Mamba, Gcina; Mbianda, Xavier Yangkou; Mishra, Ajay Kumar
2015-07-01
A simple sol-gel method was employed to prepare gadolinium, nitrogen and sulphur tridoped titania decorated on oxidised multiwalled carbon nanotubes (MWCNT/Gd,N,S-TiO2), using titanium (IV) butoxide and thiourea as titanium and nitrogen and sulphur source, respectively. Samples of varying gadolinium loadings (0.2%, 0.6%, 1.0% and 3.0% Gd3+) relative to titania were prepared to investigate the effect of gadolinium loading and the amounts of carbon nanotubes, nitrogen and sulphur were kept constant for all the samples. Furthermore, the prepared nanocomposites were evaluated for the degradation of naphthol blue black (NBB) in water under simulated solar light irradiation. Higher degradation efficiency (95.7%) was recorded for the MWCNT/Gd,N,S-TiO2 (0.6% Gd) nanocomposites. The higher photocatalytic activity is attributed to the combined effect of improved visible light absorption and charge separation due to the synergistic effect of Gd, MWCNTs, N, S and TiO2. Total organic carbon (TOC) analysis revealed a higher degree of complete mineralisation of naphthol blue black (78.0% TOC removal) which minimises the possible formation of toxic degradation by-products such as the aromatic amines. The MWCNT/Gd,N,S-TiO2 (0.6% Gd) was fairly stable and could be re-used for five times, reaching a maximum degradation efficiency of 91.8% after the five cycles. Copyright © 2015. Published by Elsevier B.V.
Özcan, Ayça Atılır; Özcan, Ali
2018-07-01
In this study, mineralization and color removal performance of electro-Fenton method were examined in water containing naphthol blue black (NBB), a diazo dye. NBB was totally converted to intermediate species in a 15-min electrolysis at 60 mA, but complete de-colorization took 180 min. A very high oxidation rate constant ((3.35 ± 0.21) x 10 10 M -1 s -1 ) was obtained for NBB, showing its high reactivity towards hydroxyl radicals. A very high total organic carbon (TOC) removal value (45.23 mg L -1 ) was obtained in the first 60 min of the electro-Fenton treatment of an aqueous solution of NBB (0.25 mM) at 300 mA, indicating the mineralization efficiency of the electro-Fenton method. Mineralization current efficiency values obtained at 300 mA gradually decreased from 24.18% to 4.47% with the electrolysis time, indicating the presence of highly parasitic reactions. Gas chromatography-mass spectrometry analyses revealed that the cleavage of azo bonds of NBB led to formation of different aromatic and aliphatic oxidation intermediates. Ion chromatography analysis showed that ammonium, nitrate and sulfate were the mineralization end-products. The concentration of sulfate ion reached to its quantitative value at the 4th h of electrolysis. On the other hand, the total concentration of ammonium and nitrate ions reached to only 61% of the stoichiometric amount of initial nitrogen after a 7 h electrolysis. Finally, it can be said that the electro-Fenton method is a suitable and efficient method for the removal of NBB and its intermediates from water. Copyright © 2018 Elsevier Ltd. All rights reserved.
Efficient removal of dyes from aqueous solutions using a novel hemoglobin/iron oxide composite.
Essandoh, Matthew; Garcia, Rafael A
2018-05-10
Magnetic particles entrapped in different matrices that display high thermal stability, low toxicity, interactive functions at the surface, and high saturation magnetization are of great interest. The objective of this work was to synthesize a novel hemoglobin/iron oxide composite (Hb/Fe 3 O 4 ) for the removal of different dyes (indigo carmine, naphthol blue black, tartrazine, erythrosine, eriochrome black T and bromophenol blue) from aqueous solutions. The Hb/Fe 3 O 4 composite was characterized using scanning electron microscopy (SEM), laser diffraction particle size analysis, FT-IR spectroscopy, isoelectric point determination and thermogravimetric analysis (TGA). The Hb/Fe 3 O 4 composite showed high removal efficiency toward all the different classes of dyes studied and the mechanism of adsorption was dominated by electrostatic interaction. Adsorption was found to follow pseudo-second order kinetic model and Langmuir isotherm. The Langmuir monolayer adsorption capacities for all the dyes range from 80 to 178 mg/g. The Hb/Fe 3 O 4 composite possesses extra advantage of being easily isolated from aqueous suspension using an external magnet. The stability of the prepared Hb/Fe 3 O 4 composite was also demonstrated. Copyright © 2018 Elsevier Ltd. All rights reserved.
Usage of FTIR-ATR as Non-Destructive Analysis of Selected Toxic Dyes
NASA Astrophysics Data System (ADS)
Bartošová, Alica; Blinová, Lenka; Sirotiak, Maroš; Michalíková, Anna
2017-06-01
The degradation of the environment which is due to the discharge of polluting wastewater from industrial sources poses a real problem in several countries. Textile industries use large volumes of water in their operations, discharging thus large volume of wastewater into the environment, most of which is untreated. The wastewater contains a variety of chemicals from various stages of process operations, including desizing, scouring, bleaching and dyeing. The main purpose of this paper is to introduce Infrared Spectrometry with Fourier transformation as a non-destructive method for study, identifation and rapid determination of selected representatives of cationic (Methylene Blue), azo (Congo Red, Eriochrome Black T) and nitroso (Naphthol Green B) dyes. In conjunction with the ATR technique, FTIR offers a reliable detection method of dyes without extraction by other dangerous substances. Spectral interpretation of dye spectra revealed valuable information about the identification and characterization of each group of dyes.
Inhibitory effects of naphthols on the activity of mushroom tyrosinase.
Lin, Yi-Fen; Hu, Yong-Hua; Jia, Yu-Long; Li, Zhi-Cong; Guo, Yun-Ji; Chen, Qing-Xi; Lin, He-Tong
2012-01-01
Tyrosinase (EC 1.14.18.1), a copper-containing multifunctional oxidase, was known to be a key enzyme for biosynthesis in fungi, plants and animals. In this work, the inhibition properties α-naphthol and β-naphthol toward the activity of tyrosinase have been evaluated, and the effects of α-naphthol and β-naphthol on monophenolase and diphenolase activity of tyrosinase have been investigated. The results showed that both α-naphthol and β-naphthol could potently inhibit both monophenolase activity and diphenolase activity of mushroom tyrosinase, and that β-naphthol exhibited stronger inhibitory effect against tyrosinase than α-naphthol. For monophenolase activity, β-naphthol could not only lengthen the lag time but also decrease the steady-state activity, while α-naphthol just only decreased the steady-state activity. For diphenolase activity, both α-naphthol and β-naphthol displayed revisible inhibition. Kinetic analyses showed that both α-naphthol and β-naphthol were competetive inhibitors. Copyright © 2012 Elsevier B.V. All rights reserved.
Peroxidase-mediated polymerization of 1-naphthol: impact of solution pH and ionic strength.
Bhandari, Alok; Xu, Fangxiang; Koch, David E; Hunter, Robert P
2009-01-01
Peroxidase-mediated oxidation has been proposed as a treatment method for naphthol-contaminated water. However, the impact of solution chemistry on naphthol polymerization and removal has not been documented. This research investigated the impact of pH and ionic strength on peroxidase-mediated removal of 1-naphthol in completely mixed batch reactors. The impact of hydrogen peroxide to 1-naphthol ratio and activity of horseradish peroxidase was also studied. Size exclusion chromatography was used to estimate the molecular weight distribution of oligomeric products, and liquid chromatography/mass spectrometry was used to estimate product structure. Naphthol transformation decreased with ionic strength, and substrate removal was lowest at neutral pHs. Solution pH influenced the size and the composition of the oligomeric products. An equimolar ratio of H(2)O(2):naphthol was sufficient for optimal naphthol removal. Polymerization products included naphthoquinones and oligomers derived from two, three, and four naphthol molecules. Our results illustrate the importance of water chemistry when considering a peroxidase-based approach for treatment of naphthol-contaminated waters.
Preuss, Ralf; Angerer, Jürgen
2004-03-05
We developed a new 3-D HPLC method for on-line clean-up and simultaneous quantification of two important naphthalene metabolites, 1-naphthol and 2-naphthol, in human urine. Except an enzymatic hydrolysis no further sample pre-treatment is necessary. The metabolites are stripped from urinary matrix by on-line extraction on a restricted access material pre-column (RAM RP-8), transferred in backflush mode onto a silica-based CN-(cyano)phase column for further purification from interfering substances. By another successive column switching step both analytes are transferred with a minimum of overlapping interferences onto a C12 bonded reversed phase column with trimethylsilyl endcapping where the final separation is carried out. The entire arrangement is software controlled. Eluting analytes are quantified by fluorescence detection (227/430 nm) after an external calibration. Within a total run time of 40 min we can selectively quantify both naphthols with detection limits in the lower ppb range (1.5 and 0.5 microg/l for 1- and 2-naphthol, respectively) with excellent reliability (ensured by precision, accuracy, matrix-independency and FIOH quality assurance program participation). First results on a collective of 53 occupationally non exposed subjects showed mean levels of 11.0 microg/l (1-naphthol) and 12.9 microg/l (2-naphthol). Among smokers (n=21) a significantly elevated mean level of urinary naphthols was determined (1-naphthol: 19.2 microg/l and 2-naphthol: 23.7 microg/l) in comparison to non smokers (n=32; 1-naphthol: 5.6 microg/l, 2-naphthol: 5.6 microg/l).
Novak, Jurica; Prlj, Antonio; Basarić, Nikola; Corminboeuf, Clémence; Došlić, Nađa
2017-06-16
The computational analysis of the isomer- and conformer-dependent photochemistry of 1- and 2-naphthols and their microsolvated water clusters is motivated by their very different excited state reactivities. We present evidence that 1- and 2-naphthol follow distinct excited state deactivation pathways. The deactivation of 2-naphthols, 2-naphthol water clusters, as well as of the anti conformer of 1-naphthol is mediated by the optically dark 1 πσ* state. The dynamics of the 1 πσ* surface leads to the homolytic cleavage of the OH bond. On the contrary, the excited state deactivation of syn 1-naphthol and 1-naphthol water clusters follows an uncommon reaction pathway. Upon excitation to the bright 1 ππ*(L a ) state, a highly specific excited state hydrogen transfer (ESHT) to carbon atoms C8 and C5 takes place, yielding 1,8- and 1,5-naphthoquinone methides. The ESHT pathway arises from the intrinsic electronic properties of the 1 ππ*(L a ) state of 1-naphthols. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
The toxicity of textile reactive azo dyes after hydrolysis and decolourisation.
Gottlieb, Anna; Shaw, Chris; Smith, Alan; Wheatley, Andrew; Forsythe, Stephen
2003-02-27
The toxicity of C.I. Reactive Black 5 and three Procion dyes, as found in textile effluents, was determined using the bioluminescent bacterium Vibrio fischeri. Hydrolysed Reactive Black had a slightly greater toxicity than the parent form (EC(50) 11.4+/-3.68 and 27.5+/-4.01 mg l(-1), respectively). A baffled bioreactor with anaerobic and aerobic compartments was used to decolourise hydrolysed Reactive Black 5 in a synthetic effluent. Decolourisation of hydrolysed Reactive Black resulted in an increased toxicity (EC(50) 0.2+/-0.03 mg l(-1)). Toxicity was not detectable when decolourised Reactive Black 5 was metabolised under aerobic conditions. No genotoxicity was detected after the decolourisation of either the parent or the hydrolysed reactive dyes, either in vitro or in the bioreactor. The toxicity and genotoxicity of decolourised C.I. Acid Orange 7 was due to the production of 1-amino-2-naphthol (EC(50) 0.1+/-0.03 mg l(-1)).
Degradation of α-Naphthol by Plasma in Aqueous Solution
NASA Astrophysics Data System (ADS)
Gao, Jin-zhang; Hu, Zhong-ai; Wang, Xiao-yan; Hou, Jing-guo; Lu, Xiao-quan; Kang, Jing-wan
2001-02-01
Degradation of α-naphthol induced by plasma in aqueous solution was investigated in different initial concentration with contact glow discharge electrolysis (CGDE). The results showed that the degradation of α-naphthol obeyed the first-rate law. Some of predominant products were analyzed by a high performance liquid chromatography (HPLC). A path of α-naphthol disappearance caused by plasma was proposed according to the detected intermediate products.
Matrix isolation FT-IR and theoretical DFT/B3LYP spectrum of 1-naphthol.
Muzomwe, Mayawila; Boeckx, Bram; Maes, Guido; Kasende, Okuma E
2013-05-01
The FT-IR spectrum of 1-Naphthol isolated in an argon matrix is performed and compared to the infrared spectra calculated at the DFT (B3LYP)/6-31+G(d) level for cis-1-Naphthol and trans-1-Naphthol rotamers in order to clarify the existence of both rotamers in the standard temperature. Comparison of the computed and the experimental matrix spectra reveals the presence in 1-Naphthol argon matrices in the standard temperature of both cis and trans rotameric forms of 1-Naphthol, the last predominating. The relative stability of the trans-1-Naphthol rotamer has also been supported by a fit comparison between the difference of predicted total energy (ETC) of both rotamers of 0.00195 a.u. corresponding to 5.12 kJ mol(-1) and the variation of the standard free Gibbs energy of rotamerization (ΔGr°) of 5.06 kJ mol(-1). Almost all 51 active vibrational modes of 1-Naphthol have been assigned. The stretching vibration of the OH group (νOH) appears to be the unique vibrational mode distinguishing the cis-1-NpOH rotamer from the trans-1-NpOH rotamer in FT-IR spectrum. Copyright © 2013 Elsevier B.V. All rights reserved.
Hogsette, Jerome A; Foil, Lane D
2018-04-02
Stable fly management is challenging because of the fly's dispersal behavior and its tendency to remain on the host only while feeding. Optically attractive traps have been used to survey and sometimes reduce adult populations. Insecticide-treated blue and black cloth targets developed for tsetse fly management in Africa were found to be attractive to stable flies in the United States, and various evaluations were conducted in Louisiana and Florida. Tests using untreated targets were designed to answer questions about configuration, size, and color relative to efficacy and stability in high winds. Studies with electric grid targets and with targets paired with Olson traps showed cloth target color attraction in the following decreasing order: black > blue-black > blue. A solid black target is easier to make than a blue-black target because no sewing is involved. Attraction was not affected when flat 1-m2 targets were formed into cylinders, despite the limited view of the blue and black colors together. There was no reduction in attraction when the 1-m2 cylindrical targets were compared with smaller (63 × 30 cm high) cylindrical targets. In addition, there was no difference in attraction between the small blue-black, blue, and black targets. Significance of findings and implications of potential uses for treated targets are discussed. Target attraction was indicated by the numbers of stable flies captured on an Olson sticky trap placed 30 cm from the target. Although this system is adequate for field research, it greatly underestimates the actual numbers of stable flies attracted to treated targets.
Levine, H.; Rowe, J.J.; Grimaldi, F.S.
1955-01-01
Microgram amounts of phosphate are usually determined by the molybdenum blue reaction, but this reaction is not specific for phosphorus. The research established the range of conditions under which phosphate, arsenate, silicate, and germanate give the molybdenum blue reaction for differentiating these elements, and developed a method for the determination of phosphate in waters containing up to 10 p.p.m. of the oxides of germanium, arsenic(V), and silicon. With stannous chloride or 1-amino-2-naphthol-4-sulfonic acid as the reducing agent no conditions were found for distinguishing silicate from germanate and phosphate from arsenate. In the recommended procedure the phosphate is concentrated by coprecipitation on aluminum hydroxide, and coprecipitated arsenic, germanium, and silicon are volatilized by a mixture of hydrofluoric, hydrochloric, and hydrobromic acids prior to the determination of phosphate. The authors are able to report that the total phosphorus content of several samples of sea water from the Gulf of Mexico ranged from 0.018 to 0.059 mg. of phosphorus pentoxide per liter of water.
Nitration of Naphthol: A Laboratory Experiment.
ERIC Educational Resources Information Center
Mowery, Dwight F.
1982-01-01
Products of nitrations, upon distillation or steam distillation, may produce dermatitis in some students. A procedure for nitration of beta-naphthol producing a relatively non-volatile product not purified by steam distillation is described. Nitration of alpha-naphthol by the same procedure yields Martius Yellow dye which dyes wool yellow or…
Chen, Weiye; Wen, Zhiyuan; Zhang, Jialin; Li, Cuicui; Huang, Kehe; Bu, Zhigao
2018-02-01
The methods of the quantitative assay of the antiviral activity of interferons (IFNs) (type I, II or III) are very important during carrying out of the research of them, since they were found. Here a recombinant vesicular stomatitis virus expressing green fluorescent protein (GFP) (VSV/GFP) and MDBK cells were used to develop an antiviral assay (AVA) for IFNs. This method was carried out on a 96-well cell culture plate, and the half reduction of virus replication was quantified by assaying GFP. To quantify GFP, cell lysis buffer was directly added to the wells infected with VSV/GFP to lyse cells, the VSV/GFP was then inactivated, and relative fluorescence unit (RFU) of GFP was measured and used to calculate the antiviral activity. This method needed only one step instead of three steps in the staining method with naphthol blue black, medium with phenol red can be used, and it had good reproducibility. The GFP-containing samples could be stored at 4°C in a wet box for at least 1 week without affecting the assay results. In addition, the results obtained with this method were similar to those obtained with the staining method. In conclusion, a safe, rapid, convenient and low-cost AVA of IFN based on recombinant VSV/GFP was established. Copyright © 2017. Published by Elsevier B.V.
DIAZOPHTHALOCYANINS AS REAGENTS FOR FINE STRUCTURAL CYTOCHEMISTRY
Tice, Lois Withrow; Barrnett, Russell J.
1965-01-01
This paper reports the synthesis of 14 diazophthalocyanins containing Mg, Cu, or Pb as the chelated metal. To assess the usefulness of these compounds for fine structural cytochemistry, the relative coupling rates with naphthols were tested as well as the solubility of the resulting azo dyes. Three of the diazotates were reacted with tissue proteins in aldehyde-fixed material, and the density increases thus produced were compared in the electron microscope with those produced by staining similarly fixed material with the phthalocyanin dye, Alcian Blue. Finally, one of the diazotates was used as a capture reagent for the demonstration of the sites of acid phosphatase activity with the electron microscope. PMID:14283629
Bhopatkar, Deepak; Feng, Tao; Chen, Feng; Zhang, Genyi; Carignano, Marcelo; Park, Sung Hyun; Zhuang, Haining; Campanella, Osvaldo H; Hamaker, Bruce R
2015-05-06
A previously reported nanoparticle formed through the self-assembly of common food constituents (amylose, protein, and fatty acids) was shown to have the capacity to carry a sparingly soluble small molecule (1-naphthol) in a dispersed system. Potentiometric titration showed that 1-naphthol locates in the lumen of the amylose helix of the nanoparticle. This finding was further supported by calorimetric measurements, showing higher enthalpies of dissociation and reassociation in the presence of 1-naphthol. Visually, the 1-naphthol-loaded nanoparticle appeared to be well-dispersed in aqueous solution. Molecular dynamics simulation showed that the self-assembly was favorable, and at 500 ns, the 1-naphthol molecule resided in the helix of the amylose lumen in proximity to the hydrophobic tail of the fatty acid. Thus, sparingly soluble small molecules, such as some nutraceuticals or drugs, could be incorporated and delivered by this soft nanoparticle carrier.
The spectrum of dermatoscopic patterns in blue nevi.
Di Cesare, Antonella; Sera, Francesco; Gulia, Andrea; Coletti, Gino; Micantonio, Tamara; Fargnoli, Maria Concetta; Peris, Ketty
2012-08-01
Blue nevi are congenital or acquired, dermal dendritic melanocytic proliferations that can simulate melanocytic and nonmelanocytic lesions including melanoma, cutaneous metastasis of melanoma, Spitz/Reed nevi, and basal cell carcinoma. We sought to investigate global and local dermatoscopic patterns of blue nevi compared with melanomas and basal cell carcinomas. We retrospectively analyzed global and local features in 95 dermatoscopic images of blue nevi and in 190 melanomas and basal cell carcinomas that were selected as control lesions on the basis of similar pigmentation. Lesion pigmentation was classified as monochromatic, dichromatic, or multichromatic. A global pattern characterized by homogeneous pigmentation was observed in all of 95 (100%) blue nevi. Eighty of 95 (84.2%) blue nevi presented a homogeneous pattern consisting of one color (blue, black, or brown) or two colors (blue-brown, blue-gray, or blue-black). Fifteen of 95 (15.8%) blue nevi had a multichromatic (blue, gray, black, brown, and/or red) pigmentation. In all, 47 of 95 (49.5%) blue nevi were characterized by pigmentation in the absence of pigment network or any other local dermatoscopic features. And 48 of 95 (50.5%) blue nevi showed local dermatoscopic patterns including whitish scarlike depigmentation, dots/globules, vascular pattern, streaks, and networklike pattern. The study was retrospective and involved only Caucasian people of Italian origin. The characteristic feature of blue nevi is a homogeneous pigmentation that is blue, blue-gray, blue-brown, or blue-black. We showed that a wide spectrum of local dermatoscopic features (whitish scarlike depigmentation, dots/globules, peripheral streaks or vessels) may also be present. In such cases, clinical and dermatoscopic distinction from melanoma or nonmelanocytic lesions may be difficult or impossible, and surgical excision is necessary. Copyright © 2011 American Academy of Dermatology, Inc. Published by Mosby, Inc. All rights reserved.
Karunya, A; Rose, C; Valli Nachiyar, C
2014-03-01
The bacterium with dye degrading ability was isolated from effluent disposal sites of textile industries, Tirupur and was identified as Moraxella osloensis based on the biochemical and morphological characterization as well as 16S rRNA sequencing. This organism was found to decolorize 87 % of Mordant Black 17 at 100 mg l⁻¹ under shake culture condition compared to 92 % under stationary culture condition. Maximum degradation of the dye by M. osloensis was achieved when the mineral salt medium was supplemented with 0.5 % glucose and 0.1 % ammonium nitrate at 35 °C. Degradation of dye was found to follow first order kinetics with the k value of 0.06282 h⁻¹ and a R² value of 0.955. Analyses for the identification of intermediate compounds confirmed the presence of naphthalene, naphthol, naphthoquinone, salicylic acid and catechol. Based on this finding a probable pathway for the degradation of Mordant Black 17 by M. osloensis has been proposed.
Isomerization of 7-oxabenzonorbornadienes into naphthols catalyzed by [RuCl(2)(CO)(3)](2).
Ballantine, Melissa; Menard, Michelle L; Tam, William
2009-10-02
Ruthenium-catalyzed isomerization of 7-oxanorbornadienes into naphthols was investigated. Among the various ruthenium catalysts tested, [RuCl(2)(CO)(3)](2) gave the highest yields in the isomerization, and various substituted naphthols were synthesized in moderate to excellent yields. Both symmetrical and unsymmetrical 7-oxanorbornadienes were employed in the study, and moderate to excellent regioselectivities were observed.
Microdetermination of calcium and magnesium in biological materials
Bowden, C. H.; Patston, Valerie J.
1963-01-01
The use of the dye calcon (1-(2 hydroxy-1-naphthylazo)-2-naphthol-4 sulphonic acid) for the estimation of calcium using E.D.T.A. and a commercial photoelectric titrimeter is described. The interfering effects of magnesium and phosphate have been overcome. The method has been extended to estimations on biological materials. Results on 55 sera show that the E.D.T.A./calcon method gave slightly lower results (—0·15 mg./100 ml. ± 0·029) than the oxalate precipitation method. Magnesium may also be estimated by incorporating the use of Eriochrome black T. PMID:14014590
NASA Astrophysics Data System (ADS)
Kooti, M.; Karimi, M.; Nasiri, E.
2018-02-01
A new Cu(II) complex supported on magnetic reduced graphene oxide was prepared and characterized by various techniques, such as FT-IR, XRD, SEM, EDX, TEM, TGA, BET, ICP, and VSM. The synthesized nanocomposite, which has size distribution of 25-30 nm, was employed as catalyst in one-pot synthesis of 1-amidoalkyl-2-naphthols via three-component condensation reaction of amides, aromatic aldehydes, and 2-naphthol, under solvent-free conditions. The introduced catalysis procedure for the synthesis of 1-amidoalkyl-2-naphthol derivatives offers several advantages namely, short reaction times, high yields, facile recyclability, and cost effectiveness. [Figure not available: see fulltext.
Green, K Kappmeier; Venter, G J
2007-12-01
The attractiveness of various colours, colour combinations and sizes of sticky traps of the 3-dimensional trap (3DT), cross-shaped target (XT), rectangular screen (RT) and monopanels were evaluated for their efficacy to capture Glossina austeni Newstead and G. brevipalpis Newstead in north-eastern KwaZulu-Natal, South Africa. The 3-dimensional shapes of the XT and 3DT in light blue (l.blue) and white were significantly (ca. 3.1-6.9 times) better than the RT for G. austeni. On bicoloured XTs, G. austeni landed preferentially on electric blue (e.blue) (58%) and black (63%) surfaces when used with white; while for G. brevipalpis, significantly more landed on e.blue (60-66%) surfaces when used with l.blue, black or white surfaces. Increased trap size increased the catches of G. brevipalpis females and both sexes of G. austeni significantly. Temoocid and polybutene sticky materials were equally effective and remained durable for 2-3 weeks. The glossy shine of trap surfaces did not have any significant effect on the attraction and landing responses of the two species. The overall trap efficiency of the e.blue/l.blue XT was 23% for G. brevipalpis and 28% for G. austeni, and that of the e.blue/black XT was 16% for G. brevipalpis and 51% for G. austeni. Larger monopanels, painted e.blue/black on both sides, increased the catches of G. austeni females significantly by up to four times compared to the standard e.blue/black XT. This monopanel would be recommended for use as a simple and cost effective survey tool for both species in South Africa.
Adsorptive removal of 1-naphthol from water with Zeolitic imidazolate framework-67
NASA Astrophysics Data System (ADS)
Yan, Xinlong; Hu, Xiaoyan; Chen, Tao; Zhang, Shiyu; Zhou, Min
2017-08-01
1-Naphthol is widely used as an intermediate in the plastics, dyes, fibers and rubbers production areas, leading to the increasing detection of 1-naphthol in the soil and water environment, which is of particular concern due to its acute toxicity and negative environmental impacts. Considering the high surface area and good stability of ZIFs (zeolitic imidazole frameworks) material, ZIF-67 (a representative cobalt-based ZIFs material) was synthesized and applied as an adsorbent for removal of 1-naphthol from aqueous solution. The obtained ZIF-67 was characterized by XRD, TEM, XPS, N2 physisorption and TG, and the adsorption isotherm, kinetics, and regeneration of the adsorbent were studied in detail. The adsorption of 1-naphthol on ZIF-67 followed a pseudo-second-order equation kinetics and fitted Langmuir adsorption model with a maximum adsorption capacity of 339 mg/g at 313 K, which is much higher than that of the common adsorbents reported such as activated carbon and carbon nanotubes et al. The solution pH was found to be an important factor influencing the adsorption process, which could be explained by the predominant mechanism controlling the process, i.e. electrostatic attraction. In addition, the ZIF-67 showed desirable reusability toward 1-naphthol removal from alkaline aqueous solution.
African Retentions in Blues and Jazz.
ERIC Educational Resources Information Center
Meadows, Eddie S.
1979-01-01
The perseverance of African musical characteristics among American Blacks is an historic reality. African retentions have been recorded in Black music of the antebellum period. Various African scales and rhythms permeate Black American music today as evidenced in the retentions found in blues and jazz. (RLV)
Effects of display characteristics and individual differences on preferences of VDT icon design.
Shieh, Kong-King; Ko, Ya-Hsien
2005-04-01
This study explored the effects of display characteristics such as target/background color combination, single/simultaneous presentation, and individual differences by sex, and design specialty on preferences of VDT icon design. The results indicated black targets (black-on-white, black-on-yellow) and black backgrounds (red-on-black, yellow-on-black) were the most popular and white targets (white-on-red, white-on-black) and white backgrounds (blue-on-white, red-on-white) were the second most popular. As for the chromatic color combinations, yellow-on-blue was the most favored. Subjects rated color combinations under single presentation higher than those under simultaneous presentation. Women rated purplish targets and rated purplish and blue backgrounds higher than men. Subjects with design background favored black more either as a target or background, but they favored turquoise less than those without design background.
Mechanisms of Photophobia in Mild Traumatic Brain Injury in Human Subjects: Therapeutic Implications
2015-10-01
R, G, B and W). FMRI Stimuli The four fMRI runs consisted of 6 cycles of: 1. 20 s of 2.5 Hz Blue/Black Flicker alternating with 20 s Steady Black...7 2. 20 s of 2.5 Hz Red/Black Flicker , alternating with 20 s Steady Black 3. 20 s of Steady Blue alternating with 20 s Steady Red 4. 20 s of Steady...Blue alternating with 20 s Steady Green The preliminary studies confirmed that we can set all flicker frequencies at 2.5Hz to match the frequency used
Hernández, G. Laguna; Franco, A.E. Brechú; De-la-Cruz-Chacón, I.; González-Esquinca, A.R.
2015-01-01
Acetogenins (ACGs) are bioactive compounds with cytotoxic properties in different cell lines. They are antitumoural, antiparasitic, antimalarial, insecticidal, antimicrobial, anti-fungal and antibacterial. These secondary metabolites function in plant defence and are found in specific organelles and specific cells, thereby preventing toxicity to the plant itself and permitting site-specific defence. The aim of this work was to histochemically determine the in situ localisation of ACGs in the endosperm of Annona macroprophyllata seeds using Kedde’s reagent. Additionally, the co-localisation of ACGs with other storage molecules was analysed. The seeds were analysed after 6 and 10 days of imbibition, when 1 or 2 cm of the radicle had emerged and metabolism was fully established. The seeds were then transversally cut in half at the midline and processed using different histological and histochemical techniques. Positive reactions with Kedde’s reagent were only observed in fresh, unfixed sections that were preserved in water, and staining was found only in the large cells (the idioblasts) at the periphery of the endosperm. The ACGs’ positive reaction with Sudan III corroborated their lipid nature. Paraffin sections stained with Naphthol Blue Black showed reactions in the endosperm parenchyma cells and stained the proteoplasts blue, indicating that they might correspond to storage sites for albumin-like proteins. Lugol’s iodine, which is similar in chemical composition to Wagner’s reagent, caused a golden brown reaction product in the cytoplasm of the idioblasts, which may indicate the presence of alkaloids. Based on these results, we propose that Kedde’s reagent is an appropriate histochemical stain for detecting ACGs in situ in idioblasts and that idioblasts store ACGs and probably alkaloids. ACGs that are located in idioblasts found in restricted, peripheral areas of the endosperm could serve as a barrier that protects the seeds against insects and pathogen attack. PMID:26428881
Urinary biomarkers of occupational jet fuel exposure among Air Force personnel.
Smith, Kristen W; Proctor, Susan P; Ozonoff, A L; McClean, Michael D
2012-01-01
There is a potential for widespread occupational exposure to jet fuel among military and civilian personnel. Urinary metabolites of naphthalene have been suggested for use as short-term biomarkers of exposure to jet fuel (jet propulsion fuel 8 (JP8)). In this study, urinary biomarkers of JP8 were evaluated among US Air Force personnel. Personnel (n=24) were divided a priori into high, moderate, and low exposure groups. Pre- and post-shift urine samples were collected from each worker over three workdays and analyzed for metabolites of naphthalene (1- and 2-naphthol). Questionnaires and breathing-zone naphthalene samples were collected from each worker during the same workdays. Linear mixed-effects models were used to evaluate the exposure data. Post-shift levels of 1- and 2-naphthol varied significantly by a priori exposure group (levels in high group>moderate group>low group), and breathing-zone naphthalene was a significant predictor of post-shift levels of 1- and 2-naphthol, indicating that for every unit increase in breathing-zone naphthalene, there was an increase in naphthol levels. These results indicate that post-shift levels of urinary 1- and 2-naphthol reflect JP8 exposure during the work-shift and may be useful surrogates of JP8 exposure. Among the high exposed workers, significant job-related predictors of post-shift levels of 1- and 2-naphthol included entering the fuel tank, repairing leaks, direct skin contact with JP8, and not wearing gloves during the work-shift. The job-related predictors of 1- and 2-naphthol emphasize the importance of reducing inhalation and dermal exposure through the use of personal protective equipment while working in an environment with JP8.
A novel solution for hydroxylated PAHs removal by oxidative coupling reaction using Mn oxide.
Kang, Ki-Hoon; Lim, Dong-Min; Shin, Hyun-Sang
2008-01-01
In this study, removals of 1-naphthol by oxidative-coupling reaction using birnessite, one of the natural Mn oxides present in soil, was investigated in various experimental conditions (reaction time, Mn oxide loadings, pH). The removal efficiency of 1-naphthol by birnessite was high in all the experimental conditions, and UV-visible and mass spectrometric analyses on the supernatant after reaction confirmed that the reaction products were oligomers formed by oxidative-coupling reaction. Pseudo-first order rate constants, k, for the oxidative transformation of 1-naphthol by birnessite was derived from the kinetic experiments under various amounts of birnessite loadings, and using the observed pseudo-first order rate constants with respect to birnessite loadings, the surface area normalised specific rate constant, k(surf), was also determined to be 9.3 x 10(-4) (L/m(2).min) for 1-naphthol. In addition, the oxidative transformation of 1-naphthol was found to be dependent on solution pH, and the pseudo-first order rate constants were increased from 0.129 at pH 10 to 0.187 at pH 4. (c) IWA Publishing 2008.
NASA Astrophysics Data System (ADS)
Fleisher, Adam J.; Pratt, David W.; Cembran, Alessandro; Gao, Jiali
2010-06-01
The extensively studied photoacid β-naphthol exhibits a large decrease in pKa upon irradiation with ultraviolet light, in the condensed phase. β-naphthol is almost 10 million times more acidic in the excited electronic state, compared to the ground state. Motivated by this fact, we report here the measurement of the electronic dipole moments of the β-naphthol-water complex in both electronic states, from which estimates of the charge transfer from solute to solvent in both states will be made. Comparisons to ab initio and density functional theory calculations will also be reported. N. Mataga and T. Kubota, Molecular Interactions and Electronic Spectra (Marcel Dekker, New York, 1970). Y. Mo, J. Gao, S.D. Peyerimhoff, J. Chem. Phys. 112, 5530 (2000).
The Blues in Black Literature.
ERIC Educational Resources Information Center
Schultz, Elizabeth
1971-01-01
The literature of black America repeatedly reflects a native rootlessness and its creators' yearning for a home. The black writer settles his work in an ethos, which has evolved from an older African heritage, primarily in response to an omnipresent white society. In this document, one of these ethnic expressions--the blues--is examined as a means…
NASA Astrophysics Data System (ADS)
Akberali, H. B.; Trueman, E. R.; Black, J. E.; Hewitt, C.
1982-10-01
The effects of 1-naphthol, the first hydrolytic product of the insecticide Sevin ®, have been studied on the estuarine bivalve Scrobicularia. Median lethal times for 5 and 10 mg l -1 1-naphthol were 15 and 9 days respectively. Final concentrations of 1, 5, 10 and 20 mg l -1 of 1-naphthol resulted in the immediate contraction of the isolated siphon. The contractions were more pronounced at higher concentrations. Application of the same range of concentrations of 1-naphthol to intact Scrobicularia resulted in valve closure and bradycardia. The similarity between the results of median lethal time experiments and the isolated siphonal and behavioural responses of Scrobicularia indicates the feasibility of the use of the isolated siphon preparations to make rapid assessments of environmental stress conditions.
Attallah, M F; Ahmed, I M; Hamed, Mostafa M
2013-02-01
The present work investigates the potential use of metal hydroxides sludge (MHS) generated from hot dipping galvanizing plant for adsorption of Congo Red and Naphthol Green B dyes from aqueous solutions. Characterization of MHS included infrared and X-ray fluorescence analysis. The effect of shaking time, initial dye concentration, temperature, adsorbent dosage and pH has been investigated. The results of adsorption experiments indicate that the maximum capacity of Congo Red and Naphthol Green B dyes at equilibrium (q(e)) and percentage of removal at pH 6 are 40 mg/g, 93 %, and 10 mg/g, 52 %, respectively. Some kinetic models were used to illustrate the adsorption process of Congo Red and Naphthol Green B dyes using MHS waste. Thermodynamic parameters such as (ΔG, ΔS, and ΔH) were also determined.
Zhou, Caihong; Tong, Shanshan; Chang, Yunxia; Jia, Qiong; Zhou, Weihong
2012-04-01
Ionic liquid (IL) based dispersive liquid-liquid microextraction (DLLME) with back-extraction coupled with capillary electrophoresis ultraviolet detection was developed to determine four phenolic compounds (bisphenol-A, β-naphthol, α-naphthol, 2, 4-dichlorophenol) in aqueous cosmetics. The developed method was used to preconcentrate and clean up the four phenolic compounds including two steps. The analytes were transferred into room temperature ionic liquid (1-octyl-3-methylimidazolium hexafluorophosphate, [C(8) MIM][PF(6) ]) rich-phase in the first step. In the second step, the analytes were back-extracted into the alkaline aqueous phase. The effects of extraction parameters, such as type and volume of extraction solvent, type and volume of disperser, extraction and centrifugal time, sample pH, salt addition, and concentration and volume of NaOH in back-extraction were investigated. Under the optimal experimental conditions, the preconcentration factors were 60.1 for bisphenol-A, 52.7 for β-naphthol, 49.2 for α-naphthol, and 18.0 for 2, 4-dichlorophenol. The limits of detection for bisphenol-A, β-naphthol, α-naphthol and 2, 4-dichlorophenol were 5, 5, 8, and 100 ng mL(-1), respectively. Four kinds of aqueous cosmetics including toner, soften lotion, make-up remover, and perfume were analyzed and yielded recoveries ranging from 81.6% to 119.4%. The main advantages of the proposed method are quick, easy, cheap, and effective. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Chao, Yi-Chun E.; Kupper, Lawrence L.; Serdar, Berrin; Egeghy, Peter P.; Rappaport, Stephen M.; Nylander-French, Leena A.
2006-01-01
Jet propulsion fuel 8 (JP-8) is the major jet fuel used worldwide and has been recognized as a major source of chemical exposure, both inhalation and dermal, for fuel-cell maintenance workers. We investigated the contributions of dermal and inhalation exposure to JP-8 to the total body dose of U.S. Air Force fuel-cell maintenance workers using naphthalene as a surrogate for JP-8 exposure. Dermal, breathing zone, and exhaled breath measurements of naphthalene were obtained using tape-strip sampling, passive monitoring, and glass bulbs, respectively. Levels of urinary 1- and 2-naphthols were determined in urine samples and used as biomarkers of JP-8 exposure. Multiple linear regression analyses were conducted to investigate the relative contributions of dermal and inhalation exposure to JP-8, and demographic and work-related covariates, to the levels of urinary naphthols. Our results show that both inhalation exposure and smoking significantly contributed to urinary 1-naphthol levels. The contribution of dermal exposure was significantly associated with levels of urinary 2-naphthol but not with urinary 1-naphthol among fuel-cell maintenance workers who wore supplied-air respirators. We conclude that dermal exposure to JP-8 significantly contributes to the systemic dose and affects the levels of urinary naphthalene metabolites. Future work on dermal xenobiotic metabolism and toxicokinetic studies are warranted in order to gain additional knowledge on naphthalene metabolism in the skin and the contribution to systemic exposure. PMID:16451852
Chao, Yi-Chun E; Kupper, Lawrence L; Serdar, Berrin; Egeghy, Peter P; Rappaport, Stephen M; Nylander-French, Leena A
2006-02-01
Jet propulsion fuel 8 (JP-8) is the major jet fuel used worldwide and has been recognized as a major source of chemical exposure, both inhalation and dermal, for fuel-cell maintenance workers. We investigated the contributions of dermal and inhalation exposure to JP-8 to the total body dose of U.S. Air Force fuel-cell maintenance workers using naphthalene as a surrogate for JP-8 exposure. Dermal, breathing zone, and exhaled breath measurements of naphthalene were obtained using tape-strip sampling, passive monitoring, and glass bulbs, respectively. Levels of urinary 1- and 2-naphthols were determined in urine samples and used as biomarkers of JP-8 exposure. Multiple linear regression analyses were conducted to investigate the relative contributions of dermal and inhalation exposure to JP-8, and demographic and work-related covariates, to the levels of urinary naphthols. Our results show that both inhalation exposure and smoking significantly contributed to urinary 1-naphthol levels. The contribution of dermal exposure was significantly associated with levels of urinary 2-naphthol but not with urinary 1-naphthol among fuel-cell maintenance workers who wore supplied-air respirators. We conclude that dermal exposure to JP-8 significantly contributes to the systemic dose and affects the levels of urinary naphthalene metabolites. Future work on dermal xenobiotic metabolism and toxicokinetic studies are warranted in order to gain additional knowledge on naphthalene metabolism in the skin and the contribution to systemic exposure.
Utilization of Natural Zeolite from Ponorogo and Purworejo for Naphthol Substance Adsorption
NASA Astrophysics Data System (ADS)
Imandiani, Sundus; Indira, Christine; Johan, Anthony; Budiyono
2018-02-01
Indonesia has many zeolite producing areas yet untapped. Researchers developed the utilization of natural zeolites useful for the adsorption of naphthol dyes commonly found in batik waste. In this study researchers used natural zeolites from Purworejo and Ponorogo that are activated using hydrochloric acid that is used for adsorption. The purpose of this research is to know the effect of natural zeolite activation from Ponorogo and Purworejo on the effectiveness of adsorption of naphthol dyes widely used in batik industry. Natural zeolite was activated using HCl concentration of 1.3N; 1.8N; 3.2N; and 3.9N for 60 minutes. The methods are preparation of natural zeolite from Purworejo and Ponorogo, dealumination using hydrochloric acid, adsorption process of naphthol dyes using activated zeolite, and test of adsorption result with uv-vis spectrophotometry. The test results showed that the higher HCl concentration will increase adsorption capacity. This can be known from the concentration of naphthol dye which decreased both using natural zeolite Ponorogo and Purworejo. While the effectiveness of adsorption shows natural zeolite Purworejo has a greater adsorption capacity than Ponorogo with optimum conditions of dealumination using concentration HCl 3,9N.
Chowdhury, Chandra; Jahiruddin, Sheik; Datta, Ayan
2016-04-07
Phosphorene (Pn) is stabilized as a layered material like graphite, yet it possess a natural direct band gap (Eg = 2.0 eV). Interestingly, unlike graphene, Pn exhibits a much richer phase diagram which includes distorted forms like the stapler-clip (black Pn, α form) and chairlike (blue Pn, β form) structures. The existence of these phases is attributed to pseudo-Jahn-Teller (PJT) instability of planar hexagonal P6(6-) rings. In both cases, the condition for vibronic instability of the planar P6(6-) rings is satisfied. Doping with electron donors like tetrathiafulvalene and tetraamino-tetrathiafulvalene and electron acceptors like tetracyanoquinodimethane and tetracyanoethylene convert blue Pn into N-type and black Pn into efficient P-type semiconductors, respectively. Interestingly, pristine blue Pn, an indirect gap semiconductor, gets converted into a direct gap semiconductor on electron or hole doping. Because of comparatively smaller undulation in blue Pn (with respect to black Pn), the van der Waals interactions between the dopants and blue Pn is stronger. PJT distortions for two-dimensional phosphorus provides a unified understanding of structural features and chemical reactivity in its different phases.
2014-01-01
Background Naphthalene exposures for most non-occupationally exposed individuals occur primarily indoors at home. Residential indoor sources include pest control products (specifically moth balls), incomplete combustion such as cigarette smoke, woodstoves and cooking, some consumer and building products, and emissions from gasoline sources found in attached garages. The study aim was to assess naphthalene exposure in pregnant women from Canada, using air measurements and biomarkers of exposure. Methods Pregnant women residing in Ottawa, Ontario completed personal and indoor air sampling, and questionnaires. During pregnancy, pooled urine voids were collected over two 24-hour periods on a weekday and a weekend day. At 2–3 months post-birth, they provided a spot urine sample and a breast milk sample following the 24-hour air monitoring. Urines were analyzed for 1-naphthol and 2-naphthol and breast milk for naphthalene. Simple linear regression models examined associations between known naphthalene sources, air and biomarker samples. Results Study recruitment rate was 11.2% resulting in 80 eligible women being included. Weekday and weekend samples were highly correlated for both personal (r = 0.83, p < 0.0001) and indoor air naphthalene (r = 0.91, p < 0.0001). Urine specific gravity (SG)-adjusted 2-naphthol concentrations collected on weekdays and weekends (r = 0.78, p < 0.001), and between pregnancy and postpartum samples (r = 0.54, p < 0.001) were correlated. Indoor and personal air naphthalene concentrations were significantly higher post-birth than during pregnancy (p < 0.0001 for signed rank tests); concurrent urine samples were not significantly different. Naphthalene in breast milk was associated with urinary 1-naphthol: a 10% increase in 1-naphthol was associated with a 1.6% increase in breast milk naphthalene (95% CI: 0.2%-3.1%). No significant associations were observed between naphthalene sources reported in self-administered questionnaires and the air or biomarker concentrations. Conclusions Median urinary concentrations of naphthalene metabolites tended to be similar to (1-naphthol) or lower (2-naphthol) than those reported in a Canadian survey of women of reproductive age. Only urinary 1-naphthol and naphthalene in breast milk were associated. Potential reasons for the lack of other associations include a lack of sources, varying biotransformation rates and behavioural differences over time. PMID:24767676
Elovaara, Eivor; Väänänen, Virpi; Mikkola, Jouni
2003-04-01
Two fluorimetric HPLC methods are described for the quantification of naphthols, phenanthrols and 1-hydroxypyrene (1-OHP) in urine specimens obtained from male Wistar rats exposed to naphthalene, phenanthrene and pyrene. The polycyclic aromatic hydrocarbons (PAHs) were given intraperitoneally, either alone (1.0 mmol/kg body weight) or as an equimolar mixture (0.33 mmol/kg), using the same dosages for repeated treatments on week 1 and week 2. Between these treatments, PAH-metabolizing activities encoded by aryl hydrocarbon (Ah) receptor-controlled genes were induced in the rats with beta-naphthoflavone (betaNF). Chromatographic separation of five phenanthrols (1-, 2-, 3-, 4-, and 9-isomers) was accomplished using two different RP C-18 columns. Despite selective detection (programmable wavelengths), the quantification limits in the urine ranged widely: 1-OHP (0.18 microg/l)
Automated selection of the most epithelium-rich areas in gynecologic tumor sections.
Schipper, N W; Baak, J P; Smeulders, A W
1991-12-01
The paper describes an image analysis technique for automated selection of the epithelium-rich areas in standard paraffin tissue sections of ovarian and endometrial premalignancies and malignancies. Two staining procedures were evaluated, Feulgen (pararosanilin) and CAM 5.2, demonstrating the presence of cytokeratin 8 and 18; both were counterstained with naphthol yellow. The technique is based on the corresponding image processing method of automated estimation of the percentage of epithelium in interactively selected microscope fields. With the technique, one image is recorded with a filter to demonstrate where epithelium and stroma lie. This filter is chosen according to the type of staining: it is yellow (lambda = 552 nm) for Feulgen and blue (lambda = 470 nm) for anticytokeratin CAM 5.2. When stroma cannot be distinguished from lumina with the green filter or from epithelium with the blue filter, a second image is recorded from the same microscope field, with a blue filter (lambda = 420 nm) for Feulgen and a yellow filter (lambda = 576 nm) for anticytokeratin CAM 5.2. Discrimination between epithelium and stroma is based on the image contrast range and the packing of nuclei in the yellow image and on the automated classification of the gray value histogram peaks in the blue image. For Feulgen stain the method was evaluated on 30 ovarian tumors of the common epithelial types (8 borderline tumors and 22 carcinomas with various degrees of differentiation) and 30 endometrial carcinomas of different grades.(ABSTRACT TRUNCATED AT 250 WORDS)
NASA Astrophysics Data System (ADS)
Scherrer, Nadim C.; Stefan, Zumbuehl; Francoise, Delavy; Annette, Fritsch; Renate, Kuehnen
2009-08-01
Some 170 organic pigments relevant to artist's paints have been collected from historic collections and modern manufacturers. The number includes multiples of the same pigment from different sources and comprises 118 different color indices (C.I.). All of them have been analysed with FTIR spectroscopy and 125 pigments (93 different C.I. No.s) of particular relevance to artist's paints have been characterised with Raman spectroscopy so far. The pigment collection encompasses the following pigment classes and subgroups: monoazo pigments represented by acetoacetic arylide yellow (hansa yellow), β-naphthol, BON, naphthol AS and benzimidazolone; disazo pigments with disazo condensation, diarylide, bisacetoacetarylide, pyrazolone; azo-azomethin metal complex pigments; non-azo, polycyclic pigments such as phthalocyanines, diketopyrrolo-pyrroles (DPP), perylenes and perinones, quinacridones, isoindolinones, polycarbocyclic anthraquinones and dioxanines. The selection of references was based on availability (historic collections) and current use in 16 acrylic, alkyd and oil-based artist's paints, and it covers pigment colors PY yellow (27 C.I. No.s), PR red (38), PO orange (9), PB blue (8), PV violet (6), PG green (3) and PBr brown (2). Besides peak tables and spectra patterns, flow charts based on color, pigment class, group and individual color index are presented to help identification of unknowns and mixed paint samples. While Raman could isolate all different C.I. numbers, multiple references of the same C.I. from different sources could not be distinguished.
NASA Astrophysics Data System (ADS)
Makarycheva, A. I.; Slizhov, Yu. G.
2017-09-01
Gas chromatography sorbents based on Silokhrom C80 and modified by 1-phenylazo-2-naphtholic complexes of 3 d metals (Co(II), Ni(II), Cu(II)) are obtained. Their structural, chromatographic, and sorption characteristics are investigated. It is found that modifying them with 1-phenylazo-2-naphthols of transition metals has a considerable effect on the chromatographic polarity and selectivity of sorption materials. The prospects for the practical application of the obtained sorbents are demonstrated by experiments on the gas chromatographic separation of mixtures of different classes of organic compounds.
Li, Yin; Cao, Ruofan; Wu, Xiaofei; Huang, Jianhan; Deng, Shuguang; Lu, Xiuyang
2013-06-15
A hypercrosslinked poly(styrene-co-divinylbenzene) resin (TEPA) was synthesized and characterized as a specific polymeric adsorbent for concentrating berberine hydrochloride from aqueous solutions. Three organic molecules of different sizes (2-naphthol, berberine hydrochloride, and Congo red) were used as target molecules to elucidate the molecular sieving effect of the TEPA adsorbent. Because the TEPA adsorbent has a pore structure consisting mainly of micropores and mesopores, the adsorption of 2-naphthol from aqueous solutions is very efficient due to the micropore filling effect. The adsorption of berberine hydrochloride mostly takes place in the mesopores as well as macropores, while the adsorption of Congo red mainly occurs in the macropores. The smaller adsorbate molecule (2-naphthol) reaches the adsorption equilibrium much faster than the larger ones (berberine hydrochloride and Congo red). An adsorption breakthrough experiment with an aqueous solution containing 2-naphthol and berberine hydrochloride demonstrated that the TEPA adsorbent could effectively remove 2-naphthol from berberine hydrochloride at 0-107 BV (bed volume, 1 BV=10 ml), and the berberine hydrochloride concentration was increased from 66.7% to 99.4%, suggesting that this polymeric adsorbent is promising for purifying berberine hydrochloride and similar alkaloids from herbal plant extracts. Copyright © 2013 Elsevier Inc. All rights reserved.
Qi, Zhichong; Hou, Lei; Zhu, Dongqiang; Ji, Rong; Chen, Wei
2014-09-02
With the increasing production and use of graphene oxide, the environmental implications of this new carbonaceous nanomaterial have received much attention. In this study, we found that the presence of low concentrations of graphene oxide nanoparticles (GONPs) significantly enhanced the transport of 1-naphthol in a saturated soil, but affected the transport of phenanthrene to a much smaller extent. The much stronger transport-enhancement effect on 1-naphthol was due to the significant desorption hysteresis (both thermodynamically irreversible adsorption and slow desorption kinetics) of GONP-adsorbed 1-naphthol, likely stemmed from the specific polar interactions (e.g., H-bonding) between 1-naphthol and GONPs. Increasing ionic strength or the presence of Cu(II) ion (a complexing cation) generally increased the transport-enhancement capability of GONPs, mainly by increasing the aggregation of GONPs and thus, sequestering adsorbed contaminant molecules. Interestingly, modifying GONPs with Suwannee River humic acid or sodium dodecyl sulfate had little or essentially no effect on the transport-enhancement capability of GONPs, in contrast with the previously reported profound effects of humic acids and surfactants on the transport-enhancement capability of C60 nanoparticles. Overall, the findings indicate that GONPs in the aquatic environment may serve as an effective carrier for certain organic compounds that can interact with GONPs through strong polar interactions.
NASA Astrophysics Data System (ADS)
Szczepanik, Beata
2015-11-01
The excited state proton transfer (ESPT) has been extensively studied for hydroxyarenes, phenols, naphthols, hydroxystilbenes, etc., which undergo large enhancement of acidity upon electronic excitation, thus classified as photoacids. The changes of acidic character in the excited state of cyano-substituted derivatives of phenol, hydroxybiphenyl and naphthol are reviewed in this paper. The acidity constants pKa in the ground state (S0), pKa∗ in the first singlet excited state (S1) and the change of the acidity constant in the excited state ΔpKa for the discussed compounds are summarized and compared. The results of the acidity studies show, that the "electro-withdrawing" CN group in the molecules of naphthol, hydroxybiphenyl and phenol causes dramatic increase of their acidity in the excited state in comparison to the ground state. This effect is greatest for the cyanonaphthols (the doubly substituted CN derivatives are almost as strong as a mineral acid in the excited state), comparable for cyanobiphenyls, and smaller for phenol derivatives. The increase of acidity enables proton transfer to various organic solvents, and the investigation of ESPT can be extended to a variety of solvents besides water. The results of theoretical investigations were also presented and used for understanding the protolytic equilibria of cyano derivatives of naphthol, hydroxybiphenyl and phenol.
19 CFR 141.90 - Notation of tariff classification and value on invoice.
Code of Federal Regulations, 2013 CFR
2013-04-01
.... (d) Importer's notations in blue or black ink. Except when invoice line data are linked to an entry... the invoice by the importer or customs broker must be in blue or black ink. [T.D. 73-175, 38 FR 17447...
19 CFR 141.90 - Notation of tariff classification and value on invoice.
Code of Federal Regulations, 2012 CFR
2012-04-01
.... (d) Importer's notations in blue or black ink. Except when invoice line data are linked to an entry... the invoice by the importer or customs broker must be in blue or black ink. [T.D. 73-175, 38 FR 17447...
19 CFR 141.90 - Notation of tariff classification and value on invoice.
Code of Federal Regulations, 2011 CFR
2011-04-01
.... (d) Importer's notations in blue or black ink. Except when invoice line data are linked to an entry... the invoice by the importer or customs broker must be in blue or black ink. [T.D. 73-175, 38 FR 17447...
19 CFR 141.90 - Notation of tariff classification and value on invoice.
Code of Federal Regulations, 2014 CFR
2014-04-01
.... (d) Importer's notations in blue or black ink. Except when invoice line data are linked to an entry... the invoice by the importer or customs broker must be in blue or black ink. [T.D. 73-175, 38 FR 17447...
Buzzini, Patrick; Massonnet, Genevieve
2013-11-01
Raman spectroscopy has been applied to characterize fiber dyes and determine the discriminating ability of the method. Black, blue, and red acrylic, cotton, and wool samples were analyzed. Four excitation sources were used to obtain complementary responses in the case of fluorescent samples. Fibers that did not provide informative spectra using a given laser were usually detected using another wavelength. For any colored acrylic, the 633-nm laser did not provide Raman information. The 514-nm laser provided the highest discrimination for blue and black cotton, but half of the blue cottons produced noninformative spectra. The 830-nm laser exhibited the highest discrimination for red cotton. Both visible lasers provided the highest discrimination for black and blue wool, and NIR lasers produced remarkable separation for red and black wool. This study shows that the discriminating ability of Raman spectroscopy depends on the fiber type, color, and the laser wavelength. © 2013 American Academy of Forensic Sciences.
Urinary naphthol metabolites and chromosomal aberrations in 5 yr old children
Orjuela, Manuela A.; Liu, XinHua; Miller, Rachel L.; Warburton, Dorothy; Tang, DeLiang; Jobanputra, Vaidehi; Hoepner, Lori; Suen, Ida Hui; Diaz-Carreno, Silvia; Li, Zheng; Sjodin, Andreas; Perera, Frederica P.
2012-01-01
Background Exposure to naphthalene, an IARC-classified possible carcinogen and polycyclic aromatic hydrocarbon (PAH), is widespread, though resulting health effects are poorly understood. Metabolites of naphthalene, 1- and 2-naphthol, are measurable in urine and are biomarkers of personal exposure. Chromosomal aberrations (CAs), including translocations, are established markers of cancer risk and a bio-dosimeter of clastogenic exposures. Although prenatal (maternal) PAH exposure predicts CAs in cord blood, few studies have examined CAs in school-age children and none has examined their association with metabolites of specific PAHs. Methods Using Whole Chromosome Paint Fluorescent in Situ Hybridization, we documented CAs including translocations, in 113 five year old urban minority children and examined their association with concurrent concentrations of PAH metabolites measured in urine. Results We report that in lymphocytes, the occurrence and frequency of CAs including translocations are associated with levels of urinary 1- and 2-naphthol. When doubling the levels of urinary naphthols, gender-adjusted Odds Ratio (OR) for CAs are 1.63 (95%CI: 1.21, 2.19) and 1.44 (95%CI: 1.02, 2.04) for 1-and 2-naphthol respectively; and for translocations: OR=1.55 (95%CI: 1.11-2.17) and 1.92 (95%CI: 1.20-3.08) for 1- and 2-naphthol respectively. Conclusion Our results demonstrate that markers of exposure to naphthalene in children are associated with translocations in a dose related manner, and that naphthalene may be a clastogen. Impact Indoor exposure to elevated levels of naphthalene is prevalent in large regions of the world. This study is the first to present an association between a marker of naphthalene exposure and a pre-carcinogenic effect in humans. PMID:22573794
NASA Astrophysics Data System (ADS)
Arif Khalil, R. M.; Ahmad, Javed; Rana, Anwar Manzoor; Bukhari, Syed Hamad; Tufiq Jamil, M.; Tehreem, Tuba; Nissar, Umair
2018-05-01
In this investigation, structural, dynamical and thermal properties of black and blue phosphorene (P) are presented through the first principles calculations based on the density functional theory (DFT). These DFT calculations depict that due to the approximately same values of ground state energy at zero Kelvin and Helmholtz free energy at room-temperature, it is expected that both structures can coexist at transition temperature. Lattice dynamics of both phases were investigated by using the finite displacement supercell approach. It is noticed on the basis of harmonic approximation thermodynamic calculations that the blue phase is thermodynamically more stable than the black phase above 155 K.
Huang, Kuo-Chen; Chiang, Shu-Ying; Chen, Chen-Fu
2008-02-01
The effects of color combinations of an icon's symbol/background and components of flicker and flicker rate on visual search performance on a liquid crystal display screen were investigated with 39 subjects who searched for a target icon in a circular stimulus array (diameter = 20 cm) including one target and 19 distractors. Analysis showed that the icon's symbol/background color significantly affected search time. The search times for icons with black/red and white/blue were significantly shorter than for white/yellow, black/yellow, and black/blue. Flickering of different components of the icon significantly affected the search time. Search time for an icon's border flickering was shorter than for an icon symbol flickering; search for flicker rates of 3 and 5 Hz was shorter than that for 1 Hz. For icon's symbol/background color combinations, search error rate for black/blue was greater than for black/red and white/blue combinations, and the error rate for an icon's border flickering was lower than for an icon's symbol flickering. Interactions affected search time and error rate. Results are applicable to design of graphic user interfaces.
Liao, R; Zhang, X; Chen, Q; Wang, Z; Wang, Q; Yang, C; Pan, Y
2016-10-01
This study was designed to investigate the genetic basis of growth and egg traits in Dongxiang blue-shelled chickens and White Leghorn chickens. In this study, we employed a reduced representation sequencing approach called genotyping by genome reducing and sequencing to detect genome-wide SNPs in 252 Dongxiang blue-shelled chickens and 252 White Leghorn chickens. The Dongxiang blue-shelled chicken breed has many specific traits and is characterized by blue-shelled eggs, black plumage, black skin, black bone and black organs. The White Leghorn chicken is an egg-type breed with high productivity. As multibreed genome-wide association studies (GWASs) can improve precision due to less linkage disequilibrium across breeds, a multibreed GWAS was performed with 156 575 SNPs to identify the associated variants underlying growth and egg traits within the two chicken breeds. The analysis revealed 32 SNPs exhibiting a significant genome-wide association with growth and egg traits. Some of the significant SNPs are located in genes that are known to impact growth and egg traits, but nearly half of the significant SNPs are located in genes with unclear functions in chickens. To our knowledge, this is the first multibreed genome-wide report for the genetics of growth and egg traits in the Dongxiang blue-shelled and White Leghorn chickens. © 2016 Stichting International Foundation for Animal Genetics.
A SIMPLE HPLC METHOD FOR DETECTING CARBARYL AND 1-NAPHTHOL IN BIOLOGICAL TISSUES.
Carbamates are a class of pesticide used in both agricultural and residential applications. A simple HPLC method for detecting Carb and its metabolite 1-naphthol (Naph) in tissues was developed to try to correlate tissue levels of carbaryl (Carb) (a prototypical carbamate) with c...
USDA-ARS?s Scientific Manuscript database
Stable fly management has been challenging. Insecticide-treated targets made from blue and black fabric, developed in Africa, were evaluated in Louisiana and Florida to determine if they would attract and kill stable flies. Untreated targets were used to answer questions about configuration, size an...
ERIC Educational Resources Information Center
Fisher, Diane
2004-01-01
It is so obvious that the sky is blue in the daytime and black at night, but it took the smartest humans thousands of years of observation, thought, discussion, conjecture, and analysis to finally come up with answers that make scientific sense as to why the sky is these colors. This article discusses light and the scientific research…
Tas, J; James, J
1981-09-01
The 'total protein staining' of biological specimens with the electrostatically binding Naphthol Yellow S or the covalently binding dinitrofluorobenzene must be interpreted as methods which yield data on the specific amino acid pool of the proteins concerned. Both dyes bind to certain free amino-acid side-chains, giving different dye--protein ratios for various proteins. In the presence of DNA, dinitrofluorobenzene stains all proteins present in cell nuclei, whereas Naphthol Yellow S only stains the majority of the non-histone proteins. When protein staining methods are combined with the Feulgen--Pararosanile (SO2) procedure for DNA, decreased Feulgen--DNA contents were measured in dinitrofluorobenzene-stained isolated nuclei and lymphocytes.
Methylation of 2-Naphthol Using Dimethyl Carbonate under Continuous-Flow Gas-Phase Conditions
ERIC Educational Resources Information Center
Tundo, Pietro; Rosamilia, Anthony E.; Arico, Fabio
2010-01-01
This experiment investigates the methylation of 2-naphthol with dimethyl carbonate. The volatility of the substrates, products, and co-products allows the reaction to be performed using a continuous-flow gas-phase setup at ambient pressure. The reaction uses catalytic quantities of base, achieves high conversion, produces little waste, and…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sueyoshi, Noriyuki; Takao, Toshihiko; Nimura, Takaki
2007-11-23
Ca{sup 2+}/calmodulin-dependent protein kinase phosphatase (CaMKP) and its nuclear isoform CaMKP-N are unique Ser/Thr protein phosphatases that negatively regulate the Ca{sup 2+}/calmodulin-dependent protein kinase (CaMK) cascade by dephosphorylating multifunctional CaMKI, II, and IV. However, the lack of specific inhibitors of these phosphatases has hampered studies on these enzymes in vivo. In an attempt to obtain specific inhibitors, we searched inhibitory compounds and found that Evans Blue and Chicago Sky Blue 6B served as effective inhibitors for CaMKP. These compounds also inhibited CaMKP-N, but inhibited neither protein phosphatase 2C, another member of PPM family phosphatase, nor calcineurin, a typical PPP familymore » phosphatase. The minimum structure required for the inhibition was 1-amino-8-naphthol-4-sulfonic acid. When Neuro2a cells cotransfected with CaMKIV and CaMKP-N were treated with these compounds, the dephosphorylation of CaMKIV was strongly suppressed, suggesting that these compounds could be used as potent inhibitors of CaMKP and CaMKP-N in vivo as well as in vitro.« less
Blue Thursday? Homicide and suicide among urban 15-24-year-old black male Americans.
Greenberg, M; Schneider, D
1992-01-01
A comparative analysis was made of day of the week variations in homicide and suicide deaths among 15-24-year-old white males, black males, white females, and black females in the 22 counties with the most black persons in the United States. Thirty-seven percent of black Americans and 14 percent of white Americans lived in these densely populated counties. The authors expected a weekend excess of homicide and a Monday excess of suicide. They found a pronounced excess of homicides on weekends, especially among white males. A slight excess of suicide was observed on Monday, but other slight excesses of suicide were also found. Young black males exhibited an unexpected excess of homicides and suicides on Thursday. On Thursdays the black male-white male ratio for homicide was 1.43 and for suicide, 1.26. Possible explanations for the young black males' blue Thursday phenomenon are offered. PMID:1594735
Phase Transition between Black and Blue Phosphorenes: A Quantum Monte Carlo Study
NASA Astrophysics Data System (ADS)
Li, Lesheng; Yao, Yi; Reeves, Kyle; Kanai, Yosuke
Phase transition of the more common black phosphorene to blue phosphorene is of great interest because they are predicted to exhibit unique electronic and optical properties. However, these two phases are predicted to be separated by a rather large energy barrier. In this work, we study the transition pathway between black and blue phosphorenes by using the variable cell nudge elastic band method combined with density functional theory calculation. We show how diffusion quantum Monte Carlo method can be used for determining the energetics of the phase transition and demonstrate the use of two approaches for removing finite-size errors. Finally, we predict how applied stress can be used to control the energetic balance between these two different phases of phosphorene.
Chen, Zi-Cong; Tong, Lang; Du, Zhi-Bo; Mao, Zhi-Feng; Zhang, Xue-Jing; Zou, Yong; Yan, Ming
2018-04-18
A new synthetic approach to dihydrofuran derivatives via the annulation reaction of β-naphthols and 4-hydroxycoumarins with vinylsulfonium salts has been developed. A variety of dihydrofuran derivatives were prepared in moderate to good yields under mild conditions. The products could be readily transformed to the corresponding furans via the dehydrogenation with DDQ.
Genetics Home Reference: Carney complex
... addition, some affected individuals have at least one blue-black mole called a blue nevus. Related Information What does it mean if ... Carney Syndrome LAMB - Lentigines, atrial myxoma, mucocutaneous myoma, blue nevus syndrome NAME - Nevi, atrial myxoma, skin myxoma, ...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Romero, V.H.; De la Rosa, E., E-mail: elder@cio.mx; Salas, P.
In this paper, we report the obtained strong broadband blue photoluminescence (PL) emission centered at 427 nm for undoped BaZrO{sub 3} observed after 266 nm excitation of submicron crystals prepared by hydrothermal/calcinations method. This emission is enhanced with the introduction of Tm{sup 3+} ions and is stronger than the characteristic PL blue emission of such lanthanide. The proposed mechanism of relaxation for host lattice emission is based on the presence of oxygen vacancies produced during the synthesis process and the charge compensation due to the difference in the electron valence between dopant and substituted ion in the host. Brilliant whitemore » light emission with a color coordinate of (x=0.29, y=0.32) was observed by combining the blue PL emission from the host with the green and red PL emission from Tb{sup 3+} and Eu{sup 3+} ions, respectively. The color coordinate can be tuned by changing the ratio between blue, green and red band by changing the concentration of lanthanides. - Graphical abstract: Strong blue emission from undoped BaZrO{sub 3} phosphor and white light emission by doping with Tb{sup 3+} (green) and Eu{sup 3+} (red) after 266 nm excitation. Highlights: Black-Right-Pointing-Pointer Blue emission from BaZrO{sub 3} phosphor. Black-Right-Pointing-Pointer Blue emission enhanced with Tm{sup 3+}. Black-Right-Pointing-Pointer White light from BaZrO{sup 3+} phosphor.« less
Rio-Zamorano, Carlos A.; Meneses-Ochoa, Itzel G.; Brechu-Franco, Alicia E.
2017-01-01
Mexico is a megadiverse country that has 3600 to 4000 species of medicinal plants, of which approximately 800 are used to treat conditions related to diabetes mellitus (DM). DM is a chronic degenerative disease of energy metabolism that exists as two types: type 1 (DM1) and type 2 (DM2). DM is considered a public health problem that affects 7% of the Mexican population older than 20 years. DM is clinically controlled with hypoglycaemic drugs, alpha-glucosidase inhibitors, insulin secretion stimulants or the direct application of insulin. The hypoglycaemic effectiveness of specific molecules has been determined only for some medicinal plants in Mexico used to treat DM2. The presence of molecules called glucokinins, wich are similar to animal insulin molecules, has been reported in some plant species; glucokinins act as both growth factors and regulators of glucose metabolism in plants. Therefore, we hypothesized that the hypoglycaemic effectiveness of some of the popularly used species for the control of DM could be due to the presence of glucokinin, as reported for Bauhinia variegata. The goal of this work was to use histochemistry to detect, the accumulation of protein that is immunocytochemically compatible with glucokinin in slide sections of hypoglycaemic species used as remedies for DM2. The top fourteen most used medicinal plants in Mexico were selected for study via microscopic sections. Proteins were histochemically detected using naphthol blue black and Johansen’s quadruple stain, and the immunocytochemical correspondence of the proteins with glucokinin was investigated using an insulin antibody. All species studied reacted positively to proteins and glucokinin in the same structures. The presence of glucokinin in these structures and the corresponding hypoglycaemic effects are discussed in the context of the actions of other compounds. PMID:28735523
Gagl, Benjamin
2016-01-01
Highlighted text in the Internet (i.e., hypertext) is predominantly blue and underlined. The perceptibility of these hypertext characteristics was heavily questioned by applied research and empirical tests resulted in inconclusive results. The ability to recognize blue text in foveal and parafoveal vision was identified as potentially constrained by the low number of foveally centered blue light sensitive retinal cells. The present study investigates if foveal and parafoveal perceptibility of blue hypertext is reduced in comparison to normal black text during reading. A silent-sentence reading study with simultaneous eye movement recordings and the invisible boundary paradigm, which allows the investigation of foveal and parafoveal perceptibility, separately, was realized (comparing fixation times after degraded vs. un-degraded parafoveal previews). Target words in sentences were presented in either black or blue and either underlined or normal. No effect of color and underlining, but a preview benefit could be detected for first pass reading measures. Fixation time measures that included re-reading, e.g., total viewing times, showed, in addition to a preview effect, a reduced fixation time for not highlighted (black not underlined) in contrast to highlighted target words (either blue or underlined or both). The present pattern reflects no detectable perceptual disadvantage of hyperlink stimuli but increased attraction of attention resources, after first pass reading, through highlighting. Blue or underlined text allows readers to easily perceive hypertext and at the same time readers re-visited highlighted words longer. On the basis of the present evidence, blue hypertext can be safely recommended to web designers for future use.
Uttarkar, Sagar; Dukare, Sandeep; Bopp, Bertan; Goblirsch, Michael; Jose, Joachim; Klempnauer, Karl-Heinz
2015-06-01
The transcription factor c-Myb is highly expressed in hematopoietic progenitor cells and controls the transcription of genes important for lineage determination, cell proliferation, and differentiation. Deregulation of c-Myb has been implicated in the development of leukemia and certain other types of human cancer. c-Myb activity is highly dependent on the interaction of the c-Myb with the KIX domain of the coactivator p300, making the disruption of this interaction a reasonable strategy for the development of Myb inhibitors. Here, we have used bacterial Autodisplay to develop an in vitro binding assay that mimics the interaction of Myb and the KIX domain of p300. We have used this binding assay to investigate the potential of Naphthol AS-E phosphate, a compound known to bind to the KIX domain, to disrupt the interaction between Myb and p300. Our data show that Naphthol AS-E phosphate interferes with the Myb-KIX interaction in vitro and inhibits Myb activity in vivo. By using several human leukemia cell lines, we demonstrate that Naphthol AS-E phosphate suppresses the expression of Myb target genes and induces myeloid differentiation and apoptosis. Our work identifies Naphthol AS-E phosphate as the first low molecular weight compound that inhibits Myb activity by disrupting its interaction with p300, and suggests that inhibition of the Myb-KIX interaction might be a useful strategy for the treatment of leukemia and other tumors caused by deregulated c-Myb. ©2015 American Association for Cancer Research.
Production and optimization of bamboo hydrochars for adsorption of Congo red and 2-naphthol.
Li, Yin; Meas, Arun; Shan, Shengdao; Yang, Ruiqin; Gai, Xikun
2016-05-01
Twelve hydrochars were produced from bamboo sawdust for adsorption of Congo red and 2-naphthol. The bamboo hydrochars have Brunauer-Emmett-Teller (BET) surface areas ranging from 2.63m(2)/g to 43.07m(2)/g, average pore diameters from 3.05nm to 3.83nm, pore volumes between 0.02cm(3)/g and 0.53cm(3)/g, and the surfaces of the hydrochars have diverse functional groups. The physico-chemical properties of the hydrochars critically depend on the hydrothermal conditions. All the hydrochars can adsorb Congo red and 2-naphthol from aqueous solutions, the largest adsorption capacity for Congo red is 33.7mg/g at the equilibrium concentration of 0.1mg/mL at 25°C, and the highest adsorption amount for 2-naphthol is 12.2mg/g at 25°C and 0.1mg/mL. Freundlich model can describe the adsorption isotherms of the both adsorbates slightly better than Langmuir model. These results provide a reference to the production and use of hydrochars as potential adsorbents in wastewater treatment. Copyright © 2016 Elsevier Ltd. All rights reserved.
ERIC Educational Resources Information Center
Dietrich, Katheryn; Greiser, Lee
The study explored sex disparities in economic remuneration for gainful employment among black, blue collar wage earners residing in selected nonmetropolitan and metropolitan areas of Texas. The bulk of the workers' families lived in or near poverty and were highly dependent on famale as well as male income. Preliminary analysis revealed that…
USDA-ARS?s Scientific Manuscript database
Here we reported a previously-undescribed coat color phenotype in Holstein cattle. Larson Blue Holsteins, located on a dairy in south Florida, exhibit a coloration pattern that is similar to that of black and white or red and white Holsteins except that, instead of being black or red, darker region...
Armstrong, D; Strogatz, D; Barnett, E; Wang, R
2003-01-01
Study objective: Occupational structure represents the unequal geographical distribution of more desirable jobs among communities (for example, white collar jobs). This study examines joint effects of social class, race, and county occupational structure on coronary mortality rates for men, ages 35–64 years, 1988–92, in upstate New York. Design: Upstate New York's 57 counties were classified into three occupational structure categories; counties with the lowest percentages of the labour force in managerial, professional, and technical occupations were classified in category I, counties with the highest percentages were in category III. Age adjusted coronary heart disease (CHD) mortality rates, 35–64 years, (from vital statistics and census data) were calculated for each occupational structure category. Main results: An inverse association between CHD mortality and occupational structure was observed among blue collar and white collar workers, among black men and white men, with the lowest CHD mortality observed among white collar, white men in category III (135/100 000). About two times higher mortality was observed among blue collar than white collar workers. Among blue collar workers, mortality was 1.3–1.8 times higher among black compared with white workers, and the highest rates were observed among black, blue collar workers (689/100 000). Also, high residential race segregation was shown in all areas. Conclusions: Results suggest the importance of community conditions in coronary health of local populations; however, differential impact on subpopulations was shown. Blue collar and black workers may especially lack economic and other resources to use available community services and/or may experience worse working and living conditions compared with white collar and white workers in the same communities. PMID:12700223
2016-01-01
Background Highlighted text in the Internet (i.e., hypertext) is predominantly blue and underlined. The perceptibility of these hypertext characteristics was heavily questioned by applied research and empirical tests resulted in inconclusive results. The ability to recognize blue text in foveal and parafoveal vision was identified as potentially constrained by the low number of foveally centered blue light sensitive retinal cells. The present study investigates if foveal and parafoveal perceptibility of blue hypertext is reduced in comparison to normal black text during reading. Methods A silent-sentence reading study with simultaneous eye movement recordings and the invisible boundary paradigm, which allows the investigation of foveal and parafoveal perceptibility, separately, was realized (comparing fixation times after degraded vs. un-degraded parafoveal previews). Target words in sentences were presented in either black or blue and either underlined or normal. Results No effect of color and underlining, but a preview benefit could be detected for first pass reading measures. Fixation time measures that included re-reading, e.g., total viewing times, showed, in addition to a preview effect, a reduced fixation time for not highlighted (black not underlined) in contrast to highlighted target words (either blue or underlined or both). Discussion The present pattern reflects no detectable perceptual disadvantage of hyperlink stimuli but increased attraction of attention resources, after first pass reading, through highlighting. Blue or underlined text allows readers to easily perceive hypertext and at the same time readers re-visited highlighted words longer. On the basis of the present evidence, blue hypertext can be safely recommended to web designers for future use. PMID:27688970
Black Musicians Leading the Way.
ERIC Educational Resources Information Center
Music Educators Journal, 1982
1982-01-01
Describes the careers and musical achievements of Blacks who were forerunners in jazz, blues, gospel, music, spirituals, band music, classical music, ragtime, and opera. The list was compiled to provide teachers with historical background information for "Black History Month." (AM)
Multifocal blue-on-yellow visual evoked potentials in early glaucoma.
Klistorner, Alexander; Graham, Stuart L; Martins, Alessandra; Grigg, John R; Arvind, Hemamalini; Kumar, Rajesh S; James, Andrew C; Billson, Francis A
2007-09-01
To determine the sensitivity and specificity of blue-on-yellow multifocal visual evoked potentials (mfVEPs) in early glaucoma. Cross-sectional study. Fifty patients with a confirmed diagnosis of early glaucoma and 60 normal participants. Black-and-white mfVEPs and blue-on-yellow mfVEPs were recorded using the Accumap version 2.0 (ObjectiVision Pty. Ltd., Sydney, Australia). All patients also underwent achromatic standard automated perimetry (SAP). Multifocal VEP amplitude and latency values in glaucoma patients were analyzed and compared with those of the normal controls. Based on the definition of visual field defect, in the group of glaucomatous eyes with SAP defects, amplitude of blue-on-yellow mfVEP was abnormal in all 64 cases (100% sensitivity), whereas black-and-white mfVEP missed 5 cases (92.2% sensitivity). Generally, larger scotomata were noted on blue-on-yellow mfVEP compared with black-and-white mfVEP for the same eyes. There was high topographic correspondence between SAP and amplitude of blue-on-yellow mfVEP and significant (P<0.0001) correlation between them (correlation coefficient, 0.73). Abnormal amplitude was detected in 3 of 60 eyes of control subjects (95% specificity). There was, however, no correlation between visual field defect and latency delay in glaucoma patients. Although there was a significant difference between averaged latency of control and glaucoma eyes, values considerably overlapped. The blue-on-yellow mfVEP is a sensitive and specific tool for detecting early glaucoma based on amplitude analysis.
25. Black and white photograph, 8 1/4" x 10" on ...
25. Black and white photograph, 8 1/4" x 10" on glossy paper. Night view of the ground floor, central display window showing an exhibit of gas ranges. On bottom right margin in blue ink, "10-8-58", on reverse in rubber stamp black ink, "Indiana Gas Company, Incorporated, 511-513 Honey Creek Drive, P.O. Box 1647, Terre Haute, Indiana 47808". Rubber stamp in blue ink, "Terre Haute Gas Corporation". Property of Indiana Gas Company, located in Terre Haute office. - John T. Beasley Building, 632 Cherry Street (between Sixth & Seventh Streets), Terre Haute, Vigo County, IN
Federal Register 2010, 2011, 2012, 2013, 2014
2011-08-10
... 1993, p. 134). Wings of males are blue above (dorsally), with a narrow black outer border and white... Krizek 1984, p. 112). Seasonal wing pattern variation may be caused by changes in humidity, temperature... the wings (Minno and Emmel 1994, p. 647). The Miami blue can be distinguished from the ceraunus blue...
Zhu, Nanwen; Gu, Lin; Yuan, Haiping; Lou, Ziyang; Wang, Liang; Zhang, Xin
2012-08-01
Degradation of naphthalene dye intermediate 1-diazo-2- naphthol-4-sulfonic acid (1,2,4-Acid) by Fenton process has been studied in depth for the purpose of learning more about the reactions involved in the oxidation of 1,2,4-Acid. During 1,2,4-Acid oxidation, the solution color initially takes on a dark red, then to dark black associated with the formation of quinodial-type structures, and then goes to dark brown and gradually disappears, indicating a fast degradation of azo group. The observed color changes of the solution are a result of main reaction intermediates, which can be an indicator of the level of oxidization reached. Nevertheless, complete TOC removal is not accomplished, in accordance with the presence of resistant carboxylic acids at the end of the reaction. The intermediates generated along the reaction time have been identified and quantified. UPLC-(ESI)-TOF-HRMS analysis allows the detection of 19 aromatic compounds of different size and complexity. Some of them share the same accurate mass but appear at different retention time, evidencing their different molecular structures. Heteroatom oxidation products like SO(4)(2-) have also been quantified and explanations of their release are proposed. Short-chain carboxylic acids are detected at long reaction time, as a previous step to complete the process of dye mineralization. Finally, considering all the findings of the present study and previous related works, the evolution from the original 1,2,4-Acid to the final products is proposed in a general reaction scheme. Copyright © 2012 Elsevier Ltd. All rights reserved.
Lakshmi, Chembolli; Krishnaswamy, Gayathri
2015-01-01
Q-switched neodymium: yttrium aluminum garnet (Nd: YAG) laser at a wavelength of 1064 nm primarily targets dermal melanin and black tattoo ink. Recent studies have shown that this laser is effective in treating black tattoos. There are few studies conducted in India for the same. The aim was to assess the effectiveness of Q-switched Nd: YAG laser (QSNYL) in the treatment of blue-black tattoos following 3 treatment sessions. This study, a prospective interventional study included a total of 12 blue-black tattoos. Following informed consent for the procedure, as well as for photographs, a questionnaire was administered, and improvement perceived by the patient was recorded. In addition, global assessment score (GAS) by a blinded physician was also recorded. Photographs were taken at baseline and at every follow-up. Each patient underwent three treatment sessions with 1064 nm QSNYL at 4-6 weekly intervals. Fluences ranged from 1.8 to 9 J/cm(2). The follow-up was done monthly for 4 months from the first treatment session. The response was assessed by patient assessment (PA) and GAS by comparing photographs. After three treatment sessions, although no patient achieved clearance, most patients showed good response with few adverse effects. An average of 64.1% (GAS) and 54.2% (PA) improvement was observed in 12 tattoos. Tattoos more than 10-year-old showed quicker clearing than those less than 10-year-old. Amateur tattoos also showed a better response in comparison to professional tattoos. Totally, 1064 nm QSNYL is safe and effective for lightening blue-black tattoos in pigmented Indian skin. All patients achieved near complete clearance following the continuation of treatment (an average of six sessions) although this was spaced at longer intervals.
Color vision in the giant panda (Ailuropoda melanoleuca).
Kelling, Angela S; Snyder, Rebecca J; Marr, M Jackson; Bloomsmith, Mollie A; Gardner, Wendy; Maple, Terry L
2006-05-01
Hue discrimination abilities of giant pandas were tested, controlling for brightness. Subjects were 2 adult giant pandas (1 male and 1 female). A simultaneous discrimination procedure without correction was used. In five tasks, white, black, and five saturations each of green, blue, and red served as positive stimuli that were paired with one or two comparison stimuli consisting of 16 saturations of gray. To demonstrate discrimination, the subjects were required to choose the positive stimulus in 16 of 20 trials (80% correct) for three consecutivesessions. Both subjects reached criterion forgreen and red. The female subject also reached criterion for blue. The male was not tested for blue. This study is a systematic replication of Bacon and Burghardt's (1976) color discrimination experiment on black bears. The results suggest that color vision in the giant panda is comparable to that of black bears and other carnivores that are not strictly nocturnal.
Urinary biomarkers of exposure to jet fuel (JP-8).
Serdar, Berrin; Egeghy, Peter P; Waidyanatha, Suramya; Gibson, Roger; Rappaport, Stephen M
2003-01-01
Benzene, naphthalene, and 1- and 2-naphthol were measured in urine samples obtained from 322 U.S. Air Force personnel categorized a priori as likely to have low, moderate, or high exposure to jet fuel [jet propulsion fuel-8 (JP-8)]. In postexposure samples, levels of these analytes in the high-exposure group were 3- to 29-fold greater than in the low-exposure group and 2- to 12-fold greater than in the moderate-exposure group. Heavy exposure to JP-8 contributed roughly the same amount of benzene and more than three times the amount of naphthalene compared with cigarette smoking. Strong correlations were observed among postexposure levels of naphthalene-based biomarkers in urine and naphthalene in air and breath. We conclude that urinary naphthalene and the naphthols can serve as biomarkers of exposure to jet fuel. Of these, the naphthols are probably more useful because of their greater abundance and slower elimination kinetics. PMID:14594628
... heart damage. Herbs that contain cardiac glycosides include black hellebore, Canadian hemp roots, digitalis leaf, hedge mustard, ... Other stimulant laxative herbs are aloe, alder buckthorn, black root, blue flag, butternut bark, colocynth, European buckthorn, ...
2007-10-25
NASA Spitzer and Chandra space telescopes have uncovered a long-lost population of active supermassive black holes, or quasars located deep in the bellies of distant, massive galaxies circled in blue.
2013-11-04
coated with enamel paint containing black, blue, red, and yellow pigment. The chemical compositions of the pigments are not known, but they show... enamel paint containing black pigment. VSFS signal intensities, ISFG,, has been normalized to constant incident laser power for each spectra. RDX...surface that has been coated with a 1 mm thick layer of enamel paint containing blue pigment. VSFS signal intensities, ISFG,, has been normalized to
Adaptive Associative Scale-Free Maps for Fusing Human and Robotic Intelligences
2006-06-01
negative documents are left out from the series . . . . . . . . 50 7.5 Sample runs Blue: Accuracy, red: Recall, black: the ratio of new docu- ments to all...The true negative documents are left out from the series . . . . . . . . 51 7.6 Sample runs Blue: Accuracy, red: Recall, black: the ratio of new docu...right corner. The true negative documents are left out from the series . . . . . . . . 52 7.7 Sample map 1 from topic ‘Language
Malo, Edi A; Cruz-Esteban, Samuel; González, Francisco J; Rojas, Julio C
2018-05-15
Fall armyworm (FAW), Spodoptera frugiperda (J. E. Smith), populations are monitored with a variety of commercial sex pheromone-baited traps. However, a number of trap-related variables may affect the number of FAW males captured. In this study, we tested the effect of trap design, trap size, and trap color for monitoring FAW males in corn crops in Mexico. We found that plastic jug trap (a home-made trap), captured significantly more FAW males than a commercial trap (Scentry Heliothis) and water bottle trap (another home-made trap). We also found that size of plastic jug traps (3.78, 10, or 20 liters) did not affect the captures of FAW males. Our results indicated that plastic yellow jug traps captured significantly more males than blue and black traps. Plastic jug white, red, and green traps captured a similar number of FAW males than plastic jug yellow, blue, and black traps. Plastic jug blue, white, and yellow traps captured more nontarget insects compared to black traps. The number of nontarget insects captured by green and red traps was similar and not significantly different to that caught by blue, white, yellow, and black traps. Traps captured more individuals from Diptera than Coleoptera and Hymenoptera. Overall, the results suggest that yellow plastic jug may be used for monitoring FAW males in corn and sorghum crops in Mexico.
Colour preferences of juvenile turbot (Scophthalmus maximus).
Li, Xian; Chi, Liang; Tian, Huiqin; Meng, Lingjie; Zheng, Jimeng; Gao, Xiaolong; Liu, Ying
2016-03-15
The background colour of aquaculture tanks is normally chosen based on practical experience and/or observations of fish behaviour and the growth rates achieved. However, some farmed species, including turbot, are sentient and can show a preference for a particular environment. In the current study, a self-referent colour preference device was developed and the self-referent colour preference of farmed fish investigated. In experiment 1, the background colour preference of juvenile turbot cultured under a grey background for >3months post-incubation was evaluated. Based on these results, in experiment 2, juvenile turbot were adapted to blue, pink, white, or black backgrounds for 50days and their preferences established. Meanwhile, the growth rates, feed intake, and metabolic rates (including oxygen consumption rate, and ammonia excretion rate) of the turbot were evaluated. The results showed that turbot farmed under a grey background, or after long-term white, blue, pink and black colour adaptation, always displayed a preference for a white background and a dislike for black, red, or brown backgrounds, although their body colour was greyish. Long-term adaptation influenced the frequency of juveniles selecting white, black, pink or blue backgrounds. They showed the highest growth rate, feed intake, and metabolic rates under blue and white backgrounds, and the lowest under a black background in accordance with their preferences shown in experiment 1. Although it is unclear how turbot determine their self-referent colour preferences over such a short period of time, these results indicate that dark colours are unsuitable for the aquaculture of turbot culture in terms of the welfare of the fish. Copyright © 2016 Elsevier Inc. All rights reserved.
Costa, D C; Mattioli, C C; Silva, W S; Takata, R; Leme, F O P; Oliveira, A L; Luz, R K
2017-03-01
The growth, physiology and skin pigmentation of pacamã Lophiosilurus alexandri juveniles were evaluated in an experiment using different tank colours (white, yellow, green, blue, brown and black) over an 80 day period. The tank colours did not cause significant differences to final body mass, total length, survival rate, carcass composition (moisture, crude protein, ash, ether extract, calcium, phosphorus, energy), or to plasma protein, triglyceride and cholesterol values. Haematocrit values, however, were highest for fish kept in white tanks (ANOVA P < 0·05), while the greatest haemoglobin levels were recorded for fish kept in blue and brown tanks (P < 0·01). The concentrations of cortisol (P < 0·001) and glucose (P < 0·01) were the most in fish in the black tanks. Tank colour affected skin pigmentation significantly, with fish in white tanks having the highest values of L* (brightness) and the lowest values in blue and black tanks. L*, however, decreased in all treatments throughout the experiment. C* ab increased significantly over the course of the experiment in fish kept in white tanks. Similar increases of C* ab were recorded in the other treatments but to a lesser extent. The use of black tanks during the cultivation of L. alexandri caused stress and should be avoided. Cultivation in white and yellow tanks produced individuals with a pale skin colour, while cultivation in blue and black tanks resulted in juveniles with a darker and more pigmented skin. © 2016 The Fisheries Society of the British Isles.
... at the center of the bite can become dark blue or purple and then evolve into a ... and brown recluse spiders prefer warm climates and dark, dry places. Black widow habitat Black widow spiders ...
2009-04-28
CAPE CANAVERAL, Fla. – A great blue heron stands tall in the water, perhaps looking for food, on grounds of NASA's Kennedy Space Center in Florida. More gray than blue, with a yellowish bill and black legs, it has a brownish-buff colored neck with a black border and white in front of its neck with a vertical black streak. The bird's head is white with a black stripe above its eye. They range throughout the U.S., inhabiting lakes, ponds, rivers and marshes. Their principal food is fish or frogs but may feed on small mammals, reptiles and occasionally birds. Kennedy shares a boundary with the Merritt Island National Wildlife Refuge, which is a habitat for more than 310 species of birds, 25 mammals, 117 fishes and 65 amphibians and reptiles. Photo credit: NASA/Ben Smegelsky
2009-04-28
CAPE CANAVERAL, Fla. – A great blue heron stands tall in the water, perhaps looking for food, on grounds of NASA's Kennedy Space Center in Florida. More gray than blue, with a yellowish bill and black legs, it has a brownish-buff colored neck with a black border and white in front of its neck with a vertical black streak. The bird's head is white with a black stripe above its eye. They range throughout the U.S., inhabiting lakes, ponds, rivers and marshes. Their principal food is fish or frogs but may feed on small mammals, reptiles and occasionally birds. Kennedy shares a boundary with the Merritt Island National Wildlife Refuge, which is a habitat for more than 310 species of birds, 25 mammals, 117 fishes and 65 amphibians and reptiles. Photo credit: NASA/Ben Smegelsky
Enzymes mediating resistance to lambda-cyhalothrin in Eriopis connexa (Coleoptera: Coccinellidae).
Rodrigues, Agna R S; Siqueira, Herbert A A; Torres, Jorge B
2014-03-01
Resistance to widely used insecticide, lambda-cyhalothrin, was recently reported in the predatory lady beetle Eriopis connexa (Germar) (Coleoptera: Coccinellidae). However, to understand whether metabolic mechanisms underlie such resistance, synergism bioassays and in vitro studies were carried out by using inhibitors and model substrates for enzymatic assays, respectively. The LD50s estimated for susceptible and resistant populations ηg of lambda-cyhalothrin/insect, and thus, a 22-fold difference in resistance ratio. Synergism ratios for the susceptible population with piperonyl butoxide (PBO), diethyl maleate (DEM), triphenyl phosphate (TPP), and S,S,S-tributylphosphorotrithioate (DEF) were respectively 33.8-, 0.24-, 0.35-, and 4.25-fold, while for the resistant population, they were 1463.0-, 0.79-, 0.85-, and 282.6-fold, respectively. The synergized resistance ratios were 0.50-, 2.00-, 6.75-, and 8.77-fold with PBO, DEF, DEM, and TPP, respectively, while resistance was virtually suppressed with DEF. The esterase exhibited 4.16-, 4.03-, and 5.38-fold greater activity towards formation of α-naphthol, β-naphthol, and 4-nitrophenol in the resistant population of E. connexa than in the susceptible population. The activity of esterase depended on concentrations of DEF applied, either using α-naphthol or β-naphthol, which completely inhibited the activity at 636 ηM. The PBO inhibited the β-naphthol formation in approximately 50%, suggesting it as inhibitor of esterases. The activities of glutathione-S-transferase were similar and corresponded to 0.36-0.47 ηmol(-1) min(-1)μg of protein, for S and R populations, respectively. Similarly, the activities of cytochrome P450-dependent microsomal monooxygenases were 0.04 and 0.05 ηmol(-1) min(-1)μg of protein. The native gel indicated that the formation of β-naphthol was completely inhibited by methyl-paraoxon, but only partially inhibited by eserine, TPP, and PBO. Although other studies with DEF and PBO have demonstrated strong inhibition of type B carboxylesterase associated with insecticide resistance, the results reported here do not rule out metabolism by cytochrome P450-dependent microsomal monooxygenases as a factor conferring E. connexa resistance to lambda-cyhalothrin and confirmed that PBO may also act by inhibiting esterases of insects. Copyright © 2014 Elsevier Inc. All rights reserved.
1981-10-01
S82-31408 (May 1983) --- The Spacelab 2 emblem is a symbolic representation of the scientific objectives of the mission. The emblem is in the shape of a triangular shield with convexly curved edges. Across the top of a black out border are the words ?SPACELAB 2?. Within the black border is a sky blue border carryhing the words: ?ASTRONOMY?, ON TOP? ?PHYSICS?, on the left; and ?BIOLOGY?, on the right. Within the blue border is a schematic view of the sun, the earth, and the orbiter with Spacelab 2. The sun appears in the upper right background as a white disc surrounded by six concentric rings ranging grom bright yellow near the disc through yellow-red to a dark red out ring. A sector of the earth with blue ocean and a black portion of North America is in the upper left corner. The black and white Orbiter is seen from directly overhead in the foreground, the right side illuminated by the sun, the left side in shadow. Although the payload bay doors are not open, the Spacelab 2 payload is seen as if the doors were open. In black on white are seen the three pallets, and the separately mounted cosmic ray experiment at the aft end of the bay.
Code of Federal Regulations, 2011 CFR
2011-10-01
... blue, all within an encircling inscription “National Transportation Safety Board.” When illustrated in... the eagle's beak. The arrows and the olive branch are a lighter shade of gold. The red and blue of the shield are national flag red and blue. The official seal of the Board, in black and white, appears below...
Code of Federal Regulations, 2013 CFR
2013-10-01
... blue, all within an encircling inscription “National Transportation Safety Board.” When illustrated in... the eagle's beak. The arrows and the olive branch are a lighter shade of gold. The red and blue of the shield are national flag red and blue. The official seal of the Board, in black and white, appears below...
Code of Federal Regulations, 2014 CFR
2014-10-01
... blue, all within an encircling inscription “National Transportation Safety Board.” When illustrated in... the eagle's beak. The arrows and the olive branch are a lighter shade of gold. The red and blue of the shield are national flag red and blue. The official seal of the Board, in black and white, appears below...
Code of Federal Regulations, 2012 CFR
2012-10-01
... blue, all within an encircling inscription “National Transportation Safety Board.” When illustrated in... the eagle's beak. The arrows and the olive branch are a lighter shade of gold. The red and blue of the shield are national flag red and blue. The official seal of the Board, in black and white, appears below...
Code of Federal Regulations, 2010 CFR
2010-10-01
... blue, all within an encircling inscription “National Transportation Safety Board.” When illustrated in... the eagle's beak. The arrows and the olive branch are a lighter shade of gold. The red and blue of the shield are national flag red and blue. The official seal of the Board, in black and white, appears below...
"Blue and seven phenomena" among Japanese students.
Saito, M
1999-10-01
To investigate color and number preferences in Japan, 586 university undergraduates (239 men and 347 women; M age = 20.9 yr.) were asked to name a color (Question 1), to name their preferred color (Question 2), and to name their preferred number between zero and nine (Question 3). The results showed that Japanese students chose blue (33.5%) or red (26.0%) when asked to name a color but that red was not chosen as frequently as blue as a preferred color (red: 11.1%, blue: 37.1%). Sex differences were found on both Questions 1 and 2 by chi-squared test. Black was chosen more by men, while pink was selected more by women. 22.5% subjects also selected the number seven, supporting Simon's observation of the "blue-seven phenomenon." The reasons given for the choice showed that seven was "a lucky number" and "represented happiness" among Japanese students. Four colors (blue, red, white, and black) accounted for 76.8% and 65.1% of responses to Questions 1 and 2, respectively, and odd numbers 68.4% for Question 3.
Pathos in Criticism: Edwin Black's Communism-as-Cancer Metaphor
ERIC Educational Resources Information Center
Condit, Celeste M.
2013-01-01
Edwin Black's essay on "The Second Persona," introduced to rhetorical critics a rationale and model for a type of ideological criticism. Because it ignored the role of pathos in both the rhetoric Black purported to critique and in the construction of his own audience, Black's essay mis-described key features of Robert Welch's "Blue Book", which…
New Research Center in Chicago Strives to Preserve and Promote the Legacy of Black Music.
ERIC Educational Resources Information Center
Paul, Angus
1987-01-01
Facilitating, stimulating, and disseminating scholarship on blues, gospel, Creole, jazz, and other kinds of black music are the goals of the Center for Black Music Research at Columbia College in Chicago. The paucity of black scholars, developing a "union catalog," and the need for reference books are discussed. (MLW)
Study of enhanced photogalvanic effect of Naphthol Green B in natural sunlight
NASA Astrophysics Data System (ADS)
Koli, Pooran
2015-07-01
The photogalvanic cells based on Naphthol Green B sensitizer-Fructose reductant-Sodium Lauryl Sulphate surfactant has been studied in natural sunlight. The cell has been found workable in natural sunlight with greatly enhanced optimum cell performance. The 1159.2 μW power, 4500 μA short-circuit current, 1070 mV open-circuit potential, 14.49% efficiency and 240 min storage capacity (as half change time) has been observed in optimum cell fabrication conditions.
Das, Vijay K; Borah, Madhurjya; Thakur, Ashim J
2013-04-05
Nano-S prepared by an annealing process showed excellent catalytic activity for the synthesis of 1-amidoalkyl-2-naphthols under solvent-free reaction condition at 50 °C. The catalyst could be reused up to the fifth cycle without loss in its action. The green-ness of the present protocol was also measured using green metrics drawing its superiority.
Seiler, Melanie; Schwitzer, Christoph; Gamba, Marco; Holderied, Marc W.
2013-01-01
As alarm calls indicate the presence of predators, the correct interpretation of alarm calls, including those of other species, is essential for predator avoidance. Conversely, communication calls of other species might indicate the perceived absence of a predator and hence allow a reduction in vigilance. This “eavesdropping” was demonstrated in birds and mammals, including lemur species. Interspecific communication between taxonomic groups has so far been reported in some reptiles and mammals, including three primate species. So far, neither semantic nor interspecific communication has been tested in a solitary and nocturnal lemur species. The aim of this study was to investigate if the nocturnal and solitary Sahamalaza sportive lemur, Lepilemur sahamalazensis, is able to access semantic information of sympatric species. During the day, this species faces the risk of falling prey to aerial and terrestrial predators and therefore shows high levels of vigilance. We presented alarm calls of the crested coua, the Madagascar magpie-robin and aerial, terrestrial and agitation alarm calls of the blue-eyed black lemur to 19 individual Sahamalaza sportive lemurs resting in tree holes. Songs of both bird species’ and contact calls of the blue-eyed black lemur were used as a control. After alarm calls of crested coua, Madagascar magpie-robin and aerial alarm of the blue-eyed black lemur, the lemurs scanned up and their vigilance increased significantly. After presentation of terrestrial alarm and agitation calls of the blue-eyed black lemur, the animals did not show significant changes in scanning direction or in the duration of vigilance. Sportive lemur vigilance decreased after playbacks of songs of the bird species and contact calls of blue-eyed black lemurs. Our results indicate that the Sahamalaza sportive lemur is capable of using information on predator presence as well as predator type of different sympatric species, using their referential signals to detect predators early, and that the lemurs’ reactions are based on experience and learning. PMID:23825658
Adegbalola, Gaye
2011-01-01
In this interview, blues lyricist and musician Gaye Adegbalola shares with audiences how various political, social, and artistic influences have inspired her work since her activist years during the Black Arts Movement leading up to the present day. As a lesbian blues artist, Adegbalola's personal and artistic development implicates the often inextricable and intimate relationships between artistic production, political involvement, and individual fulfillment.
Melanoma is the most serious type of skin cancer. Often the first sign of melanoma is a change in the size, shape, color, or feel of a mole. Most melanomas have a black or black-blue area. Melanoma ...
Phytoplankton bloom in the Black Sea
NASA Technical Reports Server (NTRS)
2002-01-01
Brightly colored waters in the Black Sea give evidence of the growth of tiny marine plants called phytoplankton, which contain chlorophyll and other pigments that reflect light different ways, producing the colorful displays. The very bright blue waters could be an organism called a coccolithophores, which has a highly reflective calcium carbonate coating that appears bright blue (or sometimes white) in true-color (visible) imagery. However, other organisms, such as cyanobacteria can also appear that color, and so often scientists will compare the ratios of reflectance at one wavelength of light to another to decide what organisms might be present. This series of images shows a bloom occurring in the Black Sea from May 11, 2002, to May 18.
Relationship between Color and Emotion: A Study of College Students
ERIC Educational Resources Information Center
Kaya, Naz; Epps, Helen H.
2004-01-01
Ninety-eight college students were asked to indicate their emotional responses to five principle hues (i.e., red, yellow, green, blue, purple), five intermediate hues (i.e., yellow-red, green-yellow, blue-green, purple-blue, and red-purple), and three achromatic colors (white, gray, and black) and the reasons for their choices. The color stimuli…
50 CFR Table 2d to Part 679 - Species Codes-Non-FMP Species
Code of Federal Regulations, 2012 CFR
2012-10-01
... Prowfish 215 Ratfish 714 Rockfish, black (GOA) 142 Rockfish, blue (GOA) 167 Rockfish, dark 173 Sardine... 830 Washington butter 810 Coral 899 Mussel, blue 855 Oyster, Pacific 880 Scallop, weathervane 850...
50 CFR Table 2d to Part 679 - Species Codes-Non-FMP Species
Code of Federal Regulations, 2013 CFR
2013-10-01
... Prowfish 215 Ratfish 714 Rockfish, black (GOA) 142 Rockfish, blue (GOA) 167 Rockfish, dark 173 Sardine... 830 Washington butter 810 Coral 899 Mussel, blue 855 Oyster, Pacific 880 Scallop, weathervane 850...
Red, White, and the Blues Part 3 of 4: The New Beat of the Blues: R&B
ERIC Educational Resources Information Center
Cassinos-Carr, Cathy
2004-01-01
When rhythm & blues--or, as it is more commonly called, R&B, was first born, it did not even have a name. Prior to 1949, all black popular music, including jazz, blues, and gospel, was known as "race music." But by the end of the 1940s, the music had become so successful that it gained a new-found respect--and Billboard magazine, realizing that…
Mizutani, Hitoshi; Akeda, Tomoko; Yamanaka, Kei-Ichi; Isoda, Kenichi; Gabazza, Esteban C
2012-02-01
Tzanck test has been recently re-evaluated as a method for the diagnosis of herpes virus infection. Giemsa staining for the Tzanck test is time-consuming and laborious. There is a need to develop simple and quick staining methods for bedside diagnosis of this disease. We report a single step and quick method for staining herpes giant cells in Tzanck smears using routinely available inks and physiological saline. A keratinocyte cell line (HaCaT) was cultured on a slide glass and stained with various commercially available blue, blue-black and black inks serially diluted with physiological saline. Clinical smear samples from herpes lesions were also stained with these solutions without specific pretreatment. The nuclei of HaCaT were clearly stained showing high contrast with the cytoplasm using 5% Parker-Quink blue-black ink saline solution. Concentration of ink solution higher or lower than 5% resulted in less contrast. Blue or black inks or other manufacturers' inks can also be used, but staining of the cultured keratinocytes was less clear. Smear of clinical samples from herpes lesions were also stained with 5% ink solution. The nuclei of the multinucleated giant cells were clearly stained, and the sample could be immediately used for microscopic examination. One step staining of Tzanck smear using this diluted ink solution is an inexpensive and a convenient bedside diagnostic tool for the dermatologist. © 2011 Japanese Dermatological Association.
Lakshmi, Chembolli; Krishnaswamy, Gayathri
2015-01-01
Background: Q-switched neodymium: yttrium aluminum garnet (Nd: YAG) laser at a wavelength of 1064 nm primarily targets dermal melanin and black tattoo ink. Recent studies have shown that this laser is effective in treating black tattoos. There are few studies conducted in India for the same. Aim: The aim was to assess the effectiveness of Q-switched Nd: YAG laser (QSNYL) in the treatment of blue-black tattoos following 3 treatment sessions. Materials and Methods: This study, a prospective interventional study included a total of 12 blue-black tattoos. Following informed consent for the procedure, as well as for photographs, a questionnaire was administered, and improvement perceived by the patient was recorded. In addition, global assessment score (GAS) by a blinded physician was also recorded. Photographs were taken at baseline and at every follow-up. Each patient underwent three treatment sessions with 1064 nm QSNYL at 4–6 weekly intervals. Fluences ranged from 1.8 to 9 J/cm2. The follow-up was done monthly for 4 months from the first treatment session. The response was assessed by patient assessment (PA) and GAS by comparing photographs. Results: After three treatment sessions, although no patient achieved clearance, most patients showed good response with few adverse effects. An average of 64.1% (GAS) and 54.2% (PA) improvement was observed in 12 tattoos. Tattoos more than 10-year-old showed quicker clearing than those less than 10-year-old. Amateur tattoos also showed a better response in comparison to professional tattoos. Conclusion: Totally, 1064 nm QSNYL is safe and effective for lightening blue-black tattoos in pigmented Indian skin. All patients achieved near complete clearance following the continuation of treatment (an average of six sessions) although this was spaced at longer intervals. PMID:26677271
Enhanced degradation of 1-naphthol in landfill leachate using Arthrobacter sp.
Hu, Wenyong; Min, Xiaobo; Li, Xinyu; Liu, Jingyi; Yu, Haibin; Yang, Yuan; Zhang, Jiachao; Luo, Lin; Chai, Liyuan; Zhou, Yaoyu
2017-12-06
Arthrobacter sp. named as JY5-1 isolated from contaminated soil of a coking plant can degrade 1-naphthol as the sole carbon source. Through identification of species, analysis of the optimal degradation condition and kinetic equation, the degradation characteristic of Arthrobacter sp. JY5-1 was obtained. Later, the acclimated strain was added into the bio-reactor to observe treatment performance of landfill leachate. The results showed that the optimal conditions for strain JY5-1 biodegradation in the study were pH 7.0 and 30 o C. The bio-reactor operation experiment declared that Arthrobacter sp. JY5-1 had a strengthened effect on COD removal of landfill leachate. Moreover, the efficiency of COD removal could be high and stable when JY5-1 was accumulated as a biofilm together with active sludge. These results demonstrate that adding 1-naphthol-degrading strain JY5-1 is a feasible technique for the enhanced treatment of sanitary landfill leachate, providing theoretical support for engineering utilization.
Esterase reactions in acute myelomonocytic leukemia.
Kass, L
1977-05-01
Specific and nonspecific esterase reactions of bone marrow cells from 14 patients with untreated acute myelomonocytic leukemia and six patients with acute histiomonocytic leukemia were examined. The technic for esterase determination permitted simultaneous visualization of both esterases on the same glass coverslip containing the marrow cells. In cases of acute histiomonocytic leukemia, monocytes, monocytoid hemohistioblasts and undifferentiated blasts stained intensely positive for nonspecific esterase, using alpha-naphthyl acetate as the substrate. No evidence of specific esterase activity using naphthol ASD-chloroacetate as the substrate and fast blue BBN as the dye coupler was apparent in these cells. In all of the cases of acute myelomonocytic leukemia, both specific and nonspecific esterases were visualized within monocytes, monocytoid cells, and granulocytic cells that had monocytoid-type nuclei. Nonspecific esterase activity was not observed in polymorphonuclear leukocytes in cases of myelomonocytic leukemia. The results support a current viewpoint that acute myelomonocytic leukemia may be a variant of acute myeloblastic leukemia, and that cytochemically, many of the leukemic cells in myelomonocytic leukemia share properties of both granulocytes and monocytes.
The Convergent Evolution of Blue Iris Pigmentation in Primates Took Distinct Molecular Paths
Meyer, Wynn K; Zhang, Sidi; Hayakawa, Sachiko; Imai, Hiroo; Przeworski, Molly
2013-01-01
How many distinct molecular paths lead to the same phenotype? One approach to this question has been to examine the genetic basis of convergent traits, which likely evolved repeatedly under a shared selective pressure. We investigated the convergent phenotype of blue iris pigmentation, which has arisen independently in four primate lineages: humans, blue-eyed black lemurs, Japanese macaques, and spider monkeys. Characterizing the phenotype across these species, we found that the variation within the blue-eyed subsets of each species occupies strongly overlapping regions of CIE L*a*b* color space. Yet whereas Japanese macaques and humans display continuous variation, the phenotypes of blue-eyed black lemurs and their sister species (whose irises are brown) occupy more clustered subspaces. Variation in an enhancer of OCA2 is primarily responsible for the phenotypic difference between humans with blue and brown irises. In the orthologous region, we found no variant that distinguishes the two lemur species or associates with quantitative phenotypic variation in Japanese macaques. Given the high similarity between the blue iris phenotypes in these species and that in humans, this finding implies that evolution has used different molecular paths to reach the same end. Am J Phys Anthropol 151:398–407, 2013.© 2013 Wiley Periodicals, Inc. PMID:23640739
Federal Register 2010, 2011, 2012, 2013, 2014
2012-04-06
.... 134). Wings of males are blue above (dorsally), with a narrow black outer border and white fringes... Krizek 1984, p. 112). Seasonal wing pattern variation may be caused by changes in humidity, temperature... on the undersides of the wings (Minno and Emmel 1994, p. 647). The Miami blue can be distinguished...
ERIC Educational Resources Information Center
Hughes, S. W.
2009-01-01
What colour is a shadow? Black, grey, or some other colour? This article describes how to use a digital camera to test the hypothesis that a shadow under a clear blue sky has a blue tint. A white sheet of A4 paper was photographed in full sunlight and in shadow under a clear blue sky. The images were analysed using a shareware program called…
Dikmen, S; Dahl, G E; Cole, J B; Null, D J; Hansen, P J
2017-03-01
Here we report a previously undescribed coat color phenotype in Holstein cattle. Larson Blue Holsteins, located on a dairy in south Florida, exhibit a coloration pattern that is similar to that of black and white or red and white Holsteins except that, instead of being black or red, darker regions of the body vary in color from gray to taupe. The Larson Blue phenotype was readily apparent in young calves. The phenotype is not due to inheritance of known mutations causing coat color variation in cattle, including dominant red, Telstar, silver color dilutor, or Dun color. Three variants with moderate effects on the () gene were identified in 2 Larson blue cows. Despite being lighter in color, there was no difference in daily variation in vaginal temperature between Larson Blue and other Holsteins when recorded during the summer for cows housed in free-stall barns with shade, fans, and sprinklers. Similarly, there was no effect of the Larson Blue phenotype on seasonal variation in milk yield. Therefore, the phenotype confers no advantage in terms of response to heat stress when cattle are housed in facilities with extensive cooling.
NASA Astrophysics Data System (ADS)
Tavana, Jalal; Edrisi, Mohammad
2016-03-01
In this study, cobalt ferrite (CoFe2O4) nanoparticles were synthesized by two novel methods. The first method is based on the thermolysis of metal-NN complexes. In the second method, a template free sonochemical treatment of mixed cobalt and iron chelates of α-nitroso-β-naphthol (NN) was applied. Products prepared through method 1 were spherical, with high specific surface area (54.39 m2 g-1) and small average crystalline size of 13 nm. However, CoFe2O4 nanoparticles prepared by method 2 were in random shapes, a broad range of crystalline sizes and a low specific surface area of 25.46 m2 g-1 though highly pure. A Taguchi experimental design was implemented in method 1 to determine and obtain the optimum catalyst. The structural and morphological properties of products were investigated by x-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, Fourier transform infrared, Brunauer-Emmett-Teller and dynamic laser light scattering. The crystalline size calculations were performed using Williamson-Hall method on XRD spectrum. The photocatalytic activity of the optimum nanocrystalline cobalt ferrite was investigated for degradation of a representative pollutant, methylene blue (MB), and visible light as energy source. The results showed that some 92% degradation of MB could be achieved for 7 h of visible light irradiation.
Exotic Physics and Chemistry of Two-Dimensional Phosphorus: Phosphorene.
Chowdhury, Chandra; Datta, Ayan
2017-07-06
Phosphorene, the monolayer form of black phosphorus, is the most recent addition to graphene-like van der Waals two-dimensional (2D) systems. Due to its several interesting properties, namely its tunable direct band gap, high carrier mobility, and unique in-plane anisotropy, it has emerged as a promising candidate for electronic and optoelectronic devices. Phosphorene (Pn) reveals a much richer phase diagram than graphene, and it comprises the two forms namely the stapler-clip like (black Pn, α form) and chairlike (blue Pn, β form) structures. Regardless of its favorable properties, black Pn suffers from instability in oxygen and water, which limits its successful applications in electronic devices. In this Perspective, the cause of structural diversity of Pn, which leads to different properties of both black and blue Pn, is discussed. We provide possible solutions for protecting phosphorene from chemical degradation and its applications in the field of energy storage namely for Li and Na ion batteries.
Durability of switchable QR code carriers under hydrolytic and photolytic conditions
NASA Astrophysics Data System (ADS)
Ecker, Melanie; Pretsch, Thorsten
2013-09-01
Following a guest diffusion approach, the surface of a shape memory poly(ester urethane) (PEU) was either black or blue colored. Bowtie-shaped quick response (QR) code carriers were then obtained from laser engraving and cutting, before thermo-mechanical functionalization (programming) was applied to stabilize the PEU in a thermo-responsive (switchable) state. The stability of the dye within the polymer surface and long-term functionality of the polymer were investigated against UVA and hydrolytic ageing. Spectrophotometric investigations verified UVA ageing-related color shifts from black to yellow-brownish and blue to petrol-greenish whereas hydrolytically aged samples changed from black to greenish and blue to light blue. In the case of UVA ageing, color changes were accompanied by dye decolorization, whereas hydrolytic ageing led to contrast declines due to dye diffusion. The Michelson contrast could be identified as an effective tool to follow ageing-related contrast changes between surface-dyed and laser-ablated (undyed) polymer regions. As soon as the Michelson contrast fell below a crucial value of 0.1 due to ageing, the QR code was no longer decipherable with a scanning device. Remarkably, the PEU information carrier base material could even then be adequately fixed and recovered. Hence, the surface contrast turned out to be the decisive parameter for QR code carrier applicability.
Serrano-Rojas, Shirley J; Whitworth, Andrew; Villacampa, Jaime; May, Rudolf VON; Gutiérrez, Roberto C; Padial, José M; Chaparro, Juan C
2017-01-16
We describe and name a new species of poison-dart frog from the Amazonian slopes of the Andes in Manu Province, Madre de Dios Department, Peru; specifically within the Amarakaeri Communal Reserve and the buffer zone of Manu National Park. Ameerega shihuemoy sp. nov. is supported by a unique combination of characters: black dorsum with cream to light orange dorsolateral lines, blue belly reticulated with black, and the lack of axillary, thigh and calf flash marks. Within Ameerega, it shares the general appearance of A. altamazonica, A. boliviana, A. hahneli, A. ignipedis, A. petersi, A. picta, A. pongoensis, A. pulchripecta, A. simulans, A. smaragdina, and A. yungicola; each possessing a granular black to brown dorsum, a light labial bar, a conspicuous dorsolateral line running from the snout to the groin, and a metallic blue belly and underside of arms and hind limbs. From most of these species it can be distinguished by lacking flash marks on the axillae, thighs, and calves (absent in only A. boliviana and A. smaragdina, most A. petersi, and some A. pongoensis), by having bright cream to orange dorsolateral stripes (white, intense yellow, or green in all other species, with the exception of A. picta), and by its blue belly reticulated with black (bluish white and black in A. boliviana, green and blue with black marbling in A. petersi, and green and blue lacking black marbling in A. smaragdina). Its mating call also shows clear differences to morphologically similar species, with a lower note repetition rate, longer space between calls, and higher fundamental and dominant frequencies. Phylogenetic analyses based on the 16S mitochondrial rRNA fragment also support the distinctiveness of the new species and suggest that A. shihuemoy is most closely related to Ameerega macero, A. altamazonica, A. rubriventris, and two undescribed species (Ameerega sp. from Porto Walter, Acre, Brazil, and Ameerega sp. from Ivochote, Cusco, Peru). Genetically, the new species is most similar to the sympatric A. macero, from which it clearly differs in characteristics of its advertisement call and coloration. The new species is found near rocky streams during the dry season and near temporary water bodies during the rainy season. Tadpoles are found in lentic water along streams, or in shallow, slow-moving streams. Given its small geographic range, we recommend that A. shihuemoy should be considered 'Near threatened' (NT) according to IUCN Red List criteria.
Promising thermoelectric properties of phosphorenes.
Sevik, Cem; Sevinçli, Hâldun
2016-09-02
Electronic, phononic, and thermoelectric transport properties of single layer black- and blue-phosphorene structures are investigated with first-principles based ballistic electron and phonon transport calculations employing hybrid functionals. The maximum values of room temperature thermoelectric figure of merit, ZT corresponding to armchair and zigzag directions of black-phosphorene, ∼0.5 and ∼0.25, are calculated as rather smaller than those obtained with first-principles based semiclassical Boltzmann transport theory calculations. On the other hand, the maximum value of room temperature ZT of blue-phosphorene is predicted to be substantially high and remarkable values as high as 2.5 are obtained for elevated temperatures. Besides the fact that these figures are obtained at the ballistic limit, our findings mark the strong possibility of high thermoelectric performance of blue-phosphorene in new generation thermoelectric applications.
Fast luminous blue transients from newborn black holes
NASA Astrophysics Data System (ADS)
Kashiyama, Kazumi; Quataert, Eliot
2015-08-01
Newborn black holes in collapsing massive stars can be accompanied by a fallback disc. The accretion rate is typically super-Eddington and strong disc outflows are expected. Such outflows could be directly observed in some failed explosions of compact (blue supergiants or Wolf-Rayet stars) progenitors, and may be more common than long-duration gamma-ray bursts. Using an analytical model, we show that the fallback disc outflows produce blue UV-optical transients with a peak bolometric luminosity of ˜ 1042-43 erg s- 1 (peak R-band absolute AB magnitudes of -16 to -18) and an emission duration of ˜ a few to ˜10 d. The spectra are likely dominated intermediate mass elements, but will lack much radioactive nuclei and iron-group elements. The above properties are broadly consistent with some of the rapid blue transients detected by Panoramic Survey Telescope & Rapid Response System and Palomar Transient Factory. This scenario can be distinguished from alternative models using radio observations within a few years after the optical peak.
Fruit color preference by birds and applications to ecological restoration.
Gagetti, B L; Piratelli, A J; Piña-Rodrigues, F C M
2016-01-01
Ecological restoration aims to retrieve not only the structure but also the functionality of ecosystems. Frugivorous birds may play an important role in this process due to their efficiency in seed dispersal. Color perception in these animals is highly developed, and then the colors of fleshy fruits may provide important clues for choosing plant species for restoration plans. This study aims to integrate bird color preferences and restoration of degraded areas, with an objective to evaluate the potential attractiveness to birds by colored fruits. We carried out an experiment with 384 artificial fruits made of edible modeling clay with the following colors: black, blue, green and red, with 96 fruits of each color in six sites, including four restored areas and two second-growth forest fragments. We also tested the possible effect of light intensity on fruit consumption by color. A total of 120 (38.6%) were assumed to be consumed by birds, and the fruit consumption varied in response to the location and light incidence. Consumption of black and blue fruits was not related to site by chance. Notwithstanding, red and black fruits were consumed significantly more than any other colors, emphasizing bird preference to these colors, regardless of location. Enrichment with shade tolerant shrubs or forest species with black or red fruits may be an alternative way to manage established restorations. In recently established or new restorations, one may introduce pioneer shrubs or short-lived forest species which have blue fruits, but also those having black or red ones.
Narayanan, Divya P; Cherikallinmel, Sudha Kochiyil; Sankaran, Sugunan; Narayanan, Binitha N
2018-06-15
A one pot synthesis of carbon dot incorporated porous coconut shell char derived sulphonated catalyst is reported here for the first time and is effectively used in the multicomponent synthesis of amidoalkyl naphthol. Macroporous nature of the char is revealed from scanning electron microscopic (SEM) analysis, whereas the dispersion of carbon dots (CDs) on the porous coconut shell char is confirmed from the high resolution transmission electron microscopic (HRTEM) analysis. Fluorescence emission spectrum further confirmed the presence of CDs in the catalyst. Fourier-transform infrared (FTIR) spectral analysis of the materials indicated that sulphonation occurred both to the CD and to the porous char. X-ray photo electron spectroscopic (XPS) analysis of the most active catalyst confirmed the presence of both sulphonic acid and carboxylic acid groups in the catalyst. The coconut shell char derived materials prepared by varying the amount of H 2 SO 4 are successfully utilized as efficient alternative green catalysts for the multicomponent reaction, where excellent activity in amidoalkyl naphthol synthesis is obtained within short periods under solvent free reaction conditions. A maximum yield of 98% is obtained in the synthesis of N-[Phenyl-(2-hydroxy-naphthalen-1-yl)-methyl]-benzamide, the representative amidoalkyl naphthol, with the best catalyst within 3 min of reaction. The catalyst is highly active for the reactions carried out with varieties of aldehydes and amides with a product yield in the range of 88-98%. The best catalyst system retained more than 90% of its initial activity even upto 6 th repeated run. Copyright © 2018 Elsevier Inc. All rights reserved.
Fleming, Aaron M; Kannan, Arunkumar; Muller, James G; Liao, Yi; Burrows, Cynthia J
2011-10-07
Exposure of cells to phenolic compounds through exogenous and endogenous sources can lead to deleterious effects via nucleobase modifications of DNA occurring under oxidative conditions. 2'-Deoxyguanosine (dG) is the most electron rich of the four canonical bases and includes many nucleophilic sites; it is also susceptible to oxidation with numerous reactive oxygen species. In these studies, dG was allowed to react with 2-naphthol in the presence of copper or iron salts yielding two principal isomeric products. Spectroscopic analysis and reactions with alkylated nucleosides support the assignment of compound 1a/1b as a pair of atropisomer N(2) adducts and compound 2a/2b as a diastereomeric mixture of tricyclic [4.3.3.0] adducts. Both products are the result of an overall four-electron oxidation process and consequently have the same masses, though drastically different structures, providing mechanistic insight into their formation. Thus, dG alkylation by 2-naphthol under oxidative conditions yields products whose structural properties are altered, leading to potentially mutagenic effects in genomic DNA.
Emasculation Blues: Black Male Teachers' Perspectives on Gender and Power in the Teaching Profession
ERIC Educational Resources Information Center
Brockenbrough, Ed
2012-01-01
Background/Context: Over the past decade, a growing chorus of educational stakeholders has called for the recruitment of more Black men into the American teaching profession, casting these men as ideal surrogate father figures for Black youth who may lack adult male role models in their families or communities. Although a small body of scholarly…
Hall, Alison V; Hall, Erika V; Perry, Jamie L
2016-04-01
In late 2014, a series of highly publicized police killings of unarmed Black male civilians in the United States prompted large-scale social turmoil. In the current review, we dissect the psychological antecedents of these killings and explain how the nature of police work may attract officers with distinct characteristics that may make them especially well-primed for negative interactions with Black male civilians. We use media reports to contextualize the precipitating events of the social unrest as we ground our explanations in theory and empirical research from social psychology and industrial and organizational (I/O) psychology. To isolate some of the key mechanisms at play, we disentangle racial bias (e.g., stereotyping processes) from common characteristics of law enforcement agents (e.g., social dominance orientation), while also addressing the interaction between racial bias and policing. By separating the moving parts of the phenomenon, we provide a more fine-grained analysis of the factors that may have contributed to the killings. In doing so, we endeavor to more effectively identify and develop solutions to eradicate excessive use of force during interactions between "Black" (unarmed Black male civilians) and "Blue" (law enforcement). (c) 2016 APA, all rights reserved).
Bird fruit preferences match the frequency of fruit colours in tropical Asia
Duan, Qiong; Goodale, Eben; Quan, Rui-chang
2014-01-01
While many factors explain the colour of fleshy fruits, it is thought that black and red fruits are common in part because frugivorous birds prefer these colours. We examined this still controversial hypothesis at a tropical Asian field site, using artificial fruits, fresh fruits, four wild-caught resident frugivorous bird species, and hand-raised naïve birds from three of the same species. We demonstrate that all birds favored red artificial fruits more than yellow, blue, black and green, although the artificial black colour was found subsequently to be similar to the artificial blue colour in its spectral reflectance. Wild-caught birds preferred both black and red fleshy natural fruits, whereas hand-raised naïve birds preferred black to red natural fleshy fruits and to those of other colours. All birds avoided artificial and naturally ripe green fruits. The inter-individual variation in colour choice was low and the preferences were constant over time, supporting the hypothesis that bird colour preferences are a contributing factor driving fruit colour evolution in tropical Asia. PMID:25033283
Kriska, György; Csabai, Zoltán; Boda, Pál; Malik, Péter; Horváth, Gábor
2006-01-01
We reveal here the visual ecological reasons for the phenomenon that aquatic insects often land on red, black and dark-coloured cars. Monitoring the numbers of aquatic beetles and bugs attracted to shiny black, white, red and yellow horizontal plastic sheets, we found that red and black reflectors are equally highly attractive to water insects, while yellow and white reflectors are unattractive. The reflection–polarization patterns of black, white, red and yellow cars were measured in the red, green and blue parts of the spectrum. In the blue and green, the degree of linear polarization p of light reflected from red and black cars is high and the direction of polarization of light reflected from red and black car roofs, bonnets and boots is nearly horizontal. Thus, the horizontal surfaces of red and black cars are highly attractive to red-blind polarotactic water insects. The p of light reflected from the horizontal surfaces of yellow and white cars is low and its direction of polarization is usually not horizontal. Consequently, yellow and white cars are unattractive to polarotactic water insects. The visual deception of aquatic insects by cars can be explained solely by the reflection–polarizational characteristics of the car paintwork. PMID:16769639
Sroykham, Watchara; Wongsathikun, J; Wongsawat, Y
2014-01-01
Light and color have been shown to have substantial physical, psychological and sociological effects on humans. Hence, an investigation on the effect of changes in light and color to the biological signals is a challenging problem. Five participants were measured the oxygen saturation (SpO2), pulse rate, and quantitative electroencephalogram (QEEG) in six colors (white, blue, green, yellow, red and black) of living environment for 5 minutes per color. Then all participants were asked to answer the emotional questionnaire of BRUMS and color performance for each color environment. The results showed brain activity of high beta wave (25-30 Hz) that associated with alertness, agitation, mental activity, and general activation of mind and body functions (at frontal lobes and temporal lobes) in red and yellow colored rooms were higher than blue, green, white and black colored rooms, respectively. It also had the relationship with the psychological effect (BRUMS). The amplitude asymmetry of beta wave (12-25 Hz) was highly attenuated in warm color (red and yellow colored rooms), moderately attenuated in cool color (green and blue colored room) and little attenuated in white and black colored rooms. The BRUMS showed that red and yellow yielded significant effect on anger (F = 4.966, p = 0.002) and confusion (F=3.853, p=0.008). Red and green color yielded high effect on vigor. Green color did not affect the depression. Blue color yielded moderate effect on confusion, tension and fatigue. White and black colors yielded low effect on any mood, but black color had no effect on vigor. In addition, we cannot observe any significant changes of pulse rate and blood oxygen saturation in each color. The results can possibly be used as the recommendation to design the room for either normal people or patients.
Synthesis of Novel Compounds as New Potent Tyrosinase Inhibitors
Hamidian, Hooshang
2013-01-01
In the present paper, we report the synthesis and pharmacological evaluation of a new series of azo compounds with different groups (1-naphthol, 2-naphthol, and N,N-dimethylaniline) and trifluoromethoxy and fluoro substituents in the scaffold. All synthesized compounds (5a–5f) showed the most potent mushroom tyrosinase inhibition (IC50 values in the range of 4.39 ± 0.76–1.71 ± 0.49 µM), comparable to the kojic acid, as reference standard inhibitor. All the novel compounds were characterized by FT-IR, 1H NMR, 13C NMR, and elemental analysis. PMID:24260737
Understanding and Developing Black Popular Music Collections.
ERIC Educational Resources Information Center
Murray, James Briggs
1983-01-01
Enumerates types of black popular music (work songs, spirituals, gospel music, blues, race records, rock and roll, soul, funk, disco, Caribbean, and African) and discusses collection development (current, retrospective, monographs, periodicals, sheet music, motion picture film, photographs, oral history), cataloging, and preservation. A 229-item…
Management of Civil Engineering Support Equipment
2003-09-01
The standard Navy plates have blue lettering on a white reflective background (Shore) or black lettering on a non-reflective olive drab background...17038. 2-54 (b) On vehicles painted white, individual letters and numbers shall be the reflective type, conforming to Type I, Class 3, Blue ...manufacturer’s color. The word “Police” in 4-inch reflectorized blue letters of material conforming to ASTM D4956, Type III, Class 1 (encapsulated lens), shall
Yabsley, Michael J; Jordan, Carly N; Mitchell, Sheila M; Norton, Terry M; Lindsay, David S
2007-03-15
In the current study, we determined the seroprevalence of Toxoplasma gondii, Sarcocystis neurona, and Encephalitozoon cuniculi in three species of lemurs from St. Catherines Island, Georgia. Serum samples were tested from 52 ring-tailed lemurs (Lemur catta), six blue-eyed black lemurs (Eulemur macaco flavifrons), and four black and white ruffed lemurs (Varecia variegata variegata) using an agglutination assay. Three ring-tailed lemurs (5.8%) were positive for T. gondii (titer of 1:50); one ring-tailed lemur (1.9%) and one black and white ruffed lemur (25%) were positive for S. neurona (titers of 1:1000); and one ring-tailed lemur (1.9%) was positive for E. cuniculi (titer of 1:400). All blue-eyed black lemurs were negative for antibodies to T. gondii, S. neurona, and E. cuniculi. This is the first detection of antibodies to T. gondii in ring-tailed lemurs and antibodies to S. neurona and E. cuniculi in any species of prosimian.
Advanced Monitoring of Migratory Birds on Military Lands
2010-03-01
BRSP Brewer‟s Sparrow BTSP Black - throated Sparrow BLGR Blue Grosbeak CAKI Cassin‟s Kingbird CONI Common Nighthawk EAME Eastern...Fuller et al. 1998). This approach has been used for many species, ranging from Black - throated Sparrow (Amphispiza bilineata, Pidgeon et al 2003) to...lightest yellow indicates a predicted abundance of zero. Species acronym key: BTSP Black - throated Sparrow ; EAME Eastern Meadowlark; WEKI Western
The Dress: Transforming a web viral event into a scientific survey.
Moccia, Marcello; Lavorgna, Luigi; Lanzillo, Roberta; Brescia Morra, Vincenzo; Tedeschi, Gioacchino; Bonavita, Simona
2016-05-01
The Dress picture recently has become a hot topic on the Internet, prompting a debate whether it was black and blue, or white and gold. To investigate The Dress color perception in both multiple sclerosis (MS) patients, characterized by frequent visual system impairment with ensuing color vision effects, and general population. We developed a questionnaire to record demographics, clinical features, and The Dress color perception, posted on general and MS-specific social networks. No statistically significant differences were observed in The Dress color perception between MS patients (n=103) and general population (n=441). Furthermore, white and gold color perception was positively associated with aging in the general population (p=0.04), whereas negatively associated with progressive course (p=0.03) and longer disease duration (p<0.001) in MS patients, independently from patients' age. The Dress black and blue or white and gold perception might be due to aging in the general population, whereas black and blue perception, despite of aging, might suggest a specific effect of the MS burden (i.e. disease duration and progression) on the visual structures specifically involved in the white and gold perception. Copyright © 2016 Elsevier B.V. All rights reserved.
The Effects of Blue Light on Ocular Health.
ERIC Educational Resources Information Center
Kitchel, Elaine
2000-01-01
This review of the literature examines the effects of blue light (or near UV - ultraviolet), especially that given off by black-light tubes, often used with children with visual impairments. It finds a long-term danger of retinal and lens damage and offers six practical suggestions which emphasize using proper filters and limiting exposure to…
Code of Federal Regulations, 2013 CFR
2013-07-01
... printed on white or very light paper. Any label markings for which colors are not specified must be in black and white as shown. Some portions of the label must be filled with a blue or blue-shaded color as specified in subpart D of this part. Use the color blue defined in CMYK values of 40c-10m-0y-0k, or it may...
Code of Federal Regulations, 2012 CFR
2012-07-01
... printed on white or very light paper. Any label markings for which colors are not specified must be in black and white as shown. Some portions of the label must be filled with a blue or blue-shaded color as specified in subpart D of this part. Use the color blue defined in CMYK values of 40c-10m-0y-0k, or it may...
Code of Federal Regulations, 2014 CFR
2014-07-01
... printed on white or very light paper. Any label markings for which colors are not specified must be in black and white as shown. Some portions of the label must be filled with a blue or blue-shaded color as specified in subpart D of this part. Use the color blue defined in CMYK values of 40c-10m-0y-0k, or it may...
The Rhetorical Dimensions of Black Music Past and Present.
ERIC Educational Resources Information Center
Baker, David N.
Examination of lyrics of the blues and jazz forms of black music indicates their importance as communication. Contemporary styles can be divided into five overlapping categories: (1) "mainstream," the post-"bebop" style and soul jazz; (2) jazz influenced by other ethnic music; (3) the avant-garde jazz, which is often…
Afro-American Music and Dance.
ERIC Educational Resources Information Center
Floyd, Samuel A., Jr.
1989-01-01
Outlines the concurrent development of Black music and Black dance in the United States, and describes the interaction of the two genres throughout their mutually dependent evolutions. Traces the histories of the dances of African American culture, known collectively as "jazz dance," in relation to ragtime, jazz, and the blues. (AF)
ERIC Educational Resources Information Center
Stuart, Reginald
2009-01-01
Today, a national economy gone bust has derailed Black Americans' plans across the country. Gone are many of the economic gains, small as they were, achieved in the post-segregation era by millions of 1960s generation children and their children. Black America today is beset by job losses, business closures, pay cuts, furloughs, investment and…
Marine Mammal Demographics Off the Outer Washington Coast and Near Hawaii
2012-04-01
and June 2009 recorded at the inshore site. Black bars represent the fraction of days blue whales were detected in a month, and blue...point FFT and 98% overlap.) Figure 12: Occurrence of fin whale calls between June 2008 and June 2009 recorded at the inshore site. Black bars...Figure 14: Occurrence of humpback whale sounds (song and non‐song) between June 2008 and June 2009 recorded at the inshore site. Black bars
Exploration of Marine Resources by Photographic Remote Sensing
NASA Technical Reports Server (NTRS)
Duntley, S. Q.; Stevenson, R. E.; Boileau, A. R.
1971-01-01
The interpretation of photographs in oceanographic remote sensing is discussed. The photographs were made from spacecraft with two exceptions. Two photographs were made from aircraft. There were three types of film used to make the photographs: black-and-white, color, and color IR. Black and white photography is well known; it presents pictures in various shades of gray from black to white. Color film presents pictures in color, very nearly as the human eye sees them. Color IR film presents pictures in color also but not as seen by the human eye. Blue becomes much deeper blue, green is suppressed to some extent, and red is recorded beyond the visual range of the human eye, out in the near infrared. The most noticeable effect of the use of color IR film is that leaf materials which are highly reflective in the infrared part of the spectrum are presented as red.
ERIC Educational Resources Information Center
Holiday, D. Alexander
The language of Black America is rich and diverse in its utterance, whether through music (Jazz, Blues, Soul, Gospel, and Rap), through street corner "shuckin''n jivin'," or through writing. This language is used as a means of survival, of getting from one day to the next. Blacks have developed a system of taking the fewest words and…
7 CFR 52.3187 - Definitions and explanations of defects.
Code of Federal Regulations, 2012 CFR
2012-01-01
... by the following are scorable as defects: (a) Off-color. “Off-color” means a skin color different from characteristic black, blue-black, reddish-purple, or other characteristic skin color for the type... length. (d) Skin or flesh damage. “Skin or flesh damage” in the case of “Whole Unpitted” style means: (1...
ERIC Educational Resources Information Center
Byrnes, Deborah A.; Kiger, Gary
The effectiveness of a well-known prejudice-reduction simulation activity, "Blue Eyes-Brown Eyes," was assessed as a tool for changing the attitudes of nonblack teacher education students toward blacks. The subjects were 164 students enrolled in eight sections of an introductory elementary education course at a state university. Three…
24. A black and white photograph, 8" x 10" on ...
24. A black and white photograph, 8" x 10" on glossy paper. The label on face, black type-script "Floor Display, Terre Haute Gas", on reverse, in red pencil "3/23/56", "Terre Haute Gas Corporation", rubber stamp in blue ink, in white paper-backed acetate sleeve. Property of Indiana Gas Company, located in the Terre Haute office. - John T. Beasley Building, 632 Cherry Street (between Sixth & Seventh Streets), Terre Haute, Vigo County, IN
Stavenga, Doekele G; Leertouwer, Hein L; Wilts, Bodo D
2014-06-15
The coloration of the common butterflies Aglais urticae (small tortoiseshell), Aglais io (peacock) and Vanessa atalanta (red admiral), belonging to the butterfly subfamily Nymphalinae, is due to the species-specific patterning of differently coloured scales on their wings. We investigated the scales' structural and pigmentary properties by applying scanning electron microscopy, (micro)spectrophotometry and imaging scatterometry. The anatomy of the wing scales appears to be basically identical, with an approximately flat lower lamina connected by trabeculae to a highly structured upper lamina, which consists of an array of longitudinal, parallel ridges and transversal crossribs. Isolated scales observed at the abwing (upper) side are blue, yellow, orange, red, brown or black, depending on their pigmentation. The yellow, orange and red scales contain various amounts of 3-OH-kynurenine and ommochrome pigment, black scales contain a high density of melanin, and blue scales have a minor amount of melanin pigment. Observing the scales from their adwing (lower) side always revealed a structural colour, which is blue in the case of blue, red and black scales, but orange for orange scales. The structural colours are created by the lower lamina, which acts as an optical thin film. Its reflectance spectrum, crucially determined by the lamina thickness, appears to be well tuned to the scales' pigmentary spectrum. The colours observed locally on the wing are also due to the degree of scale stacking. Thin films, tuned pigments and combinations of stacked scales together determine the wing coloration of nymphaline butterflies. © 2014. Published by The Company of Biologists Ltd.
Note: Views 2846 are photographic copies of architectural drawings (black ...
Note: Views 28-46 are photographic copies of architectural drawings (black India ink on blue imperial cloth Irish linen by the Shrourds-Stoner firm, dated July 19, 1924. The original drawings are located in the Indiana State University Archives. - John T. Beasley Building, 632 Cherry Street (between Sixth & Seventh Streets), Terre Haute, Vigo County, IN
49 CFR 172.407 - Label specifications.
Code of Federal Regulations, 2013 CFR
2013-10-01
..., numbers, and border must be shown in black on a label except that— (i) White may be used on a label with a one color background of green, red or blue. (ii) White must be used for the text and class number for the CORROSIVE label. (iii) White may be used for the symbol for the ORGANIC PEROXIDE label. (3) Black...
49 CFR 172.407 - Label specifications.
Code of Federal Regulations, 2014 CFR
2014-10-01
..., numbers, and border must be shown in black on a label except that— (i) White may be used on a label with a one color background of green, red or blue. (ii) White must be used for the text and class number for the CORROSIVE label. (iii) White may be used for the symbol for the ORGANIC PEROXIDE label. (3) Black...
49 CFR 172.407 - Label specifications.
Code of Federal Regulations, 2011 CFR
2011-10-01
..., numbers, and border must be shown in black on a label except that— (i) White may be used on a label with a one color background of green, red or blue. (ii) White must be used for the text and class number for the CORROSIVE label. (iii) White may be used for the symbol for the ORGANIC PEROXIDE label. (3) Black...
7 CFR 52.3187 - Definitions and explanations of defects.
Code of Federal Regulations, 2013 CFR
2013-01-01
...-color” means a skin color different from characteristic black, blue-black, reddish-purple, or other characteristic skin color for the type. (b) Poor texture. “Poor texture” means porous, woody, or fibrous flesh or... not more than 1/2 inch in length. (d) Skin or flesh damage. “Skin or flesh damage” in the case of...
7 CFR 52.3187 - Definitions and explanations of defects.
Code of Federal Regulations, 2014 CFR
2014-01-01
...-color” means a skin color different from characteristic black, blue-black, reddish-purple, or other characteristic skin color for the type. (b) Poor texture. “Poor texture” means porous, woody, or fibrous flesh or... not more than 1/2 inch in length. (d) Skin or flesh damage. “Skin or flesh damage” in the case of...
NASA Astrophysics Data System (ADS)
Ilayaraja, Renganathan; Rajkumar, Ramalingam; Rajesh, Durairaj; Muralidharan, Arumugam Ramachandran; Padmanabhan, Parasuraman; Archunan, Govindaraju
2014-06-01
Chemosignals play a crucial role in social and sexual communication among inter- and intra-species. Chemical cues are bound with protein that is present in the pheromones irrespective of sex are commonly called as pheromone binding protein (PBP). In rats, the pheromone compounds are bound with low molecular lipocalin protein α2u-globulin (α2u). We reported farnesol is a natural endogenous ligand (compound) present in rat preputial gland as a bound volatile compound. In the present study, an attempt has been made through computational method to evaluating the binding efficiency of α2u with the natural ligand (farnesol) and standard fluorescent molecule (2-naphthol). The docking analysis revealed that the binding energy of farnesol and 2-naphthol was almost equal and likely to share some binding pocket of protein. Further, to extrapolate the results generated through computational approach, the α2u protein was purified and subjected to fluorescence titration and binding assay. The results showed that the farnesol is replaced by 2-naphthol with high hydrophobicity of TYR120 in binding sites of α2u providing an acceptable dissociation constant indicating the binding efficiency of α2u. The obtained results are in corroboration with the data made through computational approach.
Valdez Domingos, F X; Oliveira Ribeiro, C A; Pelletier, É; Rouleau, C
2011-04-01
Light polycyclic aromatic hydrocarbons (PAHs) of petrogenic origin are commonly found in estuaries and coastal areas. Though they are known to be toxic to fish, little is known about their uptake and tissue distribution. This paper reports on the results of a study on uptake, elimination, and tissue distribution of three waterborne 14C-labeled PAHs in the mummichog, Fundulus heteroclitus, using whole-body autoradiography. After a 24 h exposure to 1 μCi·L(-1) of 14C-naphthalene, 14C-1-naphthol, and 14C-phenanthrene, fish were transferred to clean water and tissue distribution examined after 0, 1, 3, 7, 14, and 21 days of depuration. All compounds were readily accumulated by fish and were also rapidly eliminated (t0.5 range=1.1 to 3.0 days). Most of the radioactivity in naphthalene- and phenanthrene-treated fish was found in gall bladder≫liver>intestinal lumen. In naphthol-exposed fish, an important labeling of some brain areas was observed. Brain of naphthalene-exposed fish was also labeled after 24 h depuration, indicating that exposure to naphthalene may result in metabolite accumulation in the brain. This is the first study showing that naphthalene, naphthol, and/or unidentified metabolite(s) can accumulate in brain tissues, which may impair normal brain function.
Earthshots: Satellite images of environmental change – Lake Urmia, Iran
Adamson, Thomas
2015-01-01
The lake’s southern basin is shallower than its northern basin, so recent images show the water disappearing from the southern basin first. These Landsat images use the shortwave-infrared, near-infrared, and green wavelengths of light. Because water absorbs infrared light, water (dark blue to black) contrasts with the surrounding land areas. As the water becomes shallower, light is reflected off of the lakebed in shades of light blue. Lighter blue and bright areas immediately surrounding the lake are where the receding shoreline has exposed the lake bottom.
NASA Astrophysics Data System (ADS)
Kim, Jin Yi; Sim, Ho Hyung; Song, Sinae; Noh, Yeoung Ah; Lee, Hong Woon; Taik Kim, Hee
2018-03-01
Titanium dioxide (TiO2) is one of the representative ceramic materials containing photocatalyst, optic and antibacterial activity. The hydroxyl radical in TiO2 applies to the intensive oxidizing agent, hence TiO2 is suitable to use photocatalytic materials. Black TiO2was prepared through reduction of amorphous TiO2 conducting under H2 which leads to color changes. Its black color is proven that absorbs 100% light across the whole-visible light, drawing enhancement of photocatalytic property. In this study, we aimed to compare the photocatalytic activity of silver ion doped on TiO2(TiO2/Ag+) and silver ion doped on black TiO2(black TiO2/Ag+) under visible light range. TiO2/Ag+ was fabricated following steps. 1) TiO2 was synthesized by a sol-gel method from Titanium tetraisopropoxide (TTIP). 2) Then AgNO3 was added during an aging process step for silver ion doping on the surface of TiO2. Moreover, Black TiO2/Ag+ was obtained same as TiO2/Ag+ except for calcination under H2. The samples were characterized X-ray diffraction (XRD), UV-visible reflectance (UV-vis DRS), and Methylene Blue degradation test. XRD analysis confirmed morphology of TiO2. The band gap of black TiO2/Ag+ was confirmed (2.6 eV) through UV-vis DRS, which was lower than TiO2/Ag+ (2.9 eV). The photocatalytic effect was conducted by methylene blue degradation test. It demonstrated that black TiO2/Ag+ had a photocatalytic effect under UV light also visible light.
Horridge, Adrian
2015-01-01
Behind each facet of the compound eye, bees have photoreceptors for ultraviolet, green, and blue wavelengths that are excited by sunlight reflected from the surrounding panorama. In experiments that excluded ultraviolet, bees learned to distinguish between black, gray, white, and various colors. To distinguish two targets of differing color, bees detected, learned, and later recognized the strongest preferred inputs, irrespective of which target displayed them. First preference was the position and measure of blue reflected from white or colored areas. They also learned the positions and a measure of the green receptor modulation at vertical edges that displayed the strongest green contrast. Modulation is the receptor response to contrast and was summed over the length of a contrasting vertical edge. This also gave them a measure of angular width between outer vertical edges. Third preference was position and a measure of blue modulation. When they returned for more reward, bees recognized the familiar coincidence of these inputs at that place. They cared nothing for colors, layout of patterns, or direction of contrast, even at black/white edges. The mechanism is a new kind of color vision in which a large-field tonic blue input must coincide in time with small-field phasic modulations caused by scanning vertical edges displaying green or blue contrast. This is the kind of system to expect in medium-lowly vision, as found in insects; the next steps are fresh looks at old observations and quantitative models. PMID:28539792
NASA Astrophysics Data System (ADS)
Shechter, M.; Chefetz, B.
2009-04-01
Plant cuticle materials, especially the highly aliphatic biopolymers cutin and cutan, have been reported as highly efficient natural sorbents. The objective of this study was to examine the effects of decomposition on their sorption behavior with naphthol and phenanthrene. The level of cutin and cutan was reduced by 15 and 27% respectively during the first 3 mo of incubation. From that point, the level of the cutan did not change, while the level of the cutin continued to decrease up to 32% after 20 mo. 13C NMR analysis suggested transformation of cutan mainly within its alkyl-C structure which are assigned as crystalline moieties. Cutin, however, did not exhibit significant structure changes with time. The level of humic-like substances increased due to cutin decomposition but was not influenced in the cutan system after 20 mo of incubation. This indicates that the cutin biopolymer has been decomposed and transformed into humic-like substances, whereas the cutan was less subject to transformation. Decomposition affected sorption properties in similar trends for both cutin and cutan. The Freundlich capacity coefficients (KFOC) of naphthol were much lower than phenanthrene and were less influenced by the decomposition, whereas with phenanthrene KFOC values increased significantly with time. Naphthol exhibited non-linear isotherms; and nonlinearity was decreased with incubation time. In contrast, phenanthrene isotherms were more linear and showed only moderate change with time. The decrease in the linearity of naphthol isotherms might relate to the transformation of the sorption sites due to structural changes in the biopolymers. However, with phenanthrene, these changes did not affect sorption linearity but increased sorption affinities mainly for cutan. This is probably due to decomposition of the rigid alkyl-C moieties in the cutan biopolymer. Our data suggest that both biopolymers were relatively stable in the soil for 20 mo. Cutan is less degradable than cutin and therefore is more likely to accumulate in soils and contribute to the refractory aliphatic components of soil organic matter.
1989-03-01
detail in a small area, use achromatic colors ( black , white, and grey) and use chromatic colors for larger panels or for attracting attention. b. Blues...purposes (e.g., to draw the users attention to a total, a broken bar or other important data element). b. Black and white should be used with caution. They...enough to set the bars or columns off from the background and define figure and ground relationships. (2) Use black in small areas and for certain
27. A black & white photograph, 7 1/2" x 10" ...
27. A black & white photograph, 7 1/2" x 10" on glossy paper. An aerial oblique of central Terre Haute. This view, taken looking north, shows the gas company building on the bottom margin, slightly right of center. On reverse, in black pencil, "Summer, 1965 Arnold-Damon Studio" and in blue ink cursive script, "Aerial Views 1974". Source: Indiana State University Archives. - John T. Beasley Building, 632 Cherry Street (between Sixth & Seventh Streets), Terre Haute, Vigo County, IN
Kosnarite, KZr2(PO4)3, a new mineral from Mount Mica and Black Mountain, Oxford County, Maine
Brownfield, M.E.; Foord, E.E.; Sutley, S.J.; Botinelly, T.
1993-01-01
Kosnarite, ideally KZr2(PO4)3, has been identified as part of a late-stage, secondary phosphate mineral assemblage from the Mount Mica pegmatite at Paris, and from the Black Mountain pegmatite, Rumford, Oxford County, Maine. Kosnarite from Mount Mica occurs as pseudocubic rhombohedral crystals, as much as 0.9 mm in maximum dimension, that display the dominant {102} form. Color ranges from pale blue to blue-green to nearly colorless. The mineral has a white streak, is transparent, has a vitreous luster, and is nonfluorescent in ultraviolet light. It has a hardness of 4.5, is brittle with a conchoidal fracture, and has perfect {102} cleavage. Kosnarite from Black Mountain is almost pure KZr2(PO4)3 with only trace amounts of Hf, Mn, Na, and Rb. The mineral is one of three known alkali zirconium phosphates; the others are gainesite and the Cs analogue of gainesite. -from Author
,
2001-01-01
U.S. Geological Survey (USGS) topographic maps are printed using up to six colors (black, blue, green, red, brown, and purple). To prepare your own maps or artwork based on maps, you can order separate black-and-white film positives or negatives for any color printed on a USGS topographic map, or for one or more of the groups of related features printed in the same color on the map (such as drainage and drainage names from the blue plate.) In this document, examples are shown with appropriate ink color to illustrate the various separates. When purchased, separates are black-and-white film negatives or positives. After you receive a film separate or composite from the USGS, you can crop, enlarge or reduce, and edit to add or remove details to suit your special needs. For example, you can adapt the separates for making regional and local planning maps or for doing many kinds of studies or promotions by using the features you select and then printing them in colors of your choice.
Federal Register 2010, 2011, 2012, 2013, 2014
2010-09-01
... jackrabbit (Bednarz 1977, p. 14). The lower Animas Valley supports a variety of grass and forb species, such... Mexico as the density and vigor of grasses declined, while black-tailed jackrabbits and desert cottontail... the jackrabbit required 65 percent grass cover of species that included blue and black grama, ring...
2016-07-28
The blue dots in this field of galaxies, known as the COSMOS field, show galaxies that contain supermassive black holes emitting high-energy X-rays. The black holes were detected by NASA's Nuclear Spectroscopic Array, or NuSTAR, which spotted 32 such black holes in this field and has observed hundreds across the whole sky so far. The other colored dots are galaxies that host black holes emitting lower-energy X-rays, and were spotted by NASA's Chandra X-ray Observatory. Chandra data show X-rays with energies between 0.5 to 7 kiloelectron volts, while NuSTAR data show X-rays between 8 to 24 kiloelectron volts. http://photojournal.jpl.nasa.gov/catalog/PIA20865
The descendants of the first quasars in the BlueTides simulation
NASA Astrophysics Data System (ADS)
Tenneti, Ananth; Di Matteo, Tiziana; Croft, Rupert; Garcia, ThomasJae; Feng, Yu
2018-02-01
Supermassive blackholes with masses of a billion solar masses or more are known to exist up to z = 7. However, the present-day environments of the descendants of first quasars are not well understood and it is not known if they live in massive galaxy clusters or more isolated galaxies at z = 0. We use a dark matter-only realization (BTMassTracer) of the BlueTides cosmological hydrodynamic simulation to study the halo properties of the descendants of the most massive black holes at z = 8. We find that the descendants of the quasars with most massive black holes are not amongst the most massive haloes. They reside in haloes of with group-like (˜1014 M⊙) masses, while the most massive haloes in the simulations are rich clusters with masses ˜1015 M⊙. At z = 0, the distribution of halo masses of these quasar descendants is similar to that of the descendants of least massive black holes, which indicates that they are likely to exist in similar environments. By tracing back to the z = 8 progenitors of the most massive (cluster sized) haloes at z = 0; we find that their most likely black hole mass is less than 107 M⊙; they are clearly not amongst the most massive black holes. For haloes above 1015 M⊙, there is only 20 per cent probability that their z = 8 progenitors hosted a black hole with mass above 107 M⊙.
Microplastics in sediments from the littoral zone of the north Tunisian coast (Mediterranean Sea)
NASA Astrophysics Data System (ADS)
Abidli, Sami; Antunes, Joana C.; Ferreira, Joana L.; Lahbib, Youssef; Sobral, Paula; Trigui El Menif, Najoua
2018-05-01
The distribution of microplastics (MPs) was investigated in the sediments of five sampling sites from the northern Tunisian coast during June 2017. MPs were categorized according to type, colour and size. Representative MPs from the five sites were isolated for polymer identification using Fourier Transformed Infrared Spectroscopy in attenuated total reflectance mode (FTIR-ATR). Results showed that MPs were recovered, from all sediment samples, indicating for the first time, their extensive distribution in Tunisian coast. Concentrations varied from 141.20 ± 25.98 to 461.25 ± 29.74 items kg-1 dry weight. Fibres, fragments, Styrofoam®, pellets and films were the types registered in this study. With the exception of Menzel Bourguiba (MB), fibres significantly outnumbered plastic particles followed by fragments, Styrofoam®, films and pellets. The predominant colours are as follows: black > clear > white > red > blue > green for fibres, blue > white > clear > red > green > yellow > black for fragments, blue > white > black > clear for films while only white pellets and Styrofoam® were found. MPs particles ranged from 0.1 to 5 mm in length. A total of three polymer types were identified, polyethylene (PE), polypropylene (PP) and polystyrene (PS). Except for industrial pellets, the presence of MPs is likely due to the degradation of marine plastic debris accumulating in each site. This work provides original data of the presence of MPs in coastal sediments from Northern Tunisian coast.
Siebenhandl, Susanne; Grausgruber, Heinrich; Pellegrini, Nicoletta; Del Rio, Daniele; Fogliano, Vincenzo; Pernice, Rita; Berghofer, Emmerich
2007-10-17
Two pigmented wheat genotypes (blue and purple) and two black barley genotypes were fractionated in bran and flour fractions, examined, and compared for their free radical scavenging properties against 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt radical cation (Trolox equivalent antioxidant capacity, TEAC), ferric reducing antioxidant power (FRAP), total phenolic content (TPC), phenolic acid composition, carotenoid composition, and total anthocyanin content. The results showed that fractionation has a significant influence on the antioxidant properties, TPC, anthocyanin and carotenoid contents, and phenolic acid composition. Bran fractions had the greatest antioxidant activities (1.9-2.3 mmol TEAC/100 g) in all four grain genotypes and were 3-5-fold higher than the respective flour fractions (0.4-0.7 mmol TEAC/100 g). Ferulic acid was the predominant phenolic acid in wheat genotypes (bran fractions) while p-coumaric acid was the predominant phenolic acid in the bran fractions of barley genotypes. High-performance liquid chromatography analysis detected the presence of lutein and zeaxanthin in all fractions with different distribution patterns within the genotypes. The highest contents of anthocyanins were found in the middlings of black barley genotypes or in the shorts of blue and purple wheat. These data suggest the possibility to improve the antioxidant release from cereal-based food through selection of postharvest treatments.
Zhang, Mengli; Huang, Yuqing; Lin, Tong; Wu, Qiuju
2018-02-28
To retrospectively evaluate the efficacy of an Alexandrite picosecond laser versus Nd:YAG nanosecond laser for removing blue-black eyeliner tattoos which have existed more than 10 years. A total of 40 patients were treated with an Alexandrite picosecond laser in our department from August 2015 to July 2017, with a fluence of 1.96-6.37J/cm 2 , spot size of 2.0-3.6 mm, and pulse width of 750 ps. Another 32 patients were treated with an Nd:YAG nanosecond laser, with a fluence of 2.80-7.00 J/cm 2 , spot size of 3 mm, and pulse width of 5-20 ns. All analysed patients completed at least one treatment and follow-up. The median number of treatment for all the patients was 1 (range, 1-4). After a single session, no difference was found between the two lasers for the eyeliner removal (p > 0.05). For the people who achieved an excellent response of tattoo clearance, there was still no difference between the two groups (p > 0.05). Transient side effects were observed in two groups, but neither group had significant adverse reactions. To treat blue-black Chinese eyeliner tattoos over 10 years, Alexandrite picosecond laser does not provide better clearance than the Nd:YAG nanosecond laser.
Color- and motion-specific units in the tectum opticum of goldfish.
Gruber, Morna; Behrend, Konstantin; Neumeyer, Christa
2016-01-05
Extracellular recordings were performed from 69 units at different depths between 50 and [Formula: see text]m below the surface of tectum opticum in goldfish. Using large field stimuli (86[Formula: see text] visual angle) of 21 colored HKS-papers we were able to record from 54 color-sensitive units. The colored papers were presented for 5[Formula: see text]s each. They were arranged in the sequence of the color circle in humans separated by gray of medium brightness. We found 22 units with best responses between orange, red and pink. About 12 of these red-sensitive units were of the opponent "red-ON/blue-green-OFF" type as found in retinal bipolar- and ganglion cells as well. Most of them were also activated or inhibited by black and/or white. Some units responded specifically to red either with activation or inhibition. 18 units were sensitive to blue and/or green, 10 of them to both colors and most of them to black as well. They were inhibited by red, and belonged to the opponent "blue-green-ON/red-OFF" type. Other units responded more selectively either to blue, to green or to purple. Two units were selectively sensitive to yellow. A total of 15 units were sensitive to motion, stimulated by an excentrically rotating black and white random dot pattern. Activity of these units was also large when a red-green random dot pattern of high L-cone contrast was used. Activity dropped to zero when the red-green pattern did not modulate the L-cones. Neither of these motion selective units responded to any color. The results directly show color-blindness of motion vision, and confirm the hypothesis of separate and parallel processing of "color" and "motion".
How bees distinguish patterns by green and blue modulation
Horridge, Adrian
2015-01-01
In the 1920s, Mathilde Hertz found that trained bees discriminated between shapes or patterns of similar size by something related to total length of contrasting contours. This input is now interpreted as modulation in green and blue receptor channels as flying bees scan in the horizontal plane. Modulation is defined as total contrast irrespective of sign multiplied by length of edge displaying that contrast, projected to vertical, therefore, combining structure and contrast in a single input. Contrast is outside the eye; modulation is a phasic response in receptor pathways inside. In recent experiments, bees trained to distinguish color detected, located, and measured three independent inputs and the angles between them. They are the tonic response of the blue receptor pathway and modulation of small-field green or (less preferred) blue receptor pathways. Green and blue channels interacted intimately at a peripheral level. This study explores in more detail how various patterns are discriminated by these cues. The direction of contrast at a boundary was not detected. Instead, bees located and measured total modulation generated by horizontal scanning of contrasts, irrespective of pattern. They also located the positions of isolated vertical edges relative to other landmarks and distinguished the angular widths between vertical edges by green or blue modulation alone. The preferred inputs were the strongest green modulation signal and angular width between outside edges, irrespective of color. In the absence of green modulation, the remaining cue was a measure and location of blue modulation at edges. In the presence of green modulation, blue modulation was inhibited. Black/white patterns were distinguished by the same inputs in blue and green receptor channels. Left–right polarity and mirror images could be discriminated by retinotopic green modulation alone. Colors in areas bounded by strong green contrast were distinguished as more or less blue than the background. The blue content could also be summed over the whole target. There were no achromatic patterns for bees and no evidence that they detected black, white, or gray levels apart from the differences in blue content or modulation at edges. Most of these cues would be sensitive to background color but some were influenced by changes in illumination. The bees usually learned only to avoid the unrewarded target. Exactly the same preferences of the same inputs were used in the detection of single targets as in discrimination between two targets. PMID:28539796
Landsat 7 - First Cloud-free Image of Yellowstone National Park
NASA Technical Reports Server (NTRS)
2002-01-01
This image of Yellowstone Lake, in the center of Yellowstone National Park, was taken by Landsat 7 on July 13, 1999. Bands 5 (1.65um),4 (.825um), and 2 (.565um) were used for red, green, and blue, respectively. Water appears blue/black, snow light blue, mature forest red/green, young forest pink, and grass and fields appear light green. Southwest of the lake is young forest that is growing in the wake of the widespread fires of 1988. For more information, see: Landsat 7 Fact Sheet Landsat 7 in Mission Control Image by Rich Irish, NASA GSFC
Fluorescent and colorimetric molecular recognition probe for hydrogen bond acceptors.
Pike, Sarah J; Hunter, Christopher A
2017-11-22
The association constants for formation of 1 : 1 complexes between a H-bond donor, 1-naphthol, and a diverse range of charged and neutral H-bond acceptors have been measured using UV/vis absorption and fluorescence emission titrations. The performance of 1-naphthol as a dual colorimetric and fluorescent molecular recognition probe for determining the H-bond acceptor (HBA) parameters of charged and neutral solutes has been investigated in three solvents. The data were employed to establish self-consistent H-bond acceptor parameters (β) for benzoate, azide, chloride, thiocyanate anions, a series of phosphine oxides, phosphate ester, sulfoxide and a tertiary amide. The results demonstrate both the transferability of H-bond parameters between different solvents and the utility of the naphthol-based dual molecular recognition probe to exploit orthogonal spectroscopic techniques to determine the HBA properties of neutral and charged solutes. The benzoate anion is the strongest HBA studied with a β parameter of 15.4, and the neutral tertiary amide is the weakest H-bond acceptor investigated with a β parameter of 8.5. The H-bond acceptor strength of the azide anion is higher than that of chloride (12.8 and 12.2 respectively), and the thiocyanate anion has a β value of 10.8 and thus is a significantly weaker H-bond acceptor than both the azide and chloride anions.
Population trends and environmental contaminants in herons in the Tennessee Valley, 1980-81
Fleming, W.J.; Pullin, B.P.; Swineford, D.M.
1984-01-01
Great Blue Heron (Ardea herodias) eggs (N = 40) collected in 1980 from four of the largest colonies in the Tennessee Valley contained organochlorine pesticide, polychlorinated biphenyl (PCB), and chromium concentrations below those associated with reduced productivity. Low concentrations of organochlorine pesticide and PCB residues also were found in eggs (N = 31) from three of the larger Black-crowned Night-Heron (Nycticorax nycticorax) colonies in the Tennessee Valley. However, DDE concentrations in two of the Black-crowned Night-Heron eggs exceeded levels associated with reduced nesting success. Mercury was found in all eggs of both species with residues ranging to a high of 2.0 ppm; residues of this magnitude have not been identified as reducing nesting success of either of these two species. Green-backed Heron (Butorides striatus) eggs collected in 1981 near a former DDT manufacturing site in the Tennessee Valley had the highest DDE concentrations ever reported for this species; the effect of these high concentrations on productivity is not known. Eggshell thickness of Great Blue Heron, Green-backed Heron, and Black- crowned Night-Heron eggs averaged 7.5%, 7.6%, and 3% thinner, respectively, than shell thickness of eggs collected before 1947. This amount of thinning is not deleterious; intraclutch variation in shell thickness is often this high. Shell thickness in all three species was correlated (P lt 0.1) with DDE concentrations. The number of nesting pairs of Great Blue Herons and Black-crowned Night-Herons at each of the colonies studied has been stable or increasing during the previous decade. These population data, combined with the residue data, suggest that organochlorine pesticides, PCBs, mercury, and chromium are not adversely affecting these populations. However, we did not assess nesting success which would be a requisite for confirming this.
The anti-intuitive visual system of the honey bee.
Horridge, A
2012-01-01
Because bees fly around, visit flowers and chase mates, we conclude intuitively that they see things as we do. But their vision is unexpectedly different, so we say it is anti-intuitive. Detailed tests have demonstrated separate detectors for modulation of blue and green receptors, edge orientation (green only), and areas of black. The edge detectors are about 3° across, independent, and not re-assembled to make lines, shapes or textures. Instead, the detectors of each type are summed quantitatively to form cues in each local region with an order of preference for learning the cues. Trained bees remember the positions of the total modulation (preferred), the average edge orientation, areas of black or colour, and positions of hubs of radial and circular edges in each local region, but not the original responses, so the pattern is lost. When presented with a yellow spot on a blue background with no UV reflected, the preferred cue is not the colour, but a measure of the modulation detected by the green and separately by the blue receptors.
Shaping Globular Clusters with Black Holes
NASA Astrophysics Data System (ADS)
Kohler, Susanna
2018-03-01
How many black holes lurk within the dense environments of globular clusters, and how do these powerful objects shape the properties of the cluster around them? One such cluster, NGC 3201, is now helping us to answer these questions.Hunting Stellar-Mass Black HolesSince the detection of merging black-hole binaries by the Laser Interferometer Gravitational-Wave Observatory (LIGO), the dense environments of globular clusters have received increasing attention as potential birthplaces of these compact binary systems.The central region of the globular star cluster NGC 3201, as viewed by Hubble. The black hole is in orbit with the star marked by the blue circle. [NASA/ESA]In addition, more and more stellar-mass black-hole candidates have been observed within globular clusters, lurking in binary pairs with luminous, non-compact companions. The most recent of these detections, found in the globular cluster NGC 3201, stands alone as the first stellar-mass black hole candidate discovered via radial velocity observations: the black holes main-sequence companion gave away its presence via a telltale wobble.Now a team of scientists led by Kyle Kremer (CIERA and Northwestern University) is using models of this system to better understand the impact that black holes might have on their host clusters.A Model ClusterThe relationship between black holes and their host clusters is complicated. Though the cluster environment can determine the dynamical evolution of the black holes, the retention rate of black holes in a globular cluster (i.e., how many remain in the cluster when they are born as supernovae, rather than being kicked out during the explosion) influences how the host cluster evolves.Kremer and collaborators track this complex relationship by modeling the evolution of a cluster similar to NGC 3201 with a Monte Carlo code. The code incorporates physics relevant to the evolution of black holes and black-hole binaries in globular clusters, such as two-body relaxation, single and binary star evolution, galactic tides, and multi-body encounters. From their grid of models with varying input parameters, the authors then determine which fit best to NGC 3201s final observational properties.Surface brightness profiles for all globular-cluster models at late times compared to observations of NGC 3201 (yellow circles). Blue lines represent models with few retained black holes; black lines represent models with many retained black holes. [Kremer et al. 2018]Retention MattersKremer and collaborators find that the models that best represent NGC 3201 all retain more than 200 black holes at the end of the simulation; models that lost too many black holes due to natal kicks did not match observations of NGC 3201 as well. The models with large numbers of retained black holes also harbored binaries just like the one recently detected in NGC 3201.Models that retain few black holes, on the other hand, may instead be good descriptions of so-called core-collapsed globular clusters observed in the Milky Way. The authors demonstrate that these clusters could contain black holes in binaries with stars known as blue stragglers, which may also be detectable with radial velocity techniques.Kremer and collaborators results suggest that globular clusters similar to NGC 3201 contain hundreds of invisible black holes waiting to be discovered, and they indicate some of the differences in cluster properties caused by hosting such a large population of black holes. We can hope that future observations and modeling will continue to illuminate the complicated relationship between globular clusters and the black holes that live in them.CitationKyle Kremer et al 2018 ApJL 855 L15. doi:10.3847/2041-8213/aab26c
Static and dynamic properties of 1,1'-bi-2-naphthol and its conjugated acids and bases.
Alkorta, Ibon; Cancedda, Céline; Cocinero, Emilio José; Dávalos, Juan Z; Ecija, Patrica; Elguero, José; González, Javier; Lesarri, Alberto; Ramos, Rocio; Reviriego, Felipe; Roussel, Christian; Uriarte, Iciar; Vanthuyne, Nicolas
2014-11-03
Several convergent techniques were used to characterize 1,1'-bi-2-naphthol (BINOL) and some of its properties. Its acidity in the gas-phase, from neutral species to monoanion, was measured by mass spectrometry. The conformation and structure of BINOL in the gas phase was determined by microwave rotational spectroscopy. NMR experiments in fluorosulfonic acid established that BINOL was monoprotonated on one of the hydroxyl oxygen atoms. The enantiomerization barriers reported in the literature for BINOL under neutral, basic, and acid conditions were analyzed with regard to the species involved. Finally, DFT calculations allowed all of these results to be gathered in a coherent picture of the BINOL structure. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Non-specific esterases in the gustatory epithelia of man and dog.
Rakhawy, M T
1976-01-01
(1) Simple esterase activity has been demonstrated in the gustatory epithelium of man and dog by the simultaneous coupling azo dye technique using alpha-naphthol and naphthol As acetate. Unfixed cryostat and fixed paraffin sections were used. (2) A peculiar pattern of simple esterase activity was encountered in which--contrary to what was to be expected--the taste bud-carrying papillae showed a very poor reaction while there was a gradual increase in the enzyme intensity as the epithelium was traced away from these papillae. (3) It seems that among the reported differences between simple esterases and cholinesterases is this differential activity in relation to the gemmal system. (4) A peculiar difference in the enzyme activity was reported between the unfixed cryostat and the fixed paraffin sections in the human material.
de Carvalho, Renato L; Jardim, Guilherme A M; Santos, Augusto; Araujo, Maria H; Oliveira, Willian X C; Bombaça, Ana Cristina; Menna-Barreto, Rubem F S; Gopi, Elumalai; Gravel, Edmond; Doris, Eric; da Silva Júnior, Eufrânio Nunes
2018-06-14
We report a combination of aryl diselenides/hydrogen peroxide and carbon nanotube-rhodium nanohybrid for naphthols oxidation towards synthesis of 1,4-naphthoquinones and evaluation of their relevant trypanocidal activity. Under a combination of (PhSe)2/H2O2 in the presence of O2 in i-PrOH/Hexane, several benzenoid (A-ring) substituted quinones were prepared in moderate to high yields. We also studied the contribution of RhCNT as co-catalyst in this process and, in some cases, yields were improved. This method provides an efficient and versatile alternative for preparing A-ring modified naphthoquinonoid compounds with relevant biological profile. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
JSTO Science and Technology Update. Volume 1, Number 2, Winter 2011
2011-01-01
Figure 2. Passage of methyl salicylate simulant through an expanded Teflon control (blue), the open IPN (black) and the closed IPN (pink). The...membrane (blue). ET is used in breathable sports clothing. The materials were challenged using vapor from the CW agent simulant methyl salicylate (MS). The...was challenged with vapor from chloroethyl ethyl sulfide (a mus- tard gas simulant), benzene, and liquid with dissolved methyl parathion (a V-agent
Black Hole Jets Make Shock Waves
2014-07-02
A composite image of the spiral galaxy NGC 4258 showing X-ray emission observed with NASA Chandra X-ray Observatory blue and infrared emission observed with NASA Spitzer Space Telescope red and green.
Jung, Kyung Hwa; Liu, Bian; Lovinsky-Desir, Stephanie; Yan, Beizhan; Camann, David; Sjodin, Andreas; Li, Zheng; Perera, Frederica; Kinney, Patrick; Chillrud, Steven; Miller, Rachel L.
2014-01-01
Background Exposure to air pollutants including polycyclic aromatic hydrocarbons (PAH), and specifically pyrene from combustion of fuel oil, coal, traffic and indoor sources, has been associated with adverse respiratory health outcomes. However, time trends of airborne PAH and metabolite levels detected via repeat measures over time have not yet been characterized. We hypothesized that PAH levels, measured repeatedly from residential indoor and outdoor monitors, and children’s urinary concentrations of PAH metabolites, would decrease following policy interventions to reduce traffic-related air pollution. Methods Indoor PAH (particle- and gas-phase) were collected for two weeks prenatally (n=98), at age 5/6 years (n=397) and age 9/10 years (n=198) since 2001 and at all three age-points (n=27). Other traffic-related air pollutants (black carbon and PM2.5) were monitored indoors simultaneous with PAH monitoring at ages 5/6 (n=403) and 9/10 (n=257) between 2005 and 2012. One third of the homes were selected across seasons for outdoor PAH, BC and PM2.5 sampling. Using the same sampling method, ambient PAH, BC and PM2.5 also were monitored every two weeks at a central site between 2007 and 2012. PAH were analyzed as semivolatile PAH (e.g., pyrene; MW 178–206) and the sum of eight nonvolatile PAH (Σ8PAHnonvolatile; MW 228–278). A spot urine sample was collected from children at child ages 3, 5, 7 and 9 between 2001 and 2012 and analyzed for 10 PAH metabolites. Results Modest declines were detected in indoor BC and PM2.5 levels between 2005 and 2012 (Annual percent change [APC]=−2.08% [p=0.010] and −2.18% [p=0.059] for BC and PM2.5, respectively), while a trend of increasing pyrene levels was observed in indoor and outdoor samples, and at the central site during the comparable time periods (APC=4.81%, 3.77% and 7.90%, respectively; p<0.05 for all). No significant time trend was observed in indoor Σ8PAHnonvolatile levels between 2005 and 2012; however, significant opposite trends were detected when analyzed seasonally (APC=−8.06% [p<0.01], 3.87% [p<0.05] for nonheating and heating season, respectively). Similarly, heating season also affected the annual trends (2005–2012) of other air pollutants: the decreasing BC trend (in indoor/outdoor air) was observed only in the nonheating season, consistent with dominating traffic sources that decreased with time; the increasing pyrene trend was more apparent in the heating season. Outdoor PM2.5 levels persistently decreased over time across the seasons. With the analyses of data collected over a longer period of time (2001–2012), a decreasing trend was observed in pyrene (APC=−2.76%; p<0.01), mostly driven by measures from the nonheating season (APC=−3.54%; p<0.01). In contrast, levels of pyrene and naphthalene metabolites, 1-hydroxypyrene and 2-naphthol, increased from 2001 to 2012 (APC=6.29% and 7.90% for 1-hydroxypyrene and 2-naphthol, respectively; p<0.01 for both). Conclusions Multiple NYC legislative regulations targeting traffic-related air pollution may have led to decreases in Σ8PAHnonvolatile and BC, especially in the nonheating season. Despite the overall decrease in pyrene over the 2001–2012 periods, a rise in pyrene levels in recent years (2005–2012), that was particularly evident for measures collected during the heating season, and 2-naphthol, indicates the contribution of heating oil combustion and other indoor sources to airborne pyrene and urinary 2-naphthol. PMID:24709094
2011-06-01
Selected Security Features in BlackBerry and SME PED Devices...Figure 1, the blue bars represent the net present value (NPV) of costs for current DoD wireless services on the unclassified (e.g., BlackBerry ) and...PDA], Blackberry , iPhone, etc.) for both Battle Command applications and communications and secure data only that needs to be classified as part of
Wave Evolution in River Mouths and Tidal Inlets
2014-06-01
Monterey Bay by a Datawell Buoy (blue) and three collocated WRD buoys (red). Also shown is the f −4 spectral roll off (black dashed). .............. 48...f −4 spectral roll off (black dashed) and the blocking frequency in regions B-E. .................................................... 53 Figure...Significant Wave Height Hz hertz IMU Inertial measurement unit JONSWAP Joint North Sea Wave Program km kilometer MCR Mouth of the Columbia River MEMS
The role of one-shot learning in #TheDress.
Drissi Daoudi, Leila; Doerig, Adrien; Parkosadze, Khatuna; Kunchulia, Marina; Herzog, Michael H
2017-03-01
#TheDress is remarkable in two aspects. First, there is a bimodal split of the population in the perception of the dress's colors (white/gold vs. black/blue). Second, whereas interobserver variance is high, intra-observer variance is low, i.e., the percept rarely switches in a given individual. There are two plausible routes of explanations: either one-shot learning during the first presentation of the image splits observers into two different, stable populations, or the differences are caused by stable traits of observers, such as different visual systems. Here, we hid large parts of the image by white occluders. The majority of naïve participants perceived the dress as black and blue. With black occluders, the majority of observers perceived the dress as white and gold. The percept did not change when we subsequently presented the full image, arguing for a crucial role of one-shot learning. Next, we investigated whether the first fixation determines the perceived color in naïve observers. We found no such effect. It remains thus a puzzling question where the source of variability in the different percepts comes from.
NASA Astrophysics Data System (ADS)
Castro, Kepa; Knuutinen, Ulla; Vallejuelo, Silvia Fdez-Ortiz de; Irazola, Mireia; Madariaga, Juan Manuel
2013-04-01
Several Finish wallpapers from the 18th and 19th century were analysed by using Raman spectroscopy assisted with EDXRF instrumentation, in an attempt of determine the pigments used in their manufacture process as well as of trying to date some of the samples through pigment composition. All pigments present in samples were determined and surprisingly the unusual and strange iron (III) chromate yellow pigment was found. Besides, unusual mixtures were found to obtain fashionable colours, especially in blue and green areas, where more than one blue pigments were mixed with green and yellow pigments. Blue verditer, ultramarine blue, Prussian blue, chrome yellow, calcite, lead white, red and yellow iron oxide, gypsum and carbon black were identified. The presence of the risky and poisonous emerald green must be highlighted. The results were compared with those found in other wallpapers from Spain and France.
An Unwelcome Place for New Stars (artist concept)
NASA Technical Reports Server (NTRS)
2006-01-01
[figure removed for brevity, see original site] Poster Version Suppression of Star Formation from Supermassive Black Holes This artist's concept depicts a supermassive black hole at the center of a galaxy. NASA's Galaxy Evolution Explorer found evidence that black holes -- once they grow to a critical size -- stifle the formation of new stars in elliptical galaxies. Black holes are thought to do this by heating up and blasting away the gas that fuels star formation. The blue color here represents radiation pouring out from material very close to the black hole. The grayish structure surrounding the black hole, called a torus, is made up of gas and dust. Beyond the torus, only the old red-colored stars that make up the galaxy can be seen. There are no new stars in the galaxy.7 CFR 51.2762 - Minor defects.
Code of Federal Regulations, 2014 CFR
2014-01-01
... of the following: (a) Skin discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow...
7 CFR 51.2720 - Minor defects.
Code of Federal Regulations, 2014 CFR
2014-01-01
... of the following: (a) Skin discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow...
7 CFR 51.2762 - Minor defects.
Code of Federal Regulations, 2013 CFR
2013-01-01
... of the following: (a) Skin discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow...
7 CFR 51.2720 - Minor defects.
Code of Federal Regulations, 2013 CFR
2013-01-01
... of the following: (a) Skin discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow...
78 FR 9370 - Notice of Scope Rulings
Federal Register 2010, 2011, 2012, 2013, 2014
2013-02-08
... with a basis weight of 210 gsm, and APP's blue-, grey-, and black-center playing card board which APP... Honey Producers Association and the Sioux Honey Association; blends of honey and rice syrup, regardless...
... levels in the body might drop too low. Stimulant laxative herbs include aloe, alder buckthorn, black root, blue flag, butternut bark, colocynth, European buckthorn, fo ti, gamboge, gossypol, greater bindweed, jalap, manna, Mexican scammony root, rhubarb, senna, and yellow dock.
ERIC Educational Resources Information Center
Kernohan, James C.
1991-01-01
The effect of background color on the perception of color by students is discussed. Explanations on why students only see certain colors when viewing colored marks on a blackboard through different color filters are provided. (KR)
Wyoming Wildfire Spotted by NASA Spacecraft
2016-07-28
The blue dots in this field of galaxies, known as the COSMOS field, show galaxies that contain supermassive black holes emitting high-energy X-rays. The black holes were detected by NASA's Nuclear Spectroscopic Array, or NuSTAR, which spotted 32 such black holes in this field and has observed hundreds across the whole sky so far. The other colored dots are galaxies that host black holes emitting lower-energy X-rays, and were spotted by NASA's Chandra X-ray Observatory. Chandra data show X-rays with energies between 0.5 to 7 kiloelectron volts, while NuSTAR data show X-rays between 8 to 24 kiloelectron volts. http://photojournal.jpl.nasa.gov/catalog/PIA20865
NASA Astrophysics Data System (ADS)
Kuniyal, Ravi Shankar; Uniyal, Rashmi; Biswas, Anindya; Nandan, Hemwati; Purohit, K. D.
2018-06-01
We investigate the geodesic motion of massless test particles in the background of a noncommutative geometry-inspired Schwarzschild black hole. The behavior of effective potential is analyzed in the equatorial plane and the possible motions of massless particles (i.e. photons) for different values of impact parameter are discussed accordingly. We have also calculated the frequency shift of photons in this space-time. Further, the mass parameter of a noncommutative inspired Schwarzschild black hole is computed in terms of the measurable redshift of photons emitted by massive particles moving along circular geodesics in equatorial plane. The strength of gravitational fields of noncommutative geometry-inspired Schwarzschild black hole and usual Schwarzschild black hole in General Relativity is also compared.
40 CFR Table 6 to Subpart Vvvv of... - Default Organic HAP Contents of Petroleum Solvent Groups
Code of Federal Regulations, 2010 CFR
2010-07-01
... Spirits 150 EC, Naphtha, Mixed Hydrocarbon, Aliphatic Hydrocarbon, Aliphatic Naptha, Naphthol Spirits... Aromatic Naphtha, Light Aromatic Hydrocarbons, Aromatic Hydrocarbons, Light Aromatic Solvent.) 6 4% Xylene...
NASA Astrophysics Data System (ADS)
Mini, S.; Sadasivan, V.; Meena, S. S.; Bhatt, Pramod
2014-10-01
Two new mono nuclear Fe(III) complexes of an azodye (ANSN) and a Schiff base (FAHP) are reported. The azodye is prepared by coupling diazotized 1-amino-2-naphthol-4-sulphonicacid with 2-naphthol and the Schiff base is prepared by condensing 2-amino-3-hydroxy pyridine with furfural. The complexes were synthesized by the reaction of FeCl3˙2H2O with respective ligands. They were characterized on the basis of elemental analysis and spectral studies like IR, NMR, Electronic and M.ssbauer. Magnetic susceptibility and Molar conductance of complexes at room temperature were studied. Based on the spectroscopic evidences and other analytical data the complexes are formulated as[Fe(ANSN)Cl(H2O)2] and [Fe(FAHP)Cl2(H2O)2].
NASA Astrophysics Data System (ADS)
Fleisher, Adam J.; Young, Justin W.; Pratt, David W.
2010-06-01
An understanding of the structure and internal dynamics of water attached to the photoacid β-naphthol is attainable through rotationally resolved electronic spectroscopy. Here, we present rotational constants for the 1:1 acid-base cluster in both S0 and S1, which provide the location of water within the cluster, as well as the barrier height to internal rotation of water in each electronic state. The barrier height decreases slightly upon excitation, from 206 wn in S0, to 182 wn in S1. There is also little evidence of a large change in water location, orientation, or overall hydrogen bond length upon irradiation with UV light. Thus, a single water molecule has relatively little affect on the substrate photo-acidity measured in the liquid phase.
NASA Astrophysics Data System (ADS)
Miyan, Lal; Khan, Ishaat M.; Ahmad, Afaq
2015-07-01
The charge transfer (CT) complex of 1,2-dimethylimidazole (DMI) as an electron donor with π acceptor 2,4-dinitro-1-naphthol (DNN) has been studied spectrophotometrically in different solvents like chloroform, acetonitrile, methanol, methylene chloride, etc. at room temperature. The CT complex which is formed through the transfer of lone pair electrons from DMI to DNN exhibits well resolved CT bands and the regions of these bands were remarkably different from those of the donor and acceptor. The stoichiometry of the CT complex was found to be 1:1 by a straight-line method between donor and acceptor with maximum absorption bands. The novel CT complex has been characterized by FTIR, TGA-DTA, powder XRD, 1H NMR and 13C NMR spectroscopic techniques. The Benesi-Hildebrand equation has been used to determine the formation constant (KCT), molar extinction coefficient (εCT), standard gibbs free energy (ΔG°) and other physical parameters of the CT complex. The formation constant recorded higher values and molar extinction coefficient recorded lower values in chloroform compared with methylene chloride, methanol and acetonitrile, confirming the strong interaction between the molecular orbital's of donor and acceptor in the ground state in less polar solvent. This CT complex has been studied by absorption spectra of donor 1,2-dimethylimidazole (DMI) and acceptor 2,4-dinitro-1-naphthol (DNN) by using the spectrophotometric technique in various solvents at room temperature.
Abolhasani, Jafar; Behbahani, Mohammad
2015-01-01
Solid-phase extraction is one the most useful and efficient techniques for sample preparation, purification, cleanup, preconcentration, and determination of heavy metals at trace levels. In this paper, functionalized MCM-48 nanoporous silica with 1-(2-pyridylazo)-2-naphthol was applied for trace determination of copper, lead, cadmium, and nickel in water and seafood samples. The experimental conditions such as pH, sample and eluent flow rate, type, concentration and volume of the eluent, breakthrough volume, and effect of coexisting ions were optimized for efficient solid-phase extraction of trace heavy metals in different water and seafood samples. The content of solutions containing the mentioned heavy metals was determined by flame atomic absorption spectrometry (FAAS), and the limits of detection were 0.3, 0.4, 0.6, and 0.9 ng mL(-1) for cadmium, copper, nickel, and lead, respectively. Recoveries and precisions were >98.0 and <4%, respectively. The adsorption capacity of the modified nanoporous silica was 178 mg g(-1) for cadmium, 110 mg g(-1) for copper, 98 mg g(-1) for nickel, and 210 mg g(-1) for lead, respectively. The functionalized MCM-48 nanoporous silica with 1-(2-pyridylazo)-2-naphthol was characterized by thermogravimetry analysis (TGA), differential thermal analysis (DTA), transmission electron microscopy (TEM), Fourier transform infrared spectrometry (FT-IR), X-ray diffraction (XRD), elemental analysis (CHN), and N2 adsorption surface area measurement.
Nanothermodynamics Applied to Thermal Processes in Heterogeneous Materials
2012-08-03
models agree favorably with a wide range of measurements of local thermal and dynamic properties. Progress in understanding basic thermodynamic...Monte- Carlo (MC) simulations of the Ising model .7 The solid black lines in Fig. 4 show results using the uncorrected (Metropolis) algorithm on the...parameter g=0.5 (green, dash-dot), g=1 (black, solid ), and g=2 (blue, dash-dot-dot). Note the failure of the standard Ising model (g=0) to match
36 CFR 294.29 - List of designated Idaho Roadless Areas.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 019 X X Boise Bear Wallow 125 X X Boise Bernard 029 X X Boise Black Lake 036 X X Boise Blue Bunch 923... Meadows 027 X X Boise Ten Mile/Black Warrior 013 X X X X Boise Tennessee 033 X X Boise Whiskey 031 X Boise...-Spring Creek 111 X X X X Caribou Gibson 181 X X Caribou Hell Hole 168 X X Caribou Huckleberry Basin 165 X...
A Facile Approach to Prepare Black TiO2 with Oxygen Vacancy for Enhancing Photocatalytic Activity
Chen, Shihao; Xiao, Yang; Hu, Zhengfa; Zhao, Hui; Xie, Wei
2018-01-01
Black TiO2 has triggered worldwide research interest due to its excellent photocatalytic properties. However, the understanding of its structure–property relationships and a more effective, facile and versatile method to produce it remain great challenges. We have developed a facile approach to synthesize black TiO2 nanoparticles with significantly improved light absorption in the visible and infrared regions. The experimental results show that oxygen vacancies are the major factors responsible for black coloration. More importantly, our black TiO2 nanoparticles have no Ti3+ ions. These oxygen vacancies could introduce localized states in the bandgap and act as trap centers, significantly decreasing the electron–hole recombination. The photocatalytic decomposition of both rhodamine B and methylene blue demonstrated that, under ultraviolet light irradiation, better photocatalytic performance is achieved with our black TiO2 nanoparticles than with commercial TiO2 nanoparticles. PMID:29659500
Preheating and entropy perturbations in axion monodromy inflation
DOE Office of Scientific and Technical Information (OSTI.GOV)
McDonough, Evan; Moghaddam, Hossein Bazrafshan; Brandenberger, Robert H.
2016-05-04
We study the preheating of gauge fields in a simple axion monodromy model and compute the induced entropy perturbations and their effect on the curvature fluctuations. We find that the correction to the spectrum of curvature perturbations has a blue spectrum with index n{sub s}=5/2. Hence, these induced modes are harmless for the observed structure of the universe. Since the spectrum is blue, there is the danger of overproduction of primordial black holes. However, we show that the observational constraints are easily satisfied.
7 CFR 51.2740 - Minor defects.
Code of Federal Regulations, 2012 CFR
2012-01-01
... discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight...
7 CFR 51.2720 - Minor defects.
Code of Federal Regulations, 2011 CFR
2011-01-01
... which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight yellow...
7 CFR 51.2762 - Minor defects.
Code of Federal Regulations, 2010 CFR
2010-01-01
... discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight...
7 CFR 51.2740 - Minor defects.
Code of Federal Regulations, 2010 CFR
2010-01-01
... discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight...
7 CFR 51.2740 - Minor defects.
Code of Federal Regulations, 2011 CFR
2011-01-01
... discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight...
7 CFR 51.2720 - Minor defects.
Code of Federal Regulations, 2012 CFR
2012-01-01
... which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight yellow...
7 CFR 51.2762 - Minor defects.
Code of Federal Regulations, 2012 CFR
2012-01-01
... discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight...
7 CFR 51.2762 - Minor defects.
Code of Federal Regulations, 2011 CFR
2011-01-01
... discoloration which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight...
7 CFR 51.2720 - Minor defects.
Code of Federal Regulations, 2010 CFR
2010-01-01
... which is dark brown, dark gray, dark blue or black and covers more than one-fourth of the surface; (b) Flesh discoloration which is darker than a light yellow color or consists of more than a slight yellow...
Public response to bridge colors.
DOT National Transportation Integrated Search
1973-01-01
To determine people's reactions to bridges painted in colors as white, yellow, green, blue, red, brown, black, and aluminum, two test bridges were selected in Charlottesville, Virginia. One was painted a different color each month and the other was k...
Okumura, Tetsu; Kondo, Hisayoshi; Nagayama, Hitomi; Makino, Toshiro; Yoshioka, Toshiharu; Yamamoto, Yasuhiro
2007-01-01
The efficiency and speed with which first responders, paramedics, and emergency physicians respond to an event caused by the release of a chemical is an important concern in all modern cities worldwide. A system for the initial triage and decontamination of victims of a chemical release was developed using colored clothes pegs of the following seven colors: red, yellow, green, black, white, and blue. Red indicates the need for emergency care, yellow for semi-emergency care, green for non-emergency care, black for expectant, white for dry decontamination, and blue for wet decontamination. The system can be employed as one of the techniques directed at improving the efficiency of decontamination in countries where there is a risk of chemical releases. It is recommended that this system should be adopted internationally and used for both drills and actual events.
Doping-stabilized two-dimensional black phosphorus.
Xuan, Xiaoyu; Zhang, Zhuhua; Guo, Wanlin
2018-05-03
Two-dimensional (2D) black phosphorus (BP) has attracted broad interests but remains to be synthesized. One of the issues lies in its large number of 2D allotropes with highly degenerate energies, especially 2D blue phosphorus. Here, we show that both nitrogen and hole-carrier doping can lift the energy degeneracy and locate 2D BP in a deep global energy minimum, while arsenic doping favours the formation of 2D blue phosphorus, attributed to a delicate interplay between s-p overlapping and repulsion of lone pairs. Chemically inert substrates, e.g. graphene and hexagonal boron nitride, can be synergic with carrier doping to stabilize the BP further over other 2D allotropes, while frequently used metal substrates severely reduce the stability of 2D BP. These results not only offer new insight into the structural stability of 2D phosphorus but also suggest a promising pathway towards the chemical synthesis of 2D BP.
Colours’ Impact on Morality: Evidence from Event-related Potentials
Gan, Tian; Fang, Wei; Ge, Liezhong
2016-01-01
Black and white have been shown to be representations of moral concepts. The purpose of this study was to investigate whether colours other than black and white have similar effects on words related to morality and to determine the time course of these effects. We presented moral and immoral words in three colours (red, green and blue) in a Moral Stroop task and used the event-related potential (ERP) technique to identify the temporal dynamics of the impact of colours on moral judgement. The behavioural results showed that it took longer for people to judge immoral words than moral words when the words were coloured green than when they were red or blue. The ERP results revealed the time course of these effects. Three stages were identified in the significant effects of P200, N300 and LPC. These findings suggest a metaphorical association between the colour green and moral information. PMID:28004749
The brain's dress code: How The Dress allows to decode the neuronal pathway of an optical illusion.
Schlaffke, Lara; Golisch, Anne; Haag, Lauren M; Lenz, Melanie; Heba, Stefanie; Lissek, Silke; Schmidt-Wilcke, Tobias; Eysel, Ulf T; Tegenthoff, Martin
2015-12-01
Optical illusions have broadened our understanding of the brain's role in visual perception. A modern day optical illusion emerged from a posted photo of a striped dress, which some perceived as white and gold and others as blue and black. Here we show, using functional magnetic resonance imaging (fMRI), that those who perceive The Dress as white/gold have higher activation in response to the image of The Dress in brain regions critically involved in higher cognition (frontal and parietal brain areas). These results are consistent with theories of top-down modulation and present a neural signature associated with the differences in perceiving The Dress as white/gold or blue/black. Furthermore the results support recent psychophysiological data on this phenomenon and provide a fundamental building block to study interindividual differences in visual processing. Copyright © 2015 Elsevier Ltd. All rights reserved.
Earth observations taken from shuttle orbiter Columbia
1995-10-21
STS073-723-054 (21 October 1995) --- Central Turkey dominates this north-looking panorama, with the long fingered island of Cyprus lower left, surrounded by the deep blue waters of the Mediterranean Sea. Turkey's capital, Ankara, lies just north of the white bed of a dry lake in the center of the view. The city is supplied with water from the neighboring blue lake. The coast of Syria and Lebanon appear bottom right. Man-made lakes on the upper Euphrates River in eastern Turkey appear extreme right. According to scientists studying the STS-73 photo collection, the striking difference in visibility to north and south of Turkey suggests a pollution event over the Black Sea. Air pollution from East European industry flows down into the Black Sea basin, especially at the west end (haze top left) as shown in this view (compare clearer air top right).
Sorption Behavior of Dye Compounds onto Natural Sediment of Qinghe River.
Liu, Ruixia; Liu, Xingmin; Tang, Hongxiao; Su, Yongbo
2001-07-15
The objective of this study is to assess the adsorption behavior of C.I. Basic Yellow X-5GL, C.I. Basic Red 13, C.I. Direct Blue 86, C.I. Vat Yellow 2, and C.I. Mordant Black 11 on natural sediment and to identify sediment characteristics that play a predominant role in the adsorption of the dyes. The potentiometric titration experiment is used to investigate acid-base properties of the sediment surface with a constant capacitance surface complexation model. The parameters controlling the sorption such as solution pH and ion strength, as well as the influence of organic carbon and Ca(2+) ion on the adsorption, are evaluated. It is shown that the titration data can be successfully described by the surface protonation and deprotonation model with the least-squares FITEQL program 2.0. The sorption isotherm data are fitted to the Freundlich equation in a nonlinear form (1/n=0.3-0.9) for all tested dyes. With increasing pH value, the sorption of C.I. Mordant Black 11 and C.I. Direct Blue 86 on the sediment decreases, while for C.I. Basic Yellow X-5GL and C.I. Basic Red 13, the extent of sorption slightly increases. In addition, ion strength also exhibits a considerably different effect on the sorption behavior of these dye compounds. The addition of Ca(2+) can greatly reduce the sorption of C.I. Basic Red 13 on the sediment surface, while it enhances the sorption of C.I. Direct Blue 6. The removal of organic carbon decreases the sorption of C.I. Mordant Black 11 and C.I. Direct Blue 86. In contrast, the sorption of C.I. Basic Red 13 and C.I. Basic Yellow X-5GL is obviously enhanced after the removal of organic carbon. The differences in adsorption behavior are mainly attributed to the physicochemical properties of these dye compounds. Copyright 2001 Academic Press.
Abdel-Aal, El-Sayed M; Akhtar, Humayoun; Rabalski, Iwona; Bryan, Michael
2014-02-01
Anthocyanins are important dietary components with diverse positive functions in human health. This study investigates effects of accelerated solvent extraction (ASE) and microwave-assisted extraction (MAE) on anthocyanin composition and extraction efficiency from blue wheat, purple corn, and black rice in comparison with the commonly used solvent extraction (CSE). Factorial experimental design was employed to study effects of ASE and MAE variables, and anthocyanin extracts were analyzed by spectrophotometry, high-performance liquid chromatography-diode array detector (DAD), and liquid chromatography-mass spectrometry chromatography. The extraction efficiency of ASE and MAE was comparable with CSE at the optimal conditions. The greatest extraction by ASE was achieved at 50 °C, 2500 psi, 10 min using 5 cycles, and 100% flush. For MAE, a combination of 70 °C, 300 W, and 10 min in MAE was the most effective in extracting anthocyanins from blue wheat and purple corn compared with 50 °C, 1200 W, and 20 min for black rice. The anthocyanin composition of grain extracts was influenced by the extraction method. The ASE extraction method seems to be more appropriate in extracting anthocyanins from the colored grains as being comparable with the CSE method based on changes in anthocyanin composition. The method caused lower structural changes in anthocaynins compared with the MAE method. Changes in blue wheat anthocyanins were lower in comparison with purple corn or black rice perhaps due to the absence of acylated anthocyanin compounds in blue wheat. The results show significant differences in anthocyanins among the 3 extraction methods, which indicate a need to standardize a method for valid comparisons among studies and for quality assurance purposes. © 2014 Her Majesty the Queen in Right of Canada Journal of Food Science © 2014 Institute of Food Technologists® Reproduced with the permission of the Minister of Agriculture and Agri-Food Canada.
Decolorization of textile dyes in an air-lift bioreactor inoculated with Bjerkandera adusta OBR105.
Sodaneath, Hong; Lee, Jung-In; Yang, Seung-Ok; Jung, Hyekyeng; Ryu, Hee Wook; Cho, Kyung-Suk
2017-09-19
A new decolorizing white-rot fungus, OBR105, was isolated from Mount Odae in South Korea and identified by the morphological characterization of its fruit body and spores and partial 18s rDNA sequences. The ligninolytic enzyme activity of OBR105 was studied to characterize their decolorizing mechanism using a spectrophotometric enzyme assay. For the evaluation of the decolorization capacity of OBR105, the isolate was incubated in an erlenmeyer flask and in an airlifte bioreator with potato dextrose broth (PDB) medium supplemented with each dye. In addition, the decolorization efficiency of real textile wastewater was evaluated in an airlift bioreactor inoculated with the isolate. The isolate was identified as Bjerkandera adusta and had ligninolytic enzymes such as laccase, lignin peroxidase (LiP), and Mn-dependent peroxidase (MnP). Its LiP activity was higher than its MnP and laccase activities. B. adusta OBR105 successfully decolorized reactive dyes (red 120, blue 4, orange 16, and black 5) and acid dyes (red 114, blue 62, orange 7, and black 172). B. adusta OBR105 decolorized 91-99% of 200 mg L -1 of each dye (except acid orange 7) within 3 days in a PDB medium at 28°C, pH 5, and 150 rpm. This fungus decolorized only 45% of 200 mg L -1 acid orange 7 (single azo-type dye) within 3 days, and the decolorization efficiency did not increase by prolonging the cultivation time. In the air-lift bioreactor, B. adusta OBR105 displayed a high decolorization capacity, greater than 90%, for 3 acid dyes (red 114, blue 62, and black 172) and 1 reactive dye (blue 4) within 10-15 h of treatment. B. adusta OBR105 could decolorize real textile wastewater in the air-lift bioreactor. This result suggests that an air-lift reactor employing B. adusta OBR105 is a promising bioreactor for the treatment of dye wastewater.
Kynol/Nomex Fabrics for Fire Retardant Shipboard Utility Uniforms
1988-06-01
changes shade permanentlj" from grey to black. The activation temperature of each set ranged from 220 F to 2800F in increments of 100F. The response of the...temperature value. When a tape reaches its activation temperature it changes shade permanent l from grey to black. The activation temperature of each...are normally only available in their natural gold color, to a suitable blue shade . g. Potential cost of Kynol/Nomex uniforms versus the FRT cotton
Numerical Relativity Simulations of Compact Binary Populations in Dense Stellar Environments
NASA Astrophysics Data System (ADS)
Glennon, Derek Ray; Huerta, Eliu; Allen, Gabrielle; Haas, Roland; Seidel, Edward; NCSA Gravity Group
2018-01-01
We present a catalog of numerical relativity simulations that describe binary black hole mergers on eccentric orbits. These simulations have been obtained with the open source, Einstein Toolkit numerical relativity software, using the Blue Waters supercomputer. We use this catalog to quantify observables, such as the mass and spin of black holes formed by binary black hole mergers, as a function of eccentricity. This study is the first of its kind in the literature to quantify these astrophysical observables for binary black hole mergers with mass-ratios q<6, and eccentricities e<0.2. This study is an important step in understanding the properties of eccentric binary black hole mergers, and informs the use of gravitational wave observations to confirm or rule out the existence of compact binary populations in dense stellar environments.
Black-on-white polymer-stabilized cholesteric formulations
NASA Astrophysics Data System (ADS)
West, John L.; Magyar, Gregory R.; Francl, James J.; Nixon, Christine M.
1995-08-01
Recent research by Doane, Yang, and Chien demonstrated the use of cholesteric liquid crystals in multiplexed, high resolution, reflective diplays. These materials utilize the bistability of the cholesteric planar and focal conic states for displays with a colored image on a black background. Many commercial applications of these materials, such as electronic books and newspapers, portable faxes and personal data assistants, require, or at least prefer, black-on- white images. We report on relatively high polymer content (equalsV 20% by weight) dispersions of cholesteric liquid crystals that produce a white, reflecting, planar state. The polymer network appears to form cholesteric domains with varying pitch lengths resulting in planar states that reflect in the red, green, and blue portions of the spectrum. Utilizing a black absorbing layer behind a display using these materials offers white images on a black background, or vice-versa.
Benelli, Giovanni; Otranto, Domenico; Caselli, Alice; Romano, Donato; Remorini, Damiano; Di Giuseppe, Graziano; Stefanini, Cesare; Mele, Marcello; Canale, Angelo
2018-06-01
Calliphora vomitoria is a myiasis-causing fly in many animal species including humans. The control of blowflies is still anchored on the use of chemicals. However, mass trapping and lure-and-kill techniques represent a promising alternative to pesticides. Visual and olfactory cues are the main stimuli routing the fly's landing behavior. Notably, color attractiveness has been barely explored in flies of medical and veterinary importance, with special reference to blowflies. In this study, we investigated the innate color preferences in C. vomitoria adults, testing binary combinations of painted targets under laboratory conditions. The identity of tested species C. vomitoria was confirmed by DNA sequencing (18S and cox1 genes). C. vomitoria flies showed a significant preference for black colored targets in all tested binary color combinations, after 5, 15, 30 and 60 min of exposure. Black targets were significantly preferred over blue, red, yellow and white ones. Spectral characteristics of all tested color combinations were quantified and the innate attraction of blowflies towards black targets was discussed in relation to their behavioral ecology. To the best of our knowledge, this is the first report on innate color preferences in the Calliphora genus. Our findings can be useful to develop new, cheap and reliable monitoring traps as well as "lure and kill" tools to control blowfly pests. Copyright © 2018 Elsevier B.V. All rights reserved.
Involvement of Two Plasmids in the Degradation of Carbaryl by Arthrobacter sp. Strain RC100
Hayatsu, Masahito; Hirano, Motoko; Nagata, Tadahiro
1999-01-01
A bacterium capable of utilizing carbaryl (1-naphthyl N-methylcarbamate) as the sole carbon source was isolated from carbaryl-treated soil. This bacterium was characterized taxonomically as Arthrobacter and was designated strain RC100. RC100 hydrolyzes the N-methylcarbamate linkage to 1-naphthol, which was further metabolized via salicylate and gentisate. Strain RC100 harbored three plasmids (designated pRC1, pRC2, and pRC3). Mutants unable to degrade carbaryl arose at a high frequency after treating the culture with mitomycin C. All carbaryl-hydrolysis-deficient mutants (Cah−) lacked pRC1, and all 1-naphthol-utilization-deficient mutants (Nat−) lacked pRC2. The plasmid-free strain RC107 grew on gentisate as a carbon source. These two plasmids could be transferred to Cah− mutants or Nat− mutants by conjugation, resulting in the restoration of the Cah and Nah phenotypes. PMID:10049857
Starvin, A M; Rao, T Prasada
2004-09-10
As a part of removal of toxic heavy metals from hazardous wastes, solid phase extraction (SPE) of mercury(II) at trace and ultra trace levels was studied using 1-(2-thiazolylazo)-2-naphthol (TAN) functionalized activated carbon (AC). The SPE material removes traces of mercury(II) quantitatively in the pH range 6.0 +/- 0.2. Other parameters that influence quantitative recovery of mercury(II), viz. percent concentration of TAN in AC, amount of TAN-AC, preconcentration time and volume of aqueous phase were varied and optimized. The possible means of removal of Hg(II) from other metal ions that are likely to be present in the wastes of the chloroalkali industry is discussed. The potential of TAN-functionalized AC SPE material for decontaminating mercury from the brine sludge and cell house effluent of a chloralkali plant has been evaluated.
Determination of traces of cobalt in soils: A field method
Almond, H.
1953-01-01
The growing use of geochemical prospecting methods in the search for ore deposits has led to the development of a field method for the determination of cobalt in soils. The determination is based on the fact that cobalt reacts with 2-nitroso-1-naphthol to yield a pink compound that is soluble in carbon tetrachloride. The carbon tetrachloride extract is shaken with dilute cyanide to complex interfering elements and to remove excess reagent. The cobalt content is estimated by comparing the pink color in the carbon tetrachloride with a standard series prepared from standard solutions. The cobalt 2-nitroso-1-naphtholate system in carbon tetrachloride follows Beer's law. As little as 1 p.p.m. can be determined in a 0.1-gram sample. The method is simple and fast and requires only simple equipment. More than 40 samples can be analyzed per man-day with an accuracy within 30% or better.
Ali, S Tahir; Antonov, Liudmil; Fabian, Walter M F
2014-01-30
Tautomerization energies of a series of isomeric [(4-R-phenyl)azo]naphthols and the analogous Schiff bases (R = N(CH3)2, OCH3, H, CN, NO2) are calculated by LPNO-CEPA/1-CBS using the def2-TZVPP and def2-QZVPP basis sets for extrapolation. The performance of various density functionals (B3LYP, M06-2X, PW6B95, B2PLYP, mPW2PLYP, PWPB95) as well as MP2 and SCS-MP2 is evaluated against these results. M06-2X and SCS-MP2 yield results close to the LPNO-CEPA/1-CBS values. Solvent effects (CCl4, CHCl3, CH3CN, and CH3OH) are treated by a variety of bulk solvation models (SM8, IEFPCM, COSMO, PBF, and SMD) as well as explicit solvation (Monte Carlo free energy perturbation using the OPLSAA force field).
Van Wyk, Ilana C; Boomker, Joop
2011-11-10
Little work has been conducted on the helminth parasites of artiodactylids in the northern and western parts of the Limpopo province, which is considerably drier than the rest of the province. The aim of this study was to determine the kinds and numbers of helminth that occur in different wildlife hosts in the area as well as whether any zoonotic helminths were present. Ten impalas (Aepyceros melampus), eight kudus (Tragelaphus strepsiceros), four blue wildebeest (Connochaetes taurinus), two black wildebeest (Connochaetes gnou), three gemsbok (Oryx gazella), one nyala (Tragelaphus angasii), one bushbuck (Tragelaphus scriptus), one waterbuck (Kobus ellipsiprymnus), six warthogs (Phacochoerus aethiopicus) and a single bushpig (Potamochoerus porcus) were sampled from various localities in the semi-arid northern and western areas of the Limpopo province. New host-parasite associations included Trichostrongylus deflexus from blue wildebeest, Agriostomum gorgonis from black wildebeest, Stilesia globipunctata from the waterbuck and Fasciola hepatica in a kudu. The mean helminth burden, including extra-gastrointestinal helminths, was 592 in impalas, 407 in kudus and blue wildebeest, 588 in black wildebeest, 184 in gemsbok, and 2150 in the waterbuck. Excluding Probstmayria vivipara, the mean helminth burden in warthogs was 2228 and the total nematode burden in the bushpig was 80. The total burdens and species richness of the helminths in this study were consistently low when compared with similar studies on the same species in areas with higher rainfall. This has practical implications when animals are translocated to areas with higher rainfall and higher prevalence of helminths.
Decolorization of acid, disperse and reactive dyes by Trametes versicolor CBR43.
Yang, Seung-Ok; Sodaneath, Hong; Lee, Jung-In; Jung, Hyekyeng; Choi, Jin-Hee; Ryu, Hee Wook; Cho, Kyung-Suk
2017-07-29
The mycoremediation has been considered as a promising method for decolorizing dye wastewater. To explore new bioresource for mycoremediation, a new white-rot fungus that could decolorize various dyes commonly used in textile industries was isolated, and its ligninolytic enzyme activity and decolorization capacity were characterized. The isolated CBR43 was identified as Trametes versicolor based on the morphological properties of its fruit body and spores, as well as through partial 18S rDNA gene sequences. Isolated CBR43 displayed high activities of laccase and Mn-dependent peroxidase, whereas its lignin peroxidase activity was relatively low. These ligninolytic enzyme activities in potato dextrose broth (PDB) medium were enhanced by the addition of yeast extract (1-10 g L -1 ). In particular, lignin peroxidase activity was increased more than 5 times in the PDB medium amended with 10 g L -1 of yeast extract. The CBR43 decolorized more than 90% of 200 mg L -1 acid dyes (red 114, blue 62 and black 172) and reactive dyes (red 120, blue 4, orange 16 and black 5) within 6 days in the PDB medium. CBR43 decolorized 67% of 200 mg L -1 acid orange 7 within 9 days. The decolorization efficiencies for disperse dyes (red 1, orange 3 and black 1) were 51-80% within 9 days. The CBR43 could effectively decolorize high concentrations of acid blue 62 and acid black 172 (500-700 mg L -1 ). The maximum dye decolorization rate was obtained at 28°C, pH 5, and 150 rpm in the PDB medium. T. versicolor CBR43 had high laccase and Mn-dependent peroxidase activities, and could decolorize a wide variety of dyes such as acid, disperse and reactive textile dyes. This fungus had decolorizing activities of azo-type dyes as well as anthraquinone-type dyes. T. versicolor CBR43 is one of promising bioresources for the decolorization of textile wastewater including various dyes.
Evaluation of window-tinting films for sunlight phototherapy.
Vreman, Hendrik J; Slusher, Tina M; Wong, Ronald J; Schulz, Stephanie; Olusanya, Bolajoko O; Stevenson, David K
2013-12-01
We evaluated nine semi-transparent plastic window-tinting films for their ability to block ultraviolet A (UVA) and infrared (IR) radiation and transmit therapeutic blue light (400-520 nm) for treating jaundiced newborns. For indoor testing, three light sources (TL/52 special blue fluorescent, Black Light UVA and IR heat lamps) were positioned above each film and measured successively using a thermocouple thermometer, UVA radiometer and blue light irradiance meter, placed below each film. For outdoor testing, the same setup was used with the sun at zenith and a cloudless sky. Compared with unfiltered radiation, blue light transmission through films ranged from 24 to 83%, UVA transmission was 0.1-7.1% and reductions in IR heat were 6-12°C and 5-10°C for heat lamp and sun, respectively. The data suggest that most of the relatively low-cost window-tinting films tested can effectively reduce sunlight UV and IR and offer a range of significant attenuations of therapeutic blue light.
Big Black Holes Mean Bad News for Stars (diagram)
NASA Technical Reports Server (NTRS)
2006-01-01
[figure removed for brevity, see original site] Poster Version Suppression of Star Formation from Supermassive Black Holes This diagram illustrates research from NASA's Galaxy Evolution Explorer showing that black holes -- once they reach a critical size -- can put the brakes on new star formation in elliptical galaxies. In this graph, galaxies and their supermassive black holes are indicated by the drawings (the black circle at the center of each galaxy represents the black hole). The relative masses of the galaxies and their black holes are reflected in the sizes of the drawings. Blue indicates that the galaxy has new stars, while red means the galaxy does not have any detectable new stars. The Galaxy Evolution Explorer observed the following trend: the biggest galaxies and black holes (shown in upper right corner) are more likely to have no observable star formation (red) than the smaller galaxies with smaller black holes. This is evidence that black holes can create environments unsuitable for stellar birth. The white line in the diagram illustrates that, for any galaxy no matter what the mass, its black hole must reach a critical size before it can shut down star formation.40 CFR 82.110 - Form of label bearing warning statement.
Code of Federal Regulations, 2012 CFR
2012-07-01
... contrast are: black letters on a dark blue or dark green background, dark red letters on a light red background, light red letters on a reflective silver background, and white letters on a light gray or tan...
24 CFR 1710.102 - General instructions for completing the Statement of Record.
Code of Federal Regulations, 2014 CFR
2014-04-01
... type of uniform font in blue, black or blueblack ink. (b) Numbering and dating. Each page of the... the light of circumstances under which they are made. (2) The instructions are not all inclusive. The...
24 CFR 1710.102 - General instructions for completing the Statement of Record.
Code of Federal Regulations, 2012 CFR
2012-04-01
... of uniform font in blue, black or blueblack ink. (b) Numbering and dating. Each page of the Statement... the light of circumstances under which they are made. (2) The instructions are not all inclusive. The...
24 CFR 1710.102 - General instructions for completing the Statement of Record.
Code of Federal Regulations, 2013 CFR
2013-04-01
... type of uniform font in blue, black or blueblack ink. (b) Numbering and dating. Each page of the... the light of circumstances under which they are made. (2) The instructions are not all inclusive. The...
24 CFR 1710.102 - General instructions for completing the Statement of Record.
Code of Federal Regulations, 2011 CFR
2011-04-01
... of uniform font in blue, black or blueblack ink. (b) Numbering and dating. Each page of the Statement... the light of circumstances under which they are made. (2) The instructions are not all inclusive. The...
40 CFR 82.110 - Form of label bearing warning statement.
Code of Federal Regulations, 2013 CFR
2013-07-01
... contrast are: black letters on a dark blue or dark green background, dark red letters on a light red background, light red letters on a reflective silver background, and white letters on a light gray or tan...
Solar Array and Earth Observation
2013-09-07
ISS036-E-047951 (7 Sept. 2013) --- Backdropped by a blue and white part of Earth and the blackness of space, International Space Station solar array panels are featured in this image photographed by an Expedition 36 crew member aboard the station.
2010-06-29
ISS024-E-007103 (29 June 2010) --- Backdropped by a blue and white part of Earth and the blackness of space, International Space Station solar array panels are featured in this image photographed by an Expedition 24 crew member aboard the station.
Incidence of nest material kleptoparasitism invlovling cerulean warblers
Kelly C. Jones; Kirk L. Roth; Kamal Islam; Paul B. Hamel; Carl G. III Smith
2007-01-01
document 21 observations of interspecific stealing of nesting material involving Cerulean Warblers (Dendroica cerulea), Red-eyed Vireos (Vireo olivaceus/i>), Blue-gray Gnatcatchers (Polioptila caerulea/i>), Northern Parulas (Parula americana/i>), Black-throated Green Warblers (D. virens), American Redstarts (
Uranium deposits in Grant County, New Mexico
Granger, Harry C.; Bauer, Herman L.; Lovering, Tom G.; Gillerman, Elliot
1952-01-01
The known uranium deposits of Grant county, N. Mex., are principally in the White Signal and Black Hawk districts. Both districts are within a northwesterly-trending belt of pre-Cambrian rocks, composed chiefly of granite with included gneisses, schists, and quartzites. Younger dikes and stocks intrude the pre-Cambrian complex. The White Signal district is on the southeast flanks of the Burro Mountains; the Black Hawk district is about 18 miles northwest of the town of White Signal. In the White Signal district the seconday uranium phosphates--autunite and torbernite--occur as fracture coatings and disseminations in oxidized parts of quartz-pyrite veins, and in the adjacent mafic dikes and granites; uraniferous limonite is common locally. Most of the known uraniferous deposits are less that 50 feet in their greatest dimension. The most promising deposits in the district are on the Merry Widow and Blue Jay claims. The richest sample taken from the Merry Widow mine contained more than 2 percent uranium and a sample from the Blue Jay property contained as much as 0.11 percent; samples from the other properties were of lower grade. In the Black Hawk district pitchblende is associated with nickel, silver, and cobalt minerals in fissure veins. The most promising properties in the Black Hawk district are the Black Hawk, Alhambra, and Rose mines. No uranium analyses from this district were available in 1951. There are no known minable reserves of uranium ore in either district, although there is some vein material at the Merry Widow mine of ore grade, if a market were available in the region.
Karacan, C. Özgen
2015-01-01
Coal seam degasification and its efficiency are directly related to the safety of coal mining. Degasification activities in the Black Warrior basin started in the early 1980s by using vertical boreholes. Although the Blue Creek seam, which is part of the Mary Lee coal group, has been the main seam of interest for coal mining, vertical wellbores have also been completed in the Pratt, Mary Lee, and Black Creek coal groups of the Upper Pottsville formation to degasify multiple seams. Currently, the Blue Creek seam is further degasified 2–3 years in advance of mining using in-seam horizontal boreholes to ensure safe mining. The studied location in this work is located between Tuscaloosa and Jefferson counties in Alabama and was degasified using 81 vertical boreholes, some of which are still active. When the current long mine expanded its operation into this area in 2009, horizontal boreholes were also drilled in advance of mining for further degasification of only the Blue Creek seam to ensure a safe and a productive operation. This paper presents an integrated study and a methodology to combine history matching results from vertical boreholes with production modeling of horizontal boreholes using geostatistical simulation to evaluate spatial effectiveness of in-seam boreholes in reducing gas-in-place (GIP). Results in this study showed that in-seam wells' boreholes had an estimated effective drainage area of 2050 acres with cumulative production of 604 MMscf methane during ~2 years of operation. With horizontal borehole production, GIP in the Blue Creek seam decreased from an average of 1.52 MMscf to 1.23 MMscf per acre. It was also shown that effective gas flow capacity, which was independently modeled using vertical borehole data, affected horizontal borehole production. GIP and effective gas flow capacity of coal seam gas were also used to predict remaining gas potential for the Blue Creek seam. PMID:26435557
Karacan, C Özgen
2013-07-30
Coal seam degasification and its efficiency are directly related to the safety of coal mining. Degasification activities in the Black Warrior basin started in the early 1980s by using vertical boreholes. Although the Blue Creek seam, which is part of the Mary Lee coal group, has been the main seam of interest for coal mining, vertical wellbores have also been completed in the Pratt, Mary Lee, and Black Creek coal groups of the Upper Pottsville formation to degasify multiple seams. Currently, the Blue Creek seam is further degasified 2-3 years in advance of mining using in-seam horizontal boreholes to ensure safe mining. The studied location in this work is located between Tuscaloosa and Jefferson counties in Alabama and was degasified using 81 vertical boreholes, some of which are still active. When the current long mine expanded its operation into this area in 2009, horizontal boreholes were also drilled in advance of mining for further degasification of only the Blue Creek seam to ensure a safe and a productive operation. This paper presents an integrated study and a methodology to combine history matching results from vertical boreholes with production modeling of horizontal boreholes using geostatistical simulation to evaluate spatial effectiveness of in-seam boreholes in reducing gas-in-place (GIP). Results in this study showed that in-seam wells' boreholes had an estimated effective drainage area of 2050 acres with cumulative production of 604 MMscf methane during ~2 years of operation. With horizontal borehole production, GIP in the Blue Creek seam decreased from an average of 1.52 MMscf to 1.23 MMscf per acre. It was also shown that effective gas flow capacity, which was independently modeled using vertical borehole data, affected horizontal borehole production. GIP and effective gas flow capacity of coal seam gas were also used to predict remaining gas potential for the Blue Creek seam.
Inoshima, Yasuo; Ishiguro, Naotaka
2015-01-01
Temperature-stability of loop-mediated isothermal amplification (LAMP) reagents was determined for their use in on-site diagnosis, such as in farms/pastures. Bst and Csa DNA polymerases and the reagents that were stored at different temperatures (4 or 25°C) for 1, 2, or 4 days were used for the LAMP assay to detect orf virus DNA as a model. After storage at 4 and 25°C for 2 days, the enzymes and reagents were found to retain sufficient activity to carry out successful DNA amplification. Visual diagnosis was also possible with the reagents (Loopamp Fluorescent Detection Reagent or hydroxy naphthol blue, as well as DNA amplification checker, D-Quick) that were stored for 2 days at different temperatures. Although the time taken to obtain the positive/negative results were delayed, the enzymes and reagents, stored at 25°C for 4 days, were active and had the ability to efficiently amplify DNA in less than 50 min. These results indicate that LAMP assay can be successfully utilized for the diagnosis of infectious diseases under non-clinical settings such as for on-site diagnosis in farms/pastures, owing to the fact that the relevant enzymes and reagents does not require restricted temperature storage.
Chen, Xiaoyun; Wang, Xiaofu; Jin, Nuo; Zhou, Yu; Huang, Sainan; Miao, Qingmei; Zhu, Qing; Xu, Junfeng
2012-11-07
Genetically modified (GM) rice KMD1, TT51-1, and KF6 are three of the most well known transgenic Bt rice lines in China. A rapid and sensitive molecular assay for risk assessment of GM rice is needed. Polymerase chain reaction (PCR), currently the most common method for detecting genetically modified organisms, requires temperature cycling and relatively complex procedures. Here we developed a visual and rapid loop-mediated isothermal amplification (LAMP) method to amplify three GM rice event-specific junction sequences. Target DNA was amplified and visualized by two indicators (SYBR green or hydroxy naphthol blue [HNB]) within 60 min at an isothermal temperature of 63 °C. Different kinds of plants were selected to ensure the specificity of detection and the results of the non-target samples were negative, indicating that the primer sets for the three GM rice varieties had good levels of specificity. The sensitivity of LAMP, with detection limits at low concentration levels (0.01%−0.005% GM), was 10- to 100-fold greater than that of conventional PCR. Additionally, the LAMP assay coupled with an indicator (SYBR green or HNB) facilitated analysis. These findings revealed that the rapid detection method was suitable as a simple field-based test to determine the status of GM crops.
Sun, Jian-Nan; Chen, Juan; Shi, Yan-Ping
2014-07-01
A new mode of ionic liquid based dispersive liquid-liquid microextraction (IL-DLLME) is developed. In this work, [C6MIm][PF6] was chosen as the extraction solvent, and two kinds of hydrophilic ionic liquids, [EMIm][BF4] and [BSO3HMIm][OTf], functioned as the dispersive solvent. So in the whole extraction procedure, no organic solvent was used. With the aid of SO3H group, the acidic compound was extracted from the sample solution without pH adjustment. Two phenolic compounds, namely, 2-naphthol and 4-nitrophenol were chosen as the target analytes. Important parameters affecting the extraction efficiency, such as the type of hydrophilic ionic liquids, the volume ratio of [EMIm][BF4] to [BSO3HMIm][OTf], type and volume of extraction solvent, pH value of sample solution, sonication time, extraction time and centrifugation time were investigated and optimized. Under the optimized extraction conditions, the method exhibited good sensitivity with the limits of detection (LODs) at 5.5 μg L(-1)and 10.0 μg L(-1) for 4-nitrophenol and 2-naphthol, respectively. Good linearity over the concentration ranges of 24-384 μg L(-1) for 4-nitrophenol and 28-336 μg L(-1) for 2-naphthol was obtained with correlation coefficients of 0.9998 and 0.9961, respectively. The proposed method can directly extract acidic compound from environmental sample or even more complex sample matrix without any pH adjustment procedure. Copyright © 2014 Elsevier B.V. All rights reserved.
Selenium-mediated synthesis of biaryls through rearrangement.
Shahzad, Sohail A; Vivant, Clotilde; Wirth, Thomas
2010-03-19
A new cyclization of beta-keto ester substituted stilbene derivatives using selenium electrophiles in the presence of Lewis acids is described. Substituted naphthols are obtained through cyclization and subsequent 1,2-rearrangement of aryl groups under very mild reaction conditions.
Bionanomaterials and Bioinspired Nanostructures for Selective Vapor Sensing
2013-04-03
with the current baseline shown with yellow points. DNA sequence: 5′ GAG TCT GTG GAG GAG GTA GTC 3′. Green and black arrows in panels a–c show the...SWCNT transducer to TNT (red circles), RDX ( gray triangles), and HPT (black squares). Blue arrows in panels b and c show introduction of analyte vapors...increasing partial pressure ranging from 0 to 0.07 P/P0. Vapor concentrations are 0 ( gray dashed lines), 0.02 (red curves), 0.04 ( gold curves), and 0.07
49 CFR 1152.10 - System diagram map.
Code of Federal Regulations, 2010 CFR
2010-10-01
... described in § 1152.10(b)(2); (3) Yellow shall designate those lines described in § 1152.10(b)(3); (4) Brown shall designate those lines described in § 1152.10(b)(4); and (5) Black or dark blue shall designate...
Identification of oleoresin in epoxy-embedded slash pine tissue
DOE Office of Scientific and Technical Information (OSTI.GOV)
Birchem, R.; Brown, C.L.
1978-01-01
Sudan black B stains oleoresin blue-black in epoxy-embedded material as well as in living tissue. The Sudan black B staining properties of oleoresin are similar to those of lipid, but it can be distinguished from tannin, which stains brown. Practically all oleoresin present in resin ducts and intercellular spaces, and much of that contained in epithelial and ray cells, is extracted in preparatory procedures for electron microscopy. A fixation procedure is proposed which preserves significantly more oleoresin in situ. The use of Sudan black B enables one to localize oleoresin by light microscopy, and permits direct comparison of adjacent sectionsmore » of epoxy-embedded material at the ultrastructure level. Ultrastructurally oleoresin and lipid possess similar electron densities and can be distinguished from the highly electron-opaque tannin deposits.« less
Magnetic Origin of Black Hole Winds Across the Mass Scale
NASA Technical Reports Server (NTRS)
Fukumura, Keigo; Kazanas, Demosthenes; Shrader, Chris; Behar, Ehud; Tombesi, Francesco; Contopoulos, Ioannis
2017-01-01
Black hole accretion disks appear to produce invariably plasma outflows that result in blue-shifted absorption features in their spectra. The X-ray absorption-line properties of these outflows are quite diverse, ranging in velocity from non-relativistic (approx. 300 km/sec) to sub-relativistic (approx. 0.1c where c is the speed of light) and a similarly broad range in the ionization states of the wind plasma. We report here that semi-analytic, self-similar magnetohydrodynamic (MHD) wind models that have successfully accounted for the X-ray absorber properties of supermassive black holes, also fit well the high-resolution X-ray spectrum of the accreting stellar-mass black hole, GRO J1655-40. This provides an explicit theoretical argument of their MHD origin (aligned with earlier observational claims) and supports the notion of a universal magnetic structure of the observed winds across all known black hole sizes.
2002-03-29
KENNEDY SPACE CENTER, FLA. -- An immature -- therefore white -- Little Blue Heron (center, with black bill) joins Roseate Spoonbills and a pair of Great Egrets in a lake near Kennedy Space Center. The heron ranges along the east coast of the United States, from New York to Texas, inland to Oklahoma. It winters from South Carolina to South America. For habitat the Little Blue Heron prefers freshwater swamps and lagoons in the South, coastal thickets on islands in the North. The species is often observed in large mixed concentrations of herons and egrets
Huang, Kuo-Chen; Chiu, Tsai-Lan
2007-04-01
This study investigated the effects of color combinations for the figure/icon background, icon shape, and line width of the icon border on visual search performance on a liquid crystal display screen. In a circular stimulus array, subjects had to search for a target item which had a diameter of 20 cm and included one target and 19 distractors. Analysis showed that the icon shape significantly affected search performance. The correct response time was significantly shorter for circular icons than for triangular icons, for icon borders with a line width of 3 pixels than for 1 or 2 pixels, and for 2 pixels than for 1 pixel. The color combination also significantly affected the visual search performance: white/yellow, white/blue, black-red, and black/ yellow color combinations for the figure/icon background had shorter correct response times compared to yellow/blue, red/green, yellow/green, and blue/red. However, no effects were found for the line width of the icon border or the icon shape on the error rate. Results have implications for graphics-based design of interfaces, such as for mobile phones, Web sites, and PDAs, as well as complex industrial processes.
Mayr, Susanne; Buchner, Axel
2010-07-01
Participants performed a word-non-word discrimination task within a car control display emulated on a thin film transistor liquid-crystal display (TFT-LCD). The task simulated an information read-out from a TFT-LCD-based instrument panel. Subsequently, participants performed a low-contrast object detection task that simulated the detection of objects during night-time driving. In experiment 1, words/non-words were presented black-on-white (positive polarity) or white-on-black (negative polarity). In experiments 2 and 3, display colour was additionally manipulated. A positive polarity advantage in the discrimination task was consistently observed. In contrast, positive displays interfered more than negative displays with subsequent detection. The detrimental after-effect of positive polarity displays was strong with white and blue, reduced with amber and absent with red displays. Subjective measures showed a preference for blue over red, but a slight advantage for amber over blue. Implications for TFT-LCD design are derived from the results. STATEMENT OF RELEVANCE: When using TFT-LCDs as car instrument panels, positive polarity red TFT-LCDs are very likely to lead to good instrument readability while at the same time minimising - relative to other colours - the negative effects of an illuminated display on low-contrast object detection during night-time driving.
... per day (fasting or pre-breakfast, pre-lunch, pre-dinner, and bedtime). The straight black line shows an A1C measurement of 7.0 percent. The blue line shows an example of how blood glucose test results might look from self-monitoring four times ...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gardner, G.R.; Yevich, P.P.; Malcolm, A.R.
1991-01-01
The eastern oyster (Crassostrea virginica) developed neoplastic disorders when experimentally exposed both in the laboratory and field to chemically contaminated sediment from Black Rock Harbor (BRH), Bridgeport, Connecticut. Neoplasia was observed in oysters after 30 or 60 days of continuous exposure in a laboratory flow-through system to a 20 mg/L suspension of BRH sediment plus postexposure periods of 3, 30, or 60 days. Composite tumor incidence was 13.6% for both exposures. Tumor occurrence was highest in the renal excretory epithelium, followed in order by gill, gonad, gastrointestinal, heart, and embryonic neural tissue. Regression of experimental neoplasia was not observed whenmore » the stimulus was discontinued. In field experiments, gill neoplasms developed in oysters, deployed in cages for 30 days at BRH and 36 days at a BRH dredge material disposal area in Central Long Island Sound, and kidney and gastrointestinal neoplasms developed in caged oysters deployed 40 days in Quincy Bay, Boston Harbor. Oysters exposed to BRH sediment in the laboratory and in the field accumulated high concentrations of polychlorinated biphenyls (PCBs), polyaromatic hydrocarbons (PAHs), and chlorinated pesticides. Chemical analyses demonstrated high concentrations of PCBs, PAHs, chlorinated pesticides, and heavy metals in BRH sediment. Known genotoxic carcinogens, cocarcinogens, and tumor promoters were present as contaminants. The uptake of parent PAH and PCBs from BRH sediment observed in oysters also occurs in blue mussels (Mytilus edulis). Winter flounder fed BRH-contaminated blue mussels contained xenobiotic chemicals analyzed in mussels. The flounder developed renal and pancreatic neoplasms and hepatotoxic neoplastic precursor lesions, demonstrating trophic transfer of sediment-bound carcinogens up the food chain.« less
History of Chandra X-Ray Observatory
2000-12-04
Chandra X-Ray Observatory provided this composite X-ray (blue and green) and optical (red) image of the active galaxy NGC 1068 showing gas blowing away in a high-speed wind from the vicinity of a central supermassive black hole. Regions of intense star formation in the irner spiral arms of the galaxy are highlighted by both optical and x-ray emissions. A doughnut shaped cloud of cool gas and dust surrounding the black hole, known as the torus, appears as the elongated white spot . It has has a mass of about 5 million suns and is estimated to extend from within a few light years of the black hole out to about 300 light years.
Colored Sticky Traps to Selectively Survey Thrips in Cowpea Ecosystem.
Tang, L D; Zhao, H Y; Fu, B L; Han, Y; Liu, K; Wu, J H
2016-02-01
The bean flower thrips, Megalurothrips usitatus (Bagrall) (Thysanoptera: Thripidae), is an important pest of legume crops in South China. Yellow, blue, or white sticky traps are currently recommended for monitoring and controlling thrips, but it is not known whether one is more efficient than the other or if selectivity could be optimized by trap color. We investigated the response of thrips and beneficial insects to different-colored sticky traps on cowpea, Vigna unguiculata. More thrips were caught on blue, light blue, white, and purple traps than on yellow, green, pink, gray, red, or black traps. There was a weak correlation on the number of thrips caught on yellow traps and survey from flowers (r = 0.139), whereas a strong correlation was found for blue traps and thrips' survey on flowers (r = 0.929). On commercially available sticky traps (Jiaduo®), two and five times more thrips were caught on blue traps than on white and yellow traps, respectively. Otherwise, capture of beneficial insects was 1.7 times higher on yellow than on blue traps. The major natural enemies were the predatory ladybird beetles (63%) and pirate bugs Orius spp. (29%), followed by a number of less representative predators and parasitoids (8%). We conclude the blue sticky trap was the best to monitor thrips on cowpea in South China.
A preferred mass range for primordial black hole formation and black holes as dark matter revisited
NASA Astrophysics Data System (ADS)
Georg, Julian; Watson, Scott
2017-09-01
Bird et al. [1] and Sasaki et al. [2] have recently proposed the intriguing possibility that the black holes detected by LIGO could be all or part of the cosmological dark matter. This offers an alternative to WIMPs and axions, where dark matter could be comprised solely of Standard Model particles. The mass range lies within an observationally viable window and the predicted merger rate can be tested by future LIGO observations. In this paper, we argue that non-thermal histories favor production of black holes near this mass range — with heavier ones unlikely to form in the early universe and lighter black holes being diluted through late-time entropy production. We discuss how this prediction depends on the primordial power spectrum, the likelihood of black hole formation, and the underlying model parameters. We find the prediction for the preferred mass range to be rather robust assuming a blue spectral index less than two. We consider the resulting relic density in black holes, and using recent observational constraints, establish whether they could account for all of the dark matter today.
Code of Federal Regulations, 2013 CFR
2013-01-01
.... (9) Lead oxide in the glass envelope of Black Light Blue (BLB) lamps. (e) Components of electronic devices that are removable or replaceable, such as battery packs and light bulbs that are inaccessible...
Code of Federal Regulations, 2012 CFR
2012-01-01
.... (9) Lead oxide in the glass envelope of Black Light Blue (BLB) lamps. (e) Components of electronic devices that are removable or replaceable, such as battery packs and light bulbs that are inaccessible...
Code of Federal Regulations, 2011 CFR
2011-01-01
.... (9) Lead oxide in the glass envelope of Black Light Blue (BLB) lamps. (e) Components of electronic devices that are removable or replaceable, such as battery packs and light bulbs that are inaccessible...
Code of Federal Regulations, 2014 CFR
2014-01-01
.... (9) Lead oxide in the glass envelope of Black Light Blue (BLB) lamps. (e) Components of electronic devices that are removable or replaceable, such as battery packs and light bulbs that are inaccessible...
NASA Technical Reports Server (NTRS)
2005-01-01
Ultraviolet image of NGC 5128 (Centaurus-A). This unusual galaxy is believed to be the result of a collision of two normal galaxies. The blue regions toward the top are thought to be areas of star formation induced by powerful jets originating from a central black hole.MASA's Ultra-Long Duration Balloon Project - Teaching an Old Dog New Tricks
NASA Technical Reports Server (NTRS)
Smith, I.; Cutts, J.
1999-01-01
The leviathan silently slides through the upper atmosphere of the blue planet, its eye steadily staring into the cold, dark recesses of deep space. Periodically the eye looks at different points in the blackness while processing the information it sees.
Quintard, Benoît; Giorgiadis, Marine; Feirrera, Xavier; Lefaux, Brice; Schohn, Christophe; Lemberger, Karin
2018-03-01
The blue-eyed black lemur (Eulemur flavifrons) is classified by the International Union for Conservation of Nature (IUCN) as critically endangered. A 23-year-old male housed at Mulhouse Zoo presented with lethargy, polyphagia, alopecia, and chronic weight loss. Clinical examination suggested an endocrine pathology such as hyperthyroidism. Secondary examinations included cervical ultrasound, thyroid biopsy, and scintigraphy. The latter revealed elevated thyroid activity. Blood analysis was performed to measure the level of anti-receptor thyroid-stimulating hormone antibodies, which allowed us to test the autoimmune hypothesis. The high level of antibodies together with levels of thyroid-stimulating hormone and the scintigraphy images led to the diagnosis of Grave's disease. Carbimazole treatment followed by thyroidectomy resulted in a quick weight gain and general improvement in health status. The following breeding season, the treated individual sired an offspring. To the authors' knowledge, this is the first report of likely Grave's disease in a non-human primate.
Carbon composite lignin-based adsorbents for the adsorption of dyes.
Wang, Xiaohong; Jiang, Chenglong; Hou, Bingxia; Wang, Yingying; Hao, Chen; Wu, Jingbo
2018-05-10
Carbon composite lignin-based adsorbent were prepared through hydrothermal method with glucose as carbon source, calcium lignosulfonate and triethylene tetramine as raw materials, respectively. The optimum synthesis conditions were determined by investigating the addition of carbon and triethylene tetramine. The adsorbent was used for the adsorption of azo dyes Congo red and Eriochrome blue black R, and the five factors affecting the adsorption were discussed, including pH of dyes, initial concentration, adsorption time, adsorption temperature and adsorbent dosage. The corresponding adsorption mechanism such as pseudo first order kinetics, pseudo second order kinetics, intraparticle diffusion, Langmuir adsorption isotherm, Freundlich isotherm, Temkin isotherm, Dubinin-Radushkevich adsorption isotherm, thermodynamics were also studied. When the dye concentration is 40 mg L -1 , Congo red and Eriochrome blue black R dye removal rates reach 99%. Moreover, the adsorption process of two kinds of dyes follow the pseudo second order kinetics and the Langmuir adsorption isotherm. Copyright © 2018 Elsevier Ltd. All rights reserved.
Zhang, Linlin; Mazo-Vargas, Anyi; Reed, Robert D
2017-10-03
The optix gene has been implicated in butterfly wing pattern adaptation by genetic association, mapping, and expression studies. The actual developmental function of this gene has remained unclear, however. Here we used CRISPR/Cas9 genome editing to show that optix plays a fundamental role in nymphalid butterfly wing pattern development, where it is required for determination of all chromatic coloration. optix knockouts in four species show complete replacement of color pigments with melanins, with corresponding changes in pigment-related gene expression, resulting in black and gray butterflies. We also show that optix simultaneously acts as a switch gene for blue structural iridescence in some butterflies, demonstrating simple regulatory coordination of structural and pigmentary coloration. Remarkably, these optix knockouts phenocopy the recurring "black and blue" wing pattern archetype that has arisen on many independent occasions in butterflies. Here we demonstrate a simple genetic basis for structural coloration, and show that optix plays a deeply conserved role in butterfly wing pattern development.
Oonincx, D G A B; Volk, N; Diehl, J J E; van Loon, J J A; Belušič, G
2016-12-01
Mating in the black soldier fly (BSF) is a visually mediated behaviour that under natural conditions occurs in full sunlight. Artificial light conditions promoting mating by BSF were designed based on the spectral characteristics of the compound eye retina. Electrophysiological measurements revealed that BSF ommatidia contained UV-, blue- and green-sensitive photoreceptor cells, allowing trichromatic vision. An illumination system for indoor breeding based on UV, blue and green LEDs was designed and its efficiency was compared with illumination by fluorescent tubes which have been successfully used to sustain a BSF colony for five years. Illumination by LEDs and the fluorescent tubes yielded equal numbers of egg clutches, however, the LED illumination resulted in significantly more larvae. The possibilities to optimize the current LED illumination system to better approximate the skylight illuminant and potentially optimize the larval yield are discussed. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Liu, Zhaojun; Han, Yunxia; Han, Ligang; Cheng, Yongjian; Ma, Yiqiang; Fang, Li
2013-05-01
The pigments on the painted pottery figurines from two tombs of Northern Wei Dynasty (AD 386-534) in Luoyang were analyzed by Raman microscopy. All the pigments were identified compared with the Raman spectra of standard pigments. The red pigments were identified as haematite, the blue pigment as lapis lazuli, the green pigment as malachite, the black pigment as carbon black and the white pigment as calcite. Similar pigments were used in the two tombs despite the pottery figurines were very different in artistic style. The use of lapis lazuli as blue pigment on Chinese painted pottery figurines was found for the first time. This pigment and the painted pottery figurine of Sogdians are of great archaeological significance because it demonstrated that the trade and cultural exchanges via the Silk Road had extended to Luoyang city in the Northern Wei Dynasty. The result also confirms that micro-Raman spectroscopy is a powerful analytical method for the identification of pigments on ancient artworks.
Classical lepidopteran wing scale colouration in the giant butterfly-moth Paysandisia archon.
Stavenga, Doekele G; Leertouwer, Hein L; Meglič, Andrej; Drašlar, Kazimir; Wehling, Martin F; Pirih, Primož; Belušič, Gregor
2018-01-01
The palm borer moth Paysandisia archon (Castniidae; giant butterfly-moths) has brown dorsal forewings and strikingly orange-coloured dorsal hindwings with white spots surrounded by black margins. Here, we have studied the structure and pigments of the wing scales in the various coloured wing areas, applying light and electron microscopy and (micro)spectrophotometry, and we analysed the spatial reflection properties with imaging scatterometry. The scales in the white spots are unpigmented, those in the black and brown wing areas contain various amounts of melanin, and the orange wing scales contain a blue-absorbing ommochrome pigment. In all scale types, the upper lamina acts as a diffuser and the lower lamina as a thin film interference reflector, with thickness of about 200 nm. Scale stacking plays an important role in creating the strong visual signals: the colour of the white eyespots is created by stacks of unpigmented blue scales, while the orange wing colour is strongly intensified by stacking the orange scales.
Mediaeval cantorals in the Valladolid Biblioteca: FT-Raman spectroscopic study.
Edwards, H G; Farwell, D W; Rull Perez, F; Medina Garcia, J
2001-03-01
Raman spectroscopic studies of three mediaeval cantorals in the Biblioteca of the University of Valladolid has revealed information about the pigments used on these large manuscripts. Although executed in a simple colour palette, very pure cinnabar was used as the major colourant, offsetting the carbon black of the verses and script. A dark blue colour was achieved using a mixture of azurite (basic copper carbonate) and carbon, whereas a light blue colour was azurite alone. A grey colour was achieved using azurite, carbon particles and a calcareous 'limewash'. A yellow pigment, used sparely in the cantorals was ascribed to saffron; unusually, there was no evidence for the presence of the yellow mineral pigments orpiment, realgar and massicot. In several regions of the vellum specimens, evidence for biodeterioration was observed through the signatures of hydrated calcium oxalate. We report for the first time the Raman spectra of pigment in situ on a vellum fragment, which also shows evidence of substrate bands; comparison of black and red pigmented regions of vellum specimens has shown the presence of calcium oxalate in the black pigmented script but not in the red pigment regions, which suggests that the cinnabar in the red-pigmented regions acts as a toxic protectant for the vellum substrate against biological colonisation processes.
Development of a cyclic voltammetry method for the detection of Clostridium novyi in black disease.
Liu, L L; Jiang, D N; Xiang, G M; Liu, C; Yu, J C; Pu, X Y
2014-03-17
Black disease is an acute disease of sheep and cattle. The pathogen is the obligate anaerobe, Clostridium novyi. Due to difficulties of anaerobic culturing in the country or disaster sites, a simple, rapid, and sensitive method is required. In this study, an electrochemical method, the cyclic voltammetry method, basing on loop-mediated isothermal amplification (LAMP), electrochemical ion bonding (positive dye, methylene blue), was introduced. DNA extracted from C. novyi specimens was amplified through the LAMP reaction. Then the products combined were with methylene blue, which lead to a reduction in the oxidation peak current (ipA) and the reduction peak current (ipC) of the cyclic voltammetry. The changes of ipA/ipC were real-time measured by special designed electrode, so the DNA was quantitatively detected. The results displayed that this electrochemical detection of C. novyi could be completed in 1-2 h with the lowest bacterial concentration of 10(2) colony forming units/mL, and high accuracy (96.5%), sensitivity (96%), and specificity (97%) compared to polymerase chain reation. The cyclic voltammetry method was a simple and fast method, with high sensitivity and high specificity, and has great potential to be a usable molecular tool for fast diagnosis of Black disease.
Divergent discourse between protests and counter-protests: #BlackLivesMatter and #AllLivesMatter.
Gallagher, Ryan J; Reagan, Andrew J; Danforth, Christopher M; Dodds, Peter Sheridan
2018-01-01
Since the shooting of Black teenager Michael Brown by White police officer Darren Wilson in Ferguson, Missouri, the protest hashtag #BlackLivesMatter has amplified critiques of extrajudicial killings of Black Americans. In response to #BlackLivesMatter, other Twitter users have adopted #AllLivesMatter, a counter-protest hashtag whose content argues that equal attention should be given to all lives regardless of race. Through a multi-level analysis of over 860,000 tweets, we study how these protests and counter-protests diverge by quantifying aspects of their discourse. We find that #AllLivesMatter facilitates opposition between #BlackLivesMatter and hashtags such as #PoliceLivesMatter and #BlueLivesMatter in such a way that historically echoes the tension between Black protesters and law enforcement. In addition, we show that a significant portion of #AllLivesMatter use stems from hijacking by #BlackLivesMatter advocates. Beyond simply injecting #AllLivesMatter with #BlackLivesMatter content, these hijackers use the hashtag to directly confront the counter-protest notion of "All lives matter." Our findings suggest that Black Lives Matter movement was able to grow, exhibit diverse conversations, and avoid derailment on social media by making discussion of counter-protest opinions a central topic of #AllLivesMatter, rather than the movement itself.
NASA Astrophysics Data System (ADS)
Hurain, Syyeda Sana; Habib, Amir; Hussain, Syed Muzammil; Ul-Haq, Noaman
2015-11-01
Nanosized titania (TiO2) films and powders were prepared from titanium isopropoxide by ultrasonication then ultrasonic aerosol-assisted chemical vapor deposition (UAACVD). X-ray diffraction (XRD), used to study the crystal structure, phase, and crystallite size of TiO2 samples annealed at 500°C, revealed anatase was the main crystalline phase. Scanning electron microscopy and atomic force microscopy revealed the quasi-spherical morphology of the TiO2 nanoparticles; average size distribution was in the range 20-35 nm. Ultraviolet-visible spectroscopy was used to evaluate the photocatalytic activity of the anatase TiO2, on the basis of efficiency of degradation of β-naphthol. Pure TiO2 nanoparticles synthesized by use of sonication-UAACVD then calcination at 500°C enabled effective photodegradation under UV light. This method of synthesis of TiO2 is superior to the reflux-UAACVD method with titanium isopropoxide as precursor.
Shamzhy, Mariya; Opanasenko, Maksym; Shvets, Oleksiy; Čejka, Jiří
2013-01-01
Catalytic behavior of isomorphously substituted B-, Al-, Ga-, and Fe-containing extra-large pore UTL zeolites was investigated in Knoevenagel condensation involving aldehydes, Pechmann condensation of 1-naphthol with ethylacetoacetate, and Prins reaction of β-pinene with formaldehyde and compared with large-pore aluminosilicate zeolite beta and representative Metal-Organic-Frameworks Cu3(BTC)2 and Fe(BTC). The yield of the target product over the investigated catalysts in Knoevenagel condensation increases in the following sequence: (Al)beta < (Al)UTL < (Ga)UTL < (Fe)UTL < Fe(BTC) < (B)UTL < Cu3(BTC)2 being mainly related to the improving selectivity with decreasing strength of active sites of the individual catalysts. The catalytic performance of Fe(BTC), containing the highest concentration of Lewis acid sites of the appropriate strength is superior over large-pore zeolite (Al)beta and B-, Al-, Ga-, Fe-substituted extra-large pore zeolites UTL in Prins reaction of β-pinene with formaldehyde and Pechmann condensation of 1-naphthol with ethylacetoacetate. PMID:24790940
Russell, Joanna; Singer, Brian W; Perry, Justin J; Bacon, Anne
2011-05-01
A collection of more than 70 synthetic organic pigments were analysed using pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS). We report on the analysis of diketo-pyrrolo-pyrrole, isoindolinone and perylene pigments which are classes not previously reported as being analysed by this technique. We also report on a number of azo pigments (2-naphthol, naphthol AS, arylide, diarylide, benzimidazolone and disazo condensation pigments) and phthalocyanine pigments, the Py-GC-MS analysis of which has not been previously reported. The members of each class were found to fragment in a consistent way and the pyrolysis products are reported. The technique was successfully applied to the analysis of paints used by the artist Francis Bacon (1909-1992), to simultaneously identify synthetic organic pigments and synthetic binding media in two samples of paint taken from Bacon's studio and micro-samples taken from three of his paintings and one painting attributed to him.
NASA Astrophysics Data System (ADS)
Huang, Y.; Shi, W.; Zhang, C.; Wen, H.
2017-09-01
For the determination of nitrogen oxides in the air, the structure of diazo and coupling compounds was studied and tested by experiments. The conditions and methods of diazo and coupling reactions were investigated. Furthermore, a spectrophotometric method using sulfanilamide as a diazo compound and 2-N-ethyl-5-naphthol-7-sulfonic acid (N-ethyl J acid) as a coupling compound was proposed. The maximum absorption wavelength of sulfanilamide-Nethyl J acid azo compound was at 478 nm. The molar absorptivity was 4.31 × 104 L/(mol × cm) with a recovery of 98.7-100.9% and RSD of 1.85%. For nitrogen oxides, the determinate limit of this measurement was 0.015 mg/m3 and the determinate range 0.024-2.0 mg/m3. Moreover, a high degree of correlation was observed between the results obtained by the proposed method and the standard methods. The proposed method can be easily applied to determine nitrogen oxides in the air.
2010-12-01
infrared (FTIR) spectroscopy Differential scanning calorimetry ( DSC ) L97A1/L96A1 grenades Thermogravimetric analysis (TGA) 16. SECURITY CLASSIFICATION OF...Spectroscopy The FTIR scan (fig. 3) shows two baseline materials • The blue spectra represent the Nylon 6 sample • The black spectra represent Nylon 6...The black spectra represent a sample taken from the body of the older grenade body • The relative size and location of all the peaks are identical
The micromorphology of Younger Dryas-aged black mats from Nevada, Arizona, Texas and New Mexico
NASA Astrophysics Data System (ADS)
Harris-Parks, Erin
2016-01-01
Black mats are organic-rich sediments and soils that form in wet environments associated with spring discharge. Micromorphological and geochemical analyses of 25 black mats dating to the Younger Dryas Chronozone (12.9-11.7 ka) and early Holocene were conducted to determine their composition and depositional environment. Samples were collected from Arizona, New Mexico, Texas and Nevada. Micromorphological analyses were conducted on thin sections using polarized and blue fluorescent light. These analyses determined that black mats contain humic acids, fine (5-20 μm) plant fragments, diatoms, phytoliths, and gastropods. The dominant type of organic matter in black mats is derived from herbaceous plants, contradicting previous studies that supported algal or charcoal sources. Differences in the micromorphological characteristics of the samples revealed that black mats formed as three different types, organic horizons, moist soils and, ponded sediments, depending on their topographic position in relation to the water table. The microscopic evidence found in black mats supports the presence of widespread wet environments in Nevada and Arizona during the Younger Dryas Chronozone, clearly indicating a sustained period of greater effective moisture, optimal for spring discharge and black mat formation.
Nielsen, Henrik Krarup; Garcia, Javier; Væth, Michael; Schlafer, Sebastian
2015-01-01
Photoactivated disinfection has a strong local antimicrobial effect. In the field of dentistry it is an emerging adjunct to mechanical debridement during endodontic and periodontal treatment. In the present study, we investigate the effect of photoactivated disinfection using riboflavin as a photosensitizer and blue LED light for activation, and compare it to photoactivated disinfection with the widely used combination of toluidine blue O and red light. Riboflavin is highly biocompatible and can be activated with LED lamps at hand in the dental office. To date, no reports are available on the antimicrobial effect of photoactivated disinfection using riboflavin/blue light on oral microorganisms. Planktonic cultures of eight organisms frequently isolated from periodontal and/or endodontic lesions (Aggregatibacter actinomycetemcomitans, Candida albicans, Enterococcus faecalis, Escherischia coli, Lactobacillus paracasei, Porphyromonas gingivalis, Prevotella intermedia and Propionibacterium acnes) were subjected to photoactivated disinfection with riboflavin/blue light and toluidine blue O/red light, and survival rates were determined by CFU counts. Within the limited irradiation time of one minute, photoactivated disinfection with riboflavin/blue light only resulted in minor reductions in CFU counts, whereas full kills were achieved for all organisms when using toluidine blue O/red light. The black pigmented anaerobes P. gingivalis and P. intermedia were eradicated completely by riboflavin/blue light, but also by blue light treatment alone, suggesting that endogenous chromophores acted as photosensitizers in these bacteria. On the basis of our results, riboflavin cannot be recommended as a photosensitizer used for photoactivated disinfection of periodontal or endodontic infections.
An Archeological Survey in the Gypsum Breaks on the Elm Fork of the Red River,
1979-01-01
Tamarix gallica salt cedar Salix nigra black willow Opuntia lindenheimeri prickly pear cactus* Artemisia filifolia sand sage Bouteloua gracilis blue...125 projectile points were recovered including Gary, Bonham, Hayes barbed, Alba barbed, knives, drills, scrapers, gouges, cores, grinding stones
Salience of Primary and Secondary Colours in Infancy
ERIC Educational Resources Information Center
Franklin, Anna; Pitchford, Nicola; Hart, Lynsey; Davies, Ian R. L.; Clausse, Samantha; Jennings, Siobhan
2008-01-01
Primary colour terms ("black", "white", "red", "green", "yellow", and "blue") are more fundamental in colour language than secondary colour terms ("pink", "purple", "orange", "brown", and "grey"). Here, we assess whether this distinction exists in the absence of language, by investigating whether primary colours attract and sustain preverbal…
Ozone exposure and stomatal sluggishness in different plant physiognomic classes
E. Paoletti; N.E. Grulke
2010-01-01
Gas exchange responses to static and variable light were tested in three species: snap bean (Phaseolus vulgaris, two cultivars), California black oak (Quercus kelloggii), and blue oak (Q. douglasii). The effects of 1-month (snap beans) and 2-month (oaks) O3 (ozone) exposure (70&...
16 CFR 309.20 - Labeling requirements for new covered vehicles.
Code of Federal Regulations, 2011 CFR
2011-01-01
... ACTS OF CONGRESS LABELING REQUIREMENTS FOR ALTERNATIVE FUELS AND ALTERNATIVE FUELED VEHICLES Requirements for Alternative Fueled Vehicles § 309.20 Labeling requirements for new covered vehicles. (a... printed in process black ink on Hammermill Offset Opaque Vellum/S.70 Sky Blue (or equivalent) paper. (e...
The North-South Earnings Gap: Changes during the 1960's and 1970's.
ERIC Educational Resources Information Center
Hirschman, Charles; Blankenship, Kim
1981-01-01
A study of earnings differences between northern and southern states shows that white-collar workers in both areas now receive roughly equal pay. Women, blacks and blue-collar workers in the South still receive significantly lower wages than their northern counterparts. (AM)
Jung, Kyung Hwa; Liu, Bian; Lovinsky-Desir, Stephanie; Yan, Beizhan; Camann, David; Sjodin, Andreas; Li, Zheng; Perera, Frederica; Kinney, Patrick; Chillrud, Steven; Miller, Rachel L
2014-05-01
Exposure to air pollutants including polycyclic aromatic hydrocarbons (PAH), and specifically pyrene from combustion of fuel oil, coal, traffic and indoor sources, has been associated with adverse respiratory health outcomes. However, time trends of airborne PAH and metabolite levels detected via repeat measures over time have not yet been characterized. We hypothesized that PAH levels, measured repeatedly from residential indoor and outdoor monitors, and children׳s urinary concentrations of PAH metabolites, would decrease following policy interventions to reduce traffic-related air pollution. Indoor PAH (particle- and gas-phase) were collected for two weeks prenatally (n=98), at age 5/6 years (n=397) and age 9/10 years (n=198) since 2001 and at all three age-points (n=27). Other traffic-related air pollutants (black carbon and PM2.5) were monitored indoors simultaneous with PAH monitoring at ages 5/6 (n=403) and 9/10 (n=257) between 2005 and 2012. One third of the homes were selected across seasons for outdoor PAH, BC and PM2.5 sampling. Using the same sampling method, ambient PAH, BC and PM2.5 also were monitored every two weeks at a central site between 2007 and 2012. PAH were analyzed as semivolatile PAH (e.g., pyrene; MW 178-206) (∑8PAH(semivolatile): Including pyrene (PYR), phenanthrene (PHEN), 1-methylphenanthrene (1-MEPH), 2-methylphenanthrene (2-MEPH), 3-methylphenanthrene (3-MEPH), 9-methylphenanthrene (9-MEPH), 1,7-dimethylphenanthrene (1,7-DMEPH), and 3,6-dimethylphenanthrene (3,6-DMEPH)) and the sum of eight nonvolatile PAH (∑8PAH(nonvolatile): Including benzo[a]anthracene (BaA), chrysene/iso-chrysene (Chry), benzo[b]fluoranthene (BbFA), benzo[k]fluoranthene (BkFA), benzo[a]pyrene (BaP), indeno[1,2,3-c,d]pyrene (IP), dibenzo[a,h]anthracene (DahA), and benzo[g,h,i]perylene (BghiP); MW 228-278). A spot urine sample was collected from children at child ages 3, 5, 7 and 9 between 2001 and 2012 and analyzed for 10 PAH metabolites. Modest declines were detected in indoor BC and PM2.5 levels between 2005 and 2012 (Annual percent change [APC]=-2.08% [p=0.010] and -2.18% [p=0.059] for BC and PM2.5, respectively), while a trend of increasing pyrene levels was observed in indoor and outdoor samples, and at the central site during the comparable time periods (APC=4.81%, 3.77% and 7.90%, respectively; p<0.05 for all). No significant time trend was observed in indoor ∑8PAH(nonvolatile) levels between 2005 and 2012; however, significant opposite trends were detected when analyzed seasonally (APC=-8.06% [p<0.01], 3.87% [p<0.05] for nonheating and heating season, respectively). Similarly, heating season also affected the annual trends (2005-2012) of other air pollutants: the decreasing BC trend (in indoor/outdoor air) was observed only in the nonheating season, consistent with dominating traffic sources that decreased with time; the increasing pyrene trend was more apparent in the heating season. Outdoor PM2.5 levels persistently decreased over time across the seasons. With the analyses of data collected over a longer period of time (2001-2012), a decreasing trend was observed in pyrene (APC=-2.76%; p<0.01), mostly driven by measures from the nonheating season (APC=-3.54%; p<0.01). In contrast, levels of pyrene and naphthalene metabolites, 1-hydroxypyrene and 2-naphthol, increased from 2001 to 2012 (APC=6.29% and 7.90% for 1-hydroxypyrene and 2-naphthol, respectively; p<0.01 for both). Multiple NYC legislative regulations targeting traffic-related air pollution may have led to decreases in ∑8PAH(nonvolatile) and BC, especially in the nonheating season. Despite the overall decrease in pyrene over the 2001-2012 periods, a rise in pyrene levels in recent years (2005-2012), that was particularly evident for measures collected during the heating season, and 2-naphthol, indicates the contribution of heating oil combustion and other indoor sources to airborne pyrene and urinary 2-naphthol. Copyright © 2014 Elsevier Inc. All rights reserved.
PHOTO MICROGRAPH - LUNAR SAMPE 10022
1969-08-28
S69-47900 (September 1969) --- This is a photo micrograph of lunar sample 10022. Magnification one inch equals one-tenth millimeter. The light blue and white mineral is plagioclase. The black is ilmenite, and the blue and/or green and/or orange and/or yellow and/or red mineral is pyroxene. The large pyroxene is a phenocryst that had been partially resorbed. The lunar samples collected by astronauts Neil A. Armstrong and Edwin E. Aldrin Jr. during the Apollo 11 lunar landing mission have been subjected to extensive tests and examinations at the Manned Spacecraft Center’s Lunar Receiving Laboratory.
AFM imaging of natural optical structures
NASA Astrophysics Data System (ADS)
Dallaeva, Dinara; Tománek, Pavel; Prokopyeva, Elena; Kaspar, Pavel; Grmela, Lubomír.; Škarvada, Pavel
2015-01-01
The colors of some living organisms assosiated with the surface structure. Irridesence butterfly wings is an example of such coloration. Optical effects such as interference, diffraction, polarization are responsible for physical colors appearance. Alongside with amazing beauty this structure represent interest for design of optical devices. Here we report the results of morphology investigation by atomic force microscopy. The difference in surface structure of black and blue wings areas is clearly observed. It explains the angle dependence of the wing blue color, since these micrometer and sub-micrometer quasiperiodical structures could control the light propagation, absorption and reflection.
Dermoscopic Clues for Diagnosing Melanomas That Resemble Seborrheic Keratosis
Segura, Sonia; Aguilera, Paula; Scalvenzi, Massimiliano; Longo, Caterina; Barreiro, Alicia; Broganelli, Paolo; Cavicchini, Stefano; Llambrich, Alex; Zaballos, Pedro; Thomas, Luc; Malvehy, Josep; Puig, Susana; Zalaudek, Iris
2017-01-01
Importance Melanomas that clinically mimic seborrheic keratosis (SK) can delay diagnosis and adequate treatment. However, little is known about the value of dermoscopy in recognizing these difficult-to-diagnose melanomas. Objective To describe the dermoscopic features of SK-like melanomas to understand their clinical morphology. Design, Setting, and Participants This observational retrospective study used 134 clinical and dermoscopic images of histopathologically proven melanomas in 134 patients treated in 9 skin cancer centers in Spain, France, Italy, and Austria. Without knowledge that the definite diagnosis for all the lesions was melanoma, 2 dermoscopy-trained observers evaluated the clinical descriptions and 48 dermoscopic features (including all melanocytic and nonmelanocytic criteria) of all 134 images and classified each dermoscopically as SK or not SK. The total dermoscopy score and the 7-point checklist score were assessed. Images of the lesions and patient data were collected from July 15, 2013, through July 31, 2014. Main Outcomes and Measures Frequencies of specific morphologic patterns of (clinically and dermoscopically) SK-like melanomas, patient demographics, and interobserver agreement of criteria were evaluated. Results Of the 134 cases collected from 72 men and 61 women, all of whom were white and who had a mean (SD) age of 55.6 (17.5) years, 110 (82.1%) revealed dermoscopic features suggestive of melanoma, including pigment network (74 [55.2%]), blue-white veil (72 [53.7%]), globules and dots (68 [50.7%]), pseudopods or streaks (47 [35.1%]), and blue-black sign (43 [32.3%]). The remaining 24 cases (17.9%) were considered likely SKs, even by dermoscopy. Overall, lesions showed a scaly and hyperkeratotic surface (45 [33.6%]), yellowish keratin (42 [31.3%]), comedo-like openings (41 [30.5%]), and milia-like cysts (30 [22.4%]). The entire sample achieved a mean (SD) total dermoscopy score of 4.7 (1.6) and a 7-point checklist score of 4.4 (2.3), while dermoscopically SK-like melanomas achieved a total dermoscopy score of only 4.2 (1.3) and a 7-point checklist score of 2.0 (1.9), both in the range of benignity. The most helpful criteria in correctly diagnosing SK-like melanomas were the presence of blue-white veil, pseudopods or streaks, and pigment network. Multivariate analysis found only the blue-black sign to be significantly associated with a correct diagnosis, while hyperkeratosis and fissures and ridges were independent risk markers of dermoscopically SK-like melanomas. Conclusions and Relevance Seborrheic keratosis–like melanomas can be dermoscopically challenging, but the presence of the blue-black sign, pigment network, pseudopods or streaks, and/or blue-white veil, despite the presence of other SK features, allows the correct diagnosis of most of the difficult melanoma cases. PMID:28355453
The effect of blue light on periodontal biofilm growth in vitro.
Fontana, Carla R; Song, Xiaoqing; Polymeri, Angeliki; Goodson, J Max; Wang, Xiaoshan; Soukos, Nikolaos S
2015-11-01
We have previously shown that blue light eliminates the black-pigmented oral bacteria Porphyromonas gingivalis, Prevotella intermedia, Prevotella nigrescens, and Prevotella melaninogenica. In the present study, the in vitro photosensitivity of the above black-pigmented microorganisms and four Fusobacteria species (Fusobacterium nucleatum ss. nucleatum, F. nucleatum ss. vincentii, F. nucleatum ss. polymorphum, Fusobacterium periodonticum) was investigated in pure cultures and human dental plaque suspensions. We also tested the hypothesis that phototargeting the above eight key periodontopathogens in plaque-derived biofilms in vitro would control growth within the dental biofilm environment. Cultures of the eight bacteria were exposed to blue light at 455 nm with power density of 80 mW/cm2 and energy fluence of 4.8 J/cm2. High-performance liquid chromatography (HPLC) analysis of bacteria was performed to demonstrate the presence and amounts of porphyrin molecules within microorganisms. Suspensions of human dental plaque bacteria were also exposed once to blue light at 455 nm with power density of 50 mW/cm2 and energy fluence of 12 J/cm2. Microbial biofilms developed from the same plaque were exposed to 455 nm blue light at 50 mW/cm2 once daily for 4 min (12 J/cm2) over a period of 3 days (4 exposures) in order to investigate the cumulative action of phototherapy on the eight photosensitive pathogens as well as on biofilm growth. Bacterial growth was evaluated using the colony-forming unit (CFU) assay. The selective phototargeting of pathogens was studied using whole genomic probes in the checkerboard DNA-DNA format. In cultures, all eight species showed significant growth reduction (p < 0.05). HPLC demonstrated various porphyrin patterns and amounts of porphyrins in bacteria. Following phototherapy, the mean survival fractions were reduced by 28.5 and 48.2% in plaque suspensions and biofilms, respectively, (p < 0.05). DNA probe analysis showed significant reduction in relative abundances of the eight bacteria as a group in plaque suspensions and biofilms. The cumulative blue light treatment suppressed biofilm growth in vitro. This may introduce a new avenue of prophylactic treatment for periodontal diseases.
Low cost synthesis of TiO2-C nanocomposite powder for high efficiency visible light photocatalysis
NASA Astrophysics Data System (ADS)
Mohapatra, A. K.; Nayak, J.
2018-04-01
Titanium dioxide-carbon nanocomposite powder was synthesized via a low cost chemical route using oleic acid and titanium tetra-isopropoxide. Since the carbon remained mainly on the surface of the TiO2 nanoparticles, the powder had black color. The composition of the powder was analyzed by X-ray photoelectron spectroscopy and the structure was studied with X-ray diffraction and transmission electron microscopy. The visible photocatalytic activity of the black TiO2 powder was investigated by studying the photo-bleaching of methylene blue under visible light. Our experimental observation showed that the black-TiO2 powder had a higher visible photocatalytic activity compared to the commercial TiO2 powder (P25 Degussa).
ERIC Educational Resources Information Center
Shurpik, Anton J.; Beim, Howard J.
1982-01-01
Discusses characteristics of materials and labels used by the Department of Transportation, including label design and color: red (flammable and spontaneously combustible), white/yellow (radioactives), orange (explosives), white (poisons), yellow (oxidizers), green (non-flammable gas), black/white (corrosive), blue (dangerous when wet). Includes…
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
2013-07-29
PHOTO DATE: 29 July 2013 LOCATION: Bldg. 9NW, Space Vehicle Mockup Training Facility - POGO SUBJECT: Expedition 42 crew member and astronaut Barry "Butch" Wilmore during ISS EVA POGO 1 training. Instructors Faruq Sabur (black shirt), Allissa Battocletti (red shirt), Sandy Fletcher (light blue shirt with glasses) and astronaut Shane Kimbrough assist. PHOTOGRAPHER: Mark Sowa
Grazing management for healthy watersheds
Karl Wood
2008-01-01
(Please note, this is an abstract only) New Mexico was historically grazed by many native and introduced ungulates, often called wildlife. Their distribution was limited especially in deserts until domestic animals were introduced and drinking water was provided. Plants respond to grazing with little resistance (black grama), to great resistance (blue grama), and to...
Jazz: An Afro-American Art Music.
ERIC Educational Resources Information Center
Griffin, Marie P.
1983-01-01
Discussion of roots of jazz--form of art music which originated in United States through confrontation of blacks with European music--highlights jazz styles and stylists, blues, ragtime, dixieland, big bands, bop, cool jazz, modern jazz, jazz recording, jazz discography, and jazz collection in the library. Thirty-four references are cited. (EJS)
ERIC Educational Resources Information Center
Wright, Stephen W.
2002-01-01
Presents an activity that uses supermarket chemicals to perform a clock reaction in which the endpoint is signaled by an abrupt change in the appearance from colorless to blue-black. This activity can be used to explore reaction kinetics and the effect of reactant concentrations on the apparent rate of reaction. (DDR)
Tian, Yue Yue; Zhang, Li Xia; Zhang, Zheng Qun; Qiao, Ming Ming; Fan, Yan Gen
2017-03-18
In order to ensure the suitable shade model for 'Huangjinya' tea plant in Shandong Province, black or blue shading net at 55%, 70% or 85% shading rates was selected to recover tea garden in summer and autumn, then micro-climate of tea garden, leaf color, chlorophyll fluorescence parameters, growth status and biochemical composition of tea shoots were investigated.The results showed that compared with the control, light intensity and air temperature in tea garden, leaf temperature of tea plants in different shading treatments significantly decreased, while air humidity in tea garden increased. The contents of chlorophyll in the tea leaves were obviously increased with increasing the shading rate, which resulted in the leaf color becoming green. The yellowing characteristics and biochemical quality of 'Huangjinya' tea plants could be well kept in 55% shading treatments. In 70% shading treatments, 'Huangjinya' tea plants had better growth situation and higher yield with no photo-inhibition. Compared with the blue shading treatments, black shading treatments could obviously promote the growth of 'Huangjinya' tea plants, keep yellowing characteristics, and improve the quality. Therefore, the 70% black shading treatment (daily PAR values of 1.2-3.5 ten thousand lx) was appropriate for promoting the growth of 'Huangjinya' tea plants at the seedling stage. For mature tea plants, the 55% black shading treatment (daily PAR values of 1.8-5.5 ten thousand lx) could be used to keep the yellowing characteristics and to improve biochemical quality effectively, so as to give full play to its variety characteristics, to achieve goal of high quality and high yield.
[Effect of ascorbic acid (vitamin C) on the EPR spectra from the black and red hair].
Chikvaidze, E; Miminoshvili, A; Gogoladze, T; Kiparoidze, S
2012-02-01
The EPR spectra of melanin's free radicals in natural black and red hair have been investigated. It is show that the EPR spectrum of black hair is slightly asymmetric singlet with g=2,0035 and ΔH=0,5 mTl. The EPR spectrum of red hair with g=2,0053 differs from the spectrum of black hair. Under the influence of visible (blue with λ(max)=450 nm) in both types of hair (black and red), the protoinduced free radicals appear, which indicates an increase in the intensity of already existing EPR spectrum of hair. It should be noted that the EPR spectra of red hair from various donors are different. The antioxidant ascorbic acid has the different effect on the photoinduced free radicals. In particular, in the case of black hair, the concentration of photoinduced free radicals is slightly reduced, whereas in red hair, the disappearance of the triplet in the spectrum is observed, and at the same time, the spectrum becomes a singlet, the intensity of which increases sharply.
The Illustris simulation: supermassive black hole-galaxy connection beyond the bulge
NASA Astrophysics Data System (ADS)
Mutlu-Pakdil, Burçin; Seigar, Marc S.; Hewitt, Ian B.; Treuthardt, Patrick; Berrier, Joel C.; Koval, Lauren E.
2018-02-01
We study the spiral arm morphology of a sample of the local spiral galaxies in the Illustris simulation and explore the supermassive black hole-galaxy connection beyond the bulge (e.g. spiral arm pitch angle, total stellar mass, dark matter mass, and total halo mass), finding good agreement with other theoretical studies and observational constraints. It is important to study the properties of supermassive black holes and their host galaxies through both observations and simulations and compare their results in order to understand their physics and formative histories. We find that Illustris prediction for supermassive black hole mass relative to pitch angle is in rather good agreement with observations and that barred and non-barred galaxies follow similar scaling relations. Our work shows that Illustris presents very tight correlations between supermassive black hole mass and large-scale properties of the host galaxy, not only for early-type galaxies but also for low-mass, blue and star-forming galaxies. These tight relations beyond the bulge suggest that halo properties determine those of a disc galaxy and its supermassive black hole.
Unusual satellite data: A black hole?. [International Ultraviolet Explorer observations
NASA Technical Reports Server (NTRS)
1978-01-01
Data obtained by the NASA-launched European Space Agency's International Ultraviolet Explorer satellite suggests the possibility of a massive black hole at the center of some globular clusters (star groups) in our galaxy. Six of these clusters, three of them X-ray sources, were closely examined. Onboard short wavelength UV instrumentation penetrated the background denseness of the clusters 15,000 light years away where radiation, probably from a group of 10 to 20 bright blue stars orbiting the core, was observed. The stars may well be orbiting a massive black hole the size of 1,000 solar systems. The existence of the black hole is uncertain. The dynamics of the stars must be studied first to determine how they rotate in relation to the center of the million-star cluster. This may better indicate what provides the necessary gravitational pull that holds them in orbit.
[Permanent tattoos following injections with Dermo-Jet: anatomoclinical study. Apropos of 5 cases].
Lachapelle, J M; Tennstedt, D; Burtonboy, G
1982-01-01
Blue or black tattoos were observed in five patients who had received several intradermal injections (of a lidocaine solution or of a triamcinolone acetonide suspension) with the Dermo-Jet. A histological examination revealed the presence of black masses, rounded or elongated, different in size, distributed throughout dermal tissue. Additionally, conglomerates of black grains in the cytoplasm of histiocytes and of pericytes are precisely observed in semi-thin sections. It has been proved by several investigations that these foreign particles are not of metallic nature. It can be concluded from electron microscopic studies that the particles are fragments of black rubber, from the upper joint of the reservoir. Indeed, some rubber fragments are leached into the reservoir. Some of these are passing through the wire-mesh filter of the nozzle (with the solution or the suspension) when injections are made. Therefore, they are injected intradermally and are permanently tattooing the skin.
Mahittikorn, Aongart; Mori, Hirotake; Popruk, Supaluk; Roobthaisong, Amonrattana; Sutthikornchai, Chantira; Koompapong, Khuanchai; Siri, Sukhontha; Sukthana, Yaowalark; Nacapunchai, Duangporn
2015-01-01
Naegleria fowleri is the causative agent of the fatal disease primary amebic meningoencephalitis. Detection of N. fowleri using conventional culture and biochemical-based assays is time-consuming and laborious, while molecular techniques, such as PCR, require laboratory skills and expensive equipment. We developed and evaluated a novel loop-mediated isothermal amplification (LAMP) assay targeting the virulence-related gene for N. fowleri. Time to results is about 90 min and amplification products were easily detected visually using hydroxy naphthol blue. The LAMP was highly specific after testing against related microorganisms and able to detect one trophozoite, as determined with spiked water and cerebrospinal fluid samples. The assay was then evaluated with a set of 80 water samples collected during the flooding crisis in Thailand in 2011, and 30 natural water samples from border areas of northern, eastern, western, and southern Thailand. N. fowleri was detected in 13 and 10 samples using LAMP and PCR, respectively, with a Kappa coefficient of 0.855. To the best of our knowledge, this is the first report of a LAMP assay for N. fowleri. Due to its simplicity, speed, and high sensitivity, the LAMP method described here might be useful for quickly detecting and diagnosing N. fowleri in water and clinical samples, particularly in resource-poor settings. PMID:25822175
Mahittikorn, Aongart; Mori, Hirotake; Popruk, Supaluk; Roobthaisong, Amonrattana; Sutthikornchai, Chantira; Koompapong, Khuanchai; Siri, Sukhontha; Sukthana, Yaowalark; Nacapunchai, Duangporn
2015-01-01
Naegleria fowleri is the causative agent of the fatal disease primary amebic meningoencephalitis. Detection of N. fowleri using conventional culture and biochemical-based assays is time-consuming and laborious, while molecular techniques, such as PCR, require laboratory skills and expensive equipment. We developed and evaluated a novel loop-mediated isothermal amplification (LAMP) assay targeting the virulence-related gene for N. fowleri. Time to results is about 90 min and amplification products were easily detected visually using hydroxy naphthol blue. The LAMP was highly specific after testing against related microorganisms and able to detect one trophozoite, as determined with spiked water and cerebrospinal fluid samples. The assay was then evaluated with a set of 80 water samples collected during the flooding crisis in Thailand in 2011, and 30 natural water samples from border areas of northern, eastern, western, and southern Thailand. N. fowleri was detected in 13 and 10 samples using LAMP and PCR, respectively, with a Kappa coefficient of 0.855. To the best of our knowledge, this is the first report of a LAMP assay for N. fowleri. Due to its simplicity, speed, and high sensitivity, the LAMP method described here might be useful for quickly detecting and diagnosing N. fowleri in water and clinical samples, particularly in resource-poor settings.
Reactivities of various mediators and laccases with kraft pulp and lignin model compounds.
Bourbonnais, R; Paice, M G; Freiermuth, B; Bodie, E; Borneman, S
1997-12-01
Laccase-catalyzed oxygen delignification of kraft pulp offers some potential as a replacement for conventional chemical bleaching and has the advantage of requiring much lower pressure and temperature. However, chemical mediators are required for effective delignification by laccase, and their price is currently too high at the dosages required. To date, most studies have employed laccase from Trametes versicolor. We have found significant differences in reactivity between laccases from different fungi when they are tested for pulp delignification in the presence of the mediators 2,2(prm1)-azinobis(3-ethylbenzthiazoline-6-sulfonate) (ABTS) and 1-hydroxybenzotriazole (HBT). A more detailed study of T. versicolor laccase with ABTS and HBT showed that HBT gave the most extensive delignification over 2 h but deactivated the enzyme, and therefore a higher enzyme dosage was required. Other mediators, including 1-nitroso-2-naphthol-3,6-disulfonic acid, 4-hydroxy-3-nitroso-1-naphthalenesulfonic acid, promazine, chlorpromazine, and Remazol brilliant blue, were also tested for their ability to delignify kraft pulp. Studies with dimeric model compounds indicated that the mechanisms of oxidation by ABTS and HBT are different. In addition, oxygen uptake by laccase is much slower with HBT than with ABTS. It is proposed that the dication of ABTS and the 1-oxide radical of HBT, with redox potentials in the 0.8- to 0.9-V range, are required for pulp delignification.
Reactivities of Various Mediators and Laccases with Kraft Pulp and Lignin Model Compounds
Bourbonnais, R.; Paice, M. G.; Freiermuth, B.; Bodie, E.; Borneman, S.
1997-01-01
Laccase-catalyzed oxygen delignification of kraft pulp offers some potential as a replacement for conventional chemical bleaching and has the advantage of requiring much lower pressure and temperature. However, chemical mediators are required for effective delignification by laccase, and their price is currently too high at the dosages required. To date, most studies have employed laccase from Trametes versicolor. We have found significant differences in reactivity between laccases from different fungi when they are tested for pulp delignification in the presence of the mediators 2,2(prm1)-azinobis(3-ethylbenzthiazoline-6-sulfonate) (ABTS) and 1-hydroxybenzotriazole (HBT). A more detailed study of T. versicolor laccase with ABTS and HBT showed that HBT gave the most extensive delignification over 2 h but deactivated the enzyme, and therefore a higher enzyme dosage was required. Other mediators, including 1-nitroso-2-naphthol-3,6-disulfonic acid, 4-hydroxy-3-nitroso-1-naphthalenesulfonic acid, promazine, chlorpromazine, and Remazol brilliant blue, were also tested for their ability to delignify kraft pulp. Studies with dimeric model compounds indicated that the mechanisms of oxidation by ABTS and HBT are different. In addition, oxygen uptake by laccase is much slower with HBT than with ABTS. It is proposed that the dication of ABTS and the 1-oxide radical of HBT, with redox potentials in the 0.8- to 0.9-V range, are required for pulp delignification. PMID:16535747
Merschat, Arthur J.; Bream, Brendan R.; Huebner, Matthew T.; Hatcher, Robert D.; Miller, Calvin F.
2017-01-01
Ion microprobe U-Pb zircon rim ages from 39 samples from across the accreted terranes of the central Blue Ridge, eastward across the Inner Piedmont, delimit the timing and spatial extent of superposed metamorphism in the southern Appalachian orogen. Metamorphic zircon rims are 10–40 µm wide, mostly unzoned, and dark gray to black or bright white in cathodoluminescence, and truncate and/or embay interior oscillatory zoning. Black unzoned and rounded or ovoid-shaped metamorphic zircon morphologies also occur. Th/U values range from 0.01 to 1.4, with the majority of ratios less than 0.1. Results of 206Pb/238U ages, ±2% discordant, range from 481 to 305 Ma. Clustering within these data reveals that the Blue Ridge and Inner Piedmont terranes were affected by three tectonothermal events: (1) 462–448 Ma (Taconic); (2) 395–340 Ma (Acadian and Neoacadian); and (3) 335–322 Ma, related to the early phase of the Alleghanian orogeny. By combining zircon rim ages with metamorphic isograds and other published isotopic ages, we identify the thermal architecture of the southern Appalachian orogen: juxtaposed and superposed metamorphic domains have younger ages to the east related to the marginward addition of terranes, and these domains can serve as a proxy to delimit terrane accretion. Most 462–448 Ma ages occur in the western and central Blue Ridge and define a continuous progression from greenschist to granulite facies that identifies the intact Taconic core. The extent of 462–448 Ma metamorphism indicates that the central Blue Ridge and Tugaloo terranes were accreted to the western Blue Ridge during the Taconic orogeny. Zircon rim ages in the Inner Piedmont span almost 100 m.y., with peaks at 395–385, 376–340, and 335–322 Ma, and delimit the Acadian-Neoacadian and Alleghanian metamorphic core. The timing and distribution of metamorphism in the Inner Piedmont are consistent with the Devonian to Mississippian oblique collision of the Carolina superterrane, followed by an early phase of Alleghanian metamorphism at 335–322 Ma (temperature >500 °C). The eastern Blue Ridge contains evidence of three possible tectonothermal events: ~460 Ma, 376–340 Ma, and ~335 Ma. All of the crystalline terranes of the Blue Ridge–Piedmont megathrust sheet were affected by Alleghanian metamorphism and deformation.
NASA Astrophysics Data System (ADS)
Košařová, Veronika; Hradil, David; Hradilová, Janka; Čermáková, Zdeňka; Němec, Ivan; Schreiner, Manfred
2016-03-01
Twenty one mock-up samples containing inorganic pigments primarily used at the turn of the 19th and 20th century were selected for comparative study and measured by micro-Raman and portable Raman spectrometers. They included pure grounds (chalk-based, earth-based and lithopone-based), grounds covered by resin-based varnish, and different paint layers containing mixtures of white, yellow, orange, red, green, blue and black pigments, usually in combination with white pigments (titanium, zinc and barium whites or chalk). In addition, ten micro-samples obtained from seven paintings of two world-famous modern painters Edvard Munch and František Kupka have been investigated. Infrared reflection spectroscopy (FTIR), portable X-ray fluorescence (XRF) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) were used as supplementary methods. The measurements showed that blue pigments (ultramarine, Prussian blue and azurite), vermilion and ivory black in mixture with whites provided characteristic Raman spectra, while Co-, Cd- and Cr- pigments' bands were suppressed by fluorescence. The best success rate of micro-Raman spectroscopy has been achieved using the 780 nm excitation, however, the sensitivity of this excitation laser in a portable Raman instrument significantly decreased. The analyses of micro-samples of paintings by E. Munch and F. Kupka showed that micro-Raman spectroscopy identified pigments which would remain unidentified if analyzed only by SEM-EDS (zinc yellow, Prussian blue). On the other hand, chromium oxide green and ultramarine were not detected together in a sample due to overlap of their main bands. In those cases, it is always necessary to complement Raman analysis with other analytical methods.
A simple and rapid one-step continuous-flow synthesis route has been developed for the preparation of chromene derivatives from the reaction of aromatic aldehydes, α-cyanomethylene compounds and naphthols. In this contribution, a one-step continuous-flow protocol in a continuous ...
SYNTHESIS, IN VITRO METABOLISM, MUTAGENICITY, AND DNA-ADDUCTION OF NAPHTHO[1,2-E]PYRENE
SYNTHESIS, IN V1TRO METABOLISM, MUTAGENICITY , AND DNA-ADDUCnON OF NAPHTHO[l ,2-e ]PYRENE
Literature data, although limited, underscore the contribution of C24HI4 polycyclic aromatic hydrocarbons to the biological activity of the extracts of complex environmental samples....
A nanosized magnesium oxide catalyzed three-component condensation reaction of aldehyde, malononitrile and ¿-naphthol proceeded rapidly in water/PEG to afford corresponding 2-amino-2-chromenes in high yields at room temperature. The greener protocol was found to be fairly general...
Divergent discourse between protests and counter-protests: #BlackLivesMatter and #AllLivesMatter
Reagan, Andrew J.; Danforth, Christopher M.; Dodds, Peter Sheridan
2018-01-01
Since the shooting of Black teenager Michael Brown by White police officer Darren Wilson in Ferguson, Missouri, the protest hashtag #BlackLivesMatter has amplified critiques of extrajudicial killings of Black Americans. In response to #BlackLivesMatter, other Twitter users have adopted #AllLivesMatter, a counter-protest hashtag whose content argues that equal attention should be given to all lives regardless of race. Through a multi-level analysis of over 860,000 tweets, we study how these protests and counter-protests diverge by quantifying aspects of their discourse. We find that #AllLivesMatter facilitates opposition between #BlackLivesMatter and hashtags such as #PoliceLivesMatter and #BlueLivesMatter in such a way that historically echoes the tension between Black protesters and law enforcement. In addition, we show that a significant portion of #AllLivesMatter use stems from hijacking by #BlackLivesMatter advocates. Beyond simply injecting #AllLivesMatter with #BlackLivesMatter content, these hijackers use the hashtag to directly confront the counter-protest notion of “All lives matter.” Our findings suggest that Black Lives Matter movement was able to grow, exhibit diverse conversations, and avoid derailment on social media by making discussion of counter-protest opinions a central topic of #AllLivesMatter, rather than the movement itself. PMID:29668754
Spatially modulated structural colour in bird feathers.
Parnell, Andrew J; Washington, Adam L; Mykhaylyk, Oleksandr O; Hill, Christopher J; Bianco, Antonino; Burg, Stephanie L; Dennison, Andrew J C; Snape, Mary; Cadby, Ashley J; Smith, Andrew; Prevost, Sylvain; Whittaker, David M; Jones, Richard A L; Fairclough, J Patrick A; Parker, Andrew R
2015-12-21
Eurasian Jay (Garrulus glandarius) feathers display periodic variations in the reflected colour from white through light blue, dark blue and black. We find the structures responsible for the colour are continuous in their size and spatially controlled by the degree of spinodal phase separation in the corresponding region of the feather barb. Blue structures have a well-defined broadband ultra-violet (UV) to blue wavelength distribution; the corresponding nanostructure has characteristic spinodal morphology with a lengthscale of order 150 nm. White regions have a larger 200 nm nanostructure, consistent with a spinodal process that has coarsened further, yielding broader wavelength white reflectance. Our analysis shows that nanostructure in single bird feather barbs can be varied continuously by controlling the time the keratin network is allowed to phase separate before mobility in the system is arrested. Dynamic scaling analysis of the single barb scattering data implies that the phase separation arrest mechanism is rapid and also distinct from the spinodal phase separation mechanism i.e. it is not gelation or intermolecular re-association. Any growing lengthscale using this spinodal phase separation approach must first traverse the UV and blue wavelength regions, growing the structure by coarsening, resulting in a broad distribution of domain sizes.
Spatially modulated structural colour in bird feathers
Parnell, Andrew J.; Washington, Adam L.; Mykhaylyk, Oleksandr O.; Hill, Christopher J.; Bianco, Antonino; Burg, Stephanie L.; Dennison, Andrew J. C.; Snape, Mary; Cadby, Ashley J.; Smith, Andrew; Prevost, Sylvain; Whittaker, David M.; Jones, Richard A. L.; Fairclough, J. Patrick. A.; Parker, Andrew R.
2015-01-01
Eurasian Jay (Garrulus glandarius) feathers display periodic variations in the reflected colour from white through light blue, dark blue and black. We find the structures responsible for the colour are continuous in their size and spatially controlled by the degree of spinodal phase separation in the corresponding region of the feather barb. Blue structures have a well-defined broadband ultra-violet (UV) to blue wavelength distribution; the corresponding nanostructure has characteristic spinodal morphology with a lengthscale of order 150 nm. White regions have a larger 200 nm nanostructure, consistent with a spinodal process that has coarsened further, yielding broader wavelength white reflectance. Our analysis shows that nanostructure in single bird feather barbs can be varied continuously by controlling the time the keratin network is allowed to phase separate before mobility in the system is arrested. Dynamic scaling analysis of the single barb scattering data implies that the phase separation arrest mechanism is rapid and also distinct from the spinodal phase separation mechanism i.e. it is not gelation or intermolecular re-association. Any growing lengthscale using this spinodal phase separation approach must first traverse the UV and blue wavelength regions, growing the structure by coarsening, resulting in a broad distribution of domain sizes. PMID:26686280
Video System Highlights Hydrogen Fires
NASA Technical Reports Server (NTRS)
Youngquist, Robert C.; Gleman, Stuart M.; Moerk, John S.
1992-01-01
Video system combines images from visible spectrum and from three bands in infrared spectrum to produce color-coded display in which hydrogen fires distinguished from other sources of heat. Includes linear array of 64 discrete lead selenide mid-infrared detectors operating at room temperature. Images overlaid on black and white image of same scene from standard commercial video camera. In final image, hydrogen fires appear red; carbon-based fires, blue; and other hot objects, mainly green and combinations of green and red. Where no thermal source present, image remains in black and white. System enables high degree of discrimination between hydrogen flames and other thermal emitters.
Water depth penetration film test
NASA Technical Reports Server (NTRS)
Lockwood, H. E.; Perry, L.; Sauer, G. E.; Lamar, N. T.
1974-01-01
As part of the National Aeronautics and Space Administration Earth Resources Program, a comparative and controlled evaluation of nine film-filter combinations was completed to establish the relative effectiveness in recording water subsurface detail if exposed from an aerial platform over a typical water body. The films tested, with one exception, were those which prior was suggested had potential. These included an experimental 2-layer positive color film, a 2-layer (minus blue layer) film, a normal 3-layer color film, a panchromatic black-and-white film, and a black-and-white infrared film. Selective filtration was used with all films.
[Coat color in dogs. 2: Clinical significance].
Laukner, A
1998-04-01
The meaning of the coat colour of the dog reaches further than only to the field of breeding for beauty. Besides aspects of destination (hunting dogs, herding dogs) the clinical meaning is of particular interest. Some colours can show certain defects. Diseases of allowed colours are the colour dilution alopecia (CDA) in diluted (mostly "blue") pigmentation with its subtype of Black hair follicular dysplasia (BHFD) in black pigmentation and congenital deafness in extreme piebalds. Not allowed coat colours, which are connected with defects, are the extreme dapple of the Merle-syndrome and the "grey" Collie with cyclic hematopoesis.
2015-09-28
Figure 3 USACE ERDC mobile measurement system with Riegl VZ‐400 laser scanner (a) and OSU GPSVan with targets (b...five target materials (red: retro reflective, blue: wood, cyan: fluffy plastic, yellow: cardboard, and black: painted wood...and black: painted wood) ........................ 28 Figure 21 Waveforms shapes of in the three classes
1984-10-10
41G-34-036 (5-13 Oct 1984) --- When in space, Space Shuttle astronauts experience 18-dawns to every one on terra firma. The crew of NASA's STS-41G mission captured these spectacular colors just prior to passing through one of those orbital dawns in October of 1984. The scene is over the Pacific Ocean, approximately 2,000 miles from Tokyo. The bands of color represent the various layers of aerosol which surround the planet. The brilliant red is the atmosphere; the overlap between red and blue is the stratosphere; the blue layer is the ionosphere. With increased altitude, the electrons and ions are reduced in number, leaving the vast blackness of space.
Three Cheers for the Red, White, and Blue!
ERIC Educational Resources Information Center
Instructor, 1983
1983-01-01
This package of patriotic learning activities refers to historic tales about colonial days, Black history, and the contributions of the states to America's wealth and history. Poems, skits, riddles about states and presidents, and a play featuring mock presidential interviews are included. A Save-the-Statue-of-Liberty project is noted. (PP)
Through Black and Brown Eyes, as Well as Blue: American History from Students' Perspectives.
ERIC Educational Resources Information Center
Toman, Susan
1995-01-01
Describes a U.S. history survey course that incorporates cultural pluralism and family histories into the writing assignments. Students are encouraged to write about events that occurred in their families during the time periods being studied. Oral interviews and family documents supplement traditional research tools and secondary sources. (MJP)
ERIC Educational Resources Information Center
McLaughlin, Margaret A.
Educators at Georgia Southern University began using a whole language approach to developmental literacy instruction by adapting the model David Bartholomae and Anthony Petrosky provide in "Facts, Artifacts, and Counterfacts." Rather than a focus on information retrieval and transfer, whole language curricula encourage students to engage…
Children's Color Perception in Relation to Habitat and Skin Color.
ERIC Educational Resources Information Center
Gaines, Rosslyn; Powell, Gloria J.
1981-01-01
Developmental color perception of 278 four- and eight-year-old Black and White children in three societies was examined in relation to the theories that proximity to the equator and that fundus pigmentation (as measured by skin color) reduce shortwave (blue-green) in comparison to long-wave perception. (Author/MP)
Factors affecting the efficacy of a vinegar trap for Drosophila suzukii (Diptera: Drosophilidae)
USDA-ARS?s Scientific Manuscript database
Studies were conducted to develop an optimized, economical trap for monitoring the spotted wing fruit fly, Drosophila suzukii Matsumura. Flies were attracted to dark colors ranging from red to black compared with low attraction to white, yellow, and light blue. Similarly, fly catches in 237 ml plast...
Caetano, João V O; Maia, Maya R; Manica, Lilian T; Macedo, Regina H
2014-11-01
Predation is a major force shaping natural history traits of birds because of their vulnerability during nesting and higher visibility during diurnal activities. For most birds in the Neotropics, predation is the major cause of nest failure due to the region's high diversity and abundance of predators. The blue-black grassquit (Volatinia jacarina), similarly to other small passerines in the savanna region of central Brazil, suffers extremely high rates of nest predation. Additionally, males may be particularly vulnerable to predators since they are very conspicuous when executing courtship displays. We assessed some of the non-lethal costs of predation risk on this species by comparing physiological and morphological parameters of birds exposed to predator vocalizations with that of control subjects exposed to non-predator vocalizations. Birds exposed to the predator vocalizations exhibited an immune-related reaction (changes in their H/L ratio), but no changes were observed in other biological parameters measured. This article is part of a Special Issue entitled: Neotropical Behaviour. Copyright © 2014 Elsevier B.V. All rights reserved.
[Skyblue - the cyanometer of Horace-Bénédict de Saussure (1740 - 1799)].
Breidbach, Olaf; Karliczek, André
2011-01-01
The cyanometer is a simply constructed measuring instrument that enables a determination of skyblue. It consists of a color-scale that is arranged circularly going in equal steps from white to blue (Prussian blue) and finally into black. According to its inventor--Horace-Bénédict de Saussure--the azure is determined by the amount of so called opaque vapors in the atmosphere associated with meteorological phenomena. As outlined by De Saussure, the blackness of the universe seen through an illuminated and blurred medium results in azure. Thereby his instrument offers a relative scale that is consistent with color theories of his time like those of Johann Wolfgang von Goethe. The description allows the construction of the scale without the employment of standardized color-prints. Instead he provides a clear report of the necessary procedures to produce such a scale. The accuracy of this description is tested and discussed employing the methods of experimental history of science. The reception of the cyanometer in the time about 1800 and its implications on color theories is discussed.
Evidence for a supermassive black hole in the nucleus of the Seyfert galaxy NGC 5548
NASA Technical Reports Server (NTRS)
Crenshaw, D. Michael; Blackwell, James H., Jr.
1990-01-01
The international campaign to monitor the variable Seyfert 1 galaxy NGC 5548 with the IUE has provided an extensive and well-sampled set of spectroscopic observations. These observations are used to study the response of the C IV 1550 A emission-line profile to changes in the photoionizing continuum. Near the end of the IUE campaign, the continuum flux at 1440 A and the total C IV flux dopped by factors of 2.9 and 1.8, respectively, in 16 days. The red wing of the C IV profile responded more rapidly to the sharp continuum drop than the blue wing, indicating that clouds in the inner broad-line region (BLR) are undergoing gravitational infall. These results provide direct evidence that the central engine is a supermassive object, presumably a black hole, with a mass on the order of 10 to the 7th solar masses. Analysis of the profile variations also demonstrates that excess emission in the blue wing of C IV is from a component that is physically distinct from the bulk of the BLR.
Kamara, D; Gyenai, K B; Geng, T; Hammade, H; Smith, E J
2007-01-01
The turkey is second only to the chicken in importance as an agriculturally important poultry species. Unlike the chicken, however, genetic studies of the turkey continue to be limited. For example, to date, many genomic investigations have been conducted to characterize genetic relationships between commercial (CO) and non-CO chicken breeds, whereas the nature of the genetic relatedness between CO and heritage turkeys remains unknown. The objective of the current research was to use microsatellites to analyze the genetic relatedness between CO and heritage domestic turkeys including Narragansett, Bourbon Red, Blue Slate, Spanish Black, and Royal Palm. Primer pairs specific for 10 previously described turkey microsatellite markers were used. The phylogenetic analysis showed that the Blue Slate, Bourbon Red, and Narragansett were genetically closely related to the CO strain, with a Nei distance of 0.30, and the Royal Palm and Spanish Black were the least related to the CO strain, with Nei distances of 0.41 and 0.40, respectively. The present work provides a foundation for the basis of using heritage turkeys to genetically improve CO populations by introgression.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Trivalent chromium complexes of a... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10239 Trivalent chromium complexes of... subject to reporting. (1) The chemical substance identified generically as trivalent chromium complexes of...
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Trivalent chromium complexes of a... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10239 Trivalent chromium complexes of... subject to reporting. (1) The chemical substance identified generically as trivalent chromium complexes of...
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Trivalent chromium complexes of a... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10239 Trivalent chromium complexes of... subject to reporting. (1) The chemical substance identified generically as trivalent chromium complexes of...
2012-01-01
Background Organic agriculture involve plants which are cultivated without using synthetic pesticides, herbicides or fertilizers and promotes biodiversity, biological cycles and improve the product quality. The carotenoids, total polyphenols and the antioxidant activity from skins of some wine and table grapes cultivated in organic and conventional agriculture were studied. Results The main carotenoids identified using high performance liquid chromatography were lutein and ß-carotene. Muscat Ottonel variety has the highest ß-carotene concentration 504.9 μg/kg for organic and 593.2 μg/kg for conventional grapes. For the organic farming, the total polyphenols content were in the range of 163.23 – 1341.37 mg GAE/kg fresh weight (FW) and 148.47 – 1231.38 mg GAE/kg FW for the conventional grapes. The highest ORAC values were obtained for blue-black variety Napoca in both farming system (43.5 ± 0.95 μmol TE/g organic; 40.4 ± 0.5 μmol TE/g conventional) and lowest for Aromat de Iaşi (16.8 ± 0.6 μmol TE/g organic; 14.7 ± 1.6 μmol TE/g conventional). Napoca variety showed also the highest antioxidant activity measured by DPPH method in both cultivated system. Conclusion Nine grape varieties cultivated in organic and conventional systems were compared regarding the carotenoids, total polyphenols and antioxidant activity. The white grape varieties have a higher carotenoids content compared with the blue-black cultivars while the blue-black varieties contain higher TPC and exhibit higher antioxidant activity (except for Muscat Hamburg-ORAC). Vitis vinifera grape skins originating from wine or table grape varieties can be used as a potential source of natural antioxidants. PMID:22762349
Rodrigues, Ema G.; Smith, Kristen; Maule, Alexis L.; Sjodin, Andreas; Li, Zheng; Romanoff, Lovisa; Kelsey, Karl; Proctor, Susan; McClean, Michael D.
2016-01-01
Objective To evaluate the association between inhalation exposure to jet propulsion fuel 8 (JP-8) and urinary metabolites among US Air Force (USAF) personnel, and investigate the role of glutathione S-transferase polymorphisms. Methods Personal air samples were collected from 37 full-time USAF personnel during 4 consecutive workdays and analyzed for JP-8 constituents and total hydrocarbons. Pre- and postshift urine samples were collected each day and analyzed for polycyclic aromatic hydrocarbon urinary metabolites. Results Work shift exposure to total hydrocarbons was significantly associated with postshift urinary 1-naphthol (β = 0.17; P = <0.0001), 2-naphthol (β = 0.09; P = 0.005), and 2-hydroxyfluorene concentrations (β = 0.08; P = 0.006), and a significant gene-environment interaction was observed with glutathione S-transferase mu-1. Conclusions USAF personnel experience inhalation exposure to JP-8, which is associated with absorption of JP-8 constituents while performing typical job-related tasks, and in our data the glutathione S-transferase mu-1 polymorphism was associated with differential metabolism of naphthalene. PMID:24806557
Identification of a Novel Family of BRAF[superscript V600E] Inhibitors
DOE Office of Scientific and Technical Information (OSTI.GOV)
Qin, Jie; Xie, Peng; Ventocilla, Christian
The BRAF oncoprotein is mutated in about half of malignant melanomas and other cancers, and a kinase activating single valine to glutamate substitution at residue 600 (BRAF{sup V600E}) accounts for over 90% of BRAF-mediated cancers. Several BRAF{sup V600E} inhibitors have been developed, although they harbor some liabilities, thus motivating the development of other BRAF{sup V600E} inhibitor options. We report here the use of an ELISA based high-throughput screen to identify a family of related quinolol/naphthol compounds that preferentially inhibit BRAF{sup V600E} over BRAF{sup WT} and other kinases. We also report the X-ray crystal structure of a BRAF/quinolol complex revealing themore » mode of inhibition, employ structure-based medicinal chemistry efforts to prepare naphthol analogues that inhibit BRAF{sup V600E} in vitro with IC{sub 50} values in the 80-200 nM range under saturating ATP concentrations, and demonstrate that these compounds inhibit MAPK signaling in melanoma cells. Prospects for improving the potency and selectivity of these inhibitors are discussed.« less
Gu, Lin; Wang, Yachen; Zhu, Nanwen; Zhang, Daofang; Huang, Shouqiang; Yuan, Haiping; Lou, Ziyang; Wang, Miaolin
2013-10-01
In this study, Fenton's reagents (H2O2/Fe(2+)) are used to activate raw sewage sludge for the preparation of the sludge based activated carbon. The effect of the amount of hydrogen peroxide addition on carbon's chemical composition, texture properties, surface chemistry and morphology are investigated. Choosing an appropriate H2O2 dosage (5 v%) (equivalent to 70.7 mM/(g VS)), it is possible to obtain a comparatively highly porous materials with SBET and the total pore volume being 321 m(2)/g and 0.414 cm(3)/g, respectively. Continuously increasing the oxidant ratio resulted in a decreased SBET value. Further adsorption experiments by using 2-naphthol as model pollutant revealed that the adoption followed a pseudo-second-order kinetics better than pseudo-first-order. The calculated adsorption capacity is 111.9 mg/g on the carbon with 5% H2O2 pretreatment while this value is just 51.5mg/g on carbons without any pretreatment. Copyright © 2013 Elsevier Ltd. All rights reserved.
Rodrigues, Ema G; Smith, Kristen; Maule, Alexis L; Sjodin, Andreas; Li, Zheng; Romanoff, Lovisa; Kelsey, Karl; Proctor, Susan; McClean, Michael D
2014-05-01
To evaluate the association between inhalation exposure to jet propulsion fuel 8 (JP-8) and urinary metabolites among US Air Force (USAF) personnel, and investigate the role of glutathione S-transferase polymorphisms. Personal air samples were collected from 37 full-time USAF personnel during 4 consecutive workdays and analyzed for JP-8 constituents and total hydrocarbons. Pre- and postshift urine samples were collected each day and analyzed for polycyclic aromatic hydrocarbon urinary metabolites. Work shift exposure to total hydrocarbons was significantly associated with postshift urinary 1-naphthol (β = 0.17; P = <0.0001), 2-naphthol (β = 0.09; P = 0.005), and 2-hydroxyfluorene concentrations (β = 0.08; P = 0.006), and a significant gene-environment interaction was observed with glutathione S-transferase mu-1. USAF personnel experience inhalation exposure to JP-8, which is associated with absorption of JP-8 constituents while performing typical job-related tasks, and in our data the glutathione S-transferase mu-1 polymorphism was associated with differential metabolism of naphthalene.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schawinski, Kevin; Urry, C. Megan; Virani, Shanil
We use data from the Sloan Digital Sky Survey and visual classifications of morphology from the Galaxy Zoo project to study black hole growth in the nearby universe (z < 0.05) and to break down the active galactic nucleus (AGN) host galaxy population by color, stellar mass, and morphology. We find that the black hole growth at luminosities L[O{sub III}]>10{sup 40} erg s{sup -1} in early- and late-type galaxies is fundamentally different. AGN host galaxies as a population have a broad range of stellar masses (10{sup 10}-10{sup 11} M{sub sun}), reside in the green valley of the color-mass diagram andmore » their central black holes have median masses around 10{sup 6.5} M{sub sun}. However, by comparing early- and late-type AGN host galaxies to their non-active counterparts, we find several key differences: in early-type galaxies, it is preferentially the galaxies with the least massive black holes that are growing, while in late-type galaxies, it is preferentially the most massive black holes that are growing. The duty cycle of AGNs in early-type galaxies is strongly peaked in the green valley below the low-mass end (10{sup 10} M{sub sun}) of the red sequence at stellar masses where there is a steady supply of blue cloud progenitors. The duty cycle of AGNs in late-type galaxies on the other hand peaks in massive (10{sup 11} M{sub sun}) green and red late-types which generally do not have a corresponding blue cloud population of similar mass. At high-Eddington ratios (L/L{sub Edd}>0.1), the only population with a substantial fraction of AGNs are the low-mass green valley early-type galaxies. Finally, the Milky Way likely resides in the 'sweet spot' on the color-mass diagram where the AGN duty cycle of late-type galaxies is highest. We discuss the implications of these results for our understanding of the role of AGNs in the evolution of galaxies.« less
Nelson, LaRon E; Walker, Ja'Nina J; DuBois, Steve N; Giwa, Sulaimon
2014-12-01
Evidence-based interventions have been developed and used to prevent HIV infections among black men who have sex with men (MSM) in Canada and the United States; however, the degree to which interventions address racism and other interlocking oppressions that influence HIV vulnerability is not well known. We utilize integrative antiracism to guide a review of HIV prevention intervention studies with black MSM and to determine how racism and religious oppression are addressed in the current intervention evidence base. We searched CINAHL, PsychInfo, MEDLINE and the CDC compendium of evidence-based HIV prevention interventions and identified seventeen interventions. Three interventions targeted black MSM, yet only one intervention addressed racism, religious oppression, cultural assets and religious assets. Most interventions' samples included low numbers of black MSM. More research is needed on interventions that address racism and religious oppression on HIV vulnerability among black MSM. Future research should focus on explicating mechanisms by which multiple oppressions impact HIV vulnerability. We recommend the development and integration of social justice tools for nursing practice that aid in addressing the impacts of racism and other oppressions on HIV vulnerability of black MSM. © 2014 John Wiley & Sons Ltd.
Photosynthetic Energy Transduction | Bioenergy | NREL
a large lighter green oval. There is a black line moving from one green bar to the other indicating blue oval labeled "FDX" and one green arrow pointing into the oval, labeled "electrons images with the third red line connecting the top of one L-shape to the bottom of the next L-shape
2016-07-01
between average background spectrum and chicken egg - white lysozyme protein spectrum...spectroscopic signatures were conducted using human insulin protein and chicken egg -white lysozyme protein. Proteins with different structures...the comparison between the average background THz spectrum (black line in Figure 13) and the chicken egg -white lysozyme THz spectrum (blue line
Black and Blue: The Impact of Nonfatal Teacher Victimization
ERIC Educational Resources Information Center
Stewart, Cedric B.; Robles-Pina, Rebecca
2008-01-01
Because violence in public schools is seen by many as a growing problem, several studies have been conducted to look at the impact of nonfatal teacher victimization. However, a large number of these studies have focused exclusively on students as victims and failed to investigate the impact that school-related crime has on school personnel. The…
Flooding of the Ob and Irtysh Rivers, Russia
NASA Technical Reports Server (NTRS)
2002-01-01
This pair of true- and false-color images shows flooding along the Ob' (large east-west running river) and Irtysh (southern tributary of the Ob') on July 7, 2002. In the false-color image, land surfaces are orange-gold and flood waters are black or dark blue. Fires are marked with red dots in both images. Rivers
USDA-ARS?s Scientific Manuscript database
Plant response to blue, red, gray or black shade cloth was evaluated with willow oak (Quercus phellos L.), Nuttall oak (Quercus nuttallii Palmer, Nuttall) and Summer Red maple (Acer rubrum L. ‘Summer Red’) liners. Light transmitted through the colored shade cloth had no influence on germination of ...
78 FR 48656 - Procurement List; Proposed Additions
Federal Register 2010, 2011, 2012, 2013, 2014
2013-08-09
..., Synthetic Mesh, 24x36, Locking Drawstring NSN: 3510-00-NIB-0013--Heavy Duty, \\3/16\\'' Hole Size. NSN: 3510-00-NIB-0014--Medium Duty, \\1/16\\'' Hole Size. NPA: Bestwork Industries for the Blind, Inc., Runnemede... NSN: 7510-01-462-1383--View Framed, Navy Blue, \\1/2\\''. NSN: 7510-01-462-1384--View Framed, Black, \\1...
Mark Knaebe
2013-01-01
Iron stain, an unsightly blueâblack or gray discoloration, can occur on nearly all woods. Oak, redwood, cypress, and cedar are particularly prone to iron stain because these woods contain large amounts of tannin-like extractives. The discoloration is caused by a chemical reaction between extractives in the wood and iron in steel products, such as nails, screws, and...
New Lepidoptera records for the Blue Mountains of eastern Oregon.
David G. Grimble; Roy C. Beckwith; Paul C. Hammond
1993-01-01
Black-light trap collections in mixed-coniferous forests in eastern Oregon resulted in the identification of one Arctiidae, six Noctuidae, and one Geometridae species not previously known to occur in Oregon. The ranges of 18 other species of Noctuidae, known previously in Oregon from only the Cascade and Coast Ranges, were extended to northeastern Oregon.
78 FR 50039 - Procurement List, Additions and Deletions
Federal Register 2010, 2011, 2012, 2013, 2014
2013-08-16
... Committee for Purchase From People Who Are Blind or Severely Disabled published notices of proposed... Commissary Agency. NSN: 7510-00-NIB-9832--Portable Desktop Clipboard, 10'' W x 2-\\3/ 5\\'' D x 16'' H, Black. NSN: 7510-00-NIB-9833--Portable Desktop Clipboard, 10'' W x 2-\\3/ 5\\'' D x 16'' H, Blue. NSN: 7510-00...
Continuous Hypergolic Monitor Network for Shipboard Applications
2005-08-30
PEI Oxidizers MON-25 Polyamines and Polycarbonyls Ethanol SXFA Acetone PEO Octane Poly(ethylene-co-vinyl acetate) ( PEVA ), Polyisobutylene...polyvinylacetate ( PEVA ). These tests were performed under variable humidity and temperature (Figure 13) and under low humidity at ambient temperature...Test of Chemoselective Polymers Against Interferents with Variable Temperature and Humidity. Key: PEVA black; PEI red; SXFA blue; NmA yellow
A Study of Color Preferences for Drugs and Implications for Compliance and Drug-taking.
ERIC Educational Resources Information Center
Coffield, K. E.; Buckalew, L. W.
1988-01-01
Examined medication capsule color preferences of male and female college students, both on and not on medication. Sex and medication status were insignificant in preference rankings. Blacks, grays, tans, and browns were clearly rejected colors while blues and some reds and yellows were preferred. Findings have relevance for patient compliance…
NASA's Hubble Spots a Relic from a Shredded Galaxy
2017-12-08
February 17, 2012: Astronomers using NASA's Hubble Space Telescope may have found evidence for a cluster of young, blue stars encircling HLX-1, one of the first intermediate-mass black holes ever discovered. Astronomers believe the black hole may once have been at the core of a now-disintegrated dwarf galaxy. The discovery of the black hole and the possible star cluster has important implications for understanding the evolution of supermassive black holes and galaxies To read more go to: www.nasa.gov/mission_pages/hubble/science/shredded-relic.... Credit: NASA, ESA, and S. Farrell (Sydney Institute for Astronomy, University of Sydney) NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram
Yoo, Gang Yeol; Jeong, Jae-Seung; Lee, Soyoung; Lee, Youngki; Yoon, Hee Chang; Chu, Van Ben; Park, Gi Soon; Hwang, Yun Jeong; Kim, Woong; Min, Byoung Koun; Do, Young Rag
2017-05-03
There are four prerequisites when applying all types of thin-film solar cells to power-generating window photovoltaics (PVs): high power-generation efficiency, longevity and high durability, semitransparency or partial-light transmittance, and colorful and aesthetic value. Solid-type thin-film Cu(In,Ga)S 2 (CIGS) or Cu(In,Ga)(S,Se) 2 (CIGSSe) PVs nearly meet the first two criteria, making them promising candidates for power-generating window applications if they can transmit light to some degree and generate color with good aesthetic value. In this study, the mechanical scribing process removes 10% of the window CIGSSe thin-film solar cell with vacant line patterns to provide a partial-light-transmitting CIGSSe PV module to meet the third requirement. The last concept of creating distinct colors could be met by the addition of reflectance colors of one-dimensional (1D) photonic crystal (PC) dichroic film on the black part of a partial-light-transmitting CIGSSe PV module. Beautiful violets and blues were created on the cover glass of a black CIGSSe PV module via the addition of 1D PC blue-mirror-yellow-pass dichroic film to improve the aesthetic value of the outside appearance. As a general result from the low external quantum efficiency (EQE) and absorption of CIGSSe PVs below a wavelength of 400 nm, the harvesting efficiency and short-circuit photocurrent of CIGSSe PVs were reduced by only ∼10% without reducing the open-circuit voltage (V OC ) because of the reduced overlap between the absorption spectrum of CIGSSe PV and the reflectance spectrum of the 1D PC blue-mirror-yellow-pass dichroic film. The combined technology of partial-vacancy-scribed CIGSSe PV modules and blue 1D PC dichroic film can provide a simple strategy to be applied to violet/blue power-generating window applications, as such a strategy can improve the transparency and aesthetic value without significantly sacrificing the harvesting efficiency of the CIGSSe PV modules.
ERIC Educational Resources Information Center
Mak, Kendrew K. W.
2004-01-01
NMR spectroscopy is presented. It is seen that the experiment regarding the synthesis and resolution of 1,1'-Bi-2-naphtol presents a good experiment for teaching organic synthesis and NMR spectroscopy and provides a strategy for obtaining enantiopure compounds from achiral starting materials.
NASA Technical Reports Server (NTRS)
2004-01-01
KENNEDY SPACE CENTER, FLA. White pelicans soar into the blue sky above a lake north of Kennedy Space Center. Distinctive are the pelicans massive yellow bills and black wing tips. They winter from Florida and southern California south to Panama. The Center shares a boundary with the 92,000-acre Merritt Island National Wildlife Refuge, which is a habitat for more than 310 species of birds, 25 mammals, 117 fishes and 65 amphibians and reptiles. The marshes and open water of the refuge also provide wintering areas for 23 species of migratory waterfowl, as well as a year-round home for great blue herons, great egrets, wood storks, cormorants, brown pelicans and other species of marsh and shore birds.
What color should glacier algae be? An ecological role for red carbon in the cryosphere.
Dial, Roman J; Ganey, Gerard Q; Skiles, S McKenzie
2018-03-01
Red-colored secondary pigments in glacier algae play an adaptive role in melting snow and ice. We advance this hypothesis using a model of color-based absorption of irradiance, an experiment with colored particles in snow, and the natural history of glacier algae. Carotenoids and phenols-astaxanthin in snow-algae and purpurogallin in ice-algae-shield photosynthetic apparatus by absorbing overabundant visible wavelengths, then dissipating the excess radiant energy as heat. This heat melts proximal ice crystals, providing liquid-water in a 0°C environment and freeing up nutrients bound in frozen water. We show that purple-colored particles transfer 87%-89% of solar energy absorbed by black particles. However, red-colored particles transfer nearly as much (85%-87%) by absorbing peak solar wavelengths and reflecting the visible wavelengths most absorbed by nearby ice and snow crystals; this latter process may reduce potential cellular overheating when snow insulates cells. Blue and green particles transfer only 80%-82% of black particle absorption. In the experiment, red-colored particles melted 87% as much snow as black particles, while blue particles melted 77%. Green-colored snow-algae naturally occupy saturated snow where water is non-limiting; red-colored snow-algae occupy drier, water-limited snow. In addition to increasing melt, we suggest that esterified astaxanthin in snow-alga cells increases hydrophobicity to remain surficial. © FEMS 2018. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.
Momayyezi, Mina; Guy, Robert D
2017-06-01
To explore what role chloroplast positioning might have in relation to latitudinal variation in mesophyll conductance (g m ) of Populus trichocarpa Torr. & Gray (black cottonwood), we examined photosynthetic response to different blue light treatments in six representative genotypes (three northern and three southern). The proportion of blue (B) to red light was varied from 0:100, 10:90, 20:80, 40:60, and 60:40 while keeping the total photosynthetic photon flux density constant. Mesophyll conductance was estimated by monitoring chlorophyll fluorescence in combination with gas exchange. Compared to the control (10% B), g m was significantly lower with increasing blue light. Consistent with a change in chloroplast positioning, there was a simultaneous but reversible decrease in chlorophyll content index (CCI), as measured by foliar greenness, while the extracted, actual chlorophyll content (ACC) remained unchanged. Blue-light-induced decreases in g m and CCI were greater in northern genotypes than in southern genotypes, both absolutely and proportionally, consistent with their inherently higher photosynthetic rate. Treatment of leaves with cytochalasin D, an inhibitor of actin-based chloroplast motility, reduced both CCI and ACC but had no effect on the CCI/ACC ratio and fully blocked any effect of blue light on CCI. Cytochalasin D reduced g m by ∼56% under 10% B, but did not block the effect of 60% B on g m , which was reduced a further 20%. These results suggest that the effect of high blue light on g m is at least partially independent of chloroplast repositioning. High blue light reduced carbonic anhydrase activity by 20% (P<0.05), consistent with a possible reduction in protein-mediated facilitation of CO 2 diffusion. Copyright © 2017 Elsevier GmbH. All rights reserved.
Delrieu-Trottin, Erwan; Williams, Jeffrey T; Planes, Serge
2014-08-29
A new species of wrasse, Macropharyngodon pakoko, is described from the Marquesas Islands, bringing the total number of species of the genus Macropharyngodon to 12. Macropharyngodon pakoko was found at depths from 0-42 m and is endemic to the Marquesas Islands. Macropharyngodon pakoko is similar to M. meleagris, which is widely distributed from the central and western Pacific to Cocos-Keeling in the Indian Ocean, but differs genetically and in several coloration characters: males with irregularly curved black humeral blotch with incomplete iridescent blue border; inverted irregular "U"- shaped band on the cheek; a small black spot at the upper base of the pectoral fin; and background color of the body greenish with faint bluish black spots on each scale. Females lack black pigment on the chest posterior to the ventral attachment of the gill membranes; reddish black blotches on the body are widely spaced, particularly on the head where they are more reddish and half the size of those on body; caudal fin with small, bright yellow spots arranged in narrow vertical bands with pale interspaces; pelvic fins pale with three reddish yellow cross-bands; a small black spot at the upper base of the pectoral fin; and small reddish spots along the base of the anal fin. Juveniles have irregular black blotches on the body, a small black spot instead of an ocellus posteriorly on the dorsal fin and lack large black spots and ocellus on the anal fin.
Chronic vs. Short-Term Acute O 3 Exposure Effects on Nocturnal Transpiration in Two Californian Oaks
Nancy Grulke; E. Paoletti; R. L. Heath
2007-01-01
We tested the effect of daytime chronic moderate ozone (O3) exposure, short-term acute exposure, and both chronic and acute O3 exposure combined on nocturnal transpiration in California black oak and blue oak seedlings. Chronic O3 exposure (70 ppb for 8 h/day) was implemented in open-top chambers for...
The study of synthetic food dyes by positron annihilation lifetime spectroscopy.
NASA Astrophysics Data System (ADS)
Pivtsaev, A. A.; Razov, V. I.
2015-06-01
By method of positron annihilation lifetime spectroscopy (PALS), substances are food dyes were studied: E-102 (Tartrazine), E-124 (Ponso 4R), E 132 (Indigo carmine), E-133 (Brilliant Blue), E-151 (Black Shiny). They are examined for the presence of carcinogenic properties. The difference between dyes having explicit carcinogenic properties and mutagenic properties (non-explicit carcinogens) is established.
Eastern Tent Caterpillar (Pest Alert)
Robert Rabaglia; Daniel Twardus
1990-01-01
The eastern tent caterpillar is often mistaken for the gypsy moth. Though they are similar in appearance, they differ in habits. The fully grown eastern tent caterpillar is about 2 inches long, black with a white stripe along the middle of the back and a row of pale blue oval spots on each side. It is sparsely covered with fine light brown hairs. The gypsy moth...
ERIC Educational Resources Information Center
Wien, Carol Anne
2008-01-01
The lake is blue black and deep. It is a glaciated finger lake, clawed out of rock when ice retracted across Nova Scotia in a northerly direction during the last ice age. The lake is narrow, a little over a mile long, and deep, 90 to 190 feet in places according to local lore, off the charts in others. The author loves to swim there, with a sense…
Parental care in the multi-brooded Black-throated Blue Warbler
Kirk W Stodola; Eric T Linder; David A Buehler; Kathleen E Franzreb; Robert J. Cooper
2009-01-01
Maximizing reproductive output often entails a trade-off between energy spent on current breeding attempts and that saved for future reproductive opportunities. For species with biparental care, energy spent on the current breeding attempt represents not only a trade-off with future breeding opportunities but also an interaction with the energetic effort of oneâs mate...
Smoke plumes: Emissions and effects
Susan O' Neill; Shawn Urbanski; Scott Goodrick; Sim Larkin
2017-01-01
Smoke can manifest itself as a towering plume rising against the clear blue sky-or as a vast swath of thick haze, with fingers that settle into valleys overnight. It comes in many forms and colors, from fluffy and white to thick and black. Smoke plumes can rise high into the atmosphere and travel great distances across oceans and continents. Or smoke can remain close...
ERIC Educational Resources Information Center
Robischon, Marcel
2015-01-01
Genetic drift is a concept of population genetics that is central to understanding evolutionary processes and aspects of conservation biology. It is frequently taught using rather abstract representations. I introduce three real-life zoological examples, based on historical and recent color morphs of tigers, tapirs, and ravens, that can complement…
Raman spectroscopic analysis of the enigmatic Comper pigments.
Edwards, Howell G M; Wolstenholme, Rosalind; Wilkinson, David S; Brooke, Christopher; Pepper, Michelle
2007-03-01
An early church decoration project carried out by Sir Ninian Comper in 1896-98, involving the rood screen and canopy in St. Mary's, Egmanton, is currently undergoing restoration. Despite the rather prolific works of this famous ecclesiastical architect, there is little information available about the actual pigments that he used in his projects that gave rise to the special nomenclature "Comper green" and "Comper red". Specimens of green, red, black, grey, white and blue paint from this work have been made available for Raman spectroscopic analysis, and their identification has been achieved for the first time. The characteristic red and green pigments used in Comper's work, Comper green and Comper red, are both seen to be mixtures; in the former, Raman bands from chrome yellow (lead(II) chromate) and Prussian blue are identified, and the latter is confirmed as being a mixture of vermilion (mercury(II) sulfide) and barytes (barium sulfate). The other colours are found to represent a rich diversity of palette and include haematite, lead tin yellow (type II), lamp black, gypsum, anhydrite, hydrocerussite and calcite. The information from this first Raman spectroscopic study of Comper's palette will assist the conservation and restoration of an important nineteenth century church decoration.
Homogenous and heterogenous advanced oxidation of two commercial reactive dyes.
Balcioglu, I A; Arslan, I; Sacan, M T
2001-07-01
Two commercial reactive dyes, the azo dye Reactive Black 5 and the copper phythalocyanine dye Reactive Blue 21, have been treated at a concentration of 75 mg l(-1) by titanium dioxide mediated photocatalytic (TiO2/UV), dark and UV-light assisted Fenton (Fe2+/H2O2) and Fenton-like (Fe3+/H2O2) processes in acidic medium. For the treatment of Reactive Black 5, all investigated advanced oxidation processes were quite effective in terms of colour, COD as well as TOC removal. Moreover, the relative growth inhibition of the azo dye towards the marine algae Dunaliella tertiolecta that was initially 70%, did not exhibit an increase during the studied advanced oxidation reactions and complete detoxification at the end of the treatment period could be achieved for all investigated treatment processes. However, for Reactive Blue 21, abatement in COD and UV-VIS absorbance values was mainly due to the adsorption of the dye on the photocatalyst surface and/or the coagulative effect of Fe3+/Fe2+ ions. Although only a limited fraction of the copper phythalocyanine dye underwent oxidative degradation, 47% of the total copper in the dye was already released after 1 h photocatalytic treatment.
Raman analysis of ancient pigments on a tile from the Citadel of Algiers.
Kock, L D; De Waal, D
2008-12-15
A micro-Raman spectroscopy study of a multi-coloured (yellow, blue, white, redish-brown and brown-black) tile shard from the Citadel of Algiers was undertaken. XRD and EDX were used as complementary techniques. The study shows that the heterogeneous three-shade yellow pigment on the tile is composed largely of the ancient ternary (Pb-Sn-Sb) pyrochlore oxide with a dominant Pb-O vibration at 127 cm(-1) consistent with the Pb2SnSbO6.5 structure as verified by XRD. The literature assignment of this band at 132 cm(-1) probably comes from a mixture of pigments. The redish-brown and the brown-black pigments are found to be Naples yellow (Pb2Sb2O7) and lead(II) stannate (Pb2SnO4), respectively, while cobalt blue (CoAl2O4) gives the blue colour and cassiterite (SnO2) is the origin of the white colour. The bulk of the tile body is composed mainly of hematite (alpha-Fe2O3), maghemite (gamma-Fe2O3), magnetite (Fe3O4) and Quartz (alpha-SiO2) with traces of calcite (CaCO3) and amorphous carbon. Micro-Raman spectroscopy proved to be very useful in the characterization of pigments as well as the tile body. These results further establish Raman spectroscopy as a technique of choice for the analysis of pigments on archaeological artifacts. The results obtained here could be used in the restoration and preservation programme of the Citadel itself which stands today as a symbol of pre-colonial Algerian heritage.
Raman analysis of ancient pigments on a tile from the Citadel of Algiers
NASA Astrophysics Data System (ADS)
Kock, L. D.; De Waal, D.
2008-12-01
A micro-Raman spectroscopy study of a multi-coloured (yellow, blue, white, redish-brown and brown-black) tile shard from the Citadel of Algiers was undertaken. XRD and EDX were used as complementary techniques. The study shows that the heterogeneous three-shade yellow pigment on the tile is composed largely of the ancient ternary (Pb-Sn-Sb) pyrochlore oxide with a dominant Pb-O vibration at 127 cm -1 consistent with the Pb 2SnSbO 6.5 structure as verified by XRD. The literature assignment of this band at 132 cm -1 probably comes from a mixture of pigments. The redish-brown and the brown-black pigments are found to be Naples yellow (Pb 2Sb 2O 7) and lead(II) stannate (Pb 2SnO 4), respectively, while cobalt blue (CoAl 2O 4) gives the blue colour and cassiterite (SnO 2) is the origin of the white colour. The bulk of the tile body is composed mainly of hematite (α-Fe 2O 3), maghemite (γ-Fe 2O 3), magnetite (Fe 3O 4) and Quartz (α-SiO 2) with traces of calcite (CaCO 3) and amorphous carbon. Micro-Raman spectroscopy proved to be very useful in the characterization of pigments as well as the tile body. These results further establish Raman spectroscopy as a technique of choice for the analysis of pigments on archaeological artifacts. The results obtained here could be used in the restoration and preservation programme of the Citadel itself which stands today as a symbol of pre-colonial Algerian heritage.
An ultraluminous quasar with a twelve-billion-solar-mass black hole at redshift 6.30.
Wu, Xue-Bing; Wang, Feige; Fan, Xiaohui; Yi, Weimin; Zuo, Wenwen; Bian, Fuyan; Jiang, Linhua; McGreer, Ian D; Wang, Ran; Yang, Jinyi; Yang, Qian; Thompson, David; Beletsky, Yuri
2015-02-26
So far, roughly 40 quasars with redshifts greater than z = 6 have been discovered. Each quasar contains a black hole with a mass of about one billion solar masses (10(9) M Sun symbol). The existence of such black holes when the Universe was less than one billion years old presents substantial challenges to theories of the formation and growth of black holes and the coevolution of black holes and galaxies. Here we report the discovery of an ultraluminous quasar, SDSS J010013.02+280225.8, at redshift z = 6.30. It has an optical and near-infrared luminosity a few times greater than those of previously known z > 6 quasars. On the basis of the deep absorption trough on the blue side of the Lyman-α emission line in the spectrum, we estimate the proper size of the ionized proximity zone associated with the quasar to be about 26 million light years, larger than found with other z > 6.1 quasars with lower luminosities. We estimate (on the basis of a near-infrared spectrum) that the black hole has a mass of ∼1.2 × 10(10) M Sun symbol, which is consistent with the 1.3 × 10(10) M Sun symbol derived by assuming an Eddington-limited accretion rate.
Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes.
Li, X; Yang, J; Kozlowski, M C
2001-04-19
[reaction: see text]. Chiral 1,5-diaza-cis-decalins have been examined as ligands in the enantioselective oxidative biaryl coupling of substituted 2-naphthol derivatives. Under the optimal conditions employing a 1,5-diaza-cis-decalin copper(I) iodide complex with oxygen as the oxidant, rapid and highly selective couplings could be achieved (90-93% ee, 85% yield).
Fluorescent molecular probes based on excited state prototropism in lipid bilayer membrane
NASA Astrophysics Data System (ADS)
Mohapatra, Monalisa; Mishra, Ashok K.
2012-03-01
Excited state prototropism (ESPT) is observed in molecules having one or more ionizable protons, whose proton transfer efficiency is different in ground and excited states. The interaction of various ESPT molecules like naphthols and intramolecular ESPT (ESIPT) molecules like hydroxyflavones etc. with different microheterogeneous media have been studied in detail and excited state prototropism as a probe concept has been gaining ground. The fluorescence of different prototropic forms of such molecules, on partitioning to an organized medium like lipid bilayer membrane, often show sensitive response to the local environment with respect to the local structure, physical properties and dynamics. Our recent work using 1-naphthol as an ESPT fluorescent molecular probe has shown that the incorporation of monomeric bile salt molecules into lipid bilayer membranes composed from dipalmitoylphosphatidylcholine (DPPC, a lung surfactant) and dimyristoylphosphatidylcholine (DMPC), in solid gel and liquid crystalline phases, induce appreciable wetting of the bilayer up to the hydrocarbon core region, even at very low (<= 1 mM) concentrations of the bile salts. The incorporation and location of fisetin, an ESIPT molecule having antioxidant properties, in lipid bilayer membrane has been sensitively monitored from its intrinsic fluorescence behaviour.
In situ electrochemical detection of embryonic stem cell differentiation.
Yea, Cheol-Heon; An, Jeung Hee; Kim, Jungho; Choi, Jeong-Woo
2013-06-20
Stem cell sensors have emerged as a promising technique to electrochemically monitor the functional status and viability of stem cells. However, efficient electrochemical analysis techniques are required for the development of effective electrochemical stem cell sensors. In the current study, we report a newly developed electrochemical cyclic voltammetry (CV) system to determine the status of mouse embryonic stem (ES) cells. 1-Naphthly phosphate (1-NP), which was dephosphorylated by alkaline phosphatase into a 1-naphthol on an undifferentiated mouse ES cell, was used as a substrate to electrochemically monitor the differentiation status of mouse ES cells. The peak current in the cyclic voltammetry of 1-NP increased linearly with the concentration of pure 1-NP (R(2)=0.9623). On the other hand, the peak current in the electrochemical responses of 1-NP decreased as the number of undifferentiated ES cells increased. The increased dephosphorylation of 1-NP to 1-naphthol made a decreased electrochemical signal. Non-toxicity of 1-NP was confirmed. In conclusion, the proposed electrochemical analysis system can be applied to an electrical stem cell chip for diagnosis, drug detection and on-site monitoring. Copyright © 2013 Elsevier B.V. All rights reserved.
Hou, Li; Cui, Yuling; Xu, Mingdi; Gao, Zhuangqiang; Huang, Jianxin; Tang, Dianping
2013-09-15
A new sandwich-type impedimetric immunosensor based on functionalized graphene oxide nanosheets with a high ratio of horseradish peroxidase (HRP) and detection antibody was developed for the detection of carcinoembryonic antigen (CEA) by coupling with enzymatic biocatalytic precipitation of 4-chloro-1-naphthol (4-CN) on the captured antibody-modified glassy carbon electrode. Two molecular tags (with and without the graphene oxide nanosheets) were investigated for the detection of CEA and improved analytical features were acquired with the graphene-based labeling. With the labeling method, the performance and factors influencing the properties of the impedimetric immunosensors were also studied and evaluated. Under the optimal conditions, the dynamic concentration range of the impedimetric immunosensors spanned from 1.0pgmL(-1) to 80ngmL(-1) CEA with a detection limit (LOD) of 0.64pgmL(-1). Intra- and inter-assay coefficients of variation were less than 7.5% and 11%, respectively. Additionally, the methodology was evaluated for CEA analysis of 10 clinical serum samples and 5 diluted serum samples, receiving in a good accordance with the results obtained by the impedimetric immunoassay and the commercialized electrochemiluminescent method. Copyright © 2013 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Karmakar, Animesh; Singh, Bula
2018-07-01
The H-bonding interaction of 1-(2-pyridylazo)-2-naphthol (PAN) and 4-(2-Pyridylazo) resorcinol (PAR) with chloranilic acid (CLA) have been considered spectroscopically in methanol solvent. PAN and PAR were used as a ligand and this two ligands has diverse application in spectrophotometric, chelatometric analysis of different metal ions. However, it is seen as of the literature analysis that no molecular complex of PAN and PAR with CLA was reported. The creation of charge-transfer H-bonded adduct gives a outlook to progress the physico-chemical scenery of the donor. So the complex of PAN and PAR with chloranilic acid was recounted in this work in methanol medium. Both the hydrogen-bonded molecular complexes have been prepared and identified using 1H NMR, FT-IR, and elemental analysis. Spectroscopic data point out that PAN and PAR discretely interact with CLA by a physically potent H-bonding interaction. The thermal constancy of the above molecular complexes has been determined by TGA-DTA analysis. The computational calculation also supported the development of the H-bonded charge-transfer adduct.
Wu, Xiabing; You, Linjun; Di, Bin; Hao, Weiqiang; Su, Mengxiang; Gu, Yu; Shen, Lingling
2013-07-19
Novel chiral core-shell silica microspheres with trans-(1R,2R)-diaminocyclohexane (DACH) moiety bridged in the mesoporous shell were synthesized using layer-by-layer method. The chiral mesoporous shell around the nonporous silica core was formed by the co-condensation of N,N'-bis-[(triethoxysilyl)propyl]-trans-(1R,2R)-bis-(ureido)-cyclohexane (DACH-BS) and tetraethoxysilane (TEOS) using octadecyltrimethylammonium chloride (C18TMACl) and triblock poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) copolymer (P123) as the templates. The functionalized core-shell silica microspheres were characterized and tested as chiral stationary phases for high performance liquid chromatography (HPLC). R/S-1,1'-bi-2,2'-naphthol, R/S-6,6'-dibromo-1,1'-bi-2-naphthol and R/S-1,1'-bi-2,2'-phenanthrol were enantioseparated rapidly on the column packed with the DACH core-shell silica particles. Moreover, the column packed with core-shell particles exhibited better performance than the column packed with the DACH functionalized periodic mesoporous organosilicas. Copyright © 2013 Elsevier B.V. All rights reserved.
Aydin, Funda Armagan; Soylak, Mustafa
2010-01-15
A simple and effective method is presented for the separation and preconcentration of Th(IV), Ti(IV), Fe(III), Pb(II) and Cr(III) by solid phase extraction on 2-nitroso-1-naphthol impregnated MCI GEL CHP20P resin prior to their inductively coupled plasma-mass spectrometric determinations. The influence of analytical parameters including pH of the aqueous solution, flow rates of sample and eluent solutions and sample volume on the quantitative recoveries of analyte ions was investigated. Matrix effects caused by the presence of alkali, earth alkali and some metal ions in the analyzed solutions were investigated. The presented solid phase extraction method was applied to BCR-144R Sewage Sludge (domestic origin), BCR-141R Calcareous Loam Soil, NIST 1568a Rice Flour and NIST 1577b Bovine Liver certified reference materials (CRMs) for the determination of analyte ions and the results were in good agreement with the certified values. The separation procedure presented was also applied to the various natural water samples collected from Turkey with satisfactory results.
Iwata, Masanori; Teshima, Midori; Seki, Takahiro; Yoshioka, Shinya; Takeoka, Yukikazu
2017-07-01
Inspired by Steller's jay, which displays angle-independent structural colors, angle-independent structurally colored materials are created, which are composed of amorphous arrays of submicrometer-sized fine spherical silica colloidal particles. When the colloidal amorphous arrays are thick, they do not appear colorful but almost white. However, the saturation of the structural color can be increased by (i) appropriately controlling the thickness of the array and (ii) placing the black background substrate. This is similar in the case of the blue feather of Steller's jay. Based on the knowledge gained through the biomimicry of structural colored materials, colloidal amorphous arrays on the surface of a black particle as the core particle are also prepared as colorful photonic pigments. Moreover, a structural color on-off system is successfully built by controlling the background brightness of the colloidal amorphous arrays. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A Black-necked Stilt hunts for food in the water.
NASA Technical Reports Server (NTRS)
1999-01-01
A Black-necked Stilt hunts for food in the waters of the Merritt Island National Wildlife Refuge, which shares a boundary with Kennedy Space Center. The stilt is identified by its distinct head pattern of black and white, its very long red legs, and straight, very thin bill. The stilt's habitat is salt marshes and shallow coastal bays from Delaware and northern South America in the East, and freshwater marshes from Oregon and Saskatchewan to the Gulf Coast. The 92,000-acre refuge is a habitat for more than 310 species of birds, 25 mammals, 117 fishes and 65 amphibians and reptiles. The marshes and open water of the refuge also provide wintering areas for 23 species of migratory waterfowl, as well as a year-round home for great blue herons, great egrets, wood storks, cormorants, brown pelicans and other species of marsh and shore birds.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Klein, Stefanie; Sommer, Anja; Distel, Luitpold V.R.
Highlights: Black-Right-Pointing-Pointer Ultrasmall citrate-coated SPIONs with {gamma}Fe{sub 2}O{sub 3} and Fe{sub 3}O{sub 4} structure were prepared. Black-Right-Pointing-Pointer SPIONs uptaken by MCF-7 cells increase the ROS production for about 240%. Black-Right-Pointing-Pointer The SPION induced ROS production is due to released iron ions and catalytically active surfaces. Black-Right-Pointing-Pointer Released iron ions and SPION surfaces initiate the Fenton and Haber-Weiss reaction. Black-Right-Pointing-Pointer X-ray irradiation of internalized SPIONs leads to an increase of catalytically active surfaces. -- Abstract: Internalization of citrate-coated and uncoated superparamagnetic iron oxide nanoparticles by human breast cancer (MCF-7) cells was verified by transmission electron microscopy imaging. Cytotoxicity studies employing metabolicmore » and trypan blue assays manifested their excellent biocompatibility. The production of reactive oxygen species in iron oxide nanoparticle loaded MCF-7 cells was explained to originate from both, the release of iron ions and their catalytically active surfaces. Both initiate the Fenton and Haber-Weiss reaction. Additional oxidative stress caused by X-ray irradiation of MCF-7 cells was attributed to the increase of catalytically active iron oxide nanoparticle surfaces.« less
Chandra X-Ray Observatory Image of Andromeda Galaxy
NASA Technical Reports Server (NTRS)
1999-01-01
Chandra X-Ray Observatory took this first x-ray picture of the Andromeda Galaxy (M31) on October 13, 1999. The blue dot in the center of the image is a 'cool' million-degree x-ray source where a supermassive black hole with the mass of 30-million suns is located. The x-rays are produced by matter furneling toward the black hole. Numerous other hotter x-ray sources are also apparent. Most of these are probably due to x-ray binary systems, in which a neutron star or black hole is in close orbit around a normal star. While the gas falling into the central black hole is cool, it is only cool by comparison to the 100 other x-ray sources in the Andromeda Galaxy. To be detected by an x-ray telescope, the gas must have a temperature of more than a million degrees. The Andromeda Galaxy is our nearest neighbor spiral galaxy at a distance of two million light years. It is similar to our own Milky Way in size, shape, and also contains a supermassive black hole at the center. (Photo Credit: NASA/CXC/SAO/S. Murray, M. Garcia)
History of Chandra X-Ray Observatory
1999-10-13
Chandra X-Ray Observatory took this first x-ray picture of the Andromeda Galaxy (M31) on October 13, 1999. The blue dot in the center of the image is a "cool" million-degree x-ray source where a supermassive black hole with the mass of 30-million suns is located. The x-rays are produced by matter furneling toward the black hole. Numerous other hotter x-ray sources are also apparent. Most of these are probably due to x-ray binary systems, in which a neutron star or black hole is in close orbit around a normal star. While the gas falling into the central black hole is cool, it is only cool by comparison to the 100 other x-ray sources in the Andromeda Galaxy. To be detected by an x-ray telescope, the gas must have a temperature of more than a million degrees. The Andromeda Galaxy is our nearest neighbor spiral galaxy at a distance of two million light years. It is similar to our own Milky Way in size, shape, and also contains a supermassive black hole at the center. (Photo Credit: NASA/CXC/SAO/S. Murray, M. Garcia)
2015-10-08
A view from the Kimberly formation on Mars taken by NASA Curiosity rover. The strata in the foreground dip towards the base of Mount Sharp, indicating the ancient depression that existed before the larger bulk of the mountain formed. The colors are adjusted so that rocks look approximately as they would if they were on Earth, to help geologists interpret the rocks. This "white balancing" to adjust for the lighting on Mars overly compensates for the absence of blue on Mars, making the sky appear light blue and sometimes giving dark, black rocks a blue cast. This image was taken by the Mast Camera (Mastcam) on Curiosity on the 580th Martian day, or sol, of the mission. Malin Space Science Systems, San Diego, built and operates Curiosity's Mastcam. NASA's Jet Propulsion Laboratory, a division of the California Institute of Technology, Pasadena, built the rover and manages the project for NASA's Science Mission Directorate, Washington. http://photojournal.jpl.nasa.gov/catalog/PIA19839
Printable candlelight-style organic light-emitting diode
NASA Astrophysics Data System (ADS)
Jou, J. H.; Singh, M.; Song, W. C.; Liu, S. H.
2017-06-01
Candles or oil lamps are currently the most friendly lighting source to human eyes, physiology, ecosystems, artifacts, environment, and night skies due to their blue light-less emission. Candle light also exhibits high light-quality that provides visual comfort. However, they are relatively low in power efficacy (0.3 lm/W), making them energy-wasting, besides having problems like scorching hot, burning, catching fire, flickering, carbon blacking, oxygen consuming, and release of green house gas etc. In contrast, candlelight organic light-emitting diode (OLED) can be made blue-hazard free and energy-efficient. The remaining challenges are to maximize its light-quality and enable printing feasibility, the latter of which would pave a way to cost-effective manufacturing. We hence demonstrate herein the design and fabrication of a candlelight OLED via wet-process. From retina protection perspective, its emission is 13, 12 and 8 times better than those of the blue-enriched white CFL, LED and OLED. If used at night, it is 9, 6 and 4 times better from melatonin generation perspective.
Payne, G.A.
1977-01-01
Long Meadow Lake, Black Dog Creek, and Ponds AP-9 and AP-10 which lie in an area designated for a trunk highway bridge crossing the Minnesota River, were sampled for baseline water quality prior to construction of the bridge. Data collected show that dissolved solids fluctuate seasonally. Dissolved oxygen:/ranged from less than 1 milligram per liter under an ice cover to 13-9 milligrams per liter in the September sample at site 4 in Long Meadow Lake. The phytoplankton analyses showed pulses in algae populations, blue-green algae being the dominant type in at least one sample from each of the water courses.
[Osteogenesis imperfecta in monozygotic twins in Burundi].
Armstrong, O; Karayuba, R; Ngendahayo, L; Habonimana, E
1994-01-01
Little data is available about osteogenesis imperfecta in Black African children. This defect was diagnosed in monozygotic twins from Rwanda who presented multiple fractures, in particular of the femur, when they began to walk. Osteogenesis imperfecta was confirmed by lower limb deformity, presence of wormian bones in the skull, blue sclera, and tooth defects. In addition to the fact that it is uncommon to encounter this condition in monozygotic twins, this case is interesting for several reasons. Was osteogenesis imperfecta in these patients type I, frequent, or type III, exceptional? More importantly, this case stresses the high prevalence of type III in Black Africa which could constitute a hot-bed in the world.
Non-cardinal color perception across the retina: easy for orange, hard for burgundy and sky blue.
Gunther, Karen L
2014-04-01
Cardinal color performance (reddish, greenish, bluish, yellowish, black, and white) has been shown to decline in peripheral viewing. What about non-cardinal color performance (e.g., orange, burgundy, and sky blue)? In visual search, performance on non-cardinal colors matched that of the cardinal colors in the (L-M)/(S-(L+M)) (isoluminant) color plane (Experiment 1, n=10, to 30°; Experiment 2, n=3, to 50°). However, performance in the (L-M)/(L+M) and (S-(L+M))/(L+M) color planes was worse for non-cardinal colors, at all eccentricities, even in the fovea. The implications that these results have for the existence of non-cardinal mechanisms in each color plane are discussed.
Ling, Barbara Y; Dain, Stephen J
2018-04-01
Nonvisual demands of tests affect vision test results in children. 150 children (79 females and 71 males, 5.3-12.7 years of age) were examined. Isoluminant Blue, Yellow, Red, Green, and Black and White thresholds were established with a four-alternative forced-choice and pseudo-10-bit system with adaptive staircase and gaming elements. Where Threshold=b 0 +b 1 *age -1 , b 1 for RG=6.26±1.90 (95% confidence limits), Achr=3.96±1.07 and BY=12.48±2.76 were significantly different. The noncolor demands of the test are the same for RG, BY, and Achr, so the later development of BY discrimination is not an artifact of the test.
Lillo, Julio; González-Perilli, Fernando; Prado-León, Lilia; Melnikova, Anna; Álvaro, Leticia; Collado, José A; Moreira, Humberto
2018-01-01
Two experiments were performed to identify and compare the Basic Color Terms (BCTs) and the Basic Color Categories (BCCs) included in three dialects (Castilian, Mexican, and Uruguayan) of the Spanish language. Monolexemic Elicited lists were used in the first experiment to identify the BCTs of each dialect. Eleven BCTs appeared for the Spanish and the Mexican, and twelve did so for the Uruguayan. The six primary BCTs ( rojo "red," verde "green," amarillo "yellow," azul "blue," negro "black," and blanco "white") appeared in the three dialects. This occurred for only three derived BCTs ( gris "gray," naranja "orange," and rosa "pink") but not for the other five derived BCTs ( celeste "sky blue," marrón "brown," café "brown," morado "purple," and violeta "purple"). Color transitions were used in the second experiment for two different tasks. Extremes naming task was used to determine the relation between two different dialects' BCTs: equality, equivalence or difference. The results provided the first evidence for marrón "brown" and café "brown" being equivalent terms for the same BCC (brown in English) as is the case of morado "purple" and violeta "purple." Uruguayan celeste "sky blue" had no equivalent BCT in the other two dialects. Boundary delimitation task required the selection of the color in the boundary between two categories. The task was used to reasonably estimate the volume occupied by each BCC in the color space considering its chromatic area and lightness range. Excluding sky blue ( celeste "sky blue") and blue ( azul "blue"), the other BCCs color volumes were similar across the three dialects. Uruguayan sky blue and blue volumes conjointly occupied the portion of the color space corresponding to the Castilian and Mexican blue BCC. The fact that the BCT celeste "sky blue" only appeared in Uruguayan very probably derived from specific cultural factors (the use of the color in the flags and the arrival of an important number of Italian immigrants). Nevertheless, these cultural factors seem to nurture from a perceptive structuring of the color space, which nature is universal, as the boundaries of this category can be delimited from the responses of Spanish and Mexican participants.
NASA Astrophysics Data System (ADS)
Vaghti, Mehrey G.; Holyoak, Marcel; Williams, Amy; Talley, Theresa S.; Fremier, Alexander K.; Greco, Steven E.
2009-01-01
Societal constraints often limit full process restoration in large river systems, making local rehabilitation activities valuable for regeneration of riparian vegetation. A target of much mitigation and restoration is the federally threatened Valley elderberry longhorn beetle and its sole host plant, blue elderberry, in upper riparian floodplain environments. However, blue elderberry ecology is not well understood and restoration attempts typically have low success rates. We determined broad-scale habitat characteristics of elderberry in altered systems and examined associated plant species composition in remnant habitat. We quantified vegetation community composition in 139 remnant riparian forest patches along the Sacramento River and elderberry stem diameters along this and four adjacent rivers. The greatest proportion of plots containing elderberry was located on higher and older floodplain surfaces and in riparian woodlands dominated by black walnut. Blue elderberry saplings and shrubs with stems <5.0 cm in diameter were rare, suggesting a lack of recruitment. A complex suite of vegetation was associated with blue elderberry, including several invasive species which are potentially outcompeting seedlings for light, water, or other resources. Such lack of recruitment places increased importance on horticultural restoration for the survival of an imperiled species. These findings further indicate a need to ascertain whether intervention is necessary to maintain functional and diverse riparian woodlands, and a need to monitor vegetative species composition over time, especially in relation to flow regulation.
In Hard Times, Colleges Search for Ways to Trim the Faculty
ERIC Educational Resources Information Center
Wilson, Robin
2009-01-01
The Jones Theatre at Washington State University is getting a $500,000 face-lift this summer. A construction crew has already ripped out its 500 orange and blue seats and is replacing them with new ones covered in a wine-colored fabric. The theater's walls are being painted a light beige, and a new set of black velour curtains will grace the…
ERIC Educational Resources Information Center
Davis, Donna M.
2013-01-01
At a time when most other institutions of higher education in the country excluded ex-slaves from admission, the University of Kansas conferred degrees upon sixty African Americans by 1910. However, while the university did allow ex-slaves to matriculate, these students still experienced a degree of exclusion and encountered barriers of racial…
Flooding of the Ob and Irtysh Rivers, Russia
NASA Technical Reports Server (NTRS)
2002-01-01
This pair of true- and false-color images shows flooding along the Ob' (large east-west running river) and Irtysh (southern tributary of the Ob') on July 7, 2002. In the false-color image, land surfaces are orange-gold and flood waters are black or dark blue. Fires are marked with red dots in both images. Rivers Credit: Jacques Descloitres, MODIS Land Rapid Response Team, NASA/GSFC
Cloud Processed CCN Suppress Stratus Cloud Drizzle
NASA Astrophysics Data System (ADS)
Hudson, J. G.; Noble, S. R., Jr.
2017-12-01
Conversion of sulfur dioxide to sulfate within cloud droplets increases the sizes and decreases the critical supersaturation, Sc, of cloud residual particles that had nucleated the droplets. Since other particles remain at the same sizes and Sc a size and Sc gap is often observed. Hudson et al. (2015) showed higher cloud droplet concentrations (Nc) in stratus clouds associated with bimodal high-resolution CCN spectra from the DRI CCN spectrometer compared to clouds associated with unimodal CCN spectra (not cloud processed). Here we show that CCN spectral shape (bimodal or unimodal) affects all aspects of stratus cloud microphysics and drizzle. Panel A shows mean differential cloud droplet spectra that have been divided according to traditional slopes, k, of the 131 measured CCN spectra in the Marine Stratus/Stratocumulus Experiment (MASE) off the Central California coast. K is generally high within the supersaturation, S, range of stratus clouds (< 0.5%). Because cloud processing decreases Sc of some particles, it reduces k. Panel A shows higher concentrations of small cloud droplets apparently grown on lower k CCN than clouds grown on higher k CCN. At small droplet sizes the concentrations follow the k order of the legend, black, red, green, blue (lowest to highest k). Above 13 µm diameter the lines cross and the hierarchy reverses so that blue (highest k) has the highest concentrations followed by green, red and black (lowest k). This reversed hierarchy continues into the drizzle size range (panel B) where the most drizzle drops, Nd, are in clouds grown on the least cloud-processed CCN (blue), while clouds grown on the most processed CCN (black) have the lowest Nd. Suppression of stratus cloud drizzle by cloud processing is an additional 2nd indirect aerosol effect (IAE) that along with the enhancement of 1st IAE by higher Nc (panel A) are above and beyond original IAE. However, further similar analysis is needed in other cloud regimes to determine if MASE was typical. Hudson, J.G., S. Noble, and S. Tabor, 2015: J. Geophys. Res., Atmos., 120, 3436-3452, doi:10.1002/2014JD022669.
Prior states: evolution of composition and color in two Barnett Newman paintings
NASA Astrophysics Data System (ADS)
Epley, Bradford A.; Rogge, Corina E.
2015-11-01
The color field paintings of Barnett Newman, one of the great American abstract expressionist painters, are seminal works of the modern era. They feature large flat fields of vibrant colors intended to allow the viewer to connect with the paintings in immediate, visceral ways. Despite the apparent simplicity of his compositions, Newman considered himself an intuitive painter and allowed his compositions to evolve during the painting process. Two paintings in the Menil Collection, Untitled 2 (1950) and Unfinished Painting [Blue and Brown 1970— #2] (1970) display visual evidence of former states, but attempts to elucidate earlier compositions by X-radiography were inconclusive due to the lack of contrast in paint densities. We applied limited sampling and used a handheld X-ray fluorescence spectrometer in a `scanning' manner to determine the color and composition of the previous states of these paintings to help us better understand their evolution. Newman altered his initial cadmium red and alizarin composition in Untitled 2 (1950) by overpainting the alizarin region with a wider band of Mars black paint. He then modulated the surface of the black by partially covering it with a carbonaceous black with a different gloss. For Unfinished Painting [Blue and Brown 1970— #2] (1970), Newman not only changed the cadmium red to an umber but simplified the composition, removing multiple zips and refining it to its current monumental state. This evidence of Newman's decision-making processes permits a tantalizing glimpse of the artist consistently looking both ahead and backward, experimenting and revisiting.
Wind impact on the Black Sea ecosystem
NASA Astrophysics Data System (ADS)
Stanichny, Sergey; Ratner, Yuriy; Shokurov, Mike; Stanychna, Rimma; Soloviev, Dmytro; Burdyugov, Vyacheslav
2010-05-01
Combination of the recent satellite and meteorological data for the regional investigation allowed to describe new features of the processes in marine ecosystem and detect some relations with wind variability for different time scales. Next topics are highlighted in presentation: 1. Inter-annual variability of the wind stress curl over the Black Sea. Shift in the atmospheric processes after 2003 year and related variations in chlorophyll concentration and intensity of the mesoscale currents. 2. Like-tropical cyclone in September 2005 and its impact o the Black Sea upper layer. 3. Strong storm November 11, 2007 and oil pollutions of the Kerch Strait. 4. Relation of the Danube waters transport with wind fields for summer 2007 and 2008. 5. "Valley" wind in the Eastern part of the Black Sea and its impact on the Rim current formation. 6. Low wind conditions and blue -green algae bloom. NCEP, SKIRON and MHI MM5 wind data together with AVHRR, MODIS, MERIS, ETM+, QuikSCAT, ASAR (ESA) satellite data were used for investigation. Work was done with support of the SESAME FP7, "Stable Ecosystem" and Operational Oceanography NASU projects.
Resolution for color photography
NASA Astrophysics Data System (ADS)
Hubel, Paul M.; Bautsch, Markus
2006-02-01
Although it is well known that luminance resolution is most important, the ability to accurately render colored details, color textures, and colored fabrics cannot be overlooked. This includes the ability to accurately render single-pixel color details as well as avoiding color aliasing. All consumer digital cameras on the market today record in color and the scenes people are photographing are usually color. Yet almost all resolution measurements made on color cameras are done using a black and white target. In this paper we present several methods for measuring and quantifying color resolution. The first method, detailed in a previous publication, uses a slanted-edge target of two colored surfaces in place of the standard black and white edge pattern. The second method employs the standard black and white targets recommended in the ISO standard, but records these onto the camera through colored filters thus giving modulation between black and one particular color component; red, green, and blue color separation filters are used in this study. The third method, conducted at Stiftung Warentest, an independent consumer organization of Germany, uses a whitelight interferometer to generate fringe pattern targets of varying color and spatial frequency.
In vivo imaging of sulfotransferases
Barrio, Jorge R; Kepe, Vladimir; Small, Gary W; Satyamurthy, Nagichettiar
2013-02-12
Radiolabeled tracers for sulfotransferases (SULTs), their synthesis, and their use are provided. Included are substituted phenols, naphthols, coumarins, and flavones radiolabeled with .sup.18F, .sup.123I, .sup.124I, .sup.125I, or .sup.11C. Also provided are in vivo techniques for using these and other tracers as analytical and diagnostic tools to study sulfotransferase distribution and activity, in health and disease, and to evaluate therapeutic interventions.
Kamal, Atif; Cincinelli, Alessandra; Martellini, Tania; Malik, Riffat Naseem
2016-01-01
The aim of this study was to evaluate and compare the exposure of household women and professional male workers to combustion emission in the indoor and semi-outdoor environments, respectively, by using biochemical parameters and the biomarkers of exposure to polycyclic aromatic hydrocarbon (PAH). Female (WR n = 60) and male "cooks" (WC n = 60) exposed to the combustion emission of fuel wood and coal in rural/suburban areas of Pakistan were recruited in this study and compared to non-exposed female (CF) and male (CM) groups (n = 32 and 34, respectively). Urinary biomarkers of PAH exposure including 1-hyroxypyrene (1-OHPyr), α-naphthol, and β-naphthol were analyzed together with the biomarkers of effect, including the serum c-reactive proteins (CRP), white blood cells (WBCs), hemoglobin (Hb), red blood cells (RBC), and platelet (PLT) count. In addition, blood superoxide dismutase (SOD) and urinary level of 8-hydroxydeoxyguanosine (8-OHdG) were evaluated to determine the oxidative stress and DNA damage, respectively. A questionnaire was used to document demographic-, health-, and exposure-related information. The results showed that urinary β-naphthol was almost 44% higher in WR subjects than WC (median 7.69 vs. 3.39 μmol/mol-Cr, respectively; p = 0.01) and respective controls (CF). Higher urinary 8-OHdG were observed in WR (71.1 ng/mg-Cr) than WC (56.37 ng/mg-Cr) (p < 0.001), and lower life status and higher degree of headache were observed in WR than WC. In WCs, however, a low Hb and high WBC (8.29 × 10(3) μL(-1), ranging between 6.1 and 10.6 × 10(3) μL(-1)) were observed in comparison with CM. The study shows that WC subjects used larger amount of fuel and were subjected to prolonged exposure. It was concluded that the role of ventilation is fundamental and WR were more exposed to PAHs despite the fact that WC spent more time in cooking (due to occupational requirement) than WR.
NASA Astrophysics Data System (ADS)
Garrote, M. A.; Robador, M. D.; Perez-Rodriguez, J. L.
2017-02-01
The pigments, execution technique and repainting used on the polychrome wood ceilings and doors in the Casa de Pilatos (Seville, Spain) were studied using portable X-ray fluorescence equipment. Cross-sections of small samples were also analysed by optical microscopy, SEM with EDX analysis, micro-Raman and micro-infrared spectroscopy and X-ray diffraction. These carpentry works are magnificent examples of the Mudéjar art made in Spain in the early 16th century. Portable X-ray fluorescence gave good information on the different components of the polychrome. The SEM-EDX study of the surfaces of small samples gave information on their components and also characterized the compounds that had been deposited or formed by environmental contamination or by the alteration of some pigments. The SEM-EDX study of cross-sections facilitated the characterization of all layers and pigments from the support to the most external layer. The following pigments were characterized: red (cinnabar/vermillion, lead oxide, iron oxides and orpiment/realgar), black (carbon black), white (white lead and titanium barium white), yellow-orange-red-brown (orpiment/realgar and iron oxides), green (chromium oxide), blue (indigo blue and ultramarine blue), and gilding (gold leaf on bole). False gold, bronze and brass were also found. The pigments were applied with the oil painting technique over a support layer that had been primed with animal glue. This support layer was gypsum in some cases and white lead in others. This study is essential to the polychrome conservation of the studied artwork, and it will help clarify uncertainties in the history and painting of Mudéjar art.
Garrote, M A; Robador, M D; Perez-Rodriguez, J L
2017-02-15
The pigments, execution technique and repainting used on the polychrome wood ceilings and doors in the Casa de Pilatos (Seville, Spain) were studied using portable X-ray fluorescence equipment. Cross-sections of small samples were also analysed by optical microscopy, SEM with EDX analysis, micro-Raman and micro-infrared spectroscopy and X-ray diffraction. These carpentry works are magnificent examples of the Mudéjar art made in Spain in the early 16th century. Portable X-ray fluorescence gave good information on the different components of the polychrome. The SEM-EDX study of the surfaces of small samples gave information on their components and also characterized the compounds that had been deposited or formed by environmental contamination or by the alteration of some pigments. The SEM-EDX study of cross-sections facilitated the characterization of all layers and pigments from the support to the most external layer. The following pigments were characterized: red (cinnabar/vermillion, lead oxide, iron oxides and orpiment/realgar), black (carbon black), white (white lead and titanium barium white), yellow-orange-red-brown (orpiment/realgar and iron oxides), green (chromium oxide), blue (indigo blue and ultramarine blue), and gilding (gold leaf on bole). False gold, bronze and brass were also found. The pigments were applied with the oil painting technique over a support layer that had been primed with animal glue. This support layer was gypsum in some cases and white lead in others. This study is essential to the polychrome conservation of the studied artwork, and it will help clarify uncertainties in the history and painting of Mudéjar art. Copyright © 2016 Elsevier B.V. All rights reserved.
Bright vigorous winds as signposts of supermassive black hole birth
NASA Astrophysics Data System (ADS)
Fiacconi, Davide; Rossi, Elena M.
2016-01-01
The formation of supermassive black holes is still an outstanding question. In the quasi-star scenario, black hole seeds experience an initial super-Eddington growth, that in less than a million years may leave a 104-105 M⊙ black hole at the centre of a protogalaxy at z ˜ 20-10. Super-Eddington accretion, however, may be accompanied by vigorous mass-loss that can limit the amount of mass that reaches the black hole. In this paper, we critically assess the impact of radiative driven winds, launched from the surface of the massive envelopes from which the black hole accretes. Solving the full wind equations coupled with the hydrostatic structure of the envelope, we find mass outflows with rates between a few tens and 104 M⊙ yr-1, mainly powered by advection luminosity within the outflow. We therefore confirm the claim by Dotan et al. that mass losses can severely affect the black hole seed early growth within a quasi-star. In particular, seeds with mass >104 M⊙ can only form within mass reservoirs ≳107 M⊙, unless they are refilled at huge rates (≳100 M⊙ yr-1). This may imply that only very massive haloes (>109 M⊙) at those redshifts can harbour massive seeds. Contrary to previous claims, these winds are expected to be relatively bright (1044-1047 erg s-1), blue (Teff ˜ 8000 K) objects, that while eluding the Hubble Space Telescope, could be observed by the James Webb Space Telescope.
Nonthermal WIMPs and primordial black holes
NASA Astrophysics Data System (ADS)
Georg, Julian; Şengör, Gizem; Watson, Scott
2016-06-01
Nonthermal histories for the early universe have received notable attention as they are a rich source of phenomenology, while also being well motivated by top-down approaches to beyond the Standard Model physics. The early (pre-big bang nucleosynthesis) matter phase in these models leads to enhanced growth of density perturbations on sub-Hubble scales. Here, we consider whether primordial black hole formation associated with the enhanced growth is in conflict with existing observations. Such constraints depend on the tilt of the primordial power spectrum, and we find that nonthermal histories are tightly constrained in the case of a significantly blue spectrum. Alternatively, if dark matter is taken to be of nonthermal origin, we can restrict the primordial power spectrum on scales inaccessible to cosmic microwave background and large scale structure observations. We establish constraints for a wide range of scalar masses (reheat temperatures) with the most stringent bounds resulting from the formation of 1015 g black holes. These black holes would be evaporating today and are constrained by FERMI observations. We also consider whether the breakdown of the coherence of the scalar oscillations on subhorizon scales can lead to a Jean's pressure preventing black hole formation and relaxing our constraints. Our main conclusion is that primordial black hole constraints, combined with existing constraints on nonthermal weakly interacting massive particles, favor a primordial spectrum closer to scale invariance or a red tilted spectrum.
Lindh, Jenny M.; Goswami, Parikshit; Blackburn, Richard S.; Arnold, Sarah E. J.; Vale, Glyn A.; Lehane, Mike J.; Torr, Steve J.
2012-01-01
Background Most cases of human African trypanosomiasis (HAT) start with a bite from one of the subspecies of Glossina fuscipes. Tsetse use a range of olfactory and visual stimuli to locate their hosts and this response can be exploited to lure tsetse to insecticide-treated targets thereby reducing transmission. To provide a rational basis for cost-effective designs of target, we undertook studies to identify the optimal target colour. Methodology/Principal Findings On the Chamaunga islands of Lake Victoria , Kenya, studies were made of the numbers of G. fuscipes fuscipes attracted to targets consisting of a panel (25 cm square) of various coloured fabrics flanked by a panel (also 25 cm square) of fine black netting. Both panels were covered with an electrocuting grid to catch tsetse as they contacted the target. The reflectances of the 37 different-coloured cloth panels utilised in the study were measured spectrophotometrically. Catch was positively correlated with percentage reflectance at the blue (460 nm) wavelength and negatively correlated with reflectance at UV (360 nm) and green (520 nm) wavelengths. The best target was subjectively blue, with percentage reflectances of 3%, 29%, and 20% at 360 nm, 460 nm and 520 nm respectively. The worst target was also, subjectively, blue, but with high reflectances at UV (35% reflectance at 360 nm) wavelengths as well as blue (36% reflectance at 460 nm); the best low UV-reflecting blue caught 3× more tsetse than the high UV-reflecting blue. Conclusions/Significance Insecticide-treated targets to control G. f. fuscipes should be blue with low reflectance in both the UV and green bands of the spectrum. Targets that are subjectively blue will perform poorly if they also reflect UV strongly. The selection of fabrics for targets should be guided by spectral analysis of the cloth across both the spectrum visible to humans and the UV region. PMID:22666511
Rick G. Kelsey; Walter G. Thies; Craig L. Schmitt
2006-01-01
A total of 284 ponderosa pine growing near the southern edge of the Blue Mountains in eastern Oregon were categorized into one of three crown classes based on the degree of "tufted", or "lion's tail" appearance of their branches, a potential symptom of black-stain root disease, then pushed over and their root systems examined for visual...
The Cognitive Battlefield: A Framework for Strategic Communications
2011-12-01
York: Alfred A. Knopf Publishers, 1993), 83. 35 Richard Ned Lebow, “Thucydides and Deterrence,” Security Studies, 16:2, 163-188. 36 Brayton Harris...University Press of Kansas, 2004. Harris, Brayton . Blue & Gray in Black & White: Newspapers in the Civil War. Washington DC: Brassey’s Inc...Army Capabilities. Santa Monica, CA: Rand Arroyo Center, 2009. Lebel, Udi. Communicating Security. New York, Routledge Taylor and Francis Group, 2008
Environmental Assessment for Demolition of Building 2148 and Construction of a New Facility
2004-02-01
Athene cunicularia SP Caspian Tern Sterna caspia SP Ferruginous Hawk Buteo regalis T Grasshopper Sparrow Ammodramus savannarum SP/SD Lewis’ Woodpecker...northern latitudes winter along streams and lakes throughout Utah and have been observed at the Weber River just north of the Base. Willow Flycatchers...Pelecanus erythrorhynchos SD Black Tern Chlidonias niger SP Blue Grosbeak Guiraca caerulea SP/SD Bobolink Dolichonyx oryzivorus SP/SD Burrowing Owl
1995-03-13
The STS-70 crew patch depicts the Space Shuttle Discovery orbiting Earth in the vast blackness of space. The primary mission of deploying a NASA Tracking and Data Relay Satellite (TDRS) is depicted by three gold stars. They represent the triad composed of spacecraft transmitting data to Earth through the TDRS system. The stylized red, white, and blue ribbon represents the American goal of linking space exploration to the advancement of all humankind.
Jonathan Thompson
2006-01-01
In the mid-1990s, forest managers on the Malheur National Forest were concerned about their prescribed fire program. Although they have only a few weeks of acceptable conditions available in the spring and fall, they were worried that spring-season prescribed burning might be exacerbating black stain root disease and having negative effects on understory plants.
36 CFR 294.29 - List of designated Idaho Roadless Areas.
Code of Federal Regulations, 2014 CFR
2014-07-01
...-Spring Creek 111 X X X X Caribou Gibson 181 X X Caribou Hell Hole 168 X X Caribou Huckleberry Basin 165 X... Mink 151 X X X Caribou Williams Creek 174 X X X Caribou Worm Creek 170 X X X Challis Blue Bunch... Mountain 902 X Salmon West Big Hole 943 X X X X Salmon West Panther Creek 504 X Sawtooth Black Pine 003 X X...
Code of Federal Regulations, 2013 CFR
2013-01-01
...″ —Bruises 1/4″ to 1″ that have changed from red to a black/blue or green color due to age. —Factor is two..., except at the time of post-mortem inspection, unless their identify with the rest of the carcass is maintained in a manner satisfactory to the inspector until such inspection is made. Each carcass to be...
2013-06-01
gathering and maintaining the data needed , and completing and reviewing the collection of information. Send comments regarding this burden estimate or...undersigned certify that this thesis meets master’s-level standards or research, argumentation , and expression...this question through the lenses of organizational culture, cognitive reasoning, and physical representation, this study illuminates how the Air
78 FR 38952 - Procurement List; Proposed Additions to and Deletions
Federal Register 2010, 2011, 2012, 2013, 2014
2013-06-28
...: This notice is published pursuant to 41 U.S.C. 8503 (a)(2) and 41 CFR 51-2.3. Its purpose is to provide...: 7510-00-NIB-9832--Portable Desktop Clipboard, 10'' W x 2-3/5'' D x 16'' H, Black. NSN: 7510-00-NIB-9833--Portable Desktop Clipboard, 10'' W x 2-3/5'' D x 16'' H, Blue. NSN: 7510-00-NIB-9851--Portable Desktop...
Chemical ecology and behavioral studies on the emerald ash borer: an update
Deepa Pureswaran; Therese Poland
2008-01-01
In 2006, we tested host selection and feeding preference of the emerald ash borer (EAB) on four species of ash species (green, black, white, and blue ash) that are native to North America but exotic to the beetle. For comparison, we also included Manchurian ash (which is native to the beetle) and European ash (which is exotic to the beetle) in the test. Beetles were...
Revealing Companions to Nearby Stars with Astrometric Acceleration
2012-07-01
objects, such as stellar -mass black holes or failed supernova (Gould & Salim 2002). Table 4 includes a sample of some of the most interesting dis...knowledge of binary and multiple star statistics is needed for the study of star formation, for stellar population synthesis, for predicting the...frequency of supernovae, blue stragglers, X-ray binaries, etc. The statistical properties of binaries strongly depend on stellar mass. Only for nearby solar
Sellers translates along the S1 Truss during EVA3 on STS-121 / Expedition 13 joint operations
2006-07-12
S121-E-07413 (12 July 2006) --- Astronaut Piers J. Sellers, STS-121 mission specialist, translates along a truss on the International Space Station during the mission's third and final session of extravehicular activity (EVA) while Space Shuttle Discovery was docked with the station. A blue and white Earth and the blackness of space form the backdrop for the image.
Inorganic Substrates and Encapsulation Layers for Transient Electronics
2014-07-01
surface oxidation of the nitrides, the measurements were conducted shortly after oxide removal in buffered oxide etchant (BOE) 6:1 (Transene Company Inc...values for the time-dependent dissolution of thermally grown SiO2 (dry oxidation) in buffer solutions (black, pH 7.4; red, pH 8; blue, pH 10...22 5.1.3 Contractor will Identify and Measure Key Performance Characteristics of Candidate Metal Conductive Layers for
Picosecond lasers for tattoo removal: a systematic review.
Reiter, Ofer; Atzmony, Lihi; Akerman, Lehavit; Levi, Assi; Kershenovich, Ruben; Lapidoth, Moshe; Mimouni, Daniel
2016-09-01
Given that the pigment particles in tattoos have a relaxation time of <10 ns, picosecond lasers would be expected to be more effective than nanosecond lasers in tattoo removal. To systematically review the evidence regarding the effectiveness and safety of picosecond lasers for tattoo removal, Pubmed, Cochrane Central Register of Controlled Trials (CENTRAL), ClinicalTrials.gov, and reference lists were searched for relevant trials. The primary outcome was >70 % clearance of tattoo pigment. Secondary outcomes were 90-100 % clearance of tattoo pigment, number of laser sessions required, and adverse effects. Eight trials were included, six with human participants (160 participants) and 2 with animal models. Seven of the eight trials explored the usage of either 755, 758, 795, 1064, or 1064/532-nm picosecond lasers for black and blue ink tattoos. In the human trials, 69-100 % of tattoos showed over 70 % clearance of pigment after 1-10 laser treatments. Reported side effects included pain, hyperpigmentation and hypopigmentation, blister formation and transient erythema, edema, and pinpoint bleeding. Included articles varied in type of laser investigated, mostly non-comparative studies and with a medium to high risk of bias. There is sparse evidence that picosecond lasers are more effective than their nanosecond counterparts for mainly black and blue ink tattoo removal, with minor side effects.
Accounting for black carbon lowers estimates of blue carbon storage services.
Chew, Swee Theng; Gallagher, John B
2018-02-07
The canopies and roots of seagrass, mangrove, and saltmarsh protect a legacy of buried sedimentary organic carbon from resuspension and remineralisation. This legacy's value, in terms of mitigating anthropogenic emissions of CO 2 , is based on total organic carbon (TOC) inventories to a depth likely to be disturbed. However, failure to subtract allochthonous recalcitrant carbon overvalues the storage service. Simply put, burial of oxidation-resistant organics formed outside of the ecosystem provides no additional protection from remineralisation. Here, we assess whether black carbon (BC), an allochthonous and recalcitrant form of organic carbon, is contributing to a significant overestimation of blue carbon stocks. To test this supposition, BC and TOC contents were measured in different types of seagrass and mangrove sediment cores across tropical and temperate regimes, with different histories of air pollution and fire together with a reanalysis of published data from a subtropical system. The results suggest current carbon stock estimates are positively biased, particularly for low-organic-content sandy seagrass environs, by 18 ± 3% (±95% confidence interval) and 43 ± 21% (±95% CI) for the temperate and tropical regions respectively. The higher BC fractions appear to originate from atmospheric deposition and substantially enrich the relatively low TOC fraction within these environs.
Seeing "the Dress" in the Right Light: Perceived Colors and Inferred Light Sources.
Chetverikov, Andrey; Ivanchei, Ivan
2016-08-01
In the well-known "dress" photograph, people either see the dress as blue with black stripes or as white with golden stripes. We suggest that the perception of colors is guided by the scene interpretation and the inferred positions of light sources. We tested this hypothesis in two online studies using color matching to estimate the colors observers see, while controlling for individual differences in gray point bias and color discrimination. Study 1 demonstrates that the interpretation of the dress corresponds to differences in perceived colors. Moreover, people who perceive the dress as blue-and-black are two times more likely to consider the light source as frontal, than those who see the white-and-gold dress. The inferred light sources, in turn, depend on the circadian changes in ambient light. The interpretation of the scene background as a wall or a mirror is consistent with the perceived colors as well. Study 2 shows that matching provides reliable results on differing devices and replicates the findings on scene interpretation and light sources. Additionally, we show that participants' environmental lighting conditions are an important cue for perceiving the dress colors. The exact mechanisms of how environmental lighting and circadian changes influence the perceived colors of the dress deserve further investigation.
SOLAR - ASTRONOMY (APOLLO-SATURN [AS]-16)
1972-05-09
S72-36972 (21 April 1972) --- A color enhancement of a far-ultraviolet photo of Earth taken by astronaut John W. Young, commander, with the ultraviolet camera on April 21, 1972. The original black and white photo was printed on Agfacontour film three times, each exposure recording only one light level. The three light levels were then colored blue (dimmest), green (next brightest), and red (brightest). The three auroral belts, the sunlit atmosphere and the background stars (one very close to Earth, on left) can be studied quantitatively fro brightness. The UV camera was designed and built at the Naval Research Laboratory, Washington, D.C. EDITOR'S NOTE: The photographic number of the original black & white UV camera photograph from which this enhancement was made is AS16-123-19657.
Extent of California Blue Cut Fire Devastation Seen by NASA Spacecraft
2016-09-07
In San Bernardino County, California, the Blue Cut fire burned ferociously for one week starting Aug. 16, 2016. By the time it was contained, it had burned 36,000 acres and destroyed 105 homes. More than 80,000 people were affected by evacuation orders. Ten days after containment, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument on NASA's Terra spacecraft captured this image of the region, highlighting the extent of the damage. Healthy vegetation is depicted in red, with burnt areas in the mountains and fields shown in shades of black. The image, acquired Sept. 3, covers an area of 14 by 17 miles (22 by 27 kilometers), and is located at 34.3 degrees north, 117.5 degrees west. http://photojournal.jpl.nasa.gov/catalog/PIA20899
2013-12-23
Winter is approaching in the southern hemisphere of Saturn and with this cold season has come the familiar blue hue that was present in the northern winter hemisphere at the start of NASA's Cassini mission. The changing blue hue that we have learned marks winter at Saturn is likely due to reduction of ultraviolet sunlight and the haze it produces, making the atmosphere clearer and increasing the opportunity for Rayleigh scattering (scattering by molecules and smaller particles) and methane absorption: both processes make the atmosphere blue. The small black dot seen to the right and up from image center, within the ring shadows of the A and F rings, is the shadow of the moon, Prometheus. For an image showing winter in the northern hemisphere see PIA08166. This view looks toward the unilluminated side of the rings from about 44 degrees below the ring plane. Images taken using red, green and blue spectral filters were combined to create this natural color view. The images were taken with the Cassini spacecraft wide-angle camera on July 29, 2013. This view was acquired at a distance of approximately 1.003 million miles (1.615 million kilometers) from Saturn. Image scale is 58 miles (93 kilometers) per pixel. http://photojournal.jpl.nasa.gov/catalog/PIA17176
Black Hole Spills Kaleidoscope of Color
NASA Technical Reports Server (NTRS)
2006-01-01
This new false-colored image from NASA's Hubble, Chandra and Spitzer space telescopes shows a giant jet of particles that has been shot out from the vicinity of a type of supermassive black hole called a quasar. The jet is enormous, stretching across more than 100,000 light-years of space -- a size comparable to our own Milky Way galaxy! Quasars are among the brightest objects in the universe. They consist of supermassive black holes surrounded by turbulent material, which is being heated up as it is dragged toward the black hole. This hot material glows brilliantly, and some of it gets blown off into space in the form of powerful jets. The jet pictured here is streaming out from the first known quasar, called 3C273, discovered in 1963. A kaleidoscope of colors represents the jet's assorted light waves. X-rays, the highest-energy light in the image, are shown at the far left in blue (the black hole itself is well to the left of the image). The X-rays were captured by Chandra. As you move from left to right, the light diminishes in energy, and wavelengths increase in size. Visible light recorded by Hubble is displayed in green, while infrared light caught by Spitzer is red. Areas where visible and infrared light overlap appear yellow.Immobilization of cardioprotective drug phosphocreatine on a surface of nanoparticles of silica
NASA Astrophysics Data System (ADS)
Korolev, D. V.; Evreinova, N. V.; Zakharova, E. V.; Gareev, K. G.; Naumysheva, E. B.; Postnov, V. N.; Galagudza, M. M.
2017-11-01
In this work silica aminated nanoparticles were used to show capability for chemisorbing organic compound having a carboxyl group. Phosphocreatine (creatine phosphate) was used as an active ingredient. Since the method for determination of phosphocreatine with the sample analysis using Jaffe reaction didn’t give a positive result, the definition of free phosphocreatine was carried out by the method of diacetyl in the presence of α-naphthol.
RADIATION DOSIMETER AND DOSIMETRIC METHODS
Taplin, G.V.
1958-10-28
The determination of ionizing radiation by means of single fluid phase chemical dosimeters of the colorimetric type is presented. A single fluid composition is used consisting of a chlorinated hydrocarbon, an acidimetric dye, a normalizer and water. Suitable chlorinated hydrocarbons are carbon tetrachloride, chloroform, trichloroethylene, trichlorethane, ethylene dichioride and tetracbloroethylene. Suitable acidimetric indicator dyes are phenol red, bromcresol purple, and creosol red. Suitable normallzers are resorcinol, geraniol, meta cresol, alpha -tocopberol, and alpha -naphthol.
Das, Laboni; Chatterjee, Suchandra; Naik, Devidas B; Adhikari, Soumyakanti
2015-11-15
A combined methodology involving gamma and pulse radiolysis, product analysis and toxicity studies has been adopted to comprehend the degradation process of a model hydrophobic azo dye, 1-phenylazo-2-naphthol, emphasizing the role of the surfactant, which is an integral part of textile waste. Two new and important findings are underlined in this article. The first is the direct attestation of the hydrazyl radical-parent adduct, formed in the reaction of the dye with e(-)aq followed by protonation and subsequent addition to the unreacted dye molecule. This has been confirmed from concentration dependent studies. Secondly, we have clearly shown that in the reaction of hydroxyl radical with the dye in Triton X-100 media, the initially produced TX radicals cause reductive degradation of the dye. Identification and detailed analysis of HPLC and GCMS data reveals that similar products are formed in both the reactions of e(-)aq and OH radicals. Moreover, the cytotoxicity of 10(-4)moldm(-3) dye was found to be reduced significantly after irradiation. Thus, the present study not only depicts new pathways for the degradation of hydrophobic azo dye, but also demonstrates the role of a surfactant in the entire process. Copyright © 2015 Elsevier B.V. All rights reserved.
Naphthol-based fluorescent sensors for aluminium ion and application to bioimaging
NASA Astrophysics Data System (ADS)
Liu, Bin; Wang, Pan-feng; Chai, Jie; Hu, Xiang-quan; Gao, Tingting; Chao, Jian-bin; Chen, Ting-gui; Yang, Bin-sheng
2016-11-01
Three naphthol Schiff base-type fluorescent sensors, 1,3-Bis(2-hydroxy-1-naphthylideneamino)propane (L1), 1,3-Bis(1-naphthylideneamino)-2-hydroxypropane (L2) and 1,3-Bis(2-hydroxy-1-naphthylideneamino)-2-hydroxypropane (L3), have been synthesized. Their recognition abilities for Al3 + are studied by fluorescence spectra. Coordination with Al3 + inhibited the Cdbnd N isomerization of Schiff base which intensely increase the fluorescence of L1-L3. Possessing a suitable space coordination structure, L3 is a best selective probe for Al3 + over other metal ions in MeOH-HEPES buffer (3/7, V/V, pH = 6.6, 25 °C, λem = 435 nm). A turn-on ratio over 140-fold is triggered with the addition of 1.0 equiv. Al3 + to L3. The binding constant Ka of L3-Al3 + is found to be 1.01 × 106.5 M- 1 in a 1:1 complex mode. The detection limit for Al3 + is 0.05 μM. Theoretical calculations have also been included in support of the configuration of the L3-Al3 + complex. Importantly, the probe L3 has been successfully used for fluorescence imaging in colon cancer SW480 cells.
Alothman, Zeid A; Yilmaz, Erkan; Habila, Mohamed; Soylak, Mustafa
2015-02-01
1-(2-Pyridylazo)-2-naphthol impregnated activated carbon cloth (PAN-imp-ACC) was prepared as a solid phase sorbent and, for the first time, was used for the simultaneous separation and preconcentration of trace amounts of lead, cadmium and nickel in water, soil and sewage sludge samples prior to determination by flame atomic absorption spectrometry (FAAS). The parameters governing the efficiency of the method were optimized, including the pH, the eluent type and volume, the sample and eluent flow rates, diverse ions effects and the sample volume. A preconcentration factor of 100 was achieved for all the metal ions, with detection limits of 0.1-2.8 µg L(-1) and relative standard deviations below 6.3%. The adsorption capacity of the PAN-imp-ACC for Pb(II), Cd(II) and Ni(II) ions was found to be 45.0 mg g(-1), 45.0 mg g(-1) and 43.2 mg g(-1), respectively. The method was validated by the analysis of the certified reference materials TMDA-64.2 fortified Lake Ontario water and BCR-146R Sewage Sludge Amended Soil (Industrial Origin). The procedure was applied to determine the analytes content in real samples. Copyright © 2014 Elsevier Inc. All rights reserved.
Li, Yanqing; Liu, Qian; Yao, Shouzhuo
2008-05-15
The cationic double-chained surfactant didodecyldimethylammonium bromide (DDAB) was used as pseudostationary phase (PSP) in micellar electrokinetic capillary chromatography (MEKC). Its performance on the three kinds of drugs, i.e., basic, acidic, and neutral drugs, was systematically investigated. Nicotine, cotinine, caffeine, lidocaine, and procaine were selected as the model basic drugs. Good baseline separation and high efficiency were obtained under the optimal separation condition that consisted of 50mM phosphate (pH 4.0) and 0.08 mM DDAB. Three basic phenylenediamine isomers can also be well separated with DDAB in buffer. In addition, DDAB can form cationic bilayer on the capillary wall, thus the wall adsorption of basic analytes was greatly suppressed. Compared with commonly used CTAB, the separation of basic drugs was significantly improved with a much lower amount of DDAB present in the buffer. The DDAB-involved MEKC also showed superiority to CTAB upon the separation of acidic drugs, amoxicillin and ampicillin. In the case of neutral compounds, a good separation of resorcinol, 1-naphthol and 2-naphthol was achieved with 0.1mM DDAB and 30% (v/v) acetonitrile (ACN) present in buffer. Hence, it was concluded that the double-chained cationic surfactant DDAB can be a good substitute for traditional single-chained surfactant CTAB in MEKC.
Bosten, J. M.; Beer, R. D.; MacLeod, D. I. A.
2015-01-01
To shed light on the perceptual basis of the color white, we measured settings of unique white in a dark surround. We find that settings reliably show more variability in an oblique (blue-yellow) direction in color space than along the cardinal axes of the cone-opponent mechanisms. This is against the idea that white perception arises at the null point of the cone-opponent mechanisms, but one alternative possibility is that it occurs through calibration to the visual environment. We found that the locus of maximum variability in settings lies close to the locus of natural daylights, suggesting that variability may result from uncertainty about the color of the illuminant. We tested this by manipulating uncertainty. First, we altered the extent to which the task was absolute (requiring knowledge of the illumination) or relative. We found no clear effect of this factor on the reduction in sensitivity in the blue-yellow direction. Second, we provided a white surround as a cue to the illumination or left the surround dark. Sensitivity was selectively worse in the blue-yellow direction when the surround was black than when it was white. Our results can be functionally related to the statistics of natural images, where a greater blue-yellow dispersion is characteristic of both reflectances (where anisotropy is weak) and illuminants (where it is very pronounced). Mechanistically, the results could suggest a neural signal responsive to deviations from the blue-yellow locus or an adaptively matched range of contrast response functions for signals that encode different directions in color space. PMID:26641948
Volcan, Matheus Vieira; Klotzel, Bruno; Lanés, Luis Esteban Krause
2017-02-21
Two new species of the genus Melanorivulus are herein described from the middle Rio Verde drainage, upper Rio Paraná basin, Mato Grosso do Sul, Brazil. Both new species are members of the Melanorivulus pictus clade, diagnosed by having ventral process of angulo-articular vestigial and flanks intense greenish blue or greenish golden to purplish blue above anal fin base in males. Melanorivulus nigropunctatus, new species, from wetlands of a small drainage tributary of right side of the Rio Verde, differs from all other congeners by possessing black dots over the head and body in both sexes and pectoral fin orange with a dark grey margin in males. Melanorivulus ofaie, new species, is found in a similar environment, but at the opposite margin of the Rio Verde. It is distinguished by males presenting flank greenish blue to light blue, with seven to nine oblique chevron-like red bars, ventral portion of head whitish with dark brown spots, dorsal fin yellow with two to three transverse broad red oblique stripes and distal region red, anal fin light orangish yellow, basal area light blue with short red bars and distal portion with a dark red margin, and caudal fin yellow or orangish yellow with three to four vertical red bars in the dorsal and middle portions, sometimes with a orange distal margin. Both new species are considered endangered due to the loss and degradation of their habitat.
Biomolecule-assisted hydrothermal synthesis of silver bismuth sulfide with nanostructures
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kaowphong, Sulawan, E-mail: sulawank@gmail.com; Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200
2012-05-15
Silver bismuth sulfide (AgBiS{sub 2}) nanostructures were successfully prepared via a simple biomolecule-assisted hydrothermal synthesis at 200 Degree-Sign C for 12-72 h. Silver nitrate, bismuth nitrate and L-cysteine were used as starting materials. Here, the biomolecule, L-cysteine, was served as the sulfide source and a complexing agent. The products, characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), were cubic AgBiS{sub 2} nanoparticles with a diameter range of about 20-75 nm. It was found that their crystallinity and particle size increased with increasing reaction time. The energy dispersive X-ray spectroscopy (EDX) and inductively coupledmore » plasma optical emission spectrophotometry (ICP-OES) analyses were used to confirm the stoichiometry of AgBiS{sub 2}. The optical band gap of the AgBiS{sub 2} nanoparticles, calculated from UV-vis spectra, was 3.0 eV which indicated a strong blue shift because of the quantum confinement effect. A possible formation mechanism of the AgBiS{sub 2} nanoparticles was also discussed. - Graphical abstract: The optical band gap of the as-prepared AgBiS{sub 2} nanoparticles displays a strong blue shift comparing to the 2.46 eV of bulk AgBiS{sub 2} caused by the quantum confinement effects. Highlights: Black-Right-Pointing-Pointer A simple biomolecule-assisted hydrothermal method is developed to prepare AgBiS{sub 2}. Black-Right-Pointing-Pointer L-Cysteine is served as the sulfide source and a complexing agent. Black-Right-Pointing-Pointer Increase in band gap of the AgBiS{sub 2} nanoparticles attributes to the quantum confinement effects.« less
NASA Astrophysics Data System (ADS)
Bower, Richard G.; Schaye, Joop; Frenk, Carlos S.; Theuns, Tom; Schaller, Matthieu; Crain, Robert A.; McAlpine, Stuart
2017-02-01
Galaxies fall into two clearly distinct types: `blue-sequence' galaxies which are rapidly forming young stars, and `red-sequence' galaxies in which star formation has almost completely ceased. Most galaxies more massive than 3 × 1010 M⊙ follow the red sequence, while less massive central galaxies lie on the blue sequence. We show that these sequences are created by a competition between star formation-driven outflows and gas accretion on to the supermassive black hole at the galaxy's centre. We develop a simple analytic model for this interaction. In galaxies less massive than 3 × 1010 M⊙, young stars and supernovae drive a high-entropy outflow which is more buoyant than any tenuous corona. The outflow balances the rate of gas inflow, preventing high gas densities building up in the central regions. More massive galaxies, however, are surrounded by an increasingly hot corona. Above a halo mass of ˜1012 M⊙, the outflow ceases to be buoyant and star formation is unable to prevent the build-up of gas in the central regions. This triggers a strongly non-linear response from the black hole. Its accretion rate rises rapidly, heating the galaxy's corona, disrupting the incoming supply of cool gas and starving the galaxy of the fuel for star formation. The host galaxy makes a transition to the red sequence, and further growth predominantly occurs through galaxy mergers. We show that the analytic model provides a good description of galaxy evolution in the EAGLE hydrodynamic simulations. So long as star formation-driven outflows are present, the transition mass scale is almost independent of subgrid parameter choice.
Goldring, J P Dean
2015-01-01
Proteins bind to nitrocellulose membranes when applied directly or after electrophoretic transfer from polyacrylamide electrophoresis gels. Proteins can be stained for visualization with organic dyes Ponceau S, amido black, Coomassie Blue, and colloidal silver/gold and the intensity of the stain is directly proportional to the amount of protein present. Chemicals that interfere with dye/protein interactions in solution can be removed by washing the nitrocellulose after protein application. A method is described whereby protein-dye complexes attached to the nitrocellulose can be solubilized, dissolving the nitrocellulose and releasing dye into solution for detection by a spectrophotometer. The concentration of the dyes Ponceau S, amido black, and colloidal silver is proportional to the concentration of protein. Proteins transferred electrophoretically from SDS-PAGE, isoelectric focusing, or 2D gels to nitrocellulose can be stained with amido black, protein bands excised, and the bound dye detected in a spectrophotometer to quantify proteins in the individual protein bands.
Straightforward fabrication of black nano silica dusting powder for latent fingerprint imaging
NASA Astrophysics Data System (ADS)
Komalasari, Isna; Krismastuti, Fransiska Sri Herwahyu; Elishian, Christine; Handayani, Eka Mardika; Nugraha, Willy Cahya; Ketrin, Rosi
2017-11-01
Imaging of latent fingerprint pattern (aka fingermark) is one of the most important and accurate detection methods in forensic investigation because of the characteristic of individual fingerprint. This detection technique relies on the mechanical adherence of fingerprint powder to the moisture and oily component of the skin left on the surface. The particle size of fingerprint powder is one of the critical parameter to obtain excellent fingerprint image. This study develops a simple, cheap and straightforward method to fabricate Nano size black dusting fingerprint powder based on Nano silica and applies the powder to visualize latent fingerprint. The nanostructured silica was prepared from tetraethoxysilane (TEOS) and then modified with Nano carbon, methylene blue and sodium acetate to color the powder. Finally, as a proof-of-principle, the ability of this black Nano silica dusting powder to image latent fingerprint is successfully demonstrated and the results show that this fingerprint powder provides clearer fingerprint pattern compared to the commercial one highlighting the potential application of the nanostructured silica in forensic science.
Effect of black carbon on dust property retrievals from satellite observations
NASA Astrophysics Data System (ADS)
Lin, Tang-Huang; Yang, Ping; Yi, Bingqi
2013-01-01
The effect of black carbon on the optical properties of polluted mineral dust is studied from a satellite remote-sensing perspective. By including the auxiliary data of surface reflectivity and aerosol mixing weight, the optical properties of mineral dust, or more specifically, the aerosol optical depth (AOD) and single-scattering albedo (SSA), can be retrieved with improved accuracy. Precomputed look-up tables based on the principle of the Deep Blue algorithm are utilized in the retrieval. The mean differences between the retrieved results and the corresponding ground-based measurements are smaller than 1% for both AOD and SSA in the case of pure dust. However, the retrievals can be underestimated by as much as 11.9% for AOD and overestimated by up to 4.1% for SSA in the case of polluted dust with an estimated 10% (in terms of the number-density mixing ratio) of soot aggregates if the black carbon effect on dust aerosols is neglected.
Color discrimination, color naming and color preferences in 80-year olds.
Wijk, H; Berg, S; Sivik, L; Steen, B
1999-06-01
The aim of the present study was to investigate color discrimination, color naming and color preference in a random sample of 80-year-old men and women. Knowledge of color perception in old age can be of value when using color contrast, cues and codes in the environment to promote orientation and function. The color naming test indicated that the colors white, black, yellow, red, blue and green promoted recognition to the highest degree among all subjects. A gender-related difference, in favor of women, occurred in naming five of the mixed colors. Women also used more varied color names than men. Color discrimination was easier in the red and yellow area than in the blue and green area. This result correlates positively with visual function on far sight, and negatively with diagnosis of a cataract. The preference order for seven colors put blue, green and red at the top, and brown at the bottom, hence agreeing with earlier studies, and indicating that the preference order for colors remains relatively stable also in old age. This result should be considered when designing environments for old people.
Søndergaard, Jens; Asmund, Gert; Johansen, Poul; Rigét, Frank
2011-06-01
Contamination by lead (Pb) and zinc (Zn) was studied in seawater, sediments, seaweeds and blue mussels near the former Black Angel Pb-Zn Mine in Maarmorilik, West Greenland. The mine operated during the period 1973-90 when mine waste (tailings and later waste rock) was discharged directly into the sea. Metal concentrations peaked during the mining period and Pb and Zn in seawater within the discharge area were measured up to 440 and 790 μg L⁻¹, respectively. Pb in fiord sediments, seaweeds and blue mussels just outside the discharge area were measured in concentrations up to 190, 84 and 2650 and Zn up to 300, 360 and 1190 μg g⁻¹ dry wt., respectively. Within the discharge area, seawater metal concentrations (especially Pb) decreased abruptly after mine closure. Metals concentrations in sediments and biota, however, decreased more slowly and two decades after mine closure seaweeds and blue mussels were still contaminated 12 km from the mine. Copyright © 2011 Elsevier Ltd. All rights reserved.
Influence of background/surrounding area on accuracy of visual color matching.
Dudea, Diana; Gasparik, Cristina; Botos, Alexandra; Alb, Florin; Irimie, Ada; Paravina, Rade D
2016-07-01
Visual shade selection is subjective and influenced by factors that might be operator-dependent or not. The objective was to evaluate influence of observer nonrelated factors (background/surrounding area, and light) and observer-related factors (gender and color competence) on shade-matching quality and to identify the most often mismatched shades in correlation with the background. Ten observers with average or superior color discrimination competence according to ISO TR 28642:2011 were asked to match 48 shade tabs of three VITA Classical shade guides, in a viewing booth under two light sources: D65 and D50. Gray, white, black, red, and light blue background/surrounding area simulated various clinical situations. The results were statistically analyzed using Kruskal-Wallis test and Mann-Whitney U test. Post hoc power analyses and sample size calculations were also conducted. The matching scores ranged between 72.7 % (using blue background) and 85.9 % (using white and black backgrounds). There was a statistically significant difference between matching scores on the five backgrounds (χ (2)(4) = 12.67, p = 0.01). When neutral gray was used as reference, Mann-Whitney U value was statistically significant only for the blue background (U = 107.00, Z = -2.52, p = 0.01). The influence of gender and lighting condition was also assessed, no statistically significance being found, but in both cases, the effect size and the achieved power were small. However, color discrimination competence did influence the results (p < 0.01). Background influenced shade matching results for tabs A3, B3, B4, and D4. Within the limitations of this study, it was concluded that 1. When it comes to the influence of the background/surround area on quality of color matching, no difference among achromatic backgrounds was recorded. Significantly worse results were recorded when the blue background was used. 2. Observers with superior color matching competence performed significantly better than the ones with average competence 3. The most frequently mismatched shade tabs were A3.5, B3, B4, and D4.
NASA Astrophysics Data System (ADS)
Gallagher, Frank Woolsey, III
Many people around the world have observed green light apparently emanating from severe thunderstorms, but until recently there has been no scientific study of the phenomenon. Green thunderstorms have been observed from time to time in association with deep convection or severe weather events. Some skeptics who have not personally observed a green thunderstorm suggest that they are some kind of illusion. The existence of green thunderstorms has been objectively demonstrated by recording spectra of light from thunderstorms using a handheld spectrophotometer. During the spring and summer of 1995 and the spring of 1996 numerous storms were observed and spectra of the light emanating from these storms were recorded. Observations were made both at the ground and aboard research aircraft. Furthermore, time series of spectra were recorded as the observed color of some storms changed from dark blue to a bluish-green. Several hypotheses have been advanced to explain the occurrence of green light in connection with severe storms. Fankhauser gave some observational support to the belief that green light from thunderstorms is possible and believed that the source of the light is from the blue sky penetrating thin regions in the clouds. Fraser believes that light from the setting sun, in combination with the process of scattering by atmospheric molecules, creates the green light associated with severe weather and the thunderstorm acts only as a black backdrop. Unfortunately, no cloud illuminated by the sun is black and the green airlight produced by the Fraser theory is in reality overwhelmed by light reflected by the cloud. Often the unusual coloration has been attributed to hail or to reflection of light from foliage on the ground. The quantitative measurements made during the observation period fail to support these assumptions. We have observed thunderstorms to be green over ground that was not green and we have observed blue thunderstorms over ground that was green. Finally, Bohren believes that reddened sunlight in combination with filtering done by naturally blue-colored water creates green light. Given our observations, this is the most likely explanation for the green light. Our observations and calculations indicate that, depending on the microphysical parameters of the cloud, sunlight transmitted by the cloud may appear green.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yuan, H. C.; Oh, J.; Zhang, Y.
2012-06-01
We report solar cells with both black Si antireflection and SiO2 surface passivation provided by inexpensive liquid-phase chemistry, rather than by conventional vacuum-based techniques. Preliminary cell efficiency has reached 16.4%. Nanoporous black Si antireflection on crystalline Si by aqueous etching promises low surface reflection for high photon utilization, together with lower manufacturing cost compared to vacuum-based antireflection coating. Ag-nanoparticle-assisted black Si etching and post-etching chemical treatment recently developed at NREL enables excellent control over the pore diameter and pore separation. Performance of black Si solar cells, including open-circuit voltage, short-circuit current density, and blue response, has benefited from these improvements.more » Prior to this study, our black Si solar cells were all passivated by thermal SiO2 produced in tube furnaces. Although this passivation is effective, it is not yet ideal for ultra-low-cost manufacturing. In this study, we report, for the first time, the integration of black Si with a proprietary liquid-phase deposition (LPD) passivation from Natcore Technology. The Natcore LPD forms a layer of <10-nm SiO2 on top of the black Si surface in a relatively mild chemical bath at room temperature. We demonstrate black Si solar cells with LPD SiO2 with a spectrum-weighted average reflection lower than 5%, similar to the more costly thermally grown SiO2 approach. However, LPD SiO2 provides somewhat better surface-passivation quality according to the lifetime analysis by the photo-conductivity decay measurement. Moreover, black Si solar cells with LPD SiO2 passivation exhibit higher spectral response at short wavelength compared to those passivated by thermally grown SiO2. With further optimization, the combination of aqueous black Si etching and LPD could provide a pathway for low-cost, high-efficiency crystalline Si solar cells.« less
How Bees Discriminate a Pattern of Two Colours from Its Mirror Image
Horridge, Adrian
2015-01-01
A century ago, in his study of colour vision in the honeybee (Apis mellifera), Karl von Frisch showed that bees distinguish between a disc that is half yellow, half blue, and a mirror image of the same. Although his inference of colour vision in this example has been accepted, some discrepancies have prompted a new investigation of the detection of polarity in coloured patterns. In new experiments, bees restricted to their blue and green receptors by exclusion of ultraviolet could learn patterns of this type if they displayed a difference in green contrast between the two colours. Patterns with no green contrast required an additional vertical black line as a landmark. Tests of the trained bees revealed that they had learned two inputs; a measure and the retinotopic position of blue with large field tonic detectors, and the measure and position of a vertical edge or line with small-field phasic green detectors. The angle between these two was measured. This simple combination was detected wherever it occurred in many patterns, fitting the definition of an algorithm, which is defined as a method of processing data. As long as they excited blue receptors, colours could be any colour to human eyes, even white. The blue area cue could be separated from the green receptor modulation by as much as 50°. When some blue content was not available, the bees learned two measures of the modulation of the green receptors at widely separated vertical edges, and the angle between them. There was no evidence that the bees reconstructed the lay-out of the pattern or detected a tonic input to the green receptors. PMID:25617892
Heterogeneous Catalysis for Thermochemical Conversion Publications |
pentagons is an upside-down Y shape and H2 +with a sideways Y shape with two lines at the base. A gold arrow a photo of woody biomass. In the center is a diamond shape composed of four outer triangle sections blue spheres. In the upper left is a large molecule shape made up of a hexagon of black spheres
2007-01-01
from the Spokane area southwestward to Moses Lake and as far south as the Columbia River . Soils in the channeled scablands can be quite variable...western bluebird, red-necked grebe, great blue heron, turkey vulture, Caspian tern , black tern , and osprey. The white-tailed jackrabbit, a state...frequency are the Spokane Raceway along Hayford Road and firing range activities on FAFB and along the Spokane River . Residential development is
Demolition of Munitions Storage Area Facilities. Right Size Project 10-0192C
2011-07-01
area of the Proposed Action. 3.4.2 Affected Environment Fairchild AFB is situated within the channeled scablands of the Columbia River Basin which...grebe, great blue heron, turkey vulture, Caspian tern , black tern , and osprey. The white-tailed jackrabbit, a state candidate species, is known to...Geography The MSA is located in the Upper Columbia River Basin Basalt Geomorphic Province and lies within the Latah Creek watershed. The landtype is
The Ecology and Environmental Impact of Marshland and Estuaries
1992-12-15
species of water snakes, blue runners , ribbon snakes, black snakes, and bull snakes, as well as water moccassins, rattlesnakes, copperheads, and coral...be encountered there that should receive special consideration is the swallow-tailed kite . Kites in general seem to be seriously declining in parts of...the southern U.S., and a couple have a tenuous hold on their environment or, in the case of the swallow-tailed kite , have an undetermined status
A Next Generation Atmospheric Prediction System for the Navy
2015-09-30
by DOE and NSF , while the HiRAM system has primarily been supported by NOAA, although both models have leveraged considerably from indirect and...Neptune scalability (blue line) with the increasing number of cores compared to a perfect simulation rate (black line). Horizontal distance (km...draw on the community expertise with both MPAS and HIRAM. NRL is a no- cost collaborator with a number of proposals for the ONR Seasonal Prediction
Toward a Global 1/25degree HYCOM Ocean Prediction System with Tides
2010-01-01
configurations of ARCc. 6 Figure 4. Annual temperature field at 200 m. Left: ARCc0.72 experiment 040 (2006); Middle: GDEM climatology...Eurasian Basin. Solid lines indicate results from ARCc0.72 experiment 040 (black), 060 (blue) and GDEM climatology (green). Shades delineate 10 – 90...range of the data. Note the Atlantic Layer (positive T) is markedly well simulated in experiment 040 compared to GDEM profile. Figure 7
Recommendations and Requirements for GenCade Simluations
2014-08-01
sand transport model, GenCade. It is considered as a companion report to the first report in the GenCade series, Frey et al. (2012a), and provides...of output in *.slo (data extend both downward and to the right). .................. 31 Figure 20. Example of output for transport rates...shoreline (in red) and the transport rate at the beginning of the simulation (in blue). The initial shoreline position is shown in black. a
Coastal and Submesoscale Process Studies for ASIRI and Data Serving for ASIRI Participants
2014-09-30
spatial distributions of Chlorophyll fluorescence, colored dissolved organic matter (CDOM), and apparent oxygen utilization (AOU). It is evident that...Vertical section of tem perature (left) and salinity (right) w ith density in black contours, from 4 long tracks surveyed in Leg 2 (N ovem ber 2013) from...vertical derivative of the downwelling light is proportional to the radiant heating rate at depth. This figure shows that deeply penetrating blue
Electrically Driven Photonic Crystal Nanocavity Devices
2012-01-01
material, here gallium arsenide and indium arsenide self- assembled quantum dots (QDs). QDs are preferred for the gain medium because they can have...blue points ) and 150 K (green points ). The black lines are linear fits to the above threshold output power of the lasers, which are used to find the...SHAMBAT et al.: ELECTRICALLY DRIVEN PHOTONIC CRYSTAL NANOCAVITY DEVICES 1707 Fig. 13. (a) Tilted SEM picture of a fabricated triple cavity device. The in
Analyzing the Rationales Behind Russia’s Intervention in Ukraine
2016-03-01
87 Figure 4. Major Natural Gas Supply Pipelines from Russia to Europe ....................91 Figure 5. Gas Price Disparities between...Transporting natural gas is more difficult than transporting oil. While oil can be moved via pipeline , ship, train, or truck, natural gas must either be...Blue Stream pipeline through the Black Sea carry Russian gas directly to Germany and Turkey, respectively. In contrast, the Yamal pipeline traverses
2005-08-03
S114-E-6405 (3 August 2005) --- Space Shuttle Discoverys underside nosecone thermal protection tiles are featured in this image photographed by astronaut Stephen K. Robinson, STS-114 mission specialist, during the missions third session of extravehicular activities (EVA). Part of the P1 truss and a solar array are visible in the background. The blackness of space and a blue and white Earth form the backdrop for the image.
Accuracy of inference on the physics of binary evolution from gravitational-wave observations
NASA Astrophysics Data System (ADS)
Barrett, Jim W.; Gaebel, Sebastian M.; Neijssel, Coenraad J.; Vigna-Gómez, Alejandro; Stevenson, Simon; Berry, Christopher P. L.; Farr, Will M.; Mandel, Ilya
2018-04-01
The properties of the population of merging binary black holes encode some of the uncertain physics underlying the evolution of massive stars in binaries. The binary black hole merger rate and chirp-mass distribution are being measured by ground-based gravitational-wave detectors. We consider isolated binary evolution, and explore how accurately the physical model can be constrained with such observations by applying the Fisher information matrix to the merging black hole population simulated with the rapid binary-population synthesis code COMPAS. We investigate variations in four COMPAS parameters: common-envelope efficiency, kick-velocity dispersion, and mass-loss rates during the luminous blue variable and Wolf-Rayet stellar-evolutionary phases. We find that ˜1000 observations would constrain these model parameters to a fractional accuracy of a few per cent. Given the empirically determined binary black hole merger rate, we can expect gravitational-wave observations alone to place strong constraints on the physics of stellar and binary evolution within a few years. Our approach can be extended to use other observational data sets; combining observations at different evolutionary stages will lead to a better understanding of stellar and binary physics.
Accuracy of inference on the physics of binary evolution from gravitational-wave observations
NASA Astrophysics Data System (ADS)
Barrett, Jim W.; Gaebel, Sebastian M.; Neijssel, Coenraad J.; Vigna-Gómez, Alejandro; Stevenson, Simon; Berry, Christopher P. L.; Farr, Will M.; Mandel, Ilya
2018-07-01
The properties of the population of merging binary black holes encode some of the uncertain physics underlying the evolution of massive stars in binaries. The binary black hole merger rate and chirp-mass distribution are being measured by ground-based gravitational-wave detectors. We consider isolated binary evolution, and explore how accurately the physical model can be constrained with such observations by applying the Fisher information matrix to the merging black hole population simulated with the rapid binary-population synthesis code COMPAS. We investigate variations in four COMPAS parameters: common-envelope efficiency, kick-velocity dispersion and mass-loss rates during the luminous blue variable, and Wolf-Rayet stellar-evolutionary phases. We find that ˜1000 observations would constrain these model parameters to a fractional accuracy of a few per cent. Given the empirically determined binary black hole merger rate, we can expect gravitational-wave observations alone to place strong constraints on the physics of stellar and binary evolution within a few years. Our approach can be extended to use other observational data sets; combining observations at different evolutionary stages will lead to a better understanding of stellar and binary physics.
Colombo, L; Melardi, E; Ferri, P; Montesano, G; Samir Attaalla, S; Patelli, F; De Cillà, S; Savaresi, G; Rossetti, L
2017-08-22
To evaluate functional visual parameters using photocromic and selective blue-violet light filtering spectacle lenses in patients affected by central or peripheral scotoma due to retinal diseases. Sixty patients were enrolled in this study: 30 patients affected by central scotoma, group 1, and 30 affected by peripheral scotoma, group 2. Black on White Best Corrected Visual Acuity (BW-BCVA), White on Black Best Corrected Visual Acuity (WB-BCVA), Mars Contrast Sensitivity (CS) and a Glare Test (GT) were performed to all patients. Test results with blue-violet filter, a short-pass yellow filter and with no filters were compared. All scores from test results increased significantly with blue-violet filters for all patients. The mean BW-BCVA increased from 0.30 ± 0.20 to 0.36 ± 0.21 decimals in group 1 and from 0.44 ± 0.22 to 0.51 ± 0.23 decimals in group 2 (Mean ± SD, p < 0.0001 in both cases). The mean WB-BCVA increased from 0.31 ± 0.19 to 0.38 ± 0.23 decimals in group 1 and from 0.46 ± 0.20 to 0.56 ± 0.22 decimals in group 2 (Mean ± SD, p < 0.0001 in both cases). The letter count for the CS test increased from 26.7 ± 7.9 to 30.06 ± 7.8 in group 1 (Mean ± SD, p = 0.0005) and from 31.5 ± 7.6 to 33.72 ± 7.3 in group 2 (Mean ± SD, p = 0.031). GT was significantly reduced: the letter count increased from 20.93 ± 5.42 to 22.82 ± 4.93 in group 1 (Mean ± SD, p < 0.0001) and from 24.15 ± 5.5 to 25.97 ± 4.7 in group 2 (Mean ± SD, p < 0.0001). Higher scores were recorded with the Blue filter compared to Yellow filter in all tests (p < 0.05). No significant differences in any test results could be detected between the Yellow filter and the No filter condition. The use of a combination of photocromic lens with a selective blue-violet light filter showed functional benefit in all evaluated patients.
Precession of orbits around the stellar-mass black hole in H 1743-322
NASA Astrophysics Data System (ADS)
Ingram, Adam
2016-07-01
Accreting stellar-mass black holes often show a quasi-periodic oscillation (QPO) in their X-ray flux with a period that slowly drifts from ~10s to ~0.05s, and an iron emission line in their X-ray spectrum. The iron line is generated by fluorescent re-emission, by the accretion disk, of X-ray photons originating in the innermost hot flow. The line shape is distorted by relativistic motion of the orbiting plasma and the gravitational pull of the black hole. The QPO arises from the immediate vicinity of the black hole, but its physical origin has long been debated. It has been suggested that the QPO originates via Lense-Thirring precession, a General Relativistic effect causing the inner flow to precess as the spinning black hole twists up the surrounding space-time. This predicts a characteristic rocking of the iron line between red and blue shift as the receding and approaching sides of the disk are respectively illuminated. I will talk about our observations of the black hole binary H 1743-322 in which the line energy varies in step with the ~4.5s QPO cycle, providing strong evidence that such QPOs originate via Lense-Thirring precession. This effect has previously been measured in our Solar System but our detection is in the strong field regime of General Relativity, at a precession rate 14 orders of magnitude faster than possible in the Earth's gravitational field. Our result enables the application of tomographic techniques to map the motion of matter in the strong gravity near black hole event horizons.
Høgsberg, Trine; Jacobsen, Nicklas Raun; Clausen, Per Axel; Serup, Jørgen
2013-07-01
Black tattoo inks are composed of carbon nanoparticles, additives and water and may contain polycyclic aromatic hydrocarbons (PAHs). We aimed to clarify whether reactive oxygen species (ROS) induced by black inks in vitro is related to pigment chemistry, physico-chemical properties of the ink particles and the content of chemical additives and contaminants including PAHs. The study included nine brands of tattoo inks of six colours each (black, red, yellow, blue, green and white) and two additional black inks of different brands (n = 56). The ROS formation potential was determined by the dichlorofluorescein (DCFH) assay. A semiquantitative method was developed for screening extractable organic compounds in tattoo ink based on gas chromatography-mass spectrometry (GC-MS) and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). Two black inks produced high amounts of ROS. Peroxyl radicals accounted for up to 72% of the free radicals generated, whereas hydroxyl radicals and H₂O₂ accounted for <14% and 16%, respectively. The same two inks aggregated strongly in water in contrast to the other black inks. They did not exhibit any shared pattern in PAHs and other organic substances. Aggregation was exclusively shared by all ink colours belonging to the same two brands. Ten of 11 black inks had PAH concentrations exceeding the European Council's recommended level, and all 11 exceeded the recommended level for benzo(a)pyrene. It is a new finding that aggregation of tattoo pigment particles correlates with ROS production and brand, independently of chemical composition including PAHs. ROS is hypothesized to be implicated in minor clinical symptoms. © 2013 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sato, S.; Murphy, G.F.; Bernhard, J.D.
1981-09-01
In order to elucidate the nature and distribution of the pigment responsible for the circumscribed blue-black cutaneous hyperpigmentation occurring after administration of minocycline hydrochloride, transmission electron microscopy and energy-dispersive electron x-ray microanalysis were performed on lesional skin. Ultrastructural observations demonstrated electron-dense iron-containing particles either incorporated into a variety of siderosomes, within dermal histiocytes, free within the cytoplasm, or, rarely, scattered among dermal collagen fibers. Electron x-ray microanalysis confirmed iron content present within these particles. Although siderosomal inclusions contained occasional melanosome complexes, the degree of deposition of electron-dense iron-containing particles in dermal histiocytes seemed to be primarily responsible for the blue-blackmore » discoloration of the skin. The present study is an investigation of the structure and composition of the pigment responsible for minocycline-related cutaneous hyperpigmentation.« less
1979-07-07
Range : 1,094,666 km (677,000 mi.) This false color picture of Callisto was taken by Voyager 2 and is centered on 11 degrees N and 171 degrees W. This rendition uses an ultraviolet image for the blue component. Because the surface displays regional contrast in UV, variations in surface materials are apparent. Notice in particular the dark blue haloes which surround bright craters in the eastern hemisphere. The surface of Callisto is the most heavily cratered of the Galilean satellites and resembles ancient heavily cratered terrains on the moon, Mercury and Mars. The bright areas are ejecta thrown out by relatively young impact craters. A large ringed structure, probably an impact basin, is shown in the upper left part of the picture. The color version of this picture was constructed by compositing black and white images taken through the ultraviolet, clear and orange filters.
The global blue-sky albedo change between 2000 - 2015 seen from MODIS
NASA Astrophysics Data System (ADS)
Chrysoulakis, N.; Mitraka, Z.; Gorelick, N.
2016-12-01
The land surface albedo is a critical physical variable, which influences the Earth's climate by affecting the energy budget and distribution in the Earth-atmosphere system. Blue-sky albedo estimates provide a quantitative means for better constraining global and regional scale climate models. The Moderate Resolution Imaging Spectroradiometer (MODIS) albedo product includes parameters for the estimation of both the directional-hemispherical surface reflectance (black-sky albedo) and the bi-hemispherical surface reflectance (white-sky albedo). This dataset was used here for the blue-sky albedo estimation over the globe on an 8-day basis at 0.5 km spatial resolution for the whole time period covered by MODIS acquisitions (i.e. 2000 until today). To estimate the blue-sky albedo, the fraction of the diffused radiation is needed, a function of the Aerosol Optical Thickness (AOT). Required AOT information was acquired from the MODIS AOT product at 1̊ × 1̊ spatial resolution. Since the blue-sky albedo depends on the solar zenith angle (SZA), the 8-day mean blue-sky albedo values were computed as averages of the corresponding values for the representative SZAs covering the 24-hour day. The estimated blue-sky albedo time series was analyzed to capture changes during the 15 period. All computation were performed using the Google Earth Engine (GEE). The GEE provided access to all the MODIS products needed for the analysis without the need of searching or downloading. Moreover, the combination of MODIS products in both temporal and spatial terms was fast and effecting using the GEE API (Application Program Interface). All the products covering the globe and for the time period of 15 years were processed via a single collection. Most importantly, GEE allowed for including the calculation of SZAs covering the 24-hour day which improves the quality of the overall product. The 8-day global products of land surface albedo are available through http://www.rslab.gr/downloads.html
Violence and weapon carrying in music videos. A content analysis.
DuRant, R H; Rich, M; Emans, S J; Rome, E S; Allred, E; Woods, E R
1997-05-01
The positive portrayal of violence and weapon carrying in televised music videos is thought to have a considerable influence on the normative expectations of adolescents about these behaviors. To perform a content analysis of the depictions of violence and weapon carrying in music videos, including 5 genres of music (rock, rap, adult contemporary, rhythm and blues, and country), from 4 television networks and to analyze the degree of sexuality or eroticism portrayed in each video and its association with violence and weapon carrying, as an indicator of the desirability of violent behaviors. Five hundred eighteen videos were recorded during randomly selected days and times of the day from the Music Television, Video Hits One, Black Entertainment Television, and Country Music Television networks. Four female and 4 male observers aged 17 to 24 years were trained to use a standardized content analysis instrument. Interobserver reliability testing resulted in a mean (+/- SD) percentage agreement of 89.25% +/- 7.10% and a mean (+/- SD) kappa of 0.73 +/- 0.20. All videos were observed by rotating 2-person, male-female teams that were required to reach agreement on each behavior that was scored. Music genre and network differences in behaviors were analyzed with chi 2 tests. A higher percentage (22.4%) of Music Television videos portrayed overt violence than Video Hits One (11.8%), Country Music Television (11.8%), and Black Entertainment Television (11.5%) videos (P = .02). Rap (20.4%) had the highest portrayal of violence, followed by rock (19.8%), country (10.8%), adult contemporary (9.7%), and rhythm and blues (5.9%) (P = .006). Weapon carrying was higher on Music Television (25.0%) than on Black Entertainment Television (11.5%), Video Hits One (8.4%), and Country Music Television (6.9%) (P < .001). Weapon carrying was also higher in rock (19.8%) and rap (19.5%) videos than in adult contemporary (16.1%), rhythm and blues (6.9%), and country (6.3%) videos (P = .002). The videos with the highest level of sexuality or eroticism were found to be less likely to contain violence (P < or = .04). Because most music videos are between 3 and 4 minutes long, these data indicate that even modest levels of viewing may result in substantial exposure to violence and weapon carrying, which is glamorized by music artists, actors, and actresses.
Jet Power and Black Hole Assortment Revealed in New Chandra Image
NASA Astrophysics Data System (ADS)
2008-01-01
A dramatic new Chandra image of the nearby galaxy Centaurus A provides one of the best views to date of the effects of an active supermassive black hole. Opposing jets of high-energy particles can be seen extending to the outer reaches of the galaxy, and numerous smaller black holes in binary star systems are also visible. The image was made from an ultra-deep look at the galaxy Centaurus A, equivalent to more than seven days of continuous observations. Centaurus A is the nearest galaxy to Earth that contains a supermassive black hole actively powering a jet. X-ray Image of Centaurus A, Labeled X-ray Image of Centaurus A, Labeled A prominent X-ray jet extending for 13,000 light years points to the upper left in the image, with a shorter "counterjet" aimed in the opposite direction. Astronomers think that such jets are important vehicles for transporting energy from the black hole to the much larger dimensions of a galaxy, and affecting the rate at which stars form there. High-energy electrons spiraling around magnetic field lines produce the X-ray emission from the jet and counterjet. This emission quickly saps the energy from the electrons, so they must be continually reaccelerated or the X-rays will fade out. Knot-like features in the jets detected in the Chandra image show where the acceleration of particles to high energies is currently occurring, and provides important clues to understanding the process that accelerates the electrons to near-light speeds. People Who Read This Also Read... NASA’s Swift Satellite Catches First Supernova in The Act of Exploding Black Holes Have Simple Feeding Habits Chandra Data Reveal Rapidly Whirling Black Holes Erratic Black Hole Regulates Itself The inner part of the X-ray jet close to the black hole is dominated by these knots of X-ray emission, which probably come from shock waves -- akin to sonic booms -- caused by the jet. Farther from the black hole there is more diffuse X-ray emission in the jet. The cause of particle acceleration in this part of the jet is unknown. Hundreds of point-like sources are also seen in the Chandra image. Many of these are X-ray binaries that contain a stellar-mass black hole and a companion star in orbit around one another. Determining the population and properties of these black holes should help scientists better understand the evolution of massive stars and the formation of black holes. Another surprise was the detection of two particularly bright X-ray binaries. These sources may contain stellar mass black holes that are unusually massive, and this Chandra observation might have caught them gobbling up material at a high rate. In this image, low-energy X-rays are colored red, intermediate-energy X-rays are green, and the highest-energy X-rays detected by Chandra are blue. The dark green and blue bands running almost perpendicular to the jet are dust lanes that absorb X-rays. This dust lane was created when Centaurus A merged with another galaxy perhaps 100 million years ago. This research was presented at the American Astronomical Society meeting on January 9th by Gregory Sivakoff (The Ohio State University). Other team members include Ralph Kraft (Harvard-Smithsonian Center for Astrophysics), Martin Hardcastle (University of Hertfordshire), Diana Worrall (University of Bristol), and Andres Jordan (Smithsonian Astrophysical Observatory). NASA's Marshall Space Flight Center, Huntsville, Ala., manages the Chandra program for the agency's Science Mission Directorate. The Smithsonian Astrophysical Observatory controls science and flight operations from the Chandra X-ray Center in Cambridge, Mass.
History of the Colorado-Wyoming state line diatremes.
Collins, D.S.; Heyl, A.V.
1984-01-01
Although >90 kimberlite diatremes have been found in the area, it was not until after 1963 that these bodies were correctly identified. The presence of large inclusions of sedimentary rocks had hindered their recognition. In 1975 a diamond crystal 3.5 carats). They are usually colourless, but light-brown, blue-white, pale orange, pale to bright yellow and nearly black crystals occur. Associated minerals, including chrome-diopside, chromite, magnesian ilmenite, pyrope and omphacite, are described.-R.S.M.
Studies on Rheomelanins. VI. The Apparent Lipofuscin Characteristics of Rheomelanins,
1980-05-01
of aldchydes formed by the action of periodic acid on non carbohydrate conit-tining unsaturated phosphatides . At present we know only that in the o...A ’mV -5 1. Periodic Acid -Schiff Test 2. Long Ziehl-Neelsen Test for Acid Fast lilpofuscii 3. Alternative Nile Blue Method 4. Schmorl Test 5. Sudan...Black B in Alcohol 6. Chrome Alum Hematoxylin Test 7. Protein Determination 8. Specific Miucoprotein Test 9. Phosphoric Acid -Vanillin Lipid
Use of different spectroscopic techniques in the analysis of Roman age wall paintings.
Agnoli, Francesca; Calliari, Irene; Mazzocchin, Gian-Antonio
2007-01-01
In this paper the analysis of samples of Roman age wall paintings coming from: Pordenone, Vicenza and Verona is carried out by using three different techniques: energy dispersive x-rays spectroscopy (EDS), x-rays fluorescence (XRF) and proton induced x-rays emission (PIXE). The features of the three spectroscopic techniques in the analysis of samples of archaeological interest are discussed. The studied pigments were: cinnabar, yellow ochre, green earth, Egyptian blue and carbon black.
Salmonellosis in a captive heron colony
Locke, L.N.; Ohlendorf, H.M.; Shillinger, R.B.; Jareed, T.
1974-01-01
Salmonellosis caused by Salmonella typhimurium was one of several factors responsible for losses among young herons being held at the Patuxent Wildlife Research Center. The infection was demonstrated in five black-crowned night herons (Nycticorax nycticorax), three common egrets (Casmerodius albus), two little blue herons (Florida caerulea), one cattle egret (Bubulcus ibis), one snowy egret (Leucophoyx thula) and one Louisiana heron (Hydranassa tricolor). The disease was characterized by emaciation, focal liver necrosis, and frequently by a caseo-necrotic enteritis.
Gulf Coast Deep Water Port Facilities Study. Appendix D. Adverse Environmental Effects.
1973-04-01
mds 2. Thigmotropic effect of submerged structures 3. Attachment or shelter for marine organisms 4. Gain of sheltered habitat (lee of islands) 5...marshplants Bay margin marine grass, clams, snails and blue crab Grass flats marine grass, clams, snails, black drum and t other fish Open bay with tidal...surrounding area. F. CONCLUSION The most direct and easily understood effects of dredging projects on marine biota are: I) the destruction and removal of
Inhomogeneous Monte Carlo simulations of dermoscopic spectroscopy
NASA Astrophysics Data System (ADS)
Gareau, Daniel S.; Li, Ting; Jacques, Steven; Krueger, James
2012-03-01
Clinical skin-lesion diagnosis uses dermoscopy: 10X epiluminescence microscopy. Skin appearance ranges from black to white with shades of blue, red, gray and orange. Color is an important diagnostic criteria for diseases including melanoma. Melanin and blood content and distribution impact the diffuse spectral remittance (300-1000nm). Skin layers: immersion medium, stratum corneum, spinous epidermis, basal epidermis and dermis as well as laterally asymmetric features (eg. melanocytic invasion) were modeled in an inhomogeneous Monte Carlo model.
Optimal Combining Data for Improving Ocean Modeling
2008-09-30
hyperbolic or elliptic) and on the Hurst exponent characterizing the dynamics type (local or non-local). 3. Fusion data for estimating RD. Theoretical...1) RD vs time and different values of Hurst exponent h = 0.1 (black), h = 1 (red), h = 2 (blue) γ = 0.1,Ω = 0, 2) Same for γ = 0.1,Ω = 2 ). 3...accurate estimating the upper ocean velocity field and mixing characteristics such as relative dispersion and finite size Lyapunov exponent , (2
Textile dye decolorization using cyanobacteria.
Parikh, Amit; Madamwar, Datta
2005-03-01
Cyanobacterial cultures isolated from sites polluted by industrial textile effluents were screened for their ability to decolorize cyclic azo dyes. Gloeocapsa pleurocapsoides and Phormidium ceylanicum decolorized Acid Red 97 and FF Sky Blue dyes by more than 80% after 26 days. Chroococcus minutus was the only culture which decolorized Amido Black 10B (55%). Chlorophyll a synthesis in all cultures was strongly inhibited by the dyes. Visible spectroscopy and TLC confirmed that color removal was due to degradation of the dyes.
2013-09-30
remotely sensed data to be used for habitat modeling include sea surface temperature (SST), salinity, sea surface height, and chlorophyll a concentration...National Data Buoy Center for the parts of the SCB region with HARP deployments. Figure 1. Sixteen HARP deployment locations ( black squares...throughout the Southern California Bight between 2005 and 2012 from which data are processed for habitat modeling in this study. Light grey line
The effect of predation on begging-call evolution in nestling wood warblers.
Haskell
1999-04-01
I combined a comparative study of begging in ground- and tree-nesting wood warblers (Parulidae) with experimental measures of the predation costs of warbler begging calls. Throughout their development, ground-nesting warbler nestlings had significantly higher-frequency begging calls than did tree-nesting warblers. There was also a trend for ground-nesting birds to have less rapidly modulated calls. There were no consistent associations between nesting site and the amplitude of the calls. Using miniature walkie-talkies hidden inside artificial nests, I reciprocally transplanted the begging calls of 5- and 8-day-old black-throated blue warblers, Dendroica caerulescens (tree-nesting) and ovenbirds, Seiurus aurocapillus (ground-nesting) and measured the corresponding changes in rates of nest predation. For the begging calls of 8-day-old nestlings, but not those of 5-day-olds, the calls of the tree-nesting species coming from ground nests incurred greater costs than did the calls of ground nesters. The reciprocal transplant had little effect on the rate of predation. Tooth imprints on clay eggs placed in artificial nests indicated that eastern chipmunks, Tamias striatus, were responsible for the increased cost of begging for black-throated blue calls coming from the ground. These data suggest that nest predation may be responsible for maintaining some of the interspecific differences in the acoustic structure of begging calls. Copyright 1999 The Association for the Study of Animal Behaviour.
Application of cellulose nanofibers to remove water-based flexographic inks from wastewaters.
Balea, Ana; Monte, M Concepción; de la Fuente, Elena; Negro, Carlos; Blanco, Ángeles
2017-02-01
Water-based or flexographic inks in paper and plastic industries are more environmentally favourable than organic solvent-based inks. However, their use also creates new challenges because they remain dissolved in water and alter the recycling process. Conventional deinking technologies such as flotation processes do not effectively remove them. Adsorption, coagulation/flocculation, biological and membrane processes are either expensive or have negative health impacts, making the development of alternative methods necessary. Cellulose nanofibers (CNF) are biodegradable, and their structural and mechanical properties are useful for wastewater treatment. TEMPO-oxidised CNF have been evaluated for the decolourisation of wastewaters that contained copper phthalocyanine blue, carbon black and diarlyide yellow pigments. CNF in combination with a cationic polyacrylamide (cPAM) has also been tested. Jar-test methodology was used to evaluate the efficiency of the different treatments and cationic/anionic demand, turbidity and ink concentration in waters were measured. Results show that dual-component system for ink removal has a high potential as an alternative bio-based adsorbent for the removal of water-based inks. In addition, experiments varying CNF and cPAM concentrations were performed to optimise the ink-removal process. Ink concentration reductions of 100%, 87.5% and 83.3% were achieved for copper phthalocyanine blue, carbon black and diarlyide yellow pigments, respectively. Flocculation studies carried out show the decolourisation mechanism during the dual-component treatment of wastewaters containing water-based inks.
Joyce, Elizabeth M.; Sillett, T. Scott; Holmes, Richard T.
2001-01-01
Quantifying incubation patterns has often involved long observation periods in the field, video cameras, or the use of other electronic devices that sometimes require the partial destruction of clutches and insertion of artificial eggs. In this study, we used an inexpensive, nondestructive method involving temperature probes combined with data loggers to examine the incubation rhythm of female Black-throated Blue Warblers (Dendroica caerulescens). The method provided detailed records of on–off patterns for females for selected 24-h periods during incubation. Female warblers spent an average (±SE) of 64.0% of daylight hours incubating in bouts lasting 20.5 ± 1.5 min and made 2.4 ± 0.1 departures from the nest/h on trips that lasted 10.6 ± 0.7 min. Incubation bouts were longer and females spent more time incubating per hour in the mornings and late afternoons than at mid-day. Older females had longer incubation bouts and tended to have shorter incubation periods than did yearling females, suggesting that experienced individuals were more effective incubators. Because of its ease of use and because nests with probes were not depredated at a higher rate than controls, we suggest that the temperature probe/data logger method is an efficient and effective way to quantify incubation rhythms for open-cup nesting birds.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Islam, Syed Z.; Reed, Allen; Nagpure, Suraj
In this work, we use neutron reflectometry (NR) to investigate the roles of hydrogen in plasma treated hydrogen doped mesoporous black titania thin films in their visible light absorption and enhanced photoactivity for water oxidation. The cubic ordered mesoporous TiO 2 thin films are prepared by a surfactant-templated sol-gel method and are treated with hydrogen plasma, an approach hypothesized to capitalize on the high degree of disorder in the material and the high energy of the plasma species to achieve efficient hydrogen doping. UV-vis absorbance spectra indicate that H 2 plasma treatment makes TiO 2 films black, with broad-spectrum enhancementmore » of visible light absorption, and XPS analysis shows peak for Ti 3+ state in treated films. The presence of hydrogen in black mesoporous titania (H-TiO 2) films is confirmed by the scattering length density (SLD) profiles obtained from neutron reflectometry measurements. The H-TiO 2 shows ca. 28 times and 8 times higher photocurrent for photoelectrochemical water oxidation compared to undoped TiO 2 films under UV (365 nm) and blue (455 nm) LED irradiation, respectively. These findings provide the first direct evidence that the dramatic change in visible light absorbance of H-treated black TiO 2 is accompanied by significant hydrogen uptake and not just Ti 3+ generation or surface disordering.« less
Islam, Syed Z.; Reed, Allen; Nagpure, Suraj; ...
2017-10-26
In this work, we use neutron reflectometry (NR) to investigate the roles of hydrogen in plasma treated hydrogen doped mesoporous black titania thin films in their visible light absorption and enhanced photoactivity for water oxidation. The cubic ordered mesoporous TiO 2 thin films are prepared by a surfactant-templated sol-gel method and are treated with hydrogen plasma, an approach hypothesized to capitalize on the high degree of disorder in the material and the high energy of the plasma species to achieve efficient hydrogen doping. UV-vis absorbance spectra indicate that H 2 plasma treatment makes TiO 2 films black, with broad-spectrum enhancementmore » of visible light absorption, and XPS analysis shows peak for Ti 3+ state in treated films. The presence of hydrogen in black mesoporous titania (H-TiO 2) films is confirmed by the scattering length density (SLD) profiles obtained from neutron reflectometry measurements. The H-TiO 2 shows ca. 28 times and 8 times higher photocurrent for photoelectrochemical water oxidation compared to undoped TiO 2 films under UV (365 nm) and blue (455 nm) LED irradiation, respectively. These findings provide the first direct evidence that the dramatic change in visible light absorbance of H-treated black TiO 2 is accompanied by significant hydrogen uptake and not just Ti 3+ generation or surface disordering.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Islam, Syed Z.; Reed, Allen; Nagpure, Suraj
2018-05-01
In this work, we use neutron reflectometry (NR) to investigate the roles of hydrogen in plasma treated hydrogen doped mesoporous black titania thin films in their visible light absorption and enhanced photoactivity for water oxidation. The cubic ordered mesoporous TiO2 thin films are prepared by a surfactant-templated sol-gel method and are treated with hydrogen plasma, an approach hypothesized to capitalize on the high degree of disorder in the material and the high energy of the plasma species to achieve efficient hydrogen doping. UV-vis absorbance spectra indicate that H2 plasma treatment makes TiO2 films black, with broad-spectrum enhancement of visible lightmore » absorption, and XPS analysis shows peak for Ti3+ state in treated films. The presence of hydrogen in black mesoporous titania (H-TiO2) films is confirmed by the scattering length density (SLD) profiles obtained from neutron reflectometry measurements. The H-TiO2 shows ca. 28 times and 8 times higher photocurrent for photoelectrochemical water oxidation compared to undoped TiO2 films under UV (365 nm) and blue (455 nm) LED irradiation, respectively. These findings provide the first direct evidence that the dramatic change in visible light absorbance of H-treated black TiO2 is accompanied by significant hydrogen uptake and not just Ti3+ generation or surface disordering.« less
Space Radar Image of Star City, Russia
NASA Technical Reports Server (NTRS)
1994-01-01
This radar image shows the Star City cosmonaut training center, east of Moscow, Russia. Four American astronauts are training here for future long-duration flights aboard the Russian Mir space station. These joint flights are giving NASA and the Russian Space Agency experience necessary for the construction of the international Alpha space station, beginning in late 1997. This image was acquired by the Spaceborne Imaging Radar-C/X-band Synthetic Aperture Radar (SIR-C/X-SAR), on its 62nd orbit on October 3, 1994. This Star City image is centered at 55.55 degrees north latitude and 38.0 degrees east longitude. The area shown is approximately 32 kilometers by 49 kilometers (20 miles by 30 miles). North is to the top in this image. The radar illumination is from the top of the image. The image was produced using three channels of SIR-C radar data: red indicates L-band (23 cm wavelength, horizontally transmitted and received); green indicates L-band (horizontally transmitted and vertically received); blue indicates C-band (6 cm wavelength, horizontally transmitted and vertically received). In general, dark pink areas are agricultural; pink and light blue areas are urban communities; black areas represent lakes and rivers; dark blue areas are cleared forest; and light green areas are forested. The prominent black runways just right of center are Shchelkovo Airfield, about 4 km long. The textured pale blue-green area east and southeast of Shchelkovo Airfield is forest. Just east of the runways is a thin railroad line running southeast; the Star City compound lies just east of the small bend in the rail line. Star City contains the living quarters and training facilities for Russian cosmonauts and their families. Moscow's inner loop road is visible at the lower left edge of the image. The Kremlin is just off the left edge, on the banks of the meandering Moskva River. The Klyazma River snakes to the southeast from the reservoir in the upper left (shown in bright red), passing just east of Star City and flowing off the lower right edge of the image. The dark blue band of the Vorya River runs north-south in the upper right quadrant, east of Star City. SIR-C/X-SAR radar images are being compared with data from the Russian radar satellite Almaz to evaluate the usefulness of a permanent orbital radar platform in monitoring Earth s environment and ecology.
Buchweitz, M; Brauch, J; Carle, R; Kammerer, D R
2013-06-01
The formation of blue coloured ferric anthocyanin chelates and their colour stability during storage and thermal treatment were monitored in a pH range relevant to food (3.6-5.0). Liquid model systems were composed of different types of Citrus pectins, juices (J) and the respective phenolic extracts (E) from elderberry (EB), black currant (BC), red cabbage (RC) and purple carrot (PC) in the presence of ferric ions. For EB, BC and PC, pure blue colours devoid of a violet tint were exclusively observed for the phenolic extracts and at pH values ≥ 4.5 in model systems containing high methoxylated and amidated pectins, respectively. Colour and its stability strongly depended on the amount of ferric ions and the plant source; however, colour decay could generally be described as a pseudo-first-order kinetics. Despite optimal colour hues for RC-E and RC-J, storage and heat stabilities were poor. Highest colour intensities and best stabilities were observed for model systems containing PC-E at a molar anthocyanin:ferric ion ratio of 1:2. Ascorbic and lactic acids interfered with ferric ions, thus significantly affecting blue colour evolution and stability. Colour loss strongly depended on heat exposure with activation energies ranging between 60.5 and 78.4 kJ/mol. The comprehensive evaluation of the interrelationship of pigment source, pH conditions and pectin type on chelate formation and stability demonstrated that ferric anthocyanin chelates are promising natural blue food colourants. Copyright © 2012 Elsevier Ltd. All rights reserved.
Tracing the origin of 'blue Weimaraner' dogs by molecular genetics.
Gerding, W M; Schreiber, S; Dekomien, G; Epplen, J T
2011-04-01
Weimaraner dogs are defined by light brown coat colour termed grey including several shadings ranging from silver and deer to mouse grey. In contrast, the so-called blue Weimaraners (BW) with lightened black-pigmented coat have been proposed to represent spontaneous revertants in the Weimaraner breed. In order to investigate the genetic determinants of the characteristic grey coat colour versus those of BW, known variation in coat colour genes including TYRP1 and MLPH were analysed in a number of grey and blue dogs. Variations at the B locus cause grey coat colour in Weimaraners via two non-functional TYRP1 copies (bb) including the b(s), b(d) and b(c) alleles. In all BW, at least one functional TYRP1 allele (Bb or BB genotype) was identified. Defined microsatellite alleles in TYRP1 intron 4 are linked to this functional B allele in BW. These alleles were also detected in various other dog breeds, but not in grey Weimaraners. The combination of a dominant trait for blue versus grey together with a specific TYRP1 haplotype in BW suggests that blue coat colour is not the result of spontaneous (back-) mutation in grey Weimaraners. This inference is even emphasized by the presence of a unique Y-chomosomal haplotype in a male offspring of the supposed ancestor of the BW population which - according to pedigree information - carries a copy of the original Y chromosome. Thus, molecular genetic analyses of coat colours combined with Y-chromosomal haplotypes allow tracing the origin of atypical dogs in respective canine populations. © 2010 Blackwell Verlag GmbH.
Lauridsen, Clara Bratt; Sanyova, Jana; Simonsen, Kim Pilkjær
2015-11-05
The pigment composition of six painted metal knight shields of the Order of the Elephant dating from the second half of the 20th century belonging to the Danish royal collection were studied using Raman microscopy. By focusing a 785 nm laser with a 50× objective on particles in paint cross sections, it was possible to identify the following 20 compounds: hematite, goethite, chrome red/orange, chrome yellow, zinc chrome yellow, carbon black, toluidine red PR3, chlorinated para red PR4, dinitroaniline orange PO5, phthalocyanine blue PB15, indanthrone blue PB60, ultramarine, Prussian blue, lead white, anatase, rutile, calcium carbonate, barium sulphate, gypsum and dolomite. The components were frequently present in complex pigment mixtures. Additional information was obtained by elemental analysis with scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) to identify cobalt blue, zinc white and cadmium red, as well as to indicate the presence of zinc white in some pigment mixtures. The study allowed a comparison between the industrially applied preparation layers and the artistic paint layers applied by the heraldic painter. Differences in the choice of paint and pigment types were observed on the earliest knight shields, demonstrating a general delay of industrial materials into artist paints. Copyright © 2015 Elsevier B.V. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Iturbe-Zabalo, E., E-mail: iturbe@ill.fr; Fisika Aplikatua II Saila, Zientzia eta Teknologia Fakultatea, UPV/EHU, P.O. Box 644, 48080 Bilbao; Igartua, J.M.
2013-02-15
Crystal structures of SrNdZnRuO{sub 6}, SrNdCoRuO{sub 6}, SrNdMgRuO{sub 6} and SrNdNiRuO{sub 6} double perovskites have been studied by X-ray, synchrotron radiation and neutron powder diffraction method, at different temperatures, and using the symmetry-mode analysis. All compounds adopt the monoclinic space group P2{sub 1}/n at room-temperature, and contain a completely ordered array of the tilted MO{sub 6} and RuO{sub 6} octahedra, whereas Sr/Nd cations are completely disordered. The analysis of the structures in terms of symmetry-adapted modes of the parent phase allows the identification of the modes responsible for the phase-transition. The high-temperature study (300-1250 K) has shown that the compoundsmore » present a temperature induced structural phase-transition: P2{sub 1}/n{yields}P4{sub 2}/n{yields}Fm3{sup Macron }m. - Graphical abstract: Representation of the dominant distortion modes of the symmetry mode decomposition of the room-temperature (P2{sub 1}/n), intermediate (P4{sub 2}/n) and cubic (Fm-3m) phase SrNdMRuO{sub 6} (M=Zn,Co,Mg,Ni), with respect to the parent phase Fm-3m. The dominant distortion modes are: in the monoclinic phase-GM{sub 4}{sup +} (blue arrow), X{sub 3}{sup +} (green arrow) and X{sub 5}{sup +} acting on A-site cations (red arrow); in the tetragonal phase-GM{sub 4}{sup +} (pink arrow), X{sub 3}{sup +} (light blue arrow) and X{sub 5}{sup +} acting on A-site cations (brown arrow). Highlights: Black-Right-Pointing-Pointer Structural study of four ruthenate double perovskites. Black-Right-Pointing-Pointer Room-temperature structural determination using symmetry-mode procedure. Black-Right-Pointing-Pointer Determination of temperature induced structural phase-transitions. Black-Right-Pointing-Pointer Symmetry adapted-mode analysis.« less