Surface and adsorbate structural analysis from time-of-flight scattering and recoiling spectrometry (TOF-SARS)

NASA Astrophysics Data System (ADS)

Rabalais, J. W.; Bu, H.; Roux, C.

1992-02-01

The methods of obtaining surface structural information from low energy ion scattering spectrometry are described. These methods include measurements of backscattering, forwardscattering, and recoiling intensities vs beam incident α, beam exit β, crystal azimuthal δ, and scattering Θ angles. References are provided which give examples of each different kind of measurement. The technique of time-of-flight scattering and recoiling spectrometry (TOF-SARS), which collects both scattered.and recoiled neutrals and ions simultaneously, is described. TOF-SARS data for the three surface phases, clean Ni{110}-(1 × 1), Ni{110}-(1 × 2)-H missing row, and Ni{110}-(2 × 1)-O missing row, are used to illustrate some of the structural measurements.

The negative ions emission in nitrogen

NASA Technical Reports Server (NTRS)

Soon, W. H.; Kunc, J. A.

1991-01-01

The contribution of negative atomic ions to continuum radiation in nitrogen plasma is discussed. It is shown that both unstable N(-)(3P) and metastable N(-)(1D) ions have a significant effect on the total production of the continuum radiation at electron temperatures below 12,000 K.

Energetic Nitrogen Ions within the Inner Magnetosphere of Saturn

NASA Astrophysics Data System (ADS)

Sittler, E. C.; Johnson, R. E.; Richardson, J. D.; Jurac, S.; Moore, M.; Cooper, J. F.; Mauk, B. H.; Smith, H. T.; Michael, M.; Paranicus, C.; Armstrong, T. P.; Tsurutani, B.; Connerney, J. E. P.

2003-05-01

Titan's interaction with Saturn's magnetosphere will result in the energetic ejection of atomic nitrogen atoms into Saturn's magnetosphere due to dissociation of N2 by electrons, ions, and UV photons. The ejection of N atoms into Saturn's magnetosphere will form a nitrogen torus around Saturn with mean density of about 4 atoms/cm3 with source strength of 4.5x1025 atoms/sec. These nitrogen atoms are ionized by photoionization, electron impact ionization and charge exchange reactions producing an N+ torus of 1-4 keV suprathermal ions centered on Titan's orbital position. We will show Voyager plasma observations that demonstrate presence of a suprathermal ion component within Saturn's outer magnetosphere. The Voyager LECP data also reported the presence of inward diffusing energetic ions from the outer magnetosphere of Saturn, which could have an N+ contribution. If so, when one conserves the first and second adiabatic invariant the N+ ions will have energies in excess of 100 keV at Dione's L shell and greater than 400 keV at Enceladus' L shell. Energetic charged particle radial diffusion coefficients are also used to constrain the model results. But, one must also consider the solar wind as another important source of keV ions, in the form of protons and alpha particles, for Saturn's outer magnetosphere. Initial estimates indicate that a solar wind source could dominate in the outer magnetosphere, but various required parameters for this estimate are highly uncertain and will have to await Cassini results for confirmation. We show that satellite sweeping and charged particle precipitation within the middle and outer magnetosphere will tend to enrich N+ ions relative to protons within Saturn's inner magnetosphere as they diffuse radially inward for radial diffusion coefficients that do not violate observations. Charge exchange reactions within the inner magnetosphere can be an important loss mechanism for O+ ions, but to a lesser degree for N+ ions. Initial LECP

Detector Calibration to Spontaneous Fission for the Study of Superheavy Elements Using Gas-Filled Recoil Ion Separator

NASA Astrophysics Data System (ADS)

Takeyama, Mirei; Kaji, Daiya; Morimoto, Kouji; Wakabayashi, Yasuo; Tokanai, Fuyuki; Morita, Kosuke

Detector response to spontaneous fission (SF) of heavy nuclides produced in the 206Pb(48Ca,2n)252No reaction was investigated using a gas-filled recoil ion separator (GARIS). Kinetic energy distributions of the SF originating from 252No were observed by tuning implantation depth of evaporation residue (ER) to the detector. The focal plane detector used in the GARIS experiments was well calibrated by comparing with the known total kinetic energy (TKE) of SF due to 252No. The correction value for the TKE calculation was deduced as a function of the implantation depth of 252No to the detector. Furthermore, we have investigated the results by comparing with those obtained by a computer simulation using the particle and heavy ion transport code system (PHITS).

Four pi-recoil proportional counter used as neutron spectrometer

NASA Technical Reports Server (NTRS)

Bennett, E. F.

1968-01-01

Study considers problems encountered in using 4 pi-recoil counters for neutron spectra measurement. Emphasis is placed on calibration, shape discrimination, variation of W, the average energy loss per ion pair, and the effects of differentiation on the intrinsic counter resolution.

Complementary use of ion beam elastic backscattering and recoil detection analysis for the precise determination of the composition of thin films made of light elements

NASA Astrophysics Data System (ADS)

Climent-Font, A.; Cervera, M.; Hernández, M. J.; Muñoz-Martín, A.; Piqueras, J.

2008-04-01

Rutherford backscattering spectrometry (RBS) is a well known powerful technique to obtain depth profiles of the constituent elements in a thin film deposited on a substrate made of lighter elements. In its standard use the probing beam is typically 2 MeV He. Its capabilities to obtain precise composition profiles are severely diminished when the overlaying film is made of elements lighter than the substrate. In this situation the analysis of the energy of the recoiled element from the sample in the elastic scattering event, the ERDA technique may be advantageous. For the detection of light elements it is also possible to use beams at specific energies producing elastic resonances with these light elements to be analyzed, with a much higher scattering cross sections than the Rutherford values. This technique may be called non-RBS. In this work we report on the complementary use of ERDA with a 30 MeV Cl beam and non-RBS with 1756 keV H ions to characterize thin films made of boron, carbon and nitrogen (BCN) deposited on Si substrates.

Rutherford forward scattering and elastic recoil detection (RFSERD) as a method for characterizing ultra-thin films

DOE PAGES

Lohn, Andrew J.; Doyle, Barney L.; Stein, Gregory J.; ...

2014-04-03

We present a novel ion beam analysis technique combining Rutherford forward scattering and elastic recoil detection (RFSERD) and demonstrate its ability to increase efficiency in determining stoichiometry in ultrathin (5-50 nm) films as compared to Rutherford backscattering. In the conventional forward geometries, scattering from the substrate overwhelms the signal from light atoms but in RFSERD, scattered ions from the substrate are ranged out while forward scattered ions and recoiled atoms from the thin film are simultaneously detected in a single detector. Lastly, the technique is applied to tantalum oxide memristors but can be extended to a wide range of materialsmore » systems.« less

Measurement of Scintillation and Ionization Yield and Scintillation Pulse Shape from Nuclear Recoils in Liquid Argon

DOE PAGES

Cao, H.

2015-05-26

We have measured the scintillation and ionization yield of recoiling nuclei in liquid argon as a function of applied electric field by exposing a dual-phase liquid argon time projection chamber (LAr-TPC) to a low energy pulsed narrow band neutron beam produced at the Notre Dame Institute for Structure and Nuclear Astrophysics. Liquid scintillation counters were arranged to detect and identify neutrons scattered in the TPC and to select the energy of the recoiling nuclei. We also report measurements of the scintillation yields for nuclear recoils with energies from 10.3 to 57.3 keV and for median applied electric fields from 0more » to 970 V/cm. For the ionization yields, we report measurements from 16.9 to 57.3 keV and for electric fields from 96.4 to 486 V/cm. Furthermore, we report the observation of an anticorrelation between scintillation and ionization from nuclear recoils, which is similar to the anticorrelation between scintillation and ionization from electron recoils. Assuming that the energy loss partitions into excitons and ion pairs from 83mKr internal conversion electrons is comparable to that from 207Bi conversion electrons, we obtained the numbers of excitons (N ex) and ion pairs (N i) and their ratio (N ex/N i) produced by nuclear recoils from 16.9 to 57.3 keV. Motivated by arguments suggesting direction sensitivity in LAr-TPC signals due to columnar recombination, a comparison of the light and charge yield of recoils parallel and perpendicular to the applied electric field is presented for the first time.« less

Interpreting Recoil for Undergraduate Students

NASA Astrophysics Data System (ADS)

Elsayed, Tarek A.

2012-04-01

The phenomenon of recoil is usually explained to students in the context of Newton's third law. Typically, when a projectile is fired, the recoil of the launch mechanism is interpreted as a reaction to the ejection of the smaller projectile. The same phenomenon is also interpreted in the context of the conservation of linear momentum, which is closely related to Newton's third law. Since the actual microscopic causes of recoil differ from one problem to another, some students (and teachers) may not be satisfied with understanding recoil through the principles of conservation of linear momentum and Newton's third law. For these students, the origin of the recoil motion should be presented in more depth.

Time-of-flight scattering and recoiling spectrometer (TOF-SARS) for surface analysis

NASA Astrophysics Data System (ADS)

Grizzi, O.; Shi, M.; Bu, H.; Rabalais, J. W.

1990-02-01

A UHV spectrometer system has been designed and constructed for time-of-flight scattering and recoiling spectrometry (TOF-SARS). The technique uses a pulsed primary ion beam and TOF methods for analysis of both scattered and recoiled neutrals (N) and ions (I) simultaneously with continuous scattering angle variation over a flight path of ≊1 m. The pulsed ion beam line uses an electron impact ionization source with acceleration up to 5 keV; pulse widths down to 20 ns with average current densities of 0.05-5.0 nA/mm2 have been obtained. Typical current densities used herein are ≊0.1 nA/mm2 and TOF spectra can be collected with a total ion dose of <10-3 ions/surface atom. A channel electron multiplier detector, which is sensitive to both ions and fast neutrals, is mounted on a long tube connected to a precision rotary motion feedthru, allowing continuous rotation over a scattering angular range 0°<θ<165°. The sample is mounted on a precision manipulator, allowing azimuthal δ and incident α angle rotation, as well as translation along three orthogonal axes. The system also accommodates standard surface analysis instrumentation for LEED, AES, XPS, and UPS. The capabilities of the system are demonstrated by the following examples: (A) TOF spectra versus scattering angle θ; (B) comparison to LEED and AES; (C) surface and adsorbate structure determinations; (D) monitoring surface roughness; (E) surface semichanneling measurements; (F) measurements of scattered ion fractions; and (G) ion induced Auger electron emission.

Long-range effect in nitrogen ion-implanted AISI 316L stainless steel

NASA Astrophysics Data System (ADS)

Budzynski, P.

2015-01-01

The effect of nitrogen ion implantation on AISI 316L stainless steel was investigated. The microstructure and composition of an N implanted layer were studied by RBS, GIXRD, SEM, and EDX measurements. Friction and wear tests were also performed. The discrepancy between the measured and calculated stopped ion maximum range does not exceed 0.03 μm. After nitrogen implantation with a fluence of 5 × 1017 ion/cm2, additional phases of expanded austenite were detected. At a 5-fold larger depth than the maximum ion range, improvement in the coefficient of friction and wear was detected. We have shown, for the first time, the long-range effect in tribological investigations. The long-range effect is caused by movement of not only defects along the depth of the sample, as assumed so far, but also nitrogen atoms.

Universal Binding and Recoil Corrections to Bound State g Factors in Hydrogenlike Ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eides, Michael I.; Martin, Timothy J. S.

2010-09-03

The leading relativistic and recoil corrections to bound state g factors of particles with arbitrary spin are calculated. It is shown that these corrections are universal for any spin and depend only on the free particle gyromagnetic ratios. To prove this universality we develop nonrelativistic quantum electrodynamics (NRQED) for charged particles with an arbitrary spin. The coefficients in the NRQED Hamiltonian for higher spin particles are determined only by the requirements of Lorentz invariance and local charge conservation in the respective relativistic theory. For spin one charged particles, the NRQED Hamiltonian follows from the renormalizable QED of the charged vectormore » bosons. We show that universality of the leading relativistic and recoil corrections can be explained with the help of the Bargmann-Michael-Telegdi equation.« less

Collisional entanglement fidelities in quantum plasmas including strong quantum recoil and oscillation effects

NASA Astrophysics Data System (ADS)

Lee, Myoung-Jae; Jung, Young-Dae

2017-10-01

The quantum recoil and oscillation effects on the entanglement fidelity and the electron-exchange function for the electron-ion collision are investigated in a semiconductor plasma by using the partial wave analysis and effective interaction potential in strong quantum recoil regime. The magnitude of the electron-exchange function is found to increase as the collision energy increases, but it decreases with an increase in the exchange parameter. It is also found that the collisional entanglement fidelity in strong quantum recoil plasmas is enhanced by the quantum-mechanical and shielding effects. The collisional entanglement fidelity in a semiconductor plasma is also enhanced by the collective plasmon oscillation and electron-exchange effect. However, the electron-exchange effect on the fidelity ratio function is reduced as the plasmon energy increases. Moreover, the electron-exchange influence on the fidelity ratio function is found to increase as the Fermi energy in the semiconductor plasma increases.

Nitrogen ion implantation into various materials using 28 GHz electron cyclotron resonance ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shin, Chang Seouk; School of Mechanical Engineering, Pusan National University, Pusan 609-735; Lee, Byoung-Seob

2016-02-15

The installation of the 28 GHz electron cyclotron resonance ion source (ECRIS) ion implantation beamline was recently completed at the Korea Basic Science Institute. The apparatus contains a beam monitoring system and a sample holder for the ion implantation process. The new implantation system can function as a multipurpose tool since it can implant a variety of ions, ranging hydrogen to uranium, into different materials with precise control and with implantation areas as large as 1–10 mm{sup 2}. The implantation chamber was designed to measure the beam properties with a diagnostic system as well as to perform ion implantation withmore » an in situ system including a mass spectrometer. This advanced implantation system can be employed in novel applications, including the production of a variety of new materials such as metals, polymers, and ceramics and the irradiation testing and fabrication of structural and functional materials to be used in future nuclear fusion reactors. In this investigation, the first nitrogen ion implantation experiments were conducted using the new system. The 28 GHz ECRIS implanted low-energy, multi-charged nitrogen ions into copper, zinc, and cobalt substrates, and the ion implantation depth profiles were obtained. SRIM 2013 code was used to calculate the profiles under identical conditions, and the experimental and simulation results are presented and compared in this report. The depths and ranges of the ion distributions in the experimental and simulation results agree closely and demonstrate that the new system will enable the treatment of various substrates for advanced materials research.« less

Recoil-α-fission and recoil-α-α-fission events observed in the reaction 48Ca + 243Am

NASA Astrophysics Data System (ADS)

Forsberg, U.; Rudolph, D.; Andersson, L.-L.; Di Nitto, A.; Düllmann, Ch. E.; Fahlander, C.; Gates, J. M.; Golubev, P.; Gregorich, K. E.; Gross, C. J.; Herzberg, R.-D.; Heßberger, F. P.; Khuyagbaatar, J.; Kratz, J. V.; Rykaczewski, K.; Sarmiento, L. G.; Schädel, M.; Yakushev, A.; Åberg, S.; Ackermann, D.; Block, M.; Brand, H.; Carlsson, B. G.; Cox, D.; Derkx, X.; Dobaczewski, J.; Eberhardt, K.; Even, J.; Gerl, J.; Jäger, E.; Kindler, B.; Krier, J.; Kojouharov, I.; Kurz, N.; Lommel, B.; Mistry, A.; Mokry, C.; Nazarewicz, W.; Nitsche, H.; Omtvedt, J. P.; Papadakis, P.; Ragnarsson, I.; Runke, J.; Schaffner, H.; Schausten, B.; Shi, Yue; Thörle-Pospiech, P.; Torres, T.; Traut, T.; Trautmann, N.; Türler, A.; Ward, A.; Ward, D. E.; Wiehl, N.

2016-09-01

Products of the fusion-evaporation reaction 48Ca + 243Am were studied with the TASISpec set-up at the gas-filled separator TASCA at the GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt, Germany. Amongst the detected thirty correlated α-decay chains associated with the production of element Z = 115, two recoil-α-fission and five recoil- α- α-fission events were observed. The latter five chains are similar to four such events reported from experiments performed at the Dubna gas-filled separator, and three such events reported from an experiment at the Berkeley gas-filled separator. The four chains observed at the Dubna gas-filled separator were assigned to start from the 2n-evaporation channel 289115 due to the fact that these recoil- α- α-fission events were observed only at low excitation energies. Contrary to this interpretation, we suggest that some of these recoil- α- α-fission decay chains, as well as some of the recoil- α- α-fission and recoil-α-fission decay chains reported from Berkeley and in this article, start from the 3n-evaporation channel 288115.

Coupling of the recoil mass spectrometer CAMEL to the γ-ray spectrometer GASP

NASA Astrophysics Data System (ADS)

Spolaore, P.; Ackermann, D.; Bednarczyk, P.; De Angelis, G.; Napoli, D.; Rossi Alvarez, C.; Bazzacco, D.; Burch, R.; Müller, L.; Segato, G. F.; Scarlassara, F.

1995-02-01

A project has been realized to link the CAMEL recoil mass spectrometer to the GASP γ-spectrometer in order to perform high resolution and efficiency γ-recoil coincidence measurements. To preserve high flexibility and autonomy in the operation of the two complex apparatus a rough factor two of reduction in the overall heavy ion transmission was accepted in designing the optics of the particle transport from the GASP center to the CAMEL focal plane. The coupled configuration has been tested with the fusion reaction 58Ni (E = 212 MeV) + 64Ni, obtaining a mass resolution of {1}/{300} and efficiency between ˜ 11% and ˜ 15% for different evaporation products.

Recoil-free Fraction in Amorphous and Nanocrystalline Aluminium Based Alloys

NASA Astrophysics Data System (ADS)

Sitek, Jozef

2008-10-01

Aluminium based rapidly quenched alloys of nominal composition Al90Fe7Nb3 and Al94Fe2V4 were studied by Mössbauer spectroscopy. We have measured the recoil-free fraction and thermal shift at room and liquid nitrogen temperature. The frequency modes of atomic vibrations were determined and consequently the characteristic Debye temperature was derived. Characteristic temperature calculated from f-factor was lower than those fitted from second order Doppler shift. This indicates the presence of different frequency modes for amorphous and nanocrystalline states.

A stretch/compress scheme for a high temporal resolution detector for the magnetic recoil spectrometer time (MRSt)

DOE PAGES

Hilsabeck, T. J.; Frenje, J. A.; Hares, J. D.; ...

2016-08-02

Here we present a time-resolved detector concept for the magnetic recoil spectrometer for time-resolved measurements of the NIF neutron spectrum. The measurement is challenging due to the time spreading of the recoil protons (or deuterons) as they transit an energy dispersing magnet system. Ions arrive at the focal plane of the magnetic spectrometer over an interval of tens of nanoseconds. We seek to measure the time-resolved neutron spectrum with 20 ps precision by manipulating an electron signal derived from the ions. A stretch-compress scheme is employed to remove transit time skewing while simultaneously reducing the bandwidth requirements for signal recording.more » Simulation results are presented along with design concepts for structures capable of establishing the required electromagnetic fields.« less

A stretch/compress scheme for a high temporal resolution detector for the magnetic recoil spectrometer time (MRSt)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hilsabeck, T. J.; Frenje, J. A.; Hares, J. D.

Here we present a time-resolved detector concept for the magnetic recoil spectrometer for time-resolved measurements of the NIF neutron spectrum. The measurement is challenging due to the time spreading of the recoil protons (or deuterons) as they transit an energy dispersing magnet system. Ions arrive at the focal plane of the magnetic spectrometer over an interval of tens of nanoseconds. We seek to measure the time-resolved neutron spectrum with 20 ps precision by manipulating an electron signal derived from the ions. A stretch-compress scheme is employed to remove transit time skewing while simultaneously reducing the bandwidth requirements for signal recording.more » Simulation results are presented along with design concepts for structures capable of establishing the required electromagnetic fields.« less

Recoil polarization measurements

NASA Astrophysics Data System (ADS)

Brinkmann, Kai-Thomas

2017-01-01

Polarization observables in photon-induced meson production off nucleons have long been recognized to hold the promise of a detailed understanding of the excited states in the excitation spectrum of the nucleon. Photon beam and proton target polarization are routinely used at the ELSA facility in the Crystal Barrel/TAPS experiment and have yielded a wealth of data on contributing partial waves and nucleon resonances. A detector study on how to complement these ongoing studies by recoil polarization measurements that offer an orthogonal approach with otherwise unmeasurable observables in the field of non-strange meson photoproduction has been performed. Building on experience with silicon detectors operated in the photon beamline environment, first possible layouts of Si detector telescopes for recoil protons were developed. Various geometries, e.g. Archimedean spiral design of annular sensors, sector shapes and rectangular sensors were studied and have been used during test measurements. A prototype for the recoil polarimeter was built and subjected to performance tests in protonproton scattering at the COSY-accelerator in Jülich.

Improved cell viability and hydroxyapatite growth on nitrogen ion-implanted surfaces

NASA Astrophysics Data System (ADS)

Shafique, Muhammad Ahsan; Murtaza, G.; Saadat, Shahzad; Uddin, Muhammad K. H.; Ahmad, Riaz

2017-08-01

Stainless steel 306 is implanted with various doses of nitrogen ions using a 2 MV pelletron accelerator for the improvement of its surface biomedical properties. Raman spectroscopy reveals incubation of hydroxyapatite (HA) on all the samples and it is found that the growth of incubated HA is greater in higher ion dose samples. SEM profiles depict uniform growth and greater spread of HA with higher ion implantation. Human oral fibroblast response is also found consistent with Raman spectroscopy and SEM results; the cell viability is found maximum in samples treated with the highest (more than 300%) dose. XRD profiles signified greater peak intensity of HA with ion implantation; a contact angle study revealed hydrophilic behavior of all the samples but the treated samples were found to be lesser hydrophilic compared to the control samples. Nitrogen implantation yields greater bioactivity, improved surface affinity for HA incubation and improved hardness of the surface.

Ionization Mechanism of Positive-Ion Nitrogen Direct Analysis in Real Time.

PubMed

Song, Liguo; Chuah, Wei Chean; Lu, Xinyi; Remsen, Edward; Bartmess, John E

2018-04-01

Nitrogen can be an inexpensive alternative to helium used by direct analysis in real time (DART), especially in consideration of the looming helium shortage. Therefore, the ionization mechanism of positive-ion N 2 DART has been systematically investigated. Our experiments suggest that a range of metastable nitrogen species with a variety of internal energies existed and all of them were less energetic than metastable helium atoms. However, compounds with ionization energies (IE) equal to or lower than 10.2 eV (all organic compounds except the extremely small ones) can be efficiently ionized. Because N 2 DART was unable to efficiently ionize ambient moisture and common organic solvents such as methanol and acetonitrile, the most important ionization mechanism was direct Penning ionization followed by self-protonation of polar compounds generating [M+H] + ions. On the other hand, N 2 DART was able to efficiently ionize ammonia, which was beneficial in the ionization of hydrogen-bonding compounds with proton affinities (PA) weaker than ammonia generating [M+NH 4 ] + ions and large PAHs generating [M+H] + ions through proton transfer. N 2 DART was also able to efficiently ionize NO, which led to the ionization of nonpolar compounds such as alkanes and small aromatics generating [M-(2m+1)H] + (m=0,1…) ions. Lastly, metastable nitrogen species was also able to produce oxygen atoms, which resulted in increased oxygen adducts as the polarity of organic compounds decreased. In comparison with He DART, N 2 DART was approximately one order of magnitude less sensitive in generating [M+H] + ions, but could be more sensitive in generating [M+NH 4 ] + ions. Graphical Abstract ᅟ.

Ionization Mechanism of Positive-Ion Nitrogen Direct Analysis in Real Time

NASA Astrophysics Data System (ADS)

Song, Liguo; Chuah, Wei Chean; Lu, Xinyi; Remsen, Edward; Bartmess, John E.

2018-02-01

Nitrogen can be an inexpensive alternative to helium used by direct analysis in real time (DART), especially in consideration of the looming helium shortage. Therefore, the ionization mechanism of positive-ion N2 DART has been systematically investigated. Our experiments suggest that a range of metastable nitrogen species with a variety of internal energies existed and all of them were less energetic than metastable helium atoms. However, compounds with ionization energies (IE) equal to or lower than 10.2 eV (all organic compounds except the extremely small ones) can be efficiently ionized. Because N2 DART was unable to efficiently ionize ambient moisture and common organic solvents such as methanol and acetonitrile, the most important ionization mechanism was direct Penning ionization followed by self-protonation of polar compounds generating [M+H]+ ions. On the other hand, N2 DART was able to efficiently ionize ammonia, which was beneficial in the ionization of hydrogen-bonding compounds with proton affinities (PA) weaker than ammonia generating [M+NH4]+ ions and large PAHs generating [M+H]+ ions through proton transfer. N2 DART was also able to efficiently ionize NO, which led to the ionization of nonpolar compounds such as alkanes and small aromatics generating [M-(2m+1)H]+ (m=0,1…) ions. Lastly, metastable nitrogen species was also able to produce oxygen atoms, which resulted in increased oxygen adducts as the polarity of organic compounds decreased. In comparison with He DART, N2 DART was approximately one order of magnitude less sensitive in generating [M+H]+ ions, but could be more sensitive in generating [M+NH4]+ ions. [Figure not available: see fulltext.

EPDM Rubber Modified by Nitrogen Plasma Immersion Ion Implantation.

PubMed

Kondyurin, Alexey

2018-04-24

Ethylene-propylene diene monomer rubber (EPDM) was treated by plasma immersion ion implantation (PIII) with nitrogen ions of 20 keV energy and fluence from 10 13 to 10 16 ions/cm². The Fourier-transform infrared attenuated total reflection spectra, atomic force microscopy and optical microscopy showed significant structure changes of the surface. The analysis of an interface of PIII treated EPDM rubber with polyurethane binder showed a cohesive character of the adhesion joint fracture at the presence of solvent and interpreted as covalent bond network formation between the PIII treated rubber and the adhesive.

EPDM Rubber Modified by Nitrogen Plasma Immersion Ion Implantation

PubMed Central

2018-01-01

Ethylene-propylene diene monomer rubber (EPDM) was treated by plasma immersion ion implantation (PIII) with nitrogen ions of 20 keV energy and fluence from 1013 to 1016 ions/cm2. The Fourier-transform infrared attenuated total reflection spectra, atomic force microscopy and optical microscopy showed significant structure changes of the surface. The analysis of an interface of PIII treated EPDM rubber with polyurethane binder showed a cohesive character of the adhesion joint fracture at the presence of solvent and interpreted as covalent bond network formation between the PIII treated rubber and the adhesive. PMID:29695109

Interpreting Recoil for Undergraduate Students

ERIC Educational Resources Information Center

Elsayed, Tarek A.

2012-01-01

The phenomenon of recoil is usually explained to students in the context of Newton's third law. Typically, when a projectile is fired, the recoil of the launch mechanism is interpreted as a reaction to the ejection of the smaller projectile. The same phenomenon is also interpreted in the context of the conservation of linear momentum, which is…

Making AlN(x) Tunnel Barriers Using a Low-Energy Nitrogen-Ion Beam

NASA Technical Reports Server (NTRS)

Kaul, Anupama; Kleinsasser, Alan; Bumble, Bruce; LeDuc, Henry; Lee, Karen

2005-01-01

A technique based on accelerating positive nitrogen ions onto an aluminum layer has been demonstrated to be effective in forming thin (<2 nm thick) layers of aluminum nitride (AlN(x)) for use as tunnel barriers in Nb/Al-AlN(x)/Nb superconductor/insulator/ superconductor (SIS) Josephson junctions. AlN(x) is the present material of choice for tunnel barriers because, to a degree greater than that of any other suitable material, it offers the required combination of low leakage current at high current density and greater thermal stability. While ultra-thin AlN films with good thickness and stoichiometry control are easily formed using techniques such as reactive molecular beam epitaxy and chemical vapor deposition, growth temperatures of 900 C are necessary for the dissociative adsorption of nitrogen from either nitrogen (N2) or ammonia (NH3). These growth temperatures are prohibitively high for the formation of tunnel barriers on Nb films because interfacial reactions at temperatures as low as 200 to 300 C degrade device properties. Heretofore, deposition by reactive sputtering and nitridation of thin Al layers with DC and RF nitrogen plasmas have been successfully used to form AlN barriers in SIS junctions. However, precise control over critical current density Jc has proven to be a challenge, as is attaining adequate process reproducibility from system to system. The present ion-beam technique is an alternative to the plasma or reactive sputtering techniques as it provides a highly controlled arrival of reactive species, independent of the electrical conditions of the substrate or vacuum chamber. Independent and accurate control of parameters such as ion energy, flux, species, and direction promises more precise control of film characteristics such as stoichiometry and thickness than is the case with typical plasma processes. In particular, the background pressure during ion-beam nitride growth is 2 or 3 orders of magnitude lower, minimizing the formation of

Local formation of nitrogen-vacancy centers in diamond by swift heavy ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwartz, J.; Ilmenau University of Technology, Department of Microelectronics and Nanoelectric Systems, 98684 Ilmenau; Aloni, S.

2014-12-07

We exposed nitrogen-implanted diamonds to beams of swift heavy ions (∼1 GeV, ∼4 MeV/u) and find that these irradiations lead directly to the formation of nitrogen vacancy (NV) centers, without thermal annealing. We compare the photoluminescence intensities of swift heavy ion activated NV{sup −} centers to those formed by irradiation with low-energy electrons and by thermal annealing. NV{sup −} yields from irradiations with swift heavy ions are 0.1 of yields from low energy electrons and 0.02 of yields from thermal annealing. We discuss possible mechanisms of NV center formation by swift heavy ions such as electronic excitations and thermal spikes. While formingmore » NV centers with low efficiency, swift heavy ions could enable the formation of three dimensional NV{sup −} assemblies over relatively large distances of tens of micrometers. Further, our results show that NV center formation is a local probe of (partial) lattice damage relaxation induced by electronic excitations from swift heavy ions in diamond.« less

Local formation of nitrogen-vacancy centers in diamond by swift heavy ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwartz, J.; Aloni, S.; Ogletree, D. F.

2014-12-03

In this paper, we exposed nitrogen-implanted diamonds to beams of swift heavy ions (~1 GeV, ~4 MeV/u) and find that these irradiations lead directly to the formation of nitrogen vacancy (NV) centers, without thermal annealing. We compare the photoluminescence intensities of swift heavy ion activated NV - centers to those formed by irradiation with low-energy electrons and by thermal annealing. NV - yields from irradiations with swift heavy ions are 0.1 of yields from low energy electrons and 0.02 of yields from thermal annealing. We discuss possible mechanisms of NV center formation by swift heavy ions such as electronic excitationsmore » and thermal spikes. While forming NV centers with low efficiency, swift heavy ions could enable the formation of three dimensional NV - assemblies over relatively large distances of tens of micrometers. Finally and further, our results show that NV center formation is a local probe of (partial) lattice damage relaxation induced by electronic excitations from swift heavy ions in diamond.« less

Automation of experiments at Dubna Gas-Filled Recoil Separator

NASA Astrophysics Data System (ADS)

Tsyganov, Yu. S.

2016-01-01

Approaches to solving the problems of automation of basic processes in long-term experiments in heavy ion beams of the Dubna Gas-Filled Recoil Separator (DGFRS) facility are considered. Approaches in the field of spectrometry, both of rare α decays of superheavy nuclei and those for constructing monitoring systems to provide accident-free experiment running with highly radioactive targets and recording basic parameters of experiment, are described. The specific features of Double Side Silicon Strip Detectors (DSSSDs) are considered, special attention is paid to the role of boundary effects of neighboring p-n transitions in the "active correlations" method. An example of an off-beam experiment attempting to observe Zeno effect is briefly considered. Basic examples for nuclear reactions of complete fusion at 48Ca ion beams of U-400 cyclotron (LNR, JINR) are given. A scenario of development of the "active correlations" method for the case of very high intensity beams of heavy ions at promising accelerators of LNR, JINR, is presented.

Nitrogen Ion TRacing Observatory (NITRO) concept: a possible mission for next ESA's M-class call

NASA Astrophysics Data System (ADS)

Yamauchi, Masatoshi; Dandouras, Iannis; Paschalidis, Nikolaos

2014-05-01

Nitrogen is a key element for life as an inevitable part of the amino acid and protein, and its oxidation state (NH3 or N2 or NOX) in the ancient atmosphere is one of the key factors that determine the difficulty in forming amino acid without biological processes. Considering the fact that nitrogen molecule with triple chemical binding is much more difficult to be desolved/ionized than oxygen molecule with double chemical binding, and that dependence of the ion outflow from the ionosphere on the geomagnetic activity is more drastic for cold nitrogen ion than cold oxygen ions, it is important to understand the dynamic of N+ and N2+ at different solar conditions as compared to oxygen dynamics or proton dynamics. However, nearly no such observation exists at low energy less than keV, except very little observations for thermal nitrogen. One reason for lack of such measurement is difficulty in separating hot N+ from hot O+ even with the modern instruments, causing past instruments on board magnetospheric missions not targeting such separation but rather targeting higher temporal and spatial resolutions. However, with recent improvement of mass-separating ion analyser, it is now most likely possible to separate O+ and N+ by masking H+ and He++ and by limiting the angular coverage to minimize the contamination. In this sense, the nitrogen study in the magnetosphere requires a dedicated space mission. At moment there are two options: (1) pioneering single spacecraft mission with minimum instrumentation to detect hot nitrogen ions of missing energy range from 50 eV to 10 keV in the past missions; and (2) multi-spacecraft mission to make a comprehensive understanding of the dynamics of nitrogen ions in the magnetosphere. Here we present necessary spacecraft and instrumentation for the second option because that will be fitted into the M-class mission (450 MEUR) that European Space Agency most likely announces soon this year. The mission consists of three spacecraft, two mid

Chemical characterization of 4140 steel implanted by nitrogen ions

NASA Astrophysics Data System (ADS)

Niño, E. D. V.; Pinto, J. L.; Dugar-Zhabon, V.; Henao, J. A.

2012-06-01

AISI SAE 4140 steel samples of different surface roughness which are implanted with 20 keV and 30 keV nitrogen ions at a dose of 1017 ions/cm2 are studied. The crystal phases of nitrogen compositions of the implanted samples, obtained with help of an x-ray diffraction method, are confronted with the data reported by the International Centre for Diffraction Data (ICDD) PDF-2. The implantation treatment is realized in high-voltage pulsed discharges at low pressures. The crystal structure of the implanted solid surfaces is analyzed by the x-ray diffraction technique which permits to identify the possible newly formed compounds and to identify any change in the surface structure of the treated samples. A decrease in the intensity of the plane (110), a reduction of the cell unity in values of 2-theta and a diminishing of the crystallite dimensions in comparison with non-implanted samples are observed.

Automatic detection of recoil-proton tracks and background rejection criteria in liquid scintillator-micro-capillary-array fast neutron spectrometer

NASA Astrophysics Data System (ADS)

Mor, Ilan; Vartsky, David; Dangendorf, Volker; Tittelmeier, Kai.; Weierganz, Mathias; Goldberg, Mark Benjamin; Bar, Doron; Brandis, Michal

2018-06-01

We describe an analysis procedure for automatic unambiguous detection of fast-neutron-induced recoil proton tracks in a micro-capillary array filled with organic liquid scintillator. The detector is viewed by an intensified CCD camera. This imaging neutron detector possesses the capability to perform high position-resolution (few tens of μm), energy-dispersive transmission-imaging using ns-pulsed beams. However, when operated with CW or DC beams, it also features medium-quality spectroscopic capabilities for incident neutrons in the energy range 2-20 MeV. In addition to the recoil proton events which display a continuous extended track structure, the raw images exhibit complex ion-tracks from nuclear interactions of fast-neutrons in the scintillator, capillaries quartz-matrix and CCD. Moreover, as expected, one also observes a multitude of isolated scintillation spots of varying intensity (henceforth denoted "blobs") that originate from several different sources, such as: fragmented proton tracks, gamma-rays, heavy-ion reactions as well as events and noise that occur in the image-intensifier and CCD. In order to identify the continuous-track recoil proton events and distinguish them from all these background events, a rapid, computerized and automatic track-recognition-procedure was developed. Based on an appropriately weighted analysis of track parameters such as: length, width, area and overall light intensity, the method is capable of distinguishing a single continuous-track recoil proton from typically surrounding several thousands of background events that are found in each CCD frame.

Friction wear and auger analysis of iron implanted with 1.5-MeV nitrogen ions

NASA Technical Reports Server (NTRS)

Ferrante, J.; Jones, W. R., Jr.

1982-01-01

The effect of implantation of 1.5-MeV nitrogen ions on the friction and wear characteristics of pure iron sliding against steel was studied in a pin-on disk apparatus. An implantation dose of 5 x 10 to the 17th power ions/sq cm was used. Small reductions in initial and steady-state wear rates were observed for nitrogen-implanted iron riders as compared with unimplanted controls. Auger electron spectroscopy revealed a subsurface Gaussian nitrogen distribution with a maximum concentration of 15 at. % at a depth of 8 x 10 to the -7th m. A similar analysis within the wear scar of an implanted rider after 20 microns of wear yielded only background nitrogen concentration, thus giving no evidence for diffusion of nitrogen beyond the implanted range.

Mg2+ ions: do they bind to nucleobase nitrogens?

PubMed Central

Leonarski, Filip; D'Ascenzo, Luigi; Auffinger, Pascal

2017-01-01

Given the many roles proposed for Mg2+ in nucleic acids, it is essential to accurately determine their binding modes. Here, we surveyed the PDB to classify Mg2+ inner-sphere binding patterns to nucleobase imine N1/N3/N7 atoms. Among those, purine N7 atoms are considered to be the best nucleobase binding sites for divalent metals. Further, Mg2+ coordination to N7 has been implied in several ribozyme catalytic mechanisms. We report that Mg2+ assigned near imine nitrogens derive mostly from poor interpretations of electron density patterns and are most often misidentified Na+, K+, NH4+ ions, water molecules or spurious density peaks. Consequently, apart from few documented exceptions, Mg2+ ions do not bind to N7 atoms. Without much of a surprise, Mn2+, Zn2+ and Cd2+, which have a higher affinity for nitrogens, may contact N7 atoms when present in crystallization buffers. In this respect, we describe for the first time a potential Zn2+ ribosomal binding site involving two purine N7 atoms. Further, we provide a set of guidelines to help in the assignment of Mg2+ in crystallographic, cryo-EM, NMR and model building practices and discuss implications of our findings related to ion substitution experiments. PMID:27923930

Ion Beam Analysis Of Nitrogen Incorporated Ultrananocrystalline Diamond (UNCD) Thin Films

NASA Astrophysics Data System (ADS)

AlFaify, S.; Garratt, E.; Dissanayake, A.; Mancini, D. C.; Kayani, A.

2011-06-01

Determination of the elemental composition is important to correlate the properties of nitrogen incorporated Ultrananocrystalline Diamond (UNCD) thin films with their growth conditions. Films were deposited by CVD deposition technology and nitrogen incorporation was introduced by diluting the growth Ar/CH4 plasma with N2 gas. Deposition of UNCD thin films was carried out on tungsten (˜15 nm) coated Si substrates with varying concentrations of N2 diluted to the growth plasma. Scanning electron microscopy (SEM) and Raman spectroscopy (RS) were used to confirm the characteristic morphology of the UNCD film and its dominant sp3 bonding respectively. The deposited films were smooth on the submicron scale with the RMS roughness value of 2.9-5.1 nm. Reflectometry spectroscopy analysis (RES) technique was used to measure the films thicknesses. To obtain the elemental composition of the UNCD thin films, Rutherford Backscattering Spectrometry (RBS), Non-Rutherford Backscattering Spectrometry (NRBS), Elastic Recoil Detection Analysis (ERDA) and Nuclear Reaction Analysis (NRA) were performed. Deposited UNCD films contained less than 5 at.% of H while N content incorporated in the films was estimated to be lower than 1 at.%. The intermixing region between the substrate and the film was found to be negligible. Moreover, amorphous phase as determined by Raman analysis was found to be increasing for the sample deposited with N2.

Facile Synthesis of Pre-Doping Lithium-Ion Into Nitrogen-Doped Graphite Negative Electrode for Lithium-Ion Capacitor.

PubMed

Lee, Seul-Yi; Kim, Ji-Il; Rhee, Kyong Yop; Park, Soo-Jin

2015-09-01

Nitrogen-doped graphite, prepared via the thermal decomposition of melamine into a carbon matrix for use as the negative electrode in lithium-ion capacitors (LICs), was evaluated by electrochemical measurements. Furthermore, in order to study the performance of pre-doped lithium components as a function of nitrogen-doped material, the pre-doped lithium graphite was allowed to react with a lithium salt solution. The results showed that the nitrogen functional groups in the graphite largely influenced the pre-doped lithium components, thereby contributing to the discharge capacity and cycling performance. We confirmed that the large initial irreversible capacity could be significantly decreased by using pre-doped lithium components obtained through the nitrogen-doping method.

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

DOEpatents

Liu, D. Kwok-Keung; Chang, Shih-Ger

1987-08-25

The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

Gas powered fluid gun with recoil mitigation

DOEpatents

Grubelich, Mark C; Yonas, Gerold

2013-11-12

A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

Gas powered fluid gun with recoil mitigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grubelich, Mark C.; Yonas, Gerold

A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

Effect of nitrogen ion implantation on the structural and optical properties of indium oxide thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sethi, Riti; Aziz, Anver; Siddiqui, Azher M., E-mail: amsiddiqui@jmi.ac.in

2016-06-10

: We report here synthesis and subsequent nitrogen ion implantation of indium oxide (In{sub 2}O{sub 3}) thin films. The films were implanted with 25 keV N{sup +} beam for different ion doses between 3E15 to 1E16 ions/cm{sup 2}. The resulting changes in structural and optical properties were investigated using XRD, SEM-EDAX and UV-Vis Spectrometry. XRD studies reveal decrease in crystallite size from 20.06 to 12.42 nm with increase in ion dose. SEM micrographs show an increase in the grain size from 0.8 to 1.35 µm with increase in ion dose because of the agglomeration of the grains. Also, from EDAXmore » data on pristine and N-implanted thin films the presence of indium and oxygen without any traces of impurity elements could be seen. However, at lower ion doses such as 3E15 and 5E15 ions/cm{sup 2}, no evidence of the presence of nitrogen ion was seen. However, for the ion dose of 1E16 ions/cm{sup 2}, evidence of presence of nitrogen can be seen in the EDAX data. Band gap calculations reveal a decrease in band gap from 3.54 to 3.38 eV with increasing ion dose. However, the band gap was found to again show an increase to 3.58 eV at the highest ion dose owing to quantum confinement effect.« less

Optimizing Higgs factories by modifying the recoil mass

NASA Astrophysics Data System (ADS)

Gu, Jiayin; Li, Ying-Ying

2018-02-01

It is difficult to measure the WW-fusion Higgs production process ({{{e}}}+{{{e}}}-\\to {{ν }}\\bar{{{ν }}}{{h}}) at a lepton collider with a center of mass energy of 240-250 GeV due to its small rate and the large background from the Higgsstrahlung process with an invisible Z ({{{e}}}+{{{e}}}-\\to {{hZ}},{{Z}}\\to {{ν }}\\bar{{{ν }}}). We construct a modified recoil mass variable, {m}{{recoil}}p, defined using only the 3-momentum of the reconstructed Higgs particle, and show that it can separate the WW-fusion and Higgsstrahlung events better than the original recoil mass variable m recoil. Consequently, the {m}{{recoil}}p variable can be used to improve the overall precisions of the extracted Higgs couplings, in both the conventional framework and the effective-field-theory framework. We also explore the application of the {m}{{recoil}}p variable in the inclusive cross section measurements of the Higgsstrahlung process, while a quantitive analysis is left for future studies. JG is Supported by an International Postdoctoral Exchange Fellowship Program between the Office of the National Administrative Committee of Postdoctoral Researchers of China (ONACPR) and DESY. YYL is Supported by Hong Kong PhD Fellowship (HKPFS) and the Collaborative Research Fund (CRF) (HUKST4/CRF/13G)

The recoil transfer chamber—An interface to connect the physical preseparator TASCA with chemistry and counting setups

NASA Astrophysics Data System (ADS)

Even, J.; Ballof, J.; Brüchle, W.; Buda, R. A.; Düllmann, Ch. E.; Eberhardt, K.; Gorshkov, A.; Gromm, E.; Hild, D.; Jäger, E.; Khuyagbaatar, J.; Kratz, J. V.; Krier, J.; Liebe, D.; Mendel, M.; Nayak, D.; Opel, K.; Omtvedt, J. P.; Reichert, P.; Runke, J.; Sabelnikov, A.; Samadani, F.; Schädel, M.; Schausten, B.; Scheid, N.; Schimpf, E.; Semchenkov, A.; Thörle-Pospiech, P.; Toyoshima, A.; Türler, A.; Vicente Vilas, V.; Wiehl, N.; Wunderlich, T.; Yakushev, A.

2011-05-01

Performing experiments with transactinide elements demands highly sensitive detection methods due to the extremely low production rates (one -atom -at -a -time conditions). Preseparation with a physical recoil separator is a powerful method to significantly reduce the background in experiments with sufficiently long-lived isotopes ( t1/2≥0.5 s). In the last years, the new gas-filled TransActinide Separator and Chemistry Apparatus (TASCA) was installed and successfully commissioned at GSI. Here, we report on the design and performance of a Recoil Transfer Chamber (RTC) for TASCA—an interface to connect various chemistry and counting setups with the separator. Nuclear reaction products recoiling out of the target are separated according to their magnetic rigidity within TASCA, and the wanted products are guided to the focal plane of TASCA. In the focal plane, they pass a thin Mylar window that separates the ˜1 mbar atmosphere in TASCA from the RTC kept at ˜1 bar. The ions are stopped in the RTC and transported by a continuous gas flow from the RTC to the ancillary setup. In this paper, we report on measurements of the transportation yields under various conditions and on the first chemistry experiments at TASCA—an electrochemistry experiment with osmium and an ion exchange experiment with the transactinide element rutherfordium.

Aluminum surface modification by a non-mass-analyzed nitrogen ion beam

NASA Astrophysics Data System (ADS)

Ohira, Shigeo; Iwaki, Masaya

Non-mass-analyzed nitrogen ion implantation into polycrystal and single crystal aluminum sheets has been carried out at an accelerating voltage of 90 kV and a dose of 1 × 10 18 N ions/cm 2 using a Zymet implanter model Z-100. The pressure during implantation rose to 10 -3 Pa due to the influence of N gas feeding into the ion source. The characteristics of the surface layers were investigated by means of Auger electron spectroscopy (AES), X-ray diffraction (XRD), transmission electron diffraction (TED), and microscopy (TEM). The AES depth profiling shows a rectangular-like distribution of N atoms and little migration of O atoms near the surface. The high dose N-implantation forms c-axis oriented aluminum nitride (AIN) crystallines, and especially irradiation of Al single crystals with N ions leads to the formation of a hcp AlN single crystal. It is concluded that the high dose N-implantation in Al can result in the formation of AlN at room temperature without any thermal annealing. Furthermore, non-mass-analyzed N-implantation at a pressure of 10 -3 Pa of the nitrogen atmosphere causes the formation of pure AlN single crystals in the Al surface layer and consequently it can be practically used for AlN production.

Molecular dynamics study of structural damage in amorphous silica induced by swift heavy-ion radiation

NASA Astrophysics Data System (ADS)

Zhen, J. S.; Yang, Q.; Yan, Y. H.; Jiang, X. W.; Yan, S. A.; Chen, W.; Guo, X. Q.

2016-03-01

In this paper, the radiation defects induced by the swift heavy ions and the recoil atoms in amorphous SiO2 were studied. The energy of recoil atoms induced by the incident Au ions in SiO2 was calculated by using Monte Carlo method. Results show that the average energies of recoils reach the maximum (200 eV for Si and 130 eV for O, respectively) when the incident energy of Au ion is 100 MeV. Using Tersoff/zbl potential with the newly built parameters, the defects formation processes in SiO2 induced by the recoils were studied by using molecular dynamics method. The displacement threshold energies (Ed) for Si and O atoms are found to be 33.5 and 16.3 eV, respectively. Several types of under- and over-coordinated Si and O defects were analyzed. The results demonstrate that Si3, Si5, and O1 are the mainly defects in SiO2 after radiation. Besides, the size of cylindrical damage region produced by a single recoil atom was calculated. The calculation shows that the depth and the radius are up to 2.0 and 1.4 nm when the energy of recoils is 200 eV. Finally, it is estimated that the Au ion would induce a defected track with a diameter of 4 nm in SiO2.

Inner-Shell Electron Recoil Discrimination in Xenon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trask, Makayla; Lippincott, Hugh; Baxter, Dan

2017-01-01

\\bulletmore » $$$$ Dark matter searches using time projection chambers (TPCs) rely on the ability to distinguish between nuclear and electron interactions $$$$ Xenon TPCs are specifically searching for a low energy nuclear recoil ( < 30 keV ) signal $$$$ To do this, these interactions must be discernable from the electron recoil background« less

Measurements of the differential cross sections for recoil tritons in 4He- 3T scattering at energies between 0.5 and 2.5 MeV

NASA Astrophysics Data System (ADS)

Sawicki, J. A.

1988-03-01

Differential cross-sections for recoil detection of tritons from elastic scattering of α-particles on tritium were measured at forward recoil angles from 10° and 40° and over incident 4He energies ranging from 0.5 to 2.5 MeV. Thin solid state targets consisted of about 10 16T {at.}/{cm 2} either absorbed in a thin film of titanium or implanted at low energy in the matrix of amorphous silicon. The recoil yields were normalized against the yields of the T(d, α)n reaction measured on the same targets. It is found that the cross sections obtained are considerably enhanced as compared to the Rutherford recoil cross section, what can be attributed to the combined effect of Coulomb and nuclear potentials and formation of compound 7Li nuclei. The applications of the elastic recoil detection as a means for depth profiling of tritium in materials are briefly considered. The measured dependence of the triton recoil cross section on the incident energy of 4He + ions allows profiling the concentration of tritium across a range ˜ l μm below the surface of solids.

Nuclear-Recoil Energy Scale in CDMS II Silicon Dark-Matter Detectors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Agnese, R.; et al.

The Cryogenic Dark Matter Search (CDMS II) experiment aims to detect dark matter particles that elastically scatter from nuclei in semiconductor detectors. The resulting nuclear-recoil energy depositions are detected by ionization and phonon sensors. Neutrons produce a similar spectrum of low-energy nuclear recoils in such detectors, while most other backgrounds produce electron recoils. The absolute energy scale for nuclear recoils is necessary to interpret results correctly. The energy scale can be determined in CDMS II silicon detectors using neutrons incident from a broad-spectrummore » $$^{252}$$Cf source, taking advantage of a prominent resonance in the neutron elastic scattering cross section of silicon at a recoil (neutron) energy near 20 (182) keV. Results indicate that the phonon collection efficiency for nuclear recoils is $$4.8^{+0.7}_{-0.9}$$% lower than for electron recoils of the same energy. Comparisons of the ionization signals for nuclear recoils to those measured previously by other groups at higher electric fields indicate that the ionization collection efficiency for CDMS II silicon detectors operated at $$\\sim$$4 V/cm is consistent with 100% for nuclear recoils below 20 keV and gradually decreases for larger energies to $$\\sim$$75% at 100 keV. The impact of these measurements on previously published CDMS II silicon results is small.« less

Gas powered fluid gun with recoil mitigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grubelich, Mark C.; Yonas, Gerold

A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided by a cavitating venturi that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated.

Measurement of Nuclear Recoils in the CDMS II Dark Matter Search

NASA Astrophysics Data System (ADS)

Fallows, Scott M.

The Cryogenic Dark Matter Search (CDMS) experiment is designed to directly detect elastic scatters of weakly-interacting massive dark matter particles (WIMPs), on target nuclei in semiconductor crystals composed of Si and Ge. These scatters would occur very rarely, in an overwhelming background composed primarily of electron recoils from photons and electrons, as well as a smaller but non-negligible background of WIMP-like nuclear recoils from neutrons. The CDMS~II generation of detectors simultaneously measure ionization and athermal phonon signals from each scatter, allowing discrimination against virtually all electron recoils in the detector bulk. Pulse-shape timing analysis allows discrimination against nearly all remaining electron recoils taking place near detector surfaces. Along with carefully limited neutron backgrounds, this experimental program allowed for "background-free'' operation of CDMS~II at Soudan, with less than one background event expected in each WIMP-search analysis. As a result, exclusionary upper-limits on WIMP-nucleon interaction cross section were placed over a wide range of candidate WIMP masses, ruling out large new regions of parameter space. These results, like any others, are subject to a variety of systematic effects that may alter their final interpretations. A primary focus of this dissertation will be difficulties in precisely calibrating the energy scale for nuclear recoil events like those from WIMPs. Nuclear recoils have suppressed ionization signals relative to electron recoils of the same recoil energy, so the response of the detectors is calibrated differently for each recoil type. The overall normalization and linearity of the energy scale for electron recoils in CDMS~II detectors is clearly established by peaks of known gamma energy in the ionization spectrum of calibration data from a 133Ba source. This electron-equivalent keVee) energy scale enables calibration of the total phonon signal (keVt) by enforcing unity

Study of nitrogen ion doping of titanium dioxide films

NASA Astrophysics Data System (ADS)

Ramos, Raul; Scoca, Diego; Borges Merlo, Rafael; Chagas Marques, Francisco; Alvarez, Fernando; Zagonel, Luiz Fernando

2018-06-01

This study reports on the properties of nitrogen doped titanium dioxide (TiO2) thin films considering the application as a transparent conducting oxide (TCO). Sets of thin films were prepared by sputtering a titanium target under oxygen atmosphere on a quartz substrate at 400 or 500 °C. Films were then doped at the same temperature by 150 eV nitrogen ions. The films were prepared in Anatase phase which was maintained after doping. Up to 30 at% nitrogen concentration was obtained at the surface, as determined by in situ X-ray photoelectron spectroscopy (XPS). Such high nitrogen concentration at the surface lead to nitrogen diffusion into the bulk which reached about 25 nm. Hall measurements indicate that average carrier density reached over 1019 cm-3 with mobility in the range of 0.1-1 cm2 V-1 s-1. Resistivity about 3 · 10-1 Ω cm could be obtained with 85% light transmission at 550 nm. These results indicate that low energy implantation is an effective technique for TiO2 doping that allows an accurate control of the doping process independently from the TiO2 preparation. Moreover, this doping route seems promising to attain high doping levels without significantly affecting the film structure. Such approach could be relevant for preparation of N:TiO2 transparent conducting electrodes (TCE).

A predictive theory for elastic scattering and recoil of protons from 4He

DOE PAGES

Hupin, Guillaume; Quaglioni, Sofia; Navratil, Petr

2014-12-08

Low-energy cross sections for elastic scattering and recoil of protons from 4He nuclei (also known as α particles) are calculated directly by solving the Schrodinger equation for five nucleons interacting through accurate two- and three-nucleon forces derived within the framework of chiral effective field theory. Precise knowledge of these processes at various proton backscattering/recoil angles and energies is needed for the ion-beam analysis of numerous materials, from the surface layers of solids, to thin films, to fusion-reactor materials. Indeed, the same elastic scattering process, in two different kinematic configurations, can be used to probe the concentrations and depth profiles ofmore » either hydrogen or helium. Furthermore, we compare our results to available experimental data and show that direct calculations with modern nuclear potentials can help to resolve remaining inconsistencies among data sets and can be used to predict these cross sections when measurements are not available.« less

Study of the effects of E × B fields as mechanism to carbon-nitrogen plasma immersion ion implantation on stainless steel samples

NASA Astrophysics Data System (ADS)

Pillaca, E. J. D. M.; Ueda, M.; Oliveira, R. M.; Pichon, L.

2014-08-01

Effects of E × B fields as mechanism to carbon-nitrogen plasma immersion ion implantation (PIII) have been investigated. This magnetic configuration when used in PIII allows obtaining high nitrogen plasma density close to the ion implantation region. Consequently, high ions dose on the target is possible to be achieved compared with standard PIII. In this scenario, nitrogen and carbon ions were implanted simultaneously on stainless steel, as measured by GDOES and detected by X-ray diffraction. Carbon-tape disposed on the sample-holder was sputtered by intense bombardment of nitrogen ions, being the source of carbon atoms in this experiment. The implantation of both N and C caused changes on sample morphology and improvement of the tribological properties of the stainless steel.

Super-hard cubic BN layer formation by nitrogen ion implantation

NASA Astrophysics Data System (ADS)

Komarov, F. F.; Pilko, V. V.; Yakushev, V. A.; Tishkov, V. S.

1994-11-01

Microcrystalline and amorphous boron thin films were implanted with nitrogen ions at energies from 25 to 125 keV and with doses from 2 × 10 17 to 1 × 10 18 at.cm 2 at temperatures below 200°C. The structure of boron nitride phases after ion implantation, formation of phases and phase transformations were investigated by TEM and TED methods. The cubic boron nitride phase is revealed. The microhardness of the formed films was satisfactorily explained in terms of chemical compound formation by polyenergetic ion implantation. The influence of the copper impurity on the formation of the cubic boron nitride phase is demonstrated. It has also been shown that low concentrations of copper promote cubic BN boundary formation.

Influence of crystal orientation and ion bombardment on the nitrogen diffusivity in single-crystalline austenitic stainless steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martinavicius, A.; Abrasonis, G.; Moeller, W.

2011-10-01

The nitrogen diffusivity in single-crystalline AISI 316L austenitic stainless steel (ASS) during ion nitriding has been investigated at different crystal orientations ((001), (110), (111)) under variations of ion flux (0.3-0.7 mA cm{sup -2}), ion energy (0.5-1.2 keV), and temperature (370-430 deg. C). The nitrogen depth profiles obtained from nuclear reaction analysis are in excellent agreement with fits using the model of diffusion under the influence of traps, from which diffusion coefficients were extracted. At fixed ion energy and flux, the diffusivity varies by a factor up to 2.5 at different crystal orientations. At (100) orientation, it increases linearly with increasingmore » ion flux or energy. The findings are discussed on the basis of atomistic mechanisms of interstitial diffusion, potential lattice distortions, local decomposition, and ion-induced lattice vibrational excitations.« less

Precision Spectroscopy on Single Cold Trapped Molecular Nitrogen Ions

NASA Astrophysics Data System (ADS)

Hegi, Gregor; Najafian, Kaveh; Germann, Matthias; Sergachev, Ilia; Willitsch, Stefan

2016-06-01

The ability to precisely control and manipulate single cold trapped particles has enabled spectroscopic studies on narrow transitions of ions at unprecedented levels of precision. This has opened up a wide range of applications, from tests of fundamental physical concepts, e.g., possible time-variations of fundamental constants, to new and improved frequency standards. So far most of these experiments have concentrated on atomic ions. Recently, however, attention has also been focused on molecular species, and molecular nitrogen ions have been identified as promising candidates for testing a possible time-variation of the proton/electron mass ratio. Here, we report progress towards precision-spectroscopic studies on dipole-forbidden vibrational transitions in single trapped N2+ ions. Our approach relies on the state-selective generation of single N2+ ions, subsequent infrared excitation using high intensity, narrow-band quantum-cascade lasers and a quantum-logic scheme for non-destructive state readout. We also characterize processes limiting the state lifetimes in our experiment, which impair the measurement fidelity. P. O. Schmidt et. al., Science 309 (2005), 749. M. Kajita et. al., Phys. Rev. A 89 (2014), 032509 M. Germann , X. Tong, S. Willitsch, Nature Physics 10 (2014), 820. X. Tong, A. Winney, S. Willitsch, Phys. Rev. Lett. 105 (2010), 143001

Ion energy/momentum effects during ion assisted growth of niobium nitride films

NASA Astrophysics Data System (ADS)

Klingenberg, Melissa L.

The research described herein was performed to better understand and discern ion energy vs. ion momentum effects during ion beam assisted (IBAD) film growth and their effects on residual stress, crystalline structure, morphology, and composition, which influence film tribological properties. NbxN y was chosen for this research because it is a refractory material that can possess a large number of crystalline structures, and it has been found to have good tribological properties. To separate the effects of momentum transfer per arriving atom (p/a), which considers bombarding species mass, energy, and ion-to-atom transport ratio, from those of energy deposition per arriving atom (E/a), a mass independent parameter, different inert ion beams (krypton, argon, and neon) were used to create a matrix of coatings formed using similar energy deposition, but different momentum transfer and vice versa. Deposition was conducted in a research-scale IBAD system using electron beam evaporation, a radio frequency ion source, and a neutral nitrogen gas backfill. Films were characterized using x-ray diffraction, atomic force microscopy, Rutherford backscattering spectrometry, and residual stress analysis. Direct and quantifiable effects of bombardment were observed; however, energy deposition and momentum transfer effects could not be completely separated, confirming that thin film processes are complex. Complexities arose from ion-specific interactions (ion size, recoil energy, per cent reflected neutrals, Penning ionization, etc.) and chemistry effects that are not considered by the simple models. Overall, it can be stated that bombardment promoted nitride formation, nanocrystallinity, and compressive stress formation; influenced morphology (which influenced post-deposition oxygen uptake) and stress evolution; increased lattice parameter; modified crystalline phase and texture; and led to inert gas incorporation. High stress levels correlated strongly with material disorder and

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

DOEpatents

Liu, David K.; Chang, Shih-Ger

1989-01-01

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Analysis of hydrogen adsorption and surface binding configuration on tungsten using direct recoil spectrometry

DOE PAGES

Kolasinski, R. D.; Hammond, K. D.; Whaley, J. A.; ...

2014-12-03

In our work, we apply low energy ion beam analysis to examine directly how the adsorbed hydrogen concentration and binding configuration on W(1 0 0) depend on temperature. We exposed the tungsten surface to fluxes of both atomic and molecular H and D. We then probed the H isotopes adsorbed along different crystal directions using 1–2 keV Ne + ions. At saturation coverage, H occupies two-fold bridge sites on W(1 0 0) at 25 °C. Moreover, the H coverage dramatically changes the behavior of channeled ions, as does reconstruction of the surface W atoms. For the exposure conditions examined here,more » we find that surface sites remain populated with H until the surface temperature reaches 200 °C. Then, we observe H rapidly desorbing until only a residual concentration remains at 450 °C. Development of an efficient atomistic model that accurately reproduces the experimental ion energy spectra and azimuthal variation of recoiled H is underway.« less

Submillisecond Elastic Recoil Reveals Molecular Origins of Fibrin Fiber Mechanics

PubMed Central

Hudson, Nathan E.; Ding, Feng; Bucay, Igal; O’Brien, E. Timothy; Gorkun, Oleg V.; Superfine, Richard; Lord, Susan T.; Dokholyan, Nikolay V.; Falvo, Michael R.

2013-01-01

Fibrin fibers form the structural scaffold of blood clots. Thus, their mechanical properties are of central importance to understanding hemostasis and thrombotic disease. Recent studies have revealed that fibrin fibers are elastomeric despite their high degree of molecular ordering. These results have inspired a variety of molecular models for fibrin’s elasticity, ranging from reversible protein unfolding to rubber-like elasticity. An important property that has not been explored is the timescale of elastic recoil, a parameter that is critical for fibrin’s mechanical function and places a temporal constraint on molecular models of fiber elasticity. Using high-frame-rate imaging and atomic force microscopy-based nanomanipulation, we measured the recoil dynamics of individual fibrin fibers and found that the recoil was orders of magnitude faster than anticipated from models involving protein refolding. We also performed steered discrete molecular-dynamics simulations to investigate the molecular origins of the observed recoil. Our results point to the unstructured αC regions of the otherwise structured fibrin molecule as being responsible for the elastic recoil of the fibers. PMID:23790375

XANES analyses of silicon crystalline irradiated by nitrogen/oxygen ions.

PubMed

Yoshida, T; Hara, T; Li, T; Yoshida, H; Tanabe, T

2001-03-01

X-ray absorption techniques have been applied to the characterization of 5 keV nitrogen / oxygen ions implanted silicon samples. The depth selective measurement of XANES by recording in PEY mode and the quantitative analysis by superposition of XANES spectra were carried out to elucidate the depth profile of implanted ions. It has been revealed that the silicon nitride phase were formed in silicon after prolonged N+ irradiation and it extended over the deep part of the damaged region from the surface. On the other hand, for the O+ irradiation, silicon dioxide phase were produced only in the shallow part of the damaged region, i.e., the silicon dioxide phase likely broke off during the irradiation.

Direct Measurement of Photon Recoil from a Levitated Nanoparticle

NASA Astrophysics Data System (ADS)

Jain, Vijay; Gieseler, Jan; Moritz, Clemens; Dellago, Christoph; Quidant, Romain; Novotny, Lukas

2016-06-01

The momentum transfer between a photon and an object defines a fundamental limit for the precision with which the object can be measured. If the object oscillates at a frequency Ω0 , this measurement backaction adds quanta ℏΩ0 to the oscillator's energy at a rate Γrecoil, a process called photon recoil heating, and sets bounds to coherence times in cavity optomechanical systems. Here, we use an optically levitated nanoparticle in ultrahigh vacuum to directly measure Γrecoil. By means of a phase-sensitive feedback scheme, we cool the harmonic motion of the nanoparticle from ambient to microkelvin temperatures and measure its reheating rate under the influence of the radiation field. The recoil heating rate is measured for different particle sizes and for different excitation powers, without the need for cavity optics or cryogenic environments. The measurements are in quantitative agreement with theoretical predictions and provide valuable guidance for the realization of quantum ground-state cooling protocols and the measurement of ultrasmall forces.

The influence of nitrogen ion implantation on the tribological properties of piston rings made of Hardox and Raex steels

NASA Astrophysics Data System (ADS)

Budzyński, P.; Kamiński, M.; Pyszniak, K.

2016-09-01

The implantation of nitrogen, carbon, and oxygen can be used for enhancing the tribological properties of critical components for internal combustion engines. Hardox and Raex steels have very similar strength parameters as for steel used for piston rings in internal combustion engines. An essential criterion when selecting material for the production of piston rings is a low friction factor and a low wear index. The aim of this study was to determine the extent to which these parameters can be enhanced by nitrogen ion implantation. Samples were implanted with nitrogen ions with 65 keV energy and the fluence of implanted ions set to 1.1017 N + /cm2. Friction and wear measurements were performed on a pin-on disc stand. The results demonstrate that implantation with nitrogen ions significantly reduces the friction factor and wear of Hardox 450 and Raex 400 steels. Implantation can and should be used for enhancing the tribological properties of steel used for friction elements in internal combustion engines, particularly when heat treatment is excluded. Final elements can be subjected to implantation, as the process does not change their dimensions.

First identification of excited states in Ba 117 using the recoil- β -delayed proton tagging technique

DOE PAGES

Ding, B.; Liu, Z.; Seweryniak, D.; ...

2017-02-01

Excited states have been observed for the first time in the neutron-deficient nucleus 117Ba using the recoil-decay tagging technique following the heavy-ion fusion-evaporation reaction 64Zn( 58Ni, 2p3n) 117Ba. Prompt γ rays have been assigned to 117Ba through correlations with β-delayed protons following the decay of A = 117 recoils. Through the analysis of the γ–γ coincidence relationships, a high-spin level scheme consisting of two bands has been established in 117Ba. Based on the systematics of the level spacings in the neighboring barium isotopes, the two bands are proposed to have νh 11/2[532]5/2 – and νd 5/2[413]5/2 + configurations, respectively. Lastly,more » the observed band-crossing properties are interpreted in the framework of cranked shell model.« less

Superior Cathode Performance of Nitrogen-Doped Graphene Frameworks for Lithium Ion Batteries.

PubMed

Xiong, Dongbin; Li, Xifei; Bai, Zhimin; Shan, Hui; Fan, Linlin; Wu, Chunxia; Li, Dejun; Lu, Shigang

2017-03-29

Development of alternative cathode materials is of highly desirable for sustainable and cost-efficient lithium-ion batteries (LIBs) in energy storage fields. In this study, for the first time, we report tunable nitrogen-doped graphene with active functional groups for cathode utilization of LIBs. When employed as cathode materials, the functionalized graphene frameworks with a nitrogen content of 9.26 at% retain a reversible capacity of 344 mAh g -1 after 200 cycles at a current density of 50 mA g -1 . More surprisingly, when conducted at a high current density of 1 A g -1 , this cathode delivers a high reversible capacity of 146 mAh g -1 after 1000 cycles. Our current research demonstrates the effective significance of nitrogen doping on enhancing cathode performance of functionalized graphene for LIBs.

3D free-standing nitrogen-doped reduced graphene oxide aerogel as anode material for sodium ion batteries with enhanced sodium storage.

PubMed

Zhang, Jiao; Li, Chuanqi; Peng, Zhikun; Liu, Yushan; Zhang, Jianmin; Liu, Zhongyi; Li, Dan

2017-07-07

Sodium ion batteries have drawn extensive attentions for large-scale energy storage to replace lithium ion batteries primarily due to the natural abundance of sodium resource and low cost, but their energy density and electrochemical performance are hindered by the sluggish diffusion kinetics of sodium ion. Herein, free-standing nitrogen-doped graphene aerogel has been fabricated via hydrothermal reaction as the potential anode material for sodium ion batteries. The three dimensional porous network structure of the graphene aerogel provides sufficient interstitial space for sodium ion accommodation, allowing fast and reversible ion intercalation/de-intercalation. The nitrogen doping could introduce defects on the graphene sheets, making the feasible transport of large-sized sodium ion. Benefiting from the effective structure and nitrogen doping, the obtained material demonstrates high reversible capacities, good cycling performance (287.9 mA h g -1 after 200 cycles at a current density of 100 mA g -1 ), especially superior rate capability (151.9 mA h g -1 at a high current density of 5 A g -1 ).

Submillisecond elastic recoil reveals molecular origins of fibrin fiber mechanics.

PubMed

Hudson, Nathan E; Ding, Feng; Bucay, Igal; O'Brien, E Timothy; Gorkun, Oleg V; Superfine, Richard; Lord, Susan T; Dokholyan, Nikolay V; Falvo, Michael R

2013-06-18

Fibrin fibers form the structural scaffold of blood clots. Thus, their mechanical properties are of central importance to understanding hemostasis and thrombotic disease. Recent studies have revealed that fibrin fibers are elastomeric despite their high degree of molecular ordering. These results have inspired a variety of molecular models for fibrin's elasticity, ranging from reversible protein unfolding to rubber-like elasticity. An important property that has not been explored is the timescale of elastic recoil, a parameter that is critical for fibrin's mechanical function and places a temporal constraint on molecular models of fiber elasticity. Using high-frame-rate imaging and atomic force microscopy-based nanomanipulation, we measured the recoil dynamics of individual fibrin fibers and found that the recoil was orders of magnitude faster than anticipated from models involving protein refolding. We also performed steered discrete molecular-dynamics simulations to investigate the molecular origins of the observed recoil. Our results point to the unstructured αC regions of the otherwise structured fibrin molecule as being responsible for the elastic recoil of the fibers. Copyright © 2013 Biophysical Society. Published by Elsevier Inc. All rights reserved.

Low-energy N+ ion irradiation induced synthesis of nitrogenous compound from solid organic sodium salts

NASA Astrophysics Data System (ADS)

Wang, Xiangqin; Yu, Zengliang

2003-08-01

In this paper, samples of solid organic sodium salts (sodium formate, sodium acetate and sodium benzoate) were irradiated by low-energy N+ ions. The induced damage was detected by infrared (FT-IR). It is shown that a new cyano group (-CN) and amino group (-NH2) were formed in the irradiated sodium carbroxylic sample with N+ ion irradiation. The experimental results examined the effect of N+ ion irradiation by reacting with sodium salt molecules, and presented a new way for the synthesis of nitrogenous compound by low-energy ion irradiation.

Recoil hysteresis of Sm -Co/Fe exchange-spring bilayers

NASA Astrophysics Data System (ADS)

Kang, K.; Lewis, L. H.; Jiang, J. S.; Bader, S. D.

2005-12-01

The exchange-spring behavior found in Sm-Co (20nm)/Fe epitaxial bilayer films was investigated by analyzing major hysteresis and recoil curves as a function of anneal conditions. The hard layer consists of nanocrystalline intermetallic Sm-Co hexagonal phases (majority phase Sm2Co7 with SmCo3 and SmCo5). Recoil curves, obtained from the successive removal to remanence and reapplication of an increasingly negative field from the major demagnetization curve, reveal the reversible and irreversible components of the magnetization. The Sm-Co thickness was fixed at 20nm while the Fe thicknesses of 10 and 20nm were studied, with ex situ annealing carried out in evacuated, sealed silica tubes at different temperatures. The peak in the recoil curve area is associated with the coercivity of the hard phase. The development of the soft component magnetization is revealed by the departure of the recoil area from zero with application of a reverse field. These two features together confirm that annealing stabilizes the 10nm Fe bilayer sample against local magnetic reversal while it weakens the 20nm bilayer sample. Furthermore, in both its as-deposited and annealed states the Sm -Co/Fe bilayer of 10nm Fe thickness always displays a higher exchange field and smaller recoil loop areas than the bilayer of 20nm Fe thickness, consistent with a stronger exchange response and more reversible magnetization in the former.

Spontaneous lateral atomic recoil force close to a photonic topological material

NASA Astrophysics Data System (ADS)

Hassani Gangaraj, S. Ali; Hanson, George W.; Antezza, Mauro; Silveirinha, Mário G.

2018-05-01

We investigate the quantum recoil force acting on an excited atom close to the surface of a nonreciprocal photonic topological insulator (PTI). The main atomic emission channel is the unidirectional surface plasmon propagating at the PTI-vacuum interface, and we show that it enables a spontaneous lateral recoil force that scales at short distances as 1 /d4 , where d is the atom-PTI separation. Remarkably, the sign of the recoil force is polarization and orientation independent, and it occurs in a translation-invariant homogeneous system in thermal equilibrium. Surprisingly, the recoil force persists for very small values of the gyration pseudovector, which, for a biased plasma, corresponds to very low cyclotron frequencies. The ultrastrong recoil force is rooted in the quasihyperbolic dispersion of the surface plasmons. We consider both an initially excited atom and a continuous pump scenario, the latter giving rise to a steady lateral force whose direction can be changed at will by simply varying the orientation of the biasing magnetic field. Our predictions may be tested in experiments with cold Rydberg atoms and superconducting qubits.

Production of 14 MeV neutrons by heavy ions

DOEpatents

Brugger, Robert M.; Miller, Lowell G.; Young, Robert C.

1977-01-01

This invention relates to a neutron generator and a method for the production of 14 MeV neutrons. Heavy ions are accelerated to impinge upon a target mixture of deuterium and tritium to produce recoil atoms of deuterium and tritium. These recoil atoms have a sufficient energy such that they interact with other atoms of tritium or deuterium in the target mixture to produce approximately 14 MeV neutrons.

RECOIL LABELING OF ORGANIC COMPOUNDS (in Japanese)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oae, S.; Hamada, M.; Otsuji, Y.

1963-01-01

The results of C/sup 14/-labeling under neutron irradiation of two groups of compounds are reported: (1) naphthalene, phenanthrene, and anthracene in an attempt to determine whether or not high energy C/sup 14/ fragments formed by nuclear recoil would favor or discriminate against any particular position in product formations; (2) pseudoephedrine, 2-amino-pyrimidine, and 3,6- dihydroxypyridazine as complex nitrogen-containing compounds. These samples were irradiated with thermal neutrons obtained from a pile. To determine the radiochemical yields and the relative ratios of the C/sup 14/ distributions in the respective compounds, the samples were purified radlochemically and were degraded chemically. The results deduced frommore » the experimental data are the following: (1) higher distribution of C/sup 14/ was found in the positions where the localizations of electrons are known to be higher; (2) the re-entry of C/sup 14/ into angular positions was very small; (3) the difference of phase affected the yield but not the distribution of C/sup 14/ in the products; (4) the relatively complex compounds could be labeled directly by this method. (A.G.W.)« less

First limits on WIMP nuclear recoil signals in ZEPLIN-II: A two-phase xenon detector for dark matter detection

NASA Astrophysics Data System (ADS)

Alner, G. J.; Araújo, H. M.; Bewick, A.; Bungau, C.; Camanzi, B.; Carson, M. J.; Cashmore, R. J.; Chagani, H.; Chepel, V.; Cline, D.; Davidge, D.; Davies, J. C.; Daw, E.; Dawson, J.; Durkin, T.; Edwards, B.; Gamble, T.; Gao, J.; Ghag, C.; Howard, A. S.; Jones, W. G.; Joshi, M.; Korolkova, E. V.; Kudryavtsev, V. A.; Lawson, T.; Lebedenko, V. N.; Lewin, J. D.; Lightfoot, P.; Lindote, A.; Liubarsky, I.; Lopes, M. I.; Lüscher, R.; Majewski, P.; Mavrokoridis, K.; McMillan, J. E.; Morgan, B.; Muna, D.; Murphy, A. St. J.; Neves, F.; Nicklin, G. G.; Ooi, W.; Paling, S. M.; Pinto da Cunha, J.; Plank, S. J. S.; Preece, R. M.; Quenby, J. J.; Robinson, M.; Salinas, G.; Sergiampietri, F.; Silva, C.; Solovov, V. N.; Smith, N. J. T.; Smith, P. F.; Spooner, N. J. C.; Sumner, T. J.; Thorne, C.; Tovey, D. R.; Tziaferi, E.; Walker, R. J.; Wang, H.; White, J. T.; Wolfs, F. L. H.

2007-11-01

Results are presented from the first underground data run of ZEPLIN-II, a 31 kg two-phase xenon detector developed to observe nuclear recoils from hypothetical weakly interacting massive dark matter particles. Discrimination between nuclear recoils and background electron recoils is afforded by recording both the scintillation and ionisation signals generated within the liquid xenon, with the ratio of these signals being different for the two classes of event. This ratio is calibrated for different incident species using an AmBe neutron source and 60Co γ-ray sources. From our first 31 live days of running ZEPLIN-II, the total exposure following the application of fiducial and stability cuts was 225 kg × days. A background population of radon progeny events was observed in this run, arising from radon emission in the gas purification getters, due to radon daughter ion decays on the surfaces of the walls of the chamber. An acceptance window, defined by the neutron calibration data, of 50% nuclear recoil acceptance between 5 keV ee and 20 keV ee, had an observed count of 29 events, with a summed expectation of 28.6 ± 4.3 γ-ray and radon progeny induced background events. These figures provide a 90% c.l. upper limit to the number of nuclear recoils of 10.4 events in this acceptance window, which converts to a WIMP-nucleon spin-independent cross-section with a minimum of 6.6 × 10 -7 pb following the inclusion of an energy-dependent, calibrated, efficiency. A second run is currently underway in which the radon progeny will be eliminated, thereby removing the background population, with a projected sensitivity of 2 × 10 -7 pb for similar exposures as the first run.

First measurement of surface nuclear recoil background for argon dark matter searches

DOE PAGES

Xu, Jingke; Stanford, Chris; Westerdale, Shawn; ...

2017-09-19

Here, one major background in direct searches for weakly interacting massive particles (WIMPs) comes from the deposition of radon progeny on detector surfaces. A dangerous surface background is the 206Pb nuclear recoils produced by 210Po decays. In this paper, we report the first characterization of this background in liquid argon. The scintillation signal of low energy Pb recoils is measured to be highly quenched in argon, and we estimate that the 103 keV 206Pb recoil background will produce a signal equal to that of a ~5 keV (30 keV) electron recoil ( 40Ar recoil). In addition, we demonstrate that thismore » dangerous 210Po surface background can be suppressed, using pulse shape discrimination methods, by a factor of ~100 or higher, which can make argon dark matter detectors near background-free and enhance their potential for discovery of medium- and high-mass WIMPs. Lastly, we also discuss the impact on other low background experiments.« less

Depth profiling of high energy nitrogen ions implanted in the <1 0 0>, <1 1 0> and randomly oriented silicon crystals

NASA Astrophysics Data System (ADS)

Erić, M.; Petrović, S.; Kokkoris, M.; Lagoyannis, A.; Paneta, V.; Harissopulos, S.; Telečki, I.

2012-03-01

This work reports on the experimentally obtained depth profiles of 4 MeV 14N2+ ions implanted in the <1 0 0>, <1 1 0> and randomly oriented silicon crystals. The ion fluence was 1017 particles/cm2. The nitrogen depth profiling has been performed using the Nuclear Reaction Analysis (NRA) method, via the study of 14N(d,α0)12C and 14N(d,α1)12C nuclear reactions, and with the implementation of SRIM 2010 and SIMNRA computer simulation codes. For the randomly oriented silicon crystal, change of the density of silicon matrix and the nitrogen "bubble" formation have been proposed as the explanation for the difference between the experimental and simulated nitrogen depth profiles. During the implantation, the RBS/C spectra were measured on the nitrogen implanted and on the virgin crystal spots. These spectra provide information on the amorphization of the silicon crystals induced by the ion implantation.

Bias in bonding behavior among boron, carbon, and nitrogen atoms in ion implanted a-BN, a-BC, and diamond like carbon films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Genisel, Mustafa Fatih; Uddin, Md. Nizam; Say, Zafer

2011-10-01

In this study, we implanted N{sup +} and N{sub 2}{sup +} ions into sputter deposited amorphous boron carbide (a-BC) and diamond like carbon (DLC) thin films in an effort to understand the chemical bonding involved and investigate possible phase separation routes in boron carbon nitride (BCN) films. In addition, we investigated the effect of implanted C{sup +} ions in sputter deposited amorphous boron nitride (a-BN) films. Implanted ion energies for all ion species were set at 40 KeV. Implanted films were then analyzed using x-ray photoelectron spectroscopy (XPS). The changes in the chemical composition and bonding chemistry due to ion-implantationmore » were examined at different depths of the films using sequential ion-beam etching and high resolution XPS analysis cycles. A comparative analysis has been made with the results from sputter deposited BCN films suggesting that implanted nitrogen and carbon atoms behaved very similar to nitrogen and carbon atoms in sputter deposited BCN films. We found that implanted nitrogen atoms would prefer bonding to carbon atoms in the films only if there is no boron atom in the vicinity or after all available boron atoms have been saturated with nitrogen. Implanted carbon atoms also preferred to either bond with available boron atoms or, more likely bonded with other implanted carbon atoms. These results were also supported by ab-initio density functional theory calculations which indicated that carbon-carbon bonds were energetically preferable to carbon-boron and carbon-nitrogen bonds.« less

Characterization of the Oxidation State of 229 Th Recoils Implanted in MgF2 for the Search of the Low-lying 229 Th Isomeric State

NASA Astrophysics Data System (ADS)

Barker, Beau; Meyer, Edmund; Schacht, Mike; Collins, Lee; Wilkerson, Marianne; Zhao, Xinxin

2016-05-01

The low-lying (7.8 eV) isomeric state in 229 Th has the potential to become a nuclear frequency standard. 229 Th recoils from 233 U decays have been collected in MgF2 for use in the direct search of the transition. Of interest is the oxidation state of the implanted 229 Th atoms as this can have an influence on the decay mechanisms and photon emission rate. Too determine the oxidation state of the implanted 229 Th recoils we have employed laser induced florescence (LIF), and plan-wave pseudopotential DFT calculations to search for emission from thorium ions in oxidation states less than + 4. Our search focused on detecting emission from Th3+ ions. The DFT calculations predicted the Th3+ state to be the most likely to be present in the crystal after Th4+. We also calculated the band structure for the Th3+ doped MgF2 crystal. For LIF spectra a number of excitation wavelengths were employed, emission spectra in the visible to near-IR were recorded along with time-resolved emission spectra. We have found no evidence for Th3+ in the MgF2 plates. We also analyzed the detection limit of our apprentice and found that the minimum number of Th3+ atoms that we could detect is quite small compared to the number of implanted 229 Th recoils. The number of implanted 229 Th recoils was derived from a γ-ray spectrum by monitoring emission from the daughters of 228 Th. These were present in the MgF2 plates due to a 232 U impurity, which decays to 228 Th, in the source. LA-UR-16-20442.

Influence of nitrogen admixture to argon on the ion energy distribution in reactive high power pulsed magnetron sputtering of chromium

NASA Astrophysics Data System (ADS)

Breilmann, W.; Maszl, C.; Hecimovic, A.; von Keudell, A.

2017-04-01

Reactive high power impulse magnetron sputtering (HiPIMS) of metals is of paramount importance for the deposition of various oxides, nitrides and carbides. The addition of a reactive gas such as nitrogen to an argon HiPIMS plasma with a metal target allows the formation of the corresponding metal nitride on the substrate. The addition of a reactive gas introduces new dynamics into the plasma process, such as hysteresis, target poisoning and the rarefaction of two different plasma gases. We investigate the dynamics for the deposition of chromium nitride by a reactive HiPIMS plasma using energy- and time-resolved ion mass spectrometry, fast camera measurements and temporal and spatially resolved optical emission spectroscopy. It is shown that the addition of nitrogen to the argon plasma gas significantly changes the appearance of the localized ionization zones, the so-called spokes, in HiPIMS plasmas. In addition, a very strong modulation of the metal ion flux within each HiPIMS pulse is observed, with the metal ion flux being strongly suppressed and the nitrogen molecular ion flux being strongly enhanced in the high current phase of the pulse. This behavior is explained by a stronger return effect of the sputtered metal ions in the dense plasma above the racetrack. This is best observed in a pure nitrogen plasma, because the ionization zones are mostly confined, implying a very high local plasma density and consequently also an efficient scattering process.

Signal yields of keV electronic recoils and their discrimination from nuclear recoils in liquid xenon

NASA Astrophysics Data System (ADS)

Aprile, E.; Aalbers, J.; Agostini, F.; Alfonsi, M.; Amaro, F. D.; Anthony, M.; Arneodo, F.; Barrow, P.; Baudis, L.; Bauermeister, B.; Benabderrahmane, M. L.; Berger, T.; Breur, P. A.; Brown, A.; Brown, E.; Bruenner, S.; Bruno, G.; Budnik, R.; Bütikofer, L.; Calvén, J.; Cardoso, J. M. R.; Cervantes, M.; Cichon, D.; Coderre, D.; Colijn, A. P.; Conrad, J.; Cussonneau, J. P.; Decowski, M. P.; de Perio, P.; di Gangi, P.; di Giovanni, A.; Diglio, S.; Eurin, G.; Fei, J.; Ferella, A. D.; Fieguth, A.; Fulgione, W.; Gallo Rosso, A.; Galloway, M.; Gao, F.; Garbini, M.; Geis, C.; Goetzke, L. W.; Grandi, L.; Greene, Z.; Grignon, C.; Hasterok, C.; Hogenbirk, E.; Howlett, J.; Itay, R.; Kaminsky, B.; Kazama, S.; Kessler, G.; Kish, A.; Landsman, H.; Lang, R. F.; Lellouch, D.; Levinson, L.; Lin, Q.; Lindemann, S.; Lindner, M.; Lombardi, F.; Lopes, J. A. M.; Mahlstedt, J.; Manfredini, A.; Maris, I.; Marrodán Undagoitia, T.; Masbou, J.; Massoli, F. V.; Masson, D.; Mayani, D.; Messina, M.; Micheneau, K.; Molinario, A.; Morâ, K.; Murra, M.; Naganoma, J.; Ni, K.; Oberlack, U.; Pakarha, P.; Pelssers, B.; Persiani, R.; Piastra, F.; Pienaar, J.; Pizzella, V.; Piro, M.-C.; Plante, G.; Priel, N.; Ramírez García, D.; Rauch, L.; Reichard, S.; Reuter, C.; Rizzo, A.; Rupp, N.; Saldanha, R.; Dos Santos, J. M. F.; Sartorelli, G.; Scheibelhut, M.; Schindler, S.; Schreiner, J.; Schumann, M.; Scotto Lavina, L.; Selvi, M.; Shagin, P.; Shockley, E.; Silva, M.; Simgen, H.; Sivers, M. V.; Stein, A.; Thers, D.; Tiseni, A.; Trinchero, G.; Tunnell, C.; Vargas, M.; Wang, H.; Wang, Z.; Wei, Y.; Weinheimer, C.; Wittweg, C.; Wulf, J.; Ye, J.; Zhang, Y.; Zhu, T.; Xenon Collaboration

2018-05-01

We report on the response of liquid xenon to low energy electronic recoils below 15 keV from beta decays of tritium at drift fields of 92 V /cm , 154 V /cm and 366 V /cm using the XENON100 detector. A data-to-simulation fitting method based on Markov Chain Monte Carlo is used to extract the photon yields and recombination fluctuations from the experimental data. The photon yields measured at the two lower fields are in agreement with those from literature; additional measurements at a higher field of 366 V /cm are presented. The electronic and nuclear recoil discrimination as well as its dependence on the drift field and photon detection efficiency are investigated at these low energies. The results provide new measurements in the energy region of interest for dark matter searches using liquid xenon.

Light output response of EJ-309 liquid organic scintillator to 2.86-3.95 MeV carbon recoil ions due to neutron elastic and inelastic scatter

NASA Astrophysics Data System (ADS)

Norsworthy, Mark A.; Ruch, Marc L.; Hamel, Michael C.; Clarke, Shaun D.; Hausladen, Paul A.; Pozzi, Sara A.

2018-03-01

We present the first measurements of energy-dependent light output from carbon recoils in the liquid organic scintillator EJ-309. For this measurement, neutrons were produced by an associated particle deuterium-tritium generator and scattered by a volume of EJ-309 scintillator into stop detectors positioned at four fixed angles. Carbon recoils in the scintillator were isolated using triple coincidence among the associated particle detector, scatter detector, and stop detectors. The kinematics of elastic and inelastic scatter allowed data collection at eight specific carbon recoil energies between 2.86 and 3.95 MeV. We found the light output caused by carbon recoils in this energy range to be approximately 1.14% of that caused by electrons of the same energy, which is comparable to the values reported for other liquid organic scintillators. A comparison of the number of scattered neutrons at each angle to a Monte Carlo N-Particle eXtended simulation indicates that the ENDF/B-VII.1 evaluation of differential cross sections for 14.1 MeV neutrons on carbon has discrepancies with the experiment as large as 55%, whereas those reported in the JENDL-4.0u evaluation agree with experiment.

Friction and Wear Properties of As-deposited and Carbon Ion-implanted Diamond Films

NASA Technical Reports Server (NTRS)

Miyoshi, Kazuhisa

1994-01-01

Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 ke V ion energy, resulting in a dose of 1.2310(exp 17) carbon ions/cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, x-ray photoelectron spectroscopy, and x-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40 percent relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and were properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to 10(exp -8)mm(exp 3)/N-m) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4)mm(exp 3/N-m) in ultrahigh vacuum. The carbon ion implanation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, nondiamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine- and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7)mm(exp 3/N-m). Even in ultrahigh vacuum, the presence of the nondiamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6)mm(exp 3)/N-m. Thus, the carbon ion-implanted, fine

Friction and Wear Properties of As-Deposited and Carbon Ion-Implanted Diamond Films

NASA Technical Reports Server (NTRS)

Miyoshi, Kazuhisa

1996-01-01

Recent work on the friction and wear properties of as-deposited and carbon ion-implanted diamond films was reviewed. Diamond films were produced by the microwave plasma chemical vapor deposition (CVD) technique. Diamond films with various grain sizes and surface roughnesses were implanted with carbon ions at 60 keV ion energy, resulting in a dose of 1.2 x 10(exp 17) carbon ions per cm(exp 2). Various analytical techniques, including Raman spectroscopy, proton recoil analysis, Rutherford backscattering, transmission and scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction, were utilized to characterize the diamond films. Sliding friction experiments were conducted with a polished natural diamond pin in contact with diamond films in the three environments: humid air (40% relative humidity), dry nitrogen (less than 1 percent relative humidity), and ultrahigh vacuum (10(exp -7) Pa). The CVD diamond films indeed have friction and wear properties similar to those of natural diamond in the three environments. The as-deposited, fine-grain diamond films can be effectively used as self-lubricating, wear-resistant coatings that have low coefficients of friction (0.02 to 0.04) and low wear rates (10(exp -7) to lO(exp -8) mm(exp 3) N(exp -1) m(exp -1)) in both humid air and dry nitrogen. However, they have high coefficients of friction (1.5 to 1.7) and a high wear rate (10(exp -4) mm(exp 7) N(exp -1) m(exp -1)) in ultrahigh vacuum. The carbon ion implantation produced a thin surficial layer (less than 0.1 micron thick) of amorphous, non-diamond carbon on the diamond films. In humid air and dry nitrogen, the ion-implanted, fine and coarse-grain diamond films have a low coefficient of friction (around 0.1) and a low wear rate (10(exp -7) mm(exp 3) N(exp -1) m(exp-1)). Even in ultrahigh vacuum, the presence of the non-diamond carbon layer reduced the coefficient of friction of fine-grain diamond films to 0.1 or lower and the wear rate to 10(exp -6

Nuclear Microprobe using Elastic Recoil Detection (ERD) for Hydrogen Profiling in High Temperature Protonic Conductors

NASA Technical Reports Server (NTRS)

Berger, Pascal; Sayir, Ali; Berger, Marie-Helene

2004-01-01

The interaction between hydrogen and various high temperature protonic conductors (HTPC) has not been clearly understood due to poor densification and unreacted secondary phases. the melt-processing technique is used in producing fully dense simple SrCe(0.9)Y (0.10) O(3-delta) and complex Sr3Ca(1+x)Nb(2+x)O(9-delta) perovskites that can not be achieved by solid-state sintering. the possibilities of ion beam analysis have been investigated to quantify hydrogen distribution in HTPC perovskites subjected to water heat treatment. Nuclear microprobe technique is based on the interactions of a focused ion beam of MeV light ions (H-1, H-2, He-3, He-4,.) with the sample to be analyzed to determine local elemental concentrations at the cubic micrometer scale, the elastic recoil detection analysis technique (ERDA) has been carried out using He-4(+) microbeams and detecting the resulting recoil protons. Mappings of longitudinal sections of water treated SrCeO3 and Sr(Ca(1/3)Nb(2/3))O3 perovskites have been achieved, the water treatment strongly alters the surface of simple SrCe(0.9)Y(0.10)O(3-delta) perovskite. From Rutherford Back Scattering measurements (RBS), both Ce depletion and surface re-deposition is evidenced. the ERDA investigations on water treated Sr3Ca(1+x)Nb(2+x)O(9-delta) perovskite did not exhibit any spatial difference for the hydrogen incorporation from the surface to the centre. the amount of hydrogen incorporation for Sr3Ca(1+x)Nb(2+x)O(9-delta) was low and required further development of two less conventional techniques, ERDA in forward geometry and forward elastic diffusion H-1(p,p) H-1 with coincidence detection.

Comparative study of Monte Carlo particle transport code PHITS and nuclear data processing code NJOY for recoil cross section spectra under neutron irradiation

NASA Astrophysics Data System (ADS)

Iwamoto, Yosuke; Ogawa, Tatsuhiko

2017-04-01

Because primary knock-on atoms (PKAs) create point defects and clusters in materials that are irradiated with neutrons, it is important to validate the calculations of recoil cross section spectra that are used to estimate radiation damage in materials. Here, the recoil cross section spectra of fission- and fusion-relevant materials were calculated using the Event Generator Mode (EGM) of the Particle and Heavy Ion Transport code System (PHITS) and also using the data processing code NJOY2012 with the nuclear data libraries TENDL2015, ENDF/BVII.1, and JEFF3.2. The heating number, which is the integral of the recoil cross section spectra, was also calculated using PHITS-EGM and compared with data extracted from the ACE files of TENDL2015, ENDF/BVII.1, and JENDL4.0. In general, only a small difference was found between the PKA spectra of PHITS + TENDL2015 and NJOY + TENDL2015. From analyzing the recoil cross section spectra extracted from the nuclear data libraries using NJOY2012, we found that the recoil cross section spectra were incorrect for 72Ge, 75As, 89Y, and 109Ag in the ENDF/B-VII.1 library, and for 90Zr and 55Mn in the JEFF3.2 library. From analyzing the heating number, we found that the data extracted from the ACE file of TENDL2015 for all nuclides were problematic in the neutron capture region because of incorrect data regarding the emitted gamma energy. However, PHITS + TENDL2015 can calculate PKA spectra and heating numbers correctly.

Strong coupling between a single nitrogen-vacancy spin and the rotational mode of diamonds levitating in an ion trap

NASA Astrophysics Data System (ADS)

Delord, T.; Nicolas, L.; Chassagneux, Y.; Hétet, G.

2017-12-01

A scheme for strong coupling between a single atomic spin and the rotational mode of levitating nanoparticles is proposed. The idea is based on spin readout of nitrogen-vacancy centers embedded in aspherical nanodiamonds levitating in an ion trap. We show that the asymmetry of the diamond induces a rotational confinement in the ion trap. Using a weak homogeneous magnetic field and a strong microwave driving we then demonstrate that the spin of the nitrogen-vacancy center can be strongly coupled to the rotational mode of the diamond.

Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries

DOE PAGES

Lei, Wen; Han, Lili; Xuan, Cuijuan; ...

2016-05-24

Here, nitrogen-doped carbon nanofiber (NDCN) was synthesized via carbonization of polypyrrole (PPy) coated bacterial cellulose (BC) composites, where BC serves as templates as well as precursor, and PPy serves as the nitrogen source. The synthesized NDCN was employed as electrode for both supercapacitors and Li-ion batteries. The large surface area exposed to electrolyte resulting from the 3D carbon networks leads to sufficient electrode/electrolyte interface and creates shorter transport paths of electrolyte ions and Li + ion. Besides, the three types of N dopants in NDCN improve the electronic conductivity, as well as superior electrochemical performance.

The impact of gas-surface reactions on mass spectrometric measurements of atomic nitrogen. [determination of atmosphere ion sources

NASA Technical Reports Server (NTRS)

Engebretson, M. J.; Mauersberger, K.

1979-01-01

The paper presents a simplified model of the ion source chemistry, explains several details of the data reduction method used in obtaining atomic-nitrogen (N) densities from OSS data, and discusses implications of gas-surface reactions for the design of future satellite-borne mass spectrometers. Because of various surface reactions, N appears in three different forms in the ion source, as N, NO, and NO2. Considering the rather small spin modulation of NO and NO2 in the semi-open ionization chamber used in the OSS instrument, it is not surprising that these reaction products have not been previously identified in closed source instruments as a measure of the presence of atomic nitrogen. Warmup and/or outgassing of the ion source are shown to drastically reduce the NO2 concentration, thereby making possible reliable measurement of ambient N densities.

Recoil tritium reactions with cyclohexene and methylcyclohexene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fee, Darrell Clark

1973-06-01

A study has been made of the reactions of recoil tritium atoms with cyclohexene with methyl cyclohexene. Principle attention was given to unimolecular decomposition processes following T-for-H substitution.

Recoiling from a Kick in the Head-On Case

NASA Technical Reports Server (NTRS)

Choi, Dae-Il; Kelly, Bernard J.; Boggs, William D.; Baker, John G.; Centrella, Joan; Van Meter, James

2007-01-01

Recoil "kicks" induced by gravitational radiation are expected in the inspiral and merger of black holes. Recently the numerical relativity community has begun to measure the significant kicks found when both unequal masses and spins are considered. Because understanding the cause and magnitude of each component of this kick may be complicated in inspiral simulations, we consider these effects in the context of a simple test problem. We study recoils from collisions of binaries with initially head-on trajectories, starting with the simplest case of equal masses with no spin; adding spin and varying the mass ratio, both separately and jointly. We find spin-induced recoils to be significant even in head-on configurations. Additionally, it appears that the scaling of transverse kicks with spins is consistent with post-Newtonian (PN) theory, even though the kick is generated in the nonlinear merger interaction, where PN theory should not apply. This suggests that a simple heuristic description might be effective in the estimation of spin-kicks.

Synthesis of superheavy elements at the Dubna gas-filled recoil separator

NASA Astrophysics Data System (ADS)

Voinov, A. A.

2016-12-01

A survey of experiments at the Dubna gas-filled recoil separator (Laboratory of Nuclear Reactions, JINR, Dubna) aimed at the detection and study of the "island of stability" of superheavy nuclei produced in complete fusion reactions of 48Ca ions and 238U-249Cf target nuclei is given. The problems of synthesis of superheavy nuclei, methods for their identification, and investigation of their decay properties, including the results of recent experiments at other separators (SHIP, BGS, TASCA) and chemical setups, are discussed. The studied properties of the new nuclei, the isotopes of elements 112-118, as well as the properties of their decay products, indicate substantial growth of stability of the heaviest nuclei with increasing number of neutrons in the nucleus as the magic number of neutrons N = 184 is approached.

Measurement of Nuclear Recoils in the CDMS II Dark Matter Search

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fallows, Scott Mathew

The Cryogenic Dark Matter Search (CDMS) experiment is designed to directly detect elastic scatters of weakly-interacting massive dark matter particles (WIMPs), on target nuclei in semiconductor crystals composed of Si and Ge. These scatters would occur very rarely, in an overwhelming background composed primarily of electron recoils from photons and electrons, as well as a smaller but non-negligible background of WIMP-like nuclear recoils from neutrons. The CDMS II generation of detectors simultaneously measure ionization and athermal phonon signals from each scatter, allowing discrimination against virtually all electron recoils in the detector bulk. Pulse-shape timing analysis allows discrimination against nearly allmore » remaining electron recoils taking place near detector surfaces. Along with carefully limited neutron backgrounds, this experimental program allowed for \\background- free" operation of CDMS II at Soudan, with less than one background event expected in each WIMP-search analysis. As a result, exclusionary upper-limits on WIMP-nucleon interaction cross section were placed over a wide range of candidate WIMP masses, ruling out large new regions of parameter space.« less

Reduction of ion transport and turbulence via dilution with nitrogen and neon injection in C-Mod deuterium plasmas

NASA Astrophysics Data System (ADS)

Porkolab, M.; Ennever, P.; Baek, S. G.; Creely, A. J.; Edlund, E. M.; Hughes, J.; Rice, J. E.; Rost, J. C.; White, A. E.; Reinke, M. L.; Staebler, G.; Candy, J.; Alcator C-Mod Team

2016-10-01

Recent experiments on C-Mod ohmic plasmas and gyrokinetic studies indicated that dilution of deuterium plasmas by injection of nitrogen decreased the ion diffusivity and may also alter the direction of intrinsic toroidal rotation. Simulations with TGLF and GYRO showed that dilution of deuterium ions in low density (LOC) plasmas increased the critical ion temperature gradient, while in high density (SOC) plasmas it decreased the stiffness. The density fluctuation spectrum measured in low q95 plasmas with Phase Contrast Imaging (PCI), and corroborated with spatially localized reflectometer measurements show a reduction of turbulence near r/a = 0.8 with kρs <= 1, in agreement with modeling predictions in this region where the ion turbulence is well above marginal stability. Measurements also indicate that reversal of the toroidal rotation direction near the SOC-LOC transition may depend on ion collisionality rather than that of electrons. New experiments with neon seeding, which may be more relevant to ITER than with nitrogen seeding, show similar results. The impact of dilution on Te turbulence as measured with CECE diagnostic will also be presented. Supported by US DOE Awards DE-FG02-94-ER54235 and DE-FC02-99-ER54512.

General Synthesis of Transition-Metal Oxide Hollow Nanospheres/Nitrogen-Doped Graphene Hybrids by Metal-Ammine Complex Chemistry for High-Performance Lithium-Ion Batteries.

PubMed

Chen, Jiayuan; Wu, Xiaofeng; Gong, Yan; Wang, Pengfei; Li, Wenhui; Mo, Shengpeng; Peng, Shengpan; Tan, Qiangqiang; Chen, Yunfa

2018-02-09

We present a general and facile synthesis strategy, on the basis of metal-ammine complex chemistry, for synthesizing hollow transition-metal oxides (Co 3 O 4 , NiO, CuO-Cu 2 O, and ZnO)/nitrogen-doped graphene hybrids, potentially applied in high-performance lithium-ion batteries. The oxygen-containing functional groups of graphene oxide play a prerequisite role in the formation of hollow transition-metal oxides on graphene nanosheets, and a significant hollowing process occurs only when forming metal (Co 2+ , Ni 2+ , Cu 2+ , or Zn 2+ )-ammine complex ions. Moreover, the hollowing process is well correlated with the complexing capacity between metal ions and NH 3 molecules. The significant hollowing process occurs for strong metal-ammine complex ions including Co 2+ , Ni 2+ , Cu 2+ , and Zn 2+ ions, and no hollow structures formed for weak and/or noncomplex Mn 2+ and Fe 3+ ions. Simultaneously, this novel strategy can also achieve the direct doping of nitrogen atoms into the graphene framework. The electrochemical performance of two typical hollow Co 3 O 4 or NiO/nitrogen-doped graphene hybrids was evaluated by their use as anodic materials. It was demonstrated that these unique nanostructured hybrids, in contrast with the bare counterparts, solid transition-metal oxides/nitrogen-doped graphene hybrids, perform with significantly improved specific capacity, superior rate capability, and excellent capacity retention. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Rutherford Backscattering Spectrometry studies of 100 keV nitrogen ion implanted polypropylene polymer

NASA Astrophysics Data System (ADS)

Chawla, Mahak; Aggarwal, Sanjeev; Sharma, Annu

2017-09-01

The effect of nitrogen ion implantation on the structure and composition in polypropylene (PP) polymer has been studied. Implantation was carried out using 100 keV N+ ions at different fluences of 1 × 1015, 1 × 1016 and 1 × 1017 ions cm-2 with beam current density of ∼0.65 μA cm-2. Surface morphological changes in the pre- and post-implanted PP specimens have been studied using Rutherford Backscattering Spectrometry (RBS) and UV-Visible Spectroscopy. The spatial distribution of implantation induced modification in the form of carbonization and dehydrogenation in the near surface region of PP matrix, the projected range, retained dose of implanted nitrogen, the various elements present in the implanted layers and their differential cross-sections have been analyzed using RBS spectra. RUMP simulation yielded an increase in the concentration of carbon near the surface from 33 at.% (virgin) to 42 at.% at fluence of 1 × 1017 N+ cm-2. Further, optical absorption has been found to increase with a shift in the absorption edge from UV towards visible region with increasing fluence. UV-Vis absorption spectra also indicate a drastic decrease in optical energy gap from 4.12 eV (virgin) to 0.25 eV (1 × 1017 N+ cm-2) indicating towards the formation of carbonaceous network in the implanted region. All these changes observed using UV-Visible have been further correlated with the outcomes of the RBS characterization.

Direct Measurement of Recoil Effects on Ar-Ar Standards

NASA Astrophysics Data System (ADS)

Hall, C. M.

2011-12-01

Advances in the precision possible with the Ar-Ar method using new techniques and equipment have led to considerable effort to improve the accuracy of the calibration of interlaboratory standards. However, ultimately the accuracy of the method relies on the measurement of 40Ar*/39ArK ratios on primary standards that have been calibrated with the K-Ar method and, in turn, on secondary standards that are calibrated against primary standards. It is usually assumed that an Ar-Ar total gas age is equivalent to a K-Ar age, but this assumes that there is zero loss of Ar due to recoil. Instead, traditional Ar-Ar total gas ages are in fact Ar retention ages [1] and not, strictly speaking, comparable to K-Ar ages. There have been efforts to estimate the importance of this effect on standards along with prescriptions for minimizing recoil effects [2,3], but these studies have relied on indirect evidence for 39Ar recoil. We report direct measurements of 39Ar recoil for a set of primary and secondary standards using the vacuum encapsulation techniques of [1] and show that significant adjustments to ages assigned to some standards may be needed. The fraction f of 39Ar lost due to recoil for primary standards MMhb-1 hornblende and GA-1550 biotite are 0.00367 and 0.00314 respectively. It is possible to modify the assumed K-Ar ages of these standards so that when using their measured Ar retention 40Ar*/39ArK ratios, one obtains a correct K-Ar age for an unknown, assuming that the unknown sample has zero loss of 39Ar due to recoil. Assuming a primary K-Ar age for MMhb-1 of 520.4 Ma, the modified age would be 522.1 Ma and assuming a primary K-Ar age for GA-1550 of 98.79 Ma [4] yields a modified effective age of 99.09 Ma. Measured f values for secondary standards FCT-3 biotite, FCT-2 sanidine and TCR-2 sanidine are 0.00932, 0.00182 and 0.00039 respectively. Using an R value for FCT-3 biotite relative to MMhb-1 [5], the K-Ar age for this standard would be 27.83 Ma and using R values

Cobalt ion-coordinated self-assembly synthesis of nitrogen-doped ordered mesoporous carbon nanosheets for efficiently catalyzing oxygen reduction.

PubMed

Wang, Haitao; Wang, Wei; Asif, Muhammad; Yu, Yang; Wang, Zhengyun; Wang, Junlei; Liu, Hongfang; Xiao, Junwu

2017-10-19

The design and synthesis of a promising porous carbon-based electrocatalyst with an ordered and uninterrupted porous structure for oxygen reduction reaction (ORR) is still a significant challenge. Herein, an efficient catalyst based on cobalt-embedded nitrogen-doped ordered mesoporous carbon nanosheets (Co/N-OMCNS) is successfully prepared through a two-step procedure (cobalt ion-coordinated self-assembly and carbonization process) using 3-aminophenol as a nitrogen source, cobalt acetate as a cobalt source and Pluronic F127 as a mesoporous template. This work indicates that the formation of a two dimensional nanosheet structure is directly related to the extent of the cobalt ion coordination interaction. Moreover, the critical roles of pyrolysis temperature in nitrogen doping and ORR catalytic activity are also investigated. Benefiting from the high surface area and graphitic degree, high contents of graphitic N and pyridinic N, ordered interconnected mesoporous carbon framework, as well as synergetic interaction between the cobalt nanoparticles and protective nitrogen doped graphitic carbon layer, the resultant optimal catalyst Co/N-OMCNS-800 (pyrolyzed at 800 °C) exhibits comparable ORR catalytic activity to Pt/C, superior tolerance to methanol crossover and stability.

Ion probe measurements of carbon and nitrogen in iron meteorites

NASA Astrophysics Data System (ADS)

Sugiura, Naoji

1998-05-01

Carbon and nitrogen distributions in iron meteorites, their concentrations in various phases, and their isotopic compositions in certain phases were measured by secondary ion mass spectrometry (SIMS). Taenite (and its decomposition products) is the main carrier of carbon except for IAB irons where graphite and/or carbide (cohenite) may be the main carrier. Taenite is also the main carrier of nitrogen in most iron meteorites unless nitrides (carlsbergite CrN or roaldite (Fe,Ni)4N) are present. Carbon and nitrogen distributions in taenite are well correlated, unless carbides and/or nitrides are exsolved. There seem to be three types of C and N distributions within taenite. 1) These elements are enriched at the center of taenite (convex type). 2) They are enriched at the edge of taenite (concave type). 3) They are enriched near but some distance away from the edge of taenite (complex type). The case 1) is explained as equilibrium distribution of C and N in Fe-Ni alloy with M- shape nickel concentration profile. The case 2) seems to be best explained as diffusion controlled C and N distributions. In the case 3), the interior of taenite has been transformed to the a phase (kamacite or martensite). C and N were expelled from the a phase and enriched near the inner border of the remaining g phase. Such differences in the C and N distributions in taenite may reflect different cooling rates of iron meteorites. Nitrogen concentrations in taenite are quite high approaching 1 wt.% in some irons. Nitride (carlsbergite and roaldite) is present in meteorites with high nitrogen concentrations in taenite, suggesting that the nitride was formed due to supersaturation of the metallic phases with nitrogen. The same tendency is generally observed for carbon, i.e. high C concentrations in taenite correlate with the presence of carbide and/or graphite. Concentrations of C and N in kamacite are generally below detection limits. Isotopic compositions of C and N in taenite can be measured

Effects of nitrogen ion implantation time on tungsten films deposited by DC magnetron sputtering on AISI 410 martensitic stainless steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malau, Viktor, E-mail: malau@ugm.ac.id; Ilman, Mochammad Noer, E-mail: noer-ilman@yahoo.com; Iswanto, Priyo Tri, E-mail: priyatri@yahoo.com

Nitrogen ion implantation time on tungsten thin film deposited on surface of AISI 410 steel has been performed. Tungsten thin film produced by dc magnetron sputtering method was deposited on AISI 410 martensitic stainless steel substrates, and then the nitrogen ions were implanted on tungsten thin film. The objective of this research is to investigate the effects of implantation deposition time on surface roughness, microhardness, specific wear and corrosion rate of nitrogen implanted on tungsten film. Magnetron sputtering process was performed by using plasma gas of argon (Ar) to bombardier tungsten target (W) in a vacuum chamber with a pressuremore » of 7.6 x 10{sup −2} torr, a voltage of 300 V, a sputter current of 80 mA for sputtered time of 10 minutes. Nitrogen implantation on tungsten film was done with an initial pressure of 3x10{sup −6} mbar, a fluence of 2 x 10{sup 17} ions/cm{sup 2}, an energy of 100 keV and implantation deposition times of 0, 20, 30 and 40 minutes. The surface roughness, microhardness, specific wear and corrosion rate of the films were evaluated by surfcorder test, Vickers microhardness test, wear test and potentiostat (galvanostat) test respectively. The results show that the nitrogen ions implanted deposition time on tungsten film can modify the surface roughness, microhardness, specific wear and corrosion rate. The minimum surface roughness, specific wear and corrosion rate can be obtained for implantation time of 20 minutes and the maximum microhardness of the film is 329 VHN (Vickers Hardness Number) for implantation time of 30 minutes. The specific wear and corrosion rate of the film depend directly on the surface roughness.« less

Nonlinear gravitational recoil from the mergers of precessing black-hole binaries

NASA Astrophysics Data System (ADS)

Lousto, Carlos O.; Zlochower, Yosef

2013-04-01

We present results from an extensive study of 88 precessing, equal-mass black-hole binaries with large spins (83 with intrinsic spins |S→i/mi2| of 0.8 and 5 with intrinsic spins of 0.9), and use these data to model new nonlinear contributions to the gravitational recoil imparted to the merged black hole. We find a new effect, the cross kick, that enhances the recoil for partially aligned binaries beyond the hangup kick effect. This has the consequence of increasing the probabilities of recoils larger than 2000kms-1 by nearly a factor of 2, and consequently, of black holes getting ejected from galaxies, as well as the observation of large differential redshifts/blueshifts in the cores of recently merged galaxies.

A recoil resilient lumen support, design, fabrication and mechanical evaluation

NASA Astrophysics Data System (ADS)

Mehdizadeh, Arash; Ali, Mohamed Sultan Mohamed; Takahata, Kenichi; Al-Sarawi, Said; Abbott, Derek

2013-06-01

Stents are artificial implants that provide scaffolding to a cavity inside the body. This paper presents a new luminal device for reducing the mechanical failure of stents due to recoil, which is one of the most important issues in stenting. This device, which we call a recoil-resilient ring (RRR), is utilized standalone or potentially integrated with existing stents to address the problem of recoil. The proposed structure aims to minimize the need for high-pressure overexpansion that can induce intra-luminal trauma and excess growth of vascular tissue causing later restenosis. The RRR is an overlapped open ring with asymmetrical sawtooth structures that are intermeshed. These teeth can slide on top of each other, while the ring is radially expanded, but interlock step-by-step so as to keep the final expanded state against compressional forces that normally cause recoil. The RRRs thus deliver balloon expandability and, when integrated with a stent, bring both radial rigidity and longitudinal flexibility to the stent. The design of the RRR is investigated through finite element analysis (FEA), and then the devices are fabricated using micro-electro-discharge machining of 200-µm-thick Nitinol sheet. The standalone RRR is balloon expandable in vitro by 5-7 Atm in pressure, which is well within the recommended in vivo pressure ranges for stenting procedures. FEA compression tests indicate 13× less reduction of the cross-sectional area of the RRR compared with a typical stainless steel stent. These results also show perfect elastic recovery of the RRR after removal of the pressure compared to the remaining plastic deformations of the stainless steel stent. On the other hand, experimental loading tests show that the fabricated RRRs have 2.8× radial stiffness compared to a two-column section of a commercial stent while exhibiting comparable elastic recovery. Furthermore, testing of in vitro expansion in a mock artery tube shows around 2.9% recoil, approximately 5-11�

A series of inorganic solid nitrogen sources for the synthesis of metal nitride clusterfullerenes: the dependence of production yield on the oxidation state of nitrogen and counter ion.

PubMed

Liu, Fupin; Guan, Jian; Wei, Tao; Wang, Song; Jiao, Mingzhi; Yang, Shangfeng

2013-04-01

A series of nitrogen-containing inorganic solid compounds with variable oxidation states of nitrogen and counter ions have been successfully applied as new inorganic solid nitrogen sources toward the synthesis of Sc-based metal nitride clusterfullerenes (Sc-NCFs), including ammonium salts [(NH4)xH(3-x)PO4 (x = 0-2), (NH4)2SO4, (NH4)2CO3, NH4X (X = F, Cl), NH4SCN], thiocyanate (KSCN), nitrates (Cu(NO3)2, NaNO3), and nitrite (NaNO2). Among them, ammonium phosphates ((NH4)xH(3-x)PO4, x = 1-3) and ammonium thiocyanate (NH4SCN) are revealed to behave as better nitrogen sources than others, and the highest yield of Sc-NCFs is achieved when NH4SCN was used as a nitrogen source. The optimum molar ratio of Sc2O3:(NH4)3PO4·3H2O:C and Sc2O3:NH4SCN:C has been determined to be 1:2:15 and 1:3:15, respectively. The thermal decomposition products of these 12 inorganic compounds have been discussed in order to understand their different performances toward the synthesis of Sc-NCFs, and accordingly the dependence of the production yield of Sc-NCFs on the oxidation state of nitrogen and counter ion is interpreted. The yield of Sc3N@C80 (I(h) + D(5h)) per gram Sc2O3 by using the N2-based group of nitrogen sources (thiocyanate, nitrates, and nitrite) is overall much lower than those by using gaseous N2 and NH4SCN, indicating the strong dependence of the yield of Sc-NCFs on the oxidation state of nitrogen, which is attributed to the "in-situ" redox reaction taking place for the N2-based group of nitrogen sources during discharging. For NH3-based group of nitrogen sources (ammonium salts) which exhibits a (-3) oxidation states of nitrogen, their performance as nitrogen sources is found to be sensitively dependent on the anion, and this is understood by considering their difference on the thermal stability and/or decomposition rate. Contrarily, for the N2-based group of nitrogen sources, the formation of Sc-NCFs is independent to both the oxidation state of nitrogen (+3 or +5) and the

Surface periodicity of Ir(110) from time-of-flight scattering and recoiling spectrometry (TOF-SARS)

NASA Astrophysics Data System (ADS)

Bu, H.; Shi, M.; Rabalais, J. W.

1991-03-01

The surface periodicity of the Ir(110) surface in both the clean reconstructed (1×3) and oxygen stabilized unreconstructed (1×1) phases have been investigated using time-of-flight scattering and recoiling spectrometry (TOF-SARS). A pulsed 4 keV Ar + ion beam is directed at a grazing incident angle to the surface and the scattered neutral plus ion flux is monitored as a function of beam exit angle and crystal azimuthal angle. It is demonstrated that either maxima or minima are obtained in the scattered flux along the low-index crystallographic directions depending on whether near-specular or off-specular scattering conditions, respectively, are used. These scattering intensity patterns as a function of crystal azimuthal angle provide a direct measure of the surface periodicity. These intensity variations are explained in terms of the Lindhard critical angle, semichannel focusing effects, and trajectory simulations.

High density nitrogen-vacancy sensing surface created via He{sup +} ion implantation of {sup 12}C diamond

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kleinsasser, Ed E., E-mail: edklein@uw.edu; Stanfield, Matthew M.; Banks, Jannel K. Q.

2016-05-16

We present a promising method for creating high-density ensembles of nitrogen-vacancy centers with narrow spin-resonances for high-sensitivity magnetic imaging. Practically, narrow spin-resonance linewidths substantially reduce the optical and RF power requirements for ensemble-based sensing. The method combines isotope purified diamond growth, in situ nitrogen doping, and helium ion implantation to realize a 100 nm-thick sensing surface. The obtained 10{sup 17 }cm{sup −3} nitrogen-vacancy density is only a factor of 10 less than the highest densities reported to date, with an observed 200 kHz spin resonance linewidth over 10 times narrower.

Synthesis of superheavy elements at the Dubna gas-filled recoil separator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Voinov, A. A., E-mail: voinov@jinr.ru; Collaboration: JINR

2016-12-15

A survey of experiments at the Dubna gas-filled recoil separator (Laboratory of Nuclear Reactions, JINR, Dubna) aimed at the detection and study of the “island of stability” of superheavy nuclei produced in complete fusion reactions of {sup 48}Ca ions and {sup 238}U–{sup 249}Cf target nuclei is given. The problems of synthesis of superheavy nuclei, methods for their identification, and investigation of their decay properties, including the results of recent experiments at other separators (SHIP, BGS, TASCA) and chemical setups, are discussed. The studied properties of the new nuclei, the isotopes of elements 112–118, as well as the properties of theirmore » decay products, indicate substantial growth of stability of the heaviest nuclei with increasing number of neutrons in the nucleus as the magic number of neutrons N = 184 is approached.« less

Role of nuclear charge change and nuclear recoil on shaking processes and their possible implication on physical processes

NASA Astrophysics Data System (ADS)

Sharma, Prashant

2017-12-01

The probable role of the sudden nuclear charge change and nuclear recoil in the shaking processes during the neutron- or heavy-ion-induced nuclear reactions and weakly interacting massive particle-nucleus scattering has been investigated in the present work. Using hydrogenic wavefunctions, general analytical expressions of survival, shakeup/shakedown, and shakeoff probability have been derived for various subshells of hydrogen-like atomic systems. These expressions are employed to calculate the shaking, shakeup/shakedown, and shakeoff probabilities in some important cases of interest in the nuclear astrophysics and the dark matter search experiments. The results underline that the shaking processes are one of the probable channels of electronic transitions during the weakly interacting massive particle-nucleus scattering, which can be used to probe the dark matter in the sub-GeV regime. Further, it is found that the shaking processes initiating due to nuclear charge change and nuclear recoil during the nuclear reactions may influence the electronic configuration of the participating atomic systems and thus may affect the nuclear reaction measurements at astrophysically relevant energies.

Remote recoil: a new wave mean interaction effect

NASA Astrophysics Data System (ADS)

Bühler, Oliver; McIntyre, Michael E.

2003-10-01

We present a theoretical study of a fundamentally new wave mean or wave vortex interaction effect able to force persistent, cumulative change in mean flows in the absence of wave breaking or other kinds of wave dissipation. It is associated with the refraction of non-dissipating waves by inhomogeneous mean (vortical) flows. The effect is studied in detail in the simplest relevant model, the two-dimensional compressible flow equations with a generic polytropic equation of state. This includes the usual shallow-water equations as a special case. The refraction of a narrow, slowly varying wavetrain of small-amplitude gravity or sound waves obliquely incident on a single weak (low Froude or Mach number) vortex is studied in detail. It is shown that, concomitant with the changes in the waves' pseudomomentum due to the refraction, there is an equal and opposite recoil force that is felt, in effect, by the vortex core. This effective force is called a ‘remote recoil’ to stress that there is no need for the vortex core and wavetrain to overlap in physical space. There is an accompanying ‘far-field recoil’ that is still more remote, as in classical vortex-impulse problems. The remote-recoil effects are studied perturbatively using the wave amplitude and vortex weakness as small parameters. The nature of the remote recoil is demonstrated in various set-ups with wavetrains of finite or infinite length. The effective recoil force {bm R}_V on the vortex core is given by an expression resembling the classical Magnus force felt by moving cylinders with circulation. In the case of wavetrains of infinite length, an explicit formula for the scattering angle theta_* of waves passing a vortex at a distance is derived correct to second order in Froude or Mach number. To this order {bm R}_V {~} theta_*. The formula is cross-checked against numerical integrations of the ray-tracing equations. This work is part of an ongoing study of internal-gravity-wave dynamics in the

Highly crystalline lithium titanium oxide sheets coated with nitrogen-doped carbon enable high-rate lithium-ion batteries.

PubMed

Han, Cuiping; He, Yan-Bing; Li, Baohua; Li, Hongfei; Ma, Jun; Du, Hongda; Qin, Xianying; Yang, Quan-Hong; Kang, Feiyu

2014-09-01

Sheets of Li4Ti5O12 with high crystallinity are coated with nitrogen-doped carbon (NC-LTO) using a controlled process, comprising hydrothermal reaction followed by chemical vapor deposition (CVD). Acetonitrile (CH3 CN) vapor is used as carbon and nitrogen source to obtain a thin coating layer of nitrogen-doped carbon. The layer enables the NC-LTO material to maintain its sheet structure during the high-temperature CVD process and to achieve high crystallinity. Doping with nitrogen introduces defects into the carbon coating layer, and this increased degree of disorder allows fast transportation of lithium ions in the layer. An electrode of NC-LTO synthesized at 700 °C exhibits greatly improved rate and cycling performance due to a markedly decreased total cell resistance and enhanced Li-ion diffusion coefficient (D(Li)). Specific capacities of 159.2 and 145.8 mA h g(-1) are obtained using the NC-LTO sheets, at charge/discharge rates of 1 and 10 C, respectively. These values are much higher than values for LTO particles did not undergo the acetonitrile CVD treatment. A capacity retention value as high as 94.7% is achieved for the NC-LTO sheets after 400 cycles in a half-cell at 5 C discharge rate. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Low momentum recoil detectors in CLAS12 at Jefferson Lab

NASA Astrophysics Data System (ADS)

Charles, Gabriel; CLAS Collaboration Collaboration

2017-01-01

Part of the experimental program in Hall B of the Jefferson Lab is dedicated to studying nucleon structure using DIS on nuclei and detecting low-momentum recoil particles in coincidence with the scattered electron. For this purpose, specially designed central detectors are required in place of the inner tracker of CLAS12 to detect particles with momenta below 100 MeV/c. We will present the status of the BONuS12 RTPC detector that will take data within the next 2 years. We will detail the main improvements made from the previous BONuS RTPC. In a second part, we will discuss another recoil experiment, called ALERT, that has been proposed to run in Hall B. The constraints being different, the recoil detector is based on a drift chamber and an array of scintillators. We will present the main differences between the two detectors and summarize the R&D performed to develop the ALERT detector.

Low energy nuclear recoils study in noble liquids for low-mass WIMPs

NASA Astrophysics Data System (ADS)

Wang, Lu; Mei, Dongming

2014-03-01

Detector response to low-energy nuclear recoils is critical to the detection of low-mass dark matter particles-WIMPs (Weakly interacting massive particles). Although the detector response to the processes of low-energy nuclear recoils is subtle and direct experimental calibration is rather difficult, many studies have been performed for noble liquids, NEST is a good example. However, the response of low-energy nuclear recoils, as a critical issue, needs more experimental data, in particular, with presence of electric field. We present a new design using time of flight to calibrate the large-volume xenon detector, such as LUX-Zeplin (LZ) and Xenon1T, energy scale for low-energy nuclear recoils. The calculation and physics models will be discussed based on the available data to predict the performance of the calibration device and set up criteria for the design of the device. A small test bench is built to verify the concepts at The University of South Dakota. This work is supported by DOE grant DE-FG02-10ER46709 and the state of South Dakota.

Porous nitrogen-doped carbon microspheres as anode materials for lithium ion batteries.

PubMed

Chen, Taiqiang; Pan, Likun; Loh, T A J; Chua, D H C; Yao, Yefeng; Chen, Qun; Li, Dongsheng; Qin, Wei; Sun, Zhuo

2014-10-28

Nitrogen-doped carbon microspheres (NCSs) were fabricated via a simple, fast and energy-saving microwave-assisted method followed by thermal treatment under an ammonia atmosphere. NCSs thermally treated at different temperatures were investigated as anode materials for lithium ion batteries (LIBs). The results show that NCSs treated at 900 °C exhibit a maximum reversible capacity of 816 mA h g(-1) at a current density of 50 mA g(-1) and preserve a capacity of 660 mA h g(-1) after 50 cycles, and even at a high current density of 1000 mA g(-1), a capacity of 255 mA h g(-1) is maintained. The excellent electrochemical performance of NCSs is due to their porous structure and nitrogen-doping. The present NCSs should be promising low-cost anode materials with a high capacity and good cycle stability for LIBs.

Moving towards first science with the St. George recoil separator

NASA Astrophysics Data System (ADS)

Meisel, Zachary; Berg, G. P. A.; Gilardy, G.; Moran, M.; Schmitt, J.; Seymour, C.; Stech, E.; Couder, M.

2015-10-01

The St. George recoil mass separator has recently been coupled to the 5MV St. Ana accelerator at the University of Notre Dame's Nuclear Science Lab. St. George is a unique tool designed to measure radiative alpha-capture reactions for nuclei up to A = 40 in inverse kinematics in order to directly obtain cross sections required for astrophysical models of stellar and explosive helium burning. Commissioning of St. George is presently taking place with primary beams of hydrogen, helium, and oxygen. In this presentation, results will be shown for the measured energy acceptance of St. George, which compare favorably to COSY results when employing the calculated optimal ion-optical settings. Additionally, future plans will be discussed, such as assessing the angular acceptance of St. George and the re-integration of HiPPO at the separator target position to provide a dense, windowless helium gas-jet target. The material presented in this work is partially supported by the National Science Foundation Grant No. 1419765.

Inelastic frontier: Discovering dark matter at high recoil energy

DOE PAGES

Bramante, Joseph; Fox, Patrick J.; Kribs, Graham D.; ...

2016-12-27

There exist well-motivated models of particle dark matter which predominantly scatter inelastically off nuclei in direct detection experiments. This inelastic transition causes the dark matter to upscatter in terrestrial experiments into an excited state up to 550 keV heavier than the dark matter itself. An inelastic transition of this size is highly suppressed by both kinematics and nuclear form factors. In this paper, we extend previous studies of inelastic dark matter to determine the present bounds on the scattering cross section and the prospects for improvements in sensitivity. Three scenarios provide illustrative examples: nearly pure Higgsino supersymmetric dark matter, magnetic inelasticmore » dark matter, and inelastic models with dark photon exchange. We determine the elastic scattering rate (through loop diagrams involving the heavy state) as well as verify that exothermic transitions are negligible (in the parameter space we consider). Presently, the strongest bounds on the cross section are from xenon at LUX-PandaX (when the mass splitting δ≲160 keV), iodine at PICO (when 160≲δ≲300 keV), and tungsten at CRESST (when δ≳300 keV). Amusingly, once δ≳200 keV, weak scale (and larger) dark matter–nucleon scattering cross sections are allowed. The relative competitiveness of these diverse experiments is governed by the upper bound on the recoil energies employed by each experiment, as well as strong sensitivity to the mass of the heaviest element in the detector. Several implications, including sizable recoil energy-dependent annual modulation and improvements for future experiments, are discussed. We show that the xenon experiments can improve on the PICO results, if they were to analyze their existing data over a larger range of recoil energies, i.e., 20–500 keV Intriguingly, CRESST has reported several events in the recoil energy range 45–100 keV that, if interpreted as dark matter scattering, is compatible with δ~200 keV and an

Passive mechanism of pitch recoil in flapping insect wings.

PubMed

Ishihara, D; Horie, T

2016-12-20

The high torsional flexibility of insect wings allows for elastic recoil after the rotation of the wing during stroke reversal. However, the underlying mechanism of this recoil remains unclear because of the dynamic process of transitioning from the wing rotation during stroke reversal to the maintenance of a high angle of attack during the middle of each half-stroke, when the inertial, elastic, and aerodynamic effects all have a significant impact. Therefore, the interaction between the flapping wing and the surrounding air was directly simulated by simultaneously solving the incompressible Navier-Stokes equations, the equation of motion for an elastic body, and the fluid-structure interface conditions using the three-dimensional finite element method. This direct numerical simulation controlling the aerodynamic effect revealed that the recoil is the residual of the free pitch vibration induced by the flapping acceleration during stroke reversal in the transient response very close to critical damping due to the dynamic pressure resistance of the surrounding air. This understanding will enable the control of the leading-edge vortex and lift generation, the reduction of the work performed by flapping wings, and the interpretation of the underlying necessity for the kinematic characteristics of the flapping motion.

Significantly enhanced visible light response in single TiO2 nanowire by nitrogen ion implantation

NASA Astrophysics Data System (ADS)

Wu, Pengcheng; Song, Xianyin; Si, Shuyao; Ke, Zunjian; Cheng, Li; Li, Wenqing; Xiao, Xiangheng; Jiang, Changzhong

2018-05-01

The metal-oxide semiconductor TiO2 shows enormous potential in the field of photoelectric detection; however, UV-light absorption only restricts its widespread application. It is considered that nitrogen doping can improve the visible light absorption of TiO2, but the effect of traditional chemical doping is far from being used for visible light detection. Herein, we dramatically broadened the absorption spectrum of the TiO2 nanowire (NW) by nitrogen ion implantation and apply the N-doped single TiO2 NW to visible light detection for the first time. Moreover, this novel strategy effectively modifies the surface states and thus regulates the height of Schottky barriers at the metal/semiconductor interface, which is crucial to realizing high responsivity and a fast response rate. Under the illumination of a laser with a wavelength of 457 nm, our fabricated photodetector exhibits favorable responsivity (8 A W-1) and a short response time (0.5 s). These results indicate that ion implantation is a promising method in exploring the visible light detection of TiO2.

Significantly enhanced visible light response in single TiO2 nanowire by nitrogen ion implantation.

PubMed

Wu, Pengcheng; Song, Xianyin; Si, Shuyao; Ke, Zunjian; Cheng, Li; Li, Wenqing; Xiao, Xiangheng; Jiang, Changzhong

2018-05-04

The metal-oxide semiconductor TiO 2 shows enormous potential in the field of photoelectric detection; however, UV-light absorption only restricts its widespread application. It is considered that nitrogen doping can improve the visible light absorption of TiO 2 , but the effect of traditional chemical doping is far from being used for visible light detection. Herein, we dramatically broadened the absorption spectrum of the TiO 2 nanowire (NW) by nitrogen ion implantation and apply the N-doped single TiO 2 NW to visible light detection for the first time. Moreover, this novel strategy effectively modifies the surface states and thus regulates the height of Schottky barriers at the metal/semiconductor interface, which is crucial to realizing high responsivity and a fast response rate. Under the illumination of a laser with a wavelength of 457 nm, our fabricated photodetector exhibits favorable responsivity (8 A W -1 ) and a short response time (0.5 s). These results indicate that ion implantation is a promising method in exploring the visible light detection of TiO 2 .

Electron shakeoff following the β+ decay of +19Ne and +35Ar trapped ions

NASA Astrophysics Data System (ADS)

Fabian, X.; Fléchard, X.; Pons, B.; Liénard, E.; Ban, G.; Breitenfeldt, M.; Couratin, C.; Delahaye, P.; Durand, D.; Finlay, P.; Guillon, B.; Lemière, Y.; Mauger, F.; Méry, A.; Naviliat-Cuncic, O.; Porobic, T.; Quéméner, G.; Severijns, N.; Thomas, J.-C.

2018-02-01

The electron shakeoff of 19F and 35Cl atoms resulting from the β+ decay of +19Ne and +35Ar ions has been investigated using a Paul trap coupled to a time of flight recoil-ion spectrometer. The charge-state distributions of the recoiling daughter nuclei were compared to theoretical calculations based on the sudden approximation and accounting for subsequent Auger processes. The excellent agreement obtained for 35Cl is not reproduced in 19F. The shortcoming is attributed to the inaccuracy of the independent particle model employed to calculate the primary shakeoff probabilities in systems with rather low atomic numbers. This calls for more elaborate calculations, including explicitly the electron-electron correlations.

Tribological characteristics of nitrogen (N+) implanted iron

NASA Technical Reports Server (NTRS)

Jones, W. R.; Ferrante, J.

1982-01-01

The effect of implantation of nitrogen ions (1.5 MeV) on the friction and wear characteristics of pure ion sliding against M-50 steel (unimplanted) was studied in a pin-on-disk sliding friction apparatus. Test conditions included room temperature (25 C), a dry air atmosphere, a load of 1/2 kg (4.9 N), sliding velocities of 0.043 to 0.078 m/sec (15 to 25 rpm), a pure hydrocarbon lubricant (n-hexadecane), or a U.S.P. mineral oil and nitrogen ion implantation doses of 5x10 to the 15th power and 5x10 to the 17th power ions/sq cm. No differences in wear rates were observed in the low dose experiments. In the high dose experiments, small reductions in initial (40 percent) and steady state (20 percent) wear rates were observed for nitrogen implanted iron riders as compared with unimplanted controls. No differences in average friction coefficients were noted for either dose. Auger electron spectroscopy combined with argon ion bombardment revealed a subsurface Gaussian nitrogen distribution with a maximum concentration of 6 atomic percent at a depth of 0.8 microns. Similar analysis within the wear scar of an implanted rider after 20 microns of wear yielded only background nitrogen concentration. No inward migration of nitrogen ions was observed.

A study of intrinsic statistical variation for low-energy nuclear recoils in liquid xenon detector for dark matter searches

NASA Astrophysics Data System (ADS)

Wang, Lu; Wei, Wenzhao; Mei, Dongming; Cubed Collaboration

2015-10-01

Noble liquid xenon experiments, such as XENON100, LUX, XENON 1-Ton, and LZ are large dark matter experiments directly searches for weakly interacting massive particles (WIMPs). One of the most important features is to discriminate nuclear recoils from electronic recoils. Detector response is generally calibrated with different radioactive sources including 83mKr, tritiated methane, 241AmBe, 252Cf, and DD-neutrons. The electronic recoil and nuclear recoil bands have been determined by these calibrations. However, the width of nuclear recoil band needs to be fully understood. We derive a theoretical model to understand the correlation of the width of nuclear recoil band and intrinsic statistical variation. In addition, we conduct experiments to validate the theoretical model. In this paper, we present the study of intrinsic statistical variation contributing to the width of nuclear recoil band. DE-FG02-10ER46709 and the state of South Dakota.

Changes in the structure and wear resistance of the surface layer of copper under treatment by nitrogen ion beams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sergeev, Victor P., E-mail: vserg@mail.tomsknet.ru, E-mail: kmp1980@mail.ru; Kalashnikov, Mark P., E-mail: vserg@mail.tomsknet.ru, E-mail: kmp1980@mail.ru; Rybalko, Evgeniya V., E-mail: evgeniaribka@yandex.com, E-mail: alfred-1972@mail.ru, E-mail: tehnovak@ispms.tsc.ru, E-mail: zhastas@mail.ru

2014-11-14

The structural-phase state of the treated sample surface was investigated by TEM. It was shown by the TEM and VIMS method that the improvement of tribological properties of the copper samples can be associated with an increase of relaxation ability due to a significant increase of the nitrogen concentration in it, which is accompanied by the refinement of fcc-Cu main phase grain structure and the formation of nanopores or gas bubbles in the ion-modified surface layer. A high-dose implantation of nitrogen ions and copper samples increases the wear resistance in 1.5-4.5 times together with a counterbody from the same materialmore » in the argon environment. The microhardness of the copper samples also increases.« less

Black Hole Mergers and Recoils in Low-Mass Galaxies

NASA Astrophysics Data System (ADS)

Blecha, Laura; Kelley, Luke; Koss, Michael; Satyapal, Shobita

2018-01-01

Mergers between massive black holes (BHs) in the intermediate-mass range are one of the most promising sources of gravitational waves (GWs) detectable with LISA. These highly energetic GW events could be observed out to very high redshift, in the epoch where massive BH seeds are thought to form. Despite recent progress, however, much is still not known about the low-mass BH population even in the local Universe. The rates of BH binary formation, inspiral, and merger are also highly uncertain across the BH mass scale. To address these pressing issues in advance of LISA, cosmological hydrodynamics simulations and semi-analytic modeling are being used to model the formation and evolution of BH binaries, and the GW signals they produce. Efforts are also underway to understand the electromagnetic (EM) signatures of the BH binary population. These have proven largely elusive thus far, but an increasing population of BH pairs has been found, and advances in the coming years will provide important comparisons for models of GW sources. Moreover, asymmetry in the GW emission from BH mergers imparts a recoil kick to the merged BH, which in extreme cases can eject the BH from its host galaxy. This creates additional uncertainty in the BH merger rate, but the remnant recoiling BH could be observed as an offset quasar. Identifications of such objects would provide another EM signature of BH mergers that would help pave the way for LISA. We will review model predictions of the BH inspiral and merger rate across the mass scale. We will also describe how the EM signatures of active, merging BHs can be used to constrain theoretical merger rates. Finally, we will discuss the predicted observability of recoiling BHs and ongoing efforts to identify and confirm candidate recoils.

Polarization effects in recoil-induced resonances

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lazebnyi, D. B., E-mail: becks.ddf@gmail.com; Brazhnikov, D. V.; Taichenachev, A. V.

2017-01-15

The effect of the field polarization on the amplitude of recoil-induced resonances (RIRs) is considered for laser-cooled free atoms and for atoms in a working magneto-optical trap (MOT). For all closed dipole transitions, explicit analytical expressions are obtained for the polarization dependence of the resonance amplitudes within a perturbation theory. Optimal polarization conditions are found for the observation of resonances.

Proton recoil scintillator neutron rem meter

DOEpatents

Olsher, Richard H.; Seagraves, David T.

2003-01-01

A neutron rem meter utilizing proton recoil and thermal neutron scintillators to provide neutron detection and dose measurement. In using both fast scintillators and a thermal neutron scintillator the meter provides a wide range of sensitivity, uniform directional response, and uniform dose response. The scintillators output light to a photomultiplier tube that produces an electrical signal to an external neutron counter.

Effect of water on solid electrolyte interphase formation in Li-ion batteries

NASA Astrophysics Data System (ADS)

Saito, M.; Fujita, M.; Aoki, Y.; Yoshikawa, M.; Yasuda, K.; Ishigami, R.; Nakata, Y.

2016-03-01

Time-of-flight-elastic recoil detection analysis (TOF-ERDA) with 20 MeV Cu ions has been applied to measure the depth profiles of solid electrolyte interphase (SEI) layers on the negative electrode of lithium ion batteries (LIB). In order to obtain quantitative depth profiles, the detector efficiency was first assessed, and the test highlighted a strong mass and energy dependence of the recoiled particles, especially H and He. Subsequently, we prepared LIB cells with different water contents in the electrolyte, and subjected them to different charge-discharge cycle tests. TOF-ERDA, X-ray photoelectron spectrometry (XPS), gas chromatography (GC), ion chromatography (IC), and 1H nuclear magnetic resonance (1H NMR) were applied to characterize the SEI region of the negative electrode. The results showed that the SEI layer is formed after 300 cycle tests, and a 500 ppm water concentration in the electrolyte does not appear to cause significant differences in the elemental and organic content of the SEI.

Mechanical properties of nitrogen-rich surface layers on SS304 treated by plasma immersion ion implantation

NASA Astrophysics Data System (ADS)

Fernandes, B. B.; Mändl, S.; Oliveira, R. M.; Ueda, M.

2014-08-01

The formation of hard and wear resistant surface regions for austenitic stainless steel through different nitriding and nitrogen implantation processes at intermediate temperatures is an established technology. As the inserted nitrogen remains in solid solution, an expanded austenite phase is formed, accounting for these surface improvements. However, experiments on long-term behavior and exact wear processes within the expanded austenite layer are still missing. Here, the modified layers were produced using plasma immersion ion implantation with nitrogen gas and had a thickness of up to 4 μm, depending on the processing temperature. Thicker layers or those with higher surface nitrogen contents presented better wear resistance, according to detailed microscopic investigation on abrasion, plastic deformation, cracking and redeposition of material inside the wear tracks. At the same time, cyclic fatigue testing employing a nanoindenter equipped with a diamond ball was carried out at different absolute loads and relative unloadings. As the stress distribution between the modified layer and the substrate changes with increasing load, additional simulations were performed for obtaining these complex stress distributions. While high nitrogen concentration and/or thicker layers improve the wear resistance and hardness, these modifications simultaneously reduce the surface fatigue resistance.

Nitrogen doped carbon nanodots as fluorescent probes for selective detection and quantification of Ferric(III) ions

NASA Astrophysics Data System (ADS)

Chin, Suk-Fun; Tan, Shao-Chien; Pang, Suh-Cem; Ng, Sing-Muk

2017-11-01

Nitrogen (N) doped carbon dots (N-CDs) that showed blue fluorescence with quantum yield (QY) of 12.25% were synthesized by one step microwave irradiation of lysine in ortho-phosphoric acid at 1000 W for 5 min. The as-synthesized N-CDs were successfully explored as fluorescent probes for selective detection of ferric (Fe3+) ions in aqueous condition with a linear range from 0.2 to 5.0 mM and a detection limit of 0.074 mM ± 0.081 (S/N = 3). The N-CDs exhibited high selectivity towards the detection of Fe3+ ions even in the presence of interfering ions. The N-CDs also demonstrated the potential of practical application for determining of Fe3+ ions concentration in real samples with high recovery rate and low relative standard deviation error.

Revealing compressed stops using high-momentum recoils

DOE PAGES

Macaluso, Sebastian; Park, Michael; Shih, David; ...

2016-03-22

In this study, searches for supersymmetric top quarks at the LHC have been making great progress in pushing sensitivity out to higher mass, but are famously plagued by gaps in coverage around lower-mass regions where the decay phase space is closing off. Within the common stop-NLSP/neutralino-LSP simplified model, the line in the mass plane where there is just enough phase space to produce an on-shell top quark remains almost completely unconstrained. Here, we show that is possible to define searches capable of probing a large patch of this difficult region, with S/B ~ 1 and significances often well beyond 5σ.more » The basic strategy is to leverage the large energy gain of LHC Run 2, leading to a sizable population of stop pair events recoiling against a hard jet. The recoil not only re-establishes a E T, but also leads to a distinctive anti-correlation between the E T and the recoil jet transverse vectors when the stops decay all-hadronically. Accounting for jet combinatorics, backgrounds, and imperfections in E T measurements, we estimate that Run 2 will already start to close the gap in exclusion sensitivity with the first few 10s of fb –1. By 300 fb –1, exclusion sensitivity may extend from stop masses of 550 GeV on the high side down to below 200 GeV on the low side, approaching the “stealth” point at m t¯ = m t and potentially overlapping with limits from tt¯ cross section and spin correlation measurements.« less

Nitrogen-atom endohedral fullerene synthesis with high efficiency by controlling plasma-ion irradiation energy and C60 internal energy

NASA Astrophysics Data System (ADS)

Cho, Soon Cheon; Kaneko, Toshiro; Ishida, Hiroyasu; Hatakeyama, Rikizo

2015-03-01

The nitrogen-atom endohedral fullerene (N@C60) has been synthesized by controlling the plasma ion irradiation energy (Ei) and fullerene (C60) behavior in the sublimation phase. We examined the relationship between the synthesis purity of N@C60 [molar concentration ratio of N@C60 to pristine fullerene (C60)] and Ei, which was controlled by changing the substrate bias voltages (Vsub) and gas pressure (PN2) during the plasma irradiation process. High-density nitrogen-molecular ions (N2+) with a suitable Ei near 80 eV are confirmed to be the optimum condition of the nitrogen plasma for the synthesis of high-purity N@C60. In addition, high sublimation of C60 contributes to a higher yield due to the high internal energy of C60 and the related cage defects that are present under these conditions. As a result, a purity of 0.83% is realized for the first time, which is almost two orders of magnitude higher than that using other methods.

Recoil distance lifetime measurements in 122,124Xe

NASA Astrophysics Data System (ADS)

Govil, I. M.; Kumar, A.; Iyer, H.; Li, H.; Garg, U.; Ghugre, S. S.; Johnson, T.; Kaczarowski, R.; Kharraja, B.; Naguleswaran, S.; Walpe, J. C.

1998-02-01

Lifetimes of the lower-excited states in 122,124Xe are measured using the recoil-distance Doppler-shift technique. The reactions 110Pd(16O,4n)122Xe and 110Pd(18O,4n)124Xe at a beam energy of 66 MeV were used for this experiment. The lifetimes of the 2+, 4+, 6+, and 8+ states of the ground state band were extracted using the computer code LIFETIME including the corrections due to the side feeding and the nuclear deorientation effects. The lifetime of the 2+ state in 122Xe agrees with the recoil distance method (RDM) measurements but for the 124Xe it does not agree with the RDM measurements but agrees with the Coulomb-excitation experiment. The measured B(E2) values for both the nuclei are compared with the standard algebraic and the multishell models.

Nitrogen-doped biomass-based ultra-thin carbon nanosheets with interconnected framework for High-Performance Lithium-Ion Batteries

NASA Astrophysics Data System (ADS)

Guo, Shasha; Chen, Yaxin; Shi, Liluo; Dong, Yue; Ma, Jing; Chen, Xiaohong; Song, Huaihe

2018-04-01

In this paper, a low-cost and environmental friendly synthesis strategy is proposed to fabricate nitrogen-doped biomass-based ultra-thin carbon nanosheets (N-CNS) with interconnected framework by using soybean milk as the carbon precursor and sodium chloride as the template. The interconnected porous nanosheet structure is beneficial for lithium ion transportation, and the defects introduced by pyridine nitrogen doping are favorable for lithium storage. When used as the anodes for lithium-ion batteries, the N-CNS electrode shows a high initial reversible specific capacity of 1334 mAh g-1 at 50 mA g-1, excellent rate performance (1212, 555 and 336 mAh g-1 at 0.05, 0.5 and 2 A g-1, respectively) and good cycling stability (355 mAh g-1 at 1 A g-1 after 1000 cycles). Furthermore, this study demonstrates the prospects of biomass and soybean milk, as the potential anode for the application of electrochemical energy storage devices.

Measurement of light and charge yield of low-energy electronic recoils in liquid xenon

NASA Astrophysics Data System (ADS)

Goetzke, L. W.; Aprile, E.; Anthony, M.; Plante, G.; Weber, M.

2017-11-01

The dependence of the light and charge yield of liquid xenon on the applied electric field and recoil energy is important for dark matter detectors using liquid xenon time projections chambers. Few measurements have been made of this field dependence at recoil energies less than 10 keV. In this paper, we present results of such measurements using a specialized detector. Recoil energies are determined via the Compton coincidence technique at four drift fields relevant for liquid xenon dark matter detectors: 0.19, 0.48, 1.02, and 2.32 kV /cm . Mean recoil energies down to 1 keV were measured with unprecedented precision. We find that the charge and light yield are anticorrelated above ˜3 keV and that the field dependence becomes negligible below ˜6 keV . However, below 3 keV, we find a charge yield significantly higher than expectation and a reconstructed energy deviating from linearity.

Modeling ionization and recombination from low energy nuclear recoils in liquid argon

DOE PAGES

Foxe, M.; Hagmann, C.; Jovanovic, I.; ...

2015-03-27

Coherent elastic neutrino-nucleus scattering (CENNS) is an as-yet undetected, flavor-independent neutrino interaction predicted by the Standard Model. Detection of CENNS could offer benefits for detection of supernova and solar neutrinos in astrophysics, or for detection of antineutrinos for nuclear reactor monitoring and nuclear nonproliferation. One challenge with detecting CENNS is the low energy deposition associated with a typical CENNS nuclear recoil. In addition, nuclear recoils result in lower ionization yields than those produced by electron recoils of the same energy. While a measurement of the nuclear recoil ionization yield in liquid argon in the keV energy range has been recentlymore » reported, a corresponding model for low-energy ionization yield in liquid argon does not exist. For this reason, a Monte Carlo simulation has been developed to predict the ionization yield at sub-10 keV energies. The model consists of two distinct components: (1) simulation of the atomic collision cascade with production of ionization, and (2) the thermalization and drift of ionization electrons in an applied electric field including local recombination. As an application of our results we report updated estimates of detectable ionization in liquid argon from CENNS at a nuclear reactor.« less

A Study of Nuclear Recoils in Liquid Argon Time Projection Chamber for the Direct Detection of WIMP Dark Matter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cao, Huajie

2014-11-01

Robust results of WIMP direct detection experiments depend on rm understandings of nuclear recoils in the detector media. This thesis documents the most comprehensive study to date on nuclear recoils in liquid argon - a strong candidate for the next generation multi-ton scale WIMP detectors. This study investigates both the energy partition from nuclear recoil energy to secondary modes (scintillation and ionization) and the pulse shape characteristics of scintillation from nuclear recoils.

A study of nuclear recoil backgrounds in dark matter detectors

NASA Astrophysics Data System (ADS)

Westerdale, Shawn S.

Despite the great success of the Standard Model of particle physics, a preponderance of astrophysical evidence suggests that it cannot explain most of the matter in the universe. This so-called dark matter has eluded direct detection, though many theoretical extensions to the Standard Model predict the existence of particles with a mass on the 1-1000 GeV scale that interact only via the weak nuclear force. Particles in this class are referred to as Weakly Interacting Massive Particles (WIMPs), and their high masses and low scattering cross sections make them viable dark matter candidates. The rarity of WIMP-nucleus interactions makes them challenging to detect: any background can mask the signal they produce. Background rejection is therefore a major problem in dark matter detection. Many experiments greatly reduce their backgrounds by employing techniques to reject electron recoils. However, nuclear recoil backgrounds, which produce signals similar to what we expect from WIMPs, remain problematic. There are two primary sources of such backgrounds: surface backgrounds and neutron recoils. Surface backgrounds result from radioactivity on the inner surfaces of the detector sending recoiling nuclei into the detector. These backgrounds can be removed with fiducial cuts, at some cost to the experiment's exposure. In this dissertation we briefly discuss a novel technique for rejecting these events based on signals they make in the wavelength shifter coating on the inner surfaces of some detectors. Neutron recoils result from neutrons scattering off of nuclei in the detector. These backgrounds may produce a signal identical to what we expect from WIMPs and are extensively discussed here. We additionally present a new tool for calculating (alpha, n) yields in various materials. We introduce the concept of a neutron veto system designed to shield against, measure, and provide an anti-coincidence veto signal for background neutrons. We discuss the research and development

A Study of Nuclear Recoil Backgrounds in Dark Matter Detectors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westerdale, Shawn S.

2016-01-01

Despite the great success of the Standard Model of particle physics, a preponderance of astrophysical evidence suggests that it cannot explain most of the matter in the universe. This so-called dark matter has eluded direct detection, though many theoretical extensions to the Standard Model predict the existence of particles with a mass on themore » $1-1000$ GeV scale that interact only via the weak nuclear force. Particles in this class are referred to as Weakly Interacting Massive Particles (WIMPs), and their high masses and low scattering cross sections make them viable dark matter candidates. The rarity of WIMP-nucleus interactions makes them challenging to detect: any background can mask the signal they produce. Background rejection is therefore a major problem in dark matter detection. Many experiments greatly reduce their backgrounds by employing techniques to reject electron recoils. However, nuclear recoil backgrounds, which produce signals similar to what we expect from WIMPs, remain problematic. There are two primary sources of such backgrounds: surface backgrounds and neutron recoils. Surface backgrounds result from radioactivity on the inner surfaces of the detector sending recoiling nuclei into the detector. These backgrounds can be removed with fiducial cuts, at some cost to the experiment's exposure. In this dissertation we briefly discuss a novel technique for rejecting these events based on signals they make in the wavelength shifter coating on the inner surfaces of some detectors. Neutron recoils result from neutrons scattering from nuclei in the detector. These backgrounds may produce a signal identical to what we expect from WIMPs and are extensively discussed here. We additionally present a new tool for calculating ($$\\alpha$$, n)yields in various materials. We introduce the concept of a neutron veto system designed to shield against, measure, and provide an anti-coincidence veto signal for background neutrons. We discuss the research and

Alpha Recoil Flux of Radon in Groundwater and its Experimental Measurement

NASA Astrophysics Data System (ADS)

Mehta, N.; Harvey, C. F.; Kocar, B. D.

2016-12-01

Groundwater Radon (Rn222) activity is primarily controlled by alpha recoil process (radioactive decay), however, evaluating the rate and extent of this process, and its impact on porewater radioactivity, remains uncertain. Numerous factors contribute to this uncertainty, including the spatial distribution of parent radionuclides (e.g. U238, Th232 , Ra226 and Ra228) within native materials, differences in nuclide recoil length in host matrix and the physical structure of the rock strata (pore size distribution and porosity). Here, we experimentally measure Radon activities within porewater contributed through alpha recoil, and analyze its variations as a function of pore structure and parent nuclide distribution within host matrices, including Marcellus shale rock and Serrie-Copper Pegmatite. The shale cores originate from the Marcellus formation in Mckean, Pennsylvania collected at depths ranging from 1000-7000 feet, and the U-Th-rich Pegmatite is obtained from South Platte District, Colorado. Columns are packed with granulated rock of varying surface area (30,000-60,000 cm2/g) and subjected to low salinity sodium chloride solution in a close loop configuration. The activity of Radon (Rn222) and radium (Ra226) in the saline fluid is measured over time to determine recoil supply rates. Mineralogical and trace element data for rock specimens are characterized using XRD and XRF, and detailed geochemical profiles are constructed through total dissolution and analysis using ICP-MS and ICP-OES. Naturally occurring Radium nuclides and its daughters are quantified using a low-energy Germanium detector. The parent nuclide (U238 and Th232) distribution in the host rock is studied using X-Ray Absorption Spectroscopy (XAS). Our study elucidates the contribution of alpha recoil on the appearance and distribution of Radon (Rn222) within porewater of representative rock matrices. Further, we illustrate the effects of chemical and physical heterogeneity on the rate of this process

Nuclear-Recoil Differential Cross Sections for the Two Photon Double Ionization of Helium

NASA Astrophysics Data System (ADS)

Abdel Naby, Shahin; Ciappina, M. F.; Lee, T. G.; Pindzola, M. S.; Colgan, J.

2013-05-01

In support of the reaction microscope measurements at the free-electron laser facility at Hamburg (FLASH), we use the time-dependent close-coupling method (TDCC) to calculate fully differential nuclear-recoil cross sections for the two-photon double ionization of He at photon energy of 44 eV. The total cross section for the double ionization is in good agreement with previous calculations. The nuclear-recoil distribution is in good agreement with the experimental measurements. In contrast to the single-photon double ionization, maximum nuclear recoil triple differential cross section is obtained at small nuclear momenta. This work was supported in part by grants from NSF and US DoE. Computational work was carried out at NERSC in Oakland, California and the National Institute for Computational Sciences in Knoxville, Tennessee.

Hydrogen adsorption site on the Ni?110?-p(1 × 2)-H surface from time-of-flight scattering and recoiling spectrometry (TOF-SARS)

NASA Astrophysics Data System (ADS)

Bu, H.; Roux, C. D.; Rabalais, J. W.

The adsorption site of hydrogen on the Ni{110}-p(1 × 2)-H surface resulting from saturation exposure to H 2 at ˜ 310-350 K has been investigated by time-of-flight scattering and recoiling spectrometry (TOF-SARS). The recoiled neutral plus ion hydrogen atom flux resulting from 2-5 keV Ar + or Ne + pulsed ion beams incident on the surface was monitored as a function of crystal azimuthal angle and beam incidence angle. From classical trajectory calculations and shadowing and blocking analyses, it is concluded that hydrogen atoms are localized at the pseudo-three-fold sites on the (1 × 2) missing-row (MR) reconstructed Ni{110} surface; the (1 × 2) MR reconstruction is induced by hydrogen adsorption shown elsewhere [Surf. Sci. 259 (1991) 253]. Only the pseudo-three-fold site is consistent with all of the experimental data. The coordinates of the hydrogen adsorption site with respect to the nickel lattice were determined. The lateral distance of hydrogen from the 1st-layer Ni <1 overline10> rows is 1.56 ± 0.12 Å and the vertical distance above the substrate is 0.21 ± 0.12 Å, providing NiH bond lengths of 2.0 Å to the two-layer Ni atoms and 1.5 Å to the 2nd-layer Ni atom.

Site-specific recoil-induced effects on inner-shell photoionization of linear triatomic molecules: N 1 s photoelectron spectra of N2 O

NASA Astrophysics Data System (ADS)

Krivosenko, Yu. S.; Pavlychev, A. A.

2016-11-01

We investigate hard X-ray ionization of linear triatomic molecules accenting recoil-induced effects on the dynamics of molecular frame. This dynamics is studied within the two-springs and harmonic approximations. The mode-channel relationship connecting the excitations of vibrational, rotational and translational degrees of freedom with the Σ → Σ and Σ → Π photoionization channels is applied to compute the N 1s-1 photoelectron spectra of molecular N2 O for various photon energies. The distinct ionized-site- and molecular-orientation-specific changes in the vibration structure of the 1 s photoelectron lines of terminal and central nitrogen atoms are revealed and discussed.

Recoil Considerations for Shoulder-Fired Weapons

DTIC Science & Technology

2012-05-01

Fired Weapons 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Bruce P. Burns 5d. PROJECT NUMBER 62616AH80...the textbook. This research was supported in part by an appointment to the Knowledge Preservation Program at ARL administered by the Oak Ridge...endurance to operate. Doubtless one had to learn how to master the recoil loads posed by the weapon, and virtually every successful German

Highly nitrogen-doped carbon capsules: scalable preparation and high-performance applications in fuel cells and lithium ion batteries.

PubMed

Hu, Chuangang; Xiao, Ying; Zhao, Yang; Chen, Nan; Zhang, Zhipan; Cao, Minhua; Qu, Liangti

2013-04-07

Highly nitrogen-doped carbon capsules (hN-CCs) have been successfully prepared by using inexpensive melamine and glyoxal as precursors via solvothermal reaction and carbonization. With a great promise for large scale production, the hN-CCs, having large surface area and high-level nitrogen content (N/C atomic ration of ca. 13%), possess superior crossover resistance, selective activity and catalytic stability towards oxygen reduction reaction for fuel cells in alkaline medium. As a new anode material in lithium-ion battery, hN-CCs also exhibit excellent cycle performance and high rate capacity with a reversible capacity of as high as 1046 mA h g(-1) at a current density of 50 mA g(-1) after 50 cycles. These features make the hN-CCs developed in this study promising as suitable substitutes for the expensive noble metal catalysts in the next generation alkaline fuel cells, and as advanced electrode materials in lithium-ion batteries.

RADIOLYSIS OF NITROGEN AND WATER-ICE MIXTURE BY FAST IONS: IMPLICATIONS FOR KUIPER BELT OBJECTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barros, A. L. F. de; Silveira, E. F da; Bergantini, A.

The participation of condensed nitrogen in the surface chemistry of some objects in the outer solar system, such as Pluto and Triton, is very important. The remote observation of this species using absorption spectroscopy is a difficult task because N{sub 2} is not IR active in the gas phase. Water is also among the most abundant molecules in the surface of these objects; chemical reactions between N{sub 2} and H{sub 2}O induced by cosmic rays are therefore expected. Although pure N{sub 2} ice is hardly identified by IR spectroscopy, the species produced through the processing of the surface ice bymore » cosmic rays may give relevant clues indicating how abundant the N{sub 2} is in the outside layers of the surface of trans-Neptunian objects (TNOs). The objective of this work is to investigate the formation of nitrogenated species induced by cosmic-ray analogs in an ice mixture containing nitrogen and water. Experiments were performed in the GANIL Laboratory by bombarding N{sub 2}:H{sub 2}O (10:1) ice at 15 K with 40 MeV {sup 58}Ni{sup 11+} ions. Evolution of precursor and daughter species was monitored by Fourier transform infrared spectrometry. The main produced species are the nitrogen oxides NO{sub k} (k = 1–3), N{sub 2}O{sub j} (j = 1–5), N{sub 3}, and O{sub 3}. Among them, the N{sub 2}O and N{sub 3} are the most abundant, representing ∼61% of the total column density of the daughter molecules at 10{sup 13} ions cm{sup −2} fluence; the current results indicate that the yield of daughter species from this mixture is low, and this may be one of the reasons why N{sub i}O{sub j} molecules are not usually observed in TNOs.« less

Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Franz, Robert; Polcik, Peter; Anders, André

The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr 2+ ions were dominating in Ar and N 2 and Cr + in O 2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ionsmore » that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O 2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.« less

Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

DOE PAGES

Franz, Robert; Polcik, Peter; Anders, André

2015-06-01

The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr 2+ ions were dominating in Ar and N 2 and Cr + in O 2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ionsmore » that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O 2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.« less

Generation of Raman lasers from nitrogen molecular ions driven by ultraintense laser fields

NASA Astrophysics Data System (ADS)

Yao, Jinping; Chu, Wei; Liu, Zhaoxiang; Xu, Bo; Chen, Jinming; Cheng, Ya

2018-03-01

Atmospheric lasing has aroused much interest in the past few years. The ‘air–laser’ opens promising potential for remote chemical sensing of trace gases with high sensitivity and specificity. At present, several approaches have been successfully implemented for generating highly coherent laser beams in atmospheric condition, including both amplified-spontaneous emission, and narrow-bandwidth stimulated emission in the forward direction in the presence of self-generated or externally injected seed pulses. Here, we report on generation of multiple-wavelength Raman lasers from nitrogen molecular ions ({{{N}}}2+), driven by intense mid-infrared laser fields. Intuitively, the approach appears problematic for the small nonlinear susceptibility of {{{N}}}2+ ions, whereas the efficiency of Raman laser can be significantly promoted in near-resonant condition. More surprisingly, a Raman laser consisting of a supercontinuum spanning from ∼310 to ∼392 nm has been observed resulting from a series near-resonant nonlinear processes including four-wave mixing, stimulated Raman scattering and cross phase modulation. To date, extreme nonlinear optics in molecular ions remains largely unexplored, which provides an alternative means for air–laser-based remote sensing applications.

Potential for chlorate interference in ion chromatographic determination of total nitrogen in natural waters following alkaline persulfate digestion.

PubMed

Halstead, J A; Edwards, J; Soracco, R J; Armstrong, R W

1999-10-01

Determination of total nitrogen in aqueous samples after thermal potassium peroxydisulfate (persulfate) digestion is a commonly used alternative to the tedious Kjeldahl procedure. When ion chromatography is used to quantify the nitrate formed during digestion, there is a potential for interference from a chlorate peak if the digested sample initially contained chloride in concentrations close to or greater than the concentration of nitrogen. It was determined that this interference can be avoided either by using chromatographic conditions which cleanly resolve the nitrate and chlorate peaks (e.g., the Dionex AG9-HG column) or by using digestion reagent concentrations chosen to maintain a high pH throughout the digestion. The second alternative is not a viable option for investigators using a single digestion for both total nitrogen (TN) and total phosphorus (TP) analysis.

Measuring the absolute deuterium-tritium neutron yield using the magnetic recoil spectrometer at OMEGA and the NIF.

PubMed

Casey, D T; Frenje, J A; Gatu Johnson, M; Séguin, F H; Li, C K; Petrasso, R D; Glebov, V Yu; Katz, J; Knauer, J P; Meyerhofer, D D; Sangster, T C; Bionta, R M; Bleuel, D L; Döppner, T; Glenzer, S; Hartouni, E; Hatchett, S P; Le Pape, S; Ma, T; MacKinnon, A; McKernan, M A; Moran, M; Moses, E; Park, H-S; Ralph, J; Remington, B A; Smalyuk, V; Yeamans, C B; Kline, J; Kyrala, G; Chandler, G A; Leeper, R J; Ruiz, C L; Cooper, G W; Nelson, A J; Fletcher, K; Kilkenny, J; Farrell, M; Jasion, D; Paguio, R

2012-10-01

A magnetic recoil spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF.

On the Mössbauer Effect and the Rigid Recoil Question

NASA Astrophysics Data System (ADS)

Davidson, Mark

2017-03-01

The rigid recoil of a crystal is the accepted mechanism for the Mössbauer effect. It's at odds with the special theory of relativity which does not allow perfectly rigid bodies. The standard model of particle physics which includes QED should not allow any signals to be transmitted faster than the speed of light. If perturbation theory can be used, then the X-ray emitted in a Mössbauer decay must come from a single nuclear decay vertex at which the 4-momentum is exactly conserved in a Feynman diagram. Then the 4-momentum of the final state Mössbauer nucleus must be slightly off the mass shell. This off-shell behavior would be followed by subsequent diffusion of momentum throughout the crystal to bring the nucleus back onto the mass shell and the crystal to a final relaxed state in which it moves rigidly with the appropriate recoil velocity. This mechanism explains the Mössbauer effect at the microscopic level and reconciles it with relativity. Because off-mass-shell quantum mechanics is required, the on-mass-shell theories developed originally for the Mössbauer effect are inadequate. Another possibility is that that the recoil response involves a non-perturbative effect in the standard model which could allow for a non-local instantaneous momentum transfer between the crystal and the decay (or absorption), as proposed for example by Preparata and others in super-radiance theory. The recoil time of the crystal is probably not instantaneous, and if it could be measured, one could distinguish between various theories. An experiment is proposed in this paper to measure this time. The idea is to measure the total energy radiated due to bremsstrahlung from a charged Mössbauer crystal which has experienced a recoil. Using Larmor's formula, along with corrections to it, allows one to design an experiment. The favored idea is to use many small nano-spheres of Mössbauer-active metals, whose outer surfaces are charged. The energy radiated then varies as the charge

Controllability analysis and testing of a novel magnetorheological absorber for field gun recoil mitigation

NASA Astrophysics Data System (ADS)

Ouyang, Qing; Zheng, Jiajia; Li, Zhaochun; Hu, Ming; Wang, Jiong

2016-11-01

This paper aims to analyze the effects of combined working coils of magnetorheological (MR) absorber on the shock mitigation performance and verify the controllability of MR absorber as applied in the recoil system of a field gun. A physical scale model of the field gun is established and a long-stroke MR recoil absorber with four-stage parallel electromagnetic coils is designed to apply separate current to each stage and generate variable magnetic field distribution in the annular flow channel. Based on dynamic analysis and firing stability conditions of the field gun, ideal recoil force-stroke profiles of MR absorber at different limiting firing angles are obtained. The experimental studies are carried out on an impact test rig under different combinations of current loading: conventional unified control mode, separate control mode and timing control mode. The fullness degree index (FDI) is defined as the quantitative evaluation criterion of the controllability of MR absorber during the whole recoil motion. The results show that the force-stroke profile of the novel MR absorber can approach the ideal curve within 25 degrees of the limiting firing angle through judicious exploitation of the adjustable rheological properties of MR fluid.

Comparison of acute elastic recoil between the SAPIEN-XT and SAPIEN valves in transfemoral-transcatheter aortic valve replacement.

PubMed

Garg, Aatish; Parashar, Akhil; Agarwal, Shikhar; Aksoy, Olcay; Hammadah, Muhammad; Poddar, Kanhaiya Lal; Puri, Rishi; Svensson, Lars G; Krishnaswamy, Amar; Tuzcu, E Murat; Kapadia, Samir R

2015-02-15

The SAPIEN-XT is a newer generation balloon-expandable valve created of cobalt chromium frame, as opposed to the stainless steel frame used in the older generation SAPIEN valve. We sought to determine if there was difference in acute recoil between the two valves. All patients who underwent transfemoral-transcatheter aortic valve replacement using the SAPIEN-XT valve at the Cleveland Clinic were included. Recoil was measured using biplane cine-angiographic image analysis of valve deployment. Acute recoil was defined as [(valve diameter at maximal balloon inflation) - (valve diameter after deflation)]/valve diameter at maximal balloon inflation (reported as percentage). Patients undergoing SAPIEN valve implantation were used as the comparison group. Among the 23 mm valves, the mean (standard deviation-SD) acute recoil was 2.77% (1.14) for the SAPIEN valve as compared to 3.75% (1.52) for the SAPIEN XT valve (P = 0.04). Among the 26 mm valves, the mean (SD) acute recoil was 2.85% (1.4) for the SAPIEN valve as compared to 4.32% (1.63) for the SAPIEN XT valve (P = 0.01). Multivariable linear regression analysis demonstrated significantly greater adjusted recoil in the SAPIEN XT valves as compared to the SAPIEN valves by 1.43% [(95% CI: 0.69-2.17), P < 0.001]. However, the residual peak gradient was less for SAPIEN XT compared to SAPIEN valves [18.86 mm Hg versus 23.53 mm Hg (P = 0.01)]. Additionally, no difference in paravalvular leak was noted between the two valve types (P = 0.78). The SAPIEN XT valves had significantly greater acute recoil after deployment compared to the SAPIEN valves. Implications of this difference in acute recoil on valve performance need to be investigated in future studies. © 2014 Wiley Periodicals, Inc.

Hybrid Organic/Inorganic Materials Depth Profiling Using Low Energy Cesium Ions

NASA Astrophysics Data System (ADS)

Noël, Céline; Houssiau, Laurent

2016-05-01

The structures developed in organic electronics, such as organic light emitting diodes (OLEDs) or organic photovoltaics (OPVs) devices always involve hybrid interfaces, joining metal or oxide layers with organic layers. No satisfactory method to probe these hybrid interfaces physical chemistry currently exists. One promising way to analyze such interfaces is to use in situ ion beam etching, but this requires ion beams able to depth profile both inorganic and organic layers. Mono- or diatomic ion beams commonly used to depth profile inorganic materials usually perform badly on organics, while cluster ion beams perform excellently on organics but yield poor results when organics and inorganics are mixed. Conversely, low energy Cs+ beams (<500 eV) allow organic and inorganic materials depth profiling with comparable erosion rates. This paper shows a successful depth profiling of a model hybrid system made of metallic (Au, Cr) and organic (tyrosine) layers, sputtered with 500 eV Cs+ ions. Tyrosine layers capped with metallic overlayers are depth profiled easily, with high intensities for the characteristic molecular ions and other specific fragments. Metallic Au or Cr atoms are recoiled into the organic layer where they cause some damage near the hybrid interface as well as changes in the erosion rate. However, these recoil implanted metallic atoms do not appear to severely degrade the depth profile overall quality. This first successful hybrid depth profiling report opens new possibilities for the study of OLEDs, organic solar cells, or other hybrid devices.

Recoil polarization and beam-recoil double polarization measurement of eta electroproduction on the proton in the region of the S11(1535) resonance.

PubMed

Merkel, H; Achenbach, P; Ayerbe Gayoso, C; Bernauer, J C; Böhm, R; Bosnar, D; Cheymol, B; Distler, M O; Doria, L; Fonvieille, H; Friedrich, J; Janssens, P; Makek, M; Müller, U; Nungesser, L; Pochodzalla, J; Potokar, M; Sánchez Majos, S; Schlimme, B S; Sirca, S; Tiator, L; Walcher, Th; Weinriefer, M

2007-09-28

The beam-recoil double polarization P(x')(h) and P(z')(h) and the recoil polarization P(y') were measured for the first time for the p(e,e'p)eta reaction at a four-momentum transfer of Q(2) = 0.1 GeV(2)/c(2) and a center of mass production angle of theta = 120 degrees at the Mainz Microtron MAMI-C. With a center of mass energy range of 1500 MeV

Nitrogen-atom endohedral fullerene synthesis with high efficiency by controlling plasma-ion irradiation energy and C{sub 60} internal energy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cho, Soon Cheon; Kaneko, Toshiro, E-mail: kaneko@ecei.tohoku.ac.jp; Ishida, Hiroyasu

2015-03-28

The nitrogen-atom endohedral fullerene (N@C{sub 60}) has been synthesized by controlling the plasma ion irradiation energy (E{sub i}) and fullerene (C{sub 60}) behavior in the sublimation phase. We examined the relationship between the synthesis purity of N@C{sub 60} [molar concentration ratio of N@C{sub 60} to pristine fullerene (C{sub 60})] and E{sub i}, which was controlled by changing the substrate bias voltages (V{sub sub}) and gas pressure (P{sub N2}) during the plasma irradiation process. High-density nitrogen-molecular ions (N{sub 2}{sup +}) with a suitable E{sub i} near 80 eV are confirmed to be the optimum condition of the nitrogen plasma for themore » synthesis of high-purity N@C{sub 60}. In addition, high sublimation of C{sub 60} contributes to a higher yield due to the high internal energy of C{sub 60} and the related cage defects that are present under these conditions. As a result, a purity of 0.83% is realized for the first time, which is almost two orders of magnitude higher than that using other methods.« less

A Micromegas-based Directional Dark Matter Detector for Use with Negative Ion Gases

NASA Astrophysics Data System (ADS)

Nicoloff, Catherine; Battat, James

2017-01-01

Directional dark matter detectors seek to measure the direction of WIMP-induced nuclear recoils. The angular distribution of these recoils provides a unique signature that is not mimicked by any known background population. Low-pressure gas time projection chambers (TPCs) have a long and successful history in directional dark matter searches. The benefit of the low-pressure gas target is that nuclear recoils from dark matter extend long enough to be reliably reconstructed. For the last decade, the DRIFT collaboration has employed a MWPC-based negative-ion TPC for directional dark matter detection. DRIFT recently published the leading limit from a directional detector on the spin-dependent WIMP-proton interaction (1.1 pb at a WIMP mass of 100 GeV/c2) . Although the effective spatial granularity along the drift direction is 60 um, the MWPC wire spacing of 2 mm limits DRIFT's track reconstruction. DRIFT is now exploring TPC readouts that offer higher spatial resolution. Here, we report on one such effort that uses a Micromegas for gas amplification with orthogonal strips for charge signal readout. The detector can be used with both electron drift and negative ion gases. We will describe the detector design and present preliminary commissioning data taken in a surface laboratory. Research Corporation, NSF, and MA Space Grant.

Accurate measurements of E2 lifetimes using the coincidence recoil-distance method

NASA Astrophysics Data System (ADS)

Bhalla, R. K.; Poletti, A. R.

1984-05-01

Mean lives of four E2 transitions in the (2s, 1d) shell have been measured using the recoil-distance method (RDM), γ-rays de-exciting the level of interest were detected in coincidence with particles detected in an annular detector at a backward angle thereby reducing the background and producing a beam of recoiling nuclei of well-defined energy and recoil direction. Lifetimes measured were: 22Ne, 1.275 MeV level (2 + → 0 +), 5.16±0.13 ps; 26Mg, 3.588 MeV level (0 + → 2 +), 9.29±0.23 ps; 30Si, 3.788 MeV level (0 +→ 2 +), 12.00±0.70 ps; 38Ar, 3.377 MeV level (0 + → 2 +), 34.5±1.5 ps. The present measurements are compared to those of previous investigators. For the 22Ne level, averaged results from four different measurement techniques are compared and found to be in good agreement. The experimental results are compared to shell-model calculations.

Anatomy of the binary black hole recoil: A multipolar analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schnittman, Jeremy D.; Buonanno, Alessandra; Meter, James R. van

2008-02-15

We present a multipolar analysis of the gravitational recoil computed in recent numerical simulations of binary black hole coalescence, for both unequal masses and nonzero, nonprecessing spins. We show that multipole moments up to and including l=4 are sufficient to accurately reproduce the final recoil velocity (within {approx_equal}2%) and that only a few dominant modes contribute significantly to it (within {approx_equal}5%). We describe how the relative amplitudes, and more importantly, the relative phases, of these few modes control the way in which the recoil builds up throughout the inspiral, merger, and ringdown phases. We also find that the numerical resultsmore » can be reproduced by an 'effective Newtonian' formula for the multipole moments obtained by replacing the radial separation in the Newtonian formulas with an effective radius computed from the numerical data. Beyond the merger, the numerical results are reproduced by a superposition of three Kerr quasinormal modes. Analytic formulas, obtained by expressing the multipole moments in terms of the fundamental quasinormal modes of a Kerr black hole, are able to explain the onset and amount of 'antikick' for each of the simulations. Lastly, we apply this multipolar analysis to help explain the remarkable difference between the amplitudes of planar and nonplanar kicks for equal-mass spinning black holes.« less

Anatomy of the Binary Black Hole Recoil: A Multipolar Analysis

NASA Technical Reports Server (NTRS)

Schnittman, Jeremy; Buonanno, Alessandra; vanMeter, James R.; Baker, John G.; Boggs, William D.; Centrella, Joan; Kelly, Bernard J.; McWilliams, Sean T.

2007-01-01

We present a multipolar analysis of the recoil velocity computed in recent numerical simulations of binary black hole coalescence, for both unequal masses and non-zero, non-precessing spins. We show that multipole moments up to and including 1 = 4 are sufficient to accurately reproduce the final recoil velocity (= 98%) and that only a few dominant modes contribute significantly to it (2 95%). We describe how the relative amplitude, and more importantly, the relative phase, of these few modes control the way in which the recoil builds up throughout the inspiral, merger, and ring-down phases. We also find that the numerical results can be reproduced, to a high level of accuracy, by an effective Newtonian formula for the multipole moments obtained by replacing in the Newtonian formula the radial separation with an effective radius computed from the numerical data. Beyond the merger, the numerical results are reproduced by a superposition of three Kerr quasi-normal modes. Analytic formulae, obtained by expressing the multipole moments in terms of the fundamental QNMs of a Kerr BH, are able to explain the onset and amount of '.anti-kick" for each of the simulations. Lastly, we apply this multipolar analysis to understand the remarkable difference between the amplitudes of planar and non-planar kicks for equal-mass spinning black holes.

Improvements of anti-corrosion and mechanical properties of NiTi orthopedic materials by acetylene, nitrogen and oxygen plasma immersion ion implantation

NASA Astrophysics Data System (ADS)

Poon, Ray W. Y.; Ho, Joan P. Y.; Liu, Xuanyong; Chung, C. Y.; Chu, Paul K.; Yeung, Kelvin W. K.; Lu, William W.; Cheung, Kenneth M. C.

2005-08-01

Nickel-titanium shape memory alloys (NiTi) are useful materials in orthopedics and orthodontics due to their unique super-elasticity and shape memory effects. However, the problem associated with the release of harmful Ni ions to human tissues and fluids has been raising safety concern. Hence, it is necessary to produce a surface barrier to impede the out-diffusion of Ni ions from the materials. We have conducted acetylene, nitrogen and oxygen plasma immersion ion implantation (PIII) into NiTi alloys in an attempt to improve the surface properties. All the implanted and annealed samples surfaces exhibit outstanding corrosion and Ni out-diffusion resistance. Besides, the implanted layers are mechanically stronger than the substrate underneath. XPS analyses disclose that the layer formed by C2H2 PIII is composed of mainly TiCx with increasing Ti to C concentration ratios towards the bulk. The nitrogen PIII layer is observed to be TiN, whereas the oxygen PIII layer is composed of oxides of Ti4+, Ti3+ and Ti2+.

Ion-irradiation-induced densification of zirconia sol-gel thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levine, T.E.; Giannelis, E.P.; Kodali, P.

1994-02-01

We have investigated the densification behavior of sol-gel zirconia films resulting from ion irradiation. Three sets of films were implanted with neon, krypton, or xenon. The ion energies were chosen to yield approximately constant energy loss through the film and the doses were chosen to yield similar nuclear energy deposition. Ion irradiation of the sol-gel films resulted in carbon and hydrogen loss as indicated by Rutherford backscattering spectrometry and forward recoil energy spectroscopy. Although the densification was hypothesized to result from target atom displacement, the observed densification exhibits a stronger dependence on electronic energy deposition.

Conformational ordering of biomolecules in the gas phase: nitrogen collision cross sections measured on a prototype high resolution drift tube ion mobility-mass spectrometer.

PubMed

May, Jody C; Goodwin, Cody R; Lareau, Nichole M; Leaptrot, Katrina L; Morris, Caleb B; Kurulugama, Ruwan T; Mordehai, Alex; Klein, Christian; Barry, William; Darland, Ed; Overney, Gregor; Imatani, Kenneth; Stafford, George C; Fjeldsted, John C; McLean, John A

2014-02-18

Ion mobility-mass spectrometry measurements which describe the gas-phase scaling of molecular size and mass are of both fundamental and pragmatic utility. Fundamentally, such measurements expand our understanding of intrinsic intramolecular folding forces in the absence of solvent. Practically, reproducible transport properties, such as gas-phase collision cross-section (CCS), are analytically useful metrics for identification and characterization purposes. Here, we report 594 CCS values obtained in nitrogen drift gas on an electrostatic drift tube ion mobility-mass spectrometry (IM-MS) instrument. The instrument platform is a newly developed prototype incorporating a uniform-field drift tube bracketed by electrodynamic ion funnels and coupled to a high resolution quadrupole time-of-flight mass spectrometer. The CCS values reported here are of high experimental precision (±0.5% or better) and represent four chemically distinct classes of molecules (quaternary ammonium salts, lipids, peptides, and carbohydrates), which enables structural comparisons to be made between molecules of different chemical compositions for the rapid "omni-omic" characterization of complex biological samples. Comparisons made between helium and nitrogen-derived CCS measurements demonstrate that nitrogen CCS values are systematically larger than helium values; however, general separation trends between chemical classes are retained regardless of the drift gas. These results underscore that, for the highest CCS accuracy, care must be exercised when utilizing helium-derived CCS values to calibrate measurements obtained in nitrogen, as is the common practice in the field.

Conformational Ordering of Biomolecules in the Gas Phase: Nitrogen Collision Cross Sections Measured on a Prototype High Resolution Drift Tube Ion Mobility-Mass Spectrometer

PubMed Central

2014-01-01

Ion mobility-mass spectrometry measurements which describe the gas-phase scaling of molecular size and mass are of both fundamental and pragmatic utility. Fundamentally, such measurements expand our understanding of intrinsic intramolecular folding forces in the absence of solvent. Practically, reproducible transport properties, such as gas-phase collision cross-section (CCS), are analytically useful metrics for identification and characterization purposes. Here, we report 594 CCS values obtained in nitrogen drift gas on an electrostatic drift tube ion mobility-mass spectrometry (IM-MS) instrument. The instrument platform is a newly developed prototype incorporating a uniform-field drift tube bracketed by electrodynamic ion funnels and coupled to a high resolution quadrupole time-of-flight mass spectrometer. The CCS values reported here are of high experimental precision (±0.5% or better) and represent four chemically distinct classes of molecules (quaternary ammonium salts, lipids, peptides, and carbohydrates), which enables structural comparisons to be made between molecules of different chemical compositions for the rapid “omni-omic” characterization of complex biological samples. Comparisons made between helium and nitrogen-derived CCS measurements demonstrate that nitrogen CCS values are systematically larger than helium values; however, general separation trends between chemical classes are retained regardless of the drift gas. These results underscore that, for the highest CCS accuracy, care must be exercised when utilizing helium-derived CCS values to calibrate measurements obtained in nitrogen, as is the common practice in the field. PMID:24446877

Low energy recoil detection with a spherical proportional counter

NASA Astrophysics Data System (ADS)

Savvidis, I.; Katsioulas, I.; Eleftheriadis, C.; Giomataris, I.; Papaevangellou, T.

2018-01-01

We present results for the detection of low energy nuclear recoils in the keV energy region, from measurements performed with the Spherical Proportional Counter (SPC). An 241Am-9Be fast neutron source is used in order to obtain neutron-nucleus elastic scattering events inside the gaseous volume of the detector. The detector performance in the keV energy region was measured by observing the 5.9 keV line of a 55Fe X-ray source, with energy resolution of 10% (σ). The toolkit GEANT4 was used to simulate the irradiation of the detector by an 241Am-9Be source, while SRIM was used to calculate the Ionization Quenching Factor (IQF), the simulation results are compared with the measurements. The potential of the SPC in low energy recoil detection makes the detector a good candidate for a wide range of applications, including Supernova or reactor neutrino detection and Dark Matter (WIMP) searches (via coherent elastic scattering).

Biological effects of low energy nitrogen ion implantation on Jatropha curcas L. seed germination

NASA Astrophysics Data System (ADS)

Xu, Gang; Wang, Xiao-teng; Gan, Cai-ling; Fang, Yan-qiong; Zhang, Meng

2012-09-01

To explore the biological effects of nitrogen ion beam implantation on dry Jatropha curcas seed, a beam of N+ with energy of 25 keV was applied to treat the dry seed at six different doses. N+ beam implantation greatly decreased germination rate and seedling survival rate. The doses within the range of 12 × 1016 to 15 × 1016 ions cm-2 severely damaged the seeds: total antioxidant capacity (TAC), germination rate, seedling survival rate, reduced ascorbate acid (HAsA) and reduced glutathione (GSH) contents, and most of the tested antioxidases activity (i.e. catalase (CAT), ascorbate peroxidase (APX) and superoxide dismutase (SOD)) reached their lowest levels. At a dose of 18 × 1016 ion cm-2, biological repair took place: moderate increases were found in TAC, germination rate, seedling survival rate, HAsA and GSH contents, and some antioxidant enzyme activities (i.e. CAT, APX, SOD and GPX). The dose of 18 × 1016 ions cm-2 may be the optimum dose for use in dry J. curcas seed mutation breeding. CAT, HAsA and GSH contributed to the increase of TAC, but CAT was the most important. POD performed its important role as seed was severely damaged. The main role of the HAsA-GSH cycle appeared to be for regeneration of HAsA.

Incorporation of heterostructured Sn/SnO nanoparticles in crumpled nitrogen-doped graphene nanosheets for application as anodes in lithium-ion batteries.

PubMed

Du, Fei-Hu; Liu, Yu-Si; Long, Jie; Zhu, Qian-Cheng; Wang, Kai-Xue; Wei, Xiao; Chen, Jie-Sheng

2014-09-07

Sn/SnO nanoparticles are incorporated in crumpled nitrogen-doped graphene nanosheets by a simple melting diffusion method. The resulting composite exhibits large specific capacity, excellent cycling stability and high rate capability as an anode for lithium-ion batteries.

Determination of Ni Release in NiTi SMA with Surface Modification by Nitrogen Plasma Immersion Ion Implantation

NASA Astrophysics Data System (ADS)

de Camargo, Eliene Nogueira; Oliveira Lobo, Anderson; Silva, Maria Margareth Da; Ueda, Mario; Garcia, Edivaldo Egea; Pichon, Luc; Reuther, Helfried; Otubo, Jorge

2011-07-01

NiTi SMA is a promising material in the biomedical area due to its mechanical properties and biocompatibility. However, the nickel in the alloy may cause allergic and toxic reactions and thus limiting its applications. It was evaluated the influence of surface modification in NiTi SMA by nitrogen plasma immersion ion implantation (varying temperatures, and exposure time as follows: <250 °C/2 h, 290 °C/2 h, and 560 °C/1 h) in the amount of nickel released using immersion test in simulated body fluid. The depth of the nitrogen implanted layer increased as the implantation temperature increased resulting in the decrease of nickel release. The sample implanted in high implantation temperature presented 35% of nickel release reduction compared to reference sample.

High energy primary knock-on process in metal deuterium systems initiated by bombardment with noble gas ions

NASA Astrophysics Data System (ADS)

Gann, V. V.; Tolstolutskaya, G. D.

2008-08-01

An experimental study confirms the possibility of nuclear fusion reactions initiating in metal-deuterium targets by bombarding them with ions that are not the reagents of the fusion reaction, in particular, with noble gas ions. The yields of (d,d) and (d,t) reactions were measured as functions of energy (0.4-3.2 MeV) and mass of incident ions (He +, Ne +, Ar +, Kr + and Xe +). Irradiation by heavy ions produced a number of energetic deuterium atoms in the deuteride and deuterium + tritium metal targets. At ion energies of ˜0.1-1 MeV the d-d reaction yields are relatively high. A model of nuclear fusion reaction cross-sections in atomic collision cascades initiated by noble gas ion beam in metal-deuterium target is developed. The method for calculation tritium or deuterium recoil fluxes and the yield of d-d fusion reaction in subsequent collisions was proposed. It was shown that D(d,p)t and D(t,n) 4He reactions mainly occur in energy region of the recoiled D-atom from 10 keV to 250 keV. The calculated probabilities of d-d and d-t fusion reactions were found to be in a good agreement with the experimental data.

Constraints on the Nature of CID-42: Recoil Kick or Supermassive Black Hole Pair?

NASA Technical Reports Server (NTRS)

Blecha, Laura; Civano, Francesca; Elvis, Martin; Loeb, Abraham

2012-01-01

The galaxy CXOC J100043.1+020637, also known as CID-42, is a highly unusual object. An apparent galaxy merger remnant, it displays signatures of both an inspiraling, kiloparsecscale active galactic nucleus (AGN) pair and of a recoiling AGN with a kick velocity approximately greater than 1300 km s(exp -1). Among recoiling AGN candidates, CID-42 alone has both spatial offsets (in optical and X-ray bands) and spectroscopic offsets. In order to constrain the relative likelihood of both scenarios, we develop models using hydrodynamic galaxy merger simulations coupled with radiative transfer calculations. Our gas-rich, major merger models are generally well matched to the galactic morphology and to the inferred stellar mass and star formation rate. We show that a recoiling supermassive black hole (SMBH) in CID-42 should be observable as an AGN at the time of observation. However, in order for the recoiling AGN to produce narrow-line emission, it must be observed shortly after the kick while it still inhabits a dense gaseous region, implying a large total kick velocity (vk approximately greater than 2000 km s(exp -1)). For the dual AGN scenario, an unusually large broad-line offset is required, and the best match to the observed morphology requires a galaxy that is less luminous than CID-42. Further, the lack of X-ray emission from one of the two optical nuclei is not easily attributed to an intrinsically quiescent SMBH or to a Compton-thick galactic environment. While the current data do not allow either the recoiling or the dual AGN scenario for CID-42 to be excluded, our models highlight the most relevant parameters for distinguishing these possibilities with future observations. In particular, high-quality, spatially-resolved spectra that can pinpoint the origin of the broad and narrow line features will be critical for determining the nature of this unique source.

Atmospheric deposition of inorganic nitrogen in Spanish forests of Quercus ilex measured with ion-exchange resins and conventional collectors

Treesearch

Héctor García-Gomez; Sheila Izquieta-Rojano; Laura Aguillaume; Ignacio González-Fernández; Fernando Valiño; David Elustondo; Jesús M. Santamaría; Anna Àvila; Mark E. Fenn; Rocío Alonso

2016-01-01

Atmospheric nitrogen deposition is one of the main threats for biodiversity and ecosystem functioning. Measurement techniques like ion-exchange resin collectors (IECs), which are less expensive and time-consuming than conventional methods, are gaining relevance in the study of atmospheric deposition and are recommended to expand monitoring networks. In the present work...

Selective ionization of dissolved organic nitrogen by positive ion atmospheric pressure photoionization coupled with Fourier transform ion cyclotron resonance mass spectrometry.

PubMed

Podgorski, David C; McKenna, Amy M; Rodgers, Ryan P; Marshall, Alan G; Cooper, William T

2012-06-05

Dissolved organic nitrogen (DON) comprises a heterogeneous family of organic compounds that includes both well-known biomolecules such as urea or amino acids and more complex, less characterized compounds such as humic and fulvic acids. Typically, DON represents only a small fraction of the total dissolved organic carbon pool and therefore presents inherent problems for chemical analysis and characterization. Here, we demonstrate that DON may be selectively ionized by atmospheric pressure photionization (APPI) and characterized at the molecular level by Fourier transform ion cyclotron resonance mass spectrometry. Unlike electrospray ionization (ESI), APPI ionizes polar and nonpolar compounds, and ionization efficiency is not determined by polarity. APPI is tolerant to salts, due to the thermal treatment inherent to nebulization, and thus avoids salt-adduct formation that can complicate ESI mass spectra. Here, for dissolved organic matter from various aquatic environments, we selectively ionize DON species that are not efficiently ionized by other ionization techniques and demonstrate significant signal-to-noise increase for nitrogen species by use of APPI relative to ESI.

Single surface barrier detectors for neutron dosimetry and associated light-ion fluxes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Treado, P.A.; Allas, R.G.; Eman, B.

1981-04-01

In this paper the authors have attempted to perfect a simple, compact and inexpensive single surface barrier detection system to measure both the intensities and approximate spectral shape of continuous neutron and light ion fluxes. They have measured such fluxes for three known collimated and uncollimated neutron beams with two geometrical configurations and with at least two different thicknesses of CH/sub 2/ and CD/sub 2/ radiators. All neutron flux data were obtained with a Au shield in front of the detector; this was removed for LIF measurements. The known shapes of the impinging neutron beams were used to calculate themore » expected recoil-particle spectra and such predictions have been compared with the experimental data. Also, data have been obtained with telescopes, with carbon foil and thin detector-grade silicon foil radiators. These data allow the authors to estimate contributions to the higher-energy portion of the recoil-particle spectra from reactions due to the carbon in the CH/sub 2/ and CD/sub 2/ radiators and due to the silicon in the detector. Corrections for rim effects in the detector and multiple scattering in the radiator are calculable. The precipitous decrease in the number of observed events, expected at the maximum energy that can be deposited by a recoil particle from the radiator, was observed for each of the radiator/detector combinations studied. The data agree reasonably well with both the intensity and spectral shape predictions for recoil-particle energies above about 300 keV. The telescope data confirm the single-detector data and add significant information about the LIFs created by the collimation of the neutron beams. In fact, both the single-detector and telescope data indicate that (n,p) reactions in collimation and target-backing materials contribute significant proton components to the light-ion fluxes.« less

A high energy and power sodium-ion hybrid capacitor based on nitrogen-doped hollow carbon nanowires anode

NASA Astrophysics Data System (ADS)

Li, Dongdong; Ye, Chao; Chen, Xinzhi; Wang, Suqing; Wang, Haihui

2018-04-01

The sodium ion hybrid capacitor (SHC) has been attracting much attention. However, the SHC's power density is significantly confined to a low level due to the sluggish ion diffusion in the anode. Herein, we propose to use an electrode with a high double layer capacitance as the anode in the SHC instead of insertion anodes. To this aim, nitrogen doped hollow carbon nanowires (N-HCNWs) with a high specific surface area are prepared, and the high capacitive contribution during the sodium ion storage process is confirmed by a series of electrochemical measurements. A new SHC consisting of a N-HCNW anode and a commercial active carbon (AC) cathode is fabricated for the first time. Due to the hybrid charge storage mechanism combining ion insertion and capacitive process, the as-fabricated SHC strikes a balance between the energy density and power density, a energy density of 108 Wh kg-1 and a power density of 9 kW kg-1 can be achieved, which overwhelms the electrochemical performances of most reported AC-based SHCs.

High-resolution measurements of the DT neutron spectrum using new CD foils in the Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gatu Johnson, M., E-mail: gatu@psfc.mit.edu; Frenje, J. A.; Li, C. K.

2016-11-15

The Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility measures the DT neutron spectrum from cryogenically layered inertial confinement fusion implosions. Yield, areal density, apparent ion temperature, and directional fluid flow are inferred from the MRS data. This paper describes recent advances in MRS measurements of the primary peak using new, thinner, reduced-area deuterated plastic (CD) conversion foils. The new foils allow operation of MRS at yields 2 orders of magnitude higher than previously possible, at a resolution down to ∼200 keV FWHM.

High-resolution measurements of the DT neutron spectrum using new CD foils in the Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility

DOE PAGES

Gatu Johnson, M.; Frenje, J. A.; Bionta, R. M.; ...

2016-08-09

The Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility measures the DT neutron spectrum from cryogenically layered inertial confinement fusion implosions. Yield, areal density, apparent ion temperature, and directional fluid flow are inferred from the MRS data. Here, this paper describes recent advances in MRS measurements of the primary peak using new, thinner, reduced-area deuterated plastic (CD) conversion foils. The new foils allow operation of MRS at yields 2 orders of magnitude higher than previously possible, at a resolution down to ~200 keV FWHM.

High-resolution measurements of the DT neutron spectrum using new CD foils in the Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility.

PubMed

Gatu Johnson, M; Frenje, J A; Bionta, R M; Casey, D T; Eckart, M J; Farrell, M P; Grim, G P; Hartouni, E P; Hatarik, R; Hoppe, M; Kilkenny, J D; Li, C K; Petrasso, R D; Reynolds, H G; Sayre, D B; Schoff, M E; Séguin, F H; Skulina, K; Yeamans, C B

2016-11-01

The Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility measures the DT neutron spectrum from cryogenically layered inertial confinement fusion implosions. Yield, areal density, apparent ion temperature, and directional fluid flow are inferred from the MRS data. This paper describes recent advances in MRS measurements of the primary peak using new, thinner, reduced-area deuterated plastic (CD) conversion foils. The new foils allow operation of MRS at yields 2 orders of magnitude higher than previously possible, at a resolution down to ∼200 keV FWHM.

High temperature ion source for an on-line isotope separator

DOEpatents

Mlekodaj, Ronald L.

1979-01-01

A reduced size ion source for on-line use with a cyclotron heavy-ion beam is provided. A sixfold reduction in source volume while operating with similar input power levels results in a 2000.degree. C. operating temperature. A combined target/window normally provides the reaction products for ionization while isolating the ion source plasma from the cyclotron beam line vacuum. A graphite felt catcher stops the recoiling reaction products and releases them into the plasma through diffusion and evaporation. Other target arrangements are also possible. A twenty-four hour lifetime of unattended operation is achieved, and a wider range of elements can be studied than was heretofore possible.

Mechanical properties of carbon steel depending on the rate of the dose build-up of nitrogen and argon ions

NASA Astrophysics Data System (ADS)

Vorob'ev, V. L.; Bykov, P. V.; Bayankin, V. Ya.; Shushkov, A. A.; Vakhrushev, A. V.

2014-08-01

The effect of pulsed irradiation with argons and nitrogen ions on the mechanical properties, morphology, and structure of the surface layers of carbon steel St3 (0.2% C, 0.4% Mn, 0.15% Si, and Fe for balance) has been investigated depending on the rate of dose build-up at an average ion current density of 10, 20, and 40 μA/cm2. It has been established that the fatigue life and microhardness of surface layers increase in the entire studied range of dose build-up rates. This seems to be due to the hardening of the surface layers, which resulted from the generation of radiation defects and the irradiation-dynamic effect of fast ions. The sample irradiated by argon ions at the lowest of the selected dose build-up rates j av = 10 μA/cm2 withstands the largest number of cycles to failure.

Recoil Polarization and Beam-Recoil Double Polarization Measurement of {eta} Electroproduction on the Proton in the Region of the S{sub 11}(1535) Resonance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Merkel, H.; Achenbach, P.; Ayerbe Gayoso, C.

2007-09-28

The beam-recoil double polarization P{sub x{sup '}}{sup h} and P{sub z{sup '}}{sup h} and the recoil polarization P{sub y{sup '}} were measured for the first time for the p(e-vector,e{sup '}p-vector){eta} reaction at a four-momentum transfer of Q{sup 2}=0.1 GeV{sup 2}/c{sup 2} and a center of mass production angle of {theta}=120 deg. at the Mainz Microtron MAMI-C. With a center of mass energy range of 1500 MeV

Hyperthermal (1-100 eV) nitrogen ion scattering damage to D-ribose and 2-deoxy-D-ribose films.

PubMed

Deng, Zongwu; Bald, Ilko; Illenberger, Eugen; Huels, Michael A

2007-10-14

Highly charged heavy ion traversal of a biological medium can produce energetic secondary fragment ions. These fragment ions can in turn cause collisional and reactive scattering damage to DNA. Here we report hyperthermal (1-100 eV) scattering of one such fragment ion (N(+)) from biologically relevant sugar molecules D-ribose and 2-deoxy-D-ribose condensed on polycrystalline Pt substrate. The results indicate that N(+) ion scattering at kinetic energies down to 10 eV induces effective decomposition of both sugar molecules and leads to the desorption of abundant cation and anion fragments. Use of isotope-labeled molecules (5-(13)C D-ribose and 1-D D-ribose) partly reveals some site specificity of the fragment origin. Several scattering reactions are also observed. Both ionic and neutral nitrogen atoms abstract carbon from the molecules to form CN(-) anion at energies down to approximately 5 eV. N(+) ions also abstract hydrogen from hydroxyl groups of the molecules to form NH(-) and NH(2) (-) anions. A fraction of OO(-) fragments abstract hydrogen to form OH(-). The formation of H(3)O(+) ions also involves hydrogen abstraction as well as intramolecular proton transfer. These findings suggest a variety of severe damaging pathways to DNA molecules which occur on the picosecond time scale following heavy ion irradiation of a cell, and prior to the late diffusion-limited homogeneous chemical processes.

Positive recoil leader in rocket-triggered and tower-initiated lightning flashes as observed by high speed video camera

NASA Astrophysics Data System (ADS)

Qie, X.; Pu, Y.; Jiang, R.; Liu, M.; Sun, Z.

2017-12-01

Positive recoil leader was observed in both rocket-triggered and tower lightning flashes. The similar processes are observed in all the cases: an initial weakening dart leader propagated downward from the cloud with weak luminosity and terminated finally before reaching the ground. Then the bidirectional leaders started and propagated in the preexisting and decaying channel below the terminated downward dart leader, and the luminosity of the bileader ends was asymmetrical, but both with its tip being the weakest. The upward positive leader end started earlier and fast than the downward negative leader end. The bidirectional leader developed with the positive leader moving upward, along the decayed downward negative leader channel, and the negative leader downward, along the remnants of the channel created by the previous stroke or ICC, and, hence, could be viewed as a kind of recoil leader. However, the polarity of this recoil leader is contrary to the traditional recoil leader with negative leader end retrogressing along an existing positive leader channel. The bidirectional leaders observed herein are new as they are excited by a decayed negative leader with in the preexisting discharge channel, unlike other bidirectional leaders, e.g., the electric breakdown in virgin air or traditional recoil processes formed in a decayed positive leader channel.

Stability branching induced by collective atomic recoil in an optomechanical ring cavity

NASA Astrophysics Data System (ADS)

Ian, Hou

2017-02-01

In a ring cavity filled with an atomic condensate, self-bunching of atoms due to the cavity pump mode produce an inversion that re-emits into the cavity probe mode with an exponential gain, forming atomic recoil lasing. An optomechanical ring cavity is formed when one of the reflective mirrors is mounted on a mechanical vibrating beam. In this paper, we extend studies on the stability of linear optomechanical cavities to such ring cavities with two counter-propagating cavity modes, especially when the forward propagating pump mode is taken to its weak coupling limit. We find that when the atomic recoil is in action, stable states of the mechanical mode of the mirror converge into branch cuts, where the gain produced by the recoiling strikes balance with the multiple decay sources, such as cavity leakage in the optomechanical system. This balance is obtained when the propagation delay in the dispersive atomic medium matches in a periodic pattern to the frequencies and linewidths of the cavity mode and the collective bosonic mode of the atoms. We show an input-output hysteresis cycle between the atomic mode and the cavity mode to verify the multi-valuation of the stable states after branching at the weak coupling limit.

The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF.

PubMed

Casey, D T; Frenje, J A; Johnson, M Gatu; Séguin, F H; Li, C K; Petrasso, R D; Glebov, V Yu; Katz, J; Magoon, J; Meyerhofer, D D; Sangster, T C; Shoup, M; Ulreich, J; Ashabranner, R C; Bionta, R M; Carpenter, A C; Felker, B; Khater, H Y; LePape, S; MacKinnon, A; McKernan, M A; Moran, M; Rygg, J R; Yeoman, M F; Zacharias, R; Leeper, R J; Fletcher, K; Farrell, M; Jasion, D; Kilkenny, J; Paguio, R

2013-04-01

The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, ion-temperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

Use of Proton SEE Data as a Proxy for Bounding Heavy-Ion SEE Susceptibility

NASA Technical Reports Server (NTRS)

Ladbury, Raymond L.; Lauenstein, Jean-Marie; Hayes, Kathryn P.

2015-01-01

Although heavy-ion single-event effects (SEE) pose serious threats to semiconductor devices in space, many missions face difficulties testing such devices at heavy-ion accelerators. Low-cost missions often find such testing too costly. Even well funded missions face issues testing commercial off the shelf (COTS) due to packaging and integration. Some missions wish to fly COTS systems with little insight into their components. Heavy-ion testing such parts and systems requires access to expensive and hard-to-access ultra-high energy ion accelerators, or significant system modification. To avoid these problems, some have proposed using recoil ions from high-energy protons as a proxy to bound heavy-ion SEE rates.

Simultaneous determination of total nitrogen and total phosphorus in environmental waters using alkaline persulfate digestion and ion chromatography.

PubMed

De Borba, Brian M; Jack, Richard F; Rohrer, Jeffrey S; Wirt, Joan; Wang, Dongmei

2014-11-21

An ion chromatography (IC) method was developed for the simultaneous determination of total nitrogen and total phosphorus after alkaline persulfate digestion. This study takes advantage of advances in construction of high-resolution, high-capacity anion-exchange columns that can better tolerate the matrices typically encountered when a determination of total nitrogen and total phosphorous is required. Here, we used an electrolytically generated hydroxide eluent combined with a high-capacity, hydroxide-selective, anion-exchange column for the determination of total nitrogen (as nitrate-N) and total phosphorus (as phosphate-P) in environmental samples by IC. This method yielded LODs for nitrate-N and phosphate-P of 1.0 and 1.3 μg/L, respectively. The LOQs determined for these analytes were 3.4 and 4.2 μg/L, respectively. Due to the dilution factor required and the blank nitrate-N concentration after the persulfate digestion, the quantification limits increased for nitrate-N and phosphate-P to 171 and 63 μg/L, respectively. The suitability of the method was evaluated by determining the nitrogen and phosphorus concentrations from known concentrations of organic-containing nitrogen and phosphorus compounds. In addition, environmental samples consisting of six different wastewaters and 48 reservoir samples were evaluated for total nitrogen and phosphorus. The recoveries of nitrogen and phosphorus from the organic-containing compounds ranged from 93.1 to 100.1% and 85.2 to 97.1%, respectively. In addition, good correlation between results obtained by the colorimetric method and IC was also observed. The linearity, accuracy, and evaluation of potential interferences for determining TN and TP will be discussed. Copyright © 2014 Elsevier B.V. All rights reserved.

Immediate stent recoil in an anastomotic vein graft lesion treated by cutting balloon angioplasty.

PubMed

Akkus, Nuri Ilker; Budeepalli, Jagan; Cilingiroglu, Mehmet

2013-11-01

Saphenous vein graft (SVG) anastomotic lesions can have significant fibromuscular hyperplasia and may be resistant to balloon angioplasty alone. Stents have been used successfully to treat these lesions. There are no reports of immediate stent recoil following such treatment in the literature. We describe immediate and persistent stent recoil in an anastomotic SVG lesion even after initial and post-deployment complete balloon dilatation of the stent and its successful treatment by cutting balloon angioplasty. Copyright © 2013 Sociedade Portuguesa de Cardiologia. Published by Elsevier España. All rights reserved.

Detailed Characterization of Nuclear Recoil Pulse Shape Discrimination in the Darkside-50 Direct Dark Matter Experiment

NASA Astrophysics Data System (ADS)

Ludert, Erin Edkins

While evidence of non-baryonic dark matter has been accumulating for decades, its exact nature continues to remain a mystery. Weakly Interacting Massive Particles (WIMPs) are a well motivated candidate which appear in certain extensions of the Standard Model, independently of dark matter theory. If such particles exist, they should occasionally interact with particles of normal matter, producing a signal which may be detected. The DarkSide-50 direct dark matter experiment aims to detect the energy of recoiling argon atoms due to the elastic scattering of postulated WIMPs. In order to make such a discovery, a clear understanding of both the background and signal region is essential. This understanding requires a careful study of the detector's response to radioactive sources, which in turn requires such sources may be safely introduced into or near the detector volume and reliably removed. The CALibration Insertaion System (CALIS) was designed and built for this purpose in a joint effort between Fermi National Laboratory and the University of Hawaii. This work describes the design and testing of CALIS, its installation and commissioning at the Laboratori Nazionali del Gran Sasso (LNGS) and the multiple calibration campaigns which have successfully employed it. As nuclear recoils produced by WIMPs are indistinguishable from those produced by neutrons, radiogenic neutrons are both the most dangerous class of background and a vital calibration source for the study of the potential WIMP signal. Prior to the calibration of DarkSide-50 with radioactive neutron sources, the acceptance region was determined by the extrapolation of nuclear recoil data from a separate, dedicated experiment, ScENE, which measured the distribution of the pulse shape discrimination parameter, f 90, for nuclear recoils of known energies. This work demonstrates the validity of the extrapolation of ScENE values to DarkSide-50, by direct comparison of the f90 distribution of nuclear recoils from Sc

Multi-dimensional effects in radiation pressure acceleration of ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tripathi, V. K., E-mail: tripathivipin@yahoo.co.in

A laser carries momentum. On reflection from an ultra-thin overdense plasma foil, it deposits recoil momentum on the foil, i.e. exerts radiation pressure on the foil electrons and pushes them to the rear. The space charge field thus created takes the ions along, accelerating the electron-ion double layer as a single unit. When the foil has surface ripple, of wavelength comparable to laser wavelength, the radiation pressure acts non-uniformly on the foil and the perturbation grows as Reyleigh-Taylor (RT) instability as the foil moves. The finite spot size of the laser causes foil to bend. These effects limit the quasi-monomore » energy acceleration of ions. Multi-ion foils, e.g., diamond like carbon foil embedded with protons offer the possibility of suppressing RT instability.« less

Pressure-induced transformations of nitrogen implanted into silicon

NASA Astrophysics Data System (ADS)

Akhmetov, V. D.; Misiuk, A.; Barcz, A.; Richter, H.

2006-03-01

Czochralski (CZ) Si samples implanted with nitrogen, with doses 1017 ion/cm2 and 1018 ion/cm2, at 140 keV, were studied by means of Fourier transform infrared spectroscopy after annealing at 1130 °C/5 h under different hydrostatic pressures, from 1 bar to 10.7 kbar. It has been found for each pressure applied, that the increased nitrogen dose leads to transformation of the broadband spectra to the fine structure ones, corresponding to crystalline silicon nitride. The spectral position of observed sharp peaks in the investigated pressure region is red shifted in comparison to that for the peaks of crystalline silicon oxynitride found recently by other investigators in nitrogen-containing poly-Si as well as in a residual melt of nitrogen-doped CZ-Si. The application of the pressure during annealing results in further red shift of the nitrogen-related bands. The observed decrease of frequency of vibrational bands is explained in terms of the pressure induced lowered incorporation of oxygen into growing oxynitride phase. Secondary ion mass spectrometry data reveal the decrease of oxygen content in implanted layer with increasing pressure during annealing.

Spectroscopic investigation of nitrogen-functionalized carbon materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wood, Kevin N.; Christensen, Steven T.; Nordlund, Dennis

2016-04-07

Carbon materials are used in a diverse set of applications ranging from pharmaceuticals to catalysis. Nitrogen modification of carbon powders has shown to be an effective method for enhancing both surface and bulk properties of as-received material for a number of applications. Unfortunately, control of the nitrogen modification process is challenging and can limit the effectiveness and reproducibility of N-doped materials. Additionally, the assignment of functional groups to specific moieties on the surface of nitrogen-modified carbon materials is not straightforward. Herein, we complete an in-depth analysis of functional groups present at the surface of ion-implanted Vulcan and Graphitic Vulcan throughmore » the use of X-ray photoelectron spectroscopy (XPS) and near edge X-ray adsorption fine structure spectroscopy (NEXAFS). Our results show that regardless of the initial starting materials used, nitrogen ion implantation conditions can be tuned to increase the amount of nitrogen incorporation and to obtain both similar and reproducible final distributions of nitrogen functional groups. The development of a well-controlled/reproducible nitrogen implantation pathway opens the door for carbon supported catalyst architectures to have improved numbers of nucleation sites, decreased particle size, and enhanced catalyst-support interactions.« less

Effect of surface modification by nitrogen ion implantation on the electrochemical and cellular behaviors of super-elastic NiTi shape memory alloy.

PubMed

Maleki-Ghaleh, H; Khalil-Allafi, J; Sadeghpour-Motlagh, M; Shakeri, M S; Masoudfar, S; Farrokhi, A; Beygi Khosrowshahi, Y; Nadernezhad, A; Siadati, M H; Javidi, M; Shakiba, M; Aghaie, E

2014-12-01

The aim of this investigation was to enhance the biological behavior of NiTi shape memory alloy while preserving its super-elastic behavior in order to facilitate its compatibility for application in human body. The surfaces of NiTi samples were bombarded by three different nitrogen doses. Small-angle X-ray diffraction was employed for evaluating the generated phases on the bombarded surfaces. The electrochemical behaviors of the bare and surface-modified NiTi samples were studied in simulated body fluid (SBF) using electrochemical impedance and potentio-dynamic polarization tests. Ni ion release during a 2-month period of service in the SBF environment was evaluated using atomic absorption spectrometry. The cellular behavior of nitrogen-modified samples was studied using fibroblast cells. Furthermore, the effect of surface modification on super-elasticity was investigated by tensile test. The results showed the improvement of both corrosion and biological behaviors of the modified NiTi samples. However, no significant change in the super-elasticity was observed. Samples modified at 1.4E18 ion cm(-2) showed the highest corrosion resistance and the lowest Ni ion release.

Application of low energy ion blocking for adsorption site determination of Na Atoms on a Cu(111) surface

NASA Astrophysics Data System (ADS)

Zhang, R.; Makarenko, B.; Bahrim, B.; Rabalais, J. W.

2010-07-01

Ion blocking in the low keV energy range is demonstrated to be a sensitive method for probing surface adsorption sites by means of the technique of time-of-flight scattering and recoiling spectroscopy (TOF-SARS). Adsorbed atoms can block the nearly isotropic backscattering of primary ions from surface atoms in the outmost layers of a crystal. The relative adsorption site position can be derived unambiguously by simple geometrical constructs between the adsorbed atom site and the surface atom sites. Classical ion trajectory simulations using the scattering and recoiling imaging code (SARIC) and molecular dynamics (MD) simulations provide the detailed ion trajectories. Herein we present a quantitative analysis of the blocking effects produced by sub-monolayer Na adsorbed on a Cu(111) surface at room temperature. The results show that the Na adsorption site preferences are different at different Na coverages. At a coverage θ = 0.25 monolayer, Na atoms preferentially populate the fcc threefold surface sites with a height of 2.7 ± 0.1 Å above the 1st layer Cu atoms. At a lower coverage of θ = 0.10 monolayer, there is no adsorption site preference for the Na atoms on the Cu(111) surface.

Ammonia stress on nitrogen metabolism in tolerant aquatic plant-Myriophyllum aquaticum.

PubMed

Zhou, Qingyang; Gao, Jingqing; Zhang, Ruimin; Zhang, Ruiqin

2017-09-01

Ammonia has been a major reason of macrophyte decline in the water environment, and ammonium ion toxicity should be seen as universal, even in species frequently labeled as "NH 4 + specialists". To study the effects of high NH 4 + -N stress of ammonium ion nitrogen on tolerant submerged macrophytes and investigate the pathways of nitrogen assimilation in different organisms, Myriophyllum aquaticum was selected and treated with various concentrations of ammonium ions at different times. Increasing of ammonium concentration leads to an overall increase in incipient ammonia content in leaves and stems of plants. In middle and later stages, high concentrations of NH 4 + ion nitrogen taken up by M. aquaticum decreased, whereas the content of NO 3 - ion nitrogen increased. Moreover, in M. aquaticum, the activities of the enzymes nitrate reductase, glutamine synthetase and asparagine synthetase changed remarkably in the process of alleviating NH 4 + toxicity and deficiency. The results of the present study may support the studies on detoxification of high ammonium ion content in NH 4 + -tolerant submerged macrophytes and exploration of tissue-specific expression systems. Copyright © 2017. Published by Elsevier Inc.

Intense Pulsed Heavy Ion Beam Technology

NASA Astrophysics Data System (ADS)

Masugata, Katsumi; Ito, Hiroaki

Development of intense pulsed heavy ion beam accelerator technology is described for the application of materials processing. Gas puff plasma gun and vacuum arc discharge plasma gun were developed as an active ion source for magnetically insulated pulsed ion diode. Source plasma of nitrogen and aluminum were successfully produced with the gas puff plasma gun and the vacuum arc plasma gun, respectively. The ion diode was successfully operated with gas puff plasma gun at diode voltage 190 kV, diode current 2.2 kA and nitrogen ion beam of ion current density 27 A/cm2 was obtained. The ion composition was evaluated by a Thomson parabola spectrometer and the purity of the nitrogen ion beam was estimated to be 86%. The diode also operated with aluminum ion source of vacuum arc plasma gun. The ion diode was operated at 200 kV, 12 kA, and aluminum ion beam of current density 230 A/cm2 was obtained. The beam consists of aluminum ions (Al(1-3)+) of energy 60-400 keV, and protons (90-130 keV), and the purity was estimated to be 89 %. The development of the bipolar pulse accelerator (BPA) was reported. A double coaxial type bipolar pulse generator was developed as the power supply of the BPA. The generator was tested with dummy load of 7.5 ohm, bipolar pulses of -138 kV, 72 ns (1st pulse) and +130 kV, 70 ns (2nd pulse) were succesively generated. By applying the bipolar pulse to the drift tube of the BPA, nitrogen ion beam of 2 A/cm2 was observed in the cathode, which suggests the bipolar pulse acceleration.

Hyperthermal (1-100 eV) nitrogen ion scattering damage to D-ribose and 2-deoxy-D-ribose films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deng Zongwu; Bald, Ilko; Illenberger, Eugen

2007-10-14

Highly charged heavy ion traversal of a biological medium can produce energetic secondary fragment ions. These fragment ions can in turn cause collisional and reactive scattering damage to DNA. Here we report hyperthermal (1-100 eV) scattering of one such fragment ion (N{sup +}) from biologically relevant sugar molecules D-ribose and 2-deoxy-D-ribose condensed on polycrystalline Pt substrate. The results indicate that N{sup +} ion scattering at kinetic energies down to 10 eV induces effective decomposition of both sugar molecules and leads to the desorption of abundant cation and anion fragments. Use of isotope-labeled molecules (5-{sup 13}C D-ribose and 1-D D-ribose) partlymore » reveals some site specificity of the fragment origin. Several scattering reactions are also observed. Both ionic and neutral nitrogen atoms abstract carbon from the molecules to form CN{sup -} anion at energies down to {approx}5 eV. N{sup +} ions also abstract hydrogen from hydroxyl groups of the molecules to form NH{sup -} and NH{sub 2}{sup -} anions. A fraction of O/O{sup -} fragments abstract hydrogen to form OH{sup -}. The formation of H{sub 3}O{sup +} ions also involves hydrogen abstraction as well as intramolecular proton transfer. These findings suggest a variety of severe damaging pathways to DNA molecules which occur on the picosecond time scale following heavy ion irradiation of a cell, and prior to the late diffusion-limited homogeneous chemical processes.« less

Measuring the spectrum of mutation induced by nitrogen ions and protons in the human-hamster hybrid cell line A(L)C

NASA Technical Reports Server (NTRS)

Kraemer, S. M.; Kronenberg, A.; Ueno, A.; Waldren, C. A.; Chatterjee, A. (Principal Investigator)

2000-01-01

Astronauts can be exposed to charged particles, including protons, alpha particles and heavier ions, during space flights. Therefore, studying the biological effectiveness of these sparsely and densely ionizing radiations is important to understanding the potential health effects for astronauts. We evaluated the mutagenic effectiveness of sparsely ionizing 55 MeV protons and densely ionizing 32 MeV/nucleon nitrogen ions using cells of two human-hamster cell lines, A(L) and A(L)C. We have previously characterized a spectrum of mutations, including megabase deletions, in human chromosome 11, the sole human chromosome in the human-hamster hybrid cell lines A(L)C and A(L). CD59(-) mutants have lost expression of a human cell surface antigen encoded by the CD59 gene located at 11p13. Deletion of genes located on the tip of the short arm of 11 (11p15.5) is lethal to the A(L) hybrid, so that CD59 mutants that lose the entire chromosome 11 die and escape detection. In contrast, deletion of the 11p15.5 region is not lethal in the hybrid A(L)C, allowing for the detection of chromosome loss or other chromosomal mutations involving 11p15.5. The 55 MeV protons and 32 MeV/nucleon nitrogen ions were each about 10 times more mutagenic per unit dose at the CD59 locus in A(L)C cells than in A(L) cells. In the case of nitrogen ions, the mutations observed in A(L)C cells were predominantly due to chromosome loss events or 11p deletions, often containing a breakpoint in the pericentromeric region. The increase in the CD59(-) mutant fraction for A(L)C cells exposed to protons was associated with either translocation of portions of 11q onto a hamster chromosome, or discontinuous or "skipping" mutations. We demonstrate here that A(L)C cells are a powerful tool that will aid in the understanding of the mutagenic effects of different types of ionizing radiation.

Scintillation efficiency measurement of Na recoils in NaI(Tl) below the DAMA/LIBRA energy threshold

NASA Astrophysics Data System (ADS)

Xu, Jingke; Shields, Emily; Calaprice, Frank; Westerdale, Shawn; Froborg, Francis; Suerfu, Burkhant; Alexander, Thomas; Aprahamian, Ani; Back, Henning O.; Casarella, Clark; Fang, Xiao; Gupta, Yogesh K.; Ianni, Aldo; Lamere, Edward; Lippincott, W. Hugh; Liu, Qian; Lyons, Stephanie; Siegl, Kevin; Smith, Mallory; Tan, Wanpeng; Kolk, Bryant Vande

2015-07-01

The dark matter interpretation of the DAMA modulation signal depends on the NaI(Tl) scintillation efficiency of nuclear recoils. Previous measurements for Na recoils have large discrepancies, especially in the DAMA/LIBRA modulation energy region. We report a quenching effect measurement of Na recoils in NaI(Tl) from 3 to 52 keVnr, covering the whole DAMA/LIBRA energy region for dark matter-Na scattering interpretations. By using a low-energy, pulsed neutron beam, a double time-of-flight technique, and pulse-shape discrimination methods, we obtained the most accurate measurement of this kind for NaI(Tl) to date. The results differ significantly from the DAMA reported values at low energies but fall between the other previous measurements. We present the implications of the new quenching results for the dark matter interpretation of the DAMA modulation signal.

Changes in polyamines, inorganic ions and glutamine synthetase activity in response to nitrogen availability and form in red spruce (Picea rubens)

Treesearch

Michelle J. Serapiglia; Rakesh Minocha; Subhash C. Minocha

2008-01-01

We analyzed effects of nitrogen availability and form on growth rates, concentrations of polyamines and inorganic ions and glutamine synthetase activity in in-vitro-cultured red spruce (Picea rubens Sarg.) cells. Growth rates, concentrations of polyamines and glutamine synthetase activity declined when either the amount of nitrate or the total amount...

Pre-compound emission in low-energy heavy-ion interactions

NASA Astrophysics Data System (ADS)

Sharma, Manoj Kumar; Shuaib, Mohd.; Sharma, Vijay R.; Yadav, Abhishek; Singh, Pushpendra P.; Singh, Devendra P.; Unnati; Singh, B. P.; Prasad, R.

2017-11-01

Recent experimental studies have shown the presence of pre-compound emission component in heavy ion reactions at low projectile energy ranging from 4 to 7 MeV/nucleons. In earlier measurements strength of the pre-compound component has been estimated from the difference in forward-backward distributions of emitted particles. Present measurement is a part of an ongoing program on the study of reaction dynamics of heavy ion interactions at low energies aimed at investigating the effect of momentum transfer in compound, precompound, complete and incomplete fusion processes in heavy ion reactions. In the present work on the basis of momentum transfer the measurement of the recoil range distributions of heavy residues has been used to decipher the components of compound and pre-compound emission processes in the fusion of 16O projectile with 159Tb and 169Tm targets. The analysis of recoil range distribution measurements show two distinct linear momentum transfer components corresponding to pre-compound and compound nucleus processes are involved. In order to obtain the mean input angular momentum associated with compound and pre-compound emission processes, an online measurement of the spin distributions of the residues has been performed. The analysis of spin distribution indicate that the mean input angular momentum associated with pre-compound products is found to be relatively lower than that associated with compound nucleus process. The pre-compound components obtained from the present analysis are consistent with those obtained from the analysis of excitation functions.

Compact RF ion source for industrial electrostatic ion accelerator

NASA Astrophysics Data System (ADS)

Kwon, Hyeok-Jung; Park, Sae-Hoon; Kim, Dae-Il; Cho, Yong-Sub

2016-02-01

Korea Multi-purpose Accelerator Complex is developing a single-ended electrostatic ion accelerator to irradiate gaseous ions, such as hydrogen and nitrogen, on materials for industrial applications. ELV type high voltage power supply has been selected. Because of the limited space, electrical power, and robust operation, a 200 MHz RF ion source has been developed. In this paper, the accelerator system, test stand of the ion source, and its test results are described.

Compact RF ion source for industrial electrostatic ion accelerator.

PubMed

Kwon, Hyeok-Jung; Park, Sae-Hoon; Kim, Dae-Il; Cho, Yong-Sub

2016-02-01

Korea Multi-purpose Accelerator Complex is developing a single-ended electrostatic ion accelerator to irradiate gaseous ions, such as hydrogen and nitrogen, on materials for industrial applications. ELV type high voltage power supply has been selected. Because of the limited space, electrical power, and robust operation, a 200 MHz RF ion source has been developed. In this paper, the accelerator system, test stand of the ion source, and its test results are described.

Acute stent recoil and optimal balloon inflation strategy: an experimental study using real-time optical coherence tomography.

PubMed

Kitahara, Hideki; Waseda, Katsuhisa; Yamada, Ryotaro; Otagiri, Kyuhachi; Tanaka, Shigemitsu; Kobayashi, Yuhei; Okada, Kozo; Kume, Teruyoshi; Nakagawa, Kaori; Teramoto, Tomohiko; Ikeno, Fumiaki; Yock, Paul G; Fitzgerald, Peter J; Honda, Yasuhiro

2016-06-12

Our aim was to evaluate stent expansion and acute recoil at deployment and post-dilatation, and the impact of post-dilatation strategies on final stent dimensions. Optical coherence tomography (OCT) was performed on eight bare metal platforms of drug-eluting stents (3.0 mm diameter, n=6 for each) during and after balloon inflation in a silicone mock vessel. After nominal-pressure deployment, a single long (30 sec) vs. multiple short (10 sec x3) post-dilatations were performed using a non-compliant balloon (3.25 mm, 20 atm). Stent areas during deployment with original delivery systems were smaller in stainless steel stents than in cobalt-chromium and platinum-chromium stents (p<0.001), whereas subsequent acute recoil was comparable among the three materials. At post-dilatation, acute recoil was greater in cobalt-chromium and platinum-chromium stents than in stainless steel stents (p<0.001), resulting in smaller final stent areas in cobalt-chromium and platinum-chromium stents than in stainless steel stents (p<0.001). In comparison between conventional and latest-generation cobalt-chromium stents, stent areas were not significantly different after both deployment and post-dilatation. With multiple short post-dilatations, acute recoil was significantly improved from first to third short inflation (p<0.001), achieving larger final area than a single long inflation, despite stent materials/designs (p<0.001). Real-time OCT revealed significant acute recoil in all stent types. Both stent materials/designs and post-dilatation strategies showed a significant impact on final stent expansion.

Self-organized surface ripple pattern formation by ion implantation

NASA Astrophysics Data System (ADS)

Hofsäss, Hans; Zhang, Kun; Bobes, Omar

2016-10-01

Ion induced ripple pattern formation on solid surfaces has been extensively studied in the past and the theories describing curvature dependent ion erosion as well as redistribution of recoil atoms have been very successful in explaining many features of the pattern formation. Since most experimental studies use noble gas ion irradiation, the incorporation of the ions into the films is usually neglected. In this work we show that the incorporation or implantation of non-volatile ions also leads to a curvature dependent term in the equation of motion of a surface height profile. The implantation of ions can be interpreted as a negative sputter yield; and therefore, the effect of ion implantation is opposite to the one of ion erosion. For angles up to about 50°, implantation of ions stabilizes the surface, whereas above 50°, ion implantation contributes to the destabilization of the surface. We present simulations of the curvature coefficients using the crater function formalism and we compare the simulation results to the experimental data on the ion induced pattern formation using non-volatile ions. We present several model cases, where the incorporation of ions is a crucial requirement for the pattern formation.

Black hole as a point radiator and recoil effect on the brane world.

PubMed

Frolov, Valeri; Stojković, Dejan

2002-10-07

A small black hole attached to a brane in a higher-dimensional space emitting quanta into the bulk may leave the brane as a result of a recoil. We construct a field theory model in which such a black hole is described as a massive scalar particle with internal degrees of freedom. In this model, the probability of transition between the different internal levels is identical to the probability of thermal emission calculated for the Schwarzschild black hole. The discussed recoil effect implies that the thermal emission of the black holes, which might be created by interaction of high energy particles in colliders, could be terminated and the energy nonconservation can be observed in the brane experiments.

Detailed Characterization of Nuclear Recoil Pulse Shape Discrimination in the DarkSide-50 Direct Dark Matter Experiment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edkins, Erin Elisabeth

While evidence of non-baryonic dark matter has been accumulating for decades, its exact nature continues to remain a mystery. Weakly Interacting Massive Particles (WIMPs) are a well motivated candidate which appear in certain extensions of the Standard Model, independently of dark matter theory. If such particles exist, they should occasionally interact with particles of normal matter, producing a signal which may be detected. The DarkSide-50 direct dark matter experiment aims to detect the energy of recoiling argon atoms due to the elastic scattering of postulated WIMPs. In order to make such a discovery, a clear understanding of both the background and signal region is essential. This understanding requires a careful study of the detector's response to radioactive sources, which in turn requires such sources may be safely introduced into or near the detector volume and reliably removed. The CALibration Insertaion System (CALIS) was designed and built for this purpose in a j oint effort between Fermi National Laboratory and the University of Hawaii. This work describes the design and testing of CALIS, its installation and commissioning at the Laboratori Nazionali del Gran Sasso (LNGS) and the multiple calibration campaigns which have successfully employed it. As nuclear recoils produced by WIMPs are indistinguishable from those produced by neutrons, radiogenic neutrons are both the most dangerous class of background and a vital calibration source for the study of the potential WIMP signal. Prior to the calibration of DarkSide-50 with radioactive neutron sources, the acceptance region was determined by the extrapolation of nuclear recoil data from a separate, dedicated experiment, ScENE, which measured the distribution of the pulse shape discrimination parameter,more » $$f_{90}$$, for nuclear recoils of known energies. This work demonstrates the validity of the extrapolation of ScENE values to DarkSide-50, by direct comparison of the $$f_{90}$$ distributio n of

Scintillation efficiency measurement of Na recoils in NaI(Tl) below the DAMA/LIBRA energy threshold

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Jingke; Shields, Emily; Calaprice, Frank

2015-07-01

The dark matter interpretation of the DAMA modulation signal depends on the NaI(Tl) scintillation efficiency of nuclear recoils. Previous measurements for Na recoils have large discrepancies, especially in the DAMA/LIBRA modulation energy region. We report a quenching effect measurement of Na recoils in NaI(Tl) from 3 to 52 keVnr, covering the whole DAMA/LIBRA energy region for dark matter-Na scattering interpretations. By using a low-energy, pulsed neutron beam, a double time-of-flight technique, and pulse-shape discrimination methods, we obtained the most accurate measurement of this kind for NaI(Tl) to date. The results differ significantly from the DAMA reported values at low energies butmore » fall between the other previous measurements. We present the implications of the new quenching results for the dark matter interpretation of the DAMA modulation signal.« less

Molecular-level characterization of reactive and refractory dissolved natural organic nitrogen compounds by atmospheric pressure photoionization coupled to Fourier transform ion cyclotron resonance mass spectrometry.

PubMed

Osborne, Daniel M; Podgorski, David C; Bronk, Deborah A; Roberts, Quinn; Sipler, Rachel E; Austin, David; Bays, James S; Cooper, William T

2013-04-30

Dissolved organic nitrogen (DON) represents a significant fraction of the total dissolved nitrogen pool in most surface waters and serves as an important nitrogen source for phytoplankton and bacteria. As with other natural organic matter mixtures, ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) is the only technique currently able to provide molecular composition information on DON. Although electrospray ionization (ESI) is the most commonly used ionization method, it is not very efficient at ionizing most DON components. Positive- and negative-mode atmospheric pressure photoionization (APPI) coupled with ultrahigh resolution FTICRMS at 9.4 T were compared for determining the composition of DON before and after bioassays. Toluene was added as the APPI dopant to the solid-phase DON extracts, producing a final sample that was 90% methanol and 10% toluene by volume. Positive-mode (+) APPI proved significantly more efficient at ionizing DON; 62% of the formulas that could be assigned in the positive-ion spectrum contained at least one nitrogen atom vs. 31% in the negative-ion spectrum. FTICR mass spectral data indicated that most of the refractory DON compounds (i.e. nonreactive during the 5 days of the incubation) had molecular compositions representative of lignin-like molecules, while lipid-like and protein-like molecules comprised most of the small reactive component of the DON pool. From these data we conclude that (+) APPI FTICRMS is a promising technique for describing the molecular composition of DON mixtures. The technique is particularly valuable in assessing the bioavailability of individual components of DON when combined with bioassays. Copyright © 2013 John Wiley & Sons, Ltd.

Comparison of Ion Balance and Nitrogen Metabolism in Old and Young Leaves of Alkali-Stressed Rice Plants

PubMed Central

Wang, Huan; Wu, Zhihai; Han, Jiayu; Zheng, Wei; Yang, Chunwu

2012-01-01

Background Alkali stress is an important agricultural contaminant and has complex effects on plant metabolism. The aim of this study was to investigate whether the alkali stress has different effects on the growth, ion balance, and nitrogen metabolism in old and young leaves of rice plants, and to compare functions of both organs in alkali tolerance. Methodology/Principal Findings The results showed that alkali stress only produced a small effect on the growth of young leaves, whereas strongly damaged old leaves. Rice protected young leaves from ion harm via the large accumulation of Na+ and Cl− in old leaves. The up-regulation of OsHKT1;1, OsAKT1, OsHAK1, OsHAK7, OsHAK10 and OsHAK16 may contribute to the larger accumulation of Na+ in old leaves under alkali stress. Alkali stress mightily reduced the NO3 − contents in both organs. As old leaf cells have larger vacuole, under alkali stress these scarce NO3 − was principally stored in old leaves. Accordingly, the expression of OsNRT1;1 and OsNRT1;2 in old leaves was up-regulated by alkali stress, revealing that the two genes might contribute to the accumulation of NO3 − in old leaves. NO3 − deficiency in young leaves under alkali stress might induce the reduction in OsNR1 expression and the subsequent lacking of NH4 +, which might be main reason for the larger down-regulation of OsFd-GOGAT and OsGS2 in young leaves. Conclusions/Significance Our results strongly indicated that, during adaptation of rice to alkali stress, young and old leaves have distinct mechanisms of ion balance and nitrogen metabolism regulation. We propose that the comparative studies of young and old tissues may be important for abiotic stress tolerance research. PMID:22655071

Encapsulating micro-nano Si/SiO x into conjugated nitrogen-doped carbon as binder-free monolithic anodes for advanced lithium ion batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Jing; Zhou, Meijuan; Tan, Guoqiang

2015-01-01

Silicon monoxide, a promising silicon-based anode candidate for lithium-ion batteries, has recently attracted much attention for its high theoretical capacity, good cycle stability, low cost, and environmental benignity. Currently, the most critical challenge is to improve its low initial coulombic efficiency and significant volume changes during the charge–discharge processes. Herein, we report a binder-free monolithic electrode structure based on directly encapsulating micro-nano Si/SiOx particles into conjugated nitrogen-doped carbon frameworks to form monolithic, multi-core, cross-linking composite matrices. We utilize micro-nano Si/SiOx reduced by high-energy ball-milling SiO as active materials, and conjugated nitrogen-doped carbon formed by the pyrolysis of polyacrylonitrile both asmore » binders and conductive agents. Owing to the high electrochemical activity of Si/SiOx and the good mechanical resiliency of conjugated nitrogen-doped carbon backbones, this specific composite structure enhances the utilization efficiency of SiO and accommodates its large volume expansion, as well as its good ionic and electronic conductivity. The annealed Si/SiOx/polyacrylonitrile composite electrode exhibits excellent electrochemical properties, including a high initial reversible capacity (2734 mA h g-1 with 75% coulombic efficiency), stable cycle performance (988 mA h g-1 after 100 cycles), and good rate capability (800 mA h g-1 at 1 A g-1 rate). Because the composite is naturally abundant and shows such excellent electrochemical performance, it is a promising anode candidate material for lithium-ion batteries. The binder-free monolithic architectural design also provides an effective way to prepare other monolithic electrode materials for advanced lithium-ion batteries.« less

Further improvement in ganoderic acid production in static liquid culture of Ganoderma lucidum by integrating nitrogen limitation and calcium ion addition.

PubMed

Li, Huan-Jun; Zhang, De-Huai; Han, Li-Liang; Yu, Xuya; Zhao, Peng; Li, Tao; Zhong, Jian-Jiang; Xu, Jun-Wei

2016-01-01

To further improve the ganoderic acid (GA) production, a novel integrated strategy by combining nitrogen limitation and calcium ion addition was developed. The effects of the integrated combination on the content of GA-T (one powerful anticancer compound), their intermediates (squalene and lanosterol) and on the transcription levels of GA biosynthetic genes in G. lucidum fermentation were investigated. The maximum GA-T content with the integrated strategy were 1.87 mg/ 100 mg dry cell weight, which was 2.1-4.2 fold higher than that obtained with either calcium ion addition or nitrogen limitation alone, and it is also the highest record as ever reported in submerged fermentation of G. lucidum. The squalene content was increased by 3.9- and 2.2-fold in this case compared with either individual strategy alone. Moreover, the transcription levels of the GA biosynthetic genes encoding 3-hydroxy-3-methyglutaryl coenzyme A reductase and lanosterol synthase were also up-regulated by 3.3-7.5 and 1.3-2.3 fold, respectively.

Measurement of 1323 and 1487 keV resonances in 15N(α ,γ )19F with the recoil separator ERNA

NASA Astrophysics Data System (ADS)

Di Leva, A.; Imbriani, G.; Buompane, R.; Gialanella, L.; Best, A.; Cristallo, S.; De Cesare, M.; D'Onofrio, A.; Duarte, J. G.; Gasques, L. R.; Morales-Gallegos, L.; Pezzella, A.; Porzio, G.; Rapagnani, D.; Roca, V.; Romoli, M.; Schürmann, D.; Straniero, O.; Terrasi, F.; ERNA Collaboration

2017-04-01

Background: The origin of fluorine is a widely debated issue. Nevertheless, the 15N(α ,γ )19F reaction is a common feature among the various production channels so far proposed. Its reaction rate at relevant temperatures is determined by a number of narrow resonances together with the direct capture and the tails of the two broad resonances at Ec .m .=1323 and 1487 keV. Purpose: The broad resonances widths, Γγ and Γα, have to be measured with adequate precision in order to better determine their contribution to the 15N(α ,γ )19F stellar reaction rate. Methods: Measurement through the direct detection of the 19F recoil ions with the European Recoil separator for Nuclear Astrophysics (ERNA) were performed. The reaction was initiated by a 15N beam impinging onto a 4He windowless gas target. The observed yield of the resonances at Ec .m .=1323 and 1487 keV is used to determine their widths in the α and γ channels. Results: We show that a direct measurement of the cross section of the 15N(α ,γ )19F reaction can be successfully obtained with the recoil separator ERNA, and the widths Γγ and Γα of the two broad resonances have been determined. While a fair agreement is found with earlier determination of the widths of the 1487 keV resonance, a significant difference is found for the 1323 keV resonance Γα. Conclusions: The revision of the widths of the two more relevant broad resonances in the 15N(α ,γ )19F reaction presented in this work is the first step toward a more firm determination of the reaction rate. At present, the residual uncertainty at the temperatures of the 19F stellar nucleosynthesis is dominated by the uncertainties affecting the direct capture component and the 364 keV narrow resonance, both so far investigated only through indirect experiments.

Measurement of the ionization produced by sub-keV silicon nuclear recoils in a CCD dark matter detector

DOE PAGES

Chavarria, A. E.; Collar, J. I.; Peña, J. R.; ...

2016-10-15

We report a measurement of the ionization efficiency of silicon nuclei recoiling with sub-keV kinetic energy in the bulk silicon of a charge-coupled device (CCD). Nuclear recoils are produced by low-energy neutrons (<24 keV) from a 124Sb– 9Be photoneutron source, and their ionization signal is measured down to 60 eV electron equivalent. This energy range, previously unexplored, is relevant for the detection of low-mass dark matter particles. The measured efficiency is found to deviate from the extrapolation to low energies of the Lindhard model. Furthermore, this measurement also demonstrates the sensitivity to nuclear recoils of CCDs employed by DAMIC, amore » dark matter direct detection experiment located in the SNOLAB underground laboratory.« less

Enhanced nitrogen diffusion induced by atomic attrition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ochoa, E.A.; Figueroa, C.A.; Czerwiec, T.

2006-06-19

The nitrogen diffusion in steel is enhanced by previous atomic attrition with low energy xenon ions. The noble gas bombardment generates nanoscale texture surfaces and stress in the material. The atomic attrition increases nitrogen diffusion at lower temperatures than the ones normally used in standard processes. The stress causes binding energy shifts of the Xe 3d{sub 5/2} electron core level. The heavy ion bombardment control of the texture and stress of the material surfaces may be applied to several plasma processes where diffusing species are involved.

Identification of the nitrogen-based blister agents bis(2-chloroethyl)methylamine (HN-2) and tris(2-chloroethyl)amine (HN-3) and their hydrolysis products on soil using ion trap secondary ion mass spectrometry.

PubMed

Gresham, G L; Groenewold, G S; Olson, J E

2000-12-01

The nitrogen blister agents HN-2 (bis(2-chloroethyl)methylamine) and HN-3 (tris(2-chloroethyl)amine) were directly analyzed on the surface of soil samples using ion trap secondary ion mass spectrometry (SIMS). In the presence of water, HN-1 (bis(2-choroethyl)ethylamine), HN-2 and HN-3 undergo hydrolysis to form N-ethyldiethanolamine, N-methyldiethanolamine and triethanolamine (TEA), respectively; these compounds can be readily detected as adsorbed species on soil particles. When soil samples spiked with HN-3 in alcohol were analyzed, 2-alkoxyethylamine derivatives were observed on the sample surfaces. This result shows that nitrogen blister agents will undergo condensation reactions with nucleophilic compounds and emphasizes the need for an analytical methodology capable of detecting a range of degradation and condensation products on environmental surfaces. The ability of ion trap SIMS to isolate and accumulate ions, and then perform tandem mass spectrometric analysis improves the detection of low-abundance surface contaminants and the selectivity of the technique. Utilizing these techniques, the limits of detection for HN-3 were studied as a function of surface coverage. It was found that HN-3 could be detected at a surface coverage of 0.01 monolayer, which corresponds to 20 ppm (mass/mass) for a soil having a surface area of 2.2 m(2) g(-1). TEA, the exhaustive hydrolysis product of HN-3, was detected at a surface coverage of 0.001 monolayer, which corresponds to 0.86 ppm. Copyright 2000 John Wiley & Sons, Ltd.

Nitrogen-doped graphene by all-solid-state ball-milling graphite with urea as a high-power lithium ion battery anode

NASA Astrophysics Data System (ADS)

Liu, Chao; Liu, Xingang; Tan, Jiang; Wang, Qingfu; Wen, Hao; Zhang, Chuhong

2017-02-01

Nitrogen-doped graphene nanosheets (NGNS) are prepared by a novel mechanochemical method via all-solid-state ball-milling graphite with urea. The ball-milling process does not only successfully exfoliate the graphite into multi-layer (<10 layers) graphene nanosheets, but at the same time, enables the N element to be doped onto the graphene. Urea, acting as a new solid doping and assist-grinding agents, has the advantages of low cost and good water solubility that can simplify the fabrication process. The as-prepared NGNS are investigated in detail by XRD, SEM, HRTEM, TGA, XPS and Raman spectroscopy. The doping nitrogens are around 3.15% and dominated (>94%) by pyrindic-N and pyrrolic-N which facilitates the NGNS with enhanced electronic conductivity and Li-ion storage capability. For the first time, we demonstrate that the all-solid-state prepared NGNS exhibits, especially at high currents, enhanced cycling stability and rate capability as Lithium ion battery (LIB) anode active material when compared to pristine graphite and undoped graphene in half-cell configuration. The method presented in this article may provide a simple, clean, economical and scalable strategy for preparation of NGNS as a feasible and promising anode material for LIBs.

Compositional and structural analysis of nitrogen incorporated and ion implanted diamond thin films

NASA Astrophysics Data System (ADS)

Garratt, Elias James

Significant progress in area of nano-structured thin film systems has taken place in recent decades. In particular, diamond thin film systems are being widely studied for their wear resistant, optical and electronic properties. Of the various methods researchers use to modify the structure of such films, three techniques in particular are of interest due to their versatility: modification of the growth atmosphere, growth on metalized substrates, providing an interfacial layer, and modification through post-growth ion implantation. The aim of this study is to investigate the effects each has to the structure and composition of elements. Different techniques are applied in each section; nitrogen gas dilution in a microwave plasma CVD system, diamond deposition on a metal interfacial layer and ion implantation in thin nanocrystalline diamond film. The forms of nanocrystalline diamond film resulting from such modifications are investigated using advanced spectroscopic and spectrometric techniques, as well as mechanical testing and surface mapping. The impact of these characterizations will provide valuable perspective to researchers in materials science. Understanding the changes to the structure and properties of this class of thin films, which can be induced through various mechanisms, will allow future researchers to refine these films towards technological applications in areas of hard coatings, electronics and photonics.

Enhancement of butanol tolerance and butanol yield in Clostridium acetobutylicum mutant NT642 obtained by nitrogen ion beam implantation.

PubMed

Liu, Xiao-Bo; Gu, Qiu-Ya; Yu, Xiao-Bin; Luo, Wei

2012-12-01

As a promising alternative biofuel, biobutanol can be produced through acetone/butanol/ethanol (ABE) fermentation. Currently, ABE fermentation is still a small-scale industry due to its low production and high input cost. Moreover, butanol toxicity to the Clostridium fermentation host limits the accumulation of butanol in the fermentation broth. The wild-type Clostridium acetobutylicum D64 can only produce about 13 g butanol/L and tolerates less than 2% (v/v) butanol. To improve the tolerance of C. acetobutylicum D64 for enhancing the production of butanol, nitrogen ion beam implantation was employed and finally five mutants with enhanced butanol tolerance were obtained. Among these, the most butanol tolerant mutant C. acetobutylicum NT642 can tolerate above 3% (v/v) butanol while the wide-type strain can only withstand 2% (v/v). In batch fermentation, the production of butanol and ABE yield of C. acetobutylicum NT642 was 15.4 g/L and 22.3 g/L, respectively, which were both higher than those of its parental strain and the other mutants using corn or cassava as substrate. Enhancing butanol tolerance is a great precondition for obtaining a hyper-yield producer. Nitrogen ion beam implantation could be a promising biotechnology to improve butanol tolerance and production of the host strain C. acetobutylicum.

Shot-noise-limited monitoring and phase locking of the motion of a single trapped ion.

PubMed

Bushev, P; Hétet, G; Slodička, L; Rotter, D; Wilson, M A; Schmidt-Kaler, F; Eschner, J; Blatt, R

2013-03-29

We perform a high-resolution real-time readout of the motion of a single trapped and laser-cooled Ba+ ion. By using an interferometric setup, we demonstrate a shot-noise-limited measurement of thermal oscillations with a resolution of 4 times the standard quantum limit. We apply the real-time monitoring for phase control of the ion motion through a feedback loop, suppressing the photon recoil-induced phase diffusion. Because of the spectral narrowing in the phase-locked mode, the coherent ion oscillation is measured with a resolution of about 0.3 times the standard quantum limit.

On the Form of the Collective Bremsstrahlung Recoil Force in a Nonequilibrium Relativistic Beam-Plasma System.

DTIC Science & Technology

1984-01-01

RD-RI39 895 ON THE FORM OF THE COLLECTIVE BREMSSTRRHLUNG RECOIL i / i FORCE IN A NONEQUILIBRIUM RELATIVISTIC BEAM-PLASMA SYSTEM(U) HARRY DIAMOND LABS...A A O- I I .. . .:. .~ . ." . .- . . . AD Al 39895 H DL-TR-2026 .- 2 ,January 1984 ’ On the Form of the Collective Bremsstrahlung Recoil:O Kodf...Nonequillbrium Relativistic Beam-Plasma System; by Howard It. Brandt A and -t 4 C.. 4 :;x.. 4 4~ . Approw for *4444 𔃿 . U.S.~ Arm Lad Dee ,7 , .1 I . A L

Life-Cycle Cost and Environmental Assessment of Decentralized Nitrogen Recovery Using Ion Exchange from Source-Separated Urine through Spatial Modeling.

PubMed

Kavvada, Olga; Tarpeh, William A; Horvath, Arpad; Nelson, Kara L

2017-11-07

Nitrogen standards for discharge of wastewater effluent into aquatic bodies are becoming more stringent, requiring some treatment plants to reduce effluent nitrogen concentrations. This study aimed to assess, from a life-cycle perspective, an innovative decentralized approach to nitrogen recovery: ion exchange of source-separated urine. We modeled an approach in which nitrogen from urine at individual buildings is sorbed onto resins, then transported by truck to regeneration and fertilizer production facilities. To provide insight into impacts from transportation, we enhanced the traditional economic and environmental assessment approach by combining spatial analysis, system-scale evaluation, and detailed last-mile logistics modeling using the city of San Francisco as an illustrative case study. The major contributor to energy intensity and greenhouse gas (GHG) emissions was the production of sulfuric acid to regenerate resins, rather than transportation. Energy and GHG emissions were not significantly sensitive to the number of regeneration facilities. Cost, however, increased with decentralization as rental costs per unit area are higher for smaller areas. The metrics assessed (unit energy, GHG emissions, and cost) were not significantly influenced by facility location in this high-density urban area. We determined that this decentralized approach has lower cost, unit energy, and GHG emissions than centralized nitrogen management via nitrification-denitrification if fertilizer production offsets are taken into account.

A study to compute integrated dpa for neutron and ion irradiation environments using SRIM-2013

NASA Astrophysics Data System (ADS)

Saha, Uttiyoarnab; Devan, K.; Ganesan, S.

2018-05-01

Displacements per atom (dpa), estimated based on the standard Norgett-Robinson-Torrens (NRT) model, is used for assessing radiation damage effects in fast reactor materials. A computer code CRaD has been indigenously developed towards establishing the infrastructure to perform improved radiation damage studies in Indian fast reactors. We propose a method for computing multigroup neutron NRT dpa cross sections based on SRIM-2013 simulations. In this method, for each neutron group, the recoil or primary knock-on atom (PKA) spectrum and its average energy are first estimated with CRaD code from ENDF/B-VII.1. This average PKA energy forms the input for SRIM simulation, wherein the recoil atom is taken as the incoming ion on the target. The NRT-dpa cross section of iron computed with "Quick" Kinchin-Pease (K-P) option of SRIM-2013 is found to agree within 10% with the standard NRT-dpa values, if damage energy from SRIM simulation is used. SRIM-2013 NRT-dpa cross sections applied to estimate the integrated dpa for Fe, Cr and Ni are in good agreement with established computer codes and data. A similar study carried out for polyatomic material, SiC, shows encouraging results. In this case, it is observed that the NRT approach with average lattice displacement energy of 25 eV coupled with the damage energies from the K-P option of SRIM-2013 gives reliable displacement cross sections and integrated dpa for various reactor spectra. The source term of neutron damage can be equivalently determined in the units of dpa by simulating self-ion bombardment. This shows that the information of primary recoils obtained from CRaD can be reliably applied to estimate the integrated dpa and damage assessment studies in accelerator-based self-ion irradiation experiments of structural materials. This study would help to advance the investigation of possible correlations between the damages induced by ions and reactor neutrons.

Freeze-drying synthesis of three-dimensional porous LiFePO4 modified with well-dispersed nitrogen-doped carbon nanotubes for high-performance lithium-ion batteries

NASA Astrophysics Data System (ADS)

Tu, Xiaofeng; Zhou, Yingke; Song, Yijie

2017-04-01

The three-dimensional porous LiFePO4 modified with uniformly dispersed nitrogen-doped carbon nanotubes has been successfully prepared by a freeze-drying method. The morphology and structure of the porous composites are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and the electrochemical performances are evaluated using the constant current charge/discharge tests, cyclic voltammetry and electrochemical impedance spectroscopy. The nitrogen-doped carbon nanotubes are uniformly dispersed inside the porous LiFePO4 to construct a superior three-dimensional conductive network, which remarkably increases the electronic conductivity and accelerates the diffusion of lithium ion. The porous composite displays high specific capacity, good rate capability and excellent cycling stability, rendering it a promising positive electrode material for high-performance lithium-ion batteries.

Surface normal velocity distribution of sputtered Zr-atoms for light-ion irradiation

NASA Astrophysics Data System (ADS)

Bay, H. L.; Berres, W.; Hintz, E.

1982-03-01

The velocity distribution of sputtered Zr-atoms has been measured for 8 keV Ar + and He + ions and 2.5 keV D + ion irradiation at normal incidence. The measurements were performed with the aid of laser induced fluorescence spectroscopy (LIFS) using a CW-laser pumped dye-laser. The influence of the measuring geometry was investigated and found to be in good agreement with calculation. For light-ion sputtering the collision-cascade theory is no longer applicable. Here a distinct shift in the velocity distributions towards lower velocities compared with the Ar results was found. The shift can be correlated to anisotropic effects in connection with the change in the maximum recoil energy Tm in the cascade.

Monitoring Ion Track Formation Using In Situ RBS/c, ToF-ERDA, and HR-PIXE

NASA Astrophysics Data System (ADS)

Karlušić, Marko; Fazinić, Stjepko; Siketić, Zdravko; Tadić, Tonči; Cosic, Donny; Božičević-Mihalić, Iva; Zamboni, Ivana; Jakšić, Milko; Schleberger, Marika

2017-09-01

The aim of this work is to investigate feasibility of the ion beam analysis techniques for monitoring swift heavy ion track formation. First, use of the in situ Rutherford backscattering spectroscopy in channeling mode to observe damage build-up in quartz SiO2 after MeV heavy ion irradiation is demonstrated. Second, new results of the in situ grazing incidence time-of-flight elastic recoil detection analysis used for monitoring the surface elemental composition during ion tracks formation in various materials are presented. Ion tracks were found on SrTiO3, quartz SiO2, a-SiO2 and muscovite mica surfaces by atomic force microscopy, but in contrast to our previous studies on GaN and TiO2, surface stoichiometry remained unchanged.

The recoil implantation technique developed at the U-120 cyclotron in Bucharest

NASA Astrophysics Data System (ADS)

Muntele, C. I.; Simil, L. Popa; Racolta, P. M.; Voiculescu, D.

1999-06-01

At the U-120 cyclotron in Bucharest was developed 15 years ago the thin layer activation (TLA) technique for radioactive labeling of metallic components on depths ranging between 100 μm and 300 μm, for wear/corrosion studies. Aiming to extend these kinds of studies on non-metallic components and at sub-micrometric level we were led to the development of the recoil implantation technique for ultra thin layer activation (UTLA) applications. Due to the low energy of the recoils obtained in a sacrificial target from a nuclear reaction, the surface layer of material to be labeled must be as thick as a few hundred nanometers. Also, since the radiotracer is externally created, there are no restrictions for the kind of material to be labeled, except to be a solid. In this paper we present some results of our studies concerning the actual status of this application at our accelerator.

Deuterium permeation behaviors in tungsten implanted with nitrogen

NASA Astrophysics Data System (ADS)

Liang, Chuan-hui; Wang, Dongping; Jin, Wei; Lou, Yuanfu; Wang, Wei; Ye, Xiaoqiu; Chen, Chang-an; Liu, Kezhao; Xu, Haiyan; Wang, Xiaoying; Kleyn, Aart W.

2018-07-01

Surface modification of tungsten due to the cooling species nitrogen seeded in the divertor region, i.e., by nitrogen ion implantation or re-deposition, is considered to affect the permeation behavior of H isotopes. This work focuses on the effect of nitrogen ion implantation into tungsten (W-N) on the deuterium gas-driven permeation behavior. For comparison, both permeation in tungsten implanted with W ion (W-W) and without implantation (pristine W) are studied. These three samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photo-electron spectroscopy (XPS). The SEM results revealed that the W-W sample has various voids on the surface, and the W-N sample has a rough surface with pretty fine microstructures. These are different from the pristine W sample with a smooth and compact surface. The XRD patterns show the disappearance of crystallinity on both W-W and W-N sample surfaces. It indicates that the ion implantation process results in an almost complete conversion from crystalline to amorphous in the sample surfaces. The sputter-depth profiling XPS spectra show that the implanted nitrogen prefers to form a 140 nm thick tungsten nitride layer. In permeation experiments, it was found that the D permeability is temperature dependent. Interestingly, the W-N sample presented a lower D permeability than the W-W sample, but higher than the pristine W sample. Such behavior implies that tungsten nitride acts as a permeation barrier, while defects created by ions implantation can promote permeability. The possible permeation mechanism correlated with sample surface composition and microstructure is consequently discussed in this work.

Nitrogen-Doped Porous Carbon Nanosheets from Eco-Friendly Eucalyptus Leaves as High Performance Electrode Materials for Supercapacitors and Lithium Ion Batteries.

PubMed

Mondal, Anjon Kumar; Kretschmer, Katja; Zhao, Yufei; Liu, Hao; Wang, Chengyin; Sun, Bing; Wang, Guoxiu

2017-03-13

Nitrogen-doped porous carbon nanosheets were prepared from eucalyptus tree leaves by simply mixing the leaf powders with KHCO 3 and subsequent carbonisation. Porous carbon nanosheets with a high specific surface area of 2133 m 2  g -1 were obtained and applied as electrode materials for supercapacitors and lithium ion batteries. For supercapacitor applications, the porous carbon nanosheet electrode exhibited a supercapacitance of 372 F g -1 at a current density of 500 mA g -1 in 1 m H 2 SO 4 aqueous electrolyte and excellent cycling stability over 15 000 cycles. In organic electrolyte, the nanosheet electrode showed a specific capacitance of 71 F g -1 at a current density of 2 Ag -1 and stable cycling performance. When applied as the anode material for lithium ion batteries, the as-prepared porous carbon nanosheets also demonstrated a high specific capacity of 819 mA h g -1 at a current density of 100 mA g -1 , good rate capability, and stable cycling performance. The outstanding electrochemical performances for both supercapacitors and lithium ion batteries are derived from the large specific surface area, porous nanosheet structure and nitrogen doping effects. The strategy developed in this paper provides a novel route to utilise biomass-derived materials for low-cost energy storage systems. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Sorption of uranyl ions from various acido systems by amphoteric epoxy amine ion-exchange resins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rychkov, V.N.; Radionov, B.K.; Molochnikov, L.S.

1995-03-01

Sorption of uranyl ions by epoxy amine ampholytes with N-monomethylenephosphonic acid groups modified with pyridine or quaternary ammonium groups was studied under dynamic conditions. Heterocyclic nitrogen favors sorption of uranyl ion from fluoride, sulfate, and fluoride-sulfate solutions. The ESR studies of mono- and bimetallic forms of nitrogen-containing ampholytes with copper(II) as paramagnetic marker revealed the characteristics of uranium(VI) interaction with cation- and anion-exchange groups and its dependence on the fluoride content in solution.

Measurement of the scintillation time spectra and pulse-shape discrimination of low-energy β and nuclear recoils in liquid argon with DEAP-1

NASA Astrophysics Data System (ADS)

Amaudruz, P.-A.; Batygov, M.; Beltran, B.; Bonatt, J.; Boudjemline, K.; Boulay, M. G.; Broerman, B.; Bueno, J. F.; Butcher, A.; Cai, B.; Caldwell, T.; Chen, M.; Chouinard, R.; Cleveland, B. T.; Cranshaw, D.; Dering, K.; Duncan, F.; Fatemighomi, N.; Ford, R.; Gagnon, R.; Giampa, P.; Giuliani, F.; Gold, M.; Golovko, V. V.; Gorel, P.; Grace, E.; Graham, K.; Grant, D. R.; Hakobyan, R.; Hallin, A. L.; Hamstra, M.; Harvey, P.; Hearns, C.; Hofgartner, J.; Jillings, C. J.; Kuźniak, M.; Lawson, I.; La Zia, F.; Li, O.; Lidgard, J. J.; Liimatainen, P.; Lippincott, W. H.; Mathew, R.; McDonald, A. B.; McElroy, T.; McFarlane, K.; McKinsey, D. N.; Mehdiyev, R.; Monroe, J.; Muir, A.; Nantais, C.; Nicolics, K.; Nikkel, J.; Noble, A. J.; O'Dwyer, E.; Olsen, K.; Ouellet, C.; Pasuthip, P.; Peeters, S. J. M.; Pollmann, T.; Rau, W.; Retière, F.; Ronquest, M.; Seeburn, N.; Skensved, P.; Smith, B.; Sonley, T.; Tang, J.; Vázquez-Jáuregui, E.; Veloce, L.; Walding, J.; Ward, M.

2016-12-01

The DEAP-1 low-background liquid argon detector was used to measure scintillation pulse shapes of electron and nuclear recoil events and to demonstrate the feasibility of pulse-shape discrimination down to an electron-equivalent energy of 20 keVee. In the surface dataset using a triple-coincidence tag we found the fraction of β events that are misidentified as nuclear recoils to be < 1.4 ×10-7 (90% C.L.) for energies between 43-86 keVee and for a nuclear recoil acceptance of at least 90%, with 4% systematic uncertainty on the absolute energy scale. The discrimination measurement on surface was limited by nuclear recoils induced by cosmic-ray generated neutrons. This was improved by moving the detector to the SNOLAB underground laboratory, where the reduced background rate allowed the same measurement to be done with only a double-coincidence tag. The combined data set contains 1.23 × 108 events. One of those, in the underground data set, is in the nuclear-recoil region of interest. Taking into account the expected background of 0.48 events coming from random pileup, the resulting upper limit on the level of electronic recoil contamination is < 2.7 ×10-8 (90% C.L.) between 44-89 keVee and for a nuclear recoil acceptance of at least 90%, with 6% systematic uncertainty on the absolute energy scale. We developed a general mathematical framework to describe pulse-shape-discrimination parameter distributions and used it to build an analytical model of the distributions observed in DEAP-1. Using this model, we project a misidentification fraction of approximately 10-10 for an electron-equivalent energy threshold of 15 keVee for a detector with 8 PE/keVee light yield. This reduction enables a search for spin-independent scattering of WIMPs from 1000 kg of liquid argon with a WIMP-nucleon cross-section sensitivity of 10-46 cm2, assuming negligible contribution from nuclear recoil backgrounds.

ZIF-8 Derived, Nitrogen-Doped Porous Electrodes of Carbon Polyhedron Particles for High-Performance Electrosorption of Salt Ions.

PubMed

Liu, Nei-Ling; Dutta, Saikat; Salunkhe, Rahul R; Ahamad, Tansir; Alshehri, Saad M; Yamauchi, Yusuke; Hou, Chia-Hung; Wu, Kevin C-W

2016-07-12

Three-dimensional (3-D) ZIF-8 derived carbon polyhedrons with high nitrogen (N) content, (denoted as NC-800) are synthesized for their application as high-performance electrodes in electrosorption of salt ions. The results showed a high specific capacitance of 160.8 F·g(-1) in 1 M NaCl at a scan rate of 5 mV·s(-1). Notably, integration of 3-D mesopores and micropores in NC-800 achieves an excellent capacitive deionization (CDI) performance. The electrosorption of salt ions at the electrical double layer is enhanced by N-doping at the edges of a hexagonal lattice of NC-800. As evidenced, when the initial NaCl solution concentration is 1 mM, the resultant NC-800 exhibits a remarkable CDI potential with a promising salt electrosorption capacity of 8.52 mg·g(-1).

Isolated boron and nitrogen sites on porous graphitic carbon synthesized from nitrogen-containing chitosan for supercapacitors.

PubMed

Sun, Li; Fu, Yu; Tian, Chungui; Yang, Ying; Wang, Lei; Yin, Jie; Ma, Jing; Wang, Ruihong; Fu, Honggang

2014-06-01

Separated boron and nitrogen porous graphitic carbon (BNGC) is fabricated by a facile hydrothermal coordination/ZnCl2-activation process from renewable and inexpensive nitrogen-containing chitosan. In this synthetic pathway, chitosan, which has a high nitrogen content, first coordinates with Fe(3+) ions to form chitosan-Fe that subsequently reacts with boric acid (boron source) to generate the BNGC precursor. After simultaneous carbonization and ZnCl2 activation followed by removal of the Fe catalyst, BNGC, containing isolated boron and nitrogen centers and having a high surface area of 1567 m(2)  g(-1) and good conductivity, can be obtained. Results indicate that use of chitosan as a nitrogen-containing carbon source effectively prevents nitrogen atoms from direct combination with boron atoms. In addition, the incorporation of Fe(3+) ions not only endows BNGC with high graphitization, but also favors for nitrogen fixation. Remarkably, the unique microstructure of BNGC enables its use as an advanced electrode material for energy storage. As electrode material for supercapacitors, BNGC shows a high capacitance of 313 F g(-1) at 1 A g(-1), and also long-term durability and coulombic efficiency of >99.5 % after 5000 cycles. Notably, in organic electrolytes, the energy density could be up to 50.1 Wh kg(-1) at a power density of 10.5 kW kg(-1). The strategy developed herein opens a new avenue to prepare BNGC without inactive BN bonds from commercially available chitosan for high-performance supercapacitors. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Molecular modeling of the effects of 40Ar recoil in illite particles on their K-Ar isotope dating

NASA Astrophysics Data System (ADS)

Szczerba, Marek; Derkowski, Arkadiusz; Kalinichev, Andrey G.; Środoń, Jan

2015-06-01

The radioactive decay of 40K to 40Ar is the basis of isotope age determination of micaceous clay minerals formed during diagenesis. The difference in K-Ar ages between fine and coarse grained illite particles has been interpreted using detrital-authigenic components system, its crystallization history or post-crystallization diffusion. Yet another mechanism should also be considered: natural 40Ar recoil. Whether this recoil mechanism can result in a significant enough loss of 40Ar to provide observable decrease of K-Ar age of the finest illite crystallites at diagenetic temperatures - is the primary objective of this study which is based on molecular dynamics (MD) computer simulations. All the simulations were performed for the same kinetic energy (initial velocity) of the 40Ar atom, but for varying recoil angles that cover the entire range of their possible values. The results show that 40Ar recoil can lead to various deformations of the illite structure, often accompanied by the displacement of OH groups or breaking of the Si-O bonds. Depending on the recoil angle, there are four possible final positions of the 40Ar atom with respect to the 2:1 layer at the end of the simulation: it can remain in the interlayer space or end up in the closest tetrahedral, octahedral or the opposite tetrahedral sheet. No simulation angles were found for which the 40Ar atom after recoil passes completely through the 2:1 layer. The energy barrier for 40Ar passing through the hexagonal cavity from the tetrahedral sheet into the interlayer was calculated to be 17 kcal/mol. This reaction is strongly exothermic, therefore there is almost no possibility for 40Ar to remain in the tetrahedral sheet of the 2:1 layer over geological time periods. It will either leave the crystal, if close enough to the edge, or return to the interlayer space. On the other hand, if 40Ar ends up in the octahedral sheet after recoil, a substantially higher energy barrier of 55 kcal/mol prevents it from leaving

Production and characterization of a nitrogen-implanted Fe standard to calibrate PIGE measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rodrigues, C. L.; Silva, T. F.; Added, N.

2014-11-11

Three calibration standard was produced by ion implantation of nitrogen in samples of Armco iron (99.7% iron). The samples was irradiated with nitrogen ion beams at several different energies (between 4 keV and 40 keV), and the ion doses were adjusted to obtain an uniform depth profile, using simulations with SRIM code. Two standards, one thick and other a foil (1.62mg/cm{sup 2}), was irradiated at same time with total nominal dose of 6.6×10{sup −16} atoms/cm{sup 2} distributed in a region of 100 nm in depth, with an average concentration of 9.0% nitrogen in iron. The third sample uses the samemore » profile, but with a small dose, 1.1×10{sup −16} atoms/cm{sup 2} and average concentration of 1.5% nitrogen. The characterization of the implanted samples was done using RBS and NRA techniques to quantification of nitrogen.« less

The multistate impact parameter method for molecular charge exchange in nitrogen

NASA Technical Reports Server (NTRS)

Ioup, J. W.

1980-01-01

The multistate impact parameter method is applied to the calculation of total cross sections for low energy change transfer between nitrogen ions and nitrogen molecules. Experimental data showing the relationships between total cross section and ion energy for various pressures and electron ionization energies were obtained. Calculated and experimental cross section values from the work are compared with the experimental and theoretical results of other investigators.

The recoil implantation technique developed at the U-120 cyclotron in Bucharest

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muntele, C. I.; Simil, L. Popa; Racolta, P. M.

1999-06-10

At the U-120 cyclotron in Bucharest was developed 15 years ago the thin layer activation (TLA) technique for radioactive labeling of metallic components on depths ranging between 100 {mu}m and 300 {mu}m, for wear/corrosion studies. Aiming to extend these kinds of studies on non-metallic components and at sub-micrometric level we were led to the development of the recoil implantation technique for ultra thin layer activation (UTLA) applications. Due to the low energy of the recoils obtained in a sacrificial target from a nuclear reaction, the surface layer of material to be labeled must be as thick as a few hundredmore » nanometers. Also, since the radiotracer is externally created, there are no restrictions for the kind of material to be labeled, except to be a solid. In this paper we present some results of our studies concerning the actual status of this application at our accelerator.« less

Development of Simultaneous in situ Analysis of Carbon and Nitrogen Isotope Ratios in the Organic Matter by Secondary Ion Mass Spectrometry

NASA Astrophysics Data System (ADS)

Ishida, A.; Kitajima, K.; Williford, K. H.; Kakegawa, T.; Valley, J. W.

2017-12-01

An in-situ analytical method for simultaneous analysis of carbon and nitrogen isotope ratios in organic matter was developed for 12 μm spots by secondary ion mass spectrometry (IMS 1280 at WiscSIMS). Secondary ions of 12C12C-, 12C13C-, 12C14N-, and 12C15N- are simultaneously measured by three Faraday cups and one electron multiplier. Ions of 12C12CH- are measured to monitor hydride interferences. The spot-by-spot reproducibility of δ13C and δ15N values of UWLA-1 anthracite standard (95.7 wt%C and 1.2 wt%N), which was selected as a running reference material, are 0.16‰ and 0.56‰ (2SD), respectively. A negative correlation is observed between the instrumental mass fractionation (mass bias) of carbon and 12C12CH-/12C12C- ratios of examined reference materials. In contrast, there is no correlation of mass bias and hydride cps for nitrogen isotope measurements, suggesting the mass bias of nitrogen can be determined independently of the hydrogen. Values of 22 individual globules of organic matter in a carbonate rock from the 1.9 Ga Gunflint Formation, determined by the new procedure, average δ13C = -33.5 ± 0.25‰ (VPDB) and δ15N = +5.2 ± 0.81‰ (Air). Values of δ13C of both SIMS and bulk kerogen analyses are consistent within analytical error. In contrast, a difference of 1.7‰, which is larger than the 2SD error of each analysis, is observed in δ15N values for in situ vs. bulk kerogen analyses (δ15Nbulk = +6.9 ± 0.6‰). This difference in δ15N might be caused by the preferential removal of low-δ15N components in the organic matter by HCl/HF acid treatment during the bulk kerogen isolation. Simultaneous analyses of carbon and nitrogen in the same micro-volume of organic matter in Precambrian sedimentary rocks will allow correlations with textures and mineralogical occurrences, which will provide more detailed constraints on environments and life of the early Earth. Furthermore, this method is applicable to a wide variety of other research fields

Design of SECAR a recoil mass separator for astrophysical capture reactions with radioactive beams

NASA Astrophysics Data System (ADS)

Berg, G. P. A.; Couder, M.; Moran, M. T.; Smith, K.; Wiescher, M.; Schatz, H.; Hager, U.; Wrede, C.; Montes, F.; Perdikakis, G.; Wu, X.; Zeller, A.; Smith, M. S.; Bardayan, D. W.; Chipps, K. A.; Pain, S. D.; Blackmon, J.; Greife, U.; Rehm, K. E.; Janssens, R. V. F.

2018-01-01

A recoil mass separator SECAR has been designed for the purpose of studying low-energy (p , γ) and (α , γ) reactions in inverse kinematics with radioactive beams for masses up to about A = 65. Their reaction rates are of importance for our understanding of the energy production and nucleosynthesis during explosive hydrogen and helium burning. The radiative capture reactions take place in a windowless hydrogen or He gas target at the entrance of the separator, which consists of four Sections. The first Section selects the charge state of the recoils. The second and third Sections contain Wien Filters providing high mass resolving power to separate efficiently the intense beam from the few reaction products. In the following fourth Section, the reaction products are guided into a detector system capable of position, angle and time-of-flight measurements. In order to accept the complete kinematic cone of recoil particles including multiple scattering in the target in the center of mass energy range of 0.2 MeV to 3.0 MeV, the system must have a large polar angle acceptance of ± 25 mrad. This requires a careful minimization of higher order aberrations. The present system will be installed at the NSCL ReA3 accelerator and will be used with the much higher beam intensities of the FRIB facility when it becomes available.

Design of SECAR a recoil mass separator for astrophysical capture reactions with radioactive beams

DOE PAGES

Berg, G. P. A.; Couder, M.; Moran, M. T.; ...

2017-09-25

A recoil mass separator SECAR has been designed for the purpose of studying low-energy (p,γ) and (α,γ) reactions in inverse kinematics with radioactive beams for masses up to about A = 65. Their reaction rates are of importance for our understanding of the energy production and nucleosynthesis during explosive hydrogen and helium burning. The radiative capture reactions take place in a windowless hydrogen or He gas target at the entrance of the separator, which consists of four Sections. The first Section selects the charge state of the recoils. The second and third Sections contain Wien Filters providing high mass resolvingmore » power to separate efficiently the intense beam from the few reaction products. In the following fourth Section, the reaction products are guided into a detector system capable of position, angle and time-of-flight measurements. In order to accept the complete kinematic cone of recoil particles including multiple scattering in the target in the center of mass energy range of 0.2 MeV to 3.0 MeV, the system must have a large polar angle acceptance of ± 25 mrad. This requires a careful minimization of higher order aberrations. Furthermore, the present system will be installed at the NSCL ReA3 accelerator and will be used with the much higher beam intensities of the FRIB facility when it becomes available.« less

Nitrogen-doped carbon coated MnO nanopeapods as superior anode materials for lithium ion batteries

NASA Astrophysics Data System (ADS)

Ding, Yu; Chen, Lihui; Pan, Pei; Du, Jun; Fu, Zhengbing; Qin, Caiqin; Wang, Feng

2017-11-01

High performance nitrogen-doped carbon (NC) materials decorated with MnO hybrid (MnO@NC) composites with a nanopeapod appearance were synthesized by with a simple hydrothermal method and insuit-polymeric route. As an anode material for lithium ion batteries (LIBs), the nanopeapod structure of MnO@NC composites with internal void spaces exhibits good rate capability, high conductivity and excellent cycling stability. After 200 cycles, the nanopeapod composites yield a specific capacity of 775.4 mAh g-1 at 100 mA g-1 and a high-rate capacity of 559.7 mAh g-1 at 1000 mA g-1. The proposed synthesis of nanopeapod structure composites with an internal room is an efficient design with excellent electrode materials for rechargeable LIBs.

Force-time profile differences in the delivery of simulated toggle-recoil spinal manipulation by students, instructors, and field doctors of chiropractic.

PubMed

DeVocht, James W; Owens, Edward F; Gudavalli, Maruti Ram; Strazewski, John; Bhogal, Ramneek; Xia, Ting

2013-01-01

The objectives of this study were to examine the force-time profiles of toggle recoil using an instrumented simulator to objectively measure and evaluate students' skill to determine if they become quicker and use less force during the course of their training and to compare them to course instructors and to field doctors of chiropractic (DCs) who use this specific technique in their practices. A load cell was placed within a toggle recoil training device. The preload, speed, and magnitude of the toggle recoil thrusts were measured from 60 students, 2 instructors, and 77 DCs (ie, who use the toggle recoil technique in their regular practice). Student data were collected 3 times during their toggle course (after first exposure, at midterm, and at course end.) Thrusts showed a dual-peak force-time profile not previously described in other forms of spinal manipulation. There was a wide range of values for each quantity measured within and between all 3 subject groups. The median peak load for students decreased over the course of their class, but they became slower. Field doctors were faster than students or instructors and delivered higher peak loads. Toggle recoil thrusts into a dropping mechanism varied based upon subject and amount of time practicing the task. As students progressed through the class, speed reduced as they increased control to lower peak loads. In the group studies, field DCs applied higher forces and were faster than both students and instructors. There appears to be a unique 2-peak feature of the force-time plot that is unique to toggle recoil manipulation with a drop mechanism. Copyright © 2013 National University of Health Sciences. Published by Mosby, Inc. All rights reserved.

ZIF-8 Derived, Nitrogen-Doped Porous Electrodes of Carbon Polyhedron Particles for High-Performance Electrosorption of Salt Ions

PubMed Central

Liu, Nei-Ling; Dutta, Saikat; Salunkhe, Rahul R.; Ahamad, Tansir; Alshehri, Saad M.; Yamauchi, Yusuke; Hou, Chia-Hung; Wu, Kevin C.-W.

2016-01-01

Three-dimensional (3-D) ZIF-8 derived carbon polyhedrons with high nitrogen (N) content, (denoted as NC-800) are synthesized for their application as high-performance electrodes in electrosorption of salt ions. The results showed a high specific capacitance of 160.8 F·g−1 in 1 M NaCl at a scan rate of 5 mV·s−1. Notably, integration of 3-D mesopores and micropores in NC-800 achieves an excellent capacitive deionization (CDI) performance. The electrosorption of salt ions at the electrical double layer is enhanced by N-doping at the edges of a hexagonal lattice of NC-800. As evidenced, when the initial NaCl solution concentration is 1 mM, the resultant NC-800 exhibits a remarkable CDI potential with a promising salt electrosorption capacity of 8.52 mg·g−1. PMID:27404086

Precision Lifetime Measurements Using the Recoil Distance Method

PubMed Central

Krücken, R.

2000-01-01

The recoil distance method (RDM) for the measurements of lifetimes of excited nuclear levels in the range from about 1 ps to 1000 ps is reviewed. The New Yale Plunger Device for RDM experiments is introduced and the Differential Decay Curve Method for their analysis is reviewed. Results from recent RDM experiments on SD bands in the mass-190 region, shears bands in the neutron deficient lead isotopes, and ground state bands in the mass-130 region are presented. Perspectives for the use of RDM measurements in the study of neutron-rich nuclei are discussed. PMID:27551587

First-excited state g factor of Te 136 by the recoil in vacuum method

DOE PAGES

Stuchbery, A. E.; Allmond, J. M.; Danchev, M.; ...

2017-07-27

The g factor of the first 2 + state of radioactive 136Te with two valence protons and two valence neutrons beyond double-magic 132Sn has been measured by the recoil in vacuum (RIV) method. The lifetime of this state is an order of magnitude longer than the lifetimes of excited states recently measured by the RIV method in Sn and Te isotopes, requiring a new evaluation of the free-ion hyperfine interactions and methodology used to determine the g factor. In this paper, the calibration data are reported and the analysis procedures are described in detail. The resultant g factor has amore » similar magnitude to the g factors of other nuclei with an equal number of valence protons and neutrons in the major shell. However, an unexpected trend is found in the g factors of the N = 84 isotones, which decrease from 136Te to 144Nd. Finally, shell model calculations with interactions derived from the CD Bonn potential show good agreement with the g factors and E2 transition rates of 2 + states around 132Sn, confirming earlier indications that 132Sn is a good doubly magic core.« less

First-excited state g factor of Te 136 by the recoil in vacuum method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stuchbery, A. E.; Allmond, J. M.; Danchev, M.

The g factor of the first 2 + state of radioactive 136Te with two valence protons and two valence neutrons beyond double-magic 132Sn has been measured by the recoil in vacuum (RIV) method. The lifetime of this state is an order of magnitude longer than the lifetimes of excited states recently measured by the RIV method in Sn and Te isotopes, requiring a new evaluation of the free-ion hyperfine interactions and methodology used to determine the g factor. In this paper, the calibration data are reported and the analysis procedures are described in detail. The resultant g factor has amore » similar magnitude to the g factors of other nuclei with an equal number of valence protons and neutrons in the major shell. However, an unexpected trend is found in the g factors of the N = 84 isotones, which decrease from 136Te to 144Nd. Finally, shell model calculations with interactions derived from the CD Bonn potential show good agreement with the g factors and E2 transition rates of 2 + states around 132Sn, confirming earlier indications that 132Sn is a good doubly magic core.« less

Nucleophilic addition of nitrogen to aryl cations: mimicking Titan chemistry.

PubMed

Li, Anyin; Jjunju, Fred P M; Cooks, R Graham

2013-11-01

The reactivity of aryl cations toward molecular nitrogen is studied systematically in an ion trap mass spectrometer at 10(2) Pascal of nitrogen, the pressure of the Titan main haze layer. Nucleophilic addition of dinitrogen occurs and the nature of aryl group has a significant influence on the reactivity, through inductive effects and by changing the ground state spin multiplicity. The products of nitrogen activation, aryldiazonium ions, react with typical nitriles, aromatic amines, and alkynes (compounds that are relevant as possible Titan atmosphere constituents) to form covalently bonded heterocyclic products. Theoretical calculations at the level [DFT(B3LYP)/6-311++G(d,p)] indicate that the N2 addition reaction is exothermic for the singlet aryl cations but endothermic for their triplet spin isomers. The -OH and -NH2 substituted aryl ions are calculated to have triplet ground states, which is consistent with their decreased nitrogen addition reactivity. The energy needed for the generation of the aryl cations from their protonated precursors (ca. 340 kJ/mol starting with protonated aniline) is far less than that required to directly activate the nitrogen triple bond (the lowest energy excited state of N2 lies ca. 600 kJ/mol above the ground state). The formation of aza-aromatics via arene ionization and subsequent reactions provide a conceivable route to the genesis of nitrogen-containing organic molecules in the interstellar medium and Titan haze layers.

The production and escape of nitrogen atoms on Mars

NASA Technical Reports Server (NTRS)

Fox, J. L.

1992-01-01

The lack of agreement between our previously computed values and those measured by Viking of the N-15:N-14 isotope enhancement ratio has led us to reevaluate our model of the Martian ionosphere. In previous models, we were unable to reproduce the ion profiles measured by the RPA on Viking using electron temperatures that were higher that the ion temperatures. When we increased the electron temperatures to 2500-3000 K and with a zero flux upper boundary condition, the ion densities at high altitudes exceeded the measured values by a large factor. We found that we can better fit the observed profiles if we impose a loss process at the upper boundary of our model. If the horizontal fluxes of ions do not constitute a net loss of ions, then the escape of N due to dissociative recombination is also inhibited and better agreement with the measured isotope ratio is found. The production of escaping nitrogen atoms is closely related to the production of thermospheric odd nitrogen; therefore, the densities of NO measured by Viking provide a convenient check on our nitrogen escape model. Our standard model NO densities are less that the measured values by a factor of 2-3, as are those of previous models. We find that reasonable agreement can be obtained by assuming that the rate coefficient for loss of odd nitrogen in the reaction of N with NO is smaller at temperatures that prevail in the lower Martian thermosphere than the standard value, which applies to temperatures of 200-400 K. Other aspects of this investigation are presented.

Nitrogen-Doped Holey Graphene as an Anode for Lithium-Ion Batteries with High Volumetric Energy Density and Long Cycle Life.

PubMed

Xu, Jiantie; Lin, Yi; Connell, John W; Dai, Liming

2015-12-01

Nitrogen-doped holey graphene (N-hG) as an anode material for lithium-ion batteries has delivered a maximum volumetric capacity of 384 mAh cm(-3) with an excellent long-term cycling life up to 6000 cycles, and as an electrochemical capacitor has delivered a maximum volumetric energy density of 171.2 Wh L(-1) and a volumetric capacitance of 201.6 F cm(-3) . © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High-performance tin oxide-nitrogen doped graphene aerogel hybrids as anode materials for lithium-ion batteries

NASA Astrophysics Data System (ADS)

Tan, Chunhui; Cao, Jing; Khattak, Abdul Muqsit; Cai, Feipeng; Jiang, Bo; Yang, Gai; Hu, Suqin

2014-12-01

Tin dioxide nanoparticles on nitrogen doped graphene aerogel (SnO2-NGA) hybrid are synthesized by one-step hydrothermal method and successfully applied in lithium-ion batteries as a free-standing anode. The electrochemical performance of SnO2-NGA hybrid is investigated by galvanostatic charge-discharge cycling, rate capability test, cyclic voltammetry and electrochemical impedance spectroscopy. It is found that the SnO2-NGA hybrid with freestanding spongy-like structure exhibit remarkable lithium storage capacity (1100 mAh g-1 after 100 cycles), good cycling stability and high rate capability. The outstanding performance is attributed to the uniform SnO2 nanoparticles, unique spongy-like structure and N doping defect for Li+ diffusion.

EMMA, a Recoil Mass Spectrometer for TRIUMF's ISAC-II Facility

NASA Astrophysics Data System (ADS)

Davids, Barry; EMMA Collaboration

2016-09-01

EMMA is a recoil mass spectrometer for TRIUMF's ISAC-II facility in the final stages of installation and commissioning. In this talk I will briefly review the spectrometer's design capabilities, describe recent progress in its installation and commissioning, and discuss plans for its initial experimental program. This work was supported by the Natural Sciences and Engineering Council of Canada. TRIUMF receives federal funds through a contribution agreement with the National Research Council of Canada.

Structural properties of nitrogenated amorphous carbon films: Influence of deposition temperature and radiofrequency discharge power

NASA Astrophysics Data System (ADS)

Lazar, G.; Bouchet-Fabre, B.; Zellama, K.; Clin, M.; Ballutaud, D.; Godet, C.

2008-10-01

The structural properties of nitrogenated amorphous carbon deposited by radiofrequency magnetron sputtering of graphite in pure N2 plasma are investigated as a function of the substrate temperature and radiofrequency discharge power. The film composition is derived from x-ray photoemission spectroscopy, nuclear reaction analysis and elastic recoil detection measurements and the film microstructure is discussed using infrared, Raman, x-ray photoemission and near edge x-ray absorption fine structure spectroscopic results. At low deposition temperature and low radiofrequency power, the films are soft, porous, and easily contaminated with water vapor and other atmospheric components. The concentration of nitrogen in the films is very large for low deposition temperatures (˜33.6at.% N at 150°C) but decreases strongly when the synthesis temperature increases (˜15at.% N at 450°C). With increasing deposition temperature and discharge power values, the main observed effects in amorphous carbon nitride alloys are a loss of nitrogen atoms, a smaller hydrogen and oxygen contamination related to the film densification, an increased order of the aromatic sp2 phase, and a strong change in the nitrogen distribution within the carbon matrix. Structural changes are well correlated with modifications of the optical and transport properties.

Mutation-Screening of Pleurotus Ferulae with High Temperature Tolerance by Nitrogen Ion Implantation

NASA Astrophysics Data System (ADS)

Chen, Henglei; Wan, Honggui; Zhang, Jun; Zeng, Xianxian

2008-08-01

In order to obtain Pleurotus ferulae with high temperature tolerance, conidiophores of wild type strain ACK were implanted with nitrogen ions in energy of 5 ~15 keV and dose of 1.5 × 1015 ~ 1.5 × 1016 cm-2, and a mutant CGMCC1763 was isolated subsequently through thermotolerant screening method. It was found that during riper period the surface layer mycelium of the mutant in mushroom bag wasn't aging neither grew tegument even above 30° C. The mycelium endurable temperature of the mutant was increased by 5°C compared to that of the wild type strain. The fruiting bodies growth temperature of the mutant was 18 ~22°C in daytime and 8~14°C at night. The highest growth temperature of fruiting bodies of the mutant was increased about 7°C w.r.t. that of original strain. Through three generations investigations, it was found that the mutant CGMCC1763 was stable with high temperature tolerance.

Nitrogen reactive ion etch processes for the selective removal of poly-(4-vinylpyridine) in block copolymer films.

PubMed

Flynn, Shauna P; Bogan, Justin; Lundy, Ross; Khalafalla, Khalafalla E; Shaw, Matthew; Rodriguez, Brian J; Swift, Paul; Daniels, Stephen; O'Connor, Robert; Hughes, Greg; Kelleher, Susan M

2018-08-31

Self-assembling block copolymer (BCP) patterns are one of the main contenders for the fabrication of nanopattern templates in next generation lithography technology. Transforming these templates to hard mark materials is key for pattern transfer and in some cases, involves selectively removing one block from the nanopattern. For poly(styrene)-block-poly(4-vinylpyridine) (PS-b-P4VP), a high χ BCP system which could be potentially incorporated into semiconductor nanofabrication, this selective removal is predominantly done by a wet etch/activation process. Conversely, this process has numerous disadvantages including lack of control and high generation of waste leading to high cost. For these reasons, our motivation was to move away from the wet etch process and optimise a dry etch which would overcome the limitations associated with the activation process. The work presented herein shows the development of a selective plasma etch process for the removal of P4VP cores from PS-b-P4VP nanopatterned film. Results have shown that a nitrogen reactive ion etch plasma has a selectivity for P4VP of 2.2:1 and suggest that the position of the nitrogen in the aromatic ring of P4VP plays a key role in this selectivity. In situ plasma etching and x-ray photoelectron spectrometry measurements were made without breaking vacuum, confirming that the nitrogen plasma has selectivity for removal of P4VP over PS.

Paul Trapping of Radioactive {sup 6}He{sup +} Ions and Direct Observation of Their {beta} Decay

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flechard, X.; Lienard, E.; Mery, A.

2008-11-21

We demonstrate that abundant quantities of short-lived {beta} unstable ions can be trapped in a novel transparent Paul trap and that their decay products can directly be detected in coincidence. Low energy {sup 6}He{sup +} (807 ms half-life) ions were extracted from the SPIRAL source at GANIL, then decelerated, cooled, and bunched by means of the buffer gas cooling technique. More than 10{sup 8} ions have been stored over a measuring period of six days, and about 10{sup 5} decay coincidences between the beta particles and the {sup 6}Li{sup ++} recoiling ions have been recorded. The technique can be extendedmore » to other short-lived species, opening new possibilities for trap assisted decay experiments.« less

Compositional analysis of ultrananocrystalline diamond (UNCD) films using ion beam scattering

NASA Astrophysics Data System (ADS)

AlFaify, S.; Garratt, E.; Nandasiri, M. I.; Kayani, A.; Sumant, A. V.; Mancini, D. C.

2009-11-01

Determination of the elemental composition is important to correlate the electrical and the optical properties of ultrananocrystalline diamond (UNCD) films, doped with and without nitrogen. To obtain the complete picture of impurities in the UNCD thin films, Rutherford backscattering spectroscopy (RBS), Non-Rutherford backscattering spectroscopy (NRBS), Elastic recoil detection analysis (ERDA) and nuclear reaction analysis (NRA) were performed on UNCD films on Si substrate and on free standing films. Helium beam was used for RBS and ERDA and protons were used for NRBS measurements. Exploiting the nuclear reaction of deuterons with C, O and N, 1.1 MeV D+ beam was used to quantitatively measure the concentration of these elements. Our results show that UNCD films contain less than 3% of Hydrogen while Nitrogen content incorporated in the film was estimated to be lower than 1%. The intermixing region between the substrate and the film was found to be negligible.

Incorporation of a Variable Discharge Coefficient for the Primary Orifice into the Benet Labs Recoil Analysis Model via Results from Quasi-Steady State Simulations Using Computational Fluid Dynamics

DTIC Science & Technology

2008-03-01

Appendix 82 MatLab© Cd Calculator Routine FORTRAN© Subroutine of the Variable Cd Model ii ABBREVIATIONS & ACRONYMS Cd...Figure 29. Overview Flowchart of Benét Labs Recoil Analysis Code Figure 30. Overview Flowchart of Recoil Brake Subroutine Figure 31...Detail Flowchart of Recoil Pressure/Force Calculations Figure 32. Detail Flowchart of Variable Cd Subroutine Figure 33. Simulated Brake

The influence of Na+ and Ca2+ on the migration of colloids or/and ammonia nitrogen in an unsaturated zone medium.

PubMed

Li, HaiMing; Wei, JinBu; Ge, YaChao; Wang, ZhanQuan; Wang, Ye; Li, YingLong

2016-11-01

This experiment was conducted with an indoor sand-column device, the migration of colloids with the presence of Na + and Ca 2+ and the migration of ammonia nitrogen with the presence of Na + , Ca 2+ or/and colloids was studied. The results showed that the migration of colloids was influenced by the ion valence state, different ions with different valence could block the migration of colloids. In addition, the blocking effect of bivalent ions was more obvious than that of monovalent ions. In the presence of Na + and Ca 2+ , the R d value of the ammonia-nitrogen migration process were 1.01 and 1.41, respectively, which indicated that bivalent ions have a greater blocking effect on ammonia-nitrogen migration than monovalent ions. Colloids could also block the ammonia-nitrogen migration, and R d value in the ammonia-nitrogen migration process was 1.17. Moreover, the presence of Na + /colloids and Ca 2+ /colloids could enhance the blocking effect on the ammonia-nitrogen migration, and resulting the R d values at 1.20 and 1.52, respectively. The cohesion of colloids caused by the compaction of its electric double layer with those ions added maybe the key causes of those blocking. Copyright © 2016 Elsevier B.V. All rights reserved.

Cyclic variations in nitrogen uptake rate of soybean plants: ammonium as a nitrogen source

NASA Technical Reports Server (NTRS)

Henry, L. T.; Raper, C. D. Jr

1989-01-01

When NO3- is the sole nitrogen source in flowing solution culture, the net rate of nitrogen uptake by nonnodulated soybean (Glycine max L. Merr. cv Ransom) plants cycles between maxima and minima with a periodicity of oscillation that corresponds with the interval of leaf emergence. Since soybean plants accumulate similar quantities of nitrogen when either NH4+ or NO3- is the sole source in solution culture controlled at pH 6.0, an experiment was conducted to determine if the oscillations in net rate of nitrogen uptake also occur when NH4+ is the nitrogen source. During a 21-day period of vegetative development, net uptake of NH4+ was measured daily by ion chromatography as depletion of NH4+ from a replenished nutrient solution containing 1.0 millimolar NH4+. The net rate of NH4+ uptake oscillated with a periodicity that was similar to the interval of leaf emergence. Instances of negative net rates of uptake indicate that the transition between maxima and minima involved changes in influx and efflux components of net NH4+ uptake.

Molecular dynamics and dynamic Monte-Carlo simulation of irradiation damage with focused ion beams

NASA Astrophysics Data System (ADS)

Ohya, Kaoru

2017-03-01

The focused ion beam (FIB) has become an important tool for micro- and nanostructuring of samples such as milling, deposition and imaging. However, this leads to damage of the surface on the nanometer scale from implanted projectile ions and recoiled material atoms. It is therefore important to investigate each kind of damage quantitatively. We present a dynamic Monte-Carlo (MC) simulation code to simulate the morphological and compositional changes of a multilayered sample under ion irradiation and a molecular dynamics (MD) simulation code to simulate dose-dependent changes in the backscattering-ion (BSI)/secondary-electron (SE) yields of a crystalline sample. Recent progress in the codes for research to simulate the surface morphology and Mo/Si layers intermixing in an EUV lithography mask irradiated with FIBs, and the crystalline orientation effect on BSI and SE yields relating to the channeling contrast in scanning ion microscopes, is also presented.

A new Recoil Proton Telescope for energy and fluence measurement of fast neutron fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lebreton, Lena; Bachaalany, Mario; Husson, Daniel

The spectrometer ATHENA (Accurate Telescope for High Energy Neutron metrology Applications), is being developed at the IRSN / LMDN (Institut de Radioprotection et de Surete nucleaire / Laboratoire de Metrologie et de dosimetrie des neutrons) and aims at characterizing energy and fluence of fast neutron fields. The detector is a Recoil Proton Telescope and measures neutron fields in the range of 5 to 20 MeV. This telescope is intended to become a primary standard for both energy and fluence measurements. The neutron detection is achieved by a polyethylene radiator for n-p conversion, three 50{sub m} thick silicon sensors that usemore » CMOS technology for the proton tracking and a 3 mm thick silicon diode to measure the residual proton energy. This first prototype used CMOS sensors called MIMOSTAR, initially developed for heavy ion physics. The use of CMOS sensors and silicon diode increases the intrinsic efficiency of the detector by a factor of ten compared with conventional designs. The first prototype has already been done and was a successful study giving the results it offered in terms of energy and fluence measurements. For mono energetic beams going from 5 to 19 MeV, the telescope offered an energy resolution between 5 and 11% and fluence difference going from 5 to 7% compared to other home standards. A second and final prototype of the detector is being designed. It will hold upgraded CMOS sensors called FastPixN. These CMOS sensors are supposed to run 400 times faster than the older version and therefore give the telescope the ability to support neutron flux in the order of 107 to 108cm{sup 2}:s{sup 1}. The first prototypes results showed that a 50 m pixel size is enough for a precise scattering angle reconstruction. Simulations using MCNPX and GEANT4 are already in place for further improvements. A DeltaE diode will replace the third CMOS sensor and will be installed right before the silicon diode for a better recoil proton selection. The final

A Negative Ion Cookbook

Science.gov Websites

Acknowledgements Introduction Negative Ion Source Operating Conditions & Procedures Cathode Ionization Potentials & Electron Affinities A Negative-Ion Cookbook Roy Middleton Department Of Physics 3Li Lithium 4Be Beryllium 5B Boron 6C Carbon 7N Nitrogen 8O Oxygen 9F Fluorine 10Ne Neon 11Na Sodium

Pulse-shape discrimination between electron and nuclear recoils in a NaI(Tl) crystal

NASA Astrophysics Data System (ADS)

Lee, H. S.; Adhikari, G.; Adhikari, P.; Choi, S.; Hahn, I. S.; Jeon, E. J.; Joo, H. W.; Kang, W. G.; Kim, G. B.; Kim, H. J.; Kim, H. O.; Kim, K. W.; Kim, N. Y.; Kim, S. K.; Kim, Y. D.; Kim, Y. H.; Lee, J. H.; Lee, M. H.; Leonard, D. S.; Li, J.; Oh, S. Y.; Olsen, S. L.; Park, H. K.; Park, H. S.; Park, K. S.; Shim, J. H.; So, J. H.

2015-08-01

We report on the response of a high light-output NaI(Tl) crystal to nuclear recoils induced by neutrons from an Am-Be source and compare the results with the response to electron recoils produced by Compton-scattered 662 keV γ-rays from a 137Cs source. The measured pulse-shape discrimination (PSD) power of the NaI(Tl) crystal is found to be significantly improved because of the high light output of the NaI(Tl) detector. We quantify the PSD power with a quality factor and estimate the sensitivity to the interaction rate for weakly interacting massive particles (WIMPs) with nucleons, and the result is compared with the annual modulation amplitude observed by the DAMA/LIBRA experiment. The sensitivity to spin-independent WIMP-nucleon interactions based on 100 kg·year of data from NaI detectors is estimated with simulated experiments, using the standard halo model.

Titan's atomic nitrogen torus - Inferred properties and consequences for the Saturnian aurora

NASA Astrophysics Data System (ADS)

Barbosa, D. D.

1987-10-01

This paper follows up the lead suggested by Barbosa and Eviatar (1986) that Titanogenic nitrogen ions are a key component of the magnetospheric particle populations and can account for the energetics of the Saturnian aurora without undue assumptions. Nitrogen atoms resulting from electron impact dissociations of N2 (Strobel and Shemansky 1982) escape from Titan and form a large doughnut-shaped ring around the satellite's orbit that is cospatial with the McDonough-Brice (1973) hydrogen cloud. Processes attendant to the ionization and pickup of nitrogen ions include the production of a warm kiloelectronvolt electron population and the excitation of the UV aurora by particle precipitation from the outer magnetosphere.

The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF)

DOE PAGES

Frenje, J. A.; Hilsabeck, T. J.; Wink, C. W.; ...

2016-08-02

The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (T i), yield (Y n), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate datamore » with a time resolution of ~20 ps and energy resolution of ~100 keV for total neutron yields above ~10 16. Lastly, at lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ~20 ps.« less

The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF).

PubMed

Frenje, J A; Hilsabeck, T J; Wink, C W; Bell, P; Bionta, R; Cerjan, C; Gatu Johnson, M; Kilkenny, J D; Li, C K; Séguin, F H; Petrasso, R D

2016-11-01

The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (T i ), yield (Y n ), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate data with a time resolution of ∼20 ps and energy resolution of ∼100 keV for total neutron yields above ∼10 16 . At lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ∼20 ps.

The magnetic recoil spectrometer (MRSt) for time-resolved measurements of the neutron spectrum at the National Ignition Facility (NIF)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frenje, J. A., E-mail: jfrenje@psfc.mit.edu; Wink, C. W.; Gatu Johnson, M.

The next-generation magnetic recoil spectrometer for time-resolved measurements of the neutron spectrum has been conceptually designed for the National Ignition Facility. This spectrometer, called MRSt, represents a paradigm shift in our thinking about neutron spectrometry for inertial confinement fusion applications, as it will provide simultaneously information about the burn history and time evolution of areal density (ρR), apparent ion temperature (T{sub i}), yield (Y{sub n}), and macroscopic flows during burn. From this type of data, an assessment of the evolution of the fuel assembly, hotspot, and alpha heating can be made. According to simulations, the MRSt will provide accurate datamore » with a time resolution of ∼20 ps and energy resolution of ∼100 keV for total neutron yields above ∼10{sup 16}. At lower yields, the diagnostic will be operated at a higher-efficiency, lower-energy-resolution mode to provide a time resolution of ∼20 ps.« less

Hydrogen analysis for granite using proton-proton elastic recoil coincidence spectrometry.

PubMed

Komatsubara, T; Sasa, K; Ohshima, H; Kimura, H; Tajima, Y; Takahashi, T; Ishii, S; Yamato, Y; Kurosawa, M

2008-07-01

In an effort to develop DS02, a new radiation dosimetry system for the atomic bomb survivors of Hiroshima and Nagasaki, measurements of neutron-induced activities have provided valuable information to reconstruct the radiation situation at the time of the bombings. In Hiroshima, the depth profile of (152)Eu activity measured in a granite pillar of the Motoyasu Bridge (128 m from the hypocenter) was compared with that calculated using the DS02 methodology. For calculation of the (152)Eu production due to the thermal-neutron activation reaction, (151)Eu(n,gamma)(152)Eu, information on the hydrogen content in granite is important because the transport and slowing-down process of neutrons penetrating into the pillar is strongly affected by collisions with the protons of hydrogen. In this study, proton-proton elastic recoil coincidence spectrometry has been used to deduce the proton density in the Motoyasu pillar granite. Slices of granite samples were irradiated by a 20 MeV proton beam, and the energies of scattered and recoil protons were measured with a coincidence method. The water concentration in the pillar granite was evaluated to be 0.30 +/- 0.07%wt. This result is consistent with earlier data on adsorptive water (II) and bound water obtained by the Karl Fisher method.

Electron emission and recoil effects following the beta decay of He6

NASA Astrophysics Data System (ADS)

Schulhoff, Eva E.; Drake, G. W. F.

2015-11-01

Probabilities for atomic electron excitation (shake-up) and ionization (shake-off) are studied following the beta-decay process →Li+6He6+e-+ν¯e , and in particular, recoil-induced contributions to the shake-off probability are calculated within the nonrelativistic sudden approximation. A pseudostate expansion method together with Stieltjes imaging is used to represent the complete two-electron spectrum of final Li+6 ,Li26+, and Li36+ states. Results for the recoil correction show a 7 σ disagreement with the experiment of Carlson et al. [Phys. Rev. 129, 2220 (1963), 10.1103/PhysRev.129.2220]. A variety of sum rules, including a newly derived Thomas-Reich-Kuhn oscillator strength sum rule for dipole recoil terms, provides tight constraints on the accuracy of the results. Calculations are performed for the helium 1 s 2 s 3S metastable state, as well as for the 1 s21S ground state. Our results would reduce the recoil-induced correction to the measured electroneutrino coupling constant ae μ from the apparent 0.6% used in the experiments to 0.09%.

Nitrogen-doped 3D flower-like carbon materials derived from polyimide as high-performance anode materials for lithium-ion batteries

NASA Astrophysics Data System (ADS)

Wu, Qiong; Liu, Jiaqi; Yuan, Chenpei; Li, Qiang; Wang, Heng-guo

2017-12-01

Nitrogen-doped 3D flower-like carbon materials (NFCs) have been fabricated using a simple and effective strategy, namely, the hierarchical assembly of polyimide (PI) and subsequent thermal treatment. The effect of pyrolysis temperature on the structural evolution process of PI is also investigated systematically. When evaluated as anode materials for lithium ion batteries (LIBs), the as-obtained NFCs, especially NFCs-550, exhibit good electrochemical performance, including a high reversible capacity (1488.1 mAh g-1 at 0.05 A g-1), excellent rate performance (287.6 mAh g-1 at 2 A g-1), and good cycling stability (645 mAh g-1 with 96% retention after 300 cycles at 0.1 A g-1). The good electrochemical performance is attributed to the synergistic effect between 3D flower-like nanostructure and high nitrogen content. This approach may provide some inspiration to construct a series of heteroatom doped and hierarchical structured carbon materials using polymers for LIBs.

Scattering of hydrogen, nitrogen and water ions from micro pore optic plates for application in spaceborne plasma instrumentation

NASA Astrophysics Data System (ADS)

Stude, Joan; Wieser, Martin; Barabash, Stas

2016-10-01

Time-of-flight mass spectrometers for upcoming space missions into enhanced radiation environments need to be small, light weight and energy efficient. Time-of-flight systems using surface interactions as start-event generation can be smaller than foil-type instruments. Start surfaces for such applications need to provide narrow angular scattering, high ionization yields and high secondary electron emissions to be effective. We measured the angular scattering, energy distribution and positive ionization yield of micro pore optics for incident hydrogen, nitrogen and water ions at 2 keV. Positive ionization yields of 2% for H+ , 0.5% for N+ and 0.2% for H2O+ were detected.

Monitoring Ion Track Formation Using In Situ RBS/c, ToF-ERDA, and HR-PIXE.

PubMed

Karlušić, Marko; Fazinić, Stjepko; Siketić, Zdravko; Tadić, Tonči; Cosic, Donny Domagoj; Božičević-Mihalić, Iva; Zamboni, Ivana; Jakšić, Milko; Schleberger, Marika

2017-09-06

The aim of this work is to investigate the feasibility of ion beam analysis techniques for monitoring swift heavy ion track formation. First, the use of the in situ Rutherford backscattering spectrometry in channeling mode to observe damage build-up in quartz SiO₂ after MeV heavy ion irradiation is demonstrated. Second, new results of the in situ grazing incidence time-of-flight elastic recoil detection analysis used for monitoring the surface elemental composition during ion tracks formation in various materials are presented. Ion tracks were found on SrTiO₃, quartz SiO₂, a-SiO₂, and muscovite mica surfaces by atomic force microscopy, but in contrast to our previous studies on GaN and TiO₂, surface stoichiometry remained unchanged. Third, the usability of high resolution particle induced X-ray spectroscopy for observation of electronic dynamics during early stages of ion track formation is shown.

Monitoring Ion Track Formation Using In Situ RBS/c, ToF-ERDA, and HR-PIXE

PubMed Central

Karlušić, Marko; Fazinić, Stjepko; Siketić, Zdravko; Tadić, Tonči; Cosic, Donny Domagoj; Božičević-Mihalić, Iva; Zamboni, Ivana; Jakšić, Milko; Schleberger, Marika

2017-01-01

The aim of this work is to investigate the feasibility of ion beam analysis techniques for monitoring swift heavy ion track formation. First, the use of the in situ Rutherford backscattering spectrometry in channeling mode to observe damage build-up in quartz SiO2 after MeV heavy ion irradiation is demonstrated. Second, new results of the in situ grazing incidence time-of-flight elastic recoil detection analysis used for monitoring the surface elemental composition during ion tracks formation in various materials are presented. Ion tracks were found on SrTiO3, quartz SiO2, a-SiO2, and muscovite mica surfaces by atomic force microscopy, but in contrast to our previous studies on GaN and TiO2, surface stoichiometry remained unchanged. Third, the usability of high resolution particle induced X-ray spectroscopy for observation of electronic dynamics during early stages of ion track formation is shown. PMID:28878186

Monte-Carlo Simulations of Heavy Ions Track Structures and Applications

NASA Technical Reports Server (NTRS)

Plante, Ianik; Cucinotta, Francia A.

2013-01-01

In space, astronauts are exposed to protons, high ]energy heavy (HZE) ions that have a high charge (Z) and energy (E), and secondary radiation, including neutrons and recoil nuclei produced by nuclear reactions in spacecraft walls or in tissue. The astronauts can only be partly shielded from these particles. Therefore, on travelling to Mars, it is estimated that every cell nucleus in an astronaut fs body would be hit by a proton or secondary electron (e.g., electrons of the target atoms ionized by the HZE ion) every few days and by an HZE ion about once a month. The risks related to these heavy ions are not well known and of concern for long duration space exploration missions. Medical ion therapy is another situation where human beings can be irradiated by heavy ions, usually to treat cancer. Heavy ions have a peculiar track structure characterized by high levels of energy ]deposition clustering, especially in near the track ends in the so ]called eBragg peak f region. In radiotherapy, these features of heavy ions can provide an improved dose conformation with respect to photons, also considering that the relative biological effectiveness (RBE) of therapeutic ions in the plateau region before the peak is sufficiently low. Therefore, several proton and carbon ion therapy facilities are under construction at this moment

Relationship between ion pair geometries and electrostatic strengths in proteins.

PubMed Central

Kumar, Sandeep; Nussinov, Ruth

2002-01-01

The electrostatic free energy contribution of an ion pair in a protein depends on two factors, geometrical orientation of the side-chain charged groups with respect to each other and the structural context of the ion pair in the protein. Conformers in NMR ensembles enable studies of the relationship between geometry and electrostatic strengths of ion pairs, because the protein structural contexts are highly similar across different conformers. We have studied this relationship using a dataset of 22 unique ion pairs in 14 NMR conformer ensembles for 11 nonhomologous proteins. In different NMR conformers, the ion pairs are classified as salt bridges, nitrogen-oxygen (N-O) bridges and longer-range ion pairs on the basis of geometrical criteria. In salt bridges, centroids of the side-chain charged groups and at least a pair of side-chain nitrogen and oxygen atoms of the ion-pairing residues are within a 4 A distance. In N-O bridges, at least a pair of the side-chain nitrogen and oxygen atoms of the ion-pairing residues are within 4 A distance, but the distance between the side-chain charged group centroids is greater than 4 A. In the longer-range ion pairs, the side-chain charged group centroids as well as the side-chain nitrogen and oxygen atoms are more than 4 A apart. Continuum electrostatic calculations indicate that most of the ion pairs have stabilizing electrostatic contributions when their side-chain charged group centroids are within 5 A distance. Hence, most (approximately 92%) of the salt bridges and a majority (68%) of the N-O bridges are stabilizing. Most (approximately 89%) of the destabilizing ion pairs are the longer-range ion pairs. In the NMR conformer ensembles, the electrostatic interaction between side-chain charged groups of the ion-pairing residues is the strongest for salt bridges, considerably weaker for N-O bridges, and the weakest for longer-range ion pairs. These results suggest empirical rules for stabilizing electrostatic interactions in

Near-Resonant Raman Amplification in the Rotational Quantum Wave Packets of Nitrogen Molecular Ions Generated by Strong Field Ionization

NASA Astrophysics Data System (ADS)

Liu, Zhaoxiang; Yao, Jinping; Chen, Jinming; Xu, Bo; Chu, Wei; Cheng, Ya

2018-02-01

The generation of laserlike narrow bandwidth emissions from nitrogen molecular ions (N2+ ) generated in intense near- and mid infrared femtosecond laser fields has aroused much interest because of the mysterious physics underlying such a phenomenon. Here, we perform a pump-probe measurement on the nonlinear interaction of rotational quantum wave packets of N2+ generated in midinfrared (e.g., at a wavelength centered at 1580 nm) femtosecond laser fields with an ultrashort probe pulse whose broad spectrum overlaps both P - and R -branch rotational transition lines between the electronic states N2+(B2Σu+,v'=0 ) and N2+(X2Σg+,v =0 ) . The results indicate the occurrence of highly efficient near-resonant stimulated Raman scattering in the quantum wave packets of N2+ ions generated in strong laser fields in the midinfrared region, of which the underlying mechanism is different from that of the air lasers generated in atmospheric environment when pumping with 800 nm intense pulses.

Electrochemical behavior and biological response of Mesenchymal Stem Cells on cp-Ti after N-ions implantation

NASA Astrophysics Data System (ADS)

Rizwan, M.; Ahmad, A.; Deen, K. M.; Haider, W.

2014-11-01

Titanium and its alloys are most widely used as implant materials due to their excellent biocompatibility, mechanical properties and chemical stability. In this study Nitrogen ions of known dosage were implanted over cp-Ti by Pelletron accelerator with beam energy of 0.25 MeV.The atomic force microscopy of bare and nitrogen implanted specimens confirmed increase in surface roughness with increase in nitrogen ions concentration. X-ray diffraction patterns of ions implanted surfaces validated the formation of TiN0.3 and Ti3N2-xnitride phases. The tendency to form passive film and electrochemical behavior of these surfaces in ringer lactate (RL) solution was evaluated by Potentiodynamic polarization and electrochemical impedance spectroscopy respectively. It is proved that nitrogen ions implantation was beneficial to reduce corrosion rate and stabilizing passive film by increasing charge transfer resistance in RL. It was concluded that morphology and proliferation of Mesenchymal Stem Cells on nitrogen ions implanted surfaces strongly depends on surface roughness and nitride phases.

XENON100 Dark Matter Search: Scintillation Response of Liquid Xenon to Electronic Recoils

NASA Astrophysics Data System (ADS)

Lim, Kyungeun Elizabeth

Dark matter is one of the missing pieces necessary to complete the puzzle of the universe. Numerous astrophysical observations at all scales suggest that 23 % of the universe is made of nonluminous, cold, collisionless, nonbaryonic, yet undiscovered dark matter. Weakly Interacting Massive Particles (WIMPs) are the most well-motivated dark matter candidates and significant efforts have been made to search for WIMPs. The XENON100 dark matter experiment is currently the most sensitive experiment in the global race for the first direct detection of WIMP dark matter. XENON100 is a dual-phase (liquid-gas) time projection chamber containing a total of 161 kg of liquid xenon (LXe) with a 62kg WIMP target mass. It has been built with radiopure materials to achieve an ultra-low electromagnetic background and operated at the Laboratori Nazionali del Gran Sasso in Italy. WIMPs are expected to scatter off xenon nuclei in the target volume. Simultaneous measurement of ionization and scintillation produced by nuclear recoils allows for the detection of WIMPs in XENON100. Data from the XENON100 experiment have resulted in the most stringent limits on the spin-independent elastic WIMP-nucleon scattering cross sections for most of the significant WIMP masses. As the experimental precision increases, a better understanding of the scintillation and ionization response of LXe to low energy (< 10 keV) particles is crucial for the interpretation of data from LXe based WIMP searches. A setup has been built and operated at Columbia University to measure the scintillation response of LXe to both electronic and nuclear recoils down to energies of a few keV, in particular for the XENON100 experiment. In this thesis, I present the research carried out in the context of the XENON100 dark matter search experiment. For the theoretical foundation of the XENON100 experiment, the first two chapters are dedicated to the motivation for and detection medium choice of the XENON100 experiment

Direct measurement of resonance strengths in 34S(α ,γ )38Ar at astrophysically relevant energies using the DRAGON recoil separator

NASA Astrophysics Data System (ADS)

Connolly, D.; O'Malley, P. D.; Akers, C.; Chen, A. A.; Christian, G.; Davids, B.; Erikson, L.; Fallis, J.; Fulton, B. R.; Greife, U.; Hager, U.; Hutcheon, D. A.; Ilyushkin, S.; Laird, A. M.; Mahl, A.; Ruiz, C.

2018-03-01

Background: Nucleosynthesis of mid-mass elements is thought to occur under hot and explosive astrophysical conditions. Radiative α capture on 34S has been shown to impact nucleosynthesis in several such conditions, including core and shell oxygen burning, explosive oxygen burning, and type Ia supernovae. Purpose: Broad uncertainties exist in the literature for the strengths of three resonances within the astrophysically relevant energy range (ECM=1.94 -3.42 MeV at T =2.2 GK ). Further, there are several states in 38Ar within this energy range which have not been previously measured. This work aimed to remeasure the resonance strengths of states for which broad uncertainty existed as well as to measure the resonance strengths and energies of previously unmeasured states. Methods: Resonance strengths and energies of eight narrow resonances (five of which had not been previously studied) were measured in inverse kinematics with the DRAGON facility at TRIUMF by impinging an isotopically pure beam of 34S ions on a windowless 4He gas target. Prompt γ emissions of de-exciting 38Ar recoils were detected in an array of bismuth germanate scintillators in coincidence with recoil nuclei, which were separated from unreacted beam ions by an electromagnetic mass separator and detected by a time-of-flight system and a multianode ionization chamber. Results: The present measurements agree with previous results. Broad uncertainty in the resonance strength of the ECM=2709 keV resonance persists. Resonance strengths and energies were determined for five low-energy resonances which had not been studied previously, and their strengths were determined to be significantly weaker than those of previously measured resonances. Conclusions: The five previously unmeasured resonances were found not to contribute significantly to the total thermonuclear reaction rate. A median total thermonuclear reaction rate calculated using data from the present work along with existing literature values

An experiment on the dynamics of ion implantation and sputtering of surfaces

NASA Astrophysics Data System (ADS)

Wright, G. M.; Barnard, H. A.; Kesler, L. A.; Peterson, E. E.; Stahle, P. W.; Sullivan, R. M.; Whyte, D. G.; Woller, K. B.

2014-02-01

A major impediment towards a better understanding of the complex plasma-surface interaction is the limited diagnostic access to the material surface while it is undergoing plasma exposure. The Dynamics of ION Implantation and Sputtering Of Surfaces (DIONISOS) experiment overcomes this limitation by uniquely combining powerful, non-perturbing ion beam analysis techniques with a steady-state helicon plasma exposure chamber, allowing for real-time, depth-resolved in situ measurements of material compositions during plasma exposure. Design solutions are described that provide compatibility between the ion beam analysis requirements in the presence of a high-intensity helicon plasma. The three primary ion beam analysis techniques, Rutherford backscattering spectroscopy, elastic recoil detection, and nuclear reaction analysis, are successfully implemented on targets during plasma exposure in DIONISOS. These techniques measure parameters of interest for plasma-material interactions such as erosion/deposition rates of materials and the concentration of plasma fuel species in the material surface.

An experiment on the dynamics of ion implantation and sputtering of surfaces.

PubMed

Wright, G M; Barnard, H A; Kesler, L A; Peterson, E E; Stahle, P W; Sullivan, R M; Whyte, D G; Woller, K B

2014-02-01

A major impediment towards a better understanding of the complex plasma-surface interaction is the limited diagnostic access to the material surface while it is undergoing plasma exposure. The Dynamics of ION Implantation and Sputtering Of Surfaces (DIONISOS) experiment overcomes this limitation by uniquely combining powerful, non-perturbing ion beam analysis techniques with a steady-state helicon plasma exposure chamber, allowing for real-time, depth-resolved in situ measurements of material compositions during plasma exposure. Design solutions are described that provide compatibility between the ion beam analysis requirements in the presence of a high-intensity helicon plasma. The three primary ion beam analysis techniques, Rutherford backscattering spectroscopy, elastic recoil detection, and nuclear reaction analysis, are successfully implemented on targets during plasma exposure in DIONISOS. These techniques measure parameters of interest for plasma-material interactions such as erosion/deposition rates of materials and the concentration of plasma fuel species in the material surface.

Nanoscale Nitrogen Doping in Silicon by Self-Assembled Monolayers

NASA Astrophysics Data System (ADS)

Guan, Bin; Siampour, Hamidreza; Fan, Zhao; Wang, Shun; Kong, Xiang Yang; Mesli, Abdelmadjid; Zhang, Jian; Dan, Yaping

2015-07-01

This Report presents a nitrogen-doping method by chemically forming self-assembled monolayers on silicon. Van der Pauw technique, secondary-ion mass spectroscopy and low temperature Hall effect measurements are employed to characterize the nitrogen dopants. The experimental data show that the diffusion coefficient of nitrogen dopants is 3.66 × 10-15 cm2 s-1, 2 orders magnitude lower than that of phosphorus dopants in silicon. It is found that less than 1% of nitrogen dopants exhibit electrical activity. The analysis of Hall effect data at low temperatures indicates that the donor energy level for nitrogen dopants is located at 189 meV below the conduction band, consistent with the literature value.

Ab initio molecular dynamics simulations of low energy recoil events in MgO

NASA Astrophysics Data System (ADS)

Petersen, B. A.; Liu, B.; Weber, W. J.; Zhang, Y.

2017-04-01

Low-energy recoil events in MgO are studied using ab intio molecular dynamics simulations to reveal the dynamic displacement processes and final defect configurations. Threshold displacement energies, Ed, are obtained for Mg and O along three low-index crystallographic directions, [100], [110], and [111]. The minimum values for Ed are found along the [110] direction consisting of the same element, either Mg or O atoms. Minimum threshold values of 29.5 eV for Mg and 25.5 eV for O, respectively, are suggested from the calculations. For other directions, the threshold energies are considerably higher, 65.5 and 150.0 eV for O along [111] and [100], and 122.5 eV for Mg along both [111] and [100] directions, respectively. These results show that the recoil events in MgO are partial-charge transfer assisted processes where the charge transfer plays an important role. There is a similar trend found in other oxide materials, where the threshold displacement energy correlates linearly with the peak partial-charge transfer, suggesting this behavior might be universal in ceramic oxides.

DEVELOPMENT OF A HIGH-EFFICIENCY PROTON RECOIL TELESCOPE FOR D-T NEUTRON FLUENCE MEASUREMENT.

PubMed

Tanimura, Y; Yoshizawa, M

2017-12-22

A high-efficiency proton recoil telescope was developed to determine neutron fluences in neutron fields using the 3H(d,n)4He reaction. A 2-mm thick plastic scintillation detector was employed as a radiator to increase the detection efficiency and compensate for the energy loss of the recoil proton within. Two silicon detectors were employed as the ΔE and E detectors. The distance between the radiator and the E detector was varied between 50 and 150 mm. The telescope had detection efficiencies of 3.5 × 10-3 and 7.1 × 10-4 cm2 for distances of 50 and 100 mm, respectively, which were high enough to determine the neutron fluence in 14.8-MeV neutron fields, with a few thousand cm-2 s-1 fluence rate, within a few hours. © The Author(s) 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Electrolytic Conductance of the Ternary System of Nitric Acid--Nitrogen Dioxide--Water at 32 deg F and Atmospheric Pressure

DTIC Science & Technology

1951-11-12

solutions of nitrogen dioxide in nitric acid where nitrosonium ions (NO+) and nitrate ions (NO-) have been identified (Cf. Ref. 4). The nitrogen...0.97 weight fraction nitric acid, hydrogen and nitrate ions are the predominant conducting species. In the range 0.97 to 1.00 weight fraction nitric...self-ionization to yield nitronium ions (NJ2) and nitratej2 ions (NO3) according to the expression 2HNO3--NO+ + NO- + H2 0 It is evident from this

Shoulder-Fired Weapons with High Recoil Energy: Quantifying Injury and Shooting Performance

DTIC Science & Technology

2004-05-01

USARIEM TECHNICAL REPORT T04-05 SHOULDER-FIRED WEAPONS WITH HIGH RECOIL ENERGY: QUANTIFYING INJURY AND SHOOTING PERFORMANCE...ACKNOWLEDGMENTS The authors would like to thank the following individuals for their assistance in preparing this technical report: Robert Mello... myofascial and other musculoskeletal pain is considered abnormal if the anatomical site is 2 kg/cm2 lower relative to a normal control point, such as

Microstructural evolution of ion-irradiated sol–gel-derived thin films

DOE PAGES

Shojaee, S. A.; Qi, Y.; Wang, Y. Q.; ...

2017-07-17

In this paper, the effects of ion irradiation on the microstructural evolution of sol–gel-derived silica-based thin films were examined by combining the results from Fourier transform infrared, Raman, and X-ray photoelectron spectroscopy, Rutherford backscattering spectrometry, and elastic recoil detection. Variations in the chemical composition, density, and structure of the constituent phases and interfaces were studied, and the results were used to propose a microstructural model for the irradiated films. It was discovered that the microstructure of the films after ion irradiation and decomposition of the starting organic materials consisted of isolated hydrogenated amorphous carbon clusters within an amorphous and carbon-incorporatedmore » silica network. A decrease in the bond angle of Si–O–Si bonds in amorphous silica network along with an increase in the concentration of carbon-rich SiO x C y tetrahedra were the major structural changes caused by ion irradiation. Finally, in addition, hydrogen release from free carbon clusters was observed with increasing ion energy and fluence.« less

The Darkside-50 Experiment: Electron Recoil Calibrations and a Global Energy Variable

NASA Astrophysics Data System (ADS)

Hackett, Brianne R.

Over the course of decades, there has been mounting astronomical evidence for non-baryonic dark matter, yet its precise nature remains elusive. A favored candidate for dark matter is the Weakly Interacting Massive Particle (WIMP) which arises naturally out of extensions to the Standard Model. WIMPs are expected to occasionally interact with particles of normal matter through nuclear recoils. DarkSide-50 aims to detect this type of particle through the use of a two-phase liquid argon time projection chamber. To make a claim of discovery, an accurate understanding of the background and WIMP search region is imperative. Knowledge of the backgrounds is done through extensive studies of DarkSide-50's response to electron and nuclear recoils. The CALibration Insertion System (CALIS) was designed and built for the purpose of introducing radioactive sources into or near the detector in a joint effort between Fermi National Laboratory (FNAL) and the University of Hawai'i at Manoa. This work describes the testing, installation, and commissioning of CALIS at the Laboratori Nazionali del Gran Sasso. CALIS has been used in multiple calibration campaigns with both neutron and gamma sources. In this work, DarkSide-50's response to electron recoils, which are important for background estimations, was studied through the use of gamma calibration sources by constructing a global energy variable which takes into account the anti-correlation between scintillation and ionization signals produced by interactions in the liquid argon. Accurately reconstructing the event energy correlates directly with quantitatively understanding the WIMP sensitivity in DarkSide-50. This work also validates the theoretically predicted beta decay spectrum of 39Ar against 39Ar beta decay data collected in the early days of DarkSide-50 while it was filled with atmospheric argon; a validation of this type is not readily found in the literature. Finally, we show how well the constructed energy variable can

A RUNAWAY BLACK HOLE IN COSMOS: GRAVITATIONAL WAVE OR SLINGSHOT RECOIL?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Civano, F.; Elvis, M.; Lanzuisi, G.

2010-07-01

We present a detailed study of a peculiar source detected in the COSMOS survey at z = 0.359. Source CXOC J100043.1+020637, also known as CID-42, has two compact optical sources embedded in the same galaxy. The distance between the two, measured in the HST/ACS image, is 0.''495 {+-} 0.''005 that, at the redshift of the source, corresponds to a projected separation of 2.46 {+-} 0.02 kpc. A large ({approx}1200 km s{sup -1}) velocity offset between the narrow and broad components of H{beta} has been measured in three different optical spectra from the VLT/VIMOS and Magellan/IMACS instruments. CID-42 is also themore » only X-ray source in COSMOS, having in its X-ray spectra a strong redshifted broad absorption iron line and an iron emission line, drawing an inverted P-Cygni profile. The Chandra and XMM-Newton data show that the absorption line is variable in energy by {Delta}E = 500 eV over four years and that the absorber has to be highly ionized in order not to leave a signature in the soft X-ray spectrum. That these features-the morphology, the velocity offset, and the inverted P-Cygni profile-occur in the same source is unlikely to be a coincidence. We envisage two possible explanations, both exceptional, for this system: (1) a gravitational wave (GW) recoiling black hole (BH), caught 1-10 Myr after merging; or (2) a Type 1/Type 2 system in the same galaxy where the Type 1 is recoiling due to the slingshot effect produced by a triple BH system. The first possibility gives us a candidate GW recoiling BH with both spectroscopic and imaging signatures. In the second case, the X-ray absorption line can be explained as a BAL-like outflow from the foreground nucleus (a Type 2 AGN) at the rearer one (a Type 1 AGN), which illuminates the otherwise undetectable wind, giving us the first opportunity to show that fast winds are present in obscured active galactic nuclei (AGNs), and possibly universal in AGNs.« less

Highly Charged Rydberg Ions from the Coulomb Explosion of Clusters

NASA Astrophysics Data System (ADS)

Komar, D.; Kazak, L.; Almassarani, M.; Meiwes-Broer, K.-H.; Tiggesbäumker, J.

2018-03-01

Ion emission from a nanoplasma produced in the interaction of intense optical laser pulses with argon clusters is studied resolving simultaneously charge states and recoil energies. By applying appropriate static electric fields we observe that a significant fraction of the ions Arq + (q =1 - 7 ) has electrons with binding energies lower than 150 meV; i.e., nRyd≥15 levels are populated. Charge state changes observed on a μ s time scale can be attributed to electron emission due to autoionizing Rydberg states, indicating that high-ℓ Rydberg levels are populated as well. The experiments support theoretical predictions that a significant fraction of delocalized electrons, which are bound with hundreds of eV to the nanoplasma after the laser exposure, fill up meV bound ion states in the adiabatic expansion. We expect the process to be relevant for the long-term evolution of expanding laser-induced dense plasmas in general.

Recoil distance lifetime measurements in82Kr

NASA Astrophysics Data System (ADS)

Brüssermann, S.; Keinonen, J.; Hellmeister, H. P.; Lieb, K. P.

1982-12-01

The lifetimes τ=124±12, 6{-2/+4} and 380±100 ps of the E x ( I π )=3.46(8+), 2.92(6+) and 3.04(6-) MeV states, respectively, populated by the reaction76Ge(12C, α2 n) were measured with the recoil distance method. In addition upper lifetime limits were obtained for nine states. The measured lifetimes and energies indicate a band crossing at about I π =8+, probably arising from the alignment of two g 9/2 neutrons. For the 3.04 MeV 6- state as a second member of a band built on the 2.65 MeV 4- state the measured lifetime points to a two-quasiparticle configuration. The positive-parity states have been discussed in the frame of the interacting boson approximation, nuclear field theory and the cranked shell model.

On the Q-dependence of the lowest-order QED corrections and other properties of the ground 11S-states in the two-electron ions

NASA Astrophysics Data System (ADS)

Frolov, Alexei M.

2015-10-01

Formulas and expectation values which are need to determine the lowest-order QED corrections (∼α3) and corresponding recoil (or finite mass) corrections in the two-electron helium-like ions are presented. Other important properties of the two-electron ions are also determined to high accuracy, including the expectation values of the quasi-singular Vinti operator and < reN-2> and < ree-2> expectation values. Elastic scattering of fast electrons by the two-electron ions in the Born approximation is considered. Interpolation formulas are derived for the bound state properties of the two-electron ions as the function of the nuclear electric charge Q.

Metal-Organic Frameworks Derived Okra-like SnO2 Encapsulated in Nitrogen-Doped Graphene for Lithium Ion Battery.

PubMed

Zhou, Xiangyang; Chen, Sanmei; Yang, Juan; Bai, Tao; Ren, Yongpeng; Tian, Hangyu

2017-04-26

A facile process is developed to prepare SnO 2 -based composites through using metal-organic frameworks (MOFs) as precursors. The nitrogen-doped graphene wrapped okra-like SnO 2 composites (SnO 2 @N-RGO) are successfully synthesized for the first time by using Sn-based metal-organic frameworks (Sn-MOF) as precursors. When utilized as an anode material for lithium-ion batteries, the SnO 2 @N-RGO composites possess a remarkably superior reversible capacity of 1041 mA h g -1 at a constant current of 200 mA g -1 after 180 charge-discharge processes and excellent rate capability. The excellent performance can be primarily ascribed to the unique structure of 1D okra-like SnO 2 in SnO 2 @N-RGO which are actually composed of a great number of SnO 2 primary crystallites and numerous well-defined internal voids, can effectively alleviate the huge volume change of SnO 2 , and facilitate the transport and storage of lithium ions. Besides, the structural stability acquires further improvement when the okra-like SnO 2 are wrapped by N-doped graphene. Similarly, this synthetic strategy can be employed to synthesize other high-capacity metal-oxide-based composites starting from various metal-organic frameworks, exhibiting promising application in novel electrode material field of lithium-ion batteries.

Elastic recoil detection analysis for the determination of hydrogen concentration profiles in switchable mirrors

NASA Astrophysics Data System (ADS)

Huisman, M. C.; van der Molen, S. J.; Vis, R. D.

1999-10-01

Switchable mirrors [J.N. Huiberts, R. Griessen, J.H. Rector, R.J. Wijngaarden, J.P. Dekker, D.G. de Groot, N.J. Koeman, Nature 380 (1996) 231; J.N Huiberts, J.H. Rector, R.J. Wijngaarden, S. Jetten, D. de Groot, B. Dam, N.J.. Koeman, R. Griessen, B. Hjörvarsson, S Olafsson, Y.S. Cho, J. Alloys and Compounds 239 (1996) 158; F.J.A. den Broeder, S.J. van der Molen, M. Kremers, J. N. Huiberts, D.G. Nagengast, A.T.M. van Gogh, W.H. Huisman, N. J. Koeman, B. Dam, J.H. Rector, S. Plota, M. Haaksma, R.M.N. Hanzen, R.M. Jungblut, P.A. Duine, R. Griessen, Nature 394 (1998) 656] made of thin films of Y, La or rare-earth (RE) metals exhibit spectacular changes in their optical and electrical properties upon hydrogen loading. The study of these materials has indicated that the occurring phenomena are highly sensitive to the actual hydrogen concentration in these materials. In this paper elastic recoil detection analysis (ERDA) is used as a tool to measure hydrogen concentrations on a micrometer scale. The measurements have been performed using a 4He 2+ ion beam from a 1.7 MV Pelletron accelerator. The ion beam can be focused routinely to a spot size of approximately 10 μm 2. The experimental set-up enables the simultaneous measurement of Rutherford backscattering spectrometry (RBS) as well as particle induced X-ray emission (PIXE) spectra, which provide complementary information. The results of ERDA measurements on laterally diffused YH x (0< x<3) samples with a qualitatively known hydrogen concentration profile are presented and discussed. The calibration of the microbeam set-up and possible improvement of the measurement technique are described.

Recoil Polarization for Δ Excitation in Pion Electroproduction

NASA Astrophysics Data System (ADS)

Kelly, J. J.; Roché, R. E.; Chai, Z.; Jones, M. K.; Gayou, O.; Sarty, A. J.; Frullani, S.; Aniol, K.; Beise, E. J.; Benmokhtar, F.; Bertozzi, W.; Boeglin, W. U.; Botto, T.; Brash, E. J.; Breuer, H.; Brown, E.; Burtin, E.; Calarco, J. R.; Cavata, C.; Chang, C. C.; Chant, N. S.; Chen, J.-P.; Coman, M.; Crovelli, D.; de Leo, R.; Dieterich, S.; Escoffier, S.; Fissum, K. G.; Garde, V.; Garibaldi, F.; Georgakopoulus, S.; Gilad, S.; Gilman, R.; Glashausser, C.; Hansen, J.-O.; Higinbotham, D. W.; Hotta, A.; Huber, G. M.; Ibrahim, H.; Iodice, M.; de Jager, C. W.; Jiang, X.; Klimenko, A.; Kozlov, A.; Kumbartzki, G.; Kuss, M.; Lagamba, L.; Laveissière, G.; Lerose, J. J.; Lindgren, R. A.; Liyanage, N.; Lolos, G. J.; Lourie, R. W.; Margaziotis, D. J.; Marie, F.; Markowitz, P.; McAleer, S.; Meekins, D.; Michaels, R.; Milbrath, B. D.; Mitchell, J.; Nappa, J.; Neyret, D.; Perdrisat, C. F.; Potokar, M.; Punjabi, V. A.; Pussieux, T.; Ransome, R. D.; Roos, P. G.; Rvachev, M.; Saha, A.; Širca, S.; Suleiman, R.; Strauch, S.; Templon, J. A.; Todor, L.; Ulmer, P. E.; Urciuoli, G. M.; Weinstein, L. B.; Wijesooriya, K.; Wojtsekhowski, B.; Zheng, X.; Zhu, L.

2005-08-01

We measured angular distributions of recoil-polarization response functions for neutral pion electroproduction for W=1.23 GeV at Q2=1.0 (GeV/c)2, obtaining 14 separated response functions plus 2 Rosenbluth combinations; of these, 12 have been observed for the first time. Dynamical models do not describe quantities governed by imaginary parts of interference products well, indicating the need for adjusting magnitudes and phases for nonresonant amplitudes. We performed a nearly model-independent multipole analysis and obtained values for Re (S1+/M1+)=-(6.84±0.15)% and Re (E1+/M1+)=-(2.91±0.19)% that are distinctly different from those from the traditional Legendre analysis based upon M1+ dominance and ℓπ≤1 truncation.

Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

DOEpatents

Walker, Richard J.

1986-01-01

A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

Organic nitrogen in PM2.5 aerosol at a forest site in the Southeast US

EPA Science Inventory

There is growing evidence that organo-nitrogen compounds may constitute a significant fraction of the aerosol nitrogen (N) budget. In this study, the concentration of organic nitrogen (ON) and major inorganic ions in PM2.5 aerosol were measured at the Duke Forest Research Facilit...

Theory of ionizing neutrino-atom collisions: The role of atomic recoil

NASA Astrophysics Data System (ADS)

Kouzakov, Konstantin A.; Studenikin, Alexander I.

2016-04-01

We consider theoretically ionization of an atom by neutrino impact taking into account electromagnetic interactions predicted for massive neutrinos by theories beyond the Standard Model. The effects of atomic recoil in this process are estimated using the one-electron and semiclassical approximations and are found to be unimportant unless the energy transfer is very close to the ionization threshold. We show that the energy scale where these effects become important is insignificant for current experiments searching for magnetic moments of reactor antineutrinos.

Distribution and Energization of the Heavy Ions in Saturn's Magnetosphere

NASA Astrophysics Data System (ADS)

Tenishev, V.; Gombosi, T. I.; Combi, M. R.; Borovikov, D.; Regoli, L.

2017-12-01

Observations by Pioneer 11 and Voyager collected during their flybys of Saturn and Cassini observations during Saturn Orbit Insertion (SOI) indicate that Saturn's magnetosphere contains a significant population of energetic heavy ions, which originate in neutral tori of the moons orbiting in Saturn's magnetosphere and act as agents for the surface erosion and chemical alternation via sputtering, implantation, and radiolysis of objects embedded in Saturn's magnetosphere. The composition of these energetic heavy ions is dominated by the water group ions with a small nitrogen contribution as have been shown by observations performed with MIMI onboard Cassini, which indicate that Saturn's magnetosphere possesses a ring current located approximately between 8 and 15 RS, primarily composed of O+ ions that originate from Enceladus' neutral torus. Similarly, the energetic nitrogen ions are produced via ionization of the volatiles ejected by Titan and then accelerated in Saturn's magnetosphere. Is it suggested that the primary mechanism of energization of the heavy ions is their inward diffusion conserving the first and second adiabatic invariants. Such, nitrogen ions that have been picked up at the orbit of Titan and diffuse radially inward, could attain energies of 100 keV at Dione's Mcllwain L shell and 400 keV at Enceladus' L shell. At the same time radial transport of energetic ions will result in various loss processes such as satellite sweeping, collisions with dust and neutral clouds and precipitation into Saturn's atmosphere via wave-particle interactions. This work is focused on characterizing the global distribution and acceleration of the energetic water group and nitrogen ions produced via ionizing of the volatiles ejected by Enceladus and Titan, respectively. In our approach we will consider acceleration of the newly created pickup ions affected by the magnetic field derived from the Khurana et al. (2006) model and the convection electric field. Here we will

Proposed low-energy absolute calibration of nuclear recoils in a dual-phase noble element TPC using D-D neutron scattering kinematics

NASA Astrophysics Data System (ADS)

Verbus, J. R.; Rhyne, C. A.; Malling, D. C.; Genecov, M.; Ghosh, S.; Moskowitz, A. G.; Chan, S.; Chapman, J. J.; de Viveiros, L.; Faham, C. H.; Fiorucci, S.; Huang, D. Q.; Pangilinan, M.; Taylor, W. C.; Gaitskell, R. J.

2017-04-01

We propose a new technique for the calibration of nuclear recoils in large noble element dual-phase time projection chambers used to search for WIMP dark matter in the local galactic halo. This technique provides an in situ measurement of the low-energy nuclear recoil response of the target media using the measured scattering angle between multiple neutron interactions within the detector volume. The low-energy reach and reduced systematics of this calibration have particular significance for the low-mass WIMP sensitivity of several leading dark matter experiments. Multiple strategies for improving this calibration technique are discussed, including the creation of a new type of quasi-monoenergetic neutron source with a minimum possible peak energy of 272 keV. We report results from a time-of-flight-based measurement of the neutron energy spectrum produced by an Adelphi Technology, Inc. DD108 neutron generator, confirming its suitability for the proposed nuclear recoil calibration.

Analysis of microbial community and nitrogen transition with enriched nitrifying soil microbes for organic hydroponics.

PubMed

Saijai, Sakuntala; Ando, Akinori; Inukai, Ryuya; Shinohara, Makoto; Ogawa, Jun

2016-06-27

Nitrifying microbial consortia were enriched from bark compost in a water system by regulating the amounts of organic nitrogen compounds and by controlling the aeration conditions with addition of CaCO 3 for maintaining suitable pH. Repeated enrichment showed reproducible mineralization of organic nitrogen via the conversion of ammonium ions ([Formula: see text]) and nitrite ions ([Formula: see text]) into nitrate ions ([Formula: see text]). The change in microbial composition during the enrichment was investigated by PCR-DGGE analysis with a focus on prokaryote, ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, and eukaryote cell types. The microbial transition had a simple profile and showed clear relation to nitrogen ions transition. Nitrosomonas and Nitrobacter were mainly detected during [Formula: see text] and [Formula: see text] oxidation, respectively. These results revealing representative microorganisms acting in each ammonification and nitrification stages will be valuable for the development of artificial simple microbial consortia for organic hydroponics that consisted of identified heterotrophs and autotrophic nitrifying bacteria.

One-step synthesis of 3D sulfur/nitrogen dual-doped graphene supported nano silicon as anode for Li-ion batteries

NASA Astrophysics Data System (ADS)

Li, Ruihong; Li, Junli; Qi, Kaiyu; Ge, Xin; Zhang, Qiwei; Zhang, Bangwen

2018-03-01

Silicon is one of the most promising candidates for next-generation anode of Lithium-ion batteries. However, poor electrical conductivity and large volume change during alloying/dealloying hinder its practical use. Here we reported a three-dimensional (3D) nitrogen and sulfur codoped graphene supported silicon nanoparticles composite (SN-G/Si) through one-step hydrothermal self-assembly. The obtained SN-G/Si was investigated in term of instrumental characterizations and electrochemical properties. The results show that SN-G/Si as a freestanding anode in LIBs delivers a reversible capacity of 2020 mAh g-1 after 100 cycles with coulombic efficiency of nearly 97%. The excellent electrochemical performance is associated with the unique structure and the synergistic effect of SN-G/Si, in which SN-G provides volume buffer for nano Si as the flexible loader, short paths/fast channels for electron/Li ion transport as porous skeleton, and low charge-transfer resistance.

Clues From Pluto's Ions

NASA Astrophysics Data System (ADS)

Kohler, Susanna

2016-05-01

Nearly a year ago, in July 2015, the New Horizons spacecraft passed by the Pluto system. The wealth of data amassed from that flyby is still being analyzed including data from the Solar Wind Around Pluto (SWAP) instrument. Recent examination of this data has revealedinteresting new information about Plutos atmosphere and how the solar wind interacts with it.A Heavy Ion TailThe solar wind is a constant stream of charged particles released by the Sun at speeds of around 400 km/s (thats 1 million mph!). This wind travels out to the far reaches of the solar system, interacting with the bodies it encounters along the way.By modeling the SWAP detections, the authors determine the directions of the IMF that could produce the heavy ions detected. Red pixels represent IMF directions permitted. No possible IMF could reproduce the detections if the ions are nitrogen (bottom panels), and only retrograde IMF directions can produce the detections if the ions are methane. [Adapted from Zirnstein et al. 2016]New Horizons data has revealed that Plutos atmosphere leaks neutral nitrogen, methane, and carbon monoxide molecules that sometimes escape its weak gravitational pull. These molecules become ionized and are subsequently picked up by the passing solar wind, forming a tail of heavy ions behind Pluto. The details of the geometry and composition of this tail, however, had not yet been determined.Escaping MethaneIn a recent study led by Eric Zirnstein (Southwest Research Institute), the latest analysis of data from the SWAP instrument on board New Horizons is reported. The team used SWAPs ion detections from just after New Horizons closest approach to Pluto to better understand how the heavy ions around Pluto behave, and how the solar wind interacts with Plutos atmosphere.In the process of analyzing the SWAP data, Zirnstein and collaborators first establish what the majority of the heavy ions picked up by the solar wind are. Models of the SWAP detections indicate they are unlikely

Extra-large remnant recoil velocities and spins from near-extremal-Bowen-York-spin black-hole binaries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dain, Sergio; Max Planck Institute for Gravitational Physics; Lousto, Carlos O.

2008-07-15

We evolve equal-mass, equal-spin black-hole binaries with specific spins of a/m{sub H}{approx}0.925, the highest spins simulated thus far and nearly the largest possible for Bowen-York black holes, in a set of configurations with the spins counteraligned and pointing in the orbital plane, which maximizes the recoil velocities of the merger remnant, as well as a configuration where the two spins point in the same direction as the orbital angular momentum, which maximizes the orbital hangup effect and remnant spin. The coordinate radii of the individual apparent horizons in these cases are very small and the simulations require very high centralmore » resolutions (h{approx}M/320). We find that these highly spinning holes reach a maximum recoil velocity of {approx}3300 km s{sup -1} (the largest simulated so far) and, for the hangup configuration, a remnant spin of a/m{sub H}{approx}0.922. These results are consistent with our previous predictions for the maximum recoil velocity of {approx}4000 km s{sup -1} and remnant spin; the latter reinforcing the prediction that cosmic censorship is not violated by merging highly spinning black-hole binaries. We also numerically solve the initial data for, and evolve, a single maximal-Bowen-York-spin black hole, and confirm that the 3-metric has an O(r{sup -2}) singularity at the puncture, rather than the usual O(r{sup -4}) singularity seen for nonmaximal spins.« less

Deviation from Normal Boltzmann Distribution of High-lying Energy Levels of Iron Atom Excited by Okamoto-cavity Microwave-induced Plasmas Using Pure Nitrogen and Nitrogen-Oxygen Gases.

PubMed

Wagatsuma, Kazuaki

2015-01-01

This paper describes several interesting excitation phenomena occurring in a microwave-induced plasma (MIP) excited with Okamoto-cavity, especially when a small amount of oxygen was mixed with nitrogen matrix in the composition of the plasma gas. An ion-to-atom ratio of iron, which was estimated from the intensity ratio of ion to atomic lines having almost the same excitation energy, was reduced by adding oxygen gas to the nitrogen MIP, eventually contributing to an enhancement in the emission intensities of the atomic lines. Furthermore, Boltzmann plots for iron atomic lines were observed in a wide range of the excitation energy from 3.4 to 6.9 eV, indicating that plots of the atomic lines having lower excitation energies (3.4 to 4.8 eV) were well fitted on a straight line while those having more than 5.5 eV deviated upwards from the linear relationship. This overpopulation would result from any other excitation process in addition to the thermal excitation that principally determines the Boltzmann distribution. A Penning-type collision with excited species of nitrogen molecules probably explains this additional excitation mechanism, in which the resulting iron ions recombine with captured electrons, followed by cascade de-excitations between closely-spaced excited levels just below the ionization limit. As a result, these high-lying levels might be more populated than the low-lying levels of iron atom. The ionization of iron would be caused less actively in the nitrogen-oxygen plasma than in a pure nitrogen plasma, because excited species of nitrogen molecule, which can provide the ionization energy in a collision with iron atom, are consumed through collisions with oxygen molecules to cause their dissociation. It was also observed that the overpopulation occurred to a lesser extent when oxygen gas was added to the nitrogen plasma. The reason for this was also attributed to decreased number density of the excited nitrogen species due to collisions with oxygen

The effect of nitrogen incorporation on the bonding structure of hydrogenated carbon nitride films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Camero, M.; Buijnsters, J. G.; Gomez-Aleixandre, C.

2007-03-15

This work describes the composition and bonding structure of hydrogenated carbon nitride (a-CN{sub x}:H) films synthesized by electron cyclotron resonance chemical vapor deposition using as precursor gases argon, methane, and nitrogen. The composition of the films was derived from Rutherford backscattering and elastic recoil detection analysis and the bonding structure was examined by infrared (IR) spectroscopy and x-ray absorption near edge spectroscopy (XANES). By varying the nitrogen to methane ratio in the applied gas mixture, polymeric a-CN{sub x}:H films with N/C contents varying from 0.06 to 0.49 were obtained. Remarkably, the H content of the films ({approx}40 at. %) wasmore » rather unaffected by the nitrogenation process. The different bonding states as detected in the measured XANES C(1s) and N(1s) spectra have been correlated with those of a large number of reference samples. The XANES and IR spectroscopy results indicate that N atoms are efficiently incorporated into the amorphous carbon network and can be found in different bonding environments, such as pyridinelike, graphitelike, nitrilelike, and amino groups. The nitrogenation of the films results in the formation of N-H bonding environments at the cost of C-H structures. Also, the insertion of N induces a higher fraction of double bonds in the structure at the expense of the linear polymerlike chains, hence resulting in a more cross-linked solid. The formation of double bonds takes place through complex C=N structures and not by formation of graphitic aromatic rings. Also, the mechanical and tribological properties (hardness, friction, and wear) of the films have been studied as a function of the nitrogen content. Despite the major modifications in the bonding structure with nitrogen uptake, no significant changes in these properties are observed.« less

Precise control of atomic nitrogen production in an electron cyclotron resonance plasma using N2/noble gas mixtures

NASA Astrophysics Data System (ADS)

Fan, Z. Y.; Newman, N.

1998-07-01

The atomic nitrogen flux and impacting ion kinetic energy are two important parameters which influence the quality of deposited nitride films using reactive growth. In this letter, a method is described to control the flux and kinetic energy of atomic and molecular nitrogen ions using an electron cyclotron resonance plasma with N2/Ar and N2/Ne gas mixtures. The results clearly show that the addition of neon to nitrogen plasma can remarkably enhance the production rate of atomic nitrogen due to Penning ionization involving the metastable state of Ne. In contrast, the addition of argon significantly decreases the rate.

The Final Merger of Massive Black Holes: Recoils, Gravitational Waves, and Electromagnetic Signatures

NASA Technical Reports Server (NTRS)

Centrella, Joan M.

2010-01-01

The final merger of two massive black holes produces a powerful burst of gravitational radiation, emitting more energy than all the stars in the observable universe combined. The resulting gravitational waveforms will be easily detectable by the space-based LISA out to redshifts z greater than 10, revealing the masses and spins of the black holes to high precision. If the merging black holes have unequal masses, or asymmetric spins, the final black hole that forms can recoil with a velocity exceeding 1000 km/s. And, when the black holes merge in the presence of gas and magnetic fields, various types of electromagnetic signals may also be produced. For more than 30 years, scientists have tried to compute black hole mergers using the methods of numerical relativity. The resulting computer codes have been plagued by instabilities, causing them to crash well before the black holes in the binary could complete even a single orbit. Within the past few years, however, this situation has changed dramatically, with a series of remarkable breakthroughs. This talk will focus on new results that are revealing the dynamics and waveforms of binary black hole mergers, recoil velocities, and the possibility of accompanying electromagnetic outbursts.

Ab initio molecular dynamics simulations of low energy recoil events in MgO

DOE PAGES

Petersen, B. A.; Liu, B.; Weber, W. J.; ...

2017-01-11

In this paper, low-energy recoil events in MgO are studied using ab initio molecular dynamics simulations to reveal the dynamic displacement processes and final defect configurations. Threshold displacement energies, E d, are obtained for Mg and O along three low-index crystallographic directions, [100], [110], and [111]. The minimum values for E d are found along the [110] direction consisting of the same element, either Mg or O atoms. Minimum threshold values of 29.5 eV for Mg and 25.5 eV for O, respectively, are suggested from the calculations. For other directions, the threshold energies are considerably higher, 65.5 and 150.0 eVmore » for O along [111] and [100], and 122.5 eV for Mg along both [111] and [100] directions, respectively. These results show that the recoil events in MgO are partial-charge transfer assisted processes where the charge transfer plays an important role. Finally, there is a similar trend found in other oxide materials, where the threshold displacement energy correlates linearly with the peak partial-charge transfer, suggesting this behavior might be universal in ceramic oxides.« less

A new sliding joint to accommodate recoil of a free-piston-driven expansion tube facility

NASA Astrophysics Data System (ADS)

Gildfind, D. E.; Morgan, R. G.

2016-11-01

This paper describes a new device to decouple free-piston driver recoil and its associated mechanical vibration from the acceleration tube and test section of The University of Queensland's X3 expansion tube. A sliding joint is introduced to the acceleration tube which axially decouples the facility at this station. When the facility is fired, the upstream section of the facility, which includes the free-piston driver, can recoil upstream freely. The downstream acceleration tube remains stationary. This arrangement provides two important benefits. Firstly, it eliminates nozzle movement relative to the test section before and during the experiment. This has benefits in terms of experimental setup and alignment. Secondly, it prevents transmission of mechanical disturbances from the free-piston driver to the acceleration tube, thereby eliminating mechanically-induced transducer noise in the sensitive pressure transducers installed in this low-pressure tube. This paper details the new design, and presents experimental confirmation of its performance.

Temperature Dependence and Recoil-free Fraction Effects in Olivines Across the Mg-Fe Solid Solution

NASA Technical Reports Server (NTRS)

Sklute, E. C.; Rothstein, Y.; Dyar, M. D.; Schaefer, M. W.; Menzies, O. N.; Bland, P. A.; Berry, F. J.

2005-01-01

Olivine and pyroxene are the major ferromagnesian minerals in most meteorite types and in mafic igneous rocks that are dominant at the surface of the Earth. It is probable that they are the major mineralogical components at the surface of any planetary body that has undergone differentiation processes. In situ mineralogical studies of the rocks and soils on Mars suggest that olivine is a widespread mineral on that planet s surface (particularly at the Gusev site) and that it has been relatively unaffected by alteration. Thus an understanding of the characteristics of Mossbauer spectra of olivine is of great importance in interpreting MER results. However, variable temperature Mossbauer spectra of olivine, which are needed to quantify recoil-free fraction effects and to understand the temperature dependence of olivine spectra, are lacking in the literature. Thus, we present here a study of the temperature dependence and recoil-free fraction of a series of synthetic olivines.

A recoil-proton spectrometer based on a p-i-n diode implementing pulse-shape discrimination.

PubMed

Agosteo, S; D'Angelo, G; Fazzi, A; Foglio Para, A; Pola, A; Ventura, L; Zotto, P

2004-01-01

A recoil-proton spectrometer was created by coupling a p-i-n diode with a polyethylene converter. The maximum detectable energy, imposed by the thickness of the totally depleted layer, is approximately 6 MeV. The minimum detectable energy is limited by the contribution of secondary electrons generated by photons in the detector assembly. This limit is approximately 1.5 MeV at full-depletion voltage and was decreased using pulse-shape discrimination. The diode was set up in the 'reverse-injection' configuration (i.e. with the N+ layer adjacent to the converter). This configuration provides longer collection times for the electron-hole pairs generated by the recoil-protons. The pulse-shape discrimination was based on the zero-crossing time of bipolar signals from a (CR)2-(RC)2 filter. The detector was characterised using monoenergetic neutrons generated in the Van De Graaff CN accelerator at the INFN-Laboratori Nazionali di Legnaro. The energy limit for discrimination proved to be approximately 900 keV.

Development and evaluation of a collection apparatus for recoil products for study of the deexcitation process of (235m)U.

PubMed

Shigekawa, Y; Kasamatsu, Y; Shinohara, A

2016-05-01

The nucleus (235m)U is an isomer with extremely low excitation energy (76.8 eV) and decays dominantly through the internal conversion (IC) process. Because outer-shell electrons are involved in the IC process, the decay constant of (235m)U depends on its chemical environment. We plan to study the deexcitation process of (235m)U by measuring the energy spectra of IC electrons in addition to the decay constants for various chemical forms. In this paper, the preparation method of (235m)U samples from (239)Pu by using alpha-recoil energy is reported. A Collection Apparatus for Recoil Products was fabricated, and then collection efficiencies under various conditions were determined by collecting (224)Ra recoiling out of (228)Th electrodeposited and precipitated sources. The pressure in the apparatus (vacuum or 1 atm of N2 gas) affected the variations of the collection efficiencies depending on the negative voltage applied to the collector. The maximum values of the collection efficiencies were mainly affected by the thickness of the (228)Th sources. From these results, the suitable conditions of the (239)Pu sources for preparation of (235m)U were determined. In addition, dissolution efficiencies were determined by washing collected (224)Ra with solutions. When (224)Ra was collected in 1 atm of N2 gas and dissolved with polar solutions such as water, the dissolution efficiencies were nearly 100%. The method of rapid dissolution of recoil products would be applicable to rapid preparation of short-lived (235m)U samples for various chemical forms.

Search for Electronic Recoil Event Rate Modulation with 4 Years of XENON100 Data

NASA Astrophysics Data System (ADS)

Aprile, E.; Aalbers, J.; Agostini, F.; Alfonsi, M.; Amaro, F. D.; Anthony, M.; Arneodo, F.; Barrow, P.; Baudis, L.; Bauermeister, B.; Benabderrahmane, M. L.; Berger, T.; Breur, P. A.; Brown, A.; Brown, E.; Bruenner, S.; Bruno, G.; Budnik, R.; Bütikofer, L.; Calvén, J.; Cardoso, J. M. R.; Cervantes, M.; Cichon, D.; Coderre, D.; Colijn, A. P.; Conrad, J.; Cussonneau, J. P.; Decowski, M. P.; de Perio, P.; di Gangi, P.; di Giovanni, A.; Diglio, S.; Eurin, G.; Fei, J.; Ferella, A. D.; Fieguth, A.; Franco, D.; Fulgione, W.; Gallo Rosso, A.; Galloway, M.; Gao, F.; Garbini, M.; Geis, C.; Goetzke, L. W.; Greene, Z.; Grignon, C.; Hasterok, C.; Hogenbirk, E.; Itay, R.; Kaminsky, B.; Kessler, G.; Kish, A.; Landsman, H.; Lang, R. F.; Lellouch, D.; Levinson, L.; Lin, Q.; Lindemann, S.; Lindner, M.; Lopes, J. A. M.; Manfredini, A.; Maris, I.; Marrodán Undagoitia, T.; Masbou, J.; Massoli, F. V.; Masson, D.; Mayani, D.; Messina, M.; Micheneau, K.; Miguez, B.; Molinario, A.; Murra, M.; Naganoma, J.; Ni, K.; Oberlack, U.; Pakarha, P.; Pelssers, B.; Persiani, R.; Piastra, F.; Pienaar, J.; Pizzella, V.; Piro, M.-C.; Plante, G.; Priel, N.; Rauch, L.; Reichard, S.; Reuter, C.; Rizzo, A.; Rosendahl, S.; Rupp, N.; Dos Santos, J. M. F.; Sartorelli, G.; Scheibelhut, M.; Schindler, S.; Schreiner, J.; Schumann, M.; Scotto Lavina, L.; Selvi, M.; Shagin, P.; Silva, M.; Simgen, H.; Sivers, M. V.; Stein, A.; Thers, D.; Tiseni, A.; Trinchero, G.; Tunnell, C.; Wang, H.; Wei, Y.; Weinheimer, C.; Wulf, J.; Ye, J.; Zhang, Y.; Xenon Collaboration

2017-03-01

We report on a search for electronic recoil event rate modulation signatures in the XENON100 data accumulated over a period of 4 yr, from January 2010 to January 2014. A profile likelihood method, which incorporates the stability of the XENON100 detector and the known electronic recoil background model, is used to quantify the significance of periodicity in the time distribution of events. There is a weak modulation signature at a period of 43 1-14+16 day in the low energy region of (2.0-5.8) keV in the single scatter event sample, with a global significance of 1.9 σ ; however, no other more significant modulation is observed. The significance of an annual modulation signature drops from 2.8 σ , from a previous analysis of a subset of this data, to 1.8 σ with all data combined. Single scatter events in the low energy region are thus used to exclude the DAMA/LIBRA annual modulation as being due to dark matter electron interactions via axial vector coupling at 5.7 σ .

Measurement of the scintillation time spectra and pulse-shape discrimination of low-energy β and nuclear recoils in liquid argon with DEAP-1

DOE PAGES

Amaudruz, P. -A.; Batygov, M.; Beltran, B.; ...

2016-09-17

The DEAP-1 low-background liquid argon detector has been used to measure scintillation pulse shapes of beta decays and nuclear recoil events and to demonstrate the feasibility of pulse-shape discrimination down to an electron-equivalent energy of 20 keV ee. The relative intensities of singlet/triplet states in liquid argon have been measured as a function of energy between 15 and 500 keVee for both beta and nuclear recoils. Using a triple-coincidence tag we find the fraction of beta events that are misidentified as nuclear recoils to be less than 6 x 10 -8 between 43-86 keV ee and that the discrimination parametermore » agrees with a simple analytic model. The discrimination measurement is currently limited by nuclear recoils induced by cosmic-ray generated neutrons, and is expected to improve by operating the detector underground at SNOLAB. The analytic model predicts a beta misidentification fraction of 10 -10 for an electron-equivalent energy threshold of 20 keV ee. This reduction allows for a sensitive search for spin-independent scattering of WIMPs from 1000 kg of liquid argon with a WIMP-nucleon cross-section sensitivity of 10 -46 cm 2.« less

Measurement of the scintillation time spectra and pulse-shape discrimination of low-energy β and nuclear recoils in liquid argon with DEAP-1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amaudruz, P. -A.; Batygov, M.; Beltran, B.

The DEAP-1 low-background liquid argon detector has been used to measure scintillation pulse shapes of beta decays and nuclear recoil events and to demonstrate the feasibility of pulse-shape discrimination down to an electron-equivalent energy of 20 keV ee. The relative intensities of singlet/triplet states in liquid argon have been measured as a function of energy between 15 and 500 keVee for both beta and nuclear recoils. Using a triple-coincidence tag we find the fraction of beta events that are misidentified as nuclear recoils to be less than 6 x 10 -8 between 43-86 keV ee and that the discrimination parametermore » agrees with a simple analytic model. The discrimination measurement is currently limited by nuclear recoils induced by cosmic-ray generated neutrons, and is expected to improve by operating the detector underground at SNOLAB. The analytic model predicts a beta misidentification fraction of 10 -10 for an electron-equivalent energy threshold of 20 keV ee. This reduction allows for a sensitive search for spin-independent scattering of WIMPs from 1000 kg of liquid argon with a WIMP-nucleon cross-section sensitivity of 10 -46 cm 2.« less

Nitrogen Gas Field Ion Source (GFIS) Focused Ion Beam (FIB) Secondary Electron Imaging: A First Look.

PubMed

Schmidt, Marek E; Yasaka, Anto; Akabori, Masashi; Mizuta, Hiroshi

2017-08-01

The recent technological advance of the gas field ion source (GFIS) and its successful integration into systems has renewed the interest in the focused ion beam (FIB) technology. Due to the atomically small source size and the use of light ions, the limitations of the liquid metal ion source are solved as device dimensions are pushed further towards the single-digit nanometer size. Helium and neon ions are the most widely used, but a large portfolio of available ion species is desirable, to allow a wide range of applications. Among argon and hydrogen, $${\\rm N}_{2}^{{\\plus}} $$ ions offer unique characteristics due to their covalent bond and their use as dopant for various carbon-based materials including diamond. Here, we provide a first look at the $${\\rm N}_{2}^{{\\plus}} $$ GFIS-FIB enabled imaging of a large selection of microscopic structures, including gold on carbon test specimen, thin metal films on insulator and nanostructured carbon-based devices, which are among the most actively researched materials in the field of nanoelectronics. The results are compared with images acquired by He+ ions, and we show that $${\\rm N}_{2}^{{\\plus}} $$ GFIS-FIB can offer improved material contrast even at very low imaging dose and is more sensitive to the surface roughness.

Accurate wavelengths for X-ray spectroscopy and the NIST hydrogen-like ion database

NASA Astrophysics Data System (ADS)

Kotochigova, S. A.; Kirby, K. P.; Brickhouse, N. S.; Mohr, P. J.; Tupitsyn, I. I.

2005-06-01

We have developed an ab initio multi-configuration Dirac-Fock-Sturm method for the precise calculation of X-ray emission spectra, including energies, transition wavelengths and transition probabilities. The calculations are based on non-orthogonal basis sets, generated by solving the Dirac-Fock and Dirac-Fock-Sturm equations. Inclusion of Sturm functions into the basis set provides an efficient description of correlation effects in highly charged ions and fast convergence of the configuration interaction procedure. A second part of our study is devoted to developing a theoretical procedure and creating an interactive database to generate energies and transition frequencies for hydrogen-like ions. This procedure is highly accurate and based on current knowledge of the relevant theory, which includes relativistic, quantum electrodynamic, recoil, and nuclear size effects.

Modification of graphene by ion beam

NASA Astrophysics Data System (ADS)

Gawlik, G.; Ciepielewski, P.; Jagielski, J.; Baranowski, J.

2017-09-01

Ion induced defect generation in graphene was analyzed using Raman spectroscopy. A single layer graphene membrane produced by chemical vapor deposition (CVD) on copper foil and then transferred on glass substrate was subjected to helium, carbon, nitrogen, argon and krypton ions bombardment at energies from the range 25 keV to 100 keV. A density of ion induced defects and theirs mean size were estimated by using Raman measurements. Increasing number of defects generated by ion with increase of ion mass and decrease of ion energy was observed. Dependence of ion defect efficiency (defects/ion) on ion mass end energy was proportional to nuclear stopping power simulated by SRIM. No correlation between ion defect efficiency and electronic stopping power was observed.

The DarkSide-50 Experiment: Electron Recoil Calibrations and A Global Energy Variable

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hackett, Brianne Rae

2017-01-01

Over the course of decades, there has been mounting astronomical evidence for non-baryonic dark matter, yet its precise nature remains elusive. A favored candidate for dark matter is the Weakly Interacting Massive Particle (WIMP) which arises naturally out of extensions to the Standard Model. WIMPs are expected to occasionally interact with particles of normal matter through nuclear recoils. DarkSide-50 aims to detect this type of particle through the use of a two-phase liquid argon time projection chamber. To make a claim of discovery, an accurate understanding of the background and WIMP search region is imperative. Knowledge of the backgrounds ismore » done through extensive studies of DarkSide-50's response to electron and nuclear recoils. The CALibration Insertion System (CALIS) was designed and built for the purpose of introduc- ing radioactive sources into or near the detector in a joint eort between Fermi National Laboratory (FNAL) and the University of Hawai'i at Manoa. This work describes the testing, installation, and commissioning of CALIS at the Laboratori Nazionali del Gran Sasso. CALIS has been used in mul- tiple calibration campaigns with both neutron and sources. In this work, DarkSide-50's response to electron recoils, which are important for background estimations, was studied through the use of calibration sources by constructing a global energy variable which takes into account the anti- correlation between scintillation and ionization signals produced by interactions in the liquid argon. Accurately reconstructing the event energy correlates directly with quantitatively understanding the WIMP sensitivity in DarkSide-50. This work also validates the theoretically predicted decay spectrum of 39Ar against 39Ar decay data collected in the early days of DarkSide-50 while it was lled with atmospheric argon; a validation of this type is not readily found in the literature. Finally, we show how well the constructed energy variable can predict energy

Development of phonon-mediated cryogenic particle detectors with electron and nuclear recoil discrimination

NASA Astrophysics Data System (ADS)

Nam, Sae Woo

1999-10-01

Observations have shown that galaxies, including our own, are surrounded by halos of ``dark matter''. One possibility is that this may be an undiscovered form of matter, weakly interacting massive particles (WIMPs). This thesis describes the development of silicon based cryogenic particle detectors designed to directly detect interactions with these WIMPs. These detectors are part of a new class of detectors which are able to reject background events by simultaneously measuring energy deposited into phonons versus electron hole pairs. By using the phonon sensors with the ionization sensors to compare the partitioning of energy between phonons and ionizations we can discriminate between electron recoil events (background radiation) and nuclear recoil events (dark matter events). These detectors with built-in background rejection are a major advance in background rejection over previous searches. Much of this thesis will describe work in scaling the detectors from / g prototype devices to a fully functional prototype 100g dark matter detector. In particular, many sensors were fabricated and tested to understand the behavior of our phonon sensors, Quasipartice trapping assisted Electrothermal feedback Transition edge sensors (QETs). The QET sensors utilize aluminum quasiparticle traps attached to tungsten superconducting transition edge sensors patterned on a silicon substrate. The tungsten lines are voltage biased and self-regulate in the transition region. Phonons from particle interactions within the silicon propogate to the surface where they are absorbed by the aluminum generating quasiparticles in the aluminum. The quasiparticles diffuse into the tungsten and couple energy into the tungsten electron system. Consequently, the tungsten increases in resistance and causes a current pulse which is measured with a high bandwidth SQUID system. With this advanced sensor technology, we were able to demonstrate detectors with xy position sensitivity with electron and

Do lichens have "memory" of their native nitrogen environment?

PubMed

Munzi, Silvana; Loppi, Stefano; Cruz, Cristina; Branquinho, Cristina

2011-02-01

This study aimed to deepen the knowledge about intraspecific mechanisms regulating nitrogen tolerance in lichens to wet nitrogen deposition. Thalli of the nitrophilous lichen Xanthoria parietina were collected from environments with different nitrogen availabilities and immersed in 80 mL of ammonium sulphate (NH₄)₂SO₄ solutions with distinct concentrations (0, 0.025, 0.05 and 0.25 M) for 5 h per day during 3 days in a week. After each soaking event, lichens were air dried. After each treatment, maximal PSII efficiency, localization of ammonium ions, concentrations of K+ and Mg²+ and thalli buffer capacity were determined. Our results show that lichens are marked by their native nitrogen environment, since there were important differences between the physiological responses of X. parietina thalli previously grown in an area with high nitrogen deposition (nitrogen emissions of ca. 13,000 t/year) and those previously grown in an unpolluted area (nitrogen emissions of ca. 500 t/year). Greater N availability seems to enable X. parietina to cope better with the effects of nitrogen pollution.

Nitrogen solubility in the deep mantle and the origin of Earth's primordial nitrogen budget

NASA Astrophysics Data System (ADS)

Yoshioka, Takahiro; Wiedenbeck, Michael; Shcheka, Svyatoslav; Keppler, Hans

2018-04-01

The solubility of nitrogen in the major minerals of the Earth's transition zone and lower mantle (wadsleyite, ringwoodite, bridgmanite, and Ca-silicate perovskite) coexisting with a reduced, nitrogen-rich fluid phase was measured. Experiments were carried out in multi-anvil presses at 14 to 24 GPa and 1100 to 1800 °C close to the Fe-FeO buffer. Starting materials were enriched in 15N and the nitrogen concentrations in run products were measured by secondary ion mass spectrometry. Observed nitrogen (15N) solubilities in wadsleyite and ringwoodite typically range from 10 to 250 μg/g and strongly increase with temperature. Nitrogen solubility in bridgmanite is about 20 μg/g, while Ca-silicate perovskite incorporates about 30 μg/g under comparable conditions. Partition coefficients of nitrogen derived from coexisting phases are DNwadsleyite/olivine = 5.1 ± 2.1, DNringwoodite/wadsleyite = 0.49 ± 0.29, and DNbridgmanite/ringwoodite = 0.24 (+ 0.30 / - 0.19). Nitrogen solubility in the solid, iron-rich metal phase coexisting with the silicates was also measured and reached a maximum of nearly 1 wt.% 15N at 23 GPa and 1400 °C. These data yield a partition coefficient of nitrogen between iron metal and bridgmanite of DNmetal/bridgmanite ∼ 98, implying that in a lower mantle containing about 1% of iron metal, about half of the nitrogen still resides in the silicates. The high nitrogen solubility in wadsleyite and ringwoodite may be responsible for the low nitrogen concentrations often observed in ultradeep diamonds from the transition zone. Overall, the solubility data suggest that the transition zone and the lower mantle have the capacity to store at least 33 times the mass of nitrogen presently residing in the atmosphere. By combining the nitrogen solubility data in minerals with data on nitrogen solubility in silicate melts, mineral/melt partition coefficients of nitrogen can be estimated, from which the behavior of nitrogen during magma ocean crystallization can

Phase stability in thermally-aged CASS CF8 under heavy ion irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Meimei; Miller, Michael K.; Chen, Wei-Ying

2015-07-01

The stability of the microstructure of a cast austenitic stainless steel (CASS), before and after heavy ion irradiation, was investigated by atom probe tomography (APT). A CF8 ferrite–austenite duplex alloy was thermally aged at 400 °C for 10,000 h. After this treatment, APT revealed nanometer-sized G-phase precipitates and Fe-rich α and Cr-enriched α' phase separated regions in the ferrite. The thermally-aged CF8 specimen was irradiated with 1 MeV Kr ions to a fluence of 1.88 × 10 19 ions/m 2 at 400 °C. After irradiation, APT analysis revealed a strong spatial/dose dependence of the G-phase precipitates and the α–α' spinodalmore » decomposition in the ferrite. For the G-phase precipitates, the number density increased and the mean size decreased with increasing dose, and the particle size distribution changed considerably under irradiation. The inverse coarsening process can be described by recoil resolution. The amplitude of the α–α' spinodal decomposition in the ferrite was apparently reduced after heavy ion irradiation.« less

Persistent photoconductivity in oxygen-ion implanted KNbO3 bulk single crystal

NASA Astrophysics Data System (ADS)

Tsuruoka, R.; Shinkawa, A.; Nishimura, T.; Tanuma, C.; Kuriyama, K.; Kushida, K.

2016-12-01

Persistent Photoconductivity (PPC) in oxygen-ion implanted KNbO3 ([001] oriented bulk single crystals; perovskite structure; ferroelectric with a band gap of 3.16 eV)　is studied in air at room temperature to prevent the degradation of its crystallinity caused by the phase transition. The residual hydrogens in un-implanted samples are estimated to be 5×1014 cm-2 from elastic recoil detection analysis (ERDA). A multiple-energy implantation of oxygen ions into KNbO3 is performed using energies of 200, 400, and 600 keV (each ion fluence:1.0×1014 cm-2). The sheet resistance varies from >108 Ω/□ for an un-implanted sample to 1.9×107 Ω/□ for as-implanted one, suggesting the formation of donors due to hydrogen interstitials and oxygen vacancies introduced by the ion implantation. The PPC is clearly observed with ultraviolet and blue LEDs illumination rather than green, red, and infrared, suggesting the release of electrons from the metastable conductive state below the conduction band relating to the charge states of the oxygen vacancy.

WIMP detection and slow ion dynamics in carbon nanotube arrays.

PubMed

Cavoto, G; Cirillo, E N M; Cocina, F; Ferretti, J; Polosa, A D

2016-01-01

Large arrays of aligned carbon nanotubes (CNTs), open at one end, could be used as target material for the directional detection of weakly interacting dark matter particles (WIMPs). As a result of a WIMP elastic scattering on a CNT, a carbon ion might be injected in the body of the array and propagate through multiple collisions within the lattice. The ion may eventually emerge from the surface with open end CNTs, provided that its longitudinal momentum is large enough to compensate energy losses and its transverse momentum approaches the channeling conditions in a single CNT. Therefore, the angle formed between the WIMP wind apparent orientation and the direction of parallel carbon nanotube axes must be properly chosen. We focus on very low ion recoil kinetic energies, related to low mass WIMPs ([Formula: see text] GeV) where most of the existing experiments have low sensitivity. Relying on some exact results on two-dimensional lattices of circular obstacles, we study the low energy ion motion in the transverse plane with respect to CNT directions. New constraints are obtained on how to devise the CNT arrays to maximize the target channeling efficiency.

Experimental evidence of the vapor recoil mechanism in the boiling crisis.

PubMed

Nikolayev, V S; Chatain, D; Garrabos, Y; Beysens, D

2006-11-03

Boiling crisis experiments are carried out in the vicinity of the liquid-gas critical point of H2. A magnetic gravity compensation setup is used to enable nucleate boiling at near critical pressure. The measurements of the critical heat flux that defines the threshold for the boiling crisis are carried out as a function of the distance from the critical point. The obtained power law behavior and the boiling crisis dynamics agree with the predictions of the vapor recoil mechanism and disagree with the classical vapor column mechanism.

Increasing ion and fusion yield in a dense plasma focus by combination of pre-ionization and heavy ion gas admixture

NASA Astrophysics Data System (ADS)

Farmanfarmaei, B.; Yousefi, H. R.; Salem, M. K.; Sari, A. H.

2018-04-01

The results of an experimental study of pre-ionization and heavy gas introduced into driven gas in a plasma focus device are reported. To achieve this purpose, we made use of two methods: first, the pre-ionization method by applying the shunt resistor and second, the admixture of heavy ions. We applied the different shunt resistors and found the optimum amount to be 200 MΩ at an optimum pressure of 0.5 Torr. Ion yield that was measured by array of Faraday cups and the energy of fast ions that was calculated by using the time-of-flight method were raised up to 22% and 45%, and the impurity caused by anode's erosion was reduced approximately by 67% in comparison to when there was no pre-ionization. Also, we have used the admixture of 5% argon ions with nitrogen (working gas) to improve the ion yield up to 45% in comparison with pure nitrogen. Finally, for the first time, we have utilized the combination of these methods together and have, consequently, reached the maximum ion yield and fusion yield. With this new method, ion yield raised up to 70% greater than that of the previous condition, i.e., without pre-ionization and heavy ion admixture.

Process for Nitrogen Oxide Waste Conversion to Fertilizer

NASA Technical Reports Server (NTRS)

Lueck, Dale E. (Inventor); Parrish, Clyde F. (Inventor)

2003-01-01

The present invention describes a process for converting vapor streams from sources containing at least one nitrogen-containing oxidizing agent therein to a liquid fertilizer composition comprising the steps of: a) directing a vapor stream containing at least one nitrogen-containing oxidizing agent to a first contact zone; b) contacting said vapor stream with water to form nitrogen oxide(s) from said at least one nitrogen-containing oxidizing agent; c) directing said acid(s) as a second stream to a second contact zone; d) exposing said second stream to hydrogen peroxide which is present within said second contact zone in a relative amount of at least 0.1% by weight of said second stream within said second contact zone to convert at least some of any nitrogen oxide species or ions other than in the nitrate form present within said second stream to nitrate ion; e) sampling said stream within said second contact zone to determine the relative amount of hydrogen peroxide within said second contact zone; f) adding hydrogen peroxide to said second contact zone when a level of hydrogen peroxide less than 0.1 % by weight in said second stream is determined by said sampling; g) adding a solution comprising potassium hydroxide to said second stream to maintain a pH between 6.0 and 11.0 within said second stream within said second contact zone to form a solution of potassium nitrate; and h) removing said solution of potassium nitrate from said second contact zone.

A gas ionisation detector in the axial (Bragg) geometry used for the time-of-flight elastic recoil detection analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siketić, Zdravko; Skukan, Natko; Bogdanović Radović, Iva

2015-08-15

In this paper, time-of-flight elastic recoil detection analysis spectrometer with a newly constructed gas ionization detector for energy detection is presented. The detector is designed in the axial (Bragg) geometry with a 3 × 3 array of 50 nm thick Si{sub 3}N{sub 4} membranes as an entrance window. 40 mbar isobutane gas was sufficient to stop a 30 MeV primary iodine beam as well as all recoils in the detector volume. Spectrometer and detector performances were determined showing significant improvement in the mass and energy resolution, respectively, comparing to the spectrometer with a standard silicon particle detector for an energymore » measurement.« less

Ion Mobility Studies on the Negative Ion-Molecule Chemistry of Isoflurane and Enflurane.

PubMed

González-Méndez, Ramón; Watts, Peter; Howse, David C; Procino, Immacolata; McIntyre, Henry; Mayhew, Chris A

2017-05-01

In the present work we present an investigation of the negative ion-molecule chemistry of the anaesthetics isoflurane, ISOF, and enflurane, ENF, in an ion mobility spectrometry/mass spectrometry (IMS/MS), in both air and nitrogen. Hexachloroethane (HCE) was introduced in both air and nitrogen to produce Cl - as a reactant ion. This study was undertaken owing to uncertainties in the chemical processes, which lead to the cluster ions reported in other work (Eiceman et al. Anal. Chem. 61, 1093-1099, 1). In particular for ISOF the product ion observed was ISOF.Cl - , and it was suggested that the Cl - was formed by dissociative electron attachment (DEA) although there was mention of a chlorine containing contaminant. We show in this study that ISOF and ENF do not produce Cl - in an IMS system either by capture of free electrons or reaction with O 2 - . This demonstrates that the Cl - containing ions, reported in the earlier study, must have been the result of a chlorine containing contaminant as suggested. The failure of ISOF and ENF to undergo DEA was initially surprising given the high calculated electron affinities, but further calculations showed that this was a result of the large positive vertical attachment energies (VAEs). This experimental work has been supported by electronic structure calculations at the B3LYP level, and is consistent with those obtained in a crossed electron-molecular beam two sector field mass spectrometer. An unusual observation is that the monomer complexes of ISOF and ENF with O 2 - are relatively unstable compared with the dimer complexes. Graphical Abstract ᅟ.

Ion Mobility Studies on the Negative Ion-Molecule Chemistry of Isoflurane and Enflurane

NASA Astrophysics Data System (ADS)

González-Méndez, Ramón; Watts, Peter; Howse, David C.; Procino, Immacolata; McIntyre, Henry; Mayhew, Chris A.

2017-05-01

In the present work we present an investigation of the negative ion-molecule chemistry of the anaesthetics isoflurane, ISOF, and enflurane, ENF, in an ion mobility spectrometry/mass spectrometry (IMS/MS), in both air and nitrogen. Hexachloroethane (HCE) was introduced in both air and nitrogen to produce Cl- as a reactant ion. This study was undertaken owing to uncertainties in the chemical processes, which lead to the cluster ions reported in other work (Eiceman et al. Anal. Chem. 61, 1093-1099, 1). In particular for ISOF the product ion observed was ISOF.Cl-, and it was suggested that the Cl- was formed by dissociative electron attachment (DEA) although there was mention of a chlorine containing contaminant. We show in this study that ISOF and ENF do not produce Cl- in an IMS system either by capture of free electrons or reaction with O2 -. This demonstrates that the Cl- containing ions, reported in the earlier study, must have been the result of a chlorine containing contaminant as suggested. The failure of ISOF and ENF to undergo DEA was initially surprising given the high calculated electron affinities, but further calculations showed that this was a result of the large positive vertical attachment energies (VAEs). This experimental work has been supported by electronic structure calculations at the B3LYP level, and is consistent with those obtained in a crossed electron-molecular beam two sector field mass spectrometer. An unusual observation is that the monomer complexes of ISOF and ENF with O2 - are relatively unstable compared with the dimer complexes.

Quantify the loss of major ions induced by CO2 enrichment and nitrogen addition in subtropical model forest ecosystems

NASA Astrophysics Data System (ADS)

Liu, Juxiu; Zhang, Deqiang; Huang, Wenjuan; Zhou, Guoyi; Li, Yuelin; Liu, Shizhong

2014-04-01

Previous studies have reported that atmospheric CO2 enrichment would increase the ion concentrations in the soil water. However, none of these studies could exactly quantify the amount of ion changes in the soil water induced by elevated CO2 and all of these experiments were carried out only in the temperate areas. Using an open-top chamber design, we studied the effects of CO2 enrichment alone and together with nitrogen (N) addition on soil water chemistry in the subtropics. Three years of exposure to an atmospheric CO2 concentration of 700 ppm resulted in accelerated base cation loss via leaching water below the 70 cm soil profile. The total of base cation (K+ + Na+ + Ca2+ + Mg2+) loss in the elevated CO2 treatment was higher than that of the control by 220%, 115%, and 106% in 2006, 2007, and 2008, respectively. The N treatment decreased the effect of high CO2 treatment on the base cation loss in the leachates. Compared to the control, N addition induced greater metal cation (Al3+ and Mn2+) leaching loss in 2008 and net Al3+ and Mn2+ loss in the high N treatment increased by 100% and 67%, respectively. However, the CO2 treatment decreased the effect of high N treatment on the metal cation loss. Changes of ion export followed by the exposure to the elevated CO2, and N treatments were related to both ion concentrations and leached water amount. We hypothesize that forests in subtropical China might suffer from nutrient limitation and some poisonous metal activation in plant biomass under future global change.

Hierarchically-structured hollow NiO nanospheres/nitrogen-doped graphene hybrid with superior capacity retention and enhanced rate capability for lithium-ion batteries

NASA Astrophysics Data System (ADS)

Chen, Jiayuan; Wu, Xiaofeng; Liu, Ya; Gong, Yan; Wang, Pengfei; Li, Wenhui; Mo, Shengpeng; Tan, Qiangqiang; Chen, Yunfa

2017-12-01

A facile template-free synthesis strategy is demonstrated to fabricate nanostructured NiO/N-doped graphene hybrid, in which NiO hollow nanospheres with hierarchically mesoporous structure are tightly anchored on N-doped graphene matrix. The mesoporous shell of NiO can not only provide sufficient electrode/electrolyte contact areas to accelerate ion diffusion and electron exchange, but also efficiently mitigate the volume change that occurs during long-time reactions. Simultaneously, the reduced graphene oxide with doping nitrogen atoms are employed as effectively conductive backbone, further enhancing the electrochemical performances. When used as anodic material for lithium ion batteries, the synergistic system delivers a reversible capacity up to 1104.6 mAh g-1 after 150 cycles at a current density of 0.08 A g-1 and 422.3 mAh g-1 at a high charging rate of 4 A g-1, which is better than those of the bare counterparts and most other NiO-based materials reported in the previous literatures. The hierarchically hollow NiO nanostructure combined with N-doped graphene matrix provides a promising candidate applied in advanced anode materials for lithium ion batteries.

The Final Merger of Massive Black Holes: Recoils, Gravitational Waves, and Electromagnetic Signatures

NASA Astrophysics Data System (ADS)

Centrella, Joan

2010-03-01

The final merger of two massive black holes produces a powerful burst of gravitational radiation, emitting more energy than all the stars in the observable universe combined. The resulting gravitational waveforms will be easily detectable by the space-based LISA out to redshifts z > 10, revealing the masses and spins of the black holes to high precision. If the merging black holes have unequal masses, or asymmetric spins, the final black hole that forms can recoil with a velocity exceeding 1000 km/s. And, when the black holes merge in the presence of gas and magnetic fields, various types of electromagnetic signals may also be produced. For more than 30 years, scientists have tried to compute black hole mergers using the methods of numerical relativity. The resulting computer codes have been plagued by instabilities, causing them to crash well before the black holes in the binary could complete even a single orbit. Within the past few years, however, this situation has changed dramatically, with a series of remarkable breakthroughs. This talk will focus on new results that are revealing the dynamics and waveforms of binary black hole mergers, recoil velocities, and the possibility of accompanying electromagnetic outbursts. This research is supported in part by NASA grant 06-BEFS06-19 to Goddard Space Flight Center.

Measurements and characteristics of nitrogen-containing compounds in atmospheric particulate matter in Beijing, China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duan, F.K.; Liu, X.D.; He, K.B.

2009-03-15

The total nitrogen (TN) and water-soluble nitrogenous ions were determined by using CHN Elemental Analyzer and ion chromatography method, respectively, from November 24, 1998 to February 12, 1999 in Beijing. The average concentrations of TN, NH{sub 4}{sup +} and NO{sub 3}{sup -} were 10.62 {mu} g N m{sup -3}, 6.67 {mu} g m{sup -3} and 10.01 {mu} g m{sup -3}, respectively. The total inorganic nitrogen (IN) calculated from NH{sub 4}{sup +} and NO{sub 3}{sup -} was 7.45 {mu} g N m{sup -3}, accounting for 70% of TN, i.e., 30% of TN existed as organic nitrogen form (ON). The correlation betweenmore » ON and other pollution tracers showed that, coal combustion, biomass burning, soil humic matter and secondary formation were the important sources of ON in particulate matter in Beijing.« less

Conception of a New Recoil Proton Telescope for Real-Time Neutron Spectrometry in Proton-Therapy

NASA Astrophysics Data System (ADS)

Combe, Rodolphe; Arbor, Nicolas; el Bitar, Ziad; Higueret, Stéphane; Husson, Daniel

2018-01-01

Neutrons are the main type of secondary particles emitted in proton-therapy. Because of the risk of secondary cancer and other late occurring effects, the neutron dose should be included in the out-of-field dose calculations. A neutron spectrometer has to be used to take into account the energy dependence of the neutron radiological weighting factor. Due to its high dependence on various parameters of the irradiation (beam, accelerator, patient), the neutron spectrum should be measured independently for each treatment. The current reference method for the measurement of the neutron energy, the Bonner Sphere System, consists of several homogeneous polyethylene spheres with increasing diameters equipped with a proportional counter. It provides a highresolution reconstruction of the neutron spectrum but requires a time-consuming work of signal deconvolution. New neutron spectrometers are being developed, but the main experimental limitation remains the high neutron flux in proton therapy treatment rooms. A new model of a real-time neutron spectrometer, based on a Recoil Proton Telescope technology, has been developed at the IPHC. It enables a real-time high-rate reconstruction of the neutron spectrum from the measurement of the recoil proton trajectory and energy. A new fast-readout microelectronic integrated sensor, called FastPixN, has been developed for this specific purpose. A first prototype, able to detect neutrons between 5 and 20 MeV, has already been validated for metrology with the AMANDE facility at Cadarache. The geometry of the new Recoil Proton Telescope has been optimized via extensive Geant4 Monte Carlo simulations. Uncertainty sources have been carefully studied in order to improve simultaneously efficiency and energy resolution, and solutions have been found to suppress the various expected backgrounds. We are currently upgrading the prototype for secondary neutron detection in proton therapy applications.

Fragmentation of nitrogen-14 nuclei at 2.1 Gev per nucleon.

NASA Technical Reports Server (NTRS)

Heckman, H. H.; Greiner, D. E.; Lindstrom, P. J.; Bieser, F. S.

1971-01-01

An experiment has been carried out at the bevatron on the nuclear fragmentation of nitrogen-14 ions at an energy of 2.1 billion electron volts (Gev) per nucleon. Because of the near equality of the velocities of the nitrogen-14 beam and the fragmentation products at an angle of 0 deg, we find it possible to identify the nuclear fragments isotopically.

Measurement of Recoil Losses and Ranges for Spallation Products Produced in Proton Interactions with Al, Si, Mg at 200 and 500 MeV

NASA Technical Reports Server (NTRS)

Sisterson, J. M.

2005-01-01

Cosmic rays interact with extraterrestrial materials to produce a variety of spallation products. If these cosmogenic nuclides are produced within an inclusion in such material, then an important consideration is the loss of the product nuclei, which recoil out of the inclusion. Of course, at the same time, some atoms of the product nuclei under study may be knocked into the inclusion from the surrounding material, which is likely to have a different composition to that of the inclusion [1]. For example, Ne-21 would be produced in presolar grains, such as SiC, when irradiated in interstellar space. However, to calculate a presolar age, one needs to know how much 21Ne is retained in the grain. For small grains, the recoil losses might be large [2, 3] To study this effect under laboratory conditions, recoil measurements were made using protons with energies from 66 - 1600 MeV on Si, Al and Ba targets [3, 4, 5].

Test measurement of 7Be(p,γ)8B with the recoil mass separator ERNA

NASA Astrophysics Data System (ADS)

Buompane, R.; De Cesare, N.; Di Leva, A.; D'Onofrio, A.; Gialanella, L.; Romano, M.; De Cesare, M.; Duarte, J. G.; Fülöp, Zs.; Morales-Gallegos, L.; Gyürky, Gy.; Gasques, L. R.; Marzaioli, F.; Palumbo, G.; Porzio, G.; Rapagnani, D.; Roca, V.; Rogalla, D.; Romoli, M.; Sabbarese, C.; Schürmann, D.; Terrasi, F.

2018-06-01

7Be(p,γ)8B has an important role in nuclear astrophysics, having a direct impact on both the high energy component of solar neutrinos and the 7Li abundance after the Big Bang Nucleosynthesis. All direct measurements providing useful information on this reaction so far used the same approach, i.e. a proton beam on a radioactive 7Be target. The overall precision and accuracy of the estimate of the astrophysical rate of this reaction are limited by the discrepancy between the results of existing measurements, possibly due to the complicated stoichiometry and beam induced deterioration of the radioactive targets. The ERNA (European Recoil separator for Nuclear Astrophysics) collaboration planned a new experiment in inverse kinematics exploiting the intense 7Be beam available at CIRCE (Center for Isotopic Research on Cultural and Environmental heritage), Caserta, Italy. The 8B recoils are produced in a windowless hydrogen gas target and detected after the efficient mass separation provided by ERNA. Here we present the commissioning of the experimental setup and a first cross section measurement at E_{cm}≈ 812 keV.

Long-range effect of ion implantation of Raex and Hardox steels

NASA Astrophysics Data System (ADS)

Budzyński, P.; Kamiński, M.; Droździel, A.; Wiertel, M.

2016-09-01

Ion implantation involves introduction of ionized atoms of any element (nitrogen) to metals thanks to the high kinetic energy that they acquired in the electric field. The distribution of nitrogen ions implanted at E = 65 keV energy and D = 1.1017 N+ /cm2 fluence in the steel sample and vacancies produced by them was calculated using the SRIM program. This result was confirmed by RBS measurements. The initial maximum range of the implanted nitrogen ions is ∼⃒0.17 μm. This value is relatively small compared to the influence of nitriding on the thickness surface layer of modified steel piston rings. Measurements of the friction coefficient during the pin-on-disc tribological test were performed under dry friction conditions. The friction coefficient of the implanted sample increased to values characteristic of an unimplanted sample after ca. 1500 measurement cycles. The depth of wear trace is ca. 2.4 μm. This implies that the thickness of the layer modified by the implantation process is ∼⃒2.4 μm and exceeds the initial range of the implanted ions by an order of magnitude. This effect, referred to as a long-range implantation effect, is caused by migration of vacancies and nitrogen atoms into the sample. This phenomenon makes ion implantation a legitimate process of modification of the surface layer in order to enhance the tribological properties of critical components of internal combustion engines such as steel piston rings.

Effect of nitrogen-accommodation ability of electrodes in SiNx-based resistive switching devices

NASA Astrophysics Data System (ADS)

Yang, Mei; Wang, Hong; Ma, Xiaohua; Gao, Haixia; Wang, Bin

2017-12-01

Nitrides could create opportunities of tuning resistive-switching (RS) characteristics due to their different electrical properties and ionic chemistry with oxides. Here, we reported on the effect of nitrogen-accommodation ability of electrodes in SiNx-based RS devices. The Ti/SiNx/Pt devices show a self-compliance bipolar RS with excellent reliability. The W/SiNx/Pt devices provide an unstable RS and fall to an intermediate resistance state (IRS) after a set process. The low resistance states of the Ti/SiNx/Pt devices obey Ohmic conduction and Frenkel-Poole emission from a conductive channel. The IRS of the W/SiNx/Pt devices conforms to Schottky emission and Fowler-Nordheim tunneling from a conductive channel/insulator/electrode structure. A nitrogen-ion-based model is proposed to explain the experimental results. According to the model, the nitrogen-accommodation ability of the electrodes dominates the nitrogen-reservoir size and the nitrogen-ion migration at the metal/SiNx interface, modulating the RS characteristics of the SiNx memory devices.

Nitrogen Ion Form and Spatio-temporal Variation in Root Distribution Mediate Nitrogen Effects on Lifespan of Ectomycorrhizal Roots

NASA Astrophysics Data System (ADS)

Kou, L.; McCormack, M. L.; Chen, W.; Guo, D.; Wang, H.; Li, S.; Gao, W.; Yang, H.

2017-12-01

Background and Aims Absorptive roots active in soil resource uptake are often intimately associated with mycorrhizal fungi, yet it remains unclear how nitrogen (N) loading affects lifespan of absorptive roots associating with ectomycorrhizal (ECM) fungi. Methods Through a three-year minirhizotron experiment, we investigated the responses of ECM lifespan to different rates of N addition and examined the roles of N ion form, rooting depth, seasonal root cohort, and ECM morphotype in mediating the N effects on ECM lifespan in a slash pine (Pinus elliottii) forest in subtropical China. Results High rates of NH4Cl significantly decreased foliar P concentrations and increased foliar N: P ratios, and mean ECM lifespan was negatively correlated to foliar P concentration. N additions generally increased the lifespan of most ectomycorrhizas, but the specific differences were context dependent. N rates and forms exerted significant positive effects on ECM lifespan with stronger effects occurring at high N rates and under ammonium N addition. N additions extended lifespan of ectomycorrhizas in shallower soil and born in spring and autumn, but shortened lifespan of ectomycorrhizas in deeper soil and born in summer and winter. N additions reduced lifespan of dichotomous ectomycorrhizas, but increased lifespan of coralloid ectomycorrhizas. Conclusions The increased ECM lifespan in response to N additions may primarily be driven by the persistent and aggravated P limitation to plants. Our findings highlight the importance of environmental contexts in controlling ECM lifespan and the need to consider potential differences among mycorrhizal morphotypes when studying N—lifespan relationships of absorptive roots in the context of N deposition.

Neutralization by a Corona Discharge Ionizer in Nitrogen Atmosphere

NASA Astrophysics Data System (ADS)

Ikeuchi, Toru; Takahashi, Kazunori; Ohkubo, Takahiro; Fujiwara, Tamiya

An electrostatic neutralization of multilayer-loading silicon wafers is demonstrated using a corona discharge ionizer in nitrogen atmosphere, where ac and dc voltages are applied to two needle electrodes for generation of the negative- and positive-charged particles, respectively. We observe a surface potential of the silicon wafer decreases from ±1kV to ±20V within three seconds. Moreover, the density profiles of the charged particles generated by the electrodes are experimentally and theoretically investigated in nitrogen and air atmospheres. Our results show the possibility that the negative-charged particles contributing to the electrostatic neutralization are electrons and negative ions in nitrogen and air atmospheres, respectively.

Polymer Treatment by Plasma Immersion Ion Implantation of Nitrogen for Formation of Diamond-Like Carbon Film

NASA Astrophysics Data System (ADS)

Tan, Ing Hwie; Ueda, Mario; Kostov, Konstantin; Nascente, Pedro Augusto P.; Demarquette, Nicole Raymonde

2004-09-01

Nitrogen ions were implanted by plasma immersion in Kapton, Mylar and polypropylene, with the objective of forming a diamond-like carbon layer on these polymers. The Raman spectrum of the implanted polypropylene showed typical Diamond-Like Carbon (DLC) graphite (G) and disorder (D) peaks, with an sp3/sp2 hybridization ratio of approximately 0.4 to 0.6. The XPS analysis of the three implanted polymers also showed peaks of C-C and N-C bonds in the sp3 configuration, with hybridization ratios in the same range as the Raman result. The implanted polymers were exposed to oxygen plasma to test the resistance of the polymers to oxygen degradation. Mass loss rate results, however, showed that the DLC layer formed is not sufficiently robust for this application. Nevertheless, the layer formed can be suitable for other applications such as in gas barriers in beverage containers. Further study of implantation conditions may improve the quality of the DLC layer.

Argon ion beam induced surface pattern formation on Si

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hofsäss, H.; Bobes, O.; Zhang, K.

The development of self-organized surface patterns on Si due to noble gas ion irradiation has been studied extensively in the past. In particular, Ar ions are commonly used and the pattern formation was analyzed as function of ion incidence angle, ion fluence, and ion energies between 250 eV and 140 keV. Very few results exist for the energy regime between 1.5 keV and 10 keV and it appears that pattern formation is completely absent for these ion energies. In this work, we present experimental data on pattern formation for Ar ion irradiation between 1 keV and 10 keV and ion incidence angles between 50° and 75°.more » We confirm the absence of patterns at least for ion fluences up to 10{sup 18} ions/cm{sup 2}. Using the crater function formalism and Monte Carlo simulations, we calculate curvature coefficients of linear continuum models of pattern formation, taking into account contribution due to ion erosion and recoil redistribution. The calculations consider the recently introduced curvature dependence of the erosion crater function as well as the dynamic behavior of the thickness of the ion irradiated layer. Only when taking into account these additional contributions to the linear theory, our simulations clearly show that that pattern formation is strongly suppressed between about 1.5 keV and 10 keV, most pronounced at 3 keV. Furthermore, our simulations are now able to predict whether or not parallel oriented ripple patterns are formed, and in case of ripple formation the corresponding critical angles for the whole experimentally studied energies range between 250 eV and 140 keV.« less

Development of a compact ECR ion source for various ion production.

PubMed

Muramatsu, M; Hojo, S; Iwata, Y; Katagiri, K; Sakamoto, Y; Takahashi, N; Sasaki, N; Fukushima, K; Takahashi, K; Suzuki, T; Sasano, T; Uchida, T; Yoshida, Y; Hagino, S; Nishiokada, T; Kato, Y; Kitagawa, A

2016-02-01

There is a desire that a carbon-ion radiotherapy facility will produce various ion species for fundamental research. Although the present Kei2-type ion sources are dedicated for the carbon-ion production, a future ion source is expected that could provide: (1) carbon-ion production for medical use, (2) various ions with a charge-to-mass ratio of 1/3 for the existing Linac injector, and (3) low cost for modification. A prototype compact electron cyclotron resonance (ECR) ion source, named Kei3, based on the Kei series has been developed to correspond to the Kei2 type and to produce these various ions at the National Institute of Radiological Sciences (NIRS). The Kei3 has an outer diameter of 280 mm and a length of 1120 mm. The magnetic field is formed by the same permanent magnet as Kei2. The movable extraction electrode has been installed in order to optimize the beam extraction with various current densities. The gas-injection side of the vacuum chamber has enough space for an oven system. We measured dependence of microwave frequency, extraction voltage, and puller position. Charge state distributions of helium, carbon, nitrogen, oxygen, and neon were also measured.

A confined "microreactor" synthesis strategy to three dimensional nitrogen-doped graphene for high-performance sodium ion battery anodes

NASA Astrophysics Data System (ADS)

Li, Jiajie; Zhang, Yumin; Gao, Tangling; Han, Jiecai; Wang, Xianjie; Hultman, Benjamin; Xu, Ping; Zhang, Zhihua; Wu, Gang; Song, Bo

2018-02-01

In virtue of abundant sodium resources, sodium ion batteries (SIBs) have been regarded as one of the most promising alternatives for large-scale energy storage applications. However, the absence of a suitable anode material makes it difficult to realize these applications. Here, we demonstrate an effective synthesis strategy of using a "microreactor" consisting of melamine fiber (inside) and graphene oxide (GO, outside) to fabricate three dimensional (3D) nitrogen doped (N-doped) graphene as high-performance anode materials for sodium ion batteries. Through a controlled pyrolysis, the inside melamine fiber and the outside GO layer has been converted into N-doped graphene and reduced graphene oxide (r-GO) respectively, and thus the "microreactor" is transformed into interconnected 3D N-doped graphene structures. Such highly desired 3D graphene structures show reversible sodium storage capacities up to ∼305 mA h g-1 after 500 cycles at a current density of 0.2 A g-1 and promising long cycling stability with a stable capacity of ∼198 mA h g-1 at 5 A g-1 after 5000 cycles. The high capacity and superior durability in combination with the facile synthesis procedure of the 3D graphene structure make it a promising anode material for SIBs and other energy storage applications.

Nitrogen containing organic compounds in aerosols: results from TD-PTR-MS measurements during the CALNEX campaign

NASA Astrophysics Data System (ADS)

Holzinger, R.; Timkovsky, J.

2011-12-01

During the CALNEX campaign we deployed a thermal-desorption proton-transfer-reaction mass-spectrometer (TD-PTR-MS) at the Caltech ground site near downtown Los Angeles. The instrument was equipped with a time of flight mass spectrometer and a mass resolution power of ~4000 was realized under field conditions. Mass peaks could be determined at accuracy levels of +/- 3 mDa, which allowed identification by the empirical formula rather than by m/z alone. Over 900 ion species have been detected in aerosols. The largest signals (m/z 18.032, NH4+, and 45.991, NO2+) were attributed to ammonia and nitrate, respectively. 350 ion species accounted for 80% of the total measured mass of organic aerosol species. Of these, 66 species contained one nitrogen atom and 73 species contained two nitrogen atoms. Each group accounted for ~15% of the total measured mass. This suggests a ~30% contribution of nitrogen compounds to the total organic aerosol burden. However, this number could still underestimate the real fraction of nitrogen compounds for two reasons: (1) thermal desorption may cause decomposition of nitrogen compounds. E.g. peroxy nitrates rapidly decompose at temperatures above 100°C and produce NO2 which cannot be detected by the PTR-MS. (2) During protonation nitrogen functional groups may be preferentially lost. E.g. alkyl nitrates typically fragment during protonation in the PTR-MS. A minor fraction of the alkyl nitrates is detected as NO2+ and contributes to the signal at m/z 45.991, however, the majority is detected as alkyl ion without nitrogen. At this point it the overall loss of nitrogen due to these processes is hard to quantify. Our findings suggest that nitrogen chemistry plays a crucial role in producing secondary organic aerosol.

Structural characterization of drug-like compounds by ion mobility mass spectrometry: comparison of theoretical and experimentally derived nitrogen collision cross sections.

PubMed

Campuzano, Iain; Bush, Matthew F; Robinson, Carol V; Beaumont, Claire; Richardson, Keith; Kim, Hyungjun; Kim, Hugh I

2012-01-17

We present the use of drug-like molecules as a traveling wave (T-wave) ion mobility (IM) calibration sample set, covering the m/z range of 122.1-609.3, the nitrogen collision cross-section (Ω(N(2))) range of 124.5-254.3 Å(2) and the helium collision cross-section (Ω(He)) range of 63.0-178.8 Å(2). Absolute Ω(N(2)) and Ω(He) values for the drug-like calibrants and two diastereomers were measured using a drift-tube instrument with radio frequency (RF) ion confinement. T-wave drift-times for the protonated diastereomers betamethasone and dexamethasone are reproducibly different. Calibration of these drift-times yields T-wave Ω(N(2)) values of 189.4 and 190.4 Å(2), respectively. These results demonstrate the ability of T-wave IM spectrometry to differentiate diastereomers differing in Ω(N(2)) value by only 1 Å(2), even though the resolution of these IM experiments were ∼40 (Ω/ΔΩ). Demonstrated through density functional theory optimized geometries and ionic electrostatic surface potential analysis, the small but measurable mobility difference between the two diastereomers is mainly due to short-range van der Waals interactions with the neutral buffer gas and not long-range charge-induced dipole interactions. The experimental RF-confining drift-tube and T-wave Ω(N(2)) values were also evaluated using a nitrogen based trajectory method, optimized for T-wave operating temperature and pressures, incorporating additional scaling factors to the Lennard-Jones potentials. Experimental Ω(He) values were also compared to the original and optimized helium based trajectory methods.

Enhancement of collective atomic recoil lasing due to pump phase modulation

NASA Astrophysics Data System (ADS)

Robb, G. R. M.; Burgess, R. T. L.; Firth, W. J.

2008-10-01

We investigate the effect of a phase-modulated pump beam on collective backscattering [also termed collective atomic recoil lasing (CARL)] by a cold, collisionless atomic gas. We show using a numerical analysis that different regimes can be identified in which the atomic dynamics evolves in a qualitatively different manner during the light-atom interaction, depending on the magnitude of the pump modulation frequency. Our results also demonstrate that phase-modulating the pump field can substantially enhance the backscattered field intensity relative to the case of a monochromatic pump which has been used in CARL experiments to date.

Nitrogen implantation with a scanning electron microscope.

PubMed

Becker, S; Raatz, N; Jankuhn, St; John, R; Meijer, J

2018-01-08

Established techniques for ion implantation rely on technically advanced and costly machines like particle accelerators that only few research groups possess. We report here about a new and surprisingly simple ion implantation method that is based upon a widespread laboratory instrument: The scanning electron microscope. We show that it can be utilized to ionize atoms and molecules from the restgas by collisions with electrons of the beam and subsequently accelerate and implant them into an insulating sample by the effect of a potential building up at the sample surface. Our method is demonstrated by the implantation of nitrogen ions into diamond and their subsequent conversion to nitrogen vacancy centres which can be easily measured by fluorescence confocal microscopy. To provide evidence that the observed centres are truly generated in the way we describe, we supplied a 98% isotopically enriched 15 N gas to the chamber, whose natural abundance is very low. By employing the method of optically detected magnetic resonance, we were thus able to verify that the investigated centres are actually created from the 15 N isotopes. We also show that this method is compatible with lithography techniques using e-beam resist, as demonstrated by the implantation of lines using PMMA.

Determination of ammonia in ethylene using ion mobility spectrometry

NASA Technical Reports Server (NTRS)

Cross, J. H.; Limero, T. F.; Lane, J. L.; Wang, F.

1997-01-01

A simple procedure to analyze ammonia in ethylene by ion mobility spectrometry is described. The spectrometer is operated with a silane polymer membrane., 63Ni ion source, H+ (H2O)n reactant ion, and nitrogen drift and source gas. Ethylene containing parts per billion (ppb) (v/v) concentrations of ammonia is pulled across the membrane and diffuses into the spectrometer. Preconcentration or preseparation is unnecessary, because the ethylene in the spectrometer has no noticeable effect on the analytical results. Ethylene does not polymerize in the radioactive source. Ethylene's flammability is negated by the nitrogen inside the spectrometer. Response to ammonia concentrations between 200 ppb and 1.5 ppm is near linear, and a detection limit of 25 ppb is calculated.

Characterization of Nuclear Recoils in High Pressure Xenon Gas: Towards a Simultaneous Search for WIMP Dark Matter and Neutrinoless Double Beta Decay

DOE PAGES

Renner, J.; Gehman, V. M.; Goldschmidt, A.; ...

2015-03-24

Xenon has recently been the medium of choice in several large scale detectors searching for WIMP dark matter and neutrinoless double beta decay. Though present-day large scale experiments use liquid xenon, the gas phase offers advantages favorable to both types of searches such as improved intrinsic energy resolution and fewer fluctuations in the partition of deposited energy between scintillation and ionization channels. We recently constructed a high pressure xenon gas TPC as a prototype for the NEXT (Neutrino Experiment with a Xenon TPC) neutrinoless double beta decay experiment and have demonstrated the feasibility of 0.5% FWHM energy resolution at themore » 136Xe double beta Q-value with 3-D tracking capabilities. We now present results from this prototype on the simultaneous observation of scintillation and ionization produced by nuclear recoils at approximately 14 bar pressure. The recoils were produced by neutrons of approximately 2-6 MeV emitted from a radioisotope plutonium-beryllium source, and primary scintillation (S1) and electroluminescent photons produced by ionization (S2) were observed. We discuss the potential of gaseous xenon to distinguish between electron and nuclear recoils through the ratio of these two signals S2/S1. From these results combined with the possibility of using columnar recombination to sense nuclear recoil directionality at high pressures we envision a dual-purpose, ton-scale gaseous xenon detector capable of a combined search for WIMP dark matter and neutrinoless double beta decay. This work has been performed within the context of the NEXT collaboration.« less

Mahan polaritons and their lifetime due to hole recoil

NASA Astrophysics Data System (ADS)

Baeten, Maarten; Wouters, Michiel

2015-11-01

We present a theoretical study on polaritons in doped semiconductor microcavities, focussing on a cavity mode that is resonant with the Fermi edge. In agreement with experimental results, the strong light-matter coupling is maintained under very high doping within our ladder diagram approximation. In particular, we find that the polaritons result from the strong admixing of the cavity mode with the Mahan exciton. The upper Mahan polariton, lying in the electron-hole continuum, always remains visible and has a linewidth due to free interband electron-hole creation. The lower Mahan polariton acquires a finite lifetime due to relaxation of the valence band hole if the electron density exceeds a certain critical value. However, if the Rabi splitting exceeds the inverse hole recoil time, the lower polariton lifetime is only limited by the cavity properties.

Process and Equipment for Nitrogen Oxide Waste Conversion to Fertilizer

NASA Technical Reports Server (NTRS)

Lueck, Dale E. (Inventor); Parrish, Clyde F. (Inventor)

2000-01-01

The present invention describes a process for converting vapor streams from sources containing at least one nitrogen-containing oxidizing agent therein to a liquid fertilizer composition comprising the steps of: (1) directing a vapor stream containing at least nitrogen-containing oxidizing agent to a first contact zone; (2) contacting said vapor stream with water to form nitrogen oxide(s) from said at least one nitrogen- containing oxidizing agent; (3) directing said acid(s) as a second stream to a second contact zone; (4) exposing said second stream to hydrogen peroxide which is present within said second contact zone in a relative amount of at least 0.1% by weight of said second stream within said second contact zone to convert at least some of any nitrogen oxide species or ions other than in the nitrite form present within said second stream to nitrate ion; (5) sampling said stream within said second contact zone to determine the relative amount of hydrogen peroxide within said second contact zone; (6) adding hydrogen peroxide to said second contact zone when a level on hydrogen peroxide less than 0.1% by weight in said second stream is determined by said sampling; (7) adding a solution comprising potassium hydroxide to said second stream to maintain a pH between 6.0 and 11.0 within said second stream within said second contact zone to form a solution of potassium nitrate; and (8) removing sais solution of potassium nitrate from said second contact zone.

Production of N[sup +] ions from a multicusp ion beam apparatus

DOEpatents

Kango Leung; Kunkel, W.B.; Walther, S.R.

1993-03-30

A method of generating a high purity (at least 98%) N[sup +] ion beam using a multicusp ion source having a chamber formed by a cylindrical chamber wall surrounded by a plurality of magnets, a filament centrally disposed in said chamber, a plasma electrode having an extraction orifice at one end of the chamber, a magnetic filter having two parallel magnets spaced from said plasma electrode and dividing the chamber into arc discharge and extraction regions. The method includes ionizing nitrogen gas in the arc discharge region of the chamber, maintaining the chamber wall at a positive voltage relative to the filament and at a magnitude for an optimum percentage of N[sup +] ions in the extracted ion beams, disposing a hot liner within the chamber and near the chamber wall to limit recombination of N[sup +] ions into the N[sub 2][sup +] ions, spacing the magnets of the magnetic filter from each other for optimum percentage of N[sup 3] ions in the extracted ion beams, and maintaining a relatively low pressure downstream of the extraction orifice and of a magnitude (preferably within the range of 3-8[times]10[sup [minus]4] torr) for an optimum percentage of N[sup +] ions in the extracted ion beam.

First signal from a broadband cryogenic preamplifier cooled by circulating liquid nitrogen in a 7 T Fourier transform ion cyclotron resonance mass spectrometer.

PubMed

Choi, Myoung Choul; Lee, Jeong Min; Lee, Se Gyu; Choi, Sang Hwan; Choi, Yeon Suk; Lee, Kyung Jae; Kim, SeungYong; Kim, Hyun Sik; Stahl, Stefan

2012-12-18

Despite the outstanding performance of Fourier transform ion cyclotron/mass spectrometry (FTICR/MS), the complexity of the cellular proteome or natural compounds presents considerable challenges. Sensitivity is a key performance parameter of a FTICR mass spectrometer. By improving this parameter, the dynamic range of the instrument can be increased to improve the detection signal of low-abundance compounds or fragment ion peaks. In order to improve sensitivity, a cryogenic detection system was developed by the KBSI (Korean Basic Science Institute) in collaboration with Stahl-Electronics (Mettenheim, Germany). A simple, efficient liquid circulation cooling system was designed and a cryogenic preamplifier implemented inside a FTICR mass spectrometer. This cooling system circulates a cryoliquid from a Dewar to the "liquid circulation unit" through a CF flange to cool a copper block and a cryopreamplifier; the cooling medium is subsequently exhausted into the air. The cryopreamplifier can be operated over a very wide temperature range, from room temperature to low temperature environments (4.2 K). First, ion signals detected by the cryopreamplifier using a circulating liquid nitrogen cooling system were observed and showed a signal-to-noise ratio (S/N) about 130% better than that obtained at room temperature.

Highly dynamic cellular-level response of symbiotic coral to a sudden increase in environmental nitrogen.

PubMed

Kopp, C; Pernice, M; Domart-Coulon, I; Djediat, C; Spangenberg, J E; Alexander, D T L; Hignette, M; Meziane, T; Meibom, A

2013-05-14

Metabolic interactions with endosymbiotic photosynthetic dinoflagellate Symbiodinium spp. are fundamental to reef-building corals (Scleractinia) thriving in nutrient-poor tropical seas. Yet, detailed understanding at the single-cell level of nutrient assimilation, translocation, and utilization within this fundamental symbiosis is lacking. Using pulse-chase (15)N labeling and quantitative ion microprobe isotopic imaging (NanoSIMS; nanoscale secondary-ion mass spectrometry), we visualized these dynamic processes in tissues of the symbiotic coral Pocillopora damicornis at the subcellular level. Assimilation of ammonium, nitrate, and aspartic acid resulted in rapid incorporation of nitrogen into uric acid crystals (after ~45 min), forming temporary N storage sites within the dinoflagellate endosymbionts. Subsequent intracellular remobilization of this metabolite was accompanied by translocation of nitrogenous compounds to the coral host, starting at ~6 h. Within the coral tissue, nitrogen is utilized in specific cellular compartments in all four epithelia, including mucus chambers, Golgi bodies, and vesicles in calicoblastic cells. Our study shows how nitrogen-limited symbiotic corals take advantage of sudden changes in nitrogen availability; this opens new perspectives for functional studies of nutrient storage and remobilization in microbial symbioses in changing reef environments. The methodology applied, combining transmission electron microscopy with nanoscale secondary-ion mass spectrometry (NanoSIMS) imaging of coral tissue labeled with stable isotope tracers, allows quantification and submicrometric localization of metabolic fluxes in an intact symbiosis. This study opens the way for investigations of physiological adaptations of symbiotic systems to nutrient availability and for increasing knowledge of global nitrogen and carbon biogeochemical cycling.

Investigation of hydrogen concentration and hardness of ion irradiated organically modified silicate thin films

NASA Astrophysics Data System (ADS)

Qi, Y.; Prenzel, T.; Harriman, T. A.; Wang, Y. Q.; Lucca, D. A.; Williams, D.; Nastasi, M.; Dong, J.; Mehner, A.

2010-06-01

A study of the effects of ion irradiation of organically modified silicate thin films on the loss of hydrogen and increase in hardness is presented. NaOH catalyzed SiNa wO xC yH z thin films were synthesized by sol-gel processing from tetraethylorthosilicate (TEOS) and methyltriethoxysilane (MTES) precursors and spin-coated onto Si substrates. After drying at 300 °C, the films were irradiated with 125 keV H + or 250 keV N 2+ at fluences ranging from 1 × 10 14 to 2.5 × 10 16 ions/cm 2. Elastic Recoil Detection (ERD) was used to investigate resulting hydrogen concentration as a function of ion fluence and irradiating species. Nanoindentation was used to measure the hardness of the irradiated films. FT-IR spectroscopy was also used to examine resulting changes in chemical bonding. The resulting hydrogen loss and increase in hardness are compared to similarly processed acid catalyzed silicate thin films.

Electrochemical performance of CuNCN for sodium ion batteries and comparison with ZnNCN and lithium ion batteries

NASA Astrophysics Data System (ADS)

Eguia-Barrio, A.; Castillo-Martínez, E.; Klein, F.; Pinedo, R.; Lezama, L.; Janek, J.; Adelhelm, P.; Rojo, T.

2017-11-01

Transition metal carbodiimides (TMNCN) undergo conversion reactions during electrochemical cycling in lithium and sodium ion batteries. Micron sized copper and zinc carbodiimide powders have been prepared as single phase as confirmed by PXRD and IR and their thermal stability has been studied in air and nitrogen atmosphere. CuNCN decomposes at ∼250 °C into CuO or Cu while ZnNCN can be stable until 400 °C and 800 °C in air and nitrogen respectively. Both carbodiimides were electrochemically analysed for sodium and lithium ion batteries. The electrochemical Na+ insertion in CuNCN exhibits a relatively high reversible capacity (300 mAh·g-1) which still indicates an incomplete conversion reaction. This incomplete reaction confirmed by ex-situ EPR analysis, is partly due to kinetic limitations as evidenced in the rate capability experiments and in the constant potential measurements. On the other hand, ZnNCN shows incomplete conversion reaction but with good capacity retention and lower hysteresis as negative electrode for sodium ion batteries. The electrochemical performance of these materials is comparable to that of other materials which operate through displacement reactions and is surprisingly better in sodium ion batteries in comparison with lithium ion batteries.

Phase stability in thermally-aged CASS CF8 under heavy ion irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Meimei; Miller, Michael K.; Chen, Wei-Ying

2015-07-01

The stability of the microstructure of a cast austenitic stainless steel (CASS), before and after heavy ion irradiation, was investigated by atom probe tomography (APT). A CF8 ferrite-austenite duplex alloy was thermally aged at 400 degrees C for 10,000 h. After this treatment, APT revealed nanometer-sized G-phase precipitates and Fe-rich alpha and Cr-enriched alpha' phase separated regions in the ferrite. The thermally-aged CF8 specimen was irradiated with 1 MeV Kr ions to a fluence of 1.88 x 10(19) ions/m(2) at 400 degrees C. After irradiation, APT analysis revealed a strong spatial/dose dependence of the G-phase precipitates and the alpha-alpha' spinodalmore » decomposition in the ferrite. For the G-phase precipitates, the number density increased and the mean size decreased with increasing dose, and the particle size distribution changed considerably under irradiation. The inverse coarsening process can be described by recoil resolution. The amplitude of the alpha-alpha' spinodal decomposition in the ferrite was apparently reduced after heavy ion irradiation. (C) 2015 Elsevier B.V. All rights reserved« less

Precision Isotope Shift Measurements in Calcium Ions Using Quantum Logic Detection Schemes.

PubMed

Gebert, Florian; Wan, Yong; Wolf, Fabian; Angstmann, Christopher N; Berengut, Julian C; Schmidt, Piet O

2015-07-31

We demonstrate an efficient high-precision optical spectroscopy technique for single trapped ions with nonclosed transitions. In a double-shelving technique, the absorption of a single photon is first amplified to several phonons of a normal motional mode shared with a cotrapped cooling ion of a different species, before being further amplified to thousands of fluorescence photons emitted by the cooling ion using the standard electron shelving technique. We employ this extension of the photon recoil spectroscopy technique to perform the first high precision absolute frequency measurement of the 2D(3/2)→2P(1/2) transition in calcium, resulting in a transition frequency of f=346 000 234 867(96)  kHz. Furthermore, we determine the isotope shift of this transition and the 2S(1/2)→2P(1/2) transition for 42Ca+, 44Ca+, and 48Ca+ ions relative to 40Ca+ with an accuracy below 100 kHz. Improved field and mass shift constants of these transitions as well as changes in mean square nuclear charge radii are extracted from this high resolution data.

Chitin: 'Forgotten' Source of Nitrogen: From Modern Chitin to Thermally Mature Kerogen: Lessons from Nitrogen Isotope Ratios

USGS Publications Warehouse

Schimmelmann, A.; Wintsch, R.P.; Lewan, M.D.; DeNiro, M.J.

1998-01-01

Chitinous biomass represents a major pool of organic nitrogen in living biota and is likely to have contributed some of the fossil organic nitrogen in kerogen. We review the nitrogen isotope biogeochemistry of chitin and present preliminary results suggesting interaction between kerogen and ammonium during thermal maturation. Modern arthropod chitin may shift its nitrogen isotope ratio by a few per mil depending on the chemical method of chitin preparation, mostly because N-containing non-amino-sugar components in chemically complex chitin cannot be removed quantitatively. Acid hydrolysis of chemically complex chitin and subsequent ion-chromatographic purification of the "deacetylated chitin-monomer" D-glucosamine (in hydrochloride form) provides a chemically well-defined, pure amino-sugar substrate for reproducible, high-precision determination of ??15N values in chitin. ??15N values of chitin exhibited a variability of about one per mil within an individual's exoskeleton. The nitrogen isotope ratio differed between old and new exoskeletons by up to 4 per mil. A strong dietary influence on the ??15N value of chitin is indicated by the observation of increasing ??15N values of chitin from marine crustaceans with increasing trophic level. Partial biodegradation of exoskeletons does not significantly influence ??15N values of remaining, chemically preserved amino sugar in chitin. Diagenesis and increasing thermal maturity of sedimentary organic matter, including chitin-derived nitrogen-rich moieties, result in humic compounds much different from chitin and may significantly change bulk ??15N values. Hydrous pyrolysis of immature source rocks at 330??C in contact with 15N-enriched NH4Cl, under conditions of artificial oil generation, demonstrates the abiogenic incorporation of inorganic nitrogen into carbon-bound nitrogen in kerogen. Not all organic nitrogen in natural, thermally mature kerogen is therefore necessarily derived from original organic matter, but may

Development of a compact ECR ion source for various ion production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muramatsu, M., E-mail: m-mura@nirs.go.jp; Hojo, S.; Iwata, Y.

2016-02-15

There is a desire that a carbon-ion radiotherapy facility will produce various ion species for fundamental research. Although the present Kei2-type ion sources are dedicated for the carbon-ion production, a future ion source is expected that could provide: (1) carbon-ion production for medical use, (2) various ions with a charge-to-mass ratio of 1/3 for the existing Linac injector, and (3) low cost for modification. A prototype compact electron cyclotron resonance (ECR) ion source, named Kei3, based on the Kei series has been developed to correspond to the Kei2 type and to produce these various ions at the National Institute ofmore » Radiological Sciences (NIRS). The Kei3 has an outer diameter of 280 mm and a length of 1120 mm. The magnetic field is formed by the same permanent magnet as Kei2. The movable extraction electrode has been installed in order to optimize the beam extraction with various current densities. The gas-injection side of the vacuum chamber has enough space for an oven system. We measured dependence of microwave frequency, extraction voltage, and puller position. Charge state distributions of helium, carbon, nitrogen, oxygen, and neon were also measured.« less

Ab initio molecular dynamics investigations of low-energy recoil events in Ni and NiCo

DOE PAGES

Liu, Bin; Yuan, Fenglin; Jin, Ke; ...

2015-10-06

Low-energy recoil events in pure Ni and the equiatomic NiCo alloy are studied using ab initio molecular dynamics simulations. We found that the threshold displacement energies are strongly dependent on orientation and weakly dependent on composition. The minimum threshold displacement energies are along the [1 1 0] direction in both pure Ni and the NiCo alloy. Compared to pure Ni, the threshold displacement energies increase slightly in the NiCo alloy due to stronger bonds in the alloy, irrespective of the element type of the PKA. A single Ni interstitial occupying the center of a tetrahedron formed by four Ni atomsmore » and a <1 0 0> split interstitial is produced in pure Ni by the recoils, while only the <1 0 0> split interstitial is formed in the NiCo alloy. Compared to the replacement sequences in pure Ni, anti-site defect sequences are observed in the alloy, which have high efficiency for both producing defects and transporting energy outside of the cascade core. These results provide insights into energy transfer processes occurring in equiatomic alloys under irradiation.« less

General One-Pot Synthesis of Transition-Metal Phosphide/Nitrogen-Doped Carbon Hybrid Nanosheets as Ultrastable Anodes for Sodium-Ion Batteries.

PubMed

Li, Jingjing; Shi, Liang; Gao, Jingyu; Zhang, Genqiang

2018-01-26

Sodium-ion batteries (SIBs) have been considered as promising energy storage devices in grid-level applications, owing to their largely reduced cost compared with that of lithium-ion batteries. However, the practical application of SIBs has been seriously hindered because of the lack of appropriate anode materials, limited by the thermodynamics perspective, which is one of the central task at current stage. Herein, we have developed a general one-pot strategy for the synthesis of transition-metal phosphide (TMP) based hybrid nanosheets composed of carbon-coated TMP nanoparticles anchored to the surface of nitrogen-doped carbon nanosheets. This facile and cost-effective method is quite universal and holds potential to be further extended to other metal phosphide materials. Significantly, the hybrid nanosheet electrode possesses excellent sodium storage properties as anodes for SIBs, including high specific capacity, an ultra-long cycle life and a remarkable rate performance. This work makes a significant contribution to not only the synthetic methodology of TMP-carbon two-dimensional hybrid nanostructures, but also the application of TMP-based anodes for high-energy SIBs. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Synthesis of Fe16N2 compound Free-Standing Foils with 20 MGOe Magnetic Energy Product by Nitrogen Ion-Implantation

PubMed Central

Jiang, Yanfeng; Mehedi, Md Al; Fu, Engang; Wang, Yongqiang; Allard, Lawrence F.; Wang, Jian-Ping

2016-01-01

Rare-earth-free magnets are highly demanded by clean and renewable energy industries because of the supply constraints and environmental issues. A promising permanent magnet should possess high remanent magnetic flux density (Br), large coercivity (Hc) and hence large maximum magnetic energy product ((BH)max). Fe16N2 has been emerging as one of promising candidates because of the redundancy of Fe and N on the earth, its large magnetocrystalline anisotropy (Ku > 1.0 × 107 erg/cc), and large saturation magnetization (4πMs > 2.4 T). However, there is no report on the formation of Fe16N2 magnet with high Br and large Hc in bulk format before. In this paper, we successfully synthesize free-standing Fe16N2 foils with a coercivity of up to 1910 Oe and a magnetic energy product of up to 20 MGOe at room temperature. Nitrogen ion implantation is used as an alternative nitriding approach with the benefit of tunable implantation energy and fluence. An integrated synthesis technique is developed, including a direct foil-substrate bonding step, an ion implantation step and a two-step post-annealing process. With the tunable capability of the ion implantation fluence and energy, a microstructure with grain size 25–30 nm is constructed on the FeN foil sample with the implantation fluence of 5 × 1017/cm2. PMID:27145983

Synthesis of Fe16N2 compound Free-Standing Foils with 20 MGOe Magnetic Energy Product by Nitrogen Ion-Implantation.

PubMed

Jiang, Yanfeng; Mehedi, Md Al; Fu, Engang; Wang, Yongqiang; Allard, Lawrence F; Wang, Jian-Ping

2016-05-05

Rare-earth-free magnets are highly demanded by clean and renewable energy industries because of the supply constraints and environmental issues. A promising permanent magnet should possess high remanent magnetic flux density (Br), large coercivity (Hc) and hence large maximum magnetic energy product ((BH)max). Fe16N2 has been emerging as one of promising candidates because of the redundancy of Fe and N on the earth, its large magnetocrystalline anisotropy (Ku > 1.0 × 10(7) erg/cc), and large saturation magnetization (4πMs > 2.4 T). However, there is no report on the formation of Fe16N2 magnet with high Br and large Hc in bulk format before. In this paper, we successfully synthesize free-standing Fe16N2 foils with a coercivity of up to 1910 Oe and a magnetic energy product of up to 20 MGOe at room temperature. Nitrogen ion implantation is used as an alternative nitriding approach with the benefit of tunable implantation energy and fluence. An integrated synthesis technique is developed, including a direct foil-substrate bonding step, an ion implantation step and a two-step post-annealing process. With the tunable capability of the ion implantation fluence and energy, a microstructure with grain size 25-30 nm is constructed on the FeN foil sample with the implantation fluence of 5 × 10(17)/cm(2).

Hierarchical Carbon with High Nitrogen Doping Level: A Versatile Anode and Cathode Host Material for Long-Life Lithium-Ion and Lithium-Sulfur Batteries.

PubMed

Reitz, Christian; Breitung, Ben; Schneider, Artur; Wang, Di; von der Lehr, Martin; Leichtweiss, Thomas; Janek, Jürgen; Hahn, Horst; Brezesinski, Torsten

2016-04-27

Nitrogen-rich carbon with both a turbostratic microstructure and meso/macroporosity was prepared by hard templating through pyrolysis of a tricyanomethanide-based ionic liquid in the voids of a silica monolith template. This multifunctional carbon not only is a promising anode candidate for long-life lithium-ion batteries but also shows favorable properties as anode and cathode host material owing to a high nitrogen content (>8% after carbonization at 900 °C). To demonstrate the latter, the hierarchical carbon was melt-infiltrated with sulfur as well as coated by atomic layer deposition (ALD) of anatase TiO2, both of which led to high-quality nanocomposites. TiO2 ALD increased the specific capacity of the carbon while maintaining high Coulombic efficiency and cycle life: the composite exhibited stable performance in lithium half-cells, with excellent recovery of low rate capacities after thousands of cycles at 5C. Lithium-sulfur batteries using the sulfur/carbon composite also showed good cyclability, with reversible capacities of ∼700 mA·h·g(-1) at C/5 and without obvious decay over several hundred cycles. The present results demonstrate that nitrogen-rich carbon with an interconnected multimodal pore structure is very versatile and can be used as both active and inactive electrode material in high-performance lithium-based batteries.

Titan's Topside Ionospheric Composition: Cassini Plasma Spectrometer Ion Mass Spectrometer Measurements

NASA Astrophysics Data System (ADS)

Sittler, Edward; Hartle, Richard; Ali, Ashraf; Cooper, John; Lipatov, Alexander; Simpson, David; Sarantos, Menelaos; Chornay, Dennis; Smith, Todd

2017-01-01

We present ion composition measurements of Titan's topside ionosphere using both T9 and T15 Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) measurements. The IMS is able to make measurements of Titan's ionosphere due to ionospheric outflows as originally reported for the T9 flyby. This allows one to take advantage of the unique capabilities of the CAPS IMS which measures both the mass-per-charge (M/Q) of the ions and the fragments of the ions produced inside the sensor such as carbon, nitrogen and oxygen fragments. Specific attention will be given to such ions as NH4 +, N +, O +, CH4 +, CxHy +, and HCNH + ions as examples. The CAPS IMS uses a time-of-flight (TOF) technique which accelerates ions up to 14.6 kV, so they can pass through ultra-thin carbon foils. Neutral fragments are used to measure the ion M/Q and positive fragments to measure the atomic components. We preliminarily find, by using IMS measurements of T9 and T15 ionospheric outflows, evidence for methane group ions, nitrogen ions, ammonium ions, water group ions and CnHm + ions with n = 2, 3, and 4 within Titan's topside ionosphere. E.C. Sittler acknowledges support at Goddard Space Flight Center by the CAPS Cassini Project from JPL funds under contract # NAS703001TONMO711123/1405851.

Ion-Implanted Diamond Films and Their Tribological Properties

NASA Technical Reports Server (NTRS)

Wu, Richard L. C.; Miyoshi, Kazuhisa; Korenyi-Both, Andras L.; Garscadden, Alan; Barnes, Paul N.

1993-01-01

This paper reports the physical characterization and tribological evaluation of ion-implanted diamond films. Diamond films were produced by microwave plasma, chemical vapor deposition technique. Diamond films with various grain sizes (0.3 and 3 microns) and roughness (9.1 and 92.1 nm r.m.s. respectively) were implanted with C(+) (m/e = 12) at an ion energy of 160 eV and a fluence of 6.72 x 10(exp 17) ions/sq cm. Unidirectional sliding friction experiments were conducted in ultrahigh vacuum (6.6 x 10(exp -7)Pa), dry nitrogen and humid air (40% RH) environments. The effects of C(+) ion bombardment on fine and coarse-grained diamond films are as follows: the surface morphology of the diamond films did not change; the surface roughness increased (16.3 and 135.3 nm r.m.s.); the diamond structures were damaged and formed a thin layer of amorphous non-diamond carbon; the friction coefficients dramatically decreased in the ultrahigh vacuum (0.1 and 0.4); the friction coefficients decreased slightly in the dry nitrogen and humid air environments.

Recent changes in anthropogenic reactive nitrogen compounds

NASA Astrophysics Data System (ADS)

Andronache, Constantin

2014-05-01

Significant anthropogenic perturbations of the nitrogen cycle are the result of rapid population growth, with mounting need for food and energy production. The increase of reactive nitrogen compounds (such as NOx, HNO3, NH3, and N2O) has a significant impact on human health, environment, and climate. NOx emissions contribute to O3 chemistry, aerosol formation and acidic precipitation. Ammonia is a notable atmospheric pollutant that may deteriorate ecosystems and contribute to respiratory problems. It reacts with acidic gases to form aerosols or is deposited back to ecosystems. The application of fertilizers accounts for most of the N2O production, adding to greenhouse gas emissions. We analyze the change of some reactive nitrogen compounds based on observations, in eastern United States. Results show that the control of NOx and SO2 emissions over the last decades caused a significant decrease of acidic deposition. The nitrate deposition is highest in eastern US, while the ammonium ion concentration is highest in central US regions. Overall, the inorganic nitrogen wet deposition from nitrate and ammonium is enhanced in central, and eastern US. Research shows that sensitive ecosystems in northeastern regions exhibit a slow recovery from the accumulated effects of acidic deposition. Given the growing demand for nitrogen in agriculture and industry, we discuss possible pathways to reduce the impact of excess reactive nitrogen on the environment.

Rapid estimation of organic nitrogen in oil shale waste waters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, B.M.; Daughton, C.G.; Harris, G.J.

1984-04-01

Many of the characteristics of oil shale process waste waters (e.g., malodors, color, and resistance to biotreatment) are imparted by numerous nitrogenous heterocycles and aromatic amines. For the frequent performance assessment of waste treatment processes designed to remove these nitrogenous organic compounds, a rapid and colligative measurement of organic nitrogen is essential. Quantification of organic nitrogen in biological and agricultural samples is usually accomplished using the time-consuming, wet-chemical Kjeldahl method. For oil shale waste waters, whose primary inorganic nitorgen constituent is amonia, organic Kjeldahl nitrogen (OKN) is determined by first eliminating the endogenous ammonia by distillation and then digesting themore » sample in boiling H/sub 2/SO/sub 4/. The organic material is oxidized, and most forms of organically bound nitrogen are released as ammonium ion. After the addition of base, the ammonia is separated from the digestate by distillation and quantified by acidimetric titrimetry or colorimetry. The major failings of this method are the loss of volatile species such as aliphatic amines (during predistillation) and the inability to completely recover nitrogen from many nitrogenous heterocycles (during digestion). Within the last decade, a new approach has been developed for the quantification of total nitrogen (TN). The sample is first combusted, a« less

High Energy Density Lithium Primary Cells Using Nitrogen Containing Polymer Positives.

DTIC Science & Technology

1983-12-01

the charges were stabilized on heteroatoms, particularly nitro- gen. A positive charge would be stored in the form of an ammonium ion. in a high...operate reversibly. 2.0 POLYMERIC CATHODES A polymer which might be expected to exemplify charge stabilization by nitrogen is poly-N-methylpyrrole (PMP...This material is electronically conductive and might store one charge per nitrogen atom. ox. PMP;4 N3 red. I N + N+ An additional, seductive attraction

Production of N.sup.+ ions from a multicusp ion beam apparatus

DOEpatents

Leung, Ka-Ngo; Kunkel, Wulf B.; Walther, Steven R.

1993-01-01

A method of generating a high purity (at least 98%) N.sup.+ ion beam using a multicusp ion source (10) having a chamber (11) formed by a cylindrical chamber wall (12) surrounded by a plurality of magnets (13), a filament (57) centrally disposed in said chamber, a plasma electrode (36) having an extraction orifice (41) at one end of the chamber, a magnetic filter having two parallel magnets (21, 22) spaced from said plasma electrode (36) and dividing the chamber (11) into arc discharge and extraction regions. The method includes ionizing nitrogen gas in the arc discharge region of the chamber (11), maintaining the chamber wall (12) at a positive voltage relative to the filament (57) and at a magnitude for an optimum percentage of N.sup.+ ions in the extracted ion beams, disposing a hot liner (45) within the chamber and near the chamber wall (12) to limit recombination of N.sup.+ ions into the N.sub.2.sup.+ ions, spacing the magnets (21, 22) of the magnetic filter from each other for optimum percentage of N.sup.3 ions in the extracted ion beams, and maintaining a relatively low pressure downstream of the extraction orifice and of a magnitude (preferably within the range of 3-8.times.10.sup.-4 torr) for an optimum percentage of N.sup.+ ions in the extracted ion beam.

Control of ion content and nitrogen species using a mixed chemistry plasma for GaN grown at extremely high growth rates >9 μm/h by plasma-assisted molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Gunning, Brendan P.; Clinton, Evan A.; Merola, Joseph J.; Doolittle, W. Alan; Bresnahan, Rich C.

2015-10-01

Utilizing a modified nitrogen plasma source, plasma assisted molecular beam epitaxy (PAMBE) has been used to achieve higher growth rates in GaN. A higher conductance aperture plate, combined with higher nitrogen flow and added pumping capacity, resulted in dramatically increased growth rates up to 8.4 μm/h using 34 sccm of N2 while still maintaining acceptably low operating pressure. It was further discovered that argon could be added to the plasma gas to enhance growth rates up to 9.8 μm/h, which was achieved using 20 sccm of N2 and 7.7 sccm Ar flows at 600 W radio frequency power, for which the standard deviation of thickness was just 2% over a full 2 in. diameter wafer. A remote Langmuir style probe employing the flux gauge was used to indirectly measure the relative ion content in the plasma. The use of argon dilution at low plasma pressures resulted in a dramatic reduction of the plasma ion current by more than half, while high plasma pressures suppressed ion content regardless of plasma gas chemistry. Moreover, different trends are apparent for the molecular and atomic nitrogen species generated by varying pressure and nitrogen composition in the plasma. Argon dilution resulted in nearly an order of magnitude achievable growth rate range from 1 μm/h to nearly 10 μm/h. Even for films grown at more than 6 μm/h, the surface morphology remained smooth showing clear atomic steps with root mean square roughness less than 1 nm. Due to the low vapor pressure of Si, Ge was explored as an alternative n-type dopant for high growth rate applications. Electron concentrations from 2.2 × 1016 to 3.8 × 1019 cm-3 were achieved in GaN using Ge doping, and unintentionally doped GaN films exhibited low background electron concentrations of just 1-2 × 1015 cm-3. The highest growth rates resulted in macroscopic surface features due to Ga cell spitting, which is an engineering challenge still to be addressed. Nonetheless, the dramatically enhanced growth rates demonstrate

Monsters on the move: A search for supermassive black holes undergoing gravitational wave recoil

NASA Astrophysics Data System (ADS)

Jadhav, Yashashree; Robinson, Andrew; Lena, Davide

2018-01-01

There is compelling evidence that supermassive black holes (SMBH) reside at the centers of all large galaxies and are the gravitational ‘engines’ of Active Galactic Nuclei (AGN). Furthermore, galaxy mergers are thought to have played a fundamental role in the growth and evolution of the largest galaxies in the nearby universe. A galaxy merger is expected to lead to the formation of an SMBH binary, which itself eventually coalesces through the emission of gravitational waves. Such events fall outside the frequency range accessible to the LIGO/VIRGO gravitational wave detectors, but they can be detected via electromagnetic signatures. Numerical relativity simulations show that, depending on the initial spin-orbit configuration of the binary, the merged SMBH receives a gravitational recoil kick that may reach several 1000km/s. This recoil in turn causes the merged SMBH to oscillate for up to ~1 Gyr in the gravitational potential well of the galaxy. During this time, the recoiling SMBH may be observed as a ‘displaced’ AGN. Such events provide a strong test of gravitational physics and the formation and merger frequencies of binary SMBH. As a result of residual oscillations, displacements ~10 – 100pc may be expected even in nearby elliptical galaxies and can be measured as spatial offsets in high resolution optical or infrared images. We present the results of a preliminary study, in which isophotal analysis was conducted for a sample of 96 galaxies to obtain the photocenter of the galaxies using Hubble Space Telescope (HST) archival optical or infrared WFC2/PC, ACS or NICMOS images. The position of the nuclear point source (AGN) was also measured to obtain a displacement vector. This initial sample reveals 18 candidates that show a significant displacement. Of these, 14 are hosted by core ellipticals, while the rest have a cuspy light profile. As galactic and nuclear dust structures may interfere with the isophotal analysis, we are currently obtaining new WFC

Ion Beam Irradiation Studies Of Ultrananocrystalline Diamond (UNCD)

NASA Astrophysics Data System (ADS)

Kayani, A.; Garratt, E.; AlFaify, S.; Dissanayake, A.; Tecos, G.; Mancini, D. C.; Syed, M.

2011-06-01

Investigations into the effects of high-energy ion bombardment of ultrananocrystalline diamond (UNCD) thin films was performed using 3 and 6 MeV protons and 24 MeV F4+, with the fluence of 2.1×1017 ions/cm2, 2.9×1017 ions/cm2, and 6.7×1015 ions/cm2 respectively. Objective of the research is to investigate the effect of structural damage on the physical properties of the material and compare it with the structure of unirradiated and N doped UNCD. Pre- and post-irradiated samples were analyzed by ion beam analysis (IBA) measurements, Raman spectroscopy, atomic force microscopy (AFM) and scanning electron microscopy (SEM). IBA measurements including Rutherford backscattering spectrometry (RBS), non-Rutherford backscattering spectrometry (NRBS) and elastic recoil detection analysis (ERDA) were used to determine elemental concentration of pre- and post-irradiated samples. Visible Raman spectra corresponding to samples irradiated at 3 and 6 MeV protons did not show much variation. For 24 MeV F4+ irradiated sample, significant changes were observed, particularly the loss of a shoulder at 1179 cm-1 and sharpening of the G peak at around 1532 cm-1, indicating possible significant changes at the grain boundary and increase in sp2 phase. AFM measurements show a reduction in RMS roughness after bombardment possibly due to the graphitization of the UNCD surface. The results of IBA measurements did not show any change in the elemental concentration or interface region between film and substrate.

Nitrogen deposition in precipitation to a monsoon-affected eutrophic embayment: Fluxes, sources, and processes

NASA Astrophysics Data System (ADS)

Wu, Yunchao; Zhang, Jingping; Liu, Songlin; Jiang, Zhijian; Arbi, Iman; Huang, Xiaoping; Macreadie, Peter Ian

2018-06-01

Daya Bay in the South China Sea (SCS) has experienced rapid nitrogen pollution and intensified eutrophication in the past decade due to economic development. Here, we estimated the deposition fluxes of nitrogenous species, clarified the contribution of nitrogen from precipitation and measured ions and isotopic composition (δ15N and δ18O) of nitrate in precipitation in one year period to trace its sources and formation processes among different seasons. We found that the deposition fluxes of total dissolved nitrogen (TDN), NO3-, NH4+, NO2-, and dissolved organic nitrogen (DON) to Daya Bay were 132.5, 64.4 17.5, 1.0, 49.6 mmol m-2•yr-1, respectively. DON was a significant contributor to nitrogen deposition (37% of TDN), and NO3- accounted for 78% of the DIN in precipitation. The nitrogen deposition fluxes were higher in spring and summer, and lower in winter. Nitrogen from precipitation contributed nearly 38% of the total input of nitrogen (point sources input and dry and wet deposition) in Daya Bay. The δ15N-NO3- abundance, ion compositions, and air mass backward trajectories implicated that coal combustion, vehicle exhausts, and dust from mainland China delivered by northeast monsoon were the main sources in winter, while fossil fuel combustion (coal combustion and vehicle exhausts) and dust from PRD and southeast Asia transported by southwest monsoon were the main sources in spring; marine sources, vehicle exhausts and lightning could be the potential sources in summer. δ18O results showed that OH pathway was dominant in the chemical formation process of nitrate in summer, while N2O5+ DMS/HC pathways in winter and spring.

Linked gas chromatograph-thermal energy analyzer/ion trap mass spectrometer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alcaraz, A.; Martin, W.H.; Andresen, B.D.

1991-05-01

The capability of comparing a nitrogen chromatogram generated from a gas chromatograph (GC, Varian model 3400) linked to a thermal energy analyzer (TEA, Thermedics Inc. Model 610) with a total ion chromatogram (from a Finnigan-MAT Ion Trap Mass Spectrometer, ITMS) has provided a new means to screen and identifying trace levels of nitrogen-containing compounds in complex mixtures. Prior to the work described here, it has not been possible to simultaneously acquire TEA and MS data. What was needed was a viable GC-TEA/ITMS interface to combine the capabilities of both instruments. 4 figs.

Nitrogen doping, optical characterization, and electron emission study of diamond

NASA Astrophysics Data System (ADS)

Park, Minseo

Nitrogen-doped chemical vapor deposited (CVD) diamond films were synthesized with N2 (nitrogen) and C3H6N6 (melamine) as doping sources. More effective substitutional nitrogen doping was achieved with C3H6N6 than with N 2. Since a melamine molecule has an existing cyclic C-N bonded ring, it is expected that the incorporation of nitrogen on substitution diamond lattice should be facilitated. The diamond film doped with N2 contained a significant amount of non-diamond carbon phases. The samples were analyzed by scanning electron microscopy, Raman scattering, photoluminescence spectroscopy, and field emission measurements. The sample produced using N 2 exhibited a lower field emission turn-on field than the sample produced using C3H6N6. It is believed that the presence of the graphitic phases (or amorphous sp2 carbon) at the grain boundaries of the diamond and/or the nanocrystallinity (or microcrystallinity) of the diamond play a significant role in lowering the turn-on field of the film produced using N2. The nature of the nitrogen-related 1190 cm-1 Raman peak was investigated. Nitrogen is incorporated predominantly to the crystalline or amorphous sp2 phases when nitrogen is added to the growing diamond. Field emission characteristics from metallic field emitter coated with type Ia and Ib diamond powders were also investigated. No significant difference in electron emission characteristics were found in these samples. Voltage-dependent field emission energy distribution (V-FEED) measurement was performed to analyze the energy distribution of the emitted electrons. It is believed that substitutional nitrogen doping plays only a minor role in changing field emission characteristics in diamond. Discontinuous diamond films were deposited on silicon using a microwave plasma chemical vapor deposition (MPCVD) system. The diamond deposits were sharpened by argon ion beam etching. Raman spectroscopy was carried out to study the structural change of the diamond after ion beam

Highly Dynamic Cellular-Level Response of Symbiotic Coral to a Sudden Increase in Environmental Nitrogen

PubMed Central

Kopp, C.; Pernice, M.; Domart-Coulon, I.; Djediat, C.; Spangenberg, J. E.; Alexander, D. T. L.; Hignette, M.; Meziane, T.; Meibom, A.

2013-01-01

ABSTRACT Metabolic interactions with endosymbiotic photosynthetic dinoflagellate Symbiodinium spp. are fundamental to reef-building corals (Scleractinia) thriving in nutrient-poor tropical seas. Yet, detailed understanding at the single-cell level of nutrient assimilation, translocation, and utilization within this fundamental symbiosis is lacking. Using pulse-chase 15N labeling and quantitative ion microprobe isotopic imaging (NanoSIMS; nanoscale secondary-ion mass spectrometry), we visualized these dynamic processes in tissues of the symbiotic coral Pocillopora damicornis at the subcellular level. Assimilation of ammonium, nitrate, and aspartic acid resulted in rapid incorporation of nitrogen into uric acid crystals (after ~45 min), forming temporary N storage sites within the dinoflagellate endosymbionts. Subsequent intracellular remobilization of this metabolite was accompanied by translocation of nitrogenous compounds to the coral host, starting at ~6 h. Within the coral tissue, nitrogen is utilized in specific cellular compartments in all four epithelia, including mucus chambers, Golgi bodies, and vesicles in calicoblastic cells. Our study shows how nitrogen-limited symbiotic corals take advantage of sudden changes in nitrogen availability; this opens new perspectives for functional studies of nutrient storage and remobilization in microbial symbioses in changing reef environments. PMID:23674611

Valence and inner-valence shell dissociative photoionization of CO in the 26-33 eV range. II. Molecular-frame and recoil-frame photoelectron angular distributions.

PubMed

Lebech, M; Houver, J C; Raseev, G; dos Santos, A S; Dowek, D; Lucchese, Robert R

2012-03-07

Experimental and theoretical results for molecular-frame photoemission are presented for inner-valence shell photoionization of the CO molecule induced by linearly and circularly polarized light. The experimental recoil frame photoelectron angular distributions (RFPADs) obtained from dissociative photoionization measurements where the velocities of the ionic fragment and photoelectron were detected in coincidence, are compared to RFPADs computed using the multichannel Schwinger configuration interaction method. The formalism for including a finite lifetime of the predissociative ion state is presented for the case of general elliptically polarized light, to obtain the RFPAD rather than the molecular frame photoelectron angular distribution (MFPAD), which would be obtained with the assumption of instantaneous dissociation. We have considered photoionization of CO for the photon energies of 26.0 eV, 29.5 eV, and 32.5 eV. A comparison of experimental and theoretical RFPADs allows us to identify the ionic states detected in the experimental studies. In addition to previously identified states, we found evidence for the 2 (2)Δ state with an ionization potential of 25.3 eV and (2)Σ(+) states with ionization potentials near 32.5 eV. A comparison of the experimental and theoretical RFPADs permits us to estimate predissociative lifetimes of 0.25-1 ps for some of the ion states. Consideration of the MFPADs of a series of (2)Π ion states indicates the importance of inter-channel coupling at low photoelectron kinetic energy and the limitations of a single-channel analysis based on the corresponding Dyson orbitals. © 2012 American Institute of Physics

Effect of 120 MeV Ag9+ ion irradiation of YCOB single crystals

NASA Astrophysics Data System (ADS)

Arun Kumar, R.; Dhanasekaran, R.

2012-09-01

Single crystals of yttrium calcium oxy borate (YCOB) grown from boron-tri-oxide flux were subjected to swift heavy ion irradiation using silver Ag9+ ions from the 15 UD Pelletron facility at Inter University Accelerator Center, New Delhi. The crystals were irradiated at 1 × 1013, 5 × 1013 and 1 × 1014 ions/cm2 fluences at room temperature and with 5 × 1013 ions/cm2 fluence at liquid nitrogen temperature. The pristine and the irradiated samples were characterized by glancing angle X-ray diffraction, UV-Vis-NIR and photoluminescence studies. From the characterization studies performed on the samples, it is inferred that the crystals irradiated at liquid nitrogen temperature had fewer defects compared to the crystals irradiated at room temperature and the defects increased when the ion fluence was increased at room temperature.

The role of nitrogen ions in the ring current dynamics

NASA Astrophysics Data System (ADS)

Ilie, R.; Liemohn, M. W.; Dandouras, I. S.

2017-12-01

Changes in the ion composition throughout the Earth's magnetosphere can have profound implications on plasma structures and dynamics, since it can modify the temperature and the magnetic field configuration, altering the convection patterns inside the magnetosphere. The ratio of hydrogen to oxygen ions has been shown to be highly dependent of geomagnetic activity, with the O+ content increasing with increasing activity. This suggests that ions of ionospheric origin can become the dominant species in the inner magnetosphere during disturbed times. Therefore, numerous studies have focused on the transport and energization of O+ through the ionosphere-magnetosphere system; however, relatively few have considered the contribution of N+, in addition to that of O+ to the near-Earth plasma dynamics, even though past observations have established that N+ is a significant ion species in the ionosphere and its presence in the magnetosphere is significant. Ring current observations from the Active Magnetospheric Particle Tracer Explorer (AMPTE) spacecraft show that high energy N+ fluxes are comparable to those of O+ during disturbed times, confirming the substantial presence of N+ions in the inner magnetosphere. In spite of only 12% mass difference, N+ and O+ have different ionization potentials, scale heights and charge exchange cross sections. The latter, together with the geocoronal density distribution, plays a key role in the formation of Energetic Neutral Atoms (ENAs), which in turn control the energy budget of the inner magnetosphere and the decay of the ring current. Numerical simulations using the Hot Electron and Ion Drift Integrator (HEIDI) model suggest that the contribution of N+ to the ring current dynamics is significant, as the presence of N+, in addition to that of O+, alters the development and the decay rate of the ring current. These findings suggest that differentiating the N+ transport from that of O+ in the near-Earth environment has a profound impact

Analysis of a Compressible Fluid Soft Recoil (CFSR) Concept Applied to a 155 MM Howitzer

DTIC Science & Technology

1979-03-01

Nitrile or Buna-N ( NBR ) rubber with ’ backup rings of nylotron. HITRILE NVLOTRON Piston seals An unresolved problem is that the coefficient of...fluid at atmospheric pressure Poisson’s ratio for Nitrile rubber dynamic coefficient of friction for rubber mass of recoiling parts weight of...Greene, tweed 5 Co. Palmetto catalog.) 43 [i^ - 0.50 = coefficient of friction (An approximate figure for rubber supplied by RIA Rubber

Evidence for age-dependent air-space enlargement contributing to loss of lung tissue elastic recoil pressure and increased shear modulus in older age.

PubMed

Subramaniam, K; Kumar, H; Tawhai, M H

2017-07-01

As a normal part of mature aging, lung tissue undergoes microstructural changes such as alveolar air-space enlargement and redistribution of collagen and elastin away from the alveolar duct. The older lung also experiences an associated decrease in elastic recoil pressure and an increase in specific tissue elastic moduli, but how this relates mechanistically to microstructural remodeling is not well-understood. In this study, we use a structure-based mechanics analysis to elucidate the contributions of age-related air-space enlargement and redistribution of elastin and collagen to loss of lung elastic recoil pressure and increase in tissue elastic moduli. Our results show that age-related geometric changes can result in reduction of elastic recoil pressure and increase in shear and bulk moduli, which is consistent with published experimental data. All elastic moduli were sensitive to the distribution of stiffness (representing elastic fiber density) in the alveolar wall, with homogenous stiffness near the duct and through the septae resulting in a more compliant tissue. The preferential distribution of elastic proteins around the alveolar duct in the healthy young adult lung therefore provides for a more elastic tissue. NEW & NOTEWORTHY We use a structure-based mechanics analysis to correlate air-space enlargement and redistribution of elastin and collagen to age-related changes in the mechanical behavior of lung parenchyma. Our study highlights that both the cause (redistribution of elastin and collagen) and the structural effect (alveolar air-space enlargement) contribute to decline in lung tissue elastic recoil with age; these results are consistent with published data and provide a new avenue for understanding the mechanics of the older lung. Copyright © 2017 the American Physiological Society.

Dispersion in a thermal plasma including arbitrary degeneracy and quantum recoil.

PubMed

Melrose, D B; Mushtaq, A

2010-11-01

The longitudinal response function for a thermal electron gas is calculated including two quantum effects exactly, degeneracy, and the quantum recoil. The Fermi-Dirac distribution is expanded in powers of a parameter that is small in the nondegenerate limit and the response function is evaluated in terms of the conventional plasma dispersion function to arbitrary order in this parameter. The infinite sum is performed in terms of polylogarithms in the long-wavelength and quasistatic limits, giving results that apply for arbitrary degeneracy. The results are applied to the dispersion relations for Langmuir waves and to screening, reproducing known results in the nondegenerate and completely degenerate limits, and generalizing them to arbitrary degeneracy.

Compositional analysis and depth profiling of thin film CrO{sub 2} by heavy ion ERDA and standard RBS: a comparison

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khamlich, S., E-mail: skhamlich@gmail.com; Department of Chemistry, Tshwane University of Technology, Private Bag X 680, Pretoria, 0001; The African Laser Centre, CSIR campus, P.O. Box 395, Pretoria

2012-08-15

Chromium dioxide (CrO{sub 2}) thin film has generated considerable interest in applied research due to the wide variety of its technological applications. It has been extensively investigated in recent years, attracting the attention of researchers working on spintronic heterostructures and in the magnetic recording industry. However, its synthesis is usually a difficult task due to its metastable nature and various synthesis techniques are being investigated. In this work a polycrystalline thin film of CrO{sub 2} was prepared by electron beam vaporization of Cr{sub 2}O{sub 3} onto a Si substrate. The polycrystalline structure was confirmed through XRD analysis. The stoichiometry andmore » elemental depth distribution of the deposited film were measured by ion beam nuclear analytical techniques heavy ion elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry (RBS), which both have relative advantage over non-nuclear spectrometries in that they can readily provide quantitative information about the concentration and distribution of different atomic species in a layer. Moreover, the analysis carried out highlights the importance of complementary usage of the two techniques to obtain a more complete description of elemental content and depth distribution in thin films. - Graphical abstract: Heavy ion elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry (RBS) both have relative advantage over non-nuclear spectrometries in that they can readily provide quantitative information about the concentration and distribution of different atomic species in a layer. Highlights: Black-Right-Pointing-Pointer Thin films of CrO{sub 2} have been grown by e-beam evaporation of Cr{sub 2}O{sub 3} target in vacuum. Black-Right-Pointing-Pointer The composition was determined by heavy ion-ERDA and RBS. Black-Right-Pointing-Pointer HI-ERDA and RBS provided information on the light and heavy elements, respectively.« less

Processing of N2O ice by fast ions: implications on nitrogen chemistry in cold astrophysical environments

NASA Astrophysics Data System (ADS)

Almeida, G. C.; Pilling, S.; de Barros, A. L. F.; da Costa, C. A. P.; Pereira, R. C.; da Silveira, E. F.

2017-10-01

Nitrous oxide, N2O, is found in the interstellar medium associated with dense molecular clouds and its abundance is explained by active chemistry occurring on N2 rich ice surfaces of dust grains. Such regions are being constantly exposed to ionizing radiation that triggers chemical processes which change molecular abundances with time. Due to its non-zero dipole moment, N2O can be used as an important tracer for the abundance of N2 in such regions as well as for characterization of nitrogen content of ices in outer bodies of Solar system. In this work, we experimentally investigate the resistance of frozen N2O molecules against radiation in attempt to estimate their half-life in astrophysical environments. All the radiolysis products, such as NO2 and NO, were identified by Fourier transform infrared spectroscopy. The infrared absorbance as a function of fluence is modified by ice compaction and by radiolysis, the compaction being dominant at the beginning of the ice processing. The N2O destruction cross-section as well the formation cross-sections of the products NxOy (x = 1-2 and y = 1-5) oxides and ozone (O3) by 1.5 MeV 14N+ ion beam are determined. The characterization of radiation resistance of N2O in cold astrophysical environments is relevant since it yields limits for the nitrogen abundance where the N2O molecule is used to indirectly derive its concentration. The half-life of solid N2O molecules dissociated by medium-mass cosmic rays at Pluto's orbit and at the interstellar medium is estimated.

Conceptual study of a heavy-ion-ERDA spectrometer for energies below 6 MeV

NASA Astrophysics Data System (ADS)

Julin, Jaakko; Sajavaara, Timo

2017-09-01

Elastic recoil detection analysis (ERDA) is a well established technique and it offers unique capabilities in thin film analysis. Simultaneous detection and depth profiling of all elements, including hydrogen, is possible only with time-of-flight ERDA. Bragg ionization chambers or ΔE - E detectors can also be used to identify the recoiling element if sufficiently high energies are used. The chief limitations of time-of-flight ERDA are the beam induced sample damage and the requirement of a relatively large accelerator. In this paper we propose a detector setup, which could be used with 3 MeV to 6 MeV medium heavy beams from either a single ended accelerator (40Ar) or from a tandem accelerator (39K). The detector setup consists of two timing detectors and a gas ionization chamber energy detector. Compared to use of very heavy low energy ions the hydrogen recoils with this beam have sufficient energy to be detected with current gas ionization chamber energy detector. To reduce the beam induced damage the proposed detector setup covers a solid angle larger than 1 msr, roughly an order of magnitude improvement over most time-of-flight ERDA setups. The setup could be used together with a small accelerator to be used for light element analysis of approximately 50 nm films. The concept is tested with 39K beam from a 1.7 MV Pelletron tandem accelerator with the Jyväskylä ToF-ERDA setup. In addition to the measurements effects related to low energies and increase in the solid angle are simulated with Monte Carlo methods.

Formation of nitrogenated organic aerosols in the Titan upper atmosphere.

PubMed

Imanaka, Hiroshi; Smith, Mark A

2010-07-13

Many aspects of the nitrogen fixation process by photochemistry in the Titan atmosphere are not fully understood. The recent Cassini mission revealed organic aerosol formation in the upper atmosphere of Titan. It is not clear, however, how much and by what mechanism nitrogen is incorporated in Titan's organic aerosols. Using tunable synchrotron radiation at the Advanced Light Source, we demonstrate the first evidence of nitrogenated organic aerosol production by extreme ultraviolet-vacuum ultraviolet irradiation of a N(2)/CH(4) gas mixture. The ultrahigh-mass-resolution study with laser desorption ionization-Fourier transform-ion cyclotron resonance mass spectrometry of N(2)/CH(4) photolytic solid products at 60 and 82.5 nm indicates the predominance of highly nitrogenated compounds. The distinct nitrogen incorporations at the elemental abundances of H(2)C(2)N and HCN, respectively, are suggestive of important roles of H(2)C(2)N/HCCN and HCN/CN in their formation. The efficient formation of unsaturated hydrocarbons is observed in the gas phase without abundant nitrogenated neutrals at 60 nm, and this is confirmed by separately using (13)C and (15)N isotopically labeled initial gas mixtures. These observations strongly suggest a heterogeneous incorporation mechanism via short lived nitrogenated reactive species, such as HCCN radical, for nitrogenated organic aerosol formation, and imply that substantial amounts of nitrogen is fixed as organic macromolecular aerosols in Titan's atmosphere.

2MASS J00423991+3017515: An Interacting Oddball or a Recoiling AGN?

NASA Astrophysics Data System (ADS)

Hogg, J. Drew; Blecha, Laura; Reynolds, Christopher S.

2017-06-01

We present deep, multiband Hubble imaging and two epochs of optical spectroscopic monitoring of a peculiar nearby (z=0.14) AGN, 2MASS J00423991+3017515. The host galaxy containing the AGN is morphologically disturbed and interacting with an unmerged companion galaxy, suggesting it has had a rich merger history. The AGN itself is spatially displaced from the apparent center of its host galaxy and the symmetric broad Hα and Hβ lines are consistently blueshifted from the narrow line emission and host galaxy absorption by Δv = 1530 km/s. The investigation is ongoing, but we put forward two hypotheses to explain the odd features of this system. First, the abnormalities could be due to separate, independent causes. Projection effects from the interaction of the two galaxies could give the appearance of a spatial offset, while complex wind dynamics from the AGN accretion disk could give rise to the kinematic shift in the broad line emission. Second, this could be a recoiling AGN. This system fits the template of an accreting supermassive black hole (SMBH) that has recently received a “kick” from the asymmetric emission of gravitational waves (GWs) following the merger of two progenitor SMBHs. SMBH mergers are a likely end-product of hierarchical structure formation and are the supermassive cousins of the stellar-mass BH mergers observed with LIGO in the GW150914 and GW151226 events. However, a SMBH merger has yet to be unambigously detected. If confirmed as a recoiling AGN, 2MASS J00423991+3017515 will provide the first evidence of this growth pathway acting in the SMBH regime.

Mesospheric Odd Nitrogen Enhancements During Relativistic Electron Precipitation Events

NASA Technical Reports Server (NTRS)

Aikin, A. C.; Smith, H. J. P.

1999-01-01

The behavior of mesospheric odd nitrogen species during and following relativistic and diffuse auroral precipitation events is simulated, Below 75 km nitric oxide is enhanced in proportion to the ion pair production function associated with the electron precipitation and the length of the event. Nitrogen dioxide and nitric acid are also enhanced. At 65 km the percentage of odd nitrogen for N is 0.1%, HNO3 is 1.6%, NO2 is 15%, and NO is 83.3%. Between 75 and 85 km NO is depleted during particle events due to the faster destruction of NO by N relative to the production of NO by N reacting with O2. Recovery of NO depends on transport from the lower thermosphere, where NO is produced in abundant amounts during particle events.

calculation of B → D*lv form factor at zero recoil using the Oktay-Kronfeld action

NASA Astrophysics Data System (ADS)

Bailey, Jon A.; Bhattacharya, Tanmoy; Gupta, Rajan; Jang, Yong-Chull; Lee, Weonjong; Leem, Jaehoon; Park, Sungwoo; Yoon, Boram

2018-03-01

We present the first preliminary results for the semileptonic form factor hA1 (w = 1)/ρAj at zero recoil for the B → D*lv decay using lattice QCD with four flavors of sea quarks. We use the HISQ staggered action for the light valence and sea quarks (the MILC HISQ configurations), and the Oktay-Kronfeld (OK) action for the heavy valence quarks.

Facile Synthesis of ZnO Nanoparticles on Nitrogen-Doped Carbon Nanotubes as High-Performance Anode Material for Lithium-Ion Batteries

PubMed Central

Li, Haipeng; Liu, Zhengjun; Yang, Shuang; Zhao, Yan; Feng, Yuting; Zhang, Chengwei; Yin, Fuxing

2017-01-01

ZnO/nitrogen-doped carbon nanotube (ZnO/NCNT) composite, prepared though a simple one-step sol-gel synthetic technique, has been explored for the first time as an anode material. The as-prepared ZnO/NCNT nanocomposite preserves a good dispersity and homogeneity of the ZnO nanoparticles (~6 nm) which deposited on the surface of NCNT. Transmission electron microscopy (TEM) reveals the formation of ZnO nanoparticles with an average size of 6 nm homogeneously deposited on the surface of NCNT. ZnO/NCNT composite, when evaluated as an anode for lithium-ion batteries (LIBs), exhibits remarkably enhanced cycling ability and rate capability compared with the ZnO/CNT counterpart. A relatively large reversible capacity of 1013 mAh·g−1 is manifested at the second cycle and a capacity of 664 mAh·g−1 is retained after 100 cycles. Furthermore, the ZnO/NCNT system displays a reversible capacity of 308 mAh·g−1 even at a high current density of 1600 mA·g−1. These electrochemical performance enhancements are ascribed to the reinforced accumulative effects of the well-dispersed ZnO nanoparticles and doping nitrogen atoms, which can not only suppress the volumetric expansion of ZnO nanoparticles during the cycling performance but also provide a highly conductive NCNT network for ZnO anode. PMID:28934141

Facile Synthesis of ZnO Nanoparticles on Nitrogen-Doped Carbon Nanotubes as High-Performance Anode Material for Lithium-Ion Batteries.

PubMed

Li, Haipeng; Liu, Zhengjun; Yang, Shuang; Zhao, Yan; Feng, Yuting; Bakenov, Zhumabay; Zhang, Chengwei; Yin, Fuxing

2017-09-21

ZnO/nitrogen-doped carbon nanotube (ZnO/NCNT) composite, prepared though a simple one-step sol-gel synthetic technique, has been explored for the first time as an anode material. The as-prepared ZnO/NCNT nanocomposite preserves a good dispersity and homogeneity of the ZnO nanoparticles (~6 nm) which deposited on the surface of NCNT. Transmission electron microscopy (TEM) reveals the formation of ZnO nanoparticles with an average size of 6 nm homogeneously deposited on the surface of NCNT. ZnO/NCNT composite, when evaluated as an anode for lithium-ion batteries (LIBs), exhibits remarkably enhanced cycling ability and rate capability compared with the ZnO/CNT counterpart. A relatively large reversible capacity of 1013 mAh·g -1 is manifested at the second cycle and a capacity of 664 mAh·g -1 is retained after 100 cycles. Furthermore, the ZnO/NCNT system displays a reversible capacity of 308 mAh·g -1 even at a high current density of 1600 mA·g -1 . These electrochemical performance enhancements are ascribed to the reinforced accumulative effects of the well-dispersed ZnO nanoparticles and doping nitrogen atoms, which can not only suppress the volumetric expansion of ZnO nanoparticles during the cycling performance but also provide a highly conductive NCNT network for ZnO anode.

Deposition of reactively ion beam sputtered silicon nitride coatings

NASA Technical Reports Server (NTRS)

Grill, A.

1982-01-01

An ion beam source was used to deposit silicon nitride films by reactively sputtering a silicon target with beams of Ar + N2 mixtures. The nitrogen fraction in the sputtering gas was 0.05 to 0.80 at a total pressure of 6 to 2 millionth torr. The ion beam current was 50 mA at 500 V. The composition of the deposited films was investigated by auger electron spectroscopy and the rate of deposition was determined by interferometry. A relatively low rate of deposition of about 2 nm. one-tenth min. was found. AES spectra of films obtained with nitrogen fractions higher than 0.50 were consistent with a silicon to nitrogen ratio corresponding to Si3N4. However the AES spectra also indicated that the sputtered silicon nitride films were contaminated with oxygen and carbon and contained significant amounts of iron, nickel, and chromium, most probably sputtered from the holder of the substrate and target.

Single- and double-photoionization cross sections of atomic nitrogen from threshold to 31 A

NASA Technical Reports Server (NTRS)

Samson, James A. R.; Angel, G. C.

1990-01-01

The relative photoionization cross section of atomic nitrogen for the production of singly and doubly charged ions has been measured from 44.3 to 275 A and from 520 to 852 A. The results have been made absolute by normalization to one-half of the molecular nitrogen cross section at short wavelengths. The smoothed atomic nitrogen cross sections sigma can be accurately represented, at short wavelengths, by the equation sigma(Mb) = 36,700 x (E exp-2.3) as a function of the photon energy E (eV), thereby allowing the cross sections to be extrapolated to the nitrogen K edge at 31 A.

Tandem Mass Spectrometry and Ion Mobility Reveals Structural Insight into Eicosanoid Product Ion Formation

NASA Astrophysics Data System (ADS)

Di Giovanni, James P.; Barkley, Robert M.; Jones, David N. M.; Hankin, Joseph A.; Murphy, Robert C.

2018-04-01

Ion mobility measurements of product ions were used to characterize the collisional cross section (CCS) of various complex lipid [M-H]- ions using traveling wave ion mobility mass spectrometry (TWIMS). TWIMS analysis of various product ions derived after collisional activation of mono- and dihydroxy arachidonate metabolites was found to be more complex than the analysis of intact molecular ions and provided some insight into molecular mechanisms involved in product ion formation. The CCS observed for the molecular ion [M-H]- and certain product ions were consistent with a folded ion structure, the latter predicted by the proposed mechanisms of product ion formation. Unexpectedly, product ions from [M-H-H2O-CO2]- and [M-H-H2O]- displayed complex ion mobility profiles suggesting multiple mechanisms of ion formation. The [M-H-H2O]- ion from LTB4 was studied in more detail using both nitrogen and helium as the drift gas in the ion mobility cell. One population of [M-H-H2O]- product ions from LTB4 was consistent with formation of covalent ring structures, while the ions displaying a higher CCS were consistent with a more open-chain structure. Using molecular dynamics and theoretical CCS calculations, energy minimized structures of those product ions with the open-chain structures were found to have a higher CCS than a folded molecular ion structure. The measurement of product ion mobility can be an additional and unique signature of eicosanoids measured by LC-MS/MS techniques. [Figure not available: see fulltext.

Tandem Mass Spectrometry and Ion Mobility Reveals Structural Insight into Eicosanoid Product Ion Formation.

PubMed

Di Giovanni, James P; Barkley, Robert M; Jones, David N M; Hankin, Joseph A; Murphy, Robert C

2018-04-23

Ion mobility measurements of product ions were used to characterize the collisional cross section (CCS) of various complex lipid [M-H] - ions using traveling wave ion mobility mass spectrometry (TWIMS). TWIMS analysis of various product ions derived after collisional activation of mono- and dihydroxy arachidonate metabolites was found to be more complex than the analysis of intact molecular ions and provided some insight into molecular mechanisms involved in product ion formation. The CCS observed for the molecular ion [M-H] - and certain product ions were consistent with a folded ion structure, the latter predicted by the proposed mechanisms of product ion formation. Unexpectedly, product ions from [M-H-H 2 O-CO 2 ] - and [M-H-H 2 O] - displayed complex ion mobility profiles suggesting multiple mechanisms of ion formation. The [M-H-H 2 O] - ion from LTB 4 was studied in more detail using both nitrogen and helium as the drift gas in the ion mobility cell. One population of [M-H-H 2 O] - product ions from LTB 4 was consistent with formation of covalent ring structures, while the ions displaying a higher CCS were consistent with a more open-chain structure. Using molecular dynamics and theoretical CCS calculations, energy minimized structures of those product ions with the open-chain structures were found to have a higher CCS than a folded molecular ion structure. The measurement of product ion mobility can be an additional and unique signature of eicosanoids measured by LC-MS/MS techniques. Graphical Abstract ᅟ.

Nitrogen doped silicon-carbon multilayer protective coatings on carbon obtained by TVA method

NASA Astrophysics Data System (ADS)

Ciupina, Victor; Vasile, Eugeniu; Porosnicu, Corneliu; Lungu, Cristian P.; Vladoiu, Rodica; Jepu, Ionut; Mandes, Aurelia; Dinca, Virginia; Caraiane, Aureliana; Nicolescu, Virginia; Cupsa, Ovidiu; Dinca, Paul; Zaharia, Agripina

2017-08-01

Protective nitrogen doped Si-C multilayer coatings on carbon, used to improve the oxidation resistance of carbon, were obtained by Thermionic Vacuum Arc (TVA) method. The initial carbon layer having a thickness of 100nm has been deposed on a silicon substrate in the absence of nitrogen, and then a 3nm Si thin film to cover carbon layer was deposed. Further, seven Si and C layers were alternatively deposed in the presence of nitrogen ions, each having a thickness of 40nm. In order to form silicon carbide at the interface between silicon and carbon layers, all carbon, silicon and nitrogen ions energy has increased up to 150eV . The characterization of microstructure and electrical properties of as-prepared N-Si-C multilayer structures were done using Transmission Electron Microscopy (TEM, STEM) techniques, Thermal Desorption Spectroscopy (TDS) and electrical measurements. Oxidation protection of carbon is based on the reaction between oxygen and silicon carbide, resulting in SiO2, SiO and CO2, and also by reaction involving N, O and Si, resulting in silicon oxynitride (SiNxOy) with a continuously variable composition, and on the other hand, since nitrogen acts as a trapping barrier for oxygen. To perform electrical measurements, 80% silver filled two-component epoxy-based glue ohmic contacts were attached on the N-Si-C samples. Electrical conductivity was measured in constant current mode. The experimental data show the increase of conductivity with the increase of the nitrogen content. To explain the temperature behavior of electrical conductivity we assumed a thermally activated electric transport mechanism.

Field electron emission enhancement in lithium implanted and annealed nitrogen-incorporated nanocrystalline diamond films

NASA Astrophysics Data System (ADS)

Sankaran, K. J.; Srinivasu, K.; Yeh, C. J.; Thomas, J. P.; Drijkoningen, S.; Pobedinskas, P.; Sundaravel, B.; Leou, K. C.; Leung, K. T.; Van Bael, M. K.; Schreck, M.; Lin, I. N.; Haenen, K.

2017-06-01

The field electron emission (FEE) properties of nitrogen-incorporated nanocrystalline diamond films were enhanced due to Li-ion implantation/annealing processes. Li-ion implantation mainly induced the formation of electron trap centers inside diamond grains, whereas post-annealing healed the defects and converted the a-C phase into nanographite, forming conduction channels for effective transport of electrons. This resulted in a high electrical conductivity of 11.0 S/cm and enhanced FEE performance with a low turn-on field of 10.6 V/μm, a high current density of 25.5 mA/cm2 (at 23.2 V/μm), and a high lifetime stability of 1,090 min for nitrogen incorporated nanocrystalline diamond films.

Study of Biological Effects of Low Energy Ion Implantation on Tomato and Radish Breeding

NASA Astrophysics Data System (ADS)

Liang, Qiuxia; Huang, Qunce; Cao, Gangqiang; Ying, Fangqing; Liu, Yanbo; Huang, Wen

2008-04-01

Biological effects of 30 keV low energy nitrogen ion implantation on the seeds of five types of tomato and one type of radish were investigated. Results showed that low energy ions have different effects on different vegetables. The whole dose-response curve of the germination ratio did not take on "the shape of saddle", but was a rising and falling waveform with the increase or decrease in ion implantation. In the vegetable of Solanaceae, two outstanding aberrant plants were selected from M1 of Henan No.4 tomato at a dose of 7 × 1017 nitrogen ions/cm2, which had thin-leaves, long-petal and nipple tip fruit stably inherited to M7. Furthermore the analysis of the isozyme showed that the activity of the mutant tomato seedling was distinct in quantity and color. In Raphanus sativus L., the aberrances were obvious in the mutant of radish 791 at a dose of 5 × 1017 nitrogen ions/cm2, and the weight of succulent root and the volume of growth were over twice the control's. At present, many species for breeding have been identified in the field and only stable species have been selected for the experiment of production. It is evident that the low energy ion implantation technology has clear effects on vegetables' genetic improvement.

Anchoring ZnO Nanoparticles in Nitrogen-Doped Graphene Sheets as a High-Performance Anode Material for Lithium-Ion Batteries.

PubMed

Yuan, Guanghui; Xiang, Jiming; Jin, Huafeng; Wu, Lizhou; Jin, Yanzi; Zhao, Yan

2018-01-10

A novel binary nanocomposite, ZnO/nitrogen-doped graphene (ZnO/NG), is synthesized via a facile solution method. In this prepared ZnO/NG composite, highly-crystalline ZnO nanoparticles with a size of about 10 nm are anchored uniformly on the N-doped graphene nanosheets. Electrochemical properties of the ZnO/NG composite as anode materials are systematically investigated in lithium-ion batteries. Specifically, the ZnO/NG composite can maintain the reversible specific discharge capacity at 870 mAh g -1 after 200 cycles at 100 mA g -1 . Besides the enhanced electronic conductivity provided by interlaced N-doped graphene nanosheets, the excellent lithium storage properties of the ZnO/NG composite can be due to nanosized structure of ZnO particles, shortening the Li⁺ diffusion distance, increasing reaction sites, and buffering the ZnO volume change during the charge/discharge process.

Laser cooling of 85Rb atoms to the recoil-temperature limit

NASA Astrophysics Data System (ADS)

Huang, Chang; Kuan, Pei-Chen; Lan, Shau-Yu

2018-02-01

We demonstrate the laser cooling of 85Rb atoms in a two-dimensional optical lattice. We follow the two-step degenerate Raman sideband cooling scheme [Kerman et al., Phys. Rev. Lett. 84, 439 (2000), 10.1103/PhysRevLett.84.439], where a fast cooling of atoms to an auxiliary state is followed by a slow cooling to a dark state. This method has the advantage of independent control of the heating rate and cooling rate from the optical pumping beam. We operate the lattice at a Lamb-Dicke parameter η =0.45 and show the cooling of spin-polarized 85Rb atoms to the recoil temperature in both dimensions within 2.4 ms with the aid of adiabatic cooling.

Improvement of Nitrogen Assimilation and Fermentation Kinetics under Enological Conditions by Derepression of Alternative Nitrogen-Assimilatory Pathways in an Industrial Saccharomyces cerevisiae Strain

PubMed Central

Salmon, Jean-Michel; Barre, Pierre

1998-01-01

Metabolism of nitrogen compounds by yeasts affects the efficiency of wine fermentation. Ammonium ions, normally present in grape musts, reduce catabolic enzyme levels and transport activities for nonpreferred nitrogen sources. This nitrogen catabolite repression severely impairs the utilization of proline and arginine, both common nitrogen sources in grape juice that require the proline utilization pathway for their assimilation. We attempted to improve fermentation performance by genetic alteration of the regulation of nitrogen-assimilatory pathways in Saccharomyces cerevisiae. One mutant carrying a recessive allele of ure2 was isolated from an industrial S. cerevisiae strain. This mutation strongly deregulated the proline utilization pathway. Fermentation kinetics of this mutant were studied under enological conditions on simulated standard grape juices with various nitrogen levels. Mutant strains produced more biomass and exhibited a higher maximum CO2 production rate than the wild type. These differences were primarily due to the derepression of amino acid utilization pathways. When low amounts of dissolved oxygen were added, the mutants could assimilate proline. Biomass yield and fermentation rate were consequently increased, and the duration of the fermentation was substantially shortened. S. cerevisiae strains lacking URE2 function could improve alcoholic fermentation of natural media where proline and other poorly assimilated amino acids are the major potential nitrogen source, as is the case for most fruit juices and grape musts. PMID:9758807

Dielectric barrier structure with hollow electrodes and its recoil effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Shuang; Chen, Qunzhi; Liu, Jiahui

2015-06-15

A dielectric barrier structure with hollow electrodes (HEDBS), in which gas flow oriented parallel to the electric field, was proposed. Results showed that with this structure, air can be effectively ignited, forming atmospheric low temperature plasma, and the proposed HEDBS could achieve much higher electron density (5 × 10{sup 15}/cm{sup 3}). It was also found that the flow condition, including outlet diameter and flow rate, played a key role in the evolution of electron density. Optical emission spectroscopy diagnostic results showed that the concentration of reactive species had the same variation trend as the electron density. The simulated distribution of discharge gasmore » flow indicated that the HEDBS had a strong recoil effect on discharge gas, and could efficiently promote generating electron density as well as reactive species.« less

Single and multiple ionization of C60 fullerenes and collective effects in collisions with highly charged C, F, and Si ions with energy 3 MeV/u

NASA Astrophysics Data System (ADS)

Kelkar, A. H.; Kadhane, U.; Misra, D.; Gulyas, L.; Tribedi, L. C.

2010-10-01

We have measured absolute cross sections for single, double, triple, and quadruple ionization of C60 in collisions with 3 MeV/u C, F, and Si projectile ions at various projectile charge states. The experiment was performed using the recoil-ion time-of-flight technique. Projectile charge state dependence of the ionization yields was compared mainly with a model based on the giant dipole plasmon resonance (GDPR). In some cases, the continuum-distorted-wave-eikonal-initial-state (CDW-EIS) model which is normally applied for ion-atom collisions was also used as a reference. An excellent qualitative agreement between the experimental data for single and double ionization and the GDPR model predictions was found for all projectile charge states.

Ion-polycyclic aromatic hydrocarbon collisions: kinetic energy releases for specific fragmentation channels

NASA Astrophysics Data System (ADS)

Reitsma, G.; Zettergren, H.; Boschman, L.; Bodewits, E.; Hoekstra, R.; Schlathölter, T.

2013-12-01

We report on 30 keV He2 + collisions with naphthalene (C10H8) molecules, which leads to very extensive fragmentation. To unravel such complex fragmentation patterns, we designed and constructed an experimental setup, which allows for the determination of the full momentum vector by measuring charged collision products in coincidence in a recoil ion momentum spectrometer type of detection scheme. The determination of fragment kinetic energies is found to be considerably more accurate than for the case of mere coincidence time-of-flight spectrometers. In fission reactions involving two cationic fragments, typically kinetic energy releases of 2-3 eV are observed. The results are interpreted by means of density functional theory calculations of the reverse barriers. It is concluded that naphthalene fragmentation by collisions with keV ions clearly is much more violent than the corresponding photofragmentation with energetic photons. The ion-induced naphthalene fragmentation provides a feedstock of various small hydrocarbonic species of different charge states and kinetic energy, which could influence several molecule formation processes in the cold interstellar medium and facilitates growth of small hydrocarbon species on pre-existing polycyclic aromatic hydrocarbons.

Development of bipolar-pulse accelerator for intense pulsed ion beam acceleration

NASA Astrophysics Data System (ADS)

Masugata, Katsumi; Shimizu, Yuichro; Fujioka, Yuhki; Kitamura, Iwao; Tanoue, Hisao; Arai, Kazuo

2004-12-01

To improve the purity of intense pulsed ion beams, a new type of pulsed ion beam accelerator named "bipolar pulse accelerator" was proposed. To confirm the principle of the accelerator a prototype of the experimental system was developed. The system utilizes By type magnetically insulated acceleration gap and operated with single polar negative pulse. A coaxial gas puff plasma gun was used as an ion source, which was placed inside the grounded anode. Source plasma (nitrogen) of current density ≈25 A/cm2, duration ≈1.5 μs was injected into the acceleration gap by the plasma gun. The ions were successfully accelerated from the grounded anode to the drift tube by applying negative pulse of voltage 240 kV, duration 100 ns to the drift tube. Pulsed ion beam of current density ≈40 A/cm2, duration ≈50 ns was obtained at 41 mm downstream from the anode surface. To evaluate the irradiation effect of the ion beam to solid material, an amorphous silicon thin film of thickness ≈500 nm was used as the target, which was deposited on the glass substrate. The film was found to be poly-crystallized after 4-shots of the pulsed nitrogen ion beam irradiation.

Investigation of amorphization energies for heavy ion implants into silicon carbide at depths far beyond the projected ranges

NASA Astrophysics Data System (ADS)

Friedland, E.

2017-01-01

At ion energies with inelastic stopping powers less than a few keV/nm, radiation damage is thought to be due to atomic displacements by elastic collisions only. However, it is well known that inelastic processes and non-linear effects due to defect interaction within collision cascades can significantly increase or decrease damage efficiencies. The importance of these processes changes significantly along the ion trajectory and becomes negligible at some distance beyond the projected range, where damage is mainly caused by slowly moving secondary recoils. Hence, in this region amorphization energies should become independent of the ion type and only reflect the properties of the target lattice. To investigate this, damage profiles were obtained from α-particle channeling spectra of 6H-SiC wafers implanted at room temperature with ions in the mass range 84 ⩽ M ⩽ 133, employing the computer code DICADA. An average amorphization dose of (0.7 ± 0.2) dpa and critical damage energy of (17 ± 6) eV/atom are obtained from TRIM simulations at the experimentally observed boundary positions of the amorphous zones.

Distribution and variability of nitrogen and phosphorus in the alluvial, High Plains, Rush Springs, and Blaine aquifers in western Oklahoma

USGS Publications Warehouse

Becker, C.J.

1994-01-01

Aquifers are the primary source of water for drinking and agricultural purposes in western Oklahoma. Health concerns about consuming nitrogen and an increased reliance on ground water for drinking necessitate a better understanding of the cause and effect of contamination from nutrients. The purpose of this project was to compile nutrients data from the National Water Information System data base for the alluvial aquifers west of longitude 98 degrees W. and from three bedrock aquifers, High Plains, Rush Springs, and Blaine, and provide this information in a report for future projects and for the facilitation of nutrient source management. The scope of the work consisted of (1) compiling ground-water quality data concerning nitrogen and phosphorus ions, (2) constructing boxplots illustrating data variability, (3) maps for each aquifer showing locations of wells when nitrogen and phosphorus ions were measured in ground water and where concentrations of nitrate and nitrite, reported as nitrogen, exceed the maximum contaminant level, and (4) calculating summary statistics. Nutrient data were obtained from the U.S. Geological Survey data base called the National Water Information System. Data were restricted to ground-water samples, but no restrictions were placed on well and water use or date and time of sampling. Compiled nutrient data consist of dissolved and total concentrations of the common nitrogen and phosphorus ions measured in ground water. For nitrogen these ions include nitrate, nitrite, ammonium, and nitrite plus nitrate. All concentrations are reported in milligrams per liter as nitrogen. Phosphorus in ground water is measured as the orthophosphate ion, and is reported in milligrams per liter as phosphorus. Nutrient variability is illustrated by a standard boxplot. The data are presented by aquifer or hydrologic subregion for alluvial aquifers, with one boxplot constructed for each nutrient compound if more than four analyses are present. Maps for each

Behaviour of tetraalkylammonium ions in high-field asymmetric waveform ion mobility spectrometry.

PubMed

Aksenov, Alexander A; Kapron, James T

2010-05-30

High-field asymmetric waveform ion mobility spectrometry (FAIMS) is an ion-filtering technique recently adapted for use with liquid chromatography/mass spectrometry (LC/MS) to remove interferences during analysis of complex matrices. This is the first systematic study of a series of singly charged tetraalkylammonium ions by FAIMS-MS. The compensation voltage (CV) is the DC offset of the waveform which permits the ion to emerge from FAIMS and it was determined for each member of the series under various conditions. The electrospray ionization conditions explored included spray voltage, vaporizer temperature, and sheath and auxiliary gas pressure. The FAIMS conditions explored included carrier gas flow rate, electrode temperature and composition of the carrier gas. Optimum desolvation was achieved using sufficient carrier gas (flow rate > or = 2 L/min) to ensure stable response. Low-mass ions (m/z 100-200) are more susceptible to changes in electrode temperature and gas composition than high mass ions (m/z 200-700). As a result of this study, ions are reliably analyzed using standard FAIMS conditions (dispersion voltage -5000 V, carrier gas flow rate 3 L/min, 50% helium/50%nitrogen, inner electrode temperature 70 degrees C and outer electrode temperature 90 degrees C). Variation of FAIMS conditions may be of great use for the separation of very low mass tetraalkylammonium (TAA) ions from other TAA ions. The FAIMS conditions do not appear to have a major effect on higher mass ions. Copyright 2010 John Wiley & Sons, Ltd.

Formation of nitrogenated organic aerosols in the Titan upper atmosphere

PubMed Central

Imanaka, Hiroshi; Smith, Mark A.

2010-01-01

Many aspects of the nitrogen fixation process by photochemistry in the Titan atmosphere are not fully understood. The recent Cassini mission revealed organic aerosol formation in the upper atmosphere of Titan. It is not clear, however, how much and by what mechanism nitrogen is incorporated in Titan’s organic aerosols. Using tunable synchrotron radiation at the Advanced Light Source, we demonstrate the first evidence of nitrogenated organic aerosol production by extreme ultraviolet–vacuum ultraviolet irradiation of a N2/CH4 gas mixture. The ultrahigh-mass-resolution study with laser desorption ionization-Fourier transform-ion cyclotron resonance mass spectrometry of N2/CH4 photolytic solid products at 60 and 82.5 nm indicates the predominance of highly nitrogenated compounds. The distinct nitrogen incorporations at the elemental abundances of H2C2N and HCN, respectively, are suggestive of important roles of H2C2N/HCCN and HCN/CN in their formation. The efficient formation of unsaturated hydrocarbons is observed in the gas phase without abundant nitrogenated neutrals at 60 nm, and this is confirmed by separately using 13C and 15N isotopically labeled initial gas mixtures. These observations strongly suggest a heterogeneous incorporation mechanism via short lived nitrogenated reactive species, such as HCCN radical, for nitrogenated organic aerosol formation, and imply that substantial amounts of nitrogen is fixed as organic macromolecular aerosols in Titan’s atmosphere. PMID:20616074

Techniques for measuring the atomic recoil frequency using a grating-echo atom interferometer

NASA Astrophysics Data System (ADS)

Barrett, Brynle

I have developed three types of time-domain echo atom interferometer (AIs) that use either two or three standing-wave pulses in different configurations. Experiments approaching the transit time limit are achieved using samples of laser-cooled rubidium atoms with temperatures < 5 μK contained within a glass vacuum chamber—an environment that is largely free of both magnetic fields and field gradients. The principles of the atom-interferometric measurement of Eq can be understood based on a description of the "two-pulse" AI. This interferometer uses two standing-wave pulses applied at times t = 0 and t = T 21 to create a superposition of atomic momentum states differing by multiples of the two-photon momentum, ħq = 2 ħk where k is the optical wave number, that interfere in the vicinity of t = 2T 21. This interference or "echo" manifests itself as a density grating in the atomic sample, and is probed by applying a near-resonant traveling-wave "read-out" pulse and measuring the intensity of the coherent light Bragg-scattered in the backward direction. The scattered light from the grating is associated with a λ/2-periodic modulation produced by the interference of momentum states differing by ħq. Interfering states that differ by more than ħq—which produce higher-frequency spatial modulation within the sample—cannot be detected due to the nature of the Bragg scattering detection technique employed in the experiment. The intensity of the scattered light varies in a periodic manner as a function of the standing-wave pulse separation, T21. The fundamental frequency of this modulation is the two-photon atomic recoil frequency, ω q = ħq2/2M, where q = 2k and M is the mass of the atom (a rubidium isotope in this case). The recoil frequency, ω q, is related to the recoil energy, Eq = ħωq, which is the kinetic energy associated with the recoil of the atom after a coherent two-photon scattering process. By performing the experiment on a suitably long time scale

Nitrogen doped silicon-carbon multilayer protective coatings on carbon obtained by thermionic vacuum arc (TVA) method

NASA Astrophysics Data System (ADS)

Ciupinǎ, Victor; Vasile, Eugeniu; Porosnicu, Corneliu; Vladoiu, Rodica; Mandes, Aurelia; Dinca, Virginia; Nicolescu, Virginia; Manu, Radu; Dinca, Paul; Zaharia, Agripina

2018-02-01

To obtain protective nitrogen doped Si-C multilayer coatings on carbon, used to improve the oxidation resistance of carbon, was used TVA method. The initial carbon layer has been deposed on a silicon substrate in the absence of nitrogen, and then a 3nm Si thin film to cover carbon layer was deposed. Further, seven Si and C layers were alternatively deposed in the presence of nitrogen ions. In order to form silicon carbide at the interface between silicon and carbon layers, all carbon, silicon and nitrogen ions energy has increased up to 150eV. The characterization of microstructure and electrical properties of as-prepared N-Si-C multilayer structures were done using Transmission Electron Microscopy (TEM, STEM) techniques, Thermal Desorption Spectroscopy (TDS) and electrical measurements. The retention of oxygen in the protective layer of N-Si-C is due to the following phenomena: (a) The reaction between oxygen and silicon carbide resulting in silicon oxide and carbon dioxide; (b) The reaction involving oxygen, nitrogen and silicon resulting silicon oxinitride with a variable composition; (c) Nitrogen acts as a trapping barrier for oxygen. To perform electrical measurements, ohmic contacts were attached on the N-Si-C samples. Electrical conductivity was measured in constant current mode. To explain the temperature behavior of electrical conductivity we assumed a thermally activated electric transport mechanism.

Single and multiple ionization of C{sub 60} fullerenes and collective effects in collisions with highly charged C, F, and Si ions with energy 3 MeV/u

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kelkar, A. H.; Kadhane, U.; Misra, D.

2010-10-15

We have measured absolute cross sections for single, double, triple, and quadruple ionization of C{sub 60} in collisions with 3 MeV/u C, F, and Si projectile ions at various projectile charge states. The experiment was performed using the recoil-ion time-of-flight technique. Projectile charge state dependence of the ionization yields was compared mainly with a model based on the giant dipole plasmon resonance (GDPR). In some cases, the continuum-distorted-wave-eikonal-initial-state (CDW-EIS) model which is normally applied for ion-atom collisions was also used as a reference. An excellent qualitative agreement between the experimental data for single and double ionization and the GDPR modelmore » predictions was found for all projectile charge states.« less

Assessment of soil nitrogen variability related to N doses applied through fertirrigation system.

NASA Astrophysics Data System (ADS)

Castellanos, M. T.; Tarquis, A. M.; Ribas, F.; Cabello, M. J.; Arce, A.; Cartagena, M. C.

2009-04-01

The knowledge of water and nitrogen dynamics in soils under drip irrigation and fertilizer application is essential to optimizing water and nitrogen management. Recent studies of water and nitrogen distribution in the soil under drip irrigation focus on water and inorganic nitrogen distribution around the drip emitters. Results of the studies are not verified with field experimental data. Reasons might include difficulties in obtaining field experimental data under irrigation and nitrogen fertilization [1]. N is an element which produces a stronger crop response, accelerates vegetative growth, plant development and yield increase. Accumulation and redistribution of N within the soil varies depending on management practices, soil characteristics, and growing season precipitation. Soil N high content at post-harvest is usually provided as evidence that N fertilizer had been applied in excess. The aim of this study is to characterize mineral N distribution in the soil profile measured at 5, 15, 25, 35, 45 and 55 cm of depth at the end of melon crop that received three N treatments: 93 (N93), 243 (N243) and 393 kg N ha-1(N393). The agronomic practices created a higher variability in soil Nitrogen content. NH4- N reduction in the soil profile can also be explained by the nitrification process. The high absorption and rapid nitrification of NH4+ ions in the plot layer are the main reason of a reduce movement downstream. NO3- ions present higher mobility in the soil profile. [1] Rahil, M.H.; Antonopoulos, V.Z. 2007. Simulating soil water flow and nitrogen dynamics in a sunflower field irrigated with reclaimed wastewater. Agricultural Water Management 92, 142 - 150. Acknowledgements: This project has been supported by INIA-RTA04-111

Compositional, structural, and optical changes of polyimide implanted by 1.0 MeV Ni+ ions

NASA Astrophysics Data System (ADS)

Mikšová, R.; Macková, A.; Pupikova, H.; Malinský, P.; Slepička, P.; Švorčík, V.

2017-09-01

The ion irradiation leads to deep structural and compositional changes in the irradiated polymers. Ni+ ions implanted polymers were investigated from the structural and compositional changes point of view and their optical properties were investigated. Polyimide (PI) foils were implanted with 1.0 MeV Ni+ ions at room temperature with fluencies of 1.0 × 1013-1.0 × 1015 cm-2 and two different ion implantation currents densities (3.5 and 7.2 nA/cm2). Rutherford Back-Scattering (RBS) and Elastic Recoil Detection Analysis (ERDA) were used for determination of oxygen and hydrogen escape in implanted PI. Atomic Force Microscopy (AFM) was used to follow surface roughness modification after the ion implantation and UV-Vis spectroscopy was employed to check the optical properties of the implanted PI. The implanted PI structural changes were analysed using Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR-FTIR). High energy Ni-ion implantation causes only a minor release of hydrogen and oxygen close to the polymer sub-surface region in about 60 nm thick layer penetrated by the ion beam; especially at ion fluencies below 1.0 × 1014 cm-2. The mostly pronounced structural changes of the Ni implanted PI were found for the samples implanted above ion fluence 1.0 × 1015 cm-2 and at the ion current density 7.2 nA/cm2, where the optical band gap significantly decreases and the reduction of more complex structural unit of PI monomer was observed.

The effect of high energy ion beam analysis on D trapping in W

NASA Astrophysics Data System (ADS)

Finlay, T. J.; Davis, J. W.; Schwarz-Selinger, T.; Haasz, A. A.

2017-12-01

High energy ion beam analyses (IBA) are invaluable for measuring concentration depth profiles of light elements in solid materials, and important in the study of fusion fuel retention in tokamaks. Polycrystalline W specimens were implanted at 300 and 500 K, 5-10 × 1023 D m-2 fluence, with deuterium-only and simultaneous D-3%He ion beams. Selected specimens were analysed by elastic recoil detection analysis (ERDA) and/or nuclear reaction analysis (NRA). All specimens were measured by thermal desorption spectroscopy (TDS). The D TDS spectra show an extra peak at 900-1000 K following ERDA and/or NRA measurements. The peak height appears to correlate with the amount of D initially trapped beyond the calculated IBA probe beam peak damage depth. Similar to pre-implantation damage scenarios, the IBA probe beam creates empty high energy traps which later retrap D atoms during TDS heating, which is supported by modelling experimental results using the Tritium Migration Analysis Program.

Formation of Wear Resistant Steel Surfaces by Plasma Immersion Ion Implantation

NASA Astrophysics Data System (ADS)

Mändl, S.; Rauschenbach, B.

2003-08-01

Plasma immersion ion implantation (PIII) is a versatile and fast method for implanting energetic ions into large and complex shaped three-dimensional objects where the ions are accelerated by applying negative high voltage pulses to a substrate immersed in a plasma. As the line-of-sight restrictions of conventional implanters are circumvented, it results in a fast and cost-effective technology. Implantation of nitrogen at 30 - 40 keV at moderate temperatures of 200 - 400 °C into steel circumvents the diminishing thermal nitrogen activation encountered, e.g., in plasma nitriding in this temperature regime, thus enabling nitriding of additional steel grades. Nitride formation and improvement of the mechanical properties after PIII are presented for several steel grades, including AISI 316Ti (food industry), AISI D2 (used for bending tools) and AISI 1095 (with applications in the textile industry).

How Hot are Your Ions in TWAVE Ion Mobility Spectrometry?

PubMed Central

Merenbloom, Samuel I.; Flick, Tawnya G.; Williams, Evan R.

2012-01-01

Effective temperatures of ions during traveling wave ion mobility spectrometry (TWIMS) analysis were measured using singly protonated leucine enkephalin dimer as a chemical thermometer by monitoring dissociation of the dimer into monomer, as well as the subsequent dissociation of monomer into a-, b-, and y-ions, as a function of instrumental parameters. At fixed helium cell and TWIMS cell gas flow rates, the extent of dissociation does not vary significantly with either the wave velocity or wave height, except at low (<500 m/s) wave velocities that are not commonly used. Increasing the flow rate of nitrogen gas into the TWIMS cell and decreasing the flow rate of helium gas into the helium cell resulted in greater dissociation. However, the mobility distributions of the fragment ions formed by dissociation of the dimer upon injection into the TWIMS cell are nearly indistinguishable from those of fragment ions formed in the collision cell prior to TWIMS analysis for all TWIMS experiments. These results indicate that heating and dissociation occur when ions are injected into the TWIMS cell, and that the effective temperature subsequently decreases to a point at which no further dissociation is observed during the TWIMS analysis. An upper limit to the effective ion temperature of 449 K during TWIMS analysis is obtained at a helium flow rate of 180 mL/min, TWIMS flow rate of 80 mL/min and traveling wave height of 40 V, which is well below previously reported values. Effects of ion heating in TWIMS on gas-phase protein conformation are presented. PMID:22203576

Composition and structure of surfaces by time-of-flight scattering and recoiling spectrometry (TOF-SARS)

NASA Astrophysics Data System (ADS)

Ahn, Jeongheon

1997-10-01

Time-of-flight scattering and recoiling spectrometry (TOF-SARS) was applied to characterize surface structures in order to understand the chemical and physical phenomena on various surfaces. The combination of TOF-SARS, LEED, and classical ion trajectory simulations has allowed characterization of the elemental composition in the outermost atomic layers, surface symmetry, and possible reconstruction or relaxation. The composition and structure of the CdS\\{0001\\}-(1 x 1) and CdS\\{000bar1\\}-(1 x 1) surfaces were investigated. The termination layer of each surface was determined by grazing incidence TOF-SARS. Both (1 x 1) surfaces are bulk-terminated without any reconstruction or relaxation detected by TOF-SARS. Each surface has two domains which are rotated by 60sp° from each other and there exist steps on both surfaces. The CdS\\{0001\\}-(1 x 1) surface is stabilized by O and H covering half a monolayer which are structurally ordered on the surface, while the O and H on the CdS\\{000bar1\\}-(1 x 1) stabilize the surface without ordering. The study of GaN\\{000bar1\\}-(1 x 1) shows the bulk-termination of the surface with no detectable reconstruction or relaxation. The surface is terminated in a N layer with Ga in the 2sp{nd}-layer. H atoms are bound to the outermost N atoms with a coverage of ˜3/4 monolayer and protrude outward from the surface. The surface termination, composition and structure of the Alsb2Osb3 (sapphire) were examined. The surface relaxation was studied quantitatively using classical ion trajectory simulations along with TOF-SARS. The surface undergoes 1sp{st}{-}2sp{nd}-layer relaxation as large as 0.5 A from the bulk value resulting in near coplanarity of Al and O atoms. The reconstruction of the Ni\\{100\\}-(2 x 2)-C surface was studied by TOF-SARS. The surface contained 80% of the (2 x 2)p4g phase and 20% of the unreconstructed (2 x 2) phase. The displacement of Ni atoms was determined by comparing the experimental and simulated results.

Ball lightning dynamics and stability at moderate ion densities

NASA Astrophysics Data System (ADS)

Morrow, R.

2017-10-01

A general mechanism is presented for the dynamics and structure of ball lightning and for the maintenance of the ball lightning structure for several seconds. Results are obtained using a spherical geometry for air at atmospheric pressure, by solving the continuity equations for electrons, positive ions and negative ions coupled with Poisson’s equation. A lightning strike can generate conditions in the lightning channel with a majority of positive nitrogen ions, and a minority of negative oxygen ions and electrons. The calculations are initiated with electrons included; however, at the moderate ion densities chosen the electrons are rapidly lost to form negative ions, and after 1 µs their influence on the ion dynamics is negligible. Further development after 1 µs is followed using a simpler set of equations involving only positive ions and negative ions, but including ion diffusion. The space-charge electric field generated by the majority positive ions drives them from the centre of the distribution and drives the minority negative ions and electrons towards the centre of the distribution. In the central region the positive and negative ion distributions eventually overlap exactly and their space-charge fields cancel resulting in zero electric field, and the plasma ball formed is quite stable for a number of seconds. The formation of such plasma balls is not critically dependent on the initial diameter of the ion distributions, or the initial density of minority negative ions. The ion densities decrease relatively slowly due to mutual neutralization of positive and negative ions. The radiation from this neutralization process involving positive nitrogen ions and negative oxygen ions is not sufficient to account for the reported luminosity of ball lightning and some other source of luminosity is shown to be required; the plasma ball model used could readily incorporate other ions in order to account for the luminosity and range of colours reported for ball

Control of ion content and nitrogen species using a mixed chemistry plasma for GaN grown at extremely high growth rates >9 μm/h by plasma-assisted molecular beam epitaxy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gunning, Brendan P.; Clinton, Evan A.; Merola, Joseph J.

2015-10-21

Utilizing a modified nitrogen plasma source, plasma assisted molecular beam epitaxy (PAMBE) has been used to achieve higher growth rates in GaN. A higher conductance aperture plate, combined with higher nitrogen flow and added pumping capacity, resulted in dramatically increased growth rates up to 8.4 μm/h using 34 sccm of N{sub 2} while still maintaining acceptably low operating pressure. It was further discovered that argon could be added to the plasma gas to enhance growth rates up to 9.8 μm/h, which was achieved using 20 sccm of N{sub 2} and 7.7 sccm Ar flows at 600 W radio frequency power, for which themore » standard deviation of thickness was just 2% over a full 2 in. diameter wafer. A remote Langmuir style probe employing the flux gauge was used to indirectly measure the relative ion content in the plasma. The use of argon dilution at low plasma pressures resulted in a dramatic reduction of the plasma ion current by more than half, while high plasma pressures suppressed ion content regardless of plasma gas chemistry. Moreover, different trends are apparent for the molecular and atomic nitrogen species generated by varying pressure and nitrogen composition in the plasma. Argon dilution resulted in nearly an order of magnitude achievable growth rate range from 1 μm/h to nearly 10 μm/h. Even for films grown at more than 6 μm/h, the surface morphology remained smooth showing clear atomic steps with root mean square roughness less than 1 nm. Due to the low vapor pressure of Si, Ge was explored as an alternative n-type dopant for high growth rate applications. Electron concentrations from 2.2 × 10{sup 16} to 3.8 × 10{sup 19} cm{sup −3} were achieved in GaN using Ge doping, and unintentionally doped GaN films exhibited low background electron concentrations of just 1–2 × 10{sup 15} cm{sup −3}. The highest growth rates resulted in macroscopic surface features due to Ga cell spitting, which is an engineering challenge still

Irradiation of nitrogen-rich ices by swift heavy ions. Clues for the formation of ultracarbonaceous micrometeorites

NASA Astrophysics Data System (ADS)

Augé, B.; Dartois, E.; Engrand, C.; Duprat, J.; Godard, M.; Delauche, L.; Bardin, N.; Mejía, C.; Martinez, R.; Muniz, G.; Domaracka, A.; Boduch, P.; Rothard, H.

2016-08-01

Context. Extraterrestrial materials, such as meteorites and interplanetary dust particles, provide constraints on the formation and evolution of organic matter in the young solar system. Micrometeorites represent the dominant source of extraterrestrial matter at the Earth's surface, some of them originating from large heliocentric distances. Recent analyses of ultracarbonaceous micrometeorites recovered from Antarctica (UCAMMs) reveal an unusually nitrogen-rich organic matter. Such nitrogen-rich carbonaceous material could be formed in a N2-rich environment, at very low temperature, triggered by energetic processes. Aims: Several formation scenarios have been proposed for the formation of the N-rich organic matter observed in UCAMMs. We experimentally evaluate the scenario involving high energy irradiation of icy bodies subsurface orbiting at large heliocentric distances. Methods: The effect of Galactic cosmic ray (GCR) irradiation of ices containing N2 and CH4 was studied in the laboratory. The N2-CH4 (90:10 and 98:2) ice mixtures were irradiated at 14 K by 44 MeV Ni11+ and 160 MeV Ar15+ swift heavy ion beams. The evolution of the samples was monitored using in-situ Fourier transform infrared spectroscopy. The evolution of the initial ice molecules and new species formed were followed as a function of projectile fluence. After irradiation, the target was annealed to room temperature. The solid residue of the whole process left after ice sublimation was characterized in-situ by infrared spectroscopy, and the elemental composition was measured ex-situ. Results: The infrared bands that appear during irradiation allow us to identify molecules and radicals (HCN, CN-, NH3, ...). The infrared spectra of the solid residues measured at room temperature show similarities with that of UCAMMs. The results point towards the efficient production of a poly-HCN-like residue from the irradiation of N2-CH4 rich surfaces of icy bodies. The room temperature residue provides a viable

High resolution Li depth profiling of solid state Li ion battery by TERD technique with high energy light ions

NASA Astrophysics Data System (ADS)

Morita, K.; Tsuchiya, B.; Ohnishi, J.; Yamamoto, T.; Iriyama, Y.; Tsuchida, H.; Majima, T.; Suzuki, K.

2018-07-01

Li depth profiles in Au/Si/LiPON/LCO/Au (LCO = LiCoO2, LiPON = Li3.3PO3.8N0.2) thin films battery under charging condition, prepared on self-supporting Al substrate, have been in situ measured by means of transmission elastic recoil detection (TERD) and Rutherford backscattering spectroscopy (RBS) techniques not only with 5.4 MeV He2+ ion beam without absorber, but also 9 MeV O4+ ion beam with Al absorber. In experiments with 5.4 MeV He2+, well-resolved step-wise TERD spectra have been observed, from which thickness and Li composition of constituent films of the battery are directly estimated. The Li transport from LCO to Si films through LiPON as well as return-back of Li from Si to LCO films and Li leakage into the Al substrate out of the battery system by over-charging under charging condition have been observed in the experiments both 5.4 MeV He2+ and 9 MeV O4+. The latter result indicates that these techniques are applicable to testing degradation of the battery performance by repetition of charging and discharging. Both results are compared in details with each other.

Revised models of interstellar nitrogen isotopic fractionation

NASA Astrophysics Data System (ADS)

Wirström, E. S.; Charnley, S. B.

2018-03-01

Nitrogen-bearing molecules in cold molecular clouds exhibit a range of isotopic fractionation ratios and these molecules may be the precursors of 15N enrichments found in comets and meteorites. Chemical model calculations indicate that atom-molecular ion and ion-molecule reactions could account for most of the fractionation patterns observed. However, recent quantum-chemical computations demonstrate that several of the key processes are unlikely to occur in dense clouds. Related model calculations of dense cloud chemistry show that the revised 15N enrichments fail to match observed values. We have investigated the effects of these reaction rate modifications on the chemical model of Wirström et al. (2012) for which there are significant physical and chemical differences with respect to other models. We have included 15N fractionation of CN in neutral-neutral reactions and also updated rate coefficients for key reactions in the nitrogen chemistry. We find that the revised fractionation rates have the effect of suppressing 15N enrichment in ammonia at all times, while the depletion is even more pronounced, reaching 14N/15N ratios of >2000. Taking the updated nitrogen chemistry into account, no significant enrichment occurs in HCN or HNC, contrary to observational evidence in dark clouds and comets, although the 14N/15N ratio can still be below 100 in CN itself. However, such low CN abundances are predicted that the updated model falls short of explaining the bulk 15N enhancements observed in primitive materials. It is clear that alternative fractionating reactions are necessary to reproduce observations, so further laboratory and theoretical studies are urgently needed.

Ion-molecule reactions relevant to Titan's ionosphere.

NASA Astrophysics Data System (ADS)

McEwan, M. J.; Scott, G. B. I.; Anicich, V. G.

1998-02-01

Twenty four new ion-molecule reactions are presented for inclusion in the modeling of the ionosphere of Saturn's satellite Titan. Sixteen reactions were re-examined to reduce uncertainties in the previous literature results. In this study the authors have examined the reactions of N+ and N2+ with CH4, C2H2, C2H4, C2H6, HCN, CH2CHCN and HC3N; the reaction of N+ with CH3CN; the reactions of C3H5+ with CH4, C2H2 C2H4, C2H6, H2, HCN, HC3N and CH2CHCN; the reactions of C2N2+ with C2H2; C2H2+ and C2N2; C2H4 with C2H3+, C2H4+, CHCCNH+, and HC5N+; HCNH+ with C2H6; C3H6+ with C3H6; HCN with C2H6+, C3H6+, c-C3H6+, C2N2+ and NO+; N2 with C2H2+ and C2H5+; C2H4+ and HC3N. The ions selected for this study were derived either from nitrogen, appropriate hydrocarbons or nitriles. The reactant neutrals were selected on the basis of their known presence in Titan's atmosphere. The reaction products are consistent with the expected increase in ion size through ion-molecule reaction processing. Data are also presented for the reactions of 23 ions with molecular nitrogen. Almost all of these ions are unreactive with N2.

The XENON100 Dark Matter Experiment: Design, Construction, Calibration and 2010 Search Results with Improved Measurement of the Scintillation Response of Liquid Xenon to Low-Energy Nuclear Recoils

NASA Astrophysics Data System (ADS)

Plante, Guillaume

An impressive array of astrophysical observations suggest that 83% of the matter in the universe is in a form of non-luminous, cold, collisionless, non-baryonic dark matter. Several extensions of the Standard Model of particle physics aimed at solving the hierarchy problem predict stable weakly interacting massive particles (WIMPs) that could naturally have the right cosmological relic abundance today to compose most of the dark matter if their interactions with normal matter are on the order of a weak scale cross section. These candidates also have the added benefit that their properties and interaction rates can be computed in a well defined particle physics model. A considerable experimental effort is currently under way to uncover the nature of dark matter. One method of detecting WIMP dark matter is to look for its interactions in terrestrial detectors where it is expected to scatter off nuclei. In 2007, the XENON10 experiment took the lead over the most sensitive direct detection dark matter search in operation, the CDMS II experiment, by probing spin-independent WIMP-nucleon interaction cross sections down to sigmachi N ˜ 5 x 10-44 cm 2 at 30 GeV/c2. Liquefied noble gas detectors are now among the technologies at the forefront of direct detection experiments. Liquid xenon (LXe), in particular, is a well suited target for WIMP direct detection. It is easily scalable to larger target masses, allows discrimination between nuclear recoils and electronic recoils, and has an excellent stopping power to shield against external backgrounds. A particle losing energy in LXe creates both ionization electrons and scintillation light. In a dual-phase LXe time projection chamber (TPC) the ionization electrons are drifted and extracted into the gas phase where they are accelerated to amplify the charge signal into a proportional scintillation signal. These two signals allow the three-dimensional localization of events with millimeter precision and the ability to

Binary Black Hole Mergers and Recoil Kicks

NASA Technical Reports Server (NTRS)

Centrella, Joan; Baker, J.; Choi, D.; Koppitz, M.; vanMeter, J.; Miller, C.

2006-01-01

Recent developments in numerical relativity have made it possible to follow reliably the coalescence of two black holes from near the innermost stable circular orbit to final ringdown. This opens up a wide variety of exciting astrophysical applications of these simulations. Chief among these is the net kick received when two unequal mass or spinning black holes merge. The magnitude of this kick has bearing on the production and growth of supermassive black holes during the epoch of structure formation, and on the retention of black holes in stellar clusters. Here we report the first accurate numerical calculation of this kick, for two nonspinning black holes in a 1.5:1 mass ratio, which is expected based on analytic considerations to give a significant fraction of the maximum possible recoil. We have performed multiple runs with different initial separations, orbital angular momenta, resolutions, extraction radii, and gauges. The full range of our kick speeds is 86-116 kilometers per second, and the most reliable runs give kicks between 86 and 97 kilometers per second. This is intermediate between the estimates from two recent post-Newtonian analyses and suggests that at redshifts z greater than 10, halos with masses less than 10(exp 9) M(sub SUN) will have difficulty retaining coalesced black holes after major mergers.

Metal-Organic Framework-Derived Metal Oxide Embedded in Nitrogen-Doped Graphene Network for High-Performance Lithium-Ion Batteries.

PubMed

Sui, Zhu-Yin; Zhang, Pei-Ying; Xu, Meng-Ying; Liu, Yu-Wen; Wei, Zhi-Xiang; Han, Bao-Hang

2017-12-13

Metal-organic frameworks (MOFs) are hybrid inorganic-organic materials that can be used as effective precursors to prepare various functional nanomaterials for energy-related applications. Nevertheless, most MOF-derived metal oxides exhibit low electrical conductivity and mechanical strain. These characteristics limit their electrochemical performance and hamper their practical application. Herein, we report a rational strategy for enhancing the lithium storage performance of MOF-derived metal oxide. The hierarchically porous Co 3 O 4 @NGN is successfully prepared by embedding ZIF-67-derived Co 3 O 4 particles in a nitrogen-doped graphene network (NGN). The high electrical conductivity and porous structure of the NGN accelerates the diffusion of electrolyte ions and buffers stress resulting from the volume changes of Co 3 O 4 . As an anode material, the Co 3 O 4 @NGN shows high capacity (1030 mA h g -1 at 100 mA g -1 ), outstanding rate performance (681 mA h g -1 at 1000 mA g -1 ), and good cycling stability (676 mA h g -1 at 1000 mA g -1 after 400 cycles).

Therapeutic journery of nitrogen mustard as alkylating anticancer agents: Historic to future perspectives.

PubMed

Singh, Rajesh K; Kumar, Sahil; Prasad, D N; Bhardwaj, T R

2018-05-10

Cancer is considered as one of the most serious health problems today. The discovery of nitrogen mustard as an alkylating agent in 1942, opened a new era in the cancer chemotherapy. This valuable class of alkylating agent exerts its biological activity by binding to DNA, cross linking two strands, preventing DNA replication and ultimate cell death. At the molecular level, nitrogen lone pairs of nitrogen mustard generate a strained intermediate "aziridinium ion" which is very reactive towards DNA of tumor cell as well as normal cell resulting in various adverse side effects alogwith therapeutic implications. Over the last 75 years, due to its high reactivity and peripheral cytotoxicity, numerous modifications have been made in the area of nitrogen mustard to improve its efficacy as well as enhancing drug delivery specifically to tumor cells. This review mainly discusses the medicinal chemistry aspects in the development of various classes of nitrogen mustards (mechlorethamine, chlorambucil, melphalan, cyclophosphamide and steroidal based nitrogen mustards). The literature collection includes the historical and the latest developments in these areas. This comprehensive review also attempted to showcase the recent progress in the targeted delivery of nitrogen mustards that includes DNA directed nitrogen mustards, antibody directed enzyme prodrug therapy (ADEPT), gene directed enzyme prodrug therapy (GDEPT), nitrogen mustard activated by glutathione transferase, peptide based nitrogen mustards and CNS targeted nitrogen mustards. Copyright © 2018 Elsevier Masson SAS. All rights reserved.

Anammox-zeolite system acting as buffer to achieve stable effluent nitrogen values.

PubMed

Yapsakli, Kozet; Aktan, Cigdem Kalkan; Mertoglu, Bulent

2017-02-01

For a successful nitrogen removal, Anammox process needs to be established in line with a stable partial nitritation pretreatment unit since wastewater influent is mostly unsuitable for direct treatment by Anammox. Partial nitritation is, however, a critical bottleneck for the nitrogen removal since it is often difficult to maintain the right proportions of NO 2 -N and NH 4 -N during long periods of time for Anammox process. This study investigated the potential of Anammox-zeolite biofilter to buffer inequalities in nitrite and ammonium nitrogen in the influent feed. Anammox-zeolite biofilter combines the ion-exchange property of zeolite with the biological removal by Anammox process. Continuous-flow biofilter was operated for 570 days to test the response of Anammox-zeolite system for irregular ammonium and nitrite nitrogen entries. The reactor demonstrated stable and high nitrogen removal efficiencies (approximately 95 %) even when the influent NO 2 -N to NH 4 -N ratios were far from the stoichiometric ratio for Anammox reaction (i.e. NO 2 -N to NH 4 -N ranging from 0 to infinity). This is achieved by the sorption of surplus NH 4 -N by zeolite particles in case ammonium rich influent came in excess with respect to Anammox stoichiometry. Similarly, when ammonium-poor influent is fed to the reactor, ammonium desorption took place due to shifts in ion-exchange equilibrium and deficient amount were supplied by previously sorbed NH 4 -N. Here, zeolite acted as a preserving reservoir of ammonium where both sorption and desorption took place when needed and this caused the Anammox-zeolite system to act as a buffer system to generate a stable effluent.