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Sample records for nitrogen ion recoil

  1. Recoil separator ERNA: ion beam specifications

    NASA Astrophysics Data System (ADS)

    Rogalla, D.; Aliotta, M.; Barnes, C. A.; Campajola, L.; D'Onofrio, A.; Fritz, E.; Gialanella, L.; Greife, U.; Imbriani, G.; Ordine, A.; Ossmann, J.; Roca, V.; Rolfs, C.; Romano, M.; Sabbarese, C.; Schürmann, D.; Schümann, F.; Strieder, F.; Theis, S.; Terrasi, F.; Trautvetter, H. P.

    For improved measurements of the key astrophysical reaction 12C(α,γ)16O in inverted kinematics, a recoil separator ERNA is being developed at the 4 MV Dynamitron tandem accelerator in Bochum to detect directly the 16O recoils with about 50% efficiency. Calculations of the ion beam optics including all filtering and focusing elements of ERNA are presented. Since the 12C projectiles and the 16O recoils have essentially the same momentum, and since the 12C ion beam emerging from the accelerator passes through a momentum filter (analysing magnet), the 12C ion beam must be as free as possible from 16O contamination for ERNA to succeed. In the present work, the 16O contamination was reduced from a level of 1 × 10-11 to a level below 2 × 10-29 by the installation of Wien filters both before and after the analysing magnet. The measurement of these and other beam specifications involved other parts of the final ERNA layout - sequentially a Wien filter, a 60˚ dipole magnet, another Wien filter, and a ΔE-E telescope. The setup led to a measured suppression factor of 5 × 10-18 for the 12C ion beam. The experiments also indicate that an almost free choice of the charge state for the 16O recoils is possible in the separator.

  2. Time-of-flight direct recoil ion scattering spectrometer

    DOEpatents

    Krauss, A.R.; Gruen, D.M.; Lamich, G.J.

    1994-09-13

    A time-of-flight direct recoil and ion scattering spectrometer beam line is disclosed. The beam line includes an ion source which injects ions into pulse deflection regions and separated by a drift space. A final optics stage includes an ion lens and deflection plate assembly. The ion pulse length and pulse interval are determined by computerized adjustment of the timing between the voltage pulses applied to the pulsed deflection regions. 23 figs.

  3. Time-of-flight direct recoil ion scattering spectrometer

    DOEpatents

    Krauss, Alan R.; Gruen, Dieter M.; Lamich, George J.

    1994-01-01

    A time of flight direct recoil and ion scattering spectrometer beam line (10). The beam line (10) includes an ion source (12) which injects ions into pulse deflection regions (14) and (16) separated by a drift space (18). A final optics stage includes an ion lens and deflection plate assembly (22). The ion pulse length and pulse interval are determined by computerized adjustment of the timing between the voltage pulses applied to the pulsed deflection regions (14) and (16).

  4. Recoil ion charge state distribution following the beta(sup +) decay of {sup 21}Na

    SciTech Connect

    Scielzo, Nicholas D.; Freedman, Stuart J.; Fujikawa, Brian K.; Vetter, Paul A.

    2003-01-03

    The charge state distribution following the positron decay of 21Na has been measured, with a larger than expected fraction of the daughter 21Ne in positive charge states. No dependence on either the positron or recoil nucleus energy is observed. The data is compared to a simple model based on the sudden approximation. Calculations suggest a small but important contribution from recoil ionization has important consequences for precision beta decay correlation experiments detecting recoil ions.

  5. Production of soft X-ray emitting slow multiply charged ions - Recoil ion spectroscopy

    NASA Technical Reports Server (NTRS)

    Sellin, I. A.; Elston, S. B.; Forester, J. P.; Griffin, P. M.; Pegg, D. J.; Peterson, R. S.; Thoe, R. S.; Vane, C. R.; Wright, J. J.; Groeneveld, K.-O.

    1977-01-01

    S ions with a mean charge state of about 14+ and Cl ions with a mean charge state of 12+ were used to study Ne L-shell vacancy production. The ions caused copious production of NeII-NeVIII excited states with approximately 10 to the minus 18 sq cm cross sections. The induced recoil velocities might have application to a significantly higher resolution spectroscopy than is possible with beam-foil methods.

  6. Heavy ion elastic recoil detection analysis set up for electronic sputtering studies

    NASA Astrophysics Data System (ADS)

    Ghosh, S.; Avasthi, D. K.; Tripathi, A.; Kabiraj, D.; Sugathan, P.; Chaudhary, G. K.; Barua, P.

    2006-04-01

    Heavy ion elastic recoil detection analysis (ERDA) set up with a large solid angle (greater than or similar to 4.8 msr) Delta E - E position-sensitive telescope detector is developed at Inter University Accelerator Centre as a dedicated facility for the study of electronic sputtering of thin films under swift heavy ion (SHI) irradiation. The detector consists of a gas ionization chamber (Delta E ) and a solid-state surface barrier detector ( E ) housed in a same assembly. The electronic sputtering yield (atoms/ion) is determined by analyzing on-line fluence-dependent ERDA data obtained from a variety of thin films. Large erosion (> 10 5 atoms/ion) of carbon from a-C:H by 150 MeV Ag 13+ ions, evolution of nitrogen (greater than or similar to 880 atoms/ion) from copper nitride and depletion of oxygen (greater than or similar to 1000 atoms/ion) from copper oxide film under 200 MeV Au 15+ ion impact are studied and reported in this work. The electronic sputtering of these materials is discussed on the basis of the thermal spike model of SHI and solid interaction.

  7. Complex decay patterns in atomic core photoionization disentangled by ion-recoil measurements

    SciTech Connect

    Guillemin, Renaud; Bomme, Cedric; Marin, Thierry; Journel, Loic; Marchenko, Tatiana; Kushawaha, Rajesh K.; Piancastelli, Maria Novella; Simon, Marc; Trcera, Nicolas

    2011-12-15

    Following core 1s ionization and resonant excitation of argon atoms, we measure the recoil energy of the ions due to momentum conservation during the emission of Auger electrons. We show that such ion momentum spectroscopy can be used to disentangle to some degree complex decay patterns, involving both radiative and nonradiative decays.

  8. A recoil ion momentum spectrometer for molecular and atomic fragmentation studies.

    PubMed

    Khan, Arnab; Tribedi, Lokesh C; Misra, Deepankar

    2015-04-01

    We report the development and performance studies of a newly built recoil ion momentum spectrometer for the study of atomic and molecular fragmentation dynamics in gas phase upon the impact of charged particles and photons. The present design is a two-stage Wiley-McLaren type spectrometer which satisfies both time and velocity focusing conditions and is capable of measuring singly charged ionic fragments up-to 13 eV in all directions. An electrostatic lens has been introduced in order to achieve velocity imaging. Effects of the lens on time-of-flight as well as on the position have been investigated in detail, both, by simulation and in experiment. We have used 120 keV proton beam on molecular nitrogen gas target. Complete momentum distributions and kinetic energy release distributions have been derived from the measured position and time-of-flight spectra. Along with this, the kinetic energy release spectra of fragmentation of doubly ionized nitrogen molecule upon various projectile impacts are presented.

  9. A recoil ion momentum spectrometer for molecular and atomic fragmentation studies

    SciTech Connect

    Khan, Arnab; Tribedi, Lokesh C.; Misra, Deepankar

    2015-04-15

    We report the development and performance studies of a newly built recoil ion momentum spectrometer for the study of atomic and molecular fragmentation dynamics in gas phase upon the impact of charged particles and photons. The present design is a two-stage Wiley-McLaren type spectrometer which satisfies both time and velocity focusing conditions and is capable of measuring singly charged ionic fragments up-to 13 eV in all directions. An electrostatic lens has been introduced in order to achieve velocity imaging. Effects of the lens on time-of-flight as well as on the position have been investigated in detail, both, by simulation and in experiment. We have used 120 keV proton beam on molecular nitrogen gas target. Complete momentum distributions and kinetic energy release distributions have been derived from the measured position and time-of-flight spectra. Along with this, the kinetic energy release spectra of fragmentation of doubly ionized nitrogen molecule upon various projectile impacts are presented.

  10. What Can We Learn From Proton Recoils about Heavy-Ion SEE Sensitivity?

    NASA Technical Reports Server (NTRS)

    Ladbury, Raymond L.

    2016-01-01

    The fact that protons cause single-event effects (SEE) in most devices through production of light-ion recoils has led to attempts to bound heavy-ion SEE susceptibility through use of proton data. Although this may be a viable strategy for some devices and technologies, the data must be analyzed carefully and conservatively to avoid over-optimistic estimates of SEE performance. We examine the constraints that proton test data can impose on heavy-ion SEE susceptibility.

  11. A combined segmented anode gas ionization chamber and time-of-flight detector for heavy ion elastic recoil detection analysis

    NASA Astrophysics Data System (ADS)

    Ström, Petter; Petersson, Per; Rubel, Marek; Possnert, Göran

    2016-10-01

    A dedicated detector system for heavy ion elastic recoil detection analysis at the Tandem Laboratory of Uppsala University is presented. Benefits of combining a time-of-flight measurement with a segmented anode gas ionization chamber are demonstrated. The capability of ion species identification is improved with the present system, compared to that obtained when using a single solid state silicon detector for the full ion energy signal. The system enables separation of light elements, up to Neon, based on atomic number while signals from heavy elements such as molybdenum and tungsten are separated based on mass, to a sample depth on the order of 1 μm. The performance of the system is discussed and a selection of material analysis applications is given. Plasma-facing materials from fusion experiments, in particular metal mirrors, are used as a main example for the discussion. Marker experiments using nitrogen-15 or oxygen-18 are specific cases for which the described improved species separation and sensitivity are required. Resilience to radiation damage and significantly improved energy resolution for heavy elements at low energies are additional benefits of the gas ionization chamber over a solid state detector based system.

  12. Angular anisotropy parameters and recoil-ion momentum distribution in two-photon double ionization of helium

    SciTech Connect

    Kheifets, A. S.; Ivanov, I. A.; Bray, Igor

    2007-08-15

    We present convergent-close-coupling (CCC) calculations of the angular anisotropy parameters {beta}{sub 2},{beta}{sub 4} and the recoil ion momentum distribution d{sigma}/dp in two-photon double ionization (TPDI) of helium. In a stark contrast to single-photon double ionization (SPDI), where the {beta}{sub 2} parameter varies widely changing the angular distribution from isotropic to nearly dipole for slow and fast photoelectrons, respectively, the {beta} parameters for TPDI show very little change. The angular distribution of the recoil ion is fairly isotropic in TPDI as opposed to a strong alignment with the polarization of light in SPDI.

  13. New recoil transfer chamber for thermalization of heavy ions produced in fusion-evaporation reactions

    NASA Astrophysics Data System (ADS)

    Alfonso, M. C.; Tereshatov, E. E.; DeVanzo, M. J.; Sefcik, J. A.; Bennett, M. E.; Mayorov, D. A.; Werke, T. A.; Folden, C. M.

    2015-10-01

    A new Recoil Transfer Chamber (RTC) has been designed, fabricated, and characterized at the Cyclotron Institute at Texas A&M University. The design is based on a gas stopper that was previously in routine use at the National Superconducting Cyclotron Laboratory. This new RTC uses He gas to stop ions, and a combination of a static electric field and gas flow to maximize the extraction efficiency. In offline experiments, a 228Th source was used to produce 216Po which was successfully extracted even though it has a short half-life. In online experiments using the products of the 118Sn(40Ar, 6n)152Er reaction, an efficiency of several tens of percent was measured.

  14. First high-statistics and high-resolution recoil-ion data from the WITCH retardation spectrometer

    NASA Astrophysics Data System (ADS)

    Finlay, P.; Breitenfeldt, M.; Porobić, T.; Wursten, E.; Ban, G.; Beck, M.; Couratin, C.; Fabian, X.; Fléchard, X.; Friedag, P.; Glück, F.; Herlert, A.; Knecht, A.; Kozlov, V. Y.; Liénard, E.; Soti, G.; Tandecki, M.; Traykov, E.; Van Gorp, S.; Weinheimer, Ch.; Zákoucký, D.; Severijns, N.

    2016-07-01

    The first high-statistics and high-resolution data set for the integrated recoil-ion energy spectrum following the β^+ decay of 35Ar has been collected with the WITCH retardation spectrometer located at CERN-ISOLDE. Over 25 million recoil-ion events were recorded on a large-area multichannel plate (MCP) detector with a time-stamp precision of 2ns and position resolution of 0.1mm due to the newly upgraded data acquisition based on the LPC Caen FASTER protocol. The number of recoil ions was measured for more than 15 different settings of the retardation potential, complemented by dedicated background and half-life measurements. Previously unidentified systematic effects, including an energy-dependent efficiency of the main MCP and a radiation-induced time-dependent background, have been identified and incorporated into the analysis. However, further understanding and treatment of the radiation-induced background requires additional dedicated measurements and remains the current limiting factor in extracting a beta-neutrino angular correlation coefficient for 35Ar decay using the WITCH spectrometer.

  15. Nuclear recoil corrections to the Lamb shift of hydrogen and light hydrogenlike ions

    NASA Astrophysics Data System (ADS)

    Yerokhin, V. A.; Shabaev, V. M.

    2016-06-01

    Accurate calculations of the nuclear recoil effect on the Lamb shift of hydrogenlike atoms are presented. Numerical results are reported for the n s states with n ≤5 and for the 2 p1 /2 and 2 p3 /2 states. The calculations are performed to the first order in the electron-nucleus mass ratio and to all orders in the nuclear binding strength parameter Z α (where Z is the nuclear charge number and α is the fine structure constant). The obtained results provide accurate predictions for the higher-order remainder beyond the known Z α -expansion terms. In the case of hydrogen, the remainder was found to be much larger than anticipated. This result resolves the previously reported disagreement between the numerical all-order and the analytical Z α -expansion approaches for the nuclear recoil effect on the hydrogen Lamb shift.

  16. The negative ions emission in nitrogen

    NASA Technical Reports Server (NTRS)

    Soon, W. H.; Kunc, J. A.

    1991-01-01

    The contribution of negative atomic ions to continuum radiation in nitrogen plasma is discussed. It is shown that both unstable N(-)(3P) and metastable N(-)(1D) ions have a significant effect on the total production of the continuum radiation at electron temperatures below 12,000 K.

  17. Elastic recoil detection

    NASA Astrophysics Data System (ADS)

    Bik, W. M. A.; Habraken, F. H. P. M.

    1993-07-01

    In elastic recoil detection (ERD) one determines the yield and energy of particles ejected out of the surface region of samples under MeV ion bombardment. By application of this surface and thin film analysis technique one can obtain quantitative information concerning the depth distribution of light elements in a sample to be analysed. The quantitativity and the depth resolving power are based on knowledge of the recoil cross section and the stopping power of high-energy ions in matter. This paper reviews the fundamentals of this technique and the various experimental methods for recoil identification. Furthermore, important features for material analysis, such as detection limits, depth resolution and elemental range are discussed. Some emphasis is put on the conversion of the spectral contribution of the elements to atomic concentrations in the films for several representative cases. Throughout the review numerous examples are given to illustrate the features of ERD and to demonstrate empirically the accuracy of the quantification method.

  18. Nitrogen incorporation in carbon nitride films produced by direct and dual ion-beam sputtering

    SciTech Connect

    Abrasonis, G.; Gago, R.; Jimenez, I.; Kreissig, U.; Kolitsch, A.; Moeller, W.

    2005-10-01

    Carbon (C) and carbon nitride (CN{sub x}) films were grown on Si(100) substrates by direct ion-beam sputtering (IBS) of a carbon target at different substrate temperatures (room temperature-450 deg. C) and Ar/N{sub 2} sputtering gas mixtures. Additionally, the effect of concurrent nitrogen-ion assistance during the growth of CN{sub x} films by IBS was also investigated. The samples were analyzed by elastic recoil detection analysis (ERDA) and x-ray absorption near-edge spectroscopy (XANES). The ERDA results showed that significant nitrogen amount (up to 20 at. %) was incorporated in the films, without any other nitrogen source but the N{sub 2}-containing sputtering gas. The nitrogen concentration is proportional to the N{sub 2} content in the sputtering beam and no saturation limit is reached under the present working conditions. The film areal density derived from ERDA revealed a decrease in the amount of deposited material at increasing growth temperature, with a correlation between the C and N losses. The XANES results indicate that N atoms are efficiently incorporated into the carbon network and can be found in different bonding environments, such as pyridinelike, nitrilelike, graphitelike, and embedded N{sub 2} molecules. The contribution of molecular and pyridinelike nitrogen decreases when the temperature increases while the contribution of the nitrilelike nitrogen increases. The concurrent nitrogen ion assistance resulted in the significant increase of the nitrogen content in the film but it induced a further reduction of the deposited material. Additionally, the assisting ions inhibited the formation of the nitrilelike configurations while promoting nitrogen environments in graphitelike positions. The nitrogen incorporation and release mechanisms are discussed in terms of film growth precursors, ion bombardment effects, and chemical sputtering.

  19. Potku - New analysis software for heavy ion elastic recoil detection analysis

    NASA Astrophysics Data System (ADS)

    Arstila, K.; Julin, J.; Laitinen, M. I.; Aalto, J.; Konu, T.; Kärkkäinen, S.; Rahkonen, S.; Raunio, M.; Itkonen, J.; Santanen, J.-P.; Tuovinen, T.; Sajavaara, T.

    2014-07-01

    Time-of-flight elastic recoil detection (ToF-ERD) analysis software has been developed. The software combines a Python-language graphical front-end with a C code computing back-end in a user-friendly way. The software uses a list of coincident time-of-flight-energy (ToF-E) events as an input. The ToF calibration can be determined with a simple graphical procedure. The graphical interface allows the user to select different elements and isotopes from a ToF-E histogram and to convert the selections to individual elemental energy and depth profiles. The resulting sample composition can be presented as relative or absolute concentrations by integrating the depth profiles over user-defined ranges. Beam induced composition changes can be studied by displaying the event-based data in fractions relative to the substrate reference data. Optional angular input data allows for kinematic correction of the depth profiles. This open source software is distributed under the GPL license for Linux, Mac, and Windows environments.

  20. Electron and recoil ion momentum imaging with a magneto-optically trapped target

    SciTech Connect

    Hubele, R.; Schuricke, M.; Goullon, J.; Lindenblatt, H.; Ferreira, N.; Laforge, A.; Brühl, E.; Globig, D.; Misra, D.; Sell, M.; Song, Z.; Wang, X.; Zhang, S.; Jesus, V. L. B. de; Kelkar, A.; Schneider, K.; Schulz, M.; Fischer, D.

    2015-03-15

    A reaction microscope (ReMi) has been combined with a magneto-optical trap (MOT) for the kinematically complete investigation of atomic break-up processes. With the novel MOTReMi apparatus, the momentum vectors of the fragments of laser-cooled and state-prepared lithium atoms are measured in coincidence and over the full solid angle. The first successful implementation of a MOTReMi could be realized due to an optimized design of the present setup, a nonstandard operation of the MOT, and by employing a switching cycle with alternating measuring and trapping periods. The very low target temperature in the MOT (∼2 mK) allows for an excellent momentum resolution. Optical preparation of the target atoms in the excited Li 2{sup 2}P{sub 3/2} state was demonstrated providing an atomic polarization of close to 100%. While first experimental results were reported earlier, in this work, we focus on the technical description of the setup and its performance in commissioning experiments involving target ionization in 266 nm laser pulses and in collisions with projectile ions.

  1. Calculation of recoil implantation profiles using known range statistics

    NASA Technical Reports Server (NTRS)

    Fung, C. D.; Avila, R. E.

    1985-01-01

    A method has been developed to calculate the depth distribution of recoil atoms that result from ion implantation onto a substrate covered with a thin surface layer. The calculation includes first order recoils considering projected range straggles, and lateral straggles of recoils but neglecting lateral straggles of projectiles. Projectile range distributions at intermediate energies in the surface layer are deduced from look-up tables of known range statistics. A great saving of computing time and human effort is thus attained in comparison with existing procedures. The method is used to calculate recoil profiles of oxygen from implantation of arsenic through SiO2 and of nitrogen from implantation of phosphorus through Si3N4 films on silicon. The calculated recoil profiles are in good agreement with results obtained by other investigators using the Boltzmann transport equation and they also compare very well with available experimental results in the literature. The deviation between calculated and experimental results is discussed in relation to lateral straggles. From this discussion, a range of surface layer thickness for which the method applies is recommended.

  2. A Double Scattering Analytical Model For Elastic Recoil Detection Analysis

    SciTech Connect

    Barradas, N. P.; Lorenz, K.; Alves, E.; Darakchieva, V.

    2011-06-01

    We present an analytical model for calculation of double scattering in elastic recoil detection measurements. Only events involving the beam particle and the recoil are considered, i.e. 1) an ion scatters off a target element and then produces a recoil, and 2) an ion produces a recoil which then scatters off a target element. Events involving intermediate recoils are not considered, i.e. when the primary ion produces a recoil which then produces a second recoil. If the recoil element is also present in the stopping foil, recoil events in the stopping foil are also calculated. We included the model in the standard code for IBA data analysis NDF, and applied it to the measurement of hydrogen in Si.

  3. A recoil separator for nuclear astrophysics SECAR

    NASA Astrophysics Data System (ADS)

    Berg, G. P. A.; Bardayan, D. W.; Blackmon, J. C.; Chipps, K. A.; Couder, M.; Greife, U.; Hager, U.; Montes, F.; Rehm, K. E.; Schatz, H.; Smith, M. S.; Wiescher, M.; Wrede, C.; Zeller, A.

    2016-06-01

    A recoil separator SECAR has been designed to study radiative capture reactions relevant for the astrophysical rp-process in inverse kinematics for the Facility for Rare Isotope Beams (FRIB). We describe the design, layout, and ion optics of the recoil separator and present the status of the project.

  4. Determination of concentration profiles by elastic recoil detection with a ΔE-E gas telescope and high energy incident heavy ions

    NASA Astrophysics Data System (ADS)

    Stoquert, J. P.; Guillaume, G.; Hage-Ali, M.; Grob, J. J.; Ganter, C.; Siffert, P.

    1989-12-01

    The Elastic Recoil Detection (ERD) method has been used to determine the profile of a wide range of elements simultaneously in a thin layer (1μm) with a depth resolution of a few hundred Å and high sensitivity. Z separation is achieved by a ΔE(gas)-E(solid) telescope. Results for 127I (up to 240 MeV) incident ions used to profile thin films of dielectrics (SiOxNyHz), amorphous semiconductors (a-GaAs: H) and superconductors (YBaCuO, BiSrCaCuO) are reported. It has been considered previously that ERD is of interest for analysis of light elements. We show that high energy heavy incident ions extend the field of application of the ERD method to all elements with an approximately constant depth resolution and sensitivity.

  5. Recoil Separators for Nuclear Astrophysics

    NASA Astrophysics Data System (ADS)

    Blackmon, J. C.

    2004-10-01

    Hydrogen and helium capture reactions are important in many astrophysical environments. Measurements in inverse kinematics using recoil separators have demonstrated a particularly sensitive technique for studying low-yield capture reactions.(M. S. Smith, C. E. Rolfs, and C. A. Barnes, Nucl. Instrum. Meth. Phys. Res. A306) (1991) 233. This approach allows a low background rate to be achieved with a high detection efficiency (about 50%) for the particles of interest using a device with only modest acceptance. Recoil separators using a variety of ion-optic configurations have been installed at numerous accelerator facilities in the past decade and have been used to measure, for example, alpha capture reactions using stable beams(D. Rogalla et al.), Eur. Phys. J. 6 (1999) 471. and proton capture reactions using radioactive ion beams.(S. Bishop et al.), Phys. Rev. Lett. 90 (2003) 162501. Measurements in inverse kinematics are the only viable means for studying reactions on short-lived nuclei that are crucial for understanding stellar explosions, and a recoil separator optimized for the measurement of capture reactions with radioactive ion beams figures prominently into the design of the low energy experimental area at the Rare Isotope Accelerator (RIA). The operational requirements for such a device will be outlined, and recoil separator designs and characteristics will be presented.

  6. Electron-ion recombination in nuclear recoils tracks in nonpolar liquids. Calculation of the effect of external electric field on the escape probability

    NASA Astrophysics Data System (ADS)

    Mateja, Piotr; Wojcik, Mariusz

    2016-07-01

    A computer simulation method is applied to study electron-ion recombination in tracks of low-energy nuclear recoils in nonpolar liquids in which the electron transport can be described as ideal diffusion. The electron escape probability is calculated as a function of applied electric field, both for the field parallel to the track and for the field perpendicular to the track. The dependence of escape probability on the field direction is the stronger, the longer the ionization track, with a significant effect being found already for tracks of ~100 nm length. The results are discussed in the context of possible applications of nonpolar molecular liquids as target media in directional dark matter detectors.

  7. Reactions of recoil nitrogen-13 atoms in the ethanol-water system. Formation of [{sup 13}N]NH{sub 3} upon irradiation of water and dilute aqueous solutions of ethanol under a pressure of various gases

    SciTech Connect

    Korsakov, M.V.; Krasikova, R.N.; Fedorova, O.S.

    1995-07-01

    The influence of the nature and pressure of a gas (helium, hydrogen) contacting with a solution on radiochemical yield of the {sup 13}N-labeled products of nuclear-chemical and radiolytic reactions occurring upon irradiation of water and dilute aqueous solution of ethanol by 17-MeV protons was examined. It was shown that irradiation of water under hydrogen pressure, about 50% of recoil nitrogen-13 atoms are stabilized in the gas phase in the form of [{sup 13}N]N{sub 2}, and the main product in the liquid phase is ammonia-{sup 13}N.

  8. Elastic properties of sub-stoichiometric nitrogen ion implanted silicon

    NASA Astrophysics Data System (ADS)

    Sarmanova, M. F.; Karl, H.; Mändl, S.; Hirsch, D.; Mayr, S. G.; Rauschenbach, B.

    2015-04-01

    Elastic properties of sub-stoichiometric nitrogen implanted silicon were measured with nanometer-resolution using contact resonance atomic force microscopy (CR-AFM) as function of ion fluence and post-annealing conditions. The determined range of indentation moduli was between 100 and 180 GPa depending on the annealing duration and nitrogen content. The high indentation moduli can be explained by formation of Si-N bonds, as verified by X-ray photoelectron spectroscopy.

  9. Pitting behavior of aluminum ion implanted with nitrogen

    SciTech Connect

    McCafferty, E.; Natishan, P.M.; Hubler, G.K.

    1997-07-01

    Ion implantation of {approx} 2 at% N into aluminum increased the pitting potential in 0.1 M sodium chloride by an average of 0.35 V. Surface analysis by x-ray photoelectron spectroscopy showed implanted nitrogen was present as several species: NH{sub 4}{sup +}, NO or NH{sub 3} (as a ligand), AIN, and weakly bound or interstitial nitrogen. With anodic polarization, there was an increase in the total amount of nitrogen in the near-surface region, a decrease in the relative amount of nitride, and an increase in the relative amount of NO or NH{sub 3}. These changes resulted from migration of implanted nitrogen from the substrate into the near-surface region with partial conversion of the AIN species to NO or NH{sub 3}. It was suggested that the effect of implanted nitrogen on pitting behavior of aluminum is similar to that in nitrogen-containing stainless steels, where nitrogen at the metal surface inhibits the dissolution kinetics or aids the repassivation process in the pit by forming NH{sub 4}{sup +} ions that buffer the pit electrolyte.

  10. Surface microanalytical studies of nitrogen ion-implanted steel

    NASA Astrophysics Data System (ADS)

    Dodd, Charles G.; Meeker, G. P.; Baumann, Scott M.; Norberg, James C.; Legg, Keith O.

    1985-03-01

    Five types of industrial steels, 1018, 52100, M-2, 440C, and 304 were ion implanted with nitrogen and subjected to surface microanalysis by three independent surface techniques: AES, RBS, and SIMS. The results provided understanding for earlier observations of the properties of various types of steel after nitrogen implantation. The steels that retained the most nitrogen and that have been reported to benefit the most in improved tribological properties from ion implantation were ferritic carbon and austenitic stainless steels, such as soft 1018 and 304, respectively. Heat-treated martensitic carbon steels such as 52100 and M-2 tool steel were found to retain the least nitrogen, and they have been reported to benefit less from nitrogen implantation; however, the interaction of transition metal carbides in M-2 with nitrogen has not been clarified. The data showed that 440C steel retained as much nitrogen as 1018 and 304, but treatment benefits may be limited to improvements in properties related to toughness and impact resistance.

  11. L-shell ionization of gold by nitrogen ion impact

    SciTech Connect

    Palinkas, J.; Bauer, C.; Brankoff, K.; Grambole, D.; Kalman, Gy.; Sarkadi, L.; Schlenk, B.; Torok, I.

    1983-04-01

    Measuring the angular distributions and the absolute intensities of the L x-ray lines of gold at 2.4-18.2 MeV nitrogen ion impact, the absolute subshell ionization cross-sections and the alignment parameter of the L/sub 3/-subshell have been determined and compared to the theoretical results.

  12. Characterization of nitrogen species incorporated into graphite using low energy nitrogen ion sputtering.

    PubMed

    Kiuchi, Hisao; Kondo, Takahiro; Sakurai, Masataka; Guo, Donghui; Nakamura, Junji; Niwa, Hideharu; Miyawaki, Jun; Kawai, Maki; Oshima, Masaharu; Harada, Yoshihisa

    2016-01-01

    The electronic structures of nitrogen species incorporated into highly oriented pyrolytic graphite (HOPG), prepared by low energy (200 eV) nitrogen ion sputtering and subsequent annealing at 1000 K, were investigated by X-ray photoelectron spectroscopy (XPS), angle-dependent X-ray absorption spectroscopy (XAS), and Raman spectroscopy. An additional peak was observed at higher binding energy of 401.9 eV than 400.9 eV for graphitic1 N (graphitic N in the basal plane) in N 1s XPS, where graphitic2 N (graphitic N in the zigzag edge and/or vacancy sites) has been theoretically expected to appear. N 1s XPS showed that graphitic1 N and graphitic2 N were preferably incorporated under low nitrogen content doping conditions (8 × 10(13) ions cm(-2)), while pyridinic N and graphitic1 N were dominantly observed under high nitrogen content doping conditions. In addition, angle-dependent N 1s XAS showed that the graphitic N and pyridinic N atoms were incorporated into the basal plane of HOPG and thus were highly oriented. Furthermore, Raman spectroscopy revealed that low energy sputtering resulted in almost no fraction of the disturbed graphite surface layers under the lowest nitrogen doping condition. The suitable nitrogen doping condition was discovered for realizing the well-controlled nitrogen doped HOPG. The electrochemical properties for the oxygen reduction reaction of these samples in acidic solution were examined and discussed.

  13. FeN foils by nitrogen ion-implantation

    SciTech Connect

    Jiang, Yanfeng; Wang, Jian-Ping; Al Mehedi, Md; Fu, Engang; Wang, Yongqiang

    2014-05-07

    Iron nitride samples in foil shape (free standing, 500 nm in thickness) were prepared by a nitrogen ion-implantation method. To facilitate phase transformation, the samples were bonded on the substrate followed by a post-annealing step. By using two different substrates, single crystal Si and GaAs, structural and magnetic properties of iron nitride foil samples prepared with different nitrogen ion fluences were characterized. α″-Fe{sub 16}N{sub 2} phase in iron nitride foil samples was obtained and confirmed by the proposed approach. A hard magnetic property with coercivity up to 780 Oe was achieved for the FeN foil samples bonded on Si substrate. The feasibility of using nitrogen ion implantation techniques to prepare FeN foil samples up to 500 nm thickness with a stable martensitic phase under high ion fluences has been demonstrated. A possible mechanism was proposed to explain this result. This proposed method could potentially be an alternative route to prepare rare-earth-free FeN bulk magnets by stacking and pressing multiple free-standing thick α″-Fe{sub 16}N{sub 2} foils together.

  14. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements.

    PubMed

    Sigaud, L; de Jesus, V L B; Ferreira, Natalia; Montenegro, E C

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell-to study ionization of atoms and molecules by electron impact-is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed. PMID:27587105

  15. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements.

    PubMed

    Sigaud, L; de Jesus, V L B; Ferreira, Natalia; Montenegro, E C

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell-to study ionization of atoms and molecules by electron impact-is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed.

  16. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements

    NASA Astrophysics Data System (ADS)

    Sigaud, L.; de Jesus, V. L. B.; Ferreira, Natalia; Montenegro, E. C.

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell—to study ionization of atoms and molecules by electron impact—is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed.

  17. Protein Nitrogen Determination by Kjeldahl Digestion and Ion Chromatography.

    PubMed

    Wang, Hsiaoling; Pampati, Nagarani; McCormick, William M; Bhattacharyya, Lokesh

    2016-06-01

    We report development and validation of a simple, rapid, and accurate method for the quantitation of protein nitrogen, which combines Kjeldahl digestion and ion chromatography with suppressed conductivity detection and requires nanomolar amount of nitrogen in samples (≥10 μg protein). The mechanism of suppressed conductivity detection does not permit analysis of samples containing copper (present in Kjeldahl digestion solution) and aluminum (present in many vaccines as adjuvants) due to precipitation of their hydroxides within the suppressor. We overcame this problem by including 10 μM oxalic acid in Kjeldahl digests and in the eluent (30 mM methanesulfonic acid). The chromatography is performed using an IonPac CS-16 cation exchange column by isocratic elution. The method reduces the digestion time to less than 1 h and eliminates the distillation and titration steps of the Kjeldahl method, thereby reducing the analysis time significantly and improving precision and accuracy. To determine protein nitrogen in samples containing non-protein nitrogen, proteins are precipitated by a mixture of deoxycholate and trichloroacetic acid and the precipitates are analyzed after dissolving in KOH. The method is particularly useful for biological samples that are limited and can also be applied to food, environmental, and other materials.

  18. Protein Nitrogen Determination by Kjeldahl Digestion and Ion Chromatography.

    PubMed

    Wang, Hsiaoling; Pampati, Nagarani; McCormick, William M; Bhattacharyya, Lokesh

    2016-06-01

    We report development and validation of a simple, rapid, and accurate method for the quantitation of protein nitrogen, which combines Kjeldahl digestion and ion chromatography with suppressed conductivity detection and requires nanomolar amount of nitrogen in samples (≥10 μg protein). The mechanism of suppressed conductivity detection does not permit analysis of samples containing copper (present in Kjeldahl digestion solution) and aluminum (present in many vaccines as adjuvants) due to precipitation of their hydroxides within the suppressor. We overcame this problem by including 10 μM oxalic acid in Kjeldahl digests and in the eluent (30 mM methanesulfonic acid). The chromatography is performed using an IonPac CS-16 cation exchange column by isocratic elution. The method reduces the digestion time to less than 1 h and eliminates the distillation and titration steps of the Kjeldahl method, thereby reducing the analysis time significantly and improving precision and accuracy. To determine protein nitrogen in samples containing non-protein nitrogen, proteins are precipitated by a mixture of deoxycholate and trichloroacetic acid and the precipitates are analyzed after dissolving in KOH. The method is particularly useful for biological samples that are limited and can also be applied to food, environmental, and other materials. PMID:27238484

  19. A new value for the half-life of 10Be by Heavy-Ion Elastic Recoil Detection and liquid scintillation counting

    NASA Astrophysics Data System (ADS)

    Korschinek, G.; Bergmaier, A.; Faestermann, T.; Gerstmann, U. C.; Knie, K.; Rugel, G.; Wallner, A.; Dillmann, I.; Dollinger, G.; von Gostomski, Ch. Lierse; Kossert, K.; Maiti, M.; Poutivtsev, M.; Remmert, A.

    2010-01-01

    The importance of 10Be in different applications of accelerator mass spectrometry (AMS) is well-known. In this context the half-life of 10Be has a crucial impact, and an accurate and precise determination of the half-life is a prerequisite for many of the applications of 10Be in cosmic-ray and earth science research. Recently, the value of the 10Be half-life has been the centre of much debate. In order to overcome uncertainties inherent in previous determinations, we introduced a new method of high accuracy and precision. An aliquot of our highly enriched 10Be master solution was serially diluted with increasing well-known masses of 9Be. We then determined the initial 10Be concentration by least square fit to the series of measurements of the resultant 10Be/ 9Be ratio. In order to minimize uncertainties because of mass bias which plague other low-energy mass spectrometric methods, we used for the first time Heavy-Ion Elastic Recoil Detection (HI-ERD) for the determination of the 10Be/ 9Be isotopic ratios, a technique which does not suffer from difficult to control mass fractionation. The specific activity of the master solution was measured by means of accurate liquid scintillation counting (LSC). The resultant combination of the 10Be concentration and activity yields a 10Be half-life of T1/2 = 1.388 ± 0.018 (1 s, 1.30%) Ma. In a parallel but independent study (Chmeleff et al. [11]), found a value of 1.386 ± 0.016 (1.15%) Ma. Our recommended weighted mean and mean standard error for the new value for 10Be half-life based on these two independent measurements is 1.387 ± 0.012 (0.87%) Ma.

  20. Elastic recoil detection analysis for large recoil angles (LA-ERDA)

    NASA Astrophysics Data System (ADS)

    Bogdanović Radović, I.; Steinbauer, E.; Benka, O.

    2000-09-01

    In this paper, elastic recoil detection (ERD) measurements at recoil angle of 60° using ion-induced electron emission (IEE) for particle identification are presented. In our IEE system for particle identification, recoiled target atoms and scattered projectiles penetrate a set of thin carbon foils before their energy is analyzed in a solid state detector. Particle identification is based on the fact that the total number of electrons emitted from the foils depends on the particle nuclear charge. This method is characterized by its low minimum detectable energy, which stimulated us to study ERDA at 60°. Due to collision kinematics and due to the angular dependence of the scattering cross-sections, it is expected that the sensitivity can be significantly improved. In this work, the detection efficiency of the IEE particle identification system for H recoils at energies below 1 MeV was determined. LA-ERDA measurements were performed with 4He and 12C projectiles using two different types of samples with a well-known amount and depth distribution of H atoms near the surface. Sample 1 consisted of a 50 μg/cm 2 melamine layer evaporated on a flat Si substrate, sample 2 was a Si wafer with implanted H. Sensitivity and depth resolution were measured using LA-ERDA with a recoil angle of 60° and ERDA with recoil angles of 30° and 45°. The results for different recoil geometries and projectiles are discussed and compared with theoretical predictions.

  1. Nitrogen ion implantation into various materials using 28 GHz electron cyclotron resonance ion source

    NASA Astrophysics Data System (ADS)

    Shin, Chang Seouk; Lee, Byoung-Seob; Choi, Seyong; Yoon, Jang-Hee; Kim, Hyun Gyu; Ok, Jung-Woo; Park, Jin Yong; Kim, Seong Jun; Bahng, Jungbae; Hong, Jonggi; Lee, Seung Wook; Won, Mi-Sook

    2016-02-01

    The installation of the 28 GHz electron cyclotron resonance ion source (ECRIS) ion implantation beamline was recently completed at the Korea Basic Science Institute. The apparatus contains a beam monitoring system and a sample holder for the ion implantation process. The new implantation system can function as a multipurpose tool since it can implant a variety of ions, ranging hydrogen to uranium, into different materials with precise control and with implantation areas as large as 1-10 mm2. The implantation chamber was designed to measure the beam properties with a diagnostic system as well as to perform ion implantation with an in situ system including a mass spectrometer. This advanced implantation system can be employed in novel applications, including the production of a variety of new materials such as metals, polymers, and ceramics and the irradiation testing and fabrication of structural and functional materials to be used in future nuclear fusion reactors. In this investigation, the first nitrogen ion implantation experiments were conducted using the new system. The 28 GHz ECRIS implanted low-energy, multi-charged nitrogen ions into copper, zinc, and cobalt substrates, and the ion implantation depth profiles were obtained. SRIM 2013 code was used to calculate the profiles under identical conditions, and the experimental and simulation results are presented and compared in this report. The depths and ranges of the ion distributions in the experimental and simulation results agree closely and demonstrate that the new system will enable the treatment of various substrates for advanced materials research.

  2. Nitrogen ion implantation into various materials using 28 GHz electron cyclotron resonance ion source.

    PubMed

    Shin, Chang Seouk; Lee, Byoung-Seob; Choi, Seyong; Yoon, Jang-Hee; Kim, Hyun Gyu; Ok, Jung-Woo; Park, Jin Yong; Kim, Seong Jun; Bahng, Jungbae; Hong, Jonggi; Lee, Seung Wook; Won, Mi-Sook

    2016-02-01

    The installation of the 28 GHz electron cyclotron resonance ion source (ECRIS) ion implantation beamline was recently completed at the Korea Basic Science Institute. The apparatus contains a beam monitoring system and a sample holder for the ion implantation process. The new implantation system can function as a multipurpose tool since it can implant a variety of ions, ranging hydrogen to uranium, into different materials with precise control and with implantation areas as large as 1-10 mm(2). The implantation chamber was designed to measure the beam properties with a diagnostic system as well as to perform ion implantation with an in situ system including a mass spectrometer. This advanced implantation system can be employed in novel applications, including the production of a variety of new materials such as metals, polymers, and ceramics and the irradiation testing and fabrication of structural and functional materials to be used in future nuclear fusion reactors. In this investigation, the first nitrogen ion implantation experiments were conducted using the new system. The 28 GHz ECRIS implanted low-energy, multi-charged nitrogen ions into copper, zinc, and cobalt substrates, and the ion implantation depth profiles were obtained. SRIM 2013 code was used to calculate the profiles under identical conditions, and the experimental and simulation results are presented and compared in this report. The depths and ranges of the ion distributions in the experimental and simulation results agree closely and demonstrate that the new system will enable the treatment of various substrates for advanced materials research.

  3. Nitrogen ion implantation into various materials using 28 GHz electron cyclotron resonance ion source.

    PubMed

    Shin, Chang Seouk; Lee, Byoung-Seob; Choi, Seyong; Yoon, Jang-Hee; Kim, Hyun Gyu; Ok, Jung-Woo; Park, Jin Yong; Kim, Seong Jun; Bahng, Jungbae; Hong, Jonggi; Lee, Seung Wook; Won, Mi-Sook

    2016-02-01

    The installation of the 28 GHz electron cyclotron resonance ion source (ECRIS) ion implantation beamline was recently completed at the Korea Basic Science Institute. The apparatus contains a beam monitoring system and a sample holder for the ion implantation process. The new implantation system can function as a multipurpose tool since it can implant a variety of ions, ranging hydrogen to uranium, into different materials with precise control and with implantation areas as large as 1-10 mm(2). The implantation chamber was designed to measure the beam properties with a diagnostic system as well as to perform ion implantation with an in situ system including a mass spectrometer. This advanced implantation system can be employed in novel applications, including the production of a variety of new materials such as metals, polymers, and ceramics and the irradiation testing and fabrication of structural and functional materials to be used in future nuclear fusion reactors. In this investigation, the first nitrogen ion implantation experiments were conducted using the new system. The 28 GHz ECRIS implanted low-energy, multi-charged nitrogen ions into copper, zinc, and cobalt substrates, and the ion implantation depth profiles were obtained. SRIM 2013 code was used to calculate the profiles under identical conditions, and the experimental and simulation results are presented and compared in this report. The depths and ranges of the ion distributions in the experimental and simulation results agree closely and demonstrate that the new system will enable the treatment of various substrates for advanced materials research. PMID:26931931

  4. The Discovery of Rhea as a Source of Nitrogen Ions

    NASA Astrophysics Data System (ADS)

    Reisenfeld, Daniel; Janzen, Paul; Johnson, Robert; Powell, Ronald; Smith, H. Todd; Wilson, Robert

    The Cassini plasma spectrometer (CAPS) instrument made measurements of the plasma envi-ronment near Rhea when Cassini passed through the moon's wake on November 26, 2005 at a distance of 500 km, and again on August 30, 2007, at a distance of 5000 km. During both en-counters, the CAPS ion mass spectrometer (CAPS/IMS) detected an enhancement of nitrogen ions (N+ ) by a factor of two relative to the ambient environment. Compared to water group ions (O+ , OH+ , H2 O+ , H3 O+ ), this amounted to a fractional increase from 10% to 20% of the water group content. There has already been a suggestion that Rhea possesses a dust halo (Jones, et al., Science 2008) and that it is a source of O2 + (Martens et al., GRL, 2008). Our results provide further evidence that Rhea is a source of plasma for Saturn's magnetosphere. To explore the degree to which Rhea may have an active surface, modeling of the nitrogen source rate is currently under way. We will present our current results as well as composition results from the upcoming Rhea encounter on March 2, 2010, when Cassini passes within 100 km of the moon.

  5. High acceptance recoil polarimeter

    SciTech Connect

    The HARP Collaboration

    1992-12-05

    In order to detect neutrons and protons in the 50 to 600 MeV energy range and measure their polarization, an efficient, low-noise, self-calibrating device is being designed. This detector, known as the High Acceptance Recoil Polarimeter (HARP), is based on the recoil principle of proton detection from np[r arrow]n[prime]p[prime] or pp[r arrow]p[prime]p[prime] scattering (detected particles are underlined) which intrinsically yields polarization information on the incoming particle. HARP will be commissioned to carry out experiments in 1994.

  6. Precision Spectroscopy on Single Cold Trapped Molecular Nitrogen Ions

    NASA Astrophysics Data System (ADS)

    Hegi, Gregor; Najafian, Kaveh; Germann, Matthias; Sergachev, Ilia; Willitsch, Stefan

    2016-06-01

    The ability to precisely control and manipulate single cold trapped particles has enabled spectroscopic studies on narrow transitions of ions at unprecedented levels of precision. This has opened up a wide range of applications, from tests of fundamental physical concepts, e.g., possible time-variations of fundamental constants, to new and improved frequency standards. So far most of these experiments have concentrated on atomic ions. Recently, however, attention has also been focused on molecular species, and molecular nitrogen ions have been identified as promising candidates for testing a possible time-variation of the proton/electron mass ratio. Here, we report progress towards precision-spectroscopic studies on dipole-forbidden vibrational transitions in single trapped N2+ ions. Our approach relies on the state-selective generation of single N2+ ions, subsequent infrared excitation using high intensity, narrow-band quantum-cascade lasers and a quantum-logic scheme for non-destructive state readout. We also characterize processes limiting the state lifetimes in our experiment, which impair the measurement fidelity. P. O. Schmidt et. al., Science 309 (2005), 749. M. Kajita et. al., Phys. Rev. A 89 (2014), 032509 M. Germann , X. Tong, S. Willitsch, Nature Physics 10 (2014), 820. X. Tong, A. Winney, S. Willitsch, Phys. Rev. Lett. 105 (2010), 143001

  7. Coupled, Nitrogen, Oxygen, Carbon and Ion Chemistry on Titan

    NASA Astrophysics Data System (ADS)

    Yelle, Roger; Vuitton, Veronique; Lavvas, Panayotis; Klippenstein, Stephen; Horst, Sarah

    2016-06-01

    We present simulations of the coupled nitrogen, oxygen, and ion chemistry on Titan using a state-of-the-art photochemical model. The model is one dimensional and extends from the surface to the exobase. The chemistry linking 160 neutral species and 172 ion species is described through networks including 1139 neutral reactions and 4361 ion reactions. UV photolysis of 59 species is included as well as dissociation and ionization of 16 species due to suprathermal electrons. Reaction rate coefficients are obtained from a thorough review of the literature supplemented by calculations of rates of important reactions when laboratory values are not available. Comparison of the model with available observational constraints helps to determine the fundamental chemical pathways in the atmosphere. We will discuss in particular the importance of recent measurements of HNC, HC15N, CO2, and H2O and the role of ion chemistry in the synthesis of neutral species. Key reactions that require further laboratory of theoretical study will be identified.

  8. Effect of MeV nitrogen ion implantation on the resistivity transition in Czochralski silicon wafers

    NASA Astrophysics Data System (ADS)

    Moon, Byeong-Sam; Lee, In-Ji; Park, Jea-Gun

    2012-12-01

    We investigated how MeV nitrogen ion implantation affects the resistivity transition in Czochralski (CZ) silicon wafers. After annealing at 800 °C for 20 h and again at 1000 °C for 10 h, the implanted nitrogen atoms accumulated in the projected range (R P ) for ion doses less than 5 × 1014 cm-2 whereas they accumulated at both R P /2 and R P at ion doses above 3 × 1015 cm-2. These results indicate that no resistivity transition was found at nitrogen ion doses less than 5 × 1013 cm-2 whereas n-/p or n+/p resistivity transition was shown at ion doses higher than 5 × 1014 cm-2. Many fewer than 1% of the implanted nitrogen atoms were ionized after the heat treatment. Thus, the resistivity of nitrogen-doped silicon wafers is more than 100 times higher than that of phosphorous-doped silicon wafers.

  9. Interpreting Recoil for Undergraduate Students

    ERIC Educational Resources Information Center

    Elsayed, Tarek A.

    2012-01-01

    The phenomenon of recoil is usually explained to students in the context of Newton's third law. Typically, when a projectile is fired, the recoil of the launch mechanism is interpreted as a reaction to the ejection of the smaller projectile. The same phenomenon is also interpreted in the context of the conservation of linear momentum, which is…

  10. Interpreting Recoil for Undergraduate Students

    NASA Astrophysics Data System (ADS)

    Elsayed, Tarek A.

    2012-04-01

    The phenomenon of recoil is usually explained to students in the context of Newton's third law. Typically, when a projectile is fired, the recoil of the launch mechanism is interpreted as a reaction to the ejection of the smaller projectile. The same phenomenon is also interpreted in the context of the conservation of linear momentum, which is closely related to Newton's third law. Since the actual microscopic causes of recoil differ from one problem to another, some students (and teachers) may not be satisfied with understanding recoil through the principles of conservation of linear momentum and Newton's third law. For these students, the origin of the recoil motion should be presented in more depth.

  11. Inorganic ion and nitrogen isotopic compositions of atmospheric aerosols at Yurihonjo, Japan: Implications for nitrogen sources

    NASA Astrophysics Data System (ADS)

    Kawashima, Hiroto; Kurahashi, Takahiro

    2011-11-01

    We studied the suspended particulate matter (SPM) collected in Akita Prefecture, Japan from April 2008 to January 2009 for inorganic ion composition and nitrogen isotopic ratio ( δ15N) of NH 4+ and NO 3-. The results showed an average SPM concentration of 15.6 μg m -3. The seasonal trend for SPM was higher values in the spring, lower in the winter. The major cations were Na +, NH 4+, Ca 2+ and major anions were SO 42-, NO 3-, Cl -. The annual correlation coefficient of ions indicates a very high value with NH 4+ and SO 42- ( R = 0.93), NO 3- and K + ( R = 0.65), NO 3- and Ca 2+ ( R = 0.62). The high springtime values are the apparent result of the dust stream from Asia. Average δ15N-NH 4+ and δ15N-NO 3- were 16.1‰ and -0.69‰, respectively. δ15N-NH 4+ increased slightly in summer, and δ15N-NO 3- increased considerably in winter. The trends indicated conversely. The heavy δ15N-NH 4+ in summer appears to be from agricultural sources such as animal waste and fertilizer. In addition, according to the difference in isotopes of NO x sources as the precursor of NO 3-, the dominant origin of heavy δ15N-NO 3- in winter could be NO x emitted from fossil fuel combustion at low temperature. Moreover, the average δ15N-NO 3- seemed to be made to baseline (approximately 0%) by vehicle emissions at high temperature. These results are considered to be very reasonable.

  12. Nitrogen ion utilization by tulip poplar (Liriodendron tulipifera L. ) seedlings

    SciTech Connect

    Mann, L.K.

    1982-01-01

    Growth responses of one-year-old tulip poplar seedlings were determined for different nitrogen sources (HN/sub 4/NO/sub 3/, NH+/sub 4/, NO-/sub 3/, no nitrogen) at 336 ppm N in nutrient culture. At the end of three months, there were no significant differences in growth observed among treatments in terms of stem elongation, leaf area, and leaf size. After four months, however, seedlings of the NH/sub 4/NO/sub 3/ treatment exhibited significantly (P<0.05) greater growth (final weight gain and stem elongation) than all other nitrogen sorces. Growth was slightly less for the NO-/sub 3/ treatment plants, but compared with NH+/sub 4/ and no nitrogen treatment, both NH/sub 4/NO/sub 3/ and NO-/sub 3/ treatments exhibited significantly greater growth responses. NO-/sub 3/ is recommended as the sole nitrogen source, especially for small seedlings of tulip poplar.

  13. The damaging effects of nitrogen ion beam implantation on upland cotton ( Gossypium hirsutum L.) pollen grains

    NASA Astrophysics Data System (ADS)

    Yu, Yanjie; Wu, Lijun; Wu, Yuejin; Wang, Qingya; Tang, Canming

    2008-09-01

    With the aim to study the effects of an ion beam on plant cells, upland cotton (Gossypium hirsutum L.) cultivar "Sumian 22" pollen grains were irradiated in vacuum (7.8 × 10-3 Pa) by low-energy nitrogen ions with an energy of 20 keV at various fluences ranging from 0.26 × 1016 to 0.78 × 1016 N+/cm2. The irradiation effects on pollen grains were tested, considering the ultrastructural changes in the exine and interior walls of pollen grains, their germination rate, the growth speed of the pollen tubes in the style, fertilization and boll development after the pistils were pollinated by the pollen grains which had been implanted with nitrogen ions. Nitrogen ions entered the pollen grains by etching and penetrating the exine and interior walls and destroying cell structures. A greater percentage of the pollen grains were destroyed as the fluence of N+ ions increased. Obviously, the nitrogen ion beam penetrated the exine and interior walls of the pollen grains and produced holes of different sizes. As the ion fluence increased, the amount and the density of pollen grain inclusions decreased and the size of the lacuna and starch granules increased. Pollen grain germination rates decreased with increasing ion fluence. The number of pollen tubes in the style declined with increased ion implantation into pollen grains, but the growth speed of the tubes did not change. All of the pollen tubes reached the end of the style at 13 h after pollination. This result was consistent with that of the control. Also, the weight and the diameter of the ovary decreased and shortened with increased ion beam implantation fluence. No evident change in the fecundation time of the ovule was observed. These results indicate that nitrogen ions can enter pollen grains and cause a series of biological changes in pollen grains of upland cotton.

  14. Deconvoluting nonaxial recoil in Coulomb explosion measurements of molecular axis alignment

    NASA Astrophysics Data System (ADS)

    Christensen, Lauge; Christiansen, Lars; Shepperson, Benjamin; Stapelfeldt, Henrik

    2016-08-01

    We report a quantitative study of the effect of nonaxial recoil during Coulomb explosion of laser-aligned molecules and introduce a method to remove the blurring caused by nonaxial recoil in the fragment-ion angular distributions. Simulations show that nonaxial recoil affects correlations between the emission directions of fragment ions differently from the effect caused by imperfect molecular alignment. The method, based on analysis of the correlation between the emission directions of the fragment ions from Coulomb explosion, is used to deconvolute the effect of nonaxial recoil from experimental fragment angular distributions. The deconvolution method is then applied to a number of experimental data sets to correct the degree of alignment for nonaxial recoil, to select optimal Coulomb explosion channels for probing molecular alignment, and to estimate the highest degree of alignment that can be observed from selected Coulomb explosion channels.

  15. Generation of elliptically polarized nitrogen ion laser fields using two-color femtosecond laser pulses

    PubMed Central

    Li, Ziting; Zeng, Bin; Chu, Wei; Xie, Hongqiang; Yao, Jinping; Li, Guihua; Qiao, Lingling; Wang, Zhanshan; Cheng, Ya

    2016-01-01

    We experimentally investigate generation of nitrogen molecular ion () lasers with two femtosecond laser pulses at different wavelengths. The first pulse serves as the pump which ionizes the nitrogen molecules and excites the molecular ions to excited electronic states. The second pulse serves as the probe which leads to stimulated emission from the excited molecular ions. We observe that changing the angle between the polarization directions of the two pulses gives rise to elliptically polarized laser fields, which is interpreted as a result of strong birefringence of the gain medium near the wavelengths of the laser. PMID:26888182

  16. Generation of elliptically polarized nitrogen ion laser fields using two-color femtosecond laser pulses.

    PubMed

    Li, Ziting; Zeng, Bin; Chu, Wei; Xie, Hongqiang; Yao, Jinping; Li, Guihua; Qiao, Lingling; Wang, Zhanshan; Cheng, Ya

    2016-02-18

    We experimentally investigate generation of nitrogen molecular ion (N2+) lasers with two femtosecond laser pulses at different wavelengths. The first pulse serves as the pump which ionizes the nitrogen molecules and excites the molecular ions to excited electronic states. The second pulse serves as the probe which leads to stimulated emission from the excited molecular ions. We observe that changing the angle between the polarization directions of the two pulses gives rise to elliptically polarized N2+ laser fields, which is interpreted as a result of strong birefringence of the gain medium near the wavelengths of the N2+ laser.

  17. Generation of elliptically polarized nitrogen ion laser fields using two-color femtosecond laser pulses

    NASA Astrophysics Data System (ADS)

    Li, Ziting; Zeng, Bin; Chu, Wei; Xie, Hongqiang; Yao, Jinping; Li, Guihua; Qiao, Lingling; Wang, Zhanshan; Cheng, Ya

    2016-02-01

    We experimentally investigate generation of nitrogen molecular ion () lasers with two femtosecond laser pulses at different wavelengths. The first pulse serves as the pump which ionizes the nitrogen molecules and excites the molecular ions to excited electronic states. The second pulse serves as the probe which leads to stimulated emission from the excited molecular ions. We observe that changing the angle between the polarization directions of the two pulses gives rise to elliptically polarized laser fields, which is interpreted as a result of strong birefringence of the gain medium near the wavelengths of the laser.

  18. Carbon, nitrogen, and oxygen ion implantation of stainless steel

    SciTech Connect

    Rej, D.J.; Gavrilov, N.V.; Emlin, D.

    1995-12-31

    Ion implantation experiments of C, N, and O into stainless steel have been performed, with beam-line and plasma source ion implantation methods. Acceleration voltages were varied between 27 and 50 kV, with pulsed ion current densities between 1 and 10 mA/cm{sup 2}. Implanted doses ranged from 0.5 to 3 {times} 10{sup 18}cm{sup -2}, while workpiece temperatures were maintained between 25 and 800 C. Implant concentration profiles, microstructure, and surface mechanical properties of the implanted materials are reported.

  19. Nitrogen removal from plasma-facing components by ion cyclotron wall conditioning in TEXTOR

    NASA Astrophysics Data System (ADS)

    Carrasco, A. G.; Wauters, T.; Petersson, P.; Drenik, A.; Rubel, M.; Crombé, K.; Douai, D.; Fortuna, E.; Kogut, D.; Kreter, A.; Lyssoivan, A.; Möller, S.; Pisarek, M.; Vervier, M.

    2015-08-01

    The efficiency of ion cyclotron wall conditioning (ICWC) in the removal of nitrogen from plasma-facing components in TEXTOR was assessed. In two experiments the wall was loaded with nitrogen and subsequently cleaned by ICWC in deuterium and helium. The retention and removal of nitrogen was studied in-situ by means of mass spectrometry, and ex-situ by surface analysis of a set of graphite, tungsten and TZM plates installed on test limiter systems. 15N rare isotope was used as a marker. The results from the gas balance showed that about 25% of the retained nitrogen was removed after ICWC cleaning, whereas surface analysis of the plates based on ToF-HIERDA showed an increase of the deposited species after the cleaning. This indicates that during ICWC operation on carbon devices, nitrogen is not only pumped out but also transported to other locations on the wall. Additionally, deuterium surface content was studied before and after ICWC cleaning.

  20. Nitrogen mass transfer models for plasma-based low-energy ion implantation

    SciTech Connect

    Zheng, Bocong; Wang, Kesheng; Zhang, Zhipeng; Che, Honglong; Lei, Mingkai

    2015-03-15

    The nitrogen mass transfer process in plasma-based low-energy ion implantation (PBLEII) is theoretically and experimentally studied in order to explore the process mechanism of PBLEII and therefore to optimize the apparatus design and the process conditions. An electron cyclotron resonance (ECR) microwave discharge generates the nitrogen plasma with a high density of 10{sup 11}–10{sup 12} ions/cm{sup 3}, which diffuses downstream to the process chamber along the divergent magnetic field. The nitrogen ions in the plasma implant into the surface and transport to the matrix of an austenitic stainless steel under the low negative pulsed bias of −2 kV at a process temperature of 400 °C. A global plasma model is used to simulate the ECR microwave plasma discharge for a range of working pressures and microwave powers. The fluid models are adopted to calculate the plasma downstream diffusion, the sheath expansion and the low-energy ion implantation on the surface. A nonlinear kinetic discrete model is established to describe the nitrogen transport in the austenitic stainless steel and the results are compared with the experimental measurements. Under an average implantation current density of 0.3–0.6 mA/cm{sup 2}, the surface nitrogen concentration in the range from 18.5 to 29 at. % is a critical factor for the nitrogen transport in the AISI 304 austenitic stainless steel by PBLEII, which accelerates the implanted nitrogen diffusion inward up to 6–12 μm during a nitriding time of 4 h.

  1. Force optimized recoil control system

    NASA Astrophysics Data System (ADS)

    Townsend, P. E.; Radkiewicz, R. J.; Gartner, R. F.

    1982-05-01

    Reduction of the recoil force of high rate of fire automatic guns was proven effective. This system will allow consideration of more powerful guns for use in both helicopter and armored personnel carrier applications. By substituting the large shock loads of firing guns with a nearly constant force, both vibration and fatigue problems that prevent mounting of powerful automatic guns is eliminated.

  2. Escape of Nitrogen from Titan's atmosphere driven by magnetospheric and pick-up ions

    NASA Astrophysics Data System (ADS)

    Michael, M.; Liu, M.; Johnson, R. E.; Luhmann, J. G.; Shematovich, V. I.

    2003-05-01

    The nitrogen rich atmosphere of Titan is a significant source of the neutrals in Saturn's magnetosphere. As Titan does not posses an intrinsic magnetic field, energetic Kronian magnetospheric ions penetrate Titan's atmospheric exobase as can local pick-up ions (e.g. Shematovich et al. 2003). Penetration by energetic ions is described here using a 3-D Monte Carlo model. The incident ions can lead directly or indirectly to the production of fast neutrals that collide with other atmospheric neutrals. This leads to dissociation and the ejection of both atomic and molecular nitrogen. The recently calculated dissociation cross sections of N2 are used in the present model (Tully and Johnson 2002). The incident flux of slowed magentospheric N+ ions and pick-up C2H_5+ ions is estimated from the work of Brecht et al. (2000). These ions of energy less than 1.2 keV are shown to be more efficient in ejecting material from Titan's atmosphere than the higher energy corotating ions described in early estimates (Lammer et al. 1998). This incident flux of ions are used in the model and the results are used as a source of nitrogen for the Saturnian plasma torus. Acknowledgment: This work is supported by NASA:s Planetary Atmospheres Program. References Brecht, S.H., J.G. Luhmann, and D.J. Larson, J. Geophys. Res., 105, 13119, 2000. Lammer, H. W. Stumptner, and S.J. Bauer, Planet. Space Sci., 46, 1207, 1998. Shematovich, V.I., R.E. Johnson, M. Michael and J.G. Luhmann, J. Geophys. Res., in press, 2003. Tully, C., R.E. Johnson, J. Chem. Phys. 117, 6556-6561, 2002.

  3. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOEpatents

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  4. Shallow nitrogen ion implantation: Evolution of chemical state and defect structure in titanium

    NASA Astrophysics Data System (ADS)

    Manojkumar, P. A.; Chirayath, V. A.; Balamurugan, A. K.; Krishna, Nanda Gopala; Ilango, S.; Kamruddin, M.; Amarendra, G.; Tyagi, A. K.; Raj, Baldev

    2016-09-01

    Evolution of chemical states and defect structure in titanium during low energy nitrogen ion implantation by Plasma Immersion Ion Implantation (PIII) process is studied. The underlying process of chemical state evolution is investigated using secondary ion mass spectrometry and X-ray photoelectron spectroscopy. The implantation induced defect structure evolution as a function of dose is elucidated using variable energy positron annihilation Doppler broadening spectroscopy (PAS) and the results were corroborated with chemical state. Formation of 3 layers of defect state was modeled to fit PAS results.

  5. Nitrogen Doping of Single-Walled Carbon Nanotube by Using Mass-Separated Low-Energy Ion Beams

    NASA Astrophysics Data System (ADS)

    Yamamoto, Kazuhiro; Kamimura, Takafumi; Matsumoto, Kazuhiko

    2005-04-01

    Mass-separated nitrogen ions with the mass number of 14 were irradiated to the single-walled carbon nanotubes (SWCNTs) under an ultra high-vacuum pressure of 10-7 Pa for the purpose of achieving nitrogen doping in nanotubes. The incident angle of the ion beam was normal to the target nanotube, and the ion beam energy was 30 eV, which was close to the displacement energy of graphite. The dependence of the structure of SWCNTs on the ion dose was investigated. The ion dose ranged from 2.8× 1014 to 2.2× 1016 ions/cm2. The nitrogen ions are incorporated into graphite sheets of SWCNTs after irradiation at 2.8× 1014 ions/cm2. The graphite structure is distorted and many defects are induced in the nanotube by the nitrogen incorporation. The structure is changed to amorphous after irradiation at 2.2× 1016 ions/cm2. The nitrogen ions with the ion energy of 25 eV are irradiated to the field effect transistor device with the nanotube channel. The n-type characteristic appears upon ion irradiation, and the device exhibits ambipolar behavior.

  6. Corrosion behaviors of Mo coating on stainless steel 316 substrates implanted by different nitrogen ion fluences

    NASA Astrophysics Data System (ADS)

    Mojtahedzadeh Larijani, Madjid; Bafandeh, Nastaran

    2014-03-01

    The molybdenum nitride coating was produced by nitrogen ion implantation of the molybdenum layer deposited on the stainless steel 316 (SS) substrates. At first, molybdenum layers were deposited on the substrates by ion beam sputtering method, then nitrogen ions with an energy of 30 keV and a fluence between 1×1017 and 12×1017 N+ cm-2 were implanted in Mo/SS system. Crystal structure and topography of the surface are investigated by grazing incidence X-ray diffraction (GIXRD) and atomic force microscopy (AFM) image respectively. XRD patterns showed the formation of molybdenum nitride phases in all implanted samples. Corrosion tests showed that the corrosion resistance of the samples strongly depends on the nitrogen applied fluences. A considerable improvement of corrosion performance by increasing ions fluences was observed. The lowest corrosion current density with amount of 0.1 μA/cm2 was obtained at 12×1017 ions/cm2 fluence in our case.

  7. COSY Simulations to Guide Commissioning of the St. George Recoil Mass Separator

    NASA Astrophysics Data System (ADS)

    Schmitt, Jaclyn; Moran, Michael; Seymour, Christopher; Gilardy, Gwenaelle; Meisel, Zach; Couder, Manoel

    2015-10-01

    The goal of St. George (STrong Gradient Electromagnetic Online Recoil separator for capture Gamma ray Experiments) is to measure (α, γ) cross sections relevant to stellar helium burning. Recoil separators such as St. George are able to more closely approach the low astrophysical energies of interest because they collect reaction recoils rather than γ-rays, and thus are not limited by room background. In order to obtain an accurate cross section measurement, a recoil separator must be able to collect all recoils over their full range of expected energy and angular spread. The energy acceptance of St. George is currently being measured, and the angular acceptance will be measured soon. Here we present the results of COSY ion optics simulations and magnetic field analyses which were performed to help guide the commissioning measurements and diagnostic upgrades required to complete those measurements. National Science Foundation Research Experiences for Undergraduates program.

  8. Improving low-energy boron/nitrogen ion implantation in graphene by ion bombardment at oblique angles

    NASA Astrophysics Data System (ADS)

    Bai, Zhitong; Zhang, Lin; Liu, Ling

    2016-04-01

    Ion implantation is a widely adopted approach to structurally modify graphene and tune its electrical properties for a variety of applications. Further development of the approach requires a fundamental understanding of the mechanisms that govern the ion bombardment process as well as establishment of key relationships between the controlling parameters and the dominant physics. Here, using molecular dynamics simulations with adaptive bond order calculations, we demonstrate that boron and nitrogen ion bombardment at oblique angles (particularly at 70°) can improve both the productivity and quality of perfect substitution by over 25%. We accomplished this by systematically analyzing the effects of the incident angle and ion energy in determining the probabilities of six distinct types of physics that may occur in an ion bombardment event, including reflection, absorption, substitution, single vacancy, double vacancy, and transmission. By analyzing the atomic trajectories from 576 000 simulations, we identified three single vacancy creation mechanisms and four double vacancy creation mechanisms, and quantified their probability distributions in the angle-energy space. These findings further open the door for improved control of ion implantation towards a wide range of applications of graphene.Ion implantation is a widely adopted approach to structurally modify graphene and tune its electrical properties for a variety of applications. Further development of the approach requires a fundamental understanding of the mechanisms that govern the ion bombardment process as well as establishment of key relationships between the controlling parameters and the dominant physics. Here, using molecular dynamics simulations with adaptive bond order calculations, we demonstrate that boron and nitrogen ion bombardment at oblique angles (particularly at 70°) can improve both the productivity and quality of perfect substitution by over 25%. We accomplished this by systematically

  9. Nitrogen and boron ion implantation into electrodeposited hard chrome

    SciTech Connect

    Walter, K.C.; Tesmer, J.R.; Scarborough, W.K.; Woodring, J.S.; Nastasi, M.; Kern, K.T.

    1996-10-01

    Electrodeposited hard chrome was ion implanted with N alone, B alone, and a combination. Separate N and B implantation was done at 75 keV and incident doses of 2, 4, and 8x10{sup 17} at/cm{sup 2}. Samples with both N/B implants used 75 keV and incident dose levels of 4x10{sup 17} N- and B-at/cm{sup 2}. Beam-line system was used. Retained dose was measured using ion beam analysis, which indicated most of the incident dose was retained. Surface hardness, wear coefficient, and friction coefficient were determined by nanohardness indentation and pin-on-disk wear. At a depth of 50 nm, surface hardness increased from 18{+-}1 GPa (unimplanted) to a max of 23{+-}4 GPa for B implant and 26{+-}1 GPa for N implant. the wear coefficient was reduced by 1.3x to 7.4x, depending on implantation. N implant results in lower wear coefficients than B implant.

  10. Making AlN(x) Tunnel Barriers Using a Low-Energy Nitrogen-Ion Beam

    NASA Technical Reports Server (NTRS)

    Kaul, Anupama; Kleinsasser, Alan; Bumble, Bruce; LeDuc, Henry; Lee, Karen

    2005-01-01

    A technique based on accelerating positive nitrogen ions onto an aluminum layer has been demonstrated to be effective in forming thin (<2 nm thick) layers of aluminum nitride (AlN(x)) for use as tunnel barriers in Nb/Al-AlN(x)/Nb superconductor/insulator/ superconductor (SIS) Josephson junctions. AlN(x) is the present material of choice for tunnel barriers because, to a degree greater than that of any other suitable material, it offers the required combination of low leakage current at high current density and greater thermal stability. While ultra-thin AlN films with good thickness and stoichiometry control are easily formed using techniques such as reactive molecular beam epitaxy and chemical vapor deposition, growth temperatures of 900 C are necessary for the dissociative adsorption of nitrogen from either nitrogen (N2) or ammonia (NH3). These growth temperatures are prohibitively high for the formation of tunnel barriers on Nb films because interfacial reactions at temperatures as low as 200 to 300 C degrade device properties. Heretofore, deposition by reactive sputtering and nitridation of thin Al layers with DC and RF nitrogen plasmas have been successfully used to form AlN barriers in SIS junctions. However, precise control over critical current density Jc has proven to be a challenge, as is attaining adequate process reproducibility from system to system. The present ion-beam technique is an alternative to the plasma or reactive sputtering techniques as it provides a highly controlled arrival of reactive species, independent of the electrical conditions of the substrate or vacuum chamber. Independent and accurate control of parameters such as ion energy, flux, species, and direction promises more precise control of film characteristics such as stoichiometry and thickness than is the case with typical plasma processes. In particular, the background pressure during ion-beam nitride growth is 2 or 3 orders of magnitude lower, minimizing the formation of

  11. Local formation of nitrogen-vacancy centers in diamond by swift heavy ions

    SciTech Connect

    Schwartz, J.; Aloni, S.; Ogletree, D. F.; Tomut, M.; Bender, M.; Severin, D.; Trautmann, C.; Rangelow, I. W.; Schenkel, T.

    2014-12-07

    We exposed nitrogen-implanted diamonds to beams of swift heavy ions (∼1 GeV, ∼4 MeV/u) and find that these irradiations lead directly to the formation of nitrogen vacancy (NV) centers, without thermal annealing. We compare the photoluminescence intensities of swift heavy ion activated NV{sup −} centers to those formed by irradiation with low-energy electrons and by thermal annealing. NV{sup −} yields from irradiations with swift heavy ions are 0.1 of yields from low energy electrons and 0.02 of yields from thermal annealing. We discuss possible mechanisms of NV center formation by swift heavy ions such as electronic excitations and thermal spikes. While forming NV centers with low efficiency, swift heavy ions could enable the formation of three dimensional NV{sup −} assemblies over relatively large distances of tens of micrometers. Further, our results show that NV center formation is a local probe of (partial) lattice damage relaxation induced by electronic excitations from swift heavy ions in diamond.

  12. Concentration dependent nitrogen diffusion coefficient in expanded austenite formed by ion implantation

    NASA Astrophysics Data System (ADS)

    Mandl, S.; Rauschenbach, B.

    2002-06-01

    Expanded austenite, formed after nitrogen plasma immersion ion implantation or low energy nitriding of austenitic stainless, is characterized by a high nitrogen content CN of up to 20 at. % and an unusual fast diffusion, which in general cannot be described using a single diffusion coefficient. Here, the concentration dependent diffusivity is calculated for several experimental parameters and steel alloys. Two mathematical simplifications of the general diffusion theory, well justified for physical reasons, helped in solving the equations. First, a constant surface concentration was assumed, despite a constant nitrogen flux into the surface, and, second, only mobile nitrogen atoms in a stationary steel matrix were considered. Thus, it was possible to solve the Boltzmann-Matano equation and obtain the concentration dependent diffusion coefficient D(CN). In all cases, a step-like behavior, with a high value for high nitrogen contents and a low value for low ones, is found, with the transition point between a nitrogen concentration of 5 and 17 at. %, depending on the sample.

  13. Modification of diamond-like carbon films by nitrogen incorporation via plasma immersion ion implantation

    NASA Astrophysics Data System (ADS)

    Flege, S.; Hatada, R.; Hoefling, M.; Hanauer, A.; Abel, A.; Baba, K.; Ensinger, W.

    2015-12-01

    The addition of nitrogen to diamond-like carbon films affects properties such as the inner stress of the film, the conductivity, biocompatibility and wettability. The nitrogen content is limited, though, and the maximum concentration depends on the preparation method. Here, plasma immersion ion implantation was used for the deposition of the films, without the use of a separate plasma source, i.e. the plasma was generated by a high voltage applied to the samples. The plasma gas consisted of a mixture of C2H4 and N2, the substrates were silicon and glass. By changing the experimental parameters (high voltage, pulse length and repetition rate and gas flow ratio) layers with different N content were prepared. Additionally, some samples were prepared using a DC voltage. The nitrogen content and bonding was investigated with SIMS, AES, XPS, FTIR and Raman spectroscopy. Their influence on the electrical resistivity of the films was investigated. Depending on the preparation conditions different nitrogen contents were realized with maximum contents around 11 at.%. Those values were compared with the nitrogen concentration that can be achieved by implantation of nitrogen into a DLC film.

  14. Etching and structural changes in nitrogen plasma immersion ion implanted polystyrene films

    NASA Astrophysics Data System (ADS)

    Gan, B. K.; Bilek, M. M. M.; Kondyurin, A.; Mizuno, K.; McKenzie, D. R.

    2006-06-01

    Plasma immersion ion implantation (PIII), with nitrogen ions of energy 20 keV in the fluence range of 5 × 1014-2 × 1016 ions cm-2, is used to modify 100 nm thin films of polystyrene on silicon wafer substrates. Ellipsometry is used to study changes in thickness with etching and changes in optical constants. Two distinctly different etch rates are observed as the polymer structure is modified. FTIR spectroscopy data reveals the structural changes, including changes in aromatic and aliphatic groups and oxidation and carbonisation processes, occurring in the polystyrene film as a function of the ion fluence. The transformation to a dense amorphous carbon-like material was observed to progress through an intermediate structural form containing a high concentration of Cdbnd C and Cdbnd O bonds.

  15. Nitrogen

    USGS Publications Warehouse

    Apodaca, Lori E.

    2013-01-01

    The article presents an overview of the nitrogen chemical market as of July 2013, including the production of ammonia compounds. Industrial uses for ammonia include fertilizers, explosives, and plastics. Other topics include industrial capacity of U.S. ammonia producers CF Industries Holdings Inc., Koch Nitrogen Co., PCS Nitrogen, Inc., and Agrium Inc., the impact of natural gas prices on the nitrogen industry, and demand for corn crops for ethanol production.

  16. Effects of nitrogen sources and metal ions on ethanol fermentation with cadmium-containing medium.

    PubMed

    Xu, Qingyun; Wu, Mengnan; Hu, Jiajun; Gao, Min-Tian

    2016-01-01

    This study evaluated ethanol fermentation and its correlation with glutathione (GSH) synthesis under various cadmium-conditions with different metal ions and nitrogen sources. We found that corn steep liquor (CSL) and yeast extract have differential roles to play in GSH accumulation in cell even though both of them could alleviate the inhibition by cadmium. The different GSH accumulation in cell resulted from the different contents of metal ions in CSL and yeast extract. Intracellular GSH decreased with increasing calcium concentrations, and high calcium concentrations rendered the yeast more tolerant to cadmium stress than the nitrogen sources did. When the mole ratio of calcium to cadmium was 100:1, yeast tolerated 1000 µmol/L cadmium with no decrease in efficiency in ethanol production. As a result, the use of calcium allowed a significant saving of high-cost nutrient yeast extract with an efficient ethanol production, making the bioconversion of cadmium-containing biomass into ethanol possible.

  17. Short-range ordering of ion-implanted nitrogen atoms in SiC-graphene

    SciTech Connect

    Willke, P.; Druga, T.; Wenderoth, M.; Amani, J. A.; Weikert, S.; Hofsäss, H.; Thakur, S.; Maiti, K.

    2014-09-15

    We perform a structural analysis of nitrogen-doped graphene on SiC(0001) prepared by ultra low-energy ion bombardment. Using scanning tunneling microscopy, we show that nitrogen atoms are incorporated almost exclusively as graphitic substitution in the graphene honeycomb lattice. With an irradiation energy of 25 eV and a fluence of approximately 5 × 10{sup 14 }cm{sup −2}, we achieve a nitrogen content of around 1%. By quantitatively comparing the position of the N-atoms in the topography measurements with simulated random distributions, we find statistically significant short-range correlations. Consequently, we are able to show that the dopants arrange preferably at lattice sites given by the 6 × 6-reconstruction of the underlying substrate. This selective incorporation is most likely triggered by adsorbate layers present during the ion bombardment. This study identifies low-energy ion irradiation as a promising method for controlled doping in epitaxial graphene.

  18. The influence of nitrogen ion implantation on microhardness of the Stellite 6 alloy

    NASA Astrophysics Data System (ADS)

    Budzyński, P.; Kamiński, M.; Pałka, K.; Droździel, A.; Wiertel, M.

    2016-09-01

    Cobalt alloys known as Stellite used to produce or surfacing machine elements subjected to combustion gases and heat. They are used a currently in the manufacture of valves and valve seats in internal combustion engines. Because of the small thermal conductivity, stellite may not be subjected heat treatment. In order to improve the mechanical properties of cobalt alloys, samples were implanted with nitrogen ions with 65 keV energy and ion dose of 1·1016, 5·1016, 1·1017 N+/cm2. The influence of ion implantation on properties of strength was determined by measuring microhardness using a Vickers hardness test. The measurement results allowed to determine the increase in the microhardness of 20% with dose 5·1016 N+/cm2 compared to the sample not implanted. Implantation of nitrogen ions can increase the strength of the valves and the valve seats having Stellite without changing the external dimensions of the final element, and without interfering with its inner structure by low-temperature of modification the surface layer.

  19. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOEpatents

    Liu, David K.; Chang, Shih-Ger

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  20. Highly tunable formation of nitrogen-vacancy centers via ion implantation

    SciTech Connect

    Sangtawesin, S.; Brundage, T. O.; Atkins, Z. J.; Petta, J. R.

    2014-08-11

    We demonstrate highly tunable formation of nitrogen-vacancy (NV) centers using 20 keV {sup 15}N{sup +} ion implantation through arrays of high-resolution apertures fabricated with electron beam lithography. By varying the aperture diameters from 80 to 240 nm, as well as the average ion fluences from 5×10{sup 10} to 2 × 10{sup 11} ions/cm{sup 2}, we can control the number of ions per aperture. We analyze the photoluminescence on multiple sites with different implantation parameters and obtain ion-to-NV conversion yields of 6%–7%, consistent across all ion fluences. The implanted NV centers have spin dephasing times T{sub 2}{sup *} ∼ 3 μs, comparable to naturally occurring NV centers in high purity diamond with natural abundance {sup 13}C. With this technique, we can deterministically control the population distribution of NV centers in each aperture, allowing for the study of single or coupled NV centers and their integration into photonic structures.

  1. Nitrogen incorporation in saturated aliphatic C6-C8 hydrocarbons and ethanol in low-pressure nitrogen plasma generated by a hollow cathode discharge ion source.

    PubMed

    Usmanov, Dilshadbek T; Chen, Lee Chuin; Hiraoka, Kenzo; Wada, Hiroshi; Nonami, Hiroshi; Yamabe, Shinichi

    2016-06-01

    Ion/molecule reactions of saturated hydrocarbons (n-hexane, cyclohexane, n-heptane, n-octane and isooctane) in 28-Torr N2 plasma generated by a hollow cathode discharge ion source were investigated using an Orbitrap mass spectrometer. It was found that the ions with [M+14](+) were observed as the major ions (M: sample molecule). The exact mass analysis revealed that the ions are nitrogenated molecules, [M+N](+) formed by the reactions of N3 (+) with M. The reaction, N3 (+) + M → [M+N](+) + N2 , were examined by the density functional theory calculations. It was found that N3 (+) abstracts the H atom from hydrocarbon molecules leading to the formation of protonated imines in the forms of R'R″CNH2 (+) (i.e. C-H bond nitrogenation). This result is in accord with the fact that elimination of NH3 is the major channel for MS/MS of [M+N](+) . That is, nitrogen is incorporated in the C-H bonds of saturated hydrocarbons. No nitrogenation was observed for benzene and acetone, which was ascribed to the formation of stable charge-transfer complexes benzene⋅⋅⋅⋅N3 (+) and acetone⋅⋅⋅⋅N3 (+) revealed by density functional theory calculations. Copyright © 2016 John Wiley & Sons, Ltd. PMID:27270868

  2. Laboratory experiments for Titan's ionosphere : the chemistry of N2+, N+, and N2++ nitrogen ions

    NASA Astrophysics Data System (ADS)

    Thissen, R.; Alcaraz, C.; Dutuit, O.; Nicolas, C.; Soldi-Lose, H.; Zabka, J.; Franceschi, P.

    Laboratory experiments for Titan's ionosphere : the chemistry of N+ , N+ , and N2+ nitrogen ions 2 2 R. Thissen (1), C. Alcaraz (1), O. Dutuit (1), C. Nicolas (2), H. Soldi-Lose (3), J. Zabka (4), P. Franceschi (5) (1) LCP, Bât. 350, Centre Universitaire Paris-Sud, F-91405 Orsay Cedex, France, (2) Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin BP 48, 91192 Gif-sur-Yvette, France, (3) Institut für Chemie, Fachgruppe Organische Chemie, Technische Universität Berlin, Straße des 17. Juni 135, D-10623 Berlin, (4) J. Heyrovsky Institute of Physical Chemistry, Dolejskova 3, CZ 18223 Praha 8 - Kobylisy, Czech Republik, (5) Dept. of Physics, University of Trento, Via Sommarive 14, 38050 Povo (TN), Italy (christian.alcaraz@lcp.u-psud.fr) N2 is the major neutral componant of Titan's atmosphere, its ionisation by solar radiation and by magnetospheric electron impact is the most important production of ions in Titan's ionosphere. These primary processes not only lead to N+ molecular 2 monocations but also to N+ atomic ions and to N2+ molecular dications, which can 2 pertain some internal or translational excitation. This contribution will summarize our efforts to caracterize in gaz phase laboratory experiments the reactivity of the nitrogen ions with the most important neutral targets of the Titan's atmosphere [1-3]: • N+ + CH4 , C2 H2 , and C2 H6 2 • N+ (3 P, 1 D) + CH4 , and C2 H4 • N2+ + N2 , CH4 , and C2 H4 2 In this work, particular attention has been paid on the effect of internal and/or translational excitation of the primary nitrogen ions on the rate constant and branching ratio of these ion-molecule reactions. The results from these studies have been compared to the literature values when available and some significant differences have been found. These new values have been used as input data in 1D models of the Titan's ionosphere to show the effect on the final density profiles of the main ions [4] and to demonstrate the existence of a N2+2 dication

  3. Nitrogen- Doped Graphene Quantum Dots: "Turn-off" Fluorescent Probe for Detection of Ag(+) Ions.

    PubMed

    Tabaraki, Reza; Nateghi, Ashraf

    2016-01-01

    Highly luminescent nitrogen-doped graphene quantum dots (N-GQDs) were prepared from glucose and ammonia as carbon and nitrogen sources, respectively. The N-GQDs showed a strong emission at 458 nm with excitation at 360 nm. The N-GQDs exhibited analytical potential as sensing probes for silver ions determination. Factors affecting the fluorescence sensing of Ag(+) ions such as pH, N-GQDs concentration and incubation time were studied using Box-Behnken experimental design. The optimum conditions were determined as pH 7, N-GQDs concentration 1 mg/mL and time 60 min. It suggested that N-GQDs exhibited high sensitivity and selectivity toward Ag(+). The linear range of N-GQDs and the limit of detection (LOD) were 0.2-40 μM and 168 nM, respectively. The N-GQDs-based Ag(+) ions sensor was successfully applied to the determination of Ag(+) in tap water and real river water samples.

  4. Microstructure and oxidation behavior of high strength steel AISI 410 implanted with nitrogen ion

    NASA Astrophysics Data System (ADS)

    Bandriyana, Ismoyo, Agus Hadi; Sujitno, Tjipto; Dimyati, A.

    2016-04-01

    Surface treatment by implantation with nitrogen-ion was performed on the commercial feritic high strength steel AISI 410 which is termed for high temperature applications. The aim of this research was focused on the surface modification to improve its high temperature oxidation property in the early stages. Ion implantation was carried out at acceleration energy of 100 KeV and ion current 10 mA for 30, 60 and 90 minutes. The samples were subjected to the high temperature oxidation test by means of thermogravimetry in a magnetic suspension balance (MSB) at 500 °C for 5 hours. The scanning electron microscopy (SEM), X-ray diffraction spectrometry (XRD) and Vickers Hardness measurement were used for sample characterization. The formation of ferro-nitride phase after implantation did not occur, however a thin layer considered to contain nitrogen interstitials was detected. The oxidation of both samples before and after implantation followed parabolic kinetics indicating inward growth of oxide scale characteristically due to diffusion of oxygen anions towards matrix surface. After oxidation test relativelly stable oxide scales were observed. Oxidation rates decreased proportionally with the increasing of implantation time due to the formation of oxide layer which is considered to be effectiv inhibitor for the oxygen diffusion.

  5. Friction wear and auger analysis of iron implanted with 1.5-MeV nitrogen ions

    NASA Technical Reports Server (NTRS)

    Ferrante, J.; Jones, W. R., Jr.

    1982-01-01

    The effect of implantation of 1.5-MeV nitrogen ions on the friction and wear characteristics of pure iron sliding against steel was studied in a pin-on disk apparatus. An implantation dose of 5 x 10 to the 17th power ions/sq cm was used. Small reductions in initial and steady-state wear rates were observed for nitrogen-implanted iron riders as compared with unimplanted controls. Auger electron spectroscopy revealed a subsurface Gaussian nitrogen distribution with a maximum concentration of 15 at. % at a depth of 8 x 10 to the -7th m. A similar analysis within the wear scar of an implanted rider after 20 microns of wear yielded only background nitrogen concentration, thus giving no evidence for diffusion of nitrogen beyond the implanted range.

  6. RADIOLYSIS OF NITROGEN AND WATER-ICE MIXTURE BY FAST IONS: IMPLICATIONS FOR KUIPER BELT OBJECTS

    SciTech Connect

    Barros, A. L. F. de; Silveira, E. F da; Bergantini, A.; Rothard, H.; Boduch, P.

    2015-09-10

    The participation of condensed nitrogen in the surface chemistry of some objects in the outer solar system, such as Pluto and Triton, is very important. The remote observation of this species using absorption spectroscopy is a difficult task because N{sub 2} is not IR active in the gas phase. Water is also among the most abundant molecules in the surface of these objects; chemical reactions between N{sub 2} and H{sub 2}O induced by cosmic rays are therefore expected. Although pure N{sub 2} ice is hardly identified by IR spectroscopy, the species produced through the processing of the surface ice by cosmic rays may give relevant clues indicating how abundant the N{sub 2} is in the outside layers of the surface of trans-Neptunian objects (TNOs). The objective of this work is to investigate the formation of nitrogenated species induced by cosmic-ray analogs in an ice mixture containing nitrogen and water. Experiments were performed in the GANIL Laboratory by bombarding N{sub 2}:H{sub 2}O (10:1) ice at 15 K with 40 MeV {sup 58}Ni{sup 11+} ions. Evolution of precursor and daughter species was monitored by Fourier transform infrared spectrometry. The main produced species are the nitrogen oxides NO{sub k} (k = 1–3), N{sub 2}O{sub j} (j = 1–5), N{sub 3}, and O{sub 3}. Among them, the N{sub 2}O and N{sub 3} are the most abundant, representing ∼61% of the total column density of the daughter molecules at 10{sup 13} ions cm{sup −2} fluence; the current results indicate that the yield of daughter species from this mixture is low, and this may be one of the reasons why N{sub i}O{sub j} molecules are not usually observed in TNOs.

  7. Radiolysis of Nitrogen and Water-ice Mixture by Fast Ions: Implications for Kuiper Belt Objects

    NASA Astrophysics Data System (ADS)

    de Barros, A. L. F.; da Silveira, E. F.; Bergantini, A.; Rothard, H.; Boduch, P.

    2015-09-01

    The participation of condensed nitrogen in the surface chemistry of some objects in the outer solar system, such as Pluto and Triton, is very important. The remote observation of this species using absorption spectroscopy is a difficult task because N2 is not IR active in the gas phase. Water is also among the most abundant molecules in the surface of these objects; chemical reactions between N2 and H2O induced by cosmic rays are therefore expected. Although pure N2 ice is hardly identified by IR spectroscopy, the species produced through the processing of the surface ice by cosmic rays may give relevant clues indicating how abundant the N2 is in the outside layers of the surface of trans-Neptunian objects (TNOs). The objective of this work is to investigate the formation of nitrogenated species induced by cosmic-ray analogs in an ice mixture containing nitrogen and water. Experiments were performed in the GANIL Laboratory by bombarding N2:H2O (10:1) ice at 15 K with 40 MeV 58Ni11+ ions. Evolution of precursor and daughter species was monitored by Fourier transform infrared spectrometry. The main produced species are the nitrogen oxides NOk (k = 1-3), N2Oj (j = 1-5), N3, and O3. Among them, the N2O and N3 are the most abundant, representing ˜61% of the total column density of the daughter molecules at 1013 ions cm-2 fluence; the current results indicate that the yield of daughter species from this mixture is low, and this may be one of the reasons why NiOj molecules are not usually observed in TNOs.

  8. Influence of crystal orientation and ion bombardment on the nitrogen diffusivity in single-crystalline austenitic stainless steel

    SciTech Connect

    Martinavicius, A.; Abrasonis, G.; Moeller, W.

    2011-10-01

    The nitrogen diffusivity in single-crystalline AISI 316L austenitic stainless steel (ASS) during ion nitriding has been investigated at different crystal orientations ((001), (110), (111)) under variations of ion flux (0.3-0.7 mA cm{sup -2}), ion energy (0.5-1.2 keV), and temperature (370-430 deg. C). The nitrogen depth profiles obtained from nuclear reaction analysis are in excellent agreement with fits using the model of diffusion under the influence of traps, from which diffusion coefficients were extracted. At fixed ion energy and flux, the diffusivity varies by a factor up to 2.5 at different crystal orientations. At (100) orientation, it increases linearly with increasing ion flux or energy. The findings are discussed on the basis of atomistic mechanisms of interstitial diffusion, potential lattice distortions, local decomposition, and ion-induced lattice vibrational excitations.

  9. Influence of crystal orientation and ion bombardment on the nitrogen diffusivity in single-crystalline austenitic stainless steel

    NASA Astrophysics Data System (ADS)

    Martinavičius, A.; Abrasonis, G.; Möller, W.

    2011-10-01

    The nitrogen diffusivity in single-crystalline AISI 316L austenitic stainless steel (ASS) during ion nitriding has been investigated at different crystal orientations ((001), (110), (111)) under variations of ion flux (0.3-0.7 mA cm-2), ion energy (0.5-1.2 keV), and temperature (370-430 °C). The nitrogen depth profiles obtained from nuclear reaction analysis are in excellent agreement with fits using the model of diffusion under the influence of traps, from which diffusion coefficients were extracted. At fixed ion energy and flux, the diffusivity varies by a factor up to 2.5 at different crystal orientations. At (100) orientation, it increases linearly with increasing ion flux or energy. The findings are discussed on the basis of atomistic mechanisms of interstitial diffusion, potential lattice distortions, local decomposition, and ion-induced lattice vibrational excitations.

  10. Nitrogen

    USGS Publications Warehouse

    Kramer, D.A.

    2006-01-01

    In 2005, ammonia was produced by 15 companies at 26 plants in 16 states in the United States. Of the total ammonia production capacity, 55% was centered in Louisiana, Oklahoma and Texas because of their large reserves of natural gas. US producers operated at 66% of their rated capacity. In descending order, Koch Nitrogen, Terra Industries, CF Industries, Agrium and PCS Nitrogen accounted for 81% of the US ammonia production capacity.

  11. Radiative double electron capture (RDEC) by bare fluorine ions on a nitrogen target

    NASA Astrophysics Data System (ADS)

    Kumara, Nuwan; La Mantia, David; Kayani, Asghar; Simon, Anna; Tanis, John

    2016-05-01

    Unlike radiative electron capture (REC), in which a single photon is emitted due to capture of a single electron from the target to the projectile, radiative double electron capture (RDEC) involves two electrons accompanied by the emission of a single photon. Hence, RDEC can be considered as the inverse of double photoionization and used to study the role of electron correlation in causing the process. We report recent results obtained for 40 MeV F9+ ions incident on a nitrogen target, in which counts were observed in the calculated RDEC region (2.8-4.4 keV) for the system. Based on these observations an approximate value for the total RDEC cross section was estimated. Compared with the data obtained for 38 MeV O8+ ions incident on a carbon foil target, the present value is considerably smaller than the value found for carbon, but in better agreement with recent theory. Supported in part by NSF.

  12. [Electrooptical properties of soil nitrogen-fixing bacterium Azospirillum brasilense: effect of copper ions].

    PubMed

    Ignatov, O V; Kamnev, A A; Markina, L N; Antoniuk, L P; Kolina, M; Ignatov, V V

    2001-01-01

    The effects of copper ions on the uptake of some essential metals in the biomass and the electrooptical properties of cell suspensions of the nitrogen-fixing soil bacterium Azospirillum brasilense sp. 245 were studied. Copper cations were shown to be effectively taken up by the cell biomass from the culture medium. The addition of copper ions increased the rate of uptake of some other metals present in the culture medium. This was accompanied by changes in the electrooptical characteristics of cell suspension as measured within the orienting electric field frequency range of 10 to 10,000 kHz. The effects observed during short-term incubation of A. brasilense in the presence of copper cations were less significant than during long-term incubation. These results can be used for rapid screening of microbial cultures for enhanced efficiency of sorption and uptake of metals.

  13. Surface science studies on the interaction of nitrogen trifluoride ion beams and plasmas with silicon

    NASA Astrophysics Data System (ADS)

    Little, Thomas William

    As microelectronic dimensions continue to shrink, the role of plasma etching assumes greater importance. Recently, there has been considerable interest in using nitrogen trifluoride (NF3) to replace perfluorocarbon (PFC) etchants in some applications. Nitrogen trifluoride is capable of high etching rates, environmentally more tolerable than PFCs, and eliminates buildup of macroscopic carbonaceous surface layers. Literature exists on NF3 etch rate, selectivity and profiles during plasma etching, but very little has been done in the way of detailed surface science examinations of the interaction of NF3 with silicon (Si) surfaces. Scientifically, NF3 offers an ideal tool to probe the surface science of plasma-Si interaction during etching. Previous studies of fluorine (F) etching of Si have relied on either F2, atomic F, or an inert gas compound such as XeF2. The present work employs a gas in which both atoms (N, F) are chemically active, and is one of the first surface science examinations of NF3-Si interaction. Through the complementary use of ion beams and actual plasmas, the effects of ions and neutrals inherent in the plasma have been separated. X-ray photoelectron spectroscopy (XPS) shows that the neutrals are responsible for Si-F bonding while ions are incorporated in complex Si-N-F moieties. The results show for the first time that N is incorporated in Si during the initial stages of etching. Quantum mechanical calculations based on density functional theory (DFT) have been used to augment the XPS results. Finally, severe plasma etching produces anomalous XPS results which can be attributed to differential charging. Mechanistically, the charging is caused by ion bombardment damage during etching as evidenced by atomic force microscopy (AFM). The differential charging behavior has been studied, and it is suggested that the phenomenon may be utilized to quantify plasma etch damage.

  14. Biological effects of low energy nitrogen ion implantation on Jatropha curcas L. seed germination

    NASA Astrophysics Data System (ADS)

    Xu, Gang; Wang, Xiao-teng; Gan, Cai-ling; Fang, Yan-qiong; Zhang, Meng

    2012-09-01

    To explore the biological effects of nitrogen ion beam implantation on dry Jatropha curcas seed, a beam of N+ with energy of 25 keV was applied to treat the dry seed at six different doses. N+ beam implantation greatly decreased germination rate and seedling survival rate. The doses within the range of 12 × 1016 to 15 × 1016 ions cm-2 severely damaged the seeds: total antioxidant capacity (TAC), germination rate, seedling survival rate, reduced ascorbate acid (HAsA) and reduced glutathione (GSH) contents, and most of the tested antioxidases activity (i.e. catalase (CAT), ascorbate peroxidase (APX) and superoxide dismutase (SOD)) reached their lowest levels. At a dose of 18 × 1016 ion cm-2, biological repair took place: moderate increases were found in TAC, germination rate, seedling survival rate, HAsA and GSH contents, and some antioxidant enzyme activities (i.e. CAT, APX, SOD and GPX). The dose of 18 × 1016 ions cm-2 may be the optimum dose for use in dry J. curcas seed mutation breeding. CAT, HAsA and GSH contributed to the increase of TAC, but CAT was the most important. POD performed its important role as seed was severely damaged. The main role of the HAsA-GSH cycle appeared to be for regeneration of HAsA.

  15. Gas powered fluid gun with recoil mitigation

    DOEpatents

    Grubelich, Mark C; Yonas, Gerold

    2013-11-12

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  16. Gas powered fluid gun with recoil mitigation

    DOEpatents

    Grubelich, Mark C.; Yonas, Gerold

    2016-03-01

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  17. Photon Recoil Momentum in Dispersive Media

    SciTech Connect

    Campbell, Gretchen K.; Leanhardt, Aaron E.; Mun, Jongchul; Boyd, Micah; Streed, Erik W.; Ketterle, Wolfgang; Pritchard, David E.

    2005-05-06

    A systematic shift of the photon recoil momentum due to the index of refraction of a dilute gas of atoms has been observed. The recoil frequency was determined with a two-pulse light grating interferometer using near-resonant laser light. The results show that the recoil momentum of atoms caused by the absorption of a photon is n({Dirac_h}/2{pi})k, where n is the index of refraction of the gas and k is the vacuum wave vector of the photon. This systematic effect must be accounted for in high-precision atom interferometry with light gratings.

  18. Nitrogen

    USGS Publications Warehouse

    Apodaca, L.E.

    2012-01-01

    Ammonia was produced by 12 companies at 27 plants in 15 states in the United States during 2011. Sixty-one percent of total U.S. ammonia production capacity was centered in Louisiana, Oklahoma and Texas because of those states' large reserves of natural gas, the dominant domestic feedstock. In 2011, U.S. producers operated at about 84 percent of their rated capacity (excluding plants that were idle for the entire year). Four companies — CF Industries Holdings Inc.; Koch Nitrogen Co.; PCS Nitrogen Inc. and Agrium Inc., in descending order — accounted for 77 percent of the total U.S. ammonia production capacity.

  19. Nitrogen

    USGS Publications Warehouse

    Kramer, D.A.

    2004-01-01

    Ammonia is the principal source of fixed nitrogen. It was produced by 17 companies at 34 plants in the United States during 2003. Fifty-three percent of U.S. ammonia production capacity was centered in Louisiana, Oklahoma and Texas because of their large reserves of natural gas, the dominant domestic feedstock.

  20. Transport of Radioactive Material by Alpha Recoil

    SciTech Connect

    Icenhour, A.S.

    2005-05-19

    The movement of high-specific-activity radioactive particles (i.e., alpha recoil) has been observed and studied since the early 1900s. These studies have been motivated by concerns about containment of radioactivity and the protection of human health. Additionally, studies have investigated the potential advantage of alpha recoil to effect separations of various isotopes. This report provides a review of the observations and results of a number of the studies.

  1. Recoil by Auger electrons: Theory and application

    SciTech Connect

    Demekhin, Ph. V.; Scheit, S.; Cederbaum, L. S.

    2009-10-28

    General equations accounting for the molecular dynamics induced by the recoil of a fast Auger electron are presented. The implications of the degree of localization of the molecular orbitals of diatomic molecules involved in the Auger decay are analyzed. It is shown that the direct and exchange terms of the Auger transition matrix element may give rise to opposite signs and hence to opposite directions of the recoil momenta transferred to the nuclear vibrational motion. Consequently, these terms have a different impact on the recoil-induced nuclear dynamics in the final Auger decay state. The developed theory is applied to study the influence of the recoil on the interatomic Coulombic decay (ICD) following the K-LL Auger decay of the Ne dimer. Our calculations illustrate a significant effect of the recoil of nuclei on the computed wave packets propagating on the potential energy curve populated by the Auger decay. The corresponding final states of the Auger process decay further by ICD. We show that the recoil momentum imparted onto the nuclei modifies the computed ICD spectra considerably.

  2. Titanium and zirconium based alloys modified by intensive plastic deformation and nitrogen ion implantation for biocompatible implants.

    PubMed

    Byeli, A V; Kukareko, V A; Kononov, A G

    2012-02-01

    Titanium and zirconium alloys are considered to be promising materials for orthopaedics because of their biocompatibility with tissues. Their main drawbacks for application as implants have generally been considered to be insufficient levels of mechanical and tribological properties. In this research the influence of equal channel angular pressing and nitrogen ion implantation on the structure and properties of Ti and Zr alloys has been investigated to ensure the optimum combination of the bulk material and surface layer properties. The data obtained showed that equal channel angular pressing and nitrogen ion implantation can be efficiently used to improve bulk and surface properties of Ti and Zr based implants.

  3. Electronic transport and localization in nitrogen-doped graphene devices using hyperthermal ion implantation

    NASA Astrophysics Data System (ADS)

    Friedman, Adam L.; Cress, Cory D.; Schmucker, Scott W.; Robinson, Jeremy T.; van 't Erve, Olaf M. J.

    2016-04-01

    Hyperthermal ion implantation offers a controllable method of producing high-quality substitutionally doped graphene with nitrogen, an n -type dopant that has great potential for graphene electronics and spintronics applications where high carrier concentration, uniform doping, and minimal vacancy defect concentration is desired. Here we examine the transport properties of monolayer graphene sheets as a function of implantation beam energy and dose. We observe a transition from weak to strong localization that varies as a function of carrier concentration. For nominally equivalent doses, increased N ion energy results in an increasing magnetoresistance magnitude, reaching a value of approximately -5.5% at 5000 Oe, which we discuss in the context of dopant concentration and defect formation. We use a model for the temperature dependence of the conductivity that takes into account both temperature activation, due to the formation of a transport gap, and Mott variable-range hopping, due to the formation of defects, to further study the electronic properties of the doped films as a function of dose and N ion energy. We find that the temperature activation component dominates the behavior.

  4. Investigation of the ArN + 2 ion by dissociative ionization of argon/nitrogen clusters

    NASA Astrophysics Data System (ADS)

    Mähnert, Joachim; Baumgärtel, Helmut; Weitzel, Karl-Michael

    1995-01-01

    The ArN+2 ion has been investigated by means of photoionization of an argon/nitrogen cluster beam in a threshold photoelectron photoion coincidence experiment. Two pathways for the formation of ArN+2 ions have been observed: (i) the nondissociative ionization of ArN2 neutrals and (ii) the dissociative ionization of Ar2N2. The two pathways are distinguished by the kinetic energy released (KER) in the dissociative ionization. The KER for the reaction Ar2N+2→ArN+2+Ar has been measured as a function of the excitation energy. The comparison of the measured KER with the statistically expected KER allows us to extrapolate to the thermochemical threshold of the reaction under investigation. A consistent picture is obtained under two assumptions: (i) the ArN+2 ion is linear and (ii) the ionization potential of ArN2 is 14.486±0.05 eV. The former assumption is confirmed by high level ab initio calculations (QCISD/6-311G*).

  5. Measurement of Scintillation and Ionization Yield and Scintillation Pulse Shape from Nuclear Recoils in Liquid Argon

    DOE PAGESBeta

    Cao, H.

    2015-05-26

    We have measured the scintillation and ionization yield of recoiling nuclei in liquid argon as a function of applied electric field by exposing a dual-phase liquid argon time projection chamber (LAr-TPC) to a low energy pulsed narrow band neutron beam produced at the Notre Dame Institute for Structure and Nuclear Astrophysics. Liquid scintillation counters were arranged to detect and identify neutrons scattered in the TPC and to select the energy of the recoiling nuclei. We also report measurements of the scintillation yields for nuclear recoils with energies from 10.3 to 57.3 keV and for median applied electric fields from 0more » to 970 V/cm. For the ionization yields, we report measurements from 16.9 to 57.3 keV and for electric fields from 96.4 to 486 V/cm. Furthermore, we report the observation of an anticorrelation between scintillation and ionization from nuclear recoils, which is similar to the anticorrelation between scintillation and ionization from electron recoils. Assuming that the energy loss partitions into excitons and ion pairs from 83mKr internal conversion electrons is comparable to that from 207Bi conversion electrons, we obtained the numbers of excitons (Nex) and ion pairs (Ni) and their ratio (Nex/Ni) produced by nuclear recoils from 16.9 to 57.3 keV. Motivated by arguments suggesting direction sensitivity in LAr-TPC signals due to columnar recombination, a comparison of the light and charge yield of recoils parallel and perpendicular to the applied electric field is presented for the first time.« less

  6. Measurement of scintillation and ionization yield and scintillation pulse shape from nuclear recoils in liquid argon

    NASA Astrophysics Data System (ADS)

    Cao, H.; Alexander, T.; Aprahamian, A.; Avetisyan, R.; Back, H. O.; Cocco, A. G.; Dejongh, F.; Fiorillo, G.; Galbiati, C.; Grandi, L.; Guardincerri, Y.; Kendziora, C.; Lippincott, W. H.; Love, C.; Lyons, S.; Manenti, L.; Martoff, C. J.; Meng, Y.; Montanari, D.; Mosteiro, P.; Olvitt, D.; Pordes, S.; Qian, H.; Rossi, B.; Saldanha, R.; Sangiorgio, S.; Siegl, K.; Strauss, S. Y.; Tan, W.; Tatarowicz, J.; Walker, S.; Wang, H.; Watson, A. W.; Westerdale, S.; Yoo, J.; Scene Collaboration

    2015-05-01

    We have measured the scintillation and ionization yield of recoiling nuclei in liquid argon as a function of applied electric field by exposing a dual-phase liquid argon time projection chamber (LAr-TPC) to a low energy pulsed narrow band neutron beam produced at the Notre Dame Institute for Structure and Nuclear Astrophysics. Liquid scintillation counters were arranged to detect and identify neutrons scattered in the TPC and to select the energy of the recoiling nuclei. We report measurements of the scintillation yields for nuclear recoils with energies from 10.3 to 57.3 keV and for median applied electric fields from 0 to 970 V /cm . For the ionization yields, we report measurements from 16.9 to 57.3 keV and for electric fields from 96.4 to 486 V /cm . We also report the observation of an anticorrelation between scintillation and ionization from nuclear recoils, which is similar to the anticorrelation between scintillation and ionization from electron recoils. Assuming that the energy loss partitions into excitons and ion pairs from Krm83 internal conversion electrons is comparable to that from 207Bi conversion electrons, we obtained the numbers of excitons (Nex) and ion pairs (Ni) and their ratio (Nex/Ni ) produced by nuclear recoils from 16.9 to 57.3 keV. Motivated by arguments suggesting direction sensitivity in LAr-TPC signals due to columnar recombination, a comparison of the light and charge yield of recoils parallel and perpendicular to the applied electric field is presented for the first time.

  7. Measurement of Scintillation and Ionization Yield and Scintillation Pulse Shape from Nuclear Recoils in Liquid Argon

    SciTech Connect

    Cao, H.

    2015-05-26

    We have measured the scintillation and ionization yield of recoiling nuclei in liquid argon as a function of applied electric field by exposing a dual-phase liquid argon time projection chamber (LAr-TPC) to a low energy pulsed narrow band neutron beam produced at the Notre Dame Institute for Structure and Nuclear Astrophysics. Liquid scintillation counters were arranged to detect and identify neutrons scattered in the TPC and to select the energy of the recoiling nuclei. We also report measurements of the scintillation yields for nuclear recoils with energies from 10.3 to 57.3 keV and for median applied electric fields from 0 to 970 V/cm. For the ionization yields, we report measurements from 16.9 to 57.3 keV and for electric fields from 96.4 to 486 V/cm. Furthermore, we report the observation of an anticorrelation between scintillation and ionization from nuclear recoils, which is similar to the anticorrelation between scintillation and ionization from electron recoils. Assuming that the energy loss partitions into excitons and ion pairs from 83mKr internal conversion electrons is comparable to that from 207Bi conversion electrons, we obtained the numbers of excitons (Nex) and ion pairs (Ni) and their ratio (Nex/Ni) produced by nuclear recoils from 16.9 to 57.3 keV. Motivated by arguments suggesting direction sensitivity in LAr-TPC signals due to columnar recombination, a comparison of the light and charge yield of recoils parallel and perpendicular to the applied electric field is presented for the first time.

  8. Nitrogen

    USGS Publications Warehouse

    Kramer, D.A.

    2007-01-01

    Ammonia was produced by 15 companies at 25 plants in 16 states in the United States during 2006. Fifty-seven percent of U.S. ammonia production capacity was centered in Louisiana, Oklahoma and Texas because of their large reserves of natural gas, the dominant domestic feedstock. In 2006, U.S. producers operated at about 72 percent of their rated capacity (excluding plants that were idle for the entire year). Five companies, Koch Nitrogen, Terra Industries, CF Industries, PCS Nitro-gen, and Agrium, in descending order, accounted for 79 percent U.S. ammonia production capacity. The United States was the world's fourth-ranked ammonia producer and consumer following China, India and Russia. Urea, ammonium nitrate, ammonium phosphates, nitric acid and ammonium sulfate were the major derivatives of ammonia in the United States, in descending order of importance.

  9. Formation of nitrate and ammonium ions in titanium dioxide mediated photocatalytic degradation of organic compounds containing nitrogen atoms

    SciTech Connect

    Low, G.K.-C.; McEvoy, S.R.; Matthews, R.W. )

    1991-03-01

    The photocatalytic oxidation of a related series of primary, secondary, and tertiary amines and other nitrogen- and sulfur-containing organic compounds over a UV-illuminated film of TiO{sub 2} has been studied. The compounds were as follows: n-pentylamine, piperidine, pyridine, phenylalanine, desipramine, thioridazine, penicillamine, isosorbide dinitrate, 4-nitrocatechol, 2,4-dinitrophenol, cyclophosphamide, 5-fluorouracil, atrazine, ethylenediaminetetracetic acid, and tetrabutylammonium phosphate. Both ammonium and nitrate ions were formed. The relative concentration of the two ions depended on the nature of the nitrogen in a compound, but was also influenced by the illumination time and concentration of the solute. It was found that for n-pentylamine, piperidine and pyridine, the rate of formation of ammonium ions was n-pentylamine {much gt} pyridine > piperidine. The order of rates of nitrate formation was pyridine = piperidine {much gt} pentylamine. For n-pentylamine the rate of formation of ammonium ions was {approximately}100 times that of nitrate.

  10. Nitrogen

    USGS Publications Warehouse

    Apodaca, L.E.

    2010-01-01

    Ammonia was produced by 13 companies at 23 plants in 16 states during 2009. Sixty percent of all U.S. ammonia production capacity was centered in Louisiana. Oklahoma and Texas because of those states' large reserves of natural gas, the dominant domestic feedstock. In 2009, U.S. producers operated at about 83 percent of their rated capacity (excluding plants that were idle for the entire year). Five companies — Koch Nitrogen Co.; Terra Industries Inc.; CF Industries Inc.; PCS Nitrogen Inc. and Agrium Inc., in descending order — accounted for 80 percent of the total U.S. ammonia production capacity. U.S. production was estimated to be 7.7 Mt (8.5 million st) of nitrogen (N) content in 2009 compared with 7.85 Mt (8.65 million st) of N content in 2008. Apparent consumption was estimated to have decreased to 12.1 Mt (13.3 million st) of N, a 10-percent decrease from 2008. The United States was the world's fourth-ranked ammonia producer and consumer following China, India and Russia. Urea, ammonium nitrate, ammonium phosphates, nitric acid and ammonium sulfate were the major derivatives of ammonia in the United States, in descending order of importance.

  11. Understanding the Photoluminescence Mechanism of Nitrogen-Doped Carbon Dots by Selective Interaction with Copper Ions.

    PubMed

    Ganiga, Manjunatha; Cyriac, Jobin

    2016-08-01

    Doped fluorescent carbon dots (CDs) have drawn widespread attention because of their diverse applications and attractive properties. The present report focusses on the origin of photoluminescence in nitrogen-doped CDs (NCDs), which is unraveled by the interaction with Cu(2+) ions. Detailed spectroscopic and microscopic studies reveal that the broad steady-state photoluminescence emission of the NCDs originates from the direct recombination of excitons (high energy) and the involvement of defect states (low energy). In addition, highly selective detection of Cu(2+) is achieved, with a detection limit of 10 μm and a dynamic range of 10 μm-0.4 mm. The feasibility of the present sensor for the detection of Cu(2+) in real water samples is also presented. PMID:27159128

  12. Enhanced nitrogen and phosphorus removal from eutrophic lake water by Ipomoea aquatica with low-energy ion implantation.

    PubMed

    Li, Miao; Wu, Yue-Jin; Yu, Zeng-Liang; Sheng, Guo-Ping; Yu, Han-Qing

    2009-03-01

    Ipomoea aquatica with low-energy N+ ion implantation was used for the removal of both nitrogen and phosphorus from the eutrophic Chaohu Lake, China. The biomass growth, nitrate reductase and peroxidase activities of the implanted I. aquatica were found to be higher than those of I. aquatica without ion implantation. Higher NO3-N and PO4-P removal efficiencies were obtained for the I. aquatica irradiation at 25 keV, 3.9 x 10(16) N+ ions/cm(2) and 20 keV 5.2 x 10(16) N+ ions/cm(2), respectively (p < 0.05). Moreover, the nitrogen and phosphorus contents in the plant biomass with ion implantation were also greater than those of the controls. I. aquatica with ion implantation was directly responsible for 51-68% N removal and 54-71% P removal in the three experiments. The results further confirm that the ion implantation could enhance the growth potential of I. aquatica in real eutrophic water and increase its nutrient removal efficiency. Thus, the low-energy ion implantation for aquatic plants could be considered as an approach for in situ phytoremediation and bioremediation of eutrophic waters.

  13. The influence of nitrogen ion implantation on the tribological properties of piston rings made of Hardox and Raex steels

    NASA Astrophysics Data System (ADS)

    Budzyński, P.; Kamiński, M.; Pyszniak, K.

    2016-09-01

    The implantation of nitrogen, carbon, and oxygen can be used for enhancing the tribological properties of critical components for internal combustion engines. Hardox and Raex steels have very similar strength parameters as for steel used for piston rings in internal combustion engines. An essential criterion when selecting material for the production of piston rings is a low friction factor and a low wear index. The aim of this study was to determine the extent to which these parameters can be enhanced by nitrogen ion implantation. Samples were implanted with nitrogen ions with 65 keV energy and the fluence of implanted ions set to 1.1017 N + /cm2. Friction and wear measurements were performed on a pin-on disc stand. The results demonstrate that implantation with nitrogen ions significantly reduces the friction factor and wear of Hardox 450 and Raex 400 steels. Implantation can and should be used for enhancing the tribological properties of steel used for friction elements in internal combustion engines, particularly when heat treatment is excluded. Final elements can be subjected to implantation, as the process does not change their dimensions.

  14. Sensitivity of Nematode Life-History Groups to Ions and Osmotic Tensions of Nitrogenous Solutions

    PubMed Central

    Tenuta, Mario; Ferris, Howard

    2004-01-01

    Guild designation of nematodes of similar trophic function and life-history strategy provides a basis for using nematode faunal analyses in an integrative assessment of soil food web condition. Omnivorous and predaceous nematodes, categorized at the upper end of a colonizer-persister (c-p) continuum of nematode functional guilds are generally not abundant in cropped soil. These nematodes are more sensitive to heavy metal concentrations than those in other c-p groups, but whether sensitivity to agrochemicals contributes to the observed low abundance of high c-p groups in cropped soils is less well understood. An exposure assay in solution was used to compare the sensitivity of nematodes representing various guilds obtained from field soils and from laboratory culture to several nitrogen sources. Nematodes in c-p groups 4 and 5 were more sensitive to nitrogen solutions than nematodes representing lower c-p groups. There were both osmotic and specific ion effects—the latter most evident in exposure of nematodes to NaNO₂ and (NH₄)₂SO₄. The RC₅₀ (concentration resulting in nematode recovery of one half of that of distilled water) for (NH₄)₂SO₄ was < 0.052 M-N for c-p groups 4 and 5 compared to much greater values (0.34 to 0.81 M-N) for c-p groups 1 to 3. In non-ionic polyethylene glycol (PEG) solutions, osmotic tensions of 0.40 to 0.43 MPa reduced the recovery of exposed nematodes by half (RT₅₀; water potential of solution resulting in nematode recovery of one half of that of distilled water) for c-p groups 4 and 5 compared to > 1.93 MPa for c-p groups 1 to 3. RT₅₀ values for urea solutions, also non-ionic, were greater than for PEG. Caenorhabditis elegans N2 (c-p 1) and Meloidogyne javanica (c-p 3) reared on solid medium and in hydroponic culture, respectively, were slightly more sensitive to specific ion and osmotic effects than nematodes of similar c-p groups obtained from soil. The greater sensitivity of c-p 4 and 5 nematodes to nitrogen

  15. Nitrogen-doped carbon/graphene hybrid anode material for sodium-ion batteries with excellent rate capability

    NASA Astrophysics Data System (ADS)

    Liu, Huan; Jia, Mengqiu; Cao, Bin; Chen, Renjie; Lv, Xinying; Tang, Renjie; Wu, Feng; Xu, Bin

    2016-07-01

    Nitrogen-doped carbon/graphene (NCG) hybrid materials were prepared by an in-situ polymerization and followed pyrolysis for sodium-ion batteries. The NCG has a large interlayer distance (0.360 nm) and a high nitrogen content of 7.54 at%, resulting in a high reversible sodium storage capacity of 336 mAh g-1 at 30 mA g-1. The NCG shows a sandwich-like structure, i.e. nitrogen-doped carbon nanosheets closely coated on both sides of graphene. The carbon nanosheets shorten the ion diffusion distance, while the sandwiched graphene with high electronic conductivity guarantees fast electron transport, making the NCG exhibit excellent rate capability (94 mAh g-1 at 5 A g-1). It also exhibits good cycle stability with a capacity retention of 89% after 200 cycles at 50 mA g-1.

  16. Effects of nitrogen oxides, sulfur dioxide, and ferric ions on the corrosion of mild steel in concentrated sulfuric acid

    NASA Astrophysics Data System (ADS)

    Andersen, Terrell N.; Vanorden, Naola; Schlitt, W. Joseph

    1980-08-01

    Effects of nitrate ions, nitrous acid, sulfur dioxide, and ferric ions on the corrosion of mild steel in unstirred, concentrated sulfuric acid were determined in laboratory tests. Nitrate and nitrous acid at levels up to 1000 ppm accelerate corrosion. At concentrations greater than 1000 ppm nitrate passivates the steel. Sulfur dioxide and ferric ions have no detectable influence on the corrosion. Reaction mechanisms are presented to explain the observed effects. The impact of nitrogen oxides on the storage and handling of sulfide smelter by-product acid is discussed.

  17. Enhancement of nitrogen and phosphorus removal from eutrophic water by economic plant annual ryegrass (Lolium multiflorum) with ion implantation.

    PubMed

    Li, Miao; Sheng, Guo-ping; Wu, Yue-jin; Yu, Zeng-liang; Bañuelos, Gary S; Yu, Han-qing

    2014-01-01

    Severe eutrophication of surface water has been a major problem of increasing environmental concern worldwide. In the present study, economic plant annual ryegrass (Lolium multiflorum) was grown in floating mats as an economic plant-based treatment system to evaluate its potential after ion implantation for removing nutrients in simulated eutrophic water. The specific weight growth rate of L. multiflorum with ion implantation was significantly greater than that of the control, and the peroxidase, nitrate reductase, and acid phosphatase activities of the irradiated L. multiflorum were found to be greater than those plants without ion implantation. Higher total nitrogen (TN) and total phosphorus (TP) removal efficiencies were obtained for the L. multiflorum irradiated with 25 keV 5.2 × 10(16) N(+) ions/cm(2) and 30 keV 4.16 × 10(16) N(+) ions/cm(2), respectively (p < 0.05). Furthermore, the nitrogen and phosphorus contents in the plant biomass with ion implantation were also greater than those in the control and were positively correlated with TN and TP supplied. L. multiflorum itself was directly responsible for 39-49 and 47-58 % of the overall N and P removal in the experiment, respectively. The research results suggested that ion implantation could become a promising approach for increasing phytoremediation efficiency of nutrients from eutrophic water by L. multiflorum.

  18. Rutherford forward scattering and elastic recoil detection (RFSERD) as a method for characterizing ultra-thin films

    DOE PAGESBeta

    Lohn, Andrew J.; Doyle, Barney L.; Stein, Gregory J.; Mickel, Patrick R.; Stevens, Jim E.; Marinella, Matthew J.

    2014-04-03

    We present a novel ion beam analysis technique combining Rutherford forward scattering and elastic recoil detection (RFSERD) and demonstrate its ability to increase efficiency in determining stoichiometry in ultrathin (5-50 nm) films as compared to Rutherford backscattering. In the conventional forward geometries, scattering from the substrate overwhelms the signal from light atoms but in RFSERD, scattered ions from the substrate are ranged out while forward scattered ions and recoiled atoms from the thin film are simultaneously detected in a single detector. Lastly, the technique is applied to tantalum oxide memristors but can be extended to a wide range of materialsmore » systems.« less

  19. Rutherford forward scattering and elastic recoil detection (RFSERD) as a method for characterizing ultra-thin films

    SciTech Connect

    Lohn, Andrew J.; Doyle, Barney L.; Stein, Gregory J.; Mickel, Patrick R.; Stevens, Jim E.; Marinella, Matthew J.

    2014-04-03

    We present a novel ion beam analysis technique combining Rutherford forward scattering and elastic recoil detection (RFSERD) and demonstrate its ability to increase efficiency in determining stoichiometry in ultrathin (5-50 nm) films as compared to Rutherford backscattering. In the conventional forward geometries, scattering from the substrate overwhelms the signal from light atoms but in RFSERD, scattered ions from the substrate are ranged out while forward scattered ions and recoiled atoms from the thin film are simultaneously detected in a single detector. Lastly, the technique is applied to tantalum oxide memristors but can be extended to a wide range of materials systems.

  20. Effects of nitrogen ion implantation time on tungsten films deposited by DC magnetron sputtering on AISI 410 martensitic stainless steel

    NASA Astrophysics Data System (ADS)

    Malau, Viktor; Ilman, Mochammad Noer; Iswanto, Priyo Tri; Jatisukamto, Gaguk

    2016-03-01

    Nitrogen ion implantation time on tungsten thin film deposited on surface of AISI 410 steel has been performed. Tungsten thin film produced by dc magnetron sputtering method was deposited on AISI 410 martensitic stainless steel substrates, and then the nitrogen ions were implanted on tungsten thin film. The objective of this research is to investigate the effects of implantation deposition time on surface roughness, microhardness, specific wear and corrosion rate of nitrogen implanted on tungsten film. Magnetron sputtering process was performed by using plasma gas of argon (Ar) to bombardier tungsten target (W) in a vacuum chamber with a pressure of 7.6 x 10-2 torr, a voltage of 300 V, a sputter current of 80 mA for sputtered time of 10 minutes. Nitrogen implantation on tungsten film was done with an initial pressure of 3x10-6 mbar, a fluence of 2 x 1017 ions/cm2, an energy of 100 keV and implantation deposition times of 0, 20, 30 and 40 minutes. The surface roughness, microhardness, specific wear and corrosion rate of the films were evaluated by surfcorder test, Vickers microhardness test, wear test and potentiostat (galvanostat) test respectively. The results show that the nitrogen ions implanted deposition time on tungsten film can modify the surface roughness, microhardness, specific wear and corrosion rate. The minimum surface roughness, specific wear and corrosion rate can be obtained for implantation time of 20 minutes and the maximum microhardness of the film is 329 VHN (Vickers Hardness Number) for implantation time of 30 minutes. The specific wear and corrosion rate of the film depend directly on the surface roughness.

  1. The origin of the enhanced performance of nitrogen-doped MoS2 in lithium ion batteries.

    PubMed

    Liu, Qiuhong; Weijun, Xia; Wu, Zhenjun; Huo, Jia; Liu, Dongdong; Wang, Qiang; Wang, Shuangyin

    2016-04-29

    MoS2 with a similar layered structure to graphene has been widely applied in various areas including lithium ion batteries. However, low conductivity, capacity fading and poor rate performance are still the main challenges for MoS2 anode materials. In this work, for the first time, we prepared nitrogen-doped MoS2 (N-MoS2) nanosheets through a simple two-step method involving the preparation of MoS2 with defects by the hydrothermal method, followed by sintering in a NH3 atmosphere. Our electrochemical characterizations and density functional theory calculations demonstrated that nitrogen doping could enhance the electron conductivity and showed higher specific capacity than pristine MoS2 as anode materials of lithium ion batteries, which can be attributed to the faster transportation of electrons and ions because of nitrogen doping. This work helps us understand the origin of the enhanced performance of N-doped MoS2 in lithium ion batteries.

  2. Proton recoil scintillator neutron rem meter

    DOEpatents

    Olsher, Richard H.; Seagraves, David T.

    2003-01-01

    A neutron rem meter utilizing proton recoil and thermal neutron scintillators to provide neutron detection and dose measurement. In using both fast scintillators and a thermal neutron scintillator the meter provides a wide range of sensitivity, uniform directional response, and uniform dose response. The scintillators output light to a photomultiplier tube that produces an electrical signal to an external neutron counter.

  3. Atmospheric deposition of inorganic nitrogen in Spanish forests of Quercus ilex measured with ion-exchange resins and conventional collectors.

    PubMed

    García-Gomez, Héctor; Izquieta-Rojano, Sheila; Aguillaume, Laura; González-Fernández, Ignacio; Valiño, Fernando; Elustondo, David; Santamaría, Jesús M; Àvila, Anna; Fenn, Mark E; Alonso, Rocío

    2016-09-01

    Atmospheric nitrogen deposition is one of the main threats for biodiversity and ecosystem functioning. Measurement techniques like ion-exchange resin collectors (IECs), which are less expensive and time-consuming than conventional methods, are gaining relevance in the study of atmospheric deposition and are recommended to expand monitoring networks. In the present work, bulk and throughfall deposition of inorganic nitrogen were monitored in three different holm oak forests in Spain during two years. The results obtained with IECs were contrasted with a conventional technique using bottle collectors and with a literature review of similar studies. The performance of IECs in comparison with the conventional method was good for measuring bulk deposition of nitrate and acceptable for ammonium and total dissolved inorganic nitrogen. Mean annual bulk deposition of inorganic nitrogen ranged 3.09-5.43 kg N ha(-1) according to IEC methodology, and 2.42-6.83 kg N ha(-1) y(-1) using the conventional method. Intra-annual variability of the net throughfall deposition of nitrogen measured with the conventional method revealed the existence of input pulses of nitrogen into the forest soil after dry periods, presumably originated from the washing of dry deposition accumulated in the canopy. Important methodological recommendations on the IEC method and discussed, compiled and summarized.

  4. Amorphous Phosphorus/Nitrogen-Doped Graphene Paper for Ultrastable Sodium-Ion Batteries.

    PubMed

    Zhang, Chao; Wang, Xi; Liang, Qifeng; Liu, Xizheng; Weng, Qunhong; Liu, Jiangwei; Yang, Yijun; Dai, Zhonghua; Ding, Kejian; Bando, Yoshio; Tang, Jie; Golberg, Dmitri

    2016-03-01

    As the most promising anode material for sodium-ion batteries (SIBs), elemental phosphorus (P) has recently gained a lot of interest due to its extraordinary theoretical capacity of 2596 mAh/g. The main drawback of a P anode is its low conductivity and rapid structural degradation caused by the enormous volume expansion (>490%) during cycling. Here, we redesigned the anode structure by using an innovative methodology to fabricate flexible paper made of nitrogen-doped graphene and amorphous phosphorus that effectively tackles this problem. The restructured anode exhibits an ultrastable cyclic performance and excellent rate capability (809 mAh/g at 1500 mA/g). The excellent structural integrity of the novel anode was further visualized during cycling by using in situ experiments inside a high-resolution transmission electron microscope (HRTEM), and the associated sodiation/desodiation mechanism was also thoroughly investigated. Finally, density functional theory (DFT) calculations confirmed that the N-doped graphene not only contributes to an increase in capacity for sodium storage but also is beneficial in regards to improved rate performance of the anode.

  5. Amorphous Phosphorus/Nitrogen-Doped Graphene Paper for Ultrastable Sodium-Ion Batteries.

    PubMed

    Zhang, Chao; Wang, Xi; Liang, Qifeng; Liu, Xizheng; Weng, Qunhong; Liu, Jiangwei; Yang, Yijun; Dai, Zhonghua; Ding, Kejian; Bando, Yoshio; Tang, Jie; Golberg, Dmitri

    2016-03-01

    As the most promising anode material for sodium-ion batteries (SIBs), elemental phosphorus (P) has recently gained a lot of interest due to its extraordinary theoretical capacity of 2596 mAh/g. The main drawback of a P anode is its low conductivity and rapid structural degradation caused by the enormous volume expansion (>490%) during cycling. Here, we redesigned the anode structure by using an innovative methodology to fabricate flexible paper made of nitrogen-doped graphene and amorphous phosphorus that effectively tackles this problem. The restructured anode exhibits an ultrastable cyclic performance and excellent rate capability (809 mAh/g at 1500 mA/g). The excellent structural integrity of the novel anode was further visualized during cycling by using in situ experiments inside a high-resolution transmission electron microscope (HRTEM), and the associated sodiation/desodiation mechanism was also thoroughly investigated. Finally, density functional theory (DFT) calculations confirmed that the N-doped graphene not only contributes to an increase in capacity for sodium storage but also is beneficial in regards to improved rate performance of the anode. PMID:26928163

  6. Decay data measurements on 213Bi using recoil atoms.

    PubMed

    Marouli, M; Suliman, G; Pommé, S; Ammel, R Van; Jobbágy, V; Stroh, H; Dikmen, H; Paepen, J; Dirican, A; Bruchertseifer, F; Apostolidis, C; Morgenstern, A

    2013-04-01

    In this work, (213)Bi has been separated from an open (225)Ac source by collecting recoil atoms onto a glass plate in vacuum. The activity of such recoil sources has been measured as a function of time, using an ion-implanted planar Si detector in quasi-2π geometry. From these measurements, a new half-life value of T1/2((213)Bi)=45.62 (6)min was derived. Additionally, high-resolution alpha-spectrometry measurements were performed at a solid angle of 0.4% of 4πsr, to verify the energies and emission probabilities of the α-emissions from (213)Bi. Using (225)Ac, (221)Fr, (217)At and (213)Po peaks as reference peaks, the measured (213)Bi α-peak energies at Eα,0=5878 (4)keV and Eα,1=5560 (4)keV were about 10keV higher than validated data. The relative α-particle emission probabilities of (213)Bi, Pα,0=0.9155 (11) and Pα,1=0.0845 (11), and the (213)Bi alpha branching factor, Pα=1-Pβ=2.140 (10)%, are compatible with recommended values, but have a higher accuracy.

  7. Annealing Behavior of Ion-implanted Nitrogen in D9 Steel

    SciTech Connect

    Arunkumar, J.; David, C.; Nair, K. G. M.; Panigrahi, B. K.; Magudapathy, P.; Kennedy, John

    2011-07-15

    Nitrogen isotope N{sup 15} was implanted at the sub-surface of D9 steel. The resonance nuclear reaction analysis was used to probe the implanted nitrogen as a function of depth. The as-implanted D9 sample was isochronally annealed and by observing the broadening of nitrogen depth profile at various annealing junctures, activation energy for nitrogen diffusion in steel was deduced.

  8. Stabilization of temperature dependence of band Gap by introducing nitrogen ion into GaInNP alloy

    SciTech Connect

    Emura, Shuichi; Nonoguchi, Shogo; Kim, Kang Min

    2013-12-04

    The photoluminescence (PL) spectra of GaInNP are observed to survey the origin of the unique behavior of the band gap caused by incorporating nitrogen ions. The temperature dependence of the PL peak position is carefully analyzed. It is found that the reduction of the temperature alteration owing to the nitrogen incorporation arises from the hybridization between the nitrogen local 3s and 3p orbitals and the conduction band. In the GaInNP and host GaInP with the indium content around 50%, which has a direct band gap slightly lower than an X-valley, the band gap shrinkage with temperature is mediated by an LA phonon at X point.

  9. Changes in the structure and wear resistance of the surface layer of copper under treatment by nitrogen ion beams

    SciTech Connect

    Sergeev, Victor P. E-mail: kmp1980@mail.ru; Kalashnikov, Mark P. E-mail: kmp1980@mail.ru; Rybalko, Evgeniya V. E-mail: alfred-1972@mail.ru E-mail: zhastas@mail.ru; Sungatulin, Alfred R. E-mail: alfred-1972@mail.ru E-mail: zhastas@mail.ru; Sergeev, Oleg V. E-mail: alfred-1972@mail.ru E-mail: zhastas@mail.ru; Zharkov, Stanislav Yu. E-mail: alfred-1972@mail.ru E-mail: zhastas@mail.ru

    2014-11-14

    The structural-phase state of the treated sample surface was investigated by TEM. It was shown by the TEM and VIMS method that the improvement of tribological properties of the copper samples can be associated with an increase of relaxation ability due to a significant increase of the nitrogen concentration in it, which is accompanied by the refinement of fcc-Cu main phase grain structure and the formation of nanopores or gas bubbles in the ion-modified surface layer. A high-dose implantation of nitrogen ions and copper samples increases the wear resistance in 1.5-4.5 times together with a counterbody from the same material in the argon environment. The microhardness of the copper samples also increases.

  10. Highly crystalline lithium titanium oxide sheets coated with nitrogen-doped carbon enable high-rate lithium-ion batteries.

    PubMed

    Han, Cuiping; He, Yan-Bing; Li, Baohua; Li, Hongfei; Ma, Jun; Du, Hongda; Qin, Xianying; Yang, Quan-Hong; Kang, Feiyu

    2014-09-01

    Sheets of Li4Ti5O12 with high crystallinity are coated with nitrogen-doped carbon (NC-LTO) using a controlled process, comprising hydrothermal reaction followed by chemical vapor deposition (CVD). Acetonitrile (CH3 CN) vapor is used as carbon and nitrogen source to obtain a thin coating layer of nitrogen-doped carbon. The layer enables the NC-LTO material to maintain its sheet structure during the high-temperature CVD process and to achieve high crystallinity. Doping with nitrogen introduces defects into the carbon coating layer, and this increased degree of disorder allows fast transportation of lithium ions in the layer. An electrode of NC-LTO synthesized at 700 °C exhibits greatly improved rate and cycling performance due to a markedly decreased total cell resistance and enhanced Li-ion diffusion coefficient (D(Li)). Specific capacities of 159.2 and 145.8 mA h g(-1) are obtained using the NC-LTO sheets, at charge/discharge rates of 1 and 10 C, respectively. These values are much higher than values for LTO particles did not undergo the acetonitrile CVD treatment. A capacity retention value as high as 94.7% is achieved for the NC-LTO sheets after 400 cycles in a half-cell at 5 C discharge rate.

  11. Recoil Based Fuel Breeding Fuel Structure

    SciTech Connect

    Popa-Simil, Liviu

    2008-07-01

    Nuclear transmutation reactions are based on the absorption of a smaller particle as neutron, proton, deuteron, alpha, etc. The resulting compound nucleus gets out of its initial lattice mainly by taking the recoil, also with help from its sudden change in chemical properties. The recoil implantation is used in correlation with thin and ultra thin materials mainly for producing radiopharmaceuticals and ultra-thin layer radioactive tracers. In nuclear reactors, the use of nano-particulate pellets could facilitate the recoil implantation for breeding, transmutation and partitioning purposes. Using enriched {sup 238}U or {sup 232}Th leads to {sup 239}Pu and {sup 233}U production while using other actinides as {sup 240}Pu, {sup 241}Am etc. leads to actinide burning. When such a lattice is immersed into a radiation resistant fluid (water, methanol, etc.), the recoiled product is transferred into the flowing fluid and removed from the hot area using a concentrator/purifier, preventing the occurrence of secondary transmutation reactions. The simulation of nuclear collision and energy transfer shows that the impacted nucleus recoils in the interstitial space creating a defect or lives small lattices. The defect diffuses, and if no recombination occurs it stops at the lattices boundaries. The nano-grains are coated in thin layer to get a hydrophilic shell to be washed by the collection liquid the particle is immersed in. The efficiency of collection depends on particle magnitude and nuclear reaction channel parameters. For {sup 239}Pu the direct recoil extraction rate is about 70% for {sup 238}UO{sub 2} grains of 5 nm diameters and is brought up to 95% by diffusion due to {sup 239}Neptunium incompatibility with Uranium dioxide lattice. Particles of 5 nm are hard to produce so a structure using particles of 100 nm have been tested. The particles were obtained by plasma sputtering in oxygen atmosphere. A novel effect as nano-cluster radiation damage robustness and cluster

  12. Mechanical properties of nitrogen-rich surface layers on SS304 treated by plasma immersion ion implantation

    NASA Astrophysics Data System (ADS)

    Fernandes, B. B.; Mändl, S.; Oliveira, R. M.; Ueda, M.

    2014-08-01

    The formation of hard and wear resistant surface regions for austenitic stainless steel through different nitriding and nitrogen implantation processes at intermediate temperatures is an established technology. As the inserted nitrogen remains in solid solution, an expanded austenite phase is formed, accounting for these surface improvements. However, experiments on long-term behavior and exact wear processes within the expanded austenite layer are still missing. Here, the modified layers were produced using plasma immersion ion implantation with nitrogen gas and had a thickness of up to 4 μm, depending on the processing temperature. Thicker layers or those with higher surface nitrogen contents presented better wear resistance, according to detailed microscopic investigation on abrasion, plastic deformation, cracking and redeposition of material inside the wear tracks. At the same time, cyclic fatigue testing employing a nanoindenter equipped with a diamond ball was carried out at different absolute loads and relative unloadings. As the stress distribution between the modified layer and the substrate changes with increasing load, additional simulations were performed for obtaining these complex stress distributions. While high nitrogen concentration and/or thicker layers improve the wear resistance and hardness, these modifications simultaneously reduce the surface fatigue resistance.

  13. Simultaneous determination of total nitrogen and total phosphorus in environmental waters using alkaline persulfate digestion and ion chromatography.

    PubMed

    De Borba, Brian M; Jack, Richard F; Rohrer, Jeffrey S; Wirt, Joan; Wang, Dongmei

    2014-11-21

    An ion chromatography (IC) method was developed for the simultaneous determination of total nitrogen and total phosphorus after alkaline persulfate digestion. This study takes advantage of advances in construction of high-resolution, high-capacity anion-exchange columns that can better tolerate the matrices typically encountered when a determination of total nitrogen and total phosphorous is required. Here, we used an electrolytically generated hydroxide eluent combined with a high-capacity, hydroxide-selective, anion-exchange column for the determination of total nitrogen (as nitrate-N) and total phosphorus (as phosphate-P) in environmental samples by IC. This method yielded LODs for nitrate-N and phosphate-P of 1.0 and 1.3 μg/L, respectively. The LOQs determined for these analytes were 3.4 and 4.2 μg/L, respectively. Due to the dilution factor required and the blank nitrate-N concentration after the persulfate digestion, the quantification limits increased for nitrate-N and phosphate-P to 171 and 63 μg/L, respectively. The suitability of the method was evaluated by determining the nitrogen and phosphorus concentrations from known concentrations of organic-containing nitrogen and phosphorus compounds. In addition, environmental samples consisting of six different wastewaters and 48 reservoir samples were evaluated for total nitrogen and phosphorus. The recoveries of nitrogen and phosphorus from the organic-containing compounds ranged from 93.1 to 100.1% and 85.2 to 97.1%, respectively. In addition, good correlation between results obtained by the colorimetric method and IC was also observed. The linearity, accuracy, and evaluation of potential interferences for determining TN and TP will be discussed.

  14. Simultaneous determination of total nitrogen and total phosphorus in environmental waters using alkaline persulfate digestion and ion chromatography.

    PubMed

    De Borba, Brian M; Jack, Richard F; Rohrer, Jeffrey S; Wirt, Joan; Wang, Dongmei

    2014-11-21

    An ion chromatography (IC) method was developed for the simultaneous determination of total nitrogen and total phosphorus after alkaline persulfate digestion. This study takes advantage of advances in construction of high-resolution, high-capacity anion-exchange columns that can better tolerate the matrices typically encountered when a determination of total nitrogen and total phosphorous is required. Here, we used an electrolytically generated hydroxide eluent combined with a high-capacity, hydroxide-selective, anion-exchange column for the determination of total nitrogen (as nitrate-N) and total phosphorus (as phosphate-P) in environmental samples by IC. This method yielded LODs for nitrate-N and phosphate-P of 1.0 and 1.3 μg/L, respectively. The LOQs determined for these analytes were 3.4 and 4.2 μg/L, respectively. Due to the dilution factor required and the blank nitrate-N concentration after the persulfate digestion, the quantification limits increased for nitrate-N and phosphate-P to 171 and 63 μg/L, respectively. The suitability of the method was evaluated by determining the nitrogen and phosphorus concentrations from known concentrations of organic-containing nitrogen and phosphorus compounds. In addition, environmental samples consisting of six different wastewaters and 48 reservoir samples were evaluated for total nitrogen and phosphorus. The recoveries of nitrogen and phosphorus from the organic-containing compounds ranged from 93.1 to 100.1% and 85.2 to 97.1%, respectively. In addition, good correlation between results obtained by the colorimetric method and IC was also observed. The linearity, accuracy, and evaluation of potential interferences for determining TN and TP will be discussed. PMID:25441080

  15. Hemocompatibility of nitrogen-doped, hydrogen-free diamond-like carbon prepared by nitrogen plasma immersion ion implantation-deposition.

    PubMed

    Kwok, Sunny C H; Yang, Ping; Wang, Jin; Liu, Xuanyong; Chu, Paul K

    2004-07-01

    Amorphous hydrogenated carbon (a-C:H) has been shown to be a potential material in biomedical devices such as artificial heart valves, bone implants, and so on because of its chemical inertness, low coefficient of friction, high wear resistance, and good biocompatibility. However, the biomedical characteristics such as blood compatibility of doped hydrogen-free diamond-like carbon (DLC) have not been investigated in details. We recently began to investigate the potential use of nitrogen-doped, hydrogen-free DLC in artificial heart valves. In our experiments, a series of hydrogen-free DLC films doped with nitrogen were synthesized by plasma immersion ion implantation-deposition (PIII-D) utilizing a pulsed vacuum arc plasma source and different N to Ar (FN/FAr) gas mixtures in the plasma chamber. The structures and properties of the film were evaluated by Raman spectroscopy, Rutherford backscattering spectrometry (RBS), and X-ray photoelectron spectroscopy (XPS). To assess the blood compatibility of the films and the impact on the blood compatibility by the presence of nitrogen, platelet adhesion tests were conducted. Our results indicate that the blood compatibility of both hydrogen-free carbon films (a-C) and amorphous carbon nitride films are better than that of low-temperature isotropic pyrolytic carbon (LTIC). The experimental results are consistent with the relative theory of interfacial energy and surface tension including both dispersion and polar components. Our results also indicate that an optimal fraction of sp2 bonding is desirable, but an excessively high nitrogen concentration degrades the properties to an extent that the biocompatibility can be worse than that of LTIC.

  16. Radiative properties of molecular nitrogen ions produced by helium Penning ionization and argon effects

    NASA Technical Reports Server (NTRS)

    Miller, George, III; Song, Kyo-Dong

    1994-01-01

    The development of hypersonic aerospace vehicles requires a better understanding on the thermal and chemical nonequilibrium kinetics of participating species in shock layers. The computational fluid dynamic (CFD) codes developed for such flowfields overestimate the radiation in the spectral region of 300 - 600 nm. A speculation for this overestimation is that inclusion of Ar, CO2, and H2O at the upper atmosphere flight region makes a significant impact on radiative kinetics of molecular nitrogen ions. To define the effects of minority species on the radiative kinetics of N2(+), an experimental setup was made by using the helium Penning ionization. The vibrational and rotational temperature were measured by mapping the vibrational and rotational distributions of N2(+) emission with high spectroscopic resolution and absolute intensity measurements. Measured vibrational temperatures were in the range from 18,000 to 36,000 K, and rotational temperatures were in the range from 300 to 370 K. The irradiance of 391.44 nm line and rotational and vibrational temperatures were analyzed to define argon and CO2 effects on the N2(+) emission. When Ar or CO2 is injected with N2, the rotational temperature did not change. The irradiances were reduced by 34 percent and 78 percent for the 50 percent of mixture of Ar and CO2, respectively. The vibrational temperatures were increased by 24.1 percent and 82.9 percent for the 50 percent of mixture of Ar and CO2, respectively. It appears that there are no significant effects from small concentrations of Ar and CO2 at the upper atmosphere flight region.

  17. α -decay chains of recoiled superheavy nuclei: A theoretical study

    NASA Astrophysics Data System (ADS)

    Niyti, Sawhney, Gudveen; Sharma, Manoj K.; Gupta, Raj K.

    2015-05-01

    A systematic theoretical study of α -decay half-lives in the superheavy mass region of the periodic table of elements is carried out by extending the quantum-mechanical fragmentation theory based on the preformed cluster model (PCM) to include temperature (T ) dependence in its built-in preformation and penetration probabilities of decay fragments. Earlier, the α -decay chains of the isotopes of Z =115 were investigated by using the standard PCM for spontaneous decays, with"hot-optimum" orientation effects included, which required a constant scaling factor of 104 to approach the available experimental data. In the present approach of the PCM (T ≠0 ), the temperature effects are included via the recoil energy of the residual superheavy nucleus (SHN) left after x -neutron emission from the superheavy compound nucleus. The important result is that the α -decay half-lives calculated by the PCM (T ≠0 ) match the experimental data nearly exactly, without using any scaling factor of the type used in the PCM. Note that the PCM (T ≠0 ) is an equivalent of the dynamical cluster-decay model for heavy-ion collisions at angular momentum ℓ =0 . The only parameter of model is the neck-length parameter Δ R , which for the calculated half-lives of α -decay chains of various isotopes of Z =113 to 118 nuclei formed in "hot-fusion" reactions is found to be nearly constant, i.e., Δ R ≈0.95 ±0.05 fm for all the α -decay chains studied. The use of recoiled residue nucleus as a secondary heavy-ion beam for nuclear reactions has also been suggested in the past.

  18. RELATIVISTIC SUPPRESSION OF BLACK HOLE RECOILS

    SciTech Connect

    Kesden, Michael; Sperhake, Ulrich; Berti, Emanuele

    2010-06-01

    Numerical-relativity simulations indicate that the black hole produced in a binary merger can recoil with a velocity up to v {sub max} {approx_equal} 4000 km s{sup -1} with respect to the center of mass of the initial binary. This challenges the paradigm that most galaxies form through hierarchical mergers, yet retain supermassive black holes (SBHs) at their centers despite having escape velocities much less than v {sub max}. Interaction with a circumbinary disk can align the binary black hole spins with their orbital angular momentum, reducing the recoil velocity of the final black hole produced in the subsequent merger. However, the effectiveness of this alignment depends on highly uncertain accretion flows near the binary black holes. In this paper, we show that if the spin S {sub 1} of the more massive binary black hole is even partially aligned with the orbital angular momentum L, relativistic spin precession on sub-parsec scales can align the binary black hole spins with each other. This alignment significantly reduces the recoil velocity even in the absence of gas. For example, if the angle between S {sub 1} and L at large separations is 10{sup 0} while the second spin S {sub 2} is isotropically distributed, the spin alignment discussed in this paper reduces the median recoil from 864 km s{sup -1} to 273 km s{sup -1} for maximally spinning black holes with a mass ratio of 9/11. This reduction will greatly increase the fraction of galaxies retaining their SBHs.

  19. Response of GaN to energetic ion irradiation: conditions for ion track formation

    NASA Astrophysics Data System (ADS)

    Karlušić, M.; Kozubek, R.; Lebius, H.; Ban-d'Etat, B.; Wilhelm, R. A.; Buljan, M.; Siketić, Z.; Scholz, F.; Meisch, T.; Jakšić, M.; Bernstorff, S.; Schleberger, M.; Šantić, B.

    2015-08-01

    We investigated the response of wurzite GaN thin films to energetic ion irradiation. Both swift heavy ions (92 MeV Xe23+, 23 MeV I6+) and highly charged ions (100 keV Xe40+) were used. After irradiation, the samples were investigated using atomic force microscopy, grazing incidence small angle x-ray scattering, Rutherford backscattering spectroscopy in channelling orientation and time of flight elastic recoil detection analysis. Only grazing incidence swift heavy ion irradiation induced changes on the surface of the GaN, when the appearance of nanoholes is accompanied by a notable loss of nitrogen. The results are discussed in the framework of the thermal spike model.

  20. One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries

    PubMed Central

    Xing, Zheng; Ju, Zhicheng; Zhao, Yulong; Wan, Jialu; Zhu, Yabo; Qiang, Yinghuai; Qian, Yitai

    2016-01-01

    Nitrogen-doped (N-doped) graphene has been prepared by a simple one-step hydrothermal approach using hexamethylenetetramine (HMTA) as single carbon and nitrogen source. In this hydrothermal process, HMTA pyrolyzes at high temperature and the N-doped graphene subsequently self-assembles on the surface of MgO particles (formed by the Mg powder reacting with H2O) during which graphene synthesis and nitrogen doping are simultaneously achieved. The as-synthesized graphene with incorporation of nitrogen groups possesses unique structure including thin layer thickness, high surface area, mesopores and vacancies. These structural features and their synergistic effects could not only improve ions and electrons transportation with nanometer-scale diffusion distances but also promote the penetration of electrolyte. The N-doped graphene exhibits high reversible capacity, superior rate capability as well as long-term cycling stability, which demonstrate that the N-doped graphene with great potential to be an efficient electrode material. The experimental results provide a new hydrothermal route to synthesize N-doped graphene with potential application for advanced energy storage, as well as useful information to design new graphene materials. PMID:27184859

  1. One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries

    NASA Astrophysics Data System (ADS)

    Xing, Zheng; Ju, Zhicheng; Zhao, Yulong; Wan, Jialu; Zhu, Yabo; Qiang, Yinghuai; Qian, Yitai

    2016-05-01

    Nitrogen-doped (N-doped) graphene has been prepared by a simple one-step hydrothermal approach using hexamethylenetetramine (HMTA) as single carbon and nitrogen source. In this hydrothermal process, HMTA pyrolyzes at high temperature and the N-doped graphene subsequently self-assembles on the surface of MgO particles (formed by the Mg powder reacting with H2O) during which graphene synthesis and nitrogen doping are simultaneously achieved. The as-synthesized graphene with incorporation of nitrogen groups possesses unique structure including thin layer thickness, high surface area, mesopores and vacancies. These structural features and their synergistic effects could not only improve ions and electrons transportation with nanometer-scale diffusion distances but also promote the penetration of electrolyte. The N-doped graphene exhibits high reversible capacity, superior rate capability as well as long-term cycling stability, which demonstrate that the N-doped graphene with great potential to be an efficient electrode material. The experimental results provide a new hydrothermal route to synthesize N-doped graphene with potential application for advanced energy storage, as well as useful information to design new graphene materials.

  2. Determination of trace amounts of nitrogen in uranium based samples by ion chromatography (IC) without Kjeldahl distillation.

    PubMed

    Verma, Poonam; Rastogi, Ramakant K; Ramakumar, Karanam L

    2007-07-23

    A simple, sensitive and fast ion chromatographic (IC) method with suppressed conductivity detection is described for the determination of traces of nitrogen in uranium based fuel materials. Initially a method was developed to determine nitrogen as NH4(+) using cation exchange column after matrix separation by Kjeldahl distillation. The method was then improved by eliminating this distillation. Matrix separation after sample dissolution was done by hydrolyzing and filtering off the polyvalent cations. This had helped in reducing both the sample size and analysis time. Optimization of dissolution conditions for various kinds of uranium based samples was done to keep acid content minimum; a prerequisite chromatographic condition. The calibration plot for nitrogen was linear in the concentration range of 0.02-1 mg L(-1) with regression coefficient of 0.9999. The relative standard deviation (R.S.D.) obtained in this method (100 microL injected) was 3% and 2% in 9 replicates at nitrogen level of 28 and 55 ng g(-1), respectively. Detection limit based on S/N=3 (100 microL injected) as well as three times of variation in blank value was 4 ng g(-1). The developed method was authenticated by comparison with certified uranium-alloy standard as well as with independent indophenol photometry method. The developed method was applied to uranium-alloy, uranium-metal, sintered UO2 pellets and sintered UO2 microspheres samples.

  3. One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries.

    PubMed

    Xing, Zheng; Ju, Zhicheng; Zhao, Yulong; Wan, Jialu; Zhu, Yabo; Qiang, Yinghuai; Qian, Yitai

    2016-01-01

    Nitrogen-doped (N-doped) graphene has been prepared by a simple one-step hydrothermal approach using hexamethylenetetramine (HMTA) as single carbon and nitrogen source. In this hydrothermal process, HMTA pyrolyzes at high temperature and the N-doped graphene subsequently self-assembles on the surface of MgO particles (formed by the Mg powder reacting with H2O) during which graphene synthesis and nitrogen doping are simultaneously achieved. The as-synthesized graphene with incorporation of nitrogen groups possesses unique structure including thin layer thickness, high surface area, mesopores and vacancies. These structural features and their synergistic effects could not only improve ions and electrons transportation with nanometer-scale diffusion distances but also promote the penetration of electrolyte. The N-doped graphene exhibits high reversible capacity, superior rate capability as well as long-term cycling stability, which demonstrate that the N-doped graphene with great potential to be an efficient electrode material. The experimental results provide a new hydrothermal route to synthesize N-doped graphene with potential application for advanced energy storage, as well as useful information to design new graphene materials.

  4. One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries.

    PubMed

    Xing, Zheng; Ju, Zhicheng; Zhao, Yulong; Wan, Jialu; Zhu, Yabo; Qiang, Yinghuai; Qian, Yitai

    2016-01-01

    Nitrogen-doped (N-doped) graphene has been prepared by a simple one-step hydrothermal approach using hexamethylenetetramine (HMTA) as single carbon and nitrogen source. In this hydrothermal process, HMTA pyrolyzes at high temperature and the N-doped graphene subsequently self-assembles on the surface of MgO particles (formed by the Mg powder reacting with H2O) during which graphene synthesis and nitrogen doping are simultaneously achieved. The as-synthesized graphene with incorporation of nitrogen groups possesses unique structure including thin layer thickness, high surface area, mesopores and vacancies. These structural features and their synergistic effects could not only improve ions and electrons transportation with nanometer-scale diffusion distances but also promote the penetration of electrolyte. The N-doped graphene exhibits high reversible capacity, superior rate capability as well as long-term cycling stability, which demonstrate that the N-doped graphene with great potential to be an efficient electrode material. The experimental results provide a new hydrothermal route to synthesize N-doped graphene with potential application for advanced energy storage, as well as useful information to design new graphene materials. PMID:27184859

  5. Automation of experiments at Dubna Gas-Filled Recoil Separator

    NASA Astrophysics Data System (ADS)

    Tsyganov, Yu. S.

    2016-01-01

    Approaches to solving the problems of automation of basic processes in long-term experiments in heavy ion beams of the Dubna Gas-Filled Recoil Separator (DGFRS) facility are considered. Approaches in the field of spectrometry, both of rare α decays of superheavy nuclei and those for constructing monitoring systems to provide accident-free experiment running with highly radioactive targets and recording basic parameters of experiment, are described. The specific features of Double Side Silicon Strip Detectors (DSSSDs) are considered, special attention is paid to the role of boundary effects of neighboring p-n transitions in the "active correlations" method. An example of an off-beam experiment attempting to observe Zeno effect is briefly considered. Basic examples for nuclear reactions of complete fusion at 48Ca ion beams of U-400 cyclotron (LNR, JINR) are given. A scenario of development of the "active correlations" method for the case of very high intensity beams of heavy ions at promising accelerators of LNR, JINR, is presented.

  6. Reaction mechanisms in the system {sup 20}Ne+{sup 165}Ho: Measurement and analysis of forward recoil range distributions

    SciTech Connect

    Singh, D.; Ali, R.; Ansari, M. Afzal; Rashid, M. H.; Guin, R.; Das, S. K.

    2009-05-15

    Keeping in view the study of complete and incomplete fusion of heavy ions with a target, the forward recoil range distributions of several evaporation residues produced at 164 MeV {sup 20}Ne-ion beam energy have been measured for the system {sup 20}Ne+{sup 165}Ho. The recoil catcher activation technique followed by off-line gamma spectroscopy has been employed. Measured forward recoil range distributions of these evaporation residues show evidence of several incomplete fusion channels in addition to complete fusion. The entire and partial linear momentum transfers inferred from these recoil range distributions were used to identify the evaporation residues formed by complete and incomplete fusion mechanisms. The results indicate the occurrence of incomplete fusion involving the breakup of {sup 20}Ne into {sup 4}He+{sup 16}O and/or {sup 8}Be+{sup 12}C followed by fusion of one of the fragments with target nucleus {sup 165}Ho. Complete and incomplete fusion reaction channels have been identified in the production of various evaporation residues and an attempt has been made to separate out relative contributions of complete and incomplete fusion components from the analysis of the measured recoil range distribution data. The total contribution of complete and incomplete fusion channels has also been estimated.

  7. Nitrogen-doped porous carbon derived from metal-organic gel for electrochemical analysis of heavy-metal ion.

    PubMed

    Cui, Lin; Wu, Jie; Ju, Huangxian

    2014-09-24

    A nitrogen-doped porous carbon material (N@MOG-C) was prepared by simple pyrolysis of polypyrrole-doped Al-based metal-organic gel (PPy@MOG) at 800 °C. The N@MOG-C possessed a uniform three-dimensional (3-D) interconnected mesoporous structure with a high surface area of 1542.6 m(2) g(-1) and a large pore volume of 0.76 cm(3) g(-1). By using an ionic liquid (IL) to immobilize N@MOG-C on electrode surface, the N@MOG-C was further used for sensitive detection of heavy metal ion. The doping of nitrogen-endowed N@MOG-C with faster electron transfer kinetics than other carbon materials such as MOG-C, multiwalled carbon nanotubes, and graphene. The N@MOG-C-modified electrode showed a high effective area, because of the porous structure. Under optimized conditions, the N@MOG-C-based sensor could detect Cd ions present in concentrations of 0.025-5 μM, with a detection limit of 2.2 nM. The mesoporous structure, fast electron transfer ability, and simple and green synthesis of N@MOG-C made it a promising electrode material for practical applications in heavy-metal-ion sensing.

  8. Determination of Ni Release in NiTi SMA with Surface Modification by Nitrogen Plasma Immersion Ion Implantation

    NASA Astrophysics Data System (ADS)

    de Camargo, Eliene Nogueira; Oliveira Lobo, Anderson; Silva, Maria Margareth Da; Ueda, Mario; Garcia, Edivaldo Egea; Pichon, Luc; Reuther, Helfried; Otubo, Jorge

    2011-07-01

    NiTi SMA is a promising material in the biomedical area due to its mechanical properties and biocompatibility. However, the nickel in the alloy may cause allergic and toxic reactions and thus limiting its applications. It was evaluated the influence of surface modification in NiTi SMA by nitrogen plasma immersion ion implantation (varying temperatures, and exposure time as follows: <250 °C/2 h, 290 °C/2 h, and 560 °C/1 h) in the amount of nickel released using immersion test in simulated body fluid. The depth of the nitrogen implanted layer increased as the implantation temperature increased resulting in the decrease of nickel release. The sample implanted in high implantation temperature presented 35% of nickel release reduction compared to reference sample.

  9. Synthesis of highly fluorescent nitrogen and phosphorus doped carbon dots for the detection of Fe(3+) ions in cancer cells.

    PubMed

    Chandra, Soumen; Laha, Dipranjan; Pramanik, Arindam; Ray Chowdhuri, Angshuman; Karmakar, Parimal; Sahu, Sumanta Kumar

    2016-02-01

    Highly fluorescent nitrogen and phosphorus-doped carbon dots with a quantum yield 59% have been successfully synthesized from citric acid and di-ammonium hydrogen phosphate by single step hydrothermal method. The synthesized carbon dots have high solubility as well as stability in aqueous medium. The as-obtained carbon dots are well monodispersed with particle sizes 1.5-4 nm. Owing to a good tunable fluorescence property and biocompatibility, the carbon dots were applied for intercellular sensing of Fe(3+) ions as well as cancer cell imaging.

  10. Neutron electric form factor via recoil polarimetry

    SciTech Connect

    Madey, Richard; Semenov, Andrei; Taylor, Simon; Aghalaryan, Aram; Crouse, Erick; MacLachlan, Glen; Plaster, Bradley; Tajima, Shigeyuki; Tireman, William; Yan, Chenyu; Ahmidouch, Abdellah; Anderson, Brian; Asaturyan, Razmik; Baker, O; Baldwin, Alan; Breuer, Herbert; Carlini, Roger; Christy, Michael; Churchwell, Steve; Cole, Leon; Danagoulian, Samuel; Day, Donal; Elaasar, Mostafa; Ent, Rolf; Farkhondeh, Manouchehr; Fenker, Howard; Finn, John; Gan, Liping; Garrow, Kenneth; Gueye, Paul; Howell, Calvin; Hu, Bitao; Jones, Mark; Kelly, James; Keppel, Cynthia; Khandaker, Mahbubul; Kim, Wooyoung; Kowalski, Stanley; Lung, Allison; Mack, David; Manley, D; Markowitz, Pete; Mitchell, Joseph; Mkrtchyan, Hamlet; Opper, Allena; Perdrisat, Charles; Punjabi, Vina; Raue, Brian; Reichelt, Tilmann; Reinhold, Joerg; Roche, Julie; Sato, Yoshinori; Seo, Wonick; Simicevic, Neven; Smith, Gregory; Stepanyan, Samuel; Tadevosyan, Vardan; Tang, Liguang; Ulmer, Paul; Vulcan, William; Watson, John; Wells, Steven; Wesselmann, Frank; Wood, Stephen; Yan, Chen; Yang, Seunghoon; Yuan, Lulin; Zhang, Wei-Ming; Zhu, Hong Guo; Zhu, Xiaofeng

    2003-05-01

    The ratio of the electric to the magnetic form factor of the neutron, G_En/G_Mn, was measured via recoil polarimetry from the quasielastic d({pol-e},e'{pol-n)p reaction at three values of Q^2 [viz., 0.45, 1.15 and 1.47 (GeV/c)^2] in Hall C of the Thomas Jefferson National Accelerator Facility. Preliminary data indicate that G_En follows the Galster parameterization up to Q^2 = 1.15 (GeV/c)^2 and appears to rise above the Galster parameterization at Q^2 = 1.47 (GeV/c)^2.

  11. Recoil separator ERNA: gas target and beam suppression

    NASA Astrophysics Data System (ADS)

    Gialanella, L.; Schürmann, D.; Strieder, F.; Di Leva, A.; De Cesare, N.; D'Onofrio, A.; Imbriani, G.; Klug, J.; Lubritto, C.; Ordine, A.; Roca, V.; Röcken, H.; Rolfs, C.; Rogalla, D.; Romano, M.; Schümann, F.; Terrasi, F.; Trautvetter, H. P.

    2004-04-01

    For improved cross-section measurements of the reaction 12C(α,γ) 16O in inverted kinematics, a recoil separator ERNA is developed at the 4 MV Dynamitron tandem accelerator in Bochum to detect directly the 16O recoils with high efficiency. The 16O recoils are produced by the 12C projectiles in a windowless 4He gas target. We report on the pressure profile of the gas target, the beam suppression by the separator, and the first observation of the 16O recoils at selected energies.

  12. Thermal recoil force, telemetry, and the Pioneer anomaly

    SciTech Connect

    Toth, Viktor T.; Turyshev, Slava G.

    2009-02-15

    Precision navigation of spacecraft requires accurate knowledge of small forces, including the recoil force due to anisotropies of thermal radiation emitted by spacecraft systems. We develop a formalism to derive the thermal recoil force from the basic principles of radiative heat exchange and energy-momentum conservation. The thermal power emitted by the spacecraft can be computed from engineering data obtained from flight telemetry, which yields a practical approach to incorporate the thermal recoil force into precision spacecraft navigation. Alternatively, orbit determination can be used to estimate the contribution of the thermal recoil force. We apply this approach to the Pioneer anomaly using a simulated Pioneer 10 Doppler data set.

  13. ZIF-8 Derived, Nitrogen-Doped Porous Electrodes of Carbon Polyhedron Particles for High-Performance Electrosorption of Salt Ions

    PubMed Central

    Liu, Nei-Ling; Dutta, Saikat; Salunkhe, Rahul R.; Ahamad, Tansir; Alshehri, Saad M.; Yamauchi, Yusuke; Hou, Chia-Hung; Wu, Kevin C.-W.

    2016-01-01

    Three-dimensional (3-D) ZIF-8 derived carbon polyhedrons with high nitrogen (N) content, (denoted as NC-800) are synthesized for their application as high-performance electrodes in electrosorption of salt ions. The results showed a high specific capacitance of 160.8 F·g−1 in 1 M NaCl at a scan rate of 5 mV·s−1. Notably, integration of 3-D mesopores and micropores in NC-800 achieves an excellent capacitive deionization (CDI) performance. The electrosorption of salt ions at the electrical double layer is enhanced by N-doping at the edges of a hexagonal lattice of NC-800. As evidenced, when the initial NaCl solution concentration is 1 mM, the resultant NC-800 exhibits a remarkable CDI potential with a promising salt electrosorption capacity of 8.52 mg·g−1. PMID:27404086

  14. Nitrogen-Doped Carbon Embedded MoS2 Microspheres as Advanced Anodes for Lithium- and Sodium-Ion Batteries.

    PubMed

    Xie, Dong; Xia, Xinhui; Wang, Yadong; Wang, Donghuang; Zhong, Yu; Tang, Wangjia; Wang, Xiuli; Tu, Jiangping

    2016-08-01

    Rational design and synthesis of advanced anode materials are extremely important for high-performance lithium-ion and sodium-ion batteries. Herein, a simple one-step hydrothermal method is developed for fabrication of N-C@MoS2 microspheres with the help of polyurethane as carbon and nitrogen sources. The MoS2 microspheres are composed of MoS2 nanoflakes, which are wrapped by an N-doped carbon layer. Owing to its unique structural features, the N-C@MoS2 microspheres exhibit greatly enhanced lithium- and sodium-storage performances including a high specific capacity, high rate capability, and excellent capacity retention. Additionally, the developed polyurethane-assisted hydrothermal method could be useful for the construction of many other high-capacity metal oxide/sulfide composite electrode materials for energy storage.

  15. ZIF-8 Derived, Nitrogen-Doped Porous Electrodes of Carbon Polyhedron Particles for High-Performance Electrosorption of Salt Ions

    NASA Astrophysics Data System (ADS)

    Liu, Nei-Ling; Dutta, Saikat; Salunkhe, Rahul R.; Ahamad, Tansir; Alshehri, Saad M.; Yamauchi, Yusuke; Hou, Chia-Hung; Wu, Kevin C.-W.

    2016-07-01

    Three-dimensional (3-D) ZIF-8 derived carbon polyhedrons with high nitrogen (N) content, (denoted as NC-800) are synthesized for their application as high-performance electrodes in electrosorption of salt ions. The results showed a high specific capacitance of 160.8 F·g‑1 in 1 M NaCl at a scan rate of 5 mV·s‑1. Notably, integration of 3-D mesopores and micropores in NC-800 achieves an excellent capacitive deionization (CDI) performance. The electrosorption of salt ions at the electrical double layer is enhanced by N-doping at the edges of a hexagonal lattice of NC-800. As evidenced, when the initial NaCl solution concentration is 1 mM, the resultant NC-800 exhibits a remarkable CDI potential with a promising salt electrosorption capacity of 8.52 mg·g‑1.

  16. Low-Temperature Activation of Ion-Implanted Boron and Nitrogen Ions in Cd x Hg1- x Te Heteroepitaxial Layers

    NASA Astrophysics Data System (ADS)

    Voitsekhovskii, A. V.; Talipov, N. Kh.

    2013-12-01

    Processes of electrical activation of ion-implanted boron and nitrogen atoms in Cd x Hg1- x Te (CMT) heteroepitaxial layers grown by methods of molecular-beam epitaxy (HEL CMT MBE) and liquid-phase epitaxy (LPE CMT) have been investigated; likewise in bulk crystals of CMT with low-temperature annealings under anodic oxide. The possibility has been demonstrated of using anodic oxide as an efficient mask for postimplantation annealings of p-type HEL CMT MBE in the temperature interval Т = 200-250°C without disruption of the composition of the variband layer or alteration of the electrophysical properties of the structure. It has been established that in HEL CMT MBE the efficiency of activation of boron as a slowly diffusing donor impurity is lowered with growth of the dose of the B+ ions and is increased by thermal cycling from Т = 77 K to room temperature. Implanted nitrogen, in contrast to boron, is a rapidly diffusing acceptor impurity in CMT, efficiently compensating both radiation donor centers and activated boron. The degree of electrical activation of nitrogen grows substantially upon thermal cycling. It has been shown that the mobility spectrum is an efficient method for monitoring the process of electrical activation of boron in p-type HEL CMT MBE. Mesa photodiodes based on activated boron in p-type HEL CMT MBE with long-wavelength photosensitivity boundary λc = 11 μm, prepared here for the first time, had a high maximum value of the product of the differential resistance by the area of the photodiode R d A = (6 - 8)ṡ102 Ωṡcm2, product R 0 A = 5 - 6 Ωṡcm2 (at zero bias), and a diffusion ledge on the inverse branch of the current-voltage ( I- V) characteristic out to a bias voltage of 1.3 V.

  17. Synthesis of silicon oxynitride by ion beam sputtering and the effects of nitrogen ion-assisted bombardment

    NASA Astrophysics Data System (ADS)

    Lambrinos, M. F.; Valizadeh, R.; Colligon, J. S.

    1997-05-01

    Thin silicon oxynitride (SiO xN y) films were synthesised without substrate heating by means of N 2+ ion-beam sputtering of a silicon nitride target at an energy of 1000 eV in a N 2 and O 2 ambient with and without 200 eV N 2+ ion assistance. Unassisted films were deposited in a controlled O 2 partial pressure ranging from ambient to 5.0 × 10 -3 Pa whereas assisted films were deposited at a fixed O 2 partial pressure of 1.0 × 10 -3 Pa. The O/(O+N) atomic fraction and the SiO xN y asymmetric stretch mode IR absorption peak wavenumber of unassisted films increased almost linearly with increasing O 2 partial pressure, from 0.2 to 1.0 and 860 cm -1 to 1050 cm -1, respectively, while their refractive indices decreased from 1.92 to 1.46. The behaviour of the SiO xN y film refractive index with the SiO 2 fraction has been compared to that predicted by Drude, Lorentz-Lorenz and Bruggeman models under the assumption that the film is a mixture of SiO 2 and Si 3N 4 phases. For a fixed O 2 partial pressure, the O content of the N 2+ ion-assisted films increased with an increase in the N + ion to Si atom arrival ratio from 0 to 3. This increase in O content correlate with changes in the film refractive index and SiO xN y asymmetric stretch mode absorption peak position, from 1.56 to 1.43 and 1014 cm -1 to 1054 cm -1, respectively, indicating that the O/N atomic ratio increases with increasing N + ion to Si atom ratio until film properties consistent with stoichiometric SiO 2 are obtained.

  18. Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

    PubMed Central

    Franz, Robert; Polcik, Peter; Anders, André

    2015-01-01

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr2+ ions were dominating in Ar and N2 and Cr+ in O2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings. PMID:26120236

  19. Probing the coordination environment of Ti(3+) ions coordinated to nitrogen-containing Lewis bases.

    PubMed

    Morra, E; Maurelli, S; Chiesa, M; Van Doorslaer, S

    2015-08-28

    Multi-frequency continuous-wave and pulsed EPR techniques are employed to investigate the coordination of nitrogen-containing ligands to Ti(3+)-chloro complexes. Frozen solutions of TiCl3 and TiCl3(Py)3 dissolved in nitrogen-containing solvents have been investigated together with the TiCl3(Py)3 solid-state complex. For these different systems, the hyperfine and nuclear quadrupole data of Ti(3+)-bound (14)N nuclei are reported and discussed in the light of DFT computations, allowing for a detailed description of the microscopic structure of these systems.

  20. Gas chromatography coupled to electron capture negative ion mass spectrometry with nitrogen as the reagent gas--an alternative method for the determination of polybrominated compounds.

    PubMed

    Rosenfelder, Natalie; Vetter, Walter

    2009-12-01

    Gas chromatography in combination with electron capture negative ion mass spectrometry (GC/ECNI-MS) is a sensitive method for the determination of polybrominated compounds in environmental and food samples via detection of the bromide ion isotopes m/z 79 and 81. The standard reagent gas for inducing chemical ionization in GC/ECNI-MS is methane. However, the use of methane has some drawbacks as it promotes carbonization of the filament and ion source. In this study, we explored the suitability of nitrogen as reagent gas for the determination of brominated flame retardants (polybrominated diphenyl ethers (PBDEs), polybrominated biphenyls (PBBs), allyl-2,4,6-tribromophenyl ether (ATE) and 2,3-dibromopropyl-2,4,6-tribromophenyl ether (DPTE)) and halogenated natural products (for instance, methoxylated tetrabrominated diphenylethers and polybrominated hexahydroxanthene derivatives). An ion source temperature of 250 degrees C and a nitrogen pressure of 7 Torr in the ion source gave the highest response for m/z 79 and 81 of virtually all investigated polybrominated compounds. Using these conditions, nitrogen-mediated GC/ECNI-MS usually gave higher sensitivity than the method with methane previously used in our lab. In addition, the ion source was not contaminated to the same degree and the lifetime of the filament was significantly increased. Moreover, the response factors of the different polybrominated compounds with the exception of 2,4,6-tribromophenol were more uniform than with methane. Nitrogen is available at very high purity at relatively low price. PMID:19904736

  1. Initial results of the commissioning of the HRIBF recoil mass spectrometer

    SciTech Connect

    Gross, C.J.; Akovali, Y.A.; Brinkman, M.J.; Mas, J.; McConnell, J.W.; Milner, W.T.; Shapira, D.; Ginter, T.N.; James, A.N.

    1996-10-01

    The recoil mass spectrometer at the Holifield Radioactive Ion Beam Facility is currently undergoing commissioning tests. This new spectrometer is designed to transmit ions with rigidities of K = 100 resulting from fusion-evaporation reactions using inverse-kinematics. The device consists of two sections: a momentum separator to provide beam rejection and a mass separator for product identification. Using normal-kinematic and symmetric reactions, the commissioning tests have shown that the A/Q acceptance is almost {+-}5%, the energy acceptance is approximately {+-}12%, and there has been little, if any, primary beam observed on the focal plane. Commissioning tests are presently underway with reactions using inverse-kinematics.

  2. Characteristics of Pickup Ions in Titan's Upper Atmosphere and Escape of Nitrogen

    NASA Astrophysics Data System (ADS)

    Michael, M.; Johnson, R. E.; Ledvina, S. A.

    2004-11-01

    The distribution of 14 amu and 28-29 amu pickup ions with depth into Titan's atmosphere have calculated by Ledvina et al. (2004) and Brecht et al. (2000). Here we study the interaction of these ions with molecules in the upper atmosphere of Titan. As its environment is highly variable, Titan can be within Saturn's magnetosphere or can interact directly with the solar wind. These pickup ions follow the corresponding magnetic field as they penetrate into the atmosphere. The magnetic field strength considered here are 5.1 nT and 0.5 nT when Titan is inside the magnetosphere and in the solar wind respectively. The incident pick up ions collide with atmospheric neutrals. After they charge exchange, they are tracked under the influence of Titan's gravitational field. The energetic ions and neutral impart energy to the molecules in the Titan's atmosphere causing ejection, bond breaking and heating. Predictions will be made for the Cassini Titan flyby. The model described is flexible to incorporate that data as it becomes available. References Brecht, S.H., J.G. Luhmann, and D.J. Larson, Simulation of the Saturnian magnetospheric interaction with Titan, J. Geophys. Res., 105, 13119-13130, 2000. Ledvina, S.A., S.H. Brecht, J.G. Luhmann, Ion distribution of 14 amu pickup ions associated with Titan's plasma interaction, Geophys. Res. Lett., 31, L17S10, 10.1029/2004GL019861, 2004.

  3. A predictive theory for elastic scattering and recoil of protons from 4He

    SciTech Connect

    Hupin, Guillaume; Quaglioni, Sofia; Navratil, Petr

    2014-12-08

    Low-energy cross sections for elastic scattering and recoil of protons from 4He nuclei (also known as α particles) are calculated directly by solving the Schrodinger equation for five nucleons interacting through accurate two- and three-nucleon forces derived within the framework of chiral effective field theory. Precise knowledge of these processes at various proton backscattering/recoil angles and energies is needed for the ion-beam analysis of numerous materials, from the surface layers of solids, to thin films, to fusion-reactor materials. Indeed, the same elastic scattering process, in two different kinematic configurations, can be used to probe the concentrations and depth profiles of either hydrogen or helium. Furthermore, we compare our results to available experimental data and show that direct calculations with modern nuclear potentials can help to resolve remaining inconsistencies among data sets and can be used to predict these cross sections when measurements are not available.

  4. A predictive theory for elastic scattering and recoil of protons from 4He

    DOE PAGESBeta

    Hupin, Guillaume; Quaglioni, Sofia; Navratil, Petr

    2014-12-08

    Low-energy cross sections for elastic scattering and recoil of protons from 4He nuclei (also known as α particles) are calculated directly by solving the Schrodinger equation for five nucleons interacting through accurate two- and three-nucleon forces derived within the framework of chiral effective field theory. Precise knowledge of these processes at various proton backscattering/recoil angles and energies is needed for the ion-beam analysis of numerous materials, from the surface layers of solids, to thin films, to fusion-reactor materials. Indeed, the same elastic scattering process, in two different kinematic configurations, can be used to probe the concentrations and depth profiles ofmore » either hydrogen or helium. Furthermore, we compare our results to available experimental data and show that direct calculations with modern nuclear potentials can help to resolve remaining inconsistencies among data sets and can be used to predict these cross sections when measurements are not available.« less

  5. [Ion-exchange substrate as a source of nitrogen mobile forms in the conveyor method of vegetables cultivation on artificial soil].

    PubMed

    Velichko, V V; Ushakova, S A; Tikhomirov, A A

    2014-01-01

    The investigation had the objective to evaluate the applicability of ion-exchange substrate to maintaining the mobile nitrogen content in irrigation solution and artificial coil during cultivation of a mixed (in term of age) vegetable container. Objects of the investigation were radishes and leaf cabbage crops with the period of vegetation of 28 days. A 120-day experiment showed that single introduction of the ion-exchange substrate promoted nitrogen stabilization in the irrigation solution and, consequently, yielding of higher crops as compared with the control. PMID:25365879

  6. [Ion-exchange substrate as a source of nitrogen mobile forms in the conveyor method of vegetables cultivation on artificial soil].

    PubMed

    Velichko, V V; Ushakova, S A; Tikhomirov, A A

    2014-01-01

    The investigation had the objective to evaluate the applicability of ion-exchange substrate to maintaining the mobile nitrogen content in irrigation solution and artificial coil during cultivation of a mixed (in term of age) vegetable container. Objects of the investigation were radishes and leaf cabbage crops with the period of vegetation of 28 days. A 120-day experiment showed that single introduction of the ion-exchange substrate promoted nitrogen stabilization in the irrigation solution and, consequently, yielding of higher crops as compared with the control.

  7. Change in Uptake, Transport and Accumulation of Ions in Nerium oleander (Rosebay) as Affected by Different Nitrogen Sources and Salinity

    PubMed Central

    Abdolzadeh, Ahmad; Shima, Kazuto; Lambers, Hans; Chiba, Kyozo

    2008-01-01

    Background and Aims The source of nitrogen plays an important role in salt tolerance of plants. In this study, the effects of NaCl on net uptake, accumulation and transport of ions were investigated in Nerium oleander with ammonium or nitrate as the nitrogen source in order to analyse differences in uptake and cycling of ions within plants. Methods Plants were grown in a greenhouse in hydroponics under different salt treatments (control vs. 100 mm NaCl) with ammonium or nitrate as the nitrogen source, and changes in ion concentration in plants, xylem sap exuded from roots and stems, and phloem sap were determined. Key Results Plant weight, leaf area and photosynthetic rate showed a higher salt tolerance of nitrate-fed plants compared with that of ammonium-fed plants. The total amount of Na+ transported in the xylem in roots, accumulated in the shoot and retranslocated in the phloem of ammonium-fed plants under salt treatment was 1·8, 1·9 and 2·7 times more, respectively, than that of nitrate-treated plants. However, the amount of Na+ accumulated in roots in nitrate-fed plants was about 1·5 times higher than that in ammonium-fed plants. Similarly, Cl− transport via the xylem to the shoot and its retranslocation via the phloem (Cl− cycling) were far greater with ammonium treatment than with nitrate treatment under conditions of salinity. The uptake and accumulation of K+ in shoots decreased more due to salinity in ammonium-fed plants compared with nitrate-fed plants. In contrast, K+ cycling in shoots increased due to salinity, with higher rates in the ammonium-treated plants. Conclusions The faster growth of nitrate-fed plants under conditions of salinity was associated with a lower transport and accumulation of Na+ and Cl− in the shoot, whereas in ammonium-fed plants accumulation and cycling of Na+ and Cl− in shoots probably caused harmful effects and reduced growth of plants. PMID:18772147

  8. Quantify the loss of major ions induced by CO2 enrichment and nitrogen addition in subtropical model forest ecosystems

    NASA Astrophysics Data System (ADS)

    Liu, Juxiu; Zhang, Deqiang; Huang, Wenjuan; Zhou, Guoyi; Li, Yuelin; Liu, Shizhong

    2014-04-01

    Previous studies have reported that atmospheric CO2 enrichment would increase the ion concentrations in the soil water. However, none of these studies could exactly quantify the amount of ion changes in the soil water induced by elevated CO2 and all of these experiments were carried out only in the temperate areas. Using an open-top chamber design, we studied the effects of CO2 enrichment alone and together with nitrogen (N) addition on soil water chemistry in the subtropics. Three years of exposure to an atmospheric CO2 concentration of 700 ppm resulted in accelerated base cation loss via leaching water below the 70 cm soil profile. The total of base cation (K+ + Na+ + Ca2+ + Mg2+) loss in the elevated CO2 treatment was higher than that of the control by 220%, 115%, and 106% in 2006, 2007, and 2008, respectively. The N treatment decreased the effect of high CO2 treatment on the base cation loss in the leachates. Compared to the control, N addition induced greater metal cation (Al3+ and Mn2+) leaching loss in 2008 and net Al3+ and Mn2+ loss in the high N treatment increased by 100% and 67%, respectively. However, the CO2 treatment decreased the effect of high N treatment on the metal cation loss. Changes of ion export followed by the exposure to the elevated CO2, and N treatments were related to both ion concentrations and leached water amount. We hypothesize that forests in subtropical China might suffer from nutrient limitation and some poisonous metal activation in plant biomass under future global change.

  9. Collision integrals for the interaction of the ions of nitrogen and oxygen in a plasma at high temperatures and pressures

    NASA Technical Reports Server (NTRS)

    Stallcop, James R.; Partridge, Harry; Levin, E.

    1992-01-01

    The corrections to the transport cross-sections and collision integrals for Coulomb interactions arising from the application of realistic interaction energies of the ions of nitrogen and oxygen are investigated. Accurate potential-energy curves from an ab initio electronic-structure calculation and a semiclassical description of the scattering are used to determine the difference between the cross-sections for the real interaction forces and a Coulomb force for large values of the Debye shielding parameter. Graphs of the correction to the diffusion and viscosity-collision integrals are presented for temperatures from about 10,000 K to 150,000 K. This correction can be combined with tabulations of the collision integrals for shielded Coulomb potentials to determine the contribution of N(+)-N(+), N(+)-O(+), and O(+)-O(+) interactions to the transport properties of high-temperature air. Analytical forms are fitted to the calculated results to assist this application.

  10. Scattering of hydrogen, nitrogen and water ions from micro pore optic plates for application in spaceborne plasma instrumentation

    NASA Astrophysics Data System (ADS)

    Stude, Joan; Wieser, Martin; Barabash, Stas

    2016-10-01

    Time-of-flight mass spectrometers for upcoming space missions into enhanced radiation environments need to be small, light weight and energy efficient. Time-of-flight systems using surface interactions as start-event generation can be smaller than foil-type instruments. Start surfaces for such applications need to provide narrow angular scattering, high ionization yields and high secondary electron emissions to be effective. We measured the angular scattering, energy distribution and positive ionization yield of micro pore optics for incident hydrogen, nitrogen and water ions at 2 keV. Positive ionization yields of 2% for H+ , 0.5% for N+ and 0.2% for H2O+ were detected.

  11. A gun recoil system employing a magnetorheological fluid damper

    NASA Astrophysics Data System (ADS)

    Li, Z. C.; Wang, J.

    2012-10-01

    This research aims to design and control a full scale gun recoil buffering system which works under real firing impact loading conditions. A conventional gun recoil absorber is replaced with a controllable magnetorheological (MR) fluid damper. Through dynamic analysis of the gun recoil system, a theoretical model for optimal design and control of the MR fluid damper for impact loadings is derived. The optimal displacement, velocity and optimal design rules are obtained. By applying the optimal design theory to protect against impact loadings, an MR fluid damper for a full scale gun recoil system is designed and manufactured. An experimental study is carried out on a firing test rig which consists of a 30 mm caliber, multi-action automatic gun with an MR damper mounted to the fixed base through a sliding guide. Experimental buffering results under passive control and optimal control are obtained. By comparison, optimal control is better than passive control, because it produces smaller variation in the recoil force while achieving less displacement of the recoil body. The optimal control strategy presented in this paper is open-loop with no feedback system needed. This means that the control process is sensor-free. This is a great benefit for a buffering system under impact loading, especially for a gun recoil system which usually works in a harsh environment.

  12. Analysis of inorganic nitrogen and related anions in high salinity water using ion chromatography with tandem UV and conductivity detectors.

    PubMed

    Wilson, Brian; Gandhi, Jay; Zhang, Chunlong Carl

    2011-09-01

    Over 97% of the Earth's water is high salinity water in the form of gulfs, oceans, and salt lakes. There is an increasing concern for the quality of water in bays, gulfs, oceans, and other natural waters. These waters are affected by many different sources of contamination. The sources are, but not limited to, groundwater run-off of nitrogen containing fertilizer, pesticides, cleaning agents, solid wastes, industrial waters, and many more. The final destinations of these contaminants are rivers, lakes, and bayous that eventually will lead to bays, gulfs, and oceans. Many industries depend on the quality of these waters, such as the fishing industry. In addition to wild marine life, there are large aquariums and fish and shrimp farms that are required to know the quality of the water. However, the ability of these industries to monitor their processes is limited. Most analytical methods do not apply to the analysis of high salinity waters. They are dependent on wet chemistry techniques, spectrophotometers, and flow analyzers. These methods do not have the accuracy, precision, and sensitivity when compared to ion chromatography (IC). Since the inception of IC, it has become a standard practice for determining the content of many different water samples. Many IC methods are limited in the range of analytes that can be detected, as well as the numerous sample sources of which the methods are applicable. The main focus of current IC methods does not include high salinity waters. This research demonstrates an ion chromatographic method that has the ability to determine low level concentrations of inorganic nitrogen and related anions (nitrite-N, nitrate-N, phosphorous-P, sulfate, bromide, chloride, sulfide, fluoride, ammonia, calcium, and magnesium) in a single run using a combination of UV and conductivity detectors. This method is applicable to various waters, and uses both freshwater and high salinity water samples.

  13. Sub-5 nm graphene nanopore fabrication by nitrogen ion etching induced by a low-energy electron beam

    NASA Astrophysics Data System (ADS)

    Fox, Daniel S.; Maguire, Pierce; Zhou, Yangbo; Rodenburg, Cornelia; O’Neill, Arlene; Coleman, Jonathan N.; Zhang, Hongzhou

    2016-05-01

    A flexible and efficient method to fabricate nanopores in graphene has been developed. A focused, low-energy (5 keV) electron beam was used to locally activate etching of a graphene surface in a low pressure (0.3 Pa) N2 environment. Nanopores with sub-5 nm diameters were fabricated. The lattice structure of the graphene was observed to recover within 20 nm of the nanopore edge. Nanopore growth rates were investigated systematically. The effects of nitrogen pressure, electron beam dwell time and beam current were characterised in order to understand the etching mechanism and enable optimisation of the etching parameters. A model was developed which describes how the diffusion of ionised nitrogen affects the nanopore growth rate. Etching of other two-dimensional materials was attempted as demonstrated with MoS2. The lack of etching observed supports our model of a chemical reaction-based mechanism. The understanding of the etching mechanism will allow more materials to be etched by selection of an appropriate ion species.

  14. Mesoporous nitrogen-doped carbon hollow spheres as high-performance anodes for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Huo, Kaifu; An, Weili; Fu, Jijiang; Gao, Biao; Wang, Lei; Peng, Xiang; Cheng, Gary J.; Chu, Paul K.

    2016-08-01

    Nitrogen-doped mesoporous carbon hollow spheres (N-MCHSs) were prepared using mesoporous silica hollow spheres as template and dopamine as carbon precursor. The N-MCHSs demonstrate high specific surface area and vegetable sponge-like mesoporous shell with interconnected "carbon bridges", facilitating continuous electron transport and Li ion diffusion, and making the whole structure more stable. The influence of N contents and N-bonding configuration on the Li storage of N-MCHSs is discussed. The N-MCHSs carbonized at 800 °C demonstrate high reversible capacity and excellent rate performance, delivering a capacity of 485 mAh g-1 at a current of 0.5 A g-1 after 1,100 cycles. Even up to 4.0 A g-1, a high capacity of 214 mAh g-1 can be remained. The high electrochemical performance of N-MCHSs can be ascribed to mesoporous carbon hollow spheres structure and high level pyridinic nitrogen doping.

  15. Simultaneous speciation analysis of inorganic nitrogen with the use of ion chromatography in highly salinated environmental samples.

    PubMed

    Kurzyca, Iwona; Niedzielski, Przemyslaw; Frankowski, Marcin

    2016-09-01

    We present the development of a method for the simultaneous determination of inorganic nitrogen species in oxidized (NO2 (-) , NO3 (-) ) and reduced (NH4 (+) ) forms using ion chromatography with diode-array detection (205, 208, and 425 nm, respectively). The oxidized forms were determined directly after the separation in the anion exchanger, while the reduced form was determined in the column hold-up time after derivatization with the Nessler reagent. The use of an appropriate modifier (Seignette reagent) and mobile phase (NaCl) enabled the determination of inorganic nitrogen species in highly salinated environmental samples (water, sediments). Moreover, low detection limits were obtained of 0.04 mg/L for NH4 (+) and 0.006 and 0.005 mg/L for NO2 (-) and NO3 (-) , respectively. The analysis of environmental samples indicated NH4 (+) contents of up to 1161 ± 47 mg/kg and NO3 (-) of up to 148 ± 6 mg/kg for sediment samples, as well as the NH4 (+) concentrations of up to 0.98 ± 0.10 mg/L, NO2 (-) of up to 24 ± 1 mg/L and NO3 (-) of up to 20 ± 1 mg/L for water samples.

  16. Sub-5 nm graphene nanopore fabrication by nitrogen ion etching induced by a low-energy electron beam.

    PubMed

    Fox, Daniel S; Maguire, Pierce; Zhou, Yangbo; Rodenburg, Cornelia; O'Neill, Arlene; Coleman, Jonathan N; Zhang, Hongzhou

    2016-05-13

    A flexible and efficient method to fabricate nanopores in graphene has been developed. A focused, low-energy (5 keV) electron beam was used to locally activate etching of a graphene surface in a low pressure (0.3 Pa) N2 environment. Nanopores with sub-5 nm diameters were fabricated. The lattice structure of the graphene was observed to recover within 20 nm of the nanopore edge. Nanopore growth rates were investigated systematically. The effects of nitrogen pressure, electron beam dwell time and beam current were characterised in order to understand the etching mechanism and enable optimisation of the etching parameters. A model was developed which describes how the diffusion of ionised nitrogen affects the nanopore growth rate. Etching of other two-dimensional materials was attempted as demonstrated with MoS2. The lack of etching observed supports our model of a chemical reaction-based mechanism. The understanding of the etching mechanism will allow more materials to be etched by selection of an appropriate ion species.

  17. Mesoporous nitrogen-doped carbon hollow spheres as high-performance anodes for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Huo, Kaifu; An, Weili; Fu, Jijiang; Gao, Biao; Wang, Lei; Peng, Xiang; Cheng, Gary J.; Chu, Paul K.

    2016-08-01

    Nitrogen-doped mesoporous carbon hollow spheres (N-MCHSs) were prepared using mesoporous silica hollow spheres as template and dopamine as carbon precursor. The N-MCHSs demonstrate high specific surface area and vegetable sponge-like mesoporous shell with interconnected "carbon bridges", facilitating continuous electron transport and Li ion diffusion, and making the whole structure more stable. The influence of N contents and N-bonding configuration on the Li storage of N-MCHSs is discussed. The N-MCHSs carbonized at 800 °C demonstrate high reversible capacity and excellent rate performance, delivering a capacity of 485 mAh g-1 at a current of 0.5 A g-1 after 1,100 cycles. Even up to 4.0 A g-1, a high capacity of 214 mAh g-1 can be remained. The high electrochemical performance of N-MCHSs can be ascribed to mesoporous carbon hollow spheres structure and high level pyridinic nitrogen doping.

  18. Simultaneous speciation analysis of inorganic nitrogen with the use of ion chromatography in highly salinated environmental samples.

    PubMed

    Kurzyca, Iwona; Niedzielski, Przemyslaw; Frankowski, Marcin

    2016-09-01

    We present the development of a method for the simultaneous determination of inorganic nitrogen species in oxidized (NO2 (-) , NO3 (-) ) and reduced (NH4 (+) ) forms using ion chromatography with diode-array detection (205, 208, and 425 nm, respectively). The oxidized forms were determined directly after the separation in the anion exchanger, while the reduced form was determined in the column hold-up time after derivatization with the Nessler reagent. The use of an appropriate modifier (Seignette reagent) and mobile phase (NaCl) enabled the determination of inorganic nitrogen species in highly salinated environmental samples (water, sediments). Moreover, low detection limits were obtained of 0.04 mg/L for NH4 (+) and 0.006 and 0.005 mg/L for NO2 (-) and NO3 (-) , respectively. The analysis of environmental samples indicated NH4 (+) contents of up to 1161 ± 47 mg/kg and NO3 (-) of up to 148 ± 6 mg/kg for sediment samples, as well as the NH4 (+) concentrations of up to 0.98 ± 0.10 mg/L, NO2 (-) of up to 24 ± 1 mg/L and NO3 (-) of up to 20 ± 1 mg/L for water samples. PMID:27422313

  19. A Revival of Waste: Atmospheric Pressure Nitrogen Plasma Jet Enhanced Jumbo Silicon/Silicon Carbide Composite in Lithium Ion Batteries.

    PubMed

    Chen, Bing-Hong; Chuang, Shang-I; Liu, Wei-Ren; Duh, Jenq-Gong

    2015-12-30

    In this study, a jumbo silicon/silicon carbide (Si/SiC) composite (JSC), a novel anode material source, was extracted from solar power industry cutting waste and used as a material for lithium-ion batteries (LIBs), instead of manufacturing the nanolized-Si. Unlike previous methods used for preventing volume expansion and solid electrolyte interphase (SEI), the approach proposed here simply entails applying surface modification to JSC-based electrodes by using nitrogen-atmospheric pressure plasma jet (N-APPJ) treatment process. Surface organic bonds were rearranged and N-doped compounds were formed on the electrodes through applying different plasma treatment durations, and the qualitative examinations of before/after plasma treatment were identified by X-ray photoelectron spectroscopy (XPS) and electron probe microanalyzer (EPMA). The surface modification resulted in the enhancement of electrochemical performance with stable capacity retention and high Coulombic efficiency. In addition, depth profile and scanning electron microscope (SEM) images were executed to determine the existence of Li-N matrix and how the nitrogen compounds change the surface conditions of the electrodes. The N-APPJ-induced rapid surface modification is a major breakthrough for processing recycled waste that can serve as anode materials for next-generation high-performance LIBs.

  20. Freeze-drying for sustainable synthesis of nitrogen doped porous carbon cryogel with enhanced supercapacitor and lithium ion storage performance.

    PubMed

    Ling, Zheng; Yu, Chang; Fan, Xiaoming; Liu, Shaohong; Yang, Juan; Zhang, Mengdi; Wang, Gang; Xiao, Nan; Qiu, Jieshan

    2015-09-18

    A chitosan (CS) based nitrogen doped carbon cryogel with a high specific surface area (SSA) has been directly synthesized via a combined process of freeze-drying and high-temperature carbonization without adding any activation agents. The as-made carbon cryogel demonstrates an SSA up to 1025 m(2) g(-1) and a high nitrogen content of 5.98 wt%, while its counterpart derived from CS powder only shows an SSA of 26 m(2) g(-1). Freeze-drying is a determining factor for the formation of carbon cryogel with a high SSA, where the CS powder with a size of ca. 200 μm is transformed into the sheet-shaped cryogel with a thickness of 5-8 μm. The as-made carbon cryogel keeps the sheet-shaped structure and the abundant pores are formed in situ and decorated inside the sheets during carbonization. The carbon cryogel shows significantly enhanced performance as supercapacitor and lithium ion battery electrodes in terms of capacity and rate capability due to its quasi two-dimensional (2D) structure with reduced thickness. The proposed method may provide a simple approach to configure 2D biomass-derived advanced carbon materials for energy storage devices. PMID:26314370

  1. A Quadrupole Ion Trap Mass Spectrometer for Quantitative Analysis of Nitrogen-Purged Compartments within the Space Shuttle

    NASA Technical Reports Server (NTRS)

    Ottens, Andrew K.; Griffin, Timothy P.; Helms, William R.; Yost, Richard A.; Steinrock, T. (Technical Monitor)

    2001-01-01

    To enter orbit, the Space Shuttle burns 1.8 million liters of liquid hydrogen combined with 0.8 million liters of liquid oxygen through three rocket engines mounted in the aft. NASA monitors the nitrogen-purged aft compartment for increased levels of hydrogen or oxygen in order to detect and determine the severity of a cryogenic fuel leak. Current monitoring is accomplished with a group of mass spectrometer systems located as much as 400 feet away from the Shuttle. It can take up to 45 seconds for gas to reach the mass spectrometer, which precludes monitoring for leaks in the final moments before liftoff (the orbiter engines are started at T-00:06 seconds). To remedy the situation, NASA is developing a small rugged mass spectrometer to be used as point-sensors around the Space Shuttle. As part of this project, numerous mass analyzer technologies are being investigated. Presented here are the preliminary results for one such technology, quadrupole ion trap mass spectrometry (QITMS). A compact QITMS system has been developed in-house at the University of Florida for monitoring trace levels of four primary gases, hydrogen, helium, oxygen, and argon, all in a nitrogen background. Since commercially available QITMS systems are incapable of mass analysis at m/z(exp 2), the home-built system is preferred for the evaluation of QITMS technology.

  2. Freeze-drying for sustainable synthesis of nitrogen doped porous carbon cryogel with enhanced supercapacitor and lithium ion storage performance

    NASA Astrophysics Data System (ADS)

    Ling, Zheng; Yu, Chang; Fan, Xiaoming; Liu, Shaohong; Yang, Juan; Zhang, Mengdi; Wang, Gang; Xiao, Nan; Qiu, Jieshan

    2015-09-01

    A chitosan (CS) based nitrogen doped carbon cryogel with a high specific surface area (SSA) has been directly synthesized via a combined process of freeze-drying and high-temperature carbonization without adding any activation agents. The as-made carbon cryogel demonstrates an SSA up to 1025 m2 g-1 and a high nitrogen content of 5.98 wt%, while its counterpart derived from CS powder only shows an SSA of 26 m2 g-1. Freeze-drying is a determining factor for the formation of carbon cryogel with a high SSA, where the CS powder with a size of ca. 200 μm is transformed into the sheet-shaped cryogel with a thickness of 5-8 μm. The as-made carbon cryogel keeps the sheet-shaped structure and the abundant pores are formed in situ and decorated inside the sheets during carbonization. The carbon cryogel shows significantly enhanced performance as supercapacitor and lithium ion battery electrodes in terms of capacity and rate capability due to its quasi two-dimensional (2D) structure with reduced thickness. The proposed method may provide a simple approach to configure 2D biomass-derived advanced carbon materials for energy storage devices.

  3. Modeling the Observability of Recoiling Black Holes as Offset Quasars

    NASA Astrophysics Data System (ADS)

    Blecha, Laura; Torrey, Paul; Vogelsberger, Mark; Genel, Shy; Springel, Volker; Sijacki, Debora; Snyder, Gregory; Bird, Simeon; Nelson, Dylan; Xu, Dandan; Hernquist, Lars

    2015-08-01

    The merger of two supermassive black holes (SMBHs) imparts a gravitational-wave (GW) recoil kick to the remnant SMBH. In extreme cases these kicks may be thousands of km/s -- enough to easily eject them from their host galaxies. Moderate recoil kicks may also cause substantial displacements of the SMBH, however. An actively-accreting, recoiling SMBH may be observable as an offset quasar. Prior to the advent of a space-based GW observatory, detections of these offset quasars may offer the best chance for identifying recent SMBH mergers. Indeed, observational searches for recoiling quasars have already identified several promising candidates. However, systematic searches for recoils are currently hampered by large uncertainties regarding how often offset quasars should be observable, where they are most likely to be found, and whether BH spin alignment prior to merger is efficient at suppressing large recoils. Motivated by this, we have developed a model for the observable population of recoiling quasars in a cosmological framework, utilizing detailed information about the progenitor galaxies from state-of-the-art cosmological hydrodynamic simulations (the Illustris Project). The model for offset quasar lifetimes includes a physically-motivated, time-dependent model for accretion onto kicked SMBHs, and results are analyzed for a range of possible BH spin alignment models. We find that the observability of offset quasars depends strongly on the efficiency of pre-merger spin alignment, with promising indications that observations of recoils could distinguish between at least the extreme limits of spin alignment models. Our results also suggest that observable offset quasars should inhabit preferred types of host galaxies, where again these populations depend on the degree of pre-merger spin alignment. These findings will be valuable for planned and future dedicated searches for recoiling quasars, and they indicate that such objects might be used to place indirect

  4. Isotope shifts in beryllium-, boron-, carbon-, and nitrogen-like ions from relativistic configuration interaction calculations

    SciTech Connect

    Nazé, C.; Verdebout, S.; Godefroid, M.

    2014-09-15

    Energy levels, normal and specific mass shift parameters as well as electronic densities at the nucleus are reported for numerous states along the beryllium, boron, carbon, and nitrogen isoelectronic sequences. Combined with nuclear data, these electronic parameters can be used to determine values of level and transition isotope shifts. The calculation of the electronic parameters is done using first-order perturbation theory with relativistic configuration interaction wavefunctions that account for valence, core–valence, and core–core correlation effects as zero-order functions. Results are compared with experimental and other theoretical values, when available.

  5. Wear of UHMWPE against nitrogen-ion-implanted and NbN-coated Co-Cr-Mo alloy formed by plasma immersion ion implantation and deposition for artificial joints

    NASA Astrophysics Data System (ADS)

    Park, Won-Woong; Kim, Eun-Kyeom; Jeon, Jun-Hong; Choi, Jin-Young; Moon, Sun-Woo; Lim, Sang-Ho; Han, Seung-Hee

    2012-08-01

    NbN thin film was deposited on the Co-Cr-Mo alloy by plasma immersion ion implantation and deposition (PIII&D) to reduce the volume wear rate of UHMWPE. In addition, nitrogen ions were implanted on the surface of the Co-Cr-Mo alloy prior to the NbN film deposition in order to increase the hardness of the substrate. XPS analysis revealed that nitrogen ions were implanted into the surface of the Co-Cr-Mo alloy, leading to the formation of CrN and Cr2N. The UHMWPE volume wear rate was measured using a pin-on-disk tribometer. The wear test result showed that the volume wear rate of UHMWPE against NbN-coated Co-Cr-Mo alloy declined by 20% as compared to that in the untreated Co-Cr-Mo alloy. In addition, the UHMWPE wear rate against the nitrogen-ion-implanted and NbN-coated Co-Cr-Mo alloy could be drastically reduced by up to 48%. It can be concluded that a combination of prior nitrogen ion implantation and NbN coating via PIII&D is a promising surface treatment tool for extending the lifetime of metal-on-polymer artificial joints.

  6. Oxygen recoil implant from SiO{sub 2} layers into single-crystalline silicon

    SciTech Connect

    Wang, G.; Chen, Y.; Li, D.; Oak, S.; Srivastav, G.; Banerjee, S.; Tasch, A.; Merrill, P.; Bleiler, R.

    2001-06-01

    It is important to understand the distribution of recoil-implanted atoms and the impact on device performance when ion implantation is performed at a high dose through surface materials into single crystalline silicon. For example, in ultralarge scale integration impurity ions are often implanted through a thin layer of screen oxide and some of the oxygen atoms are inevitably recoil implanted into single-crystalline silicon. Theoretical and experimental studies have been performed to investigate this phenomenon. We have modified the Monte Carlo ion implant simulator, UT-Marlowe (B. Obradovic, G. Wang, Y. Chen, D. Li, C. Snell, and A. F. Tasch, UT-MARLOWE Manual, 1999), which is based on the binary collision approximation, to follow the full cascade and to dynamically modify the stoichiometry of the Si layer as oxygen atoms are knocked into it. CPU reduction techniques are used to relieve the demand on computational power when such a full cascade simulation is involved. Secondary ion mass spectrometry (SIMS) profiles of oxygen have been carefully obtained for high dose As and BF{sub 2} implants at different energies through oxide layers of various thicknesses, and the simulated oxygen profiles are found to agree very well with the SIMS data. {copyright} 2001 American Institute of Physics.

  7. Difference between a Photon's Momentum and an Atom's Recoil

    SciTech Connect

    Gibble, Kurt

    2006-08-18

    When an atom absorbs a photon from a laser beam that is not an infinite plane wave, the atom's recoil is less than ({Dirac_h}/2{pi})k in the propagation direction. We show that the recoils in the transverse directions produce a lensing of the atomic wave functions, which leads to a frequency shift that is not discrete but varies linearly with the field amplitude and strongly depends on the atomic state detection. The same lensing effect is also important for microwave atomic clocks. The frequency shifts are of the order of the naive recoil shift for the transverse wave vector of the photons.

  8. An improved method of ion exchange for nitrogen isotope analysis of water nitrate.

    PubMed

    Xing, Meng; Liu, Weiguo

    2011-02-01

    Nitrate nitrogen and oxygen isotopes have been widely used to trace the nitrogen biogeochemical cycle by identifying NO(3)(-) sources. An improved method of anion exchange was developed to measure δ(15)N-NO(3)(-) in fresh water by continuous-flow elemental analyzer/isotope ratio mass spectrometry (EA-IRMS). We used a custom-built exchange resin column, a peristaltic pump and the oven-drying method in our experiments. Consequently, the amount of Ag(2)O used as a neutralizer was reduced, time was saved, and operation became simpler than before. Meanwhile, analytical precision remained identical to previous studies. KNO(3) solutions were prepared at 0.2, 5 and 25 mg-N L(-1) from KNO(3) standard salt (δ(15)N=+6.27‰), and the average δ(15)N values of the solutions after having been absorbed on and subsequently stripped from anion columns were +6.62±0.22‰ (n=6), +6.38±0.09‰ (n=6), and +6.26±0.07‰ (n=6), respectively. In addition, the "natural" water sample δ(15)N-NO(3)(-) showed consistency in comparison to standards, and the mean standard deviation by the different approaches was 0.08‰. Accordingly, by these improvements the anion exchange resin technique is demonstrated to be more suitable for measuring δ(15)N in NO(3)(-) than original techniques. PMID:21237315

  9. Molecular effect on equilibrium charge-state distributions. [of nitrogen ions injected through carbon foil

    NASA Technical Reports Server (NTRS)

    Wickholm, D.; Bickel, W. S.

    1976-01-01

    The paper describes an experiment consisting of the acceleration of N(+) and N2(+) ions to energies between 0.25 and 1.75 MeV and their injection through a thin carbon foil, whereupon they were charge-state analyzed with an electrostatic analyzer. A foil-covered electrically suppressed Faraday cup, connected to a stepping motor, moved in the plane of the dispersed beams. The Faraday cup current, which was proportional to the number of incident ions, was sent to a current digitizer and computer programmed as a multiscaler. The energy-dependent charge-state fractions, the mean charge and the distribution width were calculated. It was shown that for incident atoms, the charge state distribution appeared to be spread over more charge states, while for the incident molecules, there was a greater fraction of charge states near the mean charge.

  10. Spirulina platensis growth in open raceway ponds using fresh water supplemented with carbon, nitrogen and metal ions.

    PubMed

    Costa, Jorge Alberto Vieira; Colla, Luciane Maria; Duarte Filho, Paulo

    2003-01-01

    To investigate the feasibility of using fresh water from Mangueira Lagoon (Rio Grande do Sul, Brazil) for biomass production in open raceway ponds (0.7 m long, 0.18 m wide, 0.075 m deep) we studied the influence of nutrient addition (carbon as sodium bicarbonate, nitrogen as urea, phosphate, sulfate, ferric iron, magnesium and potassium) on the growth rate of the cyanobacteria Spirulina platensis using a 22 factorial design. In unsupplemented lagoon water production of S platensis was 0.78 +/- 0.01 g/l (dry weight basis) while the addition of 2.88 g/l of sodium bicarbonate (without added urea, phosphate, sulfate or metal ions) resulted in 0.82 +/- 0.01 g/l after 400 hours of culture. The further addition of phosphate and metal ions resulted in growth for up to 750 h and a final S. platensis biomass of 1.23 +/- 0.04 to 1.34 +/- 0.03 g/l. PMID:12622231

  11. Structure and tribological performance by nitrogen and oxygen plasma based ion implantation on Ti6Al4V alloy

    NASA Astrophysics Data System (ADS)

    Feng, Xingguo; Sun, Mingren; Ma, Xinxin; Tang, Guangze

    2011-09-01

    Ti6Al4V alloy was implanted with nitrogen-oxygen mixture by using plasma based ion implantation (PBII) at pulsed voltage -10, -30 and -50 kV. The implantation was up to 6 × 1017 ions/cm2 fluence. The changes in chemical composition, structure and hardness of the modified surfaces were studied by XPS and nanoindentation measurements. According to XPS, it was found that the modified layer was predominantly TiO2, but contained small amounts of TiO, Ti2O3, TiN and Al2O3 between the outmost layer and metallic substrate. Surface hardness and wear resistance of the samples increased significantly after PBII treatment, the wear rate of the sample implanted N2-O2 mixture at -50 kV decreased eight times than the untreated one. The sample implanted N2-O2 mixture showed better wear resistance than that of the sample only implanted oxygen at - 50 kV. The wear mechanism of untreated sample was abrasive-dominated and adhesive, and the wear scar of the sample implanted at -50 kV was characterized by abrasive wear-type ploughing.

  12. Improvement of Vitamin K2 Production by Escherichia sp. with Nitrogen Ion Beam Implantation Induction

    NASA Astrophysics Data System (ADS)

    Liu, Yan; Wang, Li; Zheng, Zhiming; Wang, Peng; Zhao, Genhai; Liu, Hui; Gong, Guohong; Wu, Hefang; Liu, Hongxia; Tan, Mu; Li, Zhemin

    2015-02-01

    Low-energy ion implantation as a novel mutagen has been increasingly applied in the microbial mutagenesis for its higher mutation frequency and wider mutation spectra. In this work, N+ ion beam implantation was used to enhance Escherichia sp. in vitamin K2 yield. Optimization of process parameters under submerged fermentation was carried out to improve the vitamin K2 yield of mutant FM5-632. The results indicate that an excellent mutant FM5-632 with a yield of 123.2±1.6 μg/L, that is four times that of the original strain, was achieved by eight successive implantations under the conditions of 15 keV and 60×2.6×1013 ions/cm2. A further optimization increased the yield of the mutant by 39.7%, i.e. 172.1±1.2 μg/L which occurred in the mutant cultivated in the optimal fermentation culture medium composed of (per liter): 15.31 g glycerol, 10 g peptone, 2.89 g yeast extract, 5 g K2HPO4, 1 g NaCl, 0.5 g MgSO4·7H2O and 0.04 g cedar wood oil, incubated at 33 °C, pH 7.0 and 180 rpm for 120 h.

  13. Missing Mass Recoiling Against the Charged D

    SciTech Connect

    Cain, Hillary

    2003-09-05

    This paper chronicles the investigation of a peak in the BaBar mass data set of mass recoiling against charged D*s. Our hypothesis is that the peak at 2620 MeV is a reflection of the D{sub s}* and {pi} system. Specifically, we explored the idea that the peak might be a reflection from the decay B {yields} D**{sup -} D*{sub s}{sup +} with the D**{sup -} {yields} D*{sup -} {pi}. Theoretically, when the D**{sup -} decays, the trajectory of the resulting {pi} will form an angle with the D*{sub s}{sup +}, and different angles impart difference masses to the system over a range of a GeV or so. If quantum mechanics dictates that their paths will form a particular angle more often than others, a peak would appear in the histogram of their collective mass. Using the Monte Carlo model of particle collision events, Anders Ryd's EVTGEN program, C++ code derived from GeneratorsQA, and PAW, we tested the hypothesis that the peak might be a reflection of the system, but found that this possible explanation could not account for the peak. No 2620 MeV peak appears in the histogram of the system mass. We therefore discount the hypothesis and conclude that some other reflection, statistical fluctuation, or particle is causing the peak.

  14. Mid-Infrared Spectroscopy of Polycyclic Aromatic Nitrogen Heterocycles (PANHS) and their Ions

    NASA Technical Reports Server (NTRS)

    Mattioda, Andrew L.; Hudgin, Douglas; Bauschlicher, Charles W.; Alamandola, Louis J.

    2003-01-01

    In recent years, polycyclic aromatic nitrogen heterocycles (PANHs) have attracted a good deal of attention because of their potent carcinogenic and mutagenic properties, and their prevalence in our environment. Such species also play a prominent role in the chemistry of life up to and including the very nucleobases from which our DNA is constructed. Surprisingly, these compounds may even be common outside of our terrestrial environment. To wit, it is now widely accepted that polycyclic aromatic materials are abundant in space and represent a major reservoir of organic carbon in the interstellar medium and developing planetary systems. Given that nitrogen is the fourth most abundant chemically reactive element in space (surpassed only by hydrogen, carbon, and oxygen), it is entirely reasonable to suspect that PANHs may represent an important component of that organic reservoir. Motivated by their intrinsic merit and with special attention toward evaluating their exobiological significance, we have initiated a program to study the spectroscopic and chemical properties of P A " s under conditions relevant to extraterrestrial environments. Here we present the first results of that program-infrared spectroscopic measurements on a series of PANH"s in neutral and cationic forms, isolated in inert matrices at cryogenic temperatures.temperatures. The species studied include: 1 -, and 2-azabenz[a]anthracene, 1-, 2-, and 4- azachrysene, dibenz[a,h]acridine, and dibenz[a,J)acridine. The experimental measurements are also compared with theoretical spectra calculated using density functional theory. General spectroscopic trends observed in this series of compounds are discussed and the implications of these results for Astrophysics and Exobiology are considered.

  15. Amperometric Detection of Aqueous Silver Ions by Inhibition of Glucose Oxidase Immobilized on Nitrogen-Doped Carbon Nanotube Electrodes.

    PubMed

    Rust, Ian M; Goran, Jacob M; Stevenson, Keith J

    2015-07-21

    An amperometric glucose biosensor based on immobilization of glucose oxidase on nitrogen-doped carbon nanotubes (N-CNTs) was successfully developed for the determination of silver ions. Upon exposure to glucose, a steady-state enzymatic turnover rate was detected through amperometric oxidation of the H2O2 byproduct, directly related to the concentration of glucose in solution. Inhibition of the steady-state enzymatic glucose oxidase reaction by heavy metals ions such as Ag(+), produced a quantitative decrease in the steady-state rate, subsequently creating an ultrasensitive metal ion biosensor through enzymatic inhibition. The Ag(+) biosensor displayed a sensitivity of 2.00 × 10(8) ± 0.06 M(-1), a limit of detection (σ = 3) of 0.19 ± 0.04 ppb, a linear range of 20-200 nM, and sample recovery at 101 ± 2%, all acquired at a low-operating potential of 0.05 V (vs Hg/Hg2SO4). Interestingly, the biosensor does not display a loss in sensitivity with continued use due to the % inhibition based detection scheme: loss of enzyme (from continued use) does not influence the % inhibition, only the overall current associated with the activity loss. The heavy metals Cu(2+) and Co(2+) were also detected using the enzyme biosensor but found to be much less inhibitory, with sensitivities of 1.45 × 10(6) ± 0.05 M(-1) and 2.69 × 10(3) ± 0.07 M(-1), respectively. The mode of GOx inhibition was examined for both Ag(+) and Cu(2+) using Dixon and Cornish-Bowden plots, where a strong correlation was observed between the inhibition constants and the biosensor sensitivity.

  16. Amperometric Detection of Aqueous Silver Ions by Inhibition of Glucose Oxidase Immobilized on Nitrogen-Doped Carbon Nanotube Electrodes.

    PubMed

    Rust, Ian M; Goran, Jacob M; Stevenson, Keith J

    2015-07-21

    An amperometric glucose biosensor based on immobilization of glucose oxidase on nitrogen-doped carbon nanotubes (N-CNTs) was successfully developed for the determination of silver ions. Upon exposure to glucose, a steady-state enzymatic turnover rate was detected through amperometric oxidation of the H2O2 byproduct, directly related to the concentration of glucose in solution. Inhibition of the steady-state enzymatic glucose oxidase reaction by heavy metals ions such as Ag(+), produced a quantitative decrease in the steady-state rate, subsequently creating an ultrasensitive metal ion biosensor through enzymatic inhibition. The Ag(+) biosensor displayed a sensitivity of 2.00 × 10(8) ± 0.06 M(-1), a limit of detection (σ = 3) of 0.19 ± 0.04 ppb, a linear range of 20-200 nM, and sample recovery at 101 ± 2%, all acquired at a low-operating potential of 0.05 V (vs Hg/Hg2SO4). Interestingly, the biosensor does not display a loss in sensitivity with continued use due to the % inhibition based detection scheme: loss of enzyme (from continued use) does not influence the % inhibition, only the overall current associated with the activity loss. The heavy metals Cu(2+) and Co(2+) were also detected using the enzyme biosensor but found to be much less inhibitory, with sensitivities of 1.45 × 10(6) ± 0.05 M(-1) and 2.69 × 10(3) ± 0.07 M(-1), respectively. The mode of GOx inhibition was examined for both Ag(+) and Cu(2+) using Dixon and Cornish-Bowden plots, where a strong correlation was observed between the inhibition constants and the biosensor sensitivity. PMID:26079664

  17. Mobilities and longitudinal diffusion coefficients for K+ ions in nitrogen and argon

    NASA Astrophysics Data System (ADS)

    Takebe, M.; Satoh, Y.; Iinuma, K.; Seto, K.

    1980-10-01

    We have constructed a drift tube with a movable ion source and measured the mobilities and longitudinal diffusion coefficients for K+ ions at 303 °K in N2 and at 305 °K in Ar in the pressure range 0.3-5.0 Torr, over the E/N range 4-346 Td in N2 and 3-320 Td in Ar. The zero-field reduced mobilities for K+ ions in N2 and Ar were determined to be 2.50±0.03 and 2.63±0.03 cm2/V sec, respectively. Both values are in excellent agreement with the values reported by Elford and Milloy. When our data are compared with the values obtained by Thomson et al. in N2 and the values obtained by James et al. in Ar over the entire E/N range, we find that the mean deviations are about 1.7%, independent of gas species and E/N. Our zero-field reduced mobilities are about 1.2% lower in both cases than the values compiled by Ellis et al. It is concluded that the discrepancy is due to a systematic error and is not caused by clustering reactions. The mean values of NDL over the E/N range 4-7 Td in N2 and 5-10 Td in Ar were found to be 1.96×1018 and 2.09×1018 cm-1 sec-1, respectively. Both values are about 7% higher than the values calculated from our mobility data by the generalized Einstein relation and from the same parameters reported by Pai et al.

  18. Recoil splitting of x-ray-induced optical fluorescence

    SciTech Connect

    Gavrilyuk, S.; Aagren, H.; Gel'mukhanov, F.; Sun, Y.-P.; Levin, S.

    2010-03-15

    We show that the anisotropy of the recoil velocity distribution of x-ray-ionized atoms or molecules leads to observable splittings in subsequent optical fluorescence or absorption when the polarization vector of the x rays is parallel to the momentum of the fluorescent photons. The order of the magnitude of the recoil-induced splitting is about 10 {mu}eV, which can be observed using Fourier or laser-absorption spectroscopic techniques.

  19. RECOILING SUPERMASSIVE BLACK HOLES IN SPIN-FLIP RADIO GALAXIES

    SciTech Connect

    Liu, F. K.; Wang Dong; Chen Xian

    2012-02-20

    Numerical relativity simulations predict that coalescence of supermassive black hole (SMBH) binaries leads not only to a spin flip but also to a recoiling of the merger remnant SMBHs. In the literature, X-shaped radio sources are popularly suggested to be candidates for SMBH mergers with spin flip of jet-ejecting SMBHs. Here we investigate the spectral and spatial observational signatures of the recoiling SMBHs in radio sources undergoing black hole spin flip. Our results show that SMBHs in most spin-flip radio sources have mass ratio q {approx}> 0.3 with a minimum possible value q{sub min} {approx_equal} 0.05. For major mergers, the remnant SMBHs can get a kick velocity as high as 2100 km s{sup -1} in the direction within an angle {approx}< 40 Degree-Sign relative to the spin axes of remnant SMBHs, implying that recoiling quasars are biased to be with high Doppler-shifted broad emission lines while recoiling radio galaxies are biased to large apparent spatial off-center displacements. We also calculate the distribution functions of line-of-sight velocity and apparent spatial off-center displacements for spin-flip radio sources with different apparent jet reorientation angles. Our results show that the larger the apparent jet reorientation angle is, the larger the Doppler-shifting recoiling velocity and apparent spatial off-center displacement will be. We investigate the effects of recoiling velocity on the dust torus in spin-flip radio sources and suggest that recoiling of SMBHs would lead to 'dust-poor' active galactic nuclei. Finally, we collect a sample of 19 X-shaped radio objects and for each object give the probability of detecting the predicted signatures of recoiling SMBH.

  20. Annealing of TiO2 Films Deposited on Si by Irradiating Nitrogen Ion Beams

    SciTech Connect

    Yokota, Katsuhiro; Yano, Yoshinori; Miyashita, Fumiyoshi

    2006-11-13

    Thin TiO2 films were deposited on Si at a temperature of 600 deg. C by an ion beam assisted deposition (IBAD) method. The TiO2 films were annealed for 30 min in Ar at temperatures below 700 deg. C. The as-deposited TiO2 films had high permittivities such 200 {epsilon}o and consisted of crystallites that were not preferentially oriented to the c-axis but had an expanded c-axis. On the annealed TiO2 films, permittivities became lower with increasing annealing temperature, and crystallites were oriented preferentially to the (110) plane.

  1. Uranium (VI) ion exchange on nitrogen-phosphorus-containing polyampholytes in chloride-fluoride solutions

    SciTech Connect

    Pakholkov, V.S.; Denisova, L.A.; Richkov, V.A.; Roshchepkina, L.I.

    1988-09-01

    The adsorption of uranium form UO/sub 2/Cl/sub 2/ solutions containing HCl, NH/sub 4/Cl, and HF has been studied using polyampholyte resins ANKF-1, ANKF-2, and ANKF-3D. The effects of HCl, NH/sub 4/Cl, and HF over broad concentration ranges on uranium adsorption have also been investigated. Based on adsorption data and the results of elemental analysis and IR spectroscopy conclusions have been drawn concerning the composition of adsorbed ions and their binding forms with functional groups. A mathematical model to describe the adsorption process has been proposed.

  2. Calculated yield of isomer depletion due to NEEC for {sup 93m}Mo recoils

    SciTech Connect

    Karamian, S. A.; Carroll, J. J.

    2012-11-15

    In the present work, quantitative calculations were carried out for production and depletion of the {sup 93m}Mo isomer in a relatively simple experiment using {sup 91}Zr beam ions. Such studies could be arranged at existing and operating accelerator facilities, e.g. at GSI or in JINR. The {sup 93m}Mo nuclei produced in a He gas target due to the {sup 4}He({sup 91}Zr, 2n) reaction will recoil into a gas stopper with a high velocity, being then depleted due to NEEC in highly-ionized species.

  3. A stretch/compress scheme for a high temporal resolution detector for the magnetic recoil spectrometer time (MRSt)

    DOE PAGESBeta

    Hilsabeck, T. J.; Frenje, J. A.; Hares, J. D.; Wink, C. W.

    2016-08-02

    Here we present a time-resolved detector concept for the magnetic recoil spectrometer for time-resolved measurements of the NIF neutron spectrum. The measurement is challenging due to the time spreading of the recoil protons (or deuterons) as they transit an energy dispersing magnet system. Ions arrive at the focal plane of the magnetic spectrometer over an interval of tens of nanoseconds. We seek to measure the time-resolved neutron spectrum with 20 ps precision by manipulating an electron signal derived from the ions. A stretch-compress scheme is employed to remove transit time skewing while simultaneously reducing the bandwidth requirements for signal recording.more » Simulation results are presented along with design concepts for structures capable of establishing the required electromagnetic fields.« less

  4. A stretch/compress scheme for a high temporal resolution detector for the magnetic recoil spectrometer time (MRSt)

    NASA Astrophysics Data System (ADS)

    Hilsabeck, T. J.; Frenje, J. A.; Hares, J. D.; Wink, C. W.

    2016-11-01

    A time-resolved detector concept for the magnetic recoil spectrometer for time-resolved measurements of the NIF neutron spectrum is presented. The measurement is challenging due to the time spreading of the recoil protons (or deuterons) as they transit an energy dispersing magnet system. Ions arrive at the focal plane of the magnetic spectrometer over an interval of tens of nanoseconds. We seek to measure the time-resolved neutron spectrum with 20 ps precision by manipulating an electron signal derived from the ions. A stretch-compress scheme is employed to remove transit time skewing while simultaneously reducing the bandwidth requirements for signal recording. Simulation results are presented along with design concepts for structures capable of establishing the required electromagnetic fields.

  5. Conformational ordering of biomolecules in the gas phase: nitrogen collision cross sections measured on a prototype high resolution drift tube ion mobility-mass spectrometer.

    PubMed

    May, Jody C; Goodwin, Cody R; Lareau, Nichole M; Leaptrot, Katrina L; Morris, Caleb B; Kurulugama, Ruwan T; Mordehai, Alex; Klein, Christian; Barry, William; Darland, Ed; Overney, Gregor; Imatani, Kenneth; Stafford, George C; Fjeldsted, John C; McLean, John A

    2014-02-18

    Ion mobility-mass spectrometry measurements which describe the gas-phase scaling of molecular size and mass are of both fundamental and pragmatic utility. Fundamentally, such measurements expand our understanding of intrinsic intramolecular folding forces in the absence of solvent. Practically, reproducible transport properties, such as gas-phase collision cross-section (CCS), are analytically useful metrics for identification and characterization purposes. Here, we report 594 CCS values obtained in nitrogen drift gas on an electrostatic drift tube ion mobility-mass spectrometry (IM-MS) instrument. The instrument platform is a newly developed prototype incorporating a uniform-field drift tube bracketed by electrodynamic ion funnels and coupled to a high resolution quadrupole time-of-flight mass spectrometer. The CCS values reported here are of high experimental precision (±0.5% or better) and represent four chemically distinct classes of molecules (quaternary ammonium salts, lipids, peptides, and carbohydrates), which enables structural comparisons to be made between molecules of different chemical compositions for the rapid "omni-omic" characterization of complex biological samples. Comparisons made between helium and nitrogen-derived CCS measurements demonstrate that nitrogen CCS values are systematically larger than helium values; however, general separation trends between chemical classes are retained regardless of the drift gas. These results underscore that, for the highest CCS accuracy, care must be exercised when utilizing helium-derived CCS values to calibrate measurements obtained in nitrogen, as is the common practice in the field.

  6. Nitrogen-doped graphene-decorated LiVPO4F nanocomposite as high-voltage cathode material for rechargeable lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Cui, Kai; Hu, Shuchun; Li, Yongkui

    2016-09-01

    In this study, nitrogen-doped graphene decorated LiVPO4F cathode material is firstly synthesized via a facile method. Well-dispersed LiVPO4F nanoparticles are embedded in nitrogen-doped graphene nanosheets, forming an effective conducting network. The added nitrogen-doped graphene nanosheets greatly enhance the electronic conductivity and Li-ion diffusion of LiVPO4F sample. When tested as cathode material for rechargeable lithium-ion batteries, the hybrid electrode exhibits superior high-rate performance and long-term cycling stability between 3.0 and 4.5 V. It delivers a large discharge capacity of 152.7 mAhg-1 at 0.1 C and shows a capacity retention of 97.8% after 60 cycles. Moreover, a reversible capacity of 90.1 mAhg-1 is maintained even after 500 cycles at a high rate of 20 C. The charge-transfer resistance of LiVPO4F electrode is also reduced in the nitrogen-doped graphene, revealing that its electrode-electrolyte complex reactions take place easily and thus improve the electrochemical performance. The above results provide a facile and effective strategy for the synthesis of LiVPO4F cathode material for high-performance lithium-ion batteries.

  7. Irradiation of nitrogen-rich ices by swift heavy ions. Clues for the formation of ultracarbonaceous micrometeorites

    NASA Astrophysics Data System (ADS)

    Augé, B.; Dartois, E.; Engrand, C.; Duprat, J.; Godard, M.; Delauche, L.; Bardin, N.; Mejía, C.; Martinez, R.; Muniz, G.; Domaracka, A.; Boduch, P.; Rothard, H.

    2016-08-01

    Context. Extraterrestrial materials, such as meteorites and interplanetary dust particles, provide constraints on the formation and evolution of organic matter in the young solar system. Micrometeorites represent the dominant source of extraterrestrial matter at the Earth's surface, some of them originating from large heliocentric distances. Recent analyses of ultracarbonaceous micrometeorites recovered from Antarctica (UCAMMs) reveal an unusually nitrogen-rich organic matter. Such nitrogen-rich carbonaceous material could be formed in a N2-rich environment, at very low temperature, triggered by energetic processes. Aims: Several formation scenarios have been proposed for the formation of the N-rich organic matter observed in UCAMMs. We experimentally evaluate the scenario involving high energy irradiation of icy bodies subsurface orbiting at large heliocentric distances. Methods: The effect of Galactic cosmic ray (GCR) irradiation of ices containing N2 and CH4 was studied in the laboratory. The N2-CH4 (90:10 and 98:2) ice mixtures were irradiated at 14 K by 44 MeV Ni11+ and 160 MeV Ar15+ swift heavy ion beams. The evolution of the samples was monitored using in-situ Fourier transform infrared spectroscopy. The evolution of the initial ice molecules and new species formed were followed as a function of projectile fluence. After irradiation, the target was annealed to room temperature. The solid residue of the whole process left after ice sublimation was characterized in-situ by infrared spectroscopy, and the elemental composition was measured ex-situ. Results: The infrared bands that appear during irradiation allow us to identify molecules and radicals (HCN, CN-, NH3, ...). The infrared spectra of the solid residues measured at room temperature show similarities with that of UCAMMs. The results point towards the efficient production of a poly-HCN-like residue from the irradiation of N2-CH4 rich surfaces of icy bodies. The room temperature residue provides a viable

  8. Supramolecular complexes obtained from the interaction of violuric acid with manganese ion and nitrogenous ligands

    NASA Astrophysics Data System (ADS)

    Garcia, Humberto C.; Diniz, Renata; Speziali, Nivaldo L.; de Oliveira, Luiz Fernando C.

    2014-07-01

    This work describes the synthesis, spectroscopic characterization (Raman and infrared) and structural arrangement of three new supramolecular complexes named [Mn(H2Vi)2(H2O)4)](bpy)2(1), [Mn(bpa)2(H2O)4](H2Vi)2(2) and [Mn(bpp)2(H2Vi)2]·(bpp)2(H2O)2(3); these compounds have been obtained making use of different building blocks such as 4,4‧-bipyridyne (bpy), 1,2-bis(4-pyridyl)ethane (bpa) and 4,4‧-trimethylene-dipyridine (bpp) acting as spacers with violuric acid and manganese ion, presenting behavior related to processes of molecular self-assembling and self-organization, very common in studies of supramolecular systems. In all these compounds the violurate anion appears in the crystalline arrangement as monodentate, anionic and chelate forms for 1, 2 and 3, respectively. The important to note is that monodentate coordination in 1 and chelate in 3 through O2 and O3 oxygen atoms from the oxime group can be considered the first example in literature involving violuric acid, both in coordination or interaction with manganese ion. Moreover, it can be seen a good agreement between the structural results and the spectroscopic data; for instance the presence of an intense band in the Raman spectrum around 1603 and 1012 cm-1 in all obtained compounds, assigned to the ν(CC)/ν(CN) and ν(ring)modes of the pyridyl ligand, respectively. Other important band can be observed in 1031 cm-1 only for compound 3, assigned to the ν(Nsbnd O) mode of the violurate ligand; the band at 1284 cm-1 referring to the ν(Ndbnd O) mode, very characteristic of violurate species is not seen in the spectrum, thus confirming the coordination of this building block by the oxime moiety.

  9. Recoil-α-fission and recoil-α-α-fission events observed in the reaction 48Ca + 243Am

    NASA Astrophysics Data System (ADS)

    Forsberg, U.; Rudolph, D.; Andersson, L.-L.; Di Nitto, A.; Düllmann, Ch. E.; Fahlander, C.; Gates, J. M.; Golubev, P.; Gregorich, K. E.; Gross, C. J.; Herzberg, R.-D.; Heßberger, F. P.; Khuyagbaatar, J.; Kratz, J. V.; Rykaczewski, K.; Sarmiento, L. G.; Schädel, M.; Yakushev, A.; Åberg, S.; Ackermann, D.; Block, M.; Brand, H.; Carlsson, B. G.; Cox, D.; Derkx, X.; Dobaczewski, J.; Eberhardt, K.; Even, J.; Gerl, J.; Jäger, E.; Kindler, B.; Krier, J.; Kojouharov, I.; Kurz, N.; Lommel, B.; Mistry, A.; Mokry, C.; Nazarewicz, W.; Nitsche, H.; Omtvedt, J. P.; Papadakis, P.; Ragnarsson, I.; Runke, J.; Schaffner, H.; Schausten, B.; Shi, Yue; Thörle-Pospiech, P.; Torres, T.; Traut, T.; Trautmann, N.; Türler, A.; Ward, A.; Ward, D. E.; Wiehl, N.

    2016-09-01

    Products of the fusion-evaporation reaction 48Ca + 243Am were studied with the TASISpec set-up at the gas-filled separator TASCA at the GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt, Germany. Amongst the detected thirty correlated α-decay chains associated with the production of element Z = 115, two recoil-α-fission and five recoil- α- α-fission events were observed. The latter five chains are similar to four such events reported from experiments performed at the Dubna gas-filled separator, and three such events reported from an experiment at the Berkeley gas-filled separator. The four chains observed at the Dubna gas-filled separator were assigned to start from the 2n-evaporation channel 289115 due to the fact that these recoil- α- α-fission events were observed only at low excitation energies. Contrary to this interpretation, we suggest that some of these recoil- α- α-fission decay chains, as well as some of the recoil- α- α-fission and recoil-α-fission decay chains reported from Berkeley and in this article, start from the 3n-evaporation channel 288115.

  10. Energy Storage: Nitrogen-Doped Ordered Mesoporous Anatase TiO2 Nanofibers as Anode Materials for High Performance Sodium-Ion Batteries (Small 26/2016).

    PubMed

    Wu, Ying; Liu, Xiaowu; Yang, Zhenzhong; Gu, Lin; Yu, Yan

    2016-07-01

    On page 3522, Y. Yu and co-workers fabricate nitrogen-doped ordered mesoporous TiO2 nanofibers (denoted as N-MTO) by electrospinning and subsequent nitridation treatment. Nitrogen atoms are successfully doped into the TiO2 lattice, accompanied by the formation of Ti(3+) and oxygen vacancies, contributing to the improvement of electronic conductivity of TiO2 . When used as an anode for a sodium-ion battery, the N-MTO demonstrates excellent rate capability and superior long cycling performance. PMID:27383035

  11. Energy Storage: Nitrogen-Doped Ordered Mesoporous Anatase TiO2 Nanofibers as Anode Materials for High Performance Sodium-Ion Batteries (Small 26/2016).

    PubMed

    Wu, Ying; Liu, Xiaowu; Yang, Zhenzhong; Gu, Lin; Yu, Yan

    2016-07-01

    On page 3522, Y. Yu and co-workers fabricate nitrogen-doped ordered mesoporous TiO2 nanofibers (denoted as N-MTO) by electrospinning and subsequent nitridation treatment. Nitrogen atoms are successfully doped into the TiO2 lattice, accompanied by the formation of Ti(3+) and oxygen vacancies, contributing to the improvement of electronic conductivity of TiO2 . When used as an anode for a sodium-ion battery, the N-MTO demonstrates excellent rate capability and superior long cycling performance.

  12. Source apportionment of ammonium and nitrate ion using nitrogen stable isotope

    NASA Astrophysics Data System (ADS)

    Kawashima, H.

    2013-12-01

    Suspended particulate matter (SPM), defined to particle size as 100 % cut-off aerodynamic diameter at 10 μm, has adverse effects on human health. In these years, stable isotope ratio of small sample volume can be analyzed high precision by isotope ratio mass spectrometry coupling with elemental analyzer. Recently some fields are using stable isotope ratio. For environmental field, it is expected such as powerful tool for source identification and understanding mechanism. But the existed researches intended for stable nitrogen isotope (δ15N) of particulate matter have been limited. We try to analysis δ15N-ammonium (δ15N-NH4+) and nitrate (δ15N-NO3-) of SPM, to estimate source of NH4+ and NO3- of SPM. Average δ15N-NH4+ and δ15N-NO3- of SPM in Akita prefecture, Japan were 15.9 ‰ (1.3‰ to 38.5 ‰) and - 0.7 ‰ (-4.6 ‰ to 4.8 ‰), respectively. Although δ15N-NH4+ do not show seasonal trend, δ15N-NO3- increased in winter markedly and decreasing in summer. In generally, the dominant origin of NO3- of SPM is produced from NOx emitted by combustion of some fuel and NO by agriculture source. Heaton (1990) summarized that δ15N-NOx is very different by temperature of combustion. They insisted that δ15N-NOx values are between -13 ‰ to -2 ‰ over 2000 °C (e.g. vehicle engine) and 6 ‰ to 13 ‰ under 1300 °C (e.g. coal combustion). Therefore, the reason of the winter high trend in this study might be combustion process such as coal combustion source. Moreover, the baseline might be made by vehicle sources. In addition, the reason of decreasing in summer seemed to be affected very low δ15N-NO of fertilizer and urea indicated by Li and Wang (2008). Bacteria were activated in summer, and NO from fertilizer and urea was emitted. This summary seemed to be very reasonable.

  13. Nitrogen-doped porous carbon/Co3O4 nanocomposites as anode materials for lithium-ion batteries.

    PubMed

    Wang, Li; Zheng, Yaolin; Wang, Xiaohong; Chen, Shouhui; Xu, Fugang; Zuo, Li; Wu, Jiafeng; Sun, Lanlan; Li, Zhuang; Hou, Haoqing; Song, Yonghai

    2014-05-28

    A simple and industrially scalable approach to prepare porous carbon (PC) with high surface areas as well as abundant nitrogen element as anode supporting materials for lithium-ion batteries (LIBs) was developed. Herein, the N-doped PC was prepared by carbonizing crawfish shell, which is a kind of food waste with abundant marine chitin as well as a naturally porous structure. The porous structure can be kept to form the N-doped PC in the pyrolysis process. The N-doped PC-Co3O4 nanocomposites were synthesized by loading Co3O4 on the N-doped PC as anode materials for LIBs. The resulting N-doped PC-Co3O4 nanocomposites release an initial discharge of 1223 mA h g(-1) at a current density of 100 mA g(-1) and still maintain a high reversible capacity of 1060 mA h g(-1) after 100 cycles, which is higher than that of individual N-doped PC or Co3O4. Particularly, the N-doped PC-Co3O4 nanocomposites can be prepared in a large yield with a low cost because the N-doped PC is derived from abundant natural waste resources, which makes it a promising anode material for LIBs.

  14. Designing nitrogen-enriched echinus-like carbon capsules for highly efficient oxygen reduction reaction and lithium ion storage.

    PubMed

    Hu, Chuangang; Wang, Lixia; Zhao, Yang; Ye, Minhui; Chen, Qing; Feng, Zhihai; Qu, Liangti

    2014-07-21

    Both structural and compositional modulations are important for high-performance electrode materials in energy conversion/storage devices. Here hierarchical-structure nitrogen-rich hybrid porous carbon capsules with bamboo-like carbon nanotube whiskers (N-CC@CNTs) grown in situ have been specifically designed, which combine the advantageous features of high surface area, abundant active sites, easy access to medium and favorable mass transport. As a result, the newly prepared N-CC@CNTs show highly efficient catalytic activity in oxygen reduction reaction in alkaline media for fuel cells, which not only outperforms commercial Pt-based catalysts in terms of kinetic limiting current, stability and tolerance to methanol crossover effect, but is also better than most of the nanostructured carbon-based catalysts reported previously. On the other hand, as an anode material for lithium ion batteries, the N-CC@CNTs obtained also exhibit an excellent reversible capacity of ca. 1337 mA h g(-1) at 0.5 A g(-1), outstanding rate capability and long cycling stability, even at a current density of 20 A g(-1). The capacity is the highest among all the heteroatom-doped carbon materials reported so far, and is even higher than that of many of the composites of metal, metal oxides or metal sulfides with carbon materials. PMID:24906180

  15. Designing nitrogen-enriched echinus-like carbon capsules for highly efficient oxygen reduction reaction and lithium ion storage.

    PubMed

    Hu, Chuangang; Wang, Lixia; Zhao, Yang; Ye, Minhui; Chen, Qing; Feng, Zhihai; Qu, Liangti

    2014-07-21

    Both structural and compositional modulations are important for high-performance electrode materials in energy conversion/storage devices. Here hierarchical-structure nitrogen-rich hybrid porous carbon capsules with bamboo-like carbon nanotube whiskers (N-CC@CNTs) grown in situ have been specifically designed, which combine the advantageous features of high surface area, abundant active sites, easy access to medium and favorable mass transport. As a result, the newly prepared N-CC@CNTs show highly efficient catalytic activity in oxygen reduction reaction in alkaline media for fuel cells, which not only outperforms commercial Pt-based catalysts in terms of kinetic limiting current, stability and tolerance to methanol crossover effect, but is also better than most of the nanostructured carbon-based catalysts reported previously. On the other hand, as an anode material for lithium ion batteries, the N-CC@CNTs obtained also exhibit an excellent reversible capacity of ca. 1337 mA h g(-1) at 0.5 A g(-1), outstanding rate capability and long cycling stability, even at a current density of 20 A g(-1). The capacity is the highest among all the heteroatom-doped carbon materials reported so far, and is even higher than that of many of the composites of metal, metal oxides or metal sulfides with carbon materials.

  16. Nitrogen-Enriched Porous Carbon Coating for Manganese Oxide Nanostructures toward High-Performance Lithium-Ion Batteries.

    PubMed

    Wang, Jiangan; Zhang, Cunbao; Kang, Feiyu

    2015-05-01

    Manganese oxides are promising high-capacity anode materials for lithium-ion batteries (LIBs) yet suffer from short cycle life and poor rate capability. Herein, we demonstrate a facile in situ interfacial synthesis of core-shell heterostructures comprising nitrogen-enriched porous carbon (pN-C) nanocoating and manganese oxide (MnOx) nanotubes. When MnOx/pN-C serves as an anode material for LIBs, the pN-C coating plays multiple roles in substantially improving the lithium storage performance. In combination with the nanosized structure and nanotubular architecture, the MnOx/pN-C nanocomposites exhibit an impressive reversible capacity of 1068 mAh g(-1) at 100 mA g(-1), a high-rate delivery of 361 mAh g(-1) at 8 A g(-1), and a stable cycling retention up to 300 cycles. The surface pN-C coating strategy can be extended to design and fabricate various metal oxide nanostructures for high-performance LIBs. PMID:25871883

  17. Traditional and ion-pair halogen-bonded complexes between chlorine and bromine derivatives and a nitrogen-heterocyclic carbene.

    PubMed

    Donoso-Tauda, Oscar; Jaque, Pablo; Elguero, José; Alkorta, Ibon

    2014-10-01

    A theoretical study of the halogen-bonded complexes (A-X···C) formed between halogenated derivatives (A-X; A = F, Cl, Br, CN, CCH, CF3, CH3, H; and X = Cl, Br) and a nitrogen heterocyclic carbene, 1,3-dimethylimidazole-2-ylidene (MeIC) has been performed using MP2/aug'-cc-pVDZ level of theory. Two types of A-X:MeIC complexes, called here type-I and -II, were found and characterized. The first group is described by long C-X distances and small binding energies (8-54 kJ·mol(-1)). In general, these complexes show the traditional behavior of systems containing halogen-bonding interactions. The second type is characterized by short C-X distances and large binding energies (148-200 kJ·mol(-1)), and on the basis of the topological analysis of the electron density, they correspond to ion-pair halogen-bonded complexes. These complexes can be seen as the interaction between two charged fragments: A(-) and (+)[X-CIMe] with a high electrostatic contribution in the binding energy. The charge transfer between lone pair A(LP) to the σ* orbital of C-X bond is also identified as a significant stabilizing interaction in type-II complexes.

  18. Hyperthermal (1-100 eV) nitrogen ion scattering damage to D-ribose and 2-deoxy-D-ribose films.

    PubMed

    Deng, Zongwu; Bald, Ilko; Illenberger, Eugen; Huels, Michael A

    2007-10-14

    Highly charged heavy ion traversal of a biological medium can produce energetic secondary fragment ions. These fragment ions can in turn cause collisional and reactive scattering damage to DNA. Here we report hyperthermal (1-100 eV) scattering of one such fragment ion (N(+)) from biologically relevant sugar molecules D-ribose and 2-deoxy-D-ribose condensed on polycrystalline Pt substrate. The results indicate that N(+) ion scattering at kinetic energies down to 10 eV induces effective decomposition of both sugar molecules and leads to the desorption of abundant cation and anion fragments. Use of isotope-labeled molecules (5-(13)C D-ribose and 1-D D-ribose) partly reveals some site specificity of the fragment origin. Several scattering reactions are also observed. Both ionic and neutral nitrogen atoms abstract carbon from the molecules to form CN(-) anion at energies down to approximately 5 eV. N(+) ions also abstract hydrogen from hydroxyl groups of the molecules to form NH(-) and NH(2) (-) anions. A fraction of OO(-) fragments abstract hydrogen to form OH(-). The formation of H(3)O(+) ions also involves hydrogen abstraction as well as intramolecular proton transfer. These findings suggest a variety of severe damaging pathways to DNA molecules which occur on the picosecond time scale following heavy ion irradiation of a cell, and prior to the late diffusion-limited homogeneous chemical processes.

  19. Hyperthermal (1-100 eV) nitrogen ion scattering damage to D-ribose and 2-deoxy-D-ribose films.

    PubMed

    Deng, Zongwu; Bald, Ilko; Illenberger, Eugen; Huels, Michael A

    2007-10-14

    Highly charged heavy ion traversal of a biological medium can produce energetic secondary fragment ions. These fragment ions can in turn cause collisional and reactive scattering damage to DNA. Here we report hyperthermal (1-100 eV) scattering of one such fragment ion (N(+)) from biologically relevant sugar molecules D-ribose and 2-deoxy-D-ribose condensed on polycrystalline Pt substrate. The results indicate that N(+) ion scattering at kinetic energies down to 10 eV induces effective decomposition of both sugar molecules and leads to the desorption of abundant cation and anion fragments. Use of isotope-labeled molecules (5-(13)C D-ribose and 1-D D-ribose) partly reveals some site specificity of the fragment origin. Several scattering reactions are also observed. Both ionic and neutral nitrogen atoms abstract carbon from the molecules to form CN(-) anion at energies down to approximately 5 eV. N(+) ions also abstract hydrogen from hydroxyl groups of the molecules to form NH(-) and NH(2) (-) anions. A fraction of OO(-) fragments abstract hydrogen to form OH(-). The formation of H(3)O(+) ions also involves hydrogen abstraction as well as intramolecular proton transfer. These findings suggest a variety of severe damaging pathways to DNA molecules which occur on the picosecond time scale following heavy ion irradiation of a cell, and prior to the late diffusion-limited homogeneous chemical processes. PMID:17935431

  20. Median recoil direction as a WIMP directional detection signal

    SciTech Connect

    Green, Anne M.; Morgan, Ben

    2010-03-15

    Direct detection experiments have reached the sensitivity to detect dark matter weakly interacting massive particles (WIMPs). Demonstrating that a putative signal is due to WIMPs, and not backgrounds, is a major challenge, however. The direction dependence of the WIMP scattering rate provides a potential WIMP 'smoking gun'. If the WIMP distribution is predominantly smooth, the Galactic recoil distribution is peaked in the direction opposite to the direction of Solar motion. Previous studies have found that, for an ideal detector, of order 10 WIMP events would be sufficient to reject isotropy, and rule out an isotropic background. We examine how the median recoil direction could be used to confirm the WIMP origin of an anisotropic recoil signal. Specifically, we determine the number of events required to confirm the direction of solar motion as the median inverse recoil direction at 95% confidence. We find that for zero background 31 events are required, a factor of {approx}2 more than are required to simply reject isotropy. We also investigate the effect of a nonzero isotropic background. As the background rate is increased the number of events required increases, initially fairly gradually and then more rapidly, once the signal becomes subdominant. We also discuss the effect of features in the speed distribution at large speeds, as found in recent high resolution simulations, on the median recoil direction.

  1. Stimulated Rayleigh resonances and recoil-induced effects

    SciTech Connect

    Courtois, J.Y.; Grynberg, G.

    1996-12-31

    The organization of this paper is as follows. We present in Section II the basic ideas about stimulated Rayleigh scattering by considering more particularly the situation where it arises from a relaxation process going on in the material system, and we describe a few experimental observations made in atomic and molecular physics. We then consider the case of nonstationary two-level atoms, and we derive the shape and characteristics of the recoil-induced resonances (Section III). In particular, we show that these resonances can be interpreted either as originating from a stimulated Rayleigh effect or as a stimulated Raman phenomena between atomic energy-momentum states having different momenta. Finally, to make a clear distinction between the physical phenomena that pertain directly to recoil-induced processes (i.e., that actually permit the measurement of the photon recoil) and those for which the introduction of the recoil constitutes a mere physical convenience, we review in Section IV some indisputable manifestations of the photon recoil in atomic and molecular physics. 92 refs., 22 figs.

  2. Synthesis and characterization of novel nitrogen-containing ligands for metal ion separations

    NASA Astrophysics Data System (ADS)

    Hoch, Cortney Leigh

    A serious limiting factor in the continued development of nuclear power is the disposal of high-level radioactive waste from spent nuclear fuel. The PUREX process can be used for the recovery of U and Pu, but it does not separate the products of fission which are potentially useful, but currently cause most of our problems with radioactive waste. An important complicating factor is the presence of large amounts of lanthanides in dissolved spent nuclear fuel. The separation of lanthanides (Ln) from actinides (An) is therefore critical to the future of nuclear power. One approach to recovering these materials and decreasing the volume of the radioactive waste is the development of novel, highly selective organic ligands for the lanthanide and actinide ions. The focus of this dissertation is to design and synthesize new tridentate polyaza-ligands expected to exhibit affinity for first-row transition metals, lanthanides and actinides. In general, these chelating agents are structurally and functionally related to the pyridine and bipyridine bis-triazinyl compounds that have been investigated for potential application as separations agents for radioactive materials. Selected 1,2,3-triazoles have been synthesized using Sharpless' "Click Chemistry". Variation of the backbone and substituents on the triazole ring allows for facile modification of the cation binding pocket and phase compatibility properties of the new compounds. Characterization of the new ligands was performed using conventional analytical methods. Overall, the studies with three different ligands revealed useful information about the continuing effort of ligand design for actinide (III)/lanthanide (III) separations. Crystal structures established the purity of the organic molecules by showing that the PTMP and BDTP ligands are able to bind transition metals. Also, it was shown that the BDTB ligand was able to bind to Nd 3+ as observed from the spectrophotometric titrations and the calculated binding

  3. A new method for the determination of the nitrogen content of nitrocellulose based on the molar ratio of nitrite-to-nitrate ions released after alkaline hydrolysis.

    PubMed

    Alinat, Elodie; Delaunay, Nathalie; Archer, Xavier; Mallet, Jean-Maurice; Gareil, Pierre

    2015-04-01

    A new method was proposed to determine the nitrogen content of nitrocelluloses (NCs). It is based on the finding of a linear relationship between the nitrogen content and the molar ratio of nitrite-to-nitrate ions released after alkaline hydrolysis. Capillary electrophoresis was used to monitor the concentration of nitrite and nitrate ions. The influences of hydrolysis time and molar mass of NC on the molar ratio of nitrite-to-nitrate ions were investigated, and new insights into the understanding of the alkaline denitration mechanism of NCs, underlying this analytical strategy is provided. The method was then tested successfully with various explosive and non-explosive NC-containing samples such as various daily products and smokeless gunpowders. Inherently to its principle exploiting a concentration ratio, this method shows very good repeatability in the determination of nitrogen content in real samples with relative standard deviation (n = 3) inferior to 1.5%, and also provides very significant advantages with respect to sample extraction, analysis time (1h for alkaline hydrolysis, 3 min for electrophoretic separation), which was about 5 times shorter than for the classical Devarda's method, currently used in industry, and safety conditions (no need for preliminary drying NC samples, mild hydrolysis conditions with 1M sodium hydroxide for 1h at 60 °C). PMID:25562808

  4. A new method for the determination of the nitrogen content of nitrocellulose based on the molar ratio of nitrite-to-nitrate ions released after alkaline hydrolysis.

    PubMed

    Alinat, Elodie; Delaunay, Nathalie; Archer, Xavier; Mallet, Jean-Maurice; Gareil, Pierre

    2015-04-01

    A new method was proposed to determine the nitrogen content of nitrocelluloses (NCs). It is based on the finding of a linear relationship between the nitrogen content and the molar ratio of nitrite-to-nitrate ions released after alkaline hydrolysis. Capillary electrophoresis was used to monitor the concentration of nitrite and nitrate ions. The influences of hydrolysis time and molar mass of NC on the molar ratio of nitrite-to-nitrate ions were investigated, and new insights into the understanding of the alkaline denitration mechanism of NCs, underlying this analytical strategy is provided. The method was then tested successfully with various explosive and non-explosive NC-containing samples such as various daily products and smokeless gunpowders. Inherently to its principle exploiting a concentration ratio, this method shows very good repeatability in the determination of nitrogen content in real samples with relative standard deviation (n = 3) inferior to 1.5%, and also provides very significant advantages with respect to sample extraction, analysis time (1h for alkaline hydrolysis, 3 min for electrophoretic separation), which was about 5 times shorter than for the classical Devarda's method, currently used in industry, and safety conditions (no need for preliminary drying NC samples, mild hydrolysis conditions with 1M sodium hydroxide for 1h at 60 °C).

  5. Application of an online ion-chromatography-based instrument for gradient flux measurements of speciated nitrogen and sulfur

    NASA Astrophysics Data System (ADS)

    Rumsey, Ian C.; Walker, John T.

    2016-06-01

    The dry component of total nitrogen and sulfur atmospheric deposition remains uncertain. The lack of measurements of sufficient chemical speciation and temporal extent make it difficult to develop accurate mass budgets and sufficient process level detail is not available to improve current air-surface exchange models. Over the past decade, significant advances have been made in the development of continuous air sampling measurement techniques, resulting with instruments of sufficient sensitivity and temporal resolution to directly quantify air-surface exchange of nitrogen and sulfur compounds. However, their applicability is generally restricted to only one or a few of the compounds within the deposition budget. Here, the performance of the Monitor for AeRosols and GAses in ambient air (MARGA 2S), a commercially available online ion-chromatography-based analyzer is characterized for the first time as applied for air-surface exchange measurements of HNO3, NH3, NH4+, NO3-, SO2 and SO42-. Analytical accuracy and precision are assessed under field conditions. Chemical concentrations gradient precision are determined at the same sampling site. Flux uncertainty measured by the aerodynamic gradient method is determined for a representative 3-week period in fall 2012 over a grass field. Analytical precision and chemical concentration gradient precision were found to compare favorably in comparison to previous studies. During the 3-week period, percentages of hourly chemical concentration gradients greater than the corresponding chemical concentration gradient detection limit were 86, 42, 82, 73, 74 and 69 % for NH3, NH4+, HNO3, NO3-, SO2 and SO42-, respectively. As expected, percentages were lowest for aerosol species, owing to their relatively low deposition velocities and correspondingly smaller gradients relative to gas phase species. Relative hourly median flux uncertainties were 31, 121, 42, 43, 67 and 56 % for NH3, NH4+, HNO3, NO3-, SO2 and SO42-, respectively. Flux

  6. Recoil separator ERNA: acceptances in angle and energy

    NASA Astrophysics Data System (ADS)

    Rogalla, D.; Schürmann, D.; Strieder, F.; Aliotta, M.; DeCesare, N.; DiLeva, A.; Lubritto, C.; D'Onofrio, A.; Gialanella, L.; Imbriani, G.; Kluge, J.; Ordine, A.; Roca, V.; Röcken, H.; Rolfs, C.; Romano, M.; Schümann, F.; Terrasi, F.; Trautvetter, H. P.

    2003-11-01

    For improved cross-section measurements of the reaction 12C(α,γ) 16O in inverted kinematics, a recoil separator ERNA is developed at the 4 MV Dynamitron tandem accelerator in Bochum to detect directly the 16O recoils with high efficiency. Due to the emission of the capture γ-rays, the kinematically forward directed 16O recoils are described by an angle and energy spread. Thus, the acceptances in angle and energy of ERNA must cover these spreads in order to extract reliable cross-section values. We report on such acceptance measurements over the energy range Ecm=0.7-5.0 MeV, using an 16O pilot beam.

  7. Accounting for Recoil Effects in Geochronometers: A New Model Approach

    NASA Astrophysics Data System (ADS)

    Lee, V. E.; Huber, C.

    2012-12-01

    A number of geologically important chronometers are affected by, or owe their utility to, the "recoil effect". This effect describes the physical displacement of a nuclide due to energetic nuclear processes such as radioactive alpha decay (as in the case of various parent-daughter pairs in the uranium-series decay chains, and Sm-Nd), as well as neutron irradiation (in the case of the methodology for the 40Ar/39Ar dating method). The broad range of affected geochronometers means that the recoil effect can impact a wide range of dating method applications in the geosciences, including but not limited to: Earth surface processes, paleoclimate, volcanic processes, and cosmochemistry and planetary evolution. In particular, the recoil effect can have a notable impact on the use of fine grains (silt- and clay-sized particles) for geochronometric dating purposes. This is because recoil-induced loss of a nuclide from the surfaces of a grain can create an isotopically-depleted outer rind, and for small grains, this depleted rind can be volumetrically significant. When this recoil loss is measurable and occurs in a known time-dependent fashion, it can usefully serve as the basis for chronometers (such as the U-series comminution age method); in other cases recoil loss from fine particles creates an unwanted deviation from expected isotope values (such as for the Ar-Ar method). To improve both the accuracy and precision of ages inferred from geochronometric systems that involve the recoil of a key nuclide from small domains, it is necessary to quantify the magnitude of the recoil loss of that particular nuclide. It is also necessary to quantitatively describe the effect of geological processes that can alter the outer surface of grains, and hence the isotopically-depleted rind. Here we present a new mathematical and numerical model that includes two main features that enable enhanced accuracy and precision of ages determined from geochronometers. Since the surface area of the

  8. Nuclear Recoil Calibration of DarkSide-50

    NASA Astrophysics Data System (ADS)

    Edkins, Erin; DarkSide Collaboration

    2016-03-01

    DarkSide-50 dark matter experiment is a liquid argon time projection chamber (TPC) surrounded by a liquid scintillator active neutron veto, designed for the direct detection of Weakly Interacting Massive Particles (WIMPs). The success of such an experiment is dependent upon a detailed understanding of both the expected signal and backgrounds, achieved using radioactive calibration sources of known energies. Nuclear recoils provide a measurement of both the expected signal and the most dangerous background, as nuclear recoils from neutrons cannot be distinguished from a dark matter signal on an event-by-event basis in the TPC. In this talk, I will present the DS-50 calibration system, and analysis of the results of the calibration of DarkSide-50 to nuclear recoils using radioactive neutron sources. See also the DS-50 presentations by X. Xiang and G. Koh.

  9. Rupture and recoil of bent-core liquid crystal filaments.

    PubMed

    Salili, S M; Ostapenko, T; Kress, O; Bailey, C; Weissflog, W; Harth, K; Eremin, A; Stannarius, R; Jákli, A

    2016-05-25

    The recoil process of free-standing liquid crystal filaments is investigated experimentally and theoretically. We focus on two aspects, the contraction speed of the filament and a spontaneously formed undulation instability. At the moment of rupture, the filaments buckle similarly to the classical Euler buckling of elastic rods. The tip velocity decays with decreasing filament length. The wavelength of buckling affinely decreases with the retracting filament tip. The energy gain related to the decrease of the total length and surface area of the filaments is mainly dissipated by layer rearrangements during thickening of the fibre. A flow back into the meniscus is relevant only in the final stage of the recoil process. We introduce a model for the quantitative description of the filament retraction speed. The dynamics of this recoil behaviour may find relevance as a model for biology-related filaments. PMID:27140824

  10. Accurate hydrogen depth profiling by reflection elastic recoil detection analysis

    SciTech Connect

    Verda, R. D.; Tesmer, Joseph R.; Nastasi, Michael Anthony,; Bower, R. W.

    2001-01-01

    A technique to convert reflection elastic recoil detection analysis spectra to depth profiles, the channel-depth conversion, was introduced by Verda, et al [1]. But the channel-depth conversion does not correct for energy spread, the unwanted broadening in the energy of the spectra, which can lead to errors in depth profiling. A work in progress introduces a technique that corrects for energy spread in elastic recoil detection analysis spectra, the energy spread correction [2]. Together, the energy spread correction and the channel-depth conversion comprise an accurate and convenient hydrogen depth profiling method.

  11. Designing nitrogen-enriched echinus-like carbon capsules for highly efficient oxygen reduction reaction and lithium ion storage

    NASA Astrophysics Data System (ADS)

    Hu, Chuangang; Wang, Lixia; Zhao, Yang; Ye, Minhui; Chen, Qing; Feng, Zhihai; Qu, Liangti

    2014-06-01

    Both structural and compositional modulations are important for high-performance electrode materials in energy conversion/storage devices. Here hierarchical-structure nitrogen-rich hybrid porous carbon capsules with bamboo-like carbon nanotube whiskers (N-CC@CNTs) grown in situ have been specifically designed, which combine the advantageous features of high surface area, abundant active sites, easy access to medium and favorable mass transport. As a result, the newly prepared N-CC@CNTs show highly efficient catalytic activity in oxygen reduction reaction in alkaline media for fuel cells, which not only outperforms commercial Pt-based catalysts in terms of kinetic limiting current, stability and tolerance to methanol crossover effect, but is also better than most of the nanostructured carbon-based catalysts reported previously. On the other hand, as an anode material for lithium ion batteries, the N-CC@CNTs obtained also exhibit an excellent reversible capacity of ca. 1337 mA h g-1 at 0.5 A g-1, outstanding rate capability and long cycling stability, even at a current density of 20 A g-1. The capacity is the highest among all the heteroatom-doped carbon materials reported so far, and is even higher than that of many of the composites of metal, metal oxides or metal sulfides with carbon materials.Both structural and compositional modulations are important for high-performance electrode materials in energy conversion/storage devices. Here hierarchical-structure nitrogen-rich hybrid porous carbon capsules with bamboo-like carbon nanotube whiskers (N-CC@CNTs) grown in situ have been specifically designed, which combine the advantageous features of high surface area, abundant active sites, easy access to medium and favorable mass transport. As a result, the newly prepared N-CC@CNTs show highly efficient catalytic activity in oxygen reduction reaction in alkaline media for fuel cells, which not only outperforms commercial Pt-based catalysts in terms of kinetic limiting

  12. Double and single ionization of He and other targets studied using cold target recoil momentum spectroscopy

    SciTech Connect

    Doerner, R.; Feagin, J. M.; Brauning, H.; Jagutzki, O.; Jung, M.; Kanter, E. P.; Khemliche, H.; Kravis, S.; Mergel, V.; Prior, M. H.; Schmidt-Boeking, H.; Spielberger, L.; Ullrich, J.; Unverzagt, M.; Vogt, T.

    1997-04-01

    Double ionization of an atom by a single photon is the simplest and most fundamental many-electron process. The ejection of two electrons following the absorption of one photon is strictly prohibited in an independent electron approximation. Thus determining the probability of double photoionization alone is already a challenging test of the understanding of electron-electron correlation. Furthermore, in the slow breakup of a bound system into three charged particles, the final state wave function must represent a high degree of few-body Coulomb correlation involving the simultaneous interaction of all three particles. The case of double photoionization is again particularly well suited to study this problem as the energy and the angular momentum delivered to the system can be very well controlled. Helium, as the most basic three body system, has been the target of extensive studies over the past decades. The purpose of this project has been to study double and single ionization using cold target recoil ion momentum spectroscopy (COLTRIMS). This technique has been widely applied within the area of ion-atom collisions to study the dynamics of energy and momentum transfer in collisions between few-electron systems, and the entire technical machinery has been transferred to photon-atom collisions. The technique uses space- and time-imaging of He{sup +} and He{sup ++} recoil ions created in photon-He collisions to measure the full momentum vector of each ion produced. Event-mode recording is used and a solid angle of nearly 4{pi} is realized, allowing an extremely high data-collection efficiency. In order to reduce the initial momentum spread of the He target a precooled supersonic He jet is used.

  13. Direct measurements of (p, γ) cross-sections at astrophysical energies using radioactive beams and the Daresbury Recoil Separator

    NASA Astrophysics Data System (ADS)

    Bardayan, D. W.; Chipps, K. A.; Fitzgerald, R. P.; Blackmon, J. C.; Chae, K. Y.; Champagne, A. E.; Greife, U.; Hatarik, R.; Kozub, R. L.; Matei, C.; Moazen, B. H.; Nesaraja, C. D.; Pain, S. D.; Peters, W. A.; Pittman, S. T.; Shriner, J. F.; Smith, M. S.

    2009-12-01

    There are a number of astrophysical environments in which the path of nucleosynthesis proceeds through proton-rich nuclei. These nuclei have traditionally not been available as beams, and thus proton-capture reactions on these nuclei could only be studied indirectly. At the Holifield Radioactive Ion Beam Facility (HRIBF), some of the first direct measurements of ( p, γ) cross-sections on radioactive beams have been made. The Daresbury Recoil Separator (DRS) has been used to separate the recoils of interest from the unreacted primary beam and identify them in an isobutane-filled ionization counter. First data from 17F ( p, γ 18Ne and 7Be ( p, γ 8B measurements are presented.

  14. Direct Measurements of (p,gamma) Cross Sections at Astrophysical Energies using Radioactive Beams and the Daresbury Recoil Separator

    SciTech Connect

    Bardayan, Daniel W; Chipps, K.; Fitzgerald, R. P.; Blackmon, Jeff C; Chae, K. Y.; Champagne, A. E.; Greife, U.; Hatarik, Robert; Kozub, R. L.; Matei, Catalin; Moazen, Brian; Nesaraja, Caroline D; Pain, Steven D; Peters, W. A.; Pittman, S. T.; ShrinerJr., J. F.; Smith, Michael Scott

    2009-01-01

    There are a number of astrophysical environments in which the path of nucleosynthesis leads through proton-rich nuclei. These nuclei have traditionally not been available as beams, and thus proton-capture reactions on these nuclei could only be studied indirectly. At the Holifield Radioactive Ion Beam Facility (HRIBF), some of the first direct measurements of (p,gamma) cross sections on radioactive beams have been made. The Daresbury Recoil Separator (DRS) has been used to separate the recoils of interest from the unreacted primary beam and identify them in an isobutane-filled ionization counter. First data from 17F(p,gamma)18Ne and 7B(p,gamma)8B measurements are presented.

  15. Direct measurments of (p,gamma) cross sections at astrophysical energies using radioactive beams and the Daresbury Recoil Separator

    SciTech Connect

    Bardayan, Daniel W; Chipps, K.; Fitzgerald, R. P.; Blackmon, Jeff C; Chae, Kyung Yuk; Champagne, A. E.; Greife, Uwe; Hatarik, Robert; Kozub, R. L.; Matei, Catalin; Moazen, Brian; Nesaraja, Caroline D; Pain, Steven D; Peters, W. A.; Pittman, S. T.; ShrinerJr., J. F.; Smith, Michael Scott

    2009-01-01

    There are a number of astrophysical environments in which the path of nucleosynthesis proceeds through proton-rich nuclei. Radioactive nuclei have traditionally not been available as beams, and thus proton-capture reactions on these nuclei could only be studied indirectly. At the Holifield Radioactive Ion Beam Facility (HRIBF), some of the first direct measurements of (p,g ) cross sections on radioactive beams have been made. The Daresbury Recoil Separator (DRS) has been used to separate the recoils of interest from the unreacted primary beam and identify them in an isobutane-filled ionization counter. Data from 17F(p,g )18Ne and 7Be(p,g )8B measurements are presented.

  16. Effect of activated carbon surface oxygen- and/or nitrogen-containing groups on adsorption of copper(II) ions from aqueous solution

    SciTech Connect

    Biniak, S.; Pakula, M.; Szymanski, G.S.; Swiatkowski, A.

    1999-08-31

    The adsorption properties of a modified activated carbon with various oxygen-and/or nitrogen-containing surface groups toward copper ions was studied. Previously de-ashed and chemically modified commercial activated carbon D-43/1 (carbo-Tech, Essen, Germany) was used. The chemical properties of the modified carbon surface were estimated by standard neutralization titration with HCl, NaOH, and HaOC{sub 2}{sub 5}. The adsorption of Cu{sup 2+} ions on three modified activated carbons from aqueous CuSO{sub 4} solution of various pH was measured. The carbon samples with adsorbed Cu{sup 2+} ions were analyzed by spectroscopic methods (X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy). In addition, an electrochemical measurement (cyclic voltammetry) was performed using powdered activated carbon electrodes. While the modification procedures employed alter the surface only slightly, they strongly influence the surface chemical structure. Basic groups are predominant in the heat-treated samples; acidic functional groups are predominant in the oxidized sample. Both the copper cation adsorption studies and the spectral and electrochemical measurements show that adsorbed ions interact with the carbon surface in different ways. The number of adsorbed ions depends on the nature and quantity of surface acid-base functionalities and on the pH equilibrium in the aqueous solution. The possible mechanisms of interactions between metal ions and carbon surface functionalities are summarized and discussed.

  17. Direct Measurement of Photon Recoil from a Levitated Nanoparticle

    NASA Astrophysics Data System (ADS)

    Jain, Vijay; Gieseler, Jan; Moritz, Clemens; Dellago, Christoph; Quidant, Romain; Novotny, Lukas

    2016-06-01

    The momentum transfer between a photon and an object defines a fundamental limit for the precision with which the object can be measured. If the object oscillates at a frequency Ω0 , this measurement backaction adds quanta ℏΩ0 to the oscillator's energy at a rate Γrecoil, a process called photon recoil heating, and sets bounds to coherence times in cavity optomechanical systems. Here, we use an optically levitated nanoparticle in ultrahigh vacuum to directly measure Γrecoil. By means of a phase-sensitive feedback scheme, we cool the harmonic motion of the nanoparticle from ambient to microkelvin temperatures and measure its reheating rate under the influence of the radiation field. The recoil heating rate is measured for different particle sizes and for different excitation powers, without the need for cavity optics or cryogenic environments. The measurements are in quantitative agreement with theoretical predictions and provide valuable guidance for the realization of quantum ground-state cooling protocols and the measurement of ultrasmall forces.

  18. Epitaxial silicide formation on recoil-implanted substrates

    SciTech Connect

    Hashimoto, Shin; Egashira, Kyoko; Tanaka, Tomoya; Etoh, Ryuji; Hata, Yoshifumi; Tung, R. T.

    2005-01-15

    An epitaxy-on-recoil-implanted-substrate (ERIS) technique is presented. A disordered surface layer, generated by forward recoil implantation of {approx}0.7-3x10{sup 15} cm{sup -2} of oxygen during Ar plasma etching of surface oxide, is shown to facilitate the subsequent epitaxial growth of {approx}25-35-nm-thick CoSi{sub 2} layers on Si(100). The dependence of the epitaxial fraction of the silicide on the recoil-implantation parameters is studied in detail. A reduction in the silicide reaction rate due to recoil-implanted oxygen is shown to be responsible for the observed epitaxial formation, similar to mechanisms previously observed for interlayer-mediated growth techniques. Oxygen is found to remain inside the fully reacted CoSi{sub 2} layer, likely in the form of oxide precipitates. The presence of these oxide precipitates, with only a minor effect on the sheet resistance of the silicide layer, has a surprisingly beneficial effect on the thermal stability of the silicide layers. The agglomeration of ERIS-grown silicide layers on polycrystalline Si is significantly suppressed, likely from a reduced diffusivity due to oxygen in the grain boundaries. The implications of the present technique for the processing of deep submicron devices are discussed.

  19. Direct Measurement of Photon Recoil from a Levitated Nanoparticle.

    PubMed

    Jain, Vijay; Gieseler, Jan; Moritz, Clemens; Dellago, Christoph; Quidant, Romain; Novotny, Lukas

    2016-06-17

    The momentum transfer between a photon and an object defines a fundamental limit for the precision with which the object can be measured. If the object oscillates at a frequency Ω_{0}, this measurement backaction adds quanta ℏΩ_{0} to the oscillator's energy at a rate Γ_{recoil}, a process called photon recoil heating, and sets bounds to coherence times in cavity optomechanical systems. Here, we use an optically levitated nanoparticle in ultrahigh vacuum to directly measure Γ_{recoil}. By means of a phase-sensitive feedback scheme, we cool the harmonic motion of the nanoparticle from ambient to microkelvin temperatures and measure its reheating rate under the influence of the radiation field. The recoil heating rate is measured for different particle sizes and for different excitation powers, without the need for cavity optics or cryogenic environments. The measurements are in quantitative agreement with theoretical predictions and provide valuable guidance for the realization of quantum ground-state cooling protocols and the measurement of ultrasmall forces. PMID:27367388

  20. Conductive surface modification of LiFePO4 with nitrogen doped carbon layers for lithium-ion batteries

    SciTech Connect

    Yoon, Sukeun; Liao, Chen; Sun, Xiao-Guang; Bridges, Craig A; Unocic, Raymond R; Nanda, Jagjit; Dai, Sheng; Paranthaman, Mariappan Parans

    2012-01-01

    The LiFePO4 rod surface modified with nitrogen doped carbon layer has been prepared using hydrothermal processing followed by post-annealing in the presence of an ionic liquid. The coated LiFePO4 rod exhibits good capacity retention and high rate capability as the nitrogen doped carbon improves conductivity and prevents aggregation of the rod during cycling.

  1. Nitrogen-atom endohedral fullerene synthesis with high efficiency by controlling plasma-ion irradiation energy and C{sub 60} internal energy

    SciTech Connect

    Cho, Soon Cheon; Kaneko, Toshiro Ishida, Hiroyasu; Hatakeyama, Rikizo

    2015-03-28

    The nitrogen-atom endohedral fullerene (N@C{sub 60}) has been synthesized by controlling the plasma ion irradiation energy (E{sub i}) and fullerene (C{sub 60}) behavior in the sublimation phase. We examined the relationship between the synthesis purity of N@C{sub 60} [molar concentration ratio of N@C{sub 60} to pristine fullerene (C{sub 60})] and E{sub i}, which was controlled by changing the substrate bias voltages (V{sub sub}) and gas pressure (P{sub N2}) during the plasma irradiation process. High-density nitrogen-molecular ions (N{sub 2}{sup +}) with a suitable E{sub i} near 80 eV are confirmed to be the optimum condition of the nitrogen plasma for the synthesis of high-purity N@C{sub 60}. In addition, high sublimation of C{sub 60} contributes to a higher yield due to the high internal energy of C{sub 60} and the related cage defects that are present under these conditions. As a result, a purity of 0.83% is realized for the first time, which is almost two orders of magnitude higher than that using other methods.

  2. The mechanics of elastic loading and recoil in anuran jumping.

    PubMed

    Astley, Henry C; Roberts, Thomas J

    2014-12-15

    Many animals use catapult mechanisms to produce extremely rapid movements for escape or prey capture, resulting in power outputs far beyond the limits of muscle. In these catapults, muscle contraction loads elastic structures, which then recoil to release the stored energy extremely rapidly. Many arthropods employ anatomical 'catch mechanisms' to lock the joint in place during the loading period, which can then be released to allow joint motion via elastic recoil. Jumping vertebrates lack a clear anatomical catch, yet face the same requirement to load the elastic structure prior to movement. There are several potential mechanisms to allow loading of vertebrate elastic structures, including the gravitational load of the body, a variable mechanical advantage, and moments generated by the musculature of proximal joints. To test these hypothesized mechanisms, we collected simultaneous 3D kinematics via X-ray Reconstruction of Moving Morphology (XROMM) and single-foot forces during the jumps of three Rana pipiens. We calculated joint mechanical advantage, moment and power using inverse dynamics at the ankle, knee, hip and ilio-sacral joints. We found that the increasing proximal joint moments early in the jump allowed for high ankle muscle forces and elastic pre-loading, and the subsequent reduction in these moments allowed the ankle to extend using elastic recoil. Mechanical advantage also changed throughout the jump, with the muscle contracting against a poor mechanical advantage early in the jump during loading and a higher mechanical advantage late in the jump during recoil. These 'dynamic catch mechanisms' serve to resist joint motion during elastic loading, then allow it during elastic recoil, functioning as a catch mechanism based on the balance and orientation of forces throughout the limb rather than an anatomical catch. PMID:25520385

  3. The mechanics of elastic loading and recoil in anuran jumping.

    PubMed

    Astley, Henry C; Roberts, Thomas J

    2014-12-15

    Many animals use catapult mechanisms to produce extremely rapid movements for escape or prey capture, resulting in power outputs far beyond the limits of muscle. In these catapults, muscle contraction loads elastic structures, which then recoil to release the stored energy extremely rapidly. Many arthropods employ anatomical 'catch mechanisms' to lock the joint in place during the loading period, which can then be released to allow joint motion via elastic recoil. Jumping vertebrates lack a clear anatomical catch, yet face the same requirement to load the elastic structure prior to movement. There are several potential mechanisms to allow loading of vertebrate elastic structures, including the gravitational load of the body, a variable mechanical advantage, and moments generated by the musculature of proximal joints. To test these hypothesized mechanisms, we collected simultaneous 3D kinematics via X-ray Reconstruction of Moving Morphology (XROMM) and single-foot forces during the jumps of three Rana pipiens. We calculated joint mechanical advantage, moment and power using inverse dynamics at the ankle, knee, hip and ilio-sacral joints. We found that the increasing proximal joint moments early in the jump allowed for high ankle muscle forces and elastic pre-loading, and the subsequent reduction in these moments allowed the ankle to extend using elastic recoil. Mechanical advantage also changed throughout the jump, with the muscle contracting against a poor mechanical advantage early in the jump during loading and a higher mechanical advantage late in the jump during recoil. These 'dynamic catch mechanisms' serve to resist joint motion during elastic loading, then allow it during elastic recoil, functioning as a catch mechanism based on the balance and orientation of forces throughout the limb rather than an anatomical catch.

  4. Nuclear Microprobe using Elastic Recoil Detection (ERD) for Hydrogen Profiling in High Temperature Protonic Conductors

    NASA Technical Reports Server (NTRS)

    Berger, Pascal; Sayir, Ali; Berger, Marie-Helene

    2004-01-01

    The interaction between hydrogen and various high temperature protonic conductors (HTPC) has not been clearly understood due to poor densification and unreacted secondary phases. the melt-processing technique is used in producing fully dense simple SrCe(0.9)Y (0.10) O(3-delta) and complex Sr3Ca(1+x)Nb(2+x)O(9-delta) perovskites that can not be achieved by solid-state sintering. the possibilities of ion beam analysis have been investigated to quantify hydrogen distribution in HTPC perovskites subjected to water heat treatment. Nuclear microprobe technique is based on the interactions of a focused ion beam of MeV light ions (H-1, H-2, He-3, He-4,.) with the sample to be analyzed to determine local elemental concentrations at the cubic micrometer scale, the elastic recoil detection analysis technique (ERDA) has been carried out using He-4(+) microbeams and detecting the resulting recoil protons. Mappings of longitudinal sections of water treated SrCeO3 and Sr(Ca(1/3)Nb(2/3))O3 perovskites have been achieved, the water treatment strongly alters the surface of simple SrCe(0.9)Y(0.10)O(3-delta) perovskite. From Rutherford Back Scattering measurements (RBS), both Ce depletion and surface re-deposition is evidenced. the ERDA investigations on water treated Sr3Ca(1+x)Nb(2+x)O(9-delta) perovskite did not exhibit any spatial difference for the hydrogen incorporation from the surface to the centre. the amount of hydrogen incorporation for Sr3Ca(1+x)Nb(2+x)O(9-delta) was low and required further development of two less conventional techniques, ERDA in forward geometry and forward elastic diffusion H-1(p,p) H-1 with coincidence detection.

  5. Metal Ion Binding to Polypeptides Characterized by Irmpd Spectroscopy. Metal-Amide Nitrogen Binding and the Iminol Tautomerization.

    NASA Astrophysics Data System (ADS)

    Dunbar, Robert C.; Polfer, Nicolas; Berden, Giel; Oomens, Jos

    2012-06-01

    We have recently uncovered a new binding mode for the complexation of metal ions with gas-phase peptides. Termed the iminol mode, this binding mode is adopted by strongly binding divalent metal ions including Mg2+ and Ni2+. The metal ion displaces the amide hydrogen, which moves to protonate the amide carbonyl oxygen. A spectroscopic signature of the tautomerization is the disappearance of the characteristic Amide II band normally seen in peptide ion infrared spectra. We find that in peptides up to pentapeptides, multiple iminol binding can take place, such that all amide linkages are tautomerized to the iminol form, and chelate the metal ion. However, the iminol tautomerization depends on the nature of the metal ion, as will be discussed. Spectra of the ions were acquired by irradiating the cell of the Fourier-transform ion cyclotron resonance mass spectrometer with infrared light from the FELIX laser at wavelengths in the approximate range 500 to 1900 cm-1.

  6. Hyperthermal (1-100 eV) nitrogen ion scattering damage to D-ribose and 2-deoxy-D-ribose films

    SciTech Connect

    Deng Zongwu; Bald, Ilko; Illenberger, Eugen; Huels, Michael A.

    2007-10-14

    Highly charged heavy ion traversal of a biological medium can produce energetic secondary fragment ions. These fragment ions can in turn cause collisional and reactive scattering damage to DNA. Here we report hyperthermal (1-100 eV) scattering of one such fragment ion (N{sup +}) from biologically relevant sugar molecules D-ribose and 2-deoxy-D-ribose condensed on polycrystalline Pt substrate. The results indicate that N{sup +} ion scattering at kinetic energies down to 10 eV induces effective decomposition of both sugar molecules and leads to the desorption of abundant cation and anion fragments. Use of isotope-labeled molecules (5-{sup 13}C D-ribose and 1-D D-ribose) partly reveals some site specificity of the fragment origin. Several scattering reactions are also observed. Both ionic and neutral nitrogen atoms abstract carbon from the molecules to form CN{sup -} anion at energies down to {approx}5 eV. N{sup +} ions also abstract hydrogen from hydroxyl groups of the molecules to form NH{sup -} and NH{sub 2}{sup -} anions. A fraction of O/O{sup -} fragments abstract hydrogen to form OH{sup -}. The formation of H{sub 3}O{sup +} ions also involves hydrogen abstraction as well as intramolecular proton transfer. These findings suggest a variety of severe damaging pathways to DNA molecules which occur on the picosecond time scale following heavy ion irradiation of a cell, and prior to the late diffusion-limited homogeneous chemical processes.

  7. Improvements of anti-corrosion and mechanical properties of NiTi orthopedic materials by acetylene, nitrogen and oxygen plasma immersion ion implantation

    NASA Astrophysics Data System (ADS)

    Poon, Ray W. Y.; Ho, Joan P. Y.; Liu, Xuanyong; Chung, C. Y.; Chu, Paul K.; Yeung, Kelvin W. K.; Lu, William W.; Cheung, Kenneth M. C.

    2005-08-01

    Nickel-titanium shape memory alloys (NiTi) are useful materials in orthopedics and orthodontics due to their unique super-elasticity and shape memory effects. However, the problem associated with the release of harmful Ni ions to human tissues and fluids has been raising safety concern. Hence, it is necessary to produce a surface barrier to impede the out-diffusion of Ni ions from the materials. We have conducted acetylene, nitrogen and oxygen plasma immersion ion implantation (PIII) into NiTi alloys in an attempt to improve the surface properties. All the implanted and annealed samples surfaces exhibit outstanding corrosion and Ni out-diffusion resistance. Besides, the implanted layers are mechanically stronger than the substrate underneath. XPS analyses disclose that the layer formed by C2H2 PIII is composed of mainly TiCx with increasing Ti to C concentration ratios towards the bulk. The nitrogen PIII layer is observed to be TiN, whereas the oxygen PIII layer is composed of oxides of Ti4+, Ti3+ and Ti2+.

  8. Effect of surface modification by nitrogen ion implantation on the electrochemical and cellular behaviors of super-elastic NiTi shape memory alloy.

    PubMed

    Maleki-Ghaleh, H; Khalil-Allafi, J; Sadeghpour-Motlagh, M; Shakeri, M S; Masoudfar, S; Farrokhi, A; Beygi Khosrowshahi, Y; Nadernezhad, A; Siadati, M H; Javidi, M; Shakiba, M; Aghaie, E

    2014-12-01

    The aim of this investigation was to enhance the biological behavior of NiTi shape memory alloy while preserving its super-elastic behavior in order to facilitate its compatibility for application in human body. The surfaces of NiTi samples were bombarded by three different nitrogen doses. Small-angle X-ray diffraction was employed for evaluating the generated phases on the bombarded surfaces. The electrochemical behaviors of the bare and surface-modified NiTi samples were studied in simulated body fluid (SBF) using electrochemical impedance and potentio-dynamic polarization tests. Ni ion release during a 2-month period of service in the SBF environment was evaluated using atomic absorption spectrometry. The cellular behavior of nitrogen-modified samples was studied using fibroblast cells. Furthermore, the effect of surface modification on super-elasticity was investigated by tensile test. The results showed the improvement of both corrosion and biological behaviors of the modified NiTi samples. However, no significant change in the super-elasticity was observed. Samples modified at 1.4E18 ion cm(-2) showed the highest corrosion resistance and the lowest Ni ion release. PMID:25064465

  9. Effect of surface modification by nitrogen ion implantation on the electrochemical and cellular behaviors of super-elastic NiTi shape memory alloy.

    PubMed

    Maleki-Ghaleh, H; Khalil-Allafi, J; Sadeghpour-Motlagh, M; Shakeri, M S; Masoudfar, S; Farrokhi, A; Beygi Khosrowshahi, Y; Nadernezhad, A; Siadati, M H; Javidi, M; Shakiba, M; Aghaie, E

    2014-12-01

    The aim of this investigation was to enhance the biological behavior of NiTi shape memory alloy while preserving its super-elastic behavior in order to facilitate its compatibility for application in human body. The surfaces of NiTi samples were bombarded by three different nitrogen doses. Small-angle X-ray diffraction was employed for evaluating the generated phases on the bombarded surfaces. The electrochemical behaviors of the bare and surface-modified NiTi samples were studied in simulated body fluid (SBF) using electrochemical impedance and potentio-dynamic polarization tests. Ni ion release during a 2-month period of service in the SBF environment was evaluated using atomic absorption spectrometry. The cellular behavior of nitrogen-modified samples was studied using fibroblast cells. Furthermore, the effect of surface modification on super-elasticity was investigated by tensile test. The results showed the improvement of both corrosion and biological behaviors of the modified NiTi samples. However, no significant change in the super-elasticity was observed. Samples modified at 1.4E18 ion cm(-2) showed the highest corrosion resistance and the lowest Ni ion release.

  10. Modulation of gill Na+,K+-ATPase activity by ammonium ions: Putative coupling of nitrogen excretion and ion uptake in the freshwater shrimp Macrobrachium olfersii.

    PubMed

    Furriel, Rosa Prazeres Melo; Masui, Douglas Chodi; McNamara, John Campbell; Leone, Francisco Assis

    2004-01-01

    The effect of NH4+ ions on (Na+,K+)-ATPase hydrolytic activity was examined in a gill microsomal fraction from M. olfersii. In the absence of NH4+ ions, K+ ions stimulated ATP hydrolysis, exhibiting cooperative kinetics (nH=0.8), to a maximal specific activity of V=556.1+/-22.2 nmol.min(-1).mg(-1) with K(0.5)=2.4+/-0.1 mmol.L(-1). No further stimulation by K+ ions was observed in the presence of 50 mmol.L(-1) NH4+ ions. ATP hydrolysis was also stimulated by NH4+ ions obeying Michaelian kinetics to a maximal specific activity of V=744.8+/-22.3 nmol.min(-1).mg(-1) and KM=8.4+/-0.2 mmol.L(-1). In the presence of 10 mmol.L(-1) K+ ions, ATP hydrolysis was synergistically stimulated by NH4+ ions to V=689.8+/-13.8 nmol.min(-1).mg(-1) and K(0.5)=6.6+/-0.1 mmol.L(-1), suggesting that NH4+ ions bind to different sites than K+ ions. PNPP hydrolysis was also stimulated cooperatively by K+ or NH4+ ions to maximal values of V= 235.5+/-11.8 nmol.min(-1).mg(-1) and V=234.8+/-7.0 nmol.min(-1).mg(-1), respectively. In contrast to ATP hydrolysis, K(+)-phosphatase activity was not synergistically stimulated by NH4+ and K+ ions. These data suggest that at high NH4+ ion concentrations, the (Na+, K+)-ATPase exposes a new site; the subsequent binding of NH4+ ions stimulates ATP hydrolysis to rates higher than those for K+ ions alone. This is the first demonstration that (Na+, K+)-ATPase activity in a freshwater shrimp gill is modulated by ammonium ions, independently of K+ ions, an effect that may constitute a fine-tuning mechanism of physiological relevance to osmoregulatory and excretory processes in palaemonid shrimps.

  11. Encapsulating micro-nano Si/SiOx into conjugated nitrogen-doped carbon as binder-free monolithic anodes for advanced lithium ion batteries

    NASA Astrophysics Data System (ADS)

    Wang, Jing; Zhou, Meijuan; Tan, Guoqiang; Chen, Shi; Wu, Feng; Lu, Jun; Amine, Khalil

    2015-04-01

    Silicon monoxide, a promising silicon-based anode candidate for lithium-ion batteries, has recently attracted much attention for its high theoretical capacity, good cycle stability, low cost, and environmental benignity. Currently, the most critical challenge is to improve its low initial coulombic efficiency and significant volume changes during the charge-discharge processes. Herein, we report a binder-free monolithic electrode structure based on directly encapsulating micro-nano Si/SiOx particles into conjugated nitrogen-doped carbon frameworks to form monolithic, multi-core, cross-linking composite matrices. We utilize micro-nano Si/SiOx reduced by high-energy ball-milling SiO as active materials, and conjugated nitrogen-doped carbon formed by the pyrolysis of polyacrylonitrile both as binders and conductive agents. Owing to the high electrochemical activity of Si/SiOx and the good mechanical resiliency of conjugated nitrogen-doped carbon backbones, this specific composite structure enhances the utilization efficiency of SiO and accommodates its large volume expansion, as well as its good ionic and electronic conductivity. The annealed Si/SiOx/polyacrylonitrile composite electrode exhibits excellent electrochemical properties, including a high initial reversible capacity (2734 mA h g-1 with 75% coulombic efficiency), stable cycle performance (988 mA h g-1 after 100 cycles), and good rate capability (800 mA h g-1 at 1 A g-1 rate). Because the composite is naturally abundant and shows such excellent electrochemical performance, it is a promising anode candidate material for lithium-ion batteries. The binder-free monolithic architectural design also provides an effective way to prepare other monolithic electrode materials for advanced lithium-ion batteries.

  12. A recoil resilient lumen support, design, fabrication and mechanical evaluation

    NASA Astrophysics Data System (ADS)

    Mehdizadeh, Arash; Ali, Mohamed Sultan Mohamed; Takahata, Kenichi; Al-Sarawi, Said; Abbott, Derek

    2013-06-01

    Stents are artificial implants that provide scaffolding to a cavity inside the body. This paper presents a new luminal device for reducing the mechanical failure of stents due to recoil, which is one of the most important issues in stenting. This device, which we call a recoil-resilient ring (RRR), is utilized standalone or potentially integrated with existing stents to address the problem of recoil. The proposed structure aims to minimize the need for high-pressure overexpansion that can induce intra-luminal trauma and excess growth of vascular tissue causing later restenosis. The RRR is an overlapped open ring with asymmetrical sawtooth structures that are intermeshed. These teeth can slide on top of each other, while the ring is radially expanded, but interlock step-by-step so as to keep the final expanded state against compressional forces that normally cause recoil. The RRRs thus deliver balloon expandability and, when integrated with a stent, bring both radial rigidity and longitudinal flexibility to the stent. The design of the RRR is investigated through finite element analysis (FEA), and then the devices are fabricated using micro-electro-discharge machining of 200-µm-thick Nitinol sheet. The standalone RRR is balloon expandable in vitro by 5-7 Atm in pressure, which is well within the recommended in vivo pressure ranges for stenting procedures. FEA compression tests indicate 13× less reduction of the cross-sectional area of the RRR compared with a typical stainless steel stent. These results also show perfect elastic recovery of the RRR after removal of the pressure compared to the remaining plastic deformations of the stainless steel stent. On the other hand, experimental loading tests show that the fabricated RRRs have 2.8× radial stiffness compared to a two-column section of a commercial stent while exhibiting comparable elastic recovery. Furthermore, testing of in vitro expansion in a mock artery tube shows around 2.9% recoil, approximately 5-11

  13. Measuring the absolute DT neutron yield using the Magnetic Recoil Spectrometer at OMEGA and the NIF

    SciTech Connect

    Mackinnon, A; Casey, D; Frenje, J A; Johnson, M G; Seguin, F H; Li, C K; Petrasso, R D; Glebov, V Y; Katz, J; Knauer, J; Meyerhofer, D; Sangster, T; Bionta, R; Bleuel, D; Hachett, S P; Hartouni, E; Lepape, S; Mckernan, M; Moran, M; Yeamans, C

    2012-05-03

    A Magnetic Recoil Spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion (ICF) implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF.

  14. Lifetime measurement of 2+- state in 74Zn by recoil-distance Doppler-shift method

    NASA Astrophysics Data System (ADS)

    Niikura, M.; Mouginot, B.; Azaiez, F.; Franchoo, S.; Matea, I.; Stefan, I.; Verney, D.; Assie, M.; Bednarczyk, P.; Borcea, C.; Burger, A.; Burgunder, G.; Buta, A.; Cáceres, L.; Cléement, E.; Coquard, L.; de Angelis, G.; de France, G.; de Oliveira Santos, F.; Dewald, A.; Dijon, A.; Dombradi, Z.; Fiori, E.; Fransen, C.; Friessner, G.; Gaudefroy, L.; Georgiev, G.; Grévy, S.; Hackstein, M.; Harakeh, M. N.; Ibrahim, F.; Kamalou, O.; Kmiecik, M.; Lozeva, R.; Maj, A.; Mihai, C.; Möller, O.; Myalski, S.; Negoita, F.; Pantelica, D.; Perrot, L.; Pissulla, Th.; Rotaru, F.; Rother, W.; Scarpaci, J. A.; Stodel, C.; Thomas, J. C.; Ujic, P.

    2013-09-01

    We have performed the first direct lifetime measurement of the 2+- state in 74Zn. The neutron-rich 74Zn beam was produced by in-flight fragmentation of 76Ge at the Grand Accélérateur National d'Ions Lourds and separated with the LISE spectrometer. The lifetime of the 2+- state was measured by the recoil-distance Doppler-shift method with the Cologne plunger device combined with the EXOGAM detectors. The lifetime of the 2+- state in 74Zn was determined to be 27.0(24) ps, which corresponds to a reduced transition probability B(E2; 2+- -> 0+) = 370(33) e2fm4.

  15. The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF.

    PubMed

    Casey, D T; Frenje, J A; Johnson, M Gatu; Séguin, F H; Li, C K; Petrasso, R D; Glebov, V Yu; Katz, J; Magoon, J; Meyerhofer, D D; Sangster, T C; Shoup, M; Ulreich, J; Ashabranner, R C; Bionta, R M; Carpenter, A C; Felker, B; Khater, H Y; LePape, S; MacKinnon, A; McKernan, M A; Moran, M; Rygg, J R; Yeoman, M F; Zacharias, R; Leeper, R J; Fletcher, K; Farrell, M; Jasion, D; Kilkenny, J; Paguio, R

    2013-04-01

    The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, ion-temperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

  16. The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF

    SciTech Connect

    Casey, D. T.; Frenje, J. A.; Gatu Johnson, M.; Seguin, F. H.; Li, C. K.; Petrasso, R. D.; Glebov, V. Yu.; Katz, J.; Magoon, J.; Meyerhofer, D. D.; Sangster, T. C.; Shoup, M.; Ulreich, J.; Ashabranner, R. C.; Bionta, R. M.; Carpenter, A. C.; Felker, B.; Khater, H. Y.; LePape, S.; MacKinnon, A.; and others

    2013-04-15

    The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, ion-temperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

  17. The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF

    NASA Astrophysics Data System (ADS)

    Casey, D. T.; Frenje, J. A.; Gatu Johnson, M.; Séguin, F. H.; Li, C. K.; Petrasso, R. D.; Glebov, V. Yu.; Katz, J.; Magoon, J.; Meyerhofer, D. D.; Sangster, T. C.; Shoup, M.; Ulreich, J.; Ashabranner, R. C.; Bionta, R. M.; Carpenter, A. C.; Felker, B.; Khater, H. Y.; LePape, S.; MacKinnon, A.; McKernan, M. A.; Moran, M.; Rygg, J. R.; Yeoman, M. F.; Zacharias, R.; Leeper, R. J.; Fletcher, K.; Farrell, M.; Jasion, D.; Kilkenny, J.; Paguio, R.

    2013-04-01

    The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, ion-temperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

  18. Analysis of hydrogen adsorption and surface binding configuration on tungsten using direct recoil spectrometry

    SciTech Connect

    Kolasinski, R. D.; Hammond, K. D.; Whaley, J. A.; Buchenauer, D. A.; Wirth, B. D.

    2014-12-03

    In our work, we apply low energy ion beam analysis to examine directly how the adsorbed hydrogen concentration and binding configuration on W(1 0 0) depend on temperature. We exposed the tungsten surface to fluxes of both atomic and molecular H and D. We then probed the H isotopes adsorbed along different crystal directions using 1–2 keV Ne+ ions. At saturation coverage, H occupies two-fold bridge sites on W(1 0 0) at 25 °C. Moreover, the H coverage dramatically changes the behavior of channeled ions, as does reconstruction of the surface W atoms. For the exposure conditions examined here, we find that surface sites remain populated with H until the surface temperature reaches 200 °C. Then, we observe H rapidly desorbing until only a residual concentration remains at 450 °C. Development of an efficient atomistic model that accurately reproduces the experimental ion energy spectra and azimuthal variation of recoiled H is underway.

  19. Analysis of hydrogen adsorption and surface binding configuration on tungsten using direct recoil spectrometry

    DOE PAGESBeta

    Kolasinski, R. D.; Hammond, K. D.; Whaley, J. A.; Buchenauer, D. A.; Wirth, B. D.

    2014-12-03

    In our work, we apply low energy ion beam analysis to examine directly how the adsorbed hydrogen concentration and binding configuration on W(1 0 0) depend on temperature. We exposed the tungsten surface to fluxes of both atomic and molecular H and D. We then probed the H isotopes adsorbed along different crystal directions using 1–2 keV Ne+ ions. At saturation coverage, H occupies two-fold bridge sites on W(1 0 0) at 25 °C. Moreover, the H coverage dramatically changes the behavior of channeled ions, as does reconstruction of the surface W atoms. For the exposure conditions examined here, wemore » find that surface sites remain populated with H until the surface temperature reaches 200 °C. Then, we observe H rapidly desorbing until only a residual concentration remains at 450 °C. Development of an efficient atomistic model that accurately reproduces the experimental ion energy spectra and azimuthal variation of recoiled H is underway.« less

  20. Ionization efficiency study for low energy nuclear recoils in germanium

    NASA Astrophysics Data System (ADS)

    Barker, D.; Wei, W.-Z.; Mei, D.-M.; Zhang, C.

    2013-08-01

    We used the internal conversion (E0 transition) of germanium-72 to indirectly measure the low energy nuclear recoils of germanium. Together with a reliable Monte Carlo package, in which we implement the internal conversion process, the data was compared to the Lindhard (k = 0.159) and Barker-Mei models. A shape analysis indicates that both models agree well with data in the region of interest within 4%. The most probable value (MPV) of the nuclear recoils obtained from the shape analysis is 17.5 ± 0.12 (sys) ±0.035 (stat) keV with an average path-length of 0.014 μm.

  1. Characterization of the CRESST detectors by neutron induced nuclear recoils

    NASA Astrophysics Data System (ADS)

    Coppi, C.; Ciemniak, C.; von Feilitzsch, F.; Gütlein, A.; Hagn, H.; Isaila, C.; Jochum, J.; Kimmerle, M.; Lanfranchi, J.-C.; Pfister, S.; Potzel, W.; Rau, W.; Roth, S.; Rottler, K.; Sailer, C.; Scholl, S.; Usherov, I.; Westphal, W.

    CRESST is an experiment for the direct detection of dark matter particles via nuclear recoils. The CRESST detectors, based on CaWO4 scintillating crystals, are able to discriminate γ and β background by simultaneously measuring the light and phonon signals produced by particle interactions. The discrimination of the background is possible because of the different light output (Quenching Factor, QF) for nuclear and electron recoils. In this article a measurement is shown, aimed at the determination of the QFs of the different nuclei (O, Ca, W) of the detector crystal at 40-60 mK using an 11 MeV neutron beam produced at the Maier-Leibnitz-Laboratorium in Garching (MLL).

  2. Dynamical formation of horizons in recoiling D-branes

    SciTech Connect

    Ellis, John; Mavromatos, N. E.; Nanopoulos, D. V.

    2000-10-15

    A toy calculation of string or D-particle interactions within a world-sheet approach indicates that quantum recoil effects -- reflecting the gravitational back reaction on space-time foam due to the propagation of energetic particles -- induces the appearance of a microscopic event horizon, or ''bubble,'' inside which stable matter can exist. The scattering event causes this horizon to expand, but we expect quantum effects to cause it to contract again, in a ''bounce'' solution. Within such ''bubbles,'' massless matter propagates with an effective velocity that is less than the velocity of light in vacuo, which may lead to observable violations of Lorentz symmetry that may be tested experimentally. The conformal invariance conditions in the interior geometry of the bubbles select preferentially 3 for the number of the spatial dimensions, corresponding to a consistent formulation of the interaction of D3-branes with recoiling D particles, which are allowed to fluctuate independently only on the D3-brane hypersurface.

  3. Dynamical formation of horizons in recoiling D-branes

    NASA Astrophysics Data System (ADS)

    Ellis, John; Mavromatos, N. E.; Nanopoulos, D. V.

    2000-10-01

    A toy calculation of string or D-particle interactions within a world-sheet approach indicates that quantum recoil effects-reflecting the gravitational back reaction on space-time foam due to the propagation of energetic particles-induces the appearance of a microscopic event horizon, or ``bubble,'' inside which stable matter can exist. The scattering event causes this horizon to expand, but we expect quantum effects to cause it to contract again, in a ``bounce'' solution. Within such ``bubbles,'' massless matter propagates with an effective velocity that is less than the velocity of light in vacuo, which may lead to observable violations of Lorentz symmetry that may be tested experimentally. The conformal invariance conditions in the interior geometry of the bubbles select preferentially 3 for the number of the spatial dimensions, corresponding to a consistent formulation of the interaction of D3-branes with recoiling D particles, which are allowed to fluctuate independently only on the D3-brane hypersurface.

  4. Recoil-induced subradiance in an ultracold atomic gas

    SciTech Connect

    Cola, M. M.; Bigerni, D.; Piovella, N.

    2009-05-15

    Subradiance, i.e., the cooperative inhibition of spontaneous emission by destructive interatomic interference, can be realized in a cold atomic sample confined in a ring cavity and lightened by a two-frequency laser. The atoms, scattering the photons of the two laser fields into the cavity mode, recoil and change their momentum. Under proper conditions the atomic initial momentum state and the first two momentum recoil states form a three-level degenerate cascade. A stationary subradiant state is obtained after the scattered photons have left the cavity, leaving the atoms in a coherent superposition of the three collective momentum states. Both a semiclassical description of the process and the quantum subradiant state with its Wigner function are given. Antibunching, quantum correlations, and entanglement between the atomic modes of the subradiant state are demonstrated.

  5. Recoiling supermassive black holes: a search in the nearby universe

    SciTech Connect

    Lena, D.; Robinson, A.; Axon, D. J.; Merritt, D.; Marconi, A.; Capetti, A.; Batcheldor, D.

    2014-11-10

    The coalescence of a binary black hole can be accompanied by a large gravitational recoil due to anisotropic emission of gravitational waves. A recoiling supermassive black hole (SBH) can subsequently undergo long-lived oscillations in the potential well of its host galaxy, suggesting that offset SBHs may be common in the cores of massive ellipticals. We have analyzed Hubble Space Telescope archival images of 14 nearby core ellipticals, finding evidence for small (≲ 10 pc) displacements between the active galactic nucleus (AGN; the location of the SBH) and the center of the galaxy (the mean photocenter) in 10 of them. Excluding objects that may be affected by large-scale isophotal asymmetries, we consider six galaxies to have detected displacements, including M87, where a displacement was previously reported by Batcheldor et al. In individual objects, these displacements can be attributed to residual gravitational recoil oscillations following a major or minor merger within the last few gigayears. For plausible merger rates, however, there is a high probability of larger displacements than those observed, if SBH coalescence took place in these galaxies. Remarkably, the AGN-photocenter displacements are approximately aligned with the radio source axis in four of the six galaxies with displacements, including three of the four having relatively powerful kiloparsec-scale jets. This suggests intrinsic asymmetries in radio jet power as a possible displacement mechanism, although approximate alignments are also expected for gravitational recoil. Orbital motion in SBH binaries and interactions with massive perturbers can produce the observed displacement amplitudes but do not offer a ready explanation for the alignments.

  6. Spallation recoil and age of presolar grains in meteorites

    NASA Astrophysics Data System (ADS)

    Ott, U.; Begemann, F.

    2000-01-01

    We have determined the recoil losses from silicon carbide grain size fractions of spallation neon produced by irradiation with 1.6 GeV protons. During the irradiation the SiC grains were dispersed in paraffin wax in order to avoid re-implantation into neighboring grains. Analysis for spallogenic 21Ne of grain size separates in the size range 0.3 μm to 6 μm and comparison with the 22Na activity of the SiC+paraffin mixture indicates an effective recoil range of 2-3 μm with no apparent effect from acid treatments such as routinely used in the isolation of meteoritic SiC grains. Our results indicate that the majority of presolar SiC grains in primitive meteorites, which are ~μm-sized, will have lost essentially all spallogenic Ne produced by cosmic ray interaction in the interstellar medium. This argues against the validity of previously published presolar ages of Murchison SiC (~10 to ~130 Ma; increasing with grain size; Lewis et al., 1994), where recoil losses had been based on calculated recoil energies. It is argued that the observed variations in meteoritic SiC grain size fractions of 21Ne/22Ne ratios are more likely due to the effects of nucleosynthesis in the He burning shell of the parent AGB stars which imposes new boundary conditions on nuclear parameters and stellar models. It is suggested that spallation-Xe produced on the abundant Ba and REE in presolar SiC, rather than spallogenic Ne, may be a promising approach to the presolar age problem. There is a hint in the currently available Xe data (Lewis et al., 1994) that the large (>1 μm) grains may be younger than the smaller (<1 μm) ones.

  7. Recoil Polarization for Neutral Pion Electroproduction near the Delta Resonance

    SciTech Connect

    Kelly, James J

    2003-10-01

    We have measured angular distributions for recoil polarization in the p(e,e'p)p0 reaction at Q2»1(GeV/c)2 with 1.16 |lte| W |lte|1.36 GeV across the D resonance. The data are compared with representative models and a truncated Legendre analysis is compared with a more general multipole analysis.

  8. The velocity and recoil of DNA bands during gel electrophoresis

    NASA Astrophysics Data System (ADS)

    Keiner, Louis E.; Holzwarth, G.

    1992-09-01

    The velocity and recoil of bands of DNA containing 48.5 to 4800 kilobasepairs (kb) were measured during pulsed-field gel electrophoresis by a video imaging and analysis system. When a 10 V/cm electric field was first applied, the velocity showed an initial sharp peak after approximately 1 s whose amplitude depended on the molecular weight of the DNA and the rest time and polarity of the previous pulse. For example, G DNA (670 kb) exhibited an initial velocity peak of 13 μm/s. The velocity then oscillated through a shallow minimum and small maximum before reaching a 5.0 μm/s plateau. After the field was turned off, the bands moved backward (recoiled). The band position obeyed a stretched-exponential relation, x = x0 exp[ - (t/τ)β] with amplitude x0 equal to approximately 1/10th of the DNA contour length and β≊0.6; for S. pombe DNA, x0 was a remarkable 165 μm. Both the initial velocity spike and the recoil arise from the presence of a significant fraction of U-shaped molecules with low configurational entropy. The initial velocity spike is exploited in field-inversion gel electrophoresis to generate the ``antiresonance,'' which is the basis of size-dependent mobility. Recent computer simulations which include tube-length fluctuations and tube leakage are in excellent accord with the measured velocities.

  9. Anatomy of the Binary Black Hole Recoil: A Multipolar Analysis

    NASA Technical Reports Server (NTRS)

    Schnittman, Jeremy; Buonanno, Alessandra; vanMeter, James R.; Baker, John G.; Boggs, William D.; Centrella, Joan; Kelly, Bernard J.; McWilliams, Sean T.

    2007-01-01

    We present a multipolar analysis of the recoil velocity computed in recent numerical simulations of binary black hole coalescence, for both unequal masses and non-zero, non-precessing spins. We show that multipole moments up to and including 1 = 4 are sufficient to accurately reproduce the final recoil velocity (= 98%) and that only a few dominant modes contribute significantly to it (2 95%). We describe how the relative amplitude, and more importantly, the relative phase, of these few modes control the way in which the recoil builds up throughout the inspiral, merger, and ring-down phases. We also find that the numerical results can be reproduced, to a high level of accuracy, by an effective Newtonian formula for the multipole moments obtained by replacing in the Newtonian formula the radial separation with an effective radius computed from the numerical data. Beyond the merger, the numerical results are reproduced by a superposition of three Kerr quasi-normal modes. Analytic formulae, obtained by expressing the multipole moments in terms of the fundamental QNMs of a Kerr BH, are able to explain the onset and amount of '.anti-kick" for each of the simulations. Lastly, we apply this multipolar analysis to understand the remarkable difference between the amplitudes of planar and non-planar kicks for equal-mass spinning black holes.

  10. Recoiling from a Kick in the Head-On Case

    NASA Technical Reports Server (NTRS)

    Choi, Dae-Il; Kelly, Bernard J.; Boggs, William D.; Baker, John G.; Centrella, Joan; Van Meter, James

    2007-01-01

    Recoil "kicks" induced by gravitational radiation are expected in the inspiral and merger of black holes. Recently the numerical relativity community has begun to measure the significant kicks found when both unequal masses and spins are considered. Because understanding the cause and magnitude of each component of this kick may be complicated in inspiral simulations, we consider these effects in the context of a simple test problem. We study recoils from collisions of binaries with initially head-on trajectories, starting with the simplest case of equal masses with no spin; adding spin and varying the mass ratio, both separately and jointly. We find spin-induced recoils to be significant even in head-on configurations. Additionally, it appears that the scaling of transverse kicks with spins is consistent with post-Newtonian (PN) theory, even though the kick is generated in the nonlinear merger interaction, where PN theory should not apply. This suggests that a simple heuristic description might be effective in the estimation of spin-kicks.

  11. The recoil proton polarization in. pi. p elastic scattering

    SciTech Connect

    Seftor, C.J.

    1988-09-01

    The polarization of the recoil proton for ..pi../sup +/p and ..pi../sup -/p elastic scattering has been measured for various angles at 547 MeV/c and 625 MeV/c by a collaboration involving The George Washington University; the University of California, Los Angeles; and Abilene Christian University. The experiment was performed at the P/sup 3/ East experimental area of the Los Alamos Meson Physics Facility. Beam intensities varied from 0.4 to 1.0 x 10/sup 7/ ..pi../sup -/'s/sec and from 3.0 to 10.0 x 10/sup 7/ ..pi../sup +/'s/sec. The beam spot size at the target was 1 cm in the horizontal direction by 2.5 cm in the vertical direction. A liquid-hydrogen target was used in a flask 5.7 cm in diameter and 10 cm high. The scattered pion and recoil proton were detected in coincidence using the Large Acceptance Spectrometer (LAS) to detect and momentum analyze the pions and the JANUS recoil proton polarimeter to detect and measure the polarization of the protons. Results from this experiment are compared with previous measurements of the polarization, with analyzing power data previously taken by this group, and to partial-wave analysis predictions. 12 refs., 53 figs., 18 tabs.

  12. Hierarchical Carbon with High Nitrogen Doping Level: A Versatile Anode and Cathode Host Material for Long-Life Lithium-Ion and Lithium-Sulfur Batteries.

    PubMed

    Reitz, Christian; Breitung, Ben; Schneider, Artur; Wang, Di; von der Lehr, Martin; Leichtweiss, Thomas; Janek, Jürgen; Hahn, Horst; Brezesinski, Torsten

    2016-04-27

    Nitrogen-rich carbon with both a turbostratic microstructure and meso/macroporosity was prepared by hard templating through pyrolysis of a tricyanomethanide-based ionic liquid in the voids of a silica monolith template. This multifunctional carbon not only is a promising anode candidate for long-life lithium-ion batteries but also shows favorable properties as anode and cathode host material owing to a high nitrogen content (>8% after carbonization at 900 °C). To demonstrate the latter, the hierarchical carbon was melt-infiltrated with sulfur as well as coated by atomic layer deposition (ALD) of anatase TiO2, both of which led to high-quality nanocomposites. TiO2 ALD increased the specific capacity of the carbon while maintaining high Coulombic efficiency and cycle life: the composite exhibited stable performance in lithium half-cells, with excellent recovery of low rate capacities after thousands of cycles at 5C. Lithium-sulfur batteries using the sulfur/carbon composite also showed good cyclability, with reversible capacities of ∼700 mA·h·g(-1) at C/5 and without obvious decay over several hundred cycles. The present results demonstrate that nitrogen-rich carbon with an interconnected multimodal pore structure is very versatile and can be used as both active and inactive electrode material in high-performance lithium-based batteries. PMID:26867115

  13. Ion chromatographic analysis of selected free amino acids and cations to investigate the change of nitrogen metabolism by herbicide stress in soybean (glycine max).

    PubMed

    Jia, M; Keutgen, N; Matsuhashi, S; Mitzuniwa, C; Ito, T; Fujimura, T; Hashimoto, S

    2001-01-01

    A simple and reliable method for the determination of NH4+, K+, Na+, aspartic acid, asparagine, glutamine, and alanine by ion chromatography has been developed. It is suitable for monitoring changes of nitrogen metabolism in soybean because it can accurately measure concentrations o asparagine and NH4+, two key substances for nitrogen storage and transport in this plant species Analysis of asparagine distribution in soybean indicated that higher levels (up to 18.4 micromol g(-1) of fresh mass) occur in stems and lower levels in roots (2.0 micromol g(-1) of fresh mass) and leaves (1.6 micromol g(-1) of fresh mass). When the herbicide metsulfuron-methyl (0.5, 5, and 50 ppb) was applied via the nutrient solution to the root system, asparagine concentrations increased 3-6 times in stems roots, and leaves. Metsulfuron-methyl is known to impair the synthesis of branched amino acids and, in consequence, protein synthesis. Thus, nitrogen consumption was limited, leading to ar accumulation of asparagine. The possible use of this physiological response in agricultural practice to identify herbicide stress in soybean and to detect low-level residues of sulfonylurea herbicides ir the soil is discussed.

  14. Further improvement in ganoderic acid production in static liquid culture of Ganoderma lucidum by integrating nitrogen limitation and calcium ion addition.

    PubMed

    Li, Huan-Jun; Zhang, De-Huai; Han, Li-Liang; Yu, Xuya; Zhao, Peng; Li, Tao; Zhong, Jian-Jiang; Xu, Jun-Wei

    2016-01-01

    To further improve the ganoderic acid (GA) production, a novel integrated strategy by combining nitrogen limitation and calcium ion addition was developed. The effects of the integrated combination on the content of GA-T (one powerful anticancer compound), their intermediates (squalene and lanosterol) and on the transcription levels of GA biosynthetic genes in G. lucidum fermentation were investigated. The maximum GA-T content with the integrated strategy were 1.87 mg/ 100 mg dry cell weight, which was 2.1-4.2 fold higher than that obtained with either calcium ion addition or nitrogen limitation alone, and it is also the highest record as ever reported in submerged fermentation of G. lucidum. The squalene content was increased by 3.9- and 2.2-fold in this case compared with either individual strategy alone. Moreover, the transcription levels of the GA biosynthetic genes encoding 3-hydroxy-3-methyglutaryl coenzyme A reductase and lanosterol synthase were also up-regulated by 3.3-7.5 and 1.3-2.3 fold, respectively. PMID:26508324

  15. Further improvement in ganoderic acid production in static liquid culture of Ganoderma lucidum by integrating nitrogen limitation and calcium ion addition.

    PubMed

    Li, Huan-Jun; Zhang, De-Huai; Han, Li-Liang; Yu, Xuya; Zhao, Peng; Li, Tao; Zhong, Jian-Jiang; Xu, Jun-Wei

    2016-01-01

    To further improve the ganoderic acid (GA) production, a novel integrated strategy by combining nitrogen limitation and calcium ion addition was developed. The effects of the integrated combination on the content of GA-T (one powerful anticancer compound), their intermediates (squalene and lanosterol) and on the transcription levels of GA biosynthetic genes in G. lucidum fermentation were investigated. The maximum GA-T content with the integrated strategy were 1.87 mg/ 100 mg dry cell weight, which was 2.1-4.2 fold higher than that obtained with either calcium ion addition or nitrogen limitation alone, and it is also the highest record as ever reported in submerged fermentation of G. lucidum. The squalene content was increased by 3.9- and 2.2-fold in this case compared with either individual strategy alone. Moreover, the transcription levels of the GA biosynthetic genes encoding 3-hydroxy-3-methyglutaryl coenzyme A reductase and lanosterol synthase were also up-regulated by 3.3-7.5 and 1.3-2.3 fold, respectively.

  16. Measuring the spectrum of mutation induced by nitrogen ions and protons in the human-hamster hybrid cell line A(L)C

    NASA Technical Reports Server (NTRS)

    Kraemer, S. M.; Kronenberg, A.; Ueno, A.; Waldren, C. A.; Chatterjee, A. (Principal Investigator)

    2000-01-01

    Astronauts can be exposed to charged particles, including protons, alpha particles and heavier ions, during space flights. Therefore, studying the biological effectiveness of these sparsely and densely ionizing radiations is important to understanding the potential health effects for astronauts. We evaluated the mutagenic effectiveness of sparsely ionizing 55 MeV protons and densely ionizing 32 MeV/nucleon nitrogen ions using cells of two human-hamster cell lines, A(L) and A(L)C. We have previously characterized a spectrum of mutations, including megabase deletions, in human chromosome 11, the sole human chromosome in the human-hamster hybrid cell lines A(L)C and A(L). CD59(-) mutants have lost expression of a human cell surface antigen encoded by the CD59 gene located at 11p13. Deletion of genes located on the tip of the short arm of 11 (11p15.5) is lethal to the A(L) hybrid, so that CD59 mutants that lose the entire chromosome 11 die and escape detection. In contrast, deletion of the 11p15.5 region is not lethal in the hybrid A(L)C, allowing for the detection of chromosome loss or other chromosomal mutations involving 11p15.5. The 55 MeV protons and 32 MeV/nucleon nitrogen ions were each about 10 times more mutagenic per unit dose at the CD59 locus in A(L)C cells than in A(L) cells. In the case of nitrogen ions, the mutations observed in A(L)C cells were predominantly due to chromosome loss events or 11p deletions, often containing a breakpoint in the pericentromeric region. The increase in the CD59(-) mutant fraction for A(L)C cells exposed to protons was associated with either translocation of portions of 11q onto a hamster chromosome, or discontinuous or "skipping" mutations. We demonstrate here that A(L)C cells are a powerful tool that will aid in the understanding of the mutagenic effects of different types of ionizing radiation.

  17. Application of an online ion chromatography-based instrument for gradient flux measurements of speciated nitrogen and sulfur

    EPA Science Inventory

    In North America, the dry component of total nitrogen and sulfur deposition remains uncertain due to a lack of measurements of sufficient chemical speciation and temporal extent to develop complete annual mass budgets or of sufficient process level detail to improve current air-s...

  18. Disruption of metal ion homeostasis in soils is associated with nitrogen deposition-induced species loss in an Inner Mongolia steppe

    NASA Astrophysics Data System (ADS)

    Tian, Q.-Y.; Liu, N.-N.; Bai, W.-M.; Li, L.-H.; Zhang, W.-H.

    2015-01-01

    Enhanced deposition of atmospheric nitrogen (N) resulting from anthropogenic activities has negative impacts on plant diversity in grassland ecosystems globally. Several mechanisms have been proposed to explain the species loss. Ion toxicity due to N deposition-induced soil acidification has been suggested to be responsible for species loss in acidic grasslands, while few studies have evaluated the role of soil-mediated homeostasis of ions in species loss under elevated N deposition in alkaline grasslands. To determine whether soil-mediated processes are involved in changes in species composition by N deposition, the effects of 9 yr N addition on soil properties, aboveground biomass (AGB) and species composition were investigated in an Inner Mongolia steppe. Low to moderate N addition rate (2, 4, 8 g N m-2 yr-1) significantly enhanced AGB of grasses, while high N addition rate (> 16 g N m-2 yr-1) reduced AGB of forbs, leading to an overall increase in AGB of the community under low to moderate N addition rates. Forb richness was significantly reduced by N addition at rates greater than 8 g N m-2 yr-1, while no effect of N addition on grass richness was observed, resulting in decline in total species richness. N addition depleted base cations (Ca2+, Mg2+ and K+) in soils, reduced soil pH and mobilized Mn2+, Fe3+ and Cu2+ ions in soils. Soil inorganic-N concentration was negatively correlated with forb richness, explaining 27.2% variation of forb richness. The concentrations of base cations (Ca2+ and Mg2+) and metal ions (Mn2+ and Cu2+) showed positively and negatively linear correlation with forb richness, accounting for 25.9 and 41.4% variation of forb richness, respectively. These results reveal that disruption of metal ion homeostasis in soils by N addition, particularly enhanced release of soil Mn2+ and Cu2+ may be associated with reduction in forb richness in temperate steppe of Inner Mongolia.

  19. Response of a delta-doped charge-coupled device to low energy protons and nitrogen ions

    SciTech Connect

    Lepri, S.T.; Nikzad, Shouleh; Jones, T.; Blacksberg, J.; Zurbuchen, T.H.

    2006-05-15

    We present the results of a study of the response of a delta-doped charge-coupled device (CCD) exposed to ions with energies less than 10 keV. The study of ions in the solar wind, the majority having energies in the 1-5 keV range, has proven to be vital in understanding the solar atmosphere and the near Earth space environment. Delta-doped CCD technology has essentially removed the dead layer of the silicon detector. Using the delta-doped detector, we are able to detect H{sup +} and N{sup +} ions with energies ranging from 1 to 10 keV in the laboratory. This is a remarkable improvement in the low energy detection threshold over conventional solid-state detectors, such as those used in space sensors, one example being the solar wind ion composition spectrometer (SWICS) on the Advanced Composition Explorer spacecraft, which can only detect ions with energies greater than 30 keV because of the solid-state detector's minimum energy threshold. Because this threshold is much higher than the average energy of the solar wind ions, the SWICS instrument employs a bulky high voltage postacceleration stage that accelerates ions above the 30 keV detection threshold. This stage is massive, exposes the instrument to hazardous high voltages, and is therefore problematic both in terms of price and its impact on spacecraft resources. Adaptation of delta-doping technology in future space missions may be successful in reducing the need for heavy postacceleration stages allowing for miniaturization of space-borne ion detectors.

  20. First signal from a broadband cryogenic preamplifier cooled by circulating liquid nitrogen in a 7 T Fourier transform ion cyclotron resonance mass spectrometer.

    PubMed

    Choi, Myoung Choul; Lee, Jeong Min; Lee, Se Gyu; Choi, Sang Hwan; Choi, Yeon Suk; Lee, Kyung Jae; Kim, SeungYong; Kim, Hyun Sik; Stahl, Stefan

    2012-12-18

    Despite the outstanding performance of Fourier transform ion cyclotron/mass spectrometry (FTICR/MS), the complexity of the cellular proteome or natural compounds presents considerable challenges. Sensitivity is a key performance parameter of a FTICR mass spectrometer. By improving this parameter, the dynamic range of the instrument can be increased to improve the detection signal of low-abundance compounds or fragment ion peaks. In order to improve sensitivity, a cryogenic detection system was developed by the KBSI (Korean Basic Science Institute) in collaboration with Stahl-Electronics (Mettenheim, Germany). A simple, efficient liquid circulation cooling system was designed and a cryogenic preamplifier implemented inside a FTICR mass spectrometer. This cooling system circulates a cryoliquid from a Dewar to the "liquid circulation unit" through a CF flange to cool a copper block and a cryopreamplifier; the cooling medium is subsequently exhausted into the air. The cryopreamplifier can be operated over a very wide temperature range, from room temperature to low temperature environments (4.2 K). First, ion signals detected by the cryopreamplifier using a circulating liquid nitrogen cooling system were observed and showed a signal-to-noise ratio (S/N) about 130% better than that obtained at room temperature.

  1. Synthesis of Fe16N2 compound Free-Standing Foils with 20 MGOe Magnetic Energy Product by Nitrogen Ion-Implantation

    NASA Astrophysics Data System (ADS)

    Jiang, Yanfeng; Mehedi, Md Al; Fu, Engang; Wang, Yongqiang; Allard, Lawrence F.; Wang, Jian-Ping

    2016-05-01

    Rare-earth-free magnets are highly demanded by clean and renewable energy industries because of the supply constraints and environmental issues. A promising permanent magnet should possess high remanent magnetic flux density (Br), large coercivity (Hc) and hence large maximum magnetic energy product ((BH)max). Fe16N2 has been emerging as one of promising candidates because of the redundancy of Fe and N on the earth, its large magnetocrystalline anisotropy (Ku > 1.0 × 107 erg/cc), and large saturation magnetization (4πMs > 2.4 T). However, there is no report on the formation of Fe16N2 magnet with high Br and large Hc in bulk format before. In this paper, we successfully synthesize free-standing Fe16N2 foils with a coercivity of up to 1910 Oe and a magnetic energy product of up to 20 MGOe at room temperature. Nitrogen ion implantation is used as an alternative nitriding approach with the benefit of tunable implantation energy and fluence. An integrated synthesis technique is developed, including a direct foil-substrate bonding step, an ion implantation step and a two-step post-annealing process. With the tunable capability of the ion implantation fluence and energy, a microstructure with grain size 25–30 nm is constructed on the FeN foil sample with the implantation fluence of 5 × 1017/cm2.

  2. Infrared Spectroscopy of Matrix-Isolated Polycyclic Aromatic Compounds and their Ions. 6; Polycyclic Aromatic Nitrogen Heterocycles

    NASA Technical Reports Server (NTRS)

    Mattioda, A. L.; Hudgins, Douglas M.; Bauschlicher, C. W., Jr.; Rosi, M.; Allamandola, L. J.; DeVincenzi, D. (Technical Monitor)

    2002-01-01

    The matrix-isolation technique has been employed to measure the mid-infrared spectra of several polycyclic aromatic nitrogen heterocycles in both neutral and cationic forms. The species studied include: 7,8 benzoquinoline (C13H9N); 2-azapyrene (C15H9N); 1- and 2-azabenz(a)anthracene (C17H11N); and 1-, 2-, and 4-azachrysene (also C17H11N). The experimentally measured band frequencies and intensities for each molecule are tabulated and compared with their theoretically calculated values computed using density functional theory at the B3LYP/4-31G level. The overall agreement between experiment and theory is quite good, in keeping with previous investigations involving the parent aromatic hydrocarbons. Several interesting spectroscopic trends are found to accompany nitrogen substitution into the aromatic framework of these compounds. First, for the neutral species, the nitrogen atom produces a significant increase in the total integrated infrared intensity across the 1600 - 1100/cm region and plays an essential role in the molecular vibration that underlies an uncharacteristically intense, discrete feature that is observed near 1400/cm in the spectra of 7,8 benzoquinoline, 1-azabenz(a)anthracene, and 4-azachrysene. The origin of this enhanced infrared activity and the nature of the new 1400/cm vibrational mode are explored. Finally, in contrast to the parent hydrocarbon species, these aromatic nitrogen heterocycles possess a significant permanent dipole moment. Consequently, these dipole moments and the rotational constants are reported for these species in their neutral and ionized forms.

  3. A Sustainable Route from Biomass Byproduct Okara to High Content Nitrogen-Doped Carbon Sheets for Efficient Sodium Ion Batteries.

    PubMed

    Yang, Tingzhou; Qian, Tao; Wang, Mengfan; Shen, Xiaowei; Xu, Na; Sun, Zhouzhou; Yan, Chenglin

    2016-01-20

    A sustainable route from the biomass byproduct okara as a natural nitrogen fertilizer to high-content N-doped carbon sheets is demonstrated. The as-prepared unique structure exhibits high specific capacity (292 mAh g(-1) ) and extremely long cycle life (exceeding 2000 cycles). A full battery is devised for the practical use of materials with a flexible/wearable LED screen.

  4. Revealing compressed stops using high-momentum recoils

    DOE PAGESBeta

    Macaluso, Sebastian; Park, Michael; Shih, David; Tweedie, Brock

    2016-03-22

    In this study, searches for supersymmetric top quarks at the LHC have been making great progress in pushing sensitivity out to higher mass, but are famously plagued by gaps in coverage around lower-mass regions where the decay phase space is closing off. Within the common stop-NLSP/neutralino-LSP simplified model, the line in the mass plane where there is just enough phase space to produce an on-shell top quark remains almost completely unconstrained. Here, we show that is possible to define searches capable of probing a large patch of this difficult region, with S/B ~ 1 and significances often well beyond 5σ.more » The basic strategy is to leverage the large energy gain of LHC Run 2, leading to a sizable population of stop pair events recoiling against a hard jet. The recoil not only re-establishes a ET, but also leads to a distinctive anti-correlation between the ET and the recoil jet transverse vectors when the stops decay all-hadronically. Accounting for jet combinatorics, backgrounds, and imperfections in ET measurements, we estimate that Run 2 will already start to close the gap in exclusion sensitivity with the first few 10s of fb–1. By 300 fb–1, exclusion sensitivity may extend from stop masses of 550 GeV on the high side down to below 200 GeV on the low side, approaching the “stealth” point at mt¯ = mt and potentially overlapping with limits from tt¯ cross section and spin correlation measurements.« less

  5. Revealing compressed stops using high-momentum recoils

    NASA Astrophysics Data System (ADS)

    Macaluso, Sebastian; Park, Michael; Shih, David; Tweedie, Brock

    2016-03-01

    Searches for supersymmetric top quarks at the LHC have been making great progress in pushing sensitivity out to higher mass, but are famously plagued by gaps in coverage around lower-mass regions where the decay phase space is closing off. Within the common stop-NLSP/neutralino-LSP simplified model, the line in the mass plane where there is just enough phase space to produce an on-shell top quark remains almost completely unconstrained. Here, we show that is possible to define searches capable of probing a large patch of this difficult region, with S/B ˜ 1 and significances often well beyond 5 σ. The basic strategy is to leverage the large energy gain of LHC Run 2, leading to a sizable population of stop pair events recoiling against a hard jet. The recoil not only re-establishes a [InlineMediaObject not available: see fulltext.] signature, but also leads to a distinctive anti-correlation between the [InlineMediaObject not available: see fulltext.] and the recoil jet transverse vectors when the stops decay all-hadronically. Accounting for jet combinatorics, backgrounds, and imperfections in [InlineMediaObject not available: see fulltext.] measurements, we estimate that Run 2 will already start to close the gap in exclusion sensitivity with the first few 10s of fb-1. By 300 fb-1, exclusion sensitivity may extend from stop masses of 550 GeV on the high side down to below 200 GeV on the low side, approaching the "stealth" point at {m}_{overline{t}}={m}_t and potentially overlapping with limits from toverline{t} cross section and spin correlation measurements.

  6. Influence of nitrogen ion implantation on filtration of fluoride and cadmium using polysulfone/chitosan blend membranes

    NASA Astrophysics Data System (ADS)

    Wanichapichart, P.; Bootluck, W.; Thopan, P.; Yu, L. D.

    2014-05-01

    Composite membranes between polysulfone and biopolymer chitosan were produced with variations of the chitosan content and temperature during the phase inversion process. The lower chitosan content led to lower water permeability and smaller membrane cut off. When the temperature of the phase inversion process was reduced from 25 °C to 5 °C, membrane pores were further decreased from somewhat greater than 10 kDa to a value smaller than 2 kDa. After being implanted with N-ions of 50 keV to a fluence of 1 × 1015 ions/cm2, the composite membranes showed an improvement in the rejection by about 15% for fluoride and 10% for cadmium. In addition, a slight increase in permeation flux was observed in the ion implanted membranes. Filtration tests using the N-ion implanted membranes showed that fluoride was rejected from 100 ppm NaF solution by 47% and the rejection was increased to 60% when 2.20 ppm underground water was filtered. In the case of cadmium, the rejection was increased from 80% to 90% as an effect of the N-ion implantation.

  7. B -> D* l nu at zero recoil: an update

    SciTech Connect

    Bailey, Jon A.; Bazavov, A.; Bernard, C.; Bouchard, C.M.; DeTar, C.; El-Khadra, A.X.; Freeland, E.D.; Gamiz, E.; Gottlieb, Steven; Heller, U.M.; Hetrick, J.E.

    2010-11-01

    We present an update of our calculation of the form factor for {bar B} {yields} D*{ell}{bar {nu}} at zero recoil, with higher statistics and finer lattices. As before, we use the Fermilab action for b and c quarks, the asqtad staggered action for light valence quarks, and the MILC ensembles for gluons and light quarks (Luescher-Weisz married to 2+1 rooted staggered sea quarks). In this update, we have reduced the total uncertainty on F(1) from 2.6% to 1.7%.

  8. Projectile paths corrected for recoil and air resistance

    NASA Astrophysics Data System (ADS)

    Kemp, H. R.

    1986-01-01

    The angle of projection of a bullet is not the same as the angle of the bore of the firearm just before firing. This is because recoil alters the direction of the barrel as the bullet moves along the barrel. Neither is the angle of projection of an arrow the same as the direction of the arrow just before it is projected. The difficulty in obtaining the angle of projection limits the value of the standard equation for trajectories relative to a horizontal plane. Furthermore, air resistance makes this equation unrealistic for all but short ranges.

  9. Precision lifetime measurements using the recoil distance method

    SciTech Connect

    Kruecken, R.

    2000-02-01

    The recoil distance method (RDM) for the measurements of lifetimes of excited nuclear levels in the range from about 1 ps to 1,000 ps is reviewed. The New Yale Plunger Device for RDM experiments is introduced and the Differential Decay Curve Method for their analysis is reviewed. Results from recent RDM experiments on SD bands in the mass-190 region, shears bands in the neutron deficient lead isotopes, and ground state bands in the mass-130 region are presented. Perspectives for the use of RDM measurements in the study of neutron-rich nuclei are discussed.

  10. Recoil separator ERNA: charge state distribution, target density, beam heating, and longitudinal acceptance

    NASA Astrophysics Data System (ADS)

    Schürmann, D.; Strieder, F.; Di Leva, A.; Gialanella, L.; De Cesare, N.; D'Onofrio, A.; Imbriani, G.; Klug, J.; Lubritto, C.; Ordine, A.; Roca, V.; Röcken, H.; Rolfs, C.; Rogalla, D.; Romano, M.; Schümann, F.; Terrasi, F.; Trautvetter, H. P.

    2004-10-01

    For improved cross section measurements of the reaction 12C(α,γ)16O in inverted kinematics, a recoil separator ERNA is developed at the 4 MV Dynamitron tandem accelerator in Bochum to detect directly the 16O recoils with high efficiency. The 16O recoils are produced by the 12C projectiles in a windowless 4He gas target. We report on the charge state distribution of the 16O recoils, the gas target density, the beam heating of the gas target, and the acceptance of the separator along the extended gas target.

  11. Nitrogen In Saturn's Magnetosphere

    NASA Astrophysics Data System (ADS)

    Smith, H. T.; Sittler, E. C.; Johnson, R. E.; McComas, D. J.; Reisenfeld, D.; Shappirio, M. D.; Baragiola, R.; Michael, M.; Shematovich, V. I.; Crary, F.; Young, D. T.

    2004-12-01

    We are analyzing CAPS instrument data on Cassini to look for nitrogen ions in Saturn's magnetosphere. Because Voyager could not separate oxygen and nitrogen, there has been considerable controversy on nitrogen's presence and relative importance. Two principal sources have been suggested: Titan's atmosphere and nitrogen species trapped in Saturn's icy satellite surfaces (Sittler et al 2004). The latter may be primordial nitrogen, likely as NH3 in ice (Stevenson 1982; Squyers et al. 1983) or nitrogen ions that have been implanted in the surface (Delitsky and Lane 2002). We will present the results of Saturnian nitrogen cloud modeling and relevant CAPS observations. We recently described the Titan source (Michael, et al. 2004; Shematovich et al. 2003; Smith et al. 2004; Sittler et al. 2004) in preparation for Cassini's Saturnian plasma measurements. Two components were identified: energetic nitrogen ions formed near Titan and energized as they diffused inward (Sittler et al. 2004) and neutrals in orbits with small perigee that became ionized in the inner magnetosphere (Smith et al 2004). The latter component would be a source of lower energy, co-rotating nitrogen ions in the inner magnetosphere. Such a component would have an energy spectrum similar to nitrogen species sputtered from the icy satellite surfaces (Johnson and Sittler 1990). However, the mass spectrum would differ, likely containing NHx and NOx species also, and, hence, may be separated from the Titan source. Our preliminary analysis for nitrogen species in the CAPS data will be compared to our models. Of interest will be the energy spectra, which can indicate whether any nitrogen present is formed locally or near Titan's orbit and diffused inward. This work is supported by the NASA Planetary Atmospheres, NASA Graduate Student Research, Virginia Space Grant Consortium Graduate Research Fellowship and CAPS Cassini instrument team programs.

  12. From N-Nitro to N-Nitroamino: Preparation of High-Performance Energetic Materials by Introducing Nitrogen-Containing Ions.

    PubMed

    Yin, Ping; Shreeve, Jean'ne M

    2015-11-23

    In the design of energetic materials, high energetic performance and good molecular stability are two main goals. Energetic functionalization which strives for maximum energy often results in unstable chemical bonds and causes safety problems in practical production and storage operations. In this work, N-nitro- and N-nitroamino-functionalized mono- and bis(1,2,4-triazoles) were synthesized and characterized by infrared, and multinuclear NMR spectra, and elemental analyses. The N-nitroamino-functionalization strategy was employed for bis(imidazole), leading to high density compound 14 (2.007 g cm(-3) at 100 K; 1.94 g cm(-3) at room temperature) and energetic salt 15. While N-nitro-functionalized products are thermally unstable and highly moisture sensitive, N-nitroamino-functionalized energetic salts, which are comprised of additional nitrogen-containing ions, exhibit good density, moderate to excellent structural stabilities, and high performance.

  13. One-pot synthesis of highly greenish-yellow fluorescent nitrogen-doped graphene quantum dots for pyrophosphate sensing via competitive coordination with Eu(3+) ions.

    PubMed

    Lin, Liping; Song, Xinhong; Chen, Yiying; Rong, Mingcong; Zhao, Tingting; Jiang, Yaqi; Wang, Yiru; Chen, Xi

    2015-10-01

    Highly fluorescent nitrogen-doped graphene quantum dots (N-GQDs) with greenish-yellow emission and quantum yield of 13.2% have been synthesized via a one-pot hydrothermal method. The obtained N-GQDs displayed excellent optical properties, high photostability and resistance to strong ion strength. Based on the higher affinity of pyrophosphate (PPi) than carboxyl and amido groups on the surface of the N-GQDs to Eu(3+), a Eu(3+)-modulated N-GQD off-on fluorescent probe for PPi detection was constructed with a detection limit of 0.074 μM. The detection process was simple in design, easy to operate, and showed a highly selective response to PPi in the presence of co-existing anions. This work widens the applications of N-GQDs with versatile functionality and reactivity in clinical diagnostics and as biosensors.

  14. Effect of carbon on the microstructure, mechanical properties and metal ion release of Ni-free Co-Cr-Mo alloys containing nitrogen.

    PubMed

    Mori, Manami; Yamanaka, Kenta; Kuramoto, Koji; Ohmura, Kazuyo; Ashino, Tetsuya; Chiba, Akihiko

    2015-10-01

    This paper investigated the effect of carbon addition on the microstructure and tensile properties of Ni-free biomedical Co-29Cr-6Mo (mass%) alloys containing 0.2 mass% nitrogen. The release of metal ions by the alloys was preliminarily evaluated in an aqueous solution of 0.6% sodium chloride (NaCl) and 1% lactic acid, after which samples with different carbon contents were subjected to hot rolling. All specimens were found to primarily consist of a γ-phase matrix due to nitrogen doping, with only the volume fraction of M23C6 increasing with carbon concentration. Owing to the very fine size of these carbide particles (less than 1 μm), which results from fragmentation during hot rolling, the increased formation of M23C6 increased the 0.2% proof stress, but reduced the elongation-to-failure. Carbon addition also increased the amount of Co and Cr released during static immersion; Co and Cr concentrations at the surfaces, which increased with increasing the bulk carbon concentrations, possibly enhanced the metal ion release. However, only a very small change in the Mo concentration was noticed in the solution. Therefore, it is not necessarily considered a suitable means of improving the strength of biomedical Co-Cr-Mo alloys, even though it has only to date been used in this alloy system. The results of this study revealed the limitations of the carbon strengthening and can aid in the design of biomedical Co-Cr-Mo-based alloys that exhibit the high durability needed for their practical application.

  15. Three-dimensional nitrogen-doped graphene frameworks anchored with bamboo-like tungsten oxide nanorods as high performance anode materials for lithium ion batteries

    NASA Astrophysics Data System (ADS)

    Gu, Xinyuan; Wu, Feilong; Lei, Bingbing; Wang, Jing; Chen, Ziliang; Xie, Kai; Song, Yun; Sun, Dalin; Sun, Lixian; Zhou, Huaiying; Fang, Fang

    2016-07-01

    Bamboo-like WO3 nanorods were anchored on three-dimensional nitrogen-doped graphene frameworks (r-WO3/3DNGF) by a facile one-step hydrothermal synthesis plus heating processes. There is a strong dependence of the obtained r-WO3/3DNGF nanostructures on the content of 3DNGF. The composite with 20 wt% 3DNGF content shows the most favorable structure where bamboo-like WO3 nanorods lie flat on the surface of fungus-like 3DNGF, and exhibits a high discharge capacity of 828 mAh g-1 over 100 cycles at 80 mA g-1 with the largest capacity retention of 73.9% for WO3 and excellent rate capacities of 719, 665, 573, 453 and 313 mAh g-1 at 80, 160, 400, 800 and 1600 mA g-1, respectively. The electrochemical performance is better than most of reported WO3-based carbonaceous composites, which can be attributed to the synergistic effects of the following actions: i) WO3 nanorods effectively shorten the diffusion path of Li+; ii) mechanically strong 3DNGF alleviates the huge volume change of WO3 upon Li+ intercalation/extraction; and iii) nitrogen-doping in 3D graphene frameworks improves electronic conductivity and provides large numbers of lithium ion diffusion channels.

  16. Silicon shallow doping by erbium and oxygen recoils implantation

    NASA Astrophysics Data System (ADS)

    Feklistov, K. V.; Cherkov, A. G.; Popov, V. P.

    2016-09-01

    In order to get shallow high doping of Si with optically active complexes ErOn, Er followed by O recoils implantation was realized by means of subsequent Ar+ 250-290 keV implantation with doses 2×1015-1×1016 cm-2 through 50-nm deposited films of Er and then SiO2, accordingly. High Er concentration up to 5×1020 cm-3 to the depth of 10 nm was obtained after implantation. However, about a half of the Er implanted atoms become part of surface SiO2 during post-implantation annealing at 950 °C for 1 h in the N2 ambient under a SiO2 cap. The mechanism of Er segregation into the cap oxide following the moving amorphous-crystalline interface during recrystallization was rejected by the transmission electron microscopy (TEM) analysis. Instead, the other mechanism of immobile Er atoms and redistribution of recoil-implanted O atoms toward cap oxide was proposed. It explains the observed formation of two Er containing phases: Er-Si-O phase with a high O content adjacent to the cap oxide and deeper O depleted Er-Si phase. The correction of heat treatments is proposed in order to avoid the above-mentioned problems.

  17. A Measurement of the Recoil Polarization of Electroproduced {Lambda}(1116)

    SciTech Connect

    Simeon McAleer

    2002-01-01

    The CEBAF Large Acceptance Spectrometer at the Thomas Jefferson National Laboratory was used to study the reaction e + p {yields} e{prime} + K{sup +} + {Lambda}(1116) for events where {Lambda}(1116) subsequently decayed via the channel {Lambda}(1116) {yields} p + {pi}{sup -}. Data were taken at incident electron beam energies of 2.5, 4.0, and 4.2 GeV during the 1999 E1C run period. They hyperon production spectra span the Q{sup 2} range from 0.5 to 2.8 GeV{sup 2} and nearly the entire range in the center of mass angles. The proton angular distribution in the {Lambda}(1116) rest frame is used to deduce the recoil polarization of the hyperon, and the W and cos {theta}{sub cm}{sup K+} dependence of the recoil polarization will be presented. The data show sizeable negative polarizations for the {Lambda}(1116) as a function of both cos {theta}{sub cm}{sup K+} and W.

  18. Disruption of metal ion homeostasis in soils is associated with nitrogen deposition-induced species loss in an Inner Mongolia steppe

    NASA Astrophysics Data System (ADS)

    Tian, Q.-Y.; Liu, N.-N.; Bai, W.-M.; Li, L.-H.; Zhang, W.-H.

    2015-06-01

    Enhanced deposition of atmospheric nitrogen (N) resulting from anthropogenic activities has negative impacts on plant diversity in ecosystems. Several mechanisms have been proposed to explain the species loss. Ion toxicity due to N deposition-induced soil acidification has been suggested to be responsible for species loss in acidic grasslands, while few studies have evaluated the role of soil-mediated homeostasis of ions in species loss under elevated N deposition in grasslands with neutral or alkaline soils. To determine whether soil-mediated processes are involved in changes in biodiversity induced by N deposition, the effects of 9-year N addition on soil properties, aboveground biomass (AGB) and species richness were investigated in an Inner Mongolia steppe. Low to moderate N addition rate (2, 4, 8 g N m-2 yr-1) significantly enhanced AGB of graminoids, while high N addition rate (≥ 16 g N m-2 yr-1) reduced AGB of forbs, leading to an overall increase in AGB of the community under low to moderate N addition rates. Forb richness was significantly reduced by N addition at rates greater than 8 g N m-2 yr-1, while no effect of N addition on graminoid richness was observed, resulting in decline in total species richness. N addition reduced soil pH, depleted base cations (Ca2+, Mg2+ and K+) and mobilized Mn2+, Fe3+, Cu2+ and Al3+ ions in soils. Soil inorganic-N concentration was negatively correlated with forb richness and biomass, explaining 23.59% variation of forb biomass. The concentrations of base cations (Ca2+ and Mg2+) and metal ions (Mn2+, Cu2+ and, Fe3+) showed positively and negatively linear correlation with forb richness, respectively. Changes in the metal ion concentrations accounted for 42.77% variation of forb richness, while reduction of base cations was not associated with the reduction in forb richness. These results reveal that patterns of plant biodiversity in the temperate steppe of Inner Mongolia are primarily driven by increases in metal ion

  19. Recent Results from the Commissioning of the HRIBF Recoil Mass Spectrometer

    NASA Astrophysics Data System (ADS)

    Ginter, T. N.; Hamilton, J. H.; Ramayya, A. V.; Gross, C. J.; Johnson, J. W.; Shapira, D.; Akovali, Y. A.; Brinkman, M. J.; Mas, J.; McConnell, J. W.; Milner, W. T.; James, A. N.

    1997-04-01

    The Recoil Mass Spectrometer (RMS) at the Holifield Radioactive Ion Beam Facility at Oak Ridge National Laboratory (Managed by Lockheed Martin Energy Research Corporation for the U.S. Department of Energy.) is designed (Cole, J. D., et al.) al., Nucl. Instrum. Methods B70 (1992), 343. to transmit ions with rigidities of up to K = 100 resulting from fusion-evaporation and other nuclear reactions. Commissioning tests (We would like to acknowledge the work performed by P. F. Mantica, J. J. Das, and R. L. Auble on the installation of the RMS.) have been under way on the RMS and auxiliary detectors at its target position and focal plane. These tests, performed using normal and symmetric kinematic reactions, have shown that the RMS has an A/Q acceptance of ± 5% and an energy acceptance of ± 10%. A mass resolution M/ΔM of 470 was obtained using a ^58Ni beam on a ^60Ni target, with little primary beam observed at the focal plane. Recent results from these tests will be presented.

  20. Advances in the helium-jet coupled on-line mass separator RAMA. [Recoil Atom Mass Analyzer

    SciTech Connect

    Moltz, D M; Aysto, J; Cable, M D; Parry, R F; Haustein, P E; Wouters, J M; Cerny, J

    1980-01-01

    General improvements to the on-line mass separator RAMA (Recoil Atom Mass Analyzer) have yielded a greater reliability and efficiency for some elements. A new utilitarian helium-jet chamber has been installed to facilitate quick target and degrader foil changes in addition to a new ion source holder. A higher efficiency hollow-cathode, cathode-extraction ion source, for lower melting point elements (< 1200/sup 0/C) has also been designed. Tests with the beta-delayed proton emitter /sup 37/Ca showed a factor of five increase in yield over the old hollow-cathode, anode-extraction source. A differentially-pumped-tape drive system compatible with both ..gamma..-..gamma.. and ..beta..-..gamma.. experiments has been incorporated into the general detection system. All major operating parameters will soon be monitored by a complete stand-alone microprocessor system which will eventually be upgraded to a closed-loop control system.

  1. Ion-exchange method in the collection of nitrate from freshwater ecosystems for nitrogen and oxygen isotope analysis: a review.

    PubMed

    Li, Wen-Bing; Song, Yao-Bin; Xu, Hong-Ke; Chen, Ling-Yun; Dai, Wen-Hong; Dong, Ming

    2015-07-01

    Nitrate (NO3(-)) contamination of freshwater is considered one of the most prevalent global environmental problems. Dual stable isotopic compositions (δ(15)N and δ(18)O) of NO3(-) can provide helpful information and have been well documented as being a powerful tool to track the source of NO3(-) in freshwater ecosystems. The ion-exchange method is a reliable and precise technique for measuring the δ(15)N and δ(18)O of NO3(-) and has been widely employed to collect NO3(-) from freshwater ecosystems. This review summarizes and presents the principles, affecting factors and corresponding significant improvements of the ion-exchange method. Finally, potential improvements and perspectives for the applicability of this method are also discussed, as are suggestions for further research and development drawn from the overall conclusions.

  2. Geometries, electronic states, and spectroscopic properties of nitrogen-doped fullerene fragment C10N2(II) and its ions.

    PubMed

    Zhu, Xiaolei

    2008-03-01

    The DFT(B3LYP)/6-31G(d)//CCSD(T)/6-31G(d) method is used to investigate the low-lying electronic states of C(10)N(2)(II) and its ions. Mulliken populations, leading configurations, bond orders, and compositions of molecular orbitals are employed to explore the nature of bonding in the electronic states of C(10)N(2)(II) and its ions. Electron affinity, ionization energy, binding energy of C(10)N(2)(II), and anion photoelectron spectra of C(10)N(2)(II)(-) are also estimated at the CCSD(T)/6-31G(d) level. On the other hand, the similarities and differences between C(10)N(2)(I) and C(10)N(2)(II) are compared and discussed.

  3. Coating of α-MoO3 on nitrogen-doped carbon nanotubes by electrodeposition as a high-performance cathode material for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Zhang, Hui; Liu, Xiaojiang; Wang, Ruilin; Mi, Rui; Li, Shaomin; Cui, Yanhua; Deng, Yafeng; Mei, Jun; Liu, Hao

    2015-01-01

    In this work, α-MoO3 nanoparticles are grown on the surface of nitrogen doped carbon nanotubes (N-CNTs) via a facile electrodeposition method. The morphology of as-prepared nanocomposite shows that the interconnected α-MoO3 nanoparticles are homogeneously distributed on the surface of N-CNTs. When investigated as a cathode material for lithium ion batteries, the nanocomposite reveals a high reversible discharge capacity of 250 mA h g-1 at a current density of 30 mA g-1, simultaneously with good cycling performance and excellent rate capability compared with pristine MoO3 powder. Kinetics of this process is investigated by electrochemical impedance spectroscopy to understand the difference in electrochemical performance and the interface properties between the α-MoO3/N-CNTs nanocomposite and pristine MoO3 powder electrode. The correlation between the unique structural features of α-MoO3/N-CNTs nanocomposite and its excellent electrochemical performance is also discussed. The excellent performance makes the as-prepared α-MoO3/N-CNTs nanocomposite a promising cathode material for high-performance lithium ion batteries.

  4. One-step argon/nitrogen binary plasma jet irradiation of Li4Ti5O12 for stable high-rate lithium ion battery anodes

    NASA Astrophysics Data System (ADS)

    Lan, Chun-Kai; Chuang, Shang-I.; Bao, Qi; Liao, Yen-Ting; Duh, Jenq-Gong

    2015-02-01

    Atmospheric pressure Ar/N2 binary plasma jet irradiation has been introduced into the manufacturing process of lithium ions batteries as a facile, green and scalable post-fabrication treatment approach, which enhanced significantly the high-rate anode performance of lithium titanate (Li4Ti5O12). Main emission lines in Ar/N2 plasma measured by optical emission spectroscopy reveal that the dominant excited high-energy species in Ar/N2 plasma are N2*, N2+, N∗ and Ar∗. Sufficient oxygen vacancies have been evidenced by high resolution X-ray photoelectron spectroscopy analysis and Raman spectra. Nitrogen doping has been achieved simultaneously by the surface reaction between pristine Li4Ti5O12 particles and chemically reactive plasma species such as N∗ and N2+. The variety of Li4Ti5O12 particles on the surface of electrodes after different plasma processing time has been examined by grazing incident X-Ray diffraction. Electrochemical impedance spectra (EIS) confirm that the Ar/N2 atmospheric plasma treatment facilitates Li+ ions diffusion and reduces the internal charge-transfer resistance. The as-prepared Li4Ti5O12 anodes exhibit a superior capacity (132 mAh g-1) and excellent stability with almost no capacity decay over 100 cycles under a high C rate (10C).

  5. Surface modification produced by a nitrogen operated plasma focus device: the role of the ion beam in the heating of a substrate

    NASA Astrophysics Data System (ADS)

    Lepone, A.; Kelly, H.; Lamas, D.; Márquez, A.

    1999-04-01

    The role of the nitrogen ion beam generated with a small energy plasma focus (PF) device in the thermal processing of an austenitic stainless steel substrate is discussed. A numerical solution of the heat equation which takes into account the temperature variations of the thermal coefficients of the material is presented. By using several characteristics of the beam determined in previous works, it is found that the energy content of the beam is not enough to promote a strong heating of the outer layers of the substrate, which is required to explain the introduction of foreign particles to depths well beyond the ion range in the material, and also the martensitic transformation of steel up to a depth of ≈0.6 μm found in this work. The surface treatment is thus attributed to a plasma bubble generated by the disruption of the plasma column, and some evidence of its presence is obtained by employing a Faraday cup (FC). When the numerical model is used with an input energy density corresponding to the experimental value, and with a delivery time equal to the temporal width of the bubble, the evolution of the temperature profiles along the substrate depth shows a melting front reaching the proper depth to explain the penetration of Ti and N atoms found in a previous work, and the martensitic transformation depth presented in this work.

  6. Solid-solid grinding/templating route to magnetically separable nitrogen-doped mesoporous carbon for the removal of Cu(2+) ions.

    PubMed

    Chen, Aibing; Yu, Yifeng; Zhang, Yue; Xing, Tingting; Wang, Yanyan; Zhang, Yexin; Zhang, Jian

    2014-08-30

    N-doped ordered mesoporous carbon materials (NOMC) with 2D hexagonal symmetry structure were synthesized via a facile solid-solid grinding/templating route, in which the ionic liquids (ILs) of 1-cyanoethyl-3-methylimidazolium chloride and SBA-15 were employed as the precursor and hard template, respectively. The as-synthesized NOMC features with a uniform mesoporous size (3.5nm), ropes-like morphology (0.4-1μm in length) and high surface area (803m(2)/g). The quantitative analysis revealed the nitrogen content on the surface of NOMC is 5.5at%. Magnetic iron nanoparticles were successfully embedded into the carbon matrix by introducing iron chloride to the mixture of SBA-15 and ILs during the synthesis process. The NOMC-Fe composite possessed superior adsorption capacity of Cu(2+) ions (23.6mg/g). Kinetic and isothermal analysis demonstrated the strong interactions between Cu(2+) ion and the adsorbent. Furthermore, the composite was magnetically separable from solution under an external magnetic field and thus displayed a superior reusability in the recycling test. PMID:25072134

  7. Ion-pair formation of Bi(III)-iodide with some nitrogenous drugs and its application to pharmaceutical preparations.

    PubMed

    Abdel-Gawad, F M

    1998-01-01

    A systematic spectrophotometric study on the ion-pair formation of Bi(III)-iodide with amineptine hydrochloride, piribedil and trimebutine maleate is carried out. The optimal experimental conditions pH, concentration of Bi(III) nitrate, potassium iodide; and the nature and amount of organic solvent have been studied. The ion pairs are soluble in 1,2-dichloroethane and the optimum pH range is 2.0-2.8. By application of the methods of Sommer and Job involving non-equimolar solutions, the conditional stability constant (log K') of the Bi(III) piridedil ion pair (1:1) at the optimum pH of 2.4 and an ionic strength (mu) 0.1 M, was found to be 5.436. The validity of Beer's law has been tested in the concentration range 5-50 microg ml(-1) in the organic layer, the relative standard deviation is less than 1%. The method is applied to the determination of these drugs in tablets without interference. PMID:9535191

  8. A Quadrupole Ion Trap Mass Spectrometer for Quantitative Analysis of Nitrogen-Purged Compartments within the Space Shuttle

    NASA Technical Reports Server (NTRS)

    Ottens, Andrew K.; Griffin, Timothy P.; Helms, William R.; Yost, Richard A.; Steinrock, T. (Technical Monitor)

    2001-01-01

    To enter orbit the Space Shuttle burns 1.8 million liters of liquid hydrogen combined with 0.8 million liters of liquid oxygen through three rocket engines mounted in the aft. NASA monitors the nitrogen-purged aft compartment for increased levels of hydrogen or oxygen in order to detect and determine the severity of a cryogenic fuel leak. Current monitoring is accomplished with a group of mass spectrometer systems located as much as 400 feet away from the shuttle. It can take up to 45 seconds for gas to reach the mass spectrometer, which precludes monitoring for leaks in the final moments before liftoff (the orbiter engines are started at T-00:06 seconds). To remedy the situation, NASA is developing a small rugged mass spectrometer to be used as point-sources around the Space Shuttle.

  9. Beam suppression of the DRAGON recoil separator for 3He(α,γ)7Be

    NASA Astrophysics Data System (ADS)

    Sjue, S. K. L.; Nara Singh, B. S.; Adsley, P.; Buchmann, L.; Carmona-Gallardo, M.; Davids, B.; Fallis, J.; Fulton, B. R.; Galinski, N.; Hager, U.; Hass, M.; Howell, D.; Hutcheon, D. A.; Laird, A. M.; Martin, L.; Ottewell, D.; Reeve, S.; Ruiz, C.; Ruprecht, G.; Triambak, S.

    2013-02-01

    Preliminary studies in preparation for an absolute cross-section measurement of the radiative capture reaction 3He(α,γ)7Be with the DRAGON recoil separator have demonstrated beam suppression >1014 at the 90% confidence level. A measurement of this cross section by observation of 7Be recoils at the focal plane of the separator should be virtually background free.

  10. Analytical calculation of radiative-recoil corrections to muonium hyperfine splitting: Muon-line contribution

    SciTech Connect

    Eides, M.I.; Karshenboim, S.G.; Shelyuto, V.A. )

    1991-02-01

    Analytic expression for radiative-recoil corrections to muonium ground-state hyperfine splitting induced by muon-line radiative insertions is obtained. This result completes the program of analytic calculation of all radiative-recoil corrections. The perspectives of further muonium hyperfine splitting investigations are also discussed.

  11. Optimal control of gun recoil in direct fire using magnetorheological absorbers

    NASA Astrophysics Data System (ADS)

    Singh, Harinder J.; Wereley, Norman M.

    2014-05-01

    Optimal control of a gun recoil absorber is investigated for minimizing recoil loads and maximizing rate of fire. A multi-objective optimization problem was formulated by considering the mechanical model of the recoil absorber employing a spring and a magnetorheological (MR) damper. The damper forces are predicted by evaluating pressure drops using a nonlinear Bingham-plastic model. The optimization methodology provides multiple optimal design configurations with a trade-off between recoil load minimization and increased rate of fire. The configurations with low or high recoil loads imply low or high rate of fire, respectively. The gun recoil absorber performance is also analyzed for perturbations in the firing forces. The adaptive control of the MR damper for varying gun firing forces provides a smooth operation by returning the recoil mass to its battery position (ready to reload and fire) without incurring an end-stop impact. Furthermore, constant load transmissions are observed with respect to the recoil stroke by implementing optimal control during the simulated firing events.

  12. Exact calculations of nuclear-recoil energies from prompt gamma decays resulting from neutron capture

    SciTech Connect

    Kinney, J.H.

    1981-07-20

    The results of an accurate determination of the recoil spectrum from (n, ..gamma..) reactions in molybdenum are presented. The recoil spectrum has been calculated from nuclear level structure data and measured branching ratios. Angular correlations between successive gammas have been accounted for using the standard theoretical techniques of Racah algebra and the density matrix formalism.

  13. Ab Initio Molecular Dynamics Simulations of Low-Energy Recoil Events in ThO2, CeO2, and ZrO2

    SciTech Connect

    Xiao, Haiyan Y.; Zhang, Yanwen; Weber, William J.

    2012-08-13

    Ab initio molecular dynamics simulations of low-energy recoil events in ThO2, CeO2, and ZrO2 have been carried out to determine the threshold displacement energies, resulting defect configurations, dynamics of defect generation, and role of charge transfer during the process. The results reveal that, in most cases, these fluorite structure oxides exhibit a similar response to low-energy recoils. A variety of different defect configurations are created, consisting mainly of vacancies and interstitials. Charge transfer occurs during the dynamic displacement process. Local charge redistribution leads to cation and O vacancies being negatively and positively charged, respectively. Likewise, due to charge redistribution, the cation and O interstitials are less positively and negatively charged, respectively, than the ions on lattice sites in perfect MO2.

  14. Ab initio molecular dynamics simulations of low energy recoil events in ThO2, CeO2 and ZrO2

    SciTech Connect

    Xiao, Haiyan; Zhang, Yanwen; Weber, William J

    2012-01-01

    Ab initio molecular dynamics simulations of low energy recoil events in ThO2, CeO2 and ZrO2 have been carried out to determine the threshold displacement energies, resulting defect configurations, dynamics of defect generation, and role of charge transfer during the process. The results reveal that, in most cases, these fluorite structure oxides exhibit a similar response to low-energy recoils. A variety of different defect configurations are created, consisting mainly of vacancies and interstitials. Charge transfer occurs during the dynamic displacement process. Local charge redistribution leads to cation and O vacancies being negatively and positively charged, respectively. Likewise, due to charge redistribution, the cation and O interstitials are less positively and negatively charged, respectively, than the ions on lattice sites in perfect MO2.

  15. Comparative study on contribution of charge-transfer collision to excitations of iron ion between argon radio-frequency inductively-coupled plasma and nitrogen microwave induced plasma

    NASA Astrophysics Data System (ADS)

    Satoh, Kozue; Wagatsuma, Kazuaki

    2015-06-01

    This paper describes an ionization/excitation phenomenon of singly-ionized iron occurring in an Okamoto-cavity microwave induced plasma (MIP) as well as an argon radio-frequency inductively-coupled plasma (ICP), by comparing the Boltzmann distribution among iron ionic lines (Fe II) having a wide range of the excitation energy from 4.76 to 9.01 eV. It indicated in both the plasmas that plots of Fe II lines having lower excitation energies (4.76 to 5.88 eV) were fitted on each linear relationship, implying that their excitations were caused by a dominant thermal process such as collision with energetic electron. However, Fe II lines having higher excitation energies (more than 7.55 eV) had a different behavior from each other. In the ICP, Boltzmann plots of Fe II lines assigned to the higher excited levels also followed the normal Boltzmann relationship among the low-lying excited levels, even including a deviation from it in particular excited levels having an excitation energy of ca. 7.8 eV. This deviation can be attributed to a charge-transfer collision with argon ion, which results in the overpopulation of these excited levels, but the contribution is small. On the other hand, the distribution of the high-lying excited levels was non-thermal in the Okamoto-cavity MIP, which did not follow the normal Boltzmann relationship among the low-lying excited levels. A probable reason for the non-thermal characteristics in the MIP is that a charge-transfer collision with nitrogen molecule ion having many vibrational/rotational levels could work for populating the 3d64p (3d54s4p) excited levels of iron ion broadly over an energy range of 7.6-9.0 eV, while collisional excitation by energetic electron would occur insufficiently to excite these high-energy levels.

  16. Synthesis of Fe16N2 compound Free-Standing Foils with 20 MGOe Magnetic Energy Product by Nitrogen Ion-Implantation.

    PubMed

    Jiang, Yanfeng; Mehedi, Md Al; Fu, Engang; Wang, Yongqiang; Allard, Lawrence F; Wang, Jian-Ping

    2016-05-05

    Rare-earth-free magnets are highly demanded by clean and renewable energy industries because of the supply constraints and environmental issues. A promising permanent magnet should possess high remanent magnetic flux density (Br), large coercivity (Hc) and hence large maximum magnetic energy product ((BH)max). Fe16N2 has been emerging as one of promising candidates because of the redundancy of Fe and N on the earth, its large magnetocrystalline anisotropy (Ku > 1.0 × 10(7) erg/cc), and large saturation magnetization (4πMs > 2.4 T). However, there is no report on the formation of Fe16N2 magnet with high Br and large Hc in bulk format before. In this paper, we successfully synthesize free-standing Fe16N2 foils with a coercivity of up to 1910 Oe and a magnetic energy product of up to 20 MGOe at room temperature. Nitrogen ion implantation is used as an alternative nitriding approach with the benefit of tunable implantation energy and fluence. An integrated synthesis technique is developed, including a direct foil-substrate bonding step, an ion implantation step and a two-step post-annealing process. With the tunable capability of the ion implantation fluence and energy, a microstructure with grain size 25-30 nm is constructed on the FeN foil sample with the implantation fluence of 5 × 10(17)/cm(2).

  17. Synthesis of Fe16N2 compound Free-Standing Foils with 20 MGOe Magnetic Energy Product by Nitrogen Ion-Implantation

    PubMed Central

    Jiang, Yanfeng; Mehedi, Md Al; Fu, Engang; Wang, Yongqiang; Allard, Lawrence F.; Wang, Jian-Ping

    2016-01-01

    Rare-earth-free magnets are highly demanded by clean and renewable energy industries because of the supply constraints and environmental issues. A promising permanent magnet should possess high remanent magnetic flux density (Br), large coercivity (Hc) and hence large maximum magnetic energy product ((BH)max). Fe16N2 has been emerging as one of promising candidates because of the redundancy of Fe and N on the earth, its large magnetocrystalline anisotropy (Ku > 1.0 × 107 erg/cc), and large saturation magnetization (4πMs > 2.4 T). However, there is no report on the formation of Fe16N2 magnet with high Br and large Hc in bulk format before. In this paper, we successfully synthesize free-standing Fe16N2 foils with a coercivity of up to 1910 Oe and a magnetic energy product of up to 20 MGOe at room temperature. Nitrogen ion implantation is used as an alternative nitriding approach with the benefit of tunable implantation energy and fluence. An integrated synthesis technique is developed, including a direct foil-substrate bonding step, an ion implantation step and a two-step post-annealing process. With the tunable capability of the ion implantation fluence and energy, a microstructure with grain size 25–30 nm is constructed on the FeN foil sample with the implantation fluence of 5 × 1017/cm2. PMID:27145983

  18. Synthesis of Fe16N2 compound Free-Standing Foils with 20 MGOe Magnetic Energy Product by Nitrogen Ion-Implantation.

    PubMed

    Jiang, Yanfeng; Mehedi, Md Al; Fu, Engang; Wang, Yongqiang; Allard, Lawrence F; Wang, Jian-Ping

    2016-01-01

    Rare-earth-free magnets are highly demanded by clean and renewable energy industries because of the supply constraints and environmental issues. A promising permanent magnet should possess high remanent magnetic flux density (Br), large coercivity (Hc) and hence large maximum magnetic energy product ((BH)max). Fe16N2 has been emerging as one of promising candidates because of the redundancy of Fe and N on the earth, its large magnetocrystalline anisotropy (Ku > 1.0 × 10(7) erg/cc), and large saturation magnetization (4πMs > 2.4 T). However, there is no report on the formation of Fe16N2 magnet with high Br and large Hc in bulk format before. In this paper, we successfully synthesize free-standing Fe16N2 foils with a coercivity of up to 1910 Oe and a magnetic energy product of up to 20 MGOe at room temperature. Nitrogen ion implantation is used as an alternative nitriding approach with the benefit of tunable implantation energy and fluence. An integrated synthesis technique is developed, including a direct foil-substrate bonding step, an ion implantation step and a two-step post-annealing process. With the tunable capability of the ion implantation fluence and energy, a microstructure with grain size 25-30 nm is constructed on the FeN foil sample with the implantation fluence of 5 × 10(17)/cm(2). PMID:27145983

  19. Dielectric barrier structure with hollow electrodes and its recoil effect

    SciTech Connect

    Yu, Shuang; Chen, Qunzhi; Liu, Jiahui; Wang, Kaile; Jiang, Zhe; Sun, Zhili; Zhang, Jue; Fang, Jing

    2015-06-15

    A dielectric barrier structure with hollow electrodes (HEDBS), in which gas flow oriented parallel to the electric field, was proposed. Results showed that with this structure, air can be effectively ignited, forming atmospheric low temperature plasma, and the proposed HEDBS could achieve much higher electron density (5 × 10{sup 15}/cm{sup 3}). It was also found that the flow condition, including outlet diameter and flow rate, played a key role in the evolution of electron density. Optical emission spectroscopy diagnostic results showed that the concentration of reactive species had the same variation trend as the electron density. The simulated distribution of discharge gas flow indicated that the HEDBS had a strong recoil effect on discharge gas, and could efficiently promote generating electron density as well as reactive species.

  20. Calibration of a compact magnetic proton recoil neutron spectrometer

    NASA Astrophysics Data System (ADS)

    Zhang, Jianfu; Ouyang, Xiaoping; Zhang, Xianpeng; Ruan, Jinlu; Zhang, Guoguang; Zhang, Xiaodong; Qiu, Suizheng; Chen, Liang; Liu, Jinliang; Song, Jiwen; Liu, Linyue; Yang, Shaohua

    2016-04-01

    Magnetic proton recoil (MPR) neutron spectrometer is considered as a powerful instrument to measure deuterium-tritium (DT) neutron spectrum, as it is currently used in inertial confinement fusion facilities and large Tokamak devices. The energy resolution (ER) and neutron detection efficiency (NDE) are the two most important parameters to characterize a neutron spectrometer. In this work, the ER calibration for the MPR spectrometer was performed by using the HI-13 tandem accelerator at China Institute of Atomic Energy (CIAE), and the NDE calibration was performed by using the neutron generator at CIAE. The specific calibration techniques used in this work and the associated accuracies were discussed in details in this paper. The calibration results were presented along with Monte Carlo simulation results.

  1. Spectroscopy of {sup 144}Ho using recoil-isomer tagging

    SciTech Connect

    Mason, P. J. R; Cullen, D. M.; Scholey, C.; Greenlees, P. T.; Jakobsson, U.; Jones, P. M.; Julin, R.; Juutinen, S.; Ketelhut, S.; Leino, M.; Nyman, M.; Peura, P.; Puurunen, A.; Rahkila, P.; Ruotsalainen, P.; Sorri, J.; Saren, J.; Uusitalo, J.; Xu, F. R.

    2010-02-15

    Excited states in the proton-unbound odd-odd nucleus {sup 144}Ho have been populated using the {sup 92}Mo({sup 54}Fe,pn){sup 144}Ho reaction and studied using the recoil-isomer-tagging technique. The alignment properties and signature splitting of the rotational band above the I{sup p}i=(8{sup +}){sup 144m}Ho isomer have been analyzed and the isomer confirmed to have a pih{sub 11/2} x nuh{sub 11/2} two-quasiparticle configuration. The configuration-constrained blocking method has been used to calculate the shapes of the ground and isomeric states, which are both predicted to have triaxial nuclear shapes with |gamma|approx =24 deg.

  2. Molecular Dynamics Simulation of Energetic Uranium Recoil Damage in Zircon

    SciTech Connect

    Devanathan, Ram; Corrales, Louis R.; Weber, William J.; Chartier, Alain; Meis, Constantin

    2006-10-11

    Defect production and amorphization due to energetic uranium recoils in zircon (ZrSiO4), which is a promising ceramic nuclear waste form, is studied using molecular dynamics simulations with a partial charge model. An algorithm that distinguishes between undamaged crystal, crystalline defects and amorphous regions is used to develop a fundamental understanding of the primary damage state. The amorphous cascade core is separated from the surrounding crystal by a defect-rich region. Small, chemically inhomogeneous amorphous clusters are also produced around the core. The amorphous regions consist of under-coordinated Zr and polymerized Si leading to amorphization and phase separation on a nanometer scale into Zr- and Si-rich regions. This separation could play an important role in the experimentally observed formation of nanoscale ZrO2 in ZrSiO4 irradiated at elevated temperatures.

  3. Neutron absorbed dose determination by calculations of recoil energy.

    PubMed

    Wrobel, F; Benabdesselam, M; Iacconi, P; Lapraz, D

    2004-01-01

    The aim of this work is to calculate the absorbed dose to matter due to neutrons in the 5-150 MeV energy range. Materials involved in the calculations are Al2O3, CaSO4 and CaS, which may be used as dosemeters and have already been studied for their luminescent properties. The absorbed dose is assumed to be mainly due to the energy deposited by the recoils. Elastic reactions are treated with the ECIS code while for the non-elastic ones, a Monte Carlo code has been developed and allowed to follow the nucleus decay and to determine its characteristics (nature and energy). Finally, the calculations show that the absorbed dose is mainly due to non-elastic process and that above 20 MeV this dose decreases slightly with the neutron energy. PMID:15353750

  4. Recoil Polarization for Delta Excitation in Pion Electroproduction

    SciTech Connect

    J. J. Kelly; R. E. Roche; Z. Chai; M. K. Jones; O. Gayou; A. J. Sarty; S. Frullani; K. Aniol; E. J. Beise; F. Benmokhtar; W. Bertozzi; W. U. Boeglin; T. Botto; E. J. Brash; H. Breuer; E. Brown; E. Burtin; J. R. Calarco; C. Cavata; C. C. Chang; N. S. Chant; J.-P. Chen; M. Coman; D. Crovelli; R. De Leo; S. Dieterich; S. Escoffier; K. G. Fissum; V. Garde; F. Garibaldi; S. Georgakopoulus; S. Gilad; R. Gilman; C. Glashausser; J.-O. Hansen; D. W. Higinbotham; A. Hotta; G. M. Huber; H. Ibrahim; M. Iodice; C. W. de Jager; X. Jiang; A. Klimenko; A. Kozlov; G. Kumbartzki; M. Kuss; L. Lagamba; G. Laveissiere; J. J. LeRose; R. A. Lindgren; N. Liyanage; G. J. Lolos; R. W. Lourie; D. J. Margaziotis; F. Marie; P. Markowitz; S. McAleer; D. Meekins; R. Michaels; B. D. Milbrath; J. Mitchell; J. Nappa; D. Neyret; C. F. Perdrisat; M. Potokar; V. A. Punjabi; T. Pussieux; R. D. Ransome; P. G. Roos; M. Rvachev; A. Saha; S. Sirca; R. Suleiman; S. Strauch; J. A. Templon; L. Todor; P. E. Ulmer; G. M. Urciuoli; L. B. Weinstein; K. Wijesooriya; B. Wojtsekhowski; X. Zheng; and L. Zhu

    2005-08-01

    We measured angular distributions of recoil-polarization response functions for neutral pion electroproduction for W=1.23 GeV at Q{sup 2}=1.0 (GeV/c){sup 2}, obtaining 14 separated response functions plus 2 Rosenbluth combinations; of these, 12 have been observed for the first time. Dynamical models do not describe quantities governed by imaginary parts of interference products well, indicating the need for adjusting magnitudes and phases for nonresonant amplitudes. We performed a nearly model-independent multipole analysis and obtained values for Re(S1+/M1+)=-(6.84+/-0.15)% and Re(E1+/M1+)=-(2.91+/-0.19)% that are distinctly different from those from the traditional Legendre analysis based upon M1+ dominance and sp truncation.

  5. Study of nuclear recoils in liquid argon with monoenergetic neutrons

    NASA Astrophysics Data System (ADS)

    Regenfus, C.; Allkofer, Y.; Amsler, C.; Creus, W.; Ferella, A.; Rochet, J.; Walter, M.

    2012-07-01

    In the framework of developments for liquid argon dark matter detectors we assembled a laboratory setup to scatter neutrons on a small liquid argon target. The neutrons are produced mono-energetically (Ekin = 2.45 MeV) by nuclear fusion in a deuterium plasma and are collimated onto a 3" liquid argon cell operating in single-phase mode (zero electric field). Organic liquid scintillators are used to tag scattered neutrons and to provide a time-of-flight measurement. The setup is designed to study light pulse shapes and scintillation yields from nuclear and electronic recoils as well as from alpha particles at working points relevant for dark matter searches. Liquid argon offers the possibility to scrutinise scintillation yields in noble liquids with respect to the population strength of the two fundamental excimer states. Here we present experimental methods and first results from recent data towards such studies.

  6. B{yields}D* at zero recoil revisited

    SciTech Connect

    Gambino, Paolo; Mannel, Thomas; Uraltsev, Nikolai

    2010-06-01

    We examine the B{yields}D* form factor at zero recoil using a continuum QCD approach rooted in the heavy quark sum rules framework. A refined evaluation of the radiative corrections as well as the most recent estimates of higher-order power terms together with more careful continuum calculation are included. An upper bound on the form factor of F(1) < or approx. 0.93 is derived, based on just the positivity of inelastic contributions. A model-independent estimate of the inelastic contributions shows they are quite significant, lowering the form factor by about 6% or more. This results in an unbiased estimate F(1){approx_equal}0.86 with about 3% uncertainty in the central value.

  7. Sub-barrier reactions measured using a recoil mass separator

    SciTech Connect

    Betts, R.R.

    1988-01-01

    Few data exist in the sub-barrier region for reaction channels other than fusion. In particular, our experimental knowledge of quasi-elastic transfer reactions is sparse, despite the belief that this particular channel may be dominant in determining some features of the sub-barrier fusion enhancement. Transfer reactions are governed primarily by the closet approach of the colliding nuclei which, at low energies, results in a strong backward peaking of the angular distribution in the center-of-mass frame. For situations where the projectile has a significant fraction of the target mass, as is so in most cases of interest, the backscattered projectile-like fragment has such low energy that the usual techniques of measurement and identification become invalid. Here, we report on a solution to this problem which allows a systematic study of many aspects of transfer reactions in the energy regime of interest. We exploit the fact that associated with the low-energy backscattered projectile-like fragment is a complementary target-like fragment which recoils to forward angles with a large fraction of the incident beam energy. These target-like fragments were detected and identified using the Daresbury Recoil Mass Separator thus allowing the measurement of quasi-elastic transfer over hitherto inaccessible energy range from the vicinity of the barrier to several tens of MeV below. The experiments described here used VYNi beams of energies ranging from 180 to 260 MeV provided by the Daresbury Laboratory Nuclear Structure Facility tandem accelerator. Data on sub-barrier transfer for targets of /sup 116,118,120,122,124/Sn and /sup 144,148,150,152,154/Sm were obtained. 16 refs., 10 figs., 2 tabs.

  8. A Study of Nuclear Recoils in Liquid Argon Time Projection Chamber for the Direct Detection of WIMP Dark Matter

    SciTech Connect

    Cao, Huajie

    2014-11-01

    Robust results of WIMP direct detection experiments depend on rm understandings of nuclear recoils in the detector media. This thesis documents the most comprehensive study to date on nuclear recoils in liquid argon - a strong candidate for the next generation multi-ton scale WIMP detectors. This study investigates both the energy partition from nuclear recoil energy to secondary modes (scintillation and ionization) and the pulse shape characteristics of scintillation from nuclear recoils.

  9. Nitrogen-doped 3D macroporous graphene frameworks as anode for high performance lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Liu, Xiaowu; Wu, Ying; Yang, Zhenzhong; Pan, Fusen; Zhong, Xiongwu; Wang, Jiaqing; Gu, Lin; Yu, Yan

    2015-10-01

    Nitrogen-doped 3D graphene frameworks (N-3D GFs) were synthesized by a facile two-step method: Polystyrene (PS) encapsulated in graphene oxide (GO) composites (denoted as PS@GO) are first synthesized, followed by a post-thermal annealing in ammonia step to get N-doped 3D GFs. The resulting N-3D GFs inherit the advantages of graphene, which possesses high electrical conductivity and high specific surface area. Furthermore, the well-defined 3D interconnected structure can facilitate the access of the electrolyte to the electrode surface, thus shortening the diffusion length of both Li+/e-, keeping the overall electrode highly conductive and active in lithium storage. Simultaneously, the in-situ formation of pyridinic N and pyrrolic N in 3D GFs provide high electronic conductivity and structure stability for lithium storage. The designed N-3D GFs electrode delivers a high specific capacity of 1094 mAhg-1 after 100 cycles at 200 mAg-1 and superior rate capability (691 mAhg-1 after 500 cycles at 1000 mAg-1) when used as anode for LIBs. We believe that such an inherently inexpensive, scalable, facile method can significantly increase the feasibility of building high performance energy storage system.

  10. Effect of nitrogen ion implantation on corrosion inhibition of nickel coated 316 stainless steel and correlation with nano-structure

    NASA Astrophysics Data System (ADS)

    Grayeli-Korpi, Ali-Reza; Savaloni, Hadi

    2012-10-01

    The influence of implantation of N+ with 20 keV energy and different fluences in the range of 1 × 1017 and 5 × 1018 ions/cm2 in the nickel coated type 316 stainless steel (SS) on the corrosion inhibition of SS in 3.5 wt% NaCl solution is investigated. The highest available N+ fluence showed highest corrosion inhibition. X-ray diffraction (XRD) analysis showed formation of nickel nitride phases that enhanced by increasing the N+ fluence. Surface morphology was studied by atomic force microscope (AFM) and scanning electron microscope (SEM) before and after corrosion test, respectively. AFM results showed that by increasing N+ fluence surface of the sample becomes smoother that may be the result of heat accumulation during implantation causing higher rate of diffusion in the sample.

  11. Current-induced giant polarization rotation using a ZnO single crystal doped with nitrogen ions

    PubMed Central

    Tate, Naoya; Kawazoe, Tadashi; Nomura, Wataru; Ohtsu, Motoichi

    2015-01-01

    Giant polarization rotation in a ZnO single crystal was experimentally demonstrated based on a novel phenomenon occurring at the nanometric scale. The ZnO crystal was doped with N+ and N2+ ions serving as p-type dopants. By applying an in-plane current using a unique arrangement of electrodes on the device, current-induced polarization rotation of the incident light was observed. From the results of experimental demonstrations and discussions, it was verified that this novel behavior originates from a specific distribution of dopants and the corresponding light–matter interactions in a nanometric space, which are allowed by the existence of such a dopant distribution. PMID:26246456

  12. Atomic data and spectral analysis of carbon, nitrogen, oxygen and silicon ions observed with the International Ultraviolet Explorer

    NASA Technical Reports Server (NTRS)

    Pradhan, Anil K.

    1992-01-01

    According to the plan presented in the original proposal we have now completed most of the atomic calculations involving collision strengths and rate coefficients for electron impact excitation of C II, N III, and O IV ions. These have been reported in the first two publications appended with this report. We have now moved into the applications phase of the project with the new data being used to analyze the International Ultraviolet Explorer (IUE) observations of a variety of objects, as described in the third publication recently submitted (also appended). The analysis and interpretation of archival data will continue well into the next year with several collaborators that the PI and Co-PI are involved with. In addition, the atomic calculations on Si II have been started.

  13. Comparative study of comprehensive gas chromatography-nitrogen chemiluminescence detection and gas chromatography-ion trap-tandem mass spectrometry for determining nicotine and carcinogen organic nitrogen compounds in thirdhand tobacco smoke.

    PubMed

    Ramírez, Noelia; Vallecillos, Laura; Lewis, Alastair C; Borrull, Francesc; Marcé, Rosa M; Hamilton, Jacqueline F

    2015-12-24

    Thirdhand tobacco smoke (THS) constitutes a poorly understood pathway of exposure of non-smokers, especially toddlers, to tobacco-related carcinogens. However, to date most of the carcinogens present in tobacco smoke have not been detected in THS and, therefore, the significance of THS health risk is still unknown. In this study, we have compared the performance of two analytical methods - one based on gas chromatography coupled to ion trap mass spectrometry detection (GC-IT-MS) and the other on comprehensive two-dimensional gas chromatography coupled to a nitrogen chemiluminescence detector (GC×GC-NCD) - for simultaneously determining, in settled house dust, the presence of 16 organic nitrogen carcinogens already detected in tobacco smoke. The target compounds included four aromatic amines, two nitrocompounds, eight N-nitrosamines and two tobacco-specific nitrosamines, as well as nicotine as a tobacco marker. Dust samples were extracted using in-cell clean up pressurized liquid extraction with silica as clean up sorbent and ethyl acetate as the organic solvent, with average recovery of 89%. Although GC-IT-MS, using chemical ionization with methanol and tandem MS, performed well, the optimized GC×GC-NCD gave lower limits of detection (from 4 to 22ngg(-1)) and better repeatability and reproducibility a low concentration levels (%RSD<8%) and, therefore, was applicable for determining these different groups of carcinogens without the need for derivatization prior to the GC analysis. The performance of the optimized PLE/GC×GC-NCD method was tested by quantifying the target compounds in house dust samples from smokers' and non-smokers' homes. The median carcinogen compounds detected was 3.8μgg(-1) and 1.1μgg(-1) in smokers' and non-smokers' house dust, respectively. In this study, we have detected highly carcinogenic aromatic amines and nitro compounds for the first time in settled house dust complementing the state of knowledge of THS composition and providing

  14. Comparative study of comprehensive gas chromatography-nitrogen chemiluminescence detection and gas chromatography-ion trap-tandem mass spectrometry for determining nicotine and carcinogen organic nitrogen compounds in thirdhand tobacco smoke.

    PubMed

    Ramírez, Noelia; Vallecillos, Laura; Lewis, Alastair C; Borrull, Francesc; Marcé, Rosa M; Hamilton, Jacqueline F

    2015-12-24

    Thirdhand tobacco smoke (THS) constitutes a poorly understood pathway of exposure of non-smokers, especially toddlers, to tobacco-related carcinogens. However, to date most of the carcinogens present in tobacco smoke have not been detected in THS and, therefore, the significance of THS health risk is still unknown. In this study, we have compared the performance of two analytical methods - one based on gas chromatography coupled to ion trap mass spectrometry detection (GC-IT-MS) and the other on comprehensive two-dimensional gas chromatography coupled to a nitrogen chemiluminescence detector (GC×GC-NCD) - for simultaneously determining, in settled house dust, the presence of 16 organic nitrogen carcinogens already detected in tobacco smoke. The target compounds included four aromatic amines, two nitrocompounds, eight N-nitrosamines and two tobacco-specific nitrosamines, as well as nicotine as a tobacco marker. Dust samples were extracted using in-cell clean up pressurized liquid extraction with silica as clean up sorbent and ethyl acetate as the organic solvent, with average recovery of 89%. Although GC-IT-MS, using chemical ionization with methanol and tandem MS, performed well, the optimized GC×GC-NCD gave lower limits of detection (from 4 to 22ngg(-1)) and better repeatability and reproducibility a low concentration levels (%RSD<8%) and, therefore, was applicable for determining these different groups of carcinogens without the need for derivatization prior to the GC analysis. The performance of the optimized PLE/GC×GC-NCD method was tested by quantifying the target compounds in house dust samples from smokers' and non-smokers' homes. The median carcinogen compounds detected was 3.8μgg(-1) and 1.1μgg(-1) in smokers' and non-smokers' house dust, respectively. In this study, we have detected highly carcinogenic aromatic amines and nitro compounds for the first time in settled house dust complementing the state of knowledge of THS composition and providing

  15. Single photon simultaneous K-shell ionization and K-shell excitation. II. Specificities of hollow nitrogen molecular ions

    SciTech Connect

    Carniato, S. Selles, P.; Andric, L.; Palaudoux, J.; Penent, F.; Lablanquie, P.; Žitnik, M.; Bučar, K.; Nakano, M.; Hikosaka, Y.; Ito, K.

    2015-01-07

    The formalism developed in the companion Paper I is used here for the interpretation of spectra obtained recently on the nitrogen molecule. Double core-hole ionization K{sup −2} and core ionization-core excitation K{sup −2}V processes have been observed by coincidence electron spectroscopy after ionization by synchrotron radiation at different photon energies. Theoretical and experimental cross sections reported on an absolute scale are in satisfactory agreement. The evolution with photon energy of the relative contribution of shake-up and conjugate shake-up processes is discussed. The first main resonance in the K{sup −2}V spectrum is assigned to a K{sup −2}π{sup ∗} state mainly populated by the 1s→ lowest unoccupied molecular orbital dipolar excitation, as it is in the K{sup −1}V NEXAFS (Near-Edge X-ray Absorption Fine Structure) signals. Closer to the K{sup −2} threshold Rydberg resonances have been also identified, and among them a K{sup −2}σ{sup ∗} resonance characterized by a large amount of 2s/2p hybridization, and double K{sup −2}(2σ{sup ∗}/1π/3σ){sup −1}1π{sup ∗2} shake-up states. These resonances correspond in NEXAFS spectra to, respectively, the well-known σ{sup ∗} shape resonance and double excitation K{sup −1}(2σ{sup ∗}/1π/3σ){sup −1}1π{sup ∗2} resonances, all being positioned above the threshold.

  16. Properties of cold ions produced by synchrotron radiation and by charged particle impact

    NASA Astrophysics Data System (ADS)

    Levin, J. C.; Biedermann, C.; Cederquist, H.; O, C.-S.; Short, R. T.; Sellin, I. A.

    1989-04-01

    Argon recoil ions produced by beams of 0.8 MeV/u Cl 5+ have been detected by time-of-flight (TOF) techniques in coincidence with the loss of from one to five projectile electrons. Recoil-ion energies have been determined to be more than an order of magnitude higher than those of highly charged ions produced by unmonochromatized synchrotron radiation. Charge-state distributions, however, show similarities, suggesting that loss of projectile electrons corresponds, in some cases, to inner-shell target ionization producing vacancy cascades. In an essential improvement to the usual multinomial description of ionization in the independent-electron-ejection model, we find the inclusion of Auger vacancy cascades significantly alters the description of the recoil ion spectra corresponding to the projectile-electron loss. These conclusions are consistent with impact parameters inferred from determination of mean recoil energy.

  17. A Novel method for modeling the recoil in W boson events at hadron collider

    SciTech Connect

    Abazov, Victor Mukhamedovich; Abbott, Braden Keim; Abolins, Maris A.; Acharya, Bannanje Sripath; Adams, Mark Raymond; Adams, Todd; Aguilo, Ernest; Ahsan, Mahsana; Alexeev, Guennadi D.; Alkhazov, Georgiy D.; Alton, Andrew K.; /Michigan U. /Augustana Coll., Sioux Falls /Northeastern U.

    2009-07-01

    We present a new method for modeling the hadronic recoil in W {yields} {ell}{nu} events produced at hadron colliders. The recoil is chosen from a library of recoils in Z {yields} {ell}{ell} data events and overlaid on a simulated W {yields} {ell}{nu} event. Implementation of this method requires that the data recoil library describe the properties of the measured recoil as a function of the true, rather than the measured, transverse momentum of the boson. We address this issue using a multidimensional Bayesian unfolding technique. We estimate the statistical and systematic uncertainties from this method for the W boson mass and width measurements assuming 1 fb{sup -1} of data from the Fermilab Tevatron. The uncertainties are found to be small and comparable to those of a more traditional parameterized recoil model. For the high precision measurements that will be possible with data from Run II of the Fermilab Tevatron and from the CERN LHC, the method presented in this paper may be advantageous, since it does not require an understanding of the measured recoil from first principles.

  18. Enhancement of surface properties of SAE 1020 by chromium plasma immersion recoil implantation

    NASA Astrophysics Data System (ADS)

    Ueda, M.; Mello, C. B.; Beloto, A. F.; Rossi, J. O.; Reuther, H.

    2007-04-01

    SAE 1020 steel is commonly used as concrete reinforcement and small machine parts, but despite its good mechanical properties, as ductility, hardness and wear resistance, it is susceptible to severe corrosion. It is well known that chromium content above 12% in Fe alloys increases their corrosion resistance. In order to obtain this improvement, we studied the introduction of chromium atoms into the matrix of SAE 1020 steel by recoil implantation process using a plasma immersion ion implantation (PIII) system. Potentiodynamic scans showed that the presence of Cr film leads to a gain in the corrosion potential, from -650 mV to -400 mV. After PIII treatment, the corrosion potential increased further to -340 mV, but the corrosion current density presented no significant change. Vickers microhardness tests showed surface hardness increase of up to about 27% for the treated samples. Auger electron spectroscopy showed that, for a 30 nm film, Cr was introduced for about 20 nm into the steel matrix. Tribology tests, of pin-on-disk type, showed that friction coefficient of treated samples was reduced by about 50% and a change in wear mechanism, from adhesive to abrasive mode, occurred.

  19. Hydrogen uptake in Zircaloy-2 reactor fuel claddings studied with elastic recoil detection

    NASA Astrophysics Data System (ADS)

    Rajasekhara, S.; Doyle, B. L.; Enos, D. G.; Clark, B. G.

    2013-04-01

    The recent trend towards a high burn-up discharge spent nuclear fuel necessitates a thorough understanding of hydrogen uptake in Zr-based cladding materials that encapsulate spent nuclear fuel. Although it is challenging to experimentally replicate exact conditions in a nuclear reactor that lead to hydrogen uptake in claddings, in this study we have attempted to understand the kinetics of hydrogen uptake by first electrolytically charging Zircaloy-2 (Zr-2) cladding material for various durations (100 to 2,600 s), and subsequently examining hydrogen ingress with elastic recoil detection (ERD) and transmission electron microscopy (TEM). To understand the influence of irradiation damage defects on hydrogen uptake, an analogous study was performed on ion - irradiated (0.1, 1 and 25 dpa) Zr-2. Analysis of ERD data from the un-irradiated Zr-2 suggests that the growth of the hydride layer is diffusion controlled, and preliminary TEM results support this assertion. In un-irradiated Zr-2, the diffusivity of hydrogen in the hydride phase was found to be approximately 1.1 × 10-11 cm2/s, while the diffusivity in the hydride phase for lightly irradiated (0.1 and 1 dpa) Zr-2 is an order of magnitude lower. Irradiation to 25 dpa results in a hydrogen diffusivity that is comparable to the un-irradiated Zr-2. These results are compared with existing literature on hydrogen transport in Zr - based materials.

  20. Production of 14 MeV neutrons by heavy ions

    DOEpatents

    Brugger, Robert M.; Miller, Lowell G.; Young, Robert C.

    1977-01-01

    This invention relates to a neutron generator and a method for the production of 14 MeV neutrons. Heavy ions are accelerated to impinge upon a target mixture of deuterium and tritium to produce recoil atoms of deuterium and tritium. These recoil atoms have a sufficient energy such that they interact with other atoms of tritium or deuterium in the target mixture to produce approximately 14 MeV neutrons.

  1. Effect of ferric ion on nitrogen consumption, biomass and oil accumulation of a Scenedesmus rubescens-like microalga.

    PubMed

    Lin, Qiang; Gu, Na; Lin, Junda

    2012-05-01

    This investigation examined the effects of ferric ion source and concentration on the biomass yield, fatty acid methyl esters (FAME) productivity and composition from Scenedesmus rubescens-like microalga. The algae cultivated with Fe(2+)-SO(4)(2-)/EDTA had higher ash free dry biomass (AFDB) production and in vivo chlorophyll a concentration than those with Fe(2+)-SO(4)(2-) and Fe(3+)-Cl(-) (P<0.001). The high or low Fe(2+) concentration can partly restrict the ammonia consumption, the AFDB and FAME accumulation. The algae at 1mg/L Fe(2+) concentration had the highest AFDB and FAME productivity (341.1 ± 25.8 and 107.8 ± 19.3mg/L/d) (P<0.001). The mean content of C16 and C18 series at all Fe(2+) concentrations was 88.6% ± 2.9% of total FAME, and it decreased with the increase of Fe(2+) concentrations. Among the fatty acids profiles, the contents of C18: 0, C18: 1n-7 and C18: 1n-9 are significantly changed under the different Fe(2+) concentrations, but not the contents of C16 series.

  2. Spreading and recoil of a surfactant-containing water drop on glass-supported alcohol films.

    PubMed

    Chowdhury, Devasish; Sarkar, Surya Protim; Kalita, Dipankar; Sarma, Tridib Kumar; Paul, Anumita; Chattopadhyay, Arun

    2004-02-17

    In this paper we report the experimental observation of spreading and recoil of surfactant-containing water drops on various alcohol films supported on glass slides. The time evolution of spreading and recoil behavior was recorded by placing a web camera above the drop. We observed that the drop spread the fastest on CH3OH, followed by C2H5OH, and the slowest on i-PrOH. On the other hand, the recoil behavior was just the opposite. The drop recoiled the slowest on CH3OH and fastest on i-PrOH, while it recoiled in an intermediate time on C2H5OH. In addition, concentration of surfactant in the drop played a prominent role in the spreading and recoil time of the drop, with higher surfactant concentration making the drop spread and recoil faster. The time evolution of spreading velocity of the drop on different alcohol films at various surfactant concentrations occurred with a Gaussian distribution and the peak velocity was reached earliest on CH3OH followed by C2H5OH, while on i-PrOH it took the longest time. The recoil behavior was similar. The variation of velocity as a function of radius exhibited oscillatory behavior, indicating the existence of an interfacial phenomenon. We also report the observation that spreading of the drop occurred without observable fingering instability. Further, we observed by Fourier transform infrared (FTIR) spectroscopic measurements that the drop had mixed with the alcohol films as it spread. Miscibility of the alcohol in the film with the drop, alcohol evaporation cooling-induced temperature gradient, and Marangoni effect probably play important roles in the spreading and recoil behavior of the drop.

  3. Eco-friendly nitrogen-containing carbon encapsulated LiMn2O4 cathodes to enhance the electrochemical properties in rechargeable Li-ion batteries.

    PubMed

    Ilango, P Robert; Prasanna, K; Do, Su Jung; Jo, Yong Nam; Lee, Chang Woo

    2016-01-01

    This study describes the synthesis of nitrogen-containing carbon (N-C) and an approach to apply the N-C material as a surface encapsulant of LiMn2O4 (LMO) cathode material. The N heteroatoms in the N-C material improve the electrochemical performance of LMO. A low-cost wet coating method was used to prepare N-C@LMO particles. The N-C@LMO was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), high-resolution Raman spectroscopy (HR-Raman), field emission scanning electron microscopy (FE-SEM), and field emission scanning transmission electron microscopy (FE-TEM) with elemental mapping. Furthermore, the prepared samples were electrochemically studied using the AC electrochemical impedance spectroscopy (EIS) and the electrochemical cycler. XPS suggested that the N-C coating greatly reduced the dissolution of Mn and EIS showed that the coating greatly suppressed the charge transfer resistance, even after long-term cycling. The control of Mn dissolution and inner resistance allowed faster Li-ion transport between the two electrodes resulting in improved discharge capacity and cycling stability. PMID:27406049

  4. B and N isolate-doped graphitic carbon nanosheets from nitrogen-containing ion-exchanged resins for enhanced oxygen reduction

    NASA Astrophysics Data System (ADS)

    Wang, Lei; Yu, Peng; Zhao, Lu; Tian, Chungui; Zhao, Dongdong; Zhou, Wei; Yin, Jie; Wang, Ruihong; Fu, Honggang

    2014-06-01

    B,N-codoped carbon nanostructures (BNCS) can serve as alternative low-cost metal-free electrocatalysts for oxygen reduction reactions (ORR). However, the compensation effect between the p- (B atoms) and n-type (N atoms) dopants would make the covalent boron-nitride (BN) easily formed during the synthesis of BNCS, leading to a unsatisfactory ORR activity. Therefore, it has been challenging to develop facile and rapid synthetic strategies for highly active BNCS without forming the direct covalent BN. Here, a facile method is developed to prepare B and N isolate-doped graphitic nanosheets (BNGS) by using iron species for saving N element and simultaneous doping the B element from nitrogen-containing ion-exchanged resins (NR). The resulting BNGS exhibits much more onset potential (Eonset) compared with the B-doped graphitic carbon nanosheets (BGS), N-doped graphitic carbon nanosheets (NGS), as well as B,N-codoped disorder carbon (BNC). Moreover, the BNGS shows well methanol tolerance propery and excellent stability (a minimal loss of activity after 5,000 potential cycles) compared to that of commercial Pt/C catalyst. The goog performance for BNGS towards ORR is attributed to the synergistic effect between B and N, and the well electrons transport property of graphitic carbon in BNGS.

  5. Changes in polyamines, inorganic ions and glutamine synthetase activity in response to nitrogen availability and form in red spruce (Picea rubens).

    PubMed

    Serapiglia, Michelle J; Minocha, Rakesh; Minocha, Subhash C

    2008-12-01

    We analyzed effects of nitrogen availability and form on growth rates, concentrations of polyamines and inorganic ions and glutamine synthetase activity in in-vitro-cultured red spruce (Picea rubens Sarg.) cells. Growth rates, concentrations of polyamines and glutamine synthetase activity declined when either the amount of nitrate or the total amount of N in the culture medium was reduced. When total N in the medium was increased, cell mass increased without significant changes in glutamine synthetase activity or polyamine concentration. Reductions in the amount of nitrate or total N in the culture medium resulted in increased accumulations of Ca, Mn and Zn in the cells, and K accumulation decreased in response to decreasing nitrate:ammonium ratios. The data indicate that changes in total N availability as well as the forms of N play important roles in the physiological responses of in-vitro-grown red spruce cells that mimic the observed responses of forest trees to soil N deficiency and N fertilization.

  6. Eco-friendly nitrogen-containing carbon encapsulated LiMn2O4 cathodes to enhance the electrochemical properties in rechargeable Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Ilango, P. Robert; Prasanna, K.; Do, Su Jung; Jo, Yong Nam; Lee, Chang Woo

    2016-07-01

    This study describes the synthesis of nitrogen-containing carbon (N-C) and an approach to apply the N-C material as a surface encapsulant of LiMn2O4 (LMO) cathode material. The N heteroatoms in the N-C material improve the electrochemical performance of LMO. A low-cost wet coating method was used to prepare N-C@LMO particles. The N-C@LMO was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), high-resolution Raman spectroscopy (HR-Raman), field emission scanning electron microscopy (FE-SEM), and field emission scanning transmission electron microscopy (FE-TEM) with elemental mapping. Furthermore, the prepared samples were electrochemically studied using the AC electrochemical impedance spectroscopy (EIS) and the electrochemical cycler. XPS suggested that the N-C coating greatly reduced the dissolution of Mn and EIS showed that the coating greatly suppressed the charge transfer resistance, even after long-term cycling. The control of Mn dissolution and inner resistance allowed faster Li-ion transport between the two electrodes resulting in improved discharge capacity and cycling stability.

  7. Eco-friendly nitrogen-containing carbon encapsulated LiMn2O4 cathodes to enhance the electrochemical properties in rechargeable Li-ion batteries

    PubMed Central

    Ilango, P. Robert; Prasanna, K.; Do, Su Jung; Jo, Yong Nam; Lee, Chang Woo

    2016-01-01

    This study describes the synthesis of nitrogen-containing carbon (N-C) and an approach to apply the N-C material as a surface encapsulant of LiMn2O4 (LMO) cathode material. The N heteroatoms in the N-C material improve the electrochemical performance of LMO. A low-cost wet coating method was used to prepare N-C@LMO particles. The N-C@LMO was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), high-resolution Raman spectroscopy (HR-Raman), field emission scanning electron microscopy (FE-SEM), and field emission scanning transmission electron microscopy (FE-TEM) with elemental mapping. Furthermore, the prepared samples were electrochemically studied using the AC electrochemical impedance spectroscopy (EIS) and the electrochemical cycler. XPS suggested that the N-C coating greatly reduced the dissolution of Mn and EIS showed that the coating greatly suppressed the charge transfer resistance, even after long-term cycling. The control of Mn dissolution and inner resistance allowed faster Li-ion transport between the two electrodes resulting in improved discharge capacity and cycling stability. PMID:27406049

  8. B and N isolate-doped graphitic carbon nanosheets from nitrogen-containing ion-exchanged resins for enhanced oxygen reduction

    PubMed Central

    Wang, Lei; Yu, Peng; Zhao, Lu; Tian, Chungui; Zhao, Dongdong; Zhou, Wei; Yin, Jie; Wang, Ruihong; Fu, Honggang

    2014-01-01

    B,N-codoped carbon nanostructures (BNCS) can serve as alternative low-cost metal-free electrocatalysts for oxygen reduction reactions (ORR). However, the compensation effect between the p- (B atoms) and n-type (N atoms) dopants would make the covalent boron-nitride (BN) easily formed during the synthesis of BNCS, leading to a unsatisfactory ORR activity. Therefore, it has been challenging to develop facile and rapid synthetic strategies for highly active BNCS without forming the direct covalent BN. Here, a facile method is developed to prepare B and N isolate-doped graphitic nanosheets (BNGS) by using iron species for saving N element and simultaneous doping the B element from nitrogen-containing ion-exchanged resins (NR). The resulting BNGS exhibits much more onset potential (Eonset) compared with the B-doped graphitic carbon nanosheets (BGS), N-doped graphitic carbon nanosheets (NGS), as well as B,N-codoped disorder carbon (BNC). Moreover, the BNGS shows well methanol tolerance propery and excellent stability (a minimal loss of activity after 5,000 potential cycles) compared to that of commercial Pt/C catalyst. The goog performance for BNGS towards ORR is attributed to the synergistic effect between B and N, and the well electrons transport property of graphitic carbon in BNGS. PMID:24898033

  9. Phosphorus and nitrogen dual-doped few-layered porous graphene: a high-performance anode material for lithium-ion batteries.

    PubMed

    Ma, Xinlong; Ning, Guoqing; Qi, Chuanlei; Xu, Chenggen; Gao, Jinsen

    2014-08-27

    Few-layered graphene networks composed of phosphorus and nitrogen dual-doped porous graphene (PNG) are synthesized via a MgO-templated chemical vapor deposition (CVD) using (NH4)3PO4 as N and P source. P and N atoms have been substitutionally doped in graphene networks since the doping takes place at the same time with the graphene growth in the CVD process. Raman spectra show that the amount of defects or disorders increases after P and N atoms are incorporated into graphene frameworks. The doping levels of P and N measured by X-ray photoelectron spectroscopy are 0.6 and 2.6 at %, respectively. As anodes for Li ion batteries (LIBs), the PNG electrode exhibits high reversible capacity (2250 mA h g(-1) at the current density of 50 mA g(-1)), excellent rate capability (750 mA h g(-1) at 1000 mA g(-1)), and satisfactory cycling stability (no capacity decay after 1500 cycles), showing much enhanced electrode performance as compared to the undoped few-layered porous graphene. Our results show that the PNG is a promising candidate for anode materials in high-rate LIBs.

  10. Hybrid of porous cobalt oxide nanospheres and nitrogen-doped graphene for applications in lithium-ion batteries and oxygen reduction reaction

    NASA Astrophysics Data System (ADS)

    Zhang, Mengmeng; Li, Rong; Chang, Xiaoxuan; Xue, Chao; Gou, Xinglong

    2015-09-01

    A new single-source precursor has been developed from the hydrothermal reaction of graphite oxide (GO), melamine resin (MR) monomers, and CoCl2 to prepare a sandwich-like hybrid of ultrathin nitrogen-doped graphene (NG) sheets and porous Co3O4 nanospheres (Co3O4/NG). This unique structure endows the Co3O4/NG hybrid with large surface area and enhanced electrochemical performances as both anode material for Li-ion batteries and electrocatalyst for oxygen reduction reaction (ORR). As an anode material, it exhibits high reversible capacity, excellent cycling stability and rate performance (1236 and 489 mAh g-1 over 200 cycles at 0.1C and 2C, respectively; 371 mAh g-1 at 5C). As an ORR electrocatalyst, it shows superior catalytic activity and high selectivity for the four-electron reduction pathway compared to the bare Co3O4 and NG alone. Moreover, the Co3O4/NG hybrid is insensitive to methanol, and is much more stable than Pt/C catalyst over long term operation.

  11. Retention studies of recoiling daughter nuclides of 225Ac in polymer vesicles.

    PubMed

    Wang, G; de Kruijff, R M; Rol, A; Thijssen, L; Mendes, E; Morgenstern, A; Bruchertseifer, F; Stuart, M C A; Wolterbeek, H T; Denkova, A G

    2014-02-01

    Alpha radionuclide therapy is steadily gaining importance and a large number of pre-clinical and clinical studies have been carried out. However, due to the recoil effects the daughter recoil atoms, most of which are alpha emitters as well, receive energies that are much higher than the energies of chemical bonds resulting in decoupling of the radionuclide from common targeting agents. Here, we demonstrate that polymer vesicles (i.e. polymersomes) can retain recoiling daughter nuclei based on an experimental study examining the retention of (221)Fr and (213)Bi when encapsulating (225)Ac. PMID:24374072

  12. Retention studies of recoiling daughter nuclides of 225Ac in polymer vesicles.

    PubMed

    Wang, G; de Kruijff, R M; Rol, A; Thijssen, L; Mendes, E; Morgenstern, A; Bruchertseifer, F; Stuart, M C A; Wolterbeek, H T; Denkova, A G

    2014-02-01

    Alpha radionuclide therapy is steadily gaining importance and a large number of pre-clinical and clinical studies have been carried out. However, due to the recoil effects the daughter recoil atoms, most of which are alpha emitters as well, receive energies that are much higher than the energies of chemical bonds resulting in decoupling of the radionuclide from common targeting agents. Here, we demonstrate that polymer vesicles (i.e. polymersomes) can retain recoiling daughter nuclei based on an experimental study examining the retention of (221)Fr and (213)Bi when encapsulating (225)Ac.

  13. Nuclear recoil energy scale in liquid xenon with application to the direct detection of dark matter

    NASA Astrophysics Data System (ADS)

    Sorensen, Peter; Dahl, Carl Eric

    2011-03-01

    We show for the first time that the quenching of electronic excitation from nuclear recoils in liquid xenon is well-described by Lindhard theory, if the nuclear recoil energy is reconstructed using the combined (scintillation and ionization) energy scale proposed by Shutt et al. We argue for the adoption of this perspective in favor of the existing preference for reconstructing nuclear recoil energy solely from primary scintillation. We show that signal partitioning into scintillation and ionization is well described by the Thomas-Imel box model. We discuss the implications for liquid xenon detectors aimed at the direct detection of dark matter.

  14. Nuclear recoil energy scale in liquid xenon with application to the direct detection of dark matter

    SciTech Connect

    Sorensen, P; Dahl, C E

    2011-02-14

    We show for the first time that the quenching of electronic excitation from nuclear recoils in liquid xenon is well-described by Lindhard theory, if the nuclear recoil energy is reconstructed using the combined (scintillation and ionization) energy scale proposed by Shutt et al.. We argue for the adoption of this perspective in favor of the existing preference for reconstructing nuclear recoil energy solely from primary scintillation. We show that signal partitioning into scintillation and ionization is well-described by the Thomas-Imel box model. We discuss the implications for liquid xenon detectors aimed at the direct detection of dark matter.

  15. Improved electrochemical performance of nitrogen doped TiO2-B nanowires as anode materials for Li-ion batteries.

    PubMed

    Zhang, Yongquan; Fu, Qiang; Xu, Qiaoling; Yan, Xiao; Zhang, Rongyu; Guo, Zhendong; Du, Fei; Wei, Yingjin; Zhang, Dong; Chen, Gang

    2015-07-28

    N-doped TiO2-B nanowires are prepared by the solvothermal method using TiN nanoparticles as the starting material. X-ray photoelectron spectroscopy shows that the N dopants preferentially occupy the interstitial sites of TiO2-B up to a content of ∼0.55 at%. Above this critical value, the N dopants will substitute the oxygen atoms which improve the electronic conductivity of TiO2-B. The maximum proportion of substituted-N in the TiO2-B nanowires is ∼1.3 at%. Raman scattering shows that the substituted-N strengthens the Ti(1)-O1-Ti(2) and O1-Ti(1)-O3 bonds of TiO2-B. This improves the stability of the corresponding local structures, thus reducing the distortion of the Li(+) diffusion channel along the b-axis of TiO2-B. As a result, the substituted-N has more of an impact on the electrochemical properties of TiO2-B than the interstitial-N does. The TiO2-B nanowires containing substituted-N dopants exhibit a remarkably enhanced electrochemical performance compared to pure TiO2-B. They show a discharge capacity of 153 mA h g(-1) at the 20 C rate with a capacity retention of 76% after 1000 cycles. In addition, they can deliver a discharge capacity of 100 mA h g(-1) at an ultra-high rate of 100 C, indicating their great potential in high power lithium ion batteries.

  16. Enhancement in the photocatalytic nature of nitrogen-doped PVD-grown titanium dioxide thin films

    SciTech Connect

    Tavares, C. J.; Marques, S. M.; Viseu, T.; Teixeira, V.; Carneiro, J. O.; Alves, E.; Barradas, N. P.; Munnik, F.; Girardeau, T.; Riviere, J.-P.

    2009-12-01

    Nitrogen-doped titanium dioxide semiconductor photocatalytic thin films have been deposited by unbalanced reactive magnetron physical vapor deposition on glass substrates for self-cleaning applications. In order to increase the photocatalytic efficiency of the titania coatings, it is important to enhance the catalysts absorption of light from the solar spectra. Bearing this fact in mind, a reduction in the titania semiconductor band-gap has been attempted by using nitrogen doping from a coreactive gas mixture of N{sub 2}:O{sub 2} during the titanium sputtering process. Rutherford backscattering spectroscopy was used in order to assess the composition of the titania thin films, whereas heavy-ion elastic recoil detection analysis granted the evaluation of the doping level of nitrogen. X-ray photoelectron spectroscopy provided valuable information about the cation-anion binding within the semiconductor lattice. The as-deposited thin films were mostly amorphous, however, after a thermal annealing in vacuum at 500 deg. C the crystalline polymorph anatase and rutile phases have been developed, yielding an enhancement in the crystallinity. Spectroscopic ellipsometry experiments enabled the determination the refractive index of the thin films as a function of the wavelength, while from the optical transmittance it was possible to estimate the semiconductor indirect band-gap of these coatings, which has been proven to decrease as the N-doping increases. The photocatalytic performance of the titania films has been characterized by the degradation rate of an organic reactive dye under UV/visible irradiation. It has been found that for a certain critical limit of 1.19 at. % of nitrogen doping in the titania anatase crystalline lattice enhances the photocatalytic behavior of the thin films and it is in accordance with the observed semiconductor band-gap narrowing to 3.18 eV. By doping the titania lattice with nitrogen, the photocatalytic activity is enhanced under both UV and

  17. The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF)

    DOE PAGESBeta

    Frenje, J. A.; Hilsabeck, T. J.; Wink, C. W.; Bell, P.; Bionta, R.; Cerjan, C.; Gatu Johnson, M.; Kilkenny, J. D.; Li, C. K.; Séguin, F. H.; et al

    2016-08-02

    The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (Ti), yield (Yn), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate data with amore » time resolution of ~20 ps and energy resolution of ~100 keV for total neutron yields above ~1016. Lastly, at lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ~20 ps.« less

  18. Measuring the absolute deuterium-tritium neutron yield using the magnetic recoil spectrometer at OMEGA and the NIF.

    PubMed

    Casey, D T; Frenje, J A; Gatu Johnson, M; Séguin, F H; Li, C K; Petrasso, R D; Glebov, V Yu; Katz, J; Knauer, J P; Meyerhofer, D D; Sangster, T C; Bionta, R M; Bleuel, D L; Döppner, T; Glenzer, S; Hartouni, E; Hatchett, S P; Le Pape, S; Ma, T; MacKinnon, A; McKernan, M A; Moran, M; Moses, E; Park, H-S; Ralph, J; Remington, B A; Smalyuk, V; Yeamans, C B; Kline, J; Kyrala, G; Chandler, G A; Leeper, R J; Ruiz, C L; Cooper, G W; Nelson, A J; Fletcher, K; Kilkenny, J; Farrell, M; Jasion, D; Paguio, R

    2012-10-01

    A magnetic recoil spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF.

  19. The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF)

    NASA Astrophysics Data System (ADS)

    Frenje, J. A.; Hilsabeck, T. J.; Wink, C. W.; Bell, P.; Bionta, R.; Cerjan, C.; Gatu Johnson, M.; Kilkenny, J. D.; Li, C. K.; Séguin, F. H.; Petrasso, R. D.

    2016-11-01

    The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (Ti), yield (Yn), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate data with a time resolution of ˜20 ps and energy resolution of ˜100 keV for total neutron yields above ˜1016. At lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ˜20 ps.

  20. Hyperfine structures and Landé g{sub J}-factors for n=2 states in beryllium-, boron-, carbon-, and nitrogen-like ions from relativistic configuration interaction calculations

    SciTech Connect

    Verdebout, S.; Nazé, C.; Rynkun, P.; Godefroid, M.

    2014-09-15

    Energy levels, hyperfine interaction constants, and Landé g{sub J}-factors are reported for n=2 states in beryllium-, boron-, carbon-, and nitrogen-like ions from relativistic configuration interaction calculations. Valence, core–valence, and core–core correlation effects are taken into account through single and double-excitations from multireference expansions to increasing sets of active orbitals. A systematic comparison of the calculated hyperfine interaction constants is made with values from the available literature.

  1. Fast thermometry for trapped atoms using recoil-induced resonance

    NASA Astrophysics Data System (ADS)

    Zhao, Yan-Ting; Su, Dian-Qiang; Ji, Zhong-Hua; Zhang, Hong-Shan; Xiao, Lian-Tuan; Jia, Suo-Tang

    2015-09-01

    We have employed recoil-induced resonance (RIR) with linewidth on the order of 10 kHz to demonstrate the fast thermometry for ultracold atoms. We theoretically calculate the absorption spectrum of RIR which agrees well with the experimental results. The temperature of the ultracold sample derived from the RIR spectrum is T = 84±4.5 μK, which is close to 85 μK that measured by the method of time-of-flight absorption imaging. To exhibit the fast measurement advantage in applying RIR to the ultracold atom thermometry, we study the dependence of ultracold sample temperature on the trapping beam frequency detuning. This method can be applied to determine the translational temperature of molecules in photoassociation dynamics. Project supported by the National Basic Research Development Program of China (Grant No. 2012CB921603), the National High Technology Research and Development Program of China (Grant No. 2011AA010801), the National Natural Science Foundation of China (Grant Nos. 61275209, 11304189, 61378015, and 11434007), and Program for Changjiang Scholars and Innovative Research Team in Universities of China (Grant No. IRT13076).

  2. First Measurement of Beam-Recoil Observables Cx and Cz

    SciTech Connect

    R. Bradford; R.A. Schumacher; G. Adams; M.J. Amaryan; P. Ambrozewicz; E. Anciant; M. Anghinolfi; B. Asavapibhop; G. Asryan; G. Audit; H. Avakian; H. Bagdasaryan; N. Baillie; J.P. Ball; N.A. Baltzell; S. Barrow; V. Batourine; M. Battaglieri; K. Beard; I. Bedlinskiy; M. Bektasoglu; M. Bellis; N. Benmouna; B.L. Berman; N. Bianchi; A.S. Biselli; B.E. Bonner; S. Bouchigny; S. Boiarinov; D. Branford; W.J. Briscoe; W.K. Brooks; S. B¨ultmann; V.D. Burkert; C. Butuceanu; J.R. Calarco; S.L. Careccia; D.S. Carman; B. Carnahan; S. Chen; P.L. Cole; A. Coleman; P. Collins; P. Coltharp; D. Cords; † P. Corvisiero; D. Crabb; H. Crannell; V. Crede; J.P. Cummings; R. De Masi; E. De Sanctis; R. De Vita; P.V. Degtyarenko; H. Denizli; L. Dennis; A. Deur; K.V. Dharmawardane; R. Dickson; C. Djalali; G.E. Dodge; J. Donnelly; D. Doughty; P. Dragovitsch; M. Dugger; S. Dytman; O.P. Dzyubak; H. Egiyan; K.S. Egiyan; L. El Fassi; L. Elouadrhiri; A. Empl; P. Eugenio; R. Fatemi; G. Fedotov; G. Feldman; R.J. Feuerbach; T.A. Forest; H. Funsten; M. Garcon; G. Gavalian; G.P. Gilfoyle; K.L. Giovanetti; F.X. Girod; J.T. Goetz; A. Gonenc; R.W. Gothe; K.A. Griffioen; M. Guidal; M. Guillo; N. Guler; L. Guo; V. Gyurjyan; C. Hadjidakis; K. Hafidi; H. Hakobyan; R.S. Hakobyan; J. Hardie; D. Heddle; F.W. Hersman; K. Hicks; I. Hleiqawi; M. Holtrop; J. Hu; M. Huertas; C.E. Hyde-Wright; Y. Ilieva; D.G. Ireland; B.S. Ishkhanov; E.L. Isupov; M.M. Ito; D. Jenkins; H.S. Jo; K. Joo; H.G. Juengst; N. Kalantarians; J.D. Kellie; M. Khandaker; K.Y. Kim; K. Kim; W. Kim; A. Klein; F.J. Klein; M. Klusman; M. Kossov; L.H. Kramer; V. Kubarovsky; J. Kuhn; S.E. Kuhn; S.V. Kuleshov; J. Lachniet; J.M. Laget; J. Langheinrich; D. Lawrence; A.C.S. Lima; K. Livingston; H.Y. Lu; K. Lukashin; M. MacCormick; J.J. Manak; C. Marchand; N. Markov; S. McAleer; B. McKinnon; J.W.C. McNabb; B.A. Mecking; M.D. Mestayer; C.A. Meyer; T. Mibe; K. Mikhailov; M. Mirazita; R. Miskimen; V. Mokeev; K. Moriya; S.A. Morrow; M. Moteabbed; V. Muccifora; J. Mueller; G.S. Mutchler; P. Nadel-Turonski; J. Napolitano; R. Nasseripour; N. Natasha; S. Niccolai; G. Niculescu; I. Niculescu; B.B. Niczyporuk; M.R. Niroula; R.A. Niyazov; M. Nozar; G.V. O’Rielly; M. Osipenko; A.I. Ostrovidov; K. Park; E. Pasyuk; C. Paterson; S.A. Philips; J. Pierce; N. Pivnyuk; D. Pocanic; O. Pogorelko; E. Polli; I. Popa; S. Pozdniakov; B.M. Preedom; J.W. Price; Y. Prok; D. Protopopescu; L.M. Qin; B.P. Quinn; B.A. Raue; G. Riccardi; G. Ricco; M. Ripani; B.G. Ritchie; F. Ronchetti; G. Rosner; P. Rossi; D. Rowntree; P.D. Rubin; F. Sabatie; J. Salamanca; C. Salgado; J.P. Santoro; V. Sapunenko; V.S. Serov; A. Shafi; Y.G. Sharabian; J. Shaw; N.V. Shvedunov; S. Simionatto; A.V. Skabelin; E.S. Smith; L.C. Smith; D.I. Sober; D. Sokhan; M. Spraker; A. Stavinsky; S.S. Stepanyan; S. Stepanyan; B.E. Stokes; P. Stoler; I.I. Strakovsky; S. Strauch; M. Taiuti; S. Taylor; D.J. Tedeschi; U. Thoma; R. Thompson; A. Tkabladze; S. Tkachenko; L. Todor; C. Tur; M. Ungaro; M.F. Vineyard; A.V. Vlassov; K. Wang; D.P. Watts; L.B. Weinstein; H. Weller; D.P. Weygand; M. Williams; E. Wolin; M.H. Wood; A. Yegneswaran; J. Yun; L. Zana; J. Zhang; B. Zhao; and Z.W. Zhao

    2007-03-01

    Spin transfer from circularly polarized real photons to recoiling hyperons has been measured for the reactions $\\vec\\gamma + p \\to K^+ + \\vec\\Lambda$ and $\\vec\\gamma + p \\to K^+ + \\vec\\Sigma^0$. The data were obtained using the CLAS detector at Jefferson Lab for center-of-mass energies $W$ between 1.6 and 2.53 GeV, and for $-0.85<\\cos\\theta_{K^+}^{c.m.}< +0.95$. For the $\\Lambda$, the polarization transfer coefficient along the photon momentum axis, $C_z$, was found to be near unity for a wide range of energy and kaon production angles. The associated transverse polarization coefficient, $C_x$, is smaller than $C_z$ by a roughly constant difference of unity. Most significantly, the {\\it total} $\\Lambda$ polarization vector, including the induced polarization $P$, has magnitude consistent with unity at all measured energies and production angles when the beam is fully polarized. For the $\\Sigma^0$ this simple phenomenology does not hold. All existing hadrodynamic models are in poor agreement with these results.

  3. Superconducting Nuclear Recoil Sensor for Directional Dark Matter Detection

    NASA Astrophysics Data System (ADS)

    Junghans, Ann; Baldwin, Kevin; Hehlen, Markus; Lafler, Randy; Loomba, Dinesh; Phan, Nguyen; Weisse-Bernstein, Nina

    The Universe consists of 72% dark energy, 23% dark matter and only 5% of ordinary matter. One of the greatest challenges of the scientific community is to understand the nature of dark matter. Current models suggest that dark matter is made up of slowly moving, weakly interacting massive particles (WIMPs). But detecting WIMPs is challenging, as their expected signals are small and rare compared to the large background that can mimic the signal. The largest and most robust unique signature that sets them apart from other particles is the day-night variation of the directionality of dark matter on Earth. This modulation could be observed with a direction-sensitive detector and hence, would provide an unambiguous signature for the galactic origin of WIMPs. There are many studies underway to attempt to detect WIMPs both directly and indirectly, but solid-state WIMP detectors are widely unexplored although they would present many advantages to prevalent detectors that use large volumes of low pressure gas. We present first results of a novel multi-layered architecture, in which WIMPs would interact primarily with solid layers to produce nuclear recoils that then induce measureable voltage pulses in adjacent superconductor layers. This work was supported by the U.S. Department of Energy through the LANL Laboratory Directed Research and Development Program.

  4. Elastic recoil of coronary stents: a comparative analysis.

    PubMed

    Barragan, P; Rieu, R; Garitey, V; Roquebert, P O; Sainsous, J; Silvestri, M; Bayet, G

    2000-05-01

    Minimum elastic recoil (ER) has became an essential feature of new coronary stents when deployed in artheromatous lesions of various morphologies. The ER of coronary stent might be an important component of 6-month restenosis rate by minimizing the luminal loss. We evaluated the intrinsic ER of 23 coronary stents with a mechanical test bench. The amount of ER for one size of stent (3.0 mm) was quantified using a 3D optical contactless machine (Smartscope MVP, Rochester, NY). The stents were expanded on their own balloon for the precrimped stents; the uncrimped stents were expended using identical 3.0-mm balloons. Two types of measurements were done without exterior stress and with a 0.2-bar exterior stress, directly on the stent at the end of balloon expansion, immediately after balloon deflation, and then 30 min, 60 min, and 120 min after. ER ranged from 1.54%+/-0.81% (Bestent BES 15) to 16.51%+/-2.89% (Paragon stent) without stress (P<0.01) and from 2.35%+/-1.14% (Bestent BES 15) to 18.34%+/-2.41% (Cook GR2) under 0.2-bar pressure (P<0.0001). Furthermore, there was a significant reduction between the mean result of tubular stents (TS) and coil stents (CS). The results of in vitro mechanical tests may confirm strongly the interest of a minimum ER in the prevention of the 6-month restenosis. PMID:10816295

  5. First measurement of the ionization yield of nuclear recoils in liquid argon

    SciTech Connect

    Joshi, T.; Sangiorgio, Samuele; Bernstein, A.; Foxe, Michael P.; Hagmann, Chris; Jovanovic, Igor; Kazkaz, K.; Mozin, Vladimir V.; Norman, E. B.; Pereverzev, S. V.; Rebassoo, Finn O.; Sorensen, Peter F.

    2014-05-01

    Liquid phase argon has long been used as a target medium for particle detection via scintillation light. Recently there has been considerable interest in direct detection of both hypothetical darkmatter particles and coherent elastic neutrino nucleus scattering. These as-yet unobserved neutral particle interactions are expected to result in a recoiling argon atom O(keV), generally referred to in the literature as a nuclear recoil. This prompts the question of the available electromagnetic signal in a liquid argon detector. In this Letter we report the first measurement of the ionization yield (Qy), detected electrons per unit energy, resulting from nuclear recoils in liquid argon, measured at 6.7 keV. This is also the lowest energy measurement of nuclear recoils in liquid argon.

  6. A telescope proton recoil spectrometer for fast neutron beam-lines

    NASA Astrophysics Data System (ADS)

    Cazzaniga, C.; Rebai, M.; Tardocchi, M.; Croci, G.; Nocente, M.; Ansell, S.; Frost, C. D.; Gorini, G.

    2015-07-01

    Fast neutron measurements were performed on the VESUVIO beam-line at the ISIS spallation source using a new telescope proton recoil spectrometer. Neutrons interact on a plastic target. Proton production is mainly due to elastic scattering on hydrogen nuclei and secondly due to interaction with carbon nuclei. Recoil protons are measured by a proton spectrometer, which uses in coincidence a 2.54 cm thick YAP scintillator and a 500μm thick silicon detector, measuring the full proton recoil energy and the partial deposited energy in transmission, respectively. Recoil proton spectroscopy measurements (up to Ep = 60MeV) have been interpreted by using Monte Carlo simulations of the beam-line. This instrument is of particular interest for the characterization of the ChipIr beam-line at ISIS, which was designed to feature an atmospheric-like neutron spectrum for the irradiation of micro-electronics.

  7. MIMAC low energy electron-recoil discrimination measured with fast neutrons

    NASA Astrophysics Data System (ADS)

    Riffard, Q.; Santos, D.; Guillaudin, O.; Bosson, G.; Bourrion, O.; Bouvier, J.; Descombes, T.; Muraz, J.-F.; Lebreton, L.; Maire, D.; Colas, P.; Giomataris, I.; Busto, J.; Fouchez, D.; Brunner, J.; Tao, C.

    2016-08-01

    MIMAC (MIcro-TPC MAtrix of Chambers) is a directional WIMP Dark Matter detector project. Direct dark matter experiments need a high level of electron/recoil discrimination to search for nuclear recoils produced by WIMP-nucleus elastic scattering. In this paper, we proposed an original method for electron event rejection based on a multivariate analysis applied to experimental data acquired using monochromatic neutron fields. This analysis shows that a 105 rejection power is reachable for electron/recoil discrimination. Moreover, the efficiency was estimated by a Monte-Carlo simulation showing that a 105 electron rejection power is reached with a 86.49 ± 0.17% nuclear recoil efficiency considering the full energy range and 94.67 ± 0.19% considering a 5 keV lower threshold.

  8. Radiative-recoil corrections to hyperfine splitting: Polarization insertions in the muon factor

    SciTech Connect

    Eides, Michael I.; Shelyuto, Valery A.

    2009-09-01

    We consider three-loop radiative-recoil corrections to hyperfine splitting in muonium due to insertions of a one-loop polarization operator in the muon factor. The contribution produced by electron polarization insertions is enhanced by the large logarithm of the electron-muon mass ratio. We obtained all single-logarithmic and nonlogarithmic radiative-recoil corrections of order {alpha}{sup 3}(m/M)E{sub F} generated by the diagrams with electron and muon polarization insertions.

  9. Investigation on modeling and controability of a magnetorheological gun recoil damper

    NASA Astrophysics Data System (ADS)

    Hu, Hongsheng; Wang, Juan; Wang, Jiong; Qian, Suxiang; Li, Yancheng

    2009-07-01

    Magnetorheological (MR) fluid as a new smart material has done well in the vibration and impact control engineering fields because of its good electromechanical coupling characteristics, preferable dynamic performance and higher sensitivity. And success of MRF has been apparent in many engineering applied fields, such as semi-active suspension, civil engineering, etc. So far, little research has been done about MR damper applied into the weapon system. Its primary purpose of this study is to identify its dynamic performance and controability of the artillery recoil mechanism equipped with MR damper. Firstly, based on the traditional artillery recoil mechanism, a recoil dynamic model is developed in order to obtain an ideal rule between recoil force and its stroke. Then, its effects of recoil resistance on the stability and firing accuracy of artillery are explored. Because MR gun recoil damper under high impact load shows a typical nonlinear character and there exists a shear-thinning phenomenon, to establish an accurate dynamic model has been a seeking aim of its design and application for MR damper under high impact load. Secondly, in this paper, considering its actual bearing load, an inertia factor was introduced to Herschel-Bulkley model, and some factor's effect on damping force are simulated and analyzed by using numerical simulation, including its dynamic performance under different flow coefficients and input currents. Finally, both of tests with the fixed current and different On-Off control algorithms have been done to confirm its controability of MR gun recoil damper under high impact load. Experimental results show its dynamic performances of the large-scale single-ended MR gun recoil damper can be changed by altering the applied currents and it has a good controllability.

  10. High-resolution measurements of the DT neutron spectrum using new CD foils in the Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility

    NASA Astrophysics Data System (ADS)

    Gatu Johnson, M.; Frenje, J. A.; Bionta, R. M.; Casey, D. T.; Eckart, M. J.; Farrell, M. P.; Grim, G. P.; Hartouni, E. P.; Hatarik, R.; Hoppe, M.; Kilkenny, J. D.; Li, C. K.; Petrasso, R. D.; Reynolds, H. G.; Sayre, D. B.; Schoff, M. E.; Séguin, F. H.; Skulina, K.; Yeamans, C. B.

    2016-11-01

    The Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility measures the DT neutron spectrum from cryogenically layered inertial confinement fusion implosions. Yield, areal density, apparent ion temperature, and directional fluid flow are inferred from the MRS data. This paper describes recent advances in MRS measurements of the primary peak using new, thinner, reduced-area deuterated plastic (CD) conversion foils. The new foils allow operation of MRS at yields 2 orders of magnitude higher than previously possible, at a resolution down to ˜200 keV FWHM.

  11. High-resolution measurements of the DT neutron spectrum using new CD foils in the Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility

    DOE PAGESBeta

    Gatu Johnson, M.; Frenje, J. A.; Bionta, R. M.; Casey, D. T.; Eckart, M. J.; Farrell, M. P.; Grim, G. P.; Hartouni, E. P.; Hatarik, R.; Hoppe, M.; et al

    2016-08-09

    The Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility measures the DT neutron spectrum from cryogenically layered inertial confinement fusion implosions. Yield, areal density, apparent ion temperature, and directional fluid flow are inferred from the MRS data. Here, this paper describes recent advances in MRS measurements of the primary peak using new, thinner, reduced-area deuterated plastic (CD) conversion foils. The new foils allow operation of MRS at yields 2 orders of magnitude higher than previously possible, at a resolution down to ~200 keV FWHM.

  12. Influence of elastic recoil on restenosis after successful coronary angioplasty in unstable angina pectoris.

    PubMed

    Ardissino, D; Di Somma, S; Kubica, J; Barberis, P; Merlini, P A; Eleuteri, E; De Servi, S; Bramucci, E; Specchia, G; Montemartini, C

    1993-03-15

    The elastic behavior of the dilated coronary vessel has been reported to affect the immediate results of coronary angioplasty. To determine whether elastic recoil may also influence the long-term restenosis process, 98 consecutive patients with unstable angina and 1-vessel disease were studied. An automated coronary quantitative program was used for the assessment of balloon and coronary luminal diameters. Elastic recoil was defined as the percent reduction between minimal balloon diameter at the highest inflation pressure and minimal lesion diameter immediately after coronary angioplasty. Follow-up coronary arteriography was performed 8 to 12 months after the procedure in all patients. The mean elastic recoil averaged 17.7 +/- 16% and was correlated to the degree of residual stenosis immediately after coronary angioplasty (r = 0.64; p < 0.001). Restenosis, defined as > 50% diameter stenosis at follow-up, developed in 53 patients (54%). There was no correlation between the degree of elastic recoil and the changes in minimal lesion diameter observed during follow-up, whereas a positive correlation between the amount of elastic recoil and the incidence of restenosis was documented (r = 0.84; p < 0.05). Thus, the elastic properties of the dilated vessel do not influence the active process of restenosis. However, because elastic recoil negatively influences the initial results of angioplasty, it is more likely that further reductions in lumen diameter during follow-up can reach a threshold of obstruction considered critical for a binary definition of restenosis. PMID:8447261

  13. Diurnal variations of carbonaceous components, major ions, and stable carbon and nitrogen isotope ratios in suburban aerosols from northern vicinity of Beijing

    NASA Astrophysics Data System (ADS)

    He, Nannan; Kawamura, Kimitaka; Kanaya, Yugo; Wang, Zifa

    2015-12-01

    We report diurnal variations of organic carbon (OC), elemental carbon (EC), water-soluble organic carbon (WSOC) and major ions as well as stable carbon and nitrogen isotope ratios (δ13C and δ15N) in ambient aerosols at a suburban site (Mangshan), 40 km north of Beijing, China. We found that aerosol chemical compositions were largely controlled by the air mass transport from Beijing in daytime with southerly winds and by relatively fresh air mass in nighttime from the northern forest areas with northerly winds. Higher concentrations of aerosol mass and total carbon were obtained in daytime. Further, higher OC/EC ratios were recorded in daytime (4.0 ± 1.7) than nighttime (3.2 ± 0.7), suggesting that OC is formed by photochemical oxidation of gaseous precursors in daytime. Contributions of WSOC to OC were slightly higher in daytime (38%) than nighttime (34%), possibly due to secondary formation of WSOC in daytime. We also found higher concentrations of Ca2+ in daytime, which was originated from the construction dust in Beijing area and transported to the sampling site. δ13C ranged from -25.3 to -21.2‰ (ave. -23.5 ± 0.9‰) in daytime and -29.0 to -21.4‰ (-24.0 ± 1.5‰) in nighttime, suggesting that Mangshan aerosols were more influenced by fossil fuel combustion products in daytime and by terrestrial C3 plants in nighttime. This study suggests that daytime air mass delivery from megacity Beijing largely influence the air quality at the receptor site in the north together with photochemical processing of organic aerosols during the atmospheric transport, whereas the Mangshan site is covered with relatively clean air masses at night.

  14. Nitrogen In Saturn's Inner Magnetosphere

    NASA Astrophysics Data System (ADS)

    Smith, H. T.; Sittler, E. C.; Johnson, R. E.; McComas, D.; Reisenfeld, D.; Shappirio, M.; Michael, M.; Shematovich, V. I.; Baragiola, R. A.; Crary, F.; Young, D.

    2004-11-01

    We are analyzing CAPS instrument data on Cassini to look for nitrogen ions in Saturn's magnetosphere. Because Voyager could not separate oxygen and nitrogen, there has been considerable controversy on nitrogen's presence and relative importance. Two principal sources have been suggested: Titan's atmosphere and nitrogen species trapped in Saturn's icy satellite surfaces (Sittler et al 2004). The latter may be primordial nitrogen, likely as NH3 in ice (Stevenson 1982; Squyers et al. 1983) or nitrogen ions that have been implanted in the surface (Delitsky and Lane 2002). We will present the results of Saturnian nitrogen cloud modeling and relevant CAPS observations. We recently described the Titan source (Michael, et al. 2004; Shematovich et al. 2003; Smith et al. 2004; Sittler et al. 2004) in preparation for Cassini's Saturnian plasma measurements. Two components were identified: energetic nitrogen ions formed near Titan and energized as they diffused inward (Sittler et al. 2004) and neutrals in orbits with small perigee that became ionized in the inner magnetosphere (Smith et al 2004). The latter component would be a source of lower energy, co-rotating nitrogen ions to the inner magnetosphere. Such a component would have an energy spectrum similar to nitrogen species sputtered from the icy satellite surfaces (Johnson and Sittler 1990). However, the mass spectrum would differ, likely containing NHx and NOx species also, and, hence, may be separated from the Titan source. Our preliminary analysis for nitrogen species in the CAPS data will be compared to the models. Of interest will be the energy spectra, which can indicate whether any nitrogen present is formed locally or near Titan's orbit and diffused inward. This work is supported by the NASA Planetary Atmospheres, NASA Graduate Student Research, Virginia Space Grant Consortium Graduate Research Fellowship and the CAPS Cassini instrument team programs.

  15. A curved detection-slit to improve ERD (Elastic Recoil Detection) energy/depth resolution

    SciTech Connect

    Brice, D.K.; Doyle, B.L.

    1989-01-01

    Recoil atoms detected in Elastic Recoil Detection (ERD) experiments emerge from an initial collision area along cones of constant energy due to the cylindrical symmetry of the elastic scattering cross section. The constant energy cones therefore intercept planar slit plates placed before the detectors in conic sections. For ease of fabrication slits are typically configured as long narrow rectangles, and as a result energy resolution is adversely affected. It has been shown that the kinematic broadening caused by using rectangular slits is minimized when L = 2 (W z tan/Theta//sub recoil/)/sup 1/2/ where W is the slit width, L is the slit length, z is the slit-target distance and /Theta//sub recoil/ is the lab-frame recoil angle. The improved energy resolution which results when rectangular slits are replaced by appropriate curved slits is examined here. Formulas are given for the conic sections associated with the curved slits as a function of experimental geometry. When slit dimensions are small compared with the full extent of the conic section slit geometry can be accurately approximated as the arc of a circle with radius R/sub c/ = z tan/Theta//sub recoil/. Energy loss effects on the resolution are also accounted for in our treatment. The use of curved slits with L = 4 (W z tan/Theta//sub recoil/)/sup 1/2/ is shown to improve kinematic broadening by /approximately/50% as compared to optimized rectangular slits of the same area. 2 refs., 5 figs.

  16. A detector for filtering γ-ray spectra from weak fusion evaporation reactions out of strong background and for Doppler correction: The recoil filter detector, RFD

    NASA Astrophysics Data System (ADS)

    Męczyński, W.; Bednarczyk, P.; Grębosz, J.; Heese, J.; Janicki, M.; Maier, K. H.; Merdinger, J. C.; Spohr, K.; Ziębliński, M.; Styczeń, J.

    2007-10-01

    A detector has been designed and built to assist in-beam γ-ray spectroscopy with fusion-evaporation reactions. It measures with high efficiency the evaporation residues that recoil out of a thin target into the angular interval from 1.8° to 9.0° at an adjustable distance of 1000-1350 mm from a target, in coincidence with γ-rays detected in a Ge-detector array. This permits filtering of such γ-rays out of a much stronger background of other reaction products and scattered beam. Evaporation residues are identified by their time-of-flight and the pulse height using a pulsed beam. The velocity vector of the γ-emitting recoil is also measured in the event-by-event mode, facilitating to correct the registered γ-ray energy for the Doppler shift, with the resulting significant improvement of the energy resolution. The heavy-ion detection scheme uses emission of secondary electrons caused by the recoiling ions when hitting a thin foil. These electrons are then electrostatically accelerated and focused onto a small scintillator that measures the summed electron energy, which is proportional to the number of electrons. The detector is able to operate at high frequency of the order of 1 MHz and detect very heavy nuclei with as low kinetic energy as 5 MeV. The paper describes the properties of the detector and gives examples of measurements with the OSIRIS, GAREL+ and EUROBALL IV γ-ray spectrometers. The usefulness of the technique for spectroscopic investigations of nuclei with a continuous beam is also discussed.

  17. Recoil-Implantation Of Multiple Radioisotopes Towards Wear Rate Measurements And Particle Tracing In Prosthetic Joints

    SciTech Connect

    Warner, Jacob A.; Timmers, Heiko; Smith, Paul N.; Scarvell, Jennifer M.; Gladkis, Laura

    2011-06-01

    This study demonstrates a new method of radioisotope labeling of ultra-high molecular weight polyethylene inserts in prosthetic joints for wear studies. The radioisotopes {sup 97}Ru, {sup 100}Pd, {sup 100}Rh, and {sup 101m}Rh are produced in fusion evaporation reactions induced by {sup 12}C ions in a {sup 92}Zr target foil. The fusion products recoil-implant into ultra-high molecular weight polyethylene plugs, machined to fit into the surface of the inserts. During laboratory simulations of the joint motion, a wear rate of the labeled polyethylene may be measured and the pathways of wear debris particles can be traced by detecting characteristic gamma-rays. The concentration profiles of the radioisotopes extend effectively uniformly from the polyethylene surface to a depth of about 4 {mu}m. The multiplicity of labeling and the use of several gamma-ray lines aids with avoiding systematic measurement uncertainties. Two polyethylene plugs were labeled and one was fitted into the surface of the tibial insert of a knee prosthesis, which had been worn in. Actuation over close to 100,000 cycles with a 900 N axial load and a 24 deg. flexion angle removed (14{+-}1)% of the gamma-ray activity from the plug. Most of this activity dispersed into the serum lubricant identifying this as the important debris pathway. Less than 1% activity was transferred to the femoral component of the prosthesis and the measured activity on the tibial tray was insignificant. Assuming uniform wear across the superior surface of the insert, a wear rate of (12{+-}3) mm{sup 3}/Megacycle was determined. This is consistent with wear rate measurements under similar conditions using other techniques.

  18. A recoil detector for the measurement of antiproton-proton elastic scattering at angles close to 90°

    NASA Astrophysics Data System (ADS)

    Hu, Q.; Bechstedt, U.; Gillitzer, A.; Grzonka, D.; Khoukaz, A.; Klehr, F.; Lehrach, A.; Prasuhn, D.; Ritman, J.; Sefzick, T.; Stockmanns, T.; Täschner, A.; Wuestner, P.; Xu, H.

    2014-10-01

    The design and construction of a recoil detector for the measurement of recoil protons of antiproton-proton elastic scattering at scattering angles close to are described. The performance of the recoil detector has been tested in the laboratory with radioactive sources and at COSY with proton beams by measuring proton-proton elastic scattering. The results of laboratory tests and commissioning with beam are presented. Excellent energy resolution and proper working performance of the recoil detector validate the conceptual design of the KOALA experiment at HESR to provide the cross section data needed to achieve a precise luminosity determination at the PANDA experiment.

  19. Imprints of recoiling massive black holes on the hot gas of early-type galaxies

    NASA Astrophysics Data System (ADS)

    Devecchi, B.; Rasia, E.; Dotti, M.; Volonteri, M.; Colpi, M.

    2009-04-01

    Anisotropic gravitational radiation from a coalescing black hole (BH) binary is known to impart recoil velocities of up to ~1000kms-1 to the remnant BH. In this context, we study the motion of a recoiling BH inside a galaxy modelled as a Hernquist sphere, and the signature that the hole imprints on the hot gas, using N-body/smoothed particle hydrodynamics simulations. Ejection of the BH results in a sudden expansion of the gas ending with the formation of a gaseous core, similarly to what is seen for the stars. A cometary tail of particles bound to the BH is initially released along its trail. As the BH moves on a return orbit, a nearly spherical swarm of hot gaseous particles forms at every apocentre: this feature can live up to ~108 years. If the recoil velocity exceeds the sound speed initially, the BH shocks the gas in the form of a Mach cone in density near each supersonic pericentric passage. We find that the X-ray fingerprint of a recoiling BH can be detected in Chandra X-ray maps out to a distance of Virgo. For exceptionally massive BHs, the Mach cone and the wakes can be observed out to a few hundred of milliparsec. The detection of the Mach cone is of twofold importance as it can be a probe of high-velocity recoils, and an assessment of the scatter of the MBH - Mbulge relation at large BH masses.

  20. Measurement of nuclear recoil quenching factors in CaWO 4

    NASA Astrophysics Data System (ADS)

    Jagemann, Th.; Feilitzsch, F. v.; Hagn, H.; Jochum, J.; Potzel, W.; Rau, W.; Stark, M.; Westphal, W.

    2006-11-01

    The CRESST experiment, aiming at the direct detection of WIMPs via nuclear recoils, is currently using scintillating CaWO4 crystals. The WIMP-nucleus cross section for elastic scattering as well as the scintillation efficiency differ considerably for recoils from Ca, W and O in these crystals. Therefore a discriminating detector calibration is essential in order to improve WIMP parameter claims. At the tandem accelerator of the Maier-Leibnitz-Laboratory (MLL) in Garching, Germany, a neutron scattering facility is operated for the determination of the individual quenching factors (QF) in the bulk of a CaWO4 crystal to better understand the detector response to neutron background and a possible WIMP signal. First measurements at room temperature reveal QF(O) = 7.8 ± 0.3% (recoil energy 1.0-2.2 MeV), QF(Ca) = 6.3 ± 1.6% (recoil energy 0.4-1 MeV), QF(W) < 3.0% (2σ, recoil energy 0.1 MeV).

  1. Spatial patterns of atmospheric deposition of nitrogen and sulfur using ion-exchange resin collectors in Rocky Mountain National Park, USA

    USGS Publications Warehouse

    Clow, David W.; Roop, Heidi; Nanus, Leora; Fenn, Mark; Sexstone, Graham A.

    2015-01-01

    Lakes and streams in Class 1 wilderness areas in the western United States (U.S.) are at risk from atmospheric deposition of nitrogen (N) and sulfur (S), and protection of these resources is mandated under the Federal Clean Air Act and amendments. Assessment of critical loads, which are the maximum exposure to pollution an area can receive without adverse effects on sensitive ecosystems, requires accurate deposition estimates. However, deposition is difficult and expensive to measure in high-elevation wilderness, and spatial patterns in N and S deposition in these areas remain poorly quantified. In this study, ion-exchange resin (IER) collectors were used to measure dissolved inorganic N (DIN) and S deposition during June 2006–September 2007 at approximately 20 alpine/subalpine sites spanning the Continental Divide in Rocky Mountain National Park. Results indicated good agreement between deposition estimated from IER collectors and commonly used wet + dry methods during summer, but poor agreement during winter. Snowpack sampling was found to be a more accurate way of quantifying DIN and S deposition during winter. Summer DIN deposition was significantly greater on the east side of the park than on the west side (25–50%; p ≤ 0.03), consistent with transport of pollutants to the park from urban and agricultural areas to the east. Sources of atmospheric nitrate (NO3−) were examined using N isotopes. The average δ15N of NO3− from IER collectors was 3.5‰ higher during winter than during summer (p < 0.001), indicating a seasonal shift in the relative importance of regional NOxsources, such as coal combustion and vehicular sources of atmospheric NO3−. There were no significant differences in δ15N of NO3− between east and west sides of the park during summer or winter (p = 0.83), indicating that the two areas may have similar sources of atmospheric NO3−. Results from this study indicate that a combination of IER collectors and snowpack

  2. Spatial patterns of atmospheric deposition of nitrogen and sulfur using ion-exchange resin collectors in Rocky Mountain National Park, USA

    NASA Astrophysics Data System (ADS)

    Clow, David W.; Roop, Heidi A.; Nanus, Leora; Fenn, Mark E.; Sexstone, Graham A.

    2015-01-01

    Lakes and streams in Class 1 wilderness areas in the western United States (U.S.) are at risk from atmospheric deposition of nitrogen (N) and sulfur (S), and protection of these resources is mandated under the Federal Clean Air Act and amendments. Assessment of critical loads, which are the maximum exposure to pollution an area can receive without adverse effects on sensitive ecosystems, requires accurate deposition estimates. However, deposition is difficult and expensive to measure in high-elevation wilderness, and spatial patterns in N and S deposition in these areas remain poorly quantified. In this study, ion-exchange resin (IER) collectors were used to measure dissolved inorganic N (DIN) and S deposition during June 2006-September 2007 at approximately 20 alpine/subalpine sites spanning the Continental Divide in Rocky Mountain National Park. Results indicated good agreement between deposition estimated from IER collectors and commonly used wet + dry methods during summer, but poor agreement during winter. Snowpack sampling was found to be a more accurate way of quantifying DIN and S deposition during winter. Summer DIN deposition was significantly greater on the east side of the park than on the west side (25-50%; p ≤ 0.03), consistent with transport of pollutants to the park from urban and agricultural areas to the east. Sources of atmospheric nitrate (NO3-) were examined using N isotopes. The average δ15N of NO3- from IER collectors was 3.5‰ higher during winter than during summer (p < 0.001), indicating a seasonal shift in the relative importance of regional NOx sources, such as coal combustion and vehicular sources of atmospheric NO3-. There were no significant differences in δ15N of NO3- between east and west sides of the park during summer or winter (p = 0.83), indicating that the two areas may have similar sources of atmospheric NO3-. Results from this study indicate that a combination of IER collectors and snowpack sampling can be used to

  3. Annealing of Diamond and Diamondlike Carbon Films: AN Ion Beam Analysis Study.

    NASA Astrophysics Data System (ADS)

    Zorman, Christian Aaron

    The Van de Graaff accelerator at Case Western Reserve University was used to study annealed diamond and diamondlike carbon films. Rutherford backscattering spectroscopy and elastic recoil detection analysis were used to characterize the as-deposited and annealed samples. The diamond films were deposited by microwave enhanced CVD while the diamondlike carbon films were deposited by plasma enhanced CVD and ion beam techniques. Included in the study were nitrogenated diamondlike carbon films. The samples were annealed inside the ion scattering chamber via a heated sample holder. The samples were annealed in a stepwise manner, beginning at room temperature and ending at 550^circC. RBS and ERD spectra were simultaneously collected at each step in the annealing process. The compositional stability of the diamondlike carbon samples was determined. PECVD diamondlike carbon films remained stable up to 400^circ C, above which the hydrogen effusion was quite high. Nitrogenated diamondlike carbon films containing less than 10 atomic percent hydrogen remained stable up to 400^ circC while the hydrogenated samples were not stable above 200^circC. A distinct hydrogen enriched surface region was observed on the diamond samples. This region disappeared upon annealing at 400^circC and is most likely due to hydrogen containing adsorbates on the surface. The dynamics of this region were investigated and compared with secondary electron emission data on these samples.

  4. Effect of adduct formation with molecular nitrogen on the measured collisional cross sections of transition metal-1,10-phenanthroline complexes in traveling wave ion-mobility spectrometry: N2 is not always an "inert" buffer gas.

    PubMed

    Rijs, Nicole J; Weiske, Thomas; Schlangen, Maria; Schwarz, Helmut

    2015-10-01

    The number of separations and analyses of molecular species using traveling wave ion-mobility spectrometry-mass spectrometry (TWIMS-MS) is increasing, including those extending the technique to analytes containing metal atoms. A critical aspect of such applications of TWIMS-MS is the validity of the collisional cross sections (CCSs) measured and whether they can be accurately calibrated against other ion-mobility spectrometry (IMS) techniques. Many metal containing species have potential reactivity toward molecular nitrogen, which is present in high concentration in the typical Synapt-G2 TWIMS cell. Here, we analyze the effect of nitrogen on the drift time of a series of cationic 1,10-phenanthroline complexes of the late transition metals, [(phen)M](+), (M = Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, and Hg) in order to understand potential deviations from expected drift time behaviors. These metal complexes were chosen for their metal open-coordination site and lack of rotameric species. The target species were generated via electrospray ionization (ESI), analyzed using TWIMS in N2 drift gas, and the observed drift time trends compared. Theoretically derived CCSs for all species (via both the projection approximation and trajectory method) were also compared. The results show that, indeed, for metal containing species in this size regime, reaction with molecular nitrogen has a dramatic effect on measured drift times and must not be ignored when comparing and interpreting TWIMS arrival time distributions. Density-functional theory (DFT) calculations are employed to analyze the periodic differences due to the metal's interaction with nitrogen (and background water) in detail. PMID:26378338

  5. Experimental Concept for a Precision Measurement of Nuclear Recoil Ionization Yields for Low Mass WIMP Searches

    NASA Astrophysics Data System (ADS)

    Saab, T.; Figueroa-Feliciano, E.

    2016-07-01

    Understanding the response of dark matter detectors at the lowest recoil energies is important for correctly interpreting data from current experiments or predicting the sensitivity of future experiments to low mass weakly interacting massive particles. In particular, the ionization yield is essential for determining the correct recoil energy of candidate nuclear recoil events; however, few measurements in cryogenic crystals exist below 1 keV. Using the voltage-assisted calorimetric ionization detection technique with a mono-energetic neutron source, we show that it is possible to determine the ionization yield in cryogenic crystals down to an energy to 100 eV. This measurement will also determine the statistics of ionization production at these low energies.

  6. Dynamical simulations of radiation damage induced by 10 keV energetic recoils in UO 2

    NASA Astrophysics Data System (ADS)

    Tian, X. F.; Gao, T.; Long, Chongsheng; Li, JiuKai; Jiang, Gang; Xiao, Hongxing

    2011-08-01

    We have performed classical molecular dynamics simulations to simulate the primary damage state induced by 10 keV energetic recoils in UO 2. The numbers versus time and the distance distributions for the displaced uranium and oxygen atoms were investigated with the energetic recoils accelerated along four different directions. The simulations suggest that the direction of the primary knock-on atom (PKA) has no effect on the final primary damage state. In addition, it was found that atomic displacement events consisted of replacement collision sequences in addition to the production of Frenkel pairs. The spatial distribution of defects introduced by 10 keV collision cascades was also presented and the results were similar to that of energetic recoils with lower energy.

  7. Nuclear astrophysics at the Holifield Radioactive Ion Beam Facility

    SciTech Connect

    Blackmon, J.C.

    1996-10-01

    Reactions involving radioactive nuclei play an important role in explosive stellar events such as novae, supernovae, and X-ray bursts. The development of accelerated, proton-rich radioactive ion beams provides a tool for directly studying many of the reactions that fuel explosive hydrogen burning. The experimental nuclear astrophysics program at the Holifield Radioactive Ion Beam Facility at Oak Ridge National Laboratory is centered on absolute cross section measurements of these reactions with radioactive ion beams. Beams of {sup 17}F and {sup 18}F, important nuclei in the hot-CNO cycle, are currently under development at HRIBF. Progress in the production of intense radioactive fluorine beams is reported. The Daresbury Recoil Separator (DRS) has been installed at HRIBF as the primary experimental station for nuclear astrophysics experiments. The DRS will be used to measure reactions in inverse kinematics with the techniques of direct recoil detection, delayed-activity recoil detection, and recoil-gamma coincidence measurements. The first astrophysics experiments to be performed at HRIBF, mA the application of the recoil separator in these measurements, are discussed.

  8. Recoiling black holes: prospects for detection and implications of spin alignment

    NASA Astrophysics Data System (ADS)

    Blecha, Laura; Sijacki, Debora; Kelley, Luke Zoltan; Torrey, Paul; Vogelsberger, Mark; Nelson, Dylan; Springel, Volker; Snyder, Gregory; Hernquist, Lars

    2016-02-01

    Supermassive black hole (BH) mergers produce powerful gravitational wave emission. Asymmetry in this emission imparts a recoil kick to the merged BH, which can eject the BH from its host galaxy altogether. Recoiling BHs could be observed as offset active galactic nuclei (AGN). Several candidates have been identified, but systematic searches have been hampered by large uncertainties regarding their observability. By extracting merging BHs and host galaxy properties from the Illustris cosmological simulations, we have developed a comprehensive model for recoiling AGN. Here, for the first time, we model the effects of BH spin alignment and recoil dynamics based on the gas richness of host galaxies. We predict that if BH spins are not highly aligned, seeing-limited observations could resolve offset AGN, making them promising targets for all-sky surveys. For randomly oriented spins, ≲ 10 spatially offset AGN may be detectable in Hubble Space Telescope-Cosmological Evolution Survey, and >103 could be found with the Panoramic Survey Telescope & Rapid Response System (Pan-STARRS), the Large Synoptic Survey Telescope (LSST), Euclid, and the Wide-Field Infrared Survey Telescope (WFIRST). Nearly a thousand velocity offset AGN are predicted within the Sloan Digital Sky Survey (SDSS) footprint; the rarity of large broad-line offsets among SDSS quasars is likely due in part to selection effects but suggests that spin alignment plays a role in suppressing recoils. None the less, in our most physically motivated model where alignment occurs only in gas-rich mergers, hundreds of offset AGN should be found in all-sky surveys. Our findings strongly motivate a dedicated search for recoiling AGN.

  9. Observation of Collective Atomic Recoil Motion in a Degenerate Fermion Gas

    SciTech Connect

    Wang Pengjun; Fu Zhengkun; Chai Shijie; Zhang Jing; Deng, L.; Hagley, E. W.

    2011-05-27

    We demonstrate collective atomic recoil motion with a dilute, ultracold, degenerate fermion gas in a single spin state. By utilizing an adiabatically decompressed magnetic trap with an aspect ratio different from that of the initial trap, a momentum-squeezed fermion cloud is achieved. With a single pump pulse of the proper polarization, we observe, for the first time, multiple wave-mixing processes that result in distinct collective atomic recoil motion modes in a degenerate fermion cloud. Contrary to the case with Bose condensates, no pump-laser detuning asymmetry is present.

  10. Radiative recoil corrections to hyperfine splitting: Polarization insertions in the electron factor

    SciTech Connect

    Eides, M. I.; Shelyuto, V. A.

    2010-01-15

    We consider three-loop radiative recoil corrections to hyperfine splitting in muonium due to insertions of the one-loop polarization operator in the electron factor. The contribution generated by electron polarization insertions is a cubic polynomial in the large logarithm of the electron-muon mass ratio. The leading logarithm cubed and logarithm squared terms are well known for some time. We calculate all single-logarithmic and nonlogarithmic radiative recoil corrections of the order {alpha}{sup 3}(m/M)E{sub F} generated by diagrams with the electron and muon polarization insertions.

  11. Analytical calculation of the electron-line radiative-recoil corrections to muonium hyperfine splitting

    NASA Astrophysics Data System (ADS)

    Eides, M. I.; Karshenboim, S. G.; Shelyuto, V. A.

    1986-09-01

    An analytical calculation of electron-line radiative corrections to muonium hyperfine splitting is presented. The classic non-recoil and leading logarithmic radiative-recoil contribution is re-evaluated and a new term is obtained, which was not known previously in analytical form. This new term is found to be [ {α(Zα)}/{π 2}]( {m e}/{m μ})E F[6ζ(3)+3π 2 ln 2+ {1}/{2}π 2+ {17}/{18}], where EF is the Fermi energy.

  12. A gas-jet transport and catcher technique for on-line production of radioactive ion beams using an electron cyclotron resonance ion-source

    NASA Astrophysics Data System (ADS)

    Naik, V.; Chakrabarti, A.; Bhattacharjee, M.; Karmakar, P.; Bandyopadhyay, A.; Bhattacharjee, S.; Dechoudhury, S.; Mondal, M.; Pandey, H. K.; Lavanyakumar, D.; Mandi, T. K.; Dutta, D. P.; Kundu Roy, T.; Bhowmick, D.; Sanyal, D.; Srivastava, S. C. L.; Ray, A.; Ali, Md. S.

    2013-03-01

    Radioactive ion beams (RIB) have been produced on-line, using a gas-jet recoil transport coupled Electron Cyclotron Resonance (ECR) ion-source at the VECC-RIB facility. Radioactive atoms/molecules carried through the gas-jet were stopped in a catcher placed inside the ECR plasma chamber. A skimmer has been used to remove bulk of the carrier gas at the ECR entrance. The diffusion of atoms/molecules through the catcher has been verified off-line using stable isotopes and on-line through transmission of radioactive reaction products. Beams of 14O (71 s), 42K (12.4 h), 43K (22.2 h), and 41Ar (1.8 h) have been produced by bombarding nitrogen and argon gas targets with proton and alpha particle beams from the K130 cyclotron at VECC. Typical measured intensity of RIB at the separator focal plane is found to be a few times 103 particles per second (pps). About 3.2 × 103 pps of 1.4 MeV 14O RIB has been measured after acceleration through a radiofrequency quadrupole linac. The details of the gas-jet coupled ECR ion-source and RIB production experiments are presented along with the plans for the future.

  13. Friction and Wear Properties of As-deposited and Carbon Ion-implanted Diamond Films

    NASA Technical Reports Server (NTRS)

    Miyoshi, Kazuhisa

    1994-01-01

    Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 ke V ion energy, resulting in a dose of 1.2310(exp 17) carbon ions/cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, x-ray photoelectron spectroscopy, and x-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40 percent relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and were properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to 10(exp -8)mm(exp 3)/N-m) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4)mm(exp 3/N-m) in ultrahigh vacuum. The carbon ion implanation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, nondiamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine- and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7)mm(exp 3/N-m). Even in ultrahigh vacuum, the presence of the nondiamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6)mm(exp 3)/N-m. Thus, the carbon ion-implanted, fine

  14. Friction and Wear Properties of As-Deposited and Carbon Ion-Implanted Diamond Films

    NASA Technical Reports Server (NTRS)

    Miyoshi, Kazuhisa

    1996-01-01

    Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 keV ion energy, resulting in a dose of 1.2 x 10(exp 17) carbon ions per cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40% relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and wear properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to lO(exp -8) mm(exp 3) N(exp -1) m(exp -1)) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4) mm(exp 7) N(exp -1) m(exp -1)) in ultrahigh vacuum. The carbon ion implantation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, non-diamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7) mm(exp 3) N(exp -1) m(exp-1)). Even in ultrahigh vacuum, the presence of the non-diamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6

  15. Scalable synthesis of core-shell structured SiOx/nitrogen-doped carbon composite as a high-performance anode material for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Shi, Lu; Wang, Weikun; Wang, Anbang; Yuan, Keguo; Jin, Zhaoqing; Yang, Yusheng

    2016-06-01

    In this work, a novel core-shell structured SiOx/nitrogen-doped carbon composite has been prepared by simply dispersing the SiOx particles, which are synthesized by a thermal evaporation method from an equimolar mixture of Si and SiO2, into the dopamine solution, followed by a carbonization process. The SiOx core is well covered by the conformal and homogeneous nitrogen-doped carbon layer from the pyrolysis of polydopamine. By contrast with the bare SiOx, the electrochemical performance of the as-prepared core-shell structured SiOx/nitrogen-doped carbon composite has been improved significantly. It delivers a reversible capacity of 1514 mA h g-1 after 100 cycles at a current density of 100 mA g-1 and 933 mA h g-1 at 2 A g-1, much higher than those of commercial graphite anodes. The nitrogen-doped carbon layer ensures the excellent electrochemical performance of the SiOx/C composite. In addition, since dopamine can self-polymerize and coat virtually any surface, this versatile, facile and highly efficient coating process may be widely applicable to obtain various composites with uniform nitrogen-doped carbon coating layer.

  16. Towards understanding the effects of carbon and nitrogen-doped carbon coating on the electrochemical performance of Li4Ti5O12 in lithium ion batteries: a combined experimental and theoretical study.

    PubMed

    Ding, Zijing; Zhao, Liang; Suo, Liumin; Jiao, Yang; Meng, Sheng; Hu, Yong-Sheng; Wang, Zhaoxiang; Chen, Liquan

    2011-09-01

    We investigate the effects of carbon coating, with and without nitrogen-dopants, on the electrochemical performance of a promising anode material Li(4)Ti(5)O(12) (LTO) in lithium ion battery applications. The comparative experimental results show that LTO samples coated with nitrogen-doped carbon derived from pyridine and an ionic liquid exhibit significant improvements in rate capability and cycling performance compared with a LTO sample coated by carbon derived from toluene and the pristine LTO sample. For the first time, we construct an atomistic model for the interface between the lithium transition metal oxide and carbon coating layers. Our first-principles calculations based on density functional theory reveal that at this interface there is strong binding between the graphene coating layer and the Ti-terminated LTO surface, which significantly reduces the chemical activity of LTO surfaces and stabilizes the electrode/electrolyte interface, providing a clue to solve the swelling problem for LTO-based batteries. More importantly, electron transfer from the LTO surface to graphene greatly improves the electric conductivity of the interface. Nitrogen-dopants in graphene coatings further increase the interfacial stability and electric conductivity, which is beneficial to the electrochemical performance in energy storage applications.

  17. Control of ion content and nitrogen species using a mixed chemistry plasma for GaN grown at extremely high growth rates >9 μm/h by plasma-assisted molecular beam epitaxy

    SciTech Connect

    Gunning, Brendan P.; Clinton, Evan A.; Merola, Joseph J.; Doolittle, W. Alan; Bresnahan, Rich C.

    2015-10-21

    Utilizing a modified nitrogen plasma source, plasma assisted molecular beam epitaxy (PAMBE) has been used to achieve higher growth rates in GaN. A higher conductance aperture plate, combined with higher nitrogen flow and added pumping capacity, resulted in dramatically increased growth rates up to 8.4 μm/h using 34 sccm of N{sub 2} while still maintaining acceptably low operating pressure. It was further discovered that argon could be added to the plasma gas to enhance growth rates up to 9.8 μm/h, which was achieved using 20 sccm of N{sub 2} and 7.7 sccm Ar flows at 600 W radio frequency power, for which the standard deviation of thickness was just 2% over a full 2 in. diameter wafer. A remote Langmuir style probe employing the flux gauge was used to indirectly measure the relative ion content in the plasma. The use of argon dilution at low plasma pressures resulted in a dramatic reduction of the plasma ion current by more than half, while high plasma pressures suppressed ion content regardless of plasma gas chemistry. Moreover, different trends are apparent for the molecular and atomic nitrogen species generated by varying pressure and nitrogen composition in the plasma. Argon dilution resulted in nearly an order of magnitude achievable growth rate range from 1 μm/h to nearly 10 μm/h. Even for films grown at more than 6 μm/h, the surface morphology remained smooth showing clear atomic steps with root mean square roughness less than 1 nm. Due to the low vapor pressure of Si, Ge was explored as an alternative n-type dopant for high growth rate applications. Electron concentrations from 2.2 × 10{sup 16} to 3.8 × 10{sup 19} cm{sup −3} were achieved in GaN using Ge doping, and unintentionally doped GaN films exhibited low background electron concentrations of just 1–2 × 10{sup 15} cm{sup −3}. The highest growth rates resulted in macroscopic surface features due to Ga cell spitting, which is an engineering challenge still to be

  18. Control of ion content and nitrogen species using a mixed chemistry plasma for GaN grown at extremely high growth rates >9 μm/h by plasma-assisted molecular beam epitaxy

    NASA Astrophysics Data System (ADS)

    Gunning, Brendan P.; Clinton, Evan A.; Merola, Joseph J.; Doolittle, W. Alan; Bresnahan, Rich C.

    2015-10-01

    Utilizing a modified nitrogen plasma source, plasma assisted molecular beam epitaxy (PAMBE) has been used to achieve higher growth rates in GaN. A higher conductance aperture plate, combined with higher nitrogen flow and added pumping capacity, resulted in dramatically increased growth rates up to 8.4 μm/h using 34 sccm of N2 while still maintaining acceptably low operating pressure. It was further discovered that argon could be added to the plasma gas to enhance growth rates up to 9.8 μm/h, which was achieved using 20 sccm of N2 and 7.7 sccm Ar flows at 600 W radio frequency power, for which the standard deviation of thickness was just 2% over a full 2 in. diameter wafer. A remote Langmuir style probe employing the flux gauge was used to indirectly measure the relative ion content in the plasma. The use of argon dilution at low plasma pressures resulted in a dramatic reduction of the plasma ion current by more than half, while high plasma pressures suppressed ion content regardless of plasma gas chemistry. Moreover, different trends are apparent for the molecular and atomic nitrogen species generated by varying pressure and nitrogen composition in the plasma. Argon dilution resulted in nearly an order of magnitude achievable growth rate range from 1 μm/h to nearly 10 μm/h. Even for films grown at more than 6 μm/h, the surface morphology remained smooth showing clear atomic steps with root mean square roughness less than 1 nm. Due to the low vapor pressure of Si, Ge was explored as an alternative n-type dopant for high growth rate applications. Electron concentrations from 2.2 × 1016 to 3.8 × 1019 cm-3 were achieved in GaN using Ge doping, and unintentionally doped GaN films exhibited low background electron concentrations of just 1-2 × 1015 cm-3. The highest growth rates resulted in macroscopic surface features due to Ga cell spitting, which is an engineering challenge still to be addressed. Nonetheless, the dramatically enhanced growth rates demonstrate

  19. Sound production by a recoiling system in the pempheridae and terapontidae.

    PubMed

    Parmentier, Eric; Fine, Michael L; Mok, Hin-Kiu

    2016-06-01

    Sound-producing mechanisms in fishes are extraordinarily diversified. We report here original mechanisms of three species from two families: the pempherid Pempheris oualensis, and the terapontids Terapon jarbua and Pelates quadrilineatus. All sonic mechanisms are built on the same structures. The rostral part of the swimbladder is connected to a pair of large sonic muscles from the head whereas the posterior part is fused with bony widenings of vertebral bodies. Two bladder regions are separated by a stretchable fenestra that allows forward extension of the anterior bladder during muscle contraction. A recoiling apparatus runs between the inner face of the anterior swimbladder and a vertebral body expansion. The elastic nature of the recoiling apparatus supports its role in helping the swimbladder to recover its initial position during sonic muscle relaxation. This system should aid fast contraction (between 100 and 250Hz) of sonic muscles. There are many differences between species in terms of the swimbladder and its attachments to the vertebral column, muscle origins, and morphology of the recoiling apparatus. The recoiling apparatus found in the phylogenetically-related families (Glaucosomatidae, Pempheridae, Terapontidae) could indicate a new character within the Percomorpharia. J. Morphol. 277:717-724, 2016. © 2016 Wiley Periodicals, Inc.

  20. Modeling ionization and recombination from low energy nuclear recoils in liquid argon

    NASA Astrophysics Data System (ADS)

    Foxe, M.; Hagmann, C.; Jovanovic, I.; Bernstein, A.; Joshi, T. H.; Kazkaz, K.; Mozin, V.; Pereverzev, S. V.; Sangiorgio, S.; Sorensen, P.

    2015-09-01

    Coherent elastic neutrino-nucleus scattering (CENNS) is an as-yet undetected, flavor-independent neutrino interaction predicted by the Standard Model. Detection of CENNS could offer benefits for detection of supernova and solar neutrinos in astrophysics, or for detection of antineutrinos for nuclear reactor monitoring and nuclear nonproliferation. One challenge with detecting CENNS is the low energy deposition associated with a typical CENNS nuclear recoil. In addition, nuclear recoils result in lower ionization yields than those produced by electron recoils of the same energy. While a measurement of the nuclear recoil ionization yield in liquid argon in the keV energy range has been recently reported, a corresponding model for low-energy ionization yield in liquid argon does not exist. For this reason, a Monte Carlo simulation has been developed to predict the ionization yield at sub-10 keV energies. The model consists of two distinct components: (1) simulation of the atomic collision cascade with production of ionization, and (2) the thermalization and drift of ionization electrons in an applied electric field including local recombination. As an application of our results we report updated estimates of detectable ionization in liquid argon from CENNS at a nuclear reactor.

  1. Measurement of Nuclear Recoils in the CDMS II Dark Matter Search

    SciTech Connect

    Fallows, Scott Mathew

    2014-12-01

    The Cryogenic Dark Matter Search (CDMS) experiment is designed to directly detect elastic scatters of weakly-interacting massive dark matter particles (WIMPs), on target nuclei in semiconductor crystals composed of Si and Ge. These scatters would occur very rarely, in an overwhelming background composed primarily of electron recoils from photons and electrons, as well as a smaller but non-negligible background of WIMP-like nuclear recoils from neutrons. The CDMS II generation of detectors simultaneously measure ionization and athermal phonon signals from each scatter, allowing discrimination against virtually all electron recoils in the detector bulk. Pulse-shape timing analysis allows discrimination against nearly all remaining electron recoils taking place near detector surfaces. Along with carefully limited neutron backgrounds, this experimental program allowed for \\background- free" operation of CDMS II at Soudan, with less than one background event expected in each WIMP-search analysis. As a result, exclusionary upper-limits on WIMP-nucleon interaction cross section were placed over a wide range of candidate WIMP masses, ruling out large new regions of parameter space.

  2. Mass calibration of the energy axis in ToF-E elastic recoil detection analysis

    NASA Astrophysics Data System (ADS)

    Meersschaut, J.; Laricchiuta, G.; Sajavaara, T.; Vandervorst, W.

    2016-03-01

    We report on procedures that we have developed to mass-calibrate the energy axis of ToF-E histograms in elastic recoil detection analysis. The obtained calibration parameters allow one to transform the ToF-E histogram into a calibrated ToF-M histogram.

  3. Complete and incomplete fusion reactions in the {sup 16}O+{sup 169}Tm system: Excitation functions and recoil range distributions

    SciTech Connect

    Sharma, Manoj Kumar; Unnati,; Sharma, B.K.; Singh, B.P.; Prasad, R.; Bhardwaj, H.D.; Kumar, Rakesh; Golda, K.S.

    2004-10-01

    With the view to study complete and incomplete fusion in heavy ion induced reactions, experiments have been carried out for measuring excitation functions for several reactions in the system {sup 16}O+{sup 169}Tm at energies near the Coulomb barrier to well above it, using an activation technique. The measured excitation functions have been compared with those calculated theoretically using three different computer codes viz., ALICE-91, CASCADE and PACE2. The enhancement of experimentally measured cross sections for alpha emission channels over their theoretical prediction has been attributed to the fact that these residues are formed not only by complete fusion but also through incomplete fusion. In order to separate out the relative contributions of complete and incomplete fusion, the recoil range distributions of eight residues produced in the interaction of {sup 16}O with {sup 169}Tm at {approx_equal}87 MeV have been measured. The recoil range distributions indicate significant contributions from incomplete fusion at {approx_equal}87 MeV for some of the channels.

  4. Constraints on the Nature of CID-42: Recoil Kick or Supermassive Black Hole Pair?

    NASA Technical Reports Server (NTRS)

    Blecha, Laura; Civano, Francesca; Elvis, Martin; Loeb, Abraham

    2012-01-01

    The galaxy CXOC J100043.1+020637, also known as CID-42, is a highly unusual object. An apparent galaxy merger remnant, it displays signatures of both an inspiraling, kiloparsecscale active galactic nucleus (AGN) pair and of a recoiling AGN with a kick velocity approximately greater than 1300 km s(exp -1). Among recoiling AGN candidates, CID-42 alone has both spatial offsets (in optical and X-ray bands) and spectroscopic offsets. In order to constrain the relative likelihood of both scenarios, we develop models using hydrodynamic galaxy merger simulations coupled with radiative transfer calculations. Our gas-rich, major merger models are generally well matched to the galactic morphology and to the inferred stellar mass and star formation rate. We show that a recoiling supermassive black hole (SMBH) in CID-42 should be observable as an AGN at the time of observation. However, in order for the recoiling AGN to produce narrow-line emission, it must be observed shortly after the kick while it still inhabits a dense gaseous region, implying a large total kick velocity (vk approximately greater than 2000 km s(exp -1)). For the dual AGN scenario, an unusually large broad-line offset is required, and the best match to the observed morphology requires a galaxy that is less luminous than CID-42. Further, the lack of X-ray emission from one of the two optical nuclei is not easily attributed to an intrinsically quiescent SMBH or to a Compton-thick galactic environment. While the current data do not allow either the recoiling or the dual AGN scenario for CID-42 to be excluded, our models highlight the most relevant parameters for distinguishing these possibilities with future observations. In particular, high-quality, spatially-resolved spectra that can pinpoint the origin of the broad and narrow line features will be critical for determining the nature of this unique source.

  5. Gravitational Recoil of Inspiraling Black Hole Binaries to Second Post-Newtonian Order

    NASA Astrophysics Data System (ADS)

    Blanchet, Luc; Qusailah, Moh'd. S. S.; Will, Clifford M.

    2005-12-01

    The loss of linear momentum by gravitational radiation and the resulting gravitational recoil of black hole binary systems may play an important role in the growth of massive black holes in early galaxies. We calculate the gravitational recoil of nonspinning black hole binaries at the second post-Newtonian order (2 PN) beyond the dominant effect, obtaining, for the first time, the 1.5 PN correction term due to tails of waves and the next 2 PN term. We find that the maximum value of the net recoil experienced by the binary due to the inspiral phase up to the innermost stable circular orbit (ISCO) is of the order of 22 km s-1. We then estimate the kick velocity accumulated during the plunge from the ISCO up to the horizon by integrating the momentum flux using the 2 PN formula along a plunge geodesic of the Schwarzschild metric. We find that the contribution of the plunge dominates over that of the inspiral. For a mass ratio m2/m1=1/8, we estimate a total recoil velocity (due to both adiabatic and plunge phases) of 100+/-20 km s-1. For a ratio of 0.38, the recoil is maximum, and we estimate it to be 250+/-50 km s-1. In the limit of small mass ratio, we estimate V/c~0.043(+/-20%)(m2/m1)2. Our estimates are consistent with, but span a substantially narrower range than, those of Favata and coworkers.

  6. Modeling ionization and recombination from low energy nuclear recoils in liquid argon

    SciTech Connect

    Foxe, Michael P.; Hagmann, Chris; Jovanovic, Igor; Bernstein, A.; Joshi, T.; Kazkaz, K.; Mozin, Vladimir V.; Pereverzev, S. V.; Sangiorgio, Samuele; Sorensen, Peter F.

    2015-09-01

    Coherent neutrino-nucleus scattering (CNNS) is an as-yet undetected, flavor-independent neutrino interaction predicted by the Standard Model. CNNS is a flavor-blind interaction, which offers potential benefits for its use in nonproliferation (nuclear reactor monitoring) and astrophysics (supernova and solar neutrinos) applications. One challenge with detecting CNNS is the low energy deposition associated with a typical CNNS nuclear recoil. In addition, nuclear recoils are predicted to result in lower ionization yields than those produced by electron recoils of the same energy. This ratio of nuclear- and electron-induced ionization, known as the nuclear quenching factor, is unknown at energies typical for CNNS interactions in liquid xenon (LXe) and liquid argon (LAr), detector media being considered for CNNS detection. While there have been recent measurements [1] of the ionization yield from nuclear recoils in LAr, there is no universal model for nuclear quenching and ionization yield. For this reason, a Monte Carlo simulation has been developed to predict the ionization yield at sub-10 keV energies. The local ionization yield of a recoiling atom in the medium is calculated first. The ejected electrons are subsequently tracked in the electric field resulting from both the local electric charges and the externally applied drift field. The dependence of the ionization yield on the drift electric field is obtained by combining the calculated ionization yield for the initial collision cascade with the electron escape probability. An updated estimate of the CNNS signal expected in a LAr detector operated near a nuclear power reactor is presented.

  7. MucR Is Required for Transcriptional Activation of Conserved Ion Transporters to Support Nitrogen Fixation of Sinorhizobium fredii in Soybean Nodules.

    PubMed

    Jiao, Jian; Wu, Li Juan; Zhang, Biliang; Hu, Yue; Li, Yan; Zhang, Xing Xing; Guo, Hui Juan; Liu, Li Xue; Chen, Wen Xin; Zhang, Ziding; Tian, Chang Fu

    2016-05-01

    To achieve effective symbiosis with legume, rhizobia should fine-tune their background regulation network in addition to activating key genes involved in nodulation (nod) and nitrogen fixation (nif). Here, we report that an ancestral zinc finger regulator, MucR1, other than its paralog, MucR2, carrying a frameshift mutation, is essential for supporting nitrogen fixation of Sinorhizobium fredii CCBAU45436 within soybean nodules. In contrast to the chromosomal mucR1, mucR2 is located on symbiosis plasmid, indicating its horizontal transfer potential. A MucR2 homolog lacking the frameshift mutation, such as the one from S. fredii NGR234, can complement phenotypic defects of the mucR1 mutant of CCBAU45436. RNA-seq analysis revealed that the MucR1 regulon of CCBAU45436 within nodules exhibits significant difference compared with that of free-living cells. MucR1 is required for active expression of transporters for phosphate, zinc, and elements essential for nitrogenase activity (iron, molybdenum, and sulfur) in nodules but is dispensable for transcription of key genes (nif/fix) involved in nitrogen fixation. Further reverse genetics suggests that S. fredii uses high-affinity transporters to meet the demand for zinc and phosphate within nodules. These findings, together with the horizontal transfer potential of the mucR homolog, imply an intriguing evolutionary role of this ancestral regulator in supporting nitrogen fixation.

  8. Probing high areal-density cryogenic deuterium-tritium implosions using downscattered neutron spectra measured by the magnetic recoil spectrometera)

    NASA Astrophysics Data System (ADS)

    Frenje, J. A.; Casey, D. T.; Li, C. K.; Séguin, F. H.; Petrasso, R. D.; Glebov, V. Yu.; Radha, P. B.; Sangster, T. C.; Meyerhofer, D. D.; Hatchett, S. P.; Haan, S. W.; Cerjan, C. J.; Landen, O. L.; Fletcher, K. A.; Leeper, R. J.

    2010-05-01

    For the first time high areal-density (ρR) cryogenic deuterium-tritium (DT) implosions have been probed using downscattered neutron spectra measured with the magnetic recoil spectrometer (MRS) [J. A. Frenje et al., Rev. Sci. Instrum. 79, 10E502 (2008)], recently installed and commissioned on OMEGA [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. The ρR data obtained with the MRS have been essential for understanding how the fuel is assembled and for guiding the cryogenic program at the Laboratory for Laser Energetics (LLE) to ρR values up to ˜300 mg/cm2. The ρR data obtained from well-established charged particle spectrometry techniques [C. K. Li et al., Phys. Plasmas 8, 4902 (2001)] were used to authenticate the MRS data for low-ρR plastic capsule implosions, and the ρR values inferred from these techniques are in excellent agreement, indicating that the MRS technique provides high-fidelity data. Recent OMEGA-MRS data and Monte Carlo simulations have shown that the MRS on the NIF [G. H. Miller et al., Nucl. Fusion 44, S228 (2004)] will meet most of the absolute and relative requirements for determining ρR, ion temperature (Ti) and neutron yield (Yn) in both low-yield, tritium-rich, deuterium-lean, hydrogen-doped implosions and high-yield DT implosions.

  9. Integral cross section measurements and product recoil velocity distributions of Xe(2+) + N2 hyperthermal charge-transfer collisions.

    PubMed

    Hause, Michael L; Prince, Benjamin D; Bemish, Raymond J

    2016-07-28

    Charge exchange from doubly charged rare gas cations to simple diatomics proceeds with a large cross section and results in populations of many vibrational and electronic product states. The charge exchange between Xe(2+) and N2, in particular, is known to create N2 (+) in both the A and B electronic states. In this work, we present integral charge exchange cross section measurements of the Xe(2+) + N2 reaction as well as axial recoil velocity distributions of the Xe(+) and N2 (+) product ions for collision energies between 0.3 and 100 eV in the center-of-mass (COM) frame. Total charge-exchange cross sections decrease from 70 Å(2) to about 40 Å(2) with increasing collision energy through this range. Analysis of the axial velocity distributions indicates that a Xe(2+) - N2 complex exists at low collision energies but is absent by 17.6 eV COM. Analysis of the axial velocity distributions reveals evidence for complexes with lifetimes comparable to the rotational period at low collision energies. The velocity distributions are consistent with quasi-resonant single charge transfer at high collision energies. PMID:27475363

  10. Integral cross section measurements and product recoil velocity distributions of Xe2+ + N2 hyperthermal charge-transfer collisions

    NASA Astrophysics Data System (ADS)

    Hause, Michael L.; Prince, Benjamin D.; Bemish, Raymond J.

    2016-07-01

    Charge exchange from doubly charged rare gas cations to simple diatomics proceeds with a large cross section and results in populations of many vibrational and electronic product states. The charge exchange between Xe2+ and N2, in particular, is known to create N2 + in both the A and B electronic states. In this work, we present integral charge exchange cross section measurements of the Xe2+ + N2 reaction as well as axial recoil velocity distributions of the Xe+ and N2 + product ions for collision energies between 0.3 and 100 eV in the center-of-mass (COM) frame. Total charge-exchange cross sections decrease from 70 Å2 to about 40 Å2 with increasing collision energy through this range. Analysis of the axial velocity distributions indicates that a Xe2+ - N2 complex exists at low collision energies but is absent by 17.6 eV COM. Analysis of the axial velocity distributions reveals evidence for complexes with lifetimes comparable to the rotational period at low collision energies. The velocity distributions are consistent with quasi-resonant single charge transfer at high collision energies.

  11. NiCo2S4 nanotube arrays grown on flexible nitrogen-doped carbon foams as three-dimensional binder-free integrated anodes for high-performance lithium-ion batteries.

    PubMed

    Wu, Xiaoyu; Li, Songmei; Wang, Bo; Liu, Jianhua; Yu, Mei

    2016-02-14

    Binary metal sulfides, especially NiCo2S4, hold great promise as anode materials for high-performance lithium-ion batteries because of their excellent electronic conductivity and high capacity compared to mono-metal sulfides and oxides. Here, NiCo2S4 nanotube arrays are successfully grown on flexible nitrogen-doped carbon foam (NDCF) substrates with robust adhesion via a facile surfactant-assisted hydrothermal route and the subsequent sulfurization treatment. The obtained NiCo2S4/NDCF composites show unique three-dimensional architectures, in which NiCo2S4 nanotubes of ∼5 μm in length and 100 nm in width are uniformly grown on the NDCF skeletons to form arrays. When used directly as integrated anodes for lithium-ion batteries without any conductive additives and binders, the NiCo2S4/NDCF composites exhibit a high reversible capacity of 1721 mA h g(-1) at a high current density of 500 mA g(-1), enhanced cycling performance with the capacity maintained at 1182 mA h g(-1) after 100 cycles, and a remarkable rate capability. The excellent lithium storage performances of the composites could be attributed to the unique material composition, a rationally designed hollow nanostructure and an integrated smart architecture, which offer fast electron transport and ion diffusion, enhanced material/-electrolyte contact area and facile accommodation of strains during the lithium insertion and extraction process.

  12. On a cryogenic noble gas ion catcher

    NASA Astrophysics Data System (ADS)

    Dendooven, P.; Purushothaman, S.; Gloos, K.

    2006-03-01

    In situ purification of the gas used as stopping medium in a noble gas ion catcher by operating the device at low temperatures of 60-150 K was investigated. Alpha-decay recoil ions from a 223Ra source served as energetic probes. The combined ion survival and transport efficiencies for 219Rn ions saturated below about 90 K, reaching 28.7(17)% in helium, 22.1(13)% in neon, and 17.0(10)% in argon. These values may well reflect the charge exchange and stripping cross-sections during the slowing down of the ions, and thus represent a fundamental upper limit for the efficiency of noble gas ion catcher devices. We suggest the cryogenic noble gas ion catcher as a technically simpler alternative to the ultra-high purity noble gas ion catcher operating at room temperature.

  13. Profiling of semiconductor surface layers by heavy ion TOF-E-ERD

    NASA Astrophysics Data System (ADS)

    Arai, E.; Zounek, A.; Saito, K.

    1993-06-01

    We have adapted the elastic recoil detection (ERD) technique to analyse passivation layers of Si xN yO 1- x- y grown on Si substrates in low pressure CVD process. Sample targets were bombarded by 9.87 MeV 35Cl ions to recoil Si, O, N and C atoms incorporated in the sample film. The atomic species of recoils have been identified through eventwise registration of flight time (TOF) and kinetic energy ( E). Using an unfolding program developed by Bachmann the depth profile for each element has been calculated from the TOF energy spectrum. The unfolding program is based on an iterative algorithm that takes into account the interplay between the stopping of projectiles as well as recoils and the stoichiometry of the sample. The chemical composition as a function of depth is discussed in the context of sample preparation conditions.

  14. Enhanced visible-light absorption of mesoporous TiO2 by co-doping with transition-metal/nitrogen ions

    SciTech Connect

    Mathis, John; Bi, Zhonghe; Bridges, Craig A; Kidder, Michelle; Paranthaman, Mariappan Parans

    2013-01-01

    Titanium (IV) oxide, TiO2, has been the object of intense scrutiny for energy applications. TiO2 is inexpensive, non-toxic, and has excellent corrosion resistance when exposed to electrolytes. A major drawback preventing the widespread use TiO2 for photolysis is its relatively large band gap of ~3eV. Only light with wavelengths shorter than 400 nm, which is in the ultraviolet portion of the spectrum, has sufficient energy to be absorbed. Less than 14 percent of the solar irradiation reaching the earth s surface has energy exceeding this band gap. Adding dopants such as transition metals has long been used to reduce the gap and increase photocatalytic activity by accessing the visible part of the solar spectrum. The degree to which the band gap is reduced using transition metals depends in part on the overlap of the d-orbitals of the transition metals with the oxygen p-orbitals. Therefore, doping with anions such as nitrogen to modify the cation-anion orbital overlap is another approach to reduce the gap. Recent studies suggest that using a combination of transition metals and nitrogen as dopants is more effective at introducing intermediate states within the band gap, effectively narrowing it. Here we report the synthesis of mesoporous TiO2 spheres, co-doped with transition metals and nitrogen that exhibit a nearly flat absorbance response across the visible spectrum extending into the near infrared.

  15. Atomistic Simulation of Track Formation by Energetic Recoils in Zircon

    SciTech Connect

    Moreira, Pedro A.; Devanathan, Ramaswami; Weber, William J.

    2010-09-17

    We have performed classical molecular dynamics simulations of fission track formation in zircon. We simulated the passage of a swift heavy ion through crystalline zircon using cylindrical thermal spikes with energy deposition (dE/dx) of 2.5 to 12.8 keV/nm and radius of 3 nm. At a low dE/dx of 2.55 keV/nm, the structural damage recovered almost completely and a damage track was not produced. At higher values of dE/dx, tracks were observed and the radius of the track increased with increasing dE/dx. Our structural analysis shows amorphization in the core of the track and phase separation into Si-rich regions near the center of the track and Zr-rich regions near the periphery. These simulations establish a threshold dE/dx for fission-track formation in zircon that is relevant to thermo-chronology and nuclear waste immobilization.

  16. Recoil Polarization and Beam-Recoil Double Polarization Measurement of {eta} Electroproduction on the Proton in the Region of the S{sub 11}(1535) Resonance

    SciTech Connect

    Merkel, H.; Achenbach, P.; Ayerbe Gayoso, C.; Bernauer, J. C.; Boehm, R.; Distler, M. O.; Doria, L.; Friedrich, J.; Mueller, U.; Nungesser, L.; Pochodzalla, J.; Sanchez Majos, S.; Schlimme, B. S.; Tiator, L.; Walcher, Th.; Weinriefer, M.; Bosnar, D.; Makek, M.; Cheymol, B.; Fonvieille, H.

    2007-09-28

    The beam-recoil double polarization P{sub x{sup '}}{sup h} and P{sub z{sup '}}{sup h} and the recoil polarization P{sub y{sup '}} were measured for the first time for the p(e-vector,e{sup '}p-vector){eta} reaction at a four-momentum transfer of Q{sup 2}=0.1 GeV{sup 2}/c{sup 2} and a center of mass production angle of {theta}=120 deg. at the Mainz Microtron MAMI-C. With a center of mass energy range of 1500 MeV

  17. A coherent understanding of low-energy nuclear recoils in liquid xenon

    SciTech Connect

    Sorensen, Peter

    2010-09-01

    Liquid xenon detectors such as XENON10 and XENON100 obtain a significant fraction of their sensitivity to light (∼<10 GeV) particle dark matter by looking for nuclear recoils of only a few keV, just above the detector threshold. Yet in this energy regime a correct treatment of the detector threshold and resolution remains unclear. The energy dependence of the scintillation yield of liquid xenon for nuclear recoils also bears heavily on detector sensitivity, yet numerous measurements have not succeeded in obtaining concordant results. In this article we show that the ratio of detected ionization to scintillation can be leveraged to constrain the scintillation yield. We also present a rigorous treatment of liquid xenon detector threshold and energy resolution. Notably, the effective energy resolution differs significantly from a simple Poisson distribution. We conclude with a calculation of dark matter exclusion limits, and show that existing data from liquid xenon detectors strongly constrain recent interpretations of light dark matter.

  18. Low energy electron/recoil discrimination for directional Dark Matter detection

    SciTech Connect

    Billard, J.; Mayet, F.; Santos, D. E-mail: mayet@lpsc.in2p3.fr

    2012-07-01

    Directional detection is a promising Dark Matter search strategy. Even though it could accommodate to a sizeable background contamination, electron/recoil discrimination remains a key and challenging issue as for direction-insensitive detectors. The measurement of the 3D track may be used to discriminate electrons from nuclear recoils. While a high rejection power is expected above 20 keV ionization, a dedicated data analysis is needed at low energy. After identifying discriminant observables, a multivariate analysis, namely a Boosted Decision Tree, is proposed, enabling an efficient event tagging for Dark Matter search. We show that it allows us to optimize rejection while keeping a rather high efficiency which is compulsory for rare event search.With respect to a sequential analysis, the rejection is about ∼ 20 times higher with a multivariate analysis, for the same Dark Matter exclusion limit.

  19. Development of bubble chambers with enhanced stability and sensitivity to low-energy nuclear recoils

    SciTech Connect

    Bolte, W.J.; Collar, Juan I.; Crisler, M.; Hall, J.; Holmgren, D.; Nakazawa, D.; Odom, B.; O'Sullivan, K.; Plunkett, R.; Ramberg, E.; Raskin, A.; Sonnenschein, A.; Vieira, J.D.; /Chicago U., EFI /KICP, Chicago /Fermilab

    2005-03-01

    The viability of using a Bubble Chamber for rare event searches and in particular for the detection of dark matter particle candidates is considered. Techniques leading to the deactivation of inhomogeneous nucleation centers and subsequent enhanced stability in such a detector are described. Results from prototype trials indicate that sensitivity to low-energy nuclear recoils like those expected from Weakly Interacting Massive Particles can be obtained in conditions of near total insensitivity to minimum ionizing backgrounds. An understanding of the response of superheated heavy refrigerants to these recoils is demonstrated within the context of existing theoretical models. We comment on the prospects for the detection of supersymmetric dark matter particles with a large CF{sub 3}I chamber.

  20. Black hole as a point radiator and recoil effect on the brane world.

    PubMed

    Frolov, Valeri; Stojković, Dejan

    2002-10-01

    A small black hole attached to a brane in a higher-dimensional space emitting quanta into the bulk may leave the brane as a result of a recoil. We construct a field theory model in which such a black hole is described as a massive scalar particle with internal degrees of freedom. In this model, the probability of transition between the different internal levels is identical to the probability of thermal emission calculated for the Schwarzschild black hole. The discussed recoil effect implies that the thermal emission of the black holes, which might be created by interaction of high energy particles in colliders, could be terminated and the energy nonconservation can be observed in the brane experiments.

  1. Recoil excitation of vibrational structure in the carbon 1s photoelectron spectrum of CF4.

    PubMed

    Thomas, T Darrah; Kukk, Edwin; Sankari, Rami; Fukuzawa, Hironobu; Prümper, Georg; Ueda, Kiyoshi; Püttner, Ralph; Harries, James; Tamenori, Yusuke; Tanaka, Takahiro; Hoshino, Masamitsu; Tanaka, Hiroshi

    2008-04-14

    The carbon 1s photoelectron spectrum of CF4 measured at photon energies from 330 to 1500 eV shows significant contributions from nonsymmetric vibrational modes. These increase linearly as the photon energy increases. The excitation of these modes, which is not predicted in the usual Franck-Condon point of view, arises from the recoil momentum imparted to the carbon atom in the ionization process. A theory is presented for quantitative prediction of the recoil effect; the predictions of this theory are in agreement to the measurements. The experiments also yield the vibrational frequencies of the symmetric and asymmetric stretching modes in core-ionized CF4, the change in CF bond length upon ionization, -0.61 pm, and the Lorentzian linewidth of the carbon 1s hole, 67 meV.

  2. A coherent understanding of low-energy nuclear recoils in liquid xenon

    NASA Astrophysics Data System (ADS)

    Sorensen, Peter

    2010-09-01

    Liquid xenon detectors such as XENON10 and XENON100 obtain a significant fraction of their sensitivity to light (lesssim10 GeV) particle dark matter by looking for nuclear recoils of only a few keV, just above the detector threshold. Yet in this energy regime a correct treatment of the detector threshold and resolution remains unclear. The energy dependence of the scintillation yield of liquid xenon for nuclear recoils also bears heavily on detector sensitivity, yet numerous measurements have not succeeded in obtaining concordant results. In this article we show that the ratio of detected ionization to scintillation can be leveraged to constrain the scintillation yield. We also present a rigorous treatment of liquid xenon detector threshold and energy resolution. Notably, the effective energy resolution differs significantly from a simple Poisson distribution. We conclude with a calculation of dark matter exclusion limits, and show that existing data from liquid xenon detectors strongly constrain recent interpretations of light dark matter.

  3. A simplified version of the total Kjeldahl nitrogen method using an ammonia extraction ultrasound-assisted purge-and-trap system and ion chromatography for analyses of geological samples.

    PubMed

    Pontes, Fernanda V M; Carneiro, Manuel C; Vaitsman, Delmo S; da Rocha, Genilda P; da Silva, Lílian I D; Neto, Arnaldo A; Monteiro, Maria Inês C

    2009-01-26

    The total Kjeldahl nitrogen (TKN) method was simplified by using a manifold connected to a purge-and-trap system immersed into an ultrasonic (US) bath for simultaneous ammonia (NH(3)) extraction from many previously digested samples. Then, ammonia was collected in an acidic solution, converted to ammonium (NH(4)(+)), and finally determined by ion chromatography method. Some variables were optimized, such as ultrasonic irradiation power and frequency, ultrasound-assisted NH(3) extraction time, NH(4)(+) mass and sulfuric acid concentration added to the NH(3) collector flask. Recovery tests revealed no changes in the pH values and no conversion of NH(4)(+) into other nitrogen species during the irradiation of NH(4)Cl solutions with 25 or 40 kHz ultrasonic waves for up to 20 min. Sediment and oil free sandstone samples and soil certified reference materials (NCS DC 73319, NCS DC 73321 and NCS DC 73326) with different total nitrogen concentrations were analysed. The proposed method is faster, simpler and more sensitive than the classical Kjeldahl steam distillation method. The time for NH(3) extraction by the US-assisted purge-and-trap system (20 min) was half of that by the Kjeldahl steam distillation (40 min) for 10 previously digested samples. The detection limit was 9 microg g(-1)N, while for the Kjeldahl classical/indophenol method was 58 microg g(-1)N. Precision was always better than 13%. In the proposed method, carcinogenic reagents are not used, contrarily to the indophenol method. Furthermore, the proposed method can be adapted for fixed-NH(4)(+) determination.

  4. One-pot green synthesis of oxygen-rich nitrogen-doped graphene quantum dots and their potential application in pH-sensitive photoluminescence and detection of mercury(II) ions.

    PubMed

    Shi, Bingfang; Zhang, Liangliang; Lan, Chuanqing; Zhao, Jingjin; Su, Yubin; Zhao, Shulin

    2015-09-01

    Nitrogen doping has been a powerful method to modulate the properties of carbon materials for various applications, and N-doped graphene quantum dots (GQDs) have gained remarkable interest because of their unique chemical, electronic, and optical properties. Herein, we introduce a facile one-pot solid-phase synthesis strategy for N-doped GQDs using citric acid (CA) as the carbon source and 3,4-dihydroxy-L-phenylalanine (L-DOPA) as the N source. The as-prepared N-GQDs with oxygen-rich functional groups are uniform with an average diameter of 12.5 nm. Because of the introduction of nitrogen atoms, N-GQDs exhibit excitation-wavelength-independent fluorescence with the maximum emission at 445 nm, and a high quantum yield of 18% is achieved at an excitation wavelength of 346 nm. Furthermore, a highly efficient fluorosensor based on the as-prepared N-GQDs was developed for the detection of Hg(2+) because of the effective quenching effect of metal ions via nonradiative electron transfer. This fluorosensor exhibits high sensitivity toward Hg(2+) with a detection limit of 8.6 nM. The selectivity experiments reveal that the fluorescent sensor is specific for Hg(2+). Most importantly, the practical use of the sensor based on N-GQDs for Hg(2+) detection was successfully demonstrated in river-water samples. PMID:26003702

  5. One-pot green synthesis of oxygen-rich nitrogen-doped graphene quantum dots and their potential application in pH-sensitive photoluminescence and detection of mercury(II) ions.

    PubMed

    Shi, Bingfang; Zhang, Liangliang; Lan, Chuanqing; Zhao, Jingjin; Su, Yubin; Zhao, Shulin

    2015-09-01

    Nitrogen doping has been a powerful method to modulate the properties of carbon materials for various applications, and N-doped graphene quantum dots (GQDs) have gained remarkable interest because of their unique chemical, electronic, and optical properties. Herein, we introduce a facile one-pot solid-phase synthesis strategy for N-doped GQDs using citric acid (CA) as the carbon source and 3,4-dihydroxy-L-phenylalanine (L-DOPA) as the N source. The as-prepared N-GQDs with oxygen-rich functional groups are uniform with an average diameter of 12.5 nm. Because of the introduction of nitrogen atoms, N-GQDs exhibit excitation-wavelength-independent fluorescence with the maximum emission at 445 nm, and a high quantum yield of 18% is achieved at an excitation wavelength of 346 nm. Furthermore, a highly efficient fluorosensor based on the as-prepared N-GQDs was developed for the detection of Hg(2+) because of the effective quenching effect of metal ions via nonradiative electron transfer. This fluorosensor exhibits high sensitivity toward Hg(2+) with a detection limit of 8.6 nM. The selectivity experiments reveal that the fluorescent sensor is specific for Hg(2+). Most importantly, the practical use of the sensor based on N-GQDs for Hg(2+) detection was successfully demonstrated in river-water samples.

  6. Recoil velocity at second post-Newtonian order for spinning black hole binaries

    NASA Astrophysics Data System (ADS)

    Racine, Étienne; Buonanno, Alessandra; Kidder, Larry

    2009-08-01

    We compute the flux of linear momentum carried by gravitational waves emitted from spinning binary black holes at second post-Newtonian (2PN) order for generic orbits. In particular we provide explicit expressions of three new types of terms, namely, next-to-leading order spin-orbit terms at 1.5 post-Newtonian (1.5PN) order, spin-orbit tail terms at 2PN order, and spin-spin terms at 2PN order. Restricting ourselves to quasicircular orbits, we integrate the linear-momentum flux over time to obtain the recoil velocity as function of orbital frequency. We find that in the so-called superkick configuration the higher-order spin corrections can increase the recoil velocity up to a factor ˜3 with respect to the leading-order PN prediction. Whereas the recoil velocity computed in PN theory within the adiabatic approximation can accurately describe the early inspiral phase, we find that its fast increase during the late inspiral and plunge, and the arbitrariness in determining until when it should be trusted, makes the PN predictions for the total recoil not very accurate and robust. Nevertheless, the linear-momentum flux at higher PN orders can be employed to build more reliable resummed expressions aimed at capturing the nonperturbative effects until merger. Furthermore, we provide expressions valid for generic orbits, and accurate at 2PN order, for the energy and angular momentum carried by gravitational waves emitted from spinning binary black holes. Specializing to quasicircular orbits we compute the spin-spin terms at 2PN order in the expression for the evolution of the orbital frequency and found agreement with Mikóczi, Vasúth, and Gergely. We also verified that in the limit of extreme mass ratio our expressions for the energy and angular momentum fluxes match the ones of Tagoshi, Shibata, Tanaka, and Sasaki obtained in the context of black hole perturbation theory.

  7. Lifetimes in neutron-rich fission fragments using the differential recoil distance method

    SciTech Connect

    Kruecken, R.; Chou, W.-T.; Cooper, J. R.; Beausang, C. W.; Barton, C. J.; Caprio, M. A.; Casten, R. F.; Hecht, A. A.; Novak, J. R.; Pietralla, N.

    2001-07-01

    Lifetimes in the neutron-rich nuclei {sup 104}Mo, {sup 110}Ru, and {sup 144}Ba were measured using the differential recoil distance method. The experiment was performed with a {sup 252}Cf fission source inside the New Yale Plunger Device. {gamma} rays were detected by the SPEctrometer for Experiments with Doppler shifts at Yale (SPEEDY) while fission fragments with the appropriate kinematics were detected by an array of photocells.

  8. Recoil-proton polarization in high-energy deuteron photodisintegration with circularly plarized photons.

    SciTech Connect

    Jiang, X.; Arrington, J.; Benmokhtar, F.; Camsonne, A.; Chen, J. P.; Holt, R. J.; Qattan, I. A.; Reimer, P. E.; Schulte, E. C.; Wijesooriya, K.; Physics; Rutgers Univ.; Univ. Blaise Pascal; Thomas Jefferson National Accelerator Facility

    2007-05-01

    We measured the angular dependence of the three recoil-proton polarization components in two-body photodisintegration of the deuteron at a photon energy of 2 GeV. These new data provide a benchmark for calculations based on quantum chromodynamics. Two of the five existing models have made predictions of polarization observables. Both explain the longitudinal polarization transfer satisfactorily. Transverse polarizations are not well described, but suggest isovector dominance.

  9. Recoil-Proton Polarization in High-Energy Deuteron Photodisintegration with Circularly Polarized Photons

    SciTech Connect

    Jiang, X.; Benmokhtar, F.; Glashauser, C.; McCormick, K.; Ransome, R. D.; Arrington, J.; Holt, R. J.; Reimer, P. E.; Schulte, E. C.; Wijesooriya, K.; Camsonne, A.

    2007-05-04

    We measured the angular dependence of the three recoil-proton polarization components in two-body photodisintegration of the deuteron at a photon energy of 2 GeV. These new data provide a benchmark for calculations based on quantum chromodynamics. Two of the five existing models have made predictions of polarization observables. Both explain the longitudinal polarization transfer satisfactorily. Transverse polarizations are not well described, but suggest isovector dominance.

  10. Recoil-Proton Polarization in High-Energy Deuteron Photodisintegration with Circularly Polarized Photons

    SciTech Connect

    X. Jiang; J. Arrington; F. Benmokhtar; A. Camsonne; J. P. Chen; S. Choi; E. Chudakov; F. Cusanno; A. Deur; D. Dutta; F. Garibaldi; D. Gaskell; O. Gayou; R. Gilman; C. Glashauser; D. Hamilton; O. Hansen; D. W. Higinbotham; R. J. Holt; C. W. de Jager; M. K. Jones; L. J. Kaufman; E. R. Kinney; K. Kramer; L. Lagamba; R. de Leo; J. Lerose; D. Lhuillier; R. Lindgren; N. Liyanage; K. McCormick; Z.-E. Meziani; R. Michaels; B. Moffit; P. Monaghan; S. Nanda; K. D. Paschke; C. F. Perdrisat; V. Punjabi; I. A. Qattan; R. D. Ransome; P. E. Reimer; B. Reitz; A. Saha; E. C. Schulte; R. Sheyor; K. Slifer; P. Solvignon; V. Sulkosky; G. M. Urciuoli; E. Voutier; K. Wang; K. Wijesooriya; B. Wojtsekhowski; and L. Zhu

    2007-05-01

    We measured the angular dependence of the three recoil-proton polarization components in two-body photodisintegration of the deuteron at a photon energy of 2 GeV. These new data provide a benchmark for calculations based on quantum chromodynamics. Two of the five existing models have made predictions of polarization observables. Both explain the longitudinal polarization transfer satisfactorily. Transverse polarizations are not well described, but suggest isovector dominance.

  11. Angular dependence of recoil proton polarization in high-energy \\gamma d \\to p n

    SciTech Connect

    X. Jiang; J. Arrington; F. Benmokhtar; A. Camsonne; J.P. Chen; S. Choi; E. Chudakov; F. Cusanno; A. Deur; D. Dutta; F. Garibaldi; D. Gaskell; O. Gayou; R. Gilman; C. Glashauser; D. Hamilton; O. Hansen; D.W. Higinbotham; R.J. Holt; C.W. de Jager; M.K. Jones; L.J. Kaufman; E.R. Kinney; K. Kramer; L. Lagamba; R. de Leo; J. Lerose; D. Lhuillier; R. Lindgren; N. Liyanage; K. McCormick; Z.-E. Meziani; R. Michaels; B. Moffit; P. Monaghan; S. Nanda; K.D. Paschke; C.F. Perdrisat; V. Punjabi; I.A. Qattan; R.D. Ransome; P.E. Reimer; B. Reitz; A. Saha; E.C. Schulte; R. Sheyor; K. Slifer; P. Solvignon; V. Sulkosky; G.M. Urciuoli; E. Voutier; K. Wang; K. Wijesooriya; B. Wojtsekhowski; L. Zhu

    2007-02-26

    We measured the angular dependence of the three recoil proton polarization components in two-body photodisintegration of the deuteron at a photon energy of 2 GeV. These new data provide a benchmark for calculations based on quantum chromodynamics. Two of the five existing models have made predictions of polarization observables. Both explain the longitudinal polarization transfer satisfactorily.. Transverse polarizations are not well described, but suggest isovector dominance.

  12. Boron and Nitrogen Codoped Carbon Layers of LiFePO4 Improve the High-Rate Electrochemical Performance for Lithium Ion Batteries.

    PubMed

    Zhang, Jinli; Nie, Ning; Liu, Yuanyuan; Wang, Jiao; Yu, Feng; Gu, Junjie; Li, Wei

    2015-09-16

    An evolutionary composite of LiFePO4 with nitrogen and boron codoped carbon layers was prepared by processing hydrothermal-synthesized LiFePO4. This novel codoping method is successfully applied to LiFePO4 for commercial use, and it achieved excellent electrochemical performance. The electrochemical performance can be improved through single nitrogen doping (LiFePO4/C-N) or boron doping (LiFePO4/C-B). When modifying the LiFePO4/C-B with nitrogen (to synthesis LiFePO4/C-B+N) the undesired nonconducting N-B configurations (190.1 and 397.9 eV) are generated. This decreases the electronic conductivity from 2.56×10(-2) to 1.30×10(-2) S cm(-1) resulting in weak electrochemical performance. Nevertheless, using the opposite order to decorate LiFePO4/C-N with boron (to obtain LiFePO4/C-N+B) not only eliminates the nonconducting N-B impurity, but also promotes the conductive C-N (398.3, 400.3, and 401.1 eV) and C-B (189.5 eV) configurations-this markedly improves the electronic conductivity to 1.36×10(-1) S cm(-1). Meanwhile the positive doping strategy leads to synergistic electrochemical activity distinctly compared with single N- or B-doped materials (even much better than their sum capacity at 20 C). Moreover, due to the electron and hole-type carriers donated by nitrogen and boron atoms, the N+B codoped carbon coating tremendously enhances the electrochemical property: at the rate of 20 C, the codoped sample can elevate the discharge capacity of LFP/C from 101.1 mAh g(-1) to 121.6 mAh g(-1), and the codoped product based on commercial LiFePO4/C shows a discharge capacity of 78.4 mAh g(-1) rather than 48.1 mAh g(-1). Nevertheless, the B+N codoped sample decreases the discharge capacity of LFP/C from 101.1 mAh g(-1) to 95.4 mAh g(-1), while the commercial LFP/C changes from 48.1 mAh g(-1) to 40.6 mAh g(-1).

  13. Nitrogen-Doped Ordered Mesoporous Anatase TiO2 Nanofibers as Anode Materials for High Performance Sodium-Ion Batteries.

    PubMed

    Wu, Ying; Liu, Xiaowu; Yang, Zhenzhong; Gu, Lin; Yu, Yan

    2016-07-01

    Nitrogen-doped ordered mesoporous TiO2 nanofibers (N-MTO) have been fabricated by electrospinning and subsequent nitridation treatment. The N-doping in TiO2 leads to the formation of Ti(3+) , resulting in the improved electron conductivity of TiO2 . In addition, one-dimensional (1D) N-MTO nanostructure possesses very short diffusion length of Na(+) /e(-) in N-MTO, easy access of electrolyte, and high conductivity transport of electrons along the percolating fibers. The N-MTO shows excellent sodium storage performance.

  14. A Novel Nuclear Recoil Calibration in the LUX Detector Using a D-D Neutron Generator

    NASA Astrophysics Data System (ADS)

    Verbus, James; LUX Collaboration

    2015-04-01

    The LUX dark matter search experiment is a 350 kg two-phase liquid/gas xenon time projection chamber located at the 4850 ft level of the Sanford Underground Research Facility in Lead, SD. I will describe a novel calibration of nuclear recoils (NR) in liquid xenon (LXe) performed in-situ in the LUX detector using mono-energetic 2.45 MeV neutrons produced by a D-D neutron generator. This technique was used to measure the NR charge yield in LXe (Qy) to < 1 keV recoil energy with an absolute determination of the deposited energy. The LUX Qy result is a factor of × 5 lower in energy compared to any other previous measurement in the field, and provides a significant improvement in calibration uncertainties. We also present a measurement of the NR light yield in LXe (Leff) to recoil energies as low as ~ 2 keV using the LUX D-D data. The Leff result is also lower in energy with smaller uncertainties than has been previously achieved. These absolute, ultra-low energy calibrations of the NR signal yields in LXe are a clear confirmation of the detector response used for the first LUX WIMP search analysis. Strategies for extending this calibration technique to even lower energies and smaller uncertainties will be discussed.

  15. Lung recoil during rapid vital capacity expirations simulated by gas compression.

    PubMed

    Webster, P M; Loring, S H; Butler, J P; Hoppin, F G

    1980-07-01

    Excised dog lobes were inflated to a transpulmonary pressure (PL) of about 30 cmH2O, and their airways were occluded. Then they were rapidly compressed to a volume where PL was about zero, simulating forced expiratory maneuvers. Since there was no airflow during the compression, PL was a direct measure of lung recoil. Lung volume (VL) was calculated from absolute airway pressure using Boyle's law. At ambient temperature, lung recoil pressure during compressive maneuvers simulating forced vital capacity expirations (Pdyn) was less than that during quasi-static (30 s) compressions (Pst). Typically the dynamic component (i.e., Pst--Pdyn) decreased from about 2 cmH2O near total lung capacity to no difference at the end of the compression. Cooling the lobes to 15 degrees C increased Pst-Pdyn, and warming the lobes to 37 degrees C reduced Pst-Pdyn almost to zero. We suggest that the driving force of lung recoil during expirations is adequately modeled by the quasi-static VL/PL relationship, though a small correction should be made for excised lungs at room temperature. PMID:7399986

  16. Nuclear Recoil Calibrations in the LUX Detector Using Direct and Backscattered D-D Neutrons

    NASA Astrophysics Data System (ADS)

    Rhyne, Casey; LUX Collaboration

    2016-03-01

    The LUX dark matter search experiment is a 350 kg two-phase liquid/gas xenon time projection chamber located at the 4850 ft level of the Sanford Underground Research Facility in Lead, SD. I will discuss the latest calibration of the nuclear recoil (NR) response in liquid xenon (LXe), performed in-situ in the LUX detector using mono-energetic 2.45 MeV neutrons produced via the Adelphi Technologies, Inc. DD108 D-D neutron generator. The calibration measured the NR charge yield in LXe (Qy) to 0.7 keVnr recoil energy with an absolute determination of deposited energy and the NR light yield in LXe (Ly) to recoil energies of 1.1 keVnr, both of which improve upon all previous measurements. I will then focus in depth on the extension of this calibration using a new technique for generating a beam of sub-300 keV quasi-mono-energetic neutrons via the backscatter of 2.45 MeV neutrons off a deuterium-based reflector. Current simulations work optimizing the technique, its advantages, and its impact on future research will be discussed, including the extension of the NR Qy calibration down to 0.14 keVnr, an independent NR Ly calibration, and an a priori estimate of the expected 8B solar neutrino-nucleus coherent scattering signal in the upcoming LUX-ZEPLIN experiment.

  17. Measurement of the W boson mass and width using a novel recoil model

    SciTech Connect

    Wetstein, Matthew J.

    2009-01-01

    This dissertation presents a direct measurement of the W boson mass (MW) and decay width (ΓW) in 1 fb-1 of W → ev collider data at D0 using a novel method to model the hadronic recoil. The mass is extracted from fits to the transverse mass MT, pT(e), and ET distributions. The width is extracted from fits to the tail of the MT distribution. The electron energy measurement is simulated using a parameterized model, and the recoil is modeled using a new technique by which Z recoils are chosen from a data library to match the pT and direction of each generated W boson. We measure the the W boson mass to be MW = 80.4035 ± 0.024(stat) ± 0.039(syst) from the MT, MW = 80.4165 ± 0.027(stat) ± 0.038(syst) from the pT(e), and MW = 80.4025 ± 0.023(stat) ± 0.043(syst) from the ET distributions. ΓW is measured to be ΓW = 2.025 ± 0.038(stat) ± 0.061(syst) GeV.

  18. Einstein-Bohr recoiling double-slit gedanken experiment performed at the molecular level

    NASA Astrophysics Data System (ADS)

    Liu, Xiao-Jing; Miao, Quan; Gel'Mukhanov, Faris; Patanen, Minna; Travnikova, Oksana; Nicolas, Christophe; Ågren, Hans; Ueda, Kiyoshi; Miron, Catalin

    2015-02-01

    Double-slit experiments illustrate the quintessential proof for wave-particle complementarity. If information is missing about which slit the particle has traversed, the particle, behaving as a wave, passes simultaneously through both slits. This wave-like behaviour and corresponding interference is absent if ‘which-slit’ information exists. The essence of Einstein-Bohr's debate about wave-particle duality was whether the momentum transfer between a particle and a recoiling slit could mark the path, thus destroying the interference. To measure the recoil of a slit, the slits should move independently. We showcase a materialization of this recoiling double-slit gedanken experiment by resonant X-ray photoemission from molecular oxygen for geometries near equilibrium (coupled slits) and in a dissociative state far away from equilibrium (decoupled slits). Interference is observed in the former case, while the electron momentum transfer quenches the interference in the latter case owing to Doppler labelling of the counter-propagating atomic slits, in full agreement with Bohr's complementarity.

  19. Properties enhancement and recoil loop characteristics for hot deformed nanocrystalline NdFeB permanent magnets

    NASA Astrophysics Data System (ADS)

    Liu, Z. W.; Huang, Y. L.; Hu, S. L.; Zhong, X. C.; Y Yu, H.; Gao, X. X.

    2014-06-01

    Nanocrystalline NdFeB magnets were prepared by spark plasma sintering (SPS) and SPS followed by HD using melt spun ribbons as the starting materials. The microstructure of SPSed and HDed magnets were analyzed. The effects of process including temperature and compression ratio on the microstructure and properties were investigated. High magnetic properties were obtained in anisotropic HDed magnets. The combination of Zn and Dy additions was successfully employed to improve the coercivity and thermal stability of the SPSed magnets. Open recoil loops were found in these magnets with Nd-rich composition and without soft magnetic phase for the first time. The relationship between the recoil loops and microstructure for SPS and HD NdFeB magnets were investigated. The investigations showed that the magnetic properties of SPS+HDed magnets are related to the extent of the aggregation of Nd-rich phase, which was formed during HD due to existence of porosity in SPSed precursor. Large local demagnetization fields induced by the Nd-rich phase aggregation leads to the open loops and significantly reduced the coercivity. By reducing the recoil loop openness, the magnetic properties of HDed NdFeB magnets were successfully improved.

  20. Infrared Spectroscopy of Matrix-Isolated Polycyclic Aromatic Compounds and Their Ions. 7; Phenazine, a Dual Substituted Polycyclic Aromatic Nitrogen Heterocycle

    NASA Technical Reports Server (NTRS)

    Mattioda, A. L.; Hudgins, D. M.; Bauschlicher, C. W., Jr.; Allamandola, L. J.

    2004-01-01

    The matrix-isolation technique has been employed to measure the mid-infrared spectra of phenazine (C12H8N2), a dual substituted Polycyclic Aromatic Nitrogen Heterocycle (PANH), in the neutral, cationic and anionic forms. The experimentally measured band frequencies and intensities are tabulated and compared with their calculated values as well as those of the non-substituted parent molecule, anthracene. The theoretical band positions and intensities were calculated using both the 3-31 G as well as the larger 6-3lG* Basis Sets. A comparison of the results can be found in the tables. The spectroscopic properties of phenazine and its cation are similar to those observed in mono-substituted PANHs, with one exception. The presence of a second nitrogen atom results in an additional enhancement of the cation's total integrated intensity, for the 1500-1000 cm(sup -1) (6.7 to 10 micron) region, over that observed for a mono-substituted PANH cation. The significance of this enhancement and the astrobiological implications of these results are discussed.

  1. Stoichiometric disturbances in compound semiconductors due to ion implantation

    NASA Technical Reports Server (NTRS)

    Avila, R. E.; Fung, C. D.

    1986-01-01

    A method is developed to calculate the depth distribution of the local stoichiometric disturbance (SD) resulting from ion implantation in binary-compound substrates. The calculation includes first-order recoils considering projected range straggle of projectiles and recoils and lateral straggle of recoils. The method uses tabulated final-range statistics to infer the projectile range distributions at intermediate energies. This approach greatly simplifies the calculation with little compromise on accuracy as compared to existing procedures. As an illustration, the SD profile is calculated for implantation of boron, silicon, and aluminum in silicon carbide. The results for the latter case suggest that the SD may be responsible for otherwise unexplained distortions in the annealed aluminum profile. A comparison with calculations by other investigators using the Boltzmann transport equation shows good agreement.

  2. Collision-induced dissociation of diazirine-labeled peptide ions. Evidence for Brønsted-acid assisted elimination of nitrogen.

    PubMed

    Marek, Aleš; Tureček, František

    2014-05-01

    Gas-phase dissociations were investigated for several peptide ions containing the Gly-Leu* N-terminal motif where Leu* was a modified norleucine residue containing the photolabile diazirine ring. Collisional activation of gas-phase peptide cations resulted in facile N₂ elimination that competed with backbone dissociations. A free lysine ammonium group can act as a Brønsted acid to facilitate N₂ elimination. This dissociation was accompanied by insertion of a lysine proton in the side chain of the photoleucine residue, as established by deuterium labeling and gas-phase sequencing of the products. Electron structure calculations were used to provide structures and energies of reactants, intermediates, and transition states for Gly-Leu*-Gly-Gly-Lys amide ions that were combined with RRKM calculations of unimolecular rate constants. The calculations indicated that Brønsted acid-catalyzed eliminations were kinetically preferred over direct loss of N₂ from the diazirine ring. Mechanisms are proposed to explain the proton-initiated reactions and discuss the reaction products. The non-catalyzed diazirine ring cleavage and N₂ loss is proposed as a thermometer dissociation for peptide ion dissociations. PMID:24549894

  3. Collision-Induced Dissociation of Diazirine-Labeled Peptide Ions. Evidence for Brønsted-Acid Assisted Elimination of Nitrogen

    NASA Astrophysics Data System (ADS)

    Marek, Aleš; Tureček, František

    2014-05-01

    Gas-phase dissociations were investigated for several peptide ions containing the Gly-Leu* N-terminal motif where Leu* was a modified norleucine residue containing the photolabile diazirine ring. Collisional activation of gas-phase peptide cations resulted in facile N2 elimination that competed with backbone dissociations. A free lysine ammonium group can act as a Brønsted acid to facilitate N2 elimination. This dissociation was accompanied by insertion of a lysine proton in the side chain of the photoleucine residue, as established by deuterium labeling and gas-phase sequencing of the products. Electron structure calculations were used to provide structures and energies of reactants, intermediates, and transition states for Gly-Leu*-Gly-Gly-Lys amide ions that were combined with RRKM calculations of unimolecular rate constants. The calculations indicated that Brønsted acid-catalyzed eliminations were kinetically preferred over direct loss of N2 from the diazirine ring. Mechanisms are proposed to explain the proton-initiated reactions and discuss the reaction products. The non-catalyzed diazirine ring cleavage and N2 loss is proposed as a thermometer dissociation for peptide ion dissociations.

  4. Ion fluxes across the pitcher walls of three Bornean Nepenthes pitcher plant species: flux rates and gland distribution patterns reflect nitrogen sequestration strategies

    PubMed Central

    Moran, Jonathan A.; Hawkins, Barbara J.; Gowen, Brent E.; Robbins, Samantha L.

    2010-01-01

    Nepenthes pitcher plant species differ in their prey capture strategies, prey capture rates, and pitcher longevity. In this study, it is investigated whether or not interspecific differences in nutrient sequestration strategy are reflected in the physiology and microstructure of the pitchers themselves. Using a non-invasive technique (MIFE), ion fluxes in pitchers of Nepenthes ampullaria Jack, Nepenthes bicalcarata Hook.f., and Nepenthes rafflesiana Jack were measured. Scanning electron microscopy was also used to characterize the distribution of glandular and other structures on the inner pitcher walls. The results demonstrate that nutrient sequestration strategy is indeed mirrored in pitcher physiology and microstructure. Species producing long-lived pitchers with low prey capture rates (N. ampullaria, N. bicalcarata) showed lower rates of NH4+ uptake than N. rafflesiana, a species producing short-lived pitchers with high capture rates. Crucially, species dependent upon aquatic commensals (N. ampullaria, N. bicalcarata) actively manipulated H+ fluxes to maintain less acid pitcher fluid than found in ‘typical’ species; in addition, these species lacked the lunate cells and epicuticular waxes characteristic of ‘typical’ insectivorous congeners. An unexpected finding was that ion fluxes occurred in the wax-covered, non-glandular zones in N. rafflesiana. The only candidates for active transport of aqueous ions in these zones appear to be the epidermal cells lying beneath the lunate cells, as these are the only sites not visibly coated with epicuticular waxes. PMID:20150519

  5. In situ fabrication of three-dimensional nitrogen and boron co-doped porous carbon nanofibers for high performance lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Zhang, Lijun; Xia, Guanglin; Guo, Zaiping; Sun, Dalin; Li, Xingguo; Yu, Xuebin

    2016-08-01

    This paper reports the fabrication of three-dimensional porous carbon nanofibers network with high doping level of nitrogen (N, 5.17 at.%) and boron (B, 6.87 at.%) through a general electrospinning strategy followed by a calcination process. The employed ammonia borane (NH3BH3, denote as AB) not only functions as a porogen reagent to generate porous structures but also as the heteroatoms source to induce N and B co-doping. Such highly unique nanoarchitectures offer remarkably improved Li storage performance including high reversible capacity (∼910 mAh g-1 at a current density of 100 mA g-1) with good cycling and rate performances.

  6. In situ fabrication of three-dimensional nitrogen and boron co-doped porous carbon nanofibers for high performance lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Zhang, Lijun; Xia, Guanglin; Guo, Zaiping; Sun, Dalin; Li, Xingguo; Yu, Xuebin

    2016-08-01

    This paper reports the fabrication of three-dimensional porous carbon nanofibers network with high doping level of nitrogen (N, 5.17 at.%) and boron (B, 6.87 at.%) through a general electrospinning strategy followed by a calcination process. The employed ammonia borane (NH3BH3, denote as AB) not only functions as a porogen reagent to generate porous structures but also as the heteroatoms source to induce N and B co-doping. Such highly unique nanoarchitectures offer remarkably improved Li storage performance including high reversible capacity (∼910 mAh g-1 at a current density of 100 mA g-1) with good cycling and rate performances.

  7. Multiscale anode materials in lithium ion batteries by combining micro- with nanoparticles: design of mesoporous TiO2 microfibers@nitrogen doped carbon composites

    NASA Astrophysics Data System (ADS)

    Cheng, Wei; Rechberger, Felix; Primc, Darinka; Niederberger, Markus

    2015-08-01

    TiO2 has been considered as a promising anode material for lithium ion batteries. However, its poor rate capability originating from the intrinsically low lithium ion diffusivity and its poor electronic conductivity hampers putting such an application into practice. Both issues can be addressed by nanostructure engineering and conductive surface coating. Herein, we report a template-assisted synthesis of micron sized TiO2 fibers consisting of a mesoporous network of anatase nanoparticles of about 7.5 nm and coated by N doped carbon. In a first step, an amorphous layer of TiO2 was deposited on cobalt silicate nanobelts and subsequently transformed into crystalline anatase nanoparticles by hydrothermal treatment. The N doped carbon coating was realized by in situ polymerization of dopamine on the crystalline TiO2 followed by annealing under N2. After removal of the template, we obtained the final mesoporous TiO2 fibers@N doped carbon composite. Electrochemical tests revealed that the composite electrode exhibited excellent electrochemical properties in terms of specific capacity, rate performance and long term stability.TiO2 has been considered as a promising anode material for lithium ion batteries. However, its poor rate capability originating from the intrinsically low lithium ion diffusivity and its poor electronic conductivity hampers putting such an application into practice. Both issues can be addressed by nanostructure engineering and conductive surface coating. Herein, we report a template-assisted synthesis of micron sized TiO2 fibers consisting of a mesoporous network of anatase nanoparticles of about 7.5 nm and coated by N doped carbon. In a first step, an amorphous layer of TiO2 was deposited on cobalt silicate nanobelts and subsequently transformed into crystalline anatase nanoparticles by hydrothermal treatment. The N doped carbon coating was realized by in situ polymerization of dopamine on the crystalline TiO2 followed by annealing under N2. After

  8. Enhanced retained dose uniformity in NiTi spinal correction rod treated by three-dimensional mesh-assisted nitrogen plasma immersion ion implantation

    SciTech Connect

    Lu, Q. Y.; Hu, T.; Kwok, Dixon T. K.; Chu, Paul K.

    2010-05-15

    Owing to the nonconformal plasma sheath in plasma immersion ion implantation of a rod sample, the retained dose can vary significantly. The authors propose to improve the implant uniformity by introducing a metal mesh. The depth profiles obtained with and without the mesh are compared and the implantation temperature at various locations is evaluated indirectly by differential scanning calorimeter. Our results reveal that by using the metal mesh, the retained dose uniformity along the length is greatly improved and the effects of the implantation temperature on the localized mechanical properties of the implanted NiTi shape memory alloy rod are nearly negligible.

  9. Multiscale anode materials in lithium ion batteries by combining micro- with nanoparticles: design of mesoporous TiO2 microfibers@nitrogen doped carbon composites.

    PubMed

    Cheng, Wei; Rechberger, Felix; Primc, Darinka; Niederberger, Markus

    2015-09-01

    TiO2 has been considered as a promising anode material for lithium ion batteries. However, its poor rate capability originating from the intrinsically low lithium ion diffusivity and its poor electronic conductivity hampers putting such an application into practice. Both issues can be addressed by nanostructure engineering and conductive surface coating. Herein, we report a template-assisted synthesis of micron sized TiO2 fibers consisting of a mesoporous network of anatase nanoparticles of about 7.5 nm and coated by N doped carbon. In a first step, an amorphous layer of TiO2 was deposited on cobalt silicate nanobelts and subsequently transformed into crystalline anatase nanoparticles by hydrothermal treatment. The N doped carbon coating was realized by in situ polymerization of dopamine on the crystalline TiO2 followed by annealing under N2. After removal of the template, we obtained the final mesoporous TiO2 fibers@N doped carbon composite. Electrochemical tests revealed that the composite electrode exhibited excellent electrochemical properties in terms of specific capacity, rate performance and long term stability.

  10. Nitrogen species

    NASA Technical Reports Server (NTRS)

    Harries, J. E.; Brasseur, G.; Coffey, M. T.; Fischer, H.; Gille, J.; Jones, R.; Louisnard, N.; Mccormick, M. P.; Noxon, J.; Owens, A. J.

    1985-01-01

    Total odd nitrogen, NO(y), may be defined as the sum of all active nitrogen species that interchange photochemically with one another on a time scale of the order of weeks or less. As noted, NO + NO2 reactions dominate the processes controlling the ozone balance in the contemporary stratosphere. The observational data from non-satellite platforms are reviewed. The growth in available satellite data in the past four years is considered. Some of the most important scientific issues are discussed, taking into account new results from atmospheric models (mainly 2-D). The model results are compared with the observational data.

  11. Nano electrochemical reactors of Fe2O3 nanoparticles embedded in shells of nitrogen-doped hollow carbon spheres as high-performance anodes for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Zheng, Fangcai; He, Mengni; Yang, Yang; Chen, Qianwang

    2015-02-01

    Iron oxides are extensively investigated as anode materials for lithium-ion batteries (LIBs) because of their large specific capacities. However, they undergo huge volume changes during cycling that result in anode pulverization and loss of electrical connectivity. As a result, the capacity retention of the iron oxide anodes is poor and should be improved for commercial applications. Herein, we report the preparation of ultrasmall Fe2O3 nanoparticles embedded in nitrogen-doped hollow carbon sphere shells (Fe2O3@N-C) by the direct pyrolysis of Fe-based zeolitic imidazolate frameworks (Fe-ZIF) at 620 °C in air. As an anode material for LIBs, the capacity retained was 1573 mA h g-1 after 50 cycles at a current density of 0.1 C (1 C = 1000 mA g-1). Even undergoing the high-rate capability test twice, it can still deliver a remarkably reversible and stable capacity of 1142 mA h g-1 after 100 cycles at a current density of 1 C. The excellent electrochemical performance is attributed to the unique structure of ultrasmall Fe2O3 nanoparticles uniformly distributed in the shell of nitrogen-doped carbon spheres, which simultaneously solve the major problems of pulverization, facilitate rapid electrochemical kinetics, and effectively avoid the aggregation of Fe2O3 nanoparticles during de/lithiation. The novel method developed in this work for the synthesis of functional hybrid materials can be extended to the preparation of various MOFs-derived functional nanocomposites owing to the versatility of links and metal centers in MOFs.Iron oxides are extensively investigated as anode materials for lithium-ion batteries (LIBs) because of their large specific capacities. However, they undergo huge volume changes during cycling that result in anode pulverization and loss of electrical connectivity. As a result, the capacity retention of the iron oxide anodes is poor and should be improved for commercial applications. Herein, we report the preparation of ultrasmall Fe2O3 nanoparticles

  12. One-step Synthesis of Highly Luminescent Nitrogen-doped Carbon Dots for Selective and Sensitive Detection of Mercury(II) Ions and Cellular Imaging.

    PubMed

    Liu, Ying; Liao, Mei; He, Xueling; Liu, Xia; Kou, Xingming; Xiao, Dan

    2015-01-01

    In this paper, nitrogen-doped carbon dots (N-CDs) with high quantum yield (QY) of 40.5% were prepared through a facile and straightforward hydrothermal route. The as-prepared N-CDs exhibited excellent photoluminescence properties, good water-solublity and photostability, negligible cytotoxicity and favourable biocompatibility. Such N-CDs were found to serve as an effective fluorescent sensor for selective and sensitive detection of Hg(2+) in a wide linear response concentration range of 0 - 8 μM with a limit of detection (LOD) of 0.087 μM and could be applied to the determination of Hg(2+) in environmental water samples. The corresponding mechanisms were discussed in detail. Moreover, another attractive finding was that the N-CDs showed satisfactory performance in bioimaging before and after the addition of Hg(2+) in human lung cancer PC14 cells. With excellent sensitivity, selectivity and biocompatibility, such cheap carbonmaterials are potentially suitable for monitoring of Hg(2+) in environmental applications and promising for biological applications. PMID:26460360

  13. Order-of-Magnitude Estimate of Fast Neutron Recoil Rates in Proposed Neutrino Detector at SNS

    SciTech Connect

    Iverson, Erik B.

    2006-02-01

    Yuri Efremenko (UT-K) and Kate Scholberg (Duke) indicated, during discussions on 12 January 2006 with the SNS Neutronics Team, interest in a new type of neutrino detector to be placed within the proposed neutrino bunker at SNS, near beam-line 18, against the RTBT. The successful operation of this detector and its associated experiments would require fast-neutron recoil rates of approximately one event per day of operation or less. To this end, the author has attempted the following order-of-magnitude estimate of this recoil rate in order to judge whether or not a full calculation effort is needed or justified. For the purposes of this estimate, the author considers a one-dimensional slab geometry, in which fast and high-energy neutrons making up the general background in the target building are incident upon one side of an irbon slab. This iron slab represents the neutrino bunker walls. If we assume that a significant fraction of the dose rate throughout the target building is due to fast or high-energy neutrons, we can estimate the flux of such neutrons based upon existing shielding calculations performed for radiation protection purposes. In general, the dose rates within the target building are controlled to be less than 0.25 mrem per hour. A variety of calculations have indicated that these dose rates have significant fast and high-energy neutron components. Thus they can estimate the fast neutron flux incident on the neutrino bunker, and thereby the fast neutron flux inside that bunker. Finally, they can estimate the neutron recoil rate within a nominal detector volume. Such an estimate is outlined in Table 1.

  14. Measurement and calculation of recoil pressure produced during CO{sub 2} laser interaction with ice

    SciTech Connect

    Semak, V.V.; Knorovsky, G.A.; Maccallum, D.O.; Noble, D.R.; Kanouff, M.P.

    1999-12-09

    Evaporation is a classical physics problem which, because of its significant importance for many engineering applications, has drawn considerable attention by previous researchers. Classical theoretical models [Ta. I. Frenkel, Kinetic Theory of Liquids, Clarendon Press, Oxford, 1946] represent evaporation in a simplistic way as the escape of atoms with highest velocities from a potential well with the depth determined by the atomic binding energy. The processes taking place in the gas phase above the rapidly evaporating surface have also been studied in great detail [S.I.Anisimov and V. A. Khokhlov, Instabilities in Lasser-Matter Interaction, CRC Press, Boca Raton, 1995]. The description of evaporation utilizing these models is known to adequately characterize drilling with high beam intensity, e.g., >10{sup 7} W/cm{sup 2}. However, the interaction regimes when beam intensity is relatively low, such as during welding or cutting, lack both theoretical and experimental consideration of the evaporation. It was shown recently that if the evaporation is treated in accordance with Anisimov et.al.'s approach, then predicted evaporation recoil should be a substantial factor influencing melt flow and related heat transfer during laser beam welding and cutting. To verify the applicability of this model for low beam intensity interaction, the authors compared the results of measurements and calculations of recoil pressure generated during laser beam irradiation of a target. The target material used was water ice at {minus}10 C. The displacement of a target supported in a nearly frictionless air bearing under irradiation by a defocused laser beam from a 14 kW CO{sub 2} laser was recorded and Newton's laws of motion used to derive the recoil pressure.

  15. Quantitative angiographic assessment of elastic recoil after percutaneous transluminal coronary angioplasty.

    PubMed

    Rensing, B J; Hermans, W R; Beatt, K J; Laarman, G J; Suryapranata, H; van den Brand, M; de Feyter, P J; Serruys, P W

    1990-11-01

    Little is known about the elastic behavior of the coronary vessel wall directly after percutaneous transluminal coronary angioplasty (PTCA). Minimal luminal cross-sectional areas of 151 successfully dilated lesions were studied in 136 patients during balloon inflation and directly after withdrawal of the balloon. The circumvent geometric assumptions about the shape of the stenosis after PTCA, a videodensitometric analysis technique was used for the assessment of vascular cross-sectional areas. Elastic recoil was defined as the difference between balloon cross-sectional area of the largest balloon used at the highest pressure and minimal luminal cross-sectional area after PTCA. Mean balloon cross-sectional area was 5.2 +/- 1.6 mm2 with a mean minimal cross-sectional area of 2.8 +/- 1.4 mm2 immediately after inflation. Oversizing of the balloon (balloon artery ratio greater than 1) led to more recoil (0.8 +/- 0.3 vs 0.6 +/- 0.3 mm, p less than 0.001), suggestive of an elastic phenomenon. A difference in recoil of the 3 main coronary branches was observed: left anterior descending artery 2.7 +/- 1.3 mm2, circumflex artery 2.3 +/- 1.2 mm2 and right coronary artery 1.9 +/- 1.5 mm2 (p less than 0.025). The difference was still statistically significant if adjusted for reference area. Thus, nearly 50% of the theoretically achievable cross-sectional area (i.e., balloon cross-sectional area) is lost shortly after balloon deflation.

  16. Complexation of nitrogen and sulphur donor Schiff's base ligand to Cr(III) and Ni(II) metal ions: Synthesis, spectroscopic and antipathogenic studies

    NASA Astrophysics Data System (ADS)

    Sharma, Amit Kumar; Chandra, Sulekh

    2011-01-01

    2,6-Diacetyl pyridine based ligand was synthesized by the reaction of 2,6-diacetyl pyridine with thiocarbohydrazide in presence of acetic acid. The coordination compounds with Cr(III) and Ni(II) metal ions having [Cr(L)X]X 2 and [Ni(L)X]X compositions (where L = ligand and X = NO 3-, Cl - and CH 3COO -) were synthesized and characterized by physicochemical and spectral studies. The studies like elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, UV-Vis, NMR, mass and EPR reveal that the complexes are octahedral. The compounds were examined against the pathogenic fungal and bacterial strains like Alternaria brassicae, Aspergillus niger, Fusarium oxysporum, Xanthomonas compestris and Pseudomonas aeruginosa. A. niger causes the diseases Apergillosis and Otomycosis in humans.

  17. Soil response to a 3-year increase in temperature and nitrogen deposition measured in a mature boreal forest using ion-exchange membranes.

    PubMed

    D'Orangeville, Loïc; Houle, Daniel; Côté, Benoît; Duchesne, Louis

    2014-12-01

    The projected increase in atmospheric N deposition and air/soil temperature will likely affect soil nutrient dynamics in boreal ecosystems. The potential effects of these changes on soil ion fluxes were studied in a mature balsam fir stand (Abies balsamea [L.] Mill) in Quebec, Canada that was subjected to 3 years of experimentally increased soil temperature (+4 °C) and increased inorganic N concentration in artificial precipitation (three times the current N concentrations using NH4NO3). Soil element fluxes (NO3, NH4, PO4, K, Ca, Mg, SO4, Al, and Fe) in the organic and upper mineral horizons were monitored using buried ion-exchange membranes (PRS™ probes). While N additions did not affect soil element fluxes, 3 years of soil warming increased the cumulative fluxes of K, Mg, and SO4 in the forest floor by 43, 44, and 79 %, respectively, and Mg, SO4, and Al in the mineral horizon by 29, 66, and 23 %, respectively. We attribute these changes to increased rates of soil organic matter decomposition. Significant interactions of the heating treatment with time were observed for most elements although no clear seasonal patterns emerged. The increase in soil K and Mg in heated plots resulted in a significant but small K increase in balsam fir foliage while no change was observed for Mg. A 6-15 % decrease in foliar Ca content with soil warming could be related to the increase in soil-available Al in heated plots, as Al can interfere with the root uptake of Ca.

  18. Soil response to a 3-year increase in temperature and nitrogen deposition measured in a mature boreal forest using ion-exchange membranes.

    PubMed

    D'Orangeville, Loïc; Houle, Daniel; Côté, Benoît; Duchesne, Louis

    2014-12-01

    The projected increase in atmospheric N deposition and air/soil temperature will likely affect soil nutrient dynamics in boreal ecosystems. The potential effects of these changes on soil ion fluxes were studied in a mature balsam fir stand (Abies balsamea [L.] Mill) in Quebec, Canada that was subjected to 3 years of experimentally increased soil temperature (+4 °C) and increased inorganic N concentration in artificial precipitation (three times the current N concentrations using NH4NO3). Soil element fluxes (NO3, NH4, PO4, K, Ca, Mg, SO4, Al, and Fe) in the organic and upper mineral horizons were monitored using buried ion-exchange membranes (PRS™ probes). While N additions did not affect soil element fluxes, 3 years of soil warming increased the cumulative fluxes of K, Mg, and SO4 in the forest floor by 43, 44, and 79 %, respectively, and Mg, SO4, and Al in the mineral horizon by 29, 66, and 23 %, respectively. We attribute these changes to increased rates of soil organic matter decomposition. Significant interactions of the heating treatment with time were observed for most elements although no clear seasonal patterns emerged. The increase in soil K and Mg in heated plots resulted in a significant but small K increase in balsam fir foliage while no change was observed for Mg. A 6-15 % decrease in foliar Ca content with soil warming could be related to the increase in soil-available Al in heated plots, as Al can interfere with the root uptake of Ca. PMID:25139238

  19. Control of recoil losses in nanomechanical SiN membrane resonators

    NASA Astrophysics Data System (ADS)

    Borrielli, A.; Marconi, L.; Marin, F.; Marino, F.; Morana, B.; Pandraud, G.; Pontin, A.; Prodi, G. A.; Sarro, P. M.; Serra, E.; Bonaldi, M.

    2016-09-01

    In the context of a recoil damping analysis, we have designed and produced a membrane resonator equipped with a specific on-chip structure working as a "loss shield" for a circular membrane. In this device the vibrations of the membrane, with a quality factor of 107, reach the limit set by the intrinsic dissipation in silicon nitride, for all the modes and regardless of the modal shape, also at low frequency. Guided by our theoretical model of the loss shield, we describe the design rationale of the device, which can be used as effective replacement of commercial membrane resonators in advanced optomechanical setups, also at cryogenic temperatures.

  20. Reaction {gamma}p {sup {yields}} {eta}' (958) p and polarization of recoil protons

    SciTech Connect

    Tryasuchev, V. A.

    2006-02-15

    On the basis of the isobar model extended by including the t-channel, the cross sections for and single-polarization features of the reaction {gamma}p {sup {yields}} {eta}'p are calculated for incident-photon energies up to 5 GeV, two poorly studied resonances, S{sub 11}(1978) and P{sub 13}(2080), being taken into account in this calculation. In order to reduce the ambiguities in the choice of resonances and their parameters that make it possible to reproduce the experimental differential cross sections, it is proposed to measure the polarization of recoil protons in the reaction being considered.

  1. Recoil polarization measurements of the proton electromagnetic form factor ratio at high momentum transfer

    SciTech Connect

    Andrew Puckett

    2009-12-01

    Electromagnetic form factors are fundamental properties of the nucleon that describe the effect of its internal quark structure on the cross section and spin observables in elastic lepton-nucleon scattering. Double-polarization experiments have become the preferred technique to measure the proton and neutron electric form factors at high momentum transfers. The recently completed GEp-III experiment at the Thomas Jefferson National Accelerator Facility used the recoil polarization method to extend the knowledge of the proton electromagnetic form factor ratio GpE/GpM to Q2 = 8.5 GeV2. In this paper we present the preliminary results of the experiment.

  2. Direct recoil radon emanation from crystalline phases. Influence of moisture content

    NASA Astrophysics Data System (ADS)

    Barillon, Rémi; Özgümüs, Ahmet; Chambaudet, Alain

    2005-06-01

    This paper is devoted to the study of the radon emanation coefficient vs. water mass fraction for mineral samples. Modeling is performed considering only the direct recoil phenomena and assuming planar pores with high lengths-to-width aspect ratios. Water is assumed either to fill the pore alternatively with air or to form a continuous film on the pore surface. This modeling is applied to uranium mine tailings for which the pore size distribution was experimentally measured. It enables a good description of the change of the experimental radon emanation coefficients with the moisture content of the studied samples.

  3. The alpha-recoil effects of uranium in the Oklo reactor

    NASA Astrophysics Data System (ADS)

    Sheng, Z. Z.; Kuroda, P. K.

    1984-12-01

    A series of acid-leaching experiments have been carried out on a sample of uranium ore from reactor zone number 10 of the Oklo mines in Gabon. Anomalously high U-234/U-238 ratios were observed accompanied by modestly increased U-235/U-238 ratios in uranium fractions. These results, which can be interpreted as being due to the alpha-recoil effects of U-238 and Pu-239, provide a convenient way of calculating the conversion factor (the fraction of uranium atoms converted to plutonium) of the natural reactors from radiochemical data, obviating the necessity for mass-spectrometric measurements.

  4. Lifetime measurement of the 41+ state of 58Ni with the recoil distance method

    NASA Astrophysics Data System (ADS)

    Loelius, C.; Iwasaki, H.; Brown, B. A.; Honma, M.; Bader, V. M.; Baugher, T.; Bazin, D.; Berryman, J. S.; Braunroth, T.; Campbell, C. M.; Dewald, A.; Gade, A.; Kobayashi, N.; Langer, C.; Lee, I. Y.; Lemasson, A.; Lunderberg, E.; Morse, C.; Recchia, F.; Smalley, D.; Stroberg, S. R.; Wadsworth, R.; Walz, C.; Weisshaar, D.; Westerberg, A.; Whitmore, K.; Wimmer, K.

    2016-08-01

    The quadrupole transition rate for the 41+→21+ transition of 58Ni was determined from an application of the recoil distance method with the Gamma-Ray Energy Tracking In-beam Nuclear Array (GRETINA). The present result of the B (E 2 ;41+→21+) was found to be 50-6+11e2fm4 , which is about three times smaller than the literature value, indicating substantially less collectivity than previously believed. Shell model calculations performed with the GXPF1A effective interaction agree with the present data and the validity of the standard effective charges in understanding collectivity in the nickel isotopes is discussed.

  5. g-FACTOR Measurements of Picosecond States:. Opportunities and Limitations of the Recoil-In Method

    NASA Astrophysics Data System (ADS)

    Stone, N. J.; Stone, J. R.; Bingham, C. R.; Fischer, C. Froese; Jönsson, P.

    2008-08-01

    This paper reports a new a-priori approach to the calibration of attenuations observed in Recoil-in-Vacuum angular distribution experiments which should allow extraction of g-factors for states of picosecond (ps) lifetime in many nuclei, of both odd-A and even-A without the need for extensive experimentally based calibration. The methods used and results for Ge and Mo isotopes are discussed, with outline applications to both on-line beam/target Coulomb excitation and fission fragment experiments.

  6. Ischemic stroke secondary to aortic dissection following rifle butt recoil chest injury: a case report.

    PubMed

    Rao, Mamatha; Panduranga, Prashanth; Al-Mukhaini, Mohammed; Al-Jufaili, Mahmood; Valiath, John

    2011-11-01

    Ischemic stroke secondary to aortic dissection is not uncommon. We present a patient with left hemiplegia secondary to Stanford type A aortic dissection extending to the supra-aortic vessels, which was precipitated by rifle butt recoil chest injury. The diagnosis of aortic dissection was delayed due to various factors. Finally, the patient underwent successful Bentall procedure with complete resolution of symptoms. This case emphasizes the need for caution in the use of firearms for recreation and to take precautions in preventing such incidents. In addition, this case illustrates the need for prompt cardiovascular physical examination in patients presenting with stroke.

  7. Ischemic Stroke Secondary to Aortic Dissection Following Rifle Butt Recoil Chest Injury: A Case Report

    PubMed Central

    Rao, Mamatha; Panduranga, Prashanth; Al-Mukhaini, Mohammed; Al-Jufaili, Mahmood; Valiath, John

    2011-01-01

    Ischemic stroke secondary to aortic dissection is not uncommon. We present a patient with left hemiplegia secondary to Stanford type A aortic dissection extending to the supra-aortic vessels, which was precipitated by rifle butt recoil chest injury. The diagnosis of aortic dissection was delayed due to various factors. Finally, the patient underwent successful Bentall procedure with complete resolution of symptoms. This case emphasizes the need for caution in the use of firearms for recreation and to take precautions in preventing such incidents. In addition, this case illustrates the need for prompt cardiovascular physical examination in patients presenting with stroke. PMID:22253955

  8. Binary and Recoil Collisions in Strong Field Double Ionization of Helium

    SciTech Connect

    Staudte, A.; Villeneuve, D. M.; Corkum, P. B.; Ruiz, C.; Becker, A.; Schoeffler, M.; Schoessler, S.; Meckel, M.; Doerner, R.; Zeidler, D.; Weber, Th.

    2007-12-31

    We have investigated the correlated momentum distribution of both electrons from nonsequential double ionization of helium in a 800 nm, 4.5x10{sup 14} W/cm{sup 2} laser field. Using very high resolution coincidence techniques, we find a so-far unobserved fingerlike structure in the correlated electron momentum distribution. The structure can be interpreted as a signature of the microscopic dynamics in the recollision process. We identify features corresponding to the binary and recoil lobe in field-free (e,2e) collisions. This interpretation is supported by analyzing ab initio solutions of a fully correlated three-dimensional helium model.

  9. Experimental evidence of the vapor recoil mechanism in the boiling crisis.

    PubMed

    Nikolayev, V S; Chatain, D; Garrabos, Y; Beysens, D

    2006-11-01

    Boiling crisis experiments are carried out in the vicinity of the liquid-gas critical point of H2. A magnetic gravity compensation setup is used to enable nucleate boiling at near critical pressure. The measurements of the critical heat flux that defines the threshold for the boiling crisis are carried out as a function of the distance from the critical point. The obtained power law behavior and the boiling crisis dynamics agree with the predictions of the vapor recoil mechanism and disagree with the classical vapor column mechanism.

  10. β-delayed neutron spectroscopy using trapped radioactive ions.

    PubMed

    Yee, R M; Scielzo, N D; Bertone, P F; Buchinger, F; Caldwell, S; Clark, J A; Deibel, C M; Fallis, J; Greene, J P; Gulick, S; Lascar, D; Levand, A F; Li, G; Norman, E B; Pedretti, M; Savard, G; Segel, R E; Sharma, K S; Sternberg, M G; Van Schelt, J; Zabransky, B J

    2013-03-01

    A novel technique for β-delayed neutron spectroscopy has been demonstrated using trapped ions. The neutron-energy spectrum is reconstructed by measuring the time of flight of the nuclear recoil following neutron emission, thereby avoiding all the challenges associated with neutron detection, such as backgrounds from scattered neutrons and γ rays and complicated detector-response functions. (137)I(+) ions delivered from a (252)Cf source were confined in a linear Paul trap surrounded by radiation detectors, and the β-delayed neutron-energy spectrum and branching ratio were determined by detecting the β(-) and recoil ions in coincidence. Systematic effects were explored by determining the branching ratio three ways. Improvements to achieve higher detection efficiency, better energy resolution, and a lower neutron-energy threshold are proposed. PMID:23496704

  11. Nitrogen dioxide

    Integrated Risk Information System (IRIS)

    Nitrogen dioxide ; CASRN 10102 - 44 - 0 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogeni

  12. Heterologous Expression Implicates a GATA Factor in Regulation of Nitrogen Metabolic Genes and Ion Homeostasis in the Halotolerant Yeast Debaryomyces hansenii†

    PubMed Central

    García-Salcedo, Raúl; Casamayor, Antonio; Ruiz, Amparo; González, Asier; Prista, Catarina; Loureiro-Dias, Maria C.; Ramos, José; Ariño, Joaquín

    2006-01-01

    The yeast Debaryomyces hansenii has a remarkable capacity to proliferate in salty and alkaline environments such as seawater. A screen for D. hansenii genes able to confer increased tolerance to high pH when overexpressed in Saccharomyces cerevisiae yielded a single gene, named here DhGZF3, encoding a putative negative GATA transcription factor related to S. cerevisiae Dal80 and Gzf3. Overexpression of this gene in wild-type S. cerevisiae increased caffeine and rapamycin tolerance, blocked growth in low glucose concentrations and nonfermentable carbon sources, and resulted in lithium- and sodium-sensitive cells. Sensitivity to salt could be attributed to a reduced cation efflux, most likely because of a decrease in expression of the ENA1 Na+-ATPase gene. Overexpression of DhGZF3 did not affect cell growth in a gat1 mutant but was lethal in the absence of Gln3. These are positive factors that oppose both Gzf3 and Dal80. Genome-wide transcriptional profiling of wild-type cells overexpressing DhGZF3 shows decreased expression of a number of genes that are usually induced in poor nitrogen sources. In addition, the entire pathway leading to Lys biosynthesis was repressed, probably as a result of a decrease in the expression of the specific Lys14 transcription factor. In conclusion, our results demonstrate that DhGzf3 can play a role as a negative GATA transcription factor when expressed in S. cerevisiae and that it most probably represents the only member of this family in D. hansenii. These findings also point to the GATA transcription factors as relevant elements for alkaline-pH tolerance. PMID:16896222

  13. Stereochemistry of new nitrogen containing heterocyclic aldehyde. Part XI. Novel ligational behaviour of quinoline as chelate ligand toward transition metal ions

    NASA Astrophysics Data System (ADS)

    El-Sonbati, A. Z.; Al-Shihri, A. S.; El-Bindary, A. A.

    2004-07-01

    Novel complexes of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II) and UO 2(II) with a new Schiff base derived from 8-hydroxy-7-quinolinecarboxaldehyde and 2-aminoethanethiol (LH 2) (system name: 2-(8-hydroxy-7-carboxalimino)ethanethiol.) have been prepared and characterized on the basis of analytical, thermal, magnetic moment, infrared, electronic, NMR and EPR spectral data. From the analytical, NMR and thermal data and stoichiometry of the complexes indicate that LH 2 act as a dibasic tridentate ligand with ONS donors towards all the metal ions. The magnetic moment, electronic and EPR spectral data commensurate that the Mn(II), Fe(II), Ni(II) and UO 2(II) complexes are dimeric with octahedral configuration while the Cu(II) and Zn(II) complexes are monomeric with square-planar and tetrahedral geometries, respectively. Various ligand field parameters Dq, B and β for complex 5 was calculated. The complexes 3+ 4 have lower symmetries and the amount of distortion in terms of DT/DQ applying NSH "Hamiltonian Theory" has been evaluated which indicate that the complexes are moderately distorted.

  14. Structural defects and chemical interaction of implanted ions with substrate structure in amorphous SiO2

    NASA Astrophysics Data System (ADS)

    Hosono, Hideo; Matsunami, Noriaki

    1993-11-01

    Structural defects in SiO2 glasses implanted with Li+, N+, O+, F+, Si+, and P+ ions were examined by vacuum-ultraviolet-absorption and electron-paramagnetic-resonance spectroscopies as well as thermal-gas-release analysis. The chemical interaction of implanted ions with substrate structure was considered on the basis of the obtained results. It is found that the type of predominant defects is controlled by the electronegative nature of implants. Silicon-silicon homobonds, which are oxygen-vacancy-type defects, are produced by electropositive implants (i.e., Li, P, and Si) at concentrations comparable to those of the implants. On the other hand, in the case of electronegative implants (F and O) O2 molecules and peroxy radicals (POR), both of which may be regarded as oxygen-interstitial-type defects, are the major defects and the total concentrations of these two defects are comparable to implant concentrations. These results indicate that chemical interaction of implanted ions with SiO2 is primarily controlled by the electronegative nature of implants. Electropositive implants (M) react chemically with oxygen atoms in the substrate structure to form M-O bonds, leaving Si-Si bonds. Electronegative implants (A) react chemically with silicon atoms to form Si-A bonds and oxygen atoms recoiled with implants combine with each other to form O2 molecules or react with the silica-network structure to form POR's. Concentrations of these predominant defects relative to implants can be used quantitatively to describe the strength of chemical interactions. When the chemical interaction is strong, both concentrations are comparable. On the other hand, when the chemical interaction is weak, concentrations of these defects are much smaller than those of implants because the major fraction of implants occur in a neutral state without forming chemical bonds with constituents of the substrate. Nitrogen is an example of this category and the major fraction of implanted nitrogen atoms

  15. The Final Merger of Massive Black Holes: Recoils, Gravitational Waves, and Electromagnetic Signatures

    NASA Technical Reports Server (NTRS)

    Centrella, Joan M.

    2010-01-01

    The final merger of two massive black holes produces a powerful burst of gravitational radiation, emitting more energy than all the stars in the observable universe combined. The resulting gravitational waveforms will be easily detectable by the space-based LISA out to redshifts z greater than 10, revealing the masses and spins of the black holes to high precision. If the merging black holes have unequal masses, or asymmetric spins, the final black hole that forms can recoil with a velocity exceeding 1000 km/s. And, when the black holes merge in the presence of gas and magnetic fields, various types of electromagnetic signals may also be produced. For more than 30 years, scientists have tried to compute black hole mergers using the methods of numerical relativity. The resulting computer codes have been plagued by instabilities, causing them to crash well before the black holes in the binary could complete even a single orbit. Within the past few years, however, this situation has changed dramatically, with a series of remarkable breakthroughs. This talk will focus on new results that are revealing the dynamics and waveforms of binary black hole mergers, recoil velocities, and the possibility of accompanying electromagnetic outbursts.

  16. Precision measurement of quenching factors for low-energy nuclear recoils at TUNL

    NASA Astrophysics Data System (ADS)

    Rich, Grayson; Barbeau, Phil; Howell, Calvin; Karwowski, Hugon

    2014-03-01

    With detector technologies becoming increasingly sensitive to exotic events, a thorough understanding of signal yield as a function of deposited energy is required for appropriate interpretation of results from cutting edge detector systems. Elastic neutron scattering is a probe which has been used to mimic the nuclear recoils which may be produced in detection media by light-WIMP interactions or coherent neutrino-nucleus scattering (CNS). We have built at the Triangle Universities Nuclear Laboratory (TUNL) a facility which produces pulsed, collimated, low-energy, quasi-monoenergetic neutron beams using the 7Li(p,n) reaction, resulting in fluxes of ~ 1 neutrons / (s . cm2) at ~90 cm from the neutron-production target. The first precision results from this facility are reported for ultra-low-energy recoils in NaI(Tl) and CsI(Na) and future plans are outlined, including measurements on candidate materials for a CNS detector that can potentially be fielded at the Spallation Neutron Source of Oak Ridge National Laboratory as a part the Coherent Scatter Initiative (CSI). We discuss the implications of new, precise measurements of quenching factors on neutrino detectors and on current- and next-generation light-WIMP searches, particularly the DAMA experiment.

  17. Analytic calculation of radiative-recoil corrections to muonium hyperfine splitting: Electron-line contribution

    SciTech Connect

    Eides, M.I.; Karshenboim, S.G.; Shelyuto, V.A. )

    1991-02-01

    The detailed account of analytic calculation of radiative-recoil correction to muonium hyperfine splitting, induced by electron-line radiative insertions, is presented. The consideration is performed in the framework of the effective two-particle formalism. A good deal of attention is paid to the problem of the divergence cancellation and the selection of graphs, relevant to radiative-recoil corrections. The analysis is greatly facilitated by use of the Fried-Yennie gauge for radiative photons. The obtained set of graphs turns out to be gauge-invariant and actual calculations are performed in the Feynman gauge. The main technical tricks, with the help of which we have effectively utilized the existence in the problem of the small parameter-mass ratio and managed to perform all calculations in the analytic form are described. The main intermediate results, as well as the final answer, {delta}E{sub rr} = ({alpha}({Zeta}{alpha})/{pi}{sup 2})(m/M)E{sub F}(6{zeta}(3) + 3{pi}{sup 2} In 2 + {pi}{sup 2}/2 + 17/8), are also presented.

  18. Hydrogen analysis for granite using proton-proton elastic recoil coincidence spectrometry.

    PubMed

    Komatsubara, T; Sasa, K; Ohshima, H; Kimura, H; Tajima, Y; Takahashi, T; Ishii, S; Yamato, Y; Kurosawa, M

    2008-07-01

    In an effort to develop DS02, a new radiation dosimetry system for the atomic bomb survivors of Hiroshima and Nagasaki, measurements of neutron-induced activities have provided valuable information to reconstruct the radiation situation at the time of the bombings. In Hiroshima, the depth profile of (152)Eu activity measured in a granite pillar of the Motoyasu Bridge (128 m from the hypocenter) was compared with that calculated using the DS02 methodology. For calculation of the (152)Eu production due to the thermal-neutron activation reaction, (151)Eu(n,gamma)(152)Eu, information on the hydrogen content in granite is important because the transport and slowing-down process of neutrons penetrating into the pillar is strongly affected by collisions with the protons of hydrogen. In this study, proton-proton elastic recoil coincidence spectrometry has been used to deduce the proton density in the Motoyasu pillar granite. Slices of granite samples were irradiated by a 20 MeV proton beam, and the energies of scattered and recoil protons were measured with a coincidence method. The water concentration in the pillar granite was evaluated to be 0.30 +/- 0.07%wt. This result is consistent with earlier data on adsorptive water (II) and bound water obtained by the Karl Fisher method. PMID:18509666

  19. Hydrogen analysis for granite using proton-proton elastic recoil coincidence spectrometry.

    PubMed

    Komatsubara, T; Sasa, K; Ohshima, H; Kimura, H; Tajima, Y; Takahashi, T; Ishii, S; Yamato, Y; Kurosawa, M

    2008-07-01

    In an effort to develop DS02, a new radiation dosimetry system for the atomic bomb survivors of Hiroshima and Nagasaki, measurements of neutron-induced activities have provided valuable information to reconstruct the radiation situation at the time of the bombings. In Hiroshima, the depth profile of (152)Eu activity measured in a granite pillar of the Motoyasu Bridge (128 m from the hypocenter) was compared with that calculated using the DS02 methodology. For calculation of the (152)Eu production due to the thermal-neutron activation reaction, (151)Eu(n,gamma)(152)Eu, information on the hydrogen content in granite is important because the transport and slowing-down process of neutrons penetrating into the pillar is strongly affected by collisions with the protons of hydrogen. In this study, proton-proton elastic recoil coincidence spectrometry has been used to deduce the proton density in the Motoyasu pillar granite. Slices of granite samples were irradiated by a 20 MeV proton beam, and the energies of scattered and recoil protons were measured with a coincidence method. The water concentration in the pillar granite was evaluated to be 0.30 +/- 0.07%wt. This result is consistent with earlier data on adsorptive water (II) and bound water obtained by the Karl Fisher method.

  20. Photodissociation of laboratory oriented molecules: Revealing molecular frame properties of nonaxial recoil

    SciTech Connect

    Brom, Alrik J. van den; Rakitzis, T. Peter; Janssen, Maurice H.M.

    2004-12-15

    We report the photodissociation of laboratory oriented OCS molecules. A molecular beam of OCS molecules is hexapole state-selected and spatially oriented in the electric field of a velocity map imaging lens. The oriented OCS molecules are dissociated at 230 nm with the linear polarization set at 45 deg. to the orientation direction of the OCS molecules. The CO({nu}=0,J) photofragments are quantum state-selectively ionized by the same 230 nm pulse and the angular distribution is measured using the velocity map imaging technique. The observed CO({nu}=0,J) images are strongly asymmetric and the degree of asymmetry varies with the CO rotational state J. From the observed asymmetry in the laboratory frame we can directly extract the molecular frame angles between the final photofragment recoil velocity and the permanent dipole moment and the transition dipole moment. The data for CO fragments with high rotational excitation reveal that the dissociation dynamics is highly nonaxial, even though conventional wisdom suggests that the nearly limiting {beta} parameter results from fast axial recoil dynamics. From our data we can extract the relative contribution of parallel and perpendicular transitions at 230 nm excitation.

  1. Recoil effects due to electron shake-off following the beta decay of 6 He

    NASA Astrophysics Data System (ADS)

    Drake, Gordon W. F.; Schulhoff, Eva

    2016-05-01

    There are currently several experiments in progress to search for new physics beyond the Standard Model by high precision studies of angular correlations in the β decay of the helium isotope 6He to form 6Li +e- +νe. After the β decay process, the atomic electrons of 6 Li+ adjust to the sudden change of nuclear charge from 2 to 3. We calculate the probabilities for electron shake-up and shake-off, including recoil effects, by the use of a Stieltjes imaging representation of the final states. A variety of sum rules provides tight consistency checks on the accuracy of the results. Results obtained previously indicate that there is a 7 σ disagreement between theory and experiment for the additional nuclear recoil induced by the emission of atomic shake-off electrons. This disagreement will be further studied, and the results extended to the 1 s 2 p3 P and metastable 1 s 2 s3 S states as initial states of 6 He before β-decay. Research supported by the Natural Sciences and Engineering Research Council of Canada.

  2. Dynamic Measurements of Hydrogen and Lithium Distributions in Lithium-Cobalt-Oxide Films with Charging and Heating Using Elastic Recoil Detection Techniques

    NASA Astrophysics Data System (ADS)

    Tsuchiya, B.; Morita, K.; Iriyama, Y.; Majima, T.; Tsuchida, H.

    The migrations of lithium (Li) as well as hydrogen (H) in multi-layers thin films of Au/LiCoO2 (thickness: approximately 42 nm/80 nm), deposited onto one face of Li1.4Ti2Si0.4P2.6O12-AlPO4 (LATP) substrates, were dynamically observed with electric charging as well as isochronal annealing in vacuum by combining elastic recoil detection (ERD) analysis with Rutherford backscattering spectrometry (RBS)with 9.0-MeV O4+ ion-probe beams. The ERD spectra clearly revealed that Li atoms of approximately 9.4 at% migrated from the LiCoO2 surface to the LiCoO2/LATP interface with H absorption by a charge of approximately 0.48 e/cm2, which the acquiredvoltage was1.65 V. In addition, the diffusion of Li atoms to the LATP bulk occurred with H release by isochronal annealing at only 323 K for 10 min.The presence of H significantly influences the Li+ ion conduction for the Li-battery systems.

  3. Production of Endohedral Fullerenes by Ion Implantation

    SciTech Connect

    Diener, M.D.; Alford, J. M.; Mirzadeh, S.

    2007-05-31

    The empty interior cavity of fullerenes has long been touted for containment of radionuclides during in vivo transport, during radioimmunotherapy (RIT) and radioimaging for example. As the chemistry required to open a hole in fullerene is complex and exceedingly unlikely to occur in vivo, and conformational stability of the fullerene cage is absolute, atoms trapped within fullerenes can only be released during extremely energetic events. Encapsulating radionuclides in fullerenes could therefore potentially eliminate undesired toxicity resulting from leakage and catabolism of radionuclides administered with other techniques. At the start of this project however, methods for production of transition metal and p-electron metal endohedral fullerenes were completely unknown, and only one method for production of endohedral radiofullerenes was known. They therefore investigated three different methods for the production of therapeutically useful endohedral metallofullerenes: (1) implantation of ions using the high intensity ion beam at the Oak Ridge National Laboratory (ORNL) Surface Modification and Characterization Research Center (SMAC) and fullerenes as the target; (2) implantation of ions using the recoil energy following alpha decay; and (3) implantation of ions using the recoil energy following neutron capture, using ORNL's High Flux Isotope Reactor (HFIR) as a thermal neutron source. While they were unable to obtain evidence of successful implantation using the ion beam at SMAC, recoil following alpha decay and neutron capture were both found to be economically viable methods for the production of therapeutically useful radiofullerenes. In this report, the procedures for preparing fullerenes containing the isotopes {sup 212}Pb, {sup 212}Bi, {sup 213}Bi, and {sup 177}Lu are described. None of these endohedral fullerenes had ever previously been prepared, and all of these radioisotopes are actively under investigation for RIT. Additionally, the chemistry for

  4. Compact RF ion source for industrial electrostatic ion accelerator

    NASA Astrophysics Data System (ADS)

    Kwon, Hyeok-Jung; Park, Sae-Hoon; Kim, Dae-Il; Cho, Yong-Sub

    2016-02-01

    Korea Multi-purpose Accelerator Complex is developing a single-ended electrostatic ion accelerator to irradiate gaseous ions, such as hydrogen and nitrogen, on materials for industrial applications. ELV type high voltage power supply has been selected. Because of the limited space, electrical power, and robust operation, a 200 MHz RF ion source has been developed. In this paper, the accelerator system, test stand of the ion source, and its test results are described.

  5. Compact RF ion source for industrial electrostatic ion accelerator.

    PubMed

    Kwon, Hyeok-Jung; Park, Sae-Hoon; Kim, Dae-Il; Cho, Yong-Sub

    2016-02-01

    Korea Multi-purpose Accelerator Complex is developing a single-ended electrostatic ion accelerator to irradiate gaseous ions, such as hydrogen and nitrogen, on materials for industrial applications. ELV type high voltage power supply has been selected. Because of the limited space, electrical power, and robust operation, a 200 MHz RF ion source has been developed. In this paper, the accelerator system, test stand of the ion source, and its test results are described.

  6. A gas ionisation detector in the axial (Bragg) geometry used for the time-of-flight elastic recoil detection analysis.

    PubMed

    Siketić, Zdravko; Skukan, Natko; Bogdanović Radović, Iva

    2015-08-01

    In this paper, time-of-flight elastic recoil detection analysis spectrometer with a newly constructed gas ionization detector for energy detection is presented. The detector is designed in the axial (Bragg) geometry with a 3 × 3 array of 50 nm thick Si3N4 membranes as an entrance window. 40 mbar isobutane gas was sufficient to stop a 30 MeV primary iodine beam as well as all recoils in the detector volume. Spectrometer and detector performances were determined showing significant improvement in the mass and energy resolution, respectively, comparing to the spectrometer with a standard silicon particle detector for an energy measurement.

  7. A gas ionisation detector in the axial (Bragg) geometry used for the time-of-flight elastic recoil detection analysis

    SciTech Connect

    Siketić, Zdravko; Skukan, Natko; Bogdanović Radović, Iva

    2015-08-15

    In this paper, time-of-flight elastic recoil detection analysis spectrometer with a newly constructed gas ionization detector for energy detection is presented. The detector is designed in the axial (Bragg) geometry with a 3 × 3 array of 50 nm thick Si{sub 3}N{sub 4} membranes as an entrance window. 40 mbar isobutane gas was sufficient to stop a 30 MeV primary iodine beam as well as all recoils in the detector volume. Spectrometer and detector performances were determined showing significant improvement in the mass and energy resolution, respectively, comparing to the spectrometer with a standard silicon particle detector for an energy measurement.

  8. A gas ionisation detector in the axial (Bragg) geometry used for the time-of-flight elastic recoil detection analysis

    NASA Astrophysics Data System (ADS)

    Siketić, Zdravko; Skukan, Natko; Bogdanović Radović, Iva

    2015-08-01

    In this paper, time-of-flight elastic recoil detection analysis spectrometer with a newly constructed gas ionization detector for energy detection is presented. The detector is designed in the axial (Bragg) geometry with a 3 × 3 array of 50 nm thick Si3N4 membranes as an entrance window. 40 mbar isobutane gas was sufficient to stop a 30 MeV primary iodine beam as well as all recoils in the detector volume. Spectrometer and detector performances were determined showing significant improvement in the mass and energy resolution, respectively, comparing to the spectrometer with a standard silicon particle detector for an energy measurement.

  9. Theory of Bound-Electron g Factor in Highly Charged Ions

    SciTech Connect

    Shabaev, V. M.; Glazov, D. A.; Plunien, G.; Volotka, A. V.

    2015-09-15

    The paper presents the current status of the theory of bound-electron g factor in highly charged ions. The calculations of the relativistic, quantum electrodynamics (QED), nuclear recoil, nuclear structure, and interelectronic-interaction corrections to the g factor are reviewed. Special attention is paid to tests of QED effects at strong coupling regime and determinations of the fundamental constants.

  10. Ion Momentum Imaging of Dissociative Electron Attachment to Small Molecules

    NASA Astrophysics Data System (ADS)

    Fogle, Michael

    2015-09-01

    In recent years, low energy dissociative electron attachment (DEA) interactions have been of interest to varying biological and technological applications. To study the dynamics resulting from DEA, we used an ion-momentum imaging apparatus based on the Cold Target Recoil Ion Momentum Spectroscopy (COLTRIMS) technique in which a molecular beam is crossed by a pulsed electron beam. The beam interaction takes place in a 4 π pulsed electrostatic spectrometer that collects the anion fragments resulting from DEA. The molecular beam is formed by a supersonic expansion which results in a well-localized and cold target. Using this apparatus we have investigated the DEA dynamics for several small molecules: CO2 at the 4 eV shape resonance and the 8 eV Feshbach resonance; N2O at the 2.3 eV shape resonance; HCCH at the 3 eV shape resonance; and CF4 near the 7 eV resonance. An overview of these experimental ion-momentum results will be compared to ab initio electronic structure and fixed-nuclei scattering calculations to gauge the resulting dynamics driven by DEA. In many cases, conical intersections play a pivotal role in driving the dynamics. Some of these systems exhibit non-axial recoil conditions indicative of a bending dynamics in the transitory negative ion state while others exhibit a direct axial recoil dissociation without any bending. This work is supported by the National Science Foundation under Contract NSF-PHYS1404366.

  11. A RUNAWAY BLACK HOLE IN COSMOS: GRAVITATIONAL WAVE OR SLINGSHOT RECOIL?

    SciTech Connect

    Civano, F.; Elvis, M.; Lanzuisi, G.; Hao, H.; Aldcroft, T.; Jahnke, K.; Zamorani, G.; Comastri, A.; Bolzonella, M.; Blecha, L.; Loeb, A.; Bongiorno, A.; Brusa, M.; Leauthaud, A.; Mainieri, V.; Piconcelli, E.; Salvato, M.; Scoville, N.; Trump, J.; Vignali, C.

    2010-07-01

    We present a detailed study of a peculiar source detected in the COSMOS survey at z = 0.359. Source CXOC J100043.1+020637, also known as CID-42, has two compact optical sources embedded in the same galaxy. The distance between the two, measured in the HST/ACS image, is 0.''495 {+-} 0.''005 that, at the redshift of the source, corresponds to a projected separation of 2.46 {+-} 0.02 kpc. A large ({approx}1200 km s{sup -1}) velocity offset between the narrow and broad components of H{beta} has been measured in three different optical spectra from the VLT/VIMOS and Magellan/IMACS instruments. CID-42 is also the only X-ray source in COSMOS, having in its X-ray spectra a strong redshifted broad absorption iron line and an iron emission line, drawing an inverted P-Cygni profile. The Chandra and XMM-Newton data show that the absorption line is variable in energy by {Delta}E = 500 eV over four years and that the absorber has to be highly ionized in order not to leave a signature in the soft X-ray spectrum. That these features-the morphology, the velocity offset, and the inverted P-Cygni profile-occur in the same source is unlikely to be a coincidence. We envisage two possible explanations, both exceptional, for this system: (1) a gravitational wave (GW) recoiling black hole (BH), caught 1-10 Myr after merging; or (2) a Type 1/Type 2 system in the same galaxy where the Type 1 is recoiling due to the slingshot effect produced by a triple BH system. The first possibility gives us a candidate GW recoiling BH with both spectroscopic and imaging signatures. In the second case, the X-ray absorption line can be explained as a BAL-like outflow from the foreground nucleus (a Type 2 AGN) at the rearer one (a Type 1 AGN), which illuminates the otherwise undetectable wind, giving us the first opportunity to show that fast winds are present in obscured active galactic nuclei (AGNs), and possibly universal in AGNs.

  12. The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF

    SciTech Connect

    Casey, D. T.; Frenje, J. A.; Gatu Johnson, M.; Seguin, F. H.; Li, C. K.; Petrasso, R. D.; Glebov, V. Yu.; Katz, J.; Magoon, J.; Meyerhofer, D. D.; Sangster, T. C.; Shoup, M.; Ulreich, J.; Ashabranner, R. C.; Bionta, R. M.; Carpenter, A. C.; Felker, B.; Khater, H. Y.; LePape, S.; MacKinnon, A.; McKernan, M. A.; Moran, M.; Rygg, J. R.; Yeoman, M. F.; Zacharias, R.; Leeper, R. J.; Fletcher, K.; Farrell, M.; Jasion, D.; Kilkenny, J.; Paguio, R.

    2013-04-18

    The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, iontemperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

  13. Stability diagram of the collective atomic recoil laser with thermal atoms

    NASA Astrophysics Data System (ADS)

    Tomczyk, H.; Schmidt, D.; Georges, C.; Slama, S.; Zimmermann, C.

    2015-06-01

    We experimentally investigate cold thermal atoms in a single sidedly pumped optical ring resonator for temperatures between 0.4 and 9 μ K . The threshold for collective atomic recoil lasing (CARL) is recorded for various pump-cavity detunings. The resulting stability diagram is interpreted by simulating the classical CARL equations. We find that the stability diagram for thermal atoms shows the same asymmetry as observed for Bose-Einstein condensates in previous experiments. Whereas for condensates the asymmetry is well explained by a Dicke-type quantum model we here discuss a simplified classical model. It complements the quantum model and provides an intuitive explanation based on the change in the long-range atomic interaction with pump-cavity detuning.

  14. First measurements of the absolute neutron spectrum using the Magnetic Recoil Spectrometer (MRS) at the NIF

    NASA Astrophysics Data System (ADS)

    Frenje, J.; Casey, D.; Li, C.; Seguin, F.; Petrasso, R.; Bionta, R.; Cerjan, C.; Eckart, M.; Haan, S.; Hatchett, S.; Khater, H.; Landen, O.; MacKinnon, A.; Moran, M.; Rygg, J.; Kilkenny, J.; Glebov, V.; Sangster, T.; Meyerhofer, D.; Magoon, J.; Fletcher, K.; Leeper, R.

    2010-11-01

    Proper assembly of capsule mass, as manifested through evolution of fuel areal density (ρR), is fundamentally important for achieving hot-spot ignition planned at the National Ignition Facility (NIF). Experimental information about ρR and ρR asymmetries, Ti and yield is therefore essential for understanding how this assembly occurs. To obtain this information, a neutron spectrometer, called the Magnetic-Recoil Spectrometer (MRS) has been implemented on the NIF. Its primary objective is to measure the absolute neutron spectrum in the range 5 to 30 MeV, from which ρR, Ti and yield can be directly inferred for both low-yield tritium-hydrogen-deuterium (THD) and high-yield DT implosions. In this talk, the results from the first measurements of the absolute neutron spectrum produced in exploding pusher and THD implosions will be presented. This work was supported in part by the U.S. DOE, LLNL and LLE.

  15. Development of a compact magnetic proton recoil spectrometer for measurement of deuterium-tritium neutrons

    SciTech Connect

    Zhang, Jianfu Ouyang, Xiaoping; Zhang, Xianpeng; Qiu, Suizheng; Zhang, Guoguang; Ruan, Jinlu; Zhang, Xiaodong; Yang, Shaohua; Song, Jiwen; Liu, Linyue; Li, Hongyun

    2015-12-15

    A new compact magnetic proton recoil (MPR) neutron spectrometer has been designed for precise measurement of deuterium-tritium (DT) neutrons. This design is presented emphasizing the magnetic analyzing system, which is based on a compact quadrupole-dipole (QD) electromagnet. The focal plane detector (FPD) is also discussed with respect to application for the next step. The characteristics of the MPR spectrometer were calculated by using Monte Carlo simulation. A preliminary experiment was performed to test the magnetic analyzing system and the proton images of the FPD. Since the QD electromagnet design allows for a larger foil thickness and solid angle to be utilized, the MPR spectrometer defined in this paper can achieve neutron detection efficiency more than 5 × 10{sup −7} at an energy resolution of 1.5% for measuring DT neutrons.

  16. Three-Loop Radiative-Recoil Corrections to Hyperfine Splitting in Muonium: Diagrams with Polarization Loops

    SciTech Connect

    Eides, Michael I.; Shelyuto, Valery A.

    2009-09-25

    We consider three-loop radiative-recoil corrections to hyperfine splitting in muonium generated by the diagrams with electron and muon vacuum polarizations. We calculate single-logarithmic and nonlogarithmic contributions of order alpha{sup 3}(m/M)E{sub F} generated by gauge invariant sets of diagrams with electron and muon polarization insertions in the electron and muon factors. Combining these corrections with the older results, we obtain total contribution to hyperfine splitting generated by all diagrams with electron and muon polarization loops. The calculation of this contribution completes an important stage in the implementation of the program of reduction of the theoretical uncertainty of hyperfine splitting below 10 Hz. The new results improve the theory of hyperfine splitting and affect the value of the electron-muon mass ratio extracted from experimental data on muonium hyperfine splitting.

  17. Neutron scattering facility for the calibration of the response to nuclear recoils

    NASA Astrophysics Data System (ADS)

    Jochum, J.; Chambon, B.; Drain, D.; von Feilitzsch, F.; Gascon, J.; Huber, M.; Jagemann, T.; de Jésus, M.; Lachenmaier, T.; Lanfranchi, J.-C.; Martineau, O.; Potzel, W.; Rüdig, A.; Schnagl, J.; Simon, E.; Stark, M.; Stern, M.; Wulandari, H.

    2002-02-01

    A possibility to search for elementary particles as dark matter candidates is to detect elastic scattering with cryogenic detectors. For the interpretation of the data one has to determine the detector response to nuclear recoils, the so-called quenching factors. They can differ for the heat-, for the scintillation- and for the ionization-signal and can be measured by scattering of neutrons. The CRESST- and the EDELWEISS-collaborations have set up a neutron scattering facility for cryogenic detectors at the tandem-accelerator of the Munich `Maier-Leibniz-Labor.' The scattering angle and the time-of-flight of the neutrons are measured by an array of liquid scintillator cells. The pulsed high energy (11 MeV) neutron beam is created by nuclear reaction of a 11B on a H2-gas target. The set-up and the results of first tests are presented. .

  18. The B {r{underscore}arrow} D*{ell}{nu} form factor at zero recoil

    SciTech Connect

    Simone, J.N.; Hashimoto, S.; El-Khadra, A.X.; Kronfeld, A.S.; Mackenzie, P.B.; Ryan, S.M.

    2000-01-26

    The authors describe a model independent lattice QCD method for determining the deviation from unity for h{sub A{sub 1}}, the B {r{underscore}arrow} D*{ell}{nu} form factor at zero recoil. They extend the double ratio method previously used to determine the B {r{underscore}arrow} D{ell}{nu} form factor. The bulk of statistical and systematic errors cancel in the double ratios they consider, yielding form factors which promise to reduce present theoretical uncertainties in the determination of {vert{underscore}bar}V{sub cb}{vert{underscore}bar}. They present results from a prototype calculation at a single lattice spacing corresponding to {beta} = 5.7.

  19. Superradiant rayleigh scattering and collective atomic recoil lasing in a ring cavity.

    PubMed

    Slama, S; Bux, S; Krenz, G; Zimmermann, C; Courteille, Ph W

    2007-02-01

    Collective interaction of light with an atomic gas can give rise to superradiant instabilities. We experimentally study the sudden buildup of a reverse light field in a laser-driven high-finesse ring cavity filled with ultracold thermal or Bose-Einstein condensed atoms. While superradiant Rayleigh scattering from atomic clouds is normally observed only at very low temperatures (i.e., well below 1 microK), the presence of the ring cavity enhances cooperativity and allows for superradiance with thermal clouds as hot as several 10 microK. A characterization of the superradiance at various temperatures and cooperativity parameters allows us to link it to the collective atomic recoil laser.

  20. Doppler- and recoil-free laser excitation of Rydberg states via three-photon transitions

    SciTech Connect

    Ryabtsev, I. I.; Beterov, I. I.; Tretyakov, D. B.; Entin, V. M.; Yakshina, E. A.

    2011-11-15

    Three-photon laser excitation of Rydberg states by three different laser beams can be arranged in a starlike geometry that simultaneously eliminates the recoil effect and Doppler broadening. Our analytical and numerical calculations for a particular laser excitation scheme 5S{sub 1/2}{yields}5P{sub 3/2}{yields}6S{sub 1/2}{yields}nP in Rb atoms have shown that, compared to the one- and two-photon laser excitation, this approach provides much narrower linewidth and longer coherence time for both cold atom samples and hot vapors, if the intermediate one-photon resonances of the three-photon transition are detuned by more than respective single-photon Doppler widths. This method can be used to improve fidelity of Rydberg quantum gates and precision of spectroscopic measurements in Rydberg atoms.