Global Characterization of Tropospheric Noise for InSAR Analysis Using MODIS Data

NASA Astrophysics Data System (ADS)

Yun, S.; Hensley, S.; Chaubell, M.; Fielding, E. J.; Pan, L.; Rosen, P. A.

2013-12-01

Radio wave's differential phase delay variation through the troposphere is one of the largest error sources in Interferometric Synthetic Aperture Radar (InSAR) measurements, and water vapor variability in the troposphere is known to be the dominant factor. We use the precipitable water vapor products from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) sensors mounted on Terra and Aqua satellites to produce tropospheric noise maps of InSAR. Then we extract a small set of characteristic parameters of its power spectral density curve and 1-D covariance function, and calculate the structure function to estimate the expected tropospheric noise level as a function of distance. The results serve two purposes: 1) to provide guidance on the expected covariance matrix for geophysical modeling, 2) to provide quantitative basis of the measurement requirements for the planned US L-band SAR mission. We build over a decade span (2000-2013) of a lookup table of the parameters derived from 2-by-2 degree tiles at 1-by-1 degree posting of global coverage, representing 10 days of each season in each year. The MODIS data were retrieved from OSCAR (Online Services for Correcting Atmosphere in Radar) server. MODIS images with 5 percent or more cloud cover were discarded. Cloud mask and sensor scanning artifacts were removed with interpolation and spectral filtering, respectively. We also mitigate topography dependent stratified tropospheric delay variation using the European Centre for Medium-Range Weather Forecasts (ECMWF) and Shuttle Radar Topography Mission Digital Elevation Models (SRTM DEMs).

Ozone Profiles and Tropospheric Ozone from Global Ozone Monitoring Experiment

NASA Technical Reports Server (NTRS)

Liu, X.; Chance, K.; Sioris, C. E.; Sparr, R. J. D.; Kuregm, T. P.; Martin, R. V.; Newchurch, M. J.; Bhartia, P. K.

2003-01-01

Ozone profiles are derived from backscattered radiances in the ultraviolet spectra (290-340 nm) measured by the nadir-viewing Global Ozone Monitoring Experiment using optimal estimation. Tropospheric O3 is directly retrieved with the tropopause as one of the retrieval levels. To optimize the retrieval and improve the fitting precision needed for tropospheric O3, we perform extensive wavelength and radiometric calibrations and improve forward model inputs. Retrieved O3 profiles and tropospheric O3 agree well with coincident ozonesonde measurements, and the integrated total O3 agrees very well with Earth Probe TOMS and Dobson/Brewer total O3. The global distribution of tropospheric O3 clearly shows the influences of biomass burning, convection, and air pollution, and is generally consistent with our current understanding.

Global Modeling of Tropospheric Chemistry with Assimilated Meteorology: Model Description and Evaluation

NASA Technical Reports Server (NTRS)

Bey, Isabelle; Jacob, Daniel J.; Yantosca, Robert M.; Logan, Jennifer A.; Field, Brendan D.; Fiore, Arlene M.; Li, Qin-Bin; Liu, Hong-Yu; Mickley, Loretta J.; Schultz, Martin G.

2001-01-01

We present a first description and evaluation of GEOS-CHEM, a global three-dimensional (3-D) model of tropospheric chemistry driven by assimilated meteorological observations from the Goddard Earth Observing System (GEOS) of the NASA Data Assimilation Office (DAO). The model is applied to a 1-year simulation of tropospheric ozone-NOx-hydrocarbon chemistry for 1994, and is evaluated with observations both for 1994 and for other years. It reproduces usually to within 10 ppb the concentrations of ozone observed from the worldwide ozonesonde data network. It simulates correctly the seasonal phases and amplitudes of ozone concentrations for different regions and altitudes, but tends to underestimate the seasonal amplitude at northern midlatitudes. Observed concentrations of NO and peroxyacetylnitrate (PAN) observed in aircraft campaigns are generally reproduced to within a factor of 2 and often much better. Concentrations of HNO3 in the remote troposphere are overestimated typically by a factor of 2-3, a common problem in global models that may reflect a combination of insufficient precipitation scavenging and gas-aerosol partitioning not resolved by the model. The model yields an atmospheric lifetime of methylchloroform (proxy for global OH) of 5.1 years, as compared to a best estimate from observations of 5.5 plus or minus 0.8 years, and simulates H2O2 concentrations observed from aircraft with significant regional disagreements but no global bias. The OH concentrations are approximately 20% higher than in our previous global 3-D model which included an UV-absorbing aerosol. Concentrations of CO tend to be underestimated by the model, often by 10-30 ppb, which could reflect a combination of excessive OH (a 20% decrease in model OH could be accommodated by the methylchloroform constraint) and an underestimate of CO sources (particularly biogenic). The model underestimates observed acetone concentrations over the South Pacific in fall by a factor of 3; a missing source

Global model of zenith tropospheric delay proposed based on EOF analysis

NASA Astrophysics Data System (ADS)

Sun, Langlang; Chen, Peng; Wei, Erhu; Li, Qinzheng

2017-07-01

Tropospheric delay is one of the main error budgets in Global Navigation Satellite System (GNSS) measurements. Many empirical correction models have been developed to compensate this delay, and models which do not require meteorological parameters have received the most attention. This study established a global troposphere zenith total delay (ZTD) model, called Global Empirical Orthogonal Function Troposphere (GEOFT), based on the empirical orthogonal function (EOF, also known as geographically weighted PCAs) analysis method and the Global Geodetic Observing System (GGOS) Atmosphere data from 2012 to 2015. The results showed that ZTD variation could be well represented by the characteristics of the EOF base function Ek and associated coefficients Pk. Here, E1 mainly signifies the equatorial anomaly; E2 represents north-south asymmetry, and E3 and E4 reflects regional variation. Moreover, P1 mainly reflects annual and semiannual variation components; P2 and P3 mainly contains annual variation components, and P4 displays semiannual variation components. We validated the proposed GEOFT model using tropospheric delay data of GGOS ZTD grid data and the tropospheric product of the International GNSS Service (IGS) over the year 2016. The results showed that GEOFT model has high accuracy with bias and RMS of -0.3 and 3.9 cm, respectively, with respect to the GGOS ZTD data, and of -0.8 and 4.1 cm, respectively, with respect to the global IGS tropospheric product. The accuracy of GEOFT demonstrating that the use of the EOF analysis method to characterize ZTD variation is reasonable.

ITG: A New Global GNSS Tropospheric Correction Model

PubMed Central

Yao, Yibin; Xu, Chaoqian; Shi, Junbo; Cao, Na; Zhang, Bao; Yang, Junjian

2015-01-01

Tropospheric correction models are receiving increasing attentions, as they play a crucial role in Global Navigation Satellite System (GNSS). Most commonly used models to date include the GPT2 series and the TropGrid2. In this study, we analyzed the advantages and disadvantages of existing models and developed a new model called the Improved Tropospheric Grid (ITG). ITG considers annual, semi-annual and diurnal variations, and includes multiple tropospheric parameters. The amplitude and initial phase of diurnal variation are estimated as a periodic function. ITG provides temperature, pressure, the weighted mean temperature (Tm) and Zenith Wet Delay (ZWD). We conducted a performance comparison among the proposed ITG model and previous ones, in terms of meteorological measurements from 698 observation stations, Zenith Total Delay (ZTD) products from 280 International GNSS Service (IGS) station and Tm from Global Geodetic Observing System (GGOS) products. Results indicate that ITG offers the best performance on the whole. PMID:26196963

Modelling the global tropospheric molecular hydrogen cycle

NASA Astrophysics Data System (ADS)

Pieterse, G.

2013-01-01

Would urban air quality and climate improve if we replaced the fossil fuels by molecular hydrogen (H2) as an energy carrier? A quantitative answer to this question requires a thorough understanding of the current role of H2 in the Earth’s atmosphere. On its own, H2 does not impact climate, as for example carbon dioxide or methane. However, increasing levels of H2 in the stratosphere can lead to increased ozone loss due to the formation of polar stratospheric clouds. Additionally, the atmospheric lifetime of methane could increase because both H2 and methane are removed by photochemical oxidation with the hydroxyl radical. Consequently, the lifetime of the strong greenhouse gas methane could be prolonged. During the last two decades, more and more experimental data have become available to put tighter constraints on the different sources and sinks that contribute to the global H2 cycle. However, the main removal process, dry deposition due to microbial/enzymatic decomposition of H2 in the soils, still has a rather large uncertainty between 40-99 Tg/yr globally. This is a highly uncertain number compared to the estimated overall amount of 136-166 Tg present in the troposphere. The photochemical removal of H2 from the atmosphere is estimated at 14-24 Tg/yr. Together with the estimates for the burden and dry deposition, this implies a tropospheric lifetime of H2 between 1.1-3.1 years. The atmospheric H2 is replenished by emissions from the Earth’s surfaces due to fossil fuel burning (5-25 Tg/yr), biomass burning (7-21 Tg/yr) and nitrogen fixation processes in the oceans (1-11 Tg/yr) and soils (0-11 Tg/yr). H2 is photochemically produced from methane (15-21 Tg/yr) and non-methane hydrocarbons (10-25 Tg/yr) in the atmosphere. These uncertainties suggest that at present, the global hydrogen cycle is poorly understood. However, this statement would do little justice to the scientific quality of most studies so far. The main purpose of the research in this thesis is to

Source Attribution of Tropospheric Ozone using a Global Model

NASA Astrophysics Data System (ADS)

Coates, J.; Lupascu, A.; Butler, T. M.; Zhu, S.

2016-12-01

Tropospheric ozone is both a short-lived climate forcing pollutant and a radiatively active greenhouse gas. Ozone is not directly emitted into the troposphere but photochemically produced from chemical reactions involving nitrogen oxides (NOx) and volatile organic compounds (VOCs). Emissions of ozone precursors (NOx and VOCs) have both natural and anthropogenic sources and may be transported away from their sources to produce ozone downwind. Also, transport of ozone from the stratosphere into the troposphere also influences tropospheric ozone levels in some regions. Attributing ozone concentrations to the contributions from different sources would indicate the effects of locally emitted or transported precursors on ozone levels in specific regions. This information could be used to inform the emission reduction strategies of ozone precursors by indicating which emission sources could be targeted for effective reductions thus reducing the burden of ozone pollution. We use a "tagging" approach within the CESM global model to attribute ozone levels to their source emissions. We use different tags to quantify the impact from natural (soils, lightning, stratospheric transport) and anthropogenic (aircraft, biomass burning) sources of NOx and VOCs (including methane) on ozone levels. These source sectors of different global regions are assigned based on the global emissions specified by HTAPv2.2. Using these results, we develop a transboundary source-receptor relationship of ozone concentration to its precursor emission regions. Additionally, the transport of ozone precursors from regional anthropogenic sources is analysed to illustrate the extent to which mitigation strategies of regional emissions aid in mitigating global ozone levels.

Global Free-tropospheric NO2 Abundances Derived Using a Cloud Slicing Technique from AURA OMI

NASA Technical Reports Server (NTRS)

Choi, S.; Joiner, J.; Choi, Y.; Duncan, B.N.; Vasilkov, A.; Krotkov, N.; Bucsela, E.J.

2014-01-01

We derive free-tropospheric NO2 volume mixing ratios (VMRs) by applying a cloud-slicing technique to data from the Ozone Monitoring Instrument (OMI) on the Aura satellite. In the cloud-slicing approach, the slope of the above-cloud NO2 column versus the cloud scene pressure is proportional to the NO2 VMR. In this work, we use a sample of nearby OMI pixel data from a single orbit for the linear fit. The OMI data include cloud scene pressures from the rotational-Raman algorithm and above-cloud NO2 vertical column density (VCD) (defined as the NO2 column from the cloud scene pressure to the top of the atmosphere) from a differential optical absorption spectroscopy (DOAS) algorithm. We compare OMI-derived NO2 VMRs with in situ aircraft profiles measured during the NASA Intercontinental Chemical Transport Experiment Phase B (INTEX-B) campaign in 2006. The agreement is generally within the estimated uncertainties when appropriate data screening is applied. We then derive a global seasonal climatology of free-tropospheric NO2 VMR in cloudy conditions. Enhanced NO2 in the free troposphere commonly appears near polluted urban locations where NO2 produced in the boundary layer may be transported vertically out of the boundary layer and then horizontally away from the source. Signatures of lightning NO2 are also shown throughout low and middle latitude regions in summer months. A profile analysis of our cloud-slicing data indicates signatures of lightning-generated NO2 in the upper troposphere. Comparison of the climatology with simulations from the global modeling initiative (GMI) for cloudy conditions (cloud optical depth less than10) shows similarities in the spatial patterns of continental pollution outflow. However, there are also some differences in the seasonal variation of free-tropospheric NO2 VMRs near highly populated regions and in areas affected by lightning-generated NOx.

Airborne MAX-DOAS Measurements Over California: Testing the NASA OMI Tropospheric NO2 Product

NASA Technical Reports Server (NTRS)

Oetjen, Hilke; Baidar, Sunil; Krotkov, Nickolay A.; Lamsal, Lok N.; Lechner, Michael; Volkamer, Rainer

2013-01-01

Airborne Multi-AXis Differential Optical Absorption Spectroscopy (AMAX-DOAS) measurements of NO2 tropospheric vertical columns were performed over California for two months in summer 2010. The observations are compared to the NASA Ozone Monitoring Instrument (OMI) tropospheric vertical columns (data product v2.1) in two ways: (1) Median data were compared for the whole time period for selected boxes, and the agreement was found to be fair (R = 0.97, slope = 1.4 +/- 0.1, N= 10). (2) A comparison was performed on the mean of coincident AMAX-DOAS measurements within the area of the corresponding OMI pixels with the tropospheric NASA OMI NO2 assigned to that pixel. The effects of different data filters were assessed. Excellent agreement and a strong correlation (R = 0.85, slope = 1.05 +/- 0.09, N= 56) was found for (2) when the data were filtered to eliminate large pixels near the edge of the OMI orbit, the cloud radiance fraction was<50%, the OMI overpass occurred within 2 h of the AMAX-DOAS measurements, the flight altitude was>2 km, and a representative sample of the footprint was taken by the AMAX-DOAS instrument. The AMAX-DOAS and OMI data sets both show a reduction of NO2 tropospheric columns on weekends by 38 +/- 24% and 33 +/- 11%, respectively. The assumptions in the tropospheric satellite air mass factor simulations were tested using independent measurements of surface albedo, aerosol extinction, and NO2 profiles for Los Angeles for July 2010 indicating an uncertainty of 12%.

Global tropospheric hydroxyl distribution, budget and reactivity

NASA Astrophysics Data System (ADS)

Lelieveld, Jos; Gromov, Sergey; Pozzer, Andrea; Taraborrelli, Domenico

2016-10-01

The self-cleaning or oxidation capacity of the atmosphere is principally controlled by hydroxyl (OH) radicals in the troposphere. Hydroxyl has primary (P) and secondary (S) sources, the former mainly through the photodissociation of ozone, the latter through OH recycling in radical reaction chains. We used the recent Mainz Organics Mechanism (MOM) to advance volatile organic carbon (VOC) chemistry in the general circulation model EMAC (ECHAM/MESSy Atmospheric Chemistry) and show that S is larger than previously assumed. By including emissions of a large number of primary VOC, and accounting for their complete breakdown and intermediate products, MOM is mass-conserving and calculates substantially higher OH reactivity from VOC oxidation compared to predecessor models. Whereas previously P and S were found to be of similar magnitude, the present work indicates that S may be twice as large, mostly due to OH recycling in the free troposphere. Further, we find that nighttime OH formation may be significant in the polluted subtropical boundary layer in summer. With a mean OH recycling probability of about 67 %, global OH is buffered and not sensitive to perturbations by natural or anthropogenic emission changes. Complementary primary and secondary OH formation mechanisms in pristine and polluted environments in the continental and marine troposphere, connected through long-range transport of O3, can maintain stable global OH levels.

NASA Global Hawk Project Update and Future Plans: A New Tool for Earth Science Research

NASA Technical Reports Server (NTRS)

Naftel, Chris

2009-01-01

Science objectives include: First demonstration of the Global Hawk unmanned aircraft system (UAS) for NASA and NOAA Earth science research and applications; Validation of instruments on-board the Aura satellite; Exploration of trace gases, aerosols, and dynamics of remote upper Troposphere/lower Stratosphere regions; Sample polar vortex fragments and atmospheric rivers; Risk reduction for future missions that will study hurricanes and atmospheric rivers.

Tropospheric ozone simulated by a global-multi-regional two-way coupling model system

NASA Astrophysics Data System (ADS)

Yan, Y.; Lin, J.; Chen, J.; Hu, L.

2015-12-01

Current global chemical transport models are limited by horizontal resolutions (100-500 km), and they cannot capture small-scale processes affecting tropospheric ozone (O3). Here we use a recently built two-way coupling system of GEOS-Chem to simulate the global tropospheric O3 in 2009. The system couples the global model (~ 200 km) and its three nested models (~ 50 km) covering Asia, North America and Europe, respectively. Benefiting from the high resolution, the nested models better capture small-scale processes than the global model alone. In the coupling system, the nested models provide results to modify the global model simulation within respective nested domains while taking the lateral boundary conditions from the global model. Due to the "coupling" effects, the two-way system significantly improves the tropospheric O3 simulation upon the global model alone, as found by comparisons with a suite of ground (1420 sites from WDCGG, GMD, EMEP, and AQS), aircraft (HIPPO and MOZAIC), and satellite measurements (two OMI products). Compared to the global model alone, the two-way coupled simulation enhances the correlation in day-to-day variation of afternoon mean O3 with the ground measurements from 0.53 to 0.68 and reduces the mean model bias from 10.8 to 6.7 ppb. Regionally, the coupled model reduces the bias by 4.6 ppb over Europe, 3.9 ppb over North America, and 3.1 ppb over other regions. The two-way coupling brings O3 vertical profiles much closer to the HIPPO and MOZAIC data, reducing the tropospheric (0-9 km) mean bias by 3-10 ppb at most MOZAIC sites and by 5.3 ppb for HIPPO profiles. The two-way coupled simulation also reduces the global tropospheric column ozone by 3.0 DU (9.5%), bringing them closer to the OMI data in all seasons. Simulation improvements are more significant in the northern hemisphere, and are primarily a result of improved representation of the nonlinear ozone chemistry, including but not limited to urban-rural contrast. The two

Current and planned use of the Navstar Global Positioning System by NASA

NASA Technical Reports Server (NTRS)

Theiss, Harold L.

1993-01-01

NASA was quick to realize the potential that the Global Positioning System (GPS) had to offer for its many diverse vehicles, experiments and platforms. Soon after the first Block 1 GPS satellites were launched, NASA began to use the tremendous capabilities that they had to offer. Even with a partial GPS constellation in place, important results have been obtained about the shape, orientation and rotation of the earth and calibration of the ionosphere and troposphere. These calibrations enhance geophysical science and facilitate the navigation of interplanetary spacecraft. Some very important results have been obtained in the continuing NASA program for aircraft terminal area operations. Currently, a large amount of activity is being concentrated on real time kinematic carrier phase tracking which has the potential to revolutionize aircraft navigation. This year marks the launch of the first GPS receiver equipped earth-orbiting NASA spacecraft: the Extreme Ultraviolet Explorer and the Ocean Topography Experiment (TOPEX/Poseidon). This paper describes a cross section of GPS-based research at NASA.

Global Troposphere Experiment Project

NASA Technical Reports Server (NTRS)

Bandy, Alan R.; Thornton, Donald C.

1997-01-01

For the Global Troposphere Experiment project Pacific Exploratory Measurements West B (PEM West B), we made determinations of sulfur dioxide (SO2) and dimethyl sulfide (DMS) using gas chromatography-mass spectrometry with isotopically labelled internal standards. This technique provides measurements with precision of 1 part-per-trillion by volume below 20 pptv and 1% above 20 pptv. Measurement of DMS and SO2 were performed with a time cycle of 5-6 minutes with intermittent zero checks. The detection limits were about 1 pptv for SO2 and 2 pptv for DMS. Over 700 measurements of each compound were made in flight. Volcanic impacts on the upper troposphere were again found as a result of deep convection in the tropics. Extensive emission of SO2 from the Pacific Rim land masses were primarily observed in the lower well-mixed part of the boundary layer but also in the upper part of the boundary layer. Analyses of the SO2 data with aerosol sulfate, beryllium-7, and lead-210 indicated that SO2, contributed to half or more of the observed total oxidized sulfur (SO2 plus aerosol sulfate) in free tropospheric air. Cloud processing and rain appeared to be responsible for lower SO2 levels between 3 and 8.5 km than above or below this region. During both phases of PEM-West, dimethyl sulfide did not appear to be a major source of sulfur dioxide in the upper free troposphere over the western Pacific Ocean. In 1991 the sources Of SO2 at high altitude appeared to be both anthropogenic and volcanic with an estimated 1% being solely from DMS. The primary difference for the increase in the DMS source was the very low concentration of SO2 at high altitude. In the midlatitude region near the Asian land masses, DMS in the mixed layer was lower than in the tropical region of the western Pacific. Convective cloud systems near volcanoes in the tropical convergence in the western Pacific troposphere were a major source of SO2 at high altitudes during PEM-West B. High levels of SO2 were

A reinterpretation of the data from the NASA Stratosphere-Troposphere Exchange Project

NASA Astrophysics Data System (ADS)

Newman, Paul A.; Schoeberl, Mark R.

Data obtained during the NASA Stratosphere Troposphere Exchange Project (STEP) Mid-Latitude Field Experiment displayed laminae of ozone, water, and condensation nuclei in the stratosphere in association with a mid-latitude stratosphere-troposphere folding event. Danielsen et al. (1991) constructed cross sections of these observations, and interpreted these quasi-horizontal laminae as evidence of ultra-low frequency gravity waves. We use a new technique to show that these laminae could have resulted from differential advection, rather than transport by ultra-low frequency gravity waves. This new technique uses reverse domain filling back trajectories on multiple isentropic surfaces in conjunction with modified potential vorticity to reveal the qualitative details of the constituent laminae.

Quantifying the causes of differences in tropospheric OH within global models

NASA Astrophysics Data System (ADS)

Nicely, Julie M.; Salawitch, Ross J.; Canty, Timothy; Anderson, Daniel C.; Arnold, Steve R.; Chipperfield, Martyn P.; Emmons, Louisa K.; Flemming, Johannes; Huijnen, Vincent; Kinnison, Douglas E.; Lamarque, Jean-François; Mao, Jingqiu; Monks, Sarah A.; Steenrod, Stephen D.; Tilmes, Simone; Turquety, Solene

2017-02-01

The hydroxyl radical (OH) is the primary daytime oxidant in the troposphere and provides the main loss mechanism for many pollutants and greenhouse gases, including methane (CH4). Global mean tropospheric OH differs by as much as 80% among various global models, for reasons that are not well understood. We use neural networks (NNs), trained using archived output from eight chemical transport models (CTMs) that participated in the Polar Study using Aircraft, Remote Sensing, Surface Measurements and Models, of Climate, Chemistry, Aerosols and Transport Model Intercomparison Project (POLMIP), to quantify the factors responsible for differences in tropospheric OH and resulting CH4 lifetime (τCH4) between these models. Annual average τCH4, for loss by OH only, ranges from 8.0 to 11.6 years for the eight POLMIP CTMs. The factors driving these differences were quantified by inputting 3-D chemical fields from one CTM into the trained NN of another CTM. Across all CTMs, the largest mean differences in τCH4 (ΔτCH4) result from variations in chemical mechanisms (ΔτCH4 = 0.46 years), the photolysis frequency (J) of O3 → O(1D) (0.31 years), local O3 (0.30 years), and CO (0.23 years). The ΔτCH4 due to CTM differences in NOx (NO + NO2) is relatively low (0.17 years), although large regional variation in OH between the CTMs is attributed to NOx. Differences in isoprene and J(NO2) have negligible overall effect on globally averaged tropospheric OH, although the extent of OH variations due to each factor depends on the model being examined. This study demonstrates that NNs can serve as a useful tool for quantifying why tropospheric OH varies between global models, provided that essential chemical fields are archived.

Quantifying the Causes of Differences in Tropospheric OH Within Global Models

NASA Technical Reports Server (NTRS)

Nicely, Julie M.; Salawitch, Ross J.; Canty, Timothy; Anderson, Daniel C.; Arnold, Steve R.; Chipperfield, Martyn P.; Emmons, Louisa K.; Flemming, Johannes; Huijnen, Vincent; Kinnison, Douglas E.;

Global Distribution and Trends of Tropospheric Ozone: An Observation-Based Review

NASA Technical Reports Server (NTRS)

Cooper, O. R.; Parrish, D. D.; Ziemke, J.; Cupeiro, M.; Galbally, I. E.; Gilge, S.; Horowitz, L.; Jensen, N. R.; Lamarque, J.-F.; Naik, V.;

Tropospheric Chemistry

NASA Technical Reports Server (NTRS)

Mohnen, V.

1984-01-01

The fundamental processes that control the chemical composition and cycles of the global troposphere and how these processes and properties affect the physical behavior of the atmosphere are examined. The long-term information needs for tropospheric chemistry are: to be able to predict tropospheric responses to perturbations, both natural and anthropogenic, of these cycles, and to provide the information required for the maintenance and effective future management of the atmospheric component of our global life support system. The processes controlling global tropospheric biogeochemical cycles include: the input of trace species into the troposphere, their long-range transport and distribution as affected by the mean wind and vertical venting, their chemical transformations, including gas to particle conversion, leading to the appearance of aerosols or aqueous phase reactions inside cloud droplets, and their removal from the troposphere via wet (precipitation) and dry deposition.

Status of the first NASA EV-I Project, Tropospheric Emissions: Monitoring of Pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Chance, K.; Liu, X.; Suleiman, R. M.; Flittner, D. E.; Al-Saadi, J. A.; Janz, S. J.

2013-12-01

TEMPO is the first NASA Earth Venture Instrument. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO measures from Mexico City to the Canadian tar sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (2 km N/S × 4.5 km E/W at the center of its field of regard). The status of TEMPO including progress in instrument definition and implementation of the ground system will be presented. TEMPO provides a minimally-redundant measurement suite that includes all key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO will be delivered in 2017 for integration onto a NASA-selected GEO host spacecraft for launch as early as 2018. It will provide the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. Additional gases not central to air quality, including BrO, OClO, and IO will also be measured. TEMPO and its Asian (GEMS) and European (Sentinel-4) constellation partners make the first tropospheric trace gas measurements from GEO, building on the heritage of six spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed

Troposphere-Stratosphere Connections in Recent Northern Winters in NASA GEOS Assimilated Datasets

NASA Technical Reports Server (NTRS)

Pawson, Steven

2000-01-01

The northern winter stratosphere displays a wide range of interannual variability, much of which is believed to result from the response to the damping of upward-propagating waves. However, there is considerable (growing) evidence that the stratospheric state can also impact the tropospheric circulation. This issue will be examined using datasets generated in the Data Assimilation Office (DAO) at NASA's Goddard Space Flight Center. Just as the tropospheric circulation in each of these years was dominated by differing synoptic-scale structures, the stratospheric polar vortex also displayed different evolutions. The two extremes are the winter 1998/1999, when the stratosphere underwent a series of warming events (including two major warmings), and the winter 1999/2000, which was dominated by a persistent, cold polar vortex, often distorted by a dominant blocking pattern in the troposphere. This study will examine several operational and research-level versions of the DAO's systems. The 70-level-TRMM-system with a resolution of 2-by-2.5 degrees and the 48-level, 1-by-l-degree resolution ''Terra'' system were operational in 1998/1999 and 1999/2000, respectively. Research versions of the system used a 48-level, 2-by-2.5-degree configuration, which facilitates studies of the impact of vertical resolution. The study includes checks against independent datasets and error analyses, as well as the main issue of troposphere-stratosphere interactions.

Understanding global tropospheric ozone and its impacts on human health

NASA Astrophysics Data System (ADS)

West, J. J.

2017-12-01

Ozone is an important air pollutant for human health, one that has proven difficult to manage locally, nationally, and globally. Here I will present research on global ozone and its impacts on human health, highlighting several studies from my lab over the past decade. I will discuss the drivers of global tropospheric ozone, and the importance of the equatorward shift of emissions over recent decades. I will review estimates of the global burden of ozone on premature mortality, the contributions of different emission sectors to that burden, estimates of how the ozone health burden will change in the future under the Representative Concentration Pathway scenarios, and estimates of the contribution of projected climate change to ozone-related deaths. I will also discuss the importance of the intercontinental transport of ozone, and of methane as a driver of global ozone, from the human health perspective. I will present estimates of trends in the ozone mortality burden in the United States since 1990. Finally, I will discuss our project currently underway to estimate global ozone concentrations at the surface based on data gathered by the Tropospheric Ozone Assessment Report, combined statistically with atmospheric modeling results.

Observed and model-calculated NO2/NO ratios in tropospheric air sampled during the NASA GTE/CITE-2 field study

NASA Technical Reports Server (NTRS)

Chameides, W. L.; Davis, D. D.; Bradshaw, J.; Sandholm, S.; Rodgers, M.; Baum, B.; Ridley, B.; Gregory, G.; Torres, A.; Condon, E.

1990-01-01

Airborne measurements of NO2/NO ratios in the free troposphere, obtained using two-photon LIF (TP-LIF) and chemiluminescence (CL) detectors during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation 2 (CITE 2) program in summer 1986, are analyzed and compared with the predictions of a photochemical model. The derivation of the model is outlined, with an emphasis on the role of peroxy radicals in the fast photochemical cycling of NO and NO2 and the production of O3; the CITE 2 instruments and flight protocols are described; and the results are presented in extensive tables and graphs and discussed in detail. It was found that on three CITE 2 flights the CL data were systematically greater than the TP-LIF data; when these data were removed, the averaged values of the two instruments agreed to within 1 percent. The NO2/NO ratios predicted by the model are shown to be consistent with the measurements, although usually 20-25 percent lower.

Observations and Modeling of Composition of Upper Troposphere/Lower Stratosphere (UTILS): Isentropic Mixing Events and Morphology of HNO3 as Observed by HIRDLS and Comparison with Results from Global Modeling Initiative

NASA Technical Reports Server (NTRS)

Rodriquez, J. M.; Douglass, A.R.; Yoshida, Y.; Strahan, S.; Duncan, B.; Olsen, M.; Gille, J.; Yudin, V.; Nardi, B.

2008-01-01

isentropic exchange of air masses between the tropical upper troposphere and mid-latitude lowermost stratosphere (the so-called "middle world") is an important pathway for stratospheric-tropospheric exchange. A seasonal, global view of this process has been difficult to obtain, in part due to the lack of the vertical resolution in satellite observations needed to capture the laminar character of these events. Ozone observations at a resolution of about 1 km from the High Resolution Dynamic Limb Sounder (HIRDLS) on NASA's Aura satellite show instances of these intrusions. Such intrusions should also be observable in HN03 observations; however, the abundances of nitric acid could be additionally controlled by chemical processes or incorporation and removal into ice clouds. We present a systematic examination of the HIRDLS data on O3 and HNO3 to determine the seasonal and spatial characteristics of the distribution of isentropic intrusions. At the same time, we compare the observed distributions with those calculated by the Global Modeling Initiative combined tropospheric-stratospheric model, which has a vertical resolution of about I km. This Chemical Transport Model (CTM) is driven by meteorological fields obtained from the GEOS-4 system of NASA/Goddard Global Modeling and Assimilation Office (GMAO), for the Aura time period, at a vertical resolution of about 1 km. Such comparison brings out the successes and limitations of the model in representing isentropic stratospheric-tropospheric exchange, and the different processes controlling HNO3 in the UTAS.

Assessment of Techniques for Measuring Tropospheric H Sub x O Sub y

NASA Technical Reports Server (NTRS)

Hoell, J. M. (Editor)

1984-01-01

In its continuing efforts to direct its applications programs towards relevant national needs, NASA is conducting the Tropospheric Chemistry Program, the long-range objective of which is to apply NASA's space technology to assess and predict human impact on the troposphere, particularly on the regional to global scale. One area of required research is instrumentation development, which is aimed at improving the capability to measure important trace gases and aerosols which are key species in the major atmospheric biogeochemical cycles. To focus on specific needs, the Instrumentation Worksphop for H(x)O(y) Tropospheric Species was conducted in August 1982. The workshop discussed current measurement needs and instrument capabilities for H(x)O(y) species, including OH, HO2, and H2O2. The workshop activities and conclusions are documented.

Reducing Noise in the MSU Daily Lower-Tropospheric Global Temperature Dataset

NASA Technical Reports Server (NTRS)

Christy, John R.; Spencer, Roy W.; McNider, Richard T.

1996-01-01

The daily global-mean values of the lower-tropospheric temperature determined from microwave emissions measured by satellites are examined in terms of their signal, noise, and signal-to-noise ratio. Daily and 30-day average noise estimates are reduced by almost 50% and 35%. respectively, by analyzing and adjusting (if necessary) for errors due to 1) missing data, 2) residual harmonics of the annual cycle unique to particular satellites, 3) lack of filtering, and 4) spurious trends. After adjustments, the decadal trend of the lower-tropospheric global temperature from January 1979 through February 1994 becomes -0.058 C. or about 0.03 C per decade cooler than previously calculated.

Reducing Noise in the MSU Daily Lower-Tropospheric Global Temperature Dataset

NASA Technical Reports Server (NTRS)

Christy, John R.; Spencer, Roy W.; McNider, Richard T.

1995-01-01

The daily global-mean values of the lower-tropospheric temperature determined from microwave emissions measured by satellites are examined in terms of their signal, noise, and signal-to-noise ratio. Daily and 30-day average noise estimates are reduced by, almost 50% and 35%, respectively, by analyzing and adjusting (if necessary) for errors due to (1) missing data, (2) residual harmonics of the annual cycle unique to particular satellites, (3) lack of filtering, and (4) spurious trends. After adjustments, the decadal trend of the lower-tropospheric global temperature from January 1979 through February 1994 becomes -0.058 C, or about 0.03 C per decade cooler than previously calculated.

GreenHouse gas Observations of the Stratosphere and Troposphere (GHOST): Deployment of a Novel Shortwave Infrared Spectrometer On Board the NASA Global Hawk Unmanned Aerial Vehicle

NASA Astrophysics Data System (ADS)

Humpage, N.; Boesch, H.; Palmer, P. I.; Parr-Burman, P.; Vick, A.; Bezawada, N.; Black, M.; Born, A.; Gao, X.; Pearson, D.; Samara-Ratna, P.; Strachan, J.; Wells, M.

2015-12-01

GHOST is a novel, compact shortwave infrared spectrometer, designed for remote sensing of tropospheric columns of greenhouse gases (GHGs) over the ocean from an unmanned aircraft. This is achieved by observing solar radiation at high spectral resolution which has been directly reflected by the ocean surface. The GHOST system has been specifically designed and built to address the following science objectives: 1) testing of atmospheric transport models; 2) validation of GHG column observations over oceans obtained using polar orbiting satellites; and 3) complement in-situ tropopause transition layer observations from other instruments. During January and February 2015 GHOST successfully underwent rigorous environmental testing and was installed on board the Northrop Grumman Global Hawk N872NA, an unmanned aircraft operated by NASA from the Armstrong Flight Research Centre at Edwards Air Force Base, California. Here, we present first results from two Global Hawk flights which took place in March 2015 as part of the CAST-ATTREX campaign. The science flights comprised long, approximately north-south transects over the eastern Pacific Ocean, providing an opportunity to observe spatial trends in GHG column concentrations on regional scale. The second science flight on 10th March 2015 coincided with overpasses from both the NASA OCO-2 (Orbiting Carbon Observatory) and the JAXA GOSAT (Greenhouse gases Observing SATellite) satellites, enabling inter-comparison of the GHOST results with total column observations from both satellites. A TCCON (Total Carbon Column Observing Network) station was also operational at Edwards during the two flights, allowing the GHOST observations to be validated against ground based total column measurements of GHGs.

Improved simulation of tropospheric ozone by a global-multi-regional two-way coupling model system

NASA Astrophysics Data System (ADS)

Yan, Y.; Lin, J.; Hu, L.; Chen, J.

2016-12-01

Small-scale nonlinear chemical and physical processes over pollution source regions affect the tropospheric ozone, but these processes are not captured by current global chemical transport models and chemistry-climate models that are limited by coarse horizontal resolutions. These models tend to contain large (and mostly positive) tropospheric O3 biases in the Northern Hemisphere. Here we use a recently built two-way coupling system of the GEOS-Chem CTM to simulate the regional and global tropospheric O3in 2009. The system couples the global model (at 2.5º long. x 2º lat.) and its three nested models (at 0.667º long. x 0.5º lat.) covering Asia, North America and Europe, respectively. Specifically, the nested models take lateral boundary conditions from the global model, better capture small-scale processes, and feed back to modify the global model simulation within the nested domains, with a subsequent effect on their LBCs. Compared to the global model alone, the two-way coupled system better simulates the tropospheric O3 both within and outside the nested domains, as found by evaluation against a suite of ground (1420 sites from WDCGG, GMD, EMEP, and AQS), aircraft (HIPPO and MOZAIC), and satellite measurements (two OMI products). The two-way coupled simulation enhances the correlation in day-to-day variation of afternoon mean surface O3 with the ground measurements from 0.53 to 0.68, and it reduces the mean model bias from 10.8 to 6.7 ppb. Regionally, the coupled system reduces the bias by 4.6 ppb over Europe, 3.9 ppb over North America, and 3.1 ppb over other regions. The two-way coupling brings O3vertical profiles much closer to the HIPPO (for remote areas) and MOZAIC (for polluted regions) data, reducing the tropospheric mean bias by 3-10 ppb at most MOZAIC sites and by 5.3 ppb for HIPPO profiles. The two-way coupled simulation also reduces the global tropospheric column ozone by 3.0 DU (9.5%, annual mean), bringing them closer to the OMI data in all

Improved simulation of tropospheric ozone by a global-multi-regional two-way coupling model system

NASA Astrophysics Data System (ADS)

Yan, Y.-Y.; Lin, J.-T.; Chen, J.; Hu, L.

2015-09-01

Small-scale nonlinear chemical and physical processes over pollution source regions affect the global ozone (O3) chemistry, but these processes are not captured by current global chemical transport models (CTMs) and chemistry-climate models that are limited by coarse horizontal resolutions (100-500 km, typically 200 km). These models tend to contain large (and mostly positive) tropospheric O3 biases in the Northern Hemisphere. Here we use a recently built two-way coupling system of the GEOS-Chem CTM to simulate the global tropospheric O3 in 2009. The system couples the global model (at 2.5° long. × 2° lat.) and its three nested models (at 0.667° long. × 0.5° lat.) covering Asia, North America and Europe, respectively. Benefiting from the high resolution, the nested models better capture small-scale processes than the global model alone. In the coupling system, the nested models provide results to modify the global model simulation within respective nested domains while taking the lateral boundary conditions from the global model. Due to the "coupling" effects, the two-way system significantly improves the tropospheric O3 simulation upon the global model alone, as found by comparisons with a suite of ground (1420 sites from WDCGG, GMD, EMEP, and AQS), aircraft (HIPPO and MOZAIC), and satellite measurements (two OMI products). Compared to the global model alone, the two-way coupled simulation enhances the correlation in day-to-day variation of afternoon mean O3 with the ground measurements from 0.53 to 0.68, and it reduces the mean model bias from 10.8 to 6.7 ppb in annual average afternoon O3. Regionally, the coupled model reduces the bias by 4.6 ppb over Europe, 3.9 ppb over North America, and 3.1 ppb over other regions. The two-way coupling brings O3 vertical profiles much closer to the HIPPO (for remote areas) and MOZAIC (for polluted regions) data, reducing the tropospheric (0-9 km) mean bias by 3-10 ppb at most MOZAIC sites and by 5.3 ppb for HIPPO

NASA Global Hawk Overview

NASA Technical Reports Server (NTRS)

Naftel, Chris

2014-01-01

The NASA Global Hawk Project is supporting Earth Science research customers. These customers include: US Government agencies, civilian organizations, and universities. The combination of the Global Hawks range, endurance, altitude, payload power, payload volume and payload weight capabilities separates the Global Hawk platform from all other platforms available to the science community. This presentation includes an overview of the concept of operations and an overview of the completed science campaigns. In addition, the future science plans, using the NASA Global Hawk System, will be presented.

A New Retrieval Algorithm for OMI NO2: Tropospheric Results and Comparisons with Measurements and Models

NASA Technical Reports Server (NTRS)

Swartz, W. H.; Bucesla, E. J.; Lamsal, L. N.; Celarier, E. A.; Krotkov, N. A.; Bhartia, P, K,; Strahan, S. E.; Gleason, J. F.; Herman, J.; Pickering, K.

2012-01-01

Nitrogen oxides (NOx =NO+NO2) are important atmospheric trace constituents that impact tropospheric air pollution chemistry and air quality. We have developed a new NASA algorithm for the retrieval of stratospheric and tropospheric NO2 vertical column densities using measurements from the nadir-viewing Ozone Monitoring Instrument (OMI) on NASA's Aura satellite. The new products rely on an improved approach to stratospheric NO2 column estimation and stratosphere-troposphere separation and a new monthly NO2 climatology based on the NASA Global Modeling Initiative chemistry-transport model. The retrieval does not rely on daily model profiles, minimizing the influence of a priori information. We evaluate the retrieved tropospheric NO2 columns using surface in situ (e.g., AQS/EPA), ground-based (e.g., DOAS), and airborne measurements (e.g., DISCOVER-AQ). The new, improved OMI tropospheric NO2 product is available at high spatial resolution for the years 200S-present. We believe that this product is valuable for the evaluation of chemistry-transport models, examining the spatial and temporal patterns of NOx emissions, constraining top-down NOx inventories, and for the estimation of NOx lifetimes.

NASA's Global Hawk

NASA Image and Video Library

2014-09-23

View from a Chase Plane; HS3 Science Flight 8 Wraps Up The chase plane accompanying NASA's Global Hawk No. 872 captured this picture on Sept. 19 after the Global Hawk completed science flight #8 where it gathered data from a weakening Tropical Storm Edouard over the North Atlantic Ocean. Credit: NASA -- The Hurricane and Severe Storm Sentinel (HS3) is a five-year mission specifically targeted to investigate the processes that underlie hurricane formation and intensity change in the Atlantic Ocean basin. HS3 is motivated by hypotheses related to the relative roles of the large-scale environment and storm-scale internal processes. Read more: espo.nasa.gov/missions/hs3/mission-gallery NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Sensitivity of Photolysis Frequencies and Key Tropospheric Oxidants in a Global Model to Cloud Vertical Distributions and Optical Properties

NASA Technical Reports Server (NTRS)

Liu, Hongyu; Crawford, James H.; Considine, David B.; Platnick, Steven; Norris, Peter M.; Duncan, Bryan N.; Pierce, Robert B.; Chen, Gao; Yantosca, Robert M.

2009-01-01

Clouds affect tropospheric photochemistry through modification of solar radiation that determines photolysis frequencies. As a follow-up study to our recent assessment of the radiative effects of clouds on tropospheric chemistry, this paper presents an analysis of the sensitivity of such effects to cloud vertical distributions and optical properties (cloud optical depths (CODs) and cloud single scattering albedo), in a global 3-D chemical transport model (GEOS-Chem). GEOS-Chem was driven with a series of meteorological archives (GEOS1- STRAT, GEOS-3 and GEOS-4) generated by the NASA Goddard Earth Observing System data assimilation system. Clouds in GEOS1-STRAT and GEOS-3 have more similar vertical distributions (with substantially smaller CODs in GEOS1-STRAT) while those in GEOS-4 are optically much thinner in the tropical upper troposphere. We find that the radiative impact of clouds on global photolysis frequencies and hydroxyl radical (OH) is more sensitive to the vertical distribution of clouds than to the magnitude of column CODs. With random vertical overlap for clouds, the model calculated changes in global mean OH (J(O1D), J(NO2)) due to the radiative effects of clouds in June are about 0.0% (0.4%, 0.9%), 0.8% (1.7%, 3.1%), and 7.3% (4.1%, 6.0%), for GEOS1-STRAT, GEOS-3 and GEOS-4, respectively; the geographic distributions of these quantities show much larger changes, with maximum decrease in OH concentrations of approx.15-35% near the midlatitude surface. The much larger global impact of clouds in GEOS-4 reflects the fact that more solar radiation is able to penetrate through the optically thin upper-tropospheric clouds, increasing backscattering from low-level clouds. Model simulations with each of the three cloud distributions all show that the change in the global burden of ozone due to clouds is less than 5%. Model perturbation experiments with GEOS-3, where the magnitude of 3-D CODs are progressively varied from -100% to 100%, predict only modest

Tropospheric Ozone from Assimilation of Aura Data using Different Definitions of the Tropopause

NASA Technical Reports Server (NTRS)

Stajner, Ivanka; Wargan, K.; Chang, L.-P.; Hayashi, H.; Pawson, S.; Pawson, Steven; Livesey, N.; Bhartia, P. K.

2006-01-01

Ozone data from Aura OMI and MLS instruments were assimilated into the general circulation model (GCM) constrained by assimilated meteorological fields from the Global Modeling and Assimilation Office at NASA Goddard. Properties of tropospheric ozone and their sensitivity to the definition of the tropopause are investigated. Three definitions of the tropopause are considered: (1) dynamical (using potential vorticity and potential temperature), (2) using temperature lapse rate, and (3) using a fixed ozone value. Comparisons of the tropospheric ozone columns using these tropopause definitions will be presented and evaluated against coincident profiles from ozone sondes. Assimilated ozone profiles are used to identify possible tropopause folding events, which are important for stratosphere-troposphere exchange. Each profile is searched for multiple levels at which ozone attains the value typical of the troposphere-stratosphere transition in order to identify possible tropopause folds. Constrained by the dynamics from a global model and by assimilation of Aura ozone data every 3-hours, this data set provides an opportunity to study ozone evolution in the upper troposphere and lower stratosphere with high temporal resolution.

Tropospheric and stratospheric ozone from assimilation of Aura data

NASA Technical Reports Server (NTRS)

Stajner, I.; Wargan, K.; Chang, L.-P.; Hayashi, H.; Pawwson, S.; Froidevaux, L.; Livesey, N.; Bhartia, P. K.

2006-01-01

Ozone is an atmospheric trace gas with multiple impacts on the environment. Global ozone fields are needed for air quality predictions, estimation of the ultraviolet radiation reaching the surface, climate-radiation studies, and may also have an impact on longer-term weather predictions. We estimate global ozone fields in the stratosphere and troposphere by combining the data from EOS Aura satellite with an ozone model using data assimilation. Ozone exhibits a large temporal variability in the lower stratosphere. Our previous work showed that assimilation of satellite data from limb-sounding geometry helps constrain ozone profiles in that region. We assimilated ozone data from the Aura Microwave Limb Sounder (MLS) and the Ozone Monitoring Instrument (OMI) into the ozone system at NASA's Global Modeling and Assimilation Office (GMAO). Ozone is transported within a general circulation model (GCM) which includes parameterizations for stratospheric photochemistry, tropospheric chemistry, and a simple scheme for heterogeneous ozone loss. The focus of this study is on the representation of ozone in the lower stratosphere and tropospheric ozone columns. We plan to extend studies of tropospheric ozone distribution through assimilation of ozone data from the Tropospheric Emission Spectrometer (TES). Comparisons with ozone sondes and occultation data show that assimilation of Aura data reproduces ozone gradients and variability in the lower stratosphere well. We proceed by separating the contributions to temporal changes in the ozone field into those that are due to the model and those that are due to the assimilation of Aura data. The impacts of Aura data are illustrated and their role in the representation of ozone variability in the lower stratosphere and troposphere is shown.

Discoveries about Tropical Tropospheric Ozone from Satellite and SHADOZ (Southern Hemisphere Additional Ozonesondes) and a Future Perspective on NASA's Ozone Sensors

NASA Technical Reports Server (NTRS)

Thompson, Anne

2003-01-01

We have been producing near-real tropical tropospheric ozone ('TTO') data from TOMS since 1997 with Prof. Hudson and students at the University of Maryland. Maps for 1996-2000 for the operational Earth-Probe instrument reside at: . We also have archived 'TTO' data from the Nimbus 7/TOMS satellite (1979-1992). The tropics is a region strongly influenced by natural variability and anthropogenic activity and the satellite data have been used to track biomass burning pollution and to detect interannual variability and climate signals in ozone. We look forward to future ozone sensors from NASA; four will be launched in 2004 as part of the EOS AURA Mission. The satellite view of chemical-dynamical interactions in tropospheric ozone is not adequate to capture vertical variability. Thus, in 1998, NASA's Goddard Space Flight Center, NOAA's Climate Monitoring and Diagnostics Laboratory (CMDL) and a team of international sponsors established the SHADOZ (Southern Hemisphere ADditional OZonesondes) project to address the gap in tropical ozone soundings. SHADOZ augments launches at selected sites and provides a public archive of ozonesonde data from twelve tropical and subtropical stations at http://croc.nsfc.nasa.gov/shadoz. The stations are: Ascension Island; Nairobi, Kenya; Irene, South Africa; R,union Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil, Malindi, Kenya; Paramaribo, Surinam. From the first 3-4 years of data (presently greater than 1700 sondes), the following features emerge: (a) highly variable tropospheric ozone; (b) a zonal wave-one pattern in tropospheric column ozone; (c) tropospheric ozone variability over the Indian and Pacific Ocean displays strong convective signatures.

Improved simulation of tropospheric ozone by a global-multi-regional two-way coupling model system

NASA Astrophysics Data System (ADS)

Yan, Yingying; Lin, Jintai; Chen, Jinxuan; Hu, Lu

2016-02-01

Small-scale nonlinear chemical and physical processes over pollution source regions affect the tropospheric ozone (O3), but these processes are not captured by current global chemical transport models (CTMs) and chemistry-climate models that are limited by coarse horizontal resolutions (100-500 km, typically 200 km). These models tend to contain large (and mostly positive) tropospheric O3 biases in the Northern Hemisphere. Here we use the recently built two-way coupling system of the GEOS-Chem CTM to simulate the regional and global tropospheric O3 in 2009. The system couples the global model (at 2.5° long. × 2° lat.) and its three nested models (at 0.667° long. × 0.5° lat.) covering Asia, North America and Europe, respectively. Specifically, the nested models take lateral boundary conditions (LBCs) from the global model, better capture small-scale processes and feed back to modify the global model simulation within the nested domains, with a subsequent effect on their LBCs. Compared to the global model alone, the two-way coupled system better simulates the tropospheric O3 both within and outside the nested domains, as found by evaluation against a suite of ground (1420 sites from the World Data Centre for Greenhouse Gases (WDCGG), the United States National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory Global Monitoring Division (GMD), the Chemical Coordination Centre of European Monitoring and Evaluation Programme (EMEP), and the United States Environmental Protection Agency Air Quality System (AQS)), aircraft (the High-performance Instrumented Airborne Platform for Environmental Research (HIAPER) Pole-to-Pole Observations (HIPPO) and Measurement of Ozone and Water Vapor by Airbus In- Service Aircraft (MOZAIC)) and satellite measurements (two Ozone Monitoring Instrument (OMI) products). The two-way coupled simulation enhances the correlation in day-to-day variation of afternoon mean surface O3 with the ground measurements

The global warming potential of methane reassessed with combined stratosphere and troposphere chemistry

NASA Astrophysics Data System (ADS)

Holmes, C. D.; Archibald, A. T.; Eastham, S. D.; Søvde, O. A.

2017-12-01

Methane is a direct and indirect greenhouse gas. The direct greenhouse effect comes from the radiation absorbed and emitted by methane itself. The indirect greenhouse effect comes from radiatively active gases that are produced during methane oxidation: principally O3, H2O, and CO2. Methane also suppresses tropospheric OH, which indirectly affects numerous greenhouses gases and aerosols. Traditionally, the methane global warming potential (GWP) has included the indirect effects on tropospheric O3 and OH and stratospheric H2O, with these effects estimated independently from unrelated tropospheric and stratospheric chemistry models and observations. Using this approach the CH4 is about 28 over 100 yr (without carbon cycle feedbacks, IPCC, 2013). Here we present a comprehensive analysis of the CH4 GWP in several 3-D global atmospheric models capable of simulating both tropospheric and stratospheric chemistry (GEOS-Chem, Oslo CTM3, UKCA). This enables us to include, for the first time, the indirect effects of CH4 on stratospheric O3 and stratosphere-troposphere coupling. We diagnose the GWP from paired simulations with and without a 5% perturbation to tropospheric CH4 concentrations. Including stratospheric chemistry nearly doubles the O3 contribution to CH4 GWP because of O3 production in the lower stratosphere and because CH4 inhibits Cl-catalyzed O3 loss in the upper stratosphere. In addition, stratosphere-troposphere coupling strengthens the chemical feedback on its own lifetime. In the stratosphere, this feedback operates by a CH4 perturbation thickening the stratospheric O3 layer, which impedes UV-driven OH production in the troposphere and prolongs the CH4 lifetime. We also quantify the impact of CH4-derived H2O on the stratospheric HOx cycles but these effects are small. Combining all of the above, these models suggest that the 100-yr GWP of CH4 is over 33.5, a 20% increase over the latest IPCC assessment.

Online Simulations and Forecasts of the Global Aerosol Distribution in the NASA GEOS-5 Model

NASA Technical Reports Server (NTRS)

Colarco, Peter

2006-01-01

We present an analysis of simulations of the global aerosol system in the NASA GEOS-5 transport, radiation, and chemistry model. The model includes representations of all major tropospheric aerosol species, including dust, sea salt, black carbon, particulate organic matter, and sulfates. The aerosols are run online for the period 2000 through 2005 in a simulation driven by assimilated meteorology from the NASA Goddard Data Assimilation System. Aerosol surface mass concentrations are compared with existing long-term surface measurement networks. Aerosol optical thickness is compared with ground-based AERONET sun photometry and space-based retrievals from MODIS, MISR, and OMI. Particular emphasis is placed here on consistent sampling of model and satellite aerosol optical thickness to account for diurnal variations in aerosol optical properties. Additionally, we illustrate the use of this system for providing chemical weather forecasts in support of various NASA and community field missions.

NASA Global Atmospheric Sampling Program (GASP) data report for tape VL0006

NASA Technical Reports Server (NTRS)

Gauntner, D. J.; Holdeman, J. D.; Humenik, F. M.

1977-01-01

The NASA Global Atmospheric Sampling Program (GASP) is obtaining measurements of atmospheric trace constituents in the upper troposphere and lower stratosphere using fully automated air sampling systems on board several commercial B-747 aircraft in routine airline service. Atmospheric ozone, and related flight and meteorological data were obtained during 245 flights of a Qantas Airways of Australia B-747 and two Pan American World Airways B-747s from July 1976 through September 1976. In addition, whole air samples, obtained during three flights, were analyzed for trichlorofluoromethane, and filter samples, obtained during four flights, were analyzed for sulfates, nitrates, fluorides, and chlorides. Flight routes and dates, instrumentation, data processing procedures, data tape specifications, and selected analyses are discussed.

First Directly Retrieved Global Distribution of Tropospheric Column Ozone from GOME: Comparison with the GEOS-CHEM Model

NASA Technical Reports Server (NTRS)

Liu, Xiong; Chance, Kelly; Sioris, Christopher E.; Kurosu, Thomas P.; Spurr, Robert J. D.; Martin, Randall V.; Fu, Tzung-May; Logan, Jennifer A.; Jacob, Daniel J.; Palmer, Paul I.;

Global Radiative Forcing of Coupled Tropospheric Ozone and Aerosols in a Unified General Circulation Model

NASA Technical Reports Server (NTRS)

Liao, Hong; Seinfeld, John H.; Adams, Peter J.; Mickley, Loretta J.

2008-01-01

Global simulations of sea salt and mineral dust aerosols are integrated into a previously developed unified general circulation model (GCM), the Goddard Institute for Space Studies (GISS) GCM II', that simulates coupled tropospheric ozone-NOx-hydrocarbon chemistry and sulfate, nitrate, ammonium, black carbon, primary organic carbon, and secondary organic carbon aerosols. The fully coupled gas-aerosol unified GCM allows one to evaluate the extent to which global burdens, radiative forcing, and eventually climate feedbacks of ozone and aerosols are influenced by gas-aerosol chemical interactions. Estimated present-day global burdens of sea salt and mineral dust are 6.93 and 18.1 Tg with lifetimes of 0.4 and 3.9 days, respectively. The GCM is applied to estimate current top of atmosphere (TOA) and surface radiative forcing by tropospheric ozone and all natural and anthropogenic aerosol components. The global annual mean value of the radiative forcing by tropospheric ozone is estimated to be +0.53 W m(sup -2) at TOA and +0.07 W m(sup -2) at the Earth's surface. Global, annual average TOA and surface radiative forcing by all aerosols are estimated as -0.72 and -4.04 W m(sup -2), respectively. While the predicted highest aerosol cooling and heating at TOA are -10 and +12 W m(sup -2) respectively, surface forcing can reach values as high as -30 W m(sup -2), mainly caused by the absorption by black carbon, mineral dust, and OC. We also estimate the effects of chemistry-aerosol coupling on forcing estimates based on currently available understanding of heterogeneous reactions on aerosols. Through altering the burdens of sulfate, nitrate, and ozone, heterogeneous reactions are predicted to change the global mean TOA forcing of aerosols by 17% and influence global mean TOA forcing of tropospheric ozone by 15%.

Evaluating Effects of H2O and overhead O3 on Global Mean Tropospheric OH Concentration

NASA Technical Reports Server (NTRS)

Nicely, Julie M.; Salawitch, R.J.; Canty, T.; Lang, Chang; Duncan, Bryan; Liang, Qing; Oman, Luke David; Stolarski, Richard S.; Waugh, Darryn

2012-01-01

The oxidizing capacity of the troposphere is controlled, to a large extent, by the abundance of hydroxyl radical (OH). The global mean concentration of OH, [OH]GLOBAL, inferred from measurements of methyl chloroform, has remained relatively constant during the past several decades, despite rising levels of CH4 that should have led to a steady decline. Here we examine other factors that may have affected [OH]GLOBAL, such as the overhead burden of stratospheric O3 and tropospheric H2O, using global OH fields from the GEOS-CHEM Chemistry-Climate Model. Our analysis suggests these factors may have contributed a positive trend to [OH]GLOBAL large enough to counter the decrease due to CH4.

Tropospheric Ozone as a Short-lived Chemical Climate Forcer

NASA Technical Reports Server (NTRS)

Pickering, Kenneth E.

2012-01-01

Tropospheric ozone is the third most important greenhouse gas according to the most recent IPCC assessment. However, tropospheric ozone is highly variable in both space and time. Ozone that is located in the vicinity of the tropopause has the greatest effect on climate forcing. Nitrogen oxides (NOx) are the most important precursors for ozone In most of the troposphere. Therefore, pollution that is lofted upward in thunderstorm updrafts or NOx produced by lightning leads to efficient ozone production in the upper troposphere, where ozone is most important climatically. Global and regional model estimates of the impact of North American pollution and lightning on ozone radiative forcing will be presented. It will be shown that in the Northern Hemisphere summer, the lightning effect on ozone radiative forcing can dominate over that of pollution, and that the radiative forcing signal from North America extends well into Europe and North Africa. An algorithm for predicting lightning flash rates and estimating lightning NOx emissions is being incorporated into the NASA GEOS-5 Chemistry and Climate Model. Changes in flash rates and emissions over an ENSO cycle and in future climates will be assessed, along with the resulting changes in upper tropospheric ozone. Other research on the production of NOx per lightning flash and its distribution in the vertical based on cloud-resolving modeling and satellite observations will be presented. Distributions of NO2 and O3 over the Middle East from the OMI instrument on NASA's Aura satellite will also be shown.

Greenhouse Observations of the Stratosphere and Troposphere (GHOST): a novel shortwave infrared spectrometer developed for the Global Hawk unmanned aerial vehicle

NASA Astrophysics Data System (ADS)

Humpage, Neil; Boesch, Hartmut; Palmer, Paul; Parr-Burman, Phil; Vick, Andy; Bezawada, Naidu; Black, Martin; Born, Andy; Pearson, David; Strachan, Jonathan; Wells, Martyn

2014-05-01

The tropospheric distribution of greenhouse gases (GHGs) is dependent on surface flux variations, atmospheric chemistry and transport processes over a wide range of spatial and temporal scales. Errors in assumed atmospheric transport can adversely affect surface flux estimates inferred from surface, aircraft or satellite observations of greenhouse gas concentrations using inverse models. We present a novel, compact shortwave infrared spectrometer (GHOST) for installation on the NASA Global Hawk unmanned aerial vehicle to provide tropospheric column observations of CO2, CO, CH4, H2O and HDO over the ocean to address the need for large-scale, simultaneous, finely resolved measurements of key GHGs. These species cover a range of lifetimes and source processes, and measurements of their tropospheric columns will reflect the vertically integrated signal of their vertical and horizontal transport within the troposphere. The primary science objectives of GHOST are to: 1) provide observations which can be used to test atmospheric transport models; 2) validate satellite observations of GHG column observations over oceans, thus filling a critical gap in current validation capabilities; and 3) complement in-situ tropopause transition layer tracer observations from other instrumentation on board the Global Hawk to provide a link between upper and lower troposphere concentration measurements. The GHOST spectrometer system comprises a target acquisition module (TAM), a fibre slicer and feed system, and a multiple order spectrograph. The TAM design utilises a gimbal behind an optical dome, which is programmed to direct solar radiation reflected by the ocean surface into a fibre optic bundle. The fibre slicer and feed system then splits the light into the four spectral bands using order sorting filters. The fibres corresponding to each band are arranged with a small sideways offset to correctly centre each spectrum on the detector array. The spectrograph design is unique in that a

GreenHouse Observations of the Stratosphere and Troposphere (GHOST): a novel shortwave infrared spectrometer developed for the Global Hawk unmanned aerial vehicle

NASA Astrophysics Data System (ADS)

Humpage, Neil; Bösch, Hartmut; Palmer, Paul I.; Parr-Burman, Phil M.; Vick, Andrew J. A.; Bezawada, Naidu N.; Black, Martin; Born, Andrew J.; Pearson, David; Strachan, Jonathan; Wells, Martyn

2014-10-01

The tropospheric distribution of greenhouse gases (GHGs) depends on surface flux variations, atmospheric chemistry and transport processes over a range of spatial and temporal scales. Accurate and precise atmospheric concentration observations of GHGs can be used to infer surface flux estimates, though their interpretation relies on unbiased atmospheric transport models. GHOST is a novel, compact shortwave infrared spectrometer which will observe tropospheric columns of CO2, CO, CH4 and H2O (along with the HDO/H2O ratio) during deployment on board the NASA Global Hawk unmanned aerial vehicle. The primary science objectives of GHOST are to: 1) test atmospheric transport models; 2) evaluate satellite observations of GHG column observations over oceans; and 3) complement in-situ tropopause transition layer observations from other Global Hawk instruments. GHOST comprises a target acquisition module (TAM), a fibre slicer and feed system, and a multiple order spectrograph. The TAM is programmed to direct solar radiation reflected by the ocean surface into a fibre optic bundle. Incoming light is then split into four spectral bands, selected to optimise remote observations of GHGs. The design uses a single grating and detector for all four spectral bands. We summarise the GHOST concept and its objectives, and describe the instrument design and proposed deployment aboard the Global Hawk platform.

Observing Tropospheric Ozone From Space

NASA Technical Reports Server (NTRS)

Fishman, Jack

2000-01-01

The importance of tropospheric ozone embraces a spectrum of relevant scientific issues ranging from local environmental concerns, such as damage to the biosphere and human health, to those that impact global change questions, Such is climate warming. From an observational perspective, the challenge is to determine the tropospheric ozone global distribution. Because its lifetime is short compared with other important greenhouse gases that have been monitored over the past several decades, the distribution of tropospheric ozone cannot be inferred from a relatively small set of monitoring stations. Therefore, the best way to obtain a true global picture is from the use of space-based instrumentation where important spatial gradients over vast ocean expanses and other uninhabited areas can be properly characterized. In this paper, the development of the capability to measure tropospheric ozone from space over the past 15 years is summarized. Research in the late 1980s successfully led to the determination of the climatology of tropospheric ozone as a function of season; more recently, the methodology has improved to the extent where regional air pollution episodes can be characterized. The most recent modifications now provide quasi-global (50 N) to 50 S) maps on a daily basis. Such a data set would allow for the study of long-range (intercontinental) transport of air pollution and the quantification of how regional emissions feed into the global tropospheric ozone budget. Future measurement capabilities within this decade promise to offer the ability to provide Concurrent maps of the precursors to the in situ formation of tropospheric ozone from which the scientific community will gain unprecedented insight into the processes that control global tropospheric chemistry

Linking Urban Air Pollution to Global Tropospheric Chemistry and Climate

NASA Technical Reports Server (NTRS)

Wang, Chien

2005-01-01

The two major tasks of this project are to study: (a) the impact of urban nonlinear chemistry on chemical budgets of key pollutants in non-urban areas; and (b) the influence of air pollution control strategies in selected metropolitan areas, particularly of emerging economies in East and South Asia, on tropospheric chemistry and hence on regional and global climate.

The Tropospheric Wind Lidar Technology Experiment (TWiLiTE): An Airborne Direct Detection Doppler Lidar Instrument Development Program

NASA Technical Reports Server (NTRS)

Gentry, Bruce; McGill, Matthew; Schwemmer, Geary; Hardesty, Michael; Brewer, Alan; Wilkerson, Thomas; Atlas, Robert; Sirota, Marcos; Lindemann, Scott

2006-01-01

Global measurement of tropospheric winds is a key measurement for understanding atmospheric dynamics and improving numerical weather prediction. Global wind profiles remain a high priority for the operational weather community and also for a variety of research applications including studies of the global hydrologic cycle and transport studies of aerosols and trace species. In addition to space based winds, a high altitude airborne system flown on UAV or other advanced platforms would be of great interest for studying mesoscale dynamics and hurricanes. The Tropospheric Wind Lidar Technology Experiment (TWiLiTE) project was selected in 2005 by the NASA Earth Sun Technology Office as part of the Instrument Incubator Program. TWiLiTE will leverage significant research and development investments in key technologies made in the past several years. The primary focus will be on integrating these sub-systems into a complete molecular direct detection Doppler wind lidar system designed for autonomous operation on a high altitude aircraft, such as the NASA WB57, so that the nadir viewing lidar will be able to profile winds through the full troposphere. TWiLiTE is a collaboration involving scientists and technologists from NASA Goddard, NOAA ESRL, Utah State University Space Dynamics Lab and industry partners Michigan Aerospace Corporation and Sigma Space Corporation. NASA Goddard and it's partners have been at the forefront in the development of key lidar technologies (lasers, telescopes, scanning systems, detectors and receivers) required to enable spaceborne global wind lidar measurement. The TWiLiTE integrated airborne Doppler lidar instrument will be the first demonstration of a airborne scanning direct detection Doppler lidar and will serve as a critical milestone on the path to a fixture spaceborne tropospheric wind system. The completed system will have the capability to profile winds in clear air from the aircraft altitude of 18 h to the surface with 250 m vertical

Global observations of tropospheric BrO columns using GOME-2 satellite data

NASA Astrophysics Data System (ADS)

Theys, N.; van Roozendael, M.; Hendrick, F.; Yang, X.; de Smedt, I.; Richter, A.; Begoin, M.; Errera, Q.; Johnston, P. V.; Kreher, K.; de Mazière, M.

2010-11-01

Measurements from the GOME-2 satellite instrument have been analyzed for tropospheric BrO using a residual technique that combines measured BrO columns and estimates of the stratospheric BrO content from a climatological approach driven by O3 and NO2 observations. Comparisons between the GOME-2 results and BrO vertical columns derived from correlative ground-based and SCIAMACHY nadir observations, present a good level of consistency. We show that the adopted technique enables separation of stratospheric and tropospheric fractions of the measured total BrO columns and allows quantitative study of the BrO plumes in polar regions. While some satellite observed plumes of enhanced BrO can be explained by stratospheric descending air, we show that most BrO hotspots are of tropospheric origin, although they are often associated to regions with low tropopause heights as well. Elaborating on simulations using the p-TOMCAT tropospheric chemical transport model, this result is found to be consistent with the mechanism of bromine release through sea salt aerosols production during blowing snow events. Outside polar regions, evidence is provided for a global tropospheric BrO background with column of 1-3×1013 molec/cm2, consistent with previous estimates.

Sources of Springtime Tropospheric Ozone Over North China: A Modeling Analysis of Ozonesonde and Satellite Observations

NASA Astrophysics Data System (ADS)

Liu, H.; Chan, C.; Huang, J.; Zhang, Y.; Choi, H.; Crawford, J. H.; Considine, D. B.; Zheng, X.; Oltmans, S. J.; Liu, S. C.; Zhang, L.; Liu, X.; Thouret, V.

2012-12-01

Tropospheric ozone concentrations and emissions of NOx have both increased significantly over China as a result of rapid industrialization during the past decade. These trends degrade local and regional air quality and have important effects on background tropospheric ozone and surface ozone over downwind North Pacific and North America. In-situ observations of tropospheric ozone over China are therefore essential to testing and improving our understanding of the impact of Asian anthropogenic (versus natural) emissions and various chemical, physical, and dynamical processes on both regional and global tropospheric ozone. Despite their critical importance, in-situ observations of tropospheric ozone profiles over China have been few and far between in most of the country. To investigate the ensemble of processes that control the distribution, variability, and sources of springtime tropospheric ozone over China and its surrounding regions, an intensive ozonesonde sounding campaign, called Transport of Air Pollutants and Tropospheric Ozone over China (TAPTO-China), was conducted at nine locations across China in the springs of 2004 (South China) and 2005 (North China). In this paper, we use a global 3-D model of tropospheric chemistry (GEOS-Chem) to examine the characteristics of distribution and variability and quantify various sources of tropospheric ozone over North China by analysis of intensive ozonesonde data obtained at four stations in North / Northwest China during the second phase of TAPTO-China (April-May 2005). These four stations include Xining (36.43N, 101.45E), Beijing (39.80N, 116.18E), Longfengshan (44.44N, 127.36E), and Aletai (47.73N, 88.08E). We drive GEOS-Chem with two sets of assimilated meteorological observations (GEOS-4 and GEOS-5) from the Goddard Earth Observing System (GEOS) of the NASA Global Modeling and Assimilation Office (GAMO), allowing us to examine the impacts of variability in meteorology. We show that the observed tropospheric

High Temporal Resolution Tropospheric Wind Profile Observations at NASA Kennedy Space Center During Hurricane Irma

NASA Technical Reports Server (NTRS)

Decker, Ryan; Barbre, Robert; Huddleston, Lisa; Wilfong, Tim; Brauer, Tom

2018-01-01

The NASA Kennedy Space Center (KSC) operates a 48-MHz Tropospheric/Stratospheric Doppler Radar Wind Profiler (TDRWP) on a continual basis generating wind profiles between 2-19 km in the support of space launch vehicle operations. A benefit of the continual operability of the system is the ability to provide unique observations of severe weather events such as hurricanes. On the evening of 10 September 2017, Hurricane Irma passed within 100 miles to the west of KSC through the middle of the Florida peninsula. The hurricane was responsible for power outages to approximately 2/3 of Florida's population. This paper will describe the characteristics of the tropospheric wind observations from the TDRWP during Irma, provide a comparison to previous TDRWP observations from Hurricane Matthew in 2016, and discuss lessons learned regarding dissemination of TDRWP data during the event.

How Dry is the Tropical Free Troposphere? Implications for Global Warming Theory

NASA Technical Reports Server (NTRS)

Spencer, Roy W.; Braswell, William D.

1997-01-01

The humidity of the free troposphere is being increasingly scrutinized in climate research due to its central role in global warming theory through positive water vapor feedback. This feedback is the primary source of global warming in general circulation models (GCMs). Because the loss of infrared energy to space increases nonlinearly with decreases in relative humidity, the vast dry zones in the Tropics are of particular interest. These dry zones are nearly devoid of radiosonde stations, and most of those stations have, until recently, ignored the low humidity information from the sondes. This results in substantial uncertainty in GCM tuning and validation based on sonde data. While satellite infrared radiometers are now beginning to reveal some information about the aridity of the tropical free troposphere, the authors show that the latest microwave humidity sounder data suggests even drier conditions than have been previously reported. This underscores the importance of understanding how these low humidity levels are controlled in order to tune and validate GCMs, and to predict the magnitude of water vapor feedback and thus the magnitude of global warming.

A New NASA Data Product: Tropospheric and Stratospheric Column Ozone in the Tropics Derived from TOMS Measurements

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Chandra, S.; Bhartia, P. K.

1999-01-01

Tropospheric column ozone (TCO) and stratospheric column ozone (SCO) gridded data in the tropics for 1979-present are now available from NASA Goddard Space Flight Center via either direct ftp, world-NN,ide-NN,eb, or electronic mail. This note provides a brief overview of the method used to derive the data set including validation and adjustments.

Global Free Tropospheric NO2 Abundances Derived Using a Cloud Slicing Technique Applied to Satellite Observations from the Aura Ozone Monitoring Instrument (OMI)

NASA Technical Reports Server (NTRS)

Choi, S.; Joiner, J.; Choi, Y.; Duncan, B. N.; Bucsela, E.

2014-01-01

We derive free-tropospheric NO2 volume mixing ratios (VMRs) and stratospheric column amounts of NO2 by applying a cloud slicing technique to data from the Ozone Monitoring Instrument (OMI) on the Aura satellite. In the cloud-slicing approach, the slope of the above-cloud NO2 column versus the cloud scene pressure is proportional to the NO2 VMR. In this work, we use a sample of nearby OMI pixel data from a single orbit for the linear fit. The OMI data include cloud scene pressures from the rotational-Raman algorithm and above-cloud NO2 vertical column density (VCD) (defined as the NO2 column from the cloud scene pressure to the top-of-the-atmosphere) from a differential optical absorption spectroscopy (DOAS) algorithm. Estimates of stratospheric column NO2 are obtained by extrapolating the linear fits to the tropopause. We compare OMI-derived NO2 VMRs with in situ aircraft profiles measured during the NASA Intercontinental Chemical Transport Experiment Phase B (INTEX-B) campaign in 2006. The agreement is generally within the estimated uncertainties when appropriate data screening is applied. We then derive a global seasonal climatology of free-tropospheric NO2 VMR in cloudy conditions. Enhanced NO2 in the free troposphere commonly appears near polluted urban locations where NO2 produced in the boundary layer may be transported vertically out of the boundary layer and then horizontally away from the source. Signatures of lightning NO2 are also shown throughout low and middle latitude regions in summer months. A profile analysis of our cloud slicing data indicates signatures of uplifted and transported anthropogenic NO2 in the middle troposphere as well as lightning-generated NO2 in the upper troposphere. Comparison of the climatology with simulations from the Global Modeling Initiative (GMI) for cloudy conditions (cloud optical thicknesses > 10) shows similarities in the spatial patterns of continental pollution outflow. However, there are also some differences in

Using Satellite Observations of Cloud Vertical Distribution to Improve Global Model Estimates of Cloud Radiative Effect on Key Tropospheric Oxidants

NASA Technical Reports Server (NTRS)

Liu, Hongyu; Crawford, James; Ham, Seung-Hee; Zhang, Bo; Kato, Seiji; Voulgarakis, Apostolos; Chen, Gao; Fairlie, Duncan; Duncan, Bryan; Yantosca, Robert

2017-01-01

Clouds directly affect tropospheric photochemistry through modification of solar radiation that determines photolysis frequencies. This effect is an important component of global tropospheric chemistry-climate interaction, and its understanding is thus essential for predicting the feedback of climate change on tropospheric chemistry.

Present-day distribution and trends of global tropospheric ozone from satellite observations: Results from the Tropospheric Ozone Assessment Report (TOAR)

NASA Astrophysics Data System (ADS)

Gaudel, A.; Cooper, O. R.; Barret, B.; Boynard, A.; Clerbaux, C.; Pierre-Francois, C.; Huang, G.; Hurtmans, D.; Kerridge, B. J.; Latter, B.; Le Flochmoen, E.; Liu, X.; Neu, J. L.; Siddans, R.; Wespes, C.; Worden, H. M.; Ziemke, J. R.

2017-12-01

Tropospheric ozone is a greenhouse gas and pollutant detrimental to human health and crop and ecosystem productivity. Since 1990 a large portion of the anthropogenic emissions that react in the atmosphere to produce ozone have shifted from North America and Europe to Asia. This rapid shift, coupled with limited ozone monitoring in developing nations, has left scientists unable to answer the most basic questions: Is ozone continuing to decline in nations with strong emission controls? To what extent is ozone increasing in the developing world? IGAC's Tropospheric Ozone Assessment Report (TOAR) has been designed to answer these questions and this presentation will show the results from the TOAR-Climate initiative, focusing on the present-day distribution and trends of global tropospheric ozone from satellite observations. Five satellite products based on OMI (2 products using two different retrieval methods) and IASI (also 2 products using two different retrieval methods) and the OMI/MLS combined product were intercompared. An important result is the close agreement among the five products regarding the quantification of the total mass of all tropospheric ozone, the so called tropospheric ozone burden (TOB). The mean estimate for TOB between 60° N and 60° S is 296 Tg, with all products agreeing within ± 4%. However, on a regional basis the five satellite products have notable differences and there is no agreement in terms of ozone trends over the past decade. Continuing work is exploring the causes of these differences.

Global observations of tropospheric BrO columns using GOME-2 satellite data

NASA Astrophysics Data System (ADS)

Theys, N.; van Roozendael, M.; Hendrick, F.; Yang, X.; de Smedt, I.; Richter, A.; Begoin, M.; Errera, Q.; Johnston, P. V.; Kreher, K.; de Mazière, M.

2011-02-01

Measurements from the GOME-2 satellite instrument have been analyzed for tropospheric BrO using a residual technique that combines measured BrO columns and estimates of the stratospheric BrO content from a climatological approach driven by O3 and NO2 observations. Comparisons between the GOME-2 results and BrO vertical columns derived from correlative ground-based and SCIAMACHY nadir observations, present a good level of consistency. We show that the adopted technique enables separation of stratospheric and tropospheric fractions of the measured total BrO columns and allows quantitative study of the BrO plumes in polar regions. While some satellite observed plumes of enhanced BrO can be explained by stratospheric descending air, we show that most BrO hotspots are of tropospheric origin, although they are often associated to regions with low tropopause heights as well. Elaborating on simulations using the p-TOMCAT tropospheric chemical transport model, this result is found to be consistent with the mechanism of bromine release through sea salt aerosols production during blowing snow events. No definitive conclusion can be drawn however on the importance of blowing snow sources in comparison to other bromine release mechanisms. Outside polar regions, evidence is provided for a global tropospheric BrO background with column of 1-3 × 1013 molec cm-2, consistent with previous estimates.

Tropospheric energy cascades in a global circulation model

NASA Astrophysics Data System (ADS)

Brune, Sebastian; Becker, Erich

2010-05-01

The global horizontal kinetic energy (KE) spectrum and its budget are analyzed using results from a mechanistic GCM. The model has a standard spectral dynamical core with very high vertikal resolution up to the middle stratosphere (T330/L100). As a turbulence model we combine the Smagorinsky scheme with an energy conserving hyperdiffusion that is applied for the very smallest resolved scales. The simulation confirms a slope of the KE spectrum close to -3 in the synoptic regime where the KE is dominated by vortical modes. Towards the mesoscales the spectrum flattens and assumes a slope close to -5/3. Here divergent modes become increasingly important and even dominate the KE. Our complete analysis of the sinks and sources in the spectral KE budget reveals the overall energy fluxes through the spectrum. For the upper troposphere, the change of KE due to horizontal advection is negative for large synoptic scales. It is positive for the planetary scale, as expected, and for the mesoscales as well. This implies that the mesoscales, which include the dynamical sources of tropospheric gravity waves, are in fact sustained by the energy injection at the baroclinic scale (forward energy cascade). We find an enstrophy cascade in accordance with 2D turbulence, but zero downscaling of energy due to the vortical modes alone. In other words, the forward energy cascade in the synoptic and mesoscale regime is solely due to the divergent modes and their nonlinear interaction with the vortical modes. This picture, derived form a mechanistic model, not only lends further evidence for a generally forward energy cascade in the upper tropospheric away from the baroclinic scale. It also extends the picture proposed earlier by Tung and Orlando: The transition from a -3 to a -5/3 slope in the tropospheric macroturbulence spectrum reflects the fact, that the energy cascade due to the horizontally divergent (3D) modes is hidden behind the (2D) enstrophy cascade in the synoptic regime but

Global tropospheric ozone modeling: Quantifying errors due to grid resolution

NASA Astrophysics Data System (ADS)

Wild, Oliver; Prather, Michael J.

2006-06-01

Ozone production in global chemical models is dependent on model resolution because ozone chemistry is inherently nonlinear, the timescales for chemical production are short, and precursors are artificially distributed over the spatial scale of the model grid. In this study we examine the sensitivity of ozone, its precursors, and its production to resolution by running a global chemical transport model at four different resolutions between T21 (5.6° × 5.6°) and T106 (1.1° × 1.1°) and by quantifying the errors in regional and global budgets. The sensitivity to vertical mixing through the parameterization of boundary layer turbulence is also examined. We find less ozone production in the boundary layer at higher resolution, consistent with slower chemical production in polluted emission regions and greater export of precursors. Agreement with ozonesonde and aircraft measurements made during the NASA TRACE-P campaign over the western Pacific in spring 2001 is consistently better at higher resolution. We demonstrate that the numerical errors in transport processes on a given resolution converge geometrically for a tracer at successively higher resolutions. The convergence in ozone production on progressing from T21 to T42, T63, and T106 resolution is likewise monotonic but indicates that there are still large errors at 120 km scales, suggesting that T106 resolution is too coarse to resolve regional ozone production. Diagnosing the ozone production and precursor transport that follow a short pulse of emissions over east Asia in springtime allows us to quantify the impacts of resolution on both regional and global ozone. Production close to continental emission regions is overestimated by 27% at T21 resolution, by 13% at T42 resolution, and by 5% at T106 resolution. However, subsequent ozone production in the free troposphere is not greatly affected. We find that the export of short-lived precursors such as NOx by convection is overestimated at coarse resolution.

Global high-resolution simulations of tropospheric nitrogen dioxide using CHASER V4.0

NASA Astrophysics Data System (ADS)

Sekiya, Takashi; Miyazaki, Kazuyuki; Ogochi, Koji; Sudo, Kengo; Takigawa, Masayuki

2018-03-01

We evaluate global tropospheric nitrogen dioxide (NO2) simulations using the CHASER V4.0 global chemical transport model (CTM) at horizontal resolutions of 0.56, 1.1, and 2.8°. Model evaluation was conducted using satellite tropospheric NO2 retrievals from the Ozone Monitoring Instrument (OMI) and the Global Ozone Monitoring Experiment-2 (GOME-2) and aircraft observations from the 2014 Front Range Air Pollution and Photochemistry Experiment (FRAPPÉ). Agreement against satellite retrievals improved greatly at 1.1 and 0.56° resolutions (compared to 2.8° resolution) over polluted and biomass burning regions. The 1.1° simulation generally captured the regional distribution of the tropospheric NO2 column well, whereas 0.56° resolution was necessary to improve the model performance over areas with strong local sources, with mean bias reductions of 67 % over Beijing and 73 % over San Francisco in summer. Validation using aircraft observations indicated that high-resolution simulations reduced negative NO2 biases below 700 hPa over the Denver metropolitan area. These improvements in high-resolution simulations were attributable to (1) closer spatial representativeness between simulations and observations and (2) better representation of large-scale concentration fields (i.e., at 2.8°) through the consideration of small-scale processes. Model evaluations conducted at 0.5 and 2.8° bin grids indicated that the contributions of both these processes were comparable over most polluted regions, whereas the latter effect (2) made a larger contribution over eastern China and biomass burning areas. The evaluations presented in this paper demonstrate the potential of using a high-resolution global CTM for studying megacity-scale air pollutants across the entire globe, potentially also contributing to global satellite retrievals and chemical data assimilation.

Evaluation of Near-Tropopause Ozone Distributions in the Global Modeling Initiative Combined Stratosphere/Troposphere Model with Ozonesonde Data

NASA Technical Reports Server (NTRS)

Considine, David B.; Logan, Jennifer A.; Olsen, Mark A.

2008-01-01

The NASA Global Modeling Initiative has developed a combined stratosphere/troposphere chemistry and transport model which fully represents the processes governing atmospheric composition near the tropopause. We evaluate model ozone distributions near the tropopause, using two high vertical resolution monthly mean ozone profile climatologies constructed with ozonesonde data, one by averaging on pressure levels and the other relative to the thermal tropopause. Model ozone is high biased at the SH tropical and NH midlatitude tropopause by approx. 45% in a 4 deg. latitude x 5 deg. longitude model simulation. Increasing the resolution to 2 deg. x 2.5 deg. increases the NH tropopause high bias to approx. 60%, but decreases the tropical tropopause bias to approx. 30%, an effect of a better-resolved residual circulation. The tropopause ozone biases appear not to be due to an overly vigorous residual circulation or excessive stratosphere/troposphere exchange, but are more likely due to insufficient vertical resolution or excessive vertical diffusion near the tropopause. In the upper troposphere and lower stratosphere, model/measurement intercomparisons are strongly affected by the averaging technique. NH and tropical mean model lower stratospheric biases are less than 20%. In the upper troposphere, the 2 deg. x 2.5 deg. simulation exhibits mean high biases of approx. 20% and approx. 35% during April in the tropics and NH midlatitudes, respectively, compared to the pressure averaged climatology. However, relative-to-tropopause averaging produces upper troposphere high biases of approx. 30% and 70% in the tropics and NH midlatitudes. This is because relative-to-tropopause averaging better preserves large cross-tropopause O3 gradients, which are seen in the daily sonde data, but not in daily model profiles. The relative annual cycle of ozone near the tropopause is reproduced very well in the model Northern Hemisphere midlatitudes. In the tropics, the model amplitude of the

Global observations of BrO in the troposphere using GOME-2 satellite data

NASA Astrophysics Data System (ADS)

Theys, N.; van Roozendael, M.; Hendrick, F.; Xin, Y.; Isabelle, D.; Richter, A.; Mathias, B.; Quentin, E.; Johnston, P. V.; Kreher, K.; Martine, D.

2010-12-01

Measurements from the GOME-2 satellite instrument have been analyzed for tropospheric BrO using a residual technique that combines measured BrO columns and estimates of the stratospheric BrO content from a climatological approach driven by O3 and NO2 observations. Comparisons between the GOME-2 results and correlative data including ground-based BrO vertical columns and total BrO columns derived from SCIAMACHY nadir observations, present a good level of consistency. We show that the adopted technique enables to separate the stratospheric and tropospheric fractions of the measured total BrO columns and allows studying the BrO plumes in polar region in more detail. While several satellite BrO plumes can largely be explained by an influence of stratospheric descending air, we show that numerous tropospheric BrO hotspots are associated to regions with low tropopause heights as well. Elaborating on simulations using the p-TOMCAT tropospheric chemical transport model, this finding is found to be consistent with the mechanism of bromine release through sea salt aerosols production during blowing snow events. Outside the polar region, evidences are provided for a global tropospheric BrO background with columns of 1-3 x 1013 molec/cm2.

High Temporal Resolution Tropospheric Wind Profile Observations at NASA Kennedy Space Center During Hurricane Irma

NASA Technical Reports Server (NTRS)

Decker, Ryan K.; Barbre, Robert E., Jr.; Huddleston, Lisa; Brauer, Thomas; Wilfong, Timothy

2018-01-01

The NASA Kennedy Space Center (KSC) operates a 48-MHz Tropospheric/Stratospheric Doppler Radar Wind Profiler (TDRWP) on a continual basis generating wind profiles between 2-19 km in the support of space launch vehicle operations. A benefit of the continual operability of the system is the ability to provide unique observations of severe weather events such as hurricanes. Over the past two Atlantic Hurricane seasons the TDRWP has made high temporal resolution wind profile observations of Hurricane Irma in 2017 and Hurricane Matthew in 2016. Hurricane Irma was responsible for power outages to approximately 2/3 of Florida's population during its movement over the state(Stein,2017). An overview of the TDRWP system configuration, brief summary of Hurricanes Irma and Matthew storm track in proximity to KSC, characteristics of the tropospheric wind observations from the TDRWP during both events, and discussion of the dissemination of TDRWP data during the event will be presented.

NASA Tropospheric Composition Program field campagins as prototypes to advance the Integrated Observing System for Air Quality

NASA Astrophysics Data System (ADS)

Lefer, B. L.; Crawford, J. H.; Pierce, R. B.; Berkoff, T.; Swap, R.; Janz, S. J.; Ahn, J.; Al-Saadi, J. A.

2017-12-01

With the launch over the virtual constellation of earth observing satellites for atmospheric composition (e.g., TROPOMI, GEMS, TEMPO, and Sentinel-4) over the next several years, we have a unique opportunity to develop an Integrated Observing System (IOS) for air quality in the northern hemisphere. Recently, NASA's Tropospheric Composition Program (TCP) has participated in several different air quality related field campaigns as an effort to explore various prototypes of the IOS for Air Quality. The IOS for air quality could be a system were space-based observations of air quality (generally, column abundances of NO2, HCHO, O3, SO2, and AOD) are given added "value" by being integrated with: a) long-term ground-based observations;b) regional and global air quality and chemical transport models; as well as c) measurements from targeted airborne field campaigns. The recent Korea-US Air Quality Study (KORUS-AQ), the Lake Michigan Ozone Study 2017 (LMOS), and the Ozone Water-Land Environmental Transition Study (OWLETS) field campaigns were held in different locations and made measurements over different scale. However, all of these provide an opportunity to learn about how a future integrated air quality observing system can be implemented to serve a variety of air quality related objectives. NASA TCP is also exploring enchancements to our routine observations to strengthen the IOS for air quality in the future.

Report of the NASA working group on tropospheric program planning

NASA Technical Reports Server (NTRS)

Seinfeld, J. H.; Allario, F.; Bandeen, W. R.; Chameides, W. L.; Davis, D. D.; Hinkley, E. D.; Stewart, R. W.

1981-01-01

Increased understanding of the chemical phenomena occurring in the troposphere was the research goal. Emphasis was placed on tropospheric impact on environmental quality, including public health, agriculture, climate, and weather.

Tropospheric Ozone Lidar Network (TOLNet) - Long-term Tropospheric Ozone and Aerosol Profiling for Satellite Continuity and Process Studies

NASA Astrophysics Data System (ADS)

Newchurch, M.; Al-Saadi, J. A.; Alvarez, R. J.; Burris, J.; Cantrell, W.; Chen, G.; De Young, R.; Hardesty, R.; Hoff, R. M.; Kaye, J. A.; kuang, S.; Langford, A. O.; LeBlanc, T.; McDermid, I. S.; McGee, T. J.; Pierce, R.; Senff, C. J.; Sullivan, J. T.; Szykman, J.; Tonnesen, G.; Wang, L.

2012-12-01

An interagency research initiative for ground-based ozone and aerosol lidar profiling recently funded by NASA has important applications to air-quality studies in addition to the goal of serving the GEO-CAPE and other air-quality missions. Ozone is a key trace-gas species, a greenhouse gas, and an important pollutant in the troposphere. High spatial and temporal variability of ozone affected by various physical and photochemical processes motivates the high spatio-temporal lidar profiling of tropospheric ozone for improving the simulation and forecasting capability of the photochemical/air-quality models, especially in the boundary layer where the resolution and precision of satellite retrievals are fundamentally limited. It is well known that there are large discrepancies between the surface and upper-air ozone due to titration, surface deposition, diurnal processes, free-tropospheric transport, and other processes. Near-ground ozone profiling has been technically challenging for lidars due to some engineering difficulties, such as near-range saturation, field-of-view overlap, and signal processing issues. This initiative provides an opportunity for us to solve those engineering issues and redesign the lidars aimed at long-term, routine ozone/aerosol observations from the near surface to the top of the troposphere at multiple stations (i.e., NASA/GSFC, NASA/LaRC, NASA/JPL, NOAA/ESRL, UAHuntsville) for addressing the needs of NASA, NOAA, EPA and State/local AQ agencies. We will present the details of the science investigations, current status of the instrumentation development, data access/protocol, and the future goals of this lidar network. Ozone lidar/RAQMS comparison of laminar structures.

Ozone Production in Global Tropospheric Models: Quantifying Errors due to Grid Resolution

NASA Astrophysics Data System (ADS)

Wild, O.; Prather, M. J.

2005-12-01

Ozone production in global chemical models is dependent on model resolution because ozone chemistry is inherently nonlinear, the timescales for chemical production are short, and precursors are artificially distributed over the spatial scale of the model grid. In this study we examine the sensitivity of ozone, its precursors, and its production to resolution by running a global chemical transport model at four different resolutions between T21 (5.6° × 5.6°) and T106 (1.1° × 1.1°) and by quantifying the errors in regional and global budgets. The sensitivity to vertical mixing through the parameterization of boundary layer turbulence is also examined. We find less ozone production in the boundary layer at higher resolution, consistent with slower chemical production in polluted emission regions and greater export of precursors. Agreement with ozonesonde and aircraft measurements made during the NASA TRACE-P campaign over the Western Pacific in spring 2001 is consistently better at higher resolution. We demonstrate that the numerical errors in transport processes at a given resolution converge geometrically for a tracer at successively higher resolutions. The convergence in ozone production on progressing from T21 to T42, T63 and T106 resolution is likewise monotonic but still indicates large errors at 120~km scales, suggesting that T106 resolution is still too coarse to resolve regional ozone production. Diagnosing the ozone production and precursor transport that follow a short pulse of emissions over East Asia in springtime allows us to quantify the impacts of resolution on both regional and global ozone. Production close to continental emission regions is overestimated by 27% at T21 resolution, by 13% at T42 resolution, and by 5% at T106 resolution, but subsequent ozone production in the free troposphere is less significantly affected.

Global budget of tropospheric ozone: Evaluating recent model advances with satellite (OMI), aircraft (IAGOS), and ozonesonde observations

NASA Astrophysics Data System (ADS)

Hu, Lu; Jacob, Daniel J.; Liu, Xiong; Zhang, Yi; Zhang, Lin; Kim, Patrick S.; Sulprizio, Melissa P.; Yantosca, Robert M.

2017-10-01

The global budget of tropospheric ozone is governed by a complicated ensemble of coupled chemical and dynamical processes. Simulation of tropospheric ozone has been a major focus of the GEOS-Chem chemical transport model (CTM) over the past 20 years, and many developments over the years have affected the model representation of the ozone budget. Here we conduct a comprehensive evaluation of the standard version of GEOS-Chem (v10-01) with ozone observations from ozonesondes, the OMI satellite instrument, and MOZAIC-IAGOS commercial aircraft for 2012-2013. Global validation of the OMI 700-400 hPa data with ozonesondes shows that OMI maintained persistent high quality and no significant drift over the 2006-2013 period. GEOS-Chem shows no significant seasonal or latitudinal bias relative to OMI and strong correlations in all seasons on the 2° × 2.5° horizontal scale (r = 0.88-0.95), improving on previous model versions. The most pronounced model bias revealed by ozonesondes and MOZAIC-IAGOS is at high northern latitudes in winter-spring where the model is 10-20 ppbv too low. This appears to be due to insufficient stratosphere-troposphere exchange (STE). Model updates to lightning NOx, Asian anthropogenic emissions, bromine chemistry, isoprene chemistry, and meteorological fields over the past decade have overall led to gradual increase in the simulated global tropospheric ozone burden and more active ozone production and loss. From simulations with different versions of GEOS meteorological fields we find that tropospheric ozone in GEOS-Chem v10-01 has a global production rate of 4960-5530 Tg a-1, lifetime of 20.9-24.2 days, burden of 345-357 Tg, and STE of 325-492 Tg a-1. Change in the intensity of tropical deep convection between these different meteorological fields is a major factor driving differences in the ozone budget.

Changes in Global Tropospheric OH Expected as a Result of Climate Change Over the Last Several Decades

NASA Technical Reports Server (NTRS)

Nicely, Julie M.; Salawitch, Ross J.; Canty, Timothy P.; Douglass, Anne R.; Duncan, Bryan N.; Lang, C.; Liang, Qing; Oman, Luke D.; Rodriguez, Jose M.; Stolarksi, Richard;

Nitrogen oxides in the troposphere - Global and regional budgets

NASA Technical Reports Server (NTRS)

Logan, J. A.

1983-01-01

The cycle of nitrogen oxides in the troposphere is discussed from both global and regional perspectives. Global sources for NO(x) are estimated to be of magnitude 50 (+ or - 25) x 10 to the 12th gm N/yr. Nitrogen oxides are derived from combustion of fossil fuels (40 percent) and biomass burning (25 percent) with the balance from lightning and microbial activity in soils. Estimates for the rate of removal of NOx based on recent atmospheric and precipitation chemistry data are consistent with global source strengths derived here. Industrial and agricultural activities provide approximately two thirds of the global source for NOx. In North America, sources from combustion of fossil fuels exceed natural sources by a factor of 3-13. Wet deposition removes about one third of the combustion source of NOx over North America, while dry deposition removes a similar amount. The balance is exported from the continent. Deposition of nitrate in precipitation over eastern Canada and the western Atlantic is clearly influenced by sources of NOx in the eastern United States.

The global chemistry transport model TM5: description and evaluation of the tropospheric chemistry version 3.0

NASA Astrophysics Data System (ADS)

Huijnen, V.; Williams, J.; van Weele, M.; van Noije, T.; Krol, M.; Dentener, F.; Segers, A.; Houweling, S.; Peters, W.; de Laat, J.; Boersma, F.; Bergamaschi, P.; van Velthoven, P.; Le Sager, P.; Eskes, H.; Alkemade, F.; Scheele, R.; Nédélec, P.; Pätz, H.-W.

2010-10-01

We present a comprehensive description and benchmark evaluation of the tropospheric chemistry version of the global chemistry transport model TM5 (Tracer Model 5, version TM5-chem-v3.0). A full description is given concerning the photochemical mechanism, the interaction with aerosol, the treatment of the stratosphere, the wet and dry deposition parameterizations, and the applied emissions. We evaluate the model against a suite of ground-based, satellite, and aircraft measurements of components critical for understanding global photochemistry for the year 2006. The model exhibits a realistic oxidative capacity at a global scale. The methane lifetime is ~8.9 years with an associated lifetime of methyl chloroform of 5.86 years, which is similar to that derived using an optimized hydroxyl radical field. The seasonal cycle in observed carbon monoxide (CO) is well simulated at different regions across the globe. In the Northern Hemisphere CO concentrations are underestimated by about 20 ppbv in spring and 10 ppbv in summer, which is related to missing chemistry and underestimated emissions from higher hydrocarbons, as well as to uncertainties in the seasonal variation of CO emissions. The model also captures the spatial and seasonal variation in formaldehyde tropospheric columns as observed by SCIAMACHY. Positive model biases over the Amazon and eastern United States point to uncertainties in the isoprene emissions as well as its chemical breakdown. Simulated tropospheric nitrogen dioxide columns correspond well to observations from the Ozone Monitoring Instrument in terms of its seasonal and spatial variability (with a global spatial correlation coefficient of 0.89), but TM5 fields are lower by 25-40%. This is consistent with earlier studies pointing to a high bias of 0-30% in the OMI retrievals, but uncertainties in the emission inventories have probably also contributed to the discrepancy. TM5 tropospheric nitrogen dioxide profiles are in good agreement (within ~0

The global chemistry transport model TM5: description and evaluation of the tropospheric chemistry version 3.0

NASA Astrophysics Data System (ADS)

Huijnen, V.; Williams, J. E.; van Weele, M.; van Noije, T. P. C.; Krol, M. C.; Dentener, F.; Segers, A.; Houweling, S.; Peters, W.; de Laat, A. T. J.; Boersma, K. F.; Bergamaschi, P.; van Velthoven, P. F. J.; Le Sager, P.; Eskes, H. J.; Alkemade, F.; Scheele, M. P.; Nédélec, P.; Pätz, H.-W.

2010-07-01

We present a comprehensive description and benchmark evaluation of the tropospheric chemistry version of the global chemistry transport model TM5 (Tracer Model 5, version TM5-chem-v3.0). A full description is given concerning the photochemical mechanism, the interaction with aerosol, the treatment of the stratosphere, the wet and dry deposition parameterizations, and the applied emissions. We evaluate the model against a suite of ground-based, satellite, and aircraft measurements of components critical for understanding global photochemistry for the year 2006. The model exhibits a realistic oxidative capacity at a global scale. The methane lifetime is ~8.9 years with an associated lifetime of methyl chloroform of 5.86 years, which is similar to that derived using an optimized hydroxyl radical field. The seasonal cycle in observed carbon monoxide (CO) is well simulated at different regions across the globe. In the Northern Hemisphere CO concentrations are underestimated by about 20 ppbv in spring and 10 ppbv in summer, which is related to missing chemistry and underestimated emissions from higher hydrocarbons, as well as to uncertainties in the seasonal variation of CO emissions. The model also captures the spatial and seasonal variation in formaldehyde tropospheric columns as observed by SCIAMACHY. Positive model biases over the Amazon and eastern United States point to uncertainties in the isoprene emissions as well as its chemical breakdown. Simulated tropospheric nitrogen dioxide columns correspond well to observations from the Ozone Monitoring Instrument in terms of its seasonal and spatial variability (with a global spatial correlation coefficient of 0.89), but TM5 fields are lower by 25-40%. This is consistent with earlier studies pointing to a high bias of 0-30% in the OMI retrievals, but uncertainties in the emission inventories have probably also contributed to the discrepancy. TM5 tropospheric nitrogen dioxide profiles are in good agreement (within ~0

Comparison of tropospheric ozone profiles measured by lidars simultaneously over land and water during the 2017 NASA OWLETS campaign

NASA Astrophysics Data System (ADS)

Gronoff, G.; Sullivan, J.; Berkoff, T.; Carrion, W.; Farris, B.

2017-12-01

The NASA Langley Mobile Ozone Lidar (LMOL) and NASA Goddard's lidar (TROPOZ) have routinely measured tropospheric ozone profiles in support of various NASA campaigns and local field studies since 2013 (e.g. DISCOVER-AQ 2014). They are both charter members of the NASA Tropospheric Lidar Network (TOLNet) and were constructed within transportable containers, allowing for observations directly within a variety of complex environments. To gain a better understanding of ozone's interactions close to the surface, both of these instruments have recently designed and optimized near field optical elements for ozone detection. One of the major difficulties for the modeling and satellite communities are the sharp transition regions, both horizontal and vertical, such as the land-water gradients in O3 near coastal/urban regions that are driven by differences in surface deposition, boundary layer height, and cloud coverage.To better understand these gradients, both lidars were deployed in the Hampton Roads / Tidewater region, in Virginia, in July-August 2017, in the context of the OWLETS (Ozone Water Land Environment Transition Study) campaign. The TROPOZ lidar was deployed above land at NASA LaRC, while the LMOL lidar was deployed on the Chesapeake Bay Bridge Tunnel third island, being de-facto an over-water lidar. The distance between the two lidars was approximately 30 km. Strong differences between the two lidars measurements were observed. Some influence of the ship traffic can be seen over water, but does not affect the observations above 300m. Overall, some important discrepancies between the modeling and the lidar observations over water were found. These results shows the importance of making more measurements over water to better constrain pollution models.

The Origins of Air Parcels Uplifted in a Two Dimensional Gravity Wave in the Tropical Upper Troposphere During the NASA Stratosphere Troposphere Exchange Project (STEP)

NASA Technical Reports Server (NTRS)

Selkirk, Henry B.; Pfister, Leonhard; Chan, K. Roland; Kritz, Mark; Kelly, Ken

1989-01-01

During January and February 1987, as part of the Stratosphere-Troposphere Exchange Project, the NASA ER-2 made 11 flights from Darwin, Australia to investigate dehydration mechanisms in the vicinity of the tropical tropopause. After the monsoon onset in the second week of January, steady easterly flow of 15-25 ms (exp -1) was established in the upper troposphere and lower stratosphere over northern Australia and adjacent seas. Penetrating into this regime were elements of the monsoon convection such as overshooting convective turrets and extensive anvils including cyclone cloud shields. In cases of the latter, the resulting flow obstructions tended to produce mesoscale gravity waves. In several instances the ER- 2 meteorological and trace constituent measurements provide a detailed description of the structure of these gravity waves. Among these was STEP Flight 6, 22-23 January. It is of particular interest to STEP because of the close proximity of ice-laden and dehydrated air on the same isentropic surfaces. Convective events inject large amounts of ice into the upper troposphere and lower stratosphere which may not be completely removed by local precipitation processes. In the present instance, a gravity wave for removed from the source region appears to induce relativity rapid upward motion in the ice-laden air and subsequent dessication. Potential mechanisms for such a localized removal process are under investigation.

Interpretation of TOMS Observations of Tropical Tropospheric Ozone with a Global Model and In Situ Observations

NASA Technical Reports Server (NTRS)

Martin, Randall V.; Jacob, Daniel J.; Logan, Jennifer A.; Bey, Isabelle; Yantosca, Robert M.; Staudt, Amanda C.; Fiore, Arlene M.; Duncan, Bryan N.; Liu, Hongyu; Ginoux, Paul

2004-01-01

We interpret the distribution of tropical tropospheric ozone columns (TTOCs) from the Total Ozone Mapping Spectrometer (TOMS) by using a global three-dimensional model of tropospheric chemistry (GEOS-CHEM) and additional information from in situ observations. The GEOS-CHEM TTOCs capture 44% of the variance of monthly mean TOMS TTOCs from the convective cloud differential method (CCD) with no global bias. Major discrepancies are found over northern Africa and south Asia where the TOMS TTOCs do not capture the seasonal enhancements from biomass burning found in the model and in aircraft observations. A characteristic feature of these northern topical enhancements, in contrast to southern tropical enhancements, is that they are driven by the lower troposphere where the sensitivity of TOMS is poor due to Rayleigh scattering. We develop an efficiency correction to the TOMS retrieval algorithm that accounts for the variability of ozone in the lower troposphere. This efficiency correction increases TTOC's over biomass burning regions by 3-5 Dobson units (DU) and decreases them by 2-5 DU over oceanic regions, improving the agreement between CCD TTOCs and in situ observations. Applying the correction to CCD TTOCs reduces by approximately DU the magnitude of the "tropical Atlantic paradox" [Thompson et al, 2000], i.e. the presence of a TTOC enhancement over the southern tropical Atlantic during the northern African biomass burning season in December-February. We reproduce the remainder of the paradox in the model and explain it by the combination of upper tropospheric ozone production from lightning NOx, peristent subsidence over the southern tropical Atlantic as part of the Walker circulation, and cross-equatorial transport of upper tropospheric ozone from northern midlatitudes in the African "westerly duct." These processes in the model can also account for the observed 13-17 DU persistent wave-1 pattern in TTOCs with a maximum above the tropical Atlantic and a minimum

NASA Global Hawk: Project Overview and Future Plans

NASA Technical Reports Server (NTRS)

Naftel, J. Chris

2011-01-01

The National Aeronautics and Space Administration (NASA) Global Hawk Project became operational in 2009 and began support of Earth science in 2010. Thus far, the NASA Global Hawk has completed three Earth science campaigns and preparations are under way for two extensive multi-year campaigns. One of the most desired performance capabilities of the Global Hawk aircraft is very long endurance: the Global Hawk aircraft can remain airborne longer than almost all other jet-powered aircraft currently flying, and longer than all other aircraft available for airborne science use. This paper describes the NASA Global Hawk system, payload accommodations, concept of operations, and the scientific data-gathering campaigns.

Global measurements of gaseous and aerosol trace species in the upper troposphere and lower stratosphere from daily flights of 747 airliners

NASA Technical Reports Server (NTRS)

Perkins, P. J.

1976-01-01

A description is given of the NASA Global Atmospheric Sampling Program (GASP), taking into account the onboard system which collects atmospheric data automatically, the extensive atmospheric measurement capability, and the data handling and distribution procedure. GASP was implemented to assess the environmental impact of aircraft exhaust emissions in the upper troposphere and lower stratosphere. Global air quality data are to be obtained for a period of five to ten years. Measurements of pollutants not related to aircraft exhaust emissions, such as chlorofluoromethanes, are now included. GASP systems are operating on a United Airlines 747, two Pan Am 747s, and a Qantas Airways of Australia 747. Real-time, in-situ measurements are conducted of ozone, water vapor, carbon monoxide, and oxides of nitrogen. Chlorofluoromethanes are measured by laboratory analysis. Typical GASP data show significant changes in ozone, carbon monoxide, and water vapor related to crossings of the tropopause.

Characterization of Transport Errors in Chemical Forecasts from a Global Tropospheric Chemical Transport Model

NASA Technical Reports Server (NTRS)

Bey, I.; Jacob, D. J.; Liu, H.; Yantosca, R. M.; Sachse, G. W.

2004-01-01

We propose a new methodology to characterize errors in the representation of transport processes in chemical transport models. We constrain the evaluation of a global three-dimensional chemical transport model (GEOS-CHEM) with an extended dataset of carbon monoxide (CO) concentrations obtained during the Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft campaign. The TRACEP mission took place over the western Pacific, a region frequently impacted by continental outflow associated with different synoptic-scale weather systems (such as cold fronts) and deep convection, and thus provides a valuable dataset. for our analysis. Model simulations using both forecast and assimilated meteorology are examined. Background CO concentrations are computed as a function of latitude and altitude and subsequently subtracted from both the observed and the model datasets to focus on the ability of the model to simulate variability on a synoptic scale. Different sampling strategies (i.e., spatial displacement and smoothing) are applied along the flight tracks to search for systematic model biases. Statistical quantities such as correlation coefficient and centered root-mean-square difference are computed between the simulated and the observed fields and are further inter-compared using Taylor diagrams. We find no systematic bias in the model for the TRACE-P region when we consider the entire dataset (i.e., from the surface to 12 km ). This result indicates that the transport error in our model is globally unbiased, which has important implications for using the model to conduct inverse modeling studies. Using the First-Look assimilated meteorology only provides little improvement of the correlation, in comparison with the forecast meteorology. These general statements can be refined when the entire dataset is divided into different vertical domains, i.e., the lower troposphere (less than 2 km), the middle troposphere (2-6 km), and the upper troposphere (greater than

NASA HS3 Global Hawk on the Wing

NASA Image and Video Library

2013-08-30

The NASA Wallops T-34 chase aircraft intercepted Global Hawk 872 on its descent to runway 28 at NASA's Wallops Flight Facility in Wallops Island, Va. This photo of the Global Hawk was taken from the chase plane after finishing its third science flight. For more information about NASA's HS3 mission, visit: www.nasa.gov/HS3 Credit: NASA/ Brea Reeves NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Global tropospheric methane: An indication of atmosphere-biosphere-climate interactions?

NASA Technical Reports Server (NTRS)

Harriss, Robert C.; Sebacher, Daniel I.; Bartlett, Karen B.

1985-01-01

Methane is an important atmospheric gas with potentially critical roles in both photochemical and radiation transfer processes. A major natural source of atmospheric methane involves anaerobic fermentation of organic materials in wetland soils and sediments. A data base of field measurements of atmospheric methane was used in the development of a global methane emissions inventory. Calculations support the following hypotheses: (1) Human activities currently produce methane at a rate approximately equal to natural resources (these rapidly increasing anthropogenic sources can explain most of the recent increase observed in tropospheric methane); and (2) Prior to 200 B.P. (before the present), the influence of climate on wetland extent and distribution was probably a dominant factor controlling global biogenic methane emissions to the atmosphere.

Modeling of Isotope Fractionation in Stratospheric CO2, N2O, CH4, and O3: Investigations of Stratospheric Chemistry and Transport, Stratosphere-Troposphere Exchange, and Their Influence on Global Isotope Budgets

NASA Technical Reports Server (NTRS)

Boering, Kristie A.; Connell, Peter; Rotman, Douglas

2005-01-01

Until recently, the stable isotopic composition of chemically and datively important stratospheric species, such as ozone (O3), carbon dioxide (CO2), nitrous oxide (N2O), and methane (CH4), was largely unexplored, despite indications from the few measurements available and theoretical studies that global-scale isotopic variations will provide a unique tool for quantifying rates of global-scale mass transport into, within, and out of the stratosphere and for understanding the mechanisms of chemical reactions involved in ozone production. The number and geographical extent of observations are beginning to increase rapidly, however, as access to the stratosphere, both directly and by remote-sensing, has increased over the last 10 years and as new analytical techniques have been developed that make global-scale isotope measurements by whole-air sampling more feasible. The objective of this study, begun in April 1999, is to incorporate into the Livermore 2D model the likely photochemical fractionation processes that determine the isotopic compositions of stratospheric CO2, N2O, CH4, and O3, and to use the model results and new observations from NASA field campaigns in 1996 and 1997 to investigate stratospheric chemistry and mass transport. Additionally, since isotopic signatures from the stratosphere are transferred to the troposphere by downward transport at middle and high latitudes, the isotopic compositions may also serve as sensitive tracers of stratosphere-totroposphere transport. Comparisons of model results with stratospheric and upper tropospheric observations from these campaigns, as well as with ground-based observations from new NOAA and NSF-sponsored studies, will help determine whether the magnitudes of the stratospheric fractionation processes are large enough to use as global-scale tracers of transport into the troposphere and, if so, will be used to help constrain the degree of coupling between the troposphere and the stratosphere.

NASA's mission to planet Earth: Earth observing system

NASA Technical Reports Server (NTRS)

1993-01-01

The topics covered include the following: global climate change; radiation, clouds, and atmospheric water; the ocean; the troposphere - greenhouse gases; land cover and the water cycle; polar ice sheets and sea level; the stratosphere - ozone chemistry; volcanoes; the Earth Observing System (EOS) - how NASA will support studies of global climate change?; research and assessment - EOS Science Investigations; EOS Data and Information System (EOSDIS); EOS observations - instruments and spacecraft; a national international effort; and understanding the Earth System.

An Overview of the NASA Spring/Summer 2008 Arctic Campaign - ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites)

NASA Technical Reports Server (NTRS)

Jacob, Daniel J.; Clarke, Antony; Crawford, James H.; Dibbs, Jack; Ferrare, Richard A.; Hostetler, Chris A.; Maring, Hal; Russell, Philip B.; Singh, Hanwant B.

2008-01-01

ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) is a major NASA led airborne field campaign being performed in the spring and summer of 2008 at high latitudes (http://cloud1.arc.nasa.gov/arctas/). ARCTAS is a part of the International Polar Year program and its activities are closely coordinated with multiple U. S. (NOAA, DOE), Canadian, and European partners. Observational data from an ensemble of aircraft, surface, and satellite sensors are closely integrated with models of atmospheric chemistry and transport in this experiment. Principal NASA airborne platforms include a DC-8 for detailed atmospheric composition studies, a P-3 that focuses on aerosols and radiation, and a B-200 that is dedicated to remote sensing of aerosols. Satellite validation is a central activity in all these platforms and is mainly focused on CALIPSO, Aura, and Aqua satellites. Major ARCTAS themes are: (1) Long-range transport of pollution to the Arctic including arctic haze, tropospheric ozone, and persistent pollutants such as mercury; (2) Boreal forest fires and their implications for atmospheric composition and climate; (3) Aerosol radiative forcing from arctic haze, boreal fires, surface-deposited black carbon, and other perturbations; and (4) Chemical processes with focus on ozone, aerosols, mercury, and halogens. The spring deployment (April) is presently underway and is targeting plumes of anthropogenic and biomass burning pollution and dust from Asia and North America, arctic haze, stratosphere-troposphere exchange, and ozone photochemistry involving HOx and halogen radicals. The summer deployment (July) will target boreal forest fires and summertime photochemistry. The ARCTAS mission is providing a critical link to enhance the value of NASA satellite observations for Earth science. In this talk we will discuss the implementation of this campaign and some preliminary results.

How to Interactively Operate the Global Hawk UAS NOAA/NASA ENSO Payload, from Your Armchair, Five Thousand Kilometers Away

NASA Technical Reports Server (NTRS)

Sullivan, Don

2016-01-01

This paper will describe the information technologies developed by NASA and NOAA for the February 2016 Sensing Hazards with Operational Unmanned Technology (SHOUT) El Niño Southern Oscillation (ENSO) Campaign. The air vehicle is a NASA Global Hawk UAS, with a primary payload of four instruments, two developed by NASA, two developed by NOAA. The aircraft is based at the NASA Armstrong Flight Research Center, Edwards Air Force Base, California. The payload components are remotely operated by scientists at various facilities, and the data collected downloaded over satellite links in real time for analysis and collaboration. NOAA: Advanced Vertical Atmospheric Profiling System (AVAPS), developed by NCAR, which deploys dozens of dropsondes at altitudes up to 65,000 ft to collect high vertical resolution measurements of the temperature, pressure, relative humidity, and wind speed and direction. NASA: High-Altitude Imaging Wind and Rain Airborne Profiler (HIWRAP), a radar designed to examine the factors of storm intensity: formation, structure and intensification. NOAA: O3 Photometer (UAS-O3), designed specifically for autonomous, precise, and accurate O3 measurements in the upper troposphere and lower stratosphere (UT/LS). NASA JPL: High Altitude MMIC Sounding Radiometer (HAMSR), an atmospheric microwave temperature and humidity sounder instrument that looks at the microwave spectrum.

NASA Experiment on Tropospheric-Stratospheric Water Vapor Transport in the Intertropical Convergence Zone

NASA Technical Reports Server (NTRS)

Page, William A.

1982-01-01

The following six papers report preliminary results obtained from a field experiment designed to study the role of tropical cumulo-nimbus clouds in the transfer of water vapor from the troposphere to the stratosphere over the region of Panama. The measurements were made utilizing special NOAA enhanced IR satellite images, radiosonde-ozonesondes and a NASA U-2 aircraft carrying. nine experiments. The experiments were provided by a group of NASA, NOAA, industry, and university scientists. Measurements included atmospheric humidity, air and cloud top temperatures, atmospheric tracer constituents, cloud particle characteristics and cloud morphology. The aircraft made a total of eleven flights from August 30 through September 18, 1980, from Howard Air Force Base, Panama; the pilots obtained horizontal and vertical profiles in and near convectively active regions and flew around and over cumulo-nimbus towers and through the extended anvils in the stratosphere. Cumulo-nimbus clouds in the tropics appear to play an important role in upward water vapor transport and may represent the principal source influencing the stratospheric water vapor budget. The clouds provide strong vertical circulation in the troposphere, mixing surface air and its trace materials (water vapor, CFM's sulfur compounds, etc.) quickly up to the tropopause. It is usually assumed that large scale mean motions or eddy scale motions transport the trace materials through the tropopause and into the stratosphere where they are further dispersed and react with other stratospheric constituents. The important step between the troposphere and stratosphere for water vapor appears to depend upon the processes occurring at or near the tropopause at the tops of the cumulo-nimbus towers. Several processes have been sugested: (1) The highest towers penetrate the tropopause and carry water in the form of small ice particles directly into the stratosphere. (2) Water vapor from the tops of the cumulonimbus clouds is

Free tropospheric observations of Carbonyl Sulfide from Aura Tropospheric Emission Spectrometer over ocean

NASA Astrophysics Data System (ADS)

Kuai, Le; Worden, John; Campbell, Ellitt; Kulawik, Susan; Montzka, Stephen; Liu, Jiabin

2014-05-01

Carbonyl sulfide (OCS) is the most abundant sulfur gas in the troposphere with a global averaging mixing ratio of about 500 part per trillion (ppt). The ocean is the primary source of OCS, emitting OCS directly or its precursors, carbon disulfide and dimethyl sulfide. The most important atmospheric sink of OCS is uptake by terrestrial plants via photosynthesis. Although the global budget of atmospheric OCS has been studied, the global integrated OCS fluxes have large uncertainties, e.g. the uncertainties of the ocean fluxes are as large as 100% or more and how the ocean sources are distributed is not well known. We developed a retrieval algorithm for free tropospheric carbonyl sulfide (OCS) observations above the ocean using radiance measurements from the Tropospheric Emission Spectrometer (TES). These first observations of the free tropospheric OCS provide global maps with information of OCS seasonal and spatial variability in the mid troposphere. These data will help to characterize ocean OCS fluxes. Evaluation of the biases and uncertainties in the TES OCS estimates against aircraft profiles from the HIPPO campaign and ground data from the NOAA Mauna Loa site suggests that the OCS retrievals (1) have less than 1.0 degree of freedom for signals (DOFs), (2) are sensitive in the mid-troposphere with a peak sensitivity typically between 300 to 500 hPa, (3) and have much smaller systematic errors from temperature, CO2 and H2O calibrations relative to random errors from measurement noise. Here we estimate the monthly means from TES measurements averaged over multiple years so that random errors are reduced and useful information about OCS seasonal and latitudinal variability can be derived. With this averaging, TES OCS data are found to be consistent (within the calculated uncertainties) with NOAA ground observations and HIPPO aircraft measurements and captures the seasonal and latitudinal variations observed by these in situ data within the estimated uncertainties

Summertime tropospheric ozone distributions over central and eastern Canada

NASA Technical Reports Server (NTRS)

Anderson, B. E.; Gregory, G. L.; Barrick, J. D.; Collins, J. E., Jr.; Sachse, G. W.; Shipham, M. C.; Hudgins, C. H.

1994-01-01

Ozone measurements were obtained between the surface and the 6-km altitude on aircraft flights over central and eastern Canada during the summer 1990 NASA Global Tropospheric Experiment Arctic Boundary Layer Expedition (GTE/ABLE 3B). Tropospheric O3 budgets for these regions were observed to be highly variable and significantly impacted by long-range transport and regional scale air mass modification processes. For example, integrated O3 abundance below 5-km altitude averaged 40% and 30% greater in air masses influenced by anthropogenic sources and biomass burning, respectively, than in background (polar) air. Conversely, aged air transported from subtropical areas of the Pacific at times reduced O3 abundance in this height interval by up to 20%. Though intrusion of anthropogenic air was infrequent during the experiment period, the influence of biomass-burning emissions was particularly notable as two thirds of the flights sampled air influenced by plumes from fires burning in Alaska and western Canada. The impinging pollution, both natural and anthropogenic, not only elevated O3 levels directly but also was a source of reactive nitrogen (and nonmethane hydrocarbons) which generally increases the tropospheric lifetime of O3 via moderation of photochemical destruction rates.

Assessing cloud radiative effects on tropospheric photolysis rates and key oxidants during aircraft campaigns using satellite cloud observations and a global chemical transport model

NASA Astrophysics Data System (ADS)

Zhang, B.; Liu, H.; Crawford, J. H.; Chen, G.; Voulgarakis, A.; Fairlie, T. D.; Duncan, B. N.; Ham, S. H.; Kato, S.; Payer Sulprizio, M.; Yantosca, R.

2017-12-01

Clouds affect tropospheric photochemistry through modifying solar radiation that determines photolysis rates. Observational and modeling studies have indicated that photolysis rates are enhanced above and in the upper portion of cloud layers and are reduced below optically thick clouds due to their dominant backscattering effect. However, large uncertainties exist in the representation of cloud spatiotemporal (especially vertical) distributions in global models, which makes understanding of cloud radiative effects on tropospheric chemistry challenging. Our previous study using a global 3-D chemical transport model (GEOS-Chem) driven by various meteorological data sets showed that the radiative effects of clouds on photochemistry are more sensitive to the differences in the vertical distribution of clouds than to those in the magnitude of column cloud optical depths. In this work, we evaluate monthly mean cloud optical properties and distributions in the MERRA-2 reanalysis with those in C3M, a 3-D cloud data product developed at NASA Langley Research Center and merged from multiple A-Train satellite (CERES, CloudSat, CALIPSO, and MODIS) observations. We conduct tropospheric chemistry simulations for the periods of several aircraft campaigns, including ARCTAS (April, June-July, 2008), DC3 (May-June, 2012), and SEAC4RS (August-September, 2013) with GEOS-Chem driven by MERRA-2. We compare model simulations with and without constraints of cloud optical properties and distributions from C3M, and evaluate model photolysis rates (J[O1D] and J[NO2]) and key oxidants (e.g., OH and ozone) with aircraft profile measurements. We will assess whether the constraints provided by C3M improve model simulations of photolysis rates and oxidants as well as their variabilities.

Evaluating a Priori Ozone Profile Information Used in TEMPO (Tropospheric Emissions: Monitoring of Pollution) Tropospheric Ozone Retrievals

NASA Technical Reports Server (NTRS)

Johnson, Matthew Stephen

2017-01-01

A primary objective for TOLNet is the evaluation and validation of space-based tropospheric O3 retrievals from future systems such as the Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite. This study is designed to evaluate the tropopause-based O3 climatology (TB-Clim) dataset which will be used as the a priori profile information in TEMPO O3 retrievals. This study also evaluates model simulated O3 profiles, which could potentially serve as a priori O3 profile information in TEMPO retrievals, from near-real-time (NRT) data assimilation model products (NASA Global Modeling and Assimilation Office (GMAO) Goddard Earth Observing System (GEOS-5) Forward Processing (FP) and Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA2)) and full chemical transport model (CTM), GEOS-Chem, simulations. The TB-Clim dataset and model products are evaluated with surface (0-2 km) and tropospheric (0-10 km) TOLNet observations to demonstrate the accuracy of the suggested a priori dataset and information which could potentially be used in TEMPO O3 algorithms. This study also presents the impact of individual a priori profile sources on the accuracy of theoretical TEMPO O3 retrievals in the troposphere and at the surface. Preliminary results indicate that while the TB-Clim climatological dataset can replicate seasonally-averaged tropospheric O3 profiles observed by TOLNet, model-simulated profiles from a full CTM (GEOS-Chem is used as a proxy for CTM O3 predictions) resulted in more accurate tropospheric and surface-level O3 retrievals from TEMPO when compared to hourly (diurnal cycle evaluation) and daily-averaged (daily variability evaluation) TOLNet observations. Furthermore, it was determined that when large daily-averaged surface O3 mixing ratios are observed (65 ppb), which are important for air quality purposes, TEMPO retrieval values at the surface display higher correlations and less bias when applying CTM a priori profile information

NASA Global Hawk Overview

NASA Technical Reports Server (NTRS)

2011-01-01

NASA Global Hawk is operational and supporting Earth science research. 29 Flights were conducted during the first year of operations, with a total of 253 flight hours. Three major science campaigns have been conducted with all objectives met. Two new science campaigns are in the planning stage

Tropospheric emissions: monitoring of pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Chance, Kelly; Liu, Xiong; Suleiman, Raid M.; Flittner, David E.; Al-Saadi, Jassim; Janz, Scott J.

2013-09-01

TEMPO was selected in 2012 by NASA as the first Earth Venture Instrument, for launch circa 2018. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO measures from Mexico City to the Canadian tar sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (~2 km N/S×4.5 km E/W at 36.5°N, 100°W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a commercial GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO will launch at a prime time to be the North American component of the global geostationary constellation of pollution monitoring together with European Sentinel-4 and Korean GEMS.

Some tests of wet tropospheric calibration for the CASA Uno Global Positioning System experiment

NASA Technical Reports Server (NTRS)

Dixon, T. H.; Wolf, S. Kornreich

1990-01-01

Wet tropospheric path delay can be a major error source for Global Positioning System (GPS) geodetic experiments. Strategies for minimizing this error are investigted using data from CASA Uno, the first major GPS experiment in Central and South America, where wet path delays may be both high and variable. Wet path delay calibration using water vapor radiometers (WVRs) and residual delay estimation is compared with strategies where the entire wet path delay is estimated stochastically without prior calibration, using data from a 270-km test baseline in Costa Rica. Both approaches yield centimeter-level baseline repeatability and similar tropospheric estimates, suggesting that WVR calibration is not critical for obtaining high precision results with GPS in the CASA region.

Air Quality Forecasts Using the NASA GEOS Model: A Unified Tool from Local to Global Scales

NASA Technical Reports Server (NTRS)

Knowland, E. Emma; Keller, Christoph; Nielsen, J. Eric; Orbe, Clara; Ott, Lesley; Pawson, Steven; Saunders, Emily; Duncan, Bryan; Cook, Melanie; Liu, Junhua;

Nitrogen oxides in the global upper troposphere interpreted with cloud-sliced NO2 from the Ozone Monitoring Instrument

NASA Astrophysics Data System (ADS)

Marais, Eloise A.; Jacob, Daniel J.; Choi, Sungyeon; Joiner, Joanna; Belmonte-Rivas, Maria; Cohen, Ronald C.; Ryerson, Thomas B.; Weinheimer, Andrew J.; Volz-Thomas, Andreas

2017-04-01

Nitrogen oxides (NOx ≡ NO + NO2) are long lived in the upper troposphere (UT), and so have a large impact on ozone formation where ozone is a powerful greenhouse gas. Measurements of UT NOx are limited to summertime aircraft campaigns predominantly in North America. There are year-round NOx measurements from instruments onboard commercial aircraft, but NO2 measurements are susceptible to large interferences. Satellites provide global coverage, but traditional space-based NO2 observations only provide one piece of vertical information in the troposphere. New cloud-sliced satellite NO2 products offer additional vertical information by retrieving partial NO2 columns above clouds and further exploit differences in cloud heights to calculate UT NO2 mixing ratios. Two new cloud-sliced NO2 products from the Ozone Monitoring Instrument (OMI; 2004 launch) provide seasonal UT NO2 data centered at 350 hPa for 2005-2007 (NASA product) and 380 hPa for 2006 only (KNMI). Differences between the products include spectral fitting to obtain NO2 along the viewing path (slant column), the air mass factor calculation to convert slant columns to true vertical columns, treatment of the stratospheric NO2 component, and the choice of cloud products. The resultant NASA NO2 mixing ratios are 30% higher than KNMI NO2 and are consistent with summertime aircraft NO2 observations over North America. Comparison between NASA NO2 and the GEOS-Chem chemical transport model exposes glaring inadequacies in the model. In summer in the eastern US lightning NOx emissions are overestimated by at least a factor of 2, corroborated by comparison of GEOS-Chem and MOZAIC aircraft observations of reactive nitrogen (NOy). Too fast heterogeneous hydrolysis of dinitrogen pentoxide (N2O5) leads to an underestimate in UT NO2 in winter across the northern hemisphere. Absence of interannual variability in lightning flashes in the lightning NOx parameterization induces biases in UT NO2 in the tropics due to anomalous

Eleven years of tropospheric NO2 measured by GOME, SCIAMACHY and OMI

NASA Astrophysics Data System (ADS)

Eskes, H.; Boersma, F.; Dirksen, R.; van der A, R.; Veefkind, P.; Levelt, P.; Brinksma, E.; van Roozendael, M.; de Smedt, I.; Gleason, J.

2006-12-01

Based on measurements of GOME on ESA ERS-2, SCIAMACHY on ESA-ENVISAT, and Ozone Monitoring Instrument (OMI) on the NASA EOS-Aura satellite there is now a unique 11-year dataset of global tropospheric nitrogen dioxide measurements from space. The retrieval approach consists of two steps. The first step is an application of the DOAS (Differential Optical Absorption Spectroscopy) approach which delivers the total absorption optical thickness along the light path (the slant column). For GOME and SCIAMACHY this is based on the DOAS implementation developed by BIRA/IASB. For OMI the DOAS implementation was developed in a collaboration between KNMI and NASA. The second retrieval step, developed at KNMI, estimates the tropospheric vertical column of NO2 based on the slant column, cloud fraction and cloud top height retrieval, stratospheric column estimates derived from a data assimilation approach and vertical profile estimates from space-time collocated profiles from the TM chemistry-transport model. The second step was applied with only minor modifications to all three instruments to generate a uniform 11-year data set. In our talk we will address the following topics: - A short summary of the retrieval approach and results - Comparisons with other retrievals - Comparisons with global and regional-scale models - OMI-SCIAMACHY and SCIAMACHY-GOME comparisons - Validation with independent measurements - Trend studies of NO2 for the past 11 years

Lidar Measurements of Tropospheric Wind Profiles with the Double Edge Technique

NASA Technical Reports Server (NTRS)

Gentry, Bruce M.; Li, Steven X.; Korb, C. Laurence; Mathur, Savyasachee; Chen, Huailin

1998-01-01

Research has established the importance of global tropospheric wind measurements for large scale improvements in numerical weather prediction. In addition, global wind measurements provide data that are fundamental to the understanding and prediction of global climate change. These tasks are closely linked with the goals of the NASA Earth Science Enterprise and Global Climate Change programs. NASA Goddard has been actively involved in the development of direct detection Doppler lidar methods and technologies to meet the wind observing needs of the atmospheric science community. A variety of direct detection Doppler wind lidar measurements have recently been reported indicating the growing interest in this area. Our program at Goddard has concentrated on the development of the edge technique for lidar wind measurements. Implementations of the edge technique using either the aerosol or molecular backscatter for the Doppler wind measurement have been described. The basic principles have been verified in lab and atmospheric lidar wind experiments. The lidar measurements were obtained with an aerosol edge technique lidar operating at 1064 nm. These measurements demonstrated high spatial resolution (22 m) and high velocity sensitivity (rms variances of 0.1 m/s) in the planetary boundary layer (PBL). The aerosol backscatter is typically high in the PBL and the effects of the molecular backscatter can often be neglected. However, as was discussed in the original edge technique paper, the molecular contribution to the signal is significant above the boundary layer and a correction for the effects of molecular backscatter is required to make wind measurements. In addition, the molecular signal is a dominant source of noise in regions where the molecular to aerosol ratio is large since the energy monitor channel used in the single edge technique measures the sum of the aerosol and molecular signals. To extend the operation of the edge technique into the free troposphere we

Airborne Remote sensing of the OH tropospheric column with an Integrated Path Differential LIDAR.

NASA Astrophysics Data System (ADS)

Hanisco, T. F.; Liang, Q.; Nicely, J. M.; Brune, W. H.; Miller, D. O.; Thames, A. B.

2017-12-01

The Hydroxyl radical, OH, is central to the photochemistry that controls tropospheric oxidation including the removal of atmospheric methane. Measurements of this important species are thus critical to testing our understanding and for constraining model results. Until now, tropospheric measurements have been limited to airborne or ground-based in situ instruments best suited to test photochemical box models. However, because of the growing recognition of the importance of the global methane abundance, we have a growing need to better quantify OH at the regional to global scales that are best sampled with airborne or space-based remote sensing instruments. To address this need, we have developed an instrument concept and have begun work on a laser transmitter for an airborne integrated path differential absorption LIDAR for the detection of OH. We will describe the instrument and present the expected performance characteristics. As a demonstration, we will use measurements from the recent ATOM-1 NASA airborne campaign to show measured OH columns can be used to constrain regional and global models.

Tropospheric Chemistry Studies using Observations from GOME and TOMS

NASA Technical Reports Server (NTRS)

Chance, Kelly; Spurr, Robert J. D.; Kurosu, Thomas P.; Jacob, Daniel J.; Gleason, James F.

2003-01-01

Studies to quantitatively determine trace gas and aerosol amounts from the Global Ozone Monitoring Experiment (GOME) and the Total Ozone Monitoring Experiment (TOMS) and to perform chemical modeling studies which utilize these results are given. This includes: 1. Analysis of measurements from the GOME and TOMS instruments for troposphere distributions of O3 and HCHO; troposphere enhancements of SO2, NO2 and aerosols associated with major sources; and springtime events of elevated BrO in the lower Arctic troposphere. 2. Application of a global 3-dimensional model of troposphere chemistry to interpret the GOME observations in terms of the factors controlling the abundances of troposphere ozone and OH.

Global and Regional Decreases in Tropospheric Oxidants from Photochemical Effects of Aerosols

NASA Technical Reports Server (NTRS)

Martin, Randall V.; Jacob, Daniel J.; Yantosca, Robert M.; Chin, Mian; Ginoux, Paul

2003-01-01

We evaluate the sensitivity of tropospheric OH, O3, and O3 precursors to photochemical effects of aerosols not usually included in global models: (1) aerosol scattering and absorption of ultraviolet radiation and (2) reactive uptake of HO', NO2, and NO3. Our approach is to couple a global 3-D model of tropospheric chemistry (GEOS- CHEM) with aerosol fields from a global 3-D aerosol model (GOCART). Reactive uptake by aerosols is computed using reaction probabilities from a recent review (gamma(sub HO2) = 0.2, gamma(sub NO2) = 10(exp -4), gamma(sub NO3) = l0(exp -3). Aerosols decrease the O3 - O((sup 1)D) photolysis frequency by 5-20% at the surface throughout the Northern Hemisphere (largely due to mineral dust) and by a factor of 2 in biomass burning regions (largely due to black carbon). Aerosol uptake of HO2 accounts for 10-40% of total HOx radical ((triple bonds)OH + peroxy) loss in the boundary layer over polluted continental regions (largely due to sulfate and organic carbon) and for more than 70% over tropical biomass burning regions (largely due to organic carbon). Uptake of NO2 and NO3 accounts for 10-20% of total HNO3 production over biomass burning regions and less elsewhere. Annual mean OH concentrations decrease by 9% globally and by 5-35% in the boundary layer over the Northern Hemisphere. Simulated CO increases by 5- 15 ppbv in the remote Northern Hemisphere, improving agreement with observations. Simulated boundary layer O3 decreases by 15- 45 ppbv over India during the biomass burning season in March and by 5-9 ppbv over northern Europe in August, again improving comparison with observations. We find that particulate matter controls would increase surface O3 over Europe and other industrial regions.

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

NASA Technical Reports Server (NTRS)

Zoogman, P.; Liu, X.; Suleiman, R. M.; Pennington, W. F.; Flittner, D. E.; Al-Saadi, J. A.; Hilton, B. B.; Nicks, D. K.; Newchurch, M. J.; Carr, J. L.;

Calibration of NASA Turbulent Air Motion Measurement System

NASA Technical Reports Server (NTRS)

Barrick, John D. W.; Ritter, John A.; Watson, Catherine E.; Wynkoop, Mark W.; Quinn, John K.; Norfolk, Daniel R.

1996-01-01

A turbulent air motion measurement system (TAMMS) was integrated onboard the Lockheed 188 Electra airplane (designated NASA 429) based at the Wallops Flight Facility in support of the NASA role in global tropospheric research. The system provides air motion and turbulence measurements from an airborne platform which is capable of sampling tropospheric and planetary boundary-layer conditions. TAMMS consists of a gust probe with free-rotating vanes mounted on a 3.7-m epoxy-graphite composite nose boom, a high-resolution inertial navigation system (INS), and data acquisition system. A variation of the tower flyby method augmented with radar tracking was implemented for the calibration of static pressure position error and air temperature probe. Additional flight calibration maneuvers were performed remote from the tower in homogeneous atmospheric conditions. System hardware and instrumentation are described and the calibration procedures discussed. Calibration and flight results are presented to illustrate the overall ability of the system to determine the three-component ambient wind fields during straight and level flight conditions.

Simultaneous measurements of carbon monoxide and ozone in the NASA Global Atmospheric Sampling Program (GASP)

NASA Astrophysics Data System (ADS)

Newell, R. E.; Wu, M.-F.

It is noted that the Global Atmospheric Sampling Program (GASP) was intended to establish global baseline values of selected atmospheric constituents that could be used for studies of the dynamics of the sampled region as well as for modeling purposes. Instrument packages were carried on four Boeing 747 aircraft in routine commercial service. Carbon monoxide and ozone data were collected simultaneously from early 1977 to early 1979 when GASP terminated. CO was measured with an infrared absorption analyzer using dual isotope fluorescence. Ozone was measured via absorption of UV light. Correlations between the CO and the O3 are tabulated; they are clearly negative for both troposphere and stratosphere in middle latitudes, indicating that transport processes between the stratosphere and troposphere (discussed) dominate. But in the low latitude troposphere the correlations are positive, indicating the possible influence of photochemical effects.

Observing Tropospheric Water Vapor by Radio Occultation using the Global Positioning System

NASA Technical Reports Server (NTRS)

Kursinski, E. R.; Hajj, G. A.; Hardy, K. R.; Romans, L. J.; Schofield, J. T.

1995-01-01

Given the importance of water vapor to weather, climate and hydrology, global humidity observations from satellites are critical. At low latitudes, radio occultation observations of Earth's atmosphere using the Global Positioning System (GPS) satellites allow water vapor profiles to be retrieved with accuracies of 10 to 20% below 6 to 7 km altitude and approx. 5% or better within the boundary layer. GPS observations provide a unique combination of accuracy, vertical resolution (less than or equal to 1 km) and insensitivity to cloud and aerosol particles that is well suited to observations of the lower troposphere. These characteristics combined with the inherent stability of radio occultation observations make it an excellent candidate for the measurement of long term trends.

Coordinated profiling of stratospheric intrusions and transported pollution by the Tropospheric Ozone Lidar Network (TOLNet) and NASA Alpha Jet experiment (AJAX): Observations and comparison to HYSPLIT, RAQMS, and FLEXPART

NASA Astrophysics Data System (ADS)

Langford, A. O.; Alvarez, R. J.; Brioude, J.; Evan, S.; Iraci, L. T.; Kirgis, G.; Kuang, S.; Leblanc, T.; Newchurch, M. J.; Pierce, R. B.; Senff, C. J.; Yates, E. L.

2018-02-01

Ground-based lidars and ozonesondes belonging to the NASA-supported Tropospheric Ozone Lidar Network (TOLNet) are used in conjunction with the NASA Alpha Jet Atmospheric eXperiment (AJAX) to investigate the transport of stratospheric ozone and entrained pollution into the lower troposphere above the United States on May 24-25, 2013. TOLNet and AJAX measurements made in California, Nevada, and Alabama are compared to tropospheric ozone retrievals from the Atmospheric Infrared Sounder (AIRS), to back trajectories from the NOAA Air Resources Laboratory (ARL) Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model, and to analyses from the NOAA/NESDIS Real-time Air Quality Modeling System (RAQMS) and FLEXPART particle dispersion model. The measurements and model analyses show much deeper descent of ozone-rich upper tropospheric/lower stratospheric air above the Desert Southwest than above the Southeast, and comparisons to surface measurements from regulatory monitors reporting to the U.S. EPA Air Quality System (AQS) suggest that there was a much greater surface impact in the Southwest including exceedances of the 2008 National Ambient Air Quality Standard (NAAQS) of 0.075 ppm in both Southern California and Nevada. Our analysis demonstrates the potential benefits to be gained by supplementing the existing surface ozone network with coordinated upper air observations by TOLNet.

Development of a Portable, Ground-based Ozone Lidar Instrument for Tropospheric Ozone Research and Educational Training

NASA Technical Reports Server (NTRS)

Chyba, Thomas; Zemker, Thomas; Fishman, Jack (Technical Monitor)

1999-01-01

The objective of this research project is to develop a portable, eye-safe, ground-based ozone lidar instrument specialized for ozone differential absorption lidar (DIAL) measurements in the troposphere. This research project directly supports the goal of NASA's Earth Science Enterprise to understand the distribution and budget of tropospheric ozone (objective 1.5 of the Earth Science Strategic Enterprise Plan, 1998-2002). It can participate in ground validation experiments for TES, a tropospheric ozone satellite mission due to be launched in 2002. It can also be utilized for correlative ground measurements in future GTE (Global Tropospheric Experiment) and space-based ozone lidar missions, such as ORACLE. Multiple ground-based ozone lidar systems would improve the data obtained through current ozone-sonde networks. This prototype instrument could to serve as the basic unit for these and other future monitoring projects requiring multi-instrument networks, such as that proposed for the Global Tropospheric Ozone Project (GTOP). GTOP is currently being formulated by a scientific panel of the International Global Atmospheric Chemistry Project to meet its goal to better understand the processes that control the global distribution of tropospheric ozone. In order for the lidar to be widely deployed in networks, it must be fairly easy to use and maintain as well as being cost-competitive with a ground station launching ozonesondes several times a day. A second 2-year grant to continue this effort with students participating in ground tests and system improvements has been awarded by the Office of Equal Employment Opportunities (OEOP). This project also supports existing NASA lidar missions through its development of advanced, compact lidar technology. Innovations in both transmitters and receivers have been made in this project. Finally, this system could be modified in the future to probe more deeply into the stratosphere. This could be accomplished by increasing the

Global tropospheric experiment at the Hong Kong Atmosphere Chemistry Measurement Station

NASA Technical Reports Server (NTRS)

Carroll, Mary Ann; Wang, Tao

1995-01-01

The major activities of the Global Tropospheric Experiment at the Hong Kong Atmospheric Chemistry Measurement Station are presented for the period 1 January - 31 December 1995. Activities included data analysis, reduction, and archiving of atmospheric measurements and sampling. Sampling included O3, CO, SO2, NO, TSP, RSP, and ozone column density. A data archive was created for the surface meteorological data. Exploratory data analysis was performed, including examination of time series, frequency distributions, diurnal variations and correlation. The major results have been or will be published in scientific journals as well as presented at conferences/workshops. Abstracts are attached.

Overview of Global/Regional Models Used to Evaluate Tropospheric Ozone in North America

NASA Technical Reports Server (NTRS)

Johnson, Matthew S.

2015-01-01

Ozone (O3) is an important greenhouse gas, toxic pollutant, and plays a major role in atmospheric chemistry. Tropospheric O3 which resides in the planetary boundary layer (PBL) is highly reactive and has a lifetime on the order of days, however, O3 in the free troposphere and stratosphere has a lifetime on the order of weeks or months. Modeling O3 mixing ratios at and above the surface is difficult due to the multiple formation/destruction processes and transport pathways that cause large spatio-temporal variability in O3 mixing ratios. This talk will summarize in detail the global/regional models that are commonly used to simulate/predict O3 mixing ratios in the United States. The major models which will be focused on are the: 1) Community Multi-scale Air Quality Model (CMAQ), 2) Comprehensive Air Quality Model with Extensions (CAMx), 3) Goddard Earth Observing System with Chemistry (GEOS-Chem), 4) Real Time Air Quality Modeling System (RAQMS), 5) Weather Research and Forecasting/Chemistry (WRF-Chem) model, National Center for Atmospheric Research (NCAR)'s Model for OZone And Related chemical Tracers (MOZART), and 7) Geophysical Fluid Dynamics Laboratory (GFDL) AM3 model. I will discuss the major modeling components which impact O3 mixing ratio calculations in each model and the similarities/differences between these models. This presentation is vital to the 2nd Annual Tropospheric Ozone Lidar Network (TOLNet) Conference as it will provide an overview of tools, which can be used in conjunction with TOLNet data, to evaluate the complex chemistry and transport pathways controlling tropospheric O3 mixing ratios.

A Global Climatology of Tropospheric and Stratospheric Ozone Derived from Aura OMI and MLS Measurements

NASA Technical Reports Server (NTRS)

Ziemke, J.R.; Chandra, S.; Labow, G.; Bhartia, P. K.; Froidevaux, L.; Witte, J. C.

2011-01-01

A global climatology of tropospheric and stratospheric column ozone is derived by combining six years of Aura Ozone Monitoring Instrument (OMI) and Microwave Limb Sounder (MLS) ozone measurements for the period October 2004 through December 2010. The OMI/MLS tropospheric ozone climatology exhibits large temporal and spatial variability which includes ozone accumulation zones in the tropical south Atlantic year-round and in the subtropical Mediterranean! Asia region in summer months. High levels of tropospheric ozone in the northern hemisphere also persist in mid-latitudes over the eastern North American and Asian continents extending eastward over the Pacific Ocean. For stratospheric ozone climatology from MLS, largest ozone abundance lies in the northern hemisphere in the latitude range 70degN-80degN in February-April and in the southern hemisphere around 40degS-50degS during months August-October. The largest stratospheric ozone abundances in the northern hemisphere lie over North America and eastern Asia extending eastward across the Pacific Ocean and in the southern hemisphere south of Australia extending eastward across the dateline. With the advent of many newly developing 3D chemistry and transport models it is advantageous to have such a dataset for evaluating the performance of the models in relation to dynamical and photochemical processes controlling the ozone distributions in the troposphere and stratosphere.

Discoveries about Tropospheric Ozone Pollution from Satellite and Sounding

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

2004-01-01

We have been producing near-real time tropospheric ozone satellite maps from the TOMS (Total Ozone Mapping Spectrometer) sensor since 1997. This is most readily done for the tropics, where the stratospheric and tropospheric ozone column amounts can be discriminated readily. Maps for 1996-2000 for the operational Earth-Probe instrument reside at: chttp://www.atmos.umd.edu/-trope>. Pollution in the tropics is influenced by biomass burning and by transport patterns that favor recirculation and in other cases reflect climate variability like the El-Nino-Southern Oscillation [Thompson et al., 2001]. Time permitting, examples of mid-latitude, intercontinental transport of ozone pollution sensed by TOMS will be shown. The satellite view of chemical-dynamical interactions in tropospheric ozone is not adequate to capture vertical variability. Thus, in 1998, NASA's Goddard Space Flight Center and a team of international sponsors established the SHADOZ (Southern Hemisphere ADditional OZonesondes) project to address the gap in tropical ozone soundings. SHADOZ augments launches and provides a public archive of ozonesonde data from twelve tropical stations at http://croc.gsfc.nasa.gov/shadoz. Further insights into the role of chemical and dynamical influences have emerged from the first 4-5 years of SHADOZ data (less than 2000 ozone profiles): (a) highly variable tropospheric ozone; (b) a zonal wave-one pattern in tropospheric column ozone; (c) convective variability affects tropospheric ozone over the Indian and Pacific Ocean; (d) a "tropical Atlantic Paradox" appears in December-January-February.

Satellite observations of tropospheric ammonia and carbon monoxide: Global distributions, regional correlations and comparisons to model simulations

EPA Science Inventory

Ammonia (NH3) and carbon monoxide (CO) are primary pollutants emitted to the Earth's atmosphere from common as well as distinct sources associated with anthropogenic and natural activities. The seasonal and global distributions and correlations of NH3 and CO from the Tropospheric...

The global consequences of increasing tropospheric ozone concentrations

NASA Technical Reports Server (NTRS)

Fishman, Jack

1989-01-01

Recent analyses of long term records of tropospheric ozone measurements in the Northern Hemisphere suggest that it is increasing at a rate of 1 to 2 percent per year. Because of this, it is argued that the amount of atmospheric warming due to increasing tropospheric ozone is comparable to, or possibly even greater than, the amount of warming due to the increase of carbon dioxide. Unlike all other climatically important trace gases, ozone is toxic, and increases in its concentration will result in serious environmental damage, as well as impairment of human health.

Discoveries about Tropospheric Ozone Pollution from Satellite and Soundings

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

2004-01-01

We have been producing near-red time tropospheric ozone satellite maps from the TOMS (Total Ozone Mapping Spectrometer) sensor since 1997. Maps for 1996-2000 for the operational Earth-Probe instrument are at:. Pollution in the tropics is influenced by biomass burning and by transport patterns that favor recirculation and in other cases reflect climate variability like the El-Nino-Southern Oscillation [Thompson et al., 2001]. The satellite view of chemical-dynamical interactions in tropospheric ozone is not adequate to capture vertical gradients in pollution. Thus, in 1998, NASA's Goddard Space Flight Center and a team of international sponsors established the SHADOZ (Southern Hemisphere ADditional OZonesondes) project to address the gap in tropical ozone soundings. SHADOZ augments launches and provides a public archive of ozonesonde data from twelve tropical stations at http://croc.gsfc.nasa.gov/shadoz. Further insights into the role of chemical and dynamical influences have emerged from the first 4-5 years of SHADOZ data (more than 2000 ozone profiles). Highly variable tropospheric ozone and a zonal wave-one pattern in tropospheric ozone suggest that dynamics is as important as pollution in determining tropical ozone distributions.

Tropospheric Ozone Assessment Report: Database and Metrics Data of Global Surface Ozone Observations

DOE PAGES

Schultz, Martin G.; Schroder, Sabine; Lyapina, Olga; ...

2017-11-27

In support of the first Tropospheric Ozone Assessment Report (TOAR) a relational database of global surface ozone observations has been developed and populated with hourly measurement data and enhanced metadata. A comprehensive suite of ozone data products including standard statistics, health and vegetation impact metrics, and trend information, are made available through a common data portal and a web interface. These data form the basis of the TOAR analyses focusing on human health, vegetation, and climate relevant ozone issues, which are part of this special feature. Cooperation among many data centers and individual researchers worldwide made it possible to buildmore » the world's largest collection of in-situ hourly surface ozone data covering the period from 1970 to 2015. By combining the data from almost 10,000 measurement sites around the world with global metadata information, new analyses of surface ozone have become possible, such as the first globally consistent characterisations of measurement sites as either urban or rural/remote. Exploitation of these global metadata allows for new insights into the global distribution, and seasonal and long-term changes of tropospheric ozone and they enable TOAR to perform the first, globally consistent analysis of present-day ozone concentrations and recent ozone changes with relevance to health, agriculture, and climate. Considerable effort was made to harmonize and synthesize data formats and metadata information from various networks and individual data submissions. Extensive quality control was applied to identify questionable and erroneous data, including changes in apparent instrument offsets or calibrations. Such data were excluded from TOAR data products. Limitations of a posteriori data quality assurance are discussed. As a result of the work presented here, global coverage of surface ozone data for scientific analysis has been significantly extended. Yet, large gaps remain in the surface observation

Tropospheric Ozone Assessment Report: Database and Metrics Data of Global Surface Ozone Observations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schultz, Martin G.; Schroder, Sabine; Lyapina, Olga

In support of the first Tropospheric Ozone Assessment Report (TOAR) a relational database of global surface ozone observations has been developed and populated with hourly measurement data and enhanced metadata. A comprehensive suite of ozone data products including standard statistics, health and vegetation impact metrics, and trend information, are made available through a common data portal and a web interface. These data form the basis of the TOAR analyses focusing on human health, vegetation, and climate relevant ozone issues, which are part of this special feature. Cooperation among many data centers and individual researchers worldwide made it possible to buildmore » the world's largest collection of in-situ hourly surface ozone data covering the period from 1970 to 2015. By combining the data from almost 10,000 measurement sites around the world with global metadata information, new analyses of surface ozone have become possible, such as the first globally consistent characterisations of measurement sites as either urban or rural/remote. Exploitation of these global metadata allows for new insights into the global distribution, and seasonal and long-term changes of tropospheric ozone and they enable TOAR to perform the first, globally consistent analysis of present-day ozone concentrations and recent ozone changes with relevance to health, agriculture, and climate. Considerable effort was made to harmonize and synthesize data formats and metadata information from various networks and individual data submissions. Extensive quality control was applied to identify questionable and erroneous data, including changes in apparent instrument offsets or calibrations. Such data were excluded from TOAR data products. Limitations of a posteriori data quality assurance are discussed. As a result of the work presented here, global coverage of surface ozone data for scientific analysis has been significantly extended. Yet, large gaps remain in the surface observation

NASA Global Hawk: A New Tool for Earth Science Research

NASA Technical Reports Server (NTRS)

Naftel, J. Chris

2009-01-01

Scientists have eagerly anticipated the performance capability of the National Aeronautics and Space Administration (NASA) Global Hawk for over a decade. In 2009 this capability becomes operational. One of the most desired performance capabilities of the Global Hawk aircraft is very long endurance. The Global Hawk aircraft can remain airborne longer than almost all other jet-powered aircraft currently flying, and longer than all other aircraft available for airborne science use. This paper describes the NASA Global Hawk system, payload accommodations, concept of operations, and the first scientific data-gathering mission: Global Hawk Pacific 2009.

Atmospheric retrievals with the Tropospheric Emission Spectrometer (TES)

NASA Technical Reports Server (NTRS)

Bowman, K. W.

2003-01-01

The Tropospheric Emission Spectrometer (TES) on the EOS-Aura spacecraft will measure the global 3-dimensional distribution of ozone in the troposphere and many of the chemical species that are part of its formation and destruction.

Tropospheric Delay Raytracing Applied in VLBI Analysis

NASA Astrophysics Data System (ADS)

MacMillan, D. S.; Eriksson, D.; Gipson, J. M.

2013-12-01

Tropospheric delay modeling error continues to be one of the largest sources of error in VLBI analysis. For standard operational solutions, we use the VMF1 elevation-dependent mapping functions derived from ECMWF data. These mapping functions assume that tropospheric delay at a site is azimuthally symmetric. As this assumption does not reflect reality, we have determined the raytrace delay along the signal path through the troposphere for each VLBI quasar observation. We determined the troposphere refractivity fields from the pressure, temperature, specific humidity and geopotential height fields of the NASA GSFC GEOS-5 numerical weather model. We discuss results from analysis of the CONT11 R&D and the weekly operational R1+R4 experiment sessions. When applied in VLBI analysis, baseline length repeatabilities were better for 66-72% of baselines with raytraced delays than with VMF1 mapping functions. Vertical repeatabilities were better for 65% of sites.

Influence of isentropic transport on seasonal ozone variations in the lower stratosphere and subtropical upper troposphere

NASA Technical Reports Server (NTRS)

Jing, P.; Cunnold, D. M.; Yang, E.-S.; Wang, H.-J.

2005-01-01

The isentropic cross-tropopause ozone transport has been estimated in both hemispheres in 1999 based on the potential vorticity mapping of Stratospheric Aerosol and Gas Experiment 11 ozone measurements and contour advection calculations using the NASA Goddard Space Flight Center Global and Modeling Assimilation Office analysis. The estimated net isentropic stratosphere-to-troposphere ozone flux is approx.118 +/- 61 x 10(exp9)kg/yr globally within the layer between 330 and 370 K in 1999; 60% of it is found in the Northern Hemisphere, and 40% is found in the Southern Hemisphere. The monthly average ozone fluxes are strongest in summer and weakest in winter in both hemispheres. The seasonal variations of ozone in the lower stratosphere (LS) and upper troposphere (UT) have been analyzed using ozonesonde observations from ozonesonde stations in the extratropics and subtropics, respectively. It is shown that observed ozone levels increase in the UT over subtropical ozonesonde stations and decrease in the LS over extratropical stations in late spring/early summer and that the ozone increases in the summertime subtropical UT are unlikely to be explained by photochemical ozone production and diabatic transport alone. We conclude that isentropic transport is a significant contributor to ozone levels in the subtropical upper troposphere, especially in summer.

Tropospheric O3 over Indonesia during biomass burning events measured with GOME (Global Ozone Monitoring Experiment) and compared with backtrajectory calculation

NASA Astrophysics Data System (ADS)

Ladstaetter-Weissenmayer, A.; Meyer-Arnek, J.; Burrows, J. P.

During the dry season, biomass burning is an important source of ozone precursors for the tropical troposphere, and ozone formation can occur in biomass burning plumes originating in Indonesia and northern Australia. Satellite based GOME (Global Ozone Measuring experiment) data are used to characterize the amount of tropospheric ozone production over this region during the El Niño event in September 1997 compared to a so called "normal" year 1998. Large scale biomass burning occurred over Kalimantan in 1997 caused by the absence of the northern monsoon rains, leading to significant increases in tropospheric ozone. Tropospheric ozone was determined from GOME data using the Tropospheric Excess Method (TEM). Backtrajectory calculations show that Indonesia is influenced every summer by the emissions of trace gases from biomass buring over northern Australia. But in 1997 over Indonesia an increasing of tropospheric ozone amounts can be observed caused by the fires over Indonesia itself as well as by northern Australia. The analysis of the measurements of BIBLE-A (Biomass Burning and Lightning Experiment) and using ATSR (Along the Track Scanning Radiometer) data show differences in the view to the intensity of fire counts and therefore in the amount of the emission of precursors of tropospheric ozone comparing September 1997 to September 1998.

NASA Global Hawk: A Unique Capability for the Pursuit of Earth Science

NASA Technical Reports Server (NTRS)

Naftel, J. Chris

2007-01-01

For more than 2 years, the NASA Dryden Flight Research Center has been preparing for the receipt of two Advanced Concept Technology Demonstration Global Hawk air vehicles from the United States Air Force. NASA Dryden intends to establish a Global Hawk Project Office, which will be responsible for developing the infrastructure required to operate this unmanned aerial system and establishing a trained maintenance and operations team. The first flight of a NASA Global Hawk air vehicle is expected to occur in 2008. The NASA Global Hawk system can be used by a variety of customers, including U.S. Government agencies, civilian organizations, universities, and state governments. Initially, the main focus of the research activities is expected to be Earth science related. A combination of the vehicle s range, endurance, altitude, payload power, payload volume, and payload weight capabilities separates the Global Hawk unmanned aerial system from all other platforms available to the science community. This report describes the NASA Global Hawk system and current plans for the NASA air vehicle concept of operations, and provides examples of potential missions with an emphasis on science missions.

Tropospheric emissions: Monitoring of pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Zoogman, P.; Liu, X.; Suleiman, R. M.; Pennington, W. F.; Flittner, D. E.; Al-Saadi, J. A.; Hilton, B. B.; Nicks, D. K.; Newchurch, M. J.; Carr, J. L.; Janz, S. J.; Andraschko, M. R.; Arola, A.; Baker, B. D.; Canova, B. P.; Chan Miller, C.; Cohen, R. C.; Davis, J. E.; Dussault, M. E.; Edwards, D. P.; Fishman, J.; Ghulam, A.; González Abad, G.; Grutter, M.; Herman, J. R.; Houck, J.; Jacob, D. J.; Joiner, J.; Kerridge, B. J.; Kim, J.; Krotkov, N. A.; Lamsal, L.; Li, C.; Lindfors, A.; Martin, R. V.; McElroy, C. T.; McLinden, C.; Natraj, V.; Neil, D. O.; Nowlan, C. R.; O`Sullivan, E. J.; Palmer, P. I.; Pierce, R. B.; Pippin, M. R.; Saiz-Lopez, A.; Spurr, R. J. D.; Szykman, J. J.; Torres, O.; Veefkind, J. P.; Veihelmann, B.; Wang, H.; Wang, J.; Chance, K.

2017-01-01

TEMPO was selected in 2012 by NASA as the first Earth Venture Instrument, for launch between 2018 and 2021. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO observes from Mexico City, Cuba, and the Bahamas to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution ( 2.1 km N/S×4.4 km E/W at 36.5°N, 100°W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry, as well as contributing to carbon cycle knowledge. Measurements are made hourly from geostationary (GEO) orbit, to capture the high variability present in the diurnal cycle of emissions and chemistry that are unobservable from current low-Earth orbit (LEO) satellites that measure once per day. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a commercial GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), formaldehyde (H2CO), glyoxal (C2H2O2), bromine monoxide (BrO), IO (iodine monoxide), water vapor, aerosols, cloud parameters, ultraviolet radiation, and foliage properties. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides these near-real-time air quality products that will be made publicly available. TEMPO will launch at a prime time to be the North American component of the global geostationary constellation of pollution monitoring

Satellite Observations of Tropospheric Chemistry

NASA Technical Reports Server (NTRS)

Singh, Hanwant B.; Jacob, Daniel J.; Hipskind, R. Stephen (Technical Monitor)

2001-01-01

The troposphere is an essential component of the earth's life support system as well as the gateway for the exchange of chemicals between different geochemical reservoirs of the earth. The chemistry of the troposphere is sensitive to perturbation from a wide range of natural phenomena and human activities. The societal concern has been greatly enhanced in recent decades due to ever increasing pressures of population growth and industrialization. Chemical changes within the troposphere control a vast array of processes that impact human health, the biosphere, and climate. A main goal of tropospheric chemistry research is to measure and understand the response of atmospheric composition to natural and anthropogenic perturbations, and to develop the capability to predict future change. Atmospheric chemistry measurements are extremely challenging due to the low concentrations of critical species and the vast scales over which the observations must be made. Available tropospheric data are mainly from surface sites and aircraft missions. Because of the limited temporal extent of aircraft observations, we have very limited information on tropospheric composition above the surface. This situation can be contrasted to the stratosphere, where satellites have provided critical and detailed chemical data on the global distribution of key trace gases.

Global Weather Prediction and High-End Computing at NASA

NASA Technical Reports Server (NTRS)

Lin, Shian-Jiann; Atlas, Robert; Yeh, Kao-San

2003-01-01

We demonstrate current capabilities of the NASA finite-volume General Circulation Model an high-resolution global weather prediction, and discuss its development path in the foreseeable future. This model can be regarded as a prototype of a future NASA Earth modeling system intended to unify development activities cutting across various disciplines within the NASA Earth Science Enterprise.

Thermodynamic constraint on the depth of the global tropospheric circulation.

PubMed

Thompson, David W J; Bony, Sandrine; Li, Ying

2017-08-01

The troposphere is the region of the atmosphere characterized by low static stability, vigorous diabatic mixing, and widespread condensational heating in clouds. Previous research has argued that in the tropics, the upper bound on tropospheric mixing and clouds is constrained by the rapid decrease with height of the saturation water vapor pressure and hence radiative cooling by water vapor in clear-sky regions. Here the authors contend that the same basic physics play a key role in constraining the vertical structure of tropospheric mixing, tropopause temperature, and cloud-top temperature throughout the globe. It is argued that radiative cooling by water vapor plays an important role in governing the depth and amplitude of large-scale dynamics at extratropical latitudes.

Global Hawk Aircraft Lands at NASA Wallops for Hurricane Mission

NASA Image and Video Library

2017-12-08

The first of two NASA Global Hawk unmanned aerial vehicles supporting the Hurricane and Severe Storm Sentinel (HS3) mission landed at 7:39 a.m. today, Aug. 14, 2013, at NASA's Wallops Flight Facility, Wallops Island, Va. During August and September, NASA will fly the two Global Hawks over the Atlantic Ocean to study tropical storms and the processes that underlie hurricane formation and intensification. The aircraft are equipped with instruments to survey the overall environment of the storms and peer into the inner core of hurricanes to study their structure and processes. For more information, visit: www.nasa.gov/HS3. Photo Credit: NASA Wallops Keith Koehler NASA Wallops Flight Facility NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

NASA Global Hawk: A Unique Capability for the Pursuit of Earth Science

NASA Technical Reports Server (NTRS)

Naftel, J. Chris

2007-01-01

For more than 2 years, the NASA Dryden Flight Research Center has been preparing for the receipt of two Advanced Concept Technology Demonstration Global Hawk air vehicles from the United States Air Force. NASA Dryden intends to establish a Global Hawk Project Office, which will be responsible for developing the infrastructure required to operate this unmanned aerial system and establishing a trained maintenance and operations team. The first flight of a NASA Global Hawk air vehicle is expected to occur in 2008. The NASA Global Hawk system can be used by a variety of customers, including U.S. Government agencies, civilian organizations, universities, and state governments. A combination of the vehicle s range, endurance, altitude, payload power, payload volume, and payload weight capabilities separates the Global Hawk unmanned aerial system from all other platforms available to the science community.

Global sensing of gaseous and aerosol trace species using automated instrumentation on 747 airliners

NASA Technical Reports Server (NTRS)

Perkins, P. J.; Papathakos, L. C.

1977-01-01

The Global Atmospheric Sampling Program (GASP) by NASA is collecting and analyzing data on gaseous and aerosol trace species in the upper troposphere and lower stratosphere. Measurements are obtained from automated systems installed on four 747 airliners flying global air routes. Advances were made in airborne sampling instrumentation. Improved instruments and analysis techniques are providing an expanding data base for trace species including ozone, carbon monoxide, water vapor, condensation nuclei and mass concentrations of sulfates and nitrates. Simultaneous measurements of several trace species obtained frequently can be used to uniquely identify the source of the air mass as being typically tropospheric or stratospheric. A quantitative understanding of the tropospheric-stratospheric exchange processes leads to better knowledge of the atmospheric impact of pollution through the development of improved simulation models of the atmosphere.

Accurate Satellite-Derived Estimates of Tropospheric Ozone Radiative Forcing

NASA Technical Reports Server (NTRS)

Joiner, Joanna; Schoeberl, Mark R.; Vasilkov, Alexander P.; Oreopoulos, Lazaros; Platnick, Steven; Livesey, Nathaniel J.; Levelt, Pieternel F.

2008-01-01

Estimates of the radiative forcing due to anthropogenically-produced tropospheric O3 are derived primarily from models. Here, we use tropospheric ozone and cloud data from several instruments in the A-train constellation of satellites as well as information from the GEOS-5 Data Assimilation System to accurately estimate the instantaneous radiative forcing from tropospheric O3 for January and July 2005. We improve upon previous estimates of tropospheric ozone mixing ratios from a residual approach using the NASA Earth Observing System (EOS) Aura Ozone Monitoring Instrument (OMI) and Microwave Limb Sounder (MLS) by incorporating cloud pressure information from OMI. Since we cannot distinguish between natural and anthropogenic sources with the satellite data, our estimates reflect the total forcing due to tropospheric O3. We focus specifically on the magnitude and spatial structure of the cloud effect on both the shortand long-wave radiative forcing. The estimates presented here can be used to validate present day O3 radiative forcing produced by models.

Impact of Flow-Dependent Error Correlations and Tropospheric Chemistry on Assimilated Ozone

NASA Technical Reports Server (NTRS)

Wargan, K.; Stajner, I.; Hayashi, H.; Pawson, S.; Jones, D. B. A.

2003-01-01

The presentation compares different versions of a global three-dimensional ozone data assimilation system developed at NASA's Data Assimilation Office. The Solar Backscatter Ultraviolet/2 (SBUV/2) total and partial ozone column retrievals are the sole data assimilated in all of the experiments presented. We study the impact of changing the forecast error covariance model from a version assuming static correlations with a one that captures a short-term Lagrangian evolution of those correlations. This is further combined with a study of the impact of neglecting the tropospheric ozone production, loss and dry deposition rates, which are obtained from the Harvard GEOS-CHEM model. We compare statistical characteristics of the assimilated data and the results of validation against independent observations, obtained from WMO balloon-borne sondes and the Polar Ozone and Aerosol Measurement (POAM) III instrument. Experiments show that allowing forecast error correlations to evolve with the flow results in positive impact on assimilated ozone within the regions where data were not assimilated, particularly at high latitudes in both hemispheres. On the other hand, the main sensitivity to tropospheric chemistry is in the Tropics and sub-Tropics. The best agreement between the assimilated ozone and the in-situ sonde data is in the experiment using both flow-dependent error covariances and tropospheric chemistry.

Estimating tropospheric phase delay in SAR interferograms using Global Atmospheric Models

NASA Astrophysics Data System (ADS)

Doin, M.; Lasserre, C.; Peltzer, G.; Cavalie, O.; Doubre, C.

2008-12-01

The main limiting factor on the accuracy of Interferometric SAR (InSAR) measurements comes from phase propagation delays through the Earth's troposphere. The delay can be divided into a stratified component, which correlates with the topography and often dominates the tropospheric signal in InSAR data, and a turbulent component. The stratified delay can be expressed as a function of atmospheric pressure P, temperature T, and water vapor partial pressure e vertical profiles. We compare the stratified delay computed using results from global atmospheric models with the topography-dependent signal observed in interferograms covering three test areas in different geographic and climatic environments: Lake Mead, Nevada, USA, the Haiyuan fault area, Gansu, China, and Afar, Republic of Djibouti. For each site we compute a multi-year series of interferograms. The phase-elevation ratio is estimated for each interferogram and the series is inverted to form a timeline of delay-elevation ratios characterizing each epoch of data acquisition. InSAR derived ratios are in good agreement with the ratios computed from global atmospheric models. This agreement shows that both estimations of the delay-elevation ratio can be used to perform a first order correction of the InSAR phase. Seasonal variations of the atmosphere significantly affect the phase delay throughout the year, aliasing the results of time series inversions using temporal smoothing or data stacking when the acquisitions are not evenly distributed in time. This is particularly critical when the spatial shape of the signal of interest correlates with topography. In the Lake Mead area, the irregular temporal sampling of our SAR data results in an interannual bias of amplitude ~2~cm on range change estimates. In the Haiyuan Fault area, the coarse and uneven data sampling results in a bias of up to ~0.5~cm/yr on the line of sight velocity across the fault. In the Afar area, the seasonal signal exceeds the deformation

Tropospheric Ozone Over North America

NASA Astrophysics Data System (ADS)

Oltmans, S. J.; Thompson, A. M.; Cooper, O. R.; Merrill, J. T.; Tarasick, D. W.; Newchurch, M. J.

2007-05-01

Ozone in the troposphere plays a significant role as an absorber of infrared radiation (greenhouse gas), in the cleansing capacity of the atmosphere as a precursor of hydroxol radical formation, and a regulated air pollutant capable of deleterious health and ecosystem effects. Knowledge of the ozone budget in the troposphere over North America (NA) is required to properly understand the various mechanisms that contribute to the measured distribution and to develop and test models capable of simulating and predicting this key player in atmospheric chemical and physical processes. Recent field campaigns including the 2004 and 2006 INTEX Ozone Network Studies (IONS) http:croc.gsfc.nasa.gov/intexb/ions06.html that have included intensive ozone profile measurements from ozonesondes provide a unique data set for describing tropospheric ozone over a significant portion of the North American continent. These campaigns have focused on the spring and summer seasons when tropospheric ozone over NA is particularly influenced by long-range transport processes, significant photochemical ozone production resulting from both anthropogenic and natural (lightning) precursor emissions, and exchange with the stratosphere. This study uses ozone profiles measured over NA in the latitude band from approximately 12-60N, extending from the tropics to the high mid latitudes, to describe the seasonal behavior of tropospheric ozone over NA with an emphasis on the spring and summer. This includes the variability within seasons at a particular site as well as the contrasts between the seasons. Emphasis is placed on the variations among the sites including latitudinal and longitudinal gradients and how these differ through the seasons and with altitude in the troposphere. Regional differences are most pronounced during the summer season likely reflecting the influence of a wider variation in processes influencing the tropospheric ozone distribution including lightning NOX production in the upper

Causes of Interannual Variability over the Southern Hemispheric Tropospheric Ozone Maximum

NASA Technical Reports Server (NTRS)

Liu, Junhua; Rodriguez, Jose M.; Steenrod, Stephen D.; Douglass, Anne R.; Logan, Jennifer A.; Olsen, Mark A.; Wargan, Krzysztog; Ziemke, Jerald R.

2017-01-01

We examine the relative contribution of processes controlling the interannual variability (IAV) of tropospheric ozone over four sub-regions of the southern hemispheric tropospheric ozone maximum (SHTOM) over a 20-year period. Our study is based on hindcast simulations from the National Aeronautics and Space Administration Global Modeling Initiative chemistry transport model (NASA GMI-CTM) of tropospheric and stratospheric chemistry, driven by assimilated Modern Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields. Our analysis shows that over SHTOM region, the IAV of the stratospheric contribution is the most important factor driving the IAV of upper tropospheric ozone (270 hectopascals), where ozone has a strong radiative effect. Over the South Atlantic region, the contribution from surface emissions to the IAV of ozone exceeds that from stratospheric input at and below 430 hectopascals. Over the South Indian Ocean, the IAV of stratospheric ozone makes the largest contribution to the IAV of ozone with little or no influence from surface emissions at 270 and 430 hectopascals in austral winter. Over the tropical South Atlantic region, the contribution from IAV of stratospheric input dominates in austral winter at 270 hectopascals and drops to less than half but is still significant at 430 hectopascals. Emission contributions are not significant at these two levels. The IAV of lightning over this region also contributes to the IAV of ozone in September and December. Over the tropical southeastern Pacific, the contribution of the IAV of stratospheric input is significant at 270 and 430 hectopascals in austral winter, and emissions have little influence.

Causes of interannual variability over the southern hemispheric tropospheric ozone maximum

NASA Astrophysics Data System (ADS)

Liu, Junhua; Rodriguez, Jose M.; Steenrod, Stephen D.; Douglass, Anne R.; Logan, Jennifer A.; Olsen, Mark A.; Wargan, Krzysztof; Ziemke, Jerald R.

2017-03-01

We examine the relative contribution of processes controlling the interannual variability (IAV) of tropospheric ozone over four sub-regions of the southern hemispheric tropospheric ozone maximum (SHTOM) over a 20-year period. Our study is based on hindcast simulations from the National Aeronautics and Space Administration Global Modeling Initiative chemistry transport model (NASA GMI-CTM) of tropospheric and stratospheric chemistry, driven by assimilated Modern Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields. Our analysis shows that over SHTOM region, the IAV of the stratospheric contribution is the most important factor driving the IAV of upper tropospheric ozone (270 hPa), where ozone has a strong radiative effect. Over the South Atlantic region, the contribution from surface emissions to the IAV of ozone exceeds that from stratospheric input at and below 430 hPa. Over the South Indian Ocean, the IAV of stratospheric ozone makes the largest contribution to the IAV of ozone with little or no influence from surface emissions at 270 and 430 hPa in austral winter. Over the tropical South Atlantic region, the contribution from IAV of stratospheric input dominates in austral winter at 270 hPa and drops to less than half but is still significant at 430 hPa. Emission contributions are not significant at these two levels. The IAV of lightning over this region also contributes to the IAV of ozone in September and December. Over the tropical southeastern Pacific, the contribution of the IAV of stratospheric input is significant at 270 and 430 hPa in austral winter, and emissions have little influence.

A Global Perspective: NASA's Prediction of Worldwide Energy Resources (POWER) Project

NASA Technical Reports Server (NTRS)

Zhang, Taiping; Stackhouse, Paul W., Jr.; Chandler, William S.; Hoell, James M.; Westberg, David; Whitlock, Charles H.

2007-01-01

The Prediction of the Worldwide Energy Resources (POWER) Project, initiated under the NASA Science Mission Directorate Applied Science Energy Management Program, synthesizes and analyzes data on a global scale that are invaluable to the renewable energy industries, especially to the solar and wind energy sectors. The POWER project derives its data primarily from NASA's World Climate Research Programme (WCRP)/Global Energy and Water cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project (Version 2.9) and the Global Modeling and Assimilation Office (GMAO) Goddard Earth Observing System (GEOS) assimilation model (Version 4). The latest development of the NASA POWER Project and its plans for the future are presented in this paper.

Evaluation of the Ozone Fields in NASA's MERRA-2 Reanalysis

NASA Technical Reports Server (NTRS)

Wargan, Krzysztof; Labow, Gordon; Frith, Stacey; Pawson, Steven; Livesey, Nathaniel; Partyka, Gary

2017-01-01

We describe and assess the quality of the assimilated ozone product from the Modern-Era Retrospective Analysis for Research and Applications, Version 2 (MERRA-2) produced at NASAs Global Modeling and Assimilation Office (GMAO) spanning the time period from 1980 to present. MERRA-2 assimilates partial column ozone retrievals from a series of Solar Backscatter Ultraviolet (SBUV) radiometers on NASA and NOAA spacecraft between January 1980 and September 2004; starting in October 2004 retrieved ozone profiles from the Microwave Limb Sounder (MLS) and total column ozone from the Ozone Monitoring Instrument on NASAs EOS Aura satellite are assimilated. We compare the MERRA-2 ozone with independent satellite and ozonesonde data focusing on the representation of the spatial and temporal variability of stratospheric and upper tropospheric ozone and on implications of the change in the observing system from SBUV to EOS Aura. The comparisons show agreement within 10 (standard deviation of the difference) between MERRA-2 profiles and independent satellite data in most of the stratosphere. The agreement improves after 2004 when EOS Aura data are assimilated. The standard deviation of the differences between the lower stratospheric and upper tropospheric MERRA-2 ozone and ozonesondes is 11.2 and 24.5, respectively, with correlations of 0.8 and above, indicative of a realistic representation of the near-tropopause ozone variability in MERRA-2. The agreement improves significantly in the EOS Aura period, however MERRA-2 is biased low in the upper troposphere with respect to the ozonesondes. Caution is recommended when using MERRA-2 ozone for decadal changes and trend studies.

Evaluation of the Ozone Fields in NASA's MERRA-2 Reanalysis.

PubMed

Wargan, Krzysztof; Labow, Gordon; Frith, Stacey; Pawson, Steven; Livesey, Nathaniel; Partyka, Gary

2017-04-01

We describe and assess the quality of the assimilated ozone product from the Modern-Era Retrospective Analysis for Research and Applications, Version 2 (MERRA-2) produced at NASA's Global Modeling and Assimilation Office (GMAO) spanning the time period from 1980 to present. MERRA-2 assimilates partial column ozone retrievals from a series of Solar Backscatter Ultraviolet (SBUV) radiometers on NASA and NOAA spacecraft between January 1980 and September 2004; starting in October 2004 retrieved ozone profiles from the Microwave Limb Sounder (MLS) and total column ozone from the Ozone Monitoring Instrument on NASA's EOS Aura satellite are assimilated. We compare the MERRA-2 ozone with independent satellite and ozonesonde data focusing on the representation of the spatial and temporal variability of stratospheric and upper tropospheric ozone and on implications of the change in the observing system from SBUV to EOS Aura. The comparisons show agreement within 10 % (standard deviation of the difference) between MERRA-2 profiles and independent satellite data in most of the stratosphere. The agreement improves after 2004 when EOS Aura data are assimilated. The standard deviation of the differences between the lower stratospheric and upper tropospheric MERRA-2 ozone and ozonesondes is 11.2 % and 24.5 %, respectively, with correlations of 0.8 and above, indicative of a realistic representation of the near-tropopause ozone variability in MERRA-2. The agreement improves significantly in the EOS Aura period, however MERRA-2 is biased low in the upper troposphere with respect to the ozonesondes. Caution is recommended when using MERRA-2 ozone for decadal changes and trend studies.

NASA's Contribution to Global Space Geodesy Networks

NASA Technical Reports Server (NTRS)

Bosworth, John M.

1999-01-01

The NASA Space Geodesy program continues to be a major provider of space geodetic data for the international earth science community. NASA operates high performance Satellite Laser Ranging (SLR), Very Long Baseline Interferometry (VLBI) and Global Positioning System (GPS) ground receivers at well over 30 locations around the world and works in close cooperation with space geodetic observatories around the world. NASA has also always been at the forefront in the quest for technical improvement and innovation in the space geodesy technologies to make them even more productive, accurate and economical. This presentation will highlight the current status of NASA's networks; the plans for partnerships with international groups in the southern hemisphere to improve the geographic distribution of space geodesy sites and the status of the technological improvements in SLR and VLBI that will support the new scientific thrusts proposed by interdisciplinary earth scientists. In addition, the expanding role of the NASA Space geodesy data archive, the CDDIS will be described.

Development of a global backscatter model for NASA's laser atmospheric wind sounder

NASA Technical Reports Server (NTRS)

Bowdle, David; Collins, Laurie; Mach, Douglas; Mcnider, Richard; Song, Aaron

1992-01-01

During the Contract Period April 1, 1989, to September 30, 1992, the Earth Systems Science Laboratory (ESSL) in the Research Institute at the University of Alabama in Huntsville (UAH) conducted a program of basic research on atmospheric backscatter characteristics, leading to the development of a global backscatter model. The ESSL research effort was carried out in conjunction with the Earth System Observing Branch (ES43) at the National Aeronautics and Space Administration (NASA) Marshall Space Flight Center, as part of NASA Contract NAS8-37585 under the Atmospheric Dynamics Program at NASA Headquarters. This research provided important inputs to NASA's GLObal Backscatter Experiment (GLOBE) program, especially in the understanding of global aerosol life cycles, and to NASA's Doppler Lidar research program, especially the development program for their prospective space-based Laser Atmospheric Wind Sounder (LAWS).

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Chance, K.; Liu, X.; Suleiman, R. M.; Flittner, D. E.; Al-Saadi, J. A.; Janz, S. J.; Tempo Science Team

2013-05-01

TEMPO has been selected by NASA as the first Earth Venture Instrument. It will measure atmospheric pollution for greater North America from space using ultraviolet/visible spectroscopy. TEMPO measures from Mexico City to the Canadian tar/oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (Mexico City is measured at 1.6 km N/S by 4.5 km E/W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50%. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO makes the first tropospheric trace gas measurements from GEO, by building on the heritage of five spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed spectra, although at coarse spatial and temporal resolutions, to the precisions required for TEMPO and use retrieval algorithms developed for them by TEMPO Science Team members and currently running in operational environments. This makes TEMPO an innovative use of a well proven technique, able to produce a revolutionary

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Chance, Kelly; Liu, Xiong; Suleiman, Raid M.; Flittner, David E.; Al-Saadi, Jassim; Janz, Scott J.

2014-06-01

TEMPO, selected by NASA as the first Earth Venture Instrument, will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO measures from Mexico City to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution. TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest-cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50 %. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO makes the first tropospheric trace gas measurements from GEO, by building on the heritage of five spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed spectra, although at coarse spatial and temporal resolutions, to the precisions required for TEMPO and use retrieval algorithms developed for them by TEMPO Science Team members and currently running in operational environments. This makes TEMPO an innovative use of a well-proven technique, able to produce a revolutionary data set. TEMPO provides much of the atmospheric measurement

Troposphere Delay Raytracing Applied in VLBI Analysis

NASA Astrophysics Data System (ADS)

Eriksson, David; MacMillan, Daniel; Gipson, John

2014-12-01

Tropospheric delay modeling error is one of the largest sources of error in VLBI analysis. For standard operational solutions, we use the VMF1 elevation-dependent mapping functions derived from European Centre for Medium Range Forecasting (ECMWF) data. These mapping functions assume that tropospheric delay at a site is azimuthally symmetric. As this assumption does not reflect reality, we have instead determined the raytrace delay along the signal path through the three-dimensional troposphere refractivity field for each VLBI quasar observation. We calculated the troposphere refractivity fields from the pressure, temperature, specific humidity, and geopotential height fields of the NASA GSFC GEOS-5 numerical weather model. We discuss results using raytrace delay in the analysis of the CONT11 R&D sessions. When applied in VLBI analysis, baseline length repeatabilities were better for 70% of baselines with raytraced delays than with VMF1 mapping functions. Vertical repeatabilities were better for 2/3 of all stations. The reference frame scale bias error was 0.02 ppb for raytracing versus 0.08 ppb and 0.06 ppb for VMF1 and NMF, respectively.

HALOE Algorithm Improvements for Upper Tropospheric Sounding

NASA Technical Reports Server (NTRS)

McHugh, Martin J.; Gordley, Larry L.; Russell, James M., III; Hervig, Mark E.

1999-01-01

This report details the ongoing efforts by GATS, Inc., in conjunction with Hampton University and University of Wyoming, in NASA's Mission to Planet Earth UARS Science Investigator Program entitled "HALOE Algorithm Improvements for Upper Tropospheric Soundings." The goal of this effort is to develop and implement major inversion and processing improvements that will extend HALOE measurements further into the troposphere. In particular, O3, H2O, and CH4 retrievals may be extended into the middle troposphere, and NO, HCl and possibly HF into the upper troposphere. Key areas of research being carried out to accomplish this include: pointing/tracking analysis; cloud identification and modeling; simultaneous multichannel retrieval capability; forward model improvements; high vertical-resolution gas filter channel retrievals; a refined temperature retrieval; robust error analyses; long-term trend reliability studies; and data validation. The current (first-year) effort concentrates on the pointer/tracker correction algorithms, cloud filtering and validation, and multi-channel retrieval development. However, these areas are all highly coupled, so progress in one area benefits from and sometimes depends on work in others.

HALOE Algorithm Improvements for Upper Tropospheric Sounding

NASA Technical Reports Server (NTRS)

Thompson, Robert Earl; McHugh, Martin J.; Gordley, Larry L.; Hervig, Mark E.; Russell, James M., III; Douglass, Anne (Technical Monitor)

2001-01-01

This report details the ongoing efforts by GATS, Inc., in conjunction with Hampton University and University of Wyoming, in NASA's Mission to Planet Earth Upper Atmospheric Research Satellite (UARS) Science Investigator Program entitled 'HALOE Algorithm Improvements for Upper Tropospheric Sounding.' The goal of this effort is to develop and implement major inversion and processing improvements that will extend Halogen Occultation Experiment (HALOE) measurements further into the troposphere. In particular, O3, H2O, and CH4 retrievals may be extended into the middle troposphere, and NO, HCl and possibly HF into the upper troposphere. Key areas of research being carried out to accomplish this include: pointing/tracking analysis; cloud identification and modeling; simultaneous multichannel retrieval capability; forward model improvements; high vertical-resolution gas filter channel retrievals; a refined temperature retrieval; robust error analyses; long-term trend reliability studies; and data validation. The current (first year) effort concentrates on the pointer/tracker correction algorithms, cloud filtering and validation, and multichannel retrieval development. However, these areas are all highly coupled, so progress in one area benefits from and sometimes depends on work in others.

Tropospheric Ozone Determined from Aura OMI and MLS: Evaluation of Measurements and Comparison with the Global Modeling Initiative's Chemical Transport Model

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Chandra, S.; Duncan, B. N.; Froidevaux, L.; Bhartia, P. K.; Levelt, P. F.; Waters, J. W.

2006-01-01

Ozone measurements from the OMI and MLS instruments on board the Aura satellite are used for deriving global distributions of tropospheric column ozone (TCO). TCO is determined using the tropospheric ozone residual method which involves subtracting measurements of MLS stratospheric column ozone (SCO) from OMI total column ozone after adjusting for intercalibration differences of the two instruments using the convective-cloud differential method. The derived TCO field, which covers one complete year of mostly continuous daily measurements from late August 2004 through August 2005, is used for studying the regional and global pollution on a timescale of a few days to months. The seasonal and zonal characteristics of the observed TCO fields are also compared with TCO fields derived from the Global Modeling Initiative's Chemical Transport Model. The model and observations show interesting similarities with respect to zonal and seasonal variations. However, there are notable differences, particularly over the vast region of the Saharan desert.

Proceedings of a Workshop on Research Needs in Heterogeneous Tropospheric Chemistry

NASA Technical Reports Server (NTRS)

1983-01-01

The role of heterogeneous reactions and processes in the troposphere is critically assessed. The results of this assessment, including identification and prioritization of a number of important and scientifically tractable processes, as well as recommendations of ways in which they can be incorporated into the existing NASA tropospheric chemistry program are presented. Also presented is a detailed summary of the considerations that led to the group's recommendations.

Evaluation of the Ozone Fields in NASA's MERRA-2 Reanalysis

NASA Technical Reports Server (NTRS)

Wargan, Krzysztof; Pawson, Steven; Labow, Gordon; Frith, Stacey M.; Livesey, Nathaniel; Partyka, Gary

2017-01-01

The assimilated ozone product from the Modern-Era Retrospective Analysis for Research and Applications, Version 2 (MERRA-2), produced at NASAs Global Modeling and Assimilation Office (GMAO) is summarized. The reanalysis begins in 1980 with the use of retrieved partial-column ozone concentrations from a series of Solar Backscatter Ultraviolet Radiometer (SBUV) instruments on NASA and NOAA spacecraft. Beginning in October 2004, retrieved ozone profiles from the Microwave Limb Sounder (MLS) and total column ozone from the Ozone Monitoring Instrument (OMI) on NASAs EOS Aura satellite are assimilated. While this change in data streams does lead to a discontinuity in the assimilated ozone fields in MERRA-2, making it not useful for studies in decadal (secular) trends in ozone, this choice was made to prioritize demonstrating the value NASAs high-quality research data in the reanalysis context. The MERRA-2 ozone is compared with independent satellite and ozonesonde data, focusing on the representation of the spatial and temporal variability of stratospheric and upper-tropospheric ozone. The comparisons show agreement within 10 (standard deviation of the difference) between MERRA-2 profiles and independent satellite data in most of the stratosphere. The agreement improves after 2004, when EOS Aura data are assimilated. The standard deviation of the differences between the lower-stratospheric and upper-tropospheric MERRA-2 ozone and ozonesondes is 11.2 and 24.5, respectively, with correlations of 0.8 and above. This is indicative of a realistic representation of the UTLS ozone variability in MERRA-2. After 2004, the upper tropospheric ozone in MERRA-2 shows a low bias compared to the sondes, but the covariance with independent observations is improved compared to earlier years. Case studies demonstrate the integrity of MERRA-2 analyses in representing important features such as tropopause folds.

2-Micron Coherent Doppler Lidar Instrument Advancements for Tropospheric Wind Measurement

NASA Technical Reports Server (NTRS)

Petros, Mulugeta; Singh, U. N.; Yu, J.; Kavaya, M. J.; Koch, G.

2014-01-01

Knowledge derived from global tropospheric wind measurement is an important constituent of our overall understanding of climate behavior [1]. Accurate weather prediction saves lives and protects properties from destructions. High-energy 2-micron laser is the transmitter of choice for coherent Doppler wind detection. In addition to the eye-safety, the wavelength of the transmitter suitably matches the aerosol size in the lower troposphere. Although the technology of the 2-micron laser has been maturing steadily, lidar derived wind data is still a void in the global weather database. In the last decade, researchers at NASA Langley Research Center (LaRC) have been engaged in this endeavor, contributing to the scientific database of 2-micron lidar transmitters. As part of this effort, an in depth analysis of the physics involved in the workings of the Ho: Tm laser systems have been published. In the last few years, we have demonstrated lidar transmitter with over1Joule output energy. In addition, a large body of work has been done in characterizing new laser materials and unique crystal configurations to enhance the efficiency and output energy of the 2-micron laser systems. At present 2-micron lidar systems are measuring wind from both ground and airborne platforms. This paper will provide an overview of the advancements made in recent years and the technology maturity levels attained.

Insights into Tropical Tropospheric Ozone from Satellite and Sonde Data

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

2003-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. The data reside at: http://code916.gsfc.nasa.gov/Data_services/shadoz. SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this. In addition to leading the SHADOZ network, we have been producing near-real tropical tropospheric ozone ('TTO') data from the Total Ozone Mapping Spectrometer (TOMS) since 1997 with Prof. Hudson and students at the University of Maryland: http://metosrv2.umd.edu/tropo. Further perspective on the complexity of tropospheric ozone variability is shown using satellite observations.

GEM-AC, a stratospheric-tropospheric global and regional model for air quality and climate change: evaluation of gas phase properties

NASA Astrophysics Data System (ADS)

Kaminski, J. W.; Semeniuk, K.; McConnell, J. C.; Lupu, A.; Mamun, A.

2012-12-01

The Global Environmental Multiscale model for Air Quality and climate change (GEM-AC) is a global general circulation model based on the GEM model developed by the Meteorological Service of Canada for operational weather forecasting. It can be run with a global uniform (GU) grid or a global variable (GV) grid where the core has uniform grid spacing and the exterior grid expands. With a GV grid high resolution regional runs can be accomplished without a concern for boundary conditions. The work described here uses GEM version 3.3.2. The gas-phase chemistry consists in detailed reactions of Ox, NOx, HOx, CO, CH4, NMVOCs, halocarbons, ClOx and BrO. We have recently added elements of the Global Modal-aerosol eXtension (GMXe) scheme to address aerosol microphysics and gas-aerosol partitioning. The evaluation of the MESSY GMXe aerosol scheme is addressed in another poster. The Canadian aerosol module (CAM) is also available. Tracers are advected using the semi-Lagrangian scheme native to GEM. The vertical transport includes parameterized subgrid scale turbulence and large scale convection. Dry deposition is implemented as a flux boundary condition in the vertical diffusion equation. For climate runs the GHGs CO2, CH4, N2O, CFCs in the radiation scheme are adjusted to the scenario considered. In GV regional mode at high resolutions a lake model, FLAKE is also included. Wet removal comprises both in-cloud and below-cloud scavenging. With the gas phase chemistry the model has been run for a series of ten year time slices on a 3°×3° global grid with 77 hybrid levels from the surface to 0.15 hPa. The tropospheric and stratospheric gas phase results are compared with satellite measurements including, ACE, MIPAS, MOPITT, and OSIRIS. Current evaluations of the ozone field and other stratospheric fields are encouraging and tropospheric lifetimes for CH4 and CH3CCl3 are in reasonable accord with tropospheric models. We will present results for current and future climate

Troc: a proposed tropospheric sounder for chemistry and climate

NASA Astrophysics Data System (ADS)

Camy-Peyret, C.

TROC has been submitted to ESA in the last call for proposals of the Earth Explorer Opportunity Missions and its focus is on tropospheric composition and chemistry-climate interactions. The mission objectives of TROC cover four research subjects. Global tropospheric chemistry: perform global measurements from space of tropospheric composition in order to improve our understanding and to constrain models of tropospheric chemistry with emphasis on tropospheric ozone. Pollution: establish the impact of mega cities of industrialised or developing countries by monitoring their pollution plumes. Biomass burning: monitor the chemical species and aerosols injected in the free troposphere during major burning episodes in the intertropical region as well as by major forest fires at other latitudes. Chemistry-climate interactions: quantify on a global scale the distributions and the sources of greenhouse gases like CO2, CH4, O3, N2O and the CFCs. Contribute to demonstration studies for monitoring from space how Montreal and Kyoto protocols are enforced as far as human impacts on atmospheric chemistry and climate are concerned. To fulfil these objectives, passive remote sensing of the troposphere has been selected as the best compromise between technical maturity and multi-species coverage. The main elements of TROC are a Fourier transform infrared (FTIR) instrument and an ultraviolet-visible (UV-vis) spectrometer, both operating in the downward-looking geometry with a 10 km diameter footprint at nadir. An ``intelligent'' pointing mirror coupled to an infrared imager is used to optimise day/night sounding down to the surface. The FTIR instrument covers at 0.1 cm-1 apodised spectral resolution 3 bands from 14 to 3.3 μ m in thermal emission and one band in solar reflected light around 2.3 μ m. The UV-vis instrument covers the regions 290-490 nm (1 nm resolution) and 520-1030 nm (2.5 nm resolution) with 43 array detectors (2 bands × 2 polarizations) in reflected

Halogens and the Chemistry of the Free Troposphere

NASA Technical Reports Server (NTRS)

Lary, David John

2004-01-01

The role of halogens in both the marine boundary layer and the stratosphere has long been recognized, while their role in the free troposphere is often not considered in global chemical models. However, a careful examination of free-tropospheric chemistry constrained by observations using a full chemical data assimilation system shows that halogens do play a significant role in the free troposphere. In particular, the chlorine initiation of methane oxidation in the free troposphere can contribute more than 10%, and in some regions up to 50%, of the total rate of initiation. The initiation of methane oxidation by chlorine is particularly important below the polar vortex and in northern mid-latitudes. Likewise, the hydrolysis of BrONO2 alone can contribute more than 35% of the HNO3 production rate in the free-troposphere.

High Temporal Resolution Tropospheric Wind Profile Observations at NASA Kennedy Space Center during Hurricane Irma

NASA Technical Reports Server (NTRS)

Decker, Ryan K.; Barbre, Robert E., Jr.; Huddleston, Lisa; Brauer, Thomas; Wilfong, Timothy

2018-01-01

The National Aeronautics and Space Administration's (NASA) Kennedy Space Center (KSC) operates a 48-MHz Tropospheric/Stratospheric Doppler Radar Wind Profiler (TDRWP) on a continual basis generating wind profiles between 2-19 km (approximately 6.6-62.3 kft) in the support of space launch vehicle operations. A benefit of the continual operability of the system is the ability to provide unique observations of severe weather events such as hurricanes. On the evening of 10 September 2017, Hurricane Irma passed within 160 km (87 nmi) to the west of KSC through the middle of the Florida peninsula. The hurricane was responsible for power outages to approximately 2/3 of Florida's population (Stein, 2017). This paper will provide an overview of the TDRWP system, describe the characteristics of the wind observations from the TDRWP during Irma passage, provide a comparison to previous TDRWP observations from Hurricane Matthew in 2016, and provide the location where TDRWP data is available to the meteorological community.

Intercomparison among tropospheric ozone and nitrogen dioxide data obtained by satellite- and ground-based measurements

NASA Astrophysics Data System (ADS)

Noguchi, K.; Urita, N.; Ohta, E.; Hayashida, S.; Richter, A.; Burrows, J. P.; Liu, X.; Chance, K.; Ziemke, J. R.

2005-12-01

Rapid economical growth and industrial development in East Asian regions are causing serious air pollution. The influence of such air pollution is not limited to a local scale but reaches an intercontinental or hemispheric scale. Satellite-borne observations can monitor the behaviors of air pollutants in a global scale for long periods with a single instrument. In particular, ozone and nitrogen dioxide in the troposphere have a crucial role in air pollution, and many studies have tried to derive those species. Recently, instrumentations and retrieval techniques have made a lot of progress in measurements of tropospheric constituents. However, tropospheric observations from space need careful validation because of difficulties in detecting signals from the lower atmosphere through the middle atmosphere. In the present study, we intercompare the tropospheric ozone and nitrogen dioxide data obtained by satellite- and ground-based measurements in order to validate the satellite measurements. For the validation of tropospheric ozone, we utilize ozonesonde data provided by WOUDC, and three satellite-borne data (Tropospheric Ozone Residual (TOR), Cloud Slicing, and GOME) are intercompared. For nitrogen dioxide, we compare GOME observations with ground-based air monitoring measurements in Japan which are operationally conducted by the Ministry of the Environment Japan. This study demonstrates the validity and potential of those satellite datasets to apply for quantitative analysis of dispersion of air pollutants and their chemical lifetime. Acknowledgments. TOR data is provided by J. Fishman via http://asd-www.larc.nasa.gov/TOR/data.html. The ground observation data of nitrogen dioxide over Japan is provided by National Institute for Environmental Studies (NIES) under the collaboration study with NIES and Nara Women's University.

Source attribution of tropospheric ozone

NASA Astrophysics Data System (ADS)

Butler, T. M.

2015-12-01

Tropospheric ozone is a harmful pollutant with adverse effects on human health and ecosystems. As well as these effects, tropospheric ozone is also a powerful greenhouse gas, with an anthropogenic radiative forcing one quarter of that of CO2. Along with methane and atmospheric aerosol, tropospheric ozone belongs to the so-called Short Lived Climate forcing Pollutants, or SLCP. Recent work has shown that efforts to reduce concentrations of SLCP in the atmosphere have the potential to slow the rate of near-term climate change, while simultaneously improving public health and reducing crop losses. Unlike many other SLCP, tropospehric ozone is not directly emitted, but is instead influenced by two distinct sources: transport of air from the ozone-rich stratosphere; and photochemical production in the troposphere from the emitted precursors NOx (oxides of nitrogen), CO (Carbon Monoxide), and VOC (volatile organic compounds, including methane). Better understanding of the relationship between ozone production and the emissions of its precursors is essential for the development of targeted emission reduction strategies. Several modeling methods have been employed to relate the production of tropospheric ozone to emissions of its precursors; emissions perturbation, tagging, and adjoint sensitivity methods all deliver complementary information about modelled ozone production. Most studies using tagging methods have focused on attribution of tropospheric ozone production to emissions of NOx, even though perturbation methods have suggested that tropospheric ozone is also sensitive to VOC, particularly methane. In this study we describe the implementation into a global chemistry-climate model of a scheme for tagging emissions of NOx and VOC with an arbitrary number of labels, which are followed through the chemical reactions of tropospheric ozone production in order to perform attribution of tropospehric ozone to its emitted precursors. Attribution is performed to both

A Decadal (2004-2014) Analysis of Global-to-Regional Tropospheric Ozone Column Trends Using GFDL-AM3 Model Simulations and OMI Observations

NASA Astrophysics Data System (ADS)

Huang, G.; Liu, X.; Lin, M.; Ziemke, J. R.; Chance, K.; Zoogman, P.; Sun, K.

2017-12-01

Tropospheric ozone is a greenhouse gas, biological irritant, and significant source of highly reactive hydroxyl radicals, which remove many hazardous trace gases from the atmosphere. The decadal trend of tropospheric ozone columns (TOCs) can be influenced by many factors including anthropogenic and natural emissions of ozone precursors, large-scale atmospheric circulation patterns, and stratosphere-to-troposphere exchange. Since 2000, anthropogenic emissions of NOx have tended to shift from North America and Europe to Asia. This rapid shift has been implicated in raising background tropospheric ozone burden. However, large meteorologically-driven ozone variability complicates the unambiguous attribution of TOC trends calculated over short periods. In this study, we examine global-to-regional TOC trends during 2004-2014 using two independent satellite retrievals from OMI SAO (Smithsonian Astrophysical Observatory) and OMI/MLS, and interpret the results with a suite of GFDL-AM3 chemistry-climate model hindcasts designed to isolate the response of ozone to anthropogenic emissions, wildfires, and meteorology. Generally, OMI SAO, OMI/MLS and GFDL-AM3 BASE simulations agree on regional hot spots of TOC trends. On the regional scale, we find strong positive TOC trends during 2004-2014 in Mid-East (0.3-0.6 DU yr-1), South Asia (0.3-0.5 DU yr-1), Southeast Asia, East Asia ( 0.1-0.6 DU yr-1) and Central Africa ( 0.6 DU yr-1). Our initial analysis indicates that meteorological variability and anthropogenic emission trends play equally important roles in the positive TOC trends in East Asia and on a global scale during 2004-2014. We are working to investigate the potential influences from lightening NOx emissions, forest fires, and the stratosphere-to-troposphere exchange.

Effects of the 2004 El Nino on Tropospheric Ozone and Water Vapor

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Schoeberl, M. R.; Froidevaux, L.; Read, W. G.; Levelt, P. F.; Bhartia, P. K.

2007-01-01

The global effects of the 2004 El Nino on tropospheric ozone and H2O based on Aura OM1 and MLS measurements are analyzed. Although it was a weak El Nino from a historical perspective, it produced significant changes in these parameters in tropical latitudes. Tropospheric ozone increased by 10-20% over most of the western Pacific region and decreased by about the same amount over the eastern Pacific region. H2O in the upper troposphere showed similar changes but with opposite sign. These zonal changes in tropospheric ozone and H2O are caused by the eastward shift in the Walker circulation in the tropical pacific region during El Nino. For the 2004 El Nino, biomass burning did not have a significant effect on the ozone budget in the troposphere unlike the 1997 El Nino. Zonally averaged tropospheric column ozone did not change significantly either globally or over the tropical and subtropical latitudes.

Troposphere-to-stratosphere transport in the tropics

NASA Astrophysics Data System (ADS)

Pommereau, Jean-Pierre

2010-04-01

The analysis of the data collected over Brazil, Northern Australia and Africa from balloons, high altitude aircraft and satellites during the recent HIBISCUS, TROCCINOX, SCOUT-O3 and AMMA European campaigns, has led to significant revision in the understanding of troposphere-to-stratosphere transport. Repeated observations of strong updrafts of adiabatically cooled and washed-out tropospheric air rich in chemical and greenhouse gases by convective overshooting over the three continents, demonstrate the high frequency of occurrence of such events in contrast to their generally assumed scarcity. Moreover, global scale information provided by ODIN and CALIPSO satellite observations suggests that the mechanism could play a major, if not dominant, role in troposphere-to-stratosphere transport in contrast to the generally evoked slow ascent by radiative heating. Ignored by global scale models because of their limited extension and duration, convective overshootings might have a significant impact on the chemistry and climate of the stratosphere.

Tropospheric and ionospheric media calibrations based on global navigation satellite system observation data

NASA Astrophysics Data System (ADS)

Feltens, Joachim; Bellei, Gabriele; Springer, Tim; Kints, Mark V.; Zandbergen, René; Budnik, Frank; Schönemann, Erik

2018-06-01

Context: Calibration of radiometric tracking data for effects in the Earth atmosphere is a crucial element in the field of deep-space orbit determination (OD). The troposphere can induce propagation delays in the order of several meters, the ionosphere up to the meter level for X-band signals and up to tens of meters, in extreme cases, for L-band ones. The use of media calibrations based on Global Navigation Satellite Systems (GNSS) measurement data can improve the accuracy of the radiometric observations modelling and, as a consequence, the quality of orbit determination solutions. Aims: ESOC Flight Dynamics employs ranging, Doppler and delta-DOR (Delta-Differential One-Way Ranging) data for the orbit determination of interplanetary spacecraft. Currently, the media calibrations for troposphere and ionosphere are either computed based on empirical models or, under mission specific agreements, provided by external parties such as the Jet Propulsion Laboratory (JPL) in Pasadena, California. In order to become independent from external models and sources, decision fell to establish a new in-house internal service to create these media calibrations based on GNSS measurements recorded at the ESA tracking sites and processed in-house by the ESOC Navigation Support Office with comparable accuracy and quality. Methods: For its concept, the new service was designed to be as much as possible depending on own data and resources and as less as possible depending on external models and data. Dedicated robust and simple algorithms, well suited for operational use, were worked out for that task. This paper describes the approach built up to realize this new in-house internal media calibration service. Results: Test results collected during three months of running the new media calibrations in quasi-operational mode indicate that GNSS-based tropospheric corrections can remove systematic signatures from the Doppler observations and biases from the range ones. For the ionosphere, a

DIAL Measurements of Free-Tropospheric Ozone Profiles in Huntsville, AL

NASA Technical Reports Server (NTRS)

Kuang, Shi; Burris, John; Newchurch, Michael J.; Johnson, Steve

2007-01-01

A tropospheric ozone Differential Absorption Lidar (DIAL) system, developed jointly by NASA and the University of Alabama at Huntsville (UAH), measures free-tropospheric ozone profiles between 4-10 km. Located at 192 meters altitude in the Regional Atmospheric Profiling Laboratory for Discovery (RAPCD) on the UAH campus in Huntsville, AL, USA, this tropospheric ozone lidar operates under both daytime and nighttime conditions. Frequent coincident ozonesonde flights and theoretical calculations provide evidence to indicate the retrieval accuracy ranges from better than 8% at 4km to 40%-60% at 10 kin with 750-m vertical resolution and 30-minute integration. With anticipated improvements to allow retrievals at both higher and lower altitudes, this ozone lidar, along with co-located aerosol and Doppler Wind Lidars, will provide a unique 18 dataset for investigations of PBL and free-tropospheric chemical and dynamic processes.

Role of Climate Change in Global Predictions of Future Tropospheric Ozone and Aerosols

NASA Technical Reports Server (NTRS)

Liao, Hong; Chen, Wei-Ting; Seinfeld, John H.

2006-01-01

A unified tropospheric chemistry-aerosol model within the Goddard Institute for Space Studies general circulation model II is applied to simulate an equilibrium CO2-forced climate in the year 2100 to examine the effects of climate change on global distributions of tropospheric ozone and sulfate, nitrate, ammonium, black carbon, primary organic carbon, secondary organic carbon, sea salt, and mineral dust aerosols. The year 2100 CO2 concentration as well as the anthropogenic emissions of ozone precursors and aerosols/aerosol precursors are based on the Intergovernmental Panel on Climate Change Special Report on Emissions Scenarios (SRES) A2. Year 2100 global O3 and aerosol burdens predicted with changes in both climate and emissions are generally 5-20% lower than those simulated with changes in emissions alone; as exceptions, the nitrate burden is 38% lower, and the secondary organic aerosol burden is 17% higher. Although the CO2-driven climate change alone is predicted to reduce the global O3 concentrations over or near populated and biomass burning areas because of slower transport, enhanced biogenic hydrocarbon emissions, decomposition of peroxyacetyl nitrate at higher temperatures, and the increase of O3 production by increased water vapor at high NOx levels. The warmer climate influences aerosol burdens by increasing aerosol wet deposition, altering climate-sensitive emissions, and shifting aerosol thermodynamic equilibrium. Climate change affects the estimates of the year 2100 direct radiative forcing as a result of the climate-induced changes in burdens and different climatological conditions; with full gas-aerosol coupling and accounting for ozone and direct radiative forcings by the O2, sulfate, nitrate, black carbon, and organic carbon are predicted to be +0.93, -0.72, -1.0, +1.26, and -0.56 W m(exp -2), respectively, using present-day climate and year 2100 emissions, while they are predicted to be +0.76, -0.72, 0.74, +0.97, and -0.58 W m(exp -2

The Tropospheric Ozone Assessment Report (TOAR): A community-wide effort to quantify tropospheric ozone in a rapidly changing world

NASA Astrophysics Data System (ADS)

Cooper, O. R.; Schultz, M.; Paoletti, E.; Galbally, I. E.; Naja, M. K.; Tarasick, D. W.; Evans, M. J.; Thompson, A. M.

2017-12-01

Tropospheric ozone is a greenhouse gas and pollutant detrimental to human health and crop and ecosystem productivity. Since 1990 a large portion of the anthropogenic emissions that react in the atmosphere to produce ozone has shifted from North America and Europe to Asia. This rapid shift, coupled with limited ozone monitoring in developing nations, left scientists unable to answer the most basic questions: Which regions of the world have the greatest human and plant exposure to ozone pollution? Is ozone continuing to decline in nations with strong emissions controls? To what extent is ozone increasing in the developing world? How can the atmospheric sciences community facilitate access to the ozone metrics necessary for quantifying ozone's impact on human health and crop/ecosystem productivity? To answer these questions the International Global Atmospheric Chemistry Project (IGAC) initiated the Tropospheric Ozone Assessment Report (TOAR). With over 220 member scientists and air quality specialists from 36 nations, TOAR's mission is to provide the research community with an up-to-date scientific assessment of tropospheric ozone's global distribution and trends from the surface to the tropopause. TOAR has also built the world's largest database of surface ozone observations and generated ozone exposure and dose metrics at thousands of measurement sites around the world, freely accessible for research on the global-scale impact of ozone on climate, human health and crop/ecosystem productivity. Plots of these metrics show the regions of the world with the greatest ozone exposure for humans and crops/ecosystems, at least in areas where observations are available. The results also highlight regions where air quality is improving and where it has degraded. TOAR has also conducted the first intercomparison of tropospheric column ozone from ozonesondes and multiple satellite instruments, which provide similar estimates of the present-day tropospheric ozone burden.

Implementation of Tropospheric Emissions: Monitoring of Pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Chance, K.; Liu, X.; Suleiman, R. M.; Flittner, D. E.; Al-Saadi, J. A.; Janz, S. J.

2014-12-01

The updated status of TEMPO, as it proceeds from formulation phase into implementation phase is presented. TEMPO, the first NASA Earth Venture Instrument, will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO measures from Mexico City to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution. TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50%. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO provides much of the atmospheric measurement capability recommended for GEO-CAPE in the 2007 National Research Council Decadal Survey, Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond. GEO-CAPE is not planned for implementation this decade. However, instruments from Europe (Sentinel 4) and Asia (GEMS) will form parts of a global GEO constellation for pollution monitoring later this decade, with a major focus on intercontinental

Making NASA Earth Observing System Satellite Data Accessible to the K-12 and Citizen Scientist Communities

NASA Technical Reports Server (NTRS)

Moore, Susan W.; Phelps, Carrie S.; Chambers, Lin H.

2004-01-01

The Atmospheric Sciences Data Center (ASDC) at NASA s Langley Research Center houses over 700 data sets related to Earth s radiation budget, clouds, aerosols and tropospheric chemistry. These data sets are produced to increase academic understanding of the natural and anthropogenic perturbations that influence global climate change. The Mentoring and inquirY using NASA Data on Atmospheric and earth science for Teachers and Amateurs (MY NASA DATA) project has been established to systematically support educational activities at all levels of formal and informal education by reducing these large data holdings to microsets that will be easily explored and understood by the K-12 and the amateur scientist communities

The Altimetric Wet Tropospheric Correction: Progress Since The ERS-1 Mission

NASA Astrophysics Data System (ADS)

Eymard, L.; Obligis, E.

2006-07-01

To correct for the path delay due to humidity in the troposphere, dedicated microwave radiometers have been added to altimeters on ESA and NASA/CNES missions. This paper presents the major issues with calibration and retrieval of the wet tropospheric path d elay s ince E RS1, a s w ell a s n ew developments for in-flight monitoring, retrieval of the path delay over the open ocean and in coastal regions.

Use of an Existing Airborne Radon Data Base in the Verification of the NASA/AEAP Core Model

NASA Technical Reports Server (NTRS)

Kritz, Mark A.

1998-01-01

The primary objective of this project was to apply the tropospheric atmospheric radon (Rn222) measurements to the development and verification of the global 3-D atmospheric chemical transport model under development by NASA's Atmospheric Effects of Aviation Project (AEAP). The AEAP project had two principal components: (1) a modeling effort, whose goal was to create, test and apply an elaborate three-dimensional atmospheric chemical transport model (the NASA/AEAP Core model to an evaluation of the possible short and long-term effects of aircraft emissions on atmospheric chemistry and climate--and (2) a measurement effort, whose goal was to obtain a focused set of atmospheric measurements that would provide some of the observational data used in the modeling effort. My activity in this project was confined to the first of these components. Both atmospheric transport and atmospheric chemical reactions (as well the input and removal of chemical species) are accounted for in the NASA/AEAP Core model. Thus, for example, in assessing the effect of aircraft effluents on the chemistry of a given region of the upper troposphere, the model must keep track not only of the chemical reactions of the effluent species emitted by aircraft flying in this region, but also of the transport into the region of these (and other) species from other, remote sources--for example, via the vertical convection of boundary layer air to the upper troposphere. Radon, because of its known surface source and known radioactive half-life, and freedom from chemical production or loss, and from removal from the atmosphere by physical scavenging, is a recognized and valuable tool for testing the transport components of global transport and circulation models.

Effects of stratospheric ozone recovery on photochemistry and ozone air quality in the troposphere

NASA Astrophysics Data System (ADS)

Zhang, H.; Wu, S.; Huang, Y.; Wang, Y.

2014-04-01

There has been significant stratospheric ozone depletion since the late 1970s due to ozone-depleting substances (ODSs). With the implementation of the Montreal Protocol and its amendments and adjustments, stratospheric ozone is expected to recover towards its pre-1980 level in the coming decades. In this study, we examine the implications of stratospheric ozone recovery for the tropospheric chemistry and ozone air quality with a global chemical transport model (GEOS-Chem). With a full recovery of the stratospheric ozone, the projected increases in ozone column range from 1% over the low latitudes to more than 10% over the polar regions. The sensitivity factor of troposphere ozone photolysis rate, defined as the percentage changes in surface ozone photolysis rate for 1% increase in stratospheric ozone column, shows significant seasonal variation but is always negative with absolute value larger than one. The expected stratospheric ozone recovery is found to affect the tropospheric ozone destruction rates much more than the ozone production rates. Significant decreases in surface ozone photolysis rates due to stratospheric ozone recovery are simulated. The global average tropospheric OH decreases by 1.7%, and the global average lifetime of tropospheric ozone increases by 1.5%. The perturbations to tropospheric ozone and surface ozone show large seasonal and spatial variations. General increases in surface ozone are calculated for each season, with increases by up to 0.8 ppbv in the remote areas. Increases in ozone lifetime by up to 13% are found in the troposphere. The increased lifetimes of tropospheric ozone in response to stratospheric ozone recovery enhance the intercontinental transport of ozone and global pollution, in particular for the summertime. The global background ozone attributable to Asian emissions is calculated to increase by up to 15% or 0.3 ppbv in the Northern Hemisphere in response to the projected stratospheric ozone recovery.

NASA Global Atmospheric Sampling Program (GASP). Data report for tape VL0001. [data management and data retrieval of information from environmental surveys

NASA Technical Reports Server (NTRS)

Holdeman, J. D.; Lezberg, E. A.

1976-01-01

Atmospheric trace constituents in the upper troposphere and lower stratosphere are now being measured as part of the NASA Global Atmospheric Sampling Program (GASP), using fully automated air sampling systems on board commercial 747 aircraft in routine airline service. Measurements of atmospheric ozone and related meteorological and flight information obtained during several GASP flights in March 1975 are now available from the National Climatic Center, Asheville, North Carolina. In addition to the data from the aircraft, tropopause pressure data obtained from the National Meteorological Center (NMC) archives for the dates of the flights are included. This report is the first of a series of reports which describes the data currently available from GASP, including flight routes and dates, instrumentation, the data processing procedure used, and data tape specifications.

Tropospheric Delay from VLBI and GNSS Measurements

NASA Astrophysics Data System (ADS)

Gubanov, V. S.

2018-02-01

Using an updated version of the QUASAR software package developed at the Institute of Applied Astronomy of the Russian Academy of Sciences, we have processed the VLBI observations within the international CONT14 program (May 6-20, 2014), in which a global network of 17 stations was involved (a total of 250 000 observations). The package update concerned the optimization of data structure and the refinement of stochastic models for the random variations in wet tropospheric delay and atomic clock difference. The main goal of this paper is to compare the VLBI determinations of the tropospheric delay with its independent determinations using global navigation satellite systems (GNSS). We show that both these determinations agree well between themselves only in the case of a global analysis of the VLBI observations, where the VLBI station coordinates are also refined, along with the tropospheric delay and the clock synchronization and Earth orientation parameters. If, alternatively, the station coordinates are insufficiently accurate and are not refined from VLBI observations, then it is appropriate not to determine the tropospheric delay from these observations, but to take it from the publicly accessible independent GNSS data. However, this requires that the VLBI and GNSS techniques operate simultaneously at a common observing site. We have established the shortcomings of the universally accepted method of stabilizing the global solution associated with the absence of a criterion for choosing reference stations and radio sources. Two ways of their elimination are proposed: (i) introducing a coordinated list of weight factors for the errors in the coordinates of such stations and sources into the stabilization algorithm and (ii) adopting a coordinated list of stations and sources the refinement of whose coordinates is not required at all for a certain time.

The tropospheric emission spectrometer (TES) for the Earth Observing System (EOS)

NASA Technical Reports Server (NTRS)

Beer, R.

1992-01-01

In recent years, increasing concern has been expressed about Global Change - the natural and anthropogenic alteration of the Earth's environment involving global greenhouse warming and the associated climate change, urban and regional atmospheric pollution, acid deposition, regional increases in tropospheric zone, and the decrease in stratospheric ozone. A common theme among these problems is that they all involve those tropospheric trace gases which are fundamental to the biosphere-troposphere interaction, the chemistry of the free troposphere itself, and troposphere-stratosphere exchange. The chemical species involved all have spectral signatures within the near and mid infrared that can now be measured by advanced techniques of remote-sensing infrared spectroradiometry. Such a system is the Tropospheric Emission Spectrometer (TES), now in Phase B definition for the Earth Observing System (EOS) polar platforms. TES addresses these objectives by obtaining radiometrically calibrated, linewidth-limited spectral resolution, infrared spectra of the lower atmosphere using both natural thermal emission and reflected sunlight (where appropriate) in three different, but fully programmable, modes: a gobal mode, a pointed mode, and a limb-viewing mode. The goals of TES, its instrumentation, operational modes, sensitivity and data handling are discussed.

Precise estimation of tropospheric path delays with GPS techniques

NASA Technical Reports Server (NTRS)

Lichten, S. M.

1990-01-01

Tropospheric path delays are a major source of error in deep space tracking. However, the tropospheric-induced delay at tracking sites can be calibrated using measurements of Global Positioning System (GPS) satellites. A series of experiments has demonstrated the high sensitivity of GPS to tropospheric delays. A variety of tests and comparisons indicates that current accuracy of the GPS zenith tropospheric delay estimates is better than 1-cm root-mean-square over many hours, sampled continuously at intervals of six minutes. These results are consistent with expectations from covariance analyses. The covariance analyses also indicate that by the mid-1990s, when the GPS constellation is complete and the Deep Space Network is equipped with advanced GPS receivers, zenith tropospheric delay accuracy with GPS will improve further to 0.5 cm or better.

Tropospheric Emission Spectrometer and Airborne Emission Spectrometer

NASA Technical Reports Server (NTRS)

Glavich, T.; Beer, R.

1996-01-01

The Tropospheric Emission Spectrometer (TES) is an instrument being developed for the NASA Earth Observing System Chemistry Platform. TES will measure the distribution of ozone and its precursors in the lower atmosphere. The Airborne Emission Spectrometer (AES) is an aircraft precursor to TES. Applicable descriptions are given of instrument design, technology challenges, implementation and operations for both.

Impacts of stratospheric sulfate geoengineering on tropospheric ozone

NASA Astrophysics Data System (ADS)

Xia, Lili; Nowack, Peer J.; Tilmes, Simone; Robock, Alan

2017-10-01

A range of solar radiation management (SRM) techniques has been proposed to counter anthropogenic climate change. Here, we examine the potential effects of stratospheric sulfate aerosols and solar insolation reduction on tropospheric ozone and ozone at Earth's surface. Ozone is a key air pollutant, which can produce respiratory diseases and crop damage. Using a version of the Community Earth System Model from the National Center for Atmospheric Research that includes comprehensive tropospheric and stratospheric chemistry, we model both stratospheric sulfur injection and solar irradiance reduction schemes, with the aim of achieving equal levels of surface cooling relative to the Representative Concentration Pathway 6.0 scenario. This allows us to compare the impacts of sulfate aerosols and solar dimming on atmospheric ozone concentrations. Despite nearly identical global mean surface temperatures for the two SRM approaches, solar insolation reduction increases global average surface ozone concentrations, while sulfate injection decreases it. A fundamental difference between the two geoengineering schemes is the importance of heterogeneous reactions in the photochemical ozone balance with larger stratospheric sulfate abundance, resulting in increased ozone depletion in mid- and high latitudes. This reduces the net transport of stratospheric ozone into the troposphere and thus is a key driver of the overall decrease in surface ozone. At the same time, the change in stratospheric ozone alters the tropospheric photochemical environment due to enhanced ultraviolet radiation. A shared factor among both SRM scenarios is decreased chemical ozone loss due to reduced tropospheric humidity. Under insolation reduction, this is the dominant factor giving rise to the global surface ozone increase. Regionally, both surface ozone increases and decreases are found for both scenarios; that is, SRM would affect regions of the world differently in terms of air pollution. In conclusion

Tropical Tropospheric Ozone: New Insights from Remote Sensing, Sondes and Field Studies

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

1999-01-01

This talk will summarize our recent research in tropical tropospheric ozone studies in the field and from space. New tropospheric ozone and aerosol products from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument will be highlighted (Hudson and Thompson, 1998; Thompson and Hudson, 1999). These are suitable for studying processes like ozone pollution resulting from biomass fires, seasonal and interannual variations and trends. Archived maps of tropospheric ozone over the tropics, from the Nimbus 7 observing period (1979-1992) are available in digital form at our website: http://metosrv2.umd.edu/-tropo. Real-time processing of TOMS data has produced images of tropical tropospheric ozone (TTO) since early 1997, using Earth-Probe TOMS; these maps are also available on the homepage. The need for validation data for TTO maps has led to establishment of the NASA/NOAA-sponsored SHADOZ (Southern Hemisphere Additional Ozonesondes) network, from which a 2-year record of high-quality ozonesonde data can be obtained: (http://hyperion.gsfc.nasa.gov/Data-services/Shadoz/shadoz-hmpg2.htrnl). Examples will be shown, along with ozonesondes from the January-February 1999 Aerosols-99 cruise of the R/V Ronald H Brown from Virginia to Cape Town, South Africa.

Low to middle tropospheric profiles and biosphere/troposphere fluxes of acidic gases in the summertime Canadian taiga

NASA Technical Reports Server (NTRS)

Klemm, O.; Talbot, R. W.; Fitzgerald, D. R.; Klemm, K. I.; Lefer, B. L.

1994-01-01

We report features of acidic gases in the troposphere from 9 to 5000 m altitude above ground over the Canadian taiga in the summer of 1990. The measurements were conducted at a 30-m meteorological tower and from the NASA Wallops Electra aircraft as part of the joint U.S.-Canadian Arctic Boundary Layer Expedition (ABLE) 3B Northern Wetland Studies (NOWES). We sampled air for acidic gases using the mist chamber collector coupled with subsequent analysis using ion chromatography. At the tower we collected samples at two heights during a 13-day period, including diurnal studies. Using eddy flux and profile data, we estimated the biosphere/troposphere fluxes of nitric, formic, and acetic acids and sulfur dioxide. For the organic acids, emissions from the taiga in the afternoon hours and deposition during the predawn morning hours were observed. The flux intensities alone were however not high enough to explain the observed changes in mixing ratios. The measured deposition fluxes of nitric acid were high enough to have a significant influence on its mixing ratio in the boundary layer. On three days we measured vertical profiles of nitric, formic, and acetic acids through the lower to midtroposphere. We found that the chemical composition of the troposphere was extremely heterogenous. Pronounced layers of polluted air were readily apparent from our measurements. Local photochemical production and episodic long-range transport of trace components, originating from biomass burning and possibly industrial emissions, appear to have a strong influence on the composition of the troposphere and biosphere/troposphere fluxes of acidic gases at this site.

Simulation of Aerosols and Chemistry with a Unified Global Model

NASA Technical Reports Server (NTRS)

Chin, Mian

2004-01-01

This project is to continue the development of the global simulation capabilities of tropospheric and stratospheric chemistry and aerosols in a unified global model. This is a part of our overall investigation of aerosol-chemistry-climate interaction. In the past year, we have enabled the tropospheric chemistry simulations based on the GEOS-CHEM model, and added stratospheric chemical reactions into the GEOS-CHEM such that a globally unified troposphere-stratosphere chemistry and transport can be simulated consistently without any simplifications. The tropospheric chemical mechanism in the GEOS-CHEM includes 80 species and 150 reactions. 24 tracers are transported, including O3, NOx, total nitrogen (NOy), H2O2, CO, and several types of hydrocarbon. The chemical solver used in the GEOS-CHEM model is a highly accurate sparse-matrix vectorized Gear solver (SMVGEAR). The stratospheric chemical mechanism includes an additional approximately 100 reactions and photolysis processes. Because of the large number of total chemical reactions and photolysis processes and very different photochemical regimes involved in the unified simulation, the model demands significant computer resources that are currently not practical. Therefore, several improvements will be taken, such as massive parallelization, code optimization, or selecting a faster solver. We have also continued aerosol simulation (including sulfate, dust, black carbon, organic carbon, and sea-salt) in the global model to cover most of year 2002. These results have been made available to many groups worldwide and accessible from the website http://code916.gsfc.nasa.gov/People/Chin/aot.html.

In-cloud oxalate formation in the global troposphere: a 3-D modeling study

NASA Astrophysics Data System (ADS)

Myriokefalitakis, S.; Tsigaridis, K.; Mihalopoulos, N.; Sciare, J.; Nenes, A.; Segers, A.; Kanakidou, M.

2011-01-01

Organic acids attract increasing attention as contributors to atmospheric acidity, secondary organic aerosol mass and aerosol hygroscopicity. Oxalic acid is globally the most abundant dicarboxylic acid, formed via chemical oxidation of gas-phase precursors in the aqueous phase of aerosols and droplets. Its lifecycle and atmospheric global distribution remain highly uncertain and are the focus of this study. The first global spatial and temporal distribution of oxalate, simulated using a state-of-the-art aqueous phase chemical scheme embedded within the global 3-dimensional chemistry/transport model TM4-ECPL, is here presented. The model accounts for comprehensive gas-phase chemistry and its coupling with major aerosol constituents (including secondary organic aerosol). Model results are consistent with ambient observations of oxalate at rural and remote locations (slope = 0.83 ± 0.06, r2 = 0.67, N = 106) and suggest that aqueous phase chemistry contributes significantly to the global atmospheric burden of secondary organic aerosol. In TM4-ECPL most oxalate is formed in-clouds and less than 10% is produced in aerosol water. About 61% of the oxalate is removed via wet deposition, 35% by in-cloud reaction with hydroxyl radical and 4% by dry deposition. The global oxalate net chemical production is calculated to be about 17-27 Tg yr-1 with almost 91% originating from biogenic hydrocarbons, mainly isoprene. This condensed phase net source of oxalate in conjunction with a global mean turnover time against deposition of about 5 days, maintain oxalate's global tropospheric burden of 0.24-0.39 Tg that is about 13-19% of calculated total organic aerosol burden.

Plant responses to tropospheric ozone

USDA-ARS?s Scientific Manuscript database

Tropospheric ozone is the second most abundant air pollutant and an important component of the global climate change. Over five decades of research on the phytotoxicity of ozone in model plants systems, crop plants and forest trees have provided some insight into the physiological, biochemical and m...

The role of chemistry in under-predictions of NO2 in the upper troposphere

NASA Astrophysics Data System (ADS)

Henderson, B. H.; Pinder, R. W.; Goliff, W. S.; Stockwell, W. R.; Fahr, A.; Sarwar, G.; Hutzell, W. T.; Mathur, R.; Vizuete, W.; Cohen, R. C.

2009-12-01

Global and regional atmospheric models under-predict upper troposphere NO2 compared to satellite and aircraft observations. The upper tropospheric under-prediction of NO2 could be a function of emissions, transport, chemistry or some combination. Previous researchers have linked poor performance in the model to over-prediction of the OH and under-prediction of the HO2 by chemistry (Olson et al. 2006, Bertram et al. 2007). This study isolates upper tropospheric chemistry to evaluate the chemical contribution to NO2 under-predictions and to diagnose OH and HO2 discrepancies.

We use a 0-dimensional time dependent model to evaluate seven chemical mechanisms. Because chamber data representing upper tropospheric conditions does not exist, we evaluate the predictions based against an observation-based aging model. Following Bertram et al (2007), we use the NOx:HNO3 ratio to categorize the chemical age of thousands of 10 second average observations between 8 and 10km. Measurements of 10 inorganics and 32 hydrocarbons are translated to model species for each of seven chemical mechanisms. We chose mechanisms ranging from condensed to semi-explicit. The seven mechanisms' design scopes range from urban to global scale. Results include simulations from Model for OZone And Related chemical Tracers (MOZART), Carbon Bond 05 (CB05), State Air Pollution Research Center (SAPRC) 99, SAPRC 07, GEOS-Chem, Regional Atmospheric Chemical Mechanism version 2, and the LEEDS Master Chemical Mechanism.

Results from each chemical mechanism are compared to aircraft observations and to those obtained with other chemical mechanisms. Each mechanism is then further evaluated using integrated reaction rate analysis to identify sources of NO2 bias. We find that the largest contributors to the NO2 bias are over-predictions of PAN and HNO3. The formation of PAN is sensitive to the acetone photolysis rate. The conversion of NOx to HNO3 is most sensitive to hydroxyl radical

Tropospheric Bromine Chemistry: Implications for Present and Pre-industrial Ozone and Mercury

NASA Technical Reports Server (NTRS)

Parella, J. P.; Jacob, D. J.; Liang, Q.; Zhang, Y.; Mickley, L. J.; Miller, B.; Evans, M. J.; Yang, X.; Pyle, J. A.; Theys, N.;

Tropospheric delay ray tracing applied in VLBI analysis

NASA Astrophysics Data System (ADS)

Eriksson, David; MacMillan, D. S.; Gipson, John M.

2014-12-01

Tropospheric delay modeling error continues to be one of the largest sources of error in VLBI (very long baseline interferometry) analysis. For standard operational solutions, we use the VMF1 elevation-dependent mapping functions derived from European Centre for Medium-Range Weather Forecasts data. These mapping functions assume that tropospheric delay at a site is azimuthally symmetric. As this assumption is not true, we have instead determined the ray trace delay along the signal path through the troposphere for each VLBI quasar observation. We determined the troposphere refractivity fields from the pressure, temperature, specific humidity, and geopotential height fields of the NASA Goddard Space Flight Center Goddard Earth Observing System version 5 numerical weather model. When applied in VLBI analysis, baseline length repeatabilities were improved compared with using the VMF1 mapping function model for 72% of the baselines and site vertical repeatabilities were better for 11 of 13 sites during the 2 week CONT11 observing period in September 2011. When applied to a larger data set (2011-2013), we see a similar improvement in baseline length and also in site position repeatabilities for about two thirds of the stations in each of the site topocentric components.

Impacts of the large increase in international ship traffic 2000-2007 on tropospheric ozone and methane.

PubMed

Dalsøren, Stig B; Eide, Magnus S; Myhre, Gunnar; Endresen, Oyvind; Isaksen, Ivar S A; Fuglestvedt, Jan S

2010-04-01

The increase in civil world fleet ship emissions during the period 2000-2007 and the effects on key tropospheric oxidants are quantified using a global Chemical Transport Model (CTM). We estimate a substantial increase of 33% in global ship emissions over this period. The impact of ship emissions on tropospheric oxidants is mainly caused by the relatively large fraction of NOx in ship exhaust. Typical increases in yearly average surface ozone concentrations in the most impacted areas are 0.5-2.5 ppbv. The global annual mean radiative forcing due to ozone increases in the troposphere is 10 mWm(-2) over the period 2000-2007. We find global average tropospheric OH increase of 1.03% over the same period. As a result of this the global average tropospheric methane concentration is reduced by approximately 2.2% over a period corresponding to the turnover time. The resulting methane radiative forcing is -14 mWm(-2) with an additional contribution of -6 mWm(-2) from methane induced reduction in ozone. The net forcing of the ozone and methane changes due to ship emissions changes between 2000 and 2007 is -10 mWm(-2). This is significant compared to the net forcing of these components in 2000. Our findings support earlier observational studies indicating that ship traffic may be a major contributor to recent enhancement of background ozone at some coastal stations. Furthermore, by reducing global mean tropospheric methane by 40 ppbv over its turnover time it is likely to contribute to the recent observed leveling off in global mean methane concentration.

The temperature signature of an IMF-driven change to the global atmospheric electric circuit (GEC) in the Antarctic troposphere

NASA Astrophysics Data System (ADS)

Freeman, Mervyn; Lam, Mai Mai; Chisham, Gareth

2017-04-01

We use National Centers for Environmental Prediction (NCEP)/National Center for Atmospheric Research (NCAR) reanalysis data to show that Antarctic surface air temperature anomalies result from differences in the daily-mean duskward component,By, of the interplanetary magnetic field (IMF). We find the anomalies have strong geographical and seasonal variations. Regional anomalies are evident poleward of 60˚ S and are of diminishing representative peak amplitude from autumn (3.2˚ C) to winter (2.4˚ C) to spring (1.6˚ C) to summer (0.9˚ C). We demonstrate that anomalies of statistically-significant amplitude are due to geostrophic wind anomalies, resulting from the same By changes, moving air across large meridional gradients in zonal mean air temperature between 60 and 80˚ S. Additionally, we find that the mean tropospheric temperature anomaly for geographical latitudes ≤ -70˚ peaks at about 0.7 K and is statistically significant at the 1 - 5% level between air pressures of 1000 and 500 hPa (i.e., ˜0.1 to 5.6 km altitude above sea level) and for time lags with respect to the IMF of up to 7 days. The signature propagates vertically between air pressure p ≥ 850 hPa (≤ 1.5 km) and p = 500 hPa (˜5.6 km). The characteristics of prompt response and vertical propagation within the troposphere have previously been seen in the correlation between the IMF and high-latitude air pressure anomalies, known as the Mansurov effect, at higher statistical significances (1%). We conclude that we have identified the temperature signature of the Mansurov effect in the Antarctic troposphere. Since these tropospheric anomalies have been associated with By-driven anomalies in the electric potential of the ionosphere, we further conclude that they are caused by IMF-induced changes to the global atmospheric electric circuit (GEC). Our results support the view that variations in the ionospheric potential act on the troposphere via the action of resulting variations in the

Comparisons of the tropospheric specific humidity from GPS radio occultations with ERA-Interim, NASA MERRA, and AIRS data

NASA Astrophysics Data System (ADS)

Vergados, Panagiotis; Mannucci, Anthony J.; Ao, Chi O.; Verkhoglyadova, Olga; Iijima, Byron

2018-03-01

We construct a 9-year data record (2007-2015) of the tropospheric specific humidity using Global Positioning System radio occultation (GPS RO) observations from the Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) mission. This record covers the ±40° latitude belt and includes estimates of the zonally averaged monthly mean specific humidity from 700 up to 400 hPa. It includes three major climate zones: (a) the deep tropics (±15°), (b) the trade winds belts (±15-30°), and (c) the subtropics (±30-40°). We find that the RO observations agree very well with the European Centre for Medium-Range Weather Forecasts Re-Analysis Interim (ERA-Interim), the Modern-Era Retrospective Analysis for Research and Applications (MERRA), and the Atmospheric Infrared Sounder (AIRS) by capturing similar magnitudes and patterns of variability in the monthly zonal mean specific humidity and interannual anomaly over annual and interannual timescales. The JPL and UCAR specific humidity climatologies differ by less than 15 % (depending on location and pressure level), primarily due to differences in the retrieved refractivity. In the middle-to-upper troposphere, in all climate zones, JPL is the wettest of all data sets, AIRS is the driest of all data sets, and UCAR, ERA-Interim, and MERRA are in very good agreement, lying between the JPL and AIRS climatologies. In the lower-to-middle troposphere, we present a complex behavior of discrepancies, and we speculate that this might be due to convection and entrainment. Conclusively, the RO observations could potentially be used as a climate variable, but more thorough analysis is required to assess the structural uncertainty between centers and its origin.

Global and Regional Seasonal Variability of Mid-Tropospheric CO2 as Measured by the Atmospheric Infrared Sounder (AIRS)

NASA Technical Reports Server (NTRS)

Pagano, Thomas S.; Olsen, Edward T.; Nguyen, Hai

2012-01-01

The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the Earth Observing System (EOS) Aqua Spacecraft, launched on May 4, 2002 into a near polar sun-synchronous orbit. AIRS has 2378 infrared channels ranging from 3.7 ?m to 15.4 ?m and a 13.5 km footprint at nadir. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy on a global scale, as well as water vapor profiles and trace gas amounts for CO2, CO, SO2, O3 and CH4. AIRS CO2 climatologies have been shown to be useful for identifying anomalies associated with geophysical events such as El Nino-Southern Oscillation or Madden-Julian oscillation. In this study, monthly representations of mid-tropospheric CO2 are constructed from 10 years of AIRS Version 5 monthly Level 3 data. We compare the AIRS mid-tropospheric CO2 representations to ground-based measurements from the Scripps and National Oceanic and Atmospheric Administration Climate Modeling and Diagnostics Laboratory (NOAA CMDL) ground networks to better understand the phase lag of the CO2 seasonal cycle between the surface and middle troposphere. Results show only a small phase lag in the tropics that grows to approximately two months in the northern latitudes.

Application of ray-traced tropospheric slant delays to geodetic VLBI analysis

NASA Astrophysics Data System (ADS)

Hofmeister, Armin; Böhm, Johannes

2017-08-01

National Aeronautics and Space Administration Goddard Space Flight Center (NASA GSFC) (Eriksson and MacMillan in http://lacerta.gsfc.nasa.gov/tropodelays, 2016) with respect to the analysis performances in terms of BLR results. If tropospheric gradient estimation is included in the analysis, 51.3% of the baselines benefit from the RADIATE ray-traced delays at sub-mm difference level. If no tropospheric gradients are estimated within the analysis, the RADIATE ray-traced delays deliver a better BLR at 63% of the baselines compared to the NASA GSFC ray-traced delays.

Tropospheric Ozone Change from 1980 to 2010 Dominated by Equatorward Redistribution of Emissions

NASA Technical Reports Server (NTRS)

Zhang, Yuqiang; Cooper, Owen R.; Gaudel, Audrey; Thompson, Anne M.; Nedelec, Philippe; Ogino, Shin-Ya; West, J. Jason

2016-01-01

Ozone is an important air pollutant at the surface, and the third most important anthropogenic greenhouse gas in the troposphere. Since 1980, anthropogenic emissions of ozone precursors methane, non-methane volatile organic compounds, carbon monoxide and nitrogen oxides (NOx) have shifted from developed to developing regions. Emissions have thereby been redistributed equatorwards, where they are expected to have a stronger effect on the tropospheric ozone burden due to greater convection, reaction rates and NOx sensitivity. Here we use a global chemical transport model to simulate changes in tropospheric ozone concentrations from 1980 to 2010, and to separate the influences of changes in the spatial distribution of global anthropogenic emissions of short-lived pollutants, the magnitude of these emissions, and the global atmospheric methane concentration. We estimate that the increase in ozone burden due to the spatial distribution change slightly exceeds the combined influences of the increased emission magnitude and global methane. Emission increases in Southeast, East and South Asia may be most important for the ozone change, supported by an analysis of statistically significant increases in observed ozone above these regions. The spatial distribution of emissions dominates global tropospheric ozone, suggesting that the future ozone burden will be determined mainly by emissions from low latitudes.

In-cloud oxalate formation in the global troposphere: a 3-D modeling study

NASA Astrophysics Data System (ADS)

Myriokefalitakis, S.; Tsigaridis, K.; Mihalopoulos, N.; Sciare, J.; Nenes, A.; Kawamura, K.; Segers, A.; Kanakidou, M.

2011-06-01

Organic acids attract increasing attention as contributors to atmospheric acidity, secondary organic aerosol mass and aerosol hygroscopicity. Oxalic acid is globally the most abundant dicarboxylic acid, formed via chemical oxidation of gas-phase precursors in the aqueous phase of aerosols and droplets. Its lifecycle and atmospheric global distribution remain highly uncertain and are the focus of this study. The first global spatial and temporal distribution of oxalate, simulated using a state-of-the-art aqueous-phase chemical scheme embedded within the global 3-dimensional chemistry/transport model TM4-ECPL, is here presented. The model accounts for comprehensive gas-phase chemistry and its coupling with major aerosol constituents (including secondary organic aerosol). Model results are consistent with ambient observations of oxalate at rural and remote locations (slope = 1.16 ± 0.14, r2 = 0.36, N = 114) and suggest that aqueous-phase chemistry contributes significantly to the global atmospheric burden of secondary organic aerosol. In TM4-ECPL most oxalate is formed in-cloud and less than 5 % is produced in aerosol water. About 62 % of the oxalate is removed via wet deposition, 30 % by in-cloud reaction with hydroxyl radical, 4 % by in-cloud reaction with nitrate radical and 4 % by dry deposition. The in-cloud global oxalate net chemical production is calculated to be about 21-37 Tg yr-1 with almost 79 % originating from biogenic hydrocarbons, mainly isoprene. This condensed phase net source of oxalate in conjunction with a global mean turnover time against deposition of about 5 days, maintain oxalate's global tropospheric burden of 0.2-0.3 Tg, i.e. 0.05-0.1 Tg-C that is about 5-9 % of model-calculated water soluble organic carbon burden.

Laser Sounder for Global Measurement of CO2 Concentrations in the Troposphere from Space: Progress

NASA Technical Reports Server (NTRS)

Abshire, J. B.; Krainak, M.; Riris, H. J.; Sun, X.; Riris, H.; Andrews, A. E.; Collatz, J.

2004-01-01

We describe progress toward developing a laser-based technique for the remote measurement of the tropospheric CO2 concentrations from orbit. Our goal is to demonstrate a lidar technique and instrument technology that will permit measurements of the CO2 column abundance in the lower troposphere from aircraft at the few ppm level, with a capability of scaling to permit global CO2 measurements from orbit. Accurate measurements of the tropospheric CO2 mixing ratio from space are challenging due to the many potential error sources. These include possible interference from other trace gas species, the effects of temperature, clouds, aerosols & turbulence in the path, changes in surface reflectivity, and variability in dry air density caused by changes in atmospheric pressure, water vapor and topographic height. Some potential instrumental errors include frequency drifts in the transmitter, small transmission and sensitivity drifts in the instrument. High signal-to-noise ratios and measurement stability are needed for mixing ratio estimates at the few ppm level. We have been developing a laser sounder approach as a candidate for a future space mission. It utilizes multiple different laser transmitters to permit simultaneous measurement of CO2 and O2 extinction, and aerosol backscatter in the same measurement path. It directs the narrow co-aligned laser beams from the instrument's fiber lasers toward nadir, and measures the energy of the strong laser echoes reflected from the Earth's land and water surfaces. During the measurement its narrow linewidth lasers are rapidly tuned on- and off- selected CO2 line near 1572 nm and an O2 absorption line near 770 nm. The receiver measures the energies of the laser echoes from the surface and any clouds and aerosols in the path with photon counting detectors. Ratioing the on- to off-line echo pulse energies for each gas permits the column extinction and column densities of CO2 and O2 to be estimated simultaneously via the

Airborne Measurements of Nitric Oxide, Nitrogen Dioxide, Ozone, and Total Reactive Nitrogen During the NASA Global Tropospheric Experiment

NASA Technical Reports Server (NTRS)

Carroll, Mary Anne

2000-01-01

Fabrication of the University of Michigan Multichannel Chemiluminescence Instrument (UMMCI) was completed in early 1996 and the instrument participated in test flights on the NASA P3B at Wallops Island prior to integration and deployment for the PEM- Tropics A Mission. The UMMCI consists of 4 channels for simultaneous measurements of ozone and NO with the option for measurements of NO2 and NOy (total reactive nitrogen) when converters are placed upstream of the NO channels. Each NO channel consists of a zeroing volume and reaction vessel, while the ozone channel consists of an ozone catalyst (or scrubber) trap that is not in line with the reaction vessel. The detectors in all for channels are Hamamatsu photomultiplier tubes, which are followed by pulse amplifier discriminators on the NO channels and an electrometer on the ozone channel. Schematics of the Detector Module and NOx/03 Probe Insert and Diagrams of the Control and Data System, the Power and Ground System, the Gas Flow System, and the Calibration System Flow are attached. Intercomparisons were conducted with G. Gregory, NASA/Langley, during the test flights (following prior calibration of the ozone generator/calibrators at the Wallops Long-Path Absorption facility). Initial test results appeared to be reasonable, and instrument characterization studies proceeded for the ozone channel and the 3 NO channels until deployment for integration for the PEM-Tropics Mission. Ozone data was obtained for Flights #4, and 6-2 1, and finalized data was submitted to the PEM-Tropics Data Archive and to the Science Team during the April 1997 Data Workshop. Although it initially appeared that the instrument sensitivity varied, subsequent tests showed that this was the fault of a leak in the ozone calibrator. In fact; the instrument sensitivity has not been observed to vary in a large number of tests over the years since the PEM-Tropics mission. We have, therefore, a very high degree of confidence in the O3 data that we

Characteristics and Trade-Offs of Doppler Lidar Global Wind Profiling

NASA Technical Reports Server (NTRS)

Kavaya, Michael J.; Emmitt, G David

2004-01-01

Accurate, global profiling of wind velocity is highly desired by NASA, NOAA, the DOD/DOC/NASA Integrated Program Office (IPO)/NPOESS, DOD, and others for many applications such as validation and improvement of climate models, and improved weather prediction. The most promising technology to deliver this measurement from space is Doppler Wind Lidar (DWL). The NASA/NOAA Global Tropospheric Wind Sounder (GTWS) program is currently in the process of generating the science requirements for a space-based sensor. In order to optimize the process of defining science requirements, it is important for the scientific and user community to understand the nature of the wind measurements that DWL can make. These measurements are very different from those made by passive imaging sensors or by active radar sensors. The purpose of this paper is to convey the sampling characteristics and data product trade-offs of an orbiting DWL.

NASA's Earth Observations of the Global Environment

NASA Technical Reports Server (NTRS)

King, Michael D.

2005-01-01

A birds eye view of the Earth from afar and up close reveals the power and magnificence of the Earth and juxtaposes the simultaneous impacts and powerlessness of humankind. The NASA Electronic Theater presents Earth science observations and visualizations in an historical perspective. Fly in from outer space to Africa and Cape Town. See the latest spectacular images from NASA & NOAA remote sensing missions like Meteosat, TRMM, Landsat 7, and Terra, which will be visualized and explained in the context of global change. See visualizations of global data sets currently available from Earth orbiting satellites, including the Earth at night with its city lights, aerosols from biomass burning in the Middle East and Africa, and retreat of the glaciers on Mt. Kilimanjaro. See the dynamics of vegetation growth and decay over Africa over 17 years. New visualization tools allow us to roam & zoom through massive global mosaic images including Landsat and Terra tours of Africa and South America, showing land use and land cover change from Bolivian highlands. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa and across the Atlantic to the Caribbean and Amazon basin. See ocean vortexes and currents that bring up the nutrients to feed tiny phytoplankton and draw the fish, pant whales and fisher- man. See how the ocean blooms in response to these currents and El Nino/La Nifia. We will illustrate these and other topics with a dynamic theater-style presentation, along with animations of satellite launch deployments and orbital mapping to highlight aspects of Earth observations from space.

An Information NEXUS: The NASA Global Hawk Link Module

NASA Technical Reports Server (NTRS)

Sullivan, D. V.

2012-01-01

The Link Module described in this paper was first developed for the NASA Global Hawk Pacific Mission (GloPAC), four flights of 30 hour duration, supporting the Aura Validation Experiment (AVE). Its second use was during the Genesis and Rapid Intensification Processes (GRIP) experiment, a NASA Earth Science field experiment to better understand how tropical storms form and develop into major hurricanes. In these missions, the Link module negotiated all communication over the high bandwidth Ku satellite link, archived al the science data from onboard experiments in a spatially enable database, routed command and control of the instruments from the Global Hawk Operations Center, and retransmitted select data sets directly to experimenters control and analysis systems. The availability of aggregated information from collections of sensors, and remote control capabilities, in real-time, is revolutionizing the way Airborne Science is being conducted. Also described is the next generation Link Module now being designed and tested to support the NASA Earth Venture missions, the Hurricane and Severe Storm Sentinel (HS3) mission, and Airborne Tropical Tropopause Experiment (ATTREX) mission. Advanced data fusion technologies being developed will further advance the Scientific productivity, flexibility and robustness of these systems. Historically, the Link module evolved from the instrument and communication interface controller used by NASA's Pathfinder and Pathfinder plus solar powered UAS's in the late 1990's. It later was expanded for use in the AIRDAS four channel scanner flown on the NASA Altus UAS, and then again to a module in the AMS twelve channel multispectral scanner flying on the NASA (Predator-b) Ikhana UAS. The current system is the next step in the evolution, a multi board system packaged in a Curtiss Wright MIL-spec, flight qualified enclosure.

Uncertainties in models of tropospheric ozone based on Monte Carlo analysis: Tropospheric ozone burdens, atmospheric lifetimes and surface distributions

NASA Astrophysics Data System (ADS)

Derwent, Richard G.; Parrish, David D.; Galbally, Ian E.; Stevenson, David S.; Doherty, Ruth M.; Naik, Vaishali; Young, Paul J.

2018-05-01

Recognising that global tropospheric ozone models have many uncertain input parameters, an attempt has been made to employ Monte Carlo sampling to quantify the uncertainties in model output that arise from global tropospheric ozone precursor emissions and from ozone production and destruction in a global Lagrangian chemistry-transport model. Ninety eight quasi-randomly Monte Carlo sampled model runs were completed and the uncertainties were quantified in tropospheric burdens and lifetimes of ozone, carbon monoxide and methane, together with the surface distribution and seasonal cycle in ozone. The results have shown a satisfactory degree of convergence and provide a first estimate of the likely uncertainties in tropospheric ozone model outputs. There are likely to be diminishing returns in carrying out many more Monte Carlo runs in order to refine further these outputs. Uncertainties due to model formulation were separately addressed using the results from 14 Atmospheric Chemistry Coupled Climate Model Intercomparison Project (ACCMIP) chemistry-climate models. The 95% confidence ranges surrounding the ACCMIP model burdens and lifetimes for ozone, carbon monoxide and methane were somewhat smaller than for the Monte Carlo estimates. This reflected the situation where the ACCMIP models used harmonised emissions data and differed only in their meteorological data and model formulations whereas a conscious effort was made to describe the uncertainties in the ozone precursor emissions and in the kinetic and photochemical data in the Monte Carlo runs. Attention was focussed on the model predictions of the ozone seasonal cycles at three marine boundary layer stations: Mace Head, Ireland, Trinidad Head, California and Cape Grim, Tasmania. Despite comprehensively addressing the uncertainties due to global emissions and ozone sources and sinks, none of the Monte Carlo runs were able to generate seasonal cycles that matched the observations at all three MBL stations. Although

Assessment and Applications of NASA Ozone Data Products Derived from Aura OMI-MLS Satellite Measurements in Context of the GMI Chemical Transport Model

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Olsen, M. A.; Witte, J. C.; Douglass, A. R.; Strahan, S. E.; Wargan, K.; Liu, X.; Schoeberl, M. R.; Yang, K.; Kaplan, T. B.;

Concentration of Atmospheric Carbon Dioxide from Earth Mid-Troposphere, 2002 to 2013

NASA Image and Video Library

2013-05-22

This graph made with data from the AIRS instrument on NASA Aqua satellite shows the concentration of carbon dioxide in Earth mid-troposphere, located roughly between 3 to 6 miles 5 to 9 kilometers in altitude.

Tropical Tropospheric Ozone Climatology: Approaches Based on SHADOZ Observations

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacquelyn C.; Chatfield, Robert B.; Hudson, Robert D.; Andrade, Marcos; Coetzee, Geert J. R.; Posny, Francoise

2004-01-01

The SHADOZ (Southern Hemisphere Additional Ozonesondes) ozone sounding network was initiated in 1998 to improve the coverage of tropical in-situ ozone measurements for satellite validation, algorithm development and related process studies. Over 2000 soundings have been archived at the central website, nasa.gov/shadoz>, for 12 stations that span the entire equatorial zone [Thompson et al., JGR, 108,8238, 2003]. The most striking features of tropospheric ozone profiles in SHADOZ are: (1) persistent longitudinal variability in tropospheric ozone profiles, with a 10-15 DU column-integrated difference between Atlantic and Pacific sites; (2) intense short-term variability triggered by changing meteorological conditions and advection of pollution. The implications of these results for profile climatologies and trends are described along with several approaches to classifying ozone profiles: 1) Seasonal means during MAM (March-April-May) and SON (September-October-November); 2) Maxima and minima, identified through correlation of TOMS-derived TTO (tropical tropospheric ozone) column depth with the sonde integrated tropospheric ozone column; and 3) Meteorological regimes, a technique that is effective in the subtropics where tropical and mid-latitude conditions alternate.

Tropospheric Airborne Meteorological Data Reporting (TAMDAR) Sensor Development

NASA Technical Reports Server (NTRS)

Daniels, Taumi S.

2002-01-01

In response to recommendations from the National Aviation Weather Program Council, the National Aeronautics and Space Administration (NASA) is working with industry to develop an electronic pilot reporting capability for small aircraft. This paper describes the Tropospheric Airborne Meteorological Data Reporting (TAMDAR) sensor development effort. NASA is working with industry to develop a sensor capable of measuring temperature, relative humidity, magnetic heading, pressure, icing, and average turbulence energy dissipation. Users of the data include National Centers for Environmental Prediction (NCEP) forecast modelers, air traffic controllers, flight service stations, airline operation centers, and pilots. Preliminary results from flight tests are presented.

Tropospheric delays from GNSS for application in coastal altimetry

NASA Astrophysics Data System (ADS)

Fernandes, M. Joana; Pires, Nelson; Lázaro, Clara; Nunes, Alexandra L.

2013-04-01

In the scope of the development of an improved methodology for the computation of the wet tropospheric correction for coastal altimetry, based on the use of tropospheric delays derived from GNSS (Global Navigation Satellite Systems), various studies have been conducted aiming to improve the estimation, at global scale, of GNSS-derived tropospheric delays.Amongst these studies, two are presented in this paper: (1) a global assessment of zenith total delays (ZTD) determined at international data centres such as EPN (EUREF Permanent Network) and IGS (International GNSS Service) by comparison with ZTD solutions computed at the University of Porto (U.Porto) using state-of-the-art methodologies and ZTD estimated from ERA Interim, the latest reanalysis dataset from ECMWF (European Centre for Medium-Range Weather Forecasts), (2) evaluation of the accuracy of the hydrostatic component of the tropospheric delay (zenith hydrostatic delay, ZHD) estimation from different sources of surface pressure.When compared with ERA Interim, both IGS and U.Porto ZTD are homogeneous with a mean standard deviation of the differences, for all analysed sites, of 12 mm. The U.Porto and IGS ZTD agree within 4 mm (1σ), while for EPN the same result is only valid for the period after November 2006. Before that date, the EPN solutions are slightly degraded and require an adequate correction.Aiming to evaluate the accuracy of ZHD determination from various sources of atmospheric pressure, a study is presented that compares ZHD values determined with in situ measurements of surface pressure at a global set of 63 coastal barometric sites (GNSS stations), the corresponding values obtained from ECMWF operational model, ERA Interim sea level pressure (SLP) and ZHD from the Vienna Mapping Functions 1 (VMF1).Results show that the global grids of sea level pressure provided by ECMWF operational model, either at 0.25° or 0.125° spacing, or the ERA Interim reanalysis product at 1.5°, allow the estimation

Subtropical subsidence and surface deposition of oxidized mercury produced in the free troposphere

NASA Astrophysics Data System (ADS)

Shah, Viral; Jaeglé, Lyatt

2017-07-01

Oxidized mercury (Hg(II)) is chemically produced in the atmosphere by oxidation of elemental mercury and is directly emitted by anthropogenic activities. We use the GEOS-Chem global chemical transport model with gaseous oxidation driven by Br atoms to quantify how surface deposition of Hg(II) is influenced by Hg(II) production at different atmospheric heights. We tag Hg(II) chemically produced in the lower (surface-750 hPa), middle (750-400 hPa), and upper troposphere (400 hPa-tropopause), in the stratosphere, as well as directly emitted Hg(II). We evaluate our 2-year simulation (2013-2014) against observations of Hg(II) wet deposition as well as surface and free-tropospheric observations of Hg(II), finding reasonable agreement. We find that Hg(II) produced in the upper and middle troposphere constitutes 91 % of the tropospheric mass of Hg(II) and 91 % of the annual Hg(II) wet deposition flux. This large global influence from the upper and middle troposphere is the result of strong chemical production coupled with a long lifetime of Hg(II) in these regions. Annually, 77-84 % of surface-level Hg(II) over the western US, South America, South Africa, and Australia is produced in the upper and middle troposphere, whereas 26-66 % of surface Hg(II) over the eastern US, Europe, and East Asia, and South Asia is directly emitted. The influence of directly emitted Hg(II) near emission sources is likely higher but cannot be quantified by our coarse-resolution global model (2° latitude × 2.5° longitude). Over the oceans, 72 % of surface Hg(II) is produced in the lower troposphere because of higher Br concentrations in the marine boundary layer. The global contribution of the upper and middle troposphere to the Hg(II) dry deposition flux is 52 %. It is lower compared to the contribution to wet deposition because dry deposition of Hg(II) produced aloft requires its entrainment into the boundary layer, while rain can scavenge Hg(II) from higher altitudes more readily. We find

Radon measurements in the lower tropical stratosphere - Evidence for rapid vertical transport and dehydration of tropospheric air

NASA Technical Reports Server (NTRS)

Kritz, Mark A.; Rosner, Stefan W.; Kelly, Kenneth K.; Loewenstein, Max; Chan, K. R.

1993-01-01

During the tropical experiment of NASA's Stratosphere-Troposphere Exchange Program (STEP), in situ radon and other trace constituent measurements were made aboard a NASA ER-2 high-altitude research aircraft to investigate the mechanisms of irreversible transfers from the troposphere into the tropical stratosphere. Observations made in and downwind of the cirrus shields of three large tropical cyclones and downwind of the cirrus anvil of a large cumulonimbus cloud cluster showed several clear instances of elevated radon activity occurring simultaneously with low total water mixing ratios. These observations are unambiguous evidence of an effective dehydration process, capable of reducing total water vapor mixing ratios to less than 2.5 ppmv, occurring in conjunction with troposphere-to-stratosphere transport and indicate that rapid localized convection, rather than slow regional mean motions, was responsible for the observed transports and associated with the accompanying dehydration. Radon activities measured in regions of active or recent troposphere-to-stratosphere transport were consistent with the 17 pCi/scm mean value needed to support the observed abundance of stratospheric 210 Pb.

Tropospheric Wind Monitoring During Day-of-Launch Operations for NASA's Space Shuttle Program

NASA Technical Reports Server (NTRS)

Decker, Ryan; Leach, Richard

2004-01-01

The Environments Group at the National Aeronautics and Space Administration's Marshall Space Flight Center monitors the winds aloft above Kennedy Space Center (KSC) in support of the Space Shuttle Program day-of-launch operations. Assessment of tropospheric winds is used to support the ascent phase of launch. Three systems at KSC are used to generate independent tropospheric wind profiles prior to launch; 1) high resolution jimsphere balloon system, 2) 50-MHz Doppler Radar Wind Profiler (DRWP) and 3) low resolution radiosonde system. All independent sources are compared against each other for accuracy. To assess spatial and temporal wind variability during launch countdown each jimsphere profile is compared against a design wind database to ensure wind change does not violate wind change criteria.

Evaluation of Empirical Tropospheric Models Using Satellite-Tracking Tropospheric Wet Delays with Water Vapor Radiometer at Tongji, China

PubMed Central

Wang, Miaomiao; Li, Bofeng

2016-01-01

An empirical tropospheric delay model, together with a mapping function, is commonly used to correct the tropospheric errors in global navigation satellite system (GNSS) processing. As is well-known, the accuracy of tropospheric delay models relies mainly on the correction efficiency for tropospheric wet delays. In this paper, we evaluate the accuracy of three tropospheric delay models, together with five mapping functions in wet delays calculation. The evaluations are conducted by comparing their slant wet delays with those measured by water vapor radiometer based on its satellite-tracking function (collected data with large liquid water path is removed). For all 15 combinations of three tropospheric models and five mapping functions, their accuracies as a function of elevation are statistically analyzed by using nine-day data in two scenarios, with and without meteorological data. The results show that (1) no matter with or without meteorological data, there is no practical difference between mapping functions, i.e., Chao, Ifadis, Vienna Mapping Function 1 (VMF1), Niell Mapping Function (NMF), and MTT Mapping Function (MTT); (2) without meteorological data, the UNB3 is much better than Saastamoinen and Hopfield models, while the Saastamoinen model performed slightly better than the Hopfield model; (3) with meteorological data, the accuracies of all three tropospheric delay models are improved to be comparable, especially for lower elevations. In addition, the kinematic precise point positioning where no parameter is set up for tropospheric delay modification is conducted to further evaluate the performance of tropospheric delay models in positioning accuracy. It is shown that the UNB3 model is best and can achieve about 10 cm accuracy for the N and E coordinate component while 20 cm accuracy for the U coordinate component no matter the meteorological data is available or not. This accuracy can be obtained by the Saastamoinen model only when meteorological data is

Upper-Tropospheric Winds Derived from Geostationary Satellite Water Vapor Observations

NASA Technical Reports Server (NTRS)

Velden, Christopher S.; Hayden, Christopher M.; Nieman, Steven J.; Menzel, W. Paul; Wanzong, Steven; Goerss, James S.

1997-01-01

The coverage and quality of remotely sensed upper-tropospheric moisture parameters have improved considerably with the deployment of a new generation of operational geostationary meteorological satellites: GOES-8/9 and GMS-5. The GOES-8/9 water vapor imaging capabilities have increased as a result of improved radiometric sensitivity and higher spatial resolution. The addition of a water vapor sensing channel on the latest GMS permits nearly global viewing of upper-tropospheric water vapor (when joined with GOES and Meteosat) and enhances the commonality of geostationary meteorological satellite observing capabilities. Upper-tropospheric motions derived from sequential water vapor imagery provided by these satellites can be objectively extracted by automated techniques. Wind fields can be deduced in both cloudy and cloud-free environments. In addition to the spatially coherent nature of these vector fields, the GOES-8/9 multispectral water vapor sensing capabilities allow for determination of wind fields over multiple tropospheric layers in cloud-free environments. This article provides an update on the latest efforts to extract water vapor motion displacements over meteorological scales ranging from subsynoptic to global. The potential applications of these data to impact operations, numerical assimilation and prediction, and research studies are discussed.

NASA Soil Moisture Mission Produces First Global Radar Map

NASA Image and Video Library

2015-04-21

With its antenna now spinning at full speed, NASA new Soil Moisture Active Passive SMAP observatory has successfully re-tested its science instruments and generated its first global maps, a key step to beginning routine science operations in May, 2015

NASA Soil Moisture Mission Produces First Global Radiometer Map

NASA Image and Video Library

2015-04-21

With its antenna now spinning at full speed, NASA new Soil Moisture Active Passive SMAP observatory has successfully re-tested its science instruments and generated its first global maps, a key step to beginning routine science operations in May, 2015

Modeling of Isotope Fractionation in Stratospheric CO2, N2O, CH4, and O3: Investigations of Stratospheric Chemistry and Transport, Stratosphere-Troposphere Exchange, and Their Influence on Global Isotope Budgets

NASA Technical Reports Server (NTRS)

Boering, Kristie A.; Connell, Peter; Rotman, Douglas

2004-01-01

We investigated the isotopic fractionation of CH4 and hydrogen (H2) in the stratosphere by incorporating isotope-specific rate coefficients into the Lawrence Livermore National Laboratory (LLNL) 2D model and comparing the model results with new observations from the NASA ER-2 aircraft (funded through a separate task under the Upper Atmosphere Research Program). The model results reveal that fractionation which occurs in the stratosphere has a significant influence on isotope compositions in the free troposphere, an important point which had previously been ignored, unrecognized or unquantified for many long-lived trace gases, including CH4 and H2 which we have focused our efforts on to date. Our analyses of the model results and new isotope observations have also been used to test how well the kinetic isotope effects are known, at least to within the uncertainties in model chemistry and transport. Overall, these results represent an important step forward in our understanding of isotope fractionation in the atmosphere and demonstrate that stratospheric isotope fractionation cannot be ignored in modeling studies which use isotope observations in the troposphere to infer the global budgets of CH4 (an important greenhouse gas) and of H2 (a gas whose atmospheric budget must be better quantified, particularly before a large human perturbation from fuel cell use is realized). Our analyses of model results and observations from the NASA ER-2 aircraft are briefly summarized separately below for CH4, H2, and H2O and for the contribution of these modeling studies to date to our understanding of isotope fractionation for N2O, CO2, and O3 as well.

How much of the global aerosol optical depth is found in the boundary layer and free troposphere?

NASA Astrophysics Data System (ADS)

Bourgeois, Quentin; Ekman, Annica M. L.; Renard, Jean-Baptiste; Krejci, Radovan; Devasthale, Abhay; Bender, Frida A.-M.; Riipinen, Ilona; Berthet, Gwenaël; Tackett, Jason L.

2018-06-01

The global aerosol extinction from the CALIOP space lidar was used to compute aerosol optical depth (AOD) over a 9-year period (2007-2015) and partitioned between the boundary layer (BL) and the free troposphere (FT) using BL heights obtained from the ERA-Interim archive. The results show that the vertical distribution of AOD does not follow the diurnal cycle of the BL but remains similar between day and night highlighting the presence of a residual layer during night. The BL and FT contribute 69 and 31 %, respectively, to the global tropospheric AOD during daytime in line with observations obtained in Aire sur l'Adour (France) using the Light Optical Aerosol Counter (LOAC) instrument. The FT AOD contribution is larger in the tropics than at mid-latitudes which indicates that convective transport largely controls the vertical profile of aerosols. Over oceans, the FT AOD contribution is mainly governed by long-range transport of aerosols from emission sources located within neighboring continents. According to the CALIOP aerosol classification, dust and smoke particles are the main aerosol types transported into the FT. Overall, the study shows that the fraction of AOD in the FT - and thus potentially located above low-level clouds - is substantial and deserves more attention when evaluating the radiative effect of aerosols in climate models. More generally, the results have implications for processes determining the overall budgets, sources, sinks and transport of aerosol particles and their description in atmospheric models.

The impact of higher-order ionospheric effects on estimated tropospheric parameters in Precise Point Positioning

NASA Astrophysics Data System (ADS)

Zus, F.; Deng, Z.; Wickert, J.

2017-08-01

The impact of higher-order ionospheric effects on the estimated station coordinates and clocks in Global Navigation Satellite System (GNSS) Precise Point Positioning (PPP) is well documented in literature. Simulation studies reveal that higher-order ionospheric effects have a significant impact on the estimated tropospheric parameters as well. In particular, the tropospheric north-gradient component is most affected for low-latitude and midlatitude stations around noon. In a practical example we select a few hundred stations randomly distributed over the globe, in March 2012 (medium solar activity), and apply/do not apply ionospheric corrections in PPP. We compare the two sets of tropospheric parameters (ionospheric corrections applied/not applied) and find an overall good agreement with the prediction from the simulation study. The comparison of the tropospheric parameters with the tropospheric parameters derived from the ERA-Interim global atmospheric reanalysis shows that ionospheric corrections must be consistently applied in PPP and the orbit and clock generation. The inconsistent application results in an artificial station displacement which is accompanied by an artificial "tilting" of the troposphere. This finding is relevant in particular for those who consider advanced GNSS tropospheric products for meteorological studies.

Use of radon and cosmogenic radionuclides as indicators of exchange between troposphere and stratosphere

NASA Technical Reports Server (NTRS)

Kritz, Mark A.

1994-01-01

This research grant covered participation in the operational phase of NASA's Stratosphere-Troposphere Exchange Project (STEP), a multi-agency airborne science program conducted aboard NASA U-2 and ER-2 high altitude research aircraft. The primary goals of STEP were to investigate the mechanisms of irreversible movement of mass, trace gases, and aerosols from the troposphere into the stratosphere, and to explain the observed dryness of the stratosphere. Three flight experiments were conducted to address these questions: two extratropical experiments, in 1984 and 1986, and a tropical experiment, in 1987. The cosmogenic radionuclides Be-7 and P-32, produced in the stratosphere by cosmic rays, and Rn-222 (radon), emitted from continental soils, were well-suited as tracers of intra-stratospheric air mass movements, and to follow episodes of troposphere to stratosphere exchange. Measurements of Be-7 and P-32 were made in all three STEP experiments. Measurements of radon were made in the tropical experiment only. The equipment worked well, and produced a valuable data set in support of the STEP objectives, as indicated by the 'quick-look' results outlined.

NASA/MSFC FY92 Earth Science and Applications Program Research Review

NASA Technical Reports Server (NTRS)

Arnold, James E. (Editor); Leslie, Fred W. (Editor)

1993-01-01

A large amount of attention has recently been given to global issues such as the ozone hole, tropospheric temperature variability, etc. A scientific challenge is to better understand atmospheric processes on a variety of spatial and temporal scales in order to predict environmental changes. Measurement of geophysical parameters such as wind, temperature, and moisture are needed to validate theories, provide analyzed data sets, and initialize or constrain numerical models. One of NASA's initiatives is the Mission to Planet Earth Program comprised of an Earth Observation System (EOS) and the scientific strategy to analyze these data. This work describes these efforts in the context of satellite data analysis and fundamental studies of atmospheric dynamics which examine selected processes important to the global circulation.

Evaluation of atmospheric aerosol and tropospheric ozone effects on global terrestrial ecosystem carbon dynamics

NASA Astrophysics Data System (ADS)

Chen, Min

The increasing human activities have produced large amounts of air pollutants ejected into the atmosphere, in which atmospheric aerosols and tropospheric ozone are considered to be especially important because of their negative impacts on human health and their impacts on global climate through either their direct radiative effect or indirect effect on land-atmosphere CO2 exchange. This dissertation dedicates to quantifying and evaluating the aerosol and tropospheric ozone effects on global terrestrial ecosystem dynamics using a modeling approach. An ecosystem model, the integrated Terrestrial Ecosystem Model (iTem), is developed to simulate biophysical and biogeochemical processes in terrestrial ecosystems. A two-broad-band atmospheric radiative transfer model together with the Moderate-Resolution Imaging Spectroradiometer (MODIS) measured atmospheric parameters are used to well estimate global downward solar radiation and the direct and diffuse components in comparison with observations. The atmospheric radiative transfer modeling framework were used to quantify the aerosol direct radiative effect, showing that aerosol loadings cause 18.7 and 12.8 W m -2 decrease of direct-beam Photosynthetic Active Radiation (PAR) and Near Infrared Radiation (NIR) respectively, and 5.2 and 4.4 W m -2 increase of diffuse PAR and NIR, respectively, leading to a total 21.9 W m-2 decrease of total downward solar radiation over the global land surface during the period of 2003-2010. The results also suggested that the aerosol effect may be overwhelmed by clouds because of the stronger extinction and scattering ability of clouds. Applications of the iTem with solar radiation data and with or without considering the aerosol loadings shows that aerosol loading enhances the terrestrial productions [Gross Primary Production (GPP), Net Primary Production (NPP) and Net Ecosystem Production (NEP)] and carbon emissions through plant respiration (RA) in global terrestrial ecosystems over the

Activities of NASA's Global Modeling Initiative (GMI) in the Assessment of Subsonic Aircraft Impact

NASA Technical Reports Server (NTRS)

Rodriquez, J. M.; Logan, J. A.; Rotman, D. A.; Bergmann, D. J.; Baughcum, S. L.; Friedl, R. R.; Anderson, D. E.

2004-01-01

The Intergovernmental Panel on Climate Change estimated a peak increase in ozone ranging from 7-12 ppbv (zonal and annual average, and relative to a baseline with no aircraft), due to the subsonic aircraft in the year 2015, corresponding to aircraft emissions of 1.3 TgN/year. This range of values presumably reflects differences in model input (e.g., chemical mechanism, ground emission fluxes, and meteorological fields), and algorithms. The model implemented by the Global Modeling Initiative allows testing the impact of individual model components on the assessment calculations. We present results of the impact of doubling the 1995 aircraft emissions of NOx, corresponding to an extra 0.56 TgN/year, utilizing meteorological data from NASA's Data Assimilation Office (DAO), the Goddard Institute for Space Studies (GISS), and the Middle Atmosphere Community Climate Model, version 3 (MACCM3). Comparison of results to observations can be used to assess the model performance. Peak ozone perturbations ranging from 1.7 to 2.2 ppbv of ozone are calculated using the different fields. These correspond to increases in total tropospheric ozone ranging from 3.3 to 4.1 Tg/Os. These perturbations are consistent with the IPCC results, due to the difference in aircraft emissions. However, the range of values calculated is much smaller than in IPCC.

Use of Global Meteorological Model to Correct for Stratified Tropospheric Delays in SAR Data: Application to Active Mexican Stratovolcanoes.

NASA Astrophysics Data System (ADS)

Pinel, V. M.; Doin, M.; de La Cruz-Reyna, S.; Hooper, A.

2008-12-01

Artefacts induced by temporal changes of water content within the tropospheric layer have long been recognised as the main limitation for the use of InSAR data in order to detect magma movement at depth beneath stratovolcanoes (Delacourt, 1998). Difficulty in discriminating between tropospheric artefacts and deformation induced by magma accumulation or withdrawal at depth is mainly due to the similarity of the expected signal centred on the volcanic edifice. However it is of prime importance to be able to detect magma storage which is the most reliable precursor for volcanic eruptions. We processed time series of InSAR data acquired by ENVISAT from December 2002 to August 2006 at Popocatépetl and Colima Volcano (Mexico) using both the Stanford method for persistent scatterers and a derived small baseline approach (Hooper, 2008). Tropospheric delays are estimated for each interferogram using temperature, pressure and water content profiles from the North American Regional Reanalysis (NARR), a global atmospheric model provided by the National Centers for Environmental Prediction. A strong seasonal effect is observed leading to maximum value for delays of 10 rad/km corresponding to 4 fringes on the volcano slopes. These delays are validated using the correlation between the wrapped phase and the elevation as well as spectrometer data acquired by the Medium Resolution Imaging System (MERIS) onboard on the ENVISAT platform. The tropospheric effect is removed from the wrapped phase which improves the unwrapping process. On Popocatépetl no significant deformations were observed. We could not detect any deep magma storage zone beneath Colima volcano, but its summit area exhibits a constant and almost linear subsidence of more than 1.5 cm/year mainly related to recent volcanic deposits loading. References: Delacourt, P. Briole and J. Achache, Tropospheric corrections of SAR interferograms with strong topography. Application to Etna. Geophys. Res. Lett., 25, 2849- 2852

Continuing worldwide increase in tropospheric methane, 1978 to 1987

NASA Technical Reports Server (NTRS)

Blake, Donald R.; Rowland, F. Sherwood

1988-01-01

The average worldwide tropospheric mixing ratio of methane has increased by 11 percent from 1.52 parts per million by volume (ppmv) in January 1978 to 1.684 ppmv in September 1987, for an increment of 0.016 + or - 0.001 ppmv per year. Within the limits of the present measurements, the global tropospheric mixing ratio for methane over the past decade is consistent either with a linear growth rate of 0.016 + or - 0.001 ppmv per year or with a slight lessening of the rate of growth over the past 5 years. No indications were found of an effect of the El Nino-Southern Oscillation-El Chichon events of 1982-83 on total global methane, although severe reductions were reported in the Pacific Northwest during that time period.The growth in tropospheric methane may have increased the water concentration in the stratosphere by as much as 28 percent since the 1940s and 45 percent over the past two centuries and thus could have increased the mass of precipitable water available for the formation of polar stratospheric clouds.

Satellite Observations of Tropospheric Ammonia

NASA Astrophysics Data System (ADS)

Shephard, M. W.; Luo, M.; Rinsland, C. P.; Cady-Pereira, K. E.; Beer, R.; Pinder, R. W.; Henze, D.; Payne, V. H.; Clough, S.; Rodgers, C. D.; Osterman, G. B.; Bowman, K. W.; Worden, H. M.

2008-12-01

Global high-spectral resolution (0.06 cm-1) nadir measurements from TES-Aura enable the simultaneous retrieval of a number of tropospheric pollutants and trace gases in addition to the TES standard operationally retrieved products (e.g. carbon monoxide, ozone). Ammonia (NH3) is one of the additional species that can be retrieved in conjunction with the TES standard products, and is important for local, regional, and global tropospheric chemistry studies. Ammonia emissions contribute significantly to several well-known environmental problems, yet the magnitude and seasonal/spatial variability of the emissions are poorly constrained. In the atmosphere, an important fraction of fine particulate matter is composed of ammonium nitrate and ammonium sulfate. These particles are statistically associated with health impacts. When deposited to ecosystems in excess, nitrogen, including ammonia can cause nutrient imbalances, change in ecosystem species composition, eutrophication, algal blooms and hypoxia. Ammonia is also challenging to measure in-situ. Observations of surface concentrations are rare and are particularly sparse in North America. Satellite observations of ammonia are therefore highly desirable. We recently demonstrated that tropospheric ammonia is detectable in the TES spectra and presented some corresponding preliminary retrievals over a very limited range of conditions (Beer et al., 2008). Presented here are results that expand upon these initial TES ammonia retrievals in order to evaluate/validate the retrieval results utilizing in-situ surface observations (e.g. LADCO, CASTNet, EPA /NC State) and chemical models (e.g. GEOS-Chem and CMAQ). We also present retrievals over regions of interest that have the potential to help further understand air quality and the active nitrogen cycle. Beer, R., M. W. Shephard, S. S. Kulawik, S. A. Clough, A. Eldering, K. W. Bowman, S. P. Sander, B. M. Fisher, V. H. Payne, M. Luo, G. B. Osterman, and J. R. Worden, First

Satellite Observations of Tropospheric BrO over Salt Lakes and Northern High Latitudes from EOS/OMI and SNPP/OMPS

NASA Astrophysics Data System (ADS)

Kurosu, T. P.; Stutz, J.; Brockway, N.; Saiz-Lopez, A.; Suleiman, R. M.; Natraj, V.; Jaross, G.; Seftor, C. J.

2017-12-01

We present observations of tropospheric bromine monoxide (BrO) derived from two satellite instruments: the Ozone Monitoring Instrument (OMI) on EOS-Aura, and the Nadir Mapper component of the Ozone Mapping and Profiler Suite (OMPS) on Suomi/NPP. BrO observations from OMPS constitute a new and experimental measurement that we first report on here and compare with the standard BrO data product from OMI. BrO is a halogen oxide present mostly in the lower stratosphere, where it catalytically destroys ozone with about 25 times the efficiency of ClO. BrO also has a tropospheric component, where it is released from sea surfaces, at the interface of ocean water and sea ice in the polar spring, in volcanic plumes, and in the vicinity of salt lakes. Tropospheric BrO has been linked to mercury (Hg) deposition through BrO-induced conversion of gaseous Hg to reactive Hg, which is then deposited on the surface and enters the food chain, ultimately affecting human health. As part of NASA's Aura Science Team, we are developing an OMI Tropospheric BrO data product that provides a unique global data set on BrO spatial and vertical distribution in the troposphere and stratosphere. Information of this kind is currently unavailable from any of the past and present bromine-monitoring instruments. In this presentation, we focus on multi-year time series of BrO released from a range of salt lakes - the Rann of Kutch, Salar de Uyuni, the Aral Sea, and others. We quantify the amount of bromine released from the lakes and investigate the possibility of lake desiccation monitoring based on independent BrO observations. The quality and limits of OMI and OMPS tropospheric BrO observations is investigated by comparison with ground-based MAX-DOAS observations over central Greenland.

Estimating the Tropospheric Ozone Distribution by the Assimilation of Satellite Data

NASA Technical Reports Server (NTRS)

Hayashi, Hiroo; Stajner, Ivanka; Winslow, Nathan; Jones, Dylan B. A.; Pawson, Steven; Thompson, Anne M.

2003-01-01

Tropospheric ozone is important to the environment, because it acts as a strong oxidant to control the concentrations of many reduced gases (methane, carbon monoxide, ... ), its radiative forcing plays a significant role in the greenhouse effect, and direct contact with ozone is harmful to human health. Tropospheric ozone, whose main sources are intrusion from the stratosphere and chemical production from source gases associated with urban pollution or biomass burning, varies on a wide range of spatial and temporal scales. Its transport and chemistry can be influenced by weather, seasonal, or multiannual variability. Despite the importance of tropospheric ozone, it contributes only about 10% of the total ozone loading in the atmosphere. Consequently, satellite instruments lose sensitivity below the stratospheric ozone peak, and provide little information about middle and lower tropospheric ozone. This talk will discuss recent modifications made to the satellite ozone data assimilation system at NASA's Data Assimilation Office (DAO) in order to provide better tropospheric ozone columns and profiles. We use a version of the system that assimilates only the data from the Solar Backscatter UltraViolet/2 (SBUV/2) instrument. The quality of the assimilated ozone in the tropical troposphere is evaluated by comparison with independent observations obtained from the Southern Hemispheric Additional Ozonesondes (SHADOZ) network. It is shown that the quality of ozone fields is sensitive to the winds used in the transport model. Increasing the vertical resolution of the model also has a beneficial impact. The assimilated ozone in the lower troposphere was substantially improved by inclusion of tropospheric ozone production, loss, and dry deposition rates from the Harvard GEOS-CHEM model. The mechanisms behind these results will be examined and the implications for our understanding of tropospheric ozone will be discussed.

Improved OMI Nitrogen Dioxide Retrievals Aided by NASA's A-Train High-Resolution Data

NASA Astrophysics Data System (ADS)

Lamsal, L. N.; Krotkov, N. A.; Vasilkov, A. P.; Marchenko, S. V.; Qin, W.; Yang, E. S.; Fasnacht, Z.; Haffner, D. P.; Swartz, W. H.; Spurr, R. J. D.; Joiner, J.

2017-12-01

Space-based global observation of nitrogen dioxide (NO2) is among the main objectives of the NASA Aura Ozone Monitoring Instrument (OMI) mission, aimed at advancing our understanding of the sources and trends of nitrogen oxides (NOx). These applications benefit from improved retrieval techniques and enhancement in data quality. Here, we describe our recent and planned updates to the NASA OMI standard NO2 products. The products and documentation are publicly available from the NASA Goddard Earth Sciences Data and Information Services Center (https://disc.gsfc.nasa.gov/datasets/OMNO2_V003/summary/). The major changes include (1) improvements in spectral fitting algorithms for NO2 and cloud, (2) improved information in the vertical distribution of NO2, and (3) use of geometry-dependent surface reflectivity information derived from NASA's Aqua MODIS over land and the Cox-Munk slope distribution over ocean with a contribution from water-leaving radiance. These algorithm updates, which lead to more accurate tropospheric NO2 retrievals from OMI, are relevant for other past, contemporary, and future satellite instruments.

Tropospheric Ozone and Photochemical Smog

NASA Astrophysics Data System (ADS)

Sillman, S.

2003-12-01

emitted species, in a process that is driven by sunlight and is accelerated by warm temperatures. This smog is largely the product of gasoline-powered engines (especially automobiles), although coal-fired industry can also generate photochemical smog. The process of photochemical smog formation was first identified by Haagen-Smit and Fox (1954) in association with Los Angeles, a city whose geography makes it particularly susceptible to this type of smog formation. Sulfate aerosols and organic particulates are often produced concurrently with ozone, giving rise to a characteristic milky-white haze associated with this type of air pollution.Today ozone and particulates are recognized as the air pollutants that are most likely to affect human health adversely. In the United States, most major metropolitan areas have periodic air pollution events with ozone in excess of government health standards. Violations of local health standards also occur in major cities in Canada and in much of Europe. Other cities around the world (especially Mexico City) also experience very high ozone levels. In addition to urban-scale events, elevated ozone occurs in region-wide events in the eastern USA and in Western Europe, with excess ozone extending over areas of 1,000 km2 or more. Ozone plumes of similar extent are found in the tropics (especially in Central Africa) at times of high biomass burning (e.g., Jenkins et al., 1997; Chatfield et al., 1998). In some cases ozone associated with biomass burning has been identified at distances up to 104 km from its sources (Schultz et al., 1999).Ozone also has a significant impact on the global troposphere, and ozone chemistry is a major component of global tropospheric chemistry. Global background ozone concentrations are much lower than urban or regional concentrations during pollution events, but there is evidence that the global background has increased as a result of human activities (e.g., Wang and Jacob, 1998; Volz and Kley, 1988). A rise in

Methane Sensitivity to Perturbations in Tropospheric Oxidizing Capacity

NASA Technical Reports Server (NTRS)

Yegorova, Elena; Duncan, Bryan

2011-01-01

Methane is an important greenhouse gas and has a 25 times greater global warming potential than CO2 on a century timescale. Yet there are considerable uncertainties in the magnitude and variability of its sources and sinks. The response of the coupled non-linear methane-carbon monoxide-hydroxyl radical (OH) system is important in determining the tropospheric oxidizing capacity. Using the NASA Goddard Earth Observing System, Version 5 (GEOS-5) chemistry climate model, we study the response of methane to perturbations of OH and wetland emissions. We use a computationally-efficient option of the GEOS-5 CCM that includes an OH parameterization that accurately represents OH predicted by a full chemical mechanism. The OH parameterization allows for studying non-linear CH4-CO-OH feedbacks in computationally fast sensitivity experiments. We compare our results with surface observations (GMD) and discuss the range of uncertainty in OH and wetland emissions required to bring modeling results in better agreement with surface observations. Our results can be used to improve projections of methane emissions and methane growth.

Volcanic Contribution to Decadal Changes in Tropospheric Temperature

NASA Technical Reports Server (NTRS)

Santer, Benjamin D.; Bonfils, Celine; Painter, Jeffrey F.; Zelinka, Mark D.; Mears, Carl; Solomon, Susan; Schmidt, Gavin A.; Fyfe, John C.; Cole, Jason N.S.; Nazarenko, Larissa;

Global Precipitation Measurement Mission Products and Services at the NASA GES DISC

NASA Technical Reports Server (NTRS)

Liu, Z.; Ostrenga, D.; Vollmer, B.; Deshong, B.; MacRitchie, K.; Greene, M.; Kempler, S.

2017-01-01

This article describes NASA/JAXA Global Precipitation Measurement (GPM) mission products and services at the NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC). Built on the success of the Tropical Rainfall Measuring Mission (TRMM), the next-generation GPM mission consists of new precipitation measurement instruments and a constellation of international research and operational satellites to provide improved measurements of precipitation globally. To facilitate data access, research, applications, and scientific discovery, the GES DISC has developed a variety of data services for GPM. This article is intended to guide users in choosing GPM datasets and services at the GES DISC.

The Response of Tropospheric Ozone to ENSO in Observations and a Chemistry-Climate Simulation

NASA Technical Reports Server (NTRS)

Oman, L. D.; Douglass, A. R.; Ziemke, J. R.; Waugh, D. W.; Rodriguez, J. M.; Nielsen, J. E.

2012-01-01

The El Nino-Southern Oscillation (ENSO) is the dominant mode of tropical variability on interannual time scales. ENSO appears to extend its influence into the chemical composition of the tropical troposphere. Recent results have revealed an ENSO induced wave-l anomaly in observed tropical tropospheric column ozone. This results in a dipole over the western and eastern tropical Pacific, whereby differencing the two regions produces an ozone anomaly with an extremely high correlation to the Nino 3.4 Index. We have successfully reproduced this result using the Goddard Earth Observing System Version 5 (GEOS-5) general circulation model coupled to a comprehensive stratospheric and tropospheric chemical mechanism forced with observed sea surface temperatures over the past 25 years. An examination of the modeled ozone field reveals the vertical contributions of tropospheric ozone to the column over the western and eastern Pacific region. We will show targeted comparisons with observations from NASA's Aura satellite Microwave Limb Sounder (MLS), and the Tropospheric Emissions Spectrometer (TES) to provide insight into the vertical structure of ozone changes. The tropospheric ozone response to ENSO could be a useful chemistry-climate model evaluation tool and should be considered in future modeling assessments.

Prediction Activities at NASA's Global Modeling and Assimilation Office

NASA Technical Reports Server (NTRS)

Schubert, Siegfried

2010-01-01

The Global Modeling and Assimilation Office (GMAO) is a core NASA resource for the development and use of satellite observations through the integrating tools of models and assimilation systems. Global ocean, atmosphere and land surface models are developed as components of assimilation and forecast systems that are used for addressing the weather and climate research questions identified in NASA's science mission. In fact, the GMAO is actively engaged in addressing one of NASA's science mission s key questions concerning how well transient climate variations can be understood and predicted. At weather time scales the GMAO is developing ultra-high resolution global climate models capable of resolving high impact weather systems such as hurricanes. The ability to resolve the detailed characteristics of weather systems within a global framework greatly facilitates addressing fundamental questions concerning the link between weather and climate variability. At sub-seasonal time scales, the GMAO is engaged in research and development to improve the use of land information (especially soil moisture), and in the improved representation and initialization of various sub-seasonal atmospheric variability (such as the MJO) that evolves on time scales longer than weather and involves exchanges with both the land and ocean The GMAO has a long history of development for advancing the seasonal-to-interannual (S-I) prediction problem using an older version of the coupled atmosphere-ocean general circulation model (AOGCM). This includes the development of an Ensemble Kalman Filter (EnKF) to facilitate the multivariate assimilation of ocean surface altimetry, and an EnKF developed for the highly inhomogeneous nature of the errors in land surface models, as well as the multivariate assimilation needed to take advantage of surface soil moisture and snow observations. The importance of decadal variability, especially that associated with long-term droughts is well recognized by the

Theory and operation of the real-time data acquisition system for the NASA-LaRC differential absorption lidar (DIAL)

NASA Technical Reports Server (NTRS)

Butler, Carolyn; Spencer, Randall

1988-01-01

The improvement of computer hardware and software of the NASA Multipurpose Differential Absorption Lidar (DIAL) system is documented. The NASA DIAL system has undergone development and experimental deployment at NASA/Langley Res. Center for the remote measurement of atmospheric trace gas concentrations from ground and aircraft platforms. A viable DIAL system was developed capable of remotely measuring O3 and H2O concentrations from an aircraft platform. The DIAL Data Acquisition System (DAS) has undergone a number of improvements also. Due to the participation of the DIAL in the Global Tropospheric Experiment, modifications and improvements of the system were tested and used both in the lab and in air. Therefore, this is an operational manual for the DIAL DAS.

TOLNet - A Tropospheric Ozone Lidar Profiling Network for Satellite Continuity and Process Studies

NASA Technical Reports Server (NTRS)

Newchurch, Michael J.; Kuang, Shi; Wang, Lihua; LeBlanc, Thierry; Alvarez II, Raul J.; Langford, Andrew O.; Senff, Christoph J.; Brown, Steve; Johnson, Bryan; Burris, John F.;

NASA Global Hawk: A New Tool for Earth Science Research

NASA Technical Reports Server (NTRS)

Hall, Phill

2009-01-01

This slide presentation reviews the Global Hawk, a unmanned aerial vehicle (UAV) that NASA plans to use for Earth Sciences research. The Global Hawk is the world's first fully autonomous high-altitude, long-endurance aircraft, and is capable of conducting long duration missions. Plans are being made for the use of the aircraft on missions in the Arctic, Pacific and Western Atlantic Oceans. There are slides showing the Global Hawk Operations Center (GHOC), Flight Control and Air Traffic Control Communications Architecture, and Payload Integration and Accommodations on the Global Hawk. The first science campaign, planned for a study of the Pacific Ocean, is reviewed.

Tropospheric Wind Profile Measurements with a Direct Detection Doppler Lidar

NASA Technical Reports Server (NTRS)

Gentry, Bruce M.; Li, Steven X.; Korb, C. Laurence; Chen, Huailin; Mathur, Savyasachee

1998-01-01

Research has established the importance of global tropospheric wind measurements for large scale improvements in numerical weather prediction. In addition, global wind measurements provide data that are fundamental to the understanding and prediction of global climate change. These tasks are closely linked with the goals of the NASA Earth Science Enterprise and Global Climate Change programs. NASA Goddard has been actively involved in the development of direct detection Doppler lidar methods and technologies to meet the wind observing needs of the atmospheric science community. In this paper we describe a recently developed prototype wind lidar system using a direct detection Doppler technique for measuring wind profiles from the surface through the troposphere. This system uses a pulsed ND:YAG laser operating at 1064 nm as the transmitter. The laser pulse is directed to the atmosphere using a 40 cm diameter scan mirror. The portion of the laser energy backscattered from aerosols and molecules is collected by a 40 cm diameter telescope and coupled via fiber optics into the Doppler receiver. Single photon counting APD's are used to detect the atmospheric backscattered signal. The principle element of the receiver is a dual bandpass tunable Fabry Perot etalon which analyzes the Doppler shift of the incoming laser signal using the double edge technique. The double edge technique uses two high resolution optical filters having bandpasses offset relative to one another such that the 'edge' of the first filter's transmission function crosses that of the second at the half power point. The outgoing laser frequency is located approximately at the crossover point. Due to the opposite going slopes of the edges, a Doppler shift in the atmospheric backscattered laser frequency produces a positive change in signal for one filter and a negative change in the second filter. Taking the ratio of the two edge channel signals yields a result which is directly proportional to the

Large Scale Variability of Mid-Tropospheric Carbon Dioxide as Observed by the Atmospheric Infrared Sounder (AIRS) on the NASA EOS Aqua Platform

NASA Technical Reports Server (NTRS)

Pagano, Thomas S.; Olsen, Edward T.

2012-01-01

The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the EOS Aqua Spacecraft, launched on May 4, 2002. AIRS has 2378 infrared channels ranging from 3.7 microns to 15.4 microns and a 13.5 km footprint. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy, water vapor profiles (20%/2km), infrared cloud height and fraction, and trace gas amounts for CO2, CO, SO2, O3 and CH4 in the mid to upper troposphere. AIRS wide swath(cedilla) +/-49.5 deg , enables daily global daily coverage for over 95% of the Earth's surface. AIRS data are used for weather forecasting, validating climate model distribution and processes, and observing long-range transport of greenhouse gases. In this study, we examine the large scale and regional horizontal variability in the AIRS Mid-tropospheric Carbon Dioxide product as a function of season and associate the observed variability with known atmospheric transport processes, and sources and sinks of CO2.

Zonally Averaged Carbon Dioxide Concentration from Earth Mid-Troposphere at Different Latitudes, 2002 to 2013

NASA Image and Video Library

2013-05-22

This plot shows the concentration of carbon dioxide in Earth mid-troposphere at various latitudes as measured by NASA Aqua satellite. The colored lines represent different latitude bands that circle Earth, called zones.

Operational overview of the NASA GTE/CITE 3 airborne instrument intercomparisons for sulfur dioxide, hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, and carbon disulfide

NASA Technical Reports Server (NTRS)

Hoell, James M., Jr.; Davis, Douglas D.; Gregory, Gerald L.; Mcneal, Robert J.; Bendura, Richard J.; Drewry, Joseph W.; Barrick, John D.; Kirchhoff, Volker W. J. H.; Motta, Adauto G.; Navarro, Roger L.

1993-01-01

This paper reports the overall experimental design and gives a brief overview of results from the third airborne Chemical Instrumentation Test and Evaluation (CITE 3) mission conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment. The primary objective of CITE 3 was to evaluate the capability of instrumentation for airborne measurements of ambient concentrations of SO2, H2S, CS, dimethyl sulfide, and carbonyl sulfide. Ancillary measurements augmented the intercomparison data in order to address the secondary objective of CITE 3 which was to address specific issues related to the budget and photochemistry of tropospheric sulfur species. The CITE 3 mission was conducted on NASA's Wallops Flight Center Electra aircraft and included a ground-based intercomparison of sulfur standards and intercomparison/sulfur science flights conducted from the NASA Wallops Flight Facility, Wallops Island, Virginia, followed by flights from Natal, Brazil. Including the transit flights, CITE 3 included 16 flights encompassing approximately 96 flight hours.

The Impact of Estimating High-Resolution Tropospheric Gradients on Multi-GNSS Precise Positioning.

PubMed

Zhou, Feng; Li, Xingxing; Li, Weiwei; Chen, Wen; Dong, Danan; Wickert, Jens; Schuh, Harald

2017-04-03

Benefits from the modernized US Global Positioning System (GPS), the revitalized Russian GLObal NAvigation Satellite System (GLONASS), and the newly-developed Chinese BeiDou Navigation Satellite System (BDS) and European Galileo, multi-constellation Global Navigation Satellite System (GNSS) has emerged as a powerful tool not only in positioning, navigation, and timing (PNT), but also in remote sensing of the atmosphere and ionosphere. Both precise positioning and the derivation of atmospheric parameters can benefit from multi-GNSS observations. In this contribution, extensive evaluations are conducted with multi-GNSS datasets collected from 134 globally-distributed ground stations of the International GNSS Service (IGS) Multi-GNSS Experiment (MGEX) network in July 2016. The datasets are processed in six different constellation combinations, i.e., GPS-, GLONASS-, BDS-only, GPS + GLONASS, GPS + BDS, and GPS + GLONASS + BDS + Galileo precise point positioning (PPP). Tropospheric gradients are estimated with eight different temporal resolutions, from 1 h to 24 h, to investigate the impact of estimating high-resolution gradients on position estimates. The standard deviation (STD) is used as an indicator of positioning repeatability. The results show that estimating tropospheric gradients with high temporal resolution can achieve better positioning performance than the traditional strategy in which tropospheric gradients are estimated on a daily basis. Moreover, the impact of estimating tropospheric gradients with different temporal resolutions at various elevation cutoff angles (from 3° to 20°) is investigated. It can be observed that with increasing elevation cutoff angles, the improvement in positioning repeatability is decreased.

The Role of Wave Cyclones in Transporting Boundary Layer Air to the Free Troposphere During the Spring 2001 NASA / TRACE-P Experiment

NASA Technical Reports Server (NTRS)

Fuelberg, Henry E.; Hannan, J. R.; Crawford, J. H.; Sachse, G. W.; Blake, D. R.

2003-01-01

Transport of boundary layer air to the free troposphere by cyclones during NASA's Transport and Chemical Evolution over the Pacific (TRACE-P) experiment is investigated. Airstreams responsible for boundary layer venting are diagnosed using results from a high-resolution meteorological model (MM5) together with in situ and remotely sensed chemical data. Hourly wind data from the MM5 are used to calculate three-dimensional grids of backward air trajectories. A reverse domain filling (RDF) technique then is employed to examine the characteristics of airstreams over the computational domain, and to isolate airstreams ascending from the boundary layer to the free troposphere during the previous 36 hours. Two cases are examined in detail. Results show that airstreams responsible for venting the boundary layer differ considerably from those described by classic conceptual models and in the recent literature. In addition, airstreams sampled by the TRACE-P aircraft are found to exhibit large variability in chemical concentrations. This variability is due to differences in the boundary layer histories of individual airstreams with respect to anthropogenic sources over continental Asia and Japan. Complex interactions between successive wave cyclones also are found to be important in determining the chemical composition of the airstreams. Particularly important is the process of post-cold frontal boundary layer air being rapidly transported offshore and recirculated into ascending airstreams of upstream cyclones.

Lower tropospheric ozone over India and its linkage to the South Asian monsoon

NASA Astrophysics Data System (ADS)

Lu, Xiao; Zhang, Lin; Liu, Xiong; Gao, Meng; Zhao, Yuanhong; Shao, Jingyuan

2018-03-01

Lower tropospheric (surface to 600 hPa) ozone over India poses serious risks to both human health and crops, and potentially affects global ozone distribution through frequent deep convection in tropical regions. Our current understanding of the processes controlling seasonal and long-term variations in lower tropospheric ozone over this region is rather limited due to spatially and temporally sparse observations. Here we present an integrated process analysis of the seasonal cycle, interannual variability, and long-term trends of lower tropospheric ozone over India and its linkage to the South Asian monsoon using the Ozone Monitoring Instrument (OMI) satellite observations for years 2006-2014 interpreted with a global chemical transport model (GEOS-Chem) simulation for 1990-2010. OMI observed lower tropospheric ozone over India averaged for 2006-2010, showing the highest concentrations (54.1 ppbv) in the pre-summer monsoon season (May) and the lowest concentrations (40.5 ppbv) in the summer monsoon season (August). Process analyses in GEOS-Chem show that hot and dry meteorological conditions and active biomass burning together contribute to 5.8 Tg more ozone being produced in the lower troposphere in India in May than January. The onset of the summer monsoon brings ozone-unfavorable meteorological conditions and strong upward transport, which all lead to large decreases in the lower tropospheric ozone burden. Interannually, we find that both OMI and GEOS-Chem indicate strong positive correlations (r = 0.55-0.58) between ozone and surface temperature in pre-summer monsoon seasons, with larger correlations found in high NOx emission regions reflecting NOx-limited production conditions. Summer monsoon seasonal mean ozone levels are strongly controlled by monsoon strengths. Lower ozone concentrations are found in stronger monsoon seasons mainly due to less ozone net chemical production. Furthermore, model simulations over 1990-2010 estimate a mean annual trend of 0

Extratropical Stratosphere-Troposphere Mass Exchange

NASA Technical Reports Server (NTRS)

Schoeberl, Mark R.

2004-01-01

Understanding the exchange of gases between the stratosphere and the troposphere is important for determining how pollutants enter the stratosphere and how they leave. This study does a global analysis of that the exchange of mass between the stratosphere and the troposphere. While the exchange of mass is not the same as the exchange of constituents, you can t get the constituent exchange right if you have the mass exchange wrong. Thus this kind of calculation is an important test for models which also compute trace gas transport. In this study I computed the mass exchange for two assimilated data sets and a GCM. The models all agree that amount of mass descending from the stratosphere to the troposphere in the Northern Hemisphere extra tropics is approx. 10(exp 10) kg/s averaged over a year. The value for the Southern Hemisphere by about a factor of two. ( 10(exp 10) kg of air is the amount of air in 100 km x 100 km area with a depth of 100 m - roughly the size of the D.C. metro area to a depth of 300 feet.) Most people have the idea that most of the mass enters the stratosphere through the tropics. But this study shows that almost 5 times more mass enters the stratosphere through the extra-tropics. This mass, however, is quickly recycled out again. Thus the lower most stratosphere is a mixture of upper stratospheric air and tropospheric air. This is an important result for understanding the chemistry of the lower stratosphere.

Analysis of TES Satellite Ozone Observations from 2005 to 2013 to Understand Global Air Pollution Transport

NASA Astrophysics Data System (ADS)

Kladar, R. M.; Cooper, O. R.

2015-12-01

To better understand the causes of ozone formation and transport, we create and analyze global satellite ozone retrieval products for ground level to upper tropospheric ozone concentrations over the years 2005 to 2013 using the Tropospheric Emission Spectrometer (TES) that rides aboard the NASA Aura satellite. Many global and regional tropospheric ozone trends are not fully understood. Observing many different pressure levels between 1000 hPa to 215 hPa, we focus on the areas where model and other observation strategies disagree, namely the Arabian Peninsula, the Australian outback, and the southern Sahara. We observe (and these areas may be experiencing) unusually high ozone concentrations. We also comment on the historically high ozone areas such as China, Northern India, western Europe, and the western and southern United States and how known phenomena compare to our observations. Many observations confirm known mechanisms of ozone formation and transport, such as the effect of the yearly monsoon cycle in South, Southeast, and East Asia. Others, such as the surprisingly high monthly average concentrations on the Arabian Peninsula and Southern Sahara, deserve more thorough investigation. Several hypotheses for these disagreement areas are put forward here. Lastly, we comment on the usefulness of the TES instrument for trends analysis and future global observations.

Origins of Tropospheric Ozone Interannual Variation (IAV) over Reunion: A Model Investigation

NASA Technical Reports Server (NTRS)

Liu, Junhua; Rodriguez, Jose M.; Thompson, Anne M.; Logan, Jennifer A.; Douglass, Anne R.; Olsen, Mark A.; Steenrod, Stephen D.; Posny, Francoise

2016-01-01

Observations from long-term ozonesonde measurements show robust variations and trends in the evolution of ozone in the middle and upper troposphere over Reunion Island (21.1 degrees South Latitude, 55.5 degrees East Longitude) in June-August. Here we examine possible causes of the observed ozone variation at Reunion Island using hindcast simulations by the stratosphere-troposphere Global Modeling Initiative chemical transport model for 1992-2014, driven by assimilated Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields. Reunion Island is at the edge of the subtropical jet, a region of strong stratospheric-tropospheric exchange. Our analysis implies that the large interannual variation (IAV) of upper tropospheric ozone over Reunion is driven by the large IAV of the stratospheric influence. The IAV of the large-scale, quasi-horizontal wind patterns also contributes to the IAV of ozone in the upper troposphere. Comparison to a simulation with constant emissions indicates that increasing emissions do not lead to the maximum trend in the middle and upper troposphere over Reunion during austral winter implied by the sonde data. The effects of increasing emission over southern Africa are limited tothe lower troposphere near the surface in August-September.

Tropospheric ozone (TOR) trend over three major inland Indian cities: Delhi, Hyderabad and Bangalore

NASA Astrophysics Data System (ADS)

Kulkarni, Pavan S.; Ghude, Sachin D.; Bortoli, D.

2010-10-01

An analysis of tropospheric column ozone using the NASA Langley TOR data during 1979-2005 has been done to investigate the trend over major Indian cities Delhi, Hyderabad and Bangalore. India was under social democratic-based policies before 1990s. Economic Liberalization began in nineties which lead to a significant growth in industrial, energy and transport sectors in major cities. Our analysis shows that there is a systematic increase in the number of months with higher tropospheric ozone values after 1990. A comparison of TOR climatology before and after 1990 over these cities shows evidence of increase in the tropospheric ozone after 1990. Trend obtained from the model shows significant change during monsoon over Delhi and during pre-monsoon and post-monsoon over Hyderabad and Bangalore. The present analysis using TOR technique demonstrates the TOR potential to detect changes in tropospheric ozone over large cities which are impacted by large anthropogenic pollution.

Global Distribution and Sources of Volatile and Nonvolatile Aerosol In the Remote Troposphere

NASA Technical Reports Server (NTRS)

Singh, Hanwant B.; Avery, M.; Viezee, W.; Che, Y.; Tabazadeh, A.; Hamill, P.; Pueschel, R.; Hannan, J. R.; Anderson, B.; Fuelberg, H. E.;

Impacts of bromine and iodine chemistry on tropospheric OH and HO2: comparing observations with box and global model perspectives

NASA Astrophysics Data System (ADS)

Stone, Daniel; Sherwen, Tomás; Evans, Mathew J.; Vaughan, Stewart; Ingham, Trevor; Whalley, Lisa K.; Edwards, Peter M.; Read, Katie A.; Lee, James D.; Moller, Sarah J.; Carpenter, Lucy J.; Lewis, Alastair C.; Heard, Dwayne E.

2018-03-01

The chemistry of the halogen species bromine and iodine has a range of impacts on tropospheric composition, and can affect oxidising capacity in a number of ways. However, recent studies disagree on the overall sign of the impacts of halogens on the oxidising capacity of the troposphere. We present simulations of OH and HO2 radicals for comparison with observations made in the remote tropical ocean boundary layer during the Seasonal Oxidant Study at the Cape Verde Atmospheric Observatory in 2009. We use both a constrained box model, using detailed chemistry derived from the Master Chemical Mechanism (v3.2), and the three-dimensional global chemistry transport model GEOS-Chem. Both model approaches reproduce the diurnal trends in OH and HO2. Absolute observed concentrations are well reproduced by the box model but are overpredicted by the global model, potentially owing to incomplete consideration of oceanic sourced radical sinks. The two models, however, differ in the impacts of halogen chemistry. In the box model, halogen chemistry acts to increase OH concentrations (by 9.8 % at midday at the Cape Verde Atmospheric Observatory), while the global model exhibits a small increase in OH at the Cape Verde Atmospheric Observatory (by 0.6 % at midday) but overall shows a decrease in the global annual mass-weighted mean OH of 4.5 %. These differences reflect the variety of timescales through which the halogens impact the chemical system. On short timescales, photolysis of HOBr and HOI, produced by reactions of HO2 with BrO and IO, respectively, increases the OH concentration. On longer timescales, halogen-catalysed ozone destruction cycles lead to lower primary production of OH radicals through ozone photolysis, and thus to lower OH concentrations. The global model includes more of the longer timescale responses than the constrained box model, and overall the global impact of the longer timescale response (reduced primary production due to lower O3 concentrations

NASA's global differential GPS system and the TDRSS augmentation service for satellites

NASA Technical Reports Server (NTRS)

Bar-Sever, Yoaz; Young, Larry; Stocklin, Frank; Rush, John

2004-01-01

NASA is planning to launch a new service for Earth satellites providing them with precise GPS differential corrections and other ancillary information enabling decimeter level orbit determination accuracy, and nanosecond time-transfer accuracy, onboard, in real-time. The TDRSS Augmentation Service for Satellites (TASS) will broadcast its message on the S-band multiple access channel of NASA's Tracking and Data Relay Satellite System (TDRSS). The satellite's phase array antenna has been configured to provide a wide beam, extending coverage up to 1000 km altitude over the poles. Global coverage will be ensured with broadcast from three or more TDRSS satellites. The GPS differential corrections are provided by the NASA Global Differential GPS (GDGPS) System, developed and operated by NASA's Jet Propulsion Laboratory. The GDGPS System employs a global ground network of more than 70 GPS receivers to monitor the GPS constellation in real time. The system provides real-time estimates of the GPS satellite states, as well as many other real-time products such as differential corrections, global ionospheric maps, and integrity monitoring. The unique multiply redundant architecture of the GDGPS System ensures very high reliability, with 99.999% demonstrated since the inception of the system in Early 2000. The estimated real time GPS orbit and clock states provided by the GDGPS system are accurate to better than 20 cm 3D RMS, and have been demonstrated to support sub-decimeter real time positioning and orbit determination for a variety of terrestrial, airborne, and spaceborne applications. In addition to the GPS differential corrections, TASS will provide real-time Earth orientation and solar flux information that enable precise onboard knowledge of the Earth-fixed position of the spacecraft, and precise orbit prediction and planning capabilities. TASS will also provide 5 seconds alarms for GPS integrity failures based on the unique GPS integrity monitoring service of the

Dial Measurements of Free-Tropospheric Ozone Profiles in Huntsville, AL

NASA Technical Reports Server (NTRS)

Newchurch, Mike; Kuang, Shi; Burris, John; Johnson, Steve; Long, Stephanie

2008-01-01

A tropospheric ozone DIfferential Absorption Lidar (DIAL) system has been developed jointly by NASA and the University of Alabama at Huntsville (UAH). Two separated Nd:YAG pumped dye laser systems produce the laser pulses with wavelengths of 285 and 291 nm at 20 Hz frequency. The receiver is a Newtonian telescope with a 40 cm primary and a two-channel aft optics unit. The detection system currently uses photon counting to facilitate operations at the maximum achievable altitude. This lidar measures free-tropospheric ozone profiles between 4-10 km at Regional Atmospheric Profiling Laboratory for Discovery (RAPCD) in UAH campus (ASL 206 m) under both daytime and nighttime conditions. Frequent coincident ozonesonde flights and theoretical calculations provide evidence to indicate the retrieval accuracy ranges from approx.5% at 4 km to approx.60% at 10 km with 750-m vertical resolution and 30-minute integration. Three Hamamatsu 7400 PMTs and analog detection technique will be added on the current system to extend the measurement to approx.100 m above ground to monitor the PBL and lower tropospheric ozone variations.

Modeling and Observations of the Response of Tropical Tropospheric Ozone to ENSO

NASA Technical Reports Server (NTRS)

Oman, L. D.; Douglass, A. R.; Ziemke, J. R.; Waugh, D. W.; Lang, C.; Rodriquez, J. M.; Nielsen, J. E.

2012-01-01

The El Nino-Southern Oscillation (ENSO) is the dominant mode of tropical variability on interannual time scales. ENSO appears to extend its influence into the chemical composition of the tropical troposphere, Recent results have revealed an ENSO induced wave-1 anomaly in observed tropical tropospheric column ozone, This results in a dipole over the western and eastern tropical Pacific, whereby differencing the two regions produces an ozone anomaly with an extremely high correlation to the Nino 3.4 Index. We have successfully reproduced this result using the Goddard Earth Observing System Version 5 (GEOS-5) general circulation model coupled to a comprehensive stratospheric and tropospheric chemical mechanism forced with observed sea surface temperatures over the past 25 years, An examination of the modeled ozone field reveals the vertical contributions of tropospheric ozone to the column over the western and eastern Pacific region, We will show targeted comparisons with SHADOZ ozonesondes over these regions to provide insight into the vertical structure. Also, comparisons with NASA's Aura satellite Microwave Limb Sounder (MLS) and Tropospheric Emissions Spectrometer (TES) instruments and other appropriate data sets will be shown. In addition, the water vapor response to ENSO will be compared to help illuminate its role relative to dynamics in impacting ozone concentrations. These results indicate that the tropospheric ozone response to ENSO is potentially a very useful chemistry-climate diagnostic and should be considered in future modeling assessments.

Air Quality Forecasts Using the NASA GEOS Model

NASA Technical Reports Server (NTRS)

Keller, Christoph A.; Knowland, K. Emma; Nielsen, Jon E.; Orbe, Clara; Ott, Lesley; Pawson, Steven; Saunders, Emily; Duncan, Bryan; Follette-Cook, Melanie; Liu, Junhua;

Five blind men and the elephant: what can the NASA Aura ozone measurements tell us about stratosphere-troposphere exchange?

NASA Astrophysics Data System (ADS)

Tang, Q.; Prather, M. J.

2012-03-01

We examine whether the individual ozone (O3) measurements from the four Aura instruments can quantify the stratosphere-troposphere exchange (STE) flux of O3, an important term of the tropospheric O3 budget. The level 2 (L2) Aura swath data and the nearly coincident ozone sondes for the years 2005-2006 are compared with the 4-D, high-resolution (1° × 1° × 40-layer × 0.5 h) model simulation of atmospheric ozone for the same period from the University of California, Irvine chemistry transport model (CTM). The CTM becomes a transfer standard for comparing individual profiles from these five, not-quite-coincident measurements of atmospheric ozone. Even with obvious model discrepancies identified here, the CTM can readily quantify instrument-instrument biases in the tropical upper troposphere and mid-latitude lower stratosphere. In terms of STE processes, all four Aura datasets have some skill in identifying stratosphere-troposphere folds, and we find several cases where both model and measurements see evidence of high-O3 stratospheric air entering the troposphere. In many cases identified in the model, however, the individual Aura profile retrievals in the upper troposphere and lower stratosphere show too much noise, as expected from their low sensitivity and coarse vertical resolution at and below the tropopause. These model-measurement comparisons of individual profiles do provide some level of confidence in the model-derived STE O3 flux, but it will be difficult to integrate this flux from the satellite data alone.

Tropospheric ozone observations - How well can we assess tropospheric ozone changes?

NASA Astrophysics Data System (ADS)

Tarasick, D. W.; Galbally, I. E.; Ancellet, G.; Leblanc, T.; Wallington, T. J.; Ziemke, J. R.; Steinbacher, M.; Stähelin, J.; Vigouroux, C.; Hannigan, J. W.; García, O. E.; Foret, G.; Zanis, P.; Liu, X.; Weatherhead, E. C.; Petropavlovskikh, I. V.; Worden, H. M.; Osman, M.; Liu, J.; Lin, M.; Cooper, O. R.; Schultz, M. G.; Granados-Muñoz, M. J.; Thompson, A. M.; Cuesta, J.; Dufour, G.; Thouret, V.; Hassler, B.; Trickl, T.

2017-12-01

Since the early 20th century, measurements of ozone in the free troposphere have evolved and changed. Data records have different uncertainties and biases, and differ with respect to coverage, information content, and representativeness. Almost all validation studies employ ECC ozonesondes. These have been compared to UV-absorption measurements in a number of intercomparison studies, and show a modest ( 1-5%) high bias in the troposphere, with an uncertainty of 5%, but no evidence of a change over time. Umkehr, lidar, FTIR, and commercial aircraft all show modest low biases relative to the ECCs, and so -- if the ECC biases are transferable -- all agree within 1σ with the modern UV standard. Relative to the UV standard, Brewer-Mast sondes show a 20% increase in sensitivity from 1970-1995, while Japanese KC sondes show an increase of 5-10%. Combined with the shift of the global ozonesonde network to ECCs, this can induce a false positive trend, in analyses based on sonde data. Passive sounding methods -- Umkehr, FTIR and satellites -- have much lower vertical resolution than active methods, and this can limit the attribution of trends. Satellite biases are larger than those of other measurement systems, ranging between -10% and +20%, and standard deviations are large: about 10-30%, versus 5-10% for sondes, aircraft, lidar and ground-based FTIR. There is currently little information on measurement drift for satellite measurements of tropospheric ozone. This is an evident area of concern if satellite retrievals are used for trend studies. The importance of ECC sondes as a transfer standard for satellite validation means that efforts to homogenize existing records, by correcting for known changes and by adopting strict standard operating procedures, should continue, and additional research effort should be put into understanding and reducing sonde uncertainties. Representativeness is also a potential source of large errors, which are difficult to quantify. The global

Application of troposphere model from NWP and GNSS data into real-time precise positioning

NASA Astrophysics Data System (ADS)

Wilgan, Karina; Hadas, Tomasz; Kazmierski, Kamil; Rohm, Witold; Bosy, Jaroslaw

2016-04-01

The tropospheric delay empirical models are usually functions of meteorological parameters (temperature, pressure and humidity). The application of standard atmosphere parameters or global models, such as GPT (global pressure/temperature) model or UNB3 (University of New Brunswick, version 3) model, may not be sufficient, especially for positioning in non-standard weather conditions. The possible solution is to use regional troposphere models based on real-time or near-real time measurements. We implement a regional troposphere model into the PPP (Precise Point Positioning) software GNSS-WARP (Wroclaw Algorithms for Real-time Positioning) developed at Wroclaw University of Environmental and Life Sciences. The software is capable of processing static and kinematic multi-GNSS data in real-time and post-processing mode and takes advantage of final IGS (International GNSS Service) products as well as IGS RTS (Real-Time Service) products. A shortcoming of PPP technique is the time required for the solution to converge. One of the reasons is the high correlation among the estimated parameters: troposphere delay, receiver clock offset and receiver height. To efficiently decorrelate these parameters, a significant change in satellite geometry is required. Alternative solution is to introduce the external high-quality regional troposphere delay model to constrain troposphere estimates. The proposed model consists of zenith total delays (ZTD) and mapping functions calculated from meteorological parameters from Numerical Weather Prediction model WRF (Weather Research and Forecasting) and ZTDs from ground-based GNSS stations using the least-squares collocation software COMEDIE (Collocation of Meteorological Data for Interpretation and Estimation of Tropospheric Pathdelays) developed at ETH Zurich.

Acetone in theGlobal Troposphere: Its Possible Role as a Global Source of PAN

NASA Technical Reports Server (NTRS)

Singh, H. B.; Kanakidou, M.

1994-01-01

Oxygenated hydrocarbons are thought to be important components of the atmosphere but, with the exception of formaldehyde, very little about their distribution and fate is known. Aircraft measurements of acetone (CH3COCH3), PAN (CH3CO3NO2) and other organic species (e. g. acetaldehyde, methanol and ethanol) have been performed over the Pacific, the southern Atlantic, and the subarctic atmospheres. Sampled areas extended from 0 to 12 km altitude over latitudes of 70 deg N to 40 deg S. All measurements are based on real time in-situ analysis of cryogenically preconcentrated air samples. Substantial concentrations of these oxygenated species (10-2000 ppt) have been observed at all altitudes and geographical locations in the troposphere. Important sources include, emissions from biomass burning, plant and vegetation, secondary oxidation of primary non-methane hydrocarbons, and man-made emissions. Direct measurements within smoke plumes have been used to estimate the biomass burning source. Photochemistry studies are used to suggest that acetone could provide a major source of peroxyacetyl radicals in the atmosphere and play an important role in sequestering reactive nitrogen. Model calculations show that acetone photolysis contributes significantly to PAN formation in the middle and upper troposphere.

Tropospheric ozone and aerosols measured by airborne lidar during the 1988 Arctic boundary layer experiment

NASA Technical Reports Server (NTRS)

Browell, Edward V.; Butler, Carolyn F.; Kooi, Susan A.

1991-01-01

Ozone (O3) and aerosol distributions were measured from an aircraft using a differential absorption lidar (DIAL) system as part of the 1988 NASA Global Tropospheric Experiment - Arctic Boundary Layer Experiment (ABLE-3A) to study the sources and sinks of gases and aerosols over the tundra regions of Alaska during the summer. The tropospheric O3 budget over the Arctic was found to be strongly influenced by stratospheric intrusions. Regions of low aerosol scattering and enhanced O3 mixing ratios were usually correlated with descending air from the upper troposphere or lower stratosphere. Several cases of continental polar air masses were examined during the experiment. The aerosol scattering associated with these air masses was very low, and the atmospheric distribution of aerosols was quite homogeneous for those air masses that had been transported over the ice for greater than or = 3 days. The transition in O3 and aerosol distributions from tundra to marine conditions was examined several times. The aerosol data clearly show an abrupt change in aerosol scattering properties within the mixed layer from lower values over the tundra to generally higher values over the water. The distinct differences in the heights of the mixed layers in the two regions was also readily apparent. Several cases of enhanced O3 were observed during ABLE-3 in conjunction with enhanced aerosol scattering in layers in the free atmosphere. Examples are presented of the large scale variations of O3 and aerosols observed with the airborne lidar system from near the surface to above the tropopause over the Arctic during ABLE-3.

Real-Time Tropospheric Product Establishment and Accuracy Assessment in China

NASA Astrophysics Data System (ADS)

Chen, M.; Guo, J.; Wu, J.; Song, W.; Zhang, D.

2018-04-01

Tropospheric delay has always been an important issue in Global Navigation Satellite System (GNSS) processing. Empirical tropospheric delay models are difficult to simulate complex and volatile atmospheric environments, resulting in poor accuracy of the empirical model and difficulty in meeting precise positioning demand. In recent years, some scholars proposed to establish real-time tropospheric product by using real-time or near-real-time GNSS observations in a small region, and achieved some good results. This paper uses real-time observing data of 210 Chinese national GNSS reference stations to estimate the tropospheric delay, and establishes ZWD grid model in the country wide. In order to analyze the influence of tropospheric grid product on wide-area real-time PPP, this paper compares the method of taking ZWD grid product as a constraint with the model correction method. The results show that the ZWD grid product estimated based on the national reference stations can improve PPP accuracy and convergence speed. The accuracy in the north (N), east (E) and up (U) direction increase by 31.8 %,15.6 % and 38.3 %, respectively. As with the convergence speed, the accuracy of U direction experiences the most improvement.

The Impact of Estimating High-Resolution Tropospheric Gradients on Multi-GNSS Precise Positioning

PubMed Central

Zhou, Feng; Li, Xingxing; Li, Weiwei; Chen, Wen; Dong, Danan; Wickert, Jens; Schuh, Harald

2017-01-01

Benefits from the modernized US Global Positioning System (GPS), the revitalized Russian GLObal NAvigation Satellite System (GLONASS), and the newly-developed Chinese BeiDou Navigation Satellite System (BDS) and European Galileo, multi-constellation Global Navigation Satellite System (GNSS) has emerged as a powerful tool not only in positioning, navigation, and timing (PNT), but also in remote sensing of the atmosphere and ionosphere. Both precise positioning and the derivation of atmospheric parameters can benefit from multi-GNSS observations. In this contribution, extensive evaluations are conducted with multi-GNSS datasets collected from 134 globally-distributed ground stations of the International GNSS Service (IGS) Multi-GNSS Experiment (MGEX) network in July 2016. The datasets are processed in six different constellation combinations, i.e., GPS-, GLONASS-, BDS-only, GPS + GLONASS, GPS + BDS, and GPS + GLONASS + BDS + Galileo precise point positioning (PPP). Tropospheric gradients are estimated with eight different temporal resolutions, from 1 h to 24 h, to investigate the impact of estimating high-resolution gradients on position estimates. The standard deviation (STD) is used as an indicator of positioning repeatability. The results show that estimating tropospheric gradients with high temporal resolution can achieve better positioning performance than the traditional strategy in which tropospheric gradients are estimated on a daily basis. Moreover, the impact of estimating tropospheric gradients with different temporal resolutions at various elevation cutoff angles (from 3° to 20°) is investigated. It can be observed that with increasing elevation cutoff angles, the improvement in positioning repeatability is decreased. PMID:28368346

Prototype of NASA's Global Precipitation Measurement Mission Ground Validation System

NASA Technical Reports Server (NTRS)

Schwaller, M. R.; Morris, K. R.; Petersen, W. A.

2007-01-01

NASA is developing a Ground Validation System (GVS) as one of its contributions to the Global Precipitation Mission (GPM). The GPM GVS provides an independent means for evaluation, diagnosis, and ultimately improvement of GPM spaceborne measurements and precipitation products. NASA's GPM GVS consists of three elements: field campaigns/physical validation, direct network validation, and modeling and simulation. The GVS prototype of direct network validation compares Tropical Rainfall Measuring Mission (TRMM) satellite-borne radar data to similar measurements from the U.S. national network of operational weather radars. A prototype field campaign has also been conducted; modeling and simulation prototypes are under consideration.

Effects of Subsonic Aircraft on Aerosols and Cloudiness in the Upper Troposphere and Lower Stratosphere

NASA Technical Reports Server (NTRS)

Detwiler, Andrew G.

1997-01-01

This work was accomplished primarily by Allison G. Wozniak, a graduate research assistant who has completed the Master of Science in Meteorology program at the South Dakota School of Mines and Technology. Ms. Wozniak was guided and assisted in her work by L. R. Johnson and the principal investigator. Invaluable guidance was supplied by Dr. James Holdeman, NASA Lewis, the manager of the Global Atmospheric Sampling Program (GASP). Dr. Gregory Nastrom, St. Cloud (Minnesota) State University, who has used the GASP data set to provide unique views of the distribution of ozone, clouds, and atmospheric waves and turbulence, in the upper troposphere/lower stratosphere region, was also extremely helpful. Finally, Dr. Terry Deshler, University of Wyoming, supplied observations from the university's upper atmospheric monitoring program for comparison to GASP data.

Global distribution and sources of volatile and nonvolatile aerosol in the remote troposphere

NASA Astrophysics Data System (ADS)

Singh, Hanwant B.; Anderson, B. E.; Avery, M. A.; Viezee, W.; Chen, Y.; Tabazadeh, A.; Hamill, P.; Pueschel, R.; Fuelberg, H. E.; Hannan, J. R.

2002-06-01

Airborne measurements of aerosol (condensation nuclei, CN) and selected trace gases made over areas of the North Atlantic Ocean during Subsonic Assessment (SASS) Ozone and Nitrogen Oxide Experiment (SONEX) (October/November 1997), the south tropical Pacific Ocean during Pacific Exploratory Mission (PEM)-Tropics A (September/October 1996), and PEM-Tropics B (March/April 1999) have been analyzed. The emphasis is on interpreting variations in the number densities of fine (>17 nm) and ultrafine (>8 nm) aerosol in the upper troposphere (8-12 km). These data suggest that large number densities of highly volatile CN (104 - 105 cm-3) are present in the upper troposphere and particularly over the tropical/subtropical region. CN number densities in all regions are largest when the atmosphere is devoid of nonvolatile particles. Through marine convection and long-distance horizontal transport, volatile CN originating from the tropical/subtropical regions can frequently impact the abundance of aerosol in the middle and upper troposphere at mid to high latitudes. Nonvolatile aerosols behave in a manner similar to tracers of combustion (CO) and photochemical pollution (peroxyacetylnitrate (PAN)), implying a continental pollution source from industrial emissions or biomass burning. In the upper troposphere we find that volatile and nonvolatile aerosol number densities are inversely correlated. Results from an aerosol microphysical model suggest that the coagulation of fine volatile particles with fewer but larger nonvolatile particles, of principally anthropogenic origin, is one possible explanation for this relationship. In some instances the larger nonvolatile particles may also directly remove precursors (e.g., H2SO4) and effectively stop nucleation.

Oxidation of mercury by bromine in the subtropical Pacific free troposphere

NASA Astrophysics Data System (ADS)

Gratz, L. E.; Ambrose, J. L.; Jaffe, D. A.; Shah, V.; Jaeglé, L.; Stutz, J.; Festa, J.; Spolaor, M.; Tsai, C.; Selin, N. E.; Song, S.; Zhou, X.; Weinheimer, A. J.; Knapp, D. J.; Montzka, D. D.; Flocke, F. M.; Campos, T. L.; Apel, E.; Hornbrook, R.; Blake, N. J.; Hall, S.; Tyndall, G. S.; Reeves, M.; Stechman, D.; Stell, M.

2015-12-01

Mercury is a global toxin that can be introduced to ecosystems through atmospheric deposition. Mercury oxidation is thought to occur in the free troposphere by bromine radicals, but direct observational evidence for this process is currently unavailable. During the 2013 Nitrogen, Oxidants, Mercury and Aerosol Distributions, Sources and Sinks campaign, we measured enhanced oxidized mercury and bromine monoxide in a free tropospheric air mass over Texas. We use trace gas measurements, air mass back trajectories, and a chemical box model to confirm the origin and chemical history of the sampled air mass. We find the presence of elevated oxidized mercury to be consistent with oxidation of elemental mercury by bromine atoms in this subsiding upper tropospheric air mass within the subtropical Pacific High, where dry atmospheric conditions are conducive to oxidized mercury accumulation. Our results support the role of bromine as the dominant oxidant of mercury in the upper troposphere.

Monthly Representations of Mid-Tropospheric Carbon Dioxide from the Atmospheric Infrared Sounder

NASA Technical Reports Server (NTRS)

Pagano, Thomas S.; Olsen, Edward T.; Chahine, Moustafa T.; Ruzmaikin, Alexander; Nguyen, Hai; Jiang, Xun

2011-01-01

The Atmospheric Infrared Sounder (AIRS) on NASA's Earth Observing System Aqua spacecraft was launched in May of 2002 and acquires hyperspectral infrared spectra used to generate a wide range of atmospheric products including temperature, water vapor, and trace gas species including carbon dioxide. Here we present monthly representations of global concentrations of mid-tropospheric carbon dioxide produced from 8 years of data obtained by AIRS between the years of 2003 and 2010. We define them as "representations" rather than "climatologies" to reflect that the files are produced over a relatively short time period and represent summaries of the Level 3 data. Finally, they have not yet been independently validated. The representations have a horizontal resolution of 2.0 deg x 2.5 deg (Latitude x Longitude) and faithfully reproduce the original 8 years of monthly L3 CO2 concentrations with a standard deviation of 1.48 ppm and less than 2% outliers. The representations are intended for use in studies of the global general circulation of CO2 and identification of anomalies in CO2 typically associated with atmospheric transport. The seasonal variability and trend found in the AIRS CO2 data are discussed.

Impact of Stratospheric Ozone Distribution on Features of Tropospheric Circulation

NASA Astrophysics Data System (ADS)

Barodka, Siarhei; Krasouski, Aliaksandr; Mitskevich, Yaroslav; Shalamyansky, Arkady

2016-04-01

In this work we study connections between stratospheric ozone distribution and general circulation patterns in the troposphere and aim to investigate the causal relationship between them, including the practical side of the influence of stratospheric ozone on tropospheric medium-range weather and regional climate. Analysis of several decades of observational data, which has been performed at the A.I. Voeikov Main Geophysical Observatory, suggests a clear relation between the stratospheric ozone distribution, upper stratospheric temperature field and planetary-scale air-masses boundaries in the troposphere [1]. Furthermore, it has been shown that each global air-mass, which can be attributed to the corresponding circulation cell in a conceptual model of tropospheric general circulation, has a distinct "regime" of ozone vertical distribution in the stratosphere [1-3]. Proceeding from atmospheric reanalyses combined with satellite and ground-based observations, we study time evolution of the upper-level frontal zones (stationary fronts) with the relevant jet streams, which can be treated as boundaries of global air-masses, in connection with the tropopause height and distribution of ozone in the stratosphere. For that, we develop an algorithm for automated identification of jet streams, stationary fronts and tropopause surface from gridded data (reanalyses or modelling results), and apply it for several cases associated with rapid changes in the stratospheric temperature and ozone fields, including SSW events over Eastern Siberia. Aiming to study the causal relationship between the features of tropospheric circulation and changes in the stratospheric ozone field, we estimate the time lag between these categories of processes on different time scales. Finally, we discuss the possibility to use the elementary circulation mechanisms classification (by B.L. Dzerdzeevski) in connection with analysis of the stratospheric ozone field and the relevant stratosphere-troposphere

Origins of tropospheric ozone interannual variation over Réunion: A model investigation

NASA Astrophysics Data System (ADS)

Liu, Junhua; Rodriguez, Jose M.; Thompson, Anne M.; Logan, Jennifer A.; Douglass, Anne R.; Olsen, Mark A.; Steenrod, Stephen D.; Posny, Françoise

2016-01-01

Observations from long-term ozonesonde measurements show robust variations and trends in the evolution of ozone in the middle and upper troposphere over Réunion Island (21.1°S, 55.5°E) in June-August. Here we examine possible causes of the observed ozone variation at Réunion Island using hindcast simulations by the stratosphere-troposphere Global Modeling Initiative chemical transport model for 1992-2014, driven by assimilated Modern-Era Retrospective Analysis for Research and Applications meteorological fields. Réunion Island is at the edge of the subtropical jet, a region of strong stratospheric-tropospheric exchange. Our analysis implies that the large interannual variation (IAV) of upper tropospheric ozone over Réunion is driven by the large IAV of the stratospheric influence. The IAV of the large-scale, quasi-horizontal wind patterns also contributes to the IAV of ozone in the upper troposphere. Comparison to a simulation with constant emissions indicates that increasing emissions do not lead to the maximum trend in the middle and upper troposphere over Réunion during austral winter implied by the sonde data. The effects of increasing emission over southern Africa are limited to the lower troposphere near the surface in August-September.

The Role of DYNAMO in Situ Observations in Improving NASA Ceres-like Daily Surface and Atmospheric Radiative Flux Estimates

NASA Technical Reports Server (NTRS)

Wang, Hailan; Su, Wenying; Loeb, Norman G.; Achuthavarier, Deepthi; Schubert, Siegfried D.

2017-01-01

The daily surface and atmospheric radiative fluxes from NASA Clouds and the Earths RadiantEnergy System (CERES) Synoptic 1 degree (SYN1deg) Ed3A are among the most widely used data to studycloud-radiative feedback. The CERES SYN1deg data are based on Fu-Liou radiative transfer computations thatuse specific humidity (Q) and air temperature (T) from NASA Global Modeling and Assimilation Office (GMAO)reanalyses as inputs and are therefore subject to the quality of those fields. This study uses in situ Q and Tobservations collected during the Dynamics of the Madden-Julian Oscillation (DYNAMO) field campaign toaugment the input stream used in the NASA GMAO reanalysis and assess the impact on the CERES dailysurface and atmospheric longwave estimates. The results show that the assimilation of DYNAMOobservations considerably improves the vertical profiles of analyzed Q and T over and near DYNAMO stationsby moistening and warming the lower troposphere and upper troposphere and drying and cooling themid-upper troposphere. As a result of these changes in Q and T, the computed CERES daily surface downwardlongwave flux increases by about 5 W m(exp -2), due mainly to the warming and moistening in the lowertroposphere; the computed daily top-of-atmosphere (TOA) outgoing longwave radiation increases by2-3 W m(exp -2) during dry periods only. Correspondingly, the estimated local atmospheric longwave radiativecooling enhances by about 5 W m(exp -2) (7-8 W m(exp -2)) during wet (dry) periods. These changes reduce the bias inthe CERES SYN1deg-like daily longwave estimates at both the TOA and surface and represent animprovement over the DYNAMO region.

Dynamical response of the summer MLT to tropospheric global warming: Results from a mechanistic GCM with resolved gravity waves

NASA Astrophysics Data System (ADS)

Becker, E.

2009-04-01

The sensitivity of the mesosphere and lower thermosphere (MLT) to climate variability of the troposphere is largely controlled by the generation, propagation, and dissipation of gravity waves (GWs). Conventional climate models cannot fully describe this sensitivity since GWs must be parameterized by invoking strong assumptions. Since the Eliassen-Palm flux (EPF) of low-frequency inertia GWs is negligible, the main contribution to the EPF divergence at high latitudes of the MLT is due to mid- and high-frequency GWs with periods of a few hours or less. In order to resolve at least a good portion of these waves in a GCM, a high spatial resolution from the boundary layer to the lower thermosphere is required. Furthermore, both the generation and dissipation of resolved GWs is expected to depend strongly on the details of the parameterization of turbulence. The present study proposes a new formulation of the Kuehlungsborn mechanistic general circulation model (KMCM) with high spatial resolution and Smagorinsky-type horizontal and vertical diffusion coefficients that are both scaled by the Richardson criterion. This model version allows for an explicit and self-consistent simulation of the gravity-wave drag in the MLT. A sensitivity experiment is conducted in which the main changes associated with tropospheric global warming are imposed by the differential heating, i.e., reduced static stability in the lower troposphere along with a reduced equator-to-pole temperature difference and enhanced latent heating in the intertropical convergence zone. These changes result in both a stronger Lorenz energy cycle and enhanced gravity-wave activity in the upper troposphere at middle latitudes. The altered gravity-wave sources result in the following remote effects in the summer MLT: downward shift of the residual circulation, as well as lower temperatures and reduced easterlies below the mesopause. These changes are consistent with enhanced turbulent diffusion and dissipation below

21 Layer troposphere-stratosphere climate model

NASA Technical Reports Server (NTRS)

Rind, D.; Suozzo, R.; Lacis, A.; Russell, G.; Hansen, J.

1984-01-01

The global climate model is extended through the stratosphere by increasing the vertical resolution and raising the rigid model top to the 0.01 mb (75 km) level. The inclusion of a realistic stratosphere is necessary for the investigation of the climate effects of stratospheric perturbations, such as changes of ozone, aerosols or solar ultraviolet irradiance, as well as for studying the effect on the stratosphere of tropospheric climate changes. The observed temperature and wind patterns throughout the troposphere and stratosphere are simulated. In addition to the excess planetary wave amplitude in the upper stratosphere, other model deficiences include the Northern Hemisphere lower stratospheric temperatures being 5 to 10 C too cold in winter at high latitudes and the temperature at 50 to 60 km altitude near the equator are too cold. Methods of correcting these deficiencies are discussed.

Differential Absorption Lidar to Measure Sub-Hourly Variation of Tropospheric Ozone Profiles

NASA Technical Reports Server (NTRS)

Kuang, Shi; Burris, John F.; Newchurch, Michael J.; Johnson, Steve; Long, Stephanie

2009-01-01

A tropospheric ozone Differential Absorption Lidar (DIAL) system, developed jointly by the University of Alabama at Huntsville and NASA, is making regular observations of ozone vertical distributions between 1 and 8 km with two receivers under both daytime and nighttime conditions using lasers at 285 and 291 nm. This paper describes the lidar system and analysis technique with some measurement examples. An iterative aerosol correction procedure reduces the retrieval error arising from differential aerosol backscatter in the lower troposphere. Lidar observations with coincident ozonesonde flights demonstrate that the retrieval accuracy ranges from better than 10% below 4 km to better than 20% below 8 km with 750-m vertical resolution and 10-min temporal integration

Atlas of the global distribution of atmospheric heating during the global weather experiment

NASA Technical Reports Server (NTRS)

Schaack, Todd K.; Johnson, Donald R.

1991-01-01

Global distributions of atmospheric heating for the annual cycle of the Global Weather Experiment are estimated from the European Centre for Medium-Range Weather Forecasts (ECMWF) Level 3b data set. Distributions of monthly, seasonally, and annually averaged heating are presented for isentropic and isobaric layers within the troposphere and for the troposphere as a whole. The distributions depict a large-scale structure of atmospheric heating that appears spatially and temporally consistent with known features of the global circulation and the seasonal evolution.

Radicals and Aerosols in the Troposphere and Lower Stratosphere

NASA Astrophysics Data System (ADS)

Volkamer, Rainer; Koenig, Theodore; Dix, Barbara

2016-06-01

The remote tropical free troposphere (FT) is one of the most relevant atmospheric environments on Earth. About 75% of the global tropospheric O3 and CH4 loss occurs at tropical latitudes. Tropospheric bromine and iodine catalytically destroy tropospheric O3, oxidize atmospheric mercury, and modify oxidative capacity, and aerosols. Oxygenated VOCs (OVOC) modify HOx (= OH + HO2), NOx (= NO + NO2), tropospheric O3, aerosols, and are a sink for BrOx (= Br + BrO). Until recently, atmospheric models were untested for lack of vertically resolved measurements of BrO and IO radicals in the tropical troposphere. BrO and IO are highly reactive trace gases. Even very low concentrations (parts per trillion; 1 pptv = 10-12 volume mixing ratio) can significantly modify the lifetime of climate active gases, and determine (bromine) the rate limiting step of mercury oxidation in air (that is washed out, and subsequently bio-accumulates in fish). Analytical challenges arise when these radicals modify in sampling lines. Sensitive yet robust, portable, and inherently calibrated measurements directly in the open atmosphere have recently been demonstrated by means of limb-measurements of scattered solar photons by the University of Colorado Airborne Multi-AXis DOAS instrument (CU AMAX-DOAS) from research aircraft. The CU AMAX-DOAS instrument is optimized to (1) locate BrO, IO and glyoxal (a short lived OVOC) in the troposphere, (2) decouple stratospheric absorbers, (3) maximize sensitivity at instrument altitude, (4) facilitate altitude control and (5) enable observations over a wide range of solar zenith angles. Further, (6) the filling-in of Fraunhofer lines (Ring-effect) by Raman Scattering offers interesting opportunities for radiative closure studies to assess the effects of aerosols on Climate.

AO/NAO Response to Climate Change. 1; Respective Influences of Stratospheric and Tropospheric Climate Changes

NASA Technical Reports Server (NTRS)

Rind, D.; Perlwitz, J.; Lonergan, P.

2005-01-01

We utilize the GISS Global Climate Middle Atmosphere Model and 8 different climate change experiments, many of them focused on stratospheric climate forcings, to assess the relative influence of tropospheric and stratospheric climate change on the extratropical circulation indices (Arctic Oscillation, AO; North Atlantic Oscillation, NAO). The experiments are run in two different ways: with variable sea surface temperatures (SSTs) to allow for a full tropospheric climate response, and with specified SSTs to minimize the tropospheric change. The results show that tropospheric warming (cooling) experiments and stratospheric cooling (warming) experiments produce more positive (negative) AO/NAO indices. For the typical magnitudes of tropospheric and stratospheric climate changes, the tropospheric response dominates; results are strongest when the tropospheric and stratospheric influences are producing similar phase changes. Both regions produce their effect primarily by altering wave propagation and angular momentum transports, but planetary wave energy changes accompanying tropospheric climate change are also important. Stratospheric forcing has a larger impact on the NAO than on the AO, and the angular momentum transport changes associated with it peak in the upper troposphere, affecting all wavenumbers. Tropospheric climate changes influence both the A0 and NAO with effects that extend throughout the troposphere. For both forcings there is often vertical consistency in the sign of the momentum transport changes, obscuring the difference between direct and indirect mechanisms for influencing the surface circulation.

The 1980 stratospheric-tropospheric exchange experiment

NASA Technical Reports Server (NTRS)

Margozzi, A. P. (Editor)

1983-01-01

Data are presented from the Stratospheric-Tropospheric Water Vapor Exchange Experiment. Measurements were made during 11 flights of the NASA U-2 aircraft which provided data from horizontal traverser and samplings in and about the tops of extensive cirrus-anvil clouds produced by overshooting cumulus turrets. Aircraft measurements were made of water vapor, ozone, ambient and cloud top temperature, fluorocarbons, nitrous oxide, nitric acid, aerosols, and ice crystal populations. Balloonsondes were flown about twice daily providing data on ozone, wind fields, pressure and temperature to altitudes near 30 km. Satellite photography provided detailed cloud and cloud top temperature information. Descriptions of individual experiments and detailed compilations of all results are provided.

New Global Precipitation Products and Data Service Updates at the NASA GES DISC

NASA Technical Reports Server (NTRS)

Liu, Z.; Ostrenga, D.; Savtchenko, A.; DeShong, B.; Greene, M.; Vollmer, B.; Kempler, S.

2016-01-01

This poster describes recent updates of the ongoing GPM data service activities at the NASA Goddard Earth Sciences (GES) Data and Information Services Center(DISC) to facilitate access and exploration of GPM, TRMM and other NASA precipitation datasets for the global community. The poster contains -Updates on GPM products and data services -New features in Giovanni for precipitation data visualization -Precipitation data and service outreach activities.

NASA's East and Southeast Asia Initiatives: BASE-ASIA and EAST-AIRE

NASA Technical Reports Server (NTRS)

Tsay, S.; Maring, H.

2005-01-01

Airborne dust from northern China influences air quality and regional climate in Asia during springtime. However, with the economic growth in China, increased emission of particulate air pollutants from industrial and vehicular sources will not only impact the earth's radiation balance, but also adversely affect human health year round. In addition, both of dust and aerosol pollutants can be transported swiftly across the Pacific affecting North America within a few days. Asian dust and pollutant aerosols can be detected by their colored appearance using current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and by sunphotometers deployed on the surface of the earth. Biomass burning has been a regular practice for land clearing and conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Globally significant sources of greenhouse gases (eg., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning. These gases influence the Earth-atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play a role in determining cloud lifetime and precipitation, altering the earth's radiation and water budgets. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds; the hydrological cycle; land surface reflectivity and emissivity; and ecosystem biodiversity and stability. Two NASA initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented. The objectives of these initiatives is to

The Global Exploration Roadmap and its significance for NASA

NASA Astrophysics Data System (ADS)

Laurini, K. C.; Gerstenmaier, W. H.

2014-08-01

The Global Exploration Roadmap reflects the collaborative effort of twelve space agencies to define a long-term human space exploration strategy which provides substantial benefits for improving the quality of life on Earth and is implementable and sustainable. Such a strategy is a necessary precondition to the government investments required to enable the challenging and rewarding missions that extend human presence into the solar system. The article introduces the international strategy and elaborates on NASA's leadership role in shaping that strategy. The publication of the roadmap, a reflection of the space landscape and multilateral agency-level dialog over the last four years, allows NASA to demonstrate its commitment to leading a long-term space exploration endeavor that delivers benefits, maintains strategic human spaceflight capabilities and expands human presence in space, with human missions to the surface of Mars as a driving goal. The road mapping process has clearly demonstrated the complementary interests of the participants and the potential benefits that can be gained through cooperation among nations to achieve a common goal. The present US human spaceflight policy is examined and it is shown that the establishment of a sustainable global space exploration strategy is fully consistent with that policy.

Remote Sensing of Tropospheric Pollution from Space

NASA Technical Reports Server (NTRS)

Fishman, Jack; Bowman, Kevin W.; Burrows, John P.; Chance, Kelly V.; Edwards, David P.; Martin, Randall V.; Morris, Gary A.; Pierce, R. Bradley; Ziemke, Jerald R.; Al-Saadi, Jassim A.;

Origins of tropospheric ozone interannual variation (IAV) over Réunion: A model investigation.

PubMed

Liu, Junhua; Rodriguez, Jose M; Thompson, Anne M; Logan, Jennifer A; Douglass, Anne R; Olsen, Mark A; Steenrod, Stephen D; Posny, Francoise

2016-01-16

Observations from long-term ozonesonde measurements show robust variations and trends in the evolution of ozone in the middle and upper troposphere over Réunion Island (21.1°S, 55.5°E) in June-August. Here we examine possible causes of the observed ozone variation at Réunion Island using hindcast simulations by the stratosphere-troposphere Global Modeling Initiative chemical transport model (GMI-CTM) for 1992-2014, driven by assimilated Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields. Réunion Island is at the edge of the subtropical jet, a region of strong stratospheric-tropospheric exchange (STE). Our analysis implies that the large interannual variation (IAV) of upper tropospheric ozone over Réunion is driven by the large IAV of the stratospheric influence. The IAV of the large-scale, quasi-horizontal wind patterns also contributes to the IAV of ozone in the upper troposphere. Comparison to a simulation with constant emissions indicates that increasing emissions do not lead to the maximum trend in the middle and upper troposphere over Réunion during austral winter implied by the sonde data. The effects of increasing emission over southern Africa are limited to the lower troposphere near the surface in August - September.

Origins of tropospheric ozone interannual variation (IAV) over Réunion: A model investigation

PubMed Central

Liu, Junhua; Rodriguez, Jose M.; Thompson, Anne M.; Logan, Jennifer A.; Douglass, Anne R.; Olsen, Mark A.; Steenrod, Stephen D.; Posny, Francoise

2018-01-01

Observations from long-term ozonesonde measurements show robust variations and trends in the evolution of ozone in the middle and upper troposphere over Réunion Island (21.1°S, 55.5°E) in June-August. Here we examine possible causes of the observed ozone variation at Réunion Island using hindcast simulations by the stratosphere-troposphere Global Modeling Initiative chemical transport model (GMI-CTM) for 1992–2014, driven by assimilated Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields. Réunion Island is at the edge of the subtropical jet, a region of strong stratospheric-tropospheric exchange (STE). Our analysis implies that the large interannual variation (IAV) of upper tropospheric ozone over Réunion is driven by the large IAV of the stratospheric influence. The IAV of the large-scale, quasi-horizontal wind patterns also contributes to the IAV of ozone in the upper troposphere. Comparison to a simulation with constant emissions indicates that increasing emissions do not lead to the maximum trend in the middle and upper troposphere over Réunion during austral winter implied by the sonde data. The effects of increasing emission over southern Africa are limited to the lower troposphere near the surface in August – September. PMID:29657911

Enabling a Science Support Structure for NASAs Global Hawk UASs

NASA Technical Reports Server (NTRS)

Sullivan, Donald V.

2014-01-01

In this paper we describe the information technologies developed by NASA for the Winter/Spring 2013/2014, and Fall 2014, NASA Earth Venture Campaigns, Hurricane and Severe Storm Sentinel (HS3) and Airborne Tropical TRopopause EXperiment (ATTREX). These campaigns utilized Global Hawk UAS vehicles equipped at the NASA Armstrong (previously Dryden) Flight Research Facility (AFRC), Edwards Air Force Base, California, and operated from there, the NASA Wallops Flight Facility (WFF), Virginia, and Anderson Air Force Base (AAFB), Guam. Part of this enabling infrastructure utilized a layer 2 encrypted terrestrial Virtual Local Area Network (VLAN) that, at times, spanned greater than ten thousand miles (AAFB <-> AFRC <-> WFF) and was routed over geosynchronous Ku band communication Satellites directly to the aircraft sensor network. This infrastructure enabled seamless hand off between Satellites, and Satellite ground stations in Guam, California and Virginia, so allowing simultaneous Aircraft Command and Control and Science operations from remote locations. Additionally, we will describe the other elements of this infrastructure, from on-board geo-enabled databases, to real time communications directly from the instruments (in some cases, more than twelve were carried, and simultaneously operated, on one aircraft) to the researchers and other interested parties, world wide.

Compendium of NASA data base for the global tropospheric experiment's Transport and Atmospheric Chemistry Near the Equator-Atlantic (TRACE-A)

NASA Technical Reports Server (NTRS)

Gregory, Gerald L.; Scott, A. Donald, Jr.

1995-01-01

This compendium describes aircraft data that are available from NASA's Transport and Atmospheric Chemistry near the Equator - Atlantic (TRACE-A) conducted in September/October 1992. The broad objectives of TRACE-A were to study chemical processes and long-range transport associated with South American and African continental outflow during periods of widespread vegetation burning, and to understand the ozone enhancements observed from satellite data measured over the southern tropical Atlantic Ocean during the September/October time period. Flight experiments were conducted from Brazil, South Africa, Namibia, and the Ascension Island. This document provides a representation of aircraft data that are available from NASA Langley's Distributed Active Archive Center (DAAC). The data format of time series and altitude profile plots is not intended to support original analyses, but to assist the reader in identifying data that are of interest. This compendium is for only the NASA aircraft data. The DAAC data base includes numerous supporting data-meteorological products, results from surface studies, satellite observations, and data from sonde releases.

Impact of tropospheric sulphate aerosols on the terrestrial carbon cycle

NASA Astrophysics Data System (ADS)

Eliseev, Alexey V.

2015-01-01

Tropospheric sulphate aerosols (TSAs) may oxidise the photosynthesising tissues if they are taken up by plants. A parameterisation of this impact of tropospheric sulphate aerosols (TSAs) on the terrestrial gross primary production is suggested. This parameterisation is implemented into the global Earth system model developed at the A.M. Obukhov Institute of the Atmospheric Physics, Russian Academy of Sciences (IAP RAS CM). With this coupled model, the simulations are performed which are forced by common anthropogenic and natural climate forcings based on historical reconstructions followed by the RCP 8.5 scenario. The model response to sulphate aerosol loading is subdivided into the climatic (related to the influence of TSA on the radiative transport in the atmosphere) and ecological (related to the toxic influence of sulphate aerosol on terrestrial plants) impacts. We found that the former basically dominates over the latter on a global scale and modifies the responses of the global vegetation and soil carbon stocks to external forcings by 10%. At a regional scale, however, ecological impact may be as much important as the climatic one.

NASA Global GNSS Network (GGN) Status and Plans

NASA Astrophysics Data System (ADS)

Doelger, S.; Sklar, J.; Blume, F.; Meertens, C. M.; Mattioli, G. S.

2015-12-01

UNAVCO, in conjunction with JPL, is responsible for monitoring the 62 GNSS permanent stations, which include 88 GPS receivers, which comprise the NASA Global GNSS Network (GGN). These sites represent approximately 16% of the ~400 International GNSS Service (IGS) stations, and they provide a globally distributed GNSS network to support NASA operations and its commitments to GGOS. UNAVCO provides data flow monitoring, trouble-shooting, station installation, maintenance, as well as engineering services to improve the capabilities and performance of station infrastructure. Activities this past year include the installation of a geodetic quality wellhead monument for the new SEY2 station to replace SEY1, which is mounted on a UCSD seismic station in the Seychelles Islands. SEY1 will be removed soon to accommodate planned maintenance and upgrades by UCSD. Data from both SEY1 and SEY2 are being collected concurrently until maintenance begins. MRTG (Multi Router Traffic Grapher), a tool to aid in characterizing bandwidth usage and to identify communications problems, is now being used to monitor data throughput at 7 stations where VSAT or radio telemetry are used, including: ABPO; AREQ; FALK; GUAM; HARV; ISPA; QUIN; and STHL. Aging computers are being replaced with new hardware running Linux CentOS. These are semi-ruggedized low power solid-state systems built to endure challenging environments. With the aid of on-site collaborators, systems are now deployed at: FALK; CUSV; KELY; STHL; SANT; and ZAMB. Last, 4 new GPS stations were deployed for NASA's Space Geodesy Project (SGP); three of which (KOKF, KOKG, and KOKR) are located at Koke'e Park Geophysical Observatory on Kauai, Hawai'i, and HAL1 at the Haleakala observatory complex on Maui, Hawai'i. A campaign system was set up at Koke'e in order to sample data quality to determine if an additional station would be viable. Planning is ongoing for deployment of several new stations next year at McDonald Observatory (TX).

Global Sentry: NASA/USRA high altitude reconnaissance aircraft design, volume 2

NASA Technical Reports Server (NTRS)

Alexandru, Mona-Lisa; Martinez, Frank; Tsou, Jim; Do, Henry; Peters, Ashish; Chatsworth, Tom; Yu, YE; Dhillon, Jaskiran

1990-01-01

The Global Sentry is a high altitude reconnaissance aircraft design for the NASA/USRA design project. The Global Sentry uses proven technologies, light-weight composites, and meets the R.F.P. requirements. The mission requirements for the Global Sentry are described. The configuration option is discussed and a description of the final design is given. Preliminary sizing analyses and the mass properties of the design are presented. The aerodynamic features of the Global Sentry are described along with the stability and control characteristics designed into the flight control system. The performance characteristics are discussed as is the propulsion installation and system layout. The Global Sentry structural design is examined, including a wing structural analysis. The cockpit, controls and display layouts are covered. Manufacturing is covered and the life cost estimation. Reliability is discussed. Conclusions about the current Global Sentry design are presented, along with suggested areas for future engineering work.

Overview of NASA's Observations for Global Air Quality

NASA Astrophysics Data System (ADS)

Kaye, J. A.

2015-12-01

Observations of pollutants are central to the study of air quality. Much focus has been placed on local-scale observations that can help specific geographic areas document their air quality issues, plan abatement strategies, and understand potential impacts. In addition, long-range atmospheric transport of pollutants can cause downwind regions to not meet attainment standards. Satellite observations have shed significant light on air quality from local to regional to global scales, especially for pollutants such as ozone, aerosols, carbon monoxide, sulfur dioxide, and nitrogen dioxide. These observations have made use of multiple techniques and in some cases multiple satellite sensors. The satellite observations are complemented by surface observations, as well as atmospheric (in situ) observations typically made as part of focused airborne field campaigns. The synergy between satellite observations and field campaigns has been an important theme for recent and upcoming activities and plans. In this talk, a review of NASA's investments in observations relevant to global air quality will be presented, with examples given for a range of pollutants and measurement approaches covering the last twenty-five years. These investments have helped build national and international collaborations such that the global satellite community is now preparing to deploy a constellation of satellites that together will provide fundamental advances in global observations for air quality.

Access NASA Satellite Global Precipitation Data Visualization on YouTube

NASA Astrophysics Data System (ADS)

Liu, Z.; Su, J.; Acker, J. G.; Huffman, G. J.; Vollmer, B.; Wei, J.; Meyer, D. J.

2017-12-01

Since the satellite era began, NASA has collected a large volume of Earth science observations for research and applications around the world. Satellite data at 12 NASA data centers can also be used for STEM activities such as disaster events, climate change, etc. However, accessing satellite data can be a daunting task for non-professional users such as teachers and students because of unfamiliarity of terminology, disciplines, data formats, data structures, computing resources, processing software, programing languages, etc. Over the years, many efforts have been developed to improve satellite data access, but barriers still exist for non-professionals. In this presentation, we will present our latest activity that uses the popular online video sharing web site, YouTube, to access visualization of global precipitation datasets at the NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC). With YouTube, users can access and visualize a large volume of satellite data without necessity to learn new software or download data. The dataset in this activity is the 3-hourly TRMM (Tropical Rainfall Measuring Mission) Multi-satellite Precipitation Analysis (TMPA). The video consists of over 50,000 data files collected since 1998 onwards, covering a zone between 50°N-S. The YouTube video will last 36 minutes for the entire dataset record (over 19 years). Since the time stamp is on each frame of the video, users can begin at any time by dragging the time progress bar. This precipitation animation will allow viewing precipitation events and processes (e.g., hurricanes, fronts, atmospheric rivers, etc.) on a global scale. The next plan is to develop a similar animation for the GPM (Global Precipitation Measurement) Integrated Multi-satellitE Retrievals for GPM (IMERG). The IMERG provides precipitation on a near-global (60°N-S) coverage at half-hourly time interval, showing more details on precipitation processes and development, compared to the 3

Reference NO2 calibration system for ground-based intercomparisons during NASA's GTE/CITE 2 mission

NASA Technical Reports Server (NTRS)

Fried, Alan; Nunnermacker, Linda; Cadoff, Barry; Sams, Robert; Yates, Nathan

1990-01-01

An NO2 calibration system, based on a permeation device and a two-stage dynamic dilution system, was designed, constructed, and characterized at the National Bureau of Standards. In this system, calibrant flow entering the second stage was controlled without contacting a metal flow controller, and permeation oven temperature and flow were continuously maintained, even during transport. The system performance and the permeation emission rate were characterized by extensive laboratory tests. This system was capable of accurately delivering known NO2 concentrations in the ppbv and sub-ppbv concentration range with a total uncertainty of approximately 10 percent. The calibration system was placed on board NASA research aircraft at both the Wallops Island and Ames research facilities. There it was employed as the reference standard in NASA's Global Tropospheric Experiment/Chemical Instrumental Test and Evaluation 2 mission in August 1986.

Convective Troposphere-Stratosphere Transport in the Tropics and Hydration by ice Crystals Geysers

NASA Astrophysics Data System (ADS)

Pommereau, J.

2008-12-01

Twenty-five years ago the suggestion was made by Danielsen of direct fast convective penetration of tropospheric air in the stratosphere over land convective systems. Although the existence of the mechanism is accepted, it was thought to be rare and thus its contribution to Troposphere-Stratosphere Transport (TST) of chemical species and water vapour at global scale unimportant at global scale. In contrast to this assumption, observations of temperature, water vapour, ice particles, long-lived tropospheric species during HIBISCUS, TROCCINOX and SCOUT-O3 over Brazil, Australia and Africa and more recently CALIPSO aerosols observations suggest that it is a general feature of tropical land convective regions in the summer. Particularly relevant to stratospheric water vapour is the observation of geyser like ice crystals in the TTL over overshooting events which may result in the moistening of the stratosphere. Although such events successfully captured by small scale Cloud-Resolving Models may have a significant impact on stratospheric ozone chemistry and climate, they are currently totally ignored by NWPs, CTMs and CCMs. Several recent balloon and aircraft observations of overshoots and CRM simulations will be shown illustrating the mechanism, as well as observations from a variety of satellites suggesting a significant impact at global scale.

An Observationally Constrained Evaluation of the Oxidative Capacity in the Tropical Western Pacific Troposphere

NASA Technical Reports Server (NTRS)

Nicely, Julie M.; Anderson, Daniel C.; Canty, Timothy P.; Salawitch, Ross J.; Wolfe, Glenn M.; Apel, Eric C.; Arnold, Steve R.; Atlas, Elliot L.; Blake, Nicola J.; Bresch, James F.;

Tropospheric Ozone during the TRACE-P Mission: Comparison between TOMS Satellite Retrievals and Aircraft Lidar Data, March 2001

NASA Technical Reports Server (NTRS)

Frolov, A. D.; Thompson, A. M.; Hudson, R. D.; Browell, E. V.; Oltmans, S. J.; Witte, J. C.; Bhartia, P. K. (Technical Monitor)

2002-01-01

Over the past several years, we have developed two new tropospheric ozone retrievals from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMS-direct method ('TDOT' = TOMS Direct Ozone in the Troposphere) represents a new algorithm that uses TOMS radiances directly to extract tropospheric ozone in regions of constant stratospheric ozone. It is not geographically restricted, using meteorological regimes as the basis for classifying TOMS radiances and for selecting appropriate comparison data. TDOT is useful where tropospheric ozone displays high mixing ratios and variability characteristic of pollution. Some of these episodes were observed downwind of Asian biomass burning during the TRACE-P (Transport and Atmospheric Chemical Evolution-Pacific) field experiment in March 2001. This paper features comparisons among TDOT tropospheric ozone column depth, integrated uv-DIAL measurements made from NASA's DC-8, and ozonesonde data.

The Making of NASA's Global Selfie: 100+ Countries, Thousands of Photos

NASA Image and Video Library

2014-05-22

The 3.2 gigapixel Global Selfie mosaic, hosted by GigaPan, was made with 36,422 individual images that were posted to social media sites on or around Earth Day, April 22, 2014. Zoom in and find yours here: 1.usa.gov/SnR7ki Credit: NASA The 3.2 gigapixel Global Selfie mosaic, hosted by GigaPan, was made with 36,422 individual images that were posted to social media sites on or around Earth Day, April 22, 2014. Zoom in and find yours here: 1.usa.gov/SnR7ki

Laser Pulse Production for NASA's Global Ecosystem Dynamics Investigation (GEDI) Lidar

NASA Technical Reports Server (NTRS)

Stysley, Paul R.; Coyle, D. Barry; Clarke, Greg B.; Frese, Erich; Blalock, Gordon; Morey, Peter; Kay, Richard B.; Poulios, Demetrios; Hersh, Michael

2016-01-01

The Lasers and Electro-Optics Branch at Goddard Space Flight Center has been tasked with building the Lasers for the Global Ecosystems Dynamics Investigation (GEDI) Lidar Mission, to be installed on the Japanese Experiment Module (JEM) on the International Space Station (ISS)1. GEDI will use three NASA-developed lasers, each coupled with a Beam Dithering Unit (BDU) to produce three sets of staggered footprints on the Earth's surface to accurately measure global biomass. We will report on the design, assembly progress, test results, and delivery process of this laser system.

Laser Pulse Production for NASA's Global Ecosystem Dynamics Investigation (GEDI) Lidar

NASA Technical Reports Server (NTRS)

Stysley, Paul R.; Coyle, D. Barry; Clarke, Greg B.; Frese, Erich; Blalock, Gordon; Morey, Peter; Kay, Richard B.; Poulios, Demetrios; Hersh, Michael

2016-01-01

The Lasers and Electro-Optics Branch at Goddard Space Flight Center has been tasked with building the Lasers for the Global Ecosystems Dynamics Investigation (GEDI) Lidar Mission, to be installed on the Japanese Experiment Module (JEM) on the International Space Station (ISS). GEDI will use three NASA-developed lasers, each coupled with a Beam Dithering Unit (BDU) to produce three sets of staggered footprints on the Earth's surface to accurately measure global biomass. We will report on the design, assembly progress, test results, and delivery process of this laser system.

Static Stability in the Global Upper Troposphere and Lower Stratosphere: Observations of Long-term Mean Structure and Variability using GPS Radio Occultation Data

NASA Astrophysics Data System (ADS)

Grise, K. M.; Thompson, D. W.; Birner, T.

2009-12-01

Static stability is a fundamental dynamical quantity that measures the vertical temperature stratification of the atmosphere. The long-term mean static stability field is characterized by the well-known transition from low values in the troposphere to high values in the stratosphere. However, the magnitude and structure of fine-scale static stability features near the tropopause are difficult to discern in temperature data with low vertical resolution. In this study, the authors apply over six years of high vertical resolution Global Positioning System radio occultation temperature profiles to document the long-term mean structure and variability of static stability in the global upper troposphere and lower stratosphere (UTLS). The results of this study demonstrate that a shallow but pronounced maximum in static stability exists just above the tropopause at all latitudes (i.e., the “tropopause inversion layer,” or TIL). This study also uncovers two novel aspects of static stability in the global UTLS. In the tropical lower stratosphere, the results reveal a unique vertically and horizontally varying static stability structure, with maxima located at ~17 km and ~19 km. The upper feature peaks during the NH cold season and has its largest magnitude between 10 and 15 degrees latitude in both hemispheres; the lower feature exhibits a weaker seasonal cycle and is centered at the Equator. The results also demonstrate that the strength of the TIL is closely tied to stratospheric dynamic variability. The magnitude of the TIL is enhanced following sudden stratospheric warmings in the polar regions and the easterly phase of the quasi-biennial oscillation in the tropics.

Static Stability in the Global Upper Troposphere and Lower Stratosphere: Observations of Long-term Mean Structure and Variability using GPS Radio Occultation Data

NASA Astrophysics Data System (ADS)

Grise, Kevin M.; Thompson, David W. J.; Birner, Thomas

2010-05-01

Static stability is a fundamental dynamical quantity that measures the vertical temperature stratification of the atmosphere. The long-term mean static stability field is characterized by the well-known transition from low values in the troposphere to high values in the stratosphere. However, the magnitude and structure of fine-scale static stability features near the tropopause are difficult to discern in temperature data with low vertical resolution. In this study, the authors apply over six years of high vertical resolution Global Positioning System radio occultation temperature profiles to document the long-term mean structure and variability of static stability in the global upper troposphere and lower stratosphere (UTLS). The results of this study demonstrate that a shallow but pronounced maximum in static stability exists just above the tropopause at all latitudes (i.e., the "tropopause inversion layer," or TIL). This study also uncovers two novel aspects of static stability in the global UTLS. In the tropical lower stratosphere, the results reveal a unique vertically and horizontally varying static stability structure, with maxima located at ~17 km and ~19 km. The upper feature peaks during the NH cold season and has its largest magnitude between 10 and 15 degrees latitude in both hemispheres; the lower feature exhibits a weaker seasonal cycle and is centered at the Equator. The results also demonstrate that the strength of the TIL is closely tied to stratospheric dynamic variability. The magnitude of the TIL is enhanced following sudden stratospheric warmings in the polar regions and the easterly phase of the quasi-biennial oscillation in the tropics.

PM2.5 and tropospheric ozone in China: overview of situation and responses

NASA Astrophysics Data System (ADS)

Zhang, Hua

This work reviewed the observational status of PM2.5 and tropospheric ozone in China. It told us the observational facts on the ratios of typical types of aerosol components to the total PM2.5/PM10, and daily and seasonal change of near surface ozone concentration at different cities of China; the global concentration distribution of tropospheric ozone observed by satellite in 2010-2013 was also given for comparison; the PM2.5 concentration distribution and their seasonal change in China region were simulated by an aerosol chemistry-global climate modeling system. Different contribution from five kinds of aerosols to the simulated PM2.5 was analyzed. Then, it linked the emissions of aerosol and greenhouse gases and their radiative forcing and thus gave their climatic effect by reducing their emissions on the basis of most recently published IPCC AR5. Finally it suggested policies on reducing emissions of short-lived climate pollutants (SLCPs) (such as PM2.5 and tropospheric ozone) in China from protecting both climate and environment.

Access NASA Satellite Global Precipitation Data Visualization on YouTube

NASA Technical Reports Server (NTRS)

Liu, Z.; Su, J.; Acker, J.; Huffman, G.; Vollmer, B.; Wei, J.; Meyer, D.

2017-01-01

Since the satellite era began, NASA has collected a large volume of Earth science observations for research and applications around the world. The collected and archived satellite data at 12 NASA data centers can also be used for STEM education and activities such as disaster events, climate change, etc. However, accessing satellite data can be a daunting task for non-professional users such as teachers and students because of unfamiliarity of terminology, disciplines, data formats, data structures, computing resources, processing software, programming languages, etc. Over the years, many efforts including tools, training classes, and tutorials have been developed to improve satellite data access for users, but barriers still exist for non-professionals. In this presentation, we will present our latest activity that uses a very popular online video sharing Web site, YouTube (https://www.youtube.com/), for accessing visualizations of our global precipitation datasets at the NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC). With YouTube, users can access and visualize a large volume of satellite data without the necessity to learn new software or download data. The dataset in this activity is a one-month animation for the GPM (Global Precipitation Measurement) Integrated Multi-satellite Retrievals for GPM (IMERG). IMERG provides precipitation on a near-global (60 deg. N-S) coverage at half-hourly time interval, providing more details on precipitation processes and development compared to the 3-hourly TRMM (Tropical Rainfall Measuring Mission) Multisatellite Precipitation Analysis (TMPA, 3B42) product. When the retro-processing of IMERG during the TRMM era is finished in 2018, the entire video will contain more than 330,000 files and will last 3.6 hours. Future plans include development of flyover videos for orbital data for an entire satellite mission or project. All videos, including the one-month animation, will be uploaded and

NASA LIVE Creating a Global Classroom

ERIC Educational Resources Information Center

Townes-Young, Katrina L.; Ewing, Virginia R.

2005-01-01

This article describes NASA LIVE (Learning through Interactive Videoconferencing Experiences), a free series of videoconferencing programs produced by NASA's Langley Center for Distance Learning in Hampton, Virginia. NASA LIVE is designed for K-12 educators and students, allowing teachers and students to interact with NASA experts in a virtual…

Remote sensing of tropospheric gases and aerosols with airborne DIAL system

NASA Technical Reports Server (NTRS)

Browell, E. V.

1983-01-01

The multipurpose airborne DIAL system developed at NASA Langley Research Center is characterized, and the published results of tropospheric O3, H2O, and aerosol-backscatter remote-sensing experiments performed in 1980 and 1981 are summarized. The system comprises two tunable dye lasers pumped by frequency-doubled Nd:YAG lasers, dielectric-coated steering optics, a 36-cm-diameter Cassegrain receiver telescope, gateable photomultiplier tubes, and a minicomputer data-processing unit for real-time calculation of gas concentrations and backscattering profiles. The transmitted energy of the 100-microsec-separated dye-laser pulses is 40, 80, or 50 mJ/pulse at around 300, 600, or 720-nm wavelength, respectively. Good agreement was found between DIAL-remote-sensed and in-situ H2O and O3 profiles of the lower troposphere and O3 profiles of the tropopause region, and the usefulness of DIAL backscattering measurements in the study of boundary-layer and tropospheric dynamics is demonstrated. The feasibility of DIAL sensing of power-plant or urban plume SO2, of urban-area (or rural-area column-content) NO2, and of temperature and H2O (simultaneously using a third laser) has been suggested by simulation studies.

NASA/JPL CLIMATE DAY: Middle and High School Students Get the Facts about Global Climate Change

NASA Astrophysics Data System (ADS)

Richardson, Annie; Callery, Susan; Srinivasan, Margaret

2013-04-01

In 2007, NASA Headquarters requested that Earth Science outreach teams brainstorm new education and public outreach activities that would focus on the topic of global climate change. At the Jet Propulsion Laboratory (JPL), Annie Richardson, outreach lead for the Ocean Surface Topography missions came up with the idea of a "Climate Day", capitalizing on the popular Earth Day name and events held annually throughout the world. JPL Climate Day would be an education and public outreach event whose objectives are to provide the latest scientific facts about global climate change - including the role the ocean plays in it, the contributions that NASA/JPL satellites and scientists make to the body of knowledge on the topic, and what we as individuals can do to promote global sustainability. The primary goal is that participants get this information in a fun and exciting environment, and walk away feeling empowered and capable of confidently engaging in the global climate debate. In March 2008, JPL and its partners held the first Climate Day event. 950 students from seven school districts heard from five scientists; visited exhibits, and participated in hands-on-activities. Pleased with the outcome, we organized JPL Climate Day 2010 at the Pasadena Convention Center in Pasadena, California, reaching more than 1700 students, teachers, and members of the general public over two days. Taking note of this successful model, NASA funded a multi-center, NASA Climate Day proposal in 2010 to expand Climate Day nation-wide. The NASA Climate Day proposal is a three-pronged project consisting of a cadre of Earth Ambassadors selected from among NASA-affiliated informal educators; a "Climate Day Kit" consisting of climate-related electronic resources available to the Earth Ambassadors; and NASA Climate Day events to be held in Earth Ambassador communities across the United States. NASA/JPL continues to host the original Climate Day event and in 2012 held its 4th event, at the Pasadena

A NASA Space Sleuth Hunts the Trail of Earth Water

NASA Image and Video Library

2009-08-13

This vertical profile view from the Tropospheric Emission Spectrometer TES instrument on NASA Aura satellite depicts the distribution of water vapor molecules over Earth tropics across one transect of the satellite orbit on January 6, 2006.

The NASA Earth Science Flight Program: an update

NASA Astrophysics Data System (ADS)

Neeck, Steven P.

2015-10-01

examples are the NASA-ISRO Synthetic Aperture Radar (NISAR), Surface Water and Ocean Topography (SWOT), ICESat-2, SAGE III on ISS, Gravity Recovery and Climate Experiment Follow On (GRACE FO), Tropospheric Emissions: Monitoring of Pollution (TEMPO), Cyclone Global Navigation Satellite System (CYGNSS), ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS), and Global Ecosystem Dynamics Investigation (GEDI) Lidar missions. An overview of plans and current status will be presented.

Surface and Tropospheric Ozone Profile Variability (1999-2014) at the TOLNet Site of Table Mountain, California

NASA Astrophysics Data System (ADS)

Granados-Muñoz, M. J.; Leblanc, T.

2015-12-01

Ozone in the lower troposphere acts as an air pollutant affecting human health and vegetation. Tropospheric ozone sources and variability are not yet fully identified or understood and recent studies reveal the importance of increasing the number of tropospheric ozone profiling stations and long term measurements. As part of the international monitoring network NDACC, and the U.S.-based network TOLNet, a differential absorption lidar has been performing tropospheric ozone measurements (3-20 km) at the JPL Table Mountain Facility (TMF, California) since 1999, and surface measurements have been performed since 2013 with a UV photometric analyzer. Because of the site's geolocation and high elevation, background tropospheric ozone, unaffected by the boundary layer dynamics and local anthropogenic emissions of ozone precursors, is usually expected. However, transboundary ozone contributions such as stratospheric intrusions and Asian pollution episodes are frequently detected. In this study, a statistical analysis of the 14-year lidar profiles and the 2.5-year surface data is presented. Seasonal, interannual and diurnal variability and its possible causes (e.g. El Nino/La Nina events, North American Monsoon) are investigated. Together with the high elevation surface data gathered at TMF, surface data from ARB stations nearby are analyzed to understand the lowermost tropospheric ozone variability component. The frequency of stratospheric intrusions and Asian pollution episodes reaching the Western U.S. is also examined in an attempt to understand the relative contribution of each process to the observed variability throughout the troposphere. The Table Mountain surface and lidar measurements are expected to contribute significantly to the emerging system of global air quality observations, and to the improvement of global and regional data assimilation and modeling.

Inter-technique validation of tropospheric slant total delays

NASA Astrophysics Data System (ADS)

Kačmařík, Michal; Douša, Jan; Dick, Galina; Zus, Florian; Brenot, Hugues; Möller, Gregor; Pottiaux, Eric; Kapłon, Jan; Hordyniec, Paweł; Václavovic, Pavel; Morel, Laurent

2017-06-01

An extensive validation of line-of-sight tropospheric slant total delays (STD) from Global Navigation Satellite Systems (GNSS), ray tracing in numerical weather prediction model (NWM) fields and microwave water vapour radiometer (WVR) is presented. Ten GNSS reference stations, including collocated sites, and almost 2 months of data from 2013, including severe weather events were used for comparison. Seven institutions delivered their STDs based on GNSS observations processed using 5 software programs and 11 strategies enabling to compare rather different solutions and to assess the impact of several aspects of the processing strategy. STDs from NWM ray tracing came from three institutions using three different NWMs and ray-tracing software. Inter-techniques evaluations demonstrated a good mutual agreement of various GNSS STD solutions compared to NWM and WVR STDs. The mean bias among GNSS solutions not considering post-fit residuals in STDs was -0.6 mm for STDs scaled in the zenith direction and the mean standard deviation was 3.7 mm. Standard deviations of comparisons between GNSS and NWM ray-tracing solutions were typically 10 mm ± 2 mm (scaled in the zenith direction), depending on the NWM model and the GNSS station. Comparing GNSS versus WVR STDs reached standard deviations of 12 mm ± 2 mm also scaled in the zenith direction. Impacts of raw GNSS post-fit residuals and cleaned residuals on optimal reconstructing of GNSS STDs were evaluated at inter-technique comparison and for GNSS at collocated sites. The use of raw post-fit residuals is not generally recommended as they might contain strong systematic effects, as demonstrated in the case of station LDB0. Simplified STDs reconstructed only from estimated GNSS tropospheric parameters, i.e. without applying post-fit residuals, performed the best in all the comparisons; however, it obviously missed part of tropospheric signals due to non-linear temporal and spatial variations in the troposphere. Although the

Processes Affecting Tropospheric Ozone over Africa

NASA Technical Reports Server (NTRS)

Diab, Roseanne D.; Thompson, Anne M.

2004-01-01

This is a Workshop Report prepared for Eos, the weekly AGU magazine, The workshop took place between 26-28 January 2004 at the University of KwaZulu-Natal in Durban, South Africa and was attended by 26 participants (http//www.geography.und.ac.za). Considerable progress has been made in ozone observations except for northern Africa (large data gaps) and west Africa (to be covered by the French-sponsored AMMA program). The present-day ozone findings were evaluated and reviewed by speakers using Aircraft data (MOZAIC program), NASA satellites (MOPITT, TRMM, TOMS) and ozone soundings (SHADOZ). Besides some ozone gaps, there are challenges posed by the need to assess the relative strengths of photochemical and dynamic influences on the tropospheric ozone budget. Biogenic, biofuels, biomass burning sources of ozone precursors remain highly uncertain. Recent findings (by NASA's Chatfield and Thompson, using satellite and sounding data) show significant impact of Indian Ocean pollution on African ozone. European research on pollutants over the Mediterranean and the middle east, that suggests that ozone may be exported to Africa from these areas, also needs to be considered.

Laser Sounder for Global Measurement of CO2 Concentrations in the Troposphere from Space

NASA Technical Reports Server (NTRS)

Abshire, James B.; Riris, Haris; Kawa, S. Randy; Sun, Xiaoli; Chen, Jeffrey; Stephen, Mark A.; Collatz, G. James; Mao, Jianping; Allan, Graham

2007-01-01

Measurements of tropospheric CO2 abundance with global-coverage, a few hundred km spatial and monthly temporal resolution are needed to quantify processes that regulate CO2 storage by the land and oceans. The Orbiting Carbon Observatory (OCO) is the first space mission focused on atmospheric CO2 for measuring total column CO, and O2 by detecting the spectral absorption in reflected sunlight. The OCO mission is an essential step, and will yield important new information about atmospheric CO2 distributions. However there are unavoidable limitations imposed by its measurement approach. These include best accuracy only during daytime at moderate to high sun angles, interference by cloud and aerosol scattering, and limited signal from CO2 variability in the lower tropospheric CO2 column. We have been developing a new laser-based technique for the remote measurement of the tropospheric CO2 concentrations from orbit. Our initial goal is to demonstrate a lidar technique and instrument technology that will permit measurements of the CO2 column abundance in the lower troposphere from aircraft. Our final goal is to develop a space instrument and mission approach for active measurements of the CO2 mixing ratio at the 1-2 ppmv level. Our technique is much less sensitive to cloud and atmospheric scattering conditions and would allow continuous measurements of CO2 mixing ratio in the lower troposphere from orbit over land and ocean surfaces during day and night. Our approach is to use the 1570nm CO2 band and a 3-channel laser absorption spectrometer (i.e. lidar used an altimeter mode), which continuously measures at nadir from a near polar circular orbit. The approach directs the narrow co-aligned laser beams from the instrument's lasers toward nadir, and measures the energy of the laser echoes reflected from land and water surfaces. It uses several tunable fiber laser transmitters which allowing measurement of the extinction from a single selected CO2 absorption line in the 1570

Applying Kalman filtering to investigate tropospheric effects in VLBI

NASA Astrophysics Data System (ADS)

Soja, Benedikt; Nilsson, Tobias; Karbon, Maria; Heinkelmann, Robert; Liu, Li; Lu, Cuixian; Andres Mora-Diaz, Julian; Raposo-Pulido, Virginia; Xu, Minghui; Schuh, Harald

2014-05-01

Very Long Baseline Interferometry (VLBI) currently provides results, e.g., estimates of the tropospheric delays, with a delay of more than two weeks. In the future, with the coming VLBI2010 Global Observing System (VGOS) and increased usage of electronic data transfer, it is planned that the time between observations and results is decreased. This may, for instance, allow the integration of VLBI-derived tropospheric delays into numerical weather prediction models. Therefore, future VLBI analysis software packages need to be able to process the observational data autonomously in near real-time. For this purpose, we have extended the Vienna VLBI Software (VieVS) by a Kalman filter module. This presentation describes the filter and discusses its application for tropospheric studies. Instead of estimating zenith wet delays as piece-wise linear functions in a least-squares adjustment, the Kalman filter allows for more sophisticated stochastic modeling. We start with a random walk process to model the time-dependent behavior of the zenith wet delays. Other possible approaches include the stochastic model described by turbulence theory, e.g. the model by Treuhaft and Lanyi (1987). Different variance-covariance matrices of the prediction error, depending on the time of the year and the geographic latitude, have been tested. In winter and closer to the poles, lower variances and covariances are appropriate. The horizontal variations in tropospheric delays have been investigated by comparing three different strategies: assumption of a horizontally stratified troposphere, using north and south gradients modeled, e.g., as Gauss-Markov processes, and applying a turbulence model assuming correlations between observations in different azimuths. By conducting Monte-Carlo simulations of current standard VLBI networks and of future VGOS networks, the different tropospheric modeling strategies are investigated. For this purpose, we use the simulator module of VieVS which takes into

Aerosol indirect effect on tropospheric ozone via lightning

NASA Astrophysics Data System (ADS)

Yuan, Tianle; Remer, Lorraine A.; Bian, Huisheng; Ziemke, Jerald R.; Albrecht, Rachel; Pickering, Kenneth E.; Oreopoulos, Lazaros; Goodman, Steven J.; Yu, Hongbin; Allen, Dale J.

2012-09-01

Tropospheric ozone (O3) is a pollutant and major greenhouse gas and its radiative forcing is still uncertain. Inadequate understanding of processes related to O3 production, in particular those natural ones such as lightning, contributes to this uncertainty. Here we demonstrate a new effect of aerosol particles on O3production by affecting lightning activity and lightning-generated NOx (LNOx). We find that lightning flash rate increases at a remarkable rate of 30 times or more per unit of aerosol optical depth. We provide observational evidence that indicates the observed increase in lightning activity is caused by the influx of aerosols from a volcano. Satellite data analyses show O3is increased as a result of aerosol-induced increase in lightning and LNOx, which is supported by modle simulations with prescribed lightning change. O3production increase from this aerosol-lightning-ozone link is concentrated in the upper troposphere, where O3 is most efficient as a greenhouse gas. In the face of anthropogenic aerosol increase our findings suggest that lightning activity, LNOx and O3, especially in the upper troposphere, have all increased substantially since preindustrial time due to the proposed aerosol-lightning-ozone link, which implies a stronger O3 historical radiative forcing. Aerosol forcing therefore has a warming component via its effect on O3 production and this component has mostly been ignored in previous studies of climate forcing related to O3and aerosols. Sensitivity simulations suggest that 4-8% increase of column tropospheric ozone, mainly in the tropics, is expected if aerosol-lighting-ozone link is parameterized, depending on the background emission scenario. We note, however, substantial uncertainties remain on the exact magnitude of aerosol effect on tropospheric O3 via lightning. The challenges for obtaining a quantitative global estimate of this effect are also discussed. Our results have significant implications for understanding past and

Aerosol indirect effect on tropospheric ozone via lightning

NASA Astrophysics Data System (ADS)

Yuan, T.; Remer, L. A.; Bian, H.; Ziemke, J. R.; Albrecht, R. I.; Pickering, K. E.; Oreopoulos, L.; Goodman, S. J.; Yu, H.; Allen, D. J.

2012-12-01

Tropospheric ozone (O3) is a pollutant and major greenhouse gas and its radiative forcing is still uncertain. The unresolved difference between modeled and observed natural background O3 concentrations is a key source of the uncertainty. Here we demonstrate remarkable sensitivity of lightning activity to aerosol loading with lightning activity increasing more than 30 times per unit of aerosol optical depth over our study area. We provide observational evidence that indicates the observed increase in lightning activity is caused by the influx of aerosols from a volcano. Satellite data analyses suggest O3 is increased as a result of aerosol-induced increase in lightning and lightning produced NOx. Model simulations with prescribed lightning change corroborate the satellite data analysis. This aerosol-O3 connection is achieved via aerosol increasing lightning and thus lightning produced nitrogen oxides. This aerosol-lightning-ozone link provides a potential physical mechanism that may account for a part of the model-observation difference in background O3 concentration. More importantly, O3 production increase from this link is concentrated in the upper troposphere, where O3 is most efficient as a greenhouse gas. Both of these implications suggest a stronger O3 historical radiative forcing. This introduces a new pathway, through which increasing in aerosols from pre-industrial time to present day enhances tropospheric O3 production. Aerosol forcing thus has a warming component via its effect on O3 production. Sensitivity simulations suggest that 4-8% increase of tropospheric ozone, mainly in the tropics, is expected if aerosol-lighting-ozone link is parameterized, depending on the background emission scenario. We note, however, substantial uncertainties remain on the exact magnitude of aerosol effect on tropospheric O3 via lightning. The challenges for obtaining a quantitative global estimate of this effect are also discussed. Our results have significant implications

Estimating Real-Time Zenith Tropospheric Delay over Africa Using IGS-RTS Products

NASA Astrophysics Data System (ADS)

Abdelazeem, M.

2017-12-01

Zenith Tropospheric Delay (ZTD) is a crucial parameter for atmospheric modeling, severe weather monitoring and forecasting applications. Currently, the international global navigation satellite system (GNSS) real-time service (IGS-RTS) products are used extensively in real-time atmospheric modeling applications. The objective of this study is to develop a real time zenith tropospheric delay estimation model over Africa using the IGS-RTS products. The real-time ZTDs are estimated based on the real-time precise point positioning (PPP) solution. GNSS observations from a number of reference stations are processed over a period of 7 days. Then, the estimated real-time ZTDs are compared with the IGS tropospheric products counterparts. The findings indicate that the estimated real-time ZTDs have millimeter level accuracy in comparison with the IGS counterparts.

Drivers of the tropospheric ozone budget throughout the 21st century under the medium-high climate scenario RCP 6.0

NASA Astrophysics Data System (ADS)

Revell, L. E.; Tummon, F.; Stenke, A.; Sukhodolov, T.; Coulon, A.; Rozanov, E.; Garny, H.; Grewe, V.; Peter, T.

2015-01-01

Because tropospheric ozone is both a~greenhouse gas and harmful air pollutant, it is important to understand how anthropogenic activities may influence its abundance and distribution through the 21st century. Here, we present model simulations performed with the chemistry-climate model SOCOL, in which spatially disaggregated chemistry and transport tracers have been implemented in order to better understand the distribution and projected changes in tropospheric ozone. We examine the influences of ozone precursor emissions (nitrogen oxides (NOx), carbon monoxide (CO) and volatile organic compounds (VOCs)), climate change and stratospheric ozone recovery on the tropospheric ozone budget, in a~simulation following the climate scenario Representative Concentration Pathway (RCP) 6.0. Changes in ozone precursor emissions have the largest effect, leading to a global-mean increase in tropospheric ozone which maximises in the early 21st century at 23%. The increase is most pronounced at northern midlatitudes, due to regional emission patterns: between 1990 and 2060, northern midlatitude tropospheric ozone remains at constantly large abundances: 31% larger than in 1960. Over this 70 year period, attempts to reduce emissions in Europe and North America do not have an effect on zonally-averaged northern midlatitude ozone because of increasing emissions from Asia, together with the longevity of ozone in the troposphere. A~simulation with fixed anthropogenic ozone precursor emissions of NOx, CO and non-methane VOCs at 1960 conditions shows a 6 % increase in global-mean tropospheric ozone, and an 11% increase at northern midlatitudes. This increase maximises in the 2080s, and is mostly caused by methane, which maximises in the 2080s following RCP 6.0, and plays an important role in controlling ozone directly, and indirectly through its influence on other VOCs and CO. Enhanced flux of ozone from the stratosphere to the troposphere as well as climate change-induced enhancements in

Evidence of Tropospheric 90 Day Oscillations in the Thermosphere

NASA Astrophysics Data System (ADS)

Gasperini, F.; Hagan, M. E.; Zhao, Y.

2017-10-01

In the last decade evidence demonstrated that terrestrial weather greatly impacts the dynamics and mean state of the thermosphere via small-scale gravity waves and global-scale solar tidal propagation and dissipation effects. While observations have shown significant intraseasonal variability in the upper mesospheric mean winds, relatively little is known about this variability at satellite altitudes (˜250-400 km). Using cross-track wind measurements from the Challenging Minisatellite Payload and Gravity field and steady-state Ocean Circulation Explorer satellites, winds from a Modern-Era Retrospective Analysis for Research and Applications/Thermosphere-Ionosphere-Mesosphere-Electrodynamics General Circulation Model simulation, and outgoing longwave radiation data, we demonstrate the existence of a prominent and global-scale 90 day oscillation in the thermospheric zonal mean winds and in the diurnal eastward propagating tide with zonal wave number 3 (DE3) during 2009-2010 and present evidence of its connection to variability in tropospheric convective activity. This study suggests that strong coupling between the troposphere and the thermosphere occurs on intraseasonal timescales.

Stratospheric Ozone Distribution and Tropospheric General Circulation: Interconnections in the UTLS Region

NASA Astrophysics Data System (ADS)

Barodka, S.; Krasovsky, A.; Shalamyansky, A.

2014-12-01

The height of the tropopause, which divided the stratosphere and the troposphere, is a result of two rival categories of processes: the tropospheric vertical convection and the radiative heating of the stratosphere resulting from the ozone cycle. Hence, it is natural that tropospheric and stratospheric phenomena can have effect each other in manifold processes of stratosphere-troposphere interactions. In the present study we focus our attention to the "top-down" side of the interaction: the impact of stratospheric ozone distribution on the features of tropospheric circulation and the associated weather patterns and regional climate conditions. We proceed from analyzes of the observational data performed at the A.I. Voeikov Main Geophysical Observatory, which suggest a distinct correlation between stratospheric ozone distribution, synoptic formations and air-masses boundaries in the upper troposphere and the temperature field of the lower stratosphere [1]. Furthermore, we analyze local features of atmospheric general circulation and stratospheric ozone distribution from the atmospheric reanalyses and general circulation model data, focusing our attention to instantaneous positions of subtropical and polar stationary atmospheric fronts, which define regional characteristics of the general circulation cells in the troposphere and separate global tropospheric air-masses, correspond to distinct meteorological regimes in the TOC field [2, 3]. We assume that by altering the tropopause height, stratospheric ozone-related processes can have an impact on the location of the stationary atmospheric fronts, thereby exerting influence on circulation processes in troposphere and lower stratosphere. For midlatitudes, the tropopause height controls the position of the polar stationary front, which has a direct impact on the trajectory of motion of active vortices on synoptic tropospheric levels, thereby controlling weather patterns in that region and the regional climate. This

Transport and Mixing in the Stratosphere and Troposphere

NASA Technical Reports Server (NTRS)

Bowman, Kenneth P.

2000-01-01

Long-term changes in the composition of the atmosphere are known to have significant effects on atmospheric chemistry and stratospheric ozone. Increasing levels of greenhouse gases have the potential to change the global climate in the middle and upper atmospheres, as well as in the troposphere. Volcanic eruptions, El Nino events, and other natural variations can also cause changes in atmospheric composition and climate. Whether the causes are natural or manmade, changes in the global climate system can have impacts on human society. In order to understand and predict the consequences of these changes, and of control measures such as the Montreal Protocol, it is necessary to understand the complex interactions between radiation, chemistry, and dynamics in the atmosphere. Much of the uncertainty in our understanding of atmospheric processes comes from an incomplete understanding of atmospheric transport. A complete and self-consistent model of transport requires not only an understanding of trace-species transport, but also the transport of dynamically active quantities such as heat and potential vorticity. Therefore, the goal of the proposed research is to better understand large-scale transport and mixing processes in the middle atmosphere and troposphere.

A directional model of tropospheric horizontal gradients in Global Positioning System and its application for particular weather scenarios

NASA Astrophysics Data System (ADS)

Masoumi, Salim; McClusky, Simon; Koulali, Achraf; Tregoning, Paul

2017-04-01

Improper modeling of horizontal tropospheric gradients in GPS analysis induces errors in estimated parameters, with the largest impact on heights and tropospheric zenith delays. The conventional two-axis tilted plane model of horizontal gradients fails to provide an accurate representation of tropospheric gradients under weather conditions with asymmetric horizontal changes of refractivity. A new parametrization of tropospheric gradients whereby an arbitrary number of gradients are estimated as discrete directional wedges is shown via simulations to significantly improve the accuracy of recovered tropospheric zenith delays in asymmetric gradient scenarios. In a case study of an extreme rain event that occurred in September 2002 in southern France, the new directional parametrization is able to isolate the strong gradients in particular azimuths around the GPS stations consistent with the "V" shape spatial pattern of the observed precipitation. In another study of a network of GPS stations in the Sierra Nevada region where highly asymmetric tropospheric gradients are known to exist, the new directional model significantly improves the repeatabilities of the stations in asymmetric gradient situations while causing slightly degraded repeatabilities for the stations in normal symmetric gradient conditions. The average improvement over the entire network is ˜31%, while the improvement for one of the worst affected sites P631 is ˜49% (from 8.5 mm to 4.3 mm) in terms of weighted root-mean-square (WRMS) error and ˜82% (from -1.1 to -0.2) in terms of skewness. At the same station, the use of the directional model changes the estimates of zenith wet delay by 15 mm (˜25%).

Climate Response to the Increase in Tropospheric Ozone since Preindustrial Times: A Comparison between Ozone and Equivalent CO2 Forcings

NASA Technical Reports Server (NTRS)

Mickley L. J.; Jacob, D. J.; Field, B. D.; Rind, D.

2004-01-01

We examine the characteristics of the climate response to anthropogenic changes in tropospheric ozone. Using a general circulation model, we have carried out a pair of equilibrium climate simulations with realistic present-day and preindustrial ozone distributions. We find that the instantaneous radiative forcing of 0.49 W m(sup -2) due to the increase in tropospheric ozone since preindustrial times results in an increase in global mean surface temperature of 0.28 C. The increase is nearly 0.4 C in the Northern Hemisphere and about 0.2 C in the Southern Hemisphere. The largest increases (greater than 0.8 C) are downwind of Europe and Asia and over the North American interior in summer. In the lower stratosphere, global mean temperatures decrease by about 0.2 C due to the diminished upward flux of radiation at 9.6 micrometers. The largest stratospheric cooling, up to 1.0 C, occurs over high northern latitudes in winter, with possibly important implications for the formation of polar stratospheric clouds. To identify the characteristics of climate forcing unique to tropospheric ozone, we have conducted two additional climate equilibrium simulations: one in which preindustrial tropospheric ozone concentrations were increased everywhere by 18 ppb, producing the same global radiative forcing as present-day ozone but without the heterogeneity; and one in which CO2 was decreased by 25 ppm relative to present day, with ozone at present-day values, to again produce the same global radiative forcing but with the spectral signature of CO2 rather than ozone. In the first simulation (uniform increase of ozone), the global mean surface temperature increases by 0.25 C, with an interhemispheric difference of only 0.03 C, as compared with nearly 0.2 C for the heterogeneous ozone increase. In the second simulation (equivalent CO2), the global mean surface temperature increases by 0.36 C, 30% higher than the increase from tropospheric ozone. The stronger surface warming from CO2 is

Remote sensing of tropospheric turbulence using GPS radio occultation

NASA Astrophysics Data System (ADS)

Shume, Esayas; Ao, Chi

2016-07-01

Radio occultation (RO) measurements are sensitive to the small-scale irregularities in the atmosphere. In this study, we present a new technique to estimate tropospheric turbulence strength (namely, scintillation index) by analyzing RO amplitude fluctuations in impact parameter domain. GPS RO observations from the COSMIC (Constellation Observing System for Meteorology, Ionosphere, and Climate) satellites enabled us to calculate global maps of scintillation measures, revealing the seasonal, latitudinal, and longitudinal characteristics of the turbulent troposphere. Such information are both difficult and expensive to obtain especially over the oceans. To verify our approach, simulation experiments using the multiple phase screen (MPS) method were conducted. The results show that scintillation indices inferred from the MPS simulations are in good agreement with scintillation measures estimated from COSMIC observations.

Ozone in the troposphere and stratosphere, part 2

NASA Technical Reports Server (NTRS)

Hudson, Robert D. (Editor)

1994-01-01

This is the second of a 2-part Conference Publication. This document contains papers presented at the 1992 Quadrennial Ozone Symposium held at Charlottesville, Virginia, from June 4-13, 1992. The papers cover topics in both Tropospheric and Stratospheric research. These topics include ozone trends and climatology, ground based, aircraft, balloon, rocket and satellite measurements, Arctic and Antarctic research, global and regional modeling, and volcanic effects.

Evaluation of the MACC operational forecast system - potential and challenges of global near-real-time modelling with respect to reactive gases in the troposphere

NASA Astrophysics Data System (ADS)

Wagner, A.; Blechschmidt, A.-M.; Bouarar, I.; Brunke, E.-G.; Clerbaux, C.; Cupeiro, M.; Cristofanelli, P.; Eskes, H.; Flemming, J.; Flentje, H.; George, M.; Gilge, S.; Hilboll, A.; Inness, A.; Kapsomenakis, J.; Richter, A.; Ries, L.; Spangl, W.; Stein, O.; Weller, R.; Zerefos, C.

2015-03-01

Monitoring Atmospheric Composition and Climate (MACC/MACCII) currently represents the European Union's Copernicus Atmosphere Monitoring Service (CAMS) (http://www.copernicus.eu), which will become fully operational in the course of 2015. The global near-real-time MACC model production run for aerosol and reactive gases provides daily analyses and 5 day forecasts of atmospheric composition fields. It is the only assimilation system world-wide that is operational to produce global analyses and forecasts of reactive gases and aerosol fields. We have investigated the ability of the MACC analysis system to simulate tropospheric concentrations of reactive gases (CO, O3, and NO2) covering the period between 2009 and 2012. A validation was performed based on CO and O3 surface observations from the Global Atmosphere Watch (GAW) network, O3 surface observations from the European Monitoring and Evaluation Programme (EMEP) and furthermore, NO2 tropospheric columns derived from the satellite sensors SCIAMACHY and GOME-2, and CO total columns derived from the satellite sensor MOPITT. The MACC system proved capable of reproducing reactive gas concentrations in consistent quality, however, with a seasonally dependent bias compared to surface and satellite observations: for northern hemispheric surface O3 mixing ratios, positive biases appear during the warm seasons and negative biases during the cold parts of the years, with monthly Modified Normalised Mean Biases (MNMBs) ranging between -30 and 30% at the surface. Model biases are likely to result from difficulties in the simulation of vertical mixing at night and deficiencies in the model's dry deposition parameterization. Observed tropospheric columns of NO2 and CO could be reproduced correctly during the warm seasons, but are mostly underestimated by the model during the cold seasons, when anthropogenic emissions are at a highest, especially over the US, Europe and Asia

Evaluation of the MACC operational forecast system - potential and challenges of global near-real-time modelling with respect to reactive gases in the troposphere

NASA Astrophysics Data System (ADS)

Wagner, A.; Blechschmidt, A.-M.; Bouarar, I.; Brunke, E.-G.; Clerbaux, C.; Cupeiro, M.; Cristofanelli, P.; Eskes, H.; Flemming, J.; Flentje, H.; George, M.; Gilge, S.; Hilboll, A.; Inness, A.; Kapsomenakis, J.; Richter, A.; Ries, L.; Spangl, W.; Stein, O.; Weller, R.; Zerefos, C.

2015-12-01

The Monitoring Atmospheric Composition and Climate (MACC) project represents the European Union's Copernicus Atmosphere Monitoring Service (CAMS) (http://www.copernicus.eu/), which became fully operational during 2015. The global near-real-time MACC model production run for aerosol and reactive gases provides daily analyses and 5-day forecasts of atmospheric composition fields. It is the only assimilation system worldwide that is operational to produce global analyses and forecasts of reactive gases and aerosol fields. We have investigated the ability of the MACC analysis system to simulate tropospheric concentrations of reactive gases covering the period between 2009 and 2012. A validation was performed based on carbon monoxide (CO), nitrogen dioxide (NO2) and ozone (O3) surface observations from the Global Atmosphere Watch (GAW) network, the O3 surface observations from the European Monitoring and Evaluation Programme (EMEP) and, furthermore, NO2 tropospheric columns, as well as CO total columns, derived from satellite sensors. The MACC system proved capable of reproducing reactive gas concentrations with consistent quality; however, with a seasonally dependent bias compared to surface and satellite observations - for northern hemispheric surface O3 mixing ratios, positive biases appear during the warm seasons and negative biases during the cold parts of the year, with monthly modified normalised mean biases (MNMBs) ranging between -30 and 30 % at the surface. Model biases are likely to result from difficulties in the simulation of vertical mixing at night and deficiencies in the model's dry deposition parameterisation. Observed tropospheric columns of NO2 and CO could be reproduced correctly during the warm seasons, but are mostly underestimated by the model during the cold seasons, when anthropogenic emissions are at their highest level, especially over the US, Europe and Asia. Monthly MNMBs of the satellite data

Global biology - An interdisciplinary scientific research program at NASA, Ames Research Center

NASA Technical Reports Server (NTRS)

Lawless, J. G.; Colin, L.

1983-01-01

NASA has initiated new effort in Global Biology, the primary focus of which is to understand biogeochemical cycles. As part of this effort, an interdisciplinary team of scientists has formed at Ames Research Center to investigate the cycling of sulfur in the marine coastal zone and to study the cycling of nitrogen in terrestrial ecosystems. Both studies will use remotely sensed data, coupled with ground-based research, to identify and measure the transfer of major and minor biologically produced gases between these ecosystems and global reservoirs.

Global Biology: An Interdisciplinary Scientific Research Program at NASA Ames Research Center

NASA Technical Reports Server (NTRS)

Lawless, James G.; Colin, Lawrence

1984-01-01

NASA has initiated new effort in Global Biology, the primary focus of which is to understand biogeochemical cycles. As part of this effort, an interdisciplinary team of scientists has formed at Ames Research Center to investigate the cycling of sulfur in the marine coastal zone and to study the cycling of nitrogen in terrestrial ecosystems. Both studies will use remotely sensed data, coupled with ground-based research, to identify and measure the transfer of major and minor biologically produced gases between these ecosystems and global reservoirs.

Surface refractivity measurements at NASA spacecraft tracking sites

NASA Technical Reports Server (NTRS)

Schmid, P. E.

1972-01-01

High-accuracy spacecraft tracking requires tropospheric modeling which is generally scaled by either estimated or measured values of surface refractivity. This report summarizes the results of a worldwide surface-refractivity test conducted in 1968 in support of the Apollo program. The results are directly applicable to all NASA radio-tracking systems.

Investigation of the Physical Processes Governing Large-Scale Tracer Transport in the Stratosphere and Troposphere

NASA Technical Reports Server (NTRS)

Selkirk, Henry B.

2001-01-01

This report summarizes work conducted from January 1996 through April 1999 on a program of research to investigate the physical mechanisms that underlie the transport of trace constituents in the stratosphere-troposphere system. The primary scientific goal of the research has been to identify the processes which transport air masses within the lower stratosphere, particularly between the tropics and middle latitudes. This research was conducted in collaboration with the Subsonic Assessment (SASS) of the NASA Atmospheric Effects of Radiation Program (AEAP) and the Upper Atmospheric Research Program (UARP). The SASS program sought to understand the impact of the present and future fleets of conventional jet traffic on the upper troposphere and lower stratosphere, while complementary airborne observations under UARP seek to understand the complex interactions of dynamical and chemical processes that affect the ozone layer. The present investigation contributed to the goals of each of these by diagnosing the history of air parcels intercepted by NASA research aircraft in UARP and AEAP campaigns. This was done by means of a blend of trajectory analyses and tracer correlation techniques.

Five blind men and an elephant: can NASA Aura measurements quantify the stratosphere-troposphere exchange of ozone flux?

NASA Astrophysics Data System (ADS)

Tang, Q.; Prather, M. J.

2011-09-01

We examine whether the instantaneous ozone (O3) measurements from the four Aura instruments can quantify the stratosphere-troposphere exchange (STE) flux of O3, an important term of the tropospheric O3 budget. Comparing the level 2 (L2) Aura swaths and ozone sondes with the coincident, high-resolution (1°×1°×40-layer×0.5 h) simulations using the University of California, Irvine chemistry transport model (CTM) for years 2005-2006, it is revealed in many cases that all four Aura datasets have some skill in catching the STE process, while missing many of them. Despite a few cases, the individual retrievals in the upper troposphere and lower stratosphere contain too much noise preventing the quantification and integration of STE flux with Aura L2 data. The CTM is applied as a transfer standard to compare with different Aura observations. The statistics of exact matching CTM-Aura comparisons identify the model's high biases in the lower stratosphere and the inconsistency amongst different instruments, such as from tropics to Northern Hemisphere mid-latitudes in July 2005 at 215 hPa and over tropics at 147 hPa for July 2005 and January 2006.

Radiative forcing perturbation due to observed increases in tropospheric ozone at Hohenpeissenberg

NASA Technical Reports Server (NTRS)

Wang, Wei-Chyung; Bojkov, Rumen D.; Zhuang, Yi-Cheng

1994-01-01

The effect on surface temperature due to changes in atmospheric O3 depends highly on the latitude where the change occurs. Previous sensitivity calculations indicate that ozone changes in the upper troposphere and lower stratosphere are more effective in causing surface temperature change (Wang et al., 1980). Long term ground-based observations show that tropospheric ozone, especially at the tropopause region, has been increasing at middle and high latitudes in the Northern Hemisphere (NATO, 1988; Quadrennial Ozone Symposium, 1992). These increases will enhance the greenhouse effect and increase the radiative forcing to the troposphere-surface system, which is opposite to the negative radiative forcing calculated from the observed stratospheric ozone depletion recently reported in WMO (1992). We used more than two thousands regularly measured ozonesondes providing reliable vertical O3 distribution at Hohenpeissenberg (47N; 11E) for the 1967-1990 to study the instantaneous solar and longwave radiative forcing the two decades 1971-1990 and compare the forcing with those caused by increasing CO2, CH4, N2O, and CFCs. Calculations are also made to compare the O3 radiative forcing between stratospheric depletion and tropospheric increase. Results indicate that the O3 changes will induce a positive radiative forcing dominated by tropospheric O3 increase and the magnitude of the forcing is comparable to that due to CO2 increases during the two decades. The significant implications of the tropospheric O3 increase to the global climate are discussed.

Rapid increases in tropospheric ozone production and export from China: A view from AURA and TM5

NASA Astrophysics Data System (ADS)

Verstraeten, W. W.; Neu, J. L.; Williams, J. E.; Bowman, K. W.; Worden, J. R.; Boersma, K. F.

2015-12-01

Eastern Asia has the fastest growing anthropogenic emissions in the world, possibly affecting both the pollution in the local troposphere as well as in the trans-Pacific region. Local measurements over Asia show that tropospheric ozone (O3) has increased by 1 to 3% per year since the start of the millennium. This increase is often invoked to explain positive tropospheric O3 trends observed in western US, but to date there is no unambiguous evidence showing that enhanced Asian pollution is responsible for these trends. In this research we use observations of tropospheric O3 from TES (Tropospheric Emission Spectrometer, onboard AURA), tropospheric NO2 measurements from OMI (Ozone Monitoring Instrument, onboard AURA) and lower stratospheric observations of O3 from MLS (Microwave Limb Sounder, onboard AURA) in combination with the TM5 CTM. Satellite-based studies focusing on tropospheric O3 and NO2 have the potential to close the gap left by previous studies on air quality since spaceborne data provide large-scale observational evidence that both O3 precursor concentrations and tropospheric O3 levels are rapidly changing over source receptor areas. We show the increased ability of TM5 to reproduce the 2005-2010 observed rapid rise in free tropospheric O3 of 7% over China from TES, once OMI NO2 measurements were implemented in TM5 to update NOX emissions. MLS observations on lower stratospheric O3 have the potential to improve the stratosphere-troposphere exchange (STE) estimate in TM5 which is mainly driven by ECMWF meteorological fields. Constraining the TM5 modelled trend of the STE contribution to the 3-9 km partial O3 column using MLS observations of stratospheric O3 lead to a better explanation of the sources of the free tropospheric O3 trends over China. Based on the OMI inferred TM5 updates in NOX emissions, the impact of Asian O3 and its precursors on the free troposphere (3-9 km) over the western US could be quantified. Large import from China offsets the

Toward Quantitative Estimation of the Effect of Aerosol Particles in the Global Climate Model and Cloud Resolving Model

NASA Astrophysics Data System (ADS)

Eskes, H.; Boersma, F.; Dirksen, R.; van der A, R.; Veefkind, P.; Levelt, P.; Brinksma, E.; van Roozendael, M.; de Smedt, I.; Gleason, J.

2005-05-01

Based on measurements of GOME on ESA ERS-2, SCIAMACHY on ESA-ENVISAT, and Ozone Monitoring Instrument (OMI) on the NASA EOS-Aura satellite there is now a unique 11-year dataset of global tropospheric nitrogen dioxide measurements from space. The retrieval approach consists of two steps. The first step is an application of the DOAS (Differential Optical Absorption Spectroscopy) approach which delivers the total absorption optical thickness along the light path (the slant column). For GOME and SCIAMACHY this is based on the DOAS implementation developed by BIRA/IASB. For OMI the DOAS implementation was developed in a collaboration between KNMI and NASA. The second retrieval step, developed at KNMI, estimates the tropospheric vertical column of NO2 based on the slant column, cloud fraction and cloud top height retrieval, stratospheric column estimates derived from a data assimilation approach and vertical profile estimates from space-time collocated profiles from the TM chemistry-transport model. The second step was applied with only minor modifications to all three instruments to generate a uniform 11-year data set. In our talk we will address the following topics: - A short summary of the retrieval approach and results - Comparisons with other retrievals - Comparisons with global and regional-scale models - OMI-SCIAMACHY and SCIAMACHY-GOME comparisons - Validation with independent measurements - Trend studies of NO2 for the past 11 years

Climate Impacts on Tropospheric Ozone and Hydroxyl

NASA Technical Reports Server (NTRS)

Shindell, Drew T.; Bell, N.; Faluvegi, G.

2003-01-01

Climate change may influence tropospheric ozone and OH via several main pathways: (1) altering chemistry via temperature and humidity changes, (2) changing ozone and precursor sources via surface emissions, stratosphere-troposphere exchange, and light- ning, and (3) affecting trace gas sinks via the hydrological cycle and dry deposition. We report results from a set of coupled chemistry-climate model simulations designed to systematically study these effects. We compare the various effects with one another and with past and projected future changes in anthropogenic and natural emissions of ozone precursors. We find that white the overall impact of climate on ozone is probably small compared to emission changes, some significant seasonal and regional effects are apparent. The global effect on hydroxyl is quite large, however, similar in size to the effect of emission changes. Additionally, we show that many of the chemistry-climate links that are not yet adequately modeled are potentially important.

Effects of the 2006 El Nino on Tropospheric Ozone and Carbon Monoxide: Implications for Dynamics and Biomass Burning

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Duncan, B. N.; Diehl, t. L.

2008-01-01

We have studied the effects of the 2006 El Nino on tropospheric O3 and CO at tropical and sub-tropical latitudes measured from the OMI and MLS instruments on the Aura satellite. The 2006 El Nino-induced drought allowed forest fires set to clear land to burn out of control during October and November in the Indonesian region. The effects of these fires are clearly seen in the enhancement of GO concentration measured from the MLS instrument. We have used a global model of atmospheric chemistry and transport (GMI CTM) to quantify the relative irrrportance of biomass burning and large scale transport: in producing observed changes in tropospheric O3 and CO . The model results show that during October and November both biomass burning and meteorological changes contributed almost equally to the observed increase in tropospheric O3 in the Indonesian region. The biomass component was 4-6 DU but it was limited to the Indonesian region where the fires were most intense, The dynamical component was 4-8 DU but it covered a much larger area in the Indian Ocean extending from South East Asia in the north to western Australia in the south. By December 2006, the effect of biomass taming was reduced to zero and the obsemed changes in tropospheric O3 were mostly due to dynamical effects. The model results show an increase of 2-3% in the global burden of tropospheric ozone. In comparison, the global burdean of CO increased by 8-12%.

Air mass origins and troposphere-to-stratosphere exchange associated with mid-latitude cyclogenesis and tropopause folding inferred from Be-7 measurements

NASA Technical Reports Server (NTRS)

Kritz, Mark A.; Rosner, Stefan W.; Danielsen, Edwin F.; Selkirk, Henry B.

1991-01-01

The 1984 extratropical mission of NASA's Stratosphere-Troposphere Exchange Project (STEP) studied cross-jet transport in regions of cyclogenesis and tropopause folding. Correlations of Be-7, ozone, water vapor, and potential vorticity measured on a NASA U-2 research aircraft flying in high shear regions above the jet core are indicative of mixing between the cyclonic and the anticyclonic sides of the jet and are consistent with the hypothesis that small-scale entrainments of upper tropospheric air into the lower stratosphere during cyclogenesis are important in maintaining the vertical gradients of Be-7, ozone, water vapor and other trace constituents in the lower few kilometers of the midlatitude stratosphere. Correlations between Be-7, and ozone suggest a lower tropical stratospheric origin for the ozone-poor lamina observed above the jet core.

Tropical Tropospheric Ozone from SHADOZ (Southern Hemisphere ADditional Ozonesondes) Network: A Project for Satellite Research, Process Studies, Education

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Schmidlin, Francis J.; Coetzee, G. J. R.; Hoegger, Bruno; Kirchhoff, V. W. J. H.; Ogawa, Toshihiro; Kawakami, Shuji; Posny, Francoise

2002-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: nasa.nov/Data_services/shadoz>. SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole and convective mixing. Pollution transport from Africa and South America is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Weather Avoidance Guidelines for NASA Global Hawk High-Altitude Unmanned Aircraft Systems (UAS)

NASA Technical Reports Server (NTRS)

Cecil, Daniel J.; Zipser, Edward J.; Velden, Chris S.; Monette, Sarah A.; Heymsfield, Gerald M.; Braun, Scott A.; Newman, Paul A.; Black, Peter G.; Black, Michael L.; Dunion, Jason P.

2014-01-01

The current Global Hawk flight rules would probably not have been effective in the single event of greatest concern (the Emily encounter). The cloud top had not reached 50,000 ft until minutes before the encounter. The TOT and lightning data would not have been available until near the overflight time since this was a rapidly growing cell. This case would have required a last-minute diversion when lightning became frequent. Avoiding such a cell probably requires continual monitoring of the forward camera and storm scope, whether or not cloud tops have been exceeding specific limits. However, the current overflight rules as strictly interpreted would have prohibited significant fractions of the successful Global Hawk overpasses of Karl and Matthew that proved not to be hazardous. Many other high altitude aircraft (ER-2 and Global Hawk) flights in NASA tropical cyclone field programs have successfully overflown deep convective clouds without incident.The convective cell that caused serious concern about the safety of the ER-2 in Emily was especially strong for a tropical cyclone environment, probably as strong or stronger than any that was overflown by the ER-2 in 20 previous flights over tropical cyclones. Specifically, what made that cell a safety concern was the magnitude of the vertical velocity of the updraft, at least 20 m/s (4000 ft/minute) at the time the ER-2 overflew it. Such a strong updraft can generate strong gravity waves at and above the tropopause, posing a potential danger to aircraft far above the maximum altitude of the updraft itself or its associated cloud top. Indeed, the ER-2 was probably at least 9000 ft above that cloud top. Cloud-top height, by itself, is not an especially good indicator of the intensity of convection and the likelihood of turbulence. Nor is overflying high cloud tops (i.e. > 50,000 ft) of particular concern unless there is other evidence of very strong convective updrafts beneath those tops in the path of the aircraft

Drivers of the tropospheric ozone budget throughout the 21st century under the medium-high climate scenario RCP 6.0

NASA Astrophysics Data System (ADS)

Revell, L. E.; Tummon, F.; Stenke, A.; Sukhodolov, T.; Coulon, A.; Rozanov, E.; Garny, H.; Grewe, V.; Peter, T.

2015-05-01

Because tropospheric ozone is both a greenhouse gas and harmful air pollutant, it is important to understand how anthropogenic activities may influence its abundance and distribution through the 21st century. Here, we present model simulations performed with the chemistry-climate model SOCOL, in which spatially disaggregated chemistry and transport tracers have been implemented in order to better understand the distribution and projected changes in tropospheric ozone. We examine the influences of ozone precursor emissions (nitrogen oxides (NOx), carbon monoxide (CO) and volatile organic compounds (VOCs)), climate change (including methane effects) and stratospheric ozone recovery on the tropospheric ozone budget, in a simulation following the climate scenario Representative Concentration Pathway (RCP) 6.0 (a medium-high, and reasonably realistic climate scenario). Changes in ozone precursor emissions have the largest effect, leading to a global-mean increase in tropospheric ozone which maximizes in the early 21st century at 23% compared to 1960. The increase is most pronounced at northern midlatitudes, due to regional emission patterns: between 1990 and 2060, northern midlatitude tropospheric ozone remains at constantly large abundances: 31% larger than in 1960. Over this 70-year period, attempts to reduce emissions in Europe and North America do not have an effect on zonally averaged northern midlatitude ozone because of increasing emissions from Asia, together with the long lifetime of ozone in the troposphere. A simulation with fixed anthropogenic ozone precursor emissions of NOx, CO and non-methane VOCs at 1960 conditions shows a 6% increase in global-mean tropospheric ozone by the end of the 21st century, with an 11 % increase at northern midlatitudes. This increase maximizes in the 2080s and is mostly caused by methane, which maximizes in the 2080s following RCP 6.0, and plays an important role in controlling ozone directly, and indirectly through its

Western Pacific Tropospheric Ozone and Potential Vorticity: Implications for Asian Pollution

NASA Technical Reports Server (NTRS)

Browell, Edward V.; Newell, Reginald E.; Davis, Douglas D.; Liu, Shaw C.

1997-01-01

Tropospheric ozone (03) cross sections measured with lidar from a DC-8 aircraft over the western Pacific correspond closely with potential vorticity (PV). Both are transported from the middle latitude stratosphere, although this is not the only source of 03, and both have sinks in the tropical boundary layer. 03 and PV are good indicators of photochemical and transport process interactions. In summer, some Asian pollution, raised by convection to the upper troposphere, passes southward into the tropics and to the Southern Hemisphere. In winter, subsidence keeps the pollution at low altitudes where it moves over the ocean towards the Inter-Tropical Convergence Zone (ITCZ), with photochemical destruction and secondary pollutant generation occurring en route. Convection raises this modified air to the upper troposphere, where some re may enter the stratosphere. Thus winter Asian pollution may at have a smaller direct influence on the global atmosphere than it would if injected at other longitudes and seasons.

Ozone in the Troposphere and Stratosphere, part 1

NASA Technical Reports Server (NTRS)

Hudson, Robert D.

1994-01-01

This is the first part of a 2-part Conference Publication. This document contains papers presented at the 1992 Quadrennial Ozone Symposium held at the Charlottesville, Virginia, from June 4-13, 1992. The papers cover topics in both Tropospheric and Stratospheric research. These topics include ozone trends and climatology, ground based, aircraft, balloon, rocket and satellite measurements, Arctic and Antarctic research, global and regional modeling, and volcanic effects.

Simulations of Tropospheric NO2 by the Global Modeling Initiative (GMI) Model Utilizing Assimilated and Forecast Meteorological Fields: Comparison to Ozone Monitoring Instrument (OMI) Measurements

NASA Technical Reports Server (NTRS)

Rodriquez, J. M.; Yoshida, Y.; Duncan, B. N.; Bucsela, E. J.; Gleason, J. F.; Allen, D.; Pickering, K. E.

2007-01-01

We present simulations of the tropospheric composition for the years 2004 and 2005, carried out by the GMI Combined Stratosphere-Troposphere (Combo) model, at a resolution of 2degx2.5deg. The model includes a new parameterization of lightning sources of NO(x) which is coupled to the cloud mass fluxes in the adopted meteorological fields. These simulations use two different sets of input meteorological fields: a)late-look assimilated fields from the Global Modeling and Assimilation Office (GMAO), GEOS-4 system and b) 12-hour forecast fields initialized with the assimilated data. Comparison of the forecast to the assimilated fields indicates that the forecast fields exhibit less vigorous convection, and yield tropical precipitation fields in better agreement with observations. Since these simulations include a complete representation of the stratosphere, they provide realistic stratosphere-tropospheric fluxes of O3 and NO(y). Furthermore, the stratospheric contribution to total columns of different troposheric species can be subtracted in a consistent fashion, and the lightning production of NO(y) will depend on the adopted meteorological field. We concentrate here on the simulated tropospheric columns of NO2, and compare them to observations by the OM1 instrument for the years 2004 and 2005. The comparison is used to address these questions: a) is there a significant difference in the agreement/disagreement between simulations for these two different meteorological fields, and if so, what causes these differences?; b) how do the simulations compare to OMI observations, and does this comparison indicate an improvement in simulations with the forecast fields? c) what are the implications of these simulations for our understanding of the NO2 emissions over continental polluted regions?

Tropospheric Ozone Changes, Radiative Forcing and Attribution to Emissions in the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP)

NASA Technical Reports Server (NTRS)

Stevenson, D.S.; Young, P.J.; Naik, V.; Lamarque, J.-F.; Shindell, D. T.; Voulgarakis, A.; Skeie, R. B.; Dalsoren, S. B.; Myhre, G.; Berntsen, T. K.;

SHADOZ (Southern Hemisphere ADditional Ozonesondes): A Look at the First Three Years' (1998-2000) Tropospheric Ozone Data

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Bhartia, Pawan K. (Technical Monitor)

2001-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere ADditional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; RCunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natai, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at an open archive: nasa.gov/Data_services/shadoz>. SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, ENSO, and Madden-Julian circulation on convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude.

Future changes in the stratosphere-to-troposphere ozone mass flux and the contribution from climate change and ozone recovery

NASA Astrophysics Data System (ADS)

Meul, Stefanie; Langematz, Ulrike; Kröger, Philipp; Oberländer-Hayn, Sophie; Jöckel, Patrick

2018-06-01

Using a state-of-the-art chemistry-climate model we investigate the future change in stratosphere-troposphere exchange (STE) of ozone, the drivers of this change, as well as the future distribution of stratospheric ozone in the troposphere. Supplementary to previous work, our focus is on changes on the monthly scale. The global mean annual influx of stratospheric ozone into the troposphere is projected to increase by 53 % between the years 2000 and 2100 under the RCP8.5 greenhouse gas scenario. The change in ozone mass flux (OMF) into the troposphere is positive throughout the year with maximal increase in the summer months of the respective hemispheres. In the Northern Hemisphere (NH) this summer maximum STE increase is a result of increasing greenhouse gas (GHG) concentrations, whilst in the Southern Hemisphere(SH) it is due to equal contributions from decreasing levels of ozone depleting substances (ODS) and increasing GHG concentrations. In the SH the GHG effect is dominating in the winter months. A large ODS-related ozone increase in the SH stratosphere leads to a change in the seasonal breathing term which results in a future decrease of the OMF into the troposphere in the SH in September and October. The resulting distributions of stratospheric ozone in the troposphere differ for the GHG and ODS changes due to the following: (a) ozone input occurs at different regions for GHG- (midlatitudes) and ODS-changes (high latitudes); and (b) stratospheric ozone is more efficiently mixed towards lower tropospheric levels in the case of ODS changes, whereas tropospheric ozone loss rates grow when GHG concentrations rise. The comparison between the moderate RCP6.0 and the extreme RCP8.5 emission scenarios reveals that the annual global OMF trend is smaller in the moderate scenario, but the resulting change in the contribution of ozone with stratospheric origin (O3s) to ozone in the troposphere is of comparable magnitude in both scenarios. This is due to the larger

Global tropospheric chemistry: Chemical fluexes in the global atmosphere

NASA Technical Reports Server (NTRS)

Lenschow, Donald H. (Editor); Hicks, Bruce B. (Editor)

1989-01-01

In October 1987, NSF, NASA, and NOAA jointly sponsored a workshop at Columbia University to assess the experimental tools and analysis procedures in use and under development to measure and understand gas and particle fluxes across this critical air-surface boundary. Results are presented for that workshop. It is published to summarize the present understanding of the various measurement techniques that are available, identify promising new technological developments for improved measurements, and stimulate thinking about this important measurement challenge.

Upper tropospheric ice sensitivity to sulfate geoengineering

NASA Astrophysics Data System (ADS)

Visioni, Daniele; Pitari, Giovanni; Mancini, Eva

2017-04-01

In light of the Paris Agreement which aims to keep global warming under 2 °C in the next century and considering the emission scenarios produced by the IPCC for the same time span, it is likely that to remain below that threshold some kind of geoengineering technique will have to be deployed. Amongst the different methods, the injection of sulfur into the stratosphere has received much attention considering its effectiveness and affordability. Aside from the rather well established surface cooling sulfate geoengineering (SG) would produce, the investigation on possible side-effects of this method is still ongoing. For instance, some recent studies have investigated the effect SG would have on upper tropospheric cirrus clouds, expecially on the homogenous freezing mechanisms that produces the ice particles (Kuebbeler et al., 2012). The goal of the present study is to better understand the effect of thermal and dynamical anomalies caused by SG on the formation of ice crystals via homogeneous freezing by comparing a complete SG simulation with a RCP4.5 reference case and with a number of sensitivity studies where atmospheric temperature changes in the upper tropospheric region are specified in a schematic way as a function of the aerosol driven stratospheric warming and mid-lower tropospheric cooling. These changes in the temperature profile tend to increase atmospheric stabilization, thus decreasing updraft and with it the amount of water vapor available for homogeneous freezing in the upper troposphere. However, what still needs to be assessed is the interaction between this dynamical effect and the thermal effects of tropospheric cooling (which would increase ice nucleation rates) and stratospheric warming (which would probably extend to the uppermost troposphere via SG aerosol gravitational settling, thus reducing ice nucleation rates), in order to understand how they combine together. Changes in ice clouds coverage could be important for SG, because cirrus ice

On nonstationarity and antipersistency in global temperature series

NASA Astrophysics Data System (ADS)

KäRner, O.

2002-10-01

Statistical analysis is carried out for satellite-based global daily tropospheric and stratospheric temperature anomaly and solar irradiance data sets. Behavior of the series appears to be nonstationary with stationary daily increments. Estimating long-range dependence between the increments reveals a remarkable difference between the two temperature series. Global average tropospheric temperature anomaly behaves similarly to the solar irradiance anomaly. Their daily increments show antipersistency for scales longer than 2 months. The property points at a cumulative negative feedback in the Earth climate system governing the tropospheric variability during the last 22 years. The result emphasizes a dominating role of the solar irradiance variability in variations of the tropospheric temperature and gives no support to the theory of anthropogenic climate change. The global average stratospheric temperature anomaly proceeds like a 1-dim random walk at least up to 11 years, allowing good presentation by means of the autoregressive integrated moving average (ARIMA) models for monthly series.

Secondary ozone peaks in the troposphere over the Himalayas

NASA Astrophysics Data System (ADS)

Ojha, Narendra; Pozzer, Andrea; Akritidis, Dimitris; Lelieveld, Jos

2017-06-01

Layers with strongly enhanced ozone concentrations in the middle-upper troposphere, referred to as secondary ozone peaks (SOPs), have been observed in different regions of the world. Here we use the global ECHAM5/MESSy atmospheric chemistry model (EMAC) to (i) investigate the processes causing SOPs, (ii) explore both their frequency of occurrence and seasonality, and (iii) assess their effects on the tropospheric ozone budget over the Himalayas. The vertical profiles of potential vorticity (PV) and a stratospheric ozone tracer (O3s) in EMAC simulations, in conjunction with the structure of SOPs, suggest that SOPs over the Himalayas are formed by stratosphere-to-troposphere transport (STT) of ozone. The spatial distribution of O3s further shows that such effects are in general most pronounced in the northern part of India. Model simulated ozone distributions and backward air trajectories show that ozone rich air masses, associated with STT, originate as far as northern Africa and the North Atlantic Ocean, the Middle East, as well as in nearby regions in Afghanistan and Pakistan, and are rapidly (within 2-3 days) transported to the Himalayas. Analysis of a 15-year (2000-2014) EMAC simulation shows that the frequency of SOPs is highest during the pre-monsoon season (e.g. 11 % of the time in May), while no intense SOP events are found during the July-October period. The SOPs are estimated to enhance the tropospheric column ozone (TCO) over the central Himalayas by up to 21 %.

Measuring tropospheric wind with microwave sounders

NASA Astrophysics Data System (ADS)

Lambrigtsen, B.; Su, H.; Turk, J.; Hristova-Veleva, S. M.; Dang, V. T.

2017-12-01

In its 2007 "Decadal Survey" of earth science missions for NASA the U.S. National Research Council recommended that a Doppler wind lidar be developed for a three-dimensional tropospheric winds mission ("3D-Winds"). The technology required for such a mission has not yet been developed, and it is expected that the next Decadal Survey, planned to be released by the end of 2017, will put additional emphasis on the still pressing need for wind measurements from space. The first Decadal Survey also called for a geostationary microwave sounder (GMS) on a Precipitation and All-weather Temperature and Humidity (PATH) mission, which could be used to measure wind from space. Such a sounder, the Geostationary Synthetic Thinned Aperture Radiometer (GeoSTAR), has been developed at the Jet Propulsion Laboratory (JPL). The PATH mission has not yet been funded by NASA, but a low-cost subset of PATH, GeoStorm has been proposed as a hosted payload on a commercial communications satellite. Both PATH and GeoStorm would obtain frequent (every 15 minutes of better) measurements of tropospheric water vapor profiles, and they can be used to derive atmospheric motion vector (AMV) wind profiles, even in the presence of clouds. Measurement of wind is particularly important in the tropics, where the atmosphere is largely not in thermal balance and wind estimates cannot generally be derived from temperature and pressure fields. We report on simulation studies of AMV wind vectors derived from a GMS and from a cluster of low-earth-orbiting (LEO) small satellites (e.g., CubeSats). The results of two separate simulation studies are very encouraging and show that a ±2 m/s wind speed precision is attainable, which would satisfy WMO requirements. A GMS observing system in particular, which can be implemented now, would enable significant progress in the study of atmospheric dynamics. Copyright 2017 California Institute of Technology. Government sponsorship acknowledged

Tropospheric Wind Monitoring During Day-of-Launch Operations for National Aeronautics and Space Administration's Space Shuttle Program

NASA Technical Reports Server (NTRS)

Decker, Ryan K.; Leach, Richard

2004-01-01

The Environments Group at the National Aeronautics and Space Administration's Marshall Space Flight Center (NASA/MSFC) monitors the winds aloft at Kennedy Space Center (KSC) during the countdown for all Space Shuttle launches. Assessment of tropospheric winds is used to support the ascent phase of launch. Three systems at KSC are used to generate independent tropospheric wind profiles prior to launch; 1) high resolution Jimsphere balloon system, 2) 50-MHz Doppler Radar Wind Profiler (DRWP) and 3) low resolution radiosonde system. Data generated by the systems are used to assess spatial and temporal wind variability during launch countdown to ensure wind change observed does not violate wind change criteria constraints.

Potential role of CS2 photooxidation in tropospheric sulfur chemistry

NASA Technical Reports Server (NTRS)

Wine, P. H.; Chameides, W. L.; Ravishankara, A. R.

1981-01-01

Absorption cross section measurements and model calculations indicate that CS2 photooxidation may be an important tropospheric sink for the CS2, giving a lifetime on the order of a week or two. If background CS2 levels are 10-20 pptv, then CS2 photooxidation may be an important global source of OCS as well.

Earth Science Data and Applications for K-16 Education from the NASA Langley Atmospheric Science Data Center

NASA Astrophysics Data System (ADS)

Phelps, C. S.; Chambers, L. H.; Alston, E. J.; Moore, S. W.; Oots, P. C.

2005-05-01

NASA's Science Mission Directorate aims to stimulate public interest in Earth system science and to encourage young scholars to consider careers in science, technology, engineering and mathematics. NASA's Atmospheric Science Data Center (ASDC) at Langley Research Center houses over 700 data sets related to Earth's radiation budget, clouds, aerosols and tropospheric chemistry that are being produced to increase academic understanding of the natural and anthropogenic perturbations that influence global climate change. However, barriers still exist in the use of these actual satellite observations by educators in the classroom to supplement the educational process. Thus, NASA is sponsoring the "Mentoring and inquirY using NASA Data on Atmospheric and earth science for Teachers and Amateurs" (MY NASA DATA) project to systematically support educational activities by reducing the ASDC data holdings to `microsets' that can be easily accessible and explored by the K-16 educators and students. The microsets are available via Web site (http://mynasadata.larc.nasa.gov) with associated lesson plans, computer tools, data information pages, and a science glossary. A MY NASA DATA Live Access Server (LAS) has been populated with ASDC data such that users can create custom microsets online for desired time series, parameters and geographical regions. The LAS interface is suitable for novice to advanced users, teachers or students. The microsets may be visual representations of data or text output for spreadsheet analysis. Currently, over 148 parameters from the Clouds and the Earth's Radiant Energy System (CERES), Multi-angle Imaging SpectroRadiometer (MISR), Surface Radiation Budget (SRB), Tropospheric Ozone Residual (TOR) and the International Satellite Cloud Climatology Project (ISCCP) are available and provide important information on clouds, fluxes and cycles in the Earth system. Additionally, a MY NASA DATA OPeNDAP server has been established to facilitate file transfer of

Sensitivity of Tropospheric Chemical Composition to Halogen-Radical Chemistry Using a Fully Coupled Size-Resolved Multiphase Chemistry-Global Climate System: Halogen Distributions, Aerosol Composition, and Sensitivity of Climate-Relevant Gases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Long, M.; Keene, W. C.; Easter, Richard C.

Observations and model studies suggest a significant but highly non-linear role for halogens, primarily Cl and Br, in multiphase atmospheric processes relevant to tropospheric chemistry and composition, aerosol evolution, radiative transfer, weather, and climate. The sensitivity of global atmospheric chemistry to the production of marine aerosol and the associated activation and cycling of inorganic Cl and Br was tested using a size-resolved multiphase coupled chemistry/global climate model (National Center for Atmospheric Research’s Community Atmosphere Model (CAM); v3.6.33). Simulation results showed strong meridional and vertical gradients in Cl and Br species. The simulation reproduced most available observations with reasonable confidence permittingmore » the formulation of potential mechanisms for several previously unexplained halogen phenomena including the enrichment of Br- in submicron aerosol, and the presence of a BrO maximum in the polar free troposphere. However, simulated total volatile Br mixing ratios were generally high in the troposphere. Br in the stratosphere was lower than observed due to the lack of long-lived organobromine species in the simulation. Comparing simulations using chemical mechanisms with and without reactive Cl and Br species demonstrated a significant temporal and spatial sensitivity of primary atmospheric oxidants (O3, HOx, NOx), CH4, and non-methane hydrocarbons (NMHC’s) to halogen cycling. Simulated O3 and NOx were globally lower (65% and 35%, respectively, less in the planetary boundary layer based on median values) in simulations that included halogens. Globally, little impact was seen in SO2 and non-sea-salt SO42- processing due to halogens. Significant regional differences were evident: The lifetime of nss-SO42- was extended downwind of large sources of SO2. The burden and lifetime of DMS (and its oxidation products) were lower by a factor of 5 in simulations that included halogens, versus those without, leading

The Heritage of the Operational Usda/nasa Global Reservoir and Lake Monitor

NASA Astrophysics Data System (ADS)

Birkett, C. M.; Beckley, B. D.; Reynolds, C. A.

2012-12-01

Satellite radar altimetry has the ability to monitor variations in surface water height for large lakes and reservoirs. A clear advantage is the provision of data where in situ data are lacking or where there is restricted access to ground-based measurements. A USDA/NASA funded program is performing altimetric monitoring of the largest lakes and reservoirs around the world. The near-real time height measurements are currently derived from NASA/CNES Jason-2/OSTM mission data. Archived data are also utilized from the NASA/CNES Topex/Poseidon and Jason-1 missions, the NRL GFO mission, and the ESA ENVISAT mission. Lake level products are output within 1-2 weeks after satellite overpass, a time delay which will improve to a few days as the project moves into its next phase. The USDA/FAS utilize the products for assessing irrigation potential (and thus crop production estimates), and for general observation of high-water status and short-term drought. Other end-users explore the products to study climate trends, observe anthropogenic effects, and to consider water management and regional security issues. This presentation explores the heritage of the Global Reservoir and Lake Monitor (GRLM) which has its origins in the field of ocean surface topography and the exploration of radar altimetry techniques over non-ocean surfaces. The current system closely follows the software design of the historical NASA Ocean Pathfinder Project and utilizes a global lakes catalogue that was created for climate change/aridity studies. The output of lake level products, imagery and information also echoes an earlier trial (UNDP-funded) lakes database which first offered altimetric products via the world wide web and which enabled world-wide interest to be both assessed and highlighted.;

Lidar measurements from space for tropospheric chemistry investigations: Summary of workshop overview presentation

NASA Technical Reports Server (NTRS)

Browell, Edward V.

1987-01-01

Over the past decade, NASA has played a lead role in defining the scientific objectives and technology requirements for spaceborne lidar investigations of the atmosphere. An assessment of the potential for conducting lidar measurements from space for investigations that pertain specifically to tropospheric chemistry is presented. A description of potential lidar measurement techniques is given, and the scientific requirements for tropospheric chemistry are reviewed. The current status of airborne lidar measurements of aerosols, O3, and H2O is discussed, and a brief description of the evolution of lidar technology to space is given. Also, the measurement of tropospheric gases with a spaceborne lidar system is evaluated for a wide range of gas species. From this general assessment, it appears feasible to measure aerosols, H2O, O3, NH3, CO, CH4, NO2, atmospheric pressure and temperature, and wind with a lidar from space provided that the appropriate laser and receiver technology is available. For the mid-1990's, it is expected that lidar technology will be available for the measurement of aerosols, H2O, and O3 from a space platform.

High Output Maximum Efficiency Resonator (HOMER) Laser for NASA's Global Ecosystem Dynamics Investigation (GEDI) Lidar Mission

NASA Technical Reports Server (NTRS)

Stysley, Paul; Coyle, Barry; Clarke, Greg; Poulios, Demetrios; Kay, Richard

2015-01-01

The Global Ecosystems Dynamics Investigation (GEDI) is a planned mission sending a LIDAR instrument to the International Space Station that will employ three NASA laser transmitters. This instrument will produce parallel tracks on the Earth's surface that will provide global 3D vegetation canopy measurements. To meet the mission goals a total of 5 High Output Maximum Efficiency Resonator lasers will to be built (1 ETU + 3 Flight + 1 spare) in-house at NASA-GSFC. This presentation will summarize the HOMER design, the testing the design has completed in the past, and the plans to successfully build the units needed for the GEDI mission.

Development of the Global Ozone Lidar Demonstrator (GOLD) Instrument for Deployment on the NASA Global Hawk

NASA Technical Reports Server (NTRS)

Hair, Jonathan W.; Browell, Edward V.; McGee, Thomas; Butler, Carolyn; Fenn, Marta; Os,ao (. Sued); Notari, Anthony; Collins, James; Cleckner, Craig; Hostetler, Chris

2010-01-01

A compact ozone (O3) and aerosol lidar system is being developed for conducting global atmospheric investigations from the NASA Global Hawk Uninhabited Aerial Vehicle (UAV) and for enabling the development and test of a space-based O3 and aerosol lidar. GOLD incorporates advanced technologies and designs to produce a compact, autonomously operating O3 and aerosol Differential Absorption Lidar (DIAL) system for a UAV platform. The GOLD system leverages advanced Nd:YAG and optical parametric oscillator laser technologies and receiver optics, detectors, and electronics. Significant progress has been made toward the development of the GOLD system, and this paper describes the objectives of this program, basic design of the GOLD system, and results from initial ground-based atmospheric tests.

Ozone precursors and ozone photochemistry over eastern North Pacific during the spring of 1984 based on the NASA GTE/CITE 1 airborne observations

NASA Technical Reports Server (NTRS)

Chameides, W. L.; Davis, D. D.; Gregory, G. L.; Sachse, G.; Torres, A. L.

1989-01-01

Simultaneous high-resolution measurements of O3, NO, CO, dew point temperature, and UV flux obtained during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation (GTE/CITE 1) spring 1984 airborne field exercise over the eastern North Pacific Ocean are analyzed. Mid-tropospheric CO, O3, and NO mixing ratios averaged about 120 parts per billion by volume (ppbv), 50 ppbv, and 10 parts per trillion by volume (pptv), respectively. Statistical analysis of the high-resolution data indicates the existence of two ozone sources, one related to the downward transport of ozone-rich air from the upper troposphere and stratosphere, and the other to the transport of ozone-rich air from the continents. Modeling calculations based on these average levels imply that, from the surface to about 8 km, photochemical reactions probably supplied a net sink of ozone to the region overlying the eastern North Pacific Ocean during the sampling period. However, because the NO levels measured during the flights were frequently at or near the detection limit of the instruments and because the results are very sensitive to the absolute NO levels and their temporal variability, the conclusion must be considered provisional.

New capability for ozone dial profiling measurements in the troposphere and lower stratosphere from aircraft

NASA Astrophysics Data System (ADS)

Hair, Johnathan; Hostetler, Chris; Cook, Anthony; Harper, David; Notari, Anthony; Fenn, Marta; Newchurch, Mike; Wang, Lihua; Kuang, Shi; Knepp, Travis; Burton, Sharon; Ferrare, Richard; Butler, Carolyn; Collins, Jim; Nehrir, Amin

2018-04-01

Recently, we successfully demonstrated a new compact and robust ozone DIAL lidar for smaller aircraft such as the NASA B200 and the ER-2 high-altitude aircraft. This is the first NASA airborne lidar to incorporate advanced solid-state lasers to produce the required power at the required ultraviolet wavelengths, and is compact and robust enough to operate nearly autonomously on the high-altitude ER-2 aircraft. This technology development resulted in the first new NASA airborne ozone DIAL instrument in more than 15 years. The combined ozone, aerosol, and clouds measurements provide valuable information on the chemistry, radiation, and dynamics of the atmosphere. In particular, from the ER-2 it offers a unique capability to study the upper troposphere and lower stratosphere.

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

NASA Astrophysics Data System (ADS)

Chance, K.; Liu, X.; Suleiman, R. M.; Flittner, D. E.; Janz, S. J.

2012-12-01

TEMPO is a proposed concept to measure pollution for greater North America using ultraviolet/visible spectroscopy. TEMPO measures from Mexico City to the Canadian tar/oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (9 km2). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, reducing uncertainty in air quality predictions by 50%. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO makes the first tropospheric trace gas measurements from GEO, by building on the heritage of five spectrometers flown in low-earth-orbit (LEO). These LEO instruments measure the needed spectra, although at coarse spatial and temporal resolutions, to the precisions required for TEMPO and use retrieval algorithms developed for them by TEMPO Science Team members and currently running in operational environments. This makes TEMPO an innovative use of a well proven technique, able to produce a revolutionary data set. TEMPO provides much of the atmospheric measurement capability recommended for GEO-CAPE in the 2007

Chemistry in the Troposphere.

ERIC Educational Resources Information Center

Chameides, William L.; Davis, Douglas D.

1982-01-01

Topics addressed in this review of chemistry in the troposphere (layer of atmosphere extending from earth's surface to altitude of 10-16km) include: solar radiation/winds; earth/atmosphere interface; kinetic studies of atmospheric reactions; tropospheric free-radical photochemistry; instruments for nitric oxide detection; sampling…

Monitoring Natural Events Globally in Near Real-Time Using NASA's Open Web Services and Tools

NASA Technical Reports Server (NTRS)

Boller, Ryan A.; Ward, Kevin Alan; Murphy, Kevin J.

2015-01-01

Since 1960, NASA has been making global measurements of the Earth from a multitude of space-based missions, many of which can be useful for monitoring natural events. In recent years, these measurements have been made available in near real-time, making it possible to use them to also aid in managing the response to natural events. We present the challenges and ongoing solutions to using NASA satellite data for monitoring and managing these events.

Climatic and ecological impacts of tropospheric sulphate aerosols on the terrestrial carbon cycle

NASA Astrophysics Data System (ADS)

Eliseev, Alexey V.

2015-04-01

Tropospheric sulphate aerosols (TSA) may oxidise the photosynthesising tissues if they are taken up by plants. A parametrisation of this impact of tropospheric sulphate aerosols (TSA) on the terrestrial gross primary production is suggested. This parametrisation is implemented into the global Earth system model developed at the A.M. Obukhov Institute of the Atmospheric Physics, Russian Academy of Sciences (IAP RAS CM). With this coupled model, the simulations are performed which are forced by common anthropogenic and natural climate forcings based on historical reconstructions followed by the RCP 8.5 scenario. The model response to sulphate aerosol loading is subdivided into the climatic (related to the influence of TSA on the radiative transport in the atmosphere) and ecological (related to the toxic influence of sulphate aerosol on terrestrial plants) impacts. We found that the former basically dominates over the latter on the global scale and modifies the responses of the global vegetation and soil carbon stocks to external forcings by 10%. At regional scale, however, ecological impact may be as much important as the climatic one.

Reactive Nitrogen, Ozone and Ozone Production in the Arctic Troposphere and the Impact of Stratosphere-Troposphere Exchange

NASA Technical Reports Server (NTRS)

Liang, Q.; Rodriquez, J. M.; Douglass, A. R.; Crawford, J. H.; Apel, E.; Bian, H.; Blake, D. R.; Brune, W.; Chin, M.; Colarco, P. R.;

Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

NASA Astrophysics Data System (ADS)

Liang, Q.; Rodriguez, J. M.; Douglass, A. R.; Crawford, J. H.; Olson, J. R.; Apel, E.; Bian, H.; Blake, D. R.; Brune, W.; Chin, M.; Colarco, P. R.; da Silva, A.; Diskin, G. S.; Duncan, B. N.; Huey, L. G.; Knapp, D. J.; Montzka, D. D.; Nielsen, J. E.; Pawson, S.; Riemer, D. D.; Weinheimer, A. J.; Wisthaler, A.

2011-12-01

We use aircraft observations obtained during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) mission to examine the distributions and source attributions of O3 and NOy in the Arctic and sub-Arctic region. Using a number of marker tracers, we distinguish various air masses from the background troposphere and examine their contributions to NOx, O3, and O3 production in the Arctic troposphere. The background Arctic troposphere has a mean O3 of ~60 ppbv and NOx of ~25 pptv throughout spring and summer with CO decreasing from ~145 ppbv in spring to ~100 ppbv in summer. These observed mixing ratios are not notably different from the values measured during the 1988 ABLE-3A and the 2002 TOPSE field campaigns despite the significant changes in emissions and stratospheric ozone layer in the past two decades that influence Arctic tropospheric composition. Air masses associated with stratosphere-troposphere exchange are present throughout the mid and upper troposphere during spring and summer. These air masses, with mean O3 concentrations of 140-160 ppbv, are significant direct sources of O3 in the Arctic troposphere. In addition, air of stratospheric origin displays net O3 formation in the Arctic due to its sustainable, high NOx (75 pptv in spring and 110 pptv in summer) and NOy (~800 pptv in spring and ~1100 pptv in summer). The air masses influenced by the stratosphere sampled during ARCTAS-B also show conversion of HNO3 to PAN. This active production of PAN is the result of increased degradation of ethane in the stratosphere-troposphere mixed air mass to form CH3CHO, followed by subsequent formation of PAN under high NOx conditions. These findings imply that an adequate representation of stratospheric NOy input, in addition to stratospheric O3 influx, is essential to accurately simulate tropospheric Arctic O3, NOx and PAN in chemistry transport models. Plumes influenced by recent anthropogenic and biomass burning emissions

TOMS Tropical Tropospheric Ozone Data Sets at the University of Maryland Website

NASA Technical Reports Server (NTRS)

Kochhar, A. K.; Thompson, A. M.; Hudson, R. D.; Frolov, A. D.; Witte, J. C.; Einaudi, Franco (Technical Monitor)

2001-01-01

Since 1997, shortly after the launch of the Earth-Probe TOMS (Total Ozone Mapping Spectrometer) satellite instrument, we have been processing data in near-real time to post maps of tropical tropospheric ozone at a website: metosrv2.umd.edu/-tropo. Daily, 3-day and 9-day averages of tropical tropospheric ozone column depth (TTO) are viewable from 10N to 10S. Data can be downloaded (running 9-day means) from 20N-30S. Pollution events are trackable along with dynamically-induced variations in tropospheric ozone column. TOMS smoke aerosol (toms.gsfc.nasa.gov) can be used to interpret biomass burning ozone, as for example, during the extreme ozone and smoke pollution period during the ENSO-related fires of August November 1997. During that time plumes of ozone and smoke were frequently decoupled and ozone from Indonesian fires and from Africa merged in one large feature by late October 1997. In addition to the Earth-Probe TOMS record, data as half-month averages and as daily 9-day means from the Nimbus 7 TOMS instrument are at the metosrv2.umd.edu/-tropo website. A guide to the website and examples of ozone time-series and maps will be shown.

Tropospheric Enhancement of Ozone over the UAE

NASA Astrophysics Data System (ADS)

Abbasi, Naveed Ali; Majeed, Tariq; Iqbal, Mazhar; Kaminski, Jacek; Struzewska, Joanna; Durka, Pawel; Tarasick, David; Davies, Jonathan

2015-04-01

We use the Global Environmental Multiscale - Air Quality (GEM-AQ) model to interpret the vertical profiles of ozone acquired with ozone sounding experiments at the meteorological site located at the Abu Dhabi airport. The purpose of this study is to gain insight into the chemical and dynamical structures in the atmosphere of this unique subtropical location (latitude 24.45N; longitude 54.22E). Ozone observations for years 2012 - 2013 reveal elevated ozone abundances in the range from 70 ppbv to 120 ppbv near 500-400 hPa during summer. The ozone abundances in other seasons are much lower than these values. The preliminary results indicate that summertime enhancement in ozone is associated with the Arabian anticyclones centered over the Zagros Mountains in Iran and the Asir and Hijaz Mountain ranges in Saudi Arabia, and is consistent with TES observations of deuterated water. The model also shows considerable seasonal variation in the tropospheric ozone which is transported from the stratosphere by dynamical processes. The domestic production of ozone in the middle troposphere is estimated and compared GEM-AQ model. It is estimated that about 40-50% of ozone in the UAE is transported from the neighbouring petrochemical industries in the Gulf region. We will present ozone sounding data and GEM-AQ results including a discussion on the high levels of the tropospheric ozone responsible for contaminating the air quality in the UAE. This work is supported by National Research Foundation, UAE.

Future Climate Impacts of Direct Radiative Forcing Anthropogenic Aerosols, Tropospheric Ozone, and Long-lived Greenhouse Gases

NASA Technical Reports Server (NTRS)

Chen, Wei-Ting; Liao, Hong; Seinfeld, John H.

2007-01-01

Long-lived greenhouse gases (GHGs) are the most important driver of climate change over the next century. Aerosols and tropospheric ozone (O3) are expected to induce significant perturbations to the GHG-forced climate. To distinguish the equilibrium climate responses to changes in direct radiative forcing of anthropogenic aerosols, tropospheric ozone, and GHG between present day and year 2100, four 80-year equilibrium climates are simulated using a unified tropospheric chemistry-aerosol model within the Goddard Institute for Space Studies (GISS) general circulation model (GCM) 110. Concentrations of sulfate, nitrate, primary organic (POA) carbon, secondary organic (SOA) carbon, black carbon (BC) aerosols, and tropospheric ozone for present day and year 2100 are obtained a priori by coupled chemistry-aerosol GCM simulations, with emissions of aerosols, ozone, and precursors based on the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emissions Scenario (SRES) A2. Changing anthropogenic aerosols, tropospheric ozone, and GHG from present day to year 2100 is predicted to perturb the global annual mean radiative forcing by +0.18 (considering aerosol direct effects only), +0.65, and +6.54 W m(sup -2) at the tropopause, and to induce an equilibrium global annual mean surface temperature change of +0.14, +0.32, and +5.31 K, respectively, with the largest temperature response occurring at northern high latitudes. Anthropogenic aerosols, through their direct effect, are predicted to alter the Hadley circulation owing to an increasing interhemispheric temperature gradient, leading to changes in tropical precipitation. When changes in both aerosols and tropospheric ozone are considered, the predicted patterns of change in global circulation and the hydrological cycle are similar to those induced by aerosols alone. GHG-induced climate changes, such as amplified warming over high latitudes, weakened Hadley circulation, and increasing precipitation over the

Ozone, Tropospheric

NASA Technical Reports Server (NTRS)

Fishman, Jack

1995-01-01

In the early part of the 20th century, ground-based and balloon-borne measurements discovered that most of atmosphere's ozone is located in the stratosphere with highest concentrations located between 15 and 30 km (9,3 and 18.6 miles). For a long time, it was believed that tropospheric ozone originated from the stratosphere and that most of it was destroyed by contact with the earth's surface. Ozone, O3, was known to be produced by the photo-dissociation of molecular oxygen, O2, a process that can only occur at wavelengths shorter than 242 nm. Because such short-wave-length radiation is present only in the stratosphere, no tropospheric ozone production is possible by this mechanism. In the 1940s, however, it became obvious that production of ozone was also taking place in the troposphere. The overall reaction mechanism was eventually identified by Arie Haagen-Smit of the California Institute of Technology, in highly polluted southern California. The copious emissions from the numerous cars driven there as a result of the mass migration to Los Angeles after World War 2 created the new unpleasant phenomenon of photochemical smog, the primary component of which is ozone. These high levels of ozone were injuring vegetable crops, causing women's nylons to run, and generating increasing respiratory and eye-irritation problems for the populace. Our knowledge of tropospheric ozone increased dramatically in the early 1950s as monitoring stations and search centers were established throughout southern California to see what could be done to combat this threat to human health and the environment.

Intercomparison of 4 Years of Global Formaldehyde Observations from the GOME-2 and OMI Sensors

NASA Astrophysics Data System (ADS)

De Smedt, Isabelle; Van Roozendael, Michel; Stravrakou, Trissevgeni; Muller, Jean-Francois; Chance, Kelly; Kurosu, Thomas

2012-11-01

Formaldehyde (H2CO) tropospheric columns have been retrieved since 2007 from backscattered UV radiance measurements performed by the GOME-2 instrument on the EUMETSAT METOP-A platform. This data set extends the successful time-series of global H2CO observations established with GOME/ ERS-2 (1996-2003), SCIAMACHY/ ENVISAT (2003-2012), and OMI on the NASA AURA platform (2005-now). In this work, we perform an intercomparison of the H2CO tropospheric columns retrieved from GOME-2 and OMI between 2007 and 2010, respectively at BIRA-IASB and at Harvard SAO. We first compare the global formaldehyde data products that are provided by each retrieval group. We then investigate each step of the retrieval procedure: the slant column fitting, the reference sector correction and the air mass factor calculation. New air mass factors are computed for OMI using external parameters consistent with those used for GOME-2. By doing so, the impacts of the different a priori profiles and aerosol corrections are quantified. The remaining differences are evaluated in view of the expected diurnal variations of the formaldehyde concentrations, based on ground-based measurements performed in the Beijing area.

Software for Generating Troposphere Corrections for InSAR Using GPS and Weather Model Data

NASA Technical Reports Server (NTRS)

Moore, Angelyn W.; Webb, Frank H.; Fishbein, Evan F.; Fielding, Eric J.; Owen, Susan E.; Granger, Stephanie L.; Bjoerndahl, Fredrik; Loefgren, Johan; Fang, Peng; Means, James D.;

A GLOBAL ASSESSMENT OF SOLAR ENERGY RESOURCES: NASA's Prediction of Worldwide Energy Resources (POWER) Project

NASA Astrophysics Data System (ADS)

Zhang, T.; Stackhouse, P. W., Jr.; Chandler, W.; Hoell, J. M.; Westberg, D.; Whitlock, C. H.

2010-12-01

NASA's POWER project, or the Prediction of the Worldwide Energy Resources project, synthesizes and analyzes data on a global scale. The products of the project find valuable applications in the solar and wind energy sectors of the renewable energy industries. The primary source data for the POWER project are NASA's World Climate Research Project (WCRP)/Global Energy and Water cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project (Release 3.0) and the Global Modeling and Assimilation Office (GMAO) Goddard Earth Observing System (GEOS) assimilation model (V 4.0.3). Users of the POWER products access the data through NASA's Surface meteorology and Solar Energy (SSE, Version 6.0) website (http://power.larc.nasa.gov). Over 200 parameters are available to the users. The spatial resolution is 1 degree by 1 degree now and will be finer later. The data covers from July 1983 to December 2007, a time-span of 24.5 years, and are provided as 3-hourly, daily and monthly means. As of now, there have been over 18 million web hits and over 4 million data file downloads. The POWER products have been systematically validated against ground-based measurements, and in particular, data from the Baseline Surface Radiation Network (BSRN) archive, and also against the National Solar Radiation Data Base (NSRDB). Parameters such as minimum, maximum, daily mean temperature and dew points, relative humidity and surface pressure are validated against the National Climate Data Center (NCDC) data. SSE feeds data directly into Decision Support Systems including RETScreen International clean energy project analysis software that is written in 36 languages and has greater than 260,000 users worldwide.

Corrections of stratified tropospheric delays in SAR interferometry: Validation with global atmospheric models

NASA Astrophysics Data System (ADS)

Doin, Marie-Pierre; Lasserre, Cécile; Peltzer, Gilles; Cavalié, Olivier; Doubre, Cécile

2010-05-01

The main limiting factor on the accuracy of Interferometric SAR measurements (InSAR) comes from phase propagation delays through the troposphere. The delay can be divided into a stratified component, which correlates with the topography and often dominates the tropospheric signal, and a turbulent component. We use Global Atmospheric Models (GAM) to estimate the stratified phase delay and delay-elevation ratio at epochs of SAR acquisitions, and compare them to observed phase delay derived from SAR interferograms. Three test areas are selected with different geographic and climatic environments and with large SAR archive available. The Lake Mead, Nevada, USA is covered by 79 ERS1/2 and ENVISAT acquisitions, the Haiyuan Fault area, Gansu, China, by 24 ERS1/2 acquisitions, and the Afar region, Republic of Djibouti, by 91 Radarsat acquisitions. The hydrostatic and wet stratified delays are computed from GAM as a function of atmospheric pressure P, temperature T, and water vapor partial pressure e vertical profiles. The hydrostatic delay, which depends on ratio P/T, varies significantly at low elevation and cannot be neglected. The wet component of the delay depends mostly on the near surface specific humidity. GAM predicted delay-elevation ratios are in good agreement with the ratios derived from InSAR data away from deforming zones. Both estimations of the delay-elevation ratio can thus be used to perform a first order correction of the observed interferometric phase to retrieve a ground motion signal of low amplitude. We also demonstrate that aliasing of daily and seasonal variations in the stratified delay due to uneven sampling of SAR data significantly bias InSAR data stacks or time series produced after temporal smoothing. In all three test cases, the InSAR data stacks or smoothed time series present a residual stratified delay of the order of the expected deformation signal. In all cases, correcting interferograms from the stratified delay removes all these

Corrections of stratified tropospheric delays in SAR interferometry: Validation with global atmospheric models

NASA Astrophysics Data System (ADS)

Doin, M.-P.; Lasserre, C.; Peltzer, G.; Cavalié, O.; Doubre, C.

2009-09-01

The main limiting factor on the accuracy of Interferometric SAR measurements (InSAR) comes from phase propagation delays through the troposphere. The delay can be divided into a stratified component, which correlates with the topography and often dominates the tropospheric signal, and a turbulent component. We use Global Atmospheric Models (GAM) to estimate the stratified phase delay and delay-elevation ratio at epochs of SAR acquisitions, and compare them to observed phase delay derived from SAR interferograms. Three test areas are selected with different geographic and climatic environments and with large SAR archive available. The Lake Mead, Nevada, USA is covered by 79 ERS1/2 and ENVISAT acquisitions, the Haiyuan Fault area, Gansu, China, by 24 ERS1/2 acquisitions, and the Afar region, Republic of Djibouti, by 91 Radarsat acquisitions. The hydrostatic and wet stratified delays are computed from GAM as a function of atmospheric pressure P, temperature T, and water vapor partial pressure e vertical profiles. The hydrostatic delay, which depends on ratio P/ T, varies significantly at low elevation and cannot be neglected. The wet component of the delay depends mostly on the near surface specific humidity. GAM predicted delay-elevation ratios are in good agreement with the ratios derived from InSAR data away from deforming zones. Both estimations of the delay-elevation ratio can thus be used to perform a first order correction of the observed interferometric phase to retrieve a ground motion signal of low amplitude. We also demonstrate that aliasing of daily and seasonal variations in the stratified delay due to uneven sampling of SAR data significantly bias InSAR data stacks or time series produced after temporal smoothing. In all three test cases, the InSAR data stacks or smoothed time series present a residual stratified delay of the order of the expected deformation signal. In all cases, correcting interferograms from the stratified delay removes all these

Characterization of Upper-Troposphere Water Vapor Measurements during AFWEX Using LASE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferrare, Richard; Browell, E. V.; Ismail, S.

Water vapor profiles from NASA's Lidar Atmospheric Sensing Experiment (LASE) system acquired during the ARM/FIRE Water Vapor Experiment (AFWEX) are used to characterize upper troposphere water vapor (UTWV) measured by ground-based Raman lidars, radiosondes, and in situ aircraft sensors over the Department of Energy Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site in northern Oklahoma. LASE was deployed from the NASA DC-8 aircraft and measured water vapor over the ARM SGP Central Facility (CF) site during seven flights between November 27 and December 10, 2000. Initially, the DOE ARM SGP Cloud and Radiation Testbed (CART) Raman lidar (CARL) UTWVmore » profiles were about 5-7% wetter than LASE in the upper troposphere, and the Vaisala RS80-H radiosonde profiles were about 10% drier than LASE between 8-12 km. Scaling the Vaisala water vapor profiles to match the precipitable water vapor (PWV) measured by the ARM SGP microwave radiometer (MWR) did not change these results significantly. By accounting for an overlap correction of the CARL water vapor profiles and by employing schemes designed to correct the Vaisala RS80-H calibration method and account for the time response of the Vaisala RS80H water vapor sensor, the average differences between the CARL and Vaisala radiosonde upper troposphere water vapor profiles are reduced to about 5%, which is within the ARM goal of mean differences of less than 10%. The LASE and DC-8 in situ Diode Laser Hygrometer (DLH) UTWV measurements generally agreed to within about 3 to 4%. The DC-8 in situ frost point cryogenic hygrometer and Snow White chilled mirror measurements were drier than the LASE, Raman lidars, and corrected Vaisala RS80H measurements by about 10-25% and 10-15%, respectively. Sippican (formerly VIZ manufacturing) carbon hygristor radiosondes exhibited large variabilities and poor agreement with the other measurements. PWV derived from the LASE profiles agreed to within about 3% on average

A grid-based tropospheric product for China using a GNSS network

NASA Astrophysics Data System (ADS)

Zhang, Hongxing; Yuan, Yunbin; Li, Wei; Zhang, Baocheng; Ou, Jikun

2017-11-01

Tropospheric delay accounts for one source of error in global navigation satellite systems (GNSS). To better characterize the tropospheric delays in the temporal and spatial domain and facilitate the safety-critical use of GNSS across China, a method is proposed to generate a grid-based tropospheric product (GTP) using the GNSS network with an empirical tropospheric model, known as IGGtrop. The prototype system generates the GTPs in post-processing and real-time modes and is based on the undifferenced and uncombined precise point positioning (UU-PPP) technique. GTPs are constructed for a grid form (2.0{°}× 2.5{°} latitude-longitude) over China with a time resolution of 5 min. The real-time GTP messages are encoded in a self-defined RTCM3 format and broadcast to users using NTRIP (networked transport of RTCM via internet protocol), which enables efficient and safe transmission to real-time users. Our approach for GTP generation consists of three sequential steps. In the first step, GNSS-derived zenith tropospheric delays (ZTDs) for a network of GNSS stations are estimated using UU-PPP. In the second step, vertical adjustments for the GNSS-derived ZTDs are applied to address the height differences between the GNSS stations and grid points. The ZTD height corrections are provided by the IGGtrop model. Finally, an inverse distance weighting method is used to interpolate the GNSS-derived ZTDs from the surrounding GNSS stations to the location of the grid point. A total of 210 global positioning system (GPS) stations from the crustal movement observation network of China are used to generate the GTPs in both post-processing and real-time modes. The accuracies of the GTPs are assessed against with ERA-Interim-derived ZTDs and the GPS-derived ZTDs at 12 test GPS stations, respectively. The results show that the post-processing and real-time GTPs can provide the ZTDs with accuracies of 1.4 and 1.8 cm, respectively. We also apply the GTPs in real-time kinematic GPS PPP

Evaluating tropospheric humidity from GPS radio occultation, radiosonde, and AIRS from high-resolution time series

NASA Astrophysics Data System (ADS)

Rieckh, Therese; Anthes, Richard; Randel, William; Ho, Shu-Peng; Foelsche, Ulrich

2018-05-01

While water vapor is the most important tropospheric greenhouse gas, it is also highly variable in both space and time, and water vapor concentrations range over 3 orders of magnitude in the troposphere. These properties challenge all observing systems to accurately measure and resolve the vertical structure and variability of tropospheric humidity. In this study we characterize the humidity measurements of various observing techniques, including four separate Global Positioning System (GPS) radio occultation (RO) humidity retrievals (University Corporation for Atmospheric Research (UCAR) direct, UCAR one-dimensional variational retrieval (1D-Var), Wegener Center for Climate and Global Change (WEGC) 1D-Var, Jet Propulsion Laboratory (JPL) direct), radiosonde, and Atmospheric Infrared Sounder (AIRS) data. Furthermore, we evaluate how well the ERA-Interim reanalysis and NCEP Global Forecast System (GFS) model perform in analyzing water vapor at different levels. To investigate detailed vertical structure, we analyzed time-height cross sections over four radiosonde stations in the tropical and subtropical western Pacific for the year 2007. We found that the accuracy of RO humidity is comparable to or better than both radiosonde and AIRS humidity over 800 to 400 hPa, as well as below 800 hPa if super-refraction is absent. The various RO retrievals of specific humidity agree within 20 % in the 1000-400 hPa layer, and differences are most pronounced above 600 hPa.

Exploration of OMI Products for Air Quality Applications Through Comparisons with Models and Observations

NASA Technical Reports Server (NTRS)

Pickering, K. E.; Ziemke, J.; Bucsela, E.; Gleason, J.; Marufu, L.; Dickerson, R.; Mathur, R.; Davidson, P.; Duncan, B.; Bhartia, P. K.

2006-01-01

The Ozone Monitoring Instrument (OMI) on board NASA s Aura satellite was launched in July 2004, and is now providing daily global observations of total column ozone, NO2, and SO2, as well as aerosol information. Algorithms have also been developed to produce daily tropospheric ozone and NO2 products. The tropospheric ozone product reported here is a tropospheric residual computed through use of Aura Microwave Limb Sounder (MLS) ozone profile data to quantify stratospheric ozone. We are investigating the applicability of OMI products for use in air quality modeling, forecasting, and analysis. These investigations include comparison of the OMI tropospheric O3 and NO2 products with global and regional models and with lower tropospheric aircraft observations. Large-scale transport of pollution seen in the OM1 tropospheric O3 data is compared with output from NASA's Global Modeling Initiative global chemistry and transport model. On the regional scale we compare the OMI tropospheric O3 and NO2 with fields from the National Oceanic and Atmospheric Administration and Environmental Protection Agency (NOAA/EPA) operational Eta/CMAQ air quality forecasting model over the eastern United States. This 12-km horizontal resolution model output is roughly of equivalent resolution to the OMI pixel data. Correlation analysis between lower tropospheric aircraft O3 profile data taken by the University of Maryland over the Mid-Atlantic States and OMI tropospheric column mean volume mixing ratio for O3 will be presented. These aircraft data are representative of the lowest 3 kilometers of the atmosphere, the region in which much of the locally-generated and regionally-transported ozone exists.

HIWRAP Radar Development for High-Altitude Operation on the NASA Global Hawk and ER-2

NASA Technical Reports Server (NTRS)

Li, Lihua; Heymsfield, Gerlad; Careswell, James; Schaubert, Dan; Creticos, Justin

2011-01-01

The NASA High-Altitude Imaging Wind and Rain Airborne Profiler (HIWRAP) is a solid-state transmitter-based, dual-frequency (Ka- and Ku-band), dual-beam (30 degree and 40 degree incidence angle), conical scan Doppler radar system, designed for operation on the NASA high-altitude (20 km) aircrafts, such as the Global Hawk Unmanned Aerial System (UAS). Supported by the NASA Instrument Incubator Program (IIP), HIWRAP was developed to provide high spatial and temporal resolution 3D wind and reflectivity data for the research of tropical cyclone and severe storms. With the simultaneous measurements at both Ku- and Ka-band two different incidence angles, HIWRAP is capable of imaging Doppler winds and volume backscattering from clouds and precipitation associated with tropical storms. In addition, HIWRAP is able to obtain ocean surface backscatter measurements for surface wind retrieval using an approach similar to QuikScat. There are three key technology advances for HIWRAP. Firstly, a compact dual-frequency, dual-beam conical scan antenna system was designed to fit the tight size and weight constraints of the aircraft platform. Secondly, The use of solid state transmitters along with a novel transmit waveform and pulse compression scheme has resulted in a system with improved performance to size, weight, and power ratios compared to typical tube based Doppler radars currently in use for clouds and precipitation measurements. Tube based radars require high voltage power supply and pressurization of the transmitter and radar front end that complicates system design and implementation. Solid state technology also significantly improves system reliability. Finally, HIWRAP technology advances also include the development of a high-speed digital receiver and processor to handle the complex receiving pulse sequences and high data rates resulting from multi receiver channels and conical scanning. This paper describes HIWRAP technology development for dual-frequency operation at

Monitoring Tropospheric Ozone Enhancement in the Front Range Using the Gsfc Tropoz DIAL during Discover - AQ 2014

NASA Astrophysics Data System (ADS)

Sullivan, J. T.; McGee, T. J.; Hoff, R. M.; Twigg, L.; Sumnicht, G. K.

2014-12-01

Tropospheric ozone profiles have been retrieved from the new ground based National Aeronautics and Space Administration (NASA) Goddard Space Flight Center TROPospheric OZone DIfferential Absorption Lidar (GSFC TROPOZ DIAL) in Fort Collins, CO from 200 m to 16 km AGL. These measurements were taken as part of NASA's DISCOVER-AQ campaign in July/August 2014. Measurements were made during simultaneous aircraft spirals over the lidar site as well as collocated ozonesonde launches. Ozone enhancement from local sources typically occurred in the mid-afternoon convection period, especially when there was light winds and low cloud cover. Interesting ozone profiles and time series data will be shown. Current atmospheric satellite instruments cannot peer through the optically thick stratospheric ozone layer to remotely sense boundary layer tropospheric ozone. In order to monitor this lower ozone more effectively, the Tropospheric Ozone Lidar Network (TOLNet) has been developed, which currently consists of five stations across the US. Three of these lidars, including the GSFC TROPOZ DIAL, recorded measurements during the DISCOVER-AQ campaign. The GSFC TROPOZ DIAL is based on the Differential Absorption Lidar (DIAL) technique, which currently detects two wavelengths, 289 and 299 nm. Ozone is absorbed more strongly at 289 nm than at 299 nm. The DIAL technique exploits this difference between the returned backscatter signals to obtain the ozone number density as a function of altitude. The transmitted wavelengths are generated by focusing the output of a quadrupled Nd:YAG laser beam (266 nm) into a pair of Raman cells, filled with high pressure hydrogen and deuterium. Stimulated Raman Scattering (SRS) within the focus generates a significant fraction of the pump energy at the first Stokes shift. With the knowledge of the ozone absorption coefficient at these two wavelengths, the range resolved number density can be derived.

Multiwavelength Comparison of Modeled and Measured Remote Tropospheric Aerosol Backscatter Over Pacific Ocean

NASA Technical Reports Server (NTRS)

Cutten, D. R.; Pueschel, R. F.; Srivastava, V.; Clarke, A. D.; Rothermel, J.; Spinhirne, J. D.; Menzies, R. T.

1996-01-01

Aerosol concentrations and size distributions in the middle and upper troposphere over the remote Pacific Ocean were measured with a forward scattering spectrometer probe (FSSP) on the NASA DC-8 aircraft during NASA's Global Backscatter Experiment (GLOBE) in May-June 1990. The FSSP size channels were recalibrated based on refractive index estimates from flight-level aerosol volatility measurements with a collocated laser optical particle counter (LOPC). The recalibrated FSSP size distributions were averaged over 100-s intervals, fitted with lo-normal distributions and used to calculate aerosol backscatter coefficients at selected wavelengths. The FSSP-derived backscatter estimates were averaged over 300-s intervals to reduce large random fluctuations. The smoothed FSSP aerosol backscatter coefficients were then compared with LOPC-derived backscatter values and with backscatter measured at or near flight level from four lidar systems operating at 0.53, 1.06, 9.11, 9.25, and 10.59 micrometers. Agreement between FSSP-derived and lidar-measured backscatter was generally best at flight level in homogeneous aerosol fields and at high backscatter values. FSSP data often underestimated low backscatter values especially at the longer wavelengths due to poor counting statistics for larger particles (greater than 0.8 micrometers diameter) that usually dominate aerosol backscatter at these wavelengths. FSSP data also underestimated backscatter at shorter wavelengths when particles smaller than the FSSP lower cutoff diameter (0.35 micrometers) made significant contributions to the total backscatter.

NASA's Modern Era Retrospective-Analysis for Research and Applications (MERRA): Early Results and Future Directions

NASA Technical Reports Server (NTRS)

Schubert, Siegfried

2008-01-01

This talk will review the status and progress of the NASA/Global Modeling and Assimilation Office (GMAO) atmospheric global reanalysis project called the Modern Era Retrospective-Analysis for Research and Applications (MERRA). An overview of NASA's emerging capabilities for assimilating a variety of other Earth Science observations of the land, ocean, and atmospheric constituents will also be presented. MERRA supports NASA Earth science by synthesizing the current suite of research satellite observations in a climate data context (covering the period 1979-present), and by providing the science and applications communities with of a broad range of weather and climate data with an emphasis on improved estimates of the hydrological cycle. MERRA is based on a major new version of the Goddard Earth Observing System Data Assimilation System (GEOS-5), that includes the Earth System Modeling Framework (ESMF)-based GEOS-5 atmospheric general circulation model and the new NOAA National Centers for Environmental Prediction (NCEP) unified grid-point statistical interpolation (GST) analysis scheme developed as a collaborative effort between NCEP and the GMAO. In addition to MERRA, the GMAO is developing new capabilities in aerosol and constituent assimilation, ocean, ocean biology, and land surface assimilation. This includes the development of an assimilation capability for tropospheric air quality monitoring and prediction, the development of a carbon-cycle modeling and assimilation system, and an ocean data assimilation system for use in coupled short-term climate forecasting.

Measurements of nitric acid, carboxylic acids, and selected aerosol species for the NASA/GTE Pacific Mission - West (PEM-WEST)

NASA Technical Reports Server (NTRS)

Talbot, Robert W.; Dibb, Jack E.

1993-01-01

The research investigation funded through this grant to the University of New Hampshire was performed during a major field expedition conducted by the NASA Tropospheric Chemistry Program. The NASA Global Tropospheric Experiment (GTE) executed an airborne science mission (PEM-WEST A) aboard the NASA Ames DC-8 over the Pacific Ocean during Sep./Oct. 1981. The atmosphere over the central Pacific Ocean is the only major region in the Northern Hemisphere that is relatively free from direct anthropogenic influence. Thus, this environment is ideally suited to study the natural biogeochemical cycles of carbon, nitrogen, ozone, sulfur, and aerosols without serious confounding problems related to anthropogenic emissions. Asian sources account for about 17 percent of the global budgets of nitrogen oxides (NO(x)) and sulfur dioxide (SO2). The Pacific Rim region therefore provides the opportunity to study the anthropogenic impact on natural atmospheric chemical cycles. The PEM-WEST A flights were focused on contrasting the chemistry of 'clean' air over the central Pacific with anthropogenically impacted air advected off the Asian continent. The principal objectives of PEM-WEST A were to investigate the atmospheric chemistry of ozone (O3) and its precursors, and to study important aspects of the atmospheric sulfur cycle over the western Pacific Ocean. Measurements conducted by the University of New Hampshire contributed directly to both of these objectives. Subsequent PEM-WEST field missions are planned by GTE in the mid-1990's to contrast atmospheric chemistry documented during PEM-WEST A with other time periods. This report presents preliminary findings from the PEM-WEST A field mission. Data interpretation is currently ongoing with the goal of manuscript submission of scientific results to a special issue of the Journal of Geophysical Research-Atmospheres in Feb. 1994. The reader is strongly encouraged to review this suite of profession articles to appreciate the overall

The NASA Marshall Space Flight Center Earth Global Reference Atmospheric Model-2010 Version

NASA Technical Reports Server (NTRS)

Leslie, F. W.; Justus, C. G.

2011-01-01

Reference or standard atmospheric models have long been used for design and mission planning of various aerospace systems. The NASA Marshall Space Flight Center Global Reference Atmospheric Model was developed in response to the need for a design reference atmosphere that provides complete global geographical variability and complete altitude coverage (surface to orbital altitudes), as well as complete seasonal and monthly variability of the thermodynamic variables and wind components. In addition to providing the geographical, height, and monthly variation of the mean atmospheric state, it includes the ability to simulate spatial and temporal perturbations.

Changes in tropospheric composition and air quality due to stratospheric ozone depletion.

PubMed

Solomon, Keith R; Tang, Xiaoyan; Wilson, Stephen R; Zanis, Prodromos; Bais, Alkiviadis F

2003-01-01

chemical composition of the atmosphere including aerosols will also have an impact. For example, tropospheric OH is the 'cleaning' agent of the troposphere. While increased UV-B increases the OH concentration, increases in concentration of gases like methane, carbon monoxide and volatile organic compounds will act as sinks for OH in troposphere and hence change air quality and chemical composition in the troposphere. Also, changes in the aerosol content of the atmosphere resulting from global climate change may affect ozone photolysis rate coefficients and hence reduce or increase tropospheric ozone concentrations.

A multi-year Record of Total Column and Lower-Tropospheric Methane

NASA Astrophysics Data System (ADS)

Worden, J.; Yin, Y.; Frankenberg, C.; Bloom, A. A.

2017-12-01

Evaluating carbon / climate interactions and feedbacks and their effects on global fluxes of methane require a record of well-calibrated and validated methane data that is long enough to span several perturbations to rain and drought related to ENSO or other climactic perturbations along with the spatial sampling that can infer how these changes in the water and carbon cycles affect methane fluxes from wetlands and fires. Here we describe the first version of a decadal scale record of total column and lower-tropospheric methane derived from reflected sunlight and thermal IR measurements (SCIAMACHY, GOSAT, TES, and AIRS). We describe the validation of these data sets using independent data such as from TCCON, the surface network, and aircraft and how they can be inter-calibrated using a global atmospheric model as a transfer function to construct a long-term data record. We show how the new lower-tropospheric measurements can potentially provide new insights into wetland fluxes and how they vary inter-annually with rainfall and temperature perturbations.

Long Term δ17O, δ18O measurements of tropospheric carbon dioxide and potential application to the global carbon cycle. (Invited)

NASA Astrophysics Data System (ADS)

Thiemens, M. H.

2009-12-01

Stable isotope ratio measurements have played an important role in defining the global carbon cycle for the past half century. In the past decades, mass independent isotopic measurements of stratospheric carbon dioxide have been shown to be an important indice for understanding stratospheric ozone chemistry and the interaction with carbon dioxide. In this specific role, it is the O(1D) produced from ozone photolysis that interacts with CO2 and inscribes a mass independent isotopic composition (see review by (1)). This photochemical process simultaneously provides an isotopic record in carbon dioxide of the integrated exposure to ozone/atomic oxygen and stratosphere troposphere mixing. As a consequence of these processes, it has been observed that tropospheric oxygen possesses a mass independent composition that may be used as a tracer of bioproductivity (2) and as a potential measure of carbon dioxide levels during and following the snowball earth event (3). In addition, the magnitude of the stratospheric anomaly in the troposphere may directly reflect the atmospheric turnover rates of carbon dioxide, which is an important component of the carbon cycle (4, 5). To further develop this new methodology, the rates and magnitude of the relevant processes must be identified and quantified. Samples of tropospheric carbon dioxide were obtained in La Jolla, Ca. over a 10 year plus time period. All samples were taken under identical conditions and analyzed immediately for all three oxygen isotopes. There was no sample storage and samples were thoroughly isolated from water. All conditions, including standardization and mass spectrometry were constant throughout that time period. The data are consistent with an identifiable steady state component of stratospheric carbon dioxide. In addition, other features of the data suggest other processes operative that are presently unaccounted for, and, are only observable in the mass independent composition. References 1. Thiemens, M

Observations and modeling of bromine induced mercury oxidation in the tropical free troposphere during TORERO

NASA Astrophysics Data System (ADS)

Coburn, Sean; Wang, Siyuan; terSchure, Arnout; Evans, Matt; Volkamer, Rainer

2013-04-01

The Tropical Ocean tRoposphere Exchange experiment TORERO (Jan/Feb 2012) probed air-sea exchange of very short lived halogens and organic carbon species over the full tropospheric air column above the eastern tropical Pacific Ocean. It is well known that halogens influence the oxidative capacity in the marine boundary layer, but their distribution and abundance is less clear in the tropical free troposphere, where most of tropospheric ozone mass resides, and about 80% of the global methane destruction occurs. The oxidation of elemental mercury (GEM) by halogens (i.e., bromine) further forms gaseous oxidized mercury (GOM), and this oxidation is accelerated at the low temperatures in the free troposphere compared to the boundary layer. Free tropospheric halogen radical abundances are thus of particular importance to understand the entry pathways for GOM deposition from the free troposphere to ecosystem, and the subsequent bio-accumulation of this neurotoxin. This presentation summarizes new observational evidence for halogen vertical distributions over the full tropospheric air column, and their abundance in the tropical troposphere, at mid-latitudes in the Northern and Southern hemisphere. BrO and IO were measured simultaneously by the CU Airborne MAX-DOAS instrument, and organic halogen precursors were measured by online GC-MS (TOGA) during 22 research flights aboard the NSF/NCAR GV aircraft. We employ atmospheric box modeling constrained by observations of gas-phase hydrocarbons, aerosols, photolysis frequencies, and meterological parameters measured aboard the plane to test the observed BrO and IO abundances, and evaluate the rate of GEM oxidation in light of recent updates about the stability of the Hg-Br adduct, and it's fate (Goodsite et al., 2012; Dibble et al., 2012). Finally, we compare our measurements with output from the GEOS-Chem model for selected case studies.

Light-Absorbing Aerosol during NASA GRIP: Overview of Observations in the Free Troposphere and Associated with Tropical Storm Systems

NASA Astrophysics Data System (ADS)

Ziemba, L. D.; Beyersdorf, A. J.; Chen, G.; Corr, C. A.; Craig, L.; Dhaniyala, S.; Dibb, J. E.; Hudgins, C. H.; Ismail, S.; Latham, T.; Nenes, A.; Thornhill, K. L.; Winstead, E.; Anderson, B. E.

2010-12-01

Aerosols play a significant role in regulating Earth’s climate. Absorbing aerosols typically constitute a small fraction of ambient particle mass but can contribute significantly to direct and indirect climate forcing depending on size, mixing state, concentration, chemical composition, and vertical and spatial distribution. Aerosols may also significantly affect tropical storm/hurricane dynamics through direct light absorption and activation as cloud nuclei. An extensive suite of instrumentation measuring aerosol chemical, physical, and optical properties was deployed aboard the NASA DC-8 to characterize aerosol during the NASA GRIP (Genesis and Rapid Intensification Processes; August-September 2010) mission. The majority of flight time was spent at high altitude (greater than 9 km) and thus much of the sampling was done in the free troposphere, including extensive sampling in the vicinity of tropical storm systems and more diffuse cirrus clouds. With operations based in Fort Lauderdale, FL and St. Croix, U.S. Virgin Islands, a large geographic region was sampled including much of the Gulf of Mexico and tropical Atlantic Ocean. Observations are reported for light-absorbing carbon aerosol (mainly black carbon, BC) primarily using a single particle soot photometer (SP2). The SP2 employs single-particle laser-induced incandescence to provide a mass-specific measurement not subject to scattering interference that is optimal for the low concentration environments like those encountered during GRIP. BC mass concentrations, 100-500 nm size distributions, and mixing state (i.e. coating thickness of scattering material) are presented. Total and sub-micron aerosol absorption coefficients (principally from BC and dust aerosol) are reported using a particle soot absorption photometer (PSAP) along with comparisons with calculated absorption coefficients derived from SP2 observations in various conditions. In addition, dust aerosol is specifically identified using optical and

Inter-Annual and Decadal Changes in Tropospheric and Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Ziemke, Jr. R.; Chandra, S.

2011-01-01

Ozone data beginning October 2004 from the Aura Ozone Monitoring Instrument (OMI) and Aura Microwave Limb Sounder (MLS) are used to evaluate the accuracy of the Cloud slicing technique in effort to develop long data records of tropospheric and stratospheric ozone and studying their long-term changes. Using this technique, we have produced a 32-year (1979-2010) long record of tropospheric and stratospheric ozone from the combined Total Ozone Mapping Spectrometer (Toms) and OMI. The analyses of these time series suggest that the quasi-biennial oscillation (QBO) is the dominant source of inter-annual changes of 30-40 Dobson Units (DU). Tropospheric ozone also indicates a QBO signal in the peak to peak changes varying from 2 to 7 DU. Decadal changes in global stratospheric ozone indicate a turnaround in ozone loss around mid 1990's with most of these changes occurring in the Northern Hemisphere from the subtropics to high latitudes. The trend results are generally consistent with the prediction of chemistry climate models which include the reduction of ozone destroying substances beginning in the late 1980's mandated by the Montreal Protocol.

NASA Earth Day 2014

NASA Image and Video Library

2014-04-22

NASA Administrator Charles Bolden poses for a quick selfie with students who attended the NASA sponsored Earth Day event April 22, 2014 at Union Station in Washington, DC. NASA announced the "Global Selfie" event as part of its "Earth Right Now" campaign, celebrating the launch of five Earth-observing missions in 2014. All selfies posted to social media with the hashtag "GlobalSelfie" will be included in a mosaic image of Earth. Photo Credit: (NASA/Aubrey Gemignani)

Reactive Nitrogen Distribution and Partitioning in the North American Troposphere and Lowermost Stratosphere

NASA Technical Reports Server (NTRS)

Singh, H. B.; Salas, L.; Herlth, D.; Kolyer, R.; Czech, E.; Avery, M.; Crawford, J. H.; Pierce, B.; Sachse, G. W.; Blake, D. R.;

Hydrogen Cyanide in the Upper Troposphere: GEM-AQ Simulation and Comparison with ACE-FTS Observations

NASA Technical Reports Server (NTRS)

Lupu, A.; Kaminski, J. W.; Neary, L.; McConnell, J. C.; Toyota, K.; Rinsland, C. P.; Bernath, P. F.; Walker, K. A.; Boone, C. D.; Nagahama, Y.;

Seasonal variability of stratospheric methane: implications for constraining tropospheric methane budgets using total column observations

NASA Astrophysics Data System (ADS)

Saad, Katherine M.; Wunch, Debra; Deutscher, Nicholas M.; Griffith, David W. T.; Hase, Frank; De Mazière, Martine; Notholt, Justus; Pollard, David F.; Roehl, Coleen M.; Schneider, Matthias; Sussmann, Ralf; Warneke, Thorsten; Wennberg, Paul O.

2016-11-01

Global and regional methane budgets are markedly uncertain. Conventionally, estimates of methane sources are derived by bridging emissions inventories with atmospheric observations employing chemical transport models. The accuracy of this approach requires correctly simulating advection and chemical loss such that modeled methane concentrations scale with surface fluxes. When total column measurements are assimilated into this framework, modeled stratospheric methane introduces additional potential for error. To evaluate the impact of such errors, we compare Total Carbon Column Observing Network (TCCON) and GEOS-Chem total and tropospheric column-averaged dry-air mole fractions of methane. We find that the model's stratospheric contribution to the total column is insensitive to perturbations to the seasonality or distribution of tropospheric emissions or loss. In the Northern Hemisphere, we identify disagreement between the measured and modeled stratospheric contribution, which increases as the tropopause altitude decreases, and a temporal phase lag in the model's tropospheric seasonality driven by transport errors. Within the context of GEOS-Chem, we find that the errors in tropospheric advection partially compensate for the stratospheric methane errors, masking inconsistencies between the modeled and measured tropospheric methane. These seasonally varying errors alias into source attributions resulting from model inversions. In particular, we suggest that the tropospheric phase lag error leads to large misdiagnoses of wetland emissions in the high latitudes of the Northern Hemisphere.

Utilization of GPS Tropospheric Delays for Climate Research

NASA Astrophysics Data System (ADS)

Suparta, Wayan

2017-05-01

The tropospheric delay is one of the main error sources in Global Positioning Systems (GPS) and its impact plays a crucial role in near real-time weather forecasting. Accessibility and accurate estimation of this parameter are essential for weather and climate research. Advances in GPS application has allowed the measurements of zenith tropospheric delay (ZTD) in all weather conditions and on a global scale with fine temporal and spatial resolution. In addition to the rapid advancement of GPS technology and informatics and the development of research in the field of Earth and Planetary Sciences, the GPS data has been available free of charge. Now only required sophisticated processing techniques but user friendly. On the other hand, the ZTD parameter obtained from the models or measurements needs to be converted into precipitable water vapor (PWV) to make it more useful as a component of weather forecasting and analysis atmospheric hazards such as tropical storms, flash floods, landslide, pollution, and earthquake as well as for climate change studies. This paper addresses the determination of ZTD as a signal error or delay source during the propagation from the satellite to a receiver on the ground and is a key driving force behind the atmospheric events. Some results in terms of ZTD and PWV will be highlighted in this paper.

First Comparison of Remote Vertical Profiles of Refractory Black Carbon between the Atlantic and Pacific Basins on Global Scales

NASA Astrophysics Data System (ADS)

Katich, J. M.; Schwarz, J. P.

2016-12-01

The NASA Atmospheric Tomography Mission (ATom) provides a first opportunity to obtain vertical profiles of refractory black carbon (rBC) mass mixing ratios over global scale ( 65S - 85 N latitude) in the remote atmosphere over both the Pacific and Atlantic basins. A NOAA single-particle soot photometer (SP2) will fly on the NASA DC-8 research aircraft over July/August of 2016, obtaining near- continuous vertical profiling ( 0.3 to 12 km) over most of the Earth's latitude range, akin to the NSF HIPPO campaign that occurred only over the Pacific basin during 2009-2011. HIPPO analysis suggested both that high altitude rBC mass mixing ratios (MMRs) were likely zonally well mixed, and that global model estimates of remote rBC MMR throughout the upper troposphere globally, and not just over the Pacific, were likely biased high. Here we will present an initial analysis of the new, more complete data set in which Atlantic rBC profiles will be used to assess these prior suppositions.

Analysis of 1970-1995 Trends in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS-CHEM Model

NASA Technical Reports Server (NTRS)

Fusco, Andrew C.; Logan, Jennifer A.

2004-01-01

I ] The causes of trends in tropospheric ozone at Northern Hemisphere midlatitudes from 1970 to 1995 are investigated with the GEOS-CHEM model, a global three-dimensional model of the troposphere driven by assimilated meteorological observations from the Goddard Earth Observing System (GEOS). This model is used to investigate the sensitivity of tropospheric ozone with respect to (1) changes in the anthropogenic emission of nitrogen oxides and nonmethane hydrocarbons, (2) increases in methane concentrations, (3) variations in the stratospheric source of ozone, (4) changes in solar radiation resulting from stratospheric ozone depletion, and ( 5 ) increases in tropospheric temperatures. Model results indicate that local increases in NO, emissions have caused most of the increases seen in lower tropospheric ozone over Europe and Japan. Increases in methane are responsible for roughly one fifth of the anthropogenically induced increase in tropospheric ozone at northern midlatitudes. However, changes in ozone precursors do not adequately explain either the spatial differences in observed ozone trends across midlatitudes or the observed decreases in ozone over Canada throughout the troposphere. We argue that ozone depletion in the lowermost stratosphere is likely to have reduced the stratospheric source by as much as 30% from the early 1970s to the mid 1990s. Model simulations that account for such a reduction along with reported changes in anthropogenic emissions show steep declines of ozone in the upper troposphere and variable increases in the lower troposphere that are more consistent with observations. Differential temperature trends in summer between North America and Europe may account for at least some of the remaining spatial variation in tropospheric ozone trends. Increases in ultraviolet (UV) radiation due to stratospheric ozone depletion do not appear to significantly reduce tropospheric ozone, except at midlatitudes in the Southern Hemisphere following the

Evaluation of Simulated Photochemical Partitioning of Oxidized Nitrogen in the Upper Troposphere

EPA Science Inventory

Regional and global chemical transport models underpredict NO_x (NO +NO₂) in the upper troposphere where it is a precursor to the greenhouse gas ozone. The NO_x bias has been shown in model evaluations using aircraft data (Singh et al., 2007) and to...

Evaluation of ACCMIP Outgoing Longwave Radiation from Tropospheric Ozone Using TES Satellite Observations.

NASA Technical Reports Server (NTRS)

Bowman, Kevin W.; Shindell, Drew Todd; Worden, H. M.; Lamarque, J. F.; Young, P. J.; Stevenson, D. S.; Qu, Z.; delaTorre, M.; Bergmann, D.; Cameron-Smith, P. J.;

Methane from the Tropospheric Emission Spectrometer (TES)

NASA Technical Reports Server (NTRS)

Payne, Vivienne; Worden, John; Kulawik, Susan; Frankenberg, Christian; Bowman, Kevin; Wecht, Kevin

2012-01-01

TES V5 CH4 captures latitudinal gradients, regional variability and interannual variation in the free troposphere. V5 joint retrievals offer improved sensitivity to lower troposphere. Time series extends from 2004 to present. V5 reprocessing in progress. Upper tropospheric bias. Mitigated by N2O correction. Appears largely spatially uniform, so can be corrected. How to relate free-tropospheric values to surface emissions.

Development of a Climate Record of Tropospheric and Stratospheric Column Ozone from Satellite Remote Sensing: Evidence of an Early Recovery of Global Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Ziemke, Jerald R.; Chandra, Sushil

2012-01-01

Ozone data beginning October 2004 from the Aura Ozone Monitoring Instrument (OMI) and Aura Microwave Limb Sounder (MLS) are used to evaluate the accuracy of the Cloud Slicing technique in effort to develop long data records of tropospheric and stratospheric ozone and for studying their long-term changes. Using this technique, we have produced a 32-yr (1979-2010) long record of tropospheric and stratospheric column ozone from the combined Total Ozone Mapping Spectrometer (TOMS) and OMI. Analyses of these time series suggest that the quasi-biennial oscillation (QBO) is the dominant source of inter-annual variability of stratospheric ozone and is clearest in the Southern Hemisphere during the Aura time record with related inter-annual changes of 30- 40 Dobson Units. Tropospheric ozone for the long record also indicates a QBO signal in the tropics with peak-to-peak changes varying from 2 to 7 DU. The most important result from our study is that global stratospheric ozone indicates signature of a recovery occurring with ozone abundance now approaching the levels of year 1980 and earlier. The negative trends in stratospheric ozone in both hemispheres during the first 15 yr of the record are now positive over the last 15 yr and with nearly equal magnitudes. This turnaround in stratospheric ozone loss is occurring about 20 yr earlier than predicted by many chemistry climate models. This suggests that the Montreal Protocol which was first signed in 1987 as an international agreement to reduce ozone destroying substances is working well and perhaps better than anticipated.

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O and O3

NASA Technical Reports Server (NTRS)

Hintsa, E. J.; Boering, K. A.; Weinstock, E. M.; Anderson, J. G.; Gary, B. L.; Pfister, L.; Daube, B. C.; Wofsy, S. C.; Loewenstein, M.; Podolske, J.R.;

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O and O3

NASA Technical Reports Server (NTRS)

Hintsa, E. J.; Boering, K. A.; Weinstock, E. M.; Anderson, J. G.; Gary, B. L.; Pfister, L.; Daube, B. C.; Wofsy, S. C.; Loewenstein, M.; Podolske, J. R.

1998-01-01

The origin of air in the lowermost stratosphere is investigated with measurements from the NASA ER-2 aircraft. Air with high water vapor mixing ratios was observed in the stratosphere at theta = 330-380 K near 40 N in May 1995, indicating the influence of intrusions of tropospheric air. Assuming that observed tracer-tracer relationships reflect mixing lines between tropospheric and stratospheric air masses, we calculate mixing ratios of H2O (12-24 ppmv) and CO2 for the admixed tropospheric air at theta = 352-364 K. Temperatures on the 355 K surface at 20-40 N were low enough to dehydrate air to these values. While most ER-2 CO2 data in both hemispheres are consistent with tropical or subtropical air entering the lowermost stratosphere, measurements from May 1995 for theta < 362 K suggest that entry of air from the midlatitude upper troposphere can occur in conjunction with mixing processes near the tropopause.

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O, and O3

NASA Technical Reports Server (NTRS)

Hintsa, E. J.; Boering, K. A.; Weinstock, E. M.; Anderson, J. G.; Gary, B. L.; Pfister, L.; Daube, B. C.; Wofsy, S. C.; Loewenstein, M.; Podolske, J. R.;

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O and O3

NASA Technical Reports Server (NTRS)

Hintsa, E. J.; Boering, K. A.; Weinstock, E. M.; Anderson, J. G.; Gary, B. L.; Pfister, L.; Daube, B. C.; Wofsy, S. C.; Loewenstein, M.; Podolske, J. R.;

Global Precipitation Products at NASA GES DISC for Supporting Agriculture Research and Applications

NASA Technical Reports Server (NTRS)

Liu, Zhong; Teng, W.; Ostrenga, D.; Albayrak, R.; Savtchenko, A.; Yang, W.; Vollmer, B.; Meyer, D.

2017-01-01

This presentation describes precipitation products available at the NASA GES DISC that support agricultural research. XXXX Key environmental variables for agriculture: precipitation, temperature, water (soil moisture), solar radiation, NDVI, etc. Rainfed agriculture - major farming practices that rely on rainfall for water. Rainfed agriculture: >95% of farmed land (sub- Saharan Africa); 90% (Latin America); 75% (Near East and North Africa); 65% (East Asia); 60% (South Asia). Precipitation is very important for rainfed agriculture. Droughts can cause severe damage. Precipitation information can be used to monitor the growing season. The Goddard Earth Sciences (GES) Data and Information Services Center (DISC), one of 12 NASA data centers, located in Greenbelt, Maryland, USA. The GES DISC is a major data archive center for global precipitation, water & energy cycles, atmospheric composition, and climate variability Global and regional precipitation datasets (satellite-based and data assimilation Data services (subsetting, format conversion, online visualization, etc.) User services are available FAQs, How to (recipes), Glossary, etc. Social media (Twitter, YouTube, User forum) Help desk (phone, email, online feedback) Training materials (ARSET => Applied Remote Sensing Training) Liu,

Investigation of the Physical Processes Governing Large-scale Tracer Transport in the Stratosphere and Troposphere

NASA Technical Reports Server (NTRS)

Selkirk, Henry B.

1996-01-01

This report reviews the second year of a three-year research program to investigate the physical mechanisms which underlie the transport of trace constituents in the stratosphere- troposphere system. The primary scientific goal of the research is to identify the processes which transport air masses within the lower stratosphere, particularly between the tropics and middle latitudes. The SASS program seeks to understand the impact of the present and future fleets of conventional jet traffic on the upper troposphere and lower stratosphere, while complementary airborne observations under UARP seek to understand the complex interactions of dynamical and chemical processes that affect the ozone layer. The present investigation contributes to the goals of each of these by diagnosing the history of air parcels intercepted by NASA research aircraft in UARP and AEAP campaigns.

Twenty Five Years of Airborne Observations of Ozone-Depleting and Climate-Related Gases in the Upper Troposphere and Lower Stratosphere.

NASA Astrophysics Data System (ADS)

Elkins, J. W.; Moore, F. L.; Hintsa, E. J.; Dutton, G. S.; Nance, J. D.; Hall, B. D.

2016-12-01

NOAA scientists started in situ airborne measurements of two strong ozone-depleting gases or chlorofluorocarbons, CFC-11 and CFC-113 in 1991 on the NASA ER-2 aircraft with a two-channel gas chromatograph, Airborne Chromatograph for Atmospheric Trace Species (ACATS). We broaden our list of gases to include more ozone-depleting and other climate-related gases. An improved 4-channel gas chromatograph that included N2O, SF6, CFC-11, -12, -113, halon-1211, CCl4, CH3CCl3, CH4, CO, and H2 was added to the ER-2 aircraft in 1994. As CFC replacements took hold, we add a gas chromatograph-mass spectrometer system, PAN and other Trace Hydro-halocarbon Experiment (PANTHER), to examine shorter-lived gases mainly in the upper troposphere. These airborne measurements were to complement of ground-based flask and in situ measurements from the NOAA Halocarbon and other Trace Species Network. This talk will show results from a tropical study, Airborne Tropical Tropopause Experiment (ATTREX) on the NASA Global Hawk aircraft and preliminary results from the Atmospheric Tomography Mission (ATom) conducted in August 2016 on the NASA DC-8 aircraft. A detrended, gridded, latitudinal distribution of SF6 is shown in the figure below for the years of 1994 through 2014. Such a plot may be useful to atmospheric modelers trying to capture transport or calculate emissions.

NASA Earth Day 2014

NASA Image and Video Library

2014-04-22

NASA Astronaut John Mace Grunsfeld takes a quick selfie with astronauts at the International Space Station at the NASA sponsored Earth Day event April 22, 2014 at Union Station in Washington, DC. NASA announced the "Global Selfie" event as part of its "Earth Right Now" campaign, celebrating the launch of five Earth-observing missions in 2014. All selfies posted to social media with the hashtag "GlobalSelfie" will be included in a mosaic image of Earth. Photo Credit: (NASA/Aubrey Gemignani)