancement (MFE), that results from antisymmetric Lamb-waves propagating around the circumference of the shell. This article investigates numerically the bistatic variations of the MFE with respect to the monostatic configuration using the Wigner-Ville analysis. The observed time-frequency shifts of the MFE are modeled using a previously derived quantitative ray theory by Zhang et al. [J. Acoust. Soc. Am. 91, 1862-1874 (1993)] for spherical shell's scattering. Additionally, the advantage of an optimal array beamformer, based on joint time delays and frequency shifts is illustrated for enhancing the detection of the MFE recorded across a bistatic receiver array when compared to a conventional time-delay beamformer. © 2012 Acoustical Society of America.

Acoustic scattering from a finite cylindrical shell with evenly spaced stiffeners: Experimental investigation

NASA Astrophysics Data System (ADS)

Liétard, R.; Décultot, D.; Maze, G.; Tran-van-Nhieu, M.

2005-10-01

The influence of evenly spaced ribs (internal rings) on the acoustic scattering from a finite cylindrical shell is examined over the dimensionless frequency range 1thin shell theory [Tran-Van-Nhieu, J. Acoust. Soc. Am. 110, 2858-2866 (2001)] and a simple scattering/interference calculation.

Ultra-high-performance core–shell structured Ru@Pt/C catalyst prepared by a facile pulse electrochemical deposition method

DOE PAGES

Chen, Dan; Li, Yuexia; Liao, Shijun; ...

2015-08-03

Core–shell structured catalysts, made by placing either a monolayer or a thin layer of a noble metal on relatively cheap core-metal nanoparticles, are fascinating and promising fuel cell catalysts due to their high utilization of noble metals. Here, we report our development of a core–shell structured catalyst, Ru@Pt/C, generated by a novel and facile pulse electrochemical deposition (PED) approach. We demonstrate that compared with a commercial Pt/C catalyst, this novel catalyst achieves over four times higher mass activity towards the anodic oxidation of methanol, and 3.6 times higher mass activity towards the cathodic reduction of oxygen. Importantly, we find thatmore » the intrinsic activity of Pt in this Ru@Pt/C catalyst is doubled due to the formation of the core–shell structure. The catalyst also shows superior stability: even after 2000 scans, it still retains up to 90% of the peak current. As a result, our findings demonstrate that this novel PED approach is a promising method for preparing high-performance core–shell catalysts for fuel cell applications.« less

Comparative study of the shell development of hard- and soft-shelled turtles

PubMed Central

Nagashima, Hiroshi; Shibata, Masahiro; Taniguchi, Mari; Ueno, Shintaro; Kamezaki, Naoki; Sato, Noboru

2014-01-01

The turtle shell provides a fascinating model for the investigation of the evolutionary modifications of developmental mechanisms. Different conclusions have been put forth for its development, and it is suggested that one of the causes of the disagreement could be the differences in the species of the turtles used – the differences between hard-shelled turtles and soft-shelled turtles. To elucidate the cause of the difference, we compared the turtle shell development in the two groups of turtle. In the dorsal shell development, these two turtle groups shared the gene expression profile that is required for formation, and shared similar spatial organization of the anatomical elements during development. Thus, both turtles formed the dorsal shell through a folding of the lateral body wall, and the Wnt signaling pathway appears to have been involved in the development. The ventral portion of the shell, on the other hand, contains massive dermal bones. Although expression of HNK-1 epitope has suggested that the trunk neural crest contributed to the dermal bones in the hard-shelled turtles, it was not expressed in the initial anlage of the skeletons in either of the types of turtle. Hence, no evidence was found that would support a neural crest origin. PMID:24754673

Comparative study of the shell development of hard- and soft-shelled turtles.

PubMed

Nagashima, Hiroshi; Shibata, Masahiro; Taniguchi, Mari; Ueno, Shintaro; Kamezaki, Naoki; Sato, Noboru

2014-07-01

The turtle shell provides a fascinating model for the investigation of the evolutionary modifications of developmental mechanisms. Different conclusions have been put forth for its development, and it is suggested that one of the causes of the disagreement could be the differences in the species of the turtles used - the differences between hard-shelled turtles and soft-shelled turtles. To elucidate the cause of the difference, we compared the turtle shell development in the two groups of turtle. In the dorsal shell development, these two turtle groups shared the gene expression profile that is required for formation, and shared similar spatial organization of the anatomical elements during development. Thus, both turtles formed the dorsal shell through a folding of the lateral body wall, and the Wnt signaling pathway appears to have been involved in the development. The ventral portion of the shell, on the other hand, contains massive dermal bones. Although expression of HNK-1 epitope has suggested that the trunk neural crest contributed to the dermal bones in the hard-shelled turtles, it was not expressed in the initial anlage of the skeletons in either of the types of turtle. Hence, no evidence was found that would support a neural crest origin. © 2014 Anatomical Society.

Large uniaxial magnetostriction with sign inversion at the first order phase transition in the nanolaminated Mn2GaC MAX phase.

PubMed

Novoselova, Iuliia P; Petruhins, Andrejs; Wiedwald, Ulf; Ingason, Árni Sigurdur; Hase, Thomas; Magnus, Fridrik; Kapaklis, Vassilios; Palisaitis, Justinas; Spasova, Marina; Farle, Michael; Rosen, Johanna; Salikhov, Ruslan

2018-02-08

In 2013, a new class of inherently nanolaminated magnetic materials, the so called magnetic MAX phases, was discovered. Following predictive material stability calculations, the hexagonal Mn 2 GaC compound was synthesized as hetero-epitaxial films containing Mn as the exclusive M-element. Recent theoretical and experimental studies suggested a high magnetic ordering temperature and non-collinear antiferromagnetic (AFM) spin states as a result of competitive ferromagnetic and antiferromagnetic exchange interactions. In order to assess the potential for practical applications of Mn 2 GaC, we have studied the temperature-dependent magnetization, and the magnetoresistive, magnetostrictive as well as magnetocaloric properties of the compound. The material exhibits two magnetic phase transitions. The Néel temperature is T N  ~ 507 K, at which the system changes from a collinear AFM state to the paramagnetic state. At T t  = 214 K the material undergoes a first order magnetic phase transition from AFM at higher temperature to a non-collinear AFM spin structure. Both states show large uniaxial c-axis magnetostriction of 450 ppm. Remarkably, the magnetostriction changes sign, being compressive (negative) above T t and tensile (positive) below the T t . The sign change of the magnetostriction is accompanied by a sign change in the magnetoresistance indicating a coupling among the spin, lattice and electrical transport properties.

Core-shell titanium dioxide-titanium nitride nanotube arrays with near-infrared plasmon resonances

NASA Astrophysics Data System (ADS)

Farsinezhad, Samira; Shanavas, Thariq; Mahdi, Najia; Askar, Abdelrahman M.; Kar, Piyush; Sharma, Himani; Shankar, Karthik

2018-04-01

Titanium nitride (TiN) is a ceramic with high electrical conductivity which in nanoparticle form, exhibits localized surface plasmon resonances (LSPRs) in the visible region of the solar spectrum. The ceramic nature of TiN coupled with its dielectric loss factor being comparable to that of gold, render it attractive for CMOS polarizers, refractory plasmonics, surface-enhanced Raman scattering and a whole host of sensing applications. We report core-shell TiO2-TiN nanotube arrays exhibiting LSPR peaks in the range 775-830 nm achieved by a simple, solution-based, low cost, large area-compatible fabrication route that does not involve laser-writing or lithography. Self-organized, highly ordered TiO2 nanotube arrays were grown by electrochemical anodization of Ti thin films on fluorine-doped tin oxide-coated glass substrates and then conformally coated with a thin layer of TiN using atomic layer deposition. The effects of varying the TiN layer thickness and thermal annealing on the LSPR profiles were also investigated. Modeling the TiO2-TiN core-shell nanotube structure using two different approaches, one employing effective medium approximations coupled with Fresnel coefficients, resulted in calculated optical spectra that closely matched the experimentally measured spectra. Modeling provided the insight that the observed near-infrared resonance was not collective in nature, and was mainly attributable to the longitudinal resonance of annular nanotube-like TiN particles redshifted due to the presence of the higher permittivity TiO2 matrix. The resulting TiO2-TiN core-shell nanotube structures also function as visible light responsive photocatalysts, as evidenced by their photoelectrochemical water-splitting performance under light emitting diode illumination using 400, 430 and 500 nm photons.

Influence of the shell thickness and charge distribution on the effective interaction between two like-charged hollow spheres.

PubMed

Angelescu, Daniel G; Caragheorgheopol, Dan

2015-10-14

The mean-force and the potential of the mean force between two like-charged spherical shells were investigated in the salt-free limit using the primitive model and Monte Carlo simulations. Apart from an angular homogeneous distribution, a discrete charge distribution where point charges localized on the shell outer surface followed an icosahedral arrangement was considered. The electrostatic coupling of the model system was altered by the presence of mono-, trivalent counterions or small dendrimers, each one bearing a net charge of 9 e. We analyzed in detail how the shell thickness and the radial and angular distribution of the shell charges influenced the effective interaction between the shells. We found a sequence of the potential of the mean force similar to the like-charged filled spheres, ranging from long-range purely repulsive to short-range purely attractive as the electrostatic coupling increased. Both types of potentials were attenuated and an attractive-to-repulsive transition occurred in the presence of trivalent counterions as a result of (i) thinning the shell or (ii) shifting the shell charge from the outer towards the inner surface. The potential of the mean force became more attractive with the icosahedrally symmetric charge model, and additionally, at least one shell tended to line up with 5-fold symmetry axis along the longest axis of the simulation box at the maximum attraction. The results provided a basic framework of understanding the non-specific electrostatic origin of the agglomeration and long-range assembly of the viral nanoparticles.

Comparison of breaking strength and shell thickness as evaluators of white-faced ibis eggshell quality

USGS Publications Warehouse

Henny, C.J.; Bennett, J.K.

1990-01-01

Data from a 1986 field study of white-faced ibis (Plegadis chihi) nesting at Carson Lake, Nevada, were used to compare the utility of eggshell strength measurement and eggshell thickness as indicators of eggshell quality. The ibis population had a history of reproductive failure correlated with elevated egg concentrations of p,p`DDE, hereafter referred to as DDE. Eggs from 80 nests (one egg/nest) were tested for shell strength and thickness. Egg contents were analyzed for organochlorines, mercury and selenium; productivity at each nest (minus one egg) was monitored in the field. DDE-DDT concentrations in the eggs ranged from none detected (less than 0.1) to 29 ppm (wet weight). Shell thickness and shell strength were both negatively correlated with DDE (0.60, 0.61, respectively), but shell strength deteriorated at a faster rate than shell thickness. Scanning electron micrographs indicated the deterioration in strength was related to changes in ultrastructure as well as to decreased thickness. Fourteen eggs with less than 0.40 ppm DDE were used to exemplify normal control eggs. Of the eggs with higher concentrations of DDE (i.e., greater than or equal to 0.40 ppm), 11 of 66 were thinner (greater than 2 SD below 'control' mean) than normal, 11 of 59 were weaker than normal and 7 eggs were cracked so their strength could not be tested, although thickness was measured. Therefore, 17% of the eggs with greater than or equal to 0.40 ppm DDE were thinner than normal and 27% were either weaker than normal or cracked. Further, six eggs (four with greater than or equal to 15 ppm DDE) did not have abnormally thin shells, but did have abnormally weak shells. Nests with abnormal test eggs (thinner, weaker or cracked) produced fewer young than nests with normal eggs. Use of the shell strength parameter provides additional information for better evaluations of reproductive problems. The potential utility of monitoring eggshell quality goes beyond evaluating effects of

7 CFR 51.2289 - Shell.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 2 2011-01-01 2011-01-01 false Shell. 51.2289 Section 51.2289 Agriculture Regulations... Standards for Shelled English Walnuts (Juglans Regia) Definitions § 51.2289 Shell. Shell means the outer shell and/or the woody partition from between the halves of the kernel, and any fragments of either. ...

7 CFR 51.2289 - Shell.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Shell. 51.2289 Section 51.2289 Agriculture Regulations... Standards for Shelled English Walnuts (Juglans Regia) Definitions § 51.2289 Shell. Shell means the outer shell and/or the woody partition from between the halves of the kernel, and any fragments of either. ...

Modeling to study the role of catalyst in the formation of graphitic shells during carbon nanofiber growth subjected to reactive plasma

NASA Astrophysics Data System (ADS)

Gupta, Ravi; Gupta, Neha; Sharma, Suresh C.

2018-04-01

An analytical model to study the role of a metal catalyst nanofilm in the nucleation, growth, and resulting structure of carbon nanofibers (CNFs) in low-temperature hydrogen diluted acetylene plasma has been developed. The model incorporates the nanostructuring of thin catalyst films, growth of CNF, restructuring of catalyst nanoparticles during growth, and its repercussion on the resulting structure (alignment of rolled graphene sheets around catalyst nanoparticles) by taking into account the plasma sheath formalization, kinetics of neutrals and positively charged species in the reactive plasma, flux of plasma species onto the catalyst front surface, and numerous surface reactions for carbon generation. In order to examine the influence of the catalyst film on the growth of CNFs, the numerical solutions of the model equations have been obtained for experimentally determined initial conditions and glow discharge plasma parameters. From the solutions obtained, we found that nanostructuring of thin films leads to the formation of small nanoparticles with high surface number density. The CNF nucleates over these small-sized nanoparticles grow faster and attain early saturation because of the quick poisoning of small-sized catalyst particles, and contain only a few graphitic shells. However, thick nanofilms result in shorter CNFs with large diameters composed of many graphitic shells. Moreover, we found that the inclination of graphitic shells also depends on the extent up to which the catalyst can reconstruct itself during the growth. The small nanoparticles show much greater elongation along the growth axis and also show a very small difference between their tip and base diameter during the growth due to which graphitic shells align at very small angles as compared to the larger nanoparticles. The present study is useful to synthesize the thin and more extended CNFs/CNTs having a smaller opening angle (inclination angle of graphene layers) as the opening angle has a

Analysis of shell-type structures subjected to time-dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, G. J.; Riff, R.

1987-01-01

A general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic, or static thermomechanical loads are developed. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling and ratcheting. Thus, geometric as well as material type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model. Furthermore, this must also be accommodated in the solution procedures.

Analysis of shell-type structures subjected to time-dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, G. J.; Carlson, R. L.; Riff, R.

1987-01-01

A general mathematical model and solution methodologies are being developed for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic, or static thermomechanical loads. Among the system responses, which were associated with these load conditions, were thermal buckling, creep buckling, and ratcheting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model. Furthermore, this must also be accommodated in the solution process.

Analysis of shell-type structures subjected to time-dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, G. J.

1989-01-01

The objective is to develop a general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic, or static thermomechanical loads. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling, and racheting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model. Furthermore, this must also be accommodated in the solution procedures.

Shell structure of natural rubber particles: evidence of chemical stratification by electrokinetics and cryo-TEM.

PubMed

Rochette, Christophe N; Crassous, Jérôme J; Drechsler, Markus; Gaboriaud, Fabien; Eloy, Marie; de Gaudemaris, Benoît; Duval, Jérôme F L

2013-11-26

The interfacial structure of natural rubber (NR) colloids is investigated by means of cryogenic transmission electron microscopy (cryo-TEM) and electrokinetics over a broad range of KNO3 electrolyte concentrations (4-300 mM) and pH values (1-8). The asymptotic plateau value reached by NR electrophoretic mobility (μ) in the thin double layer limit supports the presence of a soft (ion- and water-permeable) polyelectrolytic type of layer located at the periphery of the NR particles. This property is confirmed by the analysis of the electron density profile obtained from cryo-TEM that evidences a ∼2-4 nm thick corona surrounding the NR polyisoprene core. The dependence of μ on pH and salt concentration is further marked by a dramatic decrease of the point of zero electrophoretic mobility (PZM) from 3.6 to 0.8 with increasing electrolyte concentration in the range 4-300 mM. Using a recent theory for electrohydrodynamics of soft multilayered particles, this "anomalous" dependence of the PZM on electrolyte concentration is shown to be consistent with a radial organization of anionic and cationic groups across the peripheral NR structure. The NR electrokinetic response in the pH range 1-8 is indeed found to be equivalent to that of particles surrounded by a positively charged ∼3.5 nm thick layer (mean dissociation pK ∼ 4.2) supporting a thin and negatively charged outermost layer (0.6 nm in thickness, pK ∼ 0.7). Altogether, the strong dependence of the PZM on electrolyte concentration suggests that the electrostatic properties of the outer peripheral region of the NR shell are mediated by lipidic residues protruding from a shell containing a significant amount of protein-like charges. This proposed NR shell interfacial structure questions previously reported NR representations according to which the shell consists of either a fully mixed lipid-protein layer, or a layer of phospholipids residing exclusively beneath an outer proteic film.

High-efficiency and mechano-/photo- bi-catalysis of piezoelectric-ZnO@ photoelectric-TiO2 core-shell nanofibers for dye decomposition.

PubMed

You, Huilin; Wu, Zheng; Jia, Yanmin; Xu, Xiaoli; Xia, Yuntao; Han, Zichen; Wang, Yu

2017-09-01

A mechano-/photo- bi-catalyst of piezoelectric-ZnO@photoelectric-TiO 2 core-shell nanofibers was hydrothermally synthesized for Methyl Orange (10 mg L -1 ) decomposition. The mechano-/photo- bi-catalysis in ZnO@TiO 2 is superior to mechano- or photo-catalysis in decomposing Methyl Orange, which is mainly attributed to the synergy effect of the piezoelectric-ZnO core's mechano-catalysis and the thin photoelectric TiO 2 shell's photo-catalysis. The heterostructure of the piezoelectric-ZnO@photoelectric-TiO 2 core-shell interface, being helpful to reduce electron-hole pair recombination and to separate the piezoelectrically-/photoelectric ally- induced electrons and holes, may also make a great contribution to the enhanced catalysis performance. The mechano-/photo-bi-catalysis in ZnO@TiO 2 core-shell nanofibers possesses the advantages of high efficiency, non-toxicity and tractability and is potential in utilizing mechanical/solar energy to deal with dye wastewater. Copyright © 2017 Elsevier Ltd. All rights reserved.

A compact proton spectrometer for measurement of the absolute DD proton spectrum from which yield and pR are determined in thin-shell inertial-confinement-fusion implosions

DOE PAGES

Rosenberg, M. J.; Zylstra, A. B.; Frenje, J. A.; ...

2014-10-10

A compact, step range filter proton spectrometer has been developed for the measurement of the absolute DD proton spectrum, from which yield and areal density (ρR) are inferred for deuterium-filled thin-shell inertial confinement fusion implosions. This spectrometer, which is based on tantalum step-range filters, is sensitive to protons in the energy range 1-9 MeV and can be used to measure proton spectra at mean energies of ~1-3 MeV. It has been developed and implemented using a linear accelerator and applied to experiments at the OMEGA laser facility and the National Ignition Facility (NIF). Modeling of the proton slowing in themore » filters is necessary to construct the spectrum, and the yield and energy uncertainties are ±<10% in yield and ±120 keV, respectively. This spectrometer can be used for in situ calibration of DD-neutron yield diagnostics at the NIF« less

A compact proton spectrometer for measurement of the absolute DD proton spectrum from which yield and ρR are determined in thin-shell inertial-confinement-fusion implosions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosenberg, M. J., E-mail: mrosenbe@mit.edu; Zylstra, A. B.; Frenje, J. A.

2014-10-01

A compact, step range filter proton spectrometer has been developed for the measurement of the absolute DD proton spectrum, from which yield and areal density (ρR) are inferred for deuterium-filled thin-shell inertial confinement fusion implosions. This spectrometer, which is based on tantalum step-range filters, is sensitive to protons in the energy range 1-9 MeV and can be used to measure proton spectra at mean energies of ~1-3 MeV. It has been developed and implemented using a linear accelerator and applied to experiments at the OMEGA laser facility and the National Ignition Facility (NIF). Modeling of the proton slowing in themore » filters is necessary to construct the spectrum, and the yield and energy uncertainties are ±<10% in yield and ±120 keV, respectively. This spectrometer can be used for in situ calibration of DD-neutron yield diagnostics at the NIF.« less

Controllable Synthesis of Copper Oxide/Carbon Core/Shell Nanowire Arrays and Their Application for Electrochemical Energy Storage

PubMed Central

Zhan, Jiye; Chen, Minghua; Xia, Xinhui

2015-01-01

Rational design/fabrication of integrated porous metal oxide arrays is critical for the construction of advanced electrochemical devices. Herein, we report self-supported CuO/C core/shell nanowire arrays prepared by the combination of electro-deposition and chemical vapor deposition methods. CuO/C nanowires with diameters of ~400 nm grow quasi-vertically to the substrates forming three-dimensional arrays architecture. A thin carbon shell is uniformly coated on the CuO nanowire cores. As an anode of lithium ion batteries, the resultant CuO/C nanowire arrays are demonstrated to have high specific capacity (672 mAh·g−1 at 0.2 C) and good cycle stability (425 mAh·g−1 at 1 C up to 150 cycles). The core/shell arrays structure plays positive roles in the enhancement of Li ion storage due to fast ion/electron transfer path, good strain accommodation and sufficient contact between electrolyte and active materials. PMID:28347084

Twofold origin of strain-induced bending in core-shell nanowires: the GaP/InGaP case.

PubMed

Gagliano, Luca; Albani, Marco; Verheijen, Marcel A; Bakkers, Erik P A M; Miglio, Leo

2018-08-03

Nanowires have emerged as a promising platform for the development of novel and high-quality heterostructures at large lattice misfit, inaccessible in a thin film configuration. However, despite core-shell nanowires allowing a very efficient elastic release of the misfit strain, the growth of highly uniform arrays of nanowire heterostructures still represents a challenge, for example due to a strain-induced bending morphology. Here we investigate the bending of wurtzite GaP/In x Ga 1-x P core-shell nanowires using transmission electron microscopy and energy dispersive x-ray spectroscopy, both in terms of geometric and compositional asymmetry with respect to the longitudinal axis. We compare the experimental data with finite element method simulations in three dimensions, showing that both asymmetries are responsible for the actual bending. Such findings are valid for all lattice-mismatched core-shell nanowire heterostructures based on ternary alloys. Our work provides a quantitative understanding of the bending effect in general while also suggesting a strategy to minimise it.

Molluscan shell colour.

PubMed

Williams, Suzanne T

2017-05-01

The phylum Mollusca is highly speciose, and is the largest phylum in the marine realm. The great majority of molluscs are shelled, including nearly all bivalves, most gastropods and some cephalopods. The fabulous and diverse colours and patterns of molluscan shells are widely recognised and have been appreciated for hundreds of years by collectors and scientists alike. They serve taxonomists as characters that can be used to recognise and distinguish species, however their function for the animal is sometimes less clear and has been the focus of many ecological and evolutionary studies. Despite these studies, almost nothing is known about the evolution of colour in molluscan shells. This review summarises for the first time major findings of disparate studies relevant to the evolution of shell colour in Mollusca and discusses the importance of colour, including the effects of visual and non-visual selection, diet and abiotic factors. I also summarise the evidence for the heritability of shell colour in some taxa and recent efforts to understand the molecular mechanisms underpinning synthesis of shell colours. I describe some of the main shell pigments found in Mollusca (carotenoids, melanin and tetrapyrroles, including porphyrins and bile pigments), and their durability in the fossil record. Finally I suggest that pigments appear to be distributed in a phylogenetically relevant manner and that the synthesis of colour is likely to be energetically costly. © 2016 Cambridge Philosophical Society.

Morphology and electronic structure of the oxide shell on the surface of iron nanoparticles.

PubMed

Wang, Chongmin; Baer, Donald R; Amonette, James E; Engelhard, Mark H; Antony, Jiji; Qiang, You

2009-07-01

An iron (Fe) nanoparticle exposed to air at room temperature will be instantly covered by an oxide shell that is typically approximately 3 nm thick. The nature of this native oxide shell, in combination with the underlying Fe(0) core, determines the physical and chemical behavior of the core-shell nanoparticle. One of the challenges of characterizing core-shell nanoparticles is determining the structure of the oxide shell, that is, whether it is FeO, Fe(3)O(4), gamma-Fe(2)O(3), alpha-Fe(2)O(3), or something else. The results of prior characterization efforts, which have mostly used X-ray diffraction and spectroscopy, electron diffraction, and transmission electron microscopic imaging, have been framed in terms of one of the known Fe-oxide structures, although it is not necessarily true that the thin layer of Fe oxide is a known Fe oxide. In this Article, we probe the structure of the oxide shell on Fe nanoparticles using electron energy loss spectroscopy (EELS) at the oxygen (O) K-edge with a spatial resolution of several nanometers (i.e., less than that of an individual particle). We studied two types of representative particles: small particles that are fully oxidized (no Fe(0) core) and larger core-shell particles that possess an Fe core. We found that O K-edge spectra collected for the oxide shell in nanoparticles show distinct differences from those of known Fe oxides. Typically, the prepeak of the spectra collected on both the core-shell and the fully oxidized particles is weaker than that collected on standard Fe(3)O(4). Given the fact that the origin of this prepeak corresponds to the transition of the O 1s electron to the unoccupied state of O 2p hybridized with Fe 3d, a weak pre-edge peak indicates a combination of the following four factors: a higher degree of occupancy of the Fe 3d orbital; a longer Fe-O bond length; a decreased covalency of the Fe-O bond; and a measure of cation vacancies. These results suggest that the coordination configuration in

EUV spectroscopy of high-redshift x-ray objects

NASA Astrophysics Data System (ADS)

Kowalski, M. P.; Wolff, M. T.; Wood, K. S.; Barbee, T. W., Jr.; Barstow, M. A.

2010-07-01

As astronomical observations are pushed to cosmological distances (z>3) the spectral energy distributions of X-ray objects, AGN for example, will be redshifted into the EUV waveband. Consequently, a wealth of critical spectral diagnostics, provided by, for example, the Fe L-shell complex and the O VII/VIII lines, will be lost to future planned X-ray missions (e.g., IXO, Gen-X) if operated at traditional X-ray energies. This opens up a critical gap in performance located at short EUV wavelengths, where critical X-ray spectral transitions occur in high-z objects. However, normal-incidence multilayer-grating technology, which performs best precisely at such wavelengths, together with advanced nanolaminate replication techniques have been developed and are now mature to the point where advanced EUV instrument designs with performance complementary to IXO and Gen-X are practical. Such EUV instruments could be flown either independently or as secondary instruments on these X-ray missions. We present here a critical examination of the limits placed on extragalactic EUV measurements by ISM absorption, the range where high-z measurements are practical, and the requirements this imposes on next-generation instrument designs. We conclude with a discussion of a breakthrough technology, nanolaminate replication, which enables such instruments.

Dynamic behaviour of thin composite plates for different boundary conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sprintu, Iuliana, E-mail: sprintui@yahoo.com, E-mail: rotaruconstantin@yahoo.com; Rotaru, Constantin, E-mail: sprintui@yahoo.com, E-mail: rotaruconstantin@yahoo.com

2014-12-10

In the context of composite materials technology, which is increasingly present in industry, this article covers a topic of great interest and theoretical and practical importance. Given the complex design of fiber-reinforced materials and their heterogeneous nature, mathematical modeling of the mechanical response under different external stresses is very difficult to address in the absence of simplifying assumptions. In most structural applications, composite structures can be idealized as beams, plates, or shells. The analysis is reduced from a three-dimensional elasticity problem to a oneor two-dimensional problem, based on certain simplifying assumptions that can be made because the structure is thin.more » This paper aims to validate a mathematical model illustrating how thin rectangular orthotropic plates respond to the actual load. Thus, from the theory of thin plates, new analytical solutions are proposed corresponding to orthotropic rectangular plates having different boundary conditions. The proposed analytical solutions are considered both for solving equation orthotropic rectangular plates and for modal analysis.« less

Molecular Friction-Induced Electroosmotic Phenomena in Thin Neutral Nanotubes.

PubMed

Vuković, Lela; Vokac, Elizabeth; Král, Petr

2014-06-19

We reveal by classical molecular dynamics simulations electroosmotic flows in thin neutral carbon (CNT) and boron nitride (BNT) nanotubes filled with ionic solutions of hydrated monovalent atomic ions. We observe that in (12,12) BNTs filled with single ions in an electric field, the net water velocity increases in the order of Na(+) < K(+) < Cl(-), showing that different ions have different power to drag water in thin nanotubes. However, the effect gradually disappears in wider nanotubes. In (12,12) BNTs containing neutral ionic solutions in electric fields, we observe net water velocities going in the direction of Na(+) for (Na(+), Cl(-)) and in the direction of Cl(-) for (K(+), Cl(-)). We hypothesize that the electroosmotic flows are caused by different strengths of friction between ions with different hydration shells and the nanotube walls.

Exciton dynamics in GaAs/(Al,Ga)As core-shell nanowires with shell quantum dots

NASA Astrophysics Data System (ADS)

Corfdir, Pierre; Küpers, Hanno; Lewis, Ryan B.; Flissikowski, Timur; Grahn, Holger T.; Geelhaar, Lutz; Brandt, Oliver

2016-10-01

We study the dynamics of excitons in GaAs/(Al,Ga)As core-shell nanowires by continuous-wave and time-resolved photoluminescence and photoluminescence excitation spectroscopy. Strong Al segregation in the shell of the nanowires leads to the formation of Ga-rich inclusions acting as quantum dots. At 10 K, intense light emission associated with these shell quantum dots is observed. The average radiative lifetime of excitons confined in the shell quantum dots is 1.7 ns. We show that excitons may tunnel toward adjacent shell quantum dots and nonradiative point defects. We investigate the changes in the dynamics of charge carriers in the shell with increasing temperature, with particular emphasis on the transfer of carriers from the shell to the core of the nanowires. We finally discuss the implications of carrier localization in the (Al,Ga)As shell for fundamental studies and optoelectronic applications based on core-shell III-As nanowires.

Template-Stripped Smooth Ag Nanohole Arrays with Silica Shells for Surface Plasmon Resonance Biosensing

PubMed Central

Im, Hyungsoon; Lee, Si Hoon; Wittenberg, Nathan J.; Johnson, Timothy W.; Lindquist, Nathan C.; Nagpal, Prashant; Norris, David J.; Oh, Sang-Hyun

2011-01-01

Inexpensive, reproducible and high-throughput fabrication of nanometric apertures in metallic films can benefit many applications in plasmonics, sensing, spectroscopy, lithography and imaging. Here we use template stripping to pattern periodic nanohole arrays in optically thick, smooth Ag films with a silicon template made via nanoimprint lithography. Ag is a low-cost material with good optical properties, but it suffers from poor chemical stability and biocompatibility. However, a thin silica shell encapsulating our template-stripped Ag nanoholes facilitates biosensing applications by protecting the Ag from oxidation as well as providing a robust surface that can be readily modified with a variety of biomolecules using well-established silane chemistry. The thickness of the conformal silica shell can be precisely tuned by atomic layer deposition, and a 15-nm-thick silica shell can effectively prevent fluorophore quenching. The Ag nanohole arrays with silica shells can also be bonded to polydimethylsiloxane (PDMS) microfluidic channels for fluorescence imaging, formation of supported lipid bilayers, and real-time, label-free SPR sensing. Additionally, the smooth surfaces of the template-stripped Ag films enhance refractive index sensitivity compared with as-deposited, rough Ag films. Because nearly centimeter-sized nanohole arrays can be produced inexpensively without using any additional lithography, etching or lift-off, this method can facilitate widespread applications of metallic nanohole arrays for plasmonics and biosensing. PMID:21770414

Oyster shell conveyor used to lift shells from the dock ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Oyster shell conveyor used to lift shells from the dock into the receiving room housed in the 1965 concrete block addition. - J.C. Lore Oyster House, 14430 Solomons Island Road, Solomons, Calvert County, MD

A robust approach for analysing dispersion of elastic waves in an orthotropic cylindrical shell

NASA Astrophysics Data System (ADS)

Kaplunov, J.; Nobili, A.

2017-08-01

Dispersion of elastic waves in a thin orthotropic cylindrical shell is considered, within the framework of classical 2D Kirchhoff-Love theory. In contrast to direct multi-parametric analysis of the lowest propagating modes, an alternative robust approach is proposed that simply requires evaluation of the evanescent modes (quasi-static edge effect), which, at leading order, do not depend on vibration frequency. A shortened dispersion relation for the propagating modes is then derived by polynomial division and its accuracy is numerically tested against the full Kirchhoff-Love dispersion relation. It is shown that the same shortened relation may be also obtained from a refined dynamic version of the semi-membrane theory for cylindrical shells. The presented results may be relevant for modelling various types of nanotubes which, according to the latest experimental findings, possess strong material anisotropy.

Transient Response of Shells of Revolution by Direct Integration and Modal Superposition Methods

NASA Technical Reports Server (NTRS)

Stephens, W. B.; Adelman, H. M.

1974-01-01

The results of an analytical effort to obtain and evaluate transient response data for a cylindrical and a conical shell by use of two different approaches: direct integration and modal superposition are described. The inclusion of nonlinear terms is more important than the inclusion of secondary linear effects (transverse shear deformation and rotary inertia) although there are thin-shell structures where these secondary effects are important. The advantages of the direct integration approach are that geometric nonlinear and secondary effects are easy to include and high-frequency response may be calculated. In comparison to the modal superposition technique the computer storage requirements are smaller. The advantages of the modal superposition approach are that the solution is independent of the previous time history and that once the modal data are obtained, the response for repeated cases may be efficiently computed. Also, any admissible set of initial conditions can be applied.

7 CFR 51.2002 - Split shell.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 2 2011-01-01 2011-01-01 false Split shell. 51.2002 Section 51.2002 Agriculture... Standards for Grades of Filberts in the Shell 1 Definitions § 51.2002 Split shell. Split shell means a shell... of the shell, measured in the direction of the crack. ...

7 CFR 51.2002 - Split shell.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Split shell. 51.2002 Section 51.2002 Agriculture... Standards for Grades of Filberts in the Shell 1 Definitions § 51.2002 Split shell. Split shell means a shell... of the shell, measured in the direction of the crack. ...

Multiple shell fusion targets

DOEpatents

Lindl, J.D.; Bangerter, R.O.

1975-10-31

Multiple shell fusion targets for use with electron beam and ion beam implosion systems are described. The multiple shell targets are of the low-power type and use a separate relatively low Z, low density ablator at large radius for the outer shell, which reduces the focusing and power requirements of the implosion system while maintaining reasonable aspect ratios. The targets use a high Z, high density pusher shell placed at a much smaller radius in order to obtain an aspect ratio small enough to protect against fluid instability. Velocity multiplication between these shells further lowers the power requirements. Careful tuning of the power profile and intershell density results in a low entropy implosion which allows breakeven at low powers. For example, with ion beams as a power source, breakeven at 10-20 Terrawatts with 10 MeV alpha particles for imploding a multiple shell target can be accomplished.

Self-assembled morphologies of an amphiphilic Y-shaped weak polyelectrolyte in a thin film.

PubMed

Mu, Dan; Li, Jian-Quan; Feng, Sheng-Yu

2017-11-29

Different from the self-assembly of neutral polymers, polyelectrolytes self-assemble into smaller aggregates with a more loosely assembled structure, which results from the repulsive forces acting between similar electrical compositions with the introduction of ions. The Y-shaped weak polyelectrolytes self-assemble into a core-shell type cylindrical structure with a hexagonal arrangement in a thin film, whose thickness is smaller than the gyration radius of the polymer chain. The corresponding formation mechanism consists of enrichment of the same components, adjustment of the shape of the aggregate, and the subsequent separation into individual aggregates. With the increase in the thickness of the thin film until it exceeds the gyration radius of the polymer chain, combined with the greater freedom of movement along the direction of thin film thickness, the self-assembled structure changes into a micellar structure. Under confinement, the repulsive force to the polymeric components is weakened by the repulsive forces among polyelectrolyte components with like charges, and this helps in generating aggregates with more uniform size and density distribution. In particular, when the repulsive force between the walls and the core forming components is greater than that between the walls and the shell forming components, such asymmetric confinement produces a crossed-cylindrical structure with nearly perpendicular arrangement of two cylinder arrays. Similarly, a novel three-crossed cylinder morphology is self-assembled upon removal of confinement.

Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

NASA Astrophysics Data System (ADS)

Velikovich, A. L.; Schmit, P. F.

2015-11-01

Bell-Plesset effects accounting for the time dependence of the radius, velocity and acceleration of the Rayleigh-Taylor-unstable surface are ubiquitous in the instability of spherical laser targets and magnetically driven cylindrical liners. We present an analytical model that, for an ideal incompressible fluid and small perturbation amplitudes, exactly accounts for the Bell-Plesset effects in finite-thickness targets and liners through acceleration and deceleration phases. We derive the time-dependent dispersion equations determining the ``instantaneous growth rate'' and demonstrate that by integrating this growth rate over time (the WKB approximation) we accurately evaluate the number of perturbation e-foldings during the acceleration phase. In the limit of the small target/liner thickness, we obtain the exact thin-shell perturbation equations and approximate thin-shell dispersion relations, generalizing the earlier results of Harris (1962), Ott (1972) and Bud'ko et al. (1989). This research was supported by the US DOE/NNSA (A.L.V.), and in part by appointment to the Sandia National Laboratories Truman Fellowship in National Security Science and Engineering (P.F.S.), which is part of the Laboratory Directed Research and Development (LDRD) Program, Project No. 165746, and sponsored by Sandia Corporation (a wholly owned subsidiary of Lockheed Martin Corporation) as Operator of Sandia National Laboratories under its U.S. Department of Energy Contract No. DE-AC04-94AL85000.

Analysis of shell-type structures subjected to time-dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, G. J.; Riff, R.

1988-01-01

This research is performed to develop a general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic or static thermomechanical loads. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling, and ratcheting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model. Furthermore, this must also be accommodated in the solution procedures.

Analysis of shell-type structures subjected to time-dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, George J.

1990-01-01

The development of a general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-like structures under dynamic and/or static thermomechanical loads is examined. In the mathematical model, geometric as well as material-type of nonlinearities are considered. Traditional as well as novel approaches are reported and detailed applications are presented in the appendices. The emphasis for the mathematical model, the related solution schemes, and the applications, is on thermal viscoelastic and viscoplastic phenomena, which can predict creep and ratchetting.

Analysis of shell-type structures subjected to time-dependent mechanical and thermal loading

NASA Technical Reports Server (NTRS)

Simitses, G. J.; Riff, R.

1988-01-01

The objective of this research is to develop a general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic or static thermomechanical loads. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling and racheting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model. Furthermore, this must also be accommodated in the solution procedures.

Modeling of thin-walled structures interacting with acoustic media as constrained two-dimensional continua

NASA Astrophysics Data System (ADS)

Rabinskiy, L. N.; Zhavoronok, S. I.

2018-04-01

The transient interaction of acoustic media and elastic shells is considered on the basis of the transition function approach. The three-dimensional hyperbolic initial boundary-value problem is reduced to a two-dimensional problem of shell theory with integral operators approximating the acoustic medium effect on the shell dynamics. The kernels of these integral operators are determined by the elementary solution of the problem of acoustic waves diffraction at a rigid obstacle with the same boundary shape as the wetted shell surface. The closed-form elementary solution for arbitrary convex obstacles can be obtained at the initial interaction stages on the background of the so-called “thin layer hypothesis”. Thus, the shell–wave interaction model defined by integro-differential dynamic equations with analytically determined kernels of integral operators becomes hence two-dimensional but nonlocal in time. On the other hand, the initial interaction stage results in localized dynamic loadings and consequently in complex strain and stress states that require higher-order shell theories. Here the modified theory of I.N.Vekua–A.A.Amosov-type is formulated in terms of analytical continuum dynamics. The shell model is constructed on a two-dimensional manifold within a set of field variables, Lagrangian density, and constraint equations following from the boundary conditions “shifted” from the shell faces to its base surface. Such an approach allows one to construct consistent low-order shell models within a unified formal hierarchy. The equations of the N th-order shell theory are singularly perturbed and contain second-order partial derivatives with respect to time and surface coordinates whereas the numerical integration of systems of first-order equations is more efficient. Such systems can be obtained as Hamilton–de Donder–Weyl-type equations for the Lagrangian dynamical system. The Hamiltonian formulation of the elementary N th-order shell theory is